HomeMy WebLinkAboutAllen Steam Facility - Duke Energy (20)IkO
Duke
Energy.
February 17, 2011
Mr. Bradley Bennett
Division of Water Quality
Stormwater Permitting Unit
North Carolina Department of Environment
and Natural Resources
1617 Mail Service Center
Raleigh, NC 27699-1617
Subject: NPDES Stormwater Permit Application
Allen Steam Station
Dear Mr. Bennett:
CORPORATE EHS SERVICES
Duke Energy
526 South Church St.
Charlotte, NC 28202
Mailing Address:
EC13K / PO Box 1006
Charlotte, NC 28201-1006
��r= lLgOWR O
E
2 l 2011
DENR - WATER
Branch
Duke Energy requests a stormwater discharge permit for the Allen Steam Station located in
Gaston County, North Carolina. Please find attached three sets of the following documents
related to this permit request:
a. EPA Form 1;
b. EPA Form 2F;
C. EPA Form 2F Supplemental Information;
d. Available stormwater analytical data;
e. DWQ ROS Request Form;
f. ROS Form Supplemental Information;
g. Site Location Map
h. Site Stormwater Plan Drawing
Numerous stormwater outfalls are located at the Allen Steam Station. The accompanying
stormwater analytical data was obtained from samples collected at outfalls SWO08 and SWO15
during June 2009 and April 2009, respectively.
Please contact me at Mark.McGary@duke-energy.com or at 704-634-7098 if you have any
questions or need any additional information.
Sincerely,
Mark McGary, P.E.
Environmental, Health & Safety
www.duke-energy.com
Page 4 of 60
Analytical Laboratory
Please print or type in the unshaded areas
EPA ID Number (copy from item 1 of Form 1)
Form Approved. OM6 No. 2040-0086
Approval expires 5-31-92
Form
2F'
NPDES
United States Environmental Protection Agency
Washington, DC 20460
A Application for Permit to Discharge Storm Water rrrE� PP 9
Discharges Associated with Industrial Activit
Paperwork Reduction Act Notice
Public reporting burden for this application is estimated to average 28.6 hours per application, including time for reviewing instructions, searching existing data
sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding the burden estimate,
any other aspect of this collection of information or suggestions for improving this form, including suggestions which may increase or reduce this burden to: Chief,
Information Policy Branch, PM -223, U.S. Environmental Protection Agency, 401 M St, SW, Washington, DC 20460, or Director, Office of Information and Regulatory
Affairs, Office of Man ement and Budget WashingW, DC 20503.
I. Outfall Location
For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water.
A. Outfall Number D. Receiving Water
list B. Latitude C. Longitude name
SW 015
Il. Improvements
A. Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading or
operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described
in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance
schedule letters, stipulations, court orders, and grant or loan conditions.
4. Final
1. Identification of Conditions, 2. Affected Outfalls Com fiance Date
Agreements, Etc. number source of discharge 3. Brief Description of Project a. req. b. proj.
B. You may attach additional sheets describing any additional water pollution (or other environmental projects which may affect your discharges)
you now have under way or which you plan. Indicate whether each program is now under way or planned, and indicate your actual or planned
schedules for construction.
III. Site Drainage Ma
Attach a site map showing topography (or indicating the outline of drainage areas served by the outfall(s) covered in the application if a
topographic map Is unavailable) depicting the facility including: each of its intake and discharge structures; the drainage area of each storm
water outfall; paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for
outdoor storage or disposal of significant materials, each existing structure control measure to reduce pollutants in storm water runoff,
materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied; each of its hazardous
waste treatment, storage or disposal units (including each are not required to have a RCRA permit which is used for accumulating hazardous
waste under 40 CFR 262.34); each well where Fluids from the facility are injected underground; springs, and other surface water bodies which
receive storm water discharges from the facility.
EPA Form 3510-2F (Rev. 1-92) Page 1 of 3 Continued on Page 2
Page 5 of 60
Analytical Laboratory
Continued from the Fmnt
JV. Narrative0escri tion of,Pollutant,Sources
A For each'outfall, provide,an estimate of the area,(mclude units) of Impervious surfaces (including � paved areas and,bwldmg roofs) drained
to4he outfall, and an estimate of the,total surface area drained by the outfall _
Outfall
Area of Impervious Surface
Total Area Drained
Outfall
Area of Impervious Surface
Total Area Drained
Number(provide
units
rovide units
Number
rowde units(provide
units
SWO15
B Providea narrative description of significant materials that are currently or in the past three years have been,treated, stored or disposed
in a manner to allow exposure to storm water, method of treatment, storage, or disposal, past and present matenals management
practices employed to minimize, contact by these matenals with storm water runoff, materials loading and access areas, and the location,
manner, and freouency in which pesticides, herbicides, sod, conditioners, and fertilizers are applied
C For each outfall, provide the location and a description of existing structural and `nonstructural control measures to reduce pollutants in
storm water runoff, and a description ofthe treatment the storm water receives, including the<schedule and type of maintenance for
control and treatment measures and the ultimate disposal of any solid or fluid wastes other than'by discharge
Outfall
List Codes from
;Number
Treatment
Table 2F-1
SW015
V. Non Stormwater Discharges
A I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of
nonstormwater discharges, and that all nonstormwater discharges from these outfall(s) are`idenbfied'in either an accompanymglFonn 2C
or Form 2E a licabon'for the outfall
Name of Official Title (type or print)
Signature
Date Signed
B provide a description tion of the method,used, the date of any testing, and the onsite drainage points that were directly observed during a test
VI. Significant Leaks or S ills
Provide existing informabon,regarding the history of significant leaks or spills of toxic, or hazardous, pollutants, at the facility in the last three
ears, mcludm 'the approximate date and location ofthe s dl or leak, and the type and amount,of matenal released
EPA Form 3510-2F (Rev 1-92) Page 2 of 3 Continued on Page 3
E
i
Conbnued from Page 2
EPA ID Number (copy from Item hof'Form,1)
Page 6 of 60
Analytical Laboratory
VII.Discharge-Information
A;B,C, & D See instruction -before proceeding Complete one set of tables,for each outfall Annotate the outfall number En the space provided
Tables Vii -A, VII -B, and VII -Clare mcluded,on separate sheetsinumbered VII -1 and VII -2
E Potential discharges not covered by analysis - Esfariy toxic,pollutant,lEsted in table•217-2,2F-3, or 2F4, a,,substance or a component,of a
substance which you currently use or manufacture as an intermediate or final,product or byproduct?
❑ Yes (list all such, pollutants below) ❑ No (go to Section DO
VIII. Biolo` ical Toxicity Testin Data
Do yow have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or
on a receiving water in relation,to your discharge within the last 3,years?
❑ Yes (list all such pollutants below) ❑ No (go to Section IX)
IX. Contact analysis Information
Were any,of the analysis, reported,Enitem VII performed by a contact laboratory or consulting firm?
® Yes (list the name, address, and telephone number of, and pollutants ❑ No (go to Section X)
analyzed by, each such laborato or firm below
A Name
B Address
C Area, Code,& Phone No
D -Pollutants Analyzed
Shealy Environmental Services 106 Vantage Point Drive 803-791-9111 Wet chemistry &
West Columbia, SC 29172 metals
GEL Laboratories LLC 2040 Savage Road 843-556-8171 Radio/ogicals
Charleston, SC 29407
X. Certification
I certify under penalty of law that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure, that qualified- personnel properly gather and evaluate
the information submitted Based on•my inquiry of the,person�or,personsewho�manage the system or those persons
directly responsible, for -gathering the, information, the Information, submitted is, to the best of my knowledge and
belief, true, accurate,,andreomplete / am aware that,there are, significant -penalties for submitting falsesinformation,
includln ; the•possibllr of line and ,im risonment for knowing,violations.
A Name& Official Title (type or print)
B Area Code and Phone,No
C Signature
D Date Signed
EPA Form 3510-2F (Rev 1-92)
Page 3 of 3
r
EPA Form 3510-2F (Rev 1-92)
Page 7 of 60
Analytical Laboratory
EPA ID Number (copy from Item /of Form 1) Form Approved OMB No 2040-0086
Approval, expires 5-31-92
VII. Dischar a Information Continued, from page 3 -of 'Form 2F
PartA - You must provide the fesults,of at least one analysis for every pollutant in this table Complete one table for each outfall See
_ instructions for additional fdetails
Maximum Values
Average Values
Number
Pollutant
include units
include units
Of
And
Grab Sample
Grab Sample
Storm
CAS Number
Taken During
Flow -weighted
TakemDunng
Flow -weighted
Events
(if avadable)
First 30
Composite
First 30
Composite
"Sampled
Minutes
Minutes
Sources of Pollutants
Oil & Grease
< 4 4 ifi
Biological Oxygen
2 0 mg1L
Demand BOD5
Chemical Oxygen
16 mg/L
Demand COD
Total Suspended
25 mg/L
Solids SS
Total
0 099 mg/L
Nitrogen
Total
0 059 mg/L
Phosphorus
H
Minimum
Maximum
Minimum
Maximu m
Part B - List each, pollutant, that is limited,in an, effluent, guideline which the facility is sublechto'or any pollutant listed in the facility's NPDES
permit for its,process wastewater (if the facility is operating under an existing NPDES permit) Complete one table for each outfall
See the instructions for additional details and r uirements
Maximum Values
Average Values
Number
Pollutant
mclude,units
include units
Of
And
Storm
Grab Sample
Grab Sample
CAS Number
Taken During
Flow -weighted
Taken During
Flow -weighted
Events
(Ifavadabie)
First 36
Composite
First 30
Composite
Sampled
Minutes
Minutes
Sources of Pollutants
Bromide (24959-67-9)
Chlorine, Total
residual
Ammonia (as N)
-
Chlonde
5 4 mg1L
Color
100 units
Fluoride (16984-48=8)
0.12 mg/L'
Nitrate-Nitnte (as N)
0 099 mg1L
Radioactivity, alpha
< 5 0 pCdL
total
Radioactivity, beta
710 pCi/l
-
total
Radioactivity, radium
< 1 0 pCilL
total
Radioactivity, radium
< 10 pCi/L
226 total
Sulfate (as SO4)
38 mg/L
14808-79-8
Sulfite (as S03)
14265-45-3
Aluminum, Total
0 35 mg/L
7429-90-5
Barium, Total
0 080 mg/L
(7440-39-3)_
Boron, Total (7440-
0 33 mg/L
42-8)'
Cobalt, Total (7440-
<0 005 mg1L
48-4)-
Iron, Total (7439=89-6)
18 mglL
Magnesium, Total
5.3 mg1L
-
7439-95-4
Molybdenum, Total
(7439-'98 7
Manganese, Total
0 60 mg/L
7439-96-5
Tin, Total
<0 005 mg/L
(7440-'31 -5
Page V1I-1
Continue on Reverse
Page,8 of 60
Analytical Laboratory
Titanium, Total
18 ug/L
7440-32=6
Antimony, Total'
(7440-36-0),
_
Arsenic; Total -
20 ug/L
7440-38-2
-
Beryllium, Total
e 1 0`ug&
-
7440-41-7
_
Cadmium, Total
<0 10'6g/L
7440-43-9
1
_
Chromium, Total
<5 O ug/L
7440-47-3
Copper, Total
<10 ug/L
7440-50-8
Lead, Total
-
7439-92-1
_
Mercury, Total
<0 0001 mg1L
7439-97-6
Nickel, Total
<10,ug/L
7440-02-0
Selenium, Total
<5,ug/L
7782-49-2
Silver, Total
<5 ug/L
7440-22-4
Thallium, Total
r7,40-28-0nc, Total35ug/L
440-66-6
EPA'Form 3510-2F (Rev 1-92) Page VII -1 Continue on Reverse
Page 1 of 60
Analytical Laboratory
Duke Analytical Laboratory
Mwnnergya 13339 Hagers"Ferry Road
Huntersvdle, NC 28078-7929
R@07-03-07 McGuire Nuclear Complex — MG03A2
Phone 704-875-5245 Fax, 704-875-4349
Job Summary Report
Job Number: I 09 -APR -0401
Project Name: Allen Storm Water
Customer Name: Brandy'Starnes, Don Scruggs
Copy To: Allen Stowe, Robert Wylie, Mary Ann Ogle
Customer Address:
MG03A3
Lab Contact: Mary Ann Ogle
Lab Contact Phone: 704-875-5274
Report Authorized By:
(Printed, Name)
MARY ANN OGLE
Report Authorized By:
(Signature) CA"(,— Date: /07
Data Package
This data package includes analytical results that are�applicable only to'the samples
described in this narrative An estimation of the uncertainty of measurement for the
results In the report is available upon request. This report shall not be reproduced, except
In full, without the written consent of the Analytical Laboratory. Please contact the
Analytical Laboratory with any questions The order of individual sections within this
report is as follows -
Job Summary Report
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Reports (if applicable)
Sub -contracted Laboratory Results
Customer Specific Data Sheets, Reports & Documentation (if applicable)
Customer'Database Entries
Test Case Narratives
Chain of Custody (COC)
f
Page 2 of 60
Analytical Laboratory
IEneiDuke Analytical Laboratory
13339 Hagexs Ferry Road
�y Huntersville, NC 28078-7929
Rev 07-03-07 McGuire Nuclear Complex — MG03A2
Phone 704-875-5245 Fax 704-875-4349
Job Summary Report
Certification
The Analytical Laboratory holds the following Certifications
New York State Department of Health Certification # 11717(NELAC)
North Carolina Department of Health & Human Services Certification # 3,7804
South Carolina (DAA Q Laboratory )D,# 99005
North Carolina (DENR) Certification # 248
Analytical results listed in this report may not be certified by the authorities referenced above.
Contact the Analytical Laboratory for definitive information about the certification status of
5specific`methods. The results meet all requirements of NELAC except where,deviatibns are
noted in this report
Data Flags
Any analytical tests or individual analytes within a test flagged with an "X" ora "1" indicate a
deviation from the method,quality system or quality control requirement
Calculations
All results are reported on a wet,weight basis unless otherwise noted
5amnle ID's Hca Descriptions:
Collection Sample
Sample ID Plant/Station Date Collected By Description
-------------=-------=---------------------------------
29010469 ALLEN 4/20/2009 G Long ALLEN SWO15
-----------------
1 TOTAL SAMPLES
PDuke Analytical Laboratory
O&I e_r® 13339 Hagenferry Road
�y , Huntersville„NC 28078-7929
Rev 07-0"7 McGuire Nuclear Complex — MG03A2
Phone 704-875-5245 Fax 704-8754349
ti
Job Summary Report
Validation of Analytical Data Package
COC and .pdf report are in agreement with sample totals
i and,analyses (compliance programs and procedures)
u) All results are less than the laboratory reporting limits.
iii) All laboratory QA/QC requirements are acceptable.
iv) NPDES and TCLP results are below permit or regulatory
limits respectively
It Iv) above is No, document below:
Permit
Variable Result Limit Notes
Page 3 of 60
Analytical Laboratory
1✓' Yes
rNo
r Yes
r_No
lv_ Yes
r No
ryes
I No
Components of the Job Summary Report arranged in order
V) stipulated on page one. r Yes EE
Indicate, components included.
rt Job Summary Report
Analytical Laboratory Certificate of
7 Analysis
r Analytical Laboratory QC Report
(if applicable)
j Sub -contracted Laboratory Results
A) Notes and Additional Information
Customer Specific Data Sheets, Reports &
Documentation (if applicable)
'r Customer Database Entries
r—, Test Case Narratives
r Chain of Custody
The holding time for,the fecal coliform analysts (6 hours) was exceeded for Outfall' SW015 The
results are considered estimates due to the holding time failure -
Mary Ann Ogle
Duke Energy -Analytical Lab
NPDES_ Contact
Office 704-875-5274
Cell 704-280-7956
Pagex9 of 60
Analydcal'Laboratory
Cnnhnuert,frnm'.thp Front
Part C - Listieach pollutant shown -in Tables 217-2; 2F-3, and 2F-4,that you know or have reason to believe isrpresent cSde the instructions' for
additional detads,and requirements Com lets one table for each outfall
Maximum Values — Average Values Number
Pollutant include units inc/b-e units)-- Of
And Grab Sample Grab"Sample Storm
CAS Number Taken During Flow -weighted Taken During Flow -weighted Events
(if available) First 30 Composite First 30 Composite Sampled
Minutes Minutes Sources of Pollutants
Cyanide, Total
(57-12-5) _
Phenols, Total
Surfactants (MBAs) -
Fecal Coliform CHT 410 col/100
ML
1 I
Part D - Provide data for the storm events which resulted in the maximum,values for the flow weighted com osite sample
1
Date of,
Storm
Event
2
Duration
of Storm Event
(in minutes)
3
Total rainfall
ng storm event
during
(in inches)
4
Number.of hours between
- of storm measured
and end of previous
measurable rain event
5
Total flow from
rain event
(gallons,orspecrfy,units)
7 Provide a descn tion of theimethod of flow measurement or estimate
EPA Forfn 3510-2F (Rev 1=92) Page VII -2
Page 1,O1of'60
Analytical Laboratory
SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy Corporate EHS
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention Mary Ann Ogle
Project Name Allen Steam Station = Stormwater
Project Number 09 -APR -0401'
Lot Number KD21046
Date,Completed 05/04/2009
Date Revised 05/15/2009
Grant Wilton,
Project Manager
SV -`�� r S•' E
This report shall not be reproduced, except in its entirety, without the written approval,of Shealy Environmental Services, Inc
The`followmglnon-paginated documents are considered,part of4hisseport Chain of Custody Record and Sample Receipt Checklist
I IIIIIIII Iill IIII VIII VIII VIII IIID IIII IIII
7 Shealy Environmentat'Services Inc Page 1 of 7
I 106,Vantage PointiDnve 'We§t Columbia, SC 29172 (803) 791-9700 Fax(803)i791-91,11, www shealytab com Level 1 Report v21
1
Page 11 of 60
Analytical Laboratory
SH'EALY ENVIRONM'ENT'AL SERVICES, INC.
SC DHEC No 32010 NELAC No ,E87653 NC DEHNR No 329
Case Narrative,
Duke Energy Corporate EHS
Lot,Number. KD21046
This, Report of Analysis, contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative The sample
receiving date is documented in the header information associated with each sample
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc ("Shealy") Quality Assurance Management Plan (DAMP), standard operating procedures (SOPs), and Shealy
policies Any exceptions to the NELAC standards, the QAMP, SOPS or policies are qualified on the results page or discussed below
If you have,any questions regarding this report please contact the Shealy Project Manager listed on the cover page
Shealy Environmental Services Inc Page 2 of 7
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791.9111 www shealylab oom Level 1 Report v21
Page,42 of 60
Analytical Laboratory
SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy Corporate ,EHS,
Lot Number KD21046
Sample Number Sample ID Matrix Date Sampled Date Received
001 Allen SW015 Aqueous 04/20/2009 1220 04/21/2009
(1 sample)
U
I
Shealy Environmental Services, Inc Page 3 of 7
106 Vantage Point Drive West Columbia SC 29172 (803) 791-9700 Fax (803) 791 91,11 www shealylab com Level t Report v2 t
i
Shealy Environmental Services, Inc Page 4 of 7
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Level 1 Report v2 1
(
Page 13 of 60
Analytical Laboratory
SHEALY ENVIRONMENTAL SERVICES,, INC.
Executive Summary
Duke Energy Corporate EHS
i
Lot Number- KD21046
Sample Sample ID
Matrix
Parameter Method
Result
Q
Units
Page
001
AIIen,SW015
Aqueous
BOD, 5 day SM 5210B
2 0
mg/L
5
001
AIIeniSW015
Aqueous
Chloride 30010
5,4
mg/L
5
001
Allen SWO15
Aqueous
COD SM 52200
16
mg/L
5
001
Alien SWO15
Aqueous
Fluoride 3000
012
mg/L
5
001
AIIen,SW015
Aqueous
Nitrate-Ndnte - N 3532
0099
mg/L
5
001
Allen'SW015
Aqueous
Phosphorus 3651
0 059
mg/L
5
I 001
Allen SW015
Aqueous
Platinum -Cobalt Color SM 2120B
100
color
5
001
Alien SWO15
Aqueous
Sulfate 3000
38
mg/L
5
001
Allen,SWO15
Aqueous
TSS SM 2540D
25
mg/L
5
001
Allen SWO15
Aqueous
Fecal Coliform -MF SM 9222D
410
H
col/100
5
001
Alien SWO15
Aqueous
Aluminum 2008
350
ug/L
6
001
Allen SWO15
Aqueous
Arsenic 2008
20
ug/L
6
001
Allen SWO15
Aqueous
Barium 2008
80
ug/L
6
001
Allen SWO15
Aqueous
Boron 2008
330
ug/L
6
001
Allen SWO15
Aqueous
Iron 2008
1800
ug/L
6
001
Allen SWO15
Aqueous
Magnesium 2008
5300
ug/L
6
001
Allen SWO15
Aqueous
Manganese 200'8
600
ug/L
6
001Allen
SWO15
Aqueous
Titanium 200,8
18
ug/L
6
001
Allen SWO15
Aqueous
Zinc 2008
35
ug/L
6
(19 detections)
Shealy Environmental Services, Inc Page 4 of 7
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Level 1 Report v2 1
Inorganic non-metals
Client Duke,Energy Corporate EHS Laboratory ID KD21046-001
Description Allen'SW015 Matrix Aqueous
Date Sampled 04120/2009 1220
)ate Received 04121/2009
Page+14 of 60
Analytical Laboratory
Run
Prep,Method Analytical Method
Dilution
Analysis Date
Analyst
Prep Date
Batch
1
(BOD; 5 day) SMl52108
1
04/27/200910845
SLH
04/22/2009 0759
4977
1
(Chloride) 300 0
1
04/30/2009 1050
DAS
3000
99815
1
(COD) SM 52200
1
04/24/2009 1830
SAM
04/24/2009 1620
10
1
(Fluoride) 300 0
1
04/30/2009 1050
OAS
010
99816
1
(Nitrate-Nitr) 353 2
1
04/22/2009,1154
MML
mg/L
99312
1
(Phosphorus) 365 1
1
04/30/2009 1801
RLM
04/23/2009 1721
99422
1
(Platinum -Cob) SM
2
04/22/2009 0910
HCB
Sulfate
3000
1
(Sulfate) 300 0
1
04/30/2009 1050
OAS
351 2
99817
1
351 4 (TKN) 351 2
1
05/01/2009 1757
RLM
04/28/2009 1500
99640
1
(TSS) SM 2540D
1
04/23/2009 1348
HCB
2
89404
1
(Fecal CQllfo) SM
1
04/22/2009 1523
SLH
04/21/2009 1723
1
1
(HEM (oil and) 1664A
1
04/22/2009 1413
JKP
99293
J
PQL = Practical quantitation limit B = Detected in the method blank E - Quantitation of compound exceeded the calibratton range
NO = Not detected at or above the PQL J = Estimated result < Poll. and > MDL P - The RPD between two GC columns exceeds 40%
Where applicable all sod sample analyses are reported on -a dry weight basis unless gagged wah a N - Recovery is out of criteria H - Out of holding time
Shealy, Environmental Services, Inc Page 5,of 7,r
106 Vantage PoinbDrrve West Columbia, SC 29172 '(803) 791-9700 Faxi(803) 791-9111 www shealylab com Level 1 Report v21
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
BOD, 5 day
SM 5210B
20
20
mg/L
1
Chloride
3000
54
1 0
mg/L
1
COD
SM 5220D
16
10
mg1L
1
Fluoride
3000
012
010
mg/L
1
Nitrate -Nitrite --,N
3532
0 099
0 020
mg/L
1
Phosphorus
7,723.14-0 3651
0 059
01010
mg/L
1
Platinum -Cobalt Color
SM 2120B
100
10
color units
1
Sulfate
3000
38
10
mg/L
1
TKN
351 2
NO
050
mg/L
1
TSS
SM 2540D
25
33
mg/L
1
Fecal Coliform -MF
SM 9222D
410 H
2
col/100ml-
1
HEM (oil and grease)
1664A
ND
44
mg/L
1
J
PQL = Practical quantitation limit B = Detected in the method blank E - Quantitation of compound exceeded the calibratton range
NO = Not detected at or above the PQL J = Estimated result < Poll. and > MDL P - The RPD between two GC columns exceeds 40%
Where applicable all sod sample analyses are reported on -a dry weight basis unless gagged wah a N - Recovery is out of criteria H - Out of holding time
Shealy, Environmental Services, Inc Page 5,of 7,r
106 Vantage PoinbDrrve West Columbia, SC 29172 '(803) 791-9700 Faxi(803) 791-9111 www shealylab com Level 1 Report v21
P 'Page 151of,60
"
Analytical, Laboratory
ICP -MS
Client Duke Energy Corporate EHS ' Laboratory ID KD21046-001
Description Alten,SW015a Matrix Aqueous
Date;Sampled 04/20/200911220
Date Received 04/21/2009
Run Prep Method
1 2002
Analytical Method Dilution Analysts Date Analyst.
2008 1 04/26/2009 1401 FTS
Prep Date
04/22/2009 1930
Batch
99302
CAS Analytical
Parameter
Number, Method
'Result Q
PpL
Units
Run
Aluminum
7429-90-5 2008
350
50
ug/L
1
Arsenic
7440-38-2 2008
20
5 0
ug/L
1
Barium
7440-39-3 2008
80
50
ug/L
1
Beryllium
7440-41-7 2008
NO
10
ug/L
1
Boron
7440-42-8 2008
330
50
ug/L
1
Cadmium
7440-43-9 2008
NO
010
ug/L
1
Chromium
7440-47-3 200 8'
NO
5 0
ug/L
1
Cobalt
7440-48-4 200 8
ND
50
ug/L
1
Copper
7440-50-8 2008
NO
10
ug/L
1
Iron
7439-89-6 2008
1800
20
ug/L
1
Magnesium
7439-95-4 2008
5300
50
ug/L
1
Manganese
7439-96-5 2008
600
10
ug/L
1
Nickel
7440-02-0 2008
NO
10
ug/L
1
Selenium
7782-49-2 2008
NO
50
ug/L
1
Sliver
7440-22-4 2008
ND
50
ug/L
1
Tin
7440-31-5 2008
NO
50
ug/L
1
Titanium
7440.32.6 2008
18
50
ug/L
1
Zinc
7440-66-6 2008-
35
10
ug/L
1
1
POL - Practical quantitation limit 8 = Detected in the method blank E = Quantitation of compound exceeded the calibration range
NO - Not detected at or above the POL J = Estimated result < POL and > MDL P = The RPD between two GC columns exceeds 40%
Where applicable ,all soil sample analysis are reported on a dry weight basis unless nagged with a -W- N - Recovery is out of criteria H = Out of holding time
Shealy Environmental Services, Inc
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803)1791-9111 www shealylab com
r
r
Page.,6:of 7
Levert Report v2l
Page 16 of 60
Analytical Laboratory
CVAA
Client Duke Energy, Corporate ENS Laboratory ID KD21046-001
Description Allen SWO15 Matrix Aqueous
Date Sampled 04120/20091220
)ate Received 04/21/2009
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1
245 1 1 04/24/2009 1344 BNW
04/23/2009 2215
99435
CAS Analytical
Parameter
Number Method
Result 0
POL Units Run
Mercury
7439-97-6 2451
ND
000010 mg/L 1
POL = Practical quanhiaaon limit BL- Detected in the method blank ,E • Quannlatlon of compound exceeded the calibration range
ND = Not detected at or above the PQL J - Estimated result < POL and > MDL P = The RPD between two GC columns exceeds 40%
Where applicable all sod sample analysis are reported on a dry weight basis unless flagged with a `W N - Recovery is out of criteria 1 H = Out of holding time
Shealy,Enwronmental Services, Inc' l Page 7 of 7
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Level t Report t
r
i
Page 17 of 60
Analytical Laboratory
QC Summary
I Shealy Environmental Services, Inc QC Data for Lot Number KD21046
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Level 1 Reoon v2 1
Page 18 of 60
Analytical Laboratory
Inorganic non-metals - MB,
Sample ID KQ99312-0014
Matrix: Aqueous
Batch 99312
Analytical Method 3532
Parameter Result a D11 PQL Units Analysis Date
Nitrate-Nitnte - N NO 1 0 020 mg/L 04/22/2009 1119
r
f
' PQL = Practical quantitation lima P = The RPD between two OC columns exceeds 40% N Recovery Is out of cntena
ND - Not detected at or above the PQL J -Estimated result <,PQL and> MDL + RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W
Note Calculations are performed before rounding to avoid round -off errors In calculated results
Shealy Environmental Services Inc QC Data for Lot Number KD21046
106 Vantage Point Drive West Columbia SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Level,1 Report v2 1
Page 19 of 60
Analytical Laboratory
Inorganic non-metals --LCS
Sample ID' KQ99312-002 Matrix Aqueous
Batch 99312
Analytical Method., 353 2
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Nitrate -Nitrite - N 080 084 1 105 90-110 04122/2009 1120
PGL = practical quanbtabon limit P = The RPD between two GC columns exceeds 40% N - Recovery is out of cntena
NO = Not detected at or above the PGL J = Estimated result < PQL and > MDL • RPD .s aut of cntena
Where applicable all soil sample analysis are reported on a dry weight basis unless flagged with a `W'
Note Calculationsiare performed before,rounding-to avoid round -off errors in calculated results
Shealy Environmental Services Inc QC Data for'Lot Number. KD21046
106 Vantage'Pomt Drive WesGColumbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab Com Level I Report v21
Inorganic non-metals - LCSD
Page 20 of 60
Analytical Laboratory
Sample ID I KQ99312-003 Matrix Aqueous
Batch x99312
Analytical Method. 353 2
Spike
Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) Q DO % Rec % RPD Limit Limit Analysis Date
Nitrate -Nitrite - N 080 083 1 104 048 90-110 20 04/22/2009 1121
1
I
PoL - Practical quenbtabon limit P = The RPD between two GC columns exceeds 40% N - Recovery is out of cntena
No = Not detected at or above,the POL J = Estimated result < PoL and > MDL RPD is out of cntena
i —
t Where applicable all soil sample analysis are reported on a dry weight basis unless flagged with a'W
Note* Calculations are performed before rounding to avoid round -off errors,in calculated results
Shealy Environmental Services Inc QC Data for Lot Number K021046
106 Vantage Point Drive West Columbia, SC 29172 (803)1791-9700 Fax (803),791-9111 www shealylab corn Level 1 Reportv2 t
1
Page�21 of 60
Analytical Laboratory
Inorganic non-metals - MB
Sample ID K099404-001 Matrix Aqueous
Batch 99404
Analyticab Moth od SM12540D
Parameter Result Q DR PQL Vnds AnalysisrDate
TSS ND 1 10 mg1L 04123120091348
0
I
0
PQL - Practical quanotedon limit P - The RPD between two GC columns exceeds 40% N - Recovery is out of adeno
ND = Not detected at or above the PDL J - Estimated result < PDL and > MDL + RPD is out of criteria
Where applicable all soil sample analysis are reported on a dry weight basis unless flagged with a W
Note Calculations are performed before rounding to avoid round -off errors`m calculated results
Shealy Environmental Services,}lnc QC Data,for Lot Number KD21046
106 Vantage Point Dnve Wasl,C0Iumbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www sheaiylab cam Level til l ReportQ I
I
F
Inorganic, non-metals - LCS
Page 22W 60
Analytical Laboratory
Sample ID KQ99404-002 Matrix. Aqueous
Batch 199404
Analytical Method SM 2540D
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q DII % Ree Limit Analysis Date
TSS 500 500 1 99 90-110 '04/23/2009 1348
PQL = Practical quantitallon limit P = The'RPD between two GC columns exceeds 40% N Recoveryis out of entena-
ND = Not detected at or above the PQL J - Esbmated result - PQL and >WDL RPD is out of enteda t
Where applicable, all sod sample analysis are reported on a dry weight basis unless flagged with 3.'M
Note. Calculations are performed before rounding to avoid'round-off errors'in calculated results
Shealy Environmental Services Inc QC Data for Lot Number KD21046
106 Vantage Point Drive Wast Columbia, SC 29172 (803) 791-9700 Fax(803)791-9111 www shealylab com Level 1 Report v21
Page 23 of 60
Analytical Laboratory
Inorganic non-metals - MB
Sample ID KQ99422-001 Matrix Aqueous
Batch 99422 Prep Method 365+1
Analytical Method 365 1 Prep Date 04/23/2009 1721
Parameter Result Q Dil PQL Units Analysis Date
Phosphorus ND 1 0 010 mg/L 04/28/2009 1355
PQL - Practical quantitation limit P = The RPO between two GC columns exceeds 40% N - Recovery is out of criteria
No - Not detected at or above the PQL J = Estimated result < PQL and > MOL + - RPO is out of criteria
Where applicable all soil sample analysis are reported on a dry weight basis unless (lagged with a'W'
Note., Calculations are,performed before rounding to avoid round -off errors,in calculated results
i Shealy Environmental'Serv,ces Inc QC Data for Lot Number''KD21046,
106 Vantage Polnt,Dnve West Columbia SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Level t Repon v2 1
I
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N - Recovery is out of criteria
ND = Not detected at or above the PDL J > Estimated result < PQL and >MDL RPD is out of cntena
Where applicable all soil sample analysis are reported on a dry weight basis unless flagged with a'W'
Note Calculations are performed before rounding to avoid Found-off'errors in calculated results
t Shealy Environmental Services Inc QC Data for Lot Number K021046
106 Vantage' Point Drive West Columbta,'SC 29172 (803),791-9700 Fax(803)791-911,1 www shealylab com Level 1 Report v2 1
f
Page 24 of 60
`
Analytical Laboratory
Inorganic non-metals - LCS
Sample ID KQ99422-002
Matrix Aqueous
Batch 99422
Prep,Method 3651
Analytical; Method: 3651
Prep Date 04/23/2009 1721
Spike
Amount
Result % Rec
Parameter
(mg/L)
(mg1L) Q DII %,Rec Limit
Analysis,Date-_
Phosphorus
025
024 1 98 90-110
04/28120091355
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N - Recovery is out of criteria
ND = Not detected at or above the PDL J > Estimated result < PQL and >MDL RPD is out of cntena
Where applicable all soil sample analysis are reported on a dry weight basis unless flagged with a'W'
Note Calculations are performed before rounding to avoid Found-off'errors in calculated results
t Shealy Environmental Services Inc QC Data for Lot Number K021046
106 Vantage' Point Drive West Columbta,'SC 29172 (803),791-9700 Fax(803)791-911,1 www shealylab com Level 1 Report v2 1
Pages25,of 60
Analytical Laboratory
Inorganic non-metals - LCSD
Sample ID ^KQ99422-003 ;Matrix Aqueous
Batch ,99422 Prep Method 365'1
Analytical Method. 365 1 Prep Date 04/23/2009 1721
Spike
Amount Result % Roo % RPD
Parameter (mg/L) (mg/L) Q DII % Rao % RPD Limit Limit Analysis Date
Phosphorus 025 024 1 97 047 90-110 20 04/28/2009 1355
l
POL = Practical quanlitalion hmil, P = The RPD between two GC columns exceeds 40% N - Recovery is out of crdena
ND = Not detected at or above the POL J - Estimated result < POL and > MDL + - RPD is out of criteria
Whore applicable all sod sample analysis are reported on a dry weight basis unless nagged with a "W'
Note Calculations are performed before,rounding,to avoid round -off errors In calculated'results
Shealy Environmental Services, Inc QC Data for Lot Number KD21046
106Vantage' Point Drive West Columbia SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Level 1 Report v2 1
Page 26 of 60,
Analytical Laboratory
Inorganic non-metals - MB•
Sample ID KQ99640-001 Matrix ,Aqueous,
Batch 99640 Prep Method 351 4
Analytical Method 351 2 Prep Date 04/28/2009 1500
Parameter Result Q DII PQL Units Analysis Date
TKN, ND 11 050 mg/L 05/01/200911845
t
PQL = Practical quanotation limit P - The RPD between two GC columns exceeds 40% N - Recovery is out of aitena
ND - Not detected at or above the PQL J = Estimated result < PQL and =MOL RPD is out o6cntena
! Where applicable, all sod sample analysis arg reported on a dry weight basis unless flagged wan a "W -
Note Calculations are performed before rounding to avoid round -off errors,in calculated results
Shealy Environmental Services, Inc QCtData,for Lot Number KD21046
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803),791-9111 www shealylab com Level 1 Report v2 1
'Page 27 of 60
Analytical Laboratory
Inorganic non-metals - LCS
Sample ID KQ99640-002 Matrix Aqueous
Batch 99640 Prep Method 351.4
Analytical Method: 351 2 Prep Date +04/28/2009 1500
Spike
Amount Result % Ree
Parameter (mg/L) _(mg1L) Q Dil % Rec Limit Analysis Date
TKN 20 21 1 106 90-110 05/0112009 1441
7
1
PQL - Practical cluantitalion limit P = The RPD between two GC columns exceeds 40% N - Recovery is out of criteria
NO = Not detected at or above the PQL J - Eshmated,result < PQL and > MDL RPD is out of criteria
Where applicable all soli sample analysis are reported on a dry weight basis unless flagged with a'W' -
Note Calculations are performed before rounding to avoid round -off errorsiin calculated results
Shealy Environmental Services. Inc QC Data for Lot Number KD21046
106 Vantage Point Drive West Columbia. SC 29172 (803) 791-9700 Fax (803) 791-91.11 www shealylab corn Level 1 Report v21
Page 28 of 60
Analytical Laboratory
Inorganic non-metals - LCSD,
Sample,ID IKQ99640-003 Matrix ,Aqueous
Batch 199640 Prep Method 3514
Analytical Method 351 2 Prep Date 04/28/2009 1500
Spike
Amount Result % Rao % RPD
'Parameter (mg/L) (mg/L), Q Dil % Rec '% RPD Limit Limit Analysis Date
TKN 20 21 1 105 023 90-110 20 05/01/2009 1441
PDL = Practical quantitation limit P = The RPO between two GC columns exceeds 40% N - Recovery is out of crdena
ND - Not detected at or above the PQL J = Estimated result < PGL and > MDL • - RPD is out of cntena
Where applicable all sal sample analysis are reported on a dry weight basis unless flagged with a'W
Note Calculations aWperformed before roundingito avoid'round-off errorslm calculated results
Shealy Environmental Services, Inc QC Data for Lot Number K021046
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax.(803) 791-9111 www shealylab com Level 1 Repoli v21
Page 29 of 60
' Analytical Laboratory
Inorganic non-metals - MB�
Sample ID KQ99815-001 Matrix Aqueous
Batch 99815
Analytical Method 3000
Parameter Result Q Dill PQL Units Analysts Date
Chloride ND 1 10 mg/L 04/30/20090920
PQL = Practical quantltahon limit P =,The,RPD between two GC columns exceeds 40% N - Recovery Is out of enters
NO = Not detected at or above the PQL J - Estimated result < PQL and > MDL - RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a'W'
Note Calculations are performed before rounding to avoid round -off errors In calculated results
Shealy Environmental Services Inc QC Data for Lot Number KD21046
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-91,11 www shealylab corn Level 1 Report v21
1 Page -30 of 60
I Analytical Laboratory
Inorganic non-metals = Ll
Sample ID KQ99815-002 Matrix Aqueous
Batch 99815
Analytical Method 300 0
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q DII % Rec Limit Analysis Date
Chloride 20 21 1 104 90-110 04/30/2009 0943
POL - Practical quantitation lint P = The RPD between two GC columns exceeds'40 % N - Recovery is out of criteria
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL • RPD Is out of cntena
Where applicable all soil sample analysts are reported on -a dry weight basis unless flagged with a "W'
Note Calculations are, performed before rounding'to-avoid round -off errors In, calculated�results
Shealy Environmental Services,, Inc QC Data for Lot Number KD21046
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791.9111 www shealylab com Level 1 Report Q 1
Page 31 of 60
Analytical Laboratory
Inorganic non-metals - LCSD
Sample ID: KQ99815-003 Matrix Aqueous
Batch -,99815
Analytical Method '300 0
Spike
Amount Result % Ree % RPD
Parameter (mg/L) (mg/L) Q Dil % Rec %,RPD Limit Limit Analysis Date
Chloride 20 21 1 103' 0 86 90-110 20 04/30/20091005
POL = Practical quantitation limit P =,The RPD between two GC columns oxceeds 40%, N - Recovery is out of criteria
ND,= Not detected at or above the POL J - Estimated result < POL and > MDL « RPD is out of cntena
Where applicable ,all sod sample analysis are reported on a dry weight basis unless nagged with a -W-
Note. Calculations are performed before rounding'to avoid round -off errors in calculated results
Shealy'Environmental Services Inc QC,Data for Lot Number,KD21046
106 Vantage Point Drive West Columbia SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Level 1 Report v2 1
Page 321of 60
Analytical, Laboratory
I
Inorganic non-metals - MB
Sample ID ,KQ99816-001 Matrix Aqueous
Batch 199816
Analytical Method —300 0
Parameter Result Q oil PQL Units Analysls,Date
Fluoride ND 1 010 mg/L 04/30/2009 0920
r
PQL - Practical quantitation limit P - The RPD between two GC columns exceeds 40% N Recovery is out of cntena
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + RPD is out of orliena
Where applicable all soil sample analysis are reported on a dry weight basis unless nagged with a 'W"
Note Calculations are performed before rounding do avoid round -off errors in caiculated'results
Shealy Environmental Services, Inc QC Data for Lot Number KD21046
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com - Level 1 Report v2 1
Page 33 of 60
Analytical Laboratory
Inorganic, non-metals - L' CS
Sample,ID K099816-002 /Matrix Aqueous
Batch 99816
Analytical Method 300 0
Spike
Amount Result % Ree
Parameter, (mg/L) (mg/L:)- Q D)I % Rec Limit Analysis Date
Fluoride 4'0 42 1 106 90-110 04/30/2009 0943,
r
a
POL - Practical gtianbtebon limit P = The RPD between two GC columns exceeds 40% N Recovery is out of criteria
No - Not detected at or above the PQL J = Estimated result <PQL and > MDL + RPD is out of Intens
Where applicable all soil sample analysis are reported on a dry weight basis unless Ragged with a 'W*
Note Calculations are performed beforeirounding to avoid round -off errors in calculated results
Shealy, Environmental Services Inc QC;Data for Lot Number K021046
106 Vantage PointlDrive West Columbia, SC 29172 (803) 791.9700 Fax (803) 791-9114 www shealylab corn Level 1 Report v2 t
Page 34,of 60
Analytical Laboratory
Inorganic non-metals - LCSD
Sample ID 'KQ99816-0113 Matrix Aqueous
Batch 99816
Analytical Method 300 0
Spike
Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) Q Dil % Ree % RPD Limit Limit Analysis Date
Fluonde 4,0 40 1 101 47 90-110 20 04/30/2009 1005
0
PGL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N - Recovery is out of criteria
NO = Not detected at or above the PQL J = Estimated result < PQL and - MDL • RPD is out of criteria
Where applicable all soil sample analysis are reported on a dry weight basis unless flagged with a'W'
Note Calculations are performed before rounding to avoid round -off errors in calculated c results
Shealy Environmental Services, Inc I QC Data for Lot`Number KD21046
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www sheaiylab com Level 1 Report v2 1
Page 35 of,60
Analytical Laboratory
Inorganic non-metals - MB
Sample ID KQ99817-001 Matrix Aqueous
Batch 199817
Analytical Method 300 0
Parameter Result Q oil PQL Units Analysis Date
Sulfate ND 1 10 mg/L 04/30/20090920
I
PQL = Practical quantitshon limit P = The RPD between two GC columns exceeds 40% N Recovery is out of onlena
ND = Not detected at or above the PQL J = Estimated result < PQL and - MDL . - RPD Is out of criteria
Where applicable fall sad sample analysis are reported on a dry weight basis unless gagged with a'W'
Note Calculations are performed before rounding to avoid round -off errors In calculated results
Shealy Environmental Services Inc QC Data for Lot Number KD21046
106 Vantage,Point Dnve West Columbia SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Level 1. Report v2 t
Page 36 of 60
Analytical Laboratory
Inorganic non-metals - LCS
Sample ID KQ99817-002 Matrix Aqueous
Batch 99817
Analytical Method 300 0
Spike
Amount Result % Rao
Parameter (mg/L) (mg/L) Q Dd %/ Rec Limit Analysts Date
Sulfate 20 20 1 102 90-110 04/30/2009 0943
POL - Practical quantitation limit P = The RPD between two GC columns exceeds 40% N Recovery is out of criteria
ND = Not detected at or above the POL J - Estimated result < POL and >'MDL + - RPD is out of criteria
Where applicable all soil sample analysis are r000rted on a dry weight basis unless nagged with a 9N'
Note Calculations are performed before rounding to avoid round -off errors,tn calculated results
Shealy Environmental Services, Inc QC Data for Lot Number KD21046
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803),791-9111 www shealylab com Level 1,Rep`ort Q 1
r
Page 37 of 60,
Analytical Laboratory
Inorganic non-metals - LCSD
Sample ID' K099817-003 Matrix Aqueous
Batch 99817
Analytical Method* 300 0
Spike
Amount Result % Rec % RPD
Parameter (mg/L) (mg/L)� a DII % Rec % RPD Limit Limit Analysis Date
Sulfate 20° 20 1 102 0 095 90-110 20 04/30/2009 1005
POL - Practical quantitation Ilmlt P = The RPD between two GC columns exceeds 40% N - Recovery is out of criers
ND = Not detected at or above the POL J - Estimated result c POL and >MDL + -
_ RPD is out of rntena
i
Where applicable all sat sample analysis are reported on a dry weight basis unless flagged vnlh a'W-
Note* Calculationsrare performed Ibefore, round Ing to avoidiround-off errors in calculated results
Shealy Environmental Services Inc QC Data,for Lot Number KD21046
106 Vantage Point Drive West Columbia SC 29172 (803) 791-9700 fax (803) 791-9111 WWW sheatylab com Level 1 ReportQ 1
Page 38 of 60
Analytical Laboratory
Inorganic non-metals - MB
Sample ID' KQ99293-001 Matrix Aqueous
Batch 99293
Analytical Method 1664A
Parameter Result Q Dd PQL Units Analysis,Date
HEM,(ofl and grease) ND 1 40 mg/L 04/22/20090000
0
r
PQL - Practical quantitation limit P = The RPD between two GC columns exceeds 40% N - Recovery is out of criteria
'ND . Not detected at or above the PQL J = Estimated [result < PQL and s MDL +- RPD is out of criteria
Where applicable all sod sample analysis are reported on a dry weight basis unless flagged with a W
Note Calculations are performed before rounding to avoid round -off errors In calculated results
1 Shealy Environmental Services, Inc QC Data for Lot Number KD21046,
106 Vantage'PoinVDnve West Columbia, SC 29172 (803) 791-9700 Fax,(803) 791-9111 www shealylab com Level 1 Report v2 i
Page 39 of 60
Analytical Laboratory
Inorganic non-metals - LCS
Sample ID K099293-002 Matrix Aqueous
Batch +99293,
Analytical Method 1564A
Spike
Amount Result % Rec
Parameter (mg/L), (mg/Lj Q DO % Rec Limit Analysis Date
HEM (oil and grease) `40 38 1 96 78-114 04/22/2009 0000
1
POL - Practical quantitation limit P = The RPD between two GC columns exceeds 40V N Recovery Is out of cntena
t
1 ND = Not detected at or above the POL J - Esivnated result c POL and - MDL * - RPD is out of criteriat —
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a W.
Note Calculations are'performed before rounding to avoid round-off'errors in calculated;results
Shealy Environmental Services, Inc QC Data for Lot Number KD21046
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Level 1 Report v2'1
Page 40 of 60
Analytical Laboratory
CVAA - MB
Sample ID K099435-001 - Matrix* Aqueous
Batch 99435 Prep Method 7470A
Analytical Method 245 1 Prep Date, 04/23/2009 2215
Parameter Result Q 'DII PQL Units Analysis,Date
Mercury ND 1 000010 mg/L 04/24/2009 1331
PQL - Practical quantitation limit P The RPD between two GC columns exceeds 40% N Recoveryis out of cntena
ND - Not detected at or above the PQL J - Estimated result - PQL and > MDL + - RPD at out of criteria
Where applicable'all sod sample analysis are reported on a dry weight basis unless flagged with a W'
Note, Calculations are performed before rounding to,avoid round -off errors tmcalculated results
Shealy Environmental Services Inc QC Data for Lot+Number. KD21046
106 Vantage Point Drive West Columbia SC 29172, (803) 791-9700 Fax (803) 791-9111 www shealyiab cont Level 1 Report"v2 1
I
I Page 41 of 60
Analytical Laboratory
CVAA - LCS
Sample ID K099435-002 Matrix Aqueous
Batch. 99435 Prep Method , 7470A
Analytical Method 245 1 PreprDate 04/23/2009 2215
Spoke
Amount Result % Ree
Parameter (mg/L) (mg1L) Q Dil % Roe Limit Analysis Date
Mercury 00020 00020 1 100 85-115 04/24/2009 1338
PQL = Practical quantitation limit, P = The RPD between two GC columns exceeds 40% N - Recovery is out of criteria
NO = Not detected at or above the PQL J - Estimated result < PQL and> MDL + RPD rs out of rntena
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a -W-
Note Calculations are performed before rounding to avoid round -off errors In calculated, results
Shealy, Environmental Services Inc QC Data for Lot Number KD21046
106 Vantage PointfOnve We0Columbia, SC 29172 (803) 791-9700 Fax (803)'791-9111 www shealylab cam Levsl,l Report v2 1
1
CVAA-LCSD
Page 42, of 60
Analytical Laboratory
Sample ID KQ99435-003 Matrix Aqueous
Batch 99435 Prep Method 7470A
Analytical Method: 245 1 Prep Date 04/23/2009 2215
Spike
Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) Q DII % Rec % RPD Limit Limit _ Analysis Date
Mercury 00020 00020 1 100 10 85-115 20 04/24/2009 1340
PDL = Practical quantitation limit P - The RPD between two GC columns exceeds 40% N - Recovery is out of criteria
NO - Not detected at or above the PDL J - Estimated result,< PDL and > MDL * - RPD is out of criteria
Where applicable, alPsoll sample analysis are reported on a dry weight basis unlessnagged with a "W"
Note Calculations,are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental'Services Inc, QC Dataifor LoVNumber 'KD2104&
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax(803)791-9111 www shealylab com Level 1 Report Q 1
Page 43 of 60
Analytical Laboratory
ICP -MS - MB
Sample ID KQ99302-001 Matrix Aqueous
Batch 99302 Prep Method 20042
Analytical Method. 200 8 Prep Date 04/22/2009 1930
Parameter
Result
Q Off
PQL
Units
Analysis Date
Aluminum
NO
1
50
ug/L
04/26/20091255
Arsenic
NO
1
5'0
ug/L
04/26/20091255,
Banum
NO
1
50
ug/L
04/26/20091255
Beryllium
NO
1
10
ug/L
04/26/20091255
Boron
NO
1
50
ug/L
04/26/20091255
Cadmium
NO
1
010
ug/L
04/26/20091255
Chromium
NO
1
50
ug/L
04/26/2009 1255
Cobalt
NO
1
50
ug/L
04/26/2009 1255
Copper
NO
1
10
ug/L
04/26/20091255
Iron
NO
1
20
ug/L
04/26%20091255
Magnesium
NO
1
50
ug/L
04/26/20091255
Manganese
NO
1
10
ug/L
04/26/20091255
Nickel
NO
1
10
ug/L
04/26/20091255
Selenium
NO
1
50
ug/L
04/29/2009 1451
Silver
NO
1
50
ug/L
04/26/2009 1255
Tin
NO
1
50
ug/L
04/26/2009 1255
Titanium
NO
1
5 0
ug/L
04/26/2009 1255
Zinc
NO
1
10
ug/L
04/26/20091255
PQL - Practical quantitabon limit P - The RPD between two GC columns exceeds 40% N - Recovery is out of criteria
ND = Not detected at or above the PQL J - Estimated result < PQL and > MDL - RPD is out of criteria
Where applicable all sail sample analysrs are reported on a dry weight basis unless flagged with a
Note Calculations are performed before rounding,to avoid round -off errors In,calcufated, results
Shealy Environmental Services, Inc QC Data for Lot,Number KD21046
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Level'l Report v21
Page -44 of 60
Analytical'Laboratory
ICP -MS - LCS
Samplell) iKQ99302-002
Matrix•,Aqueous
Batch- 99302
Prep Method. 200 2
Analytical Method 200 8
Prep Date ,,04/22/2009 1930
'Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
Q DII % Rae
Limit
Analysis Date
Aluminum
t00
90
1 90
85-115
04/26/20091302
Arsenic
100
110
1 106
85-115
04/26/20091302
Barium
100
100
1 100
85-115
04/26/20091302
Beryllium
100
410
1 111
85-115
04/26/20091302
Boron
100
110
1 106
85-115
04/26/20091302
Cadmium
100
99
1 99
85-115
04/26/20091302
Chromium
100
96
1 196
85-115,
04/26/20091302
Cobalt
100
95
1 95
85-115
04/26%20091302
Copper
100
99
1 99
85-115
04/26/20091302
Iron
1000
890
1 89
85-115
04/26/20091302
Magnesium
1000
900
1 90
85-115
04/26/20091302
Manganese
100
97
1 97
85-115
04126/20091302
Nickel
100
99
1 99
85-115
04126/20091302
Selenium
100
100
1 103
85-115
04/29/20091512
Silver
100
97
1 97
85-115
04/26/20091302
Tin
100
96
1 96
85-115
04/26/20091302
Titanium
100
100
1 100
85-115
04/26/20091302
Zinc
100
110
1 115
85-115
04/26/20091302
POL - Practical quan nation Ilmit = The RPD between two OC columns exceeds 40% N - Recovery is out of criteria
NO = Not detected at or above the PQL J = Estimated result < POL and > MDC • - RPD�is out of arena
Where applicable ,all sod sample analysis are reported on a dry weight basis unless flagged with a'W'
Note Calculabonsare performed before rounding to avoid'round-off errors in calculated results
Shealy Environmental Services, Inc QC Data for Lot Number KD21046
106 Vantage Point Drive West Columbia SSC 29172 (803) 791-9700 Fax (803) 791/9111 WWW shealylab com Level 1 Report Q 7
Page 45 of 60
Analytical L"aboratory
ICP -MS,- LCSD,
Sample ID' KQ99302-003
Matrix: Aqueous
Batch 99302
Prep
Method
200 2
Analytical Method 200 8
Prep Date., 04/22/2009 1930
Spike
Amount
Result
% Rec
% RPD
Parameter
(ug/L)
(ug/L) Q
D11
% Rec
% RPD
Limit
Limit
Analysts Date
Aluminum
100
91
1
91
062
85-115
20
04/26/2009 1309
Arsenic
100
1;10
1
108
17
85-115
20
04/26/20091309
Barium
100
100
1
101
10
85-115
20
04/26/20091309
Beryllium
100
110
1
110
036
85-115-
20
04/26/2009 1309
Boron
100
110
1
109
20
85-115
20
04/26/2009 1309
Cadmium
100
99
1
99
021
85-115
20
04/26/2009 1309
Chromium
100
97
1
97
11
85-115
20
04/26/20091309
Cobalt
100
95
1
95
0 031
85-115
20
04/26/2009 1309
Copper
100
99
1
99
0020
85-115
20
04/26/20091309
Iron
1000
890
1
89
074
85-115
20
04/26/2009 1309
Magnesium
1000
910
1
91
063
85-115
20
04/26/2009 1309
Manganese
100
98
1
98
099
85-115
20
04/26/2009 1309
Nickel
100
100
1
100
061
85-115
20
04/26/2009 1309
Selenium
100
100
1
100
28
85-115
20
04/29/2009 1506
Sliver
100
98
1
98
040
85-115
20
04/26/2009 1309
Tin
100
96
1
96
010
85-115
20
04/26/20091309
Titanium
100
100
1
101
17
85-115
20
04/26/20091309
Zinc
100
120
1
115
035
85-115
20
04/26/2009 1309
PDL . Practical quantitation limit P - The RPD between two GC columns exceeds 40% N - Recovery is out of cnlena
ND = Not detected at or above the,PaL J = Estimated result < PQL and > MDL r RPDis out of cntena
Where applicable gall soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note Calculations are,performed before rounding to avoid round-offlerrors to calculated results
Shealy Environmental Services, Inc QC Data for,Lot Number KD21046
106 Vantage Point Drive West Columbia, SC 29172 (803) 791 9700 Fax (803) 791-9111 www shealylab com Level 1 Report G2 1
Inorganics Non-metals Quality Control Summary
Method Blank Sample Evaluation,
Parameter
Rre9�Ll, �m9/�l
:
Analysis Date
Flag
BOD
<0`20
20
04/22/09
BOD 1 1922
Seed Control'Factor Evaluation I
Parameter
Result
Acceptable I Analysis Flag
Limit I Date
BOO
1 0'7
0 6-1 0 1 04/22/09
Glucose Glutamic Acid Sample Evaluation
Amount Recovered
Acceptable
Analysis
Parameter
Flag
m /L
Limit
Date
BOD 1 1922
167 5-228 5
04/22/09
Sample ID
KD21046
Page 461of 60
Analytical Laboratory
Page 47 of,60
Analytical Laboratory
1
Inorganics Non-metals Quality Control Summary
Method Blank SampWEvaluation
Sample ID
Parameter Result POL (mg/L),
Analysis,
Flag
(mg/L)
Date
K021046
COD ND 1 10
1 04/24/09
Laboratory Control Sample / Laboratory Control Sample Duplicate Evaluation
RPD Control Limit
20
Amount
Amount
Amount
%
Parameter
Spike
Recovered
% Recovery
Recovered
Recovery
Control
RPD
Analysis
Flag
(mglL)
LCS
LCS
LCSD
LCSD
Limit
Date
m /L
m /L
COD
50
4823
96
5091
102
95-105
54
04/24/09
I
Page,48 of 60
Analytical Laboratory
Inorganics Non-metals Quality Control Summary
Method Blank Sample Evaluation
Parameter
Result
�
PQL (CU)
Analysis
Flag
(CU)
Date
Color
ND
50
04/22/09
a
Sample ID
K021046
SHEALY ENVIRONMENTAL. SERVICES, INC.
�
_L -
--
"
I
i
i
a i I I I
ILI
I
e l
N M w r n'
1 ' v
r
e
19 109
Page 49 of 60
Analytical Laboratory
U.
r R F
ILI
e
y
^,'IT
r I
I
L I
a
�
`1
47 �V,
n• 2
c I
I .°' i ,
,� v��`--.- _
I
i
C
j �,elF.� Flc., �_y`
�'
i_
I
�
I e I�r�_ �L' n.tC �`Q'♦
\d2^5 c n ` i 1,.
� L ,
I ;
�1 I
p 1
n � K� - j • ' '
'
'
_i`r
I
iZI
,q •• 1\_
QJ,
I
!
I ,.�, I
�`�_41 i1�._.l
.. .-_ ..w✓+j s. w. �,
_ ....
_.. I
.. .__' _..._ ..
r, �-j-✓'i W
Shealy Environmental Services, Inc
106 Vantage Point OnveF West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Level 7 Report Q 1
Page'50 of 60
Analytical Laboratory
SHEALY ENVIRONMENTAL SERVICE'S, INC.
.I ztt Fr', ro,.ricn .l c-- -0, Ir': a,,_ ' 1
Rc r wLrra.r ri 4i�a\'sC°J90,
"J n -p c Rcc_ r, (''Fecklist I SRC
r„c,leI In^;p.ctW .y date Oz! C' �)� f/�l r rr - _� a/o -- -- "
Lica t=_ c;+'F] 1'PS .__..J 1 :11: } 111I•t,r'il: fi"'P
:-als p7�e n •,n rhe cu. l_,' - - —
ywere ChN_tut IJl vie' unkroken' '
C onley^ TD,tcr t'I r, _c'-jp1
Oc
j 4_ (u1ernaWr111141ar1 .-.rl;ustk3ryt'es 4�
E nt_117d cl :o-_lIl t '�f `.4'e' ice �t l I Cr lie len
1 If,�cr.5r Is N,5 oT `,I^ 1 `- 13. tv), 3€..�..1�}ana`tlnn.r'rsl lcnyim Intrst,i'c ;.rv\.d..li
}
li (.JrlT)errp'an: of my :%1* t- a cee: ct! a it'1_ ^ 'v64 r tz) ec- llntliled'
npI ed h,. SRC plec.rie, note t sj,i.^'t rl 5 ,,ul,e
:cu -K,7 FMS a .ltl'_d :l
I,, 1 _I '� i , t, lllc+.l) 1*al L7. 3' ,oil rl sr ; p::�i+f-i `St'.ikL'4'..31_CaC ; ri.4rir r€I1
t`r' pe
).',-rc-.111liple 11_'5-i;led' ..�._..�_....._..,.,..,..,.- ,
TJ, 7`
_ _
11'a+Ce_1tCUl'_G Oo e fl[. til 19,ltiia�w'
5 11 t,�<l,crfnl;l,:'J tl,,Itl rpt #1,C ��l �€ jr s+t,: LILA I--
7((i N I 9r"PIC" ?.tT'\ C 1J€ t I: 6J.=_ _7n-. lug:;' _--=1s t..�t
1,11
D- .,I1 c u=acne, a( ol'itlfct-rn�nan taI) t, dp1;, -
.:3
cs �, rh'f- ; ', 4 �_- t i
i l.yC,ll cclr'a'ncrs4a,1\C 1.': jtYJC1,C' 17 t,.r (l1JlkIIC4./ n, tic.. p11
Y; :1 —i
���
a�' t, aicqu 1tL , alcl•� .olid e �.Gll hie' - - _r_
— ; _— — -
`v1c_c ail san.p:�_ r,-rlve�l \+•,t'na h_ I,d-, t, :r-tt _r ,'~ pr"--, \�,,'cna',� ,
14
lr Jr,rle; �o; :n c-•
-
- _s- --- ----
't cc -' :��, { + , _, ,
-- (-- ",cbunblc,illleqalytpcx
ti= _ tl c rc gut, e tee„ t n_r_wa roT ' I; ed r -n
tics "` 1 N`+
,t rr'rizr tldiwlLt;,r, 't,a'' U -k
I!
C_ Nt — j I
�(N�,
--
J t-
,\,•altnrtai,•
-r�
3 � es - i i+l%+ ' ' `
\acrc�l �}�:L.J,.3t,d`'� snlfenr.•ltrl�le: lee,_.,... �t ,l : {��'- _. .—
—
! I)
we,eal',ap_llcak+le'41Ti'iTC . _+ tnl l '�klalt^' ),�'�, 1"Tt PC, Welt
�
'-1 N. c71
i
( (i Mme L } and t:Ytc1L\'
i 21,
.Ih
'Yv t'r+'ZoII: '1,1€1 I: 1i 1,C-ait,Its &tc It tltd '. �_.'�'_,Ur N C`
Sampo Pr°,tr\dll,t11 (illl:'1`_ ;ll;pl t: 11'T`l S:TT, -,J rl:Jilp_L�3'CC`5t"t ilurl 1h31S1<S ill:' (
S -6151e1',
_ int t; w �3rll ie rr:� er,trc :,lth _ _. _ lt,5tl,1��,L1 I,aC-Ir Attt- me
l� *,{,iii [! •
'1 B ` 'r ,\: r s IYf ill€^hlC� %'C ft,i, 'n 11.1t]lJic£ --_ i
w ide Te C `!I _ h'+ 1_ f:„'?.P
-
'r3c,i,
.d ri'tt3 ., p: 1',lv 1_ Sil. ,>•rT:
l-e;tlie A:mit€l lalisen. if nl;tosttr\
tiQ �i I ll:Jr�i!_L I 't'a 1+'„fj •'i 1 'ti,1
Shealy Environmental Services Inc
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803)191-9111 www shealylab corn Level 1, Report v21
Page 51 of 60
Analytical Laboratory
Subcontracted Data
Laboratories arc
d rriemoef of The GEL Group Ir;,
May 09, 2009
Ms Brooke Montgomery
Shealy Environmental
106 Vantage Point Drive
Cayce, South Carolina 29033
Re Routine Analysis
Work Order 228472
Dear Ms 'Montgomery
Page 52,of 60
Analytical Laboratory
PO Box 30712 Charleston SC 79417
2040 Savage Road Charleston SC 29407
P 843 556 8171 F 843 7661178
WWW nal rnm
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on April 23, 2009 This,origmal data report has been prepared and reviewed in,accordance
with GEL"s standard operating procedures
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical
needs on ume,every time We trust that you will find everything in order and,to your sattsfact16n If you have
any questions„pleasd do not hesitate to call me at,(843) 556-8171, ext 4512
Sincerely,
�- O
Ann Skradski
Project Manager
Chaim of Custody 97554
Enclosures
Page 1 6f 9
problem solved
i
Page153 of 60
Analytical Laboratory
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 — (843) 556-8171 — www gel corn
Certificate of Analysis Report
for,
SESI001 Shealy Environmental Services, Inc
Client SDG 228472 GEL Work Order 228472
The Qualifiers in this report are defined as follows
* A quality control analyte recovery is outside of specified acceptance cntena
** Analyte is a surrogate compound
U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD
Where the analytical rmethodlhas been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard,unless qualthed on the Certificate of Analysis
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the -detection, limit ,
This data report has been prepared and reviewed,in accordance with GEL Laboratories LLC
standard operating procedures Please,direct any questions to your k roject Manager, Ann Skradskr
Reviewed by
Page 2 of 9
t
Page 54 of,60
Analytical Laboratory
GEL. LABORATORIES? LLC
2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www gel com
Certificate of Anatvjis
Company Shealy Environmental
1
Address 106 VantagePoint Drive
Cayce, South Carolina 29033
Report Date May 9, 2009
Contact Ms Brooke Montgomery
Project Routine Analysis
Client Sample ID
Allen SW,015
Proiect
SES100203
Sample 10'
228472001
Client ID'
SESI001
Matnx
Water
Collect,Ddte
20 -APR -09 12 20
Receive,Date
23 -APR=&
Collector
Client
- —
Parameter Qualifier Result,
Uncertainty DL
RL Units DF AnalystDate lime Batch Method
Rad;Gas,Flo* Proportional Counting
,GFPC, Gross A/8, ltqutd 'A s Received"
Alpha U ND
+7-2'01 380
500 pcgL
DXB5,04/29/09 '1929 861446 b
Beta 710
+/-293 430
500 Oct/L
GFPC, foial Alpha Radium, Liquid "As Received'
Total Radium U ND
+/-0399 0 616
100 pCi/L
DXM 04/30/09 1449 861843 2
2
RadjRadlum-226
Lucas Cell, Ra22'6„hgtitd 'As Received”
Radium -226 U ND
+/-0175 0407
l00 pOIL
KSD1,05/04/09 L545862440 3
The'followirig Analytical Methods were perfor' fled
_
Method, Description
Analyst Comments
I EPA, 900 0
2 EPA,900'1 Modified
3 EPA 903 1 Modified
Surrogate/Tracei `recovery Test
Result Nominal
Reco-very Acceptable Limits
Barium Caner GFPC, Total Alpha Radium, Liquid "As
1-19 (25%-=125%)
Received" I
Page 3nof 9
a
Page,55 of 60
Analytical Laboratory
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www gel cam
Page 4 of 9
QC Summary
Reuort Date.
May 9, 2009
Shealy Environmental
Page I of 3
106 Vantage Point Drive
Cayce, South Carolina
Contact- Ms Brooke Montgomery
Workorder. 228472
Parnmame
NOM
___Sample
ual QC _Umts
RPD%a
REC%
Range "1st
Date Time
Rad Gas Flow
Batch 861446
QC1201324740 `228438001 DUP
Alpha
U
0 221
U 0 335
pCi/L
000
N/A DXB5
04/29/09 19 27
+/-149
+/-161
Beta
105
124
pCt/L
164
(0%-20%)
+/-192
+/-230
QC 1201824743 LCS
Alpha
779
827
pCi/L
106
(75%-125%)
05/04/09 16 32
+/-835
Beta
261
258
pCt/L
989
(75%-125%)
+/-104
QC 1201824739 MB
Alpha
U 0 423
pCi/L
04/30/09 08 50
+/-0582
Beta
351
pCt/L
+/-109
QC1201824741 228438001 MS
Alpha
234
U
0 221
276
pCi/L
118
(757b -125%x,)
04/29/09 19 27
+/-149
+/-288
Beta
784
10'5
835
pCi/L
105
(75%a -1250/o)
+/192
+/-329
QC1201824742 228438001 MSD
Alpha
234
U
0 221
254
pCt/L
805
109
(0%-20%)
04/29/09 19 27
+/-149
+/-269
Beta
784
105
827
pCi/L
0 982
104
(0%-20%)
+/-192
+/-321
Batch 861843
QC1201825594 228472001 DUP
Total Radium
U
0 378
U 0 194
pCt/L
000
N/A DXM2
04/30/()9j450
+/-0 399
+/-0340
QC1201825596 LCS
Total Radium
271
214
pCt/L
788
(75%-125%)
04/30/09 14 50
+/-665
QC 1201825593 MB
Total Radium
U 00218
pCi/L
04/30/09,14 49
+/-0230
QC1201825591 228472001 MS
Total Radium
545
U
0 378
522
pCt/L
958
(75%-125%)
04/30/09 14 50
+/-0399
+/-144
Rad Ra -226
Batch 862440
j QC120i827009 223472001 our
Radium -226
U
-00565
U 0 316
pCi/L
000
N/A KSD 1
05/04/09 16 55
t
+/-0 175
+/-0293
Page 4 of 9
J
Page 56 of 60
Analytical Laboratory
GEL LABORATORIES, LLC
2040 Savage Road Charleston, SC 29407 - (843) 556;8171 -www gel com
OC Summary
Workorder: 228472
Page 2 of 3
Parmname ,_ __ _ _ _
--NOM— __Sample _Qual QC
Units RPD%
REC% Range Anlst
_Date Time_
Rad Ra•226
Batch 862440
QC1201827011 LCS
Radium -226
242 300
pCt/L
124 (75%-125%) KSDI
05/04/091655
+/-216
QC1201827008 MB
Radium -226
U 00804
pCi/L
05/04/09 16 M
+/-0157
QC1201827010 228472001 MS
Radium -226
121 U -00565 108
pCdL
895 (75%-125%)
05/04/09 16 55
+/-0175 +/-784
Notes
The -Qualifiers in this report are defined as follows
** Analyte is a surrogate compound
< Result is less than value reported
> Result is greater than value reported
A The TIC is a suspected aldol -condensation product
B For General Chemistry and Organic analysis the target analyte was detected.in the associated blank
BD Results are either below�the MDC or traces recoveryas low
C Analyte has been confirmed by GC(MS analysts
D Results are reported from -a diluted aliquot of the sample
F Estimated Value
H Analytical holding time was exceeded
J Value is estimated
M M if above MDC and less'than LLD
M Matrix Related Failure
N/A RPD or 41oRecovery limits do not apply
'ND Analyte concentratiomes not detected above the detection limit'
NJ Consult Case Narrative, Data Summary package., or Project Manager concerning this qualifier
R Sample results are rejected
IU Analyte wasianalyzed for„but not detected above the MDL, MDA, or LAD
UI Gamma Spectroscopy --Uncertain identification
X Consult Case+Narrative, Data,Summary package, or Project Manager concerning this qualifier
Y QC Samples were not spiked with this compound
^ RPD of sample and duplicate evaluated using +/-RL Concentrations are <5X the RL Qualifier Not Applicable for Radiochemistry
h Preparation or peesLrvation holding time was exceeded
Page 5 of 9
i
Page 57 of 60
Analytical Laboratory
1
GEL LABORATORIES UC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www gel com
0
QC Summary
Workorder 228472 Page 3 of 3
NOM_ Sa—e Qual QC Units RPD% REM_ Range Anlst__ Date Time
N/A mdtcates that spike recovcry,ltmits do not apply'whenlsanfple concentration exceeds spike conc Eby a factor of 4`or more
^ The,Relative'Percent Difference (RPD) obtained from the sample duplicate (DUP)tis evaluated against the acceptance criteria when the sample is greater than
five times`(SX) the contract required detection hrmt'(RL) In cases where either the sample or duplicate value is less than 5X the RL a control lint of +I- the
RL is used to evaluate the DUP result
* Indicates that a Quality Control parameter was not within specifications
For PS, PSD, and SDILT results, the values,hstedarc the measured amounts, not final concentrations
Where the analytical, method has been performe&under NELAP certification, the analysts has met all of the
requirements of the NELAC stdndard "unless qualified on the QC'Summary '
r
Page 6 of 9
4C:*.
Ln
S LO
O7
0
o
�
c
y
u
A
VN
0
1�
O
I �
�
O
E[
3
N
fi
2
R�
N
Wj
Ci
�
z
sm
L"t
d m
U
�v o
U_ r
Mf
o
0
3
N Co
Ir
�> C O
to Z,
�
1 +r t6 t6
LL
i"
g
o_
W y cpS
z
g c a
❑
m E
m
C
a
V1J }
O? Er,
O
¢ ?r
N 1
�
o
J
�7
v
o �
j mm
U
� �
5 V 0
@
Z O
W m Z
m
1
ti
U�
O
t
�
z
a
2
O [i
4
m
R
c
A
VN
mm$
C
1�
O
m �
E
�
O
E[
N
Ilk
2
Ci
sm
L"t
d m
e7of5
Page 58 of 60
Analytical Laboratory
A
or1�No"
IL
E[
N
Ci
d m
�v o
a
�
g
z
❑
m E
m
C
a
V1J }
cc
�-
¢ ?r
N 1
�
o
J
�7
v
o �
j mm
U
� �
1�
ti
1E
YO
�
v
m
(i
a
❑
s
y
�
rn
Q. 01
1—
N
co
U
Page 59iof 60
Analytical laboratory
ILaboratorieS LLC SAMPLERECEIPT & REVIEW FORM
Client:E j rd,SDG/ARCOC/WorkOrder:
Received•By: Date Received: O -t"
Suspected Hazardlnformation,;
o *If Counts >,x2iarea back und on samples not marked"radioactive", contact
z the Radiation Safety Group of further investigation.
COC1S1imples marked as radioactive?
Maximum Counts Observed*-
Classified Radioactive 11 or III by_R50T
_ o dri
COC/Sampfts,tnarked containing PCBs? _
Shipped ds a DOT Hazardous?_
Class'Shipped. UN#-
Samples identified as Foreign Soil
Sample,Receipt Criteria
z x
Comments/Qualifiers (Required for Non -Conforming Items)
Gtirle Applicable
I
Shipping containers received intact and
seals broken damaged container leaking container other (describe)
sealed?
2
Samples requiring cold preservation
Preservation Method.
ice bags blue ice dry ice non other (describe)
within 0:5 6 deg C?
y c
3
Chain of custody documents included
with shipment?
Circle Applicable.
4
Sample containers intact and sealedy
seals_broken damaged contamer leaking container other (describe)
Sample IDs, containers'affected and observed pH
5
Samples requiring chemical
preservation =at proper pH'?
If Preservation added, LoW O
VOA vials free of headspace (defined as
sample ID's and containers affected.
6
<6mm,bubble)?
7
Are Encore containers
/
(If yes, immediately deliver to,Volahles laboratory)
present
US and tests affected.
S
Samples receivedwithin holding time'+
Sample ID's on COC match ID's on
sample ID's and containers affected.
9
bottles
Date & time on COC witch date & time
1
sample m's affected
10
on bottles
no �c_ o f, on w �
Number of containers received match
sample m's affected.
11
number indicated on COC?
12
COC form is properly signed in
rehnquishe,dheceived sections?
Comments.,
1� a�-�tsz3a �oo�otiLk
PM (or PMA) review Initials )VII Date `r.! L_X_> ' `, f
1
Page,60 of 60
Analytical Laboratory
List of current GEL Certifications as�of,09 May 2009
State
Certification
Arizona
AZ0668
Arkansas
88-0651
CLIA
California — NELAP
42D0904046
0115 ICA
Colorado
GEL
Connecticut
PH -0169
Dept of Navy
NFESC 4.13
EPA Region 5
WG -151
Flonda — NELAP
Georgia
E87456
E87156 (FUNELAP)
_ Georgia DW
967
Hawaii
N/A
ISO 17025
256701
Idaho
-Illinois — NELAP
SC00012
200029
Indiana
C—SC-01
Kansas — NELAP
E-10332
Kentucky
90129
Louisiana — NELAP
030_46_
Maryland
270
Massachusetts
M—SC012
Nevada
SC00012
New Jersey — NELAP
SC002
New Mexico
FL NELAP E87156
New York — NELAP
11501
North Carolina
233
North Carolina DW
45709
Oklahoma
9904
Pennsylvania — NELAP
68-00485
South Carolina
10120001/10120002
Tennessee
TN 02934
Texas — NELAP
T104704235-07B—TX
US -Dept of Agriculture
S-52597
_ Utah — NELAP
GEL
Vermont
VT87156_
Virginia
_ 00(51
Washington
_ C1541
Page 9 of 9