19890051 Ver 4_CB Sediment Sample Locations_20211013

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TI Coastal, PLLC
387-B N Green Meadow Dr.
Wilmington, NC 28405
910.821.1358
Vertical Datum
Conversion
NAVD88
2.54'
MLW
Graphic Scale
CAROLINA BEACH BOAT BASIN
PRE -CONSTRUCTION SURVEY
Notes:
1. Horizontal Datum: NC State Plane - Zone 3200
2. Vertical Datum: MLW, Beaufort Datum
3. Samples collected by TI Coastal on May 5, 2017 and represent conditions
at that time.
4. Individual samples composited in the field to 3 total samples for testing,
CBB1, CBB2 & CBB3.
5. 2012 Aerial of New Hanover County downloaded from NC OneMap.
DWG NAME: CB Boat Basin.dwg
0' 25' 50' 100'
Horizontal Scale: 1" = 50'
SEDIMENT SAMPLE LOCATIONS
DWG DATE: May 23, 2017
SURVEY DATE: As noted
SCALE: 1" = 50'
SHEET: 1 OF 1

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
May 19, 2017
Jamie Pratt
TI Coastal
9111-B Market Street
Wilmington, NC 28411
RE: Project: CAROLINA BEACH
Pace Project No.: 92339655
Dear Jamie Pratt:
Enclosed are the analytical results for sample(s) received by the laboratory on May 05, 2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
angela.baioni©pacelabs.com
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 1 of 32

CERTIFICATIONS
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Green Bay Certification IDs
1241 Bellevue Street, Green Bay, WI 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky UST Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
New York Certification #: 12064
North Dakota Certification #: R-150
Charlotte Certification IDs
9800 KinceyAve. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
Virginia VELAP ID: 460263
South Carolina Certification #: 83006001
Texas Certification #: T104704529-14-1
Wisconsin Certification #: 405132750
Wisconsin DATCP Certification #: 105-444
USDA Soil Permit #: P330-16-00157
Federal Fish & Wildlife Permit #: LE51774A-0
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 32

SAMPLE ANALYTE COUNT
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID Sample ID
Method
Analytes
Analysts Reported Laboratory
92339655001 2017-G S-C B B 1
92339655002 2017-GS-CBB2
92339655003 2017-GS-CBB3
EPA 8081 RES 24 PASI-C
9071E JMS 1 PASI-C
MADEP EPH PKS 7 PASI-C
MADEP VPH WDV 5 PASI-C
EPA6010 SH1 12 PASI-A
EPA 7471 WAB 1 PASI-A
EPA 8270 by SIM BPJ 21 PASI-C
ASTM D2974-87 KDF 1 PASI-C
EPA 9060 Modified TJJ 4 PASI-G
EPA 8081 RES 24 PASI-C
9071E JMS 1 PASI-C
MADEP EPH PKS 7 PASI-C
MADEP VPH WDV 5 PASI-C
EPA6010 SH1 12 PASI-A
EPA 7471 WAB 1 PASI-A
EPA 8270 by SIM BPJ 21 PASI-C
ASTM D2974-87 KDF 1 PASI-C
EPA 9060 Modified TJJ 4 PASI-G
EPA 8081 RES 24 PASI-C
9071E JMS 1 PASI-C
MADEP EPH PKS 7 PASI-C
MADEP VPH WDV 5 PASI-C
EPA6010 SH1 12 PASI-A
EPA 7471 WAB 1 PASI-A
EPA 8270 by SIM BPJ 21 PASI-C
ASTM D2974-87 KDF 1 PASI-C
EPA 9060 Modified TJJ 4 PASI-G
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 32

ANALYTICAL RESULTS
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2017-GS-CBB1
Lab ID: 92339655001 Collected: 05/05/17 13:15 Received: 05/05/17 16:15 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed
CAS No. Qual
8081 GCS Pesticides
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Chlordane (Technical)
4,4'-DDD
4,4'-DDE
4,4'-DDT
Dieldrin
Endosulfan I
Endosulfan 11
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
Heptachlor
Heptachlor epoxide
Hexachlorobenzene
Methoxychlor
Mirex
Toxaphene
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
9071 SGT-HEM, TPH
Total Petroleum Hydrocarbons
MADEP EPH NC Soil
Aliphatic (C09-C18)
Aliphatic (C19-C36)
Aromatic (C11-C22)
Surrogates
Nonatriacontane (S)
o-Terphenyl (S)
2-Fluorobiphenyl (S)
2-Bromonaphthalene (S)
VPH NC Soil
Aliphatic (C05-008)
Aliphatic (C09-C12)
Aromatic (C09-C10)
Surrogates
4-Bromofluorobenzene (FID) (S)
4-Bromofluorobenzene (PID) (S)
Analytical Method: EPA 8081 Preparation Method: EPA 3546
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
0
61
31.2 5 05/09/17 07:05 05/18/17 05:26 309-00-2
31.2 5 05/09/17 07:05 05/18/17 05:26 319-84-6
31.2 5 05/09/17 07:05 05/18/17 05:26 319-85-7
31.2 5 05/09/17 07:05 05/18/17 05:26 319-86-8
31.2 5 05/09/17 07:05 05/18/17 05:26 58-89-9
109 5 05/09/17 07:05 05/18/17 05:26 57-74-9
31.2 5 05/09/17 07:05 05/18/17 05:26 72-54-8
31.2 5 05/09/17 07:05 05/18/17 05:26 72-55-9
31.2 5 05/09/17 07:05 05/18/17 05:26 50-29-3
31.2 5 05/09/17 07:05 05/18/17 05:26 60-57-1
31.2 5 05/09/17 07:05 05/18/17 05:26 959-98-8
31.2 5 05/09/17 07:05 05/18/17 05:26 33213-65-9
31.2 5 05/09/17 07:05 05/18/17 05:26 1031-07-8
31.2 5 05/09/17 07:05 05/18/17 05:26 72-20-8
31.2 5 05/09/17 07:05 05/18/17 05:26 7421-93-4
31.2 5 05/09/17 07:05 05/18/17 05:26 53494-70-5
31.2 5 05/09/17 07:05 05/18/17 05:26 76-44-8
31.2 5 05/09/17 07:05 05/18/17 05:26 1024-57-3
31.2 5 05/09/17 07:05 05/18/17 05:26 118-74-1
77.9 5 05/09/17 07:05 05/18/17 05:26 72-43-5
77.9 5 05/09/17 07:05 05/18/17 05:26 2385-85-5
109 5 05/09/17 07:05 05/18/17 05:26 8001-35-2
35-108 5 05/09/17 07:05
21-123 5 05/09/17 07:05
Analytical Method: 9071 B Preparation Method: 9071 B
ND mg/kg
218 1 05/09/17 06:20
Analytical Method: MADEP EPH Preparation Method: MADEP EPH
ND
ND
ND
51
81
111
101
mg/kg
mg/kg
mg/kg
31.2
31.2
31.2
40-140
40-140
40-140
40-140
05/09/17 11:48
05/09/17 11:48
05/09/17 11:48
05/09/17 11:48
05/09/17 11:48
05/09/17 11:48
05/09/17 11:48
Analytical Method: MADEP VPH Preparation Method: MADEP VPH
ND
ND
ND
121
114
mg/kg
mg/kg
mg/kg
79.5
79.5
79.5
05/09/17 08:55
05/09/17 08:55
05/09/17 08:55
70-130 1 05/09/17 08:55
70-130 1 05/09/17 08:55
REPORT OF LABORATORY ANALYSIS
05/18/17 05:26 877-09-8 D3,S5
05/18/17 05:26 2051-24-3
05/09/17 14:38
05/15/17 23:56
05/15/17 23:56
05/15/17 23:56
05/15/17 23:56
05/15/17 23:56
05/15/17 23:56
05/15/17 23:56
05/10/17 09:43
05/10/17 09:43
05/10/17 09:43
7194-86-7
84-15-1
321-60-8
580-13-2
05/10/17 09:43 460-00-4
05/10/17 09:43 460-00-4
N2
N2
N2
N2,P4
N2,P4
N2,P4
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 32

ANALYTICAL RESULTS
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2017-GS-CBB1 Lab ID: 92339655001 Collected: 05/05/17 13:15 Received: 05/05/17 16:15 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Antimony ND mg/kg 1.2 1 05/10/17 17:05 05/13/17 17:55 7440-36-0
Arsenic 17.8 mg/kg 2.4 1 05/10/17 17:05 05/13/17 17:55 7440-38-2
Beryllium 0.43 mg/kg 0.24 1 05/10/17 17:05 05/13/17 17:55 7440-41-7
Cadmium ND mg/kg 0.24 1 05/10/17 17:05 05/13/17 17:55 7440-43-9
Chromium 33.8 mg/kg 1.2 1 05/10/17 17:05 05/13/17 17:55 7440-47-3
Copper 71.0 mg/kg 1.2 1 05/10/17 17:05 05/13/17 17:55 7440-50-8
Lead 29.0 mg/kg 1.2 1 05/10/17 17:05 05/13/17 17:55 7439-92-1
Nickel 5.5 mg/kg 1.2 1 05/10/17 17:05 05/13/17 17:55 7440-02-0
Selenium ND mg/kg 2.4 1 05/10/17 17:05 05/13/17 17:55 7782-49-2
Silver ND mg/kg 1.2 1 05/10/17 17:05 05/13/17 17:55 7440-22-4
Thallium ND mg/kg 2.4 1 05/10/17 17:05 05/13/17 17:55 7440-28-0
Zinc 147 mg/kg 2.4 1 05/10/17 17:05 05/13/17 17:55 7440-66-6
7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471
Mercury 0.033 mg/kg 0.0079 1 05/11/17 04:30 05/16/17 17:48 7439-97-6
8270 MSSV MW PAH by SIM Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546
Acenaphthene ND ug/kg 31.2 1 05/09/17 10:15 05/15/17 22:02 83-32-9
Acenaphthylene ND ug/kg 31.2 1 05/09/17 10:15 05/15/17 22:02 208-96-8
Anthracene ND ug/kg 31.2 1 05/09/17 10:15 05/15/17 22:02 120-12-7
Benzo(a)anthracene 131 ug/kg 31.2 1 05/09/17 10:15 05/15/17 22:02 56-55-3
Benzo(a)pyrene 176 ug/kg 31.2 1 05/09/17 10:15 05/15/17 22:02 50-32-8
Benzo(b)fluoranthene 302 ug/kg 31.2 1 05/09/17 10:15 05/15/17 22:02 205-99-2
Benzo(g,h,i)perylene 116 ug/kg 31.2 1 05/09/17 10:15 05/15/17 22:02 191-24-2
Benzo(k)fluoranthene 106 ug/kg 31.2 1 05/09/17 10:15 05/15/17 22:02 207-08-9
Chrysene 194 ug/kg 31.2 1 05/09/17 10:15 05/15/17 22:02 218-01-9
Dibenz(a,h)anthracene 34.0 ug/kg 31.2 1 05/09/17 10:15 05/15/17 22:02 53-70-3
Fluoranthene 353 ug/kg 31.2 1 05/09/17 10:15 05/15/17 22:02 206-44-0
Fluorene ND ug/kg 31.2 1 05/09/17 10:15 05/15/17 22:02 86-73-7
Indeno(1,2,3-cd)pyrene 116 ug/kg 31.2 1 05/09/17 10:15 05/15/17 22:02 193-39-5
1-Methylnaphthalene ND ug/kg 31.2 1 05/09/17 10:15 05/15/17 22:02 90-12-0
2-Methylnaphthalene ND ug/kg 31.2 1 05/09/17 10:15 05/15/17 22:02 91-57-6
Naphthalene ND ug/kg 31.2 1 05/09/17 10:15 05/15/17 22:02 91-20-3
Phenanthrene 111 ug/kg 31.2 1 05/09/17 10:15 05/15/17 22:02 85-01-8
Pyrene 314 ug/kg 31.2 1 05/09/17 10:15 05/15/17 22:02 129-00-0
Surrogates
Nitrobenzene-d5 (S) 45 % 10-128 1 05/09/17 10:15 05/15/17 22:02 4165-60-0
2-Fluorobiphenyl (S) 36 % 10-110 1 05/09/17 10:15 05/15/17 22:02 321-60-8
Terphenyl-d14 (S) 46 % 39-119 1 05/09/17 10:15 05/15/17 22:02 1718-51-0
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture
67.9 % 0.10 1 05/09/17 08:14
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 32

ANALYTICAL RESULTS
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2017-GS-CBB1
Lab ID: 92339655001 Collected: 05/05/17 13:15 Received: 05/05/17 16:15 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed
CAS No.
Qual
Total Organic Carbon
Surrogates
RPD%
Total Organic Carbon
Total Organic Carbon
Mean Total Organic Carbon
Analytical Method: EPA 9060 Modified
1.0
45400 mg/kg
45900 mg/kg
45600 mg/kg
0.10 1
40900 1
39200 1
40100 1
REPORT OF LABORATORY ANALYSIS
05/15/17 10:42
05/15/17 10:42 7440-44-0
05/15/17 10:48 7440-44-0
05/15/17 10:42 7440-44-0
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 6 of 32

ANALYTICAL RESULTS
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2017-GS-CBB2
Lab ID: 92339655002 Collected: 05/05/17 14:30 Received: 05/05/17 16:15 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed
CAS No. Qual
8081 GCS Pesticides
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Chlordane (Technical)
4,4'-DDD
4,4'-DDE
4,4'-DDT
Dieldrin
Endosulfan I
Endosulfan 11
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
Heptachlor
Heptachlor epoxide
Hexachlorobenzene
Methoxychlor
Mirex
Toxaphene
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
9071 SGT-HEM, TPH
Total Petroleum Hydrocarbons
MADEP EPH NC Soil
Aliphatic (C09-C18)
Aliphatic (C19-C36)
Aromatic (C11-C22)
Surrogates
Nonatriacontane (S)
o-Terphenyl (S)
2-Fluorobiphenyl (S)
2-Bromonaphthalene (S)
VPH NC Soil
Aliphatic (C05-008)
Aliphatic (C09-C12)
Aromatic (C09-C10)
Surrogates
4-Bromofluorobenzene (FID) (S)
4-Bromofluorobenzene (PID) (S)
Analytical Method: EPA 8081 Preparation Method: EPA 3546
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
1110
38
27.1 5 05/09/17 07:05 05/18/17 05:44 309-00-2
27.1 5 05/09/17 07:05 05/18/17 05:44 319-84-6
27.1 5 05/09/17 07:05 05/18/17 05:44 319-85-7
27.1 5 05/09/17 07:05 05/18/17 05:44 319-86-8
27.1 5 05/09/17 07:05 05/18/17 05:44 58-89-9
94.7 5 05/09/17 07:05 05/18/17 05:44 57-74-9
27.1 5 05/09/17 07:05 05/18/17 05:44 72-54-8
27.1 5 05/09/17 07:05 05/18/17 05:44 72-55-9
27.1 5 05/09/17 07:05 05/18/17 05:44 50-29-3
27.1 5 05/09/17 07:05 05/18/17 05:44 60-57-1
27.1 5 05/09/17 07:05 05/18/17 05:44 959-98-8
27.1 5 05/09/17 07:05 05/18/17 05:44 33213-65-9
27.1 5 05/09/17 07:05 05/18/17 05:44 1031-07-8
27.1 5 05/09/17 07:05 05/18/17 05:44 72-20-8
27.1 5 05/09/17 07:05 05/18/17 05:44 7421-93-4
27.1 5 05/09/17 07:05 05/18/17 05:44 53494-70-5
27.1 5 05/09/17 07:05 05/18/17 05:44 76-44-8
27.1 5 05/09/17 07:05 05/18/17 05:44 1024-57-3
27.1 5 05/09/17 07:05 05/18/17 05:44 118-74-1
67.6 5 05/09/17 07:05 05/18/17 05:44 72-43-5
67.6 5 05/09/17 07:05 05/18/17 05:44 2385-85-5
94.7 5 05/09/17 07:05 05/18/17 05:44 8001-35-2
35-108 5 05/09/17 07:05
21-123 5 05/09/17 07:05
Analytical Method: 9071 B Preparation Method: 9071 B
ND mg/kg
189 1 05/09/17 06:21
Analytical Method: MADEP EPH Preparation Method: MADEP EPH
ND
ND
ND
52
79
103
93
mg/kg
mg/kg
mg/kg
27.1
27.1
27.1
40-140
40-140
40-140
40-140
05/09/17 11:48
05/09/17 11:48
05/09/17 11:48
05/09/17 11:48
05/09/17 11:48
05/09/17 11:48
05/09/17 11:48
Analytical Method: MADEP VPH Preparation Method: MADEP VPH
ND
ND
ND
122
113
mg/kg
mg/kg
mg/kg
71.9
71.9
71.9
05/09/17 08:55
05/09/17 08:55
05/09/17 08:55
70-130 1 05/09/17 08:55
70-130 1 05/09/17 08:55
REPORT OF LABORATORY ANALYSIS
05/18/17 05:44 877-09-8 D3,S5
05/18/17 05:44 2051-24-3
05/09/17 14:38
05/16/17 00:23
05/16/17 00:23
05/16/17 00:23
05/16/17 00:23
05/16/17 00:23
05/16/17 00:23
05/16/17 00:23
05/10/17 10:10
05/10/17 10:10
05/10/17 10:10
7194-86-7
84-15-1
321-60-8
580-13-2
05/10/17 10:10 460-00-4
05/10/17 10:10 460-00-4
N2
N2
N2
N2,P4
N2,P4
N2,P4
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 7 of 32

ANALYTICAL RESULTS
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2017-GS-CBB2 Lab ID: 92339655002 Collected: 05/05/17 14:30 Received: 05/05/17 16:15 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Antimony ND mg/kg 1.2 1 05/10/17 17:05 05/13/17 17:58 7440-36-0
Arsenic 11.8 mg/kg 2.4 1 05/10/17 17:05 05/13/17 17:58 7440-38-2
Beryllium 0.31 mg/kg 0.24 1 05/10/17 17:05 05/13/17 17:58 7440-41-7
Cadmium ND mg/kg 0.24 1 05/10/17 17:05 05/13/17 17:58 7440-43-9
Chromium 22.3 mg/kg 1.2 1 05/10/17 17:05 05/13/17 17:58 7440-47-3
Copper 34.2 mg/kg 1.2 1 05/10/17 17:05 05/13/17 17:58 7440-50-8
Lead 15.1 mg/kg 1.2 1 05/10/17 17:05 05/13/17 17:58 7439-92-1
Nickel 4.2 mg/kg 1.2 1 05/10/17 17:05 05/13/17 17:58 7440-02-0
Selenium ND mg/kg 2.4 1 05/10/17 17:05 05/13/17 17:58 7782-49-2
Silver ND mg/kg 1.2 1 05/10/17 17:05 05/13/17 17:58 7440-22-4
Thallium ND mg/kg 2.4 1 05/10/17 17:05 05/13/17 17:58 7440-28-0
Zinc 70.9 mg/kg 2.4 1 05/10/17 17:05 05/13/17 17:58 7440-66-6
7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471
Mercury 0.052 mg/kg 0.0089 1 05/11/17 04:30 05/16/17 17:51 7439-97-6
8270 MSSV MW PAH by SIM Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546
Acenaphthene ND ug/kg 27.1 1 05/16/17 16:08 05/18/17 14:41 83-32-9
Acenaphthylene ND ug/kg 27.1 1 05/16/17 16:08 05/18/17 14:41 208-96-8
Anthracene 31.3 ug/kg 27.1 1 05/16/17 16:08 05/18/17 14:41 120-12-7
Benzo(a)anthracene 60.2 ug/kg 27.1 1 05/16/17 16:08 05/18/17 14:41 56-55-3
Benzo(a)pyrene 92.0 ug/kg 27.1 1 05/16/17 16:08 05/18/17 14:41 50-32-8
Benzo(b)fluoranthene 196 ug/kg 27.1 1 05/16/17 16:08 05/18/17 14:41 205-99-2
Benzo(g,h,i)perylene 66.4 ug/kg 27.1 1 05/16/17 16:08 05/18/17 14:41 191-24-2
Benzo(k)fluoranthene 48.2 ug/kg 27.1 1 05/16/17 16:08 05/18/17 14:41 207-08-9
Chrysene 97.7 ug/kg 27.1 1 05/16/17 16:08 05/18/17 14:41 218-01-9
Dibenz(a,h)anthracene ND ug/kg 27.1 1 05/16/17 16:08 05/18/17 14:41 53-70-3
Fluoranthene 167 ug/kg 27.1 1 05/16/17 16:08 05/18/17 14:41 206-44-0
Fluorene ND ug/kg 27.1 1 05/16/17 16:08 05/18/17 14:41 86-73-7
Indeno(1,2,3-cd)pyrene 65.1 ug/kg 27.1 1 05/16/17 16:08 05/18/17 14:41 193-39-5
1-Methylnaphthalene ND ug/kg 27.1 1 05/16/17 16:08 05/18/17 14:41 90-12-0
2-Methylnaphthalene ND ug/kg 27.1 1 05/16/17 16:08 05/18/17 14:41 91-57-6
Naphthalene 200 ug/kg 27.1 1 05/16/17 16:08 05/18/17 14:41 91-20-3
Phenanthrene 51.2 ug/kg 27.1 1 05/16/17 16:08 05/18/17 14:41 85-01-8
Pyrene 181 ug/kg 27.1 1 05/16/17 16:08 05/18/17 14:41 129-00-0
Surrogates
Nitrobenzene-d5 (S) 48 % 10-128 1 05/16/17 16:08 05/18/17 14:41 4165-60-0
2-Fluorobiphenyl (S) 34 % 10-110 1 05/16/17 16:08 05/18/17 14:41 321-60-8
Terphenyl-d14 (S) 40 % 39-119 1 05/16/17 16:08 05/18/17 14:41 1718-51-0
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture
63.0 % 0.10 1 05/09/17 08:14
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 8 of 32

ANALYTICAL RESULTS
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2017-GS-CBB2 Lab ID: 92339655002 Collected: 05/05/17 14:30 Received: 05/05/17 16:15 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Total Organic Carbon Analytical Method: EPA 9060 Modified
Surrogates
RPD% 2.2 % 0.10 1 05/15/1711:16
Total Organic Carbon 28500 mg/kg 27600 1 05/15/17 11:16 7440-44-0
Total Organic Carbon 29200 mg/kg 26700 1 05/15/17 11:22 7440-44-0
Mean Total Organic Carbon 28900 mg/kg 27100 1 05/15/17 11:16 7440-44-0
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 9 of 32

ANALYTICAL RESULTS
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2017-GS-CBB3
Lab ID: 92339655003 Collected: 05/05/17 00:00 Received: 05/05/17 16:15 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed
CAS No.
Qual
8081 GCS Pesticides
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Chlordane (Technical)
4,4'-DDD
4,4'-DDE
4,4'-DDT
Dieldrin
Endosulfan I
Endosulfan 11
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
Heptachlor
Heptachlor epoxide
Hexachlorobenzene
Methoxychlor
Mirex
Toxaphene
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
9071 SGT-HEM, TPH
Total Petroleum Hydrocarbons
MADEP EPH NC Soil
Aliphatic (C09-C18)
Aliphatic (C19-C36)
Aromatic (C11-C22)
Surrogates
Nonatriacontane (S)
o-Terphenyl (S)
2-Fluorobiphenyl (S)
2-Bromonaphthalene (S)
VPH NC Soil
Aliphatic (C05-008)
Aliphatic (C09-C12)
Aromatic (C09-C10)
Surrogates
4-Bromofluorobenzene (FID) (S)
4-Bromofluorobenzene (PID) (S)
Analytical Method: EPA 8081 Preparation Method: EPA 3546
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
0
27
22.8
22.8
22.8
22.8
22.8
79.7
22.8
22.8
22.8
22.8
22.8
22.8
22.8
22.8
22.8
22.8
22.8
22.8
22.8
56.9
56.9
79.7
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
5 05/09/17 07:05
35-108 5 05/09/17 07:05
21-123 5 05/09/17 07:05
Analytical Method: 9071 B Preparation Method: 9071 B
ND mg/kg
159 1 05/09/17 06:21
Analytical Method: MADEP EPH Preparation Method: MADEP EPH
ND
ND
ND
46
67
91
87
mg/kg
mg/kg
mg/kg
22.8
22.8
22.8
40-140
40-140
40-140
40-140
05/09/17 11:48
05/09/17 11:48
05/09/17 11:48
05/09/17 11:48
05/09/17 11:48
05/09/17 11:48
05/09/17 11:48
Analytical Method: MADEP VPH Preparation Method: MADEP VPH
ND
ND
ND
123
114
mg/kg
mg/kg
mg/kg
63.1
63.1
63.1
05/09/17 08:55
05/09/17 08:55
05/09/17 08:55
70-130 1 05/09/17 08:55
70-130 1 05/09/17 08:55
REPORT OF LABORATORY ANALYSIS
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
05/18/17 06:02
309-00-2
319-84-6
319-85-7
319-86-8
58-89-9
57-74-9
72-54-8
72-55-9
50-29-3
60-57-1
959-98-8
33213-65-9
1031-07-8
72-20-8
7421-93-4
53494-70-5
76-44-8
1024-57-3
118-74-1
72-43-5
2385-85-5
8001-35-2
05/18/17 06:02 877-09-8 D3,S5
05/18/17 06:02 2051-24-3
05/09/17 14:38
05/16/17 00:51
05/16/17 00:51
05/16/17 00:51
05/16/17 00:51
05/16/17 00:51
05/16/17 00:51
05/16/17 00:51
05/10/17 10:38
05/10/17 10:38
05/10/17 10:38
7194-86-7
84-15-1
321-60-8
580-13-2
05/10/17 10:38 460-00-4
05/10/17 10:38 460-00-4
N2
N2
N2
N2,P4
N2, P4
N2, P4
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 10 of 32

ANALYTICAL RESULTS
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2017-GS-CBB3
Lab ID: 92339655003 Collected: 05/05/17 00:00 Received: 05/05/17 16:15 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed
CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Nickel
Selenium
Silver
Thallium
Zinc
7471 Mercury
Mercury
8270 MSSV MW PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Percent Moisture
Percent Moisture
Analytical Method: EPA 6010 Preparation Method: EPA 3050
ND mg/kg
13.2 mg/kg
0.29 mg/kg
ND mg/kg
23.5 mg/kg
43.9 mg/kg
17.7 mg/kg
3.8 mg/kg
ND mg/kg
ND mg/kg
ND mg/kg
115 mg/kg
1.1 1 05/10/17 17:05 05/13/17 18:01 7440-36-0
2.2 1 05/10/17 17:05 05/13/17 18:01 7440-38-2
0.22 1 05/10/17 17:05 05/13/17 18:01 7440-41-7
0.22 1 05/10/17 17:05 05/13/17 18:01 7440-43-9
1.1 1 05/10/17 17:05 05/13/17 18:01 7440-47-3
1.1 1 05/10/17 17:05 05/13/17 18:01 7440-50-8
1.1 1 05/10/17 17:05 05/13/17 18:01 7439-92-1
1.1 1 05/10/17 17:05 05/13/17 18:01 7440-02-0
2.2 1 05/10/17 17:05 05/13/17 18:01 7782-49-2
1.1 1 05/10/17 17:05 05/13/17 18:01 7440-22-4
2.2 1 05/10/17 17:05 05/13/17 18:01 7440-28-0
2.2 1 05/10/17 17:05 05/13/17 18:01 7440-66-6
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.039 mg/kg 0.0062 1 05/11/17 04:30 05/16/17 17:53
Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546
ND ug/kg 22.8 1 05/09/17 10:15 05/15/17 22:49
ND ug/kg 22.8 1 05/09/17 10:15 05/15/17 22:49
ND ug/kg 22.8 1 05/09/17 10:15 05/15/17 22:49
86.0 ug/kg 22.8 1 05/09/17 10:15 05/15/17 22:49
89.8 ug/kg 22.8 1 05/09/17 10:15 05/15/17 22:49
148 ug/kg 22.8 1 05/09/17 10:15 05/15/17 22:49
53.1 ug/kg 22.8 1 05/09/17 10:15 05/15/17 22:49
64.4 ug/kg 22.8 1 05/09/17 10:15 05/15/17 22:49
107 ug/kg 22.8 1 05/09/17 10:15 05/15/17 22:49
ND ug/kg 22.8 1 05/09/17 10:15 05/15/17 22:49
181 ug/kg 22.8 1 05/09/17 10:15 05/15/17 22:49
ND ug/kg 22.8 1 05/09/17 10:15 05/15/17 22:49
55.7 ug/kg 22.8 1 05/09/17 10:15 05/15/17 22:49
ND ug/kg 22.8 1 05/09/17 10:15 05/15/17 22:49
ND ug/kg 22.8 1 05/09/17 10:15 05/15/17 22:49
ND ug/kg 22.8 1 05/09/17 10:15 05/15/17 22:49
83.4 ug/kg 22.8 1 05/09/17 10:15 05/15/17 22:49
141 ug/kg 22.8 1 05/09/17 10:15 05/15/17 22:49
42 % 10-128 1
27 % 10-110 1
34 % 39-119 1
Analytical Method: ASTM D2974-87
7439-97-6
83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0
05/09/17 10:15 05/15/17 22:49 4165-60-0
05/09/17 10:15 05/15/17 22:49 321-60-8
05/09/17 10:15 05/15/17 22:49 1718-51-0 SO
56.1 % 0.10 1 05/09/17 08:14
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 11 of 32

ANALYTICAL RESULTS
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2017-GS-CBB3
Lab ID: 92339655003 Collected: 05/05/17 00:00 Received: 05/05/17 16:15 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed
CAS No.
Qual
Total Organic Carbon
Surrogates
RPD%
Total Organic Carbon
Total Organic Carbon
Mean Total Organic Carbon
Analytical Method: EPA 9060 Modified
10.7
27300 mg/kg
24500 mg/kg
25900 mg/kg
0.10 1
16600 1
16400 1
16500 1
REPORT OF LABORATORY ANALYSIS
05/15/17 11:27
05/15/17 11:27 7440-44-0
05/15/17 11:33 7440-44-0
05/15/17 11:27 7440-44-0
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 12 of 32

QUALITY CONTROL DATA
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 359653 Analysis Method: 9071B
QC Batch Method: 9071B Analysis Description: 9071E SGT-HEM, TPH Gravimetric
Associated Lab Samples: 92339655001, 92339655002, 92339655003
METHOD BLANK: 1994535 Matrix: Solid
Associated Lab Samples: 92339655001, 92339655002, 92339655003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Petroleum Hydrocarbons mg/kg ND 70.0 05/09/17 14:38
LABORATORY CONTROL SAMPLE & LCSD: 1994536 1994537
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Total Petroleum Hydrocarbons mg/kg 667 643 660 97 99 78-114 3 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 13 of 32

QUALITY CONTROL DATA
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 359667 Analysis Method:
QC Batch Method: MADEP VPH Analysis Description:
Associated Lab Samples: 92339655001, 92339655002, 92339655003
MADEP VPH
VPH NC Soil
METHOD BLANK: 1994586
Matrix: Solid
Associated Lab Samples: 92339655001, 92339655002, 92339655003
Blank
Parameter Units Result
Reporting
Limit
Analyzed
Qualifiers
Aliphatic (C05-008)
Aliphatic (C09-C12)
Aromatic (C09-C10)
4-Bromofluorobenzene (FID) (S)
4-Bromofluorobenzene (PID) (S)
mg/kg
mg/kg
mg/kg
ND 2.5 05/09/17 14:45
ND 2.5 05/09/17 14:45
ND 2.5 05/09/17 14:45
120 70-130 05/09/1714:45
112 70-130 05/09/1714:45
N2
N2
N2
LABORATORY CONTROL SAMPLE & LCSD: 1994587
Parameter
Units
Spike
Conc.
1994588
LCS LCSD LCS LCSD % Rec
Result Result % Rec % Rec Limits
Max
RPD RPD Qualifiers
Aliphatic (C05-008)
Aliphatic (C09-C12)
Aromatic (C09-C10)
4-Bromofluorobenzene (FID) (S)
4-Bromofluorobenzene (PID) (S)
mg/kg
mg/kg
mg/kg
15 14.9 14.4 99 96 70-130 3 25 N2
15 14.9 15.3 99 102 30-130 3 25 N2
5 4.6 4.3 92 87 70-130 6 25 N2
122 122 70-130
115 114 70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 14 of 32

QUALITY CONTROL DATA
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 359947 Analysis Method: EPA 7471
QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury
Associated Lab Samples: 92339655001, 92339655002, 92339655003
METHOD BLANK: 1996184 Matrix: Solid
Associated Lab Samples: 92339655001, 92339655002, 92339655003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury mg/kg ND 0.0060 05/16/17 17:15
LABORATORY CONTROL SAMPLE: 1996185
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury mg/kg .083 0.087 104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1996186 1996187
MS MSD
92339778002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury
mg/kg ND .06 .069 0.042 0.049 68 69 75-125 16 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 15 of 32

QUALITY CONTROL DATA
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 359801 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET
Associated Lab Samples: 92339655001, 92339655002, 92339655003
METHOD BLANK: 1995392 Matrix: Solid
Associated Lab Samples: 92339655001, 92339655002, 92339655003
Blank Reporting
Parameter Units Result Limit Analyzed
Qualifiers
Antimony mg/kg ND 0.50 05/13/17 16:57
Arsenic mg/kg ND 1.0 05/13/17 16:57
Beryllium mg/kg ND 0.10 05/13/17 16:57
Cadmium mg/kg ND 0.10 05/13/17 16:57
Chromium mg/kg ND 0.50 05/13/17 16:57
Copper mg/kg ND 0.50 05/13/17 16:57
Lead mg/kg ND 0.50 05/13/17 16:57
Nickel mg/kg ND 0.50 05/13/17 16:57
Selenium mg/kg ND 1.0 05/13/17 16:57
Silver mg/kg ND 0.50 05/13/17 16:57
Thallium mg/kg ND 1.0 05/13/17 16:57
Zinc mg/kg ND 1.0 05/13/17 17:01
LABORATORY CONTROL SAMPLE: 1995393
Parameter
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
Antimony mg/kg 50 49.3 99 80-120
Arsenic mg/kg 50 47.0 94 80-120
Beryllium mg/kg 50 47.9 96 80-120
Cadmium mg/kg 50 48.6 97 80-120
Chromium mg/kg 50 47.9 96 80-120
Copper mg/kg 50 50.2 100 80-120
Lead mg/kg 50 48.0 96 80-120
Nickel mg/kg 50 47.6 95 80-120
Selenium mg/kg 50 49.2 98 80-120
Silver mg/kg 25 25.2 101 80-120
Thallium mg/kg 50 48.1 96 80-120
Zinc mg/kg 50 49.9 100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1995394 1995395
MS MSD
92339708006 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Antimony mg/kg ND 39.4 45.1 22.4 28.5 57 63 75-125 24 M1,R1
Arsenic mg/kg 2.1 39.4 45.1 31.9 39.0 75 82 75-125 20
Beryllium mg/kg 0.30 39.4 45.1 33.1 40.1 83 88 75-125 19
Cadmium mg/kg ND 39.4 45.1 33.7 40.1 85 89 75-125 17
Chromium mg/kg 136 39.4 45.1 166 147 76 24 75-125 12 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 16 of 32

QUALITY CONTROL DATA
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1995394 1995395
MS MSD
92339708006 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Copper mg/kg 27.1 39.4 45.1 56.4 58.8 74 71 75-125 4 M1
Lead mg/kg 13.7 39.4 45.1 58.6 51.2 114 83 75-125 13
Nickel mg/kg 581 39.4 45.1 232 161 -884 -932 75-125 36 M1,R1
Selenium mg/kg 0.59J 39.4 45.1 31.7 39.0 79 85 75-125 21 R1
Silver mg/kg ND 19.7 22.5 17.7 21.0 89 93 75-125 17
Thallium mg/kg ND 39.4 45.1 29.6 36.4 75 81 75-125 21 R1
Zinc mg/kg 139 39.4 45.1 183 126 111 -28 75-125 37 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 17 of 32

QUALITY CONTROL DATA
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 359659 Analysis Method: EPA 8081
QC Batch Method: EPA 3546 Analysis Description: 8081 GCS Pesticides
Associated Lab Samples: 92339655001, 92339655002, 92339655003
METHOD BLANK: 1994550 Matrix: Solid
Associated Lab Samples: 92339655001, 92339655002, 92339655003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
4,4'-DDD ug/kg ND 2.0 05/12/17 13:45
4,4'-DDE ug/kg ND 2.0 05/12/17 13:45
4,4'-DDT ug/kg ND 2.0 05/12/17 13:45
Aldrin ug/kg ND 2.0 05/12/17 13:45
alpha-BHC ug/kg ND 2.0 05/12/17 13:45
beta-BHC ug/kg ND 2.0 05/12/17 13:45
Chlordane (Technical) ug/kg ND 7.0 05/12/17 13:45
delta-BHC ug/kg ND 2.0 05/12/17 13:45
Dieldrin ug/kg ND 2.0 05/12/17 13:45
Endosulfan I ug/kg ND 2.0 05/12/17 13:45
Endosulfan II ug/kg ND 2.0 05/12/17 13:45
Endosulfan sulfate ug/kg ND 2.0 05/12/17 13:45
Endrin ug/kg ND 2.0 05/12/17 13:45
Endrin aldehyde ug/kg ND 2.0 05/12/17 13:45
Endrin ketone ug/kg ND 2.0 05/12/17 13:45
gamma-BHC (Lindane) ug/kg ND 2.0 05/12/17 13:45
Heptachlor ug/kg ND 2.0 05/12/17 13:45
Heptachlor epoxide ug/kg ND 2.0 05/12/17 13:45
Hexachlorobenzene ug/kg ND 2.0 05/12/17 13:45
Methoxychlor ug/kg ND 5.0 05/12/17 13:45
Mirex ug/kg ND 5.0 05/12/17 13:45
Toxaphene ug/kg ND 7.0 05/12/17 13:45
Decachlorobiphenyl (S) % 79 21-123 05/12/17 13:45
Tetrachloro-m-xylene (S) % 74 35-108 05/12/17 13:45
LABORATORY CONTROL SAMPLE & LCSD: 1994551 1994552
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
4,4'-DDD ug/kg 8.3 6.2 6.5 75 79 63-126 5 30
4,4'-DDE ug/kg 8.3 6.2 6.8 76 82 62-126 9 30
4,4'-DDT ug/kg 8.3 6.6 7.2 80 87 65-135 9 30
Aldrin ug/kg 8.3 5.7 6.3 69 76 40-120 10 30
alpha-BHC ug/kg 8.3 5.4 6.0 65 73 37-123 11 30
beta-BHC ug/kg 8.3 5.1 5.8 61 71 51-113 14 30
delta-BHC ug/kg 8.3 4.8 5.3 59 65 25-139 10 30
Dieldrin ug/kg 8.3 6.2 6.8 75 82 54-125 9 30
Endosulfan I ug/kg 8.3 6.3 6.9 76 84 54-125 10 30
Endosulfan II ug/kg 8.3 6.3 7.0 76 84 62-121 10 30
Endosulfan sulfate ug/kg 8.3 6.3 6.9 77 83 39-121 8 30
Endrin ug/kg 8.3 6.6 7.2 79 87 65-134 9 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 18 of 32

QUALITY CONTROL DATA
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE & LCSD: 1994551 1994552
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Endrin aldehyde ug/kg 8.3 6.0 6.7 73 81 44-121 11 30
Endrin ketone ug/kg 8.3 6.2 6.8 75 82 59-124 9 30
gamma-BHC (Lindane) ug/kg 8.3 5.7 6.3 69 77 41-121 10 30
Heptachlor ug/kg 8.3 5.6 6.3 68 76 43-120 11 30
Heptachlor epoxide ug/kg 8.3 5.5 6.1 66 74 47-118 11 30
Hexachlorobenzene ug/kg 8.3 5.5 6.1 67 74 50-150 9 30
Methoxychlor ug/kg 24.8 20.5 22.2 83 90 68-125 8 30
Mirex ug/kg 24.8 18.2 19.9 74 80 59-114 9 30
Decachlorobiphenyl (S) % 75 82 21-123
Tetrachloro-m-xylene (S) % 71 75 35-108
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 19 of 32

QUALITY CONTROL DATA
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 359696 Analysis Method: EPA 8270 by SIM
QC Batch Method: EPA 3546 Analysis Description: 8270 MSSV PAH by SIM
Associated Lab Samples: 92339655001, 92339655003
METHOD BLANK: 1994756 Matrix: Solid
Associated Lab Samples: 92339655001, 92339655003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1-Methylnaphthalene ug/kg ND 10.0 05/15/17 16:36
2-Methylnaphthalene ug/kg ND 10.0 05/15/17 16:36
Acenaphthene ug/kg ND 10.0 05/15/17 16:36
Acenaphthylene ug/kg ND 10.0 05/15/17 16:36
Anthracene ug/kg ND 10.0 05/15/17 16:36
Benzo(a)anthracene ug/kg ND 10.0 05/15/17 16:36
Benzo(a)pyrene ug/kg ND 10.0 05/15/17 16:36
Benzo(b)fluoranthene ug/kg ND 10.0 05/15/17 16:36
Benzo(g,h,i)perylene ug/kg ND 10.0 05/15/17 16:36
Benzo(k)fluoranthene ug/kg ND 10.0 05/15/17 16:36
Chrysene ug/kg ND 10.0 05/15/17 16:36
Dibenz(a,h)anthracene ug/kg ND 10.0 05/15/17 16:36
Fluoranthene ug/kg ND 10.0 05/15/17 16:36
Fluorene ug/kg ND 10.0 05/15/17 16:36
Indeno(1,2,3-cd)pyrene ug/kg ND 10.0 05/15/17 16:36
Naphthalene ug/kg ND 10.0 05/15/17 16:36
Phenanthrene ug/kg ND 10.0 05/15/17 16:36
Pyrene ug/kg ND 10.0 05/15/17 16:36
2-Fluorobiphenyl (S) % 50 10-110 05/15/17 16:36
Nitrobenzene-d5 (S) % 56 10-128 05/15/17 16:36
Terphenyl-d14 (S) % 62 39-119 05/15/17 16:36
LABORATORY CONTROL SAMPLE: 1994757
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1-Methylnaphthalene ug/kg 33.3 17.8 53 44-130
2-Methylnaphthalene ug/kg 33.3 18.3 55 41-134
Acenaphthene ug/kg 33.3 18.5 55 52-123
Acenaphthylene ug/kg 33.3 18.5 55 49-116
Anthracene ug/kg 33.3 21.8 65 41-133
Benzo(a)anthracene ug/kg 33.3 21.1 63 56-130
Benzo(a)pyrene ug/kg 33.3 20.5 61 51-136
Benzo(b)fluoranthene ug/kg 33.3 20.5 61 37-149
Benzo(g,h,i)perylene ug/kg 33.3 19.5 58 39-127
Benzo(k)fluoranthene ug/kg 33.3 22.6 68 45-139
Chrysene ug/kg 33.3 21.7 65 59-127
Dibenz(a,h)anthracene ug/kg 33.3 21.0 63 37-139
Fluoranthene ug/kg 33.3 21.4 64 53-132
Fluorene ug/kg 33.3 20.4 61 45-127
Indeno(1,2,3-cd)pyrene ug/kg 33.3 21.0 63 35-145
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 20 of 32

QUALITY CONTROL DATA
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 1994757
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits
Qualifiers
Naphthalene ug/kg 33.3 18.5 55 45-123
Phenanthrene ug/kg 33.3 19.3 58 50-125
Pyrene ug/kg 33.3 21.0 63 52-132
2-Fluorobiphenyl (S) % 59 10-110
Nitrobenzene-d5 (S) % 66 10-128
Terphenyl-d14 (S) % 71 39-119
SAMPLE DUPLICATE: 1994759
92339552022 Dup
Parameter Units Result Result RPD Qualifiers
1-Methylnaphthalene ug/kg ND ND
2-Methylnaphthalene ug/kg ND ND
Acenaphthene ug/kg ND ND
Acenaphthylene ug/kg 22.0J 32.2J
Anthracene ug/kg 33.3J 31.5J
Benzo(a)anthracene ug/kg 114 94.3J
Benzo(a)pyrene ug/kg 116 103J
Benzo(b)fluoranthene ug/kg 161 144 11
Benzo(g,h,i)perylene ug/kg 86.0J 81.3J
Benzo(k)fluoranthene ug/kg 76.5J ND
Chrysene ug/kg 134 103J
Dibenz(a,h)anthracene ug/kg 27.3J 24.9J
Fluoranthene ug/kg 196 149 28
Ftuorene ug/kg ND ND
Indeno(1,2,3-cd)pyrene ug/kg 76.2J 70.6J
Naphthalene ug/kg ND ND
Phenanthrene ug/kg 106J 74.8J
Pyrene ug/kg 174 133 27
2-Fluorobiphenyl (S) % 0 0 S4
Nitrobenzene-d5 (S) % 0 0 D3,S4
Terphenyl-d14 (S) % 0 0 S4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 21 of 32

QUALITY CONTROL DATA
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 360764 Analysis Method: EPA 8270 by SIM
QC Batch Method: EPA 3546 Analysis Description: 8270 MSSV PAH by SIM
Associated Lab Samples: 92339655002
METHOD BLANK: 2000914 Matrix: Solid
Associated Lab Samples: 92339655002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1-Methylnaphthalene ug/kg ND 10.0 05/18/17 13:54
2-Methylnaphthalene ug/kg ND 10.0 05/18/17 13:54
Acenaphthene ug/kg ND 10.0 05/18/17 13:54
Acenaphthylene ug/kg ND 10.0 05/18/17 13:54
Anthracene ug/kg ND 10.0 05/18/17 13:54
Benzo(a)anthracene ug/kg ND 10.0 05/18/17 13:54
Benzo(a)pyrene ug/kg ND 10.0 05/18/17 13:54
Benzo(b)fluoranthene ug/kg ND 10.0 05/18/17 13:54
Benzo(g,h,i)perylene ug/kg ND 10.0 05/18/17 13:54
Benzo(k)fluoranthene ug/kg ND 10.0 05/18/17 13:54
Chrysene ug/kg ND 10.0 05/18/17 13:54
Dibenz(a,h)anthracene ug/kg ND 10.0 05/18/17 13:54
Fluoranthene ug/kg ND 10.0 05/18/17 13:54
Fluorene ug/kg ND 10.0 05/18/17 13:54
Indeno(1,2,3-cd)pyrene ug/kg ND 10.0 05/18/17 13:54
Naphthalene ug/kg ND 10.0 05/18/17 13:54
Phenanthrene ug/kg ND 10.0 05/18/17 13:54
Pyrene ug/kg ND 10.0 05/18/17 13:54
2-Fluorobiphenyl (S) % 65 10-110 05/18/17 13:54
Nitrobenzene-d5 (S) % 76 10-128 05/18/17 13:54
Terphenyl-d14 (S) % 68 39-119 05/18/17 13:54
LABORATORY CONTROL SAMPLE: 2000915
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1-Methylnaphthalene ug/kg 33.3 21.0 63 44-130
2-Methylnaphthalene ug/kg 33.3 22.4 67 41-134
Acenaphthene ug/kg 33.3 22.6 68 52-123
Acenaphthylene ug/kg 33.3 23.7 71 49-116
Anthracene ug/kg 33.3 24.4 73 41-133
Benzo(a)anthracene ug/kg 33.3 22.6 68 56-130
Benzo(a)pyrene ug/kg 33.3 22.5 67 51-136
Benzo(b)fluoranthene ug/kg 33.3 23.6 71 37-149
Benzo(g,h,i)perylene ug/kg 33.3 19.5 59 39-127
Benzo(k)fluoranthene ug/kg 33.3 24.6 74 45-139
Chrysene ug/kg 33.3 24.5 73 59-127
Dibenz(a,h)anthracene ug/kg 33.3 22.5 68 37-139
Fluoranthene ug/kg 33.3 24.0 72 53-132
Fluorene ug/kg 33.3 25.5 77 45-127
Indeno(1,2,3-cd)pyrene ug/kg 33.3 22.1 66 35-145
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 22 of 32

QUALITY CONTROL DATA
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 2000915
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits
Qualifiers
Naphthalene ug/kg 33.3 22.8 68 45-123
Phenanthrene ug/kg 33.3 23.1 69 50-125
Pyrene ug/kg 33.3 23.6 71 52-132
2-Fluorobiphenyl (S) % 74 10-110
Nitrobenzene-d5 (S) % 85 10-128
Terphenyl-d14 (S) % 72 39-119
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 23 of 32

QUALITY CONTROL DATA
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 359714 Analysis Method: MADEP EPH
QC Batch Method: MADEP EPH Analysis Description: MADEP EPH NC Soil
Associated Lab Samples: 92339655001, 92339655002, 92339655003
METHOD BLANK: 1994884 Matrix: Solid
Associated Lab Samples: 92339655001, 92339655002, 92339655003
Blank Reporting
Parameter Units Result Limit Analyzed
Qualifiers
Aliphatic (C09-C18)
Aliphatic (C19-C36)
Aromatic (C11-C22)
2-Bromonaphthalene (S)
2-Fluorobiphenyl (S)
Nonatriacontane (S)
o-Terphenyl (S)
mg/kg
mg/kg
mg/kg
ND 10.0 05/15/17 22:34 N2
ND 10.0 05/15/17 22:34 N2
ND 10.0 05/15/17 22:34 N2
72 40-140 05/15/17 22:34
80 40-140 05/15/17 22:34
57 40-140 05/15/17 22:34
64 40-140 05/15/17 22:34
LABORATORY CONTROL SAMPLE & LCSD: 1994885 1994886
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Aliphatic (C09-C18) mg/kg 10 ND ND 78 73 40-140 50 N2
Aliphatic (C19-C36) mg/kg 13.3 11.0 10.6 83 79 40-140 4 50 N2
Aromatic (C11-C22) mg/kg 28.3 22.0 24.6 77 87 40-140 12 50 N2
2-Bromonaphthalene (S) % 74 84 40-140
2-Fluorobiphenyl (S) % 85 98 40-140
Nonatriacontane (S) % 70 62 40-140
o-Terphenyl (S) % 81 86 40-140
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 24 of 32

QUALITY CONTROL DATA
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 359589 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Associated Lab Samples: 92339655001, 92339655002, 92339655003
SAMPLE DUPLICATE: 1994317
92339701001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture
0/0
13.4
12.2 10
SAMPLE DUPLICATE: 1994318
92339655003 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture
56.1 56.4 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 25 of 32

QUALITY CONTROL DATA
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 255513 Analysis Method: EPA 9060 Modified
QC Batch Method: EPA 9060 Modified Analysis Description: 9060 TOC Average
Associated Lab Samples: 92339655001, 92339655002, 92339655003
METHOD BLANK: 1506945 Matrix: Solid
Associated Lab Samples: 92339655001, 92339655002, 92339655003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mean Total Organic Carbon mg/kg ND 668 05/15/17 10:08
LABORATORY CONTROL SAMPLE: 1506946
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mean Total Organic Carbon
mg/kg 120000 111000 93 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1506947 1506948
MS MSD
92339655001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mean Total Organic Carbon
mg/kg 45600 368000 340000 387000 343000 93 87 50-150 12
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 26 of 32

QUALIFIERS
Project: CAROLINA BEACH
Pace Project No.: 92339655
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A
PASI-C
PASI-G
Pace Analytical Services - Asheville
Pace Analytical Services - Charlotte
Pace Analytical Services - Green Bay
ANALYTE QUALIFIERS
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
N2 The lab does not hold NELAC/TNI accreditation for this parameter.
P4 Sample field preservation does not meet EPA or method recommendations for this analysis.
R1 RPD value was outside control limits.
SO Surrogate recovery outside laboratory control limits.
S4 Surrogate recovery not evaluated against control limits due to sample dilution.
S5 Surrogate recovery outside control limits due to matrix interferences (not confirmed by re -analysis).
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 27 of 32

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: CAROLINA BEACH
Pace Project No.: 92339655
Lab ID Sample ID
Analytical
QC Batch Method QC Batch Analytical Method Batch
92339655001 2017-GS-CBB1 EPA 3546 359659 EPA 8081 360187
92339655002 2017-GS-CBB2 EPA 3546 359659 EPA 8081 360187
92339655003 2017-GS-CBB3 EPA 3546 359659 EPA 8081 360187
92339655001 2017-GS-CBB1 9071E 359653 9071E 359656
92339655002 2017-GS-CBB2 9071E 359653 9071E 359656
92339655003 2017-GS-CBB3 9071E 359653 9071E 359656
92339655001 2017-GS-CBB1 MADEP EPH 359714 MADEP EPH 360581
92339655002 2017-GS-CBB2 MADEP EPH 359714 MADEP EPH 360581
92339655003 2017-GS-CBB3 MADEP EPH 359714 MADEP EPH 360581
92339655001 2017-GS-CBB1 MADEP VPH 359667 MADEP VPH 359876
92339655002 2017-GS-CBB2 MADEP VPH 359667 MADEP VPH 359876
92339655003 2017-GS-CBB3 MADEP VPH 359667 MADEP VPH 359876
92339655001 2017-GS-CBB1 EPA 3050 359801 EPA 6010 360062
92339655002 2017-GS-CBB2 EPA 3050 359801 EPA 6010 360062
92339655003 2017-GS-CBB3 EPA 3050 359801 EPA 6010 360062
92339655001 2017-GS-CBB1 EPA 7471 359947 EPA 7471 360077
92339655002 2017-GS-CBB2 EPA 7471 359947 EPA 7471 360077
92339655003 2017-GS-CBB3 EPA 7471 359947 EPA 7471 360077
92339655001 2017-GS-CBB1 EPA 3546 359696 EPA 8270 by SIM 360583
92339655002 2017-GS-CBB2 EPA 3546 360764 EPA 8270 by SIM 361124
92339655003 2017-GS-CBB3 EPA 3546 359696 EPA 8270 by SIM 360583
92339655001 2017-GS-CBB1 ASTM D2974-87 359589
92339655002 2017-GS-CBB2 ASTM D2974-87 359589
92339655003 2017-GS-CBB3 ASTM D2974-87 359589
92339655001 2017-GS-CBB1 EPA 9060 Modified 255513
92339655001 2017-GS-CBB1 EPA 9060 Modified 255526
92339655002 2017-GS-CBB2 EPA 9060 Modified 255513
92339655002 2017-GS-CBB2 EPA 9060 Modified 255526
92339655003 2017-GS-CBB3 EPA 9060 Modified 255513
92339655003 2017-GS-CBB3 EPA 9060 Modified 255526
REPORT OF LABORATORY ANALYSIS
Date: 05/19/2017 04:38 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 28 of 32

m
aceAnalytical
1
Document Name:
Sample Condition Upon Receipt(SCUR)
Document Revised: Sept. 21, 2016
Page 1 of 2
Document No.:
F-CAR-CS-033-Rev.O1
Issuing Authority:
Pace Quality Office
Laboratory receiving samples:
Asheville ❑ Eden Greenwood ❑ Huntersville7 Raleigh❑ Mechanicsville❑
Sample Condition Upon
Receipt
Courier:
❑ Commercial
Client Nan�.e:
COS:
❑Fed x ❑UPS ❑LISPS
❑Pace ❑tither:
Project#:
['Client
CustodySeal Present?.0 1 ❑Yes ,❑No Seals Intact? Dyes No
Packing Material: ❑Bubble Wrap ibble Bags ❑None ['Other:
Thermometer:
IR Gun ID: T \ �c)( Wet ❑Blue ❑None Samples on ice, cooling process has begun
Type once: I /
Correction Factor: Cooler Temp Corrected (°C): 3 • -2 Biological Tissue Frozen? ❑Yes ❑No ,❑N/A
Temp should be above freezing to 6°C
USDA Regulated Soil (❑ N/A, water sample)
Did samples, originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally,
Des QNo
WOW92339655
11111111 I II III II III III
Date/Initials Person Examining Contents: I��f
Comments/Discrepancy:
Chain of Custody Present?
'es
No
❑N/A
1.
Samples Arrived within Hold Time?
(
es
❑No
2.
• N/A
Short Hold Time Analysis (<72 hr.)?
Eyes
„ago
3.
• N/A
Rush Turn Around Time Requested?
['Yes
110
4.
■N/A
Sufficient Volume?
°-s
:No
5.
■ N/A
Correct Containers Used?
-Pace Containers Used?
__Pins
.Yes
No
❑N/A
6.
■ No
■ N/A
Containers Intact?
es
❑N/A
7.
• No
Samples Field Filtered?
❑No
,,lot A
81 Note I sediment is visible in the dissolved container
■Yes
Sample Labels MatchCOC?
-Includes Date/Time/ID/Analysis
Matrix:
A.
mNo
/
❑N/A
9�bbI 1-1I �.3I 11 l 11116 CI) • rJtl�ICck�
r i I t �� 7 � ` t �� 1'' I �'7 6/
■Yes
Headspace in VOA Vials (>5-6mm)?
Trip Blank Present?
Trip Blank Custody Seals Present?
EYes
❑Yes
10. 7 - 1 ,-15
11. NO soiii plc It '1)es oil h 11 ICs in ,i,p,c
.. .,( ctyC•jX;l
■No
iN/A
❑No
❑Na
• N/A
I ■Yes
■N/A
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Sample
Discrepancy:
tinOl1S6. CD011(Cel le�tl Data Requ red .❑Yes ❑No
-II) ys)s on H l
Date/Time:
trfl Once( I r -,`ate at() CoG . if )q took
p.br s(ynpLo. 1 b C,131 6-ion 11ifo inn can-l---axv10. •
lOgPCA 1Y1 OuVA_ Lies ( (,(56,
Project Manager SCURF Review:
Project Manager SRF Review:
46rw,
Date: 6-•
Date:
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e,
Out of hold, incorrect preservative, out of temp, incorrect containers)
Page 29 of 32

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Page 30 of 32

Document Name:
Sample Condition Upon Receipt(SCUR)
Document Revised: Sept. 21, 2016
Page 2 of 2
ace Analytical
Document No.:
f-CAR-CS-033-Rev.01
Issuing Authority:
Pace Quality Office
*Check mark top half of box if pH and/or dechlorination Project #
WO# : 92339655
is verified and within the acceptance range for
preservation samples.
**Bottom half of box is to list number of bottles
PM: AMB Due Date: 05/19/17
CLIENT: 92—T1 COASTA
N
BP4U-125 mL Plastic Unpreserved (N/A) (CI-)
BP3U-250 mL Plastic Unpreserved (N/A)
BP2U-500 mL Plastic Unpreserved (N/A)
BP1U-1 liter Plastic Unpreserved (N/A)
BP3S-250 mL Plastic H2SO4 (pH < 2) (CI-)
BP3N-250 mL plastic HNO3 (pH < 2)
BP32-250 mL Plastic ZN Acetate & NaOH (>9)
BP3C-250 mL Plastic NaOH (pH > 12) (CI-)
WGFU-Wide-mouthed Glass jar Unpreserved
AG1U-1 liter Amber Unpreserved (N/A) (CI-)
AG1H-1 liter Amber HCI (pH < 2)
AG3U-250 mL Amber Unpreserved (N/A) (CI-)
AG15-1 liter Amber H2SO4 (pH < 2)
AG3S-250 mL Amber H2SO4 (pH < 2)
AG3A(DG3A)-250 mL Amber NH4CI (N/A)(CI-)
DG9H-40 mL VOA HCI (N/A)
VG9T-40 mL VOA Na2S203 (N/A)
VG9U-40 mL VOA Unp (N/A)
DG9P-40 mL VOA H3PO4 (N/A)
VOAK (6 vials per kit)-5035 kit (N/A)
V/GK (3 vials per kit)-VPH/Gas kit (N/A)
SPST-125 mL Sterile Plastic (N/A— lab)
SPIT-250 mL Sterile Plastic (N/A — lab)
BP3A-250 mL Plastic (NH2)2504 (9.3-9.7)
Cubitainer
a
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot #
Page 31 of 32

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FALL-Q-020rev.07, 15-Feb-2007
SAMPLER NAME AND SIGNATURE
PRINT Name of SAMPLER: - - \ ,
DATE Signed
SIGNATURE of SAMPLER: - {MMiDDT Yy: -
I'Metals - Sb, As, Be, Cd, Cr, Cu, Pb, Ni, Se, Ag, TI. Zn
ADDITIONAL COMMENTS
N
o
m
m
.1
m
w
v
w
N
-,
ITEM #
(Requested Due DeteITAT: 10 days
to
O
Ozi
W
m
n
Email To: jcspratt@ticoastaLcom
Wilmington, NC 28405
Address: 387B Green Meadows Drive
Company: TI Coastal
Section A Section B Section C
Required Client Information: Required Project Information: Invoice Information:
Section b Valid Matrix Codes
Required Client Information I25 CODE
DRIMINDWA1tR OW
WATER WI
WASTE WATER WW
PRODUCT P
SOILISOLI❑ SL
O
SAMPLE ID wIILPE WP
A1R AR
(A-Z, 0-9 / ,-) OTHER OT
Sample 10s MUST BE UNIQUE TISSUE TS
Project Number:
Project Name: Carolina Beach
b
C
n
m
O
ia'
z
-.
Copy To:
Report To: Jamie Pratt
RELINQUISHED BY 1 AFFILIATION
-
MATRIX CODE (see veldcodes to left}
SAMPLE TYPE (G=GRAB C=COMP)
D
a
rM
COMPOSITE
START
COLLECTED
-1
3
m
vs
J`
➢ i
m0
p°
l
DATE
.1
-
IV
IV
'1
m
SAMPLE TEMP AT COLLECTION
m
.r
-4
-4
# OF CONTAINERS
Pace Profile #: 6738-2
Pace Prolect Angela Baionl
Maragen
Pace Quote
Reference:
D
o
Company Name:
Attention: TI Coastal
V
-4
—r
Unpreserved
Preservatives
H2SO4
(41F
w
ram,
,)"..sa,
.4
I
-
ACCEPTED BY ! AFFILIATION
HNO3
MCI
NaOH
Na-Szo3
Methanol
01her
'AnalysisTesti
'ON4
Requested Analysis Filtered I
Metals by 6010'
7471 Mercury
TOG by 9060
Oil & Grease with slice gel cleanup
����
MADEP VPH
Site Location
STATE:
I- NPDES GROUND WATER — DRINKING WATER
UST RCRA OTHER
REGULATORY AGENCY
''r
V.�
MAOEP EPH
,SIM PAH
,1
Peslicides by 8081
% Moisture
z
n
z
m
o
Temp In°c
LP,'
-
>L.
[ SAMPLE CONDITIONS
..�
Residual Chlorine (Y/N)
Received
roe (YIN))
.,.�.
` ,
^�
Pace Project No.l Lab I.D.
Cuslody
Sealed Cooler
(YfN)
Z.
Samples Intact
(Y!N)
1G
Page 32 of 32