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Home My WebLink AboutNC0000396_J15040128 Report_20150823+ DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Order Number: J15040128 Project Name: ASHEVILLE - AB GW ASSESSMENT SOIL Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker Customer Address: 200 CP and L Drive Arden, NC 28704 Lab Contact: Margaret Galvin -Karr Phone: 980-875-5219 MXG4644 (101161) Report Authorized By: U 2015.05.29 08:43:47 Date: (Signature) Ef RGY:,-04'00' Margaret Galvin -Karr Program Comments: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 5/29/2015 1 of 67 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: 2 of 67 Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015009716 ASHEVILLE 06 -Apr -15 11:45 AM Synterra K-01 2015009724 ASHEVILLE 06 -Apr -15 12:15 PM Synterra M-01 2015009725 ASHEVILLE 06 -Apr -15 2:17 PM Synterra SW -05 2015009726 ASHEVILLE 06 -Apr -15 2:20 PM Synterra SW -05 Dup 2015009727 ASHEVILLE 06 -Apr -15 1:15 PM Synterra C-02 5 Total Samples Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes F./] No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Reviewed By: Date: 3of67 Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 0 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040128 Site: K-01 Collection Date: 06 -Apr -15 11:45 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 4 of 67 Sample #: 2015009716 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040128 Site: M-01 Collection Date: 06 -Apr -15 12:15 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 67 Sample #: 2015009724 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040128 Site: SW -05 Collection Date: 06 -Apr -15 2:17 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 67 Sample #: 2015009725 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040128 Site: SW -05 Dup Collection Date: 06 -Apr -15 2:20 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 7 of 67 Sample #: 2015009726 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040128 Site: C-02 Collection Date: 06 -Apr -15 1:15 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 8 of 67 Sample #: 2015009727 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE aceAnaiXical www.pacelabs.com April 27, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: J15040128 Pace Project No.: 92244458 Pace Analytical Services, Inc. 9800 Kig,8y&e. Suite 100 Huntersville, INC 28078 (704)875-9092 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 08, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy HiQ p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 43 aceAnaiXical www.pacelabs.com Project: J15040128 Pace Project No.: 92244458 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification M PH -0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification M E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 Pace Analytical Services, Inc. 9800 Kli6c8ylfte. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Montana Certification #: Cert 0074 Nebraska Certification: NE -OS -28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification M FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification M 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 43 aceAnaiXical www.pacelabs.com SAMPLE SUMMARY Project: J15040128 Pace Project No.: 92244458 Lab ID Sample ID Matrix Date Collected Date Received 92244458001 2015009716 Solid 04/06/1511:45 04/08/1512:43 92244458002 2015009724 Solid 04/06/1512:15 04/08/1512:43 92244458003 2015009725 Solid 04/06/1514:17 04/08/1512:43 92244458004 2015009726 Solid 04/06/1514:20 04/08/1512:43 92244458005 2015009727 Solid 04/06/1513:15 04/08/1512:43 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 f iy'8yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 43 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 f iQ'8yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15040128 92244458 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92244458001 2015009716 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AIS 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92244458002 2015009724 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AIS 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92244458003 2015009725 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AIS 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92244458004 2015009726 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AIS 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92244458005 2015009727 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AIS 1 PASI-O EPA 9045 MLS 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 43 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 f ig'8yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040128 Pace Project No.: 92244458 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 43 aceAnaiXical www.pacelabs.com Project: J15040128 Pace Project No.: 92244458 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 ffli '8yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92244458001 2015009716 EPA 6010 Aluminum 16200 mg/kg 116 04/25/15 19:37 EPA 6010 Barium 101 mg/kg 11.6 04/25/15 19:37 EPA 6010 Beryllium 1.2J mg/kg 1.2 04/25/15 19:37 EPA 6010 Calcium 1660 mg/kg 581 04/25/15 19:37 EPA 6010 Chromium 34.1 mg/kg 5.8 04/25/15 19:37 EPA 6010 Copper 22.2 mg/kg 5.8 04/25/15 19:37 EPA 6010 Iron 24900 mg/kg 46.5 04/25/15 19:37 EPA 6010 Magnesium 2590 mg/kg 581 04/25/15 19:37 EPA 6010 Manganese 1070 mg/kg 5.8 04/25/15 19:37 EPA 6010 Nickel 12.8 mg/kg 5.8 04/25/15 19:37 EPA 6010 Potassium 1520 mg/kg 1160 04/25/15 19:37 EPA 6010 Strontium 23.5 mg/kg 11.6 04/25/15 19:37 EPA 6010 Zinc 68.8 mg/kg 23.3 04/25/15 19:37 EPA 6020 Arsenic 12.8J mg/kg 23.3 04/22/15 01:11 EPA 6020 Cobalt 19.5J mg/kg 23.3 04/22/15 01:11 EPA 6020 Lead 21.5J mg/kg 23.3 04/22/15 01:11 EPA 6020 Selenium 19.2J mg/kg 23.3 04/22/15 01:11 EPA 6020 Vanadium 39.3 mg/kg 23.3 04/22/15 01:11 EPA 7471 Mercury 0.043 mg/kg 0.036 04/20/15 20:08 ASTM D2974-87 Percent Moisture 77.6 % 0.10 04/17/15 09:31 EPA 9045 pH at 25 Degrees C 5.2 Std. Units 0.10 04/13/15 16:20 EPA 9056 Sulfate 673J mg/kg 1100 04/16/15 02:38 EPA 9060 Total Organic Carbon 48800 mg/kg 11000 04/24/15 06:40 EPA 9060 Total Organic Carbon 55600 mg/kg 11100 04/24/15 06:45 EPA 9060 Total Organic Carbon 69800 mg/kg 11000 04/24/15 06:52 EPA 9060 Total Organic Carbon 44700 mg/kg 11000 04/24/15 06:58 EPA 9060 Mean Total Organic Carbon 54700 mg/kg 11000 04/24/15 06:40 EPA 9060 RSD% 20.1 % 04/24/15 06:40 92244458002 2015009724 EPA 6010 Aluminum 13400 mg/kg 31.9 04/25/15 20:01 EPA 6010 Barium 80.7 mg/kg 3.2 04/25/15 20:01 EPA 6010 Beryllium 0.77 mg/kg 0.32 04/25/15 20:01 EPA 6010 Calcium 643 mg/kg 159 04/25/15 20:01 EPA 6010 Chromium 29.6 mg/kg 1.6 04/25/15 20:01 EPA 6010 Copper 13.7 mg/kg 1.6 04/25/15 20:01 EPA 6010 Iron 27800 mg/kg 12.7 04/25/15 20:01 EPA 6010 Magnesium 2980 mg/kg 159 04/25/15 20:01 EPA 6010 Manganese 1150 mg/kg 1.6 04/25/15 20:01 EPA 6010 Nickel 12.9 mg/kg 1.6 04/25/15 20:01 EPA 6010 Potassium 2140 mg/kg 319 04/25/15 20:01 EPA 6010 Strontium 5.5 mg/kg 3.2 04/25/15 20:01 EPA 6010 Zinc 51.3 mg/kg 6.4 04/25/15 20:01 EPA 6020 Cobalt 40.5 mg/kg 6.4 04/22/15 01:13 EPA 6020 Lead 7.3 mg/kg 6.4 04/22/15 01:13 EPA 6020 Selenium 9.7 mg/kg 6.4 04/22/15 01:13 EPA 6020 Vanadium 27.6 mg/kg 6.4 04/22/15 01:13 EPA 7471 Mercury 0.031 mg/kg 0.010 04/20/15 20:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 6 of 43 aceAnaiXical www.pacelabs.com Project: J15040128 Pace Project No.: 92244458 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 f ig'8yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92244458002 2015009724 ASTM D2974-87 Percent Moisture 21.2 % 0.10 04/17/15 09:31 EPA 9045 pH at 25 Degrees C 6.4 Std. Units 0.10 04/13/15 16:20 EPA 9056 Sulfate 1591 mg/kg 318 04/16/15 02:59 EPA 9060 Total Organic Carbon 3210 mg/kg 766 04/24/15 07:53 EPA 9060 Total Organic Carbon 3290 mg/kg 757 04/24/15 07:58 EPA 9060 Total Organic Carbon 3270 mg/kg 766 04/24/15 08:04 EPA 9060 Total Organic Carbon 3540 mg/kg 760 04/24/15 08:09 EPA 9060 Mean Total Organic Carbon 3320 mg/kg 762 04/24/15 07:53 EPA 9060 RSD% 4.4 % 04/24/15 07:53 92244458003 2015009725 EPA 6010 Aluminum 8830 mg/kg 35.7 04/25/15 20:05 EPA 6010 Barium 177 mg/kg 3.6 04/25/15 20:05 EPA 6010 Beryllium 1.0 mg/kg 0.36 04/25/15 20:05 EPA 6010 Calcium 1850 mg/kg 178 04/25/15 20:05 EPA 6010 Chromium 8.7 mg/kg 1.8 04/25/15 20:05 EPA 6010 Copper 11.5 mg/kg 1.8 04/25/15 20:05 EPA 6010 Iron 12600 mg/kg 14.3 04/25/15 20:05 EPA 6010 Magnesium 2360 mg/kg 178 04/25/15 20:05 EPA 6010 Manganese 325 mg/kg 1.8 04/25/15 20:05 EPA 6010 Molybdenum 1.91 mg/kg 3.6 04/25/15 20:05 EPA 6010 Nickel 12.0 mg/kg 1.8 04/25/15 20:05 EPA 6010 Potassium 3690 mg/kg 357 04/25/15 20:05 EPA 6010 Strontium 35.7 mg/kg 3.6 04/25/15 20:05 EPA 6010 Zinc 50.3 mg/kg 7.1 04/25/15 20:05 EPA 6020 Arsenic 29.8 mg/kg 7.1 04/22/15 01:15 EPA 6020 Cobalt 12.7 mg/kg 7.1 04/22/15 01:15 EPA 6020 Lead 5.6J mg/kg 7.1 04/22/15 01:15 EPA 6020 Vanadium 29.4 mg/kg 7.1 04/22/15 01:15 EPA 7471 Mercury 0.059 mg/kg 0.011 04/20/15 20:12 ASTM D2974-87 Percent Moisture 29.8 % 0.10 04/17/15 09:31 EPA 9045 pH at 25 Degrees C 6.8 Std. Units 0.10 04/13/15 16:20 EPA 9056 Sulfate 182J mg/kg 351 04/16/15 03:20 EPA 9060 Total Organic Carbon 21400 mg/kg 1940 04/24/15 08:15 EPA 9060 Total Organic Carbon 25000 mg/kg 1940 04/24/15 08:20 EPA 9060 Total Organic Carbon 28300 mg/kg 1960 04/24/15 08:26 EPA 9060 Total Organic Carbon 16500 mg/kg 1930 04/24/15 08:32 EPA 9060 Mean Total Organic Carbon 22800 mg/kg 1940 04/24/15 08:15 EPA 9060 RSD% 22.2 % 04/24/15 08:15 92244458004 2015009726 EPA 6010 Aluminum 3960 mg/kg 30.6 04/25/15 20:10 EPA 6010 Barium 40.2 mg/kg 3.1 04/25/15 20:10 EPA 6010 Beryllium 0.32 mg/kg 0.31 04/25/15 20:10 EPA 6010 Calcium 1520 mg/kg 153 04/25/15 20:10 EPA 6010 Chromium 2.3 mg/kg 1.5 04/25/15 20:10 EPA 6010 Copper 5.5 mg/kg 1.5 04/25/15 20:10 EPA 6010 Iron 7200 mg/kg 12.3 04/25/15 20:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. D3 D3 Qualifiers Page 7 of 43 aceAnaiXical www.pacelabs.com Project: J15040128 Pace Project No.: 92244458 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 ffli '8yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92244458004 2015009726 EPA 6010 Magnesium 1570 mg/kg 153 04/25/15 20:10 EPA 6010 Manganese 174 mg/kg 1.5 04/25/15 20:10 EPA 6010 Nickel 2.1 mg/kg 1.5 04/25/15 20:10 EPA 6010 Potassium 2580 mg/kg 306 04/25/15 20:10 EPA 6010 Strontium 6.8 mg/kg 3.1 04/25/15 20:10 EPA 6010 Zinc 24.0 mg/kg 6.1 04/25/15 20:10 EPA 6020 Arsenic 5.OJ mg/kg 6.1 04/22/15 01:18 EPA 6020 Vanadium 10.8 mg/kg 6.1 04/22/15 01:18 ASTM D2974-87 Percent Moisture 19.5 % 0.10 04/17/15 09:31 EPA 9045 pH at 25 Degrees C 7.0 Std. Units 0.10 04/13/15 16:20 EPA 9060 Total Organic Carbon 2030 mg/kg 742 04/24/15 08:39 EPA 9060 Total Organic Carbon 1740 mg/kg 745 04/24/15 08:45 EPA 9060 Total Organic Carbon 2500 mg/kg 751 04/24/15 08:51 EPA 9060 Total Organic Carbon 3000 mg/kg 744 04/24/15 08:56 EPA 9060 Mean Total Organic Carbon 2320 mg/kg 745 04/24/15 08:39 EPA 9060 RSD% 23.9 % 04/24/15 08:39 92244458005 2015009727 EPA 6010 Aluminum 12800 mg/kg 399 04/26/15 23:58 EPA 6010 Barium 2380 mg/kg 39.9 04/26/15 23:58 EPA 6010 Beryllium 2.7J mg/kg 4.0 04/26/15 23:58 EPA 6010 Calcium 1870J mg/kg 1990 04/26/15 23:58 EPA 6010 Copper 149 mg/kg 19.9 04/26/15 23:58 EPA 6010 Iron 16600 mg/kg 159 04/26/15 23:58 EPA 6010 Magnesium 1710J mg/kg 1990 04/26/15 23:58 EPA 6010 Manganese 34600 mg/kg 19.9 04/26/15 23:58 EPA 6010 Molybdenum 491 mg/kg 39.9 04/26/15 23:58 EPA 6010 Nickel 219 mg/kg 19.9 04/26/15 23:58 EPA 6010 Potassium 2110J mg/kg 3990 04/26/15 23:58 EPA 6010 Strontium 194 mg/kg 39.9 04/26/15 23:58 EPA 6010 Zinc 320 mg/kg 79.7 04/26/15 23:58 EPA 6020 Antimony 12.0 mg/kg 8.0 04/22/15 01:20 N2 EPA 6020 Arsenic 463 mg/kg 8.0 04/22/15 01:20 EPA 6020 Cadmium 9.5 mg/kg 0.96 04/22/15 01:20 EPA 6020 Cobalt 455 mg/kg 8.0 04/22/15 01:20 EPA 6020 Lead 16.1 mg/kg 8.0 04/22/15 01:20 EPA 6020 Selenium 27.3 mg/kg 8.0 04/22/15 01:20 EPA 6020 Thallium 9.8 mg/kg 8.0 04/22/15 01:20 EPA 6020 Vanadium 306 mg/kg 8.0 04/22/15 01:20 EPA 7471 Mercury 0.0074J mg/kg 0.013 04/20/15 20:17 ASTM D2974-87 Percent Moisture 38.1 % 0.10 04/17/15 09:31 EPA 9045 pH at 25 Degrees C 6.7 Std. Units 0.10 04/13/15 16:20 EPA 9056 Sulfate 357J mg/kg 410 04/16/15 04:03 EPA 9060 Total Organic Carbon 25300 mg/kg 974 04/24/15 09:01 EPA 9060 Total Organic Carbon 25000 mg/kg 974 04/24/15 09:07 EPA 9060 Total Organic Carbon 18900 mg/kg 973 04/24/15 09:13 EPA 9060 Total Organic Carbon 19700 mg/kg 973 04/24/15 09:20 EPA 9060 Mean Total Organic Carbon 22300 mg/kg 974 04/24/15 09:01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 8 of 43 aceAnaiXical www.pacelabs.com Project: J15040128 Pace Project No.: 92244458 Lab Sample ID Method 92244458005 EPA 9060 SUMMARY OF DETECTION Client Sample ID Parameters Result 2015009727 RSD% 15.3 Pace Analytical Services, Inc. 9800 ffli .8yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 Units Report Limit Analyzed Qualifiers REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 04/24/15 09:01 Page 9 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli '8yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040128 Pace Project No.: 92244458 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 27, 2015 General Information: 5 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23698 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92244973001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1188089) • Aluminum • Barium • Copper • Iron • Magnesium • Manganese • Potassium • Strontium • MSD (Lab ID: 1188090) • Aluminum • Barium • Copper • Iron • Magnesium • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 43 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15040128 Pace Project No.: 92244458 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 27, 2015 QC Batch: MPRP/23698 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92244973001 R1: RPD value was outside control limits. • MSD (Lab ID: 1188090) • Strontium Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 14482 Analyte Comments: QC Batch: MPRP/23698 Pace Analytical Services, Inc. 9800 Kiigc&yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1188087) • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPi '8yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040128 Pace Project No.: 92244458 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 27, 2015 General Information: 5 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23699 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92244973002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1188093) • Antimony • Cobalt • MSD (Lab ID: 1188094) • Selenium • Vanadium Additional Comments: Batch Comments: Batch was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 9630 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 �nic&yo.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040128 Pace Project No.: 92244458 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 27, 2015 Analyte Comments: QC Batch: MPRP/23699 N2: The lab does not hold TNI accreditation for this parameter. •2015009716 (Lab ID:92244458001) • Antimony •2015009724 (Lab ID:92244458002) • Antimony •2015009725 (Lab ID:92244458003) • Antimony •2015009726 (Lab ID:92244458004) • Antimony •2015009727 (Lab ID:92244458005) • Antimony • BLANK (Lab ID: 1188091) • Antimony • LCS (Lab ID: 1188092) • Antimony • MS (Lab ID: 1188093) • Antimony • MSD (Lab ID: 1188094) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K2'8yo.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040128 Pace Project No.: 92244458 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: April 27, 2015 General Information: 5 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5605 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92244973001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1188097) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KS'8yo.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040128 Pace Project No.: 92244458 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: April 27, 2015 General Information: 5 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K4'8yo.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040128 Pace Project No.: 92244458 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: April 27, 2015 General Information: 5 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45422 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015009716 (Lab ID:92244458001) • Chloride •2015009724 (Lab ID:92244458002) • Chloride • Sulfate •2015009725 (Lab ID:92244458003) • Chloride • Sulfate •2015009726 (Lab ID:92244458004) • Chloride • Sulfate •2015009727 (Lab ID:92244458005) • Chloride REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPi '8yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040128 Pace Project No.: 92244458 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: April 27, 2015 General Information: 5 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015009716 (Lab ID: 92244458001) •2015009724 (Lab ID: 92244458002) •2015009725 (Lab ID: 92244458003) •2015009726 (Lab ID: 92244458004) •2015009727 (Lab ID: 92244458005) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 tf� '8yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040128 Pace Project No.: 92244458 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: April 27, 2015 General Information: 5 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 43 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040128 Pace Project No.: 92244458 Sample: 2015009716 Lab ID: 92244458001 Collected: 04/06/15 11:45 Received: 04/08/15 12:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 16200 mg/kg 116 58.1 5 04/19/15 05:38 04/25/15 19:37 7429-90-5 Barium 101 mg/kg 11.6 5.8 5 04/19/15 05:38 04/25/15 19:37 7440-39-3 Beryllium 1.2J mg/kg 1.2 0.58 5 04/19/15 05:38 04/25/15 19:37 7440-41-7 Boron ND mg/kg 58.1 29.1 5 04/19/15 05:38 04/25/15 19:37 7440-42-8 Calcium 1660 mg/kg 581 291 5 04/19/15 05:38 04/25/15 19:37 7440-70-2 Chromium 34.1 mg/kg 5.8 2.9 5 04/19/15 05:38 04/25/15 19:37 7440-47-3 Copper 22.2 mg/kg 5.8 2.9 5 04/19/15 05:38 04/25/15 19:37 7440-50-8 Iron 24900 mg/kg 46.5 23.3 5 04/19/15 05:38 04/25/15 19:37 7439-89-6 Magnesium 2590 mg/kg 581 291 5 04/19/15 05:38 04/25/15 19:37 7439-95-4 Manganese 1070 mg/kg 5.8 2.9 5 04/19/15 05:38 04/25/15 19:37 7439-96-5 Molybdenum ND mg/kg 11.6 5.8 5 04/19/15 05:38 04/25/15 19:37 7439-98-7 Nickel 12.8 mg/kg 5.8 2.9 5 04/19/15 05:38 04/25/15 19:37 7440-02-0 Potassium 1520 mg/kg 1160 581 5 04/19/15 05:38 04/25/15 19:37 7440-09-7 Sodium ND mg/kg 1160 581 5 04/19/15 05:38 04/25/15 19:37 7440-23-5 Strontium 23.5 mg/kg 11.6 5.8 5 04/19/15 05:38 04/25/15 19:37 7440-24-6 Zinc 68.8 mg/kg 23.3 11.6 5 04/19/15 05:38 04/25/15 19:37 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 23.3 11.6 100 04/19/15 05:38 04/22/15 01:11 7440-36-0 N2 Arsenic 12.8J mg/kg 23.3 11.6 100 04/19/15 05:38 04/22/15 01:11 7440-38-2 Cadmium ND mg/kg 2.8 1.4 100 04/19/15 05:38 04/22/15 01:11 7440-43-9 Cobalt 19.5J mg/kg 23.3 11.6 100 04/19/15 05:38 04/22/15 01:11 7440-48-4 Lead 21.5J mg/kg 23.3 11.6 100 04/19/15 05:38 04/22/15 01:11 7439-92-1 Selenium 19.2J mg/kg 23.3 11.6 100 04/19/15 05:38 04/22/15 01:11 7782-49-2 Thallium ND mg/kg 23.3 11.6 100 04/19/15 05:38 04/22/15 01:11 7440-28-0 Vanadium 39.3 mg/kg 23.3 11.6 100 04/19/15 05:38 04/22/15 01:11 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.043 mg/kg 0.036 0.018 1 04/19/15 05:30 04/20/15 20:08 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 77.6 % 0.10 0.10 1 04/17/15 09:31 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.2 Std. Units 0.10 0.10 1 04/13/15 16:20 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 1100 548 5 04/16/15 02:38 16887-00-6 D3 Sulfate 673J mg/kg 1100 548 5 04/16/15 02:38 14808-79-8 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 110 54.8 5 04/16/15 02:38 14797-55-8 H3 Date: 04/27/2015 04:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 43 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040128 Pace Project No.: 92244458 Pace Analytical Services, Inc. 9800 tf�%c&yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015009716 Lab ID: 92244458001 Collected: 04/06/15 11:45 Received: 04/08/15 12:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 48800 mg/kg 11000 5520 1 04/24/15 06:40 7440-44-0 Total Organic Carbon 55600 mg/kg 11100 5570 1 04/24/15 06:45 7440-44-0 Total Organic Carbon 69800 mg/kg 11000 5510 1 04/24/15 06:52 7440-44-0 Total Organic Carbon 44700 mg/kg 11000 5480 1 04/24/15 06:58 7440-44-0 Mean Total Organic Carbon 54700 mg/kg 11000 5520 1 04/24/15 06:40 7440-44-0 Surrogates RSD% 20.1 % 1 04/24/15 06:40 Date: 04/27/2015 04:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 43 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 tf� '8yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040128 Pace Project No.: 92244458 Sample: 2015009724 Lab ID: 92244458002 Collected: 04/06/15 12:15 Received: 04/08/15 12:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 13400 mg/kg 31.9 15.9 5 04/19/15 05:38 04/25/15 20:01 7429-90-5 Barium 80.7 mg/kg 3.2 1.6 5 04/19/15 05:38 04/25/15 20:01 7440-39-3 Beryllium 0.77 mg/kg 0.32 0.16 5 04/19/15 05:38 04/25/15 20:01 7440-41-7 Boron ND mg/kg 15.9 8.0 5 04/19/15 05:38 04/25/15 20:01 7440-42-8 Calcium 643 mg/kg 159 79.6 5 04/19/15 05:38 04/25/15 20:01 7440-70-2 Chromium 29.6 mg/kg 1.6 0.80 5 04/19/15 05:38 04/25/15 20:01 7440-47-3 Copper 13.7 mg/kg 1.6 0.80 5 04/19/15 05:38 04/25/15 20:01 7440-50-8 Iron 27800 mg/kg 12.7 6.4 5 04/19/15 05:38 04/25/15 20:01 7439-89-6 Magnesium 2980 mg/kg 159 79.6 5 04/19/15 05:38 04/25/15 20:01 7439-95-4 Manganese 1150 mg/kg 1.6 0.80 5 04/19/15 05:38 04/25/15 20:01 7439-96-5 Molybdenum ND mg/kg 3.2 1.6 5 04/19/15 05:38 04/25/15 20:01 7439-98-7 Nickel 12.9 mg/kg 1.6 0.80 5 04/19/15 05:38 04/25/15 20:01 7440-02-0 Potassium 2140 mg/kg 319 159 5 04/19/15 05:38 04/25/15 20:01 7440-09-7 Sodium ND mg/kg 319 159 5 04/19/15 05:38 04/25/15 20:01 7440-23-5 Strontium 5.5 mg/kg 3.2 1.6 5 04/19/15 05:38 04/25/15 20:01 7440-24-6 Zinc 51.3 mg/kg 6.4 3.2 5 04/19/15 05:38 04/25/15 20:01 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.4 3.2 100 04/19/15 05:38 04/22/15 01:13 7440-36-0 N2 Arsenic ND mg/kg 6.4 3.2 100 04/19/15 05:38 04/22/15 01:13 7440-38-2 Cadmium ND mg/kg 0.76 0.38 100 04/19/15 05:38 04/22/15 01:13 7440-43-9 Cobalt 40.5 mg/kg 6.4 3.2 100 04/19/15 05:38 04/22/15 01:13 7440-48-4 Lead 7.3 mg/kg 6.4 3.2 100 04/19/15 05:38 04/22/15 01:13 7439-92-1 Selenium 9.7 mg/kg 6.4 3.2 100 04/19/15 05:38 04/22/15 01:13 7782-49-2 Thallium ND mg/kg 6.4 3.2 100 04/19/15 05:38 04/22/15 01:13 7440-28-0 Vanadium 27.6 mg/kg 6.4 3.2 100 04/19/15 05:38 04/22/15 01:13 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.031 mg/kg 0.010 0.0052 1 04/19/15 05:30 04/20/15 20:10 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 21.2 % 0.10 0.10 1 04/17/15 09:31 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.4 Std. Units 0.10 0.10 1 04/13/15 16:20 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 318 159 5 04/16/15 02:59 16887-00-6 D3 Sulfate 1591 mg/kg 318 159 5 04/16/15 02:59 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 31.8 15.9 5 04/16/15 02:59 14797-55-8 H3 Date: 04/27/2015 04:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 43 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040128 Pace Project No.: 92244458 Pace Analytical Services, Inc. 9800 %'8yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015009724 Lab ID: 92244458002 Collected: 04/06/15 12:15 Received: 04/08/15 12:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 3210 mg/kg 766 383 1 04/24/15 07:53 7440-44-0 Total Organic Carbon 3290 mg/kg 757 379 1 04/24/15 07:58 7440-44-0 Total Organic Carbon 3270 mg/kg 766 383 1 04/24/15 08:04 7440-44-0 Total Organic Carbon 3540 mg/kg 760 380 1 04/24/15 08:09 7440-44-0 Mean Total Organic Carbon 3320 mg/kg 762 381 1 04/24/15 07:53 7440-44-0 Surrogates RSD% 4.4 % 1 04/24/15 07:53 Date: 04/27/2015 04:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 43 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 �nic&yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040128 Pace Project No.: 92244458 Sample: 2015009725 Lab ID: 92244458003 Collected: 04/06/15 14:17 Received: 04/08/15 12:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 8830 mg/kg 35.7 17.8 5 04/19/15 05:38 04/25/15 20:05 7429-90-5 Barium 177 mg/kg 3.6 1.8 5 04/19/15 05:38 04/25/15 20:05 7440-39-3 Beryllium 1.0 mg/kg 0.36 0.18 5 04/19/15 05:38 04/25/15 20:05 7440-41-7 Boron ND mg/kg 17.8 8.9 5 04/19/15 05:38 04/25/15 20:05 7440-42-8 Calcium 1850 mg/kg 178 89.2 5 04/19/15 05:38 04/25/15 20:05 7440-70-2 Chromium 8.7 mg/kg 1.8 0.89 5 04/19/15 05:38 04/25/15 20:05 7440-47-3 Copper 11.5 mg/kg 1.8 0.89 5 04/19/15 05:38 04/25/15 20:05 7440-50-8 Iron 12600 mg/kg 14.3 7.1 5 04/19/15 05:38 04/25/15 20:05 7439-89-6 Magnesium 2360 mg/kg 178 89.2 5 04/19/15 05:38 04/25/15 20:05 7439-95-4 Manganese 325 mg/kg 1.8 0.89 5 04/19/15 05:38 04/25/15 20:05 7439-96-5 Molybdenum 1.91 mg/kg 3.6 1.8 5 04/19/15 05:38 04/25/15 20:05 7439-98-7 Nickel 12.0 mg/kg 1.8 0.89 5 04/19/15 05:38 04/25/15 20:05 7440-02-0 Potassium 3690 mg/kg 357 178 5 04/19/15 05:38 04/25/15 20:05 7440-09-7 Sodium ND mg/kg 357 178 5 04/19/15 05:38 04/25/15 20:05 7440-23-5 Strontium 35.7 mg/kg 3.6 1.8 5 04/19/15 05:38 04/25/15 20:05 7440-24-6 Zinc 50.3 mg/kg 7.1 3.6 5 04/19/15 05:38 04/25/15 20:05 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 7.1 3.6 100 04/19/15 05:38 04/22/15 01:15 7440-36-0 N2 Arsenic 29.8 mg/kg 7.1 3.6 100 04/19/15 05:38 04/22/15 01:15 7440-38-2 Cadmium ND mg/kg 0.86 0.43 100 04/19/15 05:38 04/22/15 01:15 7440-43-9 Cobalt 12.7 mg/kg 7.1 3.6 100 04/19/15 05:38 04/22/15 01:15 7440-48-4 Lead 5.6J mg/kg 7.1 3.6 100 04/19/15 05:38 04/22/15 01:15 7439-92-1 Selenium ND mg/kg 7.1 3.6 100 04/19/15 05:38 04/22/15 01:15 7782-49-2 Thallium ND mg/kg 7.1 3.6 100 04/19/15 05:38 04/22/15 01:15 7440-28-0 Vanadium 29.4 mg/kg 7.1 3.6 100 04/19/15 05:38 04/22/15 01:15 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.059 mg/kg 0.011 0.0057 1 04/19/15 05:30 04/20/15 20:12 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 29.8 % 0.10 0.10 1 04/17/15 09:31 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.8 Std. Units 0.10 0.10 1 04/13/15 16:20 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 351 176 5 04/16/15 03:20 16887-00-6 D3 Sulfate 182J mg/kg 351 176 5 04/16/15 03:20 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 35.1 17.6 5 04/16/15 03:20 14797-55-8 H3 Date: 04/27/2015 04:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 43 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040128 Pace Project No.: 92244458 Pace Analytical Services, Inc. 9800 t 2'8yo.. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015009725 Lab ID: 92244458003 Collected: 04/06/15 14:17 Received: 04/08/15 12:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 21400 mg/kg 1940 972 1 04/24/15 08:15 7440-44-0 Total Organic Carbon 25000 mg/kg 1940 970 1 04/24/15 08:20 7440-44-0 Total Organic Carbon 28300 mg/kg 1960 981 1 04/24/15 08:26 7440-44-0 Total Organic Carbon 16500 mg/kg 1930 965 1 04/24/15 08:32 7440-44-0 Mean Total Organic Carbon 22800 mg/kg 1940 972 1 04/24/15 08:15 7440-44-0 Surrogates RSD% 22.2 % 1 04/24/15 08:15 Date: 04/27/2015 04:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 43 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 t S'8yo.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040128 Pace Project No.: 92244458 Sample: 2015009726 Lab ID: 92244458004 Collected: 04/06/15 14:20 Received: 04/08/15 12:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 3960 mg/kg 30.6 15.3 5 04/19/15 05:38 04/25/15 20:10 7429-90-5 Barium 40.2 mg/kg 3.1 1.5 5 04/19/15 05:38 04/25/15 20:10 7440-39-3 Beryllium 0.32 mg/kg 0.31 0.15 5 04/19/15 05:38 04/25/15 20:10 7440-41-7 Boron ND mg/kg 15.3 7.7 5 04/19/15 05:38 04/25/15 20:10 7440-42-8 Calcium 1520 mg/kg 153 76.6 5 04/19/15 05:38 04/25/15 20:10 7440-70-2 Chromium 2.3 mg/kg 1.5 0.77 5 04/19/15 05:38 04/25/15 20:10 7440-47-3 Copper 5.5 mg/kg 1.5 0.77 5 04/19/15 05:38 04/25/15 20:10 7440-50-8 Iron 7200 mg/kg 12.3 6.1 5 04/19/15 05:38 04/25/15 20:10 7439-89-6 Magnesium 1570 mg/kg 153 76.6 5 04/19/15 05:38 04/25/15 20:10 7439-95-4 Manganese 174 mg/kg 1.5 0.77 5 04/19/15 05:38 04/25/15 20:10 7439-96-5 Molybdenum ND mg/kg 3.1 1.5 5 04/19/15 05:38 04/25/15 20:10 7439-98-7 Nickel 2.1 mg/kg 1.5 0.77 5 04/19/15 05:38 04/25/15 20:10 7440-02-0 Potassium 2580 mg/kg 306 153 5 04/19/15 05:38 04/25/15 20:10 7440-09-7 Sodium ND mg/kg 306 153 5 04/19/15 05:38 04/25/15 20:10 7440-23-5 Strontium 6.8 mg/kg 3.1 1.5 5 04/19/15 05:38 04/25/15 20:10 7440-24-6 Zinc 24.0 mg/kg 6.1 3.1 5 04/19/15 05:38 04/25/15 20:10 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.1 3.1 100 04/19/15 05:38 04/22/15 01:18 7440-36-0 N2 Arsenic 5.OJ mg/kg 6.1 3.1 100 04/19/15 05:38 04/22/15 01:18 7440-38-2 Cadmium ND mg/kg 0.74 0.37 100 04/19/15 05:38 04/22/15 01:18 7440-43-9 Cobalt ND mg/kg 6.1 3.1 100 04/19/15 05:38 04/22/15 01:18 7440-48-4 Lead ND mg/kg 6.1 3.1 100 04/19/15 05:38 04/22/15 01:18 7439-92-1 Selenium ND mg/kg 6.1 3.1 100 04/19/15 05:38 04/22/15 01:18 7782-49-2 Thallium ND mg/kg 6.1 3.1 100 04/19/15 05:38 04/22/15 01:18 7440-28-0 Vanadium 10.8 mg/kg 6.1 3.1 100 04/19/15 05:38 04/22/15 01:18 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0095 0.0047 1 04/19/15 05:30 04/20/15 20:14 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 19.5 % 0.10 0.10 1 04/17/15 09:31 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 7.0 Std. Units 0.10 0.10 1 04/13/15 16:20 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 304 152 5 04/16/15 03:42 16887-00-6 D3 Sulfate ND mg/kg 304 152 5 04/16/15 03:42 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 30.4 15.2 5 04/16/15 03:42 14797-55-8 H3 Date: 04/27/2015 04:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 43 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040128 Pace Project No.: 92244458 Pace Analytical Services, Inc. 9800 t 4'8yo.. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015009726 Lab ID: 92244458004 Collected: 04/06/15 14:20 Received: 04/08/15 12:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 2030 mg/kg 742 371 1 04/24/15 08:39 7440-44-0 Total Organic Carbon 1740 mg/kg 745 373 1 04/24/15 08:45 7440-44-0 Total Organic Carbon 2500 mg/kg 751 376 1 04/24/15 08:51 7440-44-0 Total Organic Carbon 3000 mg/kg 744 372 1 04/24/15 08:56 7440-44-0 Mean Total Organic Carbon 2320 mg/kg 745 373 1 04/24/15 08:39 7440-44-0 Surrogates RSD% 23.9 % 1 04/24/15 08:39 Date: 04/27/2015 04:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 43 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 %'8yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040128 Pace Project No.: 92244458 Sample: 2015009727 Lab ID: 92244458005 Collected: 04/06/15 13:15 Received: 04/08/15 12:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 12800 mg/kg 399 199 50 04/19/15 05:38 04/26/15 23:58 7429-90-5 Barium 2380 mg/kg 39.9 19.9 50 04/19/15 05:38 04/26/15 23:58 7440-39-3 Beryllium 2.7J mg/kg 4.0 2.0 50 04/19/15 05:38 04/26/15 23:58 7440-41-7 Boron ND mg/kg 199 99.6 50 04/19/15 05:38 04/26/15 23:58 7440-42-8 Calcium 1870J mg/kg 1990 996 50 04/19/15 05:38 04/26/15 23:58 7440-70-2 Chromium ND mg/kg 19.9 10 50 04/19/15 05:38 04/26/15 23:58 7440-47-3 Copper 149 mg/kg 19.9 10 50 04/19/15 05:38 04/26/15 23:58 7440-50-8 Iron 16600 mg/kg 159 79.7 50 04/19/15 05:38 04/26/15 23:58 7439-89-6 Magnesium 1710J mg/kg 1990 996 50 04/19/15 05:38 04/26/15 23:58 7439-95-4 Manganese 34600 mg/kg 19.9 10 50 04/19/15 05:38 04/26/15 23:58 7439-96-5 Molybdenum 491 mg/kg 39.9 19.9 50 04/19/15 05:38 04/26/15 23:58 7439-98-7 Nickel 219 mg/kg 19.9 10 50 04/19/15 05:38 04/26/15 23:58 7440-02-0 Potassium 2110J mg/kg 3990 1990 50 04/19/15 05:38 04/26/15 23:58 7440-09-7 Sodium ND mg/kg 3990 1990 50 04/19/15 05:38 04/26/15 23:58 7440-23-5 Strontium 194 mg/kg 39.9 19.9 50 04/19/15 05:38 04/26/15 23:58 7440-24-6 Zinc 320 mg/kg 79.7 39.9 50 04/19/15 05:38 04/26/15 23:58 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony 12.0 mg/kg 8.0 4.0 100 04/19/15 05:38 04/22/15 01:20 7440-36-0 N2 Arsenic 463 mg/kg 8.0 4.0 100 04/19/15 05:38 04/22/15 01:20 7440-38-2 Cadmium 9.5 mg/kg 0.96 0.48 100 04/19/15 05:38 04/22/15 01:20 7440-43-9 Cobalt 455 mg/kg 8.0 4.0 100 04/19/15 05:38 04/22/15 01:20 7440-48-4 Lead 16.1 mg/kg 8.0 4.0 100 04/19/15 05:38 04/22/15 01:20 7439-92-1 Selenium 27.3 mg/kg 8.0 4.0 100 04/19/15 05:38 04/22/15 01:20 7782-49-2 Thallium 9.8 mg/kg 8.0 4.0 100 04/19/15 05:38 04/22/15 01:20 7440-28-0 Vanadium 306 mg/kg 8.0 4.0 100 04/19/15 05:38 04/22/15 01:20 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.0074J mg/kg 0.013 0.0067 1 04/19/15 05:30 04/20/15 20:17 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 38.1 % 0.10 0.10 1 04/17/15 09:31 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.7 Std. Units 0.10 0.10 1 04/13/15 16:20 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 410 205 5 04/16/15 04:03 16887-00-6 D3 Sulfate 357J mg/kg 410 205 5 04/16/15 04:03 14808-79-8 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 41.0 20.5 5 04/16/15 04:03 14797-55-8 H3 Date: 04/27/2015 04:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 43 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040128 Pace Project No.: 92244458 Pace Analytical Services, Inc. 9800 %'8yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015009727 Lab ID: 92244458005 Collected: 04/06/15 13:15 Received: 04/08/15 12:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 25300 mg/kg 974 487 1 04/24/15 09:01 7440-44-0 Total Organic Carbon 25000 mg/kg 974 487 1 04/24/15 09:07 7440-44-0 Total Organic Carbon 18900 mg/kg 973 486 1 04/24/15 09:13 7440-44-0 Total Organic Carbon 19700 mg/kg 973 486 1 04/24/15 09:20 7440-44-0 Mean Total Organic Carbon 22300 mg/kg 974 487 1 04/24/15 09:01 7440-44-0 Surrogates RSD% 15.3 % 1 04/24/15 09:01 Date: 04/27/2015 04:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 43 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040128 Pace Project No.: 92244458 QC Batch: MERP/5605 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92244458001, 92244458002, 92244458003, 92244458004, 92244458005 METHOD BLANK: 1188095 Matrix: Solid Associated Lab Samples: 92244458001, 92244458002, 92244458003, 92244458004, 92244458005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0083 04/20/1519:36 LABORATORY CONTROL SAMPLE: 1188096 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .081 0.074 90 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188097 1188098 MS MSD 92244973001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg ND .0961 .0961 0.078 0.086 79 87 80-120 10 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:14 PM without the written consent of Pace Analytical Services, Inc.. Page 29 of 43 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040128 Pace Project No.: 92244458 QC Batch: MPRP/23698 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92244458001, 92244458002, 92244458003, 92244458004, 92244458005 METHOD BLANK: 1188087 Matrix: Solid Associated Lab Samples: 92244458001, 92244458002, 92244458003, 92244458004, 92244458005 Blank Reporting Parameter Units Result Limit Analyzed Aluminum mg/kg ND 5.1 04/25/1518:28 Barium mg/kg ND 0.51 04/25/1518:28 Beryllium mg/kg ND 0.051 04/25/1518:28 Boron mg/kg ND 2.5 04/25/1518:28 Calcium mg/kg ND 25.3 04/25/1518:28 Chromium mg/kg ND 0.25 04/25/1518:28 Copper mg/kg ND 0.25 04/25/1518:28 Iron mg/kg 3.1 2.0 04/25/1518:28 P8 Magnesium mg/kg ND 25.3 04/25/1518:28 Manganese mg/kg ND 0.25 04/25/1518:28 Molybdenum mg/kg ND 0.51 04/25/1518:28 Nickel mg/kg ND 0.25 04/25/1518:28 Potassium mg/kg ND 50.7 04/25/1518:28 Sodium mg/kg ND 50.7 04/25/1518:28 Strontium mg/kg ND 0.51 04/25/1518:28 Zinc mg/kg ND 1.0 04/25/1518:28 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1188088 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 120 125 104 80-120 Barium mg/kg 12 12.5 104 80-120 Beryllium mg/kg 1.2 1.2 103 80-120 Boron mg/kg 120 119 99 80-120 Calcium mg/kg 600 635 106 80-120 Chromium mg/kg 12 11.8 98 80-120 Copper mg/kg 12 11.8 98 80-120 Iron mg/kg 120 126 105 80-120 Magnesium mg/kg 600 619 103 80-120 Manganese mg/kg 12 12.1 101 80-120 Molybdenum mg/kg 12 12.0 100 80-120 Nickel mg/kg 12 12.4 103 80-120 Potassium mg/kg 600 615 102 80-120 Sodium mg/kg 600 644 107 80-120 Strontium mg/kg 12 12.4 103 80-120 Zinc mg/kg 60 61.7 103 80-120 Pace Analytical Services, Inc. 9800 K�gc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:14 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 43 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040128 Pace Project No.: 92244458 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188089 1188090 MS MSD 92244973001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 13500 142 150 16700 15300 2250 1240 75-125 8 20 M1 Barium mg/kg 210 14.2 15 248 205 263 -35 75-125 19 20 M1 Beryllium mg/kg 0.43 1.37 1.49 1.9 1.9 104 101 75-125 2 20 Boron mg/kg ND 142 150 127 135 89 90 75-125 7 20 Calcium mg/kg 1530 711 750 2370 2100 119 76 75-125 12 20 Chromium mg/kg 10.6 14.2 15 26.5 25.6 112 100 75-125 4 20 Copper mg/kg 84.1 14.2 15 102 87.6 127 23 75-125 15 20 M1 Iron mg/kg 23700 142 150 25600 21900 1360 -1150 75-125 15 20 M1 Magnesium mg/kg 6440 711 750 7920 6680 209 32 75-125 17 20 M1 Manganese mg/kg 168 14.2 15 160 139 -57 -192 75-125 14 20 M1 Molybdenum mg/kg ND 14.2 15 12.4 13.3 86 88 75-125 7 20 Nickel mg/kg 9.1 14.2 15 24.4 23.7 108 98 75-125 3 20 Potassium mg/kg 1970 711 750 2940 2660 138 92 75-125 10 20 M1 Sodium mg/kg 250J 711 750 1040 1050 111 106 75-125 1 20 Strontium mg/kg 23.2 14.2 15 45.6 36.4 158 88 75-125 22 20 M1,R1 Zinc mg/kg 41.3 71.1 75 120 117 111 101 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:14 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 43 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040128 Pace Project No.: 92244458 QC Batch: MPRP/23699 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92244458001, 92244458002, 92244458003, 92244458004, 92244458005 METHOD BLANK: 1188091 Matrix: Solid LCS Result Associated Lab Samples: 92244458001, 92244458002, 92244458003, 92244458004, 92244458005 mg/kg 2.5 2.6 Blank Reporting Arsenic Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 04/22/15 00:23 N2 Arsenic mg/kg ND 0.051 04/22/15 00:23 Cadmium mg/kg ND 0.0061 04/22/15 00:23 Cobalt mg/kg ND 0.051 04/22/15 00:23 Lead mg/kg ND 0.051 04/22/15 00:23 Selenium mg/kg ND 0.051 04/22/15 00:23 Thallium mg/kg ND 0.051 04/22/15 00:23 Vanadium mg/kg ND 0.051 04/22/15 00:23 Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1188092 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.6 103 80-120 N2 Arsenic mg/kg 2.5 2.6 105 80-120 Cadmium mg/kg .25 0.26 104 80-120 Cobalt mg/kg 2.5 2.7 106 80-120 Lead mg/kg 2.5 2.6 101 80-120 Selenium mg/kg 2.5 2.6 102 80-120 Thallium mg/kg 2.5 2.6 103 80-120 Vanadium mg/kg 2.5 2.7 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188093 1188094 MS MSD 92244973002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 3.61 3.61 ND ND 66 75 75-125 20 M6, N2 Arsenic mg/kg ND 3.61 3.61 5.3J 5.01 88 84 75-125 20 Cadmium mg/kg ND .361 .361 ND ND 88 80 75-125 20 Cobalt mg/kg 5.6J 3.61 3.61 11.7 10 167 122 75-125 16 20 M6 Lead mg/kg 6.7J 3.61 3.61 10.5 10.2 104 98 75-125 3 20 Selenium mg/kg ND 3.61 3.61 5.9J 4.9J 78 52 75-125 20 M6 Thallium mg/kg ND 3.61 3.61 4.2J 4.1J 90 90 75-125 20 Vanadium mg/kg 94.7 3.61 3.61 98.2 92.0 96 -76 75-125 7 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:14 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 43 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 1inlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040128 Pace Project No.: 92244458 QC Batch: PMST/3453 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92244458001, 92244458002, 92244458003, 92244458004, 92244458005 SAMPLE DUPLICATE: 1186463 35183573001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 32.5 38.8 18 10 D6 SAMPLE DUPLICATE: 1186496 35183605001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 83.8 83.0 1 10 SAMPLE DUPLICATE: 1186497 35183605002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 83.7 83.7 0 10 SAMPLE DUPLICATE: 1186498 35183608001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 95.2 94.8 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:14 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 43 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040128 Pace Project No.: 92244458 QC Batch: WET/36789 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92244458001, 92244458002, 92244458003, 92244458004, 92244458005 Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1432813 92244052001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 8.6 8.6 0 10 SAMPLE DUPLICATE: 1432814 92244371005 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.1 6.1 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:14 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 43 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040128 Pace Project No.: 92244458 QC Batch: WETA/45422 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92244458001, 92244458002, 92244458003, 92244458004, 92244458005 METHOD BLANK: 1183715 1183716 Matrix: Solid Units Associated Lab Samples: mg/kg Sulfate mg/kg Blank Reporting 1183718 Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.8 04/15/15 20:34 Sulfate mg/kg ND 49.8 04/15/15 20:34 LABORATORY CONTROL SAMPLE: 1183716 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1183718 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1183717 Parameter Chloride Sulfate Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 503 484 96 80-120 503 473 94 80-120 92245118001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 722 634 88 80-120 ND 722 649 90 80-120 92245118001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:14 PM without the written consent of Pace Analytical Services, Inc.. Page 35 of 43 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040128 Pace Project No.: 92244458 QC Batch: WETA/45423 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92244458001, 92244458002, 92244458003, 92244458004, 92244458005 METHOD BLANK: 1183719 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 04/15/15 20:34 LABORATORY CONTROL SAMPLE: 1183720 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50.3 48.1 96 80-120 MATRIX SPIKE SAMPLE: 1183722 92245118001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 72.2 64.5 89 80-120 H3 SAMPLE DUPLICATE: 1183721 92245118001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:14 PM without the written consent of Pace Analytical Services, Inc.. Page 36 of 43 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040128 Pace Project No.: 92244458 QC Batch: WETA/28164 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92244458001, 92244458002, 92244458003, 92244458004, 92244458005 METHOD BLANK: 1145576 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 04/24/15 05:56 LABORATORY CONTROL SAMPLE: 1145577 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 120000 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1145578 1145579 MS MSD 92244458001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 54700 110000 109000 160000 178000 96 114 50-150 11 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1145580 1145581 MS MSD 92244973001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg ND 6840 6900 6770 7070 94 98 50-150 4 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:14 PM without the written consent of Pace Analytical Services, Inc.. Page 37 of 43 aceAnaiXical www.pacelabs.com QUALIFIERS Project: J15040128 Pace Project No.: 92244458 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. Pace Analytical Services, Inc. 9800 %'8yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICPM/9630 [1] Batch was diluted due to the presence of high levels of non -target analytes or other matrix interference. Batch: ICP/14482 [1] Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:14 PM without the written consent of Pace Analytical Services, Inc.. Page 38 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, INC 28078 (704)875-9092 QUALIFIERS Project: J15040128 Pace Project No.: 92244458 ANALYTE QUALIFIERS R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:14 PM without the written consent of Pace Analytical Services, Inc.. Page 39 of 43 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, Inc. 9800 %'8yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040128 Pace Project No.: 92244458 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92244458001 2015009716 EPA 3050 MPRP/23698 EPA 6010 ICP/14482 92244458002 2015009724 EPA 3050 MPRP/23698 EPA 6010 ICP/14482 92244458003 2015009725 EPA 3050 MPRP/23698 EPA 6010 ICP/14482 92244458004 2015009726 EPA 3050 MPRP/23698 EPA 6010 ICP/14482 92244458005 2015009727 EPA 3050 MPRP/23698 EPA 6010 ICP/14482 92244458001 2015009716 EPA 3050 MPRP/23699 EPA 6020 ICPM/9630 92244458002 2015009724 EPA 3050 MPRP/23699 EPA 6020 ICPM/9630 92244458003 2015009725 EPA 3050 MPRP/23699 EPA 6020 ICPM/9630 92244458004 2015009726 EPA 3050 MPRP/23699 EPA 6020 ICPM/9630 92244458005 2015009727 EPA 3050 MPRP/23699 EPA 6020 ICPM/9630 92244458001 2015009716 EPA 7471 MERP/5605 EPA 7471 MERC/5593 92244458002 2015009724 EPA 7471 MERP/5605 EPA 7471 MERC/5593 92244458003 2015009725 EPA 7471 MERP/5605 EPA 7471 MERC/5593 92244458004 2015009726 EPA 7471 MERP/5605 EPA 7471 MERC/5593 92244458005 2015009727 EPA 7471 MERP/5605 EPA 7471 MERC/5593 92244458001 2015009716 ASTM D2974-87 PMST/3453 92244458002 2015009724 ASTM D2974-87 PMST/3453 92244458003 2015009725 ASTM D2974-87 PMST/3453 92244458004 2015009726 ASTM D2974-87 PMST/3453 92244458005 2015009727 ASTM D2974-87 PMST/3453 92244458001 2015009716 EPA 9045 WET/36789 92244458002 2015009724 EPA 9045 WET/36789 92244458003 2015009725 EPA 9045 WET/36789 92244458004 2015009726 EPA 9045 WET/36789 92244458005 2015009727 EPA 9045 WET/36789 92244458001 2015009716 EPA 9056 WETA/45422 92244458002 2015009724 EPA 9056 WETA/45422 92244458003 2015009725 EPA 9056 WETA/45422 92244458004 2015009726 EPA 9056 WETA/45422 92244458005 2015009727 EPA 9056 WETA/45422 92244458001 2015009716 EPA 9056 WETA/45423 92244458002 2015009724 EPA 9056 WETA/45423 92244458003 2015009725 EPA 9056 WETA/45423 92244458004 2015009726 EPA 9056 WETA/45423 92244458005 2015009727 EPA 9056 WETA/45423 92244458001 2015009716 EPA 9060 WETA/28164 92244458001 2015009716 EPA 9060 WETA/28165 92244458002 2015009724 EPA 9060 WETA/28164 92244458002 2015009724 EPA 9060 WETA/28165 92244458003 2015009725 EPA 9060 WETA/28164 92244458003 2015009725 EPA 9060 WETA/28165 92244458004 2015009726 EPA 9060 WETA/28164 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:14 PM without the written consent of Pace Analytical Services, Inc.. Page 40 of 43 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15040128 Pace Project No.: 92244458 Lab ID Sample ID QC Batch Method QC Batch 92244458004 2015009726 EPA 9060 WETA/28165 92244458005 2015009727 EPA 9060 WETA/28164 92244458005 2015009727 EPA 9060 WETA/28165 Date: 04/27/2015 04:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 %'8yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical Method Analytical Batch Page 41 of 43 Document Name: vocument Kevisea: aeptemruei tz. zu i-+ �CeAn��)ftal' Sample Condition Upon Receipt SCUR Pae 1 of 2 Document Number: Issuing AuthorAyof 67 F-CHR-CS-003-rev.15 Pace Huntersville Quality Office Client dame: ^ ��- l Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑ C Custody Seal on Cooler/Box Present: ❑ ye no :rcial❑ Pher Seals intact: ❑yes ❑ no Packing 'Material: ❑ Bubble 1❑p [Bubble Bags ❑ None ❑ Other Thermometer Used: IR Gun 14Q1 Type of Ice: Jlbff!>.,Blue None amples on ice, cooling process has begun Temp Correction Factor 4401 No Correction �� i_S Biological Tissue is Frozen: Yes No ^ D e and Initials of par n examining Corrected Cooler Temp.: 'C g contents:_ Tem[) should be above freezing to 6'C Comments: Chain of Custody Present: es ❑ ®NIA 1. Chain of Custody Filled Out: es ❑ o ❑NIA 2. Chain of Custody Relinquished: es PNo EIN/A 3. Sampler Name & Signature on COC: es ❑ ❑N1A 4. Samples Arrived within Hold Time: s ❑No A 5. Short Hold Time Analysis (<72hr): ❑Yes o ❑ W6. Rush Turn Around Time Requested: ©Yes o ❑N1A 17. Sufficient Volume: es o ❑N/A 8, Correct Containers Used: -Pace Containers Used: E5Yes ❑Yes ;E]N. IA ❑NIA 9. Containers Intact: 131e. ❑No EJ N/A 1 . Filtered volume received for Dissolved tests ❑Yes ❑N -- ❑!A 11. Sample Labels match COC: e- ❑No ❑NIA -Includes date/time/ID/Analysis Matrix: 12. All containers needing preservation have been checked. All containers needing preservation are found to be in compliance with EPA recommendation. exceptions: VOA, coliform, TOC, O&G, WI -DRO (water) ❑Yes ❑Yes ❑Yes ❑No Q IA ❑No 0 NIA L�No 13 Samples checked for dechlorination: ❑Yes ❑No DI lA Headspace in VOA Vials (>6mm): ❑Yes ❑No N_ 5. Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased): ❑Yes Ores ❑No ❑No 6! ❑NIA 16. Client Notification/ Resolution: Field Data Required? Y f N Person Contacted: Date/Time: Comments/ Resolution: SCURF Review: 1 - LG Date: ` / /t (' SRF Review: 6d Dake: I yl—CL�j Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( 1.e out of hold, incorrect preservative, out of temp, incorrect containers) WO#92244458 1111111111111111111111 Page 42 of 43 51 of 67 t i >i Y y 1 C0 O r!! im 5 w e LOl R ow9 n O a'i yq�a� SIC a n n m 0 i I N N 6 I z mA-.. ao !D 0 10 $ IITI R i o I C 1W Z . t � 0o _ c M CD CJ m° T r D j i z ! �, ITI 0 :3rD n � � n N .. 3� CusSamer to complate appropriaRe .Solumns to rhl � 0 D N c o IL+n G r a E t a � A -G. �r m A G � C V u o Ole M CU l I_ a e M zrD F o "Grab CL fl u m v Total Metals , 1 7 a O 1�8 <• A IN z t i N a C r6 � rr C a' N _ O 51 of 67 t i >i Y y 1 C0 O r!! im 5 w e LOl R ow9 n O a'i yq�a� SIC a n n m 0 i I N N 6 I z mA-.. ao !D 0 10 $ IITI R i o I C 1W Z . m r 0o n c M a O 3 > T r D j i o a �+ ! �, ITI 0 :3rD n � � n N .. 3� w 0 o IL+n G r i D a � A -G. a � G � o Ole N I_ 51 of 67 t i >i Y y 1 C0 O r!! im 5 w e LOl R ow9 n O a'i yq�a� SIC a n n m 0 i I N N 6 I z mA-.. ao !D 0 10 $ IITI R i o I C 1W 0o n c M a O 3 > T r r,> i o a �+ ! �, ITI 0 :3rD � � n N w 0 o NO D a � A -G. rln � G S o Ole N I_ Y Q 00 10A lyl3 8 F o "Grab CL fl u m v Total Metals , CL 51 of 67 t i >i Y y 1 C0 O r!! im 5 w e LOl R ow9 n O a'i yq�a� SIC a n n m 0 i I N N 6 I z mA-.. ao !D 0 10 $ IITI R i o I C 1W 0o n c M roIn O 3 > T r r,> i o a �+ ! �, ITI 0 :3rD � � n f � w 0 o NO D a � V1 -G. rln � S o Ole C Y Q 00 10A lyl3 8 F o "Grab Req Ire 'n 9 Anions, q- fl u m v Total Metals , D W 7 a O 1�8 <• A K >T I '� N a C r6 N Y � jl ro 0 Y N n c o° 10 y 2. — c n C T n M 0 o R R c 's C c M n O V •a Y a Y 0 O n 51 of 67 t i >i Y y 1 C0 O r!! im 5 w e LOl R ow9 n O a'i yq�a� SIC a n n m 0 i I N N 6 I z mA-.. ao !D 0 10 $ IITI R i o I C 1W - oz Jar (PACE) TOC 1-4ozjar (PACE) SPLP - Total Metals and Anions 2 - 8 oz jars (PACE) Sediment specific tests 2 - 8 oz jar (ACCESS ANALYTICAL) 20Total # of Containers 61 i-V ;m oiQ Z die p c C I M ro±CO o ! yN �i—'I 3r F T R — i � f0 fl 3 i� i I i a i a j m i I 010 I i I^ o Ci pain Z z rA �Q c o z O n z a �' n O V,�� Page 43 i5f 43 CL 3 Z (D D M roIn O 3 > T r r,> i o a �+ ! �, ITI 0 :3rD � � n w 0 NO a O y G V1 -G. L S m Ole I i� 'rComp. 10A lyl3 8 "Grab Req Ire 'n 9 Anions, q- i. a (n P �� R , ; „ I (n Total Metals , I 1�8 5 >T I - oz Jar (PACE) TOC 1-4ozjar (PACE) SPLP - Total Metals and Anions 2 - 8 oz jars (PACE) Sediment specific tests 2 - 8 oz jar (ACCESS ANALYTICAL) 20Total # of Containers 61 i-V ;m oiQ Z die p c C I M ro±CO o ! yN �i—'I 3r F T R — i � f0 fl 3 i� i I i a i a j m i I 010 I i I^ o Ci pain Z z rA �Q c o z O n z a �' n O V,�� Page 43 i5f 43 ACCESS ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Duke Energy 13339 Hagers Ferry Rd. Huntersville NC 28078 ATTENTION Marge Galvin -Karr PROJECT ID J15040128 LABORATORY REPORT NUMBER 1504946 DATE April 28, 2015 Primary Data Review By Secondary Data Review By Ashley Amick Chantelle Kanhai Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com PLEASE NOTE: 52 of 67 - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL -E87582, NELAP certified laboratory # E87582 - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 9 /r/ 1�,�( CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM i ��i\E An- - --Iimbarotery Be ykn ._......... .......... ._...._....._._-AaAlvi" i eoai .._ Lhw pl,. _.__ _._._._ _,_ . _ __ - . SVN7ERRA E00 �j , ENERGY.. >,�1 i�15 SOIL �- as�ld�r�t ,I41MnwIM. N. C. !f(17t Irt. .. _ w"N•!.Qy!+•�!.tfw. -.. _. INI K.'INAL to IF$, r �t s.3»•_._._ _ _ Fx Y 3 ! 5 Yo 3i COM a CLILINT ' AL GmundwaNr AtthslMnl •Sop Access Analytl cal f . L' .� a h,hs+fAo . -. PO Number 1142057 1 ,wv.t• �j%►'��"'4t As ON PACE PO 1142081 1t W . 1F�..:•MKNF.A404re�na. Mw^N41.I�4•+II .nd.. lv*I In r.41M1 .os.. 1'•rl«+v:ll:. n*. 4Aan uand n�rll tN – wt n../ tlN MVM j 11 CAIN 4MIT{I MIn4Mlti Irl 4111 kw.l�lp nw..r.w,.., el ntlllat♦ wlll ..lr 1# "".I- A,",I& I•.v.r>.Iv.lrs.l r• �.. r n t,..p lh•.Msli] c�.nl<:wn N`�I �,u 0. 1 wlrw olr.v N�� "C_ralloo'. n InfomWloN , 0 1 U 4� p g� yy .� t..lo nw•A.a...t�re I�Ssmplo,DoseMpUonort0 8.0. I 111— a-,,,.,.. I F� tl 0 s ,y: A6 W AY, 06. 110, ", CA, CA. Ca, Co, CIA. Ff. (h brW d. tY PAWN. SOA UON.eet l"C". NO V , R 0 egUovwd illta/fal•nll 7 AAy. 1e 1• 53 of1, DY t Ye Olt /� /D - tr e2of9 Analytical Environmental Services, Inc Date: 28 -Apr -1554 of 67 Client: Duke Energy Project: J15040128 Case Narrative Lab ID: 1504946 REDOX POTENTIAL: 1504946-001 100.6 mV 82.0 mV 66.2 mV 1504946-002 94.7 mV 99.0 mV 90.8 mV 1504946-003 36.2 mV 24.0 mV 38.8 mV 1504946-004 27.4 mV 22.6 mV 37.9 mV 1504946-005 35.9 mV 39.3 mV 37.0 mV LCS TRUE VALUE: 240mV LCS: 252.4 mV 105.16% Recovery Page 3 of 9 Analytical Environmental Services, Inc Date: 28 -Apr -15 55 of 67 Client: Duke Energy Client Sample ID: K-01 Project Name: J15040128 Collection Date: 4/6/2015 11:45:00 AM Lab ID: 1504946-001 Matrix: Soil Reporting Dilution Analyses Result Qual Units BatchID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: x Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 18 1.0 meq/100g 205884 1 04/16/2015 23:06 JL E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 4 of 9 Analytical Environmental Services, Inc Date: 28 -Apr -15 1ONX:Y� Client: Duke Energy Client Sample ID: M-01 Project Name: J15040128 Collection Date: 4/6/2015 12:15:00 PM Lab ID: 1504946-002 Matrix: Soil Reporting Dilution Analyses Result Qual Units BatchID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: z Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 3.5 1.0 meq/100g 205884 1 04/16/2015 23:10 JL E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 5 of 9 Analytical Environmental Services, Inc Date: 28 -Apr -15 57 of 67 Client: Duke Energy Client Sample ID: SW -05 Project Name: J15040128 Collection Date: 4/6/2015 2:17:00 PM Lab ID: 1504946-003 Matrix: Soil Reporting Dilution Analyses Result Qual Units BatchID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: z Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 1.4 1.0 meq/100g 205884 1 04/16/2015 23:13 JL E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 6 of 9 Analytical Environmental Services, Inc Date: 28 -Apr -15 A:rOX:Y� Client: Duke Energy Client Sample ID: SW -05 DUP Project Name: J15040128 Collection Date: 4/6/2015 2:20:00 PM Lab ID: 1504946-004 Matrix: Soil Reporting Dilution Analyses Result Qual Units BatchID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: s Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) BRL 1.0 meq/100g 205884 1 04/16/2015 22:34 JL E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 7 of 9 Analytical Environmental Services, Inc Date: 28 -Apr -15 1-M-M Client: Duke Energy Client Sample ID: C-02 Project Name: J15040128 Collection Date: 4/6/2015 1:15:00 PM Lab ID: 1504946-005 Matrix: Soil Reporting Dilution Analyses Result Qual Units BatchID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: z Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 11 1.0 meq/100g 205884 1 04/16/2015 23:17 JL E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 8 of 9 11.11 S .N Analytical Environmental Services, Inc. Sample/Cooler Receipt Checklist Client k� Work Order Number / .5-o y / Adjusted? Sample Condition: Good ✓ Other(Explain) (For diffusive samples or AIHA lead) Is a known blank included? See Case Narrative for resolution of the Non -Conformance. Checked by Not Present Not Present Not Present Cooler#5 Cooler #6 Not Applicable No Not Applicable Yes No ' Samples do not have to comply with the given range for certain parameters \\Aes_server\I\Sample Receipt\My Documents\COCs and pH Adjustment Sheet\Sample_Cooler_Recipt_Checklist_Revl.rtf Page 9 of 9 lt7 Checklist completed by lj Signature Date Carrier name: FedEx -,—//UPS _ Courier _ Client _ US Mail _ Other Shipping container/cooler in good condition? Yes No _ Custody seals intact on shipping container/cooler? Yes _ No Custody seals intact on sample bottles? Yes _ No Container/Temp Blank temperature in compliance? (0°:56°C* Yes No Cooler # l ' --5 Cooler #? Cooler #3 Cooler #4 Chain of custody present? Yes ✓ No Chain of custody signed when relinquished and received? Yes 1l No Chain of custody agrees with sample labels? Yes �l No Samples in proper container/bottle? Yes f/ No Sample containers intact? Yes✓ No Sufficient sample volume for indicated test? Yes ✓/ No All samples received within holding time? Yes No _ Was TAT marked on the COC? .� Yes No Proceed with Standard TAT as per project history? Yes _ No Water - VOA vials have zero headspace? No VOA / vials submitted ✓ Yes Water - pH acceptable upon receipt? Yes _ No / Adjusted? Sample Condition: Good ✓ Other(Explain) (For diffusive samples or AIHA lead) Is a known blank included? See Case Narrative for resolution of the Non -Conformance. Checked by Not Present Not Present Not Present Cooler#5 Cooler #6 Not Applicable No Not Applicable Yes No ' Samples do not have to comply with the given range for certain parameters \\Aes_server\I\Sample Receipt\My Documents\COCs and pH Adjustment Sheet\Sample_Cooler_Recipt_Checklist_Revl.rtf Page 9 of 9 April 22, 2015 Access Analytical 7478 Carlisle Street Irmo, South Carolina 29063 Attn: Mr. Ashley Amick Re: Summary of Laboratory Testing AB Groundwater Assessment Terracon Project No. 73075016 (WOJ15040128) Dear Mr. Amick: 61 of 67 Irerracon Terracon has performed the requested laboratory testing program indicated by your Chain of Custody Record, dated 04/18/15. The correspondence indicated hydrometer testing for Samples K-08, M-01, SW -05, SW-05DUP, and C-02. The results have been electronically forwarded to you in PDF format at aamick@accessanalyticalinc.com, as instructed. If there are any questions regarding the results or if we can be of additional service, please contact us. Sincerely, Terracon Consultants, Inc. Rebecca Simms, CET Laboratory Manager Attachments Copies: 1xc: Above (PDF via email) 1xc: File lZ63Mdil Phillip A. Morrison, P.E. Geotechnical Department Manager Terracon Consultants, Inc. 521 Clemson Road Columbia, South Carolina 29229 P [803] 741 9000 F [803] 741 9900 terracon.com 100 95 90 85 80 75 70 65 H 2 60 w >- 55 m ry Z 50 LL z 45 w 40 w CL 35 30 25 20 15 10 5 0 GRAIN SIZE DISTRIBUTION 62 of 67 ASTM D422 U.S. SIEVE OPENING IN INCHES I U.S. SIEVE NUMBERS I HYDROMETER a 4 z 2 9 r 1 qid 1/2z/Q 3 d 6 A10 1416 qn 30 do 50 an 1001Ar, 200 100 10 1 0.1 GRAIN SIZE IN MILLIMETERS 0.01 0.001 I COBBLES GRAVEL SAND SILT OR CLAY i coarse I fine coarse I medium I fine Boring ID Depth AASHTO Classification LL PL PI Cc Cu • C-02 0 () 6.49 612.07 Boring ID Depthl D,00 D60 D30 D10 -/.Gravel %Sand %Silt I %Clay 1 • C-02 0 25 3.03 0.312 0.005 35.0 47.9 7.0 10.0 PROJECT: AB GW Assessment - Asheville Sediment PROJECT NUMBER: 73075016 SITE: Asheville, North Carolina 1 rerracon CLIENT: Access Analytial 521 Clemson Road Columbia, South Carolina 100 95 90 85 80 75 70 65 T 60 w >- 55 M Z 50 LL z 45 LU ry 40 LU o_ 35 30 25 20 15 10 5 0 GRAIN SIZE DISTRIBUTION 63 of 67 ASTM D422 U.S. SIEVE OPENING IN INCHES U.S. SIEVE NUMBERS I HYDROMETER A 7 i i/7 Z F in I 4n 1;n inn )nn Ur ■II111�■■ullYl®■�1■■IY111®■■■■II 100 10 1 0.1 GRAIN SIZE IN MILLIMETERS 0.01 J 0.001 COBBLES GRAVEL SAND SILT OR CLAY coarse I fine coarse medium I fine Boring ID Depth AASHTO Classification LL PL PI Cc Cu • K-01 0 Q 2.12 63.66 Boring ID Depthl D,00 D60 D30 D,0 %Gravel %Sand °/oSilt I %Clay 1 • K-01 0 19 0.165 0.03 0.003 7.9 46.2 31.6 14.4 PROJECT: AB GW Assessment - Asheville Sediment PROJECT NUMBER: 73075016 SITE: Asheville, North Carolina Irerracon CLIENT: Access Analytial 521 Clemson Road Columbia, South Carolina 100 95 90 85 80 75 70 65 T 60 w >- 55 M Z 50 LL z 45 LU ry 40 LU o_ 35 30 25 20 15 10 5 0 GRAIN SIZE DISTRIBUTION 64 of 67 ASTM D422 U.S. SIEVE OPENING IN INCHES U.S. SIEVE NUMBERS I HYDROMETER A 7 i i/7 Z F in I 4n 1;n inn )nn ■IIIII�I�■■�IIIII®■�1■■IIIII®■■■■II 100 10 1 0.1 GRAIN SIZE IN MILLIMETERS 0.01 0.001 I COBBLES GRAVEL SAND SILT OR CLAY i coarse I fine coarse medium I fine Boring ID Depth AASHTO Classification LL PL PI Cc Cu • M-01 0 Q 4.27 132.85 Boring ID Depthl D,00 D60 D30 D,0 %Gravel %Sand °/oSilt I %Clay W • M-01 0 37.5 1.953 0.35 0.015 25.2 62.9 3.4 8.5 PROJECT: AB GW Assessment - Asheville Sediment PROJECT NUMBER: 73075016 SITE: Asheville, North Carolina Irerracon CLIENT: Access Analytial 521 Clemson Road Columbia, South Carolina 95 90 85 80 75 70 65 T 60 w >- 55 M Z 50 LL z 45 LU ry 40 LU o_ 35 30 25 20 15 10 5 0 GRAIN SIZE DISTRIBUTION ASTM D422 U.S. SIEVE OPENING IN INCHES I U.S. SIEVE NUMBERS I HYDROMETER 6 4 3 z 1.5 1 3/4 uz s 4 b 8_iu 14 ib 20 su 40 ou 60 1uu140zuu 100 10 1 0.1 GRAIN SIZE IN MILLIMETERS 0.01 65 of 67 J 0.001 COBBLES GRAVEL SAND SILT OR CLAY coarse I fine coarse medium I fine Boring ID Depth AASHTO Classification LL PL PI Cc Cu • SW -05 0 Q Boring ID Depthl D,00 D60 D30 D,0 %Gravel %Sand °/oSilt I %Clay W• SW -05 0 9.5 0.424 0.067 1.2 67.9 16.0 15.0 PROJECT: AB GW Assessment - Asheville Sediment PROJECT NUMBER: 73075016 SITE: Asheville, North Carolina Irerracon CLIENT: Access Analytial 521 Clemson Road Columbia, South Carolina 100 95 90 85 80 75 70 65 T 60 w >- 55 M Z 50 LL z 45 LU ry 40 LU o_ 35 30 25 20 15 10 5 0 GRAIN SIZE DISTRIBUTION 66 of 67 ASTM D422 U.S. SIEVE OPENING IN INCHES U.S. SIEVE NUMBERS I HYDROMETER A 7 i i/7 Z F in I 4n 1;n inn )nn U 1.0 4 3/i5 4 0 14 N 4U bU 14U 100 10 1 0.1 GRAIN SIZE IN MILLIMETERS 0.01 J 0.001 COBBLES GRAVEL SAND SILT OR CLAY coarse I fine coarse medium I fine Boring ID Depth AASHTO Classification LL PL PI Cc Cu • SW -05 DUP 0 Q 10.77 212.90 Boring ID Depthl D,00 D60 D30 D,0 %Gravel %Sand %Silt %Clay I• SW -05 DUP 0 19 1.499 0.337 0.007 14.3 69.2 8.1 8.4 PROJECT: AB GW Assessment - Asheville Sediment PROJECT NUMBER: 73075016 SITE: Asheville, North Carolina Irerracon CLIENT: Access Analytial 521 Clemson Road Columbia, South Carolina E E t ('DUKE ENERGY.. CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM _ - - - " Analytical Laboratory Services - ; _._._._._._.-,_,_-_._._._._-_-_._.-•-Analytical Laboratory Use Only Mail Code MG63A2 (Building 7405) i i Work order Matrix: SOIL g Ferry 13339 Ha ers Fer Rd Samples Originating From Huntersvine, N. C. 28078 i il.oy0ed By Date a rima (980) 875-5245 i Dr— V. -- -I '; SYNTERRA EDD SC sc� ; DISTRIBUTION 67 of 67 oH_ ORIGINAL to LAB, ` COPY to CLIENT i Fa)u. 980 8757349 i SAMPLE PROGRAM Ground Water_ NPDES_ Other_ Plant 1)Project Name AB Groundwater Assessment - Soil Asheville 21Phone No. 69-5( $)CIhM YiE�, AS GW 4jFax No: jBualnass unit: 6)Project ID: 7)Nell core: &) operating Unit: 91Activitp to: �- 10)Preceas ID DweiTime� IMpj2=: When specific accounting has been established and is not indicated above we need the following: 1) Enter correct accounting in all 5 accounting fields above, or Pra;vilc : Orn:cl aceouiiting for Operating unit and Procea-, ID. � ...l.As USE ONLY ! Matrix i "Lab ID ! (Soil, Sedinterrt, Ashj `"Sample DeSCriotion or ID /0 -G( LJ -US EQUIPMENT BLANK 0 PER Access Analytical !;LP V -e ry- y� Accepteaey uafari Requested Turnaround Ret. uis By r) � • V DweiTime� Accepled By. 6LZeDatelY t9 e i�!(,+/� I r PO Number 1142057 Gaoler Tem C Relinquished By - DateiTime Accept Datesfrime - SealediLackcd By Datel7ime Saaledfl-o& opened By Datelnme -48 Hr 241Commetria Metals: Al, Sb, As, Ba, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Na, Sr, TI, V, Zn, Mercury, pH Anions: Cl, Nitrate -N, SO4 Sediment Specific Parameters: °/ Solids, CEC, Particle Size Distribution, Redox Potential - serJ-1 PACE 'O` u7 PO 1142081 _ Q @ .� lt.l ?s- EW.i c Preservatives when used must be d 2. 14 Q Q added within 16 minutes of sample � � V) � URr at collection C — 4Collection Information W a 00U �_ r Q. . G N Gli Q a hY- 9 o -.1 . z 03Date - A°2 n c°t C7 Signature ( I f 21)R had V -e ry- y� Accepteaey uafari Requested Turnaround Ret. uis By r) � • V DweiTime� Accepled By. 6LZeDatelY t9 e i�!(,+/� I r 14 Days x� Relinquished By - DateiTime Accept Datesfrime •7 Days SealediLackcd By Datel7ime Saaledfl-o& opened By Datelnme -48 Hr 241Commetria Metals: Al, Sb, As, Ba, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Na, Sr, TI, V, Zn, Mercury, pH Anions: Cl, Nitrate -N, SO4 Sediment Specific Parameters: °/ Solids, CEC, Particle Size Distribution, Redox Potential