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Home My WebLink AboutNC0005363_W2-Ele1-FR_20150805Duke Energy Laboratory Services 13339 Hagers Ferry Road Bld. MG03A Huntersville, NC 28078 Project ID: Ash Basin GW Assessment — W2 Metals, Mercury, Hexavalent Chromium, Chloride, Sulfate, Sodium, Alkalinity, Bicarbonate, Carbonate, Turbidity, Total Dissolved Solids, Total Suspended Solids, Dissolved Oxygen, pH, Temperature and Conductivity Analytical Report 24274 Element One, Inc. ell 6319-D Carolina Beach Rd., Wilmington, NC 28412 910-793-0128 FAX: 910-792-6853 el lab(c)e1lab.com The following data for Analytical Report 24274 has- been reviewed for completeness, accuracy, adherence to method protocol, and compliance with quality assurance guidelines. Review by: Katie Strickland, B.S. Chemist March 31, 2015 Report Reviewed and Finalized By: Ken Smit4: � h, Laboratory Director March 31, 2015 elementOne 24274 Duke Report Packet Page 2 of 52 SUMMARY OF RESULTS elementOne 24274 Duke Report Packet Page 3 of 52 Summary of Analysis Summary of Method 200.8 Metals Analysis W2 1500 Old Whiteville Rd 24274-1 Element mg/L ----------------- Aluminum --------------- 0.209 Antimony < 0.001 Arsenic < 0.005 Barium 0.027 Beryllium < 0.001 Boron 0.007 Cadmium < 0.002 Calcium 15.8 Chromium < 0.005 Cobalt < 0.001 Copper 0.009 1 ron 0.027 Lead < 0.003 Magnesium 2.94 Manganese 0.015 Molybdenum < 0.005 Nickel < 0.005 Potassium 3.00 Selenium < 0.005 Strontium 0.061 Thallium < 0.0002 Vanadium < 0.0003 Zinc 0.035 Summary of Method 245.1 Mercury Analysis W2 1500 Old W2 1500 Old Whiteville Rd Whiteville Rd 24274-1 24274-1 dup Element mg/L mg/L Mercury #1 < 0.0002 #2 < 0.0002 elementOne 24274 Duke Report Packet Page 4 of 52 < 0.0002 < 0.0002 Summary of Analysis Summary of Method 218.6 Hexavalent Chromium Analysis W2 1500 Old Whiteville Rd 24274-1 Element pg/L Chromium (VI) < 0.1 Summary of Method 300.0 Anions Analysis W2 1500 Old Whiteville Rd 24274-1 Element mg/L Chloride 23.8 Sulfate 2.99 Summary of Method ASTM D6919-03 Sodium Analysis W2 1500 Old Whiteville Rd 24274-1 Element mg/L Sodium 4.20 elementOne 24274 Duke Report Packet Page 5 of 52 Summary of Analysis Summary of Standard Method 2320B Alkalinity Analysis W2 1500 Old Whiteville Rd 24274-1 Assay mg/L Alkalinity as CaCO3 1.99 Summary of Standard Method 4500 CO2 E Analysis W2 1500 Old Whiteville Rd 24274-1 Assay mg/L Bicarbonate (HC032- as CaCO3) 1.99 Carbonate (C032- as CaCO3) < 1 Summary of Standard Method 2130 B Turbidity Analysis W2 1500 Old Whiteville Rd 24274-1 Assay NTU Turbidity < 1.0 Summary of Standard Method 2540 C TDS Analysis W2 1500 Old W2 1500 Old Whiteville Rd Whiteville Rd 24274-1 24274-1 dup Assay mg/L mg/L Total Dissolved Solids 109 111 Summary of Standard Method 2540 D TSS Analysis W2 1500 Old Whiteville Rd 24274-1 Assay mg/L Total Suspended Solids < 2.5 elementOne 24274 Duke Report Packet Page 6 of 52 Summary of Analysis Summary of Standard Method 45000 G DO Analysis W2 1500 Old Whiteville Rd 24274-1 Assay mg/L Dissolved Oxygen 8.38 Summary of Standard Method 4500H+ pH Analysis W2 1500 Old Whiteville Rd 24274-1 Assay SU pH 5.26 Summary of Standard Method 2500 B Temperature Analysis W2 1500 Old Whiteville Rd 24274-1 Assay °C Temperature 15.3 Summary of Standard Method 2510 B Conductivity Analysis W2 1500 Old Whiteville Rd 24274-1 Assay pmhos/cm Conductivity 153 elementOne 24274 Duke Report Packet Page 7 of 52 ANALYTICAL NARRATIVE elementOne 24274 Duke Report Packet Page 8 of 52 Element One Analytical Narrative Client: Duke Energy Element One #: 24274 Client ID: Ash Basin GW Assessment -W2 Analyst: DBW, DAM, KLS, LAW, PQT, DMR Method: See table below Dates Received: 03/18/2015 Analytes: See table below Dates Analyzed: 03/18-20/15 Summary of Analysis The samples were collected by Element One, Inc. on 03/18/2015 and were analyzed for pH, temperature, conductivity and dissolved oxygen in the field immediately following sampling. Samples were returned to Element One, Inc., prepared and analyzed for the other parameters following method protocol. The samples were analyzed for metals according to EPA Method 200.8 protocol on a PerkinElmer ELAN 6100 ICP-MS. The samples were analyzed for mercury according to EPA method 245.1 on a PerkinElmer FIMS-100 CVAA mercury analyzer. Samples were prepared and analyzed for chromium (VI) according to SW-846 Method 0061 protocol on a Shimadzu 2010 HPLC unit and a Timberline RDR-1 Reaction Module. Samples were analyzed for chloride, sulfate by EPA 300.0 and sodium by ATSM D6919-03 on Metrohm 861/788 and 761/788 ion chromatograph system. Detection Limits The following is a list of parameters, methods used and the associated reporting limit for each: Parameter DL, mg/L Method Parameter DL, mg/L Method Beryllium 0.001 EPA 200.8 Antimony *0.001 EPA 200.8 Boron 0.005 EPA 200.8 Barium 0.005 EPA 200.8 Magnesium 0.02 EPA 200.8 Thallium *0.0002 EPA 200.8 Aluminum 0.005 EPA 200.8 Lead 0.003 EPA 200.8 Potassium 0.02 EPA 200.8 Mercury 0.0002 EPA 245.1 Calcium 0.05 EPA 200.8 Chloride 0.1 EPA 300.0 Vanadium *0.0003 EPA 200.8 Sulfate 0.1 EPA 300.0 Chromium 0.005 EPA 200.8 Sodium 0.05 ASTM D6919-03 Manganese 0.005 EPA 200.8 Alkalinity 1 SM 2320 B Iron 0.02 EPA 200.8 Bicarbonate 1 SM 4500 CO2 D Cobalt *0.001 EPA 200.8 Carbonate 1 SM 4500 CO2 D Nickel 0.005 EPA 200.8 Turbidity 1.0 NTU SM 2130 B Copper 0.003 EPA 200.8 TDS 10 SM 2540 C Zinc 0.005 EPA 200.8 TSS 2.5 SM 2540 D Arsenic 0.005 EPA 200.8 Dissolved Oxygen SM 45000 G Selenium 0.005 EPA 200.8 pH 1.0 SU SM 4500-H+ Strontium 0.005 EPA 200.8 Temperature SM 2500 B Molybdenum 0.005 EPA 200.8 Conductivity 10pmhos/cm SM2510B Cadmium 0.002 EPA 200.8 *Detection Limit based on client request. elementOne 24274 Duke Report Packet Page 9 of 52 Element One Analytical Narrative Analysis QA/QC Duplicate analyses relative percent difference (RPD), sample spike recovery and second source calibration verification data are summarized in the Quality Control Section. All QA/QC data was within the criteria of the method. Additional Comments The reported results have not been corrected for any blank values or spike recovery values. The reported results relate only to the items tested or calibrated. elementOne 24274 Duke Report Packet Page 10 of 52 QUALITY CONTROL SUMMARY elementOne 24274 Duke Report Packet Page 11 of 52 Summary of Quality Control Data 200.8 Sample Spike Recovery (QC limits: 75-125% for Recovery.) W2 1500 Old Whiteville Rd Element Recovery Aluminum 93% Antimony 94% Arsenic 108% Barium 92% Beryllium 98% Boron 103% Cadmium 106% Calcium 92% Chromium 104% Cobalt 105% Copper 107% Iron 107% Lead 98% Magnesium 128% Manganese 106% Molybdenum 98% Nickel 114% Potassium 123% Selenium 103% Strontium 122% Thallium 93% Vanadium 102% Zinc 89% elementOne 24274 Duke Report Packet Page 12 of 52 Summary of Quality Control Data Metals Second Source Calibration Check Recoveries (QC limits: ±10% for Second Source Continuing Check Standard*) Element ----------------- 1 ppb ----------------- 50 ppb ----------------- 100 ppb* ----------------- 250 ppb ----------------- Aluminum 102% 101 % 99% 102% Antimony 96% 95% 94% 93% Arsenic 125% 105% 103% 107% Barium 96% 95% 94% 95% Beryllium 101 % 99% 100% 99% Cadmium 107% 103% 104% 105% Chromium 89% 97% 94% 107% Cobalt 101 % 95% 96% 107% Copper 102% 98% 96% 102% Lead 99% 96% 101% 103% Manganese 96% 96% 96% 106% Molybdenum 196% 93% 92% 100% Nickel 109% 102% 104% 106% Selenium 109% 106% 106% 108% Strontium 88% 94% 102% 104% Thallium 98% 92% 105% 104% Zinc 108% 105% 106% 107% Element 21 ppb 250 ppb 1100 ppb* 2500 ppb Calcium ----- 100% 101 % 103% Iron 85% 101 % 96% 99% Magnesium 67% 93% 102% 105% Potassium 109% 98% 102% 102% Element 5 ppb 50 ppb 100 ppb* 250 ppb ----------------- Boron ----------------- 81 % ----------------- 110% ----------------- 99% ----------------- 109% Element 0.3 ppb 1 ppb 10 ppb* 25 ppb ----------------- Vanadium ----------------- 104% ----------------- 101 % ----------------- 99% ----------------- 101 % elementOne 24274 Duke Report Packet Page 13 of 52 Summary of Quality Control Data Mercury 245.1 Duplicate Analysis RPD (QC limits: < 20% for RPD) Sample ID RPD W2 1500 Old Whiteville Rd NA Mercury 245.1 Sample Spike Recovery (QC limits: 75-125% for Recovery) Sample ID Recovery W2 1500 Old Whiteville Rd 88% 218.6 Sample Spike Recovery (QC limits: 90-110% for Recovery) W2 1500 Old Whiteville Rd Element Recovery Chromium (VI) 103% 300.0 Sample Spike Recovery (QC limits: 90-110% for Recovery) W2 1500 Old Whiteville Rd Element Recovery Chloride 101 % Sulfate 99% Sodium ASTM D6919-03 Spike Recovery (QC limits: 90-110% for Recovery) Sample ID Recovery W2 1500 Old Whiteville Rd 105% Total Dissolved Solids SM 2540 C Duplicate Analysis RPD (QC limits: < 5% for RPD) Sample ID RPD W2 1500 Old Whiteville Rd 2.7% elementOne 24274 Duke Report Packet Page 14 of 52 SAMPLE CUSTODY elementOne 24274 Duke Report Packet Page 15 of 52 Lb LL - w CL a LL iz 0 E `o L me z 2 'W M IOH -oNH x { tv WH o 4 HORN a .Jo Jeupe}urO CL 0. 13L C 5Sl' Cll x #jPl4inl'el � X .1 6 t s uc q�e3i9 ° iullujIV `17QS 'l3 x sY 9+10 c� 5A "uZ 'A'L `J 'QN 'n X >1 'IN `4W 'uVq '6VI Ad `9.� 'nO 'JO X � 100 'go 'po '8 ° `g9 '&'v `a5 `I'v X n 2 0 r c a3 Cl Ck z CL 6L Rp E o __ e euMl�t fe ' ` i D B i '�. d �. 4 Alt A Ln M Cm C] C3 Inx W [V rd CV N r r r r r r r 4b u7 LL 4*7 4 Q L4 4L 4L �. •+ rrj Ll tti 0 O 0 0 � rerlif} � 9 C7 O �= ii3 ti} t29 C 3 lii Y elementOne 24274 Duke Report Packet Page 16 of 52 ANALYTICAL DATA elementOne 24274 Duke Report Packet Page 17 of 52 Analytical Calculations Metals, Mercury - Metals (mg/L) = ICP Results (jig/L)*Dilution 1000 Where- ICP-Hg Results = Raw sample concentration (ppb)—/CP-Hg -Data Sheet Dilution= Diluted Volume--/CP-MS Run Sheet/Hg Run Sheet Aliquot Chromium (VI)- Chromium (VI) (pg/L) = HPLC Results (pg/L)*Dilution Where - HPLC Results = Raw sample concentration (ppb)—HPLC -Data Sheet Dilution= Diluted Volume--HPLC Run Sheet Aliquot Anions- Anions (mg/L) = IC Results (mg/L)*Dilution Where - IC Results = Raw sample concentration (ppm)—/C-Data Sheet Dilution= Diluted Volume-- IC -Data Sheet Aliquot elementOne 24274 Duke Report Packet Page 18 of 52 Analytical Calculations Spike Recovery - Spike (%) _ (Spiked Result (pq/L) — Sample Result (pq/L)) X100 Spike Amount (pg/L) Where - Spike Result = Raw sample concentration (ppb)--/CP-Data Sheet Sample Result = Raw sample concentration (ppb)--/CP-Data Sheet Spike Amount--/cp-MS Spike Table Duplicate Analysis RPD- RPD (%) _ (Duplicate Result (pq/L) - Sample Result (pq/L)) X100 Average (pg/L) Where - Sample Result and Duplicate Results=Raw sample concentration (ppb)--ICP-Data Sheet Average= (Duplicate + Sample Results) 2 elementOne 24274 Duke Report Packet Page 19 of 52 0 C 0 r � 3 Vk G C] 7 C`5J r• N EQ Ci �` rg t7 G G 4J Q 73 J E� r. c: I -93 CL CO 93O ` _ a C [y} 47 v m ? Ir F = Am�yy L) -7 a i2 C�3 u) � N I C p. a� •L LIB I—_ m L!i SQ Ii i1? IE dC1 T ij Q, F, 0... a' idol_ P14H v ParvasaJd � CO CO 1 RIQi I « � Cry piwusswdun is L PIQH EN r AIJJVUOCIF SAljeIUGS" POAPA G pa�,Jast'iJ� ISfl.MFV 2 - Hd ji9AjjJy r~ -2L6ICI.U• _, . SLIJJf,-i ? G7 L9 0 Li o O CD pug uCh z (0) jaL410 IHi 9dGH'@] ;Bdl�,�, JBLFI�IlG;j � E # Cl I eldwe f m elementOne 24274 Duke Report Packet Page 20 of 52 E 97 Elemenli One. Ino. Lab ID '4-1 Well Owner Information If public, Wal I Owner ID what Is (and well No. if Public Wall public If public, how Well Site more than one Well Owner Naive' or Primate Water many homes Addmw well at property) Well? System serwe0 Name arO ID? ) i Lra.�'Y�ct Akan well Information (from MAI tag) Well Use Well Installation Well Casing {i.e. driniring, oat$ Well Depth Interval W*l I Sma-en Interval irrigation) u f , 1 sample Information Sample Date Sample Time Sample Takers If not taken at well head, Indicate why and Taken Talon Directly list any treatment devices installed prior to from Well sample location Head (y f N) elementOne 24274 Duke Report Packet Page 21 of 52 }Uv. Ix ho f.J C Held Coliection 1544 Did' Whiteville Road W2 j D,-i 4 w ��- pH SM 4.500 H g-2000 Temperature SM 25GO H-2000 pH CaIibrati urk (SUS 4 ✓ 7 `} u 10 - a,3te 5mpled Time Sampled Sample rvlat•;x bo Sample Type collected BY Sample pH redirg (SU) 5ampleTemp Reading 1500 Old WhiMvi Ile Road W2 Road Conductivity SM 25109-19,97 Conductivity Callbratlory Of)) 10µn heading nogn Reading 1000p€t Reading Date SompWd Time Sa letl Sample Matrix Sam laTy e Collected By Sample reading (µDI elementOne 24274 Duke Report Packet Page 22 of 52 1500 old"' WhltevIlle (toad W2 Dissolved Oxygen SM 4500 a G-2001 Do Calibration Barometric p reading Meter readout Date Sampled 1 } Time Sampled 11 7, Sample Matrix ti Sam le Type 611— Col lected B j 773 5amle neadirxg 1507 old Whiteville Road W2 Metals Date Sampled - Time Sampled } i Sample Matrix t arty ple Type [ Lollerted By 1507 old Whiteville Rand W2 Non -Metals Date Sampled l t Time Sampled M Sample Matrix SamptCLType Collected By elementOne 24274 Duke Report Packet Page 23 of 52 elementOne BATCH DIGESTION WORKSHEET (drinking and wastewater). Dale PreparecMigested: Start Time: q Stop Time. /1:Q6 Digestion black temperature: Analyst; LAB # Client FV (ML) BV {mt3 HNOa iMQ HCI (MQ 'Spike SoM Matrix Elements Laks 13LK 40 40 DA 0.2 Cal H2O Lab SPK i 40 40 40 DA GA 0.2 HH2O 40 0,2 40 40 0.4 0-2 + 40 40 0.4 0.4 0-2 al 40 0 0-2 4 7-1 40 4D 0.4 0.2 4ICJ 40 40 0.4 0,2 40 44 0.4 0.2 mil' r ill 40 40 0.4 0.2 40 40 0A 0.2 hM� 40 40 0-4 € -2 1 0, ,K,% 40 40 0A 0-2 40 40 0-4 0.2 - Li"I'ir�_} Icy 2 4} 40 40 0.4 0.4 0,4 0.2 0_2 0.2 Y't 40 40 40 40 � , r I 40 40 40 40 0.4 0.4 0_ -v' 4G 40 40 40 0A 0-4 0.2 46 40 40 0 4 0,2 40 40 0-4 0.2 40 40 6.4 0.2 NOTE. Lab blanks and Spikes must be prepared with each batch digestion � Spike ForiCP-MS: Using appropriate 25ppm standard mix A, 0, C, 1), 0, ,i spike solutions at the rate of 0.08mL & 0.27rni of 900ppm standard mix F per 40mL for IV W & DW samples TCLP Spike as (O.OmL of appropriate standard mixes) per 40rnl of sample digested. Spike st �~ c .�H C�4C 2'1415-C = I�lot # 0 41 C ok # {J21415 � J lot # 021415-J 5512M Nitric Acid Lrat # + i �i Hydrochloric Acid Lot # 51emenl One, Inc. Form 127 - Revrslon 3.0 elementOne 24274 Duke Report Packet Page 24 of 52 r*- Sample/Batch Report User Name: icp Computer Name: F88NT12-I CPMS Sample File, C'ElandatalSample%xl l.sam Report aatelTlme: Friday, March 20, 2015 05:11,15 dS Loc. Batch Ib Sempe 10 De Von Sample Type 5 aC STD2 Sample 103 2429&1.1 Sample 104 d 2429$•1,1 Duplipateof2 1D5 x50 242954.1 $ample 1w x5w 2'429&1,1 Duplicate &4 107 2429&2,1 Samlple 108 s 2429&2.1 Spiko - 1 of 6 109 x50 2446-11 Sample 110 X505 24295-2.1 Spike - 2 of 8 111 24297-1-1 Sample 112 xW 2447.1.1 Sample 11a Z4300 Sample 114 24302.1.1 $ample ll$ X60 24$02-1.1 Sample 11115 24302-2.1 samplo 117 x50 24302-2.1 Sample 1143 24289-1.1 Semple Ili) d 24269-1.1 Duplicate of 17 120 A) 242W-1,1 Sample 121 x50d 24269 1.1 Duplicate of 19 122 24274-1.1 Sample 123 s 24274-1.1 5piko- i ad21 124 x50 24274-1.1 Sample 125 xEOr, 24274-1.1 Splke - 2 of 23 126 2427134 $ample 127 2427G12 Sampld t I nit. Duani. Prep. Vol. Aliquot Val- Diluted Vol. $pros Ratio Page 1 elementOne 24274 Duke Report Packet Page 25 of 52 Dataset Report User Name_ icp Computer Name: F88NT12-IGPM Dataset File Path; CAEland etakLata eB031915-21 � � Report aatelTirne, Friday, March 20, 2015 00;11;27 Autosamplar Position_ 3 The Data;set Time Sample ID Salo IQ Read Type Deacript on Ink. QuarA Prop. Vol. AfigG4f Vol. 11WMThu 19-Mar-15 Blank Blank 1216*3 Thu 19-Mar-15 Standard 1 Standard #1 12:3831 Thu 19-Mar-15 Standard 2 Standard #2 12;4M Thu 19-Mor-15 Standard 3 Standard #3 ` 12745:27 Thu 1 O-Wr-1S Oc Std 1 QC Std #1 — V 12-48;55 Thu 19-1ar-15 OC Std 2 QC Std aka 12-5213 Thu 194.4ar-15 OC Sid 3 QC Std #$ 1n5:92 Thu 10 r--1S QC Std 4 QC Std 04 i2:39:20 Thu 1"ar--16 QC Std 5 QC Std 1415 13:02:49 Thu 1"ar-45 QC Std 9 QC Std 99, $10617 Thu 19-Mar45 C IC .Sid 10 QC Std 910 i3;0 M Thu l Mar-15 QC 45TD2 Sample 13:19;14Thu13Mar-'S 242915-1.1 sample 19'1@;42Thu 1 -rdar -� 24298-1.1 d Oupllcab of 13 1120:19Thu 1y Mal -.5 24298-1-1 x5t) Sample 13'25:56Thu 15-rdyr_:�) 24296-1-1 X50d dupbrnafa of 15 13:27:46Thu 19LMar-15 24296-2.1I Sarnp[6 13:34:34Thu 19-Mw l6 242W-2.i s Spike - 1 of 17 13:3402Thu 19•Mar-15 24296-2.i x50 _ Sample 13:372871tu 19-Mar-15 24296-2-1 xWS Spike - 2 of 19 114017 Tha 19-MEkF-15 2+4297-1-1 Sample 13.4417 Thu 19-Mar-15 Oc Sid 1 QC Std #1 13:47-55 Thu 19-Mer-15 Oc Stet 4 QC 3td #d 13.51.26Thu 19-Mar-15 24297-1-1 xw Sample 13:54153Thu 19-Mar-13 2430O Sample 13:58-V Thu 19t-Mar-15 243112-1.1 Sample 14+¢1.4gThu 14-M r-15 24302-1.1 X54 Sample 14 M 17 Thu 19.44ar-15 24302-2.1 Sample 1400:44 Thu 1Mar-15 24302-2.1 xx Sam* 14:1'.2'12 TAW 1'%Mo -15 24289.1.1 Sample 14.15:40 "Phu 19War-15 24269-1,1 d Duplicate Of 3p 14:19:08 Thu 19,-Mar-15 242$1�,1 ,1 x5o SarnplB 14:22:36 Thu 1"er-15 24265-1,1 x50d Duplicate of 32 14;26;06 Thu 19-Mar-16 cc Sod 1 Qc Std #1 14:29:34 Thu 19-Mar-15 CC Sid 4 QC $td #4 14:33TOThu 19-Mar-15 24274-1 1 sample 14:35.31 Thu 19-Mw.16 2r4274-1-1 a Spike - 1 9f,36 14:39:59Thu 19-1VISM5 24274-1A x550 Sanipl�! 14:43:27 Thu P9-Mar-15 24274-1.1 x50B Spike - 2 Crf 36 14:46:55Thu 19-Mar-15 24270-1 Sample 14:50-23Thu 19-Ku-15 24270�-2 Sample 1453E 52 Thu 19-Mar-15 QC bid 1 G1C $to #1 14-57-20 Thu 19-Ker-1S Qc Std 4 GG Std #q Page 1 elementOne 24274 Duke Report Packet Page 26 of 52 Diluted VOL Mal.: Cal L, -4% f. - - - - - - - - - - - -- - - - - - - - - - - jd ------------ k, al. � 1-1. m as m P51 0, s F ii, n Y, Y,. :; n 'T : elementOne 24274 Duke Report Packet Page 27 of 52 �5 as as a esa v 87A J S St st 3 R St St& R a FOtRJRA a N9a�ZSt & R a A � _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ „ „ „ „ „ „ „ , - 4 - +t- elementOne 24274 Duke Report Packet Page 28 of 52 i SamplelBatch Report User Name: icp Computer game: F88NT12-IGPMS Sample File: c:Tlandata'SamplelxIIsam, Report Date/Time: Friday, March 20, 2015 09,54,20 M3 Loc. Batch ID Semple ID Descripton Sample Type 5 Of, STp$ Sompla 203 24269-T.1 Semple 204 d 2426�-1.1 Dupllcme of 2 205 24274-1.1 Sampla 2D6 s 24274-1.1 Spike - 1 of 4 InML uen1. Prep. Vol, AllquctVol_ Diluted VoL Solids Rates Page 1 elementOne 24274 Duke Report Packet Page 29 of 52 Data ** Repoit eril User NameicpCertlputer Name- F8SNT12-1CP�MS Detaset File Path; C.Sandatall)atauet%032015-11Repot DatzTim e; Friday, March 20, 2015 09;54.25 AutosamPlar PosikW: 5 The Dataset Time Sample ID etch ID Read Type Description Ind- Quarrt Prep. Vol- AliqUof. Vol. Diltited Vol. 09:19:11 Fri 20-Mr-15 131ank Blank 09:20:23 Fri 2D-Mar-15 Stanr�ard T Standard #1 99:21:35 Fri 2D-Mar-t5 Sfwdard 2 Standard #2 00:22:40 Fri 20-Mar-I9 Standard 3 Standard #3 09:23:39 Fri 2Mar--15 QC std T QC std #1 09;25:10 Fri 20 ar-t5 QC Std 2 QC Std #2 09:26.21 Fri 2"Eir-15 QC $td 3 OC s#i #3 09.27.34 Fri 20-Mar-i s QC Std 4 OC Std #4 09:26A Fn 20-Mar-15 QC $td 15 0C Std #15 Q9:29:1a9 Fn Mar-15 QC Std 13 l%C Sid 49 09'31-11 Fit 20-Max-15 OC Std 111 {3O Sta #10 WN-24Fri 20-Mar-15 QCSTD2 Sample .i9-33:37 Fri 20-Mpr-15 242r39-1 .1 $amplL OMAI48 Fri 20-Mpr-15 24269-1-1 d UupllcsM of 13 49 X00 Fri 20-Wr•15 24274-1.1 Sample 09:37:12 Fri 20AUr-15 24274-1-1 s Spike - 1 of 15 09:3a:26 Fri 2DW;Rr-15 Oc I^- t9 1 Oc stil At1 r19:39:3s Fri 2NMar-15 OC Std 4 QC Std #4 Page 1 elementOne 24274 Duke Report Packet Page 30 of 52 i 9 § S 11 elementOne 24274 Duke Report Packet Page 31 of 52 a] ampleiRatch !Report User Name: iep Computer Name: F'88NT12-IGPMS Sample File: C:Elandelte1. amplelA 4.sam Report Date17ima; Friday, Mamb 20. 2015 1.3:22:15 A+S Loc Batch ID nple 10 aesoription Sampla "hype 5 QC SO 2 Sample 103 24269-1-1 Samplo 104 d 242%-1-1 Duplicataar2 11)5 24274.11 $ample 1 L5 24274-1-1 Splice -1 0t 4 107 X5 24 7G-2 sanvIe 108 24270-1 SerrPla 5 QC Sid 2 Sampie 105 24274-1.1 Salo 106 a 24274-1-1 ,Spike-1 of b� j r� / 7 / Init, Cluant Priap, Vol, Allqmt Vol, Diluted Vol Solids Ratio Pie 'I elementOne 24274 Duke Report Packet Page 32 of 52 Dataset Report User Name: icp Computer Name: F88NTI 2-1 GPMS o Dataset File PaPath:CAElandataV)WaSeW32045-2' vex Report DateJ-Fimei Friday, March 20, 2015 1122:25 ALdasampler Posltlon' 5 The Dataset TITM Sample 10 IGEkh ID Read Type Descilption [nit. truant Prep- Vat. Aliquot, Vol. OjMed Vd. 09:44;03 Fri 20-Mar-16 Blank Blank 09:45:24 Fri 20•Nar-15 Standard I Standard #1 09:46:45 Fri 20-Mar,15 Standard 2 Standard #2 00:40:08 Fri 20-Mar-15 Standard 3 ;Standard #3 09:49:27 PH 20-Mer-15 QC Std 1 QC Sid 0:50:48 PH 2"er-t5 QC Std 2 OC Std 02 09:52:09 PH 20-Mer-15 QC Std 3 OC Sid #3 09:93:31 PH 2"ar-16 OC Sid 4 OC Stid #4 09:54:53 Fri 20-Mar-15 GG Std 5 GG Std #5 09:6814 Fri 2"ar-15 OC Sid 9 QG Std #9 CA Z) 09:57:35 Fri 20-Mar-16 QC Std 10 QC Sid 910 �—:S 09:613:57 Fri 2",ar-16 OC Std 2 Sample 10;00;19 Fri 20 Oar-16 24269-1.1 Sample 10;01;40 Fri K4;ir-15 24269-Ij d Duplicate of 1 10!03:01 Fri 20-Mgir-16 24274-1.1 Sample 10:11422 Fri 20-Mar-15 24274-1-1 $ Spike - 1 of 15 1 N543 Fri 2V.M*r-1 5 24270-2 X5 Sample 100704 Fri 20-Mar-1 5 24270-1 aample 10:13827 Fri 20-Mar-15 QC Sid I 0C Sid 01 10!09,.48 Fri 2"ar-15 QC Sid 4 QC Sid 04 10:21:19 Fri 20-Mer-I 5 OC Std 2 Sample 10:26-22 PH 20-Mar-15 Standard 1 Standard #1 10;27-.46 Fri 20-Mar-15 Standard 2 Standard #2 10:29: 10 Fri 20-Mar-1 6 Standard 5 Standard *3 10:3D-34 Fri 29-Mar-15 QC Std I QC Sid #1 —�p rz 10:3$ 59 Fri 20-Mor-I 5 QC Sid 2 QC Sid #2 10:W23 Fri 20-Mar-15 OC Std 3 0C Std #3 10:�4AOF62CI-Mat,16 QC 5'W 4 OC Sid #4 10!35A2Ff120-IVIar-15 QC Sid 5 QC Std #5 10-'37-'37 Fri 213-MEkr-15 Qc sm 9 QC Sid #9 10-2ini Fri 2G-MOLO5 QC Std lil QC, Sid #1 G 1G-'4-26FrJ2Q-M6Lr-15 QC SM 2 Sample 10-.4t:32 IFFUG-Mw-15 24274-1.1 Sample 10-43-10 FeE20-Mar-15 24274-1.1 5 Spike - 1 of 34 10-44A1 F620-Mitr-15 QC Std I Gc &W #1 10A9-09 Fri 20-Mar-15 OC Std 4 Q-C Sid *4 Page I elementOne 24274 Duke Report Packet Page 33 of 52 B elementOne 24274 Duke Report Packet Page 34 of 52 z4wv M elementOne 24274 Duke Report Packet Page 35 of 52 lCP Standards and QC Standards Values Table Elerre^i ar Test Mass Symbol Stdd..#1 S 2 S�3 OC 41 OC 92 QC 43 OC 44 OC #5 OC #6 A OC #7 OC N OC #9 OC 410 4C #11 ppb P9 .25 LFRB LRB+ LRB+ LiNum 8 Li Lthium 7 Li 1 100 500 0 1 250 100 50 Beryllium 9 Be 1 100 5ti3 0 1 250 100 EO BOFOD 10 a 1 50 100 0 1 250 100 EO Boren 11 B 1 50 100 0 1 2510 1011 50 Sodium 23 Na 210 1100 5500 0 21 251M 1109 250 250000 Magnesium 24 Mg 210 1100 5500 0 21 251M 1109 250 100000 Magnesium 25 Adg 20 1100 5500 0 21 2500 1100 260 100000 Alumkm 27 AI 1 100 5w 0 1 250 100 50 100000 Phosphorus 31 P 20 1000 5000 0 20 2500 1000 200 100000 Patassium 3.9 K 20 1100 5500 0 21 2500 1100 2100 100000 Calcium 44 Ca 50 1100 5500 0 21 2500 1100 250 300000 Scarmhum 45 Titanium 47 Ti 1 100 frpo 0 1 250 100 50 2000 Titanium 49 Ti 1 100 Z103 0 1 250 100 51l 2000 Vanadium 51 V 1 100 -100 0 1 250 100 50 Vanadium 51 V 1 100 EW 0 1 250 100 56l Chromium 52 Cr 1 100 -rw 0 1 250 100 EO Chromium 53 Cr 1 100 EW 0 1 250 100 50 hm 54 Fe 20 1100 5500 0 21 2f00 1100 250 25MM Manganese 55 Mn 1 100 5Ci3 0 1 250 100 r,,0 Iron 57 Fe 20 1100 5500 0 21 25M 1100 250 250000 Cobalt 59 Co 1 100 0 1 250 100 EO Nickel 60 Ni 1 100 500 0 1 250 100 50 Copper 63 cu 1 100 5tAl 0 1 250 100 50 Capper 65 cu 1 100 500 0 1 250 100 f0 Zinc 66 Zn 1 100 5C0 0 1 250 100 f0 Zinc 67 zn 1 100 bw 0 1 2511 100 50 Zino 68 Zn 1 100 504D 0 1 250 100 50 Ck manium 72 Coe 1 100 5dJ4D 0 1 250 100 50 Arsenic 75 As 1 100 500 0 1 250 100 50 Selenium 77 Se 1 100 5C0 0 1 250 100 50 Selenium 82 Se 1 100 5017 0 1 250 100 bO Stonrn.n a9 Sr 1 100 5A0 0 1 250 100 EO MolML-nun 95 Mb 1 100 5w 0 1 250 100 50 2000 Molybdenum 97 A& 1 100 floo 0 1 250 100 50 2000 Molybdenum 98 Mn 1 100 507 0 1 200 100 50 2000 Rhodium 103 Silver 107 A0 1 100 500 0 1 250 100 50 :Silver 109 Ag 1 100 500 0 1 250 100 50 Cadmium 111 Cd 1 100 bw 0 1 250 100 69 Cadmium 114 Cd 1 100 Ew 0 1 250 100 50 Tin 118 Sn 1 100 500 0 1 250 100 50 Antimony 121 Sb 1 100 r1w 0 1 250 100 50 Antimony 123 Sb 1 100 faD 0 1 250 1011 fti Tellurium 128 Te 1 100 5w 0 1 250 100 EO Cesium 133 Barium 135 Ela 1 100 500 0 1 250 100 50 Barium 137 Ba 1 100 5C0 0 1 250 100 50 Lanthanum 139 La 1 100 500 0 1 250 100 ,,EO Tantalum 169 Ta 1 100 500 0 1 250 100 EO Platinum 105 Pt 1 100 503 0 1 250 100 50 GAd 181 Au 1 100 f00 0 1 250 100 50 Thallium 2D5 TI 1 100 bw 0 1 250 100 fA Lead 208 Pb 1 100 °Ew 0 1 250 100 50 Bismuth 200 Bi 1 100 6w 0 1 250 100 50 Thorium Z32 7h 1 100 -1w 0 1 250 100 50 Uranium 23B U 1 100 full 0 1 250 10i] EO Krypton 83 elemeniOne elementOne 24274 Duke Report Packet Page 36 of 52 2000 2000 2000 20(M 2000 2000 2000 2000 1000 1000 1000 1000 1000 1000 2000 2000 1000 1000 0 0-25 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 50 50 50 50 718 550 660 50 200 500 550 50 50 50 50 50 50 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 NO 1C0 1C0 100 100 100 100 1CO 100 NO 100 100 100 100 100 100 100 100 100 elementOne MERCURY BATCH DIGESTION - RUN WORKSHEET Data Prepamd1Dlgested: Prep By: ^, I SIF File#,i: Biock #1 Temperature, Start Time: S' f Madhine ID Block #2 TemperAwre: Stop Time, ° l(] _ Batch Anialyat; Black 93 Tern pr ratura: Typed By: r7wkfo Veriified By; f IVS Curve & QC's 0 ,4uglml working std BV. Ml M Ml Standard Lot fdumbem 1 Lab BLK 3# bags o 40 40 tandard 91 r working Std L t #: I o5i 0 2 0.00460 0.01rni 40 40 Working Standard, 3 a.G4 U9 0,10MI 40 _ 40 Lot ##: o icpo by,.k 4 108 Y9 0.20ml 43 40 UIndard Q . is 0-18 Ug 0.40rrll 40 40 Lot #: f S`- iR fi O, Ou 0,50MI 40 40 Standard #3 € C #3 log #: t f -- 7 QC #2= 0.06u 0-2ml t#2 std Oil �[J 8 QC #3= 0.0NgL 0,2rnf #3 std 40 40 Curve prepared b ' InKal Review 6.- Date; Time. — -Flnal CC Review 9 = Date: II.4 Time' , y Comments; Af LAI ## Client Wt(FV Ali Used ml used Samplo Val ml Spike pg 'I 14 V'R rum 17 _ q{c1 NO Se Lab blanks and spikes rrlust be ri ared with each batch d` ngti n Sp ke farr g, Use oalibratiun working 0.4ug/ml standard at the rate of 0.20ml per40mill sample - Digestion cherrlf(als h' 2 SO; 9 to be added in order at the faffo Wing rate per 40mr' voijimm 2,Oml...... NN0 3 @ 1.0'm.1....... Persuffate a 3.Om?......... KJ n(),, @ &Omf SC), Lot# ersuh`ate Lot # IP 2 HNO3Lo1-A BVtb- � HOLot#. t 3 ' fvf O4 Lot ## o tZ 15 - Hydrox Lot#' Q�l l r Cleer samples miter d estion with. 3.2ml of I-f drox lwnine solOon. Fl,meni One, rrc form 129-Rfw1slm 9-4 elementOne 24274 Duke Report Packet Page 37 of 52 Pr��e 1 0l ;,-- ¥ementO.e MERCURY BATCH DIGESION - RUN WORKSHEET Sy Bk + £ J-25 - mp+ AIS LA # CwM WVFV Ali Used m12ed vol,m Ski. 20:g16 -?I §o 1 21 J @ g \ 26 2 2e 2e 3 : 2 3 ,33 . 3 3 _3 . 3 . A .4 \ 41 4 42 . . 44 45 . - 46 � *S m m . s] 52 54 . . E+m#Oe° form ,2eR« , 0 Page 2« e|ementOne 24274 Duke Report Packet Page 38 G 52 ✓aPLC Data Sheet elementOne Lab ID * 24274r1.2 Client; Auks Client PG#: Date: 03.10-15 Detection Limit, (ligPL)_ 0.10 Analyst: LAW Mettoad ID : 219.6 Results Cr*#, Spike, % Sample, ID Cr+tt, Ng(L 011ulion pWL pq;L Rzwvvery RPD File OMMO LRB 10.032 a 0.1 031915-1 LRB CaAw LR6 spk 4.941 1 4.94 5.0 031915-1 LIMB ®pk_oae.VA 24Z74-1,2 4.04^G 1 K 0.1 031915-1_24274-1.2 0L7.Icd 24274-i.2spk 6.1-3p 1 5.13 5.0 103% 031915-1_74274-1,2spk 008.1sd Correlation, 0.9999396 8tanriends (PRb) D.0 PPB 4.D17 U.OQ a31915-1_0-6 PP9_d0�.t;d D.1 PPB 4-W4 0.10 94% 031915-1_0-1 PP9_004.0 1.0 PPB 1.0143 1.00 102% ❑319i&1 1.0 PPB 005.kd 5.0 PPB 4944 5.00 W % 031916-1 6,OPPB 0%.Icd 10.0 PPB 10.026 10-00 1CO% a31916-1 10.4 PPB 007.kd Owe lery Standards QC 5.0 4 B D 5.0 97% 031915-1 OC 5.0-001-lod Oc 5.0 55A58 5.0 101'h 031915-1_pp C(41,Icd Oc 5.0 4,9M 5.0 90% 031915-1_QC 5.0 _015,101 QL (M 0.108 0.1 1{)[ % 031915-1 X 0. i 004.iod elementOrm 44A'Ik-'�b C24274-131 AnelpskIAW 0311,1!i-1 elementOne 24274 Duke Report Packet Page 39 of 52 3119�20154:34;00 PM Page 1 f 1 ==== Shimadzu LabSolutions Browser Report == <-4 UVis >> IDAI Compound Name; Chromium He Flame S. gM915-1_BLANK _001.1ui BL 031915-1_BL�INI Q02.1 6L 031$15-1�Q_4PIPr�,ld 14.0 051915-1 0-1 PP5 004.led 10.1 031915-1 1-O PPE3 4d5-rod 11.0 PPB 031915-1 S.O PPH 006.Icd 5.0 PPB 031015-1 14.OPPB_007JGd .10.OPPB_ 031915-1 QC 5.0 001,1ld QC 5.C1 031915-1 JAL 0.1 041od L D.1 031916-1 !,fie 005.lDd LRB 031915-1 LfRB dpk_QOO.Icd LIMB spk 031915-1 24274-1.2 0C17.1cd :24274-1.2 03191.5-1_24274-1.2 spk-0[i8. 24274-1.2 spk 431915-1 2&2663-1.2 0Cl9,lcd 2d2�sg-1.2 031915-1�24269-1.2 spk_01(1.: 241i g-9.2 tpk O iM5-1-24283-3 011-10d 24283^3 031915-1_24283.3 dup_012 Ic,: 24283-3 dup U3i®15-1 24283.3 si3k_013,1er 242293-3 spk 981131 �i-1-24283-3 spk dup_Qi 24283-3 spk dup. 031915-1_2.1283-2 Sx_DDi .Ic-A 2429a3 3 5x, 031916-1_24263-3 5xdup_ 01 24283-3 5x dup 031915-1_2428 -3 5xspk_009 24283-3 5x spk 0311315-1_24283-3 5x spk dup, 24283-3 5x spk d 031g15-1,24M-310x 001Jc424283-310x 03`U115-124283-3 10 x spk-N. 24283-3 10 x spk 0=3' 915 24283-3 20x 001 Jo- 242#33-3 2ax 09' 91 1,3'1_24283-3 20x dup-Pt 24283-3 20x dup. OT 915-1 24283-20x spk_00324283-20x spk 0 3 915.1 2428,3-20x spk dup 24283-20x spk d�. 031915,1-QC 001,Icd GC r 031915-1 R._ 402.IGd BLK 031915-1�242$3-310x_003,1c 24293-514x 031915-1 24283-3 TDx spk_0024283-8 1(x spk 1031215-1^_2420-11Ox N5,1ci24283-1 IOx _ Q31415-1 _242]M-1 1 Dx dup_p' 'l 24283-I& dup n1915-1 24283-2 1 Ox 007-IC4 24283-2 16 091916-1 24283-210xdup-[ 2429S:F1Vciup 031915-1 24283-2 1) 10xDO,9.24283-2 D 1Ox . 031015-1 24283-2 I7 dup 10x, 24283-2 D du p 1 C 031915-1_24213 44 01TJcd 24283-4 031915-1_242834 duP _012 Ic 24283-4 dup 031 15.1_QG 5.O 013.10 Gc 5-0 03.1)151_BLJ 014.ItxJ eLK - Cane. - Daia Acqu Ired"lhme A Ukriid Area -0-0471 WI902015 9;!.17:37 AM ?�q 0.0 13{9812015 :15:41 AV 1388 0.01713#1pf2015 9:23:43AM 1274 U9413I1 W015 _ $_31:46 APA 9;39749 AM 5;47:52 AM 9:55:55 AM 10:09;14 AM 10--17;19AAM 2389 15{1;43 72971 14.6927 71296 4 1.11h1813MQJ2015 4.944 3f19f2015 1042e 3 SraI5 4.829 3119=16 0.000 3HS2015 3111 n 27 15 10:29.21 AM 2W9 C 032 3 19,'2015 10:33:25AM 550 4.9W 31132015 10-41;3-JAM � 77-_19 (LOCO 319..2015 10-49;33AM 0 5r 130 31191'2015 10:57:.M ALI 75675 -0.047 3119.E 15 11:0q:40 AM 341 6A44 3+19fi2015 11:13:43ANI -76892' 0.084 N1912016 1"I:21.46AM 2251 0.0137 3+1g12015 11.29 1AA1 1998 2.503 W1 015 �i1.37:53 4hd 37447' 2529 3d194di- 11:45.58AM 3.7ffb 0.212 3ri%P2015 12: Se PM 4103 0,211 3119f2015 2,70 E4,8a PM 417g1 3,515 W1012015 72;15:42 PM 52187 3.591 WS12015 12N4;4� Ph1 53283 0.122 3,°1g�2015 129 7 PKI 279 -3 4.654 3r1gt20i5 _ �-9144 0.433 311912015 _12:43:10pM _ 12:59:12 PM 1496 0,031 3119f2U15 1:07;15 PM 14PI 4.5L51 3119E 015 TA5;1-aPM €17401 4-6D4 3J19 616 1;23:21 PM 68016 5.058 311g12015 2.15:060M 74634 0,004`'d,0?r�➢i.5 2 -e07-'M D 0 124 3f19 015 2 31 'd9 PM _ -2821) 4,679 3i19�2015 2,3912 PM 6911B 0.123 311902015 2: 7:18 PM. ` 191 g 00124 311912015 2;5&f8- PM 2g27 1621311 42 311W201-5 0.104 3119f2015 3:03:21 PM 3:11:25 PM --W 2 _25371 0.107' 3119E 15 3:19:29 PM ZSB6 0.107 a'1812015 3 27:34 PM 2575. 0-110.3+19l2015 3 35: S7 PM _ 2923 0-11013d1912015 3 43:40 PM 1 4 gs6 W1.99015 3-r11; PM 2134 elementOne 24274 Duke Report Packet Page 40 of 52 fez . ,q'iq 9 3 4 HPLC-Run Sheet -L4 Z IL4 u 1.2- Analyst: Std. LoM. KJPL - k j ` 3 Lab ID 2q ZC9, t. Z Batcb ID: Ci QC Lot* ,Li Data: (1 SEEM .. _ a _ 1 i Fiea Crxa Run Sheet YAM nuimbom I of 2 elementOne 24274 Duke Report Packet Page 41 of 52 HPLC-Run Sheet Analyst: !� � Std, Lot #- 44VLr-1o1- LabID: -Z41 Z I Batch 10: QC L*t#: Date: [} y elementOne 24274 Duke Report Packet Page 42 of 52 }di a) �n cx y s L] � C! +C bn ppppppl1 ��ryy a+m+�fi0. d dd. i++1��a r4rp�p 2 V 16 1O 4} l} 0 r4' a e41 Q ey 'p r O7 IFi Nas NMKF •t �' � LL#4i4Y}-0D a} tli dO E6 �r'396 {4 �bdd �� 47d ds Nr dr dam ['6 _m eto LL � C6 ee5 v7 e+ rA o5 i+°l coi e0 M of M 92 M eq �.M q 12 nN'k N N N N N N N N N N N N N N N N N N a w}d�+ �4 Lli ci r- taffy = a�u`��gao n4ic farsofl iaA p@�,��7� o Cl ui V G L6 M :-i 0 k rl 10 6 r U e+5 M r7 m s*s m c icZ � ❑�q ,�L�3 `mp� a ror ia's � ' a64 4m&44 COw n L) V �Z hv Im+ 0 -m m9 a m"rY V elementOne 24274 Duke Report Packet Page 43 of 52 el ID: 24269 Client, Duke Date: 0310.15 IC tll:031915-24269 Analyst: LAW Sampla ID N2 C®nC- Dilution PPM Raaoveiy RPD 0 0 1 0-45 0.054 1 D.5 0.521 1 1 1.041 1 5 1 5.085 1 10 20,w 1 20 19.933 1 QC SM2 1 5-09 102% Blank i1 1 0-00 DL 0.053 1 1 01053 106% LR8 0 1 0-170 LRB SPK 5.214 1 5-21 104% 24274-1.3 4.204 1 4,20 24274.1.3 spk 9.470 1 9-47 10-S% 24269-1.3 3.077 1 M8 24269.1.3spk S.272 1 1 8.27 104% M- 5.056 1 1 15.46 101 6 01. 0.049 1 0-09 sN % Ri.ank 0 1 0-00 Correlation: 0.99993 Analysis Began:013,19.15 @ 1151 Analysis End. 03F19115 @ 1727 elementOne 24274 Duke Report Packet Page 44 of 52 eleme ntone Date: v 3 -�9 A Analyst, L-r t -) Batch name. p3 19 l - Z4Z.(Ori IBC Sample Sheet Lab ID # 42(,j Column: Me rasep C 2 100 Eluent: 4.0 mM tar ariel 0.75mM dipicclinic Flair Rate: 1.0 mL.'min. Method: 06919-M �vu l AS LOC. Semple ID Gh ,ent nalyte Results u dmL Re$ug u °m CGz 6 -Z IC {' O.Os . G l`i 2- '1 ti Ci 5. l 5 Zl9 b I Q L ry. 69.E L V 4 Y l & 4�j "CC':'-, CW.Std Vendor & Lot # QC Veto & Lol `p3 Curve Jr, Lyt #: 1 C. Spike % UL from tODO uWrnL Sid, to 10nnL awnple Comments: 5utirnifted farQG l7a[ee 0 2L By. QC Review- Data: Time By. _ Re-re� aegwr� rJ� �_�amr'n�: Re'-SuExnlrt p for QG aete By: Ott Reel Time- 2 elementOne 24274 Duke Report Packet Page 45 of 52 i L�} v, CO 4t M Nr CD � r u3 [D � M .10 LO N.t IT11 1�i1�. J I,-.- . m Cc [f3 Cyl 0 Lt3 Cf¢ Iti CL ' pp C3 r o ID El - CD u E r C cw la �I } t> IL +� 5: O 8 CO Q) O C C ju 4 Vf V J a 10 3 ,rah Q E IL II CDs a��6 w. us m OJ_ us n a O <m cn CA C? t 1 CM -E '� p T n d 0 .. r K'7 CV #V r r7 yfF+p �I I I I IJ � �g�tSlrit b 4 m G r C7 C+7 Q CM1i C4 T mC+'j '7` m N L K'V CO CG F+ rn a Vl J Oi arF •a _ _ L� qS CD 6? - CO 03 Qn W ^ C5 O Q 0 p ELr?D N all etc '� a Q — Q I7— Q _ v b o o Q -, li ati 11 ry G Lr3 qyc C3 .0 N c+} M rh M M ev 55' Ofi :I T N r Y--� CQ �y )FA E 6 � J N N N i*9 N N d — N SV N N tY1 N Ctt Cfl elementOne 24274 Duke Report Packet Page 46 of 52 Cr si m CC \ k yf\ Fmk 0 )fg §\� /t kf� � � 2 LL ƒ� � § . . \7 !� .o I\$ 2e« k� Q ; e � \ ) V3:2 J & & \ 2- AC �_ � 32 \ \ . e|ementOne 24274 Duke Report Packet Page 47 9 52 � � � elemelntOne Turbidity Lab ID 4 e 24269, 24274, 24296 24304 Reference Method: SM 213D D Analyst: DMR Dnte Sampled: 3118 Time Sampled: 124296 3112 10:05 -11:20 15.18) Analysis Data: 3118115 DuplicatBs Required for every Sample RPD must =+1- 10% Time Analysis Began: 18,017 Time Analysis Finished: 13:18 SAMPLE [I] NTU Ccrt_ Vaiti€r Differenco Refererii.+i Standards ONTU Std. 4,00 0 #DIVIOI Set metert4 ream 0.10 ,Std as 0.10 1.0 NTU Sid. 0,95 1,13( 95° Read and record the 0. �0 4.0. 20. 0 10-0 NTLI Std, 100 10,00 107% & 4 0. 0 Ref. SO& and the OC Std. AI; Stds-,houlcf a Tp to the: r,,ri, value by +/- 10% SAMPLE la NTU Mean Value RPD 013SI_RVATIONS oc <0.1 rrru -0.20 QC 20.0 NTU 21.0 105% QC 100,0 NTU 104.1 104% 2426-D-1. a 1.37 24274.1.3 0.52 242915-1.5 2,20 242%6 2.5 0.19 24'ki} l 3.37 24 a Gd-2 20.3 24H4-2 dup 20.9 20.60 3°la 24 804-3 17.5 24304-4 _ 3.36 t 3-09 240174-5 DNTU SU 1.0 NTU Std. � — 0.00 1. 03 c .20.0 Nru 20.E Qr_ 100-0 XTO i 103.6 103°1u 104% NOTES; SubmittedP for QA1 B [Ponu: DMR PMU elementOne Firm 133-11 Rev 4.0 elementOne 24274 Duke Report Packet Page 48 of 52 0 U') z cn � a O 0 2 � t#.ry a� 13 0) CO + C� G L 0 jy •{7 E3 UOs5 CCDL #r*J d.lL {V(5i tC") {ej�k1 E E Elip E � }� fia m 'c C} C} C3 C} 5 6 6 C; nY 0 r C5 It LO r �f J C51 t[- }' S`9 '� 6sy� E � I`ti CDOO P'. 'DO mC6G6 CL w b Y N 07 N �f- O fY O lr] (f) f17 N OD T QS LO {'7 d�-- r- 4 4 do E_ '�_ C G tti ED w r- oa w qc} w _ _ ifs t97 -7 u3 7 O ra ' Lon r? G t^J 4 CV O Cal C f4 O CiS C%9 04 4*1 r r• CO E m LD CS d} M W +X r--. C6 CT C6 SQ I`- 4�i C6 4b C6 0 m m m m N "" X CO CL m C5 [r] O N ,— r E m q. E m U x ro x x ro ca cci u7 p w E o fisry C5 N L C1 y C1 D m � �. N CO dD V ti vs elementOne 24274 Duke Report Packet Page 49 of 52 � 'til} iq yr r $ LO 9} �t9 �C7 u'7 4ii 'r: L th{ N V Y v V v V L �} { i V u 4i} 4P! ld'} I tip W O tti C3 s c3 r +[] LV w7 6 V -1 47 C c c v 2 i O o r, 'm C7 C} cN E yr, C 2 � } p �' f? W �LO Qj° s*7 O) €°4 �^ Cy59 P- In En, "} Y st V R7` *f Tcnfm N L iY} c� � aeQ7 rn MQ N M1 W) � GG O j m m N 4� d m $ ct A to 4i � t La S JE E +u E r r — r H P7- H 5 r r C7 �cp7 �u3y 7 Q C5 � [L 1 r 0 t fm bh c3 r r7 C� r 3 0 � � � C5 r � N � 4 4 E m Im CL p _ £] 'S OF E d' r C] _ C C] Qk 0 E 3 tV N + P cii i = Vx Z' €Y rq tJ M Cm N � rh elementOne 24274 Duke Report Packet Page 50 of 52 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Blank Sample Da Thursday, March 19, 2015 12:31:35 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 62460.4 ppb Be 9 1 ppb B 10 218.7 ppb �- B 11 952.1 ppb �- Na 23 72845.9 ppb Mg 24 25621.7 ppb Mg 25 3621.7 ppb Al 27 817.7 ppb P 31 2306 ppb K 39 292014.9 ppb Ca 44 24375 ppb Sc 45 235530.9 ppb Cr 52 11300.4 ppb Cr 53 44013 ppb Fe 54 33780.3 ppb Mn 55 1114.4 ppb Fe 57 5667.1 ppb Co 59 53 ppb Ni 60 47 ppb Cu 63 901.4 ppb Cu 65 455.7 ppb Zn 66 1448.1 ppb Zn 67 4184.3 ppb Zn 68 2471.3 ppb As 75 -1599.7 ppb Se 77 5079.8 ppb Se 82 6 ppb Sr 88 4915.7 ppb Mo 95 193 ppb Mo 97 133 ppb Mo 98 329 ppb I> Rh 103 632245.7 ppb Ag 107 229.7 ppb Ag 109 234 ppb Cd 111 7.2 ppb �- Cd 114 18 ppb �- Sb 121 198 ppb Sb 123 150.5 ppb Ba 135 66 ppb Ba 137 110.3 ppb �> Ho 165 1118820.4 ppb TI 205 161 ppb Pb 206 136 ppb Pb 207 124.7 ppb �- Pb 208 555 ppb Kr 83 8.7 ppb elementOne ICP-Data 1 of 37 e 24274-Metals 51.1 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 1 Sample Da Thursday, March 19, 2015 12:35:03 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 57297.9 ppb Be 9 345.3 1 ppb B 10 642.7 5 ppb �- B 11 2863.8 5 ppb �- Na 23 140839.1 21 ppb Mg 24 71004.3 21 ppb Mg 25 10058.9 21 ppb Al 27 5821.5 1 ppb P 31 8299.5 20 ppb K 39 483544.9 21 ppb Ca 44 25522.8 21 ppb Sc 45 225430.2 ppb Cr 52 19276.4 1 ppb Cr 53 45440.3 1 ppb Fe 54 46243.3 21 ppb Mn 55 15548.6 1 ppb Fe 57 11411.5 21 ppb Co 59 11610.4 1 ppb Ni 60 2526.7 1 ppb Cu 63 6450 1 ppb Cu 65 3207.6 1 ppb Zn 66 2738.1 1 ppb Zn 67 4430.7 1 ppb Zn 68 3345.6 1 ppb As 75 902.9 1 ppb Se 77 4843.3 1 ppb Se 82 243 1 ppb Sr 88 32263.5 1 ppb Mo 95 4611.8 1 ppb Mo 97 2908.1 1 ppb Mo 98 7501.3 1 ppb I> Rh 103 606929.8 ppb Ag 107 13250.7 1 ppb Ag 109 12587.7 1 ppb Cd 111 3099.8 1 ppb �- Cd 114 7513.9 1 ppb �- Sb 121 10662.3 1 ppb Sb 123 8213 1 ppb Ba 135 3147.2 1 ppb Ba 137 5478.7 1 ppb �> Ho 165 1085649.2 ppb TI 205 32114.3 1 ppb Pb 206 10817.8 1 ppb Pb 207 9546.7 1 ppb �- Pb 208 43353.8 1 ppb Kr 83 -177.1 ppb elementOne ICP-Data 2 of 37 e 24274-Metals 51.2 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 2 Sample Da Thursday, March 19, 2015 12:38:31 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 52082 ppb Be 9 30732.2 99.99982 ppb B 10 7951.8 99.99152 ppb �- B 11 36600.2 99.99738 ppb �- Na 23 5394929 1100.141 ppb Mg 24 3402902.2 1100.132 ppb Mg 25 463597.5 1100.121 ppb Al 27 456241.6 99.9997 ppb P 31 296481.6 1000.015 ppb K 39 9254382.5 1099.959 ppb Ca 44 313173.9 1100.258 ppb Sc 45 209618 ppb Cr 52 816250 100.0003 ppb Cr 53 139342.5 99.98016 ppb Fe 54 786283.9 1100.043 ppb Mn 55 1360783.7 100.0001 ppb Fe 57 307219 1100.014 ppb Co 59 1059413.1 99.99983 ppb Ni 60 226161.3 99.99977 ppb Cu 63 526661.7 100.0001 ppb Cu 65 262448 100.0002 ppb Zn 66 159847 100.0021 ppb Zn 67 30775.3 99.99569 ppb Zn 68 121841.1 100.0024 ppb As 75 198439.4 99.99866 ppb Se 77 20673.8 100.0119 ppb Se 82 22373.9 100.0001 ppb Sr 88 3145854.6 100.0018 ppb Mo 95 422659.9 100.0002 ppb Mo 97 266372.4 100.0003 ppb Mo 98 687216.4 100.0003 ppb I> Rh 103 565568.7 ppb Ag 107 1208468.5 99.99995 ppb Ag 109 1173366.5 100.0002 ppb Cd 111 290084.9 100.0001 ppb �- Cd 114 680412.7 99.99973 ppb �- Sb 121 996795.8 100 ppb Sb 123 759373.7 99.99993 ppb Ba 135 289753 99.99991 ppb Ba 137 504878 99.99991 ppb �> Ho 165 1029287.6 ppb TI 205 3233469 100.0006 ppb Pb 206 1007023.9 99.99994 ppb Pb 207 882359 99.99987 ppb �- Pb 208 4160203.6 100.0002 ppb Kr 83 -21282 ppb elementOne ICP-Data 3 of 37 e 24274-Metals 51.3 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 3 Sample Da Thursday, March 19, 2015 12:41:59 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 49153.8 ppb Be 9 144960.1 499.9927 ppb B 10 35420.2 499.2258 ppb �- B 11 163163.2 499.2241 ppb �- Na 23 25492803 5500.881 ppb Mg 24 15878524 5497.281 ppb Mg 25 2283113.7 5508.613 ppb Al 27 2233946.8 500.5927 ppb P 31 1350148.9 4992.745 ppb K 39 43252263 5501.307 ppb Ca 44 1407487.8 5500.343 ppb Sc 45 201892.9 ppb Cr 52 4055417 501.0242 ppb Cr 53 487858.2 498.9462 ppb Fe 54 3791032.4 5509.566 ppb Mn 55 6820734.3 501.0119 ppb Fe 57 1423581.2 5497.433 ppb Co 59 5350864.5 501.1402 ppb Ni 60 1048722.8 499.5261 ppb Cu 63 2634279.8 500.9861 ppb Cu 65 1213737.4 499.4959 ppb Zn 66 715016.1 498.9365 ppb Zn 67 124467 498.8026 ppb Zn 68 545881.1 499.1302 ppb As 75 933212.5 499.6879 ppb Se 77 80640.5 499.9207 ppb Se 82 104679.1 499.7002 ppb Sr 88 15149862 500.2757 ppb Mo 95 2151696.1 501.2842 ppb Mo 97 1284186.8 500.2817 ppb Mo 98 3564468.7 501.6244 ppb I> Rh 103 537487.3 ppb Ag 107 5531628.5 499.2625 ppb Ag 109 5299545.5 498.9935 ppb Cd 111 1338511.4 499.4259 ppb �- Cd 114 3472954.5 501.3316 ppb �- Sb 121 5237863.6 501.3143 ppb Sb 123 3976411.2 501.2495 ppb Ba 135 1404857.9 499.8064 ppb Ba 137 2643617.6 501.2472 ppb �> Ho 165 1008193.8 ppb TI 205 15597736 499.7061 ppb Pb 206 5181371 500.9282 ppb Pb 207 4510352.1 500.8071 ppb �- Pb 208 20547463 500.1623 ppb Kr 83 -102657.2 ppb elementOne ICP-Data 4 of 37 e 24274-Metals 51.4 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample Da Thursday, March 19, 2015 12:45:27 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 49911.8 ppb Be 9 3.3 0.00886 ppb B 10 812.7 8.93288 ppb �- B 11 3735.8 9.0431 ppb �- Na 23 35535.7 -5.5783 ppb Mg 24 21147.6 -0.15133 ppb Mg 25 3019.5 -0.07346 ppb Al 27 757.4 0.01596 ppb P 31 2002.9 0.2313 ppb K 39 303738.5 7.48669 ppb Ca 44 25715 20.82873 ppb Sc 45 191757.1 ppb Cr 52 8171 -0.16801 ppb Cr 53 42404.7 5.98123 ppb Fe 54 25989.1 -3.64434 ppb Mn 55 1176.7 0.01785 ppb Fe 57 4586.8 -0.72711 ppb Co 59 172.7 0.01229 ppb Ni 60 74.7 0.01712 ppb Cu 63 1121.1 0.06994 ppb Cu 65 578.7 0.08127 ppb Zn 66 1176.4 -0.03051 ppb Zn 67 4154.6 2.62641 ppb Zn 68 2095.2 0.01294 ppb As 75 -1001.1 0.18934 ppb Se 77 3775.5 -3.33002 ppb Se 82 25.6 0.09985 ppb Sr 88 4491.8 0.01188 ppb Mo 95 1696.8 0.3616 ppb Mo 97 1062.4 0.37428 ppb Mo 98 2722.1 0.34796 ppb I> Rh 103 532499.9 ppb Ag 107 173134.1 15.72593 ppb Ag 109 164474.9 15.58439 ppb Cd 111 54.4 0.0184 ppb �- Cd 114 135.4 0.01771 ppb �- Sb 121 312.7 0.01441 ppb Sb 123 223.7 0.01253 ppb Ba 135 88.7 0.012 ppb Ba 137 152.3 0.01156 ppb �> Ho 165 963864.1 ppb TI 205 815.7 0.02281 ppb Pb 206 331.7 0.02188 ppb Pb 207 293.7 0.02181 ppb �- Pb 208 1279 0.02056 ppb Kr 83 13.9 ppb elementOne ICP-Data 5 of 37 e 24274-Metals 51.5 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample Da Thursday, March 19, 2015 12:48:55 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 58908.9 ppb Be 9 351.7 1.00661 ppb B 10 1160.4 11.27721 ppb �- B 11 5383.6 11.52303 ppb �- Na 23 130953.1 12.03866 ppb Mg 24 68393.9 13.66879 ppb Mg 25 9802 13.75155 ppb Al 27 6001.3 1.04775 ppb P 31 8343.5 20.38179 ppb K 39 477676.2 22.94663 ppb Ca 44 23781.1 2.29287 ppb Sc 45 225769.7 ppb Cr 52 18397.3 0.84813 ppb Cr 53 40944.7 -0.83295 ppb Fe 54 45611.3 17.7194 ppb Mn 55 15661.2 0.9599 ppb Fe 57 11372.1 20.76249 ppb Co 59 12107.4 1.01027 ppb Ni 60 2611.4 1.09374 ppb Cu 63 6823.2 1.01561 ppb Cu 65 3382 1.08616 ppb Zn 66 2888.5 0.94596 ppb Zn 67 4225.3 0.93809 ppb Zn 68 3475.7 0.92677 ppb As 75 1172.1 1.29104 ppb Se 77 4350.4 -2.78488 ppb Se 82 267.3 1.1174 ppb Sr 88 34542.2 0.88295 ppb Mo 95 9848 2.01566 ppb Mo 97 6154.1 2.10178 ppb Mo 98 15971.9 1.97232 ppb I> Rh 103 600520.3 ppb Ag 107 32757.4 2.62532 ppb Ag 109 31877.2 2.66493 ppb Cd 111 3208.1 1.06927 ppb �- Cd 114 7525.1 0.97032 ppb �- Sb 121 11097.8 0.96546 ppb Sb 123 8371.9 0.95932 ppb Ba 135 3212.2 1.03594 ppb Ba 137 5586.4 0.9608 ppb �> Ho 165 1090441 ppb TI 205 33313.3 0.98241 ppb Pb 206 11200.9 0.99019 ppb Pb 207 9716.5 0.98553 ppb �- Pb 208 44343.9 0.98624 ppb Kr 83 -192.6 ppb elementOne ICP-Data 6 of 37 e 24274-Metals 51.6 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 3 Sample Da Thursday, March 19, 2015 12:52:23 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 62324.4 ppb Be 9 90583.7 246.4558 ppb B 10 25320.9 280.3701 ppb �- B 11 117131.2 281.6378 ppb �- Na 23 13719109 2564.878 ppb Mg 24 8737043.7 2623.724 ppb Mg 25 1159352.7 2426.185 ppb Al 27 1282962.9 249.6558 ppb P 31 804857.4 2581.644 ppb K 39 23172754 2543.808 ppb Ca 44 771265.6 2575.648 ppb Sc 45 236064.7 ppb Cr 52 2496835.5 267.4794 ppb Cr 53 307908.9 254.8923 ppb Fe 54 1977078.5 2473.602 ppb Mn 55 4150027.2 264.8831 ppb Fe 57 795022.3 2658.285 ppb Co 59 3279567.3 266.8989 ppb Ni 60 641198.6 265.302 ppb Cu 63 1545780.5 255.2887 ppb Cu 65 769121.5 274.8792 ppb Zn 66 453697.6 274.6279 ppb Zn 67 81016.6 275.6782 ppb Zn 68 346235.5 274.1563 ppb As 75 572288.6 266.5757 ppb Se 77 52700 271.6485 ppb Se 82 65005.4 269.6026 ppb Sr 88 9072405 260.2472 ppb Mo 95 2589365.1 524.3536 ppb Mo 97 1479022 500.5908 ppb Mo 98 4093659.8 500.5242 ppb I> Rh 103 618677.2 ppb Ag 107 3710330.1 290.8945 ppb Ag 109 3539695.9 289.4771 ppb Cd 111 809007.8 262.2692 ppb �- Cd 114 1942235.3 243.5157 ppb �- Sb 121 3002697.8 252.8169 ppb Sb 123 2266774.2 251.3609 ppb Ba 135 807709.8 252.7197 ppb Ba 137 1399416 233.355 ppb �> Ho 165 1146276.5 ppb TI 205 9196844.2 259.2008 ppb Pb 206 3030128.9 257.7042 ppb Pb 207 2636841.6 257.599 ppb �- Pb 208 12030284 257.6192 ppb Kr 83 -61462 ppb elementOne ICP-Data 7 of 37 e 24274-Metals 51.7 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample Da Thursday, March 19, 2015 12:55:52 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 56378.5 ppb Be 9 33161.4 99.71258 ppb B 10 9729.9 117.6968 ppb �- B 11 44104.4 115.8867 ppb �- Na 23 5675068.4 1111.314 ppb Mg 24 3571160.7 1126.692 ppb Mg 25 480034.1 1055.005 ppb Al 27 478929.4 98.18719 ppb P 31 308967.1 1040.857 ppb K 39 9861436.6 1123.719 ppb Ca 44 326977.8 1105.835 ppb Sc 45 217401.8 ppb Cr 52 842359 94.37231 ppb Cr 53 138800.9 99.40913 ppb Fe 54 817315.6 1054.547 ppb Mn 55 1421239.5 95.58175 ppb Fe 57 328556 1147.829 ppb Co 59 1117476.4 95.85688 ppb Ni 60 237718.3 103.7087 ppb Cu 63 553610.3 96.32507 ppb Cu 65 274385.4 103.3101 ppb Zn 66 167944.7 106.6725 ppb Zn 67 32068.1 106.5194 ppb Zn 68 128842.4 106.4158 ppb As 75 208903.5 103.0582 ppb Se 77 21903 103.1165 ppb Se 82 24191.9 105.7794 ppb Sr 88 3358019.4 101.4681 ppb Mo 95 441228.2 94.15351 ppb Mo 97 277110.7 98.86314 ppb Mo 98 714410.1 92.05903 ppb I> Rh 103 586798A ppb Ag 107 1289488.3 106.6288 ppb Ag 109 1253894 108.1824 ppb Cd 111 302677.7 103.4512 ppb �- Cd 114 713602 94.35687 ppb �- Sb 121 1023275.3 93.05505 ppb Sb 123 780790.8 93.52128 ppb Ba 135 300465.1 101.5714 ppb Ba 137 521806.3 94.00411 ppb �> Ho 165 1060878.3 ppb TI 205 3461786.6 105.3963 ppb Pb 206 1050642.7 96.52623 ppb Pb 207 909441.9 95.96344 ppb �- Pb 208 4384136.9 101.417 ppb Kr 83 -22725.7 ppb elementOne ICP-Data 8 of 37 e 24274-Metals 51.8 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 5 Sample Da Thursday, March 19, 2015 12:59:20 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 54769.6 ppb Be 9 15955.7 49.38884 ppb B 10 5237.8 64.13752 ppb �- B 11 23661.4 62.96628 ppb �- Na 23 1132811.7 219.6366 ppb Mg 24 730427.7 233.2634 ppb Mg 25 103525.5 230.4187 ppb Al 27 231263.8 49.14196 ppb P 31 58658.7 199.3248 ppb K 39 1871211.8 195.877 ppb Ca 44 87855.5 249.2134 ppb Sc 45 211683.5 ppb Cr 52 420112.9 48.28795 ppb Cr 53 89006 52.31545 ppb Fe 54 210969.9 251.7581 ppb Mn 55 690652.9 48.18486 ppb Fe 57 74745 256.7951 ppb Co 59 531213.3 47.3123 ppb Ni 60 112391.9 50.89756 ppb Cu 63 270932.5 48.87029 ppb Cu 65 135634.8 52.94015 ppb Zn 66 81210.8 53.12415 ppb Zn 67 17393 53.56216 ppb Zn 68 62071.9 52.2545 ppb As 75 101337 52.25698 ppb Se 77 12182.8 47.60673 ppb Se 82 11594.4 52.62214 ppb Sr 88 1495129.8 46.83017 ppb Mo 95 213622.1 47.30855 ppb Mo 97 134961.9 49.96083 ppb Mo 98 346679.5 46.35996 ppb I> Rh 103 565174.3 ppb Ag 107 623828 53.54805 ppb Ag 109 599271.2 53.66642 ppb Cd 111 145695.3 51.70101 ppb �- Cd 114 342434.1 47.00836 ppb �- Sb 121 501500.5 46.68664 ppb Sb 123 382849.3 46.94142 ppb Ba 135 144511.3 50.00552 ppb Ba 137 250343.1 46.16569 ppb �> Ho 165 1036161.2 ppb TI 205 1468066.7 45.7572 ppb Pb 206 511130.5 48.07222 ppb Pb 207 445495.8 48.12498 ppb �- Pb 208 2033960.7 48.16666 ppb Kr 83 -10090.5 ppb elementOne ICP-Data 9 of 37 e 24274-Metals 51.9 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 9 Sample Da Thursday, March 19, 2015 13:02:49 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 51951.5 ppb Be 9 5.7 0.01591 ppb B 10 636 6.09043 ppb �- B 11 3020.8 6.48132 ppb �- Na 23 60960 0.29167 ppb Mg 24 3988.5 -6.11338 ppb Mg 25 584 -5.97146 ppb Al 27 8111.3 1.73462 ppb P 31 2355.3 1.80855 ppb K 39 308268.2 9.24256 ppb Ca 44 23392.7 14.28925 ppb Sc 45 190395.4 ppb Cr 52 12226.6 0.38497 ppb Cr 53 86146.8 57.8263 ppb Fe 54 34528.5 10.52195 ppb Mn 55 1054.1 0.01092 ppb Fe 57 4783.6 0.60252 ppb Co 59 66 0.0022 ppb Ni 60 60 0.01066 ppb Cu 63 1119.4 0.07561 ppb Cu 65 550.7 0.07621 ppb Zn 66 4849 2.66353 ppb Zn 67 10135.4 28.83057 ppb Zn 68 5101.8 2.9403 ppb As 75 -2437.4 -0.63033 ppb Se 77 9139.9 33.9697 ppb Se 82 12.6 0.03782 ppb Sr 88 622.7 -0.11667 ppb Mo 95 636.7 0.11604 ppb Mo 97 412.7 0.12313 ppb Mo 98 1075 0.11794 ppb I> Rh 103 516995.7 ppb Ag 107 14537 1.34589 ppb Ag 109 13827.2 1.33441 ppb Cd 111 20.4 0.00558 ppb �- Cd 114 51.9 0.00556 ppb �- Sb 121 1559.8 0.14313 ppb Sb 123 1159.3 0.13971 ppb Ba 135 86.3 0.0118 ppb Ba 137 131.3 0.00788 ppb �> Ho 165 939274.3 ppb TI 205 237.3 0.00351 ppb Pb 206 275 0.01669 ppb Pb 207 246.3 0.01689 ppb �- Pb 208 1113 0.01691 ppb Kr 83 43.1 ppb elementOne ICP-Data 10 of 37 e 24274-Metals 51.10 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 10 Sample Da Thursday, March 19, 2015 13:06:17 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 49824.9 ppb Be 9 14801.4 50.36258 ppb B 10 4298 57.61146 ppb �- B 11 19531.3 56.92869 ppb �- Na 23 2434191.1 536.6048 ppb Mg 24 1427406.2 509.3373 ppb Mg 25 203406.7 505.8591 ppb Al 27 203826.7 47.56628 ppb P 31 123306.8 469.7264 ppb K 39 4014216.6 504.6177 ppb Ca 44 155897.7 563.7343 ppb Sc 45 187696.6 ppb Cr 52 379738.8 47.93087 ppb Cr 53 138950 119.3163 ppb Fe 54 379930.6 539.0933 ppb Mn 55 620993.7 47.58529 ppb Fe 57 143587.5 562.5605 ppb Co 59 493272A 48.25454 ppb Ni 60 105441.3 52.44728 ppb Cu 63 249470.3 49.4286 ppb Cu 65 124968.9 53.57981 ppb Zn 66 74822.7 53.77231 ppb Zn 67 23203.2 85.31105 ppb Zn 68 57754.9 53.44699 ppb As 75 89239.2 50.56894 ppb Se 77 16658.9 85.69725 ppb Se 82 9846.9 49.08412 ppb Sr 88 1379074.1 47.44543 ppb Mo 95 199835.6 48.6101 ppb Mo 97 126385.8 51.39014 ppb Mo 98 323890.4 47.57395 ppb I> Rh 103 514552.3 ppb Ag 107 558390.9 52.6465 ppb Ag 109 540841.7 53.19794 ppb Cd 111 128666 50.14768 ppb �- Cd 114 303460.5 45.75605 ppb �- Sb 121 463191.5 47.53556 ppb Sb 123 354418 47.90674 ppb Ba 135 132526.7 50.55517 ppb Ba 137 231988.5 47.16777 ppb �> Ho 165 940077.5 ppb TI 205 1375515.8 47.267 ppb Pb 206 476190.3 49.36942 ppb Pb 207 412366 49.10682 ppb �- Pb 208 1895109.8 49.47314 ppb Kr 83 -9291.2 ppb elementOne ICP-Data 11 of 37 e 24274-Metals 51.11 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC STD2 Sample Da Thursday, March 19, 2015 13:09:46 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 57236.1 ppb Be 9 324.7 0.95749 ppb B 10 979.7 9.4843 ppb �- B 11 4369.4 9.23524 ppb �- Na 23 121003.5 10.96005 ppb Mg 24 65040.1 13.38095 ppb Mg 25 9331.1 13.48946 ppb Al 27 5711.1 1.03221 ppb P 31 7945.8 20.06453 ppb K 39 462821.5 23.22876 ppb Ca 44 23781.1 5.45201 ppb Sc 45 215924 ppb Cr 52 18099.3 0.89154 ppb Cr 53 48690.2 8.71874 ppb Fe 54 43487.6 17.06543 ppb Mn 55 14927.9 0.9484 ppb Fe 57 10996 20.89663 ppb Co 59 11322.4 0.98052 ppb Ni 60 2515.3 1.09407 ppb Cu 63 6300.9 0.96739 ppb Cu 65 3189.9 1.05944 ppb Zn 66 2743.1 0.9194 ppb Zn 67 5281.5 5.5926 ppb Zn 68 3373.3 0.94679 ppb As 75 1061.9 1.25295 ppb Se 77 4457.1 -1.16425 ppb Se 82 237 1.02638 ppb Sr 88 33053.7 0.87585 ppb Mo 95 9401.9 1.99593 ppb Mo 97 6012 2.13005 ppb Mo 98 15275.4 1.956 ppb I> Rh 103 578820.E ppb Ag 107 13667.6 1.12828 ppb Ag 109 13323.4 1.14658 ppb Cd 111 3053.9 1.05554 ppb �- Cd 114 7219.3 0.96551 ppb �- Sb 121 10709.6 0.96342 ppb Sb 123 8131.1 0.96363 ppb Ba 135 3093.9 1.03187 ppb Ba 137 5364.9 0.95445 ppb �> Ho 165 1054327.5 ppb TI 205 32354.2 0.98681 ppb Pb 206 10787.4 0.98547 ppb Pb 207 9317.4 0.97698 ppb �- Pb 208 42742.7 0.98293 ppb Kr 83 -180.8 ppb elementOne ICP-Data 12 of 37 e 24274-Metals 51.12 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample Da Thursday, March 19, 2015 13:44:27 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 51541.8 ppb Be 9 1 0.00058 ppb B 10 241 0.81885 ppb �- B 11 1149.4 1.0672 ppb �- Na 23 54516.6 -2.34035 ppb Mg 24 22923.5 -0.07865 ppb Mg 25 3179.6 -0.21592 ppb Al 27 739.4 0.00003 ppb P 31 1951.5 -0.46077 ppb K 39 302771.8 4.66733 ppb Ca 44 27789.8 21.4576 ppb Sc 45 209061.2 ppb Cr 52 12865.1 0.30842 ppb Cr 53 63143 24.32024 ppb Fe 54 30856 0.43062 ppb Mn 55 1151.4 0.00994 ppb Fe 57 4827.9 -1.07312 ppb Co 59 63 0.00136 ppb Ni 60 51.3 0.00396 ppb Cu 63 873 0.01033 ppb Cu 65 413.7 0.00071 ppb Zn 66 1354.8 0.03019 ppb Zn 67 5700.5 7.43146 ppb Zn 68 2307.6 0.06329 ppb As 75 -1463.1 -0.00921 ppb Se 77 7166.8 15.87288 ppb Se 82 -6.1 -0.05183 ppb Sr 88 4489.1 0.00137 ppb Mo 95 104.7 -0.01526 ppb Mo 97 72 -0.01759 ppb Mo 98 141.4 -0.02064 ppb I> Rh 103 571637.9 ppb Ag 107 256 0.0041 ppb Ag 109 231.7 0.00177 ppb Cd 111 12.8 0.00219 ppb �- Cd 114 23.6 0.00099 ppb �- Sb 121 175.3 -0.00067 ppb Sb 123 118.3 -0.00249 ppb Ba 135 56.3 -0.00156 ppb Ba 137 97.7 -0.00077 ppb �> Ho 165 1030432.8 ppb TI 205 105.7 -0.00134 ppb Pb 206 106 -0.00182 ppb Pb 207 100 -0.00161 ppb �- Pb 208 414.3 -0.00231 ppb Kr 83 17.2 ppb elementOne ICP-Data 13 of 37 e 24274-Metals 51.13 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample Da Thursday, March 19, 2015 13:47:55 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 49031.6 ppb Be 9 28804.6 99.59203 ppb B 10 7597.5 105.4299 ppb �- B 11 34567.6 104.2048 ppb �- Na 23 5235651 1084.131 ppb Mg 24 3296392.5 1099.866 ppb Mg 25 435416.7 1011.944 ppb Al 27 427384.1 92.67894 ppb P 31 278292.5 991.4566 ppb K 39 9161207.7 1103.905 ppb Ca 44 305137.5 1090.6 ppb Sc 45 202263.5 ppb Cr 52 789261.6 93.52407 ppb Cr 53 147692.9 117.0805 ppb Fe 54 759359.6 1035.494 ppb Mn 55 1317141.6 93.69586 ppb Fe 57 300673 1110.44 ppb Co 59 1027739.1 93.27257 ppb Ni 60 218385.9 100.7902 ppb Cu 63 507239.9 93.36177 ppb Cu 65 250585.9 99.80523 ppb Zn 66 150990.7 101.4122 ppb Zn 67 30296.7 106.4301 ppb Zn 68 116373.3 101.5732 ppb As 75 192648 100.5465 ppb Se 77 22060.4 111.7217 ppb Se 82 21539.8 99.63606 ppb Sr 88 3151471.3 100.7432 ppb Mo 95 414307 93.52516 ppb Mo 97 258261.6 97.46947 ppb Mo 98 674065.8 91.89239 ppb I> Rh 103 554661.5 ppb Ag 107 1168522.8 102.2266 ppb Ag 109 1125137.3 102.6866 ppb Cd 111 279964.7 101.2261 ppb �- Cd 114 658612.9 92.11983 ppb �- Sb 121 979790.7 94.64535 ppb Sb 123 749820.7 95.39577 ppb Ba 135 285521.6 102.518 ppb Ba 137 491640.2 94.07601 ppb �> Ho 165 998754.1 ppb TI 205 3214552.8 103.9571 ppb Pb 206 980003 95.62951 ppb Pb 207 853596.3 95.67313 ppb �- Pb 208 4124502.7 101.3425 ppb Kr 83 -21314.1 ppb elementOne ICP-Data 14 of 37 e 24274-Metals 51.14 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample Da Thursday, March 19, 2015 14:26:06 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 55899.1 ppb Be 9 2.7 0.0054 ppb B 10 368.3 2.151 ppb �- B 11 1726.5 2.36258 ppb �- Na 23 17939 -9.55155 ppb Mg 24 19158.5 -0.9594 ppb Mg 25 2706.7 -0.94723 ppb Al 27 666 -0.00767 ppb P 31 1612.8 -1.33318 ppb K 39 263224.7 1.66528 ppb Ca 44 25113.3 16.6854 ppb Sc 45 187775.3 ppb Cr 52 12464.2 0.34216 ppb Cr 53 65955.7 31.06651 ppb Fe 54 27302.9 -2.37086 ppb Mn 55 1081.4 0.00927 ppb Fe 57 4379.7 -1.82561 ppb Co 59 31.7 -0.00127 ppb Ni 60 37.7 -0.00122 ppb Cu 63 672.4 -0.01882 ppb Cu 65 344.7 -0.01873 ppb Zn 66 1217.1 -0.01607 ppb Zn 67 4888 5.33917 ppb Zn 68 2116.9 0 ppb As 75 -1868.8 -0.26656 ppb Se 77 9104.2 30.90516 ppb Se 82 -2.7 -0.03683 ppb Sr 88 4142.3 -0.00225 ppb Mo 95 40.7 -0.02881 ppb Mo 97 30 -0.03246 ppb Mo 98 57.2 -0.03136 ppb I> Rh 103 541607.7 ppb Ag 107 151.3 -0.00407 ppb Ag 109 151.3 -0.00459 ppb Cd 111 11.9 0.00211 ppb �- Cd 114 22.9 0.00107 ppb �- Sb 121 73.7 -0.01003 ppb Sb 123 59.5 -0.0096 ppb Ba 135 53.7 -0.00209 ppb Ba 137 97.7 -0.00035 ppb �> Ho 165 1009351.1 ppb TI 205 84 -0.00196 ppb Pb 206 100.7 -0.00213 ppb Pb 207 87.3 -0.00279 ppb �- Pb 208 382.7 -0.00287 ppb Kr 83 11.6 ppb elementOne ICP-Data 15 of 37 e 24274-Metals 51.15 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample Da Thursday, March 19, 2015 14:29:34 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 52547.1 ppb Be 9 29628.9 95.58739 ppb B 10 7559.5 97.6976 ppb �- B 11 34236 96.11863 ppb �- Na 23 4513518.1 1021.256 ppb Mg 24 2830790.1 1032.379 ppb Mg 25 374998.4 952.5685 ppb Al 27 367551.6 87.14422 ppb P 31 234907.4 914.6092 ppb K 39 7849489.2 1032.339 ppb Ca 44 268957.3 1048.3 ppb Sc 45 180488.3 ppb Cr 52 699322.5 90.57043 ppb Cr 53 137026.9 119.3458 ppb Fe 54 670524 998.218 ppb Mn 55 1169407.8 90.95332 ppb Fe 57 269604.5 1088.365 ppb Co 59 939771A 93.27022 ppb Ni 60 202625.3 102.2633 ppb Cu 63 469710.5 94.54104 ppb Cu 65 234529.3 102.1448 ppb Zn 66 139545.3 102.4934 ppb Zn 67 27780.4 106.759 ppb Zn 68 108464.4 103.5428 ppb As 75 179358.4 102.3252 ppb Se 77 21680.9 122.1392 ppb Se 82 20053 101.4031 ppb Sr 88 2885766.6 100.8563 ppb Mo 95 380020.9 93.7995 ppb Mo 97 238915.5 98.58286 ppb Mo 98 620116.9 92.42558 ppb I> Rh 103 507309.1 ppb Ag 107 1074897.1 102.7973 ppb Ag 109 1038828.6 103.6685 ppb Cd 111 261025.7 103.1926 ppb �- Cd 114 618127.2 94.51863 ppb �- Sb 121 918847.9 90.62548 ppb Sb 123 693153.3 90.05087 ppb Ba 135 268010.1 98.26825 ppb Ba 137 465440.8 90.947 ppb �> Ho 165 978114.1 ppb TI 205 3142070.8 103.7613 ppb Pb 206 963428.3 95.99539 ppb Pb 207 846275.4 96.85464 ppb �- Pb 208 4026775.9 101.0286 ppb Kr 83 -19508.4 ppb elementOne ICP-Data 16 of 37 e 24274-Metals 51.16 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 24274-1.1 Sample Da Thursday, March 19, 2015 14:33:03 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 54765.2 ppb Be 9 6 0.01604 ppb B 10 1346.8 14.71088 ppb �- B 11 6119.1 14.59817 ppb �- Na 23 17625455 3979.109 ppb Mg 24 8130739.6 2943.894 ppb Mg 25 1069946.6 2698.395 ppb Al 27 845626.4 198.2583 ppb P 31 5481.3 13.99786 ppb K 39 22651707 3002.691 ppb Ca 44 3635874.3 15016.95 ppb Sc 45 193710 ppb Cr 52 21380.9 1.57915 ppb Cr 53 109933.4 85.83198 ppb Fe 54 45126.6 27.12221 ppb Mn 55 201282.5 15.41424 ppb Fe 57 14955.6 42.01821 ppb Co 59 3390 0.32842 ppb Ni 60 1017.7 0.48844 ppb Cu 63 43444.4 8.50568 ppb Cu 65 21819.5 9.24448 ppb Zn 66 52367.7 37.45552 ppb Zn 67 18029.3 63.10491 ppb Zn 68 41697 38.13172 ppb As 75 -3020.5 -0.95789 ppb Se 77 15872.9 80.54463 ppb Se 82 39.2 0.17261 ppb Sr 88 1779760.1 61.43399 ppb Mo 95 540.3 0.09385 ppb Mo 97 341 0.09546 ppb Mo 98 861.6 0.08799 ppb I> Rh 103 513252.2 ppb Ag 107 197 0.0011 ppb Ag 109 206 0.00166 ppb Cd 111 41.8 0.01412 ppb �- Cd 114 98.2 0.01271 ppb �- Sb 121 343.3 0.01605 ppb Sb 123 317.2 0.02317 ppb Ba 135 79354.9 28.40881 ppb Ba 137 138936.8 26.50409 ppb �> Ho 165 1001493.3 ppb TI 205 1196.1 0.03398 ppb Pb 206 9473.6 0.91074 ppb Pb 207 8105.6 0.89388 ppb �- Pb 208 37655 0.9109 ppb Kr 83 -12016.9 ppb elementOne ICP-Data 17 of 37 e 24274-Metals 51.17 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 24274-1.1 Sample Da Thursday, March 19, 2015 14:36:31 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 61512.2 ppb Be 9 17802.1 49.06273 ppb B 10 6620.8 72.42687 ppb �- B 11 30325.6 72.15503 ppb �- Na 23 22320740 4719.481 ppb Mg 24 10748363 3644.996 ppb Mg 25 1419611.7 3354.446 ppb Al 27 1204603.6 264.5105 ppb P 31 150087.3 537.5573 ppb K 39 29584069 3677.826 ppb Ca 44 4263364.9 16494.77 ppb Sc 45 220130.1 ppb Cr 52 451487.7 53.6157 ppb Cr 53 162973.1 135.5044 ppb Fe 54 459453.1 617.4625 ppb Mn 55 950534.4 68.38131 ppb Fe 57 181387 670.3396 ppb Co 59 570999.7 52.41907 ppb Ni 60 122205.4 57.04497 ppb Cu 63 332098.6 61.78257 ppb Cu 65 166728.8 67.12051 ppb Zn 66 132463.8 89.90157 ppb Zn 67 33504.3 120.8157 ppb Zn 68 102634.1 90.41312 ppb As 75 101886.1 54.12819 ppb Se 77 25051.8 132.564 ppb Se 82 11976.8 56.03058 ppb Sr 88 3781483.1 122.3024 ppb Mo 95 218937.3 49.97608 ppb Mo 97 138165 52.72017 ppb Mo 98 356451.5 49.13231 ppb I> Rh 103 548321.8 ppb Ag 107 616963.5 54.58756 ppb Ag 109 594860.3 54.90676 ppb Cd 111 145212.4 53.11117 ppb �- Cd 114 340359.9 48.15853 ppb �- Sb 121 493298.2 43.96471 ppb Sb 123 374567.2 43.96858 ppb Ba 135 230650.4 76.43052 ppb Ba 137 400405.3 70.71243 ppb �> Ho 165 1082245.6 ppb TI 205 1551390.4 46.29674 ppb Pb 206 540819.4 48.69884 ppb Pb 207 468109.7 48.4122 ppb �- Pb 208 2151342 48.77519 ppb Kr 83 -25584.6 ppb elementOne ICP-Data 18 of 37 e 24274-Metals 51.18 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 24274-1.1 Sample Da Thursday, March 19, 2015 14:39:59 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 59291 ppb Be 9 1.3 0.0011 ppb B 10 460.7 2.96877 ppb �- B 11 2040.6 2.89516 ppb �- Na 23 375583.2 67.96126 ppb Mg 24 170235.7 51.548 ppb Mg 25 24254 51.2387 ppb Al 27 21632.7 4.6996 ppb P 31 1798.5 -0.58939 ppb K 39 715001.1 59.83753 ppb Ca 44 100357.9 316.4465 ppb Sc 45 193131.1 ppb Cr 52 12129.8 0.31463 ppb Cr 53 54568.4 19.08218 ppb Fe 54 29561.4 1.29369 ppb Mn 55 5031.1 0.30051 ppb Fe 57 4818.9 0.03161 ppb Co 59 112 0.00628 ppb Ni 60 109 0.03297 ppb Cu 63 1281.4 0.09834 ppb Cu 65 623.7 0.09764 ppb Zn 66 8517.3 5.10148 ppb Zn 67 6474 12.06759 ppb Zn 68 7701.9 5.15106 ppb As 75 -1361.5 -0.00136 ppb Se 77 6186.8 12.29799 ppb Se 82 13.7 0.04157 ppb Sr 88 37426.6 1.09996 ppb Mo 95 212 0.01124 ppb Mo 97 135.3 0.00875 ppb Mo 98 332.9 0.00756 ppb I> Rh 103 536710.1 ppb Ag 107 83.7 -0.01007 ppb Ag 109 80.3 -0.01116 ppb Cd 111 15 0.00329 ppb �- Cd 114 33.2 0.00259 ppb �- Sb 121 262.3 0.00769 ppb Sb 123 187.9 0.00626 ppb Ba 135 1757.5 0.5969 ppb Ba 137 2982.5 0.5401 ppb �> Ho 165 1019719.2 ppb TI 205 201 0.00171 ppb Pb 206 402.3 0.02659 ppb Pb 207 349.7 0.02592 ppb �- Pb 208 1597.4 0.02625 ppb Kr 83 -222.1 ppb elementOne ICP-Data 19 of 37 e 24274-Metals 51.19 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 24274-1.1 Sample Da Thursday, March 19, 2015 14:43:27 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 55687.3 ppb Be 9 16008.1 48.73139 ppb B 10 396 2.50954 ppb �- B 11 1892.9 2.83441 ppb �- Na 23 1368362.3 293.1462 ppb Mg 24 834423.9 292.0353 ppb Mg 25 118359.2 288.7014 ppb Al 27 223116.2 51.62847 ppb P 31 53145.3 196.5196 ppb K 39 2269171.9 268.8311 ppb Ca 44 152811 545.5627 ppb Sc 45 186504.7 ppb Cr 52 383291.1 47.96843 ppb Cr 53 95548.2 68.16647 ppb Fe 54 193671.6 251.672 ppb Mn 55 634675.4 48.2175 ppb Fe 57 69426.5 259.9634 ppb Co 59 495924.3 48.1006 ppb Ni 60 105732.7 52.13974 ppb Cu 63 251600.5 49.42486 ppb Cu 65 125606.9 53.38466 ppb Zn 66 79825.4 56.91455 ppb Zn 67 18209.6 63.10603 ppb Zn 68 62718.4 57.6756 ppb As 75 93254.3 52.36047 ppb Se 77 13861.2 65.75831 ppb Se 82 10993 54.32941 ppb Sr 88 37523.3 1.14551 ppb Mo 95 198049.1 47.76428 ppb Mo 97 124705.2 50.2695 ppb Mo 98 322640.9 46.98303 ppb I> Rh 103 519058.5 ppb Ag 107 563316.5 52.64547 ppb Ag 109 543727.7 53.02403 ppb Cd 111 135001.1 52.1673 ppb �- Cd 114 320475.3 47.90396 ppb �- Sb 121 471839.1 45.74992 ppb Sb 123 358720.6 45.81109 ppb Ba 135 137413.6 49.52503 ppb Ba 137 240344.2 46.16558 ppb �> Ho 165 994798.5 ppb TI 205 1453595.2 47.19181 ppb Pb 206 503569 49.33132 ppb Pb 207 435300.6 48.97808 ppb �- Pb 208 1997125.3 49.26006 ppb Kr 83 -207.8 ppb elementOne ICP-Data 20 of 37 e 24274-Metals 51.20 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample Da Thursday, March 19, 2015 14:53:52 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 54301.1 ppb Be 9 0.7 -0.00047 ppb B 10 230.3 0.52064 ppb �- B 11 1079.7 0.7072 ppb �- Na 23 15574.6 -9.86622 ppb Mg 24 18522.2 -0.86334 ppb Mg 25 2642.7 -0.79038 ppb Al 27 750.7 0.01983 ppb P 31 1547.1 -1.29601 ppb K 39 257204.8 2.55846 ppb Ca 44 24262 18.21689 ppb Sc 45 180215.4 ppb Cr 52 13402.2 0.53892 ppb Cr 53 69975.5 39.50277 ppb Fe 54 27135.5 -0.68218 ppb Mn 55 1116.1 0.01602 ppb Fe 57 4240.7 -1.55245 ppb Co 59 31 -0.00121 ppb Ni 60 43 0.00236 ppb Cu 63 647.4 -0.01764 ppb Cu 65 359.7 -0.00511 ppb Zn 66 1185.1 0.00116 ppb Zn 67 5502 9.03026 ppb Zn 68 2121.2 0.09975 ppb As 75 -1655.8 -0.19294 ppb Se 77 8899.7 32.48484 ppb Se 82 -15.7 -0.10187 ppb Sr 88 4048.9 0.00118 ppb Mo 95 52 -0.02568 ppb Mo 97 38.3 -0.02845 ppb Mo 98 85.5 -0.02685 ppb I> Rh 103 516028.7 ppb Ag 107 138.3 -0.00459 ppb Ag 109 137.3 -0.00524 ppb Cd 111 10.6 0.00185 ppb �- Cd 114 20.4 0.0009 ppb �- Sb 121 119 -0.00547 ppb Sb 123 88.3 -0.00572 ppb Ba 135 56.3 -0.00056 ppb Ba 137 108.7 0.00233 ppb �> Ho 165 985819.2 ppb TI 205 100.3 -0.00136 ppb Pb 206 92.3 -0.0027 ppb Pb 207 78.7 -0.00354 ppb �- Pb 208 364 -0.00311 ppb Kr 83 18.5 ppb elementOne ICP-Data 21 of 37 e 24274-Metals 51.21 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample Da Thursday, March 19, 2015 14:57:20 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit �> Li 6 63231.1 ppb Be 9 35082.6 94.05911 ppb B 10 9841.7 105.8516 ppb �- B 11 44807.5 104.6821 ppb �- Na 23 5145218.3 1045.887 ppb Mg 24 3220180.7 1054.975 ppb Mg 25 428970.2 979.1031 ppb Al 27 423406.1 90.17886 ppb P 31 274529.3 960.3574 ppb K 39 8863098.4 1047.406 ppb Ca 44 303592.9 1064.165 ppb Sc 45 203948.6 ppb Cr 52 803455.7 93.53687 ppb Cr 53 146376.9 112.9805 ppb Fe 54 786936.6 1055.248 ppb Mn 55 1353979.2 94.6242 ppb Fe 57 313355.7 1137.288 ppb Co 59 1089201.8 97.11551 ppb Ni 60 234246.8 106.2151 ppb Cu 63 546352.5 98.80049 ppb Cu 65 271699.8 106.3233 ppb Zn 66 169466.7 111.9169 ppb Zn 67 32676.6 113.6566 ppb Zn 68 128920.8 110.7145 ppb As 75 205150.1 105.1512 ppb Se 77 25323.9 129.6676 ppb Se 82 24448.6 111.1032 ppb Sr 88 3319137.6 104.241 ppb Mo 95 423436.5 93.91442 ppb Mo 97 264520 98.07069 ppb Mo 98 681955.8 91.33913 ppb I> Rh 103 564628.9 ppb Ag 107 1228594.4 105.5818 ppb Ag 109 1186903.8 106.4147 ppb Cd 111 298454.3 106.0141 ppb �- Cd 114 705690.3 96.97626 ppb �- Sb 121 989044.2 86.6284 ppb Sb 123 753634.9 86.94839 ppb Ba 135 294478.1 95.86736 ppb Ba 137 510393.6 88.55457 ppb �> Ho 165 1101505.2 ppb TI 205 3604649.3 105.7054 ppb Pb 206 1091506.1 96.59238 ppb Pb 207 960286.1 97.60563 ppb �- Pb 208 4593211.6 102.3421 ppb Kr 83 -22460.7 ppb elementOne ICP-Data 22 of 37 e 24274-Metals 51.22 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Blank Sample Da Friday, March 20, 2015 09:19:11 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 51518.2 ppb �- Sc 45 205083.8 ppb V-1 51 15722.6 ppb V 51 17747.7 ppb 1> Rh 103 598204.8 ppb Ho 165 1031344.9 ppb Kr 83 52.1 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 1 Sample DaFriday, March 20, 2015 09:20:23 Sample Description: Concentration Results Analyte Mass Meas. Intent Conc. Mear Report Unit Li 6 49395.7 ppb �- Sc 45 213211.3 ppb V-1 51 24766.8 1 ppb V 51 36887.1 1 ppb 1> Rh 103 585278.5 ppb Ho 165 998938.7 ppb Kr 83 -154.3 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 2 Sample Da' Friday, March 20, 2015 09:21:35 Sample Description: Concentration Results Analyte Mass Meas. Inten: Conc. Mear Report Unit Li 6 48516.6 ppb �- Sc 45 204645.7 ppb V-1 51 112843.1 10.00973 ppb V 51 211013.2 10.00515 ppb 1> Rh 103 553465.2 ppb Ho 165 958498.8 ppb Kr 83 -1913.8 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 3 Sample Da' Friday, March 20, 2015 09:22:46 Sample Description: Concentration Results Analyte Mass Meas. Intent Conc. Mear Report Unit Li 6 46366.8 ppb �- Sc 45 202100.2 ppb V-1 51 290905.9 29.95663 ppb V 51 563135.1 29.94985 ppb �> Rh 103 527988 ppb Ho 165 916347.7 ppb Kr 83 -5529.7 mg/L elementOne ICP-Data 23 of 37 e 24274-Metals 51.23 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample Da Friday, March 20, 2015 09:23:58 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 48562.1 ppb �- Sc 45 193303.8 ppb V-1 51 15218.7 0.06315 ppb V 51 16865.4 0.01985 ppb 1> Rh 103 556441.2 ppb Ho 165 965817.2 ppb Kr 83 41.2 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample DaFriday, March 20, 2015 09:25:10 Sample Description: Concentration Results Analyte Mass Meas. Intent Conc. Mear Report Unit Li 6 47588.3 ppb �- Sc 45 189569.3 ppb V-1 51 18044.2 0.37544 ppb V 51 22246.4 0.31303 ppb 1> Rh 103 550025.9 ppb Ho 165 946963.6 ppb Kr 83 46.1 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 3 Sample Da' Friday, March 20, 2015 09:26:21 Sample Description: Concentration Results Analyte Mass Meas. Inten: Conc. Mear Report Unit Li 6 48294.6 ppb �- Sc 45 201657.1 ppb V-1 51 24759.3 1.02624 ppb V 51 36123.4 1.00693 ppb 1> Rh 103 560401 ppb Ho 165 970313A ppb Kr 83 42.7 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample Da' Friday, March 20, 2015 09:27:34 Sample Description: Concentration Results Analyte Mass Meas. Intent Conc. Mear Report Unit Li 6 48082.5 ppb �- Sc 45 208093.9 ppb V-1 51 110151.5 9.83939 ppb V 51 206311.6 9.88832 ppb �> Rh 103 555121.1 ppb Ho 165 947895.7 ppb Kr 83 -1912.4 mg/L elementOne ICP-Data 24 of 37 e 24274-Metals 51.24 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 5 Sample Da Friday, March 20, 2015 09:28:46 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 51252.2 ppb �- Sc 45 220310.8 ppb V-1 51 270139.9 25.08818 ppb V 51 525798.2 25.32323 ppb 1> Rh 103 579960.6 ppb Ho 165 992631.7 ppb Kr 83 40.9 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 9 Sample DaFriday, March 20, 2015 09:29:59 Sample Description: Concentration Results Analyte Mass Meas. Intent Conc. Mear Report Unit Li 6 57308 ppb �- Sc 45 233378 ppb V-1 51 11890.8 -0.4579 ppb V 51 14743 -0.20312 ppb 1> Rh 103 652451.9 ppb Ho 165 1105409.3 ppb Kr 83 32.7 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 10 Sample Da' Friday, March 20, 2015 09:31:11 Sample Description: Concentration Results Analyte Mass Meas. Inten: Conc. Mear Report Unit Li 6 57978.9 ppb �- Sc 45 242230.6 ppb V-1 51 591439.8 49.95893 ppb V 51 1173989.8 50.82185 ppb 1> Rh 103 656359.1 ppb Ho 165 1107765.2 ppb Kr 83 40.7 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC STD2 Sample Da' Friday, March 20, 2015 09:32:24 Sample Description: Concentration Results Analyte Mass Meas. Intent Conc. Mear Report Unit Li 6 57293.5 ppb �- Sc 45 224391.3 ppb V-1 51 11528.3 -0.47585 ppb V 51 13695.3 -0.24063 ppb �> Rh 103 643326.2 ppb Ho 165 1089625.8 ppb Kr 83 40.8 mg/L elementOne ICP-Data 25 of 37 e 24274-Metals 51.25 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 24274-1.1 Sample Da Friday, March 20, 2015 09:36:00 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 54028.9 ppb �- Sc 45 228816.4 ppb V-1 51 14333.3 -0.14669 ppb V 51 18036.2 0.00593 ppb 1> Rh 103 604969.2 ppb Ho 165 1059490.9 ppb Kr 83 -14528.5 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: 24274-1.1 Sample DaFriday, March 20, 2015 09:37:12 Sample Description: Concentration Results Analyte Mass Meas. Intent Conc. Mear Report Unit Li 6 51093.6 ppb �- Sc 45 227747.8 ppb V-1 51 546959.5 50.04511 ppb V 51 1082823.5 50.7722 ppb 1> Rh 103 605604.8 ppb Ho 165 1058441.3 ppb Kr 83 -13115.1 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample Da' Friday, March 20, 2015 09:38:26 Sample Description: Concentration Results Analyte Mass Meas. Inten: Conc. Mear Report Unit Li 6 49906.9 ppb �- Sc 45 204997.9 ppb V-1 51 13057 -0.26485 ppb V 51 15027.3 -0.13785 ppb 1> Rh 103 603813.3 ppb Ho 165 1038228.1 ppb Kr 83 39.9 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample Da' Friday, March 20, 2015 09:39:38 Sample Description: Concentration Results Analyte Mass Meas. Intent Conc. Mear Report Unit Li 6 46381.4 ppb �- Sc 45 209522 ppb V-1 51 111696 9.70007 ppb V 51 210583.4 9.82634 ppb �> Rh 103 569268.3 ppb Ho 165 976102.7 ppb Kr 83 -1952.5 mg/L elementOne ICP-Data 26 of 37 e 24274-Metals 51.26 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Blank Sample Da Friday, March 20, 2015 09:44:03 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit 1> Li 6 52152.4 ppb B 10 216.3 ppb �- B 11 960.7 ppb �- Al 27 797.4 ppb Sc 45 180971.4 ppb Zn 66 908.4 ppb Zn 67 1279.8 ppb Zn 68 1760.8 ppb 1> Rh 103 531462.9 ppb Ho 165 947211.6 ppb Kr 83 37.6 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 1 Sample DaFriday, March 20, 2015 09:45:24 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit I> Li 6 49925.1 ppb B 10 551.4 5 ppb �- B 11 2531 5 ppb �- Al 27 8200.4 1 ppb Sc 45 180521.7 ppb Zn 66 5858.9 1 ppb Zn 67 2866.1 1 ppb Zn 68 5462.6 1 ppb I> Rh 103 524385.4 ppb Ho 165 928647.1 ppb Kr 83 -145.2 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 2 Sample Da' Friday, March 20, 2015 09:46:45 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit 1> Li 6 50158.1 ppb B 10 6694.1 99.98322 ppb �- B 11 31243.7 99.98303 ppb �- Al 27 396553.9 99.99104 ppb Sc 45 183855 ppb Zn 66 145409.3 99.97525 ppb Zn 67 27208.4 99.94752 ppb Zn 68 111935.4 99.97581 ppb �> Rh 103 530687.1 ppb Ho 165 948682 ppb Kr 83 -20286.1 ppb elementOne ICP-Data 27 of 37 e 24274-Metals 51.27 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 3 Sample Da Friday, March 20, 2015 09:48:06 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit 1> Li 6 56634.5 ppb B 10 40617 501.7911 ppb �- B 11 188725.2 501.6911 ppb �- Al 27 2300658.2 501.4058 ppb Sc 45 209364.3 ppb Zn 66 788685.3 500.2304 ppb Zn 67 138251.2 499.5839 ppb Zn 68 603910.3 500.2667 ppb 1> Rh 103 571628.5 ppb Ho 165 1047909.5 ppb Kr 83 -110006.9 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DaFriday, March 20, 2015 09:49:27 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit I> Li 6 64941.7 ppb B 10 787 ppb �- B 11 3600 ppb �- Al 27 1572.8 ppb Sc 45 232339.9 ppb Zn 66 1678.2 ppb Zn 67 3259.3 ppb Zn 68 2575.7 ppb I> Rh 103 645065.9 ppb Ho 165 1132700.9 ppb Kr 83 25.1 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample Da' Friday, March 20, 2015 09:50:48 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit 1> Li 6 72490.9 ppb B 10 1266.8 3.77428 ppb �- B 11 5955.6 4.05337 ppb �- Al 27 7957.5 1.13652 ppb Sc 45 260046.1 ppb Zn 66 4471.4 1.41215 ppb Zn 67 4088.6 1.85936 ppb Zn 68 4852 1.45287 ppb �> Rh 103 688463.7 ppb Ho 165 1199562.1 ppb Kr 83 -233.4 ppb elementOne ICP-Data 28 of 37 e 24274-Metals 51.28 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 3 Sample Da Friday, March 20, 2015 09:52:09 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit 1> Li 6 60315.7 ppb B 10 24540.8 278.07 ppb �- B 11 111610.4 271.915 ppb �- Al 27 1211559.9 253.6305 ppb Sc 45 221753.3 ppb Zn 66 437573.2 266.1943 ppb Zn 67 78264.8 264.1722 ppb Zn 68 341156.4 270.5374 ppb 1> Rh 103 594786 ppb Ho 165 1060649.3 ppb Kr 83 -59645.6 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DaFriday, March 20, 2015 09:53:31 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit I> Li 6 60892.3 ppb B 10 9449.9 100.8023 ppb �- B 11 43002.5 98.62222 ppb �- Al 27 488587.3 99.23161 ppb Sc 45 216144.7 ppb Zn 66 180679 106.2506 ppb Zn 67 34200.6 106.0817 ppb Zn 68 138475.7 105.5636 ppb I> Rh 103 611872.5 ppb Ho 165 1084015.6 ppb Kr 83 -24022.2 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 5 Sample Da' Friday, March 20, 2015 09:54:53 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit 1> Li 6 56735 ppb B 10 5153.8 55.41966 ppb �- B 11 23795.5 55.14874 ppb �- Al 27 239074 50.62308 ppb Sc 45 206543.6 ppb Zn 66 85934.7 52.36946 ppb Zn 67 18310.1 54.77221 ppb Zn 68 67334.6 52.76485 ppb �> Rh 103 585002.7 ppb Ho 165 1027742.5 ppb Kr 83 34.7 ppb elementOne ICP-Data 29 of 37 e 24274-Metals 51.29 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 9 Sample Da Friday, March 20, 2015 09:56:14 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit 1> Li 6 56540.4 ppb B 10 529 -1.94495 ppb �- B 11 2484 -1.7365 ppb �- Al 27 8660.1 1.62731 ppb Sc 45 199023.9 ppb Zn 66 5531.7 2.64696 ppb Zn 67 8394.6 20.73937 ppb Zn 68 5597.7 2.85991 ppb 1> Rh 103 558886 ppb Ho 165 990514.4 ppb Kr 83 43.7 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 10 Sample DaFriday, March 20, 2015 09:57:35 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit I> Li 6 55813.1 ppb B 10 4705.2 50.91042 ppb �- B 11 22098.5 51.63372 ppb �- Al 27 222245 49.75019 ppb Sc 45 199785 ppb Zn 66 81028.1 52.20581 ppb Zn 67 22481.8 74.22032 ppb Zn 68 63106.8 52.25739 ppb I> Rh 103 553320.5 ppb Ho 165 992366.5 ppb Kr 83 -10249.9 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample Da' Friday, March 20, 2015 09:58:57 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit 1> Li 6 55352.4 ppb B 10 815.7 1.86382 ppb �- B 11 3776.8 1.95069 ppb �- Al 27 6384.9 1.08386 ppb Sc 45 202784.5 ppb Zn 66 3619.1 1.34701 ppb Zn 67 5458 9.33699 ppb Zn 68 4103.6 1.50418 ppb �> Rh 103 573276.8 ppb Ho 165 995599.4 ppb Kr 83 -168.3 ppb elementOne ICP-Data 30 of 37 e 24274-Metals 51.30 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 24274-1.1 Sample Da Friday, March 20, 2015 10:03:01 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit 1> Li 6 51465.2 ppb B 10 1171.1 7.49207 ppb �- B 11 5325.9 7.29326 ppb �- Al 27 843496.2 209.464 ppb Sc 45 188177.2 ppb Zn 66 49457.9 34.89513 ppb Zn 67 16619.2 58.66064 ppb Zn 68 39140.5 35.19762 ppb 1> Rh 103 501154.7 ppb Ho 165 937807.8 ppb Kr 83 -11513.4 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: 24274-1.1 Sample DaFriday, March 20, 2015 10:04:22 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit I> Li 6 50389.7 ppb B 10 4870.3 59.54346 ppb �- B 11 22277.3 58.59094 ppb �- Al 27 1045811.7 255.7956 ppb Sc 45 189267.3 ppb Zn 66 112675.4 79.41368 ppb Zn 67 28035.5 104.3985 ppb Zn 68 87460.3 79.69848 ppb I> Rh 103 508896.1 ppb Ho 165 939510.9 ppb Kr 83 -22828.5 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample Da' Friday, March 20, 2015 10:08:27 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit 1> Li 6 55586.9 ppb B 10 364.3 -3.90926 ppb �- B 11 1673.5 -3.83501 ppb �- Al 27 2010.6 0.15304 ppb Sc 45 197951.4 ppb Zn 66 1381.4 -0.03761 ppb Zn 67 5256.5 9.30915 ppb Zn 68 2259.3 0.04392 ppb �> Rh 103 553634.5 ppb Ho 165 993471.7 ppb Kr 83 44.9 ppb elementOne ICP-Data 31 of 37 e 24274-Metals 51.31 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample Da Friday, March 20, 2015 10:09:48 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit 1> Li 6 62942.2 ppb B 10 9681.2 99.82199 ppb �- B 11 44791.7 99.34744 ppb �- Al 27 506281.6 101.499 ppb Sc 45 227202.6 ppb Zn 66 186858.2 108.4985 ppb Zn 67 36609.1 112.731 ppb Zn 68 144855.5 109.131 ppb 1> Rh 103 619554 ppb Ho 165 1105483 ppb Kr 83 -24399.5 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample DaFriday, March 20, 2015 10:21:19 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit I> Li 6 55423.4 ppb B 10 275 -5.04073 ppb �- B 11 1236.1 -5.01941 ppb �- Al 27 5797.2 1.01655 ppb Sc 45 197774.3 ppb Zn 66 3050.2 1.07894 ppb Zn 67 5029.1 8.63693 ppb Zn 68 3645.1 1.26662 ppb I> Rh 103 547256.4 ppb Ho 165 975128.7 ppb Kr 83 -168.6 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Blank Sample Da' Friday, March 20, 2015 10:24:58 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 51988.4 ppb �- Sc 45 186499.3 ppb Se 77 4505.1 ppb Se 82 -5.4 ppb �> Rh 103 532283.2 ppb �- Sb 121 114.3 ppb Sb 123 83.8 ppb Ba 135 104.3 ppb Ba 137 200 ppb �> Ho 165 942224 ppb Kr 83 50.3 ppb elementOne ICP-Data 32 of 37 e 24274-Metals 51.32 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 1 Sample Da Friday, March 20, 2015 10:26:22 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 50724.9 ppb �- Sc 45 187212.2 ppb Se 77 4595.5 1.28273 ppb Se 82 210.3 1.01602 ppb �> Rh 103 520186.7 ppb �- Sb 121 9436.6 0.95966 ppb Sb 123 7206.5 0.96502 ppb Ba 135 2885.1 1.06518 ppb Ba 137 4945 0.97084 ppb I> Ho 165 926179.8 ppb Kr 83 -141.6 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 2 Sample DaFriday, March 20, 2015 10:27:46 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 50573.1 ppb �- Sc 45 188693 ppb Se 77 19733.4 99.19176 ppb Se 82 21180 98.87665 ppb I> Rh 103 524371.3 ppb �- Sb 121 954129 96.99874 ppb Sb 123 727898.5 97.44578 ppb Ba 135 273944.1 103.5954 ppb Ba 137 472216.4 95.3806 ppb 1> Ho 165 937138 ppb Kr 83 -19892.5 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 3 Sample Da' Friday, March 20, 2015 10:29:10 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 51923.7 ppb �- Sc 45 194522.9 ppb Se 77 82077.2 500.1611 ppb Se 82 107890.4 500.2246 ppb �> Rh 103 527467.8 ppb �- Sb 121 5155782.2 500.6003 ppb Sb 123 3914643.3 500.5109 ppb Ba 135 1382236.9 499.2808 ppb Ba 137 2596349.5 500.9239 ppb �> Ho 165 981356.3 ppb Kr 83 -101271.3 ppb elementOne ICP-Data 33 of 37 e 24274-Metals 51.33 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample Da Friday, March 20, 2015 10:30:34 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 55033.8 ppb �- Sc 45 197453.4 ppb Se 77 4261 -2.93386 ppb Se 82 21.9 0.12054 ppb �> Rh 103 560837.9 ppb �- Sb 121 477.3 0.03495 ppb Sb 123 356.9 0.03463 ppb Ba 135 240.3 0.04775 ppb Ba 137 391.7 0.03545 ppb I> Ho 165 990937.5 ppb Kr 83 42.6 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample DaFriday, March 20, 2015 10:31:59 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 57612.1 ppb �- Sc 45 215465.3 ppb Se 77 4938.7 -0.22867 ppb Se 82 255.3 1.08716 ppb I> Rh 103 588202.5 ppb �- Sb 121 10579.2 0.96584 ppb Sb 123 8007.6 0.96291 ppb Ba 135 3166.6 1.04869 ppb Ba 137 5434 0.95748 ppb 1> Ho 165 1032140.1 ppb Kr 83 -184 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 3 Sample Da' Friday, March 20, 2015 10:33:23 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 58843.8 ppb �- Sc 45 217869.9 ppb Se 77 51186.8 274.3346 ppb Se 82 63043.6 268.6493 ppb �> Rh 103 573883 ppb �- Sb 121 2784776.8 254.4831 ppb Sb 123 1937070.6 233.0831 ppb Ba 135 751889.3 255.6345 ppb Ba 137 1307105.5 237.321 ppb �> Ho 165 1042873.7 ppb Kr 83 -57890.1 ppb elementOne ICP-Data 34 of 37 e 24274-Metals 51.34 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample Da Friday, March 20, 2015 10:34:48 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 62633 ppb �- Sc 45 224757.6 ppb Se 77 24914.1 108.5653 ppb Se 82 26739.3 106.1036 ppb �> Rh 103 616582.2 ppb �- Sb 121 1082546.2 92.79713 ppb Sb 123 828341.7 93.46687 ppb Ba 135 319268.5 101.8239 ppb Ba 137 554062.2 94.38774 ppb I> Ho 165 1111544.1 ppb Kr 83 -24173.6 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 5 Sample DaFriday, March 20, 2015 10:36:12 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 58962.6 ppb �- Sc 45 213246 ppb Se 77 14061.5 52.13069 ppb Se 82 12790.6 52.96702 ppb I> Rh 103 590794.8 ppb �- Sb 121 525000.4 47.59406 ppb Sb 123 397923.8 47.4897 ppb Ba 135 151390.2 51.0363 ppb Ba 137 263880.3 47.51372 ppb 1> Ho 165 1051019.8 ppb Kr 83 37.5 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 9 Sample Da' Friday, March 20, 2015 10:37:37 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 58793.9 ppb �- Sc 45 207807 ppb Se 77 11196.9 38.15209 ppb Se 82 20.9 0.1154 ppb �> Rh 103 568692.2 ppb �- Sb 121 670.4 0.05076 ppb Sb 123 527.3 0.05344 ppb Ba 135 91.3 -0.00767 ppb Ba 137 164 -0.00986 ppb �> Ho 165 1026199.2 ppb Kr 83 40.5 ppb elementOne ICP-Data 35 of 37 e 24274-Metals 51.35 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 10 Sample Da Friday, March 20, 2015 10:39:01 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 57049.2 ppb �- Sc 45 205349.9 ppb Se 77 19798.2 91.42902 ppb Se 82 11443.5 50.03246 ppb �> Rh 103 559819.2 ppb �- Sb 121 496338.4 46.77589 ppb Sb 123 379435 47.08953 ppb Ba 135 143470.3 50.28117 ppb Ba 137 249471 46.69609 ppb I> Ho 165 1010622.1 ppb Kr 83 -10381.2 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample DaFriday, March 20, 2015 10:40:26 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 55778.5 ppb �- Sc 45 204962.9 ppb Se 77 4972 0.91935 ppb Se 82 227.2 0.99957 ppb I> Rh 103 570109.1 ppb �- Sb 121 10341.5 0.97781 ppb Sb 123 7952.7 0.99068 ppb Ba 135 3094.2 1.06175 ppb Ba 137 5279.2 0.96298 ppb 1> Ho 165 996110.3 ppb Kr 83 -167.8 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: 24274-1.1 Sample Da' Friday, March 20, 2015 10:41:52 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 54853.3 ppb �- Sc 45 202373.8 ppb Se 77 10766.7 39.68179 ppb Se 82 30.2 0.16398 ppb �> Rh 103 534479.2 ppb �- Sb 121 541.3 0.04048 ppb Sb 123 434.9 0.04384 ppb Ba 135 81858 29.27501 ppb Ba 137 141160.5 26.95939 ppb �> Ho 165 989968.4 ppb Kr 83 -12366.2 ppb elementOne ICP-Data 36 of 37 e 24274-Metals 51.36 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 24274-1.1 Sample Da Friday, March 20, 2015 10:43:16 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 52831.4 ppb �- Sc 45 200369.7 ppb Se 77 19433.4 97.06779 ppb Se 82 11056.2 51.55482 ppb �> Rh 103 525218.1 ppb �- Sb 121 482469.7 47.21444 ppb Sb 123 364955 47.02591 ppb Ba 135 217034.9 79.01974 ppb Ba 137 375291.7 72.99912 ppb I> Ho 165 973172.2 ppb Kr 83 -23804.4 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DaFriday, March 20, 2015 10:44:41 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 53870.6 ppb �- Sc 45 197571.3 ppb Se 77 4855.6 1.2553 ppb Se 82 -3.1 0.01111 ppb I> Rh 103 550042.7 ppb �- Sb 121 240 0.01196 ppb Sb 123 186.8 0.01286 ppb Ba 135 134.3 0.0096 ppb Ba 137 210.7 0.00076 ppb 1> Ho 165 976162.4 ppb Kr 83 49.6 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample Da' Friday, March 20, 2015 10:46:06 Sample Description: Concentration Results Analyte Mass Meas. Intem Conc. Mear Report Unit Li 6 53480.1 ppb �- Sc 45 200658.6 ppb Se 77 21464.6 104.8007 ppb Se 82 22815.3 102.1509 ppb �> Rh 103 546589.4 ppb �- Sb 121 989360.4 95.1423 ppb Sb 123 758683.2 96.09378 ppb Ba 135 288134.8 103.0515 ppb Ba 137 495420.4 94.62682 ppb �> Ho 165 991455.7 ppb Kr 83 -21327.9 ppb elementOne ICP-Data 37 of 37 e 24274-Metals 51.37 PerkinElmer FIMS-100 CVAA Mercury Analyzer Sample -ID Date Time Mean_Sig Mean_Rd Mean_Rt Units Alq. Vol. Sig 1 Reading-1 Result-1 Sig 2 Reading-2 Result-2 Calib Blank 3/19/2015 10:14:51 AM 0.00018269 Ng 0.00016879 0.00019658 STD 1= .004 ug 3/19/2015 10:16:31 AM 0.00137162 Ng 0.00139061 0.00135264 STD 2= .04 ug 3/19/2015 10:18:13 AM 0.01459709 Ng 0.01466346 0.01453071 STD 3= .08 ug 3/19/2015 10:20:06 AM 0.02897143 Ng 0.02890999 0.02903287 STD 4= .16 ug 3/19/2015 10:22:01 AM 0.06032927 Ng 0.0606153 0.06004323 STD 5= .20 ug 3/19/2015 10:23:56 AM 0.07091303 Ng 0.07094749 0.07087857 Reagent Blank 3/19/2015 10:25:49 AM -0.0001505 -0.0004141 -0.0004141 Ng -0.0001584 -0.0004356 -0.0004356 -0.0001427 -0.0003925 -0.0003925 0.004ug = DL 3/19/2015 10:27:30 AM 0.00136241 0.00374738 0.00374738 Ng 0.00137173 0.00377299 0.00377299 0.0013531 0.00372176 0.00372176 0.080ug = QC STD 2 3/19/2015 10:29:13 AM 0.03086209 0.08488752 0.08488752 Ng 0.03107762 0.08548034 0.08548034 0.03064656 0.08429469 0.08429469 0.080ug = QC STD 3 3/19/2015 10:31:10 AM 0.02914807 0.08017302 0.08017302 Ng 0.02927349 0.08051799 0.08051799 0.02902265 0.07982805 0.07982805 Reagent Blank 3/19/2015 10:33:04 AM -0.0001063 -0.0002923 -0.0002923 Ng -0.0001201 -0.0003303 -0.0003303 -9.24E-05 -0.0002542 -0.0002542 0.004ug = DL 3/19/2015 10:52:35 AM 0.00135315 0.0037219 0.0037219 Ng 0.00138323 0.00380464 0.00380464 0.00132307 0.00363916 0.00363916 0.080ug = QC STD 2 3/19/2015 10:54:18 AM 0.0308233 0.08478082 0.08478082 Ng 0.03093375 0.08508463 0.08508463 0.03071285 0.08447701 0.08447701 Reagent Blank 3/19/2015 10:56:12 AM -0.0001189 -0.000327 -0.000327 Ng -0.0001438 -0.0003955 -0.0003955 -9.40E-05 -0.0002585 -0.0002585 24274- 1.1 3/19/2015 11:08:24 AM -8.22E-05 0.00018798 4.70E-06 Ng 40 1 -9.95E-05 0.00014049 3.51 E-06 -6.49E-05 0.00023548 5.89E-06 24274- 1.1 DUP 3/19/2015 11:10:08 AM 0.00017336 0.0008909 2.23E-05 Ng 40 1 0.00017632 0.00089904 2.25E-05 0.0001704 0.00088276 2.21 E-05 24274- 1.1 SPK 3/19/2015 11:11:52 AM 0.02545712 0.07043498 0.00176087 Ng 40 1 0.02555556 0.07070572 0.00176764 0.02535869 0.07016423 0.00175411 0.004ug = DL 3/19/2015 11:13:46 AM 0.00139102 0.00382606 0.00382606 Ng 0.00143361 0.00394319 0.00394319 0.00134844 0.00370893 0.00370893 0.080ug = QC STD 3 3/19/2015 11:15:30 AM 0.02805468 0.07716562 0.07716562 Ng 0.02806559 0.07719562 0.07719562 0.02804377 0.07713561 0.07713561 Reagent Blank 3/19/2015 11:17:24 AM -8.23E-05 -0.0002264 -0.0002264 Ng -7.04E-05 -0.0001938 -0.0001938 -9.42E-05 -0.000259 -0.000259 elementOne Hg-Data 1 of 1 e 24274-Hg 52.1