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HomeMy WebLinkAboutNCS000549_Riverbend SW Permit Application Updated Info_20140505f � DUKE ENERGY May 15, 2014 Mr Bradley Bennett State of North Carolina Department of Environment and Natural Resources Division of Energy, Mineral & Land Resources Stormwater Permitting Program 1612 Mail Service Center Raleigh, North Carolina 27699 -1612 Subject. Duke Energy Carolinas LLC - Stormwater Supplemental Information Riverbend Steam Station - NPDES Permit #NC0004961 Dear Mr. Bennett: Environmental Services Duke Energy 526 South Church Street Charlotte, NC 28202 Mailing Address. Mail Code EC13K/ P O Box 1006 Charlotte, NC 28201 -1006 Please refer to the attached addendum, which represents updates to the stormwater application that was submitted to your office on May 9, 2011 for Riverbend Steam Station (also attached). Since the date of the original application submittal, Riverbend Steam Station ceased industrial operation of all of its electric generating units (April 1, 2013) Also enclosed is location map which depicts the current stormwater outfalls and their coordinates. A rainfall event was observed on May 9, 2014. This event resulted in adequate sample flow at some outfalls Stormwater outfalls SW001, SW002, SW003, SWO10 and SWO11 were sampled at this time. The analytical results will be provided to you as soon as they are available. The remaining outfalls could not be sampled due to insufficient or nonexistent flow. These outfalls will be sampled and analyzed when a sufficient storm event occurs to produce adequate sample flow. If additional information is needed, please advise Should you have questions regarding this application, please contact Allen Stowe at (704) 382 -4309. Sincerel Jason Allen Senior Vice President Environmental, Health & Safety Attachments cc w/. Mr. Mike Parker - NCDENR Mooresville R.O. RIVERBEND STEAM STATION Stormwater Discharge Permit Application Form 2F Supplemental Information GENERAL SITE INFORMATION Riverbend Steam Station was a fossil - fueled, electric generation plant located in Gaston County approximately six miles northeast of Mount Holly, North Carolina. The station property encompasses 572 acres adjacent to and on the western side of Mountain Island Lake which is formed by the Catawba River. The station is accessed from Steam Plant Road off of Horseshoe Bend Beach Road. Riverbend Steam Station was retired on April 1, 2013. The station had four coal -fired generation units with a total generating capacity of 454 megawatts; four oil or gas -fired combustion turbine units rated at 30 megawatts each. The primary station generation yard area encompasses approximately 20 acres. The facility includes a Main Switchyard, a 44 kV Switchyard, and a 230 kV Switchyard occupying a total of approximately 8 acres. Also associated with the station is a coal storage pile covering approximately 13 acres (all useable coal was shipped to Marshall Steam Station), a primary ash setting basin occupying approximately 41 acres, a secondary ash settling basin occupying approximately 28 acres, and a closed dry ash stack occupying approximately 35 acres. Prior to construction of the ash settling basins, waste ash was disposed of in a cinder pit that remains on -site and encompasses approximately 9 acres. The ash stack was used as a repository for ash cleaned out of the ash settling basins. The ash stack is no longer used and has been stabilized with a vegetated soil cap. The Riverbend Steam Station also has several construction spoil and laydown areas, a wastewater treatment facility, a warehouse, a fuel oil storage tank (now empty), paved parking areas, approximately one mile of rail lines, and approximately one mile of paved access roadways. The Lark Maintenance Garage is considered part of the Riverbend Steam Station as well, and is located along the facility western property boundary. In developed areas, runoff generally flows overland to ditches and catch basins which are connected to a buried network of corrugated metal pipes (CMP). In most areas west of the Powerhouse, this collected runoff discharges into one of three oil trap tanks prior to discharging to surface waters. In most areas east of the Powerhouse, this collected runoff discharges into the station yard sump that subsequently pumps to the ash settling basins. The Riverbend Steam Station maintains an up -to -date Spill Prevention Control and Countermeasures (SPCC) Plan in place in accordance with the USEPA Oil Pollution Prevention Regulation 40 CFR Part 112. Riverbend Steam Station was included in the stormwater application submitted to EPA in March of 1991. Stormwater outfalls SW001, SW002 and SW003 have been evaluated and deemed representative of the other stormwater outfalls at Riverbend Steam Station. Form 2F has been submitted as part of the NPDES permit renewal applications. STORMWATER OUTFALLS AND DRAINAGE AREA DESCRIPTIONS The Riverbend Steam Station has twelve identified active stormwater outfalls that discharge to surface waters. The outfall locations and contributing drainage area delineations are shown on the accompanying site plan. All identified stormwater outfalls discharge into Mountain Island Lake formed by the Catawba River. Five outfalls discharge into the station intake canal upstream of the plant intake structure. Two outfalls discharge into Mountain Island Lake north of the coal storage pile. The remaining five outfalls discharge onto the ground and then flow overland eventually reaching Mountain Island Lake. There are two abandoned outfalls at the station. A description of the contributing drainage area for each outfall is provided below. Included with the description is the approximate location coordinates of the outfalls, the amount of impervious surface area within the drainage areas, a description of any significant materials and activities located within the drainage areas, the type of discharge conveyances, and a description of any discharge control measures. Also included is a Stormwater Outfall Location Map (see Figure 1). In addition to any significant materials particular to each drainage basin, herbicides are applied to selected areas at the Riverbend Steam Station to eliminate undesirable vegetation. Herbicides are generally used along railways, ash pipelines, and the perimeter fence. Herbicides are also applied, as needed, in the gravel parking lots, switchyard, and laydown areas. Herbicides are sprayed around the fuel oil bulk storage tanks, yard sumps, transformers, trailers, and the intake structure. All herbicides used at Riverbend Steam Station are approved by the company and considered safe to the environment when used according to directions. Records are retained at the facility documenting the areas treated, and the type and amount of herbicides used. Certain stormwater outfall drainage areas share similarities regarding the presence of significant materials and /or activities. Based on these similarities, stormwater discharges from certain groups of outfalls can be represented by the discharge of a designated representative outfall within the group. Outfall SW001 (Drainage Area 1) Discharge Structure: 24 inch diameter CMP Location: West side of station intake canal Coordinates: 35 021'38" N 80 058'30" W Drainage Area: 4.4 acres Impervious Area: 100% Area Description The drainage area for SW001 includes 1.5 acres comprised of the Powerhouse roof, approximately 2.7 acres of the Main Switchyard, and approximately 0.2 acres of paved areas on the west side of the Powerhouse. The Main Switchyard is a large paved area containing numerous transformers and circuit breakers containing mineral oil. A black start diesel generator is located in the northern corner of the Main Switchyard, and occasional tanker truck refueling of diesel fuel occurs adjacent to the generator. All stormwater runoff from Drainage Area 1 is routed into the 10,000 gallon capacity No. 3 Oil Trap Tank located on the west end of the Powerhouse. The Oil Trap Tank discharges into the intake canal. Significant Materials /Activities Mineral Oil: Mineral oil is stored inside numerous oil- cooled transformers and circuit breakers in the SW001 drainage area portion of the Main Switchyard. The largest mineral oil containers in this area are the 6B and 7B transformers containing 10,990 gallons each. These two large transformers are located within concrete containment pits with drain valves that discharge into the No. 3 Oil Trap Tank. Stormwater runoff from remaining areas surrounding all other electrical equipment in this drainage area enters catch basins that discharge into the No. 3 Oil Trap Tank. Diesel Fuel: The black start diesel generator has the capacity to store up to 1,200 gallons of diesel fuel within a self- contained double - walled integral tank. Occasional tanker unloading operations are conducted adjacent to the generator to refuel the unit. Stormwater runoff from this tanker unloading area enters catch basins that discharge into the No. 3 Oil Trap Tank. Discharge Controls 10,000 gallon capacity No. 3 Oil Trap Tank. Outfall SW002 (Drainage Area 2) Discharge Structure: 21 inch diameter CMP Location: West side of station intake canal Coordinates: 35 021'38" N 80 058'30" W Drainage Area: 13.2 acres Impervious Area: 35% Area Description The drainage area for SW002 is comprised of station yard areas located south and west of the Powerhouse. Located within Drainage Area 2 are the remaining portions of the Main Switchyard, the entire 44 kV Switchyard, and the two control buildings for the combustion turbine units. The two switchyards are paved and cover approximately 2.6 acres. The now unused fuel oil unloading station encompasses 0.9 acres and is located along the southeastern drainage area boundary. This area is paved and was previously used by tanker trucks to unload fuel oil for refilling of the 4,250,000 gallon capacity Main Fuel Oil Storage Tank. All stormwater runoff from the unloading station discharges into the 30,000 gallon capacity No. 4 Oil Trap Tank located 150 feet northwest of the unloading station. This oil trap tank discharges into the No. 2 Oil Trap Tank. A service transformer associated with the fuel oil unloading station is located within a containment pit on the north end of the unloading station. Stormwater runoff from the area surrounding this transformer enters a ditch that discharges into the 30,000 gallon capacity No. 4 Oil Trap Tank. Drainage Area 2 also includes approximately 0.5 acres of paved parking areas, approximately 6 acres of grassed lawn and grassed embankment areas, approximately 2000 linear feet of paved access roadway, and approximately 6000 linear feet of rail lines. All stormwater runoff from Drainage Area 2 discharges into the 10,000 gallon capacity No. 2 Oil Trap Tank located on the west end of the Powerhouse. The No. 2 Oil Trap Tank discharges into the intake canal. Significant Materials /Activities Mineral Oil: Mineral oil is stored inside numerous oil- cooled transformers and circuit breakers in the SW002 drainage area portion of the Main Switchyard and in the 44kV Switchyard. All stormwater runoff from these switchyard areas enters catch basins that discharge into the No. 2 Oil Trap Tank. 482 gallons of mineral oil is stored in the fuel oil unloading area service transformer. Stormwater runoff from the area surrounding this transformer discharges into the 30,000 gallon capacity No. 4 oil trap tank that subsequently discharges into the No. 2 Oil Trap Tank. Discharge Controls 10,000 gallon capacity No. 2 Oil Trap Tank. Outfall SW003 (Drainage Area 3) Discharge Structure: 36 inch diameter CMP Location: West side of station intake canal Coordinates: 35 021'40" N 80 058'32" W Drainage Area: 15.4 acres Impervious Area: 5% Area Description The drainage area for SW003 is comprised of station yard areas southwest of Drainage Area 2. Located within Drainage Area 3 is the entire gravel - surfaced 230 kV Switchyard containing numerous transformers and circuit breakers with a total mineral oil storage capacity of 6,700 gallons. Stormwater runoff from the switchyard enters catch basins that discharge into a concrete ditch that subsequently directs the flow westerly to a 36 inch diameter CMP beneath the station entrance road. The inlet end of this CMP is fitted with a swing gate that can be closed in the event of a mineral oil release from any electrical equipment in the switchyard. This pipe discharges into a concrete ditch that runs north along the east side of the Main Fuel Oil Storage Tank containment dike. This ditch terminates into a 36 inch diameter CMP that eventually discharges into the station intake canal. Approximately 900 linear feet of paved access roadway passes through the drainage area and approximately 800 linear feet of rail lines cross the southeastern region of the drainage area. Drainage Area 3 also includes approximately 10 acres of grassed lawn areas and the vegetated external slope of the southern portion of the earthen containment dike surrounding the empty Main Fuel Oil Storage Tank. A small section of fuel oil piping from the tanker unloading area to the tank is present aboveground where the piping crosses the concrete ditch southeast of the tank containment dike. Fuel unloading activities have been terminated. Sianificant Materials /Activities Mineral Oil: Mineral oil is stored inside numerous oil- cooled transformers and circuit breakers in the 230kV Switchyard. Discharge Controls None. Outfall SW004 (Drainage Area 4) Discharge Structure: 15 inch diameter Reinforced Concrete Pipe Location: East side Horseshoe Bend Beach Road Coordinates: 35 021'22" N 80 058'32" W Drainage Area: 4.6 acres Impervious Area: 15% Area Description The drainage area for SW004 is comprised of a narrow strip of station property located along the southeastern boundary between Horseshoe Bend Beach Road and the access road leading to the tanker fuel oil unloading station. The area is primarily comprised of a grassed yard. Approximately 200 linear feet of the paved tanker fuel oil unloading station access road crosses through the area. Stormwater is discharged from SW004 into a ditch that subsequently flows off -site to the south approximately 1000 feet to Mountain Island Lake. Significant Materials /Activities None. Discharge Controls None. Outfall SW005 (Drainage Area 5) Discharge Structure: 24 inch diameter CMP Location: South side of Steam Plant Road Coordinates: 35 021'21" N 80 058'37" W Drainage Area: 3.5 acres Impervious Area: 8% Area Description The drainage area for SW005 is located along the northeast side of Steam Plant Road in the extreme southeastern area of the station property. The drainage area is primarily comprised of grassed yard with the western boundary of the area being formed by the centerline of the paved Steam Plant Road. Stormwater is discharged from SW005 into a ditch that subsequently flows off -site to the southwest. Significant Materials /Activities None. Discharge Controls None. Outfall SW006 (Drainage Area 6) Discharge Structure: 36 inch diameter CMP Location: West side of station intake canal Coordinates: 35 021'39" N 80 058'32" W Drainage Area: 5.2 acres Impervious Area: 35% Area Description The drainage area for SW006 is comprised of station yard areas west of the Powerhouse in the vicinity of the retired combustion turbine units and the empty Main Fuel Oil Storage Tank. Located within Drainage Area 6 are the retired four combustion turbine units and the instrumentation house and warehouse associated with these units. Drainage Area 6 also includes the 4,250,000 gallon Main Fuel Oil Storage Tank (empty) and the northeastern portion of the surrounding earthen containment dike for this tank. A large transformer associated with the retired combustion turbine units is also located in this area southeast of the units. Four lube oil storage tanks are located at the two active combustion turbine units. These tanks are empty but may have some residual drainage. A contaminated groundwater remediation /recovery system is in operation within Drainage Area 6. Groundwater is recovered from several monitoring wells within the area and is discharged into an oil /water separator. The separator discharges collected petroleum product into a 55 gallon drum, and discharges collected water into the station yard drainage sump. Drainage Area 6 includes approximately 3 acres of grassed lawn areas, the grassed external slope of the earthen containment dike, and approximately 500 linear feet of paved access roadway surrounding the retired combustion turbine units. The Main Fuel Oil Tank containment dike is drained of collected rainwater by a manually operated siphon system. The collected rainwater discharges into a concrete ditch at the eastern base of the dike embankment. All stormwater runoff from within Drainage Area 6, including drainage from the containment dike, enters catch basins or ditches that discharge into the 20,000 gallon capacity No. 1 Oil Trap Tank located between the retired combustion turbines units and the station intake canal. The No. 1 Oil Trap Tank discharges into the intake canal. Significant Materials /Activities Fuel Oil: Fuel oil was stored in the 4,250,000 gallon Main Fuel Oil Storage Tank located within an earthen containment dike. This tank is now empty. Mineral Oil: 9,237 gallons of mineral oil is present in the combustion turbine transformer. Lube Oil: Lube oil is stored in four 750 gallon capacity turbine lube oil tanks located at the turbine units. These tanks are largely empty but there may be some residuals that are drained periodically. Contaminated Groundwater: Petroleum contaminated groundwater is recovered from several monitoring wells within the area. Discharge Controls 20,000 gallon capacity No. 1 Oil Trap Tank. Outfall SW007 (Drainage Area 7) Discharge Structure: 24 inch diameter steel pipe Location: Mountain Island Lake Coordinates: 35 021'80" N 80 058'28" W Drainage Area: 0.9 acres Impervious Area: 0% Area Description The drainage area for SW007 is comprised of a small portion of a grassed embankment on the northern side of the coal storage pile and a small section of gravel - surfaced roadway and laydown yard located between the coal storage pile and Mountain Island Lake. Sianificant Materials /Activities Inert Materials: Various quantities of structural steel, cable, truck trailers, and other inert materials may be stored on the gravel laydown yard area at various times. Discharge Controls None. Outfall SW008 (Drainage Area 8) Discharge Structure: 36 inch diameter CMP Location: Mountain Island Lake Coordinates: 35 °21'51" N 80 058'16" W Drainage Area: 70 acres Impervious Area: 2% Area Description Drainage Area 8 is located in the central area of the station property and includes the closed dry ash stack occupying approximately 35 acres, and the cinder pit encompassing approximately 9 acres. Drainage Area 8 extends into undeveloped woodland areas on the south side of Horseshoe Bend Beach Road. Located within the drainage area is approximately 7 acres of woodlands, approximately 1,600 linear feet of ash sluice piping, approximately 6,150 linear feet of rail lines, approximately 2,425 linear feet of gravel - surfaced roadways, and approximately 3,500 linear feet of the paved Horseshoe Bend Beach Road. All coal deliveries and ash sluicing activities have been terminated. Two service transformers for the yard sump pumps are located within the drainage area at the north end of the coal storage pile. These transformers are surrounded by a containment dike with a chemical polymer oil containment barrier. Stormwater runoff from the ash stack and all areas south of the rail lines within Drainage Area 8 enters a stormwater collection basin located west of the ash stack. This basin discharges into the cinder pit through a pie beneath the rail lines. All stormwater runoff from within Drainage Area 8 eventually enters the cinder pit which functions as a large dry detention pond. The pit is fitted with a 3 feet high CMP riser pipe leading to the 36 inch diameter CMP discharge outlet pipe. Stormwater entering the cinder pit typically evaporates and /or infiltrates before reaching a level high enough to discharge into the riser pipe. Discharges from the 36 inch diameter CMP rarely occur. Significant Materials /Activities Mineral Oil: Mineral oil is present in the two yard sump pump service transformers located within a containment berm. Inert Materials: Various quantities of inert materials may be stored on the scrap yard. Discharge Controls Cinder pit dry detention pond. Outfall SW009 (Abandoned). Outfall SW010 (Drainage Area 10) Discharge Structure: 18 inch diameter CMP Location: North of Lark Maintenance Facility Coordinates: 35 021'38" N 80 °58'41" W Drainage Area: 0.6 acres Impervious Area: 50% Area Description The drainage area for SW010 is comprised of the southeastern portion of the Lark Maintenance Facility roof, portions of a paved driveway and storage area on the east side of the facility, and vegetated areas east of the driveway. Stormwater from Drainage Area 10 is discharged into a woodlands area north of the facility that subsequently flows overland approximately 800 feet to Mountain Island Lake. Significant Materials /Activities Inert Materials: Various quantities of inert materials may be stored on the paved storage area on the east side of the facility. Discharge Controls None. Outfall SW011 (Drainage Area 11) Discharge Structure: 18 inch diameter CMP Location: West of Lark Maintenance Facility Coordinates: 35 021'33" N 80 °58'45" W Drainage Area: 1.1 acres Impervious Area: 70% Area Description The drainage area for SW011 is comprised of the southwestern portion of the Lark Maintenance Facility roof, portions of a paved driveway and parking lot on the west side of the facility, and a small vegetated areas on the west side of the building. Stormwater from Drainage Area 11 is discharged into a woodlands area west of the facility that subsequently flows overland approximately 800 feet to Mountain Island Lake. Significant Materials /Activities None. Discharge Controls None. Outfall SW012 (Drainage Area 12) Discharge Structure: 8 inch diameter polyethylene pipe Location: North of Lark Maintenance Facility Coordinates: 35 021'37" N 80 058'42" W Drainage Area: 0.1 acres Impervious Area: 100% Area Description The drainage area for SW012 is comprised wholly of roof drainage from the northeastern portion of the Lark Maintenance Facility roof. Stormwater from Drainage Area 12 is discharged into a woodlands area south of the facility that subsequently flows overland approximately 800 feet to Mountain Island Lake. Significant Materials /Activities None. Discharge Controls None. Outfall SW013 (Abandoned) Outfall SW014 (Drainage Area 14) Discharge Structure: 12 inch diameter CMP Location: East side of station intake canal Coordinates: 35 021'42" N 80 058'30" W Drainage Area: 0.02 acres Impervious Area: 0% Area Description The drainage area for SW014 is comprised wholly of a grassed bermed area surrounding the station septic tank. Stormwater runoff from within this small bermed area enters a catch basin that discharges into the intake canal from the steep eastern side of the canal embankment. Access to the discharge end of this pipe is difficult due to thick vegetation and the steepness of the bank. Sianificant Materials /Activities None. Discharge Controls None. REMAINING DRAINAGE AREA DESCRIPTIONS The Riverbend Steam Station has additional non -point source stormwater runoff areas that discharge into Mountain Island Lake; and non - stormwater discharge drainage areas that discharge into the station yard sump that pumps to the ash settling basins. Non -point source stormwater runoff areas are described as follows: Non -Point Runoff - Immediately West of Station Intake Canal This area comprises approximately 1.5 acres and is located along the western side of the intake canal east of Drainage Area 6 and north of Drainage Area 2. The area contains a mobile office trailer and approximately 1 acre of asphalt pavement. Approximately 65% of this drainage area is impervious. Stormwater runoff flows overland down the riprap slope of the western intake canal embankment. Non -Point Runoff - Immediately East of Station Intake Canal This area comprises approximately 1 acre and is located along the eastern side of the intake canal from the Powerhouse to the septic tank system. The area contains the 27,000 gallon capacity Light -off Fuel Oil Storage Tank and the 25,000 gallon capacity Used PCB Mineral Oil Storage Tank. The Used PCB Mineral Oil Storage Tank is now empty. Both of these tanks area are located within covered concrete containment basins with closed and locked drain valves. Aboveground fuel oil piping from the empty Main Fuel Oil Storage Tank to the Light -off Fuel Oil Storage Tank passes through this area. The area also contains a gravel - surfaced roadway and a small storage shed. The septic tanks area located within an earthen - bermed area that drains through Outfall SW014. Approximately 15% of this drainage area is impervious. Stormwater runoff flows overland down the vegetated slope of the eastern intake canal embankment. Non -Point Runoff - North End of Lark Maintenance Facility This area covers approximately 1.5 acres and is comprised of most of the northern portions of the facility roof and asphalt -paved roadways and parking areas surrounding the northern half of the building. Inert materials are stored outside on pavement on the east side of the building. Approximately 75% of this drainage area is impervious. Stormwater runoff flows across asphalt pavement into the wooded area to the north. Non -Point Runoff — Areas Surrounding the Ash Settling Basins This large area extends from the intake canal across the area north of the cinder pit, and continues around the perimeter of the two ash settling basins. The area is primarily woodlands and includes the grassed exterior slopes of the ash settling basin embankments and dirt or gravel - surfaced access roads around the ash basins. A small gravel - surfaced laydown yard containing inert materials is located within this area north of the coal storage pile. There are no significant materials or activities located within this area, and none of the drainage area is impervious. The Riverbend Steam Station has one yard sump that receives wastewater discharges from various internal and external areas of the station and subsequently pumps this wastewater to the ash basins. The sump pumps to the ash basins through a 30 inch diameter ductile iron pipe. Rarely occurring emergency sump overflows will discharge through a 24 inch diameter CMP to Mountain Island Lake. This outfall is permitted as NPDES Outfall 002A — Yard Sump Overflow. This sump accepts wastewater discharges from the boiler room sump and the turbine room sump inside the Powerhouse. These discharges include effluent from the sanitary system, effluent from a groundwater remediation system, minimal service water flow, effluent from floor drains, and industrial wastewater from various powerhouse equipment. This yard sump also accepts stormwater runoff from several areas around the Powerhouse. This runoff generally flows into catch basins that discharge via subsurface piping into the sump. Located within the yard sump stormwater drainage area are the following: • The approximately 13 acre coal storage pile; • Approximately 1.3 acres of Powerhouse roof area; • All coal handling buildings, maintenance sheds, conveyors and equipment; • Warehouses and storage shed roofs; • Asphalt and gravel - surfaced roadways and parking areas; • Rail lines. Included within this drainage area are numerous transformers containing mineral oil, numerous 55 gallons drums containing new and used oils, a 750 gallon capacity sulfuric acid tank, and a hazardous waste accumulation area. Refueling and tanker truck loading and unloading operations are conducted within the area for the coal handling bulldozers and tractors at the Light -off Fuel Oil Storage Tank. Various oils, chemicals, paints and solvents are unloaded from trucks within the drainage area. OJT Q -OQO� l v 1i i I � NPDES 002A / • SW -008 / j CINDER STORAGE r \I —SSW -007 it SW-014 SW -010 SW-012 �/ / , �\ SW -002 / SW-00/ 3 SW_ � SW-011 • n' /OP/ 1 RIVERBEND / 1 / LARK STEAM STATION <` MAINTENANCE �\ FACILITY / �g�; ®"° 1 O NPDES 001 'A li Jrl ASH BASIN SECONDARY CELL a L \NPDES 002 �r PRIMARY CELL 1- Stormwater Outfall Location Coordinates Outfall Pipe Description Location Description Latitude Longitude SW -001 35.361 - 80.975 24" CMP West side of Intake Canal SW -002 35.361 - 80.975 21" CMP West side of Intake Canal SW -003 35.361 - 80.975 36" CMP West side of Intake Canal SW -004 35.357 - 80.975 15" RCP East side of Horseshoe Bend Beach Road SW -005 35.356 - 80.976 24" CMP South side of Steam Plant Road SW -006 35.361 - 80.976 36" CMP West side of Intake Canal SW -007 35.363 - 80.973 24" Steel Mountain Island Lake SW -008 35.364 - 80.971 36" CMP Mountain Island Lake SW -010 35.360 - 80.978 18" CMP Wooded area north of Lark Maintenance Facility SW -011 35.360 - 80.979 18" CMP Wooded area west of Lark Maintenance Facility SW -012 35.360 - 80.978 8" Polyethylene Wooded area north of Lark Maintenance Facility SW -014 35.362 - 80.975 12" CMP East side of Intake Canal V / SW-004 \ / /SW -005 \ NOTES: 1 SCALE (FEET) 1. PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE. 2. TOPOGRAPHY DATA PROVIDED BY DUKE ENERGY. 300' 0 300' 600' 3. STORMWATER 0UTFALL LOCATIONS WERE OBTAINED BY H D R USING A TRIMBLE HANDHELD GPS UNIT ON APRIL 29, 2014. P = 600' 4. NPDES OUTFALL LOCATIONS WERE PROVIDED BY DUKE ENERGY AND ARE APPROXIMATE. FM HDR Engineering, Inc. of th. Carolinas LEGEND: DUKE ENERGY PROPERTY BOUNDARY MOUNTAIN ISLAND LAKE BOUNDARY SW -004 • STORMWATER OUTFALL SAMPLE LOCATION NPDES 002 A NPDES OUTFALL LOCATION STORMWATER OUTFALL LOCATION MAP RIVERBEND STEAM STATION ASH BASIN DUKE ENERGY CAROLINAS, LLC GASTON COUNTY, NC I IN DATE MAY 14, 2014 FIGURE 1 Duke ir-Energy. May 9, 2011 Mr. Bradley Bennett Division of Water Quality Stormwater Permitting Unit North Carolina Department of Environment and Natural Resources 1617 Mail Service Center Raleigh, NC 27699 -1617 Subject: NPDES Stormwater Permit Application Riverbend Steam Station Dear Mr. Bennett: CORPORATE EHS SERVICES Duke Energy 526 South Church St Charlotte, NC 28202 Mailing Address: EC13K / PO Box 1006 Charlotte, NC 28201 -1006 Duke Energy requests a stormwater discharge permit for the Riverbend Steam Station located in Gaston County, North Carolina. Enclosed is a check from Duke Energy in the amount of $860.00 for the subject stormwater permitting fee; and three sets of the following documents related to this permit request: a. EPA Form 1; b. EPA Form 2F; C. EPA Form 2F Supplemental Information; d. Available stormwater analytical data; e. DWQ ROS Request Form; f. ROS Form Supplemental Information; g. Site Location Map; h. Site Stormwater Plan Drawing Numerous stormwater outfalls are located at the Riverbend Steam Station. The accompanying stormwater analytical data was obtained from samples collected at outfalls SW001, SWO02 and SWO03 during the period June through September, 2008. Please contact me at Mark.McGary@duke- energy.com or at 704 - 634 -7098 if you have any questions or need any additional information. Sincerely, Mark McGary, P.E. Environmental, Health & Safety attachments www duke - energy corn Cc w /att: Steve Jones Cc w/o att: Mr. Robert Krebbs, NCDENR MRO Dayna Herrick John Velte File Number: 8 -6 Record Number: 248464 Certified Mail: 7009 1410 0000 0602 8497 Check Date: 13.Apr.2011 Vendor Number: 0000071960 Name: NCDENR - NORTH CAROLINA DEPARTMENT OF Check Number. 1000 56696 Invoice Number Invoice Date Voucher ID Gross Amount Discounts Taken Late Charge Paid Amount 041 1 1 1 86000NC II.Apr.2011 10439421 860.00 0.00 0.00 860.00 Total Total Total Total Check Number: Date Gross Amount Discounts Late Charges Paid Amount 1000056696 13.Apr.2011 $860.00 $0.00 $0.00 $860.00 %OFA 1:stn.. + ... Duke Duke FrteW Rusiomi Services 1q{1 56696 ter o 400 South Tryon Street JI'i4iQRCAIY CHASE BANK. N.A. �� . C'hatInttc NC 28285 Syracum NY 50-9371213 Caiputalu AC�O[YIIIS Payat+lc Wl C04 Sd258 4Q65uulH'8ynn Strecl Gbadolts, HC 28185 hate 4113111 Pity Eight hun tire d sixty andxx/ 100 D0liars To The Order Of NCDENR - NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES STORMWATER PERMITTING., UNIT 1617 MAIL SERVICE CENTER Raleieh. NC 27699 -1617 ;littlaurirr.d fii�su�lsn c S**86 {1.[111 FORM U.S. ENVIRONMENTAL PROTECTION AGENCY I. EPA I.D. NUMBER EPA GENERAL INFORMATION S T/A NC0004961 p D Consolidated Permits Program GENERAL (Read the "General Instructions" before starting.) 1_ 2 13 14 15 LABEL ITEMS GENERAL INSTRUCTIONS If a preprinted label has been provided, affix it in the I. EPA I.D. NUMBER designated space. Review the information carefully; if any of it is incorrect, cross through it and enter the correct data in the appropriate fill -in area below. II. FACILITY NAME Also, if any of the preprinted data is absent (the area to the left of the label space lists the III. FACILITY MAILING PLEASE PLACE LABEL IN THIS SPACE information that should appear), please provide it in the proper fill -in area(s) below. If the label is ADDRESS complete and correct, you need not complete Items i—..- I, III, V, and VI(except VI -B which must be IV. FACILITY LOCATION completed regardless). Complete all items if no label has been proved. Refer to the instructions for detailed item descriptions and for the legal authorization under which this data is collected. II. POLLUTANT CHARACTERISTICS INSTRUCTIONS: Complete A through J to determine whether you need to submit any permit application forms to the EPA, If you answer "yes" to any questions, you must submit this form and the supplemental from listed in the parenthesis following the question. Mark "X' in the box in the third column if the supplemental form is attached. If you answer "no' to each question, you need not submit any of these forms. You may answer "no' if your activity is excluded from permit requirements; see Section C of the instructions. See also, Section D of the instructions for definitions of bold -faced terms. MARK "F MARK "X SPECIFIC QUESTIONS SPECIFIC QUESTIONS FORM FORM YES NO ATTACHED YES NO ATTACHED A. Is this facility a publicly owned treatment B. Does or will this facility (either existing or works which results in a discharge to waters of ❑ ® ❑ proposed) include a concentrated animal ❑ ® 1:1 the U.S.? (FORM 2A) feeding operation or aquatic animal production facility which results in a discharge to waters of the U.S.? (FORM 213) 16 17 18 19 20 21 C. Is this facility which currently results in ® ❑ ® D. Is this proposal facility (other than those E] ® El to waters of the U.S. other than described in A or B above) which will result in a those described in A or B above? (FORM 2C) 22 23 24 discharge to waters of the U.S.? (FORM 2D) 25 26. 27 j E. Does or will this facility treat, store, or dispose of F. Do you or will you inject at this facility industrial or hazardous wastes? (FORM 3) ❑ ® ❑ municipal effluent below the lowermost stratum ❑ ® ❑ containing, within one quarter mile of the well bore, 1 underground sources of drinking water? (FORM 4) 28 29 30 _ 31 32 33 G. Do you or will you inject at this facility any produced H. Do you or will you Inject at this facility fluids for water other fluids which are brought to the surface in connection with conventional oil or natural gas ❑ ® ❑ special processes such as mining of sulfer by the Frasch process, solution mining of minerals, in ❑ ® ❑ production, inject fluids used for enhanced recovery situ combustion of fossil fuel, or recovery of of oil or natural gas, or inject fluids for storage of geothermal energy? (FORM 4) liquid hydrocarbons? (FORM 4) 34 35 36 37 38 39 f. Is this facility a proposed stationary source J. Is this facility a proposed stationary source which is one of the 28 industrial categories listed which is NOT one of the 28 industrial categories E] ® 1:1 El El in the instructions and which will potentially emit listed in the instructions and which will potentially 100 tons per year of any air pollutant regulated emit 250 tons per year of any air pollutant under the Clean Air Act and may affect or be regulated under the Clean Air Act and may affect located in an attainment area? FORM 5) 40 41 a2 or be located in an attainment are? FORM 5 43 44 45 III. NAME OF FACILITY C SKIP Riverbend Steam Station 1 15 1 16 -29 I 30 69 IV. FACILITY CONTACT A. NAME &TITLE last first &title B. PHONE area code & no. _ 2 McGary, Mark / Sr. Engineer 980 373 7898 46 48 49 51 52. 55 1$ 16 -- _ -- - - - _ -- _ -- - - 45 1 V. FACILITY MAILING ADDRESS A. STREET OR P.O. BOX D. ZIP CODE 28201 P.O. Box 1006, Mail Code EC13K 3 is 1 16 45 B. CITY OR TOWN C. STATE C Charlotte NC 4 15 16 40 1 1 41 42 47 51 V1. FACILITY LOCATION A. STREET, ROUTE NO. OR OTHER SPECIFIC IDENTIFIER 175 Steam Plant Road 5 .� I 16 45 B. COUNTY NAME Gaston a8 70 C. CITY OR TOWN D. STATE E. ZIP F. COUNTY CODE CODE Mount Holly NC 28120 6 15 18 40 41 42 1 47 51 52 54 EPA FORM 3510 -1 (8 -90) CONTINUED ON REVERSE CONTINUED FROM THE FRONT VII. SIC CODES 4:qi it, in order of riart"t A. FIRST B. SECOND _ c 4911 (specify) 7 (specify) Electric Services s ,s n 1s 1s C. THIRD D. FOURTH c (specify) 7 (specify) H 7 7 1 1s 19 15 1 16 to. Vill. OPERATOR INFORMATION A. NAME B. Is the name listed in Item c Duke Energy Carolinas, LLC (Attention: Mark McGary) VIII -A also the owner? 8 ® YES ❑ NO P 1 6 1s 50 C. STATUS OF OPERATOR Enter theapp L o riate letter into the answer box; if "Other, "s D. PHONE area code & no. F = FEDERAL M = PUBLIC (other than federal or state) P neci (specify) 980 373 7898 S = STATE O = OTHER (specify) Electric Utility 56 i6 18 19 21 P = PRIVATE 22 25 E. STREET OR PO BOX P.O. Box 1006, Mail Code EC13K 26 55 F. CiTY OR TOWN G. STATE H. ZIP CODE IX. INDIAN LAND c Charlotte NC 28201 Is the Facility located on Indian lands? B I [:] YES ® NO 42 42 47 51 15 16 40 X. EXISTING ENVIRONMENTAL PERMITS A. NPDES (Discharges to Surface Water D. PSD Air Emissions from Pro osed Sources c P 5 16 17 16 30 c ° NC0004961 N 15 1 16 17 18 30 B. UIC (Underground Injection of Fluids E. OTHER (specify) (Specify) c r ' $ 03788T32 Air permit s u s 15 16 17 16 30 15 1 16 1 17 1 18 30 C. RCRA Hazardous Wastes E. OTHER (speci )-T (Specify) W00000452 Distribution of Residual 9 ' NCD024717423 s T e Solids ,5 16 17 16 30 15 16 17 1A 30 XI. MAP Attach to this application a topographic map of the area extending to at least one mile beyond property boundaries. The map must j show the outline of the facility, the location of each of its existing and proposed intake and discharge structures, each of its hazardous waste treatment, storage, or disposal facilities, and each well where it injects fluids underground. Include all springs, rivers and other surface water bodies in the map area. See instructions for precise requirements. XII. NATURE OF BUSINESS (provide a brief description) Coal -fired electric generation ){III. CERTIFICATION (see instrucfions) u 1 certify under penalty of law that I have personally examined and am familiar with the information submitted in this application and all attachments and that, based on my inquiry of those persons immediately responsible for obtaining the information contained in the application, 1 believe that the information is true, accurate and complete. 1 am aware that there are significant penalties for submitting false information, including the possibft of fine and im rlsonment. A. NAME & OFFICIAL TITLE (type or print) B. SIGN TUBE J C. DATE SIGNED Terry L. Taylor - General Manager II S of COMMENTS FOR OFFICIAL USE ONLY c C 15 16 55 EPA FORM 3510 -1 (8 -90) EPA ID Number (copy from Item 1 of Form 1) Form Approved OMB No. 2040 -0086 Please Drint or Woe in the unshaded areas only NC0004961 I Aoomval expires 5 -31 -92 FORM 2F NPDr=S U.S. Environmental Protection Agency n Washington, DC 20460 �.. EPA Application for Permit to Discharge Storm Water Discharges Associated with Industrial Activity Paperwork Reduction Act Notice Public reporting burden for this application is estimated to average 28.6 hours per application, including time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding the burden estimate, any other aspect of this collection of information, or suggestions for improving this form, including suggestions which may increase or reduce this burden to: Chief, Information Policy Branch, PM -223, U S Environmental Protection Agency, 1200 Pennsylvania Avenue, NW, Washington, DC 20460, or Director, Office of Information and Regulatory Affairs, Office of Management and Budget, Washington, DC 20503 I.Outfall Location For each outfall. list the latitude and longitude of its location to the nearest 15 seconds and the name of the receivinq water A. Ouffall Number psp B. Latitude C. Longitude 0. Receiving Water (panne) See attached See attached supplemental information Il. linprovenients A. Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading or operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders, and grant or loan conditions. 1. Identificalian of Conditions, Agreements, Etc 2 Afieoed Outfalls 3 Brief Description of Project 4 Final Compliance Orate number source or discharge a, req b. prof KJA B: You may attach additional sheets describing any additional water pollution (or other environmental projects which may affect your discharges) you now have under way or which you plan. Indicate whether each program is now under way or planned, and indicate your actual or planned schedules for construction. III, Site Drainage Map Attach a site map showing topography (or indicating the outline of drainage areas served by the outfalls(s) covered in the application if a topographic map is unavailable) depicting the facility including: each of its intake and discharge structures; the drainage area of each storm water outfall; paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for outdoor storage of disposal of significant materials, each existing structural control measure to reduce pollutants in storm water runoff, materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied; each of its hazardous waste treatment, storage or disposal units (including each area not required to have a RCRA permit which is used for accumulating hazardous waste under 40 CFR 262.34); each well where fluids from the facility are injected underground; springs, and other surface water bodies which received storm water discharges from the facility. EPA Form 3510 -2F (1 -92) Page 1 of 3 Continue on Page 2 r.,..n..,,o.l from fho P—f IV. Narrative Description of Pollutant Sources A For each outfall, provide an estimate of the area (include units) of imperious surfaces (including paved areas and building roofs) drained to the outfall, and an estimate of the total surface area drained by the outfall. Outfall Area of Impervious Surface Total Area Drained Outfall Area of Impervious Surface Total Area Drained Number (provide units) (provide units) Number (provide units) (provide units) See attached supplemental information B Provide a narrative description of significant materials that are currently or in the past three years have been treated, stored or disposed in a manner to allow exposure to storm water; method of treatment, storage, or disposal; past and present materials management practices employed to minimize contact by these materials with storm water runoff; materials loading and access areas, and the location, manner, and frequency in which pesticides, herbicides, soil conditioners, and fertilizers are applied. 13ee attached supplemental information C For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in storm water runoff; and a description of the treatment the storm water receives, including the schedule and type of maintenance for control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge. Outfall List Codes from Number Treatment Table 2F -1 :3ee attached supplemental information V. Nonstormwater Discharges A. I certify under penalty of law hat the outfall(s) covered by this application have been tested or evaluated for the presence of nonstormwater discharges, and that all nonstormwater discharged from these outfall(s) are identified in either an accompanying Form 2C or From 2E application for the outfall Name and Official Title (type or print) Mignature Date Signed Terry L. Taylor - General Manager II Jo B. Provide a description of the method used, the date of any testing, and the onsite drainage points that were directly observed during a test. Visual inspection was performed on December 9, 2010. Stormwater outfalls were inspected following a period of dry weather of at least 72 hours duration to determine if any process water was discharging. VI. Significant Leaks or Spills Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three years, including the approximate date and location of the spill or leak, and the type and amount of material released. Within the past three years there have been no significant spills or leaks of hazardous substances in excess of reportable quantities set forth by Section 311 of the Clean Water Act or Section 102 of CERCLA. EPA Form 3510 -21F (1 -92) Page 2 of 3 Continue on Page 3 Continued from Page 2 INC000 96iD Number (copy from Item 1 ofForm 1) V11. Discharge Information A, B, C. & D: See instructions before proceeding. Complete one set of tables for each outfall. Annotate the outfall number in the space provided. Table VII -A, VII -B, VII -C are included on separate sheets numbers VII -1 and VII -2. E. Potential discharges not covered by analysis - is any toxic pollutant listed in table 2F -2, 2F -3, or 2F -4, a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct? ❑ Yes (list all such pollutants below) Q No (go to Section IX) Vlll. Biological. Toxicity Testing Data Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? ❑ Yes (list all such pollutants below) ❑✓ No (go to Section W roxicity testing has been conducted in association with NPDES wastewater discharge 002. No toxicity testing has been performed for stormwater outfalls. IX. Contract Analysis Information Were any of the analyses reported in Item VII performed by a contract laboratory or consulting firm? Q/ Yes (list the name, address, and telephone number of, and pollutants ❑ No (go to Section ?f) analyzed by, each such laboratory or firm below) A. Name B. Address C Area Code & Phone No. D. Pollutants Analyzed Pace Analytical services, Inc. 9800 Kincey Ave, Suite 100 704- 875 -9092 Oil and Grease Huntersville, NC 28078 Pace Analytical Services, Inc. 2225 Riverside Drive 828- 254 -7176 Wet chemistry and metals Asheville, NC 28804 X. Certification 1 certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel property gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations A. Name & Official Title (Type Or Print) B Area Code and Phone No Terry L. Taylor - General Manager II (704) 263 -3204 C. Sgnaturn D Date Signed % �I. U EPA Form 35/6-2F (1 -92) / Page 3 of 3 I EPA ID Number (copy from Item 1 of Form 1) Form Approved OMB No. 2040 -0086 MV, 0004963 I Approval expires 5 -31 -92 VII. Discharge information (Continued from page 3 of Form 2F) Part A — You must provide the results of at least one analysis for av9ry pollutant in this table Complete one table for each outfall, See instructions for additional details Pollutant and CAS Number (ifavaitable) Mcammum Values i'mcluds Urals) Average Values (include units) Number of Storm Events Sampled Sowees ofPolk4anls Grab Sample Taken [luring Firsl 20 Minutes Flow- Weighted Composite Grab Sample Taken During First 20 Minutes Flour- Weighted Composite Oil and Grease WA Outfalls SW001, SWO02 and SWO03 Biological oxygern Demand BODS) (see other attached Forms 2F China Oxygen Demand (COD) for analytical results summary) Total Suspended Solids (TSS) row Nilmgon Toial phosphorus PH Minimunn Maximum MINmtlm Maximum Part B — List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES permit for its process wastewater (if the facility is operating under an existing NPDES permit) Complete one table for each outfall. See the instructions for additional details and requirements Pollutant and CAS Number (+favailawa) Maximum Values (Mcludeunituj Average Values (includeamis) Number of Storm Events Sampled Sources of Pollutants Grab Sample Taken During First 2°o Minutes Flaw•Weighted Composite Grab Sample Taken During First 20 Minutes Flow-Weighted Composite Outfalls SW001, SWO02 and SWO03 (see other attached Forms 2F for analytical results summary) EPA Form 3510 -2F (1 -92) Page VII -1 Continue on Reverse Continued from the Front Part C - List each pollutant shown in Table 2F -2, 2F -3, and 2F -4 that you know or have reason to believe is present. See the instructions for additional details and requirements Complete one table for each outfall Pollutant and CAS Number (if available) Maximum Values (include units) Average Values (include units) _ Number of Storm Events Sampled Sources of Pollutants Grab Sample Taken During First 20 Minutes Flow- Weighted Composite Grab Sample Taken During First 20 Minutes Flow- Weighted Composite outfalls SW001, SWO02 and SWO03 (see other attached Forms 2F for analytical results summary) Part D — Provide data for the storm event(s) which resulted in the maximum values for the flow weighted composite sample 1. Date of Storm Event 2. Duration of Storm Event (in minutes) 3- Total rainfall during storm event (in inches) 4. Number of hours between beginning of storm measured and end of previous measurable rain event 5. Maximum flow rate during rain event (gallons/minute or specify units) 6• Total flow from rain event (gallons or specify units) see other attached Forms 2F for analytical results for SW001, SWO02 and SWO03 7. Provide a description of the method of flow measurement or estimate Flow data derived from a theoretical flow calculation using local meteorological data and contributing watershed area of the outfalls. EPA Form 3510 -2F (1 -92) Page VII -2 RIVERBEND STEAM STATION Stormwater Discharge Permit Application Form 2F Supplemental Information GENERAL SITE INFORMATION Riverbend Steam Station is a fossil - fueled, electric generation plant located in Gaston County approximately six miles northeast of Mount Holly, North Carolina. The station property encompasses 572 acres adjacent to and on the western side of Mountain Island Lake which is formed by the Catawba River. The station is accessed from Steam Plant Road off of Horseshoe Bend Beach Road. The station has four active coal -fired generation units with a total generating capacity of 227 megawatts; three active oil or gas -fired combustion turbine units rated at 30 megawatts each, and one out -of- service combustion turbine unit. The primary station generation yard area encompasses approximately 20 acres. The facility includes a Main Switchyard, a 44 kV Switchyard, and a 230 kV Switchyard occupying a total of approximately 8 acres. Also associated with the station is a coal storage pile covering approximately 13 acres, a primary ash setting basin occupying approximately 41 acres, a secondary ash settling basin occupying approximately 28 acres, and a closed dry ash stack occupying approximately 35 acres. Prior to construction of the ash settling basins, waste ash was disposed of in a cinder pit that remains on -site and encompasses approximately 9 acres. Ash is sluiced to the primary ash settling basin. The ash stack was used as a repository for ash cleaned out of the ash settling basins. The ash stack is no longer used and has been stabilized with a vegetated soil cap. The Riverbend Steam Station also includes a approximately one acre -size scrap yard, several construction spoil and laydown areas, a wastewater treatment facility, a coal unloading and handling operation, a warehouse, a fuel oil storage tank, paved parking areas, approximately two miles of rail lines, and approximately 1 mile of paved access roadways. The Lark Maintenance Garage is considered part of the Riverbend Steam Station as well, and is located along the facility western property boundary. In developed areas, runoff generally flows overland to ditches and catch basins which are connected to a buried network of corrugated metal pipes (CMP). In most areas west of the Powerhouse, this collected runoff discharges into one of three oil trap tanks prior to discharging to surface waters. In most areas east of the Powerhouse, this collected runoff discharges into the station yard sump that subsequently pumps to the ash settling basins. The Riverbend Steam Station maintains an up -to -date Spill Prevention Control and Countermeasure (SPCC) Plan in place in accordance with the USEPA Oil Pollution Prevention Regulation 40 CFR Part 112. NPDES PERMITTED DISCHARGES SUMMARY Riverbend Steam Station has three NPDES process water outfalls. The NPDES discharges are summarized as follows: NPDES Outfall 001 — Once - Through Cooling Water This discharge is a once - through non - contact cooling water system which condenses steam from the plant condensers. This discharge occurs at the station discharge canal. NPDES Outfall 002 - Ash Settling Basins This is the outflow from the ash settling basins. The ash settling basins are the repositories for waste ash sluiced from the plant. These basins also accept wastewater discharges from the boiler room sump, the turbine room sump, and the yard drainage sump. These discharges include stormwater runoff from the coal storage pile, effluent from the sanitary system, once - through cooling water from the induced draft fan motors and the preheater bearings, effluent from a groundwater remediation system, effluent from a vehicle wash -down station, and industrial wastewater from various powerhouse equipment. NPDES Outfall 002A — Yard Sump Overflow Should the pumps in the Yard Sump lose power, experience a mechanical failure, or become inundated during a large storm event, the sump would overflow through a pipe into Mountain Island Lake (the Catawba River). Overflow from this sump is not a normal occurrence. STORMWATER OUTFALLS AND DRAINAGE AREA DESCRIPTIONS The Riverbend Steam Station has twelve identified active stormwater outfalls that discharge to surface waters. The outfall locations and contributing drainage area delineations are shown on the accompanying site plan. All identified stormwater outfalls discharge into Mountain Island Lake formed by the Catawba River. Five outfalls discharge into the station intake canal upstream of the plant intake structure. Two outfalls discharge into Mountain Island Lake north of the coal storage pile. The remaining five outfalls discharge onto the ground and then flow overland eventually reaching Mountain Island Lake. There are two abandoned outfalls at the station. A description of the contributing drainage area for each outfall is provided below. Included with the description is the approximate location coordinates of the outfalls, the amount of impervious surface area within the drainage areas, a description of any significant materials and activities located within the drainage areas, the type of discharge conveyances, and a description of any discharge control measures. In addition to any significant materials particular to each drainage basin, herbicides are applied to selected areas at the Riverbend Steam Station to eliminate undesirable vegetation. Herbicides are generally used along railways, ash pipelines, and the perimeter fence. Herbicides are also applied, as needed, in the gravel parking lots, switchyard, and laydown areas. Herbicides are sprayed around the fuel oil bulk storage tanks, yard sumps, transformers, trailers, and the intake structure. All herbicides used at Riverbend Steam Station are approved by the company and considered safe to the environment when used according to directions. Records are retained at the facility documenting the areas treated, and the type and amount of herbicides used. Certain stormwater outfall drainage areas share similarities regarding the presence of significant materials and /or activities. Based on these similarities, stormwater discharges from certain groups of outfalls can be represented by the discharge of a designated representative outfall within the group. Ouffall SW001 (Drainage Area 1) Discharge Structure: 24 inch diameter CMP Location: West side of station intake canal Coordinates: 35 021'38" N 80 058'30" W Drainage Area: 4.4 acres Impervious Area: 100% Area Description The drainage area for SWO01 includes 1.5 acres comprised of the Powerhouse roof, approximately 2.7 acres of the Main Switchyard, and approximately 0.2 acres of paved areas on the west side of the Powerhouse. The Main Switchyard is a large paved area containing numerous transformers and circuit breakers containing mineral oil. A black start diesel generator is located in the northern corner of the Main Switchyard, and occasional tanker truck refueling of diesel fuel occurs adjacent to the generator. All stormwater runoff from Drainage Area 1 is routed into the 10,000 gallon capacity No. 3 Oil Trap Tank located on the west end of the Powerhouse. The Oil Trap Tank discharges into the intake canal. Significant Materials /Activities Mineral Oil: Mineral oil is stored inside numerous oil- cooled transformers and circuit breakers in the SWO01 drainage area portion of the Main Switchyard. The largest mineral oil containers in this area are the 6B and 7B transformers containing 10,990 gallons each. These two large transformers are located within concrete containment pits with drain valves that discharge into the No. 3 Oil Trap Tank. Stormwater runoff from remaining areas surrounding all other electrical equipment in this drainage area enters catch basins that discharge into the No. 3 Oil Trap Tank. Diesel Fuel: The black start diesel generator has the capacity to store up to 1,200 gallons of diesel fuel within a self- contained double - walled integral tank. Occasional tanker unloading operations are conducted adjacent to the generator to refuel the unit. Stormwater runoff from this tanker unloading area enters catch basins that discharge into the No. 3 Oil Trap Tank. Discharge Controls 10,000 gallon capacity No. 3 Oil Trap Tank. Outfall SWO02 (Drainage Area 2) Discharge Structure: 21 inch diameter CMP Location: West side of station intake canal Coordinates: 35 021'38" N 80 058'30" W Drainage Area: 13.2 acres Impervious Area: 35% Area Description The drainage area for SWO02 is comprised of station yard areas located south and west of the Powerhouse. Located within Drainage Area 2 are the remaining portions of the Main Switchyard, the entire 44 kV Switchyard, two control buildings for the combustion turbine units, and the fuel oil unloading station for the Main Fuel Oil Storage Tank. The two switchyards are paved and cover approximately 2.6 acres. The fuel oil unloading station encompasses 0.9 acres and is located along the southeastern drainage area boundary. This area is paved and used by tanker trucks to unload fuel oil for refilling of the 4,250,000 gallon capacity Main Fuel Oil Storage Tank. The unloading station has ten unloading bays, however only two of the bays are operational. The unloaded fuel oil is transferred to the tank through underground piping fitted with a backflow preventer. All stormwater runoff from the unloading station discharges into the 30,000 gallon capacity No. 4 Oil Trap Tank located 150 feet northwest of the unloading station. This oil trap tank discharges into the No. 2 Oil Trap Tank. A service transformer associated with the fuel oil unloading station is located within a containment pit on the north end of the unloading station. Stormwater runoff from the area surrounding this transformer enters a ditch that discharges into the 30,000 gallon capacity No. 4 Oil Trap Tank. Drainage Area 2 also includes approximately 0.5 acres of paved parking areas, approximately 6 acres of grassed lawn and grassed embankment areas, approximately 2000 linear feet of paved access roadway, and approximately 6000 linear feet of rail lines used for coal delivery to the station. All stormwater runoff from Drainage Area 2 discharges into the 10,000 gallon capacity No. 2 Oil Trap Tank located on the west end of the Powerhouse. The No. 2 Oil Trap Tank discharges into the intake canal. Significant Materials /Activities Mineral Oil: Mineral oil is stored inside numerous oil- cooled transformers and circuit breakers in the SW002 drainage area portion of the Main Switchyard and in the 44kV Switchyard. All stormwater runoff from these switchyard areas enters catch basins that discharge into the No. 2 Oil Trap Tank. 482 gallons of mineral oil is stored in the fuel oil unloading area service transformer. Stormwater runoff from the area surrounding this transformer discharges into the 30,000 gallon capacity oil trap tank that subsequently discharges into the No. 2 Oil Trap Tank. Fuel Oil: Tanker trucks with individual capacities of 8,000 gallons each unload fuel oil at the tanker unloading station. Stormwater runoff from this area discharges into the 30,000 gallon capacity oil trap tank that subsequently discharges into the No. 2 Oil Trap Tank. Coal: Train cars carrying coal use the rail lines that pass through the eastern portion of Drainage Area 2. All stormwater runoff from these rail lines eventually discharge into the No. 2 Oil Trap Tank. Discharge Controls 10,000 gallon capacity No. 2 Oil Trap Tank. Outfall SW003 (Drainage Area 3) Discharge Structure: 36 inch diameter CMP Location: West side of station intake canal Coordinates: 35 021'40" N 80 058'32" W Drainage Area: 15.4 acres Impervious Area: 5% Area Description The drainage area for SW003 is comprised of station yard areas southwest of Drainage Area 2. Located within Drainage Area 3 is the entire gravel- surfaced 230 kV Switchyard containing numerous transformers and circuit breakers with a total mineral oil storage capacity of 6,700 gallons. Stormwater runoff from the switchyard enters catch basins that discharge into a concrete ditch that subsequently directs the flow westerly to a 36 inch diameter CMP beneath the station entrance road. The inlet end of this CMP is fitted with a swing gate that can be closed in the event of a mineral oil release from any electrical equipment in the switchyard. This pipe discharges into a concrete ditch that runs north along the east side of the Main Fuel Oil Storage Tank containment dike. This ditch terminates into a 36 inch diameter CMP that eventually discharges into the station intake canal. Approximately 900 linear feet of paved access roadway passes through the drainage area and approximately 800 linear feet of rail lines cross the southeastern region of the drainage area. Drainage Area 3 also includes approximately 10 acres of grassed lawn areas and the vegetated external slope of the southern portion of the earthen containment dike surrounding the Main Fuel Oil Storage Tank. A small section of fuel oil piping from the tanker unloading area to the tank is present aboveground where the piping crosses the concrete ditch southeast of the tank containment dike. Significant Materials /Activities Mineral Oil: Mineral oil is stored inside numerous oil- cooled transformers and circuit breakers in the 230kV Switchyard. Fuel Oil: A small section of fuel oil delivery piping is present aboveground southeast of the tank containment dike. Coal: Train cars carrying coal use the rail lines that pass along the southeastern edge of the drainage area. Discharge Controls None. Outfall SW004 (Drainage Area 4) Discharge Structure: 15 inch diameter Reinforced Concrete Pipe Location: East side Horseshoe Bend Beach Road Coordinates: 35 021'22" N 80 058'32" W Drainage Area: 4.6 acres Impervious Area: 15% Area Description The drainage area for SW004 is comprised of a narrow strip of station property located along the southeastern boundary between Horseshoe Bend Beach Road and the access road leading to the tanker fuel oil unloading station. The area is primarily comprised of a grassed yard. Approximately 200 linear feet of the paved tanker fuel oil unloading station access road crosses through the area. Stormwater is discharged from SW004 into a ditch that subsequently flows off -site to the south approximately 1000 feet to Mountain Island Lake. Significant Materials /Activities None. Discharge Controls None. 0 OutFall SW005 (Drainage Area 5) Discharge Structure: 24 inch diameter CMP Location: South side of Steam Plant Road Coordinates: 35 021'21" N 80 058'37" W Drainage Area: 3.5 acres Impervious Area: 8% Area Description The drainage area for SW005 is located along the northeast side of Steam Plant Road in the extreme southeastern area of the station property. The drainage area is primarily comprised of grassed yard with the western boundary of the area being formed by the centerline of the paved Steam Plant Road. Stormwater is discharged from SW005 into a ditch that subsequently flows off -site to the southwest. Significant Materials /Activities None. Discharge Controls None. Outfall SW006 (Drainage Area 6) Discharge Structure: 36 inch diameter CMP Location: West side of station intake canal Coordinates: 35 021'39" N 80 058'32" W Drainage Area: 5.2 acres Impervious Area: 35% Area Description The drainage area for SW006 is comprised of station yard areas west of the Powerhouse in the vicinity of the combustion turbine units and the Main Fuel Oil Storage Tank. Located within Drainage Area 6 are the four combustion turbine units and the instrumentation house and warehouse associated with these units. Drainage Area 6 also includes the 4,259,000 gallon Main Fuel Oil Storage Tank and the northeastern portion of the surrounding earthen containment dike for this tank. Aboveground fuel oil piping from the tank to the combustion turbine units and to the Powerhouse passes through the SW006 drainage area. A large transformer associated with the combustion turbine units is also located in this area southeast of the units. Four lube oil storage tanks are located at the two active combustion turbine units. A contaminated groundwater remediation /recovery system is in operation within Drainage Area 6. Groundwater is recovered from several monitoring wells within the area and is discharged into an oil /water separator. The separator discharges collected petroleum product into a 55 gallon drum, and discharges collected water into the station wastewater treatment system. Drainage Area 6 includes approximately 3 acres of grassed lawn areas, the grassed external slope of the earthen containment dike, and approximately 500 linear feet of paved access roadway surrounding the combustion turbine units. The Main Fuel Oil Tank containment dike is drained of collected rainwater by a manually operated siphon system. The collected rainwater discharges into a concrete ditch at the eastern base of the dike embankment. All stormwater runoff from within Drainage Area 6, including drainage from the containment dike, enters catch basins or ditches that discharge into the 20,000 gallon capacity No. 1 Oil Trap Tank located between the combustion turbines units and the station intake canal. The No. 1 Oil Trap Tank discharges into the intake canal. Significant Materials /Activities Fuel Oil: Fuel oil is stored in the 4,259,000 gallon Main Fuel Oil Storage Tank located within an earthen containment dike. Aboveground fuel oil piping runs between the tank and the combustion turbine units, and continues on to the Powerhouse. Mineral Oil: 9,237 gallons of mineral oil is present in the combustion turbine transformer. Lube Oil: Lube oil is stored in four 750 gallon capacity turbine lube oil tanks located at the two active turbine units. Contaminated Groundwater: Petroleum contaminated groundwater is recovered from several monitoring wells within the area. Discharge Controls 20,000 gallon capacity No. 1 Oil Trap Tank. Outfall SW007 (Drainage Area 7) Discharge Structure: 24 inch diameter steel pipe Location: Mountain Island Lake Coordinates: 35 021'80" N 80 058'28" W Drainage Area: 0.9 acres Impervious Area: 0% Area Description The drainage area for SW007 is comprised of a small portion of a grassed embankment on the northern side of the coal storage pile and a small section of gravel- surfaced roadway and laydown yard located between the coal storage pile and Mountain Island Lake. Significant Materials /Activities Inert Materials: Various quantities of structural steel, cable, truck trailers, and other inert materials may be stored on the gravel laydown yard area at various times. Discharge Controls None. Outfall SW008 (Drainage Area 8) Discharge Structure: 36 inch diameter CMP Location: Mountain Island Lake Coordinates: 35 °21'51" N 80 °58'16" W Drainage Area: 70 acres Impervious Area: 2% Area Description Drainage Area 8 is located in the central area of the station property and includes the closed dry ash stack occupying approximately 35 acres, the cinder pit encompassing approximately 9 acres, and a scrap yard adjacent to the cinder pit. Drainage Area 8 extends into undeveloped woodland areas on the south side of Horseshoe Bend Beach Road. Located within the drainage area is approximately 7 acres of woodlands, approximately 1,600 linear feet of ash sluice piping, approximately 6,150 linear feet of rail lines, approximately 2,425 linear feet of gravel- surfaced roadways, and approximately 3,500 linear feet of the paved Horseshoe Bend Beach Road. Two service transformers for the yard sump pumps are located within the drainage area at the north end of the coal storage pile. These transformers are surrounded by a containment dike with a chemical polymer oil containment barrier. Stormwater runoff from the ash stack and all areas south of the rail lines within Drainage Area 8 enters a stormwater collection basin located west of the ash stack. This basin discharges into the cinder pit through a pie beneath the rail lines. All stormwater runoff from within Drainage Area 8 eventually enters the cinder pit which functions as a large dry detention pond. The pit is fitted with a 3 feet high CMP riser pipe leading to the 36 inch diameter CMP discharge outlet pipe. Stormwater entering the cinder pit typically evaporates and /or infiltrates before reaching a level high enough to discharge into the riser pipe. Discharges from the 36 inch diameter CMP rarely occur. Significant Materials /Activities Mineral Oil: Mineral oil is present in the two yard sump pump service transformers located within a containment berm. Coal: Train cars carrying coal use the rail lines that pass through the drainage area. Ash: Waste ash is transported through ash sluice piping that runs through the drainage area. Inert Materials: Various quantities of inert materials may be stored on the scrap yard. Discharge Controls Cinder pit dry detention pond. Outfall SW009 (Abandoned). Outfall SW010 (Drainage Area 10) Discharge Structure: 18 inch diameter CMP Location: North of Lark Maintenance Facility Coordinates: 35 021'38" N 80 °58'41" W Drainage Area: 0.6 acres Impervious Area: 50% Area Description The drainage area for SW010 is comprised of the southeastern portion of the Lark Maintenance Facility roof, portions of a paved driveway and storage area on the east side of the facility, and vegetated areas east of the driveway. Stormwater from Drainage Area 10 is discharged into a woodlands area north of the facility that subsequently flows overland approximately 800 feet to Mountain Island Lake. Significant Materials /Activities Inert Materials: Various quantities of inert materials may be stored on the paved storage area on the east side of the facility. Discharge Controls None. Outfall SW011 (Drainage Area 11) Discharge Structure: 18 inch diameter CMP Location: West of Lark Maintenance Facility Coordinates: 35 021'33" N 80 058'45" W Drainage Area: 1.1 acres Impervious Area: 70% Area Description The drainage area for SW011 is comprised of the southwestern portion of the Lark Maintenance Facility roof, portions of a paved driveway and parking lot on the west side of the facility, and a small vegetated areas on the west side of the building. Stormwater from Drainage Area 11 is discharged into a woodlands area west of the facility that subsequently flows overland approximately 800 feet to Mountain Island Lake. Significant Materials /Activities None. Discharge Controls None. 10 Outfall SW012 (Drainage Area 12) Discharge Structure: 8 inch diameter polyethylene pipe Location: North of Lark Maintenance Facility Coordinates: 35 021'37" N 80 058'42" W Drainage Area: 0.1 acres Impervious Area: 100% Area Description The drainage area for SW012 is comprised wholly of roof drainage from the northeastern portion of the Lark Maintenance Facility roof. Stormwater from Drainage Area 12 is discharged into a woodlands area south of the facility that subsequently flows overland approximately 800 feet to Mountain Island Lake. Significant Materials /Activities None. Discharge Controls None. Outfall SW013 (Abandoned) Outfall SW014 (Drainage Area 14) Discharge Structure: 12 inch diameter CMP Location: East side of station intake canal Coordinates: 35 021'42" N 80 058'30" W Drainage Area: 0.02 acres Impervious Area: 0% Area Description The drainage area for SW014 is comprised wholly of a grassed bermed area surrounding the station septic tank. Stormwater runoff from within this small bermed area enters a catch basin that discharges into the intake canal from the steep eastern side of the canal embankment. Access to the discharge end of this pipe is difficult due to thick vegetation and the steepness of the bank. Significant Materials /Activities None. Discharge Controls None. 11 REMAINING DRAINAGE AREA DESCRIPTIONS The Riverbend Steam Station has additional non -point source stormwater runoff areas that discharge into Mountain Island Lake; and non - stormwater discharge drainage areas that discharge into the station yard sump that pumps to the ash settling basins. Non -point source stormwater runoff areas are described as follows: Non -Point Runoff - Immediately West of Station Intake Canal This area comprises approximately 1.5 acres and is located along the western side of the intake canal east of Drainage Area 6 and north of Drainage Area 2. The area contains a mobile office trailer and approximately 1 acre of asphalt pavement. Aboveground fuel oil piping from the Main Fuel Oil Storage Tank to the Powerhouse passes through this area. Approximately 65% of this drainage area is impervious. Stormwater runoff flows overland down the riprap slope of the western intake canal embankment. Non -Point Runoff - Immediately East of Station Intake Canal This area comprises approximately 1 acre and is located along the eastern side of the intake canal from the Powerhouse to the septic tank system. The area contains the 27,000 gallon capacity Light -off Fuel Oil Storage Tank and the 25,000 gallon capacity Used PCB Mineral Oil Storage Tank. Both of these tanks area are located within covered concrete containment basins with closed and locked drain valves. Aboveground fuel oil piping from the Main Fuel Oil Storage Tank to the Light -off Fuel Oil Storage Tank passes through this area. The area also contains a gravel - surfaced roadway and a small storage shed. The septic tanks area located within an earthen - bermed area that drains through Outfall SW014. Approximately 15% of this drainage area is impervious. Stormwater runoff flows overland down the vegetated slope of the eastern intake canal embankment. Non -Point Runoff - North End of Lark Maintenance Facility This area covers approximately 1.5 acres and is comprised of most of the northern portions of the facility roof and asphalt -paved roadways and parking areas surrounding the northern half of the building. Approximately 30 drums of various petroleum products, coolants, and solvents are stored inside a covered shed on the east side of the building. Inert materials are stored outside on pavement on the east side of the building. Approximately 75% of this drainage area is impervious. Stormwater runoff flows across asphalt pavement into the wooded area to the north. Non -Point Runoff — Areas Surrounding the Ash Settling Basins This large area extends from the intake canal across the area north of the cinder pit, and continues around the perimeter of the two ash settling basins. The area is primarily woodlands and includes the grassed exterior slopes of the ash settling basin embankments and dirt or gravel - surfaced access roads around the ash basins. A small gravel - surfaced laydown yard containing inert materials is located within this area north of the coal storage pile. There are no significant materials or activities located within this area, and none of the drainage area is impervious. 12 The Riverbend Steam Station has one yard sump that receives wastewater discharges from various internal and external areas of the station and subsequently pumps this wastewater to the ash basins. The sump pumps to the ash basins through a 30 inch diameter ductile iron pipe. Rarely occurring emergency sump overflows will discharge through a 24 inch diameter CMP to Mountain Island Lake. This outfall is permitted as NPDES Outfall 002A — Yard Sump Overflow. This sump accepts wastewater discharges from the boiler room sump and the turbine room sump inside the Powerhouse. These discharges include effluent from the sanitary system, once - through cooling water from the induced draft fan motors and the preheater bearings, effluent from a groundwater remediation system, effluent from a vehicle wash - down station, effluent from floor drains, and industrial wastewater from various powerhouse equipment. This yard sump also accepts stormwater runoff from several areas around the Powerhouse. This runoff generally flows into catch basins that discharge via subsurface piping into the sump. Located within the yard sump stormwater drainage area are the following: • The approximately 13 acre coal storage pile; • Approximately 1.3 acres of Powerhouse roof area; • All coal handling buildings, maintenance sheds, conveyors and equipment; • Warehouses and storage shed roofs; • Asphalt and gravel - surfaced roadways and parking areas; • Rail lines. Included within this drainage area are numerous transformers containing mineral oil, numerous 55 gallons drums containing new and used oils, a 1,000 gallon capacity gasoline underground storage tank, a 750 gallon capacity sulfuric acid tank, and a hazardous waste accumulation area. Refueling and tanker truck loading and unloading operations are conducted within the area for the coal handling bulldozers and tractors, at the gasoline underground storage tank, at the Light -off Fuel Oil Storage Tank, and at the Used PCB Mineral Oil Storage Tank. Various oils, chemicals, paints and solvents are unloaded from trucks within the drainage area. 13 OUTFALL SAMPLED SW001 SW003 SAMPLE COLLECTION DATE June 23, 2008 June 23, 2008 SAMPLE TYPE ANALYSES Grab EPA 1664A EPA 200.7 EPA 245.1 EPA 350.1 EPA 351.2 EPA 353.2 EPA 365.1 EPA 420.4 SM2540D SM 52106 SM 5220D SM 9222D Grab EPA 1664A EPA 200.7 EPA 245.1 EPA 350.1 EPA 351.2 EPA 353.2 EPA 365.1 EPA 420.4 SM2540D SM 52106 SM 5220D SM 9222D SW003 I June 23, 2008 1 Composite SM 52106 Page 1 or 46 Analytical Laboratory Duke Analytical Laboratory *Energy@ H13339 Ferry Road untersvilleille, NC 28078 -7929 Rev 07 -09 -07 McGuire Nuclear Complex — MG03A2 Phone: 704 - 875 -5245 Fax: 704 - 875 -5038 Job Summary Report Job Number: 08 -JUN -0400 j Project Name: Customer Name: Copy To: Customer Address: Riverbend Stormwater (6/23) Brandy Starnes Steve Jones, Greg Phillips Riverbend Steam Station Lab Contact: I Mary Ann Ogle Lab Contact Phone: 704 - 875 -5274 Report Authorized By: (Printed Name) MARY ANN OGLE Report Authorized By: (Signature) ' Date: o / 7 O Data Package This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical Laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Reports (if applicable) Sub - contracted Laboratory Results Customer Specific Data Sheets, Reports & Documentation (if applicable) Customer Database Entries Test Case Narratives Chain of Custody (COQ i .i Duke Analytical Laboratory *Energyo H13339 Ferry Road untersvilleille, NC 28078 -7929 00,07 61-0? McGuire Nuclear Complex — MG03A2 Phone: 704 - 875 -5245 Fax: 704 - 875 -5038 Job Summary Report Certification The Analytical Laboratory holds the following Certifications: New York State Department of Health Certification # 11717(7VELAC) North Carolina Department of Health & Human Services Certification # 37804 South Carolina (DHEC) Laboratory ID # 99005 North Carolina (DENR) Certification # 248 Analytical results listed in this report may not be certified by the authorities referenced above. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. The results meet all requirements of NELAC except where deviations are noted in this report. Data Flags Any analytical tests or individual analytes within a test flagged with an "X" or a "1" indicate a deviation from the method quality system or quality control requirement. Calculations All results are reported on a wet weight basis unless otherwise noted. Sample ID's & Descriptions: Page 2 of 46 Analytical Laboratory Collection Sample Sample ID Plant /Station Date Collected By Description 28017343 FOSSIL 6/23/2008 B. STARNES SWO01 (GRAB) RIVERBEND 28017347 FOSSIL 6/23/2008 B. STARNES SWO03 (GRAB) RIVERBEND 28017348 FOSSIL 6/23/2008 B. STARNES SWO03 (COMP.) RIVERBEND 3 TOTAL SAMPLES Duke Analytical Laboratory 16DEnergye H13339 Ferry Road untersvillille, NC 28078 -7929 ReY07 -03 -07 McGuire Nuclear Complex — MG03A2 Phone: 704 - 875 -5245 Fax: 704 - 875 -5038 Job Summary Report Validation of Analytical Data Package COC and .pdf report are in agreement with sample totals 1 and analyses (compliance programs and procedures). ii) All results are less than the laboratory reporting limits. iii) All laboratory QA/QC requirements are acceptable. 1V) NPDES and TCLP results are below permit or regulatory limits respectively. it iv) above is ivo, cocument ociow: Permit Variable Result I Limit Motes Page 3 of 46 Analytical Laboratory r Yes EE Yes KNo r No Yes j— No V) Components of the Job Summary Report arranged in order �!. Yes No stipulated on page one. Indicate components included: Job Summary Report Customer Specific Data Sheets, Reports & Documentation of applicable) Analytical Laboratory Certificate of lv Customer Database Entries Analysis Analytical Laboratory QC Report Test Case Narratives (if applicable) j' Sub - contracted Laboratory Results r Chain of Custody vi) Notes and Additional Information This is a partial report for SW 003 and SW 001. The other reports for this outfall are 08-JUL -0641 and 08- JUN -0400. SW 001 had a quality control failure for BOD on the grab sample. The value must be flagged when reporting to the state. The oxygen depeletion was < 2.0. The BOD results are considered questionable. The following parameters contained quality control failures for matrix spike recovery, but the spike was not performed on this sample: ammonia. The following parameters contained quality control failures for duplicate relative percent difference, the quality control was not performed on this sample: mercury and TKN. These quality control failures should be documented when reporting result, but these results are still considered valid. Mary Ann Ogle Duke Energy Analytical Lab NPDES Contact Office 704- 875 -5274 Cell 704- 280 -7956 1 aceAnalytical www.pacoobs.com , July 09, 2008 Mr. Jay Perkins Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: 08- JUN -0400 Pace Project No.: 9221945 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 Page 4 of 46 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)8759092 Dear Mr. Perkins: Enclosed are the analytical results for sample(s) received by the laboratory on June 23, 2008. The results relate only to the samples included in this report. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All Microbiological analyses were performed at the laboratory where the samples were received. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring @pacel abs.com Project Manager Enclosures cc: Accounts Payable DPEHS, Duke Energy Carolinas, LLC REPORT OF LABORATORY ANALYSIS Page 1 of 24 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. �Ft4: Page 5 of 46 Analytical Laboratory Pace Analytical Services, Inc. Pace Analytical Services, Inc. I 11IM11116111 2225 R iverside Dr. 9800 KlnceyAve. Suite 100 WW Paaccafabscnm Asheville, NC 28804 Huntersville, NC 28078 (828)2547176 (704)875 -9092 Project: 08- JUN -0400 Pace Project No.: 9221945 Charlotte Certification IDs Florida /NELAP Certification Number: E87627 Kansas Certification Number: E -10364 Louisiana /LELAP Certification Number: 04034 North Carolina Drinking Water Certification Number: 37706 North Carolina Wastewater Certification Number: 12 Asheville Certificatlon IDs Florida/NELAP Certification Number: E87648 Louisiana/LELAP Certification Number: 03095 New Jersey Certification Number: NC011 North Carolina Drinking Water Certification Number: 37712 North Carolina Wastewater Certification Number: 40 North Carolina Bioassay Certification Number: 9 Eden Certification IDs North Carolina Drinking Water Certification Number: 37738 Virginia Drinking Water Certification Number: 00424 CERTIFICATIONS North Carolina Field Services Certification Number: 5342 South Carolina Certification Number: 990060001 South Carolina Bloassay Certification Number: 990060003 Tennessee Certification Number: 04010 Virginia Certification Number 00213 Pennsylvania Certification Number: 68 -03578 South Carolina Certification Number: 99030001 South Carolina Bioassay Certification Number: 99030002 Tennessee Certification Number: 2980 Virginia Certification Number: 00072 North Carolina Wastewater Certification Number: 633 REPORT OF LABORATORY ANALYSIS Page 2 of 24 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. i I O r' J CEk ujyfical wwwpacalabu m Project: 08- JUN -0400 Pace Project No.: 9221945 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 SAMPLE SUMMARY Lab ID Sample ID Matrix Date Collected Date Received 9221945001 28017343 Water 06/23108 08:30 06/23/08 11:45 9221945002 28017347 Water 06/23/08 08:40 06/23/08 11:45 9221945003 28017348 Water 06/23/08 08:40 06/23/08 11:45 Page 6 of 46 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875 -9092 REPORT OF LABORATORY ANALYSIS Page 3 of 24 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. cri„„ � Pace Analytical Services, Inc. /r. 1" dCFr'Allr?lytjCa1 J 2225 Riverside Dr. �Wnvpacefabscom Asheville, NC 28804 (828)254 -7176 SAMPLE ANALYTE COUNT Project: 08- JUN -0400 Pace Project No.: 9221945 Lab ID Sample ID Method Analysts 9221945001 28017343 EPA 1664A DNP EPA 200.7 JMW EPA 245.1 EWS EPA 350.1 SAJ EPA 351.2 SAJ EPA 353.2 JDA EPA 365.1 DMN EPA 420.4 JDA SM 2540D SER SM 5210B JDA SM 5220D MJR SM 9222D CLW 9221945002 28017347 EPA 1664A DNP EPA 200.7 JMW EPA 245.1 EWS EPA 350.1 SAJ EPA 351.2 SAJ EPA 353.2 JDA EPA 365.1 DMN EPA 420.4 JDA SM 2540D SER SM 52108 JDA SM 5220D MJR SM 9222D CLW 9221945003 28017348 SM 5210B JDA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. a. Page 7 of 46 Analytical Laboratory Pace Analytical Services, Inc. 9800 Klncey Ave. Suite 100 Huntersville, NC 28078 (704)875.9092 Analytes Reported 1 17 1 1 1 1 1 1 1 1 1 1 1 17 1 1 1 1 1 1 1 1 1 1 1 Page 4 of 24 Page 8 of 46 Analytical Laboratory rr'�.• Pace Analytical Services, Inc. Pace Analytical Services, Inc. P a Ai�alj4ical 2225 Riverside Dr. 9800 KlnceyAve. Suite 100 rv�xaacnin5scorr Asheville, NC 28804 Huntersvllle, NC 28078 (828)254 -7176 (704)875 -9092 ANALYTICAL RESULTS Project: 08- JUN -0400 Pace Project No.: 9221945 Sample: 28017343 Lab ID: 9221945001 Collected: 06/23/08 08:30 Received: 06/23/08 11:45 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. faual HEM, Oil and Grease Oil and Grease 200.7 MET ICP Aluminum Arsenic Barium Boron Cadmium Chromium Cobalt Copper Iran Magnesium Manganese Nickel Selenium Silver Tin Titanium Zinc MBIO 9222D Fecal Coliform CHT Fecal Collforms 245.1 Mercury Mercury 2640D Total Suspended Solids Total Suspended Solids 52108 BOD, Low Level BOD, 5 day 350.1 Ammonia Nitrogen, Ammonia 351.2 Total Kjeldahl Nitrogen Nitrogen, Kjeldahl, Total 353.2 Nitrogen, N021NO3 pros. Nitrogen, NO2 plus NO3 365.1 Phosphorus, Total Phosphorus Analytical Method: EPA 1664A ND mg /L 5.0 1.1 1 06/30/08 12:19 Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 915 ug /L 100 25.0 1 06125/08 11:40 06/27/08 20:02 7429 -90 -5 5.4 ug /L 5.0 2.7 1 06/25/08 11:40 06/27/08 20:02 7440 -38 -2 33.9 ug /L 5.0 0.20 1 06125108 11:40 06/27/08 20:02 7440 -39 -3 79.5 ug /L 50.0 4.7 1 06/25/08 11:40 06/27/08 20:02 7440 -42 -8 1.3 ug /L 1.0 0.50 1 06/25/08 11:40 06/27/08 20:02 7440 -43 -9 NO ug /L 5.0 0.40 1 06/25/08 11:40 06/27/08 20:02 7440 -47 -3 ND ug /L 5.0 0.60 1 06125/08 11:40 06127/08 20:02 7440 -48 -4 68.4 ug /L 5.0 0.30 1 06/25/08 11:40 06/27/08 20:02 7440 -50 -8 2000 ug /L 50.0 14.0 1 06/25/08 11:40 06/27108 20:02 7439 -89-6 1700 ug /L 100 3.0 1 06/25/08 11:40 06/27/08 20:02 7439 -95 -4 78.4 ug /L 5.0 0.30 1 06/25/08 11:40 06/27/08 20:02 7439 -96 -5 7.0 ug /L 5.0 1.7 1 06/25/08 11:40 06/27/08 20:02 7440 -02 -0 62.0 ug /L 10.0 3.8 1 06/25/08 11:40 06/27/08 20:02 7782 -49 -2 ND ug /L 5.0 0.10 1 06/25/08 11:40 06/27/08 20:02 7440 -22 -4 ND ug /L 5.0 1.8 1 06/25/08 11:40 06/27/08 20:02 7440 -31 -5 25.6 ug /L 5.0 0.10 1 06/25/08 11:40 06127/08 20:02 7440 -32 -6 863 ug /L 10.0 0.40 1 06/25/08 11:40 06127/08 20:02 7440 -66 -6 Analytical Method: SM 9222D ND CFU 1100 mL 1.0 1 06/23108 13:46 Analytical Method: EPA 245.1 Preparation Method: EPA 245.1 NO ug /L 0 20 0.20 1 06/25/08 16:00 06/27/08 15:09 7439 -97-6 Analytical Method: SM 2540D 29.3 mg /L 313 1 06/29/0817:25 Analytical Method: SM 5210B 13.0 mg /L 2.0 1 06/25/08 07:30 06/30/08 07:30 Analytical Method: EPA 350.1 1.7 mg /L 0.10 0.10 1 07/01/0814:41 7764 -41 -7 Analytical Method: EPA 351.2 2.4 mg /L 0.50 0.50 1 07/03108 15:28 7727 -37 -9 Analytical Method: EPA 353.2 1.5 mg /L 0.10 0.10 1 07/05/08 09:04 Analytical Method: EPA 365.1 0.53 mg /L 0.10 0.10 1 07/01/0810:48 7723 -14 -0 B2 Date: 07/0912008 03:30 PM REPORT OF LABORATORY ANALYSIS Page 5 of 24 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. die Page 9 of 46 _> Analytical Laboratory f r ✓f.' ® Pace Analytical Services, Inc. Pace Analytical Services, Inc. ..ace Analytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 wwwpacelabs.cart Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)8759092 Project: 08- JUN -0400 Pace Project No.: 9221945 Sample: 28017343 Parameters 420.4 Phenolics, Total Phenol 5220D COD Chemical Oxygen Demand ANALYTICAL RESULTS Lab ID: 9221945001 Collected: 06/23/08 08:30 Received: 06123/08 11:45 Matrix: Water Report Results Units Limit MDL DF Prepared Analyzed CAS No. Analytical Method: EPA 420.4 ND mg /L 0.010 0.010 1 06/30/08 13:12 108 -95 -2 Analytical Method: SM 5220D ND mg /L 25.0 25.0 I 06/26/08 11:39 Oual Date: 07/09/2008 03:30 PM REPORT OF LABORATORY ANALYSIS Page 6 of 24 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. { Page 10 of 46 Analytical Laboratory rf a Pace Analytical Services, Inc. Pace Analytical Services, Inc. rr"aceAnalytieal 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 www.pacelaftcom Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)875 -9092 Project: 08-JUN -0400 Pace Project No.: 9221945 Sample: 28017347 Parameters HEM, Oil and Grease Oil and Grease 200.7 MET ICP Aluminum Arsenic Barium Boron Cadmium Chromium Cobalt Copper Iron Magnesium Manganese Nickel Selenium Silver Tin Titanium Zinc MBIO 9222D Fecal Collform CHT Fecal Colifonns 245.1 Mercury Mercury 2540D Total Suspended Solids Total Suspended Solids 52108 BOD, Low Level BOD, 5 day 350.1 Ammonia Nitrogen, Ammonia 351.2 Total Kjeldahl Nitrogen Nitrogen, Kjeldahl, Total 353.2 Nitrogen, NO2/NO3 pres. Nitrogen, NO2 plus NO3 365.1 Phosphorus, Total Phosphorus ANALYTICAL RESULTS Lab ID: 9221945002 Collected: 06123/08 08:40 Received: 06/23/08 11:45 Matrix: Water Report Results Units Limit MOIL OF Prepared Analyzed CAS No. Qual Analytical Method: EPA 1664A ND mg /L 5.0 1.1 1 06/30/08 12:20 Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 753 ug /L 100 25.0 1 06/25/08 11:40 06/27108 20:05 7429 -90 -5 5.0 ug /L 5.0 2.7 1 06/25/08 11:40 06/27108 20:05 7440 -38 -2 115 ug /L 5.0 0.20 1 06/25/08 11:40 06/27/08 20:05 7440 -39 -3 72.2 ug /L 50.0 4.7 1 06/25/08 11:40 06/27/08 20:05 7440 -42 -8 NO ug /L 1.0 0.50 1 06/25/08 11:40 06/27/08 20:05 7440 -43 -9 NO ug /L 5.0 0.40 1 06/25/08 11:40 06127/08 20:05 7440 -47 -3 ND ug /L 5.0 0.60 1 06/25/08 11:40 06/27/08 20:05 7440 -48 -4 53.3 ug /L 5.0 0.30 1 06/25/0811:40 06/27/08 20:05 7440 -50 -8 21200 ug /L 50.0 14.0 1 06/25/08 11:40 06/27/08 20:05 7439 -89 -6 9570 ug /L 100 3.0 1 06/25108 11:40 06/27/08 20:05 7439 -95 -4 1380 ug /L 5.0 0.30 1 06/25108 11:40 06/27/08 20:05 7439 -96 -5 6.8 ug /L 5.0 1.7 1 06/25/08 11:40 06/27/08 20:05 7440 -02 -0 NO ug /L 10.0 3.8 1 06/25108 11:40 06/27/08 20:05 7782 -49 -2 NO ug /L 5.0 0.10 1 06/25/08 11:40 06/27/08 20:05 7440 -22 -4 NO ug /L 5.0 1.8 1 06125108 11:40 06/27/08 20:05 7440 -31 -5 29.9 ug /L 5.0 0.10 1 06/25108 11:40 06/27108 20:05 7440 -32 -6 2290 ug /L 10.0 0.40 1 06/25/08 11:40 06/27108 20:05 7440 -66 -6 Analytical Method: SM 9222D 100 CFU 1100 mL 1.0 1 06/23/08 13:46 Analytical Method: EPA 245.1 Preparation Method: EPA 245.1 NO ug /L 0.20 0.20 1 06/25/08 16:00 06/27108 15:17 7439 -97 -6 Analytical Method: SM 25400 151 mg /L 6.7 1 06/29/0817:25 Analytical Method: SM 5210B 72.9 mg /L 2.0 1 06/25/08 07:30 06/30/08 07:30 Analytical Method: EPA 350.1 0.80 mg /L 0.10 0.10 1 07/01/0814:42 7764 -41 -7 Analytical Method: EPA 351.2 7.7 mg /L 0.50 0.50 1 07/03/08 15:30 7727 -37 -9 Analytical Method: EPA 353.2 1.2 mg /L 0.10 0.10 1 07/05/08 09:04 Analytical Method: EPA 365.1 1.6 mg /L 0.10 0.10 1 07/01/0810:48 7723 -14 -0 101 Date: 07/09/2008 03:30 PM REPORT OF LABORATORY ANALYSIS Page 7 of 24 This report shall not be reproduced, except in Full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 46 Analytical Laboratory Pace Analytical Services, Inc. Pace Analytical Services, Inc. r�/+ �jr�r� }�+�j e `Cl6+�/if fCll�t1UQ1 2225 Riverside Dr. 9900 Kincey Ave. Suite 100 ? Asheville, NC 28804 Huntersville, NC 28078 wriw3�aturrrax.rtm (828)254 -7176 (704)875.9092 ANALYTICAL RESULTS Project: 08- JUN -0400 Pace Project No.: 9221945 Sample: 26017347 Lab ID: 9221945002 Collected: 06/23/08 08:40 Received: 06/23/08 11:45 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No, QuaP 420.4 Phenolics, Total Analytical Method: EPA 420.4 Phenol 0.045 mg /L 0.010 0.010 1 06/30108 13:12 108 -95 -2 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 233 mg /L 25.0 25.0 1 06126/08 11:39 Date: 07109/2008 03:30 PM REPORT OF LABORATORY ANALYSIS Page 8 of 24 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc. Page 12 of 46 Analytical Laboratory e Pace Analytical Services, Inc. Pace Analytical Services, Inc. �CeAna1 ica f 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 www.pacelaba,com Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7178 (704)875 -9092 ANALYTICAL RESULTS Project: 08- JUN -0400 Pace Project No.: 9221945 Sample: 28017348 Lab ID: 9221845003 Collected: 06/23/08 08:40 Received: 06123/08 11:45 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 52108 BOD, Low Level Analytical Method: SM 5210B BOD, 5 day 54.9 mg /L 2.0 1 06/25/08 07:30 06/30/08 07:30 Date: 07109/2008 03:30 PM REPORT OF LABORATORY ANALYSIS Page 9 of 24 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. ' FaceAnalytical www.paceiabs.com Project: 08- JUN -0400 Pace Project No.: 9221945 QC Batch: MBCH 11652 QC Batch Method: SM 9222D Associated Lab Samples: 9221945001, 9221945002 METHOD BLANK: 132486 Associated Lab Samples: 9221945001, 9221945002 Parameter tlnlls Fecal Colifonns CFU /100 mL Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 QUALITY CONTROL DATA Analysis Method: SM 9222D Analysis Description: 9222D MBIO Fecal Coliform - CHT Blank Reporting Result Limit Qualifiers ND t 4 Page 13 of 46 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875 -9092 SAMPLE DUPLICATE: 132487 9221945001 Dup Max Parameter Units Result Result RPD RPD Quailfiers Fecal Coliforms CFU /100 mL ND Nn 0 20 Date: 07/09/2008 03:30 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. QQtty�yy� o Page 10 of 24 e Pace Analytical Services, Inc. �eeAnalyiical 2225 Riverside Dr. wwwpacelabs.cam Asheville, NC 26604 ( (828)254 -7176 QUALITY CONTROL DATA Project: 08- JUN -0400 Pace Project No.: 9221945 QC Batch: WET /4435 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210B BOD, Low Level Associated Lab Samples: 9221945001, 9221945002, 9221945003 METHOD BLANK: 132528 Associated Lab Samples: 9221945001, 9221945002, 9221945003 Blank Reporting Parameter Units Result Limit Qualifiers BOD, 5 day mg /L ND 2.0 Page 14 of 46 Analytical Laboratory Pace Analytical Services, Inc. 9800 KlnceyAve. Suite 100 Huntersvllle, NC 28078 (704)875 -9092 LABORATORY CONTROL SAMPLE: 132529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day mg /L 198 211 107 84 -115 SAMPLE DUPLICATE: 132530 9221990001 Dup Max Parameter Units Result Result RPD RPD Qualifiers BOD, 5 day mg /L 3.1 3.1 0 20 Date: 07/09/2008 03:30 PM REPORT OF LABORATORY ANALYSIS Page 11 of 24 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 46 f` Analytical Laboratory 0 Pace Analytical Services, Inc. Pace Analytical Services, Inc. Ct�t� �C�IICr! 2225 Riverside Dr. 9800 Klncey Ave. Suite 100 wwwPac9kb&coin Asheville, NC 28604 Huntersvllle, NC 28076 (828)254 -7176 (704)875.9092 QUALITY CONTROL DATA i Project: 08- JUN -0400 Pace Project No.: 9221945 QC Batch: MERP /1556 Analysis Method: EPA 245.1 QC Batch Method: EPA 245.1 Analysis Description: 245.1 Mercury Associated Lab Samples: 9221945001, 9221945002 METHOD BLANK: 132539 Associated Lab Samples: 9221945001, 9221945002 Parameter Units Mercury ug /L LABORATORY CONTROL SAMPLE: 132540 Parameter Units Mercury ug /L i MATRIX SPIKE SAMPLE: 132541 Parameter Units Mercury ug /L SAMPLE DUPLICATE: 132542 Parameter Mercury Blank Reporting Result Limit Qualifiers ND 0.20 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 2.5 2.7 109 85 -115 92 21 9700 01 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers 2.4 2.5 4.3 76 70 -130 9221970002 Dup Max Units Result Result RPD RPD Qualifiers ug /L ND ND 1,07 20 Ras_ Date: 07/09/2008 03:30 PM REPORT OF LABORATORY ANALYSIS Page 12 of 24 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 46 Analytical Laboratory / 0 Pace Analytical Services, Inc. Pace Analytical Services, Inc. cem f �Saixical 2225 Riverside Dr. 9800 Klncey Ave. Suite 100 QG �.cp�acje'laatis=M Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)8759092 QUALITY CONTROL DATA Project: 08-JUN -0400 Pace Project No.: 9221945 QC Batch: MPRP /2580 Analysis Method: EPA 200.7 QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET i Associated Lab Samples: 9221945001, 9221945002 METHOD BLANK: 132549 Associated Lab Samples: 9221945001, 9221945002 Blank Reporting Parameter Units Result Limit Qualifiers Aluminum ug /L NO 100 Arsenic ug /L NO 5.0 Barium ug /L NO 5.0 Boron ug /L NO 50.0 Cadmium ug /L NO 1.0 Chromium ug /L NO 5.0 Cobalt ug /L NO 5.0 Copper ug /L NO 5.0 Iron ug /L NO 50.0 Magnesium ug /L NO 100 Manganese ug /L NO 5.0 Nickel ug /L NO 5.0 Selenium ug /L NO 10.0 Silver ug /L NO 5.0 Tin ug /L NO 5.0 Titanium ug /L NO 5.0 Zinc ug /L NO 10.0 LABORATORY CONTROL SAMPLE: 132550 Spike LCS LCS % Rec Parameter Units Conc. Result - % Rec Limits Qualifiers Aluminum ug/L 5000 4610 92 85 -115 Arsenic ug/L 500 481 96 85 -115 Barium ug /L 500 466 93 85 -115 Boron ug /L 500 478 96 85 -115 Cadmium ug /L 500 477 95 85 -115 Chromium ug /L 500 483 97 85 -115 Cobalt ug /L 500 474 95 85 -115 Copper ug /L 500 474 95 85 -115 Iron ug /L 5000 4780 96 85 -115 Magnesium ug /L 5000 4750 95 85 -115 Manganese ug /L 500 481 96 85 -115 Nickel ug /L 500 478 96 85 -115 Selenium ug /L Soo 462 92 85 -115 Silver ug /L 250 243 97 85 -115 Tin ug /L 500 483 97 85 -115 Titanium ug /L 500 483 97 85 -115 Zinc ug /L 500 470 94 85 -115 Date: 07/09/2008 03:30 PM REPORT OF LABORATORY ANALYSIS Page 13 of 24 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 46 Analytical Laboratory Ar- ® Pace Analytical Services, Inc. Pace Analytical Services, Inc. i aceAna1y6cal 2225 Riverside Dr. 9800 Klncey Ave, Suite 100 www.pacelabs.com Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)875 -9092 Project: 08- JUN -0400 Pace Project No.: 9221945 MATRIX SPIKE SAMPLE: Parameter Aluminum Arsenic Barium Boron Cadmium Chromium Cobalt Copper Iron Magnesium Manganese Nickel Selenium Silver Tin Titanium Zinc SAMPLE DUPLICATE: 132552 Parameter Aluminum Arsenic Barium Boron Cadmium Chromium Cobalt Copper Iron Magnesium Manganese Nickel Selenium Silver Tin Titanium Zinc QUALITY CONTROL DATA 1,12551 9221925001 Result Dup Result RPD Max RPD Qualifiers ug /L 46500 9221909014 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers ug/L ND 5000 4730 93 70 -130 ug /L ND 500 468 93 70 -130 ug /L ND 500 389 77 70 -130 ug /L 82.5 500 523 88 70 -130 ug /L ND 500 407 81 70 -130 ug /L ND 500 425 85 70 -130 ug /L ND 500 398 80 70 -130 ug /L 11.3 500 453 88 70 -130 ug /L 256 5000 4270 80 70 -130 ug /L 3840 5000 7610 75 70 -130 ug /L 8.5 500 413 81 70 -130 ug /L ND 500 402 80 70 -130 ug /L 10.4 500 467 91 70 -130 ug /L ND 250 226 90 70 -130 ug /L ND 500 418 83 70 -130 ug /L ND 500 421 84 70 -130 ug /L 36.3 500 476 88 70 -130 ullils 9221925001 Result Dup Result RPD Max RPD Qualifiers ug /L 46500 47000 1 20 ug /L 22.5 19.7 13 20 ug /L 526 536 2 20 ug /L 56.0 54.4 3 20 ug /L 10.4 11.1 7 20 ug /L 553 560 1 20 ug /L ND ND 0 20 ug /L 1550 1590 2 20 ug /L 228000 249000 9 20 ug /L 27200 27500 1 20 ug/L 2760 2790 1 20 ug /L 398 404 1 20 ug /L 31.5 30.1 5 20 ug /L ND 2.6J 3 20 ug/L 285 289 1 20 ug /L 3350 3380 .7 20 ug /L 268000 290000 8 20 Date: 07/0912008 03:30 PM REPORT OF LABORATORY ANALYSIS Page 14 of 24 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 46 Analytical Laboratory 0 Pace Analytical Services, Inc. Pace Analytical Services, Inc. f+ ?FaceAnalytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 www.pacelabs.com Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)875.9092 QUALITY CONTROL DATA Project: 08- JUN -0400 Pace Project No.: 9221945 QC Batch: WETA/2944 Analysis Method: SM 5220D QC Batch Method: SM 5220D Analysis Description: 5220D COD Associated Lab Samples: 9221945001, 9221945002 METHOD BLANK: 132909 Associated Lab Samples: 9221945001, 9221945002 Blank Reporting Parameter Units Result Limit Qualifiers Chemical Oxygen Demand mg /L ND 25.0 LABORATORY CONTROL SAMPLE: 132910 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg /L 750 760 101 90 -110 MATRIX SPIKE SAMPLE: 132911 9221755001 Spike MS MS % Rec Parameter Units Result Cone. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg1L 2040 750 5220 424 - 75-125 M0 MATRIX ;SPIRE SAMPLE: 13291 ai 9221804002 Spike MS MS % Rec Parameter Units Result Cone. Result % Rec Limits Qualifiers Chemical Oxygen Demand _ . mg /L _ 115 750 904 _.e 105 75 -125 SAMPLE DUPLICATE: 132912 9221381001 Dup Marc Parameter Units Result Result RPD RPD Qualifiers Chemical Oxygen Demand mg /L ND ND 52 20 R1 SAMPLE DUPLICATE: 132913 9221804001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Chemical Oxygen Demand mg /L 12800 11900 8 20 Date: 07/09/2008 03:30 PM REPORT OF LABORATORY ANALYSIS Page 15 of 24 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. i CeArlrl" wwwpacelabs.com i Project: 08- JUN -0400 Pace Project No.: 9221945 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 QUALITY CONTROL DATA QC Batch: WET 14484 Analysis Method: SM 25400 QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 9221945001, 9221945002 METHOD BLANK: 134338 Associated Lab Samples: 9221945001, 9221945002 Parameter Units Total Suspended Solids mg /L LABORATORY CONTROL SAMPLE: Parameter 134339 Units Total Suspended Solids mg /L SAMPLE DUPLICATE: 134341 Parameter Units Total Suspended Solids mg /L SAMPLE DUPLICATE: 134410 Parameter Units Total Suspended Solids mg /L Blank Reporting Result Limit Qualifiers ND 1.0 Page 19 of 46 Analytical Laboratory Pace Analytical Services, Inc, 9800 Klncey Ave. Suite 100 Huntersville, NC 28078 (704)875 -9092 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 264 108 80 -120 9222027001 Dup Max Result Resuit RPD RPD Qualifiers 94,0 98.0 4 20 9222029002 Dup Max Result Result RPD RPD Qualifiers ND NO 4 209 20 tlAx 5 Date: 07/09/2008 03:30 PM REPORT OF LABORATORY ANALYSIS Page 16 of 24 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. `hey QUV!'1f�Ci +,�f/LLi a www.pacelaWom Project: 08- JUN -0400 Pace Project No.: 9221945 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 QUALITY CONTROL DATA QC Batch: WETA12975 Analysis Method: EPA 420.4 QC Batch Method: EPA 420.4 Analysis Description: 420.4 Phenolics Associated Lab Samples: 9221945001, 9221945002 METHOD BLANK: 134431 Associated Lab Samples: 9221945001, 9221945002 Blank Reporting Parameter Units Result Limit Qualifiers Phenol mg /L t,IU 0.010 Page 20 of 46 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875 -9092 LABORATORY CONTROL SAMPLE: Parameter 134432 Units Spike LCS Conc. Result LCS % Rec % Rec Limits Qualifiers Phenol mg /L .25 0.24 9tS 90 -110 MATRIX SPIKE SAMPLE: 134433 9221843006 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Phenol mg /L 0.21 _25 0.47 104 90 -110 SAMPLE DUPLICATE: 134434 9221925001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Phenol mg /L ND ND 47 201:R.1 � ft� t� Date: 07/09/2008 03:30 PM REPORT OF LABORATORY ANALYSIS Page 17 of 24 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 46 Analytical Laboratory Pace Analytical Services, Inc. Pace Analytical Services, Inc. F�rTlyticC 2225 Riverside Dr. 9600 Kincey Ave. Suite 100 wwvwpacelabscvm Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)6759092 QUALITY CONTROL DATA Project: 08- JUN -0400 Pace Project No.: 9221945 QC Batch: GCSV /3150 Analysis Method: EPA 1664A QC Batch Method: EPA 1664A Analysis Description: 1664 HEM, Oil and Grease Associated Lab Samples: 9221945001, 9221945002 METHOD BLANK: 134471 Associated Lab Samples: 9221945001, 9221945002 Blank Reporting Parameter Units Result Limit Qualifiers Oil and Grease mg /L ND 5.0 LABORATORY CONTROL SAMPLE & LCSD: 134472 134473 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Oil and Grease mg /L 40 39.5 38.7 99 97 78 -114 2 30 Date: 07/0912008 03:30 PM REPORT OF LABORATORY ANALYSIS Page 1S of 24 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. � wee "W..pacalaos.com Project: 08- JUN -0400 Pace Project No.: 9221945 QUALITY CONTROL DATA QC Batch: WETA12976 Page 22 of 46 Analysis Method: EPA 365.1 Analytical Laboratory Pace Analytical Services, Inc. Pace Analytical Services, Inc. 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)875.9092 QUALITY CONTROL DATA QC Batch: WETA12976 Analysis Method: EPA 365.1 QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total Associated Lab Samples: 9221 945001, 9221945002 METHOD BLANK: 134637 Associated Lab Samples: 9221945001, 9221945002 Blank Reporting Parameter Units Result Limit Qualifiers Phosphorus mg /L ND 0,10 LABORATORY CONTROL SAMPLE: 134638 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg /L 1 1.1 107 90 -110 MATRIX SPIKE SAMPLE: 134639 9222315001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Phosphorus mg /L 7.7 1 8.8 110 90 -110 MATRIX SPIKE SAMPLE: 134647 9222090001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Phosphorus mg /L 19 1 4.6 97 90 -110 SAMPLE DUPLICATE: 134640 9222315002 Dup Max Parameter LJOIs Result Result RPD RPD Qualifiers Phosphorus mg /L 0.50 0,48 3 20 SAMPLE DUPLICATE: 134648 9222112001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Phosphorus mg /L 0.25 0.22 13 20 Date: 07/09/2008 03:30 PM REPORT OF LABORATORY ANALYSIS Page 19 of 24 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 46 >, Analytical Laboratory r Pace Analytical Services, Inc. Pace Analytical Services, Inc. f . iaccAnalyiieal a 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 wmpacelabs.com Asheville, NC 28604 Huntersville, NC 28078 (828)254 -7178 (704)8759092 QUALITY CONTROL DATA Project: 08- JUN -0400 Pace Project No.: 9221945 QC Batch: WETA/2979 Analysis Method: EPA 350.1 QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia Associated Lab Samples: 9221945001, 9221945002 METHOD BLANK: 134684 Associated Lab Samples: 9221945001, 9221945002 Blank Reporting Parameter Units Result Limit Qualifiers Nitrogen, Ammonia mg /L f ND 0.10 LABORATORY CONTROL SAMPLE: 134685 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg /L T 5 5.1 102 90 -110 MATRIX SPIKE SAMPLE: 134686 9221937001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg /L 0.94 5 7.0 121 90 -110 MO MATRIX SPIKE SAMPLE: 134689 9221967005 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg /L 307 500 366 -.2 '' 90=110 M0 SAMPLE DUPLICATE: 134687 9221945001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, Ammonia mg /L 1.7 1.6 3 20 SAMPLE DUPLICATE: 134688 9221967004 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, Ammonia mg /L 19.2 19.5 2 20 Date: 07/09/2008 03:30 PM REPORT OF LABORATORY ANALYSIS Page 20 of 24 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 46 Analytical Laboratory ;a r�. f' { Pace Analytical Services, Inc. Pace Analytical Services, Inc. �` ...-P cc AaalX cal 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 ,efw.nars;;k,coart+ Asheville, NC 26604 Huntersvilla, NC 28078 r (828)254 -7176 (704)875 -9092 QUALITY CONTROL DATA Project: 08- JUN -0400 Pace Project No.: 9221945 QC Batch: WETA/2980 Analysis Method: EPA 351.2 QC Batch Method: EPA 351.2 Analysis Description: 351.2 TKN Associated Lab Samples: 9221945001, 9221945002 METHOD BLANK: 135028 Associated Lab Samples: 9221945001, 9221945002 Blank Reporting Parameter Units Result Limit Qualifiers Nitrogen, Kjeldahl, Total mg /L trU 0.50 LABORATORY CONTROL SAMPLE: 135029 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg /L 5 51 104 90 -110 MATRIX SPIKE SAMPLE: 135030 9222267008 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg /L 2 -7 5 7,3 92 90-110 MATRIX SPIKE SAMPLE: 135032 9221945001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers _ Nitrogen, Kjeldahl, Total ....... mg /L 2.4 138 90 90 -110 SAMPLE DUPLICATE: 135031 u 9222267009 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, Kjeldahl, Total mg /L 2.7 2.2 23 20 :131 SAMPLE DUPLICATE: 135033 9221945002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, Kjeldahl, Total mg /L 7,7 5.7 29 20 RI Date: 07/0912008 03:30 PM REPORT OF LABORATORY ANALYSIS Page 21 of 24 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. r<a i _. aceArraJyficaJ a www.pkalabacom Project: 08- JUN -0400 Pace Project No.: 9221945 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 QUALITY CONTROL DATA QC Batch: WETA/2997 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, preserved Associated Lab Samples: 9221945001, 9221945002 METHOD BLANK: 136274 Associated Lab Samples: 9221945001. 9221945002 Parameter Units Nitrogen, NO2 plus NO3 mg /L LABORATORY CONTROL SAMPLE: 136275 Parameter Units Nitrogen, NO2 plus NO3 mg /L MATRIX SPIKE SAMPLE: 136276 Parameter Units Nitrogen, NO2 plus NO3 mg /L MATRIX SPIKE SAMPLE: Parameter Nitrogen, NO2 plus NO3 SAMPLE DUPLICATE: 136277 Parameter Nitrogen, NO2 plus NO3 SAMPLE DUPLICATE: 136279 Parameter Nitrogen, NO2 plus NO3 136278 Units mg /L Units mg /L Units mg /L Blank Reporting Result Limit Qualifiers ND 0.10 Page 25 of 46 Analytical Laboratory Pace Analytical Services, Inc. 9800 KIncey Ave. Suite 100 Huntersville, NC 28078 (704)875 -9092 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers w, 50 101 90 -110 9222267009 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers NI-) 9 11 cl 98 75 -125 9221945002 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers 1.2 5 5.5 86 75 -125 9222267010 Dup Max Result Result RPD RPD Qualifiers ND ND 75 20 R1 9222177003 Dup Result Result RPD 6.9 6.9 .1 Max RPD Qualifiers 20 Date: 07/0912008 03:30 PM REPORT OF LABORATORY ANALYSIS Page 22 of 24 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 46 Analytical Laboratory r r a Pace Analytical Services, Inc. Pace Analytical Services, Inc. r�ceAnadydcal 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 l www.pacelabs.com Asheville, NC 28804 Huntersvills, NC 28078 (828)254 -7176 (704)875 -9092 QUALIFIERS Project: 08- JUN -0400 Pace Project No.: 9221945 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. S - Surrogate 1,2- Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes. ANALYTE QUALIFIERS B2 Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. MO Matrix spike recovery was outside laboratory control limits. R1 RPD value was outside control limits. R3 RPD value was outside control limits due to uncertainty of values at or near the PRL. u1 Results based upon colony counts outside acceptable range. Date: 07/09/2008 03:30 PM REPORT OF LABORATORY ANALYSIS Page 23 of 24 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 9 a.. nk �l f 9 i i 4 r Pace Analytical Services, Inc. f�)� ftrFf' 2225 Riverside Dr. I www.paccofabs.com Asheville, NC 28804 r' (828)254 -7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 08- JUN -0400 Pace Project No.: 9221945 Page 27 of 46 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875 -9092 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 9221945001 28017343 SM 9222D MBCH /1652 9221946002 28017347 SM 9222D MBCH /1652 9221945001 28017343 SM 5210B WET/4435 SM 5210B 9221945002 28017347 SM 5210B WET /4435 SM 5210B 9221945003 28017348 SM 5210B WET14435 SM 5210B 9221945001 28017343 EPA 245.1 MERP /1556 EPA 245.1 9221945002 28017347 EPA 245.1 MERP /1556 EPA 245.1 9221945001 28017343 EPA 200.7 MPRP /2580 EPA 200.7 9221945002 28017347 EPA 200.7 MPRP 12580 EPA 200.7 9221945001 28017343 SM 5220D WETA/2944 9221945002 28017347 SM 5220D WETA/2944 9221945001 28017343 SM 2540D WET/4484 9221945002 28017347 SM 2540D WET/4484 9221945001 28017343 EPA 420.4 WETA/2975 9221945002 28017347 EPA 420.4 WETA/2975 9221945001 28017343 EPA 1664A GCSV /3150 9221945002 28017347 EPA 1664A GCSV /3150 9221945001 28017343 EPA 365.1 WETA12976 9221945002 28017347 EPA 365.1 WETA12976 9221945001 28017343 EPA 350.1 WETA/2979 9221945002 28017347 EPA 350.1 WETA/2979 9221945001 28017343 EPA 351.2 WETA12980 9221945002 28017347 EPA 351.2 WETA12980 9221945001 28017343 EPA 353.2 WETA12997 9221945002 28017347 EPA 353.2 WETA12997 Date: 07/09/2008 03:30 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch WET/4499 WET/4499 WET/4499 MERC /1558 MERC /1558 ICP/2462 ICP/2462 Page 24 of 24 Page 28 of 46 Analytical Laboratory Client Name: J��� Project Courier: jo Fed Ex ❑ UPS ❑ USPS ❑ Client ❑ Commercial YJ Pace Other Custody Seal on Cooler /Box Present: yes Ef no Seals Intact: �t yes El no �` �f/�` ! Ff 4m] f4i[[l Packing Material: ❑ Bubble Wrap ubble Bags ❑ None ❑Other Thermometer Used T060 r Type of Ice: D'Blue None [fir pies on ice, cooling process has begun /]I n,te and t, : �� of Cooler Temperature ,2 Biological Tissue is Frozen: Yes N� N7R1 n_ n to ers_et gxvrr,ir;nr, contents: G 6 Temp should be above freezing to 6'C Comments: Chain of Custody Present: Yes ❑No ❑N /A 1. Chain of Custody Filled Out: Yes ❑No ❑N /A 2. Chain of Custody Relinquished: Yes ❑No ❑NIA 3. Sampler Name & Signature on COC: Yes ❑No ❑N /A 4. Samples Arrived within Hold Time: AYes ❑No ❑N /A 5. Short Hold Time Analysis ( <72hr): JAYes ❑No ❑N /A .6 Rush Turn Around Time Requested: Yes ❑No ❑N /A T Sufficient Volume: ❑Yes JANo ❑N/A a, k/ %d �� d �v�Ga �,p hl, r Correct Containers Used: ❑Yes XNo ❑N /A g. ?l k.e VOIS -Pace Containers Used: ❑Yes No• ❑N /A cSA&lrYb(aa Containers Intact: Yes ❑No ❑N/A 10, s Filtered volume received for Dissolved tests ❑Yes ❑No NIA 11 Sample Labels match COC: AYes ❑No ❑N /A 12. - Includes date /time /ID /Analysis Matrix:_ All containers needing preservation have been checked, Yes ❑No ❑N /A 13. All containers needing preservation are found to be in Yes ❑No ❑N /A compliance with EPA recommendation, (( exceptions: VOA, collform, TOG, 0 &G, WI -DRO (water) ❑Yes ❑No Initial when completed Samples checked for dechlorination: Yes ❑No ❑NIA 14. IHeadspace in VOA Vials ( >6mm): ❑Yes ❑No ON /A 15. "trip Blank Present: ❑Yes ❑No . (SIN /A 16. trip Blank Custody Seals Present ❑Yes ❑No mNIA r Pace Trip Blank Lot # (if purchased): N/A Client Notification/ Resolution: Field Data Required? Y / N / N/A Person Contacted: �F AA-rJ Date/Time: G APLOg3 Comments/ Resolution: Project Manager Review: Date: 6 Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) Page 29 of 46 Analytical Laboratory EPA ID Number (copy from item I of Form 7) Please print or type in the unshaded areas Form Approved. OMB No. 2040 -0086 Approval expires 5 -31 -92 United States Environmental Protection Agency Form Washington, DC 20460 2F Application for Permit to Discharge Storm Water i NPOES Discharges Associated with Industrial Activity Paperwork Reduction Act Notice Public reporting burden for this application is estimated to average 28.6 hours per application, including time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding the burden estimate, any other aspect of this collection of information or suggestions for improving this form, including suggestions which may increase or reduce this burden to: Chief, Information Policy Branch, PM -223, U.S. Environmental Protection Agency, 401 M SL, SW, Washington, DC 20460, or Director, Office of Information and Regulatory Affairs, 0H. w of Man22=tand BudrA Washington, DC 20503, 1. O utfall Locaition For each outWI list the latitude and Con itude of its location to the nearest 15 seconds and the name of the receiving water. A. Outfall Number (list) B. Latitude C. Longitude 0. Receiving Water name SW O01 H. improvements A. Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading or operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule tatters, stipulations, court orders, and grant or loan conditions. _ 1. IdentifIcatian of Conditions, Agreements, Eta 2. Affected Outfalls 3. Brief Description of Project d. Final Compliance Date number I source of diacha a a. req. b. pro]. B. You may attach additional shoots describing any additional water pollution (or other environmental projects which may affect your discharges) you now have under way or which you plan. Indicate whether each program is now under way or planned, and indicate your actual or planned schedules for construction. III. Site Drainage Ma Attach a site map showing topography (or indicating the outline of dralnage areas served by the outfall (s) covered in the application if a topographic map Is unavailable) depicting the facility including: each of its intake and discharge structures; the drainage area of each storm water outfall; paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for outdoor storage or disposal of significant materials, each existing structure control measure to reduce pollutants in storm water runoff, materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied; each of its hazardous waste treatment, storage or disposal units (including each are not required to have a RCRA permit which is used for accumulating hazardous waste under 40 CFR 262.34); each well where fluids from the facility are injected underground; springs, and other surface water bodies which receive storm water discharges from the facility. EPA Form 3510 -2F (Rev. 1 -92) Page 1 of 3 Continued on Page 2 Page 30 of 46 Analytical Laboratory r:nntinuPrt frnm the Frnnt IV. Narrative Description of Pollutant Sources A. For each outfall, provide an estimate of the area (include units) of impervious surfaces (including paved areas and building roofs) drained to the outfall, and an estimate of the total surface area drained by the outfall. Outfall Area of Impervious Surface Total Area Drained Outfall Area of Impervious Surface Total Area Drained Number (provide units) rovide units) Number Aprovide units) (provide units_ SW001 B. Provide narrative description of significant materials that are currently or in the past three years have been treated, stored or disposed a in a manner to allow exposure to storm water; method of treatment, storage, or disposal; past and present materials management practices employed to minimize contact by these materials with storm water runoff; materials loading and access areas; and the location, manner, and frequency in which pesticides, herbicides, soil conditioners, and fertilizers are applied. C. For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in storm water runoff; and a description of the treatment the storm water receives, including the schedule and type of maintenance for control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by dischar e. Outfall List Codes from Number Treatment Table 2F -1 SW001 V. Non Stormwater Discharges A. I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of nonstormwater discharges, and that all nonstormwater discharges from these outfall(s) are identified in either an accompanying Form 2C or Form 2E application for the outfall. Name of Official Title (type or print) Signature Date Signed B. provide a description of the method used the date of any testing, and the onsite drainage points that were directly observed during a test. VI. Significant Leaks or Spills Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three ears, including the apgroximate date and location of the spill or leak, and the type and amount of material released. EPA Form 3510 -2F (Rev. 1 -92) Page 2 of 3 Continued on Page 3 EPA ID Number (copy from Item I of Form 1) Continued from Page 2 Page 31 of 46 Analytical Laboratory Vli. Discharge Information A,B,C, & D: See instruction before proceeding. Complete one set of tables for each outfall. Annotate the outfall number in the space provided. Tables Vii -A, VII -B, and VII -C are included on separate sheets numbered VII -1 and VII -2. E. Potential discharges not covered by analysis - is any toxic pollutant listed in table 2F -2, 2F -3, or 2F -4, a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct? Yes (list all such pollutants below) ❑ No (go to Section IX) VIII. Biological Toxicity Testing Data Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? I ecI Yes (list all such pollutants below) ❑ No (go to Section IX) IX. Contact anal slis Information Were any of the analysis reported in item VII performed by a contact laboratory or consulting firm? ® Yes (list the name, address, and telephone number of and pollutants ❑ No (go to Section X) analyzed by, each such /aborato or firm below _ A. Name B. Address C. Area Code & Phone No. D. Pollutants Analyzed Pace Analytical Services, Inc 9800 Kincey Ave Suite 100 704 -875 -9092 Oil &Grease/ Huntersville, NC 28078 Organic Pace Analytical Services, Inc 2225 Riverside Dr 828 - 254 -7176 Asheville, NC 28804 Wet chemistry & metals X. Certificatil l certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel'properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. A. Name & Official Title (type or print) B. Area Code and Phone No. C. Signature D. Date Signed EPA Form 3510 -2F (Rev. 1 -92) Page 3 of 3 EPA ID Number (copy from Item I of Form 1) Page 32 of 46 Analytical Laboratory Form Approved. OMB No. 2040 -0086 Approval expires 5 -31 -92 VII. Discha a Information Continued from a e 3 of Form 2F) Part A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. Sea instructions for additional details. Maximum Values Average Values Number Pollutant include units r'nclude units Of And Grab Sample Grab Sample Storm CAS Number Taken During Flaw- welghted Taken During Flaw - weighted Events (if available) First 30 Composite First 30 Composite Sampler! Minutes Minutes Sources of Pollutants Oil & Grease < 5.0 mglL NIA 1 Biological Oxygen 110 mglL 1 Demand SODS Chemical Oxygen < 25,0 mg1L 1 Demand COD Total Suspended 29.3 mg1L 1 Solids SS Total 3.9 mglL 1 Nitr en Total 0.53 mglL 1 Phos horus PH Minlmurn — Maximum Minimum Maximum Part B - List each pollutant that Is limited In an effluent guideline which the fncillty is subject to or any Pori Ilan( listed in the facility's NPDES permit for its process wastewater (if the facility is operating under an existing NPDES permit). Complete one table for each outfall. See the instructions for additional details and re uirements. Maximum Values Average Values hfumWr Pollutant Include units finclu rie units ) Of And Storm Grab Sample Grab Sample CAS Number Taken During Flow-weighted Taken During Flow - weighted Events (Ifavailable) First 30 Composite First 30 Composite Sampler! Minutes Minutes Sources of Pollutants Bromide (e4�;59Ci7»9) Chlorine, Total residual Ammonia (as N) 1.7 mg1L i Chloride Color Fluorlde (16984 -48-8) Nitrate•Nitrlte (as N) 1.5 mglL 1 Radicadivity, alpha total Radioactivity, beta total Radioactivity, radium _ total Radioactivity, radium 226 total Sulfate (as SO4) 14808 -79.8 Sulfite (as SN 1426645 -3 Aluminum, Total 0.915 mg1L 1 7429 -90 -5 Barium, Total 0.0339 mg1L 1 7444 -39.3 Boron, Total (7440- 0.0705 mglL 1 42-8 Cobalt, Total (7440- <0.005 mglL 1 48.4 Iron, Total (7439 -89.6) 2.00 mgiL 1 Magnesium. Total 1.7 mg1L i 439 -95.4 Magnesium, Dissolved Molybdenum, Total 7439-98 - - Manganese, Total 0.0784 mglL 1 7d35 -96 -5) EPA Form 3510 -2F (Rev. 1 -92) Page VII -1 Continue on Reverse Page 33 of 46 Analytical Laboratory Tin, Total <0.005 mg /L 1 7440 -31 -5 Titanium, Total 0.0256 mg /L 1 7440 -32 -6 Antimony, Total 7440 -36 -0 _ Arsenic, Total 0.0054 mg /L 1 7440 -38 -2) Beryllium, Total 7440 -41 -T) Cadmium, Total 0.0013 mg /L 1 (7440 -43 -9) Chromium, Total <0.005 mg[L 1 7440-47 -3 Copper, Total 0.0684 mg /L 1 7440 -50 -8) Lead, Total 7439 -92 -1 Mercury, Total <0.200 ug /L 1 (7439 -97 -6 Nickel, Total 0.007 mg /L 1 7440 -02 -0 _ Selenium, Total 0.062 mg /L 1 7782 -49 -2) Silver, Total <0.005 mg /L 1 (7440 -22-4) Thallium, Total (7440 -28 -0) Zinc, Total 0.863 mg /L 1 (7440 -66 -6) EPA Form 3510 -2F (Rev. 1 -92) Page VII -I Continue on Reverse Page 34 of 46 Analytical Laboratory nntinued from the Front Part C- list each pollutant shown in Tables ZF -2, 21Fm3, and 2F-4 that you know or have reason to believe is present. Seethe instructions for additional detalls and LegutremeriM Comp one table for each outfail. Maxim um Values Average Values _ Number Pollutant include rmiLS include units Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow- weighted Taken luring Flow-welghted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Cyanide, Total 51 -12 -q Phenols, Total �;U10 mglL 1 1 Surfactants (MBAs) Total Dissolved Solids Total Organic Carbon Total Kjaldahi Nkr en TKN 2.4 mglt. 1 Fecal Cotiform 1.6 CFlll 10pmL 1 Part a - Provide data for the storm events which resulted in the maximum values for the flow wet hteJ - Invoslte sample. i . Date of Stomp Event 2'. Duration of Storm Event (in minutes) 3. Total rainfall Burin storm event g (in inches) 4. Number of hours between beginning of storm measured and end of previous measurable rain event 5• Total flow from rain event (gallons or specify units) 1 1 1 1 1 1- 7. - provide a dasciri icon of the method of flow measurement or astknate. EPA Form 3510 -2F (Rev. 1 -92) Page VII -2 Page 35 of 46 Analytical Laboratory EPA Form 3510 -2F (Rev. 1 -92) Page VII -2 Page 36 of 46 Analytical Laboratory Please print or type in the unshaded areas EPA ID Number (copy from item l of Form 1) Form Approved. OMB No. 2040 -0086 Approval expires 5 -31 -92 Forms 2F NPDES United States Environmental Protection Agency Washington, DC 20460 11 12 "O Application for Permit to Discharge Storm Water NY Discharges Associated with Industrial Activity Paperwork Reduction Act Notice Public reporting burden for this application is estimated to average 28.6 hours per application, including time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding the burden estimate, any other aspect of this collection of information or suggestions for improving this form, including suggestions which may increase or reduce this burden to: Chief, Information Policy Branch, PM -223, U.S. Environmental Protection Agency, 401 M St, SW, Washington, DC 20460, or Director, Office of Information and Regulatory Affairs, Off ice of MarWerrent and 6 at Wash' n, DC 205M I. Outfall Location For each outfall, list the latitude and Ian itude of its location to the nearest 15 seconds and the name of the receiving water. A. Outfall Number D_ Receiving Water trst B. Latitude C. Longitude flame SWO03 to meet any implementation schedule for the construction, upgrading or other environmental programs which may affect the discharges described conditions, administrative or enforcement orders, enforcement compliance - - li.Improvements A. Are you now required by any Federal. State. or local authority operation of wastewater treatment equipment or practices or any in this application? This includes, but is not limited to, permit scheduie letters st ulations court orders and grant or loan conditions. 1, identification of Conditions, Acireements, Etc,_ 2. Affected Outfalls 3. Brief Description of Pro ect 4. Final Compile ce rate number source of discharge a, req. b. proi. B. You may attach additional sheets describiing any additional water pollution (or other environmental projects which may affect your discharges) you now have under way or which you plan. Indicate whether each program is now under way or planned, and indicate your actual or planned schedules for construction. 111. Site Drainage Ma Attach a site map showing topography (or indicating the outline of drainage areas served by the outfall(s) covered in the application if a topographic map Is unavailable) depicting the facility including: each of its intake and discharge structures; the drainage area of each storm water outfall; paved areas and buildings within, the drainage area of each storm water outfall, each known past or present areas used for outdoor storage or disposal of significant materials, each existing structure control measure to reduce pollutants in storm water runoff, materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied; each of its hazardous waste treatment, storage or disposal units (including each are not required to have a RCRA permit which Is used for accumulating hazardous waste under 40 CFR 262.34); each well where fluids from the facility are injected underground; springs, and other surface water bodies which receive stone water dischar es from the facili . EPA Form 3510 -2F (Rev. 1 -92) Page 1 of 3 Continued on Page 2 Page 37 of 46 Analytical Laboratory rnM ➢nned F—m H­ IV. Narrative Description of Pollutant Sources A. For each outfall, provide an estimate of the area (include units) of impervious surfaces (including paved areas and building roofs) drained to the outfall, and an estimate of the total surface area drained by the outfall. Outfall Area of Impervious Surface Total Area Drained Outtail Area of Impervious Surface Total Area Drained Number (provide units rovide_ u_ nits ) Number (provide units) rovide uniks SWO03 B. Provide a narrative description of significant materials that are currently or in the past three years have been treated, stored or disposed in a manner to allow exposure to storm water; method of treatment, storage, or disposal; past and present materials management practices employed to minimize contact by these materials with storm water runoff; materials loading and access areas; and the location, manner, and frequency in which pesticides herbicides, soil conditioners and fertilizers are applied. _ C. For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in storm water runoff; and a description of the treatment the storm water receives, including the schedule and type of maintenance for control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge. Outfall List Codes from Number Treatment Table 2F -1 SWO03 V. Non Stormwater Discharges A. I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of nonstormwater discharges, and that all nonstormwater discharges from these outfall(s) are identified in either an accompanying Form 2C or Form 2E ap lication for the outfall. Name of Official Title (type or print) Signature Date Sigried B. provide a description of the method used, the date of any testing, and the onsite drainage points that were directly observed during a "test. VI. Significant Leaks or Spills--M... Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three ears, including the approximate date and location of the spill or leak, and the type and amount of material released. EPA Form 3510 -21F (Rev. 1 -92) Page 2 of 3 Continued on Page 3 Page 38 of 46 Analytical Laboratory EPA ID Number (copy from Item I of Form 1) Continued from Page 2 VII. Discharge Information A,B,C, & D: See instruction before proceeding. Complete one set of tables for each outfall. Annotate the outfall number in the space provided. Tables Vii -A, VII -B, and VII -C are included on separate sheets numbered VII -1 and VII -2. E. Potential discharges not covered by analysis - is any toxic pollutant listed in table 2F -2, 2F -3, or 2F -4, a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct? ❑ Yes (list all such pollutants below) ❑ No (go to Section DO VIII. Biological Toxicity Testing Data Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? ❑ Yes (list all such pollutants below) ❑ No (go to Section IX) IX. Contact analysis Information Were any of the analysis reported in item VII performed by a contact laboratory or consulting firm? ® Yes (list the name, address, and telephone number of, and pollutants ❑ No (go to Section ) analyzed by, each such laboratory or firm below) A. Name B. Address C. Area Code & Phone No. D. Pollutants Analyzed Pace Analytical Services, Inc 9800 Kincey Ave Suite 100 704 -875 -9092 Oil &Grease/ Huntersville, NC 28078 Organic Pace Analytical Services, Inc 2225 Riverside Dr 828 - 254 -7176 Asheville, NC 28804 Wet chemistry & metals X. Certification I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. A. Name & Official Title (type or print) I B. Area Code and Phone No. C. Signature D. Date Signed EPA Form 3510 -2F (Rev. 1 -92) Page 3 of 3 EPA ID Number (copy from Item 1 of Form 1) Page 39 of 46 Analytical Laboratory Form Approved. OMB No. 2040 -0086 Approval expires 5 -31 -92 VII. Discharge Information (Continued from pa e 3 of Form 2F Part A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each oulfall. See instructions far add [Lin nal details. Maximum Values Average Values Number Pollutant include, units) include units Of Grab Sample Grab Sample And Stamm CAS Number Taken [luring Row -weighted Takers During Flow-weighted Events (if available) First 30 Minutes Composite First 30 'Minutes Composite Sampled Sources of Pollutants Oil & Grease c 5.0 mgiL N/A 1 Biological Oxygen 72.9 mgiL 54.9 mg1L - 2 Demand BOD5 Chemical Oxygen 233 mgiL 58.0 mglL 2 Demand COD Total Suspended 151 mg1L 1 Solids SS Total 8.9 mgJL 2.28 mg1L 2 Nitrogen Total 1.5 mg1L 0.16 mgiL 2 Phosphorus PH I Minimum Maximum Minimum Maximum Part B - List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility"s NPDES permit for its process wastewater (if the facility is operating under an existing NPDES permit). Complete one table for each outfall. See the instructions for additional details_ and re uirements. Maximum Values Average Values Number Pollutant Lclude units Include units Of And Grab Sample Grab Sample Storm GAS Number Taken (Suring Flow- weighted Taken During Flowmweighted Events (if avaifakle) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Bromide (24959 -87 -9) Chlorine, Total residual _ Ammonia (as N) 0.80 mgiL 0.25 mg1L - 2 Chloride - -- Color Fluoride (15984 -48-8) Nitrate- Nitrite (as N) 1.2 mgiL 0.78 mglA 2 Radioactivity, alpha total Radioactivity, beta total Radioactivity, radium total Radioactivity. radium 226 total - Sulfate (as 804) 14808-79 8 Sulfite (as SO,) 14265 -45 -3 Aluminum, Total 0.753 mgiL 0.897 mgiL 2 (742930 -5 Barium, Total 4.11.5. mg/L 4.0222 mgiL 2 7440 -39-3 Boron. Total (7440- 0.072 mgiL <4.050 mgiL - 2 42-8 Cobalt, Total (7440- 0.005 mglL -0.005 mgiL 2 48-4 Iron. Total (7439 -89-6) 21.2 mgiL 0.0199 mgiL 2 - Magnesium. Total 9.57 mg /L 0.934 rnglL 2 7439 -93.4 Magnesium. Dissolved - Molybdenum, Total 7+139 -9t] -7 _ Manganese, Total 1.38 mgiL 0.0792 mg1L 2 439. -96 -5) EPA Form 3510 -2F (Rev. 1 -92) Page VII -I Continue on Reverse Page 40 of 46 Analytical Laboratory Tin, Total <0.005 mg /L <0.005 mg /L 2 7440 -31 -5) Titanium, Total 0.0299 mg /L 0.0403 mg /L 2 (7440 -32 -6) Antimony, Total 7440 -36 -0) Arsenic, Total 0.005 mg /L <0.005 mg /L 2 7440 -38 -2 Beryllium, Total 7440 -41 -7) Cadmium, Total <0.001 mg /L <0.001 mg /L 2 7440 -43 -9 Chromium, Total <0.005 mg/L <0.005 mg /L 2 7440 -47 -3) Copper, Total 0.0533 mg /L 0.0182 mg /L 2 (7440 -50 -8 Lead, Total 7439 -92 -1 Mercury, Total <0.200 ug /L <0.200 ug /L 2 7439 -97 -6) Nickel, Total 0.0068 mg /L <0.005 mg /L 2 7440 -02 -0) Selenium, Total <0.010 mg /L <0.010 mg /L 1 2 (778249 -2) Silver, Total <0.005 mg /L <0.005 mg /L 2 7440 -22 -4) Thallium, Total 7440 -28 -0) Zinc, Total 2.29 mg /L 0.758 mg /L 2 7440 -66-6) EPA Form 3510 -2F (Rev. 1 -92) Page VII -I Continue on Reverse Page 41 of 46 Analytical Laboratory Cnn+in norl from +ha Frnn+ Part C - List each pollutant shown in Tables 2F -2, 2F -3, and 2F -4 that you know or have reason to believe is present. See the instructions for additional details and requirements. Complete one table for each outfall. _ Pollutant And CAS Number (if available) Maximum Values include units) - Average Values (inrluda units Number Of Storm Events Sampled Sources of Pollutants Grab Sample Taken During First 30 Minutes Flow- weighted Composite _ Grab Sample Taken During First 30 Minutes Flow- weighted Composite Cyanide, Total 57 -12 -5) Phenols, Total 0.045 mg /L 1 Surfactants (MBAs) Total Dissolved Solids Total Organic Carbon Total Kjeldahl Nitro en KN 7.7 mglL 1.5 mg /L 2 Fecal Coliform 100 CFU /100 mL Part D - Provide data for the storm event (s) which resulted in the maximum values for the flow weighted com osite sample. 1. Date of Storm Event 2. Duration of Storm Event (in minutes) 3. Total rainfall during storm event (in inches) 4. Number of hours between beginning of storm measured and end of prevlous measurable rain event 5. Total flow from rain event (gallons or specify units) 7. Provide a description of the method of flow measurement or estimate. EPA Form 3510 -2F (Rev. 1 -92) Page VII -2 Page 42 of 46 Analytical Laboratory EPA Form 3510 -2F (Rev. 1 -92) Page VII -2 s: I MWA Page 43 of 46 Analytical Laboratory IY =ti y a � A 7; ° c pi ci c6 _, + a "n +1 cn ;,n aaa { rn `Q t ;rn �r ;(A T" 0 .p 0 T k4�41Y W.MA. ry,�r, � O d ft11N gay O :Cj Ig < Z r WdWm 77R }+ o iN 3 n m z TOC&I0 C"CaInws ~ Page 44 of 46 Analytical Labomtory Culppnlrf NkIF CY�tpYM i _ t 4� i �i 0 �G i� M 0 10 'z gg Z 22 in e0 w n d Cuce4 mpg !D eomyfela approDN�ia evtumrt� !e �l L � � � $ � C w: ;- � y+ ca Y S Y � N I to R O 4. ru C d i g7 m m'. w 'd" .w 'R ,f 53 � x Ilk � I D R 13 'r it a 5 o I Customer, important: please indicate desired turnaround `n J Bpd +J 25 I 'II fti v a7 O.Y • 0 p P A a 0 0 n m 0 M Z — — J✓ ! Tth}, TP, COO z }� ran G 1 .... \ �pw o a Alm I t..A•3j���c,a�v sw. �. V c k -On� ;1V) p o �cI. total Bru C r a O O ^ < Z In ptJ Rxdtum 776 m z a o Total 0contsinrrs i _ t 4� i �i 0 �G i� M 0 10 'z gg Z 22 in e0 Cnalw�air■ to ewnylexa +f+4roaHa a O Oyu -�r N d n T-9 R: m, � m I m'' I � 1 i et 14 1 I I Custome(. important: please indicate desired turnaround .6 V p O Analytical Laboratory - - - - -' .+�. >.. a m = �0 C N 0 N o r 9 a CA m3f C d D V O o < p 7 v � a s 5' 7 C 3 m m —11 9,1 ,. CKI m 1 Page 45 of 46 O Analytical Laboratory - - - - -' .+�. >.. G.lY'nx■ Wr.�r ean0al. CA m3f w s 5' 7 C 3 m m —11 9,1 ,. L....._ a v 1 O 11 1 O O CA m3f w s I 0 >v n m c as zii- IC) v ti 21 0 4 :a �'z 44 fit� Fecal Ceilferm OA4 Zfi :M e :M 4010E ^ $ f A a a I I : ^t Y v - Q taa G� �n cn z z$ y •1 m ti y v TNrl, TP, CO4 I it �i r'a 0 _ z F., A., C.. c4,c., s., Al. B., 9, 149. Mn, 71, C7, _n v in INF.rj ROM y ;a �! m A wrtat Bna ACI 0 1 { _ �N 0 I RadlYrn 72� $ C7 m Z Total x ConulnPrts aceAnalytical www..pacelabs.com t SAMPLE ACKNOWLEDGEMENT Page 46 of 46 Analytical Laboratory 9800 KinceyAve., Suite 100 Huntersvllle, NC 28078 (704)875 -9092 Samples Submitted By: Duke Energy Pace Project Manager: Kevin Herring Client Project ID: 08- JUN -0400 Phone 1(704)875 -9092 kevin.herring @pacelabs.com Client PO #: ISW01.0000000341 Pace Analytical Project ID: 9221945 Samples Received: June 23, 2008 Estimated Completion: July 08, 2008 Pace Analytical DateMme Customer Sample ID Lab ID Matrix Collected Method 28017343 9221945001 %vntcr 06/23108 08:30 200.7 MET ICP Aluminum, Arsenic, Barium, Boron, Cadmium, Chromium, Cobalt, Copper, Iron, Magnesium, Manganese, Nickel, Silver, Zinc, Titanium, Tin, Selenium 245 1 Mercury 2540D Total Suspended Solids 350 1 Ammonia 351.2 Total Kjeldaht Nitrogen 353.2 Nitrogen, NO2/NO3 pres. 365,1 Phosphorus, Total, 420.4 Phenolics, -Total 5210B DOD, LoW Level 5220D COD HEM, Oil and Grease , MBIO 9222D Fecal Coliform CHT ' 28017347 9221945002 wamr 06/23/08 08:40 200.7 MET ICP Aluminum, Arsenic, Barium, Boron, Cadmium, Chromium, Cobalt, Copper, Iron, Magnesium, Manganese, Nickel, Silver, Zinc, Titanium, Tin, Selenium 245.1 Mercury 2540D Total Suspended Solids 350.1 Ammonia 351.2 Total- Kjeldahl Nitrogen 353.2 Nitrogen, NO2/NO3 pres. 365.1 Phosphorus, Total 420.4 Phenolics, Total 5210E BOD, Low Level 5220D COD HEM, Oil and Grease MBIO 9222D Fecal Coliform CHT 28017348 9221945003 ww_.r 06123/08 08:40 5210B HOD, Low Level v Please contact your project manager if you recognize any discrepancy in this form or have any questions about your project. Thank you for choosing Pace Analytical Services, Inc. Page 1 of 1 OUTFALL SAMPLED SAMPLE COLLECTION DATE SAMPLE TYPE ANALYSES SW003 July 5, 2008 Composite EPA 200.7 EPA 245.1 EPA 350.1 EPA 351.2 EPA 353.2 EPA 365.1 SM 5220D Duke - {{� /Energy® y Rev 07 -09 -07 Analytical Laboratory 13339 Hagers Ferry Road Huntersville, NC 28078 -7929 McGuire Nuclear Complex — MG03A2 Phone: 704 - 875 -5245 Fax: 704 -875 -5038 Job Summary Report Job Number: 08JUL -0149 Project Name: Customer Name: Copy To: Customer Address: Riverbend Stormwater Brandy Starnes Steve Jones, Greg Phillips MG03A3 Lab Contact: Mary Ann Ogle Lab Contact Phone: 704 - 875 -5274 Report Authorized By: (Printed Name) MARY ANN OGLE Page 1 of 28 Analytical Laboratory Report Authorized By: (Signature) )ate: 101,1711--) if Data Package This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measufement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical Laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Reports (f applicable) Sub - contracted Laboratory Results Customer Specific Data Sheets, Reports & Documentation (if applicable) Customer Database Entries Test Case Narratives Chain of Custody (COQ Page 2 of 28 Analytical Laboratory Duke Analytical Labbratory /Energy® 13339 Halters Ferry Road Huntersville, NC 28078 -7929 Rev 07 -03 -07 McGuire Nuclear Complex — MG03A2 Phone: 704 - 875 -5245 Fax: 704 - 875 -5038 Job Summary Report Certification The Analytical Laboratory holds the following Certifications: New York State Department of Health Certification # 11717(NEL4C) North Carolina Department of Health & Human Services Certification # 37804 South Carolina (DHEC) Laboratory ID # 99005 North Carolina (DENR) Certification # 248 Analytical results listed in this report may not be certified by the authorities referenced above. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. The results meet all requirements of NELAC except where deviations are noted in this report. Data Flags Any analytical tests or individual analytes within a test flagged with an "X" or a "1" indicate a deviation from the method quality system or quality control requirement. Calculations All results are reported on a wet weight basis unless otherwise noted. Sample ID's & Descriptions: Collection Sample Sample ID Plant /Station Date Collected By Description 28018958 FOSSIL 7/05/2008 B STARNES RIVERBEND SWO03 - COMP 1 TOTAL SAMPLES i I Duke 1 I Energy® auva�.c r��w Analytical Laboratory 13339 Hagers Ferry Road Huntersville, NC 28078 -7929 McGuire Nuclear Complex — MG03A2 Phone: 704 - 875 -5245 Fax: 704 -875 -5038 Job Summary Report Validation of Analytical Data Package COC and .pdf report are in agreement with sample totals ' and analyses (compliance programs and procedures). ii) All results are less than the laboratory reporting limits. iii) All laboratory QA/QC requirements are acceptable. NPDES and TCLP results are below permit or regulatory iv) limits respectively. It iv) above is No, document below: Permit Variable Result I Limit Notes Page 3 of 28 Analytical Laboratory Yes F No ' Yes v No Yes` No Yes No Components of the Job Summary Report arranged in order V) stipulated on page one. h+ Yes 1"" No Indicate components included: fi Job Summary Report 170 Customer Specific Data Sheets, Reports & Documentation (if applicable) Analytical Laboratory Certificate of Analysis Customer Database Entries Analytical Laboratory QC Report (if applicable) f r Test Case Narratives f i Sub - contracted Laboratory Results rv— Chain of Custody vi) Notes and Additional Information This is a partial report for SW 003. The other reports for this outfall are 08 -JUL -0641 and 08 -JUN -0400. The following parameters contained quality control failures for matrix spike recovery, but the spike was not performed on this sample : COD,TKN and ammonia. The following parameters contained quality control failures for duplicate relative percent difference, the quality control was not performed on this sample: metals and ammonia. These quality control failures should be documented when reporting result, but these results are still considered valid. Mary Ann Ogle Duke Energy Analytical Lab NPDES Contact Office 704 - 875 -5274 Cell 704 - 280.7956 Page 4 of 28 Analytical Laboratory Pace Analytical Services, Inc. Pace Analytical Services, Inc. J aC�'%Analyticaar 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 Ui, 1 www.pacelebs.com Asheville, NC 26804 Huntersville, NC 28078 t (828)254 -7176 (704)8759092 July 28, 2008 Mr. Jay Perkins Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: 08 -JUL -0149 Pace Project No.: 9222864 Dear Mr. Perkins: Enclosed are the analytical results for sample(s) received by the laboratory on July 08, 2008. The results relate only to the samples included in this report. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All Microbiological analyses were performed at the laboratory where the samples were received. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring @pacelabs.com Project Manager Enclosures cc: Accounts Payable DPEHS, Duke Energy Carolinas, LLC REPORT OF LABORATORY ANALYSIS Page 1 of 15 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc., acMnaltical www pacelaft com Project: 08 -JUL -0149 Pace Project No.: 9222864 Charlotte Certification IDs Florida /NELAP Certification Number: E87627 Kansas Certification Number: E -10364 Louisiana /LELAP Certification Number: 04034 North Carolina Drinking Water Certification Number: 37706 North Carolina Wastewater Certification Number: 12 Asheville Certification IDs Florida /NELAP Certification Number: E87648 Louisiana /LELAP Certification Number: 03095 New Jersey Certification Number: NC011 North Carolina Drinking Water Certification Number: 37712 North Carolina Wastewater Certification Number: 40 North Carolina Bioassay Certification Number: 9 Eden Certification IDs North Carolina Drinking Water Certification Number: 37738 Virginia Drinking Water Certification Number: 00424 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 CERTIFICATIONS Page 5 of 28 Analytical Laboratory Pace Analytical Services, Inc. 9800 Klncey Ave. Suite 100 Huntersville, NC 28078 (704)875 -9092 North Carolina Field Services Certification Number: 5342 South Carolina Certification Number: 990060001 South Carolina Bioassay Certification Number. 990060003 Tennessee Certification Number: 04010 Virginia Certification Number. 00213 Pennsylvania Certification Number: 68 -03578 South Carolina Certification Number: 99030001 South Carolina Bioassay Certification Number: 99030002 Tennessee Certification Number: 2980 Virginia Certification Number. 00072 North Carolina Wastewater Certification Number: 633 REPORT OF LABORATORY ANALYSIS Page 2 of 15 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 28 Analytical Laboratory Pace Analytical Services, Inc. Pace Analytical Services, Inc, Analytical 2225 Riverside Dr. 9800 KinceyAve. Suite 100 U[[.. wwwpacelabacom Asheville, NC 28804 Huntersville, NC 28078 (628)2547176 (704)e75-9092 Project: 08 -JUL -0149 Pace Project No.: 9222864 Lab ID Sample ID 9222864001 28018958 SWO03 SAMPLE SUMMARY Matrix Date Collected Date Received Water 07/05/08 09:30 07/08/08 14:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 15 a MAnalybcal f w MCpawlabs.com 1 Project: 08 -JUL -0149 Pace Project No.: 9222884 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 SAMPLE ANALYTE COUNT Page 7 of 28 Analytical Laboratory Pace Analytical Services, Inc. 9800 Klncey Ave. Suite 100 Huntersville, NC 28078 (704)875.9092 Lab ID Sample ID Method Analysts Analytes Reported 9222864001 20018958SWO03 EPA 200.7 EWS 17 EPA 245.1 SHB 1 EPA 350.1 RAB 1 EPA351,2 JDA 1 EPA 353.2 JDA 1 EPA 365.1 SER 1 SM 5220D SAJ 1 REPORT OF LABORATORY ANALYSIS Page 4 of 15 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 28 Analytical Laboratory ® Pace Analytical Services, Inc. Pace Analytical Services, Inc. acemalxica! 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 www.pece /ebacam Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)8759092 ANALYTICAL RESULTS Project: 08 -JUL -0149 Pace Project No.: 9222864 Sample: 28018958 SWO03 Lab ID: 9222864001 Collected: 07/05/08 09:30 Received: 07/08/08 14:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Aluminum 897 ug /L 100 25.0 1 07/14/08 11:23 07118/08 01:29 7429 -90 -5 Arsenic ND ug /L 5.0 2.7 1 07/14/08 11:23 07/18/08 01:29 7440 -38 -2 Barium 22.2 ug /L 5.0 0.20 1 07/14108 11:23 07/18/08 01:29 7440 -39 -3 Boron ND ug /L 50.0 4.7 1 07/14/08 11:23 07/18/08 01:29 7440 -42 -8 Cadmium ND ug /L 1.0 0.50 1 07/14/08 11:23 07/18108 01:29 7440 -43 -9 Chromium ND ug /L 5.0 0.40 1 07/14/08 11:23 07/18/08 01:29 7440 -47 -3 Cobalt ND ug /L 5.0 0.60 1 07/14/08 11:23 07/18/08 01:29 7440 -48 -4 Copper 18.2 ug /L 5.0 0.30 1 07/14/08 11:23 07118/08 01:29 7440 -50 -8 Iron 999 ug /L 50.0 14.0 1 07/14108 11:23 07/18/08 01:29 7439 -89 -6 Magnesium 934 ug /L 100 3.0 1 07/14/08 11:23 07/18/08 01:29 7439 -95-4 Manganese 79.2 ug /L 5.0 0.30 1 07/14108 11:23 07/18/08 01:29 7439 -96 -5 Nickel ND ug /L 5.0 1.7 1 07/14/08 11:23 07/18/08 01:29 7440 -02 -0 Selenium ND ug /L 10.0 3.8 1 07/14/08 11:23 07/18/08 01:29 7782 -49 -2 Silver ND ug /L 5.0 0.10 1 07/14/08 11 :23 07/18108 01:29 7440 -22 -4 Tin ND ug /L 5.0 1.8 1 07/14/08 11:23 07/18/08 01:29 7440 -31 -5 Titanium 40.3 ug /L 5.0 0.10 1 07/14108 11:23 07/18108 01:29 7440 -32-6 Zinc 758 ug /L 10.0 0.40 1 07/14/08 11:23 07/18/08 01:29 7440 -66 -6 245.1 Mercury Analytical Method: EPA 245.1 Preparation Method: EPA 245.1 Mercury ND ug /L 0.20 0.20 t 07/09/08 12:15 07/09/08 15:47 7439 -97 -6 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia 0.25 mg /L 0.10 0.10 I 07/25/08 18:07 7764 -41 -7 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Nitrogen, Kjeldahl, Total 1.5 mg /L 0.50 0.50 1 07/19/08 11:54 7727 -37 -9 353.2 Nitrogen, NO2/NO3 pros. Analytical Method: EPA 353.2 Nitrogen, NO2 plus NO3 0.78 mg /L 0.10 0.10 1 07/27108 13:46 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Phosphorus 0.16 mg /L 0.10 0.10 1 07/14/08 00:41 7723 -14 -0 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 58.0 mg /L 250 25.0 1 07/11/08 21:45 Date: 07/28/2008 04:07 PM REPORT OF LABORATORY ANALYSIS Page 5 of 15 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc,. 'C7e eAnalytical { _ www.eacelabs.com f Project: 08 -JUL -0149 Pace Analytical Services, Inc, 2226 Riverside Dr. Asheville, NC 28804 (828)254 -7176 QUALITY CONTROL DATA Pace Project No.: 9222864 QC Batch: MERP /1575 Analysis Method: EPA 245.1 QC Batch Method: EPA 245.1 Analysis Description: 245.1 Mercury Associated Lab Samples: 9222864001 Page 9 of 28 Analytical Laboratory Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 METHOD BLANK: 137270 137272 9222860001 , Spike MS Units Result Cone. Result ug /L ND 2.5 1.9 MS % Rec 77 % Rec Limits Qualifiers 70 -130 Associated Lab Samples: 9222864001 Blank Reporting Parameter Units Result Limit Qualifiers Mercury ug /L ug /L ND ND 0 ND 0.20 Date: 07/28/2008 04:07 PM REPORT OF LABORATORY ANALYSIS LABORATORY CONTROL SAMPLE: 137271 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Mercury ug /L 2.5 2.6 105 85 -115 MATRIX SPIKE SAMPLE: Parameter Mercury 137272 9222860001 , Spike MS Units Result Cone. Result ug /L ND 2.5 1.9 MS % Rec 77 % Rec Limits Qualifiers 70 -130 SAMPLE DUPLICATE: 137273 9222860002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Mercury ug /L ND ND 0 20 Date: 07/28/2008 04:07 PM REPORT OF LABORATORY ANALYSIS Page 6 of 15 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. at^ier Anali &a � www.pacalabs.com Project: 08 -JUL -0149 Pace Project No.: 9222864 QC Batch: WETA13047 QC Batch Method: SM 5220D Associated Lab Samples: 9222864001 METHOD BLANK: 138813 Associated Lab Samples: 9222864001 Parameter Units Chemical Oxygen Demand mg /L LABORATORY CONTROL SAMPLE: 138814 Parameter Units Chemical Oxygen Demand mg /L MATRIX SPIKE SAMPLE: Parameter Chemical Oxygen Demand MATRIX SPIKE SAMPLE: Parameter Chemical Oxygen Demand SAMPLE DUPLICATE: 138816 Parameter Chemical Oxygen Demand Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 QUALITY CONTROL DATA Analysis Method: SM 5220D Analysis Description: 5220D COD Blank Reporting Result Limit Qualifiers NO 25.0 Page 10 of 28 Analytical Laboratory Pace Analytical Services, Inc. 9800 KlnceyAve. Suite 100 Huntersvilla, NC 28078 (704)875 -9092 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 750 792 106 90 -110 138815 9222112014 Spike MS MS % Rec Units Result Cone. Result % Rec Limits Qualifiers mg /L ND 750 NO .3 75 -125 MO , 138818 9222640001 Spike MS MS % Rec Units Result Cone. Result % Rec Limits Qualifiers mg /L 122 750 ` 113 -1 — 75-125 MO ' 9222770001 Dup Max Units Result Result RPD RPD Qualtfiers mg /L 58.1 78.6 30 20 R1 SAMPLE DUPLICATE: 138817 9222628001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Chemical Oxygen Demand mg /L •158 438 d 20 Date: 07/28/2008 04:07 PM REPORT OF LABORATORY ANALYSIS Page 7 of 15 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. n���i: Page 11 of 28 Analytical Laboratory ® Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceArralytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 www.pace/e6scom Asheville, NC 28804 Huntersville, NC 28078 v (828)254 -7176 (704)875 -9092 Project: 08 -JUL -0149 Pace Project No.: 9222864 QC Batch: WETA/3059 Reporting QC Batch Method: EPA 365.1 Associated Lab Samples: 9222864001 Limit METHOD BLANK: 139287 Associated Lab Samples: 9222864001 ND Parameter Units Phosphorus mg /L Spike LCS LABORATORY CONTROL SAMPLE: 139288 Parameter Units Phosphorus mg /L Qualifiers MATRIX SPIKE SAMPLE: 139289 Parameter 110 Units Phosphorus mg /L 9222867002 MATRIX SPIKE SAMPLE: 139291 Parameter % Rec Units Phosphorus mg /L Result SAMPLE DUPLICATE: 139290 Limits Qualifiers Parameter 1 Units Phosphorus mg /L SAMPLE DUPLICATE: 139292 Parameter Units Phosphorus mg /L QUALITY CONTROL DATA Analysis Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total Blank Reporting Result Limit Qualifiers ND 0.10 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 1 1.1 110 90 -110 9222867002 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers 4.7 1 5.4 75 90 -110 MO r aQ \. 9222864001 Spike MS MS % Rec 10\ Result Conc. Result % Rec Limits Qualifiers 0.16 1 1.2 105 90 -110 9223151002 Dup Max Result Result RPD RPD Qualifiers 1.4 1.3 5 20 9222866002 Dup Max Result Result RPD RPD Qualifiers .......... 0.72 0.73 :3 20 Date: 07/28/2008 04:07 PM REPORT OF LABORATORY ANALYSIS Page 8 of 15 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. �-aceAnalytical' wwwpacelabs.com f± Project: 08 -JUL -0149 Pace Project No.: 9222864 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7178 QUALITY CONTROL DATA QC Batch: MPRP 12651 Analysis Method: EPA 200.7 QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET Associated Lab Samples: 9222864001 METHOD BLANK: 139450 Associated Lab Samples: 9222864001 Parameter Aluminum Arsenic Barium Boron Cadmium Chromium Cobalt Copper I ron Magnesium Manganese Nickel Selenium Silver Tin Titanium Zinc ug /L ug /L ug /L ug /L ug /L ug /L ug /L ug /L ug /L ug /L ug /L ug /L ug /L ug /L ug /L ug /L ug /L Units LABORATORY CONTROL SAMPLE: 139451 Parameter Units Aluminum ug /L Arsenic ug /L Barium ug /L Boron ug /L Cadmium ug /L Chromium ug /L Cobalt ug /L Copper ug /L Iron ug /L Magnesium ug /L Manganese ug /L Nickel ug /L Selenium ug /L Silver ug /L Tin ug /L Titanium ug /L Zinc ug /L Blank Result ND ND ND ND ND ND ND NO ND ND ND ND NO ND ND ND ND Reporting Limit 100 5.0 5.0 50.0 1.0 5.0 5.0 5.0 50.0 100 5.0 5.0 10.0 5.0 5.0 5.0 10.0 Qualifiers Spike Conc. LCS Result LCS % Rec % Rec Limits 5000 4860 97 85 -115 500 508 102 85 -115 500 494 99 85 -115 500 493 99 85 -115 500 511 102 85 -115 500 516 103 85 -115 500 501 100 85 -115 500 491 98 85 -115 5000 5060 101 85 -115 5000 5020 100 85 -115 500 513 103 85 -115 500 512 102 85 -115 500 495 99 85 -115 250 253 101 85 -115 500 519 104 85 -115 500 503 101 85 -115 500 508 102 85 -115 Page 12 of 28 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Date: 07/28/2008 04:07 PM REPORT OF LABORATORY ANALYSIS Page 9 of 15 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. meld Page 13 of 28 Analytical Laboratory It Pace Analytical Services, Inc. Pace Analytical Services, Inc. 9!+©Analytical 2225 Riverside Dr. 9800 KinceyAve. Suite 100 UC.G 1 fRp cala�vrowm Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)875 -9092 QUALITY CONTROL DATA Project: 08 -JUL -0149 Pace Project No.: 9222864 MATRIX SPIKE SAMPLE: 139452 9222818001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Aluminum ug /L 196 5000 4930 95 70 -130 Arsenic ug /L NO 500 494 98 70 -130 Barium ug /L NO 500 415 82 70 -130 Boron ug /L 2300 500 2790 98 70 -130 Cadmium ug /L ND 500 463 93 70 -130 Chromium ug /L NO 500 465 93 70 -130 Cobalt ug /L NO 500 438 88 70 -130 Copper ug /L NO 500 445 89 70 -130 Iron ug /L 214 5000 4680 89 70 -130 Magnesium ug /L 862 5000 5170 86 70 -130 Manganese ug /L ND 500 454 91 70 -130 Nickel ug /L ND 500 452 90 70 -130 Selenium ug /L NO 500 478 95 70 -130 Silver ug /L NO 250 233 93 70 -130 Tin ug /L NO 500 466 93 70 -130 Titanium ug /L NO 500 455 90 70 -130 Zinc ug /L NO 500 487 97 70 -130 SAMPLE DUPLICATE: 139453 9222819001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Aluminum ug /L 368 346 6 20 Arsenic ug /L NO 3047 .6 20 Barium ug /L 23.8 20.7 14 20 Boron ug /L /L 723 ND 713 NO 1 76 20 20 R3 4 Cadmium ug 55 1p Chromium ug /L 9.0 9.2 2 20 ,0111 Cobalt ug /L ND NO 11 20 Copper ug /L 15.6 15.5 .6 20 Iron ug /L 662 631 5 20 Magnesium ug /L 1640 1510 8 20 Manganese ug /L 97.6 48.6 67 20 R2 Nickel ug /L NO 4J 6 20 Selenium ug /L NO NO 200 20 R3 Silver ug /L NO NO 117 20 R3 Tin ug /L NO NO 183 20 R3 Titanium ug /L 15.5 14.7 5 20 Zinc ug /L 160 163 2 20 Date: 07/28/2008 04:07 PM REPORT OF LABORATORY ANALYSIS Page 10 of 15 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 20a"�AnalXicaie www.pacelabacom Project: 08 -JUL -0149 Pace Project No.: 9222864 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7178 QUALITY CONTROL DATA QC Batch: WETA13105 Analysis Method: EPA 351.2 QC Batch Method: EPA 351.2 Analysis Description: 351.2 TKN Associated Lab Samples: 9222864001 METHOD BLANK: 142058 Associated Lab Samples: 9222864001 Blank Reporting Parameter Uniis Result Limit Qualifiers Nitrogen, Kjeldahl, Total mg /L ND 0.50 Page 14 of 28 Analytical Laboratory Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875 -9092 LABORATORY CONTROL SAMPLE: 142059 Spike !.CS LCS k Rec Parameter Units Cone. Resull A Pd.- I_1111it", Qualifiers Nitrogen, Kjeldahl, Total mg /L 5 ;> t t p 90 -110 MATRIX SPIKE SAMPLE: 142060 9223043011 Spike MS MS % Rec Parameter Units Result Cone. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg /L 0.96 5 2.5 30 90 -110 MO MATRIX SPIKE SAMPLE: 142062 9223199004 Spike MS MS % Rec Parameter Units Result Cone. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg /L 19.0 5 28.8 19B 90 -110 MO SAMPLE DUPLICATE: 142061 9222763001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, Kjeldahl, Total mg /L 14.5 1G.6 14 20 SAMPLE DUPLICATE: 142063 9222884003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, Kjeldahl, Total mg /L 0.57 ND 30 20 Date: 07/28/2008 04:07 PM REPORT OF LABORATORY ANALYSIS Page 11 of 15 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. 1 eli�`; --.PaceAna1Xica1 www.pacetabs.com Project: 08 -JUL -0149 Pace Project No.: 9222864 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 QUALITY CONTROL DATA QC Batch: WETA/3146 Analysis Method: EPA 350.1 QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia Associated Lab Samples: 9222864001 METHOD BLANK: 144936 Associated Lab Samples: 9222864001 Blank Reporting Parameter Units Result Limit Qualifiers Nitrogen, Ammonia mg /L ND 0.10 Page 15 of 28 Analytical Laboratory Pace Analytical Services, Inc. 9600 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875 -9092 LABORATORY CONTROL SAMPLE: 144937 9223591002 Dup Max Parameter Units Spike LCS Result RPD LCS % Rec ND Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg /L 5 5.5 109 90 -110 RPD Qualifiers Nitrogen, Ammonia mg /L NO ND 183 20 R1 MATRIX SPIKE SAMPLE: 144938 9222864001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers _ m Nitrogen, Ammonia mg /L 0.25 5 5,7 109 90 -110 MATRIX SPIKE SAMPLE: 144940 9223554002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg /L 16.8 5 22.5 113 90 -110 MO SAMPLE DUPLICATE: 144939 9223591002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, Ammonia mg /L ND ND 0 20 SAMPLE DUPLICATE: 144941 9223568001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, Ammonia mg /L NO ND 183 20 R1 Date: 07/28/2008 04:07 PM REPORT OF LABORATORY ANALYSIS Page 12 of 15 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. �acoAnalytical www,pacelabs.com Project: 08 -JUL -0149 Pace Project No.: 9222864 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 QUALITY CONTROL DATA QC Batch: WETA/3155 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, preserved Associated Lab Samples: 9222864001 Page 16 of 28 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)8759092 METHOD BLANK: 145132 Associated Lab Samples: 9222864001 Blank Reporting Parameter Units Result Limit Qualifiers Nitrogen, NO2 plus NO3 mg /L ND 0.10 T LABORATORY CONTROL SAMPLE: 145133 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, NO2 plus NO3 mg /L 5 4.9 97 90 -110 MATRIX SPIKE SAMPLE: 145134 9223154002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, NO2 plus NO3 mg /L 23.4 5 28.4 102 75 -125 MATRIX SPIKE SAMPLE: 145136 9223870009 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, NO2 plus NO3 mg /L ND 5 4.6 92 75 -125 SAMPLE DUPLICATE: 145135 Parameter Nitrogen, NO2 plus NO3 SAMPLE DUPLICATE: 145137 Parameter Nitrogen, NO2 plus NO3 i Date: 07128/2008 04:07 PM 9222864001 Dup Max Units Result Result RPD RPD Qualifiers mg /L 0.78 0.79 1 20 9223870010 Dup Max Units Result Result RPD RPD Qualifiers mg /L ND NO 0 20 REPORT OF LABORATORY ANALYSIS Page 13 of 15 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. e Page 17 of 28 Analytical Laboratory ® Pace Analytical Services, Inc. Pace Analytical Services, Inc. . a ce MaIXical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 / - 7wwwpacelabsxom Asheville, NC 28804 Huntersville, NC 26078 +r (828)254 -7176 (704)875-9092 QUALIFIERS Project: 08 -JUL -0149 Pace Project No.: 9222864 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. S - Surrogate 1,2- Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes. ANALYTE QUALIFIERS Mo Matrix spike recovery was outside laboratory control limits. R1 RPD value was outside control limits. R2 RPD value was outside control limits due to matrix interference R3 RPD value was outside control limits due to uncertainty of values at or near the PRL. Date: 07/28/2008 04:07 PM REPORT OF LABORATORY ANALYSIS Page 14 of 15 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. AceAnalytical 1 www.pacelabs.com I I Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 08 -JUL -0149 Analytical Method Pace Project No.: 9222864 EPA 245.1 SM 5220D WETA13047 Lab ID Sample ID 9222864001 28018958 SWO03 9222864001 28018958 SWO03 9222864001 28018958 SWO03 9222864001 28018958 SWO03 9222864001 28018958 SWO03 9222864001 28018958 SWO03 9222864001 28018958 SWO03 Page 18 of 28 Analytical Laboratory Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875 -9092 QC Batch Method QC Batch Analytical Method EPA 245.1 MERP /1575 EPA 245.1 SM 5220D WETA13047 EPA 365.1 WETA/3059 EPA 200.7 MPRP /2651 EPA 200.7 EPA 351.2 WETA/3105 EPA 350.1 WETA/3146 EPA 353.2 WETA/3155 Analytical Batch MERC /1576 ICP/2522 Date: 07/28/2008 04:07 PM REPORT OF LABORATORY ANALYSIS Page 15 of 15 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. aS.RifwRLi Page 19 of 28 Analytical Laboratory Vrr,�,• • � r • r r Client Name: , �,(/�9 &0&r Project #• Courier: ❑ Fed Ex ❑ UPS ❑ USPS ❑ C' nt ❑ Commercial 211/pace Other PIOl]ei3teC( �, Custody Seal on Cooler /Box Present: EYyes ❑ no als intact: [yes ❑ no ��:'rw.�n;�c,a• �, I�tr7j NtTI'. �, / Packing Material: ❑ Bubble Wrap ❑Bubble Bags None ❑Clther Thermometer Used T060 Type of tce V�! Blue None Samples on ice, cooling process has begun Cooler Temperature Biological Tissue is Frozen: Yes No NIA Date and Initia o p xa inin 9 contents: O Temp should be above freezing to 6 °C Comments: Chain of Custody Present: CAX ONO ❑N /A 1. Chain of Custody Filled Out: ONO ❑N /A 2. Chain of Custody Relinquished: 92 ONO ON/A 3, Sampler Name & Signature on COG: Y s ONO ON /A 4• Samples Arrived within Hold Time: IVYX ONO ONIA 5. Short Hold Time Analysis <72hr): Yes 0 N ON /A 6, Rush Turn Around Time Requested: ❑Y s 1140 ❑N /A 7. Sufficient Volume: Y s ONO ❑N /A 8, Correct Containers Used: s 0 N NIA 9. -Pace Containers Used: Y o• ON/A Containers Intact: a Yes ONO ONY 10.. Filtered volume received for Dissolved tests ❑Y s ONo N/A 11. Sample Labels match COC: L,Yles 0N0 ON /A 12. - Includes date /time /ID /Analysis Matrix: W All containers needing preservation have been checked. ONO ❑N /A 13. All containers needing preservation are found to be in Yes ONO ❑N /A compliance with EPA recommeridation. exceptions: VOA, coliform, TOC, O&G, WI -DRO (water) OY ONo Inifial when completed Samples checked for dechlodnation:' Yes ONO ❑N 14. IHeadspace in VOA Vials ( >6mm): ❑Yes ONo N/ e 15. Trip Blank Present: ❑Yes ONo M41A F3. Trip Blank Custody Seals Present ❑Yes ❑No /A Pace Trip Blank Lot # (if purchased): N/A Client Notification/ Resolution: Person Contacted: Comments/ Resolution: Project Manager Review: Date/Time, Field Data Required? Y / N / N/A Date: 13, Ity Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Cerlificalinn Office 11 e oul of hold innnrrPH nrr cPrvativra Alit of tomn in—r— v Page 20 of 28 Analytical Laboratory Page 21 of 28 Analytical Laboratory Please print or type in the unshaded areas I EPA ID Number (copy from item I of Form 1) Form Approved. OMB No. 2040 -0086 I Approval expires 5 -31 -92 ��� 2F� NPDES United States Environmental Proterction Agency Washington, DC 20460 Application for Permit to Discharge Storm Water Dischar es Associated with Industrial Activity Paperwork Reduction Act Notice Public reporting burden for this application is estimated to average 28.6 hours per application, including time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding the burden estimate, any other aspect of this collection of information or suggestions fur improving this form, including suggestions which may increase or reduce this burden to: Chief, Information Policy Branch, PM -223, U.S. Environmental Protection Agency, 401 M St, SW, Washington, DC 20460, or Director, Oltioe of Information and Regulatory Affairs. Office of M nt and Washington, DC 2053 I. Outfall Location For each outtall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A. Outfall Number 1Fstj B. Latitude C. Longitude D; Receiving Water name S W O03 H.Improvements A. Are you now required operation of wastewater in this application? This schedule letters, sti Motions; by any Federal. State, or local authority to meet any implementation schedule for the construction, upgrading or treatment equipment or practices or any other environmental programs which may affect the discharges described includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance court orders, and grantor loan conditions. 1. Identification of Conditions, A reements, Etc, 2. Affected Outfalls 3. Brief Description of Pro ect 4. Final Com liance Date number source ofdischar a a. req. b• pro . B. You may attach additional sheets describing any additional water pollution (or other environmental projects which may affect your discharges) you now have under way or which you plan. Indicate whether each program is now under way or planned, and indicate your actual or planned schedules for construction. M. Site Drainage Map Attach a site map showing topography (or indicating the outline of drainage areas served by the duttail(s) covered in the application if a topographic map Is unavailable) depicting the facility including: each of its intake and discharge structures; the drainage area of each storm water outfall; paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for outdoor storage or disposal of significant materials, each existing structure control measure to reduce pollutants in storm water runoff, materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied; each of its hazardous waste treatment, storage or disposal units (including each are not required to have a RCRA permit which is°used for accumulating hazardous waste under 40 CFR 262.34); each well where fluids from the facility are injected underground; springs, and other surface water bodies which receive storm water discharges from the facitity. EPA Form 3510 -2F (Rev. 1 -92) Page 1 of 3 Continued on Page 2 Page 22 of 28 Analytical Laboratory Continued from the Front rv. Narrative veucri ti:en or rvlwutanx Sources A. For each outfall, provide an estimate of the area (include units) of impervious surfaces (including paved areas and building roofs) drained to the outfall, and an estimate of the total surface area drained by the outfall. Outfall Area of Impervious Surface Total Area Drained Outfall Area of Impervious Surface Total Area Drained Number provide units) provide units) Number provide units) (provide units) SWO03 B Provide a narrative description of significant materials that are currently or in the past three years have been treated, stored or disposed in a manner to allow exposure to storm water; method of treatment, storage, or disposal; past and present materials management practices employed to minimize contact by these materials with storm water runoff; materials loading and access areas; and the location, manner. and frequency in which pesticides. herbicides. soil conditioners, and fertilizers are applied. _ - -- ..... ....... _ C For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in storm water runoff; and a description of the treatment the storm water receives, including the schedule and type of maintenance for control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge. Outfaii List Codes from Number Treatment Table 217-1 S WO03 V. Ton Stormwater Dinharges A. I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of nonstormwater discharges, and that all nonstomtwater discharges from these outfall(s) are identified in either an accompanying Form 2C or Form 2E a plicadon for the outfall. Name of Official Title (type or print) Signature Date Signed B. provide a description of the method used, the date of any testing. and the onsite drainage points that were directly observed during a test. Vl. Significant Leans or Spills Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three ears, including the approximate date and location of the spill or leak, and the type and amount of material released. EPA Form 3510 -2F (Rev. 1 -92) Page 2 of 3 Continued on Page 3 EPA ID Number (copy from Item 1 of Form 1) Continued from Page 2 Page 23 of 28 Analytical Laboratory VII. Discharge Information A,B,C, & D: See instruction before proceeding. Complete one set of tables for each outfall. Annotate the outfall number in the space provided. T_ ables Vii-A, VII -B, and VII -C are included on separate sheets numbered VII -1 and VII -2. E. Potential discharges not covered by analysis - is any toxic pollutant listed in table 2F -2, 2F -3, or 2F -4, a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct? ❑ Yes (list all such pollutants below) ❑ No (go to Section /X) Vlll. Biological Toxicity Testing Data Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? Yes (list all such pollutants below) ❑ No (go to Section IX) IX. Contact analysis Information Were any of the analysis reported in item VII performed by a contact laboratory or consulting firm? ® Yes (list the name, address, and telephone number of, and pollutants ❑ No (go to Section X) anal zed b ,each such laboratory or firm below) A. Name B. Address C. Area Code & Phone No. D. Pollutants Analyzed Pace Analytical Services, Inc 9800 Kincey Ave Suite 100 704 - 875 -9092 Oil &Grease) Huntersville, NC 28078 Organic Pace Analytical Services, Inc 2225 Riverside Dr 828- 254 -7176 Asheville, NC 28804 Wet chemistry & metals X. Certification I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including theoossibility of fine and imprisonment for knowing violations. A. Name & Official Title (type or print) B. Area Code and Phone No. C. Signature D. Date Signed EPA Form 3510 -2F (Rev. 1 -92) Page 3 of EPA ID Number (copy from Item /of Form 1) Page 24 of 28 Analytical Laboratory Form Approved. OMB No. 2040 -0086 Approval expires 5 -31 -92 VII. Dischar a Information Continued from page 3 of Form 2F Part A - YOU must provide the resulis of at wait one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. Maximum Values Average Values Number Pollutant lrrdltde units irutlude vrrits Or And Grab Sample Grab Sample Storm CAS Number Taken During_ Flow - weighted Taken During Raw- welghted Events . (lf available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Oil & Grease NIA Biological Oxygen Demand BOD5 Chemical "gen 58.0 rra & 1 Demand C8Q) Total Suspended Solids TSS Total 2.28 mgR 1 Nitrogen Total 0.16 mglt. 1 Phosphorus pH Minimum I ,Maximum Minimum Maximum Part B - List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES permit for its process wastewater (if the facility is operating under an existing NPDES permit). Complete one table for each outfall. Seethe instructlons for additional details and n3 uirements. Mauirnum Values Average Values Number Pollutant rinclu da unr'ts ir2cJude units) Of Grab Sample Grab Sample And Storm GAS Number Takers During Flow- weighted Taken During Flow - weighted Events (lf available) First 30 Composite First 30 Composite Sampled - Minutes Minutes Sourcas of Pollutants Bromide (24959.67 -9) Chlorine, Total residual Ammonia (as N) 0.25 mglL i Chloride Color Fluoride (16984 -48 -5) Nitrate. Nitrite (as N) 0.78 mgIl 1 Radloaciivity, alpha total Radioactivity, Meta total Radloactivlty, radium total Radioactivity, radium 226 total Sulfate (as SO4 _ 14808 -79.8 Sulfite (as SOz) 14265 -45-3 Aluminum, Total 0,897 mg1L 1 17429-'90-5) Barium, Total 0.0222 mglL 1 7440-39 -3 Boron, Total (7440- _ <0.050 mglL 1 42 -8 Cobalt, Total (7440- 40.005 mglL 1 48-4 Iran, Total (743J- ") 0.999 mgM. 1 Magnesium, Total 0,934 mgfL 1 7439.95 -4 Magnesium, Dissolved Molybdenum, Total 7439-98 - Manganese, Total 0.0792 mglL 1 (7439 -96 -5 ) _ EPA Form 3510 -2F (Rev. 1 -92) Page VII -I Continue on Reverse Page 25 of 28 Analytical Laboratory Tin, Total <0.005 mg /L 1 (7440 -31 -5) Titanium, Total 0.0403 mg /L 1 (7440 -32 -6) Antimony, Total (7440 -36 -0) Arsenic, Total <0.005 mg /L 1 (7440 -38 -2) Beryllium, Total (7440 -41 -7) Cadmium, Total <0.001 mg /L 1 7440 -43 -9) Chromium, Total <0,005 mg /L 1 7440 -47 -3 Copper, Total 0.0182 mg /L 1 7440 -50 -8) Lead, Total I 7439 -92 -1) Mercury, Total <0.200 ug /L 1 7439 -97-6) Nickel, Total <0.005 mg /L 1 7440 -02 -0 Selenium, Total <0.010 mg /L 1 7782 -49 -2 Silver, Total <0.005 mg /L 7440 -22 -4 Thallium, Total 7440-28 -0) Zinc, Total 0.758 mg /L i (7440 -66 -6) I EPA Form 3510 -21F (Rev. 1 -92) Page VII -1 Continue on Reverse Page 26 of 28 Analytical Laboratory n^nel .A q fr fhn 9MM - Part C - List each pollutant shown in Tables 2F -2. 2F -3, and 2F-4 that you know or have reason to believe is present. See the instructions for additional details and requirements. Cam lets one table for each outfall. Pollutant And CAS Number Of available) Maximum Values incl[+de units Average Values (Include unifs) Number Of Storm Events Sampled Sources of Pollutants Grab Sample Taken During First 30 Minutes Flow-weighted Composite Crab Sample Taken During First 30 Minutes Flow - weighted Composite Cyantde, Total X57 -125) 'Phenols, Total Surfactants (MBAs) Total Dissolved Solids Total Organic Carbon Total Netdahl Nitrogen N 1.5 mgiL $ Part t) - Provide data for the storm events which resulted in the maximum values for the flow weighted composite sample. t. (Sate of Storm Event 2. Duration of Storm Event (in Mintries) 3. Total rainfall during storm event (in inches) 4. Number of hours between beginning of storm measured and end of previous measurable rain event Total flow from rain event (gallons or specify units) 7- Provide a description of the method of Flow measurement or estimate. EPA Form 3510 -2F (Rev. 1 -92) Page VII -2 Page 27 of 28 Analytical Laboratory EPA Form 3510 -2F (Rev. 1 -92) Page VII -2 Page 28 of 28 Analytical Laboratory iQ 71 TI C Ilk �-..0 ._ ..._., _ .__. -.. t 41ai9tnerlpanmp feleapprepHateanlumnbAyt. � Lfs � i °- O�' 4 0 o O 3 a ® C o 9y1 K o ® a� g m c 2L ° t 4 0 d i7 5 ° X511 � v l al Cn is 1p13, FEQ7l�tK12. Faani COMM o E`7 4 ak Ot s S a3o Wor � Customer, important: please I I TSS $ I + Indicate desired turnaround ROD Q t5 u 8019. ct ll k � a a N � phanals a O m o 0 vrrsv,. con p c CL S m 7u z CL 3 Q VV O N 74, Al•, Cw Cd,C*, 9n, AI, tlr, e, Ri% W. M cr, ev zn Ha 6 i} m° 00 to total Bata -0 $ 2 ,.. S N O � Andlum�Gl6 j r-- m z � 1 o 4 o 0 o a o Total 0 Conteinar iQ 71 TI C OUTFALL SAMPLED SAMPLE COLLECTION DATE SAMPLE TYPE ANALYSES SW002 y July 29, 2008 Grab ASTM D516- EPA 16641 EPA 350.1 EPA 353.2 SM 21208 SM2540D SM 4500 -CI SW003 July 29, 2008 Composite ASTM D516- EPA 200.7 EPA 245.1 EPA 350.1 EPA 351.2 EPA 353.2 EPA 365.1 SM 2120B S M 2540D SM 4500-Cl- SM 5220D •E 90 Page 1 of 47 Analytical Laboratory Duke Analytical Laboratory 16AVEner13339 ryv Hagers Ferry Road 71 Huntersville, NC 28078 -7929 McGuire Nuclear Complex — MG03A2 Phone: 704 - 875 -5245 Fax: 704 - 875 -5038 Job Summary Report Job Number: j 08 -JUL -0641 Project Name: Customer Name: Copy To: Customer Address: Riverbend Stormwater (7/29) Brandy Starnes J Steve Jones, Greg Phillips Riverbend Steam Station Lab Contact: Mary Ann Ogle Lab Contact Phone: 704 - 875 -5274 Report Authorized By: (Printed Name) MARY ANN OGLE Report Authorized By: (Signature) ��� Date: /04/2/b% Data Package This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical Laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report Analytical Laboratory Certificate ofAnalysis Analytical Laboratory QC Reports (f applicable) Sub - contracted Laboratory Results Customer Specific Data Sheets, Reports & Documentation (if applicable) Customer Database Entries Test Case Narratives Chain of Custody (COQ Page 2 of 47 Analytical Laboratory Duke Analytical Laboratory /Energy® 13339 Ferry Road Huntersvillille, NC 28078 -7929 %907 -08-07 McGuire Nuclear Complex— MG03A2 Phone: 704 -875 -5245 Fax: 704 - 875 -5038 Job Summary Report Certification The Analytical Laboratory holds the following Certifications: New York State Department of Health Certification # 11717(NELAC) North Carolina Department of Health & Human Services Certification # 37804 South Carolina (DHEC) Laboratory ID # 99005 North Carolina (DENR) Certification # 248 Analytical results listed in this report may not be certified by the authorities referenced above. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. The results meet all requirements of NELAC except where deviations are noted in this report. Data Flags Any analytical tests or individual analytes within a test flagged with an "X" or a "1" indicate a deviation from the method quality system or quality control requirement. Calculations All results are reported on a wet weight basis unless otherwise noted. Sample ID's & Descrintions: Collection Sample Sample ID Plant /Station Date Collected By Description 28021487 FOSSIL 7/29/2008 B. STARNES - SWO02(GRAB) RIVERBEND 28021488 FOSSIL 7/29/2008 B. STARNES SWO03 (COMP) RIVERBEND 3 TOTAL SAMPLES Ph Duke Analytical Laboratory Energy. H13339 Hagers Ferry Road untersville, NC 28078 -7929 Rev 07 -09 -07 McGuire Nuclear Complex — MG03A2 Phone: 704 -875 -5245 Fax: 704 - 875 -5038 Job Summary Report Validation of Analytical Data Package ) COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). ii) All results are less than the laboratory reporting limits. iii) All laboratory QA/QC requirements are acceptable. NPDES and TCLP results are below permit or regulatory iv) limits respectively. If iv) above i document below: Page 3 of 47 Analytical Laboratory Yes No Yes ,1 No Yes r No j Yes r" No Components of the Job Summary Report arranged in order v stipulated on page one. f No Indicate components included: 17 Job Summary Report Analytical Laboratory Certificate of Analysis �. Analytical Laboratory QC Report (if applicable) -" Sub- contracted Laboratory Results vi) Notes and Additional Information Customer Specific Data Sheets, Reports & Documentation (if applicable) j Customer Database Entries 1"- Test Case Narratives 17 Chain of Custody This is a partial report for SW 002 and SW 003. The other reports for this outfall are 08 -JUL -0149 and 08- JUN -0400. The following parameters contained quality control failures for matrix spike recovery, but the spike was not performed on this sample : TP. The following parameters contained quality control failures for duplicate relative percent difference, the quality control was not performed on this sample: metals. These quality control failures should be documented when reporting result, but these results are still considered valid. Mary Ann Ogle Duke Energy Analytical Lab NPDES Contact Office 704 -875 -5274 Cell 704 -280 -7956 Page 4 of 47 Analytical Laboratory a Pace Analytical Services, Inc. Pace Analytical Services, Inc. t3CBAnalXica1 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 1 wwwfwlrieum Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)8759092 August 13, 2008 Mr. Jay Perkins Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: 08 -JUL -0641 Pace Project No.: 9224413 Dear Mr. Perkins: Enclosed are the analytical results for sample(s) received by the laboratory on July 30, 2008. The results relate only to the samples included in this report. Results reported herein conform to the most current NELAC standards, where applicable, unless otherw ise narrated in the body of the report. Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All Microbiological analyses were performed at the laboratory where the samples were received. If you have any questions concerning this report, please feel free to contact me. Sincerely, '6&V 4"Ze' _ Renee Spencer for Kevin Herring kevin.herring @pace) abs.com Project Manager Enclosures cc: Accounts Payable DPEHS, Duke Energy Carolinas, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 23 F keAnalytical www.pacelabs.com Project: 08 -JUL -0641 Pace Project No.: 9224413 Charlotte Certification IDs Connecticut Certification Number: PH -0104 Pennsylvania Certification Number: 68 -00784 West Virginia Certification Number: 357 Virginia Certification Number: 00213 Tennessee Certification Number: 04010 South Carolina Bioassay Certification Number: 990060003 South Carolina Certification Number: 990060001 Asheville Certification IDs Connecticut Certification Number: PH -0106 Massachusetts Certification Number: M -NC030 West Virginia Certification Number: 356 Virginia Certification Number: 00072 Tennessee Certification Number: 2980 South Carolina Bioassay Certification Number: 99030002 South Carolina Certification Number: 99030001 Eden Certification IDs Virginia Drinking Water Certification Number: 00424 North Carolina Wastewater Certification Number: 633 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 CERTIFICATIONS Page 5 of 47 Analytical Laboratory Pace Analytical Services, Inc. 9800 Klncey Ave. Suite 100 Huntersville, NC 28078 North Carolina Field Services Certification Number: 5342 North Carolina Wastewater Certification Number: 12 North Carolina Drinking Water Certification Number: 37706 Louisiana /LELAP Certification Number: 04034 Kentucky UST Certification Number: 84 New Jersey Certification Number: NC012 Florida/NELAP Certification Number: E87627 Pennsylvania Certification Number: 68 -03578 North Carolina Bioassay Certification Number: 9 North Carolina Wastewater Certification Number: 40 North Carolina Drinking Water Certification Number: 37712 New Jersey Certification Number: NC011 Louisiana /LELAP Certification Number: 03095 Florida/NELAP Certification Number: E87648 North Carolina Drinking Water Certifcation Number: 37738 (704)875 -9092 REPORT OF LABORATORY ANALYSIS Page 2 of 23 This report shall not be reproduced, except in Full, without the written consent of Pace Analytical Services, Inc.. Al Page 6 of 47 Analytical Laboratory � a Pace Analytical Services, Inc. Pace Analytical Services, Inc. r �"dB�F]c7�7Cc?ar 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 7 w+w.p jace!' abs.com Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)875 -9092 SAMPLE SUMMARY Project: 08 -JUL -0641 Pace Project No.: 9224413 Lab ID Sample ID Matrix Date Collected Date Received 9224413001 9224413002 SW002 SW003 Water Water 07/29/0812:20 07/29/0812:30 07/30/0811:39 07/30/0811:39 REPORT OF LABORATORY ANALYSIS Page 3 of 23 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc - Page 7 of 47 I a j r , f `r�^' f www.pacefaos'7 1 Project: 08 -JUL -0641 Pace Project No.: 9224413 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 SAMPLE ANALYTE COUNT Analytical Laboratory Pace Analytical Services, Inc. 9800 KlnceyAve. Suite loo Huntersville, NC 28078 (704)875 -9092 Analytes Lab ID Sample ID Method Analysts Reported 9224413001 SWO02 ASTM D516 -90 SAP 1 EPA 1664A DNP 1 EPA 350.1 RAB 1 EPA 353.2 JDA 1 SM 2120B SAJ 1 SM 2540D RAB 1 SM 4500 -CI -E SAP 1 9224413002 SWO03 ASTM D616 -90 SAP 1 EPA 200.7 EWS 17 EPA 245.1 SHB 1 EPA 350.1 RAB 1 EPA 351.2 JDA 1 EPA 353.2 JDA 1 EPA 365.1 SER 1 SM 2120B SAJ 1 SM 2540D RAB 1 SM 4500 -CI -E SAP 1 1 i "I i I SM 5220D DMN 1 REPORT OF LABORATORY ANALYSIS Page 4 of 23 This report shall not be reproduced, except In full, without the written consent of of Pace Analytical Services, Inc. .pl.l�. Page 8 of 47 Analytical Laboratory f ' Pace Analytical Services, Inc. Pace Analytical Services, Inc. C�CP 11nl�i�l�iCl „ 2225 Riverside Dr. 9800 KlnceyAve Suite 100 www.pacelabs.com Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)875 -9092 Project: 08 -JUL -0641 Pace Project No.: 9224413 Sample: SWO02 Parameters HEM, Oil and Grease Oil and Grease 2120B W Apparent Color Apparent Color 2640D Total Suspended Solids Total Suspended Solids 350.1 Ammonia Nitrogen, Ammonia 353.2 Nitrogen, NO2 /NO3 pros. Nitrogen, NO2 plus NO3 4500 Chloride Chloride ASTM D516 -90 Sulfate Water Sulfate ANALYTICAL RESULTS Lab ID: 9224413001 Collected: 07/29/08 12:20 Received: 07/30/08 11:39 Matrix: Water Report Results Units Limit MDL DF Prepared Analyzed CAS No. wuat Analytical Method: EPA 1664A NO mg /L 5.0 1.1 1 07/31/08 09:55 Analytical Method: SM 2120B ND units 510 1 07/31/08 09:43 Analytical Method: SM 25400 13.1 mg /L 2.2 1 07/31/08 22:45 Analytical Method: EPA 350.1 0.90 mg /L 0.10 0.10 1 08/06/08 20:32 7764 -41 -7 Analytical Method: EPA 353.2 1.0 mg /L 0.10 0.10 1 08/03/08 13:15 Analytical Method: SM 4500 -CI -E NO mg /L 5.0 5.0 1 08/04/0816:06 16887 -00 -6 Analytical Method: ASTM D516 -90 17.3 mg /L 5.0 5'a 1 08/07/08 17:55 14808 -79 -8 Date: 08/13/200810:10 AM REPORT OF LABORATORY ANALYSIS Page 5 of 23 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. +��• E4i� <y +a e Pace Analytical Services, Inc. Iaaekialytical 2225 Riverside Dr. wwwpacelebs.com Asheville, NC 28804 (828)254 -7176 ANALYTICAL RESULTS Project: 08 -JUL -0641 Pace Project No.: 9224413 Page 9 of 47 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave Suite 100 Huntersville, NC 28078 (704)875 -9092 Sample: SWO03 Parameters Lab ID: 9224413002 Collected: 07/29/08 12:30 Report Results Units Limit MDL OF Received: 07/30/08 11:39 Matrix: Water Prepared Analyzed CAS No. 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Aluminum 366 ug /L 100 25.0 1 08/04/0810:10 08/11/0816:04 7429 -90 -5 Arsenic ND ug /L 5.0 2.7 1 08/04/0810:10 08/11/0816:04 7440 -38 -2 Barium 22.6 ug /L 5.0 0.20 1 08/04/0810:10 08/11/0816:04 7440 -39 -3 Boron ND ug /L 50.0 4.7 1 08/04/0810:10 08/11/0816:04 7440 -42 -8 Cadmium NO ug /L 1.0 0.50 1 08/04/0810:10 08/11/0816:04 7440 -43 -9 Chromium NO ug /L 5.0 0.40 1 08/04/08 10:10 08/11/0816:04 7440 -47 -3 Cobalt ND ug /L 5.0 0.60 1 08104/08 10:10 08/11/0816:04 7440 -48 -4 Copper 15.3 ug /L 5.0 0.30 1 08104108 10:10 08/11/0816:04 7440 -50 -8 Iron 447 ug /L 50.0 14.0 1 08/04/08 10:10 08/11/0816:04 7439 -89 -6 Magnesium 1210 ug /L 100 3.0 1 08/04/0810:10 08/11/0816:04 7439 -95 -4 Manganese 41.7 ug /L 5.0 0.30 1 08/04/0810:10 08/11/0816:04 7439 -96 -5 Nickel NO ug /L 5.0 1.7 1 08/04/0810:10 08/11/0816:04 7440 -02 -0 Selenium NO ug /L 10.0 3.8 1 08/04/0810:10 08/11/0816:04 7782 -49 -2 Silver NO ug /L 5.0 0.10 1 08/04/0810:10 08/11/0816:04 7440 -22 -4 Tin ND ug /L 5.0 1.8 1 08/04108 10:10 08/11/0816:04 7440 -31 -5 Titanium 13.2 ug /L 5.0 0.10 1 08/04/0810:10 08/11/0816:04 7440 -32 -6 Zinc 746 ug /L 10.0 0.40 1 08/04/0810:10 08/11/0816:04 7440 -66 -6 245.1 Mercury Analytical Method: EPA 245.1 Preparation Method: EPA 245.1 Mercury NO ug /L 0.20 0.20 1 08/04/0812:30 08/06/0610:12 7439 -97 -6 21208 W Apparent Color Analytical Method: SM 2120B Apparent Color 40.0 units 5.0 1 07/31/08 09:43 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 8.1 mg /L 2.1 1 07/31/08 22:46 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia 0.27 mg /L 0.10 0.10 1 08/06/08 20:33 7764 -41 -7 351.2 Total KJeldahl Nitrogen Analytical Method: EPA 351.2 Nitrogen, Kjeldahl, Total 1.3 mg /L 0.50 0.50 1 08/12/08 11:11 7727 -37 -9 353.2 Nitrogen, NO2/NO3 pres. Analytical Method: EPA 353.2 Nitrogen, NO2 plus NO3 1.3 mg /L 0.10 0.10 1 08/09/08 13:56 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Phosphorus 0.20 mg /L 0.10 0.10 1 08/08/08 17:54 7723 -14 -0 4500 Chloride Analytical Method: SM 4500 -CI -E Chlorlde ND mg /L 5.0 5.0 t 08/04/08 16:06 16887 -00 -6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 104 mg /L 25.0 25.0 1 08/08/08 20:05 Qual Date: 08/13/2006 10:10 AM REPORT OF LABORATORY ANALYSIS Page 6 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. / Arlo'), r ..- laceAnalytical www.pacelabs.com f Project: 08 -JUL -0641 Pace Project No.: 9224413 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)2547176 ANALYTICAL RESULTS Page 10 of 47 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875 -9092 Sample: SWO03 Lab ID: 9224413002 Collected: 07/29/08 12:30 Received: 07/30/08 11:39 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ASTM D616 -90 Sulfate Water Analytical Method: ASTM D516 -90 Sulfate 10.3 mg /L 5.0 5.0 f 08/07/0817:55 14808 -79 -8 Date: 08/13/2008 10:10 AM REPORT OF LABORATORY ANALYSIS Page 7 of 23 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. ?hela3d, Page 11 of 47 Analytical Laboratory ® Pace Analytical Services, Inc. Pace Analytical Services, Inc. a ce Analytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 ivww.Dacelabs.com Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)8755-9092 Project: 08 -JUL -0641 Pace Project No.: 9224413 QC Batch: WET 14880 QC Batch Method: SM 2120B Associated Lab Samples: 9224413001, 9224413002 METHOD BLANK: 146985 Associated Lab Samples: 9224413001, 9224413002 Parameter Units Apparent Color units SAMPLE DUPLICATE: 146986 Parameter Apparent Color QUALITY CONTROL DATA Analysis Method: SM 2120B Analysis Description: 2120B Color Blank Reporting Result Limit Qualifiers ND 5.0 9224413001 Dup Units Result Result units NO ND Max RPD RPD Qualifiers Ct 1U Date: 08/13/2008 10:10 AM REPORT OF LABORATORY ANALYSIS Page 8 of 23 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. es� e . , aceAnalytical www.pacelaWwn Project: 08 -JUL -0641 Pace Project No.: 9224413 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 QUALITY CONTROL DATA QC Batch: GCSV /3368 Analysis Method: EPA 1664A QC Batch Method: EPA 1664A Analysis Description: 1664 HEM. Oil and Grease Associated Lab Samples: 9224413001 METHOD BLANK: 147077 Associated Lab Samples: 9224413001 Blank Reporting Parameter Units Result Limit Qualifiers Oil and Grease mg /L ND 50 Page 12 of 47 Analytical Laboratory Pace Analytical Services, Inc. 9800 Klncey Ave. Suite 100 Huntersvllle, NC 28078 (704)8759092 LABORATORY CONTROL SAMPLE & LCSD: 147078 147079 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Oil and Grease m /L 40 37.5 37.7 94 94 78 -114 .5 30 Date: 08/13/2008 10:10 AM REPORT OF LABORATORY ANALYSIS Page 9 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc- 1 , Page 13 of 47 Analytical Laboratory ® Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceA flack ii! 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 rW J" Asheville, NC 28804 Huntersville, NC 28078 � ww�vpacalabs.com (828)254.7176 (704)875 -9092 Project: 08 -JUL -0641 Pace Project No.: 9224413 QC Batch: WET 14902 QC Batch Method: SM 2540D Associated Lab Samples: 9224413001, 9224413002 METHOD BLANK: 147617 Associated Lab Samples: 9224413001, 9224413002 Parameter Units Total Suspended Solids mg /L LABORATORY CONTROL SAMPLE: 147618 Parameter Units Total Suspended Solids mg /L SAMPLE DUPLICATE: 147619 Parameter Total Suspended Solids Units mg /L QUALITY CONTROL DATA Analysis Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Blank Reporting Result Limit Qualifiers ND 1.0 Spike LCS Conc. Result 250 252 9224329003 Result 142 Dup Result 144 LCS % Rec % Rec Limits Qualifiers 1.115 80 -120 Max RPD RPD Qualifiers 1 20 Date: 08/13 /2008 10:10 AM REPORT OF LABORATORY ANALYSIS Page 10 of 23 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. �4 Page 14 of 47 Analytical Laboratory e Pace Analytical Services, Inc. Pace Analytical Services, Inc. FaaceAnalXical 2225 Riverside Dr. 9800 KlnceyAve. Suite 100 www.pacelabs.cam Asheville, NC 28804 Huntersvllle, NC 28078 (828)254 -7176 (704)875 -9092 Project: 08 -JUL -0641 Pace Project No.: 9224413 QC Batch: WETA/3198 QC Batch Method: EPA 353.2 Associated Lab Samples: 9224413001 METHOD BLANK: 148319 Associated Lab Samples: 9224413001 Parameter Units Nitrogen, NO2 plus NO3 mg /L QUALITY CONTROL DATA Analysis Method: EPA 353.2 Analysis Description: 353 -2 Nitrate + Nitrite, preserved Blank Reporting Result Limit Qualifiers ND 0.10 LABORATORY CONTROL SAMPLE: 148320 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, NO2 plus NO3 mg /L 5 5.1 t02 90 -110 MATRIX SPIKE SAMPLE: Parameter Nitrogen, NO2 plus NO3 MATRIX SPIKE SAMPLE: Parameter Nitrogen, NO2 plus NO3 SAMPLE DUPLICATE: 148322 Parameter Nitrogen, NO2 plus NO3 SAMPLE DUPLICATE: 148324 Parameter Nitrogen, NO2 plus NO3 148321 Units mg /L 148323 Units mg /L 9224499001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 5 5.2 105 75 -125 9224500006 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers 0.22 5 5.8 112 75 -125 9224499002 Dup Max Urlits Result Result RPD RPD Qualifiers mg /L NO ND 0 20 9224373002 Dup Max Units Result Result RPD RPD Qualifiers mg /L NO _ ND 0 20 Date: 08/13/200810:10 AM REPORT OF LABORATORY ANALYSIS Page 11 of 23 This report shall not be reproduced, except In Tull, without the written consent of Pace Analytical Services, Inc.. i ceAnalyt'ica! e mmpacelabs,com i Project: 08 -JUL -0641 Pace Project No.: 9224413 QC Batch: MPRP /2771 QC Batch Method: EPA 200.7 Associated Lab Samples: 9224413002 QUALITY CONTROL DATA Analysis Method: EPA 200.7 Analysis Description: 200.7 MET METHOD BLANK: 148418 Associated Lab Samples: Parameter Page 15 of 47 Blank Result Analytical Laboratory Pace Analytical Services, Inc. Pace Analytical Services, Inc. 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 Asheville, NO 26804 Huntersville, NO 28078 (828)254 -7176 (704)875 -9092 QUALITY CONTROL DATA Analysis Method: EPA 200.7 Analysis Description: 200.7 MET METHOD BLANK: 148418 Associated Lab Samples: Parameter 9224413002 Units Blank Result Reporting Limit Qualifiers Aluminum ug /L ND 100 Arsenic ug /L ND 5.0 Barium ug/L NO 5.0 Boron ug /L NO 50.0 Cadmium ug /L NO 1.0 Chromium ug/L NO 5.0 Cobalt ug /L NO 5.0 Copper ug /L ND 5.0 Iron ug /L ND 50.0 Magnesium ug /L ND 100 Manganese ug /L ND 5.0 Nickel ug /L ND 5.0 Selenium ug /L ND 10.0 Silver ug /L ND 5.0 Tin ug /L NO 5.0 Titanium ug /L NO 5.0 Zinc ug /L NO 10.0 LABORATORY CONTROL SAMPLE: Parameter 148419 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug /L 5000 4600 92 85 -115 Arsenic ug/L 500 466 93 85 -115 Barium ug /L 500 470 94 85 -115 Boron ug /L 500 480 96 85 -115 Cadmium ug /L 500 452 90 85 -115 Chromium ug /L 500 464 93 85 -115 Cobalt ug /L 500 469 94 85 -115 Copper ug /L 500 480 96 85 -115 Iron ug /L 5000 4830 97 85 -115 Magnesium ug /L 5000 4660 93 85 -115 Manganese ug /L 500 462 92 85 -115 Nickel ug /L 500 456 91 85 -115 Selenium ug /L 500 462 92 85 -115 Silver ug /L 250 235 94 85 -115 Tin ug /L 500 459 92 85 -115 Titanium ug /L 500 476 95 85 -115 Zinc ug /L 500 456 91 85 -115 Date: 08/13/2008 10:10 AM REPORT OF LABORATORY ANALYSIS Page 12 of 23 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. cuay Page 16 of 47 Analytical Laboratory Pace Analytical Services, Inc. Pace Analytical Services, Inc. PaceAnalytr' cal 2225 Riverside Or. 9800 KlnceyAve. Suite 100 WWW..pacelebs.com Asheville, NO 28804 Huntersvllle, NO 28078 (828)254 -7176 (704)875 -9092 QUALITY CONTROL DATA Project: 08 -JUL -0641 Pace Project No.: 9224413 MATRIX SPIKE SAMPLE: 148420 9224413002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Llmits Qualifiers Aluminum u /L 366 5000 5200 97 70 -130 Arsenic ug /L NO 500 471 94 70 -130 Barium ug /L 22.6 500 483 92 70 -130 Boron ug /L NO 500 500 93 70 -130 Cadmium ug /L NO 500 450 90 70 -130 Chromium ug /L NO 500 461 92 70 -130 Cobalt ug /L ND 500 465 93 70 -130 Copper ug /L 15.3 500 493 96 70 -130 Iron ug /L 447 5000 5250 96 70 -130 Magnesium ug /L 1210 5000 5820 92 70 -130 Manganese ug /L 41.7 500 492 90 70 -130 Nickel ug /L NO 500 455 91 70 -130 Selenium ug /L NO 500 470 93 70 -130 Silver ug /L NO 250 234 94 70 -130 Tin ug /L ND 500 458 92 70 -130 Titanium ug /L 13.2 500 484 94 70 -130 Zinc i ug /L 748 500 1210 93 70 -130 SAMPLE DUPLICATE: 148421 9224415001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Aluminum ug /L 925 905 2 20 Arsenic ug /L NO NO 413- _ R3-': Barium ug /L 41.4 40.5 2 20 Boron ug /L 51.1 48J 6 20 Cadmium ug /L NO NO 0 20 Chromium ug /L NO NO 0 20 Cobalt ug /L 5.6 6.1 8 20 Copper ug /L NO 1.2J 12 20 Iron ug /L 946 933 1 20 Magnesium ug /L 1270 1240 2 20 Manganese ug /L 41.3 40.6 2 20 Nickel ug /L 51.4 50.6 2 20 Selenium ug /L NO NO 200., . .. 20' R3 Silver ug/L NO NO 69 . 20 R3. Tin ug /L NO NO 148 20 R_31 = Titanium ug /L NO .52J 19 20 Zinc ug /L 80.2 76.4 5 20 Date: 08113/2008 10:10 AM REPORT OF LABORATORY ANALYSIS Page 13 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. to." afi_I AA Page 17 of 47 Analytical Laboratory ,,, ### Pace Analytical Services, Inc. Pace Analytical Services, Inc. 'AceAnalical ' 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 www.pacefabscom Asheville, NC 28804 Huntersville, NC 28078 f (828)254 -7176 (704)875 -9092 Project: 08 -JUL -0641 Pace Project No.: 9224413 QC Batch: MERP /1624 QC Batch Method: EPA 245.1 Associated Lab Samples: 9224413002 METHOD BLANK: 148450 Associated Lab Samples: 9224413002 Parameter Units Mercury ug /L LABORATORY CONTROL SAMPLE: 148451 Parameter Units Mercury ug /L QUALITY CONTROL DATA Analysis Method: EPA 245.1 Analysis Description: 245.1 Mercury Blank Reporting Result Limit Qualifiers ND 0.20 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 2.5 2.5 102 85 -115 MATRIX SPIKE SAMPLE: 148452 9223856007 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Mercury ug /L ND 24 2.0 77 70 -130 SAMPLE DUPLICATE: 148453 9224516001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Mercury ug /L ND ND 16 20 Date: 08/13/2008 10:10 AM REPORT OF LABORATORY ANALYSIS Page 14 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc., y Pace Analytical Services, Inc. 1 ceAnalytkal 2225 Riverside Dr. {YWW.paCalabd.Cplp j Asheville, NC 28804 r r (828)254-7176 QUALITY CONTROL DATA Project: 08 -JUL -0641 Pace Project No.: 9224413 Page 18 of 47 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875 -9092 QC Batch: WETA13200 Analysis Method: SM 4500 -CI -E QC Batch Method: SM 4500 -CI -E Analysis Description: 4500 Chloride Associated Lab Samples: 9224413001, 9224413002 METHOD BLANK: 148478 Associated Lab Samples: 9224413001, 9224413002 Blank Reporting Parameter Units Result Limit Qualifiers Chloride mg /L ND 5.0 LABORATORY CONTROL SAMPLE: 148479 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg /L 20 2Q.3 101 90 -110 MATRIX SPIKE SAMPLE: 148480 9224054001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chloride mg /L _ 13.8 20 31.6 89 75 -125 SAMPLE DUPLICATE: 148481 9224054002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Chloride mg /L 16.4 16,6 .9 20 Date: 08/1312008 10:10 AM W REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. c:�ro Page 15 of 23 o r i cekialjrtic l P : wrvrvpacefab.com Project: 08 -JUL -0641 Pace Project No.: 9224413 QC Batch: WETA13207 QC Batch Method: EPA 365.1 Associated Lab Samples: 9224413002 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 QUALITY CONTROL DATA Analysis Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total Page 19 of 47 Analytical Laboratory Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)8755-9092 METHOD BLANK: 148728 Associated Lab Samples: 9224413002 Blank Reporting Parameter Units Result Limit Qualifiers Phosphorus mg /L ND 0.10 LABORATORY CONTROL SAMPLE: 148729 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg /L 1 0.92 92 90 -110 MATRIX SPIKE SAMPLE: 148730 9224586007 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Phosphorus mg /L _ ND 1 0.83 78 .9.5? -11 t). JMO. MATRIX SPIKE SAMPLE: 148732 9224586017 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Phosphorus i mg /L 0,31 1 1.2 88 SAMPLE DUPLICATE: 148731 i 9224586008 Dup Max Parameter Units Result Result RPD, RPD Qualifiers Phosphorus mg/L ND . JD 146 20 SAMPLE DUPLICATE: 148733 9224586018 Dup Max Parameter Units Result Result RPD RPD Qualifiers Phosphorus mg/L 0.43 0.39 10 20 Date: 08/13/2008 10:10 AM REPORT OF LABORATORY ANALYSIS Page 16 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Ilk i'. i �cekialytical' www.pacelabs,com Project: 08 -JUL -0641 Pace Project No.: 9224413 QUALITY CONTROL DATA QC Batch: WETA/3215 Analysis Method: EPA 350.1 QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia i Associated Lab Samples: 9224413001, 9224413002 METHOD BLANK: 149962 Assoclated Lab Samples: 9224413001, 9224413002 Blank Reporting Parameter Units Result Limit Qualifiers Nitrogen, Ammonia mg /L ND 0.10 LABORATORY CONTROL SAMPLE: 149963 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia f mg /L 5 5.1 103 90 -i10 MATRIX SPIKE SAMPLE: Page 20 of 47 Analytical Laboratory Pace Analytical Services, Inc. Pace Analytical Services, Inc. 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)875 -9092 QUALITY CONTROL DATA QC Batch: WETA/3215 Analysis Method: EPA 350.1 QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia i Associated Lab Samples: 9224413001, 9224413002 METHOD BLANK: 149962 Assoclated Lab Samples: 9224413001, 9224413002 Blank Reporting Parameter Units Result Limit Qualifiers Nitrogen, Ammonia mg /L ND 0.10 LABORATORY CONTROL SAMPLE: 149963 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia f mg /L 5 5.1 103 90 -i10 MATRIX SPIKE SAMPLE: 149964 9224836001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg /L 0.19 ? 4.8 93 90 -110 MATRIX SPIKE SAMPLE: 149966 9224482001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg /L NO 5 4.9 99 90 -110 SAMPLE DUPLICATE: 149965 9224411001 Dup Max Parameter Units Result Result RPD RPD Quailfiers Nitrogen, Ammonia mg /L ND NU 5 20 SAMPLE DUPLICATE: 149967 9224598001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, Ammonia mg /L 0 37 0.37 1 20 Date: 08/13/2008 10:10 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 23 t Inc. n Pace Analytical Services, /r Pa"ceAnaly `j +ar 2225 Riverside Dr. I [� www.pacefaBacom Asheville, NC 28804 SAMPLE DUPLICATE: 150033 Parameter (828)254 -7176 QUALITY CONTROL DATA Project: 08 -JUL -0641 Pace Project No.: 9224413 QC Batch: WETA/3222 Analysis Method: ASTM D516 -90 QC Batch Method: ASTM D516 -90 Analysis Description: ASTM D516 -90 Sulfate Water Associated Lab Samples: 9224413001, 9224413002 METHOD BLANK: 150030 Associated Lab Samples: 9224413001, 9224413002 Blank Reporting Parameter Units Result Limit Qualifiers Sulfate mg /L ND 5.0 LABORATORY CONTROL SAMPLE: Parameter 150031 Units Sulfate mg /L MATRIX SPIKE SAMPLE: Parameter 150032 Units Sulfate _ mg /L SAMPLE DUPLICATE: 150033 Parameter Units Sulfate mg /L SAMPLE DUPLICATE: 150571 Parameter Units Sulfate mg /L Page 21 of 47 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875 -9092 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 20 19.0 95 90 -110 _ 9224836001 Spike MS MS % Rec Result Cone. Result % Rec Limits Qualifiers ND 20 19.7 90 75 -125 9224776003 Dup Max Result Result RPD RPD Qualifiers 11.9 12.0 4 20 9224928002 Dup Max Result Result RPD RPD Qualifiers 337 339 .7 20 Date: 08/13/2008 10:10 AM REPORT OF LABORATORY ANALYSIS Page 18 of 23 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. .�'fiie��ic-. ceAnaiytical www.pacelabscam r Project: 08 -JUL -0641 Pace Project No.: 9224413 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 QUALITY CONTROL DATA QC Batch: WETA/3236 Analysis Method: SM 5220D QC Batch Method: SM 5220D Analysis Description: 5220D COD Associated Lab Samples: 9224413002 Page 22 of 47 Analytical Laboratory Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875 -9092 METHOD BLANK: 151412 Associated Lab Samples: 9224413002 Blank Reporting Parameter Units Result Limit Qualifiers Chemical Oxygen Demand mg /L ND 25 0 LABORATORY CONTROL SAMPLE: 151413 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers . ..................... _ .. — ........ Chemical Oxygen Demand mg /L 750 758 i01 90 -110 MATRIX SPIKE SAMPLE: 151414 9224345001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg /L 179 750 853 97 75 -125 MATRIX SPIKE SAMPLE: 151416 9224940001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg /L 8180 6000 13300 85 75 -125 SAMPLE DUPLICATE: 151415 9224355001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Chemical Oxygen Demand mg /L NO NO 0 20 SAMPLE DUPLICATE: 151417 9224942002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Chemical Oxygen Demand mg /L 375 364 3 20 Date: 08/1312008 10:10 AM REPORT OF LABORATORY ANALYSIS Page 19 of 23 This report shall not be reproduced, except in full, without the written consent of of Pace Analytical Services, Inc.. Page 23 of 47 Analytical Laboratory Pace Analytical Services, Inc. Pace Analytical Services, Inc. ane A'?a F�'ical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 ±' www.pacjaletbtccm Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)875-9092 QUALITY CONTROL DATA Project: 08 -JUL -0641 Pace Project No.: 9224413 QC Batch: WETA13239 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, preserved Associated Lab Samples: 9224413002 METHOD BLANK: 151542 Associated Lab Samples: 9224413002 Blank Reporting Parameter Units Result Limit Qualifiers Nitrogen, NO2 plus NO3 mg /L ND 0.10 LABORATORY CONTROL SAMPLE: 151543 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, NO2 plus NO3 mg /L 5.4 107 90 -110 MATRIX SPIKE SAMPLE: 151544 9224740001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, NO2 plus NO3 mg /L ND 5 5.3 106 75 -125 MATRIX SPIKE SAMPLE: 151546 9224740011 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, NO2 plus NO3 mg /L ND 5 5.6 112 75 -125 SAMPLE DUPLICATE: 151545 9224740002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, NO2 plus NO3 mg /L ND ND 0 20 SAMPLE DUPLICATE: 151547 9224413002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, NO2 plus NO3 mg /L 1.3 1.3 0 20 Date: 08/13/2008 10:10 AM REPORT OF LABORATORY ANALYSIS Page 20 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. i I aceAnalytical + www.pacelabs.com i I ' I i Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 QUALITY CONTROL DATA Project: 08 -JUL -0641 Pace Project No.: 9224413 QC Batch: WETA13244 Analysis Method: EPA 351.2 QC Batch Method: EPA 351.2 Analysis Description: 351.2 TKN Associated Lab Samples: 9224413002 Page 24 of 47 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875 -9092 METHOD BLANK: 151749 Associated Lab Samples: 9224413002 Blank Reporting Parameter Units Result Limit Qualifiers Nitrogen, Kjeldahl, Total mg /L ND 0.50 LABORATORY CONTROL SAMPLE: 151750 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg /L a 44 91 90 -110 MATRIX SPIKE SAMPLE: 151751 9224601005 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg /L 375 5 53.4 318 80.1 # O MO '��t , , " " 0 u��j1M 5 MATRIX SPIKE SAMPLE: 151754 9224740010 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg /L N❑ 55. 1 94 90 -110 SAMPLE DUPLICATE: 151752 9224601006 Dup Max Parameter 1 -mils Result Result RPD RPD Qualifiers Nitrogen, Kjeldahl, Total mg /L 38.3 40.3 5 20 SAMPLE DUPLICATE: 151753 9224740009 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, Kjeldahl, Total mg /L 0,94 0.57 49 20 Date: 08/13/2008 10:10 AM REPORT OF LABORATORY ANALYSIS Page 21 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. .dew, ,/ �.- �eArralytical wwwDacelftcom QUALIFIERS Project: 08 -JUL -0641 Pace Project No.: 9224413 DEFINITIONS Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 Page 25 of 47 Analytical Laboratory Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875 -9092 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. S - Surrogate 1,2- Diphenylhydrazine (8270 listed analyte) decomposes toAzobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes. ANALYTE QUALIFIERS MO Matrix spike recovery was outside laboratory control limits. R3 RPD value was outside control limits due to uncertainty of values at or near the PRL. Date: 08/13/2008 10:10 AM REPORT OF LABORATORY ANALYSIS Page 22 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 47 JJJI Analytical Laboratory a� Pace Analytical Services, Inc. Pace Analytical Services, Inc. ?r+t]�'i!� f� 2225 Riverside Dr. 9800 KlnceyAve. Suite 100 LiUG j s Asheville, NC 28804 Huntersvllle, NC 28078 wwwpacelabs.com j a (628)254 -7176 (704)875 -9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: 08 -JUL -0641 9224413 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 9224413001 SWO02 SM 2120B WET 14880 9224413002 SWO03 SM 2120B WET /4880 9224413001 SWO02 EPA 1664A GCSV /3368 9224413001 SWO02 SM 2540D WET /4902 9224413002 SWO03 SM 2540D WET /4902 9224413001 SWO02 EPA 353.2 WETA13198 9224413002 SWO03 EPA200.7 MPRP /2771 EPA 200.7 ICP/2636 9224413002 SWO03 EPA 245.1 MERP /1624 EPA 245.1 MERC /1623 9224413001 SWO02 SM 4500 -CI -E WETA/3200 9224413002 SWO03 SM 4500 -CI -E WETA/3200 9224413002 SWO03 EPA 365.1 WETA/3207 9224413001 SWO02 EPA 350.1 WETA/3215 9224413002 SWO03 EPA 350.1 WETA/3215 9224413001 SWO02 ASTM D516 -90 WETA13222 9224413002 SWO03 ASTM D516 -90 WETA/3222 9224413002 SWO03 SM 52200 WETA13236 9224413002 SWO03 EPA 353.2 WETA/3239 9224413002 SWO03 EPA 351.2 WETA/3244 Date: 08/13/2008 10:10 AM REPORT OF LABORATORY ANALYSIS Page 23 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. ka Page 27 of 47 Analytical Laboratory pnt a t a a 1 s a r" �-1 �`c2malytICaf Client Name: Project #/ Courier: ❑ Fed Ex ❑ UPS ❑ USPS ❑ Client _❑ Commercial Pace 01her 7p1iC3Fi l A---a 'g*:- s 8' ; Pra'L7� te" l' Custody Seal on Cooler /Box Present yes ;01ce heals intact: ❑ yes no pr �" t C M Packing Material: p Bubble Wrap �bble Bags one ❑Other Thermometer Used T060, _ Type �Iet Blue None copies on ice, cooling process has begun Cooler Temperature `'('J Temp should be above freezing to 6'C Biological Tissue is Frozen: Yes No N/A "Qte and Initi of er x i 'ng contents: Comments: Chain of Custody Present: -2�Ves ONo ❑NIA 1. Chain of Custody Filled Out: El es ❑No ❑NIA 2. Chain of Custody Relinquished: 437'es ONo ON /A 3. Sampler Name & Signature on COC: _LJ1°es ONo ❑N /A 4. Samples Arrived within Hold Time: -84es ONO ❑NIA 5. Short Hold Time Analysis ( <72hr): OYes .9 fko ❑N /A 6. Rush Turn Around Time Requested: Q.Yes .2lTo ❑N /A 17. Sufficient Volume: o ON /A 8. I/j AJ Correct Containers Used: -Pace Containers Used: ❑Yes EMb ❑Yes_QNo• ONIA ON /A g. Containers Intact: ffY—es ONo ❑N /A 10, Filtered volume received for Dissolved tests ❑Yes ONo M4 WA 11. Sample Labels match COC: - Includes date /time /ID /Anal sis Matrix: IIET es ONo 11 N/A 12, All containers needing preservation have been checked, All containers needing preservation are found to be in compliance with EPA recommendation. exceptions: VOA, coliform. TOC, 0 &G, WI -ORO (water) *es ONo uYes ONo ❑Yes ONo ❑N /A ❑NIA 13. Initial when completed Samples checked for dechlorination:' Dares ONo ❑NIA 14. Headspace in VOA Vials ( >6mm): ❑Yes ONo -EtM9 15. Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased): N/A ❑Yes ONo ❑Yes ONo 9+0A ❑N /A 16, Client Notification/ Resolution: Person Contacted: Comments/ Resolution: Project Manager Review: Date/Time: Field Data Required? Y / N / NIA Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i e out of hold, incorrect preservative, out of temp, incorrect containers) -.l Page 28 of 47 Analytical Laboratory I Client nt Na me. Rn U7cr- Project # 4J'rI-,-A q(4t-3 Courier: ❑ Fed Ex ❑ UPS ❑ USPS ❑ Client ❑ Commercial 121 Pace Other7ptica�aL_a Custody eat on CooterlSox Present Proj� f��l f ter +~ -k Y yes eats intact; yes na P,ze f�r �� f �`1K;ill Packing Material: ❑ Bubble Wrap bble Sags one ❑cither ��_ .: Thermometer Used Tg060� Type o Ice +r Blue None An M01125 on ice, cooling process has begun Cooler Temperature �rvi �^( ' Biological Tissue is Frozen: Yes No N/A Cate and Initi of er x i 'ng contents: Temp should be above freezing to 6'C Comments: Chain of Custody Present: -Elle-s ONo ❑N /A 1. Chain of Custody Filled Out: 137e-s ONo ❑N /A 2. Chain of Custody Relinquished: -eTes ONo ON /A 3. Sampler Name & Signature on COC: _;*es ONo ❑N /A 14. Samples Arrived within Hold Time: -BYes ONo ❑N /A 5. Short Hold Time Analysis (<72hr): OYes -Qko ON /A 6• Rush Turn Around Time Requested: Yes $To ❑N /A 7. Sufficient Volume: o ❑N /A Correct Containers Used: -Pace Containers Used: ❑Yes .e'IRo ❑Yes„Lg-No ❑N /A 'g El N/A Containers Intact: ErYes ONo ❑N /A 10. Filtered volume received for Dissolved tests OYes ONo t7O11A 11. Sample Labels match COC: - Includes date /time /ID /Analysis Matrix: es ON T OWA 12. All containers needing preservation have been checked, n y '" es ONo ON /A 13. All containers needing preservation are found to be in compliance with EPA recommendation. tJYes ONo ON /A exceptions: VOA, coliform, TOC, 0 &G. WI.ORO (water) OYes ONo initial when completed Samples checked for dechlorination: :eras ONo ON /A 14. Headspace in VOA Vials ( >6mm): OYes ONo -E MW 15, Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased): N/A Oyes OYes ONo . 64fM 16. ONo ❑N /A Client Notification/ Resolution: Person Contacted: Comments/ Resolution: Project Manager Review: Date/Time: Field Data Required? Y / N / N/A Date- Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le out of hold, incorrect preservative, out of temp, incorrect containers) tiolejogej leogRleuy L4 10 6Z abed \,� 0 \ suleLw°7i1NYiRl o a +� r.. ee o w 1 '' Y� ulnmra NI d n" IRO 9 iR 9Y r J c E dIU N IL ,y'WI.''Ji�:'►Y ° 4f°° u Ksu to S K 0 o: t _a I I I i o°s punoieuwnjpalssp elealpul snsld :aueyodwl hewolsno ; on ! 1 � _ ! I 3�I rt Rsl P r ❑ a I 1 g ova � � � �• uualll42 Yw ■p i I '""'• r• ! � s 2a1PCON"R}lH JN {'•4 •v � t•�' � � � � � It YWa3 K K D � a E ■ E I k m m E$LL�ie: e f.. Gt!.P !c y s {) r � i O !�01 Ywwo y.a_ d&w "vidwna uslMpKTF* -" ■ 1 I0tgl 1 � � � � � •_•••, _•••,�•_•_• � wn�niunn ►1 � fanM AY�OfNiIO �.�... ...._ _.. ....•• ..... •...�• .�... ...� ..,� -... .� r_. «_. .«..- sue.. .... _.. _ tiolejogej leogRleuy L4 10 6Z abed V LL ill I Jf Qy 0! 0 ! 0: Lij r17 I LL' 0 �n I i( qql-3 4-W Ajolejoqel leoilAleuV Lt 10 OE 96Bd Ott wrilprd U 'rte 050 tion ikncq fivil CD CD CL coo "'u rx 0 - W to, 009 — — — — — — — w2-- — — — — — 4 Ow o awn �j vg a at: 2" if 0 .J - o7e- qql-3 4-W Ajolejoqel leoilAleuV Lt 10 OE 96Bd Page 31 of 47 Analytical Laboratory Please print or type in the unshaded areas EPA ID Number (copy from item / of Form 1) Form Approved. OMB No. 2040 -0086 L Approval expires 5 -31 -92 Form 2F�, NPDES United States Environmental Protection Agenr ;y Washington, DC 20460 Application for Permit to Discharge Storm Water Discharges Associated with Industrial Activity Paperwork Reduction Act Notice Put*c. repo" burden for this application is estimated to average 28.6 hours per aWrcakon, including tune for ovtawing instructions, searching emoting data souroers, gathering and maintaining the data needed, and ccmpletir g and reviewing flue eoVection of Wbutatiorl. Send omynants mgardirx3 the burden esfinat% any other aspect of the oDliewon of thfsarm,'ttion or suggestions W impravinp this form, including suggestions which may irxrem or reduce this burden to: Chief, Information Policy Brand PM -223, U.S. Envi anrnental Protection Agency. 401 M SL, SW. Washington. t3C 20460. orDkedor Me of Irformabon and Regulatory Affairs, Olnca of M ementand 13 Udgat, Wash - on, DC 20503. I. Outfall Location For each outfail list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A. autfali Number list B. Latitude C. Longitude I D, Receiving Water (name) SW 042 I _ H. Improverxtents A. Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading or operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters. sti ulations. court orders, and rant or loan co, ditions. 1. Identification of Conditions, Agreements, Etc. 2. Affected Outfalls _ 3. BrW Descrl tion of Pro ect 4. Final Cam ilance Date number source of discharge a. req, b. pro. B. '+!''ou may attach additional shaets describing any additional water pollution (or other environmental projects which may affect your discharges) you now have under way or which you plan. Indicate whether each program is now under way or planned, and indicate your actual or planned schedules for construction. til. Site Drainage Map Attach a site map showing topography (or Indicating the outline of drainage areas served by the outfall(s) covered in the application if a. topographic map Is unavailable) depicting the facility including: each of its intake and discharge structures; the drainage area of each storm water outfall; paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for outdoor storage or disposal of significant materials, each existing structure control measure to reduce pollutants in stone water runoff, materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied; each of its hazardous waste treatment, storage or disposal units (including each are not required to have a RCRA permit which is used for accumulating hazardous waste under 40 CFR 262.34); each well where Fluids from the facility are injected underground; springs, and other surface water bodies which receive storm water discharges from the facility, EPA Form 3510 -21F (Rev. 1 -92) Page 1 of 3 Continued on Page 2 Page 32 of 47 Analytical Laboratory r'nnfinisarl frnm tha FrnnF IV. Narrative Description of Pollutant Sources A. For each outfall, provide an estimate of the area (include units) of impervious surfaces (including paved areas and building roofs) drained to the outfall, and an estimate of the total surface area drained by the outfall. Outfall Area of Impervious Surface Total Area Drained Outfall Area of Impervious Surface Total Area Drained Number (provide units) (provide units) Number (provide units rovide units SWO02 B. Provide a narrative description of significant materials that are currently or in the past three years have been treated, stored or disposed in a manner to allow exposure to storm water; method of treatment, storage, or disposal; past and present materials management practices employed to minimize contact by these materials with storm water runoff; materials loading and access areas; and the location, manner, and frequency in which pesticides. herbicides. soil conditioners, and fertilizers are applied. C. For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in storm water runoff; and a description of the treatment the storm water receives, including the schedule and type of maintenance for control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge. _ Outfall List Codes from Number Treatment Table 2F -1 SWO02 V. Non Stormwater Disi es A. I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of nonstorrnwater discharges, and that all nonstormwater discharges from these outfall(s) are identified in either an accompanying Form 2C or Form 2E application for the outfall. Name of Official Title (type or print) Signature Date Signed B. provide a description of the method used, the date of any testing. and the onsite drainage points that were drectl observed during a test. VI. Significant Leaks or 5 ills Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three ears. including the approximate date and location of the spill or leak. and the t ype and amount of material released. EPA Form 3510 -2F (Rev. 1 -92) Page 2 of 3 Continued on Page 3 EPA ID Number (copy from Item / of Form 1) Continued from Page 2 Page 33 of 47 Analytical Laboratory Vll. Discharge Information & D; See instruction before proceeding. Complete one set of tables for each outfall. Annotate the outfall number in the space provided. Tables Vii -A, VII -B, and VII -C are included on separate sheets numbered VII -1 and VII -2. E. Potential discharges not covered by analysis - is any toxic pollutant listed in table 2F -2, 2F -3, or 2F-4, a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct? ❑ Yes (list all such pollutants below) ❑ No (go to Section IX) Vlll. Biological Toxicity Testing Data Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? ❑ Yes (list all such pollutants below) ❑ No (go to Section /X) IX. Contact analysis information Were any of the analysis reported in item VII performed by a contact laboratory or consulting firm? ® Yes (list the name, address, and telephone number of and pollutants ❑ No (go to Section XJ analyzed by, each such laboratory or firm bell, A. Name B. Address Q. Area Code & Phone No. G D. Pollutants Analyzed Pace Analytical Services, Inc 9800 Kincey Ave Suite 100 704 -875 -9092 Oil &Grease/ Huntersville, NC 28078 Organic Pace Analytical Services, Inc 2225 Riverside Dr 828- 254 -7176 Asheville, NC 28804 Wet chemistry & metals X. Certification I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. A. Name & Official Title (type or print) _ B. Area Code and Phone No. C. Signature D. Date Signed EPA Form 3510 -2F (Rev. 1 -92) Page 3 of 3 EPA ID Number (copy from Item I of Form 1) Page 34 of 47 Analytical Laboratory Form Approved. OMB No. 2040 -0086 Approval expires 5 -31 -92 VII. Discharge Information (Continued from page 3 of Form 2F) Part A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See Instructions for additional details. Maximum Values. Average Values Number Pollutant include units lnclu cle units Of r And storm Grab Sample Grab Sample CAS Number Taken During Flow- wefghted Taken During Flow - weighted Events. (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Oil 8. Grease c 5.0 mglL NIA 1 Biological Oxygen Demand 130175 Chemical Oxygen Demand COD Total Suspended 13.1 mtgIL 1 Solids S Total 1,0 mg/L 1 Nitrogen FF Total Phosphorus pH Minimum Maximum Minimum yoximum Part B - List each pollutant that is limited In an effluent guideline which the facility is subject to or any pollutant listed in the faclilty's NPDES permit for its process wastewater (if the facility is operating under an existing NPDES permit). Complete one table for each outfall. See the instructions for additional details and requirements. Maximum Values Averatga Values Number Pollutant 0 udo units include units Of And grab Sample Grab Sample Storm CAS Number Taken During Flow- weighted Taken During Flow - weighted Events X available). First 30 Composite First 30 composite 'Sampled Minutes Minutes Sources of Pollutants Bromsde (24959.67 -9) — Chlorine, Total residual Ammonia (as N) 0.90 rrrglL 1 Chloride <5.0 rnglL 1 Color 4 54 units 1 Fluoride (16984 48-8) Nitrate- Nitrite (as N) 1.0 mglL I Radioactivity, a£pha total Radioactivity, beta total Radioactivity. radium total Radioactivity. radium Z2$ total Sulfate (as G04) 17.3 m91L 1 14$f18 -79-$ Sulfite (as S03) 14265-45.3 Aluminum, Total 7429.90 -5. Barium, Total f 440 -39 -3 Baron, Total (7440- 42- Cobalt, Total (7440- 48.4 Iron, Total (7439 -89-6) Magnesium, Total 7439 -951 _ _ Magnesium, Dissolved Molybdenum, Total 439 -98 -7 EPA Form 3510 -21F (Rev. 1 -92) Page VII -1 Continue on Reverse f r� Page 35 of 47 Analytical Laboratory Manganese, Total 7439_966 =5) Tin, Total 7440 -31 -5) Titanium, Total (7440 -32 -6 Antimony, Total 7440 -36 -0 Arsenic, Total 7440 -3$ Beryllium, Total 7440 -41 -7 Cadmium, Total 7440 -43 -9 Chromium, Total (7440 -47 -3 Copper, Total 7440 -50 -8 Lead, Total 7439 -92 -1 Mercury, Total 7439 -97 -6 Nickel, Total 7440 -02 -0 Selenium, Total _J7782 -49 -2 . Silver, Total 7440 -22 -4) Thallium, Total 7440 -28 -0) _ Zinc, Total 7440 -66 -6) EPA Form 3510 -2F (Rev. 1 -92) Page VII -I Continue on Reverse Page 36 of 47 Analytical Laboratory Continued from the Front Part C - List each pollutant shown in Tables 2F -2, 2F -3, and 2F-4 that you know or have reason to believe is present. Seethe instructions for additional details and requirements. Complete one table for each outfall. Pollutant And CAS Number (if available) Maximum Values include unit Average include Values units) Number Of Storm Events - Sampled Sources of Pollutants Grab Sample Taken During First 30 Minutes Flow- weighted Composite Grab Sample Taken During First 30 Minutes Flow- weighted Composite Cyanide, Total (57 -12 -5) Phenols, Total Surfactants (MBAs) Total Dissolved Solids Total Organic Carbon Total Kjeldahl Nitrogen TKN) Fecal Coliform Part D - Provide data for the storm events which resulted in the maximum values for the flow weighted composite sample. 1. Date of Storm Event 2. Duration of Storm Event (in minutes 3. Total rainfall during storm event (in inches) 4. Number of hours between beginning of storm measured and end of previous measurable rain event 5. Total flow from rain event (gallons or specify units) 7. Provide a description of the method of flow measurement or estimate. EPA Form 3510 -2F (Rev. 1 -92) Page VII -2 Page 37 of 47 Analytical Laboratory EPA Form 3510 -2F (Rev. 1 -92) Page VII -2 Page 38 of 47 Analytical Laboratory Instructions - Form 2F Application for Permit to Discharge Storm Water Associated with Industrial Activity Who Must File Form 2F Form 2F must completed by operators of facilities which discharge storm water associated with industrial activity or by operators of storm water discharges that EPA is evaluating for designation of a significant contributor of pollutants to waters of the United States, or as contributing to a violation of water quality standard. Operators of discharges which are composed entirely of storm water must complete Form 2F (EPA Form 3510 - 2F) in conjunction with Form 1 (EPA From 3510 -1). Operators of discharges of storm water which are combined with process wastewater (process wastewater is water that comes into direct contact with or results from the production or use of any raw material, intermediate product, finished product, byproduct, waste product, or wastewater) must complete and submit Form 217, Form 1, and Form 2C (EPA Form 3510 -2C). Operators of discharges of storm water which are combined with nonprocess wastewater ( nonprocess wastewater includes noncontact cooling water and sanitary wastes which are not regulated by effluent guidelines or a new source performance standard, except discharges by educational, medical, or commercial chemical laboratories) must complete Form 1, Form 2F, and Form 2E (EPA Form 3510 -2E). Operators of new sources or new discharges of storm water associated with industrial activity which will be combined with other nonstormwater new sources or new discharges must submit Form 1, Form 2F, and Form 2D (EPA Form 3510 -2D). Where to File Applications The application forms should be sent to the EPA Regional Office which covers the State in which the facility is located. Form 2F must be used only when applying for permits in State where the NPDES permits program is administered by EPA. For facilities located in States which are approved to administer the NPDES permits program, the State environmental agency should be contacted for proper permit application forms and instructions. Information on whether a particular program is administered by EPA or by a State agency can be obtained from your EPA Regional Office. Form 1, Table 1 of the "General Instructions" lists the addresses of EPA Regional Offices and the States within the jurisdiction of each Office. Completeness Your application will not be considered complete unless you answer every question on this form and on Form 1. If an item does not apply to you, enter "NA" (for not applicable) to show that you considered the question. Public Availability of Submitted Information You may not claim as confidential any information required by this form or Form 1, or Form 2C you may claim as confidential, but claims for information which are effluent data will be denied. If you do not assert a claim of confidentiality at the time of submitting the information, EPA may make the information public without further notice to you. Claims of confidentiality will be handled in accordance with EPA's business confidentiality regulations at 40 CFR Part 2. Definitions All significant terms used in these instructions and in the form are defined in the glossary found in the General Instructions which accompany Form 1. EPA ID Number Fill in your EPA Identification Number at the top of each odd - numbered page of Form 2F. You may copy this number directly from item 1 of Form 1. EPA Form 3510 -2F (Rev. 1 -92) Page I -1 Page 39 of 47 Analytical Laboratory Please print or type in the unshaded areas EPA ID Number (copy from item / of Form 1) Form Approved. OMB No. 2040 -0086 Approval expires 5 -31 -92 fffl 2F NPDES f.lrtiCed States Environmental Protection Agency Washington, DC 20460 r Application for Permit to Discharge Storm Water Discharges Associated with Industrial Activit Paperwork Reduction Act Notice Public reporting burden for this application is estimated to average 28.6 hours per application, including time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding the burden estimate, any other aspect of this collection of information or suggestions for improving this form, including suggestions which may increase or reduce this burden to: Chief, Information Policy Branch, PM -223, U.S. Environmental Protection Agency, 401 M St, SW, Washington, DC 20460, or Director, Office of Information and Regulatory Affairs, Office of Management and Budget. Washington, DC 20503. _ I. Outfall Location For each outfall, list the latitude and Ion itude of its location to the nearest 15 seconds and the name of the receiving water. A. Outfall Number (list) B. Latitude C. Longitude D. Receiving Water 0. SIN 003 Il.Improvements A. Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading or operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, sti utaklons, court orders and grant or loan conditions. 1, Identification of Conditions, Agreements, Etc, 2. Affected Outfalts I Brief Desadiption of Project 4. Final Com fiance Date number source of dis0arge a. teg, I b. proj. B. You may attach additional sheets describing any additional water pollution (or other environmental projects which may affect your discharges) you now have under way or which you plan. Indicate whether each program is now under way or planned, and indicate your actual or planned schedules for construction. III. Site Drainage Ma Attach a site map showing topographv (or indicating the outline of drainage areas served by the outfall(s) covered in the application if a topographic map Is unavailable) depicting the facility including: each of its intake -and discharge structures; the drainage area of each storm water outfall; paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for outdoor storage or disposal of significant materials, each existing structure control measure to reduce pollutants in storm water runoff, materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied; each of its hazardous waste treatment, storage or disposal units (including each are not required to have a RCRA permit which is used for accumulating hazardous waste under 40 CFR 262.34); each well where fluids from the facility are injected underground; springs, and other surface water bodies which receive storm water discharges from the facility. EPA Form 3510 -21F (Rev. 1 -92) Page 1 of 3 Continued on Page 2 Page 40 of 47 Analytical Laboratory Continued from the Front 1 V.. IYS1Fr7UVV U1V5UF11 UU[1 OF i'U11UWHE `IUUMM5 A. For each outfall, provide an estimate of the area (include units) of impervious surfaces (including paved areas and building roofs) drained to the outfall, and an estimate of the total surface area drained by the outfall. Outfall Area of Impervious Surface Total Area Drained aurfali Area of Impervious Surface Total Area Drained Number rovide units) rovide units Number (provide units) (provide units) SW003 B. Provide a narrative description of significant materials that are currently or in the past three years have been treated, stored or disposed in a manner to allow exposure to storm water; method of treatment, storage, or disposal; past and present materials management practices employed to minimize contact by these materials with storm water runoff; materials loading and access areas; and the location, manner, and frequenc in which pesticides, herbicides, soil conditioners, and fertilizers are applied. C. For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in storm water runoff; and a description of the treatment the storm water receives, including the schedule and type of maintenance for control and treatment measures and the ultimate disposal of any solid or fluid wastes other thariby discharge. Outfall List Codes from Number Treatment Table 2F -1 SW003 V. Non Storrrtwater Dischar es A. I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of nonstormwater discharges, and that all nonstormwater discharges from these outfall(s) are identified in either an accompanying Form 2C or Form 2E ap lication for the outfall. Name of Official Title (type or print) Signature Date Signed B. provide a description of the method used, the date of any testing, and the onsite drainage points that were direct) observed during a test. VI. Significant Leaks or Spills Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three ears, including the approximate date and location of the spill or leak, and the type and amount of material released. EPA Form 3510 -2F (Rev. 1 -92) Page 2 of 3 Continued on Page 3 Page 41 of 47 Analytical Laboratory 1 EPA ID Number (copy from Item I of Form Continued from Page 2 V11. Discharge Information A.B.C. & D: See instruction before proceeding. Complete one set of tables for each outfall. Annotate the outfall number in the space provided. Tables Vii -A, VII -B, and VII -C are included on separate sheets numbered VII -1 and VII -2. E. Potential discharges not covered by analysis - is any toxic pollutant listed in table 2F -2, 2F -3, or 2F -4, a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct? ❑ Yes (list all such pollutants below) ❑ No (go to Section /X) Vlll. Biological Toxicity Testing Data Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? ❑ Yes (list all such pollutants below) ❑ No (go to Section IX) IX. Contact analysis Information Were any of the analysis reported in item VII performed by a contact laboratory or consulting firm? ® Yes (list the name, address, and telephone number of, and pollutants ❑ No (go to Section X) anal yzed b , each such laborato ry or firm below A. Name S. Address C. Area Code & Phone No. D. Pollutants Analyzed Pace Analytical Services, Inc 9800 Kincey Ave Suite 100 704 -875 -9092 Oil &Grease/ Huntersville, NC 28078 Organic Pace Analytical Services, Inc 2225 Riverside Dr 828- 254 -7176 Asheville, NC 28804 Wet chemistry & metals X. Certification I -certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties tot submitting false information, including the possibility of fine and imprisonment for knowin violations. A. Name & Official Title (type or print) B. Area Code and Phone No. C. Signature D. Date Signed EPA Form 3510 -2F (Rev. 1 -92) Page 3 of 3 EPA ID Number (copy from Item I of Form 1) J I Page 42 of 47 Analytical Laboratory Form Approved. OMB No. 2040 -0086 Approval expires 5 -31 -92 VII. Discharge Information Continued from page 3 of Form 2F Part A - You must rovide the results of at least one analysis for p y every pollutant in this table. Complete one table for each outfall. See lns ns for additional details, Maximum Values Average Values Number PoNutant include unks include units Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow - weighted Taken During Flow- weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Oil & Grease 5.0 rngll. N/A 1 Biological Oxygen 72.9 mWL 54.9 mgiL 2 Demand BODS Chemloal Oxygen 233 mgfL 104 mglL 81 mglL 3 Demand COD Total Suspended 151 mglL 8.1 mg1L 2 Solids SS Total U mglL 2,6 mglL 2.44 mglL 3 Nitrogen Total 1.6 mgfL 0.20 mglL 0,18 mglL 3 Phosphorus pH MinJmurn Maximum Minimum Maximum Part 3 - List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES permit for its process wastewater (if the facility is operating under an existing NPDES permit). Complete one table for each outfall. See the instructions for additional details and re uirements. Maximum Values Average Values Number Pollutant (lrrctuda un+ include units Of And Storm Grab Sample Grab Sample CAS Number Taken During Flow- weighted Taken During Flow weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Bromide (2435967 -9) Chlorine, 'fatal residual Ammonia (as N) 0.80 mglL 0.27 mg1L 0.026 mglL 3 Chloride < 5.0 mglL 1 Color 40.0 units 1 Fluoride (16984.48 -8) Nitrate - Nitrite (as N) 1.2 mglL 1.3 mgll 1.04 mglL 3 Radioactivity; alpha total Radloactivity, beta total Radioactivity, radium total Radioactivity, radium 226 total Sulfate (as SOA) 10.3 mglL 1 148418.79 -8 Sulfite (as S03) 14205 -45.3) Aluminum, Toted 0.753 mg;IL 0.697 mglL 0,631 mglL 3 429 -gt3.5 Barium, Total 0.115 mglL 0.0226 mglL 0.0224 mglL 3 7440 -39 -3 Boron, Total (7440- 0.072 mg)L 40.050 mglL <0.050 mglL 3 42.8 Cobalt, Total (7440- <0.005 mglL 440.OD5 mgll- <0.005 mglL 3 +48.4 Iron, Total (7435 -8g-6) 21.2 mgA- 0.599 Mg /L 0.723 mglL 3 Magnesium, Total 9.57 mg1L 1.21 mglL 1,07 mglL 3 - 7439 6.4 Magnesium, Dissolved Molybdenum, Total 7439.98.7 Manganese, Total 1.33mgIL 0.0792 mgll 0.0604mgIL 3 7439 -%-5 EPA Form 3510 -2F (Rev. 1 -92) Page VII -1 Continue on Reverse Page 43 of 47 Analytical Laboratory Tin, Total <0.005 mg /L <0.005 mg /L <0.005 mg /L 3 7440 -31 -5) Titanium, Total 0.0299 mg /L 0.0403 mg/L 0.0267 mg /L 3 (7440 -32 -6) — — — Antimony, Total 7440 -36 -0 Arsenic, Total 0.005 mg /L <0.005 mg /L <0.005 mg /L 3 (7440 -38 -2) Beryllium, Total _ 7440 -41 -7 Cadmium, Total <0.001 mg /L <0.001 mg /L <0.001 mg /L 3 7440 -43 -9 Chromium, Total <0.005 mg /L <0.005 mg /L <0.005 mg /L 3 (7440 -47 -3) 3 Copper, Total 0.0533 mg /L 0.0182 mg /L _ 0.0167 mg /L (7440 -50 -8 Lead, Total _C7439 -92 -1) Mercury, Total <0.200 ug /L <0.200 ug /L <0.200 ug /L 3 7439 -97 -6 Nickel, Total 0.0068 mg /L <0.005 mg /L <0.005 mg /L 3 7440 -02 -0) Selenium, Total <0.010 mg /L <0.010 mg /L <0.010 mg /L 3 7782 -49 -2 Silver, Total <0.005 mg /L <0.005 mg /L <0.005 mg /L 3 (7440 -22 -4) Thallium, Total 7440 -28.0) Zinc, Total 2.29 mg /L 0.758 mg /L 0.753 mg /L 3 (7440-66 -6) EPA Form 3510 -2F (Rev. 1 -92) Page VII -1 Continue on Reverse Continued from the Front i Page 44 of 47 Analytical Laboratory Part C - List each pollutant shown in Tables 2F -2, 2F -3, and 2F-4 that you know or have reason to believe is present. See the instructions for additional details and requirements. Complete one table for each outfall. Maximum Values Average Values Pollutant include units (include units) And Grab Sample Grab Sample CAS Number Taken During Flow- weighted Taken During Flow- weighted (if available) First 30 Composite First 30 Composite Minutes Minutes Number Of Storm Events Sampled 1 Sources of Pollutants Cyanide, Total (57 -12 -5) _ _ Phenols, Total 0.045 mg /L 1 Surfactants (MBAs) Total Dissolved Solids Total Organic Carbon Total Kjeldahl 7.7 mg /L Nitrogen (TKN) 1.5 mg1L 1.4 mg /L 3 Fecal Coliform 100 CFU/100 mL 1 Part D 1. Date of Stone Event - Provide data for the storm events 2. Duration of Storm Event (in minutes) which resulted in the maximum 3. Total rainfall during storm event (in inches) values for the flow weighted com 4. Number of hours between beginning of storm measured and end of previous measurable rain event osite sample. 5. Total flow from rain event (gallons or specify units) 7. Provide a description of the method of flow measurement or estimate. EPA Form 3510 -2F (Rev. 1 -92) Page VII -2 Page 45 of 47 Analytical Laboratory EPA Form 3510 -2F (Rev. 1 -92) Page VII -2 Page 46 of 47 Analytical Laboratory IA 33ss nm f� vI dO� m ��3' x c m � a 3 0 d A 11� .-..J � w 3 cup"tocumplara A '"vf ••�• ••~. .._ _.• A N Er M j i c ° c Cr a Q M 0 � I o �r a 7 � r ro ` d l I W 0 � N' � � I 3 m l m { _ °_ '01 $ � 8 � XY G '; 6 9 IS 8 n ds 4 do r' N g g� a� V { yl q „ 9 ; -T 0 a 10 jo qq t� a h a o �v O n' ;In m 3 jn o �° ,0 1 i O GOD ilz © Faoarl Crollrntm ` $''� ! i N m � ' � L i {0 Customer, Important: please Indicate desired turnaround V4 _ a } Aoo { UP s II � � I q 74fRRc0u m +C o I 0 CL smateon o ¢ 'D of x x 0 Wxdhon 23S � s m z i -4 � c a y� o o TatAl #cWliR771R Page 47 of 47 Analytical Laboratory i ,i i �I m� 01 al d di of 010 .Z v!0 iT i .0 I C !N I-4 !0 i0 I� ]irn 10 0 BIZ riz Z gig 9 1(A p! ;1 VhA Ec i Ca l� i0 i� I i i CIO GICRIgnifMUr4 igEit is ON ti a r"- 6 m. C pap IC— ,GGAttln3CC to AQ{nRi0t0 AR�PlI 4 i41nM1n i4 ri ~ilt pr O SO 0 C i OO 0 6 O N �� E O IN e. Z g d �j 0 tea ut rn 0 ka ��nmo F� ur.. 1 v/ W ♦• N,� t7 it If' W N F 4 1 7 O i.O n 4�r Camp, A !9 � A rr is 1 NO N at x „� � FLI i a ? of �I 'I a ran � 44 g K Customer, important: please i indicate desired turnaround BOO S c 1 .j a dd"jjj O m m G) t F o -1 N FIfAYyr-�y� Ca.�p.•, ylrl }'�,4$'�Ip 4 y v �n 4 , .P a � rG C Vr N ,iq+},HIyYY.,., O z FUdWrn 228 S $ W iN n r rfi z q q -4 � 4 --I o Tatty 0 t:Unialnar - i ,i i �I m� 01 al d di of 010 .Z v!0 iT i .0 I C !N I-4 !0 i0 I� ]irn 10 0 BIZ riz Z gig 9 1(A p! ;1 VhA Ec i Ca l� i0 i� I i i OUTFALL SAMPLED SAMPLE COLLECTION DATE SAMPLE TYPE ANALYSES SW002 Sep 10, 2008 Grab ASTM D516 -90 EPA 1664A EPA 200.7 EPA 245.1 EPA 350.1 EPA 351.2 EPA 353.2 EPA 365.1 EPA 420.4 SM 21206 SM2540D SM 4500 -CI -E SM 52106 SM 5220D Page 1 of 38 Analytical Laboratory Duke Analytical Laboratory 11VEnergy. 13339 Hagers Ferry Road Huntersville, NC 28078 -7929 Rev 07 -09 -07 McGuire Nuclear Complex — MG03A2 Phone: 704 - 875 -5245 Fax: 704 - 875 -5038 Job Summary Report Job Number: 08 -SEP -0240 1 Project Name: Customer Name: Copy To: Customer Address: Riverbend Storm Water Brandy Starnes Steve Jones, Greg Phillips MG03A3 Lab Contact: Mary Ann Ogle Lab Contact Phone: ! 704 - 875 -5274 Report Authorized By: (Printed Name) Report Authorized By: (Signature) MARY ANN OGLE Date: /o O Data Package This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical Laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Reports (f applicable) Sub - contracted Laboratory Results Customer Specific Data Sheets, Reports & Documentation (if applicable) Customer Database Entries Test Case Narratives Chain of Custody (COQ I i Duke Analytical Laboratory }� 13339 Hagers Ferry Road PolEnergyoHuntersville, NC 28078 -7929 Rev 07 -09 -07 McGuire Nuclear Complex — MG03A2 Phone: 704 - 875 -5245 Fax: 704 - 875 -5038 Job Summary Report Certification The Analytical Laboratory holds the following Certifications: New York State Department of Health Certification # 11717(NELAC) North Carolina Department of Health & Human Services Certification # 37804 South Carolina (DHEC) Laboratory ID # 99005 North Carolina (DENR) Certification # 248 Analytical results listed in this report may not be certified by the authorities referenced above. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. The results meet all requirements of NELAC except where deviations are noted in this report. Data Flags Any analytical tests or individual analytes within a test flagged with an "X" or a "1" indicate a deviation from the method quality system or quality control requirement. Calculations All results are reported on a wet weight basis unless otherwise noted. Samule ID's & Descriptions: Collection Sample Sample ID Plant /Station Date Collected By Description 28026404 FOSSIL 9/10/2008 B STARNES RIyERBEND SWO02 1 TOTAL SAMPLES Page 2 of 38 Analytical Laboratory Duke Analytical Laboratory /Energy. 13339 Hagers Ferry Road Huntersville, NC 28078 -7929 Rev 07 -09-07 McGuire Nuclear Complex — MG03A2 Phone: 704 - 875 -5245 Fax: 704 -875 -5038 Job Summary Report Validation of Analytical Data Package i) COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). ii) All results are less than the laboratory reporting limits. iii) All laboratory QA/QC requirements are acceptable. NPDES and TCLP results are below permit or regulatory iv) limits respectively. Page 3 of 38 Analytical Laboratory r Yes [W' No EE Yes IF—No] i Yes r No Components of the Job Summary Report arranged in order V) stipulated on page one. Indicate components included: Job Summary Report F Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report (if applicable) [7 Sub - contracted Laboratory Results vi) Notes and Additional Information Yes F No Customer Specific Data Sheets, Reports & 17 Documentation (if applicable) f-" Customer Database Entries j" Test Case Narratives f7 Chain of Custody This is a partial report for SW 002. The other reports for this outfall are 08-JUL -0641 . The following parameters contained quality control failures for matrix spike recovery, but the spike was not performed on this sample: TP, phenols, sulfate, chloride. The following parameters contained quality control failures for duplicate relative percent difference, the quality control was not performed on this sample: TSS. These quality control failures should be documented when reporting result, but these results are still considered valid. Mary Ann Ogle Duke Energy Analytical Lab NPDES Contact Office 704- 875 -5274 Cell 704- 280 -7956 Page 4 of 38 Analytical Laboratory Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceAna f !Ifical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 j www..pacews.com Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7178 (704)875 -9092 October 03, 2008 Mr. Jay Perkins Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: 08 -SEP -0240 Pace Project No.: 9227707 Dear Mr. Perkins: Enclosed are the analytical results for sample(s) received by the laboratory on September 11, 2008. The results relate only to the samples included in this report. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All Microbiological analyses were performed at the laboratory where the samples were received. If you have any questions concerning this report, please feel free to contact me. Sincerely, 4 --- ��- Kevin Herring kevin.herring @pacelabs.com Project Manager Enclosures cc: Accounts Payable DPEHS, Duke Energy Carolinas, LLC REPORT OF LABORATORY ANALYSIS Page 1 of 23 This report shall not be reproduced, except in full, without the written consent or Pace Analytical Services, Inc.. aceAnalytical"' V114UP 13blcom f Project: 08 -SEP -0240 Pace Project No.: 9227707 Charlotte Certification IDs Connecticut Certification Number: PH -0104 Pennsylvania Certification Number: 68 -00784 West Virginia Certification Number: 357 Virginia Certification Number: 00213 Tennessee Certification Number: 04010 South Carolina Drinking Water Cert. Number: 990060003 South Carolina Certification Number: 990060001 Asheville Certification IDs Connecticut Certification Number: PH -0106 Massachusetts Certification Number: M -NC030 West Virginia Certification Number: 356 Virginia Certification Number: 00072 Tennessee Certification Number: 2980 South Carolina Bioassay Certification Number: 99030002 South Carolina Certification Number: 99030001 Eden Certification IDs Virginia Drinking Water Certification Number: 00424 North Carolina Wastewater Certification Number: 633 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 CERTIFICATIONS Page 5 of 38 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 North Carolina Field Services Certification Number: 5342 North Carolina Wastewater Certification Number: 12 North Carolina Drinking Water Certificatlon Number: 37706 Louisiana /LELAP Certification Number. 04034 Kentucky LIST Certification Number: 84 New Jersey Certification Number: NC012 Florida /NELAP Certification Number: E87627 Pennsylvania Certification Number: 68 -03578 North Carolina Bioassay Certification Number: 9 North Carolina Wastewater Certification Number. 40 North Carolina Drinking Water Certification Number: 37712 New Jersey Certification Number: NC011 Louisiana/LELAP Certification Number: 03095 Florida /NELAP Certification Number: E87648 North Carolina Drinking Water Certification Number: 37738 (704)875 -9092 REPORT OF LABORATORY ANALYSIS Page 2 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. a� s a i C�LrU r7f ICU�I��! r vN+r+.pacelabs.com Project: 08 -SEP -0240 Pace Project No.: 9227707 Lab ID Sample ID 9227707001 28026404 SW002 Pace Analytical Services, Inc. 2225 Riverside Dc Asheville, NC 28804 (828)254 -7176 SAMPLE SUMMARY Matrix Date Collected Date Received Water 09/1010816:00 0911110814:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 38 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875 -9092 Page 3 of 23 Page 7 of 38 Analytical Laboratory ' Pace Analytical 5 Riverside Dr. Pace 9800 Kinccey Ave. Suite 100 aCBAr�aljl�rcal Veympacalatlacom Asheville, NC 28804 Huntersville, NC 28078 j (828)254 -7176 (704)875 -9092 SAMPLE ANALYTE COUNT Project. 08 -SEP -0240 Pace Project No.: 9227707 Lab ID Sample ID Method Analysts Analyses Reported 9227707001 28026404 SWO02 ASTM D516 -90 SER 1 EPA 1664A DNP 1 EPA 200.7 EWS 17 EPA 245.1 SHB 1 EPA 350.1 RAB 1 EPA 351.2 RAB 1 EPA 353.2 JDA 1 EPA 365.1 JDA 1 EPA 420.4 SER 1 SM 2120B RAB 1 SM 2540D SAJ 1 SM 4500 -CI -E SER 1 SM 5210B SAJ 1 SM 5220D RAB 1 REPORT OF LABORATORY ANALYSIS Page 4 of 23 This report shall not be reproduced, except in full, without the written conseyyntt� of Pace Analytical Services, Inc,. "E1G`.�R�Iti: Page 8 of 38 Analytical Laboratory e Pace Analytical Services, Inc. Pace Analytical Services, Inc. accAnalXical 2225 Riverside Dr. 9600 Kincey Ave. Suite 100 vroNipacelabs.com Asheville, NC 28804 Huntersville, NC 28078 f (828)254 -7176 (704)875 -9092 ANALYTICAL RESULTS Project: 08 -SEP -0240 Pace Project No.: 9227707 Sample: 28026404 SWO02 Parameters Lab ID: 9227707001 Collected: 09/10108 16:00 Report Results Units Limit MDL DF Received: 09/11108 14:30 Matrix: Water Prepared Analyzed CAS No. Qua[ HEM, Oil and Grease Analytical Method: EPA 1664A Oil and Grease 27.6 mg /L 5.0 1.1 r 09/22/08 10:52 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Aluminum 1580 ug /L 100 25.0 1 09 /17/08 12:55 09/25108 22:11 7429 -90 -5 Arsenic ND ug /L 5.0 2.7 1 09/17/08 12:55 09/25/08 22:11 7440 -38 -2 Barium 51.7 ug /L 5.0 0.20 1 09117/08 12:55 09/25/08 22:11 7440 -39 -3 Boron 91.5 ug /L 50.0 4.7 1 09/17/08 12:55 09/25/08 22:11 7440 -42 -8 Cadmium 1.2 ug /L 1.0 0.50 1 09117108 12:55 09/25108 22:11 7440 -43 -9 Chromium ND ug /L 5.0 0.40 1 09/17/08 12:55 09/25/08 22:11 7440 -47 -3 Cobalt ND ug /L 5.0 0.60 1 09/17/08 12:55 09/25108 22:11 7440 -48 -4 Copper 33.3 ug /L 5.0 0.30 1 09117/08 12:55 09/25108 22:11 7440 -50 -8 Iron 5790 ug /L 50.0 14.0 1 09/17/08 12:55 09/25/08 22:11 7439 -89 -6 Magnesium 3520 ug /L 100 30 1 09/17108 12:55 09/25/08 22:11 7439 -95 -4 Manganese 117 ug /L 5.0 0.30 1 09/17/08 12:55 09/25/08 22:11 7439 -96 -5 Nickel ND ug /L 5.0 1.7 1 09/17108 12:55 09/25/08 22:11 7440 -02 -0 Selenium 56.2 ug /L 10.0 3.8 1 09117/08 12:55 09/25/08 22:11 7782 -49 -2 Silver ND ug /L 5.0 0.10 1 09117/08 12:55 09125108 22:11 7440 -22 -4 Tin ND ug /L 5.0 1.8 1 09/17/08 12:55 09/25/08 22:11 7440 -31 -5 Titanium 81.3 ug /L 510 0.10 1 09117/08 12:55 09/25/08 22:11 7440 -32 -6 Zinc 486 ug /L 10.0 0.40 1 09/17/08 12:55 09/25/08 22:11 7440 -66 -6 245.1 Mercury Analytical Method: EPA 245.1 Preparation Method: EPA 245.1 Mercury ND ug /L 0.20 0.20 1 09/29/0818:10 09/30/08 09:48 7439 -97 -6 2120B W Apparent Color Analytical Method: SM 2120B Apparent Color 180 units 5.0 1 09/11/08 22:50 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 67.7 mg /L 3.3 1 09/15/08 14:49 5210B BOD, Low Level Analytical Method: SM 5210B BOD, 5 day 5.2 mg /L 2.0 1 09/12108 06:00 09117/08 12:00 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia 0.21 mg /L 0.10 0.10 1 09/17/08 20:30 7764 -41 -7 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Nitrogen, Kjeldahl, Total 1.3 mg /L 0.50 0.50 1 09/15108 20:30 7727 -37 -9 353.2 Nitrogen, NO2/NO3 pres. Analytical Method: EPA 353.2 Nitrogen, NO2 plus NO3 0.94 mg /L 0.10 0.10 1 09/20/08 12:26 365.1 Phosphorus, Total Analytical Method: EPA365.1 Phosphorus 0.12 mg /L 0.10 0.10 1 09/16/0810;52 7723 -14 -0 Date: 10/03/2008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 5 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. ill t; Project: 08 -SEP -0240 Pace Project No.: 9227707 Sample: 28026404SWO02 Parameters Lab ID: 9227707001 Collected: 09/10/0816:00 Report Results Units Limit MDL DF Page 9 of 38 420.4 Phenolics, Total Analytical Method: EPA 420.4 Analytical Laboratory / � Pace Analytical Services, Inc. Pace Analytical Services, Inc. .PalceAnalytical 2225 Riverside Dr. 9600 Kincey Ave. Suite 100 r4rwyac €idl S ,frrrr Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)875 -9092 Chloride ANALYTICAL RESULTS 5.0 1 Project: 08 -SEP -0240 Pace Project No.: 9227707 Sample: 28026404SWO02 Parameters Lab ID: 9227707001 Collected: 09/10/0816:00 Report Results Units Limit MDL DF Received: 09/11/0814:30 Matrix: Water Prepared Analyzed CAS No. Qual 420.4 Phenolics, Total Analytical Method: EPA 420.4 Phenol ND mg /L 0.010 0.0110 1 09117/08 16:52 108 -95 -2 4500 Chloride Analytical Method: SM 4500 -CI -E Chloride 5.8 mg /L 5.0 5.0 1 09/16108 17:20 16887 -00 -6 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 49.0 mg /L 25.0 25.0 1 09/12/08 17:25 ASTM D516 -90 Sulfate Water Analytical Method: ASTM D516 -90 Sulfate 20.7 mg /L 5.0 5 .0 1 09/16/08 13:56 14808 -79 -8 Date: 10/03/2008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 6 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc., +4,,, Page 10 of 38 Analytical Laboratory Pace Analytical Services, Inc. Pace Analytical Services, Inc. �����JI /� 2225 Riverside Dr 9800 Klncey Ave. Suite 100 www.pwelabs.com Asheville, NC 28804 Huntersville, NC 28078 f (828)2547176 (704)875 -9092 QUALITY CONTROL DATA Project: 08 -SEP -0240 Pace Project No.: 9227707 QC Batch: WET /5428 Analysis Method: SM 2120B QC Batch Method: SM 2120B Analysis Description: 21208 Color Associated Lab Samples: 9227707001 METHOD BLANK: 166940 Matrix: Water Associated Lab Samples: 9227707001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers - -.._. . ....... - -.. v..r.. ... Apparent Color units ND 5.0 09111108 22:50 SAMPLE DUPLICATE: 166941 9227707001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Apparent Color u,t+ls _ v 180 180 0 20 Date: 10/03/2008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 7 of 23 This report shall not be reproduced, except in Full, without the written consent of PaceAnalylical Services, Inc.. p ! ® Pace Analytical Services, Inc. f -paceAnalytical 2225 Riverside Dr. vnw.pnelabacom Asheville, NC 28804 (828)254 -7176 QUALITY CONTROL DATA Project: 08 -SEP -0240 Pace Project No.: 9227707 QC Batch: WET 15431 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210B BOD, Low Level Associated Lab Samples: 9227707001 METHOD BLANK: 166948 Matrix: Water Associated Lab Samples: 9227707001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg /L ND 2.0 09/17/08 12:00 LABORATORY CONTROL SAMPLE: 166949 Page 11 of 38 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875 -9092 Spike LCS LCS % Rec Parameter Units Canc. Result % Rec Limits Qualifiers BOD, 5 day mg /L 198 192 97 84 -115 SAMPLE DUPLICATE: 166950 9227681001 Dup Max Parameter units Result Result RPD RPD Qualifiers BOD, 5 day mg /L 8.9 6.5 5 20 B2 Date: 10/03/2008 03 :34 PM REPORT OF LABORATORY ANALYSIS Page 8 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. SAMPLE DUPLICATE: 167259 9227662001 Dup Max Parameter Units Result Result RPO RPD Qualifiers Chemical Oxygen Demand mg /t. 8510 85.0 d 20 Date: 10/03/2008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 9 of 23 This report shall not be reproduced, except In full, without the written consent f of Pace Analytical Services, Inc.. l _ 1L�_ V Page 12 of 38 Analytical Laboratory a Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceAnalXical 2225 Riverside Dr. 9600 KinceyAve. Suite 100 www.pacdabs.com Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)8755-9092 j P i QUALITY CONTROL DATA Project: 08 -SEP -0240 i Pace Project No.: 9227707 QC Batch: WETA/3453 m Analysis Method: SM 5220D QC Batch Method: SM 5220D Analysis Description: 5220D COD Associated Lab Samples: 9227707001 METHOD BLANK: 167254 Matrix: Water Associated Lab Samples: 9227707001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chemical Oxygen Demand mg /L NO 25.0 09/12/0817:25 LABORATORY CONTROL SAMPLE: 167255 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg /L 750 755 101 90 -110 MATRIX SPIKE SAMPLE: 167256 9227080001 Spike MS MS % Rec Parameter Units Result Conc.` Result % Rec Limits Qualifiers Chemical Oxygen Demand mg /L 118 750 813 93 75 -125 MATRIX SPIKE SAMPLE: 167258 9227647002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg /L 380 750 1106 96 75 -125 SAMPLE DUPLICATE: 167257 9227094001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Chemical Oxygen Demand mg /L 673 678 1 20 SAMPLE DUPLICATE: 167259 9227662001 Dup Max Parameter Units Result Result RPO RPD Qualifiers Chemical Oxygen Demand mg /t. 8510 85.0 d 20 Date: 10/03/2008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 9 of 23 This report shall not be reproduced, except In full, without the written consent f of Pace Analytical Services, Inc.. l _ 1L�_ Page 13 of 38 Analytical Laboratory j e Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceAnalg1Cai 2225 Riverside Dr. 9800 KinceyAve. Suite 100 www.pacelabs.00m Asheville, NC 28804 Huntersvills, NC 28078 I (828)254 -7178 (704)875 -9092 QUALITY CONTROL DATA Project: 08 -SEP -0240 Pace Project No.: 9227707 QC Batch: WETA13464 Analysis Method: EPA 365.1 QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total Associated Lab Samples: 9227707001 METHOD BLANK: 167967 Matrix: Water Associated Lab Samples: 9227707001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phosphorus mg /L ND 0.10 09/16/0810:49 LABORATORY CONTROL SAMPLE: 167968 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg /L 1 1't) 100 90-110 MATRIX SPIKE SAMPLE: 167969 9227807001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Phosphorus mg /L 7.1 1 7.;ri0 90 -110 MO MATRIX SPIKE SAMPLE: 167971 9227680001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Phosphorus mg /L 3.6 l 5.0 137 90 -110 MO SAMPLE DUPLICATE: 167970 9227807002 Dup Max Parameter Units Result Result fl`C RPD Qualifiers Phosphorus mg /L 0.52 0.49 5 ?0 SAMPLE DUPLICATE: 167972 9227707001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Phosphorus mg /L 0.12 0.11 9 20 Date: 10 /0312008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 10 of 23 This report shall not be reproduced, except in full, without the written consent ]ofPace Analytical Services, Inc.. Page 14 of 38 Analytical Laboratory ,.�/ e Pace Analytical Services, Inc. Pace Analytical Services, Inc. _-i"aCeAnaiyticai 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 www.pace /abs.com Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)875 -9092 QUALITY CONTROL DATA Project: 08 -SEP -0240 Pace Project No.: 9227707 QC Batch: WET15458 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 9227707001 METHOD BLANK: 167976 Associated Lab Samples: 9227707001 Parameter Units ... _ ..............w..__ Total Suspended Solids mg /L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 1.0 09/15/0814:39 LABORATORY CONTROL SAMPLE: 167977 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg /L 250 240 96 80 -120 SAMPLE DUPLICATE: 167978 9227751001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg /L 11.7 16,0 31 20 R1 Date: 10/03/2008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 11 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Q�ere.� Y ty4 _ a acekialylical , www.pacelabs,com Project: 08 -SEP -0240 Pace Project No.: 9227707 QUALITY CONTROL DATA QC Batch: WETA/3473 Page 15 of 38 Analysis Method: EPA 351.2 Analytical Laboratory Pace Analytical Services, Inc. Pace Analytical Services, Inc. 2225 Riverside Dr. 9800 KinceyAve. Suite 100 Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)875 -9092 QUALITY CONTROL DATA QC Batch: WETA/3473 Analysis Method: EPA 351.2 QC Batch Method: EPA 351.2 Analysis Description: 351.2 TKN Associated Lab Samples: 9227707001 METHOD BLANK: 168200 Matrix: Water Associated Lab Samples: 9227707001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Kjeldahl, Total mg /L NQ 0.50 09/15/08 20:30 LABORATORY CONTROL SAMPLE: 168201 Spike LCS LCS %Rec - Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg /L 5 4.9 98 90 -110 MATRIX SPIKE SAMPLE: 168202 9227643002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg /L 1.7 5 5.3 F1 90 -110 MO � f� MATRIX SPIKE SAMPLE: 168204 9227643012 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg /L 1,4 5 6 -8 103 90 -110 SAMPLE DUPLICATE: 168203 9227643003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, Kjeldahl, Total mg /L 0.66 0.72 18 20 SAMPLE DUPLICATE: 168205 9227677001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, Kjeldahl, Total mg /L 1.3 1.5 15 20 Date: 10/03/2008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 12 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. weny� ! Date: 10103/2008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 13 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. k fE I Page 16 of 38 Analytical Laboratory ,� Pace Analytical Services, Inc. Pace Analytical Services, Inc. ° 1�;alceAnalyfical G 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 74aacam Asheville, NC 28804 Huntersville, NC 28078 i (828)254 -7176 (704)875 -9092 QUALITY CONTROL DATA Project: 08 -SEP -0240 Pace Project No.: 9227707 I QC Batch: WETA/3475 Analysis Method: EPA 420.4 QC Batch Method: EPA 420.4 Analysis Description: 420.4 Phenolics Associated Lab Samples: 9227707001 METHOD BLANK: 168285 Matrix: Water Associated Lab Samples: 9227707001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phenol mg /L NO 0.010 09/17/0816:44 LABORATORY CONTROL SAMPLE: 168286 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phenol mg /L 25; 0.26 105 90 -110 MATRIX SPIKE SAMPLE: 168287 9227048002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Phenol mg /L NO 25 NO 0 90 -110 M1 MATRIX SPIKE SAMPLE: 7882$3 9227666003 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Phenol mg /L 14 D 25 NILt 90 -110 M1 SAMPLE DUPLICATE: 168288 9227047003 Dup Max Parameter Units Result Result RP{7 RPD Qualifiers Phenol mg /L ND NO 20 SAMPLE DUPLICATE: 168290 9227700001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Phenol mg /L NO 0.012 20 ! Date: 10103/2008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 13 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. k fE I I i ��tta A a ff jj kk wrw".pa 100S.00m Project: 08 -SEP -0240 Pace Project No.: 9227707 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)2547176 QUALITY CONTROL DATA Page 17 of 38 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersvilie, NC 28078 (704)875 -9092 QC Batch: WETA/3476 Analysis Method: ASTM D516 -90 QC Batch Method: ASTM D516 -90 Analysis Description: ASTM D516 -90 Sulfate Water Associated Lab Samples: 9227707001 METHOD BLANK: 168291 Matrix: Water Associated Lab Samples: 9227707001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers ..... ....... —_ Sulfate m g /L ND 5.0 09/16/0813:51 LABORATORY CONTROL SAMPLE: 168292 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg /L 20 t£i 5 97 90 -110 MATRIX SPIKE SAMPLE: 168293 9227649005 Spike MS MS % Rec g Parameter Units Result Conc. Result % Rec Limits Qualifiers Sulfata mg /L 1' 9 20 i105 -19 75 -125 MO MATRIX SPIKE SAMPLE: 168295 9227708006 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Sulfate mg /L ND 20 ND A 75 -125 MO SAMPLE DUPLICATE: 168294 9227785001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Sulfate mg /L 161 160 .9 20 SAMPLE DUPLICATE: 168296 9227708007 Dup Max Parameter Units Result Result PI'D RPD Qualifiers Sulfate mg /L ND ND 20 Date: 10103/2008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 14 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. QUALITY CONTROL DATA Project: 08 -SEP -0240 Page 18 of 38 Analytical Laboratory Pace Analytical Services, Inc. Pace Analytical Services, Inc. accAnalytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 wwxpacelabs.cern Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)875 -9092 QUALITY CONTROL DATA Project: 08 -SEP -0240 Pace Project No.: 9227707 QC Batch: WETA13477 Analysis Method: SM 4500 -CI -E QC Batch Method: SM 4500 -CI -E Analysis Description: 4500 Chloride Associated Lab Samples: 9227707001 METHOD BLANK: 168297 Matrix: Water Associated Lab Samples: 9227707001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg /L NO 5.0 09/1610817:20 LABORATORY CONTROL SAMPLE: 168298 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg /L 20 21.0 105 90 -110 MATRIX SPIKE SAMPLE: 168299 9227527001 Spike MS MS % Rec Parameter Units Result Conc. Result % RPc Limits Qualifiers Chloride mg /L 2300 20 4260 9830 75 -125 M1 MATRIX SPIKE SAMPLE: 168301 9227708008 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chloride mg/L NO 20 NO .2 75 -125 M1 SAMPLE DUPLICATE: 168300 9227527002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Chloride mg /L 9390 8840 6 20 SAMPLE DUPLICATE: 168302 9227708009 Dup Max Parameter Units Result Result RPD RPD Qualifiers Chloride mg /L NO NO 20 Date: 10/03/2008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 15 of 23 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. Project: 08 -SEP -0240 Pace Project No.: 9227707 QC Batch: MPRP /3024 QC Batch Method: EPA 200.7 Associated Lab Samples: 9227707001 METHOD BLANK: 168952 Associated Lab Samples: 9227707001 Parameter Aluminum Arsenic Barium Boron Cadmium Chromium Cobalt Copper Iron Magnesium Manganese Nickel Selenium Silver Tin Titanium Zinc ug /L ug /L ug /L ug /L ug /L ug /L ug /L ug /L ug /L ug/L ug /L ug /L ug /L ug /L ug /L ug /L ug /L Units LABORATORY CONTROL SAMPLE: 168953 Page 19 of 38 Units Aluminum Analytical Laboratory Arsenic ug /L Barium ug /L Pace Analytical Services, Inc. Pace Analytical Services, Inc. r�'IAnalytical 2225 Riverside Dr. 9800 KinceyAve. Suite 100 ce wwripacelabs.com Asheville, NC 28804 Huntersville, NC 28078 Copper (828)254 -7176 (704)875 -9092 Project: 08 -SEP -0240 Pace Project No.: 9227707 QC Batch: MPRP /3024 QC Batch Method: EPA 200.7 Associated Lab Samples: 9227707001 METHOD BLANK: 168952 Associated Lab Samples: 9227707001 Parameter Aluminum Arsenic Barium Boron Cadmium Chromium Cobalt Copper Iron Magnesium Manganese Nickel Selenium Silver Tin Titanium Zinc ug /L ug /L ug /L ug /L ug /L ug /L ug /L ug /L ug /L ug/L ug /L ug /L ug /L ug /L ug /L ug /L ug /L Units LABORATORY CONTROL SAMPLE: 168953 Parameter Units Aluminum ug /L Arsenic ug /L Barium ug /L Boron ug /L Cadmium ug /L Chromium ug /L Cobalt ug /L Copper ug /L Iron ug /L Magnesium ug /L Manganese ug /L Nickel ug /L Selenium ug /L Silver ug /L Tin ug /L Titanium ug /L Zinc ug /L QUALITY CONTROL DATA Analysis Method: EPA 200.7 Analysis Description: 200.7 MET Matrix: Water LCS Result Blank Reporting 5000 Result Limit Analyzed ND 100 09/25/08 20:49 ND 5.0 09/25/08 20:49 ND 5.0 09/25/08 20:49 ND 50.0 09/25108 20:49 ND 1.0 09/25/08 20:49 ND 5.0 09/25/08 20:49 ND 5.0 09/25/08 20:49 NO 5.0 09/25/08 20:49 NO 50.0 09/25/08 20:49 ND 100 09/25108 20:49 NO 5.0 09/25/08 20:49 ND 5.0 09125/08 20:49 ND 10.0 09/25108 20:49 ND 5.0 09/25/08 20:49 NO 5.0 09/25/08 20:49 NO 5.0 09/25/08 20:49 ND 10.0 09/25/08 20:49 Qualifiers Spike Conc. LCS Result LCS % Rec % Rec Limits 5000 5080 102 85 -115 500 538 108 85 -115 500 510 102 85 -115 500 522 104 85 -115 500 523 105 85 -115 500 528 106 85 -115 500 511 102 85 -115 500 515 103 85 -115 5000 5180 104 85 -115 5000 5140 103 85 -115 500 526 105 85 -115 500 523 105 85 -115 500 552 110 85 -115 250 251 100 85 -115 500 515 103 85 -115 500 520 104 85 -115 500 536 107 85 -115 Qualifiers Date: 10/03/2008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 16 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. SAMPLE DUPLICATE: 168956 9227673001 Dup Page 20 of 38 Max Parameter Units Result Result RPD RPD Qualifiers Aluminum ug /L 969 Analytical Laboratory 2 ............. — 20 Arsenic ug /L ND ND 20 Barium ug /L 23.5 a 2 20 Boron ug/L Pace Analytical Services, Inc. 3170 Pace Analytical Services, Inc. a ce maly cal ug /L ND ND 20 2225 Riverside Dr. ug /L 9800 KlnceyAve. Suite 100 0blimm 1 20 Cobalt ug/L 10.2 Asheville, NC 28804 0 20 Huntersville, NC 28076 ug /L 26.8 28.1 5 20 Iron ug/L (828)254 -7176 1080 3 (704)875 -9092 Magnesium ug /L 998 QUALITY CONTROL DATA 3 20 Manganese ug /L Project: 08 -SEP -0240 18.0 2 20 Nickel ug /L 12.8 13.0 2 20 Pace Project No.: 9227707 ug /L ND ND 20 Silver ug /L ND ND MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 168954 ug /L ND 168955 20 Titanium ug /L 19.9 20.3 2 20 MS MSD 50.2 52.3 4 20 9227672001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conic. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug /L 328 5000 5000 5800 5890 109 111 70 -130 2 20 Arsenic ug /L ND 500 500 550 563 110 113 70 -130 2 20 Barium ug/L ND 500 500 533 540 106 108 70 -130 1 20 Boron ug /L 85.0 500 500 609 622 105 107 70 -130 2 20 Cadmium ug /L ND 500 500 536 540 107 108 70 -130 .7 20 Chromium ug/L 630 500 500 1210 1220 116 118 70 -130 .8 20 Cobalt ug /L ND 500 500 525 530 105 106 70 -130 .9 20 Copper ug /L ND 500 500 551 561 110 112 70 -130 2 20 Iron ug /L ND 5000 5000 5370 5420 107 108 70 -130 .9 20 Magnesium ug /L ND 5000 5000 5410 5460 107 108 70 -130 .9 20 Manganese ug /L ND 500 500 542 547 108 109 70 -130 .9 20 Nickel ug /L ND 500 500 541 545 108 109 70 -130 .7 20 Selenium ug /L ND 500 500 562 573 112 114 70 -130 2 20 Silver ug /L ND 250 250 262 267 105 107 70 -130 2 20 Tin ug /L ND 500 500 535 540 107 108 70 -130 .9 20 Titanium ug /L ND 500 500 537 543 107 - 109 70 -130 1 20 Zinc ug /L 39.4 500 500 594 603 111 113 70 -130 2 20 SAMPLE DUPLICATE: 168956 9227673001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Aluminum ug /L 969 991 2 ............. — 20 Arsenic ug /L ND ND 20 Barium ug /L 23.5 23.9 2 20 Boron ug/L 3110 3170 2 20 Cadmium ug /L ND ND 20 Chromium ug /L 20.2 20.0 1 20 Cobalt ug/L 10.2 10.2 0 20 Copper ug /L 26.8 28.1 5 20 Iron ug/L 1050 1080 3 20 Magnesium ug /L 998 1030 3 20 Manganese ug /L 17.6 18.0 2 20 Nickel ug /L 12.8 13.0 2 20 Selenium ug /L ND ND 20 Silver ug /L ND ND 20 Tin ug /L ND 4.8J 20 Titanium ug /L 19.9 20.3 2 20 Zinc ug /L 50.2 52.3 4 20 Date: 10/03/2008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 17 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. ,coati I aceAnalyfical www.paMabs,00m Project: 08 -SEP -0240 Pace Project No.: 9227707 QC Batch: WETA13486 QC Batch Method: EPA 350.1 i Associated Lab Samples: 9227707001 METHOD BLANK: 169416 Associated Lab Samples: 9227707001 Parameter Units Nitrogen, Ammonia mg /L Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 QUALITY CONTROL DATA Analysis Method: EPA 350.1 Analysis Description: 350.1 Ammonia Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.10 09/17/08 20:30 Page 21 of 38 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875 -9092 LABORATORY CONTROL SAMPLE: 169417 Spike LCS LCS % Rec MS Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg /L :5 5.3 106 90 -110 NO 5 5.7 '114 90 -110 MO SAMPLE DUPLICATE: 169419 MATRIX SPIKE SAMPLE: 169418 9227654001 9227651001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg /L 0.29 5 5.4 103 90 -110 MATRIX SPIKE SAMPLE: 169420 9227910002 Spike MS MS % Rec toAl� Parameter Units Result Conc. Result %o Rec Limits Qualifiers Nitrogen, Ammonia mg /L NO 5 5.7 '114 90 -110 MO SAMPLE DUPLICATE: 169419 9227654001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, Ammonia mg /L ND Nil 20 SAMPLE DUPLICATE:,- 169421 9227910003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, Ammonia mg /L ND NO 20 Date: 10103/2008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 18 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Y�= r aceAnalXicate www.pacelebs.00m f Project: 08 -SEP -0240 Pace Project No.: 9227707 QC Batch: WETA/3511 QC Batch Method: EPA 353.2 Associated Lab Samples: 9227707001 METHOD BLANK: 170839 Associated Lab Samples: 9227707001 Parameter Units Nitrogen, NO2 plus NO3 mg /L Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 QUALITY CONTROL DATA Analysis Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, preserved Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers NO 0.10 09/20/0812:26 Page 22 of 38 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875 -9092 LABORATORY CONTROL SAMPLE: 170840 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, NO2 plus NO3 mg /L 5 5.0 99 90 -110 MATRIX SPIKE SAMPLE: 170841 9227680001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, NO2 plus NO3 mg /L 161 5 24A 153 75 -125 MO MATRIX SPIKE SAMPLE: 170843 9227910009 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, NO2 plus NO3 mg /L N1) 5 5.t t0'? 75 -125 SAMPLE DUPLICATE: 170842 9227707001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, NO2 plus NO3 mg /L 0.94 0.94 0 20 SAMPLE DUPLICATE: 170844 9227910010 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, NO2 plus NO3 mg /L NO NO 20 Date: 10/0312008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 19 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 1 lUac'eAnalytical wwwpacelabs.com Project: 08 -SEP -0240 Pace Project No.: 9227707 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7176 QUALITY CONTROL DATA QC Batch: GCSV /3754 Analysis Method: EPA 1664A QC Batch Method: EPA 1664A Analysis Description: 1664 HEM, Oil and Grease Associated Lab Samples: 9227707001 METHOD BLANK: 171008 Associated Lab Samples: 9227707001 Parameter Emits Oil and Grease mg /L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers NCB 5.0 09/22/0810:44 Page 23 of 38 Analytical Laboratory Pace Analytical Services, Inc. 9800 KlnceyAve. Suite 100 Huntersville, NC 28078 (704)875 -9092 LABORATORY CONTROL SAMPLE: 171009 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Oil and Grease mg /L 40 36.0 90 78 -114 MATRIX SPIKE SAMPLE: 171010 5018622003 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Oil and Grease mg /L 6,7 42.6 49.0 99 78 -114 Date: 10 /03/2008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 20 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc -.11 aceAnalytical www..p&wlabs.com Project: 08 -SEP -0240 Pace Project No.: 9227707 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254 -7178 QUALITY CONTROL DATA QC Batch: MERP /1725 Analysis Method: EPA 245.1 QC Batch Method: EPA 245.1 Analysis Description: 2451 Mercury Associated Lab Samples: 9227707001 METHOD BLANK: 174972 Matrix: Water Associated Lab Samples: 9227707001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug /L ND 0.20 09/30/08 09:43 LABORATORY CONTROL SAMPLE: Parameter 174973 Units Mercury ug /L MATRIX SPIKE SAMPLE: Parameter 174974 Units Mercury ug /L SAMPLE DUPLICATE: 174975 Parameter Units Mercury ug /L Date: 10/03/2008 03:34 PM Page 24 of 38 Analytical Laboratory Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875 -9092 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 15 2.4 98 85 115 9227707001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 2.5 2.5 97 70 -130 9228780004 Dup Max Result Result RPD RPD Qualifiers ........... _. ND ND 20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. t c�Cr 4 r � Page 21 of 23 vnnrpaC01abs.00m QUALIFIERS Project: 08 -SEP -0240 Pace Project No.: 9227707 DEFINITIONS Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254.7176 Page 25 of 38 Analytical Laboratory Pace Analytical Services, Inc. 9800 KlnceyAve. Suite 100 Huntersville, NC 28078 (704)875 -9092 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. S - Surrogate 1,2- Diphenylhydrazine (8270 listed analyte) decomposes toAzobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes. ANALYTE QUALIFIERS B2 Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. MO Matrix spike recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. Date: 10/03/2008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 22 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Project: 08 -SEP -0240 Pace Project No.: 9227707 Lab ID Page 26 of 38 QC Batch Method Analytical Laboratory r m Pace Analytical Services, Inc. Pace Analytical Services, Inc. acaAnalXical 2225 Riverside Dc 9800 KlnceyAve. Suite 100 VIVIW Wabs.com Asheville, NC 28804 Huntersville, NC 28078 (828)254 -7176 (704)875 -9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE 28026404 SWO02 Project: 08 -SEP -0240 Pace Project No.: 9227707 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 9227707001 28026404 SWO02 SM 2120B WET15428 9227707001 28026404 SWO02 SM 52106 WET15431 SM 5210B WET 15439 9227707001 28026404 SWO02 SM 5220D WETA/3453 9227707001 28026404 SWO02 EPA 365.1 WETA/3464 9227707001 28026404 SWO02 SM 2540D WET /5458 9227707001 28026404 SWO02 EPA 351.2 WETA/3473 9227707001 28026404 SWO02 EPA 420.4 WETA13475 9227707001 28026404 SWO02 ASTM D516 -90 WETA/3476 - 9227707001 28026404 SWO02 SM 4500 -CI -E WETA/3477 9227707001 28026404 SWO02 EPA 200.7 MPRP /3024 EPA 200.7 ICP/2855 9227707001 28026404 SWO02 EPA 350.1 WETA/3486 9227707001 28026404 SWO02 EPA 353.2 WETA/3511 9227707001 28026404 SWO02 EPA 1664A GCSV /3754 9227707001 28026404 SWO02 EPA 245.1 MERP /1725 EPA 245.1 MERC /1721 Date: 10/03/2008 03:34 PM REPORT OF LABORATORY ANALYSIS Page 23 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 38 Analytical Laboratory Florida Radiochemistry Services, Inc. Sample Login Client: Pace Anaytical services Date / Time Work order 0 Received 09113108 09:45 0809089 Client Contact; Kevin Herring COW P.O. CHS 04699 Project I.D. 28026404 Lab Sample I.D. Client Sample I.D. Sample Analysis Date/rime Requested 0809085 -01 28026404 SWO02 09/1010818:00 Gross Alpha / Beta Analysis Results Gross Alpha c1.1 Gross Beta 4.8 Error +1. 0.7 Error +/. 1.2 MDL 1.1 MDL 1.6 EPA Method 900.0 EPA Method 900.0 Prep Data 09/18108 Prep Date 09118/08 Prep Time 06:40 Prop Time 06:40 Analysis pate 09/17/08 Analysis Date 09/17/08 Analysis Time 10:30 Analysis Time 10:90 Analyst MJN Analyst MJN Units pCUI Unite pCill Page 28 of 38 Analytical Laboratory •. Florida Radiochemistry Services, Inc. OA Page Anelyte Sample 0 Date Sample Amount Spike Spike /Dup Spike Spike Dup Analyzed Result Spiked Result Result % Rec. % Rpd Gross Alpha 0809084 -02 08/17/08 0.2 10.2 10.4 10.9 102 4.7 Gross Beta 0808084 -02 09/17/08 0.6 16.7 17.1 15.7 109 8.6 Duality Control Limits % RPD % Rec. Gross Alpha 21.8 62191 Gross Beta 16.7 80416 Page 29 of 38 Analytical Laboratory Correct Containers Used: ❑Yes VeKo ❑N /A `�n Pace Containers Used: ❑Yes IeNo ❑N /A C P(-,d j �l "�•� Y► �ur; .� . Containers Intact: es ONo ❑N /A 10. Filtered volume received for Dissolved tests ❑Yes ONo /A 11. Sample Labels match COC: ❑Yes�No ❑N /A 12. NvWQ[) r?k-v� MIS + 0 U q7' - Includes date /time /ID /Analysis Matrix: qu containers needing preservation have been checked, G� ,, /rJ res ONo C1 NIA 13. All containers needing preservation are found to be in compliance with EPA recommendation. des ❑No ❑NIA exceplions: VOA, coliform. TOC, 08G, WI•DRO (water) ❑Yes ❑No Y acaAr,alytim Client Name: Project # Courier: Q Fed Ex ❑ UPS ❑ USPS ❑ Client ❑ Commercial Z Pace Other Headspace in VOA Vials ( >6mm): Custody Seal on Cooler /Box Present: es Y ❑ no Seals intact: yes ,o to fit. [] no Y+�i • C' �. Packing Material: 0 Bubble Wrap ❑Bubble Bags None []Other r I.ii 7T.JRC.•L '�' . l Thermometer Used T060 Type of Ice: /1 0 Blue None C1 Samples on ice, cooling process has begun ONo LEA 'Pace Trip Blank Lot # (if purchased): N/A Cooler Temperature Biological Tissue is Frozen: Yes No N/A Date and In i s o pe examining Temp should be above freezing to 6 °C Comments: contents: Chain of Custody Present: j;�Yes ONo ON /A 1. Chain of Custody Filled Out: -21'es ONo OWA 2 Field Data Required? Y / N / N/A Chain of Custody Relinquished: BYes ONo ❑N /A 3• Sampler Name & Signature on COC: Byes ONo ❑N /A 4, Samples Arrived within Hold Time: ZiYes ONo ❑N /A 5. Short Hold Time Analysis ( <72hr): fYes ❑No ❑N /A 6, l� Rush Turn Around Time Requested: ❑Yes ,®No ❑N /A 7. Sufficient Volume: ❑Yes No C1 N/A ,g, \ a Correct Containers Used: ❑Yes VeKo ❑N /A `�n Pace Containers Used: ❑Yes IeNo ❑N /A C P(-,d j �l "�•� Y► �ur; .� . Containers Intact: es ONo ❑N /A 10. Filtered volume received for Dissolved tests ❑Yes ONo /A 11. Sample Labels match COC: ❑Yes�No ❑N /A 12. NvWQ[) r?k-v� MIS + 0 U q7' - Includes date /time /ID /Analysis Matrix: qu containers needing preservation have been checked, G� ,, /rJ res ONo C1 NIA 13. All containers needing preservation are found to be in compliance with EPA recommendation. des ❑No ❑NIA exceplions: VOA, coliform. TOC, 08G, WI•DRO (water) ❑Yes ❑No Initial when completed Samples checked for dechlorination:'J'�es ONo ❑NIA 14. Headspace in VOA Vials ( >6mm): ❑Yes ONo � 15, Trip Blank Present: ❑Yes ONo ..21VA '16. Trip Blank Custody Seals Present ❑Yes ONo LEA 'Pace Trip Blank Lot # (if purchased): N/A Client Notification/ Resolution: Field Data Required? Y / N / N/A Person Contacted: Date/Time: Comments/ Resolution: Project Manager Review: Date: III Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) � k ; Fi� Page Se# Analytical Laboratory � \ %� { n § ' i> ¥ { % |q + � .\ .m ,m } i\ .Q ■ 00 )� � � � . � \ � � { } � � � . ¥ @+_@_o_,w_- +l», dootrad mm__, � §� k Q k ƒ ƒ � k ; Fi� Page Se# Analytical Laboratory � \ %� { n § ' i> ¥ { % |q + � .\ .m ,m } i\ .Q ■ 00 )� � EPA ID Number (copy from item I of Form 1) Please print or type in the unshaded areas Page 31 of 38 Analytical Laboratory Form Approved, OMB No. 2040 -0086 Approval expires 5 -31 -92 Form 2F NPDES United States Environmental Protection Agency Washington, DC 20460 Application for Permit to Discharge Storm Water Discharges Associated with Industrial Activity Paperwork Reduction Act Notice Public reporting burden for this application is estimated to average 28.6 hours per application, including time far reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding the burden estimate, any other aspect of this collection of information or suggestions for improving this form, inducting suggestions which may increase or reduce this burden to: Chief, Information Policy Branch, P%223, U.S. Environmental Protection Agency, 401 M St, SW, Washington, DC 20460, or Director, Office of Information and Regulatory Affairs, Office of Managwneat and Budget Wasihingtan, DC 20503. _ I.Outfall Location For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receivin2 seater. A. Outfall Number Ifsr B. Latitude C. Longitude�me I7. Receiving Water SW O02 H. Improvements A. Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading or operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges descrlbed in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters. sti ulations, court orders, and grant or loan co ditions. 1. Identification of Condiflons, Agreements, Etc. 2. Affected Outfalls 3, Brief Des ori pdon of Pr 4. Final Com liance Date cumber source of discharne a li. r OL B. You may attach additional sheets describing any additional water pollutfan (or other environmental projects which may affect your discharges) you now have under way or which you plan. Indicate whether each program is now under way or planned, and indicate your actual or planned schedules for construction. M. Site Drains a Ms Attach a site map showing topography (or indicating the outline of drainage areas served by the outfall(s) covered in the application if a topographic map Is unavailable) depicting the facility including: each of its intake and discharge structures; the drainage area of each storm water outfall; paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for outdoor storage or disposal of significant materials, each existing structure control measure to reduce pollutants in stone water runoff, materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied; each of its hazardous waste treatment, storage or disposal units (including each are not required to have a RCRA permit which is used for accumulating hazardous waste under 40 CFR 262.34); each well where fluids from the facility are injected underground; springs, and other surface water bodies which receive storm water discharges from the facility. EPA Form 3510 -2F (Rev. 1 -92) Page 1 of 3 Continued on Page 2 Page 32 of 38 Analytical Laboratory Continued from the Front IV. lydriailvtt UWZ*t:ra UUZ1 UI rullutdrlt 7Vuru A. For each outfall, provide an estimate of the area (include units) of impervious surfaces (including paved areas and building roofs) drained to the outfall, and an estimate of the total surface area drained b y the outfall. Outfall Area of Impervious Surface Total Area Drained Outfali Area of Impervious Surface Total Area Drained Number (provide units) (provide units Number rovide units) provide units) SWO02 B. Provide a narrative description of significant materials that are currently or in the past three years have been treated, stored or disposed in a manner to allow exposure to stone water; method of treatment, storage, or disposal; past and present materials management practices employed to minimize contact by these materials with storm water runoff; materials loading and access areas; and the location, manner, and frequency in which pesticides, herbicides, soil conditioners, and fertilizers are applied. C. For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in storm water runoff; and a description of the treatment the storm water receives, including the schedule and type of maintenance for control and treatment measures and the ultlmate disposal of any solid or fluid wastes other than by dischar e. Outfall List Codes from Number Treatment Table 2F -1 SWO02 V. Nan Stormwater Discharges A. I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of nonstormwater discharges, and that all nonstormwater discharges from these outfall(s) are identified in either an accompanying Form 2C or Form 2E application for the outfall. Name of Official Title (type or print) Signature Date Signed B. proVide a description of the method used, the date of any testin , and the onsite drainage points that were directly observed during a test. VI. Significant teaks or Spills Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three ears, including the approximate date and location of the spill or leak, and the type and amount of material released. EPA Form 3510 -2F (Rev. 1 -92) Page 2 of 3 Continued on Page 3 Page 33 of 38 Analytical Laboratory EPA ID Number (copy from Item I of Form 1) Continued from Page 2 f VII. Dischar a Information A,B,C, & D: See instruction before proceeding. Complete one set of tables for each outfall. Annotate the outfall number in the space provided. Tables Vii -A, VII -B, and VII -C are included on separate sheets numbered VII -1 and VII -2. E. Potential discharges not covered by analysis - is any toxic pollutant listed in table 2F -2, 2F -3, or 2F -4, a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct? ❑ Yes (list all such pollutants below) No (go to Section IX) Vlll. Etiological Toxicity Testing Data Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? ❑ Yes (list all such pollutants below) ❑ No (go to Section /X) IX. Contact analysis Information Were any of the analysis reported in item VII performed by a contact laboratory or consulting firm? ® Yes (list the name, address, and telephone number of and pollutants ❑ No (go to Section X) analyzed by, each such laboratory or firm below) A. Name B. Address C. Area Code & Phone No. D. Pollutants Analyzed Pace Analytical Services, Inc 9800 Kincey Ave Suite 100 704 -875 -9092 Oil &Grease/ Huntersville, NC 28078 Organic Pace Analytical Services, Inc 2225 Riverside Dr 828 -254 -7176 Asheville, NC 28804 Wet chemistry & metals X. Certification I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. _ A. Name & Official Title (type orprint) B. Area Code and Phone No. C. Signature D. Date Signed EPA Form 3510 -2F (Rev. 1 -92) Page 3 of 3 EPA ID Number (copy from Item I of Form 1) Page 34 of 38 Analytical Laboratory Form Approved. OMB No. 2040 -0086 Approval expires 5 -31 -92 VII. Discharge Information Continued from page 3 of Form 2F Part A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. Sae instructlons for additional details. Maximum Values Average Values Number Pollutant firtelude units fin cfa units Of And Storm Grab Sample Grab Sample CAS Number Taken During Flow- weighted Taken During Flow- weighted Events (if avadahle) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Oil & Grease 27 -6 mg1L NIA 13.$ mglL 2 Biological Oxygen 5.2 mglL 1 Demand SODS Chemical Oxygen 49.0 mglL 1 Demand (COD) Total Suspended 67.7 mglL 40.4 mglL 2 Solids ff SS Total 2.24 mg1L 1 Nitrogen Total 0.12 mgtL 1 Ph ❑s horns PH itiRW um Maximum L Minimum Maximum Part B - List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES permit for its process wastewater (if the facility is operating under an existing NPDES permit). Complete one table for each outfall. See the instructions for additional details and r uirements. Maximum Values Average Values Number Pollutant Intrude uni% finclu de units Of And Grab Sample Grab Sample Storm CA$ Number Taken During Flow - weighted Taken During Flow- weighted Events (ifavallable) First 30 Composite First 30 Composite Sampted Minutes Mlnutes Sources of Pollutants Bromide (24959 -67 -9) Chlorine. Total residual Ammonia (as N) 0.90 mg1L 0.55 mglL 2 Chloride 5.8 mglL 2.9 ntg1L 2 Color 180 units 90 units 2 Fluoride (16984 -48 -8) Nitrate-Nitrite (as f3) 1.0mgIL 0.97 mglL 2 Radioactivity, alpha a 1.1 k 0.7 1 total 17CUL Radioactivity, beta 4.$ t 1,2 1 total CIIL Radioactivity, radium toter Radioactivity, radium 226 total Sulfate (as SO;) 20.7 mglL 19.0 mg1L 2 (14808 -79-8 Sulfite (as SO,) 1426545-3) Aluminum. Total 1.58 mg1L 1 1429 -90-a Barium, Total 0,0517 mgll. 1 7440.39 -3 Boron, Total (7440- 0.0915 mgIL 1 42.8 Cobalt, Total (7440- <0.005 rng1L 1 48-4 Iron, Total t7439-89 -6) 5.79 mglL 1 — Magnesium, Total 3.52 mglL 1 7439 -95.4 Magnesium, Dissolved Molybdenum, Total 7439.98 - EPA Form 3510 -2F (Rev. 1 -92) Page VII -1 Continue on Reverse Page 35 of 38 Analytical Laboratory Manganese, Total 0.117 mg /L 1 7439 -96 -5) Tin, Total <0.005 mg/L 7440 -31 -5) Titanium, Total 0.0813 mg /L 1 7440 -32 -6 Antimony, Total (7440 -36 -0 Arsenic, Total <0.005 mg /L 1 7440 -38 -2 Beryllium, Total 7440 -41 -7) Cadmium, Total 0.0012 mg /L 1 _(7440 -43 -9 Chromium, Total <0.005 mg /L 1 (7440 -47 -3 Copper, Total 0.0333 mg /L 1 7440 -50 -8) Lead, Total 7439 -92 -1) Mercury, Total <0.020 ug /L 1 7439-97-6 Nickel, Total <0.005 7440 -02 -0) Selenium, Total 0.0562 mg /L 1 7782-49-2 Silver, Total <0.005 mg /L 1 7440 -22 -4) Thallium, Total 7440 -28 -0) Zinc, Total 0.486 mg /L 1 (7440 -66 -6 EPA Form 3510 -2F (Rev. 1 -92) Page VII -1 Continue on Reverse Page 36 of 38 Analytical Laboratory Continued from the Front Part C - List each pollutant shown in Tables 2F -2, 2F -3, and 2F -4 that you know or have reason to believe is present. Seethe instructions for additional details and requirement& Coup iete one table for each autfall. - Maximum Values Pollutant rnrludo units And Grab Sample CAS Number Taken During Flow - weighted (if available) first 30 composite Minutes Average Values rnaluda writs Number of Storm - Events Sampled Sources of Pollutants Grab Sample Takers During First 30 i Minutes Flow- weighted Composite Cyanide, Total 57 -12 -5 Phenols, Total s0.010 mgg/L 1 Surfactants (MBAs) Total Dissolved Solids TTotal Organic Carbon Total Kjeldahl 1.3 mgtL Nitro9an KN ; Fecal Coliform Part D - Provide data for the storm event (s) which resulted_ in the maximum values for the fiow weighted com osite sample. 1. Date of Storm Event 2. Duration of Storm Event (in minutes) 3. Total rainfall during storm event (in inches ) � 4. Number of hours between beginning of storm measured and end of previous measurable rain event 5. Total flow from rain event (gallons or•specify units) 7. Provide a description of the method of flow measurement or estimate. EPA Form 3510 -2F (Rev. 1 -92) Page VII -2 Page 37 of 38 Analytical Laboratory EPA Form 3510 -2F (Rev. 1 -92) Page VII -2 Ciutanmrta 0 e a d Page 38 of 38 Analytical Laboratory aalnntp a a _.R q a e G 'C p4 p C ` C} aaFii O rMMJ b V ' a ` i i t1� e n rz M- C� q 'fir F o � IN r L P N M 3� OE "a * -S G 0) -V Customer, important: please Indicate desired turnaround O " ' m D s e cl a w C 0 S O m 9 C �a Ciutanmrta 0 e a d Page 38 of 38 Analytical Laboratory aalnntp l0 rl _.R i - m Y to p4 p C ` C} aaFii O n i i c �► e M- C� q 'fir F o IN `p L _ N M 3� OE "a G iv i 2T..i MA, NG'002 F#=0 Collrarm i i C� q 'fir F qy `p L MA, NG'002 F#=0 Collrarm i V, y1��t ' � m I "a / i Chi N P,Jbaflnlsae � � � jj SCI ,a TKN, TP, COD q q z liAS.t} �`7 r_n =i Rndlurn i29 ,j'� ; —iC Total rk C%onrAlno d FOR AGENCY USE ONLY • Division of Water Quality / Surface Water Protection Date Received _ Year Month Day NCDENR National Pollutant Discharge Elimination System NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES REPRESENTATIVE OUTFALL STATUS (ROS) REQUEST FORM If a facility is required to sample multiple discharge locations with very similar stormwater discharges, the permittee may petition the Director for Representative Outfall Status (ROS). DWQ may grant Representative Outfall Status if stormwater discharges from a single outfall are representative of discharges from multiple outfalls. Approved ROS will reduce the number of outfalls where analytical sampling requirements apply. if Representative Outfall Status is granted, ALL outfalls are still subject to the qualitative monitoring requirements of the facility's permit — unless otherwise allowed by the permit (such as NCGO20000) and DWQ approval. The approval letter from DWQ must be kept on site with the facility's Stormwater Pollution Prevention Plan. The facility must notify DWQ in writing if any changes affect representative status. For questions, please contact the DWQ Regional Office for your area (see page 3). (Please print or type) 1) Enter the permit number to which this ROS request applies: Individual Permit (or) Certificate of Coverage N I C S , N C G -` 2) Facility Information: Owner /Facility Name Duke Energy Carolinas, LLC Riverbend Steam Station 175 Steam Plant Road, Mount Holly, NC 28120 Facility Contact Street Address City E -mail Address Telephone No. Mark McGary PO Box 1006 Mail Code EC13K Charlotte State NC ZIP Code 28201 Mark.McGary@duke - energy.com 980 - 373 -7898 Fax: 3) List the representative outfall(s) information (attach additional sheets if necessary): Outfall(s) SWO04 is representative of Outfalls SW004, SW005, SW007, SW010, SW011 SWO12 & SWO14 Outfalls' drainage areas have the same or similar activities? w*'Ies ❑ No Outfalls' drainage areas contain the same or similar materials? VYes ❑ No Outfalls have similar monitoring results? ❑ Yes ❑ No i Ao data* Outfall(s) SWO02 is representative of Outfalls SW001, SW002, SW003, SWO06 and SWO08 Outfalls' drainage areas have the same or similar activities? sYes ❑ No Outfalls' drainage areas contain the same or similar materials? @KYes ❑ No Outfalls have similar monitoring results? ❑ Yes ❑ No Ao data* *Non - compliance with analytical monitoring prior to this request may prevent ROS approval. Specific circumstances will be considered by the Regional Office responsible for review. 4) Detailed explanation about why the outfalls above should be granted Representative Status: (Or, attach a letter or narrative to discuss this information.) For example, describe how activities and /or materials are similar. See attached representative outfalls summary table Page 1 of 3 SWU -ROS -2009 Last revised 12/30/2009 Representative Outfall Status Request 5) Certification: North Carolina General Statute 143 -215.6 B(i) provides that: Any person who knowingly makes any false statement, representation, or certification in any application, record, report, plan, or other document filed or required to be maintained under this Article or a rule implementing this Article; or who knowingly makes a false statement of a material fact in a rulemaking proceeding or contested case under this Article; or who falsifies, tampers with, or knowingly renders inaccurate any recording or monitoring device or method required to be operated or maintained under this Article or rules of the [Environmental Management] Commission implementing this Article shall be guilty of a Class 2 misdemeanor which may include a fine not to exceed ten thousand dollars ($10,000). I hereby request Representative Outfall Status for my NPDES Permit. I understand that ALL outfalls are still subject to the qualitative monitoring requirements of the permit, unless otherwise allowed by the permit and regional office approval. I must notify DWQ in writing if any changes to the facility or its operations take place after ROS is granted that may affect this status. If ROS no longer applies, I understand I must resume monitoring of all outfalls as specified in my NPDES permit. I certify that I am familiar with the information contained in this application and that to the best of my knowledge and belief such information is true, complete, and accurate. Printed Name of Person Signing: Terry L Taylor k-"" rI. /" v! , r Title: General Manager II (Signature Applicant) (Date Signed) Please note: This application for Representative Outfall Status is subject to approval by the NCDENR Regional Office. The Regional Office may inspect your facility for compliance with the conditions of the permit prior to that approval. Final Checklist for ROS Request This application should include the following items: ❑ This completed form. ❑ Letter or narrative elaborating on the reasons why specified outfalls should be granted representative status, unless all information can be included in Question 4. • Two (2) copies of a site map of the facility with the location of all outfalls clearly marked, including the drainage areas, industrial activities, and raw materials /finished products within each drainage area. • Summary of results from monitoring conducted at the outfalls listed in Question 3. • Any other supporting documentation. 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