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Home My WebLink AboutNC0000396_J15030498 Report_20150823DUE Analytical Laboratory Page 1 of 49 ' ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report J15030498 ASHEVILLE - AB GW ASSESSMENT SOIL Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker 200 CP and L Drive Arden,NC 28704 Margaret Galvin -Karr Phone: 980-875-5219 Margaret Galvin -Karr ma rge.ga Ivi n-karr@duke- energy.com Date: 2015.05.12 12:25:20 -04'00' Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 5/5/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time 2015007765 2015007766 2015007767 2015007768 2015007769 5 Total Samples Collected By Sample Description ASHEVILLE 16 -Mar -15 1:30 PM illegible Equipment Blank ASHEVILLE 16 -Mar -15 2:00 PM illegible MW -12 SB (1.5-2) ASHEVILLE 16 -Mar -15 3:15 PM illegible MW -12 SB (36-38) ASHEVILLE 16 -Mar -15 3:30 PM illegible MW -12 SB (42-43) ASHEVILLE 16 -Mar -15 3:50 PM illegible MW -12 SB (52-54) Page 2 of 49 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: LU Job Summary Report ❑ Sample Identification P/1 Technical Validation of Data Package J❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Page 3 of 49 LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries d❑ Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 5/5/2015 Certificate of Laboratory Analysis Page 4 of 49 This report shall not be reproduced, except in full. Order # J15030498 Site: Equipment Blank Collection Date: 16 -Mar -15 1:30 PM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015007765 Matrix: OTHER Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030498 Site: MW -12 SB (1.5-2) Collection Date: 16 -Mar -15 2:00 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 5 of 49 Sample #: 2015007766 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030498 Site: MW -12 SB (36-38) Collection Date: 16 -Mar -15 3:15 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 6 of 49 Sample #: 2015007767 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030498 Site: MW -12 SB (42-43) Collection Date: 16 -Mar -15 3:30 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 7 of 49 Sample #: 2015007768 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030498 Site: MW -12 SB (52-54) Collection Date: 16 -Mar -15 3:50 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 8 of 49 Sample #: 2015007769 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE -- Additional Information -- Sample 2015007769 was used as the duplicate for % moisture. The RPD was 93%, well above the acceptance range of 20%. M. Galvin -Karr 5/5/2015 aceAnaiXical www.pacelabs.com April 27, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: J15030498 Pace Project No.: 92241963 Pace Analytical Services, Inc. 9P2Q.�C§,8yhe. Suite 100 �Huntersville, INC 28078 (704)875-9092 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on March 19, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy HiQ p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 40 aceAnaiXical www.pacelabs.com Project: J15030498 Pace Project No.: 92241963 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification M PH -0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification M E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 Pace Analytical Services, Inc. 098gfii6'8yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Montana Certification #: Cert 0074 Nebraska Certification: NE -OS -28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification M FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification M 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 40 aceAnaiXical www.pacelabs.com SAMPLE SUMMARY Project: J15030498 Pace Project No.: 92241963 Lab ID Sample ID Matrix Date Collected Date Received 92241963002 201507766 Solid 03/16/1514:00 03/19/1515:00 92241963003 201507767 Solid 03/16/1515:15 03/19/1515:00 92241963004 201507768 Solid 03/16/1515:30 03/19/1515:00 92241963005 201507769 Solid 03/16/1515:50 03/19/1515:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. �Q�ff�in�c&fie. Suite100 y Huntersville, NC 28078 (704)875-9092 Page 3 of 40 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 098gfliQ'8yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15030498 92241963 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92241963002 201507766 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241963003 201507767 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241963004 201507768 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241963005 201507769 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 40 aceAnaiXical www.pacelabs.com SUMMARY OF DETECTION Pace Analytical Services, Inc. 09Qgffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15030498 92241963 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92241963002 201507766 EPA 6010 Aluminum 26200 mg/kg 64.0 03/29/1516:24 D4,M6,R1 EPA 6010 Barium 205 mg/kg 6.4 03/29/1516:24 D3,M6 EPA 6010 Beryllium 1.9 mg/kg 0.64 03/29/1516:24 D3,M6 EPA 6010 Calcium 1390 mg/kg 320 03/29/1516:24 D3,M6,R1 EPA 6010 Chromium 22.2 mg/kg 3.2 03/29/1516:24 D3,M6 EPA 6010 Copper 11.3 mg/kg 3.2 03/29/15 16:24 D3,M6,R1 EPA 6010 Iron 32500 mg/kg 51.2 03/31/1512:12 D4,M6,R1 EPA 6010 Magnesium 7290 mg/kg 320 03/29/15 16:24 D3,M6,R1 EPA 6010 Manganese 664 mg/kg 6.4 03/31/1512:12 D4,M6 EPA 6010 Nickel 19.7 mg/kg 3.2 03/29/1516:24 D3,M6 EPA 6010 Potassium 6990 mg/kg 640 03/29/1516:24 D3,M6,R1 EPA 6010 Strontium 31.6 mg/kg 12.8 03/31/1512:12 D3,M6,R1 EPA 6010 Zinc 128 mg/kg 12.8 03/29/1516:24 D3,M6 EPA 6020 Arsenic 3.6 mg/kg 3.2 03/30/15 16:35 D3 EPA 6020 Cobalt 24.0 mg/kg 3.2 03/30/15 16:35 D3 EPA 6020 Lead 12.5 mg/kg 3.2 03/30/15 16:35 D3 EPA 6020 Selenium 5.1 mg/kg 3.2 03/30/15 16:35 D3 EPA 6020 Vanadium 35.3 mg/kg 3.2 03/30/15 16:35 D4 EPA 7471 Mercury 0.0079J mg/kg 0.011 03/31/15 07:56 ASTM D2974-87 Percent Moisture 22.7 % 0.10 03/30/15 12:56 EPA 9045 pH at 25 Degrees C 7.3 Std. Units 0.10 03/26/15 11:30 EPA 9056 Chloride 246J mg/kg 320 03/25/15 23:42 D3 EPA 9056 Sulfate 204J mg/kg 320 03/25/15 23:42 D3 EPA 9060 Total Organic Carbon 5620 mg/kg 780 03/27/15 11:31 EPA 9060 Total Organic Carbon 3320 mg/kg 770 03/27/15 11:36 EPA 9060 Total Organic Carbon 4020 mg/kg 778 03/27/15 11:43 EPA 9060 Total Organic Carbon 3770 mg/kg 776 03/27/15 11:49 EPA 9060 Mean Total Organic Carbon 4180 mg/kg 776 03/27/15 11:31 EPA 9060 RSD% 23.9 % 03/27/15 11:31 92241963003 201507767 EPA 6010 Aluminum 20200 mg/kg 115 03/29/15 16:37 D3 EPA 6010 Barium 205 mg/kg 11.5 03/29/15 16:37 D3 EPA 6010 Beryllium 1.1J mg/kg 1.2 03/29/1516:37 D3 EPA 6010 Chromium 37.8 mg/kg 5.8 03/29/15 16:37 D3 EPA 6010 Copper 14.8 mg/kg 5.8 03/29/15 16:37 D3 EPA 6010 Iron 50400 mg/kg 92.0 03/31/1512:24 D4 EPA 6010 Magnesium 8320 mg/kg 575 03/29/15 16:37 D3 EPA 6010 Manganese 2940 mg/kg 11.5 03/31/1512:24 D3 EPA 6010 Nickel 24.2 mg/kg 5.8 03/29/15 16:37 D3 EPA 6010 Potassium 8410 mg/kg 1150 03/29/15 16:37 D3 EPA 6010 Zinc 116 mg/kg 23.0 03/29/15 16:37 D3 EPA 6020 Arsenic 8.6 mg/kg 5.8 03/30/1516:54 D3,M6 EPA 6020 Cobalt 35.3 mg/kg 5.8 03/30/1516:54 D3,M6 EPA 6020 Lead 19.3 mg/kg 5.8 03/30/1516:54 D3,M6 EPA 6020 Selenium 10.6 mg/kg 5.8 03/30/1516:54 D3,M6 EPA 6020 Vanadium 73.7 mg/kg 5.8 03/30/1516:54 D4,M6 ASTM D2974-87 Percent Moisture 55.0 % 0.10 03/30/15 12:57 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 40 aceAnaiXical www.pacelabs.com Project: J15030498 Pace Project No.: 92241963 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 098gfli4'8yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92241963003 201507767 EPA 9045 pH at 25 Degrees C 5.8 Std. Units 0.10 03/26/15 11:30 EPA 9060 Total Organic Carbon 832J mg/kg 1330 03/27/15 11:56 EPA 9060 Total Organic Carbon 1160J mg/kg 1330 03/27/15 12:02 EPA 9060 Total Organic Carbon 699J mg/kg 1320 03/27/15 12:15 EPA 9060 Mean Total Organic Carbon 793J mg/kg 1330 03/27/15 11:56 EPA 9060 RSD% 36.2 % 03/27/15 11:56 92241963004 201507768 EPA 6010 Aluminum 6020 mg/kg 52.2 03/29/15 16:46 D3 EPA 6010 Barium 54.3 mg/kg 5.2 03/29/15 16:46 D3 EPA 6010 Beryllium 1.2 mg/kg 0.52 03/29/15 16:46 D3 EPA 6010 Chromium 6.3 mg/kg 2.6 03/29/15 16:46 D3 EPA 6010 Copper 13.8 mg/kg 2.6 03/29/15 16:46 D3 EPA 6010 Iron 37800 mg/kg 41.8 03/31/1512:28 D3 EPA 6010 Magnesium 556 mg/kg 261 03/29/15 16:46 D3 EPA 6010 Manganese 2440 mg/kg 5.2 03/31/1512:28 D3 EPA 6010 Nickel 17.3 mg/kg 2.6 03/29/15 16:46 D3 EPA 6010 Potassium 313J mg/kg 522 03/29/15 16:46 D3 EPA 6010 Zinc 17.7 mg/kg 10.4 03/29/15 16:46 D3 EPA 6020 Arsenic 4.6 mg/kg 2.6 03/30/15 17:01 D3 EPA 6020 Cobalt 48.0 mg/kg 2.6 03/30/15 17:01 D4 EPA 6020 Lead 9.9 mg/kg 2.6 03/30/15 17:01 D3 EPA 6020 Selenium 5.2 mg/kg 2.6 03/30/15 17:01 D3 EPA 6020 Vanadium 34.2 mg/kg 2.6 03/30/15 17:01 D4 ASTM D2974-87 Percent Moisture 5.0 % 0.10 03/30/15 12:57 EPA 9045 pH at 25 Degrees C 5.4 Std. Units 0.10 03/26/15 11:30 D6 EPA 9060 Total Organic Carbon 1260 mg/kg 633 03/27/15 12:20 EPA 9060 Total Organic Carbon 795 mg/kg 635 03/27/15 12:27 EPA 9060 Total Organic Carbon 1520 mg/kg 635 03/27/15 12:33 EPA 9060 Total Organic Carbon 836 mg/kg 635 03/27/15 12:39 EPA 9060 Mean Total Organic Carbon 1100 mg/kg 635 03/27/15 12:20 EPA 9060 RSD% 31.5 % 03/27/15 12:20 92241963005 201507769 EPA 6010 Aluminum 8930 mg/kg 5.7 03/28/15 22:34 EPA 6010 Barium 146 mg/kg 0.57 03/28/15 22:34 EPA 6010 Beryllium 0.49 mg/kg 0.29 03/29/15 16:51 D3 EPA 6010 Calcium 172 mg/kg 28.7 03/28/15 22:34 EPA 6010 Chromium 11.7 mg/kg 1.4 03/29/15 16:51 D3 EPA 6010 Iron 16900 mg/kg 46.0 03/31/1512:44 D4 EPA 6010 Magnesium 5230 mg/kg 144 03/29/15 16:51 D3 EPA 6010 Manganese 248 mg/kg 5.7 03/31/1512:44 D3 EPA 6010 Nickel 6.5 mg/kg 0.29 03/28/15 22:34 EPA 6010 Potassium 5780 mg/kg 57.4 03/28/15 22:34 EPA 6010 Sodium 201J mg/kg 287 03/29/1516:51 D3 EPA 6010 Zinc 42.0 mg/kg 1.1 03/28/15 22:34 EPA 6020 Cobalt 5.4 mg/kg 2.9 03/30/15 17:04 D3 EPA 6020 Lead 4.8 mg/kg 2.9 03/30/15 17:04 D3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 40 aceAnaiXical www.pacelabs.com Project: J15030498 Pace Project No.: 92241963 Lab Sample ID Method Client Sample ID Parameters 92241963005 201507769 EPA 6020 Selenium EPA 6020 Vanadium ASTM D2974-87 Percent Moisture EPA 9045 pH at 25 Degrees C EPA 9060 RSD% SUMMARY OF DETECTION Result Units 2.9 1.7J mg/kg 17.9 mg/kg 10.4 % 7.7 Std. Units 7.4 % REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 09Qgffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Report Limit Analyzed Qualifiers 2.9 03/30/1517:04 D3 2.9 03/30/1517:04 D3 0.10 03/30/1512:57 D6 0.10 03/26/1511:30 03/27/15 12:45 Page 7 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 li %rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030498 Pace Project No.: 92241963 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 27, 2015 General Information: 4 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23301 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241963002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1168167) • Aluminum • Barium • Beryllium • Calcium • Copper • Iron • Magnesium • Manganese • Molybdenum • Potassium • MSD (Lab ID: 1168168) • Aluminum • Barium • Beryllium • Calcium • Chromium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Qgfflic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030498 Pace Project No.: 92241963 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 27, 2015 QC Batch: MPRP/23301 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241963002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • Iron • Magnesium • Manganese • Nickel • Potassium • Strontium • Zinc R1: RPD value was outside control limits. • MSD (Lab ID: 1168168) • Aluminum • Calcium • Copper • Iron • Magnesium • Potassium • Strontium Additional Comments: Analyte Comments: QC Batch: MPRP/23301 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •201507766 (Lab ID: 92241963002) • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Potassium • Magnesium • Molybdenum • Sodium • Nickel • Strontium • Zinc •201507767 (Lab ID: 92241963003) • Aluminum • Boron • Barium • Beryllium • Calcium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 i %rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030498 Pace Project No.: 92241963 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 27, 2015 Analyte Comments: QC Batch: MPRP/23301 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • 201507767 (Lab ID: 92241963003) • Chromium • Copper • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •201507768 (Lab ID: 92241963004) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •201507769 (Lab ID: 92241963005) • Boron • Beryllium • Chromium • Copper • Magnesium • Manganese • Sodium • Strontium • MSD (Lab ID: 1168168) • Aluminum • Boron • Barium • Beryllium • Calcium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 li '8yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030498 Pace Project No.: 92241963 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 27, 2015 Analyte Comments: QC Batch: MPRP/23301 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • MSD (Lab ID: 1168168) • Chromium • Copper • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc D4: Sample was diluted due to the presence of high levels of target analytes. •201507766 (Lab ID: 92241963002) • Aluminum • Iron • Manganese •201507767 (Lab ID: 92241963003) • Iron •201507769 (Lab ID: 92241963005) • Iron • MSD (Lab ID: 1168168) • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 i -8fhe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030498 Pace Project No.: 92241963 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 27, 2015 General Information: 4 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23302 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241963003 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1168177) • Antimony • Arsenic • Cobalt • Lead • Selenium • Vanadium • MSD (Lab ID: 1168178) • Antimony • Arsenic • Cobalt • Lead • Selenium • Vanadium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKinic&rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030498 Pace Project No.: 92241963 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 27, 2015 Additional Comments: Analyte Comments: QC Batch: MPRP/23302 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •201507766 (Lab ID: 92241963002) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •201507767 (Lab ID: 92241963003) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •201507768 (Lab ID: 92241963004) • Arsenic • Cadmium • Lead • Antimony • Selenium • Thallium •201507769 (Lab ID: 92241963005) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • MS (Lab ID: 1168177) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 K n rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030498 Pace Project No.: 92241963 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 27, 2015 Analyte Comments: QC Batch: MPRP/23302 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • MSD (Lab ID: 1168178) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium D4: Sample was diluted due to the presence of high levels of target analytes. •201507766 (Lab ID: 92241963002) • Vanadium •201507767 (Lab ID: 92241963003) • Vanadium • 201507768 (Lab ID: 92241963004) • Cobalt • Vanadium • MS (Lab ID: 1168177) • Vanadium • MSD (Lab ID: 1168178) • Vanadium N2: The lab does not hold TNI accreditation for this parameter. •201507766 (Lab ID: 92241963002) • Antimony •201507767 (Lab ID: 92241963003) • Antimony •201507768 (Lab ID: 92241963004) • Antimony •201507769 (Lab ID: 92241963005) • Antimony • BLANK (Lab ID: 1168175) • Antimony • LCS (Lab ID: 1168176) • Antimony • MS (Lab ID: 1168177) • Antimony • MSD (Lab ID: 1168178) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKis rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030498 Pace Project No.: 92241963 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: April 27, 2015 General Information: 4 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gK4-8yhe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030498 Pace Project No.: 92241963 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: April 27, 2015 General Information: 4 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/36412 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1418509) • pH at 25 Degrees C • DUP (Lab ID: 1418510) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 i .8fhe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030498 Pace Project No.: 92241963 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: April 27, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44808 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •201507766 (Lab ID:92241963002) • Chloride • Sulfate •201507767 (Lab ID:92241963003) • Chloride • Sulfate •201507768 (Lab ID:92241963004) • Chloride • Sulfate •201507769 (Lab ID:92241963005) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�K�i�c&)rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030498 Pace Project No.: 92241963 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: April 27, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •201507766 (Lab ID: 92241963002) •201507767 (Lab ID: 92241963003) •201507768 (Lab ID: 92241963004) •201507769 (Lab ID: 92241963005) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44807 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •201507766 (Lab ID: 92241963002) • Nitrate as N •201507767 (Lab ID: 92241963003) • Nitrate as N • 201507768 (Lab ID: 92241963004) • Nitrate as N •201507769 (Lab ID: 92241963005) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098v i�c& rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030498 Pace Project No.: 92241963 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: April 27, 2015 General Information: 4 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 40 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030498 Pace Project No.: 92241963 Pace Analytical Services, Inc. 0988 %-& rhe. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 201507766 Lab ID: 92241963002 Collected: 03/16/15 14:00 Received: 03/19/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate Date: 04/27/2015 04:44 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 26200 mg/kg 64.0 32.0 10 03/27/1518:00 03/29/1516:24 7429-90-5 205 mg/kg 6.4 3.2 10 03/27/1518:00 03/29/1516:24 7440-39-3 1.9 mg/kg 0.64 0.32 10 03/27/1518:00 03/29/1516:24 7440-41-7 ND mg/kg 32.0 16.0 10 03/27/1518:00 03/29/1516:24 7440-42-8 1390 mg/kg 320 160 10 03/27/1518:00 03/29/1516:24 7440-70-2 22.2 mg/kg 3.2 1.6 10 03/27/1518:00 03/29/1516:24 7440-47-3 11.3 mg/kg 3.2 1.6 10 03/27/1518:00 03/29/1516:24 7440-50-8 32500 mg/kg 51.2 25.6 20 03/27/1518:00 03/31/1512:12 7439-89-6 7290 mg/kg 320 160 10 03/27/1518:00 03/29/1516:24 7439-95-4 664 mg/kg 6.4 3.2 20 03/27/1518:00 03/31/1512:12 7439-96-5 ND mg/kg 6.4 3.2 10 03/27/1518:00 03/29/1516:24 7439-98-7 19.7 mg/kg 3.2 1.6 10 03/27/1518:00 03/29/1516:24 7440-02-0 6990 mg/kg 640 320 10 03/27/1518:00 03/29/1516:24 7440-09-7 ND mg/kg 640 320 10 03/27/1518:00 03/29/1516:24 7440-23-5 31.6 mg/kg 12.8 6.4 20 03/27/1518:00 03/31/1512:12 7440-24-6 128 mg/kg 12.8 6.4 10 03/27/1518:00 03/29/1516:24 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 3.2 1.6 50 03/28/1518:00 03/30/1516:35 7440-36-0 3.6 mg/kg 3.2 1.6 50 03/28/1518:00 03/30/1516:35 7440-38-2 ND mg/kg 0.38 0.19 50 03/28/1518:00 03/30/1516:35 7440-43-9 24.0 mg/kg 3.2 1.6 50 03/28/1518:00 03/30/1516:35 7440-48-4 12.5 mg/kg 3.2 1.6 50 03/28/1518:00 03/30/1516:35 7439-92-1 5.1 mg/kg 3.2 1.6 50 03/28/1518:00 03/30/1516:35 7782-49-2 ND mg/kg 3.2 1.6 50 03/28/1518:00 03/30/1516:35 7440-28-0 35.3 mg/kg 3.2 1.6 50 03/28/1518:00 03/30/1516:35 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.0079J mg/kg 0.011 0.0053 1 03/30/15 13:23 03/31/15 07:56 7439-97-6 Analytical Method: ASTM D2974-87 22.7 % 0.10 0.10 1 03/30/1512:56 Analytical Method: EPA 9045 7.3 Std. Units 0.10 0.10 1 03/26/15 11:30 Analytical Method: EPA 9056 D4,M6, R1 D3,M6 D3,M6 D3 D3,M6, R1 D3,M6 D3,M6, R1 D4,M6, R1 D3,M6, R1 D4,M6 D3,M6 D3,M6 D3,M6, R1 D3 D3,M6, R1 D3,M6 D3,N2 D3 D3 D3 D3 D3 D3 D4 246J mg/kg 320 160 5 03/25/15 23:42 16887-00-6 D3 204J mg/kg 320 160 5 03/25/15 23:42 14808-79-8 D3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 40 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 0988 � -8fhe. Suite 100 �yJ Huntersville, NC 28078 (704)875-9092 Project: J15030498 Pace Project No.: 92241963 Sample: 201507766 Lab ID: 92241963002 Collected: 03/16/15 14:00 Received: 03/19/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 32.0 16.0 5 03/25/15 23:42 14797-55-8 D3,H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 5620 mg/kg 780 390 1 03/27/15 11:31 7440-44-0 Total Organic Carbon 3320 mg/kg 770 385 1 03/27/15 11:36 7440-44-0 Total Organic Carbon 4020 mg/kg 778 389 1 03/27/15 11:43 7440-44-0 Total Organic Carbon 3770 mg/kg 776 388 1 03/27/15 11:49 7440-44-0 Mean Total Organic Carbon 4180 mg/kg 776 388 1 03/27/15 11:31 7440-44-0 Surrogates RSD% 23.9 % 1 03/27/1511:31 Date: 04/27/2015 04:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 40 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030498 Pace Project No.: 92241963 Pace Analytical Services, Inc. 098nn rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 201507767 Lab ID: 92241963003 Collected: 03/16/15 15:15 Received: 03/19/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 04/27/2015 04:44 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 20200 mg/kg 115 57.5 10 03/27/1518:00 03/29/1516:37 7429-90-5 205 mg/kg 11.5 5.8 10 03/27/1518:00 03/29/1516:37 7440-39-3 1.1J mg/kg 1.2 0.58 10 03/27/1518:00 03/29/1516:37 7440-41-7 ND mg/kg 57.5 28.8 10 03/27/1518:00 03/29/1516:37 7440-42-8 ND mg/kg 575 288 10 03/27/1518:00 03/29/1516:37 7440-70-2 37.8 mg/kg 5.8 2.9 10 03/27/1518:00 03/29/1516:37 7440-47-3 14.8 mg/kg 5.8 2.9 10 03/27/1518:00 03/29/1516:37 7440-50-8 50400 mg/kg 92.0 46.0 20 03/27/1518:00 03/31/1512:24 7439-89-6 8320 mg/kg 575 288 10 03/27/1518:00 03/29/1516:37 7439-95-4 2940 mg/kg 11.5 5.8 20 03/27/1518:00 03/31/1512:24 7439-96-5 ND mg/kg 11.5 5.8 10 03/27/1518:00 03/29/1516:37 7439-98-7 24.2 mg/kg 5.8 2.9 10 03/27/1518:00 03/29/1516:37 7440-02-0 8410 mg/kg 1150 575 10 03/27/1518:00 03/29/1516:37 7440-09-7 ND mg/kg 1150 575 10 03/27/1518:00 03/29/1516:37 7440-23-5 ND mg/kg 23.0 11.5 20 03/27/1518:00 03/31/1512:24 7440-24-6 116 mg/kg 23.0 11.5 10 03/27/1518:00 03/29/1516:37 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 5.8 2.9 50 03/28/1518:00 03/30/1516:54 7440-36-0 8.6 mg/kg 5.8 2.9 50 03/28/1518:00 03/30/1516:54 7440-38-2 ND mg/kg 0.69 0.35 50 03/28/1518:00 03/30/1516:54 7440-43-9 35.3 mg/kg 5.8 2.9 50 03/28/1518:00 03/30/1516:54 7440-48-4 19.3 mg/kg 5.8 2.9 50 03/28/1518:00 03/30/1516:54 7439-92-1 10.6 mg/kg 5.8 2.9 50 03/28/1518:00 03/30/1516:54 7782-49-2 ND mg/kg 5.8 2.9 50 03/28/1518:00 03/30/1516:54 7440-28-0 73.7 mg/kg 5.8 2.9 50 03/28/1518:00 03/30/1516:54 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.018 0.0090 1 03/30/15 13:23 03/31/15 07:58 7439-97-6 Analytical Method: ASTM D2974-87 55.0 % 0.10 0.10 1 03/30/1512:57 Analytical Method: EPA 9045 5.8 Std. Units 0.10 0.10 1 03/26/15 11:30 Analytical Method: EPA 9056 D3 D3 D3 D3 D3 D3 D3 D4 D3 D3 D3 D3 D3 D3 D3 D3 D3,M6, N2 D3,M6 D3 D3,M6 D3,M6 D3,M6 D3 D4,M6 ND mg/kg 555 278 5 03/26/15 00:46 16887-00-6 D3 ND mg/kg 555 278 5 03/26/15 00:46 14808-79-8 D3 Analytical Method: EPA 9056 ND mg/kg 55.1 27.5 5 03/26/15 00:46 14797-55-8 D3,H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 40 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030498 Pace Project No.: 92241963 Pace Analytical Services, Inc. 098niy rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 201507767 Lab ID: 92241963003 Collected: 03/16/15 15:15 Received: 03/19/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 832J mg/kg 1330 666 1 03/27/15 11:56 7440-44-0 Total Organic Carbon 1160J mg/kg 1330 664 1 03/27/15 12:02 7440-44-0 Total Organic Carbon ND mg/kg 1330 665 1 03/27/15 12:08 7440-44-0 Total Organic Carbon 699J mg/kg 1320 661 1 03/27/15 12:15 7440-44-0 Mean Total Organic Carbon 793J mg/kg 1330 664 1 03/27/15 11:56 7440-44-0 Surrogates RSD% 36.2 % 1 03/27/1511:56 Date: 04/27/2015 04:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 40 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030498 Pace Project No.: 92241963 Pace Analytical Services, Inc. 098nn rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 201507768 Lab ID: 92241963004 Collected: 03/16/15 15:30 Received: 03/19/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 04/27/2015 04:44 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 6020 mg/kg 52.2 26.1 10 03/27/1518:00 03/29/1516:46 7429-90-5 54.3 mg/kg 5.2 2.6 10 03/27/1518:00 03/29/1516:46 7440-39-3 1.2 mg/kg 0.52 0.26 10 03/27/1518:00 03/29/1516:46 7440-41-7 ND mg/kg 26.1 13.0 10 03/27/1518:00 03/29/1516:46 7440-42-8 ND mg/kg 261 130 10 03/27/1518:00 03/29/1516:46 7440-70-2 6.3 mg/kg 2.6 1.3 10 03/27/1518:00 03/29/1516:46 7440-47-3 13.8 mg/kg 2.6 1.3 10 03/27/1518:00 03/29/1516:46 7440-50-8 37800 mg/kg 41.8 20.9 20 03/27/1518:00 03/31/1512:28 7439-89-6 556 mg/kg 261 130 10 03/27/1518:00 03/29/1516:46 7439-95-4 2440 mg/kg 5.2 2.6 20 03/27/1518:00 03/31/1512:28 7439-96-5 ND mg/kg 5.2 2.6 10 03/27/1518:00 03/29/1516:46 7439-98-7 17.3 mg/kg 2.6 1.3 10 03/27/1518:00 03/29/1516:46 7440-02-0 313J mg/kg 522 261 10 03/27/1518:00 03/29/1516:46 7440-09-7 ND mg/kg 522 261 10 03/27/1518:00 03/29/1516:46 7440-23-5 ND mg/kg 10.4 5.2 20 03/27/1518:00 03/31/1512:28 7440-24-6 17.7 mg/kg 10.4 5.2 10 03/27/1518:00 03/29/1516:46 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 2.6 1.3 50 03/28/1518:00 03/30/1517:01 7440-36-0 4.6 mg/kg 2.6 1.3 50 03/28/1518:00 03/30/1517:01 7440-38-2 ND mg/kg 0.31 0.16 50 03/28/1518:00 03/30/1517:01 7440-43-9 48.0 mg/kg 2.6 1.3 50 03/28/1518:00 03/30/1517:01 7440-48-4 9.9 mg/kg 2.6 1.3 50 03/28/1518:00 03/30/1517:01 7439-92-1 5.2 mg/kg 2.6 1.3 50 03/28/1518:00 03/30/1517:01 7782-49-2 ND mg/kg 2.6 1.3 50 03/28/1518:00 03/30/1517:01 7440-28-0 34.2 mg/kg 2.6 1.3 50 03/28/1518:00 03/30/1517:01 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0088 0.0044 1 03/30/15 13:23 03/31/15 08:00 7439-97-6 Analytical Method: ASTM D2974-87 5.0 % 0.10 0.10 1 03/30/1512:57 Analytical Method: EPA 9045 5.4 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 263 132 5 ND mg/kg 263 132 5 Analytical Method: EPA 9056 ND mg/kg 26.3 13.2 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3,N2 D3 D3 D4 D3 D3 D3 D4 UZ:I 03/26/15 01:08 16887-00-6 D3 03/26/15 01:08 14808-79-8 D3 03/26/15 01:08 14797-55-8 D3,H3 Page 24 of 40 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030498 Pace Project No.: 92241963 Pace Analytical Services, Inc. 09Q�K�i�c&rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 201507768 Lab ID: 92241963004 Collected: 03/16/15 15:30 Received: 03/19/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1260 mg/kg 633 316 1 03/27/15 12:20 7440-44-0 Total Organic Carbon 795 mg/kg 635 318 1 03/27/15 12:27 7440-44-0 Total Organic Carbon 1520 mg/kg 635 317 1 03/27/15 12:33 7440-44-0 Total Organic Carbon 836 mg/kg 635 318 1 03/27/15 12:39 7440-44-0 Mean Total Organic Carbon 1100 mg/kg 635 317 1 03/27/15 12:20 7440-44-0 Surrogates RSD% 31.5 % 1 03/27/1512:20 Date: 04/27/2015 04:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 40 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 09Q�K�i�c&rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030498 Pace Project No.: 92241963 Sample: 201507769 Lab ID: 92241963005 Collected: 03/16/15 15:50 Received: 03/19/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 8930 mg/kg 5.7 2.9 1 03/27/15 18:00 03/28/15 22:34 7429-90-5 Barium 146 mg/kg 0.57 0.29 1 03/27/15 18:00 03/28/15 22:34 7440-39-3 Beryllium 0.49 mg/kg 0.29 0.14 5 03/27/1518:00 03/29/1516:51 7440-41-7 D3 Boron ND mg/kg 14.4 7.2 5 03/27/1518:00 03/29/1516:51 7440-42-8 D3 Calcium 172 mg/kg 28.7 14.4 1 03/27/15 18:00 03/28/15 22:34 7440-70-2 Chromium 11.7 mg/kg 1.4 0.72 5 03/27/1518:00 03/29/1516:51 7440-47-3 D3 Copper ND mg/kg 5.7 2.9 20 03/27/1518:00 03/31/1512:44 7440-50-8 D3 Iron 16900 mg/kg 46.0 23.0 20 03/27/1518:00 03/31/1512:44 7439-89-6 D4 Magnesium 5230 mg/kg 144 71.8 5 03/27/1518:00 03/29/1516:51 7439-95-4 D3 Manganese 248 mg/kg 5.7 2.9 20 03/27/1518:00 03/31/1512:44 7439-96-5 D3 Molybdenum ND mg/kg 0.57 0.29 1 03/27/15 18:00 03/28/15 22:34 7439-98-7 Nickel 6.5 mg/kg 0.29 0.14 1 03/27/15 18:00 03/28/15 22:34 7440-02-0 Potassium 5780 mg/kg 57.4 28.7 1 03/27/15 18:00 03/28/15 22:34 7440-09-7 Sodium 201J mg/kg 287 144 5 03/27/1518:00 03/29/1516:51 7440-23-5 D3 Strontium ND mg/kg 11.5 5.7 20 03/27/1518:00 03/31/1512:44 7440-24-6 D3 Zinc 42.0 mg/kg 1.1 0.57 1 03/27/15 18:00 03/28/15 22:34 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 2.9 1.4 50 03/28/1518:00 03/30/1517:04 7440-36-0 D3,N2 Arsenic ND mg/kg 2.9 1.4 50 03/28/1518:00 03/30/1517:04 7440-38-2 D3 Cadmium ND mg/kg 0.34 0.17 50 03/28/1518:00 03/30/1517:04 7440-43-9 D3 Cobalt 5.4 mg/kg 2.9 1.4 50 03/28/1518:00 03/30/1517:04 7440-48-4 D3 Lead 4.8 mg/kg 2.9 1.4 50 03/28/1518:00 03/30/1517:04 7439-92-1 D3 Selenium 1.7J mg/kg 2.9 1.4 50 03/28/1518:00 03/30/1517:04 7782-49-2 D3 Thallium ND mg/kg 2.9 1.4 50 03/28/1518:00 03/30/1517:04 7440-28-0 D3 Vanadium 17.9 mg/kg 2.9 1.4 50 03/28/1518:00 03/30/1517:04 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0091 0.0045 1 03/30/15 13:23 03/31/15 08:03 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 10.4 % 0.10 0.10 1 03/30/15 12:57 D6 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 7.7 Std. Units 0.10 0.10 1 03/26/15 11:30 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 278 139 5 03/26/15 01:29 16887-00-6 D3 Sulfate ND mg/kg 278 139 5 03/26/15 01:29 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 27.8 13.9 5 03/26/15 01:29 14797-55-8 D3,H3 Date: 04/27/2015 04:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 40 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030498 Pace Project No.: 92241963 Pace Analytical Services, Inc. 098nn rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 201507769 Lab ID: 92241963005 Collected: 03/16/15 15:50 Received: 03/19/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 674 337 1 03/27/15 12:45 7440-44-0 Total Organic Carbon ND mg/kg 669 335 1 03/27/15 12:50 7440-44-0 Total Organic Carbon ND mg/kg 667 334 1 03/27/15 12:56 7440-44-0 Total Organic Carbon ND mg/kg 667 333 1 03/27/15 13:03 7440-44-0 Mean Total Organic Carbon ND mg/kg 669 335 1 03/27/15 12:45 7440-44-0 Surrogates RSD% 7.4 % 1 03/27/1512:45 Date: 04/27/2015 04:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 40 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098nn rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030498 Pace Project No.: 92241963 QC Batch: MERP/5523 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92241963002, 92241963003, 92241963004, 92241963005 METHOD BLANK: 1169198 Matrix: Solid Associated Lab Samples: 92241963002, 92241963003, 92241963004, 92241963005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0082 03/31/15 07:30 LABORATORY CONTROL SAMPLE: 1169199 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .081 0.075 93 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1169200 1169201 MS MSD 35180581001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.021 .0886 .092 0.12 0.11 114 92 80-120 14 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:44 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 40 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030498 Pace Project No.: 92241963 QC Batch: MPRP/23301 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92241963002, 92241963003, 92241963004, 92241963005 METHOD BLANK: 1168165 Matrix: Solid Associated Lab Samples: 92241963002, 92241963003, 92241963004, 92241963005 Blank Reporting Parameter Units Result Limit Analyzed Aluminum mg/kg ND 4.9 03/31/1511:59 Barium mg/kg ND 0.49 03/31/1511:59 Beryllium mg/kg ND 0.049 03/31/1511:59 Boron mg/kg ND 2.5 03/31/1511:59 Calcium mg/kg ND 24.7 03/31/1511:59 Chromium mg/kg ND 0.25 03/31/1511:59 Copper mg/kg ND 0.25 03/31/1511:59 Iron mg/kg ND 2.0 03/31/1511:59 Magnesium mg/kg ND 24.7 03/31/1511:59 Manganese mg/kg ND 0.25 03/31/1511:59 Molybdenum mg/kg ND 0.49 03/31/1511:59 Nickel mg/kg ND 0.25 03/31/1511:59 Potassium mg/kg ND 49.4 03/31/1511:59 Sodium mg/kg ND 49.4 03/31/1511:59 Strontium mg/kg ND 0.49 03/31/1511:59 Zinc mg/kg ND 0.99 03/31/1511:59 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1168166 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 128 128 100 80-120 Barium mg/kg 12.8 13.3 103 80-120 Beryllium mg/kg 1.3 1.3 102 80-120 Boron mg/kg 128 129 100 80-120 Calcium mg/kg 642 653 102 80-120 Chromium mg/kg 12.8 12.9 100 80-120 Copper mg/kg 12.8 12.6 98 80-120 Iron mg/kg 128 128 100 80-120 Magnesium mg/kg 642 646 101 80-120 Manganese mg/kg 12.8 13.0 101 80-120 Molybdenum mg/kg 12.8 12.7 99 80-120 Nickel mg/kg 12.8 13.1 102 80-120 Potassium mg/kg 642 675 105 80-120 Sodium mg/kg 642 691 108 80-120 Strontium mg/kg 12.8 12.8 100 80-120 Zinc mg/kg 64.2 66.2 103 80-120 Pace Analytical Services, Inc. 098v i�c& rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:44 PM without the written consent of Pace Analytical Services, Inc.. Page 29 of 40 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098nn rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030498 Pace Project No.: 92241963 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1168167 1168168 MS MSD 92241963002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 26200 150 159 27700 20300 1040 -3660 75-125 31 20 D3,M6, R1 Barium mg/kg 205 15 15.9 213 175 48 -194 75-125 20 20 D3,M6 Beryllium mg/kg 1.9 1.55 1.55 3.0 2.7 74 55 75-125 8 20 D3,M6 Boron mg/kg ND 150 159 128 148 82 90 75-125 14 20 D3 Calcium mg/kg 1390 749 798 2410 18400 137 2130 75-125 154 20 D3,M6, R1 Chromium mg/kg 22.2 15 15.9 36.0 32.7 92 66 75-125 10 20 D3,M6 Copper mg/kg 11.3 15 15.9 21.2 28.9 66 110 75-125 31 20 D3,M6, R1 Iron mg/kg 32500 150 159 32600 25100 54 -4690 75-125 26 20 D4,M6, R1 Magnesium mg/kg 7290 749 798 7500 15400 28 1010 75-125 69 20 D3,M6, R1 Manganese mg/kg 664 15 15.9 528 447 -907 -1360 75-125 17 20 D3,M6 Molybdenum mg/kg ND 15 15.9 11.1 12.8 74 80 75-125 14 20 D3,M6 Nickel mg/kg 19.7 15 15.9 31.5 29.5 79 62 75-125 6 20 D3,M6 Potassium mg/kg 6990 749 798 7060 5420 9 -196 75-125 26 20 D3,M6, R1 Sodium mg/kg ND 749 798 734 876 87 99 75-125 18 20 D3 Strontium mg/kg 31.6 15 15.9 45.9 56.7 96 157 75-125 21 20 D3,M6, R1 Zinc mg/kg 128 74.9 79.8 188 186 80 73 75-125 1 20 D3,M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:44 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 40 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030498 Pace Project No.: 92241963 QC Batch: MPRP/23302 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92241963002, 92241963003, 92241963004, 92241963005 METHOD BLANK: 1168175 Matrix: Solid LCS Result Associated Lab Samples: 92241963002, 92241963003, 92241963004, 92241963005 mg/kg 2.4 2.4 Blank Reporting Arsenic Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 03/30/1516:30 N2 Arsenic mg/kg ND 0.051 03/30/1516:30 Cadmium mg/kg ND 0.0061 03/30/1516:30 Cobalt mg/kg ND 0.051 03/30/1516:30 Lead mg/kg ND 0.051 03/30/1516:30 Selenium mg/kg ND 0.051 03/30/1516:30 Thallium mg/kg ND 0.051 03/30/1516:30 Vanadium mg/kg ND 0.051 03/30/1516:30 Pace Analytical Services, Inc. 098nn rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1168176 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.4 2.4 100 80-120 N2 Arsenic mg/kg 2.4 2.4 100 80-120 Cadmium mg/kg .24 0.25 101 80-120 Cobalt mg/kg 2.4 2.6 105 80-120 Lead mg/kg 2.4 2.4 99 80-120 Selenium mg/kg 2.4 2.3 95 80-120 Thallium mg/kg 2.4 2.5 103 80-120 Vanadium mg/kg 2.4 2.5 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1168177 MS 92241963003 Spike Parameter Units Result Conc. MSD Spike Conc. 1168178 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual Antimony mg/kg ND 5.33 5.77 3.6J 3.2J 68 56 75-125 20 D3,M6, N2 Arsenic mg/kg 8.6 5.33 5.77 12.3 12.4 71 67 75-125 1 20 D3,M6 Cadmium mg/kg ND .533 .577 0.67 0.66J 105 96 75-125 20 D3 Cobalt mg/kg 35.3 5.33 5.77 44.5 49.9 172 254 75-125 11 20 D3,M6 Lead mg/kg 19.3 5.33 5.77 28.7 31.2 178 209 75-125 8 20 D3,M6 Selenium mg/kg 10.6 5.33 5.77 12.5 11.5 37 17 75-125 8 20 D3,M6 Thallium mg/kg ND 5.33 5.77 7.3 7.1 105 94 75-125 3 20 D3 Vanadium mg/kg 73.7 5.33 5.77 72.6 82.4 -21 152 75-125 13 20 D4,M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:44 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 40 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030498 Pace Project No.: 92241963 QC Batch: PMST/3396 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92241963002, 92241963003, 92241963004, 92241963005 Pace Analytical Services, Inc. 098gwnrhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1169375 92241963005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 10.4 28.3 93 10 D6 SAMPLE DUPLICATE: 1169376 35180774003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 29.7 36.5 21 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:44 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 40 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030498 Pace Project No.: 92241963 QC Batch: WET/36412 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92241963002, 92241963003, 92241963004, 92241963005 Pace Analytical Services, Inc. 098gWinlc&�rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1418509 92242504025 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.9 5.7 3 10 D6 SAMPLE DUPLICATE: 1418510 Parameter pH at 25 Degrees C 92241963004 Dup Units Result Result Std. Units 5.4 5.5 Max RPD RPD Qualifiers 2 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:44 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 40 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030498 Pace Project No.: 92241963 QC Batch: WETA/44808 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92241963002, 92241963003, 92241963004, 92241963005 METHOD BLANK: 1165183 1165184 Matrix: Solid Units Associated Lab Samples: mg/kg Sulfate mg/kg Blank Reporting 1165186 Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.7 03/25/1519:25 Sulfate mg/kg ND 49.7 03/25/1519:25 LABORATORY CONTROL SAMPLE: 1165184 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1165186 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1165185 Parameter Chloride Sulfate Pace Analytical Services, Inc. 098gwnrhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 496 473 95 80-120 496 475 96 80-120 92241508001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 848 842 80 80-120 ND 848 851 87 80-120 92241508001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:44 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 40 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098gwnrhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030498 Pace Project No.: 92241963 QC Batch: WETA/44807 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92241963002, 92241963003, 92241963004, 92241963005 METHOD BLANK: 1165175 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 03/25/15 19:25 LABORATORY CONTROL SAMPLE: 1165176 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.6 49.6 100 80-120 MATRIX SPIKE SAMPLE: 1165178 92241508001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 84.8 83.5 98 80-120 H3 SAMPLE DUPLICATE: 1165177 92241508001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:44 PM without the written consent of Pace Analytical Services, Inc.. Page 35 of 40 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098m.8fhe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030498 Pace Project No.: 92241963 QC Batch: WETA/27740 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92241963002, 92241963003, 92241963004, 92241963005 METHOD BLANK: 1132149 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 03/27/15 06:06 LABORATORY CONTROL SAMPLE: 1132150 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 118000 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1132151 1132152 MS MSD 92241509002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 2100 9910 9890 11600 11900 96 99 50-150 3 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:44 PM without the written consent of Pace Analytical Services, Inc.. Page 36 of 40 Pace Analytical Services, Inc aceAnalXical ® � ��t i�c&rrhe. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: J15030498 Pace Project No.: 92241963 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D4 Sample was diluted due to the presence of high levels of target analytes. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 04:44 PM without the written consent of Pace Analytical Services, Inc.. Page 37 of 40 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15030498 Pace Project No.: 92241963 Pace Analytical Services, Inc. 098gwnrhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92241963002 201507766 EPA 3050 MPRP/23301 EPA 6010 92241963003 201507767 EPA 3050 MPRP/23301 EPA 6010 92241963004 201507768 EPA 3050 MPRP/23301 EPA 6010 92241963005 201507769 EPA 3050 MPRP/23301 EPA 6010 92241963002 201507766 EPA 3050 MPRP/23302 EPA 6020 92241963003 201507767 EPA 3050 MPRP/23302 EPA 6020 92241963004 201507768 EPA 3050 MPRP/23302 EPA 6020 92241963005 201507769 EPA 3050 MPRP/23302 EPA 6020 92241963002 201507766 EPA 7471 MERP/5523 EPA 7471 92241963003 201507767 EPA 7471 MERP/5523 EPA 7471 92241963004 201507768 EPA 7471 MERP/5523 EPA 7471 92241963005 201507769 EPA 7471 MERP/5523 EPA 7471 92241963002 201507766 ASTM D2974-87 PMST/3396 92241963003 201507767 ASTM D2974-87 PMST/3396 92241963004 201507768 ASTM D2974-87 PMST/3396 92241963005 201507769 ASTM D2974-87 PMST/3396 92241963002 201507766 EPA 9045 WET/36412 92241963003 201507767 EPA 9045 WET/36412 92241963004 201507768 EPA 9045 WET/36412 92241963005 201507769 EPA 9045 WET/36412 92241963002 201507766 EPA 9056 WETA/44808 92241963003 201507767 EPA 9056 WETA/44808 92241963004 201507768 EPA 9056 WETA/44808 92241963005 201507769 EPA 9056 WETA/44808 92241963002 201507766 EPA 9056 WETA/44807 92241963003 201507767 EPA 9056 WETA/44807 92241963004 201507768 EPA 9056 WETA/44807 92241963005 201507769 EPA 9056 WETA/44807 92241963002 201507766 EPA 9060 WETA/27740 92241963002 201507766 EPA 9060 WETA/27741 92241963003 201507767 EPA 9060 WETA/27740 92241963003 201507767 EPA 9060 WETA/27741 92241963004 201507768 EPA 9060 WETA/27740 92241963004 201507768 EPA 9060 WETA/27741 92241963005 201507769 EPA 9060 WETA/27740 92241963005 201507769 EPA 9060 WETA/27741 Date: 04/27/2015 04:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/14253 ICP/14253 ICP/14253 ICP/14253 ICPM/9494 ICPM/9494 ICPM/9494 ICPM/9494 MERC/5515 MERC/5515 MERC/5515 MERC/5515 Page 38 of 40 Document Name: Document Revised: September 22. 'Z014 �1 C eAnalyticol° Sample Condition Upon Receipt SCUR Pae 1 of 2 Document Number: Issuing Authigno:47 of 49 F-CHR-CS-003-rev.16 Pace Huntersville Quality Office Client Name: 00 Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑ Commercial❑ P� Other v. f Custody Seal on Cooler/Box Present: Elyy s— El Seals intact: ❑ yes ❑ no Packing Material: ❑ Bubble V❑p ❑_" Bubble Bags ❑ None ❑ Other Thermometer Used: IR Gun 144 Type of Ice: et Blue None Samples on Ice, cooling process has begun 7pmn CnrrPrtinn Farfnr T1 01 No Correction Corrected Cooler Temp.: ° °C Temp should be above freezing to &°C Chain of Custody Present: Biological Tissue is Frozen: Yes No �11 Comments: • esu❑NIA 1. Date and Initials of r�.on exa I ng contents: Chain of Custody Filled Out: 136, No ❑NIA 2. Dyes ❑N` o Chain of Custody Relinquished: Yes ❑ ❑NIA 3. 14. Sampler Name & Signature on COC: QY s No ❑NrA 4. Dyes ❑No1A Samples Arrived within Hold Time: es ONO NIA 6. Short Hold Time Analysis (<72hr): Dyes 114 N1A 6. Rush Turn Around Time Requested: Dyes 1A,' O—Wff 7. Sufficient Volume: Dyes ❑N1A 8. Correct Containers Used: -Pace Containers Used: es ❑Yes ❑NNW Wk o ❑NIA 9. Containers Intact: Dyes ❑No ❑NIA 0. Filtered volume received for Dissolved tests Dyes ❑No. N]A 11. Sample Labels match COC: -Includes date/time/ID/Analysis Matrix: ❑Yes D o ❑NIA v� 12, t 7 )° ^ All containers needing preservation have been checked. Dyes ONO ❑ IA 1.3. All containers needing preservation are found to be in ❑Yes ONO ❑N/A compliance with EPA recommendation. ' exceptions: VOA, coliform, TOC, O&G, WI -DRO (water) Dyes ❑N` o Samples checked for dechlorination: Dyes ONO ❑ IA 14. Headspace in VOA Vials ( >6mm): ❑Yes ONO ❑Nr �.5. Trip Blank Present: Dyes ❑No1A 16. Trip Blank Custody Seals Present Dyes ONO NIA Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Person Contacted: Comments/ Resolution: DatelTime: SCURF Review: W I Date: SRF Review: Date: 7pt� Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( Le out of hold, incorrect preservative, out of temp, incorrect containers) Field Data Required? -WO#:92241963 11111111111111 1 11111111 92241963 Y 1 N Page 39 of 40 I .._ ._. r...._ ._. _., ......._. _....---.�_......_��_..�.,_ .tom..._.._..: cuslomar W coniplcls approplialo columns to itght Customer muss campi[to mm Page mm N 'e . �i it 0 m c $ o - 3 W c n 0 O no S m 0 s C p_ [ 2 n o IDN 0 CL o w Y 6 N O n CL O Q N v ► u n o r R pp0 p Q { 4g I mm Page CHAIN OF CUSTODY RECORD ACED ANALYSIS REQUEST FORM _ --------------- -----_ Analytical I_abDratory Services i i Ana 1 L.itborplto, 1J9+ fJrl1 l DUKEI Worts Ordar I� Ps r y OF 1 Ry[RO1God;Wi[3>au I.rauudi"7an31 i i mom.- SOIL �— � p1.�7'F;IBUTIOIhb 1539' Hupere� ferry RJ I i TQ _9dngkdngrruKr 1 CIRIC,IP+I.d'aC to I.R41. Lb lU Hunlermwilla, It C. ztil & I it oy w BY 17e6ri IIrwr i COPY td> CLIENT - 49041 075 52-05ly fax- 95.4149 I I _ SAMPLE PROU•RAM GfWJrrd Watrf_ t�rL'QEj1 61} 83 A8 GW jap'.r}nn ID, lall Ca m Olwro i..g Hry: @IA dlvlly-N}; IOJF'nirraM r[r Whim ddpe idlc accw ting has boikin eviAbliah ad ♦rind is mil MtllesMd ■bone r roved tllr rmllarrMrp: 1I I ll"' cufreel soconul Ung. Ila alll 5 accourNAng dlwddN ■hove, of Pmvia. [ orrael acs alanCl Ifar CF 11 Unfit mo Promm 11), I LAS USE GNt e R M01FIN i a SWI i tl- [ A I.J776 ur 4Z!- PACE Code Tam C - - PC)/'y �] jI J �f`y (j �1 - I 142081 rdPf rare :4=1i 2=W 9=H t-..- - - .4 .- darty rrs a an W191a all Pro -so rvative4 when used miist Rae ;nyiilf d) wilhin 16 rninubus of sample cu llect-lon "CollecUon rnFornnation r�Lrb 4O -" n n "Sample Description or 10 QIyt6 �ImE !r_r�€. F 1 F - 9 i _ 1 i _ 9 I j 1 _ 1 1 '. WATER EQUIPMENT BLANK 1 PER DAY1. xilariiqr.iadrer or - ur;,. nb.r Aterpiitl B,r_ RWndIulrPltl B!' - BWIrf7lrria ,ssr�pred Syr: Irnalnqulikrd OrraLnnw - Ac[rp� f f 5e�ahtdirLeGb P. o k GpAid lay lSiNrfRtrr+R f f - arrf`rlrrkl Metals: Al, Sh, As, Ba, Be, Br Cd, Ca, Cr, Co, CII, Fe, Pb, Mgr Mn, Wldi, Ni, K, Se,. NR, Sr, TI, V. Anldarw Cl. Nirtrate . 904 Sediment Soeciflc Parameters: hSolidis. C€f;. Pc+r-ticle fixe r 2'Requl=sleOT u raardallnd 14 tltW s •7 Uay3 _ • 4Q W ur 4Z!- o l O ccmCA `'�0C'L a CL 4 s' a � F— + s*I lSiNrfRtrr+R f f - arrf`rlrrkl Metals: Al, Sh, As, Ba, Be, Br Cd, Ca, Cr, Co, CII, Fe, Pb, Mgr Mn, Wldi, Ni, K, Se,. NR, Sr, TI, V. Anldarw Cl. Nirtrate . 904 Sediment Soeciflc Parameters: hSolidis. C€f;. Pc+r-ticle fixe r 2'Requl=sleOT u raardallnd 14 tltW s •7 Uay3 _ • 4Q W