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HomeMy WebLinkAboutNC0005088_3_FINAL_CSA Supplement 2_Tables_20160808Table 1-1: Well Construction Information Well • AB -1D Deep ft 545332.08 ft 1179466.53 • ft btoc 773.44 ft -0.29 Casing Type PVC in 4.0 ... :.Total ft btoc 121.21 ft btoc 126.21 Depth ft btoc 135.21 Program CAMA AB -1S Shallow 545330.77 1179457.78 773.19 -0.61 PVC 2.0 53.39 68.39 108.39 CAMA AB -2D Deep 544298.96 1177102.27 773.00 -0.47 PVC 5.0 72.03 77.03 80.03 CAMA AB -2S Shallow 544305.19 1177106.20 772.92 -0.61 PVC 2.0 43.39 48.39 48.39 CAMA AB-3BR Bedrock 543931.26 1178015.85 796.55 3.14 PVC 6.0 178.64 188.64 190.14 CAMA AB-3BRU Deep 543946.27 1178033.57 795.78 1.97 PVC 5.0 119.97 124.97 132.47 CAMA AB -31 Shallow 543941.37 1178027.86 795.97 2.25 PVC 2.0 94.25 104.25 107.25 CAMA AB -3S Shallow 543959.27 1178050.31 795.64 1.87 PVC 2.0 23.87 38.87 38.87 CAMA AB-3SL Shallow 543953.91 1178043.47 796.02 3.02 PVC 2.0 65.22 75.22 75.22 CAMA AB-4BR Bedrock 543722.93 1178887.51 770.66 2.10 PVC 6.0 106.60 111.60 122.70 CAMA AB -413 Deep 543723.87 1178896.54 770.59 2.05 PVC 6.0 57.05 62.05 72.45 CAMA AB -4S Shallow 543721.76 1178877.73 770.59 2.08 PVC 2.0 7.08 22.08 22.38 CAMA AB-4SL Shallow 543721.09 1178871.93 770.61 2.10 PVC 2.0 27.97 30.80 41.10 CAMA AB-5BR Bedrock 542961.78 1179103.52 772.13 3.03 PVC NR 94.23 99.13 117.00 CAMA AB-5BRU Deep 542963.70 1179112.82 771.81 2.00 PVC 5.0 62.50 67.50 70.20 CAMA AB -5S Shallow 542958.87 1179111.06 771.74 2.09 PVC 2.0 22.09 25.09 45.09 CAMA AB-6BR Bedrock 542716.60 1178350.92 770.61 2.00 PVC 5.0 98.00 103.00 112.50 CAMA AB -6D Deep 542709.35 1178397.12 770.68 2.05 PVC 5.0 67.85 72.85 78.55 CAMA AB -6S Shallow 542714.00 1178366.14 770.56 2.08 PVC 2.0 7.08 22.08 23.08 CAMA AS -1D Deep 544824.26 1177989.02 809.41 1.89 PVC 5.0 107.89 112.89 133.39 CAMA AS -1S Shallow 544826.09 1177983.86 809.20 2.20 PVC 2.0 85.20 100.20 102.20 CAMA AS -21) Deep 545499.30 1177801.35 697.26 1.83 PVC 5.0 56.83 61.83 70.13 CAMA AS -2S Shallow 545494.72 1177817.37 697.84 2.11 PVC 2.0 17.61 32.61 35.61 CAMA AS-3BRU Deep 545386.76 1178583.59 754.16 1.56 PVC 5.0 50.06 55.06 57.06 CAMA AS -41) Deep 544888.58 1178502.06 837.71 2.12 PVC 5.0 97.12 102.12 114.32 CAMA AS -4S Shallow 544893.77 1178495.92 837.49 1.79 PVC 2.0 86.19 96.19 96.79 CAMA AS-5BR Bedrock 545349.36 1178357.59 739.77 -0.13 PVC 5.0 74.97 79.97 119.77 CAMA AS-5BRU Deep 545349.10 1178362.70 740.45 -0.14 PVC 5.0 54.86 59.86 62.86 CAMA AS -5S Shallow 545349.81 1178351.05 739.72 -0.23 PVC 2.0 29.07 44.07 45.07 CAMA AS-6BR Bedrock 545108.97 1178477.25 817.89 1.90 PVC 5.0 155.00 160.00 187.60 CAMA AS -61) Deep 545101.08 1178487.30 818.30 1.13 PVC 5.0 124.13 129.13 136.63 CAMA AS -6S Shallow 545112.15 1178486.75 817.74 2.61 PVC 2.0 88.61 103.61 104.11 CAMA AS-7BR Bedrock 545161.83 1177998.47 742.70 2.41 PVC 5.0 124.41 129.41 144.51 CAMA AS -7D Deep 545161.95 1178002.80 742.90 2.13 PVC 5.0 84.63 89.63 94.63 CAMA AS -7S Shallow 545162.39 1177993.46 742.06 2.23 PVC 2.0 30.73 45.73 46.03 CAMA BG-1BR Bedrock 541369.47 1177169.46 802.50 1.70 PVC 5.0 93.70 98.70 112.10 CAMA BG -1D Deep 541371.23 1177162.64 802.63 1.79 PVC 6.0 68.29 73.29 78.79 CAMA BG -1S Shallow 541373.37 1177156.06 802.67 1.95 PVC 2.0 21.95 36.95 36.95 CAMA BG -2D Deep 543463.45 1171516.98 846.51 1.86 PVC 6.0 50.86 55.86 64.36 CAMA GWA-101) Deep 546338.87 1176427.09 679.74 -0.17 PVC 5.0 47.43 52.43 61.03 CAMA GWA-10S Shallow 546329.99 1176416.53 679.55 -0.17 PVC 2.0 11.83 26.83 28.83 CAMA Cliffside Steam Station Page 1 of 5 CSA Supplement 2 Table 1-1: Well Construction Information Monitoring Well • GWA-11BRU Monitonn��Northi Deep ng 546031.16 La sting ,• 1176972.33 674.99 0.01 Casing PVC 5.0 .. 37.01 42.01 Depth 45.11 Program CAMA GWA-11S Shallow 546035.96 1176967.86 674.98 -0.04 PVC 2.0 11.96 26.96 28.46 CAMA GWA-12BRU Deep 545469.36 1177265.70 719.66 1.71 PVC 5.0 49.71 54.71 61.61 CAMA GWA-12S Shallow 545473.23 1177268.05 719.40 1.81 PVC 2.0 20.81 35.81 36.81 CAMA GWA-13BR Bedrock 545131.60 1176624.21 724.12 -0.26 PVC 6.0 80.24 85.24 86.24 CAMA GWA-14D Deep 545444.81 1176393.21 712.52 -0.33 PVC 5.0 47.67 52.67 61.27 CAMA GWA-14S Shallow 545438.58 1176397.91 712.41 -0.30 PVC 2.0 21.00 36.00 37.70 CAMA GWA-1BRU Deep 544172.39 1171772.81 781.29 1.98 PVC 5.0 24.78 29.78 30.88 CAMA GWA-20D Deep 544359.26 1177009.95 736.24 2.21 PVC 5.0 27.21 32.21 40.71 CAMA GWA-20S Shallow 544365.78 1177012.53 736.13 2.27 PVC 2.0 6.77 21.77 21.77 CAMA GWA-21BR Bedrock 545690.80 1179245.36 672.98 2.35 PVC 5.0 62.95 67.95 70.35 CAMA GWA-21BRU Deep 545685.65 1179247.30 672.91 2.37 PVC 5.0 22.37 27.37 34.37 CAMA GWA-215 GWA-22D Shallow Deep 545686.38 545851.22 1179239.27 1180003.08 673.32 665.16 2.36 1.91 PVC PVC 2.0 6.0 7.86 18.91 17.86 23.91 18.16 30.91 CAMA CAMA GWA-22S Shallow 545851.42 1179998.61 665.19 1.93 PVC 2.0 4.53 14.53 14.93 CAMA GWA-23D Deep 544500.42 1180105.67 786.80 1.98 PVC 5.0 25.48 30.48 32.38 CAMA GWA-24BR Bedrock 543396.12 1179590.64 798.92 2.97 PVC 6.0 67.97 72.97 74.97 CAMA GWA-24D Deep 543416.75 1179608.58 794.94 2.11 PVC 5.0 30.11 35.11 42.51 CAMA GWA-245 Shallow 543416.96 1179599.95 794.47 2.08 PVC 2.0 16.08 26.08 26.58 CAMA GWA-25D Deep 541834.97 1178142.16 792.01 2.02 PVC 5.0 38.52 43.52 51.52 CAMA GWA-25S Shallow 541839.06 1178137.47 791.81 2.17 PVC 2.0 12.17 27.17 28.17 CAMA GWA-26D Deep 542464.26 1177888.15 782.98 1.80 PVC 5.0 70.40 75.60 87.80 CAMA GWA-26S Shallow 542467.12 1177879.86 783.36 1.93 PVC 2.0 12.13 27.13 28.43 CAMA GWA-27D-A Deep 543379.54 1177743.44 805.53 2.53 PVC 5.0 53.53 58.53 63.53 CAMA GWA-28BR Bedrock 545417.94 1178962.45 757.90 1.97 PVC 6.0 86.97 91.97 102.57 CAMA GWA-28BRU Deep 545412.27 1178963.41 758.35 1.99 PVC 5.0 55.89 60.89 62.89 CAMA GWA-285 Shallow 545417.20 1178968.54 757.74 1.79 PVC 2.0 24.29 39.29 40.29 CAMA GWA-29BR GWA-29D Bedrock Deep 545660.02 545661.19 1177541.87 1177536.39 679.38 679.56 1.58 1.80 PVC PVC 6.0 5.0 41.58 22.30 46.58 27.30 69.38 30.40 CAMA CAMA GWA-2BRU Deep 545297.33 1173057.26 685.35 2.09 PVC 5.0 34.49 39.49 45.49 CAMA GWA-2S Shallow 545302.41 1173057.42 685.56 2.22 PVC 2.0 8.22 23.22 24.22 CAMA GWA-30BR Bedrock 542781.71 1173642.64 806.90 1.89 PVC 5.0 66.89 71.89 82.39 CAMA GWA-30D Deep 542776.62 1173643.86 806.72 1.84 PVC 5.0 39.84 44.84 46.84 CAMA GWA-30S Shallow 542786.16 1173642.62 806.89 1.98 PVC 2.0 39.98 44.98 29.48 CAMA GWA-31BR Bedrock 544586.56 1174353.57 755.04 2.05 PVC 5.0 47.95 52.95 68.15 CAMA GWA-31BR-A Bedrock 544600.62 1174368.22 757.13 3.47 PVC 6.0 119.97 129.97 130.47 CAMA GWA-31D Deep 544590.13 1174359.77 754.89 2.00 PVC 5.0 12.40 17.40 23.80 CAMA GWA-32BR Bedrock 546973.12 1175046.67 698.56 1.98 PVC 5.0 61.98 66.98 97.28 CAMA GWA-32D Deep 546972.81 1175043.33 698.53 1.91 PVC 4.0 36.91 41.91 47.61 CAMA GWA-33BR Bedrock 544548.03 1176568.66 722.94 1.84 PVC 6.0 86.84 91.84 94.94 CAMA GWA-33D Deep 544542.77 1176568.78 722.88 1.77 PVC 6.0 27.77 32.77 34.77 CAMA Cliffside Steam Station Page 2 of 5 CSA Supplement 2 Table 1-1: Well Construction Information Monitoring Well • GWA-33S Shallow ft 544553.92 ft 1176568.35 • ft btoc 722.71 ft 1.90 Casing Type PVC in 2.0 :. ofINEENEwiottom ft btoc 6.90 of ft btoc 16.90 Total Depth ft btoc 18.40 Program CAMA GWA-34S Shallow 545058.04 1171545.44 715.88 3.33 PVC 2.0 17.63 32.63 33.33 CAMA GWA-35D Deep 545450.05 1172891.97 697.74 2.49 PVC 6.0 64.49 69.49 71.49 CAMA GWA-35S Shallow 545443.02 1172882.81 698.04 2.35 PVC 2.0 22.35 37.35 40.35 CAMA GWA-36D Deep 545365.46 1174228.18 710.53 3.01 PVC 6.0 86.01 91.01 99.01 CAMA GWA-36S Shallow 545361.74 1174231.06 710.53 2.73 PVC 2.0 9.73 24.73 24.73 CAMA GWA-37D Deep 545741.36 1174065.36 710.47 2.80 PVC 6.0 97.80 102.80 104.80 CAMA GWA-37S Shallow 545745.17 1174059.49 710.56 2.97 PVC 2.0 42.97 57.97 57.97 CAMA GWA-38D Deep 545295.90 1176204.21 760.01 2.73 PVC NR 55.73 60.73 67.73 CAMA GWA-38S Shallow 545303.18 1176204.41 760.20 3.16 PVC 2.0 38.16 53.16 53.16 CAMA GWA-39S Shallow 544433.87 1176960.10 723.41 3.24 PVC 2.0 6.24 8.24 8.24 CAMA GWA-31) Deep 545307.36 1173872.82 757.53 1.66 PVC 5.0 63.66 68.66 72.16 CAMA GWA-405 Shallow 544290.09 1176893.36 723.09 3.02 PVC 2.0 7.02 10.02 10.52 CAMA GWA-42S Shallow 544318.29 1176795.54 724.65 2.70 PVC 2.0 6.70 11.70 11.70 CAMA GWA-43D Deep 544428.69 1176622.32 725.10 2.75 PVC 6.0 45.25 50.25 52.25 CAMA GWA-43S Shallow 544428.85 1176616.35 725.19 2.70 PVC 2.0 NA NA NA CAMA GWA-44BR Bedrock 544232.45 1176085.01 769.03 3.07 PVC 6.0 97.17 102.17 134.07 CAMA GWA-44D Deep 544225.17 1176084.81 769.07 3.05 PVC 6.0 73.05 78.05 80.05 CAMA GWA-44S Shallow 544236.09 1176085.11 768.88 2.73 PVC 2.0 54.73 53.73 54.73 CAMA GWA-45D Deep 543267.82 1175816.16 816.59 3.08 PVC 6.0 93.08 55.08 93.08 CAMA GWA-455 Shallow 543264.18 1175816.06 816.55 2.87 PVC 2.0 58.87 58.37 58.87 CAMA GWA-46D Deep 543651.41 1177341.76 788.60 3.05 PVC 6.0 21.05 26.05 33.05 CAMA GWA-47D Deep 542672.01 1177735.90 805.18 2.65 PVC 6.0 52.65 57.65 62.65 CAMA GWA-48BR Bedrock 543048.02 1179539.18 808.90 3.36 PVC 6.0 85.36 90.36 114.36 CAMA GWA-41) Deep 545086.73 1174248.31 711.64 1.80 PVC 5.0 33.80 38.80 44.30 CAMA GWA-4S Shallow 545093.95 1174247.23 711.61 1.78 PVC 2.0 6.78 21.78 22.78 CAMA GWA-SBRU Deep 543860.81 1174616.21 776.83 2.04 PVC 6.0 42.04 47.04 47.74 CAMA GWA-5S Shallow 543865.77 1174613.96 777.01 2.04 PVC 2.0 16.04 31.04 31.54 CAMA GWA-61) Deep 543999.47 1173153.06 809.97 1.67 PVC 4.0 43.67 48.67 62.17 CAMA GWA-6S Shallow 544008.58 1173149.13 810.00 1.67 PVC 2.0 32.67 42.67 42.67 CAMA 113-113 Deep 546207.74 1176417.80 700.72 1.88 PVC 5.0 96.88 101.88 108.18 CAMA 113-1S Shallow 546195.14 1176407.27 700.74 1.87 PVC 2.0 29.87 44.87 45.87 CAMA 113-2AL Shallow 545888.70 1176632.62 697.55 1.97 PVC 2.0 39.47 50.77 52.97 CAMA 1B-2BRU Deep 545875.38 1176636.10 697.67 1.99 PVC 5.0 98.99 103.99 105.59 CAMA IB -21 Shallow 545863.40 1176644.01 697.22 2.22 PVC 2.0 71.22 81.22 83.72 CAMA 1B -2S -SL Shallow 545912.14 1176622.28 697.73 2.06 PVC 2.0 24.06 39.06 45.06 CAMA 1B -3D Deep 545819.44 1177130.04 704.08 -0.24 PVC 5.0 60.76 65.76 69.76 CAMA 1B -3S Shallow 545822.90 1177126.70 704.15 -0.19 PVC 2.0 25.81 40.81 42.31 CAMA 113-41311 Bedrock 545507.67 1176894.55 701.93 3.44 PVC 5.0 72.74 77.74 109.04 CAMA 113-41) Deep 545503.10 1176913.89 700.38 1.94 PVC 5.0 48.94 53.94 60.44 CAMA IB -45 -SL Shallow 545504.39 1176907.15 700.34 2.04 PVC 2.0 12.04 27.04 36.04 CAMA Cliffside Steam Station Page 3 of 5 CSA Supplement 2 Table 1-1: Well Construction Information s MW-21BR .- Bedrock 544846.80 1180097.69 •a. 777.56 2.01 PVC ng 5.0 Top of' Bottom 83.11 o?m' 88.11 Tota Depth 97.81 Program CAMA MW-22BR Bedrock 542828.34 1179648.35 821.11 2.18 PVC 5.0 88.18 93.18 102.68 CAMA MW -23S Shallow 544296.91 1176385.60 733.62 2.68 PVC 2.0 12.68 27.68 29.68 CAMA MW -30D Deep 542470.65 1173384.07 833.26 2.20 PVC 5.0 88.30 93.30 103.30 CAMA MW -30S Shallow 542484.88 1173386.25 833.73 2.28 PVC 2.0 34.98 49.98 50.28 CAMA MW-32BR Bedrock 542916.96 1172313.50 839.40 2.03 PVC 6.0 69.53 74.53 93.23 CAMA MW -32D Deep 542927.03 1172308.70 839.28 2.04 PVC 6.0 50.54 55.54 58.84 CAMA MW -32S Shallow 542935.85 1172312.99 839.71 2.14 PVC 2.0 22.14 37.14 37.14 CAMA MW-34BRU Deep 544844.38 1171585.40 751.66 2.02 PVC 5.0 45.72 50.72 52.72 CAMA MW -34S Shallow 544847.26 1171592.47 751.87 1.98 PVC 2.0 16.38 31.38 31.98 CAMA MW-36BRU Deep 545612.63 1172349.08 678.40 1.92 PVC 5.0 79.52 84.52 87.52 CAMA MW -36S Shallow 545610.32 1172353.94 678.87 1.97 PVC 2.0 5.97 20.97 21.97 CAMA MW -38D Deep 545675.79 1173812.70 707.68 -0.22 PVC 6.0 68.78 73.78 81.28 CAMA MW -38S Shallow 545680.97 1173810.80 707.60 -0.26 PVC 2.0 37.44 52.44 54.74 CAMA MW-40BRU Deep 545211.31 1174668.81 709.56 -0.53 PVC 5.0 29.87 34.87 39.77 CAMA MW -40S Shallow 545216.38 1174674.71 709.38 -0.26 PVC 2.0 4.74 19.74 21.24 CAMA MW -42D Deep 543355.32 1175355.63 811.12 2.10 PVC 6.0 46.80 51.80 57.60 CAMA MW -42S Shallow 543353.33 1175362.41 811.47 2.00 PVC 2.0 30.00 40.00 40.50 CAMA U5 -1D Deep 544204.05 1172474.31 802.94 1.94 PVC 4.0 56.94 61.94 70.14 CAMA U5 -1S Shallow 544207.33 1172478.77 802.71 1.89 PVC 2.0 40.89 55.89 56.89 CAMA U5-2BR Bedrock 544669.18 1172562.42 795.06 2.96 PVC 6.0 103.26 108.26 108.96 CAMA U5 -2D Deep 544678.47 1172564.38 793.73 1.74 PVC 4.0 73.74 78.74 82.04 CAMA U5-2S/SL Shallow 544678.51 1172558.64 794.05 1.88 PVC 2.0 51.88 66.88 68.88 CAMA U5 -2S -SL -A Shallow 544669.35 1172556.45 795.42 3.03 PVC 2.0 53.03 68.03 68.53 CAMA U5 -3D Deep 545043.91 1172643.60 765.68 -0.41 PVC 5.0 73.59 78.59 80.99 CAMA U5 -3S Shallow 545042.65 1172647.88 765.39 -0.75 PVC 2.0 34.25 49.25 50.25 CAMA U5 -3S -A Shallow 545045.70 1172638.67 765.85 -0.22 PVC 2.0 NA NA NA CAMA US-4BR Bedrock 544943.89 1173140.33 765.06 0.06 PVC 5.0 125.16 130.16 149.66 CAMA U5 -4D Deep 544943.46 1173133.62 764.99 -0.42 PVC 5.0 103.98 108.98 115.98 CAMA US -4S Shallow 544943.87 1173128.56 764.82 -0.56 PVC 2.0 59.44 74.44 75.44 CAMA U5 -5D U5-61) U5 -6S U5 -7D Deep Deep Shallow Deep 545115.11 544862.59 544871.20 544583.00 1173681.05 1174118.33 1174112.58 1173958.04 765.40 765.19 765.28 767.37 -0.57 -0.24 -0.36 -0.26 PVC PVC PVC PVC 5.0 5.0 2.0 5.0 63.93 56.26 36.64 71.24 68.93 61.26 51.64 76.54 70.03 68.26 53.04 85.44 CAMA CAMA CAMA CAMA U5 -7S Shallow 544587.86 1173960.06 767.30 -0.29 PVC 2.0 21.71 36.71 37.71 CAMA U5-7SL Shallow 544593.92 1173962.12 767.21 -0.41 PVC 2.0 55.59 65.59 67.59 CAMA U5-81311 Bedrock 543330.49 1174610.73 770.31 -0.23 PVC 6.0 120.67 125.67 126.77 CAMA U5 -8D Deep 543339.56 1174601.29 770.25 -0.32 PVC 4.0 70.68 75.68 83.78 CAMA U5 -8S Shallow 543335.66 1174605.44 770.29 -0.34 PVC 2.0 4.66 19.66 20.66 CAMA MW -20D Shallow 545809.00 1179558.00 665.20 2.57 PVC 2.0 9.07 24.07 24.07 NPDES MW-20DR Deep 545807.10 1179556.00 665.38 2.62 PVC 2.0 15.12 65.12 65.62 NPDES Cliffside Steam Station Page 4 of 5 CSA Supplement 2 Table 1-1: Well Construction Information Monitoring Well • MW -21D Monitonn��Northing• Deep 544842.60 Easting 1180102.00 777.51 2.08 Casing PVC 2.0 :. ofINEENEwiottom 8.68 of 23.28 Total Depth Program 23.58 NPDES MW-22DR Deep 542820.80 1179651.00 821.81 3.22 PVC 2.0 43.62 93.42 93.62 NPDES MW -23D Shallow 544306.90 1176393.00 734.08 2.99 PVC 2.0 38.99 48.99 49.19 NPDES MW-23DR Deep 544306.30 1176399.00 733.80 3.11 PVC 2.0 48.11 98.11 98.61 NPDES MW -24D Shallow 541289.40 1178297.00 816.36 3.23 PVC 2.0 36.43 56.23 56.63 NPDES MW-24DR Deep 541281.00 1178293.00 816.28 2.97 PVC 2.0 63.27 108.07 108.47 NPDES MW-25DR Deep 545921.80 1178089.00 667.05 2.52 PVC 2.0 39.82 89.52 89.82 NPDES CLMW-1 Shallow 544506.00 1178001.00 789.08 3.30 PVC 2.0 50.80 60.80 61.30 Voluntary CLMW-2 Shallow 545343.00 1177765.00 728.92 2.08 PVC 2.0 45.08 55.08 55.08 Voluntary CLMW-31) Shallow 544860.00 1177685.00 774.92 2.45 PVC 2.0 95.45 105.45 105.45 Voluntary CLMW-35 Shallow 544870.00 1177695.00 775.07 2.45 PVC 2.0 51.45 61.45 61.45 Voluntary CLMW-4 Shallow 545724.00 1179262.00 670.58 2.68 PVC 2.0 7.68 17.68 18.18 Voluntary CLMW-5S Shallow 545326.00 1179406.00 773.78 -0.19 PVC 2.0 49.81 59.81 59.81 Voluntary CLMW-6 Shallow 542145.00 1178181.00 770.86 2.45 PVC 2.0 25.59 35.59 35.59 Voluntary MW -10D Shallow 544812.00 1179010.00 785.50 2.10 PVC 2.0 36.10 41.10 41.10 Voluntary MW -10S Shallow 544816.00 1179004.00 785.81 2.41 PVC 2.0 22.11 37.11 37.41 Voluntary MW -11D Deep 545432.00 1179823.00 763.67 2.22 PVC 2.0 40.22 45.22 45.22 Voluntary MW -11S Shallow 545431.00 1179829.00 764.51 2.41 PVC 2.0 17.41 32.41 32.91 Voluntary MW -2 DA Deep 545334.70 1177757.00 730.62 3.17 PVC 2.0 74.37 79.17 79.57 Voluntary MW -41) Deep 545716.00 1179246.00 672.12 2.21 PVC 2.0 23.46 28.46 28.46 Voluntary MW -7D Shallow 543371.41 1177747.98 807.35 3.24 PVC 2.0 39.27 44.27 766.32 Voluntary MW -81) Deep 544314.00 1176988.00 736.64 2.53 PVC 2.0 32.53 37.53 37.53 Voluntary MW -8S Shallow 544313.00 1176983.00 736.27 2.49 PVC 2.0 5.39 20.39 20.49 Voluntary Notes: 1. TOC indicates top of casing 2. TOC elevation based on NAVD 88 vertical datum 3. Northing and Easting based on NAD83 horizontal datum 4. ft indicates measurements in feet 5. btoc indicates measurements below the top of casing 6. Construction log for U5 -3S -A was not available at the time of this report 7. Deep and Bedrock CAMA wells installed with 2 -inch riser; casing value listed for D/BR wells indicates outer casing diameter. 8. NR indicates no record Cliffside Steam Station Page 5 of 5 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells Cliffside Steam Station Page 1 of 15 CSA Supplement 2 NCAC 2L Standard: NS NS NS NS 6.5-8.5 500 10 250 250 Units: .0 mV µf2/cm mg/L SU mg/L mg/L mg/L mg/L Well ID Sample Date Temperature ORP Specific Conductivity D• pH (Field) TDS Nitrate Chloride Sulfate CLMW-1 8/25/2008 20.17 216.6 - 4.53 180 <0.02 13 76 CLMW-1 2/9/2009 19.6 211.4 4.87 92 <0.02 14 67 CLMW-1 8/3/2009 20.41 - 224.7 -- 4.71 158 <0.02 11 74 CLMW-1 2/23/2010 19.21 248.2 4.87 122 <0.02 14 75 CLMW-1 8/2/2010 20.83 -- 246.9 -- 4.65 148 <0.11 15 85 CLMW-2 8/25/2008 16.9 - 55.6 5.06 54 0.21 9.2 2.9 CLMW-2 2/9/2009 16.7 -- 53 5.23 60 0.19 8.7 3.6 CLMW-2 8/3/2009 18.19 - 55 5.17 60 0.21 8.9 5 CLMW-2 2/23/2010 16.63 -- 61 5.4 60 0.18 8 8 CLMW-2 8/2/2010 17.53 64 5.09 52 0.25 8.9 7.6 CLMW-3S 8/25/2008 17.83 -- 68.2 4.75 60 0.16 7.2 11 CLMW-3S 2/9/2009 17.59 64 4.94 42 0.16 <7.2 12 CLMW-3S 8/3/2009 18.21 - 72 4.83 70 0.17 9.8 12 CLMW-3S 2/23/2010 16.64 84 5.05 64 0.13 9.5 18 CLMW-3S 8/2/2010 18.95 -- 109 4.75 73 0.19 14 26 CLMW-3D 8/25/2008 17.28 142.2 5.21 116 0.16 8.1 39 CLMW-3D 2/9/2009 17.3 -- 137 5.45 108 0.16 <7.9 34 CLMW-3D 8/3/2009 18.2 137 5.33 124 0.14 9.1 39 CLMW-3D 2/23/2010 16.4 -- 144 5.54 108 0.14 9.4 38 CLMW-3D 8/2/2010 19.13 149 5.29 106 0.19 12 41 CLMW-4 8/25/2008 19.8 -- 308.2 6.52 138 <0.02 <0.1 <0.1 CLMW-4 2/9/2009 13.8 - 452 6.76 170 0.13 <0.1 26 CLMW-4 8/3/2009 18.87 - 362 -- 6.6 174 0.04 6.1 1.2 CLMW-4 2/23/2010 12.06 610 6.87 278 <0.02 4.6 100 CLMW-4 8/3/2010 22.15 -- 777 -- 6.49 -- <0.2 5.1 88 CLMW-5S 8/25/2008 17.48 68.7 4.88 46 <0.02 9.4 3 CLMW-5S 2/9/2009 17.3 -- 71 -- 5.34 38 <0.02 12 3.7 CLMW-5S 8/3/2009 17.42 74 5.12 50 <0.02 13 3.5 CLMW-5S 2/23/2010 16.52 - 79 -- 5.31 26 <0.02 12 4 CLMW-5S 8/2/2010 17.24 -- 81 - 5 52 <0.11 20 2.2 CLMW-6 8/26/2008 17.41 -- 37.8 -- 5.21 36 1.42 2.9 0.41 CLMW-6 2/9/2009 16.45 26.8 -- 5.35 32 1.34 2.8 0.36 CLMW-6 8/4/2009 16.72 -- 34.7 -- 5.12 <20 1.41 2.9 0.44 MW -2 DA 4/5/2011 15.3 193 296 2.6 7.44 200 <0.1 5.6 40 MW -21) 8/25/2008 20.52 -- 228.3 -- 8.31 176 <0.02 4.6 38 MW -21) 2/10/2009 16.69 - 1235 11.64 312 <0.02 4.9 38 MW -21) 8/4/2009 18.19 -- 1376 -- 11.46 326 <0.02 4.8 41 MW -2D 2/24/2010 16.69 2267 12.05 380 0.08 4.8 40 MW -2D 8/3/2010 17.45 -- 907 -- 11.26 235 <0.2 5 54 MW -4D 8/25/2008 17.22 - 268 6.7 170 <0.02 5.1 10 MW -4D 2/9/2009 15.5 -- 244 -- 6.84 158 <0.02 4.7 11 MW -4D 8/3/2009 16.72 245 - 6.55 160 <0.02 4.7 13 MW -41) 2/23/2010 14.76 -- 234 -- 6.85 116 <0.02 4 14 MW -4D 8/2/2010 16.78 238 6.61 160 0.13 5.7 12 MW -8S 8/25/2008 22.14 - 473.3 -- 6.65 296 0.05 11 21 MW -8S 2/9/2009 12.82 - 431 7.15 272 0.03 11 40 MW -8S 8/3/2009 21.14 -- 474 -- 6.81 308 0.07 13 50 MW -8S 2/23/2010 11.28 444.6 7.05 242 0.03 8.1 31 MW -8S 8/2/2010 22.46 -- 503.1 6.84 287 0.12 16 38 MW -8D 8/25/2008 19.01 239.7 5.96 176 <0.02 8.6 60 MW -8D 2/9/2009 16.76 - 237.4 6.22 176 <0.02 11 50 MW -8D 8/3/2009 17.61 254.4 6.09 152 <0.02 12 57 Cliffside Steam Station Page 1 of 15 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells Cliffside Steam Station Page 2 of 15 CSA Supplement 2 NCAC 2L Standard: NS NS NS NS 6.5-8.5 500 10 250 250 Units: °C mV µf2/cm mg/L SU mg/L mg/L mg/L mg/L Well ID Sample Date Temperature ORP Specific Conductivity D• pH (Field) TDS Nitrate Chloride Sulfate MW -8D 2/23/2010 16.67 262.2 - 6.28 136 <0.02 9.4 57 MW -8D 8/2/2010 17.99 258.2 6.06 158 0.33 14 66 MW -10S 8/25/2008 16.43 - 178.7 4.86 114 1.66 11 46 MW -10S 2/9/2009 16.34 181.4 5.03 128 2.05 13 43 MW -10S 8/3/2009 16.3 -- 241.8 -- 4.91 168 2.15 15 69 MW -10S 2/23/2010 15.77 - 275.5 4.96 156 2.6 15 86 MW -105 8/2/2010 17.76 -- 237.1 4.83 141 1.2 14 81 MW -10D 8/25/2008 16.6 - 85.3 4.96 56 1.26 8.7 11 MW -10D 2/9/2009 16.1 -- 68.9 5.11 66 1.14 8 9.4 MW -10D 8/3/2009 16.23 - 79.8 5.11 56 1.21 10 9.6 MW -10D 2/23/2010 15.79 -- 86.6 5.23 42 0.91 8.1 11 MW -10D 8/2/2010 17.41 - 78.7 4.98 54 0.95 9.6 10 MW -11S 8/25/2008 18.37 -- 68 5.01 42 0.12 12 2.2 MW -11S 2/9/2009 16.67 - 69.2 5.15 64 0.11 17 1.9 MW -11S 8/3/2009 17.3 -- 68.6 5 56 0.14 14 4.7 MW -11S 2/23/2010 16.38 77.1 5.39 44 0.32 9 12 MW -11S 8/2/2010 17.57 -- 65.9 5.18 47 0.11 9.9 9.7 MW -11D 8/26/2008 20.31 802.9 8.66 -- -- -- -- MW-11D 2/10/2009 15 -- 609.4 - 8.3 -- -- -- -- MW-11D 8/4/2009 18.32 622.3 7.89 0.06 4 190 MW -11D 2/24/2010 14.82 -- 599.8 -- 8.45 -- <0.02 3.4 170 MW -11D 8/3/2010 18.84 -- 606.1 -- 9.66 -- 0.43 4.1 160 MW -20D 4/28/2011 15.78 124 472 2.75 6.95 300 <0.023 5.8 0.15 MW -20D 8/1/2011 17.96 115 465.9 1.04 7.01 290 <0.023 5.7 0.26 MW -20D 12/5/2011 15.25 147 463.9 1.09 7.13 280 <0.023 5.5 <0.1 MW -20D 4/2/2012 15.59 128 461 2.77 7.06 269 <0.02 6.1 0.26 MW -20D 8/14/2012 17.75 114 441 2.85 7.08 280 <0.023 5.8 0.19 MW -20D 12/3/2012 15.48 137 461 2.97 7.25 280 <0.023 3 0.16 MW -20D 4/1/2013 14.53 129 454 3.86 7.03 280 <0.023 6.4 0.24 MW -20D 8/7/2013 16.76 131 452 3.94 6.9 280 <0.023 7.3 0.46 MW -20D 12/10/2013 15.03 131 451 4.35 7.01 280 <0.023 7.8 0.57 MW -20D 4/1/2014 14.27 146 436 5.02 6.93 270 <0.023 8.6 1.5 MW -20D 8/4/2014 16.3 154 396 4.92 6.89 230 <0.023 15 7.3 MW -20D 12/1/2014 15.04 139 402 6.28 7.03 250 <0.023 17 9 MW -20D 4/7/2015 14.44 148 372 6.57 6.93 230 <0.023 24 14 MW -20D 8/3/2015 16.37 151 354 6.3 6.89 220 0.03 31 18 MW -20D 12/3/2015 15.5 136 373 5.98 6.76 230 <0.023 21 12 MW -20D 4/4/2016 14.69 172 333 6.41 6.93 220 <0.023 24 11 MW-20DR 4/28/2011 16.34 139 477.1 3.16 6.95 300 <0.023 5.8 <0.1 MW-20DR 8/1/2011 17.84 113 464.4 0.15 6.99 290 <0.023 5.6 <0.1 MW-20DR 12/5/2011 15.47 164 466 0 7.12 290 <0.023 5.3 <0.1 MW-20DR 4/2/2012 15.87 158 468 0 7.06 273 <0.02 5.6 <0.1 MW-20DR 8/14/2012 17.07 157 464 0.4 7.03 290 <0.023 5.6 <0.1 MW-20DR 12/3/2012 15.15 210 463 0.28 7.1 290 <0.023 3.7 <0.1 MW-20DR 4/1/2013 15.02 172 462 0.77 7 290 <0.023 6.2 <0.1 MW-20DR 8/7/2013 17.06 171 464 0.68 6.93 280 <0.023 6.7 <0.1 MW-20DR 12/10/2013 15.04 170 465 0.09 6.95 290 <0.023 7.1 <0.1 MW-20DR 4/1/2014 15.06 191 468 0.1 6.95 290 <0.023 6.9 <0.1 MW-20DR 8/4/2014 17.16 141 461 0 7.04 290 <0.023 7 <0.1 MW-20DR 12/1/2014 13.7 161 470 0 7.07 290 <0.023 7.7 <0.1 MW-20DR 4/7/2015 15.1 122 457 0.06 7.1 290 <0.023 7.5 <0.1 MW-20DR 8/3/2015 17.61 135 482 5.62 7.23 300 <0.023 7.6 <0.1 Cliffside Steam Station Page 2 of 15 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells MW -21D NCAC 2L Standard: NS NS NS NS 6.5-8.5 500 10 250 250 45 Units: °C mV µf2/cm mg/L SU mg/L mg/L mg/L mg/L Well ID Sample Date Temperature ORP Specific Conductivity D• pH (Field) TDS Nitrate Chloride Sulfate MW-20DR 12/3/2015 14.58 148 471 0.08 6.92 660 <0.023 8 <0.1 MW-20DR 4/4/2016 15.93 _ 171 471 0 6.96 300 <0.023 7 <0.1 MW -21D 4/5/2011 14.92 474 48.5 6.72 5.08 39 1.5 5.9 2.1 MW -21D 8/1/2011 16.64 424 46.1 6.82 4.68 24 1.4 5.7 1.9 MW -21D 12/5/2011 15.58 479 44.1 7.25 5.15 MW -21D 4/2/2012 15.62 484 45 7.08 5.17 MW -21D 8/14/2012 16.72 431 44 7.42 4.83 MW -21D 12/3/2012 14.88 450 43 6.85 _ 5.08 MW -21D 4/1/2013 14.28 424 45 6.98 4.95 MW -21D 8/7/2013 16.99 464 44 7.78 4.64 MW -21D 12/10/2013 14.81 424 45 7.19 5.08 MW -21D 4/1/2014 17.12 481 46 7.81 5.07 MW -21D 8/4/2014 16.81 450 43 7.97 5.1 MW -21D 12/1/2014 15.51 442 42 7.84 5.19 MW -21D 4/7/2015 15.09 462 43 7.56 5.19 MW -21D 8/3/2015 16.46 443 40 7.51 5.27 MW -21D 12/3/2015 15.4 445 40 7.32 5.01 MW -21D 4/4/2016 15.11 511 51 8.16 5.11 MW-22DR 4/5/2011 14.9 190 115.8 0.26 6.41 MW-22DR MW-22DR MW-22DR 8/1/2011 12/5/2011 4/2/2012 17.16 14.62 15.85 179 215 234 73 99 95 0.26 1.37 1.3 6.32 6.19 6.27 MW-22DR 8/14/2012 16.91 206 100 1.03 6.24 MW-22DR 12/3/2012 16.97 208 98 0.93 6.37 MW-22DR 4/1/2013 18.04 244 86 4.58 5.98 MW-22DR 8/8/2013 15.62 308 77 2.69 5.43 MW-22DR 12/9/2013 15.29 212 99 0.02 6.11 MW-22DR 4/1/2014 15.72 327 72 2.98 5.67 MW-22DR 8/4/2014 15.75 244 84 1.69 6 MW-22DR 12/1/2014 15.78 212 98 0 6.24 MW-22DR 4/8/2015 15.48 212 100 0.17 6.14 MW-22DR 8/3/2015 15.98 271 86 2.17 6.14 20 1.4 5.2 1.6 27 1.4 5.7 1.4 33 1.3 5.3 1.4 33 1.3 5.4 1.5 30 1.2 5.1 1.4 61 0.95 5.5 1.8 30 1.2 5.8 1.5 39 1.2 5.4 1.6 32 1.2 5.3 1.2 36 1.3 5.2 1.3 36 1.2 5.1 1.3 34 1.1 5 1.5 35 1.3 5.3 1.8 50 2.1 5.7 1.5 100 <0.02 3.4 12 77 72 67 <0.023 <0.023 0.25 3.5 3.1 3.4 13 13 12 85 0.02 3.4 13 91 <0.023 3.2 14 80 0.1 3.3 12 86 0.33 3.5 11 82 <0.023 3.9 14 57 0.45 3.5 11 68 0.34 3.7 11 96 80 72 <0.023 <0.023 0.37 3.8 3.9 3.7 14 15 12 MW-22DR MW-22DR MW -23D MW -23D 12/3/2015 4/4/2016 4/5/2011 8/1/2011 15.32 15.48 15.15 17.09 272 396 256 179 81 50 786 791 2.13 5.2 0.42 0.14 5.95 5.52 6.76 6.89 76 56 590 600 0.33 0.73 <0.02 <0.023 3.9 3.3 11 16 12 6.9 280 300 MW -23D 12/5/2011 15.99 162 880 0.56 7.07 660 <0.023 18 330 MW -23D 4/2/2012 15.4 134 941 0.4 6.89 709 <0.02 19 370 MW -23D 8/14/2012 16.52 232 947 0.19 6.67 750 <0.023 17 370 MW -23D 12/3/2012 15.87 222 1031 0.12 6.84 790 <0.023 15 420 MW -23D 4/2/2013 13.61 199 1055 0.42 7.04 820 <0.023 17 200 MW -23D 8/7/2013 16.93 186 1017 0.11 6.85 820 <0.023 17 430 MW -23D 12/9/2013 15.42 220 1007 0.09 6.72 770 <0.023 17 410 MW -23D 4/1/2014 15.3 245 991 0.07 6.75 760 <0.023 16 390 MW -23D 8/4/2014 16.37 200 958 0.17 6.81 730 <0.023 18 370 MW -23D 12/1/2014 15.51 214 983 0.12 6.88 760 0.02 19 400 MW -23D 4/7/2015 15.79 172 968 0.08 6.86 740 <0.046 17 380 MW -23D 8/3/2015 15.99 168 945 0.1 7.2 730 <0.023 17 360 MW -23D 12/3/2015 15.76 239 949 0.1 6.81 710 <0.023 18 370 MW -23D 4/4/2016 15.61 179 917 0 6.74 710 <0.023 18 370 MW-23DR 4/5/2011 15.2 149 211 0.4 16.99 160 <0.02 2.7 17 MW-23DR 8/1/2011 16.41 8 186 0.01 7.07 130 <0.023 2.8 16 Cliffside Steam Station Page 3 of 15 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells MW-23DR NCAC 2L Standard: NS NS NS NS 6.5-8.5 500 10 250 250 MW-23DR Units: °C mV µf2/cm mg/L SU mg/L mg/L mg/L mg/L Well ID Sample Date Temperature ORP Specific Conductivity D• pH (Field) TDS Nitrate Chloride Sulfate MW-23DR 12/5/2011 15.92 110 213 0.02 7.29 130 <0.023 2.6 17 MW-23DR 4/2/2012 15.45 22 212 0.21 7.21 125 <0.02 2.8 17 MW-23DR 8/14/2012 16.26 123 211 0.05 6.95 150 <0.023 2.5 20 MW-23DR 12/3/2012 16.06 128 214 0.1 7.21 150 <0.023 2.5 18 MW-23DR 4/2/2013 14.74 123 213 0.12 7.37 150 <0.023 2.5 21 MW-23DR 8/7/2013 16.33 89 218 0.41 7.23 170 <0.023 2.7 24 MW-23DR 12/9/2013 15.13 128 221 0.09 7.14 150 <0.023 3 24 MW-23DR 4/1/2014 15.12 139 247 0.09 7.13 170 <0.023 3.1 36 MW-23DR 8/4/2014 16.43 46 262 0.12 7.23 180 <0.023 3.2 41 MW-23DR 12/1/2014 15.57 76 237 0.12 7.52 170 <0.023 3.3 31 MW-23DR 4/7/2015 15.63 70 246 0.09 7.33 160 <0.023 3.1 34 MW-23DR 8/3/2015 15.87 87 242 0.1 7.57 170 <0.023 3.1 31 MW-23DR 12/3/2015 15.64 89 258 0.08 7.27 160 <0.023 3.4 42 MW-23DR 4/4/2016 15.45 56 249 0 7.19 180 <0.023 3.4 41 MW -24D 4/5/2011 14.73 450 47 6.99 5.23 52 2.1 3.7 1.6 MW -24D 8/1/2011 17.14 390 45 6.82 5.29 24 2.1 3.8 1.3 MW -24D 12/5/2011 14.91 384 44 6 5.4 22 2.1 3.5 1.1 MW -24D 4/2/2012 15.36 294 48 7.75 5.4 39 2.4 4.1 0.76 MW -24D 8/14/2012 16.4 382 46 7.55 5.14 40 2.2 3.8 0.69 MW -24D 12/3/2012 14.92 461 47 7.06 5.09 36 2.3 4 0.68 MW -24D 4/1/2013 15.3 417 47 7.24 5.21 40 2.3 3.8 0.65 MW -24D 8/7/2013 17.73 464 47 7.11 5.24 49 2.4 4.1 0.66 MW -24D 12/9/2013 14.17 394 47 7.72 5.19 35 2.4 4.2 0.63 MW -24D 4/1/2014 15.12 470 47 7.95 5.22 40 2.4 4.1 0.79 MW -24D 8/4/2014 16.56 399 47 8.5 5.21 40 2.4 4 0.59 MW -24D 12/1/2014 14.66 335 50 8.32 5.3 49 2.6 4.2 0.6 MW -24D 4/8/2015 15.29 422 49 8.17 5.19 38 2.5 4.1 0.58 MW -24D 8/3/2015 16.07 394 52 7.63 5.82 57 2.3 3.9 1.3 MW -24D 12/3/2015 15.02 342 50 7.55 5.34 43 2.5 4.3 0.64 MW -24D 4/4/2016 15.2 386 48 8.13 5.19 45 2.6 4.4 0.72 MW-24DR 4/5/2011 14.96 133 136 1.34 7.11 120 <0.02 1.4 9.8 MW-24DR 8/1/2011 16.37 105 80 0.37 7.17 97 <0.023 1.4 10 MW-24DR 12/5/2011 15.38 149 133 0.68 7.23 110 <0.023 1.3 9.8 MW-24DR 4/2/2012 15.6 132 132 0.34 7.2 108 <0.02 1.5 10 MW-24DR 8/14/2012 16.09 139 131 0.04 6.98 110 <0.023 1.4 9.6 MW-24DR 12/3/2012 15.48 158 131 0.17 7.12 120 <0.023 1.3 10 MW-24DR 4/1/2013 15.34 143 133 0.85 7.11 120 <0.023 1.3 9.5 MW-24DR 8/7/2013 16.31 116 132 0.32 7.07 98 <0.023 1.6 10 MW-24DR 12/9/2013 15.12 125 133 0.08 7.13 110 <0.023 1.4 10 MW-24DR 4/1/2014 15.19 142 135 0.11 7.12 120 <0.023 1.3 9.9 MW-24DR 8/4/2014 15.99 79 135 0.08 7.17 110 <0.023 1.4 9.7 MW-24DR 12/1/2014 15.44 116 132 0.13 7.42 120 <0.023 1.5 10 MW-24DR 4/8/2015 15.43 92 135 0.12 7.2 120 <0.023 1.4 9.9 MW-24DR 8/3/2015 16.27 93 137 0.17 7.56 120 <0.023 1.5 9.9 MW-24DR 12/3/2015 15.31 122 135 0.14 7.27 120 <0.023 1.6 10 MW-24DR 4/4/2016 15.47 100 131 0 7.19 130 <0.023 1.5 10 MW-25DR 4/5/2011 14.74 277 167.6 1.72 9.46 130 <0.02 2.5 14 MW-25DR 8/1/2011 16.99 174 143.1 0.89 8.71 84 <0.023 2.1 9.8 MW-25DR 12/5/2011 15.3 144 152.5 0.48 9.03 110 <0.023 1.7 6.2 MW-25DR 4/2/2012 15.81 326 125 3.94 6.76 88 <0.02 2 3.6 MW-25DR 8/14/2012 16.19 166 138 1.84 6.88 98 <0.023 1.8 4.2 MW-25DR 12/3/2012 15.73 59 146 0.74 7.19 100 <0.023 1.6 4.8 Cliffside Steam Station Page 4 of 15 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells NCAC 2L Standard: Units NS . C MW-25DR 4/2/2013 15.4 MW-25DR 8/8/2013 15.99 MW-25DR 12/10/2013 15.43 MW-25DR 4/1/2014 15.67 NS NS NS 6.5-8.5 500 10 250 250 mV µf2/cm mg/L SU mg/L mg/L mg/L mg/L ORP Specific Conductivity D• pH (Field) TDS Nitrate Chloride Sulfate 326 107 4.99 6.52 89 <0.023 1.9 2.5 393 77 6.29 5.85 55 <0.023 2.5 2.1 391 82 5.37 6.12 71 <0.023 2.3 2.7 387 78 5.86 6.09 72 <0.023 2.2 2.3 MW-25DR 8/4/2014 15.67 401 85 5.46 6.15 67 <0.023 2.2 2.7 MW-25DR 12/1/2014 15.63 332 99 3.47 6.2 80 <0.023 2.1 3.6 MW-25DR 4/8/2015 15.55 361 88 4.89 6.28 74 <0.023 2.1 2.7 MW-25DR 8/3/2015 15.65 337 101 3.58 6.55 81 <0.023 2.1 3.4 MW-25DR 12/3/2015 15.41 311 101 3.9 6.45 98 <0.023 2.2 3.1 MW-25DR 4/4/2016 15.51 3b1 /U 6.28 6.05 63 <0.023 2.2 2.2 Notes: 1. °C indicates temperature measured in degrees celsius 2. mV indicates oxidation/reduction potential measured in millivolts 3. µf2/cm indicates specific conductivity measured in micromhos per centimeter 4. mg/L indicates concentrations measured in milligrams per liter 5. lug/L indicates concentrations measured in micrograms per liter 6. SU indicates pH values measured in standard units 7. NTU indicates turbidity values measured in Nephalometric Turbidity Units 8. Parameters are compared to standards found in 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina 9. 2L Standards are established as part of 15A NCAC 02L .0202 10. Interim Maximum Allowable Concentrations (IMACs) can be found in Appendix #1 of 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina Cliffside Steam Station Page 5 of 15 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells Well ID CLMW-1 CLMW-1 NCAC 2L Standard: Units: 7 Sample Date 8/25/2008 2/9/2009 10 µg/L Arsenic <2 <2 700 lug/L Barium 58 50 700 Vg/L Boron 509 477 2 µg/L Cadmium <0.5 <0.5 10 µg/L Chromium <1 <1 1 mg/L Copper <0.002 <0.002 300 µg/L Iron 242 98 15 µg/L <2 <2 50 µg/l- 190 167 CLMW-1 8/3/2009 <1 54 496 <1 <1 0.001 158 1.1 176 CLMW-1 2/23/2010 <1 50 471 <1 <1 <0.001 41.2 <1 175 CLMW-1 8/2/2010 <1 54.8 488 <1 <1 <0.001 134 <1 185 CLMW-2 8/25/2008 <2 37 <100 <0.5 <1 <0.002 19 <2 36 CLMW-2 2/9/2009 <2 31 <100 <0.5 <1 <0.002 13 <2 29 CLMW-2 8/3/2009 <1 31 <100 <1 <1 <0.001 <10 <1 29 CLMW-2 2/23/2010 <1 32 115 <1 <1 <0.001 <10 <1 28.5 CLMW-2 8/2/2010 <1 36.1 142 <1 <1 <0.001 <10 <1 33 CLMW-3S 8/25/2008 <2 122 230 <0.5 <1 <0.002 73 <2 62 CLMW-3S 2/9/2009 <2 115 231 <0.5 <1 <0.002 35 <2 59 CLMW-3S 8/3/2009 <1 133 254 <1 <1 <0.001 22 <1 68 CLMW-3S 2/23/2010 <1 129 289 <1 <1 <0.001 22.1 <1 67.1 CLMW-3S 8/2/2010 <1 211 358 <1 <1 <0.001 15.6 <1 106 CLMW-3D CLMW-3D CLMW-3D CLMW-3D CLMW-3D CLMW-4 CLMW-4 8/25/2008 2/9/2009 8/3/2009 2/23/2010 8/2/2010 8/25/2008 2/9/2009 <2 <2 <1 <1 <1 <2 <2 79 72 76 78.1 102 26 35 280 263 298 315 311 <100 <100 <0.5 <0.5 <1 <1 <1 <0.5 0.6 2.73 1.55 <1 <1 6.6 <1 <1 <0.002 <0.002 <0.001 <0.001 <0.001 <0.002 0.051 1030 473 292 184 2510 33300 29900 <2 <2 <1 <1 1.1 <2 <2 36 18 15 12.4 76.8 545 488 CLMW-4 8/3/2009 <1 27 <100 <1 <1 <0.001 10600 <1 267 CLMW-4 2/23/2010 <1 38.6 <50 <1 <1 <0.001 23100 <1 294 CLMW-4 8/3/2010 -- -- -- -- -- -- - CLMW-5S 8/25/2008 <2 67 <100 <0.5 <1 <0.002 271 <2 2490 CLMW-5S 2/9/2009 <2 60 <100 <0.5 <1 <0.002 175 <2 2980 CLMW-5S 8/3/2009 <1 71 <100 <1 <1 <0.001 193 1.6 _ 3230 CLMW-5S 2/23/2010 <1 76 <50 <1 <1 <0.001 202 1.61 3530 CLMW-5S 8/2/2010 <1 86.7 <50 <1 <1 0.001 208 1.2 3440 CLMW-6 8/26/2008 <2 19 <100 <0.5 <1 <0.002 44 <2 8 CLMW-6 2/9/2009 <2 17 <100 <0.5 <1 <0.002 37 <2 8 CLMW-6 8/4/2009 <1 18 <100 <1 <1 <0.001 26 <1 8 MW -2 DA 4/5/2011 1.67 16 <50 <1 <5 <0.005 352 <1 400 MW -21) 8/25/2008 6.01 19 <100 <0.5 33.4 0.003 96 <2 37 MW -21) 2/10/2009 5.5 30 <100 <0.5 47.5 0.003 129 <2 6 MW -21) 8/4/2009 7.9 25 <100 <1 62.1 0.007 96 <1 11 MW -21) 2/24/2010 5.67 47.3 <50 <1 70.7 0.004 16.2 <1 <5 MW -21) 8/3/2010 5.7 18.6 <50 <1 35.8 0.003 15.8 <1 <5 MW -41) 8/25/2008 <2 47 <100 <0.5 <1 <0.002 4980 <2 188 MW -41) 2/9/2009 <2 17 <100 <0.5 <1 <0.002 6410 <2 187 MW -41) 8/3/2009 <1 14 <100 <1 <1 <0.001 6610 <1 191 MW -41) 2/23/2010 <1 11 <50 <1 <1 0.006 5780 <1 169 MW -4D 8/2/2010 <1 13.9 <50 <1 <1 <0.001 6640 <1 181 MW -8S 8/25/2008 <2 42 133 <0.5 <1 <0.002 3300 <2 3500 MW -8S MW -8S MW -8S MW -8S MW -81) MW -8D MW -81) 2/9/2009 8/3/2009 2/23/2010 8/2/2010 8/25/2008 2/9/2009 8/3/2009 <2 1.2 3.14 3.1 <2 <2 <1 30 41 63.7 50.7 33 28 31 119 143 107 140 115 106 107 <0.5 <1 <1 <1 <0.5 <0.5 <1 <1 <1 2 <1 <1 <1 <1 <0.002 <0.001 0.001 <0.001 0.003 <0.002 <0.001 5290 13900 47100 14000 24700 21700 24200 <2 <1 3.2 <1 <2 <2 <1 3160 3270 3260 2810 3730 3290 3590 Cliffside Steam Station Page 6 of 15 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells MW -10S NCAC 2L Standard: 10 700 700 2 10 1 300 15 50 MW -10S Units: µg/L lug/L Vg/L µg/L µg/L mg/L µg/L µg/L µg/L MW -10D 10. <2 44 Boron Cadmium Chromium 0.054 1510 <2 272 MW -8D 2/23/2010 <1 30 101 <1 <1 <0.001 24300 <1 3590 MW -8D 8/2/2010 <1 30.2 96.3 <1 <1 <0.001 24900 <1 3740 MW -10S 8/25/2008 <2 91 177 <0.5 7.32 0.006 5620 3.09 193 MW -10S 2/9/2009 <2 52 160 0.57 2.77 0.004 761 <2 139 MW -10S 8/3/2009 <1 70 170 <1 3.7 0.001 1650 1.5 174 MW -10S 2/23/2010 <1 67.1 112 <1 5.93 <0.001 639 <1 164 MW -10S 8/2/2010 <1 52.8 256 <1 1.1 <0.001 391 <1 168 MW -10D 8/25/2008 <2 44 177 <0.5 1.52 0.054 1510 <2 272 MW -10D 2/9/2009 <2 39 163 0.588 1.5 0.042 1370 <2 165 MW -10D 8/3/2009 <1 36 162 <1 <1 0.038 1110 <1 161 MW -10D 2/23/2010 <1 40.8 173 <1 1.54 0.039 1930 <1 167 i MW -10D 8/2/2010 <1 30.5 154 <1 <1 0.025 850 <1 110 MW -11S 8/25/2008 <2 46 160 <0.5 1.82 <0.002 442 <2 441 MW -11S 2/9/2009 <2 55 173 0.599 2.66 <0.002 845 <2 709 MW -11S 8/3/2009 <1 57 160 <1 4.3 <0.001 1680 2 736 MW -11S 2/23/2010 <1 38.1 169 <1 1.75 <0.001 676 <1 859 MW -11S 8/2/2010 <1 31.3 183 <1 2 <0.001 570 <1 769 MW -11D 8/26/2008 2.62 26 <100 <0.5 3.93 0.023 2790 <2 30 MW -11D 2/10/2009 <2 16 <100 0.574 1.87 0.01 1190 <2 30 MW -11D 8/4/2009 <1 16 <100 <1 1.4 0.006 663 <1 21 MW -11D 2/24/2010 <1 12.8 <50 <1 1.83 0.004 254 <1 11.7 MW -11D 8/3/2010 6.3 6.77 <50 <1 3.1 0.004 369 <1 <5 MW -20D 4/28/2011 <1 23 113 <1 <5 <0.005 4970 <1 459 MW -20D 8/1/2011 <1 21 124 <1 <5 <0.005 5070 <1 516 MW -20D 12/5/2011 <1 33 107 <1 <5 <0.005 8620 4.46 549 MW -20D 4/2/2012 <1 15 117 <1 <5 <0.005 3950 <1 478 MW -20D 8/14/2012 <1 14 110 <1 <5 <0.005 4050 <1 496 MW -20D 12/3/2012 <1 13 119 <1 <5 <0.005 3470 <1 591 MW -20D 4/1/2013 <1 14 119 <1 <5 <0.005 3890 <1 649 MW -20D 8/7/2013 <1 15 128 <1 <5 <0.005 4500 <1 584 MW -20D 12/10/2013 <1 15 137 <1 <5 <0.005 4560 <1 561 MW -20D 4/1/2014 <1 14 149 <1 <5 <0.005 4380 <1 514 MW -20D 8/4/2014 <1 15 229 <1 <5 <0.005 3710 <1 462 MW -20D 12/1/2014 <1 14 250 <1 <5 <0.005 3360 <1 444 MW -20D 4/7/2015 <1 15 344 <1 <5 <0.005 3830 <1 427 MW -20D 8/3/2015 <1 17 459 <1 <5 <0.005 4170 <1 498 MW -20D 12/3/2015 <1 15 316 <1 <5 <0.005 5190 <1 556 MW -20D 4/4/2016 <1 13 300 <1 <5 <0.005 5030 <1 390 MW-20DR 4/28/2011 <1 <5 117 <1 <5 <0.005 193 <1 683 MW-20DR 8/1/2011 <1 <5 130 <1 <5 <0.005 244 <1 704 MW-20DR 12/5/2011 <1 <5 147 <1 <5 <0.005 226 <1 632 MW-20DR 4/2/2012 <1 <5 120 <1 <5 <0.005 232 <1 620 MW-20DR 8/14/2012 <1 <5 119 <1 <5 <0.005 330 <1 634 MW-20DR 12/3/2012 <1 <5 124 <1 <5 <0.005 285 <1 610 MW-20DR 4/1/2013 <1 <5 122 <1 <5 <0.005 266 <1 600 MW-20DR 8/7/2013 <1 <5 135 <1 <5 <0.005 262 <1 617 MW-20DR 12/10/2013 <1 <5 137 <1 <5 <0.005 267 <1 629 MW-20DR 4/1/2014 <1 <5 143 <1 <5 <0.005 270 <1 623 MW-20DR 8/4/2014 <1 <5 149 <1 <5 <0.005 247 <1 633 MW-20DR MW-20DR MW-20DR 12/1/2014 4/7/2015 8/3/2015 <1 <1 <1 <5 <5 <5 151 157 164 <1 <1 <1 <5 <5 <5 <0.005 <0.005 <0.005 297 260 256 <1 <1 <1 616 620 612 Cliffside Steam Station Page 7 of 15 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells Cliffside Steam Station Page 8 of 15 CSA Supplement 2 NCAC 2L Standard: 10 700 700 2 10 1 300 15 50 Units: µg/L lug/L Vg/L µg/L µg/L mg/L µg/L µg/L µg/l- Date Arsenic Barium Boron Cadmium Chromium Copper Iron MW-20DR 12/3/2015 <1 <5 156 <1 <5 <0.005 344 <1 624 MW-20DR 4/4/2016 <1 <5 166 <1 <5 <0.005 274 <1 618 MW -21D 4/5/2011 <1 22 <50 <1 <5 <0.005 125 <1 84 MW -21D 8/1/2011 <1 24 <50 <1 <5 <0.005 76 <1 57 MW -21D 12/5/2011 <1 20 <50 <1 <5 <0.005 89 <1 34 MW -21D 4/2/2012 <1 20 <50 <1 <5 <0.005 31 <1 22 MW -21D 8/14/2012 <1 21 <50 <1 <5 <0.005 36 <1 23 MW -21D 12/3/2012 <1 20 <50 <1 <5 <0.005 50 <1 20 MW -21D 4/1/2013 <1 21 <50 <1 <5 <0.005 75 <1 16 MW -21D 8/7/2013 <1 22 <50 <1 <5 <0.005 238 <1 13 MW -21D 12/10/2013 <1 21 <50 <1 <5 <0.005 139 <1 14 MW -21D 4/1/2014 <1 19 <50 <1 <5 <0.005 132 <1 11 MW -21D 8/4/2014 <1 20 <50 <1 <5 <0.005 158 <1 11 MW -21D 12/1/2014 <1 20 <50 <1 <5 <0.005 178 <1 12 MW -21D 4/7/2015 <1 21 <50 <1 <5 <0.005 343 <1 13 MW -21D 8/3/2015 <1 21 <50 <1 <5 <0.005 434 <1 13 MW -21D 12/3/2015 <1 24 <50 <1 <5 <0.005 274 <1 12 MW -21D 4/4/2016 <1 20 <50 <1 <5 <0.005 75 <1 7 MW-22DR 4/5/2011 <1 28 <50 <1 7 0.006 9890 1.71 148 MW-22DR 8/1/2011 <1 10 <50 <1 <5 <0.005 8510 <1 114 MW-22DR 12/5/2011 <1 8 <50 <1 <5 <0.005 6880 <1 93 MW-22DR 4/2/2012 <1 9 <50 <1 <5 <0.005 5280 <1 127 MW-22DR 8/14/2012 <1 8 <50 <1 <5 <0.005 6490 <1 90 MW-22DR 12/3/2012 <1 8 <50 <1 <5 <0.005 6220 <1 82 MW-22DR 4/1/2013 <1 8 <50 <1 <5 <0.005 4690 <1 85 MW-22DR 8/8/2013 <1 11 <50 <1 <5 <0.005 3710 <1 134 MW-22DR 12/9/2013 <1 8 <50 <1 <5 <0.005 6100 <1 82 MW-22DR 4/1/2014 <1 15 <50 <1 <5 <0.005 3220 <1 113 MW-22DR 8/4/2014 <1 10 <50 <1 <5 <0.005 5190 <1 89 MW-22DR 12/1/2014 <1 28 <50 <1 <5 <0.005 8240 1.18 84 MW-22DR 4/8/2015 <1 14 <50 <1 <5 <0.005 7100 <1 79 MW-22DR 8/3/2015 <1 12 <50 <1 <5 <0.005 2570 <1 134 MW-22DR 12/3/2015 <1 8 <50 <1 <5 <0.005 2660 <1 89 MW-22DR 4/4/2016 <1 17 <50 <1 <5 <0.005 1460 <1 108 MW -23D 4/5/2011 <1 90 <50 <1 14 <0.005 349 <1 410 MW -23D 8/1/2011 <1 105 <50 <1 <5 <0.005 450 <1 483 MW -23D 12/5/2011 <1 103 <50 <1 <5 <0.005 534 <1 542 MW -23D 4/2/2012 <1 103 <50 <1 <5 <0.005 650 <1 604 MW -23D 8/14/2012 1.01 100 <50 <1 <5 <0.005 774 <1 610 MW -23D 12/3/2012 <1 100 <50 <1 <5 <0.005 945 <1 750 MW -23D 4/2/2013 <1 84 <50 <1 <5 <0.005 746 <1 672 MW -23D 8/7/2013 <1 83 <50 <1 <5 <0.005 830 <1 666 MW -23D 12/9/2013 <1 73 <50 <1 <5 <0.005 1000 <1 759 MW -23D 4/1/2014 1.12 67 <50 <1 <5 <0.005 1130 <1 693 MW -23D 8/4/2014 1.15 59 <50 <1 <5 <0.005 1100 <1 678 MW -23D 12/1/2014 1.12 55 <50 <1 <5 <0.005 1280 <1 776 MW -23D 4/7/2015 <1 53 <50 <1 <5 <0.005 1110 <1 776 MW -23D 8/3/2015 1.05 67 <50 <1 <5 <0.005 1210 <1 660 MW -23D 12/3/2015 1.2 58 <50 <1 <5 <0.005 1220 <1 686 MW -23D 4/4/2016 1.08 56 <50 <1 <5 <0.005 1160 <1 678 MW-23DR 4/5/2011 <1 38 <50 <1 <5 <0.005 1240 <1 51 MW-23DR 8/1/2011 <1 41 <50 <1 <5 <0.005 1010 <1 51 Cliffside Steam Station Page 8 of 15 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells MW-23DR NCAC 2L Standard: 10 700 700 2 10 1 300 15 50 MW-23DR Units: µg/L µg/l- Vg/L µg/L µg/L mg/L µg/L µg/L µg/l- Well ID 7 Sample Date Arsenic Barium Boron Cadmium Chromium Copper Iron <1 45 MW-23DR 12/5/2011 <1 35 <50 <1 <5 <0.005 847 <1 44 MW-23DR 4/2/2012 <1 35 <50 <1 <5 <0.005 828 <1 _ 43 MW-23DR 8/14/2012 <1 36 <50 <1 <5 <0.005 850 <1 45 MW-23DR 12/3/2012 <1 37 <50 <1 <5 <0.005 861 <1 44 MW-23DR 4/2/2013 <1 36 <50 <1 <5 <0.005 871 <1 44 MW-23DR 8/7/2013 <1 39 <50 <1 <5 <0.005 960 <1 48 MW-23DR 12/9/2013 <1 36 <50 <1 <5 <0.005 828 <1 45 MW-23DR 4/1/2014 <1 42 <50 <1 <5 <0.005 905 <1 54 MW-23DR 8/4/2014 <1 46 <50 <1 <5 <0.005 907 <1 54 MW-23DR 12/1/2014 <1 40 <50 <1 <5 <0.005 816 <1 47 MW-23DR 4/7/2015 <1 43 <50 <1 <5 <0.005 847 <1 48 MW-23DR 8/3/2015 <1 44 <50 <1 <5 <0.005 851 <1 48 MW-23DR 12/3/2015 <1 47 <50 <1 <5 <0.005 1080 <1 54 MW-23DR 4/4/2016 <1 45 <50 <1 <5 <0.005 886 <1 50 MW -24D 4/5/2011 <1 30 <50 <1 <5 0.005 2170 <1 87 MW -24D 8/1/2011 <1 22 <50 <1 <5 <0.005 383 <1 43 MW -24D 12/5/2011 <1 19 <50 <1 <5 <0.005 382 <1 30 MW -24D 4/2/2012 <1 20 <50 <1 <5 <0.005 515 <1 31 MW -24D 8/14/2012 <1 20 <50 <1 <5 <0.005 193 <1 21 MW -24D 12/3/2012 <1 20 <50 <1 <5 <0.005 172 <1 19 MW -24D 4/1/2013 <1 19 <50 <1 <5 <0.005 146 <1 16 MW -24D 8/7/2013 <1 20 <50 <1 <5 <0.005 250 <1 14 MW -24D 12/9/2013 <1 20 <50 <1 <5 <0.005 140 <1 13 MW -24D 4/1/2014 <1 20 <50 <1 <5 <0.005 137 <1 11 MW -24D 8/4/2014 <1 20 <50 <1 <5 <0.005 74 <1 8 MW -24D 12/1/2014 <1 20 <50 <1 <5 <0.005 34 <1 8 MW -24D 4/8/2015 <1 21 <50 <1 <5 <0.005 134 <1 8 MW -24D 8/3/2015 3.84 30 <50 <1 <5 <0.005 2150 <1 28 MW -24D 12/3/2015 <1 22 <50 <1 <5 <0.005 336 <1 9 MW -24D 4/4/2016 1.38 24 <50 <1 <5 <0.005 563 <1 11 MW-24DR 4/5/2011 <1 <5 <50 <1 <5 <0.005 963 <1 61 MW-24DR 8/1/2011 <1 <5 <50 <1 <5 <0.005 1130 <1 61 MW-24DR 12/5/2011 <1 <5 <50 <1 <5 <0.005 962 <1 _ 54 MW-24DR 4/2/2012 <1 <5 <50 <1 <5 <0.005 1170 <1 54 MW-24DR 8/14/2012 <1 <5 <50 <1 <5 <0.005 1710 <1 57 MW-24DR 12/3/2012 <1 <5 <50 <1 <5 <0.005 1030 <1 54 MW-24DR 4/1/2013 <1 <5 <50 <1 <5 <0.005 1290 <1 54 MW-24DR 8/7/2013 <1 <5 <50 <1 <5 <0.005 1300 <1 56 MW-24DR 12/9/2013 <1 <5 <50 <1 <5 <0.005 1360 <1 58 MW-24DR 4/1/2014 <1 <5 <50 <1 <5 <0.005 952 <1 56 MW-24DR 8/4/2014 <1 <5 <50 <1 <5 <0.005 934 <1 55 MW-24DR 12/1/2014 <1 <5 <50 <1 <5 <0.005 989 <1 56 MW-24DR 4/8/2015 <1 <5 <50 <1 <5 <0.005 MW-24DR 8/3/2015 <1 <5 <50 <1 <5 <0.005 MW-24DR 12/3/2015 <1 <5 <50 <1 <5 <0.005 MW-24DR 4/4/2016 <1 <5 <50 <1 <5 <0.005 MW-25DR 4/5/2011 8.74 34 <50 <1 45 0.226 MW-25DR 8/1/2011 8.11 <5 <50 <1 <5 0.01 MW-25DR 12/5/2011 3.37 <5 <50 <1 <5 0.013 MW-25DR 4/2/2012 1.16 <5 <50 <1 <5 0.023 MW-25DR 8/14/2012 <1 <5 <50 <1 <5 _ 0.009 MW-25DR 12/3/2012 <1 <5 <50 <1 <5 <0.005 Page 9 of 15 1040 989 978 965 6610 504 409 580 284 97 <1 59 <1 57 <1 55 <1 55 12.6 213 <1 1.01 15 24 1.3 36 <1 22 <1 25 Cliffside Steam Station CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells NCAC 2L Standard: 10 700 700 10 300 15 50 Units: µg/L lug/L Vg/L µg/L µg/L mg/L µg/L µg/L µg/l- 7 Well ID Sample Date Arsenic Barium Boron Cadmium Chromium Copper Iron <1 MW-25DR 4/2/2013 <1 <5 <50 <1 <5 0.01 204 <1 21 MW-25DR 8/8/2013 <1 <5 <50 <1 <5 0.009 177 <1 _ 18 MW-25DR 12/10/2013 <1 <5 <50 <1 <5 0.006 100 <1 18 MW-25DR 4/1/2014 <1 <5 <50 <1 <5 0.018 429 <1 20 MW-25DR 8/4/2014 <1 <5 <50 <1 <5 0.013 347 <1 19 MW-25DR 12/1/2014 <1 <5 <50 <1 <5 0.007 133 <1 15 MW-25DR 4/8/2015 <1 <5 <50 <1 <5 0.008 153 <1 12 MW-25DR 8/3/2015 <1 7 <50 <1 <5 0.011 556 <1 24 MW-25DR 12/3/2015 <1 <5 <50 <1 <5 0.007 343 <1 17 MW-25DR 4/4/2016 <1 <5 <50 <1 <5 <0.005 22 <1 Notes: 1. °C indicates temperature measured in degrees celsius 2. mV indicates oxidation/reduction potential measured in millivolts 3. µO/cm indicates specific conductivity measured in micromhos per centimeter 4. mg/L indicates concentrations measured in milligrams per liter 5. lug/L indicates concentrations measured in micrograms per liter 6. SU indicates pH values measured in standard units 7. NTU indicates turbidity values measured in Nephalometric Turbidity Units 8. Parameters are compared to standards found in 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina 9. 2L Standards are established as part of 15A NCAC 02L .0202 10. Interim Maximum Allowable Concentrations (IMACs) can be found in Appendix #1 of 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina Cliffside Steam Station Page 10 of 15 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells Well ID CLMW-1 CLMW-1 NCAC 2L Standard: 0.2 Units: µg/L Sample Date Thallium 8/25/2008 -- 2/9/2009 100 µg/L Nickel <2 <2 1 1 mg/L µg/L Zinc Antimony* 0.006 - <0.005 20 µg/L Selenium <2 <2 1 µg/L Mercury <0.05 <0.05 NS NTU Turbidity (Field) 13.4 5.72 CLMW-1 8/3/2009 - 1.2 <0.005 <1 <0.05 10.3 CLMW-1 2/23/2010 1.39 <0.005 <1 <0.05 4.28 CLMW-1 8/2/2010 -- 1.9 <0.005 -- <1 <0.05 7.62 CLMW-2 8/25/2008 <2 <0.005 <2 <0.05 0.06 CLMW-2 2/9/2009 - <2 <0.005 <2 <0.05 0.99 CLMW-2 8/3/2009 <1 <0.005 <1 <0.05 1.47 CLMW-2 2/23/2010 - <1 <0.005 - <1 <0.05 1.49 CLMW-2 8/2/2010 - <1 <0.005 <1 <0.05 1.24 CLMW-3S 8/25/2008 -- <2 0.011 - <2 <0.05 3.37 CLMW-3S 2/9/2009 <2 0.008 <2 <0.05 1.96 CLMW-3S 8/3/2009 -- <1 0.007 <1 <0.05 2.4 CLMW-3S 2/23/2010 <1 0.01 <1 <0.05 1.82 CLMW-3S 8/2/2010 -- <1 0.015 -- 1.1 <0.05 1.18 CLMW-3D 8/25/2008 <2 0.006 <2 <0.05 19.7 CLMW-3D 2/9/2009 - <2 <0.005 <2 <0.05 9.97 CLMW-3D 8/3/2009 <1 <0.005 <1 <0.05 8.36 CLMW-3D 2/23/2010 <1 <0.005 <1 <0.05 5.95 CLMW-3D 8/2/2010 3.9 0.012 <1 <0.05 30 CLMW-4 8/25/2008 - <2 0.005 <2 <0.05 0.98 CLMW-4 2/9/2009 <2 <0.005 <2 <0.05 0.62 CLMW-4 8/3/2009 - <1 <0.005 <1 <0.05 1.93 CLMW-4 2/23/2010 <1 <0.005 <1 <0.05 1.4 CLMW-4 8/3/2010 -- -- -- - -- -- 41.6 CLMW-5S 8/25/2008 <2 0.008 <2 <0.05 10.3 CLMW-5S 2/9/2009 - <2 <0.005 -- <2 <0.05 14.3 CLMW-5S 8/3/2009 1 <0.005 <1 <0.05 18.8 CLMW-5S 2/23/2010 -- 1.52 0.006 - <1 <0.05 9.48 CLMW-5S 8/2/2010 1.8 0.011 <1 <0.05 5.28 CLMW-6 8/26/2008 - <2 <0.005 <2 <0.05 5.68 CLMW-6 2/9/2009 <2 <0.005 <2 <0.05 3.77 CLMW-6 8/4/2009 -- <1 <0.005 -- <1 <0.05 9.24 MW -2 DA 4/5/2011 <0.2 <5 0.006 <1 <1 <0.05 29.5 MW -21) 8/25/2008 -- <2 <0.005 -- <2 <0.05 5.31 MW -21) 2/10/2009 <2 <0.005 <2 <0.05 1.65 MW -21) 8/4/2009 -- <1 <0.005 -- <1 <0.05 2.89 MW -21) 2/24/2010 <1 <0.005 <1 <0.05 1.91 MW -21) 8/3/2010 -- <1 <0.005 <1 <0.05 1.39 MW -41) 8/25/2008 <2 <0.005 <2 <0.05 1.97 MW -41) 2/9/2009 - <2 <0.005 - <2 <0.05 1 MW -4D 8/3/2009 <1 <0.005 <1 <0.05 4.33 MW -41) 2/23/2010 -- <1 <0.005 - <1 <0.05 5.15 MW -4D 8/2/2010 <1 <0.005 <1 <0.05 2.55 MW -8S 8/25/2008 - 2.47 <0.005 <2 <0.05 11.6 MW -8S 2/9/2009 <2 <0.005 <2 <0.05 56.8 MW -8S 8/3/2009 - <1 <0.005 -- <1 <0.05 144 MW -8S 2/23/2010 2.74 0.009 <1 <0.05 52.2 MW -8S 8/2/2010 - 1.7 <0.005 <1 <0.05 34.2 MW -81) MW -8D MW -81) 8/25/2008 2/9/2009 8/3/2009 <2 <2 <1 <0.005 <0.005 -- <0.005 - <2 <2 <1 <0.05 <0.05 <0.05 30.5 4.25 5.56 Cliffside Steam Station Page 11 of 15 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells Cliffside Steam Station Page 12 of 15 CSA Supplement 2 NCAC 2L Standard: Units: 0.2 µg/L 100 µg/L 1 mg/L 1 µg/L 20 µg/L 1 µg/L NS NTU MW -8D MW -8D M 2/23/2010 8/2/2010 Thallium -- Nickel <1 <1 Zinc <0.005 <0.005 Antimony* Selenium <1 <1 Mercury <0.05 <0.05 Turbidity (Field) 3.4 4.13 MW -10S 8/25/2008 - 5.22 0.026 3.75 0.152 283 MW -10S 2/9/2009 2.58 0.01 3.92 0.213 29.6 MW -10S 8/3/2009 -- 2.7 0.012 -- 3.8 0.176 80.6 MW -10S 2/23/2010 3.02 0.014 5.74 0.066 19.3 MW -10S 8/2/2010 -- 2.5 0.009 -- 3.6 <0.05 25.8 MW -10D 8/25/2008 - 8.92 0.013 <2 <0.05 47.7 MW -10D 2/9/2009 -- 6.01 0.011 -- <2 <0.05 38.6 MW -10D 8/3/2009 - 5.5 0.01 - <1 <0.05 34.8 MW -10D 2/23/2010 - 5.96 0.015 - <1 <0.05 40.9 MW -10D 8/2/2010 3.9 0.009 <1 <0.05 46.3 MW -11S 8/25/2008 - <2 <0.005 <2 0.054 56.5 MW -11S 2/9/2009 2.15 <0.005 <2 <0.05 71.7 MW -11S 8/3/2009 -- 2.3 0.006 -- <1 <0.05 107 MW -11S 2/23/2010 1.55 <0.005 <1 <0.05 280 MW -11S 8/2/2010 - 1.3 <0.005 <1 <0.05 23.6 MW -11D 8/26/2008 3.82 0.01 6.79 -- 73.8 MW -11D 2/10/2009 - 2.46 <0.005 - 2.68 -- 15.4 MW -11D 8/4/2009 1.6 <0.005 1 5.62 MW -11D 2/24/2010 - 1.63 <0.005 <1 4.82 MW -11D 8/3/2010 -- 1.8 <0.005 -- 1.2 -- 5.24 MW -20D 4/28/2011 <0.2 <5 <0.005 <1 <1 <0.05 15.2 MW -20D 8/1/2011 <0.2 <5 <0.005 <1 <1 <0.05 45.4 MW -20D 12/5/2011 <0.2 <5 0.009 <1 <1 <0.05 43.8 MW -20D 4/2/2012 <0.2 <5 <0.005 <1 <1 <0.05 14.8 MW -20D 8/14/2012 <0.2 <5 <0.005 <1 <1 <0.05 12 MW -20D 12/3/2012 <0.2 <5 <0.005 <1 <1 <0.05 10.9 MW -20D 4/1/2013 <0.2 <5 <0.005 <1 <1 <0.05 9.72 MW -20D 8/7/2013 <0.2 <5 <0.005 <1 <1 <0.05 8.01 MW -20D 12/10/2013 <0.2 <5 0.005 <1 <1 <0.05 9.82 MW -20D 4/1/2014 <0.2 <5 <0.005 <1 <1 <0.05 12.5 MW -20D 8/4/2014 <0.2 <5 <0.005 <1 <1 <0.05 9.28 MW -20D 12/1/2014 <0.2 9 <0.005 <1 <1 <0.05 8.12 MW -20D 4/7/2015 <0.2 <5 <0.005 <1 <1 <0.05 9.82 MW -20D 8/3/2015 <0.2 <5 <0.005 1 <1 <0.05 9.54 MW -20D 12/3/2015 <0.2 <5 <0.005 <1 <1 <0.05 6.27 MW -20D 4/4/2016 <0.2 <5 <0.005 <1 <1 <0.05 10.1 MW-20DR 4/28/2011 <0.2 <5 <0.005 <1 <1 <0.05 1.48 MW-20DR 8/1/2011 <0.2 <5 <0.005 <1 <1 <0.05 5.86 MW-20DR 12/5/2011 <0.2 <5 <0.005 <1 <1 <0.05 0.75 MW-20DR 4/2/2012 <0.2 <5 <0.005 <1 <1 <0.05 0.71 MW-20DR 8/14/2012 <0.2 <5 <0.005 <1 <1 <0.05 0.36 MW-20DR 12/3/2012 <0.2 <5 <0.005 <1 <1 <0.05 1.84 MW-20DR 4/1/2013 <0.2 <5 <0.005 <1 <1 <0.05 1.7 MW-20DR 8/7/2013 <0.2 <5 <0.005 <1 <1 <0.05 1.31 MW-20DR 12/10/2013 <0.2 <5 <0.005 <1 <1 <0.05 3.59 MW-20DR 4/1/2014 <0.2 <5 <0.005 <1 <1 <0.05 2.18 MW-20DR 8/4/2014 <0.2 <5 <0.005 <1 <1 <0.05 0.86 MW-20DR 12/1/2014 <0.2 <5 0.005 <1 <1 <0.05 2.24 MW-20DR 4/7/2015 0.4 <5 <0.005 <1 <1 <0.05 0.26 MW-20DR 8/3/2015 <0.2 <5 <0.005 <1 <1 <0.05 4.25 Cliffside Steam Station Page 12 of 15 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells Well ID MW-20DR MW-20DR NCAC 2L Standard: Units: Sample Date 12/3/2015 4/4/2016 0.2 µg/L Thallium <0.2 <0.2 100 µg/L Nickel <5 <5 1 mg/L Zinc <0.005 <0.005 1 µg/L Antimony* 1.25 <1 20 µg/L Selenium <1 <1 1 µg/L Mercury <0.05 <0.05 NS NTU Turbidity (Field) 1.97 2.32 MW -21D 4/5/2011 <0.2 7 0.008 <1 <1 <0.05 7.6 MW -21D 8/1/2011 <0.2 5 0.006 <1 <1 <0.05 7.6 MW -21D 12/5/2011 <0.2 <5 0.007 <1 <1 <0.05 2.05 MW -21D 4/2/2012 <0.2 <5 <0.005 <1 <1 <0.05 2.49 MW -21D 8/14/2012 <0.2 <5 <0.005 <1 <1 <0.05 2.55 MW -21D 12/3/2012 <0.2 <5 <0.005 <1 <1 <0.05 3.89 MW -21D 4/1/2013 <0.2 <5 <0.005 <1 <1 <0.05 9.63 MW -21D 8/7/2013 <0.2 <5 <0.005 <1 <1 <0.05 10 MW -21D 12/10/2013 <0.2 <5 0.006 <1 <1 <0.05 9.87 MW -21D 4/1/2014 <0.2 <5 <0.005 <1 <1 <0.05 8.8 MW -21D 8/4/2014 <0.2 <5 0.005 <1 <1 <0.05 9.79 MW -21D 12/1/2014 <0.2 <5 0.006 <1 <1 <0.05 6.22 MW -21D 4/7/2015 <0.2 <5 <0.005 <1 <1 <0.05 5.42 MW -21D 8/3/2015 <0.2 <5 <0.005 <1 <1 <0.05 8.09 MW -21D 12/3/2015 <0.2 <5 <0.005 <1 <1 <0.05 10 MW -21D 4/4/2016 <0.2 <5 <0.005 <1 <1 <0.05 2.82 MW-22DR 4/5/2011 <0.2 <5 0.019 <1 <1 <0.05 175 MW-22DR MW-22DR MW-22DR 8/1/2011 12/5/2011 4/2/2012 <0.2 <0.2 <0.2 <5 <5 <5 <0.005 <0.005 <0.005 <1 <1 <1 <1 <1 <1 <0.05 <0.05 <0.05 16.1 22 18 MW-22DR 8/14/2012 <0.2 <5 <0.005 <1 <1 <0.05 8.34 MW-22DR 12/3/2012 <0.2 <5 <0.005 <1 <1 <0.05 6.28 MW-22DR 4/1/2013 <0.2 <5 <0.005 <1 <1 <0.05 9.4 MW-22DR 8/8/2013 <0.2 <5 <0.005 <1 <1 <0.05 8.15 MW-22DR 12/9/2013 <0.2 <5 <0.005 <1 <1 <0.05 9.51 MW-22DR 4/1/2014 <0.2 8 <0.005 <1 <1 <0.05 5.65 MW-22DR 8/4/2014 <0.2 <5 <0.005 <1 <1 <0.05 7.07 MW-22DR 12/1/2014 <0.2 <5 0.01 <1 <1 <0.05 25.9 MW-22DR 4/8/2015 <0.2 <5 <0.005 <1 <1 <0.05 11.7 MW-22DR 8/3/2015 <0.2 <5 0.006 <1 <1 <0.05 6.21 MW-22DR 12/3/2015 <0.2 <5 <0.005 <1 <1 <0.05 2.99 MW-22DR 4/4/2016 <0.2 7 0.007 <1 <1 <0.05 8.83 MW -23D 4/5/2011 <0.2 <5 <0.005 <1 <1 <0.05 1.3 MW -23D 8/1/2011 <0.2 <5 <0.005 <1 <1 <0.05 1.6 MW -23D 12/5/2011 <0.2 <5 <0.005 <1 <1 <0.05 0.68 MW -23D 4/2/2012 <0.2 6 <0.005 <1 <1 <0.05 0.77 MW -23D 8/14/2012 <0.2 6 <0.005 <1 <1 <0.05 0.8 MW -23D 12/3/2012 <0.2 8 <0.005 <1 <1 <0.05 1.83 MW -23D 4/2/2013 <0.2 6 <0.005 <1 <1 <0.05 1.93 MW -23D 8/7/2013 <0.2 6 <0.005 <1 <1 <0.05 2.19 MW -23D 12/9/2013 <0.2 7 <0.005 <1 <1 <0.05 3.73 MW -23D 4/1/2014 <0.2 10 <0.005 <1 <1 <0.05 3.75 MW -23D 8/4/2014 <0.2 7 <0.005 <1 <1 <0.05 6.19 MW -23D 12/1/2014 <0.2 10 <0.005 <1 <1 <0.05 3.05 MW -23D 4/7/2015 <0.2 7 <0.005 <1 <1 <0.05 1.08 MW -23D 8/3/2015 <0.2 6 <0.005 <1 <1 <0.05 6.37 MW -23D 12/3/2015 <0.2 7 <0.005 1.06 <1 <0.05 3.5 MW -23D 4/4/2016 <0.2 7 <0.005 <1 <1 <0.05 7.04 MW-23DR 4/5/2011 <0.2 <5 <0.005 <1 <1 <0.05 5.46 MW-23DR 8/1/2011 <0.2 <5 <0.005 <1 <1 <0.05 1.47 Cliffside Steam Station Page 13 of 15 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells Well ID MW-23DR MW-23DR NCAC 2L Standard: Units: Sample Date 12/5/2011 4/2/2012 0.2 µg/L Thallium <0.2 <0.2 100 µg/L Nickel <5 <5 1 mg/L Zinc <0.005 <0.005 1 µg/L Antimony* <1 <1 20 µg/L Selenium <1 <1 1 µg/L Mercury <0.05 <0.05 NS NTU Turbidity (Field) 0.54 0.77 MW-23DR 8/14/2012 <0.2 <5 <0.005 <1 <1 <0.05 0.8 MW-23DR 12/3/2012 <0.2 <5 <0.005 <1 <1 <0.05 0.6 MW-23DR 4/2/2013 <0.2 <5 <0.005 <1 <1 <0.05 2.82 MW-23DR 8/7/2013 <0.2 <5 <0.005 <1 <1 <0.05 2.47 MW-23DR 12/9/2013 <0.2 <5 <0.005 <1 <1 <0.05 4.64 MW-23DR 4/1/2014 <0.2 <5 <0.005 <1 <1 <0.05 2.19 MW-23DR 8/4/2014 <0.2 <5 <0.005 <1 <1 <0.05 3.83 MW-23DR 12/1/2014 <0.2 <5 <0.005 <1 <1 <0.05 1.96 MW-23DR 4/7/2015 <0.2 <5 <0.005 <1 <1 <0.05 0.36 MW-23DR 8/3/2015 <0.2 <5 <0.005 <1 <1 <0.05 0.69 MW-23DR 12/3/2015 <0.2 <5 <0.005 <1 <1 <0.05 2.56 MW-23DR 4/4/2016 <0.2 <5 <0.005 <1 <1 <0.05 2.73 MW -24D 4/5/2011 <0.2 <5 0.009 <1 <1 <0.05 215 MW -24D 8/1/2011 <0.2 <5 <0.005 <1 <1 <0.05 9.37 MW -24D 12/5/2011 <0.2 <5 <0.005 <1 <1 <0.05 7.34 MW -24D 4/2/2012 <0.2 <5 <0.005 <1 <1 <0.05 5.42 MW -24D 8/14/2012 <0.2 <5 <0.005 <1 <1 <0.05 3.88 MW -24D 12/3/2012 <0.2 <5 <0.005 <1 <1 <0.05 2.4 MW -24D 4/1/2013 <0.2 <5 <0.005 <1 <1 <0.05 4.73 MW -24D 8/7/2013 <0.2 <5 <0.005 <1 <1 <0.05 4.97 MW -24D 12/9/2013 <0.2 <5 <0.005 <1 <1 <0.05 5.8 MW -24D 4/1/2014 <0.2 <5 <0.005 <1 <1 <0.05 2.94 MW -24D 8/4/2014 <0.2 <5 <0.005 <1 <1 <0.05 4.22 MW -24D 12/1/2014 <0.2 <5 <0.005 <1 <1 <0.05 1.94 MW -24D 4/8/2015 <0.2 <5 <0.005 <1 <1 <0.05 1.76 MW -24D 8/3/2015 <0.2 <5 0.006 <1 <1 <0.05 39.8 MW -24D 12/3/2015 <0.2 <5 <0.005 <1 <1 <0.05 6.7 MW -24D 4/4/2016 <0.2 <5 <0.005 <1 <1 <0.05 17.7 MW-24DR 4/5/2011 <0.2 <5 <0.005 <1 <1 <0.05 4.29 MW-24DR 8/1/2011 <0.2 <5 <0.005 <1 <1 <0.05 1.73 MW-24DR 12/5/2011 <0.2 <5 <0.005 <1 <1 <0.05 0.92 MW-24DR 4/2/2012 <0.2 <5 <0.005 <1 <1 <0.05 1.12 MW-24DR 8/14/2012 <0.2 <5 <0.005 <1 <1 <0.05 1.35 MW-24DR 12/3/2012 <0.2 <5 <0.005 <1 <1 <0.05 0.84 MW-24DR 4/1/2013 <0.2 <5 <0.005 <1 <1 <0.05 4.18 MW-24DR 8/7/2013 <0.2 <5 <0.005 <1 <1 <0.05 3.68 MW-24DR 12/9/2013 <0.2 <5 <0.005 <1 <1 <0.05 5.28 MW-24DR 4/1/2014 <0.2 <5 <0.005 <1 <1 <0.05 1.35 MW-24DR 8/4/2014 <0.2 <5 <0.005 <1 <1 <0.05 4.68 MW-24DR 12/1/2014 <0.2 <5 <0.005 <1 <1 <0.05 1.55 MW-24DR 4/8/2015 <0.2 <5 <0.005 <1 <1 <0.05 0.57 MW-24DR 8/3/2015 <0.2 <5 <0.005 <1 <1 <0.05 0.94 MW-24DR 12/3/2015 <0.2 <5 <0.005 1.59 <1 <0.05 2.36 MW-24DR 4/4/2016 <0.2 <5 <0.005 <1 <1 <0.05 3.01 MW-25DR 4/5/2011 <0.2 19 0.075 <1 <1 <0.05 683 MW-25DR 8/1/2011 <0.2 <5 <0.005 <1 <1 <0.05 18.8 MW-25DR 12/5/2011 <0.2 <5 <0.005 <1 <1 <0.05 12.3 MW-25DR 4/2/2012 <0.2 <5 0.01 <1 <1 <0.05 13.9 MW-25DR MW-25DR 8/14/2012 12/3/2012 <0.2 <0.2 <5 <5 0.005 <0.005 <1 <1 <1 <1 <0.05 <0.05 4.93 2.65 Cliffside Steam Station Page 14 of 15 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells Well ID MW-25DR MW-25DR NCAC 2L Standard: Units: Sample Date 4/2/2013 8/8/2013 0.2 µg/L Thallium <0.2 <0.2 100 µg/L Nickel <5 <5 1 mg/L Zinc 0.007 0.006 1 µg/L Antimony* <1 <1 20 µg/L Selenium <1 <1 1 µg/L Mercury <0.05 <0.05 NS NTU Turbidity (Field) 8.18 6.58 MW-25DR 12/10/2013 <0.2 <5 <0.005 <1 <1 <0.05 4.36 MW-25DR 4/1/2014 <0.2 <5 0.008 <1 <1 <0.05 4.61 MW-25DR 8/4/2014 <0.2 <5 0.008 <1 <1 <0.05 5.85 MW-25DR 12/1/2014 <0.2 <5 0.006 <1 <1 <0.05 2.67 MW-25DR 4/8/2015 <0.2 <5 <0.005 <1 <1 <0.05 1.62 MW-25DR 8/3/2015 <0.2 <5 0.007 <1 <1 <0.05 9.46 MW-25DR MW-25DR 12/3/2015 4/4/2016 <0.2 <0.2 <5 <5 <0.005 <0.005 <1 <1 <1 <1 <0.05 <0.05 6.97 3.26 Notes: °C indicates temperature measured in degrees celsius mV indicates oxidation/reduction potential measured in millivolts µ0/cm indicates specific conductivity measured in micromhos per centimeter 4. mg/L indicates concentrations measured in milligrams per liter 5. lug/L indicates concentrations measured in micrograms per liter 6. SU indicates pH values measured in standard units 7. NTU indicates turbidity values measured in Nephalometric Turbidity Units 8. Parameters are compared to standards found in 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina 9. 2L Standards are established as part of 15A NCAC 02L .0202 10. Interim Maximum Allowable Concentrations (IMACs) can be found in Appendix #1 of 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina Cliffside Steam Station Page 15 of 15 CSA Supplement 2 Table 1-3: 2L Groundwater Standard Exceedances from NPDES Sampling Notes: 1. mg/L indicates concentrations measured in milligrams per liter 2. µg/L indicates concentrations measured in micrograms per liter 3. SU indicates pH values measured in standard units 4. Parameters are compared to standards found in 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina 2L Standards are established as part of 15A NCAC 02L .0202 5. Interim Maximum Allowable Concentrations (IMACs) can be found in Appendix #1 of 1SA NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina Cliffside Steam Station Page 1 of 1 CSA Supplement 2 2L Standard: 1 10 300 50 250,000 500,000 0.2 6.5-8.5 Units: µg/L µg/L µg/L µg/L µg/L µg/L µg/l- SU r. ,e Range Antimony Chromium Iron Manganese Sulfate TDS Thalliurn pH MW -20D 4/28/2011- 4/4/2016 1 No Exceedances 3,360 — 8,620 390-649 No Exceedances No Exceedances No Exceedances No Exceedances MW-20DR 4/28/2011— 4/4/2016 1.25 No Exceedances 330-344 600-704 No Exceedances_ 660,000 0.4 No Exceedances MW -21D 4/5/2011— 4/4/2016_ No Exceedances No Exceedances 343-434 57-84 No Exceedances No Exceedances No Exceedances 4.64-5.27 MW-22DR 4/5/2011— 4/4/2016 No Exceedances No Exceedances 1,460 — 9,890 79-148 No Exceedances No Exceedances No Exceedances 5.43-6.41 MW -23D 4/5/2011— 4/4/2016 1.06 14 349-1,280 410-776 280,000 — 430,000 590,000 — 820,000 No Exceedances No Exceedances MW-23DR 4/5/2011— 4/4/2016 No Exceedances No Exceedances 816-1,240 51-54 No Exceedances No Exceedances No Exceedances No Exceedances MW-24DR 4/5/2011— 4/4/2016 No Exceedances No Exceedances 336-2,170 87 No Exceedances No Exceedances No Exceedances 5.09-5.82 MW-24DR 4/5/2011— 4/4/2016 1.59 No Exceedances 934-1,710 54-61 No Exceedances No Exceedances No Exceedances No Exceedances 5.85-6.45 MW-25DR 4/5/2011— 4/4/2016 No Exceedances 45 343-6,610 213 No Exceedances No Exceedances No Exceedances 8.71-9.46 Notes: 1. mg/L indicates concentrations measured in milligrams per liter 2. µg/L indicates concentrations measured in micrograms per liter 3. SU indicates pH values measured in standard units 4. Parameters are compared to standards found in 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina 2L Standards are established as part of 15A NCAC 02L .0202 5. Interim Maximum Allowable Concentrations (IMACs) can be found in Appendix #1 of 1SA NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina Cliffside Steam Station Page 1 of 1 CSA Supplement 2 Table 2-1: Responses to Global NCDEQ Comments Type CSA Supplement 2 Check latitude and longitude shown on report cover pages (the HDR will review and provide corrected latitude and longitude coordinates for the sites in forthcoming General 1 conversion appears to be incorrect on the Mooresville region reports, if needed. reports and needs to be reconciled). "Proposed Provisional Background Concentrations" or PPBCs is the terminology used for statistically Background 2 Use terminology PEPA "provisional estimates for purposes of determined background concentrations in the CAP reporting. PPBCs are discussed in CAP Part 1, Section 2. assessment" provide for background concentrations of COls. The approach to refine PPBCs when additional data is available is presented in CSA Supplement 2, Section 4. COI Use results from porewater, groundwater and other media to COls were selected based on exceedances found in porewater, groundwater, soil, and surface water 3 develop COI list. sample results. Hexavalent Chromium is included as a CO] in CAP Part 1 data tables and is considered with respect to the include as COI at each site duer interest and due to NC DHHS screening level and has been carried forward with subsequent evaluations. Samples were COI 4 receptor recepwell results. Use NCDHHS screening ning value. analyzed for Hexavalent Chromium in select groundwater monitoring wells, and further Cr(VI) evaluation may take place based on the results of each site respectively. CAP Part 1, Section 1.9.2 states that Cr(VI) is included in the COI list. Need to evaluate vanadium and strontium at every site to show Vanadium has been considered across the sites in CSA reporting. Strontium was not included in the CSA COI 5 differences between background concentrations and potential tables, however strontium data was collected with other constituents, including vanadium, and is source -related concentrations. presented in the CSA Supplement 2. COI - Receptors 6 Add evaluation of receptor wells in CAP. Water supply wells are shown on Figure 1-3 in the CSA Supplement 2 along with analytical results facilitating the interpretation of receptor water quality relative to site water quality. Private and public water supply wells sampled should be shown Water supply wells are shown on Figure 1-3 in the CSA Supplement 2 along with analytical results COI - Receptors 7 on a map with zoom in boxes showing concentration results even facilitating the interpretation of receptor water quality relative to site water quality. if below 2L. COI - Receptors 8 Add table with all receptor well results. Water supply wells are shown on Figure 1-3 in the CSA Supplement 2 along with analytical results facilitating the interpretation of receptor water quality relative to site water quality. All private receptor wells shown on figures (use or add DEQ designations). All water supply wells are shown on Figure 1-3. Those water supply wells that can be shown in the COI - Receptors 9 Show results for detection constituents. viewports of the the potentiometric surface and isoconcentration figures in the CSA Supplement 2 are also included. A table of analytical results, including strontium, is included on Figure 1-3. Add strontium. Add total uranium and Ra226+228. DEQ considers radionuclides to be a driver of alpha activity in the ash basins. Sample the following locations both below ash ponds and other downgradient areas Select wells located downstream and along transects were sampled for these constituents in the CSA and COI where other constituent concentrations are high: Post -CSA sampling periods. At the time of the CSA Supplement 2, the analytical results from Round 5 had 10 Downgradient monitoring well locations, at locations with been received and upon review, were recommended for re -issue prior to completing review and inclusion exceedances, and at background locations. in the CSA Supplement 2. Upon receipt, these data will be provided in a subsequent submittal. Uranium and Ra226+228 may be included in NPDES monitoring. List Federal MCL as standard for Ra 226-228 and uranium. Source Characterization 11 Address soils as being primary and secondary sources —address in A separate risk assessment has been provided subsequent to the CSA report by Duke Energy via Haley & CAP and CSA supplement. Aldritch. Source Characterization Describe how geochemical conditions may affect release of 12 Discussion of geochemical conditions were provided in CAP Part 2 with geochemical modeling results. naturally occurring constituents such as iron and manganese. CSA Supplement 2 Table 2-1: Responses to Global NCDEQ Comments Source Characterization 13 Soil to be identified as secondary source — due to leaching of ash A separate risk assessment has been provided subsequent to the CSA report by Duke Energy via Haley & onto unsaturated soil. Aldritch. Background soil concentrations need to be evaluated. Native soils Background 14 may be a source based on geochemical conditions in/beneath the Proposed Provisional Background Concentrations or PPBCs are discussed in CAP Part 1, Section 2. The ash ponds. Need to address background soil conditions and approach to refine PPBCs when additional data is available is presented in CSA Supplement 2, Section 4. relationship to observed 2L exceedances. "Proposed Provisional Background Concentrations" or PPBCs is the terminology used for statistically Background 15 Provide "provisional estimates" of background if there are determined background concentrations in the CAP reporting. PPBCs are discussed in CAP Part 1, Section 2. insufficient numbers of samples for statistics. The approach to refine PPBCs when additional data is available is presented in CSA Supplement 2, Section 4. A similar analysis/evaluation of downgradient soils and their Background 16 relationship to 2L exceedances also needs to be included in the Proposed Provisional Background Concentrations or PPBCs are discussed in CAP Part 1, Section 2. The approach to refine PPBCs when additional data is available is presented in CSA Supplement 2, Section 4. CAP. Background Potential release mechanisms need to be considered in the CAP 17 Discussion of potential migration pathways is discussed in CAP Part 2, Section 3.3 (i.e., migration of leachate beneath the ash basin, etc.). Background determinations. Background concentrations need to "Proposed Provisional Background Concentrations" or PPBCs is the terminology used for statistically be evaluated to determine site-specific constituent concentration determined background concentrations in the CAP reporting. PPBCs are discussed in CAP Part 1, Section 2. Background 18 levels and this evaluation needs to be included in CAP. Use all The approach to refine PPBCs when additional data is available is presented in CSA Supplement 2, Section available historic data from compliance wells and newly installed wells. 4. Background groundwater monitoring wells need to be sampled 2 Background 19 more times before the end of 2015 (samples need to be These samples have been collected. Data from Rounds 2 through 4 was included in the CAP Part 2. speciated). Separate background concentrations need to be determined for "Proposed Provisional Background Concentrations" or PPBCs are discussed in CAP Part 1, Section 2. The Background 20 shallow, intermediate and deep flow layers (as well as any other approach to refine PPBCs when additional data is available is presented in CSA Supplement 2, Section 4. site-specific conditions like wetlands). This approach includes consideration to these calcuations by flow layer. Background 21 Use all available site data (include example background wells PHR, Background data from historical sources was utilized where applicable in the CAP Part 2. FGD, Craig Rd.). Well and Constituents 22 Wells must meet 2C rule requirements; turbidity cannot impact Results from Round 5 sampling are presented in the CSA Supplement 2 and wells with turbidity results results. above 10 NTU are identified so that results may be qualified upon review. Elevated pH and turbidity must be addressed or well must be Duke Energy has installed additional monitoring wells to address concerns with elevated pH and turbidity Well and Constituents 23 redeveloped or replaced. seen when sampling as well as to refine understanding of exceedances. Results from the Round 5, including additional assessment wells, has been included in CSA Supplement 2. Include discussion of pH and turbidity in background well "Proposed Provisional Background Concentrations" or PPBCs are discussed in CAP Part 1, Section 2. The Well and Constituents 24 discussion. approach to refine PPBCs when additional data is available is presented in CSA Supplement 2, Section 4. This approach includes consideration to these calcuations by utilizing viable samples below 10 NTU. "Proposed Provisional Background Concentrations" or PPBCs are discussed in CAP Part 1, Section 2. The Well and Constituents 25 Results above 10 NTU to be removed from data set for statistics. approach to refine PPBCs when additional data is available is presented in CSA Supplement 2, Section 4. This approach includes consideration to these calcuations by utilizing viable samples below 10 NTU. CSA Supplement 2 Table 2-1: Responses to Global NCDEQ Comments Soil Contamination 27 General Resolution delineation of COls are noted on cross sections included in the CSA Supplement 2. anuw tAWFIL of pmn nguleb dew un uu»>eu.wnb. Compare soil results to Preliminary Soil Remediation Goals (PSRG) Where additional soil samples were collected as part of the installation of additional assessment wells, for protection of groundwater standards (POG). those results will be presented to PSRG POG standards. Soil Contamination 28 roIKL vs. rw are issue Tor seiectea constituents; oris may require uuKe tnergy worKea witn the Taos to reauce the reporting emits. however, iowenng me roircL to Detow ine resampling. POG was not able to be achieved to date for certain constituents. Soils PSRGs, detection limits above standards is problematic. Soil Contamination 29 Review IHSB Guidelines for Assessment and Cleanup section Duke Energy worked with the labs to reduce the reporting limits. However, lowering the MRL to below the 4.1.1.2 to develop site specific background values for soil, if POG was not able to be achieved to date for certain constituents. applicable Soil Contamination 30 Cr(VI) is driving risk, use Cr(VI) in review. In the CAP reporting as well as CSA Supplement 2, Cr(VI) is added to the list of Cols in groundwater. Soils will be compared to the PSRG POG Cr(VI) standard of 3.8 mg/kg in subsequent reporting, where Soil Contamination 31 Need to compare soils results to Cr(VI) (not Cr(III)). additional soil samples were collected. Hydrology/geologic controls and the effects on contaminant On June 25, 2015, NCDEQ requested that these geochemical issues be addressed in a Site Conceptual and transport are not discussed in CSA. Discuss Model. This topic was introduced in the CSA and announced that the SCM would be refined as an iterative Hydrologdistribution and Chemical Controls Chemical Controls 32 relative to DO, pH, Eh, etc. It is imperative that this discussion be process in the forthcoming CAP. CAP Part 1 Section 3.2.2 included discussion of general geochemical included as part of CAP #1 as this is requirement of CAMA. The characteristics such as cations/anions, redox potential, solute speciation, and Kd testing. These items were discussion can be refined in CAP #2. further addressed in CAP Part 2 Section 2.4.4, and Section 3.3. On June 25, 2015, NCDEQ requested that these geochemical issues be addressed in a Site Conceptual Model. This topic was introduced in the CSA and announced that the SCM would be refined as an iterative Hydrology/Geology and Discuss how geochemical conditions affect contaminant process in the forthcoming CAP. CAP Part 1 Section 3.2.2 included discussion of general geochemical Chemical Controls 33 distribution? (Geochemical "halo' releasing Mn and Fe). characteristics such as cations/anions, redox potential, solute speciation, and Kd testing. These items are further addressed in CAP Part 2 Section 2.4.4: Site Geochemistry and Influence on COls, which treats spatial distribution of groundwater geochemistry relative to the source area. Hydrology/Geology and The CAP Part 2 report states where the model is consistent with LeGrand, specifically in the Groundwater Chemical Controls 34 Specify where differences exist from LeGrand conceptual model. Migration subsection, and the COI Occurrence and Distribution Section. Groundwater velocities in bedrock and transition zone appear to Hydrology/Geology and Chemical Controls 35 be too high. Verify or correct these values. Describe transmissivity These values were corrected and updated in CAP Part 2 Appendix A. concept versus joint flow velocity. Hydrology/Geology and 36 Explain why one contaminant may be elevated in a particular area. CAP Part 2 Section 3.7 included an expanded discussion of site geochemical controls on contaminant Chemical Controls mobility and migration to address this concern. Hydrology/Geology and 37 Describe how constituents are mobilized or attenuated CAP Part 2 Section 3.7 included an expanded discussion of site geochemical controls on contaminant Chemical Controls . mobility and migration to address this concern. Describe geochemical conditions and mechanisms, and charges, The groundwater model considers linear adsorption (Freundlich adsorption for select COls in the Buck Hydrology/Geology and along flow paths. DEQ considers flow paths to be from the model) for COls (except sulfate and chloride). The adsorption term (Kd) is uniform within the model Chemical Controls 38 maximum concentration for a COI to a receptor or to the domain, including from the active and inactive ash basins/storage (sources) to downgradient monitor wells compliance boundary. and the compliance boundary. CAP Part 2, Appendix B, groundwater model. Hydrology/Geology and 39 Describe nature of sorptive materials present in three-part system Sorption constants and calculations are described in CAP Part 2 Section 4.3, in the methodology subsection Chemical Controls and along flow paths to receptors. CSA Supplement 2 Table 2-1: Responses to Global NCDEQ Comments The groundwater model is setup per source area and then calibrated to concentrations observed in downgradient monitor wells. Calibration to observed concentrations is achieved by adjusting source Describe how boron, sulfate, TDS "islands" are located along flow concentrations within active/inactive ash basins and ash storage areas within the measured values, Hydrology/Geology and adjusting hydraulic conductivity based on reported values, adjusting kd based on lab data, and other -hemical Controls 40 paths and how these are considered/incorporated into HGCM and measured hydrogeologic properties. The calibration attempts to match concentrations observed in numerical models. downgradient monitor wells by matching the flow paths and thus the observed COI "islands". The model did not incorporate TDS (boron and sulfate are both included in the groundwater model. CAP Part 2, Appendix B, groundwater model. Hydrology/Geology and Chemical Controls Hydrology/Geology and Chemical Controls Hydrogeologic and Other Geochemical Conceptual Subsurface drainage systems at dike/dams should be shown and 41 potential impacts to fate & transport modeling should be Subsurface drainage systems are shown and discussed in Section 4 of the CSA reports. They are shown in described in in hydrogeologic and geochemical conceptual the CSA Section 4 Figures. models. Pond, river, and lake elevations will be shown on figures where applicable. For example, in the CSA 42 Show measured water levels on ponds, streams, rivers. Supplement 2, these elevations are included on the shallow potentiometric figures, but not on all flow 43 Refined conceptual model needs to be presented in CAP I. Site Conceptual Models were updated and included in the CAP Part 2. Hydrogeologic and Other Geochemical Conceptual Models 44 Hydrogeo and geochemical conceptual models need to be discussed in terms of specific source areas. Include upgradient, source, and downgradient. Develop narrative for each source area and downgradient footprint (flow system recharge/discharge, horizontal flow direction, flow paths emanating from all sides (include map). CAP Part 2 Section 2.4.4 included discussion of geochemical parameters with consideration to whether there are trends upgradient or downgradient from the source. The refined SCM also included flow paths determined across the entire site. Hydrogeologic and Other Explain implications of vertical gradients in recharge and discharge Vertical hydraulic gradients were calculated for Round 2 data, and were included in CAP Part 1. The Geochemical Conceptual Models 45 area in each source area and its downgradient footprint. patterns in vertical gradients are discussed in CAP Part 2 Section 2.3.1.1. Hydrogeologic and Other Include effects f receptor wells in discussion. Also include In CAP Part 2 Appendix C, the issue of pumping wells is discussed. Where appropriate,. pumping wells are Geochemical Conceptual 46 possible impactssfrom basin to receptors in conceptual model included as an influence in the groundwater model. For example, for the DEC Cliffside site, the pumping Modelswells discussions. weren't modeled because of the influence of the Broad River. Other DEC sites, such as Allen, Belews Creek, and Buck, the pumping wells were included in the model. Hydrogeologic and Other Site heterogeneities are not adequately explained. Explain existing The groundwater models are being updated and recalibrated including new data as it has becoms available Geochemical Conceptual 47 heterogeneities and implications for fate and transport modeling. as part of the expanded groundwater model domain activities. Uncertainties and limitations will be Models Describe uncertainties and explain impact of uncertainties. presented as part of the results, which are expected to be completed during Fall 2016. Hydrogeologic and Other The groundwater models are being updated and recalibrated including new data as it has becoms available Geochemical Conceptual 48 Explain impact of uncertainties in conceptual model. as part of the expanded groundwater model domain activities. Uncertainties and limitations will be Models presented as part of the results, which are expected to be completed during Fall 2016. Hydrogeologic and Other Geochemical Conceptual 49 Models Hydrogeologic and Other Geochemical Conceptual 50 Models Ensure that streams, wetlands, etc. shown in Section 12 are included on all figures as needed. Include in conceptual model discussions as appropriate. Description of AMEC ecological survey report findings not utilized in report or in figures. Data should be used, shown on figures or not. CAP Part 2 Section 2 figures include wetlands and streams. Ecological data concerning vegetation was included in the CSA Section 12 Risk Assessment and referenced in the Eco -Checklists provided for each site. CSA Supplement 2 Table 2-1: Responses to Global NCDEQ Comments I Type Comment Number Comment Batch geochemical modeling for each of three layers per General Resolution As provided in CAP Part 2 Modeling Appendix B, Model Construction Section, each constituent was Modeling 51 constituent with narrative of what happens along flow path. modeled in one of 7 layers, which fall into the following categories: Ash material, Dike and ash storage Select flow path alignment with MOD PATH. material, Alluvium, M1 Saprolite, M2 Saprolite, Transition Zone, and Fractured bedrock. Describe geochemical conditions and mechanisms, and charges, Modeling 52 along flow paths. DEQ considers flow paths to be from the MODPATH was used to identify and delineate flow paths. This is displayed in CAP Part 2 Modeling Appendix maximum concentration for a COI to a receptor or to the B, Model Calibration in the particle tracking figure. compliance boundary. Model should use highest COPC in source area for model input. The model presented in the CAP Part 2 Appendix B uses variable concentrations in the source areas to Modeling 53 There will be different flow paths as flow path is based on match downgradient concentrations observed in monitor wells. In areas where the flow path from the maximum concentration of COI. source to an elevated observed concentration in a monitor well is observed, the highest measured source concentration is used in the model. Impacts from Fe, Mn are not related to Kd — how will modeling The groundwater model does not address Fe and Mn, however the geochemical modeling report does Modeling 54 treat Fe and Mn as COls (CAP Part 2 Appendix E), and determines the forms they likely exist in under address these constituents? conditions at the respective sites (CAP Part 2 Appendix E Section 2: Pourbaix diagrams). Modeling 55 Groundwater modeling should use site specific Kds. Sorption terms were developed and utilized as part of the groundwater modeling presented in CAP Part 2, Appendix B. Describe Kds and HFO or soil samples in areas not affected by ash. Modeling 56 Explain differences between these Kds and Kds from impacted A uniform Kd value for the groundwater model was utilized as these values are variable from sample to sample, regardless of site location (CAP Part 2, Appendix A, Groundwater Model). areas. Groundwater flow modeling in CAP needs to account for cumulative effect of off-site receptor wells (i.e., water supply The cumulative effect of off-site receptor wells were accounted for in the groundwater modeling (CAP Part wells). Need to come up with some assumptions regarding depth 2 Modeling Appendix B). The yield of these wells was estimated at 400 gpd, which is the average EPA I 57 and yield. CSA reports generally discount potential for upgradient household usage. The groundwater models are being updated and recalibrated including new data as it flow direction resulting from off-site pumping. Model results need has becoms available as part of the expanded groundwater model domain activities, including water supply to be included in the CAP now and revise once results are in from well information. Uncertainities and limitations will be presented as part of the results, which are expected data gap wells that are located to help inform groundwater flow to be completed during Fall 2016. direction near the property boundary. The groundwater model was calibrated to steady-state flow conditions and considered water levels from summer 2015. Historic water levels in the ponds were not modeled. The timing of start of the ash Modeling 58 Address historic water levels in pond in groundwater modeling. operations in different basins was considered in the groundwater model. The groundwater models are being updated and recalibrated including new data as it has becoms available as part of the expanded groundwater model domain activities, including historic water levels. Need to discuss how groundwater model results are incorporated The CAP Part 1 Surface water modeling Appendix details how groundwater model results are incorporated Modeling 59 in surface water model results (including how on-site streams are in surface water model results. incorporated). Modeling 60 Deep rock groundwater flow not well presented relative to off-site Particle flow maps that take into account offsite pumping are presented in the groundwater modeling pumping. This needs to be presented in CAP. Appendix B of the CAP Part 2. Subsurface drainage systems at dike/dams should be shown and Modeling 61 potential impacts to fate & transport modeling should be Subsurface drainage systems are shown and discussed in Section 4 of the CSA reports. considered. CSA Supplement 2 Table 2-1: Responses to Global NCDEQ Comments r— �Type Comment Number Comment Guidelines require — seep, sediment, surface water, receptor well General Resolution CAP Part 2 included chem box maps for seeps, sediments, surface water, and groundwater. Chem boxes for Data Presentation 62 data, results show all COIs (field and results) in chem boxes. receptor wells were not able to be shown spatially for all sampling events, however, Figure 1-3 in the CSA Supplement 2 shows location and analytical results. Data Presentation 63 Show concentrations above PQLs on chem box maps, not just Chem box maps show all detected constituents for detection and assessment monitoring constituents as constituents above 2L. part of the CAP Part 2. Data Presentation 64 Add vertical gradients to figures —plan view. CAP Part 1 Section 3 included figures depicting vertical gradients between shallow and deep wells, and between deep and bedrock wells. Data Presentation 65 Add vertical gradient maps. CAP Part 1 Section 3 includes figures depicting vertical gradients between shallow and deep wells, and between deep and bedrock wells. Data Presentation 66 Develop a potentiometric surface map for the transition zone Deep flow layer wells are used to investigate the transition zone, and potentiometric surfaces figures were wells. developed as part of the CAP Part 2 as well as CSA Supplement 2. Piper diagram figures are in Section 10 of the CSA. Updated piper diagrams utilizing Round 5 data have Data Presentation 67 Show cation -anion balance values on Piper diagrams, remove been included in the CSA Supplement 2 to include only those events with balance differences that are less results with balance differences > 10%. than 10%. Show all receptor wells on figures given the existing figure Figure 1-3 in the CSA Supplement 2 presents all receptor wells and their analytical results. Those water Data Presentation 68 supply wells that can be shown in the viewports of the the potentiometric surface and isoconcentration extents. figures in the CSA Supplement 2 are also included. Data Presentation 69 Need one map with all receptor wells and MWs. Figure 1-3 in the CSA Supplement 2 presents all receptor wells and their analytical results. Data Presentation 70 Show seep results with chem boxes. Seeps and DEQ Seeps were provided in CAP Part 1 Section 2 figures. Data Presentation 71 Show topography on groundwater surface contour maps (add Topography has been included on the potentiometric surface figures provided in CSA Supplement 2. elevation labels to contours). Add geologic data and iso -concentration data (include Kds) on Cross-sections will be expanded with additional assessment monitoring wells for the CSA Supplement 2. Data Presentation 72 cross-sections. These will include lithology, recovery, ROD, where available, as well as the vertical extent of COls Data Presentation 73 Add figure showing pH, Eh, etc. results. CAP Part 1 Section 2 Chem Box figures included field parameters. Data Presentation 74 Add table w/NPDES sample event results. A NPDES sample events results table has been provided in Section 1 of the CSA Supplement 2. Data Presentation 75 Chem box figures for groundwater— add round 2 data as column Round 2 chembox figures were included in CAP Part 2. to right of existing data. Iso contours - Need to address how iso contour lines are shown on figures. Show part of the line as dashed where uncertainty exists Data Presentation 76 (i.e., no downgradient data to help determine extent of iso Isoconcentration maps utilizing Round 5 analytical results, including strontium, where it is a COI, are contour). Depict concentrations above reporting limit. included in CSA Supplement 2. Add iso -contour figure for strontium. Need to show natural resource information (i.e., surface water Data Presentation 77 features, wetland features, heron rookery at Buck, etc.) on "base CAP Part 2 Section 2 figures includes wetlands and streams which were delineated by USACE. Other map" figures. natural resources were included on figures as part of the Eco -Checklist referenced in Section 12 of the CSA. Data Presentation 78 Ensure that streams, wetlands, etc. shown in Section 12 are CAP Part 2 Section 2 figures included wetlands and streams as needed. included on all figures as needed. Data Presentation 79 Modify results tables to include field parameters DOs, Eh, spec Field parameters were included on the CAP Part 2 results tables, referenced in Section 2, as well as the CSA conductance, pH, NTU in all results tables. Supplement 2 results tables, referenced in Section 3. Surface, Groundwater Describe SW hydrology (streams, wetlands) in CAP and how CAP Part 2, Section 3 pertains to the Site Conceptual model, and it discusses surface water and seeps in Discharge 80 relates to seeps in CSM. relation to site source areas. Surface, Groundwater Check for alignment of description of streams and wetlands in CAP Part 2, Section 3 pertains to the Site Conceptual model, and it discusses surface water and seeps in Discharge 81 Section 12. relation to site source areas. CSA Supplement 2 Table 2-1: Responses to Global NCDEQ Comments CSA Supplement 2 CSA and CAP site maps include labels of major surface water bodies at each site. In addition, the CSA Surface, Groundwater Discharge 82 Show all surface water features on maps and cross sections. included surface water information in Figure 4-4: Surface Water Bodies. CAP Part 2 included Figure 3-1: Site Conceptual Model, and Figure 3-2: Cross Section with these features. Streamflow measurements have been incorporated into the expanded groundwater model domain Surface, Groundwater Discharge 83 Add wording on stream flow measurements performed. activities. The groundwater models are being updated and recalibrated including new data as it has becoms available and is expected to be completed during Fall 2016. Include non -trespassing recreation users of surface water and In the stand-alone Risk Assessment report, recreational swimmers, boaters, waders, and fishers are Risk Assessment 84 included in the receptors, as are current/future off-site residents. In addition, a separate risk assessment drinking water well receptors. has been provided subsequent to the CSA report by Duke Energy via Haley & Aldritch. Coal ash should be included as primary affected media until it is A separate risk assessment has been provided subsequent to the CSA report by Duke Energy via Haley & Risk Assessment 85 completely removed or otherwise made inaccessible to human contact. Revise Tables 12-1, 12-2, and wording in Section 12. Aldritch. Risk Assessment 86 Expand speciation results discussion with regards to receptors. A separate risk assessment has been provided subsequent to the CSA report by Duke Energy via Haley & Aldritch. Where 2L exceedances intercept rivers/streams implications Inadequate Data —All 87 should be discussed. Discuss vertical gradients for well pairs Vertical hydraulic gradients were calculated for Round 2 data, and were included in CAP Part 1. The Source Areas adjacent to rivers/streams. patterns in vertical gradients are discussed in CAP Part 2 Section 2.3.1.1. If a MW does not exist between a 2L exceedance and receptor Duke Energy has installed additional monitoring wells to address concerns to refine understanding of Inadequate Data — AII 88 (stream and water supply well) additional wells or transport exceedances. Results from the Round 5, including additional assessment wells, has been included in CSA Source Areas modeling is needed to fill data gap. Supplement 2. If uncertainty exists about local flow due to insufficient number or Duke Energy has installed additional monitoring wells to address concerns to refine understanding of Inadequate Data —All 89 placement of wells, then additional wells should be installed. exceedances. Results from the Round 5, including additional assessment wells, has been included in CSA Source Areas Same comment applies for uncertainty on vertical gradients. Supplement 2. CSA Supplement 2 Table 2-2: Total Porosity, Secondary (Effective) Porosity/Specific Yield, and Specific Storage for Lower Hydrostratigraphic Units (TZ and BR) Secondary (Effective) Hydrostratigraphic Unit Porosity / Specific Yield (%) Total Porosity (%) Specific Storage (1/ft) Transition Zone (TZ) 5.0-10.0 5-15 1.0E-06 - 2.1 E-05 Bedrock (BR) - Fractured 2.0-5.0 5-10 < 1.0E-06 Bedrock (BR) - Dense 0 - 3 0 - 5 < 1.0E-06 Notes: Ranges based on published values (Domenico and Mifflin, 1965; Singhal and Gupta, 2010). 2. Effective porosity and specific yield are not synonymous. For practical purposes, they may be estimated as approximately equal in value. 3. Table revised 07/13/2016. Cliffside Steam Station Page 1 of 1 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Cliffside Steam Station Page 1 of 32 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: AB -1D 4/18/2016 N CS -AB -1D AB -1S 4/18/2016 N CS -AB -1S AB -2D 4/14/2016 N CS -AB -2D AB -2S 4/14/2016 FD CS -FD -AB -2S AB -2S 4/14/2016 N CS -AB -2S AB-3BRU 4/13/2016 N CS-AB-3BRU AB -31 4/13/2016 N CS -AB -31 AB-4BR 4/13/2016 N CS-AB-4BR AB -4D 4/13/2016 N CS -AB -4D AB-5BR 3/7/2016 N CS -ABS -BR Constituent Fraction NCDEQ 02L GWQS, IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 5000 U 5000 U 5000 U 5000 U 5000 U 181000 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 68200 22200 36800 9700 11600 91200 70700 62500 8400 70900 Alkalinity, lab N ug/I 68200 22200 36800 9700 11600 273000 70700 62500 8400 70900 Aluminum D ug/I 100 U 100 U 100 U 100 U 100 U 2180 100 U 100 U 72.4 J 100 U Aluminum T ug/I 108 153 100 U 100 U 100 U 1540 70.3 J 100 U 83.6 J 100 U Antimony D ug/1 5 U 0.2 J 0.5 U 0.29 J 0.3 J 24.6 0.66 0.5 U 0.5 U 0.16 J Antimony T 1 IMAC ug/I 5 U 0.21 J 0.14 J 0.31 J 0.54 J 31.1 0.81 0.5 U 0.5 U 0.18 J Arsenic D -- ug/I 1 U 0.16 0.08 J 0.098 J 0.11 1 U 4.6 0.046 J 0.068 J 0.1 Arsenic T 10 02L ug/I 1 U 0.18 0.12 0.12 0.11 1 U 4.6 0.062 J 0.082 J 0.12 Barium D -- ug/I 11.7 57.2 38.9 41.9 42 168 141 5.1 16.1 9.5 Barium T 700 02L ug/I 13.7 62 36.3 36.7 37.4 106 156 5.3 15.5 10.1 Beryllium D -- ug/I 1 U 0.032 J 0.1 U 0.1 U 0.1 U 1 U 0.013 J 0.026 J 0.079 J 0.023 J Beryllium T 4 IMAC ug/I 1 U 0.069 J 0.037 J 0.036 J 0.1 U 0.37 J 0.039 J 0.018 J 0.05 J 0.019 J Boron D -- ug/I 591 50 U 159 164 164 50 U 83.4 27.5 J 50 U 50 U Boron T 700 02L ug/I 647 50 U 146 149 148 50 U 82.9 29.6 J 50 U 50 U Cadmium D -- ug/1 0.8 U 0.4 0.2 0.08 U 0.053 J 0.8 U 0.08 U 0.08 U 0.08 U 0.08 U Cadmium T 2 02L ug/1 0.8 U 0.46 0.08 U 0.059 J 0.058 J 0.8 U 0.055 J 0.08 U 0.08 U 0.08 U Calcium T -- ug/I 51200 6410 27600 5150 5350 74800 7270 16000 1200 24900 Carbon N -- ug/I 1000 U 1000 U 1000 U 1000 U 1000 U 3000 1000 U 1000 U 1000 U -- Chloride N 250000 02L ug/I 55600 14700 45300 47900 47000 3800 2400 3400 3200 1800 Chromium D -- ug/I 5 U 0.14 J 0.53 1.7 1.6 8.9 0.2 J 1.5 0.46 J 2.8 Chromium T 10 02L ug/1 5 U 0.25 J+ 0.74 4.3 J 2.5 J 12 0.35 J+ 0.7 0.94 20.4 Chromium 6+ T 0.07 DHHS ug/I 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 11.8 0.03 U 0.03 U 0.03 U 0.012 J Cobalt D -- ug/I 0.87 J 41 8.6 40.7 41 1 U 0.54 0.093 J 5.8 0.41 Cobalt T 1 IMAC ug/I 0.93 J 41.7 9.2 42.9 42.8 1 U 0.66 0.091 J 5.8 0.57 Copper D -- ug/1 5 U 2.6 0.5 U 2 J 3.5 J 8.1 25.5 0.39 J 2.8 0.38 J+ Copper T 1000 02L ug/I 5 U 0.26 J 0.5 U 0.66 0.32 J 17.1 0.81 0.25 J 0.63 0.64 Iron D -- ug/I 7140 323 19800 8900 8840 62.8 498 10600 63.5 810 Iron T 300 02L ug/I 7460 406 20500 8740 8730 50 U 68.3 11600 62.2 871 Lead D -- ug/I 1U 0.7 0.1U 0.1U 0.1U 1U 0.1U 0.1U 0.14 0.1U Lead T 15 02L ug/1 1 U 1.2 0.1 U 0.1 U 0.12 1 U 0.58 0.1 U 0.14 0.1 U Magnesium T - ug/I 7210 1820 5500 1960 1900 100 U 1150 2750 961 2700 Manganese D -- ug/I 2400 3760 3720 11800 11800 5 U 890 144 137 340 Manganese T 50 02L ug/I 2510 3970 3550 13800 13900 5 U 1050 148 126 370 Mercury D -- ug/1 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.83 0.2 U Mercury T 1 02L ug/1 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 UJ 0.2 UJ 0.2 U 6.8 0.2 U Methane N ug/I 828 33 12.5 19.1 19.7 10 U 10 U 249 387 21.7 Molybdenum D ug/I 5 U 0.5 U 0.15 J 0.5 U 0.5 U 18.1 3.1 0.19 J 0.5 U 0.8 Molybdenum T ug/I 5 U 0.5 U 0.18 J 0.5 U 0.5 U 17.8 2.7 0.21 J 0.5 U 1.2 Nickel D -- ug/I 5 U 2.2 2.2 5.1 5.3 5 U 0.5 U 0.78 1.5 2 Nickel T 100 02L ug/I 5 U 2.2 1.3 6.3 J 3.9 J 5 U 0.5 U 0.5 U 1.4 10 Nitrogen, NO2 plus NO3 N -- ug/I 20 U 20 U 20 U 20 U 20 U 140 20 U 20 U 180 20 U Potassium T ug/I 3510 J 3680 J 10200 2700 J 2840 J 70900 18900 5000 U 5000 U 3820 J Selenium D -- ug/I 5 U 1.3 0.5 U 0.4 J 0.7 J 5 U 1.5 0.5 U 0.33 J 0.5 U Selenium T 20 02L ug/1 5 U 1.3 0.5 U 0.66 J 0.54 J 5 U 0.38 J 0.5 U 0.36 J 0.5 U Sodium T -- ug/I 11700 5640 16500 16800 16500 29700 13200 5810 3140J 10100 Strontium D ug/I 200 19.8 238 29.8 29.8 773 138 95.8 10.4 66 Strontium T -- ug/I 219 22.1 218 24.9 27.8 452 132 97 9 71.3 Sulfate N 250000 02L ug/I 33600 2400 48000 15400 15100 69200 7000 4200 840J 11100 Sulfide N -- ug/I 100 U 100 U 100 U 100 U 100 U 100 UJ 100 UJ 100 U 100 U 100 U Thallium D -- ug/I 1 U 0.36 0.1 U 0.33 0.32 1 U 0.51 0.1 U 0.071 J 0.1 U Thallium T 0.2 IMAC ug/1 1 U 0.36 0.1 U 0.34 0.35 1 U 0.52 0.1 U 0.057 J 0.1 U Total Dissolved Solids N 500000 02L ug/I 234000 40000 211000 100000 115000 370000 92000 99000 25000 U 111000 Total Organic Carbon N -- ug/I -- -- -- -- -- -- -- -- -- 14300 Total Suspended Solids N ug/I 4000 4200 6900 3100 U 2500 U 2900 2500 U 2800 5000 U 4100 Uranium, Natural T ug/I 5 U 0.5 U 0.5 U 0.5 U 0.5 U -- -- -- -- -- Vanadium D -- ug/I 3 U 0.3 U 0.3 U 0.3 U 0.3 U 5.9 1.2 0.3 U 0.094 J 0.084 J Vanadium T 0.3 IMAC ug/1 3 U 0.23 J 0.3 U 0.3 U 0.3 U 6.3 0.81 J+ 0.09 J 0.3 U 0.18 J Zinc D -- ug/1 6.5 J 17.8 4.4 J+ 59 62 101-1 5.7 J 6.1 J 5.3 J 4.2 J+ Zinc T 1000 02L ug/I 5.8 J+ 15.5 J+ 6.9 J+ 56.6 63.4 10 U 8.8 J 3.1 J 3.7 J 5.5 J+ Dissolved Oxygen N -- mg/I 0.5 0.2 0.2 1.8 1.8 2.2 0.2 0.7 0.5 0.2 Oxidation Reduction Potential N mV -21.5 141 1 -52.7 127.3 127.3 1 -77.8 -9 -42.6 125.9 -166.2 Cliffside Steam Station Page 1 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 2 of 32 CSA Supplement 2 Location: AB -1D AB -1S AB -2D AB -2S AB -2S AB-313RU AB -31 AB-4BR AB -4D AB-5BR Date: 4/18/2016 4/18/2016 4/14/2016 4/14/2016 4/14/2016 4/13/2016 4/13/2016 4/13/2016 4/13/2016 3/7/2016 Sample Type: N N N FD N N N N N N Sample Name: CS -AB -1D CS -AB -1S CS -AB -2D CS -FD -AB -2S CS -AB -2S CS-AB-3BRU CS -AB -31 CS-AB-4BR CS -AB -4D CS -ABS -BR Event: NCDEQ 02L GWQS, Constituent Fraction GWQS Source Unit IMAC, or DHHS pH N 6.5-8.5 02L SU 6.3 5.8 6.4 6.4 6.4 11.8 7.1 6.3 5.3 7 Specific Conductivity N NS/cm 411.7 93.5 318.7 224.3 224.3 1339 160.9 152.6 37.7 189.7 Specific Conductivity N US/cm -- -- -- -- -- -- -- -- -- -- Temperature N Deg C 20.2 19.7 21 25.2 25.2 20.6 22.1 19.4 17.9 18.2 Turbidity, field N NTU 4.4 9.6 29.1 9.5 9.5 4.5 5.3 8.9 0.4 4.3 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 2 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Cliffside Steam Station Page 3 of 32 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: AB-5BRU 4/13/2016 N CS-AB-5BRU AB-6BR 4/13/2016 N CS-AB-6BR AB -6D 4/13/2016 N CS -AB -6D AS -1D 4/14/2016 N CS -AS -1D AS-1SB 4/14/2016 N CS-AS-1SB AS -21D 4/14/2016 N CS -AS -21D AS -2S 4/14/2016 N CS -AS -2S AS -2S 4/14/2016 FD CS -AS -2S -FD AS-3BRU 4/18/2016 N CS-AS-3BRU AS -41D 4/15/2016 N CS -AS -41D Constituent Fraction NCDEQ 02L GWQS, IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 10500 53700 8200 4300 J 5000 U 82000 5000 U 5000 U 6100 103000 Alkalinity, lab N ug/I 10500 53700 8200 4300 J 5000 U 82000 5000 U 5000 U 6100 103000 Aluminum D ug/I 100 U 100 U 100 U 100 U 1550 100 U 921 J 1020 100 U 100 U Aluminum T ug/I 100 U 100 U 100 U 189 2160 55.1 J 1150 1040 94.7 J 53.7 J Antimony D ug/I 0.5U 0.5U 0.5U 0.5U 5U 5U 5U 5U 0.13J 0.43J Antimony T 1 IMAC ug/I 0.21 J 0.5 U 0.5 U 0.5 U 5 U 5 U 5 U 5 U 0.11 J 0.46 J Arsenic D -- ug/I 0.47 0.1 0.042 J 0.066 J 6.7 2.1 8.4 7.9 0.1 U 0.53 Arsenic T 10 02L ug/I 0.65 0.11 0.1 U 0.1 8.9 2.3 7.7 9 0.051 J 0.8 Barium D -- ug/I 19.8 7 21.7 208 41 J 85.5 35.9 J 34.6 J 37.4 15.2 Barium T 700 02L ug/I 19.6 6.9 21.4 226 55.7 76.4 46.3 J 45.3 J 39.2 15.7 Beryllium D -- ug/I 0.023 J 0.032 J 0.1 U 0.18 5.7 1 U 0.19 J 1 UJ 0.055 J 0.1 U Beryllium T 4 IMAC ug/I 0.049 J 0.012 J 0.067 J 0.16 4.7 1 U 0.39 J 1 U 0.1 0.011 J Boron D -- ug/I 50 U 50 U 50 U 504 1390 241 684 J- 690 50 U 50 U Boron T 700 02L ug/I 50 U 50 U 50 U 554 1650 259 786 789 50 U 50 U Cadmium D -- ug/I 0.08 U 0.08 U 0.08 U 0.097 0.8 U 0.8 U 0.76 J 0.62 J 0.08 U 0.08 U Cadmium T 2 02L ug/I 0.08 U 0.08 U 0.08 U 0.15 0.8 U 0.8 U 0.75 J 0.76 J 0.08 U 0.08 U Calcium T -- ug/1 3420 12400 2220 13800 130000 72600 86600 86700 J+ 1430 40000 Carbon N -- ug/I 1000 U 1000 U 1000 U 1000 U 1000 U 12600 1000 U 1000 U 1000 U 1000 U Chloride N 250000 02L ug/I 3400 2900 3200 24200 47700 20900 38300 38200 5000 5800 Chromium D -- ug/I 0.17 J 0.33 J 0.16 J 0.58 1 J 7.5 5 U 5 U 0.26 J 1.1 Chromium T 10 02L ug/I 0.27 J 0.23 J 0.26 J 2 2.8 J 5 U 5 UJ 5 UJ 1.11 1.7 Chromium 6+ T 0.07 DHHS ug/I 0.03 U 0.03 U 0.021 J 0.17 0.032 0.12 0.086 0.077 0.03 U 1.3 Cobalt D -- ug/I 11.6 0.015 J 0.89 1.5 18.2 0.28 J 20.5 19.3 0.075 J 0.099 J Cobalt T 1 IMAC ug/I 10.2 0.013 J 0.87 2.1 21.9 0.18 J 18.9 21.2 0.073 J 0.11 Copper D -- ug/I 2.7 0.2 J 3.6 3.4 2.5 J 5 U 12.1 J 5.3 J 2 1.7 Copper T 1000 02L ug/I 2 0.5 U 0.88 3.6 5 U 5 U 5 U 5 U 0.59 J 0.91 Iron D -- ug/I 262 3160 50 U 30.5 J 288 J 267 500 U 500 U 50 U 50 U Iron T 300 02L ug/I 223 3300 50 U 207 753 252 500 U 500 U 48.9 J 50 U Lead D -- ug/I 0.1U 0.1U 0.1U 0.1U 1U 1U 1U 1U 0.11 0.1U Lead T 15 02L ug/I 0.1 U 0.1 U 0.1 U 0.37 1.1 1 U 1 U 1 U 0.12 0.1 U Magnesium T -- ug/I 1260 2390 1000 4370 13800 9780 23600 23800 J+ 620 1190 Manganese D -- ug/I 685 82 47 202 1800 160 7850 J- 7930 4.4 J 8.2 Manganese T 50 02L ug/I 566 78.5 46.1 233 2040 153 8800 8700 4.9 J 9 Mercury D -- ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U Mercury T 1 02L ug/I 0.2 U 0.2 U 0.2 U 0.13 J 0.2 U 0.2 U 0.086 J 0.086 J 0.2 U 0.2 U Methane N ug/I 10U 10 LI 10U 117 110 10U 10U 10U 10U 10U Molybdenum D ug/I 0.19 J 0.5 U 0.5 U 0.5 U 5 U 3.9 J 5 U 5 U 0.5 U 2.5 Molybdenum T ug/I 0.3 J 0.5 U 0.5 U 0.17 J 5 U 5.2 5 U 5 U 0.5 U 2.9 Nickel D -- ug/I 5 0.5 U 0.77 1.3 4.9 J 5.2 5 U 5 U 0.5 U 3 Nickel T 100 02L ug/I 4.7 0.5 U 0.63 1.6 6 5 U 5 U 5 U 0.74 2.1 Nitrogen, NO2 plus NO3 N -- ug/1 1000 20 U 1400 37 82 20 U 350 390 400 600 Potassium T ug/I 5000 U 2950 J 5000 U 7080 50000 U 12600 50000 U 50000 UJ 3150 J 11600 Selenium D -- ug/I 0.5 U 0.5 U 0.5 U 1.1 83.7 5 U 89.8 94 0.5 U 0.38 J Selenium T 20 02L ug/I 0.5 U 0.5 U 0.5 U 1.2 90 5 U 71.4 84.6 0.5 U 0.39 J Sodium T -- ug/I 4310 J 5680 3590 J 13100 12800 J 38200 10600 J 10600 J+ 3130 J 6960 Strontium D ug/I 33.4 115 27 151 118 346 157 151 18.6 88.1 Strontium T -- ug/I 34.3 109 26.6 164 136 363 174 174 19.5 89.8 Sulfate N 250000 02L ug/I 5800 3600 1100 49000 371000 209000 284000 283000 1000 U 11600 Sulfide N -- ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U Thallium D -- ug/I 0.13 0.1 U 0.058 J 0.2 0.37 J 1 U 0.18 J 1 U 0.033 J 0.1 U Thallium T 0.2 IMAC ug/1 0.12 0.1 U 0.055 J 0.24 0.48 J 1 U 0.27 J 0.32 J 0.033 J 0.1 U Total Dissolved Solids N 500000 02L ug/I 25000 U 81000 25000 U 138000 633000 395000 485000 516000 30000 139000 Total Organic Carbon N -- ug/I -- -- -- -- -- -- -- -- -- -- Total Suspended Solids N ug/I 2500 U 2500 U 2500 U 14000 10500 3300 U 2500 U 2500 U 3300 2500 U Uranium, Natural T ug/I -- -- -- -- -- - 5 U 5 U -- -- Vanadium D -- ug/I 0.27 J 0.3 U 0.3 U 0.3 U 3 U 1.3 J 3 U 3 U 0.13 J 1.6 Vanadium T 0.3 IMAC ug/1 0.39 0.3 U 0.3 U 0.36 3 U 0.97 J 3 U 3 U 0.1 J 1.9 Zinc D -- ug/I 8.7 J 10 U 3.5 J 9.1 J 83.3 J 2.8 J 25.3 J 100 U 6.5 J 13.7 Zinc T 1000 02L ug/I 7.1 J 10 U 10 U 4.8 J 89.3 J 4.8 J 100 U 100 U 5.5 J+ 6.4 J Dissolved Oxygen N mg/I 2.7 0.3 3.6 0.3 0.07 0.9 1.9 1.9 6.8 2.5 Oxidation Reduction Potential N mV 169.3 -3.3 176.1 103.1 213.9 -207.8 602 602 101.3 163.1 Cliffside Steam Station Page 3 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 4 of 32 CSA Supplement 2 Location: AB-51BRU AB-6BR AB -6D AS -1D AS-1SB AS -21D AS -2S AS -2S AS-31BRU AS -41D Date: 4/13/2016 4/13/2016 4/13/2016 4/14/2016 4/14/2016 4/14/2016 4/14/2016 4/14/2016 4/18/2016 4/15/2016 Sample Type: N N N N N N N FD N N Sample Name: CS-AB-5BRU CS-AB-6BR CS -AB -6D CS -AS -1D CS-AS-1SB CS -AS -2D CS -AS -2S CS -AS -2S -FD CS-AS-31BRU CS -AS -41D Event: NCDEQ 02L GWQS, Constituent Fraction GWQS Source Unit IMAC, or DHHS pH N 6.5-8.5 02L SU 5.7 6.4 5.4 5.6 4.5 8.8 4.3 4.3 5.3 6.7 Specific Conductivity N NS/cm 61.2 123.5 46.5 228.2 899 695 745 745 41.2 251.3 Specific Conductivity N US/cm -- -- -- -- -- -- -- -- -- -- Temperature N Deg C 20.5 19.9 20.9 20.1 20.2 17 15.8 15.8 17.6 14.3 Turbidity, field N NTU 1 4.68 0.7 9.5 9.92 2.4 3.6 3.6 5.7 2.7 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 4 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Cliffside Steam Station Page 5 of 32 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: AS-5BR 4/15/2016 N CS-AS-5BR AS-5BRU 4/15/2016 N CS-AS-5BRU AS -5S 4/18/2016 N CS -AS -SS AS-6BR 4/15/2016 N CS-AS-6BR AS -6D 4/15/2016 N CS -AS -6D AS -6S 4/15/2016 N CS -AS -6S AS-7BR 4/14/2016 N CS-AS-7BR AS -7D 4/14/2016 FD CS -AS -7D -FD AS -7D 4/14/2016 N CS -AS -7D BG -1 BR 3/28/2016 N CS -BG -1 BR Constituent Fraction NCDEQ 02L GWQS, IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 5000 U 5000 U 5000 U 395000 5000 U 5000 U 623000 5000 U 5000 U 3500 J Alkalinity, HCO3 N ug/I 52600 13100 5700 161000 12500 11900 5000 U 10400 12700 73800 Alkalinity, lab N ug/I 52600 13100 5700 556000 12500 11900 1130000 10400 12700 77300 Aluminum D ug/I 106 100 U 52.6 J 310 100 U 60.2 J 1570 100 U 100 U 100 U Aluminum T ug/I 131 164 405 963 100 U 1780 J+ 1780 59.5 J 100 U 100 U Antimony D ug/I 1.3 0.1 J 0.5 U 3.4 J 0.11 J 0.14 J 4.4 J 0.2 J 0.19 J 0.43 J Antimony T 1 IMAC ug/I 1.6 0.13 J 0.5 U 8.5 0.19 J 0.2 J 4.2 J 0.37 J 0.23 J 0.53 Arsenic D -- ug/I 0.56 0.16 0.1 U 1 U 0.1 U 0.36 1 U 0.13 0.12 2.1 Arsenic T 10 02L ug/I 0.52 0.24 0.074 J 1.1 0.051 J 1 0.42 J 0.28 0.22 2 Barium D -- ug/I 12.5 7.2 24.3 130 12.5 25.3 1280 97.5 97.3 13 Barium T 700 02L ug/I 13.4 8.2 28.3 139 13.2 50.9 1370 108 114 15.9 Beryllium D -- ug/I 0.1 U 0.027 J 0.072 J 1 U 0.1 U 0.067 J 0.27 J 0.017 J 0.1 U 0.02 J Beryllium T 4 IMAC ug/I 0.1 U 0.03 J 0.09 J 1 U 0.068 J 0.23 0.26 J 0.075 J 0.064 J 0.1 U Boron D -- ug/I 50 U 50 U 50 U 50 U 50 U 50 U 50 U 487 486 50 U Boron T 700 02L ug/I 50 U 50 U 50 U 50 U 50 U 50 U 50 U 534 533 50 U Cadmium D -- ug/I 0.08 U 0.08 U 0.08 U 0.8 U 0.08 U 0.055 J 0.8 U 0.26 0.24 0.08 U Cadmium T 2 02L ug/I 0.08 U 0.08 U 0.092 0.8 U 0.08 U 0.13 0.8 U 0.28 0.2 0.08 U Calcium T -- ug/1 19000 2350 654 242000 2540 2460 281000 31800 32400 23400 Carbon N -- ug/I 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 9200 1000 U 1000 U -- Chloride N 250000 02L ug/I 1600 1300 1500 1600 1500 2400 1800 32000 32400 1800 J+ Chromium D -- ug/I 3.6 0.23 J 0.18 J+ 4.9 J 0.22 J 1.7 2.5 J 0.65 0.66 0.29 J+ Chromium T 10 02L ug/I 5.9 10.2 0.49 J+ 7 1.6 10.3 4.5 J 1.5 1.1 0.35 J+ Chromium 6+ T 0.07 DHHS ug/I 4.6 0.03 U 0.03 U 9.3 0.03 U 0.03 U 5.6 0.31 0.14 0.12 Cobalt D -- ug/I 0.023 J 0.062 J 0.26 1 U 0.079 J 2.1 0.11 0.16 0.15 0.039 J Cobalt T 1 IMAC ug/I 0.041 J 0.28 0.33 1 U 0.12 3.1 0.21 J 0.24 0.17 0.066 J+ Copper D -- ug/I 0.39 J 0.76 2.1 3.1 J 1.2 0.87 5.6 1.4 1 7.6 Copper T 1000 02L ug/I 0.88 1.4 0.19 J 5 U 0.84 2.8 4.8 J 0.41 J 0.28 J 0.63 J+ Iron D -- ug/I 50 U 50 U 50 U 50 U 50 U 500 50 U 50 U 50 U 60 Iron T 300 02L ug/I 50 U 226 251 69.8 46.4 J 2560 J+ 48 J 104 70 61.2 Lead D -- ug/I 0.1U 0.1U 0.1U 1U 0.1U 0.76 1U 0.1U 0.1U 1.2 Lead T 15 02L ug/I 0.1 U 0.27 0.44 1 U 0.1 U 6.7 1 U 0.12 0.1 U 0.1 U Magnesium T -- ug/I 418 425 519 149 578 1080 100 U 7470 7450 1870 Manganese D -- ug/I 6.1 14.9 37.9 5 U 10.9 532 5 U 830 829 23 Manganese T 50 02L ug/I 6.1 26.1 41.9 3J 11.4 600 5 U 941 847 21.7 Mercury D -- ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U Mercury T 1 02L ug/I 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U Methane N ug/I 10 U 10 U 10 U 30.7 10 U 10 U 10 U 87 79.9 1.5 J+ Molybdenum D ug/I 2.6 0.5 U 0.5 U 8.4 0.5 U 0.51 13.2 0.35 J 0.38 J 1.7 Molybdenum T ug/I 3.2 0.29 J+ 0.5 U 9.5 0.11 J+ 0.78 J+ 15.4 0.35 J 0.21 J 1.8 Nickel D -- ug/I 0.72 0.86 0.98 5 U 0.84 2.9 5 U 3.5 3.4 0.49 J Nickel T 100 02L ug/I 1.5 6 0.5 U 5 U 1.7 6.1 5 U 4 3.9 0.5 U Nitrogen, NO2 plus NO3 N -- ug/1 320 260 120 20 U 420 310 20 U 66 46 120 J+ Potassium T ug/I 9450 5000 U 5000 U 3690 J 5000 U 5000 U 282000 7330 7680 19400 Selenium D -- ug/I 0.39 J 0.5 U 0.5 U 5 U 0.5 U 0.35 J 5 U 0.59 0.56 0.52 Selenium T 20 02L ug/11 0.38 J 0.5 U 0.5 U 5 U 0.5 U 2.7 5 U 0.9 0.83 0.5 U Sodium T -- ug/I 8470 4130 J 1690 J 11600 3640 J 4400 J 77400 13700 14100 12100 Strontium D ug/I 83.3 20.4 4.9 J 437 24.9 22 8800 220 220 140 Strontium T -- ug/I 92.6 21.2 4.9 J 450 25.1 28.8 9170 239 249 156 Sulfate N 250000 02L ug/I 14500 420 J 1000 U 6100 1000 U 850 J 8200 88100 85600 18900 Sulfide N -- ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U Thallium D -- ug/I 0.1 U 0.1 U 0.059 J 1 U 0.1 U 0.055 J 1 U 0.08 J 0.08 J 0.1 U Thallium T 0.2 IMAC ug/1 0.1 U 0.1 U 0.062 J 1 U 0.1 U 0.14 1 U 0.084 J 0.064 J 0.1 U Total Dissolved Solids N 500000 02L ug/I 96000 33000 30000 300000 34000 77000 12600000 207000 207000 178000 Total Organic Carbon N -- ug/I -- -- -- -- -- -- -- -- -- 1000 U Total Suspended Solids N ug/I 2800 4900 13400 J 132000 2600 U 169000 5000 U 3600 2500 U 2600 U Uranium, Natural T ug/I -- -- -- -- -- -- -- -- -- 0.22 J Vanadium D -- ug/I 1.8 0.087 J 0.3 U 3.4 0.12 J 0.2 J 2.1 J 0.12 J 0.1 J 2.8 Vanadium T 0.3 IMAC ug/1 2.1 0.43 0.17 J 8 0.16 J 1.9 2.3 J 0.2 J 0.16 J 3.3 Zinc D -- ug/I 10 U 91 7.8 J 10 U 13.4 99.4 31.4 9.2 J 8.9 J 14 J+ Zinc T 1000 02L ug/I 10 U 11.3 4.4 J 11.3 9.9 J 208 37.4 8.8 J 7.9 J 4.7 J+ Dissolved Oxygen N -- mg/I 2.1 2.6 7.23 1 4.6 3.6 0.96 0.4 0.4 2.6 Oxidation Reduction Potential N mV 88.1 195.6 285 37.6 225.5 114.7 -90.1 57.3 57.3 164 Cliffside Steam Station Page 5 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 6 of 32 CSA Supplement 2 Location: AS-5BR AS-51BRU AS -5S AS-6BR AS -61D AS -6S AS-7BR AS -71D AS -71D BG -1 BR Date: 4/15/2016 4/15/2016 4/18/2016 4/15/2016 4/15/2016 4/15/2016 4/14/2016 4/14/2016 4/14/2016 3/28/2016 Sample Type: N N N N N N N FD N N Sample Name: CS-AS-5BR CS-AS-51BRU CS -AS -SS CS-AS-6BR CS -AS -6D CS -AS -6S CS-AS-7BR CS -AS -7D -FD CS -AS -7D CS -BG -1 BR Event: NCDEQ 02L GWQS, Constituent Fraction GWQS Source Unit IMAC, or DHHS pH N 6.5-8.5 02L SU 9.7 5.8 5.41 12.3 6.1 5.9 12.5 6 6 9.3 Specific Conductivity N NS/cm 155 37.6 24 2637 38.7 45.6 5256 332.2 332.2 209 Specific Conductivity N US/cm -- -- -- -- -- -- -- -- -- 209 Temperature N Deg C 17.5 17.4 18 17.9 14.4 19.5 20.4 20.1 20.1 18 Turbidity, field N NTU 4.9 8.88 8.44 40.6 3.3 88.2 4.2 4.6 4.6 2.4 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 6 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Cliffside Steam Station Page 7 of 32 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: BG -1D 3/28/2016 FD CS -BG -1D -FD BG -1D 3/28/2016 N CS -BG -1D BG -1S 3/28/2016 N CS -BG -1S BG -2D 3/29/2016 N CS -BG -2D CCP-MW1D 3/30/2016 N CD-CCPMW-1D CCP-MW1S 3/30/2016 N CD-CCPMW-1S CLMW-2 4/14/2016 N CS-CLMW-2 CLMW-3D 4/14/2016 N CS-CLMW3-D CLMW-3S 4/14/2016 N CS-CLMW-3S CLMW-5S 4/18/2016 N CS-CLMW-5S Constituent Fraction NCDEQ 02L GWQS, IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 8000 8000 1100 J 52300 J+ 4500 J+ 1000 J+ 5000 U 3300 J 5000 U 7400 Alkalinity, lab N ug/I 8000 8000 1100 J 52900 J+ 4500 J+ 1000 J+ 5000 U 3300 J 5000 U 7400 Aluminum D ug/I 100 U 100 U 100 U 69 J 100 U 51 J 1470 100 U 1680 100 U Aluminum T ug/I 100 U 100 U 196 208 J+ 100 U 77.7 J+ 1550 153 1760 104 Antimony D ug/I 0.5 U 0.5 U 0.5 U 0.71 0.5 U 0.5 U 0.17 J 5 U 0.28 J 0.88 Antimony T 1 IMAC ug/I 0.5 U 0.5 U 0.5 U 1 J+ 0.5 U 0.5 U 0.17 J 5 U 0.51 1 Arsenic D -- ug/I 0.042 J 0.05 J 0.052 J 2 0.1 U 0.1 U 0.89 1 U 1.8 0.097 J Arsenic T 10 02L ug/I 0.088 J 0.072 J 0.077 J 4 0.1 U 0.1 U 0.96 1 U 2 0.15 Barium D -- ug/I 15 15 120 6.6 15 26 57 45.1 20.7 58.5 Barium T 700 02L ug/I 15.3 15.8 128 7.1 J+ 14.3 J+ 28.6 J+ 57.6 51.3 22 62.4 Beryllium D -- ug/I 0.1 U 0.1 U 0.31 0.1 U 0.014 J 0.078 J 0.91 0.16 J 1.3 0.052 J Beryllium T 4 IMAC ug/I 0.03 J 0.1 U 0.22 0.1 U 0.1 U 0.052 J 0.76 0.16 J 1.5 0.07 J Boron D -- ug/I 50 U 50 U 50 U 50 U 50 U 50 U 266 449 561 50 U Boron T 700 02L ug/I 50 U 50 U 50 U 50 U 50 U 50 U 278 506 561 50 U Cadmium D -- ug/I 0.08 U 0.08 U 0.11 0.08 U 0.08 U 0.08 U 0.57 0.8 U 0.36 0.13 Cadmium T 2 02L ug/I 0.06 J 0.08 U 0.087 0.08 U 0.08 U 0.08 U 0.56 0.8 U 0.47 0.24 Calcium T -- ug/1 2410 J+ 2410 J+ 645 J+ 13800 J+ 2240 J+ 166 J+ 20200 56400 26300 2470 Carbon N -- ug/I -- -- -- -- -- -- 1000 U 1000 U 1000 U 1000 U Chloride N 250000 02L ug/I 2500 J+ 2500 J+ 12200 J+ 8000 J+ 5700 3800 39400 42100 40700 15100 Chromium D -- ug/I 0.13 J+ 0.18 J+ 0.49 J+ 1 0.3 J 0.89 0.88 5 U 0.26 J 0.34 J Chromium T 10 02L ug/I 0.18 J+ 0.15 J+ 0.7 J+ 2.8 J+ 0.36 J+ 2.2 J+ 5.3 4 J 0.42 J+ 0.5 Chromium 6+ T 0.07 DHHS ug/I 0.012 J 0.03 U 0.048 J- 0.32 0.083 J+ 0.11 J+ 0.16 0.09 0.058 0.03 U Cobalt D -- ug/I 2.5 2.5 8.3 0.035 J 0.41 1.7 13.7 1 U 31 32.1 Cobalt T 1 IMAC ug/I 2.8 2.8 8.8 0.1 J+ 0.44 1.9 14.3 0.29 J 38.8 34 Copper D -- ug/I 4.9 J+ 4.9 J+ 6.9 0.97 0.79 J+ 1.1 J+ 6.2 1.6 J 6.1 17.4 Copper T 1000 02L ug/I 5 5 0.54 J+ 2.3 J+ 0.3 J+ 0.23 J+ 0.55 5 U 5.4 13.6 Iron D -- ug/I 50 U 50 U 50 U 50 U 50 U 50 U 25.6 J 56.2 50 U 108 Iron T 300 02L ug/I 50 U 33.4 J 254 741 J+ 50 U 61.4 J+ 47.1 J 245 41.7 J 171 Lead D -- ug/I 0.17 0.17 0.1 U 0.1 U 0.1 U 0.1 U 0.35 1 U 0.3 0.37 Lead T 15 02L ug/I 0.22 0.22 0.13 0.41 J+ 0.1 U 0.1 U 0.36 1 U 0.39 1.1 Magnesium T -- ug/I 1040 1030 2260 648 J+ 1520 J+ 913 J+ 28500 23400 26600 1140 Manganese D -- ug/I 57 57 96 5 U 7.5 18 923 29.3 877 2580 Manganese T 50 02L ug/I 64.7 64.5 101 3.7 J 7.3 J+ 19.4 J+ 1020 43.2 952 2660 Mercury D -- ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U Mercury T 1 02L ug/I 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U Methane N ug/I 2.6 J+ 2.6 J+ 10 U 2.3 J+ 1.7 J+ 1.6 J+ 101-1 10 U 10 U 62.8 Molybdenum D ug/I 0.5 U 0.5 U 0.5 U 0.61 0.5 U 0.5 U 0.5 U 5 U 0.5 U 0.5 U Molybdenum T ug/I 0.5 U 0.5 U 0.5 U 1.2 J+ 0.5 U 0.5 U 0.17 J 5 U 0.16 J 0.5 U Nickel D -- ug/I 5.3 5.3 2 0.5 U 1 1.3 3.7 5 U 1.5 2.4 Nickel T 100 02L ug/I 5.8 6.1 2.2 0.62 J+ 1 1.7 5.7 5 U 1.7 2.4 Nitrogen, NO2 plus NO3 N -- ug/1 1200 1500 2200 220 J+ 920 17J 180 95 140 20 U Potassium T ug/I 5000 U 5000 U 5000 U 2530 J 5000 U 5000 U 11100 8630 7620 2780 J Selenium D -- ug/I 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 13.7 5J 28 0.48 J Selenium T 20 02L ug/I 0.5 U 0.5 U 0.46 J 0.5 U 0.5 U 0.42 J 14.2 4.9 J 32.4 0.72 Sodium T -- ug/I 4380 J 4380 J 6680 23500 J+ 2540 J 5000 U 15100 15800 10800 6760 Strontium D ug/I 32 32 17 47 19 2.9 J 60.4 305 40.4 23.2 Strontium T -- ug/I 32.3 32.6 17.8 J+ 51.2 J+ 18.7 2.9 J 61.8 338 46.4 26.9 Sulfate N 250000 02L ug/I 3800 J+ 3700 J+ 1000 U 28600 J+ 1700 740 J 172000 208000 189000 2500 Sulfide N -- ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U Thallium D -- ug/I 0.1 U 0.1 U 0.06 J 0.1 U 0.1 U 0.1 U 0.39 1 U 0.28 0.24 Thallium T 0.2 IMAC ug/1 0.035 J 0.018 J 0.074 J 0.1 U 0.1 U 0.1 U 0.4 1 U 0.34 0.26 Total Dissolved Solids N 500000 02L ug/I 48000 53000 54000 131000 J+ 25000 U 25000 U 198000 378000 365000 29000 Total Organic Carbon N -- ug/I 1000 U 1000 U 1000 U 2700 J+ 1000 U 1000 U -- -- -- -- Total Suspended Solids N ug/I 5000 U 2500 U 2800 25800 2500 U 2500 U 2500 U 4500 2500 U 2500 U Uranium, Natural T ug/I 0.5 U 0.5 U 0.5 U 0.71 0.5 U 0.5 U -- -- -- -- Vanadium D -- ug/I 0.3 U 0.073 J 0.3 U 7.1 0.3 U 0.3 U 0.3 U 3 U 0.3 U 0.3 U Vanadium T 0.3 IMAC ug/1 0.098 J 0.091 J 0.25 J 15 0.3 U 0.086 J 0.12 J 3 U 0.079 J 0.24 J Zinc D -- ug/I 5.9 J+ 8.6 J+ 18J+ 10 U 10 U 2.9 J 78 23.5 63.8 52 Zinc T 1 1000 1 02L ug/I 6.4 J+ 9.1 J+ 11 J+ 6J+ 10 U 4J 88.8 24.7 73.1 41.2 Dissolved Oxygen N mg/I 3.3 3.3 5.3 2.3 7.3 7.8 0.8 0.42 1.5 0.4 Oxidation Reduction Potential N mV 279 279 359 53 305 313 370.3 264 445.2 212.5 Cliffside Steam Station Page 7 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 8 of 32 CSA Supplement 2 Location: BG -1D BG -1D BG -1S BG -2D CCP-MW1D CCP-MW1S CLMW-2 CLMW-3D CLMW-3S CLMW-5S Date: 3/28/2016 3/28/2016 3/28/2016 3/29/2016 3/30/2016 3/30/2016 4/14/2016 4/14/2016 4/14/2016 4/18/2016 Sample Type: FD N N N N N N N N N Sample Name: CS -BG -1D -FD CS -BG -1D CS -BG -1S CS -BG -2D CD-CCPMW-1D CD-CCPMW-1S CS-CLMW-2 CS-CLMW3-D CS-CLMW-3S CS-CLMW-5S Event: NCDEQ 02L GWQS, Constituent Fraction GWQS Source Unit IMAC, or DHHS pH N 6.5-8.5 02L SU 5.8 5.8 4.7 9.1 5.3 5 4.1 5.14 4.5 5.2 Specific Conductivity N NS/cm 51 51 75 219 49 24 518.8 577 568 82.4 Specific Conductivity N US/cm -- 51 75 219 49 24 -- -- -- -- Temperature N Deg C 17 17 16 16 17 16 17.5 17 18.9 22.9 Turbidity, field N NTU 1 1 8.1 13 2 4 1.5 6.79 4 6.1 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 8 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Cliffside Steam Station Page 9 of 32 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: CLMW-6 4/13/2016 N CS-CLMW-6 GWA-10D 4/15/2016 N CS-GWA-10D GWA-10S 4/15/2016 N CS-GWA-10S GWA-11BRU 4/15/2016 N CS-GWA-11BRU GWA-11S 4/15/2016 N CS-GWA-11S GWA-12BRU 4/15/2016 N CS-GWA-12BRU GWA-12S 4/15/2016 N CS-GWA-12S GWA-14D 4/14/2016 N CS-GWA-14D GWA-14S 4/14/2016 N CS-GWA-14S GWA-1BRU 4/14/2016 N CS-GWA-1BRU Constituent Fraction NCDEQ 02L GWQS, IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 4600 J 80200 4300 J 81900 66800 37200 19900 119000 74800 67800 Alkalinity, lab N ug/I 4600 J 80200 4300 J 81900 66800 37200 19900 119000 74800 67800 Aluminum D ug/I 100 U 74 J 601 100 U 100 U 100 U 100 U 100 U 100 U 100 U Aluminum T ug/I 100 U 108 1040 100 U 100 U 100 U 100 U 100 U 200 69.4 J Antimony D ug/I 0.5U 0.14J 5U 5U 5U 0.5U 0.5U 5U 5U 0.5U Antimony T 1 IMAC ug/I 0.5 U 0.5 U 5 U 5 U 5 U 0.5 U 0.5 U 5 U 5 U 0.5 U Arsenic D -- ug/I 0.04 J 0.19 2 1 U 0.6 J 0.24 0.07 J 1 U 1 U 0.18 Arsenic T 10 02L ug/I 0.048 J 0.17 2 1 U 0.52 J 0.43 0.071 J 1 U 1 U 0.21 Barium D -- ug/I 23.6 78 27.3 12.9 46.2 6.4 13.3 77.6 85.6 3.5 J Barium T 700 02L ug/I 23.2 82 27.7 13.2 45.7 7.1 14.1 77.6 97 4.4 J Beryllium D -- ug/I 0.025 J 0.1 U 1.1 0.11 J 1 U 0.019 J 0.011 J 0.19 J 1 UJ 0.1 UJ Beryllium T 4 IMAC ug/I 0.049 J 0.1 U 0.59 J 1 U 1 U 0.011 J 0.1 U 1 U 0.15 J 0.1 U Boron D -- ug/I 50 U 50 U 275 321 318 50 U 50 U 48.1 J 52.5 50 U Boron T 700 02L ug/I 50 U 50 U 275 332 315 50 U 50 U 52.5 55.4 50 U Cadmium D -- ug/I 0.08 U 0.08 U 0.8 U 0.8 U 0.8 U 0.08 U 0.08 U 0.8 U 0.8 U 0.08 U Cadmium T 2 02L ug/I 0.08 U 0.08 U 0.8 U 0.8 U 0.8 U 0.08 U 0.08 U 0.8 U 0.8 U 0.08 U Calcium T -- ug/1 1060 29500 53200 66400 90400 8890 11000 98200 55700 23700 Carbon N -- ug/I 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U Chloride N 250000 02L ug/I 2800 6500 23800 23600 24100 4900 15500 8400 5900 3700 Chromium D -- ug/I 0.87 0.94 1.6 J 5 U 5 U 0.16 J+ 0.29 J+ 5 U 1.5 J 0.89 Chromium T 10 02L ug/I 0.33 J 0.62 J 3.1 J 5 U 5 U 0.23 J+ 0.37 J+ 1.2 J+ 2.6 J 0.38 J Chromium 6+ T 0.07 DHHS ug/I 0.091 0.33 2.3 0.03 U 0.03 U 0.03 U 0.07 0.99 1.6 0.03 U Cobalt D -- ug/I 13.6 2.3 0.86 J 0.47 J 1.1 2.1 0.04 J 0.16 J 0.37 J 0.12 Cobalt T 1 IMAC ug/I 12.3 2.2 1.2 0.5 J 1.1 2.6 0.046 J 0.27 J 0.89 J 0.26 Copper D -- ug/I 1.7 1.1 2.3 J 5 U 5 U 0.5 U 1.7 5 U 5 U 0.79 Copper T 1000 02L ug/I 0.14 J 0.14 J 5 U 5 U 5 U 0.5 U 0.5 U 5 U 5 U 0.7 Iron D -- ug/I 50 U 50 U 50 U 452 43.6 J 406 50 U 129 50 U 234 Iron T 300 02L ug/I 34.6 J 50 U 140 524 62.2 474 50 U 50 U 230 311 Lead D -- ug/I 0.1U 0.1U 1U 1U 1U 0.1 LI 0.1U 1U 1U 0.1 LI Lead T 15 02L ug/I 0.1 LI 0.1U 1U 1U 1U 0.1U 0.1U 1U 1U 0.16 Magnesium T -- ug/I 744 4300 11600 13200 16200 4430 4050 26500 16700 1380 Manganese D -- ug/I 170 104 197 844 1910 48.9 5 U 6.2 23.9 85.2 Manganese T 50 02L ug/I 170 102 193 855 1810 52.8 5 U 10.1 33.6 177 Mercury D -- ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U Mercury T 1 02L ug/I 0.16J 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U Methane N ug/I 25 10 LI 10U 10U 10U 10U 10U 10U 10U 10U Molybdenum D ug/I 0.5 U 0.75 5 U 5 U 14.9 0.5 U 0.5 U 5 U 5 U 0.68 Molybdenum T ug/I 0.5 U 0.73 5 U 5 U 15.1 0.12 J+ 0.5 UJ 5 U 5 U 0.7 Nickel D -- ug/I 1.9 2.1 6 5 U 5 U 4.8 0.5 U 5 U 5 U 1.5 Nickel T 100 02L ug/I 1.2 1.7 7.2 5 U 5 U 5.5 0.5 U 5 U 5 U 0.86 Nitrogen, NO2 plus NO3 N -- ug/1 890 94 780 28 180 20 U 250 2300 4200 20 U Potassium T ug/I 5000 U 3840 J 4370 J 9650 8710 2590 J 5000 U 5860 3630 J 5000 U Selenium D -- ug/I 0.5 U 0.5 U 24 5 U 5 U 0.5 U 0.81 5 U 5 U 0.5 U Selenium T 20 02L ug/I 0.5 U 0.5 U 26.9 5 U 5 U 0.5 U 0.63 5 U 5 U 0.5 U Sodium T -- ug/I 3000 J 8120 9730 16200 14800 6890 6580 6700 4360 J 5890 Strontium D ug/I 14.6 401 323 293 971 43 15 241 101 45 Strontium T -- ug/I 14.1 395 334 298 988 43.6 18.1 244 110 48 Sulfate N 250000 02L ug/I 750 J 15500 172000 132000 204000 8400 13700 227000 118000 7000 Sulfide N -- ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U Thallium D -- ug/I 0.061J 0.1U 1U 1U 1U 0.1U 0.1U 1U 1U 0.1U Thallium T 0.2 IMAC ug/1 0.051J 0.1 LI 1U 1U 1U 0.1U 0.1U 1U 1U 0.1U Total Dissolved Solids N 500000 02L ug/I 25000 U 152000 335000 348000 425000 82000 68000 456000 260000 96000 Total Organic Carbon N -- ug/I -- -- -- -- -- -- -- -- -- -- Total Suspended Solids N ug/I 2500 U 2500 U 2500 U 2500 U 2500 U 2500 U 2500 U 2500 U 7500 2500 U Uranium, Natural T ug/I -- 0.5 U 5 U 5 U 5 U - -- -- -- -- Vanadium D -- ug/I 0.094 J 0.82 3 U 3 U 3 U 0.3 U 0.3 U 3 U 3 U 0.13 J Vanadium T 0.3 IMAC ug/1 0.13 J 0.76 3 U 3 U 3 U 0.3 U 0.3 U 3 U 1.5 J 0.21 J Zinc D -- ug/I 5.4 J 5.3 J+ 4.6 J+ 3.2 J+ 3.2 J+ 7.1 J 5.2 J 3.5 J 3.2 J 3.1 J Zinc T 1000 02L ug/I 10U 10U 10U 10U 10U 20 10U 10U 10U 2.8J Dissolved Oxygen N mg/I 1.3 -- -- 1.9 3 1.3 3 1.7 Oxidation Reduction Potential N mV 316 5.2 252.8 201.9 228.4 21.8 Cliffside Steam Station Page 9 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 10 of 32 CSA Supplement 2 Location: CLMW-6 GWA-10D GWA-10S GWA-11BRU GWA-11S GWA-12BRU GWA-12S GWA-14D GWA-14S GWA-1BRU Date: 4/13/2016 4/15/2016 4/15/2016 4/15/2016 4/15/2016 4/15/2016 4/15/2016 4/14/2016 4/14/2016 4/14/2016 Sample Type: N N N N N N N N N N Sample Name: CS-CLMW-6 CS-GWA-10D CS-GWA-10S CS-GWA-11BRU CS-GWA-11S CS-GWA-12BRU CS-GWA-12S CS-GWA-14D CS-GWA-14S CS-GWA-1BRU Event: NCDEQ 02L GWQS, Constituent Fraction GWQS Source Unit IMAC, or DHHS pH N 6.5-8.5 02L SU 5.3 6.1 5.7 6 5.9 7.3 Specific Conductivity N NS/cm 34.5 119 137.7 676 433.2 155.5 Specific Conductivity N US/cm -- -- -- -- -- -- Temperature N Deg C 16.1 22.7 17 21.8 24.2 16.3 Turbidity, field N NTU 4.2 0.7 1 1 8.6 7.4 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 10 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Cliffside Steam Station Page 11 of 32 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: GWA-20D 4/14/2016 N CS-GWA-20D GWA-20S 4/14/2016 N CS-GWA-20S GWA-21BR 4/18/2016 N CS-GWA-21BR GWA-21BRU 4/18/2016 N CS-GWA-21BRU GWA-21S 4/18/2016 N CS-GWA-21S GWA-22BRU 4/19/2016 N CS-GWA-22BRU GWA-22S 4/19/2016 N CS-GWA-22S GWA-23D 4/19/2016 N CS-GWA-23D GWA-24BR 4/21/2016 N CS-GWA-24BR GWA-24D 4/15/2016 FD CS-FD-GWA-24D Constituent Fraction NCDEQ 02L GWQS, IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 5000 U 5000 U 5000 U 5000 U 5000 U 119000 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 19300 133000 181000 36800 10200 7800 23000 2400 J 16000 10800 Alkalinity, lab N ug/I 19300 133000 181000 36800 10200 127000 23000 2400 J 16000 10800 Aluminum D ug/I 100 U 100 U 100 U 100 U 59.7 J 316 135 60.6 J 100 U 100 U Aluminum T ug/I 100 U 356 103 68.3 J 51.1 J 483 183 515 110 100 U Antimony D ug/I 0.5U 5U 5U 0.5U 0.5U 0.111 0.5U 0.14J 0.5U 0.5U Antimony T 1 IMAC ug/I 0.5 U 5 U 5 U 0.5 U 0.5 U 0.1 J 0.5 U 0.16 J 0.5 U 0.5 U Arsenic D -- ug/I 0.15 1 U 1 U 0.1 U 0.15 3.4 0.27 0.063 J 0.053 J 0.1 U Arsenic T 10 02L ug/I 0.19 0.78 J 1 U 0.069 J 0.11 3.5 0.25 0.2 0.095 J 0.1 U Barium D -- ug/I 60.2 44.4 4.5 J 15 17.8 11.8 18.4 19.8 8.8 10.3 Barium T 700 02L ug/I 53.6 41.2 6.7 15.9 17.9 11 19.6 23.6 9.3 10.3 Beryllium D -- ug/I 0.092 J 1 U 1 U 0.1 U 0.039 J 0.1 U 0.1 U 0.067 J+ 0.027 J 0.087 J Beryllium T 4 IMAC ug/I 0.1 U 1 U 1 U 0.1 U 0.063 J 0.1 U 0.028 J 0.067 J 0.057 J 0.059 J Boron D -- ug/I 641 300 67.6 148 92.7 50 U 122 50 U 50 U 50 U Boron T 700 02L ug/I 541 277 73.2 160 111 50 U 122 50 UJ 50 U 50 U Cadmium D -- ug/I 0.08 U 0.8 U 0.8 U 0.08 U 0.053 J 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U Cadmium T 2 02L ug/I 0.08 U 0.8 U 0.8 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U Calcium T -- ug/1 47100 76700 70300 37300 31100 11600 16800 1190 4230 3790 Carbon N -- ug/I 1000 U 1000 U 540 J 1000 U 1000 U 1500 1000 U 1000 U -- 1000 U Chloride N 250000 02L ug/I 45500 42200 13800 20300 9400 14500 28800 4500 1100 2300 Chromium D -- ug/I 0.2 J 5 U 5 UJ 0.23 J+ 0.1 J 0.65 J+ 0.15 J+ 2.5 0.32 J 0.14 J Chromium T 10 02L ug/I 0.44 J 1.6 J 0.94 J+ 0.63 J 0.15 J+ 0.93 0.3 J 63.8 0.37 J 0.16 J Chromium 6+ T 0.07 DHHS ug/I 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.81 J- 0.03 U 0.038 0.03 U 0.022 J Cobalt D -- ug/I 141 13 1.6 0.42 29.1 0.11 0.54 1.3 0.7 0.26 Cobalt T 1 IMAC ug/I 162 13.8 2.3 0.5 28 0.11 0.81 1.9 0.81 0.25 Copper D -- ug/I 1.7 5 U 5 U 2.1 2.8 0.76 0.18 J 2.3 1.1 0.84 Copper T 1000 02L ug/I 0.84 5 U 5.4 0.78 0.71 J 0.94 0.5 U 3 0.52 0.36 J Iron D -- ug/I 1040 114 3920 50 U 4800 97.4 104 60 176 50 U Iron T 300 02L ug/I 1730 5030 8610 113 5080 56 53.5 1130 263 50 U Lead D -- ug/I 0.1U 1U 1U 0.1U 0.1U 0.1U 0.1U 0.17 0.1U 0.1U Lead T 15 02L ug/I 0.1 U 0.94 J 3.3 0.12 0.1 U 0.1 U 0.1 U 0.28 0.18 0.1 U Magnesium T - ug/I 12100 13300 5990 9550 7800 161 3370 1290 1640 1370 Manganese D -- ug/I 6200 5230 373 9 436 11.8 21.2 10.1 17 5.5 Manganese T 50 02L ug/I 5830 5040 407 10.5 409 5.4 23.5 23 18.3 6.7 Mercury D -- ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U Mercury T 1 02L ug/I 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U Methane N ug/I 10 U 10 U 1950 10 U 10 U 10 U 10 UJ 10 U 10 U 10 U Molybdenum D ug/I 0.5 U 5 U 5 U 0.83 0.17 J 1.2 0.32 J 0.5 U 0.5 U 0.5 U Molybdenum T ug/I 0.5 U 5 U 5 U 0.83 0.191 1.3 0.34 J 1.3 0.5 U 0.5 UJ Nickel D -- ug/I 5.8 5 U 5 U 2.3 23.1 0.5 U 0.59 3.5 2.6 1.5 Nickel T 100 02L ug/I 6.1 5 U 5 U 2.3 22.4 0.5 U 0.61 33.8 2.8 1.2 Nitrogen, NO2 plus NO3 N -- ug/1 20 U 20 U 20 U 200 20 U 97 16J 1100 190 1300 Potassium T ug/I 4930 J 5000 U 3200 J 3170 J 4230 J 65600 5000 U 5000 U 5000 U 5000 U Selenium D -- ug/I 1.2 5 U 5 U 2.1 0.98 0.33 J 0.5 U 0.5 U 0.5 U 0.5 U Selenium T 20 02L ug/I 1 5 U 5 U 2.8 0.87 0.4 J 0.5 U 0.46 J 0.5 U 0.5 U Sodium T -- ug/I 17400 13600 8820 5320 4980 J 19000 4980 J 2610 J 4840 J 3420 J Strontium D ug/I 295 168 219 132 135 135 65.5 17.3 29.7 23.6 Strontium T -- ug/I 277 149 234 140 140 132 62.9 18 30.8 23.6 Sulfate N 250000 02L ug/I 127000 J- 76800 J- 600 J 64500 84900 8200 2300 1100 8700 2100 Sulfide N -- ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U Thallium D -- ug/I 0.58 1 U 1 U 0.084 J 0.055 J 0.1 U 0.1 U 0.051 J 0.1 U 0.1 U Thallium T 0.2 IMAC ug/1 0.6 1 U 1 U 0.085 J 0.069 J 0.1 U 0.1 U 0.04 J 0.1 U 0.1 U Total Dissolved Solids N 500000 02L ug/I 275000 312000 242000 172000 170000 211000 115000 38000 J 59000 34000 Total Organic Carbon N -- ug/I -- -- -- -- -- -- -- -- 1000 U -- Total Suspended Solids N ug/I 2600 U 2500 U 47200 3400 2500 U 2500 U 2500 U 38600 J 6400 2500 U Uranium, Natural T ug/I 0.5 U 5 U 5 U 0.5 U 0.5 U 0.68 0.5 U -- 0.079 J -- Vanadium D -- ug/I 0.3 U 3 U 3 U 0.3 U 0.3 U 18.1 1.6 0.21 J 0.3 U 0.3 U Vanadium T 0.3 IMAC ug/1 0.3 U 3 U 3 U 0.14 J 0.3 U 20.4 1.6 1.1 0.13 J 0.3 U Zinc D -- ug/I 25.1 2.9 J+ 10 U 15.4 17.6 10 UJ 10 UJ 7.4 J+ 3.9 J 10 U Zinc T 1000 02L ug/I 8.9 J+ 10 UJ 10 U IOU 13J 5.2 J 5.2 J 7.3 J 3.3 J 10 U Dissolved Oxygen N -- mg/I 0.3 0.7 -- 1.39 0.7 4 0.6 6.6 1.4 5.6 Oxidation Reduction Potential N mV 460.8 194.4 174 47.6 29.1 54.4 131.7 121.9 92.3 Cliffside Steam Station Page 11 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 12 of 32 CSA Supplement 2 Location: GWA-20D GWA-20S GWA-21BR GWA-21BRU GWA-21S GWA-22BRU GWA-22S GWA-23D GWA-24BR GWA-24D Date: 4/14/2016 4/14/2016 4/18/2016 4/18/2016 4/18/2016 4/19/2016 4/19/2016 4/19/2016 4/21/2016 4/15/2016 Sample Type: N N N N N N N N N FD Sample Name: CS-GWA-20D CS-GWA-20S CS-GWA-21BR CS-GWA-21BRU CS-GWA-21S CS-GWA-22BRU CS-GWA-22S CS-GWA-23D CS-GWA-24BR CS-FD-GWA-24D Event: NCDEQ 02L GWQS, Constituent Fraction GWQS Source Unit IMAC, or DHHS pH N 6.5-8.5 02L SU 5.7 6.6 6.09 5.6 10.6 7.2 5.1 5.9 5.8 Specific Conductivity N NS/cm 134.3 449.3 296 260.7 409.3 164.2 42.6 66.7 49.4 Specific Conductivity N US/cm -- -- -- -- -- -- -- -- -- Temperature N Deg C 16.6 17.3 20 22 15.5 15.6 17.8 16 14.6 Turbidity, field N NTU 6.7 36.7 3.8 6.9 1.3 1.8 9.7 3.44 2.7 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 12 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Cliffside Steam Station Page 13 of 32 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: GWA-24D 4/15/2016 N CS-GWA-24D GWA-24S 4/15/2016 N CS-GWA-24S GWA-25D 4/13/2016 N CS-GWA-25D GWA-25S 4/13/2016 N CS-GWA-25S GWA-26D 4/13/2016 N CS-GWA-26D GWA-26S 4/13/2016 N CS-GWA-26S GWA-27D-A 4/13/2016 N CS-GWA-27D-A GWA-28BR 4/18/2016 FD CS-FD-GWA-28BR GWA-28BR 4/18/2016 N CS-GWA-28BR GWA-28BRU 4/18/2016 N CS-GWA-28BRU Constituent Fraction NCDEQ 02L GWQS, IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 5000 U 5000 U 5000 U 5000 U 225000 5000 U 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 10700 2700 J 48000 5400 61900 1400 J 1200 J 56300 56100 23500 Alkalinity, lab N ug/I 10700 2700 J 48000 5400 287000 1400 J 1200 J 56300 56100 23500 Aluminum D ug/I 100 U 100 U 94.9 J 100 U 724 100 U 100 U 100 U 100 U 100 U Aluminum T ug/I 100 U 53.9 J 144 100 U 742 113 100 U 100 U 100 U 100 U Antimony D ug/I 0.5U 0.5U 0.5U 0.5U 9.4 0.5U 0.5U 0.5U 0.5U 0.5U Antimony T 1 IMAC ug/I 0.5 U 0.5 U 0.5 U 0.5 U 8.1 0.5 U 0.5 U 0.15 J 0.5 U 0.12 J Arsenic D -- ug/I 0.1 U 0.1 U 0.56 0.1 U 1 U 0.1 U 0.21 0.1 U 0.1 U 0.9 Arsenic T 10 02L ug/I 0.1 U 0.04 J 0.58 0.052 J 0.43 J 0.11 0.16 0.1 U 0.1 U 0.87 Barium D -- ug/I 10.3 12.6 14.5 35.2 169 21 126 6.1 6.1 5.9 Barium T 700 02L ug/I 10.6 12.6 14.3 36.2 175 20.6 127 6.9 7.3 6.4 Beryllium D -- ug/I 0.01 J 0.04 J 0.1 U 0.06 J 1 U 0.1 U 0.2 0.1 U 0.1 U 0.1 U Beryllium T 4 IMAC ug/I 0.012 J 0.05 J 0.1 U 0.11 1 U 0.1 U 0.13 0.1 U 0.022 J 0.1 U Boron D -- ug/I 50 U 50 U 50 U 50 U 50 U 50 U 1010 50 U 50 U 50 U Boron T 700 02L ug/I 50 U 50 U 50 U 50 U 50 U 50 U 987 50 U 50 U 50 U Cadmium D -- ug/I 0.08 U 0.08 U 0.08 U 0.08 U 0.8 U 0.08 U 0.14 0.08 U 0.08 U 0.08 U Cadmium T 2 02L ug/I 0.08 U 0.093 0.08 U 0.08 U 0.8 U 0.08 U 0.14 0.08 U 0.08 U 0.08 U Calcium T -- ug/1 3810 707 20600 1620 103000 58.9 J 35700 19400 18900 5600 Carbon N -- ug/I 1000 U 1000 U 1000 U 1000 U 1100 1000 U 1000 U 1000 U 1000 U 1000 U Chloride N 250000 02L ug/I 2300 3600 3500 3700 1700 2100 47000 2900 2900 2200 Chromium D -- ug/I 0.43 J 0.26 J 1.4 0.86 5.1 0.37 J 1.7 0.46 J 0.59 J 0.14 J Chromium T 10 02L ug/I 0.18 J 0.51 1.6 0.19 J 4.6 J 0.46 J 2.4 J 0.14 J 0.2 J 0.2 J Chromium 6+ T 0.07 DHHS ug/I 0.03 U 0.03 U 1.7 0.064 7.7 0.03 U 0.16 0.03 U 0.03 U 0.03 U Cobalt D -- ug/I 0.24 5.7 0.019 J 8.6 1 U 0.86 0.83 0.11 0.1 2 Cobalt T 1 IMAC ug/I 0.29 6.1 0.02 J 10 1 U 0.81 0.82 0.094 J 0.11 2.5 Copper D -- ug/I 0.94 2 0.5 U 1.4 3.2 J 2.6 0.61 0.17 J 0.13 J 0.5 U Copper T 1000 02L ug/I 0.44 J 0.5 J 0.5 U 0.5 U 5 U 0.2 J 0.49 J 0.11 J 0.5 U 0.5 U Iron D -- ug/I 50 U 50 U 50 U 50 U 50 U 50 U 35.5 J 4700 4700 6340 Iron T 300 02L ug/I 28.7 J 50 U 50 U 38.4 J 50 U 102 35.6 J 4190 5040 6510 Lead D -- ug/I 0.1U 0.1U 0.1U 0.1U 1U 0.12 0.1U 0.1U 0.1U 0.1U Lead T 15 02L ug/I 0.1U 0.1U 0.1U 0.1U 1U 0.21 0.1U 0.1U 0.1U 0.1U Magnesium T - ug/I 1390 880 1320 1410 100 U 247 4810 1970 1980 1550 Manganese D -- ug/I 5.5 72.6 5 U 264 5 U 21.7 1330 80 79.7 45 Manganese T 50 02L ug/I 6.9 66.6 5 U 312 5 U 23.1 1240 74.2 89.3 44.3 Mercury D -- ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U Mercury T 1 02L ug/I 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U Methane N ug/I 10U 10U 10U 10U 10U 10U 10U 15.9 18.9 10U Molybdenum D ug/I 0.5 U 0.5 U 1.2 0.5 U 9.7 0.5 U 0.5 U 0.5 U 0.5 U 0.12 J Molybdenum T ug/I 0.5 UJ 0.5 U 1.4 0.5 U 8.5 0.5 U 0.14 J+ 0.5 U 0.5 U 0.14 J Nickel D -- ug/I 1.4 3.2 0.5 U 2.3 5 U 0.91 3 0.61 0.51 1.2 Nickel T 100 02L ug/I 1.3 3.5 0.5 U 2 5 U 0.5 J 2.9 0.5 U 0.5 U 0.97 Nitrogen, NO2 plus NO3 N -- ug/1 1300 550 1900 2000 280 20 U 150 20 U 20 U 20 U Potassium T ug/I 5000 U 5000 U 6160 2660 J 36300 5000 U 2980 J 5000 U 5000 U 3200 J Selenium D -- ug/I 0.5U 0.5U 0.5U 0.5U 5U 0.36J 6 0.5U 0.5U 0.5U Selenium T 20 02L ug/I 0.5 U 0.5 U 0.32 J 0.5 U 5 U 1 6.4 0.5 U 0.5 U 0.5 U Sodium T -- ug/I 3470 J 2940 J 5910 2900 J 15000 1760 J 8440 6430 6440 6100 Strontium D ug/I 23.6 7.9 64.7 20.4 1370 2.5 J 108 72.5 72.4 38.7 Strontium T -- ug/I 24.3 8.1 69.8 20.8 1420 5 U 109 77 82.8 40.6 Sulfate N 250000 02L ug/I 2000 1100 12800 760J 45200 600J 76500 4700 4900 10200 Sulfide N -- ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U Thallium D -- ug/I 0.1 U 0.1 U 0.1 U 0.073 J 1 U 0.016 J 0.13 0.1 U 0.1 U 0.1 U Thallium T 0.2 IMAC ug/1 0.1 U 0.1 U 0.1 U 0.079 J 1 U 0.015 J 0.12 0.1 U 0.1 U 0.1 U Total Dissolved Solids N 500000 02L ug/I 36000 25000 U 70000 25000 U 356000 25000 U 197000 96000 110000 82000 Total Organic Carbon N -- ug/I -- -- -- -- -- -- -- -- -- -- Total Suspended Solids N ug/I 2500 U 2500 U 2500 U 2500 U 2500 U 5300 2500 U 2500 U 5000 U 2500 U Uranium, Natural T ug/I -- -- -- -- -- -- -- 0.5 U 0.5 U 0.5 U Vanadium D -- ug/I 0.3 U 0.3 U 2.6 0.3 U 7.9 0.1 J 0.3 U 0.3 U 0.3 U 0.3 U Vanadium T 0.3 IMAC ug/1 0.3 U 0.3 U 2.9 0.086 J 6.6 0.18 J 0.1 J+ 0.3 U 0.3 U 0.07 J Zinc D -- ug/I 10U 4.6J 10U 4.9J 5J 6.7J 15.1 10U 10U 15 Zinc T 1000 02L ug/I 10 U 10 U 10 U 3.4 J 10 U 3.5 J 13.9 9.2 J+ 4.7 J+ 12.7 J+ Dissolved Oxygen N mg/I 5.6 6 2.6 5.8 1.2 6.8 1.8 0.4 0.4 0.6 Oxidation Reduction Potential N mV 92.3 123.9 77.2 129 30.6 129.2 261.1 -38.1 -38.1 27.7 Cliffside Steam Station Page 13 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 14 of 32 CSA Supplement 2 Location: GWA-24D GWA-24S GWA-25D GWA-25S GWA-26D GWA-26S GWA-27D-A GWA-28BR GWA-28BR GWA-28BRU Date: 4/15/2016 4/15/2016 4/13/2016 4/13/2016 4/13/2016 4/13/2016 4/13/2016 4/18/2016 4/18/2016 4/18/2016 Sample Type: N N N N N N N FD N N Sample Name: CS-GWA-24D CS-GWA-24S CS-GWA-25D CS-GWA-25S CS-GWA-26D CS-GWA-26S CS-GWA-27D-A CS-FD-GWA-28BR CS-GWA-28BR CS-GWA-28BRU Event: NCDEQ 02L GWQS, Constituent Fraction GWQS Source Unit IMAC, or DHHS pH N 6.5-8.5 02L SU 5.8 5.3 8.9 5.4 12 5.1 5.1 6.8 6.8 6.2 Specific Conductivity N NS/cm 49.4 31.8 156.5 47.8 1469 18.4 330.3 131.4 131.4 88.5 Specific Conductivity N US/cm -- -- -- -- -- -- -- -- -- -- Temperature N Deg C 14.6 16.8 16 14.7 19.1 19.3 18.8 18.4 18.4 20.9 Turbidity, field N NTU 2.7 2.6 0 2 1.5 8.9 0.9 3.2 3.2 7.6 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 14 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Cliffside Steam Station Page 15 of 32 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: GWA-28S 4/18/2016 N CS-GWA-28S GWA-28S 4/19/2016 N CS-GWA-28S GWA-29BR 4/15/2016 N CS-GWA-29BR GWA-29D 4/15/2016 N CS-GWA-29D GWA-2BRU 4/14/2016 N CS-GWA-2BRU GWA-2S 4/14/2016 N CS-GWA-2S GWA-30BR 4/14/2016 N CS-GWA-30BR GWA-30BRU 4/14/2016 N CS-GWA-30BRU GWA-30S 4/14/2016 N CS-GWA-30S GWA-31BR-A 4/13/2016 N CS-GWA-31BR-A Constituent Fraction NCDEQ 02L GWQS, IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 5000 U 1260000 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 1600 J 5000 U 17500 120000 53900 38300 183000 10900 Alkalinity, lab N ug/I 1600 J 1610000 17500 120000 53900 38300 183000 10900 -- Aluminum D ug/I -- 160 271 100 U 100 U 100 U 100 UJ 1360 J- 100 UJ 334 Aluminum T ug/I 141 -- 281 100 U 100 U 136 100 U 1570 106 849 Antimony D ug/I -- 2.4 IOU 0.5 U 5 U 0.25 J 0.5 U 1.3 J 0.5 U 6.8 Antimony T 1 IMAC ug/I 3.8 -- 0.5 U 0.5 U 5 U 0.41 J 0.32 J 1.8 J 0.5 U 14.8 Arsenic D -- ug/I -- 0.17 2 U 0.055 J 1 U 0.064 J 0.19 2.5 0.1 U 2.5 Arsenic T 10 02L ug/I 0.11 -- 0.1 U 0.1 U 1 U 0.18 0.55 3.9 0.1 U 2.9 Barium D -- ug/I -- 22.4 3560 20.6 7.9 29.7 11 J- 26.1 J- 17.6 J- 9.4 Barium T 700 02L ug/I 23.9 -- 3570 20.9 8.6 29.1 17.5 19.9 18.7 19.1 Beryllium D -- ug/I -- 0.86 2 U 0.1 U 1 UJ 0.037 J+ 0.019 J 1 U 0.1 U 0.1 U Beryllium T 4 IMAC ug/I 0.12 -- 0.1 U 0.1 U 1 U 0.094 J 0.11 0.16 J 0.039 J 0.066 J Boron D -- ug/I -- 32.3 J 50 U 50 U 106 105 50 UJ 50 UJ 50 UJ 50 U Boron T 700 02L ug/I 50 U -- 50 U 50 U 108 100 50 U 40.5 J 50 U 31.8 J Cadmium D -- ug/I -- 0.06 J 1.6 U 0.08 U 0.8 U 0.084 0.08 U 0.8 U 0.08 U 0.08 U Cadmium T 2 02L ug/I 0.08 U -- 0.08 U 0.08 U 0.8 U 0.082 0.08 U 0.8 U 0.08 U 0.08 U Calcium T -- ug/1 2120 -- 721000 7940 51500 29700 11900 55400 2160 36700 Carbon N -- ug/I -- 2200 4200 1000 U 1000 U 1000 U 1000 U 16000 1000 U -- Chloride N 250000 02L ug/I 2500 1800 8700 4200 1800 7500 6500 3000 -- Chromium D -- ug/I -- 1.5 10 UJ 0.23 J+ 5 U 1.1 0.38 J 5 U 0.39 J 3.8 J+ Chromium T 10 02L ug/I 0.84 J+ -- 0.092 J+ 0.39 J+ 1 J 1.7 2.2 J+ 5 UJ 0.6 J+ 10.4 J+ Chromium 6+ T 0.07 DHHS ug/I 0.057 -- 5.1 0.17 0.035 0.65 J- 0.03 U 0.057 0.16 -- Cobalt D -- ug/I -- 6.5 2 U 0.3 0.61 J 0.71 0.026 J 1 U 0.45 0.24 Cobalt T 1 IMAC ug/I 7.9 -- 0.012 J 0.36 0.48 J 0.88 0.1 1 U 0.57 0.51 Copper D -- ug/I -- 87.8 IOU 0.54 5 U 6.5 0.12 J+ 5 UJ 1.6 J+ 11.7 Copper T 1000 02L ug/I 5.1 -- 0.5 U 0.3 J 5 U 7.3 0.31 J 5 U 0.34 J 104 Iron D -- ug/I -- 220 50 U 50 U 114 51.3 6230 J- 50 UJ 50 UJ 31 J Iron T 300 02L ug/I 41.8 J -- 50 U 25.1 J 348 255 11000 36.5 J 116 874 J+ Lead D -- ug/I -- 0.54 4.2 0.1 U 1 U 0.1 U 0.1 U 1 U 0.1 U 0.15 Lead T 15 02L ug/I 0.11 -- 0.2 0.1 U 1 U 0.15 0.1 U 1 U 0.098 J 1.1 Magnesium T -- ug/I 1380 -- 100 U 3030 5450 11100 2370 100 U 1460 643 Manganese D -- ug/I -- 57.8 5 U 8.8 111 244 57.8 J- 5 UJ 23.4 J- 5 U Manganese T 50 02L ug/I 47.1 -- 5 U 11.1 120 253 92.1 5 U 24.9 16.5 Mercury D -- ug/I -- 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U Mercury T 1 02L ug/I 0.2U -- 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U Methane N ug/I 10 U -- 33.9 10 U 10 U 10 U 10 U 10 U 10 U -- Molybdenum D ug/I -- 1.6 10 U 0.15 J 5 U 0.5 U 0.5 U 20.6 0.5 U 65.2 Molybdenum T ug/I 0.37 J -- 0.5 UJ 0.5 UJ 5 U 0.5 U 0.14 J 23.6 0.5 U 60.2 Nickel D -- ug/I -- 17.6 10 U 0.79 5 U 2 0.5 U 5 U 0.97 3.5 Nickel T 100 02L ug/I 17.9 -- 0.5 U 1.1 5 U 2.1 1.5 5 U 1.1 5 Nitrogen, NO2 plus NO3 N -- ug/1 -- 1100 17J 180 20 U 180 20 U 20 U 120 -- Potassium T ug/I 5000 U -- 162000 5000 U 8660 2860 J 14100 16000 5000 U 88300 Selenium D -- ug/I -- 0.49 J 10 U 0.55 5 U 0.5 U 0.5 U 5 U 0.5 U 2.3 Selenium T 20 02L ug/I 0.52 -- 0.5 U 0.34 J 5 U 0.36 J 0.5 U 5 U 0.5 U 2.7 Sodium T -- ug/I 1670 J -- 52300 4260 J 12200 3700 J 6510 48700 1670 J 326000 Strontium D ug/I -- 113 25800 27.1 158 115 70 J- 334 J- 18.7 J- 610 Strontium T -- ug/I 19 -- 31500 28.7 164 110 116 323 17.9 605 Sulfate N 250000 02L ug/I -- 4400 2600 5600 56200 7500 11100 45400 1000 U -- Sulfide N -- ug/I 100 U 100 U 100 U 100 U 100 UJ 100 U 100 U 100 U -- Thallium D -- ug/I -- 0.031 J 2 U 0.05 J 1 U 0.08 J 0.1 U 1 U 0.039 J 0.1 U Thallium T 0.2 IMAC ug/1 0.042 J -- 0.1 U 0.023 J 1 U 0.094 J 0.1 U 1 U 0.051 J 0.1 U Total Dissolved Solids N 500000 02L ug/I -- 40000 1940000 61000 230000 154000 87000 330000 25000 U -- Total Organic Carbon N -- ug/I -- -- -- -- -- -- -- -- -- Total Suspended Solids N ug/I 2500 U 5000 U 2500 U 2500 U 2500 U 14800 2500 U 2500 U Uranium, Natural T ug/I -- -- 10 U -- 0.78 J 0.5 U -- -- -- -- Vanadium D -- ug/I -- 0.56 6 U 0.3 U 0.72 J 0.13 J 0.3 U 7.4 0.11 J 16 Vanadium T 0.3 IMAC ug/1 0.079 J -- 0.3 U 0.084 J 3 U 0.46 0.14 J 4.8 0.32 14.5 Zinc D -- ug/I -- 263 5.2 J 10 U 4.2 J 31.6 3.7 J+ 10 UJ 4.9 J+ 9.4 J Zinc T 1000 02L ug/I 36.6 -- 10 U 10 U 3.2 J 29.7 17.2 J 10 U 4.9 J 119 Dissolved Oxygen N -- mg/I 4.2 1.7 4.2 5.9 0.5 0.6 0.4 4.9 0.02 Oxidation Reduction Potential N mV 271 -130.5 229.4 86.2 202.2 -67.3 -191.4 298.2 -210.4 Cliffside Steam Station Page 15 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 16 of 32 CSA Supplement 2 Location: GWA-28S GWA-28S GWA-29BR GWA-29D GWA-21BRU GWA-2S GWA-30BR GWA-30BRU GWA-30S GWA-31BR-A Date: 4/18/2016 4/19/2016 4/15/2016 4/15/2016 4/14/2016 4/14/2016 4/14/2016 4/14/2016 4/14/2016 4/13/2016 Sample Type: N N N N N N N N N N Sample Name: CS-GWA-28S CS-GWA-28S CS-GWA-29BR CS-GWA-29D CS-GWA-2BRU CS-GWA-2S CS-GWA-30BR CS-GWA-30BRU CS-GWA-30S CS-GWA-31BR-A Event: NCDEQ 02L GWQS, Constituent Fraction GWQS Source Unit IMAC, or DHHS pH N 6.5-8.5 02L SU 5 13 6 6.5 5.7 6.2 11.4 4.8 11.1 Specific Conductivity N NS/cm 41.6 8921 100.3 321.8 263.2 169.1 1015 39.8 2131 Specific Conductivity N US/cm -- -- -- -- -- -- -- -- -- Temperature N Deg C 24 14.5 15.1 20.3 18.9 17.5 16.8 16.8 22.1 Turbidity, field N NTU 6 0.1 5.1 3.5 7.6 3 0.9 4.1 9.8 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 16 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Cliffside Steam Station Page 17 of 32 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: GWA-31D 4/13/2016 N CS-GWA-31D GWA-32BR 4/15/2016 N CS-GWA-32BR GWA-32D 4/15/2016 N CS-GWA-32D GWA-33BR 4/14/2016 N CS-GWA-33BR GWA-33D 4/14/2016 N CS-GWA-33D GWA-33S 4/14/2016 N CS-GWA-33S GWA-34S 4/19/2016 N CS-GWA-34S GWA-35D 4/19/2016 N CS-GWA-35D GWA-35S 4/19/2016 N CS-GWA-35S GWA-36D 2/25/2016 N CS-GWA-36D-1Q16 Constituent Fraction NCDEQ 02L GWQS, IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 5000 U 71100 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 6700 Alkalinity, HCO3 N ug/I 93400 38000 4200 J 88400 103000 1400 J 7700 65500 41000 16800 Alkalinity, lab N ug/I 93400 109000 4200 J 88400 103000 1400 J 7700 65500 41000 23500 Aluminum D ug/I 106 86.8 J 100 U 100 U 100 U 89.5 J 100 U 100 U 100 U 100 U Aluminum T ug/I 100 U 129 100 U 100 U 100 U 232 171 269 303 100 U Antimony D ug/I 5 U 0.68 0.5 U 0.5 U 0.5 U 0.5 U 0.13 J 0.13 J 0.5 U 0.11 J Antimony T 1 IMAC ug/I 5 U 1.3 0.5 U 0.5 U 0.5 U 0.5 U 0.1 J 0.11 J 0.5 U 0.18 J Arsenic D -- ug/I 0.79 J 1.9 0.1 U 0.071 J 0.094 J 0.21 0.092 J 0.12 0.68 0.33 Arsenic T 10 02L ug/I 0.44 J 2.6 0.055 J 0.066 J 0.11 0.26 0.098 J 0.18 0.67 0.5 Barium D -- ug/I 24.8 17.1 5.8 15.3 160 37.4 9.1 10.5 J 28.8 35 Barium T 700 02L ug/I 36 26 6 15.6 172 40.5 9.7 11.3 29.4 37 Beryllium D -- ug/I 1 U 0.027 J 0.098 J 0.1 UJ 0.1 UJ 0.8 J+ 0.05 J 0.039 J 0.1 U 0.1 U Beryllium T 4 IMAC ug/I 1 U 0.1 U 0.1 0.1 U 0.1 U 1 0.029 J 0.1 U 0.065 J 0.04 J Boron D -- ug/I 28.8 J 50 U 50 U 74.4 50 U 50 U 50 U 126 J 87.7 130 Boron T 700 02L ug/I 47.8 J 50 U 50 U 74.2 50 U 50 U 50 U 134 92.5 150 Cadmium D -- ug/I 0.8 U 0.07 J 0.08 U 0.08 U 0.08 U 0.16 0.08 U 0.08 U 0.08 U 0.08 U Cadmium T 2 02L ug/I 0.8 U 0.08 U 0.08 U 0.08 U 0.08 U 0.16 0.08 U 0.08 U 0.08 U 0.08 U Calcium T -- ug/1 57800 30600 1190 30700 44500 21700 2430 37600 11600 108000 Carbon N -- ug/I -- 2900 1000 U 1000 U 23200 850 J -- -- -- -- Chloride N 250000 02L ug/I 2200 2900 1100 9400 5900 2900 2400 2900 3000 5700 Chromium D -- ug/I 2 J+ 1.1 J+ 0.22 J+ 0.4 J 0.27 J 0.7 0.55 J 0.26 J+ 0.92 J 0.27 J+ Chromium T 10 02L ug/I 5 UJ 2.1 0.23 J 0.41 J+ 0.54 J+ 1 J+ 0.66 2.9 5 0.63 J+ Chromium 6+ T 0.07 DHHS ug/I 0.088 2 0.02 J 0.042 0.14 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U Cobalt D -- ug/I 0.3 J 0.045 J 0.053 J 0.1 U 0.27 19 2.3 1.4 15.9 6.7 Cobalt T 1 IMAC ug/I 0.32 J 0.072 J 0.091 J 0.01 J 0.27 20 2.2 1.2 15.4 11 Copper D -- ug/I 1.4 J 1 J+ 1.1 J+ 0.5 U 1.4 1.1 1.4 0.5 U 0.91 0.33 J+ Copper T 1000 02L ug/I 1.4 J 1.1 0.3 J 0.5 U 1.2 0.49 J 0.12 J 0.37 J 2 0.36 J+ Iron D -- ug/I 50 U 50 U 50 U 137 63.9 J- 7800 70 6650 J 16100 50 U Iron T 300 02L ug/I 50 UJ 50 U 50 U 494 50 U 9130 219 7040 15900 300 Lead D -- ug/I 1U 0.1U 0.1U 0.1U 0.1U 0.2 0.1U 0.1U 0.1U 0.1U Lead T 15 02L ug/I 1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.34 0.1 U 0.18 0.21 0.1 U Magnesium T -- ug/I 9980 397 165 5060 8700 9380 706 4120 5800 16800 Manganese D -- ug/I 7.4 5 U 3.8 J 124 110 J- 526 102 162 J 1850 420 Manganese T 50 02L ug/I 9.9 5 U 3.7 J 142 145 601 118 177 1960 680 Mercury D -- ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U Mercury T 1 02L ug/I 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U Methane N ug/I 10 U 10 U 10 U 30.3 10 U 10 U 10 U 29 J 169 9.2 J+ Molybdenum D ug/I 4 J 2.5 0.5 U 0.35 J 0.13 J 0.5 U 0.5 U 0.36 J 0.5 U 2.2 Molybdenum T ug/I 1.3 J 3.2 0.5 UJ 0.36 J 0.18 J 0.5 U 0.5 U 0.41 J 0.5 U 2.3 Nickel D -- ug/I 7.4 0.58 0.5 U 0.5 U 13.5 19.3 3.8 2.3 3.1 3.2 Nickel T 100 02L ug/I 10.8 0.51 0.5 U 0.5 U 15.2 20 3.5 3.1 2.7 4.4 Nitrogen, NO2 plus NO3 N -- ug/1 140 63 270 20 U 460 20 U 41 20 U 20 U 20 U Potassium T ug/I 14200 33600 5000 U 31100 16000 5000 U 5000 U 3890 J 5000 U 11200 Selenium D -- ug/I 5U 0.45J 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Selenium T 20 02L ug/I 5 U 0.66 0.5 U 0.5 U 0.5 U 0.55 0.5 U 0.34 J 0.5 U 0.5 U Sodium T -- ug/I 13400 19500 1880 J 20200 11400 2870 J 1930 J 12200 2660 J 11100 Strontium D ug/I 135 131 5.6 156 152 150 14.4 112 J 44.4 450 Strontium T -- ug/I 140 184 5.6 164 166 158 14.4 114 41.3 490 Sulfate N 250000 02L ug/I 114000 31200 430 J 39500 73100 99100 1900 71000 J 25900 272000 Sulfide N -- ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U Thallium D -- ug/I 1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.065 J 0.1 U Thallium T 0.2 IMAC ug/1 1 U 0.1 U 0.033 J 0.1 U 0.1 U 0.048 J 0.1 U 0.1 U 0.063 J 0.029 J Total Dissolved Solids N 500000 02L ug/I 268000 210000 25000 U 172000 243000 177000 42000 224000 121000 402000 J+ Total Organic Carbon N -- ug/I 900 J -- -- -- -- -- 1000 U 1000 U 530 J 1000 U Total Suspended Solids N ug/I 2500 U 2500 U 2500 U 8700 2500 U 7200 5000 U 19200 9800 37400 Uranium, Natural T ug/I -- 71.4 -- -- -- -- 0.5 U 0.16 J 0.5 U -- Vanadium D -- ug/I 1.1 J 2.6 0.3 U 0.3 U 0.37 0.49 0.3 U 0.3 U 0.3 U 0.25 J Vanadium T 0.3 IMAC ug/1 3 U 4.2 0.3 U 0.3 U 0.39 0.98 0.22 J 0.32 0.72 1.6 Zinc D -- ug/I 3.5 J 10 U 10 U IOU 5.9 J- 40.2 5.1 J+ 10.1 J 15.3 J 6.7 J+ Zinc T 1000 02L ug/I 10 U 10 U 10 U IOU 4J 43.9 4.4 J 13.6 15.4 9.9 J Dissolved Oxygen N mg/I 2.3 2.1 6.9 0.4 0.4 0.2 6.5 0.1 0.2 0.1 Oxidation Reduction Potential N mV 94.5 -18.9 285.5 -19.6 1 150.9 201 1 225.4 -122.9 3.6 -214.4 Cliffside Steam Station Page 17 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 18 of 32 CSA Supplement 2 Location: GWA-31D GWA-32BR GWA-32D GWA-33BR GWA-33D GWA-33S GWA-34S GWA-35D GWA-35S GWA-36D Date: 4/13/2016 4/15/2016 4/15/2016 4/14/2016 4/14/2016 4/14/2016 4/19/2016 4/19/2016 4/19/2016 2/25/2016 Sample Type: N N N N N N N N N N Sample Name: CS-GWA-31D CS-GWA-32BR CS-GWA-32D CS-GWA-33BR CS-GWA-33D CS-GWA-33S CS-GWA-34S CS-GWA-35D CS-GWA-35S CS-GWA-36D-1Q16 Event: NCDEQ 02L GWQS, Constituent Fraction GWQS Source Unit IMAC, or DHHS pH N 6.5-8.5 02L SU 6.96 10.5 4.8 9.3 6.3 4.9 5.5 6.7 5.9 9.8 Specific Conductivity N NS/cm 443.2 350.3 23.9 341 379.1 253.7 34 315.6 186.4 686 Specific Conductivity N US/cm -- -- -- -- -- -- -- -- -- -- Temperature N Deg C 18.3 20.4 15 17.2 12.5 19.2 18.1 17.5 16.9 16.3 Turbidity, field N NTU 1.62 0.6 0.5 4.4 0.2 8.2 5 9.8 6.6 1.4 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 18 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Cliffside Steam Station Page 19 of 32 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: GWA-36S 2/29/2016 N CS-GWA-36S GWA-37D 4/21/2016 N CS-GWA-37D GWA-37S 4/21/2016 N CS-GWA-37S GWA-38D 4/20/2016 N CS-GWA-38D GWA-31D 4/14/2016 N CS-GWA-3D GWA-42S 4/20/2016 N CS-GWA-42S GWA-43D 4/19/2016 N CS-GWA-43D GWA-43S 4/20/2016 N CS-GWA-43S GWA-44BR 2/26/2016 N CS-GWA-44BR GWA-44D 2/26/2016 N CS-GWA-44D Constituent Fraction NCDEQ 02L GWQS, IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 5000 U 5000 U 5000 U 4200 J 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 33400 54800 16300 47900 36800 1000 J 96600 11100 80100 32300 Alkalinity, lab N ug/I 33400 54800 16300 52100 36800 1000 J 96600 11100 80100 32300 Aluminum D ug/I 120 100 U 100 U 490 80.1 J 112 100 U 100 U 100 U 100 U Aluminum T ug/I 240 83.8 J 100 U 3880 128 93.3 J 258 149 150 160 Antimony D ug/I 10U 5U 0.5U 1.5 5U 0.5U 0.41J 0.5U 2.5U 2.5U Antimony T 1 IMAC ug/I IOU 5 U 0.5 U 1.7 5 U 0.5 U 0.54 0.5 U 0.67 J 2.5 U Arsenic D -- ug/I 2 U 1 U 1.1 19.5 1 U 0.07 J 0.17 0.066 J 0.76 0.9 Arsenic T 10 02L ug/I 2 U 1 U 1.1 29.2 1 U 0.07 J 0.28 0.087 J 0.77 0.98 Barium D -- ug/I 100 43.3 24 16.3 18.9 181 122 79 34 39 Barium T 700 02L ug/I 120 46 25.8 55.2 19.1 175 114 80.4 40 45 Beryllium D -- ug/I 0.52 J 1 U 0.059 J 0.1 UJ 1 U 0.18 0.1 U 0.064 J+ 0.12 J+ 0.2 J+ Beryllium T 4 IMAC ug/I 0.42 J 0.35 J 0.15 0.2 1 U 0.2 0.031 J 0.039 J 0.13 J+ 0.21 J Boron D -- ug/I 67 41.5 J 110 26.2 J 383 43.4 J 27.2 J 71.6 32 J 27 J Boron T 700 02L ug/I 73 58.4 116 36.9 J 403 51.6 27 J 83.2 35 J 30 J Cadmium D -- ug/I 1.6 U 0.8 U 0.17 0.08 U 0.8 U 0.08 U 0.059 J 0.071 J 0.4 U 0.4 U Cadmium T 2 02L ug/I 1.6 U 0.8 U 0.14 0.08 U 0.8 U 0.08 U 0.08 U 0.061 J 0.4 U 0.4 U Calcium T -- ug/1 45700 94500 J+ 16700 32100 65500 7380 38500 11600 160000 110000 Carbon N -- ug/I -- -- -- -- 1000 U -- -- -- -- -- Chloride N 250000 02L ug/I 3900 3500 12800 5800 5100 1200 3400 1400 18100 16400 Chromium D -- ug/I IOU 2.6 J 0.32 J 14.5 1.7 J 0.3 J 0.34 J+ 0.26 J 2.5 U 0.46 J Chromium T 10 02L ug/I IOU 3.4 J 0.42 J 17.8 1.9 J 0.6 J 4 1.2 J 1.8 J+ 1.1 J+ Chromium 6+ T 0.07 DHHS ug/I 0.03 U 1.1 0.03 U 2.5 0.24 0.16 0.03 U 0.096 0.03 U 0.13 J+ Cobalt D -- ug/I 22.2 3.6 76.6 0.44 4.6 3.8 0.93 9 2.5 0.52 Cobalt T 1 IMAC ug/I 17.4 4 84.7 2.5 5.3 4.4 1.1 9 2.6 0.74 Copper D -- ug/I 1101-1 5 U 0.25 J 1.2 1.7 J 2 1.3 0.54 0.56 J 2.3 J Copper T 1000 02L ug/I IOU 4.1 J 0.2 J 4.8 1.3 J 0.15 J+ 0.75 1.8 5.2 8 Iron D -- ug/I 250 134 26300 153 83 33.1 J 396 36.1 J 850 50 U Iron T 300 02L ug/I 230 235 24800 3360 207 42.1 J 758 236 1100 180 Lead D -- ug/I 2 U 1 U 0.1 U 0.21 1 U 0.099 J 0.1 U 0.1 U 0.5 U 0.45 J Lead T 15 02L ug/I 2 U 1 U 0.1 1.8 1 U 0.1 U 0.2 0.1 U 0.5 U 0.51 Magnesium T -- ug/I 13300 23100 12600 2140 16000 4700 11100 3620 21800 15400 Manganese D -- ug/I 570 283 5100 6.9 1330 131 26.5 347 570 65 Manganese T 50 02L ug/I 600 314 5560 99.2 1460 172 31.4 374 600 77 Mercury D -- ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U Mercury T 1 02L ug/I 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U Methane N ug/I 2J+ 10 U 349 10 U 10 U 10 U 10 U 10 U 24 28.2 Molybdenum D ug/I 10 U 5 U 0.5 U 13.1 5 U 0.5 U 0.32 J 0.44 J 3.5 3.8 Molybdenum T ug/I 10 U 5 U 0.5 U 9.9 5 U 0.5 U 0.44 J 0.45 J 3.6 3.9 Nickel D -- ug/I 12.3 10.2 16.3 8.4 25.4 4.7 7.3 12.7 15.9 3.2 Nickel T 100 02L ug/I 13.4 11.5 17 11.8 28.3 4.9 7.2 13 17.1 3.6 Nitrogen, NO2 plus NO3 N -- ug/1 130 J+ 20 U 20 UJ 20 U 79 47 20 U 230 20 U 450 Potassium T ug/I 5750 5680 3650 J 15800 6270 4350 J 7570 3400 J 16600 14400 Selenium D -- ug/I 10 U 5 U 0.5 U 0.69 5 U 0.5 0.5 U 0.5 U 2.5 U 2.5 U Selenium T 20 02L ug/I 10 U 5 U 0.5 U 1.8 5 U 0.38 J 0.5 U 0.5 U 2.5 U 2.5 U Sodium T -- ug/I 6910 15000 5310 28100 9440 964 J 8020 2360 J 16300 14800 Strontium D ug/I 330 554 54.2 72.4 246 107 155 91.4 270 260 Strontium T -- ug/I 380 585 55.5 108 254 103 146 90.7 320 310 Sulfate N 250000 02L ug/I 146000 306000 125000 44000 212000 41900 67900 37200 346000 283000 Sulfide N -- ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U Thallium D -- ug/I 2 U 1 U 0.038 J 0.1 U 1 U 0.021 J 0.1 U 0.1 U 0.5 U 0.5 U Thallium T 0.2 IMAC ug/1 2 U 1 U 0.049 J 0.083 J 1 U 0.031 J 0.1 U 0.1 U 0.5 U 0.5 U Total Dissolved Solids N 500000 02L ug/I 234000 547000 232000 182000 387000 81000 225000 88000 623000 490000 Total Organic Carbon N -- ug/I 14700 1000 U 1000 U 8100 J -- 1000 U 1000 U 1000 U 680 J 740 J Total Suspended Solids N ug/I 5300 3200 9800 970000 2600 5000 U 17400 2500 U 14400 2500 U Uranium, Natural T ug/I -- 5 U 0.5 U 1.1 5 U 0.5 U 1.2 0.5 U -- -- Vanadium D -- ug/I 6 U 3 U 0.3 U 38.6 1.2 J 0.3 U 0.35 0.3 U 0.6 J 5.1 Vanadium T 0.3 IMAC ug/1 6 U 3 U 0.1 J 33.9 0.9 J 0.1 J 0.92 0.67 0.92 J 5.9 Zinc D -- ug/I 40 3.7 J 25.5 10 UJ 46.4 13.7 J 4.3 J+ 3.7 J+ 2.9 J 2.9 J Zinc T 1 1000 02L ug/I 43 J+ 1101-1 22.6 14.8 46.4 6.9 J 5.5 J 3.6 J 4.8 J 8.9 J Dissolved Oxygen N mg/I 4 0.2 0.2 0.5 0.8 0.8 0.4 3.7 0.3 0.51 Oxidation Reduction Potential N mV 147.4 78.3 61.6 -146.9 203.2 290.2 43.6 160.2 -86.5 -119.4 Cliffside Steam Station Page 19 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 20 of 32 CSA Supplement 2 Location: GWA-36S GWA-37D GWA-37S GWA-38D GWA-31D GWA-42S GWA-43D GWA-43S GWA-44BR GWA-44D Date: 2/29/2016 4/21/2016 4/21/2016 4/20/2016 4/14/2016 4/20/2016 4/19/2016 4/20/2016 2/26/2016 2/26/2016 Sample Type: N N N N N N N N N N Sample Name: CS-GWA-36S CS-GWA-37D CS-GWA-37S CS-GWA-38D CS-GWA-3D CS-GWA-42S CS-GWA-43D CS-GWA-43S CS-GWA-44BR CS-GWA-44D Event: NCDEQ 02L GWQS, Constituent Fraction GWQS Source Unit IMAC, or DHHS pH N 6.5-8.5 02L SU 5.9 5.9 5.4 10 5.6 5.1 6.2 5.8 7.2 9.47 Specific Conductivity N NS/cm 421.2 715 347.8 337.1 514.5 117.3 320.4 124.4 892 721 Specific Conductivity N US/cm -- -- -- -- -- -- -- -- -- -- Temperature N Deg C 16.2 19.1 18.9 23.5 18.8 17.3 23.4 14 16.6 17.4 Turbidity, field N NTU 2.1 2.4 1.7 39.7 9.8 2.6 8.9 0.9 5.8 6.09 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 20 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Cliffside Steam Station Page 21 of 32 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: GWA-44S 2/29/2016 N CS-GWA-44S GWA-45D 2/24/2016 N CS-GWA-45D GWA-45S 2/26/2016 N CS-GWA-45S GWA-47D 4/20/2016 N CS-GWA-47 GWA-48BR 4/21/2016 N CS-GWA-48BR GWA-41D 4/14/2016 N CS-GWA-41D GWA-4S 4/14/2016 N CS-GWA-4S GWA-5BRU 4/14/2016 N CS-GWA-5BRU GWA-5S 4/13/2016 N CS-GWA-SS GWA-6D 4/14/2016 N CS-GWA-61D Constituent Fraction NCDEQ 02L GWQS, IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 5000 U 7500 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 25000 54000 5000 U 34800 65400 48200 5000 U 276000 28000 45300 Alkalinity, lab N ug/I 25000 61500 5000 U 34800 65400 48200 5000 U 276000 28000 45300 Aluminum D ug/I 100 U 100 U 2800 100 U 100 U 71.7 J 2900 100 U 100 U 98.4 J - Aluminum T ug/I 750 110 3500 102 100 U 71 J 3320 100 U 171 152 Antimony D ug/I 10U 2.4 0.5U 0.5U 0.5U 5U 0.5U 5U 0.5U 0.12J Antimony T 1 IMAC ug/I 1101-11 2.4 0.5 U 0.5 U 0.5 U 5 U 0.5 U 5 U 0.5 U 0.14 J Arsenic D -- ug/I 2 U 36.5 3 0.3 0.2 1 U 0.96 1.3 0.24 0.52 Arsenic T 10 02L ug/I 1 J 37.5 3 0.29 0.23 1 U 0.87 1.7 0.25 0.58 Barium D -- ug/I 48 20 50 78 3.9 J 31.1 16.5 37 30.1 9.8 J - Barium T 700 02L ug/I 56 19 56 80.9 4.1 J 33.9 17.7 39.7 31.6 9.8 Beryllium D -- ug/I 0.38 J 0.1 U 2.1 0.041 J+ 0.1 U 0.18 J 2 1 U 0.14 0.1 U Beryllium T 4 IMAC ug/I 0.42 J 0.013 J 2.3 0.055 J 0.1 U 1 U 2 0.17 J 0.14 0.1 U Boron D -- ug/I 50 U 50 U 50 U 130 50 U 168 164 29.6 J 50 U 50 UJ Boron T 700 02L ug/I 30 J 50 U 50 U 141 50 U 183 175 27 J 50 U 50 U Cadmium D -- ug/I 1.6 U 0.08 U 0.17 0.08 U 0.08 U 0.8 U 0.08 U 0.8 U 0.14 0.08 U Cadmium T 2 02L ug/I 1.6 U 0.08 U 0.17 0.08 U 0.08 U 0.8 U 0.06 J 0.8 U 0.12 0.08 U Calcium T -- ug/1 113000 23300 7400 13300 20700 67500 29300 80400 44800 16200 Carbon N -- ug/I -- -- -- -- -- 1000 U 1000 U 16800 -- 1000 U Chloride N 250000 02L ug/I 13500 4400 6200 27200 1900 6500 5400 12100 13400 2400 Chromium D -- ug/I IOU 0.37 J+ 2.3 0.4 J 0.14 J 5 U 0.24 J 5 U 0.28 J+ 0.79 Chromium T 10 02L ug/I IOU 0.78 J+ 2.9 J+ 0.53 J 0.25 J 5 UJ 1 J+ 5 UJ 0.84 J+ 1.2 J+ Chromium 6+ T 0.07 DHHS ug/I 0.071 J+ 0.13 J+ 1.9 0.03 U 0.03 U 0.03 U 0.03 U 0.11 0.06 0.69 Cobalt D -- ug/I 2.8 0.013 J 15.6 6 0.1 U 29.5 61.7 0.14 J 8.7 0.13 Cobalt T 1 IMAC ug/I 3.1 0.066 J 16.5 5.9 0.012 J 31.2 65.1 1 U 9 0.14 Copper D -- ug/I 1101-1 0.13 J 4.6 1.2 0.14 J 5 U 7.6 5 U 1.3 0.45 J+ Copper T 1000 02L ug/I 2.7 J 0.22 J 2.8 0.12 J+ 0.24 J 5 U 7.5 5 U 0.44 J 0.3 J Iron D -- ug/I 330 50 U 34 J 1020 1600 15400 16500 588 50 U 50 UJ Iron T 300 02L ug/I 1200 32 J 140 1130 1540 18000 18900 302 145 J+ 38.5 J Lead D -- ug/I 2U 0.1U 0.27 0.1U 0.1U 1U 0.41 1U 0.1U 0.1U Lead T 15 02L ug/I 2 U 0.1 U 0.2 0.11 0.1 U 1 U 0.5 1 U 0.1 U 0.1 U Magnesium T -- ug/I 26400 1310 4950 2660 2740 13100 13000 10900 33500 1050 Manganese D -- ug/I 140 5 U 450 1400 86.7 3810 1680 296 985 12.5 J - Manganese T 50 02L ug/I 150 5 U 480 1470 87.3 4300 1860 350 974 12.6 Mercury D -- ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U Mercury T 1 02L ug/I 0.2 U 0.074 J+ 6 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U Methane N ug/I 1.3 J+ 3.4 J+ 1.4 J+ 10 U 101-1 21.9 101-1 10 U 101-1 10 U Molybdenum D ug/I 10 U 3.6 0.5 U 2.7 0.22 J 5 U 0.5 U 5 U 0.5 U 0.5 Molybdenum T ug/I 10 U 3.7 0.5 U 2.7 0.23 J 5 U 0.5 U 5 U 0.5 U 0.56 Nickel D -- ug/I 10 U 0.5 U 7.2 3.4 0.5 U 13.3 16.3 5 U 14.5 1 Nickel T 100 02L ug/I 11 0.61 7.8 3.1 0.5 U 13.6 17.6 5 U 15.1 1.2 Nitrogen, NO2 plus NO3 N -- ug/1 980 191 4300 210 20 U 20 U 20 U 20 U 6200 34 Potassium T ug/I 7140 5140 3090 J 5270 5430 7570 6480 11500 7760 3180 J Selenium D -- ug/I 7.2 J 34.3 23.7 0.5 U 0.5 U 3.2 J 6.2 5 U 2.7 0.5 U Selenium T 20 02L ug/I 10 U 36 22.6 0.5 U 0.5 U 5 U 6.1 5 U 2.8 0.5 U Sodium T -- ug/I 6350 16400 3750 J 9210 6330 11700 4510 J 59300 6030 4270 J Strontium D ug/I 220 70 43 75.4 61.4 384 553 239 118 53.7 J - Strontium T -- ug/I 250 66 50 76.8 61.7 420 580 239 116 53.8 Sulfate N 250000 02L ug/I 361000 20200 43600 1300 12400 226000 177000 94800 191000 9900 Sulfide N -- ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U Thallium D -- ug/I 2 U 0.1 U 0.16 0.19 0.1 U 1 U 0.96 1 U 0.45 0.1 U Thallium T 0.2 IMAC ug/1 2 U 0.1 U 0.15 0.22 0.1 U 1 U 1.1 1 U 0.42 0.1 U Total Dissolved Solids N 500000 02L ug/I 558000 141000 J+ 81000 97000 126000 420000 261000 471000 348000 74000 Total Organic Carbon N -- ug/I 830 J 8200 1100 1000 U 1000 U -- -- -- 1300 -- Total Suspended Solids N ug/I 15400 2500 U 2900 3600 2500 U 2500 U 4500 3100 U 3500 2500 U Uranium, Natural T ug/I -- -- -- 0.5 U 0.5 U 0.18 J 5 U -- -- -- Vanadium D -- ug/I 6 U 160 0.5 U 0.36 0.3 U 3 U 0.11 J 3 U 0.18 J 4.6 Vanadium T 0.3 IMAC ug/1 2.7 J 179 0.24 J 0.45 0.3 U 3 U 0.59 0.77 J 0.51 5.3 Zinc D -- ug/I 5.7 J 10 U 15 10 J+ 10 U 9.3 J 29.8 15.7 J+ 4.3 J 25.6 J+ Zinc T 1000 02L ug/I 18J+ 10 U 15 8.5 J 10 U 4.3 J 29.2 10 U 3.4 J 15.9 J Dissolved Oxygen N mg/I 1.1 0.2 2.39 2.18 0.12 0.2 0.1 0.3 0.22 5.1 Oxidation Reduction Potential N mV 177.2 -23.8 425.1 -27.6 -231.6 7 246 -209.2 284 106 Cliffside Steam Station Page 21 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 22 of 32 CSA Supplement 2 Location: GWA-44S GWA-45D GWA-45S GWA-47D GWA-48BR GWA-41D GWA-4S GWA-5BRU GWA-5S GWA-6D Date: 2/29/2016 2/24/2016 2/26/2016 4/20/2016 4/21/2016 4/14/2016 4/14/2016 4/14/2016 4/13/2016 4/14/2016 Sample Type: N N N N N N N N N N Sample Name: CS-GWA-44S CS-GWA-45D CS-GWA-45S CS-GWA-47 CS-GWA-48BR CS-GWA-4D CS-GWA-4S CS-GWA-5BRU CS-GWA-SS CS-GWA-6D Event: NCDEQ 02L GWQS, Constituent Fraction GWQS Source Unit IMAC, or DHHS pH N 6.5-8.5 02L SU 5.7 9.3 4.57 6.01 7.62 5.6 4.2 7.2 5.25 8.1 Specific Conductivity N NS/cm 840 211.6 178.7 181.5 176.1 563 427 717 534.6 117.2 Specific Conductivity N US/cm -- -- -- -- -- -- -- -- -- -- Temperature N Deg C 18.2 17.5 16.5 17.6 16.7 18 17 16.9 18.7 17.2 Turbidity, field N NTU 7.4 1.1 4.79 4.51 1.97 3.4 3.9 7.8 8.75 4.1 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 22 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Cliffside Steam Station Page 23 of 32 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: IB -1D 4/15/2016 N CS -IB -1D IB -3D 4/15/2016 N CS -IB -3D IB -3S 4/15/2016 N CS -IB -3S MW -10D 4/18/2016 N CS -MW -10D MW -10S 4/18/2016 N CS -MW -10S MW -11S 4/15/2016 N CS -MW -11S MW -21 BR 4/19/2016 FD CS -MW -2I BR -FD MW -21 BR 4/19/2016 N CS-MW-21BR MW-22BR 4/15/2016 N CS-MW-22BR MW -23S 3/10/2016 N CS -MW -23S Constituent Fraction NCDEQ 02L GWQS, IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 68400 47100 12200 8300 5200 4500 J 57000 55500 30800 10500 Alkalinity, lab N ug/I 68400 47100 12200 8300 5200 4500 J 57000 55500 30800 10500 Aluminum D ug/I 50 J 100 U 141 100 U 314 100 U 100 U 100 U 100 U 100 U Aluminum T ug/I 102 100 U 1820 63.6 J 708 100 U 100 U 100 U 147 159 Antimony D ug/I 0.53 0.5 U 0.5 U 0.5 U 0.15 J 0.5 U 0.5 U 0.5 U 0.1 J 5 U Antimony T 1 IMAC ug/I 0.86 0.5 U 0.1 J 0.5 U 0.23 J 0.5 U 0.5 U 0.5 U 0.13 J 5 U Arsenic D -- ug/I 0.84 0.096 J 0.91 0.059 J 2 0.12 0.33 0.31 0.1 1 U Arsenic T 10 02L ug/I 0.81 0.12 1.5 0.054 J 2.3 0.14 0.29 0.3 0.15 1 U Barium D -- ug/I 11.3 55.9 39.5 23.8 66.9 70.6 8.4 7.9 11.7 53 Barium T 700 02L ug/I 13.7 53.9 58.3 25.7 68.6 70.4 8 8.4 12.4 152 Beryllium D -- ug/I 0.012 J 0.019 J 0.31 0.1 0.25 0.13 0.1 UJ 0.1 UJ 0.02 J 1.1 Beryllium T 4 IMAC ug/I 0.032 J 0.088 J 0.54 0.076 J 0.26 0.15 0.1 U 0.1 U 0.031 J 0.51 J+ Boron D -- ug/I 50 U 243 485 158 175 744 50 U 50 U 50 U 670 Boron T 700 02L ug/I 50 U 241 442 158 167 742 50 UJ 50 UJ 50 U 50 U Cadmium D -- ug/I 0.08 U 0.08 U 0.16 0.08 U 0.081 0.08 U 0.08 U 0.08 U 0.08 U 0.8 U Cadmium T 2 02L ug/I 0.08 U 0.08 U 0.15 0.08 U 0.1 0.05 J 0.08 U 0.08 U 0.08 U 0.8 U Calcium T -- ug/1 35900 36400 23800 6500 20300 33000 19000 19100 11300 34100 Carbon N -- ug/I 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U -- Chloride N 250000 02L ug/I 6300 4700 2300 11200 34600 58900 3700 3700 2300 14100 Chromium D -- ug/I 0.24 J 0.24 J 0.76 0.3 J+ 1 1.2 0.2 J 0.23 J 0.35 J 2.1 J Chromium T 10 02L ug/I 0.86 J 0.64 8.7 0.2 J+ 1.5 2.5 0.26 J+ 0.19 J+ 0.67 2.9 J+ Chromium 6+ T 0.07 DHHS ug/I 0.047 0.03 U 0.088 0.03 U 0.63 0.78 J+ 0.03 U 0.01 J 0.074 1.4 Cobalt D -- ug/I 0.0111 2.7 113 1.8 3.9 0.71 0.046 J 0.02 J 0.35 6.2 Cobalt T 1 IMAC ug/I 0.03 J 2.8 122 1.8 4.4 0.82 0.022 J 0.021 J 0.59 6.1 Copper D -- ug/I 0.22 J 0.13 J 1.2 14.2 4.6 2.1 1.6 J 0.36 J 0.29 J 3.4 J Copper T 1000 02L ug/I 0.36 J 0.15 J 2 8.4 1.4 J 0.18 J 0.31 J 0.12 J 1.2 3.8 J Iron D -- ug/I 50 U 9050 931 50 U 33.3 J 50 U 50 U 50 U 60.1 3000 Iron T 300 02L ug/I 50 U 8800 3840 50 343 50 U 29.9 J 50 U 443 193 J+ Lead D -- ug/I 0.1U 0.1U 0.12 0.1U 0.098J 0.1U 0.1U 0.1U 0.1U 1U Lead T 15 02L ug/I 0.1 U 0.1 U 1.6 0.1 U 0.39 0.1 U 0.1 U 0.1 U 0.12 1 U Magnesium T - ug/I 3290 6440 33100 4500 24200 7690 2090 2080 1850 19200 Manganese D -- ug/I 4J 4060 16900 100 217 1660 8.5 7.4 27.9 4200 Manganese T 50 02L ug/I 4.2 J 3850 22600 103 203 1660 8.8 9.6 35 233 Mercury D -- ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U Mercury T 1 02L ug/I 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.66 Methane N ug/I 10U 10U 10U 10U 10U 10U 10U 10U 10U 1.6 J+ Molybdenum D ug/I 2.7 0.12 J 0.5 U 0.5 U 0.5 U 0.5 U 0.48 J 0.49 J 0.37 J 5 U Molybdenum T ug/I 3.2 0.13 J 0.12 J 0.5 U 0.5 U 0.5 U 0.46 J 0.44 J 0.41 J- 5 U Nickel D -- ug/I 0.5 U 1.2 32.6 2.3 3.9 1.9 2 0.5 U 1.4 5.3 Nickel T 100 02L ug/I 0.5 U 1.4 38.7 1.7 4.2 2.7 0.5 U 0.5 U 2 5.6 Nitrogen, NO2 plus NO3 N -- ug/1 20 U 20 U 20 U 510 8200 320 20 U 20 U 460 310 Potassium T ug/I 7050 4070 J 5000 U 5000 U 5000 U 5000 U 3220 J 3220 J 2760 J 3060 J Selenium D -- ug/I 0.5 U 0.44 J 12.6 1.4 32.8 1.4 0.5 U 0.5 U 0.5 U 5 U Selenium T 20 02L ug/I 0.37 J 0.57 15.1 1.5 35.8 2 0.5 U 0.5 U 0.5 U 5 U Sodium T -- ug/I 11000 6200 8390 5550 6120 8380 4490 J 4470 J 5940 6630 Strontium D ug/I 111 128 19.3 46 46 37.5 61 56.8 54.4 2700 Strontium T -- ug/I 128 125 20.7 48.5 44.9 36 59.1 60.9 56.1 201 Sulfate N 250000 02L ug/I 43600 81700 229000 15900 87400 42100 7300 7300 8500 142000 Sulfide N -- ug/I 100 U 100 U 100 U 100 U 100 UJ 100 U 100 U 100 U 100 U 100 U Thallium D -- ug/I 0.1 U 0.1 U 0.27 0.068 J 0.15 0.029 J 0.1 U 0.1 U 0.1 U 1 U Thallium T 0.2 IMAC ug/1 0.1 U 0.1 U 0.33 0.064 J 0.16 0.049 J 0.1 U 0.1 U 0.1 U 1 U Total Dissolved Solids N 500000 02L ug/I 176000 202000 377000 65000 234000 178000 114000 J 102000 J 78000 234000 Total Organic Carbon N -- ug/I -- -- -- -- -- -- -- -- -- 530 J Total Suspended Solids N ug/I 3200 2500 U 2500 U 2900 13200 J 2500 U 2500 U 2500 U 2500 U 2500 U Uranium, Natural T ug/I -- -- -- 0.5 U 0.12 J -- -- -- -- -- Vanadium D -- ug/I 7 0.3 U 0.3 U 0.3 U 0.098 J 0.3 U 0.52 J 0.51 J 0.35 3 U Vanadium T 0.3 IMAC ug/1 7.3 0.12 J 5.8 0.3 U 0.48 0.3 U 0.5 0.4 0.37 3 U Zinc D -- ug/I 10 UJ 30.4 45.5 14 19.9 2.7 J 3.3 J+ 10 UJ 101-1 14 J+ Zinc T 1000 02L ug/I 10 U 30.2 46 3.6 J 14.9 J IOU 2.7 J 4.9 J 10 U 8.8 J+ Dissolved Oxygen N -- mg/I -- -- -- 3.09 4.4 4.7 0.89 0.89 1.6 2.4 Oxidation Reduction Potential N mV 268 126.5 276.1 85.1 85.1 49.9 229.6 Cliffside Steam Station Page 23 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 24 of 32 CSA Supplement 2 Location: IB -1D IB -3D IB -3S MW -10D MW -10S MW -11S MW -21 BR MW -21 BR MW-22BR MW -23S Date: 4/15/2016 4/15/2016 4/15/2016 4/18/2016 4/18/2016 4/15/2016 4/19/2016 4/19/2016 4/15/2016 3/10/2016 Sample Type: N N N N N N FD N N N Sample Name: CS -I13 -1D CS -I13 -31D CS -I13 -3S CS -MW -10D CS -MW -10S CS -MW -11S CS -MW -2I BR -FD CS-MW-21BR CS-MW-22BR CS -MW -23S Event: NCDEQ 02L GWQS, Constituent Fraction GWQS Source Unit IMAC, or DHHS pH N 6.5-8.5 02L SU 5.02 4.9 5.2 7.1 7.1 6.5 4.9 Specific Conductivity N NS/cm 114 415.3 316.3 152.2 152.2 99.8 429.6 Specific Conductivity N US/cm -- -- -- -- -- -- -- Temperature N Deg C 20 23 19.4 20 20 15.3 20.2 Turbidity, field N NTU 4.54 7 1.5 0.7 0.7 3.1 4.1 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 24 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Cliffside Steam Station Page 25 of 32 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: MW -24D 3/30/2016 N CS -MW -24D MW-24DR 3/30/2016 N CS-MW-24DR MW-2DA 4/14/2016 N CS-MW-2DA MW -30D 3/29/2016 N CS -MW -30D MW -30S 3/29/2016 N CS -MW -30S MW-32BR 3/29/2016 N CS-MW-32BR MW -32D 3/29/2016 N CS -MW -32D MW -32S 3/29/2016 N CS -MW -32S MW -34D 4/14/2016 N CS-MW-34BRU MW -34S 4/14/2016 N CS -MW -34S Constituent Fraction NCDEQ 02L GWQS, IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 5000 U 5000 U 5000 U 19200 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 3300 J+ 55600 J+ 62000 29200 J+ 3800 J+ 28600 J+ 16000 J+ 5000 U 60200 3100 J Alkalinity, lab N ug/I 3300 J+ 55600 J+ 62000 48500 J+ 3800 J+ 28600 J+ 16000 J+ 5000 U 60200 3100 J Aluminum D ug/I 100 U 100 U 100 U 130 100 U 100 U 110 100 U 100 U 100 U Aluminum T ug/I 100 U 100 U 103 408 J+ 271 J+ 100 U 760 J+ 117J+ 70.9 J 82.2 J Antimony D ug/I 0.5 U 0.5 U 0.36 J 1.1 0.5 U 0.5 U 0.28 J 0.5 U 0.5 U 0.5 U Antimony T 1 IMAC ug/I 0.5 U 0.5 U 0.36 J 0.99 J+ 0.12 J+ 0.5 U 0.38 J+ 0.5 U 0.5 U 0.5 U Arsenic D -- ug/I 0.16 0.1 U 0.23 0.48 0.1 U 0.22 0.15 0.1 U 0.1 U 0.1 U Arsenic T 10 02L ug/I 0.18 J+ 0.1 U 0.3 0.52 J+ 0.089 J+ 0.29 J+ 0.44 J+ 0.083 J+ 0.05 J 0.048 J Barium D -- ug/I 18 3.1 J 6.7 25 30 2.6 J 6.7 46 5 U 10 Barium T 700 02L ug/I 19.3 J+ 3.6 J+ 8.6 26.6 J+ 32 J+ 3.2 J+ 7.2 J+ 49.1 J+ 5 U 10.5 Beryllium D -- ug/I 0.043 J 0.042 J 0.1 U 0.1 U 0.038 J 0.1 U 0.1 U 0.13 0.1 U 0.028 J Beryllium T 4 IMAC ug/I 0.067 J 0.1 U 0.1 U 0.1 U 0.18 J+ 0.047 J+ 0.033 J+ 0.16 J+ 0.1 U 0.1 U Boron D -- ug/I 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U Boron T 700 02L ug/I 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U Cadmium D -- ug/I 0.06 J 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U Cadmium T 2 02L ug/I 0.08 U 0.08 U 0.08 U 0.08 U 0.061 J 0.08 U 0.078 J 0.08 U 0.08 U 0.08 U Calcium T -- ug/1 1760 J+ 16100 12400 17700 J+ 900 J+ 11200 J+ 11300 J+ 1910 J+ 22000 731 Carbon N -- ug/I -- -- 1000 U -- -- -- -- -- 1000 U 1000 U Chloride N 250000 02L ug/I 3900 1100 5700 7000 J+ 3700 J+ 3500 J+ 5000 J+ 7000 J+ 4800 2100 Chromium D -- ug/I 0.34 J 0.13 J 1.5 0.74 2 0.52 1.4 0.28 J 0.36 J 0.14 J Chromium T 10 02L ug/I 0.45 J+ 0.17 J+ 3 1.3 J+ 2.8 J+ 8.8 1.3 J+ 0.54 J+ 0.44 J+ 0.46 J+ Chromium 6+ T 0.07 DHHS ug/I 0.017 J+ 0.03 UJ 0.8 1.7 0.41 0.03 U 1.2 0.16 J+ 0.03 U 0.03 U Cobalt D -- ug/I 0.1 0.1 U 0.25 0.057 J 0.38 0.029 J 4.1 1.3 0.033 J 1.5 Cobalt T 1 IMAC ug/I 0.13 J+ 0.1 U 0.4 0.15 J+ 0.57 J+ 0.14 J+ 4 1.2 0.059 J 1.7 Copper D -- ug/I 0.83 J+ 0.11 J+ 2.1 0.52 1.2 0.13 J 2.6 6.8 0.13 J 2.7 Copper T 1000 02L ug/I 0.2 J+ 0.5 U 1.7 1.2 J+ 1.1 J+ 0.58 J+ 3.6 J+ 4.3 J+ 0.44 J 0.38 J Iron D -- ug/I 50 U 820 50 U 84 50 U 3600 53 50 U 267 50 U Iron T 300 02L ug/I 50 U 882 J+ 312 190 J+ 510 J+ 4160 30.8 J+ 188 J+ 489 91.9 Lead D -- ug/I 0.1U 0.1U 0.1 LI 0.1U 0.1 LI 0.1U 0.1U 0.1U 0.1U 0.1 LI Lead T 15 02L ug/I 0.1 U 0.1 U 0.19 0.12 J+ 0.21 J+ 0.1 U 0.2 J+ 0.1 U 0.1 U 0.1 U Magnesium T -- ug/I 1100 J+ 1850 J+ 2200 2340 J+ 1480 J+ 1980 J+ 1610 J+ 2200 J+ 1650 474 Manganese D -- ug/I 5.2 47 30.8 6.2 8 26 25 37 37.5 24.5 Manganese T 50 02L ug/I 5.1 J+ 47.7 130 8.6 12.3 30.4 25 38.2 43.4 26.8 Mercury D -- ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U Mercury T 1 02L ug/I 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U Methane N ug/I 1.8 J+ 1.8 J+ 10 U 1.7 J+ 1.6 J+ 1.7 J+ 1.6 J+ 1.5 J+ 101-1 10 U Molybdenum D ug/I 0.5 U 0.14 J 4 3.6 0.5 U 1.5 0.31 J 0.5 U 0.5 U 0.5 U Molybdenum T ug/I 0.5 U 0.14 J 4.1 3.6 0.5 U 1.6 J+ 0.31 J+ 0.5 U 0.14 J 0.5 U Nickel D -- ug/I 0.65 0.5 U 2.1 0.83 1.3 1 13.9 2.5 0.5 U 1.5 Nickel T 100 02L ug/I 0.66 0.5 U 2.8 1.1 J+ 1.8 J+ 5.3 J+ 12.9 2.4 J+ 0.59 0.5 U Nitrogen, NO2 plus NO3 N -- ug/1 2700 20 U 86 240 J+ 630 J+ 20 U 2400 3800 20 U 84 Potassium T ug/I 5000 U 2510 J 3790 J 5500 5000 U 2650 J 5000 U 5000 U 5000 U 5000 U Selenium D -- ug/I 0.5U 0.5U 0.5U 1.2 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Selenium T 20 02L ug/I 0.5 U 0.5 U 0.5 U 1 0.5 U 0.5 U 0.5 U 0.36 J 0.5 U 0.5 U Sodium T -- ug/I 4410 J 7660 17000 8040 J+ 5000 U 5770 J+ 4000 J+ 4090 J+ 4990 J 1610 J Strontium D ug/I 22 72 85.2 70 8.2 51 38 24 64.8 5.8 Strontium T -- ug/I 22.6 74.8 86.6 70.3 J+ 8.1 J+ 54.5 J+ 38.6 J+ 25.9 J+ 68.8 9.5 Sulfate N 250000 02L ug/I 940 J 9000 13100 13700 J+ 1000 U 15800 J+ 10600 J+ 540 J+ 10800 1000 U Sulfide N -- ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U Thallium D -- ug/I 0.1 U 0.1 U 0.017 J 0.1 U 0.024 J 0.1 U 0.1 U 0.023 J 0.1 U 0.1 U Thallium T 0.2 IMAC ug/1 0.1 U 0.1 U 0.024 J 0.1 U 0.078 J 0.1 U 0.1 U 0.043 J 0.1 U 0.017 J Total Dissolved Solids N 500000 02L ug/I 27000 96000 122000 98000 J+ 25000 U 96000 J+ 62000 J+ 41000 J+ 114000 25000 U Total Organic Carbon N -- ug/I 1000 U 9400 -- 1000 U 1000 U 1000 U 1000 U 1000 U -- - Total Suspended Solids N ug/I 2500 U 2500 U 6000 6500 3100 6300 5000 2500 U 5000 U 2500 U Uranium, Natural T ug/I 0.5 U 0.5 U -- 0.31 J 0.5 U 0.5 U 0.5 U 0.5 U -- -- Vanadium D -- ug/I 0.079 J 0.3 U 0.27 J 20.2 0.3 U 0.3 U 0.56 0.3 U 0.3 U 0.3 U Vanadium T 0.3 IMAC ug/1 0.3 U 0.3 U 0.48 21.5 0.74 J+ 0.17 J+ 0.63 J+ 0.18 J+ 0.13 J 0.16 J Zinc D -- ug/I 6J 10 U 6.4 J 10 U 5.7 J+ 10 U 8J+ 9.1 J+ 10 UJ 8.4 J+ Zinc T 1000 02L ug/I 10 U 10 U 5.4 J 3.2 J+ 6.8 J+ IOU 5.9 J+ 7.1 J+ 2.9 J 3.2 J Dissolved Oxygen N mg/I 7.3 0.2 2.4 0.9 5.7 0.2 4.2 6.3 0.3 6.8 Oxidation Reduction Potential N mV 244 -95 91.6 164 318 -108 271 367 -106.7 196.7 Cliffside Steam Station Page 25 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 26 of 32 CSA Supplement 2 Location: MW -24D MW-24DR MW-2DA MW -30D MW -30S MW-32BR MW -32D MW -32S MW -34D MW -34S Date: 3/30/2016 3/30/2016 4/14/2016 3/29/2016 3/29/2016 3/29/2016 3/29/2016 3/29/2016 4/14/2016 4/14/2016 Sample Type: N N N N N N N N N N Sample Name: CS -MW -24D CS-MW-24DR CS-MW-2DA CS -MW -30D CS -MW -30S CS-MW-32BR CS -MW -32D CS -MW -32S CS-MW-34BRU CS -MW -34S Event: NCDEQ 02L GWQS, Constituent Fraction GWQS Source Unit IMAC, or DHHS pH N 6.5-8.5 02L SU 5.3 7.1 6.8 8.9 5.3 7 6.3 4.8 7.4 5.4 Specific Conductivity N NS/cm 53 136 171.1 155 32 125 108 68 151.5 20.3 Specific Conductivity N US/cm 53 136 -- 155 32 125 108 68 -- -- Temperature N Deg C 15 15 18 17 18 18 18 18 20.2 18.4 Turbidity, field N NTU 2 0.6 7.9 4 5 1.5 3.8 5 5.8 8.7 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 26 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Cliffside Steam Station Page 27 of 32 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: MW-36BRU 4/14/2016 N CS-MW-36BRU MW -36S 4/14/2016 N CS -MW -36S MW -38D 4/14/2016 N CS -MW -38D MW -38S 4/14/2016 N CS -MW -38S MW-40BRU 4/14/2016 N CS-MW-40BRU MW -40S 4/14/2016 N CS -MW -40S MW -42D 4/13/2016 N CS -MW -42D MW -42S 4/14/2016 N CS -MW -42S MW -8D 4/14/2016 N CS -MW -BD MW -8S 4/14/2016 N CS -MW -BS Constituent Fraction NCDEQ 02L GWQS, IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 172000 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 69400 11200 64500 14500 117000 10400 202000 20800 14800 174000 Alkalinity, lab N ug/I 69400 11200 64500 14500 117000 10400 374000 20800 14800 174000 Aluminum D ug/I 100 U 100 U 100 U 100 U 100 U 100 U 1430 100 UJ 100 U 100 U Aluminum T ug/I 100 U 74.4 J 80.5 J 88.9 J 100 U 143 1700 131 100 U 100 U Antimony D ug/I 0.1 J 0.5 U 5 U 0.5 U 5 U 0.5 U 0.89 0.12 J 0.5 U 5 U Antimony T 1 IMAC ug/I 0.28 J 0.5 U 5 U 0.5 U 5 U 0.5 U 3.5 0.24 J 0.5 U 5 U Arsenic D -- ug/I 0.17 0.05 J 1 U 0.069 J 1.7 0.051 J 3.7 0.31 0.1 U 1 U Arsenic T 10 02L ug/I 0.29 0.052 J 1 U 0.083 J 2.2 0.07 J 4.7 0.73 0.1 U 1 U Barium D -- ug/I 5 U 76.3 36.8 37.4 15.7 64.4 17.7 31.6 J- 37.3 37 Barium T 700 02L ug/I 5 U 71.2 40.7 38.3 16.8 67.8 20.7 29.8 34.8 33.7 Beryllium D -- ug/I 0.01 J+ 0.045 J 1 UJ 0.11 1 UJ 0.027 J 0.1 UJ 0.1 U 0.018 J 1 U Beryllium T 4 IMAC ug/I 0.1 U 0.019 J 1 U 0.15 1 U 0.18 0.1 U 0.1 U 0.089 J 1 U Boron D -- ug/I 50 U 66 198 112 50 U 27.6 J 30.3 J 50 UJ 104 190 Boron T 700 02L ug/I 50 U 62.6 212 120 50 U 27.1 J 50 U 50 U 107 172 Cadmium D -- ug/I 0.08 U 0.08 U 0.8 U 0.17 0.8 U 0.08 U 0.08 U 0.08 U 0.08 U 0.8 U Cadmium T 2 02L ug/I 0.08 U 0.08 U 0.8 U 0.2 0.8 U 0.08 U 0.08 U 0.08 U 0.08 U 0.8 U Calcium T -- ug/1 22700 7860 99500 28600 62600 32000 29600 8080 15100 81400 Carbon N -- ug/I 1000 U 1000 U 1000 U 1000 U 740 J 1000 U 3900 15500 1000 U 1000 U Chloride N 250000 02L ug/I 3200 1000 U 4300 6600 6000 15300 7300 2800 45700 37000 Chromium D -- ug/I 0.13 J 0.35 J 5 U 0.58 5 U 0.91 7.8 0.61 0.22 J 5 U Chromium T 10 02L ug/I 0.27 J 0.36 J 5 UJ 1.3 J+ 5 UJ 1.4 J+ 8.5 1.3 J+ 0.28 J 5 U Chromium 6+ T 0.07 DHHS ug/I 0.051 0.15 0.03 U 0.2 0.034 0.63 8.8 0.29 0.03 U 0.03 U Cobalt D -- ug/I 0.013 J 0.035 J 2.8 3.5 1 U 0.48 0.24 0.42 4.7 1.7 Cobalt T 1 IMAC ug/I 0.035 J 0.028 J 3.3 3.8 1 U 0.66 0.26 0.53 4.6 1.7 Copper D -- ug/I 0.5 U 1.8 5 U 2.8 5 U 1.4 2.1 0.95 J+ 0.31 J 5 U Copper T 1000 02L ug/I 0.5 U 1 5 U 0.14 J 5 U 0.32 J 2.5 0.57 0.5 U 5 U Iron D -- ug/I 38 J 50 U 142 283 50 U 50 U 50 U 50 UJ 30300 186 Iron T 300 02L ug/I 54.6 68.8 252 408 118 144 33.7 J 163 30100 J- 325 Lead D -- ug/I 0.1U 0.1U 1U 0.1U 1U 0.1U 0.1U 0.1 LI 0.1U 1U Lead T 15 02L ug/I 0.1 U 0.1 U 1 U 0.1 1 U 0.14 0.23 0.11 0.1 U 1 U Magnesium T -- ug/I 1320 3840 25000 30800 3680 13100 2400 3160 4800 15000 Manganese D -- ug/I 39.1 2.8 J 1200 418 55.3 22.2 5 U 9.7 J- 4740 1980 Manganese T 50 02L ug/I 28.6 3.3 J 1400 452 58 25.3 5 U 10.9 4560 J- 2030 Mercury D -- ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U Mercury T 1 02L ug/I 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U Methane N ug/I 23.9 10 U 10 U 22 10 U 10 U 18.5 10 U 12.5 10 U Molybdenum D ug/I 0.74 0.5 U 5 U 0.5 U 196 0.5 U 2.7 0.5 U 0.5 U 5 U Molybdenum T ug/I 1.1 0.5 U 1.3 J 0.5 U 202 0.5 U 2.8 0.16 J 0.5 U 5 U Nickel D -- ug/I 0.5 U 0.98 27.6 3.6 5 U 1 1.1 1.8 0.5 U 5 U Nickel T 100 02L ug/I 0.5 U 0.5 U 29.8 2.4 5 U 1.3 1.2 2.3 0.5 U 5 U Nitrogen, NO2 plus NO3 N -- ug/1 20 U 20 U 20 U 410 100 540 20 U 410 20 U 39 Potassium T ug/I 5000 U 2550 J 8630 3750 J 10000 5000 U 262000 5000 U 3260 J 2610 J Selenium D -- ug/11 0.5 U 0.5 U 5 U 0.6 5 U 0.88 0.82 0.5 U 0.5 U 5 U Selenium T 20 02L ug/I 0.5 U 0.5 U 5 U 0.62 5 U 0.58 0.67 0.39 J 0.5 U 5 U Sodium T -- ug/I 9730 4090 J 12400 8230 8910 5100 44500 3180 J 15400 11700 Strontium D ug/I 68.8 79.1 283 97.3 173 129 170 44.9 J- 97.5 131 Strontium T -- ug/I 59 72.4 301 106 174 134 187 42.5 91.2 115 Sulfate N 250000 02L ug/I 26500 1000 U 280000 171000 74000 106000 122000 13600 51800 58600 Sulfide N -- ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U Thallium D -- ug/I 0.1 U 0.1 U 1 U 0.1 U 1 U 0.1 U 0.1 U 0.026 J 0.1 U 1 U Thallium T 0.2 IMAC ug/1 0.1 U 0.1 U 1 U 0.028 J 1 U 0.061 J 0.1 U 0.034 J 0.1 U 1 U Total Dissolved Solids N 500000 02L ug/I 95000 59000 518000 291000 257000 199000 650000 60000 192000 316000 Total Organic Carbon N -- ug/I -- -- -- -- -- -- -- -- -- -- Total Suspended Solids N ug/I 2500 U 3800 2500 U 3200 2500 U 4800 17700 2500 U 5500 2500 U Uranium, Natural T ug/I 0.5 U 0.5 U 5 U 0.5 U -- -- -- -- -- -- Vanadium D -- ug/I 0.075 J 0.18 J 3 U 0.2 J 0.92 J 0.18 J 37.6 0.3 U 0.3 U 3 U Vanadium T 0.3 IMAC ug/1 0.097 J 0.26 J 3 U 0.41 3 U 0.64 35.1 0.39 0.3 U 3 U Zinc D -- ug/I 6.8 J 11.2 J 18.5 20.9 6.4 J 2.8 J IOU 136 10 UJ 10 UJ Zinc T 1000 02L ug/I 10 UJ 5.2 J+ 16.3 16.3 23.8 10 U 25.1 125 3.4 J+ 10 UJ Dissolved Oxygen N -- mg/I 0.3 3.1 0.17 0.14 6.79 4.9 3.3 3.8 0.5 0.8 Oxidation Reduction Potential N mV -150.2 279.7 110 199 6.63 278 -82.5 221.1 -2.3 -9.4 Cliffside Steam Station Page 27 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 28 of 32 CSA Supplement 2 Location: MW-36BRU MW -36S MW -38D MW -38S MW-40BRU MW -40S MW -42D MW -42S MW -8D MW -8S Date: 4/14/2016 4/14/2016 4/14/2016 4/14/2016 4/14/2016 4/14/2016 4/13/2016 4/14/2016 4/14/2016 4/14/2016 Sample Type: N N N N N N N N N N Sample Name: CS-MW-36BRU CS -MW -36S CS -MW -38D CS -MW -38S CS-MW-40BRU CS -MW -40S CS -MW -42D CS -MW -42S CS -MW -BD CS -MW -BS Event: NCDEQ 02L GWQS, Constituent Fraction GWQS Source Unit IMAC, or DHHS pH N 6.5-8.5 02L SU 8.4 5.5 5.94 5.27 7.4 5.5 11.5 5.4 6 7 Specific Conductivity N NS/cm 159.2 105.6 707 432 381 313 1993 100.1 282.2 544.9 Specific Conductivity N US/cm -- -- -- -- -- -- -- -- -- -- Temperature N Deg C 18.2 13.7 18 19 17 18 17.7 16.7 17.5 18.1 Turbidity, field N NTU 1.1 6.7 3 6.38 1.39 8 15.4 7.1 5.1 6.4 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTLI - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 28 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Cliffside Steam Station Page 29 of 32 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: U5 -1D 4/13/2016 N CS -U5 -1D U5 -1S 4/13/2016 N CS -U5 -1S U5-2BR 3/3/2016 N CS-U5-2BR U5 -2D 4/13/2016 N CS -U5 -2D U5 -31D 4/13/2016 N CS -1-15-31D U5 -3S -A 3/8/2016 N CS -U5 -3S -A U5-4BR 4/13/2016 N CS-U5-4BR U54D 4/13/2016 N CS -U5 -4D U54S 4/13/2016 N CS -U5 -4S 1,15-5D 4/14/2016 N CS -U5 -5D Constituent Fraction NCDEQ 02L GWQS, IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 1060000 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 48800 98300 92900 273000 40200 39800 5000 U 79500 15900 69100 Alkalinity, lab N ug/I 48800 98300 92900 273000 40200 39800 1280000 79500 15900 69100 Aluminum D ug/I 130 100 U 100 U 100 U 100 U 100 U 184 100 U 100 U 100 U Aluminum T ug/I 168 100 U 140 439 129 360 174 53.4 J 141 100 U Antimony D ug/I 0.21 J 0.5 U 0.16 J 5 U 0.5 U 0.5 U 6.9 1.2 0.44 J 5 U Antimony T 1 IMAC ug/I 0.23 J 0.5 U 0.18 J 5 U 0.5 U 0.5 U 6.3 1.2 0.55 5 U Arsenic D -- ug/I 1.7 2 99.7 2050 0.11 0.08 J 3.1 0.7 0.34 1.1 Arsenic T 10 02L ug/I 1.8 3.1 106 1630 0.14 0.19 2.8 0.76 0.49 1.1 Barium D -- ug/I 6.8 145 42 239 33.7 29 305 10.2 21 16.2 Barium T 700 02L ug/I 6.6 140 51 250 35.2 36.1 284 10.8 22.4 16.6 Beryllium D -- ug/I 0.1 UJ 0.1 UJ 0.063 J 1 UJ 0.015 J 0.069 J 1 U 0.08 J 0.12 0.1 J+ Beryllium T 4 IMAC ug/I 0.1 U 0.1 U 0.075 J 1 U 0.11 0.042 J+ 0.19 J 0.15 0.095 J 1 U Boron D -- ug/I 50 U 27.4 J 55 284 123 120 92.7 50 U 239 418 Boron T 700 02L ug/I 25.3 J 27.9 J 85 286 124 136 91.7 50 U 235 448 Cadmium D -- ug/I 0.08 U 0.08 U 0.08 U 0.8 U 0.052 J 0.05 J 0.8 U 0.08 U 0.08 U 0.8 U Cadmium T 2 02L ug/I 0.08 U 0.08 U 0.08 U 0.8 U 0.08 U 0.055 J 0.8 U 0.08 U 0.08 U 0.8 U Calcium T -- ug/1 27700 18800 25700 87800 22000 23700 136000 26500 14000 104000 Carbon N -- ug/I 1000 U 5600 -- 1100 1000 U -- 178000 2000 1000 U 690 J Chloride N 250000 02L ug/I 4800 8700 5800 6400 3500 3500 8800 2500 3400 4900 Chromium D -- ug/I 0.56 J+ 0.59 J+ 0.16 J 5 UJ 0.77 0.53 8.5 1.1 J+ 2.9 5 U Chromium T 10 02L ug/I 0.29 J+ 1.2 J+ 0.56 J+ 1.9 J 1.3 1.6 J+ 8.8 3.6 3.8 5 U Chromium 6+ T 0.07 DHHS ug/I 0.043 0.03 U 0.03 U 0.03 U 0.33 0.1 10 0.37 3.3 0.03 U Cobalt D -- ug/I 0.077 J 1.8 11.2 2.2 7.7 14.4 0.14 J 0.058 J 2.8 19.7 Cobalt T 1 IMAC ug/I 0.025 J 3.1 11.4 2.4 7.7 15.1 0.18 J 0.082 J 3 19.6 Copper D -- ug/I 0.5 U 0.5 U 0.15 J 5 U 2.2 6.2 8.6 3.7 2.2 5 U Copper T 1000 02L ug/I 0.33 J 0.34 J 0.5 U 1.4 J 0.32 J 0.58 5.8 10.1 0.21 J 2.5 J Iron D -- ug/I 29 J 112000 3900 43100 56.4 61 50 U 50 U 50 U 23400 Iron T 300 02L ug/I 50 U 133000 4500 40500 237 616 50 U 52.8 125 27200 Lead D -- ug/I 0.1U 0.1U 0.12 1U 0.1U 0.73 1U 0.1U 0.1U 1U Lead T 15 02L ug/I 0.1 U 0.12 0.24 1.2 0.1 U 0.24 1 U 0.11 0.26 1 U Magnesium T -- ug/I 969 7490 4980 24600 8530 8940 100 U 697 5470 17600 Manganese D -- ug/I 35.2 10600 2800 1380 1200 1200 5 U 3.1 J 29.5 4690 Manganese T 50 02L ug/I 11.4 9450 2800 1390 1190 1280 5 U 3.5 J 30.7 5080 Mercury D -- ug/I 0.2 U 0.36 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U Mercury T 1 02L ug/I 0.2 U 0.34 0.2 U 0.071 J 0.15 J 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U Methane N ug/I 10 U 6050 191 J 3220 403 177 10 U 10 U 10 U 22.4 J - Molybdenum D ug/I 2.3 0.11 J 3.6 54.8 0.5 U 0.5 U 14.6 2.3 0.5 U 5 U Molybdenum T ug/I 2.6 0.16 J 3.6 43.5 0.5 U 0.2 J 14.8 2.4 0.5 U 5 U Nickel D -- ug/I 0.85 0.5 U 1.6 5 U 2.9 2.1 5 U 1.3 1.3 64.3 Nickel T 100 02L ug/I 0.5 U 0.97 1.7 5 U 2.6 2.6 5 U 1.7 1.2 66.5 Nitrogen, NO2 plus NO3 N -- ug/1 12J 20 U 20 U 20 U 130 94 20 U 120 840 20 U Potassium T ug/I 10100 5000 U 3540 J 11600 5000 U 5000 U 460000 5120 5000 U 10600 Selenium D -- ug/I 0.5 U 0.44 J 0.5 U 5 U 0.51 0.38 J 5 U 0.5 U 1.1 5 U Selenium T 20 02L ug/I 0.5 U 0.68 0.5 U 5 U 0.68 0.45 J 5 U 0.5 U 1 5 U Sodium T -- ug/I 9380 1060 J 7000 5130 2810 J 2940 J 268000 14700 4190 J 13100 Strontium D ug/I 92.6 141 190 2190 67.6 67 3680 83.9 9.2 224 Strontium T -- ug/I 86.9 136 210 2120 69.1 74.4 3460 93 9.6 230 Sulfate N 250000 02L ug/I 49000 7300 10000 92800 51100 55500 133000 17200 39800 379000 Sulfide N -- ug/I 100 U 100 U 100 U 100 UJ 100 UJ 100 U 500 U 100 U 100 U 100 U Thallium D -- ug/I 0.1 U 0.1 U 0.23 1 U 0.065 J 0.084 J 1 U 0.1 U 0.04 J 1 U Thallium T 0.2 IMAC ug/1 0.1 U 0.1 U 0.22 1 U 0.081 J 0.084 J 1 U 0.1 U 0.033 J 1 U Total Dissolved Solids N 500000 02L ug/I 139000 153000 128000 410000 88000 137000 1380000 124000 64000 599000 Total Organic Carbon N -- ug/I -- -- 33900 -- -- 1000 U -- -- -- -- Total Suspended Solids N ug/I 2500 U 33400 4300 98200 3800 6100 5000 U 2500 U 4800 13200 Uranium, Natural T ug/I -- -- -- -- -- -- -- -- -- -- Vanadium D -- ug/I 0.48 0.18 J 0.3 J+ 3 U 0.078 J 0.3 U 33.9 1.3 0.16 J 3 U Vanadium T 0.3 IMAC ug/1 0.59 0.44 0.53 J+ 2.8 J 0.36 1 32.9 1.3 0.74 3 U Zinc D -- ug/I 15 17.4 5.8J 8.9J 4.9J 11 8.7J 7.2J 7.4J 20.8 Zinc T 1000 02L ug/I 13.5 12.7 15 35.9 2.6 J 8J 4J 8.9 J 3.8 J 14.9 Dissolved Oxygen N -- mg/I 0.8 0.3 2.8 0.1 0.1 0.2 3.2 1.9 1.6 4.5 Oxidation Reduction Potential N mV 89.8 -97.2 1.7 -99.7 215.3 196 -30.1 178 305.5 -42.1 Cliffside Steam Station Page 29 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratorys method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 30 of 32 CSA Supplement 2 Location: U5 -1D U5 -1S U5-2BR U5 -2D U5 -3D U5 -3S -A U5-4BR U54D U5 -4S U5 -5D Date: 4/13/2016 4/13/2016 3/3/2016 4/13/2016 4/13/2016 3/8/2016 4/13/2016 4/13/2016 4/13/2016 4/14/2016 Sample Type: N N N N N N N N N N Sample Name: CS -U5 -1D CS -U5 -1S CS-U5-2BR CS -U5 -2D CS -U5 -3D CS -U5 -3S -A CS-U5-4BR CS -1-15-4D CS -U5 -4S CS -U5 -5D Event: Constituent Fraction NCDEQ 02L GWQS,IMAC, GWQS Source or DHHS Unit pH N 6.5-8.5 02L SU 8.7 6.3 5.8 6.4 5.6 5.5 12.5 8 5.2 6.3 Specific Conductivity N PS/cm 224.4 562.1 224.9 754 208.2 222.6 6240 207.4 150.6 943 Specific Conductivity N us/cm -- -- -- -- -- -- -- -- Temperature N Deg C 18.4 18.4 15.9 20.6 18.2 18.2 19.6 17.5 19.3 13.4 Turbidity, field N NTU 0.8 5.1 3.6 9.1 9.5 9.2 6.14 1.9 8.4 4.5 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratorys method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 30 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Cliffside Steam Station Page 31 of 32 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: U5 -6D 4/13/2016 N CS -U5 -6D U5 -7D 4/14/2016 N CS -U5 -7D U5 -8D 4/13/2016 N CS -1-15-81D U5 -8S 4/13/2016 N CS -U5 -8S Constituent Fraction NCDEQ 02L GWQS, IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 5000 U 138000 38400 143000 Alkalinity, lab N ug/I 5000 U 138000 38400 143000 Aluminum D ug/I 1130 214 100 U 100 U Aluminum T ug/I 1120 294 50.8 J 95.8 J Antimony D ug/I 0.5 U 1.1 J 0.5 U 5 U Antimony T 1 IMAC ug/I 0.5 U 1.11 0.14 J 5 U Arsenic D -- ug/I 0.45 1.5 0.12 16 Arsenic T 10 02L ug/I 0.48 1.5 0.13 16.1 Barium D -- ug/I 19.6 83.8 13.5 58.1 Barium T 700 02L ug/I 19.7 90.2 13.2 56.3 Beryllium D -- ug/I 0.84 1 UJ 0.013 J 1 U Beryllium T 4 IMAC ug/I 0.81 1 U 0.1 U 0.26 J Boron D -- ug/I 185 98.6 43.3 J 31.2 J Boron T 700 02L ug/I 184 103 130 49 J Cadmium D -- ug/I 0.058 J 0.8 U 0.08 U 0.8 U Cadmium T 2 02L ug/I 0.052 J 0.8 U 0.08 U 0.8 U Calcium T -- ug/1 33700 97000 J- 11000 59800 Carbon N -- ug/I 1000 U 7500 -- -- Chloride N 250000 02L ug/I 5400 5700 3100 4300 Chromium D -- ug/I 0.78 J+ 3.8 J 1.7 J+ 5 UJ Chromium T 10 02L ug/I 0.72 5.6 1.2 J+ 5 UJ Chromium 6+ T 0.07 DHHS ug/I 0.03 U 10.2 0.65 0.03 U Cobalt D -- ug/I 44 0.93 J 0.24 2.9 Cobalt T 1 IMAC ug/I 40.4 1.5 0.41 2.7 Copper D -- ug/I 5.6 1.7 J 0.66 5 U Copper T 1000 02L ug/I 0.5 U 2.4 J 0.67 5 U Iron D -- ug/I 19400 50 U 50 U 7340 Iron T 300 02L ug/I 19600 70.8 39.9 J+ 7020 J+ Lead D -- ug/I 0.28 1 U 0.1 U 1 U Lead T 15 02L ug/I 0.3 1 U 0.16 1 U Magnesium T -- ug/I 14000 1560 2660 7380 Manganese D -- ug/I 1670 12.4 49.3 3000 Manganese T 50 02L ug/I 1630 65 51.3 2800 Mercury D -- ug/I 0.2 U 0.2 U 0.2 U 0.2 U Mercury T 1 02L ug/I 0.2 U 0.2 U 0.2 U 0.2 U Methane N ug/I 16.6 10 U 10 U 8580 Molybdenum D ug/I 0.5 U 28.1 0.22 J 5 U Molybdenum T ug/I 0.5 U 30 0.13 J 5 U Nickel D -- ug/I 14.6 5 U 3 5 U Nickel T 100 02L ug/I 12.5 5 U 2.6 5 U Nitrogen, NO2 plus NO3 N -- ug/1 20 U 20 U 470 20 U Potassium T ug/I 6680 41400 5000 U 4110 J Selenium D -- ug/I 2.7 5 U 0.5 U 5 U Selenium T 20 02L ug/I 3.3 5 U 0.5 U 5 U Sodium T -- ug/I 5030 38900 4100 J 2460 J Strontium D ug/I 486 830 42.3 138 Strontium T -- ug/I 476 886 42.9 132 Sulfate N 250000 02L ug/I 195000 243000 3400 51400 Sulfide N -- ug/I 100 U 100 U 100 U 100 U Thallium D -- ug/I 0.63 1 U 0.029 J 1 U Thallium T 0.2 IMAC ug/1 0.6 1 U 0.1 U 1 U Total Dissolved Solids N 500000 02L ug/I 283000 476000 66000 230000 Total Organic Carbon N -- ug/I -- -- 1000 U 570 J Total Suspended Solids N ug/I 2500 U 81700 2500 U 11200 Uranium, Natural T ug/I -- -- -- -- Vanadium D -- ug/I 0.18 J 6.4 0.89 3 U Vanadium T 0.3 IMAC ug/1 0.2 J 7 0.86 3 U Zinc D -- ug/I 23.3 3.9 J 2.8 J 10 U Zinc T 1000 02L ug/I 15.8 35.9 7.6 J 20.7 Dissolved Oxygen N mg/I 0.08 -- 1.5 0.3 Oxidation Reduction Potential N mV 193 182.4 -69.8 Cliffside Steam Station Page 31 of 32 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratorys method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 32 of 32 CSA Supplement 2 Location: U5 -6D U5 -7D U5 -8D U5 -8S Date: 4/13/2016 4/14/2016 4/13/2016 4/13/2016 Sample Type: N N N N Sample Name: CS -U5 -6D CS -U5 -7D CS -U5 -8D CS -U5 -8S Event: NCDEQ 02L GWQS, T Constituent Fraction GWQS Source Unit ]NINE IMAC, or DHHS pH N 6.5-8.5 02L SU 4.66 41, 6.6 Specific Conductivity N PS/cm 445 100 406.5 Specific Conductivity N us/cm -- -- -- Temperature N Deg C 18 15.9 16.5 Turbidity, field N NTU 7.19 3.2 6.5 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratorys method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 32 of 32 CSA Supplement 2 Table 3-2: Round 5 Analytical Results of Porewater Monitoring Cliffside Steam Station Page 1 of 4 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: AB -3S 4/13/2016 N CS -AB -3S AB-3SL 4/13/2016 N CS-AB-3SL AB -4S 4/13/2016 N CS -AB -4S AB-4SL 4/13/2016 N CS-AB-4SL AB -5S 4/13/2016 FD CS -FD -AB -SS AB -5S 4/13/2016 N CS -AB -SS AB -6S 4/13/2016 N CS -AB -6S AS -7S 4/14/2016 N CS -AS -7S Constituent Fraction NCDEQ 02L GWQS,IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 1 5000 U 5000 U 5000 U 8800 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 598000 24400 27600 100000 110000 104000 34300 175000 Alkalinity, lab N ug/I 598000 24400 27600 109000 110000 104000 34300 175000 Aluminum D - ug/I 56.2 J 1040 315 1290 64.4 J 59.8 J 74.7 J 100 U Aluminum T - ug/I 97.7 J 1220 300 1270 79.6 J 89.4 J 93.7 J 100 U Antimony D - ug/I 5 U 2.8 1.3 J 7.8 5 U 5 U 2.6 J 5 U Antimony T 1 IMAC ug/I 5 U 3.1 5 U 7.5 5 U 5 U 2.6 J 5 U Arsenic D -- ug/I 207 862 112 1220 982 1070 216 91.4 Arsenic T 10 02L ug/I 194 934 103 1330 1080 1010 198 109 Barium D -- ug/I 81.7 186 122 90.8 194 199 144 26 Barium T 700 02L ug/I 76.7 199 120 94.3 196 196 142 27.5 Beryllium D -- ug/I 1 U 0.022 J 1 U 0.1 U 0.12 J 1 U 0.31 J 1 U Beryllium T 4 IMAC ug/I 1 U 0.1 U 1 U 0.029 J 1 U 1 U 1 U 1 U Boron D -- ug/I 3770 868 1390 1650 3080 3090 2000 1170 Boron T 700 02L ug/I 3550 895 1400 1590 2990 2940 1960 1250 Cadmium D -- ug/I 0.8U 0.08U 0.8U 0.08U 0.8U 0.8U 0.8U 0.8U Cadmium T 2 02L ug/I 0.8 U 0.08 U 0.8 U 0.08 U 0.8 U 0.8 U 0.8 U 0.8 U Calcium T -- ug/I 491000 39900 74000 31600 77100 77400 71500 191000 Carbon N -- ug/I 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 6100 1000 U Chloride N 250000 02L ug/I 27600 36600 94700 3700 46300 47100 70000 32200 Chromium D -- ug/I 5 U 0.14 J 5 U 0.25 J+ 5 U 5 U 5 U 5 U Chromium T 10 02L ug/I 4J+ 0.28 J+ 1 J 0.7 5 U 5 U 5 U 5 UJ Chromium 6+ T 0.07 DHHS ug/I 0.03 U 0.03 UJ 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U Cobalt D -- ug/I 2.3 0.019 J 1 U 0.035 J+ 0.23 J 0.24 J 0.13 J 2.6 Cobalt T 1 IMAC ug/I 2.1 0.09 J 1 U 0.12 0.23 J 0.27 J 0.18 J 3 Copper D -- ug/I 5 U 0.5 U 5 U 0.53 J+ 5 U 5 U 5 U 5 U Copper T 1000 02L ug/I 5 U 0.42 J 5 U 0.34 J 5 U 5 U 5 U 5 U Iron D -- ug/I 7330 105 50 U 50 U 793 J 978 J 249 20100 Iron T 300 02L ug/I 6430 157 50 U 60.4 1100 1050 482 23200 Lead D -- ug/I 1U 0.1U 1U 0.1U 1U 1U 1U 1U Lead T 15 02L ug/I 1 U 0.14 1 U 0.25 1 U 1 U 1 U 1 U Magnesium T -- ug/I 88200 1330 5360 8590 14500 14500 4290 43300 Manganese D -- ug/I 2780 43 5 U 4.4 J 142 144 87.4 12600 Manganese T 50 02L ug/I 2350 94 5 U 5.6 131 135 86.1 14300 Mercury D -- ug/I 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U Mercury T 1 02L ug/I 0.2 UJ 0.2 UJ 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U Methane N -- ug/I 322 3110 128 5960 224 201 3560 41.6 Molybdenum D -- ug/I 28.3 154 105 81.4 731 828 207 12.4 Molybdenum T -- ug/I 25.1 161 93.5 79.7 770 745 172 13.3 Nickel D -- ug/I 6.5 0.57 5 U 0.61 J+ 5 U 5 U 5 U 6.7 Nickel T 100 02L ug/I 6.2 0.74 5 U 1.5 5 U 5 U 5 U 6.8 Nitrogen, NO2 plus NO3 N -- ug/I 20 U 20 U 20 U 20 U 20 U 20 U 18J 20 U Potassium T -- ug/I 17200 11200 6960 8390 8530 8690 4950 J 26400 Selenium D -- ug/I 5 U 1.9 5 U 0.57 5 U 5 U 12.4 5 U Selenium T 20 02L ug/I 5 U 2.7 5 U 0.63 5 U 5 U 10 5 U Sodium T -- ug/I 24800 12000 12600 2910 J 10700 10900 9540 18300 Strontium D -- ug/I 5710 1020 1210 1280 2310 2350 1180 3040 Strontium T -- ug/I 5120 988 1170 1280 2220 2230 1130 3170 Sulfate N 250000 02L ug/I 1060000 76000 84400 25100 111000 111000 95100 422000 J - Sulfide N -- ug/I 100 UJ 100 UJ 100 U 100 U 100 U 100 U 100 U 100 U Thallium D -- ug/I 0.91 J 0.065 J 1 U 0.049 J 1 U 1 U 1 U 0.48 J Thallium T 0.2 IMAC ug/I 0.77 J 0.093 J 1 U 0.071 J 1 U 1 U 1 U 0.59 J Cliffside Steam Station Page 1 of 4 CSA Supplement 2 Table 3-2: Round 5 Analytical Results of Porewater Monitoring Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 2 of 4 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: AB -3S 4/13/2016 N CS -AB -3S AB-3SL 4/13/2016 N CS-AB-3SL AB -4S 4/13/2016 N CS -AB -4S AB-4SL 4/13/2016 N CS-AB-4SL AB -5S 4/13/2016 FD CS -FD -AB -SS AB -5S 4/13/2016 N CS -AB -SS AB -6S 4/13/2016 N CS -AB -6S AS -7S 4/14/2016 N CS -AS -7S Constituent Fraction NCDEQ 02L GWQS,IMAC, or DHHS GWQS Source Unit Total Dissolved Solids N 500000 02L ug/I 160000 193000 361000 131000 333000 333000 305000 250000 U Total Organic Carbon N -- ug/I -- -- -- -- -- -- -- -- Total Suspended Solids N ug/I 20200 2500 2500 U 3100 4400 J 7000 J 3500 15900 Uranium, Natural T ug/I -- -- -- -- -- -- -- -- Vanadium D -- ug/I 2.5 J 48.6 26.6 97.9 1.5J 1.9 J 28 1.7J Vanadium T 0.3 IMAC ug/I 3.3 61.4 23 93.3 1.9 J 1.7 J 27.3 2.8 J Zinc D -- ug/I 33.1 lou lou 3.8 J lou lou lou 9.4 J+ Zinc T 1000 02L ug/I 27.9 lou lou 2.8 J lou lou 5.8 J 13.2 Dissolved Oxygen N -- mg/I 0.2 0.1 0.1 0.1 0.2 0.2 0.3 0.1 Oxidation Reduction Potential N -- mV -141.4 -111.1 31 -101 -210.9 -210.9 167.7 -63.2 pH N 6.5-8.5 02L SU 7.3 9.5 9.4 9.06 8 8 7.9 6.6 Specific Conductivity N -- NS/cm 2481 338.1 543 273 573 573 471.7 1321 Temperature N -- Deg C 22.1 22 15 17 21 21 17.1 19.6 Turbidity, field N -- NTU 7.6 3.4 0.8 8.85 7.8 7.8 4 9.6 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 2 of 4 CSA Supplement 2 Table 3-2: Round 5 Analytical Results of Porewater Monitoring Cliffside Steam Station Page 3 of 4 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: IB -1S 4/15/2016 N CS -IB -1S U5 -2S -SL -A 4/20/2016 N CS-U5-2S/SLA U5 -7S 4/13/2016 N CS -U5 -7S U5-7SL 4/13/2016 N CS-U5-7SL Constituent Fraction NCDEQ 02L GWQS,IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 1 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 34300 208000 95800 24300 Alkalinity, lab N ug/I 34300 208000 95800 J+ 24300 Aluminum D - ug/I 100 U 65.8 J 100 U 100 U Aluminum T - ug/I 67.1 J 3120 J+ 100 U 100 U Antimony D - ug/I 5 U 0.49 J 0.5 U 5 U Antimony T 1 IMAC ug/I 5 U 2.1 J 0.5 U 5 U Arsenic D -- ug/I 0.75 J 1870 1060 110 Arsenic T 10 02L ug/I 0.88 J 2030 1110 104 Barium D -- ug/I 44 268 126 26.8 Barium T 700 02L ug/I 46.2 369 125 26.6 Beryllium D -- ug/I 1 U 0.082 J+ 0.15 0.26 J Beryllium T 4 IMAC ug/I 0.12 J 2 0.09 J 0.29 J Boron D -- ug/I 156 417 174 175 Boron T 700 02L ug/I 165 443 172 180 Cadmium D -- ug/I 0.8 U 0.067 J 0.08 U 0.8 U Cadmium T 2 02L ug/I 0.8 U 0.8 U 0.08 U 0.8 U Calcium T -- ug/I 170000 67300 35800 63300 Carbon N -- ug/I 1000 U -- 1000 U 860 J Chloride N 250000 02L ug/I 21900 8500 4600 4900 Chromium D -- ug/I 5 U 2.9 0.9 J+ 5 UJ Chromium T 10 02L ug/I 5 UJ 36.6 0.41 J 5 U Chromium 6+ T 0.07 DHHS ug/I 0.03 U 0.03 U 0.03 UJ 0.03 U Cobalt D -- ug/I 7.9 16.8 0.063 J+ 0.19 J+ Cobalt T 1 IMAC ug/I 7.9 21.6 0.081 J 0.22 J Copper D -- ug/I 5 U 1.4 J 0.51 J+ 5 UJ Copper T 1000 02L ug/I 5 U 21.9 0.49 J 5 U Iron D -- ug/I 7360 50800 24300 64800 Iron T 300 02L ug/I 7490 54900 24100 64200 Lead D -- ug/I 1 U 0.4 0.1 U 1 U Lead T 15 02L ug/I 1 U 15.5 0.1 U 1 U Magnesium T -- ug/I 31600 38400 8480 17800 Manganese D -- ug/I 2400 905 726 2560 Manganese T 50 02L ug/I 2420 960 715 2590 Mercury D -- ug/I 0.2 U 0.2 U 0.2 U 0.2 U Mercury T 1 02L ug/I 0.2 U 0.2 U 0.2 U 0.2 U Methane N -- ug/I 48.9 279 10 U 28 Molybdenum D -- ug/I 5 U 222 11.4 1.5 J Molybdenum T -- ug/I 5 U 216 11.4 1.3 J Nickel D -- ug/I 5 U 11.7 0.89 J+ 5 UJ Nickel T 100 02L ug/I 5 U 29.4 0.45 J 5 U Nitrogen, NO2 plus NO3 N -- ug/I 20 U 20 U 20 U 20 U Potassium T -- ug/I 10600 13000 7180 12800 Selenium D -- ug/I 5 U 5 U 0.5 U 5 U Selenium T 20 02L ug/I 5 U 5.6 0.5 U 5 U Sodium T -- ug/I 26000 4100 J 3400 J 6560 Strontium D -- ug/I 905 2570 935 1030 Strontium T -- ug/I 946 2690 920 1020 Sulfate N 250000 02L ug/I 433000 128000 28900 267000 Sulfide N -- ug/I 100 U 100 U 100 U 100 U Thallium D -- ug/I 1 1.2 0.1 U 1 U Thallium T 0.2 IMAC ug/I 0.82 J 2.4 0.02 J 0.24 J Cliffside Steam Station Page 3 of 4 CSA Supplement 2 Table 3-2: Round 5 Analytical Results of Porewater Monitoring Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 4 of 4 CSA Supplement 2 Location: Date: Sample Type: Sample Name: Event: IB -1S 4/15/2016 N CS -IB -1S U5 -2S -SL -A 4/20/2016 N CS-U5-2S/SLA U5 -7S 4/13/2016 N CS -U5 -7S U5-7SL 4/13/2016 N CS-U5-7SL Constituent Fraction NCDEQ 02L GWQS,IMAC, or DHHS GWQS Source Unit Total Dissolved Solids N 500000 02L ug/I 864000 465000 200000 479000 Total Organic Carbon N -- ug/I -- 1000 U -- -- Total Suspended Solids N ug/I 2600 511000 20000 28500 Uranium, Natural T ug/I -- 13.1 -- -- Vanadium D -- ug/I 3 U 1.7 0.16 J 3 U Vanadium T 0.3 IMAC ug/I 3 U 34.8 0.31 3 U Zinc D -- ug/I 19 J 7.6 J+ 2.9 J 4 J Zinc T 1000 02L ug/I 11.2 14.8 4 J 2.9 J Dissolved Oxygen N -- mg/I -- 0.3 0.29 0.71 Oxidation Reduction Potential N -- mV -- -38 -66 -45 pH N 6.5-8.5 02L SU -- 6.3 6.69 6.36 Specific Conductivity N -- NS/cm -- 805 359 729 Temperature N -- Deg C -- 19 17.5 20 Turbidity, field N -- NTU -- 241 5.72 5.69 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 4 of 4 CSA Supplement 2 Table 3-3: Round 5 Analytical Results of Surface Water Locations Cliffside Steam Station Page 1 of 4 CSA Supplement 2 Location: Date: Sample Type: Sample Name: SW -1 4/18/2016 N CS -SW -1 SW -2 4/18/2016 N CS -SW -2 SW -3 4/18/2016 N CS -SW -3 SW -4 4/18/2016 N CS -SW -4 SW -4 4/18/2016 FD CS -FD -SW -4 SW -5 4/19/2016 N CS -SW -5 SW -5 4/19/2016 FD CS -SW -5 -FD -MRM -1 SW -7 4/19/2016 N CS -SW -7 SW -8 4/19/2016 N CS -SW -8 SW -9 4/19/2016 N CS -SW -9 Constituent Fraction NCDEQ 02B SWQS (Class B - Water Supply) Unit Alkalinity, CO3 N ug/1 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 16800 8700 9100 8500 8600 5000 U 5000 U 12100 52000 13000 Alkalinity, lab N ug/I 16800 8700 9100 8500 8600 5000 U 5000 U 12100 52000 13000 Aluminum D -- ug/I 100 U 100 U 100 U 100 U 100 U 58.3 J 59.9 J 100 U 100 U 100 U Aluminum T 87 ug/I 100 U 84.2 J 85.6 J 108 114 324 294 53.3 J 147 98.4 J Antimony D -- ug/I 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.46 J 0.5 U 0.5 U Antimony T 5.6 ug/I 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.4 J 0.5 U 0.5 U Arsenic D 150 ug/I 0.44 0.18 0.14 0.15 0.16 0.21 0.19 5 0.6 0.091 J Arsenic T 10 ug/I 0.52 0.19 0.2 0.17 J 0.23 J 0.4 0.47 5.6 0.67 0.089 J Barium D -- ug/I 21.1 22.3 20.6 20.4 20.4 28.4 28.5 31.2 11.7 11.2 Barium T 1000 ug/I 22.4 25.2 22.6 21.9 22.4 29.7 29.5 34.5 18.1 11.9 Beryllium D 6.5 ug/I 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.23 J 0.13 J 0.016 J+ 0.1 UJ 0.1 UJ Beryllium T -- ug/I 0.015 J 0.05 J 0.1 U 0.015 J 0.1 U 0.26 J 0.18 J 0.1 UJ 0.013 J+ 0.1 U Boron D ug/I 50 U 50 U 50 U 50 U 50 U 46.9 J 44.5 J 326 28.5 J 50 U Boron T -- ug/I 50 U 50 U 50 U 50 U 50 U 55.7 55.9 360 37.9 J 32.9 J+ Cadmium D 0.15 ug/I 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.3 0.32 0.088 0.08 U 0.08 U Cadmium T -- ug/I 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.27 0.3 0.14 0.08 U 0.08 U Calcium T ug/I 11800 2430 3450 3130 3190 15500 15400 43300 37500 2830 Carbon N -- ug/I 2200 940 J 880 J 830 J 890 J 1000 U 1000 U 520 J 4700 510 J Chloride N 230000 ug/I 5800 3500 3700 3600 3600 21400 21200 66200 7800 1700 Chromium D 11 ug/I 0.23 J+ 0.34 J+ 0.35 J+ 0.25 J 0.31 J 0.25 J 0.26 J 0.29 J 0.3 J 0.73 Chromium T -- ug/I 0.28 J+ 0.45 J+ 0.35 J+ 0.49 J+ 0.43 J+ 0.88 J 0.71 J 0.41 J+ 0.52 0.35 J+ Chromium 6+ T ug/I 0.03 UJ 0.03 U 0.019 J 0.028 J 0.018 J 0.03 U 0.03 U 0.14 0.072 0.042 Cobalt D -- ug/I 0.1 0.28 0.43 0.22 0.21 5.4 5.4 2 0.36 0.069 J Cobalt T 3 ug/I 0.14 0.31 0.54 0.26 0.28 5 5 2.1 0.45 0.11 Copper D 2.7 ug/I 0.75 1.2 0.5 0.48 J 0.34 J 10.1 10.2 1.7 0.93 1.6 Copper T -- ug/I 0.4 J 0.48 J 0.32 J 0.28 J 0.32 J 10 9.9 1.5 J 0.51 J 0.35 J Iron D ug/I 115 406 146 153 183 1630 1610 53.2 185 66.9 Iron T -- ug/I 442 818 721 734 746 2110 2020 199 472 225 Lead D 0.54 ug/I 0.1U 0.11 0.1U 0.1U 0.1U 0.1U 0.1U 0.1U 0.1U 0.1U Lead T -- ug/I 0.1 U 0.18 0.13 0.13 0.14 0.19 0.19 0.1 U 0.13 0.14 Magnesium T ug/I 3040 1250 1460 1430 1440 1700 1720 3330 9800 1090 Manganese D ug/I 6.5 33.6 44.6 33.5 33.2 167 166 127 54.6 10.6 Manganese T -- ug/I 9.2 37.5 50.7 36.9 37.6 172 173 150 70 17.8 Mercury T 0.012 ug/I 0.000496 J 0.000902 0.00106 0.00105 0.00111 0.000742 0.000746 0.000634 0.000916 0.000656 Methane N -- ug/I 10U 10U 10U 10U 10U 10U 10U 10U 18.7 10U Molybdenum D -- ug/I 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.35 J 0.34 J 22.4 0.29 J 0.5 U Molybdenum T 160 ug/I 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.24 J 0.26 J 19.4 0.25 J 0.5 U Nickel D 16 ug/I 1.6 0.86 0.45 J 0.5 U 0.5 U 7.2 7.4 4.2 3 1.4 Nickel T 25 ug/I 1.7 0.47 J 0.5 U 0.5 U 0.44 J 6.6 6.7 3.1 1.5 0.5 U Nitrogen, NO2 plus NO3 N -- ug/I 20 J 500 450 450 450 140 J 190 J 310 110 120 Potassium T ug/I 3200 J 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 3390 J 4490 J 5000 U Selenium D -- ug/I 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1.1 1.3 2.2 0.39 J 0.5 U Selenium T 5 ug/I 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1.4 1.3 1.9 0.5 U 0.5 U Sodium T -- ug/I 2600 J 2690 J 2720 J 2660 J 2660 J 6110 6080 8740 4610 J 2960 J Strontium D -- ug/I 30.3 16.2 20.2 18.7 18.7 93.1 93.2 285 91 18.8 Strontium T 14000 ug/I 31.4 18 21.7 19.4 19.9 95.7 96 306 96 18.8 Sulfate N 250000 ug/I 18300 1200 3200 2700 2600 36000 36000 39400 81800 1700 Sulfide N -- ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U Thallium D -- ug/I 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 2 2.1 0.58 0.1 U 0.1 U Thallium T 0.24 ug/I 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 1.9 1.9 0.53 0.021 J 0.1 U Total Dissolved Solids N 500000 ug/I 62000 42000 32000 30000 32000 121000 115000 287000 211000 40000 J Total Suspended Solids N -- ug/I 2500 U 4200 2800 6500 U 2500 U 5000 UJ 4200 J 2700 7700 3400 Vanadium D ug/I 0.3 U 0.17 J 0.075 J 0.17 J 0.16 J 0.3 U 0.3 U 1 0.31 0.36 Vanadium T -- ug/I 0.11 J 0.35 0.3 J 0.36 0.37 0.4 0.42 1.2 0.65 0.64 Zinc D 36 ug/I 10U 10U 4.6J 10U 10U 19.2 20.3 2.5J 10U 10U Zinc T -- ug/I 10U 10U 10U 10U 10U 19.3 19.7 119 10U 10U Dissolved Oxygen N mg/I 7.2 7.9 8.09 8.7 8.7 5.36 5.36 7.69 9.63 8 Cliffside Steam Station Page 1 of 4 CSA Supplement 2 Table 3-3: Round 5 Analytical Results of Surface Water Locations Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 2 of 4 CSA Supplement 2 Location: SW -1 SW -2 SW -3 SW -4 SW -4 SW -5 SW -5 SW -7 SW -8 SW -9 Date: 4/18/2016 4/18/2016 4/18/2016 4/18/2016 4/18/2016 4/19/2016 4/19/2016 4/19/2016 4/19/2016 4/19/2016 Sample Type: N N N N FD N FD N N N Sample Name: CS -SW -1 CS -SW -2 CS -SW -3 CS -SW -4 CS -FD -SW -4 CS -SW -5 CS -SW -5 -FD -MRM -1 CS -SW -7 CS -SW -8 CS -SW -9 NCDEQ 02B SWQS Constituent Fraction (Class B - Water Unit Supply) Oxidation Reduction Potential N my 127.3 142 120.6 244.3 244.3 65.5 65.5 110.9 117.5 71.5 pH N 6.0-9.0 SU 6.56 6.9 6.9 7.8 7.8 6.5 6.5 7.4 8 7.3 Specific Conductivity N PS/cm 125.3 384 79.5 57.3 57.3 196.8 196.8 368.7 320.9 54.8 Temperature N Deg C 22.1 12.8 17.7 18.3 18.3 28.4 28.4 25.3 27.3 20.7 Turbidity, field N I I NTU 9.7 3.9 3.15 6.3 6.3 3.17 3.17 1.82 1.5 5.2 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 2 of 4 CSA Supplement 2 Table 3-3: Round 5 Analytical Results of Surface Water Locations Cliffside Steam Station Page 3 of 4 CSA Supplement 2 Location: Date: Sample Type: Sample Name: SW -10A 4/28/2016 N CS -SW -10A SW -10B 4/28/2016 N CS -SW -10B SW -10C 4/28/2016 FD -SW -10C -FD DUPLIC SW -10C 4/28/2016 N CS -SW -10C Constituent Fraction NCDEQ 02B SWQS (Class B - Water Supply) Unit Alkalinity, CO3 N ug/I 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 14400 14400 13700 15400 Alkalinity, lab N ug/I 14400 14400 13700 15400 Aluminum D -- ug/I 100 U 100 U 100 U 100 U Aluminum T 87 ug/I 222 270 225 233 Antimony D -- ug/I 0.1 J 0.5 U 0.14 J 0.14 J Antimony T 5.6 ug/I 0.5 U 0.5 U 0.5 U 0.5 U Arsenic D 150 ug/I 0.27 0.094 J 0.26 J 0.11 J Arsenic T 10 ug/I 0.34 0.11 0.32 J 0.12 J Barium D -- ug/I 13.4 11.6 13.5 12.7 Barium T 1000 ug/I 16.7 14.9 16.6 15.9 Beryllium D 6.5 ug/I 0.1 U 0.1 U 0.1 U 0.1 U Beryllium T -- ug/I 0.032 J+ 0.032 J+ 0.1 UJ 0.041 J+ Boron D ug/I 50 U 50 U 50 U 50 U Boron T -- ug/I 50 U 50 U 50 U 50 U Cadmium D 0.15 ug/I 0.08 U 0.08 U 0.08 U 0.08 U Cadmium T -- ug/I 0.08 U 0.08 U 0.08 U 0.08 U Calcium T ug/I 5050 3230 5050 J 3610 J Carbon N -- ug/I 1000 870 J 860 J 1000 Chloride N 230000 ug/I 4500 2000 4600 J 2500 J Chromium D 11 ug/I 0.59 J+ 0.66 J+ 0.74 J+ 0.43 J+ Chromium T -- ug/I 0.61 J+ 0.58 J+ 0.52 J+ 0.66 J+ Chromium 6+ T ug/I 0.043 0.041 0.046 J- 0.029 J Cobalt D -- ug/I 0.29 0.09 J 0.26 J 0.087 J Cobalt T 3 ug/I 0.43 0.2 0.44 J 0.2 J Copper D 2.7 ug/I 1.5 3.8 2.3 J 3.4 J Copper T -- ug/I 0.5 0.49 J 0.63 0.65 Iron D ug/I 53.8 43.3 J 42 J 44.7 J Iron T -- ug/I 446 475 433 529 Lead D 0.54 ug/I 0.092 J 0.35 0.1 U 0.1 U Lead T -- ug/I 0.19 0.21 0.18 J 0.24 J Magnesium T ug/I 1320 1240 1320 1470 Manganese D ug/I 30.2 13.1 29.8 J 17.8 J Manganese T -- ug/I 49.7 31.1 47.7 J 32.9 J Mercury T 0.012 ug/I 0.00117 0.0005 U 0.00167 0.000297 J Methane N -- ug/I 10 U 10 U 10 U 10 U Molybdenum D -- ug/I 0.8 0.5 U 0.79 0.5 U Molybdenum T 160 ug/I 0.75 0.5 U 0.78 0.5 U Nickel D 16 ug/I 1.3 1.5 1.2 0.99 Nickel T 25 ug/I 0.47 J 0.5 U 0.47 J 0.5 U Nitrogen, NO2 plus NO3 N -- ug/I 170 170 170 J 270 J Potassium T ug/I 5000 U 5000 U 5000 U 5000 U Selenium D -- ug/I 0.5 U 0.5 U 0.5 U 0.5 U Selenium T 5 ug/I 0.5 U 0.5 U 0.5 U 0.5 U Sodium T -- ug/I 3560 J 3450 J 3550 J 3920 J Strontium D -- ug/I 32.3 20.1 32.8 J 21.8 J Strontium T 14000 ug/I 36.7 22.9 36.6 J 24.1 J Sulfate N 250000 ug/I 3500 1900 3500 J 2000 J Sulfide N -- ug/I 100 U 100 U 100 U 100 U Thallium D -- ug/I 0.1 U 0.1 U 0.1 U 0.1 U Thallium T 0.24 ug/I 0.028 J 0.1 U 0.034 J 0.1 U Total Dissolved Solids N 500000 ug/I 31000 26000 33000 36000 Total Suspended Solids N -- ug/I 5000 U 10500 4500 J 8000 J Vanadium D ug/I 0.44 0.49 0.45 0.52 Vanadium T -- ug/I 1 1 0.94 1.1 Zinc D 36 ug/I 3.5 J 4.3 J 4.7 J 3.8 J Zinc T -- ug/I 2.5 J+ 10 UJ 10 UJ 3.4 J+ Dissolved Oxygen N mg/I -- Cliffside Steam Station Page 3 of 4 CSA Supplement 2 Table 3-3: Round 5 Analytical Results of Surface Water Locations Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 4 of 4 CSA Supplement 2 Location: SW -10A SW -10B SW -10C SW -10C Date: 4/28/2016 4/28/2016 4/28/2016 4/28/2016 Sample Type: N N FD N Sample Name: CS -SW -10A CS -SW -10B -SW -10C -FD DUPLIC CS -SW -10C NCDEQ 02B SWQS Constituent Fraction (Class B - Water Unit Supply) Oxidation Reduction Potential N my pH N 6.0-9.0 SU Specific Conductivity N PS/cm Temperature N Deg C Turbidity, field N I I NTU Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 4 of 4 CSA Supplement 2 Table 3-4: Round 5 Analytical Results of Areas of Wetness Cliffside Steam Station Page 1 of 2 CSA Supplement 2 Location: Date: Sample Type: Sample Name: S-1 4/19/2016 N CS -S-1 S-4 4/18/2016 N CS -S-4 S-5 4/19/2016 N CS -S-5 S-6 4/19/2016 N CS -S-6 S-7 4/19/2016 N CS -S-7 S-8 4/18/2016 N CS -S-8 S-18 4/18/2016 N CS -S-18 S-19 4/18/2016 N CS -S-19 S -19A 4/18/2016 N CS -S -19A S-22 4/19/2016 N CS -S-22 Constituent Fraction NCDEQ 02L GWQS, IMAC, or DHHS GWQS Source Unit Alkalinity, CO3 N ug/I 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N ug/I 8300 96300 4800 J 42800 4400 J 10700 63300 152000 179000 55000 Alkalinity, lab N ug/I 8300 96300 4800 J 42800 4400 J 10700 63300 152000 179000 55000 Aluminum D ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U Aluminum T ug/I 110 100 U 100 U 213 77.1 J 69.4 J 63.9 J 100 U 100 U 100 U Antimony D -- ug/I 0.5 U 5 U 0.5 U 0.5 U 0.5 U 0.5 U 5 U 0.5 U 5 U 5 U Antimony T 1 IMAC ug/I 0.5 U 5 U 0.5 U 0.5 U 0.5 U 0.5 U 5 U 0.5 U 0.5 U 5 U Arsenic D -- ug/I 0.049 J 34.2 0.079 J 0.22 0.041 J 0.061 J 1 U 0.1 1 U 1 U Arsenic T 10 02L ug/I 0.0911 37.4 0.1 0.3 0.047 J 0.044 J 0.48 J 0.11 0.18 1 U Barium D -- ug/I 14.8 101 68.8 43.6 15.9 19.5 18.6 46.7 37.3 58.7 Barium T 700 02L ug/I 16.4 105 71.8 47.2 18.8 20.5 19.4 50.2 38.7 59.8 Beryllium D -- ug/I 0.031 J+ 1 U 0.19 0.1 UJ 0.1 UJ 0.1 U 1 U 0.1 U 1 U 1 UJ Beryllium T 4 IMAC ug/I 0.031 J 1 U 0.14 0.016 J+ 0.045 J+ 0.015 J 0.68 J 0.022 J 0.1 U 1 UJ Boron D -- ug/I 50 U 548 100 736 50 U 50 U 715 59.2 101 827 Boron T 700 02L ug/I 42.6 J+ 596 112 774 30.5 J 50 U 734 61.7 105 859 Cadmium D -- ug/I 0.08 U 0.8 U 0.05 J 0.08 U 0.08 U 0.08 U 0.8 U 0.08 U 0.8 U 0.8 U Cadmium T 2 02L ug/I 0.08 U 0.8 U 0.057 J 0.08 U 0.08 U 0.08 U 0.8 U 0.08 U 0.08 U 0.8 U Calcium T -- ug/I 3030 67500 5940 47300 1710 2950 96800 47600 75900 52800 Carbon N -- ug/I 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U Chloride N 250000 02L ug/I 4900 33600 9600 59500 4600 2800 4100 5100 4900 65200 Chromium D -- ug/I 0.34 J 5 UJ 0.23 J 0.32 J 1 0.22 J+ 5 U 0.111 5 UJ 5 U Chromium T 10 02L ug/I 0.39 J+ 5 UJ 0.24 J+ 0.83 J 0.36 J+ 0.26 J+ 5 UJ 0.19 J+ 0.33 J+ 5 UJ Chromium 6+ T 0.07 DHHS ug/I 0.015 J 0.03 U 0.04 0.016 J 0.072 0.017 J 0.03 U 0.014 J 0.03 U 0.03 U Cobalt D -- ug/I 0.12 2 0.14 15.2 0.055 J 0.067 J 15.9 0.054 J 2.6 65.3 Cobalt T 1 IMAC ug/I 0.16 1.8 0.15 14.4 0.078 J 0.082 J 19 0.082 J 2.9 61.5 Copper D -- ug/I 1.5 5 U 0.6 0.98 0.47 J 0.52 5 U 0.9 5 U 5 U Copper T 1000 02L ug/I 0.87 5 U 0.14 J+ 0.43 J+ 0.5 UJ 0.59 5 U 0.5 U 0.6 5 UJ Iron D -- ug/I 61 2370 28.6 J 267 50 U 25.8 J 422 50 U 161 271 Iron T 300 02L ug/I 247 2580 37.3 J 610 77.4 76.5 1360 50 U 409 391 Lead D -- ug/I 0.1 U 1 U 0.1 U 0.1 U 0.1 U 0.1 U 1 U 0.1 U 1 U 1 U Lead T 15 02L ug/I 0.22 1 U 0.1 U 0.36 0.092 J 0.1 U 1 U 0.1 U 0.22 1 U Magnesium T -- ug/I 1570 18100 4410 8530 1160 1060 35100 18200 28800 9250 Manganese D -- ug/I 8.3 3150 37.1 1520 5 U 5 U 2210 29.3 1140 4000 Manganese T 50 02L ug/I 9.7 3240 J- 39.3 1590 4.1 J 2.5 J 2290 36.9 1160 4110 Mercury T 1 02L ug/I 0.000886 0.00264 0.0282 0.00352 0.0011 0.000738 0.000341 J 0.000404 J 0.000845 0.000687 Methane N -- ug/I 10 U 405 10 U 19.8 10 UJ 10 U 10 U 10 U 10 U 61.4 Molybdenum D ug/I 0.5 U 2.4 J 0.5 U 0.63 0.5 U 0.5 U 5 U 0.5 U 5 U 5 U Molybdenum T ug/I 0.5 U 2.4 J 0.5 U 0.46 J 0.5 U 0.5 U 5 U 0.5 U 0.5 U 5 U Nickel D -- ug/I 1.6 5 U 2.7 2 1.5 0.5 U 14 0.66 5 U 4.4 J Nickel T 100 02L ug/I 0.5 U 5 U 2.6 1.9 0.5 U 0.5 U 16.8 0.79 2.9 5 U Nitrogen, NO2 plus NO3 N -- ug/I 530 20 U 490 150 310 520 32 23 20U 20 U Potassium T ug/I 5000 U 9060 3100 J 3030 J 5000 U 5000 U 5660 2990 J 2860 J 2990 J Selenium D -- ug/I 0.5 U 5 U 1.7 0.5 U 0.5 U 0.5 U 5 U 0.5 U 5 U 5 U Selenium T 20 02L ug/I 0.5 U 5 U 1.8 0.31 J 0.5 U 0.5 U 5 U 0.5 U 0.5 U 5 U Sodium T -- ug/I 2710 J 12600 5260 10600 1870 J 2950 J 6280 3430 J 4060 J 10700 Strontium D ug/I 17.3 652 40.2 239 14.9 17.5 263 81.7 270 312 Strontium T -- ug/I 18.2 701 42 253 16.6 18.4 269 86.9 273 319 Sulfate N 250000 02L ug/I 2600 115000 26700 59900 1100 1000 307000 34400 105000 64600 Sulfide N -- ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U Thallium D -- ug/I 0.1 U 1 U 0.073 J 0.071 J 0.1 U 0.1 U 1 U 0.1 U 1 U 1 U Thallium T 0.2 IMAC ug/I 0.1 U 1 U 0.1 0.07 J 0.1 U 0.1 U 0.17 J 0.015 J 0.036 J 1 U Total Dissolved Solids N 500000 02L ug/I 36000 J 335000 106000 311000 39000 25000 U 528000 207000 344000 346000 Total Suspended Solids N -- ug/I 2500 U 2500 U 2500 U 10800 3000 16600 2500 U 2500 U 2500 U 2600 Vanadium D -- ug/I 0.11 3 U 0.3 U 0.21 J 0.111 0.12 J 3 U 0.15 J 3 U 3 U Vanadium T 0.3 IMAC ug/I 0.36 3 U 0.3 U 1.3 0.16 J 0.16 J 3 U 0.14 J 0.3 U 3 U Zinc D -- ug/I 9.2J 10U 5.5J 3.7J 10U 10U 5.7J 10U 10U 10U Zinc T 1000 02L ug/I 10.2 10 U 3.9 J 2.6 J 2.7 J 10 U 4.4 J 10 U 15.2 10 U Dissolved Oxygen N -- mg/I 8.2 1.45 6.93 4.9 7.31 6.5 4.75 3.6 6.7 4.8 Oxidation Reduction Potential N mV 50.2 -18.6 137 158.2 52.4 128 53.7 206.5 69.3 88.4 PH N 6.5-8.5 02L SU 7.2 6.5 6.8 6.5 7 6.8 6.54 6.4 6.5 6.6 Specific Conductivity N NS/cm 67.9 586 133.3 780 47.3 119.1 755 387.1 457.6 485.1 Temperature N Deg C 19.6 22.3 19.5 21.8 19.5 16.9 25.5 23.9 20.5 18.9 Turbidity, field N NTU 4.3 0.04 0.07 3.85 0.61 1.21 0.87 3.7 7 3.98 Cliffside Steam Station Page 1 of 2 CSA Supplement 2 Table 3-4: Round 5 Analytical Results of Areas of Wetness Location: S-1 S-4 S-5 S-6 S-7 S-8 S-18 S-19 S -19A S-22 Date: 4/19/2016 4/18/2016 4/19/2016 4/19/2016 4/19/2016 4/18/2016 4/18/2016 4/18/2016 4/18/2016 4/19/2016 Sample Type: N N N N N N N N N N Sample Name: CS -S-1 CS -S-4 CS -S-5 CS -S-6 CS -S-7 CS -S-8 CS -S-18 CS -S-19 CS -S -19A CS -S-22 Constituent Fraction NCDEQ 02L GWQS, GWQS Source Unit IMAC, or DHHS Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T1 5A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Cliffside Steam Station Page 2 of 2 CSA Supplement 2 Table 3-5: Summary of Groundwater Elevations Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation AB -1D 6/24/2015 773.44 63.00 710.44 8/27/2015 62.59 710.85 4/18/2016 62.85 710.59 6/16/2016 63.61 709.83 AB -1S 6/24/2015 773.19 38.51 734.68 8/27/2015 39.62 733.57 4/18/2016 40.55 732.64 6/16/2016 40.72 732.47 AB -2D 6/24/2015 773.00 41.01 731.99 8/27/2015 40.00 733.00 4/14/2016 40.00 733.00 6/16/2016 30.24 742.76 AB -2S 6/24/2015 772.92 29.80 743.12 8/27/2015 29.44 743.48 4/14/2016 29.60 743.32 6/16/2016 29.59 743.33 AB -313R 796.55 3/3/2016 33.67 762.88 6/16/2016 -- -- AB-313RU 6/24/2015 795.78 33.45 762.33 8/27/2015 33.22 762.56 4/13/2016 33.36 762.42 6/16/2016 33.34 762.37 AB -31 6/24/2015 795.97 33.60 762.37 8/27/2015 33.37 762.60 4/13/2016 33.53 762.44 6/16/2016 33.49 762.38 AB -3S 6/24/2015 795.64 33.45 762.19 8/27/2015 33.12 762.52 4/13/2016 33.12 762.52 6/16/2016 33.43 762.10 AB-3SL 6/24/2015 796.02 33.70 762.32 8/27/2015 33.46 762.56 4/13/2016 33.60 762.42 6/16/2016 33.61 762.28 AB-4BR 6/24/2015 770.66 12.31 758.35 8/27/2015 12.80 757.86 4/13/2016 13.10 757.56 6/16/2016 13.59 757.07 AB -4D 6/24/2015 770.59 8.05 762.54 8/27/2015 8.37 762.22 4/13/2016 8.30 762.29 6/16/2016 8.82 761.77 AB -4S 6/24/2015 770.59 8.40 762.19 8/27/2015 8.90 761.69 4/13/2016 8.75 761.84 6/16/2016 9.37 761.22 Cliffside Steam Station Page 1 of 16 CSA Supplement 2 Table 3-5: Summary of Groundwater Elevations Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation AB-4SL 6/24/2015 770.61 8.20 762.41 8/27/2015 8.59 762.02 4/13/2016 8.55 762.06 6/16/2016 9.11 761.50 AB-5BR 772.13 3/7/2016 9.15 762.98 6/16/2016 9.29 787.26 AB-56RU 6/24/2015 771.81 7.70 764.11 8/27/2015 7.84 763.97 4/13/2016 7.30 764.51 6/16/2016 7.21 764.69 AB -5S 6/24/2015 771.74 7.95 763.79 8/27/2015 8.04 763.70 4/13/2016 8.00 763.74 6/16/2016 7.78 763.92 AB-6BR 6/24/2015 770.61 12.09 758.52 8/27/2015 12.55 758.06 4/13/2016 11.40 759.21 6/16/2016 11.60 759.16 AB -6D 6/24/2015 770.68 6.53 764.15 8/27/2015 6.85 763.83 4/13/2016 5.90 764.78 6/16/2016 5.84 764.90 AB -6S 6/24/2015 770.56 6.36 764.20 8/27/2015 6.82 763.74 4/13/2016 6.35 764.21 6/16/2016 6.01 764.62 AS -11) 6/25/2015 809.41 80.30 729.11 8/27/2015 80.15 729.26 4/14/2016 78.54 730.87 6/16/2016 79.29 730.12 AS-1SB 6/24/2015 809.20 79.00 730.20 8/27/2015 79.12 730.08 4/14/2016 77.20 732.00 6/16/2016 -- -- AS -21) 6/26/2015 697.26 59.63 637.63 8/27/2015 31.99 665.27 4/14/2016 30.20 667.06 6/16/2016 30.88 666.38 AS -2S 6/24/2015 697.84 24.96 672.88 8/27/2015 25.70 672.14 4/14/2016 24.00 673.84 6/16/2016 24.62 673.22 AS-313RU 6/24/2015 754.16 49.80 704.36 8/27/2015 49.90 704.26 4/18/2016 49.50 704.66 6/16/2016 49.57 704.60 Cliffside Steam Station Page 2 of 16 CSA Supplement 2 Table 3-5: Summary of Groundwater Elevations Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation AS -4D 6/25/2015 837.71 92.79 744.92 8/27/2015 92.97 744.74 4/15/2016 91.25 746.46 6/16/2016 91.86 745.85 AS -4S 6/25/2015 837.49 94.24 743.25 8/27/2015 98.58 738.91 4/15/2016 92.96 744.53 6/16/2016 93.44 744.05 AS -513R 6/25/2015 739.77 36.70 703.07 8/27/2015 36.97 702.80 4/15/2016 35.90 703.87 6/16/2016 36.21 703.56 AS-5BRU 6/25/2015 740.45 40.00 700.45 8/27/2015 41.30 699.15 4/15/2016 39.00 701.45 6/16/2016 39.33 701.12 AS -5S 6/25/2015 739.72 37.60 702.12 8/27/2015 38.08 701.64 4/18/2016 36.30 703.42 6/16/2016 36.98 702.79 AS -613R 6/25/2015 817.89 86.00 731.89 8/27/2015 88.28 729.61 4/15/2016 85.20 732.69 6/16/2016 88.69 729.20 AS -6D 6/26/2015 818.30 96.03 722.27 8/27/2015 96.30 722.00 4/15/2016 95.05 723.25 6/16/2016 95.03 723.27 AS -6S 6/26/2015 817.74 94.50 723.24 8/27/2015 95.98 721.76 4/15/2016 94.25 723.49 6/16/2016 94.23 723.51 AS -713R 6/26/2015 742.70 123.55 619.15 8/27/2015 >100 -- 4/14/2016 38.61 704.09 6/16/2016 42.18 700.52 AS -7D 6/29/2015 742.90 36.65 706.25 8/27/2015 38.25 704.65 4/14/2016 35.10 707.80 6/16/2016 36.00 706.90 AS -7S 6/29/2015 742.06 31.79 710.27 8/27/2015 32.67 709.39 4/14/2016 29.68 712.38 6/16/2016 30.80 711.26 BG-1BR 6/24/2015 802.50 26.79 775.71 8/27/2015 28.54 773.96 4/15/2016 23.15 779.35 6/16/2016 24.76 777.83 Cliffside Steam Station Page 3 of 16 CSA Supplement 2 Table 3-5: Summary of Groundwater Elevations Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation BG -1D 6/24/2015 802.63 26.70 775.93 8/27/2015 28.46 774.17 4/15/2016 23.11 779.52 6/16/2016 24.71 777.98 BG -1S 6/24/2015 802.67 26.80 775.87 8/27/2015 28.55 774.12 4/15/2016 23.05 779.62 6/16/2016 24.69 777.97 BG -2D 6/26/2015 846.51 49.08 797.43 8/27/2015 48.91 797.60 4/15/2016 44.23 802.28 6/16/2016 45.39 801.12 CCPM W -1D 875.89 3/30/2016 32.88 843.01 6/16/2016 36.17 839.41 CCPMW-1S 875.58 3/30/2016 32.23 843.35 6/16/2016 35.09 840.80 CLMW-1 6/25/2015 789.08 38.28 750.80 8/27/2015 38.06 751.02 4/14/2016 37.30 751.78 6/16/2016 37.82 751.26 CLMW-2 6/25/2015 728.92 39.76 689.16 8/27/2015 40.09 688.83 4/14/2016 38.31 690.61 6/16/2016 39.03 689.89 CLMW-3D 6/25/2015 774.92 48.30 726.62 8/27/2015 48.61 726.31 4/14/2016 46.30 728.62 6/16/2016 47.30 727.62 CLMW-3S 6/25/2015 775.07 48.35 726.72 8/27/2015 48.72 726.35 4/14/2016 46.45 728.62 6/16/2016 47.39 727.68 CLMW-4 6/26/2015 670.58 15.51 655.07 8/27/2015 15.65 654.93 6/16/2016 - -- CLMW-5S 6/25/2015 773.78 35.60 738.18 8/27/2015 37.43 736.35 4/18/2016 36.25 737.53 6/16/2016 37.82 735.96 CLMW-6 6/25/2015 770.86 5.80 765.06 8/27/2015 6.15 764.71 4/13/2016 4.40 766.46 6/16/2016 4.71 766.15 Cliffside Steam Station Page 4 of 16 CSA Supplement 2 Table 3-5: Summary of Groundwater Elevations Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation GWA-10D 6/24/2015 679.74 20.79 658.95 8/27/2015 18.45 661.29 4/15/2016 18.46 661.28 6/16/2016 18.49 661.25 GWA-10S 6/24/2015 679.55 21.50 658.05 8/27/2015 18.80 660.75 4/15/2016 18.75 660.80 6/16/2016 18.74 660.81 GWA-11BRU 6/24/2015 674.99 16.94 658.05 8/27/2015 14.55 660.44 4/15/2016 14.85 660.14 6/16/2016 15.02 659.97 GWA-11S 6/24/2015 674.98 16.79 658.19 8/27/2015 14.79 660.19 4/15/2016 14.57 660.41 6/16/2016 14.67 660.31 GWA-12BRU 6/24/2015 719.66 36.11 683.55 8/27/2015 36.56 683.10 4/15/2016 34.81 684.85 6/16/2016 35.70 683.96 GWA-12S 6/24/2015 719.40 27.90 691.50 8/27/2015 28.20 691.20 4/15/2016 27.25 692.15 6/16/2016 27.77 691.63 GWA-13BR 6/24/2015 72412 19.18 704.94 8/27/2015 19.30 704.82 6/16/2016 19.05 705.07 GWA-14D 6/26/2015 712.52 26.57 685.95 8/27/2015 27.08 685.44 4/14/2016 27.36 685.16 6/16/2016 27.06 685.46 GWA-14S 6/24/2015 712.41 26.14 686.27 8/27/2015 26.62 685.79 4/14/2016 24.59 687.82 6/16/2016 26.56 685.85 GWA-1BRU 6/25/2015 78129 15.13 766.16 8/27/2015 14.11 767.18 4/14/2016 12.90 768.39 6/16/2016 13.42 767.87 GWA-20D 6/25/2015 736.24 13.39 722.85 8/27/2015 13.46 722.78 4/14/2016 12.40 723.84 6/16/2016 13.02 723.22 GWA-20S 6/25/2015 736.13 8.04 728.09 8/27/2015 8.41 727.72 4/14/2016 7.50 728.63 6/16/2016 8.48 727.65 Cliffside Steam Station Page 5 of 16 CSA Supplement 2 Table 3-5: Summary of Groundwater Elevations Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation GWA-21BR 6/24/2015 672.98 26.60 646.38 8/27/2015 2.73 670.25 4/18/2016 -- -- 6/16/2016 2.94 669.67 GWA-21BRU 6/25/2015 672.91 14.56 658.35 8/27/2015 14.83 658.08 4/18/2016 13.70 659.21 6/16/2016 14.07 658.44 GWA-21S 6/25/2015 673.32 14.55 658.77 8/27/2015 14.95 658.37 4/18/2016 13.38 659.94 6/16/2016 13.87 659.13 GWA-22BRU 6/26/2015 665.16 12.00 653.16 8/27/2015 12.98 652.18 4/19/2016 11.39 653.77 6/16/2016 12.12 653.03 GWA-22S 6/26/2015 665.19 9.42 655.77 8/27/2015 9.73 655.46 4/19/2016 8.26 656.93 6/16/2016 9.12 656.05 GWA-23D 6/24/2015 786.80 26.00 760.80 8/27/2015 25.45 761.35 4/19/2016 25.25 761.55 6/16/2016 27.25 759.57 GWA-24BR 798.92 - 4/21/2016 18.37 780.55 6/16/2016 20.41 778.51 GWA-24D 6/26/2015 794.94 19.41 775.53 8/27/2015 20.40 774.54 4/15/2016 17.40 777.54 6/16/2016 17.79 777.09 GWA-24S 6/26/2015 794.47 21.00 773.47 8/27/2015 22.15 772.32 4/15/2016 19.20 775.27 6/16/2016 20.34 774.01 GWA 25D 6/25/2015 792.01 23.35 768.66 8/27/2015 23.67 768.34 4/13/2016 22.22 769.79 6/16/2016 22.61 769.40 GWA 25S 6/25/2015 791.81 23.16 768.65 8/27/2015 23.50 768.31 4/13/2016 22.10 769.71 6/16/2016 22.42 769.39 GWA 26D 6/24/2015 782.98 19.35 763.63 8/27/2015 20.58 762.40 4/13/2016 17.45 765.53 6/16/2016 18.04 764.94 Cliffside Steam Station Page 6 of 16 CSA Supplement 2 Table 3-5: Summary of Groundwater Elevations Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation GWA-26S 6/24/2015 783.36 20.25 763.11 8/27/2015 20.58 762.78 4/13/2016 17.50 765.86 6/16/2016 19.05 764.31 GWA-27D-A 6/24/2015 805.53 49.65 755.88 8/27/2015 49.52 756.01 4/13/2016 49.40 756.13 6/16/2016 49.39 756.09 GWA-28BR 6/24/2015 757.90 48.45 709.45 8/27/2015 48.17 709.73 4/18/2016 47.60 710.30 6/16/2016 48.34 709.54 GWA-28BRU 6/24/2015 758.35 42.84 715.51 8/27/2015 43.11 715.24 4/18/2016 42.42 715.93 6/16/2016 42.79 715.49 GWA-28S 6/24/2015 757.74 38.00 719.74 8/27/2015 38.30 719.44 4/18/2016 36.70 721.04 6/16/2016 37.62 720.15 GWA-29BR 6/24/2015 679.38 34.41 644.97 8/27/2015 29.10 650.28 4/15/2016 16.49 662.89 6/16/2016 19.08 660.54 GWA-29D 6/24/2015 679.56 22.74 656.82 8/27/2015 24.46 655.10 4/15/2016 22.68 656.88 6/16/2016 22.73 656.90 GWA-2BRU 685.35 8/27/2015 15.74 669.61 4/14/2016 14.40 670.95 6/16/2016 14.86 670.49 GWA-2S 6/26/2015 685.56 13.70 671.86 8/27/2015 14.26 671.30 4/14/2016 12.15 673.41 6/16/2016 12.92 672.64 GWA-30BR 6/25/2015 806.90 35.66 771.24 8/27/2015 35.95 770.95 4/14/2016 35.34 771.56 6/16/2016 35.29 771.61 GWA-30BRU 6/25/2015 806.72 27.42 779.30 8/27/2015 28.43 778.29 4/14/2016 26.07 780.65 6/16/2016 26.64 780.08 GWA-30S 6/25/2015 806.89 23.21 783.68 8/27/2015 25.61 781.28 4/14/2016 22.39 784.50 6/16/2016 23.17 783.72 Cliffside Steam Station Page 7 of 16 CSA Supplement 2 Table 3-5: Summary of Groundwater Elevations Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation GWA-31BR 6/26/2015 755.04 51.22 703.82 8/27/2015 49.12 705.92 4/13/2016 37.96 717.08 6/16/2016 42.25 712.63 GWA-31BR-A 757.13 4/13/2016 16.73 740.40 6/16/2016 -- -- GWA-31D 6/24/2015 754.89 13.01 741.88 8/27/2015 13.78 741.11 4/13/2016 13.15 741.74 6/16/2016 13.04 741.89 GWA-32BR 6/26/2015 698.56 31.03 667.53 8/27/2015 31.73 666.83 4/15/2016 29.12 669.44 6/16/2016 29.59 668.97 GWA-32D 6/26/2015 698.53 32.66 665.87 8/27/2015 33.85 664.68 4/15/2016 30.75 667.78 6/16/2016 32.32 666.26 GWA-33BR 6/24/2015 722.94 17.20 705.74 8/27/2015 17.71 705.23 4/14/2016 16.86 706.08 6/16/2016 17.30 705.64 GWA-33D 6/24/2015 722.88 6.91 715.97 8/27/2015 7.81 715.07 4/14/2016 6.01 716.87 6/16/2016 6.56 716.32 GWA-33S 6/24/2015 722.71 6.19 716.52 8/27/2015 7.23 715.48 4/14/2016 5.31 717.40 6/16/2016 5.69 717.02 GWA-34S 715.88 4/19/2016 5.82 710.06 6/16/2016 7.77 708.11 GWA-35D 697.74 4/19/2016 27.63 670.11 6/16/2016 28.06 669.68 GWA-35S 698.04 4/19/2016 26.00 672.04 6/16/2016 26.95 671.09 GWA-36D 710.53 2/25/2016 39.72 670.81 6/16/2016 8.13 702.40 Cliffside Steam Station Page 8 of 16 CSA Supplement 2 Table 3-5: Summary of Groundwater Elevations Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation GWA-36S 710.53 2/29/2016 8.88 701.65 6/16/2016 9.22 701.31 GWA-37D 710.47 4/21/2016 37.55 672.92 6/16/2016 38.21 672.26 GWA-37S 710.56 4/21/2016 47.11 663.45 6/16/2016 42.27 668.29 GWA-38D 760.01 4/20/2016 54.14 705.87 6/16/2016 54.38 705.63 GWA-38S 760.20 2/29/2016 53.18 707.02 6/16/2016 -- -- GWA-39S 723.41 4/19/2016 3.42 719.99 6/16/2016 3.89 719.52 GWA-3D 6/25/2015 757.53 60.85 696.68 8/27/2015 61.78 695.75 4/14/2016 58.90 698.63 6/16/2016 59.30 698.44 GWA-40S 723.09 4/19/2016 5.85 717.24 6/16/2016 6.60 716.49 GWA-42S 724.65 4/20/2016 9.36 715.29 6/16/2016 9.81 714.84 GWA-43D 725.10 4/19/2016 12.45 712.65 6/16/2016 15.22 709.88 GWA-43S 725.19 4/20/2016 8.78 716.41 6/16/2016 9.24 715.95 GWA-44BR 769.03 2/26/2016 34.92 734.11 6/16/2016 36.56 732.47 Cliffside Steam Station Page 9 of 16 CSA Supplement 2 Table 3-5: Summary of Groundwater Elevations Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation GWA-44D 769.07 2/26/2016 41.60 727.47 6/16/2016 42.89 726.18 GWA-44S 768.88 2/29/2016 44.60 724.28 6/16/2016 44.50 724.38 GWA-45D 816.59 2/24/2016 66.12 750.47 6/16/2016 63.96 752.63 GWA-45S 816.55 2/26/2016 53.00 763.55 6/16/2016 -- -- GWA-46D 788.60 3/4/2016 25.38 763.22 6/16/2016 -- -- GWA-47D 805.18 4/20/2016 46.28 758.90 6/16/2016 47.20 757.98 GWA-48BR 808.90 4/21/2016 25.63 783.27 6/16/2016 29.27 779.63 GWA-4D 6/24/2015 711.64 5.53 706.11 8/27/2015 6.11 705.53 4/14/2016 4.88 706.76 6/16/2016 5.21 706.43 GWA-4S 6/24/2015 711.61 4.50 707.11 8/27/2015 4.93 706.68 4/14/2016 3.73 707.88 6/16/2016 3.95 707.66 GWA-5BRU 6/25/2015 776.83 31.10 745.73 8/27/2015 23.35 753.48 4/14/2016 31.90 744.93 6/16/2016 21.97 754.76 GWA-5S 6/25/2015 777.01 22.10 754.91 8/27/2015 22.32 754.69 4/13/2016 21.45 755.56 6/16/2016 20.62 756.35 GWA-6D 6/25/2015 809.97 40.27 769.70 8/27/2015 41.22 768.75 4/14/2016 33.59 776.38 6/16/2016 35.64 774.33 Cliffside Steam Station Page 10 of 16 CSA Supplement 2 Table 3-5: Summary of Groundwater Elevations Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation GWA-6S 6/25/2015 810.00 40.08 769.92 8/27/2015 40.99 769.01 4/14/2016 33.58 776.42 6/16/2016 35.62 774.38 113-1D 6/24/2015 700.72 36.69 664.03 8/27/2015 36.20 664.52 4/15/2016 36.75 663.97 6/16/2016 -- -- IB -1S 6/24/2015 700.74 35.59 665.15 8/27/2015 34.54 666.20 4/15/2016 36.10 664.64 6/16/2016 -- -- 1B-2AL 6/24/2015 697.55 30.76 666.79 8/27/2015 30.33 667.22 6/16/2016 -- -- 113-213RU 6/24/2015 697.67 22.57 675.10 8/27/2015 22.66 675.01 6/16/2016 -- -- IB -21 6/24/2015 697.22 30.08 667.14 8/27/2015 26.69 670.53 6/16/2016 - -- IB -2S -SL 6/24/2015 697.73 26.56 671.17 8/27/2015 27.00 670.73 6/16/2016 - -- 113-3D 6/24/2015 704.08 44.84 659.24 8/27/2015 44.02 660.06 4/15/2016 42.55 661.53 6/16/2016 43.15 660.93 113-3S 6/24/2015 704.15 32.22 671.93 8/27/2015 32.93 671.22 4/15/2016 32.65 671.50 6/16/2016 33.11 671.04 IB-4BR 6/24/2015 701.93 13.22 688.71 8/27/2015 13.63 688.30 6/16/2016 - -- 113-4D 6/24/2015 700.38 13.34 687.04 8/27/2015 13.75 686.63 6/16/2016 - -- IB -4S -SL 6/24/2015 700.34 16.23 684.11 8/27/2015 16.31 684.03 6/16/2016 - Cliffside Steam Station Page 11 of 16 CSA Supplement 2 Table 3-5: Summary of Groundwater Elevations Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation MW -10D 6/25/2015 785.50 26.76 758.74 8/27/2015 27.25 758.25 4/18/2016 26.22 759.28 6/16/2016 28.27 757.23 MW -10S 6/25/2015 785.81 27.35 758.46 8/27/2015 27.72 758.09 4/18/2016 26.58 759.23 6/16/2016 28.63 757.18 MW -11D 6/25/2015 763.67 43.90 719.77 8/27/2015 43.12 720.55 4/15/2016 39.10 724.57 6/16/2016 42.74 720.93 MW -11S 6/25/2015 764.51 27.16 737.35 8/27/2015 27.03 737.48 4/15/2016 28.20 736.31 6/16/2016 28.67 735.84 MW -2 DA 6/26/2015 730.62 36.47 694.15 8/27/2015 36.88 693.74 4/14/2016 35.36 695.26 6/16/2016 36.04 694.58 MW -20D 6/26/2015 665.20 9.30 655.90 8/27/2015 7.17 658.03 6/16/2016 -- -- MW-21BR 6/26/2015 777.56 12.57 764.99 8/27/2015 13.05 764.51 4/19/2016 11.75 765.81 6/16/2016 13.93 763.58 MW -21D 6/24/2015 777.51 6.45 771.06 8/27/2015 7.15 770.36 6/16/2016 - -- MW-22BR 6/25/2015 821.11 43.25 777.86 8/27/2015 41.87 779.24 4/15/2016 32.22 788.89 6/16/2016 35.08 785.76 MW-22DR 6/26/2015 821.81 39.34 782.47 8/27/2015 40.64 781.17 6/16/2016 - MW -23S 733.62 3/10/2016 19.78 713.84 6/16/2016 16.96 716.66 MW -23D 6/26/2015 733.80 17.87 715.93 8/27/2015 18.27 715.53 6/16/2016 - Cliffside Steam Station Page 12 of 16 CSA Supplement 2 Table 3-5: Summary of Groundwater Elevations Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation MW-23DR 6/26/2015 733.80 15.80 718.00 8/27/2015 16.84 716.96 6/16/2016 -- -- MW -24D 6/26/2015 816.36 19.50 796.86 8/27/2015 21.47 794.89 3/30/2016 14.79 801.57 6/16/2016 17.99 798.37 MW-24DR 6/26/2015 816.28 14.80 801.48 8/27/2015 16.89 799.39 3/30/2016 10.66 805.62 6/16/2016 13.56 802.72 MW-25DR 6/26/2015 667.05 12.63 654.42 8/27/2015 12.73 654.32 6/16/2016 -- -- MW -30D 6/25/2015 833.26 42.30 790.96 8/27/2015 43.80 789.46 3/29/2016 41.18 792.08 6/16/2016 41.67 791.53 MW -30S 6/25/2015 833.73 43.01 790.72 8/27/2015 43.13 790.60 3/29/2016 40.59 793.14 6/16/2016 41.06 792.63 MW-32BR 6/25/2015 839.40 29.25 810.15 8/27/2015 30.76 808.64 3/29/2016 26.67 812.73 6/16/2016 29.34 809.96 MW -32D 6/25/2015 839.28 30.20 809.08 8/27/2015 29.93 809.35 3/29/2016 26.90 812.38 6/16/2016 29.73 809.45 MW -32S 6/25/2015 839.71 31.91 807.80 8/27/2015 33.02 806.69 3/29/2016 28.97 810.74 6/16/2016 31.56 808.08 MW -34D 6/25/2015 751.66 29.00 722.66 8/27/2015 31.21 720.45 4/14/2016 27.60 724.06 6/16/2016 29.22 722.44 MW -34S 6/25/2015 751.87 28.17 723.70 8/27/2015 31.26 720.61 4/14/2016 26.80 725.07 6/16/2016 31.12 720.75 MW-36BRU 6/26/2015 678.40 13.09 665.31 8/27/2015 13.56 664.84 4/14/2016 10.63 667.77 6/16/2016 11.87 666.00 Cliffside Steam Station Page 13 of 16 CSA Supplement 2 Table 3-5: Summary of Groundwater Elevations Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation MW -36S 6/26/2015 678.87 13.00 665.87 8/27/2015 14.33 664.54 4/14/2016 9.51 669.36 6/16/2016 11.65 667.25 MW -38D 6/24/2015 707.68 39.76 667.92 8/27/2015 40.32 667.36 4/14/2016 38.72 668.96 6/16/2016 39.27 668.41 MW -38S 6/24/2015 707.60 40.89 666.71 8/27/2015 41.32 666.28 4/14/2016 39.90 667.70 6/16/2016 40.35 667.26 MW-40BRU 6/24/2015 709.56 36.78 672.78 8/27/2015 6.00 703.56 4/14/2016 4.80 704.76 6/16/2016 5.10 704.46 MW -40S 6/24/2015 709.38 9.44 699.94 8/27/2015 8.25 701.13 4/14/2016 6.52 702.86 6/16/2016 6.85 702.53 MW -42D 6/25/2015 811.12 50.46 760.66 8/27/2015 37.59 773.53 4/13/2016 35.30 775.82 6/16/2016 37.10 774.02 MW -42S 6/25/2015 811.47 36.72 774.75 8/27/2015 38.00 773.47 4/14/2016 35.32 776.15 6/16/2016 37.04 774.43 MW -4D 6/26/2015 67212 15.98 656.14 8/27/2015 16.35 655.77 6/16/2016 -- -- MW -7D 6/26/2015 807.35 40.65 766.70 8/27/2015 DRY -- 4/13/2016 41.23 766.12 6/16/2016 -- -- MW -8D 6/25/2015 736.64 8.65 727.99 8/27/2015 9.81 726.83 4/14/2016 9.65 726.99 6/16/2016 9.80 726.84 MW -8S 6/25/2015 736.27 6.31 729.96 8/27/2015 6.40 729.87 4/14/2016 6.22 730.05 6/16/2016 6.29 729.98 U5 -1D 6/25/2015 802.94 47.50 755.44 8/27/2015 48.35 754.59 4/13/2016 44.29 758.65 6/16/2016 45.13 757.81 Cliffside Steam Station Page 14 of 16 CSA Supplement 2 Table 3-5: Summary of Groundwater Elevations Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation U5 -1S 6/25/2015 802.71 46.72 755.99 8/27/2015 47.72 754.99 4/13/2016 43.51 759.20 6/16/2016 44.32 758.39 U5-2BR 795.06 3/3/2016 62.02 733.04 6/16/2016 66.09 728.97 U5-21) 6/25/2015 793.73 65.79 727.94 8/27/2015 68.11 725.62 4/13/2016 60.65 733.08 6/16/2016 62.69 731.04 U5 -2S -SL -A 6/25/2015 795.42 57.53 736.52 8/27/2015 60.30 733.75 4/20/2016 55.50 738.55 6/16/2016 58.45 736.97 U5-31) 6/25/2015 765.68 54.31 711.37 8/27/2015 51.78 713.90 4/13/2016 45.40 720.28 6/16/2016 46.68 719.18 U5 -35-A 6/25/2015 765.85 48.00 717.39 8/27/2015 50.12 715.27 3/8/2016 43.24 722.15 6/16/2016 46.69 719.16 U5-4BR 6/26/2015 765.06 125.10 639.96 8/27/2015 >100 -- 4/13/2016 83.07 681.99 6/16/2016 85.89 679.17 U5 -4D 6/25/2015 764.99 93.81 671.18 8/27/2015 73.10 691.89 4/13/2016 60.80 704.19 6/16/2016 61.75 703.46 U5 -4S 6/25/2015 764.82 65.28 699.54 8/27/2015 66.09 698.73 4/13/2016 59.07 705.75 6/16/2016 60.25 704.78 U5-51) 6/25/2015 765.40 61.28 704.12 8/27/2015 19.61 745.79 4/14/2016 60.00 705.40 6/16/2016 61.34 704.34 U5-61) 6/24/2015 765.19 50.55 714.64 8/27/2015 51.14 714.05 4/13/2016 49.25 715.94 6/16/2016 35.72 729.47 U5 -6S 6/24/2015 765.28 50.79 714.49 8/27/2015 51.35 713.93 4/13/2016 49.55 715.73 6/16/2016 50.81 714.47 Cliffside Steam Station Page 15 of 16 CSA Supplement 2 Table 3-5: Summary of Groundwater Elevations Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation U5-71) 6/26/2015 767.37 42.90 724.47 8/27/2015 32.17 735.20 4/14/2016 -- -- 6/16/2016 29.23 738.15 U5 -7S 6/26/2015 767.30 28.84 738.46 8/27/2015 29.37 737.93 4/13/2016 26.07 741.23 6/16/2016 26.31 741.02 U5-7SL 6/26/2015 767.21 29.68 737.53 8/27/2015 30.58 736.63 4/13/2016 26.47 740.74 6/16/2016 26.71 740.54 U5-8BR 770.31 2/23/2016 99.90 670.41 6/16/2016 -- -- U5-81) 6/25/2015 770.25 9.34 760.91 8/27/2015 9.86 760.39 4/13/2016 7.90 762.35 6/16/2016 8.01 762.24 U5 -8S 6/25/2015 770.29 7.92 762.37 8/27/2015 8.40 761.89 4/13/2016 5.95 764.34 6/16/2016 6.10 764.19 Cliffside Steam Station Page 16 of 16 CSA Supplement 2 Table 3-6: Summary of Cation -Anion Balance Differences Cliffside Steam Station Page 1 of 4 CSA Supplement 2 Anions Cations Constituent: Molecular Weight (g/mol) Charge Equivalent Weight : Alkalinity, CO3 60 2 30 Alkalinity, HCO3 61 1 61 Chloride 35.5 1 35.5 Nitrogen, NO2plus NO3 62 1 62 Sulfate 96.1 2 48.05 urn of Anions Calcium 40.1 2 20.05 Magnesium 24.3 2 12.15 Potassium 39.1 1 39.1 Sodium 23 1 23 Sum of Cations Charge Balance (%) Site Location Matrix Date Result eq/L Result eq/L Result eq/L Result eq/L Result eq/L eq/L Result eq/L Result eq/L Result eq/L Result eq/L eq/L Cliffside SW -1 Surface Water 4/18/2016 0 0 16.8 0.275 5.8 0.163 0.02 0 18.3 0.381 0.819 11.8 0.589 3.04 0.25 3.2 0.082 2.6 0.113 1.034 11.6% SW -10A Surface Water 4/28/2016 0 0 14.4 0.236 4.5 0.127 0.17 0.003 3.5 0.073 0.439 5.05 0.252 1.32 0.109 0 0 3.56 0.155 0.516 8.1% SW -10B Surface Water 4/28/2016 0 0 14.4 0.236 2 0.056 0.17 0.003 1.9 0.04 0.335 3.23 0.161 1.24 0.102 0 0 3.45 0.15 0.413 10.4% SW -10C Surface Water 4/28/2016 0 0 15.4 0.252 2.5 0.07 0.27 0.004 2 0.042 0.368 3.61 0.18 1.47 0.121 0 0 3.92 0.17 0.471 12.3% SW -2 Surface Water 4/18/2016 0 1 0 8.7 0.143 3.5 0.099 0.5 0.008 1.2 0.025 0.275 2.43 0.121 1.25 0.103 0 0 2.69 0.117 0.341 10.7% SW -3 Surface Water 4/18/2016 0 0 9.1 0.149 3.7 0.104 0.45 0.007 3.2 0.067 0.327 3.45 0.172 1.46 0.12 0 0 2.72 0.118 0.41 11.3% SW -4 Surface Water 4/18/2016 0 0 8.5 0.139 3.6 0.101 0.45 0.007 2.7 0.056 0.303 3.13 0.156 1.43 0.118 0 0 2.66 0.116 0.39 12.6% SW -5 Surface Water 4/19/2016 0 0 0 0 21.4 0.603 0.14 0.002 36 0.749 1.354 15.5 0.773 1.7 0.14 0 0 6.11 0.266 1.179 -6.9% SW -7 Surface Water 4/19/2016 0 0 12.1 0.198 66.2 1.865 0.31 0.005 39.4 0.82 2.888 43.3 2.16 3.33 0.274 3.39 0.087 8.74 0.38 2.901 0.2% SW -8 Surface Water 4/19/2016 0 0 52 0.852 7.8 0.22 0.11 0.002 81.8 1.702 2.776 37.5 1.87 9.8 0.807 4.49 0.115 4.61 0.2 2.992 3.7% SW -9 Surface Water 4/19/2016 0 0 13 0.213 1.7 0.048 0.12 0.002 1.7 0.035 0.298 2.83 0.141 1.09 0.09 0 0 2.96 0.129 0.36 9.4% AB -1 D Groundwater 4/18/2016 0 0 68.2 1.118 55.6 1.566 0 0 33.6 0.699 3.383 51.2 2.554 7.21 0.593 3.51 0.09 11.7 0.509 3.746 5.1% AB -1 S Groundwater 4/18/2016 0 0 22.2 0.364 14.7 0.414 0 0 2.4 0.05 0.828 6.41 0.32 1.82 0.15 3.68 0.094 5.64 0.245 0.809 -1.2% AB -2D Groundwater 4/14/2016 0 0 36.8 0.603 45.3 1.276 0 0 48 0.999 2.878 27.6 1.377 5.5 0.453 10.2 0.261 16.5 0.717 2.808 -1.2% AB -2S Groundwater 4/14/2016 0 0 11.6 0.19 47 1.324 0 0 15.1 0.314 1.828 5.35 0.267 1.9 0.156 2.84 0.073 16.5 0.717 1.213 -20.2% AB-3BRU Groundwater 4/13/2016 181 6.033 91.2 1.495 3.8 0.107 0.14 0.002 69.2 1.44 9.077 74.8 3.731 0 0 70.9 1.813 29.7 1.291 6.835 -14.1% AB -31 Groundwater 4/13/2016 0 0 70.7 1.159 2.4 0.068 0 0 7 0.146 1.373 7.27 0.363 1.15 0.095 18.9 0.483 13.2 0.574 1.515 4.9% AB-4BR Groundwater 4/13/2016 0 0 62.5 1.025 3.4 0.096 0 0 4.2 0.087 1.208 16 0.798 2.75 0.226 0 0 5.81 0.253 1.277 2.8% AB -4D Groundwater 4/13/2016 0 0 8.4 0.138 3.2 0.09 0.18 0.003 0.84 0.017 0.248 1.2 0.06 0.961 0.079 0 0 3.14 0.137 0.276 5.3% AB-5BR Groundwater 3/7/2016 0 0 70.9 1.162 1.8 0.051 0 0 11.1 0.231 1.444 24.9 1.242 2.7 0.222 3.82 0.098 10.1 0.439 2.001 16.2% AB-5BRU Groundwater 4/13/2016 0 0 10.5 0.172 3.4 0.096 1 0.016 5.8 0.121 0.405 3.42 0.171 1.26 0.104 0 0 4.31 0.187 0.462 6.6% AB-6BR Groundwater 4/13/2016 0 0 53.7 0.88 2.9 0.082 0 0 3.6 0.075 1.037 12.4 0.618 2.39 0.197 2.95 0.075 5.68 0.247 1.137 4.6% AB -6D Groundwater 4/13/2016 0 0 8.2 0.134 3.2 0.09 1.4 0.023 1.1 0.023 0.27 2.22 0.111 1 0.082 0 0 3.59 0.156 0.349 12.8% AS -1 D Groundwater 4/14/2016 0 0 4.3 0.07 24.2 0.682 0.037 0.001 49 1.02 1.773 13.8 0.688 4.37 0.36 7.08 0.181 13.1 0.57 1.799 0.7% AS -1 SB Groundwater 4/14/2016 0 0 0 0 47.7 1.344 0.082 0.001 371 7.721 9.066 130 6.484 13.8 1.136 0 0 12.8 0.557 8.177 -5.2% AS -2D Groundwater 4/14/2016 0 0 82 1.344 20.9 0.589 0 0 209 4.35 6.283 72.6 3.621 9.78 0.805 12.6 0.322 38.2 1.661 6.409 1.0% AS -2S Groundwater 4/14/2016 0 0 0 0 38.3 1.079 0.35 0.006 284 5.911 6.996 86.6 4.319 23.6 1.942 0 0 10.6 0.461 6.722 -2.0% AS-3BRU Groundwater 4/18/2016 0 0 6.1 0.1 5 0.141 0.4 0.006 0 0 0.247 1.43 0.071 0.62 0.051 3.15 0.081 3.13 0.136 0.339 15.7% AS -4D Groundwater 4/15/2016 0 0 103 1.689 5.8 0.163 0.6 0.01 11.6 0.241 2.103 40 1.995 1.19 0.098 11.6 0.297 6.96 0.303 2.693 12.3% AS-5BR Groundwater 4/15/2016 0 0 52.6 0.862 1.6 0.045 0.32 0.005 14.5 0.302 1.214 19 0.948 0.418 0.034 9.45 0.242 8.47 0.368 1.592 13.5% AS-5BRU Groundwater 4/15/2016 0 0 13.1 0.215 1.3 0.037 0.26 0.004 0.42 0.009 0.265 2.35 0.117 0.425 0.035 0 0 4.13 0.18 0.332 11.2% AS -5S Groundwater 4/18/2016 0 0 5.7 0.093 1.5 0.042 0.12 0.002 0 0 0.137 0.654 0.033 0.519 0.043 0 0 1.69 0.073 0.149 4.2% AS-6BR Groundwater 4/15/2016 395 13.167 161 2.639 1.6 0.045 0 0 6.1 0.127 15.978 242 12.07 0.149 0.012 3.69 0.094 11.6 0.504 12.68 -11.5% AS -6D Groundwater 4/15/2016 0 0 12.5 0.205 1.5 0.042 0.42 0.007 0 0 0.254 2.54 0.127 0.578 0.048 0 0 3.64 0.158 0.333 13.5% AS -6S Groundwater 4/15/2016 0 0 11.9 0.195 2.4 0.068 0.31 0.005 0.85 0.018 0.286 2.46 0.123 1.08 0.089 0 0 4.4 0.191 0.403 17.0% AS-7BR Groundwater 4/14/2016 623 20.767 0 0 1.8 0.051 0 0 8.2 0.171 20.989 281 14.015 0 0 282 7.212 77.4 3.365 24.592 7.9% AS -7D Groundwater 4/14/2016 0 0 12.7 0.208 32.4 0.913 0.046 0.001 85.6 1.781 2.903 32.4 1.616 7.45 0.613 7.68 0.196 14.1 0.613 3.038 2.3% BG -1 BR Groundwater 3/28/2016 3.5 0.117 73.8 1.21 1.8 0.051 0.12 0.002 18.9 0.393 1.773 23.4 1.167 1.87 0.154 19.4 0.496 12.1 0.526 2.343 13.8% BG -1 D Groundwater 3/28/2016 0 0 8 0.131 2.5 0.07 1.5 0.024 3.7 0.077 0.302 2.41 0.12 1.03 0.085 0 0 4.38 0.19 0.395 13.3% BG -1S Groundwater 3/28/2016 0 0 1.1 0.018 12.2 0.344 2.2 0.035 0 0 0.397 0.645 0.032 2.26 0.186 0 0 6.68 0.29 0.508 12.3% BG -21D Groundwater 3/29/2016 0 0 52.3 0.857 8 0.225 0.22 0.004 28.6 0.595 1.681 13.8 0.688 0.648 0.053 2.53 0.065 23.5 1.022 1.828 4.2% CCP-MW1D Groundwater 3/30/2016 0 0 4.5 0.074 5.7 0.161 0.92 0.015 1.7 0.035 0.285 2.24 0.112 1.52 0.125 0 0 2.54 0.11 0.347 9.8% CCP-MW1S Groundwater 3/30/2016 0 0 1 0.016 3.8 0.107 0.017 0 0.74 0.015 0.138 0.166 0.008 0.913 0.075 0 0 0 0 0.083 -24.9% CLMW-2 Groundwater 4/14/2016 0 0 0 0 39.4 1.11 0.18 0.003 172 3.58 4.693 20.2 1.007 28.5 2.346 11.1 0.284 15.1 0.657 4.294 -4.4% CLMW-3D Groundwater 4/14/2016 0 0 3.3 0.054 42.1 1.186 0.095 0.002 208 4.329 5.571 56.4 2.813 23.4 1.926 8.63 0.221 15.8 0.687 5.647 0.7% CLMW-3S Groundwater 4/14/20161 0 0 1 0 0 40.7 1.146 0.14 0.002 189 3.933 5.081 26.3 1.312 26.6 2.189 7.62 0.195 10.8 0.47 4.166 -9.9% CLMW-5S Groundwater 4/18/20161 0 1 0 1 7.4 1 0.121 15.1 0.425 0 0 2.5 0.052 0.598 2.47 1 0.123 1.14 0.0942.78 0.071 6.76 0.294 0.582 -1.4% Cliffside Steam Station Page 1 of 4 CSA Supplement 2 Table 3-6: Summary of Cation -Anion Balance Differences Cliffside Steam Station Page 2 of 4 CSA Supplement 2 Anions Cations Constituent: Molecular Weight (g/mol) Charge Equivalent Weight : Alkalinity, CO3 60 2 30 Alkalinity, HCO3 61 1 61 Chloride 35.5 1 35.5 Nitrogen, NO2plus NO3 62 1 62 Sulfate 96.1 2 48.05 urn of Anions Calcium 40.1 2 20.05 Magnesium 24.3 2 12.15 Potassium 39.1 1 39.1 Sodium 23 1 23 Sum of Cations Charge Balance (%) Site Location Matrix Date Result eq/L Result eq/L Result eq/L Result eq/L Result eq/L eq/L Result eq/L Result eq/L Result eq/L Result eq/L eq/L CLMW-6 Groundwater 4/13/2016 0 0 4.6 0.075 2.8 0.079 0.89 0.014 0.75 0.016 0.184 1.06 0.053 0.744 0.061 0 0 3 0.13 0.244 14.0% GWA-10D Groundwater 4/15/2016 0 0 80.2 1.315 6.5 0.183 0.094 0.002 15.5 0.323 1.823 29.5 1.471 4.3 0.354 3.84 0.098 8.12 0.353 2.276 11.1% GWA-10S Groundwater 4/15/2016 0 0 4.3 0.07 23.8 0.67 0.78 0.013 172 3.58 4.333 53.2 2.653 11.6 0.955 4.37 0.112 9.73 0.423 4.143 -2.2% GWA-11 BRU Groundwater 4/15/2016 0 0 81.9 1.343 23.6 0.665 0.028 0 132 2.747 4.755 66.4 3.312 13.2 1.086 9.65 0.247 16.2 0.704 5.349 5.9% GWA-11 S Groundwater 4/15/2016 0 0 66.8 1.095 24.1 0.679 0.18 0.003 204 4.246 6.023 90.4 4.509 16.2 1.333 8.71 0.223 14.8 0.643 6.708 5.4% GWA-12BRU Groundwater 4/15/2016 0 0 37.2 0.61 4.9 0.138 0 0 8.4 0.175 0.923 8.89 0.443 4.43 0.365 2.59 0.066 6.89 0.3 1.174 12.0% GWA-12S Groundwater 4/15/2016 0 0 19.9 0.326 15.5 0.437 0.25 0.004 13.7 0.285 1.052 11 0.549 4.05 0.333 0 0 6.58 0.286 1.168 5.2% GWA-14D Groundwater 4/14/2016 0 0 119 1.951 8.4 0.237 2.3 0.037 227 4.724 6.949 98.2 4.898 26.5 2.181 5.86 0.15 6.7 0.291 7.52 3.9% GWA-14S Groundwater 4/14/2016 0 0 74.8 1.226 5.9 0.166 4.2 0.068 118 2.456 3.916 55.7 2.778 16.7 1.374 3.63 0.093 4.36 0.19 4.435 6.2% GWA-1 BRU Groundwater 4/14/2016 0 0 67.8 1.111 3.7 0.104 0 0 7 0.146 1.361 23.7 1.182 1.38 0.114 0 0 5.89 0.256 1.552 6.6% GWA-20D Groundwater 4/14/2016 0 0 19.3 0.316 45.5 1.282 0 0 127 2.643 4.241 47.1 2.349 12.1 0.996 4.93 0.126 17.4 0.757 4.228 -0.2% GWA-20S Groundwater 4/14/2016 0 0 133 2.18 42.2 1.189 0 0 76.8 1.598 4.967 76.7 3.825 13.3 1.095 0 0 13.6 0.591 5.511 5.2% GWA-21 BR Groundwater 4/18/2016 0 0 181 2.967 13.8 0.389 0 0 0.6 0.012 3.368 70.3 3.506 5.99 0.493 3.2 0.082 8.82 0.383 4.464 14.0% GWA-21 BRU Groundwater 4/18/2016 0 0 36.8 0.603 20.3 0.572 0.2 0.003 64.5 1.342 2.52 37.3 1.86 9.55 0.786 3.17 0.081 5.32 0.231 2.958 8.0% GWA-21S Groundwater 4/18/2016 0 0 10.2 0.167 9.4 0.265 0 0 84.9 1.767 2.199 31.1 1.551 7.8 0.642 4.23 0.108 4.98 0.217 2.518 6.8% GWA-22BRU Groundwater 4/19/2016 119 3.967 7.8 0.128 14.5 0.408 0.097 0.002 8.2 0.171 4.676 11.6 0.579 0.161 0.013 65.6 1.678 19 0.826 3.096 -20.3% GWA-22S Groundwater 4/19/2016 0 0 23 0.377 28.8 0.811 0.016 0 2.3 0.048 1.236 16.8 0.838 3.37 0.277 0 0 4.98 0.217 1.332 3.7% GWA-23D Groundwater 4/19/2016 0 0 2.4 0.039 4.5 0.127 1.1 0.018 1.1 0.023 0.207 1.19 0.059 1.29 0.106 0 0 2.61 0.113 0.278 14.6% GWA-24BR Groundwater 4/21/2016 0 0 16 0.262 1.1 0.031 0.19 0.003 8.7 0.181 0.477 4.23 0.211 1.64 0.135 0 0 4.84 0.21 0.556 7.6% GWA-24D Groundwater 4/15/2016 0 0 10.7 0.175 2.3 0.065 1.3 0.021 2 0.042 0.303 3.81 0.19 1.39 0.114 0 0 3.47 0.151 0.455 20.1% GWA-24S Groundwater 4/15/2016 0 0 2.7 0.044 3.6 0.101 0.55 0.009 1.1 0.023 0.177 0.707 0.035 0.88 0.072 0 0 2.94 0.128 0.235 14.1% GWA-25D Groundwater 4/13/2016 0 0 48 0.787 3.5 0.099 1.9 0.031 12.8 0.266 1.183 20.6 1.027 1.32 0.109 6.16 0.158 5.91 0.257 1.551 13.5% GWA-25S Groundwater 4/13/2016 0 0 5.4 0.089 3.7 0.104 2 0.032 0.76 0.016 0.241 1.62 0.081 1.41 0.116 2.66 0.068 2.9 0.126 0.391 23.7% GWA-26D Groundwater 4/13/2016 225 7.5 61.9 1.015 1.7 0.048 0.28 0.005 45.2 0.941 9.509 103 5.137 0 0 36.3 0.928 15 0.652 6.717 -17.2% GWA-26S Groundwater 4/13/2016 0 0 1.4 0.023 2.1 0.059 0 0 0.6 0.012 0.094 0.0589 0.003 0.247 0.02 0 0 1.76 0.077 0.1 3.1% GWA-27D-A Groundwater 4/13/2016 0 0 1.2 0.02 47 1.324 0.15 0.002 76.5 1.592 2.938 35.7 1.781 4.81 0.396 2.98 0.076 8.44 0.367 2.62 -5.7% GWA-28BR Groundwater 4/18/2016 0 0 56.1 0.92 2.9 0.082 0 0 4.9 0.102 1.104 18.9 0.943 1.98 0.163 0 0 6.44 0.28 1.386 11.3% GWA-28BRU Groundwater 4/18/2016 0 0 23.5 0.385 2.2 0.062 0 0 10.2 0.212 0.659 5.6 0.279 1.55 0.128 3.2 0.082 6.1 0.265 0.754 6.7% GWA-28S Groundwater 4/18/2016 0 0 1.6 0.026 2.5 0.07 1.1 0.018 4.4 0.092 0.206 2.12 0.106 1.38 0.114 0 0 1.67 0.073 0.293 17.4% GWA-28S Groundwater 4/19/2016 0 0 1.6 0.026 2.5 0.07 1.1 0.018 4.4 0.092 0.206 2.12 0.106 1.38 0.114 0 0 1.67 0.073 0.293 17.4% GWA-29BR Groundwater 4/15/2016 1260 42 0 0 1.8 0.051 0.017 0 2.6 0.054 42.105 721 35.96 0 0 162 4.143 52.3 2.274 42.377 0.3% GWA-29D Groundwater 4/15/2016 0 0 17.5 0.287 8.7 0.245 0.18 0.003 5.6 0.117 0.652 7.94 0.396 3.03 0.249 0 0 4.26 0.185 0.83 12.0% GWA-2BRU Groundwater 4/14/2016 0 0 120 1.967 4.2 0.118 0 0 56.2 1.17 3.255 51.5 2.569 5.45 0.449 8.66 0.221 12.2 0.53 3.769 7.3% GWA-2S Groundwater 4/14/2016 0 0 53.9 0.884 1.8 0.051 0.18 0.003 7.5 0.156 1.094 29.7 1.481 11.1 0.914 2.86 0.073 3.7 0.161 2.629 41.2% GWA-30BR Groundwater 4/14/2016 0 0 38.3 0.628 7.5 0.211 0 0 11.1 0.231 1.07 11.9 0.594 2.37 0.195 14.1 0.361 6.51 0.283 1.433 14.5% GWA-30BRU Groundwater 4/14/2016 0 0 183 3 6.5 0.183 0 0 45.4 0.945 4.128 55.4 2.763 0 0 16 0.409 48.7 2.117 5.289 12.3% GWA-30S Groundwater 4/14/2016 0 0 10.9 0.179 3 0.085 0.12 0.002 0 0 0.266 2.16 0.108 1.46 0.12 0 0 1.67 0.073 0.301 6.2% GWA-31 BR Groundwater 4/13/2016 -- -- -- -- -- -- -- - -- -- -- 36.7 1.83 0.643 0.053 88.3 2.258 326 14.174 18.315 GWA-31 D Groundwater 4/13/2016 0 0 93.4 1.531 2.2 0.062 0.14 0.002 114 2.373 3.968 57.8 2.883 9.98 0.821 14.2 0.363 13.4 0.583 4.65 7.9% GWA-32BR Groundwater 4/15/2016 71.1 2.37 38 0.623 2.9 0.082 0.063 0.001 31.2 0.649 3.725 30.6 1.526 0.397 0.033 33.6 0.859 19.5 0.848 3.266 -6.6% GWA-32D Groundwater 4/15/2016 0 0 4.2 0.069 1.1 0.031 0.27 0.004 0.43 0.009 0.113 1.19 0.059 0.165 0.014 0 0 1.88 0.082 0.155 15.7% GWA-33BR Groundwater 4/14/2016 0 0 88.4 1.449 9.4 0.265 0 0 39.5 0.822 2.536 30.7 1.531 5.06 0.416 31.1 0.795 20.2 0.878 3.62 17.6% GWA-33D Groundwater 4/14/2016 0 0 103 1.689 5.9 0.166 0.46 0.007 73.1 1.521 3.383 44.5 2.219 8.7 0.716 16 0.409 11.4 0.496 3.84 6.3% GWA-33S Groundwater 4/14/2016 0 0 1.4 0.023 2.9 0.082 0 0 99.1 2.062 2.167 21.7 1.082 9.38 0.772 0 0 2.87 0.125 1.979 -4.5% GWA-34S Groundwater 4/19/2016 0 0 7.7 0.126 2.4 0.068 0.041 0.001 1.9 0.04 0.235 2.43 0.121 0.706 0.058 0 0 1.93 0.084 0.263 5.6% GWA-35D Groundwater 4/19/2016 0 0 65.5 1.074 2.9 0.082 0 0 71 1.478 2.634 37.6 1.875 4.12 0.339 3.89 0.099 12.2 0.53 2.843 3.8% GWA-35S Groundwater 4/19/2016 0 0 41 0.672 3 0.085 0 0 25.9 0.539 1.296 11.6 0.579 5.8 0.477 0 0 2.66 0.116 1.172 -5.0% GWA-36D Groundwater 2/25/2016 6.7 0.223 16.8 0.275 5.7 0.161 0 0 272 5.661 6.32 108 5.387 16.8 1.383 11.2 0.286 11.1 0.483 7.539 8.80/. Cliffside Steam Station Page 2 of 4 CSA Supplement 2 Table 3-6: Summary of Cation -Anion Balance Differences Cliffside Steam Station Page 3 of 4 CSA Supplement 2 Anions Cations Constituent: Molecular Weight (g/mol) Charge Equivalent Weight : Alkalinity, CO3 60 2 30 Alkalinity, HCO3 61 1 61 Chloride 35.5 1 35.5 Nitrogen, NO2plusNO3 62 1 62 Sulfate 96.1 2 48.05 urn of Anions Calcium 40.1 2 20.05 Magnesium 24.3 2 12.15 Potassium 39.1 1 39.1 Sodium 23 1 23 Sum of Cations Charge Balance (%) Site Location Matrix Date Result eq/L Result eq/L Result eq/L Result eq/L Result eq/L eq/L Result eq/L Result eq/L Result eq/L Result eq/L eq/L GWA-36S Groundwater 2/29/2016 0 0 33.4 0.548 3.9 0.11 0.13 0.002 146 3.039 3.699 45.7 2.279 13.3 1.095 5.75 0.147 6.91 0.3 3.821 1.6% GWA-37D Groundwater 4/21/2016 0 0 54.8 0.898 3.5 0.099 0 0 306 6.368 7.365 94.5 4.713 23.1 1.901 5.68 0.145 15 0.652 7.411 0.3% GWA-37S Groundwater 4/21/2016 0 0 16.3 0.267 12.8 0.361 0 0 125 2.601 3.229 16.7 0.833 12.6 1.037 3.65 0.093 5.31 0.231 2.194 -19.1% GWA-38D Groundwater 4/20/2016 4.2 0.14 47.9 0.785 5.8 0.163 0 0 44 0.916 2.004 32.1 1.601 2.14 0.176 15.8 0.404 28.1 1.222 3.403 25.9% GWA-313 Groundwater 4/14/2016 0 0 36.8 0.603 5.1 0.144 0.079 0.001 212 4.412 5.16 65.5 3.267 16 1.317 6.27 0.16 9.44 0.41 5.154 -0.1% GWA-42S Groundwater 4/20/2016 0 0 1 0.016 1.2 0.034 0.047 0.001 41.9 0.872 0.923 7.38 0.368 4.7 0.387 4.35 0.111 0.964 0.042 0.908 -0.8% GWA-43D Groundwater 4/19/2016 0 0 96.6 1.584 3.4 0.096 0 0 67.9 1.413 3.093 38.5 1.92 11.1 0.914 7.57 0.194 8.02 0.349 3.377 4.4% GWA-43S Groundwater 4/20/2016 0 0 11.1 0.182 1.4 0.039 0.23 0.004 37.2 0.774 0.999 11.6 0.579 3.62 0.298 3.4 0.087 2.36 0.103 1.067 3.3% GWA-44BR Groundwater 2/26/2016 0 0 80.1 1.313 18.1 0.51 0 0 346 7.201 9.024 160 7.98 21.8 1.794 16.6 0.425 16.3 0.709 10.908 9.5% GWA-44D Groundwater 2/26/2016 0 0 32.3 0.53 16.4 0.462 0.45 0.007 283 5.89 6.889 110 5.486 15.4 1.267 14.4 0.368 14.8 0.643 7.764 6.0% GWA-44S Groundwater 2/29/2016 0 0 25 0.41 13.5 0.38 0.98 0.016 361 7.513 8.319 113 5.636 26.4 2.173 7.14 0.183 6.35 0.276 8.268 -0.3% GWA-45D Groundwater 2/24/2016 7.5 0.25 54 0.885 4.4 0.124 0.019 0 20.2 0.42 1.679 23.3 1.162 1.31 0.108 5.14 0.131 16.4 0.713 2.114 11.5% GWA-45S Groundwater 2/26/2016 0 0 0 0 6.2 0.175 4.3 0.069 43.6 0.907 1.151 7.4 0.369 4.95 0.407 3.09 0.079 3.75 0.163 1.018 -6.1% GWA-47D Groundwater 4/20/2016 0 0 34.8 0.57 27.2 0.766 0.21 0.003 1.3 0.027 1.366 13.3 0.663 2.66 0.219 5.27 0.135 9.21 0.4 1.417 1.8% GWA-48BR Groundwater 4/21/2016 0 0 65.4 1.072 1.9 0.054 0 0 12.4 0.258 1.384 20.7 1.032 2.74 0.226 5.43 0.139 6.33 0.275 1.672 9.4% GWA-413 Groundwater 4/14/2016 0 0 48.2 0.79 6.5 0.183 0 0 226 4.703 5.676 67.5 3.367 13.1 1.078 7.57 0.194 11.7 0.509 5.148 -4.9% GWA-4S Groundwater 4/14/2016 0 0 0 0 5.4 0.152 0 0 177 3.684 3.836 29.3 1.461 13 1.07 6.48 0.166 4.51 0.196 2.893 -14.0% GWA-5BRU Groundwater 4/14/2016 0 0 276 4.525 12.1 0.341 0 0 94.8 1.973 6.839 80.4 4.01 1 10.9 0.897 11.5 0.294 59.3 2.578 7.779 6.4% GWA-5S Groundwater 4/13/2016 0 0 28 0.459 13.4 0.377 6.2 0.1 191 3.975 4.911 44.8 2.234 33.5 2.757 7.76 0.198 6.03 0.262 5.451 5.2% GWA-613 Groundwater 4/14/2016 0 0 45.3 0.743 2.4 0.068 0.034 0.001 9.9 0.206 1.018 16.2 0.808 1.05 0.086 3.18 0.081 4.27 0.186 1.161 6.6% IB -1 D Groundwater 4/15/2016 0 0 68.4 1.121 6.3 0.177 0 0 43.6 0.907 2.205 35.9 1.791 3.29 0.271 7.05 0.18 11 0.478 2.72 10.5% IB -31D Groundwater 4/15/2016 0 0 47.1 0.772 4.7 0.132 0 0 81.7 1.7 2.604 36.4 1.815 6.44 0.53 4.07 0.104 6.2 0.27 2.719 2.2% IB -3S Groundwater 4/15/2016 0 0 12.2 0.2 2.3 0.065 0 0 229 4.766 5.031 23.8 1.187 33.1 2.724 0 0 8.39 0.365 4.276 -8.1% MW -10D Groundwater 4/18/2016 0 0 8.3 0.136 11.2 0.315 0.51 0.008 15.9 0.331 0.79 6.5 0.324 4.5 0.37 0 0 5.55 0.241 0.935 8.4% MW -10S Groundwater 4/18/2016 0 0 5.2 0.085 34.6 0.975 8.2 0.132 87.4 1.819 3.011 20.3 1.012 24.2 1.992 0 0 6.12 0.266 3.27 4.1% MW -11S Groundwater 4/15/2016 0 0 4.5 0.074 58.9 1.659 0.32 0.005 42.1 0.876 2.614 33 1.646 7.69 0.633 0 0 8.38 0.364 2.643 0.6% MW -21 BR Groundwater 4/19/2016 0 0 55.5 0.91 3.7 0.104 0 0 7.3 0.152 1.166 19.1 0.953 2.08 0.171 3.22 0.082 4.47 0.194 1.4 9.1% MW-22BR Groundwater 4/15/2016 0 0 30.8 0.505 2.3 0.065 0.46 0.007 8.5 0.177 0.754 11.3 0.564 1.85 0.152 2.76 0.071 5.94 0.258 1.045 16.2% MW -23S Groundwater 3/10/2016 0 0 10.5 0.172 14.1 0.397 0.31 0.005 142 2.955 3.529 34.1 1.701 19.2 1.58 3.06 0.078 6.63 0.288 3.647 1.6% MW -24D Groundwater 3/30/2016 0 0 3.3 0.054 3.9 0.11 2.7 0.044 0.94 0.02 0.228 1.76 0.088 1.1 0.091 0 0 4.41 0.192 0.371 23.9% MW-24DR Groundwater 3/30/2016 0 0 55.6 0.911 1.1 0.031 0 0 9 0.187 1.129 16.1 0.803 1.85 0.152 2.51 0.064 7.66 0.333 1.352 9.0% MW-2DA Groundwater 4/14/2016 0 0 62 1.016 5.7 0.161 0.086 0.001 13.1 0.273 1.451 12.4 0.618 2.2 0.181 3.79 0.097 17 0.739 1.635 6.0% MW -30D Groundwater 3/29/2016 19.2 0.64 29.2 0.479 7 0.197 0.24 0.004 13.7 0.285 1.605 17.7 0.883 2.34 0.193 5.5 0.141 8.04 0.35 1.567 -1.2% MW -30S Groundwater 3/29/2016 0 0 3.8 0.062 3.7 0.104 0.63 0.01 0 0 0.176 0.9 0.045 1.48 0.122 0 0 0 0 0.167 -2.6% MW-32BR Groundwater 3/29/2016 0 0 28.6 0.469 3.5 0.099 0 0 15.8 0.329 0.897 11.2 0.559 1.98 0.163 2.65 0.068 5.77 0.251 1.041 7.4% MW -32D Groundwater 3/29/2016 0 0 16 0.262 5 0.141 2.4 0.039 10.6 0.221 0.663 11.3 0.564 1.61 0.133 0 0 4 0.174 0.871 13.6% MW -32S Groundwater 3/29/2016 0 0 0 0 7 0.197 3.8 0.061 0.54 0.011 0.269 1.91 0.095 2.2 0.181 0 0 4.09 0.178 0.454 25.6% MW -34D Groundwater 4/14/2016 0 0 60.2 0.987 4.8 0.135 0 0 10.8 0.225 1.347 22 1.097 1.65 0.136 0 0 4.99 0.217 1.45 3.7% MW -34S Groundwater 4/14/2016 0 0 3.1 0.051 2.1 0.059 0.084 0.001 0 0 0.111 0.731 0.036 0.474 0.039 0 0 1.61 0.07 0.145 13.3% MW-36BRU Groundwater 4/14/2016 0 0 69.4 1.138 3.2 0.09 0 0 26.5 0.552 1.78 22.7 1.132 1.32 0.109 0 0 9.73 0.423 1.664 -3.4% MW -36S Groundwater 4/14/2016 0 0 11.2 0.184 0 0 0 0 0 0 0.184 7.86 0.392 3.84 0.316 2.55 0.065 4.09 0.178 0.951 67.6% MW -38D Groundwater 4/14/2016 0 0 64.5 1.057 4.3 0.121 0 0 280 5.827 7.005 99.5 4.963 25 2.058 8.63 0.221 12.4 0.539 7.781 5.2% MW -38S Groundwater 4/14/2016 0 0 14.5 0.238 6.6 0.186 0.41 0.007 171 3.559 3.99 28.6 1.426 30.8 2.535 3.75 0.096 8.23 0.358 4.415 5.1% MW-40BRU Groundwater 4/14/2016 0 0 117 1.918 6 0.169 0.1 0.002 74 1.54 3.629 62.6 3.122 3.68 0.303 10 0.256 8.91 0.387 4.068 5.7% MW -40S Groundwater 4/14/2016 0 0 10.4 0.17 15.3 0.431 0.54 0.009 106 2.206 2.816 32 1.596 13.1 1.078 0 0 5.1 0.222 2.896 1.4% MW -42D Groundwater 4/13/2016 172 5.733 202 3.311 7.3 0.206 0 0 122 2.539 11.789 29.6 1.476 2.4 0.198 262 6.701 44.5 1.935 10.31 -6.7% MW -42S Groundwater 4/14/2016 0 0 20.8 0.341 2.8 0.079 0.41 0.007 13.6 0.283 0.71 8.08 0.403 3.16 0.26 0 0 3.18 0.138 0.801 6.0% MW -81D Groundwater 4/14/2016 0 0 14.8 0.243 45.7 1.287 0 0 51.8 1.078 2.608 15.1 0.753 4.8 0.395 3.26 0.083 15.4 0.67 1.901 -15.7% Cliffside Steam Station Page 3 of 4 CSA Supplement 2 Table 3-6: Summary of Cation -Anion Balance Differences * NO2 + NO3 is being used as a surrogate for nitrate and the molecular weight of nitrate is assumed. ** GWA-31 BR not sampled for anions due to insufficient sample volume. Results of "0" are reported as non -detects by the analytical laboratory. Dataset consists of aqueous data associated with the first quarter of 2016 (even if dates do not align to traditional quarters). Formulas: Molecular Weight (mol) Result Value (ig) Cations (L ) - E Anions(L ) Equivalent Weight = eq/L= o Molecular Wr. g CBE/o = eq eq X 100 Charge r hnot)l E Cations )+ )+ E Anions( ) Charge J Cliffside Steam Station Page 4 of 4 CSA Supplement 2 Anions Cations Constituent: Molecular Weight (g/mol) Charge Equivalent Weight : Alkalinity, CO3 60 2 30 Alkalinity, HCO3 61 1 61 Chloride 35.5 1 35.5 Nitrogen, NO2plus NO3 62 1 62 Sulfate 96.1 2 48.05 urn of Anions Calcium 40.1 2 20.05 Magnesium 24.3 2 12.15 Potassium 39.1 1 39.1 Sodium 23 1 23 Sum of Cations Charge Balance N Site Location Matrix Date Result eq/L Result eq/L Result eq/L Result eq/L Result eq/L eq/L Result eq/L Result eq/L Result eq/L Result eq/L eq/L MW -8S Groundwater 4/14/2016 0 0 174 2.852 37 1.042 0.039 0.001 58.6 1.22 5.115 81.4 4.06 15 1.235 2.61 0.067 11.7 0.509 5.871 6.9% U5-1 D Groundwater 4/13/2016 0 0 48.8 0.8 4.8 0.135 0.012 0 49 1.02 1.955 27.7 1.382 0.969 0.08 10.1 0.258 9.38 0.408 2.128 4.2% U5 -1S Groundwater 4/13/2016 0 0 98.3 1.611 8.7 0.245 0 0 7.3 0.152 2.008 18.8 0.938 7.49 0.616 0 0 1.06 0.046 1.6 -11.3% U5-2BR Groundwater 3/3/2016 0 0 92.9 1.523 5.8 0.163 0 0 10 0.208 1.894 25.7 1.282 4.98 0.41 1 3.54 0.091 7 0.304 2.087 4.8% U5 -2D Groundwater 4/13/2016 0 0 273 1 4.475 6.4 0.18 0 0 92.8 1.931 6.586 87.8 4.379 24.6 2.025 11.6 0.297 5.13 0.223 6.924 2.5% U5 -3D Groundwater 4/13/2016 0 0 40.2 0.659 3.5 0.099 0.13 0.002 51.1 1.063 1.823 22 1.097 8.53 0.702 0 0 2.81 0.122 1.921 2.6% U5 -3S Groundwater 3/8/2016 0 0 39.8 0.652 3.5 0.099 0.094 0.002 55.5 1.155 1.908 23.7 1.182 8.94 0.736 0 0 2.94 0.128 2.046 3.5% U54BR Groundwater 4/13/2016 1060 35.333 0 0 8.8 0.248 0 0 133 2.768 38.349 136 6.783 0 0 460 11.765 268 11.652 30.2 -11.9% U54D Groundwater 4/13/2016 0 0 79.5 1.303 2.5 0.07 0.12 0.002 17.2 0.358 1.733 26.5 1.322 0.697 0.057 5.12 0.131 14.7 0.639 2.149 10.7% U54S Groundwater 4/13/2016 0 0 15.9 0.261 3.4 0.096 0.84 0.014 39.8 0.828 1.199 14 0.698 5.47 0.45 0 0 4.19 0.182 1.33 5.2% U5 -5D Groundwater 4/14/2016 0 0 69.1 1.133 4.9 0.138 0 0 379 7.888 9.159 104 5.187 17.6 1.449 10.6 0.271 13.1 0.57 7.477 -10.1% U5 -6D Groundwater 4/13/2016 0 0 0 0 5.4 0.152 0 0 195 4.058 4.21 33.7 1.681 14 1.152 6.68 0.171 5.03 0.219 3.223 -13.3% U5 -7D Groundwater 4/14/2016 0 0 138 2.262 5.7 0.161 0 0 243 5.057 7.48 97 4.838 1.56 0.128 41.4 1.059 38.9 1.691 7.716 1.6% U5 -8D Groundwater 4/13/2016 0 0 38.4 0.63 3.1 0.087 0.47 0.008 3.4 0.071 0.796 11 0.549 2.66 0.219 0 0 4.1 0.178 0.946 8.6% U5 -8S Groundwater 4/13/2016 0 0 143 2.344 4.3 0.121 0 0 51.4 1.07 3.535 59.8 2.983 7.38 0.607 4.11 0.105 2.46 0.107 3.802 3.6% S-1 AOW 4/19/2016 0 0 8.3 0.136 4.9 0.138 0.53 0.009 2.6 0.054 0.337 3.03 0.151 1.57 0.129 0 0 2.71 0.118 0.398 8.3% S-18 AOW 4/18/2016 0 0 63.3 1.038 4.1 0.115 0.032 0.001 307 6.389 7.543 96.8 4.828 35.1 2.889 5.66 0.145 6.28 0.273 8.135 3.8% S-19 AOW 4/18/2016 0 0 152 2.492 5.1 0.144 0.023 0 34.4 0.716 3.352 47.6 2.374 18.2 1.498 2.99 0.076 3.43 0.149 4.097 10.0% S -19A AOW 4/18/2016 0 0 179 2.934 4.9 0.138 0 0 105 2.185 5.257 75.9 3.786 28.8 2.37 2.86 0.073 4.06 0.177 6.406 9.9% S-22 AOW 4/19/2016 0 0 55 0.902 65.2 1.837 0 0 64.6 1.344 4.083 52.8 2.633 9.25 0.761 2.99 0.076 10.7 0.465 3.935 -1.8% S-4 AOW 4/18/2016 0 0 96.3 1.579 33.6 0.946 0 0 115 2.393 4.918 67.5 3.367 18.1 1.49 9.06 0.232 12.6 0.548 5.637 6.8% S-5 AOW 4/19/2016 0 0 4.8 0.079 9.6 0.27 0.49 0.008 26.7 0.556 0.913 5.94 0.296 4.41 0.363 3.1 0.079 5.26 0.229 0.967 2.9% S-6 AOW 4/19/2016 0 0 42.8 0.702 59.5 1.676 0.15 0.002 59.9 1.247 3.627 47.3 2.359 8.53 0.702 3.03 0.077 10.6 0.461 3.599 -0.4% S-7 AOW 4/19/2016 0 0 4.4 0.072 4.6 0.13 0.31 0.005 1.1 0.023 0.23 1.71 0.085 1.16 0.095 0 0 1.87 0.081 0.261 6.3% S-8 AOW 4/18/2016 0 0 10.7 0.175 2.8 0.079 0.52 0.008 1 0.021 0.283 2.95 0.147 1.06 0.087 0 0 2.95 0.128 0.362 12.2% AB -3S Porewater 4/13/2016 0 0 598 9.803 27.6 0.777 0 0 1060 22.06 32.64 491 24.489 88.2 7.259 17.2 0.44 24.8 1.078 33.266 0.9% AB-3SL Porewater 4/13/2016 0 0 24.4 0.4 36.6 1.031 0 0 76 1.582 3.013 39.9 1.99 1.33 0.109 11.2 0.286 12 0.522 2.907 -1.8% AB -4S Porewater 4/13/2016 0 0 27.6 0.452 94.7 2.668 0 0 84.4 1.757 4.877 74 3.691 5.36 0.441 6.96 0.178 12.6 0.548 4.858 -0.2% AB-4SL Porewater 4/13/2016 8.8 0.293 100 1.639 3.7 0.104 0 0 25.1 0.522 2.558 31.6 1.576 8.59 0.707 8.39 0.215 2.91 0.127 2.625 1.3% AB -5S Porewater 4/13/2016 0 0 104 1.705 47.1 1.327 0 0 111 2.31 5.342 77.4 3.86 14.5 1.193 8.69 0.222 10.9 0.474 5.749 3.7% AB -6S Porewater 4/13/2016 0 0 34.3 0.562 70 1.972 0.018 0 95.1 1.979 4.513 71.5 3.566 4.29 0.353 4.95 0.127 9.54 0.415 4.461 -0.6% AS -7S Porewater 4/14/2016 0 0 175 2.869 32.2 0.907 0 0 422 8.783 12.559 191 9.526 43.3 3.564 26.4 0.675 18.3 0.796 14.561 7.4% IBA S Porewater 4/15/2016 0 0 34.3 0.562 21.9 0.617 0 0 433 9.011 10.19 170 8.479 31.6 2.601 10.6 0.271 26 1.13 12.481 10.1% U5 -2S -SL -A Porewater 4/20/2016 0 0 208 3.41 8.5 0.239 0 0 128 2.664 6.313 67.3 3.357 38.4 3.16 13 0.332 4.1 0.178 7.027 5.4% U5 -7S Porewater 4/13/2016 0 0 95.8 1.57 4.6 0.13 0 0 28.9 0.601 2.301 35.8 1.786 8.48 0.698 7.18 0.184 3.4 0.148 2.816 10.1% U5-7SL Porewater 4/13/20161 0 1 0 1 24.3 1 0.398 1 4.9 0.138 0 0 267 5.557 6.093 63.3 3.157 17.8 1.465 12.8 0.327 6.56 0.285 1 5.234 -7.6% * NO2 + NO3 is being used as a surrogate for nitrate and the molecular weight of nitrate is assumed. ** GWA-31 BR not sampled for anions due to insufficient sample volume. Results of "0" are reported as non -detects by the analytical laboratory. Dataset consists of aqueous data associated with the first quarter of 2016 (even if dates do not align to traditional quarters). Formulas: Molecular Weight (mol) Result Value (ig) Cations (L ) - E Anions(L ) Equivalent Weight = eq/L= o Molecular Wr. g CBE/o = eq eq X 100 Charge r hnot)l E Cations )+ )+ E Anions( ) Charge J Cliffside Steam Station Page 4 of 4 CSA Supplement 2