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HomeMy WebLinkAboutNC0004979_2_FINAL_CSA Supplement 2_Allen_Tables_20160802Table 1-1: Well Construction Information Monitoring Well ID AB-10D Monitoring Well Type Deep Northing 524935.10 Easting 1400640.00 TOC Elevation Stick-up . 574.97 Casing 2.56 Casing Type PVC Casing Diameter 2.0 Top. Screen 62.56 Bottom Screen 67.56 Depth Program 67.56 NDPES AB-10S Shallow 524935.40 1400636.00 575.05 2.44 PVC 2.0 8.29 23.29 23.29 NDPES AB-11D Deep 523285.10 1399060.00 618.07 2.68 PVC 2.0 20.89 25.89 25.89 NDPES AB-12D Deep 524231.40 1396540.00 651.75 2.04 PVC 2.0 95.61 100.61 100.61 NDPES AB-12S Shallow 524228.90 1396539.00 651.69 2.05 PVC 2.0 12.68 27.68 27.68 NDPES AB-13D Deep 526169.10 1397489.00 648.54 2.65 PVC 2.0 72.50 77.50 77.50 NDPES AB-13S Shallow 526178.50 1397490.00 648.72 2.74 PVC 2.0 12.45 27.45 27.45 NDPES AB-14BR Bedrock 527214.02 1396717.34 642.20 3.30 PVC 6.0 93.30 98.30 133.30 CAMA AB-14D Deep 527206.50 1396717.00 641.80 2.44 PVC 2.0 29.33 34.33 34.33 NDPES AB-1R Deep 529135.90 1396854.00 675.86 2.29 PVC 2.0 65.47 75.47 75.47 NDPES AB-2 Shallow 527194.33 1397478.40 638.74 3.04 PVC 2.0 10.36 25.36 25.36 Voluntary AB-20D Deep 524964.84 1396758.69 649.27 2.70 PVC 6.0 127.70 132.70 143.70 CAMA AB-20S Shallow 524970.53 1396759.63 649.42 2.68 PVC 2.0 7.68 22.68 27.68 CAMA AB-21BR Bedrock 524738.89 1398290.74 647.68 3.02 PVC 6.0 166.02 171.02 195.02 CAMA AB-21D Deep 524739.11 1398296.52 647.57 2.87 PVC 5.0 145.87 150.87 153.87 CAMA AB-21S Shallow 524740.26 1398306.99 647.41 2.59 PVC 2.0 8.59 23.59 25.59 CAMA AB-21SL Shallow 524740.51 1398302.56 647.36 2.58 PVC 2.0 37.58 47.58 49.58 CAMA AB-22D Deep 524916.43 1400273.56 644.81 -0.30 PVC 5.0 159.70 164.70 171.70 CAMA AB-22S Shallow 524921.09 1400273.79 644.89 -0.27 PVC 2.0 84.73 99.73 99.73 CAMA AB-23BRU Deep 525580.33 1398488.24 646.47 2.87 PVC 6.0 121.07 126.07 131.87 CAMA AB-23S Shallow 525583.88 1398467.74 646.61 2.83 PVC 2.0 28.23 43.23 45.43 CAMA AB-24D Deep 526162.84 1398769.18 647.86 2.81 PVC 6.0 112.81 117.81 129.81 CAMA AB-24S Shallow 526175.48 1398769.28 647.86 2.97 PVC 2.0 7.97 22.97 24.97 CAMA AB-24SL Shallow 526169.17 1398769.43 647.92 2.90 PVC 2.0 28.40 38.40 39.90 CAMA AB-25BR Bedrock 526171.41 1399445.35 647.11 2.72 PVC 6.0 142.72 147.72 160.42 CAMA AB-25BRU Deep 526176.80 1399444.96 646.76 2.35 PVC 6.0 110.35 115.35 123.75 CAMA AB-25S Shallow 526187.94 1399446.45 647.22 2.76 PVC 2.0 7.76 22.76 22.76 CAMA AB-25SL Shallow 526182.95 1399446.13 646.97 2.52 PVC 2.0 32.52 47.52 52.02 CAMA AB-26D Deep 526169.32 1400299.86 643.42 -0.13 PVC 5.0 191.37 196.37 196.87 CAMA AB-26S Shallow 526162.31 1400297.16 643.32 -0.18 PVC 2.0 84.82 94.82 97.82 CAMA AB-27D Deep 526924.04 1399826.60 643.24 -0.30 PVC 5.0 110.20 115.20 120.20 CAMA AB-27S Shallow 526924.00 1399819.36 643.25 -0.28 PVC 2.0 7.72 22.72 24.72 CAMA AB-28D Deep 526856.21 1399114.72 644.17 -0.15 PVC 6.0 157.85 162.85 164.35 CAMA AB-28S Shallow 526855.23 1399109.48 644.19 -0.16 PVC 2.0 4.84 19.84 19.84 CAMA AB-29D Deep 527156.38 1399802.12 620.46 -0.13 PVC 6.0 112.37 117.37 124.87 CAMA AB-29S Shallow 527157.39 1399812.91 620.46 -0.14 PVC 2.0 4.86 19.86 21.86 CAMA AB-29SL Shallow 527157.06 1399807.64 620.45 -0.14 PVC 2.0 35.86 45.86 47.86 CAMA AB-2D Deep 527201.00 1397474.00 638.33 3.13 PVC 2.0 71.11 76.11 76.11 Voluntary AB-30D Deep 527093.69 1399073.65 621.38 -0.15 PVC 5.0 137.85 142.85 150.85 CAMA AB-30S Shallow 527093.94 1399081.26 621.21 -0.25 PVC 2.0 4.75 19.75 20.75 CAMA AB-31D Deep 527632.78 1400475.00 627.25 -0.18 PVC 6.0 130.82 135.82 144.82 CAMA AB-31S Shallow 527638.54 1400475.19 627.20 -0.20 PVC 2.0 57.80 72.80 74.80 CAMA AB-32D Deep 528139.15 1400491.68 624.40 -0.23 PVC 5.0 119.77 124.77 127.77 CAMA AB-32S Shallow 528145.19 1400492.08 624.34 -0.36 PVC 2.0 54.64 69.64 71.64 CAMA AB-33D Deep 528418.78 1399662.14 627.39 3.12 PVC 5.0 119.12 124.12 129.12 CAMA AB-33S Shallow 528412.71 1399660.97 627.00 3.04 PVC 2.0 23.04 38.04 43.04 CAMA AB-34D Deep 527985.77 1398800.76 632.93 -0.24 PVC 6.0 137.76 142.76 155.26 CAMA AB-34S Shallow 527978.64 1398800.46 632.88 -0.28 PVC 2.0 19.72 34.72 34.72 CAMA AB-35BR Bedrock 527568.09 1398178.34 664.54 2.81 PVC 6.0 184.81 189.81 208.81 CAMA AB-35D Deep 527569.06 1398169.55 664.55 2.90 PVC 5.0 149.90 159.90 173.40 CAMA AB-35S Shallow 527569.89 1398175.10 664.47 2.85 PVC 2.0 37.85 52.85 74.85 CAMA AB-36D Deep 527601.00 1397268.43 626.68 2.66 PVC 5.0 95.66 100.66 109.66 CAMA Allen Steam Station Page 1 of 3 CSA Supplement 2 Table 1-1: Well Construction Information Monitoring Well ID AB-36S AB-37D Monitoring Well Type Shallow Deep Northing 527599.84 527634.75 Easting 1397261.61 1396738.90 TOC Elevation Stick-up . 627.18 628.09 Casing 3.09 3.20 Casing Type PVC PVC Casing Diameter 2.0 6.0 Top. Screen 8.09 63.20 Bottom Screen 18.09 68.20 Depth 28.09 77.20 Program CAMA CAMA AB-37S Shallow 527637.90 1396742.38 628.01 3.13 PVC 2.0 6.18 21.18 23.13 CAMA AB-38D Deep 528656.29 1397550.45 634.41 3.09 PVC 6.0 70.79 75.79 78.59 CAMA AB-38S Shallow 528659.00 1397556.20 634.64 3.17 PVC 2.0 12.97 27.97 30.17 CAMA AB-39D Deep 528645.17 1398379.38 637.46 2.98 PVC 6.0 85.98 90.98 109.86 CAMA AB-39S Shallow 528645.78 1398373.98 637.47 3.05 PVC 2.0 33.05 48.05 53.05 CAMA AB-4BR Bedrock 525725.80 1396687.07 648.55 2.96 PVC 6.0 82.96 87.96 107.96 CAMA AB-4D Deep 525728.30 1396718.00 649.17 2.19 PVC 2.0 49.37 54.37 54.37 NDPES AB-4S Shallow 525732.00 1396724.00 650.46 2.52 PVC 2.0 12.42 27.42 27.42 NDPES AB-5 Shallow 524016.00 1397760.00 677.02 2.92 PVC 2.0 32.96 47.96 47.96 Voluntary AB-6A Shallow 524632.00 1400457.00 579.30 2.00 PVC 2.0 35.37 38.37 38.37 Voluntary AB-611 Shallow 524621.00 1400454.00 579.90 2.10 PVC 2.0 42.31 45.31 45.31 Voluntary AB-91) Deep 527134.60 1400632.00 582.72 2.35 PVC 2.0 114.93 119.93 119.93 NDPES AB-9S Shallow 527138.00 1400631.00 582.73 2.19 PVC 2.0 10.39 25.39 25.39 NDPES BG-1D Deep 523296.60 1396799.34 694.88 2.95 PVC 6.0 116.95 121.95 138.60 CAMA BG-1S Shallow 523301.49 1396799.30 695.13 2.75 PVC 2.0 51.75 66.75 68.25 CAMA BG-2BR Bedrock 528793.92 1395229.00 644.48 3.04 PVC 5.0 138.04 143.04 158.04 CAMA BG-2D Deep 528797.04 1395225.05 644.22 2.89 PVC 5.0 109.89 114.89 122.89 CAMA BG-2S BG-3D BG-3S Shallow Deep Shallow 528799.49 530292.81 530297.38 1395218.22 1395436.71 1395442.04 644.31 674.44 675.18 2.90 2.45 2.68 PVC PVC PVC 2.0 6.0 2.0 55.90 95.45 72.68 70.90 100.45 87.68 72.90 114.95 88.68 CAMA CAMA CAMA BG-4BR Bedrock 530970.57 1397618.52 662.08 3.27 PVC 6.0 163.07 168.07 174.27 CAMA BG-41) Deep 530963.41 1397612.39 661.62 2.79 PVC 6.0 108.79 113.79 120.79 CAMA BG-4S Shallow 530960.01 1397600.37 662.19 3.20 PVC 6.0 81.30 96.30 97.00 CAMA GWA-14D GWA-14S GWA-15D Deep Shallow Deep 526981.04 526979.86 527474.29 1396843.66 1396838.78 1396447.25 653.21 653.57 633.27 -0.30 -0.23 -0.22 PVC PVC PVC 6.0 2.0 6.0 108.70 18.77 84.28 113.70 33.77 89.28 139.40 34.77 94.78 CAMA CAMA CAMA GWA-15S Shallow 527479.25 1396447.37 632.71 -0.34 PVC 2.0 16.66 31.66 31.66 CAMA GWA-16D Deep 528364.68 1395091.10 656.06 3.49 PVC 6.0 101.49 111.49 118.49 CAMA GWA-16S Shallow 528357.41 1395090.95 656.59 3.22 PVC 2.0 48.22 63.22 63.22 CAMA GWA-17D Deep 529320.81 1396760.20 681.72 2.38 PVC 6.0 117.38 127.38 137.38 CAMA GWA-17S Shallow 529317.36 1396751.17 681.89 1.71 PVC 6.0 71.71 86.71 86.71 CAMA GWA-18D Deep 528931.76 1397095.96 651.14 2.54 PVC 6.0 89.54 94.54 102.54 CAMA GWA-185 Shallow 528920.85 1397095.74 651.04 2.66 PVC 6.0 57.66 72.66 73.66 CAMA GWA-19D Deep 527930.65 1395847.31 669.95 -0.27 PVC 6.0 124.93 129.93 134.73 CAMA GWA-19S Shallow 527926.76 1395859.19 669.85 -0.13 PVC 6.0 41.87 56.87 57.87 CAMA GWA-1BR Bedrock 523655.00 1399520.45 629.37 3.65 PVC 6.0 119.65 124.65 138.65 CAMA GWA-11) Deep 523653.02 1399504.38 629.38 2.85 PVC 5.0 80.85 85.85 92.85 CAMA GWA-1S Shallow 523653.79 1399508.75 629.27 2.74 PVC 2.0 7.74 22.74 23.74 CAMA GWA-21BR Bedrock 526327.23 1396469.18 671.74 -0.33 PVC 6.0 202.22 207.22 237.00 CAMA GWA-21D Deep 526312.61 1396471.87 671.31 -0.40 PVC 6.0 177.10 182.10 182.60 CAMA GWA-21S Shallow 526294.36 1396474.48 671.24 -0.12 PVC 6.0 23.32 38.32 40.12 CAMA GWA-22D Deep 526669.77 1397525.17 665.29 2.80 PVC 6.0 180.00 185.00 188.80 CAMA GWA-22S Shallow 526666.13 1397525.09 665.14 2.78 PVC 6.0 24.88 39.88 47.78 CAMA GWA-23D Deep 525594.85 1397398.72 669.26 2.88 PVC 6.0 79.88 84.88 85.88 CAMA GWA-23S Shallow 525605.71 1397401.93 670.09 3.05 PVC 6.0 23.05 38.05 40.55 CAMA GWA-24BR Bedrock 524969.35 1396115.76 675.45 -0.11 PVC 6.0 160.39 165.39 169.39 CAMA GWA-24D Deep 524991.19 1396116.20 675.48 -0.05 PVC 6.0 122.95 127.95 134.95 CAMA GWA-24S Shallow 524980.27 1396115.98 675.35 -0.33 PVC 2.0 22.17 37.17 38.67 CAMA GWA-26D Deep 523773.28 1396934.29 683.12 2.85 PVC 6.0 55.35 70.35 70.35 CAMA GWA-26S Shallow 523776.92 1396934.36 683.10 2.95 PVC 2.0 114.95 119.95 129.95 CAMA Allen Steam Station Page 2 of 3 CSA Supplement 2 Table 1-1: Well Construction Information Monitoring Well ID GWA-21) GWA-2S Monitoring Well Type Deep Shallow Northing 523815.05 523812.22 Easting 1400345.47 1400353.25 TOC Elevation Stick-up . 579.66 579.36 Casing 3.09 3.21 Casing Type PVC PVC Casing Diameter 5.0 2.0 Top. Screen 120.39 12.91 Bottom Screen 125.39 27.91 Depth 137.59 30.41 Program CAMA CAMA GWA-3BR Bedrock 526135.61 1400483.77 583.60 2.94 PVC 6.0 167.94 172.94 197.54 CAMA GWA-31) Deep 526121.37 1400483.88 580.30 -0.17 PVC 6.0 138.83 143.83 152.83 CAMA GWA-3S Shallow 526128.48 1400484.31 583.59 3.00 PVC 2.0 10.00 25.00 27.00 CAMA GWA-41) Deep 527595.45 1400641.07 580.30 -0.15 PVC 6.0 91.85 96.85 99.15 CAMA GWA-4S Shallow 527587.48 1400640.91 580.32 -0.22 PVC 2.0 3.78 18.78 20.02 CAMA GWA-5BR Bedrock 528156.95 1400653.57 581.17 -0.10 PVC 6.0 133.40 138.40 164.90 CAMA GWA-51) Deep 528173.28 1400654.34 581.02 -0.15 PVC 6.0 107.85 112.85 125.85 CAMA GWA-5S Shallow 528165.11 1400654.44 580.93 -0.37 PVC 2.0 8.63 23.63 25.63 CAMA GWA-6BR Bedrock 529035.85 1399117.10 628.14 -0.10 PVC 5.0 171.50 176.50 195.90 CAMA GWA-61) Deep 529039.97 1399093.63 628.55 -0.30 PVC 6.0 118.10 123.10 144.70 CAMA GWA-6D-A Deep 529014.07 1399138.73 630.16 2.67 PVC 6.0 121.67 126.67 127.70 CAMA GWA-6S Shallow 529041.79 1399102.80 628.35 -0.19 PVC 2.0 25.31 40.31 41.21 CAMA GWA-71) Deep 529487.89 1399021.00 594.27 2.58 PVC 6.0 134.58 139.58 148.38 CAMA GWA-7S Shallow 529478.47 1399022.18 595.05 2.65 PVC 2.0 17.65 32.65 33.65 CAMA GWA-81) Deep 529525.30 1397773.72 676.66 3.08 PVC 6.0 122.58 127.58 133.08 CAMA GWA-8S Shallow 529530.38 1397776.26 676.88 3.45 PVC 2.0 63.45 78.45 81.45 CAMA GWA-91) GWA-9S Deep Shallow 525022.91 525017.56 1396566.40 1396564.56 647.65 647.56 3.26 2.93 PVC PVC 6.0 2.0 111.26 8.93 116.26 23.93 123.26 26.93 CAMA CAMA Notes: 1. TOC indicates top of casing 2. TOC elevation based on NAVD 88 vertical datum 3. Northing and Easting based on NAD83 horizontal datum 4. ft indicates measurements in feet S. btoc indicates measurements below the top of casing 6. Deep and Bedrock CAMA wells installed with 2-inch riser; Casing value listed for D/BR wells indicates outer casing diameter. Allen Steam Station Page 3 of 3 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells Well ID MW-IS NCAC 2L Standard: Units: Sample Date 11/15/2006 NS NS °C mV Temperature • 16.95 NS 110/cm 409.4 NS 6.5 - 8.5 mg/L SU DO pH (Field) 7.3 500 mg/L TDS 270 10 mg/L Nitrate 0.77 250 mg/L Chloride 13.09 250 mg/L Sulfate 23.62 10 µg/L Arsenic <2 MW-1S 5/15/2007 16 399.7 6.77 380 0.52 10.9 27.3 <2 MW-IS 11/19/2007 17.66 - 418 6.87 289 0.41 12.53 33.67 <2 MW-1S 5/21/2008 15.6 - 401.6 6.81 160 0.67 13 32 <2 MW-IS 11/24/2008 15.6 -- 406 6.92 254 0.6 13 37 <2 MW-1S 5/12/2009 17.05 - 355 6.88 220 1.91 20 12 <1 MW-IS 11/2/2009 17.7 - 367 6.7 248 1.71 19 15 <1 MW-1S 5/25/2010 17.1 355 6.88 219 2.25 22 7.9 <1 MAD 11/15/2006 15.39 - 405.8 7.27 270 0.19 10.43 25.79 <2 MAD 5/15/2007 18.49 415.1 6.83 268 0.17 9.22 29.87 <2 MAD 11/19/2007 17.49 -- 417.7 6.81 258 0.09 10.66 36.99 <2 MAD 5/21/2008 16.21 415 6.88 160 0.15 11 36 <2 MAD 11/24/2008 15.1 -- 415 6.95 260 <0.23 11 40 <2 MAD 5/12/2009 16.9 405 6.93 248 0.43 13 28 <1 MAD MAD MW-2S MW-2S MW-2S MW-2S MW-2D 11/2/2009 5/25/2010 11/15/2006 5/16/2007 11/19/2007 5/21/2008 11/15/2006 16.04 - 16.49 15 - 15.6 14.65 - 15.6 14.89 - 399 388 250.1 253.6 263 248.3 199.1 6.68 6.83 6.02 5.47 5.88 5.620 6.6 254 208 160 184 154 160 160 0.54 1.06 <0.02 0.02 <0.02 <0.02 0.53 13 15 7.67 8.86 6.99 9.1 5.28 28 19 85.69 94.76 94.63 84 37.63 <1 <1 <2 <2 <2 <2 <2 MW-2D 5/16/2007 15.85 188.4 6.12 MW-2D 11/19/2007 14.99 - 227.4 6.21 MW-2D 5/21/2008 15.41 219 6.22 MW-3S 11/15/2006 16.34 - 222.5 5.49 MW-3S 5/15/2007 14.63 230.3 5.4 MW-3S 11/19/2007 17.04 - 222.1 5.37 MW-3S 5/21/2008 15.03 214.7 5.45 MW-3S 11/24/2008 15.92 - 198.5 5.66 MW-3S 5/12/2009 15.27 199.4 5.63 MW-3S 11/2/2009 17.86 - 197.8 5.54 MW-3S 5/25/2010 16.05 - 197.2 5.5 MW-3D 11/15/2006 15.45 - 377.3 6.14 MW-3D 5/15/2007 16.11 367.5 6.12 MW-3D 11/19/2007 15.82 - 367.3 5.99 MW-3D 5/21/2008 16.21 358.4 6.12 MW-3D 11/24/2008 15.07 - 343.1 6.28 MW-3D 5/12/2009 16.62 339.3 6.27 MW-3D 11/2/2009 16.4 - 333.5 6.15 MW-3D 5/25/2010 16.88 324 6.1 MW-4S 11/14/2006 17.56 - 189.5 6.27 MW-4S 5/15/2007 16.94 182.3 6.16 MW-4S 11/19/2007 18.02 - 184.3 6.09 MW-4S 5/21/2008 15.48 186.9 6.1 MW-4S 11/24/2008 15.27 - 180.5 6.22 MW-4S 5/12/2009 15.11 184.3 6.23 MW-4S 11/2/2009 16.94 - 189.6 6.15 MW-4S 5/25/2010 15.93 189.2 6.09 MW-4D 11/14/2006 16.64 - 199.5 6.15 MW-4D 5/15/2007 16.97 196.4 6.03 MW-4D 11/19/2007 17.04 - 194.1 5.93 MW-4D 5/21/2008 15.96 - 198.5 5.93 MW-4D 11/24/2008 15.21 -- 188.2 6.14 MW-4D 5/12/2009 15.7 - 195.7 6.09 MW-4D 11/2/2009 16.15 -- 194.4 6.06 MW-4D 5/25/2010 16.36 - 195.4 6 168 0.45 4.78 33.92 <2 165 0.35 4.51 53.98 <2 38 0.39 5.6 51 <2 130 <0.02 10.8 64.93 <2 152 <0.02 9.18 71.71 <2 114 <0.02 10.6 65.83 <2 66 <0.02 10 61 <2 114 <0.23 10 57 <2 108 0.04 10 55 <1 130 <0.02 9.8 52 <1 86 <0.02 9.4 53 <1 250 <0.02 9.09 106.07 <2 268 <0.02 7.99 114 <2 237 <0.02 8.99 105.48 <2 i 110 <0.02 8.6 100 <2 220 <0.23 9 94 <2 202 <0.02 9.5 88 <1 224 <0.02 9 81 <1 187 <0.02 9.1 81 <1 110 <0.02 8.22 25.35 <2 152 <0.02 7.91 24.37 <2 87 <0.02 7.62 23.57 <2 140 <0.02 8 22 <2 48 <0.23 8.3 23 <2 94 0.03 9 23 <1 88 0.03 10 23 <1 87 <0.02 8.5 22 <1 140 <0.02 8.15 30.41 <2 158 <0.02 7.64 30.4 <2 118 <0.02 6.39 30.41 <2 14 <0.02 5.8 28 <2 72 <0.23 6.4 29 <2 114 <0.02 8.5 29 <1 150 <0.02 8.4 28 <1 124 <0.02 8.9 28 <1 Page 1 of 18 Buck Steam Station CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells NCAC 2L Standard: Units: NS °C Well ID MW-5S Sample Date 11/15/2006 Temperature 15.88 MW-5S 5/16/2007 16.13 MW-5S 11/20/2007 15.44 MW-5S 5/21/2008 16.97 MW-5S 11/24/2008 15.82 MW-5S 5/12/2009 15.93 MW-5S 11/2/2009 16.35 MW-5S 5/25/2010 16.9 MW-5D 11/15/2006 15.98 MW-5D 5/16/2007 16.36 MW-SD 11/20/2007 15.59 MW-5D 5/21/2008 16.92 MW-5D 11/24/2008 15.86 MW-5D 5/12/2009 16.11 MW-SD 11/2/2009 16.32 MW-5D 5/25/2010 17.13 MW-6S 11/14/2006 15.37 MW-6S 5/15/2007 14.69 MW-6S 11/20/2007 14.13 MW-6S 5/21/2008 15.88 MW-6S 11/24/2008 13.56 MW-6S 5/12/2009 14.48 MW-6S 11/2/2009 14.64 MW-6S 5/25/2010 15.6 MW-65 3/7/2011 15.6 MW-6S 7/5/2011 15.87 MW-6S 11/2/2011 14.46 MW-6S 3/7/2012 15.65 MW-6S 7/3/2012 16.27 MW-6S 11/7/2012 14.58 MW-6S 3/6/2013 15.09 MW-6S 7/8/2013 16.24 MW-6S 11/4/2013 14.97 MW-6S 3/3/2014 15.38 MW-65 7/1/2014 15.79 MW-6S 11/3/2014 14.82 MW-65 3/4/2015 15.43 MW-6S 7/6/2015 15.95 MW-65 11/3/2015 15.52 MW-6S 3/1/2016 15.77 MW-6D 11/14/2006 15.86 MW-6D 5/15/2007 16.32 MW-6D 11/20/2007 14.27 MW-6D 5/21/2008 16.14 MW-6D 11/24/2008 14.05 MW-6D 5/12/2009 15.15 MW-6D 11/2/2009 15.01 MW-6D 5/25/2010 15.93 MW-6D 3/7/2011 15.21 MW-6D 7/5/2011 16.48 MW-6D 11/2/2011 14.32 MW-6D 3/7/2012 15.32 MW-6D 7/3/2012 15.99 MW-6D 11/7/2012 14.99 MW-6D 3/6/2013 14.5 MW-6D 7/8/2013 16.32 NS NS NS mV ORP go/cm SpecificDo mg/L -- 148.9 143.7 - 157.1 158.1 - 157.3 159.5 - 157.4 - - - 152.8 196.2 193.4 190.4 188.7 180 - 191 -- 191.1 - 195.4 -- 43.1 - 39.2 -- 41.7 - 42.7 - 36 - 42 - 40 - 51 - 43 - 48 -- 46 -- 408 53 0.43 362 52 0.43 432 48 0.12 378 52 0.56 273 54 0.2 354 50 0.1 364 49 1.24 483 45 0.69 523 46 1.44 409 51 2.02 377 55 1.3 385 53 1.58 385 62 3.19 -- 72.8 -- - 74.3 -- 83 - 90.3 -- 94 - 112 -- 112 - 125 -- 123 - 127 -- 125 -- 365 133 2.45 334 133 2.39 393 133 2.29 315 138 2.36 230 144 2.4 6.5 - 8.5 500 10 250 250 10 SU I -I (Field) ®5.8 mg/L TDS mg/L Nitrate mg/L Chloride mg/L Sulfate µg/L Arsenic 9111 90 0.04 7.67 28.9 <2 5.84 106 0.16 7.97 30.57 <2 5.81 I 73 <0.02 8.73 31.64 <2 5.77 94 0.34 9.6 32 <2 5.9 I 40 <0.23 8.2 35 <2 5.88 54 0.14 9 36 <1 5.82 110 0.05 8.8 35 <1 5.75 66 0.1 9.5 36 <1 6.04 I 130 0.02 9.12 25.49 <2 6.12 168 0.02 8.3 25.11 <2 6.13 I 113 <0.02 9.43 23.66 <2 6.02 130 0.02 9.3 23 <2 6.13 I 68 <0.23 8.6 21 <2 6.08 134 <0.02 9.4 21 <1 6 I 142 0.02 9.1 22 <1 5.96 113 <0.02 9.5 22 <1 5.76 I 24 0.33 4.13 0.18 <2 5.28 36 0.3 4.23 0.23 <2 5.48 55 0.36 3.81 0.2 <2 5.42 <10 0.39 4.5 0.18 <2 5.29 I <20 0.26 3.5 <1 <2 5.4 24 0.21 4.3 0.3 <1 5.32 I <20 0.2 4.2 0.18 <1 5.3 <25 <0.02 4.7 <0.1 <1 5.54 I 32 <0.1 4.9 0.19 <1 5.09 39 0.23 4.7 0.19 <1 5.41 I 21 0.19 4.8 0.26 <1 5.26 33 0.5 4.5 0.18 <1 4.48 I <250 0.49 4 0.2 <1 5.24 38 0.38 4.2 0.2 <1 5.13 I 47 0.4 4.6 0.21 <1 5.07 63 0.53 4.6 0.25 <1 5.19 I 50 0.54 4.6 0.24 <1 5.12 36 0.51 4.7 0.16 <1 5.23 I 32 0.3 4.7 0.14 <1 5.27 39 0.43 4.8 0.14 <1 5.24 I 36 0.51 4.9 0.15 <1 5.28 38 0.27 4.4 0.15 <1 5.36 35 0.45 4.7 0.17 <1 5.12 � 48 0.07 4.4 0.15 <1 7.05 68 0.68 1.21 1.3 <2 6.94 102 0.66 1.32 1.31 <2 6.98 48 0.64 1.63 1.43 <2 6.9 73 0.58 2 1.3 <2 6.8 50 0.52 1.7 1.3 <2 6.84 62 0.54 2.3 1.2 <1 6.67 78 0.51 2.1 1.2 <1 6.73 94 0.52 2.2 1.1 <1 6.98 100 0.55 2.5 1.3 <1 6.63 97 0.56 2.7 1.4 <1 6.83 93 0.53 2.6 1.2 <1 6.8 106 0.54 2.6 1.3 <1 <250 0.53 2.5 1.5 <1 6.69 110 0.49 2.7 1.4 <1 6.58 120 0.49 2.8 1.4 <1 6.55 140 0.51 2.8 1.6 <1 Page 2 of 18 Buck Steam Station CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells NCAC 2L Standard: NS NS NS NS 6.5 - 8.5 500 10 250 250 10 Units: °C mV go/cm mg/L SU mg/L mg/L mg/L mg/L µg/L Well ID Sample Date Temperature ORP SpecificDO pH (Field) TDS Nitrate Chloride Sulfate Arsenic MW-6D 11/4/2013 14.85 291 146 1.95 6.6 120 0.48 3 1.5 <1 MW-6D 3/3/2014 14.97 273 144 2.12 6.58 120 0.52 4.3 0.17 <1 MW-6D 7/1/2014 16.43 449 150 1.91 6.69 110 0.48 3.2 1.8 <1 MW-6D 11/3/2014 15.16 479 145 2.11 6.67 110 0.5 3 1.7 <1 MW-6D 3/4/2015 15.2 327 145 2.02 6.69 120 0.48 3 1.7 <1 MW-6D 7/6/2015 15.85 324 147 2.03 6.74 120 0.48 3 1.7 <1 MW-6D 11/3/2015 15.56 335 145 2 6.8 100 0.46 3 1.6 <1 MW-6D 3/1/2016 14.96 505 151 0 6.59 110 0.48 3.2 2 <1 MW-75 3/8/2011 13.21 -- 106 -- 95 0.14 5.6 3.4 <1 MW-7S 7/5/2011 15.84 - 102 5.88 96 0.17 5.8 1.8 <1 MW-7S 11/2/2011 15.78 -- 102 -- 6.18 I 110 0.15 9.6 2.4 <1 MW-7S 3/7/2012 14.35 416 100 2.48 5.82 93 0.15 6.3 1.3 <1 MW-7S 7/3/2012 16.24 371 100 2.02 5.93 I <250 0.15 5.5 0.94 <1 MW-7S 11/7/2012 15.98 428 101 1.54 5.86 96 0.09 9 2.4 <1 MW-7S 3/6/2013 14.88 359 98 1.98 5.78 I 100 0.11 7 2.4 <1 MW-7S 7/8/2013 15.81 260 95 1.48 5.8 120 0.12 6.4 1.5 <1 MW-7S 11/4/2013 16.42 319 99 1.38 5.84 I 120 0.14 5.8 0.85 <1 MW-7S 3/3/2014 14.51 318 97 1.82 5.76 98 0.16 7.8 0.85 <1 MW-7S 7/1/2014 15.27 420 106 1.19 5.76 I 95 0.12 8.9 0.88 <1 MW-7S 11/3/2014 15.76 386 102 1.08 5.83 95 0.14 6.4 0.7 <1 MW-7S 3/4/2015 14.56 374 94 3.02 5.85 I 89 0.23 7.3 1.2 <1 MW-7S 7/6/2015 15.06 358 101 2.13 5.93 97 0.13 5.7 0.55 <1 MW-75 11/3/2015 16.21 346 117 2.3 5.95 100 0.61 13 1 <1 MW-7S 3/1/2016 14.7 498 86 1.04 5.67 83 0.3 6.6 0.81 <1 MW-7D 3/8/2011 14.8 -- 248 -- 7.16 170 0.32 3.7 32 <1 MW-7D 7/5/2011 17 - 184 6.9 130 0.33 4.8 14 <1 MW-7D 11/2/2011 15.17 -- 168 -- 7.19 160 0.44 2.5 5 <1 MW-7D 3/7/2012 14.95 283 155 1.56 6.85 110 0.37 6.6 8.1 <1 MW-7D 7/3/2012 15.71 316 161 1.94 6.88 <250 0.49 3.6 4.3 <1 MW-7D 11/7/2012 15.22 403 158 2.09 6.82 150 0.48 2.4 2.5 <1 MW-7D 3/6/2013 14.06 323 131 1.61 100 0.06 7.4 8.8 <1 MW-7D 7/8/2013 16.26 147 148 0.88 6.52 130 0.02 8.3 8.6 <1 MW-7D 11/4/2013 15.71 300 152 2.22 6.76 120 0.53 2.6 2.1 <1 MW-7D 3/3/2014 14.8 270 151 0.59 110 0.05 7.9 6.7 <1 MW-7D 7/1/2014 15.79 340 137 1.91 110 0.44 4.3 2.7 <1 MW-7D 11/3/2014 15.16 372 145 1.59 6.52 MW-7D 3/4/2015 14.83 324 110 3.53 6.67 MW-7D 7/6/2015 15.7 325 148 2.46 6.71 MW-7D 11/3/2015 15.66 303 155 1.06 6.76 MW-7D 3/1/2016 15.09 486 143 0.41 6.67 MW-8S 3/7/2011 13.85 -- 214 -- 6.05 MW-8S 7/5/2011 17.21 - 128 6.13 MW-8S 11/2/2011 17.53 -- 154 -- 6.11 MW-8S 3/7/2012 13.99 359 204 1.15 6.25 MW-8S 7/3/2012 16.5 334 164 1.31 6.19 MW-8S 11/7/2012 16.72 355 160 1.7 6.25 MW-8S 3/6/2013 10.46 350 180 4.36 6.01 MW-8S 7/8/2013 20.17 311 152 3.82 6.19 MW-85 11/4/2013 10.91 318 142 4.63 6.25 MW-8S 3/3/2014 11.33 347 140 3.76 6.03 MW-85 7/1/2014 15.18 346 148 3.18 6.04 MW-8S 11/3/2014 15.51 389 143 3.81 6.29 MW-85 3/4/2015 13.45 372 235 2.08 5.96 MW-8S 7/6/2015 14.61 381 235 1.52 6.07 MW-85 11/3/2015 16.48 363 164 2.92 6.18 MW-8S 3/2/2016 13.5 448 174 2.29 6.13 110 0.5 3.4 2.3 <1 80 0.49 7.8 12 <1 120 0.59 2.2 1.6 <1 110 0.67 3.1 6.5 <1 100 0.71 3.5 2.5 <1 150 0.71 3.7 12 <1 120 1.2 3.2 3.7 <1 150 1.1 3.2 3.2 <1 134 0.69 3.4 4.8 <1 <250 1.1 2.6 3 <1 140 1.1 2.9 2.7 <1 150 1.2 3.3 7 <1 150 1.5 2.9 3.7 <1 130 1.6 2.9 1.7 <1 130 1.5 3 2.9 <1 130 1.4 3.2 2 <1 120 170 1.5 0.78 3.1 3.7 2.6 7.5 <1 <1 170 0.71 3.9 4.1 <1 130 1.2 3.3 2.4 <1 150 1.1 3.7 3.5 <1 Page 3 of 18 Buck Steam Station CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells NCAC 2L Standard: Units: NS °C Well ID MW-8D Sample Date 3/7/2011 Temperaturg, 14.92 MW-8D 7/5/2011 17.95 MW-8D 11/2/2011 16.12 MW-8D 3/7/2012 14.61 MW-8D 7/3/2012 15.64 MW-8D 11/7/2012 15.39 MW-8D 3/6/2013 12.7 MW-8D 7/8/2013 16.74 MW-8D 11/4/2013 14.59 MW-8D 3/3/2014 13.68 MW-8D 7/1/2014 16.09 MW-8D 11/3/2014 14.96 MW-8D 3/4/2015 14.62 MW-8D 7/6/2015 15.31 MW-8D 11/3/2015 15.32 MW-8D 3/2/2016 14.57 MW-9S 3/7/2011 13 MW-9S 7/5/2011 18.99 MW-9S 11/2/2011 19.67 MW-9S 3/7/2012 14.33 MW-95 7/3/2012 18.36 MW-9S 11/7/2012 17.89 MW-9S 3/7/2013 12.58 MW-9S 7/9/2013 18.27 MW-9S 11/5/2013 17.74 MW-9S 3/4/2014 12.11 MW-9S 7/1/2014 17.01 MW-9S 11/3/2014 18.05 MW-9S 3/4/2015 12.38 MW-9S 7/6/2015 17.44 MW-9S 11/3/2015 18.28 MW-9S 3/1/2016 14.13 MW-9D 3/7/2011 14.94 MW-9D 7/5/2011 18.61 MW-9D 11/2/2011 16.77 MW-9D 3/7/2012 16.23 MW-9D 7/3/2012 17 MW-9D 11/7/2012 16.13 MW-9D 3/7/2013 15.64 MW-9D 7/9/2013 16.38 MW-9D 11/5/2013 16.1 MW-9D 3/4/2014 15.58 MW-9D 7/1/2014 16.11 MW-9D 11/3/2014 16.04 MW-9D 3/4/2015 15.61 MW-9D 7/6/2015 15.77 MW-9D 11/3/2015 16.17 MW-9D 3/1/2016 15.99 MW-10D 3/8/2011 15.27 MW-10D 7/5/2011 17.71 MW-10D 11/2/2011 15.22 MW-10D 3/7/2012 15.92 MW-10D 7/3/2012 16.61 MW-10D 11/7/2012 15.38 MW-10D 3/6/2013 15.48 MW-10D 7/8/2013 16.03 NS NS NS mV ORP go/cm SpecificDO mg/L -- 139 - 129 -- 128 -- 366 128 4.09 334 126 4.14 347 126 4.16 339 127 5.02 322 128 4.08 315 127 4.2 338 131 4.48 338 127 4.59 380 130 4.28 365 130 4.33 363 127 4.48 372 128 4.38 430 132 4.05 -- 171 -- - 177 -- 175 -- 406 179 1.92 365 184 3.86 476 190 1.9 348 194 4.99 356 209 1.13 329 218 3.67 348 218 3.8 516 226 3.68 495 246 3.84 353 249 3.86 366 262 3.55 358 275 2.64 521 257 0.89 -- 187 -- - 182 -- 183 -- 398 186 2.01 368 183 1.87 467 185 2.08 346 193 1.91 356 198 1.96 324 203 1.91 345 213 2.01 509 218 1.9 537 227 1.78 346 243 1.65 365 249 1.93 357 253 1.62 520 257 0.32 -- 763 -- - 738 -- 747 -- 380 753 1.67 327 756 1.65 453 741 1.87 336 782 1.75 W 328 793 1.93 h 6.5 - 8.5 500 10 250 SU mg/L mg/L mg/L 250 10 6.43 9111 6.33 120 100 2.2 2.1 3.3 3.3 5.9 2.9 <1 <1 6.3 I 130 2.1 3.4 2.4 <1 6.52 123 2.1 3.2 2.4 <1 6.36 6.33 6.17 6.21 6.32 6.19 6.16 6.38 6.25 6.32 6.34 6.33 <250 2.2 3 2.1 <1 120 2.1 3.2 2 <1 120 2.1 3.2 2.1 <1 130 2.2 3.4 2.1 <1 120 2.1 3.2 1.8 <1 110 2.2 3.3 2.1 <1 120 2.2 3.4 2 <1 110 2.3 3.4 2 <1 110 2.1 3.3 1.9 <1 120 2.2 3.3 1.8 <1 100 2.1 3.4 1.9 <1 120 2.1 3.4 2.1 <1 6.54 150 0.16 6.2 10 <1 6.25 150 0.15 6.1 11 <1 6.62 170 0.17 6.6 10 <1 6.47 5.32 6.11 6.03 6.04 6.1 5.78 6.23 6.23 6.11 6.13 6.23 5.95 6.46 6.23 6.48 6.46 5.22 6.19 6.1 6.14 6.13 5.93 6.23 6.23 6.17 6.22 6.32 137 0.13 5.8 13 <1 <250 0.19 5.2 15 <1 150 0.19 6.2 14 <1 170 0.19 6.2 18 <1 190 0.27 7.3 25 <1 180 0.37 6.8 26 <1 180 0.41 6 30 <1 190 0.55 6.7 33 <1 190 0.59 7.4 37 <1 180 0.44 7.1 38 <1 210 0.43 7.3 42 <1 200 0.47 7.8 43 <1 190 0.38 6.4 42 <1 160 0.19 6.4 10 <1 140 0.19 6.3 8.8 <1 170 0.17 6.6 9.2 <1 157 0.17 6.4 9.1 <1 <250 0.17 5.6 9.3 <1 160 0.14 6.5 10 <1 170 0.17 6.7 13 <1 170 0.17 6.9 15 <1 170 0.19 7 16 <1 180 0.25 6.9 22 <1 180 0.26 7.3 26 <1 170 0.25 7.4 27 <1 180 0.28 7.6 34 <1 200 0.27 7.5 36 <1 180 0.29 8 37 <1 6.06 200 0.34 7.8 40 <1 6.33 0.88 6.8 1111116 3& <1 5.98 490 1 6.5 320 <1 6.17 600 0.9 6.5 i350 <1 6.12 561 0.98 5.9 330 <1 5.85 604 1 5.2 340 <1 5.81 580 0.87 5.5 340 <1 5.52 630 0.93 5.5 �&50 <1 5.74 660 I 1 5.7 �380 <1 Buck Steam Station Page 4 of 18 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells NCAC 2L Standard: NS NS NS NS 6.5 - 8.5 500 10 250 250 Units: .0 mV go/cm mg/L SU mg/L mg/L mg/L mg/I Well ID Sample Date Temperature ORP SpecificDO MMEW C. TDS Nitrate MW-10D 11/5/2013 15.43 348 802 2.09 5' � 01.1 5.4, MW-10D 3/4/2014 15.16 381 805 2.08 5.53 640 1.2 5.5 360 MW-10D 7/1/2014 16.1 377 799 2.22 5.8 650 1.3 5.5 390 MW-10D 11/3/2014 15.38 464 812 2.25 5.84 630 1.3 5.5 390 MW-10D 3/4/2015 15.46 368 829 2.07 5.75 650 1.1 5.3 1&6 390 MW-10D 7/10/2015 15.95 385 844 2.39 5.74 700 1.1 5.3 400 MW-10D 11/3/2015 15.73 366 839 2.04 5.88 660 A 0.95 5.6 390 MW-10D 3/2/2016 14.99 471 844 1.85 5.44 670 in 1.3 5.7 380 MW-11S 3/7/2011 13 97 -- 193 -- 6 22 120 <0 1 11 23 MW-11S 7/5/2011 16.33 - 189 6.03 MW-11S 11/2/2011 15.8 -- 190 -- 6.16 MW-11S 3/7/2012 15.42 405 192 0.59 6.16 MW-11S 7/3/2012 16.21 324 180 0.37 5.97 MW-11S 11/7/2012 16.1 351 184 0.42 6.27 MW-11S 3/7/2013 13.98 345 185 0.78 5.86 MW-11S 7/9/2013 16.29 338 192 0.6 5.87 MW-11S 11/5/2013 16.35 328 200 0.43 5.83 MW-11S 3/4/2014 14.24 317 204 0.41 5.85 MW-11S 7/1/2014 16.48 310 208 0.45 5.96 MW-11S 11/3/2014 16.85 337 218 0.46 6.19 MW-11S 3/4/2015 14.76 381 226 0.64 6.04 MW-11S 7/6/2015 15.69 363 240 0.57 6.13 MW-11S 11/3/2015 17.25 388 246 0.74 6.11 MW-11S 3/2/2016 14.39 409 254 0 6.13 MW-11D 3/7/2011 15.52 -- 177 -- 5.91 MW-11D 7/5/2011 16.57 - 178 5.79 MW-11D 11/2/2011 15.32 -- 177 -- 5.94 MW-11D 3/7/2012 16.39 404 175 0.5 6 MW-11D 7/3/2012 16.79 364 171 0.29 5.74 MW-11D 11/7/2012 15.29 373 172 0.72 6.01 MW-11D 3/7/2013 14.26 359 174 1.81 5.76 MW-11D 7/9/2013 17.07 353 176 0.36 5.7 MW-11D 11/5/2013 10.04 355 185 2.08 5.45 MW-11D 3/4/2014 12.41 338 170 0.45 5.72 MW-11D 7/1/2014 18.93 331 175 0.4 5.82 MW-11D 11/3/2014 16.07 365 175 0.27 5.94 MW-11D 3/4/2015 16.17 389 172 0.23 5.86 MW-11D 7/6/2015 16.21 378 176 0.26 5.95 MW-11D 11/3/2015 16.26 403 200 0.42 5.9 MW-11D 3/2/2016 16.17 417 170 0 5.98 MW-12S 3/8/2011 13.8 -- 116 -- 6.12 MW-12S 7/5/2011 15.81 - 92 6.02 MW-12S 11/2/2011 15.99 -- 95 -- 6.3 MW-12S 3/7/2012 14.8 397 86 4.18 6.21 MW-12S 7/3/2012 16.22 367 75 4.55 5.97 MW-12S 11/7/2012 16.25 335 78 3.97 6.24 MW-12S 3/7/2013 12.26 351 91 3.58 5.85 MW-12S 7/9/2013 16.3 362 79 3.53 5.85 MW-12S 11/4/2013 16.36 327 80 3.28 5.96 MW-12S 3/4/2014 12.04 351 73 5.14 5.86 MW-12S 7/1/2014 15.13 346 71 5.38 5.94 MW-12S 11/3/2014 16.07 353 72 4.98 6.12 MW-12S 3/4/2015 13.79 384 71 5.2 6 MW-12S 7/6/2015 14.61 352 67 6.08 6.14 MW-12S 11/3/2015 16.33 366 71 4.87 6.09 MW-12S 3/1/2016 14.4 453 68 5.75 5.97 10 u 120 <0.023 11 22 <1 130 <0.023 10 22 <1 122 <0.02 8 17 <1 <250 <0.023 9.2 20 <1 120 <0.023 9.3 20 <1 130 <0.023 9.7 20 <1 140 <0.023 11 22 <1 130 <0.023 12 21 <1 150 <0.023 14 21 <1 130 <0.023 15 23 <1 140 <0.023 17 24 <1 140 <0.023 19 25 <1 160 <0.023 20 29 <1 140 <0.023 21 29 <1 160 <0.023 25 31 <1 140 <0.1 9.4 3.6 <1 160 <0.023 10 39 <1 160 <0.023 10 36 <1 151 0.04 10 34 <1 <250 <0.023 9.5 35 <1 190 <0.023 9.6 33 <1 240 0.03 10 33 <1 170 <0.023 10 35 <1 180 <0.023 9.6 33 <1 160 <0.023 10 32 <1 180 <0.023 10 34 1.2 150 <0.023 10 33 <1 130 0.02 10 30 <1 140 <0.023 10 33 <1 140 0.04 15 35 <1 140 <0.023 12 31 <1 110 0.62 4.2 15 <1 87 0.63 3.6 4 <1 110 0.59 2.6 5.1 <1 98 0.71 3.4 1.4 <1 <250 0.76 2.2 0.66 <1 94 0.66 2.4 0.68 <1 100 0.36 6.5 2.4 <1 110 0.7 3.7 0.58 <1 110 0.7 4 0.5 <1 95 0.77 3 0.38 <1 89 0.83 2.5 0.18 <1 94 0.78 2.7 0.31 <1 82 0.74 2.7 0.28 <1 95 0.82 2.4 0.2 <1 89 0.76 2.6 0.42 <1 92 0.77 2.7 0.28 <1 Page 5 of 18 Buck Steam Station CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells NCAC 2L Standard: NS NS NS NS 6.5 - 8.5 500 10 250 250 Units: °C mV go/cm mg/L SU mg/L mg/L mg/L mg/L Well ID Sample Date Temperature ORP Specific Conductivity D• MW-12D 3/8/2011 15.03 -- 73 81 0.91 2.2 1.9 MW-12D 7/5/2011 16.2 - 67 6.17 80 0.93 2.3 1.1 MW-12D 11/2/2011 15.29 -- 69 -- 6.32 76 0.89 2.2 1.1 MW-12D 3/7/2012 15.47 401 67 6.84 6.25 85 0.89 2.1 0.62 MW-12D 7/3/2012 15.71 362 64 6.69 6.06 1 <250 0.9 1.9 0.48 MW-12D 11/7/2012 15.47 361 66 6.72 6.35 82 0.86 2.1 0.46 MW-12D 3/7/2013 15.39 338 67 6.7 5.89 I 74 0.88 2.1 0.39 MW-12D 7/9/2013 15.75 389 66 6.67 6.01 90 0.89 2.2 0.38 MW-12D 11/4/2013 15.61 333 66 6.51 6.15 I 83 0.86 2.1 0.35 MW-12D 3/4/2014 15.04 350 66 6.7 6.02 79 0.87 2.2 0.3 MW-12D 7/1/2014 15.59 349 66 6.77 6.07 I 79 0.89 2.2 0.3 MW-12D 11/3/2014 15.43 363 66 6.71 6.23 75 0.89 2.2 0.31 MW-12D 3/4/2015 15.21 395 67 6.77 6.14 I 72 0.87 2.2 0.31 MW-12D 7/6/2015 15.45 383 67 6.81 6.28 82 0.88 2.2 0.28 MW-12D 11/3/2015 15.44 377 67 6.8 6.22 I 75 0.88 2.2 0.33 MW-12D 3/1/2016 15.17 452 66 6.95 6.17 71 0.87 2.2 0.28 MW-13D 3/8/2011 14.58 -- 154 -- 6.21 130 2.1 6 3.2 MW-13D 7/5/2011 16.23 - 156 6.23 1 140 2.5 6 2.5 MW-13D 11/2/2011 15.17 -- 146 -- 6.35 1 140 2 6.1 2.2 MW-13D 3/7/2012 15.63 411 140 4.44 6.38 l 126 1.9 5.8 2.1 MW-13D 7/3/2012 15.45 425 148 3.79 6.15 1 <250 2.5 5.1 2.2 MW-13D 11/7/2012 15.24 360 143 3.84 6.33 130 2 5.6 2.1 MW-13D 3/6/2013 14.09 349 138 5 6.14 140 1.9 5.9 2 MW-13D 7/8/2013 16.67 301 147 4.05 6.2 MW-13D 11/4/2013 14.7 316 152 4.98 6.25 MW-13D 3/3/2014 11.36 343 141 4.84 6.15 MW-13D 7/1/2014 15.03 330 160 3.75 6.17 MW-13D 11/3/2014 14.85 371 161 3.95 6.3 MW-13D 3/4/2015 15.03 369 143 3.96 6.2 MW-13D 7/6/2015 14.81 358 156 3.89 6.32 MW-13D 11/3/2015 15.02 370 145 3.93 6.29 MW-13D 3/1/2016 15.05 418 139 4.11 6.22 10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 150 2.2 5 2.3 <1 140 2.3 5.8 2.2 <1 140 1.9 5.7 2.2 <1 1 150 2.6 6.2 2.3 <1 1 140 2.6 6.2 2.2 <1 130 1.9 5.9 2.1 <1 150 2.4 5.9 2.2 <1 9- 120 2 6.2 2.1 <1 130 1.8 5.6 2.1 <1 Notes: 1. °C indicates temperature measured in degrees celsius 2. mV indicates oxidation/reduction potential measured in millivolts 3. µf2/cm indicates specific conductivity measured in micromhos per centimeter 4. mg/L indicates concentrations measured in milligrams per liter 5. µg/L indicates concentrations measured in micrograms per liter 6. SU indicates pH values measured in standard units 7. NTU indicates turbidity values measured in Nephalometric Turbidity Units 8. Parameters are compared to standards found in 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina 9. 2L Standards are established as part of 15A NCAC 02L .0202 10. Interim Maximum Allowable Concentrations (IMACs) can be found in Appendix #1 of 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina Buck Steam Station Page 6 of 18 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells NCAC 2L Standard: 700 700 2 10 1 300 15 50 0.2 100 Units: µg/L µg/L µg/L µg/L mg/L µg/L µg/L µg/L µg/L µg/L D. :. la, Thafflurn Nickel MW-IS 11/15/2006 67 302 <0.5 4.88 0.013 �2 <2, 476 3.86 MW-1S 5/15/2007 69 322 <0.5 6.4 0.015 PF 3420 <2 402 4.55 MW-IS 11/19/2007 50 428 <0.5 5.29 0.009 3180 <2 215 3.19 MW-1S 5/21/2008 59 465 <0.5 3.94 0.008 4020 <2 325 3.42 MW-IS 11/24/2008 48 516 <0.5 5 0.007 2210 <2 148 2.86 MW-1S 5/12/2009 41 279 <0.5 1.4 0.003 1210 <1 82 <1 MW-IS 11/2/2009 35 254 <1 1.8 0.002 804 <1 63.7 1 MW-1S 5/25/2010 38.1 97.6 <1 2.33 0.003 1520 <1 78.3 1.19 MAD 11/15/2006 31 280 <0.5 1.18 0.004 161 <2 <2 MAD 5/15/2007 36 373 <0.5 <1 <0.002 125 <2 43 2 MAD 11/19/2007 27 466 <0.5 <1 <0.002 169 <2 27 <2 MAD 5/21/2008 27 506 <0.5 <1 <0.002 33 <2 27 <2 MW-1D 11/24/2008 23 593 <0.5 1.06 <0.002 55 <2 23 <2 MAD 5/12/2009 25 388 <0.5 <1 <0.001 34 <1 21 <1 MW-1D 11/2/2009 22.8 442 <1 <1 <0.001 20.5 <1 19.3 <1 MAD 5/25/2010 18.3 304 <1 <1 <0.001 50.4 <1 13 <1 MW-2S 11/15/2006 134 440 <0.5 <1 <0.002 102 <2 2.64 MW-2S 5/16/2007 128 463 <0.5 <1 <0.002 87 <2 400 2.93 MW-2S 11/19/2007 127 449 <0.5 <1 0.002 215 <2 466 3.71 MW-2S 5/21/2008 125 487 <0.5 <1 <0.002 177 <2 296 2.81 MW-2D 11/15/2006 200 <100 <0.5 0.033 <2 267 7.2 MW-2D 5/16/2007 89 <100 <0.5 0.011 <2 rw 66 3.24 MW-2D 11/19/2007 80 <60 <0.5 3.43 <0.002 166 <2 7 <2 MW-2D 5/21/2008 76 <100 <0.5 4.33 <0.002 124 <2 6 <2 MW-3S 11/15/2006 35 1309 <0.5 <1 <0.0 Uza <2 2672 <2 MW-3S 5/15/2007 30 1208 <0.5 <1 <0.002 PV 1076 <2 2796 2.21 MW-3S 11/19/2007 31 1260 <0.5 <1 <0.002 604 <2 2310 <2 MW-3S 5/21/2008 27 1210 <0.5 <1 <0.002 882 <2 2310 <2 MW-3S 11/24/2008 30 1180 <0.5 1.11 <0.002 1470 <2 1990 <2 MW-3S 5/12/2009 28 1130 <0.5 <1 <0.001 1750 <1 1990 1.1 MW-3S 11/2/2009 22.7 1260 <1 <1 <0.001 645 <1 1950 1.3 MW-3S 5/25/2010 22.9 1110 <1 <1 <0.001 f 947 <1 1850 1.28 MW-3D 11/15/2006 109 934 <0.5 <1 <0.002 <2 73 <2 MW-3D 5/15/2007 97 ` 919 <0.5 <1 0.003 83 <2 56 2 MW-3D 11/19/2007 98 866 <0.5 <1 <0.002 57 <2 48 <2 MW-3D 5/21/2008 98 881 <0.5 <1 <0.002 13 <2 49 <2 MW-3D 11/24/2008 88 r 805 <0.5 <1 <0.002 13 <2 43 <2 MW-3D 5/12/2009 91 780 <0.5 <1 <0.001 14 <1 42 <1 MW-3D 11/2/2009 83 817 <1 <1 <0.001 <10 <1 42.6 <1 MW-3D 5/25/2010 80.7 732 <1 <1 <0.001 <10 <1 39.1 <1 MW-4S 11/14/2006 32 483 <0.5 <1 <0.002 404 <2 286 <2 MW-4S 5/15/2007 30 487 <0.5 <1 0.002 435 <2 153 2 MW-4S 11/19/2007 35 466 <0.5 <1 <0.002 1040 <2 103 <2 MW-4S 5/21/2008 73 481 <0.5 1.69 0.003 6160 <2 159 <2 MW-4S 11/24/2008 32 456 <0.5 <1 <0.002 232 <2 72 <2 MW-4S 5/12/2009 100 494 <0.5 <1 0.002 1.9 192 <1 MW-4S 11/2/2009 43.8 505 <1 <1 <0.( W1360 <1 81 <1 MW-4S 5/25/2010 37.9 499 <1 <1 <0.001 694 <1 69.6 <1 MW-4D 11/14/2006 20 434 <0.5 <1 <0.002 105 <2 31 <2 MW-4D 5/15/2007 15 455 <0.5 <1 <0.002 11 <2 9 2 MW-4D 11/19/2007 18 461 <0.5 <1 <0.002 <10 <2 7 <2 MW-4D 5/21/2008 18 489 <0.5 <1 <0.002 24 <2 5 <2 MW-4D 11/24/2008 17 478 <0.5 <1 <0.002 <10 <2 <5 <2 MW-4D 5/12/2009 19 502 <0.5 <1 <0.001 165 <1 <5 <1 MW-4D 11/2/2009 16.3 533 <1 <1 <0.001 <10 <1 <5 <1 MW-4D 5/25/2010 17.1 528 <1 <1 <0.001 <10 <1 <5 <1 Buck Steam Station Page 7 of 18 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells NCAC 2L Standard: 700 700 2 10 1 300 15 50 0.2 100 Units: µg/L µg/L µg/L µg/L mg/L µg/L µg/L µg/L µg/L µg/L Well ID Sample Date Barium Boron Cadmium Chromium Copper Iron Lead Mangan -A L Thallium Nickel MW-5S 11/15/2006 34 230 <0.5 <1 0.002 185 <2 165 7 <2 MW-5S 5/16/2007 28 259 <0.5 1.2 0.003 114 <2 60 2 MW-5S 11/20/2007 49 242 <0.5 1.86 0.007 <2 62 <2 MW-5S 5/21/2008 37 243 <0.5 1.02 <0.002 194 <2 15 <2 MW-5S 11/24/2008 37 213 <0.5 1.58 <0.002 66 <2 7 <2 MW-5S 5/12/2009 37 202 <0.5 <1 <0.001 135 <1 8 <1 MW-5S 11/2/2009 39.9 210 <1 1.3 0.003 <1 28 <1 MW-5S 5/25/2010 32 222 <1 1.26 0.002 232 <1 8.74 <1 MW-SD 11/15/2006 24 388 <0.5 <1 <0.002 62 <2 17 <2 MW-5D 5/16/2007 19 384 <0.5 <1 <0.002 41 <2 8 2 MW-SD 11/20/2007 22 363 <0.5 <1 <0.002 40 <2 8 <2 MW-5D 5/21/2008 20 372 <0.5 <1 <0.002 12 <2 <5 <2 MW-SD 11/24/2008 20 340 <0.5 <1 <0.002 <10 <2 <5 <2 MW-5D 5/12/2009 22 349 <0.5 <1 <0.001 49 <1 <5 <1 MW-SD 11/2/2009 20.1 369 <1 <1 <0.001 <10 <1 <5 <1 MW-51) 5/25/2010 20.8 342 <1 <1 <0.001 <10 <1 <5 <1 MW-6S 11/14/2006 47 <100 <0.5 1.78 0.005 52 <2 5.33 MW-6S 5/15/2007 23 <100 <0.5 2.3 <0.002 36 <2 20 5.62 MW-6S 11/20/2007 39 <60 <0.5 2.58 0.002 799 <2 34 6.09 MW-6S 5/21/2008 43 <100 <0.5 2.05 0.002 995 <2 38 4.95 MW-6S 11/24/2008 40 <100 <0.5 2.36 0.002 710 <2 40 5.2 MW 6S 5/12/2009 39 <100 <0.5 1.6 0.001 505 <1 27 4.6 MW-6S 11/2/2009 32.9 <50 <1 1.5 <0.001 306 <1 21.1 4.6 MW-6S 5/25/2010 32.9 <50 <1 <1 0.006 1270 <1 228 6.58 MW-6S 3/7/2011 36 <50 <1 <5 <0.005 <1 100 <0.2 7 MW-6S 7/5/2011 40 <50 <1 <5 <0.005 139 <1 97 <0.2 7 MW-6S 11/2/2011 36 <50 <1 <5 <0.005 56 <1 1 59 MW-6S 3/7/2012 39 <50 <1 <5 <0.005 185 <1 80 MW-6S 7/3/2012 39 <50 <1 <5 <0.005 137 <1 1 114 MW-6S 11/7/2012 40 <50 <1 <5 <0.005 51 <1 60 MW-6S 3/6/2013 39 <50 <1 <5 <0.005 142 <1 72 MW-6S 7/8/2013 41 <50 <1 <5 <0.005 201 <1 135 MW-6S 11/4/2013 39 <50 <1 <5 <0.005 247 <1 73 MW-6S 3/3/2014 41 <50 <1 <5 <0.005 37 <1 73 <0.2 7 <0.2 6 <0.2 8 <0.2 7 <0.2 7 <0.2 7 <0.2 7 <0.2 7 MW-6S MW-6S 7/1/2014 11/3/2014 38 37 <50 <50 <1 <1 <5 <5 <0.005 70 <0.005 <1 <1 43 35 <0.2 <0.2 6 7 MW-6S 3/4/2015 41 <50 <1 <5 <0.005 <1 29 <0.2 7 MW-6S 7/6/2015 47 <50 <1 <5 <0.005 55 <1 35 <0.2 6 MW-6S 11/3/2015 42 <50 <1 <5 <0.005 65 <1 41 <0.2 7 MW-6S 3/1/2016 52 <50 <1 <5 <0.005 <1 <0.2 9 MW-6D 11/14/2006 40 <100 <0.5 2.35 0.005 0 -- 3.24 MW-61) 5/15/2007 36 <100 <0.5 3 0.004 247 <2 15 2 MW-6D 11/20/2007 44 <60 <0.5 2.33 <0.002 37 <2 <5 <2 MW-61) 5/21/2008 45 <100 <0.5 1.58 <0.002 10 <2 <5 <2 MW-61) 11/24/2008 51 <100 <0.5 1.74 <0.002 10 <2 <5 <2 MW-61) 5/12/2009 60 <100 <0.5 1.1 <0.001 <10 <1 <5 <1 MW-61) 11/2/2009 57 <50 <1 1.4 <0.001 <10 <1 <5 <1 MW-61) 5/25/2010 60.7 <50 <1 1.1 <0.001 <10 <1 <5 -- <1 MW-61) 3/7/2011 63 <50 <1 <5 <0.005 31 <1 <5 <0.2 <5 MW-61) 7/5/2011 64 <50 <1 <5 <0.005 <10 <1 <5 <0.2 <5 MW-61) 11/2/2011 62 <50 <1 <5 <0.005 <10 <1 <5 <0.2 <5 MW-61) 3/7/2012 65 <50 <1 <5 <0.005 26 <1 <5 <0.2 <5 MW-61) 7/3/2012 70 <50 <1 <5 <0.005 18 <1 <5 <0.2 <5 MW-6D 11/7/2012 70 <50 <1 <5 <0.005 25 <1 <5 <0.2 <5 MW-61) 3/6/2013 73 <50 <1 <5 <0.005 62 <1 <5 <0.2 <5 MW-6D 7/8/2013 84 <50 <1 <5 <0.005 127 <1 <5 <0.2 <5 Buck Steam Station Page 8 of 18 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells NCAC 2L Standard: 700 700 2 10 1 300 15 50 0.2 100 Units: µg/L µg/L µg/L µg/L mg/L µg/L µg/L µg/L µg/L µg/L Well ID Sample Date Barium Boron Cadmium Chromium Copper MW-61) 11/4/2013 81 <50 <1 <5 <0.005 55 <1 <5 <0.2 <5 MW-61) 3/3/2014 83 <50 <1 <5 <0.005 47 <1 <5 <0.2 <5 MW-61) 7/1/2014 86 <50 <1 <5 <0.005 78 <1 <5 <0.2 <5 MW-61) 11/3/2014 76 <50 <1 <5 <0.005 25 <1 <5 <0.2 <5 MW-61) 3/4/2015 77 <50 <1 <5 <0.005 33 <1 <5 <0.2 <5 MW-61) 7/6/2015 86 <50 <1 <5 <0.005 <1 7 <0.2 <5 MW-61) 11/3/2015 77 <50 <1 <5 <0.005 14 <1 <5 <0.2 <5 MW-61) 3/1/2016 92 <50 <1 <5 <0.005 <1 16 <0.2 <5 MW-75 3/8/2011 23 <50 <1 6 <0.005 67 <1 <0.2 6 MW-7S 7/5/2011 23 <50 <1 8 <0.005 199 <1 36 <0.2 7 MW-7S 11/2/2011 24 <50 <1 6 <0.005 89 <1 <0.2 7 MW-7S 3/7/2012 21 <50 <1 8 <0.005 41 <1 30 <0.2 5 MW-7S 7/3/2012 22 <50 <1 8 <0.005 47 <1 35 <0.2 6 MW-7S 11/7/2012 25 <50 <1 6 <0.005 38 <1 <0.2 7 MW-7S 3/6/2013 20 <50 <1 9 <0.005 14 <1 30 <0.2 <5 MW-7S 7/8/2013 24 <50 <1 8 <0.005 68 <1 21 <0.2 5 MW-75 11/4/2013 23 <50 <1 9 <0.005 76 <1 20 <0.2 5 MW-7S 3/3/2014 24 <50 <1 8 <0.005 77 <1 <0.2 6 MW-7S 7/1/2014 27 <50 <1 7 <0.005 69 <1 33 <0.2 6 MW-7S 11/3/2014 25 <50 <1 9 <0.005 59 <1 14 <0.2 5 MW-7S 3/4/2015 24 <50 <1 6 <0.005 47 <1 18 <0.2 5 MW-7S 7/6/2015 25 <50 <1 <1.005 121 <1 12 <0.2 7 MW-7S 11/3/2015 33 <50 <1 8 <0.005 79 <1 24 <0.2 7 MW-7S 3/1/2016 25 <50 <1 9 <0.005 86 <1 150 <0.2 5 MW-71) 3/8/2011 12 <50 <1 <5 <0.005 265 <1 98 <0.2 <5 MW-7D 7/5/2011 15 <50 <1 <5 <0.005 <1 129 <0.2 <5 MW-71) 11/2/2011 13 <50 <1 5 <0.005 274 <1 45 <0.2 <5 MW-7D 3/7/2012 14 <50 <1 <5 <0.005 <1 87 <0.2 <5 MW-71) 7/3/2012 13 <50 <1 <5 <0.005 234 <1 41 <0.2 <5 MW-7D 11/7/2012 19 <50 <1 5 <0.005 <1 19 <0.2 <5 MW-71) 3/6/2013 10 <50 <1 <5 <0.005 218 <1 19 <0.2 <5 MW-7D 7/8/2013 14 <50 <1 <5 <0.005 216 <1 43 <0.2 <5 MW-71) 11/4/2013 13 <50 <1 <5 <0.005 96 <1 11 <0.2 <5 MW-7D 3/3/2014 14 <50 <1 <5 <0.005 151 <1 21 <0.2 <5 MW-71) 7/1/2014 13 <50 <1 <5 <0.005 59 <1 18 <0.2 <5 MW-71) 11/3/2014 14 <50 <1 <5 <0.005 83 <1 10 <0.2 <5 MW-71) 3/4/2015 9 <50 <1 <5 <0.005 354 <1 9 <0.2 <5 MW-71) 7/6/2015 19 <50 <1 < 1.005 hill, 635 <1 <0.2 <5 MW-71) 11/3/2015 15 <50 <1 6 <0.005 394 A <1 22 <0.2 <5 MW-71) 3/1/2016 15 <50 <1 <5 <0.005 199 <1 10 <0.2 <5 MW-8S 3/7/2011 37 <50 <1 <5 <0.005 559 <1 <0.2 <5 MW-8S 7/5/2011 29 <50 <1 <5 <0.005 1360 AVE <1 <0.2 <5 MW-8S 11/2/2011 21 <50 <1 <5 <0.005 84 <1 22 <0.2 <5 MW-8S 3/7/2012 53 <50 <1 <5 <0.005 2000 111111F <1 246 <0.2 6 MW-8S 7/3/2012 23 <50 <1 <5 <0.005 282 <1 j6 <0.2 <5 MW-8S 11/7/2012 21 <50 <1 <5 <0.005 75 <1 38 <0.2 <5 MW-8S 3/6/2013 29 <50 <1 <5 <0.005 849 <1 62 <0.2 <5 MW-8S 7/8/2013 41 <50 <1 <5 0.007 4730 <1 152 <0.2 7 MW-8S 11/4/2013 50 <50 <1 6 0.011 7610 <1 127 <0.2 10 MW-8S 3/3/2014 44 <50 <1 <5 0.009 6550 <1 225 <0.2 9 MW-8S 7/1/2014 21 <50 <1 <5 <0.005 679 _ <1 27 <0.2 <5 MW-8S 11/3/2014 20 <50 <1 <5 <0.005 739 <1 88 <0.2 <5 MW-85 3/4/2015 30 <50 <1 <5 <0.005 378 <1 130 qjE<0.2 <5 MW-8S 7/6/2015 31 <50 <1 <5 <0.005 198 <1 11 <0.2 <5 MW-8S 11/3/2015 22 <50 <1 <5 <0.005 619 <1 JIM<0.2 <5 MW-8S 3/2/2016 31 <50 <1 <5 <0.005 2450 <1 47 <0.2 <5 Buck Steam Station Page 9 of 18 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells Well ID MW-81) MW-81) NCAC 2L Standard: Units: Sample Date 3/7/2011 7/5/2011 700 µg/L Barium 19 18 700 µg/L Boron <50 <50 2 µg/L Cadmium <1 <1 10 µg/L Chromium <5 <5 1 mg/L Copper <0.005 <0.005 300 µg/L Iron 147 15 µg/L Lead <1 <1 Manganese 50 µg/L 35 13 0.2 µg/L Thallium <0.2 <0.2 100 µg/L Nickel <5 <5 MW-81) 11/2/2011 17 <50 <1 <5 <0.005 88 <1 7 <0.2 <5 MW-81) 3/7/2012 16 <50 <1 <5 <0.005 129 <1 6 <0.2 <5 MW-81) 7/3/2012 17 <50 <1 <5 <0.005 64 <1 <5 <0.2 <5 MW-81) 11/7/2012 17 <50 <1 <5 <0.005 111 <1 <5 <0.2 <5 MW-81) 3/6/2013 16 <50 <1 <5 <0.005 157 <1 <5 <0.2 <5 MW-81) 7/8/2013 18 <50 <1 <5 <0.005 <1 5 <0.2 <5 MW-81) 11/4/2013 17 <50 <1 <5 <0.005 224 <1 <5 <0.2 <5 MW-81) 3/3/2014 19 <50 <1 <5 <0.005 <1 6 <0.2 <5 MW-81) 7/1/2014 17 <50 <1 <5 <0.005 87 <1 <5 <0.2 <5 MW-81) 11/3/2014 17 <50 <1 <5 <0.005 214 <1 <5 <0.2 <5 MW-81) 3/4/2015 18 <50 <1 <5 <0.005 123 <1 <5 <0.2 <5 MW-81) MW-81) MW-81) MW-9S MW-9S MW-9S MW-9S MW-9S 7/6/2015 11/3/2015 3/2/2016 3/7/2011 7/5/2011 11/2/2011 3/7/2012 7/3/2012 20 18 17 31 29 26 22 28 <50 <50 <50 <50 <50 <50 <50 <50 <1 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5 <5 <5 <5 <5 <5 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 279 227 70 190 <1 <1 <1 <1 <1 <1 <1 <1 1 7 6 <5 63 88 55 45 45 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <5 <5 <5 <5 <5 <5 <5 <5 MW-9S 11/7/2012 29 <50 <1 <5 <0.005 195 <1 38 <0.2 <5 MW-9S 3/7/2013 24 <50 <1 <5 <0.005 75 <1 22 <0.2 <5 MW-9S 7/9/2013 28 <50 <1 <5 <0.005 26 <1 27 <0.2 <5 MW-9S 11/5/2013 30 <50 <1 <5 <0.005 147 <1 22 <0.2 <5 MW-9S 3/4/2014 33 <50 <1 <5 <0.005 <1 29 <0.2 <5 MW-9S 7/1/2014 30 <50 <1 <5 <0.005 24 <1 9 <0.2 <5 MW-9S 11/3/2014 34 <50 <1 <5 <0.005 <1 18 <0.2 <5 MW-9S 3/4/2015 33 <50 <1 <0.005 228 <1 16 <0.2 5 MW-9S 7/6/2015 38 <50 <1 <5 <0.005 <1 37 <0.2 <5 MW-9S 11/3/2015 41 <50 <1 <5 <0.005 222 <1 20 <0.2 <5 MW-9S 3/1/2016 38 <50 <1 <5 <0.005 164 <1 12 <0.2 <5 MW-91) 3/7/2011 25 <50 <1 <5 <0.005 <1 18 <0.2 <5 MW-91) 7/5/2011 20 <50 <1 <5 <0.005 52 <1 <5 <0.2 <5 MW-91) 11/2/2011 20 <50 <1 <5 <0.005 41 <1 <5 <0.2 <5 MW-91) 3/7/2012 20 <50 <1 <5 <0.005 79 <1 <5 <0.2 <5 MW-91) 7/3/2012 28 <50 <1 <5 <0.005 46 <1 <5 <0.2 <5 MW-91) 11/7/2012 22 <50 <1 <5 <0.005 103 <1 5 <0.2 <5 MW-91) 3/7/2013 19 <50 <1 <5 <0.005 10 <1 <5 <0.2 <5 MW-91) 7/9/2013 21 <50 <1 <5 <0.005 37 <1 <5 <0.2 <5 MW-91) 11/5/2013 22 <50 <1 <5 <0.005 91 <1 <5 <0.2 <5 MW-91) 3/4/2014 24 <50 <1 <5 <0.005 120 <1 <5 <0.2 <5 MW-91) 7/1/2014 23 <50 <1 <5 <0.005 35 <1 <5 <0.2 <5 MW-91) 11/3/2014 24 <50 <1 <5 <0.005 14 <1 <5 <0.2 <5 MW-91) 3/4/2015 25 <50 <1 <5 0.005 20 <1 <5 <0.2 <5 MW-91) 7/6/2015 28 <50 <1 <5 <0.005 80 <1 <5 <0.2 <5 MW-91) MW-91) MW-10D MW-10D MW-10D MW-10D MW-10D MW-10D MW-10D MW-10D 11/3/2015 3/1/2016 3/8/2011 7/5/2011 11/2/2011 3/7/2012 7/3/2012 11/7/2012 3/6/2013 7/8/2013 26 30 52 50 45 42 43 46 40 40 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 13 137 279 193 119 104 136 188 110 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <5 <5 1130 944 734 634 539 392 310 272 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 Buck Steam Station Page 10 of 18 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells NCAC 2L Standard: 700 700 2 10 1 300 15 50 0.2 100 Units: µg/L µg/L µg/L µg/L mg/L µg/L µg/L µg/L µg/L µg/L Well ID Sample Date Barium Boron Cadmium Chromium Copper Iron Lead Mangan Thallium Nickel MW-10D 11/5/2013 39 <50 <1 <5 <0.005 61 <1 159 <0.2 <5 MW-10D 3/4/2014 47 <50 <1 <5 <0.005 <1 228 <0.2 <5 MW-10D 7/1/2014 36 <50 <1 <5 <0.005 56 <1 110 <0.2 <5 MW-10D 11/3/2014 33 <50 <1 <5 <0.005 98 <1 74 <0.2 <5 MW-10D 3/4/2015 36 <50 <1 <5 <0.005 121 <1 70 <0.2 <5 MW-10D 7/10/2015 41 <50 <1 <5 <0.005 <1 155 <0.2 <5 MW-10D 11/3/2015 32 <50 <1 <5 <0.005 197 <1 62 <0.2 <5 MW-10D 3/2/2016 31 <50 <1 <5 <0.005 94 <1 34 <0.2 <5 MW-11S 3/7/2011 13 440 <1 <5 <0.005 <1 242 <0.2 <5 MW-11S 7/5/2011 8 472 <1 <5 <0.005 218 <1 153 <0.2 <5 MW-11S 11/2/2011 8 481 <1 <5 <0.005 108 <1 120 <0.2 <5 MW-11S 3/7/2012 7 438 <1 <5 <0.005 96 <1 136 <0.2 <5 MW-11S 7/3/2012 9 442 <1 <5 <0.005 0 <1 151 <0.2 <5 MW-11S 11/7/2012 7 453 <1 <5 <0.005 119 <1 126 <0.2 <5 MW-11S 3/7/2013 7 416 <1 <5 <0.005 129 <1 106 <0.2 <5 MW-11S 7/9/2013 8 453 <1 <5 <0.005 L 316 <1 111 <0.2 <5 MW-11S 11/5/2013 8 446 <1 <5 <0.005 375 <1 139 <0.2 <5 MW-11S 3/4/2014 13 440 <1 <5 <0.005 1150 <1 132 <0.2 <5 MW-11S 7/1/2014 7 446 <1 <5 <0.005 63 <1 129 <0.2 <5 MW-11S 11/3/2014 10 425 <1 <5 <0.005 L 617 <1 119 <0.2 <5 MW-11S 3/4/2015 9 416 <1 <5 <0.005 315 <1 116 <0.2 <5 MW-11S 7/6/2015 11 444 <1 <5 <0.005 425<1 310 <0.2 <5 MW-11S 11/3/2015 11 467 <1 <5 <0.005 230 <1 224 <0.2 <5 MW-11S 3/2/2016 10 435 <1 <5 <0.005 53 <1 231 <0.2 <5 MW-11D 3/7/2011 32 1190 <1 <5 <0.005 318 <1 21 <0.2 <5 MW-11D 7/5/2011 45 1290 <1 <5 <0.005 806 1.94 35 <0.2 <5 MW-11D 11/2/2011 48 1260 <1 <5 <0.005 968 2.62 <0.2 <5 MW-11D 3/7/2012 61 1160 <1 <5 <0.005 L 1720 5.1 69 <0.2 <5 MW-11D 7/3/2012 47 1240 A <1 <5 <0.005 1260 2.82 41 <0.2 <5 MW-11D 11/7/2012 52 1220 <1 <5 <0.005 PW 1610 4.3 56 <0.2 <5 MW-11D 3/7/2013 78 1130 <1 <5 <0.005 3230 8.42 122 1 <0.2 <5 MW-11D 7/9/2013 89 1250 <1 <5 <0.005 3810 6.51 81 J <0.2 <5 MW-11D 11/5/2013 59 r 1270 <1 <5 <0.005 2150 4.3 Aw Old <0.2 <5 MW-11D 3/4/2014 51 1240 <1 <5 <0.005 1710 2.57 41 <0.2 <5 MW-11D 7/1/2014 166 1280 <1 <5 0.009 7340 12.5 <0.2 8 MW-11D 11/3/2014 46 1250 <1 <5 <0.005 f 1130 1.77 37 <0.2 <5 MW-11D 3/4/2015 42 r 1170 <1 <5 0.005 806 1.42 26 <0.2 <5 MW-11D 7/6/2015 34 1320 <1 <5 <0.005 PW 317 <1 17 <0.2 <5 MW-11D 11/3/2015 33 1140 <1 <5 <0.005 91 <1 12 <0.2 <5 MW-11D 3/2/2016 28 1160 <1 <5 <0.005 74 <1 9 <0.2 <5 MW-12S 3/8/2011 25 <50 <1 <0.005 <1 444 <0.2 <5 MW-12S 7/5/2011 21 <50 <1 <0.005 246 <1 239 <0.2 <5 MW-12S 11/2/2011 19 <50 <1 <0.005 119 <1 316 <0.2 <5 MW-12S 3/7/2012 17 <50 <1 <5 <0.005 196 <1 122 <0.2 <5 MW-12S 7/3/2012 17 <50 <1 <5 <0.005 157 <1 137 <0.2 <5 MW-12S 11/7/2012 17 <50 <1 <5 <0.005 117 <1 140 <0.2 <5 MW-12S 3/7/2013 17 <50 <1 <5 <0.005 259 <1 52 <0.2 <5 MW-12S 7/9/2013 18 <50 <1 <5 <0.005 r7 571 <1 35 <0.2 <5 MW-12S 11/4/2013 19 <50 <1 <5 <0.005 11 721 <1 68 <0.2 <5 MW-12S 3/4/2014 16 <50 <1 <5 <0.005 329 <1 53 <0.2 <5 MW-12S 7/1/2014 16 <50 <1 <5 <0.005 236 <1 79 <0.2 <5 MW-12S 11/3/2014 20 <50 <1 <5 <0.005 ' 1010 <1 69 <0.2 <5 MW-12S 3/4/2015 17 <50 <1 <5 <0.005 ' 439 <1 41 <0.2 <5 MW-12S 7/6/2015 25 <50 <1 <5 <0.005 ' 2640 <1 89 <0.2 <5 MW-12S 11/3/2015 19 <50 <1 <5 <0.005 1020 <1 61 <0.2 <5 MW-12S 3/1/2016 17 <50 <1 <5 <0.005 476 <1 20 <0.2 <5 Buck Steam Station Page 11 of 18 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells Well ID MW-12D MW-12D MW-12D MW-12D MW-12D NCAC 2L Standard: Units: Sample Date� 3/8/2011 7/5/2011 11/2/2011 3/7/2012 7/3/2012 700 µg/L 74 55 46 28 20 700 µg/L <50 <50 <50 <50 <50 2 µg/L <1 <1 <1 <1 <1 10 µg/L <5 <5 <5 <5 <5 1 mg/L <0.005 <0.00577F <0.005 <0.005 <0.005 L 300 µg/L 1070 871 994 530 281 15 µg/L 3.21 2.71 2.03 1.5 <1 50 33 38 19 12 02 <0.2 <0.2 <0.2 <0.2 <0.2 100 <5 <5 <5 <5 <5 MW-12D 11/7/2012 19 <50 <1 <5 <0.005 203 <1 10 <0.2 <5 MW-12D 3/7/2013 14 <50 <1 <5 <0.005 130 <1 7 <0.2 <5 MW-12D 7/9/2013 26 <50 <1 <5 <0.005 201 <1 7 <0.2 <5 MW-12D 11/4/2013 16 <50 <1 <5 <0.005 94 <1 <5 <0.2 <5 MW-12D 3/4/2014 31 <50 <1 <5 <0.005 281 <1 7 <0.2 <5 MW-12D 7/1/2014 16 <50 <1 <5 <0.005 83 <1 <5 <0.2 <5 MW-12D 11/3/2014 17 <50 <1 <5 <0.005 96 <1 <5 <0.2 <5 MW-12D 3/4/2015 26 <50 <1 <5 0.017 106 <1 <5 <0.2 <5 MW-12D 7/6/2015 20 <50 <1 <5 <0.005 <1 8 <0.2 <5 MW-12D 11/3/2015 19 <50 <1 <5 <0.005 254 <1 6 <0.2 <5 MW-12D 3/1/2016 15 <50 <1 <5 <0.005 98 <1 <5 <0.2 <5 MW-13D 3/8/2011 44 <50 <1 <5 <0.005 179 <1 15 <0.2 <5 MW-13D 7/5/2011 48 <50 <1 <5 <0.005 257 <1 6 <0.2 <5 MW-13D 11/2/2011 42 <50 <1 <5 <0.005 64 <1 <5 <0.2 <5 MW-13D 3/7/2012 41 <50 <1 <5 <0.005 263 <1 <5 <0.2 <5 MW-13D 7/3/2012 45 <50 <1 <5 <0.005 47 <1 <5 <0.2 <5 MW-13D 11/7/2012 43 <50 <1 <5 <0.005 42 <1 <5 <0.2 <5 MW-13D MW-13D MW-13D MW-13D MW-13D MW-13D MW-13D 3/6/2013 7/8/2013 11/4/2013 3/3/2014 7/1/2014 11/3/2014 3/4/2015 40 46 45 48 50 45 43 <50 <50 <50 <50 <50 <50 <50 <1 <1 <1 <1 <1 <1 <1 <5 5 5 7 5 <5 <5 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 228 680 344 1260 134 84 111 <1 <1 <1 <1 <1 <1 <1 <5 6 <5 8 <5 <5 <5 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <5 <5 <5 <5 <5 <5 <5 MW-13D 7/6/2015 50 <50 <1 7 <0.005 <1 <5 <0.2 <5 MW-13D 11/3/2015 45 <50 <1 <5 <0.005 <1 <5 <0.2 <5 MW-13D 3/1/2016 43 <50 <1 5 <0.005 85 <1 <5 <0.2 <5 Notes: 1. °C indicates temperature measured in degrees celsius 2. mV indicates oxidation/reduction potential measured in millivolts 3. µO/cm indicates specific conductivity measured in micromhos per centimeter 4. mg/L indicates concentrations measured in milligrams per liter 5. µg/L indicates concentrations measured in micrograms per liter 6. SU indicates pH values measured in standard units 7. NTU indicates turbidity values measured in Nephalometric Turbidity Units 8. Parameters are compared to standards found in 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina 9. 2L Standards are established as part of 15A NCAC 02L .0202 10. Interim Maximum Allowable Concentrations (IMACs) can be found in Appendix #1 of 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina Buck Steam Station Page 12 of 18 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells Well ID MW-IS NCAC 2L Standard: Units: Sample Date 11/15/2006 1 1 mg/L µg/L Zinc Antimony* 0.019 - 20 µg/L Selenium <2 1 µg/L Mercury <0.2 NS NTU Turbidity (Field) 95.8 MW-1S 5/15/2007 0.016 <2 <0.1 326 MW-IS 11/19/2007 0.008 - <2 <0.1 146 MW-1S 5/21/2008 0.013 <2 <0.05 236 MW-IS 11/24/2008 0.007 - <2 <0.05 104 MW-1S 5/12/2009 0.008 <1 <0.05 50.5 MW-IS 11/2/2009 <0.005 - <1 <0.05 45.4 MW-1S 5/25/2010 <0.005 <1 <0.05 100 MW-1D 11/15/2006 <0.005 - <2 <0.2 17.8 MW-1D 5/15/2007 0.014 <2 <0.1 1.93 MW-1D 11/19/2007 <0.005 - <2 <0.1 3.75 MW-1D 5/21/2008 <0.005 - <2 <0.05 1.61 MW-1D 11/24/2008 <0.005 - <2 <0.05 1.8 MW-1D 5/12/2009 <0.005 - <1 <0.05 0.89 MW-1D 11/2/2009 <0.005 -- <1 <0.05 2.98 MW-1D 5/25/2010 <0.005 - <1 <0.05 1.66 MW-2S 11/15/2006 0.023 -- <2 <0.2 3.83 MW-2S 5/16/2007 0.015 - <2 <0.1 7.44 MW-2S 11/19/2007 0.013 -- <2 <0.1 22.2 MW-2S 5/21/2008 0.016 - <2 <0.05 6.23 MW-2D 11/15/2006 0.038 -- <2 <0.2 887 MW-2D 5/16/2007 0.006 - <2 <0.1 105 MW-2D 11/19/2007 <0.005 - <2 <0.1 4.23 MW-2D 5/21/2008 <0.005 <2 <0.05 3.92 MW-3S 11/15/2006 <0.005 -- <2 <0.2 13.9 MW-3S 5/15/2007 <0.005 <2 <0.1 6.59 MW-3S 11/19/2007 <0.005 -- <2 <0.1 7.7 MW-3S 5/21/2008 <0.005 <2 <0.05 21.4 MW-3S 11/24/2008 <0.005 -- <2 <0.05 24 MW-3S 5/12/2009 <0.005 <1 <0.05 20.6 MW-3S 11/2/2009 <0.005 -- <1 <0.05 7.54 MW-3S 5/25/2010 <0.005 - <1 <0.05 8.59 MW-3D 11/15/2006 0.006 - <2 <0.2 12.7 MW-3D 5/15/2007 <0.005 <2 <0.1 2.49 MW-3D 11/19/2007 <0.005 - <2 <0.1 1.82 MW-3D 5/21/2008 <0.005 <2 <0.05 4.13 MW-3D 11/24/2008 <0.005 - <2 <0.05 1.16 MW-3D 5/12/2009 <0.005 <1 <0.05 1.51 MW-3D 11/2/2009 <0.005 - <1 <0.05 2.68 MW-3D 5/25/2010 <0.005 <1 <0.05 1.05 MW-4S 11/14/2006 <0.005 - <2 <0.2 16.4 MW-4S 5/15/2007 <0.005 <2 <0.1 39.8 MW-4S 11/19/2007 <0.005 - <2 <0.1 18.4 MW-4S 5/21/2008 0.019 - <2 <0.05 140 MW-4S 11/24/2008 <0.005 - <2 <0.05 9.76 MW-4S 5/12/2009 0.03 - <1 <0.05 158 MW-4S 11/2/2009 <0.005 - <1 <0.05 74.3 MW-4S 5/25/2010 <0.005 - <1 <0.05 14.7 MW-4D 11/14/2006 <0.005 -- <2 <0.2 10.9 MW-4D 5/15/2007 <0.005 - <2 <0.1 0.52 MW-4D 11/19/2007 <0.005 -- <2 <0.1 1.16 MW-4D 5/21/2008 <0.005 - <2 0.125 6.22 MW-4D 11/24/2008 <0.005 -- <2 <0.05 1.08 MW-4D 5/12/2009 <0.005 - <1 <0.05 2.18 MW-41) 11/2/2009 <0.005 -- <1 <0.05 2.78 MW-4D 5/25/2010 <0.005 - <1 <0.05 0.81 Buck Steam Station Page 13 of 18 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells Well ID Sample Date Zinc Antimony* Selenium Mercury Turbidity (Field) MW-5S 5/16/2007 <0.005 - <2 <0.1 7.99 MW-5S 11/20/2007 0.007 -- <2 <0.1 18.1 MW-5S 5/21/2008 <0.005 - <2 0.054 10.9 MW-5S 11/24/2008 <0.005 -- <2 <0.05 4.18 MW-5S 5/12/2009 0.006 - <1 <0.05 8.24 MW-5S 11/2/2009 <0.005 -- <1 <0.05 19 MW-5S 5/25/2010 <0.005 - <1 <0.05 7.8 MW-5D 11/15/2006 <0.005 - <2 <0.2 7.75 MW-51) 5/16/2007 <0.005 <2 <0.1 0.64 MW-51) 11/20/2007 <0.005 - <2 <0.1 1.24 MW-5D 5/21/2008 <0.005 - <2 <0.05 5.54 MW-51) 11/24/2008 <0.005 - <2 <0.05 0.69 MW-5D 5/12/2009 <0.005 - <1 <0.05 1.97 MW-51) 11/2/2009 <0.005 - <1 <0.05 3.44 MW-5D 5/25/2010 <0.005 - <1 <0.05 1.56 MW-6S 11/14/2006 0.023 -- <2 <0.2 71.8 MW-6S 5/15/2007 0.006 - <2 <0.1 4.79 MW-6S 11/20/2007 0.009 -- <2 <0.1 37.8 MW-6S 5/21/2008 0.012 - <2 <0.05 64.9 MW-6S 11/24/2008 0.006 -- <2 <0.05 78 MW-6S 5/12/2009 0.007 - <1 <0.05 59.6 MW-6S 11/2/2009 <0.005 -- <1 <0.05 14.5 MW-6S 5/25/2010 0.006 <1 <0.05 11.9 MW-6S 3/7/2011 0.009 <1 <1 <0.05 8.1 MW-6S 7/5/2011 0.007 <1 <1 <0.05 7.5 MW-6S 11/2/2011 0.006 <1 <1 <0.05 4 MW-6S 3/7/2012 0.008 <1 <1 <0.05 1.63 MW-6S 7/3/2012 0.007 <1 <1 <0.05 5.21 MW-6S 11/7/2012 0.007 <1 <1 <0.05 4.26 MW-6S 3/6/2013 0.008 <1 <1 <0.05 2.04 MW-6S 7/8/2013 0.01 <1 <1 <0.05 4.24 MW-6S 11/4/2013 <0.005 <1 <1 <0.05 3.32 MW-6S 3/3/2014 0.014 <1 <1 <0.05 1.36 MW-6S 7/1/2014 <0.005 <1 <1 <0.05 5.29 MW-6S 11/3/2014 0.011 <1 <1 <0.05 8.43 MW-6S 3/4/2015 0.01 <1 <1 <0.05 6.64 MW-6S 7/6/2015 0.008 <1 <1 <0.05 0.82 MW-6S 11/3/2015 0.007 <1 <1 <0.05 2.32 MW-6S 3/1/2016 0.007 <1 <0.05 2.83 MW-6D 11/14/2006 0.017 - <2 <0.2 24.5 MW-6D 5/15/2007 0.006 <2 <0.1 8.15 MW-6D 11/20/2007 <0.005 -- <2 <0.1 1.39 MW-6D 5/21/2008 <0.005 <2 <0.05 1.08 MW-61) 11/24/2008 <0.005 -- <2 <0.05 0.63 MW-6D 5/12/2009 <0.005 <1 <0.05 0.32 MW-61) 11/2/2009 <0.005 -- <1 <0.05 2.58 MW-6D 5/25/2010 <0.005 - <1 <0.05 0.67 MW-61) 3/7/2011 <0.005 <1 <1 <0.05 2 MW-6D 7/5/2011 <0.005 <1 <1 <0.05 0.9 MW-61) 11/2/2011 <0.005 <1 <1 <0.05 0.5 MW-6D 3/7/2012 <0.005 <1 <1 <0.05 0.94 MW-61) 7/3/2012 <0.005 <1 <1 <0.05 0.5 MW-6D 11/7/2012 <0.005 <1 <1 <0.05 0.54 MW-61) 3/6/2013 <0.005 <1 <1 <0.05 2.1 MW-6D 7/8/2013 <0.005 <1 <1 <0.05 1.98 Buck Steam Station Page 14 of 18 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells NCAC 2L Standard: 1 1 20 1 NS Units: mg/L µg/L µg/L µg/L NTU SampleWell ID Turbidity MW-6D 3/3/2014 0.007 <1 <1 <0.05 1.35 MW-6D 7/1/2014 <0.005 <1 <1 <0.05 2.35 MW-6D 11/3/2014 <0.005 <1 <1 <0.05 1.24 MW-6D 3/4/2015 <0.005 <1 <1 <0.05 1.66 MW-6D 7/6/2015 <0.005 <1 <1 <0.05 7.31 MW-6D 11/3/2015 <0.005 <1 <1 <0.05 1.48 MW-6D 3/1/2016 <0.005 <1 <0.05 9.92 MW-75 3/8/2011 <0.005 <1 <1 <0.05 4.8 MW-7S 7/5/2011 <0.005 <1 <1 <0.05 8.3 MW-7S 11/2/2011 <0.005 <1 <1 <0.05 3.6 MW-7S 3/7/2012 <0.005 <1 <1 <0.05 2.12 MW-75 7/3/2012 <0.005 <1 <1 <0.05 1.46 MW-7S 11/7/2012 <0.005 <1 <1 <0.05 1.04 MW-75 3/6/2013 <0.005 <1 <1 <0.05 1.99 MW-7S 7/8/2013 <0.005 <1 <1 <0.05 1.14 MW-75 11/4/2013 <0.005 <1 <1 <0.05 2.43 MW-7S 3/3/2014 <0.005 <1 <1 <0.05 1.37 MW-7S 7/1/2014 <0.005 <1 <1 <0.05 1.99 MW-7S 11/3/2014 0.006 <1 <1 <0.05 2.4 MW-7S 3/4/2015 <0.005 <1 <1 <0.05 2.18 MW-7S 7/6/2015 <0.005 <1 <1 <0.05 1.57 MW-7S 11/3/2015 <0.005 <1 <1 <0.05 1.95 MW-7S 3/1/2016 <0.005 <1 <0.05 2.74 MW-7D 3/8/2011 <0.005 <1 <1 <0.05 8.5 MW-7D 7/5/2011 <0.005 <1 <1 <0.05 7 MW-7D 11/2/2011 <0.005 <1 <1 <0.05 9.6 MW-7D 3/7/2012 <0.005 <1 <1 <0.05 9.3 MW-7D 7/3/2012 <0.005 <1 <1 <0.05 9.66 MW-7D 11/7/2012 <0.005 <1 <1 <0.05 14.3 MW-7D 3/6/2013 <0.005 <1 <1 <0.05 7.17 MW-7D 7/8/2013 <0.005 <1 <1 <0.05 4.54 MW-7D 11/4/2013 <0.005 <1 <1 <0.05 3.96 MW-7D 3/3/2014 <0.005 <1 <1 <0.05 3.15 MW-7D 7/1/2014 <0.005 <1 <1 <0.05 3.09 MW-7D 11/3/2014 <0.005 <1 <1 <0.05 3.16 MW-7D 3/4/2015 <0.005 <1 <1 <0.05 8.78 MW-71) 7/6/2015 <0.005 <1 <1 <0.05 9.93 MW-7D 11/3/2015 <0.005 <1 <1 <0.05 3.7 MW-71) 3/1/2016 <0.005 <1 <0.05 6.29 MW-8S 3/7/2011 <0.005 <1 <1 <0.05 27.2 MW-8S 7/5/2011 <0.005 <1 <1 <0.05 47.1 MW-8S 11/2/2011 <0.005 <1 <1 <0.05 6.6 MW-8S 3/7/2012 0.007 <1 <1 <0.05 70.3 MW-8S 7/3/2012 <0.005 <1 <1 <0.05 4.48 MW-8S 11/7/2012 <0.005 <1 <1 <0.05 2.04 MW-8S 3/6/2013 0.007 <1 <1 <0.05 15.3 MW-8S 7/8/2013 0.011 <1 <1 <0.05 19.5 MW-8S 11/4/2013 0.009 <1 <1 <0.05 48.2 MW-8S 3/3/2014 0.011 <1 <1 <0.05 86.5 MW-8S 7/1/2014 <0.005 <1 <1 <0.05 16.9 MW-8S 11/3/2014 <0.005 <1 <1 <0.05 11.4 MW-85 3/4/2015 <0.005 <1 <1 <0.05 7.71 MW-8S 7/6/2015 <0.005 <1 <1 <0.05 3.54 MW-8S 11/3/2015 <0.005 <1 <1 <0.05 10.8 MW-8S 3/2/2016 <0.005 <1 <0.05 32.6 Page 15 of 18 Buck Steam Station CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells Well ID Sample Date Zinc Antimony* Selenium Mercury Turbidity (Field) IVIVV-25U .5///LUll GU.UU.� 11. Gl 11U.U.7 11 MW-81) 7/5/2011 <0.005 <1 <1 <0.05 16 MW-8D 11/2/2011 <0.005 <1 <1 <0.05 6.2 MW-8D 3/7/2012 <0.005 <1 <1 <0.05 3.55 MW-8D 7/3/2012 <0.005 <1 <1 <0.05 4.48 MW-81) 11/7/2012 <0.005 <1 <1 <0.05 2.59 MW-8D 3/6/2013 <0.005 <1 <1 <0.05 4.77 MW-8D 7/8/2013 <0.005 <1 <1 <0.05 3.87 MW-8D 11/4/2013 <0.005 <1 <1 <0.05 4.78 MW-81) 3/3/2014 <0.005 <1 <1 <0.05 8.03 MW-81) 7/1/2014 <0.005 <1 <1 <0.05 11 MW-8D 11/3/2014 <0.005 <1 <1 <0.05 4.78 MW-81) 3/4/2015 <0.005 <1 <1 <0.05 4.91 MW-8D 7/6/2015 <0.005 <1 <1 <0.05 5.48 MW-81) 11/3/2015 <0.005 <1 <0.05 6.96 MW-8D 3/2/2016 <0.005 <1 <0.05 4.74 MW-9S 3/7/2011 <0.005 <1 <1 <0.05 30.6 MW-9S 7/5/2011 <0.005 <1 <1 <0.05 9.9 MW-9S 11/2/2011 <0.005 <1 <1 <0.05 9.3 MW-9S 3/7/2012 <0.005 <1 <1 <0.05 3.01 MW-9S 7/3/2012 <0.005 <1 <1 <0.05 9.86 MW-9S 11/7/2012 <0.005 <1 <1 <0.05 6.03 MW-9S 3/7/2013 <0.005 <1 <1 <0.05 7.93 MW-9S 7/9/2013 <0.005 <1 <1 <0.05 0.91 MW-9S 11/5/2013 <0.005 <1 <1 <0.05 6.23 MW-9S 3/4/2014 <0.005 <1 <1 <0.05 8.26 MW-9S 7/1/2014 <0.005 <1 <1 <0.05 3.82 MW-9S 11/3/2014 <0.005 <1 <1 <0.05 8.16 MW-9S 3/4/2015 <0.005 <1 <1 <0.05 5.59 MW-9S 7/6/2015 <0.005 <1 <1 <0.05 5.31 MW-9S 11/3/2015 <0.005 <1 <1 <0.05 6.13 MW-9S 3/1/2016 <0.005 <1 <0.05 5.32 MW-91) 3/7/2011 <0.005 <1 <1 <0.05 15 MW-91) 7/5/2011 <0.005 <1 <1 <0.05 2.2 MW-9D 11/2/2011 <0.005 <1 <1 <0.05 2.1 MW-91) 3/7/2012 <0.005 <1 <1 <0.05 3.04 MW-9D 7/3/2012 <0.005 <1 <1 <0.05 1.76 MW-91) 11/7/2012 <0.005 <1 <1 <0.05 3.11 MW-9D 3/7/2013 <0.005 <1 <1 <0.05 1.58 MW-91) 7/9/2013 <0.005 <1 <1 <0.05 1.12 MW-9D 11/5/2013 <0.005 <1 <1 <0.05 4.14 MW-91) 3/4/2014 <0.005 <1 <1 <0.05 2.04 MW-9D 7/1/2014 <0.005 <1 <1 <0.05 2.22 MW-91) 11/3/2014 <0.005 <1 <1 <0.05 1.59 MW-91) 3/4/2015 <0.005 <1 <1 <0.05 1.02 MW-91) 7/6/2015 <0.005 <1 <1 <0.05 1.06 MW-91) 11/3/2015 <0.005 <1 <1 <0.05 1.22 MW-91) 3/1/2016 <0.005 <1 <0.05 4.43 MW-10D 3/8/2011 <0.005 <1 <1 <0.05 9.5 MW-10D 7/5/2011 <0.005 <1 <1 <0.05 1.7 MW-10D 11/2/2011 <0.005 <1 <1 <0.05 1.1 MW-10D 3/7/2012 <0.005 <1 <1 <0.05 1.54 MW-10D 7/3/2012 <0.005 <1 <1 <0.05 0.46 MW-10D 11/7/2012 <0.005 <1 <1 <0.05 1.43 MW-10D 3/6/2013 <0.005 <1 <1 <0.05 1.79 MW-10D 7/8/2013 <0.005 <1 <1 <0.05 0.79 Buck Steam Station Page 16 of 18 CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells NCAC 2L Standard: 1 1 20 1 NS Units: mg/L µg/L µg/L µg/L NTU SampleWell ID Turbidity MW-10D 3/4/2014 <0.005 <1 <1 <0.05 5.96 MW-10D 7/1/2014 <0.005 <1 <1 <0.05 6.84 MW-10D 11/3/2014 <0.005 <1 <1 <0.05 2.6 MW-10D 3/4/2015 <0.005 <1 <1 <0.05 2.73 MW-10D 7/10/2015 0.006 <1 <1 <0.05 9.44 MW-10D 11/3/2015 <0.005 <1 <1 <0.05 3.86 MW-10D 3/2/2016 <0.005 <1 <0.05 4.54 MW-11S 3/7/2011 <0.005 <1 <1 <0.05 22.9 MW-11S 7/5/2011 <0.005 <1 <1 <0.05 14.3 MW-11S 11/2/2011 <0.005 <1 <1 <0.05 7.2 MW-11S 3/7/2012 <0.005 <1 <1 <0.05 2.59 MW-11S 7/3/2012 <0.005 <1 <1 <0.05 4.89 MW-11S 11/7/2012 <0.005 <1 <1 <0.05 3.09 MW-11S 3/7/2013 <0.005 <1 <1 <0.05 4.83 MW-11S 7/9/2013 <0.005 <1 <1 <0.05 6.05 MW-11S 11/5/2013 <0.005 <1 <1 <0.05 7.76 MW-11S 3/4/2014 <0.005 <1 <1 <0.05 16.2 MW-11S 7/1/2014 <0.005 <1 <1 <0.05 4.9 MW-11S 11/3/2014 0.005 <1 <1 <0.05 9.77 MW-11S 3/4/2015 <0.005 <1 <1 <0.05 7.83 MW-11S 7/6/2015 <0.005 <1 <1 <0.05 8.77 MW-11S 11/3/2015 <0.005 <1 <1 <0.05 4.45 MW-11S 3/2/2016 <0.005 <1 <0.05 1.91 MW-11D 3/7/2011 <0.005 <1 <1 <0.05 12.8 MW-11D 7/5/2011 0.005 <1 <1 <0.05 37.5 MW-11D 11/2/2011 0.006 <1 <1 <0.05 53.3 MW-11D 3/7/2012 0.01 <1 <1 <0.05 76.8 MW-11D 7/3/2012 <0.005 <1 <1 <0.05 56.2 MW-11D 11/7/2012 0.009 <1 <1 <0.05 126 MW-11D 3/7/2013 0.017 <1 <1 <0.05 277 MW-11D 7/9/2013 0.019 <1 <1 <0.05 202 MW-11D 11/5/2013 0.009 <1 <1 <0.05 123 MW-11D 3/4/2014 0.011 <1 <1 <0.05 33.8 MW-11D 7/1/2014 0.028 <1 <1 <0.05 313 MW-11D 11/3/2014 0.007 <1 <1 <0.05 36.3 MW-11D 3/4/2015 0.007 <1 <1 <0.05 27.9 MW-11D 7/6/2015 <0.005 <1 <1 <0.05 6.81 MW-11D 11/3/2015 <0.005 <1 <1 <0.05 2.53 MW-11D 3/2/2016 <0.005 <1 <0.05 2.88 MW-12S 3/8/2011 <0.005 <1 <1 <0.05 13.4 MW-12S 7/5/2011 <0.005 <1 <1 <0.05 9 MW-12S 11/2/2011 <0.005 <1 <1 <0.05 9.5 MW-12S 3/7/2012 <0.005 <1 <1 <0.05 8.01 MW-12S 7/3/2012 <0.005 <1 <1 <0.05 2.5 MW-12S 11/7/2012 <0.005 <1 <1 <0.05 2.56 MW-12S 3/7/2013 <0.005 <1 <1 <0.05 8.14 MW-12S 7/9/2013 <0.005 <1 <1 <0.05 7.76 MW-12S 11/4/2013 <0.005 <1 <1 <0.05 13.2 MW-12S 3/4/2014 <0.005 <1 <1 <0.05 7.11 MW-12S 7/1/2014 <0.005 <1 <1 <0.05 9.75 MW-12S 11/3/2014 0.006 <1 <1 <0.05 13.8 MW-12S 3/4/2015 <0.005 <1 <1 <0.05 12 MW-12S 7/6/2015 0.006 <1 <1 <0.05 35.4 MW-12S 11/3/2015 <0.005 <1 <1 <0.05 16 MW-12S 3/1/2016 <0.005 <1 <0.05 9.18 Page 17 of 18 Buck Steam Station CSA Supplement 2 Table 1-2: Historical Data from NPDES Compliance and Voluntary Wells NCAC 2L Standard: 1 1 20 Units: mg/L µg/L µg/L Well ID Sample Date, Zinc Antimony* SeleniL ,n NS lity WWI MW-12D 7/5/2011 0.005 <1 <1 <0.05 63.2 MW-12D 11/2/2011 0.01 <1 <1 <0.05 68.6 MW-12D 3/7/2012 <0.005 <1 <1 <0.05 23.6 MW-12D 7/3/2012 <0.005 <1 <1 <0.05 9.34 MW-12D 11/7/2012 <0.005 <1 <1 <0.05 6.14 MW-12D 3/7/2013 <0.005 <1 <1 <0.05 5.87 MW-12D 7/9/2013 <0.005 <1 <1 <0.05 4.52 MW-12D 11/4/2013 <0.005 <1 <1 <0.05 3.89 MW-12D 3/4/2014 <0.005 <1 <1 <0.05 7.4 MW-12D 7/1/2014 <0.005 <1 <1 <0.05 5.23 MW-12D 11/3/2014 <0.005 <1 <1 <0.05 3.87 MW-12D 3/4/2015 0.006 <1 <1 <0.05 5.18 MW-12D 7/6/2015 <0.005 <1 <1 <0.05 7.11 MW-12D 11/3/2015 <0.005 <1 <1 <0.05 6.51 MW-12D 3/1/2016 <0.005 <1 <0.05 4.18 MW-13D 3/8/2011 <0.005 <1 <1 <0.05 12.9 MW-13D 7/5/2011 <0.005 <1 <1 <0.05 17.7 MW-13D 11/2/2011 <0.005 <1 <1 <0.05 7.3 MW-13D 3/7/2012 <0.005 <1 <1 <0.05 9.9 MW-13D 7/3/2012 <0.005 <1 <1 <0.05 1.63 MW-13D 11/7/2012 <0.005 <1 <1 <0.05 1.37 MW-13D 3/6/2013 <0.005 <1 <1 <0.05 9.8 MW-13D 7/8/2013 <0.005 <1 <1 <0.05 9.47 MW-13D 11/4/2013 <0.005 <1 <1 <0.05 4.9 MW-13D 3/3/2014 <0.005 <1 <1 <0.05 27.2 MW-13D 7/1/2014 <0.005 <1 <1 <0.05 9.17 MW-13D 11/3/2014 <0.005 <1 <1 <0.05 4.1 MW-13D 3/4/2015 <0.005 <1 <1 <0.05 4.92 MW-13D 7/6/2015 <0.005 <1 <1 <0.05 9.9 MW-13D 11/3/2015 <0.005 <1 <1 <0.05 6.74 MW-13D 3/1/2016 <0.005 <1 <0.05 2.72 Notes: 1. °C indicates temperature measured in degrees celsius 2. mV indicates oxidation/reduction potential measured in millivolts 3. µO/cm indicates specific conductivity measured in micromhos per centimeter 4. mg/L indicates concentrations measured in milligrams per liter 5. µg/L indicates concentrations measured in micrograms per liter 6. SU indicates pH values measured in standard units 7. NTU indicates turbidity values measured in Nephalometric Turbidity Units 8. Parameters are compared to standards found in 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina 9. 2L Standards are established as part of 15A NCAC 02L .0202 10. Interim Maximum Allowable Concentrations (IMACs) can be found in Appendix #1 of 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina Buck Steam Station Page 18 of 18 CSA Supplement 2 Table 1-3: 2L Groundwater Standard Exceedances from NPDES Sampling AB-1R 2L Standard: Units: Date Range 3/1/2011- 3/3/2016 1 µg/L Antimony 1.1- 2.57 700 µg/L Boron No Exceedances 300 µg/L Iron 381- 476 50 µg/L Manganese No Exceedances 100 µg/L Nickel No Exceedances 6.5 - 8.5 SU . 5.91- 6.5 AB-4S A13-4D AB-9S AB-91) 11/2/2004 - 3/3/2016 11/2/2004 - 3/3/2016 3/1/2011- 3/3/2016 3/1/2011- 3/3/2016 1.07 - 2.46 1.04 - 2.54 1.05 - 2.52 1.07 - 2.19 No Exceedances No Exceedances 705 - 740 No Exceedances 314 - 3,600 750 4,470-10,500 356 - 909 64 - 380 74 -110 9,130-10,200 95 No Exceedances No Exceedances No Exceedances No Exceedances 5.3 - 6.14 5.76 - 6.3 5.93 - 6.49 6.32 - 6.4 AB-10D 3/1/2011- 3/3/2016 1.05 - 2.58 No Exceedances 333 - 843 373 - 557 No Exceedances 5.74 - 6.31 AB-11S 3/1/2011- 3/3/2016 2.35 No Exceedances 307 -1,060 50 -144 No Exceedances 5.84 - 6.49 AB-11D 3/1/2011- 3/3/2016 1.11- 2.5 No Exceedances 355 - 844 No Exceedances No Exceedances 5.5 - 6.14 AB-12S 3/1/2011- 3/3/2016 1.92 No Exceedances 549 - 2,770 53 -132 No Exceedances 4.71- 5.19 AB-12D 3/1/2011- 3/3/2016 2.56 No Exceedances 307 - 823 No Exceedances No Exceedances 6.09 - 6.48 AB-13S 3/1/2011- 3/3/2016 1.05 - 2.49 No Exceedances 324 - 817 55 -165 No Exceedances 5.16 - 5.94 AB-13D 3/1/2011- 3/3/2016 1.24 - 2.45 No Exceedances 391- 3,100 57 - 240 No Exceedances 5.85 - 6.49 AB-14D 3/1/2011- 3/3/2016 2 No Exceedances 301- 8,350 52 - 945 104 - 544 5.16 - 6.17 Notes: 1. mg/L indicates concentrations measured in milligrams per liter 2. µg/L indicates concentrations measured in micrograms per liter 3. SU indicates pH values measured in standard units 4. Parameters are compared to standards found in 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina 2L Standards are established as part of 15A NCAC 02L .0202 5. Interim Maximum Allowable Concentrations (IMACs) can be found in Appendix #1 of 15A NCAC Subchapter 02L Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina Allen Steam Station Page 1 of 1 CSA Supplement 2 Table 2-1: Responses to Global NCDEQ Comments Check latitude and longitude shown on report cover pages (the HDR will review and provide corrected latitude and longitude coordinates for the sites in forthcoming General 1 conversion appears to be incorrect on the Mooresville region reports, if needed. reports and needs to be reconciled). "Proposed Provisional Background Concentrations" or PPBCs is the terminology used for statistically Background 2 Use terminology PEPA "provisional estimates for purposes of determined background concentrations in the CAP reporting. PPBCs are discussed in CAP Part 1, Section 2. assessment" provide for background concentrations of COls. The approach to refine PPBCs when additional data is available is presented in CSA Supplement 2, Section 4. COI Use results from porewater, groundwater and other media to COls were selected based on exceedances found in porewater, groundwater, soil, and surface water 3 develop COI list. sample results. Hexavalent Chromium is included as a CO] in CAP Part 1 data tables and is considered with respect to the include as COI at each site duer interest and due to NC DHHS screening level and has been carried forward with subsequent evaluations. Samples were COI 4 receptor recepwell results. Use NCDHHS screening ning value. analyzed for Hexavalent Chromium in select groundwater monitoring wells, and further Cr(VI) evaluation may take place based on the results of each site respectively. CAP Part 1, Section 1.9.2 states that Cr(VI) is included in the COI list. Need to evaluate vanadium and strontium at every site to show Vanadium has been considered across the sites in CSA reporting. Strontium was not included in the CSA COI 5 differences between background concentrations and potential tables, however strontium data was collected with other constituents, including vanadium, and is source -related concentrations. presented in the CSA Supplement 2. COI - Receptors 6 Add evaluation of receptor wells in CAP. Water supply wells are shown on Figure 1-3 in the CSA Supplement 2 along with analytical results facilitating the interpretation of receptor water quality relative to site water quality. Private and public water supply wells sampled should be shown Water supply wells are shown on Figure 1-3 in the CSA Supplement 2 along with analytical results COI - Receptors 7 on a map with zoom in boxes showing concentration results even facilitating the interpretation of receptor water quality relative to site water quality. if below 2L. COI - Receptors 8 Add table with all receptor well results. Water supply wells are shown on Figure 1-3 in the CSA Supplement 2 along with analytical results facilitating the interpretation of receptor water quality relative to site water quality. All private receptor wells shown on figures (use or add DEQ designations). All water supply wells are shown on Figure 1-3. Those water supply wells that can be shown in the COI - Receptors 9 Show results for detection constituents. viewports of the the potentiometric surface and isoconcentration figures in the CSA Supplement 2 are also included. A table of analytical results, including strontium, is included on Figure 1-3. Add strontium. Add total uranium and Ra226+228. DEQ considers radionuclides to be a driver of alpha activity in the ash basins. Sample the following locations both below ash ponds and other downgradient areas Select wells located downstream and along transects were sampled for these constituents in the CSA and COI where other constituent concentrations are high: Post-CSA sampling periods. At the time of the CSA Supplement 2, the analytical results from Round 5 had 10 Downgradient monitoring well locations, at locations with been received and upon review, were recommended for re -issue prior to completing review and inclusion exceedances, and at background locations. in the CSA Supplement 2. Upon receipt, these data will be provided in a subsequent submittal. Uranium and Ra226+228 may be included in NPDES monitoring. List Federal MCL as standard for Ra 226-228 and uranium. Source Characterization 11 Address soils as being primary and secondary sources —address in A separate risk assessment has been provided subsequent to the CSA report by Duke Energy via Haley & CAP and CSA supplement. Aldritch. Source Characterization Describe how geochemical conditions may affect release of 12 Discussion of geochemical conditions were provided in CAP Part 2 with geochemical modeling results. naturally occurring constituents such as iron and manganese. CSA Supplement 2 Table 2-1: Responses to Global NCDEQ Comments Source Characterization 13 Soil to be identified as secondary source — due to leaching of ash A separate risk assessment has been provided subsequent to the CSA report by Duke Energy via Haley & onto unsaturated soil. Aldritch. Background soil concentrations need to be evaluated. Native soils Background 14 may be a source based on geochemical conditions in/beneath the Proposed Provisional Background Concentrations or PPBCs are discussed in CAP Part 1, Section 2. The ash ponds. Need to address background soil conditions and approach to refine PPBCs when additional data is available is presented in CSA Supplement 2, Section 4. relationship to observed 2L exceedances. "Proposed Provisional Background Concentrations" or PPBCs is the terminology used for statistically Background 15 Provide "provisional estimates" of background if there are determined background concentrations in the CAP reporting. PPBCs are discussed in CAP Part 1, Section 2. insufficient numbers of samples for statistics. The approach to refine PPBCs when additional data is available is presented in CSA Supplement 2, Section 4. A similar analysis/evaluation of downgradient soils and their Background 16 relationship to 2L exceedances also needs to be included in the Proposed Provisional Background Concentrations or PPBCs are discussed in CAP Part 1, Section 2. The approach to refine PPBCs when additional data is available is presented in CSA Supplement 2, Section 4. CAP. Background Potential release mechanisms need to be considered in the CAP 17 Discussion of potential migration pathways is discussed in CAP Part 2, Section 3.3 (i.e., migration of leachate beneath the ash basin, etc.). Background determinations. Background concentrations need to "Proposed Provisional Background Concentrations" or PPBCs is the terminology used for statistically be evaluated to determine site -specific constituent concentration determined background concentrations in the CAP reporting. PPBCs are discussed in CAP Part 1, Section 2. Background 18 levels and this evaluation needs to be included in CAP. Use all The approach to refine PPBCs when additional data is available is presented in CSA Supplement 2, Section available historic data from compliance wells and newly installed wells. 4. Background groundwater monitoring wells need to be sampled 2 Background 19 more times before the end of 2015 (samples need to be These samples have been collected. Data from Rounds 2 through 4 was included in the CAP Part 2. speciated). Separate background concentrations need to be determined for "Proposed Provisional Background Concentrations" or PPBCs are discussed in CAP Part 1, Section 2. The Background 20 shallow, intermediate and deep flow layers (as well as any other approach to refine PPBCs when additional data is available is presented in CSA Supplement 2, Section 4. site -specific conditions like wetlands). This approach includes consideration to these calcuations by flow layer. Background 21 Use all available site data (include example background wells PHR, Background data from historical sources was utilized where applicable in the CAP Part 2. FGD, Craig Rd.). Well and Constituents 22 Wells must meet 2C rule requirements; turbidity cannot impact Results from Round 5 sampling are presented in the CSA Supplement 2 and wells with turbidity results results. above 10 NTU are identified so that results may be qualified upon review. Elevated pH and turbidity must be addressed or well must be Duke Energy has installed additional monitoring wells to address concerns with elevated pH and turbidity Well and Constituents 23 redeveloped or replaced. seen when sampling as well as to refine understanding of exceedances. Results from the Round 5, including additional assessment wells, has been included in CSA Supplement 2. Include discussion of pH and turbidity in background well "Proposed Provisional Background Concentrations" or PPBCs are discussed in CAP Part 1, Section 2. The Well and Constituents 24 discussion. approach to refine PPBCs when additional data is available is presented in CSA Supplement 2, Section 4. This approach includes consideration to these calcuations by utilizing viable samples below 10 NTU. "Proposed Provisional Background Concentrations" or PPBCs are discussed in CAP Part 1, Section 2. The Well and Constituents 25 Results above 10 NTU to be removed from data set for statistics. approach to refine PPBCs when additional data is available is presented in CSA Supplement 2, Section 4. This approach includes consideration to these calcuations by utilizing viable samples below 10 NTU. CSA Supplement 2 Table 2-1: Responses to Global NCDEQ Comments Soil Contamination 27 General Resolution delineation of COls are noted on cross sections included in the CSA Supplement 2. anuw tAWFIL of pmn nguleb dew un uu»>eu.wnb. Compare soil results to Preliminary Soil Remediation Goals (PSRG) Where additional soil samples were collected as part of the installation of additional assessment wells, for protection of groundwater standards (POG). those results will be presented to PSRG POG standards. Soil Contamination 28 roIKL vs. rw are issue Tor seiectea constituents; tnis may require uuKe tnergy worKea witn the Taos to reauce the reporting emits. however, iowenng me roircL to Detow ine resampling. FOG was not able to be achieved to date for certain constituents. Soils PSRGs, detection limits above standards is problematic. Soil Contamination 29 Review IHSB Guidelines for Assessment and Cleanup section Duke Energy worked with the labs to reduce the reporting limits. However, lowering the MRL to below the 4.1.1.2 to develop site specific background values for soil, if FOG was not able to be achieved to date for certain constituents. applicable Soil Contamination 30 Cr(VI) is driving risk, use Cr(VI) in review. In the CAP reporting as well as CSA Supplement 2, Cr(VI) is added to the list of Cols in groundwater. Soil Contamination 31 Need to compare soils results to Cr(VI) (not Cr(III)). Soils will be compared to the PSRG POG Cr(VI) standard of 3.8 mg/kg in subsequent reporting, where additional soil samples were collected. Hydrology/geologic controls and the effects on contaminant On June 25, 2015, NCDEQ requested that these geochemical issues be addressed in a Site Conceptual and transport are not discussed in CSA. Discuss Model. This topic was introduced in the CSA and announced that the SCM would be refined as an iterative Hydrologdistribution and Chemical Controls Chemical Controls 32 relative to DO, pH, Eh, etc. It is imperative that this discussion be process in the forthcoming CAP. CAP Part 1 Section 3.2.2 included discussion of general geochemical included as part of CAP #1 as this is requirement of CAMA. The characteristics such as cations/anions, redox potential, solute speciation, and Kd testing. These items were discussion can be refined in CAP #2. further addressed in CAP Part 2 Section 2.4.4, and Section 3.3. On June 25, 2015, NCDEQ requested that these geochemical issues be addressed in a Site Conceptual Model. This topic was introduced in the CSA and announced that the SCM would be refined as an iterative Hydrology/Geology and Discuss how geochemical conditions affect contaminant process in the forthcoming CAP. CAP Part 1 Section 3.2.2 included discussion of general geochemical Chemical Controls 33 distribution? (Geochemical "halo' releasing Mn and Fe). characteristics such as cations/anions, redox potential, solute speciation, and Kd testing. These items are further addressed in CAP Part 2 Section 2.4.4: Site Geochemistry and Influence on COls, which treats spatial distribution of groundwater geochemistry relative to the source area. Hydrology/Geology and 34 Specify where differences exist from LeGrand conceptual model. The CAP Part 2 report states where the model is consistent with LeGrand, specifically in the Groundwater Chemical Controls Migration subsection, and the COI Occurrence and Distribution Section. Groundwater velocities in bedrock and transition zone appear to Hydrology/Geology and Chemical Controls 35 be too high. Verify or correct these values. Describe transmissivity These values were corrected and updated in CAP Part 2 Appendix A. concept versus joint flow velocity. Hydrology/Geology and 36 Explain why one contaminant may be elevated in a particular area. CAP Part 2 Section 3.7 included an expanded discussion of site geochemical controls on contaminant Chemical Controls mobility and migration to address this concern. Hydrology/Geology and 37 Describe how constituents are mobilized or attenuated CAP Part 2 Section 3.7 included an expanded discussion of site geochemical controls on contaminant Chemical Controls . mobility and migration to address this concern. Describe geochemical conditions and mechanisms, and charges, The groundwater model considers linear adsorption (Freundlich adsorption for select COls in the Buck Hydrology/Geology and along flow paths. DEQ considers flow paths to be from the model) for COls (except sulfate and chloride). The adsorption term (Kd) is uniform within the model Chemical Controls 38 maximum concentration for a COI to a receptor or to the domain, including from the active and inactive ash basins/storage (sources) to downgradient monitor wells compliance boundary. and the compliance boundary. CAP Part 2, Appendix B, groundwater model. Hydrology/Geology and 39 Describe nature of sorptive materials present in three-part system Sorption constants and calculations are described in CAP Part 2 Section 4.3, in the methodology subsection Chemical Controls and along flow paths to receptors. CSA Supplement 2 Table 2-1: Responses to Global NCDEQ Comments The groundwater model is setup per source area and then calibrated to concentrations observed in downgradient monitor wells. Calibration to observed concentrations is achieved by adjusting source Describe how boron, sulfate, TDS "islands" are located along flow concentrations within active/inactive ash basins and ash storage areas within the measured values, Hydrology/Geology and adjusting hydraulic conductivity based on reported values, adjusting kd based on lab data, and other chemical Controls 40 paths and how these are considered/incorporated into HGCM and measured hydrogeologic properties. The calibration attempts to match concentrations observed in numerical models. downgradient monitor wells by matching the flow paths and thus the observed COI "islands". The model did not incorporate TDS (boron and sulfate are both included in the groundwater model. CAP Part 2, Appendix B, groundwater model. Hydrology/Geology and Chemical Controls Hydrology/Geology and Chemical Controls Hydrogeologic and Other Geochemical Conceptual Subsurface drainage systems at dike/dams should be shown and 41 potential impacts to fate & transport modeling should be Subsurface drainage systems are shown and discussed in Section 4 of the CSA reports. They are shown in described in in hydrogeologic and geochemical conceptual the CSA Section 4 Figures. models. Pond, river, and lake elevations will be shown on figures where applicable. For example, in the CSA 42 Show measured water levels on ponds, streams, rivers. Supplement 2, these elevations are included on the shallow potentiometric figures, but not on all flow 43 Refined conceptual model needs to be presented in CAP I. Site Conceptual Models were updated and included in the CAP Part 2. Hydrogeologic and Other Geochemical Conceptual Models 44 Hydrogeo and geochemical conceptual models need to be discussed in terms of specific source areas. Include upgradient, source, and downgradient. Develop narrative for each source area and downgradient footprint (flow system recharge/discharge, horizontal flow direction, flow paths emanating from all sides (include map). CAP Part 2 Section 2.4.4 included discussion of geochemical parameters with consideration to whether there are trends upgradient or downgradient from the source. The refined SCM also included flow paths determined across the entire site. Hydrogeologic and Other Explain implications of vertical gradients in recharge and discharge Vertical hydraulic gradients were calculated for Round 2 data, and were included in CAP Part 1. The Geochemical Conceptual Models 45 area in each source area and its downgradient footprint. patterns in vertical gradients are discussed in CAP Part 2 Section 2.3.1.1. Hydrogeologic and Other Include effects f receptor wells in discussion. Also include In CAP Part 2 Appendix C, the issue of pumping wells is discussed. Where appropriate,. pumping wells are Geochemical Conceptual 46 possible impactssfrom basin to receptors in conceptual model included as an influence in the groundwater model. For example, for the DEC Cliffside site, the pumping Models discussions. wells weren't modeled because of the influence of the Broad River. Other DEC sites, such as Allen, Belews Creek, and Buck, the pumping wells were included in the model. Hydrogeologic and Other Site heterogeneities are not adequately explained. Explain existing The groundwater models are being updated and recalibrated including new data as it has becoms available Geochemical Conceptual 47 heterogeneities and implications for fate and transport modeling. as part of the expanded groundwater model domain activities. Uncertainties and limitations will be Models Describe uncertainties and explain impact of uncertainties. presented as part of the results, which are expected to be completed during Fall 2016. Hydrogeologic and Other The groundwater models are being updated and recalibrated including new data as it has becoms available Geochemical Conceptual 48 Explain impact of uncertainties in conceptual model. as part of the expanded groundwater model domain activities. Uncertainties and limitations will be Models presented as part of the results, which are expected to be completed during Fall 2016. Hydrogeologic and Other Geochemical Conceptual 49 Models Hydrogeologic and Other Geochemical Conceptual 50 Models Ensure that streams, wetlands, etc. shown in Section 12 are included on all figures as needed. Include in conceptual model discussions as appropriate. Description of AMEC ecological survey report findings not utilized in report or in figures. Data should be used, shown on figures or not. CAP Part 2 Section 2 figures include wetlands and streams. Ecological data concerning vegetation was included in the CSA Section 12 Risk Assessment and referenced in the Eco-Checklists provided for each site. CSA Supplement 2 Table 2-1: Responses to Global NCDEQ Comments I Type Comment Number Comment Batch geochemical modeling for each of three layers per General Resolution As provided in CAP Part 2 Modeling Appendix B, Model Construction Section, each constituent was Modeling 51 constituent with narrative of what happens along flow path. modeled in one of 7 layers, which fall into the following categories: Ash material, Dike and ash storage Select flow path alignment with MOD PATH. material, Alluvium, M1 Saprolite, M2 Saprolite, Transition Zone, and Fractured bedrock. Describe geochemical conditions and mechanisms, and charges, Modeling 52 along flow paths. DEQ considers flow paths to be from the MODPATH was used to identify and delineate flow paths. This is displayed in CAP Part 2 Modeling Appendix maximum concentration for a COI to a receptor or to the B, Model Calibration in the particle tracking figure. compliance boundary. Model should use highest COPC in source area for model input. The model presented in the CAP Part 2 Appendix B uses variable concentrations in the source areas to Modeling 53 There will be different flow paths as flow path is based on match downgradient concentrations observed in monitor wells. In areas where the flow path from the maximum concentration of COI. source to an elevated observed concentration in a monitor well is observed, the highest measured source concentration is used in the model. Impacts from Fe, Mn are not related to Kd — how will modeling The groundwater model does not address Fe and Mn, however the geochemical modeling report does Modeling 54 treat Fe and Mn as COls (CAP Part 2 Appendix E), and determines the forms they likely exist in under address these constituents? conditions at the respective sites (CAP Part 2 Appendix E Section 2: Pourbaix diagrams). Modeling 55 Groundwater modeling should use site specific Kds. Sorption terms were developed and utilized as part of the groundwater modeling presented in CAP Part 2, Appendix B. Describe Kds and HFO or soil samples in areas not affected by ash. Modeling 56 Explain differences between these Kds and Kds from impacted A uniform Kd value for the groundwater model was utilized as these values are variable from sample to sample, regardless of site location (CAP Part 2, Appendix A, Groundwater Model). areas. Groundwater flow modeling in CAP needs to account for cumulative effect of off -site receptor wells (i.e., water supply The cumulative effect of off -site receptor wells were accounted for in the groundwater modeling (CAP Part wells). Need to come up with some assumptions regarding depth 2 Modeling Appendix B). The yield of these wells was estimated at 400 gpd, which is the average EPA I 57 and yield. CSA reports generally discount potential for upgradient household usage. The groundwater models are being updated and recalibrated including new data as it flow direction resulting from off -site pumping. Model results need has becoms available as part of the expanded groundwater model domain activities, including water supply to be included in the CAP now and revise once results are in from well information. Uncertainities and limitations will be presented as part of the results, which are expected data gap wells that are located to help inform groundwater flow to be completed during Fall 2016. direction near the property boundary. The groundwater model was calibrated to steady-state flow conditions and considered water levels from summer 2015. Historic water levels in the ponds were not modeled. The timing of start of the ash Modeling 58 Address historic water levels in pond in groundwater modeling. operations in different basins was considered in the groundwater model. The groundwater models are being updated and recalibrated including new data as it has becoms available as part of the expanded groundwater model domain activities, including historic water levels. Need to discuss how groundwater model results are incorporated The CAP Part 1 Surface water modeling Appendix details how groundwater model results are incorporated Modeling 59 in surface water model results (including how on -site streams are in surface water model results. incorporated). Modeling 60 Deep rock groundwater flow not well presented relative to off -site Particle flow maps that take into account offsite pumping are presented in the groundwater modeling pumping. This needs to be presented in CAP. Appendix B of the CAP Part 2. Subsurface drainage systems at dike/dams should be shown and Modeling 61 potential impacts to fate & transport modeling should be Subsurface drainage systems are shown and discussed in Section 4 of the CSA reports. considered. CSA Supplement 2 Table 2-1: Responses to Global NCDEQ Comments r— �Type Comment Number Comment Guidelines require — seep, sediment, surface water, receptor well General Resolution CAP Part 2 included chem box maps for seeps, sediments, surface water, and groundwater. Chem boxes for Data Presentation 62 data, results show all COIs (field and results) in chem boxes. receptor wells were not able to be shown spatially for all sampling events, however, Figure 1-3 in the CSA Supplement 2 shows location and analytical results. Data Presentation 63 Show concentrations above PQLs on chem box maps, not just Chem box maps show all detected constituents for detection and assessment monitoring constituents as constituents above 2L. part of the CAP Part 2. Data Presentation 64 Add vertical gradients to figures —plan view. CAP Part 1 Section 3 included figures depicting vertical gradients between shallow and deep wells, and between deep and bedrock wells. Data Presentation 65 Add vertical gradient maps. CAP Part 1 Section 3 includes figures depicting vertical gradients between shallow and deep wells, and between deep and bedrock wells. Data Presentation 66 Develop a potentiometric surface map for the transition zone Deep flow layer wells are used to investigate the transition zone, and potentiometric surfaces figures were wells. developed as part of the CAP Part 2 as well as CSA Supplement 2. Piper diagram figures are in Section 10 of the CSA. Updated piper diagrams utilizing Round 5 data have Data Presentation 67 Show cation -anion balance values on Piper diagrams, remove been included in the CSA Supplement 2 to include only those events with balance differences that are less results with balance differences > 10%. than 10%. Show all receptor wells on figures given the existing figure Figure 1-3 in the CSA Supplement 2 presents all receptor wells and their analytical results. Those water Data Presentation 68 supply wells that can be shown in the viewports of the the potentiometric surface and isoconcentration extents. figures in the CSA Supplement 2 are also included. Data Presentation 69 Need one map with all receptor wells and MWs. Figure 1-3 in the CSA Supplement 2 presents all receptor wells and their analytical results. Data Presentation 70 Show seep results with chem boxes. Seeps and DEQ Seeps were provided in CAP Part 1 Section 2 figures. Data Presentation 71 Show topography on groundwater surface contour maps (add Topography has been included on the potentiometric surface figures provided in CSA Supplement 2. elevation labels to contours). Add geologic data and iso-concentration data (include Kds) on Cross -sections will be expanded with additional assessment monitoring wells for the CSA Supplement 2. Data Presentation 72 cross -sections. These will include lithology, recovery, ROD, where available, as well as the vertical extent of COls Data Presentation 73 Add figure showing pH, Eh, etc. results. CAP Part 1 Section 2 Chem Box figures included field parameters. Data Presentation 74 Add table w/NPDES sample event results. A NPDES sample events results table has been provided in Section 1 of the CSA Supplement 2. Data Presentation 75 Chem box figures for groundwater— add round 2 data as column Round 2 chembox figures were included in CAP Part 2. to right of existing data. Iso contours - Need to address how iso contour lines are shown on figures. Show part of the line as dashed where uncertainty exists Data Presentation 76 (i.e., no downgradient data to help determine extent of iso Isoconcentration maps utilizing Round 5 analytical results, including strontium, where it is a COI, are contour). Depict concentrations above reporting limit. included in CSA Supplement 2. Add iso-contour figure for strontium. Need to show natural resource information (i.e., surface water Data Presentation 77 features, wetland features, heron rookery at Buck, etc.) on "base CAP Part 2 Section 2 figures includes wetlands and streams which were delineated by USACE. Other map" figures. natural resources were included on figures as part of the Eco-Checklist referenced in Section 12 of the CSA. Data Presentation 78 Ensure that streams, wetlands, etc. shown in Section 12 are CAP Part 2 Section 2 figures included wetlands and streams as needed. included on all figures as needed. Data Presentation 79 Modify results tables to include field parameters DOs, Eh, spec Field parameters were included on the CAP Part 2 results tables, referenced in Section 2, as well as the CSA conductance, pH, NTU in all results tables. Supplement 2 results tables, referenced in Section 3. Surface, Groundwater Describe SW hydrology (streams, wetlands) in CAP and how CAP Part 2, Section 3 pertains to the Site Conceptual model, and it discusses surface water and seeps in Discharge 80 relates to seeps in CSM. relation to site source areas. Surface, Groundwater Check for alignment of description of streams and wetlands in CAP Part 2, Section 3 pertains to the Site Conceptual model, and it discusses surface water and seeps in Discharge 81 Section 12. relation to site source areas. CSA Supplement 2 Table 2-1: Responses to Global NCDEQ Comments CSA and CAP site maps include labels of major surface water bodies at each site. In addition, the CSA Surface, Groundwater Discharge 82 Show all surface water features on maps and cross sections. included surface water information in Figure 4-4: Surface Water Bodies. CAP Part 2 included Figure 3-1: Site Conceptual Model, and Figure 3-2: Cross Section with these features. Streamflow measurements have been incorporated into the expanded groundwater model domain Surface, Groundwater Discharge 83 Add wording on stream flow measurements performed. activities. The groundwater models are being updated and recalibrated including new data as it has becoms available and is expected to be completed during Fall 2016. Include non -trespassing recreation users of surface water and In the stand-alone Risk Assessment report, recreational swimmers, boaters, waders, and fishers are Risk Assessment 84 drinking water well receptors. included in the receptors, as are current/future off -site residents. In addition, a separate risk assessment has been provided subsequent to the CSA report by Duke Energy via Haley & Aldritch. Coal ash should be included as primary affected media until it is A separate risk assessment has been provided subsequent to the CSA report by Duke Energy via Haley & Risk Assessment 85 completely removed or otherwise made inaccessible to human Aldritch. contact. Revise Tables 12-1, 12-2, and wording in Section 12. Risk Assessment 86 Expand speciation results discussion with regards to receptors. A separate risk assessment has been provided subsequent to the CSA report by Duke Energy via Haley & Aldritch. Inadequate Data —All Where 2L exceedances intercept rivers/streams implications Vertical hydraulic gradients were calculated for Round 2 data, and were included in CAP Part 1. The Source Areas 87 should be discussed. Discuss vertical gradients for well pairs patterns in vertical gradients are discussed in CAP Part 2 Section 2.3.1.1. adjacent to rivers/streams. Inadequate Data — AII If a MW does not exist between a 2L exceedance and receptor Duke Energy has installed additional monitoring wells to address concerns to refine understanding of 88 (stream and water supply well) additional wells or transport exceedances. Results from the Round 5, including additional assessment wells, has been included in CSA Source Areas modeling is needed to fill data gap. Supplement 2. Inadequate Data —All If uncertainty exists about local flow due to insufficient number or Duke Energy has installed additional monitoring wells to address concerns to refine understanding of 89 placement of wells, then additional wells should be installed. exceedances. Results from the Round 5, including additional assessment wells, has been included in CSA Source Areas Same comment applies for uncertainty on vertical gradients. Supplement 2. CSA Supplement 2 Table 2-2: Total Porosity, Secondary (Effective) Porosity/Specific Yield, and Specific Storage for Lower Hydrostratigraphic Units (TZ and BR) Hydrostratigraphic Unit Secondary (Effective) Porosity / Specific Yield N Total Porosity (%) Specific Storage (1/ft) Transition Zone (TZ) 5.0 - 10.0 5 - 15 1.0E-06 - 2.1 E-05 Bedrock (BR) - Fractured 2.0 - 5.0 5 - 10 < 1.0E-06 Bedrock (BR) - Dense 0-3 0-5 < 1.0E-06 Notes: 1. Ranges based on published values (Domenico and Mifflin, 1965; Singhal and Gupta, 2010). 2. Effective porosity and specific yield are not synonymous. For practical purposes, they may be estimated as approximately equal in value. 3. Table revised 07/13/2016. Allen Steam Station CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: AB-14BR 3/8/2016 N AN-AB-14BR AB-1 R 3/14/2016 N AN-AB-1 R AB-2 3/18/2016 N AN-AB-2 AB-20D 3/17/2016 N AN-AB-20D AB-21 BR 3/18/2016 N AN-AB-21 BR AB-21 D 3/18/2016 N AN-AB-21 D AB-22D 3/21/2016 N AN-AB-22D Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Alkalinity, CO3 N - ug/I 5000 U 5000 U 5000 U 5000 U 93400 70500 5000 U TRG Alkalinity, HCO3 N - ug/I 58700 47900 5400 72900 6000 2500 J 113000 TRG Alkalinity, lab N - ug/I 58700 47900 5400 72900 99500 73000 113000 TRG jAluminum D - ug/I 100 U 100 U 100 U 100 U 230 150 100 U TRG Aluminum T - ug/I 145 228 116 100 U 248 159 100 U TRG Antimony D - ug/I 0.16 J 0.14 J 0.5 U 0.16 J 1.8 2.7 0.13 J TRG Antimony T 1 IMAC ug/I 0.18 J 0.16 J 0.5 U 0.19 J 1.9 2.5 J 0.14 J TRG Arsenic D - ug/I 0.54 0.11 0.1 U 1.2 1.1 0.21 0.11 TRG Arsenic T 10 02L ug/I 0.6 0.12 0.1 U 1.3 1.1 1 U 0.11 TRG Barium D - ug/I 21 55 15 13 6.3 32 71 TRG Barium T 700 02L ug/I 27.9 70.9 15.6 11.6 7.1 33.3 71.4 TRG Beryllium D - ug/I 0.029 J+ 0.1 U 0.078 J+ 0.1 U 0.1 U 0.038 J+ 0.038 J+ TRG Beryllium T 4 ]MAC ug/I 0.011 J+ 0.06 J+ 0.045 J 0.1 U 0.1 U 1 U 0.032 J+ TRG Boron D - ug/I 50 U 50 U 50 U 50 U 50 U 50 U 1600 TRG Boron T 700 02L ug/I 50 U 50 U 50 U 50 U 50 U 50 U 1480 TRG Cadmium D - ug/I 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U TRG Cadmium T 2 02L ug/I 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.8 U 0.08 U TRG Calcium T - ug/I 17100 43700 260 21000 11400 28100 39000 TRG Chloride N 250000 02L ug/I 2700 880 J 2700 3900 14800 13500 15400 TRG Chromium D - ug/I 0.25 J+ 4.6 0.36 J+ 1.3 J+ 22.3 12.1 0.21 J+ TRG Chromium T 10 02L ug/I 0.5 J+ 5.9 0.29 J+ 0.97 J+ 22.3 11.4 J+ 0.48 J+ TRG Chromium 6+ T 0.07 DHHS ug/I 0.15 4.1 0.15 0.69 24.3 11.2 0.03 U TRG Cobalt D - ug/I 0.017 J 0.16 J+ 0.33 0.024 J 0.11 0.15 0.56 TRG Cobalt T 1 ]MAC ug/I 0.064 J 0.25 J+ 0.25 0.02 J+ 0.11 0.1 J 0.54 TRG Copper D - ug/I 1.7 1.5 J+ 1.4 J+ 0.37 J 0.94 J+ 0.57 J+ 0.19 J+ TRG Copper T 1000 02L ug/I 0.5 U 0.41 J+ 0.2 J+ 0.45 J+ 0.94 J+ 4.1 J 0.27 J+ TRG Iron D - ug/I 50 U 50 U 50 U 50 U 50 U 50 U 680 TRG Iron T 300 02L ug/I 98.7 253 114 50 U 50 U 50 U 654 TRG Lead D - ug/I 0.21 0.16 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U TRG Lead T 15 02L ug/I 0.1 U 0.11 0.1 U 0.1 U 0.1 U 1 U 0.1 U TRG Magnesium T - ug/I 4210 11000 958 2350 100 U 100 U 12200 TRG Manganese D - ug/I 5 U 4 J 21 5 U 5 U 5 U 190 TRG Manganese T 50 02L ug/I 3 J 12 20.2 5 U 5 U 5 U 200 TRG Mercury D - ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG IMercury T 1 02L ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG Methane N - ug/I 1.3 J+ 1.5 J+ 1.4 J+ 1.8 J+ 2.8 J+ 2.2 J+ 10 J+ TRG Molybdenum D - ug/I 5.3 0.13 J 0.5 U 5.6 17.6 4.4 1.5 TRG Molybdenum T - ug/I 5.6 0.13 J 0.5 U 6 17.2 3.9 J 1.7 TRG Nickel D - ug/I 0.5 U 2.9 1.9 0.57 1 0.64 2.1 TRG Nickel T 100 02L ug/I 0.5 U 3.2 0.54 0.5 U 0.52 5 U 2.3 TRG Nitrogen, NO2 plus NO3 N - ug/I 2400 140 17 J+ 810 270 310 20 U TRG Potassium T - ug/I 4480 J 5000 U 5000 U 3430 J 18200 11200 3570 J TRG Selenium D - ug/I 0.5 U 2.3 0.5 U 0.5 U 1.4 0.75 0.5 U TRG Selenium T 20 02L ug/I 0.5 U 2.1 0.5 U 0.5 U 1.5 5 U 0.5 U TRG Sodium T - ug/I 8960 7930 2580 J 12600 62400 23200 13700 TRG Strontium D - ug/I 94 410 4.4 J 100 180 280 380 TRG Strontium T - ug/I 95.8 494 4 J 93.8 185 279 398 TRG Sulfate N 250000 02L ug/I 4600 J+ 126000 870 J 9600 59800 33900 37300 TRG Sulfide N - ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U TRG Thallium D - ug/] 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.015 J 0.1 U TRG Thallium T 0.2 IMAC ug/I 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 1 U 0.1 U Allen Steam Station Page 1 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: AB-14BR 3/8/2016 N AN-AB-14BR AB-1 R 3/14/2016 N AN-AB-1 R AB-2 3/18/2016 N AN-AB-2 AB-20D 3/17/2016 N AN-AB-20D AB-21 BR 3/18/2016 N AN-AB-21 BR AB-21 D 3/18/2016 N AN-AB-21 D AB-22D 3/21/2016 N AN-AB-22D Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Total Dissolved Solids N 500000 02L ug/I 128000 275000 25000 U 121000 239000 177000 248000 J+ TRG Total Organic Carbon N - ug/I 710 J 1000 U 1000 U 10600 1200 2100 690 J TRG Total Suspended Solids N - ug/I 8900 4200 2500 U 2500 U 5000 5000 U 2500 U TRG jUranium, Natural T - ug/I -- 5 U -- -- -- -- 0.41 J TRG Vanadium D - ug/I 11.2 2.1 0.3 U 14.5 22.8 10.1 2.4 TRG Vanadium T 0.3 ]MAC ug/I 12.2 2.3 0.29 J+ 15.7 22.7 9.6 2.8 TRG Zinc D - ug/I 10 U 3.8 J 5.1 J 10 U 10 U 10 U 10 U TRG Zinc T 1000 02L ug/I 10 U 5 J+ 3.9 J 10 U 5.1 J 10 U 10 U FRS Dissolved Oxygen N - mg/I 2.3 5.3 2.28 1 1.66 0.91 0.23 FRS 10xidation Reduction Potential N - mV 37 214.8 344.1 53.1 -58.1 -108.1 -38.2 FRS pH N 6.5-8.5 02L SU 8.7 6.1 5.4 9.09 11.28 11.2 6.54 FRS Specific Conductivity N - PS/Cm 161.2 390.3 30.2 189 543.3 426.9 355.1 FRS Temperature N - Deg C 17.3 21.2 14.9 19.6 17.1 17.3 14.4 FRS Turbidity, field N - NTU 1 3 6.1 3.33 0.68 1.62 1.97 2.42 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 2 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: AB-22S 3/21/2016 N AN-AB-22S AB-23BRU 3/17/2016 N AN-AB-23D AB-24D 3/17/2016 N AN-AB-24D AB-25BR 3/17/2016 N AN-AB-25BR AB-25BRU 3/17/2016 N AN-AB-25BRU AB-26D 3/21/2016 N AN-AB-26D AB-26S 3/21/2016 N AN-AB-26S Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Alkalinity, CO3 N - ug/I 5000 U 136000 5000 U 109000 79700 77900 5000 U TRG Alkalinity, HCO3 N - ug/I 21400 5000 U 60300 243000 40000 13300 28200 TRG Alkalinity, lab N - ug/I 21400 262000 60300 351000 120000 91200 28200 TRG jAluminum D - ug/I 50 J 1700 2700 230 200 100 U 58 J TRG Aluminum T - ug/I 282 1650 2130 240 225 114 168 TRG Antimony D - ug/I 0.39 J 1.2 J 3.7 J 25 U 5 U 1.2 0.5 U TRG Antimony T 1 IMAC ug/I 0.64 1.2 J 1.2 J 25 U 5 U 2.1 0.5 U TRG Arsenic D - ug/I 0.29 3.2 1.2 5 U 3 0.92 0.15 TRG Arsenic T 10 02L ug/I 1 0.65 2.9 1 U 5 U 2.8 1.3 0.23 TRG Barium D - ug/I 53 12 78 190 11 16 140 TRG Barium T 700 02L ug/I 56 10.8 74.6 178 11 16.3 147 TRG Beryllium D - ug/I 0.62 1 U 1 U 5 U 0.19 J 0.06 J+ 0.1 U TRG Beryllium T 4 IMAC ug/I 0.9 1 U 1 U 5 U 1 U 0.4 0.1 U TRG Boron D - ug/I 50 U 50 U 50 U 50 U 50 U 210 920 TRG Boron T 700 02L ug/I 50 U 29.1 J 50 U 50 U 50 U 197 989 TRG Cadmium D - ug/I 0.14 0.8 U 0.8 U 4 U 0.8 U 1.4 0.054 J TRG Cadmium T 2 02L ug/I 0.092 0.8 U 0.8 U 4 U 0.8 U 0.08 U 0.08 U TRG Calcium T - ug/I 2880 53000 111000 115000 22000 4020 20000 TRG Chloride N 250000 02L ug/I 9700 4700 10600 9300 7500 5700 9600 TRG Chromium D - ug/I 0.37 J+ 18.4 5.9 18.9 J 0.93 J+ 2.7 J+ 1 TRG Chromium T 10 02L ug/I 0.91 J+ 16.6 1.5 J+ 18.4 J 5 U 2.1 J+ 2.4 TRG Chromium 6+ T 0.07 DHHS ug/I 0.03 U 18.5 11.5 21 0.11 1.5 J- 0.2 TRG Cobalt D - ug/I 24.2 1 U 1 U 5 U 0.21 J 0.043 J+ 1.4 TRG Cobalt T 1 IMAC ug/I 29.3 1 U 1 U 5 U 0.13 J+ 0.19 1.3 TRG Copper D - ug/I 6.7 2 J 1.7 J 25 U 5 U 0.64 J+ 0.82 TRG Copper T 1000 02L ug/I 47.5 2.3 J+ 5 U 25 U 5 U 23.3 0.34 J+ TRG Iron D - ug/I 1400 50 U 50 U 50 U 50 U 50 U 470 TRG Iron T 300 02L ug/I 2650 50 U 27.5 J+ 50 U 50 U 136 635 TRG Lead D - ug/I 0.1 U 1 U 1 U 5 U 1 U 0.1 U 0.1 U TRG Lead T 15 02L ug/I 0.3 1 U 1 U 5 U 1 U 0.13 0.092 J TRG Magnesium T - ug/I 1770 100 U 100 U 100 U 1200 656 9340 TRG Manganese D - ug/I 850 5 U 5 U 5 U 3 J 11 340 TRG Manganese T 50 02L ug/I 1030 5 U 5 U 5 U 3.8 J 9.5 324 TRG Mercury D - ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG Mercury T 1 02L ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG Methane N - ug/I 17.7 3 J+ 3.8 J+ 1.9 J+ 2.3 J+ 1.9 J+ 106 TRG Molybdenum D - ug/I 0.13 J 18.9 26.6 18.9 J 5.5 5.9 0.14 J TRG Molybdenum T - ug/I 0.78 18 5 20 J 5.7 7.3 0.13 J TRG Nickel D - ug/I 2.5 5 U 5 U 25 U 5 U 1 3.9 TRG Nickel T 100 02L ug/I 2.6 5 U 5 U 25 U 5 U 0.5 U 4.3 TRG Nitrogen, NO2 plus NO3 N - ug/I 20 U 380 250 300 10 J+ 120 20 U TRG Potassium T - ug/I 5000 U 17300 23400 61900 18000 44000 5000 U TRG Selenium D - ug/I 0.5 U 5 U 5 U 25 U 5 U 0.5 U 0.5 U TRG Selenium T 20 02L ug/I 0.5 U 5 U 5 U 25 U 5 U 0.44 J 0.5 U TRG Sodium T - ug/I 12800 77000 46900 29200 37000 35100 14000 TRG Strontium D - ug/I 45 670 970 1400 250 220 230 TRG Strontium T - ug/I 48.7 618 880 1280 237 252 245 TRG Sulfate N 250000 02L ug/I 5800 51000 14600 43300 29500 35000 84400 TRG Sulfide N - ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U TRG IThallium D - I ug/I 0.055 J 1 U 1 U 5 U 0.18 J 0.1 U 0.1 U TRG IThalliurn T 0.2 1 IMAC ug/I 0.043 J 1 U 1 U 5 U 1 U 0.1 U 0.1 U Allen Steam Station Page 3 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: AB-22S 3/21/2016 N AN-AB-22S AB-23BRU 3/17/2016 N AN-AB-23D AB-24D 3/17/2016 N AN-AB-24D AB-25BR 3/17/2016 N AN-AB-25BR AB-25BRU 3/17/2016 N AN-AB-25BRU AB-26D 3/21/2016 N AN-AB-26D AB-26S 3/21/2016 N AN-AB-26S Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Total Dissolved Solids N 500000 02L ug/I 26000 J+ 395000 364000 478000 227000 218000 J+ 209000 J+ TRG Total Organic Carbon N - ug/I 30900 1800 J+ 2200 1200 J+ 7500 J+ 650 J 1000 U TRG Total Suspended Solids N - ug/I 12300 2500 U 14600 3200 2600 5800 9000 TRG jUranium, Natural T - ug/I 0.12 J -- -- -- -- 0.2 J 0.5 U TRG Vanadium D - ug/I 0.31 33.4 20.5 16.8 18.9 7.3 0.34 TRG Vanadium T 0.3 ]MAC ug/I 1.3 31.2 4.5 17 19.7 11.6 0.57 TRG Zinc D - ug/I 40 10 U 10 U 3.3 J 10 U 10 U 10 TRG Zinc T 1000 02L ug/I 64 3.1 J+ 4.9 J+ 12 J+ 10 U 22.7 J+ 14.4 J+ FRS Dissolved Oxygen N - mg/I 0.6 2.13 1.5 2.1 0.28 0.7 0.2 FRS 10xidation Reduction Potential N - mV 138.9 -81.7 -86.3 -99.8 -135.9 58.6 151.2 FRS pH N 6.5-8.5 02L SU 5.4 11.59 11.8 11.98 10.08 10.6 5.7 FRS Specific Conductivity N - PS/cm 106.7 1243 1898 1968 334.8 332.6 288.4 FRS Temperature N - Deg C 11.7 23.1 22 16.7 16 19.2 20.1 FRS Turbidity, field N - NTU 9.2 0.98 8.3 0.98 1.75 9.42 9.7 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 4 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: AB-27D 3/21/2016 N AN-AB-27D AB-28D 3/17/2016 N AN-AB-28D AB-29D 3/17/2016 N AN-AB-29D AB-2D 3/18/2016 N AN-AB-2D AB-30D 3/16/2016 N AN-AB-30D AB-31 D 3/16/2016 N AN-AB-31 D AB-31 S 3/16/2016 N AN-AB-31 S Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Alkalinity, CO3 N - ug/I 5000 U 26800 5000 U 5000 U 5000 U 52000 5000 U TRG Alkalinity, HCO3 N - ug/I 34200 72900 59800 28900 47300 99200 5000 U TRG Alkalinity, lab N - ug/I 34200 99700 59800 28900 47300 151000 5000 U TRG jAluminum D - ug/I 100 U 100 U 100 U 100 U 100 U 870 100 U TRG Aluminum T - ug/I 137 100 U 342 100 U 99.6 J 1020 334 TRG Antimony D - ug/I 5 U 5 U 5 U 0.5 U 0.14 J 6.1 0.5 U TRG Antimony T 1 IMAC ug/I 5 U 5 U 5 U 0.5 U 0.16 J 5.9 0.5 U TRG Arsenic D - ug/I 1 U 0.79 J 0.64 J 0.083 J 0.3 0.18 0.058 J TRG Arsenic T 10 02L ug/I 1 U 1.1 1.1 0.056 J 0.3 1 U 0.12 TRG Barium D - ug/I 66 32 48 28 38 16 18 TRG Barium T 700 02L ug/I 69.3 30.3 49.3 27.8 39 17.2 21.4 TRG Beryllium D - ug/I 1 U 1 U 1 U 0.028 J+ 0.038 J 0.1 U 0.019 J TRG Beryllium T 4 IMAC ug/I 1 U 1 U 1 U 0.012 J 0.1 U 1 U 0.057 J TRG Boron D - ug/I 1300 33 J 230 50 U 50 U 290 2000 TRG Boron T 700 02L ug/I 1400 40.1 J 244 50 U 50 U 295 J+ 1870 TRG Cadmium D - ug/I 0.8 U 0.8 U 0.8 U 0.08 U 0.08 U 0.08 U 0.12 TRG Cadmium T 2 02L ug/I 0.8 U 0.8 U 0.8 U 0.08 U 0.08 U 0.8 U 0.22 TRG Calcium T - ug/I 37000 24700 26900 5560 14800 58600 34600 TRG Chloride N 250000 02L ug/I 9000 5400 6300 1400 3400 7900 8100 TRG Chromium D - ug/I 5 U 5 U 2.3 J+ 2.4 0.6 1.5 0.99 TRG Chromium T 10 02L ug/I 1.6 J+ 5 U 2.6 J+ 2 J+ 0.8 J+ 5.8 3 J+ TRG Chromium 6+ T 0.07 DHHS ug/I 0.012 J 0.087 0.5 1.9 0.15 0.033 0.12 TRG Cobalt D - ug/I 0.47 J 1 U 0.41 J 0.015 J 0.36 0.034 J 0.066 J TRG Cobalt T 1 IMAC ug/I 0.51 J 0.15 J 1.6 0.1 U 0.44 0.26 J 0.19 TRG Copper D - ug/I 5 U 5 U 4.6 J 1 J+ 0.99 0.36 J 0.3 J TRG Copper T 1000 02L ug/I 5 U 5 U 3.4 J 0.34 J+ 1.6 1.8 J 0.37 J TRG Iron D - ug/I 200 50 U 50 U 50 U 50 U 50 U 40 J TRG Iron T 300 02L ug/I 281 50 U 482 50 U 111 126 348 TRG Lead D - ug/I 1 U 1 U 1 U 0.1 U 0.1 U 0.1 U 0.1 U TRG Lead T 15 02L ug/I 1 U 1 U 1 U 0.1 U 0.1 U 1 U 0.1 U TRG Magnesium T - ug/I 9540 3080 6160 1530 4200 161 4740 TRG Manganese D - ug/I 120 3 J 17 5 U 14 5 U 23 TRG Manganese T 50 02L ug/I 127 3.3 J+ 33.9 5 U 16.7 3.5 J 29.2 TRG Mercury D - ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG Mercury T 1 02L ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG Methane N - ug/I 1.3 J+ 2.1 J+ 1.4 J+ 1.6 J+ 1.6 J+ 5.4 J+ 135 TRG Molybdenum D - ug/I 5 U 2.4 J 5 U 0.5 U 0.38 J 13.3 0.5 U TRG Molybdenum T - ug/I 5 U 3.4 J 5 U 0.5 U 0.42 J 12.8 0.5 U TRG Nickel D - ug/I 5 U 5 U 5 U 0.8 1.5 1.1 0.86 TRG Nickel T 100 02L ug/I 5 U 5 U 5.5 J+ 0.61 0.71 J+ 5 U 1.2 TRG Nitrogen, NO2 plus NO3 N - ug/I 24 120 320 130 250 20 U 20 U TRG Potassium T - ug/I 3460 J 17100 3190 J 5000 U 5000 U 8760 5000 U TRG Selenium D - ug/I 5 U 5 U 5 U 0.5 U 0.5 U 2.5 0.5 U TRG Selenium T 20 02L ug/I 5 U 5 U 5 U 0.5 U 0.5 U 5 U 0.5 U TRG Sodium T - ug/I 14200 19000 12200 5400 10800 26800 13400 TRG Strontium D - ug/I 390 270 230 81 140 310 260 TRG Strontium T - ug/I 412 263 228 74.3 148 335 285 TRG Sulfate N 250000 02L ug/I 117000 22100 45900 640 J 19700 37500 118000 TRG Sulfide N - ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U TRG IThallium D - I ug/I 1 U 1 U 1 U 0.1 U 0.1 U 0.1 U 0.1 U TRG IThalliurn I T 1 0.2 IMAC ug/I 0.2 J 0.2 J 1 U 0.1 U 0.1 U 1 U 0.1 U Allen Steam Station Page 5 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: AB-27D 3/21/2016 N AN-AB-27D AB-28D 3/17/2016 N AN-AB-28D AB-29D 3/17/2016 N AN-AB-29D AB-2D 3/18/2016 N AN-AB-2D AB-30D 3/16/2016 N AN-AB-30D AB-31 D 3/16/2016 N AN-AB-31 D AB-31 S 3/16/2016 N AN-AB-31 S Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Total Dissolved Solids N 500000 02L ug/I 302000 153000 78000 65000 115000 230000 192000 TRG Total Organic Carbon N - ug/I 8300 10600 1000 U 1000 U 1000 U 1900 1000 U TRG Total Suspended Solids N - ug/I 4900 2500 U 5600 2500 U 2600 14900 J+ 19100 J+ TRG jUranium, Natural T - ug/I -- -- -- -- -- 5 U 5 U TRG Vanadium D - ug/I 3 U 11.6 8.4 2.8 11.7 10.8 0.71 TRG Vanadium T 0.3 ]MAC ug/I 1.1 J 11.2 9.4 2.3 12.1 12 2.6 TRG Zinc D - ug/I 8.7 J 10 U 7.8 J+ 35 14 J+ 3.4 J+ 4.3 J+ TRG Zinc T 1000 02L ug/I 13.6 J+ 10 U 8.9 J 4.2 J 18.4 6.7 J+ 6.3 J+ FRS Dissolved Oxygen N - mg/I 0.1 0.4 0.3 4.14 0.65 0.2 0.1 FRS 10xidation Reduction Potential N - mV -1.7 -13.2 55.4 222.6 65 -149.9 91 FRS pH N 6.5-8.5 02L SU 6.2 9.4 7.1 6.1 6.87 11.3 6 FRS Specific Conductivity N - PS/cm 384.1 279 248.1 66.7 158.3 777 316.3 FRS Temperature N - Deg C 17.9 19.5 25.4 16.2 19.1 21.1 21.3 FRS Turbidity, field N - NTU 1 1.8 0.4 9 0.91 2.73 85 9.7 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 6 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: AB-32D 3/16/2016 N AN-AB-32D AB-32S 3/16/2016 N AN-AB-32S AB-33D 3/17/2016 N AN-AB-33D AB-33D 3/17/2016 FD AN-AB-33D-FD AB-33S 3/16/2016 N AN-AB-33S AB-34D 3/16/2016 N AN-AB-34D AB-34S 3/16/2016 N AN-AB-34S Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Alkalinity, CO3 N - ug/I 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U TRG Alkalinity, HCO3 N - ug/I 65300 32500 80700 86800 120000 58200 111000 TRG Alkalinity, lab N - ug/I 65300 32500 80700 86800 120000 58200 111000 J TRG jAluminum D - ug/I 100 U 100 U 100 U 100 U 110 100 U 100 U TRG Aluminum T - ug/I 207 100 U 138 1190 228 100 U 218 TRG Antimony D - ug/I 0.5 U 0.12 J 5 U 5 U 1.1 0.5 U 0.5 U TRG Antimony T 1 IMAC ug/I 0.5 U 0.1 J 5 U 5 U 1.6 J 0.5 U 0.5 U TRG Arsenic D - ug/I 0.18 0.44 1 U 1 U 0.34 0.24 0.4 TRG Arsenic T 10 02L ug/I 1 0.2 0.54 1 U 1 U 0.4 J 0.26 0.47 TRG Barium D - ug/I 39 18 44 44 18 20 46 TRG Barium T 700 02L ug/I 43.7 17.1 37.5 J 56.9 J 22.4 20.6 46.4 TRG Beryllium D - ug/I 0.019 J 0.02 J 1 U 1 U 0.41 0.093 J 0.1 U TRG Beryllium T 4 IMAC ug/I 0.054 J 0.1 U 1 U 0.13 J+ 1.8 0.1 U 0.1 U TRG Boron D - ug/I 480 50 U 140 140 750 50 U 250 TRG Boron T 700 02L ug/I 483 50 U 168 155 768 50 U 252 TRG Cadmium D - ug/I 0.08 U 0.08 U 0.8 U 0.8 U 1.7 0.08 U 0.08 U TRG Cadmium T 2 02L ug/I 0.08 U 0.08 U 0.8 U 0.8 U 2.2 0.08 U 0.08 U TRG Calcium T - ug/I 20900 5500 17800 20400 115000 14200 41600 TRG Chloride N 250000 02L ug/I 5100 8600 2000 2000 6100 1700 5600 TRG Chromium D - ug/I 1 0.6 5 U 1 J+ 1 J+ 0.97 0.52 TRG Chromium T 10 02L ug/I 2 J+ 1.2 J+ 3.5 J+ 5.1 J+ 4.3 J 1 J+ 0.37 J+ TRG Chromium 6+ T 0.07 DHHS ug/I 0.015 J 0.049 0.03 U 0.03 U 0.03 U 0.53 0.15 U TRG Cobalt D - ug/I 0.32 17.1 0.19 J 0.21 J 36.4 0.033 J 1.2 TRG Cobalt T 1 IMAC ug/I 0.58 17.1 0.22 J 1.1 42.2 0.034 J+ 1.5 TRG Copper D - ug/I 0.4 J 0.62 5 U 5 U 18.9 0.55 0.31 J TRG Copper T 1000 02L ug/I 0.63 0.24 J 5 U 7.4 21.8 0.22 J 0.35 J TRG Iron D - ug/I 100 13200 130 110 6200 50 U 83000 TRG Iron T 300 02L ug/I 245 14300 289 J 1880 J 5260 64.2 83200 TRG Lead D - ug/I 0.1 U 0.1 U 1 U 1 U 0.1 U 0.1 U 0.1 U TRG Lead T 15 02L ug/I 0.1 U 0.1 U 1 U 1 U 1 U 0.1 U 0.1 U TRG Magnesium T - ug/I 5260 3280 3020 3600 34600 3140 14500 TRG Manganese D - ug/I 18 3800 130 130 3200 5 U 4500 TRG Manganese T 50 02L ug/I 21.3 3940 137 J 191 J 3160 3 J 4530 TRG Mercury D - ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG IMercury T 1 02L ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG Methane N - ug/I 3.9 J+ 4050 1.5 J+ 1.4 J+ 8.7 J+ 1.8 J+ 46.4 TRG Molybdenum D - ug/I 0.81 0.5 U 2.2 J 2.4 J 1.7 1.1 0.5 U TRG Molybdenum T - ug/I 0.87 0.11 J 2.4 J 2.7 J 1.5 J 1.2 0.5 U TRG Nickel D - ug/I 0.86 1.3 5 U 5 U 44.5 1.2 1.4 TRG Nickel T 100 02L ug/I 1.4 1.7 5 U 5 U 55 0.5 U 0.5 U TRG Nitrogen, NO2 plus NO3 N - ug/I 160 20 U 350 330 2400 500 20 U TRG Potassium T - ug/I 4430 J 3620 J 9140 11100 27900 3610 J 10200 TRG Selenium D - ug/I 0.5 U 0.5 U 5 U 5 U 72.3 0.5 U 0.5 U TRG Selenium T 20 02L ug/I 0.5 U 0.5 U 5 U 5 U 88.4 0.5 U 0.33 J TRG Sodium T - ug/I 11100 4170 J 15300 16100 13100 7920 5660 TRG Strontium D - ug/I 180 28 260 270 2000 120 830 TRG Strontium T - ug/I 196 30.4 248 294 2180 124 835 TRG Sulfate N 250000 02L ug/I 24000 2500 4900 5300 386000 2500 82100 TRG Sulfide N - ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U TRG Thallium D - ug/I 0.1 U 0.097 J 1 U 1 U 5.1 0.1 U 0.1 U TRG IThalliurn T 1 0.2 IMAC I ug/I 0.1 U 0.075 J 1 U 1 U 5.7 0.1 U 0.1 U Allen Steam Station Page 7 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: AB-32D 3/16/2016 N AN-AB-32D AB-32S 3/16/2016 N AN-AB-32S AB-33D 3/17/2016 N AN-AB-33D AB-33D 3/17/2016 FD AN-AB-33D-FD AB-33S 3/16/2016 N AN-AB-33S AB-34D 3/16/2016 N AN-AB-34D AB-34S 3/16/2016 N AN-AB-34S Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Total Dissolved Solids N 500000 02L ug/I 140000 43000 130000 148000 711000 35000 242000 TRG Total Organic Carbon N - ug/I 1000 U 1000 U 1000 U 14900 1000 U 1000 U 740 J TRG Total Suspended Solids N - ug/I 11200 J+ 3500 J+ 3200 31400 13900 2500 U 43500 TRG jUranium, Natural T - ug/I 5 U 0.5 U 0.5 U 0.18 J 5 U -- -- TRG Vanadium D - ug/I 5.6 0.3 U 3.3 3.6 0.076 J 12.6 0.3 U TRG Vanadium T 0.3 ]MAC ug/I 6.7 0.096 J+ 3.8 7.4 0.8 J+ 13 0.25 J+ TRG Zinc D - ug/I 10 U 7.9 J+ 10 U 10 U 120 10 U 10 U TRG Zinc T 1000 02L ug/I 3.1 J+ 8.7 J+ 3.6 J 6.6 J 159 3.3 J 10 U FRS Dissolved Oxygen N - mg/I 0.3 0.5 0.2 0.2 0.4 2.28 0.18 FRS 10xidation Reduction Potential N - mV -4.8 -3.1 -51 -51 78.8 16.1 -69.1 FRS pH N 6.5-8.5 02L SU 6.7 5.9 7.5 7.5 5.8 7.28 6.35 FRS Specific Conductivity N - PS/cm 215.2 174 185 185 977 130.4 637 FRS Temperature N - Deg C 25 20.2 18.5 18.5 27.4 21.3 19.7 FRS Turbidity, field N - NTU 1 9.4 8.1 5.6 5.6 9.2 0.72 9.07 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 8 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: AB-35BR 3/16/2016 N AN-AB-35BR AB-35D 3/16/2016 N AN-AB-35D AB-36S 3/18/2016 N AN-AB-36S AB-36D 3/18/2016 N AN-AB-36D AB-36D 3/18/2016 FD AN-AB-36D-FD AB-37D 3/18/2016 N AN-AB-37D AB-38D 3/18/2016 N AN-AB-38D Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Alkalinity, CO3 N - ug/I 16800 39100 5000 U 5000 U 5000 U 5000 U 5000 U TRG Alkalinity, HCO3 N - ug/I 78000 54400 257000 64800 63300 59600 141000 TRG Alkalinity, lab N - ug/I 94800 93400 257000 64800 63300 59600 141000 TRG jAluminum D - ug/I 100 U 130 100 U 100 U 100 U 100 U 100 U TRG Aluminum T - ug/I 100 U 105 100 U 65.4 J 77 J 118 100 U TRG Antimony D - ug/I 3.4 4.5 0.5 U 0.5 U 0.5 U 0.1 J 0.5 U TRG Antimony T 1 IMAC ug/I 2.9 3.7 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U TRG Arsenic D - ug/I 1.9 1.3 680 0.081 J 0.32 0.26 0.24 TRG Arsenic T 10 02L ug/I 1 1.9 1.3 871 0.37 0.36 0.3 0.24 TRG Barium D - ug/I 13 17 780 31 31 24 130 TRG Barium T 700 02L ug/I 13.3 18.7 916 34.5 34.3 27.9 148 TRG Beryllium D - ug/I 0.1 U 0.038 J 0.023 J+ 0.015 J+ 0.1 U 0.1 U 0.1 U TRG Beryllium T 4 IMAC ug/I 0.1 U 0.1 U 0.053 J+ 0.1 U 0.1 U 0.02 J+ 0.022 J+ TRG Boron D - ug/I 50 U 50 U 380 50 U 50 U 50 U 50 U TRG Boron T 700 02L ug/I 32.5 J 30 J 468 50 U 50 U 50 U 50 U TRG Cadmium D - ug/I 0.08 U 0.08 U 0.08 U 0.19 0.08 U 0.08 U 0.08 U TRG Cadmium T 2 02L ug/I 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U TRG Calcium T - ug/I 30900 22800 58300 16600 16300 17400 29800 TRG Chloride N 250000 02L ug/I 10700 7200 2900 2100 2100 4400 4000 TRG Chromium D - ug/I 5.3 5.8 0.21 J+ 0.22 J+ 1.7 0.31 J+ 0.24 J+ TRG Chromium T 10 02L ug/I 5.3 J+ 5.5 J+ 0.32 J+ 0.78 J+ 0.91 J+ 0.35 J+ 0.16 J+ TRG Chromium 6+ T 0.07 DHHS ug/I 5.5 5.4 0.03 U 0.056 0.086 J- 0.089 0.03 U TRG Cobalt D - ug/I 0.12 0.045 J 0.44 24.2 0.075 J 0.023 J 4.6 TRG Cobalt T 1 IMAC ug/I 0.13 0.056 J+ 0.47 0.077 J 0.07 J 0.12 4.1 TRG Copper D - ug/I 0.5 J 0.36 J 0.5 U 0.95 0.24 J 0.19 J 6.1 TRG Copper T 1000 02L ug/I 0.48 J 0.97 0.29 J+ 0.42 J+ 0.3 J+ 0.4 J+ 5.4 TRG Iron D - ug/I 50 U 50 U 25000 50 U 50 U 50 U 200 TRG Iron T 300 02L ug/I 50 U 50 U 29500 59.2 60.5 127 223 TRG Lead D - ug/I 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U TRG Lead T 15 02L ug/I 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U TRG Magnesium T - ug/I 1180 725 15700 4580 4530 4620 9460 TRG Manganese D - ug/I 5 U 5 U 1600 11 11 5 U 410 TRG Manganese T 50 02L ug/I 5 U 5 U 1770 10.7 10.8 6 465 TRG Mercury D - ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG IMercury T 1 02L ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG Methane N - ug/I 2 J+ 2 J+ 14500 10 U 1.7 J+ 1.5 J+ 2.4 J+ TRG Molybdenum D - ug/I 7.6 7.6 5.9 0.5 U 1.3 2.4 0.94 TRG Molybdenum T - ug/I 7.5 7.3 6.7 1.3 1.3 2.1 1 TRG Nickel D - ug/I 0.5 U 0.5 U 0.5 U 3.3 0.98 0.5 U 7.3 TRG Nickel T 100 02L ug/I 0.5 U 0.5 U 0.5 U 0.5 U 0.46 J 0.5 U 6.7 TRG Nitrogen, NO2 plus NO3 N - ug/I 470 520 20 UJ 530 480 2800 20 U TRG Potassium T - ug/I 9940 13400 6860 3260 J 3240 J 3500 J 15900 TRG Selenium D - ug/I 0.41 J 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U TRG Selenium T 20 02L ug/I 0.5 U 0.36 J 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U TRG Sodium T - ug/I 21200 23600 17800 8650 8610 8790 18500 TRG Strontium D - ug/I 160 200 2100 130 130 120 400 TRG Strontium T - ug/I 157 204 2360 148 147 137 444 TRG Sulfate N 250000 02L ug/I 22600 15400 5600 5400 5100 3800 24300 TRG Sulfide N - ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U TRG Thallium D - ug/I 0.1 U 0.1 U 0.1 U 0.11 0.1 U 0.1 U 0.1 U TRG IThalliurn T 0.2 1 IMAC ug/I 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.015 J Allen Steam Station Page 9 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: AB-35BR 3/16/2016 N AN-AB-35BR AB-35D 3/16/2016 N AN-AB-35D AB-36S 3/18/2016 N AN-AB-36S AB-36D 3/18/2016 N AN-AB-36D AB-36D 3/18/2016 FD AN-AB-36D-FD AB-37D 3/18/2016 N AN-AB-37D AB-38D 3/18/2016 N AN-AB-38D Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Total Dissolved Solids N 500000 02L ug/I 146000 142000 280000 95000 101000 108000 207000 TRG Total Organic Carbon N - ug/I 570 J 1000 U 850 J 1000 U 1000 U 1000 U 1000 U TRG Total Suspended Solids N - ug/I 5000 U 3600 38000 2500 U 2500 U 2500 U 4200 TRG jUranium, Natural T - ug/I -- -- 0.52 -- -- -- -- TRG Vanadium D - ug/I 12.9 20.3 -- 0.081 J 8.6 9.4 1.4 TRG Vanadium T 0.3 ]MAC ug/I 12.8 19.4 0.66 8.9 8.8 9.5 1.4 TRG Zinc D - ug/I IOU IOU 2.7 J IOU IOU 10 U 5.5 J TRG Zinc T 1000 02L ug/I IOU 2.5 J IOU IOU IOU 3.9 J 6.3 J FRS Dissolved Oxygen N - mg/I 1.57 1.43 0.3 0.3 0.3 2.6 0.3 FRS 10xidation Reduction Potential N - mV -9.9 32.4 -137.1 128.4 128.4 174 102.2 FRS pH N 6.5-8.5 02L SU 9.59 10.45 6.8 8.3 8.3 7.2 6.3 FRS Specific Conductivity N - PS/cm 258.8 259.2 647 159.3 159.3 166 302.2 FRS Temperature N - Deg C 19.2 19 14 15.4 15.4 15.8 17.4 FRS Turbidity, field N - NTU 1 1.32 2.74 8.3 5.3 5.3 4.4 1.7 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 10 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: AB-39D 3/16/2016 N AN-AB-39D AB-4BR 2/2/2016 N AN-AB-4BR-NS-1Q16 AB-5 3/18/2016 N AN-AB-5 AB-6A 3/18/2016 N AN-AB-6A AB-6R 3/18/2016 N AN-AB-6R BG-1 D 3/14/2016 N AN-BG-1D BG-1 D 3/14/2016 FD AN-BG-1D-FD Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Alkalinity, CO3 N - ug/I 5000 U 5000 U 5000 U 5000 U 5000 U 45000 39000 TRG Alkalinity, HCO3 N - ug/I 105000 69500 6100 16800 18700 35500 41500 TRG Alkalinity, lab N - ug/I 105000 69500 6100 16800 18700 80500 80500 TRG jAluminum D - ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U TRG Aluminum T - ug/I 100 U 58 J 287 100 U 100 U 95.4 J 100 U TRG Antimony D - ug/I 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 5 U 5 U TRG Antimony T 1 IMAC ug/I 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.39 J 0.35 J TRG Arsenic D - ug/I 0.24 0.15 0.1 U 0.11 0.094 J 3.2 3.6 TRG Arsenic T 10 02L ug/I 0.28 0.16 0.1 U 0.085 J 0.1 4.7 3.7 TRG Barium D - ug/I 170 49 24 34 27 10 10 TRG Barium T 700 02L ug/I 171 54 28.4 33.4 27.7 10.6 10 TRG Beryllium D - ug/I 0.1 U 0.1 U 0.036 J 0.029 J+ 0.014 J+ 0.51 J 1 U TRG Beryllium T 4 IMAC ug/I 0.1 U 0.1 U 0.037 J+ 0.035 J 0.1 U 0.02 J+ 0.013 J+ TRG Boron D - ug/I 74 50 U 50 U 50 U 50 U 50 U 50 U TRG Boron T 700 02L ug/I 86.7 J+ 50 U 50 U 50 U 50 U 35.2 J 26.7 J TRG Cadmium D - ug/I 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.8 U 0.8 U TRG Cadmium T 2 02L ug/I 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U TRG Calcium T - ug/I 34800 19800 1370 11100 11100 19100 17400 TRG Chloride N 250000 02L ug/I 13400 8700 2600 9300 7500 5500 4900 TRG Chromium D - ug/I 0.38 J 0.51 1.3 J+ 18 10.4 2.6 J+ 2.9 J+ TRG Chromium T 10 02L ug/I 0.38 J+ 1.9 J+ 3.6 15 10.8 J+ 0.96 J+ 1.1 J+ TRG Chromium 6+ T 0.07 DHHS ug/I 0.043 0.16 1 17.8 J+ 11.1 0.12 J- 0.12 J- TRG Cobalt D - ug/I 0.28 1.2 0.017 J 0.068 J 0.071 J 1 U 1 U TRG Cobalt T 1 IMAC ug/I 0.28 1.2 0.099 J 0.056 J 0.021 J 0.043 J 0.036 J TRG Copper D - ug/I 1 0.24 J+ 1.3 0.72 J+ 0.46 J+ 2.2 J+ 4.6 J TRG Copper T 1000 02L ug/I 0.56 0.29 J+ 0.67 0.14 J+ 0.15 J+ 1.4 1.2 TRG Iron D - ug/I 50 U 74 50 U 50 U 50 U 50 U 50 U TRG Iron T 300 02L ug/I 50 U 160 247 26 J 50 U 50 U 50 U TRG Lead D - ug/I 0.14 0.1 U 0.13 0.1 U 0.1 U 1 U 1 U TRG Lead T 15 02L ug/I 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U TRG Magnesium T - ug/I 8150 4990 871 3430 3320 334 483 TRG Manganese D - ug/I 21 400 2.9 J 7.5 34 4.8 J 4.3 J TRG Manganese T 50 02L ug/I 24.3 440 8.6 9 20.2 5 U 4.1 J TRG Mercury D - ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG IMercury T 1 02L ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG Methane N - ug/I 1.5 J+ 4.3 J+ 1.5 J+ 1.5 J+ 1.5 J+ 2.1 J+ 1.7 J+ TRG Molybdenum D - ug/I 0.16 J 2.3 0.5 U 0.15 J 0.5 U 6.2 6.1 TRG Molybdenum T - ug/I 0.17 J 2.4 0.5 U 0.5 U 0.5 U 7.5 6.1 TRG Nickel D - ug/I 2.1 1.3 0.86 1.4 2.2 5 U 5 U TRG Nickel T 100 02L ug/I 1.3 J+ 2 2.4 0.73 1 0.5 U 0.58 TRG Nitrogen, NO2 plus NO3 N - ug/I 1200 4800 20 U 100 100 67 75 TRG Potassium T - ug/I 4700 J 4360 J 5000 U 5000 U 5000 U 2780 J 2530 J TRG Selenium D - ug/I 3.4 0.5 U 0.5 U 0.36 J 0.32 J 5 U 5 U TRG Selenium T 20 02L ug/I 3.2 0.5 U 0.5 U 0.44 J 0.49 J 0.34 J 0.34 J TRG Sodium T - ug/I 15600 12200 2510 J 9740 9460 40400 33800 TRG Strontium D - ug/I 380 210 17 190 180 100 100 TRG Strontium T - ug/I 391 240 18.8 184 180 119 112 TRG Sulfate N 250000 02L ug/I 26600 4500 1400 28700 28800 60300 J 48100 J TRG Sulfide N - ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U TRG Thallium D - ug/I 0.1 U 0.1 U 0.025 J 0.1 U 0.1 U 1 U 1 U TRG IThalliurn T 0.2 IMAC ug/I 0.1 U 0.1 U 0.02 J 0.1 U 0.1 U 0.1 U 0.1 U Allen Steam Station Page 11 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: AB-39D 3/16/2016 N AN-AB-39D AB-4BR 2/2/2016 N AN-AB-4BR-NS-1Q16 AB-5 3/18/2016 N AN-AB-5 AB-6A 3/18/2016 N AN-AB-6A AB-6R 3/18/2016 N AN-AB-6R BG-1 D 3/14/2016 N AN-BG-1D BG-1 D 3/14/2016 FD AN-BG-1D-FD Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Total Dissolved Solids N 500000 02L ug/I 198000 129000 26000 115000 112000 258000 J 207000 J TRG Total Organic Carbon N - ug/I 50000 1000 U 1000 U 1000 U 1000 U 25900 J 16900 J TRG Total Suspended Solids N - ug/I 3500 2500 U 7800 2500 U 2500 U 5000 U 2500 U TRG jUranium, Natural T - ug/I -- -- 0.5 U 0.5 U -- 5 U 5 U TRG Vanadium D - ug/I 1.9 3.3 0.18 J 4.1 3.4 22.1 21.1 TRG Vanadium T 0.3 ]MAC ug/I 2.1 3.5 0.87 3.4 3.3 24.3 21 TRG Zinc D - ug/I 29 J+ 7 J+ 36 10 U 10 U 10 U 5.6 J TRG Zinc T 1000 02L ug/I 27.8 J+ 7.7 J+ 32.9 10 U 10 U 10 U 10 U FRS Dissolved Oxygen N - mg/I 0.87 3.03 4.7 1.38 0.98 0.92 0.92 FRS 10xidation Reduction Potential N - mV 165.9 90.1 258.7 168 187.5 -7.3 -7.3 FRS pH N 6.5-8.5 02L SU 5.82 6.29 5.5 6.25 6.27 10 10 FRS Specific Conductivity N - PS/cm 311.3 225 28 145.6 143.1 351.8 351.8 FRS Temperature N - Deg C 17.2 16.6 19.7 17.9 19.1 17.7 17.7 FRS Turbidity, field N - NTU 1 0.25 0.51 9 0.6 0.57 3.6 3.6 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 12 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: BG-1 S 3/14/2016 N AN-BG-1S BG-2BR 3/14/2016 N AN-BG-2BR BG-2D 3/14/2016 N AN-BG-2D BG-2S 3/14/2016 N AN-BG-2S BG-3D 3/14/2016 N AN-BG-3D BG-3S 3/14/2016 N AN-BG-3S BG-4BR 2/4/2016 FD BG-4BR DUPLICATE Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Alkalinity, CO3 N - ug/I 5000 U 239000 5000 U 5000 U 5000 U 5000 U 5000 U TRG Alkalinity, HCO3 N - ug/I 9400 5000 U 68600 53900 77300 92600 81900 TRG Alkalinity, lab N - ug/I 9400 1570000 68600 53900 77300 92600 81900 TRG jAluminum D - ug/I 100 U 130 100 U 100 U 100 U 100 U 100 U TRG Aluminum T - ug/I 106 206 51 J 100 U 227 305 2000 TRG Antimony D - ug/I 0.5 U 4 J 0.5 U 0.16 J 0.5 U 0.12 J 0.5 U TRG Antimony T 1 IMAC ug/I 0.11 J 4 0.16 J 0.18 J 0.5 U 0.17 J 0.5 U TRG Arsenic D - ug/I 2.4 1 U 0.25 0.16 0.11 1 0.41 TRG Arsenic T 10 02L ug/I 2.7 J+ 0.26 0.27 0.15 0.14 J+ 1 J+ 0.5 TRG Barium D - ug/I 32 690 41 13 76 52 10 TRG Barium T 700 02L ug/I 33.4 893 51 15.4 75.3 54.6 26 TRG Beryllium D - ug/I 0.074 J+ 1.2 0.03 J+ 0.034 J+ 0.1 U 0.03 J+ 0.1 U TRG Beryllium T 4 IMAC ug/I 0.066 J+ 0.05 J+ 0.018 J+ 0.066 J+ 0.1 U 0.036 J+ 0.042 J TRG Boron D - ug/I 50 U 50 U 50 U 50 U 50 U 50 U 50 U TRG Boron T 700 02L ug/I 50 U 50 U 50 U 50 U 50 U 50 U 50 U TRG Cadmium D - ug/I 0.08 U 0.8 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U TRG Cadmium T 2 02L ug/I 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U TRG Calcium T - ug/I 2530 57200 12800 14700 14300 20200 21700 TRG Chloride N 250000 02L ug/I 2100 5600 J- 2100 10500 2600 1700 1900 TRG Chromium D - ug/I 0.35 J+ 32.2 1.3 J+ 2 0.4 J+ 0.75 J+ 0.26 J+ TRG Chromium T 10 02L ug/I 1.8 J+ 32.4 1.6 J+ 1.8 J+ 1.7 J+ 1.2 J+ 2.1 J+ TRG Chromium 6+ T 0.07 DHHS ug/I 0.12 37.7 0.84 1.7 0.27 0.46 0.11 TRG Cobalt D - ug/I 0.067 J+ 0.1 J+ 0.048 J+ 0.026 J+ 0.059 J+ 0.023 J+ 0.13 J+ TRG Cobalt T 1 IMAC ug/I 0.1 0.08 J+ 0.078 J+ 0.048 J+ 0.13 0.13 1.3 TRG Copper D - ug/I 3.9 2.3 J 1.3 J+ 0.32 J+ 3.1 6.1 0.37 J+ TRG Copper T 1000 02L ug/I 0.32 J 2.1 0.47 J+ 0.22 J+ 0.78 0.52 7.1 J+ TRG Iron D - ug/I 50 U 50 U 50 U 50 U 50 U 50 U 50 U TRG Iron T 300 02L ug/I 112 29.4 J 60.4 49.4 J 173 158 2000 TRG Lead D - ug/I 0.41 1 U 0.14 0.1 U 0.31 0.58 0.1 U TRG Lead T 15 02L ug/I 0.1 U 0.63 0.1 U 0.1 U 0.1 U 0.1 U 0.31 TRG Magnesium T - ug/I 789 100 U 4360 3600 4680 3870 4440 TRG Manganese D - ug/I 5.9 5 U 3.4 J 4.3 J 5.6 15 150 TRG Manganese T 50 02L ug/I 7.5 5 U 5.9 6.7 8.6 48.1 240 TRG Mercury D - ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG IMercury T 1 02L ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG Methane N - ug/I 1.6 J+ 2.1 J+ 1.6 J+ 1.4 J+ 1.9 J+ 1.8 J+ 1.4 J+ TRG Molybdenum D - ug/I 0.5 U 29.5 1.6 0.5 U 0.32 J 0.34 J 5.6 TRG Molybdenum T - ug/I 0.12 J 29.8 1.8 0.5 U 0.33 J 0.3 J 5.6 TRG Nickel D - ug/I 0.85 5 U 0.63 0.5 U 0.55 0.64 0.5 U TRG Nickel T 100 02L ug/I 1.4 1.3 1 0.5 U 1.5 0.82 1.8 TRG Nitrogen, NO2 plus NO3 N - ug/I 370 450 930 1900 520 450 280 TRG Potassium T - ug/I 5000 U 5000 U 7190 5000 U 2940 J 3840 J 6980 TRG Selenium D - ug/I 0.5 U 5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U TRG Selenium T 20 02L ug/I 0.5 U 1.2 0.5 U 0.5 U 0.5 U 0.5 U 0.35 J TRG Sodium T - ug/I 5000 U 4440 J 8580 10800 8900 10200 8000 TRG Strontium D - ug/I 26 2700 160 190 190 240 89 TRG Strontium T - ug/I 30.2 3420 200 214 204 269 100 TRG Sulfate N 250000 02L ug/I 970 J 8600 J- 1800 1200 1000 1200 3900 TRG Sulfide N - ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U TRG Thallium D - ug/I 0.1 U 1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U TRG IThalliurn T 0.2 IMAC ug/I 0.1 U 0.066 J 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U Allen Steam Station Page 13 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: BG-1 S 3/14/2016 N AN-BG-1S BG-2BR 3/14/2016 N AN-BG-2BR BG-2D 3/14/2016 N AN-BG-2D BG-2S 3/14/2016 N AN-BG-2S BG-3D 3/14/2016 N AN-BG-3D BG-3S 3/14/2016 N AN-BG-3S BG-4BR 2/4/2016 FD BG-4BR DUPLICATE Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Total Dissolved Solids N 500000 02L ug/I 31000 1550000 110000 145000 133000 134000 91000 TRG Total Organic Carbon N - ug/I 1000 U 1700 11000 1000 U 1000 U 1000 U 1000 U TRG Total Suspended Solids N - ug/I 3100 5000 U 2500 U 2500 U 2500 U 3700 37800 TRG jUranium, Natural T - ug/I 0.5 U 5 U 0.15 J 0.5 U 0.5 U 0.061 J -- TRG Vanadium D - ug/I 0.56 0.77 J 8.4 1.8 6.5 3.3 6.7 TRG Vanadium T 0.3 ]MAC ug/I 0.72 0.87 7.8 1.7 6.1 3.3 11.8 TRG Zinc D - ug/I 22 7.1 J 3.8 J 5.8 J 12 14 10 U TRG Zinc T 1000 02L ug/I 18.6 9.3 J+ 4.5 J+ 8.7 J+ 7.7 J 10.8 12 FRS Dissolved Oxygen N - mg/I 5.3 2.1 4.1 5.6 6.64 5.47 2.61 FRS 10xidation Reduction Potential N - mV 217 -93.7 179.9 234.6 211.6 236.2 -24.4 FRS pH N 6.5-8.5 02L SU 5.8 12.5 7.3 5.9 6.3 6.5 8.39 FRS Specific Conductivity N - PS/cm 36.5 7035 172.1 166 160.4 196.8 180 FRS Temperature N - Deg C 23 17.4 19 21.5 20.2 20 17.6 FRS Turbidity, field N - NTU 9.1 8.2 2.6 2.5 9.9 8.2 71.1 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 14 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: BG-4BR 2/4/2016 N BG-4BR BG-4D 2/3/2016 N BG-4D BG-4S 2/4/2016 N BG-4S GWA-14D 3/17/2016 N AN-GWA-14D GWA-14S 3/17/2016 N AN-GWA-14S GWA-15D 3/16/2016 N AN-GWA-15D GWA-15S 3/16/2016 N AN-GWA-15S Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Alkalinity, CO3 N - ug/I 5000 U 16100 5000 U 420000 5000 U 5000 U 5000 U TRG Alkalinity, HCO3 N - ug/I 80500 11100 55900 5000 U 1700 J 63900 36700 TRG Alkalinity, lab N - ug/I 80500 27200 55900 1640000 1700 J 63900 36700 TRG jAluminum D - ug/I 100 U 140 100 U 680 100 U 100 U 100 U TRG Aluminum T - ug/I 2000 330 230 820 123 100 U 399 TRG Antimony D - ug/I 0.5 U 0.5 J 0.84 25 U 0.5 U 0.5 U 0.5 U TRG Antimony T 1 IMAC ug/I 0.5 U 0.57 0.93 25 U 0.5 U 5 U 0.5 U TRG Arsenic D - ug/I 0.43 2.4 0.33 5 U 0.1 U 0.17 0.15 TRG Arsenic T 10 02L ug/I 1 0.46 2.4 0.36 5 U 0.057 J 1.6 0.16 TRG Barium D - ug/I 10 30 50 500 74 60 29 TRG Barium T 700 02L ug/I 29 35 58 567 67.3 62 33.7 TRG Beryllium D - ug/I 0.1 U 0.1 U 0.022 J 5 U 0.14 0.1 U 0.044 J TRG Beryllium T 4 IMAC ug/I 0.04 J 0.017 J+ 0.02 J 5 U 0.11 1 U 0.019 J TRG Boron D - ug/I 50 U 26 J 50 U 50 U 50 U 50 U 78 TRG Boron T 700 02L ug/I 50 U 34 J 26 J 50 U 50 U 50 U 96 TRG Cadmium D - ug/I 0.08 U 0.08 U 0.08 U 4 U 0.08 U 0.08 U 0.08 U TRG Cadmium T 2 02L ug/I 0.08 U 0.08 U 0.08 U 4 U 0.08 U 0.8 U 0.08 U TRG Calcium T - ug/I 21800 45000 14600 456000 343 21500 13400 TRG Chloride N 250000 02L ug/I 1900 3900 7600 4600 2900 11400 5400 TRG Chromium D - ug/I 0.35 J+ 2.7 0.92 J+ 12.8 J 0.39 J 1.4 0.74 TRG Chromium T 10 02L ug/I 2.2 J+ 3.4 4 14.4 J 0.54 J+ 19 0.66 J+ TRG Chromium 6+ T 0.07 DHHS ug/I 0.1 2.5 0.4 J- 14.8 0.14 0.91 0.32 TRG Cobalt D - ug/I 0.13 J+ 0.014 J 1.6 5 U 3.7 0.07 J 0.14 TRG Cobalt T 1 IMAC ug/I 1.3 0.12 J+ 1.8 5 U 3.9 0.74 J 0.34 TRG Copper D - ug/I 1.6 J+ 0.72 2.7 J+ 6 J 1.6 0.44 J 0.83 TRG Copper T 1000 02L ug/I 7.6 J+ 0.92 J+ 1.7 J+ 25 U 0.69 J+ 4.3 J 0.68 TRG Iron D - ug/I 50 U 50 U 65 50 U 50 U 50 U 50 U TRG Iron T 300 02L ug/I 2200 240 430 135 233 30.6 J 641 TRG Lead D - ug/I 0.092 J 0.2 0.19 5 U 0.1 U 0.1 U 0.1 U TRG Lead T 15 02L ug/I 0.3 0.12 J+ 0.13 5 U 0.1 U 1 U 0.1 U TRG Magnesium T - ug/I 4530 950 3890 100 U 979 6020 3910 TRG Manganese D - ug/I 160 5 U 410 5 U 35 29 75 TRG Manganese T 50 02L ug/I 250 6.7 470 2.7 J 37.8 27.4 95.5 TRG Mercury D - ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG IMercury T 1 02L ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG Methane N - ug/I 1.5 J+ 2.8 J+ 1.1 J+ 4.6 J+ 1.5 J+ 1.9 J+ 1.7 J+ TRG Molybdenum D - ug/I 5.7 8.1 3.3 25 U 0.5 U 0.45 J 0.14 J TRG Molybdenum T - ug/I 5.5 8.1 3.3 25 U 0.5 U 4.4 J 0.14 J TRG Nickel D - ug/I 0.74 0.5 U 2 25 U 1.7 0.76 3.8 TRG Nickel T 100 02L ug/I 1.9 0.44 J 2.1 25 U 1.9 9.2 4.1 TRG Nitrogen, NO2 plus NO3 N - ug/I 280 220 29 200 700 3600 1800 TRG Potassium T - ug/I 7160 7650 5240 15800 5000 U 2550 J 4230 J TRG Selenium D - ug/I 0.5 U 1.3 0.39 J 25 U 0.5 U 0.5 U 0.5 U TRG Selenium T 20 02L ug/I 0.32 J 1.5 0.32 J 25 U 0.5 U 5 U 0.5 U TRG Sodium T - ug/I 8120 19900 28000 34300 5000 U 12400 9440 TRG Strontium D - ug/I 90 210 160 2100 4.8 J 210 160 TRG Strontium T - ug/I 110 220 180 2420 4.6 J 217 167 TRG Sulfate N 250000 02L ug/I 3900 49400 43900 1300 1100 3900 12900 TRG Sulfide N - ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U TRG Thallium D - ug/I 0.1 U 0.1 U 0.1 U 5 U 0.1 U 0.1 U 0.1 U TRG IThalliurn T 0.2 IMAC ug/I 0.1 U 0.1 U 0.1 U 5 U 0.1 U 1 U 0.1 U Allen Steam Station Page 15 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: BG-4BR 2/4/2016 N BG-4BR BG-4D 2/3/2016 N BG-4D BG-4S 2/4/2016 N BG-4S GWA-14D 3/17/2016 N AN-GWA-14D GWA-14S 3/17/2016 N AN-GWA-14S GWA-15D 3/16/2016 N AN-GWA-15D GWA-15S 3/16/2016 N AN-GWA-15S Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Total Dissolved Solids N 500000 02L ug/I 94000 157000 J+ 118000 1460000 25000 U 114000 97000 TRG Total Organic Carbon N - ug/I 1000 U 2100 J+ 1600 6700 1000 U 1000 U 10700 J- TRG Total Suspended Solids N - ug/I 45400 47600 5100 U 16200 3100 2500 U 11100 TRG jUranium, Natural T - ug/I -- -- -- -- -- -- -- TRG Vanadium D - ug/I 6.7 25.3 1.2 5.9 J 0.13 J+ 4.4 3.2 TRG Vanadium T 0.3 ]MAC ug/I 11.8 26 1.8 7.4 J 0.51 J+ 48.4 4.1 TRG Zinc D - ug/I 4.1 J+ 10 U 17 J+ 18 J+ 9.8 J+ 2.7 J 4.8 J+ TRG Zinc T 1000 02L ug/I 13 2.9 J+ 11 5.7 J+ 6.5 J+ 10 U 3.8 J FRS Dissolved Oxygen N - mg/I 2.61 2.04 2.25 1.1 6 2.5 0.3 FRS 10xidation Reduction Potential N - mV -24.4 -38.9 93.3 -120.5 291.3 204.4 195.1 FRS pH N 6.5-8.5 02L SU 8.39 10.18 6.59 12.8 5.2 6.3 6 FRS Specific Conductivity N - PS/cm 180 332.9 249.3 6356 27.2 195.4 134.3 FRS Temperature N - Deg C. 17.6 19.1 15.9 16.6 18.1 17.3 17.6 FRS Turbidity, field N - NTU 1 71.1 5.4 8.8 9.6 4.8 0.7 9.3 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 16 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: GWA-16D 2/5/2016 N N-GWA-16D-NS-1Q1 GWA-16S 2/9/2016 N N-GWA-16S-NS-1Q1 GWA-17D 2/4/2016 N N-GWA-17D-NS-1Q1 GWA-17S 2/8/2016 N N-GWA-17S-NS-1Q1 GWA-18D 2/8/2016 N N-GWA-18D-NS-1Q1 GWA-18S 2/8/2016 N N-GWA-18S-NS-1Q1 GWA-19D 4/22/2016 N AN-GWA-19D Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Alkalinity, CO3 N - ug/I 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 13400 TRG Alkalinity, HCO3 N - ug/I 37100 89000 79200 48200 68300 44300 76700 TRG Alkalinity, lab N - ug/I 37100 89000 79200 48200 68300 44300 90100 TRG jAluminum D - ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U TRG Aluminum T - ug/I 100 U 370 220 100 U 100 U 62 J 211 TRG Antimony D - ug/I 0.5 U 0.22 J 0.5 U 0.2 J 0.5 U 0.5 U 0.39 J TRG Antimony T 1 IMAC ug/I 0.5 U 0.22 J 0.5 U 0.24 J 0.5 U 0.5 U 0.46 J TRG Arsenic D - ug/I 0.15 0.62 0.18 0.78 0.23 0.28 0.88 TRG Arsenic T 10 02L ug/I 1 0.17 0.71 0.19 0.85 0.25 0.28 0.9 TRG Barium D - ug/I 25 24 24 44 32 21 7.7 TRG Barium T 700 02L ug/I 28 30 29 48 36 23 9.6 TRG Beryllium D - ug/I 0.1 U 0.013 J 0.1 U 0.073 J 0.1 U 0.1 U 0.1 U TRG Beryllium T 4 IMAC ug/I 0.011 J 0.022 J 0.02 J 0.067 J 0.011 J 0.012 J 0.034 J TRG Boron D - ug/I 50 U 50 U 50 U 50 U 50 U 50 U 50 U TRG Boron T 700 02L ug/I 50 U 50 U 50 U 50 U 50 U 50 U 50 U TRG Cadmium D - ug/I 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U TRG Cadmium T 2 02L ug/I 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U TRG Calcium T - ug/I 9540 19500 16300 13600 15600 9750 19600 TRG Chloride N 250000 02L ug/I 1 1900 4100 2300 7400 2300 4300 3900 TRG Chromium D - ug/I 1.9 0.39 J 0.49 J 0.26 J 1.1 2.8 1.4 J+ TRG Chromium T 10 02L ug/I 3.2 1.5 3.7 0.58 J+ 1.1 J+ 3 J+ 2 TRG Chromium 6+ T 0.07 DHHS ug/I 1.5 0.03 U 0.023 J+ 0.03 U 0.87 0.03 U 1.2 TRG Cobalt D - ug/I 0.053 J 0.11 J+ 0.52 1.2 0.51 0.66 0.042 J TRG Cobalt T 1 IMAC ug/I 0.073 J 0.32 0.58 1.3 0.49 0.7 0.15 TRG Copper D - ug/I 4.5 1.4 0.71 2.4 1.2 6.2 1.5 TRG Copper T 1000 02L ug/I 0.2 J 3.2 J+ 0.46 J+ 4.8 0.94 J+ 0.26 J+ 1.8 TRG Iron D - ug/I 26 J 50 U 28 J 1200 50 U 50 U 50 U TRG Iron T 300 02L ug/I 51 620 190 1300 50 U 69 J+ 177 TRG Lead D - ug/I 0.42 0.47 0.12 0.35 0.1 U 0.45 0.1 U TRG Lead T 15 02L ug/I 0.1 U 0.17 0.094 J 0.1 U 0.1 U 0.1 U 0.1 U TRG Magnesium T - ug/I 2590 3370 4600 4660 4400 3460 3710 TRG Manganese D - ug/I 7.5 240 210 1200 32 170 5 U TRG Manganese T 50 02L ug/I 8.9 180 240 1300 35 180 6.4 TRG Mercury D - ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG IMercury T 1 02L ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG Methane N - ug/I 2 J+ 2.3 J+ 2.5 J+ 6.1 J+ 2.1 J+ 2.4 J+ 10 U TRG Molybdenum D - ug/I 0.75 16.5 3 6.8 0.87 1.6 2.7 TRG Molybdenum T - ug/I 0.78 17.6 3.1 7.2 0.91 1.7 2.9 TRG Nickel D - ug/I 0.57 0.5 U 1.5 1.3 0.5 U 1.1 0.5 U TRG Nickel T 100 02L ug/I 1.5 0.5 U 2.7 1.2 0.5 U 1.1 0.5 U TRG Nitrogen, NO2 plus NO3 N - ug/I 900 150 240 20 U 32 12 J 2100 TRG Potassium T - ug/I 2780 J 2990 J 4890 J 3840 J 5000 U 5000 U 10900 TRG Selenium D - ug/I 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U TRG Selenium T 20 02L ug/I 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U TRG Sodium T - ug/I 6770 20600 10300 24600 8400 8780 14200 TRG Strontium D - ug/I 110 180 190 230 150 150 151 TRG Strontium T - ug/I 130 170 210 260 180 170 165 TRG Sulfate N 250000 02L ug/I 4000 5100 5200 43700 1900 3500 5100 TRG Sulfide N - ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U TRG Thallium D - ug/I 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U TRG IThalliurn T 0.2 IMAC ug/I 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U Allen Steam Station Page 17 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: GWA-16D 2/5/2016 N N-GWA-16D-NS-1Q1 GWA-16S 2/9/2016 N N-GWA-16S-NS-1Q1 GWA-17D 2/4/2016 N N-GWA-17D-NS-1Q1 GWA-17S 2/8/2016 N N-GWA-17S-NS-1Q1 GWA-18D 2/8/2016 N N-GWA-18D-NS-1Q1 GWA-18S 2/8/2016 N N-GWA-18S-NS-1Q1 GWA-19D 4/22/2016 N AN-GWA-19D Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Total Dissolved Solids N 500000 02L ug/I 43000 140000 90000 133000 57000 25000 U 135000 TRG Total Organic Carbon N - ug/I 6500 880 J 720 J+ 6900 660 J 830 J 510 J TRG Total Suspended Solids N - ug/I 2500 U 7300 2500 U 2500 U 2500 U 3000 21300 TRG jUranium, Natural T - ug/I -- -- -- -- -- -- 0.53 TRG Vanadium D - ug/I 7.4 2.5 5.1 0.3 J 6 1.9 11.9 TRG Vanadium T 0.3 ]MAC ug/I 7.3 3.9 5.4 0.41 JI 5.8 2 12.6 TRG Zinc D - ug/I 10 U 130 J- 2.5 J 11 4.2 J 3.5 J 10 U TRG Zinc T 1000 02L ug/I 10 U 10 3.4 J 13 10 U 2.6 J 2.9 J+ FRS Dissolved Oxygen N - mg/I 5.3 3.99 2.81 0.7 2.9 5.3 -- FRS 10xidation Reduction Potential N - mV 26 -49.8 6.9 -35.4 73.8 154.8 -- FRS pH N 6.5-8.5 02L SU 7.08 7.76 7.4 6.64 7.1 6.5 -- FRS Specific Conductivity N - PS/cm 103.4 219.6 208.1 229 144.1 117 -- FRS Temperature N - Deg C 15.6 16.1 17.2 17.1 15.2 15.1 -- FRS Turbidity, field N - NTU 0.66 9.34 8.2 2.79 0.3 1.7 -- Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 18 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: GWA-19S 4/22/2016 N AN-GWA-19S GWA-1 BR 3/17/2016 N AN-GWA-1 BR GWA-1 D 3/17/2016 N AN-GWA-1 D GWA-1 S 3/17/2016 N AN-GWA-1 S GWA-21 D 3/10/2016 N AN-GWA-21 D GWA-21 S 3/8/2016 N AN-GWA-21 S GWA-22D 2/3/2016 N N-GWA-22D-NS-1 Q11 Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Alkalinity, CO3 N - ug/I 5000 U 1400 J 5700 5000 U 1270000 5000 U 5000 U TRG Alkalinity, HCO3 N - ug/I 29200 74000 67700 2800 J 1570000 17900 124000 TRG Alkalinity, lab N - ug/I 29200 75400 73400 2800 J 2840000 17900 124000 TRG jAluminum D - ug/I 100 U 100 U 180 100 U 2100 J- 100 U 100 U TRG Aluminum T - ug/I 2530 59.8 J 290 100 U 2200 228 640 TRG Antimony D - ug/I 0.27 J 5 U 0.5 U 0.5 U 5 U 0.28 J 0.2 J TRG Antimony T 1 IMAC ug/I 0.3 J 5 U 0.5 U 0.5 U 0.5 U 0.51 0.19 J TRG Arsenic D - ug/I 0.49 0.8 J 0.35 0.1 U 1 U 0.095 J 0.23 TRG Arsenic T 10 02L ug/I 0.63 1 0.41 0.1 U 0.37 0.14 0.26 TRG Barium D - ug/I 34.7 16 20 49 49 27 38 TRG Barium T 700 02L ug/I 62.2 15.5 18 47.6 41.9 38.8 45 TRG Beryllium D - ug/I 0.016 J 1 U 0.012 J 0.041 J 1 U 0.029 J+ 0.012 J TRG Beryllium T 4 IMAC ug/I 0.15 J+ 1 U 0.1 U 0.041 J 0.049 J+ 0.038 J+ 0.026 J TRG Boron D - ug/I 50 U 50 U 50 U 50 U 50 U 50 U 50 U TRG Boron T 700 02L ug/I 50 U 50 U 50 U 50 U 50 U 50 U 50 U TRG Cadmium D - ug/I 0.08 U 0.8 U 0.08 U 0.08 U 0.8 U 0.08 U 0.08 U TRG Cadmium T 2 02L ug/I 0.08 U 0.8 U 0.08 U 0.078 J 0.08 U 0.08 U 0.08 U TRG Calcium T - ug/I 1 5180 23300 14300 533 97800 1670 24000 TRG Chloride N 250000 02L ug/I 3500 9300 11600 8600 5000 4700 2400 TRG Chromium D - ug/I 4 2.5 J 6.7 0.62 8.3 0.22 J+ 0.28 J TRG Chromium T 10 02L ug/I 7.9 2.3 J+ 6.7 2.2 J+ 7.7 0.28 J+ 0.92 J+ TRG Chromium 6+ T 0.07 DHHS ug/I 3.9 2.4 6.4 0.4 7.9 0.03 U 0.022 J+ TRG Cobalt D - ug/I 0.3 1 U 0.064 J 3.5 1 U 4.3 2.2 TRG Cobalt T 1 IMAC ug/I 0.86 1 U 0.058 J 4.4 0.058 J 5 2.4 J+ TRG Copper D - ug/I 1 5 U 0.39 J 1.2 1.3 J 0.46 J 1.2 TRG Copper T 1000 02L ug/I 4.6 5 U 0.36 J+ 0.54 J+ 0.7 J+ 0.21 J 0.92 J+ TRG Iron D - ug/I 33.4 J 50 U 50 U 50 U 41 J+ 130 81 J+ TRG Iron T 300 02L ug/I 1650 50 U 27.1 J 50 U 57.3 395 840 TRG Lead D - ug/I 0.1 U 1 U 0.1 U 0.1 U 1 U 0.14 0.14 TRG Lead T 15 02L ug/I 0.65 1 U 0.1 U 0.1 U 0.1 U 0.17 0.15 TRG Magnesium T - ug/I 1550 3700 2430 946 1530 916 8220 TRG Manganese D - ug/I 96.8 5 U 12 21 5 U 250 680 TRG Manganese T 50 02L ug/I 149 5 U 11.9 29.9 3.2 J 286 760 TRG Mercury D - ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG IMercury T 1 02L ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG Methane N - ug/I 10 U 1.4 J+ 1.7 J+ 1.5 J+ 2 J+ 2 J+ 1.6 J+ TRG Molybdenum D - ug/I 2.6 2.2 J 1.5 0.5 U 10.9 0.5 U 3.5 TRG Molybdenum T - ug/I 2.8 2.4 J 1.8 0.5 U 10 0.13 J 3.4 TRG Nickel D - ug/I 0.5 5 U 1.2 1.6 5 U 0.86 2.3 TRG Nickel T 100 02L ug/I 2.1 5 U 0.57 1.6 0.5 U 1.1 2.5 TRG Nitrogen, NO2 plus NO3 N - ug/I 440 150 100 17 J 1200 140 490 TRG Potassium T - ug/I 5000 U 3780 J 12100 5000 U 18200 5000 U 5410 TRG Selenium D - ug/I 0.5 U 5 U 0.38 J 0.5 U 5 U 0.5 U 0.5 U TRG Selenium T 20 02L ug/I 0.46 J 5 U 0.42 J 0.5 U 0.5 U 0.5 U 0.5 U TRG Sodium T - ug/I 10800 14100 18100 4740 J 23100 9490 11500 TRG Strontium D - ug/I 85.9 180 190 6.6 770 J+ 21 250 TRG Strontium T - ug/I 111 182 176 7.2 651 23.1 270 TRG Sulfate N 250000 02L ug/I 6400 16500 12500 1600 3100 3200 J+ 3200 TRG Sulfide N - ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U TRG Thallium D - ug/I 0.1 U 1 U 0.1 U 0.1 U 1 U 0.023 J 0.1 U TRG IThalliurn T 0.2 IMAC ug/I 0.1 U 1 U 0.1 U 0.1 U 0.1 U 0.021 J 0.1 U Allen Steam Station Page 19 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: GWA-19S 4/22/2016 N AN-GWA-19S GWA-1 BR 3/17/2016 N AN-GWA-1 BR GWA-1 D 3/17/2016 N AN-GWA-1 D GWA-1 S 3/17/2016 N AN-GWA-1 S GWA-21 D 3/10/2016 N AN-GWA-21 D GWA-21 S 3/8/2016 N AN-GWA-21 S GWA-22D 2/3/2016 N N-GWA-22D-NS-1 Q11 Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Total Dissolved Solids N 500000 02L ug/I 81000 159000 117000 25000 U 318000 25000 U 184000 TRG Total Organic Carbon N - ug/I 1000 U 1000 U 7300 1000 U 3700 12300 680 J TRG Total Suspended Solids N - ug/I 21600 4100 3000 5000 U 35000 4000 15900 TRG jUranium, Natural T - ug/I 0.12 J 4.2 -- 0.5 U -- -- -- TRG Vanadium D - ug/I 1.5 15.1 18.8 0.15 J+ 8.8 0.3 U 4.7 TRG Vanadium T 0.3 ]MAC ug/I 3.9 15.4 22.9 0.16 J+ 9.9 0.32 6.2 TRG Zinc D - ug/I 10 U 10 U 10 U 12 J+ 10 U 22 13 TRG Zinc T 1000 02L ug/I 9.2 J+ 10 U 10 U 13.6 J+ 9.1 J 43 12 FRS Dissolved Oxygen N - mg/I -- 1.9 1.2 3.6 1.7 2 1.1 FRS 10xidation Reduction Potential N - mV -- 111 74.5 257.4 -62.9 40.1 3.1 FRS pH N 6.5-8.5 02L SU -- 9.6 9.5 5.2 12 5.8 6.7 FRS Specific Conductivity N - PS/cm -- 191.4 188.6 42.2 1205 66.4 147.3 FRS Temperature N - Deg C -- 18.9 18.5 17.5 17.9 20.3 17 FRS Turbidity, field N - NTU 1 1.8 2.7 1.1 3.5 5.4 17.1 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 20 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: GWA-22S 2/4/2016 N N-GWA-22S-NS-1Q1 GWA-23D 2/2/2016 N N-GWA-23D-NS-1Q1 GWA-23S 2/3/2016 N N-GWA-23S-NS-1Q11 GWA-24BR 4/21/2016 N AN-GWA-24BR GWA-24D 4/22/2016 N AN-GWA-24D GWA-26D 2/10/2016 N N-GWA-26D-NS-1Q1 GWA-26D 2/10/2016 FD N-GWA-26D-FD-IQ1E Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Alkalinity, CO3 N - ug/I 5000 U 14600 5000 U 25500 5000 U 5000 U 5000 U TRG Alkalinity, HCO3 N - ug/I 7800 85400 8300 45800 47600 5000 U 5000 U TRG Alkalinity, lab N - ug/I 7800 100000 8300 71300 47600 5000 U 5000 U TRG jAluminum D - ug/I 69 J 260 66 J 100 U 53.2 J 100 U 100 U TRG Aluminum T - ug/I 840 560 160 82.7 J 425 510 J+ 490 J+ TRG Antimony D - ug/I 0.55 0.27 J 0.85 0.5 U 0.5 U 0.11 J 0.12 J TRG Antimony T 1 IMAC ug/I 0.61 0.3 J 1.4 0.5 U 0.5 U 0.15 J 0.15 J TRG Arsenic D - ug/I 0.091 J 2.7 0.12 1.1 0.37 0.44 0.42 TRG Arsenic T 10 02L ug/I 0.15 0.46 0.13 1.4 0.4 0.51 0.5 TRG Barium D - ug/I 39 11 26 8.6 23.3 20 20 TRG Barium T 700 02L ug/I 46 14 26 10 28.8 29 28 TRG Beryllium D - ug/I 0.032 J 0.1 U 0.034 J 0.1 U 0.1 U 0.1 U 0.012 J TRG Beryllium T 4 IMAC ug/I 0.052 J 0.023 J 0.027 J 0.014 J 0.014 J+ 0.12 0.12 TRG Boron D - ug/I 50 U 50 U 50 U 50 U 50 U 50 U 50 U TRG Boron T 700 02L ug/I 28 J 50 U 50 U 50 U 50 U 50 U 50 U TRG Cadmium D - ug/I 0.3 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U TRG Cadmium T 2 02L ug/I 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U TRG Calcium T - ug/I 1080 27500 1380 27300 13300 10800 12200 TRG Chloride N 250000 02L ug/I 7300 3900 5800 4600 3000 4400 4400 TRG Chromium D - ug/I 0.58 5.8 0.56 0.85 0.78 J+ 0.53 J+ 0.54 J+ TRG Chromium T 10 02L ug/I 2 6.7 0.63 J+ 1.2 J+ 1.1 J+ 1.6 1.6 TRG Chromium 6+ T 0.07 DHHS ug/I 0.12 6.6 0.08 0.87 0.62 0.3 0.32 TRG Cobalt D - ug/I 5.7 1 1.1 0.02 J 0.027 J 0.39 0.4 TRG Cobalt T 1 IMAC ug/I 5.8 1.5 1.1 J 0.054 J 0.22 0.76 0.77 TRG Copper D - ug/I 2.1 0.29 J+ 1.8 0.53 0.39 J 0.64 J+ 4.2 J+ TRG Copper T 1000 02L ug/I 1.1 0.79 J+ 1.2 J+ 0.18 J 1.1 0.57 0.49 J TRG Iron D - ug/I 110 37 J 58 J+ 50 U 50 U 50 U 50 U TRG Iron T 300 02L ug/I 670 380 180 64.4 444 320 J+ 290 J+ TRG Lead D - ug/I 0.16 0.1 U 0.12 0.1 U 0.1 U 0.11 J+ 0.14 J+ TRG Lead T 15 02L ug/I 0.17 0.21 0.12 0.1 U 0.09 J 0.64 0.6 TRG Magnesium T - ug/I 747 3240 719 2540 2270 1390 1600 TRG Manganese D - ug/I 150 6 86 5 U 26.4 30 30 TRG Manganese T 50 02L ug/I 170 22 90 5 U 36.2 38 37 TRG Mercury D - ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG IMercury T 1 02L ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG Methane N - ug/I 0.87 J+ 3 J+ 1.9 J+ 10 U 10 U 6 J+ 6.9 J+ TRG Molybdenum D - ug/I 0.15 J 8.2 0.5 U 4.6 1.6 3.8 3.8 TRG Molybdenum T - ug/I 0.21 J 7.9 0.5 U 5.3 1.7 3.6 3.6 TRG Nickel D - ug/I 1.9 0.5 U 0.55 0.5 U 0.5 U 0.46 J 0.53 TRG Nickel T 100 02L ug/I 1.8 0.5 U 0.54 0.5 U 0.5 U 0.94 1 TRG Nitrogen, NO2 plus NO3 N - ug/I 20 U 520 200 2800 1200 370 370 TRG Potassium T - ug/I 2820 J 6580 5000 U 4730 J 2760 J 2710 J 2960 J TRG Selenium D - ug/I 0.82 0.5 U 0.5 U 0.5 U 0.38 J 0.5 U 0.5 U TRG Selenium T 20 02L ug/I 1.1 0.36 J 0.5 U 0.5 U 0.5 U 0.59 0.38 J TRG Sodium T - ug/I 14200 16600 10200 8810 8930 14800 16400 TRG Strontium D - ug/I 14 100 11 98 114 89 87 TRG Strontium T - ug/I 16 110 12 105 126 93 94 TRG Sulfate N 250000 02L ug/I 1 20200 6500 10700 10400 7600 6700 6700 TRG Sulfide N - ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U TRG Thallium D - ug/I 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U TRG IThalliurn T 0.2 IMAC ug/I 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U Allen Steam Station Page 21 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: GWA-22S 2/4/2016 N N-GWA-22S-NS-1Q1 GWA-23D 2/2/2016 N N-GWA-23D-NS-1Q1 GWA-23S 2/3/2016 N N-GWA-23S-NS-1Q11 GWA-24BR 4/21/2016 N AN-GWA-24BR GWA-24D 4/22/2016 N AN-GWA-24D GWA-26D 2/10/2016 N N-GWA-26D-NS-1Q1 GWA-26D 2/10/2016 FD N-GWA-26D-FD-IQ1E Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Total Dissolved Solids N 500000 02L ug/I 25000 U 133000 64000 J+ 152000 112000 182000 J+ 156000 J+ TRG Total Organic Carbon N - ug/I 39900 12400 680 J 1000 U 1000 U 4800 11600 TRG Total Suspended Solids N - ug/I 27200 18400 4400 5000 U 4000 42000 34700 TRG jUranium, Natural T - ug/I -- -- -- 0.42 J 0.075 J -- -- TRG Vanadium D - ug/I 0.5 U 8.4 0.35 J 10.3 10.5 4.5 4.5 TRG Vanadium T 0.3 ]MAC ug/I 1 8.8 0.4 JI 11.8 11.7 4.7 4.6 TRG Zinc D - ug/I 68 10 U 17 10 U 10 U 9.2 J+ 23 J+ TRG Zinc T 1000 02L ug/I 84 5.5 J+ 19 10 U 10 U 4.2 J+ 4 J+ FRS Dissolved Oxygen N - mg/I 2.9 4.31 7.06 3.1 -- 3.68 3.68 FRS 10xidation Reduction Potential N - mV 221.8 3 209.1 -70.4 -- -224.4 -224.4 FRS pH N 6.5-8.5 02L SU 5.4 9.24 5.61 9.7 -- 8.6 8.6 FRS Specific Conductivity N - PS/cm 103.1 226.1 71.6 195 -- 134.2 134.2 FRS Temperature N - Deg C 15.2 16.2 17.5 18.3 -- 16.3 16.3 FRS Turbidity, field N - NTU 27.1 5.82 8.75 1.4 -- 23.4 23.4 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 22 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: GWA-26S 2/10/2016 N N-GWA-26S-NS-1Q1 I GWA-2D 3/18/2016 N AN-GWA-2D GWA-2S 3/18/2016 N AN-GWA-2S GWA-3BR 3/18/2016 N AN-GWA-3BR GWA-31D 3/18/2016 N AN-GWA-3D GWA-3S 3/18/2016 N AN-GWA-3S GWA-4D 3/18/2016 N AN-GWA-4D Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Alkalinity, CO3 N - ug/I 5000 U 5000 U 5000 U 45500 5000 U 5000 U 5000 U TRG Alkalinity, HCO3 N - ug/I 5000 U 54700 10300 5000 U 66200 50800 57500 TRG Alkalinity, lab N - ug/I 5000 U 54700 10300 51000 66200 50800 57500 TRG jAluminum D - ug/I 91 J 100 U 100 U 56 J 64 J 100 U 100 U TRG Aluminum T - ug/I 1200 93.6 J 100 U 119 202 100 U 94 J TRG Antimony D - ug/I 1.3 0.5 U 0.5 U 1.5 0.12 J 0.5 U 0.5 U TRG Antimony T 1 IMAC ug/I 1.4 0.5 U 0.5 U 1.4 0.14 J 0.5 U 5 U TRG Arsenic D - ug/I 0.51 0.21 0.041 J 3.2 0.43 0.19 0.094 J TRG Arsenic T 10 02L ug/I 1 0.75 0.15 0.057 J 4.1 0.53 0.15 1 U TRG Barium D - ug/I 9.2 30 45 9.5 4.1 J 24 20 TRG Barium T 700 02L ug/I 21 33.3 50.1 11.1 6.1 26.9 21.6 TRG Beryllium D - ug/I 0.021 J 0.031 J 0.063 J 0.1 U 0.023 J+ 0.02 J 0.1 U TRG Beryllium T 4 IMAC ug/I 0.48 0.037 J+ 0.097 J+ 0.044 J+ 0.022 J+ 0.1 U 1 U TRG Boron D - ug/I 50 U 50 U 50 U 48 J 91 250 620 TRG Boron T 700 02L ug/I 50 U 50 U 50 U 56.2 106 255 631 TRG Cadmium D - ug/I 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U TRG Cadmium T 2 02L ug/I 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.8 U TRG Calcium T - ug/I 14200 11900 1670 23200 20400 12100 23300 TRG Chloride N 250000 02L ug/I 3000 2100 5700 5900 3400 13400 7500 TRG Chromium D - ug/I 0.72 J+ 1.7 0.3 J+ 2 1.8 0.21 J+ 0.095 J TRG Chromium T 10 02L ug/I 11.7 2.2 J+ 0.25 J+ 3.2 28.6 0.21 J+ 5 U TRG Chromium 6+ T 0.07 DHHS ug/I 0.47 2.3 0.031 0.4 0.16 0.03 U 0.03 U TRG Cobalt D - ug/I 0.18 0.17 7.9 0.036 J 0.052 J 11.9 0.043 J TRG Cobalt T 1 IMAC ug/I 1.2 0.3 7.9 0.055 J 0.51 11.7 1 U TRG Copper D - ug/I 0.94 J+ 1.5 2.7 0.32 J 0.5 U 0.25 J 0.26 J TRG Copper T 1000 02L ug/I 109 0.27 J 0.12 J 1.6 2.5 0.18 J+ 4.1 J TRG Iron D - ug/I 50 U 50 U 35 J 50 U 50 U 10200 50 U TRG Iron T 300 02L ug/I 3200 J+ 138 71.8 50 U 481 11500 89.3 TRG Lead D - ug/I 0.22 J+ 0.16 0.24 0.1 U 0.1 U 0.1 U 0.1 U TRG Lead T 15 02L ug/I 1.1 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 1 U TRG Magnesium T - ug/I 934 2580 1500 522 3940 7190 8530 TRG Manganese D - ug/I 90 13 150 5 U 5.3 2200 16 TRG Manganese T 50 02L ug/I 170 17.8 170 5 U 14.1 2370 16.6 TRG Mercury D - ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG Mercury T 1 02L ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG Methane N - ug/I 2.6 J+ 1.4 J+ 3.1 J+ 1.8 J+ 1.6 J+ 188 1.3 J+ TRG Molybdenum D - ug/I 2.7 0.52 0.5 U 6.7 1.7 0.5 U 0.41 J TRG Molybdenum T - ug/I 5 0.42 J 0.5 U 7.6 2.7 0.5 U 5 U TRG Nickel D - ug/I 0.5 U 0.51 0.97 0.5 U 1.4 0.5 0.5 U TRG Nickel T 100 02L ug/I 2.4 0.65 0.99 0.5 21.6 0.45 J 5 U TRG Nitrogen, NO2 plus NO3 N - ug/I 390 88 13 J 16 J+ 400 20 U 42 TRG Potassium T - ug/I 5000 U 5000 U 5000 U 10200 2810 J 2860 J 3660 J TRG Selenium D - ug/I 0.5 U 0.5 U 0.5 U 0.39 J 0.5 U 0.5 U 1 TRG Selenium T 20 02L ug/I 0.33 J 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 5 U TRG Sodium T - ug/I 7220 8740 4560 J 24900 8990 31800 12300 TRG Strontium D - ug/I 86 150 23 170 120 87 220 TRG Strontium T - ug/I 81 158 25.6 193 136 95.8 215 TRG Sulfate N 250000 02L ug/I 2100 960 J 1400 52900 9600 62600 55500 TRG Sulfide N - ug/I 100 UJ 100 U 100 U 100 U 100 U 100 U 100 U TRG IThallium D - ug/I 0.1 U 0.022 J 0.026 J 0.017 J 0.1 U 0.047 J 0.1 U TRG IThalliurn T 0.2 IMAC ug/I 0.1 U 0.1 U 0.016 J 0.1 U 0.1 U 0.021 J 1 U Allen Steam Station Page 23 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: GWA-26S 2/10/2016 N N-GWA-26S-NS-1Q1 I GWA-2D 3/18/2016 N AN-GWA-2D GWA-2S 3/18/2016 N AN-GWA-2S GWA-3BR 3/18/2016 N AN-GWA-3BR GWA-3D 3/18/2016 N AN-GWA-3D GWA-3S 3/18/2016 N AN-GWA-3S GWA-4D 3/18/2016 N AN-GWA-4D Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Total Dissolved Solids N 500000 02L ug/I 116000 J+ 92000 25000 U 157000 111000 157000 171000 TRG Total Organic Carbon N - ug/I 820 J 1000 U 1000 U 6300 8200 1400 9400 TRG Total Suspended Solids N - ug/I 33300 2500 U 2500 U 4900 5500 5000 U 4400 TRG jUranium, Natural T - ug/I -- -- 0.5 U 0.13 J -- 0.17 J 0.13 J TRG Vanadium D - ug/I 2.9 3.7 0.3 U 17.3 8.9 0.3 U 3.6 TRG Vanadium T 0.3 ]MAC ug/I 5.9 4 0.12 J 18.9 9.9 0.3 U 4.6 TRG Zinc D - ug/I 10 U 3 J 5.1 J 10 U 10 U 10 U 10 U TRG Zinc T 1000 02L ug/I 46 10 U 3.8 J 2.8 J 2.7 J 10 U 10 U FRS Dissolved Oxygen N - mg/I 6.28 2.2 0.2 0.8 0.2 0.3 0.2 FRS 10xidation Reduction Potential N - mV -15.1 111.4 246.5 -79.9 -32.1 23.3 90.1 FRS pH N 6.5-8.5 02L SU 8.8 6.7 5.3 10.5 8.8 6.1 6.6 FRS Specific Conductivity N - PS/cm 111 105.2 45.5 295.2 165.6 315.7 276.1 FRS Temperature N - Deg C 13 17.4 16.2 22.8 21.2 21.8 21.2 FRS Turbidity, field N - NTU 39.3 3.1 3.3 6.7 9 8.6 6.8 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 24 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: GWA-4S 3/18/2016 N AN-GWA-4S GWA-5BR 3/18/2016 N AN-GWA-5BR GWA-5D 3/18/2016 N AN-GWA-SD GWA-5S 3/18/2016 N AN-GWA-SS GWA-6BR 3/16/2016 N AN-GWA-6BR GWA-6DA 3/16/2016 N AN-GWA-6D GWA-6DA 2/3/2016 N N-GWA-6DA-NS-1Q1i Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Alkalinity, CO3 N - ug/I 5000 U 5000 U 5000 U 5000 U 5000 U 193000 20200 TRG Alkalinity, HCO3 N - ug/I 4100 J 45100 92900 42900 135000 5000 U 112000 TRG Alkalinity, lab N - ug/I 4100 J 45100 92900 42900 135000 590000 132000 TRG jAluminum D - ug/I 100 U 100 U 100 U 100 U 100 U 620 100 U TRG Aluminum T - ug/I 68.3 J 100 U 50.8 J 95.5 J 195 1150 89 J TRG Antimony D - ug/I 0.5 U 1.1 0.5 U 0.5 U 0.35 J 1.9 0.12 J TRG Antimony T 1 IMAC ug/I 5 U 1 0.5 U 0.5 U 5 U 5 U 0.28 J TRG Arsenic D - ug/I 0.12 0.69 0.88 0.29 0.81 0.14 0.94 TRG Arsenic T 10 02L ug/I 1 U 0.69 0.9 0.14 0.63 J 1 U 1 TRG Barium D - ug/I 47 9.1 56 140 120 130 28 TRG Barium T 700 02L ug/I 47.3 10.5 61.5 139 121 145 31 TRG Beryllium D - ug/I 0.023 J+ 0.029 J+ 0.044 J+ 0.1 U 0.034 J 0.1 U 0.1 U TRG Beryllium T 4 IMAC ug/I 0.42 J 0.1 U 0.024 J 0.018 J 1 U 1 U 0.1 U TRG Boron D - ug/I 1800 610 570 50 U 50 U 50 U 50 U TRG Boron T 700 02L ug/I 1810 716 673 50 U 39.9 J+ 50 U 28 J TRG Cadmium D - ug/I 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U TRG Cadmium T 2 02L ug/I 0.8 U 0.086 0.54 0.19 0.8 U 0.8 U 0.08 U TRG Calcium T - ug/I 52400 13700 35300 9090 54000 95200 95500 TRG Chloride N 250000 02L ug/I 8100 6200 5500 4400 4100 7600 6300 TRG Chromium D - ug/I 0.41 J 0.29 J 0.26 J 0.86 0.44 J+ 5.3 1.2 TRG Chromium T 10 02L ug/I 5 U 0.65 J+ 2.4 0.24 J+ 1.9 J+ 7.3 1.6 J+ TRG Chromium 6+ T 0.07 DHHS ug/I 0.03 U 0.03 U 0.025 J 0.014 J 0.039 6.6 J- 1.2 TRG Cobalt D - ug/I 4.6 0.024 J 0.1 0.054 J 0.92 0.083 J+ 0.16 TRG Cobalt T 1 IMAC ug/I 4.8 0.022 J 0.12 20.6 1 0.31 J 0.15 TRG Copper D - ug/I 0.13 J 9.7 1 0.18 J 0.36 J+ 11.2 2.5 TRG Copper T 1000 02L ug/I 4 J 27.8 0.27 J 0.4 J 5 U 14.2 0.62 J+ TRG Iron D - ug/I 330 50 U 50 U 550 100 50 U 50 U TRG Iron T 300 02L ug/I 520 25.1 J 50 U 689 253 347 42 J TRG Lead D - ug/I 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.12 0.21 TRG Lead T 15 02L ug/I 1 U 0.1 U 0.1 U 0.1 U 1 U 1 U 0.1 U TRG Magnesium T - ug/I 2850 2940 5790 3000 17100 57.6 J 11900 TRG Manganese D - ug/I 520 5 U 120 5800 130 5 U 5 U TRG Manganese T 50 02L ug/I 503 5 U 134 6030 149 10.4 5 U TRG Mercury D - ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG IMercury T 1 02L ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG Methane N - ug/I 10.2 J+ 2.1 J+ 10 U 7.1 J+ 1.5 J+ 3.1 J+ 2.4 J+ TRG Molybdenum D - ug/I 0.5 U 4.4 0.78 1.1 1.8 52.7 2.7 TRG Molybdenum T - ug/I 5 U 4.3 0.77 0.5 U 1.9 J 52.8 3.2 TRG Nickel D - ug/I 0.5 U 0.54 1 0.59 1.3 1.2 0.5 U TRG Nickel T 100 02L ug/I 5 U 0.47 J 1.9 2.9 5 U 5 U 0.5 U TRG Nitrogen, NO2 plus NO3 N - ug/I 20 U 20 U 80 160 220 170 120 J+ TRG Potassium T - ug/I 4020 J 8780 4040 J 5000 U 14800 133000 5240 TRG Selenium D - ug/I 0.56 0.5 J 0.5 U 0.5 U 0.5 U 2 0.59 TRG Selenium T 20 02L ug/I 5 U 0.46 J 0.5 U 0.38 J 5 U 5 U 0.39 J TRG Sodium T - ug/I 11400 22300 10600 6430 18000 104000 36600 TRG Strontium D - ug/I 340 190 260 46 690 1200 490 TRG Strontium T - ug/I 318 209 260 49.6 682 1280 530 TRG Sulfate N 250000 02L ug/I 149000 43700 31000 8700 111000 68900 226000 TRG Sulfide N - ug/I 100 UJ 100 U 100 U 100 U 100 U 100 U 100 U TRG Thallium D - ug/I 0.049 J 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U TRG IThalliurn T 0.2 IMAC ug/I 1 U 0.1 U 0.1 U 0.052 J 1 U 1 U 0.1 U Allen Steam Station Page 25 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: GWA-4S 3/18/2016 N AN-GWA-4S GWA-5BR 3/18/2016 N AN-GWA-5BR GWA-5D 3/18/2016 N AN-GWA-SD GWA-5S 3/18/2016 N AN-GWA-SS GWA-6BR 3/16/2016 N AN-GWA-6BR GWA-6DA 3/16/2016 N AN-GWA-6D GWA-6DA 2/3/2016 N N-GWA-6DA-NS-1Q1i Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Total Dissolved Solids N 500000 02L ug/I 237000 166000 200000 72000 356000 460000 491000 TRG Total Organic Carbon N - ug/I 1000 U 5600 1000 U 830 J 1000 U 2300 J- 6600 TRG Total Suspended Solids N - ug/I 2500 U 5000 U 2500 U 3100 6000 17900 5000 U TRG jUranium, Natural T - ug/I 0.5 U 0.094 J 0.44 J 0.5 U 1.9 J 5 U -- TRG Vanadium D - ug/I 0.07 J 9.5 6.8 7.6 3.5 7.6 10.7 TRG Vanadium T 0.3 ]MAC ug/I 1.2 J+ 9.4 6.7 0.29 J+ 3.5 9.4 12.3 TRG Zinc D - ug/I 10 U 10 U 10 U 7.7 J 26 J+ 6.3 J+ 4.4 J TRG Zinc T 1000 02L ug/I 8.2 J 10 U 10 U 7.7 J 28.3 J+ 3.7 J+ 9.2 J FRS Dissolved Oxygen N - mg/I 0.2 0.5 0.4 0.2 0.4 1.8 2.26 FRS 10xidation Reduction Potential N - mV 143.6 -111.1 82.9 230.9 43 1.6 88.5 FRS pH N 6.5-8.5 02L SU 5.5 9 7.7 5.4 6.8 12.1 9.19 FRS Specific Conductivity N - PS/cm 405.6 238.6 299.6 140.9 540 2905 716 FRS Temperature N - Deg C 20.1 20.5 16.1 17.9 24 18.9 18 FRS Turbidity, field N - NTU 1 5.5 2.5 1.6 6.2 8.5 6.7 0.7 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 26 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: GWA-6S 3/16/2016 N AN-GWA-6S GWA-7D 3/16/2016 N AN-GWA-7D GWA-7D 3/16/2016 FD AN-FD-GWA-7D GWA-7S 3/16/2016 N AN-GWA-7S GWA-81D 3/16/2016 N AN-GWA-BD GWA-8S 3/16/2016 N AN-GWA-8S GWA-91D 3/17/2016 N AN-GWA-9D Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Alkalinity, CO3 N - ug/I 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U TRG Alkalinity, HCO3 N - ug/I 5000 U 87700 87800 5000 U 86300 31200 52400 TRG Alkalinity, lab N - ug/I 5000 U 87700 87800 5000 U 86300 31200 52400 TRG jAluminum D - ug/I 74400 100 U 100 U 680 100 U 100 U 100 U TRG Aluminum T - ug/I 84400 100 U 100 U 651 73.2 J 695 128 TRG Antimony D - ug/I 10 U 0.5 U 0.5 U 0.5 U 0.5 U 0.13 J 0.24 J TRG Antimony T 1 IMAC ug/I 2.7 J 5 U 5 U 0.5 U 5 U 5 U 0.33 J TRG Arsenic D - ug/I 136 0.11 0.1 0.47 0.15 0.053 J 0.28 TRG Arsenic T 10 02L ug/I 135 1 U 1 U 0.64 1 U 1 U 0.36 TRG Barium D - ug/I 250 U 92 92 110 230 310 23 TRG Barium T 700 02L ug/I 250 U 87.5 92 109 241 326 21.5 TRG Beryllium D - ug/I 51.8 0.083 J 0.1 U 0.63 0.012 J 0.035 J 0.1 U TRG Beryllium T 4 IMAC ug/I 37 0.13 J 1 U 0.68 1 U 1 U 0.1 U TRG Boron D - ug/I 2500 U 50 U 50 U 50 U 50 U 50 U 50 U TRG Boron T 700 02L ug/I 2500 U 50 U 50 U 50 U 50 U 50 U 50 U TRG Cadmium D - ug/I 10.8 0.08 U 0.08 U 0.12 0.36 0.072 J 0.08 U TRG Cadmium T 2 02L ug/I 9.8 0.8 U 0.8 U 0.14 0.8 U 0.8 U 0.08 U TRG Calcium T - ug/I 209000 45500 45800 928 17200 36100 14000 TRG Chloride N 250000 02L ug/I 4700 2700 2600 2700 2500 103000 3900 TRG Chromium D - ug/I 9.8 J 4.9 4.7 5.9 3.5 4 0.84 TRG Chromium T 10 02L ug/I 7.2 J 2.8 J+ 5.6 6.2 1.3 J+ 7.6 2.1 J+ TRG Chromium 6+ T 0.07 DHHS ug/I 0.03 U 0.2 J 4.2 J 5.1 J- 0.33 3.1 1.1 TRG Cobalt D - ug/I 4860 0.052 J 0.04 J 42.9 0.073 J 0.14 0.071 J TRG Cobalt T 1 IMAC ug/I 4810 1 U 1 U 39.4 1 U 0.62 J 0.13 TRG Copper D - ug/I 295 0.27 J 0.13 J 6.6 0.28 J 0.46 J 0.56 TRG Copper T 1000 02L ug/I 286 4.1 J 4 J 2.7 5 5.2 0.95 J+ TRG Iron D - ug/I 2500 U 50 U 50 U 50 U 50 U 50 U 50 U TRG Iron T 300 02L ug/I 2500 U 78.1 71.6 50 U 105 1380 223 TRG Lead D - ug/I 2 U 0.1 U 0.1 U 0.12 0.1 U 0.1 U 0.1 U TRG Lead T 15 02L ug/I 2 U 1 U 1 U 0.1 U 1 U 1 U 0.1 U TRG Magnesium T - ug/I 144000 12600 12700 10300 7150 20600 2430 TRG Manganese D - ug/I 162000 9.2 8.7 230 4.3 J 11 17 TRG Manganese T 50 02L ug/I 185000 18.4 8.3 218 5.4 33.4 22.3 TRG Mercury D - ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG IMercury T 1 02L ug/I 0.2 UJ 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG Methane N - ug/I 2.2 J+ 2.1 J+ 1.7 J+ 1.4 J+ 1.6 J+ 1.5 J+ 1.5 J+ TRG Molybdenum D - ug/I 10 U 0.26 J 0.24 J 0.5 U 0.66 0.5 U 2.1 TRG Molybdenum T - ug/I 10 U 5 U 5 U 0.5 U 5 U 5 U 2.6 TRG Nickel D - ug/I 1090 0.72 0.5 U 5.9 2.2 8.8 0.88 TRG Nickel T 100 02L ug/I 1070 5 U 5 U 5.3 5 U 11.7 0.6 TRG Nitrogen, NO2 plus NO3 N - ug/I 70 220 250 890 360 4600 1500 TRG Potassium T - ug/I 250000 U 3230 J 3190 J 5000 U 4080 J 4230 J 4250 J TRG Selenium D - ug/I 1020 2.2 2.3 5.8 0.5 U 0.5 U 0.5 U TRG Selenium T 20 02L ug/I 953 5 U 3.2 J 8.3 5 U 5 U 0.5 U TRG Sodium T - ug/I 250000 U 14200 14200 17800 9980 7840 9880 TRG Strontium D - ug/I 1400 450 450 15 240 530 110 TRG Strontium T - ug/I 1700 430 442 14.6 235 552 106 TRG Sulfate N 250000 02L ug/I 2340000 93600 96400 75700 1500 1500 5600 TRG Sulfide N - ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U TRG Thallium D - ug/I 0.36 J 0.1 U 0.1 U 0.057 J 0.1 U 0.1 U 0.1 U TRG IThalliurn T 0.2 IMAC ug/I 0.3 J 1 U 1 U 0.028 J 1 U 1 U 0.1 U Allen Steam Station Page 27 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: GWA-6S 3/16/2016 N AN-GWA-6S GWA-7D 3/16/2016 N AN-GWA-7D GWA-71D 3/16/2016 FD AN-FD-GWA-7D GWA-7S 3/16/2016 N AN-GWA-7S GWA-81D 3/16/2016 N AN-GWA-BD GWA-8S 3/16/2016 N AN-GWA-8S GWA-9D 3/17/2016 N AN-GWA-9D Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Total Dissolved Solids N 500000 02L ug/I 2850000 230000 233000 122000 105000 243000 44000 TRG Total Organic Carbon N - ug/I 22100 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U TRG Total Suspended Solids N - ug/I 7600 2500 U 2500 U 2500 U 2500 U 16700 3100 TRG jUranium, Natural T - ug/I 6.7 J -- -- 0.5 U -- 5 U -- TRG Vanadium D - ug/I 6 U 4.3 4.3 0.3 U 6.3 1.4 6.9 TRG Vanadium T 0.3 ]MAC ug/I 6 U 5.6 5.2 0.12 J 7 4.6 8.2 TRG Zinc D - ug/I 1900 16 14 36 3.6 J+ 50 10 U TRG Zinc T 1000 02L ug/I 2230 29 10.2 26.9 6.5 J 44.8 13 J+ FRS Dissolved Oxygen N - mg/I 2.2 0.5 0.5 2.2 2.8 4.6 2.9 FRS 10xidation Reduction Potential N - mV 401.4 102.6 102.6 282 191.5 212.5 187.4 FRS pH N 6.5-8.5 02L SU 4.1 6.4 6.4 4.5 6.7 5.9 7.2 FRS Specific Conductivity N - PS/cm 2911 352 352 195 170 451.6 135.4 FRS Temperature N - Deg C. 25.6 17.4 17.4 18 18.7 24.7 16.7 FRS Turbidity, field N - NTU 9.7 1.2 1.2 0.7 7.1 9 5.1 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 28 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: GWA-91D 3/17/2016 FD AN-FD-GWA-9D GWA-9S 3/17/2016 N AN-GWA-9S PH WELL 3/21/2016 N AN -PH -WELL Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Alkalinity, CO3 N - ug/I 5000 U 5000 U 5000 U TRG Alkalinity, HCO3 N - ug/I 49200 34200 38200 TRG Alkalinity, lab N - ug/I 49200 34200 38200 TRG jAluminum D - ug/I 100 U 100 U 100 U TRG Aluminum T - ug/I 100 U 100 U 100 U TRG Antimony D - ug/I 0.2 J 0.5 U 0.5 U TRG Antimony T 1 IMAC ug/I 0.2 J 0.5 U 0.5 U TRG Arsenic D - ug/I 0.23 0.47 0.075 J TRG Arsenic T 10 02L ug/I 1 0.27 0.46 0.081 J TRG Barium D - ug/I 23 42 120 TRG Barium T 700 02L ug/I 22.1 42.4 121 TRG Beryllium D - ug/I 0.029 J 0.089 J 0.1 U TRG Beryllium T 4 IMAC ug/I 0.1 U 0.1 0.039 J+ TRG Boron D - ug/I 50 U 50 U 91 TRG Boron T 700 02L ug/I 50 U 25.2 J 95.5 TRG Cadmium D - ug/I 0.08 U 0.08 U 0.08 U TRG Cadmium T 2 02L ug/I 0.15 0.08 U 0.08 U TRG Calcium T - ug/I 12300 8120 40900 TRG Chloride N 250000 02L ug/I 3700 26200 64200 TRG Chromium D - ug/I 0.99 0.16 J 1.7 J+ TRG Chromium T 10 02L ug/I 3.8 J+ 0.37 J+ 1.1 J+ TRG Chromium 6+ T 0.07 DHHS ug/I 0.77 0.014 J 0.6 TRG Cobalt D - ug/I 0.058 J 19.9 0.028 J+ TRG Cobalt T 1 IMAC ug/I 0.11 21.3 0.024 J+ TRG Copper D - ug/I 0.26 J 0.46 J 2.5 TRG Copper T 1000 02L ug/I 0.45 J+ 0.34 J+ 0.44 J+ TRG Iron D - ug/I 50 U 150 50 U TRG Iron T 300 02L ug/I 60.3 249 92.6 TRG Lead D - ug/I 0.1 U 0.1 U 0.2 TRG Lead T 15 02L ug/I 0.1 U 0.1 U 0.24 TRG Magnesium T - ug/I 2430 4540 9820 TRG Manganese D - ug/I 19 1000 5 U TRG Manganese T 50 02L ug/I 19.6 1160 5 U TRG Mercury D - ug/I 0.2 U 0.2 U 0.2 U TRG Mercury T 1 02L ug/I 0.2 U 0.2 U 0.2 U TRG Methane N - ug/I 1.6 J+ 3.1 J+ 1.6 J+ TRG Molybdenum D - ug/I 1.8 0.13 J 0.5 U TRG Molybdenum T - ug/I 2.1 0.15 J 0.5 U TRG Nickel D - ug/I 0.5 U 2.5 0.68 TRG Nickel T 100 02L ug/I 1.6 2.9 0.55 TRG Nitrogen, NO2 plus NO3 N - ug/I 1600 20 U 20 U TRG Potassium T - ug/I 3480 J 5000 U 2830 J TRG Selenium D - ug/I 0.5 U 0.5 U 0.5 U TRG Selenium T 20 02L ug/I 0.5 U 0.5 U 0.5 U TRG Sodium T - ug/I 8760 77900 17300 TRG Strontium D - ug/I 110 110 490 TRG Strontium T - ug/I 104 110 535 TRG Sulfate N 250000 02L ug/I 4500 131000 42700 TRG Sulfide N - ug/I 100 U 100 U 100 U TRG IThallium D - I ug/I 0.1 U 0.1 U 0.1 U TRG IThalliurn T 0.2 1 IMAC ug/I 0.1 U 0.1 U 0.1 U Allen Steam Station Page 29 of 30 CSA Supplement 2 Table 3-1: Round 5 Analytical Results of Groundwater Monitoring Results Location: Date: Sample Type: Sample Name: GWA-91D 3/17/2016 FD AN-FD-GWA-9D GWA-9S 3/17/2016 N AN-GWA-9S PH WELL 3/21/2016 N AN -PH -WELL Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Total Dissolved Solids N 500000 02L ug/I 121000 174000 327000 TRG Total Organic Carbon N - ug/I 1000 U 9800 1000 U TRG Total Suspended Solids N - ug/I 2500 U 2500 U 2500 U TRG jUranium, Natural T - ug/I -- -- -- TRG Vanadium D - ug/I 6.2 0.18 J+ 3.9 TRG Vanadium T 0.3 ]MAC ug/I 6.9 0.28 J+ 4.4 TRG Zinc D - ug/I 10 U 15 J+ 12 TRG Zinc T 1000 02L ug/I 10 U 16 J+ 38.5 FRS Dissolved Oxygen N - mg/I 1 2.9 0.4 3 FRS 10xidation Reduction Potential N - mV 187.4 184.9 44.6 FRS pH N 6.5-8.5 02L SU 7.2 5.6 7.2 FRS Specific Conductivity N - PS/cm 135.4 425 385 FRS Temperature N - Deg C 16.7 15.6 17.2 FRS Turbidity, field N - NTU 5.1 4.1 1.55 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 30 of 30 CSA Supplement 2 Table 3-2: Round 5 Analytical Results of Porewater Monitoring Results Location: Date: Sample Type: Sample Name: AB-20S 3/17/2016 N AN-AB-20S AB-21S 3/18/2016 N AN-AB-21S AB-21SL 3/18/2016 N AN-AB-21SL AB-23S 3/17/2016 N AN-AB-23S AB-23S 3/17/2016 FD AN-AB-23S-FD AB-24S 3/17/2016 N AN-AB-24S AB-24SL 3/17/2016 N AN-AB-24SL AB-25S 3/17/2016 N AN-AB-25S AB-25SL 3/17/2016 N AN-AB-25SL Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Alkalinity, CO3 N ug/I 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U TRG Alkalinity, HCO3 N ug/I 308000 387000 133000 64100 63900 145000 62400 184000 189000 TRG Alkalinity, lab N ug/I 308000 387000 134000 64100 63900 145000 62400 184000 189000 TRG Aluminum D ug/I 100 U 100 U 300 380 400 100 U 190 100 U 360 TRG Aluminum T ug/I 207 99.2 J 295 409 392 100 U 202 100 U 338 TRG Antimony D ug/I 25 U 0.5 U 8.9 0.63 0.65 5 U 5 U 7.5 5 U TRG Antimony T 1 IMAC ug/I 25 U 5 U 6.9 0.68 0.54 5 U 5 U 7.3 5 U TRG Arsenic D - ug/I 38.1 379 575 1390 1450 70.8 669 98.1 786 TRG Arsenic T 10 02L ug/I 43 397 584 1270 1380 106 686 96.5 717 TRG Barium D - ug/I 70 380 210 54 54 240 80 140 190 TRG Barium T 700 02L ug/I 68.9 405 215 50.9 52.2 233 76.4 133 188 TRG Beryllium D - ug/I 5 U 0.054 J+ 0.055 J+ 0.1 U 0.1 U 1 U 1 U 1 U 1 U TRG Beryllium T 4 IMAC ug/I 2.6 J 1 U 1 U 0.1 U 0.1 U 1 U 1 U 1 U 1 U TRG Boron D - ug/I 1800 3200 6800 440 440 620 570 1800 1500 TRG Boron T 700 02L ug/I 1810 3320 6740 443 458 658 591 1820 1610 TRG Cadmium D - ug/I 4 U 0.08 U 0.34 0.08 U 0.08 U 0.8 U 0.8 U 0.8 U 0.8 U TRG Cadmium T 2 02L ug/I 4 U 0.8 U 0.8 U 0.08 U 0.08 U 0.8 U 0.8 U 0.8 U 0.8 U TRG Calcium T - ug/I 148000 143000 73200 17500 18300 55400 23800 88600 73300 TRG Chloride N 250000 02L ug/I 2100 33700 13800 6700 6800 11200 8000 8900 8400 TRG Chromium D - ug/I 25 U 0.27 J+ 0.65 J+ 1 J+ 0.52 J+ 5 U 5 U 1.4 J+ 5 U TRG Chromium T 10 02L ug/I 25 U 5 U 0.94 J+ 0.32 J+ 0.74 J+ 5 U 5 U 5 U 5 U TRG Chromium 6+ T 0.07 DHHS ug/I 0.056 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U TRG Cobalt D - ug/I 2 J 1.6 0.19 0.051 J 0.043 J 2.1 1 U 3.8 0.12 J TRG Cobalt T 1 IMAC ug/I 2.6 J 1.5 0.13 J 0.045 J+ 0.054 J+ 2.3 1 U 3.6 1 U TRG Copper D - ug/I 25 U 0.99 J+ 0.21 J+ 0.23 J 0.16 J 5 U 5 U 5 U 5 U TRG Copper T 1000 02L ug/I 25 U 3.9 J 3.7 J 0.5 U 0.17 J+ 5 U 5 U 5 U 5 U TRG Iron D - ug/I 600 8000 90 50 U 50 U 2800 31 J 85 63 TRG Iron T 300 02L ug/I 844 8520 106 50 U 50 U 3380 50.4 J+ 138 89 TRG Lead D - ug/I 5U 0.1U 0.1U 0.1U 0.1U 1U 1U 1U 1U TRG Lead T 15 02L ug/I 5 U 1 U 1 U 0.1 U 0.1 U 1 U 1 U 1 U 1 U TRG Magnesium T - ug/I 14000 29000 28100 4900 5360 11000 3640 14200 11800 TRG Manganese D - ug/I 150 1200 100 140 130 920 18 310 49 TRG Manganese T 50 02L ug/I 157 1150 98.7 139 150 996 22.9 J+ 336 53.5 TRG Mercury D - ug/I 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U TRG Mercury T 1 02L ug/I 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U TRG Methane N - ug/I 2450 11200 903 11400 J 19400 J 237 8 J+ 4.4 J+ 11.3 J+ TRG Molybdenum D ug/I 26.8 378 3090 52.6 52.4 43.6 62 255 189 TRG Molybdenum T ug/I 27.8 348 3110 57.1 49 45.6 64.5 254 183 TRG Nickel D - ug/I 25 U 1.4 2.9 0.96 0.68 4.5 J 5 U 5.8 5 U TRG Nickel T 100 02L ug/I 25 U 5 U 5 U 0.5 J+ 0.8 J+ 4.5 J 5 U 5 U 5 U TRG Nitrogen, NO2 plus NO3 N - ug/I 20 U 20 U 20 U 20 U 12 J+ 20 U 20 U 24 J+ 20 U TRG Potassium T ug/I 15700 9510 4850 J 8750 8720 6530 5850 6620 9230 TRG Selenium D - ug/I 173 0.5 U 0.98 0.32 J 0.5 U 5 U 5 U 5 U 5 U TRG Selenium T 20 02L ug/I 194 5 U 5 U 0.5 U 0.35 J 5 U 5 U 5 U 5 U TRG Sodium T - ug/I 16700 11900 5540 3390 J 3500 J 7160 6920 11500 12300 TRG Strontium D ug/I 2100 3700 1800 550 550 1600 630 2100 2200 TRG Strontium T - ug/I 2000 3770 1740 509 524 1500 596 2060 2190 TRG Sulfate N 250000 02L ug/I 158000 87500 151000 9400 9100 56200 22500 113000 83300 TRG Sulfide N - ug/I 100 U 100 UJ 100 U 100 U 100 U 100 U 100 U 100 U 100 U TRG Thallium D - ug/I 5 U 0.1 U 0.1 U 0.1 U 0.1 U 1 U 1 U 0.2 J 1 U TRG Thallium T 0.2 IMAC ug/I 1.4 J 1 U 1 U 0.1 U 0.1 U 1 U 1 U 0.19 J 1 U TRG Total Dissolved Solids N 500000 02L ug/I 594000 573000 396000 47000 104000 164000 75000 397000 314000 TRG Total Organic Carbon N - ug/I 910 J+ 700 J 20000 1300 J+ 1200 J+ 1000 U 1000 U 1100 J+ 790 J+ TRG Total Suspended Solids N ug/I 6500 21800 2500 U 5000 U 2600 U 7400 2600 U 5000 U 2800 U TRG Vanadium D - ug/I 31.2 2.1 54 6.4 6.6 5 10.3 24.5 11.2 TRG Vanadium T 0.3 IMAC ug/I 34.6 3.9 41.8 7.8 5.9 5.8 8.4 23.8 8.8 TRG Zinc D - ug/I 4.8J 10U 10U 10U 12 10U 10U 10U 10U TRG Zinc T 1000 02L ug/I 5.7 J+ 10 U 10 U 10 U 10 U 10 U 10 U 5 J+ 10 U FRS Dissolved Oxygen N i - mg/I 0.87 0.13 0.16 1.57 1.57 0.1 0.3 0.1 0.19 Allen Steam Station Page 1 of 4 CSA Supplement 2 Table 3-2: Round 5 Analytical Results of Porewater Monitoring Results Location: Date: Sample Type: Sample Name: AB-20S 3/17/2016 N AN-AB-20S AB-21S 3/18/2016 N AN-AB-21S AB-21SL 3/18/2016 N AN-AB-21SL AB-23S 3/17/2016 N AN-AB-23S AB-23S 3/17/2016 FD AN-AB-23S-FD AB-24S 3/17/2016 N AN-AB-24S AB-24SL 3/17/2016 N AN-AB-24SL AB-25S 3/17/2016 N AN-AB-25S AB-25SL 3/17/2016 N AN-AB-25SL Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit FRS Oxidation Reduction Potential N my -3.4 -172.7 -182 8.7 8.7 -119.5 -180.6 -75 -86.9 FRS pH N 6.5 - 8.5 02L SU 6.69 7.04 8.1 8.95 8.95 7 8.6 8 8.6 FRS Specific Conductivity N PS/cm 875 968 588 184.1 184.1 439.8 205.5 634 549 FRS Temperature N Deg C 19.1 15 15.3 23 23 21.6 20.6 18.6 18.4 FRS ITurbidity, field I N I I NTU 7.6 9.56 1.07 1.58 1.58 9.8 0.5 4.96 0.78 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 2 of 4 CSA Supplement 2 Table 3-2: Round 5 Analytical Results of Porewater Monitoring Results Location: Date: Sample Type: Sample Name: AB-27S 3/17/2016 N AN-AB-27S AB-28S 3/17/2016 N AN-AB-28S AB-29S 3/17/2016 N AN-AB-29S AB-29SL 3/17/2016 N AN-AB-29SL AB-30S 3/16/2016 N AN-AB-30S AB-35S 3/16/2016 N AN-AB-35S AB-37S 3/18/2016 N AN-AB-37S AB-38S 3/18/2016 N AN-AB-38S AB-39S 3/16/2016 N AN-AB-39S Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit TRG Alkalinity, CO3 N ug/I 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U TRG Alkalinity, HCO3 N ug/I 167000 159000 173000 40000 128000 222000 32700 90100 134000 TRG Alkalinity, lab N ug/I 167000 159000 173000 40600 128000 222000 32700 90100 134000 TRG Aluminum D ug/I 100 U 100 U 180 1800 100 U 100 U 100 U 100 U 100 U TRG Aluminum T ug/I 100 U 100 U 192 2370 100 U 54.2 J 220 100 U 100 U TRG Antimony D ug/I 5 U 5 U 5 U 6.2 0.31 J 0.36 J 0.5 U 0.5 U 0.5 U TRG Antimony T 1 IMAC ug/I 5 U 5 U 0.57 5.9 0.4 J 5 U 0.5 U 0.5 U 0.5 U TRG Arsenic D - ug/I 179 25.9 665 84.4 313 85.7 0.2 181 3.2 TRG Arsenic T 10 02L ug/I 188 37.9 729 115 407 89.1 0.2 186 3.3 TRG Barium D - ug/I 240 66 300 160 280 110 19 160 210 TRG Barium T 700 02L ug/I 214 61.5 276 152 297 112 20.8 175 230 TRG Beryllium D - ug/I 0.31 J 1 U 1 U 1 U 0.028 J 0.1 0.03 J+ 0.1 U 0.021 J TRG Beryllium T 4 IMAC ug/I 1 U 1 U 0.1 U 0.19 J 0.1 U 0.66 J 0.021 J+ 0.1 U 0.1 U TRG Boron D - ug/I 420 960 890 1800 880 840 50 U 81 100 TRG Boron T 700 02L ug/I 429 994 917 1850 838 823 50 U 89.4 124 J+ TRG Cadmium D - ug/I 0.8 U 0.8 U 0.8 U 0.8 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U TRG Cadmium T 2 02L ug/I 0.8 U 0.8 U 0.054 J 0.8 U 0.08 U 0.8 U 0.08 U 0.08 U 0.08 U TRG Calcium T - ug/I 51400 80400 77200 83700 48100 118000 6310 16600 31000 TRG Chloride N 250000 02L ug/I 6800 18300 8700 7500 9300 4900 3000 2300 9600 TRG Chromium D - ug/I 5 U 5 U 2.1 J+ 1.8 J+ 0.45 J 0.52 0.42 J+ 0.2 J+ 0.53 TRG Chromium T 10 02L ug/I 5 U 5 U 1.3 J+ 1 J+ 0.5 J+ 2 J+ 0.55 J+ 0.23 J+ 0.44 J+ TRG Chromium 6+ T 0.07 DHHS ug/I 0.03 U 0.03 U 0.03 U 0.017 J+ 0.03 U 0.03 U 0.38 0.03 U 0.076 TRG Cobalt D - ug/I 15.4 28.5 1 U 1 U 1.3 0.14 0.048 J 5.6 3.2 TRG Cobalt T 1 IMAC ug/I 14.8 28.9 0.12 J+ 1 U 1.4 0.25 J 0.027 J 5.4 3 TRG Copper D - ug/I 5 U 5 U 4.4 J 6.5 0.16 J 0.16 J 1.5 1.5 0.12 J TRG Copper T 1000 02L ug/I 5 U 5 U 0.17 J 5 U 0.11 J 45.8 0.15 J+ 0.5 U 0.5 U TRG Iron D - ug/I 12200 7200 93 50 U 3800 58600 50 U 46200 49600 TRG Iron T 300 02L ug/I 11100 7420 305 72.8 4520 56600 152 50800 54000 TRG Lead D - ug/I 1U 1U 1U 1U 0.1U 0.1U 0.1U 0.1U 0.1U TRG Lead T 15 02L ug/I 1U 1U 0.1U 1U 0.1U 1U 0.1U 0.1U 0.1U TRG Magnesium T - ug/I 8660 21000 16800 6700 9780 46400 2730 8660 7360 TRG Manganese D - ug/I 3000 4400 45 38 990 10800 7.1 1800 4900 TRG Manganese T 50 02L ug/I 3160 4880 45.4 42.9 961 13100 5 U 1890 5320 TRG Mercury D - ug/I 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2UJ TRG Mercury T 1 02L ug/I 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U TRG Methane N - ug/I 1320 76.6 32 6.8 J+ 28.7 450 1.6 J+ 3250 7070 TRG Molybdenum D ug/I 5.1 8.6 19.1 21.8 7 3.8 0.5 U 1.5 0.34 J TRG Molybdenum T ug/I 4.8 J 8.9 21.1 22.2 8.2 3.8 J 0.5 U 1.5 0.32 J TRG Nickel D - ug/I 5 U 5.4 5 U 5 U 1.3 0.5 U 0.5 U 2.5 0.81 TRG Nickel T 100 02L ug/I 5 U 5.4 0.92 J+ 5 U 0.68 J+ 5 U 0.5 U 1 0.5 U TRG Nitrogen, NO2 plus NO3 N - ug/I 29 20 U 20 U 71 J+ 20 U 20 U 1400 20 U 20 UJ TRG Potassium T ug/I 8530 10200 5520 6260 5500 51500 5000 U 4170 J 2530 J TRG Selenium D - ug/I 5 U 5 U 5 U 19.4 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U TRG Selenium T 20 02L ug/I 5 U 5 U 0.5 U 20 0.5 U 5 U 0.5 U 0.5 U 0.5 U TRG Sodium T - ug/I 9100 35500 10200 10900 11300 20300 9030 2600J 12100 TRG Strontium D ug/I 910 1800 1800 1300 1200 1700 100 390 290 TRG Strontium T - ug/I 826 1660 1740 1190 1250 1710 108 423 313 TRG Sulfate N 250000 02L ug/I 26800 211000 95600 198000 49100 420000 2500 5100 2300 TRG Sulfide N - ug/I 100 U 100 UJ 100 U 100 U 100 U 100 U 100 U 100 U 100 U TRG Thallium D - ug/I 1 U 1 U 1 U 1 U 0.1 U 0.1 U 0.1 U 0.14 0.1 U TRG Thallium T 0.2 IMAC ug/I 1 U 0.22 J 0.1 U 1 U 0.1 U 1 U 0.1 U 0.14 0.1 U TRG Total Dissolved Solids N 500000 02L ug/I 214000 523000 310000 376000 119000 905000 98000 134000 199000 TRG Total Organic Carbon N - ug/I 570 J 1100 1000 U 1000 U 1000 U 550 J 1000 U 980 J 2300 TRG Total Suspended Solids N ug/I 14900 7400 2500 U 5000 U 11000 46000 2500 U 16400 57500 TRG Vanadium D - ug/I 1.5 J 1.5 J 11.4 53.3 2.4 0.27 J 7.6 0.3 U -- TRG Vanadium T 0.3 IMAC ug/I 1.2 J 3 U 12.1 56.4 3.6 0.95 J+ 7.7 0.089 J 0.28 J TRG Zinc D - ug/I 32 J+ 7.6 J+ 19 J+ 8.5 J+ 10 U 38 10 U 3.8 J 0.46 J+ TRG IZinc T 1000 1 02L ug/I 49.1 9.2 J+ 10 U 4.6 J 3.5 J 57.1 10 U 10 U 10 U FRS I Dissolved Oxygen N mg/I 0.4 0.2 0.28 0.3 0.04 0.33 2.1 0.1 16.4 J+ Allen Steam Station Page 3 of 4 CSA Supplement 2 Table 3-2: Round 5 Analytical Results of Porewater Monitoring Results Location: Date: Sample Type: Sample Name: AB-27S 3/17/2016 N AN-AB-27S AB-28S 3/17/2016 N AN-AB-28S AB-29S 3/17/2016 N AN-AB-29S AB-29SL 3/17/2016 N AN-AB-29SL AB-30S 3/16/2016 N AN-AB-30S AB-35S 3/16/2016 N AN-AB-35S AB-37S 3/18/2016 N AN-AB-37S AB-38S 3/18/2016 N AN-AB-38S AB-39S 3/16/2016 N AN-AB-39S Result Type Constituent Fraction NCDEQ GWQS GWQS Source Unit FRS Oxidation Reduction Potential N my -94.3 0.3 -182.9 74.6 -188.6 -125.4 150.4 -68.4 0.14 FRS pH N 6.5 - 8.5 02L SU 6.7 6.1 8.3 9.2 7.5 6.63 6.5 6.5 -105.4 FRS Specific Conductivity N PS/cm 444.6 794 513.7 509.7 378.6 1289 93.8 302.8 6.37 FRS Temperature N Deg C 19.8 16.5 21 22.1 17.9 21.8 16.5 16.4 444 FRS ITurbidity, field I N I I NTU 5.6 7.7 3.5 8.6 7.22 4.36 4.2 8.9 17 0.98 Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 4 of 4 CSA Supplement 2 Table 3-3: Round 5 Analytical Results of Surface Water Locations Location: Sample Date: Sample Type Code: Sample Name/ID: SW-5 3/21/2016 N AN-SW-5 SW-6 3/21/2016 N AN-SW-6 SW-7 3/21/2016 N AN-SW-7 Constituent CAS RN Fraction NCDEQ GWQS, IMAC, DHHS NCDEQ SWQSUnits Class B Aluminum 7429-90-5 D -- ug/1 98 J 120 56 J Aluminum 7429-90-5 T 87 ug/I 1 170 190 210 Antimony 7440-36-0 D -- -- ug/I 0.5 U 0.16 J 0.14 J Antimony 7440-36-0 T 1 5.6 ug/I 5 U 0.17 J 0.15 J Arsenic 7440-38-2 D -- 150 ug/I 0.79 0.25 0.24 Arsenic 7440-38-2 T 10 10 ug/I 1 U 0.28 0.34 Barium 7440-39-3 D -- -- ug/I 43 12 13 Barium 7440-39-3 T 700 1000 ug/I 46 13 15 Beryllium 7440-41-7 D -- 6.5 ug/I 0.097 J+ 0.024 J+ 0.048 J+ Beryllium 7440-41-7 T 4 -- ug/I 1 U 0.1 U 0.1 U Boron 7440-42-8 D -- ug/I 9700 33 J 60 Boron 7440-42-8 T 700 -- ug/I 10900 39 J 64 Cadmium 7440-43-9 D -- 0.15 ug/1 0.15 0.074 J 0.08 U Cadmium 7440-43-9 T 2 -- ug/I 0.8 U 0.08 U 0.08 U Calcium 7440-70-2 T -- -- ug/I 149000 5260 5680 Chromium 7440-47-3 D -- 11 ug/I 0.28 J 0.27 J 0.29 J Chromium 7440-47-3 T 10 -- ug/I 1.2 J+ 0.4 J+ 0.84 J+ Cobalt 7440-48-4 D -- -- ug/I 3.9 0.12 0.08 J+ Cobalt 7440-48-4 T 1 3 ug/I 4.3 0.12 J+ 0.16 J+ Copper 7440-50-8 D -- 2.7 ug/I 9 L 1.8 J+ 1.5 J+ Copper 7440-50-8 T 1000 -- ug/I 17.6 1.6 1.4 Iron 7439-89-6 D -- ug/I 81 100 52 Iron 7439-89-6 T 300 -- ug/I 520 250 270 Lead 7439-92-1 D -- 0.54 ug/I 0.12 0.1 U 0.1 U Lead 7439-92-1 T 15 -- ug/I 1 U 0.12 0.14 Magnesium 7439-95-4 T -- ug/I 49300 1850 1900 Manganese 7439-96-5 D -- ug/I 190 17 11 Manganese 7439-96-5 T 50 -- ug/I 190 22 23 Mercury 7439-97-6 T 1 0.012 ug/I 0.0028 0.00101 0.00171 J+ Methane 74-82-8 N -- -- ug/I 1.8 J+ 6.7 J+ 4.3 J+ Molybdenum 7439-98-7 D -- ug/I 0.93 0.26 J 0.37 J Molybdenum 7439-98-7 T 160 ug/I 5 U 0.25 J 0.38 J Nickel 7440-02-0 D -- 16 ug/I 7.2 1.5 1.6 Nickel 7440-02-0 T 100 25 ug/I 7.2 0.5 U 0.47 J Potassium 7440-09-7 T -- -- ug/I 3570 J 5000 U 5000 U Selenium 7782-49-2 D -- -- ug/I 0.52 0.5 U 0.5 U Selenium 7782-49-2 T 20 5 ug/I 5 U 0.5 U 0.5 U Sodium 7440-23-5 T -- -- ug/I 13500 4560 J 4240 J Strontium 7440-24-6 D -- ug/I 430 30 37 Strontium 7440-24-6 T 14000 ug/I 460 33 40 Thallium 7440-28-0 D -- -- ug/I 0.062 J 0.1 U 0.1 U Thallium 7440-28-0 T 0.2 0.24 ug/I 1 U 0.1 U 0.1 U Vanadium 7440-62-2 D -- -- ug/I 0.65 0.58 0.5 Vanadium 7440-62-2 T 0.3 -- ug/I 3 U 0.85 0.94 Zinc 7440-66-6 D -- 36 ug/I 36 10 U 10 U Zinc 7440-66-6 T 1000 -- ug/I 39 2.8 J 10 U Total Dissolved Solids TDS N 500000 500000 ug/I 883000 52000 J+ 88000 J+ Total Organic Carbon TOC N -- -- ug/I 1300 1700 1700 Total Suspended Solids TSS N ug/I 5800 5000 U 3000 Alkalinity, CO3 ALK-CO3 N ug/I 5000 U 5000 U 5000 U Allen Steam Station CSA Supplement 2 Page 1 of 2 Table 3-3: Round 5 Analytical Results of Surface Water Locations Location: Sample Date: Sample Type Code: Sample Name/ID: SW-5 3/21/2016 N AN-SW-5 SW-6 3/21/2016 N AN-SW-6 SW-7 3/21/2016 N AN-SW-7 Constituent CAS RN Fraction NCDEQ GWQS, IMAC, DHHS NCDEQ SWQSUnits Class B Alkalinity, HCO3 ALK-HCO3 N ug/1 10500 16200 17300 Alkalinity, lab ALK-LAB N -- -- ug/I 10500 16200 17300 Chloride 16887-00-6 N 250000 230000 ug/I 282000 4800 4700 Nitrogen, NO2 plus NO3 NO2-NO3 N -- -- ug/I 260 320 270 Sulfate 14808-79-8 N 250000 250000 ug/I 158000 5100 4800 Sulfide 18496-25-8 N -- -- ug/I 100 U 100 U 100 U Chromium 6+ 18540-29-9 T 0.07 ug/I 0.03 U 0.034 0.04 Dissolved Oxygen DO N -- mg/I 6.69 7.07 7.9 Temperature TEMP N Deg C 17.7 16.1 17.7 pH PH N 6.5-8.5 6.0-9.0 SU 6.4 7.2 7.3 Turbidity, field TURB N NTU 3.69 3.91 5.2 Specific Conductivity SC N PS/cm 1260 99.1 79.2 Oxidation Reduction Potential ORP N mV 207.9 195.9 1857 50 Exceeds NCDEQ 02L GWQS, IMAC, or DHHS standards. 50 I Exceeds NCDEQ 02B SWQS Class B standards. Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 2 of 2 CSA Supplement 2 Table 3-4: Round 5 Analytical Results of Ash Basin Surface Water Locations Location: Sample Date: Sample Type Code: Sample Name/ID: SW-1 3/21/2016 N AN-SW-1 SW-2 3/21/2016 N AN-SW-2 SW-3 3/21/2016 N AN-SW-3 SW-4 3/21/2016 N AN-SW-4 Constituent CAS RN Fraction NCDEQ GWQS, IMAC, DHHS NCDEQ SWQS Class B Units Aluminum 7429-90-5 D -- ug/I 100 U 52 J 77 J 590 Aluminum 7429-90-5 T 87 ug/I 83 J 170 89 J 2000 Antimony 7440-36-0 D -- -- ug/l 0.16 J 0.17 J 0.12 J 0.17 J Antimony 7440-36-0 T 1 5.6 ug/l 5 U 5 U 0.15 J 0.25 J Arsenic 7440-38-2 D -- 150 ug/l 1.4 1.6 1.1 0.35 Arsenic 7440-38-2 T 10 10 ug/I 2.5 3.2 1.4 2.2 Barium 7440-39-3 D -- -- ug/I 48 49 35 60 Barium 7440-39-3 T 700 1000 ug/l 49 51 36 74 Beryllium 7440-41-7 D -- 6.5 ug/l 0.055 J+ 0.069 J+ 0.015 J+ 0.77 Beryllium 7440-41-7 T 4 -- ug/l 1 U 1 U 0.1 U 1 Boron 7440-42-8 D -- ug/I 1 2600 2800 43 J 220 Boron 7440-42-8 T 700 -- ug/l 2700 3000 44 J 260 Cadmium 7440-43-9 D -- 0.15 ug/l 0.17 0.2 0.08 U 0.56 Cadmium 7440-43-9 T 2 -- ug/I 0.8 U 0.8 U 0.08 U 0.65 Calcium 7440-70-2 T -- -- ug/I 52200 53100 6760 21900 Chromium 7440-47-3 D -- 11 ug/l 0.5 U 0.1 J 0.14 J 0.38 J Chromium 7440-47-3 T 10 -- ug/l 5 U 5 U 0.26 J+ 1.6 J+ Cobalt 7440-48-4 D -- -- ug/I 6 7.7 0.059 J+ 12.5 Cobalt 7440-48-4 T 1 3 ug/I 6_9 7.7 0.073 J+ 16 Copper 7440-50-8 D -- 2.7 ug/l 2.3 J+ 3.2 J+ 1.6 J+ 34.5 Copper 7440-50-8 T 1000 -- ug/l 2.9 J 3.8 J 1.1 69.3 Iron 7439-89-6 D -- ug/I 70 37 J 41 J 6800 Iron 7439-89-6 T 300 -- ug/I 120 190 71 14000 Lead 7439-92-1 D -- 0.54 ug/I 0.1 U 0.1 U 0.1 U 0.2 Lead 7439-92-1 T 15 -- ug/l 1 U 1 U 0.1 1.5 Magnesium 7439-95-4 T -- ug/l 12800 13500 1920 6300 Manganese 7439-96-5 D -- ug/l 190 210 7.8 520 Manganese 7439-96-5 T 50 -- ug/I 200 220 11 680 Mercury 7439-97-6 T 1 0.012 ug/I 0.00136 0.00124 0.000853 J+ 0.005 U Methane 74-82-8 N -- -- ug/l 2.9 J+ 3.5 J+ 1.5 J+ 3.6 J+ Molybdenum 7439-98-7 D -- ug/I 4.3 4.2 0.68 0.46 J Molybdenum 7439-98-7 T 160 ug/I 4.5 J 4.5 J 0.87 2.6 Nickel 7440-02-0 D -- 16 ug/1 6 7.1 1 19.9 Nickel 7440-02-0 T 100 25 ug/I 6.5 6.7 0.52 23.5 Potassium 7440-09-7 T -- -- ug/l 2920 J 3040 J 5000 U 5000 U Selenium 7782-49-2 D -- -- ug/I 5.5 5.4 0.5 U 2.1 Selenium 7782-49-2 T 20 5 ug/l 8.5 11.8 0.5 U 3.8 Sodium 7440-23-5 T -- -- ug/I 11200 11400 4420 J 33700 Strontium 7440-24-6 D -- ug/l 210 210 37 150 Strontium 7440-24-6 T 14000 ug/l 200 210 40 180 Thallium 7440-28-0 D -- -- ug/l 0.12 0.12 0.032 J 0.2 Thallium 7440-28-0 T 0.2 0.24 ug/l 1 U 1 U 0.049 J+ 0.22 Vanadium 7440-62-2 D -- -- ug/I 0.16 J 0.31 0.76 0.24 J Vanadium 7440-62-2 T 0.3 -- ug/l 3 U 3 U 1.1 6.9 Zinc 7440-66-6 D -- 36 ug/l 22 J+ 26 J+ 10 U 88 Zinc 7440-66-6 T 1000 -- ug/I 30 32 2.9 J 120 Total Dissolved Solids TDS N 500000 500000 ug/I 355000 J+ 390000 J+ 46000 J+ 277000 J+ Total Organic Carbon TOC N -- -- ug/I 1 1300 1300 1600 2500 Total Suspended Solids TSS N ug/l 29300 8200 2500 U 49000 Alkalinity, CO3 ALK-CO3 N ug/I 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 ALK-HCO3 N ug/I 10400 10600 15600 5000 U Alkalinity, lab ALK-LAB N -- -- ug/I 10400 10600 15600 5000 U Chloride 16887-00-6 N 250000 230000 ug/l 83200 86500 4700 43200 Nitrogen, NO2 plus NO3 NO2-NO3 N -- -- ug/l 360 390 120 230 Sulfate 14808-79-8 N 250000 250000 ug/I 74600 79000 6200 129000 Sulfide 18496-25-8 N -- -- ug/I 100 U 100 U 100 U 100 U Chromium 6+ 18540-29-9 T 0.07 ug/I 0.03 U 0.03 U 0.082 0.03 U Dissolved Oxygen DO N -- mg/I 6.8 6.26 7.85 6.68 Temperature TEMP N I Deg C 13.3 12.8 16.6 17.2 Allen Steam Station CSA Supplement 2 Page 1 of 2 Table 3-4: Round 5 Analytical Results of Ash Basin Surface Water Locations Location: SW-1 SW-2 SW-3 SW-4 Sample Date: 3/21/2016 3/21/2016 3/21/2016 3/21/2016 Sample Type Code: N N N N Sample Name/ID: AN-SW-1 AN-SW-2 AN-SW-3 AN-SW-4 NCDEQ GWQS, NCDEQ SWQSUnits Constituent CAS RN Fraction IMAC, DHHS Class B pH PH N 6.5-8.5 6.0-9.0 SU 6.6 6.7 6.5 5.4 Turbidity, field TURB N NTU 1.56 3.46 2.54 42.48 Specific Conductivity SC N PS/Cm 503.6 496.7 45.8 422.5 Oxidation Reduction Potential ORP N mV 206.1 197.7 266.4 214.8 50 Exceeds NCDEQ 02L GWQS, IMAC, or DHHS standards. 50 Exceeds NCDEQ 02B SWQS Class B standards. Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter mV = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard IMAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 2 of 2 CSA Supplement 2 Table 3-5: Round 5 Analytical Results of Areas of Wetness Location: Sample Date: Sample Type Code: Sample Name/ID: ANSP005 3/21 /2016 N AN-ANSP005 ANSW015 3/21 /2016 N AN-ANSW015 ANSW016 3/21 /2016 N AN-ANSW016 ANTD001 3/21 /2016 N AN-ANTD001 S-1 3/21 /2016 N AN-S-1 S-2 3/21 /2016 N AN-S-2 S-3 3/21 /2016 FD AN-S-3 DUPLICATE S-3 3/21 /2016 N AN-S-3 S-4 3/21 /2016 N AN-S-4 Constituent CAS RN Fraction NCDEQ GWQS, IMAC, DHHS NCDEQ SWQS Class B Unit Aluminum 7429-90-5 D ug/I 100 U 100 U 100 U 100 U 230 100 U 100 U 100 U 100 U Aluminum 7429-90-5 T 87 ug/I 89 J 100 U 100 U 100 U 240 100 U 100 U 100 U 100 U Antimony 7440-36-0 D -- -- ug/I 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 5 U 5 U 0.5 U Antimony 7440-36-0 T 1 5.6 ug/I 5 U 0.5 U 0.5 U 5 U 0.5 U 0.5 U 5 U 5 U 0.5 U Arsenic 7440-38-2 D -- 150 ug/I 0.048 J 3.8 0.17 0.071 J 0.11 0.082 J 1 U 1 U 0.16 Arsenic 7440-38-2 T 10 10 ug/I 1 U 5 0.18 1 U 0.16 J+ 0.088 J 1 U 1 U 0.13 Barium 7440-39-3 D -- -- ug/I 51 140 28 16 35 88 41 41 38 Barium 7440-39-3 T 700 1000 ug/I 52 140 28 17 37 93 44 44 40 Beryllium 7440-41-7 D -- 6.5 ug/I 0.1 U 0.023 J+ 0.015 J+ 0.024 J+ 0.1 U 0.1 U 1 U 0.15 J 0.1 U Beryllium 7440-41-7 T 4 -- ug/I 1 U 0.011 J+ 0.1 U 1 U 0.1 U 0.1 U 1 U 1 U 0.1 U Boron 7440-42-8 D -- ug/I 390 520 50 U 1100 50 U 740 560 560 690 Boron 7440-42-8 T 700 -- ug/I 370 500 50 U 1200 50 U 770 580 590 720 Cadmium 7440-43-9 D -- 0.15 ug/I 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.8 U 0.8 U 0.08 U Cadmium 7440-43-9 T 2 -- ug/I 0.8 U 0.08 U 0.08 U 0.8 U 0.08 U 0.08 U 0.8 U 0.8 U 0.08 U Calcium 7440-70-2 T -- -- ug/I 96500 41800 11100 128000 5830 7780 57600 58100 66100 Chromium 7440-47-3 D -- 11 ug/I 0.5 U 0.78 0.37 J 0.12 J 0.47 J 0.34 J 5 U 5 U 0.091 J Chromium 7440-47-3 T 10 -- ug/I 5 U 0.38 J+ 0.21 J 5 U 0.97 J+ 0.31 J+ 5 U 5 U 0.15 J+ Cobalt 7440-48-4 D -- -- ug/I 1 0.42 0.05 J 0.67 0.77 1.6 0.36 J 0.34 J 0.28 Cobalt 7440-48-4 T 1 3 ug/I 1.4 0.46 0.057 J+ 0.74 J 0.95 J+ 1.5 0.32 J 0.34 J 0.26 Copper 7440-50-8 D -- 2.7 ug/I 1.5 0.73 J+ 1.2 1.5 1.2 0.55 5 U 5 U 0.42 J Copper 7440-50-8 T 1000 -- ug/I 1.3 J 0.33 J+ 0.54 5 U 0.48 J+ 0.15 J+ 1.3 J 5 U 0.16 J+ Iron 7439-89-6 D -- ug/I 50 U 42 J 50 U 50 U 180 76 50 U 50 U 36 J Iron 7439-89-6 T 300 -- ug/I 160 150 34 J 79 410 250 90 84 63 Lead 7439-92-1 D -- 0.54 ug/I 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 1 U 1 U 0.1 U Lead 7439-92-1 T 15 -- ug/I 1 U 0.1 U 0.1 U 1 U 0.21 J+ 0.1 U 1 U 1 U 0.1 U Magnesium 7439-95-4 T -- ug/I 11100 12800 4040 22600 2560 14700 12600 12600 16500 Manganese 7439-96-5 D -- ug/I 5 U 130 8.6 240 120 280 80 80 140 Manganese 7439-96-5 T 50 -- ug/I 4.1 J 160 11 290 150 300 94 94 150 Mercury 7439-97-6 T 1 0.012 ug/I 0.000493 J 0.000909 0.00028 J+ 0.00143 0.0005 U 0.00201 J+ 0.000809 0.00111 J+ 0.000719 J+ Methane 74-82-8 N -- -- ug/I 1.4 J+ 1.5 J+ 2.3 J+ 1.3 J+ 5.7 J+ 2.6 J+ 1.9 J+ 1.7 J+ 3.8 J+ Molybdenum 7439-98-7 D -- ug/I 1.4 14 0.13 J 12.7 0.5 U 0.5 U 5 U 5 U 0.26 J Molybdenum 7439-98-7 T 160 ug/I 1.6 J 13.8 0.21 J 12.4 0.5 U 0.5 U 5 U 5 U 0.23 J Nickel 7440-02-0 D -- 16 ug/I 2.1 1.1 0.64 1.1 0.48 J 3.2 5 U 5 U 0.48 J Nickel 7440-02-0 T 100 25 ug/I 5 U 0.64 0.5 U 5 U 0.5 U 1.9 J+ 5 U 5 U 0.49 J+ Potassium 7440-09-7 T -- -- ug/I 6230 5790 5000 U 11800 5000 U 3220 J 5000 U 5000 U 2580 J Selenium 7782-49-2 D -- -- ug/I 0.35 J 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 5 U 5 U 0.5 U Selenium 7782-49-2 T 20 5 ug/I 5 U 0.5 U 0.5 U 5 U 0.5 U 0.5 U 5 U 5 U 0.5 U Sodium 7440-23-5 T -- -- ug/I 3700 J 7180 7450 13600 6180 9750 11500 11500 10300 Strontium 7440-24-6 D -- ug/I 130 760 58 1600 47 74 230 230 180 Strontium 7440-24-6 T 14000 ug/I 140 860 65 1700 52 78 240 240 190 Thallium 7440-28-0 D -- -- ug/I 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.015 J 1 U 1 U 0.033 J Thallium 7440-28-0 T 0.2 0.24 ug/I 1 U 0.025 J 0.02 J 1 U 0.02 J+ 0.1 U 1 U 1 U 0.1 U Vanadium 7440-62-2 D -- -- ug/I 0.51 0.2 J 0.33 0.3 U 0.8 0.3 U 3 U 3 U 0.1 J Vanadium 7440-62-2 T 0.3 -- ug/I 3 U 0.19 J 0.41 3 U 1.5 J+ 0.15 J 3 U 3 U 0.089 J Zinc 7440-66-6 D -- 36 ug/I 17 10 U 37 32 10 U 5.6 J 10 U 10 U 10 U Zinc 7440-66-6 T 1000 -- ug/I 30 3 J 45 38 5 J 5.3 J 10 U 10 U 10 U Total Dissolved Solids TDS N 500000 500000 ug/1 366000 231000 J+ 94000 569000 82000 139000 J+ 329000 318000 337000 Total Organic Carbon TOC N -- -- ug/I 560 J 2000 800 J 1000 U 1100 1400 600 J 600 J 960 J Total Suspended Solids TSS N ug/I 3800 5000 U 2500 U 2500 U 19100 5000 U 2500 U 2500 U 2500 U Alkalinity, CO3 ALK-CO3 N ug/I 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 ALK-HCO3 N ug/1 200000 110000 37600 204000 28200 8700 152000 151000 189000 Alkalinity, lab ALK-LAB N -- -- ug/I 200000 110000 37600 204000 28200 8700 152000 151000 189000 Chloride 16887-00-6 N 250000 230000 ug/1 6700 7000 2500 9500 4600 58900 42300 42200 44700 Nitrogen, NO2 plus NO3 NO2-NO3 N -- -- ug/1 360 27 2100 240 20 U 20 U 30 33 20 U Sulfate 14808-79-8 N 250000 250000 ug/I 98900 50600 6600 235000 2700 14000 27100 27100 24100 Sulfide 18496-25-8 N -- -- ug/I 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U Chromium 6+ 18540-29-9 T 0.07 ug/I 0.033 0.03 U 0.074 0.03 U 0.22 0.03 U 0.03 U 0.03 U 0.03 U Dissolved Oxygen DO N -- mg/I 10.1 9.73 10.06 8.72 7.1 9.6 9.2 9.2 9 Temperature TEMP N Deg C 9.5 12 11.7 14.9 14.1 13 15 15 16 pH PH N 6.5 - 8.5 6.0 - 9.0 SU 6.45 7.2 7.7 7.3 7.6 7.8 7.7 7.7 7.5 Allen Steam Station Page 1 of 4 CSA Supplement 2 Table 3-5: Round 5 Analytical Results of Areas of Wetness Location: ANSP005 ANSW015 ANSW016 ANTD001 S-1 S-2 S-3 S-3 S 4 Sample Date: 3/21/2016 3/21/2016 3/21/2016 3/21/2016 3/21/2016 3/21/2016 3/21/2016 3/21/2016 3/21/2016 Sample Type Code: N N N N N N FD N N Sample Name/ID: AN-ANSP005 AN-ANSW015 AN-ANSW016 AN-ANTD001 AN-S-1 AN-S-2 AN-S-3 DUPLICATE AN-S-3 AN-S-4 Constituent CAS RN NCDEQ GWQS, Fraction NCDEQ SWQS Unit 0 --11W IMAC, DHHS Class B Turbidity, field TURB N NTU 6.56 13.8 1.61 0.6 12.8 2.2 1 1 1 1 Specific Conductivity SC IN PS/CM 383.6 241.8 98 613 84.4 258 466 466 524 Oxidation Reduction Potential ORP N I -- -- my 165.7 1 122.8 101.1 104.5 120.4 103 153 153 163 50 Exceeds NCDEQ 02L GWQS, IMAC, or DHHS standards. 50 Exceeds NCDEQ 02B SWQS Class B standards. Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard ]MAC = Interim Maximum Allow Concentration N = normal INS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 2 of 4 CSA Supplement 2 Table 3-5: Round 5 Analytical Results of Areas of Wetness Location: Sample Date: Sample Type Code: Sample Name/ID: S-5 3/21/2016 N AN-S-5 S-6 3/21/2016 N AN-S-6 S-7 3/21/2016 N AN-S-7 S-8 3/21/2016 N AN-S-8 S-9 4/20/2016 N AN-S-9 Constituent CAS RN Fraction NCDEQ GWQS, IMAC, DHHS NCDEQ SWQS Class B Unit Aluminum 7429-90-5 D ug/1 100 U 210 100 U 100 U 100 U Aluminum 7429-90-5 T 87 ug/I 100 U 86 J 100 U 82 J 100 U Antimony 7440-36-0 D -- -- ug/I 0.5 U 0.5 U 0.5 U 0.5 U 5 U Antimony 7440-36-0 T 1 5.6 ug/I 0.5 U 0.5 U 0.5 U 5 U 5 U Arsenic 7440-38-2 D -- 150 ug/I 0.053 J 0.18 0.063 J 0.047 J 1 U Arsenic 7440-38-2 T 10 10 ug/I 0.066 J 0.18 0.063 J 1 U 1 U Barium 7440-39-3 D -- -- ug/I 200 280 65 54 20.3 Barium 7440-39-3 T 700 1000 ug/I 210 55 J+ 72 55 20.9 Beryllium 7440-41-7 D -- 6.5 ug/I 0.049 J+ 0.17 0.1 U 0.066 J+ 1 U Beryllium 7440-41-7 T 4 -- ug/I 0.1 U 0.2 0.1 U 1 U 1 U Boron 7440-42-8 D -- ug/I 960 980 700 400 1230 Boron 7440-42-8 T 700 -- ug/I 1000 430 J+ 780 430 1300 Cadmium 7440-43-9 D -- 0.15 ug/I 0.1 0.16 0.08 U 0.08 U 0.8 U Cadmium 7440-43-9 T 2 -- ug/1 0.13 J+ 0.17 J+ 0.08 U 0.8 U 0.8 U Calcium 7440-70-2 T -- -- ug/I 24100 23400 17000 99100 133000 Chromium 7440-47-3 D -- 11 ug/I 0.12 J 0.17 J 0.14 J 0.24 J 5 U Chromium 7440-47-3 T 10 -- ug/I 0.2 J+ 0.25 J+ 0.15 J+ 5 U 5 U Cobalt 7440-48-4 D -- -- ug/I 34.5 45.4 7.7 1.1 0.77 J Cobalt 7440-48-4 T 1 3 ug/I 35.4 46.1 7_6 1.3 0.75 J Copper 7440-50-8 D -- 2.7 ug/I 1.7 5_5 0.34 J 1.3 5 U Copper 7440-50-8 T 1000 -- ug/I 0.53 J+ 1.2 0.24 J+ 2.8 J 5 U Iron 7439-89-6 D -- ug/I 50 U 50 U 82 50 U 50 U Iron 7439-89-6 T 300 -- ug/I 50 U 110 110 110 78.6 Lead 7439-92-1 D -- 0.54 ug/I 0.1 U 0.43 0.1 U 0.1 U 1 U Lead 7439-92-1 T 15 -- ug/I 0.1 U 0.47 0.1 U 1 U 1 U Magnesium 7439-95-4 T -- ug/I 15900 17200 7970 11000 21900 Manganese 7439-96-5 D -- ug/I 1300 2100 390 5 U 309 Manganese 7439-96-5 T 50 -- ug/I 1400 3 J+ 430 3 J 334 Mercury 7439-97-6 T 1 0.012 ug/I 0,0373 0.0663 0.0111 0.000917 J+ 0.00082 J+ Methane 74-82-8 N -- -- ug/I 2.6 J+ 8.2 J+ 11.5 J+ 1.4 J+ 10 U Molybdenum 7439-98-7 D -- ug/I 0.5 U 0.5 U 0.5 U 1.6 10.5 Molybdenum 7439-98-7 T 160 ug/I 0.5 U 0.5 U 0.5 U 1.4 J 10.1 Nickel 7440-02-0 D -- 16 ug/I 9.1 2.8 1.1 1.8 5 U Nickel 7440-02-0 T 100 25 ug/I 9.1 2.8 J+ 0.99 J+ 5 U 5 U Potassium 7440-09-7 T -- -- ug/I 5000 U 4070 J 5000 U 6050 11600 Selenium 7782-49-2 D -- -- ug/1 0.47 J 1.7 0.5 U 0.5 5 U Selenium 7782-49-2 T 20 5 ug/1 0.52 2.1 0.5 U 5 U 5 U Sodium 7440-23-5 T -- -- ug/1 13200 9730 8110 3520 J 12800 Strontium 7440-24-6 D -- ug/1 190 200 170 140 2050 Strontium 7440-24-6 T 14000 ug/1 200 140 190 140 2120 Thallium 7440-28-0 D -- -- ug/1 0.067 J 0.34 0.049 J 0.1 U 1 U Thallium 7440-28-0 T 0.2 0.24 ug/I 0.087 J 0.35 0.027 J 1 U 1 U Vanadium 7440-62-2 D -- -- ug/I 0.15 J 0.3 U 0.11 J 0.46 3 U Vanadium 7440-62-2 T 0.3 -- ug/I 0.13 J 0.073 J 0.14 J 3 U 3 U Zinc 7440-66-6 D -- 36 ug/I 11 11 3.6 J 18 24.2 J+ Zinc 7440-66-6 T 1000 -- ug/I 10 24 4.6 J 24 28.4 Total Dissolved Solids TDS N 500000 500000 ug/I 249000 J+ 290000 J+ 179000 J+ 343000 518000 Total Organic Carbon TOC N -- -- ug/I 1300 1000 U 1000 U 530 J 1000 U Total Suspended Solids TSS N ug/I 48000 12600 2500 U 3100 2500 U Alkalinity, CO3 ALK-CO3 N ug/I 5000 U 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 ALK-HCO3 N ug/I 13700 5000 U 13800 205000 196000 Alkalinity, lab ALK-LAB N -- -- ug/I 13700 5000 U 13800 205000 196000 Chloride 16887-00-6 N 250000 230000 ug/I 63800 81100 8300 6800 9600 Nitrogen, NO2 plus NO3 NO2-NO3 N -- -- ug/I 160 230 41 370 220 Sulfate 14808-79-8 N 250000 250000 ug/1 50100 53300 72300 99300 227000 Sulfide 18496-25-8 N -- -- ug/1 100 U 100 UJ 100 U 100 U 100 U Chromium 6+ 18540-29-9 T 0.07 ug/I 0.041 0.046 0.03 U 0.024 J 0.03 U Dissolved Oxygen DO N -- mg/I 5 3.2 2.3 9.8 6.2 Temperature TEMP N Deg C 14 14 17 11 16.5 PH PH N 6.5-8.5 6.0-9.0 SU 6.7 5._2 5_8 7.8 7.2 Allen Steam Station Page 3 of 4 CSA Supplement 2 Table 3-5: Round 5 Analytical Results of Areas of Wetness Location: S-5 S-6 S-7 S-8 S-9 Sample Date: 3/21/2016 3/21/2016 3/21/2016 3/21/2016 4/20/2016 Sample Type Code: N N N N N Sample Name/ID: AN-S-5 AN-S-6 AN-S-7 AN-S-8 AN-S-9 NCDEQ GWQS, NCDEQ SWQSUnit Constituent CAS RN Fraction IMAC, DHHS Class B Turbidity, field TURB N NTU 5 1.6 0.7 4.4 0.1 Specific Conductivity SC N PS/CM 373 407 228 568 1237 Oxidation Reduction Potential ORP N mV 150 239 186 144 187.2 50 Exceeds NCDEQ 02L GWQS, IMAC, or DHHS standards. 50 Exceeds NCDEQ 02B SWQS Class B standards. Notes: pm = micron pg/L = micrograms per liter pS/cm = microsiemens per centimeter ft = feet mg/L = milligrams per liter my = millivolts NTU - nephelometric turbidity units pCi/L = picocuries per liter SU = standard unit J = laboratory estimated concentration J- = estimated concentration, biased low J+ = estimated concentration, biased high U = results not detected at concentrations which equal the laboratory's method reporting limit 02B = North Carolina surface water standards as specified in T15 NCAC 02B .0211 and .0216 (amended effective January 2015) 02L = North Carolina groundwater standards as specified in T15A NCAC 02L D = dissolved Deg C = degree Celsius DHHS = North Carolina Department of Health and Human Services DO = dissolved oxygen GW = groundwater GWQS = groundwater quality standard ]MAC = Interim Maximum Allow Concentration N = normal NS = no standard T = total TDS = total dissolved solids TOC = total organic carbon Allen Steam Station Page 4 of 4 CSA Supplement 2 Table 3-6: Groundwater Elevation Table Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation AB-10D 06/26/15 574.97 9.06 565.91 -- -- -- AB-10S 06/26/15 575.05 9.08 565.97 -- -- -- AB-11D 06/26/15 618.07 8.63 609.44 -- -- -- 5/23/2016 6.62 611.45 AB-12D 06/26/15 651.75 13.78 637.97 -- -- -- 5/23/2016 10.42 641.33 AB-12S 06/26/15 651.69 15.6 636.09 -- -- -- 5/23/2016 11.9 639.79 AB-13D 06/26/15 648.54 10.58 637.96 -- -- -- AB-13S 06/26/15 648.72 10.85 637.87 -- -- -- AB-14BR 642.2 9/18/2015 13.98 628.22 5/2/2016 13.98 628.22 AB-14D 06/26/15 641.8 17.12 624.68 -- -- -- AB-1R 06/26/15 675.86 54.1 621.76 9/18/2015 55.25 620.61 5/2/2016 52.45 623.41 AB-2 06/26/15 638.74 17.41 621.33 9/18/2015 13.87 624.87 5/2/2016 13.87 624.87 AB-20D 06/25/15 649.27 12.86 636.41 9/18/2015 14.57 634.7 5/2/2016 11.01 638.26 AB-20S 06/25/15 649.42 12.54 636.88 9/18/2015 13.04 636.38 5/2/2016 11.93 637.49 AB-21BR 06/25/15 647.68 11.99 635.69 9/18/2015 11.4 636.28 5/2/2016 10.62 637.06 AB-21D 06/25/15 647.57 11.87 635.7 9/18/2015 11.25 636.32 5/2/2016 10.52 637.05 AB-21S 06/25/15 647.41 11.8 635.61 9/18/2015 11.26 636.15 5/2/20161 1 10.51 636.91 Allen Steam Station Page 1 of 8 CSA Supplement 2 Table 3-6: Groundwater Elevation Table Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation AB-21SL 06/25/15 647.36 11.45 635.91 9/18/2015 11.01 636.35 5/2/2016 10.4 636.96 AB-22D 06/25/15 644.81 45.77 599.04 9/18/2015 46.33 598.48 5/2/2016 45.42 599.39 AB-22S 06/25/15 644.89 49.88 595.01 9/18/2015 56.3 588.59 5/2/2016 50 594.89 AB-23BRU 06/25/15 646.47 120.21 526.26 9/18/2015 39.21 607.26 5/2/2016 21.57 624.9 AB-23S 06/25/15 646.61 10.32 636.29 9/18/2015 9.44 637.17 5/2/2016 8.21 638.4 AB-24D 06/26/15 647.86 13.18 634.68 9/18/2015 12.55 635.31 5/2/2016 11.32 636.54 AB-24S 06/26/15 647.86 11.02 636.84 9/18/2015 10.27 637.59 5/2/2016 9.3 638.56 AB-24SL 06/26/15 647.92 10.79 637.13 9/18/2015 10.54 637.38 5/2/2016 9.74 638.18 AB-25BR 06/26/15 647.11 10.62 636.49 9/18/2015 10.35 636.76 5/2/2016 10 637.11 AB-25BRU 06/26/15 646.76 10.19 636.57 9/18/2015 9.34 637.42 5/2/2016 9.55 637.21 AB-25S 06/26/15 647.22 7.3 639.92 9/18/2015 7.11 640.11 5/2/2016 6.95 640.27 AB-25SL 06/26/15 646.97 9.96 637.01 9/18/2015 9.7 637.27 5/2/2016 9.33 637.64 AB-26D 06/25/15 643.42 59.81 583.61 9/18/2015 61.27 582.15 5/2/2016 59.31 584.11 AB-26S 06/25/15 643.32 61.27 582.05 9/18/2015 62.92 580.4 5/23/2016 61.03 582.29 AB-27D 06/25/15 643.24 26.02 617.22 9/18/2015 26.03 617.21 5/2/2016 25.08 618.16 AB-27S 06/25/15 643.25 4.49 638.76 9/18/2015 4.51 638.74 5/2/20161 3.31 639.95 Allen Steam Station Page 2 of 8 CSA Supplement 2 Table 3-6: Groundwater Elevation Table Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation AB-28D 06/25/15 644.17 14.91 629.26 9/18/2015 14.65 629.52 5/2/2016 13.88 630.29 AB-28S 06/25/15 644.19 3.21 640.98 9/18/2015 3 641.19 5/2/2016 3 641.19 AB-29D 06/25/15 620.46 7.75 612.71 9/18/2015 7.9 612.56 5/2/2016 6.8 613.66 AB-29S 06/25/15 620.46 9.38 611.08 9/18/2015 9.35 611.11 5/2/2016 8.05 612.41 AB-29SL 06/25/15 620.45 9.08 611.37 9/18/2015 9.22 611.23 5/2/2016 7.98 612.47 AB-2D 06/26/15 638.33 16.8 621.53 9/18/2015 19.99 618.34 5/2/2016 14.2 624.13 AB-30D 06/25/15 621.38 1.84 619.54 9/18/2015 1.9 619.48 5/2/2016 0.88 620.5 AB-30S 06/25/15 621.21 3.36 617.85 9/18/2015 4.57 616.64 5/2/2016 3.65 617.56 AB-31D 06/25/15 627.25 48.34 578.91 9/18/2015 49.24 578.01 5/2/2016 47.35 579.9 AB-31S 06/25/15 627.2 49.3 577.9 9/18/2015 50.31 576.89 5/2/2016 48.68 578.52 AB-32D 06/25/15 624.4 47.4 577 9/18/2015 49.15 575.25 5/2/2016 46.32 578.08 AB-32S 06/25/15 624.34 41.6 582.74 9/18/2015 42.85 581.49 5/2/2016 46.58 577.76 AB-33D 06/26/15 627.39 33.44 593.95 9/18/2015 32.93 594.46 5/2/2016 31.03 596.36 AB-33S 06/26/15 627 26.61 600.39 9/18/2015 27.41 599.59 5/2/2016 24.91 602.09 AB-34D 06/25/15 632.93 21.2 611.73 9/18/2015 22.19 610.74 5/2/2016 19.63 613.3 AB-34S 06/25/15 632.88 20.23 612.65 9/18/2015 21.36 611.52 5/2/20161 18.741 614.14 Allen Steam Station Page 3 of 8 CSA Supplement 2 Table 3-6: Groundwater Elevation Table Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation AB-35BR 06/26/15 664.54 43.97 620.57 9/18/2015 45.58 618.96 5/2/2016 42.48 622.06 AB-35D 06/26/15 664.55 44.08 620.47 9/18/2015 45.65 618.9 5/2/2016 42.58 621.97 AB-35S 06/26/15 664.47 44.67 619.8 9/18/2015 45.67 618.8 5/2/2016 43.72 620.75 AB-36D 06/25/15 626.68 5.75 620.93 9/18/2015 8.56 618.12 5/2/2016 3.32 623.36 AB-36S 06/25/15 627.18 6.95 620.23 9/18/2015 9.2 617.98 5/2/2016 4.22 622.96 AB-37D 06/25/15 628.09 5.4 622.69 9/18/2015 8.45 619.64 5/2/2016 2.61 625.48 AB-37S 06/25/15 628.01 6.88 621.13 9/18/2015 8.47 619.54 5/2/2016 3.62 624.39 AB-38D 06/26/15 634.41 10.15 624.26 9/18/2015 13.35 621.06 5/2/2016 6.98 627.43 AB-38S 06/26/15 634.64 9.94 624.7 9/18/2015 13.12 621.52 5/2/2016 7.07 627.57 AB-39D 06/26/15 637.46 17.74 619.72 9/18/2015 19.97 617.49 5/2/2016 16.19 621.27 AB-39S 06/26/15 637.47 17.8 619.67 9/18/2015 20.11 617.36 5/2/2016 17 620.47 AB-4BR 648.552 9/18/2015 6.81 641.742 5/2/2016 6.81 641.742 AB-4D 649.17 9/18/2015 14.73 634.44 5/23/2016 7.8 641.37 AB-4S 06/26/15 650.46 12.63 637.83 -- -- -- 5/23/2016 9.23 641.23 AB-5 06/26/15 677.02 39.94 637.08 9/18/2015 41.01 636.01 5/2/2016 38.4 638.62 AB-6A 579.3 9/18/2015 9.05 570.25 5/2/20161 7.91 571.4 Allen Steam Station Page 4 of 8 CSA Supplement 2 Table 3-6: Groundwater Elevation Table Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation AB-611 06/26/15 579.9 8.38 571.52 9/18/2015 8.65 571.25 5/2/2016 7.74 572.16 AB-9D 06/26/15 582.72 14.49 568.23 9/18/2015 17.05 565.67 5/23/2016 13.24 569.48 AB-9S 06/26/15 582.73 12.59 570.14 9/18/2015 13.86 568.87 5/23/2016 12.06 570.67 BG-1D 06/25/15 694.88 59.21 635.67 9/18/2015 60.84 634.04 5/2/2016 58.5 636.38 BG-1S 06/25/15 695.13 59.65 635.48 9/18/2015 61.21 633.92 5/2/2016 58.58 636.55 BG-2BR 06/25/15 644.48 110.65 533.83 9/18/2015 59.5 584.98 5/2/2016 58.32 586.16 BG-2D 06/25/15 644.22 57.09 587.13 9/18/2015 57.75 586.47 5/2/2016 56.65 587.57 BG-2S 06/25/15 644.31 54.63 589.68 9/18/2015 55.36 588.95 5/2/2016 54.61 589.7 BG-3D 06/26/15 674.44 66.68 607.76 9/18/2015 69.42 605.02 5/2/2016 66.8 607.64 BG-3S 06/26/15 675.18 69.65 605.53 9/18/2015 70.06 605.12 5/2/2016 67.33 607.85 BG-4BR 662.077 9/18/2015 88.53 573.547 5/2/2016 88.53 573.547 BG-4D -- 661.624 0 661.624 9/18/2015 87.6 574.024 5/2/2016 87.6 574.024 BG-4S 662.193 9/18/2015 85.53 576.663 5/2/2016 85.53 576.663 GWA-14D 06/25/15 653.21 27.17 626.04 9/18/2015 30.18 623.03 5/2/2016 24.35 628.86 GWA-14S 06/25/15 653.57 25.91 627.66 9/18/2015 80.45 573.12 5/2/2016 23.5 630.07 GWA-15D 06/25/15 633.27 7.4 625.87 9/18/2015 9.91 623.36 5/2/20161 1 5.161 628.11 Allen Steam Station Page 5 of 8 CSA Supplement 2 Table 3-6: Groundwater Elevation Table Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation GWA-15S 06/25/15 632.71 6.91 625.8 9/18/2015 4.3 628.41 5/2/2016 4.62 628.09 GWA-16D 656.059 9/18/2015 52.33 603.729 5/2/2016 52.33 603.729 GWA-16S 656.593 9/18/2015 61.3 595.293 5/2/2016 51.3 605.293 GWA-17D 681.719 9/18/2015 64.6 617.119 5/2/2016 64.6 617.119 GWA-17S 681.89 9/18/2015 63.78 618.11 5/2/2016 63.78 618.11 GWA-18D 651.137 9/18/2015 23.74 627.397 5/2/2016 23.74 627.397 GWA-18S 651.04 9/18/2015 23.61 627.43 5/2/2016 23.61 627.43 GWA-19D 669.948 9/18/2015 42.33 627.618 5/2/2016 42.33 627.618 GWA-19S 669.849 9/18/2015 39.65 630.199 5/2/2016 39.65 630.199 GWA-1BR 06/25/15 629.37 15.1 614.27 9/18/2015 16.94 612.43 5/2/2016 12.68 616.69 GWA-11) 06/25/15 629.38 14.65 614.73 9/18/2015 16.9 612.48 5/2/2016 12.6 616.78 GWA-1S 06/25/15 629.27 14.03 615.24 9/18/2015 16.28 612.99 5/2/2016 11.9 617.37 GWA-21D 671.306 9/18/2015 32.61 638.696 5/2/2016 32.61 638.696 GWA-21S 671.24 -- -- -- 5/2/2016 24.7 646.54 GWA-22D 665.288 9/18/2015 32.61 632.678 5/2/2016 31.04 634.248 GWA-22S 665.141 9/18/2015 27.8 637.341 5/2/2016 27.8 637.341 Allen Steam Station Page 6 of 8 CSA Supplement 2 Table 3-6: Groundwater Elevation Table Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation GWA-23D 669.261 9/18/2015 28.3 640.961 5/2/2016 28.3 640.961 GWA-23S 670.089 9/18/2015 28.9 641.189 5/2/2016 28.9 641.189 GWA-24BR 675.452 9/18/2015 37.6 637.852 5/2/2016 37.6 637.852 GWA-24D 675.476 9/18/2015 36.35 639.126 5/2/2016 36.35 639.126 GWA-24S 675.346 -- -- -- 5/23/2016 35.44 639.906 GWA-26D 683.122 9/18/2015 45.24 637.882 5/2/2016 45.24 637.882 GWA-26S 683.103 9/18/2015 45.22 637.883 5/2/2016 45.22 637.883 GWA-21) 06/25/15 579.66 6.39 573.27 9/18/2015 8.46 571.2 5/2/2016 4.6 575.06 GWA-2S 06/25/15 579.36 8.83 570.53 9/18/2015 10.94 568.42 5/2/2016 6.7 572.66 GWA-3BR 06/25/15 583.6 9.91 573.69 9/18/2015 12.15 571.45 5/2/2016 9.22 574.38 GWA-31) 06/25/15 580.3 6.48 573.82 9/18/2015 8.73 571.57 5/2/2016 5.74 574.56 GWA-3S 06/25/15 583.59 12.11 571.48 9/18/2015 14.59 569 5/2/2016 11.31 572.28 GWA-4D 06/26/15 580.3 9.47 570.83 9/18/2015 11.42 568.88 5/2/2016 8.65 571.65 GWA-4S 06/26/15 580.32 8.6 571.72 9/18/2015 10.35 569.97 5/2/2016 7.95 572.37 GWA-5BR 06/26/15 581.17 18.8 562.37 9/18/2015 11.75 569.42 5/2/2016 9.38 571.79 GWA-51) 06/26/15 581.02 9.78 571.24 9/18/2015 11.35 569.67 5/2/2016 9.2 571.82 Allen Steam Station Page 7 of 8 CSA Supplement 2 Table 3-6: Groundwater Elevation Table Well Identification Date Top of Casing (TOC) Depth to Water (DTW) Groundwater Elevation GWA-5S 06/26/15 580.93 13.74 567.19 9/18/2015 16.28 564.65 5/2/2016 12.45 568.48 GWA-6BR 06/26/15 628.14 39.58 588.56 9/18/2015 41.15 586.99 5/2/2016 36.47 591.67 GWA-61) 06/26/15 628.55 41.87 586.68 9/18/2015 40 588.55 5/2/2016 35.45 593.1 GWA-6DA 630.162 9/18/2015 37.67 592.492 5/2/2016 37.67 592.492 GWA-6S 06/26/15 628.35 31.04 597.31 9/18/2015 32.56 595.79 5/2/2016 27.74 600.61 GWA-7D 06/26/15 594.27 16.96 577.31 9/18/2015 19.86 574.41 5/2/2016 14.98 579.29 GWA-7S 06/26/15 595.05 12.65 582.4 9/18/2015 14.75 580.3 5/2/2016 10.08 584.97 GWA-81) 06/26/15 676.66 66.05 610.61 9/18/2015 67.35 609.31 5/2/2016 64.02 612.64 GWA-8S 06/26/15 676.88 68.18 608.7 9/18/2015 70.22 606.66 5/2/2016 66.75 610.13 GWA-9D 06/25/15 647.65 10.95 636.7 9/18/2015 14.2 633.45 5/2/2016 8.2 639.45 GWA-9S 06/25/15 647.56 11.88 635.68 9/18/2015 14.111 633.45 5/2/2016 8.9 638.66 Allen Steam Station Page 8 of 8 CSA Supplement 2 Table 3-7: Summary of Cation -Anion Balance Differences Constituent: Molecular Weight (g/mol) Charge Equivalent Weight: Site Location Matrix Date Anions (negatively charged) Cations (positively charged) Charge Balance (%) Alkalinity, CO3 Alkalinity, HCO3 Chloride plus NitrogenO2 N , NOW 62 1 62 Sulfate 96.1 2 48.05 Sum of Anions Calcium Magnesium Potassium Sodium Sum of Cations 60 61 35.5 40.1 24.3 39.1 23 2 1 1 2 2 1 1 30 61 35.5 20.05 12.15 39.1 23 Result eq/L Result eq/L Result eq/L Result eq/L Result eq/L eq/L Result eq/L Result eq/L Result eq/L Result eq/L eq/L Allen SW-1 Surface Water 3/21/2016 0 0 10.4 0.17 83.2 2.344 0.36 0.006 74.6 1.553 4.073 52.2 2.603 12.8 1.053 2.92 0.075 11.2 0.487 4.218 2% SW-2 Surface Water 3/21/2016 0 0 10.6 0.174 86.5 2.437 0.39 0.006 79 1.644 4.261 53.1 2.648 13.5 1.111 3.04 0.078 11.4 0.496 4.333 1% SW-3 Surface Water 3/21/2016 0 0 15.6 0.256 4.7 0.132 0.12 0.002 6.2 0.129 0.519 6.76 0.337 1.92 0.158 0 0 4.42 0.192 0.687 14% SW-4 Surface Water 3/21/2016 0 0 0 0 43.2 1.217 0.23 0.004 129 2.685 3.906 21.9 1.092 6.3 0.519 0 0 33.7 1.465 3.076 -12% SW-5 Surface Water 3/21/2016 0 0 10.5 0.172 282 7.944 0.26 0.004 158 3.288 11.408 149 7.431 49.3 4.058 3.57 0.091 13.5 0.587 12.167 3% SW-6 Surface Water 3/21/2016 0 0 16.2 0.266 4.8 0.135 0.32 0.005 5.1 0.106 0.512 5.26 0.262 1.85 0.152 0 0 4.56 0.198 0.612 9% SW-7 Surface Water 3/21/2016 0 0 17.3 0.284 4.7 0.132 0.27 0.004 4.8 0.1 0.52 5.68 0.283 1.9 0.156 0 0 4.24 0.184 0.623 9% AB-14BR Groundwater 3/8/2016 0 0 58.7 0.962 2.7 0.076 2.4 0.039 4.6 0.096 1.173 17.1 0.853 4.21 0.347 4.48 0.115 8.96 0.39 1.705 18% AB-1 R Groundwater 3/14/2016 0 0 47.9 0.785 0.88 0.025 0.14 0.002 126 2.622 3.434 43.7 d 2.18 11 0.905 0 0 7.93 0.345 3.43 0% A13-2 Groundwater 3/18/2016 0 0 5.4 0.089 2.7 0.076 0.017 0 0.87 0.018 0.183 0.26 0.013 0.958 0.079 0 0 2.58 0.112 0.204 5% AB-20D Groundwater 3/17/2016 0 0 72.9 1.195 3.9 0.11 0.81 0.013 9.6 0.2 1.518 21 1.047 2.35 0.193 3.43 0.088 12.6 0.548 1.876 11% AB-21 BR Groundwater 3/18/2016 93.4 3.113 6 0.098 14.8 0.417 0.27 0.004 59.8 1.245 4.877 11.4 0.569 0 0 18.2 0.465 62.4 2.713 3.747 -13% AB-21 D Groundwater 3/18/2016 70.5 2.35 2.5 0.041 13.5 0.38 0.31 0.005 33.9 0.706 3.482 28.1 1.401 0 0 11.2 0.286 23.2 1.009 2.696 -13% AB-22D Groundwater 3/21/2016 0 0 113 1.852 15.4 0.434 0 0 37.3 0.776 3.062 39 1.945 12.2 1.004 3.57 0.091 13.7 0.596 3.636 9% AB-22S Groundwater 3/21/2016 0 0 21.4 0.351 9.7 0.273 0 0 5.8 0.121 0.745 2.88 0.144 1.77 0.146 0 0 12.8 0.557 0.847 6% AB-23BRU Groundwater 3/17/2016 136 4.533 0 0 4.7 0.132 0.38 0.006 51 1.061 5.732 53 2.643 0 0 17.3 0.442 77 3.348 6.433 6% AB-24D Groundwater 3/17/2016 0 0 60.3 0.989 10.6 0.299 0.25 0.004 14.6 0.304 1.596 111 Q 5.536 0 0 23.4 0.598 46.9 2.039 8.173 67% AB-25BR Groundwater 3/17/2016 109 3.633 243 3.984 9.3 0.262 0.3 0.005 43.3 0.901 8.785F4.O2 5.736 0 0 61.9 1.583 29.2 1.27 8.589 -1 % AB-25BRU Groundwater 3/17/2016 79.7 2.657 40 0.656 7.5 0.211 0.01 0 29.5 0.614 4.1381.097 1.2 0.099 18 0.46 37 1.609 3.265 -12% AB-26D Groundwater 3/21/2016 77.9 2.597 13.3 0.218 5.7 0.161 0.12 0.002 35 0.728 3.706El .2 0.656 0.054 44 1.125 35.1 1.526 2.905 -12% AB-26S Groundwater 3/21/2016 0 0 28.2 0.462 9.6 0.27 0 0 84.4 1.757 2.48998 9.34 0.769 0 0 14 0.609 2.376 -2% AB-27D Groundwater 3/21/2016 0 0 34.2 0.561 9 0.254 0.024 0 117 2.435 3.25845 9.54 0.785 3.46 0.088 14.2 0.617 3.335 1% AB-28D Groundwater 3/17/2016 26.8 0.893 72.9 1.195 5.4 0.152 0.12 0.002 22.1 0.46 2.702 24.7 1.232 3.08 0.253 17.1 0.437 19 0.826 2.748 1 % AB-28S Groundwater 3/17/2016 0 0 159 2.607 18.3 0.515 0 0 211 4.391 7.513 80.4 4.01 21 1.728 10.2 0.261 35.5 1.543 7.542 0% AB-29D Groundwater 3/17/2016 0 0 59.8 0.98 6.3 0.177 0.32 0.005 45.9 0.955 2.117 26.9 d 1.342 6.16 0.507 3.19 0.082 12.2 0.53 2.461 8% A13-21D Groundwater 3/18/2016 0 0 28.9 0.474 1.4 0.039 0.13 0.002 0.64 0.013 0.528 5.56 0.277 1.53 0.126 0 0 5.4 0.235 0.638 9% AB-30D Groundwater 3/16/2016 0 0 47.3 0.775 3.4 0.096 0.25 0.004 19.7 0.41 1.285 14.8 0.738 4.2 0.346 0 0 10.8 0.47 1.554 9% AB-31 D Groundwater 3/16/2016 52 1.733 99.2 1.626 7.9 0.223 0 0 37.5 0.78 4.362 58.6 2.923 0.161 0.013 8.76 0.224 26.8 1.165 4.325 0% AB-31S Groundwater 3/16/2016 0 0 0 0 8.1 0.228 0 0 118 2.456 2.684 34.6 1.726 4.74 0.39 0 0 13.4 0.583 2.699 0% AB-32D Groundwater 3/16/2016 0 0 65.3 1.07 5.1 0.144 0.16 0.003 24 0.499 1.716 20.9 1.042 5.26 0.433 4.43 0.113 11.1 0.483 2.071 9% AB-32S Groundwater 3/16/2016 0 0 32.5 0.533 8.6 0.242 0 0 2.5 0.052 0.827 5.5 0.274 3.28 0.27 3.62 0.093 4.17 0.181 0.818 -1 % AB-33D Groundwater 3/17/2016 0 0 80.7 1.323 2 0.056 0.35 0.006 4.9 0.102 1.487 17.8 0.888 3.02 0.249 9.14 0.234 15.3 0.665 2.036 16% AB-33S Groundwater 3/16/2016 0 0 120 1.967 6.1 0.172 2.4 0.039 386 8.033 10.211 115 d 5.736 34.6 2.848 27.9 0.714 13.1 0.57 9.868 -2% AB-34D Groundwater 3/16/2016 0 0 58.2 0.954 1.7 0.048 0.5 0.008 2.5 0.052 1.062 14.2 0.708 3.14 0.258 3.61 0.092 7.92 0.344 1.402 14% AB-34S Groundwater 3/16/2016 0 0 111 1.82 5.6 0.158 0 0 82.1 1.709 3.687 41.6 2.075 14.5 1.193 10.2 0.261 5.66 0.246 3.775 1 % AB-35BR Groundwater 3/16/2016 16.8 0.56 78 1.279 10.7 0.301 0.47 0.008 22.6 0.47 2.618 30.9 1.541 1.18 0.097 9.94 0.254 21.2 0.922 2.814 4% AB-35D Groundwater 3/16/2016 39.1 1.303 54.4 0.892 7.2 0.203 0.52 0.008 15.4 0.32 2.726 22.8 1.137 0.725 0.06 13.4 0.343 23.6 1.026 2.566 -3% AB-36D Groundwater 3/18/2016 0 0 64.8 1.062 2.1 0.059 0.53 0.009 5.4 0.112 1.242 16.6 0.828 4.58 0.377 3.26 0.083 8.65 0.376 1.664 15% AB-37D Groundwater 3/18/2016 0 0 59.6 0.977 4.4 0.124 2.8 0.045 3.8 0.079 1.225 17.4 0.868 4.62 0.38 3.5 0.09 8.79 0.382 1.72 17% AB-38D Groundwater 3/18/2016 0 0 141 2.311 4 0.113 0 0 24.3 0.506 2.93 29.8 1.486 9.46 0.779 15.9 0.407 18.5 0.804 3.476 9% AB-39D Groundwater 3/16/2016 0 0 105 1.721 13.4 0.377 1.2 0.019 26.6 0.554 2.671 34.8 d 1.736 8.15 0.671 4.7 0.12 15.6 0.678 3.205 9% AB-39S Groundwater 3/16/2016 0 0 134 2.197 9.6 0.27 0 0 2.3 0.048 2.515 31 1.546 7.36 0.606 2.53 0.065 12.1 0.526 2.743 4% AB-4BR Groundwater 2/2/2016 0 0 69.5 1.139 8.7 0.245 4.8 0.077 4.5 0.094 1.555 19.8 0.988 4.99 0.411 4.36 0.112 12.2 0.53 2.041 14% AB-5 Groundwater 3/18/2016 0 0 6.1 0.1 2.6 0.073 0 0 1.4 0.029 0.202 1.37 0.068 0.871 0.072 0 0 2.51 0.109 0.249 10% AB-6A Groundwater 3/18/2016 0 0 16.8 0.275 9.3 0.262 0.1 0.002 28.7 0.597 1.136 11.1 0.554 3.43 0.282 0 0 9.74 0.423 1.259 5% AB-6R Groundwater 3/18/2016 0 0 18.7 0.307 7.5 0.211 0.1 0.002 28.8 0.599 1.119 11.1 0.554 3.32 0.273 0 0 9.46 0.411 1.238 5% BG-1 D Groundwater 3/14/20161 45 1.5 35.5 0.582 5.5 0.155 0.067 0.001 60.3 1.255 3.493 19.1 0.953 0.334 0.027 2.78 0.071 40.4 1.757 2.808 -11 % Allen Steam Station Page 1 of 3 CSA Supplement 2 Table 3-7: Summary of Cation -Anion Balance Differences Constituent: Molecular Weight (g/mol) Charge Equivalent Weight: Site Location Matrix Date Anions (negatively charged) Cations (positively charged) Charge Balance (%) Alkalinity, CO3 Alkalinity, HCO3 Chloride plus NitrogenO2 N , NOW 62 1 62 Sulfate 96.1 2 48.05 Sum of Anions Calcium Magnesium Potassium Sodium Sum of Cations 60 61 35.5 40.1 24.3 39.1 23 2 1 1 2 2 1 1 30 61 35.5 20.05 12.15 39.1 23 Result eq/L Result eq/L Result eq/L Result eq/L Result eq/L eq/L Result eq/L Result eq/L Result eq/L Result eq/L eq/L BG-1 S Groundwater 3/14/2016 0 0 9.4 0.154 2.1 0.059 0.37 0.006 0.97 0.02 0.239 2.53 0.126 0.789 0.065 0 0 0 0 0.191 -11% BG-2BR Groundwater 3/14/2016 239 7.967 0 0 5.6 0.158 0.45 0.007 8.6 0.179 8.311 57.2 2.853 0 0 0 0 4.44 0.193 3.046 -46% BG-2D Groundwater 3/14/2016 0 0 68.6 1.125 2.1 0.059 0.93 0.015 1.8 0.037 1.236 12.8 0.638 4.36 0.359 7.19 0.184 8.58 0.373 1.554 11% BG-2S Groundwater 3/14/2016 0 0 53.9 0.884 10.5 0.296 1.9 0.031 1.2 0.025 1.236 14.7 0.733 3.6 0.296 0 0 10.8 0.47 1.499 10% BG-3D Groundwater 3/14/2016 0 0 77.3 1.267 2.6 0.073 0.52 0.008 1 0.021 1.369 14.3 0.713 4.68 0.385 2.94 0.075 8.9 0.387 1.56 7% BG-3S Groundwater 3/14/2016 0 0 92.6 1.518 1.7 0.048 0.45 0.007 1.2 0.025 1.598 20.2 1.007 3.87 0.319 3.84 0.098 10.2 0.443 1.867 8% BG-4BR Groundwater 2/4/2016 0 0 80.5 1.32 1.9 0.054 0.28 0.005 3.9 0.081 1.46 21.8 1.087 4.53 0.373 7.16 0.183 8.12 0.353 1.996 16% BG-4D Groundwater 2/3/2016 16.1 0.537 11.1 0.182 3.9 0.11 0.22 0.004 49.4 1.028 1.861 45 2.244 0.95 0.078 7.65 0.196 19.9 0.865 3.383 29% BG-4S Groundwater 2/4/2016 0 0 55.9 0.916 7.6 0.214 0.029 0 43.9 0.914 2.044 14.6 0.728 3.89 0.32 5.24 0.134 28 1.217 2.399 8% GWA-14D Groundwater 3/17/2016 420 14 0 0 4.6 0.13 0.2 0.003 1.3 0.027 14.16 456 22.743 0 0 15.8 0.404 34.3 1.491 24.638 27% GWA-14S Groundwater 3/17/2016 0 0 1.7 0.028 2.9 0.082 0.7 0.011 1.1 0.023 0.144 0.343 0.017 0.979 0.081 0 0 0 0 0.098 -19% GWA 15D Groundwater 3/16/2016 0 0 63.9 1.048 11.4 0.321 3.6 0.058 3.9 0.081 1.508 21.5 1.072 6.02 0.495 2.55 0.065 12.4 0.539 2.171 18% GWA-15S Groundwater 3/16/2016 0 0 36.7 0.602 5.4 0.152 1.8 0.029 12.9 0.268 1.051 13.4 0.668 3.91 0.322 4.23 0.108 9.44 0.41 1.508 18% GWA-16D Groundwater 2/5/2016 0 0 37.1 0.608 1.9 0.054 0.9 0.015 4 0.083 0.76 9.54 d 0.476 2.59 0.213 2.78 0.071 6.77 0.294 1.054 16% GWA-16S Groundwater 2/9/2016 0 0 89 1.459 4.1 0.115 0.15 0.002 5.1 0.106 1.682 19.5 0.973 3.37 0.277 2.99 0.076 20.6 0.896 2.222 14% GWA-17D Groundwater 2/4/2016 0 0 79.2 1.298 2.3 0.065 0.24 0.004 5.2 0.108 1.475 16.3 0.813 4.6 0.379 4.89 0.125 10.3 0.448 1.765 9% GWA-17S Groundwater 2/8/2016 0 0 48.2 0.79 7.4 0.208 0 0 43.7 0.909 1.907 13.6 0.678 4.66 0.384 3.84 0.098 24.6 1.07 2.23 8% GWA-18D Groundwater 2/8/2016 0 0 68.3 1.12 2.3 0.065 0.032 0.001 1.9 0.04 1.226 15.6 0.778 4.4 0.362 0 0 8.4 0.365 1.505 10% GWA-18S Groundwater 2/8/2016 0 0 44.3 0.726 4.3 0.121 0.012 0 3.5 0.073 0.92 9.75 0.486 3.46 0.285 0 0 8.78 0.382 1.153 11% GWA-19D Groundwater 4/22/2016 13.4 0.447 76.7 1.257 3.9 0.11 2.1 0.034 5.1 0.106 1.954 19.6 0.978 3.71 0.305 10.9 0.279 14.2 0.617 2.179 5% GWA-19S Groundwater 4/22/2016 0 0 29.2 0.479 3.5 0.099 0.44 0.007 6.4 0.133 0.718 5.18 0.258 1.55 0.128 0 0 10.8 0.47 0.856 9% GWA-1 BR Groundwater 3/17/2016 1.4 0.047 74 1.213 9.3 0.262 0.15 0.002 16.5 0.343 1.867 23.3 Q 1.162 3.7 0.305 3.78 0.097 14.1 0.613 2.177 8% GWA-1 D Groundwater 3/17/2016 5.7 0.19 67.7 1.11 11.6 0.327 0.1 0.002 12.5 0.26 1.889 14.3 0.713 2.43 0.2 12.1 0.309 18.1 0.787 2.009 3% GWA-1S Groundwater 3/17/2016 0 0 2.8 0.046 8.6 0.242 0.017 0 1.6 0.033 0.321 0.533 0.027 0.946 0.078 0 0 4.74 0.206 0.311 -2% GWA-21 D Groundwater 3/10/2016 1270 42.333 1570 25.738 5 0.141 1.2 0.019 3.1 0.065 68.296 97.8 4.878 1.53 0.126 18.2 0.465 23.1 1.004 6.473 -83% GWA-21S Groundwater 3/8/2016 0 0 17.9 0.293 4.7 0.132 0.14 0.002 3.2 0.067 0.494 1.67 0.083 0.916 0.075 0 0 9.49 0.413 0.571 7% GWA-22D Groundwater 2/3/2016 0 0 124 2.033 2.4 0.068 0.49 0.008 3.2 0.067 2.176 24 1.197 8.22 0.677 5.41 0.138 11.5 0.5 2.512 7% GWA-22S Groundwater 2/4/2016 0 0 7.8 0.128 7.3 0.206 0 0 20.2 0.42 0.754 1.08 0.054 0.747 0.061 2.82 0.072 14.2 0.617 0.804 3% GWA-23D Groundwater 2/2/2016 14.6 0.487 85.4 1.4 3.9 0.11 0.52 0.008 6.5 0.135 2.14 27.5 1.372 3.24 0.267 6.58 0.168 16.6 0.722 2.529 8% GWA-23S Groundwater 2/3/2016 0 0 8.3 0.136 5.8 0.163 0.2 0.003 10.7 0.223 0.525 1.38 0.069 0.719 0.059 0 0 10.2 0.443 0.571 4% GWA-24BR Groundwater 4/21/2016 25.5 0.85 45.8 0.751 4.6 0.13 2.8 0.045 10.4 0.216 1.992 27.3 1.362 2.54 0.209 4.73 0.121 8.81 0.383 2.075 2% GWA-24D Groundwater 4/22/2016 0 0 47.6 0.78 3 0.085 1.2 0.019 7.6 0.158 1.042 13.3 0.663 2.27 0.187 2.76 0.071 8.93 0.388 1.309 11% GWA-26D Groundwater 2/10/2016 0 0 0 0 4.4 0.124 0.37 0.006 6.7 0.139 0.269 10.8 0.539 1.39 0.114 2.71 0.069 14.8 0.643 1.365 67% GWA-26S Groundwater 2/10/2016 0 0 0 0 3 0.085 0.39 0.006 2.1 0.044 0.135 14.2 0.708 0.934 0.077 0 0 7.22 0.314 1.099 78% GWA-21D Groundwater 3/18/2016 0 0 54.7 0.897 2.1 0.059 0.088 0.001 0.96 0.02 0.977 11.9 0.594 2.58 0.212 0 0 8.74 0.38 1.186 10% GWA-2S Groundwater 3/18/2016 0 0 10.3 0.169 5.7 0.161 0.013 0 1.4 0.029 0.359 1.67 0.083 1.5 0.123 0 0 4.56 0.198 0.404 6% GWA-313R Groundwater 3/18/2016 45.5 1.517 0 0 5.9 0.166 0.016 0 52.9 1.101 2.784 23.2 1.157 0.522 0.043 10.2 0.261 24.9 1.083 2.544 -5% GWA-31D Groundwater 3/18/2016 0 0 66.2 1.085 3.4 0.096 0.4 0.006 9.6 0.2 1.387 20.4 d 1.017 3.94 0.324 2.81 0.072 8.99 0.391 1.804 13% GWA-3S Groundwater 3/18/2016 0 0 50.8 0.833 13.4 0.377 0 0 62.6 1.303 2.513 12.1 0.603 7.19 0.592 2.86 0.073 31.8 1.383 2.651 3% GWA-41D Groundwater 3/18/2016 0 0 57.5 0.943 7.5 0.211 0.042 0.001 55.5 1.155 2.31 23.3 1.162 8.53 0.702 3.66 0.094 12.3 0.535 2.493 4% GWA-4S Groundwater 3/18/2016 0 0 4.1 0.067 8.1 0.228 0 0 149 3.101 3.396 52.4t2.613 2.85 0.235 4.02 0.103 11.4 0.496 3.447 1 % GWA-5BR Groundwater 3/18/2016 0 0 45.1 0.739 6.2 0.175 0 0 43.7 0.909 1.823 13.73 2.94 0.242 8.78 0.225 22.3 0.97 2.12 8% GWA-5D Groundwater 3/18/2016 0 0 92.9 1.523 5.5 0.155 0.08 0.001 31 0.645 2.324 35.31 5.79 0.477 4.04 0.103 10.6 0.461 2.802 9% GWA-5S Groundwater 3/18/2016 0 0 42.9 0.703 4.4 0.124 0.16 0.003 8.7 0.181 1.011 9.09 0.453 3 0.247 0 0 6.43 0.28 0.98 -2% GWA-6BR Groundwater 3/16/2016 0 0 135 2.213 4.1 0.115 0.22 0.004 111 2.31 4.642 54 2.693 17.1 1.407 14.8 0.379 18 0.783 5.262 6% GWA-61D Groundwater 3/16/2016 193 6.433 0 0 7.6 0.214 0.17 0.003 68.9 1.434 8.084 95.2 Q 4.748 0.057 0.005 133 3.402 104 4.522 12.677 22% GWA-6DA Groundwater 2/3/2016 20.2 0.673 112 1.836 6.3 0.177 0.12 0.002 226 4.703 7.391 95.5 4.763 11.9 0.979 5.24 0.134 36.6 1.591 7.467 1 % GWA-6S Groundwater 3/16/20161 0 1 0 0 0 4.7 0.132 0.07 0.001 2340 48.699 48.832 209 10.424 144 11.852 0 0 0 0 22.276 -37% Allen Steam Station Page 2 of 3 CSA Supplement 2 Table 3-7: Summary of Cation -Anion Balance Differences Constituent: Molecular Weight (g/mol) Charge Equivalent Weight: Site Location Matrix Date Anions (negatively charged) Cations (positively charged) Charge Balance (%) Alkalinity, CO3 Alkalinity, HCO3 Chloride plus NitrogenO2 N , NOW 62 1 62 Sulfate 96.1 2 48.05 Sum of Anions Calcium Magnesium Potassium Sodium Sum of Cations 1 60 61 35.5 40.1 24.3 39.1 23 2 1 1 2 2 1 1 30 61 35.5 20.05 12.15 39.1 23 Result eq/L Result eq/L Result eq/L Result eq/L Result eq/L eq/L Result eq/L Result eq/L Result eq/L Result eq/L eq/L GWA-71D Groundwater 3/16/2016 0 0 87.7 1.438 2.7 0.076 0.22 0.004 93.6 1.948 3.466 45.5 2.269 12.6 1.037 3.23 0.083 14.2 0.617 4.006 7% GWA-7S Groundwater 3/16/2016 0 0 0 0 2.7 0.076 0.89 0.014 75.7 1.575 1.665 0.928 0.046 10.3 0.848 0 0 17.8 0.774 1.668 0% GWA-8D Groundwater 3/16/2016 0 0 86.3 1.415 2.5 0.07 0.36 0.006 1.5 0.031 1.522 17.2 0.858 7.15 0.588 4.08 0.104 9.98 0.434 1.984 13% GWA-8S Groundwater 3/16/2016 0 0 31.2 0.511 103 2.901 4.6 0.074 1.5 0.031 3.517 36.1 1.8 20.6 1.695 4.23 0.108 7.84 0.341 3.944 6% GWA-9D Groundwater 3/17/2016 0 0 52.4 0.859 3.9 0.11 1.5 0.024 5.6 0.117 1.11 14 0.698 2.43 0.2 4.25 0.109 9.88 0.43 1 1.437 13% GWA-9S Groundwater 3/17/2016 0 0 34.2 0.561 26.2 0.738 0 0 131 2.726 4.025 8.12 d 0.405 4.54 0.374 0 0 77.9 3.387 4.166 2% AB-20S Porewater 3/17/2016 0 0 308 5.049 2.1 0.059 0 0 158 3.288 8.396 148 7.382 14 1.152 15.7 0.402 16.7 0.726 9.662 7% AB-21 S Porewater 3/18/2016 0 0 387 6.344 33.7 0.949 0 0 87.5 1.821 9.114 143 7.132 29 2.387 9.51 0.243 11.9 0.517 10.279 6% AB-21 SL Porewater 3/18/2016 0 0 133 2.18 13.8 0.389 0 0 151 3.143 5.712 73.2 3.651 28.1 2.313 4.85 0.124 5.54 0.241 6.329 5% AB-23S Porewater 3/17/2016 0 0 64.1 1.051 6.7 0.189 0 0 9.4 j 0.196 1.436 17.5 0.873 4.9 0.403 8.75 0.224 3.39 0.147 1.647 7% AB-24S Porewater 3/17/2016 0 0 145 2.377 11.2 0.315 0 0 56.2 1.17 3.862 55.4 2.763 11 0.905 6.53 0.167 7.16 0.311 4.146 4% AB-24SL Porewater 3/17/2016 0 0 62.4 1.023 8 0.225 0 0 22.5 0.468 1.716 23.8 1.187 3.64 0.3 5.85 0.15 6.92 0.301 1.938 6% AB-25S Porewater 3/17/2016 0 0 184 3.016 8.9 0.251 0.024 0 113 2.352 5.619 88.6 4.419 14.2 1.169 6.62 0.169 11.5 0.5 6.257 5% AB-25SL Porewater 3/17/2016 0 0 189 3.098 8.4 0.237 0 0 83.3 1.734 5.069 73.3 d 3.656 11.8 0.971 9.23 0.236 12.3 0.535 5.398 3% AB-27S Porewater 3/17/2016 0 0 167 2.738 6.8 0.192 0.029 0 26.8 0.558 3.488 51.4 2.564 8.66 0.713 8.53 0.218 9.1 0.396 3.891 5% AB-29S Porewater 3/17/2016 0 0 173 2.836 8.7 0.245 0 0 95.6 1.99 5.071 77.2 3.85 16.8 1.383 5.52 0.141 10.2 0.443 5.817 7% AB-29SL Porewater 3/17/2016 0 0 40 0.656 7.5 0.211 0.071 0.001 198 4.121 4.989 83.7 4.175 6.7 0.551 6.26 0.16 10.9 0.474 5.36 4% AB-30S Porewater 3/16/2016 0 0 128 2.098 9.3 0.262 0 0 49.1 1.022 3.382 48.1 2.399 9.78 0.805 5.5 0.141 11.3 0.491 3.836 6% AB-35S Porewater 3/16/2016 0 0 222 3.639 4.9 0.138 0 0 420 8.741 12.518 118 5.885 46.4 3.819 51.5 1.317 20.3 0.883 11.904 -3% AB-36S Porewater 3/18/2016 0 0 257 4.213 2.9 0.082 0 0 5.6 0.117 4.412 58.3 2.908 15.7 1.292 6.86 0.175 17.8 0.774 5.149 8% AB-37S Porewater 3/18/2016 0 0 32.7 0.536 3 0.085 1.4 0.023 2.5 0.052 0.696 6.31 0.315 2.73 0.225 0 0 9.03 0.393 0.933 15% AB-38S Porewater 3/18/2016 0 0 90.1 1.477 2.3 0.065 0 0 5.1 0.106 1.648 16.6 Q 0.828 8.66 0.713 4.17 0.107 2.6 0.113 1.761 3% ANSP005 AOW 3/21/2016 0 0 200 3.279 6.7 0.189 0.36 0.006 98.9 2.058 5.532 96.5 4.813 11.1 0.914 6.23 0.159 3.7 0.161 6.047 4% ANSW015 AOW 3/21/2016 0 0 110 1.803 7 0.197 0.027 0 50.6 1.053 3.053 41.8 2.085 12.8 1.053 5.79 0.148 7.18 0.312 3.598 8% ANSW016 AOW 3/21/2016 0 0 37.6 0.616 2.5 0.07 2.1 0.034 6.6 0.137 0.857 11.1 0.554 4.04 0.333 0 0 7.45 0.324 1.211 17% ANTD001 AOW 3/21/2016 0 0 204 3.344 9.5 0.268 0.24 0.004 235 4.891 8.507 128 6.384 22.6 1.86 11.8 0.302 13.6 0.591 9.137 4% S-1 AOW 3/21/2016 0 0 28.2 0.462 4.6 0.13 0 0 2.7 0.056 0.648 5.83 0.291 2.56 0.211 0 0 6.18 0.269 0.771 9% S-2 AOW 3/21/2016 0 0 8.7 0.143 58.9 1.659 0 0 14 0.291 2.093 7.78 0.388 14.7 1.21 3.22 0.082 9.75 0.424 2.104 0% S-3 AOW 3/21/2016 0 0 151 2.475 42.2 1.189 0.033 0.001 27.1 0.564 4.229 58.1 2.898 12.6 1.037 0 0 11.5 0.5 4.435 2% S-4 AOW 3/21/2016 0 0 189 3.098 44.7 1.259 0 0 24.1 0.502 4.859 66.1 d 3.297 16.5 1.358 2.58 0.066 10.3 0.448 5.169 3% S-5 AOW 3/21/2016 0 0 13.7 0.225 63.8 1.797 0.16 0.003 50.1 1.043 3.068 24.1 1.202 15.9 1.309 0 0 13.2 0.574 3.085 00 S-6 AOW 3/21/2016 0 0 0 0 81.1 2.285 0.23 0.004 53.3 1.109 3.398 23.4 1.167 17.2 1.416[4.07 0.104 9.73 0.423 3.11 -4% S-7 AOW 3/21/2016 0 0 13.8 0.226 8.3 0.234 0.041 0.001 72.3 1.505 1.966 17 0.848 7.97 0.656 0 0 8.11 0.353 1.857 -3% S-8 AOW 3/21/2016 0 0 205 3.361 6.8 0.192 0.37 0.006 99.3 2.067 5.626 99.1 4.943 11 0.9056.05 0.155 3.52 0.153 6.156 4% S-9 AOW 4/20/2016 0 0 196 3.213 9.6 0.27 0.22 0.004 227 4.724 8.211 133 6.633 21.9 1.80211.6 0.297 12.8 0.557 9.289 6% NO2 + NO3 is being used as a surrogate for nitrate and the molecular weight of nitrate is assumed. Results of "0" are reported as non -detects by the analytical laboratory. Dataset consists of aqueous data associated with the first quarter of 2016 (even if dates do not align to traditional quarters). Formulas: Molecular Weight( g Result Value (Lg) CMolations (ea) - Anions(ea) Equivalent Weight = Charge eq/L �> CBE% - g eg Motecularwt.l g Y. Cations( )+ Anions( ) X 100 � mol 1 � Charge J Allen Steam Station Page 3 of 3 CSA Supplement 2