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HomeMy WebLinkAboutNCS000575_Previous Wastewater-SW Application_20100616�j Progress Energy NPDES permit renewal request Asheville Steam Electric Plant Permit Number: NC0000396 Buncombe County June 11, 2010 I 1 JUN 16 2010 ID] ��?O Progress Energy ' Hand Delivered June 11, 2010 File Point: 12520-B-01 Tom Belnick, Supervisor Complex NPDES Permitting Unit i North Carolina Division of Water Quality 1 1617 Mail Service Center I Raleigh, NC 27699-1617 ' Subject: Carolina Power & Light Company dba Progress Energy Carolinas Inc. Asheville Steam Electric Plant NPDES Permit No. NC0000396 Buncombe County Renewal Application I M Dear Mr. Belnick: The current NPDES permit for the Asheville Steam Electric Plant expires on December 31, 2010. ' Progress Energy hereby requests that the NPDES permit for the facility be reissued. Enclosed are EPA Application Form 1 — General Information, EPA Application Form 2C — Wastewater Discharge Information and EPA Application Form 2F — Stormwater Discharges Associated with Industrial Activity, ' all in triplicate. As we have previously discussed with DWQ staff, in order to facilitate enhancements to the existing dam of our 1964 ash pond, Progress Energy proposes to relocate outfa11001 to a point approximately 3000 feet downstream of its current location. This relocation will be necessary to allow for additional stabilization work to be undertaken on the existing 1964 ash pond dam. The proposed relocation is to a point where access under Interstate 26 already exists. Coordinates for the proposed discharge point are North 35.47367 and West-82.504. Enclosed with this renewal application is information pertaining to the 7Q10 and IQ 10 flows provided to us by staff of the USGS for this location. With reissuance of the NPDES permit, Progress Energy requests the following language regarding usage of biocides and the completion of the Biocide Form 101 be added to the permit: The permittee shall not use any biocides except those approved in conjunction with the permit application. The permittee shall notify the Director in writing not later than ninety (90) days prior to instituting use of any additional biocide used in cooling systems which may be toxic to aquatic life other than those previously reported to the Division of Water Quality. Such notification shall include completion of Biocide/Chemical Treatment Worksheet--Form 101. Division of Water Quality approval is not necessary for the introduction of new biocides into outfalls that are tested for whole effluent toxicity. Completion of the Biocide Worksheet is thus, not necessary for those outfalls with toxicity testing requirement. In addition, Progress Energy also requests the following reductions in monitoring requirements based on analysis of sampling results during the term of the current permit: Progress Energy Carolinas, Inc. Asheville Steam Plant 200 CP&L Drive Arden, NC 28704 AN Outfall 005 Remove sampling requirements for Beryllium, Cadmium, Chromium, Copper, Lead, Manganese, Nickel, Silver, Thallium, Zinc and Fluoride. Outfall 001 Remove monitoring requirements for Beryllium, -Cadmium, Chromium, Copper, Lead, Manganese, .. Silver, Thallium, Zinc, Fluoride, Total Nitrogen and Total Phosphorus. Reduce required monitoring for Mercury to twice per month. Condition A.(7) of the current NPDES permit for the Asheville Steam Electric Plant requires that Progress Energy request a continuation of its 316(a) variance beyond the term of the present permit. Enclosed is an EPA guidance letter dated August 11, 1988 outlining the general procedure to be followed in requesting the continuance of a 316(a) variance. The following is Progress Energy's response to the pertinent factors contained in the EPA general procedure for the reissuance of the 316(a) variance: 1. The permittee must request the variance be continued. Response: Progress Energy hereby requests continuation of the 316(a) variance reflected in its present NPDES permit for the Asheville Steam Electric Plant. 2. Plant operating conditions and load factors are unchanged and are expected to remain so for the term of the reissued permit. do Response: The plant operating conditions and load factors are unchanged and are expected to remain so for the term of the reissued permit. 3. There are no changes to the permittee's knowledge to the plant discharges or other discharges in WO the plant area which could interact with thermal discharges. Response: During periods of drought, as makeup water is pumped from the French Broad River to Lake Julian to sustain operating cooling water levels, Progress Energy staff suspect there may be some influence in Lake Julian from our upstream discharge point in the French Broad River. This permit application includes a ... proposal to relocate the discharge point from the facility's ash pond (outfall 001) to facilitate enhancements to the facility's 1964 ash pond dam. This outfall relocation should also eliminate any potential influence in Lake Julian from our discharge in the French Broad River. 4. There are no changes to the permittee's knowledge to the biotic community of the receiving water body which could impact the previous 316(a) determinations. Response: As demonstrated by Progress Energy's environmental monitoring, since issuance of the current NPDES permit there have been no changes to the biotic community of Lake Julian which would impact the previous 316(a) determinations. r-7 Am NO If you have any questions regarding the enclosed information, please contact Shannon Langley at (919) 546-2439. I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Enclosures cc: Laurie Moorhead (Asheville Plant) Crystal Diedrich (Asheville Plant) Shannon Langley (PEB 4) Sincerely, Garry A. Whisnant Asheville Plant Manager '.4 . - %.. UNITED STATES ENVIRONMENTAL. PROTECTION AGENCY REGION IV 345 COURTLANO XTRCCT 3 ATL%1fMTA, GCORGiA 30343 August 11, 1988 REF: 4M-FP Mr. Clyde Baldwin Division of Water KY' Natural Resources & Environmental Protection Cabinet Fort Boone Plaza l8 Reilly Road Frankfort, KY 40601 • RE: 316 GL for Permit Reissuance � idra�nce _ . Dear Mr. n: • Quet locos have arisen as to what prooedures aa:d activities are neaesrary in ng permit for A facility which has thermal limitations based on a Previous variance granted under Section 316(a) of the Clean water Act. The hollowing is provided as a follow-up to information provided at the- Feliruary 1988, EPA,/State meting in Destin, Florida. J A thermal variance granted under S316(a) terminates on expiration of the NPMS pe=it of which it is a part (Attachment -A). Procedures for a reissuanoe are virtually unchanged. from an initial determination. The amount of data necessary to SUPPQrt the variance at the time of reissuance will probably be minimal. Noweeer, if conditions have changed materially, a significant quantity of informa- tion may be needed. NOTE:-Tb the extent that peaaitteen are. unaware of these requirements, they should be notified of them expeditiously so that they can be prepared. The general procedure is as follows: I. The permittee must request that the variance be continued, preferably at the time of permit application. At that time, he should provide a basis for that continuance. The basis could be as simple as: (a) plant operating conditions and load fors are unchanged and are expected to remain so for the team of the reissued permitr (b) there are no changes (to his krxwl edge) to plant discharges or other discharges in the plant site area which could interact with the thermal di to the biotic canmungo�f ?thedreceivthere i �waterbare � changes (to his knowledge) previous 316 d6termin ations. body which would impact the rrt 2. If the permitting authority agrees with the basis► appropriate permit condi- tions would be developed; otherwise, additional data would be requested as needed. Request for additional data must be made within 60 clays of receipt of the application (Answer to Question 7► Attachment A). Additional studies can be made a permit requirement if needed (Answer to Question 7). R, Page 2 August 11, 1988 3. The Fact ShOO Rationale should contain a s frcm the - previaus 'wry of 316 variance activs pezmits (dates, detezncinations, limitations, itieetc.) and an indication of the M40sed basis for continuing the 316 variance. Stele language is included in Attachment s. 4. The Public notice requirements are contained in S124.75(a). is also included in Attachment B. ale language Should ld you z have � motions or need assistance, feel free to contact me at Sincerely yours, Charles H. Kaplan, P.E. National ExPert Steam Electric/Water ©ncicsures g cc: Mr. R. Bru e • Scott Identical letters sent to all states in Regien IV t. go atlls Please print or type in the unshaded areas only. Form Approved. OMB No. 2040-0086. FORM U.S. ENVIRONMENTAL PROTECTION AGENCY GENERAL INFORMATION T,A C Consolidated Permits Program XEPAMBE\=.EPA D GENERAL (Read the "GeneralInstructions" before starting.) LABEL ITEMS GENERAL INSTRUCTIONS label has been provided, affix it in the designated space. Review the information carefully; if any of it 1, ' SPA (. f't(LiSiW is Incorrect, cross through it and enter the correct data in the appropriate 111Hn area below. Also, If any of the preprinted data is absent (the area to the left of the label space lists the EASE pUA01E 1AML I - H' 45' information that should appear), please provide it in the proper fllNn steals) below. If the label is complete and correct, you V. PA ,ITY MAIL11dG need not complete Items I, 111, V, and VI (except VI-B which Ap must be col mpeted regardless). Complete all items f no label has been proded. Refer to the Instructions for detailed item Vf," FACILITY LOCATION descriptions and for the legal authorizations under which this data is collected. 11. POLLUTANT CHARACTERISTICS iN INSTRUCTIONS: Complete A through J to determine whether you need to submit any permit application forms to the EPA. If you answer "yes" to any questions, you must submit this form and the supplemental form listed in the parenthesis following the question. Mark "X" in the box in the third column if the supplemental form is attached. If you answer "no" to each question, you need not submit any of these forms. You may answer "no" if your activity is excluded from permit requirements; see Section C of the instructions. See also, Section D of the instructions for definitions of bold-faced terms. Mark "X" Mark "X' SPECIFIC QUESTIONS YES NO FORM SPECIFIC QUESTIONS YES NO FORM ATTACHED ATTACHED A. Is this facility a publicly owned treatment works which B. Does or will this facility (either existing or proposed) results in a discharge to waters of the U.S,? (FORM 2A) X include a concentrated animal feeding operation or X aquatic animal production facility which results in a is 17 18 19 discharge to waters of the U.S.? (FORM 2B) C. Is this a facility which currently results in discharges to �/ X �/ X D. Is this a proposed facility (other than those described in A waters of the U.S. other than those described in A or B or B above) which will result in a discharge to waters of X above? (FORM 2C) the U.S.? (FORM 2D) 25 1 26 27 22 27 24 E. Does or will this facility treat, store, or dispose of F. Do you or will you Inject at this facility industrial or hazardous wastes? (FORM 3) X municipal effluent below the lowermost stratum X containing, within one quarter mile of the well bore, underground sources of drinking water? (FORM 4) 31 J2 33 25 29 30 G. Do you or will you inject at this facility any produced water H. Do you or will you inject at this facility fluids for special or other fluids which are brought to the surface in processes such as mining of sulfur by the Frasch process, connection with conventional oil or natural gas production, X solution mining of minerals, in situ combustion of fossil X inject fluids used for enhanced recovery of oil or natural fuel, or recovery of geothermal energy? (FORM 4) gas, or inject fluids for storage of liquid hydrocarbons? (FORM 4) 77 38 39 N 75 11>B I. Is this facility a proposed stationary source which is one J. Is this facility a proposed stationary source which is Of the 28 industrial categories listed in the instructions and which will emit 100 tons �/ X NOT one of the 28 industrial categories listed in the X potentially per year of any air instructions and which will potentially emit 250 tons per pollutant regulated under the Clean Air Act and may affect year of any air pollutant regulated under the Clean Air Act a 41 42 a N 45 or be located in an attainment area? (FORM 5) and may affect or be located in an attainment area? (FORM 5) III. NAME OF FACILITY c 1 SKIP Asheville Steam Electric lant 15 15 — 2a 75 ' IV. FACILITY CONTACT A. NAME & TITLE last, rrst, & title ( .% ) B. PHONE (area code & no.) 2 W isnant, Garry A. P ant Manager I I 1 1 1 1 1 1 1 1 1 8 8 6 7-5 0 Is 1a 45 45 48 1 49 51 52• 55 y V.FACILTY MAILING ADDRESS A. STREET OR P.O. BOX a c a 3 2 0 C & rive 1s +e 4s B. CITY OR TOWN C. STATE D. ZIP CODE 4 Arden C 112117144 �r , VI. FACILITY LOCATION A. STREET, ROUTE NO. OR OTHER SPECIFIC IDENTIFIER 2 0C & F rive' 151 1a 17 ."? d ,f4.p >'.,y 1y �!, . %,•nz+v B. COUNTY NAME r, Buncombe a' 70k;. .., alp C. CITY OR TOWN D. STATE E. ZIP CODE F. COUNTY CODE (fknown) 6 A d n C 2 7 4 1s 1a b Ii {2 47 51 Si .51 EPA Form 3510-1 (8-90) CONTINUE ON REVERSE 177 CONTINUED FROM THE FRONT VII. SIC CODES 4-di it in order of riori A. FIRST B. SECOND 7 4911 (sped) Electric Power services (specify) 7 19 C. THIRD D. FOURTH 7 (specfy) 7 (specify) 115 , ,Y VIII. OPERATOR INFORMATION A. NAME B.Is the name listed in Item VIII-A also the owner? 8 Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc. m YES O NO a 55 ea C. STATUS OF OPERATOR (Enter the appropriate letter Into the answer box: if "Other, " specify.) D. PHONE (area code & no.) F = FEDERAL S = STATE M = PUBLIC (other thanfederal or state) p (specify) P=PRIVATE O= OTHER (specify) l3 A 828 687 5201 66 a 19 to 21 122 26 E. STREET OR P.O. BOX g 7 S. i •, 2 0 C & Drive 121 s3 F. CITY OR TOWN G. STATE H.ZIP CODE IX. INDIAN LAND JBArden NC 28704 Is thefacility located on Indian lands? O YES m NO 52 40 tl 4 a X. EXISTING ENVIRONMENTAL PERMITS A. NPDES f2jLaes to Su ace Water D. PSD Air issi Emons om Pro osedSources t T c 7 I 9 N N00000396 9 p 1s /a 17 10 3e I 15 1a 17 ,9 ee B. UIC Unde raundin'ecttano Fluids E. OTHER s eci 77 9 U I c T I 11— 6 —05A (specify) wNCRAPCA Air Permit 9 s 10 17 to >D is ,e ,7 ,e ep C. RCRA Hazardo-7 Wastes E. OTHER s ec1 C 9 7 7us 7 WQ0000020 (specify) State non discharge permit for ash reuse g ,a ,e ,7 76 301 Xl. MAP ,a 1 ,e I ,7 I ,e ee Attach to this application a topographic map of the area extending to at least one mile beyond property boundaries. The map must show the outline of the facility, the location of each of its existing and proposed intake and discharge structures, each of its hazardous waste treatment, storage, or disposal facilities, and each well where it injects fluids underground, Include all springs, rivers, and other surface water bodies in the map area. See instructions for precise requirements. XII. NATURE OF BUSINESS(provide a briefdescri 'on) Electric utility - This facility is an electric generating facility consisting of two coal fired units with a total net capacity of 376 Megawatts and two Internal Combustion turbines with a total net capacity of 324 Megawatts. Xill. CERTIFICATION (see instructions) I certify under penalty of law that I have personally examined and am familiar with the information submitted in this application and all attachments and that, based on my inquiry of those persons immediately responsible for obtaining the information contained in the application, I believe that the information is true, accurate, and complete. I am aware that there are significant penalties for submitting false infomration, including the possibility of fine and imprisonment. A. NAME & OFFICIAL TITLE (type orprint) B. SIGNATURE C. DATE SIGNED Garry A. Whisnant Manager - Asheville Steam Plant (✓ i `—'(/ COMMENTS FOR OFFICIAL USE ONLY c t i > EPA Form 3510-1 (8-90) wr 1= 11= do Please print p type in the unshaded areas only. EPA I.D. NUMBER (copyfromltem I ofForm /) NC0000396 Form Approved. OMB No.2040-0086. Approval expires 3-31-98, FORM 2C NPDES i. OUTFALL LOCATION U.S. ENVIRONMENTAL PROTECTION AGENCY Aw APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURE OPERATIONS Consolidated Permits Program For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A. OUTFALL NUMBER (list) B. LATITUDE C. LONGITUDE D. RECEIVING WATER (name) 1. DEG. 2. MIN. 3. SEC. 1. DEG. 2. MIN. 3. SEC. 001 35 28 03 82 32 56 French Broad River 002 35 28 10 82 32 20 Lake Julian ll. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wastewater to the effluent, and treatment units labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing by showing average flows between intakes, operations, treatment units, and outfalis. If a water balance cannot be determined (e.g., for certain mining activities), provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measures. B. For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, including process wastewater, sanitary wastewater, cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wastewater. Continue on additional sheets if necessary. 1. OUT- 2. OPERATION(S) CONTRIBUTING FLOW 3. TREATMENT FALL N0. (list) a. OPERATION (list) b. AVERAGE FLOW (include units) a. DESCRIPTION b. LISTTABLE 2C-1 CODES FROM 001 Ash sluice water See attachment 2 for flows n, NeuSe imentat otra zat on 1-U 2-K Coal File runoff See attachment 2 for flows Sedimentation, Neutralization 1-11 2-K POD wastewater See attachment 2 for flowswet Flocculation, coagulation, an treatment 1-G Low volume wastewater See attachment 2 for flows1-U Sedimentation, Neutralization 2-K water treatment wastes Dolor blowdown Plant drains , Ash hopper seal water Air preheater cleaning wastes Chemical metal cleaning wastes Evaporation of neutralization and precipitation 1-F 2-K Plant stormwater See attachment 2 for flows Sedimentation, Neutralization 1-U 2-K Combustion Turbine wastewaters See attachment 2 for flows Sedimentation, Neutralization 1-U 2-K 002 Once through cooling water See attachment 2 for flows Evaporation 1-F circulating water to heat exchangers See attachment 2 for flows Evaporation 1-P OFFICIAL USE ONLY (effluent guidelines sub -categories) EPA Form 3510-2C (8-90) PAGE 1 of 4 CONTINUE ON REVERSE 0 wig CONTINUED FROM THE FRONT C. Except for storm runoff, leaks, or spills, are any of the discharges described in Items II -A or B intermittent or seasonal? © YES (complete the following table) M NO (go to Section 111) 3. FREQUENCY 4. FLOW a. DAYS PER B. TOTAL VOLUME 2. OPERATION(s) WEEK b. MONTHS a. FLOW RATE (in mgd) (specify with units) 1. OUTFALL CONTRIBUTING FLOW (specify PER YEAR 1. LONG TERM 2. MAXIMUM 1. LONG TERM 2. MAXIMUM C. DURATION NUMBER (list) (list) a nz e g) (specifyavarage) AVERAGE DAILY AVERAGE DAILY (in days) 001 Water treatment wastes/Filter Rarely 0.003 0.006 backwash - 2/year 0.003 per 0.005 Combustion Turbines unit Chemical metal cleaning waste 0-90,000 gallons produced every 5-8 years. Plans are to evap instead of discharge Air preheater cleaning 2/yr/unit 0.01 0.01 Revere Osmosis reject stream (if installed for process water makeup) as needed 0.015 0.075 III. PRODUCTION A. Does an effluent guideline limitation promulgated by EPA under Section 304 of the Clean Water Act apply to your facility? ® YES (complete Item 111-8) ❑ NO (go to Section 117 B. Are the limitations in the applicable effluent guideline expressed in terms of production (or other measure of operation)? ❑ YES (complete Item I11-0 m NO (go to Section IV) C. If you answered "yes" to Item III-B, list the quantity which represents an actual measurement of your level of production, expressed in the terms and units used in the applicable effluent guideline, and indicate the affected outfalls. 1. AVERAGE DAILY PRODUCTION c. OPERATION, PRODUCT, MATERIAL, ETC. 2• AFFECTED OUTFACES a. QUANTITY PER DAY b. UNITS OF MEASURE (list outfall numbers) (specify) IV. IMPROVEMENTS A. Are you now required by any Federal, State or local authority to meet any implementation schedule for the construction, upgrading or operations of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders, and grant or loan conditions. ❑ YES (complete thefollowing table) NO (go to Item IV--B) 1. IDENTIFICATION OF CONDITION, 2. AFFECTED OUTFALLS 3. BRIEF DESCRIPTION OF PROJECT 4. FINAL COMPLIANCE DATE AGREEMENT, ETC. a. NO. b. SOURCE OF DISCHARGE a. REQUIRED b. PROJECTED B. OPTIONAL: You may attach additional sheets describing any additional water pollution control programs (or other environmental projects which may affect your discharges) you now have underway or which you plan. Indicate whether each program is now underway or planned, and indicate your actual or planned schedules for construction. ® MARK "X" IF DESCRIPTION OF ADDITIONAL CONTROL PROGRAMS IS ATTACHED EPA Form 3510-2C (8-90) PAGE 2 of 4 CONTINUE ON PAGE 3 M 71 w EPA Form 3510-2C (8-90) PAGE 3 of 4 CONTINUE ON REVERSE m L CONTINUED FROM THE FRONT VII. BIOLOGICAL TOXICITY TESTING DATA Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? © YES (identify the test(j) and describe their purposes below) ❑ NO (go to Section VIII) Outfall 001 From 2006 through 2009, 12 chronic toxicity tests were performed on the ash discharge as pond required by the current NPDES permit. All of the tests were recorded as "pass" and exhibited no toxicity at required testing concentrations. Vill. CONTRACT ANALYSIS INFORMATION Were any of the analyses reported in Item V performed by a contract laboratory or consulting firm? ® YES (list the name, address, and telephone number of, and pollutants analyzed by, NO (go to Section IX) each such laboratory or firm below) A. NAME B.ADDRESS C.TELEPHONE D.POLLUTANTS ANALYZED (area code & no.) (list) Pace Analytical Labs 2225 Riverside Drive (828) 254-7176 Metals, TOC, BOD, Asheville, NC 28804 Nutrients, TSS, COD, Flouride, Oil and Grease, cyanide, phenols, volatiles Environmental Testing Solutions PO Box 7565 (828) 350-9364 Aquatic Toxicity Asheville, NC 28802 Applied Speciation and 18804 Northcreek Parkway (425) 483-3300 Selenium Speciation Consulting Bothell, WA 98011 IX. CERTIFICATION I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel property gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. A. NAME & OFFICIAL TITLE (type or print) B. PHONE NO. (area code & no.) Garry A. Whisnant, Plant Manager (828) 687-5201 C. SIGNATURE D. DATE SIGNED /o ( o EPA Form 3510-2C (8-90) ri PAGE 4 of 4 am Mr_Az5t t'KIN I UK I YPI: IN THE UNSHADED AREAS ONLY. You may report some or all of this information EPA I.D. NUMBER (copyfrotn/rem I of Form !) on separate sheets (use the same format) instead of completing these pages. INCO000396 SEE INSTRUCTIONS. V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-C) EO.U.TFALL NO. o PART A -You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2. EFFLUENT 3. UNITS (specify if blank) 4. INTAKE (optio-1) b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM a. MAXIMUM DAILY VALUE (if-dable) (ifavadable) AVERAGE VALUE 1. POLLUTANT d. NO. OF ANALYSES a. CONCEN- TRATION b. MASS b. NO. OF ANALYSES CONCEN RATION (2) MASS (1) CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS a. Biochemical Oxygen Demand (BOD) 0 2 < 7 <1.4 N A / N A / N A / N A / 1 mg/1 lb/day b.Chemical Oxygen D D Demand (COD) 50 1784.8 N/A N / A N A / N / A 1 mg/1 lb/day c. Total Organic Carbon (TOO 3.5 124.9 N/A N/A N/A N/A 1 mg/1 lb/day d_ Total Suspended Solids (TS5) 4.4 230.5 N/A N/A 1.71 50.2 12 mg/1 lb/day e. Ammonia (as N) 6.5 232 N/A N/A N/A N/A 1 mg/1 lb/day f.Flow VALUE 6.28 MGD VALUE 4.23 MGD VALUE 3.52 MGD 52 MGD N/A VALUE g. Temperature VALUE VALUE VALUE VALUE (winter) 14.1 12.2 8.3 22 "C h. Temperature VALUE VALUE VALUE VALUE (summer) 26.6 24.9 19.2 34 "C MINIMUM MAXIMUM MINIMUM MAXIMUM I.pH 6.8 7.9 7.3 7.9 52 STANDARD UNITS PART B - Mark 'X' in column 2a for each pollutant you know or have reason to believe is present. Mark 'X" in column 2-b for each pollutant you believe to be absent If you mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which mark column 2a, you you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additional details and requirements. 1. POLLUTANT 2. MARK'X' 3. EFFLUENT 4. UNITS 5. INTAKE (optional) (P n AND b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM AVERAGE CAS NO. a. b. a. MAXIMUM DAILY VALUE (if-dable) (ifavad(able) VALUE CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS CONCENTRATION (2) MASS (ifavai/able) BELIEVED PRESENT BELIEVED ABSENT d. NO. OF ANALYSES a. CONCEN- TRATION b. MASS b. NO. OF ANALYSES (1) a. Bromide CONCENTRATION (2) MASS (24959-67-9) X b. Chlorine, Total �/ Residual X c. Color X d. Fecal Coliforrn X e. Fluoride (16984-48-8) 1.4 41.1 N/A N/A 0.97 28.5 4 mg/1 lb/da f. Nitrate -Nitrite M X(as 0"" ""1 " to-vu) PAGE V-1 CONTINUE ON REVERSE I' ITEM V-B CONTINUED FROM FRONT 1. POLLUTANT 2. MARK'X' 3. EFFLUENT 4. UNITS 5. INTAKE (oprionan AND b. MAXIMUM 30 DAY VALUE c. LONGTERM AVRG. VALUE a. LONG TERM CAS NO. a. b. a. MAXIMUM DAILY VALUE (if—dable) (if —actable) AVERAGE VALUE CONCENTRATION (2) MASS (1) CONCEN TRATION (2) MASS (1) CONCENTRATION (2) MASS r adable) (f BELIEVED PRESENT BELIEVED ABSENT d. NO. OF ANALYSES a. N- TRATIORATION b. MASS b. NO. OF ANALYSES (1) CONCENTRATION g. Nitrogen.` / (2) MASS Total Organic (as AO/X\ h. Oil Grease Gse /\ X <5.0 <146.8 N/A N/A <5.0 <146.8 13 mg/1 lb/da i. Phosphorus ` � n72314-0) X <0.1 <2.9 N/A N/A <0.1 <2.9 4 mg/1 lb/da j. Radioactivity (1) Alpha, Total ` ' X (2) Beta, Total X (3) Radium, Total (4) Radium 226, Total k. Sulfate (as SO,) (14808-79-8) I. Sulfide S) �/ x (- m. Sulfite (-SO,) (14265-45-3) n. Surfactants X o. Aluminum, Tots! x (7429-90.5) p. Barium, Total (7440-393) q. Boron, Total (7440-42-8) r. Cobalt, Total �/ (7440-48-4) /� s. Iron, Total �/ (7439 89-6) x L Magnesium, Total x (743195.4) /� u. Molybdenum, Total x (7439-98-7) /� v. Manganese, Total x (7439-96-5) /� w. Tin, Total (7440-31-5) x. Titanium, Total X (7440.32-6) w-c to-vu/ PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D. NUMBER (copvjrom Item I of Form I) OUTFALL NUMBER CONTINI 1Fn FPOAA PAr_F Q r1F Cr%ol �s INCO000396 001 PART C - If you are a primary industry and this outfall contains process wastewater, refer to Table 2o-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark 'X" in column 2a for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2a (secondary industries, nonprocess wastewater outfal/s, and nonrequired GCAWS 'X' fractions), mark in column 2-b for each pollutant you know or have reason to believe is present Mark 'X' in column 2-c for each pollutant you believe is absent If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that If mark 2b for pollutant you column any pollutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylonitrie, 2,4 dinitrophenol, or 2-methyl-4, 6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, must either submit least you at one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See instructions for additional details and requirements. 1. POLLUTANT 2. MARK-X' 3. EFFLUENT 4. UNITS 5. INTAKE oP nonce4 ( b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a. b. c. a. MAXIMUM DAILY VALUE (if-ailable) VALUE (ijavadable) AVERAGE VALUE CAS NUMBER TESTING BEUEVED BELIEVEo (1) (1) d. NO. OF a. CONCEN-b. OF (rfavarlable) REQUIRED PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS NAO $ES METALS, CYANIDE, AND TOTAL PHENOLS 1M.Antimony. Total 8.2 0.29 N/A N/A (7440-36-0) N/A N/A 1 ug/1 lb/day 2M. Arsenic, Total 108 3.6 N/A N/A (7440-38-2) 0.063 1.85 12 1 mg/1 lb/day 3M. Beryllium. Total X <0.001 <0.03 N/A N/A (/440�1-7) <0.001 <0.03 4 mg/1 lb/day 4M. Cadmium, Cadmium, Total X <0.001 <0.03 N/A N/A (74 <0.001 <0.03 4 mg/1 lb/day 5M.Chromium. X 0.0051 0.15 N/A N/A Total (7440-47-3) 0.003 0.09 4 mg/1 lb/day 6M.C-50-8) Total X0.0126 0.37 N/A (7440 N/A 0.005 0.15 4 mg/1 lb/day 7Lead, Total X X <0.005 <0.15 N/A N/A (7439-92439-92-1) <0.005 <0.15 4 mg/1 lb/day 8M. Mercury, Total X X 0.0564 0.0016 0.0416 0.0014 (7439-97-6) r 0.024 .0007 52 ug/1 lb/day 9M. Nickel, Total (7440-02-0) X 0.0186 0.55 N/A N/A 0.012 0.35 4 mg/1 lb/day 10M. Selenium, X 0. 0794 2 33 N/A N/A Total (7782-t9-2) . 0 . 061 1. 79 12 mg/1 lb/day 11M. Silver, Total �/ X X <0 <0 N/A N/A (7440-22-4) .005 .15 <0 . 005 <0.15 4 mg/1 lb/day 12M. Thallium, X X <0.010 <0.29 N/A N/A Total (7440-zs-0) /� /� <0. 010 <0.29 4 mg/1 lb/day 13MZinc, Total X X 0.0194 0.57 N/A (744 (7440-66-6) /� /� N/A 0.011 0.32 4 mg/1 lb/day 14M. Cyanide, Total X X <0.005 (57-12-5) <0.15 N/A N/A N/A N/A 1 mg/1 lb/day 15M. Phenols, Total X X <0.01 <0.29 N/A N/A N/A N/A 1 mg/1 lb/day DIOXIN DESCRIBE RESULTS chlor dibenz chlorodibenzo-P- Dioxin (1764-01-6) FAUL V-3 CONTINUE ON REVERSE I I I I I I I I I I I CONTINUED FROM THE FRONT 1. POLLUTANT 2. MARK'X' 3. EFFLUENT 1 4. UNITS S. INTAKE (option!) AND b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM CAS NUMBER a. TESTING b. BELIEVED c. [-- DAILY VALUE (if-ailable) VALUE (ifavailable) d. NO. OF a. CONCEN- AVERAGE VALUE BELIEVED ABSENT MXIMUM CONTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS (ifaoallable) REQUIRED PRESENT ANALYSES TRATION b. MASS ANALYSES GC/MS FRACTION -VOLATILE COMPOUNDS 1 V. Accrolein x X N/A N/A (107-02-8) 1100 <3.57 N/A N/A 1 ug/1 lb/day 2V. Aaylonitrile x X <100 N/A N/A (107-13-1) <3.57 N/A N/A 1 ug/1 lb/day 3V.Benzene x X (7143-2) <5.0 <0.18 N/A N/A N/A N/A 1 ug/1 lb/day 4V. Bis (Chloro- methyl) Ether (542-88.1) Testing not required 5V. Bromo(orm x X <5.0 (75-25-2) <0.18 N/A N/A N/A N/A 1 ug/1 lb/day 6V. Carbon Tetrachloride (58-23-5-23-5) X X <5.0 <0.18 N/A N/A N/A N/A 1 ug/1 lb/day orobenzene X X <5.0 N/A (108-9 (108-90.7) <0.18 N/A N/A N/A 1 ug/1 lb/day bro di_ bramomet48-1) ne X X <5.0 <0.18 N/A N/A (124-48-t) N/A N/A 1 ug/1 lb/day 9V. Chloroethane x X <10.0 (75-M3) <0.36 N/A N/A N/A N/A 1 ug/1 lb/day 10V. 2-CMoro- yl 5-8) her X X 110.0 N/A N/A (110- (110.75-8) <0.36 N/A N/A 1 ug/1 lb/day 11 V. Chloroform X X (67-W3) <5.0 <0.18 N/A N/A N/A N/A 1 ug/1 lb/day 12V. Dichloro- broane -27�) (75-27-4) X X <5.0 <0.18 N/A N/A N/A N/A 1 ug/1 lb/day 13V. Dichbro- dinuoromethane (.15-71-8) Testing not required 14Vethane %< <5.0 N/A N A / e(7DbMoro ethane(75-34�) <0.18 N A / N A / 1 ug/1 lb/day 15V. 1,2-Dichloro- x X <5.0 N/A N/A ethane(107-06-2) <0.18 N/A N/A 1 ug/1 lb/day 1thyien x X <5.0 N/A N/A ethylene (75-35�) (75-3 -4) /� <0.18 N/A N/A 1 ug/1 lb/day 17V. 1,2-Dichloro- x X <5.0 N/A N/A propane(78-87-5) <0.18 N/A N/A 1 ug/1 lb/day 18V.1,3-Dichloro- propylene X ` , X <5.0 N/A (542-75.6) <0.18 N/A N/A N/A 1 ug/1 lb/day 19V. Ethylbenzene �/ <5.0 18 N/A N/A (100-41-4) /� <0 . N/A N/A 1 ug/1 lb/day 20V. Methyl Bromidep4-83-9) X <10.0 <0.36 N/A N/A N/A N/A 1 ug/1 lb/day 21V. Methyl Chloride (74-87-3) <5 .0 <0 . 18 N/A N/A N/A N/A 1 ug/1 lb/day EPA Form 351U-2G (8-90) PAGE V-4 CONTINUE ON PAGE V-5 CONTINUED FROM PAGE V-4 1. POLLUTANT 2. MARK "X" 3. EFFLUENT 4. UNITS 5. INTAKE (optionan AND b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM CAS NUMBER a. TESTING b. BELIEVED c. BELIEVED(1) �a.AXIMUM DAILY VALUE (ijavailable) VALUE (ijavailable) 0. NO. OF a. CONCEN- rb. AVERAGE VALUE b. CENTRATION (2) MASS CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS CONCENTRATION (2) MASS (ijavailable) REQUIRED PRESENT ABSENT ANALYSES1 TRATION MASS NO. OF ANALYSES GC/MS FRACTION -VOLATILE COMPOUNDS (continued) 22V. Methylene Chloride (75-09-2) X x X <5.0 <0.18 N/A N/A N/A N/A 1 ug/1 lb/day Tetras 1 2,2- X . X <5.0 <0.18 N/A N/A N/A N/A 1 ug/1 lb/day 9-34-orcethane 9.34-5 24V. Tetrachtoro- ethylene(127-18-4) x X <5.0 <0.18 N/A N/A N/A N/A 1 ug/1 lb/day 25V.Toluene (108-88-3) �/ x �( <5.0 <0.18 N/A N/A N/A N/A 1 ug/1 lb/day 26V. 1,2-Trans- Dichloroethylene X X <5.0 N/A 156-60-5 <0.18 N/A N/A N/A 1 ug/1 lb/day 27V.1,1,1-Trichloro- X X <5.0 N ethane (71-55-6) <0.18 / A N A / N A / N A / 1 ug/1 lb/day 28V. 1,12-Trichloro- ethane (79-00-5) X <S _ 0 <0 . 18 N A / N A / N A / N A / 1 ug/1 lb/day 29V X X <5.0 N/A ene (7 - ethylene (79-01-0) / \ <0.18 N/A N/A N/A 1 ug/1 lb/day 30V. mehbro- flu ane ` , X ` , X <5.0 N/A 5.69-4 -69-4) <0.18 N/A N/A N/A 1 ug/1 lb/day (7�14)VinyChloride X X <5.0 <0.18 N/A N/A N/A N/A 1 ug/1 lb/day GC/MS FRACTION -ACID COMPOUNDS 1 A. 2-Chlorophenol (95-57-8) �/ x X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 2A. 2,4-Dichloro- phenol(120-83-2) x X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 3A.2,4-Dimethyl- phenol(105-67-9) X <10.0 <0.4 N A / N A / N A / N A / 1 u 1 g/ lb / da y 4A. 4,6-Dinitro-o- Cresol(534-52-1) X <20.0 <0.8 N/A N/A N/A N/A 1 ug/1 lb/day phenol(51-2ro- <50.0 <2.0 N/A N/A N/A N/A 1 ug/1 lb/day 6A.2-Nitrophenol (88-75-5) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 7A.4-Nitrophenol (100.02-7) �/ x X <50.0 <2.0 N/A N/A N/A N/A 1 ug/1 lb/day 8A. P-Chloro-M- Cresol(59-50-7) x X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 9A. Pentachloro- phenol (87-86-5) x <25 . 0 <1. 0 N A / N A / N A / N A / 1 u 1 g/ lb / da Y (10895-2) x u <5.0 1 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 11A.2,4,6-Trichloro- phenol (80-05-2) %< <10.0 <0.4 N A / N A / N A / N A / 1 ug/1 lb/day EPA Form joiv-2l: (if-yu) PAGE V-5 CONTINUE ON REVERSE II I E ! 1 1 1 a a CONTINUED FROM THE FRONT 1. POLLUTANT 2. MARK W 3. EFFLUENT 4. UNITS 5. INTAKE (optional) AND b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM CAS NUMBER TESTING b. BELIEVED C. BELIEVED a. MAXIMUM DAILY VALUE (ifavadlable) VALUE (ifavailable) d. NO. OF a. CONCEN- AVERAGE VALUE (1) CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS CONCENTRATION (2) MASS (ijavailable) REQUIRED PRESENT ABSENT ANALYSES TRATION b. MASS b. NO. OF ANALYSES GC/MS FRACTION - BASE/NEUTRAL COMPOUNDS 1 B.(3 2cenaphthene X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day ( Ac6-8'phtylene X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day (120-1 -7) (120-12-7) X <5.0 <0.2 N A / N A / N A / N A / 1 ug/1 lb/day 46. Benzidine (92-87-5) X -- Not requird per 40 CFR App D -- N/A N/A 5B. Benzo (a) (AnnttS�ne X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day �ene(5032-8) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 7B. 3,4-Benzo- (205-9 -2) (205-93-2) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 8B. Benzo (ght) PerAene (191-24-2) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 9B. Benzo (k) Fluoranthe (207-08-9) (2o7-oas) X <5.0 <0.2 N/A N/A N/A N/A 1 u 1 g/ lb da / Y 10B. Bis (1-Chloro- (1hoxy)11-9 Methane (111-91-1) <10 . 0 <0. 4 N A / N A / N A / N A / 1 ug/1 lb/day 11 B. Bis (2-Chloro- 1er (111 �4- 144-4) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 128. Bis (2- ChlorolsopropyQ EtherIt02-80-1) -- Not. re required per 40 CFR App D -- N/A N/A 13B. Bis (2-Ethyl- hexyg Phthalate (117-81-7) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 14B. 4-Bromophenyl Phenyl Ether (101-5 (101-55-3) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 15B. Butyl Benzy65-68- Phthalate Phthalate (8568-7) X <5 . 0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 16B. 2-Chloro- ene (91-587) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 17B. 4-Chloro- phenyl Phenyl Ether (7005-72-3) X <5. 0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day iBB.01-9) e &01-9) (21 X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 19B. Dibenzo (a,h) Anthrace (53.70.3) (53-70-3) X <5.0 <0.2 N/A NIA N/A N/A 1 ug/1 lb/day 20B. 1,2-Dichloro- benzene(95-50-1) x -- Not required per 40 CFR App D -- N/A N/A 21 B. 1,3-Di-chloro- benzene (541-73-1) x -- Not requiLredj per 40 CFR App D -- N/A N/A " k-w) PAGE V-6 CONTINUE ON PAGE V-7 a 1 I I I 1 I I I E Ia I a I I I L CONTINUED FROM PAGE V-6 1. POLLUTANT 2. MARK "X" 3. EFFLUENT 4. UNITS 5. INTAKE (opiion4 b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a. b. C. a. MAXIMUM DAILY VALUE (if-dable) VALUE (ijavailable) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) d. NO. OF a. CONCEN- (ijavailable) REQUIRED PRESENT ABSENT (1) (1) b. NO. OF CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES GC/MS FRACTION - BASEINEUTRAL COMPOUNDS (continued) 22B.1,4Dichloro- beenzene(106-46-7) x -- Not required per 40 CFR App D -- N/A N/A 238. 3,34Dichbro- benzidine(91-94-1) fx <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 24B. Diethyl Phthalate(84-66-2) <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 2513_ Dimethyl Phthalate (131 -11-3) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 266. Di-N-Butyl Phthalate(84-74-2) <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 276.2,4Dinitro- toluene(121-14-2) <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 28B. 2,6-Dindro- toluene(606-20.2) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 29B. Di-N-Octyl Phthalate(117434-0) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 30B. 1,2-Diphenyl- hydrazine (as Azo- benzene)(122-66-7) -- Not required per 40 CFR App D -- N/A N/A 31 B. Fluoranthene (206-44-0) x <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 32B. Fluorene (86.73-7) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 33B. Hexachloro- benzene(118-74-1) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 34B. Hexachloro- butadlene(87-68-3) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 35B. Hexachloro- cydopentadiene <10.0 <0.4 N/A N/A N/A N/A 1 ug/1 lb/day 36B Hexachloro- ethane (67-72-1) x 5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 37B.Indeno (1,2,3-cd) Pyrene (193-39-5) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day (78-59-1jhorone <10.0 <0.4 N/A N/A N/A N/A 1 ug/1 lb/day Naphthalene (9- X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 40B. Nitrobenzene (9&953) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 41B. N-Nitro- (odimetth)ylamine <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day 428. N-Nitrosodi- tnine B2-64-7) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/1 lb/day tern rurm 3510-2C (&90) PAGE V-7 CONTINUE ON REVERSE I I CONTINUED FROM THE FRONT POLLUTANT 2. MARK'X' 3. EFFLUENT 4. UNITS S. INTAKE (-prom!) 1. AND b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONGTERM CAS NUMBER a. b. C. a. MAXIMUM DAILY VALUE (ifavai able) VALUE (ifavailable) AVERAGE VALUE (ifavailable TESTING REQUIRED BELIEVED PRESENT BELIEVED ABSENT (1) CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS d. NO. OF ANALYSES a. CONCEN- TRATION b. MASS (1) CONCENTRATION (2) MASS b. NO. OF ANALYSES GC/MS FRACTION — BASEINEUTRAL COMPOUNDS (continued) 43B. N-Nitro- (8630he6n)�rne X <10.0 <0.4 N/A N/A N/A N/A 1 ug/l lb/day nanthrene 85-018) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/l lb/day 45B. Pyrene (129-00-0) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/l lb/day 468. 1,2,4-Tri- chtoro (120-8 -1) (120-82-1) X <5.0 <0.2 N/A N/A N/A N/A 1 ug/l lb/day GC/MS FRACTION — PESTICIDES 1P. Aldrin (309-00-2) Not 2P. a-BHC (319-84-6) required 3P. ft-BHC (319-85-7) per 40CFR 4P. y-BHC (58-89-9) Pt 122 5P, b-BHC (319-86-8) Appendix 6P. CNordane D (57-74-9) 7P. 4,4'-DDT (50-29-3) 8P. 4.4'-DDE (72-55-9) 9P. 4,4'-DDD (72-548) 10P. Dieldrin (60-57-1) 11 P. a-Enosutran (115-29-7) 12P.O-Endosutfan (115-29-7) 13P. Endosulfan Sulfate (1031-07-8) 14P.Endrin (72-20-8) 15P.Endrin Aldehyde (7421-934) 16P. Heptachlor (7644-8) crA Form 35iu-2V (8-aU) PAGE V-8 CONTINUE ON PAGE V-9 I t a EPA I.D. NUMBER (copyfrom liem 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-8 I NC0000396 001 I.POLLUTANT 2. MARK" 3. EFFLUENT 4. UNITS 5. INTAKE (opaonan ANDb. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. a. LONG TERM CAS NUMBER a. TESTING b. BELIEVED C. BELIEVED a. MAXIMUM DAILY VALUE (ifavailab/e) VALUE (ffavadable) AVERAGE VALUE (1) CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS (1favailable) REQUIRED PRESENT ABSENT d. NO. OF ANALYSES a_ CONCEN- TRATION b. MASS b. NO. OF CONCENTRATION (2) MASS ANALYSES GC/MS FRACTION — PESTICIDES (cominae� 17P. Heptachlor Epoxide Not (1024-57-3) 18P. PCB-1242 (53469 21-9) required 19P_ PCB-1254 (11097-69-1) per 40CFR 20P. PCB-1221 (11104-28-2) Pt. 122 21P. PCB-1232 (11141-16-5) Appendix 22P. PCB-1248 (12672-29-6) D 23P. PCB-1260 (11096.825) 24P. PCB-1016 (12674-11-2) 25P.Toxaphene (8001-35-2) EPA Form 3510-2C (8-90) PAGE V-9 I t t t 1t t a; t t t t t 1 t t t t I 11-OC C-MIN i UK I Trt IN i I It UIVSHADW AREAS ONLY. You may report some or all of this information EPA I.D. NUMBER (copyfrom Item 1 of Form /) on separate sheets (use the same format) instead of completing these pages. INCO000396 SEE INSTRUCTIONS. V. INTAKE AND EFFLUENT CHARACTERISTICS continued from OUTFALL NO. ( page 3 of Form 2 C) 001 (once through cooling PART A -You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2. EFFLUENT 3. UNITS (speck ifblank) 4. INTAKE (optional) a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE (ifavadable) c. LONG TERM AVRG. VALUE a. LONG TERM 1. POLLUTANTmi (if-dable) d. NO. OF a. CONCEN- AVERAGE VALUE b. NO. OF (1) CONCENTRATION (1> (2) MASS CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES a. Biochemical Oxygen Demand (BOD) 0 <2 <3062 N A / N/A N/A N/A 1 mg/1 lb/day b. Chemical Oxygen D Demand (COD) <25 . 0 <0 3828 NA / N A / N / A N/A 1 m 1 g/ lb da / y c. Total Organic Carbon (TOO 3.8 5818 N/A N/A N/A N/A 1 mg/1 lb/day d. Total Suspended Solids(TSS) <2.4 <3675 N/A N/A N/A N/A 1 mg/1 lb/day e. Ammonia (asN) 0.14 214.4 N/A N/A N/A N/A 1 mg/1 lb/day f.Flow VALUE 305.5 VALUE 305.5 VALUE 255.34 52 VALUE MGD N/A g. Temperature VALUE VALUE VALUE (winter) 34.5 30.8 29.7 151 'C VALUE h. Temperature VALUE VALUE VALUE VALUE (summer) 4 2.1 40.6 36.5 214 'C MINIMUM MAXIMUM MINIMUM MAXIMi. UM PH 6.7 8.2 7.6 8 .2 52 STANDARD UNITS PART B - Mark 'X" in column 2-a for each pollutant you know or have reason to believe is present Mark 'X' in column 2-b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, must the least you provide results of at one analysis for that pollutant For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additional details and requirements. 2. MARK `X' 3. EFFLUENT 4. UNITS 5. INTAKE (optionao 1. POLLUTANT AND a, b. a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE (ifavailable) c. LONG TERM AVRG. VALUE a. LONG TERM AVERAGE CAS NO. (ifavadable) BELIEVED PRESENT BELIEVED ABSENT 1 (1) (ifavailable) 1 d. NO. OF a. CONCEN- VALUE (1) CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION 2) MASS ( CONCENTRATION (2) MASS ANALYSES TRATION b. MASS ANALYSES a. Bromide v (24959-67-9) b. Chlorine. ,Total v Residual 110* 168.4* 87.5* 222.9* 74.2* 157.8* 60* Ug/1 c. Color X d. Fecal Coliform X e. Fluoride (16984A") f. Nitrate -Nitrite M X(as coe r__ ­ CONTINUE ON REVERSE * TRC analyzed when added t I t I< t I, I t t t t t t t ITEM V-R r:r1IJTIN119:11 9:QnU 9!Gr11JT t t t t 1. POLLUTANT 2. MARK'X' 3. EFFLUENT 4. UNITS 5. INTAKE (oprionao AND b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM CAS NO. a. BELIEVED b. BELIEVED a. MAXIMUM DAILY VALUE i available (f (rfav°d°ble) AVERAGE VALUE CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS Afavailable) PRESENT ABSENT d. NO. OF ANALYSES a. CONCEN- TRATION b. MASS b. NO. OF ANALYSES (1) CONCENTRATION (2) MASS g. Nitrogen, ` Total Organic (as X A) h.Oil and Grease <5.0 <7656 N/A N/A N/A N/A 1 mg/1 lb/da i. Phosphorus ` , (as P), Total X (7723-14-0) j. Radioactivity (1) Alpha, Total ` , X (2) Beta, Total X (3) Radium, Total (4) Radium 226, Total k. Sulfate (as SO,) (14808-79-8) 1. Sulfide S) \/ x (-' m. Sulfite (os SO,) (14265-45-3) n. Surfactants X o. Aluminum, Total v (7429-90-5) /� p. Barium, Total (7440-39-3) q. Boron, Total (7440-42-8) r. Cobalt, Total v (7440-48-4) s. iron, Total \/ (7439-89-6) x 82.5 <126 N/A N/A N/A N/A 1 ug/1 lb/da L Magnesium, Total X (7439-95-4) u. Molybdenum, Total x (7439-98-7) /� v. Manganese, Total x (7439-96-5) w. Tin, Total \/ (7440-31-5) x x Titanium, Total "' """ "-"'tom-"'i PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D. NUMBER (copvjrom item f afForm /) OUTFALL NUMBER CONTINIIFD FROM PAr:F s nF FnaM'3r INCO000396 1002 (Once thrnii hl PART C - If you are a primary industry and this outfall contains process wastewater, refer to Table 20-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark'X' in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2a (secondary industries, nonprocess wastewater outfalls, and nonrequifed GCYMS 'X' fracfons), mark in column 2-b for each pollutant you know or have reason to believe is present Mark 'X' in column 2-c for each pollutant you believe is absent If you mark column 2a for any pollutant, must you provide the results of at least one analysis for that pollutant If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylonitrie, 2,4 dinitrophenol, or 2-methyl-4, 6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See instructions for additional details and requirements. 1. POLLUTANT 2. MARK'X' 3. EFFLUENT 4. UNITS S. INTAKE (opitonal) AND b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM CAS NUMBER a. TESTING b. BELIEVED c. BELIEVED a. MAXIMUM DAILY VALUE (ijavailable) VALUE (ijavailable) d. NO. OF a. CONCEN AVERAGE VALUE CONCENTRATION (Z) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS (ijava/lable) REQUIRED PRESENT ABSENT ANALYSES - TRATION b. MASS b. ANALOY ES METALS, CYANIDE, AND TOTAL PHENOLS 1 M. Antimony, Total v (7440-36-0) 2M. Arsenic, Total v (7440-38-2) 3M. Beryllium, Total (7440-41-7) 4M. Cadmium, Total v (7440-43-9) 5M. Chromium, v Total (7440-47-3) 6M. Copper,-50-8)Total (7440 X <5. 0 <7 . 65 N/A N/A N/A N/A 1 ug/1 lb/day 7M. Lead, Total v (7439-92-1) 8M. Mercury, Total �/ (7439-97-6) 9M. Nickel, Total v (7440-02-0) 10M. Selenium, v Total (7782-49-2) 11 M. Silver, Total v (7440-22-4) 12M. Thallium, v Total (7440-28-0) 13M. Zinc, Total v (7440-66-6) 14M. Cyanide, Total(57-12-5) 15M. Phenols, Total DIOXIN 2,3,7,8-Tetra- DESCRIBE RESULTS chlorodibenzo-P- x Dioxin (1764-01-6) PAGE V-3 CONTINUE ON REVERSE i II t t I i I a I t' I ! I I a a [ t rMiTINI IFr) PPMA TUG COMIT 1. POLLUTANT 2. MARK'X' 3. EFFLUENT 4. UNITS S. INTAKE o aona (P !% AND b. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. a. LONG TERM CAS NUMBER a. TESTING b. BELIEVED C. BELIEVED a. MAXIMUM DAILY VALUE (if --able) VALUE (ifavailable) AVERAGE VALUE (1) CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS (ijavailable) REQUIRED PRESENT ABSEN7 d. NO. OF ANALYSES a. CONCEN- TRATION b. MASS ANALOYSES GC/MS FRACTION —VOLATILE COMPOUNDS 1 V. Accrolein v (107-02-8) 2V. Acrylonitrile ` / (107-13-1) n 3V. Benzene ` (71.43-2) n 4V. Bisyl) h ` , mrUryl) Etther X (542438-1) 5V. Bromoform (75-25-2) 6V. Carbon Tetrachloride (56-23-5) 7V. Chlorobenzene (108-90-7) 8V. i- ` , bromomethemethane X (124-48-1) 9V. Chloroethane (754K)-3) 1 W. 2-Chloro- ethylvinyl Ether (110-75-8) 11 V. Chloroform (67-W3) n 12V. Dichloro- bromomethane (75-27-4) 13V. Dichloro- difluoromethane (75-71-8) 14V.1,1-Dichloro- v ethane (75-34-3) 15V.1.2-Dichioro- ethane (107-06-2) 16V. 1,1-Didlloro- v ethylene (75-35.4) 17V. 1,2-Dichloro- v propane (78-87-5) 3-Diddoro- propylene propyl ` , X (542-75-6) 19V. Ethylbenzene (100-41-4) 20V. Methyl Iv Bromide (74-83-9) 21V. Methyl Chloride (74-87-3) PAGE V-4 CONTINUE ON PAGE V-5 I a' I ! 1 I I t I t I a a - I I t t I CONTINUED FROM PAGE V-4 I.POLLUTANT 2. MARK'X' 3. EFFLUENT 4. UNITS 5. INTAKE (optio no AND b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM a, b. C. a. MAXIMUM DAILY VALUE (ijavailable) VALUE (ijavailable) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED I d. NO. OF a. CONCEN-b AO SES (favailable) REQUIRED PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS GC/MS FRACTION — VOLATILE COMPOUNDS (continued) 22V. Methylene v Chloride p5-09-2) 23V.1,1,2,2- Tetrad Ioroethane 9.34-5 24V. Tetrachloro- ethylene (127-18-4) 25V. Toluene (108-88-3) 26V.1,2-Trans- Dichloroethylene - X 156-60 5 27V. 1,1,1-Trichloro- ethane (71-55-6) 28V. 1,1,2-Trichbro- \/ ethane (79-00-5) x 29V Trichloro- ethylene (79-015) 30V. eh fluorenimethane ane ` , X 5-69-4 31 V. Vinyl Chloride (75-01-4) GC/MS FRACTION — ACID COMPOUNDS 1A. 2-Chloraphenol (9557-8) 2A. 2,4-DichWo- phenol (120-83-2) 3A. 2,4-Dimethyl- v phenol(105-67-9) 4A. 4,6-Dinitro-0- �/ Cresol (53452-1) 5A. 2,4-D'rnitro- phenal (51-28-5) 6A. 2-Nitrophenol (88-75-5) 7A. 4-Nitrophenol �/ (100-02-7) 8A. P-Chloro-M- v Cresol (59-50-7) 9A. Pentachloro- �/ phenol (87-86-5) x 10A. Phenol {108-95-2) 11A 2,4,6Trichloro v------- - -T phenol (88-05-2) I c— lonn oa rv-«, (8-90) PAGE V-5 CONTINUE ON REVERSE I I AI CONTINUED FROM THE FRONT 2. MARK "X' 3. EFFLUENT 4. UNITS 5. INTAKE (opa wo 1. POLLUTANT b. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. a. LONG TERM AND a, b. a a. MAXIMUM DAILY VALUE (if --able) VALUE (ifavailable) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d. NO. OF a. CONCEN- b. NO. OF (iJavailable) REQUIRED PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASSANALYSES GC/MS FRACTION — BASE/NEUTRAL COMPOUNDS 1 B. Acenaphthene (83-32-9) Not 2B. Acenaphtylene (208-96-8) required 3B. Anthracene (120-12-7) per 40CFR 4B. Benzidine (92-87-5) PT 122 5B. Benzo (a) Anthracene (56.55-3) Appendix 68. Benzo (a) Pyrene (50-32-8) D 7B. 3,4-Benzo- fluoranthene (205-99-2) 8B. Benzo (ghr) Perylene (191-24-2) 9B. Benzo (k) Fluoranthene (207-)8-9) 101B. Bis (1-Chlmv- elhoxy) Methane (111-91-1) 11 B. Bis (1-Chloro- erhyl) Ether (111-44.4) 128. Bis (2- Chlororsopropy4 Ether (102-80-1) 13B. Bis (2-Erhyl- hexA Phthalate (117-81-7) 148. 4-Bromophenyl Phenyl Ether (101-55-3) 15B. Butyl Benzyl Phthalate (8568 7) 131 2-CNoro- naphthalene (91-58-7) 178.4-Chloro- phenyl Phenyl Ether (7005-72-3) 18B. Chrysene (218-01-9) 198. Dibenzoj(.,h)Anthracene(53-70-3) 20B. 1,2-Dichbenzene (W 21 B. 1,3Di-chloro- benzene (541-73-1) EPA Fnrm 351n-9r. rsLani PAGE V-6 CONTINUE ON PAGE V-7 m 71 CONTINUED FROM PAGE V-6 1. POLLUTANT 2. MARK'X 3. EFFLUENT 4. UNITS 5. INTAKE o aoda (P 4 b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. AND a b. a a. MAXIMUM DAILY VALUE (ifavadable) VALUE (ifavailable) a. LONG TERM AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED d. NO. OF a. CONCEN- (ifavaitabte) REQUIRED PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS (1) b. NO. OF CONCENTRATION (2) MASS ANALYSES GC/MS FRACTION — BASE/NEUTRAL COMPOUNDS (continue 22B.1,4-Oichloro- benzene (106-46-7) Not 23B. 3,3-Dichloro- benzidine (91-94-1) required 248. Diethyl Phthaiate(84-66-2) per 40CFR 25B. Dimethyl Phthalate (131 -11-3) pt 122 26B. Di-N-Butyl Phthalate (84-74-2) Appendix 27B. 2,4-DiniUo- toluene (121-14-2) D 288.2,6-Dinitro- toluene (606-20-2) 29B. Di-N-Octyl Phthalate (117-84-0) 30B.1,2-Diphenyl- hydrazine (as Azo- benzene)(122-66-7) 31 B. Fluoranthene (206-44-0) 32B. Fluorene (86-73-7) 338. Hexachloro- benzene (118-74-1) 34B. Hexachloro- butadiene (87-68-3) 35B. Hexachloro- cydopentadiene (77-47-4) 36B Hexachloro- ethane (67-72-1) 37B.Indeno (1,2.3-cd) Pyrene (193-39-5) 38B.Isophorone (78.59-1) 398. Naphthalene (91-20-3) 408. Nitrobenzene (98-95-3) 41B. N-Nitro- sodimethylamine (62-75-9) 42B. N-Nilrosodi- N-Propylai (621-64-7) FDA L..— —n on io nn. PAGE V-7 CONTINUE ON REVERSE e CONTINUED FROM THE FRONT 1. POLLUTANT 2. MARK'X' 3. EFFLUENT 4. UNITS S. INTAKE o on (P Ir b. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. a. LONG TERM AND a. b. c. �"MAXIMUM DAILY VALUE (ijavailable) VALUE (ijavoilable) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1)d. NO. OF a. CONCEN-b. NO. OF (javailable) REQUIRED PRESENT ABSENT NCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS 1 ANALYSES CONCENTRATION (2) MASS GC/MS FRACTION — BASEMEUTRAL COMPOUNDS (continued) 43B. N-Nitro- sodiphenylamine Not (8630-6) 44B.Phenanthrene (85-01-8) required 45B. Pyrene (129-00-0) per 40CFR 46B.1,2,4•Tri- chlorobenzene (120-82-1) Appendix D GC/MS FRACTION — PESTICIDES 1 P. Aldrin (309-00-2) Not 2P. a-BHC (S19-84-6) required 3P. Q-BHC (319-85-7) per 40CFR 4P, y-BHC (58489-9) Pt 122 5P. SBHC (319-86-8) Appendix 6P. Chlordane (57-74-9) D 7P. 4,4'-DDT (50-29-3) 8P. 4,4'-DDE (72-55-9) 9P. 4,4'-DDD (72 `4-8) 10P. Dieldrin (60-57-1) 11 P. a-Enosulfan (115-29-7) 12P. VEndosulfan (115-29-7) 13P. Endosutfan Sulfate (1031-07-8) 14P. Endrin (72-20.8) 15P. Endrin Aldehyde (7421-93-4) 16P. Heptachlor (764") FPA;:— ssln-qr m-an% vmt V-ts CONTINUE ON PAGE V-9 I EPA I.D. NUMBER (copyfromltem 1 of Form 1) OUTFALL NUMBER NC0000396 1002 (once throu hCONTINUED FROM PAGE V-89 ) I.POLLUTANT 2. MARK W 3. EFFLUENT 4. UNITS 5. INTAKE (opiionao AND b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM CAS NUMBER a b. C. a. MAXIMUM DAILY VALUE (if —actable) VALUE (if—d-ble) AVERAGE VALUE (ija dable) TESTING ING REQUIRED BELI PRESENT BELIEVED ABSENT d. NO. OF a. CONCEN- CONCFNNTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS NALYSES GC/MS FRACTION — PESTICIDES (continued) 17P. Heptachlor EpOwae Not (1024-57-3) 18P. PCB-1242 (53469-21-9) required 19P. PCB-1254 (11097-69-1) per 40CFR 20P. PCB-1221 (11104-28-2) Pt. 122 21P. PCB-1232 (11141-16-5) Appendix 22P. PCB-1248 (12672-29-6) D 23P. PCB-1260 (11096-82-5) 24P. PCB-1016 (12674-11-2) 25P.Toxaphene (8001-35-2) -<., ka- 1 PAGE V-9 wia aril raW EPA ID Number (copy fromItem 1 of Form 1) Plaasa nrint nr tvna in the nnchnei—i —, ...,k, NC00003 96 Form Approved, OMB No. 2040-0086 FORM ZF NPDES U.S. Environmental Protection Agency E PA Washington, DC 20460 . Application for Permit to Discharge Storm Water Discharges Associated with Industrial Activity Paperwork Reduction Act Notice Public reporting burden for this application is estimated to average 28.6 hours per application, including time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding the burden estimate, any other aspect of this collection of information, or suggestions for improving this form, including suggestions which may increase or reduce this burden to: Chief, Information Policy Branch, PM-223, U.S. Environmental Protection Agency, 1200 Pennsylvania Avenue, NW, Washington, DC 20460, or Director, Office of Information and Regulatory Affairs, Office of Management and Budget, Washington, DC 20503. I. Outfall Location For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A. Outfall Number (list) B. Latitude C. Longitude D. Receiving Water (name) SW-1 35 1 28 02 82 32 13 Lake Julian SW-2 35 1 27 51 82 32 05 Lake Julian SW-3 35 27 55 82 32 06 Lake Julian SW-4 35 28 39 82 32 46 Lake Julian SW-5 35 28 29 82 32 51 Unnamed tributary to Powell Creek $W-6 35 28 23 82 32 45 Lake Julian Il. Improvements A. Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading or operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders, and grant or loan conditions. 1. Identification of Conditions, Agreements, Etc. 2. Affected Outfalls 3. Brief Description of Project 4. Final om Compliance Date number source of discharge a. b. proj. N/A B: You may attach additional sheets describing any additional water pollution (or other environmental projects which may affect your discharges) you now have under way or which you plan. Indicate whether each program is now under way or planned, and indicate your actual or planned schedules for construction. III. Site Drainage Map Attach a site map showing topography (or indicating the outline of drainage areas served by the outfails(s) covered in the application if a topographic map is unavailable) depicting the facility including: each of its Intake and discharge structures; the drainage area of each storm water outfall; paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for outdoor storage of disposal of significant materials, each existing structural control measure to reduce pollutants in storm water runoff, materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied; each of its hazardous waste treatment, storage or disposal units (including each area not required to have a RCRA permit which is used for accumulating hazardous waste under 40 CFR 262.34); each well where fluids from the facility are injected underground; springs, and other surface water bodies which received storm water discharges from the facility. EPA Form 3510-2F (1-92) Page 1 of 3 Continue on Page 2 M 177 Continued from the Front IV. Narrative Description of Pollutant Sources A. For each outfall, provide an estimate of the area (include units) of Imperious surfaces (including paved areas and building roofs) drained to the outfall, and an estimate of the total surface area drained by the outfall. Outfall Number Area of Impervious Surface Total Area Drained Outfall Area of Impervious Surface Total Area Drained (provide units) (provide units) Number (provide units) (provide units) SW-1 0.34 acres 3.69 area SW-4 0.09 acres 5.5 acres SW-2 0.13 acres 0.38 acres SW-5 0.09 acres 4.0 acres SW-3 0.84 acres 9.06 acres SW-6 0.18 acres 7.6 acres -- a „a, iauve ucsunpnon or sigrnncam materials that are currently or in the past three years have been treated, stored or disposed in a manner to allow exposure to storm water; method of treatment, storage, or disposal; past and present materials management practices employed to minimize contact by these materials with storm water runoff; materials loading and access areas, and the location, manner, and frequency in which pesticides, herbicides, soil conditioners, and fertilizers are applied. to See attachment 6 C. For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in storm water runoff; and a description of the treatment the storm water receives, Including the schedule and type of maintenance for control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge. rill Outfail List Codes from Number Treatment _ Table2F-1 V. Nonstormwater Discharges arr A.I cer tify under penalty of law hat the outfall(s) covered by this application have been tested or evaluated for the presence of nonstormwater discharges, and that all nonstormwater discharged from these outfall(s) are identified in either an accompanying Form 2C or From 2E application for the outfall. Name and Official Title (type or print) Signature Date Signed YID Laurie Moorhead, Env. Specialist ` ^ / / 16fictle .X.-' B. Provide a description of the method used, the date of any testing, and the onsite drainage points that were directly observed during a test. rli On an annual basis, the Asheville Plant Environmental Specialist conducts a visual inspection of all stormwater outfalls during an extended period of dry weather. This visual inspection serves to ensure that there are nunpermitted discharges from the permitted stormwater outfalls. Certification statements are signed, dated and kept onsite beo hind Tab 5 Annual Certification Page of the SWPPP. Dates for previous certifications include: April 16, 2010, April 23, 2009 I. Significant Leaks or Spills Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three years, including the rna approximate date and location of the spill or leak, and the type and amount of material released. here have been no leaks of spills of toxic or hazardous pollutants on the old or new access roads in the past three years. EPA Form 3510-2F (1-92) In Page 2 of 3 Continue on Page 3 so 0 --I Continued from Page 2 NC000039eD Number (copy from Item f ofForm f) /II. Discharge Information A. B. C, & D: See instructions before proceeding. Complete one set of tables for each outfall. Annotate the outfall number in the space provided. Table VII-A, VII-B, VII-C are included on separate sheets numbers VII-1 and VII-2_ E. Potential discharges not covered by analysis — is any toxic pollutant listed in table 2F-2, 2F-3, or 2F-4, a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct? © Yes (list all such pollutants below) ❑ No (go to Section IX) The following elements could be present in coal and/or oil: Antimony Arsenic Beryllium Cadmiun Chromium Lead Mercury Nickel Selenium Silver Thallium Zinc VIII. Biological Toxicity Testing Data Do you have any knowledge or reason to believe that any biological test for acute relation to your discharge within the last 3 years? or chronic toxicity has been made on any of your discharges or on a receiving water in ❑ Yes (list all such pollutants below) Q✓ No (go to Section IX) IX. Contract Analysis Information Were any of the analyses reported in Item VII performed by a contract laboratory or consulting firm? © Yes (list the name, address, and telephone number of, and pollutants ❑ No (go to Section X) analyzed by, each such laboratory or firm below) A. Name B. Address C. Area Code & Phone No. D. Pollutants Analyzed Pace Analytical Services, Inc. 2225 Riverside Drive (828)254-7176 All Asheville, NC 28804 X. Certification I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the of fine Imprisonment possibility and for knowing violations. A. Name & Official Title (Type Or Print) B. Area Code and Phone No. Garry A. Whisnant, Plant Manager (828) 687-5201 C. Signature D. Date Signed -Z 'Y , j '/' �� e1/o%(a - rviiji Jv Iv-Lr tl-vz) Page 3 of 3 do rW EPA ID Number (copy from Item 1 of Form 1) Form Approved. OMB No. 2040-0086 C0000396 Approval expires 5-31-92 V11. Discharge information (Continued from page 3 of Form 2F) rrr Part A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. Maximum Values Average Values (include units) (include units) Number Pollutant Grab Sample Grab Sample of and Taken During Taken During Storm CAS Number First 20 Flow -Weighted First 20 Flow -Weighted Events (if available] n�,. 4.. _ .. . . _ t am a 0 111111111 M Orland Grease <5.0 mg/l N/A 1 Below detection level Biological Oxygen Demand(BOD5) 4.6 mg/l 2.0 mg/1 1 Decaying vegetation Chemical Oxygen Demand (COD) 432 mg/1 64.o mg/1 1 Decaying vegetation Total Suspended Solids(TSS) 426 mg/l 92.7 mg/l 1 Erosion, Settled dust and debris Total Nitrogen 4.9 mg/l 2.1 mg/1 1 Fertilizer Total Phosphorus 0.79 mg/l 0.18 mg/1 1 Fertilizer pH Minimum 6.7 Maximum 6.7 Minimum Maximum 1 Part B - List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES permit for its process wastewater (if the facility is operating under an existing NPDES permit). Complete one table for each outfall. See the instructions for additional details and requirements. Pollutant and CAS Number (ifavailable) Maximum Values (include units) Average Values (include units) Number of Storm Events Sampled Sources of Pollutants Grab Sample Taken During First 20 Minutes Flow -Weighted Composite Grab Sample Taken During First 20 Minutes Flow -Weighted Composite Total Copper 68.5 ug/l 11.8 ug/l 1 Total Iron 38300 ug/1 7230 ug/l 1 Total Arsenic 46.4 ug/1 13.6 ug/1 1 Total Selenium <10 ug/1 <10 ug/l 1 Total Silver <5.0 ug/l <5.0 ug/1 1 Total Thallium <10 ug/l <10 ug/1 1 TKN 4.5 mg/l 1.9 mg/1 1 Nitrate -Nitrite 0.40 mg/1 0.15 mg/1 1 Total Mercury 0.33 ug/1 <0.2 ug/1 1 Total Beryllium 3.4 ug/1 <0.1 ug/1 1 Total Cadmium <1.0 ug/l <1.0 ug/1 1 Total Chlorides 69.4 mg/l 31.3 mg/1 1 Total Chromium 43.4 ug/1 7.8 ug/1 1 Total Flouride <0.10 mg/1 <0.10 mg/1 1 Total Lead 45.8 ug/l 7.3 ug/l 1 Tot. Managanese 1010 ug/l 125 ug/l 1 Total Nickel 32.2 ug/l 5.2 ug/1 1 Total Zinc 325 ug/1 54.1 ug/1 1 TRC+ 250 ug/li 1 + Possibly analytical inteference from naturally occurring manganese and/or turbidity in the sample. Result from TRC grab sample at end sampled outfall SW-3 only due to representative outfall sta tus of Sw sampling event was 20 ug/l. No known source. arm ruirn oo-iu-cr tl-az) Page VII-1 Continue on Reverse Continued from the Front Part C - List each pollutant shown in Table 2F-2, 2F-3, and 2F-4 that you know or have reason to believe is present. See the instructions for additional details and requirements. Complete one table for each outfall. Maximum Values Average Values (include units) (include units) Number Pollutant Grab Sample Grab Sample of and Taken During Taken During Storm CAS Number First 20 Flow -Weighted First 20 Flow -Weighted Events (if available) Minutes Composite Minutes I Composite Sampled Sources of Pollutants Part D — Provide data for the storm event(s) which resulted in the maximum values for the flow weighted composite sample. Date of Storm Event 2' Duration of Storm Event (in minutes) 3. Total rainfall during storm event (in inches) 4. Number of hours between beginning of storm measured and end of previous measurable rain event 5. Maximum flow rate during rain event (gallons/minute or specify units) 6• Total flow from rain event (gallons or specify units) 3/11/2010 210 minutes 0.39 on 3/11/2010 (during sampling). Precipitation over the next four days totaled 1.81 inches. 168 hours 20.6 GPM 9,548 gallons from outfall SW-3 during sampling event. 7. Provide a description of the method of flow measurement or estimate. A container with a known volume and a stopwatch was used to measure flow from SW outfall pipe. -, -, v,m k,-oy Page VII-2 ism I+ Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc. Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 Attachment 1 Form 1— Item XI - Map M c L f t M. i jjaid �I� �� —�q �'i ♦' n r(f',i Party a'yI-� ,�•'�� /� a;i � '!�� t _�;� .�1 f 'l 1 `� .r i S _ 4 �'a \,�i ♦ p�l'4�p '. 7 i v a / oF� ��sv� -'• rr '� " r "l 1f �.• )NJ (1161 i { A• mod..'- _ \ .. It r-. r lJ �„�•� ��$ /t 1 Atyd�.. Lam., \\ 1. ., .. UFe I jj•ra > Y _ vr� , Asheville Plant ' r;.,. 8�en ��C (i 1 Aotlefe V ��c•, f� l K• W.1 � a . r Post on b } <t tw a.. ' �, rt -�•Q �:.4 � — • l a �1 � rA �.. .7M7fr"pa , � t`X�" r �nbb , t n _•� � >"] UE 04'- ,/ r 1spr� Cfercr'6 ptar 1 Qu: 1 s .ate n� l` Tr6riw �; • 4 / { Est- 1 : S • 44IF N 0 600 1,200 2,400 3,600 4,800 we Feet a Attachment 1 — Form 1 — Item XI — Map Carolina Power & Light Company Asheville Steam Electric Plant Buncombe County Page 1 of 2 June 2010 n' , I yia nd ' '' '• • .� _ f'1t1+ .r' i '-a•�" "b i��! i`J f'a y Na b11 •T o ers Ai Spry40 • -'" :. e , Na- r .f t .I; tell r h ko �° ►^' • T� ui �1 ._ f i��(�? /;-�.i � 1 r-'., _.-,, �y id,t �Qt' r "`i ` ji r t� �_.. s� •�`�' , . � +jy� r ,..n — . J i f Shoals r'••. t Proposed relocation f '�%' '� ' fit ' of Outfall 001 '-• "` .„ � � .,_„ \ .�� "J `+_ter-••4, � ✓� • ""'� ° , - Jt1liS l+ran U -... � � . �\ -:+r• ---•wfthevi • ant '. •+ . ,Co pile;_'''- ,r J � � 4 Outfa11002 0,4 i �0 jW Outfall001 r " •„ �,.,/� ` .,yam yk •r \ z. • 660 330 0 660 1,320 1,980 Feet a Attachment 1 — Form 1 — Item XI — Map Carolina Power & Light Company Asheville Steam Electric Plant Buncombe County Page 2 of 2 June 2010 Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc. Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 Attachment 2 Form 2C Item II —A Line drawing for Flows, Sources of Pollution and Treatment Technologies I I 1 I t I t I I t I I I I I I a a I French Broad Make -Up Consumptive River Water intake Loss Stormwater -� 1964 Ash Pon Evaporation X Flue Gas Dam Seepage D Settling Desulfurization V Clarifier Zone Y Equalization o; Basin o; Units 1 & 2 S Lake Julian 0" B Condensers Outfall 002 01 Lake N Intake o; Julian Structure Circulating Water F o; to Heat Exchanger Ash Sump; U Oi U Diesel T i oI re Pum Fire Preheater Ash Evaporation o; AA Protection Cleaning Sluice in Boilers W System Water Water TL !'' 31 Service Water Q Vendor supplied R Chemical Metal Cleaning 01 water treatment Waste G �; Constructed 2I Wetland �; (Alt.) 111 Combustion M Turbine Site -' -' -' Z 1 1982 Low Volume E 30 Ash Pond Secondary French Broad Waste Sources Settling River Basin A Outfall001 Storm Wate J H K Coal Pile Dam Seepage Public Potable and C Public Runoff Attachment 2 - form 2C - Item ILA Flows, sources of Water Sanitary Sewage Evaporation P Treatment nol ; es Supply System System Carolina Power a I inhr r%nm.,— a�,. n ------ Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc. to Asheville Steam Electric Plant — NPDES Permit Number NC0000396 Attachment 2 Form 2C - Item II -A Flow, Sources of Pollution, and Treatment Technologies Stream Name Average Flow Comments A Ash Pond Discharge 3.52 MGD Outfall 001 B Intake to Once -through Cooling & Circulating Water to Heat Exchangers 255.1MGD C Plant Potable and Sanitary Uses 0.002 MGD From POTW D F Makeup to Lake from River I nw Vn6 imo 1A/..+co 2.68 MGD 2009 Average • Ash Hopper Seals • Sandbed Filter Backwash • Boiler Blowdown • Truck Wash • Water Purification process waste streams 0.05 MGD 2600 Gal/event 0.006 MGD Variable variable Rare Usage Startup - Estimated F Circulating Water from Heat Exchangers 19.3 MGD Estimated G Ash Sluice Water 3.03 MGD Estimated H Dam Seepage 0.09 MGD Calculated I City Water Supply to Boiler Makeup 0 MGD Rare Usage J Coal Pile Runoff 0.01 MGD Based on Average Annual Rainfall of 47" and 50 % Runoff K Storm Water 0.07 MGD Estimated L Chemical Metal Cleaning Wastes 0 - 90,000 Gallons (0 gallons anticipated) Normal Practice is Evaporation M Water From Combustion Turbine Facility Operation (Blade wash activities) 0 - 0.02 MGD Intermittent N From Lake to Intake 256.59 MGD Estimated O Intake to Service Water 0.05 MGD Estimated Q Fire Protection Water 0.010 MGD Estimated R Air Preheater Cleaning 10,000 gallons/event Estimated S Discharge to Lake Julian 255.1 MGD T Emergency Fire Protection Water 0 Used for fire fighting Outfall 002 -Calculated U Diesel Fire Pump to Lake Julian 0.128 MG/week Estimate - pump testing V Flue Gas Desulfurization Blowdown 0.086 MGD Calculated X Intake to FGD system 01.08 MGD Y Chloride Dilution Water 0.35 MGD z Constructed Wetland Discharge 0.376 MGD Outfall 005 AA Makeup water sup I 22 Million allons/ ear I Calculated Attachment 2 - form 2C - Item IIA Flows, Sources of Pollution, and Treatment Technologies Carolina Power & Light Company d/b/a/Progress Energy Carolinas, Inc. Asheville Steam Electric Plant Buncombe County June 2010 Page 2of 2 • Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc. Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 Attachment 3 Form 2C — Item II-B Description of Flows, Sources of Pollution and Treatment Technologies at r -1 Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc. Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 Attachment 3 Form 2C - Item II-B Flow, Sources of Pollution, and Treatment Technologies The Asheville Steam Electric Plant is located in Arden, North Carolina south of Asheville, North Carolina. The Asheville Steam Electric Plant is a coal-fired, steam cycle electric generating plant with two generating units. Two Internal Combustion (IC) Turbines are also located on the plant site. The plant has a 320-acre cooling lake (Lake Julian) on the east side of the French Broad River in Buncombe County, North Carolina. Chemical constituents contained in the discharges from this plant will, in part be representative of the naturally occurring chemical quality of the intake water and will also have chemical constituents of such quality and quantity associated with similar discharges for fossil generating facilities of this size, type and in this geographical location. Either all or part of the elements listed on the Periodic Table, either singularly or in any combination, may from time to time be contained in the discharge. Outfall 001 - Discharge from Ash Pond to French Broad River The Plant's ash pond (hereinafter referred to as the 1982 ash pond), is located east of the French Broad River, south of the plant and discharges into the French Broad River. The ash pond receives ash sluice water, various low volume wastes, coal pile runoff, limestone pile runoff, gypsum pile runoff, air pre -heater cleaning water, lire protection system drainage, chemical metal cleaning wastes (potentially), storm water and other waters from the Combustion Turbine Facility on the Plant's site. Wastewater from the plant's truck wash and weigh stations also are directed to the plant's 1982 Ash Pond. Accumulated water within the boundaries of the old ash pond (hereinafter referred to as the 1964 ash pond) may also from time to time be transferred to the 1982 pond. The plant will also be considering installation of a reverse osmosis system to treat water for plant process uses. Reject water from this plant process system will be sent to the ash pond. The pond provides treatment by sedimentation and neutralization to the above -referenced individual waste streams. Water leaves the 1982 ash pond via a standpipe with skimmer and flows by pipe and lined ditch to a secondary basin, where it is discharged by overflow to a ditch that coveys it to the French Broad River. Toe Oft M Carolina Power & Light Company Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 drains from both the 1982 pond and the 1964 pond drain to the French Broad River. Detailed descriptions of the individual waste streams are below. ift Ash Sluice Water Fly ash and bottom ash from both units are hydraulically conveyed by an ash sluice pipeline to r the ash pond. As needed, alum is added to the ash sluice influent to aid settling. A Selective Catalytic Reduction system (SCR) is operated on both Unit 1 and Unit 2 for NOx emissions control. Urea is injected to reduce NOx emissions. A byproduct of this process is an "ammonia slip" which will be carried to the 1982 ash pond via ash sluice water. As necessary, a system to mitigate SO3 emissions may also inject additional ammonia into the combustion process. This mitigation system has not been needed to date but may become necessary as fuel sources change. Various boiler sediments and ash accumulations collected during maintenance activities may also be transported to the 1982 ash pond. The ash pond discharge flows into the secondary settling pond where it combines with the FGD treated wastewater prior to discharging to the French Broad River. Progress Energy plans to relocate this secondary settling pond and discharge point during the term of this permit to facilitate modifications designed to enhance the 1964 ash pond dam's safety factor. Coal Pile Runoff Storm water runoff from the coal pile is collected in drainage ditches that surround the coal pile. The drainage ditches are routed to the 1982 ash pond for treatment. During maintenance activities, sludges removed from catch basins, sumps, etc. may be transported to either the 1982 ash pond or the 1964 ash pond for disposal. Limestone and Gypsum Piles Runoff do Storm water runoff from the limestone and gypsum piles is collected in drainage ditches which are routed to the 1982 ash pond for treatment. During maintenance activities, sludges removed �` from catch basins, sumps, etc, may be transported to the 1964 ash pond and/or the 1982 ash pond for disposal. C7 Storm Water Storm water runoff from the plant area, parking lots, combustion turbine area, oil storage and handling facility and the plant's substations is routed to the ash ponds for treatment. During E Carolina Power & Light Company Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 maintenance activities, sludges removed from catch basins, sumps, etc. may be transported to the 1964 ash pond and/or the 1982 ash pond for disposal. Low Volume Wastes Boiler water make up is withdrawn from Lake Julian and purified utilizing vendor supplied equipment. Boiler water is treated with ammonia, hydrazine, and sodium hydroxide. Boiler blowdown and drainage is sent to the ash pond and may contain small quantities of the chemicals. A new Reverse Osmosis system or alum coagulation/filtration service will be used in conjunction with the vendor supplied equipment to provide water for various plant processes. The reject stream from the Reverse osmosis unit will be sent to the 1982 ash pond. .Some molybdate waste from the closed cooling water system is created through valve leakage and maintenance activities and is discharged to the 1982 ash pond. A furnace ash hopper seal is maintained by using plant service water. A standard operation water level is maintained in a seal trough for the ash hopper seal. Overflow from this trough is discharged to the 1982 ash pond. A sodium hydroxide solution is fed into this flow stream as necessary for ash pond pH adjustment. Sulfuric acid is fed to the ash sluice water as necessary for 1982 ash pond pH adjustment. Coal dust suppression is achieved by spraying a proprietary chemical on coal at r different stages of coal use. Small amounts of excess dust suppression chemical have the potential to be discharged to the 1982 ash pond via plant drains or coal pile runoff. Small amounts of urea waste from bulk urea unloading operations are discharged to the 1982 ash pond. All plant area floor drains are routed to the 1982 ash pond and include equipment drainage and wash down along with rainfall runoff. During maintenance activities sludges removed from catch basins, sumps, etc. may be transported to the 1982 ash pond and/or the 1964 ash pond for disposal. In many cases, added chemicals are consumed or chemically altered during the plant processes. Only trace amounts might be recoverable in water entering the 1982 ash pond. Detectable levels of these chemicals would not be expected to occur in ash pond discharges. Flue Gas Desulfurization Blowdown (Low Volume Waste) The Flue Gas Desulfurization (FGD) system directs flue gas into an absorber where a limestone (calcium carbonate) slurry is sprayed. Sulfur dioxide in the flue gas reacts with the limestone to +wr produce calcium sulfate (gypsum). This system reclaims any unreacted limestone slurry to be r„ 3 o Carolina Power & Light Company Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 reused in the absorber. A small blowdown stream is used to maintain the chloride concentration in the reaction tank. The blowdown stream is passed through a clarifier to remove solids and the chloride concentration in the waste stream is diluted using water from Lake Julian. Chemicals are used to adjust pH and to aid solids removal in the clarifier. A constructed wetland is used to remove metals, mercury and selenium specifically, and the treated wastewater is discharged into the secondary settling pond. Air Preheater Cleaning (Low Volume Waste) The air preheater will be water washed once per year or more frequently as needed. The wastewater from this activity will be discharged to the 1982 ash pond. Chemical Metal Cleaning Wastes The boilers are chemically cleaned every five -to -eight years using Tetraammonia ethylene diamine tetraaccetic acid (EDTA) solution. This cleaning solution and its rinses are stored on site for disposal by evaporation in an operating unit's furnace. Typical cleanings would result in a waste of approximately 80,000 gallons. Should evaporation not be used, the wastewater can be treated by neutralization and precipitation prior to being conveyed to the 1964 ash pond, or to the 1982 ash pond, or other means of disposal. Cleaning of other heat exchanger surfaces w may produce 5,000-10,000 gallons of wastewater every three -to -five years. r7 Other Wastes Operation of the combustion turbine (CT) generation facility may produce turbine blade wash water, inlet filter cooling water, various condensate waters, and water from equipment and tank drains. These wastewaters will be collected in the storm water collection system of the CT site and routed to the 1982 ash pond. During maintenance activities, sludges removed from catch basins, sumps, etc, may be transported to the 1964 ash pond and/or the 1982 ash pond for disposal. Plant Potable and Sanitary System The supply of water for plant potable and sanitary use is obtained from the Asheville/Buncombe Water Authority system and waste from this system is discharged to the Metropolitan Sewage District System. 4 W Carolina Power & Light Company Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 Herbicide and Pesticide Usage in the Treatment System Ponds Herbicides may be used as needed to control nuisance aquatic vegetation. These herbicides are applied by licensed applicators, or persons under the immediate supervision of a licensed applicator, in accordance with the manufacturer's instructions. Pesticides may be used as needed to perform biological assessments. These Pesticides are applied by licensed applicators, or persons under the immediate supervision of a licensed applicator, in accordance with the manufacturer's instructions. 230 KV Substation Storm Water Storm water runoff from the substation located adjacent to the plant is conveyed to the 1964 ash pond. This water may be transferred to the 1982 ash pond as needed to maintain appropriate water levels in the 1964 ash pond. Outfall 002 - Discharge to Lake Julian Once -Through Cooling Water This flow provides condenser cooling water for the generating units 1 and 2. Maximum condenser flows for units 1 and 2 are 150 MGD and 156 MGD, respectively. Once -through cooling water is used to supply non -contact cooling water for the component closed cooling water system. The component closed cooling water system flows combine with unit 1 and 2 condenser flows prior to discharge to Lake Julian. Maximum component closed cooling water system flows for unit 1 and 2 are 9.1 MGD and 10.2 MGD, respectively. Discharge flow to Lake Julian is calculated at the intake to units 1 and 2 condensers and to the circulating water to the heat exchanger. The discharge of water from the heat exchangers is routed to an ash sump. The majority of this water is further routed to the discharge of units 1 and 2 condensers. Less than one percent of the flow to the ash sump is used to supply ash sluice water, preheater cleaning water, and fire protection water. Control of biological fouling on heat -exchanger surfaces is accomplished by addition of sodium hypochlorite as required, which is usually less that 2 hours per day per unit, with a net total residual chlorine of less than 0.2 ppm discharged during that period. Cooling is accomplished by evaporation from the surface of Lake Julian and mixing and convection with lake waters. Make up for Lake Julian is from the French Broad River, natural runoff and creek flows. Water 12 do Carolina Power & Light Company Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 ON is pumped from the French Broad River during dry periods to supplement the flow. Although discharge from Lake Julian to the river is extremely rare, any occurrence would be during periods of heavy rainfall. Herbicide and Pesticide Usage in the Treatment System Ponds WA Herbicides may be used as needed to control nuisance aquatic vegetation. These herbicides are applied by licensed applicators, or persons under the immediate supervision of a licensed applicator, in accordance with the manufacturer's instructions. Pesticides may be used as needed to perform biological assessments. These Pesticides are applied by licensed applicators, or persons under the immediate supervision of a licensed applicator, in accordance with the manufacturer's instructions. R to Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc. Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 Attachment 4 Form 2C — Item VI Potential Discharges Not Covered by Analysis M am Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc. Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 Attachment 4 Form 2C - Item VI - Potential Discharges Not Covered By Analysis Chemical Estimated Quantity Frequency Purpose Used(per ear Hydrazine (35%) 1840 lb./yr. Continuous Oxygen scavenger in boiler Ammonium hydroxide 2730 lb./yr. Continuous pH control of boiler water Sodium hydroxide 141,139 Ib./yr Continuous pH control of ash pond 25 Sodium hydroxide 30 gallons As required pH control of boiler 50% water Sodium hypochlorite 91,072 lb./yr. As required Control of biological (15%) fouling on heat exchangers Sodium molybdate 100 pounds As required Corrosion control in closed cooling water system Tetraammonia EDTA 35,000 pounds Every 5 to 8 years Boiler cleaning 38% Urea (50%) 7365 tons/yr. Continuous during NOx control high ozone months Sulfuric acid (93%) Variable As needed pH control pf ash pond BetzDearborn Dustreat 11,400 pounds - As required Coal dust suppression - DC9136 estimated proprietary chemical Fyrewash (detergent) 200 gallons As needed Combustion turbine blade washing Detergents/cleaning Variable As needed Housekeeping agents Limestone (Calcium 21,944 tons/yr. Continuous Flue Gas carbonate) Desulfurization Polymer (high weight, 3255 lb./yr. Continuous Solids removal — FGD anionic, emulsion -type) wastewater Coagulant (Ferric 3060 lb./yr. Continuous Solids removal — FGD chloride — 41 %) wastewater Sodium Hydroxide 17600 lb./yr. Continuous pH adjustment — FGD 25% wastewater Hydrochloric Acid 400 gallons - Continuous pH adjustment — FGD 30% estimated wastewater Magnesium Hydroxide Variable Continuous Applied to coal for slag control Aluminum Sulfate 25%- variable As required Water treatment 50% Alum processes, TSS control „o Carolina Power & Light Company Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 ift Sumachlor 50 As needed Coagulant for water treatment filter MIT7602 (Organic As needed R.O. Anti-scalant Polymer) 50% Caustic Variable for R.O. pH As needed for pH R.O. pH adjustment adjustment adjustment and 1000 gallons for Periodic Typically 4/yr R.O. cleaning per for R.O. cleaning R.O. cleaning event Hydrocloric Acid 1000 gallons/event Periodic Typically 4/yr R.O. membrane cleaning Citric acid 1000 gallons/event Periodic Typically 4/yr R.O. membrane cleaning Trilon B (EDTA) 1000 gallons/event Periodic Typically 4/yr R.O. cleaning ROClean P911 1000 gallons/event Periodic Typically 4/yr R.O. cleaning Bisulfite (sodium As needed R.O. layup bisulfite 600gallons/event Alkyl alcohol Variable As needed Freeze conditioning agent Propylene Glycol Variable As needed Freeze conditioning agent Calcium Chloride Variable As needed Freeze conditioning agent Diethylene glycol Variable As needed Freeze conditioning agent Glycerin variable As needed Freeze conditioning agent Fertilizer Variable As needed Wetland treatment cell plant management Pelletized Lime Variable As needed Wetland treatment cell plant management NMI 2 Rev. April2010 ift Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc. Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 Attachment 5 Form 2F — Item III Site Drainage Map U- 1 r -- 44��• Old Access Road W r SW-6 +�- �. SW-5 y� hev i • e A t New Access Road SW-1 (approximate location) W ' • "",mow' �,°.,, El'T � � � r SW-3 s a ... y ♦ '/...... ° .J r ,„• SW-2 i #All 0 250 500 1,000 1,500 2,000 Feet " 5 Attachment 5 — Form 2F — Item III — Map Carolina Power & Light Company Asheville Steam Electric Plant Buncombe County Page 1 of 3 A"� 14( Id w Spillway N, N 13 33 SW-4 SW-5 Lake Julian SW-6 -T substawc fiqw loop ev C 0 e Attachment 5 — Form 2F — Item III Site Drainage Map Progress Energy Carolinas, Inc. Asheville Steam Electric Plant Buncombe County Page 2 of 3 Attachment 5 — Form 2F — Item III Site Drainage Map Progress Energy Carolinas, Inc. Asheville Steam Electric Plant Buncombe County Page 3 of 3 .o Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc. Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 Attachment 6 Form 2F —Item IV-B Narrative Description of Pollutant Sources on Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc. Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 Attachment 6 Form 2F - Item IV B. Narrative Description of Pollutant Sources Various products and waste products will enter and leave the plant via the old access road, new access road and rail line. The enclosed site drainage maps display the sections of the site access roads from which storm water will discharge to Lake Julian or an unnamed tributary of Powell Creek which discharges into the French Broad River. Storm water from other sections of the roads flows via sheet flow or is conveyed to the 1982 ash pond or to the hot pond prior to discharging to, respectfully, the French Broad River and Lake Julian. The discharges from the hot pond and 1982 ash pond to Lake Julian and the French Broad River, respectively, are NPDES permitted discharge outfalls. New Access Road The portion of the road from which storm water will discharge directly to Lake Julian is divided into 3 separate drainage areas, each with an outfall. Storm water that is routed to SW-1 is carried to Lake Julian using piping, grass -lined ditches, concrete -lined ditches and sheet flow. The area drained contains Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc. (PEC) property, non-PEC property, the access road and a railroad storage yard where coal -filled rail cars can be stored. Storm water that is routed to SW-2 will be collected in a riprap-lined ditch that will then allow sheet flow to Lake Julian. The area drained contains only the access road. Storm water that is routed to outfall SW-3 will be routed through piping and both grass and riprap-lined ditches. The area drained to SW-3 includes PEC property, non-PEC property, the access road, and the railroad storage yard. PEC can only provide a rough estimate of impervious area for the property not owned by PEC. The property used for the new access road was purchased by PEC. The past use of this property was residential; therefore, PEC has no knowledge of any significant materials that have been treated, stored or disposed on this property in the past. PEC staff performed a limited Phase 1 Environmental Site Assessment on this property and found no visual evidence of the storage, use, or disposal of chemicals or hazardous substances. Any chemicals used are likely limited to consumer products in limited quantities. PEC has stored in the past and will store in the future coal at the railroad storage yard. The coal is contained in rail cars that are waiting to be unloaded at the plant. Other than the coal stored at the railroad storage yard, PEC has not treated, stored or disposed of any significant materials on any property already owned by PEC in the drainage area of this access road and has no plans to treat, store, or dispose of significant materials on this access road or on immediately surrounding property owned by PEC in the future. No materials loading or unloading activities will take place on the access road, railroad storage yard, or on immediately surrounding property owned by PEC. Various brands of commercial herbicides (i.e., Roundup, Crossbow) might be used to control weeds and other unwanted plant growth for security reasons. These herbicides will be carefully applied by licensed applicators, or persons under the immediate supervision of a licensed applicator, in accordance with the manufacturer's Carolina Power & Light Company Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 instructions. Fertilizers, pesticides (other than herbicides), and soil conditioners will not be used by PEC. No hazardous waste treatment, storage, or disposal will occur on this property. Old Access Road The portion of the road from which storm water will discharge directly to Lake Julian is divided into 3 separate drainage areas each with an outfall. Storm water that is routed to SW-4 flows over grass -lined ditches and gravel to Lake Julian. The area drained contains PEC property, non-PEC property, and the old access road. Storm water that is routed to SW-5 is collected in a grass -lined ditch that discharges into a concrete conveyance that discharges into the Lake Julian spillway. The spillway discharges to an unnamed tributary of Powell Creek which discharges to the French Broad River. The area drained contains only PEC property, including the access road. Storm water that is routed to outfall SW-6 is conveyed through grass -lined ditches and piping to Lake Julian. The area drained contains PEC property including the access road and a picnic area with several buildings and a shelter. PEC has not treated, stored or disposed of any significant materials on property owned by PEC in the drainage area of this access road and has no plans to treat, store, or go dispose of significant materials on property in the drainage area owned by PEC. No materials loading or unloading activities will take place on the access property owned by PEC. Various brands of commercial herbicides (i.e., Roundup, Crossbow) might be used to control weeds and other unwanted plant growth for security reasons. These herbicides will be carefully applied by licensed applicators, or persons under the immediate supervision of a licensed applicator, in accordance with the manufacturer's instructions. Fertilizers, pesticides (other than herbicides), and/or soil conditioners will not be used by PEC in this drainage area. No hazardous waste treatment, storage, or disposal will occur on PEC property in this drainage area. Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc. Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 Attachment 7 Form 2F —Item IV-C Description of Structural and Nonstructural Control Measures ift WE Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc. Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 Attachment 7 Form 2F - Item IV C. Description of existing structural and nonstructural control measures to reduce pollutants No conventional treatment will be provided for the storm water discharging from any of the outfalls. Prior to discharging to Lake Julian, storm water from Outfalis SW-1, SW-2, SW-4, SW-5, and SW-6 will flow over a vegetative buffer which will provide some filtering of sediment from the storm water. All coal, limestone, ash and gypsum trucks that travel on the access road are required to be covered which will prevent spillage on this road. These same trucks are required to wash down their wheels prior to exiting the site. The wash water from these wheel washes is routed to the 1982 ash pond for treatment. During maintenance activities, sludges removed from ditches or manholes may be transported to the 1964 and/or 1982 ash pond for disposal. Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc. Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 Attachment 8 1Q10 flow determination M F" Mar, lb, IUIU 1;4drm iuo, Mo r, i ift to ❑ Not applkable '7 � ke� 00 yd Fax to:- sclemae flare abmft twiff Date: Mold Subject: - Comments: A aukknote from J, Curtk Weaver, P.E. Hydrologist (Civil ring) jcweavergusgs.gov http://ne.woW.usgs, gov/ U.S. Department of the Interior U.S. Geological Survey 3,16 Sunset Ridge Road Raleigh, NO 27W7 (919)571-4043 (919) 571-4041 FAX ivia r, i o, zu i u i : 4orm no, L000 r. L � 865� NO: . Request l'� 7= Site No: _0_w StvemdlO r Conditions:.,.,,,,,_ LOGIN RPMUD Mqii= YOR WATER-3t1 mY sTATIsTicS Station No. D y<l'7i��eD Type Station Zd Data Inds; Station Name „ Y, eK 4A 131.001 k)r4•4, cL* ;OQC 2149 %t4Ir %-h QJ/ . Location •�' !1� C / y_-_c+y� << ►+^ 1 t �...' a S�'r %�, d .......�.,. Lat. 3S ° "�' '�, Was b2°37' 29"0 Basin ycrree� e vee.�,. Sky y 4*4 Qaad No. - 9 Gouty, lea. Je, g o s-% .- O' q State District ' 3 7 sqc A 6 d I S" .. NNE y- Drainage Area i 4 Average Dischargei r Estiaaated using �. ~% tfsat. k-' 12 IV in efs. �}) Miaa� Diseharges irr Kira. day 0 -year recurrence taterv'al . � Y _ 9 � N C3 7 (A ) �afsm.,� s. Kin._ D ,¢ay a -yea; recurrence interval, df W.�cEs. , (�) � `" 2"d z lain. 7day i b -ye= r==eacc jut 16f=. t%b9-fs. Kin .}-_ day -year recmCresnces interval, Opq �Pw. ��!efs. (A) rr �ceMe1 %�ra�ltiver at lC e Air4— D.A. y� •�-.�.�wawa rll ■w sq sd . Type .••1u- '2.A�t l •�..�.r �•1111 �Y1 - River at D.A. se; mi. Type _. _ ;�4D3 Creels near r River at D.a. sq mi. Typq- Crexk, nett letter Traasaxitted by carp. to �14 o � � 3cn^,a tt�ed by �{ W�_,"te Z - t o - a y /C�ooMp I V` ++ c wC Cbecko i �. �v�f data - l ­ 0 4 Mariam by date Z- . }y.,, I� Re marks t , �', • r . ,7 p Q '� • 1 - W -7 ,4 T -2� Gqd�77 ..+.�r F -;L7 �. Yz (a) Sstimte is based an records Gated at av Rear the BUG. (b) »stimea= is beats antUmly on runaft, observed at nearby straws. r (a) Istfzates based on pswcedarea given W open -fits wort 90-399 "Lox. -Flow { hWXQtUristirts of Straws f= North C4WQ i] " (d) EstUaw based on procedaras given in Open -file Report 90-399 and in coujucti,on with recoods •collscteed at or near the site. . p mar, lb. mu 1;4yrm IVo. L000 r. j a United States Department of the Interior U.S. GEOLOGICAL SURVEY 3916 Sunset Ridge Road Raleigh, North Carolina 27607 February 23, 2004 Ms. Susan A. Wilson, Environmental Engineer N.C, Division of Water Quality, NPDES Unit 1617 Mail Service Center Raleigh, North Carolina 27699-1617 Dear Ms. Wilson: In response to your request for, low -flow data, the U.S. Geological Survey (USGS) does not have site -specific, low -flow discharge data for French. Broad River at NC 280 near Skyland, NC (station id 03447840, drainage area 660 m12).. The low -flow characteristics that are pro- vided on the attached sheet have been computed by correlating the runoff characteristics of a nearby continuous -record gaging station upstream of the request site.. Please note that the flow estimates do not specifically account for the presence of any diversions or regulation, present or. future, which may occur upstream of the request site, Because a similar request for the 1Q10 low -flow discharge was received about the same time from Progress Energy, this low» flow statistic is included on the attached shoot. Low -flow characteristics were analyzed using streamflow records from a continuous -record gaging station on the' French Broad River near Fletcher, operated since July 2001 and located upstream at Secondary Road 1419 (station id 03447840, drainage area 640 m12). Because of the short period of record at the Fletcher gage, low -flow analyses at this gage were completed by correlation analyses using two other gaging stations having long periods of record (station id's 03443000 and 03451500), Then, using the difference in drainage areas between the request site and the Fletcher gage, low -flow characteristics at the request location were deter- mined using the low -flow yields' (expressed as flow per square mile drainage area) at the Fletcher gage. The,estimated 7Q10 discharge is 306 fols and is'lower than the estimate pro- vided to you in an e-mail dated January 14, 2004. Analyses of low -flow characteristics at all three gaging stations indicates a decreasing trend in low -flow yields between the gages at Blantyre and Asheville. Between these two locations, the river is affected by some diversions occurring in tributaries along with regulation by small upstream reservoirs' and a power plant located about 8 miles upstream of Blantyre. The anal- yses indicate that most of the decrease in low -flow yields occurs between the Blantyre and •� Fletcher gages. The table shown on the accompanying page summarizes the low -flow characteristics at the gaging stations used in the analyses. As previously discussed in January, the French Broad River downstream from Blantyre is affected by some regulation and diversions. The low -flow discharge values are based on streamflow records available through September 2003, and the associated low4low yields for each value is listed to provide insight in the changing low -flow yields between the gages. (919) 5n 4DW 0 FAX (919) 5714041 iYla r, I0. LU I U I : 4yrivi IM Louo r. 'r .. Ms, Susan A. Wilson Page 2 February 10, 2004 +rr Low4law'charat"HoUce 0019) 8lation name r—r2 e+ v et .err 03443M F=& Brmd River at BI=V a (Secondary Road 1503, Honda= CMV) 296• 3.3 197 (0." 375 (1,267) 252 (0.851) 316 (1.068) 03447687 French Broad River new Fletcher 640 17 ' 297 613 397 515 (Secondary Road 1419, Buno=bo County) (0.463) (9,957) (0.620) (0.804) 03441500 Raub Broad River at Adhe me 945 2.2 425 • 933 563 720 (Secondary Road 1348, B=M*e County) (0.450) (0.882) (0.596) (0,762) These data are preliminary and subject to revision pending approval for publication by the Director of the L.S. Geological Survey, and are made available, through our cooperative pro- gram' of water�resources investigations with the North Carolina Department of Environment and Natural Resources.: If you have any questions regarding this information, please contact us at (919) 571-4000, Enclosure r Sincerely, . Curtis Weaver hydrologist r7 ma r, 14. LU I U I ; 4Yrm iuo. L000 r, REQUEST NO: 91623 SITE NO: � 1 DATE: 02/10/2004 SOURCE: DENR�} ACTION: ew . - , STATION NUMBER: 03447840 STATION TYPE: Unggg d (20) STATION NAME: French Broad River at NC 280 near Mland. NC LOCATION: At NC 280 (Lwg Skds bridW. and 2 miles west of Skvlsnd LATITUDE: 3502815311 LONGITUDE: 8 ° 33'28" QUANDRANGLE NAME AND NUMBER: S&„lsn_d MUM . COUNTY CODE; klenderson r0891 STATE CODE: NC r371DISTRICT CODE: _ NC HYDROLOGIC UNIT CODE: Q6010105 ENR BASIN CODE: 04-03-Q2 DRAINAGE AREA: 6 --a Flow statistics as follows: AVERAGE FLOW: Estimated using 2.70 ft3/sW2 1,780 ft3/s see note f, A l ANNUAL 7Q10 MINIM[ m now: 0,4634 f 3/8/mi2 306 to!s see note r A ANNUAL 30Q2 MINIMUM FLOW: 0.9670 ft3/w�mI2 631 fO/s see note r A WINTER 7Q10 MINIMUM FLOW: 0.6198 fo/stmo 409 fe/s see note f A ANNUAL 7Q2 MYNINUM FLOW: 0.8041 ft3/dnd2 531 fe/s we note A OAR FLOW (specify); 1010 0,4258 fo/s&l2 282 fe/s see note A NOTES: [A] Estimate is based on records Collected at or yam the request site. • US) Estimate is based entirely on runoff characteristics observed at nearby streams. [C] Estimate based on procedures given in USES Water Supply Paper 2403'%ow-flow Characteristics of Streams in North Carolina" (Giese and Masoxy 1993). .,,. [D] Estimate based on procedures given in USGS Water Supply Paper 2403 and in conjunction with streamflow records collected at or near the request site. [E] See remarks. These data are considered provisional and subject to revision pending approval by the Director, USGS. REMA.R�'3: • Low -flow estimates based on low -flow characteristics upstream gaging station 03447687 (French Broad River new Fletcher) during July 2001 thmugh September 2003, 1Q10 flow requested by Progress Bnergy. • Requested by Ms. Susan Wilson, N.C. Division of Waw Quality // Ms. Louise England, Progress Energy ENTERED BY: XCW FEE CHARGED: $ _150 im mar, io. [U1V I:gyrm ivo, Z000 r. o r United States Department of the Interior . UA GEOLOGICAL SUP E"Y 3916 Sunset Ridge Road Raleigh, North Carolina 27607 February 23, 2004 r Ms, Louise England, Senior Environmental Specialist Progress Energy - HIMBC 3932 New Hill - Woman Road New MI), North Carolina 27562 Dear Ms. England: Ln response to your request for low -mow data, the U.S. Geological Survey (USGS) does not have site -specific, low -flow discharge data for French Broad diver at NC 280 near Skyland, NC (station id 03447840, drainage area 660 m12), The low -flow characteristics that are provided on the attached sheet have been computed by correlating the ruaoff characteristics of a nearby continuous -record gaging station upstream of the request site. please note that the flow estimates do not specifically account for the presence of any diversions or regulation, present or future, which may occur upstream of the request site. Because your request was received about the same time as a similar request from the N-C, Division of Water Quality (DWQ), the low -flow statistics Cad - mated for the DWQ are included on the attached sheet. Low -flow characteristics were analyzed using streamflow records from a continuous -record gaging station on the French Broad River near Pletcher,, operated since July 2001 and located upstream at Secondary Road 1419 (station id 03447840, drainage area 640 mi2). Because of the short period of record at the Pletcher gage, low - flow analyses at this gage were completed by correlation analyses using two other gaging stations having long periods.of record (station id's 03443000 and 03451500). Then, using the difference in drainage areas between the request site and the Fletcher gage, low -flow characteristics at the request location were determined using the Iow-flow yields (expressed as flow per square mile drainage area) at the Pletcher gage,. The estimated 1Q10 discharge is 282 63/s and is lower than the estimated 7Q10 discharge of 306 ft3ts. Analyses of low -flow characteristics at all three gaging stations indicates a decreasing trend in low -flow yields between the gages at Blantyre and Asheville. Between these two locations, the river is affected by some diver., sions occurring in tributaries along with regulation by small upstream reservoirs and a power plant located about 8 miles upstream of Blantyre, The analyses indicate that most of the decrease in low -flow yields occurs between the Blantyre and Fletcher gages. A charge for accessing and processing information has been assessed to partWly onset these costs. Your requested data and an invoice covering processing costs for these data are enclosed. Please forward the orig- inal bill with your check to the U.S. Geological Survey,12201 Sunrise Valley Drive, MS 271, Reston, Virginia 20192. These data are preliminary and subject to revision pending approval for publication by the Director of the U.S. Geological Survey, and are made available through our cooperative program of water -resources investigations with the North Carolina Department of Environment and Natural Resources. If you have any questions regarding this information, please contact us at (919) 571.4000. Enclosures F Sincerely, , 7. Curtis Weaves Hydrologist (919) 571.4000 1- FAX (919) 57140C ma r, i U. Lu i u i ; �vrm ivo. Lvov r. t REQU1ST NO: , 11623 SITE NO: _. 1 DATE: 02/1QQM SOURCE:" '"U!EIiTR (DWOZ ACTION': ' -New _..� ..�.. _.. STATION NUb=R: 0344709 M STATION TYPE: Unpaged (20) STATION NAME: F ich Broad River at NQ 280 near SWat�+d, NC,_ LOCATION: At UC 280 (=& Shoals bridge).. d-2 miles we_ is of Skyland im LATITUDE: 35028'53" LONGITUDEs 82033'28" QUANDRANGLE NAME AND NUMBER: SWWdd rF 8•NE] COUNTY CODES Henderson _ r0891 STATE CODE: NC r371 DISTRICT CODE: _. Imo_ r371 MROLOGIC UNIT CODE; 0601010 ENR BASIN CODE: 04-03-02 im DRAINAGE AREA: 66Q 3mO Flow statbtics as %cows; AVERAGE FLOW; Estimated using 2,70 fe/s,&O12 1,780 Sys see note �--� ANNUAL 7Q10 MINIMUM FLOW: 0.4634 fe/s/M12 306 ft3/s see note A ANNUAL 30Q2 MINIMUM FLOW: 0,9570 f 3/s/Mi2 631 W/$ see note L-A-J WINTER 7Q10 MINIMUM FLOW: 0.6198 fo/wImI2 409 f0/$ see note F A ANNUAL 7Q2 MINIMUM FLOW: 0,8041 f 3ldW2 531 W/s see note [AI OTHER FLOW (specify); _1010� 0,4258 i1t%/ mil 282 0/s see note Lam, NOTES. - [A] Estimate is based on records collected at or near the request site. [01 Estimate is based entirely on runoff characteristics observed at nearby streams. [C] Estimate based on procedures given in USGS Water Supply Paper 24031%ow-Sow Cbraracteristics of Streams In North Carolina" (Giese and Nk5on,1993). [D] Estimate based on procedures given in USGS Witter Sup* Paper 2403 and in conjunction with stareatmflow records collected at or near the request site. [E] See remarks. These data are considered provisional and subject to revW011 pending approval by the Director, USGS. REMARKS: • Low -flow esd=tes based on low -flow characteristics upstream gaging station 03447687 (F=ch Broad River near Fletcher) during July 2001 through September 2003. 1Q10 flow requested by Progress Energy. • Requested by Ms. Susan Wilson, N.C. Division of Water Quality // Ms. Louise England, Progress Energy ENTERED BY: JQW FEE CHARGED.- $ 150 Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc. Asheville Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0000396 Attachment 9 Proposed conceptual relocation route of outfall 001 im W" M Proposed relocation of outfall 001 In order to facilitate enhancements to the 1964 ash pond dam, it will be necessary to relocate the existing settling basin and discharge outfall 001. The Asheville Steam Electric Plant is located in close proximity to the French Broad River but has limited access to the river because of Interstate 26. In order to relocate outfall 001, it will be necessary to go north approximately 3000 feet to a point where existing access under the Interstate is located. This proposed discharge location is on property owned by Progress Energy. The entire span of property between the existing outfall and the proposed outfall is rr also owned by Progress Energy. In addition to the current flows from the 1982 ash pond, a "new" flow will be added to the relocated outfall. This flow will consists of stormwater and ground water seepage that currently flows into the 1964 ash pond. Historically, this flow has been allowed to evaporate and/or infiltrate. The enhancements to the 1964 pond require that this water level be managed and maintained below a certain elevation. Therefore, it may be necessary to periodically pump water from the 1964 ash pond to the combined, relocated settling basin and outfall 001. A sample of the water from the 1964 ash pond was taken as part of the preparation of this application. Results from that sampling analysis are attached. in rrrr aceAnalytical MWw.pacels"com April 23, 2010 Alto Ms. Crystal Diedrich Progress Energy 200 CP&L Drive Arden, NC 28704 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 9800 KinoeyAve. Suite lo0 Huntersville, NC 28078 (704)875-9092 WIN RE: Project: DUCK POND 04/12 Pace Project No.: 9267173 Dear Ms. Diedrich: Enclosed are the analytical results for sample(s) received by the laboratory on April 12, 2010. The results relate only to the samples included in this report. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All INMicrobiological analyses were performed at the laboratory where the samples were received. If you have any questions concerning this report, please feel free to contact me. Sincerely, Lord Patton 0111111 lorri.patton@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, s� without the written consent of Pace Analytical Services, Inc.. cao, rr Page 1 of 14 ac"Analytical www.peostab&com 96 No Project: DUCK POND 04/12 Pace Project No.: 9267173 0111111 Asheville Certification IDs 2225 Riverside Dr. Asheville, NC 28804 Connecticut Certification #: PH-0106 Virginia Certification #: 00072 Tennessee Certification M 2980 South Carolina Certification #: 99030001 South Carolina Bioassay Certification #: 99030002 Pennsylvania Certification #: 68-03578 North Carolina Wastewater Certification #: 40 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 CERTIFICATIONS North Carolina Drinking Water Certification #: 37712 North Carolina Bioassay Certification #: 9 New Jersey Certification* NC011 Massachusetts Certification #: M-NCO30 Louisiana/LELAP Certification #: 03095 Flodda/NELAP Certification #: E87648 West Virginia Certification #: 356 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, toThis the written consent of Pace Analytical Services, Inc.. u/ll •lli/8�,\mil z Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 14 �Ia'neAnaocal www.peodebs w" im do Project: DUCK POND 04/12 Pace Project No.: 9267173 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 9267173001 DUCK POND EPA 200.7 JMW 11 PASI-A do EPA 245.1 SHB 1 PASI-A SM 5210B JDA 1 PASI-A 40CFR PART 503 SAJ 1 PASI-A w EPA 351.2 EWS 1 PASI-A EPA 353.2 JDA 1 PASI-A EPA 365.1 JDA 1 PASI-A SM 5220D LEP 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, so without the written consent of Pace Analytical Services, Inc.. IJl -11�.1 ON Page 3 of 14 aceAnal)ftal. awwwwaleDa.wm rrf, Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: DUCK POND 04/12 Pace Project No.: 9267173 ift Sample: DUCK POND Lab ID: 9267173001 Collected: 04/12/10 09:00 Received: 04/12/10 12:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 too200.7 Antimony ND ug/L 10.0 2 04/15/10 17:00 04/19/10 12:28 7440-36-0 D3 Arsenic ND ug/L 10.0 2 04/15/10 17:00 04/19/10 12:28 7440-38-2 D3 Beryllium ND ug/L 2.0 2 04/15/10 17:00 04/19/10 12:28 7440-41-7 D3 do Cadmium ND ug/L 2.0 2 04/15/10 17:00 04/19/10 12:28 7440-43-9 D3 Chromium ND ug/L 10.0 2 04/15/10 17:00 04/19/10 12:28 7440-47-3 D3 Lead ND ug/L 10.0 2 04/15/10 17:00 04/19/10 12:28 7439-92-1 D3 Nickel 29.6 ug/L 10.0 2 04/15/10 17:00 04/19/10 12:28 7440-02-0 D3 do Selenium 21.4 ug/L 20.0 2 04/15/10 17:00 04/19/10 12:28 7782-49-2 D3 Silver ND ug/L 10.0 2 04/15/10 17:00 04/19/10 12:28 7440-22-4 D3 Thallium ND ug/L 20.0 2 04/15/10 17:00 04/19/10 12:28 7440-28-0 D3 Zinc 37.6 ug/L 20.0 2 04/15/10 17:00 04/19/10 12:28 7440-66-6 D3 on 245.1 Mercury Analytical Method: EPA 245.1 Preparation Method: EPA 245.1 Mercury ND ug/L 0.20 1 04/16/10 10:55 04/16/1018:01 7439-97-6 ON 5210E BOD, 5 day Analytical Method: SM 5210B BOD, 5 day ND mg/L 2.0 1 04/13/10 17:30 04/18/10 14:50 B2 Total Nitrogen Calculation Analytical Method: 40CFR PART 503 ao Nitrogen 0.73 mg/L 0.60 1 04/21/1015:25 7727-37-9 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 so Nitrogen, Kjeldahl, Total 0.66 mg/L 0.50 1 04/22/10 13:30 7727-37-9 353.2 Nitrogen, NO2/NO3 pros. Analytical Method: EPA 353.2 Nitrogen, NO2 plus NO3 ND mg/L 0.10 1 04/19/10 11:28 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Phosphorus ND mg/L 0.10 1 04/18/1011:33 7723-14-0 No 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand ND mg/L 25.0 1 04/14/10 16:46 Date: 04/23/2010 03:48 PM rrl REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 14 AWN auaaftlytical awwpecelliftcom ill AN Project: DUCK POND 04/12 Pace Project No.: 9267173 An QC Batch: MPRP/6150 QC Batch Method: EPA 200.7 Associated Lab Samples: 9267173001 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Analysis Method: EPA 200.7 Analysis Description: 200.7 MET Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 METHOD BLANK: 429215 Matrix: Water Associated Lab Samples: 9267173001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony ug/L ND 5.0 04/16/1017:25 Arsenic ug/L ND 5.0 04/16/1017:25 Beryllium ug/L ND 1.0 04/16/1017:25 Cadmium ug/L ND 1.0 04/16/1017:25 Chromium ug/L ND 5.0 04/16/1017:25 Lead ug/L ND 5.0 04/16/1017:25 Nickel ug/L ND 5.0 04/16/1017:25 Selenium ug/L ND 10.0 04/16/1017:25 Silver ug/L ND 5.0 04/16/1017:25 Thallium ug/L ND 10.0 04/16/1017:25 rig Zinc ug/L ND 10.0 04/16/1017:25 LABORATORY CONTROL SAMPLE: 429216 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 500 474 95 85-115 Arsenic ug/L 500 480 96 85-115 rail Beryllium ug/L 500 496 99 85-115 Cadmium ug/L 500 479 96 85-115 Chromium ug/L 500 483 97 85-115 Lead ug/L 500 486 97 85-115 fills Nickel ug/L 500 482 96 85-115 Selenium ug/L 500 480 96 85-115 Silver ug/L 250 224 90 85-115 Thallium ug/L 500 468 94 85-115 rm Zinc ug/L 500 490 98 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 429217 429218 lio MS MSD 9267053001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual sin Antimony ug/L ND 500 500 491 488 97 97 70-130 1 Arsenic ug/L 0.0080 500 500 510 507 100 100 70-130 1 mg/L Beryllium ug/L ND 500 500 503 499 101 100 70-130 1 Sri Cadmium ug/L 0.0013 500 500 476 474 95 95 70-130 0 mg/L Chromium ug/L 0.034 500 500 519 514 97 96 70-130 1 mg/L Lead ug/L 0.034 500 500 511 506 95 94 70-130 1 NO mg/L Date: 04/23/2010 03:48 PM REPORT OF LABORATORY ANALYSIS Page 5 of 14 This report shall not be reproduced, except In full, INSwithout the written consent of Pace Analytical Services, Inc ` s' ON aceAnaljftal WW pecelakoom ON Project: DUCK POND 04/12 Pace Project No.: 9267173 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 AN rvl„I MIA Jrlrlt W MAltoll.->rlrlt LJW'LIUAIt: 4;Mel1 429218 MS MSD 9267053001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual am Nickel ug/L 0.53 500 500 1010 987 95 91 70-130 2 mg/L Selenium ug/L ND 500 500 489 480 98 96 70-130 2 Silver ug/L ND 250 250 225 224 90 89 70-130 0 do Thallium ug/L ND 500 500 429 429 86 86 70-130 0 Zinc ug/L 4.3 500 500 4790 4810 93 98 70-130 0 mg/L SAMPLE DUPLICATE: 429219 Parameter rr Units 9266960001 Result Dup Result RPD Qualifiers Antimony ug/L 87.5 90.0 3 Arsenic ug/L 258 280 9 Beryllium ug/L 26.4 28.5 8 Cadmium ug/L 187 204 9 Chromium ug/L 1310 1400 7 Lead ug/L 3460 3500 1 Nickel ug/L 1260 1380 9 Selenium ug/L 193 195 1 Silver ug/L 171 195 13 Thallium ug/L ND 28,6J Zinc ug/L 126000 138000 9 Date: 04/23/2010 03:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, WN without the written consent of Pace Analytical Services, Inc.. CCp,O ))) 3 . ♦yam Page 6of14 am a Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceftlytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 Wmpaoataba.corn Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 aw QUALITY CONTROL DATA dIN Project: DUCK POND 04112 Pace Project No.: 9267173 no QC Batch: MERP/2765 Analysis Method: EPA 245.1 QC Batch Method: EPA 245.1 Analysis Description: 245.1 Mercury Associated Lab Samples: 9267173001 arr METHOD BLANK: 428949 Matrix: Water Associated Lab Samples: 9267173001 Blank Reporting ro Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 04/16/10 21:21 ,is LABORATORY CONTROL SAMPLE: 428950 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers add Mercury ug/L 2.5 2.5 100 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 428951 428952 arr MS MSD 9267110001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Mercury ug/L ND 2.5 2.5 ND 2.5 -2 97 70-130 MO ss SAMPLE DUPLICATE: 428953 9267173001 Dup sr Parameter Units Result Result RPD Qualifiers Mercury ug/L ND ND rr Date: 04/23/2010 03:48 PM d0l REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 14 aceAnalytical www.pooeiaba.00m i1Yli Am Project: DUCK POND 04/12 Pace Project No.: 9267173 ON .av vaaN b vvG 1 / I4v".t QC Batch Method: SM 5210B Associated Lab Samples: 9267173001 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Analysis Method: SM 5210B Analysis Description: 5210B BOD, 5 day ift METHOD BLANK: 428123 Matrix: Water Associated Lab Samples: 9267173001 Blank Reporting do Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg/L ND 2.0 04/18/10 14:50 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 etr LAt$UKAI UKY UUN I KUL 5AMNLL: 428124 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers do BOD, 5 day mg/L 198 174 88 84-115 SAMPLE DUPLICATE: 428137 rnrl 9267206001 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 1370 1370 0 Wit Date: 04/23/2010 03:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. ouc,c `4CyLia Page 8 of 14 610 WA aceft ytical • Pace Analytical Services, Inc. Pace Analytical Services, Inc. 2225 Riverside Dr. 9800 Kinsey Ave. Suite 100 www.pacelsbs.wn Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 do QUALITY CONTROL DATA orr Project: DUCK POND 04/12 Pace Project No.: 9267173 NO QC Batch: WETA/7196 Analysis Method: EPA 351.2 QC Batch Method: EPA 351.2 Analysis Description: 351.2 TKN Associated Lab Samples: 9267173001 am METHOD BLANK: 431150 Matrix: Water Associated Lab Samples: 9267173001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers im Nitrogen, Kjeldahl, Total mg/L ND 0.50 04/22/10 13:27 MIN LABORATORY CONTROL SAMPLE: 431151 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Kjeldahl, Total mg/L 5 5.2 105 90-110 amNitrogen, MATRIX SPIKE SAMPLE: 431152 so 9266978001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg/L 6.0 5 9.7 74 90-110 MO do SAMPLE DUPLICATE: 431153 9267173001 Dup Units Result Result RPD Qualifiers IsmParameter Nitrogen, Kjeldahl, Total mg/L 0.66 1.6 82 R1 rw Date: 04/23/2010 03:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc,. ul ll• I�I�A�if1 s Page 9 of 14 WA ac"Analytical Wmpecabbs.corn all Project: DUCK POND 04/12 Pace Project No.: 9267173 so W%,Ddiar VVLINtIdi QC Batch Method: EPA 353.2 Associated Lab Samples: 9267173001 do METHOD BLANK: 430324 Associated Lab Samples: 9267173001 to Parameter Units Nitrogen, NO2 plus NO3 mg/L Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Analysis Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, preserved Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.10 04/18/1010:32 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 of LABORATORY CONTROL SAMPLE: 430325 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, NO2 plus NO3 mg/L 5 5.1 102 90-110 MATRIX SPIKE SAMPLE: 430326 r 9266802001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, NO2 plus NO3 mg/L 0.41 5 5.2 96 75-125 rri MATRIX SPIKE SAMPLE: 430328 9267367005 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, NO2 plus NO3 mg/L 7.6 5 11.7 81 75-125 SAMPLE DUPLICATE: 430327 9266805001 Dup Parameter Units Result Result RPD Qualifiers am Nitrogen, NO2 plus NO3 mg/L 0.46 0.46 2 SAMPLE DUPLICATE: 430329 rrl 9267367007 Dup Parameter Units Result Result RPD Qualifiers Nitrogen, NO2 plus NO3 mg/L ND ND as Date: 04/23/2010 03:48 PM WIN REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. «o, :/JrI�.LIa Page 10 of 14 do aceAnalytical WW pecabbs.com to ter Project: DUCK POND 04/12 Pace Project No.: 9267173 ro QC Batch: WETA17175 QC Batch Method: EPA 365.1 Associated Lab Samples: 9267173001 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Analysis Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Am METHOD BLANK: 429864 Matrix: Water Associated Lab Samples: 9267173001 Blank Reporting w Parameter Units Result Limit Analyzed Qualifiers Phosphorus mg/L ND 0.10 04/18/1011:26 d0k LABORATORY CONTROL SAMPLE: 429865 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Was Phosphorus mg/L 1 1.0 101 90-110 MATRIX SPIKE SAMPLE: 429866 rrr 9267367015 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Phosphorus mg/L 43.6 1 44.9 123 90-110 MO r11f MATRIX SPIKE SAMPLE: 429868 9266715001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Phosphorus mg/L 3.2 1 5.1 194 90-110 MO Wall SAMPLE DUPLICATE: 429867 9266947001 Dup Parameter Units Result Result RPD Qualifiers av Phosphorus mg/L 3.4 3.4 0 SAMPLE DUPLICATE: 429869 ON 9267067001 Dup Parameter Units Result Result RPD Qualifiers Phosphorus mg/L 7.0 7.1 2 am go Date: 04/23/2010 03:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 4EC N M1CC09 n J�o`/,� i Page 11 of 14 • aceAn Pical Pace Analytical Services, Inc. Pace Analytical Services, Inc. 2225 Riverside Dr. 9800 Kincey Ave. Suite 1o0 www.psoebbs.can Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 QUALITY CONTROL DATA Project: DUCK POND 04/12 Pace Project No.: 9267173 r r QC Batch: WETA17144 Analysis Method: SM 5220D QC Batch Method: SM 5220D Analysis Description: 5220D COD Associated Lab Samples: 9267173001 `IN METHOD BLANK: 428014 Matrix: Water Associated Lab Samples: 9267173001 Blank Reporting No Parameter Units Result Limit Analyzed Qualifiers Chemical Oxygen Demand mg/L ND 25.0 04/14/10 16:46 AN LABORATORY CONTROL SAMPLE: 428015 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers NO Chemical Oxygen Demand mg/L 750 716 95 90-110 MATRIX SPIKE SAMPLE: 428016 do 9266663008 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg/L 70.0 750 804 98 75-125 will MATRIX SPIKE SAMPLE: 428022 9266996001 Spike MS MS % Rec im Parameter Units Result Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg/L 179 750 890 95 75-125 to SAMPLE DUPLICATE: 428021 9266750007 Dup Parameter Units Result Result RPD Qualifiers uw Chemical Oxygen Demand mg/L 600 596 1 SAMPLE DUPLICATE: 428023 rrl 9266758005 Dup Parameter Units Result Result RPD Qualifiers Chemical Oxygen Demand mg/L 2630 2580 2 rtll ift Date: 04/23/2010 03:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 14 to �n�J /+� Pace Analytical Services, Inc. C011 ent K�I �Ol a 2225 Riverside Dr. www.Paoslabloom Asheville, NC 28804 (828)254-7176 sri QUALIFIERS Project: DUCK POND 04/12 Pace Project No.: 9267173 DEFINITIONS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 10o Huntersville, NC 28078 (704)875-9092 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes toAzobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes. U - Indicates the compound was analyzed for, but not detected. LABORATORIES PASI-A Pace Analytical Services -Asheville ANALYTE QUALIFIERS B2 Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. Mo Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. R1 RPD value was outside control limits. Date: 04/23/2010 03:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, ttYl without the written consent of Pace Analytical Services, Inc.. 000,o, im Page 13 of 14 OWN /+ �/]a Pace Analytical Services, Inc. Pace Analytical Services, Inc. Ve' Y alXka'® 2225 Riverside Dr, 9800 Kincey Ave. Suite 100 Wwwwwa ba.com Asheville, NC 28804 Huntersville, NC 28078 M (828)254-7176 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: DUCK POND 04/12 Pace Project No.: 9267173 Lab ID Sample ID P CIC Batch Method QC Batch Analytical Method Analytical Batch 9267173001 DUCK POND EPA200.7 MPRP/6150 EPA200.7 ICP/5675 9267173001 DUCK POND EPA 245.1 MERP/2765 EPA 245.1 MERC/2731 9267173001 DUCK POND SM 5210B WET/12044 SM 5210B WET/12085 9267173001 DUCK POND 40CFR PART 503 WET/12127 9267173001 DUCK POND EPA 351.2 WETA/7196 9267173001 DUCK POND EPA 353.2 WETA/7183 9267173001 DUCK POND EPA 365.1 WETA17175 9267173001 DUCK POND SM 5220D WETA/7144 Date: 04/23/2010 03:48 PM do REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. :111_lE�� a Page 14 of 14