NC0000396_J15030693 Report_20150823

DUE Analytical Laboratory Page 1 of 118
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
J15030693
ASHEVILLE - AB GW ASSESSMENT SOIL
Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker
200 CP and L Drive
Arden,NC 28704
Margaret Galvin -Karr Phone: [phone]
Margaret Galvin -Karr
MXG4644(101161)
2015.05.13 15:31:05 -04,00, Date:
Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report.
Data Flags & Calculations:
5/5/2015
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Page 2 of 118
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2015008641
ASHEVILLE
24 -Mar -15 8:20 AM
illegible
Equipment Blank
2015008642
ASHEVILLE
24 -Mar -15 11:25 AM
illegible
ABMW-06 (5-7)
2015008643
ASHEVILLE
24 -Mar -15 11:45 AM
illegible
ABMW-06 (13-14)
2015008644
ASHEVILLE
25 -Mar -15 10:35 AM
illegible
Equipment Blank
2015008645
ASHEVILLE
25 -Mar -15 11:15 AM
illegible
MW -03 SB (1-2)
2015008646
ASHEVILLE
25 -Mar -15 2:35 PM
illegible
MW -03 SB (20-22)
2015008647
ASHEVILLE
25 -Mar -15 2:40 PM
illegible
MW -03 SB (28-30)
2015008648
ASHEVILLE
25 -Mar -15 12:55 PM
illegible
AB -10 SB (6-7)
2015008649
ASHEVILLE
25 -Mar -15 1:05 PM
illegible
AB -10 SB (14-15)
2015008650
ASHEVILLE
25 -Mar -15 1:10 PM
illegible
AB -10 SB ASH
2015008651
ASHEVILLE
25 -Mar -15 3:40 PM
illegible
ABMW-05 SB (2-3)
2015008652
ASHEVILLE
25 -Mar -15 3:50 PM
illegible
ABMW-05 SB (25-27)
2015008653
ASHEVILLE
25 -Mar -15 4:00 PM
illegible
ABMW-05 SB (36.5-37)
2015008654
ASHEVILLE
25 -Mar -15 4:05 PM
illegible
ABMW-05 SB (12-13)
14 Total Samples

Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes No
All laboratory QA/QC requirements are acceptable. (] Yes ❑ No
Report Sections Included:
LU Job Summary Report
❑ Sample Identification
P/1 Technical Validation of Data Package
J❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Page 3 of 118
L-1 Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
d❑ Chain of Custody
LVI Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 5/5/2015

Certificate of Laboratory Analysis Page 4 of 118
This report shall not be reproduced, except in full.
Order # J15030693
Site: Equipment Blank
Collection Date: 24 -Mar -15 8:20 AM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015008641
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030693
Site: ABMW-06 (5-7)
Collection Date: 24 -Mar -15 11:25 AM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 5 of 118
Sample #: 2015008642
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030693
Site: ABMW-06 (13-14)
Collection Date: 24 -Mar -15 11:45 AM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 6 of 118
Sample #: 2015008643
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030693
Site: Equipment Blank
Collection Date: 25 -Mar -15 10:35 AM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015008644
Matrix: SOIL
Page 7 of 118
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030693
Site: MW -03 SB (1-2)
Collection Date: 25 -Mar -15 11:15 AM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 8 of 118
Sample #: 2015008645
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030693
Site: MW -03 SB (20-22)
Collection Date: 25 -Mar -15 2:35 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 9 of 118
Sample #: 2015008646
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030693
Site: MW -03 SB (28-30)
Collection Date: 25 -Mar -15 2:40 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 10 of 118
Sample #: 2015008647
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030693
Site: AB -10 SB (6-7)
Collection Date: 25 -Mar -15 12:55 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 11 of 118
Sample #: 2015008648
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030693
Site: AB -10 SB (14-15)
Collection Date: 25 -Mar -15 1:05 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 12 of 118
Sample #: 2015008649
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030693
Site: AB -10 SB ASH
Collection Date: 25 -Mar -15 1:10 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 13 of 118
Sample #: 2015008650
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030693
Site: ABMW-05 SB (2-3)
Collection Date: 25 -Mar -15 3:40 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 14 of 118
Sample #: 2015008651
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030693
Site: ABMW-05 SB (25-27)
Collection Date: 25 -Mar -15 3:50 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 15 of 118
Sample #: 2015008652
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030693
Site: ABMW-05 SB (36.5-37)
Collection Date: 25 -Mar -15 4:00 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 16 of 118
Sample #: 2015008653
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030693
Site: ABMW-05 SB (12-13)
Collection Date: 25 -Mar -15 4:05 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 17 of 118
Sample #: 2015008654
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

aceAnaiXical
www.pacelabs.com
April 29, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
RE: Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
Pggoi�weytie. Suite 100
y Huntersville, INC 28078
[phone]
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on March 27, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Marge Galvin -Karr, Duke Energy
Program Manager, Duke Energy
Rodney Wilke, Duke Energy
HiQ p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
y without the written consent of Pace Analytical Services, Inc.. Page 1 of 100

lacmnalyfica(
www.pacelabs.com
Project: J15030693
Pace Project No.: 92243093
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A21 -A Certification #: 2926.01
Alaska Certification #: UST -078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ -0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH -0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH -0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Green Bay Certification IDs
1241 Bellevue Street, Green Bay, WI 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Pace Analytical Services, Inc.
pR8R01gr6fy.11ge. Suite 100
Huntersville, NC 28078
[phone]
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN -002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Montana Certification #: Cert 0074
Nebraska Certification: NE -OS -28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New Jersey Certification #: FL765
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Washington Certification #: C955
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Dakota Certification #: R-150
South Carolina Certification #: 83006001
Texas Certification #: T104704529-14-1
US Dept of Agriculture #: S-76505
Wisconsin Certification #: 405132750
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 100

aceAnaiXical
www.pacelabs.com
Project: J15030693
Pace Project No.: 92243093
Asheville Certification IDs
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
CERTIFICATIONS
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
P3S�Ozlbirfyte. Suite 100
y Huntersville, NC 28078
[phone]
Page 3 of 100

aceAnaiXical
www.pacelabs.com
SAMPLE SUMMARY
Project: J15030693
Pace Project No.: 92243093
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92243093001
2015008641
Water
03/24/15 08:20
03/27/1515:48
92243093002
2015008644
Water
03/25/1510:35
03/27/1515:48
92243093003
2015008642 SPLP
Water
03/24/15 11:25
03/27/15 15:48
92243093004
2015008643 SPLP
Water
03/24/15 11:45
03/27/15 15:48
92243093005
2015008648 SPLP
Water
03/25/15 12:55
03/27/15 15:48
92243093006
2015008651 SPLP
Water
03/25/15 15:40
03/27/15 15:48
92243093007
2015008642
Solid
03/24/1511:25
03/27/1515:48
92243093008
2015008643
Solid
03/24/1511:45
03/27/1515:48
92243093009
2015008648
Solid
03/25/1512:55
03/27/1515:48
92243093010
2015008651
Solid
03/25/1515:40
03/27/1515:48
92243093011
2015008645
Solid
03/25/1511:15
03/27/1515:48
92243093012
2015008646
Solid
03/25/1514:35
03/27/1515:48
92243093013
2015008647
Solid
03/25/1514:40
03/27/1515:48
92243093014
2015008649
Solid
03/25/1513:05
03/27/1515:48
92243093015
2015008650
Solid
03/25/1513:10
03/27/1515:48
92243093016
2015008652
Solid
03/25/1515:50
03/27/1515:48
92243093017
2015008653
Solid
03/25/1516:00
03/27/1515:48
92243093018
2015008654
Solid
03/25/1516:05
03/27/1515:48
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
Pggc0 Sirpyt.. Suite 100
y Huntersville, NC 28078
[phone]
Page 4 of 100

aceAnaiXical
www.pacelabs.com
SAMPLE ANALYTE COUNT
Pace Analytical Services, Inc.
P360916fyte. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
J15030693
92243093
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92243093001
2015008641
EPA 6020A
TT3
24
PASI-M
EPA 7470
LMW
1
PASI-M
92243093002
2015008644
EPA 6020A
TT3
24
PASI-M
EPA 7470
LMW
1
PASI-M
92243093003
2015008642 SPLP
EPA 6020A
RJS
24
PASI-M
EPA 7470
JDD
1
PASI-M
92243093004
2015008643 SPLP
EPA 6020A
RJS
24
PASI-M
EPA 7470
JDD
1
PASI-M
92243093005
2015008648 SPLP
EPA 6020A
RJS
24
PASI-M
EPA 7470
JDD
1
PASI-M
92243093006
2015008651 SPLP
EPA 6020A
RJS
24
PASI-M
EPA 7470
JDD
1
PASI-M
92243093007
2015008642
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
CRT
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500 -CI -E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92243093008
2015008643
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
CRT
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500 -CI -E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92243093009
2015008648
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 5 of 100

aceAnaiXical
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SAMPLE ANALYTE COUNT
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
PA OzS'Wyte. Suite 100
y Huntersville, NC 28078
[phone]
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
ASTM D2974-87
CRT
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500 -CI -E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92243093010
2015008651
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
CRT
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500 -CI -E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92243093011
2015008645
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
CRT
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92243093012
2015008646
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
CRT
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92243093013
2015008647
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 6 of 100

aceAnaiXical
www.pacelabs.com
SAMPLE ANALYTE COUNT
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
PARGA Wyte. Suite 100
y Huntersville, NC 28078
[phone]
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
CRT
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92243093014
2015008649
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
CRT
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92243093015
2015008650
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
CRT
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92243093016
2015008652
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
CRT
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92243093017
2015008653
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
CRT
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 7 of 100

aceAnaiXical
www.pacelabs.com
SAMPLE ANALYTE COUNT
Pace Analytical Services, Inc.
PARGArwyte. Suite 100
y Huntersville, NC 28078
[phone]
Project:
J15030693
Pace Project No.:
92243093
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
EPA 9060
TJJ
6
PASI-G
92243093018
2015008654
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
CRT
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 8 of 100

aceAnaiXical
www.pacelabs.com
Project: J15030693
Pace Project No.: 92243093
Lab Sample ID Client Sample ID
Method Parameters
Pace Analytical Services, Inc.
PAROAlwytie. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92243093001
2015008641
EPA 6020A
Aluminum
144
ug/L
10.0
04/02/15 19:20
EPA 6020A
Barium
2.3
ug/L
0.30
04/02/15 19:20
EPA 6020A
Calcium
216
ug/L
40.0
04/02/15 19:20
EPA 6020A
Chromium
1.5
ug/L
0.50
04/02/15 19:20
EPA 6020A
Cobalt
2.4
ug/L
0.50
04/02/15 19:20
EPA 6020A
Iron
426
ug/L
50.0
04/02/15 19:20
EPA 6020A
Lead
0.14
ug/L
0.10
04/02/15 19:20
EPA 6020A
Magnesium
67.4
ug/L
10.0
04/02/15 19:20
EPA 6020A
Manganese
6.5
ug/L
0.50
04/02/15 19:20
EPA 6020A
Potassium
165
ug/L
50.0
04/02/15 19:20
EPA 6020A
Zinc
8.9
ug/L
5.0
04/02/15 19:20
92243093002
2015008644
EPA 6020A
Aluminum
1010
ug/L
10.0
04/02/15 19:22
EPA 6020A
Barium
6.5
ug/L
0.30
04/02/15 19:22
EPA 6020A
Calcium
933
ug/L
40.0
04/02/15 19:22
EPA 6020A
Chromium
3.1
ug/L
0.50
04/02/15 19:22
EPA 6020A
Cobalt
1.2
ug/L
0.50
04/02/15 19:22
EPA 6020A
Iron
1720
ug/L
50.0
04/02/15 19:22
EPA 6020A
Lead
0.25
ug/L
0.10
04/02/15 19:22
EPA 6020A
Magnesium
486
ug/L
10.0
04/02/15 19:22
EPA 6020A
Manganese
21.2
ug/L
0.50
04/02/15 19:22
EPA 6020A
Molybdenum
0.84
ug/L
0.50
04/02/15 19:22
EPA 6020A
Nickel
1.1
ug/L
0.50
04/02/15 19:22
EPA 6020A
Potassium
679
ug/L
50.0
04/02/15 19:22
EPA 6020A
Sodium
244
ug/L
50.0
04/02/15 19:22
EPA 6020A
Strontium
2.8
ug/L
0.50
04/02/15 19:22
EPA 6020A
Vanadium
1.4
ug/L
1.0
04/02/15 19:22
EPA 6020A
Zinc
7.4
ug/L
5.0
04/02/15 19:22
92243093003
2015008642 SPLP
EPA 6020A
Barium
98.4
ug/L
0.30
04/17/15 18:17
EPA 6020A
Boron
65.5
ug/L
25.0
04/20/15 15:13
EPA 6020A
Calcium
811
ug/L
40.0
04/17/15 18:17
EPA 6020A
Cobalt
0.93
ug/L
0.50
04/17/15 18:17
EPA 6020A
Copper
3.6
ug/L
1.0
04/17/15 18:17
EPA 6020A
Magnesium
350
ug/L
10.0
04/17/15 18:17
EPA 6020A
Manganese
118
ug/L
0.50
04/17/15 18:17
EPA 6020A
Nickel
1.7
ug/L
0.50
04/17/15 18:17
EPA 6020A
Potassium
74.3
ug/L
50.0
04/17/15 18:17
EPA 6020A
Sodium
1640
ug/L
50.0
04/17/15 18:17
EPA 6020A
Strontium
7.0
ug/L
0.50
04/17/15 18:17
EPA 6020A
Zinc
18.0
ug/L
5.0
04/17/15 18:17
92243093004
2015008643 SPLP
EPA 6020A
Barium
118
ug/L
0.30
04/17/15 18:55
EPA 6020A
Boron
44.9
ug/L
25.0
04/20/15 15:18
EPA 6020A
Calcium
341
ug/L
40.0
04/17/15 18:55
EPA 6020A
Cobalt
3.3
ug/L
0.50
04/17/15 18:55
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 9 of 100

aceAnaiXical
www.pacelabs.com
Project: J15030693
Pace Project No.: 92243093
Lab Sample ID Client Sample ID
Method Parameters
Pace Analytical Services, Inc.
PW1*r6fyte. Suite 100
y Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92243093004
2015008643 SPLP
EPA 6020A
Copper
1.3
ug/L
1.0
04/17/15 18:55
EPA 6020A
Magnesium
449
ug/L
10.0
04/17/15 18:55
EPA 6020A
Manganese
95.0
ug/L
0.50
04/17/15 18:55
EPA 6020A
Nickel
1.6
ug/L
0.50
04/17/15 18:55
EPA 6020A
Potassium
1260
ug/L
50.0
04/17/15 18:55
EPA 6020A
Sodium
1880
ug/L
50.0
04/17/15 18:55
EPA 6020A
Strontium
5.2
ug/L
0.50
04/17/15 18:55
EPA 6020A
Zinc
20.4
ug/L
5.0
04/17/15 18:55
92243093005
2015008648 SPLP
EPA 6020A
Aluminum
12.4
ug/L
10.0
04/17/15 18:59
EPA 6020A
Barium
65.7
ug/L
0.30
04/17/15 18:59
EPA 6020A
Boron
55.6
ug/L
25.0
04/20/15 15:22
EPA 6020A
Calcium
123
ug/L
40.0
04/17/15 18:59
EPA 6020A
Copper
3.1
ug/L
1.0
04/17/15 18:59
EPA 6020A
Magnesium
65.9
ug/L
10.0
04/17/15 18:59
EPA 6020A
Manganese
11.7
ug/L
0.50
04/17/15 18:59
EPA 6020A
Nickel
1.7
ug/L
0.50
04/17/15 18:59
EPA 6020A
Potassium
71.1
ug/L
50.0
04/17/15 18:59
EPA 6020A
Sodium
1130
ug/L
50.0
04/17/15 18:59
EPA 6020A
Strontium
2.5
ug/L
0.50
04/17/15 18:59
EPA 6020A
Zinc
22.8
ug/L
5.0
04/17/15 18:59
92243093006
2015008651 SPLP
EPA 6020A
Aluminum
976
ug/L
10.0
04/17/15 19:04
EPA 6020A
Barium
116
ug/L
0.30
04/17/15 19:04
EPA 6020A
Boron
56.3
ug/L
5.0
04/20/15 15:27
EPA 6020A
Calcium
325
ug/L
40.0
04/17/15 19:04
EPA 6020A
Chromium
1.3
ug/L
0.50
04/17/15 19:04
EPA 6020A
Cobalt
5.7
ug/L
0.50
04/17/15 19:04
EPA 6020A
Copper
1.6
ug/L
1.0
04/17/15 19:04
EPA 6020A
Iron
687
ug/L
50.0
04/17/15 19:04
EPA 6020A
Lead
0.48
ug/L
0.10
04/17/15 19:04
EPA 6020A
Magnesium
207
ug/L
10.0
04/17/15 19:04
EPA 6020A
Manganese
118
ug/L
0.50
04/17/15 19:04
EPA 6020A
Nickel
1.5
ug/L
0.50
04/17/15 19:04
EPA 6020A
Potassium
815
ug/L
50.0
04/17/15 19:04
EPA 6020A
Sodium
1530
ug/L
50.0
04/17/15 19:04
EPA 6020A
Strontium
10
ug/L
0.50
04/17/15 19:04
EPA 6020A
Vanadium
1.5
ug/L
1.0
04/20/15 15:27
EPA 6020A
Zinc
30.8
ug/L
5.0
04/17/15 19:04
92243093007
2015008642
EPA 6010
Aluminum
30500
mg/kg
29.0
04/09/15 03:15
D4
EPA 6010
Barium
118
mg/kg
2.9
04/09/15 03:15
D3
EPA 6010
Beryllium
1.1
mg/kg
0.29
04/09/15 03:15
D3
EPA 6010
Boron
18.3
mg/kg
14.5
04/09/15 03:15
D3
EPA 6010
Calcium
131J
mg/kg
145
04/09/15 03:15
D3
EPA 6010
Chromium
37.8
mg/kg
1.5
04/09/15 03:15
D3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 100

aceAnaiXical
www.pacelabs.com
SUMMARY OF DETECTION
Pace Analytical Services, Inc.
PAROA16fyte. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
J15030693
92243093
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
92243093007
2015008642
EPA 6010
Copper
37.7
mg/kg
1.5
04/09/15 03:15
D3
EPA 6010
Iron
18000
mg/kg
11.6
04/09/15 03:15
D3
EPA 6010
Magnesium
4040
mg/kg
145
04/09/15 03:15
D3
EPA 6010
Manganese
830
mg/kg
1.5
04/09/15 03:15
D3
EPA 6010
Nickel
28.4
mg/kg
1.5
04/09/15 03:15
D3
EPA 6010
Potassium
971
mg/kg
290
04/09/15 03:15
D3
EPA 6010
Strontium
4.4
mg/kg
2.9
04/09/15 03:15
D3
EPA 6010
Zinc
51.2
mg/kg
5.8
04/09/15 03:15
D3
EPA 6020
Arsenic
2.2J
mg/kg
2.9
04/06/15 08:51
D3
EPA 6020
Cobalt
65.3
mg/kg
2.9
04/06/15 08:51
D3
EPA 6020
Lead
10.8
mg/kg
2.9
04/06/15 08:51
D3
EPA 6020
Selenium
3.4
mg/kg
2.9
04/06/15 08:51
D3
EPA 6020
Vanadium
39.0
mg/kg
2.9
04/06/15 08:51
D3
ASTM D2974-87
Percent Moisture
18.0
%
0.10
04/04/15 20:01
EPA 9045
pH at 25 Degrees C
6.3
Std. Units
0.10
04/02/15 09:35
EPA 300.0
Sulfate
6.0
mg/L
2.4
04/07/15 19:26
B
EPA 9060
Total Organic Carbon
2390
mg/kg
736
04/15/15 07:32
EPA 9060
Total Organic Carbon
2600
mg/kg
735
04/15/15 07:39
EPA 9060
Total Organic Carbon
2530
mg/kg
732
04/15/15 07:46
EPA 9060
Total Organic Carbon
2420
mg/kg
727
04/15/15 07:53
EPA 9060
Mean Total Organic Carbon
2490
mg/kg
733
04/15/15 07:32
EPA 9060
RSD%
3.9
%
04/15/15 07:32
92243093008
2015008643
EPA 6010
Aluminum
21200
mg/kg
27.1
04/09/15 03:19
D3
EPA 6010
Barium
88.3
mg/kg
2.7
04/09/15 03:19
D3
EPA 6010
Beryllium
1.3
mg/kg
0.27
04/09/15 03:19
D3
EPA 6010
Boron
29.8
mg/kg
13.6
04/09/15 03:19
D3
EPA 6010
Calcium
607
mg/kg
136
04/09/15 03:19
D3
EPA 6010
Chromium
14.1
mg/kg
1.4
04/09/15 03:19
D3
EPA 6010
Copper
44.9
mg/kg
1.4
04/09/15 03:19
D3
EPA 6010
Iron
32300
mg/kg
10.9
04/09/15 03:19
D4
EPA 6010
Magnesium
8970
mg/kg
136
04/09/15 03:19
D3
EPA 6010
Manganese
126
mg/kg
1.4
04/09/15 03:19
D3
EPA 6010
Nickel
12.5
mg/kg
1.4
04/09/15 03:19
D3
EPA 6010
Potassium
7790
mg/kg
271
04/09/15 03:19
D3
EPA 6010
Strontium
3.1
mg/kg
2.7
04/09/15 03:19
D3
EPA 6010
Zinc
83.2
mg/kg
5.4
04/09/15 03:19
D3
EPA 6020
Arsenic
3.4
mg/kg
2.7
04/06/15 08:53
D3
EPA 6020
Cobalt
9.6
mg/kg
2.7
04/06/15 08:53
D3
EPA 6020
Lead
4.0
mg/kg
2.7
04/06/15 08:53
D3
EPA 6020
Selenium
5.6
mg/kg
2.7
04/06/15 08:53
D3
EPA 6020
Vanadium
21.2
mg/kg
2.7
04/06/15 08:53
D3
ASTM D2974-87
Percent Moisture
6.6
%
0.10
04/04/15 20:01
D6
EPA 9045
pH at 25 Degrees C
6.4
Std. Units
0.10
04/02/15 09:35
EPA 300.0
Sulfate
6.6
mg/L
2.1
04/07/15 19:40
B
EPA 9060
Total Organic Carbon
362J
mg/kg
640
04/15/15 08:07
EPA 9060
Total Organic Carbon
334J
mg/kg
643
04/15/15 08:19
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 11 of 100

aceAnaiXical
www.pacelabs.com
Project: J15030693
Pace Project No.: 92243093
Lab Sample ID
Method
Client Sample ID
Parameters
92243093008
2015008643
EPA 9060
RSD%
92243093009
2015008648
EPA 6010
Aluminum
EPA 6010
Barium
EPA 6010
Beryllium
EPA 6010
Boron
EPA 6010
Chromium
EPA 6010
Copper
EPA 6010
Iron
EPA 6010
Magnesium
EPA 6010
Manganese
EPA 6010
Nickel
EPA 6010
Potassium
EPA 6010
Zinc
EPA 6020
Arsenic
EPA 6020
Cobalt
EPA 6020
Selenium
EPA 6020
Vanadium
ASTM D2974-87
Percent Moisture
EPA 9045
pH at 25 Degrees C
EPA 300.0
Sulfate
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Mean Total Organic Carbon
EPA 9060
RSD%
92243093010
2015008651
EPA 6010
Aluminum
EPA 6010
Barium
EPA 6010
Beryllium
EPA 6010
Boron
EPA 6010
Calcium
EPA 6010
Chromium
EPA 6010
Copper
EPA 6010
Iron
EPA 6010
Magnesium
EPA 6010
Manganese
EPA 6010
Nickel
EPA 6010
Potassium
EPA 6010
Strontium
EPA 6010
Zinc
EPA 6020
Arsenic
EPA 6020
Cobalt
EPA 6020
Lead
EPA 6020
Selenium
Pace Analytical Services, Inc.
PARGArwyte. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed
Qualifiers
11.3
%
04/15/15 08:01
17800
mg/kg
39.5
04/09/15 03:24
D3
29.2
mg/kg
3.9
04/09/15 03:24
D3
1.2
mg/kg
0.39
04/09/15 03:24
D3
22.6
mg/kg
19.7
04/09/15 03:24
D3
7.9
mg/kg
2.0
04/09/15 03:24
D3
34.4
mg/kg
2.0
04/09/15 03:24
D3
24200
mg/kg
15.8
04/09/15 03:24
D3
2470
mg/kg
197
04/09/15 03:24
D3
197
mg/kg
2.0
04/09/15 03:24
D3
7.4
mg/kg
2.0
04/09/15 03:24
D3
1190
mg/kg
395
04/09/15 03:24
D3
57.0
mg/kg
7.9
04/09/15 03:24
D3
4.6
mg/kg
3.9
04/06/15 08:55
D3
6.8
mg/kg
3.9
04/06/15 08:55
D3
7.1
mg/kg
3.9
04/06/15 08:55
D3
14.2
mg/kg
3.9
04/06/15 08:55
D3
37.1
%
0.10
04/04/15 20:01
6.0
Std. Units
0.10
04/03/15 10:15
3.3
mg/L
3.2
04/07/15 20:21
B
1460
mg/kg
954
04/15/15 09:14
1750
mg/kg
953
04/15/15 09:21
1490
mg/kg
964
04/15/15 09:28
1310
mg/kg
962
04/15/15 09:35
1500
mg/kg
958
04/15/15 09:14
12.2
%
04/15/15 09:14
35600
mg/kg
29.3
04/09/15 03:28
D4
255
mg/kg
2.9
04/09/15 03:28
D3
2.2
mg/kg
0.29
04/09/15 03:28
D3
45.0
mg/kg
14.7
04/09/15 03:28
D3
632
mg/kg
147
04/09/15 03:28
D3
73.5
mg/kg
1.5
04/09/15 03:28
D3
129
mg/kg
1.5
04/09/15 03:28
D3
48500
mg/kg
11.7
04/09/15 03:28
D4
9520
mg/kg
147
04/09/15 03:28
D3
631
mg/kg
1.5
04/09/15 03:28
D3
48.5
mg/kg
1.5
04/09/15 03:28
D3
6480
mg/kg
293
04/09/15 03:28
D3
33.1
mg/kg
2.9
04/09/15 03:28
D3
90.9
mg/kg
5.9
04/09/15 03:28
D3
7.0
mg/kg
2.9
04/06/15 09:05
D3
59.6
mg/kg
2.9
04/06/15 09:05
D3
15.3
mg/kg
2.9
04/06/15 09:05
D3
4.2
mg/kg
2.9
04/06/15 09:05
D3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 12 of 100

aceAnaiXical
www.pacelabs.com
Project: J15030693
Pace Project No.: 92243093
Lab Sample ID Client Sample ID
Method Parameters
Pace Analytical Services, Inc.
PWIbrwyte. Suite 100
y Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92243093010
2015008651
EPA 6020
Vanadium
62.4
mg/kg
2.9
04/06/15 09:05
D3
EPA 7471
Mercury
0.029
mg/kg
0.0097
04/07/15 08:55
ASTM D2974-87
Percent Moisture
16.8
%
0.10
04/04/15 20:01
EPA 9045
pH at 25 Degrees C
6.4
Std. Units
0.10
04/03/15 10:15
EPA 300.0
Sulfate
3.9
mg/L
2.4
04/07/15 20:34
B
EPA 9060
Total Organic Carbon
10500
mg/kg
1490
04/15/15 09:42
EPA 9060
Total Organic Carbon
15600
mg/kg
1480
04/15/15 09:49
EPA 9060
Total Organic Carbon
7690
mg/kg
1490
04/15/15 09:55
EPA 9060
Total Organic Carbon
6600
mg/kg
1500
04/15/15 10:01
EPA 9060
Mean Total Organic Carbon
10100
mg/kg
1490
04/15/15 09:42
EPA 9060
RSD%
39.8
%
04/15/15 09:42
92243093011
2015008645
EPA 6010
Aluminum
16800
mg/kg
6.0
04/05/15 05:20
EPA 6010
Barium
93.5
mg/kg
0.60
04/05/15 05:20
EPA 6010
Beryllium
0.53
mg/kg
0.30
04/09/15 03:32
D3
EPA 6010
Boron
25.5
mg/kg
14.9
04/09/15 03:32
D3
EPA 6010
Calcium
102
mg/kg
29.8
04/05/15 05:20
EPA 6010
Chromium
17.2
mg/kg
1.5
04/09/15 03:32
D3
EPA 6010
Copper
10.0
mg/kg
1.5
04/09/15 03:32
D3
EPA 6010
Iron
27000
mg/kg
11.9
04/09/15 03:32
D4
EPA 6010
Magnesium
762
mg/kg
29.8
04/05/15 05:20
EPA 6010
Manganese
135
mg/kg
1.5
04/09/15 03:32
D3
EPA 6010
Nickel
3.6
mg/kg
0.30
04/05/15 05:20
EPA 6010
Potassium
687
mg/kg
59.5
04/05/15 05:20
EPA 6010
Strontium
2.3
mg/kg
0.60
04/05/15 05:20
EPA 6010
Zinc
24.1
mg/kg
1.2
04/05/15 05:20
EPA 6020
Arsenic
2.9J
mg/kg
3.0
04/06/15 09:07
D3
EPA 6020
Cobalt
7.7
mg/kg
3.0
04/06/15 09:07
D3
EPA 6020
Lead
13.1
mg/kg
3.0
04/06/15 09:07
D3
EPA 6020
Selenium
1.91
mg/kg
3.0
04/06/15 09:07
D3
EPA 6020
Vanadium
28.8
mg/kg
3.0
04/06/15 09:07
D3
EPA 7471
Mercury
0.024
mg/kg
0.0096
04/07/15 08:57
ASTM D2974-87
Percent Moisture
14.0
%
0.10
04/04/15 20:02
EPA 9045
pH at 25 Degrees C
4.5
Std. Units
0.10
04/03/15 10:15
EPA 9060
Total Organic Carbon
5210
mg/kg
955
04/15/15 10:07
EPA 9060
Total Organic Carbon
6060
mg/kg
950
04/15/15 10:14
EPA 9060
Total Organic Carbon
5550
mg/kg
955
04/15/15 10:19
EPA 9060
Total Organic Carbon
5390
mg/kg
950
04/15/15 10:25
EPA 9060
Mean Total Organic Carbon
5550
mg/kg
952
04/15/15 10:07
EPA 9060
RSD%
6.7
%
04/15/15 10:07
92243093012
2015008646
EPA 6010
Aluminum
24000
mg/kg
25.9
04/09/15 03:36
D3
EPA 6010
Barium
136
mg/kg
2.6
04/09/15 03:36
D3
EPA 6010
Beryllium
1.6
mg/kg
0.26
04/09/15 03:36
D3
EPA 6010
Boron
31.3
mg/kg
12.9
04/09/15 03:36
D3
EPA 6010
Calcium
214
mg/kg
129
04/09/15 03:36
D3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Qualifiers
Page 13 of 100

aceAnaiXical
www.pacelabs.com
SUMMARY OF DETECTION
Pace Analytical Services, Inc.
P36gmirpyt.. Suite 100
y Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
J15030693
92243093
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
92243093012
2015008646
EPA 6010
Chromium
12.7
mg/kg
1.3
04/09/15 03:36
D3
EPA 6010
Copper
46.5
mg/kg
1.3
04/09/15 03:36
D3
EPA 6010
Iron
32800
mg/kg
10.3
04/09/15 03:36
D4
EPA 6010
Magnesium
7800
mg/kg
129
04/09/15 03:36
D3
EPA 6010
Manganese
325
mg/kg
1.3
04/09/15 03:36
D3
EPA 6010
Nickel
9.7
mg/kg
1.3
04/09/15 03:36
D3
EPA 6010
Potassium
5630
mg/kg
259
04/09/15 03:36
D3
EPA 6010
Strontium
5.2
mg/kg
2.6
04/09/15 03:36
D3
EPA 6010
Zinc
81.2
mg/kg
5.2
04/09/15 03:36
D3
EPA 6020
Arsenic
3.6
mg/kg
2.6
04/06/15 09:09
D3
EPA 6020
Cobalt
16.4
mg/kg
2.6
04/06/15 09:09
D3
EPA 6020
Lead
10.4
mg/kg
2.6
04/06/15 09:09
D3
EPA 6020
Selenium
6.0
mg/kg
2.6
04/06/15 09:09
D3
EPA 6020
Vanadium
17.7
mg/kg
2.6
04/06/15 09:09
D3
ASTM D2974-87
Percent Moisture
4.0
%
0.10
04/04/15 20:02
EPA 9045
pH at 25 Degrees C
5.9
Std. Units
0.10
04/03/15 10:15
EPA 9060
Total Organic Carbon
4410
mg/kg
627
04/15/15 10:30
EPA 9060
Total Organic Carbon
4430
mg/kg
626
04/15/15 10:38
EPA 9060
Total Organic Carbon
5380
mg/kg
628
04/15/15 10:46
EPA 9060
Total Organic Carbon
3640
mg/kg
626
04/15/15 10:53
EPA 9060
Mean Total Organic Carbon
4460
mg/kg
627
04/15/15 10:30
EPA 9060
RSD%
15.9
%
04/15/15 10:30
92243093013
2015008647
EPA 6010
Aluminum
13900
mg/kg
27.4
04/09/15 03:41
D3
EPA 6010
Barium
56.4
mg/kg
2.7
04/09/15 03:41
D3
EPA 6010
Beryllium
0.33
mg/kg
0.27
04/09/15 03:41
D3
EPA 6010
Boron
28.3
mg/kg
13.7
04/09/15 03:41
D3
EPA 6010
Calcium
437
mg/kg
137
04/09/15 03:41
D3
EPA 6010
Chromium
10.9
mg/kg
1.4
04/09/15 03:41
D3
EPA 6010
Copper
52.6
mg/kg
1.4
04/09/15 03:41
D3
EPA 6010
Iron
29900
mg/kg
11.0
04/09/15 03:41
D4
EPA 6010
Magnesium
6950
mg/kg
137
04/09/15 03:41
D3
EPA 6010
Manganese
109
mg/kg
1.4
04/09/15 03:41
D3
EPA 6010
Nickel
15.9
mg/kg
1.4
04/09/15 03:41
D3
EPA 6010
Potassium
5480
mg/kg
274
04/09/15 03:41
D3
EPA 6010
Strontium
3.6
mg/kg
2.7
04/09/15 03:41
D3
EPA 6010
Zinc
64.8
mg/kg
5.5
04/09/15 03:41
D3
EPA 6020
Arsenic
3.2
mg/kg
2.8
04/06/15 09:12
D3
EPA 6020
Cobalt
16.0
mg/kg
2.8
04/06/15 09:12
D3
EPA 6020
Lead
5.4
mg/kg
2.8
04/06/15 09:12
D3
EPA 6020
Selenium
5.3
mg/kg
2.8
04/06/15 09:12
D3
EPA 6020
Vanadium
13.5
mg/kg
2.8
04/06/15 09:12
D3
ASTM D2974-87
Percent Moisture
7.5
%
0.10
04/04/15 20:02
EPA 9045
pH at 25 Degrees C
4.9
Std. Units
0.10
04/03/15 10:15
EPA 9056
Sulfate
477
mg/kg
273
04/02/15 23:36
EPA 9060
Total Organic Carbon
4110
mg/kg
651
04/15/15 11:12
EPA 9060
Total Organic Carbon
4320
mg/kg
647
04/15/15 11:19
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 14 of 100

aceAnaiXical
www.pacelabs.com
Project: J15030693
Pace Project No.: 92243093
Lab Sample ID
Method
Client Sample ID
Parameters
92243093013
2015008647
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Mean Total Organic Carbon
EPA 9060
RSD%
92243093014
2015008649
EPA 6010
Aluminum
EPA 6010
Barium
EPA 6010
Beryllium
EPA 6010
Boron
EPA 6010
Calcium
EPA 6010
Chromium
EPA 6010
Copper
EPA 6010
Iron
EPA 6010
Magnesium
EPA 6010
Manganese
EPA 6010
Nickel
EPA 6010
Potassium
EPA 6010
Strontium
EPA 6010
Zinc
EPA 6020
Arsenic
EPA 6020
Cobalt
EPA 6020
Lead
EPA 6020
Selenium
EPA 6020
Vanadium
ASTM D2974-87
Percent Moisture
EPA 9045
pH at 25 Degrees C
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Mean Total Organic Carbon
EPA 9060
RSD%
Pace Analytical Services, Inc.
PW1*r6fyte. Suite 100
y Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed
Qualifiers
EPA 6010
Aluminum
1740
4170
mg/kg
647
04/15/1511:25
Barium
3920
mg/kg
653
04/15/1511:33
EPA 6010
4130
mg/kg
649
04/15/1511:12
04/06/15 15:25
4.0
%
54.6
04/15/1511:12
34.8
17500
mg/kg
29.6
04/09/15 03:45
D3
70.8
mg/kg
3.0
04/09/15 03:45
D3
1.9
mg/kg
0.59
04/09/15 08:55
D3
26AJ
mg/kg
29.6
04/09/15 08:55
D3
168
mg/kg
148
04/09/15 03:45
D3
12.6
mg/kg
3.0
04/09/15 08:55
D3
98.9
mg/kg
3.0
04/09/15 08:55
D3
24600
mg/kg
11.8
04/09/15 03:45
D4
6040
mg/kg
148
04/09/15 03:45
D3
266
mg/kg
3.0
04/09/15 08:55
D4
14.4
mg/kg
1.5
04/09/15 03:45
D3
4120
mg/kg
296
04/09/15 03:45
D3
2AJ
mg/kg
3.0
04/09/15 03:45
D3
134
mg/kg
5.9
04/09/15 03:45
D3
6.4
mg/kg
3.0
04/06/15 09:14
D3
18.4
mg/kg
3.0
04/06/15 09:14
D3
7.8
mg/kg
3.0
04/06/15 09:14
D3
10.6
mg/kg
3.0
04/06/15 09:14
D3
20.7
mg/kg
3.0
04/06/15 09:14
D3
14.2
%
0.10
04/04/15 20:02
5.3
Std. Units
0.10
04/03/15 10:15
2830
mg/kg
693
04/15/1511:40
2200
mg/kg
701
04/15/1511:48
2210
mg/kg
695
04/15/1511:54
1900
mg/kg
693
04/15/1512:02
2280
mg/kg
695
04/15/1511:40
17.2
%
04/15/1511:40
92243093015
2015008650
EPA 6010
Aluminum
1740
mg/kg
7.0
04/06/15 15:25
EPA 6010
Barium
7.4
mg/kg
0.70
04/06/15 15:25
EPA 6010
Beryllium
0.056J
mg/kg
0.070
04/06/15 15:25
EPA 6010
Calcium
54.6
mg/kg
34.8
04/06/15 15:25
EPA 6010
Chromium
1.5
mg/kg
0.35
04/06/15 15:25
EPA 6010
Copper
6.5
mg/kg
0.35
04/06/15 15:25
EPA 6010
Iron
12600
mg/kg
13.9
04/09/15 04:02 D4
EPA 6010
Magnesium
889
mg/kg
34.8
04/06/15 15:25
EPA 6010
Manganese
14.5
mg/kg
0.35
04/06/15 15:25
EPA 6010
Nickel
1.9
mg/kg
0.35
04/06/15 15:25
EPA 6010
Potassium
748
mg/kg
69.7
04/06/15 15:25
EPA 6010
Strontium
0.511
mg/kg
0.70
04/06/15 15:25
EPA 6010
Zinc
8.8
mg/kg
1.4
04/06/15 15:25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 15 of 100

aceAnaiXical
www.pacelabs.com
SUMMARY OF DETECTION
Pace Analytical Services, Inc.
P36
911slWyte. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
J15030693
92243093
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
92243093015
2015008650
EPA 6020
Arsenic
96.7
mg/kg
3.5
04/06/15 09:16
D3
EPA 6020
Cadmium
0.38J
mg/kg
0.42
04/06/15 09:16
D3
EPA 6020
Cobalt
13.5
mg/kg
3.5
04/06/15 09:16
D3
EPA 6020
Lead
17.7
mg/kg
3.5
04/06/15 09:16
D3
EPA 6020
Selenium
12.2
mg/kg
3.5
04/06/15 09:16
D3
EPA 6020
Vanadium
66.0
mg/kg
3.5
04/06/15 09:16
D3
EPA 7471
Mercury
0.23
mg/kg
0.011
04/07/15 09:06
ASTM D2974-87
Percent Moisture
29.5
%
0.10
04/04/15 20:02
EPA 9045
pH at 25 Degrees C
7.5
Std. Units
0.10
04/03/15 10:15
EPA 9060
Total Organic Carbon
72800
mg/kg
8570
04/15/15 12:08
EPA 9060
Total Organic Carbon
62300
mg/kg
8630
04/15/15 12:15
EPA 9060
Total Organic Carbon
63300
mg/kg
9100
04/15/15 12:20
EPA 9060
Total Organic Carbon
60700
mg/kg
8670
04/15/15 12:27
EPA 9060
Mean Total Organic Carbon
64800
mg/kg
8740
04/15/15 12:08
EPA 9060
RSD%
8.4
%
04/15/15 12:08
92243093016
2015008652
EPA 6010
Aluminum
15700
mg/kg
44.5
04/09/15 04:07
D3
EPA 6010
Barium
34.1
mg/kg
4.4
04/09/15 04:07
D3
EPA 6010
Beryllium
1.1
mg/kg
0.44
04/09/15 04:07
D3
EPA 6010
Boron
45.2
mg/kg
22.2
04/09/15 04:07
D3
EPA 6010
Calcium
343
mg/kg
222
04/09/15 04:07
D3
EPA 6010
Chromium
15.7
mg/kg
2.2
04/09/15 04:07
D3
EPA 6010
Copper
40.6
mg/kg
2.2
04/09/15 04:07
D3
EPA 6010
Iron
49200
mg/kg
17.8
04/09/15 04:07
D4
EPA 6010
Magnesium
5490
mg/kg
222
04/09/15 04:07
D3
EPA 6010
Manganese
128
mg/kg
2.2
04/09/15 04:07
D3
EPA 6010
Nickel
14.7
mg/kg
2.2
04/09/15 04:07
D3
EPA 6010
Potassium
1860
mg/kg
445
04/09/15 04:07
D3
EPA 6010
Strontium
5.8
mg/kg
4.4
04/09/15 04:07
D3
EPA 6010
Zinc
74.5
mg/kg
8.9
04/09/15 04:07
D3
EPA 6020
Arsenic
4.7
mg/kg
4.4
04/06/15 09:19
D3
EPA 6020
Cobalt
8.3
mg/kg
4.4
04/06/15 09:19
D3
EPA 6020
Lead
10.4
mg/kg
4.4
04/06/15 09:19
D3
EPA 6020
Selenium
7.1
mg/kg
4.4
04/06/15 09:19
D3
EPA 6020
Vanadium
11.5
mg/kg
4.4
04/06/15 09:19
D3
ASTM D2974-87
Percent Moisture
43.0
%
0.10
04/04/15 20:02
EPA 9045
pH at 25 Degrees C
6.4
Std. Units
0.10
04/03/15 10:15
EPA 9060
Total Organic Carbon
1380
mg/kg
1050
04/15/15 13:22
EPA 9060
Total Organic Carbon
1430
mg/kg
1060
04/15/15 13:27
EPA 9060
Total Organic Carbon
1540
mg/kg
1060
04/15/15 13:33
EPA 9060
Total Organic Carbon
1540
mg/kg
1050
04/15/15 13:40
EPA 9060
Mean Total Organic Carbon
1470
mg/kg
1060
04/15/15 13:22
EPA 9060
RSD%
5.7
%
04/15/15 13:22
92243093017
2015008653
EPA 6010
Aluminum
19500
mg/kg
6.6
04/06/15 15:33
EPA 6010
Barium
65.6
mg/kg
0.66
04/06/15 15:33
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 16 of 100

aceAnaiXical
www.pacelabs.com
SUMMARY OF DETECTION
Pace Analytical Services, Inc.
PAROA116fytie. Suite 100
y Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
J15030693
92243093
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
92243093017
2015008653
EPA 6010
Beryllium
1.0
mg/kg
0.066
04/05/15 05:58
EPA 6010
Calcium
3390
mg/kg
32.9
04/06/15 15:33
EPA 6010
Chromium
38.6
mg/kg
0.33
04/05/15 05:58
EPA 6010
Copper
92.3
mg/kg
0.33
04/05/15 05:58
EPA 6010
Iron
64600
mg/kg
13.2
04/09/15 04:11
D4
EPA 6010
Magnesium
16300
mg/kg
32.9
04/06/15 15:33
EPA 6010
Manganese
194
mg/kg
0.33
04/05/15 05:58
EPA 6010
Molybdenum
1.6
mg/kg
0.66
04/06/15 15:33
EPA 6010
Nickel
39.9
mg/kg
0.33
04/06/15 15:33
EPA 6010
Potassium
4510
mg/kg
65.9
04/06/15 15:33
EPA 6010
Sodium
437
mg/kg
65.9
04/06/15 15:33
EPA 6010
Strontium
7.3
mg/kg
0.66
04/06/15 15:33
EPA 6010
Zinc
86.6
mg/kg
1.3
04/06/15 15:33
EPA 6020
Arsenic
3AJ
mg/kg
3.3
04/06/15 09:21
D3
EPA 6020
Cobalt
36.9
mg/kg
3.3
04/06/15 09:21
D3
EPA 6020
Lead
9.0
mg/kg
3.3
04/06/15 09:21
D3
EPA 6020
Selenium
4.9
mg/kg
3.3
04/06/15 09:21
D3
EPA 6020
Vanadium
51.2
mg/kg
3.3
04/06/15 09:21
D3
ASTM D2974-87
Percent Moisture
23.9
%
0.10
04/04/15 20:02
EPA 9045
pH at 25 Degrees C
7.6
Std. Units
0.10
04/03/15 10:15
EPA 9060
Total Organic Carbon
64200
mg/kg
7510
04/15/15 13:46
EPA 9060
Total Organic Carbon
60200
mg/kg
7490
04/15/15 13:55
EPA 9060
Total Organic Carbon
58700
mg/kg
7740
04/15/15 14:01
EPA 9060
Total Organic Carbon
54800
mg/kg
7620
04/15/15 14:09
EPA 9060
Mean Total Organic Carbon
59400
mg/kg
7590
04/15/15 13:46
EPA 9060
RSD%
6.6
%
04/15/15 13:46
92243093018
2015008654
EPA 6010
Aluminum
18700
mg/kg
6.5
04/05/15 06:03
EPA 6010
Barium
87.5
mg/kg
0.65
04/05/15 06:03
EPA 6010
Beryllium
1.5
mg/kg
0.33
04/09/15 04:15
D3
EPA 6010
Boron
48.5
mg/kg
16.3
04/09/15 04:15
D3
EPA 6010
Calcium
484
mg/kg
32.5
04/05/15 06:03
EPA 6010
Chromium
87.3
mg/kg
1.6
04/09/15 04:15
D3
EPA 6010
Copper
56.0
mg/kg
1.6
04/09/15 04:15
D3
EPA 6010
Iron
52600
mg/kg
13.0
04/09/15 04:15
D4
EPA 6010
Magnesium
2210
mg/kg
32.5
04/05/15 06:03
EPA 6010
Manganese
681
mg/kg
1.6
04/09/15 04:15
D3
EPA 6010
Nickel
15.7
mg/kg
0.33
04/05/15 06:03
EPA 6010
Potassium
1790
mg/kg
65.1
04/05/15 06:03
EPA 6010
Strontium
2.1
mg/kg
0.65
04/05/15 06:03
EPA 6010
Zinc
36.8
mg/kg
1.3
04/05/15 06:03
EPA 6020
Arsenic
2.7J
mg/kg
3.3
04/06/15 09:23
D3
EPA 6020
Cobalt
53.5
mg/kg
3.3
04/06/15 09:23
D3
EPA 6020
Lead
15.0
mg/kg
3.3
04/06/15 09:23
D3
EPA 6020
Selenium
2.7J
mg/kg
3.3
04/06/15 09:23
D3
EPA 6020
Vanadium
81.0
mg/kg
3.3
04/06/15 09:23
D3
EPA 7471
Mercury
0.019
mg/kg
0.011
04/07/15 09:18
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 17 of 100

aceAnaiXical
www.pacelabs.com
Project: J15030693
Pace Project No.: 92243093
Lab Sample ID
Method
Client Sample ID
Parameters
92243093018
2015008654
ASTM D2974-87
Percent Moisture
EPA 9045
pH at 25 Degrees C
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Mean Total Organic Carbon
EPA 9060
RSD%
SUMMARY OF DETECTION
Result Units
22.8
%
6.1
Std. Units
29600
mg/kg
27300
mg/kg
30200
mg/kg
30100
mg/kg
29300
mg/kg
4.7
%
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
PARIAr6fyte. Suite 100
y Huntersville, NC 28078
[phone]
Report Limit Analyzed Qualifiers
0.10 04/04/15 20:03
0.10 04/03/1510:15
1210 04/15/1514:16
1210 04/15/1514:24
1200 04/15/1514:31
1210 04/15/1514:37
1210 04/15/1514:16
04/15/15 14:16
Page 18 of 100

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
PARGArwyte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 29, 2015
General Information:
12 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23404
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243090001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1173228)
• Aluminum
• Barium
• Boron
• Iron
• Manganese
• Molybdenum
• MSD (Lab ID: 1173229)
• Aluminum
• Barium
• Boron
• Calcium
• Iron
• Magnesium
• Manganese
• Molybdenum
• Potassium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 19 of 100

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
POWWyte. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 29, 2015
QC Batch: MPRP/23404
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243090001
R1: RPD value was outside control limits.
• MSD (Lab ID: 1173229)
• Manganese
Additional Comments:
Analyte Comments:
QC Batch: MPRP/23404
D3: D3
•2015008649 (Lab ID: 92243093014)
• Copper
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008642 (Lab ID: 92243093007)
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
•2015008643 (Lab ID: 92243093008)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 20 of 100

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
PARGArwyte. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 29, 2015
Analyte Comments:
QC Batch: MPRP/23404
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008643 (Lab ID: 92243093008)
• Zinc
•2015008645 (Lab ID: 92243093011)
• Boron
• Beryllium
• Chromium
• Copper
• Manganese
• Sodium
•2015008646 (Lab ID: 92243093012)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
•2015008647 (Lab ID: 92243093013)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
•2015008648 (Lab ID: 92243093009)
• Aluminum
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 21 of 100

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
PW'Arwyte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 29, 2015
Analyte Comments:
QC Batch: MPRP/23404
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008648 (Lab ID: 92243093009)
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
•2015008649 (Lab ID: 92243093014)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Potassium
• Magnesium
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
•2015008651 (Lab ID:92243093010)
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 22 of 100

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369041birWYte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 29, 2015
Analyte Comments:
QC Batch: MPRP/23404
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008651 (Lab ID:92243093010)
• Strontium
• Zinc
•2015008652 (Lab ID: 92243093016)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
•2015008654 (Lab ID: 92243093018)
• Boron
• Beryllium
• Chromium
• Copper
• Manganese
• Sodium
D4: Sample was diluted due to the presence of high levels of target analytes.
•2015008642 (Lab ID: 92243093007)
• Aluminum
•2015008643 (Lab ID:92243093008)
• Iron
•2015008645 (Lab ID: 92243093011)
• Iron
•2015008646 (Lab ID:92243093012)
• Iron
•2015008647 (Lab ID:92243093013)
• Iron
•2015008649 (Lab ID:92243093014)
• Iron
• Manganese
•2015008650 (Lab ID: 92243093015)
• Iron
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 23 of 100

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P36904fflir6fYt-. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 29, 2015
Analyte Comments:
QC Batch: MPRP/23404
D4: Sample was diluted due to the presence of high levels of target analytes.
•2015008651 (Lab ID:92243093010)
• Aluminum
• Iron
•2015008652 (Lab ID: 92243093016)
• Iron
•2015008653 (Lab ID: 92243093017)
• Iron
•2015008654 (Lab ID: 92243093018)
• Iron
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 24 of 100

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P36904KWeYte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 29, 2015
General Information:
12 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23405
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243090002
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1173232)
• Antimony
• Cobalt
• Vanadium
• MSD (Lab ID: 1173233)
• Antimony
• Cobalt
• Vanadium
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 25 of 100

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P36904K�WeYtie. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 29, 2015
Analyte Comments:
QC Batch: MPRP/23405
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008642 (Lab ID: 92243093007)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
•2015008643 (Lab ID:92243093008)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
•2015008645 (Lab ID: 92243093011)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
•2015008646 (Lab ID:92243093012)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
•2015008647 (Lab ID: 92243093013)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 26 of 100

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P36904'iWfYte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 29, 2015
Analyte Comments:
QC Batch: MPRP/23405
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008647 (Lab ID: 92243093013)
• Thallium
• Vanadium
•2015008648 (Lab ID:92243093009)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
•2015008649 (Lab ID:92243093014)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
•2015008650 (Lab ID:92243093015)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
•2015008651 (Lab ID:92243093010)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
•2015008652 (Lab ID: 92243093016)
• Arsenic
• Cadmium
• Cobalt
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 27 of 100

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369041jWeYtie. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 29, 2015
Analyte Comments:
QC Batch: MPRP/23405
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008652 (Lab ID: 92243093016)
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
•2015008653 (Lab ID:92243093017)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
•2015008654 (Lab ID:92243093018)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
• MS (Lab ID: 1173232)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
• MSD (Lab ID: 1173233)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 28 of 100

aceAnaiXical
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Pace Analytical Services, Inc.
P369041�WeYtie. Suite 100
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[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 29, 2015
Analyte Comments:
QC Batch: MPRP/23405
N2: The lab does not hold TNI accreditation for this parameter.
•2015008642 (Lab ID:92243093007)
• Antimony
•2015008643 (Lab ID:92243093008)
• Antimony
•2015008645 (Lab ID: 92243093011)
• Antimony
•2015008646 (Lab ID:92243093012)
• Antimony
•2015008647 (Lab ID:92243093013)
• Antimony
•2015008648 (Lab ID:92243093009)
• Antimony
•2015008649 (Lab ID:92243093014)
• Antimony
•2015008650 (Lab ID:92243093015)
• Antimony
•2015008651 (Lab ID:92243093010)
• Antimony
•2015008652 (Lab ID:92243093016)
• Antimony
•2015008653 (Lab ID:92243093017)
• Antimony
•2015008654 (Lab ID:92243093018)
• Antimony
• BLANK (Lab ID: 1173230)
• Antimony
• LCS (Lab ID: 1173231)
• Antimony
• MS (Lab ID: 1173232)
• Antimony
• MSD (Lab ID: 1173233)
• Antimony
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 29 of 100

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Pace Analytical Services, Inc.
P36904f�WeYtie. Suite 100
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[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: April 29, 2015
General Information:
6 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3020 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 30 of 100

aceAnaiXical
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Pace Analytical Services, Inc.
P369041�WeYtie. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 7470
Description: 7470 Mercury
Client: Duke Energy
Date: April 29, 2015
General Information:
6 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 31 of 100

aceAnaiXical
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Pace Analytical Services, Inc.
P36904f�WeYtie. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 7471
Description: 7471 Mercury
Client: Duke Energy
Date: April 29, 2015
General Information:
12 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7471 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 32 of 100

aceAnaiXical
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Pace Analytical Services, Inc.
PO05kbi Wyte. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 9045
Description: 9045 pH Soil
Client: Duke Energy
Date: April 29, 2015
General Information:
12 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 33 of 100

aceAnaiXical
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Pace Analytical Services, Inc.
PggcO)irpyt.. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 300.0
Description: 300.0 IC Anions, SPLP
Client: Duke Energy
Date: April 29, 2015
General Information:
4 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
QC Batch: WETA/22469
B: Analyte was detected in the associated method blank.
• BLANK for HBN 258521 [WETA/224 (Lab ID: 1428206)
• Sulfate
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 34 of 100

aceAnaiXical
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Pace Analytical Services, Inc.
PO05kf�i Wyte. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 353.2
Description: 353.2 Nitrogen, NO2/NO3, SPLP
Client: Duke Energy
Date: April 29, 2015
General Information:
4 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-11: Analysis conducted outside the EPA method holding time.
•2015008642 (Lab ID: 92243093007)
•2015008643 (Lab ID: 92243093008)
•2015008648 (Lab ID: 92243093009)
•2015008651 (Lab ID:92243093010)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 35 of 100

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PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: SM 4500 -CI -E
Description: 4500 Chloride, SPLP
Client: Duke Energy
Date: April 29, 2015
Pace Analytical Services, Inc.
P�S�05kf�i WYte. Suite 100
y Huntersville, NC 28078
[phone]
General Information:
4 samples were analyzed for SM 4500 -CI -E. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 36 of 100

aceAnaiXical
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Pace Analytical Services, Inc.
PAMIirwyte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: April 29, 2015
General Information:
12 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/45037
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008642 (Lab ID:92243093007)
• Chloride
• Sulfate
•2015008643 (Lab ID:92243093008)
• Chloride
• Sulfate
•2015008645 (Lab ID: 92243093011)
• Chloride
• Sulfate
•2015008646 (Lab ID:92243093012)
• Chloride
• Sulfate
•2015008647 (Lab ID:92243093013)
• Chloride
•2015008648 (Lab ID:92243093009)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 37 of 100

aceAnaiXical
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Pace Analytical Services, Inc.
PWOAirwyte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: April 29, 2015
Analyte Comments:
QC Batch: WETA/45037
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008651 (Lab ID:92243093010)
• Chloride
• Sulfate
QC Batch: WETA/45049
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008649 (Lab ID:92243093014)
• Chloride
• Sulfate
•2015008650 (Lab ID:92243093015)
• Chloride
• Sulfate
•2015008652 (Lab ID:92243093016)
• Chloride
• Sulfate
•2015008653 (Lab ID:92243093017)
• Chloride
• Sulfate
•2015008654 (Lab ID:92243093018)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 38 of 100

aceAnaiXical
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Pace Analytical Services, Inc.
POWWyte. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: April 29, 2015
General Information:
12 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-13: Sample was received or analysis requested beyond the recognized method holding time.
•2015008642 (Lab ID:92243093007)
•2015008643 (Lab ID:92243093008)
•2015008645 (Lab ID:92243093011)
•2015008646 (Lab ID:92243093012)
•2015008647 (Lab ID:92243093013)
•2015008648 (Lab ID:92243093009)
•2015008649 (Lab ID:92243093014)
•2015008650 (Lab ID:92243093015)
•2015008651 (Lab ID:92243093010)
•2015008652 (Lab ID:92243093016)
•2015008653 (Lab ID:92243093017)
•2015008654 (Lab ID:92243093018)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 39 of 100

aceAnaiXical
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Pace Analytical Services, Inc.
P3690*rWyte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030693
Pace Project No.: 92243093
Method: EPA 9060
Description: Total Organic Carbon Quad
Client: Duke Energy
Date: April 29, 2015
General Information:
12 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 40 of 100

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ANALYTICAL RESULTS
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
PAROAirwyte. Suite 100
y Huntersville, NC 28078
[phone]
Sample: 2015008641 Lab ID: 92243093001 Collected: 03/24/15 08:20 Received: 03/27/15 15:48 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\ri,I=11 l[99�r 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/29/2015 08:01 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
144
ug/L
10.0
3.0
1
04/02/15 07:30
04/02/15 19:20
7429-90-5
ND
ug/L
0.50
0.15
1
04/02/15 07:30
04/02/15 19:20
7440-36-0
ND
ug/L
0.50
0.11
1
04/02/15 07:30
04/02/15 19:20
7440-38-2
2.3
ug/L
0.30
0.081
1
04/02/15 07:30
04/02/15 19:20
7440-39-3
ND
ug/L
0.20
0.067
1
04/02/15 07:30
04/02/15 19:20
7440-41-7
ND
ug/L
5.0
1.1
1
04/02/15 07:30
04/02/15 19:20
7440-42-8
ND
ug/L
0.080
0.024
1
04/02/15 07:30
04/02/15 19:20
7440-43-9
216
ug/L
40.0
16.0
1
04/02/15 07:30
04/02/15 19:20
7440-70-2
1.5
ug/L
0.50
0.17
1
04/02/15 07:30
04/02/15 19:20
7440-47-3
2.4
ug/L
0.50
0.13
1
04/02/15 07:30
04/02/15 19:20
7440-48-4
ND
ug/L
1.0
0.21
1
04/02/15 07:30
04/02/15 19:20
7440-50-8
426
ug/L
50.0
13.7
1
04/02/15 07:30
04/02/15 19:20
7439-89-6
0.14
ug/L
0.10
0.046
1
04/02/15 07:30
04/02/15 19:20
7439-92-1
67.4
ug/L
10.0
3.2
1
04/02/15 07:30
04/02/15 19:20
7439-95-4
6.5
ug/L
0.50
0.24
1
04/02/15 07:30
04/02/15 19:20
7439-96-5
ND
ug/L
0.50
0.094
1
04/02/15 07:30
04/02/15 19:20
7439-98-7
ND
ug/L
0.50
0.16
1
04/02/15 07:30
04/02/15 19:20
7440-02-0
165
ug/L
50.0
11.7
1
04/02/15 07:30
04/02/15 19:20
7440-09-7
ND
ug/L
0.50
0.20
1
04/02/15 07:30
04/02/15 19:20
7782-49-2
ND
ug/L
50.0
16.3
1
04/02/15 07:30
04/02/15 19:20
7440-23-5
ND
ug/L
0.50
0.13
1
04/02/15 07:30
04/02/15 19:20
7440-24-6
ND
ug/L
0.10
0.015
1
04/02/15 07:30
04/02/15 19:20
7440-28-0
ND
ug/L
1.0
0.28
1
04/02/15 07:30
04/02/15 19:20
7440-62-2
8.9
ug/L
5.0
2.4
1
04/02/15 07:30
04/02/15 19:20
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/01/15 09:20 04/01/15 13:48 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 41 of 100

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ANALYTICAL RESULTS
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
POWWyte. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015008644 Lab ID: 92243093002 Collected: 03/25/15 10:35 Received: 03/27/15 15:48 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\�i,I=11 l[99�r 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/29/2015 08:01 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
1010
ug/L
10.0
3.0
1
04/02/15 07:30
04/02/15 19:22
7429-90-5
ND
ug/L
0.50
0.15
1
04/02/15 07:30
04/02/15 19:22
7440-36-0
ND
ug/L
0.50
0.11
1
04/02/15 07:30
04/02/15 19:22
7440-38-2
6.5
ug/L
0.30
0.081
1
04/02/15 07:30
04/02/15 19:22
7440-39-3
ND
ug/L
0.20
0.067
1
04/02/15 07:30
04/02/15 19:22
7440-41-7
ND
ug/L
5.0
1.1
1
04/02/15 07:30
04/02/15 19:22
7440-42-8
ND
ug/L
0.080
0.024
1
04/02/15 07:30
04/02/15 19:22
7440-43-9
933
ug/L
40.0
16.0
1
04/02/15 07:30
04/02/15 19:22
7440-70-2
3.1
ug/L
0.50
0.17
1
04/02/15 07:30
04/02/15 19:22
7440-47-3
1.2
ug/L
0.50
0.13
1
04/02/15 07:30
04/02/15 19:22
7440-48-4
ND
ug/L
1.0
0.21
1
04/02/15 07:30
04/02/15 19:22
7440-50-8
1720
ug/L
50.0
13.7
1
04/02/15 07:30
04/02/15 19:22
7439-89-6
0.25
ug/L
0.10
0.046
1
04/02/15 07:30
04/02/15 19:22
7439-92-1
486
ug/L
10.0
3.2
1
04/02/15 07:30
04/02/15 19:22
7439-95-4
21.2
ug/L
0.50
0.24
1
04/02/15 07:30
04/02/15 19:22
7439-96-5
0.84
ug/L
0.50
0.094
1
04/02/15 07:30
04/02/15 19:22
7439-98-7
1.1
ug/L
0.50
0.16
1
04/02/15 07:30
04/02/15 19:22
7440-02-0
679
ug/L
50.0
11.7
1
04/02/15 07:30
04/02/15 19:22
7440-09-7
ND
ug/L
0.50
0.20
1
04/02/15 07:30
04/02/15 19:22
7782-49-2
244
ug/L
50.0
16.3
1
04/02/15 07:30
04/02/15 19:22
7440-23-5
2.8
ug/L
0.50
0.13
1
04/02/15 07:30
04/02/15 19:22
7440-24-6
ND
ug/L
0.10
0.015
1
04/02/15 07:30
04/02/15 19:22
7440-28-0
1.4
ug/L
1.0
0.28
1
04/02/15 07:30
04/02/15 19:22
7440-62-2
7.4
ug/L
5.0
2.4
1
04/02/15 07:30
04/02/15 19:22
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/01/15 09:20 04/01/15 13:50 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 42 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
P�SR18rWyte. Suite 100
y Huntersville, NC 28078
[phone]
Sample: 2015008642 SPLP Lab ID: 92243093003 Collected: 03/24/15 11:25 Received: 03/27/15 15:48 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\riil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/29/2015 08:01 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
ND
ug/L
10.0
3.0
1
04/15/15 22:19
04/17/15 18:17
7429-90-5
ND
ug/L
0.50
0.15
1
04/15/15 22:19
04/17/15 18:17
7440-36-0
ND
ug/L
0.50
0.11
1
04/15/15 22:19
04/17/15 18:17
7440-38-2
98.4
ug/L
0.30
0.081
1
04/15/15 22:19
04/17/15 18:17
7440-39-3
ND
ug/L
0.20
0.067
1
04/15/15 22:19
04/17/15 18:17
7440-41-7
65.5
ug/L
25.0
5.6
5
04/15/15 22:19
04/20/15 15:13
7440-42-8
ND
ug/L
0.080
0.024
1
04/15/15 22:19
04/17/15 18:17
7440-43-9
811
ug/L
40.0
16.0
1
04/15/15 22:19
04/17/15 18:17
7440-70-2
ND
ug/L
0.50
0.17
1
04/15/15 22:19
04/17/15 18:17
7440-47-3
0.93
ug/L
0.50
0.13
1
04/15/15 22:19
04/17/15 18:17
7440-48-4
3.6
ug/L
1.0
0.21
1
04/15/15 22:19
04/17/15 18:17
7440-50-8
ND
ug/L
50.0
13.7
1
04/15/15 22:19
04/17/15 18:17
7439-89-6
ND
ug/L
0.10
0.046
1
04/15/15 22:19
04/17/15 18:17
7439-92-1
350
ug/L
10.0
3.2
1
04/15/15 22:19
04/17/15 18:17
7439-95-4
118
ug/L
0.50
0.24
1
04/15/15 22:19
04/17/15 18:17
7439-96-5
ND
ug/L
0.50
0.094
1
04/15/15 22:19
04/17/15 18:17
7439-98-7
1.7
ug/L
0.50
0.16
1
04/15/15 22:19
04/17/15 18:17
7440-02-0
74.3
ug/L
50.0
11.7
1
04/15/15 22:19
04/17/15 18:17
7440-09-7
ND
ug/L
0.50
0.20
1
04/15/15 22:19
04/17/15 18:17
7782-49-2
1640
ug/L
50.0
16.3
1
04/15/15 22:19
04/17/15 18:17
7440-23-5
7.0
ug/L
0.50
0.13
1
04/15/15 22:19
04/17/15 18:17
7440-24-6
ND
ug/L
0.10
0.015
1
04/15/15 22:19
04/17/15 18:17
7440-28-0
ND
ug/L
1.0
0.28
1
04/15/15 22:19
04/17/15 18:17
7440-62-2
18.0
ug/L
5.0
2.4
1
04/15/15 22:19
04/17/15 18:17
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/16/15 08:58 04/16/15 20:01 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 43 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
Pggmirpyt.. Suite 100
y Huntersville, NC 28078
[phone]
Sample: 2015008643 SPLP Lab ID: 92243093004 Collected: 03/24/15 11:45 Received: 03/27/15 15:48 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\riil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/29/2015 08:01 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
ND
ug/L
10.0
3.0
1
04/15/15 22:19
04/17/15 18:55
7429-90-5
ND
ug/L
0.50
0.15
1
04/15/15 22:19
04/17/15 18:55
7440-36-0
ND
ug/L
0.50
0.11
1
04/15/15 22:19
04/17/15 18:55
7440-38-2
118
ug/L
0.30
0.081
1
04/15/15 22:19
04/17/15 18:55
7440-39-3
ND
ug/L
0.20
0.067
1
04/15/15 22:19
04/17/15 18:55
7440-41-7
44.9
ug/L
25.0
5.6
5
04/15/15 22:19
04/20/15 15:18
7440-42-8
ND
ug/L
0.080
0.024
1
04/15/15 22:19
04/17/15 18:55
7440-43-9
341
ug/L
40.0
16.0
1
04/15/15 22:19
04/17/15 18:55
7440-70-2
ND
ug/L
0.50
0.17
1
04/15/15 22:19
04/17/15 18:55
7440-47-3
3.3
ug/L
0.50
0.13
1
04/15/15 22:19
04/17/15 18:55
7440-48-4
1.3
ug/L
1.0
0.21
1
04/15/15 22:19
04/17/15 18:55
7440-50-8
ND
ug/L
50.0
13.7
1
04/15/15 22:19
04/17/15 18:55
7439-89-6
ND
ug/L
0.10
0.046
1
04/15/15 22:19
04/17/15 18:55
7439-92-1
449
ug/L
10.0
3.2
1
04/15/15 22:19
04/17/15 18:55
7439-95-4
95.0
ug/L
0.50
0.24
1
04/15/15 22:19
04/17/15 18:55
7439-96-5
ND
ug/L
0.50
0.094
1
04/15/15 22:19
04/17/15 18:55
7439-98-7
1.6
ug/L
0.50
0.16
1
04/15/15 22:19
04/17/15 18:55
7440-02-0
1260
ug/L
50.0
11.7
1
04/15/15 22:19
04/17/15 18:55
7440-09-7
ND
ug/L
0.50
0.20
1
04/15/15 22:19
04/17/15 18:55
7782-49-2
1880
ug/L
50.0
16.3
1
04/15/15 22:19
04/17/15 18:55
7440-23-5
5.2
ug/L
0.50
0.13
1
04/15/15 22:19
04/17/15 18:55
7440-24-6
ND
ug/L
0.10
0.015
1
04/15/15 22:19
04/17/15 18:55
7440-28-0
ND
ug/L
1.0
0.28
1
04/15/15 22:19
04/17/15 18:55
7440-62-2
20.4
ug/L
5.0
2.4
1
04/15/15 22:19
04/17/15 18:55
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/16/15 08:58 04/16/15 20:03 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 44 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
P369%f� 6fytie. Suite 100
y Huntersville, NC 28078
[phone]
Sample: 2015008648 SPLP Lab ID: 92243093005 Collected: 03/25/15 12:55 Received: 03/27/15 15:48 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/29/2015 08:01 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
12.4
ug/L
10.0
3.0
1
04/15/15 22:19
04/17/15 18:59
7429-90-5
ND
ug/L
0.50
0.15
1
04/15/15 22:19
04/17/15 18:59
7440-36-0
ND
ug/L
0.50
0.11
1
04/15/15 22:19
04/17/15 18:59
7440-38-2
65.7
ug/L
0.30
0.081
1
04/15/15 22:19
04/17/15 18:59
7440-39-3
ND
ug/L
0.20
0.067
1
04/15/15 22:19
04/17/15 18:59
7440-41-7
55.6
ug/L
25.0
5.6
5
04/15/15 22:19
04/20/15 15:22
7440-42-8
ND
ug/L
0.080
0.024
1
04/15/15 22:19
04/17/15 18:59
7440-43-9
123
ug/L
40.0
16.0
1
04/15/15 22:19
04/17/15 18:59
7440-70-2
ND
ug/L
0.50
0.17
1
04/15/15 22:19
04/17/15 18:59
7440-47-3
ND
ug/L
0.50
0.13
1
04/15/15 22:19
04/17/15 18:59
7440-48-4
3.1
ug/L
1.0
0.21
1
04/15/15 22:19
04/17/15 18:59
7440-50-8
ND
ug/L
50.0
13.7
1
04/15/15 22:19
04/17/15 18:59
7439-89-6
ND
ug/L
0.10
0.046
1
04/15/15 22:19
04/17/15 18:59
7439-92-1
65.9
ug/L
10.0
3.2
1
04/15/15 22:19
04/17/15 18:59
7439-95-4
11.7
ug/L
0.50
0.24
1
04/15/15 22:19
04/17/15 18:59
7439-96-5
ND
ug/L
0.50
0.094
1
04/15/15 22:19
04/17/15 18:59
7439-98-7
1.7
ug/L
0.50
0.16
1
04/15/15 22:19
04/17/15 18:59
7440-02-0
71.1
ug/L
50.0
11.7
1
04/15/15 22:19
04/17/15 18:59
7440-09-7
ND
ug/L
0.50
0.20
1
04/15/15 22:19
04/17/15 18:59
7782-49-2
1130
ug/L
50.0
16.3
1
04/15/15 22:19
04/17/15 18:59
7440-23-5
2.5
ug/L
0.50
0.13
1
04/15/15 22:19
04/17/15 18:59
7440-24-6
ND
ug/L
0.10
0.015
1
04/15/15 22:19
04/17/15 18:59
7440-28-0
ND
ug/L
1.0
0.28
1
04/15/15 22:19
04/17/15 18:59
7440-62-2
22.8
ug/L
5.0
2.4
1
04/15/15 22:19
04/17/15 18:59
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/16/15 08:58 04/16/15 20:05 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 45 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
P�S�06Jf3irWyte. Suite 100
y Huntersville, NC 28078
[phone]
Sample: 2015008651 SPLP Lab ID: 92243093006 Collected: 03/25/15 15:40 Received: 03/27/15 15:48 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\riil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/29/2015 08:01 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
976
ug/L
10.0
3.0
1
04/15/15 22:19
04/17/15 19:04
7429-90-5
ND
ug/L
0.50
0.15
1
04/15/15 22:19
04/17/15 19:04
7440-36-0
ND
ug/L
0.50
0.11
1
04/15/15 22:19
04/17/15 19:04
7440-38-2
116
ug/L
0.30
0.081
1
04/15/15 22:19
04/17/15 19:04
7440-39-3
ND
ug/L
0.20
0.067
1
04/15/15 22:19
04/17/15 19:04
7440-41-7
56.3
ug/L
5.0
1.1
1
04/15/15 22:19
04/20/15 15:27
7440-42-8
ND
ug/L
0.080
0.024
1
04/15/15 22:19
04/17/15 19:04
7440-43-9
325
ug/L
40.0
16.0
1
04/15/15 22:19
04/17/15 19:04
7440-70-2
1.3
ug/L
0.50
0.17
1
04/15/15 22:19
04/17/15 19:04
7440-47-3
5.7
ug/L
0.50
0.13
1
04/15/15 22:19
04/17/15 19:04
7440-48-4
1.6
ug/L
1.0
0.21
1
04/15/15 22:19
04/17/15 19:04
7440-50-8
687
ug/L
50.0
13.7
1
04/15/15 22:19
04/17/15 19:04
7439-89-6
0.48
ug/L
0.10
0.046
1
04/15/15 22:19
04/17/15 19:04
7439-92-1
207
ug/L
10.0
3.2
1
04/15/15 22:19
04/17/15 19:04
7439-95-4
118
ug/L
0.50
0.24
1
04/15/15 22:19
04/17/15 19:04
7439-96-5
ND
ug/L
0.50
0.094
1
04/15/15 22:19
04/17/15 19:04
7439-98-7
1.5
ug/L
0.50
0.16
1
04/15/15 22:19
04/17/15 19:04
7440-02-0
815
ug/L
50.0
11.7
1
04/15/15 22:19
04/17/15 19:04
7440-09-7
ND
ug/L
0.50
0.20
1
04/15/15 22:19
04/17/15 19:04
7782-49-2
1530
ug/L
50.0
16.3
1
04/15/15 22:19
04/17/15 19:04
7440-23-5
10
ug/L
0.50
0.13
1
04/15/15 22:19
04/17/15 19:04
7440-24-6
ND
ug/L
0.10
0.015
1
04/15/15 22:19
04/17/15 19:04
7440-28-0
1.5
ug/L
1.0
0.28
1
04/15/15 22:19
04/20/15 15:27
7440-62-2
30.8
ug/L
5.0
2.4
1
04/15/15 22:19
04/17/15 19:04
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/16/15 08:58 04/16/15 20:13 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 46 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
P� %'0 Iirwyte. Suite 100
y Huntersville, NC 28078
[phone]
Sample: 2015008642 Lab ID: 92243093007 Collected: 03/24/15 11:25 Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 04/29/2015 08:01 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
30500
mg/kg
29.0
14.5
5
04/02/15 20:00
04/09/15 03:15
7429-90-5
D4
118
mg/kg
2.9
1.5
5
04/02/15 20:00
04/09/15 03:15
7440-39-3
D3
1.1
mg/kg
0.29
0.15
5
04/02/15 20:00
04/09/15 03:15
7440-41-7
D3
18.3
mg/kg
14.5
7.3
5
04/02/15 20:00
04/09/15 03:15
7440-42-8
D3
131J
mg/kg
145
72.6
5
04/02/15 20:00
04/09/15 03:15
7440-70-2
D3
37.8
mg/kg
1.5
0.73
5
04/02/15 20:00
04/09/15 03:15
7440-47-3
D3
37.7
mg/kg
1.5
0.73
5
04/02/15 20:00
04/09/15 03:15
7440-50-8
D3
18000
mg/kg
11.6
5.8
5
04/02/15 20:00
04/09/15 03:15
7439-89-6
D3
4040
mg/kg
145
72.6
5
04/02/15 20:00
04/09/15 03:15
7439-95-4
D3
830
mg/kg
1.5
0.73
5
04/02/15 20:00
04/09/15 03:15
7439-96-5
D3
ND
mg/kg
2.9
1.5
5
04/02/15 20:00
04/09/15 03:15
7439-98-7
D3
28.4
mg/kg
1.5
0.73
5
04/02/15 20:00
04/09/15 03:15
7440-02-0
D3
971
mg/kg
290
145
5
04/02/15 20:00
04/09/15 03:15
7440-09-7
D3
ND
mg/kg
290
145
5
04/02/15 20:00
04/09/15 03:15
7440-23-5
D3
4.4
mg/kg
2.9
1.5
5
04/02/15 20:00
04/09/15 03:15
7440-24-6
D3
51.2
mg/kg
5.8
2.9
5
04/02/15 20:00
04/09/15 03:15
7440-66-6
D3
Analytical
Method: EPA 6020
Preparation Method: EPA 3050
ND
mg/kg
2.9
1.5
50
04/02/15 20:00
04/06/15 08:51
7440-36-0
D3,N2
2.2J
mg/kg
2.9
1.5
50
04/02/15 20:00
04/06/15 08:51
7440-38-2
D3
ND
mg/kg
0.35
0.17
50
04/02/15 20:00
04/06/15 08:51
7440-43-9
D3
65.3
mg/kg
2.9
1.5
50
04/02/15 20:00
04/06/15 08:51
7440-48-4
D3
10.8
mg/kg
2.9
1.5
50
04/02/15 20:00
04/06/15 08:51
7439-92-1
D3
3.4
mg/kg
2.9
1.5
50
04/02/15 20:00
04/06/15 08:51
7782-49-2
D3
ND
mg/kg
2.9
1.5
50
04/02/15 20:00
04/06/15 08:51
7440-28-0
D3
39.0
mg/kg
2.9
1.5
50
04/02/15 20:00
04/06/15 08:51
7440-62-2
D3
Analytical
Method: EPA 7471
Preparation Method: EPA 7471
ND
mg/kg 0.010
0.0050
1
04/04/15 19:50
04/07/15 08:44
7439-97-6
Analytical
Method: ASTM D2974-87
18.0
%
0.10
0.10
1
04/04/15 20:01
Analytical
Method: EPA 9045
6.3
Std. Units
0.10
0.10
1
04/02/15 09:35
Analytical
Method: EPA 300.0 Leachate Method/Date:
EPA 1312; 04/02/15
18:00
6.0
mg/L
2.4
1.2
1
04/07/1519:26
14808-79-8
B
Analytical
Method: EPA 353.2 Leachate Method/Date:
EPA 1312; 04/02/15
18:00
ND
mg/L
0.24
0.24
1
04/09/1519:34
H1
Analytical
Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 04/02/15 18:00
ND
mg/L
6.1
3.0
1
04/08/15 02:34
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 47 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
PAR18rWyte. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
Sample: 2015008642 Lab ID: 92243093007 Collected: 03/24/15 11:25 Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
306
153
5
04/02/15 21:27
16887-00-6 D3
Sulfate
ND mg/kg
306
153
5
04/02/15 21:27
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
30.6
15.3
5
04/02/15 21:27
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
2390 mg/kg
736
368
1
04/15/15 07:32
7440-44-0
Total Organic Carbon
2600 mg/kg
735
368
1
04/15/15 07:39
7440-44-0
Total Organic Carbon
2530 mg/kg
732
366
1
04/15/15 07:46
7440-44-0
Total Organic Carbon
2420 mg/kg
727
364
1
04/15/15 07:53
7440-44-0
Mean Total Organic Carbon
2490 mg/kg
733
366
1
04/15/15 07:32
7440-44-0
Surrogates
RSD%
3.9 %
1
04/15/15 07:32
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc..
Page 48 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
P�S�06}�i WYte. Suite 100
y Huntersville, NC 28078
[phone]
Sample: 2015008643 Lab ID: 92243093008 Collected: 03/24/15 11:45 Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 04/29/2015 08:01 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
21200
mg/kg
27.1
13.6
5
04/02/15 20:00
04/09/15 03:19
7429-90-5
D3
88.3
mg/kg
2.7
1.4
5
04/02/15 20:00
04/09/15 03:19
7440-39-3
D3
1.3
mg/kg
0.27
0.14
5
04/02/15 20:00
04/09/15 03:19
7440-41-7
D3
29.8
mg/kg
13.6
6.8
5
04/02/15 20:00
04/09/15 03:19
7440-42-8
D3
607
mg/kg
136
67.9
5
04/02/15 20:00
04/09/15 03:19
7440-70-2
D3
14.1
mg/kg
1.4
0.68
5
04/02/15 20:00
04/09/15 03:19
7440-47-3
D3
44.9
mg/kg
1.4
0.68
5
04/02/15 20:00
04/09/15 03:19
7440-50-8
D3
32300
mg/kg
10.9
5.4
5
04/02/15 20:00
04/09/15 03:19
7439-89-6
D4
8970
mg/kg
136
67.9
5
04/02/15 20:00
04/09/15 03:19
7439-95-4
D3
126
mg/kg
1.4
0.68
5
04/02/15 20:00
04/09/15 03:19
7439-96-5
D3
ND
mg/kg
2.7
1.4
5
04/02/15 20:00
04/09/15 03:19
7439-98-7
D3
12.5
mg/kg
1.4
0.68
5
04/02/15 20:00
04/09/15 03:19
7440-02-0
D3
7790
mg/kg
271
136
5
04/02/15 20:00
04/09/15 03:19
7440-09-7
D3
ND
mg/kg
271
136
5
04/02/15 20:00
04/09/15 03:19
7440-23-5
D3
3.1
mg/kg
2.7
1.4
5
04/02/15 20:00
04/09/15 03:19
7440-24-6
D3
83.2
mg/kg
5.4
2.7
5
04/02/15 20:00
04/09/15 03:19
7440-66-6
D3
Analytical
Method: EPA 6020
Preparation Method: EPA 3050
ND
mg/kg
2.7
1.4
50
04/02/15 20:00
04/06/15 08:53
7440-36-0
D3,N2
3.4
mg/kg
2.7
1.4
50
04/02/15 20:00
04/06/15 08:53
7440-38-2
D3
ND
mg/kg
0.33
0.16
50
04/02/15 20:00
04/06/15 08:53
7440-43-9
D3
9.6
mg/kg
2.7
1.4
50
04/02/15 20:00
04/06/15 08:53
7440-48-4
D3
4.0
mg/kg
2.7
1.4
50
04/02/15 20:00
04/06/15 08:53
7439-92-1
D3
5.6
mg/kg
2.7
1.4
50
04/02/15 20:00
04/06/15 08:53
7782-49-2
D3
ND
mg/kg
2.7
1.4
50
04/02/15 20:00
04/06/15 08:53
7440-28-0
D3
21.2
mg/kg
2.7
1.4
50
04/02/15 20:00
04/06/15 08:53
7440-62-2
D3
Analytical
Method: EPA 7471
Preparation Method: EPA 7471
ND
mg/kg 0.0086
0.0043
1
04/04/15 19:50
04/07/15 08:51
7439-97-6
Analytical
Method: ASTM D2974-87
6.6
%
0.10
0.10
1
04/04/15 20:01
D6
Analytical
Method: EPA 9045
6.4
Std. Units
0.10
0.10
1
04/02/15 09:35
Analytical
Method: EPA 300.0 Leachate Method/Date:
EPA 1312; 04/02/15
18:00
6.6
mg/L
2.1
1.1
1
04/07/1519:40
14808-79-8
B
Analytical
Method: EPA 353.2 Leachate Method/Date:
EPA 1312; 04/02/15
18:00
ND
mg/L
0.21
0.21
1
04/09/1519:35
H1
Analytical
Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 04/02/15 18:00
ND
mg/L
5.4
2.7
1
04/08/15 02:35
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 49 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
PARVrWyte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
Sample: 2015008643 Lab ID: 92243093008 Collected: 03/24/15 11:45 Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
269
135
5
04/02/15 21:49
16887-00-6 D3
Sulfate
ND mg/kg
269
135
5
04/02/15 21:49
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
26.9
13.5
5
04/02/15 21:49
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
ND mg/kg
642
321
1
04/15/15 08:01
7440-44-0
Total Organic Carbon
362J mg/kg
640
320
1
04/15/15 08:07
7440-44-0
Total Organic Carbon
ND mg/kg
642
321
1
04/15/15 08:13
7440-44-0
Total Organic Carbon
334J mg/kg
643
321
1
04/15/15 08:19
7440-44-0
Mean Total Organic Carbon
ND mg/kg
642
321
1
04/15/15 08:01
7440-44-0
Surrogates
RSD%
11.3 %
1
04/15/15 08:01
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc..
Page 50 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
PAR816fyte. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015008648 Lab ID: 92243093009 Collected: 03/25/15 12:55 Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 04/29/2015 08:01 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
17800
mg/kg
39.5
19.7
5
04/02/15 20:00
04/09/15 03:24
7429-90-5
D3
29.2
mg/kg
3.9
2.0
5
04/02/15 20:00
04/09/15 03:24
7440-39-3
D3
1.2
mg/kg
0.39
0.20
5
04/02/15 20:00
04/09/15 03:24
7440-41-7
D3
22.6
mg/kg
19.7
9.9
5
04/02/15 20:00
04/09/15 03:24
7440-42-8
D3
ND
mg/kg
197
98.7
5
04/02/15 20:00
04/09/15 03:24
7440-70-2
D3
7.9
mg/kg
2.0
0.99
5
04/02/15 20:00
04/09/15 03:24
7440-47-3
D3
34.4
mg/kg
2.0
0.99
5
04/02/15 20:00
04/09/15 03:24
7440-50-8
D3
24200
mg/kg
15.8
7.9
5
04/02/15 20:00
04/09/15 03:24
7439-89-6
D3
2470
mg/kg
197
98.7
5
04/02/15 20:00
04/09/15 03:24
7439-95-4
D3
197
mg/kg
2.0
0.99
5
04/02/15 20:00
04/09/15 03:24
7439-96-5
D3
ND
mg/kg
3.9
2.0
5
04/02/15 20:00
04/09/15 03:24
7439-98-7
D3
7.4
mg/kg
2.0
0.99
5
04/02/15 20:00
04/09/15 03:24
7440-02-0
D3
1190
mg/kg
395
197
5
04/02/15 20:00
04/09/15 03:24
7440-09-7
D3
ND
mg/kg
395
197
5
04/02/15 20:00
04/09/15 03:24
7440-23-5
D3
ND
mg/kg
3.9
2.0
5
04/02/15 20:00
04/09/15 03:24
7440-24-6
D3
57.0
mg/kg
7.9
3.9
5
04/02/15 20:00
04/09/15 03:24
7440-66-6
D3
Analytical
Method: EPA 6020
Preparation Method: EPA 3050
ND
mg/kg
3.9
2.0
50
04/02/15 20:00
04/06/15 08:55
7440-36-0
D3,N2
4.6
mg/kg
3.9
2.0
50
04/02/15 20:00
04/06/15 08:55
7440-38-2
D3
ND
mg/kg
0.47
0.24
50
04/02/15 20:00
04/06/15 08:55
7440-43-9
D3
6.8
mg/kg
3.9
2.0
50
04/02/15 20:00
04/06/15 08:55
7440-48-4
D3
ND
mg/kg
3.9
2.0
50
04/02/15 20:00
04/06/15 08:55
7439-92-1
D3
7.1
mg/kg
3.9
2.0
50
04/02/15 20:00
04/06/15 08:55
7782-49-2
D3
ND
mg/kg
3.9
2.0
50
04/02/15 20:00
04/06/15 08:55
7440-28-0
D3
14.2
mg/kg
3.9
2.0
50
04/02/15 20:00
04/06/15 08:55
7440-62-2
D3
Analytical
Method: EPA 7471
Preparation Method: EPA 7471
ND
mg/kg 0.012
0.0062
1
04/04/15 19:50
04/07/15 08:53
7439-97-6
Analytical
Method: ASTM D2974-87
37.1
%
0.10
0.10
1
04/04/15 20:01
Analytical
Method: EPA 9045
6.0
Std. Units
0.10
0.10
1
04/03/15 10:15
Analytical
Method: EPA 300.0 Leachate Method/Date:
EPA 1312; 04/02/15
18:00
3.3
mg/L
3.2
1.6
1
04/07/15 20:21
14808-79-8
B
Analytical
Method: EPA 353.2 Leachate Method/Date:
EPA 1312; 04/02/15
18:00
ND
mg/L
0.32
0.32
1
04/09/1519:37
H1
Analytical
Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 04/02/15 18:00
ND
mg/L
8.0
4.0
1
04/08/15 02:35
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 51 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
PAR16rWyte. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
Sample: 2015008648 Lab ID: 92243093009 Collected: 03/25/15 12:55 Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
394
197
5
04/02/15 22:10
16887-00-6 D3
Sulfate
ND mg/kg
394
197
5
04/02/15 22:10
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
39.4
19.7
5
04/02/15 22:10
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
1460 mg/kg
954
477
1
04/15/15 09:14
7440-44-0
Total Organic Carbon
1750 mg/kg
953
476
1
04/15/15 09:21
7440-44-0
Total Organic Carbon
1490 mg/kg
964
482
1
04/15/15 09:28
7440-44-0
Total Organic Carbon
1310 mg/kg
962
481
1
04/15/15 09:35
7440-44-0
Mean Total Organic Carbon
1500 mg/kg
958
479
1
04/15/15 09:14
7440-44-0
Surrogates
RSD%
12.2 %
1
04/15/15 09:14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc..
Page 52 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
P369Oit816fy �ie. Suite 100
y Huntersville, NC 28078
[phone]
Sample: 2015008651 Lab ID: 92243093010 Collected: 03/25/15 15:40 Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 04/29/2015 08:01 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
35600
mg/kg
29.3
14.7
5
04/02/15 20:00
04/09/15 03:28
7429-90-5
D4
255
mg/kg
2.9
1.5
5
04/02/15 20:00
04/09/15 03:28
7440-39-3
D3
2.2
mg/kg
0.29
0.15
5
04/02/15 20:00
04/09/15 03:28
7440-41-7
D3
45.0
mg/kg
14.7
7.3
5
04/02/15 20:00
04/09/15 03:28
7440-42-8
D3
632
mg/kg
147
73.3
5
04/02/15 20:00
04/09/15 03:28
7440-70-2
D3
73.5
mg/kg
1.5
0.73
5
04/02/15 20:00
04/09/15 03:28
7440-47-3
D3
129
mg/kg
1.5
0.73
5
04/02/15 20:00
04/09/15 03:28
7440-50-8
D3
48500
mg/kg
11.7
5.9
5
04/02/15 20:00
04/09/15 03:28
7439-89-6
D4
9520
mg/kg
147
73.3
5
04/02/15 20:00
04/09/15 03:28
7439-95-4
D3
631
mg/kg
1.5
0.73
5
04/02/15 20:00
04/09/15 03:28
7439-96-5
D3
ND
mg/kg
2.9
1.5
5
04/02/15 20:00
04/09/15 03:28
7439-98-7
D3
48.5
mg/kg
1.5
0.73
5
04/02/15 20:00
04/09/15 03:28
7440-02-0
D3
6480
mg/kg
293
147
5
04/02/15 20:00
04/09/15 03:28
7440-09-7
D3
ND
mg/kg
293
147
5
04/02/15 20:00
04/09/15 03:28
7440-23-5
D3
33.1
mg/kg
2.9
1.5
5
04/02/15 20:00
04/09/15 03:28
7440-24-6
D3
90.9
mg/kg
5.9
2.9
5
04/02/15 20:00
04/09/15 03:28
7440-66-6
D3
Analytical
Method: EPA 6020
Preparation Method: EPA 3050
ND
mg/kg
2.9
1.5
50
04/02/15 20:00
04/06/15 09:05
7440-36-0
D3,N2
7.0
mg/kg
2.9
1.5
50
04/02/15 20:00
04/06/15 09:05
7440-38-2
D3
ND
mg/kg
0.35
0.18
50
04/02/15 20:00
04/06/15 09:05
7440-43-9
D3
59.6
mg/kg
2.9
1.5
50
04/02/15 20:00
04/06/15 09:05
7440-48-4
D3
15.3
mg/kg
2.9
1.5
50
04/02/15 20:00
04/06/15 09:05
7439-92-1
D3
4.2
mg/kg
2.9
1.5
50
04/02/15 20:00
04/06/15 09:05
7782-49-2
D3
ND
mg/kg
2.9
1.5
50
04/02/15 20:00
04/06/15 09:05
7440-28-0
D3
62.4
mg/kg
2.9
1.5
50
04/02/15 20:00
04/06/15 09:05
7440-62-2
D3
Analytical
Method: EPA 7471
Preparation Method: EPA 7471
0.029
mg/kg 0.0097
0.0048
1
04/04/15 19:50
04/07/15 08:55
7439-97-6
Analytical
Method: ASTM D2974-87
16.8
%
0.10
0.10
1
04/04/15 20:01
Analytical
Method: EPA 9045
6.4
Std. Units
0.10
0.10
1
04/03/15 10:15
Analytical
Method: EPA 300.0 Leachate Method/Date:
EPA 1312; 04/02/15
18:00
3.9
mg/L
2.4
1.2
1
04/07/15 20:34
14808-79-8
B
Analytical
Method: EPA 353.2 Leachate Method/Date:
EPA 1312; 04/02/15
18:00
ND
mg/L
0.24
0.24
1
04/09/1519:38
H1
Analytical
Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 04/02/15 18:00
ND
mg/L
6.0
3.0
1
04/08/15 02:37
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 53 of 100

aceAnaiXical
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ANALYTICAL RESULTS
Pace Analytical Services, Inc.
PgRoAirpyt.. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
Sample: 2015008651 Lab ID: 92243093010 Collected: 03/25/15 15:40 Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
302
151
5
04/02/15 22:31
16887-00-6 D3
Sulfate
ND mg/kg
302
151
5
04/02/15 22:31
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
30.2
15.1
5
04/02/15 22:31
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
10500 mg/kg
1490
745
1
04/15/15 09:42
7440-44-0
Total Organic Carbon
15600 mg/kg
1480
742
1
04/15/15 09:49
7440-44-0
Total Organic Carbon
7690 mg/kg
1490
746
1
04/15/15 09:55
7440-44-0
Total Organic Carbon
6600 mg/kg
1500
751
1
04/15/15 10:01
7440-44-0
Mean Total Organic Carbon
10100 mg/kg
1490
746
1
04/15/15 09:42
7440-44-0
Surrogates
RSD%
39.8 %
1
04/15/15 09:42
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc..
Page 54 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
P3690hwfyte. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
Sample: 2015008645
Lab ID:
92243093011 Collected:
03/25/15 11:15
Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA 3050
Aluminum
16800
mg/kg
6.0
3.0
1
04/02/15 20:00
04/05/15 05:20
7429-90-5
Barium
93.5
mg/kg
0.60
0.30
1
04/02/15 20:00
04/05/15 05:20
7440-39-3
Beryllium
0.53
mg/kg
0.30
0.15
5
04/02/15 20:00
04/09/15 03:32
7440-41-7
D3
Boron
25.5
mg/kg
14.9
7.4
5
04/02/15 20:00
04/09/15 03:32
7440-42-8
D3
Calcium
102
mg/kg
29.8
14.9
1
04/02/15 20:00
04/05/15 05:20
7440-70-2
Chromium
17.2
mg/kg
1.5
0.74
5
04/02/15 20:00
04/09/15 03:32
7440-47-3
D3
Copper
10.0
mg/kg
1.5
0.74
5
04/02/15 20:00
04/09/15 03:32
7440-50-8
D3
Iron
27000
mg/kg
11.9
6.0
5
04/02/15 20:00
04/09/15 03:32
7439-89-6
D4
Magnesium
762
mg/kg
29.8
14.9
1
04/02/15 20:00
04/05/15 05:20
7439-95-4
Manganese
135
mg/kg
1.5
0.74
5
04/02/15 20:00
04/09/15 03:32
7439-96-5
D3
Molybdenum
ND
mg/kg
0.60
0.30
1
04/02/15 20:00
04/05/15 05:20
7439-98-7
Nickel
3.6
mg/kg
0.30
0.15
1
04/02/15 20:00
04/05/15 05:20
7440-02-0
Potassium
687
mg/kg
59.5
29.8
1
04/02/15 20:00
04/05/15 05:20
7440-09-7
Sodium
ND
mg/kg
298
149
5
04/02/15 20:00
04/09/15 03:32
7440-23-5
D3
Strontium
2.3
mg/kg
0.60
0.30
1
04/02/15 20:00
04/05/15 05:20
7440-24-6
Zinc
24.1
mg/kg
1.2
0.60
1
04/02/15 20:00
04/05/15 05:20
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA 3050
Antimony
ND
mg/kg
3.0
1.5
50
04/02/15 20:00
04/06/15 09:07
7440-36-0
D3,N2
Arsenic
2.9J
mg/kg
3.0
1.5
50
04/02/15 20:00
04/06/15 09:07
7440-38-2
D3
Cadmium
ND
mg/kg
0.36
0.18
50
04/02/15 20:00
04/06/15 09:07
7440-43-9
D3
Cobalt
7.7
mg/kg
3.0
1.5
50
04/02/15 20:00
04/06/15 09:07
7440-48-4
D3
Lead
13.1
mg/kg
3.0
1.5
50
04/02/15 20:00
04/06/15 09:07
7439-92-1
D3
Selenium
1.91
mg/kg
3.0
1.5
50
04/02/15 20:00
04/06/15 09:07
7782-49-2
D3
Thallium
ND
mg/kg
3.0
1.5
50
04/02/15 20:00
04/06/15 09:07
7440-28-0
D3
Vanadium
28.8
mg/kg
3.0
1.5
50
04/02/15 20:00
04/06/15 09:07
7440-62-2
D3
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA 7471
Mercury
0.024
mg/kg 0.0096
0.0048
1
04/04/15 19:50
04/07/15 08:57
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
14.0
%
0.10
0.10
1
04/04/15 20:02
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
4.5
Std. Units
0.10
0.10
1
04/03/15 10:15
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
295
147
5
04/02/15 22:53
16887-00-6
D3
Sulfate
ND
mg/kg
295
147
5
04/02/15 22:53
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
29.5
14.7
5
04/02/15 22:53
14797-55-8
H3
Date: 04/29/2015 08:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 55 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
P3690 �irwyte. Suite 100
y Huntersville, NC 28078
[phone]
Sample: 2015008645
Lab ID:
92243093011
Collected:
03/25/15 11:15
Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
5210
mg/kg
955
478
1
04/15/15 10:07
7440-44-0
Total Organic Carbon
6060
mg/kg
950
475
1
04/15/15 10:14
7440-44-0
Total Organic Carbon
5550
mg/kg
955
477
1
04/15/15 10:19
7440-44-0
Total Organic Carbon
5390
mg/kg
950
475
1
04/15/15 10:25
7440-44-0
Mean Total Organic Carbon
5550
mg/kg
952
476
1
04/15/15 10:07
7440-44-0
Surrogates
RSD%
6.7
%
1
04/15/1510:07
Date: 04/29/2015 08:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 56 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
P36907 WYte. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
Sample: 2015008646
Lab ID:
92243093012 Collected:
03/25/15 14:35
Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
24000
mg/kg
25.9
12.9
5
04/02/15 20:00
04/09/15 03:36
7429-90-5
D3
Barium
136
mg/kg
2.6
1.3
5
04/02/15 20:00
04/09/15 03:36
7440-39-3
D3
Beryllium
1.6
mg/kg
0.26
0.13
5
04/02/15 20:00
04/09/15 03:36
7440-41-7
D3
Boron
31.3
mg/kg
12.9
6.5
5
04/02/15 20:00
04/09/15 03:36
7440-42-8
D3
Calcium
214
mg/kg
129
64.7
5
04/02/15 20:00
04/09/15 03:36
7440-70-2
D3
Chromium
12.7
mg/kg
1.3
0.65
5
04/02/15 20:00
04/09/15 03:36
7440-47-3
D3
Copper
46.5
mg/kg
1.3
0.65
5
04/02/15 20:00
04/09/15 03:36
7440-50-8
D3
Iron
32800
mg/kg
10.3
5.2
5
04/02/15 20:00
04/09/15 03:36
7439-89-6
D4
Magnesium
7800
mg/kg
129
64.7
5
04/02/15 20:00
04/09/15 03:36
7439-95-4
D3
Manganese
325
mg/kg
1.3
0.65
5
04/02/15 20:00
04/09/15 03:36
7439-96-5
D3
Molybdenum
ND
mg/kg
2.6
1.3
5
04/02/15 20:00
04/09/15 03:36
7439-98-7
D3
Nickel
9.7
mg/kg
1.3
0.65
5
04/02/15 20:00
04/09/15 03:36
7440-02-0
D3
Potassium
5630
mg/kg
259
129
5
04/02/15 20:00
04/09/15 03:36
7440-09-7
D3
Sodium
ND
mg/kg
259
129
5
04/02/15 20:00
04/09/15 03:36
7440-23-5
D3
Strontium
5.2
mg/kg
2.6
1.3
5
04/02/15 20:00
04/09/15 03:36
7440-24-6
D3
Zinc
81.2
mg/kg
5.2
2.6
5
04/02/15 20:00
04/09/15 03:36
7440-66-6
D3
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
2.6
1.3
50
04/02/15 20:00
04/06/15 09:09
7440-36-0
D3,N2
Arsenic
3.6
mg/kg
2.6
1.3
50
04/02/15 20:00
04/06/15 09:09
7440-38-2
D3
Cadmium
ND
mg/kg
0.31
0.16
50
04/02/15 20:00
04/06/15 09:09
7440-43-9
D3
Cobalt
16.4
mg/kg
2.6
1.3
50
04/02/15 20:00
04/06/15 09:09
7440-48-4
D3
Lead
10.4
mg/kg
2.6
1.3
50
04/02/15 20:00
04/06/15 09:09
7439-92-1
D3
Selenium
6.0
mg/kg
2.6
1.3
50
04/02/15 20:00
04/06/15 09:09
7782-49-2
D3
Thallium
ND
mg/kg
2.6
1.3
50
04/02/15 20:00
04/06/15 09:09
7440-28-0
D3
Vanadium
17.7
mg/kg
2.6
1.3
50
04/02/15 20:00
04/06/15 09:09
7440-62-2
D3
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
ND
mg/kg 0.0085
0.0042
1
04/04/15 19:50
04/07/15 09:00
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
4.0
%
0.10
0.10
1
04/04/15 20:02
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
5.9
Std. Units
0.10
0.10
1
04/03/15 10:15
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
258
129
5
04/02/15 23:14
16887-00-6
D3
Sulfate
ND
mg/kg
258
129
5
04/02/15 23:14
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
25.8
12.9
5
04/02/15 23:14
14797-55-8
H3
Date: 04/29/2015 08:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 57 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
P36908rwyte. Suite 100
y Huntersville, NC 28078
[phone]
Sample: 2015008646
Lab ID:
92243093012
Collected:
03/25/15 14:35
Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
4410
mg/kg
627
314
1
04/15/15 10:30
7440-44-0
Total Organic Carbon
4430
mg/kg
626
313
1
04/15/15 10:38
7440-44-0
Total Organic Carbon
5380
mg/kg
628
314
1
04/15/15 10:46
7440-44-0
Total Organic Carbon
3640
mg/kg
626
313
1
04/15/15 10:53
7440-44-0
Mean Total Organic Carbon
4460
mg/kg
627
313
1
04/15/15 10:30
7440-44-0
Surrogates
RSD%
15.9
%
1
04/15/1510:30
Date: 04/29/2015 08:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 58 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
P3690 �irwyte. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
Sample: 2015008647
Lab ID:
92243093013 Collected:
03/25/15 14:40
Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
13900
mg/kg
27.4
13.7
5
04/02/15 20:00
04/09/15 03:41
7429-90-5
D3
Barium
56.4
mg/kg
2.7
1.4
5
04/02/15 20:00
04/09/15 03:41
7440-39-3
D3
Beryllium
0.33
mg/kg
0.27
0.14
5
04/02/15 20:00
04/09/15 03:41
7440-41-7
D3
Boron
28.3
mg/kg
13.7
6.9
5
04/02/15 20:00
04/09/15 03:41
7440-42-8
D3
Calcium
437
mg/kg
137
68.5
5
04/02/15 20:00
04/09/15 03:41
7440-70-2
D3
Chromium
10.9
mg/kg
1.4
0.69
5
04/02/15 20:00
04/09/15 03:41
7440-47-3
D3
Copper
52.6
mg/kg
1.4
0.69
5
04/02/15 20:00
04/09/15 03:41
7440-50-8
D3
Iron
29900
mg/kg
11.0
5.5
5
04/02/15 20:00
04/09/15 03:41
7439-89-6
D4
Magnesium
6950
mg/kg
137
68.5
5
04/02/15 20:00
04/09/15 03:41
7439-95-4
D3
Manganese
109
mg/kg
1.4
0.69
5
04/02/15 20:00
04/09/15 03:41
7439-96-5
D3
Molybdenum
ND
mg/kg
2.7
1.4
5
04/02/15 20:00
04/09/15 03:41
7439-98-7
D3
Nickel
15.9
mg/kg
1.4
0.69
5
04/02/15 20:00
04/09/15 03:41
7440-02-0
D3
Potassium
5480
mg/kg
274
137
5
04/02/15 20:00
04/09/15 03:41
7440-09-7
D3
Sodium
ND
mg/kg
274
137
5
04/02/15 20:00
04/09/15 03:41
7440-23-5
D3
Strontium
3.6
mg/kg
2.7
1.4
5
04/02/15 20:00
04/09/15 03:41
7440-24-6
D3
Zinc
64.8
mg/kg
5.5
2.7
5
04/02/15 20:00
04/09/15 03:41
7440-66-6
D3
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
2.8
1.4
50
04/02/15 20:00
04/06/15 09:12
7440-36-0
D3,N2
Arsenic
3.2
mg/kg
2.8
1.4
50
04/02/15 20:00
04/06/15 09:12
7440-38-2
D3
Cadmium
ND
mg/kg
0.33
0.17
50
04/02/15 20:00
04/06/15 09:12
7440-43-9
D3
Cobalt
16.0
mg/kg
2.8
1.4
50
04/02/15 20:00
04/06/15 09:12
7440-48-4
D3
Lead
5.4
mg/kg
2.8
1.4
50
04/02/15 20:00
04/06/15 09:12
7439-92-1
D3
Selenium
5.3
mg/kg
2.8
1.4
50
04/02/15 20:00
04/06/15 09:12
7782-49-2
D3
Thallium
ND
mg/kg
2.8
1.4
50
04/02/15 20:00
04/06/15 09:12
7440-28-0
D3
Vanadium
13.5
mg/kg
2.8
1.4
50
04/02/15 20:00
04/06/15 09:12
7440-62-2
D3
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
ND
mg/kg 0.0085
0.0042
1
04/04/15 19:50
04/07/15 09:02
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
7.5
%
0.10
0.10
1
04/04/15 20:02
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
4.9
Std. Units
0.10
0.10
1
04/03/15 10:15
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
273
136
5
04/02/15 23:36
16887-00-6
D3
Sulfate
477
mg/kg
273
136
5
04/02/15 23:36
14808-79-8
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
27.3
13.6
5
04/02/15 23:36
14797-55-8
H3
Date: 04/29/2015 08:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 59 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
P3690nrwyte. Suite 100
y Huntersville, NC 28078
[phone]
Sample: 2015008647
Lab ID:
92243093013
Collected:
03/25/15 14:40
Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
4110
mg/kg
651
325
1
04/15/15 11:12
7440-44-0
Total Organic Carbon
4320
mg/kg
647
323
1
04/15/15 11:19
7440-44-0
Total Organic Carbon
4170
mg/kg
647
324
1
04/15/15 11:25
7440-44-0
Total Organic Carbon
3920
mg/kg
653
326
1
04/15/15 11:33
7440-44-0
Mean Total Organic Carbon
4130
mg/kg
649
325
1
04/15/15 11:12
7440-44-0
Surrogates
RSD%
4.0
%
1
04/15/1511:12
Date: 04/29/2015 08:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 60 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
P3690 �irwyte. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
Sample: 2015008649
Lab ID:
92243093014 Collected:
03/25/15 13:05
Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
17500
mg/kg
29.6
14.8
5
04/02/15 20:00
04/09/15 03:45
7429-90-5
D3
Barium
70.8
mg/kg
3.0
1.5
5
04/02/15 20:00
04/09/15 03:45
7440-39-3
D3
Beryllium
1.9
mg/kg
0.59
0.30
10
04/02/15 20:00
04/09/15 08:55
7440-41-7
D3
Boron
26AJ
mg/kg
29.6
14.8
10
04/02/15 20:00
04/09/15 08:55
7440-42-8
D3
Calcium
168
mg/kg
148
74.0
5
04/02/15 20:00
04/09/15 03:45
7440-70-2
D3
Chromium
12.6
mg/kg
3.0
1.5
10
04/02/15 20:00
04/09/15 08:55
7440-47-3
D3
Copper
98.9
mg/kg
3.0
1.5
10
04/02/15 20:00
04/09/15 08:55
7440-50-8
D3
Iron
24600
mg/kg
11.8
5.9
5
04/02/15 20:00
04/09/15 03:45
7439-89-6
D4
Magnesium
6040
mg/kg
148
74.0
5
04/02/15 20:00
04/09/15 03:45
7439-95-4
D3
Manganese
266
mg/kg
3.0
1.5
10
04/02/15 20:00
04/09/15 08:55
7439-96-5
D4
Molybdenum
ND
mg/kg
3.0
1.5
5
04/02/15 20:00
04/09/15 03:45
7439-98-7
D3
Nickel
14.4
mg/kg
1.5
0.74
5
04/02/15 20:00
04/09/15 03:45
7440-02-0
D3
Potassium
4120
mg/kg
296
148
5
04/02/15 20:00
04/09/15 03:45
7440-09-7
D3
Sodium
ND
mg/kg
296
148
5
04/02/15 20:00
04/09/15 03:45
7440-23-5
D3
Strontium
2.1J
mg/kg
3.0
1.5
5
04/02/15 20:00
04/09/15 03:45
7440-24-6
D3
Zinc
134
mg/kg
5.9
3.0
5
04/02/15 20:00
04/09/15 03:45
7440-66-6
D3
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
3.0
1.5
50
04/02/15 20:00
04/06/15 09:14
7440-36-0
D3,N2
Arsenic
6.4
mg/kg
3.0
1.5
50
04/02/15 20:00
04/06/15 09:14
7440-38-2
D3
Cadmium
ND
mg/kg
0.36
0.18
50
04/02/15 20:00
04/06/15 09:14
7440-43-9
D3
Cobalt
18.4
mg/kg
3.0
1.5
50
04/02/15 20:00
04/06/15 09:14
7440-48-4
D3
Lead
7.8
mg/kg
3.0
1.5
50
04/02/15 20:00
04/06/15 09:14
7439-92-1
D3
Selenium
10.6
mg/kg
3.0
1.5
50
04/02/15 20:00
04/06/15 09:14
7782-49-2
D3
Thallium
ND
mg/kg
3.0
1.5
50
04/02/15 20:00
04/06/15 09:14
7440-28-0
D3
Vanadium
20.7
mg/kg
3.0
1.5
50
04/02/15 20:00
04/06/15 09:14
7440-62-2
D3
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
ND
mg/kg 0.0097
0.0049
1
04/04/15 19:50
04/07/15 09:04
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
14.2
%
0.10
0.10
1
04/04/15 20:02
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
5.3
Std. Units
0.10
0.10
1
04/03/15 10:15
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
286
143
5
04/03/15 01:23
16887-00-6
D3
Sulfate
ND
mg/kg
286
143
5
04/03/15 01:23
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
28.6
14.3
5
04/03/15 01:23
14797-55-8
H3
Date: 04/29/2015 08:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 61 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
P3690 �irwyte. Suite 100
y Huntersville, NC 28078
[phone]
Sample: 2015008649
Lab ID:
92243093014
Collected:
03/25/15 13:05
Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
2830
mg/kg
693
347
1
04/15/15 11:40
7440-44-0
Total Organic Carbon
2200
mg/kg
701
350
1
04/15/15 11:48
7440-44-0
Total Organic Carbon
2210
mg/kg
695
347
1
04/15/15 11:54
7440-44-0
Total Organic Carbon
1900
mg/kg
693
346
1
04/15/15 12:02
7440-44-0
Mean Total Organic Carbon
2280
mg/kg
695
348
1
04/15/15 11:40
7440-44-0
Surrogates
RSD%
17.2
%
1
04/15/1511:40
Date: 04/29/2015 08:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 62 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
PARV16fyte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
Sample: 2015008650
Lab ID:
92243093015 Collected:
03/25/15 13:10
Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
1740
mg/kg
7.0
3.5
1
04/02/15 20:00
04/06/15 15:25
7429-90-5
Barium
7.4
mg/kg
0.70
0.35
1
04/02/15 20:00
04/06/15 15:25
7440-39-3
Beryllium
0.056J
mg/kg 0.070
0.035
1
04/02/15 20:00
04/06/15 15:25
7440-41-7
Boron
ND
mg/kg
3.5
1.7
1
04/02/15 20:00
04/06/15 15:25
7440-42-8
Calcium
54.6
mg/kg
34.8
17.4
1
04/02/15 20:00
04/06/15 15:25
7440-70-2
Chromium
1.5
mg/kg
0.35
0.17
1
04/02/15 20:00
04/06/15 15:25
7440-47-3
Copper
6.5
mg/kg
0.35
0.17
1
04/02/15 20:00
04/06/15 15:25
7440-50-8
Iron
12600
mg/kg
13.9
7.0
5
04/02/15 20:00
04/09/15 04:02
7439-89-6
D4
Magnesium
889
mg/kg
34.8
17.4
1
04/02/15 20:00
04/06/15 15:25
7439-95-4
Manganese
14.5
mg/kg
0.35
0.17
1
04/02/15 20:00
04/06/15 15:25
7439-96-5
Molybdenum
ND
mg/kg
0.70
0.35
1
04/02/15 20:00
04/06/15 15:25
7439-98-7
Nickel
1.9
mg/kg
0.35
0.17
1
04/02/15 20:00
04/06/15 15:25
7440-02-0
Potassium
748
mg/kg
69.7
34.8
1
04/02/15 20:00
04/06/15 15:25
7440-09-7
Sodium
ND
mg/kg
69.7
34.8
1
04/02/15 20:00
04/06/15 15:25
7440-23-5
Strontium
0.511
mg/kg
0.70
0.35
1
04/02/15 20:00
04/06/15 15:25
7440-24-6
Zinc
8.8
mg/kg
1.4
0.70
1
04/02/15 20:00
04/06/15 15:25
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
3.5
1.7
50
04/02/15 20:00
04/06/15 09:16
7440-36-0
D3,N2
Arsenic
96.7
mg/kg
3.5
1.7
50
04/02/15 20:00
04/06/15 09:16
7440-38-2
D3
Cadmium
0.38J
mg/kg
0.42
0.21
50
04/02/15 20:00
04/06/15 09:16
7440-43-9
D3
Cobalt
13.5
mg/kg
3.5
1.7
50
04/02/15 20:00
04/06/15 09:16
7440-48-4
D3
Lead
17.7
mg/kg
3.5
1.7
50
04/02/15 20:00
04/06/15 09:16
7439-92-1
D3
Selenium
12.2
mg/kg
3.5
1.7
50
04/02/15 20:00
04/06/15 09:16
7782-49-2
D3
Thallium
ND
mg/kg
3.5
1.7
50
04/02/15 20:00
04/06/15 09:16
7440-28-0
D3
Vanadium
66.0
mg/kg
3.5
1.7
50
04/02/15 20:00
04/06/15 09:16
7440-62-2
D3
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
0.23
mg/kg
0.011
0.0056
1
04/04/15 19:50
04/07/15 09:06
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
29.5
%
0.10
0.10
1
04/04/15 20:02
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
7.5
Std. Units
0.10
0.10
1
04/03/15 10:15
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
355
177
5
04/03/15 01:44
16887-00-6
D3
Sulfate
ND
mg/kg
355
177
5
04/03/15 01:44
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
35.5
17.7
5
04/03/15 01:44
14797-55-8
H3
Date: 04/29/2015 08:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 63 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
P36R08 irpyt.. Suite 100
y Huntersville, NC 28078
[phone]
Sample: 2015008650
Lab ID:
92243093015
Collected:
03/25/15 13:10
Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
72800
mg/kg
8570
4290
1
04/15/15 12:08
7440-44-0
Total Organic Carbon
62300
mg/kg
8630
4320
1
04/15/15 12:15
7440-44-0
Total Organic Carbon
63300
mg/kg
9100
4550
1
04/15/15 12:20
7440-44-0
Total Organic Carbon
60700
mg/kg
8670
4330
1
04/15/15 12:27
7440-44-0
Mean Total Organic Carbon
64800
mg/kg
8740
4370
1
04/15/15 12:08
7440-44-0
Surrogates
RSD%
8.4
%
1
04/15/1512:08
Date: 04/29/2015 08:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 64 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
PARYWYte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
Sample: 2015008652
Lab ID:
92243093016 Collected:
03/25/15 15:50
Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
15700
mg/kg
44.5
22.2
5
04/02/15 20:00
04/09/15 04:07
7429-90-5
D3
Barium
34.1
mg/kg
4.4
2.2
5
04/02/15 20:00
04/09/15 04:07
7440-39-3
D3
Beryllium
1.1
mg/kg
0.44
0.22
5
04/02/15 20:00
04/09/15 04:07
7440-41-7
D3
Boron
45.2
mg/kg
22.2
11.1
5
04/02/15 20:00
04/09/15 04:07
7440-42-8
D3
Calcium
343
mg/kg
222
111
5
04/02/15 20:00
04/09/15 04:07
7440-70-2
D3
Chromium
15.7
mg/kg
2.2
1.1
5
04/02/15 20:00
04/09/15 04:07
7440-47-3
D3
Copper
40.6
mg/kg
2.2
1.1
5
04/02/15 20:00
04/09/15 04:07
7440-50-8
D3
Iron
49200
mg/kg
17.8
8.9
5
04/02/15 20:00
04/09/15 04:07
7439-89-6
D4
Magnesium
5490
mg/kg
222
111
5
04/02/15 20:00
04/09/15 04:07
7439-95-4
D3
Manganese
128
mg/kg
2.2
1.1
5
04/02/15 20:00
04/09/15 04:07
7439-96-5
D3
Molybdenum
ND
mg/kg
4.4
2.2
5
04/02/15 20:00
04/09/15 04:07
7439-98-7
D3
Nickel
14.7
mg/kg
2.2
1.1
5
04/02/15 20:00
04/09/15 04:07
7440-02-0
D3
Potassium
1860
mg/kg
445
222
5
04/02/15 20:00
04/09/15 04:07
7440-09-7
D3
Sodium
ND
mg/kg
445
222
5
04/02/15 20:00
04/09/15 04:07
7440-23-5
D3
Strontium
5.8
mg/kg
4.4
2.2
5
04/02/15 20:00
04/09/15 04:07
7440-24-6
D3
Zinc
74.5
mg/kg
8.9
4.4
5
04/02/15 20:00
04/09/15 04:07
7440-66-6
D3
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
4.4
2.2
50
04/02/15 20:00
04/06/15 09:19
7440-36-0
D3,N2
Arsenic
4.7
mg/kg
4.4
2.2
50
04/02/15 20:00
04/06/15 09:19
7440-38-2
D3
Cadmium
ND
mg/kg
0.53
0.27
50
04/02/15 20:00
04/06/15 09:19
7440-43-9
D3
Cobalt
8.3
mg/kg
4.4
2.2
50
04/02/15 20:00
04/06/15 09:19
7440-48-4
D3
Lead
10.4
mg/kg
4.4
2.2
50
04/02/15 20:00
04/06/15 09:19
7439-92-1
D3
Selenium
7.1
mg/kg
4.4
2.2
50
04/02/15 20:00
04/06/15 09:19
7782-49-2
D3
Thallium
ND
mg/kg
4.4
2.2
50
04/02/15 20:00
04/06/15 09:19
7440-28-0
D3
Vanadium
11.5
mg/kg
4.4
2.2
50
04/02/15 20:00
04/06/15 09:19
7440-62-2
D3
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
ND
mg/kg 0.015
0.0073
1
04/04/15 19:50
04/07/15 09:08
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
43.0
%
0.10
0.10
1
04/04/15 20:02
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
6.4
Std. Units
0.10
0.10
1
04/03/15 10:15
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
434
217
5
04/03/15 02:05
16887-00-6
D3
Sulfate
ND
mg/kg
434
217
5
04/03/15 02:05
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
43.4
21.7
5
04/03/15 02:05
14797-55-8
H3
Date: 04/29/2015 08:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 65 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
PARYWYte. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015008652
Lab ID:
92243093016
Collected:
03/25/15 15:50
Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
1380
mg/kg
1050
526
1
04/15/15 13:22
7440-44-0
Total Organic Carbon
1430
mg/kg
1060
530
1
04/15/15 13:27
7440-44-0
Total Organic Carbon
1540
mg/kg
1060
531
1
04/15/15 13:33
7440-44-0
Total Organic Carbon
1540
mg/kg
1050
526
1
04/15/15 13:40
7440-44-0
Mean Total Organic Carbon
1470
mg/kg
1060
529
1
04/15/15 13:22
7440-44-0
Surrogates
RSD%
5.7
%
1
04/15/1513:22
Date: 04/29/2015 08:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 66 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
PAMIirwyte. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
Sample: 2015008653
Lab ID:
92243093017
Collected:
03/25/15 16:00
Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
19500
mg/kg
6.6
3.3
1
04/02/15 20:00
04/06/15 15:33
7429-90-5
Barium
65.6
mg/kg
0.66
0.33
1
04/02/15 20:00
04/06/15 15:33
7440-39-3
Beryllium
1.0
mg/kg
0.066
0.033
1
04/02/15 20:00
04/05/15 05:58
7440-41-7
Boron
ND
mg/kg
3.3
1.6
1
04/02/15 20:00
04/05/15 05:58
7440-42-8
Calcium
3390
mg/kg
32.9
16.5
1
04/02/15 20:00
04/06/15 15:33
7440-70-2
Chromium
38.6
mg/kg
0.33
0.16
1
04/02/15 20:00
04/05/15 05:58
7440-47-3
Copper
92.3
mg/kg
0.33
0.16
1
04/02/15 20:00
04/05/15 05:58
7440-50-8
Iron
64600
mg/kg
13.2
6.6
5
04/02/15 20:00
04/09/15 04:11
7439-89-6
D4
Magnesium
16300
mg/kg
32.9
16.5
1
04/02/15 20:00
04/06/15 15:33
7439-95-4
Manganese
194
mg/kg
0.33
0.16
1
04/02/15 20:00
04/05/15 05:58
7439-96-5
Molybdenum
1.6
mg/kg
0.66
0.33
1
04/02/15 20:00
04/06/15 15:33
7439-98-7
Nickel
39.9
mg/kg
0.33
0.16
1
04/02/15 20:00
04/06/15 15:33
7440-02-0
Potassium
4510
mg/kg
65.9
32.9
1
04/02/15 20:00
04/06/15 15:33
7440-09-7
Sodium
437
mg/kg
65.9
32.9
1
04/02/15 20:00
04/06/15 15:33
7440-23-5
Strontium
7.3
mg/kg
0.66
0.33
1
04/02/15 20:00
04/06/15 15:33
7440-24-6
Zinc
86.6
mg/kg
1.3
0.66
1
04/02/15 20:00
04/06/15 15:33
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
3.3
1.6
50
04/02/15 20:00
04/06/15 09:21
7440-36-0
D3,N2
Arsenic
3.1J
mg/kg
3.3
1.6
50
04/02/15 20:00
04/06/15 09:21
7440-38-2
D3
Cadmium
ND
mg/kg
0.40
0.20
50
04/02/15 20:00
04/06/15 09:21
7440-43-9
D3
Cobalt
36.9
mg/kg
3.3
1.6
50
04/02/15 20:00
04/06/15 09:21
7440-48-4
D3
Lead
9.0
mg/kg
3.3
1.6
50
04/02/15 20:00
04/06/15 09:21
7439-92-1
D3
Selenium
4.9
mg/kg
3.3
1.6
50
04/02/15 20:00
04/06/15 09:21
7782-49-2
D3
Thallium
ND
mg/kg
3.3
1.6
50
04/02/15 20:00
04/06/15 09:21
7440-28-0
D3
Vanadium
51.2
mg/kg
3.3
1.6
50
04/02/15 20:00
04/06/15 09:21
7440-62-2
D3
7471 Mercury
Analytical
Method: EPA 7471 Preparation
Method: EPA
7471
Mercury
ND
mg/kg
0.010
0.0052
1
04/04/15 19:50
04/07/15 09:10
7439-97-6
Percent Moisture
Analytical
Method: ASTM
D2974-87
Percent Moisture
23.9
%
0.10
0.10
1
04/04/15 20:02
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
7.6
Std. Units
0.10
0.10
1
04/03/15 10:15
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
329
164
5
04/03/15 02:27
16887-00-6
D3
Sulfate
ND
mg/kg
329
164
5
04/03/15 02:27
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
32.9
16.4
5
04/03/15 02:27
14797-55-8
H3
Date: 04/29/2015 08:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 67 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
POWWyte. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015008653
Lab ID:
92243093017
Collected:
03/25/15 16:00
Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
64200
mg/kg
7510
3760
1
04/15/15 13:46
7440-44-0
Total Organic Carbon
60200
mg/kg
7490
3750
1
04/15/15 13:55
7440-44-0
Total Organic Carbon
58700
mg/kg
7740
3870
1
04/15/15 14:01
7440-44-0
Total Organic Carbon
54800
mg/kg
7620
3810
1
04/15/15 14:09
7440-44-0
Mean Total Organic Carbon
59400
mg/kg
7590
3800
1
04/15/15 13:46
7440-44-0
Surrogates
RSD%
6.6
%
1
04/15/1513:46
Date: 04/29/2015 08:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 68 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
PARVrWyte. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
Sample: 2015008654
Lab ID:
92243093018 Collected:
03/25/15 16:05
Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
18700
mg/kg
6.5
3.3
1
04/02/15 20:00
04/05/15 06:03
7429-90-5
Barium
87.5
mg/kg
0.65
0.33
1
04/02/15 20:00
04/05/15 06:03
7440-39-3
Beryllium
1.5
mg/kg
0.33
0.16
5
04/02/15 20:00
04/09/15 04:15
7440-41-7
D3
Boron
48.5
mg/kg
16.3
8.1
5
04/02/15 20:00
04/09/15 04:15
7440-42-8
D3
Calcium
484
mg/kg
32.5
16.3
1
04/02/15 20:00
04/05/15 06:03
7440-70-2
Chromium
87.3
mg/kg
1.6
0.81
5
04/02/15 20:00
04/09/15 04:15
7440-47-3
D3
Copper
56.0
mg/kg
1.6
0.81
5
04/02/15 20:00
04/09/15 04:15
7440-50-8
D3
Iron
52600
mg/kg
13.0
6.5
5
04/02/15 20:00
04/09/15 04:15
7439-89-6
D4
Magnesium
2210
mg/kg
32.5
16.3
1
04/02/15 20:00
04/05/15 06:03
7439-95-4
Manganese
681
mg/kg
1.6
0.81
5
04/02/15 20:00
04/09/15 04:15
7439-96-5
D3
Molybdenum
ND
mg/kg
0.65
0.33
1
04/02/15 20:00
04/05/15 06:03
7439-98-7
Nickel
15.7
mg/kg
0.33
0.16
1
04/02/15 20:00
04/05/15 06:03
7440-02-0
Potassium
1790
mg/kg
65.1
32.5
1
04/02/15 20:00
04/05/15 06:03
7440-09-7
Sodium
ND
mg/kg
325
163
5
04/02/15 20:00
04/09/15 04:15
7440-23-5
D3
Strontium
2.1
mg/kg
0.65
0.33
1
04/02/15 20:00
04/05/15 06:03
7440-24-6
Zinc
36.8
mg/kg
1.3
0.65
1
04/02/15 20:00
04/05/15 06:03
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
3.3
1.6
50
04/02/15 20:00
04/06/15 09:23
7440-36-0
D3,N2
Arsenic
2.7J
mg/kg
3.3
1.6
50
04/02/15 20:00
04/06/15 09:23
7440-38-2
D3
Cadmium
ND
mg/kg
0.39
0.20
50
04/02/15 20:00
04/06/15 09:23
7440-43-9
D3
Cobalt
53.5
mg/kg
3.3
1.6
50
04/02/15 20:00
04/06/15 09:23
7440-48-4
D3
Lead
15.0
mg/kg
3.3
1.6
50
04/02/15 20:00
04/06/15 09:23
7439-92-1
D3
Selenium
2.7.11
mg/kg
3.3
1.6
50
04/02/15 20:00
04/06/15 09:23
7782-49-2
D3
Thallium
ND
mg/kg
3.3
1.6
50
04/02/15 20:00
04/06/15 09:23
7440-28-0
D3
Vanadium
81.0
mg/kg
3.3
1.6
50
04/02/15 20:00
04/06/15 09:23
7440-62-2
D3
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
0.019
mg/kg
0.011
0.0054
1
04/04/15 19:50
04/07/15 09:18
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
22.8
%
0.10
0.10
1
04/04/15 20:03
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
6.1
Std. Units
0.10
0.10
1
04/03/15 10:15
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
321
161
5
04/03/15 02:48
16887-00-6
D3
Sulfate
ND
mg/kg
321
161
5
04/03/15 02:48
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
32.1
16.1
5
04/03/15 02:48
14797-55-8
H3
Date: 04/29/2015 08:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 69 of 100

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
PARVrWyte. Suite 100
y Huntersville, NC 28078
[phone]
Sample: 2015008654
Lab ID:
92243093018
Collected:
03/25/15 16:05
Received: 03/27/15 15:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
29600
mg/kg
1210
605
1
04/15/15 14:16
7440-44-0
Total Organic Carbon
27300
mg/kg
1210
606
1
04/15/15 14:24
7440-44-0
Total Organic Carbon
30200
mg/kg
1200
601
1
04/15/15 14:31
7440-44-0
Total Organic Carbon
30100
mg/kg
1210
605
1
04/15/15 14:37
7440-44-0
Mean Total Organic Carbon
29300
mg/kg
1210
604
1
04/15/15 14:16
7440-44-0
Surrogates
RSD%
4.7
%
1
04/15/1514:16
Date: 04/29/2015 08:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 70 of 100

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
P36919rwyte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
QC Batch: MERP/13104
Analysis Method: EPA 7470
QC Batch Method: EPA 7470
Analysis Description: 7470 Mercury
Associated Lab Samples: 92243093001, 92243093002
METHOD BLANK: 1929182
Matrix: Water
Associated Lab Samples: 92243093001, 92243093002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ug/L
ND 0.20
04/01/1513:03
LABORATORY CONTROL SAMPLE: 1929183
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury ug/L
5 5.4
108 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1929376 1929377
MS MSD
92242976005
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND
5 5 5.3
5.5 106 110 75-125 4 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc..
Page 71 of 100

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
POWWyte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
QC Batch: MERP/13232
Analysis Method: EPA 7470
QC Batch Method: EPA 7470
Analysis Description: 7470 Mercury
Associated Lab Samples: 92243093003, 92243093004,
92243093005, 92243093006
METHOD BLANK: 1939457
Matrix: Water
Associated Lab Samples: 92243093003, 92243093004,
92243093005, 92243093006
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ug/L
ND 0.20
04/16/1519:16
LABORATORY CONTROL SAMPLE: 1939458
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury ug/L
5 4.7
94 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1939459 1939460
MS MSD
92245092001
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND
5 5 4.7
4.8 95 96 75-125 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc..
Page 72 of 100

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
PARVrWyte. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
QC Batch: MERP/5552 Analysis Method: EPA 7471
QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury
Associated Lab Samples: 92243093007,92243093008,92243093009,92243093010,92243093011,92243093012,92243093013,
92243093014,92243093015,92243093016,92243093017,92243093018
METHOD BLANK: 1175000 Matrix: Solid
Associated Lab Samples: 92243093007,92243093008,92243093009,92243093010,92243093011,92243093012,92243093013,
92243093014,92243093015,92243093016,92243093017,92243093018
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury mg/kg ND 0.0083 04/07/15 08:19
LABORATORY CONTROL SAMPLE: 1175001
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury mg/kg .083 0.078 95 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1175002 1175003
MS MSD
92243090001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Mercury mg/kg ND .0898 .0909 0.093 0.093 100 99 80-120 0 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc..
Page 73 of 100

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
P36gmirpy.�ie. Suite 100
y Huntersville, NC 28078
[phone]
QC Batch: MPRP/23404 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 92243093007,92243093008,92243093009,92243093010,92243093011,92243093012,92243093013,
92243093014,92243093015,92243093016,92243093017,92243093018
METHOD BLANK: 1173226 Matrix: Solid
Associated Lab Samples: 92243093007,92243093008,92243093009,92243093010,92243093011,92243093012,92243093013,
92243093014,92243093015,92243093016,92243093017,92243093018
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Aluminum
mg/kg
ND
5.2
04/06/1513:45
Barium
mg/kg
ND
0.52
04/06/1513:45
Beryllium
mg/kg
ND
0.052
04/06/1513:45
Boron
mg/kg
ND
2.6
04/06/1513:45
Calcium
mg/kg
ND
25.8
04/06/1513:45
Chromium
mg/kg
ND
0.26
04/06/1513:45
Copper
mg/kg
ND
0.26
04/06/1513:45
Iron
mg/kg
ND
2.1
04/06/1513:45
Magnesium
mg/kg
ND
25.8
04/06/1513:45
Manganese
mg/kg
ND
0.26
04/06/1513:45
Molybdenum
mg/kg
ND
0.52
04/06/1513:45
Nickel
mg/kg
ND
0.26
04/06/1513:45
Potassium
mg/kg
ND
51.7
04/06/1513:45
Sodium
mg/kg
ND
51.7
04/06/1513:45
Strontium
mg/kg
ND
0.52
04/06/1513:45
Zinc
mg/kg
ND
1.0
04/06/1513:45
LABORATORY CONTROL SAMPLE:
Parameter
1173227
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
mg/kg
126
129
102
80-120
Barium
mg/kg
12.6
12.5
99
80-120
Beryllium
mg/kg
1.3
1.3
103
80-120
Boron
mg/kg
126
126
100
80-120
Calcium
mg/kg
630
640
102
80-120
Chromium
mg/kg
12.6
12.6
100
80-120
Copper
mg/kg
12.6
13.0
103
80-120
Iron
mg/kg
126
117
93
80-120
Magnesium
mg/kg
630
627
100
80-120
Manganese
mg/kg
12.6
12.8
102
80-120
Molybdenum
mg/kg
12.6
12.3
98
80-120
Nickel
mg/kg
12.6
12.7
100
80-120
Potassium
mg/kg
630
636
101
80-120
Sodium
mg/kg
630
650
103
80-120
Strontium
mg/kg
12.6
12.3
98
80-120
Zinc
mg/kg
63
64.1
102
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc.. Page 74 of 100

aceAnaiXical
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QUALITY CONTROL DATA
Pace Analytical Services, Inc.
P36906rwyte. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1173228
1173229
MS
MSD
92243090001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
mg/kg
13400
133
137
14300
14300
614
647
75-125
0
20 M1
Barium
mg/kg
204
13.3
13.7
206
224
10
144
75-125
9
20 M1
Beryllium
mg/kg
0.21
1.33
1.33
1.2
1.3
76
79
75-125
5
20
Boron
mg/kg
ND
133
137
98.2
102
74
74
75-125
3
20 M1
Calcium
mg/kg
3960
665
686
4660
4240
105
40
75-125
9
20 M1
Chromium
mg/kg
5.2
13.3
13.7
15.1
17.0
75
86
75-125
12
20
Copper
mg/kg
22.4
13.3
13.7
32.6
35.9
77
98
75-125
10
20
Iron
mg/kg
14400
133
137
14800
15200
315
603
75-125
3
20 M1
Magnesium
mg/kg
9940
665
686
10500
10200
89
37
75-125
3
20 M1
Manganese
mg/kg
235
13.3
13.7
234
301
-7
477
75-125
25
20 M1,R1
Molybdenum
mg/kg
ND
13.3
13.7
8.5
8.8
64
64
75-125
4
20 M1
Nickel
mg/kg
4.8
13.3
13.7
16.5
18.0
88
96
75-125
9
20
Potassium
mg/kg
6810
665
686
7560
7010
112
29
75-125
8
20 M1
Sodium
mg/kg
230
665
686
908
904
102
98
75-125
0
20
Strontium
mg/kg
18.3
13.3
13.7
30.3
30.9
90
92
75-125
2
20
Zinc
mg/kg
51.5
66.5
68.6
110
112
89
88
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc..
Page 75 of 100

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
P36906rwyte. Suite 100
y Huntersville, NC 28078
[phone]
QC Batch: MPRP/23405 Analysis Method: EPA 6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92243093007,92243093008,92243093009,92243093010,92243093011,92243093012,92243093013,
92243093014,92243093015,92243093016,92243093017,92243093018
METHOD BLANK: 1173230
Matrix:
Solid
LCS
Result
Associated Lab Samples:
92243093007,92243093008,92243093009,92243093010,92243093011,92243093012,92243093013,
Antimony
mg/kg
2.6
92243093014,92243093015,92243093016,92243093017,92243093018
98
80-120 N2
Arsenic
mg/kg
Blank
Reporting
107
Parameter
Units
Result
Limit
Analyzed Qualifiers
Antimony
mg/kg
ND
0.051
04/06/15 08:17 N2
Arsenic
mg/kg
ND
0.051
04/06/15 08:17
Cadmium
mg/kg
ND
0.0061
04/06/15 08:17
Cobalt
mg/kg
ND
0.051
04/06/15 08:17
Lead
mg/kg
ND
0.051
04/06/15 08:17
Selenium
mg/kg
ND
0.051
04/06/15 08:17
Thallium
mg/kg
ND
0.051
04/06/15 08:17
Vanadium
mg/kg
ND
0.051
04/06/15 08:17
LABORATORY CONTROL SAMPLE:
Parameter
1173231
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
mg/kg
2.6
2.5
98
80-120 N2
Arsenic
mg/kg
2.6
2.7
107
80-120
Cadmium
mg/kg
.26
0.26
103
80-120
Cobalt
mg/kg
2.6
2.7
106
80-120
Lead
mg/kg
2.6
2.6
103
80-120
Selenium
mg/kg
2.6
2.7
106
80-120
Thallium
mg/kg
2.6
2.7
104
80-120
Vanadium
mg/kg
2.6
2.7
104
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1173232
1173233
MS
MSD
92243090002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
mg/kg
ND
2.55
2.65
1.4J
1.5J
51
52
75-125
20 D3,M6,
N2
Arsenic
mg/kg
ND
2.55
2.65
2.5J
2.8
87
94
75-125
20 D3
Cadmium
mg/kg
ND
.255
.265
0.29J
0.29J
101
98
75-125
20 D3
Cobalt
mg/kg
16.6
2.55
2.65
14.3
15.2
-90
-51
75-125
6
20 D3,M6
Lead
mg/kg
ND
2.55
2.65
3.3
3.5
86
90
75-125
6
20 D3
Selenium
mg/kg
ND
2.55
2.65
2.9
2.7
88
77
75-125
7
20 D3
Thallium
mg/kg
ND
2.55
2.65
2.5J
2.8
82
87
75-125
20 D3
Vanadium
mg/kg
27.3
2.55
2.65
22.9
25.3
-170
-75
75-125
10
20 D3,M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc..
Page 76 of 100

aceAnaiXical
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QUALITY CONTROL DATA
Project: J15030693
Pace Project No.: 92243093
QC Batch: MPRP/53294 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92243093001, 92243093002
METHOD BLANK: 1929140
Associated Lab Samples: 92243093001, 92243093002
Parameter
Units
Aluminum
ug/L
Antimony
ug/L
Arsenic
ug/L
Barium
ug/L
Beryllium
ug/L
Boron
ug/L
Cadmium
ug/L
Calcium
ug/L
Chromium
ug/L
Cobalt
ug/L
Copper
ug/L
Iron
ug/L
Lead
ug/L
Magnesium
ug/L
Manganese
ug/L
Molybdenum
ug/L
Nickel
ug/L
Potassium
ug/L
Selenium
ug/L
Sodium
ug/L
Strontium
ug/L
Thallium
ug/L
Vanadium
ug/L
Zinc
ug/L
Matrix: Water
Blank
Result
Reporting
Limit
Analyzed
ND
10.0
04/02/1515:57
ND
0.50
04/02/1515:57
ND
0.50
04/02/1515:57
ND
0.30
04/02/1515:57
ND
0.20
04/02/1515:57
ND
5.0
04/02/1515:57
ND
0.080
04/02/1515:57
ND
40.0
04/02/1515:57
ND
0.50
04/02/1515:57
ND
0.50
04/02/1515:57
ND
1.0
04/02/1515:57
ND
50.0
04/02/1515:57
ND
0.10
04/02/1515:57
ND
10.0
04/02/1515:57
ND
0.50
04/02/1515:57
ND
0.50
04/02/1515:57
ND
0.50
04/02/1515:57
ND
50.0
04/02/1515:57
ND
0.50
04/02/1515:57
ND
50.0
04/02/1515:57
ND
0.50
04/02/1515:57
ND
0.10
04/02/1515:57
ND
1.0
04/02/1515:57
ND
5.0
04/02/1515:57
Qualifiers
Pace Analytical Services, Inc.
PAROAirwyte. Suite 100
y Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
1929141
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
ug/L
80
84.1
105
80-120
Antimony
ug/L
80
83.2
104
80-120
Arsenic
ug/L
80
84.5
106
80-120
Barium
ug/L
80
81.8
102
80-120
Beryllium
ug/L
80
84.6
106
80-120
Boron
ug/L
80
83.9
105
80-120
Cadmium
ug/L
80
81.8
102
80-120
Calcium
ug/L
1000
981
98
80-120
Chromium
ug/L
80
83.4
104
80-120
Cobalt
ug/L
80
81.8
102
80-120
Copper
ug/L
80
77.6
97
80-120
Iron
ug/L
1000
1060
106
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc..
Page 77 of 100

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
PAROAirwyte. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
LABORATORY CONTROL SAMPLE:
1929141
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
86.5
108
80-120
Magnesium
ug/L
1000
1020
102
80-120
Manganese
ug/L
80
86.1
108
80-120
Molybdenum
ug/L
80
79.2
99
80-120
Nickel
ug/L
80
81.2
101
80-120
Potassium
ug/L
1000
1060
106
80-120
Selenium
ug/L
80
83.2
104
80-120
Sodium
ug/L
1000
1030
103
80-120
Strontium
ug/L
80
83.1
104
80-120
Thallium
ug/L
80
85.4
107
80-120
Vanadium
ug/L
80
83.2
104
80-120
Zinc
ug/L
80
84.9
106
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1929142
1929143
MS
MSD
92242959001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
11.6
80
80
102
97.4
113
107
75-125
5
20
Antimony
ug/L
ND
80
80
83.7
83.2
105
104
75-125
1
20
Arsenic
ug/L
ND
80
80
85.5
85.6
107
107
75-125
0
20
Barium
ug/L
ND
80
80
83.5
83.1
104
103
75-125
0
20
Beryllium
ug/L
ND
80
80
85.8
85.2
107
107
75-125
1
20
Boron
ug/L
ND
80
80
86.4
85.8
107
106
75-125
1
20
Cadmium
ug/L
ND
80
80
82.2
82.9
103
104
75-125
1
20
Calcium
ug/L
ND
1000
1000
1050
1000
102
96
75-125
5
20
Chromium
ug/L
ND
80
80
85.2
85.3
106
106
75-125
0
20
Cobalt
ug/L
ND
80
80
83.6
82.9
105
104
75-125
1
20
Copper
ug/L
1.5
80
80
80.3
79.9
99
98
75-125
1
20
Iron
ug/L
ND
1000
1000
1090
1080
107
106
75-125
1
20
Lead
ug/L
0.24
80
80
87.0
87.8
108
109
75-125
1
20
Magnesium
ug/L
12.9
1000
1000
1070
1050
105
104
75-125
1
20
Manganese
ug/L
1.1
80
80
87.9
87.9
109
109
75-125
0
20
Molybdenum
ug/L
ND
80
80
79.8
80.1
100
100
75-125
0
20
Nickel
ug/L
ND
80
80
83.3
82.5
104
103
75-125
1
20
Potassium
ug/L
ND
1000
1000
1120
1130
110
110
75-125
1
20
Selenium
ug/L
ND
80
80
84.0
84.0
105
105
75-125
0
20
Sodium
ug/L
ND
1000
1000
1090
1090
105
105
75-125
0
20
Strontium
ug/L
ND
80
80
83.8
84.3
105
105
75-125
1
20
Thallium
ug/L
ND
80
80
83.7
84.3
105
105
75-125
1
20
Vanadium
ug/L
ND
80
80
83.4
83.7
104
105
75-125
0
20
Zinc
ug/L
ND
80
80
87.3
86.6
106
105
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc..
Page 78 of 100

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Project: J15030693
Pace Project No.: 92243093
QC Batch: MPRP/53628 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92243093003, 92243093004, 92243093005, 92243093006
METHOD BLANK: 1939436 Matrix: Water
Associated Lab Samples: 92243093003, 92243093004, 92243093005, 92243093006
Blank Reporting
Parameter Units Result Limit
Analyzed
Aluminum
ug/L
ND
10.0
04/17/1517:03
Antimony
ug/L
ND
0.50
04/17/1517:03
Arsenic
ug/L
ND
0.50
04/17/1517:03
Barium
ug/L
ND
0.30
04/17/1517:03
Beryllium
ug/L
ND
0.20
04/17/1517:03
Boron
ug/L
ND
5.0
04/17/1517:03
Cadmium
ug/L
ND
0.080
04/17/1517:03
Calcium
ug/L
ND
40.0
04/20/1514:02
Chromium
ug/L
ND
0.50
04/17/1517:03
Cobalt
ug/L
ND
0.50
04/17/1517:03
Copper
ug/L
ND
1.0
04/17/1517:03
Iron
ug/L
ND
50.0
04/17/1517:03
Lead
ug/L
ND
0.10
04/17/1517:03
Magnesium
ug/L
ND
10.0
04/17/1517:03
Manganese
ug/L
ND
0.50
04/17/1517:03
Molybdenum
ug/L
ND
0.50
04/17/1517:03
Nickel
ug/L
ND
0.50
04/17/1517:03
Potassium
ug/L
ND
50.0
04/17/1517:03
Selenium
ug/L
ND
0.50
04/17/1517:03
Sodium
ug/L
ND
50.0
04/17/1517:03
Strontium
ug/L
ND
0.50
04/17/1517:03
Thallium
ug/L
ND
0.10
04/17/1517:03
Vanadium
ug/L
ND
1.0
04/17/1517:03
Zinc
ug/L
ND
5.0
04/17/1517:03
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1939437
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
ug/L
80
78.0
98
80-120
Antimony
ug/L
80
76.9
96
80-120
Arsenic
ug/L
80
78.2
98
80-120
Barium
ug/L
80
76.5
96
80-120
Beryllium
ug/L
80
68.9
86
80-120
Boron
ug/L
80
79.4
99
80-120
Cadmium
ug/L
80
76.6
96
80-120
Calcium
ug/L
1000
1060
106
80-120
Chromium
ug/L
80
77.1
96
80-120
Cobalt
ug/L
80
77.9
97
80-120
Copper
ug/L
80
80.4
101
80-120
Iron
ug/L
1000
977
98
80-120
Pace Analytical Services, Inc.
PAROAirwyte. Suite 100
y Huntersville, NC 28078
[phone]
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc.. Page 79 of 100

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
P3690orwyte. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
LABORATORY CONTROL SAMPLE:
1939437
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
76.9
96
80-120
Magnesium
ug/L
1000
951
95
80-120
Manganese
ug/L
80
77.1
96
80-120
Molybdenum
ug/L
80
77.8
97
80-120
Nickel
ug/L
80
80.1
100
80-120
Potassium
ug/L
1000
991
99
80-120
Selenium
ug/L
80
79.4
99
80-120
Sodium
ug/L
1000
951
95
80-120
Strontium
ug/L
80
77.1
96
80-120
Thallium
ug/L
80
77.3
97
80-120
Vanadium
ug/L
80
81.3
102
80-120
Zinc
ug/L
80
79.2
99
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1939446
1939447
MS
MSD
92245087005
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
ND
80
80
98.4
83.9
120
102
75-125
16
20
Antimony
ug/L
ND
80
80
76.9
77.7
96
97
75-125
1
20
Arsenic
ug/L
ND
80
80
77.2
78.0
97
97
75-125
1
20
Barium
ug/L
ND
80
80
76.5
77.2
95
96
75-125
1
20
Beryllium
ug/L
ND
80
80
68.0
68.6
85
86
75-125
1
20
Boron
ug/L
ND
80
80
79.4
78.5
97
95
75-125
1
20
Cadmium
ug/L
ND
80
80
75.6
77.2
94
97
75-125
2
20
Calcium
ug/L
66.3
1000
1000
1130
1070
106
100
75-125
5
20
Chromium
ug/L
0.50
80
80
78.2
79.8
97
99
75-125
2
20
Cobalt
ug/L
ND
80
80
76.9
78.1
96
98
75-125
2
20
Copper
ug/L
ND
80
80
80.2
80.9
100
101
75-125
1
20
Iron
ug/L
ND
1000
1000
993
1010
98
99
75-125
1
20
Lead
ug/L
ND
80
80
76.7
78.3
96
98
75-125
2
20
Magnesium
ug/L
11.0
1000
1000
961
983
95
97
75-125
2
20
Manganese
ug/L
0.78
80
80
77.4
78.5
96
97
75-125
1
20
Molybdenum
ug/L
ND
80
80
76.8
77.4
96
97
75-125
1
20
Nickel
ug/L
1.1
80
80
80.8
82.4
100
102
75-125
2
20
Potassium
ug/L
ND
1000
1000
984
994
97
98
75-125
1
20
Selenium
ug/L
ND
80
80
78.8
79.4
98
99
75-125
1
20
Sodium
ug/L
56.3
1000
1000
999
985
94
93
75-125
1
20
Strontium
ug/L
ND
80
80
76.8
78.4
96
98
75-125
2
20
Thallium
ug/L
ND
80
80
79.6
80.8
99
101
75-125
2
20
Vanadium
ug/L
ND
80
80
81.2
80.8
101
101
75-125
0
20
Zinc
ug/L
ND
80
80
80.7
81.6
96
97
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc..
Page 80 of 100

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
PARVrwyte. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
QC Batch: PMST/3411
Analysis Method:
ASTM D2974-87
QC Batch Method: ASTM
D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Associated Lab Samples:
92243093007,92243093008,92243093009,92243093010,92243093011,92243093012,92243093013,
92243093014,92243093015,92243093016,92243093017,92243093018
SAMPLE DUPLICATE:
1174882
35181405002
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
15.7
15.5 1
10
SAMPLE DUPLICATE:
1174883
92243188001
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
18.7 1
10
SAMPLE DUPLICATE:
1174884
92243093008
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
6.6
4.6 35
10 D6
SAMPLE DUPLICATE:
1174885
92243093018
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
22.8
23.9 5
10
SAMPLE DUPLICATE:
1174886
92242955005
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
4.1
4.2 3
10
SAMPLE DUPLICATE:
1174887
92243087002
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
19.2
18.8 2
10
SAMPLE DUPLICATE:
1174888
92242920003
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
25.3
25.9 2
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Project: J15030693
Pace Project No.: 92243093
SAMPLE DUPLICATE: 1174889
92242920016 Dup Max
Parameter Units Result Result RPD RPD
Percent Moisture % 19.3 20.3 5 10
Pace Analytical Services, Inc.
P36906rwyte. Suite 100
y Huntersville, NC 28078
[phone]
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc..
Page 82 of 100

aceAnaiXical
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QUALITY CONTROL DATA
Project: J15030693
Pace Project No.: 92243093
QC Batch: WET/36550 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92243093007, 92243093008
Pace Analytical Services, Inc.
Padg"MrWy te. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE DUPLICATE: 1423905
92243388001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 7.1 7.2 1 10
SAMPLE DUPLICATE: 1423906
92243093007 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 6.3 6.3 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
Padg"lirpyte. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: WET/36581 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92243093009,92243093010,92243093011,92243093012,92243093013,92243093014,92243093015,
92243093016,92243093017,92243093018
SAMPLE DUPLICATE: 1424937
92242396001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 5.1 5.1 1 10
SAMPLE DUPLICATE: 1424938
92243093010 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 6.4 6.3 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc.. Page 84 of 100

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
Padg"rwyte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
QC Batch: WETA/22469 Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92243093007, 92243093008, 92243093009, 92243093010
METHOD BLANK: 1428206 Matrix: Water
Associated Lab Samples: 92243093007, 92243093008, 92243093009, 92243093010
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfate mg/L 2.OJ 2.0 04/07/1514:55
LABORATORY CONTROL SAMPLE: 1428207
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfate mg/L 20 19.6 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1428208 1428209
MS MSD
92240170029 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 2.OJ 24.8 24.8 25.3 25.4 94 94 0 H1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1428210 1428211
MS MSD
92242976002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 12.7 41 41 53.8 53.7 100 100 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc..
Page 85 of 100

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
Padg"Wfy te. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
QC Batch: WETA/22500
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92243093007, 92243093008,
92243093009, 92243093010
METHOD BLANK: 1431018
Matrix: Water
Associated Lab Samples: 92243093007, 92243093008,
92243093009, 92243093010
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate mg/L
0.11 0.020
04/09/15 19:03 Z2
LABORATORY CONTROL SAMPLE: 1431019
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
2.5 2.4
97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1431020 1431021
MS MSD
92242504018
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L ND
4 4 4.1
4.1 99 99 90-110 0 10 H1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1431022 1431023
MS MSD
92242504019 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L ND 2.5 2.5 2.4 2.4 92 92 90-110 0 10 H1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc..
Page 86 of 100

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
PaOffl�116fytie. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
QC Batch: WETA/22478
Analysis Method: SM 4500 -CI -E
QC Batch Method: SM 4500 -CI -E
Analysis Description: 4500 Chloride
Associated Lab Samples: 92243093007, 92243093008,
92243093009, 92243093010
METHOD BLANK: 1428876
Matrix: Water
Associated Lab Samples: 92243093007, 92243093008,
92243093009, 92243093010
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chloride mg/L
ND 1.0
04/08/15 02:24
LABORATORY CONTROL SAMPLE: 1428877
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chloride mg/L
20 20.2
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1428878 1428879
MS MSD
92242504017
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND
26.3 26.3 28.3
28.1 103 102 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1428880 1428881
MS MSD
92243093009 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND 31.8 31.8 32.7 32.0 100 98 90-110 2 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc..
Page 87 of 100

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
Pa89QMr6fyte. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: WETA/45037 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92243093007,92243093008,92243093009,92243093010,92243093011,92243093012,92243093013
METHOD BLANK: 1171692
1171693
Matrix: Solid
Units
Associated Lab Samples:
mg/kg
Sulfate
mg/kg
Blank Reporting
1171695
Parameter
Units
Result Limit
Analyzed Qualifiers
Chloride
mg/kg
ND 50.0
04/02/1514:40
Sulfate
mg/kg
ND 50.0
04/02/1514:40
LABORATORY CONTROL SAMPLE:
1171693
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1171695
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
SAMPLE DUPLICATE: 1171694
Parameter
Chloride
Sulfate
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
499 457 92 80-120
499 472 95 80-120
92243087001 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 662 598 73 80-120 M1
ND 662 616 93 80-120
92243087001 Dup
Units Result Result
mg/kg ND ND
mg/kg ND ND
Max
RPD RPD Qualifiers
20
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc.. Page 88 of 100

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Project: J15030693
Pace Project No.: 92243093
QC Batch: WETA/45049 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92243093014, 92243093015, 92243093016, 92243093017, 92243093018
METHOD BLANK: 1172374
1172376
Matrix: Solid
Units
Associated Lab Samples:
mg/kg
Sulfate
mg/kg
Blank Reporting
1172378
Parameter
Units
Result Limit
Analyzed Qualifiers
Chloride
mg/kg
ND 49.5
04/03/15 00:40
Sulfate
mg/kg
ND 49.5
04/03/15 00:40
LABORATORY CONTROL SAMPLE:
1172376
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1172378
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
SAMPLE DUPLICATE: 1172377
Parameter
Chloride
Sulfate
Pace Analytical Services, Inc.
Padg"MrWy te. Suite 100
Huntersville, NC 28078
[phone]
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
497 524 105 80-120
497 513 103 80-120
92243245003 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 1190 1010 77 80-120 MO
ND 1190 1040 88 80-120
92243245003 Dup
Units Result Result
mg/kg ND ND
mg/kg ND ND
Max
RPD RPD Qualifiers
20
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
Padg"ifyte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
QC Batch: WETA/45038
Analysis Method: EPA 9056
QC Batch Method: EPA 9056
Analysis Description: 9056 IC Anions
Associated Lab Samples: 92243093007,92243093008,92243093009,92243093010,92243093011,92243093012,92243093013
METHOD BLANK: 1171696
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 5.0 04/02/15 14:40
LABORATORY CONTROL SAMPLE:
1171697
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Nitrate as N
mg/kg
49.9 47.9 96
80-120
MATRIX SPIKE SAMPLE:
1171699
92243087001 Spike MS
MS % Rec
Parameter
Units
Result Conc. Result
% Rec Limits Qualifiers
Nitrate as N
mg/kg
ND 66.2 60.5
91 80-120 H3
SAMPLE DUPLICATE: 1171698
92243087001 Dup
Max
Parameter
Units
Result Result RPD
RPD Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
Padg"Wfyte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
QC Batch: WETA/45063
Analysis Method: EPA 9056
QC Batch Method: EPA 9056
Analysis Description: 9056 IC Anions
Associated Lab Samples: 92243093014, 92243093015, 92243093016, 92243093017, 92243093018
METHOD BLANK: 1172585
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 5.0 04/03/15 00:40
LABORATORY CONTROL SAMPLE:
1172586
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits
Qualifiers
Nitrate as N
mg/kg
49.7 52.6 106
80-120
MATRIX SPIKE SAMPLE:
1172588
92243245003 Spike MS
MS
% Rec
Parameter
Units
Result Conc. Result
% Rec
Limits Qualifiers
Nitrate as N
mg/kg
ND 119 107
91 80-120 H3
SAMPLE DUPLICATE: 1172587
92243245003 Dup
Max
Parameter
Units
Result Result RPD
RPD
Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
Padg"ifyte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030693
Pace Project No.: 92243093
QC Batch: WETA/27997
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92243093007,92243093008,92243093009,92243093010,92243093011,92243093012,92243093013,
92243093014,92243093015,92243093016,92243093017,92243093018
METHOD BLANK: 1140556
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600 04/15/15 06:45
LABORATORY CONTROL SAMPLE: 1140557
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000 122000 102 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1140558 1140559
MS MSD
92243093008
Spike Spike MS MSD MS MSD
% Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec
Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg ND
6400 6440 6210 7100 92 105
50-150 13 30
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1140560 1140561
MS MSD
92243093015
Spike Spike MS MSD MS MSD
% Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec
Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 64800
86200 88500 153000 153000 102 100
50-150 0 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc..
Page 92 of 100

Pace Analytical Services, Inc
aceAnalXical ® Pa���1�i �'�e. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALIFIERS
Project: J15030693
Pace Project No.: 92243093
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A
Pace Analytical Services - Asheville
PASI-G
Pace Analytical Services - Green Bay
PASI-M
Pace Analytical Services - Minneapolis
PASI-O
Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
B Analyte was detected in the associated method blank.
D3 D3
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
D4 Sample was diluted due to the presence of high levels of target analytes.
D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
H1 Analysis conducted outside the EPA method holding time.
H3 Sample was received or analysis requested beyond the recognized method holding time.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
N2 The lab does not hold TNI accreditation for this parameter.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Padgaplypyt.. Suite 100
Huntersville, INC 28078
[phone]
QUALIFIERS
Project: J15030693
Pace Project No.: 92243093
ANALYTE QUALIFIERS
Z2 Analyte present in the associated method blank above the detection limit.
REPORT OF LABORATORY ANALYSIS
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Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc.. Page 94 of 100

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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15030693
Pace Project No.: 92243093
Pace Analytical Services, Inc.
Padgom leyte. Suite 100
Huntersville, NC 28078
[phone]
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92243093007
2015008642
EPA
3050
MPRP/23404
EPA
6010
ICP/14316
92243093008
2015008643
EPA
3050
MPRP/23404
EPA
6010
ICP/14316
92243093009
2015008648
EPA
3050
MPRP/23404
EPA
6010
ICP/14316
92243093010
2015008651
EPA
3050
MPRP/23404
EPA
6010
ICP/14316
92243093011
2015008645
EPA
3050
MPRP/23404
EPA
6010
ICP/14316
92243093012
2015008646
EPA
3050
MPRP/23404
EPA6010
EPA 6020
ICP/14316
92243093013
2015008647
EPA
3050
MPRP/23404
EPA
6010
ICP/14316
92243093014
2015008649
EPA
3050
MPRP/23404
EPA
6010
ICP/14316
92243093015
2015008650
EPA
3050
MPRP/23404
EPA
6010
ICP/14316
92243093016
2015008652
EPA
3050
MPRP/23404
EPA
6010
ICP/14316
92243093017
2015008653
EPA
3050
MPRP/23404
EPA
6010
ICP/14316
92243093018
2015008654
EPA
3050
MPRP/23404
EPA
6010
ICP/14316
92243093007
2015008642
EPA 3050
MPRP/23405
EPA 6020
ICPM/9526
92243093008
2015008643
EPA 3050
MPRP/23405
EPA 6020
ICPM/9526
92243093009
2015008648
EPA 3050
MPRP/23405
EPA 6020
ICPM/9526
92243093010
2015008651
EPA 3050
MPRP/23405
EPA 6020
ICPM/9526
92243093011
2015008645
EPA 3050
MPRP/23405
EPA 6020
ICPM/9526
92243093012
2015008646
EPA 3050
MPRP/23405
EPA 6020
ICPM/9526
92243093013
2015008647
EPA 3050
MPRP/23405
EPA 6020
ICPM/9526
92243093014
2015008649
EPA 3050
MPRP/23405
EPA 6020
ICPM/9526
92243093015
2015008650
EPA 3050
MPRP/23405
EPA 6020
ICPM/9526
92243093016
2015008652
EPA 3050
MPRP/23405
EPA 6020
ICPM/9526
92243093017
2015008653
EPA 3050
MPRP/23405
EPA 6020
ICPM/9526
92243093018
2015008654
EPA 3050
MPRP/23405
EPA 6020
ICPM/9526
92243093001
2015008641
EPA 3020
MPRP/53294
EPA 6020A
ICPM/23639
92243093002
2015008644
EPA 3020
MPRP/53294
EPA 6020A
ICPM/23639
92243093003
2015008642 SPLP
EPA 3020
MPRP/53628
EPA 6020A
ICPM/23839
92243093004
2015008643 SPLP
EPA 3020
MPRP/53628
EPA 6020A
ICPM/23839
92243093005
2015008648 SPLP
EPA 3020
MPRP/53628
EPA 6020A
ICPM/23839
92243093006
2015008651 SPLP
EPA 3020
MPRP/53628
EPA 6020A
ICPM/23839
92243093001
2015008641
EPA 7470
MERP/13104
EPA 7470
MERC/15220
92243093002
2015008644
EPA 7470
MERP/13104
EPA 7470
MERC/15220
92243093003
2015008642 SPLP
EPA 7470
MERP/13232
EPA 7470
MERC/15387
92243093004
2015008643 SPLP
EPA 7470
MERP/13232
EPA 7470
MERC/15387
92243093005
2015008648 SPLP
EPA 7470
MERP/13232
EPA 7470
MERC/15387
92243093006
2015008651 SPLP
EPA 7470
MERP/13232
EPA 7470
MERC/15387
92243093007
2015008642
EPA 7471
MERP/5552
EPA 7471
MERC/5540
92243093008
2015008643
EPA 7471
MERP/5552
EPA 7471
MERC/5540
92243093009
2015008648
EPA 7471
MERP/5552
EPA 7471
MERC/5540
92243093010
2015008651
EPA 7471
MERP/5552
EPA 7471
MERC/5540
92243093011
2015008645
EPA 7471
MERP/5552
EPA 7471
MERC/5540
92243093012
2015008646
EPA 7471
MERP/5552
EPA 7471
MERC/5540
92243093013
2015008647
EPA 7471
MERP/5552
EPA 7471
MERC/5540
92243093014
2015008649
EPA 7471
MERP/5552
EPA 7471
MERC/5540
92243093015
2015008650
EPA 7471
MERP/5552
EPA 7471
MERC/5540
92243093016
2015008652
EPA 7471
MERP/5552
EPA 7471
MERC/5540
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc.. Page 95 of 100

aceAnaiXical
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15030693
Pace Project No.: 92243093
Lab ID Sample ID QC Batch Method QC Batch
92243093017
2015008653
EPA 7471
M ERP/5552
92243093018
2015008654
EPA 7471
MERP/5552
92243093007
2015008642
ASTM D2974-87
PMST/3411
92243093008
2015008643
ASTM D2974-87
PMST/3411
92243093009
2015008648
ASTM D2974-87
PMST/3411
92243093010
2015008651
ASTM D2974-87
PMST/3411
92243093011
2015008645
ASTM D2974-87
PMST/3411
92243093012
2015008646
ASTM D2974-87
PMST/3411
92243093013
2015008647
ASTM D2974-87
PMST/3411
92243093014
2015008649
ASTM D2974-87
PMST/3411
92243093015
2015008650
ASTM D2974-87
PMST/3411
92243093016
2015008652
ASTM D2974-87
PMST/3411
92243093017
2015008653
ASTM D2974-87
PMST/3411
92243093018
2015008654
ASTM D2974-87
PMST/3411
92243093007
2015008642
EPA 9045
WET/36550
92243093008
2015008643
EPA 9045
WET/36550
92243093009
2015008648
EPA 9045
WET/36581
92243093010
2015008651
EPA 9045
WET/36581
92243093011
2015008645
EPA 9045
WET/36581
92243093012
2015008646
EPA 9045
WET/36581
92243093013
2015008647
EPA 9045
WET/36581
92243093014
2015008649
EPA 9045
WET/36581
92243093015
2015008650
EPA 9045
WET/36581
92243093016
2015008652
EPA 9045
WET/36581
92243093017
2015008653
EPA 9045
WET/36581
92243093018
2015008654
EPA 9045
WET/36581
92243093007
2015008642
EPA 300.0
WETA/22469
92243093008
2015008643
EPA 300.0
WETA/22469
92243093009
2015008648
EPA 300.0
WETA/22469
92243093010
2015008651
EPA 300.0
WETA/22469
92243093007
2015008642
EPA 353.2
WETA/22500
92243093008
2015008643
EPA 353.2
WETA/22500
92243093009
2015008648
EPA 353.2
WETA/22500
92243093010
2015008651
EPA 353.2
WETA/22500
92243093007
2015008642
SM 4500 -CI -E
WETA/22478
92243093008
2015008643
SM 4500 -CI -E
WETA/22478
92243093009
2015008648
SM 4500 -CI -E
WETA/22478
92243093010
2015008651
SM 4500 -CI -E
WETA/22478
92243093007
2015008642
EPA 9056
WETA/45037
92243093008
2015008643
EPA 9056
WETA/45037
92243093009
2015008648
EPA 9056
WETA/45037
92243093010
2015008651
EPA 9056
WETA/45037
92243093011
2015008645
EPA 9056
WETA/45037
92243093012
2015008646
EPA 9056
WETA/45037
92243093013
2015008647
EPA 9056
WETA/45037
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 08:01 AM without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
Padgop1lswleyte. Suite 100
Huntersville, NC 28078
[phone]
Analytical Method
EPA 7471
EPA 7471
Analytical
Batch
MERC/5540
MERC/5540
Page 96 of 100

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15030693
Pace Project No.: 92243093
Lab ID
Sample ID
QC Batch Method
QC Batch
92243093014
2015008649
EPA
9056
WETA/45049
92243093015
2015008650
EPA
9056
WETA/45049
92243093016
2015008652
EPA
9056
WETA/45049
92243093017
2015008653
EPA
9056
WETA/45049
92243093018
2015008654
EPA
9056
WETA/45049
92243093007
2015008642
EPA
9056
WETA/45038
92243093008
2015008643
EPA
9056
WETA/45038
92243093009
2015008648
EPA
9056
WETA/45038
92243093010
2015008651
EPA
9056
WETA/45038
92243093011
2015008645
EPA
9056
WETA/45038
92243093012
2015008646
EPA
9056
WETA/45038
92243093013
2015008647
EPA
9056
WETA/45038
92243093014
2015008649
EPA
9056
WETA/45063
92243093015
2015008650
EPA
9056
WETA/45063
92243093016
2015008652
EPA
9056
WETA/45063
92243093017
2015008653
EPA
9056
WETA/45063
92243093018
2015008654
EPA
9056
WETA/45063
92243093007
2015008642
EPA
9060
WETA/27997
92243093007
2015008642
EPA
9060
WETA/27998
92243093008
2015008643
EPA
9060
WETA/27997
92243093008
2015008643
EPA
9060
WETA/27998
92243093009
2015008648
EPA
9060
WETA/27997
92243093009
2015008648
EPA
9060
WETA/27998
92243093010
2015008651
EPA
9060
WETA/27997
92243093010
2015008651
EPA
9060
WETA/27998
92243093011
2015008645
EPA
9060
WETA/27997
92243093011
2015008645
EPA
9060
WETA/27998
92243093012
2015008646
EPA
9060
WETA/27997
92243093012
2015008646
EPA
9060
WETA/27998
92243093013
2015008647
EPA
9060
WETA/27997
92243093013
2015008647
EPA
9060
WETA/27998
92243093014
2015008649
EPA
9060
WETA/27997
92243093014
2015008649
EPA
9060
WETA/27998
92243093015
2015008650
EPA
9060
WETA/27997
92243093015
2015008650
EPA
9060
WETA/27998
92243093016
2015008652
EPA
9060
WETA/27997
92243093016
2015008652
EPA
9060
WETA/27998
Date: 04/29/2015 08:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
PadooBryne. Suite 100
Huntersville, NC 28078
[phone]
Analytical Method
Analytical
Batch
Page 97 of 100

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15030693
Pace Project No.: 92243093
Lab ID
Sample ID
QC Batch Method
QC Batch
92243093017
2015008653
EPA 9060
WETA/27997
92243093017
2015008653
EPA 9060
WETA/27998
92243093018
2015008654
EPA 9060
WETA/27997
92243093018
2015008654
EPA 9060
WETA/27998
Date: 04/29/2015 08:01 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
Padgom leyte. Suite 100
Huntersville, NC 28078
[phone]
Analytical Method
Analytical
Batch
Page 98 of 100

,.. s�coAnalytrc�l'
uocument Name: rxuvlJvu. QUVLl 'iiiucl
Condition Upon Receipt (SCUR) Pa9e 1 of 2
Document Number: Issuing At�hori�
F-CHR-CS-003-rev.15 Pace Huntersville uaityf ice
Client Name: -LA 4. ('Ivrv�
Courier: ❑led Ex ❑ UPS❑ USPS[] Client❑�no
ercial❑ ac Other tj
ans .
Custody Seal on Cooler/Box Present: ❑ yes Seals intact: ❑ yes ❑ no :.Nam.'n
Packing Material: ❑ Bubble V❑, - Bubble Bags ❑ None ❑ Other
Thermometer Used: IR Gun 14 Type of I�lue None Samples on ice, cooling process has begun
Tmmn ('nrrac4inn Farfinr T'id0l Nn Cnrrartinn
Temp.: •C
Corrected Cooler Tem
Temp should be above freezing to 6°C
Chain of Custody Present:
Biological Tissue is Frozen: Yes H NIA
Comments:
es © DNIA 1.
ate and Initial L erson exa� in .
contents: �d,/
Chain of Custody Filled Out:
E Yes PNo
❑NIA
2.
Chain of Custody Relinquished:
es ❑ o
Ll NIA
3.
Sampler Name & Signature on COC:
f s o
DNIA
4.
Samples Arrived within Hold Time:
D es L3 No
❑NIA
6.
Short Hold Time Analysis (<72hr):
Dyes M o
PNIA
6.
Rush Turn Around Time Requested:
Dyes o
❑NIA
7.
Sufficient Volume:
Yes N6
❑N/A
8.
Correct Containers Used:
-Pace Containers Used:
ffYes DN
Dyes o
NIA
DNIA
9.
Containers Intact:
0 Yes ONO
❑NIA
1 .
Filtered volume received for Dissolved tests
Dyes o
MWA
11.
Sample Labels match COC:
-Includes date/time/ID/Analysis Matrix:
Elles ONO
❑NIA
12.
All containers needing preservation have been cheated.
All containers needing preservation are found to be in
compliance with EPA recommendation,
exceptions: VOA, coliform, TOC, 0&G, WI -DRO (water)
Ek-," El No ❑NIA
es ❑No ❑NIA
Dyes LJFJo
13.
Samples checked for dechlorination:
Dyes ONO
❑
Headspace in VOA Vials (>6mm):
Dyes ON
q IA
4 5.
Trip Blank Present:
Trip Blank Custody Seals Present
Pace Trip Blank Lot # (if purchased):
Dyes ❑No
Dyes GNoIA
P, 1A
6.
Client Notification/ Resolution: Field Data Required? Y 1 N
Person Contacted: Date/Time:
Comments/ Resolution:
SCURF Reviewd SRF Review: �/� � [Date: 1I]ate: ��r� �(r5� wo# • 922'43093
Note: Whenever there is a discrepancy affecting North Carolina compliance
samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office ( Le out of hold, incorrect preservative, out of temp, 92243093
incorrect containers)
Page 99 of 100

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Anions; C,, NYlrataA. Soo Sedilnunt Speck is Parameter: `fs$QI Id® CEG, Particle Sire DlcalribLrlipn, Redox Pott; Val
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