Loading...
HomeMy WebLinkAboutIMP Update November 2019 - Compiled�DUKE � ENERGY. November 26, 2019 North Carolina Department of Environmental Quality Division of Water Resources Attn: Mr. Rick Bolich 1636 Mail Service Center Raleigh, NC 27699-1636 Subject: Optimized Interim Monitoring Plans (IMP) — Update Dear Mr. Bolich: 410 S. Wilmington Street. Raleigh, NC 27601 Mailing Address Mail Code NC 15 Raleigh, NC27601 919-546-7863 Duke Energy (Duke) submits updates to the optimized Interim Monitoring Plans and requests approval from the North Carolina Department of Environmental Quality (DEQ) by end of the yearsuch that sampling can continue starting January 2020. Duke understands DEQ had questions regarding groundwater sampling for speciation and dissolved constituents. The purpose of these updates is to remove that confusion along with modify monitoring well list due to abandonments and/or installs recently completed. The enclosed Tables 2.1 through 2.14 identify which wells are sampled for which constituents and whether they are sampled semi-annually or quarterly. Duke will submit Table 3 to DEQ at a later date as our internal sampling team is finalizing the 2020 schedule. Table 3 will identify what months during a quarter sampling is to take place along with when the quarterly data update to DEQ will be submitted (end of month). If you have any questions or need any clarification regarding the information provided, feel free to contact me at john.toepfer@duke-energy.com or at 919-546-7863 at your convenience. Respectfully submit d, hn Toepfer, P.E. Lead Engineer, Duke Energy EHS CCP Waste & Groundwater Programs cc/att (via email): Mr. Eric Smith and Steve Lanter— DEQ Central Office Ms. Brandy Costner— Mooresville Regional Office Ms. Shuying Wang— Winston-Salem Regional Office Mr. Ted Campbell — Asheville Regional Office Mr. Eric Rice — Raleigh Regional Office Mr. Will Hart —Washington Regional Office Mr. Geoff Kegley —Wilmington Regional Office Mr. Kent White — Fayetteville Regional Office Mr. Ed Sullivan and Bryan Moeller - Duke Energy November 26, 2019 Page 2 Ms. Kathy Webb — SynTerra Corp. Attachments: Tables 1—Summary of Analytical Parameters for Newly Installed Wells Table 2.1—Summary of Wells, Frequency & Parameters — Allen Table 2.1A—Additional Source Area Wells - Allen Table 2.2—Summary of Wells, Frequency & Parameters —Asheville Table 2.3 — Summary of Wells, Frequency & Parameters — Belews Creek Table 2.3A - Additional Source Area Wells — Belews Creek Table 2.4 — Summary of Wells, Frequency & Parameters — Buck Table 2.5 — Summary of Wells, Frequency & Parameters — Cape Fear Table 2.6 — Summary of Wells, Frequency & Parameters — Cliffside Table 2.6A - Additional Source Area Wells - Cliffside Table 2.7 — Summary of Wells, Frequency & Parameters — Dan River Table 2.8 — Summary of Wells, Frequency & Parameters — HF Lee Table 2.9 — Summary of Wells, Frequency & Parameters — Marshall Table 2.10 —Summary of Wells, Frequency & Parameters — Mayo Table 1.10A - Additional Source Area Wells - Mayo Table 2.11— Summary of Wells, Frequency & Parameters — Riverbend Table 2.12 — Summary of Wells, Frequency & Parameters — Roxboro Table 2.12A - Additional Source Area Wells - Roxboro Table 2.13—Summary of Wells, Frequency & Parameters —Sutton Table 2.14 — Summary of Wells, Frequency & Parameters — Weatherspoon TABLE 1 IMP Optimization Summary of Analytical Parameters for Newly Installed Wells and 1st Semi -Annual Event (to begin Q1 2020) For each of Duke Energy's 14 North Carolina facilities, new wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily. After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. A summary of analytical parameters to include under this criteria is provided below. SUMMARY OF ANALYTICAL PARAMETERS FOR NEWLY INSTALLED WELLS AND 1st SEMI-ANNUAL SAMPLING EVENT (SITE -WIDE) Minimum CAMA Parameters per Q4 2018 IMP (22) Additional Voluntary Parameters (4) [Total and dissolved^ metals] Aluminum^ Iron Lead Fluoride Nitrate + Nitrite Antimony^ Lithium^ Phosphorus, dissolved only^ Arsenic^ Manganese Barium^ Mercury^ Beryllium" Molybdenum^ Boron Nickel^ Cadmium" Selenium^ Chromium, total^ Strontium^ Chromium, hexavalent Thallium^ Cobalt^ Vanadium^ Copper Zinc^ ^Dissolved metals will be analyzed once per year during the 1st semi- annual sampling event. ^Dissolved metals will be analyzed once per year during the 1st semi-annual sampling event. Additional Water Quality Parameters (13) Additional Voluntary Field Parameters (7) Alkalinity (CO3/HCO3) Sodium, total Sulfate Dissolved Oxygen (DO) Redox Potential (Eh) Specific Conductance Calcium, total Oxidation -Reduction Potential (ORP) Chloride Sulfide Temperature Magnesium, total Total Dissolved Solids (TDS) pH Turbidity Potassium, total Total Organic Carbon (TOC) Total Radium Total Uranium (233+234+236+238) (226+228) Total Suspended Solids (TSS) Table 2.1- Allen Wells for Quarterly Monitoring (36) AB-10BR*/ BRL* AB-40SS* / D* AB-41SS* / D* AB-42AP* / SS* / D* AB-43AP* / SS* / D* AB-44AP* / SS* / D* CCR-26S* CP-3S*/D* CP-5S*/D* CP-6S*/D* GWA-3BRL* GWA-4BRL* GWA-5BRL* GWA-6BRL* GWA-27S* / D* GWA-28S* / D* / BR* GWA-29S* / D* / BR* GWA-30S* / D* Allen Steam Station - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2020) Modification - November 2019 Wells for Semi -Annual Monitoringt (123) AB-04S / D / BR CP-2S/D AB-06R CP-4S/D AB-09S / D CP-6BR AB-10S / D GWA-01S / D / BR AB-12S / D GWA-02S / D AB-13S / D GWA-03S / D / BRA AB-14D / BR GWA-04S / D / BR GWA-05S / D / BRA AB-20S / D AB-21S / SL / SS / D** / BRL GWA-06S / DA / BRA AB-22S / D / BR / BRL GWA-07S / D AB-24S / SL / D** / BR GWA-08S AB-25S / SL / SS / BRU** / BR** GWA-09S / D / BR AB-26S / D GWA-14S / DA** AB-29SS GWA-15S / D AB-30S GWA-16S / D AB-32S / D GWA-19S / D AB-33S / SS / D1 GWA-21S / DA / BR AB-34S / D GWA-22S / D AB-35S / PWS / D** / BR GWA-23S / D AB-36S / D GWA-24SA / D / BR AB-37S / D GWA-26S / D AB-38S / SS / D / BR AB-39S / D BG-1S / DA / BR BG-2S / D / 2BRA2 BG-3S / D BG-4S / D / BR 1st semi-annual sampling event to be analyzed for parameters in Table 1. CCR-16BR CCR-26D / BR CP-1S/D Optimized Quarterly & Semi -Annual Parameters for "non -new wells" (36) 2018 CSA Update COls Water Quality Parameters Field Parameters (Total and dissolvedA metals) (Total and dissolvedA metals) Antimony^ ---------------------------------- Manganese ------------------------ AluminumA ------------------------------------------ Dissolved Oxygen (DO) ---------------------------- Arsenic^ MolybdenumA Alkalinity (CO3/HCO3) Oxidation-Reduction ---------------------------------- Beryl JiUMA ---------------------------------- ------------------------ NickelA ------------------------ ------------------------------------------- Calcium ------------------------------------------ Potential (ORP) ------------------------------ Boron A Selenium^ Chloride pH ---------------------------------- CadmiumA ------------------------ StrontiumA -------------------- ---------------------- Fluoride ---------------------------- Redox Potential (Eh) ----------- ------------------------------------------------ Chromium (total)^ ---------------------------------- Sulfate ------------------------ ------------------------------------------ Magnesium ------------------------------------------ ---------------------------- Specific Conductance ---------------------------- Chromium (hexavalent) ---------------------------------- Thallium^ ------------------------ Nitrate + Nitrite ------------------------------------------ Temperature ----------------------------- Coba ItA Total Dissolved Potassium Turbidity ---------------------------------- Iron Solids (TDS) ------------------------------------------ Sodium ---------------------------- ---------------------------------- Lithi UMA ------------------------ Vanadium^ ------------------------------------------ Total Organic Carbon (TOC) ---------------------------- A Dissolved metals will be analyzed once per year during the 1st semi-annual sampling event. Water Level Only (23) AB-01R AB-02/D AB-05 AB-06A AB-11D AB-23S / BRU AB-27S /D / BR AB-28S / D AB-29S / SL / D AB-30D AB-31S GWA-08 D GWA-17S / D GWA-18S / D Comprehensive water level sweeps will occur semi-annually and will include wells in Quarterly, Semi -Annual, and Water Level Only lists. To Be Replaced No well replacements planned at this time To be Abandoned (1) GWA-6D Discontinued Parameters (10) Proposed (non -COI) Constituents to be Discontinued Barium Copper Lead Mercury Nitrate as N Total Radium (226+228) Sulfide Total Suspended Solids (TSS) Total Uranium Zinc Notes: IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment Cols = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ= North Carolina Department of Environmental Quality tSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace. ** Denotes well was sampled for Boron and Sulfate only in historic versions of the IMP due to elevated pH. Respective well is proposed to remain a Boron- and Sulfate -only sample if location is proposed to remain in the IMP. i Well re -development has historically been conducted with favorable results. Recent results indicate pH values are increasing. Further well re -development will be conducted to re- establish groundwater quality in the monitoring well. Wells in bold are ash basin wells that may become restricted in 2020 at any time due to stability concerns from decanting/construction activities. Data submittals will identify any wells that were not sampled as a result. Table 2.1A - Allen Allen Steam Station - Additional Source Area Wells Wells for Quarterly Monitoring (12) GP-1S/D G P-2S/D G P-3S/D G P-4S/D G P-SS/D G P-6S/D Summary of Wells, Frequency, & Parameters (to begin Q1 2020) Modification - November 2019 Wells for Semi -Annual Monitoringt (0) AL Quarterly & Semi -Annual Parameters for Additional Source Area Wells Additional source area wells will be analyzed for parameters in Table 1. Notes: IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COls = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ = North Carolina Department of Environmental Quality +Semi -Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. Table 2.2 - Asheville Wells for Quarterly Monitoring (32) CB-6 MW-9D1 CB-7 MW-9BR1 CB-81 M W-16A1 CB-8BR1 MW-16D1 CCR-101BR1 MW-16BR1 CCR-102S1 MW-16BRL1 CCR-102D1 MW-16BRLL1 CCR-103 D M W-17A1 CCR-103BR MW-17BRL1 CPA-5D*/BR* MW-20BR1 CPA-6D*/BR* MW-20BRL1 EXT-011 EXT-02 EXT-A GW-21 MW-5D MW-5BR M W-8S1 M W-9S1 Asheville Steam Electric Plant - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2020) - November 2019 Wells for Semi -Annual Monitoringt (57) AMW-03B1 CCR-105BR MW-18BRL AS-5BR** GW-11 MW-20A CB-11 GW-11) MW-24S1 CB-1D1 GW-1BR MW-25S CB-3R1 GW-31 MW-25BR CB-41 GW-41 MW-25BRL CB-4B1 MW-31)1 MW-26S CB-5 MW-6S1 MW-26BR1 CB-9 MW-61)1 P-103 CB-9SL MW-6BR1 PZ-17S1 CB-9BR MW-101 PZ-17D1 CCR-100SL1 MW-11 PZ-17BRL CCR-100BR1 MW-11D PZ-19 CCR-100BRL1 MW-13D CCR-104D1 MW-13BR CCR-105D1 MW-15A1 CPA-1D2/BR2 MW-15D1 CPA-21)2/BR2 MW-15BRL1 CPA-3D2/BR2 MW-18D CPA-4D2/BR2 MW-18BR1 1st semi-annual sampling event to be analyzed for parameters in Table 1. Optimized Quarterly & Semi -Annual Parameters for "non -new wells" (36) Water Quality Parameters (Total and dissolved^ metals) IL Field Parameters Alkalinity (CO3/HCO3) Fluoride Strontium^ Sulfate Dissolved Oxygen (DO) Antimony^ Iron Oxidation -Reduction Potential (ORP) Arsenic^ Lithium^ Thallium^ Beryllium^ Magnesium Total Dissolved Solids (TDS) pH Boron Manganese Total Organic Carbon (TOC) Redox Potential (Eh) Cadmium^ Molybdenum^ Total Radium' (226+228) Specific Conductance Calcium Nickel^ Vanadium^ Temperature Chloride Nitrate+Nitrite Turbidity Chromium (total)^ Potassium ^Dissolved metals will be analyzed once per year during the 1st semi-annual sampling event. Chromium (hexavalent) Selenium^ Cobalt^ Sodium Water Level Only (25) MW-14BR CB-1BR/BRL MW-23DU CB-2 MW-23DL CB-81) MW-23BR GW-5 AMW-113 MW-7BR ABMW-11BR MW-15BR AMW-2A MW-19BR AMW-213 P-102 APZ-30 EXT-D B-1 MW-8BR B-1-A MW-26BRL B-2 AS-5BRL Comprehensive water level sweeps will occur semi- annually and will include wells in Quarterly, Semi - Annual, and Water level Only lists. To Be Installed (4) CPA-5D/BR and CPA-6D/BR planned to be added as new wells downgradient of the coal pile in 2019. To be Abandoned (4) CPA-2D/BR and CPA-4D/BR are planned to be abandoned in early 2020. Discontinued Parameters (2) Proposed (non -COI) Constituents to be Discontinued Nitrate as N Total Uranium IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COls = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ= North Carolina Department of Environmental Quality tSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace. ** Denotes well with high pH. If well is on quarterly or semi annual sampling, sampled for Boron and Sulfate only due to elevated pH. Respective well is proposed to remain a Boron- and Sulfate -only sample if location is proposed to remain in the IMP. However, if the pH improves with redevelopment those wells will be sampled for the full suite of Cols and water quality parameters proposed herein IF pH is within compliance. 1 Wells to be sampled for total radium, in addition to water quality parameters noted. Wells in vincinity of coal pile. Samples from these wells will be analyzed for parameters on Table 1. Table 2.3 - Belews Creek Belews Creek Steam Station - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2020) Modification - November 2019 LWells for Quarterly Monitoring (38) �jj AB-2BR* GWA-18SA AB-4S/SAP/LowerAsh/D/BR/BRD GWA-19SA/D AB-6SL GWA-20SA2/D' A113-7S GWA-21S/D CCR-2S2/D GWA-27S/D' CCR-13S*/D*/BR* LRB-01S/D/BR EXOB-01 LRB-02S/D/BR EXOB-02 MW-104BRA*' GWA-01S MW-200BR GWA-10S1 M W-04 GWA-11S/D Replaced (1) MW-104BR (replaced by MW- 104BRA) Wells for Semi -Annual Monitoringt (52) AB-1BR GWA-27BR AB-2Sz/D GWA-30S/D AB-3 D GWA-31S/D BG-01S2/D GWA-32S/D BG-02S/D/BRA GWA-3S2 BG-03S/D GWA-6S GWA-01 D/BR* * GWA-7SA GWA-10DA GWA-8S/D GWA-16S/DA/BR** GWA-9BR GWA-17S MW-03 GWA-18D M W-20OS/D GWA-19BR** MW-202S/D/BR' GWA-20BR MW-204D GWA-22S/D 1st semi-annual sampling event to be analyzed for parameters in Table 1. GWA-23S/D GWA-24S2/D/BR GWA-25BR GWA-26S/D/BR bandoned (2) CP 4BR(10/24/19) SFMW-4BR (10/24/19) Optimized Quarterly & Semi -Annual Parameters for "non -new wells" (38) 2017 CSA Update COls Water Quality Parameters Field Parameters (Total and dissolved^ metals) (Total and dissolved^ metals) Antimony -------------------------------------- Iron ------------------------------------ Aluminum^ -------------------------------------- Dissolved Oxygen (DO) ---------------------------------------- Arsenic^ Manganese^ Alkalinity (CO3/HCO3) Oxidation -Reduction Potential -------------------------------------- Barium^ ------------------------------------ Molybdenum^ -------------------------------------- Calcium (ORP) -------------------------------------- Beryllium^ -------------------------------------- ------------------------------------ Selenium^ ------------------------------------ -------------------------------------- Fluoride -------------------------------------- ---------------------------------------- pH ----------------------------------------- Boro Strontium^ Lithium^ Redox Potential (Eh) -------------------------------------- Cadmium^ -------------------------------------- ------------------------------------ Sulfate ------------------------------------ -------------------------------------- Magnesium -------------------------------------- ----------------------------------------- Specific Conductance ----------------------------------------- Chloride -------------------------------------- Total Dissolved Solids (TDS) ------------------------------------ Nitrate + Nitrite -------------------------------------- Temperature ----------------------------------------- Chromium (total)^ Thallium^ Potassium Turbidity -------------------------------------- Chromium (hexavalent) ------------------------------------ Vanadium^ ---------- ---- --------------- --------- Total Radium' (226 + 228) ----------------------------------------- ------------------------------------------ -------------------------------------- Coba ItA ------------------------------------ -------------------------------------- Sodium -------------------------------------- Ca- Total Organic Carbon TotalOrganic ----------------------------------------- Dissolved metals will be analyzed once per year during the 1st ---- ---T --- i --------- ----------------------------------------- semi-annual sampling event. Total Uranium ----------------------------------------- (233+234+236+238) LWaterevel Only (36) AB-1S/D/BRD3 AB-2BRD3 AB-3S/BR3 AB-4SL AB-5S/SL/D AB-6S/D AB-7D AB-8S/SL/D AB-9S/D/BR/BRD GWA-2S/D GWA-3 D GWA-6D GWA-7D GWA-9S/D GWA-17D MW-104S/D MW-201D/BR MW-203S/D/BR M W-204S Comprehensive water level sweeps will occur semi- annually and will include wells in Quarterly, Semi - Annual, and Water Level Only lists. Discontinued Parameters (10) 1 I Proposed (non -COI) Constituents to I be Discontinued Copper -------------------------------------------------- Lead -------------------------------------------------- Mercury -------------------------------------------------- Methane -------------------------------------------------- Nickel -------------------------------------------------- Nitrate as N -------------------------------------------------- Phosphorus Sulfide Suspended Solids (TSS) ----------------------Zinc--- -------- = Interim Monitoring Plan CSA = Comprehensive Site Assessment Cols = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ= North Carolina Department of Environmental Quality tSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace. ** Denotes well with high pH. If well is on quarterly or semi annual sampling, sampled for Boron and Sulfate only due to elevated pH. Respective well is proposed to remain a Boron- and Sulfate -only sample if location is proposed to remain in the IMP. However, if the pH improves with redevelopment those wells will be sampled for the full suite of Cols and water quality parameters proposed herein IF pH is within compliance. 1 -Wells to be sampled for total radium and total uranium, in addition to water quality parameters noted. If results are less than the Federal MCL, revaluation may indicate historical exceedances are anomalous and a revision to the routine monitoring plan will be considered. Background well cluster MW-202S/D/BR will also be included in semiannual sampling of total radium and total uranium for ongoing comparative purposes. z - Wells have at times been been historically dry (i.e. no available water for sampling). Collect water level and sample if suffcient water for sampling. 3 - Low flow wells (0.02-0.03 gpm drawdown sampling range) with high pH (11.1- 12.6 S.U.) Wells in bold are ash basin wells that may become restricted in 2020 at any time due to stability concerns from decanting/construction activities. Data submittals will identify any wells that were not sampled as a result. Table 2.3A - Belews Creek Belews Creek Steam Station - Additional Source Area Wells Summary of Wells, Frequency, & Parameters (to begin Q1 2020) Modification - November 2019 Wells for Quarterly Monitoring (33) 1i CCR-FGD-11S/D GP-11BR CCR-FGD-12S/D GP-12BR CP-1S/D/BR GP-13S/D/BR CP-2S/D/BR CP-3S/D/BR CP-4S/D CP-5S/D/BR CP-6S/D/BR CP-7S/D/BR CP-8BR G P-10S/D/B R Wells for Semi -Annual Monitoringt (0) Quarterly & Semi -Annual Parameters for Additional Source Area Wells Additional source area wells will be analyzed for parameters in Table 1. Notes: IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COls = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ= North Carolina Department of Environmental Quality tSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. Table 2.4 - Buck Wells for Quarterly Monitoring (31) AB-04S AB-05S AB-09BRA1 BG-01 DA CPA-1S*/D*/BR* CPA-2S*/D*/BR* CPA-3S*/D*/BR* CPA-4D*/BR* CPA-5S*/D*/BR* CPA-6BR* GWA-01Sz GWA-09SA */ DA*/ BRAA* GWA-10S / D GWA-14D GWA-15BR3 GWA-19BR* M W-01 D4 M W-08 B RA5 MW-11BRL Buck Steam Station - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2020) Modification - November 2019 Wells for Semi -Annual Monitoringt (62) AB-04SL GWA-18S / DA AB-05SL GWA-19S / D AB-06BRU GWA-20S2 / D AB-07S / BRU GWA-22D AB-8S6 / BRU M W-03S / D AB-09S' / BRUA M W-04S / D BG-01S / BRA MW-5S / D BG-02S / D M W-06BR BG-03S / BRU MW-07S / D GWA-01D MW-08S / D GWA-02S / BRA / BRU MW-09S / D GWA-7S / D MW-11S / D / BR GWA-8D MW-12S / D GWA-11S / D MW-13D GWA-12S / BRU GWA-13SR2 / D GWA-14S / D GWA-15S / D GWA-16S5 / D/ BR GWA-17S 1st semi-annual sampling event to be analyzed for parameters in Table 1. Optimized Quarterly & Semi -Annual Parameters for "non -new wells" (34) Water Quality Parameters (Total and dissolved^ metals) Field Parameters Alkalinity (CO3/HCO3) Chromium (hexavalent) Phosphorus, dissolved Potassium Dissolved Oxygen (DO) Aluminum^ Cobalt^ Oxidation -Reduction Potential (CRP) Antimony^ Fluoride Selenium^ Arsenic^ Iron Sodium pH Barium^ Lithium^ Strontium^ Redox Potential (Eh) Boron Magnesium Sulfate Specific Conductance Calcium Manganese Thallium^ Temperature Chloride Nickel^ Total Dissolved Solids (TDS) Turbidity Chromium (total)^ Nitrate + Nitrite Vanadium^ Dissolved metals will be analyzed once per year during the 1st semi-annual sampling event Water Level Only (7) AB-04BRU AB-05 B R U GWA-06S GWA-14BR M W-01S M W-06 D M W-06S Comprehensive water level sweeps will occur semi-annually and will include wells in Quarterly, Semi - Annual and Water Level Only lists. To Be Replaced (3) AB-4BRL BG-1DA GWA-14D To be Abandoned (0) No well abandonments planned at this time. Discontinued Parameters (14) Proposed (non -COI) Constituents to be Discontinued Beryllium Cadmium Copper Lead Mercury Methane Molybdenum Nitrate as N Total Radium (226 + 228) Sulfide Total Organic Carbon (TOC) Total Suspended Solids (TSS) Total Uranium Zinc Notes: IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COls = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ= North Carolina Department of Environmental Quality tSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace. 1 Quarterly until antimony and chromium have stabilized. 5 Monitor sulfate and TDS closely Z Monitor chromium closely 6 Monitor barium closely 3 Quarterly due to pH and TDS 7 Monitor turbidity when sampling and if necessary do additional development to ensure representative samples are being collected. 4 Erratic boron concentration; sample quarterly until stabilized Wells in bold are ash basin wells that may become restricted in 2020 at any time due to stability concerns from decanting/construction activities. Data submittals will identify any wells that were not sampled as a result. Wells for Quarterly Monitoring (22) CPBG-1S* / BR* CP-2S* / BR* CP-3S* / BR* CP-4S* / BR* CP-5S* / BR* CP-6S* / BR* CP-7S* / BR* CP-8S* / BR* CP-9S* / BR* CP-10S* / BR* CP-11S* / BR* Table 2.5 - Cape Fear Cape Fear Steam Electric Plant - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2020) Modification - November 2019 Wells for Semi -Annual Monitoringt (64) ABMW-01/S/BR MW-17SU / SL/ BR ABMW-02SU / SL MW-21SU / SL / BR ABMW-03 / SR / BR MW-22S / BR ABMW-04 / S MW-23S / D / BR ABMW-05S / BR MW-24S / BR BGMW-04 MW-25BR / BRL / BRLL BGTM W-04 PZ-01 CMW-01 PZ-02 CMW-02 PZ-03S / D CMW-03 PZ-04 CMW-05 R PZ-05 CMW-06 PZ-06 CMW-07 PZ-08 CMW-08 CTM W-01 CTM W-02 CTM W-07 CTM W-08 MW-06BR 1st semi-annual sampling event to be analyzed for parameters in Table 1. MW-09 / BR MW-10 / D / BR / BRL MW-11 MW-12 / BR MW-15SU / SL / BR MW-16S / BR Optimized Quarterly & Semi -Annual Parameters for "non -new wells" (35) Water Quality Parameters Field Parameters (Total and dissolved^ metals) Alkalinity (CO3/HCO3) Chromium (total)^ Potassium Dissolved Oxygen (DO) ---------------------------------- Alumin UMA ---------------------------------- Chromium (hexavalent) ------------------------------------------ Selenium^ -------------------------------- Oxidation -Reduction ---------------------------------- Antimony^ ---------------------------------- ---------------------------------- Cobalt^ ---------------------------------- ------------------------------------------ Sodium ------------------------------------------ Potential (ORP) ------------------------------- Arsenic^ Iron Strontium^ pH ---------------------------------- Bari ---------------------------------- ---------------------------------- Magnesium ---------------------------------- ------------------------------------------ Sulfate ------------------------------------------ ------------------------------- Redox Potential (Eh) ------------------------------- Beryl ---------------------------------- Manganese ---------------------------------- Thallium^ ------------------------------------------ Specific Conductance ------------------------------- Boron Molybdenum^ Total Dissolved Solids (TDS) Temperature ---------------------------------- Calcium ----------------------------- ---- ---------------------------------- Nickel^ ---------------------------------- ------------------------------------------ Total Organic Carbon ------------------------------------------ ------------------------------- Turbidity ------------------------------- Chlorid-e Nitrate + Nitrite Vanadium^ ^ Dissolved metals will be analyzed once per year during the --------------- --------------------------- Zinc^ ------------------------------- 1st semi-annual sampling event. ------------------------------------------ ------------------------------- Water Level Only (10) ABMW-5 MW-13 MW-18S MW-19S MW-20S / BR MW-5BRR PZ-07 PZ-09 PZ-10 Comprehensive water level sweeps will occur semi-annually and will include wells in Quarterly, Semi -Annual and Water Level Only lists. To Be Replaced No well replacements planned at this time ABMW-01/S/BR PZ-6 Discontinued Parameters (9) Proposed (non -COI) Constituents to be Discontinued Cadmium Copper Lead Mercury Nitrate as N Total Radium (226+228) Sulfide Total Suspended Solids (TSS) Total Uranium Notes: IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COls = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ = North Carolina Department of Environmental Quality tSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace. Wells in bold are ash basin wells that may become restricted in 2020 at any time due to stability concerns from decanting/construction activities. Data submittals will identify any wells that were not sampled as a result. Wells for Quarterly Monitoring (77) AB-1S'/D' GWA-32D2 / BR2 AB-7S*/BRU*/BR* GWA-33S"' / D1,2/ BR1,2 AB-8S*/I*/BRU*/BR* GWA-38S2/D2 AS-1D' GWA-395* AS-2S' GWA-405* AS-7D' / BRB* GWA-425 AS-8BR* GWA-43S2 / D2 AS-9D*/BR* GWA-4452 / D'/ BR CCR-IB-3S2 / D2 /BR2 GWA-545/D/BRO CLMW-2 GWA-56S2 / D2 CLMW-3S'/D' GWA-575*/BRU*/BR* GWA-2BRA'* GWA-58S*/BRU*/BR* GWA-10S2/D2 GWA-59D*/BR* GWA-11S''2/ BRU''2/BR2/BRL' GWA-62BRU*/BR* GWA-13BR2 GWA-63S*/BRU* GWA-1452 / D'/ BR IB-752/D' GWA-20D' MW-20D' GWA-21S'/BRU'/BR' MW-23S2 / D2 / DR2 GWA-22S' U5-2S-SLB* Table 2.6 - Cliffside Cliffside Steam Station - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2020) Modification - November 2019 Wells for Semi -Annual Monitoringt (170) AB-1BROR' GWA-113RU IB-65/D AB-25'/D'/BRO' GWA-2S'/ BRU' MW-115'/DA/BRO/BRL AB-3S'/SL'/MA15/I'/BRUA/BR/BRA GWA-3D' MW-2DA AB-4S'/SL'/D/BR GWA-4S'/ D' MW-85'/ D AB -SS'/ BRU / BR GWA-5S / BRU MW-105 / D AB-6S'/ D / BR GWA-12S / BRU MW-20DR' AS-1SB' GWA-20S'/BR' MW-21D/BR AS-2D'/ BR GWA-21BRL MW-22BR / DR AS-313RU GWA-22BRU MW-24D'/ DR' AS-4S/D GWA-23D MW-25DR AS-5S / BRU / BR GWA-24S / D / BR MW-30S'/ D' / DA' AS-65 / D / BRA GWA-25S MW-32S' / D' / BR' AS-7S'/I/BRL GWA-265 MW-34S / BRU AS-8S/D GWA-27DA'/ BR' MW-36S / BRU BG-1S'/ D'/BRA GWA-285 / BRU / BR MW-38S'/ D'/ BR' CCR-IB-15 / D GWA-29D'/ BRA MW-405 / BRU CCR-U5-3S' / D' GWA-30S / BR MW-42S / DA CCR-U5-4S / D / BR GWA-31D / BRA U5-1S / D CCR-3BR GWA-34S/BR U5-2S-SLA' / D'/ BR' CCR-6S / D GWA-35S / D U5-45 / D / BRA CCR-7S' / D' GWA-36S'/ D' U5-5D'/ BR CCR-8D' / BR GWA-37S / D U5-6S / D CCR-9D GWA-45D U5-85 / D / BR CCR-125 / D / BR GWA-46D CCR-13D GWA-47D CCR-15D GWA-48BR CLMW-1' GWA-51D CLMW-5S GWA-64BRL CLMW-6 GWA-65BR/BRL CLP-1 GWA-66BRL CLP-2 GWA-67BR/BRL GWA-68BRL 1st semi-annual sampling event to be analyzed for parameters in Table 1. Optimized Quarterly & Semi -Annual Parameters for "non -new wells" (36) IL 2018 CSA Update COls (Total and dissolved^ metals) kArniCA Water Quality Parameters (Total and dissolved- metals) Field Parameters Total Uranium' (233+234+236+238) Aluminum^ Dissolved Oxygen (DO) Boron Alkalin'ty(CO3/HCO3) Oxidation -Reduction Chromium (total)^ Vanadium^ BariumA Potential (ORP) Chromium (hexavalent) Beryllium^ pH Cobalt^ Calcium Redox Potential (Eh) Iron Chloride Specific Conductance Manganese^ Fluoride Temperature Total Radium' (226+228) Lithium^ Turbidity Strontium^ Magnesium Sulfate Nitrate + Nitrite Thallium^ Potassium Total Dissolved Solids (TDS) Selenium^ A Dissolved metals will be analyzed once per year during the 1st semi-annual sampling event. Sodium Phosphorus, dissolved Total Organic Carbon (TOC) Water Level Only (20) AB-4UA15/LA15 BG-2D CCPMW-2S / D CCPMW-3S / D CCPMW-4 CCPMW-5 CCPMW-6S / D CCPTW-1S / D CCPTW-2 GWA-6S / D GWA-25D GWA-26D GWA-30BRU GWA-455 Comprehensive water level sweeps will occur semi-annually and will include wells in Quarterly, Semi -Annual and Water Level Only lists. Replaced (3) AS-7BRA (replaced by AS-7BRB) GWA-2BR (replaced by GWA-2BRA) U5-2S-SLA CLMW-5D MW-4D MW-7D MW-11D AB-9S / D / BR Discontinued Parameters (10) Proposed (non -COI) Constituents to be Discontinued Antimony Cadmium Copper Lead Mercury Molybdenum Nickel Sulfide Total Suspended Solids (TSS) Zinc Notes: IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COls = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ = North Carolina Department of Environmental Quality tSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. **Wells were previously approved by DEQto be sampled for boron and sulfate only in historic versions of the IMP due to elevated pH. Wells that exhibit elevated pH are proposed to remain a boron-and- sulfate- only sample location; however, if the pH improves with redevelopment to fall :58.5 at such well, the well will be sampled for the complete appropriate parameter suite for that well; i.e. "optimized non - new well' or "new well' lists as proposed herein. No wells are currently flagged with this note but may be in the future. ' Wells to be sampled for total radium and total uranium, in addition to water quality parameters noted. ZWell is sampled as part of CAMA Ash Basin IMP. Data is used for evaluating additional source units. These wells will be analyzed for parameters in Table 1. Wells in bold are ash basin wells that may become restricted in 2020 at any time due to stability concerns from decanting/construction activities. Data submittals will identify any wells that were not sampled as a result. Wells for Quarterly Monitoring (24) CP-11) GP-1BR CP-2S/BRU/BR GP-2BRU/BR CP-3S/BR GP-3S/BR CP-4S/BRU GP-4S/BR CP-5S/I/BR GWA-60BRU/BR CP-6S/BR GWA-61BRU/BR Table 2.6A - Cliffside Cliffside Steam Station - Additional Source Area Wells Summary of Wells, Frequency, & Parameters (to begin Q1 2020) Modification - November 2019 Wells for Semi -Annual Monitoringt (0) Quarterly & Semi -Annual Parameters for Additional Source Area Wells Additional source area wells will be analyzed for parameters in Table 1. Notes: IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment CON = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ= North Carolina Department of Environmental Quality tSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. Table 2.7 - Dan River Dan River Steam Station - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2020) Modification - November 2019 Wells for Quarterly Monitoring (45) CPA-1S*/D*/BR* CTA-3S*/D*/BR* CPA-2S*/D*/BR* CWA-1S*/D*/BR* CPA-3S*/BR* CWA-2S*/D*/BR* CPA-4D*/BR* CWA-3S*/D*/BR* CPA-5D*/BR* CWA-4S*/D*/BR* CPA-6S*/D*/BR* CWA-5S*/D*/BR* CPA-7BR* CWA-6S*/D*/BR* CTA-1S*/D*/BR* GWA-7BR* CTA-2S*/D*/BR* GWA-12BR* Wells for Semi -Annual Monitoringt (51) BG-1DA GWA-15D ------------------------------------------ BG-5S/D ------------------------------------------ ----------------------------- GWA-16S/D ----------------------------- BG-10S/D/BR GWA-17D ------------------------------------------ CCR-03S/D ------------------------------------------ ----------------------------- GWA-20S/D ----------------------------- G WA-4S/D ------------------------------------------ LF-CCR-04S/D ----------------------------- GWA-5BR/BRD ------------------------------------------ LF-CCR-05S/D ----------------------------- GWA-6S/D/BR ------------------------------------------ MW-12/D ----------------------------- GWA-7S/D ------------------------------------------ MW-20S/D ----------------------------- GWA-8S/D/BR ------------------------------------------ MW-21S/D ----------------------------- GWA-9S/D/BR ------------------------------------------ MW-22S/D/BR ----------------------------- GWA-10D MW-23D/BR ------------------------------------------ GWA-12S/D ------------------------------------------ ----------------------------- MW-317BR/BRL ----- ------------------------ GWA-14S/D 1st semi-annual sampling event to be analyzed for parameters in Table 1. Optimized Quarterly & Semi -Annual Parameters for "non -new wells" (35) 2018 CSA Update CON Water Quality Parameters Field Parameters (Total and dissolved^ metals) (Total and dissolved^ metals) Antimony^ ------------------------------------------------------------------------- Manganese Aluminum^ ------------------------------------------ Dissolved Oxygen (DO) ------------------------------ Arsen iCA Molybdenum^ Alkalinity (CO3/HCO3) Oxidation -Reduction Beryllium^ ---------------------------------- ------------------------------------- Nickel^ -------------------------------------- ------------------------------------------ Calcium ------------------------------------------ Potential (ORP) ------------------------------ Boron ^ -------------- Selenium^ -------------------------------------- Chloride ------------------------------------------ H ----------------------------- y------------------ Ber Ilium^ ---------------------------------- Strontium^ -------------------------------------- Fluoride ------------------------------------------ Redox Potential Eh ----------------------------- Chromium (total)^ Sulfate Lithium^ Specific Conductance ---------------------------------- Chromium (hexavalent) ---------------------------------- -------------------------------------- Total Dissolved Solids (TDS) -------------------------------------- ------------------------------------------ Magnesium ------------------------------------------ ----------------------------- Temperature ------------------- -------- Cobalt^ Vanadium^ Nitrate + Nitrite ------------------------------------------ Turbidity ---------------------------------- Iron A -------------------------------------- Phosphorus, dissolved ------------------------------ ^ Dissolved metals will be analyzed once per year during the ------------------------------------------ Potassium ----------------------------- 1st semi-annual sampling event. ------------------------------------------ Sodium P = Interim Monitoring Plan 4 = Comprehensive Site Assessment Is = Constituents of Interest MA = Coal Ash Management Act DEQ = North Carolina Department of Environmental Quality Water Level Only (1) GWA-10S Comprehensive water level sweeps will occur semi- annually and will include wells on Quarterly, Semi -Annual, and Water Level Only lists. To be Replaced No well replacements planned at this time. o be Aband0ne No well abandonments planned at this time. Discontinued Parameters 13 Proposed (non -COI) Constituents to be Discontinued Barium Cadmium Copper Lead Mercury Nitrate as N Total Radium (226+228) Sulfide Thallium Total Organic Carbon (TOC) Total Suspended Solids (TSS) Total Uranium Zinc +Semi -Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re- evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace. Wells for Quarterly Monitoring (19) Active Basin CMW-5 DMW-2 MW-1 MW-3 Inactive Basins DMW-3 IABMW-3S IMW-4S Coal Pile CP-1S*/D* CP-2S*/D* CP-3S*/D* CP-4S*/D* CP-5S*/D* CP-6S*/D* Table 2.8 - H.F. Lee H.F. Lee Energy Complex - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2020) Modification - November 2019 Wells for Semi -Annual Monitoringt (57) EL Active Basin Inactive Basins AMW-6RBC IABMW-1/S AMW-11S/BC IABMW-2/S AMW-12S/BC IABMW-3 AMW-13S/BC IMW-1S/BC AMW-14S/BC IMW-2BC AMW-15S/BC IMW-3S/BC AMW-16BC IMW-4BC AMW-17S/BC IMW-5S/BC AMW-18S IMW-6S AMW-19S/BC IMW-7S AMW-20S/BC SMW-3 AMW-22S/BC SMW-4 AMW-23S/BC BW-1 BG M W-9 CW-1 CCR-100S CW-3 CCR-104S CW-4 CCR-106S SMW-S CMW-6/6R 1st semi-annual sampling event to be analyzed for parameters in Table 1. CTMW-1 MW 2 LOLA LLMW-1/S LLMW-2/S JOWL Optimized Quarterly & Semi -Annual Parameters for "non -new wells" (33) Water Quality Parameters (Total and dissolved^ metals) Field Parameters Alkalinity (CO3/HCO3) Calcium Nitrate + Nitrite Dissolved Oxygen (DO) ------------------------------------ Aluminum^ ----------------------------------- Chloride ------------------------------------- Phosphorus, dissolved ------------------------------- Oxidation-Reduction ------------------------------------ Antimony^ ----------------------------------- Chromium (total)^ ------------------------------------- Potassium Potential (ORP) ------------------------------------ Arsenic^ ----------------------------------- Chromium (hexavalent) ------------------------------------- Selenium^ ------------------------------- pH ------------------------------------ BariUMA ----------------------------------- Cobalt^ ------------------------------------- Sodium ..... Redox Potential (Eh) ------------------------------------ Boron^ ----------------------------------- Fluoride ------------------------------------- Strontium^ ------------------------------- Specific Conductance ^Dissolved metals will be ----------------------------------- Iron^ ------------------------------------- Sulfate ------------------------------- Te_ mperature __ analyzed once per year during Lithium^_ -------------- -- Thallium^ ------------- --------------------- --- Turbidity ------------ -- the 1st semi-annual sampling Magnesium Total Dissolved Solids (TDS) - - - - ------------------------------- event. Manganese^ Vanadium^ Water Level Only (9) Active Basin AMW-9BC AMW-21S/BC BGMW-10 CMW-7 CMW-8 CMW-10 DMW-1 Inactive Basins CW-2 Comprehensive water level sweeps will occur semi-annually and will include wells on Quarterly, Semi -Annual and Water Level Only lists. JW To Be Replaced No well replacements planned at this time Wells within the footprint of the Active Basin are slated for abandonment in 2020. ABM W-1/S/D PZ-2 PZ-3 Discontinued Parameters (15) Proposed (non -COI) Constituents to be Discontinued Beryllium Cadmium Copper Lead Mercury Methane Molybdenum Nickel Nitrate as N Total Radium (226+228) Sulfide Total Organic Carbon (TOC) Total Suspended Solids (TSS) Total Uranium Zinc Notes: IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COIs = Constituents of Interest LAMA = Coal Ash Management Act NCDEQ= North Carolina Department of Environmental Quality t5emi-Annual monitoring events are scheduled to be performed concurrently with two quarterly monitoring events per year and will include the wells listed under "Wells for Quarterly Monitoring" for respective events. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace. Wells in bold are ash basin wells that may become restricted in 2020 at any time due to stability concerns from decanting/construction activities. Data submittals will identify any wells that were not sampled as a result. Wells for Quarterly Monitoring (48) AB-1S'/D'/BR'/BRL'/B RLL'/B RLLL' AB-10SL/D/BR/BRL' AL-1S'/D'/BR'/BRL' AL-2S/D/BR/BRL/BRLL/BRLLL' AL-3S/D/BR AL-4D/BR/BRL CP-1S/D/BR CP-2S/D CP-3S/D GWA-15S'/D' PVSF-15/D/BR PVSF-2S/D/BR/BRL PVSF-3S'/D'/BR' PVSF-45' D' BR' Table 2.9 - Marshall Marshall Steam Station - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2020) Modification - November 2019 Wells for Semi -Annual Monitoringt (103) A J AB-2S'/D'/BR' GWA-4S/D AB-3S/D GWA-5S/D AB-SS'/D'/DU'/BR' GWA-6S/D AB-6S/D/BRA/BRL GWA-7S/D AB-7DU GWA-8S/D AB-8DU GWA-9B R AB-9S/D/BR GWA-10S/D AB-12S'/SL'/D'/BR' GWA-11S'/D'/BR' AB-14S/D/DU GWA-12S'/D* */BR' AB-1SSL/D/BR GWA-13S/DA** AB-16DU GWA-145/D AB-20S/D ILF-15/D/BR AB-21S/D ILF-25/D/BR BG-1S'/D'/BRA' MW-1 BG-25'/BR' MW-4'/D' BG-35'/D'/BR' M W-65'/D' CCR-9S/DA MW-75'/D' GP-1S/D MW-8S'/D' GP-25/D MW-9S'/D' G P-3S/D M W-12S/D GWA-1S/D/BR M W-13S/D GWA-2DA M W-145/D/BR'/BRL' GWA-35/D 1st semi-annual sampling event to be analyzed for parameters in Table 1. Optimized Quarterly & Semi -Annual Parameters for "non -new wells" (38) 2018 CSA Update COls (Total and dissolved^ metals) Water Quality Parameters (Total and dissolved^ metals) Field Parameters Antimony^ Manganese^ Aluminum^ Dissolved Oxygen (DO) Arsenic^ Molybdenum^ Alkalinity (CO3/HCO3) Oxidation -Reduction Potential (ORP) Barium^ Nickel^ Calcium pH Beryllium^ Total Radium' (226+228) Fluoride Redox Potential (Eh) Boron^ Selenium^ Lithium^ Specific Conductance Cadmium^ Strontium^ Magnesium Temperature Chloride Sulfate Nitrate + Nitrite Turbidity Chromium (total)^ Total Dissolved Solids (TDS) Potassium Chromium (hexavalent) Thallium^ Sodium Cobalt^ Vanadium^ Total Organic Carbon (TOC) Iron^ A Dissolved metals will be analyzed once per year during the 1st semi- annual sampling event. Notes: IMP = Interim Monitoring Plan --------------------------------------------------------------------------------------------------------------------------------------------- CSA = Comprehensive Site Assessment --------------------------------------------------------------------------------------------------------------------------------------------- COls = Constituents of Interest --------------------------------------------------------------------------------------------------------------------------------------------- CAMA = Coal Ash Management Act --------------------------------------------------------------------------------------------------------------------------------------------- NCDEQ = North Carolina Department of Environmental Quality --------------------------------------------------------------------------------------------------------------------------------------------- tSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. --------------------------------------------------------------------------------------------------------------------------------------------- *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace. --------------------------------------------------------------------------------------------------------------------------------------------- ** Wells to be analyzed for boron and sulfate only due to elevated pH. --------------------------------------------------------------------------------------------------------------------------------------------- ' Wells to be sampled for total radium (226+228), in addition to water quality param-eters- noted. - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 2 Well currently included on IMP list that is proposed to be removed from IMP (CAMA) sampling; will continue to be sampled under applicable landfill permit requirements. - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - Wells in bold are ash basin wells that may become restricted in 2020 at anytime due to stability concerns from decanting/construction activities. Data submittals will identify any wells that were not sampled as a result. I Water Level Only (27) AB-4S/SL/D AB-7S/D AB-8S/D AB-10S AB-11S/D AB-13S/D AB-16S/D GWA-2S MS-82 MS-102 MS-112 MS-132 MW-22 M W-32 M W-52 M W-10S/D M W-11S/D OB-1 (Ash Basin) Comprehensive water level sweeps will occur semi- annually and will include wells on Quarterly, Semi - Annual and Water Level Only lists. AB-17S/D 7 AB-185/D/DU To Be Replaced (2) AB-17S/D Discon rs (8) Proposed (non -COI) Constituents to be Discontinued Copper Lead Mercury Nitrate as N Sulfide Total Suspended Solids(TSS) Total Uranium Zinc Wells for Quarterly Monitoring (3) I CW-21/D' CCR-102BR-BG Table 2.10 - Mayo Mayo Steam Electric Plant - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2020) Modification - November 2019 Wells for Semi -Annual Monitorin la ABMW-11 MW-31 ABW-2/BR/BRL MW-3BR ABMW-3/S MW-5BR ABMW-4X/D/BR MW-9BRL BG-1' MW-12S' / D1 BG-2' MW-13BR CW-1 / D MW-16S / D' / BR' CW-3 MW-18D / BR CW-4 MW-19D / BR CW-5 MW-104BRM/BRL CW-61 MW-2 MW-105BRM 1st semi-annual sampling event to be analyzed for parameters in Table 1. Optimized Quarterly & Semi -Annual Parameters for "non -new wells" (32) 2017 CSA Update COls Water Quality Parameters Field Parameters (Total and dissolved^ metals) Arsenic^ Molybdenum^ Alkalinity (CO3/HCO3) Dissolved Oxygen (DO) ---------------------------------- Bariu MA ---------------------------------- Total Radium' (226 + 228) ------------------------------------------ Calcium ----------------------------- Oxidation-Reduction ---------------------------------- Boron A ---------------------------------- Strontium^ ------------------------------------------- Chloride Potential (ORP) ---------------------------------- Chromium (total)^ ---------------------------------- ---------------------------------- Sulfate ---------------------------------- ---------------- -------------------------- Fluoride ------------------------------------------ ---------------------------- pH ---------------------------- ---Chromium-----(hexavalent)- ------------------------------------------------------------------------------------- Solids (TDS) Total-Dissolved - Magnesium -------------- Redox Potential (Eh) ---------------------------- Cobalt^ ---------------------------------- Total Uranium' Nitrate + Nitrite ------------------------------------------ Specific Conductance ---------------------------- Iron^ (233+234+236+238) Potassium Temperature -------------- ------------------------------------------------------- Lithium^ Vanadium^ ------------------------------------------ Sodium ---------------------------- Turbidity ---------------------------------- Manganese ---------------------------------- --------- Total Organic -----------------Carbon ---------------- ---------------------------- A Dissolved metals will be analyzed once per year during the ------------------------------------------ ------------------------------------------ ---------------------------- ---------------------------- 1st semi-annual sampling event. Water Level Only M W-4 MW-8BR MW-10BR MW-14BR MW-103BRL MW-105BRL MW-107BRL Comprehensive water level sweeps will occur semi-annually and will include wells on Quarterly, Semi -Annual and Water Level Only lists. To Be Replaced No well replacements planned at this time To be Abandoned No well abandonments planned at this time Discontinued Parameters (14) Proposed (non -COI) Constituents to be Discontinued Aluminum Antimony Beryllium Copper Cadmium Lead Mercury Nickel Nitrate as N Selenium Sulfide Thallium Total Suspended Solids Zinc Notes: IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment Cols = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ = North Carolina Department of Environmental Quality tSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. 1 Wells to be sampled for total radium (226 + 228), in addition to water quality parameters noted. If concentrations are greater than the Federal MCL, sample quarterly. If concentrations are less than the Federal MCL, reduce total radium sampling to semi-annually and reevaluate historical exceedances as possibly anomalous. If determined to be anomalous, discontinue sampling for total radium. Background wells BG-1 and BG-2 will also be included in semiannual sampling of total radium for ongoing comparative purposes. Wells in bold are ash basin wells that may become restricted in 2020 at any time due to stability concerns from decanting/construction activities. Data submittals will identify any wells that were not sampled as a result. Wells for Quarterly Monitoring (18) CPA-ID/BR CPA-2 D/B R CPA-3 D/B R CPA-4D CPA-5S/D/BR CPA-7D GYP-1D GYP-2BR GYP-3D/BR GYP-4D GYP-5D/BR Table 2.10A - Mayo Mayo Steam Electric Plant - Additional Source Area Wells Summary of Wells, Frequency, & Parameters (to begin Q1 2020) Modification - November 2019 Wells for Semi -Annual Monitoringt (0) Quarterly & Semi -Annual Parameters for Additional Source Area Wells Additional source area wells will be analyzed for parameters in Table 1. MP = Interim Monitoring Plan ;SA = Comprehensive Site Assessment ;Ols = Constituents of Interest ;AMA = Coal Ash Management Act = North Carolina Department of Environmental Quality Water Level Only (1) I GYP-1BR I emi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under iarterly for respective events. Wells for Quarterly Monitoring (21) CPA-1S/D CPA-2S/D CPA-3S/D CPA-4S CPA-5S/D CPA-6S CPA-7S/D GWA-11S/D GWA-12S/D GWA-20S GWA-2BRU GWA-3SA/D/BR Table 2.11 - Riverbend Riverbend Steam Station - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2020) - November 2019 Wells for Semi -Annual Monitoringt (70) AB-8S/D GWA-21S/D/BR BG-1S/DA GWA-22S/D/BRA BG-4S/D MW-1S/D BG-5D/BR MW-2SA/D GWA-1S/BRU MW-3S/D GWA-2S/BR MW-4S/D GWA-4S/D/BR MW-5S/D GWA-5S/D MW-6S/D GWA-6S/D M W-7SR/D/BRA GWA-7S/D/BR MW-8S/I/D GWA-8S/D M W-9/9 DA/9 B RA GWA-9S/D/BR MW-10 GWA-10S/BRU MW-11SR/DR GWA-13S/D M W-13 GWA-14S/D GWA-20DA/BR M W-14 MW-15/15DA/156R 1st semi-annual sampling event to be analyzed for parameters in Table 1. Optimized Quarterly & Semi -Annual Parameters for "non -new wells" (33) E 2018 CSA Update COls (Total and dissolved^ metals) Water Quality Parameters (Total and dissolved^ metals) ____j Field Parameters Antimony^ Iron Aluminum^ Dissolved Oxygen (DO) Arsenic^ Manganese Alkalinity (CO3/HCO3) Oxidation -Reduction Potential (ORP) Beryllium^ Strontium^ Cadmium^ Boron Sulfate Calcium pH Chromium (total)^ Total Dissolved Solids (TDS) Magnesium Redox Potential (Eh) Chromium (hexavalent) Molybdenum^ Nickel^ Specific Conductance Temperature Cobalt^ Vanadium^ ^ Dissolved metals will be analyzed once per year during the 1st semi-annual sampling event. Nitrate + Nitrite Turbidity Phosphorus, dissolved Potassium Sodium Thallium^ Zinc^ IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COls = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ = North Carolina Department of Environmental Quality Water Level Only (8) BG-2S/D/BR BG-3S/D BG-4BR OB-1 O B-2 Comprehensive water level sweeps will occur semi-annually and will include wells on Quarterly, Semi - Annual and Water Level Only lists. To Be Replaced (9) GWA-9BRA GWA-15SA/DA GWA-20BRA GWA-22SA GWA-23 SA/DAA/BRA M W-4SA Abandoned(Z) GWA-15S/D Discontinued Parameters (12) Proposed (non -COI) Constituents to be Discontinued Barium Chloride Copper Lead Mercury Nitrate as N Total Radium (226+228) Selenium Sulfide Total Organic Carbon (TOC) Total Suspended Solids (TSS) Total Uranium nual monitoring events are scheduled to be performed concurrently with two of the Quarterly monitoring events and will include the wells listed under Quarterly for respective Wells for Quarterly Monitoring (24) ABMW-07BRLL* MW-37D* HWMW-01BR* MW-37S* MW-01BRL* MW-39BR* MW-21BRLR MW-39D* MW-34BR* MW-108BRL* MW-34D* MW-108BRLL* MW-35BR* MW-205BRL* MW-35D* MW-205BRLL* MW-35S* MW-205BRLLL* MW-36BR* MW-208BRL* MW-36D* MW-208BRLL* MW-37BR* MW-208BRLLL* Table 2.12 - Roxboro Roxboro Steam Electric Plant - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2020) Modification - November 2019 Wells for Semi -Annual Monitoringt (76) ABMW-011 GMW-09 MW-1SBR1 ABMW-01BR' GMW-10 MW-15D1 ABMW-02' GMW-11 MW-16BR1 ABMW-02BR' GPMW-1BR MW-17BR1 ABMW-03 GPMW-1D MW-18BR1 ABMW-03BR GPMW-1S MW-18D1 ABMW-03BRL GPMW-2BR MW-19BRL1 ABMW-05D' GPMW-2D MW-20BRL ABMW-06 GPMW-3BR MW-22BR ABMW-06BR GPMW-3D MW-22D ABMW-07BR MW-01BR MW-23BRR ABMW-07BRL MW-021 MW-24BR BG-011 MW-02BR MW-26BR BG-01BR1 MW-03BR1 MW-27BR BG-01BRLR1 MW-04BR MW-28BR BG-2BR1 MW-05BR1 MW-29BR CCR-113BR MW-05D1 MW-30BR CCR-113D MW-06BR1 MW-31BR CW-01 MW-06D1 MW-32BR CW-021 MW-07BR MW-33BR** CW-02D1 MW-08BR 1st semi-annual sampling event to be analyzed for parameters in Table 1 CW-03 MW-09BR1 CW-03D MW-10BR1 CW-04 MW-11BR1 CW-051 MW-11D1 GMW-06 MW-12BR GMW-07 MW-13BR1 GMW-8R MW-14BR' Optimized Quarterly & Semi -Annual Parameters for "non -new wells" (34) 2017 CSA Update CON (Total and dissolved^ metals) ILAntimonyA Water Quality Parameters (Total and dissolved^ metals) Field Parameters Sulfate Aluminum^ Boron Total Dissolved Solids (TDS) Alkalinity (CO3/HCO3) Dissolved Oxygen (DO) Chromium (total)^ Total Uranium' (233+234+236+238) Arsenic^ Oxidation -Reduction Potential (ORP) Chromium (hexavalent) Calcium Cobalt^ Vanadium^ Chloride pH Iron Fluoride Redox Potential (Eh) Manganese Lithium^ Specific Conductance Molybdenum^ Magnesium Temperature Selenium^ Nitrate + Nitrite Turbidity Strontium^ Potassium ^ Dissolved metals will be analyzed once per year during the 1st semi-annual sampling event. Total Radium' (226 + 228) Sodium Total Organic Carbon (TOC) Water Level Only (2) ABMW-05 MW-25BR Comprehensive water level sweeps will occur semi-annually and will include wells on Quarterly, Semi -Annual and Water Level Only lists. To Be Replaced No well replacements planned at this time No well abandonments planned this time. Discontinued Parameters (12) Proposed (non -COI) Constituents to be Discontinued Barium Beryllium Copper Cadmium Lead Mercury Nickel Nitrate as N Sulfide Thallium Total Suspended Solids (TSS) Zinc s: IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COls = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ = North Carolina Department of Environmental Quality tSemi-Annual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. ** Denotes well with high pH. If well is on quarterly or semi annual sampling, sample for Boron and Sulfate only due to elevated pH. Respective well is proposed to remain a Boron- and Sulfate -only sample if location is proposed to remain in the IMP. However, if the pH improves with redevelopment, those wells will be sampled for the full suite of COls and water quality parameters proposed herein if pH is within compliance. 1 Wells to be sampled for total radium and total uranium, in addition to water quality parameters noted. Wells in bold are ash basin wells that may become restricted in 2020 at any time due to stability concerns from decanting/construction activities. Data submittals will identify any wells that were not sampled as a result. Table 2.12A - Roxboro Roxboro Steam Electric Plant - Additional Source Area Wells Summary of Wells, Frequency, & Parameters (to begin Q1 2020) Modification - November 2019 Wells for Quarterly Monitoring (16) CPA-1BR CPA-4BR CPA -ID CPA-41D CPA -IS CPA-4S CPA-2BR CPA-5BR CPA-2 D CPA-5 D CPA-2S CPA-6BR CPA-3BR CPA-61D CPA-31D CPA-6S Wells for Semi -Annual Monitoringt (0) Quarterly & Semi -Annual Parameters for Additional Source Area Wells Additional source area wells will be analyzed for parameters in Table 1. IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COls = Constituents of Interest CAMA = Coal Ash Management Act NCDEQ = North Carolina Department of Environmental Quality nual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for events. Table 2.13 - Sutton L.V. Sutton Energy Complex - IMP Optimization Summary of Wells, Frequency, & Parameters (to begin Q1 2020) Modification - November 2019 Wells for Quarterly Monitoring (38) Wells for Semi -Annual Monitoringt (51 CCR-110B MW-15RB* AW-03C MW-24RC CCR-110C M W-15 RC* AW-04C M W-27B CCR-112 B M W-33C AW-05C M W-27C CCR-112C M W-41B AW-08C M W-28C CCR-114B MW-45B* AW-09C MW-31R-C CCR-114C MW-45C* MW-05B MW-36B CCR-115B MW-46B* MW-05C MW-36C CCR-115C MW-46C* MW-05CD MW-37B FPA-02B* MW-50B* MW-05D MW-37C FPA-02C* M W-50C* M W-05R-E M W-37CD FPA-03B* MW-41C MW-07C MW-37D FPA-03C* MW-41D MW-08B MW-37E FPA-04B* MW-43B* MW-08 MW-38C FPA-04C* MW-43C* MW-08D MW-39C FPA-09 B*1 M W-44B* M W-08E M W-40C FPA-09C* 1 M W-44C* M W-16 M W-41B MW-08B SMW-01C MW-16D MW-41C MW-08D SMW-02C MW-20 MW-41D MW-12R SMW-03C MW-20D MW-41E MW-21C SMW-01B MW-22C SMW-04C MW-23B SMW-05B MW-23C SMW-05C MW-23D SMW-06B MW-23E SMW-06C MW-24RB 1st semi-annual sampling event to be analyzed for parameters in Table 1. Optimized Quarterly & Semi -Annual Parameters for "non -new wells" (31) 2018 CSA Update CON Water Quality Parameters Field Parameters (Total and dissolved^ metals) (Total and dissolved^ metals) Arsenic^ Strontium^ Alkalinity (CO3/HCO3) Dissolved Oxygen (DO) ------------------------------------ Boron^ ------------------------------------------- Sulfate ---------------------------------------------------- Aluminum^ ----------------------------------- Oxidation-Reduction ------------------------------------ Chloride ------------------------------------------- TDS (Total Dissolved Solids) ---------------------------------------------------- Barium^ Potential (ORP) ------------------------------------ Chromium (hexavalent) ------------------------------------------- Vanadium^ ---------------------------------------------------- Calcium ----------------------------------- Redox Potential (Eh) ------------------------------------ Cobalt^ ------------------------------------ ------------------------------------------- ------------------------------------------- ---------------------------------------------------- Lithium^ ---------------------------------------------------- ----------------------------------- Specific Conductance ----------------------------------- Iron^ ------------------------------------ ------------------------------------------- Fluoride ---------------------------------------------------- Temperature ----------------------------------- Manganese^ ------------------------------------ ------------------------------------------- Magnesium ---------------------------------------------------- Turbidity ----------------------------------- Molybdenum^ ------------------------------------ ------------------------------------------- Nitrate + Nitrite ---------------------------------------------------- ----------------------------------- pH ------------------------------------ ------------------------------------------- Potassium ---------------------------------------------------- ----------------------------------- Selenium^ Sodium ---------------------------------------------------- Total Organic Carbon (TOC) ---------------------------------------------------- ----------------------------------- ----------------------------------- A Dissolved metals will be analyzed once per year during the 1st semi-annual sampling event. P = Interim Monitoring Plan --------------------------------------------------------------- 4 = Comprehensive Site Assessment Is = Constituents of Interest --------------------------------------------------------------- MA = Coal Ash Management Act DEQ= North Carolina Department of Environmental Quality Water Level Only (20) AW-01C AW-02C AW-02D AW-05D AW-06R-D AW-06R-E AW-07R-D AW-09D MW-11 MW-19 MW-22B MW-28B MW-32C MW-38B MW-38D MW-39B MW-39D MW-40B M W-40D SMW-06D Comprehensive water level sweeps will occur semi-annually and will include wells on Quarterly, Semi -Annual and Water Level Only lists. To Be Replaced No well replacements planned at this time. IDiscontinued Parameters (16) IProposed (non -COI) I Constituents to be Discontinued Antimony •------------------- Beryllium •------------------- Cadmium •------------------- Chromium (total Lead Mercury Nickel Nitrate as N Phosphorus Total Radium (226+228) ------------Sulfide------------• Thallium Total Suspended Solids (TSS) Total Uranium Zinc nual monitoring events are scheduled to be performed concurrently with two Quarterly monitoring events per year and will include the wells listed under Quarterly for respective events. *New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional :onstituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace. - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - Revised from March 2019 IMP (after well installation): well FPA-16 is now labeled FPA-913 and FPA-1C is now labeled FPA-9C. Wells for Quarterly Monitoring (19) BW-4DA* CPA-1S*/I* CPA-21 * CPA-3S*/I* CPA-4S*/I * CPA-5S*/I* CPA-6S*/I * CPA-7S*/I* CPA-8S*/I* M W-5511 PW-1 (DEP #2) PZ-103* Table 2.14 - Weatherspoon Weatherspoon Power Plant - IMP Optimization Summary of Wells, Frequency & Parameters (to begin Q1 2020) Modification Request - November 2019 Wells for Semi -Annual Monitoringt (26) AW-02S CW-31 AW-03S/I MW_11 AW-04S M W-2' AW-05S M W-3' AW-06S M W-4' BW-2S1 MW-5' BW-3S1/11 MW-33S/l/D BW-4S1/11 M W-411 BW-5S MW-521 CCR-101-BG' CCR-107' CW-2 1st semi-annual sampling event to be analyzed for parameters in Table 1. Optimized Quarterly & Semi -Annual Parameters for "non -new wells" (39) Water Quality Parameters Field Parameters (Total and dissolved^ metals) Alkalinity (CO3/HCO3) Lithium^ Vanadium^ Dissolved Oxygen (DO) -------------------------------------------------------------- Aluminum^ --------- --------------------- Magnesium •------------------------------ ----------------------------------------------------------- Total Uranium' Oxidation -Reduction Arsenic^ ------------------------------ Manganese ------------------------------- (233+234+236+238)) ----------------------------------------------------------- Potential (ORP) Barium^ -------------------------------------------------------------- Molybdenum^ Zinc^ ----------------------------------------------------------- pH Beryllium^ Nickel^ Redox Potential (Eh) Boron Nitrate + Nitrite Specific Conductance ------------------------------ Calcium ------------------------------- Potassium ----------------------------- ----------------------------- Temperature Chloride Total Radium' (226 + 228) Turbidity ---------- ---------------------- Chromium (total)^ ------------------------------ Selenium^ ----------------------------------------------------------- ------------------------------ Chromium (hexavalent) ------------------------------- Sodium ----------------------------------------------------------- Cobalt^ Strontium^ ------------------------------ Copper A -------------------- Sulfate -------------------------------------------------------------- Fluoride- Thallium^ --------- --------- •------------------------------ ^ Dissolved metals will be analyzed once per year Iron Total Dissolved Solids ____________ during the 1st semi-annual sampling event. Lead (TDS) Water Level Only (16) AW-01S/l/D AW-02D AW-03D BW-01 BW-3D BW-4D CW-1 M W -6 M W-7 MW-41D MW-531/D M W-54D MW-55D Comprehensive water level sweeps will occur semi-annually and will include wells on Quarterly, Semi -Annual and Water Level Only lists. Replaced (2) MW-6 (replaced by CCR-107) MW-7 (replaced by CCR-107) Discontinued Parameters (7) Antimony Cadmium Mercury Nitrate as N Sulfide Total Organic Carbon (TOC) Total Suspended Solids (TSS) Notes: IMP = Interim Monitoring Plan CSA = Comprehensive Site Assessment COls - Constituents of Interest CAMA = Coal Ash Management Act NCDEQ = North Carolina Department of Environmental Quality tSemi-Annual monitoring events are scheduled to be performed concurrently with two of the quarterly monitoring events and will include the wells listed under Quarterly for respective events. * New wells installed as part of the CAMA program will be monitored quarterly. Samples from these wells will be analyzed for parameters formerly included as part of the 4th Quarter 2018 IMP and additional constituents analyzed voluntarily (see Table 1). After four quarterly events, the monitoring frequency and/or parameter list for the new wells will be re-evaluated with NCDEQ and may be reduced and/or optimized. Replacement wells will not be considered "new wells" and will follow the respective monitoring protocol for the well in which they replace. 11 Wells to be sampled for total radium (226 + 228) and total uranium (233 + 234 + 236 + 238), in addition to water quality parameters noted.