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HomeMy WebLinkAboutNC0000396_J15020201 Report_20150823DUE Analytical Laboratory Page 1 of 102 ' ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report J15020201 AB GW ASSESSMENT SOIL Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker 200 CP and L Drive Arden,NC 28704 Margaret Galvin -Karr Phone: 980-875-5219 R marge.-karr@duke- 'Y, energy.com Date: 2015.03.24 13:45:30 -04'00' Margaret Galvin -Karr Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 3/23/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015003284 ASHEVILLE 29 -Jan -15 11:00 AM MW 13SB (1.5-2) 2015003285 ASHEVILLE 29 -Jan -15 11:05 AM MW 13SB (14.5-15) 2015003286 ASHEVILLE 29 -Jan -15 11:10 AM MW 13SB (22-22.5) 2015003287 ASHEVILLE 29 -Jan -15 11:15 AM MW 13SB (37-37.5) 2015003288 ASHEVILLE 03 -Feb -15 10:00 AM MW 14SB (1.5-2) 2015003289 ASHEVILLE 03 -Feb -15 11:30 AM MW 14SB (23-24) 2015003290 ASHEVILLE 04 -Feb -15 11:50 AM MW 11 SB (1.5-2) 2015003291 ASHEVILLE 04 -Feb -15 12:00 PM MW 11 S13 (9.5-10) 2015003292 ASHEVILLE 04 -Feb -15 12:05 PM MW 11 SB (13.5-14) 2015003293 ASHEVILLE 04 -Feb -15 12:40 PM MW 11 SB (26.5-27) 10 Total Samples Page 2 of 102 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: LU Job Summary Report ❑ Sample Identification P/1 Technical Validation of Data Package J❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Page 3 of 102 LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries d❑ Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 3/23/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020201 Site: MW 13SB (1.5-2) Collection Date: 29 -Jan -15 11:00 AM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 4 of 102 Sample #: 2015003284 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020201 Site: MW 13SB (14.5-15) Collection Date: 29 -Jan -15 11:05 AM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 5 of 102 Sample #: 2015003285 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020201 Site: MW 13SB (22-22.5) Collection Date: 29 -Jan -15 11:10 AM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 6 of 102 Sample #: 2015003286 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020201 Site: MW 13SB (37-37.5) Collection Date: 29 -Jan -15 11:15 AM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 7 of 102 Sample #: 2015003287 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020201 Site: MW 14SB (1.5-2) Collection Date: 03 -Feb -15 10:00 AM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 8 of 102 Sample #: 2015003288 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020201 Site: MW 14SB (23-24) Collection Date: 03 -Feb -15 11:30 AM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 9 of 102 Sample #: 2015003289 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020201 Site: MW 11 SB (1.5-2) Collection Date: 04 -Feb -15 11:50 AM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 10 of 102 Sample #: 2015003290 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020201 Site: MW 11 SB (9.5-10) Collection Date: 04 -Feb -15 12:00 PM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 11 of 102 Sample #: 2015003291 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020201 Site: MW 11 SB (13.5-14) Collection Date: 04 -Feb -15 12:05 PM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 12 of 102 Sample #: 2015003292 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020201 Site: MW 11 SB (26.5-27) Collection Date: 04 -Feb -15 12:40 PM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 13 of 102 Sample #: 2015003293 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE aceAnaiXical www.pacelabs.com March 18, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: J15020201 Pace Project No.: 92236923 Pace Analytical Services, Inc. PggoiwrwY(i�e. Suite 100 Huntersville, INC 28078 (704)875-9092 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on February 09, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy HiQ p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� ��� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 88 lacmnalyfica( www.pacelabs.com Project: J15020201 Pace Project No.: 92236923 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21 -A Certification #: 2926.01 Alaska Certification #: UST -078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ -0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH -0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. 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Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN -002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE -OS -28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 88 aceAnaiXical www.pacelabs.com Project: J15020201 Pace Project No.: 92236923 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. Pgg011 wey(i�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 88 aceAnaiXical www.pacelabs.com SAMPLE SUMMARY Project: J15020201 Pace Project No.: 92236923 Lab ID Sample ID Matrix Date Collected Date Received 92236923001 2015003284 Solid 01/29/1511:00 02/09/1514:47 92236923002 2015003285 Solid 01/29/1511:05 02/09/1514:47 92236923003 2015003286 Solid 01/29/1511:10 02/09/1514:47 92236923004 2015003287 Solid 01/29/1511:15 02/09/1514:47 92236923005 2015003288 Solid 02/03/1510:00 02/09/1514:47 92236923006 2015003289 Solid 02/03/1511:30 02/09/1514:47 92236923007 2015003291 Solid 02/04/1512:00 02/09/1514:47 92236923008 2015003293 Solid 02/04/1512:40 02/09/1514:47 92236923009 2015003290 Solid 02/04/1511:50 02/09/1514:47 92236923010 2015003292 Solid 02/04/1512:05 02/09/1514:47 92236923011 2015003289 SPLP METALS Water 02/03/15 11:30 02/09/15 14:47 92236923012 2015003291 SPLP METALS Water 02/04/15 12:00 02/09/15 14:47 92236923013 2015003293 SPLP METALS Water 02/04/15 12:40 02/09/15 14:47 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. Pggoi wey(i�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Page 4 of 88 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. Pggoi�ir�y�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15020201 92236923 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92236923001 2015003284 EPA 6010 CKJ, TAP 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 SKW 1 PASI-G EPA 9045 MLS 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92236923002 2015003285 EPA 6010 TAP 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 SKW 1 PASI-G EPA 9045 MLS 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92236923003 2015003286 EPA 6010 TAP 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 SKW 1 PASI-G EPA 9045 MLS 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92236923004 2015003287 EPA 6010 TAP 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AH 1 PASI-G EPA 9045 MLS 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92236923005 2015003288 EPA 6010 TAP 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 SKW 1 PASI-G EPA 9045 MLS 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 88 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. P36g01qrwY(i�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15020201 92236923 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92236923006 2015003289 EPA 6010 TAP 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 SKW 1 PASI-G EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92236923007 2015003291 EPA 6010 TAP 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 SKW 1 PASI-G EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92236923008 2015003293 EPA 6010 TAP 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 SKW 1 PASI-G EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92236923009 2015003290 EPA 6010 TAP 15 PASI-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 88 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Project: J15020201 Pace Project No.: 92236923 Pace Analytical Services, Inc. P360816fyd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 SKW 1 PASI-G EPA 9045 MLS 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92236923010 2015003292 EPA 6010 TAP 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 SKW 1 PASI-G EPA 9045 MLS 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92236923011 2015003289 SPLP METALS EPA 6020A RJS 24 PASI-M EPA 7470 DM 1 PASI-M 92236923012 2015003291 SPLP METALS EPA 6020A TT3 24 PASI-M EPA 7470 DM 1 PASI-M 92236923013 2015003293 SPLP METALS EPA 6020A RJS 24 PASI-M EPA 7470 DM 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 88 aceAnaiXical www.pacelabs.com SUMMARY OF DETECTION Pace Analytical Services, Inc. Pggc0 Sirpyo"�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15020201 92236923 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92236923001 2015003284 EPA 6010 Aluminum 12700 mg/kg 5.0 02/14/15 22:56 M6 EPA 6010 Barium 36.3 mg/kg 0.50 02/14/15 22:56 M1 EPA 6010 Boron 36.4 mg/kg 25.1 02/15/15 18:57 D3 EPA 6010 Calcium 664 mg/kg 25.1 02/14/15 22:56 M1 EPA 6010 Chromium 41.7 mg/kg 2.5 02/15/1518:57 D3,M6 EPA 6010 Copper 21.4 mg/kg 2.5 02/15/1518:57 D3,M6 EPA 6010 Iron 36200 mg/kg 20.0 02/15/1518:57 D3,M6 EPA 6010 Magnesium 622 mg/kg 25.1 02/14/15 22:56 M1 EPA 6010 Manganese 215 mg/kg 2.5 02/15/1518:57 D3,M6,R1 EPA 6010 Nickel 3.3 mg/kg 0.25 02/14/15 22:56 EPA 6010 Potassium 372 mg/kg 50.1 02/14/15 22:56 EPA 6010 Strontium 1.8 mg/kg 0.50 02/14/15 22:56 EPA 6010 Zinc 10.7 mg/kg 1.0 02/14/15 22:56 EPA 6020 Beryllium 0.40 mg/kg 0.12 02/16/15 15:31 D3 EPA 6020 Cobalt 11.0 mg/kg 2.5 02/17/15 12:10 D3 EPA 6020 Lead 12.7 mg/kg 1.0 02/16/15 15:31 D3 EPA 6020 Vanadium 45.0 mg/kg 2.5 02/17/15 12:10 D4 EPA 7471 Mercury 0.041 mg/kg 0.0078 02/16/15 17:13 ASTM D2974-87 Percent Moisture 13.5 % 0.10 03/09/15 08:41 EPA 9045 pH at 25 Degrees C 6.9 Std. Units 0.10 02/11/15 11:00 D6 EPA 9060 Total Organic Carbon 4560 mg/kg 1140 02/18/15 07:58 EPA 9060 Total Organic Carbon 4560 mg/kg 1160 02/18/15 08:05 EPA 9060 Total Organic Carbon 4580 mg/kg 1150 02/18/15 08:11 EPA 9060 Total Organic Carbon 4170 mg/kg 1140 02/18/15 08:18 EPA 9060 Mean Total Organic Carbon 4470 mg/kg 1150 02/18/15 07:58 EPA 9060 RSD% 4.5 % 02/18/15 07:58 92236923002 2015003285 EPA 6010 Aluminum 32700 mg/kg 50.6 02/15/15 19:10 D3 EPA 6010 Barium 172 mg/kg 5.1 02/15/15 19:10 D3 EPA 6010 Boron 36.2 mg/kg 25.3 02/15/15 19:10 D3 EPA 6010 Calcium 271 mg/kg 253 02/15/15 19:10 D3 EPA 6010 Chromium 34.2 mg/kg 2.5 02/15/15 19:10 D3 EPA 6010 Copper 11.6 mg/kg 2.5 02/15/15 19:10 D3 EPA 6010 Iron 39200 mg/kg 20.3 02/15/15 19:10 D3 EPA 6010 Magnesium 4890 mg/kg 253 02/15/15 19:10 D3 EPA 6010 Manganese 226 mg/kg 2.5 02/15/15 19:10 D3 EPA 6010 Nickel 15.5 mg/kg 2.5 02/15/15 19:10 D3 EPA 6010 Potassium 4490 mg/kg 506 02/15/15 19:10 D3 EPA 6010 Zinc 116 mg/kg 10.1 02/15/15 19:10 D3 EPA 6020 Beryllium 0.89 mg/kg 0.30 02/17/1512:28 D3,M6 EPA 6020 Cobalt 9.4 mg/kg 2.5 02/17/15 12:28 D3 EPA 6020 Lead 12.2 mg/kg 1.0 02/16/1515:44 D3,M6 EPA 6020 Selenium 2AJ mg/kg 2.5 02/17/1512:28 D3,M6 EPA 6020 Vanadium 48.7 mg/kg 2.5 02/17/1512:28 D4,M6 EPA 7471 Mercury 0.016 mg/kg 0.0079 02/16/15 17:16 ASTM D2974-87 Percent Moisture 21.0 % 0.10 03/09/15 08:41 EPA 9045 pH at 25 Degrees C 6.3 Std. Units 0.10 02/11/15 11:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 88 aceAnaiXical www.pacelabs.com Project: J15020201 Pace Project No.: 92236923 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. P360916fyd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92236923002 2015003285 EPA 9060 RSD% 2.9 % 02/18/15 09:14 92236923003 2015003286 EPA 6010 Aluminum 26100 mg/kg 51.0 02/15/15 19:19 D3 EPA 6010 Barium 209 mg/kg 5.1 02/15/15 19:19 D3 EPA 6010 Boron 27.3 mg/kg 25.5 02/15/15 19:19 D3 EPA 6010 Chromium 24.6 mg/kg 2.6 02/15/15 19:19 D3 EPA 6010 Copper 1.91 mg/kg 2.6 02/15/15 19:19 D3 EPA 6010 Iron 28900 mg/kg 20.4 02/15/15 19:19 D3 EPA 6010 Magnesium 7520 mg/kg 255 02/15/15 19:19 D3 EPA 6010 Manganese 336 mg/kg 2.6 02/15/15 19:19 D3 EPA 6010 Nickel 21.1 mg/kg 2.6 02/15/15 19:19 D3 EPA 6010 Potassium 7650 mg/kg 510 02/15/15 19:19 D3 EPA 6010 Strontium 3.2J mg/kg 5.1 02/15/15 19:19 D3 EPA 6010 Zinc 192 mg/kg 10.2 02/15/15 19:19 D3 EPA 6020 Arsenic 1.51 mg/kg 2.6 02/17/15 12:32 D3 EPA 6020 Beryllium 1.8 mg/kg 0.12 02/16/15 16:05 D3 EPA 6020 Cobalt 16.1 mg/kg 2.6 02/17/15 12:32 D3 EPA 6020 Lead 11.9 mg/kg 1.0 02/16/15 16:05 D3 EPA 6020 Selenium 4.3 mg/kg 2.6 02/17/15 12:32 D3 EPA 6020 Thallium 0.52J mg/kg 1.0 02/16/15 16:05 D3 EPA 6020 Vanadium 39.3 mg/kg 2.6 02/17/15 12:32 D4 EPA 7471 Mercury 0.00501 mg/kg 0.0078 02/16/15 17:18 ASTM D2974-87 Percent Moisture 16.2 % 0.10 03/09/15 08:41 EPA 9045 pH at 25 Degrees C 5.5 Std. Units 0.10 02/11/15 11:00 EPA 9060 RSD% 8.8 % 02/18/15 09:38 92236923004 2015003287 EPA 6010 Aluminum 18800 mg/kg 48.0 02/15/15 19:23 D3 EPA 6010 Barium 158 mg/kg 4.8 02/15/15 19:23 D3 EPA 6010 Boron 18.3J mg/kg 24.0 02/15/15 19:23 D3 EPA 6010 Calcium 186J mg/kg 240 02/15/15 19:23 D3 EPA 6010 Chromium 14.9 mg/kg 2.4 02/15/15 19:23 D3 EPA 6010 Copper 4.4 mg/kg 2.4 02/15/15 19:23 D3 EPA 6010 Iron 18700 mg/kg 19.2 02/15/15 19:23 D3 EPA 6010 Magnesium 6040 mg/kg 240 02/15/15 19:23 D3 EPA 6010 Manganese 284 mg/kg 2.4 02/15/15 19:23 D3 EPA 6010 Nickel 15.4 mg/kg 2.4 02/15/15 19:23 D3 EPA 6010 Potassium 7100 mg/kg 480 02/15/15 19:23 D3 EPA 6010 Strontium 5.8 mg/kg 4.8 02/15/15 19:23 D3 EPA 6010 Zinc 85.8 mg/kg 9.6 02/15/15 19:23 D3 EPA 6020 Beryllium 1.7 mg/kg 0.12 02/16/15 16:08 D3 EPA 6020 Cobalt 6.1 mg/kg 2.4 02/17/15 12:35 D3 EPA 6020 Lead 4.3 mg/kg 0.96 02/16/15 16:08 D3 EPA 6020 Selenium 1.8J mg/kg 2.4 02/17/15 12:35 D3 EPA 6020 Vanadium 15.9 mg/kg 2.4 02/17/15 12:35 D3 ASTM D2974-87 Percent Moisture 19.2 % 0.10 03/09/15 08:55 EPA 9045 pH at 25 Degrees C 5.5 Std. Units 0.10 02/11/15 11:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 88 aceAnaiXical www.pacelabs.com Project: J15020201 Pace Project No.: 92236923 Lab Sample ID Method Client Sample ID Parameters 92236923004 2015003287 EPA 9060 RSD% 92236923005 2015003288 EPA 6010 Aluminum EPA 6010 Barium EPA 6010 Boron EPA 6010 Calcium EPA 6010 Chromium EPA 6010 Copper EPA 6010 Iron EPA 6010 Magnesium EPA 6010 Manganese EPA 6010 Nickel EPA 6010 Potassium EPA 6010 Zinc EPA 6020 Arsenic EPA 6020 Beryllium EPA 6020 Cobalt EPA 6020 Lead EPA 6020 Selenium EPA 6020 Vanadium EPA 7471 Mercury ASTM D2974-87 Percent Moisture EPA 9045 pH at 25 Degrees C EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Mean Total Organic Carbon EPA 9060 RSD% 92236923006 2015003289 EPA 6010 Aluminum EPA 6010 Barium EPA 6010 Boron EPA 6010 Calcium EPA 6010 Chromium EPA 6010 Copper EPA 6010 Iron EPA 6010 Magnesium EPA 6010 Manganese EPA 6010 Nickel EPA 6010 Potassium EPA 6010 Strontium EPA 6010 Zinc EPA 6020 Beryllium EPA 6020 Cobalt EPA 6020 Lead Pace Analytical Services, Inc. P360srwyd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 8.9 % 02/18/1510:03 21000 mg/kg 50.3 02/15/1519:40 D3 113 mg/kg 5.0 02/15/1519:40 D3 31.1 mg/kg 25.1 02/15/1519:40 D3 167J mg/kg 251 02/15/1519:40 D3 36.1 mg/kg 2.5 02/15/1519:40 D3 66.2 mg/kg 2.5 02/15/1519:40 D3 32200 mg/kg 20.1 02/15/1519:40 D3 4840 mg/kg 251 02/15/1519:40 D3 616 mg/kg 2.5 02/15/1519:40 D3 16.4 mg/kg 2.5 02/15/1519:40 D3 3790 mg/kg 503 02/15/1519:40 D3 85.6 mg/kg 10.1 02/15/1519:40 D3 2.2J mg/kg 2.5 02/17/1512:38 D3 0.72 mg/kg 0.12 02/16/1516:11 D3 31.8 mg/kg 2.5 02/17/1512:38 D4 12.1 mg/kg 1.0 02/16/1516:11 D3 2.9 mg/kg 2.5 02/17/1512:38 D3 41.5 mg/kg 2.5 02/17/1512:38 D4 0.011 mg/kg 0.0081 02/16/1517:22 25.7 % 0.10 03/09/15 08:41 6.4 Std. Units 0.10 02/11/15 11:00 1350 mg/kg 805 02/18/1510:25 1360 mg/kg 813 02/18/1510:31 1900 mg/kg 805 02/18/1510:37 1720 mg/kg 808 02/18/1510:43 1580 mg/kg 808 02/18/1510:25 17.0 % 02/18/1510:25 16300 mg/kg 48.7 02/15/1519:45 D3 238 mg/kg 4.9 02/15/1519:45 D3 28.4 mg/kg 24.4 02/15/1519:45 D3 2750 mg/kg 244 02/15/1519:45 D3 25.2 mg/kg 2.4 02/15/1519:45 D3 41.2 mg/kg 2.4 02/15/1519:45 D3 29400 mg/kg 19.5 02/15/1519:45 D3 10400 mg/kg 244 02/15/1519:45 D3 492 mg/kg 2.4 02/15/1519:45 D3 25.3 mg/kg 2.4 02/15/1519:45 D3 12700 mg/kg 487 02/15/1519:45 D3 8.6 mg/kg 4.9 02/15/1519:45 D3 111 mg/kg 9.7 02/15/1519:45 D3 0.63 mg/kg 0.12 02/16/1516:15 D3 13.0 mg/kg 2.4 02/17/1512:42 D3 3.0 mg/kg 0.97 02/16/1516:15 D3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 88 aceAnaiXical www.pacelabs.com Project: J15020201 Pace Project No.: 92236923 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. P 3 RGAIir6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92236923006 2015003289 EPA 6020 Selenium 1.3J mg/kg 2.4 02/17/15 12:42 D3 EPA 6020 Thallium 0.83J mg/kg 0.97 02/16/15 16:15 D3 EPA 6020 Vanadium 27.7 mg/kg 2.4 02/17/15 12:42 D4 ASTM D2974-87 Percent Moisture 19.3 % 0.10 03/09/15 08:41 EPA 9045 pH at 25 Degrees C 8.0 Std. Units 0.10 02/11/15 11:00 EPA 300.0 Sulfate 2AJ mg/L 2.5 02/25/15 18:22 SM 4500 -CI -E Chloride 5.91 mg/L 6.2 02/21/15 02:02 EPA 9060 RSD% 2.2 % 02/18/15 10:49 92236923007 2015003291 EPA 6010 Aluminum 18600 mg/kg 49.0 02/15/15 19:49 D3 EPA 6010 Barium 86.7 mg/kg 4.9 02/15/15 19:49 D3 EPA 6010 Boron 14.1J mg/kg 24.5 02/15/1519:49 D3 EPA 6010 Calcium 145J mg/kg 245 02/15/15 19:49 D3 EPA 6010 Chromium 19.5 mg/kg 2.5 02/15/15 19:49 D3 EPA 6010 Copper 10.3 mg/kg 2.5 02/15/15 19:49 D3 EPA 6010 Iron 14000 mg/kg 19.6 02/15/15 19:49 D3 EPA 6010 Magnesium 4260 mg/kg 245 02/15/15 19:49 D3 EPA 6010 Manganese 120 mg/kg 2.5 02/15/15 19:49 D3 EPA 6010 Nickel 8.8 mg/kg 2.5 02/15/15 19:49 D3 EPA 6010 Potassium 2840 mg/kg 490 02/15/15 19:49 D3 EPA 6010 Zinc 50.0 mg/kg 9.8 02/15/15 19:49 D3 EPA 6020 Beryllium 0.60 mg/kg 0.12 02/16/15 16:18 D3 EPA 6020 Cobalt 5.5 mg/kg 2.5 02/17/15 12:45 D3 EPA 6020 Lead 8.6 mg/kg 0.98 02/16/15 16:18 D3 EPA 6020 Selenium 1.3J mg/kg 2.5 02/17/15 12:45 D3 EPA 6020 Vanadium 36.0 mg/kg 2.5 02/17/15 12:45 D4 EPA 7471 Mercury 0.018 mg/kg 0.0082 02/16/15 17:26 ASTM D2974-87 Percent Moisture 23.6 % 0.10 03/09/15 08:41 EPA 9045 pH at 25 Degrees C 5.3 Std. Units 0.10 02/11/15 11:00 EPA 300.0 Sulfate 4.5 mg/L 2.6 02/27/15 12:57 EPA 9060 Total Organic Carbon 1560 mg/kg 783 02/18/15 11:22 EPA 9060 Total Organic Carbon 1480 mg/kg 780 02/18/15 11:27 EPA 9060 Total Organic Carbon 1550 mg/kg 789 02/18/15 11:33 EPA 9060 Total Organic Carbon 1480 mg/kg 785 02/18/15 11:38 EPA 9060 Mean Total Organic Carbon 1520 mg/kg 784 02/18/15 11:22 EPA 9060 RSD% 3.0 % 02/18/15 11:22 92236923008 2015003293 EPA 6010 Aluminum 16800 mg/kg 51.8 02/15/15 19:53 D3 EPA 6010 Barium 209 mg/kg 5.2 02/15/15 19:53 D3 EPA 6010 Boron 23.6J mg/kg 25.9 02/15/15 19:53 D3 EPA 6010 Calcium 418 mg/kg 259 02/15/15 19:53 D3 EPA 6010 Chromium 21.4 mg/kg 2.6 02/15/15 19:53 D3 EPA 6010 Copper 1.51 mg/kg 2.6 02/15/15 19:53 D3 EPA 6010 Iron 24300 mg/kg 20.7 02/15/15 19:53 D3 EPA 6010 Magnesium 7310 mg/kg 259 02/15/15 19:53 D3 EPA 6010 Manganese 247 mg/kg 2.6 02/15/15 19:53 D3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 11 of 88 aceAnaiXical www.pacelabs.com Project: J15020201 Pace Project No.: 92236923 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. P 3 RGA r6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92236923008 2015003293 EPA 6010 Nickel 13.7 mg/kg 2.6 02/15/15 19:53 EPA 6010 Potassium 8930 mg/kg 518 02/15/15 19:53 EPA 6010 Strontium 12.2 mg/kg 5.2 02/15/15 19:53 EPA 6010 Zinc 76.1 mg/kg 10.4 02/15/15 19:53 EPA 6020 Beryllium 0.68 mg/kg 0.12 02/16/15 16:21 EPA 6020 Cobalt 10.6 mg/kg 2.6 02/17/15 12:48 EPA 6020 Lead 4.5 mg/kg 1.0 02/16/15 16:21 EPA 6020 Thallium 0.551 mg/kg 1.0 02/16/15 16:21 EPA 6020 Vanadium 31.5 mg/kg 2.6 02/17/15 12:48 ASTM D2974-87 Percent Moisture 17.4 % 0.10 03/09/15 08:41 EPA 9045 pH at 25 Degrees C 6.1 Std. Units 0.10 02/12/15 13:15 EPA 300.0 Sulfate 2.9 mg/L 2.4 02/25/15 18:36 SM 4500 -CI -E Chloride 3.1J mg/L 6.1 02/21/15 02:03 EPA 9060 RSD% 8.7 % 02/18/15 17:59 92236923009 2015003290 EPA 6010 Aluminum 18100 mg/kg 51.5 02/15/15 19:58 EPA 6010 Barium 112 mg/kg 5.2 02/15/15 19:58 EPA 6010 Boron 20AJ mg/kg 25.8 02/15/15 19:58 EPA 6010 Calcium 975 mg/kg 258 02/15/15 19:58 EPA 6010 Chromium 18.5 mg/kg 2.6 02/15/15 19:58 EPA 6010 Copper 5.9 mg/kg 2.6 02/15/15 19:58 EPA 6010 Iron 20900 mg/kg 20.6 02/15/15 19:58 EPA 6010 Magnesium 5470 mg/kg 258 02/15/15 19:58 EPA 6010 Manganese 190 mg/kg 2.6 02/15/15 19:58 EPA 6010 Nickel 13.6 mg/kg 2.6 02/15/15 19:58 EPA 6010 Potassium 4470 mg/kg 515 02/15/15 19:58 EPA 6010 Strontium 3.6J mg/kg 5.2 02/15/15 19:58 EPA 6010 Zinc 62.4 mg/kg 10.3 02/15/15 19:58 EPA 6020 Arsenic 1 AJ mg/kg 2.6 02/17/15 12:52 EPA 6020 Beryllium 0.51 mg/kg 0.12 02/16/15 16:25 EPA 6020 Cobalt 10.1 mg/kg 2.6 02/17/15 12:52 EPA 6020 Lead 7.3 mg/kg 1.0 02/16/15 16:25 EPA 6020 Selenium 1.6J mg/kg 2.6 02/17/15 12:52 EPA 6020 Vanadium 26.0 mg/kg 2.6 02/17/15 12:52 EPA 7471 Mercury 0.018 mg/kg 0.0081 02/16/15 17:31 ASTM D2974-87 Percent Moisture 10.9 % 0.10 03/09/15 08:41 EPA 9045 pH at 25 Degrees C 7.2 Std. Units 0.10 02/12/15 13:15 EPA 9060 Total Organic Carbon 1970 mg/kg 671 02/18/15 12:19 EPA 9060 Total Organic Carbon 1900 mg/kg 673 02/18/15 12:25 EPA 9060 Total Organic Carbon 2120 mg/kg 673 02/18/15 12:31 EPA 9060 Total Organic Carbon 2150 mg/kg 676 02/18/15 12:36 EPA 9060 Mean Total Organic Carbon 2030 mg/kg 673 02/18/15 12:19 EPA 9060 RSD% 5.9 % 02/18/15 12:19 92236923010 2015003292 D3 D3 D3 D3 D3 D3 D3 D3 D4 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D4 EPA 6010 Aluminum 18700 mg/kg 50.8 02/15/15 20:02 D3 EPA 6010 Barium 185 mg/kg 5.1 02/15/15 20:02 D3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 12 of 88 aceAnaiXical www.pacelabs.com Project: J15020201 Pace Project No.: 92236923 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. P3Sy RGA r6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92236923010 2015003292 EPA 6010 Boron 21.8J mg/kg 25.4 02/15/15 20:02 EPA 6010 Calcium 859 mg/kg 254 02/15/15 20:02 EPA 6010 Chromium 15.7 mg/kg 2.5 02/15/15 20:02 EPA 6010 Copper 1 AJ mg/kg 2.5 02/15/15 20:02 EPA 6010 Iron 23300 mg/kg 20.3 02/15/15 20:02 EPA 6010 Magnesium 9570 mg/kg 254 02/15/15 20:02 EPA 6010 Manganese 285 mg/kg 2.5 02/15/15 20:02 EPA 6010 Nickel 20.5 mg/kg 2.5 02/15/15 20:02 EPA 6010 Potassium 8060 mg/kg 508 02/15/15 20:02 EPA 6010 Strontium 12.3 mg/kg 5.1 02/15/15 20:02 EPA 6010 Zinc 97.4 mg/kg 10.2 02/15/15 20:02 EPA 6020 Beryllium 0.64 mg/kg 0.12 02/16/15 16:28 EPA 6020 Cobalt 13.8 mg/kg 2.5 02/17/15 12:55 EPA 6020 Lead 3.1 mg/kg 1.0 02/16/15 16:28 EPA 6020 Thallium 0.52J mg/kg 1.0 02/16/15 16:28 EPA 6020 Vanadium 23.3 mg/kg 2.5 02/17/15 12:55 ASTM D2974-87 Percent Moisture 18.6 % 0.10 03/09/15 08:42 EPA 9045 pH at 25 Degrees C 6.7 Std. Units 0.10 02/12/15 13:15 EPA 9060 RSD% 4.8 % 02/18/15 12:42 92236923011 2015003289 SPLP METALS EPA 6020A Aluminum 15100 ug/L 10.0 03/13/15 20:09 EPA 6020A Arsenic 2.8 ug/L 0.50 03/13/15 20:09 EPA 6020A Barium 251 ug/L 0.30 03/13/15 20:09 EPA 6020A Beryllium 0.68 ug/L 0.20 03/13/15 20:09 EPA 6020A Boron 7.1 ug/L 5.0 03/13/15 20:09 EPA 6020A Calcium 3100 ug/L 40.0 03/13/15 20:09 EPA 6020A Chromium 17.5 ug/L 0.50 03/13/15 20:09 EPA 6020A Cobalt 10.1 ug/L 0.50 03/13/15 20:09 EPA 6020A Copper 40.8 ug/L 1.0 03/13/15 20:09 EPA 6020A Iron 20500 ug/L 50.0 03/13/15 20:09 EPA 6020A Lead 4.0 ug/L 0.10 03/13/15 20:09 EPA 6020A Magnesium 5750 ug/L 10.0 03/13/15 20:09 EPA 6020A Manganese 646 ug/L 2.5 03/16/15 09:53 EPA 6020A Molybdenum 1.5 ug/L 0.50 03/13/15 20:09 EPA 6020A Nickel 15.1 ug/L 0.50 03/13/15 20:09 EPA 6020A Potassium 8270 ug/L 50.0 03/13/15 20:09 EPA 6020A Selenium 2.8 ug/L 0.50 03/13/15 20:09 EPA 6020A Sodium 4170 ug/L 50.0 03/13/15 20:09 EPA 6020A Strontium 19.8 ug/L 0.50 03/13/15 20:09 EPA 6020A Thallium 0.42 ug/L 0.10 03/13/15 20:09 EPA 6020A Vanadium 24.0 ug/L 1.0 03/13/15 20:09 EPA 6020A Zinc 61.4 ug/L 5.0 03/13/15 20:09 92236923012 2015003291 SPLP METALS EPA 6020A Aluminum 47.6 ug/L 10.0 03/12/15 15:01 EPA 6020A Barium 4.1 ug/L 0.30 03/12/15 15:01 EPA 6020A Boron 20.2 ug/L 5.0 03/12/15 15:01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D4 Qualifiers Page 13 of 88 aceAnaiXical www.pacelabs.com Project: J15020201 Pace Project No.: 92236923 Lab Sample ID Method 92236923012 EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A 92236923013 EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A SUMMARY OF DETECTION Client Sample ID Parameters 2015003291 SPLP METALS Calcium Chromium Lead Magnesium Manganese Potassium Sodium Strontium 2015003293 SPLP METALS Aluminum Barium Boron Calcium Chromium Magnesium Potassium Sodium Result UnitE 0.50 748 ug/L 0.54 ug/L 0.38 ug/L 390 ug/L 7.3 ug/L 127 ug/L 3390 ug/L 2.9 ug/L 17.6 ug/L 0.54 ug/L 47.8 ug/L 158 ug/L 0.51 ug/L 112 ug/L 344 ug/L 3940 ug/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. PWI*rwy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Report Limit Analyzed Qualifiers 40.0 03/12/1515:01 0.50 03/12/1515:01 0.10 03/12/1515:01 10.0 03/12/1515:01 0.50 03/12/1515:01 50.0 03/12/1515:01 50.0 03/12/1515:01 0.50 03/12/1515:01 10.0 03/13/15 20:14 0.30 03/13/15 20:14 5.0 03/13/15 20:14 40.0 03/13/15 20:14 0.50 03/13/15 20:14 10.0 03/13/15 20:14 50.0 03/13/15 20:14 50.0 03/13/15 20:14 Page 14 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P3Sy 90Ar6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Date: March 18, 2015 2015003291 (Lab ID: 92236923007) • Insufficient sample received from client to perform the analysis per EPA requirements. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P3Sy 90Ar6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 18, 2015 General Information: 10 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/22645 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92236923001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1128077) • Calcium • Molybdenum • MSD (Lab ID: 1128078) • Barium • Magnesium • Molybdenum M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1128077) • Aluminum • Chromium • Copper • Iron • Manganese • MSD (Lab ID: 1128078) • Aluminum • Chromium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PWIbrwy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 18, 2015 QC Batch: MPRP/22645 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92236923001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • Iron • Manganese R1: RPD value was outside control limits. • MSD (Lab ID: 1128078) • Manganese Additional Comments: Analyte Comments: QC Batch: MPRP/22645 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003284 (Lab ID: 92236923001) • Boron • Chromium • Copper • Iron • Manganese •2015003285 (Lab ID: 92236923002) • Aluminum • Boron • Barium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015003286 (Lab ID: 92236923003) • Aluminum • Boron • Barium • Calcium • Chromium • Copper • Iron • Potassium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36gmirpy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 18, 2015 Analyte Comments: QC Batch: MPRP/22645 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003286 (Lab ID: 92236923003) • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015003287 (Lab ID: 92236923004) • Aluminum • Boron • Barium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015003288 (Lab ID: 92236923005) • Aluminum • Boron • Barium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015003289 (Lab ID: 92236923006) • Aluminum • Boron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PWI*Wfyd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 18, 2015 Analyte Comments: QC Batch: MPRP/22645 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003289 (Lab ID: 92236923006) • Barium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015003290 (Lab ID: 92236923009) • Aluminum • Boron • Barium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015003291 (Lab ID: 92236923007) • Aluminum • Boron • Barium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PW'Isrwy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 18, 2015 Analyte Comments: QC Batch: MPRP/22645 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003291 (Lab ID: 92236923007) • Nickel • Strontium • Zinc •2015003292 (Lab ID: 92236923010) • Aluminum • Boron • Barium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015003293 (Lab ID: 92236923008) • Aluminum • Boron • Barium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PAROAir6fY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 18, 2015 General Information: 10 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/22646 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92236923002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1128081) • Antimony • Arsenic • Beryllium • Cadmium • Lead • Selenium • Vanadium • MSD (Lab ID: 1128082) • Antimony • Arsenic • Selenium • Vanadium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PW'Arwy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 18, 2015 Additional Comments: Analyte Comments: QC Batch: MPRP/22646 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003284 (Lab ID: 92236923001) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015003285 (Lab ID:92236923002) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015003286 (Lab ID:92236923003) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015003287 (Lab ID:92236923004) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015003288 (Lab ID: 92236923005) • Arsenic • Beryllium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P 3 RGA r6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 18, 2015 Analyte Comments: QC Batch: MPRP/22646 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003288 (Lab ID:92236923005) • Cadmium • Lead • Antimony • Selenium • Thallium •2015003289 (Lab ID:92236923006) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015003290 (Lab ID:92236923009) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015003291 (Lab ID:92236923007) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015003292 (Lab ID:92236923010) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PWI*Wfyd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 18, 2015 Analyte Comments: QC Batch: MPRP/22646 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003293 (Lab ID: 92236923008) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • MS (Lab ID: 1128081) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • MSD (Lab ID: 1128082) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium D4: Sample was diluted due to the presence of high levels of target analytes. •2015003284 (Lab ID: 92236923001) • Vanadium •2015003285 (Lab ID:92236923002) • Vanadium •2015003286 (Lab ID:92236923003) • Vanadium •2015003288 (Lab ID:92236923005) • Cobalt • Vanadium •2015003289 (Lab ID:92236923006) • Vanadium •2015003290 (Lab ID:92236923009) • Vanadium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36RGA r6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 18, 2015 Analyte Comments: QC Batch: MPRP/22646 D4: Sample was diluted due to the presence of high levels of target analytes. •2015003291 (Lab ID: 92236923007) • Vanadium •2015003292 (Lab ID: 92236923010) • Vanadium •2015003293 (Lab ID: 92236923008) • Vanadium • MS (Lab ID: 1128081) • Vanadium • MSD (Lab ID: 1128082) • Vanadium N2: The lab does not hold TNI accreditation for this parameter. •2015003284 (Lab ID:92236923001) • Antimony •2015003285 (Lab ID:92236923002) • Antimony •2015003286 (Lab ID:92236923003) • Antimony •2015003287 (Lab ID:92236923004) • Antimony •2015003288 (Lab ID:92236923005) • Antimony •2015003289 (Lab ID:92236923006) • Antimony •2015003290 (Lab ID:92236923009) • Antimony •2015003291 (Lab ID:92236923007) • Antimony •2015003292 (Lab ID:92236923010) • Antimony •2015003293 (Lab ID:92236923008) • Antimony • BLANK (Lab ID: 1128079) • Antimony • LCS (Lab ID: 1128080) • Antimony • MS (Lab ID: 1128081) • Antimony • MSD (Lab ID: 1128082) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PW'Arwy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: March 18, 2015 General Information: 3 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/52897 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92239540010 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MSD (Lab ID: 1916666) • Aluminum QC Batch: MPRP/52931 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92240320006 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1917522) • Aluminum • Calcium • Sodium • MSD (Lab ID: 1917523) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P 3 9041bir6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 7470 Description: 7470 Mercury Client: Duke Energy Date: March 18, 2015 General Information: 3 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. • 2015003289 SPLP METALS (Lab ID: 92236923011) • 2015003291 SPLP METALS (Lab ID: 92236923012) • 2015003293 SPLP METALS (Lab ID: 92236923013) Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904ff WYOIY e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: March 18, 2015 General Information: 10 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904K WeY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: March 18, 2015 General Information: 10 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/35670 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1388982) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904K WeYde. Suite 100 P36904 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: March 18, 2015 General Information: 3 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P 3 904r6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: March 18, 2015 General Information: 3 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. P4: Sample field preservation does not meet EPA or method recommendations for this analysis. •2015003289 (Lab ID: 92236923006) •2015003293 (Lab ID: 92236923008) Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H1: Analysis conducted outside the EPA method holding time. •2015003291 (Lab ID: 92236923007) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 88 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: SM 4500 -CI -E Description: 4500 Chloride, SPLP Client: Duke Energy Date: March 18, 2015 Pace Analytical Services, Inc. P3690AWIe. Suite 100 y Huntersville, NC 28078 (704)875-9092 General Information: 3 samples were analyzed for SM 4500 -CI -E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 32 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P3690AWIe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: March 18, 2015 General Information: 10 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/43576 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003284 (Lab ID:92236923001) • Chloride • Sulfate •2015003285 (Lab ID:92236923002) • Chloride • Sulfate •2015003286 (Lab ID:92236923003) • Chloride •2015003287 (Lab ID:92236923004) • Chloride • Sulfate •2015003288 (Lab ID:92236923005) • Chloride • Sulfate •2015003289 (Lab ID:92236923006) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 33 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904f WeYde. Suite 100 P3690* Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: March 18, 2015 Analyte Comments: QC Batch: WETA/43576 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003290 (Lab ID: 92236923009) • Chloride • Sulfate •2015003291 (Lab ID: 92236923007) • Chloride • Sulfate •2015003292 (Lab ID: 92236923010) • Chloride • Sulfate •2015003293 (Lab ID: 92236923008) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 34 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P3690AWIe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: March 18, 2015 General Information: 10 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015003284 (Lab ID:92236923001) •2015003285 (Lab ID:92236923002) •2015003286 (Lab ID:92236923003) •2015003287 (Lab ID:92236923004) •2015003288 (Lab ID:92236923005) •2015003289 (Lab ID:92236923006) •2015003290 (Lab ID:92236923009) •2015003291 (Lab ID:92236923007) •2015003292 (Lab ID:92236923010) •2015003293 (Lab ID:92236923008) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 35 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904f WeYde. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020201 Pace Project No.: 92236923 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: March 18, 2015 General Information: 10 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 36 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. P3yy SMr6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 Sample: 2015003284 Lab ID: 92236923001 Collected: 01/29/15 11:00 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 12700 mg/kg 5.0 2.5 1 02/11/15 17:37 02/14/15 22:56 7429-90-5 M6 Barium 36.3 mg/kg 0.50 0.25 1 02/11/15 17:37 02/14/15 22:56 7440-39-3 M1 Boron 36.4 mg/kg 25.1 12.5 10 02/11/1517:37 02/15/1518:57 7440-42-8 D3 Calcium 664 mg/kg 25.1 12.5 1 02/11/15 17:37 02/14/15 22:56 7440-70-2 M1 Chromium 41.7 mg/kg 2.5 1.3 10 02/11/1517:37 02/15/1518:57 7440-47-3 D3,M6 Copper 21.4 mg/kg 2.5 1.3 10 02/11/1517:37 02/15/1518:57 7440-50-8 D3,M6 Iron 36200 mg/kg 20.0 10.0 10 02/11/1517:37 02/15/1518:57 7439-89-6 D3,M6 Magnesium 622 mg/kg 25.1 12.5 1 02/11/15 17:37 02/14/15 22:56 7439-95-4 M1 Manganese 215 mg/kg 2.5 1.3 10 02/11/1517:37 02/15/1518:57 7439-96-5 D3,M6, R1 Molybdenum ND mg/kg 0.50 0.25 1 02/11/15 17:37 02/14/15 22:56 7439-98-7 M1 Nickel 3.3 mg/kg 0.25 0.13 1 02/11/15 17:37 02/14/15 22:56 7440-02-0 Potassium 372 mg/kg 50.1 25.1 1 02/11/15 17:37 02/14/15 22:56 7440-09-7 Sodium ND mg/kg 501 251 10 02/11/1517:37 02/15/1518:57 7440-23-5 Strontium 1.8 mg/kg 0.50 0.25 1 02/11/15 17:37 02/14/15 22:56 7440-24-6 Zinc 10.7 mg/kg 1.0 0.50 1 02/11/15 17:37 02/14/15 22:56 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.0 0.50 20 02/11/1517:37 02/16/1515:31 7440-36-0 D3,N2 Arsenic ND mg/kg 2.5 1.3 50 02/11/1517:37 02/17/1512:10 7440-38-2 D3 Beryllium 0.40 mg/kg 0.12 0.060 20 02/11/1517:37 02/16/1515:31 7440-41-7 D3 Cadmium ND mg/kg 0.30 0.15 50 02/11/1517:37 02/17/1512:10 7440-43-9 D3 Cobalt 11.0 mg/kg 2.5 1.3 50 02/11/1517:37 02/17/1512:10 7440-48-4 D3 Lead 12.7 mg/kg 1.0 0.50 20 02/11/1517:37 02/16/1515:31 7439-92-1 D3 Selenium ND mg/kg 2.5 1.3 50 02/11/1517:37 02/17/1512:10 7782-49-2 D3 Thallium ND mg/kg 1.0 0.50 20 02/11/1517:37 02/16/1515:31 7440-28-0 D3 Vanadium 45.0 mg/kg 2.5 1.3 50 02/11/1517:37 02/17/1512:10 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.041 mg/kg 0.0078 0.0039 1 02/13/1515:37 02/16/1517:13 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 13.5 % 0.10 0.10 1 03/09/15 08:41 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.9 Std. Units 0.10 0.10 1 02/11/15 11:00 D6 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 248 124 5 02/13/15 03:43 16887-00-6 D3,M1 Sulfate ND mg/kg 248 124 5 02/13/15 03:43 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 24.8 12.4 5 02/13/15 03:43 14797-55-8 H3 Date: 03/18/2015 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 37 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020201 Pace Project No.: 92236923 Pace Analytical Services, Inc. PggcO )irpy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015003284 Lab ID: 92236923001 Collected: 01/29/15 11:00 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 4560 mg/kg 1140 570 1 02/18/15 07:58 7440-44-0 Total Organic Carbon 4560 mg/kg 1160 578 1 02/18/15 08:05 7440-44-0 Total Organic Carbon 4580 mg/kg 1150 577 1 02/18/15 08:11 7440-44-0 Total Organic Carbon 4170 mg/kg 1140 572 1 02/18/15 08:18 7440-44-0 Mean Total Organic Carbon 4470 mg/kg 1150 574 1 02/18/15 07:58 7440-44-0 Surrogates RSD% 4.5 % 1 02/18/15 07:58 Date: 03/18/2015 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 38 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020201 Pace Project No.: 92236923 Pace Analytical Services, Inc. P3yy S�05kf�ir6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015003285 Lab ID: 92236923002 Collected: 01/29/15 11:05 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Beryllium Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 03/18/2015 07:29 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 32700 mg/kg 50.6 25.3 10 02/11/1517:37 02/15/1519:10 7429-90-5 172 mg/kg 5.1 2.5 10 02/11/1517:37 02/15/1519:10 7440-39-3 36.2 mg/kg 25.3 12.7 10 02/11/1517:37 02/15/1519:10 7440-42-8 271 mg/kg 253 127 10 02/11/1517:37 02/15/1519:10 7440-70-2 34.2 mg/kg 2.5 1.3 10 02/11/1517:37 02/15/1519:10 7440-47-3 11.6 mg/kg 2.5 1.3 10 02/11/1517:37 02/15/1519:10 7440-50-8 39200 mg/kg 20.3 10.1 10 02/11/1517:37 02/15/1519:10 7439-89-6 4890 mg/kg 253 127 10 02/11/1517:37 02/15/1519:10 7439-95-4 226 mg/kg 2.5 1.3 10 02/11/1517:37 02/15/1519:10 7439-96-5 ND mg/kg 5.1 2.5 10 02/11/1517:37 02/15/1519:10 7439-98-7 15.5 mg/kg 2.5 1.3 10 02/11/1517:37 02/15/1519:10 7440-02-0 4490 mg/kg 506 253 10 02/11/1517:37 02/15/1519:10 7440-09-7 ND mg/kg 506 253 10 02/11/1517:37 02/15/1519:10 7440-23-5 ND mg/kg 5.1 2.5 10 02/11/1517:37 02/15/1519:10 7440-24-6 116 mg/kg 10.1 5.1 10 02/11/1517:37 02/15/1519:10 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 1.0 0.51 20 02/11/1517:37 02/16/1515:44 7440-36-0 ND mg/kg 2.5 1.3 50 02/11/1517:37 02/17/1512:28 7440-38-2 0.89 mg/kg 0.30 0.15 50 02/11/1517:37 02/17/1512:28 7440-41-7 ND mg/kg 0.30 0.15 50 02/11/1517:37 02/17/1512:28 7440-43-9 9.4 mg/kg 2.5 1.3 50 02/11/1517:37 02/17/1512:28 7440-48-4 12.2 mg/kg 1.0 0.51 20 02/11/1517:37 02/16/1515:44 7439-92-1 2AJ mg/kg 2.5 1.3 50 02/11/1517:37 02/17/1512:28 7782-49-2 ND mg/kg 1.0 0.51 20 02/11/1517:37 02/16/1515:44 7440-28-0 48.7 mg/kg 2.5 1.3 50 02/11/1517:37 02/17/1512:28 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.016 mg/kg 0.0079 0.0040 1 02/13/1515:37 02/16/1517:16 7439-97-6 Analytical Method: ASTM D2974-87 21.0 % 0.10 0.10 1 03/09/15 08:41 Analytical Method: EPA 9045 6.3 Std. Units 0.10 0.10 1 02/11/15 11:00 Analytical Method: EPA 9056 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3,M6, N2 D3,M6 D3,M6 D3,M6 D3 D3,M6 D3,M6 D3 D4,M6 ND mg/kg 248 124 5 02/12/1517:45 16887-00-6 D3 ND mg/kg 248 124 5 02/12/1517:45 14808-79-8 D3 Analytical Method: EPA 9056 ND mg/kg 24.8 12.4 5 02/12/1517:45 14797-55-8 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 39 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020201 Pace Project No.: 92236923 Pace Analytical Services, Inc. P3yy SMr6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015003285 Lab ID: 92236923002 Collected: 01/29/15 11:05 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 756 378 1 02/18/15 09:14 7440-44-0 Total Organic Carbon ND mg/kg 753 377 1 02/18/15 09:20 7440-44-0 Total Organic Carbon ND mg/kg 760 380 1 02/18/15 09:26 7440-44-0 Total Organic Carbon ND mg/kg 755 378 1 02/18/15 09:33 7440-44-0 Mean Total Organic Carbon ND mg/kg 756 378 1 02/18/15 09:14 7440-44-0 Surrogates RSD% 2.9 % 1 02/18/15 09:14 Date: 03/18/2015 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 40 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. P 3 M,r6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 Sample: 2015003286 Lab ID: 92236923003 Collected: 01/29/15 11:10 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 26100 mg/kg 51.0 25.5 10 02/11/1517:37 02/15/1519:19 7429-90-5 D3 Barium 209 mg/kg 5.1 2.6 10 02/11/1517:37 02/15/1519:19 7440-39-3 D3 Boron 27.3 mg/kg 25.5 12.8 10 02/11/1517:37 02/15/1519:19 7440-42-8 D3 Calcium ND mg/kg 255 128 10 02/11/1517:37 02/15/1519:19 7440-70-2 D3 Chromium 24.6 mg/kg 2.6 1.3 10 02/11/1517:37 02/15/1519:19 7440-47-3 D3 Copper 1.91 mg/kg 2.6 1.3 10 02/11/1517:37 02/15/1519:19 7440-50-8 D3 Iron 28900 mg/kg 20.4 10.2 10 02/11/1517:37 02/15/1519:19 7439-89-6 D3 Magnesium 7520 mg/kg 255 128 10 02/11/1517:37 02/15/1519:19 7439-95-4 D3 Manganese 336 mg/kg 2.6 1.3 10 02/11/1517:37 02/15/1519:19 7439-96-5 D3 Molybdenum ND mg/kg 5.1 2.6 10 02/11/1517:37 02/15/1519:19 7439-98-7 D3 Nickel 21.1 mg/kg 2.6 1.3 10 02/11/1517:37 02/15/1519:19 7440-02-0 D3 Potassium 7650 mg/kg 510 255 10 02/11/1517:37 02/15/1519:19 7440-09-7 D3 Sodium ND mg/kg 510 255 10 02/11/1517:37 02/15/1519:19 7440-23-5 D3 Strontium 3.2J mg/kg 5.1 2.6 10 02/11/1517:37 02/15/1519:19 7440-24-6 D3 Zinc 192 mg/kg 10.2 5.1 10 02/11/1517:37 02/15/1519:19 7440-66-6 D3 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.0 0.51 20 02/11/1517:37 02/16/1516:05 7440-36-0 D3,N2 Arsenic 1.5J mg/kg 2.6 1.3 50 02/11/1517:37 02/17/1512:32 7440-38-2 D3 Beryllium 1.8 mg/kg 0.12 0.061 20 02/11/1517:37 02/16/1516:05 7440-41-7 D3 Cadmium ND mg/kg 0.31 0.15 50 02/11/1517:37 02/17/1512:32 7440-43-9 D3 Cobalt 16.1 mg/kg 2.6 1.3 50 02/11/1517:37 02/17/1512:32 7440-48-4 D3 Lead 11.9 mg/kg 1.0 0.51 20 02/11/1517:37 02/16/1516:05 7439-92-1 D3 Selenium 4.3 mg/kg 2.6 1.3 50 02/11/1517:37 02/17/1512:32 7782-49-2 D3 Thallium 0.52J mg/kg 1.0 0.51 20 02/11/1517:37 02/16/1516:05 7440-28-0 D3 Vanadium 39.3 mg/kg 2.6 1.3 50 02/11/1517:37 02/17/1512:32 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.0050J mg/kg 0.0078 0.0039 1 02/13/1515:37 02/16/1517:18 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 16.2 % 0.10 0.10 1 03/09/15 08:41 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.5 Std. Units 0.10 0.10 1 02/11/15 11:00 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 251 126 5 02/12/1518:07 16887-00-6 D3 Sulfate ND mg/kg 251 126 5 02/12/1518:07 14808-79-8 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 25.1 12.6 5 02/12/15 18:07 14797-55-8 H3 Date: 03/18/2015 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 41 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020201 Pace Project No.: 92236923 Pace Analytical Services, Inc. P 3 90Ar6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015003286 Lab ID: 92236923003 Collected: 01/29/15 11:10 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 712 356 1 02/18/15 09:38 7440-44-0 Total Organic Carbon ND mg/kg 717 358 1 02/18/15 09:45 7440-44-0 Total Organic Carbon ND mg/kg 716 358 1 02/18/15 09:50 7440-44-0 Total Organic Carbon ND mg/kg 719 360 1 02/18/15 09:57 7440-44-0 Mean Total Organic Carbon ND mg/kg 716 358 1 02/18/15 09:38 7440-44-0 Surrogates RSD% 8.8 % 1 02/18/15 09:38 Date: 03/18/2015 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 42 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. PW%Pwyd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 Sample: 2015003287 Lab ID: 92236923004 Collected: 01/29/15 11:15 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 18800 mg/kg 48.0 24.0 10 02/11/1517:37 02/15/1519:23 7429-90-5 D3 Barium 158 mg/kg 4.8 2.4 10 02/11/1517:37 02/15/1519:23 7440-39-3 D3 Boron 18.3J mg/kg 24.0 12.0 10 02/11/1517:37 02/15/1519:23 7440-42-8 D3 Calcium 186J mg/kg 240 120 10 02/11/1517:37 02/15/1519:23 7440-70-2 D3 Chromium 14.9 mg/kg 2.4 1.2 10 02/11/1517:37 02/15/1519:23 7440-47-3 D3 Copper 4.4 mg/kg 2.4 1.2 10 02/11/1517:37 02/15/1519:23 7440-50-8 D3 Iron 18700 mg/kg 19.2 9.6 10 02/11/1517:37 02/15/1519:23 7439-89-6 D3 Magnesium 6040 mg/kg 240 120 10 02/11/1517:37 02/15/1519:23 7439-95-4 D3 Manganese 284 mg/kg 2.4 1.2 10 02/11/1517:37 02/15/1519:23 7439-96-5 D3 Molybdenum ND mg/kg 4.8 2.4 10 02/11/1517:37 02/15/1519:23 7439-98-7 D3 Nickel 15.4 mg/kg 2.4 1.2 10 02/11/1517:37 02/15/1519:23 7440-02-0 D3 Potassium 7100 mg/kg 480 240 10 02/11/1517:37 02/15/1519:23 7440-09-7 D3 Sodium ND mg/kg 480 240 10 02/11/1517:37 02/15/1519:23 7440-23-5 D3 Strontium 5.8 mg/kg 4.8 2.4 10 02/11/1517:37 02/15/1519:23 7440-24-6 D3 Zinc 85.8 mg/kg 9.6 4.8 10 02/11/1517:37 02/15/1519:23 7440-66-6 D3 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 0.96 0.48 20 02/11/1517:37 02/16/1516:08 7440-36-0 D3,N2 Arsenic ND mg/kg 2.4 1.2 50 02/11/1517:37 02/17/1512:35 7440-38-2 D3 Beryllium 1.7 mg/kg 0.12 0.058 20 02/11/1517:37 02/16/1516:08 7440-41-7 D3 Cadmium ND mg/kg 0.29 0.14 50 02/11/1517:37 02/17/1512:35 7440-43-9 D3 Cobalt 6.1 mg/kg 2.4 1.2 50 02/11/1517:37 02/17/1512:35 7440-48-4 D3 Lead 4.3 mg/kg 0.96 0.48 20 02/11/1517:37 02/16/1516:08 7439-92-1 D3 Selenium 1.8J mg/kg 2.4 1.2 50 02/11/1517:37 02/17/1512:35 7782-49-2 D3 Thallium ND mg/kg 0.96 0.48 20 02/11/1517:37 02/16/1516:08 7440-28-0 D3 Vanadium 15.9 mg/kg 2.4 1.2 50 02/11/1517:37 02/17/1512:35 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0080 0.0040 1 02/13/1515:37 02/16/1517:20 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 19.2 % 0.10 0.10 1 03/09/15 08:55 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.5 Std. Units 0.10 0.10 1 02/11/15 11:00 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 249 124 5 02/12/1518:29 16887-00-6 D3 Sulfate ND mg/kg 249 124 5 02/12/1518:29 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 24.9 12.4 5 02/12/15 18:29 14797-55-8 H3 Date: 03/18/2015 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 43 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020201 Pace Project No.: 92236923 Pace Analytical Services, Inc. P 3 90*r6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015003287 Lab ID: 92236923004 Collected: 01/29/15 11:15 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 741 371 1 02/18/15 10:03 7440-44-0 Total Organic Carbon ND mg/kg 747 373 1 02/18/15 10:09 7440-44-0 Total Organic Carbon ND mg/kg 740 370 1 02/18/15 10:14 7440-44-0 Total Organic Carbon ND mg/kg 738 369 1 02/18/15 10:20 7440-44-0 Mean Total Organic Carbon ND mg/kg 741 371 1 02/18/15 10:03 7440-44-0 Surrogates RSD% 8.9 % 1 02/18/1510:03 Date: 03/18/2015 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 44 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. P 3 90Ar6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 Sample: 2015003288 Lab ID: 92236923005 Collected: 02/03/15 10:00 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 21000 mg/kg 50.3 25.1 10 02/11/1517:37 02/15/1519:40 7429-90-5 D3 Barium 113 mg/kg 5.0 2.5 10 02/11/1517:37 02/15/1519:40 7440-39-3 D3 Boron 31.1 mg/kg 25.1 12.6 10 02/11/1517:37 02/15/1519:40 7440-42-8 D3 Calcium 167J mg/kg 251 126 10 02/11/1517:37 02/15/1519:40 7440-70-2 D3 Chromium 36.1 mg/kg 2.5 1.3 10 02/11/1517:37 02/15/1519:40 7440-47-3 D3 Copper 66.2 mg/kg 2.5 1.3 10 02/11/1517:37 02/15/1519:40 7440-50-8 D3 Iron 32200 mg/kg 20.1 10.1 10 02/11/1517:37 02/15/1519:40 7439-89-6 D3 Magnesium 4840 mg/kg 251 126 10 02/11/1517:37 02/15/1519:40 7439-95-4 D3 Manganese 616 mg/kg 2.5 1.3 10 02/11/1517:37 02/15/1519:40 7439-96-5 D3 Molybdenum ND mg/kg 5.0 2.5 10 02/11/1517:37 02/15/1519:40 7439-98-7 D3 Nickel 16.4 mg/kg 2.5 1.3 10 02/11/1517:37 02/15/1519:40 7440-02-0 D3 Potassium 3790 mg/kg 503 251 10 02/11/1517:37 02/15/1519:40 7440-09-7 D3 Sodium ND mg/kg 503 251 10 02/11/1517:37 02/15/1519:40 7440-23-5 D3 Strontium ND mg/kg 5.0 2.5 10 02/11/1517:37 02/15/1519:40 7440-24-6 D3 Zinc 85.6 mg/kg 10.1 5.0 10 02/11/1517:37 02/15/1519:40 7440-66-6 D3 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.0 0.50 20 02/11/1517:37 02/16/1516:11 7440-36-0 D3,N2 Arsenic 2.2J mg/kg 2.5 1.3 50 02/11/1517:37 02/17/1512:38 7440-38-2 D3 Beryllium 0.72 mg/kg 0.12 0.060 20 02/11/1517:37 02/16/1516:11 7440-41-7 D3 Cadmium ND mg/kg 0.30 0.15 50 02/11/1517:37 02/17/1512:38 7440-43-9 D3 Cobalt 31.8 mg/kg 2.5 1.3 50 02/11/1517:37 02/17/1512:38 7440-48-4 D4 Lead 12.1 mg/kg 1.0 0.50 20 02/11/1517:37 02/16/1516:11 7439-92-1 D3 Selenium 2.9 mg/kg 2.5 1.3 50 02/11/1517:37 02/17/1512:38 7782-49-2 D3 Thallium ND mg/kg 1.0 0.50 20 02/11/1517:37 02/16/1516:11 7440-28-0 D3 Vanadium 41.5 mg/kg 2.5 1.3 50 02/11/1517:37 02/17/1512:38 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.011 mg/kg 0.0081 0.0041 1 02/13/1515:37 02/16/1517:22 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 25.7 % 0.10 0.10 1 03/09/15 08:41 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.4 Std. Units 0.10 0.10 1 02/11/15 11:00 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 248 124 5 02/12/1518:51 16887-00-6 D3 Sulfate ND mg/kg 248 124 5 02/12/1518:51 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 24.8 12.4 5 02/12/15 18:51 14797-55-8 H3 Date: 03/18/2015 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 45 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020201 Pace Project No.: 92236923 Pace Analytical Services, Inc. P3Sy Mr6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015003288 Lab ID: 92236923005 Collected: 02/03/15 10:00 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1350 mg/kg 805 403 1 02/18/15 10:25 7440-44-0 Total Organic Carbon 1360 mg/kg 813 406 1 02/18/15 10:31 7440-44-0 Total Organic Carbon 1900 mg/kg 805 402 1 02/18/15 10:37 7440-44-0 Total Organic Carbon 1720 mg/kg 808 404 1 02/18/15 10:43 7440-44-0 Mean Total Organic Carbon 1580 mg/kg 808 404 1 02/18/15 10:25 7440-44-0 Surrogates RSD% 17.0 % 1 02/18/1510:25 Date: 03/18/2015 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 46 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. P369%1birwy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 Sample: 2015003289 Lab ID: 92236923006 Collected: 02/03/15 11:30 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 16300 mg/kg 48.7 24.4 10 02/11/1517:37 02/15/1519:45 7429-90-5 D3 Barium 238 mg/kg 4.9 2.4 10 02/11/1517:37 02/15/1519:45 7440-39-3 D3 Boron 28.4 mg/kg 24.4 12.2 10 02/11/1517:37 02/15/1519:45 7440-42-8 D3 Calcium 2750 mg/kg 244 122 10 02/11/1517:37 02/15/1519:45 7440-70-2 D3 Chromium 25.2 mg/kg 2.4 1.2 10 02/11/1517:37 02/15/1519:45 7440-47-3 D3 Copper 41.2 mg/kg 2.4 1.2 10 02/11/1517:37 02/15/1519:45 7440-50-8 D3 Iron 29400 mg/kg 19.5 9.7 10 02/11/1517:37 02/15/1519:45 7439-89-6 D3 Magnesium 10400 mg/kg 244 122 10 02/11/1517:37 02/15/1519:45 7439-95-4 D3 Manganese 492 mg/kg 2.4 1.2 10 02/11/1517:37 02/15/1519:45 7439-96-5 D3 Molybdenum ND mg/kg 4.9 2.4 10 02/11/1517:37 02/15/1519:45 7439-98-7 D3 Nickel 25.3 mg/kg 2.4 1.2 10 02/11/1517:37 02/15/1519:45 7440-02-0 D3 Potassium 12700 mg/kg 487 244 10 02/11/1517:37 02/15/1519:45 7440-09-7 D3 Sodium ND mg/kg 487 244 10 02/11/1517:37 02/15/1519:45 7440-23-5 D3 Strontium 8.6 mg/kg 4.9 2.4 10 02/11/1517:37 02/15/1519:45 7440-24-6 D3 Zinc 111 mg/kg 9.7 4.9 10 02/11/1517:37 02/15/1519:45 7440-66-6 D3 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 0.97 0.49 20 02/11/1517:37 02/16/1516:15 7440-36-0 D3,N2 Arsenic ND mg/kg 2.4 1.2 50 02/11/1517:37 02/17/1512:42 7440-38-2 D3 Beryllium 0.63 mg/kg 0.12 0.058 20 02/11/1517:37 02/16/1516:15 7440-41-7 D3 Cadmium ND mg/kg 0.29 0.15 50 02/11/1517:37 02/17/1512:42 7440-43-9 D3 Cobalt 13.0 mg/kg 2.4 1.2 50 02/11/1517:37 02/17/1512:42 7440-48-4 D3 Lead 3.0 mg/kg 0.97 0.49 20 02/11/1517:37 02/16/1516:15 7439-92-1 D3 Selenium 1.3J mg/kg 2.4 1.2 50 02/11/1517:37 02/17/1512:42 7782-49-2 D3 Thallium 0.83J mg/kg 0.97 0.49 20 02/11/1517:37 02/16/1516:15 7440-28-0 D3 Vanadium 27.7 mg/kg 2.4 1.2 50 02/11/1517:37 02/17/1512:42 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0079 0.0039 1 02/13/1515:37 02/16/1517:24 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 19.3 % 0.10 0.10 1 03/09/15 08:41 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 8.0 Std. Units 0.10 0.10 1 02/11/15 11:00 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 02/19/15 16:00 Sulfate 2AJ mg/L 2.5 1.2 1 02/25/1518:22 14808-79-8 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 02/19/15 16:00 Nitrogen, Nitrate ND mg/L 0.25 0.25 1 02/20/15 21:35 P4 4500 Chloride, SPLP Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 02/19/15 16:00 Chloride 5.9J mg/L 6.2 3.1 1 02/21/15 02:02 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 47 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. P36R%-)ir6fYo"�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 Sample: 2015003289 Lab ID: 92236923006 Collected: 02/03/15 11:30 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 250 125 5 02/12/1519:13 16887-00-6 D3 Sulfate ND mg/kg 250 125 5 02/12/1519:13 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 25.0 12.5 5 02/12/15 19:13 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 742 371 1 02/18/15 10:49 7440-44-0 Total Organic Carbon ND mg/kg 747 373 1 02/18/15 10:54 7440-44-0 Total Organic Carbon ND mg/kg 741 371 1 02/18/15 11:00 7440-44-0 Total Organic Carbon ND mg/kg 744 372 1 02/18/15 11:05 7440-44-0 Mean Total Organic Carbon ND mg/kg 744 372 1 02/18/15 10:49 7440-44-0 Surrogates RSD% 2.2 % 1 02/18/1510:49 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 48 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. PW06Jf WydW e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 Sample: 2015003291 Lab ID: 92236923007 Collected: 02/04/15 12:00 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 18600 mg/kg 49.0 24.5 10 02/11/1517:37 02/15/1519:49 7429-90-5 D3 Barium 86.7 mg/kg 4.9 2.5 10 02/11/1517:37 02/15/1519:49 7440-39-3 D3 Boron 14.1J mg/kg 24.5 12.3 10 02/11/1517:37 02/15/1519:49 7440-42-8 D3 Calcium 145J mg/kg 245 123 10 02/11/1517:37 02/15/1519:49 7440-70-2 D3 Chromium 19.5 mg/kg 2.5 1.2 10 02/11/1517:37 02/15/1519:49 7440-47-3 D3 Copper 10.3 mg/kg 2.5 1.2 10 02/11/1517:37 02/15/1519:49 7440-50-8 D3 Iron 14000 mg/kg 19.6 9.8 10 02/11/1517:37 02/15/1519:49 7439-89-6 D3 Magnesium 4260 mg/kg 245 123 10 02/11/1517:37 02/15/1519:49 7439-95-4 D3 Manganese 120 mg/kg 2.5 1.2 10 02/11/1517:37 02/15/1519:49 7439-96-5 D3 Molybdenum ND mg/kg 4.9 2.5 10 02/11/1517:37 02/15/1519:49 7439-98-7 D3 Nickel 8.8 mg/kg 2.5 1.2 10 02/11/1517:37 02/15/1519:49 7440-02-0 D3 Potassium 2840 mg/kg 490 245 10 02/11/1517:37 02/15/1519:49 7440-09-7 D3 Sodium ND mg/kg 490 245 10 02/11/1517:37 02/15/1519:49 7440-23-5 D3 Strontium ND mg/kg 4.9 2.5 10 02/11/1517:37 02/15/1519:49 7440-24-6 D3 Zinc 50.0 mg/kg 9.8 4.9 10 02/11/1517:37 02/15/1519:49 7440-66-6 D3 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 0.98 0.49 20 02/11/1517:37 02/16/1516:18 7440-36-0 D3,N2 Arsenic ND mg/kg 2.5 1.2 50 02/11/1517:37 02/17/1512:45 7440-38-2 D3 Beryllium 0.60 mg/kg 0.12 0.059 20 02/11/1517:37 02/16/1516:18 7440-41-7 D3 Cadmium ND mg/kg 0.29 0.15 50 02/11/1517:37 02/17/1512:45 7440-43-9 D3 Cobalt 5.5 mg/kg 2.5 1.2 50 02/11/1517:37 02/17/1512:45 7440-48-4 D3 Lead 8.6 mg/kg 0.98 0.49 20 02/11/1517:37 02/16/1516:18 7439-92-1 D3 Selenium 1.3J mg/kg 2.5 1.2 50 02/11/1517:37 02/17/1512:45 7782-49-2 D3 Thallium ND mg/kg 0.98 0.49 20 02/11/1517:37 02/16/1516:18 7440-28-0 D3 Vanadium 36.0 mg/kg 2.5 1.2 50 02/11/1517:37 02/17/1512:45 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.018 mg/kg 0.0082 0.0041 1 02/13/1515:37 02/16/1517:26 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 23.6 % 0.10 0.10 1 03/09/15 08:41 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.3 Std. Units 0.10 0.10 1 02/11/15 11:00 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 02/25/15 16:00 Sulfate 4.5 mg/L 2.6 1.3 1 02/27/1512:57 14808-79-8 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 02/25/15 16:00 Nitrogen, Nitrate ND mg/L 0.26 0.26 1 02/26/15 18:15 H1 4500 Chloride, SPLP Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 02/25/15 16:00 Chloride ND mg/L 6.5 3.3 1 02/27/15 02:39 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 49 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. P3y SHISr6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 Sample: 2015003291 Lab ID: 92236923007 Collected: 02/04/15 12:00 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 248 124 5 02/12/1519:35 16887-00-6 D3 Sulfate ND mg/kg 248 124 5 02/12/1519:35 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 24.8 12.4 5 02/12/15 19:35 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1560 mg/kg 783 392 1 02/18/15 11:22 7440-44-0 Total Organic Carbon 1480 mg/kg 780 390 1 02/18/15 11:27 7440-44-0 Total Organic Carbon 1550 mg/kg 789 395 1 02/18/15 11:33 7440-44-0 Total Organic Carbon 1480 mg/kg 785 393 1 02/18/15 11:38 7440-44-0 Mean Total Organic Carbon 1520 mg/kg 784 392 1 02/18/15 11:22 7440-44-0 Surrogates RSD% 3.0 % 1 02/18/1511:22 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 50 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. P 3 9%16 1ir6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 Sample: 2015003293 Lab ID: 92236923008 Collected: 02/04/15 12:40 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 16800 mg/kg 51.8 25.9 10 02/11/1517:37 02/15/1519:53 7429-90-5 D3 Barium 209 mg/kg 5.2 2.6 10 02/11/1517:37 02/15/1519:53 7440-39-3 D3 Boron 23.6J mg/kg 25.9 12.9 10 02/11/1517:37 02/15/1519:53 7440-42-8 D3 Calcium 418 mg/kg 259 129 10 02/11/1517:37 02/15/1519:53 7440-70-2 D3 Chromium 21.4 mg/kg 2.6 1.3 10 02/11/1517:37 02/15/1519:53 7440-47-3 D3 Copper 1.51 mg/kg 2.6 1.3 10 02/11/1517:37 02/15/1519:53 7440-50-8 D3 Iron 24300 mg/kg 20.7 10.4 10 02/11/1517:37 02/15/1519:53 7439-89-6 D3 Magnesium 7310 mg/kg 259 129 10 02/11/1517:37 02/15/1519:53 7439-95-4 D3 Manganese 247 mg/kg 2.6 1.3 10 02/11/1517:37 02/15/1519:53 7439-96-5 D3 Molybdenum ND mg/kg 5.2 2.6 10 02/11/1517:37 02/15/1519:53 7439-98-7 D3 Nickel 13.7 mg/kg 2.6 1.3 10 02/11/1517:37 02/15/1519:53 7440-02-0 D3 Potassium 8930 mg/kg 518 259 10 02/11/1517:37 02/15/1519:53 7440-09-7 D3 Sodium ND mg/kg 518 259 10 02/11/1517:37 02/15/1519:53 7440-23-5 D3 Strontium 12.2 mg/kg 5.2 2.6 10 02/11/1517:37 02/15/1519:53 7440-24-6 D3 Zinc 76.1 mg/kg 10.4 5.2 10 02/11/1517:37 02/15/1519:53 7440-66-6 D3 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.0 0.52 20 02/11/1517:37 02/16/1516:21 7440-36-0 D3,N2 Arsenic ND mg/kg 2.6 1.3 50 02/11/1517:37 02/17/1512:48 7440-38-2 D3 Beryllium 0.68 mg/kg 0.12 0.062 20 02/11/1517:37 02/16/1516:21 7440-41-7 D3 Cadmium ND mg/kg 0.31 0.16 50 02/11/1517:37 02/17/1512:48 7440-43-9 D3 Cobalt 10.6 mg/kg 2.6 1.3 50 02/11/1517:37 02/17/1512:48 7440-48-4 D3 Lead 4.5 mg/kg 1.0 0.52 20 02/11/1517:37 02/16/1516:21 7439-92-1 D3 Selenium ND mg/kg 2.6 1.3 50 02/11/1517:37 02/17/1512:48 7782-49-2 D3 Thallium 0.55J mg/kg 1.0 0.52 20 02/11/1517:37 02/16/1516:21 7440-28-0 D3 Vanadium 31.5 mg/kg 2.6 1.3 50 02/11/1517:37 02/17/1512:48 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0078 0.0039 1 02/13/1515:37 02/16/1517:28 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 17.4 % 0.10 0.10 1 03/09/15 08:41 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.1 Std. Units 0.10 0.10 1 02/12/15 13:15 D6 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 02/19/15 16:00 Sulfate 2.9 mg/L 2.4 1.2 1 02/25/1518:36 14808-79-8 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 02/19/15 16:00 Nitrogen, Nitrate ND mg/L 0.24 0.24 1 02/20/15 21:44 P4 4500 Chloride, SPLP Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 02/19/15 16:00 Chloride 3.1J mg/L 6.1 3.0 1 02/21/15 02:03 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 51 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. P 3 9%18r6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 Sample: 2015003293 Lab ID: 92236923008 Collected: 02/04/15 12:40 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 250 125 5 02/12/1519:57 16887-00-6 D3 Sulfate ND mg/kg 250 125 5 02/12/1519:57 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 25.0 12.5 5 02/12/15 19:57 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 728 364 1 02/18/15 17:59 7440-44-0 Total Organic Carbon ND mg/kg 720 360 1 02/18/15 18:04 7440-44-0 Total Organic Carbon ND mg/kg 725 362 1 02/18/15 18:10 7440-44-0 Total Organic Carbon ND mg/kg 720 360 1 02/18/15 18:15 7440-44-0 Mean Total Organic Carbon ND mg/kg 723 362 1 02/18/15 17:59 7440-44-0 Surrogates RSD% 8.7 % 1 02/18/1517:59 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 52 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. P369% 6fydy e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 Sample: 2015003290 Lab ID: 92236923009 Collected: 02/04/15 11:50 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 18100 mg/kg 51.5 25.8 10 02/11/1517:37 02/15/1519:58 7429-90-5 D3 Barium 112 mg/kg 5.2 2.6 10 02/11/1517:37 02/15/1519:58 7440-39-3 D3 Boron 20AJ mg/kg 25.8 12.9 10 02/11/1517:37 02/15/1519:58 7440-42-8 D3 Calcium 975 mg/kg 258 129 10 02/11/1517:37 02/15/1519:58 7440-70-2 D3 Chromium 18.5 mg/kg 2.6 1.3 10 02/11/1517:37 02/15/1519:58 7440-47-3 D3 Copper 5.9 mg/kg 2.6 1.3 10 02/11/1517:37 02/15/1519:58 7440-50-8 D3 Iron 20900 mg/kg 20.6 10.3 10 02/11/1517:37 02/15/1519:58 7439-89-6 D3 Magnesium 5470 mg/kg 258 129 10 02/11/1517:37 02/15/1519:58 7439-95-4 D3 Manganese 190 mg/kg 2.6 1.3 10 02/11/1517:37 02/15/1519:58 7439-96-5 D3 Molybdenum ND mg/kg 5.2 2.6 10 02/11/1517:37 02/15/1519:58 7439-98-7 D3 Nickel 13.6 mg/kg 2.6 1.3 10 02/11/1517:37 02/15/1519:58 7440-02-0 D3 Potassium 4470 mg/kg 515 258 10 02/11/1517:37 02/15/1519:58 7440-09-7 D3 Sodium ND mg/kg 515 258 10 02/11/1517:37 02/15/1519:58 7440-23-5 D3 Strontium 3.6J mg/kg 5.2 2.6 10 02/11/1517:37 02/15/1519:58 7440-24-6 D3 Zinc 62.4 mg/kg 10.3 5.2 10 02/11/1517:37 02/15/1519:58 7440-66-6 D3 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.0 0.52 20 02/11/1517:37 02/16/1516:25 7440-36-0 D3,N2 Arsenic 1.4J mg/kg 2.6 1.3 50 02/11/1517:37 02/17/1512:52 7440-38-2 D3 Beryllium 0.51 mg/kg 0.12 0.062 20 02/11/1517:37 02/16/1516:25 7440-41-7 D3 Cadmium ND mg/kg 0.31 0.15 50 02/11/1517:37 02/17/1512:52 7440-43-9 D3 Cobalt 10.1 mg/kg 2.6 1.3 50 02/11/1517:37 02/17/1512:52 7440-48-4 D3 Lead 7.3 mg/kg 1.0 0.52 20 02/11/1517:37 02/16/1516:25 7439-92-1 D3 Selenium 1.6J mg/kg 2.6 1.3 50 02/11/1517:37 02/17/1512:52 7782-49-2 D3 Thallium ND mg/kg 1.0 0.52 20 02/11/1517:37 02/16/1516:25 7440-28-0 D3 Vanadium 26.0 mg/kg 2.6 1.3 50 02/11/1517:37 02/17/1512:52 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.018 mg/kg 0.0081 0.0040 1 02/13/1515:37 02/16/1517:31 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 10.9 % 0.10 0.10 1 03/09/15 08:41 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 7.2 Std. Units 0.10 0.10 1 02/12/15 13:15 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 247 124 5 02/12/15 20:20 16887-00-6 D3 Sulfate ND mg/kg 247 124 5 02/12/15 20:20 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 24.7 12.4 5 02/12/15 20:20 14797-55-8 H3 Date: 03/18/2015 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 53 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020201 Pace Project No.: 92236923 Pace Analytical Services, Inc. PWVrwyd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015003290 Lab ID: 92236923009 Collected: 02/04/15 11:50 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1970 mg/kg 671 336 1 02/18/15 12:19 7440-44-0 Total Organic Carbon 1900 mg/kg 673 337 1 02/18/15 12:25 7440-44-0 Total Organic Carbon 2120 mg/kg 673 336 1 02/18/15 12:31 7440-44-0 Total Organic Carbon 2150 mg/kg 676 338 1 02/18/15 12:36 7440-44-0 Mean Total Organic Carbon 2030 mg/kg 673 337 1 02/18/15 12:19 7440-44-0 Surrogates RSD% 5.9 % 1 02/18/1512:19 Date: 03/18/2015 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 54 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. P369%18ir6fy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 Sample: 2015003292 Lab ID: 92236923010 Collected: 02/04/15 12:05 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 18700 mg/kg 50.8 25.4 10 02/11/15 17:37 02/15/15 20:02 7429-90-5 D3 Barium 185 mg/kg 5.1 2.5 10 02/11/15 17:37 02/15/15 20:02 7440-39-3 D3 Boron 21.8J mg/kg 25.4 12.7 10 02/11/15 17:37 02/15/15 20:02 7440-42-8 D3 Calcium 859 mg/kg 254 127 10 02/11/15 17:37 02/15/15 20:02 7440-70-2 D3 Chromium 15.7 mg/kg 2.5 1.3 10 02/11/15 17:37 02/15/15 20:02 7440-47-3 D3 Copper 1.4J mg/kg 2.5 1.3 10 02/11/15 17:37 02/15/15 20:02 7440-50-8 D3 Iron 23300 mg/kg 20.3 10.2 10 02/11/15 17:37 02/15/15 20:02 7439-89-6 D3 Magnesium 9570 mg/kg 254 127 10 02/11/15 17:37 02/15/15 20:02 7439-95-4 D3 Manganese 285 mg/kg 2.5 1.3 10 02/11/15 17:37 02/15/15 20:02 7439-96-5 D3 Molybdenum ND mg/kg 5.1 2.5 10 02/11/15 17:37 02/15/15 20:02 7439-98-7 D3 Nickel 20.5 mg/kg 2.5 1.3 10 02/11/15 17:37 02/15/15 20:02 7440-02-0 D3 Potassium 8060 mg/kg 508 254 10 02/11/15 17:37 02/15/15 20:02 7440-09-7 D3 Sodium ND mg/kg 508 254 10 02/11/15 17:37 02/15/15 20:02 7440-23-5 D3 Strontium 12.3 mg/kg 5.1 2.5 10 02/11/15 17:37 02/15/15 20:02 7440-24-6 D3 Zinc 97.4 mg/kg 10.2 5.1 10 02/11/15 17:37 02/15/15 20:02 7440-66-6 D3 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.0 0.51 20 02/11/1517:37 02/16/1516:28 7440-36-0 D3,N2 Arsenic ND mg/kg 2.5 1.3 50 02/11/1517:37 02/17/1512:55 7440-38-2 D3 Beryllium 0.64 mg/kg 0.12 0.061 20 02/11/1517:37 02/16/1516:28 7440-41-7 D3 Cadmium ND mg/kg 0.30 0.15 50 02/11/1517:37 02/17/1512:55 7440-43-9 D3 Cobalt 13.8 mg/kg 2.5 1.3 50 02/11/1517:37 02/17/1512:55 7440-48-4 D3 Lead 3.1 mg/kg 1.0 0.51 20 02/11/1517:37 02/16/1516:28 7439-92-1 D3 Selenium ND mg/kg 2.5 1.3 50 02/11/1517:37 02/17/1512:55 7782-49-2 D3 Thallium 0.52J mg/kg 1.0 0.51 20 02/11/1517:37 02/16/1516:28 7440-28-0 D3 Vanadium 23.3 mg/kg 2.5 1.3 50 02/11/1517:37 02/17/1512:55 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0077 0.0039 1 02/13/1515:37 02/16/1517:33 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 18.6 % 0.10 0.10 1 03/09/15 08:42 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.7 Std. Units 0.10 0.10 1 02/12/15 13:15 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 249 124 5 02/12/15 20:42 16887-00-6 D3 Sulfate ND mg/kg 249 124 5 02/12/15 20:42 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 24.9 12.4 5 02/12/15 20:42 14797-55-8 H3 Date: 03/18/2015 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 55 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020201 Pace Project No.: 92236923 Pace Analytical Services, Inc. P 3 9%16r6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015003292 Lab ID: 92236923010 Collected: 02/04/15 12:05 Received: 02/09/15 14:47 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 730 365 1 02/18/15 12:42 7440-44-0 Total Organic Carbon ND mg/kg 734 367 1 02/18/15 12:47 7440-44-0 Total Organic Carbon ND mg/kg 739 369 1 02/18/15 12:53 7440-44-0 Total Organic Carbon ND mg/kg 733 367 1 02/18/15 12:58 7440-44-0 Mean Total Organic Carbon ND mg/kg 734 367 1 02/18/15 12:42 7440-44-0 Surrogates RSD% 4.8 % 1 02/18/1512:42 Date: 03/18/2015 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 56 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020201 Pace Project No.: 92236923 Pace Analytical Services, Inc. P36907`bir6fY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015003289 SPLP METALS Lab ID: 92236923011 Collected: 02/03/15 11:30 Received: 02/09/15 14:47 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 03/18/2015 07:29 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 15100 ug/L 10.0 1.2 1 03/13/15 13:04 03/13/15 20:09 7429-90-5 ND ug/L 0.50 0.25 1 03/13/15 13:04 03/13/15 20:09 7440-36-0 2.8 ug/L 0.50 0.25 1 03/13/15 13:04 03/13/15 20:09 7440-38-2 251 ug/L 0.30 0.14 1 03/13/15 13:04 03/13/15 20:09 7440-39-3 0.68 ug/L 0.20 0.066 1 03/13/15 13:04 03/13/15 20:09 7440-41-7 7.1 ug/L 5.0 1.0 1 03/13/15 13:04 03/13/15 20:09 7440-42-8 ND ug/L 0.080 0.033 1 03/13/15 13:04 03/13/15 20:09 7440-43-9 3100 ug/L 40.0 8.4 1 03/13/15 13:04 03/13/15 20:09 7440-70-2 17.5 ug/L 0.50 0.22 1 03/13/15 13:04 03/13/15 20:09 7440-47-3 10.1 ug/L 0.50 0.25 1 03/13/15 13:04 03/13/15 20:09 7440-48-4 40.8 ug/L 1.0 0.22 1 03/13/15 13:04 03/13/15 20:09 7440-50-8 20500 ug/L 50.0 8.0 1 03/13/15 13:04 03/13/15 20:09 7439-89-6 4.0 ug/L 0.10 0.046 1 03/13/15 13:04 03/13/15 20:09 7439-92-1 5750 ug/L 10.0 2.8 1 03/13/15 13:04 03/13/15 20:09 7439-95-4 646 ug/L 2.5 0.68 5 03/13/15 13:04 03/16/15 09:53 7439-96-5 1.5 ug/L 0.50 0.24 1 03/13/15 13:04 03/13/15 20:09 7439-98-7 15.1 ug/L 0.50 0.23 1 03/13/15 13:04 03/13/15 20:09 7440-02-0 8270 ug/L 50.0 8.3 1 03/13/15 13:04 03/13/15 20:09 7440-09-7 2.8 ug/L 0.50 0.25 1 03/13/15 13:04 03/13/15 20:09 7782-49-2 4170 ug/L 50.0 18.2 1 03/13/15 13:04 03/13/15 20:09 7440-23-5 19.8 ug/L 0.50 0.057 1 03/13/15 13:04 03/13/15 20:09 7440-24-6 0.42 ug/L 0.10 0.025 1 03/13/15 13:04 03/13/15 20:09 7440-28-0 24.0 ug/L 1.0 0.21 1 03/13/15 13:04 03/13/15 20:09 7440-62-2 61.4 ug/L 5.0 2.5 1 03/13/15 13:04 03/13/15 20:09 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.026 1 03/12/1511:18 03/12/1514:52 7439-97-6 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 57 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020201 Pace Project No.: 92236923 Pace Analytical Services, Inc. PgRoAirpy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015003291 SPLP METALS Lab ID: 92236923012 Collected: 02/04/15 12:00 Received: 02/09/15 14:47 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\riil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 03/18/2015 07:29 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 47.6 ug/L 10.0 1.2 1 03/12/1510:12 03/12/1515:01 7429-90-5 ND ug/L 0.50 0.25 1 03/12/1510:12 03/12/1515:01 7440-36-0 ND ug/L 0.50 0.25 1 03/12/1510:12 03/12/1515:01 7440-38-2 4.1 ug/L 0.30 0.14 1 03/12/1510:12 03/12/1515:01 7440-39-3 ND ug/L 0.20 0.066 1 03/12/1510:12 03/12/1515:01 7440-41-7 20.2 ug/L 5.0 1.0 1 03/12/1510:12 03/12/1515:01 7440-42-8 ND ug/L 0.080 0.033 1 03/12/1510:12 03/12/1515:01 7440-43-9 748 ug/L 40.0 8.4 1 03/12/1510:12 03/12/1515:01 7440-70-2 0.54 ug/L 0.50 0.22 1 03/12/1510:12 03/12/1515:01 7440-47-3 ND ug/L 0.50 0.25 1 03/12/1510:12 03/12/1515:01 7440-48-4 ND ug/L 1.0 0.22 1 03/12/1510:12 03/12/1515:01 7440-50-8 ND ug/L 50.0 8.0 1 03/12/1510:12 03/12/1515:01 7439-89-6 0.38 ug/L 0.10 0.046 1 03/12/1510:12 03/12/1515:01 7439-92-1 390 ug/L 10.0 2.8 1 03/12/1510:12 03/12/1515:01 7439-95-4 7.3 ug/L 0.50 0.14 1 03/12/1510:12 03/12/1515:01 7439-96-5 ND ug/L 0.50 0.24 1 03/12/1510:12 03/12/1515:01 7439-98-7 ND ug/L 0.50 0.23 1 03/12/1510:12 03/12/1515:01 7440-02-0 127 ug/L 50.0 8.3 1 03/12/1510:12 03/12/1515:01 7440-09-7 ND ug/L 0.50 0.25 1 03/12/1510:12 03/12/1515:01 7782-49-2 3390 ug/L 50.0 18.2 1 03/12/1510:12 03/12/1515:01 7440-23-5 2.9 ug/L 0.50 0.057 1 03/12/1510:12 03/12/1515:01 7440-24-6 ND ug/L 0.10 0.025 1 03/12/1510:12 03/12/1515:01 7440-28-0 ND ug/L 1.0 0.21 1 03/12/1510:12 03/12/1515:01 7440-62-2 ND ug/L 5.0 2.5 1 03/12/1510:12 03/12/1515:01 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.026 1 03/11/15 21:20 03/12/15 11:32 7439-97-6 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 58 of 88 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020201 Pace Project No.: 92236923 Pace Analytical Services, Inc. PARO&WYde. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015003293 SPLP METALS Lab ID: 92236923013 Collected: 02/04/15 12:40 Received: 02/09/15 14:47 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 03/18/2015 07:29 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 17.6 ug/L 10.0 1.2 1 03/13/15 13:04 03/13/15 20:14 7429-90-5 ND ug/L 0.50 0.25 1 03/13/15 13:04 03/13/15 20:14 7440-36-0 ND ug/L 0.50 0.25 1 03/13/15 13:04 03/13/15 20:14 7440-38-2 0.54 ug/L 0.30 0.14 1 03/13/15 13:04 03/13/15 20:14 7440-39-3 ND ug/L 0.20 0.066 1 03/13/15 13:04 03/13/15 20:14 7440-41-7 47.8 ug/L 5.0 1.0 1 03/13/15 13:04 03/13/15 20:14 7440-42-8 ND ug/L 0.080 0.033 1 03/13/15 13:04 03/13/15 20:14 7440-43-9 158 ug/L 40.0 8.4 1 03/13/15 13:04 03/13/15 20:14 7440-70-2 0.51 ug/L 0.50 0.22 1 03/13/15 13:04 03/13/15 20:14 7440-47-3 ND ug/L 0.50 0.25 1 03/13/15 13:04 03/13/15 20:14 7440-48-4 ND ug/L 1.0 0.22 1 03/13/15 13:04 03/13/15 20:14 7440-50-8 ND ug/L 50.0 8.0 1 03/13/15 13:04 03/13/15 20:14 7439-89-6 ND ug/L 0.10 0.046 1 03/13/15 13:04 03/13/15 20:14 7439-92-1 112 ug/L 10.0 2.8 1 03/13/15 13:04 03/13/15 20:14 7439-95-4 ND ug/L 0.50 0.14 1 03/13/15 13:04 03/13/15 20:14 7439-96-5 ND ug/L 0.50 0.24 1 03/13/15 13:04 03/13/15 20:14 7439-98-7 ND ug/L 0.50 0.23 1 03/13/15 13:04 03/13/15 20:14 7440-02-0 344 ug/L 50.0 8.3 1 03/13/15 13:04 03/13/15 20:14 7440-09-7 ND ug/L 0.50 0.25 1 03/13/15 13:04 03/13/15 20:14 7782-49-2 3940 ug/L 50.0 18.2 1 03/13/15 13:04 03/13/15 20:14 7440-23-5 ND ug/L 0.50 0.057 1 03/13/15 13:04 03/13/15 20:14 7440-24-6 ND ug/L 0.10 0.025 1 03/13/15 13:04 03/13/15 20:14 7440-28-0 ND ug/L 1.0 0.21 1 03/13/15 13:04 03/13/15 20:14 7440-62-2 ND ug/L 5.0 2.5 1 03/13/15 13:04 03/13/15 20:14 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.026 1 03/12/1511:18 03/12/1514:54 7439-97-6 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 59 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P3690 3irwY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 QC Batch: MERP/12942 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92236923012 METHOD BLANK: 1915712 Matrix: Water Associated Lab Samples: 92236923012 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 03/12/1511:27 LABORATORY CONTROL SAMPLE: 1915713 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.4 89 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1915716 1915717 MS MSD 10298112001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.0 5.0 99 99 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 60 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P36907 rWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 QC Batch: MERP/12953 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92236923011, 92236923013 METHOD BLANK: 1916588 Matrix: Water Associated Lab Samples: 92236923011, 92236923013 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 03/12/1514:47 LABORATORY CONTROL SAMPLE: 1916589 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.9 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1916590 1916591 MS MSD 92239540010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.9 4.8 98 95 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 61 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P36908r6fY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 QC Batch: MERP/5372 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92236923001, 92236923002, 92236923003, 92236923004, 92236923005, 92236923006, 92236923007, 92236923008,92236923009,92236923010 METHOD BLANK: 1130569 Matrix: Solid Associated Lab Samples: 92236923001, 92236923002, 92236923003, 92236923004, 92236923005, 92236923006, 92236923007, 92236923008,92236923009,92236923010 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0081 02/16/1515:55 LABORATORY CONTROL SAMPLE: 1130570 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .082 0.084 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1130571 1130572 MS MSD 35174947001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Mercury mg/kg 0.018 .094 .0894 0.12 0.12 105 110 80-120 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 62 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15020201 Pace Project No.: 92236923 Pace Analytical Services, Inc. P3690 �irwy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QC Batch: MPRP/22645 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92236923001, 92236923002, 92236923003, 92236923004, 92236923005, 92236923006, 92236923007, 92236923008,92236923009,92236923010 METHOD BLANK: 1128075 Matrix: Solid Associated Lab Samples: 92236923001, 92236923002, 92236923003, 92236923004, 92236923005, 92236923006, 92236923007, 92236923008,92236923009,92236923010 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Aluminum mg/kg ND 5.2 02/15/1518:49 Barium mg/kg ND 0.52 02/15/1518:49 Boron mg/kg ND 2.6 02/15/1518:49 Calcium mg/kg ND 25.8 02/15/1518:49 Chromium mg/kg ND 0.26 02/15/1518:49 Copper mg/kg ND 0.26 02/15/1518:49 Iron mg/kg ND 2.1 02/15/1518:49 Magnesium mg/kg ND 25.8 02/15/1518:49 Manganese mg/kg ND 0.26 02/15/1518:49 Molybdenum mg/kg ND 0.52 02/15/1518:49 Nickel mg/kg ND 0.26 02/15/1518:49 Potassium mg/kg ND 51.5 02/15/1518:49 Sodium mg/kg ND 51.5 02/15/1518:49 Strontium mg/kg ND 0.52 02/15/1518:49 Zinc mg/kg ND 1.0 02/15/1518:49 LABORATORY CONTROL SAMPLE: Parameter 1128076 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum mg/kg 128 133 104 80-120 Barium mg/kg 12.8 13.6 106 80-120 Boron mg/kg 128 134 105 80-120 Calcium mg/kg 642 667 104 80-120 Chromium mg/kg 12.8 13.4 104 80-120 Copper mg/kg 12.8 13.6 106 80-120 Iron mg/kg 128 131 102 80-120 Magnesium mg/kg 642 656 102 80-120 Manganese mg/kg 12.8 13.5 105 80-120 Molybdenum mg/kg 12.8 12.5 98 80-120 Nickel mg/kg 12.8 13.0 101 80-120 Potassium mg/kg 642 648 101 80-120 Sodium mg/kg 642 695 108 80-120 Strontium mg/kg 12.8 13.2 103 80-120 Zinc mg/kg 64.2 65.7 102 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 63 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. PARO&WYde. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1128077 1128078 MS MSD 92236923001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 12700 119 123 25700 28500 10900 12900 75-125 10 20 M6 Barium mg/kg 36.3 11.9 12.3 50.5 52.8 120 135 75-125 4 20 M1 Boron mg/kg 36.4 119 123 138 141 86 85 75-125 2 20 Calcium mg/kg 664 595 614 1430 1280 128 100 75-125 11 20 M1 Chromium mg/kg 41.7 11.9 12.3 44.7 45.1 25 28 75-125 1 20 M6 Copper mg/kg 21.4 11.9 12.3 37.3 35.8 134 118 75-125 4 20 M6 Iron mg/kg 36200 119 123 36900 37900 632 1400 75-125 3 20 M6 Magnesium mg/kg 622 595 614 1150 1010 90 63 75-125 14 20 M1 Manganese mg/kg 215 11.9 12.3 206 254 -82 313 75-125 21 20 M6,R1 Molybdenum mg/kg ND 11.9 12.3 7.8 8.2 64 65 75-125 5 20 M1 Nickel mg/kg 3.3 11.9 12.3 14.6 14.2 95 89 75-125 3 20 Potassium mg/kg 372 595 614 886 851 86 78 75-125 4 20 Sodium mg/kg ND 595 614 731 652 114 97 75-125 11 20 Strontium mg/kg 1.8 11.9 12.3 13.6 13.5 99 95 75-125 0 20 Zinc mg/kg 10.7 59.5 61.4 65.8 67.7 93 93 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 64 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15020201 Pace Project No.: 92236923 Pace Analytical Services, Inc. P3690 �irwy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QC Batch: MPRP/22646 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92236923001, 92236923002, 92236923003, 92236923004, 92236923005, 92236923006, 92236923007, 92236923008,92236923009,92236923010 METHOD BLANK: 1128079 Matrix: Solid Associated Lab Samples: 92236923001, 92236923002, 92236923003, 92236923004, 92236923005, 92236923006, 92236923007, 92236923008,92236923009,92236923010 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1128080 Units Spike Conc. LCS Result LCS % Rec Antimony mg/kg ND 0.053 02/16/1515:24 N2 Arsenic mg/kg ND 0.053 02/16/1515:24 Beryllium mg/kg ND 0.0063 02/16/1515:24 Cadmium mg/kg ND 0.0063 02/16/1515:24 Cobalt mg/kg ND 0.053 02/16/1515:24 Lead mg/kg ND 0.053 02/16/1515:24 Selenium mg/kg ND 0.053 02/16/1515:24 Thallium mg/kg ND 0.053 02/16/1515:24 Vanadium mg/kg ND 0.053 02/16/1515:24 LABORATORY CONTROL SAMPLE: Parameter 1128080 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.4 99 80-120 N2 Arsenic mg/kg 2.5 2.5 101 80-120 Beryllium mg/kg .25 0.26 104 80-120 Cadmium mg/kg .25 0.24 96 80-120 Cobalt mg/kg 2.5 2.5 102 80-120 Lead mg/kg 2.5 2.5 101 80-120 Selenium mg/kg 2.5 2.6 106 80-120 Thallium mg/kg 2.5 2.5 100 80-120 Vanadium mg/kg 2.5 2.4 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1128081 92236923002 Parameter Units Result MS Spike Conc. MSD Spike Conc. 1128082 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qua] Antimony mg/kg ND 2.6 2.4 0.60J 0.55J 22 22 75-125 20 D3,M6, N2 Arsenic mg/kg ND 2.6 2.4 2.3J 2.2J 44 43 75-125 20 D3,M6 Beryllium mg/kg 0.89 .26 .24 1.0 1.1 46 84 75-125 8 20 D3,M6 Cadmium mg/kg ND .26 .24 0.37 0.24J 129 85 75-125 20 D3,M6 Cobalt mg/kg 9.4 2.6 2.4 11.7 11.2 90 77 75-125 4 20 D3 Lead mg/kg 12.2 2.6 2.4 13.7 14.4 56 90 75-125 5 20 D3,M6 Selenium mg/kg 2AJ 2.6 2.4 3.7 3.6 50 49 75-125 2 20 D3,M6 Thallium mg/kg ND 2.6 2.4 2.8 2.7 89 92 75-125 3 20 D3 Vanadium mg/kg 48.7 2.6 2.4 45.6 47.0 -120 -71 75-125 3 20 D4,M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 65 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15020201 Pace Project No.: 92236923 QC Batch: MPRP/52897 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92236923012 METHOD BLANK: 1916229 Associated Lab Samples: 92236923012 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 03/12/1515:35 ND 0.50 03/12/1515:35 ND 0.50 03/12/1515:35 ND 0.30 03/12/1515:35 ND 0.20 03/12/1515:35 ND 5.0 03/12/1515:35 ND 0.080 03/12/1515:35 ND 40.0 03/12/1515:35 ND 0.50 03/12/1515:35 ND 0.50 03/12/1515:35 ND 1.0 03/12/1515:35 ND 50.0 03/12/1515:35 ND 0.10 03/12/1515:35 ND 10.0 03/12/1515:35 ND 0.50 03/12/1515:35 ND 0.50 03/12/1515:35 ND 0.50 03/12/1515:35 ND 50.0 03/12/1515:35 ND 0.50 03/12/1515:35 ND 50.0 03/12/1515:35 ND 0.50 03/12/1515:35 ND 0.10 03/12/1515:35 ND 1.0 03/12/1515:35 ND 5.0 03/12/1515:35 Qualifiers Pace Analytical Services, Inc. P3690 �irwY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1916230 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 79.2 99 80-120 Antimony ug/L 80 82.0 103 80-120 Arsenic ug/L 80 82.2 103 80-120 Barium ug/L 80 83.3 104 80-120 Beryllium ug/L 80 79.7 100 80-120 Boron ug/L 80 82.0 102 80-120 Cadmium ug/L 80 84.3 105 80-120 Calcium ug/L 1000 1070 107 80-120 Chromium ug/L 80 84.2 105 80-120 Cobalt ug/L 80 87.8 110 80-120 Copper ug/L 80 84.1 105 80-120 Iron ug/L 1000 1060 106 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 66 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. PW%Vwyd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 LABORATORY CONTROL SAMPLE: 1916230 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 85.1 106 80-120 Magnesium ug/L 1000 1020 102 80-120 Manganese ug/L 80 88.5 111 80-120 Molybdenum ug/L 80 88.3 110 80-120 Nickel ug/L 80 88.3 110 80-120 Potassium ug/L 1000 1040 104 80-120 Selenium ug/L 80 84.6 106 80-120 Sodium ug/L 1000 1040 104 80-120 Strontium ug/L 80 82.6 103 80-120 Thallium ug/L 80 91.4 114 80-120 Vanadium ug/L 80 87.4 109 80-120 Zinc ug/L 80 80.3 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1916665 1916666 MS MSD 92239540010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 44.7 80 80 142 147 121 128 75-125 4 20 M1 Antimony ug/L ND 80 80 83.1 82.4 104 103 75-125 1 20 Arsenic ug/L ND 80 80 81.0 81.8 101 102 75-125 1 20 Barium ug/L 3.8 80 80 84.2 85.7 100 102 75-125 2 20 Beryllium ug/L ND 80 80 81.0 78.8 101 98 75-125 3 20 Boron ug/L ND 80 80 93.8 87.2 112 103 75-125 7 20 Cadmium ug/L ND 80 80 84.8 85.2 106 107 75-125 0 20 Calcium ug/L 3900 1000 1000 5040 5150 114 125 75-125 2 20 Chromium ug/L 4.2 80 80 87.0 87.7 103 104 75-125 1 20 Cobalt ug/L ND 80 80 84.3 85.0 105 106 75-125 1 20 Copper ug/L 2.0 80 80 84.9 86.0 104 105 75-125 1 20 Iron ug/L 404 1000 1000 1470 1500 107 110 75-125 2 20 Lead ug/L 0.47 80 80 85.4 85.8 106 107 75-125 1 20 Magnesium ug/L 229 1000 1000 1240 1280 101 105 75-125 3 20 Manganese ug/L 8.0 80 80 96.7 98.5 111 113 75-125 2 20 Molybdenum ug/L 1.5 80 80 87.8 88.9 108 109 75-125 1 20 Nickel ug/L ND 80 80 88.0 89.1 109 111 75-125 1 20 Potassium ug/L 1290 1000 1000 2370 2400 108 111 75-125 1 20 Selenium ug/L ND 80 80 85.3 83.7 106 104 75-125 2 20 Sodium ug/L 3180 1000 1000 4250 4390 108 121 75-125 3 20 Strontium ug/L 21.4 80 80 103 104 102 104 75-125 2 20 Thallium ug/L ND 80 80 87.8 87.5 110 109 75-125 0 20 Vanadium ug/L 1.8 80 80 88.9 90.1 109 110 75-125 1 20 Zinc ug/L 5.1 80 80 84.9 85.8 100 101 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 67 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15020201 Pace Project No.: 92236923 QC Batch: MPRP/52931 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92236923011, 92236923013 METHOD BLANK: 1917520 Associated Lab Samples: 92236923011, 92236923013 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 03/16/15 09:43 ND 0.50 03/16/15 09:43 ND 0.50 03/16/15 09:43 ND 0.30 03/16/15 09:43 ND 0.20 03/16/15 09:43 ND 5.0 03/16/15 09:43 ND 0.080 03/16/15 09:43 ND 40.0 03/16/15 09:43 ND 0.50 03/16/15 09:43 ND 0.50 03/16/15 09:43 ND 1.0 03/16/15 09:43 ND 50.0 03/16/15 09:43 ND 0.10 03/16/15 09:43 ND 10.0 03/16/15 09:43 ND 0.50 03/16/15 09:43 ND 0.50 03/16/15 09:43 ND 0.50 03/16/15 09:43 ND 50.0 03/16/15 09:43 ND 0.50 03/16/15 09:43 ND 50.0 03/16/15 09:43 ND 0.50 03/16/15 09:43 ND 0.10 03/16/15 09:43 ND 1.0 03/16/15 09:43 ND 5.0 03/16/15 09:43 Qualifiers Pace Analytical Services, Inc. P36gg8 pyo".. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1917521 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 76.9 96 80-120 Antimony ug/L 80 79.4 99 80-120 Arsenic ug/L 80 79.0 99 80-120 Barium ug/L 80 80.7 101 80-120 Beryllium ug/L 80 82.8 104 80-120 Boron ug/L 80 81.1 101 80-120 Cadmium ug/L 80 80.0 100 80-120 Calcium ug/L 1000 1000 100 80-120 Chromium ug/L 80 79.9 100 80-120 Cobalt ug/L 80 80.8 101 80-120 Copper ug/L 80 77.4 97 80-120 Iron ug/L 1000 1040 104 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 68 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. PW%Ywyd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 LABORATORY CONTROL SAMPLE: 1917521 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 80.9 101 80-120 Magnesium ug/L 1000 1010 101 80-120 Manganese ug/L 80 80.3 100 80-120 Molybdenum ug/L 80 79.5 99 80-120 Nickel ug/L 80 80.4 100 80-120 Potassium ug/L 1000 1040 104 80-120 Selenium ug/L 80 80.6 101 80-120 Sodium ug/L 1000 988 99 80-120 Strontium ug/L 80 79.6 100 80-120 Thallium ug/L 80 79.1 99 80-120 Vanadium ug/L 80 80.6 101 80-120 Zinc ug/L 80 78.9 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1917522 1917523 MS MSD 92240320006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 168 80 80 359 387 238 274 75-125 8 20 M1 Antimony ug/L ND 80 80 80.9 78.9 101 98 75-125 3 20 Arsenic ug/L ND 80 80 79.9 78.5 100 98 75-125 2 20 Barium ug/L 20.0 80 80 103 101 104 101 75-125 2 20 Beryllium ug/L ND 80 80 84.1 85.0 105 106 75-125 1 20 Boron ug/L 138 80 80 232 231 117 117 75-125 0 20 Cadmium ug/L ND 80 80 81.1 79.6 101 100 75-125 2 20 Calcium ug/L 7460 1000 1000 8970 8670 151 122 75-125 3 20 M1 Chromium ug/L ND 80 80 81.4 80.3 101 100 75-125 1 20 Cobalt ug/L ND 80 80 82.7 81.1 103 101 75-125 2 20 Copper ug/L ND 80 80 79.8 79.0 99 98 75-125 1 20 Iron ug/L 499 1000 1000 1630 1630 113 113 75-125 0 20 Lead ug/L 0.29 80 80 82.3 81.8 103 102 75-125 1 20 Magnesium ug/L 2720 1000 1000 3910 3840 118 112 75-125 2 20 Manganese ug/L 39.8 80 80 123 121 104 102 75-125 2 20 Molybdenum ug/L ND 80 80 81.1 79.4 101 99 75-125 2 20 Nickel ug/L ND 80 80 82.1 80.0 102 100 75-125 3 20 Potassium ug/L 1470 1000 1000 2640 2570 117 110 75-125 3 20 Selenium ug/L ND 80 80 81.8 80.9 102 101 75-125 1 20 Sodium ug/L 5770 1000 1000 7190 7000 142 123 75-125 3 20 M1 Strontium ug/L 47.2 80 80 130 127 103 100 75-125 2 20 Thallium ug/L ND 80 80 83.1 82.3 104 103 75-125 1 20 Vanadium ug/L ND 80 80 83.2 82.7 103 102 75-125 1 20 Zinc ug/L ND 80 80 84.2 84.6 103 104 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 69 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15020201 Pace Project No.: 92236923 Pace Analytical Services, Inc. P3Sy Mr6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: PMST/10947 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92236923001, 92236923002, 92236923003, 92236923005, 92236923006, 92236923007, 92236923008, 92236923009,92236923010 SAMPLE DUPLICATE: 1124935 40111307022 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 12.7 13.0 3 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 70 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15020201 Pace Project No.: 92236923 QC Batch: PMST/10951 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92236923004 Pace Analytical Services, Inc. P 3 M,r6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1125151 40111309001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 19.0 18.4 3 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 71 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15020201 Pace Project No.: 92236923 Pace Analytical Services, Inc. P3Sy Mr6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: WET/35633 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92236923001,92236923002,92236923003,92236923004,92236923005,92236923006,92236923007 SAMPLE DUPLICATE: 1387791 92236923001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.9 7.2 4 10 SAMPLE DUPLICATE: 1387792 92236749027 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.7 6.5 4 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 72 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15020201 Pace Project No.: 92236923 QC Batch: WET/35670 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92236923008, 92236923009, 92236923010 Pace Analytical Services, Inc. PWVrwyd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1388982 92236923008 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.1 6.0 2 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 73 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. PARV,Wyd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 QC Batch: WETA/21996 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92236923006, 92236923007, 92236923008 METHOD BLANK: 1395953 Matrix: Water Associated Lab Samples: 92236923006, 92236923007, 92236923008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L ND 2.0 02/25/1515:12 LABORATORY CONTROL SAMPLE: 1395954 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.3 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1395955 1395956 MS MSD 92236749024 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 2.OJ 24.5 24.5 24.1 23.8 90 89 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1396814 1396815 MS MSD 92236749023 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 1.4J 21.3 21.3 21.6 21.9 95 96 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 74 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P36919rwyd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 QC Batch: WETA/21986 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92236923006, 92236923008 METHOD BLANK: 1395834 Matrix: Water Associated Lab Samples: 92236923006, 92236923008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.020 02/20/15 21:30 LABORATORY CONTROL SAMPLE: 1395835 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1395836 1395837 MS MSD 92236923006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 3.1 3.1 3.0 3.0 96 96 90-110 0 10 P4 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 75 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P3Sy Mr6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 QC Batch: WETA/22038 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92236923007 METHOD BLANK: 1398816 Matrix: Water Associated Lab Samples: 92236923007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.020 02/26/15 18:12 LABORATORY CONTROL SAMPLE: 1398817 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.6 105 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1398818 1398819 MS MSD 92236923007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 3.3 3.3 3.4 3.4 98 98 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 76 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. PARVrwy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 QC Batch: WETA/21988 Analysis Method: SM 4500 -CI -E QC Batch Method: SM 4500 -CI -E Analysis Description: 4500 Chloride Associated Lab Samples: 92236923006, 92236923008 METHOD BLANK: 1395841 Matrix: Water Associated Lab Samples: 92236923006, 92236923008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 02/21/15 01:58 LABORATORY CONTROL SAMPLE: 1395842 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.6 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1395843 1395844 MS MSD 92236749030 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L 2.9J 22.2 22.2 25.4 25.0 101 99 90-110 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 77 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P36gmirpyo"�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 QC Batch: WETA/22044 Analysis Method: SM 4500 -CI -E QC Batch Method: SM 4500 -CI -E Analysis Description: 4500 Chloride Associated Lab Samples: 92236923007 METHOD BLANK: 1398870 Matrix: Water Associated Lab Samples: 92236923007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 02/27/15 02:38 LABORATORY CONTROL SAMPLE: 1398871 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.3 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1398872 1398873 MS MSD 92236923007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 26.2 26.2 27.3 27.0 98 97 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 78 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15020201 Pace Project No.: 92236923 Pace Analytical Services, Inc. P 3 906r6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: WETA/43576 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92236923001, 92236923002, 92236923003, 92236923004, 92236923005, 92236923006, 92236923007, 92236923008,92236923009,92236923010 METHOD BLANK: 1128888 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.9 02/13/15 04:05 Sulfate mg/kg ND 49.9 02/13/15 04:05 LABORATORY CONTROL SAMPLE: 1128889 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1128891 Parameter Units Chloride mg/kg Sulfate mg/kg Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 499 535 107 80-120 499 530 106 80-120 92236923001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 495 446 73 80-120 M1 ND 495 487 81 80-120 SAMPLE DUPLICATE: 1128890 92236923001 Dup Parameter Units Result Result Chloride mg/kg ND ND Sulfate mg/kg ND ND Max RPD RPD Qualifiers 20 D3 20 D3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 79 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P 3 906r6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 QC Batch: WETA/43575 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92236923001, 92236923002, 92236923003, 92236923004, 92236923005, 92236923006, 92236923007, 92236923008,92236923009,92236923010 METHOD BLANK: 1128882 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 02/13/15 04:05 LABORATORY CONTROL SAMPLE: 1128885 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.9 54.7 110 80-120 MATRIX SPIKE SAMPLE: 1128887 92236923001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 49.5 46.5 92 80-120 H3 SAMPLE DUPLICATE: 1128886 92236923001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 80 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P 3 90A,16fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020201 Pace Project No.: 92236923 QC Batch: WETA/27275 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92236923001, 92236923002, 92236923003, 92236923004, 92236923005, 92236923006, 92236923007, 92236923008,92236923009,92236923010 METHOD BLANK: 1118643 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 02/18/15 07:14 LABORATORY CONTROL SAMPLE: 1118644 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 121000 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1118645 1118646 MS MSD 92236923001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 4470 11500 11500 16000 16100 100 101 50-150 1 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1118647 1118648 MS MSD 92236749021 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 685 6690 6710 7260 7050 98 95 50-150 3 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 81 of 88 aceAnaiXical www.pacelabs.com QUALIFIERS Project: J15020201 Pace Project No.: 92236923 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. Pace Analytical Services, Inc. P 3 90Ar6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach SAMPLE QUALIFIERS Sample: 92236923007 [1] Insufficient sample received from client to perform the analysis per EPA requirements. ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D4 Sample was diluted due to the presence of high levels of target analytes. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 82 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P 3 90Ar6fYd�e. Suite 100 Huntersville, INC 28078 (704)875-9092 QUALIFIERS Project: J15020201 Pace Project No.: 92236923 ANALYTE QUALIFIERS P4 Sample field preservation does not meet EPA or method recommendations for this analysis. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 83 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, Inc. P 3 900r6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15020201 92236923 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92236923001 2015003284 EPA 3050 MPRP/22645 EPA 6010 ICP/13856 92236923002 2015003285 EPA 3050 MPRP/22645 EPA 6010 ICP/13856 92236923003 2015003286 EPA 3050 MPRP/22645 EPA 6010 ICP/13856 92236923004 2015003287 EPA 3050 MPRP/22645 EPA 6010 ICP/13856 92236923005 2015003288 EPA 3050 MPRP/22645 EPA 6010 ICP/13856 92236923006 2015003289 EPA 3050 MPRP/22645 EPA6010 ICP/13856 92236923007 2015003291 EPA 3050 MPRP/22645 EPA 6010 ICP/13856 92236923008 2015003293 EPA 3050 MPRP/22645 EPA 6010 ICP/13856 92236923009 2015003290 EPA 3050 MPRP/22645 EPA 6010 ICP/13856 92236923010 2015003292 EPA 3050 MPRP/22645 EPA 6010 ICP/13856 92236923001 2015003284 EPA 3050 MPRP/22646 EPA 6020 ICPM/9250 92236923002 2015003285 EPA 3050 MPRP/22646 EPA 6020 ICPM/9250 92236923003 2015003286 EPA 3050 MPRP/22646 EPA 6020 ICPM/9250 92236923004 2015003287 EPA 3050 MPRP/22646 EPA 6020 ICPM/9250 92236923005 2015003288 EPA 3050 MPRP/22646 EPA 6020 ICPM/9250 92236923006 2015003289 EPA 3050 MPRP/22646 EPA 6020 ICPM/9250 92236923007 2015003291 EPA 3050 MPRP/22646 EPA 6020 ICPM/9250 92236923008 2015003293 EPA 3050 MPRP/22646 EPA 6020 ICPM/9250 92236923009 2015003290 EPA 3050 MPRP/22646 EPA 6020 ICPM/9250 92236923010 2015003292 EPA 3050 MPRP/22646 EPA 6020 ICPM/9250 92236923011 2015003289 SPLP METALS EPA 3020 MPRP/52931 EPA 6020A ICPM/23462 92236923012 2015003291 SPLP METALS EPA 3020 MPRP/52897 EPA 6020A ICPM/23451 92236923013 2015003293 SPLP METALS EPA 3020 MPRP/52931 EPA 6020A ICPM/23462 92236923011 2015003289 SPLP METALS EPA 7470 MERP/12953 EPA 7470 MERC/15027 92236923012 2015003291 SPLP METALS EPA 7470 MERP/12942 EPA 7470 MERC/15022 92236923013 2015003293 SPLP METALS EPA 7470 MERP/12953 EPA 7470 MERC/15027 92236923001 2015003284 EPA 7471 MERP/5372 EPA 7471 MERC/5363 92236923002 2015003285 EPA 7471 MERP/5372 EPA 7471 MERC/5363 92236923003 2015003286 EPA 7471 MERP/5372 EPA 7471 MERC/5363 92236923004 2015003287 EPA 7471 MERP/5372 EPA 7471 MERC/5363 92236923005 2015003288 EPA 7471 MERP/5372 EPA 7471 MERC/5363 92236923006 2015003289 EPA 7471 MERP/5372 EPA 7471 MERC/5363 92236923007 2015003291 EPA 7471 MERP/5372 EPA 7471 MERC/5363 92236923008 2015003293 EPA 7471 MERP/5372 EPA 7471 MERC/5363 92236923009 2015003290 EPA 7471 MERP/5372 EPA 7471 MERC/5363 92236923010 2015003292 EPA 7471 MERP/5372 EPA 7471 MERC/5363 92236923001 2015003284 ASTM D2974-87 PMST/10947 92236923002 2015003285 ASTM D2974-87 PMST/10947 92236923003 2015003286 ASTM D2974-87 PMST/10947 92236923004 2015003287 ASTM D2974-87 PMST/10951 92236923005 2015003288 ASTM D2974-87 PMST/10947 92236923006 2015003289 ASTM D2974-87 PMST/10947 92236923007 2015003291 ASTM D2974-87 PMST/10947 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Page 84 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15020201 Pace Project No.: 92236923 Lab ID Sample ID QC Batch Method QC Batch 92236923008 2015003293 ASTM D2974-87 PMST/10947 92236923009 2015003290 ASTM D2974-87 PMST/10947 92236923010 2015003292 ASTM D2974-87 PMST/10947 92236923001 2015003284 EPA 9045 WET/35633 92236923002 2015003285 EPA 9045 WET/35633 92236923003 2015003286 EPA 9045 WET/35633 92236923004 2015003287 EPA 9045 WET/35633 92236923005 2015003288 EPA 9045 WET/35633 92236923006 2015003289 EPA 9045 WET/35633 92236923007 2015003291 EPA 9045 WET/35633 92236923008 2015003293 EPA 9045 WET/35670 92236923009 2015003290 EPA 9045 WET/35670 92236923010 2015003292 EPA 9045 WET/35670 92236923006 2015003289 EPA 300.0 WETA/21996 92236923007 2015003291 EPA 300.0 WETA/21996 92236923008 2015003293 EPA 300.0 WETA/21996 92236923006 2015003289 EPA 353.2 WETA/21986 92236923007 2015003291 EPA 353.2 WETA/22038 92236923008 2015003293 EPA 353.2 WETA/21986 92236923006 2015003289 SM 4500 -CI -E WETA/21988 92236923007 2015003291 SM 4500 -CI -E WETA/22044 92236923008 2015003293 SM 4500 -CI -E WETA/21988 92236923001 2015003284 EPA 9056 WETA/43576 92236923002 2015003285 EPA 9056 WETA/43576 92236923003 2015003286 EPA 9056 WETA/43576 92236923004 2015003287 EPA 9056 WETA/43576 92236923005 2015003288 EPA 9056 WETA/43576 92236923006 2015003289 EPA 9056 WETA/43576 92236923007 2015003291 EPA 9056 WETA/43576 92236923008 2015003293 EPA 9056 WETA/43576 92236923009 2015003290 EPA 9056 WETA/43576 92236923010 2015003292 EPA 9056 WETA/43576 92236923001 2015003284 EPA 9056 WETA/43575 92236923002 2015003285 EPA 9056 WETA/43575 92236923003 2015003286 EPA 9056 WETA/43575 92236923004 2015003287 EPA 9056 WETA/43575 92236923005 2015003288 EPA 9056 WETA/43575 92236923006 2015003289 EPA 9056 WETA/43575 92236923007 2015003291 EPA 9056 WETA/43575 92236923008 2015003293 EPA 9056 WETA/43575 92236923009 2015003290 EPA 9056 WETA/43575 92236923010 2015003292 EPA 9056 WETA/43575 92236923001 2015003284 EPA 9060 WETA/27275 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:29 AM without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. PWVrwyd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical Analytical Method Batch Page 85 of 88 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15020201 Pace Project No.: 92236923 Lab ID Sample ID QC Batch Method QC Batch 92236923001 2015003284 EPA 9060 WETA/27276 92236923002 2015003285 EPA 9060 WETA/27275 92236923002 2015003285 EPA 9060 WETA/27276 92236923003 2015003286 EPA 9060 WETA/27275 92236923003 2015003286 EPA 9060 WETA/27276 92236923004 2015003287 EPA 9060 WETA/27275 92236923004 2015003287 EPA 9060 WETA/27276 92236923005 2015003288 EPA 9060 WETA/27275 92236923005 2015003288 EPA 9060 WETA/27276 92236923006 2015003289 EPA 9060 WETA/27275 92236923006 2015003289 EPA 9060 WETA/27276 92236923007 2015003291 EPA 9060 WETA/27275 92236923007 2015003291 EPA 9060 WETA/27276 92236923008 2015003293 EPA 9060 WETA/27275 92236923008 2015003293 EPA 9060 WETA/27276 92236923009 2015003290 EPA 9060 WETA/27275 92236923009 2015003290 EPA 9060 WETA/27276 92236923010 2015003292 EPA 9060 WETA/27275 92236923010 2015003292 EPA 9060 WETA/27276 Date: 03/18/2015 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. P 3 906r6fYd�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical Method Analytical Batch Page 86 of 88 (7�1 CIO A11,11) 01 Document Name: uocument rtevisea: zseptemuer zz. `u iE+ Condition Upon Receipt (SCUR) Pae 1 of 2 Document Number: Issuing AuN0 of 102 F-CHR-CS-003-rev.15 Pace Huntersville Quality Office Client Name: 'poi4e, -- f Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑ Commercial❑ (15ab—e�) Other Custody Sea[ on CoolerlBox Present: ❑ yes �_n2i Seals intact: ❑ yes ❑ no Packing Material: ❑ Bubble'VDp �[]jE ul e Fags ❑ None ❑ Other �,� Thermometer Used: IR Gun 14 1" f `' Type of Ice t Blue None E� Samples on ice, cooling process has begun Tamn rnrrarfinn Fartnr T1401 No Correction �y •C Biological Tissue is Frozen: Yes No IA Date and Initials of person examining `l Corrected Cooler Temp: contents: S Temp should be above freezing to VC Comments: Chain of Custody Present: "s LINO 11 N/A 1. Chain of Custody Filled Out: MYes ❑No ONIA 2. Chain of Custody Relinquished: lv3ires ONO 11 NIA 3. Sampler Name & Signature on COC: IiYes ONO EINIA 4. Samples Arrived within Mold Time: (S es ONO ❑NIA 5. Short Hold Time Analysis (<72hr): DYes (QKo DNIA 6. Rush Turn Around Time Requested: ❑Yes 1040 ❑NIA 7. Sufficient Volume: `Q(yes ❑No DN/A 8. Correct Containers Used: 'LiKes ONO ❑NIA 9. -Pace Containers Used: DYGsV&o ONIA Containers Intact: 'UJYes LINO F1 NIA 10. Filtered volume received for Dissolved tests DYes ❑No '(NIA 11. Sample Labels match COC: Yes ONO ❑NIA 12. -Includes date/llmellt]IAnalysis Matrix: All containers needing preservation have been checked. DYes LINONNIA 13. All containers needing preservation are found to be in DYes ONO QNIA compliance with EPA recommendation. ❑Yes 61' 1 exceptions: VOA, coliform, TQC, 4&G,1WDRO (water) Samples checked for dechlorination: OYes ONO 14. Headspace in VOA Vials (>6mm): DYes ONO �/1A [F NIA 15. Trip Blank Present: ❑Yes ONO 15KIA 16. Trip Blank Custody Seals Present DYes DNo KA/A Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Field Data Required? Person Contacted: Daterfime: Comments/ Resolution: SCURF Review: Date: I a67ttS SRF Review Date:2 (.p IS Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ([.e out of hold, incorrect preservative, out of temp, incorrect containers) Wpg:92236923 1111 yiiiiiim11111111 Y 1 N Page 87 of 88 n n 0 Page 101 of 102 Customer must Complete _ o n M p�AR u d ILI rs 3I caO �-' ® "l �T'D 7 A:� ! T m 3 xa>s s1 1 i 25. �^5 D rb n � � i r nIL fD ! c O F 1 ndn j"m a3 Irl' A N ID '13 M Page 101 of 102 Customer must Complete _ o n "Comp. t#yY l1°Grab Rre Total Metals (PACtf Anions (PAGE) pH (PACE) SPLP - Total Metals and Anions (PACE) Sediment specific tests (Access 7f dotal 9 of Containers Ok � © d M p�AR u "►ti ILI rs 3I caO ® In n �T'D 7 A:� ! T m 3 xa>s s1 1 i 25. �^5 D rb n � � i r nIL fD ! c O F 1 ndn j"m a3 Irl' A N ID '13 M 0 Y a .n. n N ; y j 1 i g lio 1, i Q I on0 $ \ ! i i s M G• n ! I NJ ° } O !lRJ b sNi � ,�a �. f z g ! "Comp. t#yY l1°Grab Rre Total Metals (PACtf Anions (PAGE) pH (PACE) SPLP - Total Metals and Anions (PACE) Sediment specific tests (Access 7f dotal 9 of Containers Ok � © d I M t i Z Oix I 3I caO A� fl! �T'D 7 A:� ! T m 3 xa>s s1 1 i 25. �^5 D y ! 1 n � � i r nIL fD ! c O F 1 ndn j"m a3 Irl' A N rj O CrI��Jy L f "j 0 Y a z I aA7 w1(n j 1 i g lio 1, i I on0 $ \ ! i i s M 1 ! I NJ ° } O !lRJ 1 1 C7 f z I ! 00 ! bl� d It'i �y 9 0 $ v ? �.�� '• riin ao It ;V(w 3 "ll a! n r r a;rr� y C] O 1 5 2i 33 c i In +yDii► 5 a a 01' 5 0 I s KZZ t i ix Sm° Oix I 3I _ "._ I,_. _.� rn _. 0 NJ 00 z1 1 M o D W $ V� 0 Y �1 rn z R ^� j 1 So 1, Page 88 of 88 CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM i� Y`� �i= T' Ashevlbeq L I'� Caole'T Tem naly0cal Laboratory Servieall i i i Analytical Labor'&t Lla@ on i r■w i tft� V UKEAL P 1142091 I w t»r Ka raft MG03A2 {ttltlW"O 7Ai461 !. ., Rd ` raemr_ FA2& NC t:. CT1W W of 4 I pl� fl ENER �/ M 13 54 FIYlgere teary P1uM 4WD 276 b21b26g79 { I I i4A'➢O�rri In 4rorr — SAMPLE PR08RA41 Crai.n�'�h'al�� I ORIGINAL. i/fOIl�aYhlgL. to LAB, COPY to Cl II-N� +' ?+d mark MCIDNW. $yrlfitn"i 4=Ice 6=Noe L .1] Lia Fe �: f-994a1J &T6h3+1� .--------o.-J `t Il18u9V14S►Yllre: MPdES-_ Ti1iaS CaNI I iGroundwailer Assessment - So11 '2)'n rw: PA6 ACE �' UIPe _ pl.nY_ i Y REV DATE irasr iy i� Y`� �i= T' Ashevlbeq L I'� Caole'T Tem c __ k Lk / 1a ,�. 1 37C16re�S John Tnepfer, Clk*lt .ijiaR Mi P 1142091 I In 1 c7 mark MCIDNW. $yrlfitn"i 4=Ice 6=Noe Ml3 .1] Lia yG Il18u9V14S►Yllre: iiP'neol D. ACiJILI= � 4�Q� Ti1iaS CaNI "° 11+o ItY®: Iplpr�gena� !^GI�`51 BjkL 2 'gmlmints all Si$Sr�aB I - I i r3penNigY UN< t AEOO'•r'PPt5r5frJr5 dNSM Qi _ tC � i at -it When apee8le gCmunling nem Leen 4"tDhlls14ed Ind Is not inUic-ated abnwe P�reserwallwes when used mull be � UetairMew,�. 10 LL) _ '_ p- rr+ we nM need 1f0IW1Mng: I I f=rller cce;act mccO enYing YrY dill 4c aaunNYrp YMAWR 2b0".. O added within 15 m inuler of sample rialii,iiuli9ln 0 # UL lt! S m 44 4) 0 23 ptmvIck etgrert ercauntir !qf 9 mtin UnLt end PYoceSa l'o- coll-eetlon _ Y `•LM USE ONLM+C Mulrpo "Ccalllactlon Infotination --- - a i'Sarrr � � .0 Z fl t -Loe1a ; �1%4A. 9"IrPmrrL AIM le areacr -tion or I� olFIY 1� S� *� i� Y`� �i= T' — �1; ��tl.? .�� �- %•e �, 17.17- I, sa 9K` I1 1,7` f`rhip�l' i tlg C L I'� rl� Ifo_ 11TO rte' + X_ - - - lti. x - - - __ k Lk / 1a ,�. 1 1 c7 - I - I I - I i -- - - - 211wrlluqu�incd aY•. Roln9�"*rwi Ry- JJ l� NelelTilmY ,� �. Y3atiF71ner - Piee ,f.;r� � UetairMew,�. 5 5 ,. '��Requei5ted Turnarourr(i I.9 I7ey6 x—. Attopai6 -_ r� 3Q rialii,iiuli9ln '4F" +7 Days # SYalQiVL orka• 1194 Sa■ _ '48 Hr 24)Camm.nr� Metals: Alt Sbr AS, 4ts. Be, B• C.A. Car Cr, Co. Cur Fe, Pb, Mg, yam- Se,. V. 2n. IIMIiGU