14006 Classic Coffee EA Rpt 20120316

REPORT OF ENVIRONMENTAL ASSESSMENT

FORMER PLIANA FACILITY
1016 AND 1024 MONTANA DRIVE
CHARLOTTE, MECKLENBURG COUNTY, NORTH CAROLINA
Prepared for:
ROYAL PACIFIC CORPORATION
1016 MONTANA DRIVE
CHARLOTTE, NORTH CAROLINA

Prepared By:
AMEC ENVIRONMENT & INFRASTRUCTURE, INC. 2801 YORKMONT ROAD, SUITE 100 CHARLOTTE, NORTH CAROLINA 28208
MARCH 16, 2012
AMEC PROJECT: 6228-09-5055
Former Pliana Facility – Report of Environmental Assessment March 16, 2012 1016 and 1024 Montana Drive, Charlotte, North Carolina AMEC Project 6228-09-5055

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TABLE OF CONTENTS

1. SITE HISTORY AND CHARACTERIZATION ............................................................................... 1
2. HISTORICAL ENVIRONMENTAL ASSESSMENT INFORMATION .......................................... 3
3. ASSESSMENT ACTIVITIES ........................................................................................................... 5
3.1 GROUNDWATER SAMPLING ACTIVITIES ......................................................................................................... 5
3.2 SUB-SLAB SOIL-GAS SAMPLING ACTIVITIES .................................................................................................... 6
3.3 RECEPTOR SURVEY ASSESSMENT ACTIVITIES................................................................................................... 7
3.3.1 Water-Supply Wells .................................................................................................................... 7
3.3.2 Public Water Supplies ................................................................................................................. 8
3.3.3 Surface Water ............................................................................................................................ 8
3.3.4 Wellhead Protection Areas ......................................................................................................... 8
3.3.5 Deep Aquifers in the Coastal Plain Physiographic Region .......................................................... 8
3.3.6 Subsurface Structures ................................................................................................................. 8
3.4 LABORATORY ANALYTICAL RESULTS .............................................................................................................. 8
3.4.1 Groundwater Results .................................................................................................................. 8
3.4.2 Groundwater QA/QC Results ...................................................................................................... 9
3.4.3 Sub-Slab Soil-Gas Analytical Results ......................................................................................... 10
4. CONCLUSIONS ............................................................................................................................. 11

LIST OF APPENDICES
APPENDIX A – Figures
APPENDIX B – Monitoring Well Sampling Field Data Sheets
APPENDIX C – Tables
APPENDIX D – Laboratory Analytical Reports and Chain-of-Custody Forms
APPENDIX E – Receptor Survey Registered-Mail Receipts and Returned Survey Forms
LIST OF FIGURES FIGURE 1 – Site Location/Surrounding Properties
FIGURE 2 – Site Layout Map
FIGURE 3 – Well Survey Map
LIST OF TABLES
TABLE 1 – Groundwater Analytical Results – Volatile Organic Compounds (VOCs) and
Semi-Volatile Organic Compounds (SVOCs)
TABLE 2 – Groundwater Analytical Results – Metals TABLE 3 – Sub-Slab Soil-Gas Analytical Results
TABLE 4 – Hourly Weather Observations for January 19, 2012
Former Pliana Facility – Report of Environmental Assessment March 16, 2012 1016 and 1024 Montana Drive, Charlotte, North Carolina AMEC Project 6228-09-5055
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1. SITE HISTORY AND CHARACTERIZATION

The 4.47-acre subject property (subject property) is located at 1016 and 1024 Montana
Drive in Charlotte, North Carolina and consists of Mecklenburg County Tax Parcels 069-
155-40 (1024 Montana Drive) and 069-155-41 (1016 Montana Drive). The subject
property contains three buildings, an approximately 16,572-square foot light
manufacturing building constructed in 1965, an approximately 26,510-square foot
warehouse building constructed in 1997 and an approximately 14,236-square foot
warehouse building constructed in 1962. Remaining portions of the site are asphalt-
paved driveway and parking areas and grass covered areas. The site is currently
occupied by the Classic Coffee Concepts, Inc. A topographic is provided as Figure 1
and a site layout map is provided as Figure 2 in Appendix A.

The original building at 1016 Montana Drive was operated as a production facility for
Chem-Tex Laboratories, Inc. (Chem-Tex) prior to 1999. Chem-Tex produced textile-
cleaning products by blending and processing raw materials into finished products that
were transported off site in bulk containers and smaller drummed quantities. In
approximately 1999, Chem-Tex vacated the property and removed chemicals,
processing and packaging equipment, and waste material from the subject property.
From 1999 to approximately 2010, Pliana, Inc. occupied the front office space of the
building at 1016 Montana Drive and utilized the main portion of the building for storage
of yarn product. In 2010, Pearl Pacific Properties, LLC purchased the property and
utilizes the subject property to store coffee brewing equipment and supplies.

The subject property is located within the Charlotte Belt of the Piedmont Physiographic
Province. Based on a review of the Geologic Map of North Carolina (1985), the site is
underlain by granitic rock.
The Soil Survey of Mecklenburg County indicates that soils at the subject property are
classified as Cecil-Urban land complex. Urban soils consist of areas where more than
85 percent of the surface area is covered with asphalt, concrete, buildings or other
impervious cover.
Based on the USGS topographic map, the elevation of the subject property ranges from
approximately 670 to 700 feet above mean sea level. Surface drainage patterns within
Former Pliana Facility – Report of Environmental Assessment March 16, 2012 1016 and 1024 Montana Drive, Charlotte, North Carolina AMEC Project 6228-09-5055
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the Piedmont typically indicate the direction contaminants would be transported by
surface water or groundwater. Based on our interpretation of the topographic map and
on-site observations, surface water on the property would primarily be expected to flow
south-southeast toward Stewart Creek.
The direction and movement of groundwater through soil is dependent on soil type and
the presence of relict structures and textures of the underlying rock. Fractures, faults,
folds and foliation planes affect the migration of groundwater in rock. Since no
significant geologic features were identified on the site, it is reasonable to assume that
the direction of groundwater flow under static conditions (no pumping interference)
approximates the surface topography of the site. Groundwater at the property would be
expected to flow south-southeast toward Stewart Creek.
Former Pliana Facility – Report of Environmental Assessment March 16, 2012 1016 and 1024 Montana Drive, Charlotte, North Carolina AMEC Project 6228-09-5055
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2. HISTORICAL ENVIRONMENTAL ASSESSMENT INFORMATION

Based on the results of a Phase I Environmental Site Assessment Update (dated
November 5, 1999) completed by AMEC (as LAW) a Phase II Environmental Site
Assessment was conducted at the former Chem-Tex facility. In 1999, analysis of soil
samples collected at the 1016 site identified concentrations of Total Chromium above
background levels. Concentrations of volatile organic compounds (VOCs) were
detected, including the presence of 2-Butanone (MEK) and Acetone at concentrations of
0.11 mg/kg and 0.66 mg/kg, respectively, as well as, trace amounts of tetrachloroethene
and 1,1,1-trichloroethane.

In 2002, AMEC (as MACTEC) completed a Phase I Environmental Site Assessment
Update (report dated July 26, 2002) of both parcels. Several areas of chemically-
damaged concrete flooring were observed adjacent to floor drains within the plant building
at 1024 Montana Drive. Corroded flooring beneath a vat located within the plant was also
observed. In the 2002 update report, AMEC recommended soil sampling at 1024
Montana Drive to assess the potential impact of chemical products to soil; and
groundwater sampling at 1016 Montana Drive.

In May 2006, AMEC (as MACTEC) completed a Phase II Environmental Assessment on
behalf of a prospective purchaser of the property. Four monitoring wells were installed
(MW-1016, MW-1024, MW-1 and MW-2) at the locations shown on Figure 2. Soil and
groundwater samples were collected and analyzed.

The analytical results of the soil samples 1016-1 and 1016-2 identified elevated
concentrations of total chromium, but they did not exceed the applicable state standards.
Furthermore, hexavalent chromium (Chromium VI) was not identified in these samples.
Therefore, the identified total chromium is presumed to be Chromium III, which is less
toxic than chromium VI. Furthermore, the soil analytical results identified concentrations of
tetrachloroethene (PCE) ranging from 7.5 to 18 parts per billion (ppb) at the 1016 and
1024 parcels.

The groundwater analytical results identified concentrations of the organic solvent PCE
at concentrations ranging from 51 to 150 ppb in water samples MW-1016, MW-1024,
MW-1 and MW-2. The North Carolina Administrative Code 15A Subchapter 2L –
Former Pliana Facility – Report of Environmental Assessment March 16, 2012 1016 and 1024 Montana Drive, Charlotte, North Carolina AMEC Project 6228-09-5055
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Groundwater Classifications and Standard, dated January 2010 (NC 2L Standard) for
PCE is 0.7 ppb. Trichloroethene, 1,1-dichloroethene and 1,2-dichloroethane were also
identified at concentrations that exceeded their respective NC 2L standards.

On July 23 and 27, 2009 AMEC personnel collected groundwater samples from three of
the four wells. Well MW-1016 was apparently paved over by a previous occupant and
could not be sampled. The samples were placed on ice and delivered to Pace Analytical
Services, Inc. (PACE) for analysis of VOCs (EPA Method 6200B). The groundwater
analytical results identified concentrations of the organic solvent PCE at concentrations
ranging from 32.8 to 74.9 ppb in water samples MW-1024, MW-1 and MW-2.
Trichloroethene, 1,1-dichloroethene and 1,2-dichloroethane were also identified at
concentrations that exceeded their respective NC 2L standards.
Former Pliana Facility – Report of Environmental Assessment March 16, 2012 1016 and 1024 Montana Drive, Charlotte, North Carolina AMEC Project 6228-09-5055
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3. ASSESSMENT ACTIVITIES
3.1 Groundwater Sampling Activities
On January 19, 2012, AMEC personnel mobilized to the subject property to sample the
three remaining groundwater monitoring wells (MW-1024, MW-1 and MW-2) at the
subject property. The locations of the monitoring wells are depicted on Figure 2. Prior
to sampling, the water level was measured in each well with an electric water level
indicator to determine the depth to the water surface from the top of the PVC riser pipe.
The measured water depth was used in conjunction with the total casing depth to
determine the height of the water column and the volume of the water in each monitoring
well.

AMEC personnel purged each monitoring well of at least three casing volumes of
groundwater prior to sampling. During purging of the well, groundwater characteristics
(pH, conductivity, turbidity, dissolved oxygen, temperature and oxidation reduction
potential) were obtained to aid in determining an adequate purge volume as well as
evaluate the general groundwater chemistry. After purging was complete, a
groundwater sample was collected from each well using a disposable PVC bailer. A
blind duplicate sample was collected from location MW-2 for QA/QC purposes. The
collected groundwater samples were placed in laboratory-provided containers with
appropriate preservatives, placed in an ice-filled sample cooler and delivered to PACE in
Huntersville, North Carolina for laboratory analysis. The samples were maintained
under a chain-of-custody protocol and were submitted for laboratory analysis of VOCs
via EPA Method 8260B, semi-volatile organic compounds (SVOCs) via EPA Method
8270C, and 13 Hazardous Substance List metals plus total and hexavalent chromium.
Monitoring well sampling field data sheets are included in Appendix B.

Former Pliana Facility – Report of Environmental Assessment March 16, 2012 1016 and 1024 Montana Drive, Charlotte, North Carolina AMEC Project 6228-09-5055
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3.2 Sub-slab Soil-Gas Sampling Activities

AMEC selected six sub-slab soil-gas sampling locations at the subject property, at which
sampling ports were installed. One port was installed near the office portion of the
building at 1016 Montana Drive (SG-1), one was installed near the loading ramp of the
building at 1016 Montana Drive (SG-2), one was installed in the center of the warehouse
portion of the building at 1016 Montana Drive (SG-3), one was installed in the center of
the southern building at 1024 Montana Drive (SG-4), one was installed in the warehouse
portion of the northern building at 1024 Montana Drive (SG-5) and one was installed
near the office portion of the northern building at 1024 Montana Drive (SG-6). The six
sub-slab soil-gas sampling locations are depicted on Figure 2.
On January 18, 2012, AMEC personnel mobilized to the subject property to install the six
sub-slab soil-gas sampling locations. The sample locations were installed and sampled
in general accordance with the “Supplemental Guidelines for the Evaluation of Structural
Vapor Intrusion Potential for Site Assessments and Remedial Actions Under the Inactive
Hazardous Sites Branch”, dated June 21, 20011. Prior to advancement of the borings,
AMEC retained a private utility locator, Priority Underground Locating Service (Priority),
to check the sampling locations for buried utilities. After locating utilities, under the
direction of AMEC personnel, Priority advanced a one-inch diameter borehole through
the concrete slab to the native soil using a hammer drill. After Priority advanced the
borehole, AMEC personnel advanced a dedicated soil-gas sampling tip approximately
12 inches beneath the concrete slab using an AMS Manual Soil Vapor Probe kit. The kit
consists of a dedicated soil-gas sampling tip, a 5/8” x 3’ soil-gas vapor probe rod and a
slide hammer. Teflon® tubing was attached to the dedicated sampling tip and threaded
through the probe rod prior to advancement of the probe rod. The probe rod was
advanced to a depth of approximately 12 inches below the base of the concrete slab and
then retracted, leaving the dedicated sampling tip and tubing in the borehole. The
annular space of the borehole was then filled with cement to the surface. The seal was
left to cure for 24 hours prior to sampling.
On January 19, 2012, AMEC personnel returned to the subject property to sample the
six sub-slab soil-gas sampling locations. A helium shroud was installed around the
sample tubing to assist with collection of soil-gas samples with no breakthrough of
outside air. The helium shroud consisted of a bucket which surrounded the sample
Former Pliana Facility – Report of Environmental Assessment March 16, 2012 1016 and 1024 Montana Drive, Charlotte, North Carolina AMEC Project 6228-09-5055
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tubing and contained a valve which allowed helium to be added to the bucket and
measured with a detector. A Dielectric MGD-2002 helium detector was used to measure
the concentration of helium within the shroud. Prior to connecting a six liter Summa
canister to the sample tubing, stagnant air inside the tubing was purged using a hand
pump. After purging was complete, a sample was collected into the Summa canister at
a flow rate of approximately 12.5 mL/min (8-hour sample time). The samples were
submitted to Pace for laboratory analysis of VOCs by EPA Method TO-15 and helium by
EPA Method 3C. The samples were maintained under a chain-of-custody protocol.
Hourly weather observations for the weather station at the Charlotte Douglas
International Airport (KCLT) (approximately 5.5 mile west-southwest from the subject
property) were obtained from Weather Underground. During the eight hour sample
collection period, the average temperature was 42.1 °F, the average barometric
pressure was 30.16 in. of Hg, the average wind speed was 6.0 mph, the average wind
direction was south and the average precipitation was 0.0 in. A summary of the hourly
weather data obtained from Weather Underground is provided in Table 4.

3.3 Receptor Survey Assessment Activities
The receptor survey included identification of water-supply wells, public water supplies,
surface waters, wellhead protection areas, subsurface structures, land use, and property
owners and occupants. The following sections provide our results of the receptor
investigation.
3.3.1 Water-Supply Wells
AMEC personnel conducted a potable well search by walking through the surrounding
neighborhood within 500 feet of the source area, and performed a driving
reconnaissance of streets and properties within 1,500 feet, and searched Mecklenburg
County water-supply well data available on the Mecklenburg County Well Information
System 2.0. No water-supply wells were identified on properties adjacent to the subject
property. AMEC identified one water-supply well within a half-mile radius of the subject
property. The water-supply well was identified at 512 Ingle Street and is used for
drinking water at the same address. The identified well is approximately 2,040 feet to
the southwest and upgradient of the subject property. A well survey map is included as
Figure 3.
Former Pliana Facility – Report of Environmental Assessment March 16, 2012 1016 and 1024 Montana Drive, Charlotte, North Carolina AMEC Project 6228-09-5055
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3.3.2 Public Water Supplies
AMEC observed water-meter vaults along the streets and sidewalks while walking within
500 feet of the site. AMEC mailed water-supply well information surveys to adjacent
property owners. AMEC received a limited response from the adjacent property owners.
Returned Receptor Survey Registered-Mail Receipts and Returned Survey Forms are
included in Appendix E.

3.3.3 Surface Water
Stewart Creek traverses the eastern portion of the subject property from north to south.

3.3.4 Wellhead Protection Areas
The subject property is not in a wellhead protection area.

3.3.5 Deep Aquifers in the Coastal Plain Physiographic Region
The subject property is not located in the Atlantic Coastal Plain Physiographic Province of
North Carolina.

3.3.6 Subsurface Structures
Basements were not observed at the subject property, and were not confirmed at
adjacent buildings.

3.4 Laboratory Analytical Results
3.4.1 Groundwater Results
The results of the organic groundwater laboratory analyses identified tetrachloroethene
(PCE) in the three monitoring wells (MW-1024 (68.4 µg/L), MW-1 (23.7 µg/L) and MW-2
(24.0 µg/L)). The concentrations of PCE reported exceeded the NC 2L Standard for
PCE of 0.7 µg/L in each of the three wells. Trichloroethene (TCE) was identified in wells
MW-1024 (3.3 µg/L) and MW-2 (3.4 µg/L) at a concentration which exceeded the NC 2L
Standard for TCE of 3.0 µg/L. Concentrations of 1,1-dichloroethane and 1,1-
dichloroethene identified in wells MW-1 (15.0 µg/L and 7.7 µg/L, respectively) and MW-2
(19.8 µg/L and 16.0 µg/L, respectively) exceeded the NC 2L Standards for 1,1-
dichloroethane (6.0 µg/L) and 1,1-dichloroethene (7.0 µg/L). Other VOCs and SVOCs
identified during the 2012 sampling event did not exceed their respective NC 2L
Former Pliana Facility – Report of Environmental Assessment March 16, 2012 1016 and 1024 Montana Drive, Charlotte, North Carolina AMEC Project 6228-09-5055
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Standards. A summary of the current and historical VOC and SVOC groundwater
laboratory analytical results is provided in Table 1.

The results of the metals groundwater laboratory analysis identified chromium and
manganese in wells MW-1024 (0.03 mg/L and 1.61 mg/L, respectively) and MW-1
(0.0573 mg/L and 1.61 mg/L, respectively) at concentrations which exceeded their NC
2L Standards (chromium 0.01 mg/L and manganese 0.05 mg/L). Manganese was also
detected in well MW-2 (0.222 mg/L) at a concentration which exceeded the NC 2L
Standard. In addition, mercury was identified in well MW-2 (0.0015 mg/L) at a
concentration which exceeded the NC 2L Standard of 0.001 mg/L. Other metals
identified during the 2012 sampling event did not exceed their respective NC 2L
Standards. A summary of the current and historical metals groundwater laboratory
analytical results is provided in Table 2.

3.4.2 Groundwater QA/QC Results
For QA/QC purposes, a duplicate sample (Duplicate) was collected from well MW-2 to
measure the precision of the laboratory data or how consistent or reproducible the field
sampling or analytical procedures have been. Precision is usually expressed as the
relative standard deviation, variance, percent difference, or a range, in either absolute or
relative terms. When two separate samples are collected from replicate locations (i.e.,
field duplicates), relative percent difference (RPD) is used to measure precision. RPD is
calculated as follows:
RPD = ()100*2/


+
−
BA
BA
Where A = Replicate Result 1
B = Replicate Result 2
Generally, laboratory precision is considered acceptable at levels of 20% or less. The
RPD between samples MW-2 and Duplicate in general ranged from 0 % to 6.9 %, with
the exception of the zinc results at 49 %.

A trip blank was used to determine whether the samples were being contaminated
during transit or storage. Trip blanks are samples of reagent water prepared by the
laboratory and are shipped and stored with the samples. A trip blank was submitted with
the cooler that contained the VOC samples. The results of the laboratory analysis of the
Former Pliana Facility – Report of Environmental Assessment March 16, 2012 1016 and 1024 Montana Drive, Charlotte, North Carolina AMEC Project 6228-09-5055
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trip blank identified methylene chloride at a concentration of 2.7 µg/L. However,
methylene chloride was not identified in the samples from the three monitoring wells
above the laboratory reporting limit (2.0 µg/L) and therefore, is considered a laboratory
contaminant.

3.4.3 Sub-Slab Soil-Gas Analytical Results
The results of the sub-slab soil-gas analysis identified several VOCs in each of the six
sub-slab soil-gas samples collected. Most notably, PCE was identified in soil-gas
samples SG-1, SG-2, SG-3, SG-5 and SG-6, with the concentrations identified in
samples SG-5 (719 µg/m3) and SG-6 (1,690 µg/m3) exceeding the NCDENR Inactive
Hazardous Sites Branch (IHSB) Industrial/Commercial Acceptable Soil-Gas
concentration for PCE of 210 µg/m3. In addition, TCE was identified in soil-gas samples
SG-1, SG-2, SG-3 and SG-5 at concentrations below the NCDENR IHSB
Industrial/Commercial Acceptable Soil-Gas concentration of TCE of 610 µg/m3. Other
VOC constituents concentrations identified above their respective laboratory reporting
limits did not exceed their respective NCDENR IHSB Acceptable Soil-Gas
concentrations. Helium was not detected in the six sub-slab soil-gas samples above the
laboratory detection limits, confirming that no leaks were present during the sampling.
Former Pliana Facility – Report of Environmental Assessment March 16, 2012 1016 and 1024 Montana Drive, Charlotte, North Carolina AMEC Project 6228-09-5055
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4. CONCLUSIONS

Based on the results from the 2012 assessment activities, AMEC concludes the
following:

• The PCE concentrations in groundwater reported during the 2012
sampling event represented a decrease in concentration from the previous sampling event in 2009. The PCE concentrations reported in well MW-1024 decreased from 78.9 µg/L to 68.4 µg/L, in well MW-1 from
32.8 µg/L to 23.7 µg/L and in well MW-2 from 47.4 µg/L to 24.0 µg/L.
However, the concentrations of PCE reported in the three wells exceeded the NC 2L Standard for PCE (0.7 µg/L).

• The TCE concentrations in groundwater reported during the 2012
sampling event represented a decrease in concentration from the previous sampling event in 2009. The TCE concentrations reported in well MW-1024 were 3.3 µg/L in 2012 and 2009 and decreased in well
MW-1 from 1.3 µg/L to <1.0 µg/L and in well MW-2 from 7.0 µg/L to 3.4 µg/L. However, the concentrations of TCE reported in wells MW-1024
and MW-2 exceeded the NC 2L Standard for TCE (3.0 µg/L).

• Concentrations of 1,1-dichloroethane and 1,1-dichloroethene reported
during the 2012 sampling event represented a decrease in concentrations in groundwater from the previous sampling event in 2009. 1,1-
Dichloroethane was not detected in the sample from well MW-1024 and
decreased in well MW-1 from 20.2 µg/L to 15.0 µg/L and in well MW-2 from 37.7 µg/L to 19.8 µg/L. However, the concentrations of 1,1-
dichloroethane reported in wells MW-1 and MW-2 exceeded the NC 2L
Standard of 6.0 µg/L. 1,1-Dichloroethene decreased in well MW-1 from 15.5 µg/L to 7.7 µg/L and in well MW-2 from 33.8 µg/L to 16.0 µg/L. The
concentrations of 1,1-dichloroethene reported in MW-1 and MW-2 exceeded the NC 2L Standard of 7.0 µg/L. In addition, the concentration of 1,1-dichloroethene identified in well MW-1024 (1.1 µg/L) represented
an increase from 2009 (0.98 µg/L). However, the concentration reported
in MW-1024 did not exceed the NC 2L Standard.
• The presence of 1,1-dichloroethane and 1,1-dichloroethene, and cis-1,2-dichloroethene which are considered daughter products of 1,1,1-
trichloroethane, PCE and TCE, and the general decrease in concentrations of 1,1,1-dichloroethane, PCE and TCE suggest that the natural attenuation of 1,1,1-dichloroethane, PCE and TCE is occurring in
the groundwater at the subject property.
• The total chromium concentrations identified in groundwater during the 2012 sampling event represented a decrease in concentration from the previous sampling event in 2009. The total chromium concentration
reported in well MW-1024 decreased from 0.10 mg/L to 0.03 mg/L, in well MW-1 from 0.059 mg/L to 0.0573 mg/L and in well MW-2 from 0.013 mg/L
Former Pliana Facility – Report of Environmental Assessment March 16, 2012 1016 and 1024 Montana Drive, Charlotte, North Carolina AMEC Project 6228-09-5055
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to <0.005 mg/L. However, the concentrations of total chromium reported
in wells MW-1024 and MW-1 exceeded the NC 2L Standard of 0.01 mg/L.

• Hexavalent chromium was not detected in the three monitoring wells
sampled above the laboratory reporting limit of 0.05 mg/L.
• Manganese was reported in wells MW-1024 (1.61 mg/L), MW-1 (1.61 mg/L) and MW-2 (0.222 mg/L) at concentrations which exceeded the NC
2L Standard of 0.05 mg/L in the groundwater. The samples from the
2009 sampling event were not analyzed for manganese.
• In general, based on the QA/QC results, the precision of the laboratory data is considered acceptable. In addition, the identification of methylene
chloride in the trip blank and not in the groundwater samples indicates
that the methylene chloride is present as laboratory contamination. Methylene chloride is used in laboratories as a solvent and is a known
common laboratory contaminant.

• PCE was detected in sub-slab soil-gas samples SG-5 and SG-6 at a
concentration which exceeded the NCDENR IHSB Acceptable Soil-Gas concentration of 210 µg/m3.

• Helium was used as a leak-check during soil-gas sample collection and
was not detected in the six sub-slab soil-gas samples above laboratory
detection limits indicating breakthrough of outside air did not occur during sample collection.

• No water-supply wells were identified on properties adjacent to the
subject property. One water-supply well was identified within a half-mile
radius of the subject property. The water-supply well was identified at 512 Ingle Street and is used for drinking water at the subject property.
The identified well is approximately 2,040 feet to the southwest same address upgradient of the subject property.
Former Pliana Facility – Report of Environmental Assessment March 16, 2012 1016 and 1024 Montana Drive, Charlotte, North Carolina AMEC Project 6228-09-5055

APPENDIX A
FIGURES
PREPAREDBY DATE CHECKEDBY DATE JOB NUMBER FIGURE
0 2,000 4,000 6,000 8,0001,000 Feet
16228-09-5055
Source: USDA-NRCS Digital Raster Graphic Mosaic for Mecklenburg County, NC, dated 2005.
§¨¦77
§¨¦85
§¨¦277
§¨¦77
£¤29
£¤74
£¤74£¤29
PROJECT VICINITY
Charlotte, NC
SITE LOCATION/SURROUNDING PROPERTIESFORMER PLIANA FACILITY1016 AND 1024 MONTANA DRIVECHARLOTTE, NORTH CAROLINA
r
SITE LOCATION
Site Location
PREPAREDBY DATE CHECKEDBY DATE JOB NUMBER FIGURE
0 150 300 450 60075Feet
26228-09-5055
Source: Mecklenburg County Aerial Photography, dated 2009.
!P
!P
U!U !P !P
!U
!P
!U
!P
M O N T A N A D RI-8 5
Stew ar t C k
SG-1
SG-2
MW-1016
MW-1 SG-3 SG-4
MW-2
SG-5MW-1024
SG-6
SITE LAYOUT MAPFORMER PLIANA FACILITY1016 AND 1024 MONTANA DRIVECHARLOTTE, NORTH CAROLINA
rSite Boundary
!U Approximate Monitoring Well Location
!P Approximate Soil-Gas Sample Location
U Former Location of MW-1016
AE (100-Year Floodplain)
100-Year Floodplain Future Conditions
100-Year Floodplain Future Conditions Contained in Culvert
1016
1024
PREPAREDBY DATE CHECKEDBY DATE JOB NUMBER FIGURE
0 800 1,600 2,400 3,200400Feet
36228-09-5055
Source: Mecklenburg County Aerial Photography, dated 2009.I-8 5
5 0 0 '1 ,0 0 0 '0 .5 m i le
!?
730 710690730710 770750690710
7307307507
5
0750
690
750
710770
6
9
0
710
710
75073
0
730
6
9
0
750770770670750
73
0
700 700700700
700
700
740
720720760
720
740720740
760740680740760
760
680720
7407
4
0 680680WELL SURVEY MAPFORMER PLIANA FACILITY1016 AND 1024 MONTANA DRIVECHARLOTTE, NORTH CAROLINA
r
Water-SupplyWell
512 Ingle Street Subject Property Boundary Streams 10ft Contour LineStewart Ck
Former Pliana Facility – Report of Environmental Assessment March 16, 2012 1016 and 1024 Montana Drive, Charlotte, North Carolina AMEC Project 6228-09-5055

APPENDIX B MONITORING WELL SAPMLING FIELD DATA SHEETS

Former Pliana Facility – Report of Environmental Assessment March 16, 2012 1016 and 1024 Montana Drive, Charlotte, North Carolina AMEC Project 6228-09-5055

APPENDIX C TABLES

Constituent MW-1026 Duplicate Trip Blank
Sampling Date 5/23/2006 5/23/2006 7/23/2009 1/19/2012 5/23/2006 7/23/2009 1/19/2012 5/23/2006 7/27/2009 1/19/2012 1/19/2012 1/19/2012
Chloroform 2.3 3.1 2.9 2.6 1.4 0.8 <1.0 0.56 0.6 <1.0 <1.0 <1.0 70
1,1-Dichloroethane 35.0 <0.5 <0.5 <1.0 27.0 20.2 15.0 51.0 37.7 19.8 18.8 <1.0 6.0
1,1-Dichloroethene <0.5 <0.5 0.98 1.1 29.0 15.5 7.7 41.0 33.8 16.0 15.2 <1.0 7.01,2-Dichloroethane 43.0 <0.5 <0.5 <1.0 <0.5 <0.5 <1.0 2.2 2.0 <1.0 <1.0 <1.0 0.4cis-1,2-Dichloroethene 6.7 7.5 4.7 4.1 9.0 3.7 2.2 3.4 2.8 1.0 <1.0 <1.0 70Diisopropyl ether <0.5 <0.5 <0.5 <1.0 6.9 <0.5 <1.0 2.1 2.1 <1.0 <1.0 <1.0 70
Methylene Chloride <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 2.7 5.0
Naphthalene <2.0 <2.0 <2.0 1.7 <2.0 <2.0 <1.0 <2.0 <2.0 <1.0 <1.0 <1.0 6.0
Tetrachloroethene 150 140 74.9 68.4 51.0 32.8 23.7 56.0 47.4 24.0 22.4 <1.0 0.7
1,1,1-Trichloroethane 8.0 <0.5 <0.5 <1.0 2.2 <0.5 <1.0 15.0 5.1 1.8 1.8 <1.0 200
Trichloroethene 3.1 3.1 3.3 3.3 1.7 1.3 <1.0 10.0 7.0 3.4 3.4 <1.0 3.0
Total Xylenes 1.4 <0.5 <0.5 <3.0 <0.5 <0.5 <3.0 <0.5 <0.5 <3.0 <3.0 <3.0 500
Butylbenzylphthalate NA NA NA 13.5 NA NA <10.0 NA NA <10.0 <10.0 NA 1,000
Notes:
1. Concentrations shown in µg/L (micrograms per liter)Prepared By/Date:AJF 1-31-12
Standards, January 2010 Checked By/Date:RCF 1-31-12
3. Bold concentrations exceed the NC 2L Standard
4. Duplicate sample was collected from monitoring well MW-2
5. NA = Not Analyzed
6. MW-1026 not sampled in 2009 and 2012 because well could not be located
Table 1: Groundwater Analytical Results - Volatile Organic Compounds (VOCs) and Semi-Volatile Organic Compounds (SVOCs)
Former Pliana FacilityCharlotte, North Carolina
AMEC Project: 6228-09-5055
2. NC 2L Standard = North Carolina Administrative Code 15A Subchapter 2L - Groundwater Classifications and
NC 2L StandardMW-1024 MW-1 MW-2
Volatile Organic Compounds
Semi-Volatile Organic Compounds
Constituent MW-1016 Duplicate
Sampling Date 5/23/2006 5/23/2006 1/19/2012 5/23/2006 1/19/2012 5/23/2006 1/19/2012 1/19/2012
Antimony, Total ----<0.005 --<0.005 --<0.005 <0.005 NSLArsenic, Total <0.005 0.0064 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005
Arsenic, Dissolved 0.044 0.05 --0.054 --0.07 ----
Beryllium, Total ----<0.001 --0.001 --<0.001 <0.001 NSL
Barium, Total 0.66 0.78 --0.37 --0.48 ----
Barium, Dissolved 0.016 <0.005 --0.03 --0.058 ----
Cadmium, Total <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001
Cadmium, Dissolved <0.001 <0.001 --<0.001 --<0.001 ----
Chromium, Total 0.39 0.10 0.03 0.059 0.0573 0.013 <0.005 <0.005
Chromium, Dissolved 0.0056 0.0023 --0.023 --0.004 ----
Copper, Total NA NA 0.0413 NA 0.133 NA 0.0212 0.0214 1.0
Lead, Total 0.024 0.035 0.0063 0.014 0.0085 0.024 <0.005 <0.005
Lead, Dissolved 0.059 0.064 --0.059 --0.078 ----
Manganese, Total ----1.61 --1.61 --0.222 0.217 0.05
Mercury, Total <0.0002 <0.0002 <0.0002 0.0013 <0.0002 <0.0002 0.0015 0.0014
Mercury, Dissolved <0.0002 <0.0002 --<0.0002 --<0.0002 ----
Nickle, Total ----<0.005 --0.0339 --<0.005 <0.005 0.1
Selenium, Total <0.005 <0.005 <0.01 <0.005 <0.01 <0.005 <0.01 <0.01
Selenium, Dissolved <0.005 <0.005 --<0.005 --<0.005 ----
Silver, Total <0.002 <0.002 <0.005 0.002 <0.005 <0.002 <0.005 <0.005
Silver, Dissolved <0.002 <0.002 --<0.002 --<0.002 ----
Thallium, Total ----<0.01 --<0.01 --<0.01 <0.01 NSL
Zinc, Total ----0.168 --0.172 --0.134 0.222 1.0
Hexavalent Chromium, Total ----<0.05 --<0.05 --<0.05 <0.05 NSL
Notes:
1. Concentrations shown in mg/L (milligrams per liter)Prepared By/Date:AJF 1-31-12
Classifications and Standards, January 2010 Checked By/Date:RCF 1-31-12
3. Bold concentrations exceed the NC 2L Standard
4. Duplicate sample was collected from monitoring well MW-2
5. Groundwater samples collected in 2009 were not analyzed for total metal concentrations
6. MW-1016 was not sampled in 2012 because well could not be located
7. -- = Not Analyzed
0.001
0.02
0.02
2. NC 2L Standard = North Carolina Administrative Code 15A Subchapter 2L - Groundwater
Table 2: Groundwater Analytical Results - Metals
Former Pliana FacilityCharlotte, North Carolina
AMEC Project: 6228-09-5055
MW-1024 MW-1 MW-2 NC 2L Standard
0.01
0.7
0.002
0.01
0.015
Constituent SG-1 SG-2 SG-3 SG-4 SG-5 SG-6
NC IHSB
Industrial/Commercial
Acceptable Soil-Gas
Concentrations
Acetone 8.3 20.5 36.5 5.7 43.6 200 280,000
Benzene <0.44 <0.47 0.52 0.57 <0.47 <0.47 160
2-Butanone (MEK)0.92 2.0 6.4 6.7 0.92 4.6 44,000
Carbon disulfide <0.84 2.1 16.7 <0.84 2.1 12.7 6,200
Carbon tetrachloride <0.86 <0.92 <0.89 <0.86 <0.92 30.5 200
Chloromethane <0.56 <0.60 <0.58 1.0 <0.60 0.77 780
Dichlorodifluoromethane 2.4 2.6 2.4 2.9 2.5 2.8 880
Ethyl acetate <0.98 3.0 2.5 8.5 <1.1 <1.1 NSL
n-Hexane 1.6 12.2 2.3 <0.96 <1.0 1.9 6,200
Methylene chloride 8.3 24.6 <0.99 <0.95 1.4 5.3 2,600
4-Methyl-2-pentanone (MIBK)<1.1 <1.2 <1.2 <1.1 <1.2 1.6 26,000
Styrene <1.2 <1.3 1.3 1.5 <1.3 <1.3 8,800
Tetrachloroethene 19.4 144 1.2 <0.92 719 1,690 350
THC as Gas 658 944 427 <81.5 789 1,890 NSL
Toluene 1.0 5.1 4.3 5.0 1.5 6.5 44,000
1,1,1,-Trichloroethane 10.5 18.8 <1.5 <1.5 <1.6 44.4 44,000
Trichloroethene 0.82 17.3 1.3 <0.74 1.8 <0.79 17.6
Trichlorofluoromethane <1.5 <1.6 5.5 1.6 1.7 1.6 6,200
1,1,2-Trichlorotrifluoroethane <2.1 <2.3 <2.2 <2.1 10.6 <2.3 NSL
1,2,4-Trimethylbenzene 1.6 1.7 <1.4 <1.3 1.6 1.9 62
Helium <5.0 <4.4 <5.7 <3.3 <6.3 <4.6 NSL
Notes:
1. Concentrations shown in µg/m3 Prepared By/Date:AJF 1-31-12
2. NC IHSB - North Carolina Inactive Hazardous Sites Branch
3. Bold concentrations exceed NC IHSB Industrial/Commercal Acceptable Soil-Gas Checked By/Date:RCF 1-31-12
Concentrations, February 2012
4. NSL - No Standard Listed
5. THC - Total Hydrocarbons
6. Helium used as leak check
Table 3: Sub-Slab Soil-Gas Analytical ResultsFormer Pliana FacilityCharlotte, North Carolina
AMEC Project: 6228-09-5055
Time (EST)Temperature (°F)Pressure (in. of Hg)Wind Speed (mph)Wind Direction Precipitaion (in.)
8:52 33.1 30.22 5.8 ENE 0.0
9:52 36.0 30.21 5.8 SE 0.0
10:52 39.9 30.21 5.8 SSE 0.0
11:52 41.0 30.18 4.6 S 0.0
12:52 46.0 30.15 5.8 Variable 0.0
13:52 46.0 30.12 5.8 SSW 0.0
14:52 46.0 30.12 4.6 SSW 0.0
15:52 46.0 30.11 8.1 SSW 0.0
16:52 45.0 30.10 8.1 SSW 0.0
Average 42.1 30.16 6.0 S 0.0
Notes:
1. Data collected at Charlotte Douglas International Airport (KCLT)Prepared By/Date:AJF 1-31-12
2. Data obtained from Weather Underground (www.wunderground.com)
3. EST = Eastern Standard Time Cheked By/Date:RCF 1-31-12
4. °F = Degrees Fahrenheit
5. in. of Hg = Inches of Mercury
6. mph = Miles per hour
7. in. = Inches
Table 4: Hourly Weather Observations for January 19, 2012Former Pliana FacilityCharlotte, North Carolina
AMEC Project: 6228-09-5055
Former Pliana Facility – Report of Environmental Assessment March 16, 2012 1016 and 1024 Montana Drive, Charlotte, North Carolina AMEC Project 6228-09-5055

APPENDIX D LABORATORY ANALYTICAL REPORTS AND CHAIN-OF-CUSODY FORMS

January 26, 2012
LIMS USE: FR - ROB FOSTER
LIMS OBJECT ID: 92110579
92110579
Project:
Pace Project No.:
RE:
Mr. Rob FosterAMEC-Charlotte2801 Yorkmont Road Suite 100Charlotte, NC 28208
PLIANA 6228-09-5055
Dear Mr. Foster:
Enclosed are the analytical results for sample(s) received by the laboratory on January 19, 2012.
The results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Renee Spencer forKevin Godwin
[e-mail] Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Received and reviewed by AJF 1/26/2012
CERTIFICATIONS
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001South Carolina Drinking Water Cert. #: 99006003Virginia Drinking Water Certification #: 00213
Connecticut Certification #: PH-0104Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84Louisiana DHH Drinking Water # LA 100031West Virginia Certification #: 357Virginia/VELAP Certification #: 460144
Asheville Certification IDs2225 Riverside Dr., Asheville, NC 28804Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030North Carolina Drinking Water Certification #: 37712North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001Virginia Certification #: 00072West Virginia Certification #: 356Virgina/VELAP Certification #: 460147
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92110579001 MW-1024 EPA 6010 13 PASI-ASHB
EPA 7470 1 PASI-ADMB
EPA 8270 74 PASI-CBPJ
EPA 8260 63 PASI-CKJM
EPA 7196 1 PASI-ADMN
92110579002 MW-1 EPA 6010 13 PASI-ASHB
EPA 7470 1 PASI-ADMB
EPA 8270 74 PASI-CBPJ
EPA 8260 63 PASI-CKJM
EPA 7196 1 PASI-ADMN
92110579003 MW-2 EPA 6010 13 PASI-ASHB
EPA 7470 1 PASI-ADMB
EPA 8270 74 PASI-CBPJ
EPA 8260 63 PASI-CKJM
EPA 7196 1 PASI-ADMN
92110579004 DUPLICATE EPA 6010 13 PASI-ASHB
EPA 7470 1 PASI-ADMB
EPA 8270 74 PASI-CBPJ
EPA 8260 63 PASI-CKJM
EPA 7196 1 PASI-ADMN
92110579005 TRIP BLANK EPA 8260 63 PASI-CKJM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Sample: MW-1024 Lab ID: 92110579001 Collected: 01/19/12 12:30 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010
Antimony ND ug/L 1 01/23/12 16:40 7440-36-001/20/12 10:505.0
Arsenic ND ug/L 1 01/23/12 16:40 7440-38-201/20/12 10:505.0
Beryllium ND ug/L 1 01/23/12 16:40 7440-41-701/20/12 10:501.0
Cadmium ND ug/L 1 01/23/12 16:40 7440-43-901/20/12 10:501.0
Chromium 30.0 ug/L 1 01/23/12 16:40 7440-47-301/20/12 10:505.0
Copper 41.3 ug/L 1 01/23/12 16:40 7440-50-801/20/12 10:505.0
Lead 6.3 ug/L 1 01/23/12 16:40 7439-92-101/20/12 10:505.0
Manganese 1610 ug/L 1 01/23/12 16:40 7439-96-501/20/12 10:505.0
Nickel ND ug/L 1 01/23/12 16:40 7440-02-001/20/12 10:505.0
Selenium ND ug/L 1 01/23/12 16:40 7782-49-201/20/12 10:5010.0
Silver ND ug/L 1 01/23/12 16:40 7440-22-401/20/12 10:505.0
Thallium ND ug/L 1 01/23/12 16:40 7440-28-001/20/12 10:5010.0
Zinc 168 ug/L 1 01/23/12 16:40 7440-66-601/20/12 10:5010.0
7470 Mercury Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury ND ug/L 1 01/25/12 17:37 7439-97-601/24/12 15:350.20
8270 MSSV Semivolatile Organic Analytical Method: EPA 8270 Preparation Method: EPA 3510
Acenaphthene ND ug/L 1 01/25/12 16:38 83-32-901/23/12 12:0010.0
Acenaphthylene ND ug/L 1 01/25/12 16:38 208-96-801/23/12 12:0010.0
Aniline ND ug/L 1 01/25/12 16:38 62-53-301/23/12 12:0010.0
Anthracene ND ug/L 1 01/25/12 16:38 120-12-701/23/12 12:0010.0
Benzo(a)anthracene ND ug/L 1 01/25/12 16:38 56-55-301/23/12 12:0010.0
Benzo(a)pyrene ND ug/L 1 01/25/12 16:38 50-32-801/23/12 12:0010.0
Benzo(b)fluoranthene ND ug/L 1 01/25/12 16:38 205-99-201/23/12 12:0010.0
Benzo(g,h,i)perylene ND ug/L 1 01/25/12 16:38 191-24-201/23/12 12:0010.0
Benzo(k)fluoranthene ND ug/L 1 01/25/12 16:38 207-08-901/23/12 12:0010.0
Benzoic Acid ND ug/L 1 01/25/12 16:38 65-85-001/23/12 12:0050.0
Benzyl alcohol ND ug/L 1 01/25/12 16:38 100-51-601/23/12 12:0020.0
4-Bromophenylphenyl ether ND ug/L 1 01/25/12 16:38 101-55-301/23/12 12:0010.0
Butylbenzylphthalate 13.5 ug/L 1 01/25/12 16:38 85-68-701/23/12 12:0010.0
4-Chloro-3-methylphenol ND ug/L 1 01/25/12 16:38 59-50-701/23/12 12:0020.0
4-Chloroaniline ND ug/L 1 01/25/12 16:38 106-47-801/23/12 12:0020.0
bis(2-Chloroethoxy)methane ND ug/L 1 01/25/12 16:38 111-91-101/23/12 12:0010.0
bis(2-Chloroethyl) ether ND ug/L 1 01/25/12 16:38 111-44-401/23/12 12:0010.0
bis(2-Chloroisopropyl) ether ND ug/L 1 01/25/12 16:38 108-60-101/23/12 12:0010.0
2-Chloronaphthalene ND ug/L 1 01/25/12 16:38 91-58-701/23/12 12:0010.0
2-Chlorophenol ND ug/L 1 01/25/12 16:38 95-57-801/23/12 12:0010.0
4-Chlorophenylphenyl ether ND ug/L 1 01/25/12 16:38 7005-72-301/23/12 12:0010.0
Chrysene ND ug/L 1 01/25/12 16:38 218-01-901/23/12 12:0010.0
Dibenz(a,h)anthracene ND ug/L 1 01/25/12 16:38 53-70-301/23/12 12:0010.0
Dibenzofuran ND ug/L 1 01/25/12 16:38 132-64-901/23/12 12:0010.0
1,2-Dichlorobenzene ND ug/L 1 01/25/12 16:38 95-50-101/23/12 12:0010.0
1,3-Dichlorobenzene ND ug/L 1 01/25/12 16:38 541-73-101/23/12 12:0010.0
1,4-Dichlorobenzene ND ug/L 1 01/25/12 16:38 106-46-701/23/12 12:0010.0
3,3'-Dichlorobenzidine ND ug/L 1 01/25/12 16:38 91-94-101/23/12 12:0020.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 4 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Sample: MW-1024 Lab ID: 92110579001 Collected: 01/19/12 12:30 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
8270 MSSV Semivolatile Organic Analytical Method: EPA 8270 Preparation Method: EPA 3510
2,4-Dichlorophenol ND ug/L 1 01/25/12 16:38 120-83-201/23/12 12:0010.0
Diethylphthalate ND ug/L 1 01/25/12 16:38 84-66-201/23/12 12:0010.0
2,4-Dimethylphenol ND ug/L 1 01/25/12 16:38 105-67-901/23/12 12:0010.0
Dimethylphthalate ND ug/L 1 01/25/12 16:38 131-11-301/23/12 12:0010.0
Di-n-butylphthalate ND ug/L 1 01/25/12 16:38 84-74-201/23/12 12:0010.0
4,6-Dinitro-2-methylphenol ND ug/L 1 01/25/12 16:38 534-52-101/23/12 12:0020.0
2,4-Dinitrophenol ND ug/L 1 01/25/12 16:38 51-28-501/23/12 12:0050.0
2,4-Dinitrotoluene ND ug/L 1 01/25/12 16:38 121-14-201/23/12 12:0010.0
2,6-Dinitrotoluene ND ug/L 1 01/25/12 16:38 606-20-201/23/12 12:0010.0
Di-n-octylphthalate ND ug/L 1 01/25/12 16:38 117-84-001/23/12 12:0010.0
bis(2-Ethylhexyl)phthalate ND ug/L 1 01/25/12 16:38 117-81-701/23/12 12:006.0
Fluoranthene ND ug/L 1 01/25/12 16:38 206-44-001/23/12 12:0010.0
Fluorene ND ug/L 1 01/25/12 16:38 86-73-701/23/12 12:0010.0
Hexachloro-1,3-butadiene ND ug/L 1 01/25/12 16:38 87-68-301/23/12 12:0010.0
Hexachlorobenzene ND ug/L 1 01/25/12 16:38 118-74-101/23/12 12:0010.0
Hexachlorocyclopentadiene ND ug/L 1 01/25/12 16:38 77-47-401/23/12 12:0010.0
Hexachloroethane ND ug/L 1 01/25/12 16:38 67-72-101/23/12 12:0010.0
Indeno(1,2,3-cd)pyrene ND ug/L 1 01/25/12 16:38 193-39-501/23/12 12:0010.0
Isophorone ND ug/L 1 01/25/12 16:38 78-59-101/23/12 12:0010.0
1-Methylnaphthalene ND ug/L 1 01/25/12 16:38 90-12-001/23/12 12:0010.0
2-Methylnaphthalene ND ug/L 1 01/25/12 16:38 91-57-601/23/12 12:0010.0
2-Methylphenol(o-Cresol) ND ug/L 1 01/25/12 16:38 95-48-701/23/12 12:0010.0
3&4-Methylphenol(m&p Cresol) ND ug/L 1 01/25/12 16:3801/23/12 12:0010.0
Naphthalene ND ug/L 1 01/25/12 16:38 91-20-301/23/12 12:0010.0
2-Nitroaniline ND ug/L 1 01/25/12 16:38 88-74-401/23/12 12:0050.0
3-Nitroaniline ND ug/L 1 01/25/12 16:38 99-09-201/23/12 12:0050.0
4-Nitroaniline ND ug/L 1 01/25/12 16:38 100-01-601/23/12 12:0020.0
Nitrobenzene ND ug/L 1 01/25/12 16:38 98-95-301/23/12 12:0010.0
2-Nitrophenol ND ug/L 1 01/25/12 16:38 88-75-501/23/12 12:0010.0
4-Nitrophenol ND ug/L 1 01/25/12 16:38 100-02-701/23/12 12:0050.0
N-Nitrosodimethylamine ND ug/L 1 01/25/12 16:38 62-75-901/23/12 12:0010.0
N-Nitroso-di-n-propylamine ND ug/L 1 01/25/12 16:38 621-64-701/23/12 12:0010.0
N-Nitrosodiphenylamine ND ug/L 1 01/25/12 16:38 86-30-601/23/12 12:0010.0
Pentachlorophenol ND ug/L 1 01/25/12 16:38 87-86-501/23/12 12:0025.0
Phenanthrene ND ug/L 1 01/25/12 16:38 85-01-801/23/12 12:0010.0
Phenol ND ug/L 1 01/25/12 16:38 108-95-201/23/12 12:0010.0
Pyrene ND ug/L 1 01/25/12 16:38 129-00-001/23/12 12:0010.0
1,2,4-Trichlorobenzene ND ug/L 1 01/25/12 16:38 120-82-101/23/12 12:0010.0
2,4,5-Trichlorophenol ND ug/L 1 01/25/12 16:38 95-95-401/23/12 12:0010.0
2,4,6-Trichlorophenol ND ug/L 1 01/25/12 16:38 88-06-201/23/12 12:0010.0
Surrogates
Nitrobenzene-d5 (S) 56 % 1 01/25/12 16:38 4165-60-001/23/12 12:0021-110
2-Fluorobiphenyl (S) 61 % 1 01/25/12 16:38 321-60-801/23/12 12:0027-110
Terphenyl-d14 (S) 75 % 1 01/25/12 16:38 1718-51-001/23/12 12:0031-107
Phenol-d6 (S) 22 % 1 01/25/12 16:38 13127-88-301/23/12 12:0010-110
2-Fluorophenol (S) 34 % 1 01/25/12 16:38 367-12-401/23/12 12:0012-110
2,4,6-Tribromophenol (S) 83 % 1 01/25/12 16:38 118-79-601/23/12 12:0027-110
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 5 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Sample: MW-1024 Lab ID: 92110579001 Collected: 01/19/12 12:30 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
8260 MSV Low Level Analytical Method: EPA 8260
Acetone ND ug/L 1 01/20/12 21:24 67-64-125.0
Benzene ND ug/L 1 01/20/12 21:24 71-43-21.0
Bromobenzene ND ug/L 1 01/20/12 21:24 108-86-11.0
Bromochloromethane ND ug/L 1 01/20/12 21:24 74-97-51.0
Bromodichloromethane ND ug/L 1 01/20/12 21:24 75-27-41.0
Bromoform ND ug/L 1 01/20/12 21:24 75-25-21.0
Bromomethane ND ug/L 1 01/20/12 21:24 74-83-92.0
2-Butanone (MEK) ND ug/L 1 01/20/12 21:24 78-93-35.0
Carbon tetrachloride ND ug/L 1 01/20/12 21:24 56-23-51.0
Chlorobenzene ND ug/L 1 01/20/12 21:24 108-90-71.0
Chloroethane ND ug/L 1 01/20/12 21:24 75-00-31.0
Chloroform 2.6 ug/L 1 01/20/12 21:24 67-66-31.0
Chloromethane ND ug/L 1 01/20/12 21:24 74-87-31.0
2-Chlorotoluene ND ug/L 1 01/20/12 21:24 95-49-81.0
4-Chlorotoluene ND ug/L 1 01/20/12 21:24 106-43-41.0
1,2-Dibromo-3-chloropropane ND ug/L 1 01/20/12 21:24 96-12-85.0
Dibromochloromethane ND ug/L 1 01/20/12 21:24 124-48-11.0
1,2-Dibromoethane (EDB) ND ug/L 1 01/20/12 21:24 106-93-41.0
Dibromomethane ND ug/L 1 01/20/12 21:24 74-95-31.0
1,2-Dichlorobenzene ND ug/L 1 01/20/12 21:24 95-50-11.0
1,3-Dichlorobenzene ND ug/L 1 01/20/12 21:24 541-73-11.0
1,4-Dichlorobenzene ND ug/L 1 01/20/12 21:24 106-46-71.0
Dichlorodifluoromethane ND ug/L 1 01/20/12 21:24 75-71-81.0
1,1-Dichloroethane ND ug/L 1 01/20/12 21:24 75-34-31.0
1,2-Dichloroethane ND ug/L 1 01/20/12 21:24 107-06-21.0
1,1-Dichloroethene 1.1 ug/L 1 01/20/12 21:24 75-35-41.0
cis-1,2-Dichloroethene 4.1 ug/L 1 01/20/12 21:24 156-59-21.0
trans-1,2-Dichloroethene ND ug/L 1 01/20/12 21:24 156-60-51.0
1,2-Dichloropropane ND ug/L 1 01/20/12 21:24 78-87-51.0
1,3-Dichloropropane ND ug/L 1 01/20/12 21:24 142-28-91.0
2,2-Dichloropropane ND ug/L 1 01/20/12 21:24 594-20-71.0
1,1-Dichloropropene ND ug/L 1 01/20/12 21:24 563-58-61.0
cis-1,3-Dichloropropene ND ug/L 1 01/20/12 21:24 10061-01-51.0
trans-1,3-Dichloropropene ND ug/L 1 01/20/12 21:24 10061-02-61.0
Diisopropyl ether ND ug/L 1 01/20/12 21:24 108-20-31.0
Ethylbenzene ND ug/L 1 01/20/12 21:24 100-41-41.0
Hexachloro-1,3-butadiene ND ug/L 1 01/20/12 21:24 87-68-31.0
2-Hexanone ND ug/L 1 01/20/12 21:24 591-78-65.0
p-Isopropyltoluene ND ug/L 1 01/20/12 21:24 99-87-61.0
Methylene Chloride ND ug/L 1 01/20/12 21:24 75-09-22.0
4-Methyl-2-pentanone (MIBK) ND ug/L 1 01/20/12 21:24 108-10-15.0
Methyl-tert-butyl ether ND ug/L 1 01/20/12 21:24 1634-04-41.0
Naphthalene 1.7 ug/L 1 01/20/12 21:24 91-20-31.0
Styrene ND ug/L 1 01/20/12 21:24 100-42-51.0
1,1,1,2-Tetrachloroethane ND ug/L 1 01/20/12 21:24 630-20-61.0
1,1,2,2-Tetrachloroethane ND ug/L 1 01/20/12 21:24 79-34-51.0
Tetrachloroethene 68.4 ug/L 1 01/20/12 21:24 127-18-41.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 6 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Sample: MW-1024 Lab ID: 92110579001 Collected: 01/19/12 12:30 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
8260 MSV Low Level Analytical Method: EPA 8260
Toluene ND ug/L 1 01/20/12 21:24 108-88-31.0
1,2,3-Trichlorobenzene ND ug/L 1 01/20/12 21:24 87-61-61.0
1,2,4-Trichlorobenzene ND ug/L 1 01/20/12 21:24 120-82-11.0
1,1,1-Trichloroethane ND ug/L 1 01/20/12 21:24 71-55-61.0
1,1,2-Trichloroethane ND ug/L 1 01/20/12 21:24 79-00-51.0
Trichloroethene 3.3 ug/L 1 01/20/12 21:24 79-01-61.0
Trichlorofluoromethane ND ug/L 1 01/20/12 21:24 75-69-41.0
1,2,3-Trichloropropane ND ug/L 1 01/20/12 21:24 96-18-41.0
Vinyl acetate ND ug/L 1 01/20/12 21:24 108-05-42.0
Vinyl chloride ND ug/L 1 01/20/12 21:24 75-01-41.0
m&p-Xylene ND ug/L 1 01/20/12 21:24 179601-23-12.0
o-Xylene ND ug/L 1 01/20/12 21:24 95-47-61.0
Surrogates4-Bromofluorobenzene (S) 95 % 1 01/20/12 21:24 460-00-470-130
Dibromofluoromethane (S) 103 % 1 01/20/12 21:24 1868-53-770-130
1,2-Dichloroethane-d4 (S) 99 % 1 01/20/12 21:24 17060-07-070-130
Toluene-d8 (S) 95 % 1 01/20/12 21:24 2037-26-570-130
7196 Chromium, Hexavalent Analytical Method: EPA 7196
Chromium, Hexavalent ND mg/L 1 01/19/12 21:30 18540-29-9 N20.050
Sample: MW-1 Lab ID: 92110579002 Collected: 01/19/12 11:30 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010
Antimony ND ug/L 1 01/23/12 16:44 7440-36-001/20/12 10:505.0
Arsenic ND ug/L 1 01/23/12 16:44 7440-38-201/20/12 10:505.0
Beryllium 1.0 ug/L 1 01/23/12 16:44 7440-41-701/20/12 10:501.0
Cadmium ND ug/L 1 01/23/12 16:44 7440-43-901/20/12 10:501.0
Chromium 57.3 ug/L 1 01/23/12 16:44 7440-47-301/20/12 10:505.0
Copper 133 ug/L 1 01/23/12 16:44 7440-50-801/20/12 10:505.0
Lead 8.5 ug/L 1 01/23/12 16:44 7439-92-101/20/12 10:505.0
Manganese 1610 ug/L 1 01/23/12 16:44 7439-96-501/20/12 10:505.0
Nickel 33.9 ug/L 1 01/23/12 16:44 7440-02-001/20/12 10:505.0
Selenium ND ug/L 1 01/23/12 16:44 7782-49-201/20/12 10:5010.0
Silver ND ug/L 1 01/23/12 16:44 7440-22-401/20/12 10:505.0
Thallium ND ug/L 1 01/23/12 16:44 7440-28-001/20/12 10:5010.0
Zinc 172 ug/L 1 01/23/12 16:44 7440-66-601/20/12 10:5010.0
7470 Mercury Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury ND ug/L 1 01/25/12 17:40 7439-97-601/24/12 15:350.20
8270 MSSV Semivolatile Organic Analytical Method: EPA 8270 Preparation Method: EPA 3510
Acenaphthene ND ug/L 1 01/25/12 17:07 83-32-901/23/12 12:0010.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 7 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Sample: MW-1 Lab ID: 92110579002 Collected: 01/19/12 11:30 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
8270 MSSV Semivolatile Organic Analytical Method: EPA 8270 Preparation Method: EPA 3510
Acenaphthylene ND ug/L 1 01/25/12 17:07 208-96-801/23/12 12:0010.0
Aniline ND ug/L 1 01/25/12 17:07 62-53-301/23/12 12:0010.0
Anthracene ND ug/L 1 01/25/12 17:07 120-12-701/23/12 12:0010.0
Benzo(a)anthracene ND ug/L 1 01/25/12 17:07 56-55-301/23/12 12:0010.0
Benzo(a)pyrene ND ug/L 1 01/25/12 17:07 50-32-801/23/12 12:0010.0
Benzo(b)fluoranthene ND ug/L 1 01/25/12 17:07 205-99-201/23/12 12:0010.0
Benzo(g,h,i)perylene ND ug/L 1 01/25/12 17:07 191-24-201/23/12 12:0010.0
Benzo(k)fluoranthene ND ug/L 1 01/25/12 17:07 207-08-901/23/12 12:0010.0
Benzoic Acid ND ug/L 1 01/25/12 17:07 65-85-001/23/12 12:0050.0
Benzyl alcohol ND ug/L 1 01/25/12 17:07 100-51-601/23/12 12:0020.0
4-Bromophenylphenyl ether ND ug/L 1 01/25/12 17:07 101-55-301/23/12 12:0010.0
Butylbenzylphthalate ND ug/L 1 01/25/12 17:07 85-68-701/23/12 12:0010.0
4-Chloro-3-methylphenol ND ug/L 1 01/25/12 17:07 59-50-701/23/12 12:0020.0
4-Chloroaniline ND ug/L 1 01/25/12 17:07 106-47-801/23/12 12:0020.0
bis(2-Chloroethoxy)methane ND ug/L 1 01/25/12 17:07 111-91-101/23/12 12:0010.0
bis(2-Chloroethyl) ether ND ug/L 1 01/25/12 17:07 111-44-401/23/12 12:0010.0
bis(2-Chloroisopropyl) ether ND ug/L 1 01/25/12 17:07 108-60-101/23/12 12:0010.0
2-Chloronaphthalene ND ug/L 1 01/25/12 17:07 91-58-701/23/12 12:0010.0
2-Chlorophenol ND ug/L 1 01/25/12 17:07 95-57-801/23/12 12:0010.0
4-Chlorophenylphenyl ether ND ug/L 1 01/25/12 17:07 7005-72-301/23/12 12:0010.0
Chrysene ND ug/L 1 01/25/12 17:07 218-01-901/23/12 12:0010.0
Dibenz(a,h)anthracene ND ug/L 1 01/25/12 17:07 53-70-301/23/12 12:0010.0
Dibenzofuran ND ug/L 1 01/25/12 17:07 132-64-901/23/12 12:0010.0
1,2-Dichlorobenzene ND ug/L 1 01/25/12 17:07 95-50-101/23/12 12:0010.0
1,3-Dichlorobenzene ND ug/L 1 01/25/12 17:07 541-73-101/23/12 12:0010.0
1,4-Dichlorobenzene ND ug/L 1 01/25/12 17:07 106-46-701/23/12 12:0010.0
3,3'-Dichlorobenzidine ND ug/L 1 01/25/12 17:07 91-94-101/23/12 12:0020.0
2,4-Dichlorophenol ND ug/L 1 01/25/12 17:07 120-83-201/23/12 12:0010.0
Diethylphthalate ND ug/L 1 01/25/12 17:07 84-66-201/23/12 12:0010.0
2,4-Dimethylphenol ND ug/L 1 01/25/12 17:07 105-67-901/23/12 12:0010.0
Dimethylphthalate ND ug/L 1 01/25/12 17:07 131-11-301/23/12 12:0010.0
Di-n-butylphthalate ND ug/L 1 01/25/12 17:07 84-74-201/23/12 12:0010.0
4,6-Dinitro-2-methylphenol ND ug/L 1 01/25/12 17:07 534-52-101/23/12 12:0020.0
2,4-Dinitrophenol ND ug/L 1 01/25/12 17:07 51-28-501/23/12 12:0050.0
2,4-Dinitrotoluene ND ug/L 1 01/25/12 17:07 121-14-201/23/12 12:0010.0
2,6-Dinitrotoluene ND ug/L 1 01/25/12 17:07 606-20-201/23/12 12:0010.0
Di-n-octylphthalate ND ug/L 1 01/25/12 17:07 117-84-001/23/12 12:0010.0
bis(2-Ethylhexyl)phthalate ND ug/L 1 01/25/12 17:07 117-81-701/23/12 12:006.0
Fluoranthene ND ug/L 1 01/25/12 17:07 206-44-001/23/12 12:0010.0
Fluorene ND ug/L 1 01/25/12 17:07 86-73-701/23/12 12:0010.0
Hexachloro-1,3-butadiene ND ug/L 1 01/25/12 17:07 87-68-301/23/12 12:0010.0
Hexachlorobenzene ND ug/L 1 01/25/12 17:07 118-74-101/23/12 12:0010.0
Hexachlorocyclopentadiene ND ug/L 1 01/25/12 17:07 77-47-401/23/12 12:0010.0
Hexachloroethane ND ug/L 1 01/25/12 17:07 67-72-101/23/12 12:0010.0
Indeno(1,2,3-cd)pyrene ND ug/L 1 01/25/12 17:07 193-39-501/23/12 12:0010.0
Isophorone ND ug/L 1 01/25/12 17:07 78-59-101/23/12 12:0010.0
1-Methylnaphthalene ND ug/L 1 01/25/12 17:07 90-12-001/23/12 12:0010.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 8 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Sample: MW-1 Lab ID: 92110579002 Collected: 01/19/12 11:30 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
8270 MSSV Semivolatile Organic Analytical Method: EPA 8270 Preparation Method: EPA 3510
2-Methylnaphthalene ND ug/L 1 01/25/12 17:07 91-57-601/23/12 12:0010.0
2-Methylphenol(o-Cresol) ND ug/L 1 01/25/12 17:07 95-48-701/23/12 12:0010.0
3&4-Methylphenol(m&p Cresol) ND ug/L 1 01/25/12 17:0701/23/12 12:0010.0
Naphthalene ND ug/L 1 01/25/12 17:07 91-20-301/23/12 12:0010.0
2-Nitroaniline ND ug/L 1 01/25/12 17:07 88-74-401/23/12 12:0050.0
3-Nitroaniline ND ug/L 1 01/25/12 17:07 99-09-201/23/12 12:0050.0
4-Nitroaniline ND ug/L 1 01/25/12 17:07 100-01-601/23/12 12:0020.0
Nitrobenzene ND ug/L 1 01/25/12 17:07 98-95-301/23/12 12:0010.0
2-Nitrophenol ND ug/L 1 01/25/12 17:07 88-75-501/23/12 12:0010.0
4-Nitrophenol ND ug/L 1 01/25/12 17:07 100-02-701/23/12 12:0050.0
N-Nitrosodimethylamine ND ug/L 1 01/25/12 17:07 62-75-901/23/12 12:0010.0
N-Nitroso-di-n-propylamine ND ug/L 1 01/25/12 17:07 621-64-701/23/12 12:0010.0
N-Nitrosodiphenylamine ND ug/L 1 01/25/12 17:07 86-30-601/23/12 12:0010.0
Pentachlorophenol ND ug/L 1 01/25/12 17:07 87-86-501/23/12 12:0025.0
Phenanthrene ND ug/L 1 01/25/12 17:07 85-01-801/23/12 12:0010.0
Phenol ND ug/L 1 01/25/12 17:07 108-95-201/23/12 12:0010.0
Pyrene ND ug/L 1 01/25/12 17:07 129-00-001/23/12 12:0010.0
1,2,4-Trichlorobenzene ND ug/L 1 01/25/12 17:07 120-82-101/23/12 12:0010.0
2,4,5-Trichlorophenol ND ug/L 1 01/25/12 17:07 95-95-401/23/12 12:0010.0
2,4,6-Trichlorophenol ND ug/L 1 01/25/12 17:07 88-06-201/23/12 12:0010.0
Surrogates
Nitrobenzene-d5 (S) 69 % 1 01/25/12 17:07 4165-60-001/23/12 12:0021-110
2-Fluorobiphenyl (S) 70 % 1 01/25/12 17:07 321-60-801/23/12 12:0027-110
Terphenyl-d14 (S) 61 % 1 01/25/12 17:07 1718-51-001/23/12 12:0031-107
Phenol-d6 (S) 29 % 1 01/25/12 17:07 13127-88-301/23/12 12:0010-110
2-Fluorophenol (S) 43 % 1 01/25/12 17:07 367-12-401/23/12 12:0012-110
2,4,6-Tribromophenol (S) 80 % 1 01/25/12 17:07 118-79-601/23/12 12:0027-110
8260 MSV Low Level Analytical Method: EPA 8260
Acetone ND ug/L 1 01/20/12 21:49 67-64-125.0
Benzene ND ug/L 1 01/20/12 21:49 71-43-21.0
Bromobenzene ND ug/L 1 01/20/12 21:49 108-86-11.0
Bromochloromethane ND ug/L 1 01/20/12 21:49 74-97-51.0
Bromodichloromethane ND ug/L 1 01/20/12 21:49 75-27-41.0
Bromoform ND ug/L 1 01/20/12 21:49 75-25-21.0
Bromomethane ND ug/L 1 01/20/12 21:49 74-83-92.0
2-Butanone (MEK) ND ug/L 1 01/20/12 21:49 78-93-35.0
Carbon tetrachloride ND ug/L 1 01/20/12 21:49 56-23-51.0
Chlorobenzene ND ug/L 1 01/20/12 21:49 108-90-71.0
Chloroethane ND ug/L 1 01/20/12 21:49 75-00-31.0
Chloroform ND ug/L 1 01/20/12 21:49 67-66-31.0
Chloromethane ND ug/L 1 01/20/12 21:49 74-87-31.0
2-Chlorotoluene ND ug/L 1 01/20/12 21:49 95-49-81.0
4-Chlorotoluene ND ug/L 1 01/20/12 21:49 106-43-41.0
1,2-Dibromo-3-chloropropane ND ug/L 1 01/20/12 21:49 96-12-85.0
Dibromochloromethane ND ug/L 1 01/20/12 21:49 124-48-11.0
1,2-Dibromoethane (EDB) ND ug/L 1 01/20/12 21:49 106-93-41.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 9 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Sample: MW-1 Lab ID: 92110579002 Collected: 01/19/12 11:30 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
8260 MSV Low Level Analytical Method: EPA 8260
Dibromomethane ND ug/L 1 01/20/12 21:49 74-95-31.0
1,2-Dichlorobenzene ND ug/L 1 01/20/12 21:49 95-50-11.0
1,3-Dichlorobenzene ND ug/L 1 01/20/12 21:49 541-73-11.0
1,4-Dichlorobenzene ND ug/L 1 01/20/12 21:49 106-46-71.0
Dichlorodifluoromethane ND ug/L 1 01/20/12 21:49 75-71-81.0
1,1-Dichloroethane 15.0 ug/L 1 01/20/12 21:49 75-34-31.0
1,2-Dichloroethane ND ug/L 1 01/20/12 21:49 107-06-21.0
1,1-Dichloroethene 7.7 ug/L 1 01/20/12 21:49 75-35-41.0
cis-1,2-Dichloroethene 2.2 ug/L 1 01/20/12 21:49 156-59-21.0
trans-1,2-Dichloroethene ND ug/L 1 01/20/12 21:49 156-60-51.0
1,2-Dichloropropane ND ug/L 1 01/20/12 21:49 78-87-51.0
1,3-Dichloropropane ND ug/L 1 01/20/12 21:49 142-28-91.0
2,2-Dichloropropane ND ug/L 1 01/20/12 21:49 594-20-71.0
1,1-Dichloropropene ND ug/L 1 01/20/12 21:49 563-58-61.0
cis-1,3-Dichloropropene ND ug/L 1 01/20/12 21:49 10061-01-51.0
trans-1,3-Dichloropropene ND ug/L 1 01/20/12 21:49 10061-02-61.0
Diisopropyl ether ND ug/L 1 01/20/12 21:49 108-20-31.0
Ethylbenzene ND ug/L 1 01/20/12 21:49 100-41-41.0
Hexachloro-1,3-butadiene ND ug/L 1 01/20/12 21:49 87-68-31.0
2-Hexanone ND ug/L 1 01/20/12 21:49 591-78-65.0
p-Isopropyltoluene ND ug/L 1 01/20/12 21:49 99-87-61.0
Methylene Chloride ND ug/L 1 01/20/12 21:49 75-09-22.0
4-Methyl-2-pentanone (MIBK) ND ug/L 1 01/20/12 21:49 108-10-15.0
Methyl-tert-butyl ether ND ug/L 1 01/20/12 21:49 1634-04-41.0
Naphthalene ND ug/L 1 01/20/12 21:49 91-20-31.0
Styrene ND ug/L 1 01/20/12 21:49 100-42-51.0
1,1,1,2-Tetrachloroethane ND ug/L 1 01/20/12 21:49 630-20-61.0
1,1,2,2-Tetrachloroethane ND ug/L 1 01/20/12 21:49 79-34-51.0
Tetrachloroethene 23.7 ug/L 1 01/20/12 21:49 127-18-41.0
Toluene ND ug/L 1 01/20/12 21:49 108-88-31.0
1,2,3-Trichlorobenzene ND ug/L 1 01/20/12 21:49 87-61-61.0
1,2,4-Trichlorobenzene ND ug/L 1 01/20/12 21:49 120-82-11.0
1,1,1-Trichloroethane ND ug/L 1 01/20/12 21:49 71-55-61.0
1,1,2-Trichloroethane ND ug/L 1 01/20/12 21:49 79-00-51.0
Trichloroethene ND ug/L 1 01/20/12 21:49 79-01-61.0
Trichlorofluoromethane ND ug/L 1 01/20/12 21:49 75-69-41.0
1,2,3-Trichloropropane ND ug/L 1 01/20/12 21:49 96-18-41.0
Vinyl acetate ND ug/L 1 01/20/12 21:49 108-05-42.0
Vinyl chloride ND ug/L 1 01/20/12 21:49 75-01-41.0
m&p-Xylene ND ug/L 1 01/20/12 21:49 179601-23-12.0
o-Xylene ND ug/L 1 01/20/12 21:49 95-47-61.0
Surrogates
4-Bromofluorobenzene (S) 95 % 1 01/20/12 21:49 460-00-470-130
Dibromofluoromethane (S) 105 % 1 01/20/12 21:49 1868-53-770-130
1,2-Dichloroethane-d4 (S) 103 % 1 01/20/12 21:49 17060-07-070-130
Toluene-d8 (S) 95 % 1 01/20/12 21:49 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 10 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Sample: MW-1 Lab ID: 92110579002 Collected: 01/19/12 11:30 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
7196 Chromium, Hexavalent Analytical Method: EPA 7196
Chromium, Hexavalent ND mg/L 1 01/19/12 21:30 18540-29-9 N20.050
Sample: MW-2 Lab ID: 92110579003 Collected: 01/19/12 10:30 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010
Antimony ND ug/L 1 01/23/12 16:48 7440-36-001/20/12 10:505.0
Arsenic ND ug/L 1 01/23/12 16:48 7440-38-201/20/12 10:505.0
Beryllium ND ug/L 1 01/23/12 16:48 7440-41-701/20/12 10:501.0
Cadmium ND ug/L 1 01/23/12 16:48 7440-43-901/20/12 10:501.0
Chromium ND ug/L 1 01/23/12 16:48 7440-47-301/20/12 10:505.0
Copper 21.2 ug/L 1 01/23/12 16:48 7440-50-801/20/12 10:505.0
Lead ND ug/L 1 01/23/12 16:48 7439-92-101/20/12 10:505.0
Manganese 222 ug/L 1 01/23/12 16:48 7439-96-501/20/12 10:505.0
Nickel ND ug/L 1 01/23/12 16:48 7440-02-001/20/12 10:505.0
Selenium ND ug/L 1 01/23/12 16:48 7782-49-201/20/12 10:5010.0
Silver ND ug/L 1 01/23/12 16:48 7440-22-401/20/12 10:505.0
Thallium ND ug/L 1 01/23/12 16:48 7440-28-001/20/12 10:5010.0
Zinc 134 ug/L 1 01/23/12 16:48 7440-66-601/20/12 10:5010.0
7470 Mercury Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury 1.5 ug/L 1 01/25/12 17:43 7439-97-601/24/12 15:350.20
8270 MSSV Semivolatile Organic Analytical Method: EPA 8270 Preparation Method: EPA 3510
Acenaphthene ND ug/L 1 01/25/12 17:36 83-32-901/23/12 12:0010.0
Acenaphthylene ND ug/L 1 01/25/12 17:36 208-96-801/23/12 12:0010.0
Aniline ND ug/L 1 01/25/12 17:36 62-53-301/23/12 12:0010.0
Anthracene ND ug/L 1 01/25/12 17:36 120-12-701/23/12 12:0010.0
Benzo(a)anthracene ND ug/L 1 01/25/12 17:36 56-55-301/23/12 12:0010.0
Benzo(a)pyrene ND ug/L 1 01/25/12 17:36 50-32-801/23/12 12:0010.0
Benzo(b)fluoranthene ND ug/L 1 01/25/12 17:36 205-99-201/23/12 12:0010.0
Benzo(g,h,i)perylene ND ug/L 1 01/25/12 17:36 191-24-201/23/12 12:0010.0
Benzo(k)fluoranthene ND ug/L 1 01/25/12 17:36 207-08-901/23/12 12:0010.0
Benzoic Acid ND ug/L 1 01/25/12 17:36 65-85-001/23/12 12:0050.0
Benzyl alcohol ND ug/L 1 01/25/12 17:36 100-51-601/23/12 12:0020.0
4-Bromophenylphenyl ether ND ug/L 1 01/25/12 17:36 101-55-301/23/12 12:0010.0
Butylbenzylphthalate ND ug/L 1 01/25/12 17:36 85-68-701/23/12 12:0010.0
4-Chloro-3-methylphenol ND ug/L 1 01/25/12 17:36 59-50-701/23/12 12:0020.0
4-Chloroaniline ND ug/L 1 01/25/12 17:36 106-47-801/23/12 12:0020.0
bis(2-Chloroethoxy)methane ND ug/L 1 01/25/12 17:36 111-91-101/23/12 12:0010.0
bis(2-Chloroethyl) ether ND ug/L 1 01/25/12 17:36 111-44-401/23/12 12:0010.0
bis(2-Chloroisopropyl) ether ND ug/L 1 01/25/12 17:36 108-60-101/23/12 12:0010.0
2-Chloronaphthalene ND ug/L 1 01/25/12 17:36 91-58-701/23/12 12:0010.0
2-Chlorophenol ND ug/L 1 01/25/12 17:36 95-57-801/23/12 12:0010.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 11 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Sample: MW-2 Lab ID: 92110579003 Collected: 01/19/12 10:30 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
8270 MSSV Semivolatile Organic Analytical Method: EPA 8270 Preparation Method: EPA 3510
4-Chlorophenylphenyl ether ND ug/L 1 01/25/12 17:36 7005-72-301/23/12 12:0010.0
Chrysene ND ug/L 1 01/25/12 17:36 218-01-901/23/12 12:0010.0
Dibenz(a,h)anthracene ND ug/L 1 01/25/12 17:36 53-70-301/23/12 12:0010.0
Dibenzofuran ND ug/L 1 01/25/12 17:36 132-64-901/23/12 12:0010.0
1,2-Dichlorobenzene ND ug/L 1 01/25/12 17:36 95-50-101/23/12 12:0010.0
1,3-Dichlorobenzene ND ug/L 1 01/25/12 17:36 541-73-101/23/12 12:0010.0
1,4-Dichlorobenzene ND ug/L 1 01/25/12 17:36 106-46-701/23/12 12:0010.0
3,3'-Dichlorobenzidine ND ug/L 1 01/25/12 17:36 91-94-101/23/12 12:0020.0
2,4-Dichlorophenol ND ug/L 1 01/25/12 17:36 120-83-201/23/12 12:0010.0
Diethylphthalate ND ug/L 1 01/25/12 17:36 84-66-201/23/12 12:0010.0
2,4-Dimethylphenol ND ug/L 1 01/25/12 17:36 105-67-901/23/12 12:0010.0
Dimethylphthalate ND ug/L 1 01/25/12 17:36 131-11-301/23/12 12:0010.0
Di-n-butylphthalate ND ug/L 1 01/25/12 17:36 84-74-201/23/12 12:0010.0
4,6-Dinitro-2-methylphenol ND ug/L 1 01/25/12 17:36 534-52-101/23/12 12:0020.0
2,4-Dinitrophenol ND ug/L 1 01/25/12 17:36 51-28-501/23/12 12:0050.0
2,4-Dinitrotoluene ND ug/L 1 01/25/12 17:36 121-14-201/23/12 12:0010.0
2,6-Dinitrotoluene ND ug/L 1 01/25/12 17:36 606-20-201/23/12 12:0010.0
Di-n-octylphthalate ND ug/L 1 01/25/12 17:36 117-84-001/23/12 12:0010.0
bis(2-Ethylhexyl)phthalate ND ug/L 1 01/25/12 17:36 117-81-701/23/12 12:006.0
Fluoranthene ND ug/L 1 01/25/12 17:36 206-44-001/23/12 12:0010.0
Fluorene ND ug/L 1 01/25/12 17:36 86-73-701/23/12 12:0010.0
Hexachloro-1,3-butadiene ND ug/L 1 01/25/12 17:36 87-68-301/23/12 12:0010.0
Hexachlorobenzene ND ug/L 1 01/25/12 17:36 118-74-101/23/12 12:0010.0
Hexachlorocyclopentadiene ND ug/L 1 01/25/12 17:36 77-47-401/23/12 12:0010.0
Hexachloroethane ND ug/L 1 01/25/12 17:36 67-72-101/23/12 12:0010.0
Indeno(1,2,3-cd)pyrene ND ug/L 1 01/25/12 17:36 193-39-501/23/12 12:0010.0
Isophorone ND ug/L 1 01/25/12 17:36 78-59-101/23/12 12:0010.0
1-Methylnaphthalene ND ug/L 1 01/25/12 17:36 90-12-001/23/12 12:0010.0
2-Methylnaphthalene ND ug/L 1 01/25/12 17:36 91-57-601/23/12 12:0010.0
2-Methylphenol(o-Cresol) ND ug/L 1 01/25/12 17:36 95-48-701/23/12 12:0010.0
3&4-Methylphenol(m&p Cresol) ND ug/L 1 01/25/12 17:3601/23/12 12:0010.0
Naphthalene ND ug/L 1 01/25/12 17:36 91-20-301/23/12 12:0010.0
2-Nitroaniline ND ug/L 1 01/25/12 17:36 88-74-401/23/12 12:0050.0
3-Nitroaniline ND ug/L 1 01/25/12 17:36 99-09-201/23/12 12:0050.0
4-Nitroaniline ND ug/L 1 01/25/12 17:36 100-01-601/23/12 12:0020.0
Nitrobenzene ND ug/L 1 01/25/12 17:36 98-95-301/23/12 12:0010.0
2-Nitrophenol ND ug/L 1 01/25/12 17:36 88-75-501/23/12 12:0010.0
4-Nitrophenol ND ug/L 1 01/25/12 17:36 100-02-701/23/12 12:0050.0
N-Nitrosodimethylamine ND ug/L 1 01/25/12 17:36 62-75-901/23/12 12:0010.0
N-Nitroso-di-n-propylamine ND ug/L 1 01/25/12 17:36 621-64-701/23/12 12:0010.0
N-Nitrosodiphenylamine ND ug/L 1 01/25/12 17:36 86-30-601/23/12 12:0010.0
Pentachlorophenol ND ug/L 1 01/25/12 17:36 87-86-501/23/12 12:0025.0
Phenanthrene ND ug/L 1 01/25/12 17:36 85-01-801/23/12 12:0010.0
Phenol ND ug/L 1 01/25/12 17:36 108-95-201/23/12 12:0010.0
Pyrene ND ug/L 1 01/25/12 17:36 129-00-001/23/12 12:0010.0
1,2,4-Trichlorobenzene ND ug/L 1 01/25/12 17:36 120-82-101/23/12 12:0010.0
2,4,5-Trichlorophenol ND ug/L 1 01/25/12 17:36 95-95-401/23/12 12:0010.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 12 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Sample: MW-2 Lab ID: 92110579003 Collected: 01/19/12 10:30 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
8270 MSSV Semivolatile Organic Analytical Method: EPA 8270 Preparation Method: EPA 3510
2,4,6-Trichlorophenol ND ug/L 1 01/25/12 17:36 88-06-201/23/12 12:0010.0
Surrogates
Nitrobenzene-d5 (S) 69 % 1 01/25/12 17:36 4165-60-001/23/12 12:0021-110
2-Fluorobiphenyl (S) 72 % 1 01/25/12 17:36 321-60-801/23/12 12:0027-110
Terphenyl-d14 (S) 60 % 1 01/25/12 17:36 1718-51-001/23/12 12:0031-107
Phenol-d6 (S) 31 % 1 01/25/12 17:36 13127-88-301/23/12 12:0010-110
2-Fluorophenol (S) 45 % 1 01/25/12 17:36 367-12-401/23/12 12:0012-110
2,4,6-Tribromophenol (S) 82 % 1 01/25/12 17:36 118-79-601/23/12 12:0027-110
8260 MSV Low Level Analytical Method: EPA 8260
Acetone ND ug/L 1 01/20/12 22:14 67-64-125.0
Benzene ND ug/L 1 01/20/12 22:14 71-43-21.0
Bromobenzene ND ug/L 1 01/20/12 22:14 108-86-11.0
Bromochloromethane ND ug/L 1 01/20/12 22:14 74-97-51.0
Bromodichloromethane ND ug/L 1 01/20/12 22:14 75-27-41.0
Bromoform ND ug/L 1 01/20/12 22:14 75-25-21.0
Bromomethane ND ug/L 1 01/20/12 22:14 74-83-92.0
2-Butanone (MEK) ND ug/L 1 01/20/12 22:14 78-93-35.0
Carbon tetrachloride ND ug/L 1 01/20/12 22:14 56-23-51.0
Chlorobenzene ND ug/L 1 01/20/12 22:14 108-90-71.0
Chloroethane ND ug/L 1 01/20/12 22:14 75-00-31.0
Chloroform ND ug/L 1 01/20/12 22:14 67-66-31.0
Chloromethane ND ug/L 1 01/20/12 22:14 74-87-31.0
2-Chlorotoluene ND ug/L 1 01/20/12 22:14 95-49-81.0
4-Chlorotoluene ND ug/L 1 01/20/12 22:14 106-43-41.0
1,2-Dibromo-3-chloropropane ND ug/L 1 01/20/12 22:14 96-12-85.0
Dibromochloromethane ND ug/L 1 01/20/12 22:14 124-48-11.0
1,2-Dibromoethane (EDB) ND ug/L 1 01/20/12 22:14 106-93-41.0
Dibromomethane ND ug/L 1 01/20/12 22:14 74-95-31.0
1,2-Dichlorobenzene ND ug/L 1 01/20/12 22:14 95-50-11.0
1,3-Dichlorobenzene ND ug/L 1 01/20/12 22:14 541-73-11.0
1,4-Dichlorobenzene ND ug/L 1 01/20/12 22:14 106-46-71.0
Dichlorodifluoromethane ND ug/L 1 01/20/12 22:14 75-71-81.0
1,1-Dichloroethane 19.8 ug/L 1 01/20/12 22:14 75-34-31.0
1,2-Dichloroethane ND ug/L 1 01/20/12 22:14 107-06-21.0
1,1-Dichloroethene 16.0 ug/L 1 01/20/12 22:14 75-35-41.0
cis-1,2-Dichloroethene 1.0 ug/L 1 01/20/12 22:14 156-59-21.0
trans-1,2-Dichloroethene ND ug/L 1 01/20/12 22:14 156-60-51.0
1,2-Dichloropropane ND ug/L 1 01/20/12 22:14 78-87-51.0
1,3-Dichloropropane ND ug/L 1 01/20/12 22:14 142-28-91.0
2,2-Dichloropropane ND ug/L 1 01/20/12 22:14 594-20-71.0
1,1-Dichloropropene ND ug/L 1 01/20/12 22:14 563-58-61.0
cis-1,3-Dichloropropene ND ug/L 1 01/20/12 22:14 10061-01-51.0
trans-1,3-Dichloropropene ND ug/L 1 01/20/12 22:14 10061-02-61.0
Diisopropyl ether ND ug/L 1 01/20/12 22:14 108-20-31.0
Ethylbenzene ND ug/L 1 01/20/12 22:14 100-41-41.0
Hexachloro-1,3-butadiene ND ug/L 1 01/20/12 22:14 87-68-31.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 13 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Sample: MW-2 Lab ID: 92110579003 Collected: 01/19/12 10:30 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
8260 MSV Low Level Analytical Method: EPA 8260
2-Hexanone ND ug/L 1 01/20/12 22:14 591-78-65.0
p-Isopropyltoluene ND ug/L 1 01/20/12 22:14 99-87-61.0
Methylene Chloride ND ug/L 1 01/20/12 22:14 75-09-22.0
4-Methyl-2-pentanone (MIBK) ND ug/L 1 01/20/12 22:14 108-10-15.0
Methyl-tert-butyl ether ND ug/L 1 01/20/12 22:14 1634-04-41.0
Naphthalene ND ug/L 1 01/20/12 22:14 91-20-31.0
Styrene ND ug/L 1 01/20/12 22:14 100-42-51.0
1,1,1,2-Tetrachloroethane ND ug/L 1 01/20/12 22:14 630-20-61.0
1,1,2,2-Tetrachloroethane ND ug/L 1 01/20/12 22:14 79-34-51.0
Tetrachloroethene 24.0 ug/L 1 01/20/12 22:14 127-18-41.0
Toluene ND ug/L 1 01/20/12 22:14 108-88-31.0
1,2,3-Trichlorobenzene ND ug/L 1 01/20/12 22:14 87-61-61.0
1,2,4-Trichlorobenzene ND ug/L 1 01/20/12 22:14 120-82-11.0
1,1,1-Trichloroethane 1.8 ug/L 1 01/20/12 22:14 71-55-61.0
1,1,2-Trichloroethane ND ug/L 1 01/20/12 22:14 79-00-51.0
Trichloroethene 3.4 ug/L 1 01/20/12 22:14 79-01-61.0
Trichlorofluoromethane ND ug/L 1 01/20/12 22:14 75-69-41.0
1,2,3-Trichloropropane ND ug/L 1 01/20/12 22:14 96-18-41.0
Vinyl acetate ND ug/L 1 01/20/12 22:14 108-05-42.0
Vinyl chloride ND ug/L 1 01/20/12 22:14 75-01-41.0
m&p-Xylene ND ug/L 1 01/20/12 22:14 179601-23-12.0
o-Xylene ND ug/L 1 01/20/12 22:14 95-47-61.0
Surrogates4-Bromofluorobenzene (S) 93 % 1 01/20/12 22:14 460-00-470-130
Dibromofluoromethane (S) 106 % 1 01/20/12 22:14 1868-53-770-130
1,2-Dichloroethane-d4 (S) 104 % 1 01/20/12 22:14 17060-07-070-130
Toluene-d8 (S) 95 % 1 01/20/12 22:14 2037-26-570-130
7196 Chromium, Hexavalent Analytical Method: EPA 7196
Chromium, Hexavalent ND mg/L 1 01/19/12 21:30 18540-29-9 N20.050
Sample: DUPLICATE Lab ID: 92110579004 Collected: 01/19/12 10:35 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010
Antimony ND ug/L 1 01/23/12 16:51 7440-36-001/20/12 10:505.0
Arsenic ND ug/L 1 01/23/12 16:51 7440-38-201/20/12 10:505.0
Beryllium ND ug/L 1 01/23/12 16:51 7440-41-701/20/12 10:501.0
Cadmium ND ug/L 1 01/23/12 16:51 7440-43-901/20/12 10:501.0
Chromium ND ug/L 1 01/23/12 16:51 7440-47-301/20/12 10:505.0
Copper 21.4 ug/L 1 01/23/12 16:51 7440-50-801/20/12 10:505.0
Lead ND ug/L 1 01/23/12 16:51 7439-92-101/20/12 10:505.0
Manganese 217 ug/L 1 01/23/12 16:51 7439-96-501/20/12 10:505.0
Nickel ND ug/L 1 01/23/12 16:51 7440-02-001/20/12 10:505.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 14 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Sample: DUPLICATE Lab ID: 92110579004 Collected: 01/19/12 10:35 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010
Selenium ND ug/L 1 01/23/12 16:51 7782-49-201/20/12 10:5010.0
Silver ND ug/L 1 01/23/12 16:51 7440-22-401/20/12 10:505.0
Thallium ND ug/L 1 01/23/12 16:51 7440-28-001/20/12 10:5010.0
Zinc 222 ug/L 1 01/23/12 16:51 7440-66-601/20/12 10:5010.0
7470 Mercury Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury 1.4 ug/L 1 01/25/12 17:45 7439-97-601/24/12 15:350.20
8270 MSSV Semivolatile Organic Analytical Method: EPA 8270 Preparation Method: EPA 3510
Acenaphthene ND ug/L 1 01/25/12 18:04 83-32-901/23/12 12:0010.0
Acenaphthylene ND ug/L 1 01/25/12 18:04 208-96-801/23/12 12:0010.0
Aniline ND ug/L 1 01/25/12 18:04 62-53-301/23/12 12:0010.0
Anthracene ND ug/L 1 01/25/12 18:04 120-12-701/23/12 12:0010.0
Benzo(a)anthracene ND ug/L 1 01/25/12 18:04 56-55-301/23/12 12:0010.0
Benzo(a)pyrene ND ug/L 1 01/25/12 18:04 50-32-801/23/12 12:0010.0
Benzo(b)fluoranthene ND ug/L 1 01/25/12 18:04 205-99-201/23/12 12:0010.0
Benzo(g,h,i)perylene ND ug/L 1 01/25/12 18:04 191-24-201/23/12 12:0010.0
Benzo(k)fluoranthene ND ug/L 1 01/25/12 18:04 207-08-901/23/12 12:0010.0
Benzoic Acid ND ug/L 1 01/25/12 18:04 65-85-001/23/12 12:0050.0
Benzyl alcohol ND ug/L 1 01/25/12 18:04 100-51-601/23/12 12:0020.0
4-Bromophenylphenyl ether ND ug/L 1 01/25/12 18:04 101-55-301/23/12 12:0010.0
Butylbenzylphthalate ND ug/L 1 01/25/12 18:04 85-68-701/23/12 12:0010.0
4-Chloro-3-methylphenol ND ug/L 1 01/25/12 18:04 59-50-701/23/12 12:0020.0
4-Chloroaniline ND ug/L 1 01/25/12 18:04 106-47-801/23/12 12:0020.0
bis(2-Chloroethoxy)methane ND ug/L 1 01/25/12 18:04 111-91-101/23/12 12:0010.0
bis(2-Chloroethyl) ether ND ug/L 1 01/25/12 18:04 111-44-401/23/12 12:0010.0
bis(2-Chloroisopropyl) ether ND ug/L 1 01/25/12 18:04 108-60-101/23/12 12:0010.0
2-Chloronaphthalene ND ug/L 1 01/25/12 18:04 91-58-701/23/12 12:0010.0
2-Chlorophenol ND ug/L 1 01/25/12 18:04 95-57-801/23/12 12:0010.0
4-Chlorophenylphenyl ether ND ug/L 1 01/25/12 18:04 7005-72-301/23/12 12:0010.0
Chrysene ND ug/L 1 01/25/12 18:04 218-01-901/23/12 12:0010.0
Dibenz(a,h)anthracene ND ug/L 1 01/25/12 18:04 53-70-301/23/12 12:0010.0
Dibenzofuran ND ug/L 1 01/25/12 18:04 132-64-901/23/12 12:0010.0
1,2-Dichlorobenzene ND ug/L 1 01/25/12 18:04 95-50-101/23/12 12:0010.0
1,3-Dichlorobenzene ND ug/L 1 01/25/12 18:04 541-73-101/23/12 12:0010.0
1,4-Dichlorobenzene ND ug/L 1 01/25/12 18:04 106-46-701/23/12 12:0010.0
3,3'-Dichlorobenzidine ND ug/L 1 01/25/12 18:04 91-94-101/23/12 12:0020.0
2,4-Dichlorophenol ND ug/L 1 01/25/12 18:04 120-83-201/23/12 12:0010.0
Diethylphthalate ND ug/L 1 01/25/12 18:04 84-66-201/23/12 12:0010.0
2,4-Dimethylphenol ND ug/L 1 01/25/12 18:04 105-67-901/23/12 12:0010.0
Dimethylphthalate ND ug/L 1 01/25/12 18:04 131-11-301/23/12 12:0010.0
Di-n-butylphthalate ND ug/L 1 01/25/12 18:04 84-74-201/23/12 12:0010.0
4,6-Dinitro-2-methylphenol ND ug/L 1 01/25/12 18:04 534-52-101/23/12 12:0020.0
2,4-Dinitrophenol ND ug/L 1 01/25/12 18:04 51-28-501/23/12 12:0050.0
2,4-Dinitrotoluene ND ug/L 1 01/25/12 18:04 121-14-201/23/12 12:0010.0
2,6-Dinitrotoluene ND ug/L 1 01/25/12 18:04 606-20-201/23/12 12:0010.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 15 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Sample: DUPLICATE Lab ID: 92110579004 Collected: 01/19/12 10:35 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
8270 MSSV Semivolatile Organic Analytical Method: EPA 8270 Preparation Method: EPA 3510
Di-n-octylphthalate ND ug/L 1 01/25/12 18:04 117-84-001/23/12 12:0010.0
bis(2-Ethylhexyl)phthalate ND ug/L 1 01/25/12 18:04 117-81-701/23/12 12:006.0
Fluoranthene ND ug/L 1 01/25/12 18:04 206-44-001/23/12 12:0010.0
Fluorene ND ug/L 1 01/25/12 18:04 86-73-701/23/12 12:0010.0
Hexachloro-1,3-butadiene ND ug/L 1 01/25/12 18:04 87-68-301/23/12 12:0010.0
Hexachlorobenzene ND ug/L 1 01/25/12 18:04 118-74-101/23/12 12:0010.0
Hexachlorocyclopentadiene ND ug/L 1 01/25/12 18:04 77-47-401/23/12 12:0010.0
Hexachloroethane ND ug/L 1 01/25/12 18:04 67-72-101/23/12 12:0010.0
Indeno(1,2,3-cd)pyrene ND ug/L 1 01/25/12 18:04 193-39-501/23/12 12:0010.0
Isophorone ND ug/L 1 01/25/12 18:04 78-59-101/23/12 12:0010.0
1-Methylnaphthalene ND ug/L 1 01/25/12 18:04 90-12-001/23/12 12:0010.0
2-Methylnaphthalene ND ug/L 1 01/25/12 18:04 91-57-601/23/12 12:0010.0
2-Methylphenol(o-Cresol) ND ug/L 1 01/25/12 18:04 95-48-701/23/12 12:0010.0
3&4-Methylphenol(m&p Cresol) ND ug/L 1 01/25/12 18:0401/23/12 12:0010.0
Naphthalene ND ug/L 1 01/25/12 18:04 91-20-301/23/12 12:0010.0
2-Nitroaniline ND ug/L 1 01/25/12 18:04 88-74-401/23/12 12:0050.0
3-Nitroaniline ND ug/L 1 01/25/12 18:04 99-09-201/23/12 12:0050.0
4-Nitroaniline ND ug/L 1 01/25/12 18:04 100-01-601/23/12 12:0020.0
Nitrobenzene ND ug/L 1 01/25/12 18:04 98-95-301/23/12 12:0010.0
2-Nitrophenol ND ug/L 1 01/25/12 18:04 88-75-501/23/12 12:0010.0
4-Nitrophenol ND ug/L 1 01/25/12 18:04 100-02-701/23/12 12:0050.0
N-Nitrosodimethylamine ND ug/L 1 01/25/12 18:04 62-75-901/23/12 12:0010.0
N-Nitroso-di-n-propylamine ND ug/L 1 01/25/12 18:04 621-64-701/23/12 12:0010.0
N-Nitrosodiphenylamine ND ug/L 1 01/25/12 18:04 86-30-601/23/12 12:0010.0
Pentachlorophenol ND ug/L 1 01/25/12 18:04 87-86-501/23/12 12:0025.0
Phenanthrene ND ug/L 1 01/25/12 18:04 85-01-801/23/12 12:0010.0
Phenol ND ug/L 1 01/25/12 18:04 108-95-201/23/12 12:0010.0
Pyrene ND ug/L 1 01/25/12 18:04 129-00-001/23/12 12:0010.0
1,2,4-Trichlorobenzene ND ug/L 1 01/25/12 18:04 120-82-101/23/12 12:0010.0
2,4,5-Trichlorophenol ND ug/L 1 01/25/12 18:04 95-95-401/23/12 12:0010.0
2,4,6-Trichlorophenol ND ug/L 1 01/25/12 18:04 88-06-201/23/12 12:0010.0
Surrogates
Nitrobenzene-d5 (S) 72 % 1 01/25/12 18:04 4165-60-001/23/12 12:0021-110
2-Fluorobiphenyl (S) 73 % 1 01/25/12 18:04 321-60-801/23/12 12:0027-110
Terphenyl-d14 (S) 72 % 1 01/25/12 18:04 1718-51-001/23/12 12:0031-107
Phenol-d6 (S) 28 % 1 01/25/12 18:04 13127-88-301/23/12 12:0010-110
2-Fluorophenol (S) 41 % 1 01/25/12 18:04 367-12-401/23/12 12:0012-110
2,4,6-Tribromophenol (S) 86 % 1 01/25/12 18:04 118-79-601/23/12 12:0027-110
8260 MSV Low Level Analytical Method: EPA 8260
Acetone ND ug/L 1 01/20/12 22:40 67-64-125.0
Benzene ND ug/L 1 01/20/12 22:40 71-43-21.0
Bromobenzene ND ug/L 1 01/20/12 22:40 108-86-11.0
Bromochloromethane ND ug/L 1 01/20/12 22:40 74-97-51.0
Bromodichloromethane ND ug/L 1 01/20/12 22:40 75-27-41.0
Bromoform ND ug/L 1 01/20/12 22:40 75-25-21.0
Bromomethane ND ug/L 1 01/20/12 22:40 74-83-92.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 16 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Sample: DUPLICATE Lab ID: 92110579004 Collected: 01/19/12 10:35 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
8260 MSV Low Level Analytical Method: EPA 8260
2-Butanone (MEK) ND ug/L 1 01/20/12 22:40 78-93-35.0
Carbon tetrachloride ND ug/L 1 01/20/12 22:40 56-23-51.0
Chlorobenzene ND ug/L 1 01/20/12 22:40 108-90-71.0
Chloroethane ND ug/L 1 01/20/12 22:40 75-00-31.0
Chloroform ND ug/L 1 01/20/12 22:40 67-66-31.0
Chloromethane ND ug/L 1 01/20/12 22:40 74-87-31.0
2-Chlorotoluene ND ug/L 1 01/20/12 22:40 95-49-81.0
4-Chlorotoluene ND ug/L 1 01/20/12 22:40 106-43-41.0
1,2-Dibromo-3-chloropropane ND ug/L 1 01/20/12 22:40 96-12-85.0
Dibromochloromethane ND ug/L 1 01/20/12 22:40 124-48-11.0
1,2-Dibromoethane (EDB) ND ug/L 1 01/20/12 22:40 106-93-41.0
Dibromomethane ND ug/L 1 01/20/12 22:40 74-95-31.0
1,2-Dichlorobenzene ND ug/L 1 01/20/12 22:40 95-50-11.0
1,3-Dichlorobenzene ND ug/L 1 01/20/12 22:40 541-73-11.0
1,4-Dichlorobenzene ND ug/L 1 01/20/12 22:40 106-46-71.0
Dichlorodifluoromethane ND ug/L 1 01/20/12 22:40 75-71-81.0
1,1-Dichloroethane 18.8 ug/L 1 01/20/12 22:40 75-34-31.0
1,2-Dichloroethane ND ug/L 1 01/20/12 22:40 107-06-21.0
1,1-Dichloroethene 15.2 ug/L 1 01/20/12 22:40 75-35-41.0
cis-1,2-Dichloroethene ND ug/L 1 01/20/12 22:40 156-59-21.0
trans-1,2-Dichloroethene ND ug/L 1 01/20/12 22:40 156-60-51.0
1,2-Dichloropropane ND ug/L 1 01/20/12 22:40 78-87-51.0
1,3-Dichloropropane ND ug/L 1 01/20/12 22:40 142-28-91.0
2,2-Dichloropropane ND ug/L 1 01/20/12 22:40 594-20-71.0
1,1-Dichloropropene ND ug/L 1 01/20/12 22:40 563-58-61.0
cis-1,3-Dichloropropene ND ug/L 1 01/20/12 22:40 10061-01-51.0
trans-1,3-Dichloropropene ND ug/L 1 01/20/12 22:40 10061-02-61.0
Diisopropyl ether ND ug/L 1 01/20/12 22:40 108-20-31.0
Ethylbenzene ND ug/L 1 01/20/12 22:40 100-41-41.0
Hexachloro-1,3-butadiene ND ug/L 1 01/20/12 22:40 87-68-31.0
2-Hexanone ND ug/L 1 01/20/12 22:40 591-78-65.0
p-Isopropyltoluene ND ug/L 1 01/20/12 22:40 99-87-61.0
Methylene Chloride ND ug/L 1 01/20/12 22:40 75-09-22.0
4-Methyl-2-pentanone (MIBK) ND ug/L 1 01/20/12 22:40 108-10-15.0
Methyl-tert-butyl ether ND ug/L 1 01/20/12 22:40 1634-04-41.0
Naphthalene ND ug/L 1 01/20/12 22:40 91-20-31.0
Styrene ND ug/L 1 01/20/12 22:40 100-42-51.0
1,1,1,2-Tetrachloroethane ND ug/L 1 01/20/12 22:40 630-20-61.0
1,1,2,2-Tetrachloroethane ND ug/L 1 01/20/12 22:40 79-34-51.0
Tetrachloroethene 22.4 ug/L 1 01/20/12 22:40 127-18-41.0
Toluene ND ug/L 1 01/20/12 22:40 108-88-31.0
1,2,3-Trichlorobenzene ND ug/L 1 01/20/12 22:40 87-61-61.0
1,2,4-Trichlorobenzene ND ug/L 1 01/20/12 22:40 120-82-11.0
1,1,1-Trichloroethane 1.8 ug/L 1 01/20/12 22:40 71-55-61.0
1,1,2-Trichloroethane ND ug/L 1 01/20/12 22:40 79-00-51.0
Trichloroethene 3.4 ug/L 1 01/20/12 22:40 79-01-61.0
Trichlorofluoromethane ND ug/L 1 01/20/12 22:40 75-69-41.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 17 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Sample: DUPLICATE Lab ID: 92110579004 Collected: 01/19/12 10:35 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
8260 MSV Low Level Analytical Method: EPA 8260
1,2,3-Trichloropropane ND ug/L 1 01/20/12 22:40 96-18-41.0
Vinyl acetate ND ug/L 1 01/20/12 22:40 108-05-42.0
Vinyl chloride ND ug/L 1 01/20/12 22:40 75-01-41.0
m&p-Xylene ND ug/L 1 01/20/12 22:40 179601-23-12.0
o-Xylene ND ug/L 1 01/20/12 22:40 95-47-61.0
Surrogates
4-Bromofluorobenzene (S) 96 % 1 01/20/12 22:40 460-00-470-130
Dibromofluoromethane (S) 106 % 1 01/20/12 22:40 1868-53-770-130
1,2-Dichloroethane-d4 (S) 105 % 1 01/20/12 22:40 17060-07-070-130
Toluene-d8 (S) 96 % 1 01/20/12 22:40 2037-26-570-130
7196 Chromium, Hexavalent Analytical Method: EPA 7196
Chromium, Hexavalent ND mg/L 1 01/19/12 21:30 18540-29-9 N20.050
Sample: TRIP BLANK Lab ID: 92110579005 Collected: 01/19/12 00:00 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
8260 MSV Low Level Analytical Method: EPA 8260
Acetone ND ug/L 1 01/20/12 17:10 67-64-125.0
Benzene ND ug/L 1 01/20/12 17:10 71-43-21.0
Bromobenzene ND ug/L 1 01/20/12 17:10 108-86-11.0
Bromochloromethane ND ug/L 1 01/20/12 17:10 74-97-51.0
Bromodichloromethane ND ug/L 1 01/20/12 17:10 75-27-41.0
Bromoform ND ug/L 1 01/20/12 17:10 75-25-21.0
Bromomethane ND ug/L 1 01/20/12 17:10 74-83-92.0
2-Butanone (MEK) ND ug/L 1 01/20/12 17:10 78-93-35.0
Carbon tetrachloride ND ug/L 1 01/20/12 17:10 56-23-51.0
Chlorobenzene ND ug/L 1 01/20/12 17:10 108-90-71.0
Chloroethane ND ug/L 1 01/20/12 17:10 75-00-31.0
Chloroform ND ug/L 1 01/20/12 17:10 67-66-31.0
Chloromethane ND ug/L 1 01/20/12 17:10 74-87-31.0
2-Chlorotoluene ND ug/L 1 01/20/12 17:10 95-49-81.0
4-Chlorotoluene ND ug/L 1 01/20/12 17:10 106-43-41.0
1,2-Dibromo-3-chloropropane ND ug/L 1 01/20/12 17:10 96-12-85.0
Dibromochloromethane ND ug/L 1 01/20/12 17:10 124-48-11.0
1,2-Dibromoethane (EDB) ND ug/L 1 01/20/12 17:10 106-93-41.0
Dibromomethane ND ug/L 1 01/20/12 17:10 74-95-31.0
1,2-Dichlorobenzene ND ug/L 1 01/20/12 17:10 95-50-11.0
1,3-Dichlorobenzene ND ug/L 1 01/20/12 17:10 541-73-11.0
1,4-Dichlorobenzene ND ug/L 1 01/20/12 17:10 106-46-71.0
Dichlorodifluoromethane ND ug/L 1 01/20/12 17:10 75-71-81.0
1,1-Dichloroethane ND ug/L 1 01/20/12 17:10 75-34-31.0
1,2-Dichloroethane ND ug/L 1 01/20/12 17:10 107-06-21.0
1,1-Dichloroethene ND ug/L 1 01/20/12 17:10 75-35-41.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 18 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Sample: TRIP BLANK Lab ID: 92110579005 Collected: 01/19/12 00:00 Received: 01/19/12 14:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
8260 MSV Low Level Analytical Method: EPA 8260
cis-1,2-Dichloroethene ND ug/L 1 01/20/12 17:10 156-59-21.0
trans-1,2-Dichloroethene ND ug/L 1 01/20/12 17:10 156-60-51.0
1,2-Dichloropropane ND ug/L 1 01/20/12 17:10 78-87-51.0
1,3-Dichloropropane ND ug/L 1 01/20/12 17:10 142-28-91.0
2,2-Dichloropropane ND ug/L 1 01/20/12 17:10 594-20-71.0
1,1-Dichloropropene ND ug/L 1 01/20/12 17:10 563-58-61.0
cis-1,3-Dichloropropene ND ug/L 1 01/20/12 17:10 10061-01-51.0
trans-1,3-Dichloropropene ND ug/L 1 01/20/12 17:10 10061-02-61.0
Diisopropyl ether ND ug/L 1 01/20/12 17:10 108-20-31.0
Ethylbenzene ND ug/L 1 01/20/12 17:10 100-41-41.0
Hexachloro-1,3-butadiene ND ug/L 1 01/20/12 17:10 87-68-31.0
2-Hexanone ND ug/L 1 01/20/12 17:10 591-78-65.0
p-Isopropyltoluene ND ug/L 1 01/20/12 17:10 99-87-61.0
Methylene Chloride 2.7 ug/L 1 01/20/12 17:10 75-09-22.0
4-Methyl-2-pentanone (MIBK) ND ug/L 1 01/20/12 17:10 108-10-15.0
Methyl-tert-butyl ether ND ug/L 1 01/20/12 17:10 1634-04-41.0
Naphthalene ND ug/L 1 01/20/12 17:10 91-20-31.0
Styrene ND ug/L 1 01/20/12 17:10 100-42-51.0
1,1,1,2-Tetrachloroethane ND ug/L 1 01/20/12 17:10 630-20-61.0
1,1,2,2-Tetrachloroethane ND ug/L 1 01/20/12 17:10 79-34-51.0
Tetrachloroethene ND ug/L 1 01/20/12 17:10 127-18-41.0
Toluene ND ug/L 1 01/20/12 17:10 108-88-31.0
1,2,3-Trichlorobenzene ND ug/L 1 01/20/12 17:10 87-61-61.0
1,2,4-Trichlorobenzene ND ug/L 1 01/20/12 17:10 120-82-11.0
1,1,1-Trichloroethane ND ug/L 1 01/20/12 17:10 71-55-61.0
1,1,2-Trichloroethane ND ug/L 1 01/20/12 17:10 79-00-51.0
Trichloroethene ND ug/L 1 01/20/12 17:10 79-01-61.0
Trichlorofluoromethane ND ug/L 1 01/20/12 17:10 75-69-41.0
1,2,3-Trichloropropane ND ug/L 1 01/20/12 17:10 96-18-41.0
Vinyl acetate ND ug/L 1 01/20/12 17:10 108-05-42.0
Vinyl chloride ND ug/L 1 01/20/12 17:10 75-01-41.0
m&p-Xylene ND ug/L 1 01/20/12 17:10 179601-23-12.0
o-Xylene ND ug/L 1 01/20/12 17:10 95-47-61.0
Surrogates
4-Bromofluorobenzene (S) 94 % 1 01/20/12 17:10 460-00-470-130
Dibromofluoromethane (S) 104 % 1 01/20/12 17:10 1868-53-770-130
1,2-Dichloroethane-d4 (S) 102 % 1 01/20/12 17:10 17060-07-070-130
Toluene-d8 (S) 95 % 1 01/20/12 17:10 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 19 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/3995
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92110579001, 92110579002, 92110579003, 92110579004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 713147
Associated Lab Samples:92110579001, 92110579002, 92110579003, 92110579004
Matrix: Water
Analyzed
Mercury ug/L ND 0.20 01/25/12 14:32
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
713148LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.02.5 80 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
713149MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92110483001
713150
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Mercury ug/L 2.5 114 75-125116 22.5ND 2.8 2.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 20 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/9765
EPA 3010
EPA 6010
6010 MET
Associated Lab Samples: 92110579001, 92110579002, 92110579003, 92110579004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 712269
Associated Lab Samples:92110579001, 92110579002, 92110579003, 92110579004
Matrix: Water
Analyzed
Antimony ug/L ND 5.0 01/23/12 15:53
Arsenic ug/L ND 5.0 01/23/12 15:53
Beryllium ug/L ND 1.0 01/23/12 15:53
Cadmium ug/L ND 1.0 01/23/12 15:53
Chromium ug/L ND 5.0 01/23/12 15:53
Copper ug/L ND 5.0 01/23/12 15:53
Lead ug/L ND 5.0 01/23/12 15:53
Manganese ug/L ND 5.0 01/23/12 15:53
Nickel ug/L ND 5.0 01/23/12 15:53
Selenium ug/L ND 10.0 01/23/12 15:53
Silver ug/L ND 5.0 01/23/12 15:53
Thallium ug/L ND 10.0 01/23/12 15:53
Zinc ug/L ND 10.0 01/23/12 15:53
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
712270LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 508500 102 80-120
Arsenic ug/L 501500 100 80-120
Beryllium ug/L 517500 103 80-120
Cadmium ug/L 517500 103 80-120
Chromium ug/L 517500 103 80-120
Copper ug/L 512500 102 80-120
Lead ug/L 512500 102 80-120
Manganese ug/L 514500 103 80-120
Nickel ug/L 515500 103 80-120
Selenium ug/L 508500 102 80-120
Silver ug/L 261250 104 80-120
Thallium ug/L 508500 102 80-120
Zinc ug/L 503500 101 80-120
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
712271MATRIX SPIKE SAMPLE:
MSSpike
Result
92110483001
Antimony ug/L 483500 96 75-125ND
Arsenic ug/L 475500 95 75-125ND
Beryllium ug/L 484500 97 75-125ND
Cadmium ug/L 481500 96 75-125ND
Chromium ug/L 485500 97 75-125ND
Copper ug/L 492500 97 75-1256.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 21 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
712271MATRIX SPIKE SAMPLE:
MSSpike
Result
92110483001
Lead ug/L 475500 95 75-125ND
Manganese ug/L 495500 96 75-12515.1
Nickel ug/L 483500 96 75-125ND
Selenium ug/L 473500 94 75-125ND
Silver ug/L 247250 99 75-125ND
Thallium ug/L 473500 94 75-125ND
Zinc ug/L 486500 94 75-12517.7
Parameter Units
Dup
Result QualifiersRPDResult
92110483002
712272SAMPLE DUPLICATE:
Antimony ug/L NDND
Arsenic ug/L NDND
Beryllium ug/L NDND
Cadmium ug/L NDND
Chromium ug/L NDND
Copper ug/L NDND
Lead ug/L NDND
Manganese ug/L 125 0125
Nickel ug/L NDND
Selenium ug/L NDND
Silver ug/L NDND
Thallium ug/L NDND
Zinc ug/L 25.1 324.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 22 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/17960
EPA 8260
EPA 8260
8260 MSV Low Level
Associated Lab Samples: 92110579001, 92110579002, 92110579003, 92110579004, 92110579005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 712453
Associated Lab Samples:92110579001, 92110579002, 92110579003, 92110579004, 92110579005
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 1.0 01/20/12 16:44
1,1,1-Trichloroethane ug/L ND 1.0 01/20/12 16:44
1,1,2,2-Tetrachloroethane ug/L ND 1.0 01/20/12 16:44
1,1,2-Trichloroethane ug/L ND 1.0 01/20/12 16:44
1,1-Dichloroethane ug/L ND 1.0 01/20/12 16:44
1,1-Dichloroethene ug/L ND 1.0 01/20/12 16:44
1,1-Dichloropropene ug/L ND 1.0 01/20/12 16:44
1,2,3-Trichlorobenzene ug/L ND 1.0 01/20/12 16:44
1,2,3-Trichloropropane ug/L ND 1.0 01/20/12 16:44
1,2,4-Trichlorobenzene ug/L ND 1.0 01/20/12 16:44
1,2-Dibromo-3-chloropropane ug/L ND 5.0 01/20/12 16:44
1,2-Dibromoethane (EDB) ug/L ND 1.0 01/20/12 16:44
1,2-Dichlorobenzene ug/L ND 1.0 01/20/12 16:44
1,2-Dichloroethane ug/L ND 1.0 01/20/12 16:44
1,2-Dichloropropane ug/L ND 1.0 01/20/12 16:44
1,3-Dichlorobenzene ug/L ND 1.0 01/20/12 16:44
1,3-Dichloropropane ug/L ND 1.0 01/20/12 16:44
1,4-Dichlorobenzene ug/L ND 1.0 01/20/12 16:44
2,2-Dichloropropane ug/L ND 1.0 01/20/12 16:44
2-Butanone (MEK) ug/L ND 5.0 01/20/12 16:44
2-Chlorotoluene ug/L ND 1.0 01/20/12 16:44
2-Hexanone ug/L ND 5.0 01/20/12 16:44
4-Chlorotoluene ug/L ND 1.0 01/20/12 16:44
4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 01/20/12 16:44
Acetone ug/L ND 25.0 01/20/12 16:44
Benzene ug/L ND 1.0 01/20/12 16:44
Bromobenzene ug/L ND 1.0 01/20/12 16:44
Bromochloromethane ug/L ND 1.0 01/20/12 16:44
Bromodichloromethane ug/L ND 1.0 01/20/12 16:44
Bromoform ug/L ND 1.0 01/20/12 16:44
Bromomethane ug/L ND 2.0 01/20/12 16:44
Carbon tetrachloride ug/L ND 1.0 01/20/12 16:44
Chlorobenzene ug/L ND 1.0 01/20/12 16:44
Chloroethane ug/L ND 1.0 01/20/12 16:44
Chloroform ug/L ND 1.0 01/20/12 16:44
Chloromethane ug/L ND 1.0 01/20/12 16:44
cis-1,2-Dichloroethene ug/L ND 1.0 01/20/12 16:44
cis-1,3-Dichloropropene ug/L ND 1.0 01/20/12 16:44
Dibromochloromethane ug/L ND 1.0 01/20/12 16:44
Dibromomethane ug/L ND 1.0 01/20/12 16:44
Dichlorodifluoromethane ug/L ND 1.0 01/20/12 16:44
Diisopropyl ether ug/L ND 1.0 01/20/12 16:44
Ethylbenzene ug/L ND 1.0 01/20/12 16:44
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 23 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 712453
Associated Lab Samples:92110579001, 92110579002, 92110579003, 92110579004, 92110579005
Matrix: Water
Analyzed
Hexachloro-1,3-butadiene ug/L ND 1.0 01/20/12 16:44
m&p-Xylene ug/L ND 2.0 01/20/12 16:44
Methyl-tert-butyl ether ug/L ND 1.0 01/20/12 16:44
Methylene Chloride ug/L ND 2.0 01/20/12 16:44
Naphthalene ug/L ND 1.0 01/20/12 16:44
o-Xylene ug/L ND 1.0 01/20/12 16:44
p-Isopropyltoluene ug/L ND 1.0 01/20/12 16:44
Styrene ug/L ND 1.0 01/20/12 16:44
Tetrachloroethene ug/L ND 1.0 01/20/12 16:44
Toluene ug/L ND 1.0 01/20/12 16:44
trans-1,2-Dichloroethene ug/L ND 1.0 01/20/12 16:44
trans-1,3-Dichloropropene ug/L ND 1.0 01/20/12 16:44
Trichloroethene ug/L ND 1.0 01/20/12 16:44
Trichlorofluoromethane ug/L ND 1.0 01/20/12 16:44
Vinyl acetate ug/L ND 2.0 01/20/12 16:44
Vinyl chloride ug/L ND 1.0 01/20/12 16:44
1,2-Dichloroethane-d4 (S) % 101 70-130 01/20/12 16:44
4-Bromofluorobenzene (S) % 95 70-130 01/20/12 16:44
Dibromofluoromethane (S) % 104 70-130 01/20/12 16:44
Toluene-d8 (S) % 95 70-130 01/20/12 16:44
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
712454LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 49.850 100 70-130
1,1,1-Trichloroethane ug/L 44.650 89 70-130
1,1,2,2-Tetrachloroethane ug/L 45.150 90 70-130
1,1,2-Trichloroethane ug/L 53.250 106 70-130
1,1-Dichloroethane ug/L 41.550 83 70-130
1,1-Dichloroethene ug/L 46.550 93 70-132
1,1-Dichloropropene ug/L 45.550 91 70-130
1,2,3-Trichlorobenzene ug/L 51.650 103 70-135
1,2,3-Trichloropropane ug/L 45.650 91 70-130
1,2,4-Trichlorobenzene ug/L 53.450 107 70-134
1,2-Dibromo-3-chloropropane ug/L 46.050 92 70-130
1,2-Dibromoethane (EDB) ug/L 51.150 102 70-130
1,2-Dichlorobenzene ug/L 49.950 100 70-130
1,2-Dichloroethane ug/L 46.550 93 70-130
1,2-Dichloropropane ug/L 49.650 99 70-130
1,3-Dichlorobenzene ug/L 49.450 99 70-130
1,3-Dichloropropane ug/L 48.850 98 70-130
1,4-Dichlorobenzene ug/L 48.350 97 70-130
2,2-Dichloropropane ug/L 44.150 88 58-145
2-Butanone (MEK) ug/L 101100 101 70-145
2-Chlorotoluene ug/L 48.950 98 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 24 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
712454LABORATORY CONTROL SAMPLE:
LCSSpike
2-Hexanone ug/L 105100 105 70-144
4-Chlorotoluene ug/L 51.350 103 70-130
4-Methyl-2-pentanone (MIBK) ug/L 104100 104 70-140
Acetone ug/L 99.9100 100 50-175
Benzene ug/L 49.150 98 70-130
Bromobenzene ug/L 50.450 101 70-130
Bromochloromethane ug/L 49.850 100 70-130
Bromodichloromethane ug/L 50.850 102 70-130
Bromoform ug/L 55.250 110 70-130
Bromomethane ug/L 46.050 92 54-130
Carbon tetrachloride ug/L 51.950 104 70-132
Chlorobenzene ug/L 49.550 99 70-130
Chloroethane ug/L 48.850 98 64-134
Chloroform ug/L 47.950 96 70-130
Chloromethane ug/L 46.450 93 64-130
cis-1,2-Dichloroethene ug/L 46.250 92 70-131
cis-1,3-Dichloropropene ug/L 52.850 106 70-130
Dibromochloromethane ug/L 51.850 104 70-130
Dibromomethane ug/L 50.250 100 70-131
Dichlorodifluoromethane ug/L 41.250 82 56-130
Diisopropyl ether ug/L 49.450 99 70-130
Ethylbenzene ug/L 49.950 100 70-130
Hexachloro-1,3-butadiene ug/L 50.650 101 70-130
m&p-Xylene ug/L 97.6100 98 70-130
Methyl-tert-butyl ether ug/L 50.550 101 70-130
Methylene Chloride ug/L 49.350 99 63-130
Naphthalene ug/L 48.550 97 70-138
o-Xylene ug/L 49.150 98 70-130
p-Isopropyltoluene ug/L 53.450 107 70-130
Styrene ug/L 51.450 103 70-130
Tetrachloroethene ug/L 47.650 95 70-130
Toluene ug/L 49.150 98 70-130
trans-1,2-Dichloroethene ug/L 44.750 89 70-130
trans-1,3-Dichloropropene ug/L 48.850 98 70-132
Trichloroethene ug/L 48.750 97 70-130
Trichlorofluoromethane ug/L 47.650 95 62-133
Vinyl acetate ug/L 76.3100 76 66-157
Vinyl chloride ug/L 51.950 104 69-130
1,2-Dichloroethane-d4 (S) % 95 70-130
4-Bromofluorobenzene (S) % 99 70-130
Dibromofluoromethane (S) % 97 70-130
Toluene-d8 (S) % 102 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 25 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
712455MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92110579001
712456
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1-Dichloroethene ug/L 50 95 70-166110 14501.1 48.8 56.0
Benzene ug/L 50 100 70-148113 1250ND50.0 56.5
Chlorobenzene ug/L 50 95 70-146109 1450ND47.4 54.4
Toluene ug/L 50 92 70-155105 1350ND45.9 52.5
Trichloroethene ug/L 50 97 69-151113 14503.3 51.6 59.6
1,2-Dichloroethane-d4 (S) % 104 70-130104
4-Bromofluorobenzene (S) %95 70-13096
Dibromofluoromethane (S) % 105 70-130105
Toluene-d8 (S) %96 70-13097
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 26 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/16211
EPA 3510
EPA 8270
8270 Water MSSV
Associated Lab Samples: 92110579001, 92110579002, 92110579003, 92110579004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 713048
Associated Lab Samples:92110579001, 92110579002, 92110579003, 92110579004
Matrix: Water
Analyzed
1,2,4-Trichlorobenzene ug/L ND 10.0 01/24/12 17:33
1,2-Dichlorobenzene ug/L ND 10.0 01/24/12 17:33
1,3-Dichlorobenzene ug/L ND 10.0 01/24/12 17:33
1,4-Dichlorobenzene ug/L ND 10.0 01/24/12 17:33
1-Methylnaphthalene ug/L ND 10.0 01/24/12 17:33
2,4,5-Trichlorophenol ug/L ND 10.0 01/24/12 17:33
2,4,6-Trichlorophenol ug/L ND 10.0 01/24/12 17:33
2,4-Dichlorophenol ug/L ND 10.0 01/24/12 17:33
2,4-Dimethylphenol ug/L ND 10.0 01/24/12 17:33
2,4-Dinitrophenol ug/L ND 50.0 01/24/12 17:33
2,4-Dinitrotoluene ug/L ND 10.0 01/24/12 17:33
2,6-Dinitrotoluene ug/L ND 10.0 01/24/12 17:33
2-Chloronaphthalene ug/L ND 10.0 01/24/12 17:33
2-Chlorophenol ug/L ND 10.0 01/24/12 17:33
2-Methylnaphthalene ug/L ND 10.0 01/24/12 17:33
2-Methylphenol(o-Cresol) ug/L ND 10.0 01/24/12 17:33
2-Nitroaniline ug/L ND 50.0 01/24/12 17:33
2-Nitrophenol ug/L ND 10.0 01/24/12 17:33
3&4-Methylphenol(m&p Cresol) ug/L ND 10.0 01/24/12 17:33
3,3'-Dichlorobenzidine ug/L ND 20.0 01/24/12 17:33
3-Nitroaniline ug/L ND 50.0 01/24/12 17:33
4,6-Dinitro-2-methylphenol ug/L ND 20.0 01/24/12 17:33
4-Bromophenylphenyl ether ug/L ND 10.0 01/24/12 17:33
4-Chloro-3-methylphenol ug/L ND 20.0 01/24/12 17:33
4-Chloroaniline ug/L ND 20.0 01/24/12 17:33
4-Chlorophenylphenyl ether ug/L ND 10.0 01/24/12 17:33
4-Nitroaniline ug/L ND 20.0 01/24/12 17:33
4-Nitrophenol ug/L ND 50.0 01/24/12 17:33
Acenaphthene ug/L ND 10.0 01/24/12 17:33
Acenaphthylene ug/L ND 10.0 01/24/12 17:33
Aniline ug/L ND 10.0 01/24/12 17:33
Anthracene ug/L ND 10.0 01/24/12 17:33
Benzo(a)anthracene ug/L ND 10.0 01/24/12 17:33
Benzo(a)pyrene ug/L ND 10.0 01/24/12 17:33
Benzo(b)fluoranthene ug/L ND 10.0 01/24/12 17:33
Benzo(g,h,i)perylene ug/L ND 10.0 01/24/12 17:33
Benzo(k)fluoranthene ug/L ND 10.0 01/24/12 17:33
Benzoic Acid ug/L ND 50.0 01/24/12 17:33
Benzyl alcohol ug/L ND 20.0 01/24/12 17:33
bis(2-Chloroethoxy)methane ug/L ND 10.0 01/24/12 17:33
bis(2-Chloroethyl) ether ug/L ND 10.0 01/24/12 17:33
bis(2-Chloroisopropyl) ether ug/L ND 10.0 01/24/12 17:33
bis(2-Ethylhexyl)phthalate ug/L ND 6.0 01/24/12 17:33
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 27 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 713048
Associated Lab Samples:92110579001, 92110579002, 92110579003, 92110579004
Matrix: Water
Analyzed
Butylbenzylphthalate ug/L ND 10.0 01/24/12 17:33
Chrysene ug/L ND 10.0 01/24/12 17:33
Di-n-butylphthalate ug/L ND 10.0 01/24/12 17:33
Di-n-octylphthalate ug/L ND 10.0 01/24/12 17:33
Dibenz(a,h)anthracene ug/L ND 10.0 01/24/12 17:33
Dibenzofuran ug/L ND 10.0 01/24/12 17:33
Diethylphthalate ug/L ND 10.0 01/24/12 17:33
Dimethylphthalate ug/L ND 10.0 01/24/12 17:33
Fluoranthene ug/L ND 10.0 01/24/12 17:33
Fluorene ug/L ND 10.0 01/24/12 17:33
Hexachloro-1,3-butadiene ug/L ND 10.0 01/24/12 17:33
Hexachlorobenzene ug/L ND 10.0 01/24/12 17:33
Hexachlorocyclopentadiene ug/L ND 10.0 01/24/12 17:33
Hexachloroethane ug/L ND 10.0 01/24/12 17:33
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 01/24/12 17:33
Isophorone ug/L ND 10.0 01/24/12 17:33
N-Nitroso-di-n-propylamine ug/L ND 10.0 01/24/12 17:33
N-Nitrosodimethylamine ug/L ND 10.0 01/24/12 17:33
N-Nitrosodiphenylamine ug/L ND 10.0 01/24/12 17:33
Naphthalene ug/L ND 10.0 01/24/12 17:33
Nitrobenzene ug/L ND 10.0 01/24/12 17:33
Pentachlorophenol ug/L ND 25.0 01/24/12 17:33
Phenanthrene ug/L ND 10.0 01/24/12 17:33
Phenol ug/L ND 10.0 01/24/12 17:33
Pyrene ug/L ND 10.0 01/24/12 17:33
2,4,6-Tribromophenol (S) % 56 27-110 01/24/12 17:33
2-Fluorobiphenyl (S) % 53 27-110 01/24/12 17:33
2-Fluorophenol (S) % 47 12-110 01/24/12 17:33
Nitrobenzene-d5 (S) % 54 21-110 01/24/12 17:33
Phenol-d6 (S) % 29 10-110 01/24/12 17:33
Terphenyl-d14 (S) % 68 31-107 01/24/12 17:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
713049LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 29.850 60 10-110
1,2-Dichlorobenzene ug/L 29.050 58 10-110
1,3-Dichlorobenzene ug/L 27.650 55 10-110
1,4-Dichlorobenzene ug/L 28.350 57 10-110
1-Methylnaphthalene ug/L 30.150 60 21-110
2,4,5-Trichlorophenol ug/L 28.850 58 23-116
2,4,6-Trichlorophenol ug/L 32.250 64 21-114
2,4-Dichlorophenol ug/L 32.650 65 22-120
2,4-Dimethylphenol ug/L 27.550 55 15-109
2,4-Dinitrophenol ug/L 138250 55 10-103
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 28 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
713049LABORATORY CONTROL SAMPLE:
LCSSpike
2,4-Dinitrotoluene ug/L 36.850 74 24-119
2,6-Dinitrotoluene ug/L 34.950 70 25-116
2-Chloronaphthalene ug/L 33.050 66 18-110
2-Chlorophenol ug/L 32.750 65 10-104
2-Methylnaphthalene ug/L 30.550 61 16-110
2-Methylphenol(o-Cresol) ug/L 28.850 58 13-110
2-Nitroaniline ug/L 61.6100 62 20-117
2-Nitrophenol ug/L 30.750 61 16-108
3&4-Methylphenol(m&p Cresol) ug/L 27.550 55 14-110
3,3'-Dichlorobenzidine ug/L 48.3100 48 13-131
3-Nitroaniline ug/L 71.5100 71 15-117
4,6-Dinitro-2-methylphenol ug/L 68.5100 69 13-119
4-Bromophenylphenyl ether ug/L 33.050 66 23-120
4-Chloro-3-methylphenol ug/L 67.3100 67 21-119
4-Chloroaniline ug/L 63.3100 63 10-122
4-Chlorophenylphenyl ether ug/L 32.550 65 22-112
4-Nitroaniline ug/L 57.0100 57 14-118
4-Nitrophenol ug/L 90.8250 36 10-110
Acenaphthene ug/L 31.750 63 20-105
Acenaphthylene ug/L 30.950 62 23-106
Aniline ug/L 27.550 55 10-110
Anthracene ug/L 33.050 66 25-120
Benzo(a)anthracene ug/L 35.650 71 21-128
Benzo(a)pyrene ug/L 33.350 67 25-116
Benzo(b)fluoranthene ug/L 34.150 68 23-117
Benzo(g,h,i)perylene ug/L 36.650 73 17-128
Benzo(k)fluoranthene ug/L 34.350 69 25-127
Benzoic Acid ug/L 47.8J250 19 10-110
Benzyl alcohol ug/L 66.7100 67 10-101
bis(2-Chloroethoxy)methane ug/L 30.950 62 19-107
bis(2-Chloroethyl) ether ug/L 32.550 65 10-108
bis(2-Chloroisopropyl) ether ug/L 30.850 62 10-108
bis(2-Ethylhexyl)phthalate ug/L 37.250 74 16-123
Butylbenzylphthalate ug/L 36.450 73 20-118
Chrysene ug/L 35.850 72 24-125
Di-n-butylphthalate ug/L 37.950 76 23-115
Di-n-octylphthalate ug/L 37.650 75 20-115
Dibenz(a,h)anthracene ug/L 36.950 74 18-131
Dibenzofuran ug/L 32.650 65 23-106
Diethylphthalate ug/L 34.950 70 24-115
Dimethylphthalate ug/L 33.950 68 22-113
Fluoranthene ug/L 37.250 74 24-125
Fluorene ug/L 31.650 63 24-114
Hexachloro-1,3-butadiene ug/L 27.850 56 10-110
Hexachlorobenzene ug/L 34.450 69 22-127
Hexachlorocyclopentadiene ug/L 40.450 81 10-110
Hexachloroethane ug/L 26.650 53 10-110
Indeno(1,2,3-cd)pyrene ug/L 36.550 73 18-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 29 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
713049LABORATORY CONTROL SAMPLE:
LCSSpike
Isophorone ug/L 34.350 69 23-114
N-Nitroso-di-n-propylamine ug/L 35.950 72 21-114
N-Nitrosodimethylamine ug/L 24.450 49 10-110
N-Nitrosodiphenylamine ug/L 34.650 69 24-123
Naphthalene ug/L 29.450 59 14-110
Nitrobenzene ug/L 32.850 66 16-106
Pentachlorophenol ug/L 85.6100 86 10-123
Phenanthrene ug/L 33.250 66 25-119
Phenol ug/L 17.550 35 10-110
Pyrene ug/L 32.950 66 22-127
2,4,6-Tribromophenol (S) % 90 27-110
2-Fluorobiphenyl (S) % 72 27-110
2-Fluorophenol (S) % 50 12-110
Nitrobenzene-d5 (S) % 73 21-110
Phenol-d6 (S) % 34 10-110
Terphenyl-d14 (S) % 84 31-107
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 30 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/11370
EPA 7196
EPA 7196
7196 Chromium, Hexavalent
Associated Lab Samples: 92110579001, 92110579002, 92110579003, 92110579004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 712229
Associated Lab Samples:92110579001, 92110579002, 92110579003, 92110579004
Matrix: Water
Analyzed
Chromium, Hexavalent mg/L ND 0.050 N201/19/12 21:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
712230LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent mg/L 0.51 N2.5 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
712231MATRIX SPIKE SAMPLE:
MSSpike
Result
92110579003
Chromium, Hexavalent mg/L 0.47 N2.5 94 75-125ND
Parameter Units
Dup
Result QualifiersRPDResult
92110579003
712232SAMPLE DUPLICATE:
Chromium, Hexavalent mg/L ND N2ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 31 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALIFIERS
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution ofthe sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The lab does not hold TNI accreditation for this parameter.N2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 32 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92110579
PLIANA 6228-09-5055
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92110579001 MPRP/9765 ICP/9012MW-1024 EPA 3010 EPA 6010
92110579002 MPRP/9765 ICP/9012MW-1 EPA 3010 EPA 6010
92110579003 MPRP/9765 ICP/9012MW-2 EPA 3010 EPA 6010
92110579004 MPRP/9765 ICP/9012DUPLICATEEPA 3010 EPA 6010
92110579001 MERP/3995 MERC/3924MW-1024 EPA 7470 EPA 7470
92110579002 MERP/3995 MERC/3924MW-1 EPA 7470 EPA 7470
92110579003 MERP/3995 MERC/3924MW-2 EPA 7470 EPA 7470
92110579004 MERP/3995 MERC/3924DUPLICATEEPA 7470 EPA 7470
92110579001 OEXT/16211 MSSV/5908MW-1024 EPA 3510 EPA 8270
92110579002 OEXT/16211 MSSV/5908MW-1 EPA 3510 EPA 8270
92110579003 OEXT/16211 MSSV/5908MW-2 EPA 3510 EPA 8270
92110579004 OEXT/16211 MSSV/5908DUPLICATEEPA 3510 EPA 8270
92110579001 MSV/17960MW-1024 EPA 8260
92110579002 MSV/17960MW-1 EPA 8260
92110579003 MSV/17960MW-2 EPA 8260
92110579004 MSV/17960DUPLICATEEPA 8260
92110579005 MSV/17960TRIP BLANK EPA 8260
92110579001 WETA/11370MW-1024 EPA 7196
92110579002 WETA/11370MW-1 EPA 7196
92110579003 WETA/11370MW-2 EPA 7196
92110579004 WETA/11370DUPLICATEEPA 7196
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/26/2012 04:20 PM Page 33 of 33
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
January 31, 2012
LIMS USE: FR - ROB FOSTER
LIMS OBJECT ID: 92110595
92110595
Project:
Pace Project No.:
RE:
Mr. Rob FosterAMEC-Charlotte2801 Yorkmont Road Suite 100Charlotte, NC 28208
PLIANA 6228-09-5055
Dear Mr. Foster:
Enclosed are the analytical results for sample(s) received by the laboratory on January 20, 2012.
The results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail] Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Received and reviewed by AJF 1/31/12
CERTIFICATIONS
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
Minnesota Certification IDs1700 Elm Street SE Suite 200, Minneapolis, MN 55414A2LA Certification #: 2926.01Alaska Certification #: UST-078Alaska Certification #MN00064Arizona Certification #: AZ-0014Arkansas Certification #: 88-0680California Certification #: 01155CAEPA Region 8 Certification #: PaceFlorida/NELAP Certification #: E87605Georgia Certification #: 959Idaho Certification #: MN00064Illinois Certification #: 200011Iowa Certification #: 368Kansas Certification #: E-10167Louisiana Certification #: 03086Louisiana Certification #: LA080009Maine Certification #: 2007029Maryland Certification #: 322Michigan DEQ Certification #: 9909Minnesota Certification #: 027-053-137
Mississippi Certification #: PaceMontana Certification #: MT CERT0092Nevada Certification #: MN_00064Nebraska Certification #: PaceNew Jersey Certification #: MN-002New Mexico Certification #: PaceNew York Certification #: 11647North Carolina Certification #: 530North Dakota Certification #: R-036North Dakota Certification #: R-036AOhio VAP Certification #: CL101Oklahoma Certification #: D9921Oklahoma Certification #: 9507Oregon Certification #: MN200001Pennsylvania Certification #: 68-00563Puerto Rico CertificationTennessee Certification #: 02818Texas Certification #: T104704192Washington Certification #: C754Wisconsin Certification #: 999407970
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92110595001 SG-1 Method 3C Gases 1 PASI-MRTP
TO-15 59 PASI-MDR1
92110595002 SG-2 Method 3C Gases 1 PASI-MRTP
TO-15 59 PASI-MDR1
92110595003 SG-3 Method 3C Gases 1 PASI-MRTP
TO-15 59 PASI-MDR1
92110595004 SG-4 Method 3C Gases 1 PASI-MRTP
TO-15 59 PASI-MDR1
92110595005 SG-5 Method 3C Gases 1 PASI-MRTP
TO-15 59 PASI-MDR1
92110595006 SG-6 Method 3C Gases 1 PASI-MRTP
TO-15 59 PASI-MDR1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
Sample: SG-1 Lab ID: 92110595001 Collected: 01/19/12 16:50 Received: 01/20/12 09:55 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Method 3C AIR - Fixed Gases Analytical Method: Method 3C Gases
Helium ND % 1.38 01/25/12 09:46 7440-59-75.0
TO15 MSV AIR Analytical Method: TO-15
Acetone 8.3 ug/m3 1.34 01/27/12 18:50 67-64-10.64
Benzene ND ug/m3 1.34 01/27/12 18:50 71-43-20.44
Bromodichloromethane ND ug/m3 1.34 01/27/12 18:50 75-27-41.9
Bromoform ND ug/m3 1.34 01/27/12 18:50 75-25-22.8
Bromomethane ND ug/m3 1.34 01/27/12 18:50 74-83-91.1
1,3-Butadiene ND ug/m3 1.34 01/27/12 18:50 106-99-00.60
2-Butanone (MEK)0.92 ug/m3 1.34 01/27/12 18:50 78-93-30.80
Carbon disulfide ND ug/m3 1.34 01/27/12 18:50 75-15-00.84
Carbon tetrachloride ND ug/m3 1.34 01/27/12 18:50 56-23-50.86
Chlorobenzene ND ug/m3 1.34 01/27/12 18:50 108-90-71.3
Chloroethane ND ug/m3 1.34 01/27/12 18:50 75-00-30.72
Chloroform ND ug/m3 1.34 01/27/12 18:50 67-66-31.3
Chloromethane ND ug/m3 1.34 01/27/12 18:50 74-87-30.56
Cyclohexane ND ug/m3 1.34 01/27/12 18:50 110-82-70.91
Dibromochloromethane ND ug/m3 1.34 01/27/12 18:50 124-48-12.3
1,2-Dibromoethane (EDB) ND ug/m3 1.34 01/27/12 18:50 106-93-42.1
1,2-Dichlorobenzene ND ug/m3 1.34 01/27/12 18:50 95-50-11.6
1,3-Dichlorobenzene ND ug/m3 1.34 01/27/12 18:50 541-73-11.6
1,4-Dichlorobenzene ND ug/m3 1.34 01/27/12 18:50 106-46-71.6
Dichlorodifluoromethane 2.4 ug/m3 1.34 01/27/12 18:50 75-71-81.3
1,1-Dichloroethane ND ug/m3 1.34 01/27/12 18:50 75-34-31.1
1,2-Dichloroethane ND ug/m3 1.34 01/27/12 18:50 107-06-20.55
1,1-Dichloroethene ND ug/m3 1.34 01/27/12 18:50 75-35-41.1
cis-1,2-Dichloroethene ND ug/m3 1.34 01/27/12 18:50 156-59-21.1
trans-1,2-Dichloroethene ND ug/m3 1.34 01/27/12 18:50 156-60-51.1
1,2-Dichloropropane ND ug/m3 1.34 01/27/12 18:50 78-87-51.3
cis-1,3-Dichloropropene ND ug/m3 1.34 01/27/12 18:50 10061-01-51.2
trans-1,3-Dichloropropene ND ug/m3 1.34 01/27/12 18:50 10061-02-61.2
Dichlorotetrafluoroethane ND ug/m3 1.34 01/27/12 18:50 76-14-21.9
Ethyl acetate ND ug/m3 1.34 01/27/12 18:50 141-78-60.98
Ethylbenzene ND ug/m3 1.34 01/27/12 18:50 100-41-41.2
4-Ethyltoluene ND ug/m3 1.34 01/27/12 18:50 622-96-83.4
n-Heptane ND ug/m3 1.34 01/27/12 18:50 142-82-51.1
Hexachloro-1,3-butadiene ND ug/m3 1.34 01/27/12 18:50 87-68-32.9
n-Hexane 1.6 ug/m3 1.34 01/27/12 18:50 110-54-30.96
2-Hexanone ND ug/m3 1.34 01/27/12 18:50 591-78-61.1
Methylene Chloride 8.3 ug/m3 1.34 01/27/12 18:50 75-09-20.95
4-Methyl-2-pentanone (MIBK) ND ug/m3 1.34 01/27/12 18:50 108-10-11.1
Methyl-tert-butyl ether ND ug/m3 1.34 01/27/12 18:50 1634-04-40.98
Naphthalene ND ug/m3 1.34 01/27/12 18:50 91-20-33.6
Propylene ND ug/m3 1.34 01/27/12 18:50 115-07-10.47
Styrene ND ug/m3 1.34 01/27/12 18:50 100-42-51.2
1,1,2,2-Tetrachloroethane ND ug/m3 1.34 01/27/12 18:50 79-34-50.94
Tetrachloroethene 19.4 ug/m3 1.34 01/27/12 18:50 127-18-40.92
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/31/2012 08:49 AM Page 4 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
Sample: SG-1 Lab ID: 92110595001 Collected: 01/19/12 16:50 Received: 01/20/12 09:55 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
TO15 MSV AIR Analytical Method: TO-15
Tetrahydrofuran ND ug/m3 1.34 01/27/12 18:50 109-99-90.80
THC as Gas 658 ug/m3 1.34 01/27/12 18:5081.5
Toluene 1.0 ug/m3 1.34 01/27/12 18:50 108-88-31.0
1,2,4-Trichlorobenzene ND ug/m3 1.34 01/27/12 18:50 120-82-11.3
1,1,1-Trichloroethane 10.5 ug/m3 1.34 01/27/12 18:50 71-55-61.5
1,1,2-Trichloroethane ND ug/m3 1.34 01/27/12 18:50 79-00-50.74
Trichloroethene 0.82 ug/m3 1.34 01/27/12 18:50 79-01-60.74
Trichlorofluoromethane ND ug/m3 1.34 01/27/12 18:50 75-69-41.5
1,1,2-Trichlorotrifluoroethane ND ug/m3 1.34 01/27/12 18:50 76-13-12.1
1,2,4-Trimethylbenzene 1.6 ug/m3 1.34 01/27/12 18:50 95-63-61.3
1,3,5-Trimethylbenzene ND ug/m3 1.34 01/27/12 18:50 108-67-81.3
Vinyl acetate ND ug/m3 1.34 01/27/12 18:50 108-05-40.95
Vinyl chloride ND ug/m3 1.34 01/27/12 18:50 75-01-40.35
m&p-Xylene ND ug/m3 1.34 01/27/12 18:50 179601-23-12.4
o-Xylene ND ug/m3 1.34 01/27/12 18:50 95-47-61.2
Sample: SG-2 Lab ID: 92110595002 Collected: 01/19/12 16:52 Received: 01/20/12 09:55 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Method 3C AIR - Fixed Gases Analytical Method: Method 3C Gases
Helium ND % 1.21 01/25/12 10:14 7440-59-74.4
TO15 MSV AIR Analytical Method: TO-15
Acetone 20.5 ug/m3 1.44 01/27/12 19:18 67-64-10.69
Benzene ND ug/m3 1.44 01/27/12 19:18 71-43-20.47
Bromodichloromethane ND ug/m3 1.44 01/27/12 19:18 75-27-42.0
Bromoform ND ug/m3 1.44 01/27/12 19:18 75-25-23.0
Bromomethane ND ug/m3 1.44 01/27/12 19:18 74-83-91.1
1,3-Butadiene ND ug/m3 1.44 01/27/12 19:18 106-99-00.65
2-Butanone (MEK)2.0 ug/m3 1.44 01/27/12 19:18 78-93-30.86
Carbon disulfide 2.1 ug/m3 1.44 01/27/12 19:18 75-15-00.91
Carbon tetrachloride ND ug/m3 1.44 01/27/12 19:18 56-23-50.92
Chlorobenzene ND ug/m3 1.44 01/27/12 19:18 108-90-71.4
Chloroethane ND ug/m3 1.44 01/27/12 19:18 75-00-30.78
Chloroform ND ug/m3 1.44 01/27/12 19:18 67-66-31.4
Chloromethane ND ug/m3 1.44 01/27/12 19:18 74-87-30.60
Cyclohexane ND ug/m3 1.44 01/27/12 19:18 110-82-70.98
Dibromochloromethane ND ug/m3 1.44 01/27/12 19:18 124-48-12.4
1,2-Dibromoethane (EDB) ND ug/m3 1.44 01/27/12 19:18 106-93-42.3
1,2-Dichlorobenzene ND ug/m3 1.44 01/27/12 19:18 95-50-11.7
1,3-Dichlorobenzene ND ug/m3 1.44 01/27/12 19:18 541-73-11.7
1,4-Dichlorobenzene ND ug/m3 1.44 01/27/12 19:18 106-46-71.7
Dichlorodifluoromethane 2.6 ug/m3 1.44 01/27/12 19:18 75-71-81.4
1,1-Dichloroethane ND ug/m3 1.44 01/27/12 19:18 75-34-31.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/31/2012 08:49 AM Page 5 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
Sample: SG-2 Lab ID: 92110595002 Collected: 01/19/12 16:52 Received: 01/20/12 09:55 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
TO15 MSV AIR Analytical Method: TO-15
1,2-Dichloroethane ND ug/m3 1.44 01/27/12 19:18 107-06-20.59
1,1-Dichloroethene ND ug/m3 1.44 01/27/12 19:18 75-35-41.2
cis-1,2-Dichloroethene ND ug/m3 1.44 01/27/12 19:18 156-59-21.2
trans-1,2-Dichloroethene ND ug/m3 1.44 01/27/12 19:18 156-60-51.2
1,2-Dichloropropane ND ug/m3 1.44 01/27/12 19:18 78-87-51.4
cis-1,3-Dichloropropene ND ug/m3 1.44 01/27/12 19:18 10061-01-51.3
trans-1,3-Dichloropropene ND ug/m3 1.44 01/27/12 19:18 10061-02-61.3
Dichlorotetrafluoroethane ND ug/m3 1.44 01/27/12 19:18 76-14-22.0
Ethyl acetate 3.0 ug/m3 1.44 01/27/12 19:18 141-78-61.1
Ethylbenzene ND ug/m3 1.44 01/27/12 19:18 100-41-41.3
4-Ethyltoluene ND ug/m3 1.44 01/27/12 19:18 622-96-83.6
n-Heptane ND ug/m3 1.44 01/27/12 19:18 142-82-51.2
Hexachloro-1,3-butadiene ND ug/m3 1.44 01/27/12 19:18 87-68-33.2
n-Hexane 12.2 ug/m3 1.44 01/27/12 19:18 110-54-31.0
2-Hexanone ND ug/m3 1.44 01/27/12 19:18 591-78-61.2
Methylene Chloride 24.6 ug/m3 1.44 01/27/12 19:18 75-09-21.0
4-Methyl-2-pentanone (MIBK) ND ug/m3 1.44 01/27/12 19:18 108-10-11.2
Methyl-tert-butyl ether ND ug/m3 1.44 01/27/12 19:18 1634-04-41.1
Naphthalene ND ug/m3 1.44 01/27/12 19:18 91-20-33.9
Propylene ND ug/m3 1.44 01/27/12 19:18 115-07-10.50
Styrene ND ug/m3 1.44 01/27/12 19:18 100-42-51.3
1,1,2,2-Tetrachloroethane ND ug/m3 1.44 01/27/12 19:18 79-34-51.0
Tetrachloroethene 144 ug/m3 1.44 01/27/12 19:18 127-18-40.99
Tetrahydrofuran ND ug/m3 1.44 01/27/12 19:18 109-99-90.86
THC as Gas 944 ug/m3 1.44 01/27/12 19:1887.6
Toluene 5.1 ug/m3 1.44 01/27/12 19:18 108-88-31.1
1,2,4-Trichlorobenzene ND ug/m3 1.44 01/27/12 19:18 120-82-11.4
1,1,1-Trichloroethane 18.8 ug/m3 1.44 01/27/12 19:18 71-55-61.6
1,1,2-Trichloroethane ND ug/m3 1.44 01/27/12 19:18 79-00-50.79
Trichloroethene 17.3 ug/m3 1.44 01/27/12 19:18 79-01-60.79
Trichlorofluoromethane ND ug/m3 1.44 01/27/12 19:18 75-69-41.6
1,1,2-Trichlorotrifluoroethane ND ug/m3 1.44 01/27/12 19:18 76-13-12.3
1,2,4-Trimethylbenzene 1.7 ug/m3 1.44 01/27/12 19:18 95-63-61.4
1,3,5-Trimethylbenzene ND ug/m3 1.44 01/27/12 19:18 108-67-81.4
Vinyl acetate ND ug/m3 1.44 01/27/12 19:18 108-05-41.0
Vinyl chloride ND ug/m3 1.44 01/27/12 19:18 75-01-40.37
m&p-Xylene ND ug/m3 1.44 01/27/12 19:18 179601-23-12.5
o-Xylene ND ug/m3 1.44 01/27/12 19:18 95-47-61.3
Sample: SG-3 Lab ID: 92110595003 Collected: 01/19/12 16:54 Received: 01/20/12 09:55 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Method 3C AIR - Fixed Gases Analytical Method: Method 3C Gases
Helium ND % 1.58 01/25/12 10:26 7440-59-75.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/31/2012 08:49 AM Page 6 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
Sample: SG-3 Lab ID: 92110595003 Collected: 01/19/12 16:54 Received: 01/20/12 09:55 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
TO15 MSV AIR Analytical Method: TO-15
Acetone 36.5 ug/m3 1.39 01/27/12 19:46 67-64-10.67
Benzene 0.52 ug/m3 1.39 01/27/12 19:46 71-43-20.45
Bromodichloromethane ND ug/m3 1.39 01/27/12 19:46 75-27-41.9
Bromoform ND ug/m3 1.39 01/27/12 19:46 75-25-22.9
Bromomethane ND ug/m3 1.39 01/27/12 19:46 74-83-91.1
1,3-Butadiene ND ug/m3 1.39 01/27/12 19:46 106-99-00.63
2-Butanone (MEK)6.4 ug/m3 1.39 01/27/12 19:46 78-93-30.83
Carbon disulfide 16.7 ug/m3 1.39 01/27/12 19:46 75-15-00.88
Carbon tetrachloride ND ug/m3 1.39 01/27/12 19:46 56-23-50.89
Chlorobenzene ND ug/m3 1.39 01/27/12 19:46 108-90-71.3
Chloroethane ND ug/m3 1.39 01/27/12 19:46 75-00-30.75
Chloroform ND ug/m3 1.39 01/27/12 19:46 67-66-31.4
Chloromethane ND ug/m3 1.39 01/27/12 19:46 74-87-30.58
Cyclohexane ND ug/m3 1.39 01/27/12 19:46 110-82-70.95
Dibromochloromethane ND ug/m3 1.39 01/27/12 19:46 124-48-12.4
1,2-Dibromoethane (EDB) ND ug/m3 1.39 01/27/12 19:46 106-93-42.2
1,2-Dichlorobenzene ND ug/m3 1.39 01/27/12 19:46 95-50-11.7
1,3-Dichlorobenzene ND ug/m3 1.39 01/27/12 19:46 541-73-11.7
1,4-Dichlorobenzene ND ug/m3 1.39 01/27/12 19:46 106-46-71.7
Dichlorodifluoromethane 2.4 ug/m3 1.39 01/27/12 19:46 75-71-81.4
1,1-Dichloroethane ND ug/m3 1.39 01/27/12 19:46 75-34-31.1
1,2-Dichloroethane ND ug/m3 1.39 01/27/12 19:46 107-06-20.57
1,1-Dichloroethene ND ug/m3 1.39 01/27/12 19:46 75-35-41.1
cis-1,2-Dichloroethene ND ug/m3 1.39 01/27/12 19:46 156-59-21.1
trans-1,2-Dichloroethene ND ug/m3 1.39 01/27/12 19:46 156-60-51.1
1,2-Dichloropropane ND ug/m3 1.39 01/27/12 19:46 78-87-51.3
cis-1,3-Dichloropropene ND ug/m3 1.39 01/27/12 19:46 10061-01-51.3
trans-1,3-Dichloropropene ND ug/m3 1.39 01/27/12 19:46 10061-02-61.3
Dichlorotetrafluoroethane ND ug/m3 1.39 01/27/12 19:46 76-14-21.9
Ethyl acetate 2.5 ug/m3 1.39 01/27/12 19:46 141-78-61.0
Ethylbenzene ND ug/m3 1.39 01/27/12 19:46 100-41-41.2
4-Ethyltoluene ND ug/m3 1.39 01/27/12 19:46 622-96-83.5
n-Heptane 1.6 ug/m3 1.39 01/27/12 19:46 142-82-51.2
Hexachloro-1,3-butadiene ND ug/m3 1.39 01/27/12 19:46 87-68-33.1
n-Hexane 2.3 ug/m3 1.39 01/27/12 19:46 110-54-31.0
2-Hexanone ND ug/m3 1.39 01/27/12 19:46 591-78-61.2
Methylene Chloride ND ug/m3 1.39 01/27/12 19:46 75-09-20.99
4-Methyl-2-pentanone (MIBK) ND ug/m3 1.39 01/27/12 19:46 108-10-11.2
Methyl-tert-butyl ether ND ug/m3 1.39 01/27/12 19:46 1634-04-41.0
Naphthalene ND ug/m3 1.39 01/27/12 19:46 91-20-33.8
Propylene ND ug/m3 1.39 01/27/12 19:46 115-07-10.49
Styrene 1.3 ug/m3 1.39 01/27/12 19:46 100-42-51.2
1,1,2,2-Tetrachloroethane ND ug/m3 1.39 01/27/12 19:46 79-34-50.97
Tetrachloroethene 1.2 ug/m3 1.39 01/27/12 19:46 127-18-40.96
Tetrahydrofuran ND ug/m3 1.39 01/27/12 19:46 109-99-90.83
THC as Gas 427 ug/m3 1.39 01/27/12 19:4684.5
Toluene 4.3 ug/m3 1.39 01/27/12 19:46 108-88-31.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/31/2012 08:49 AM Page 7 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
Sample: SG-3 Lab ID: 92110595003 Collected: 01/19/12 16:54 Received: 01/20/12 09:55 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
TO15 MSV AIR Analytical Method: TO-15
1,2,4-Trichlorobenzene ND ug/m3 1.39 01/27/12 19:46 120-82-11.4
1,1,1-Trichloroethane ND ug/m3 1.39 01/27/12 19:46 71-55-61.5
1,1,2-Trichloroethane ND ug/m3 1.39 01/27/12 19:46 79-00-50.76
Trichloroethene 1.3 ug/m3 1.39 01/27/12 19:46 79-01-60.76
Trichlorofluoromethane 5.5 ug/m3 1.39 01/27/12 19:46 75-69-41.5
1,1,2-Trichlorotrifluoroethane ND ug/m3 1.39 01/27/12 19:46 76-13-12.2
1,2,4-Trimethylbenzene ND ug/m3 1.39 01/27/12 19:46 95-63-61.4
1,3,5-Trimethylbenzene ND ug/m3 1.39 01/27/12 19:46 108-67-81.4
Vinyl acetate ND ug/m3 1.39 01/27/12 19:46 108-05-40.99
Vinyl chloride ND ug/m3 1.39 01/27/12 19:46 75-01-40.36
m&p-Xylene ND ug/m3 1.39 01/27/12 19:46 179601-23-12.4
o-Xylene ND ug/m3 1.39 01/27/12 19:46 95-47-61.2
Sample: SG-4 Lab ID: 92110595004 Collected: 01/19/12 16:56 Received: 01/20/12 09:55 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Method 3C AIR - Fixed Gases Analytical Method: Method 3C Gases
Helium ND % 0.93 01/25/12 10:35 7440-59-73.3
TO15 MSV AIR Analytical Method: TO-15
Acetone 5.7 ug/m3 1.34 01/27/12 20:14 67-64-10.64
Benzene 0.57 ug/m3 1.34 01/27/12 20:14 71-43-20.44
Bromodichloromethane ND ug/m3 1.34 01/27/12 20:14 75-27-41.9
Bromoform ND ug/m3 1.34 01/27/12 20:14 75-25-22.8
Bromomethane ND ug/m3 1.34 01/27/12 20:14 74-83-91.1
1,3-Butadiene ND ug/m3 1.34 01/27/12 20:14 106-99-00.60
2-Butanone (MEK)6.7 ug/m3 1.34 01/27/12 20:14 78-93-30.80
Carbon disulfide ND ug/m3 1.34 01/27/12 20:14 75-15-00.84
Carbon tetrachloride ND ug/m3 1.34 01/27/12 20:14 56-23-50.86
Chlorobenzene ND ug/m3 1.34 01/27/12 20:14 108-90-71.3
Chloroethane ND ug/m3 1.34 01/27/12 20:14 75-00-30.72
Chloroform ND ug/m3 1.34 01/27/12 20:14 67-66-31.3
Chloromethane 1.0 ug/m3 1.34 01/27/12 20:14 74-87-30.56
Cyclohexane ND ug/m3 1.34 01/27/12 20:14 110-82-70.91
Dibromochloromethane ND ug/m3 1.34 01/27/12 20:14 124-48-12.3
1,2-Dibromoethane (EDB) ND ug/m3 1.34 01/27/12 20:14 106-93-42.1
1,2-Dichlorobenzene ND ug/m3 1.34 01/27/12 20:14 95-50-11.6
1,3-Dichlorobenzene ND ug/m3 1.34 01/27/12 20:14 541-73-11.6
1,4-Dichlorobenzene ND ug/m3 1.34 01/27/12 20:14 106-46-71.6
Dichlorodifluoromethane 2.9 ug/m3 1.34 01/27/12 20:14 75-71-81.3
1,1-Dichloroethane ND ug/m3 1.34 01/27/12 20:14 75-34-31.1
1,2-Dichloroethane ND ug/m3 1.34 01/27/12 20:14 107-06-20.55
1,1-Dichloroethene ND ug/m3 1.34 01/27/12 20:14 75-35-41.1
cis-1,2-Dichloroethene ND ug/m3 1.34 01/27/12 20:14 156-59-21.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/31/2012 08:49 AM Page 8 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
Sample: SG-4 Lab ID: 92110595004 Collected: 01/19/12 16:56 Received: 01/20/12 09:55 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
TO15 MSV AIR Analytical Method: TO-15
trans-1,2-Dichloroethene ND ug/m3 1.34 01/27/12 20:14 156-60-51.1
1,2-Dichloropropane ND ug/m3 1.34 01/27/12 20:14 78-87-51.3
cis-1,3-Dichloropropene ND ug/m3 1.34 01/27/12 20:14 10061-01-51.2
trans-1,3-Dichloropropene ND ug/m3 1.34 01/27/12 20:14 10061-02-61.2
Dichlorotetrafluoroethane ND ug/m3 1.34 01/27/12 20:14 76-14-21.9
Ethyl acetate 8.5 ug/m3 1.34 01/27/12 20:14 141-78-60.98
Ethylbenzene ND ug/m3 1.34 01/27/12 20:14 100-41-41.2
4-Ethyltoluene ND ug/m3 1.34 01/27/12 20:14 622-96-83.4
n-Heptane ND ug/m3 1.34 01/27/12 20:14 142-82-51.1
Hexachloro-1,3-butadiene ND ug/m3 1.34 01/27/12 20:14 87-68-32.9
n-Hexane ND ug/m3 1.34 01/27/12 20:14 110-54-30.96
2-Hexanone ND ug/m3 1.34 01/27/12 20:14 591-78-61.1
Methylene Chloride ND ug/m3 1.34 01/27/12 20:14 75-09-20.95
4-Methyl-2-pentanone (MIBK) ND ug/m3 1.34 01/27/12 20:14 108-10-11.1
Methyl-tert-butyl ether ND ug/m3 1.34 01/27/12 20:14 1634-04-40.98
Naphthalene ND ug/m3 1.34 01/27/12 20:14 91-20-33.6
Propylene ND ug/m3 1.34 01/27/12 20:14 115-07-10.47
Styrene 1.5 ug/m3 1.34 01/27/12 20:14 100-42-51.2
1,1,2,2-Tetrachloroethane ND ug/m3 1.34 01/27/12 20:14 79-34-50.94
Tetrachloroethene ND ug/m3 1.34 01/27/12 20:14 127-18-40.92
Tetrahydrofuran ND ug/m3 1.34 01/27/12 20:14 109-99-90.80
THC as Gas ND ug/m3 1.34 01/27/12 20:1481.5
Toluene 5.0 ug/m3 1.34 01/27/12 20:14 108-88-31.0
1,2,4-Trichlorobenzene ND ug/m3 1.34 01/27/12 20:14 120-82-11.3
1,1,1-Trichloroethane ND ug/m3 1.34 01/27/12 20:14 71-55-61.5
1,1,2-Trichloroethane ND ug/m3 1.34 01/27/12 20:14 79-00-50.74
Trichloroethene ND ug/m3 1.34 01/27/12 20:14 79-01-60.74
Trichlorofluoromethane 1.6 ug/m3 1.34 01/27/12 20:14 75-69-41.5
1,1,2-Trichlorotrifluoroethane ND ug/m3 1.34 01/27/12 20:14 76-13-12.1
1,2,4-Trimethylbenzene ND ug/m3 1.34 01/27/12 20:14 95-63-61.3
1,3,5-Trimethylbenzene ND ug/m3 1.34 01/27/12 20:14 108-67-81.3
Vinyl acetate ND ug/m3 1.34 01/27/12 20:14 108-05-40.95
Vinyl chloride ND ug/m3 1.34 01/27/12 20:14 75-01-40.35
m&p-Xylene ND ug/m3 1.34 01/27/12 20:14 179601-23-12.4
o-Xylene ND ug/m3 1.34 01/27/12 20:14 95-47-61.2
Sample: SG-5 Lab ID: 92110595005 Collected: 01/19/12 16:58 Received: 01/20/12 09:55 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Method 3C AIR - Fixed Gases Analytical Method: Method 3C Gases
Helium ND % 1.74 01/25/12 10:45 7440-59-76.3
TO15 MSV AIR Analytical Method: TO-15
Acetone 43.6 ug/m3 1.44 01/27/12 20:42 67-64-10.69
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/31/2012 08:49 AM Page 9 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
Sample: SG-5 Lab ID: 92110595005 Collected: 01/19/12 16:58 Received: 01/20/12 09:55 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
TO15 MSV AIR Analytical Method: TO-15
Benzene ND ug/m3 1.44 01/27/12 20:42 71-43-20.47
Bromodichloromethane ND ug/m3 1.44 01/27/12 20:42 75-27-42.0
Bromoform ND ug/m3 1.44 01/27/12 20:42 75-25-23.0
Bromomethane ND ug/m3 1.44 01/27/12 20:42 74-83-91.1
1,3-Butadiene ND ug/m3 1.44 01/27/12 20:42 106-99-00.65
2-Butanone (MEK)0.92 ug/m3 1.44 01/27/12 20:42 78-93-30.86
Carbon disulfide 2.1 ug/m3 1.44 01/27/12 20:42 75-15-00.91
Carbon tetrachloride ND ug/m3 1.44 01/27/12 20:42 56-23-50.92
Chlorobenzene ND ug/m3 1.44 01/27/12 20:42 108-90-71.4
Chloroethane ND ug/m3 1.44 01/27/12 20:42 75-00-30.78
Chloroform ND ug/m3 1.44 01/27/12 20:42 67-66-31.4
Chloromethane ND ug/m3 1.44 01/27/12 20:42 74-87-30.60
Cyclohexane ND ug/m3 1.44 01/27/12 20:42 110-82-70.98
Dibromochloromethane ND ug/m3 1.44 01/27/12 20:42 124-48-12.4
1,2-Dibromoethane (EDB) ND ug/m3 1.44 01/27/12 20:42 106-93-42.3
1,2-Dichlorobenzene ND ug/m3 1.44 01/27/12 20:42 95-50-11.7
1,3-Dichlorobenzene ND ug/m3 1.44 01/27/12 20:42 541-73-11.7
1,4-Dichlorobenzene ND ug/m3 1.44 01/27/12 20:42 106-46-71.7
Dichlorodifluoromethane 2.5 ug/m3 1.44 01/27/12 20:42 75-71-81.4
1,1-Dichloroethane ND ug/m3 1.44 01/27/12 20:42 75-34-31.2
1,2-Dichloroethane ND ug/m3 1.44 01/27/12 20:42 107-06-20.59
1,1-Dichloroethene ND ug/m3 1.44 01/27/12 20:42 75-35-41.2
cis-1,2-Dichloroethene ND ug/m3 1.44 01/27/12 20:42 156-59-21.2
trans-1,2-Dichloroethene ND ug/m3 1.44 01/27/12 20:42 156-60-51.2
1,2-Dichloropropane ND ug/m3 1.44 01/27/12 20:42 78-87-51.4
cis-1,3-Dichloropropene ND ug/m3 1.44 01/27/12 20:42 10061-01-51.3
trans-1,3-Dichloropropene ND ug/m3 1.44 01/27/12 20:42 10061-02-61.3
Dichlorotetrafluoroethane ND ug/m3 1.44 01/27/12 20:42 76-14-22.0
Ethyl acetate ND ug/m3 1.44 01/27/12 20:42 141-78-61.1
Ethylbenzene ND ug/m3 1.44 01/27/12 20:42 100-41-41.3
4-Ethyltoluene ND ug/m3 1.44 01/27/12 20:42 622-96-83.6
n-Heptane ND ug/m3 1.44 01/27/12 20:42 142-82-51.2
Hexachloro-1,3-butadiene ND ug/m3 1.44 01/27/12 20:42 87-68-33.2
n-Hexane ND ug/m3 1.44 01/27/12 20:42 110-54-31.0
2-Hexanone ND ug/m3 1.44 01/27/12 20:42 591-78-61.2
Methylene Chloride 1.4 ug/m3 1.44 01/27/12 20:42 75-09-21.0
4-Methyl-2-pentanone (MIBK) ND ug/m3 1.44 01/27/12 20:42 108-10-11.2
Methyl-tert-butyl ether ND ug/m3 1.44 01/27/12 20:42 1634-04-41.1
Naphthalene ND ug/m3 1.44 01/27/12 20:42 91-20-33.9
Propylene ND ug/m3 1.44 01/27/12 20:42 115-07-10.50
Styrene ND ug/m3 1.44 01/27/12 20:42 100-42-51.3
1,1,2,2-Tetrachloroethane ND ug/m3 1.44 01/27/12 20:42 79-34-51.0
Tetrachloroethene 719 ug/m3 7.2 01/30/12 12:07 127-18-45.0
Tetrahydrofuran ND ug/m3 1.44 01/27/12 20:42 109-99-90.86
THC as Gas 789 ug/m3 1.44 01/27/12 20:4287.6
Toluene 1.5 ug/m3 1.44 01/27/12 20:42 108-88-31.1
1,2,4-Trichlorobenzene ND ug/m3 1.44 01/27/12 20:42 120-82-11.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/31/2012 08:49 AM Page 10 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
Sample: SG-5 Lab ID: 92110595005 Collected: 01/19/12 16:58 Received: 01/20/12 09:55 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
TO15 MSV AIR Analytical Method: TO-15
1,1,1-Trichloroethane ND ug/m3 1.44 01/27/12 20:42 71-55-61.6
1,1,2-Trichloroethane ND ug/m3 1.44 01/27/12 20:42 79-00-50.79
Trichloroethene 1.8 ug/m3 1.44 01/27/12 20:42 79-01-60.79
Trichlorofluoromethane 1.7 ug/m3 1.44 01/27/12 20:42 75-69-41.6
1,1,2-Trichlorotrifluoroethane 10.6 ug/m3 1.44 01/27/12 20:42 76-13-12.3
1,2,4-Trimethylbenzene 1.6 ug/m3 1.44 01/27/12 20:42 95-63-61.4
1,3,5-Trimethylbenzene ND ug/m3 1.44 01/27/12 20:42 108-67-81.4
Vinyl acetate ND ug/m3 1.44 01/27/12 20:42 108-05-41.0
Vinyl chloride ND ug/m3 1.44 01/27/12 20:42 75-01-40.37
m&p-Xylene ND ug/m3 1.44 01/27/12 20:42 179601-23-12.5
o-Xylene ND ug/m3 1.44 01/27/12 20:42 95-47-61.3
Sample: SG-6 Lab ID: 92110595006 Collected: 01/19/12 17:00 Received: 01/20/12 09:55 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Method 3C AIR - Fixed Gases Analytical Method: Method 3C Gases
Helium ND % 1.27 01/25/12 10:53 7440-59-74.6
TO15 MSV AIR Analytical Method: TO-15
Acetone 200 ug/m3 14.4 01/30/12 12:34 67-64-16.9
Benzene ND ug/m3 1.44 01/27/12 21:10 71-43-20.47
Bromodichloromethane ND ug/m3 1.44 01/27/12 21:10 75-27-42.0
Bromoform ND ug/m3 1.44 01/27/12 21:10 75-25-23.0
Bromomethane ND ug/m3 1.44 01/27/12 21:10 74-83-91.1
1,3-Butadiene ND ug/m3 1.44 01/27/12 21:10 106-99-00.65
2-Butanone (MEK)4.6 ug/m3 1.44 01/27/12 21:10 78-93-30.86
Carbon disulfide 12.7 ug/m3 1.44 01/27/12 21:10 75-15-00.91
Carbon tetrachloride 30.5 ug/m3 1.44 01/27/12 21:10 56-23-50.92
Chlorobenzene ND ug/m3 1.44 01/27/12 21:10 108-90-71.4
Chloroethane ND ug/m3 1.44 01/27/12 21:10 75-00-30.78
Chloroform ND ug/m3 1.44 01/27/12 21:10 67-66-31.4
Chloromethane 0.77 ug/m3 1.44 01/27/12 21:10 74-87-30.60
Cyclohexane ND ug/m3 1.44 01/27/12 21:10 110-82-70.98
Dibromochloromethane ND ug/m3 1.44 01/27/12 21:10 124-48-12.4
1,2-Dibromoethane (EDB) ND ug/m3 1.44 01/27/12 21:10 106-93-42.3
1,2-Dichlorobenzene ND ug/m3 1.44 01/27/12 21:10 95-50-11.7
1,3-Dichlorobenzene ND ug/m3 1.44 01/27/12 21:10 541-73-11.7
1,4-Dichlorobenzene ND ug/m3 1.44 01/27/12 21:10 106-46-71.7
Dichlorodifluoromethane 2.8 ug/m3 1.44 01/27/12 21:10 75-71-81.4
1,1-Dichloroethane ND ug/m3 1.44 01/27/12 21:10 75-34-31.2
1,2-Dichloroethane ND ug/m3 1.44 01/27/12 21:10 107-06-20.59
1,1-Dichloroethene ND ug/m3 1.44 01/27/12 21:10 75-35-41.2
cis-1,2-Dichloroethene ND ug/m3 1.44 01/27/12 21:10 156-59-21.2
trans-1,2-Dichloroethene ND ug/m3 1.44 01/27/12 21:10 156-60-51.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/31/2012 08:49 AM Page 11 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
Sample: SG-6 Lab ID: 92110595006 Collected: 01/19/12 17:00 Received: 01/20/12 09:55 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
TO15 MSV AIR Analytical Method: TO-15
1,2-Dichloropropane ND ug/m3 1.44 01/27/12 21:10 78-87-51.4
cis-1,3-Dichloropropene ND ug/m3 1.44 01/27/12 21:10 10061-01-51.3
trans-1,3-Dichloropropene ND ug/m3 1.44 01/27/12 21:10 10061-02-61.3
Dichlorotetrafluoroethane ND ug/m3 1.44 01/27/12 21:10 76-14-22.0
Ethyl acetate ND ug/m3 1.44 01/27/12 21:10 141-78-61.1
Ethylbenzene ND ug/m3 1.44 01/27/12 21:10 100-41-41.3
4-Ethyltoluene ND ug/m3 1.44 01/27/12 21:10 622-96-83.6
n-Heptane ND ug/m3 1.44 01/27/12 21:10 142-82-51.2
Hexachloro-1,3-butadiene ND ug/m3 1.44 01/27/12 21:10 87-68-33.2
n-Hexane 1.9 ug/m3 1.44 01/27/12 21:10 110-54-31.0
2-Hexanone ND ug/m3 1.44 01/27/12 21:10 591-78-61.2
Methylene Chloride 5.3 ug/m3 1.44 01/27/12 21:10 75-09-21.0
4-Methyl-2-pentanone (MIBK)1.6 ug/m3 1.44 01/27/12 21:10 108-10-11.2
Methyl-tert-butyl ether ND ug/m3 1.44 01/27/12 21:10 1634-04-41.1
Naphthalene ND ug/m3 1.44 01/27/12 21:10 91-20-33.9
Propylene ND ug/m3 1.44 01/27/12 21:10 115-07-10.50
Styrene ND ug/m3 1.44 01/27/12 21:10 100-42-51.3
1,1,2,2-Tetrachloroethane ND ug/m3 1.44 01/27/12 21:10 79-34-51.0
Tetrachloroethene 1690 ug/m3 14.4 01/30/12 12:34 127-18-49.9
Tetrahydrofuran ND ug/m3 1.44 01/27/12 21:10 109-99-90.86
THC as Gas 1890 ug/m3 1.44 01/27/12 21:1087.6
Toluene 6.5 ug/m3 1.44 01/27/12 21:10 108-88-31.1
1,2,4-Trichlorobenzene ND ug/m3 1.44 01/27/12 21:10 120-82-11.4
1,1,1-Trichloroethane 44.4 ug/m3 1.44 01/27/12 21:10 71-55-61.6
1,1,2-Trichloroethane ND ug/m3 1.44 01/27/12 21:10 79-00-50.79
Trichloroethene ND ug/m3 1.44 01/27/12 21:10 79-01-60.79
Trichlorofluoromethane 1.6 ug/m3 1.44 01/27/12 21:10 75-69-41.6
1,1,2-Trichlorotrifluoroethane ND ug/m3 1.44 01/27/12 21:10 76-13-12.3
1,2,4-Trimethylbenzene 1.9 ug/m3 1.44 01/27/12 21:10 95-63-61.4
1,3,5-Trimethylbenzene ND ug/m3 1.44 01/27/12 21:10 108-67-81.4
Vinyl acetate ND ug/m3 1.44 01/27/12 21:10 108-05-41.0
Vinyl chloride ND ug/m3 1.44 01/27/12 21:10 75-01-40.37
m&p-Xylene ND ug/m3 1.44 01/27/12 21:10 179601-23-12.5
o-Xylene ND ug/m3 1.44 01/27/12 21:10 95-47-61.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/31/2012 08:49 AM Page 12 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/14108
Method 3C Gases
Method 3C Gases
METHOD 3C AIR - FIXED GASES
Associated Lab Samples: 92110595001, 92110595002, 92110595003, 92110595004, 92110595005, 92110595006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1130763
Associated Lab Samples:92110595001, 92110595002, 92110595003, 92110595004, 92110595005, 92110595006
Matrix: Air
Analyzed
Helium % ND 3.6 01/25/12 09:37
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1130764LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1130765
Helium % 14.618 81 70-1308615.4 6 30
Parameter Units
Dup
Result QualifiersRPDResult
92110595001
1130766SAMPLE DUPLICATE:
Helium % NDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/31/2012 08:49 AM Page 13 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/14137
TO-15
TO-15
TO15 MSV AIR Low Level
Associated Lab Samples: 92110595001, 92110595002, 92110595003, 92110595004, 92110595005, 92110595006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1132793
Associated Lab Samples:92110595001, 92110595002, 92110595003, 92110595004, 92110595005, 92110595006
Matrix: Air
Analyzed
1,1,1-Trichloroethane ug/m3 ND 1.1 01/27/12 09:34
1,1,2,2-Tetrachloroethane ug/m3 ND 0.70 01/27/12 09:34
1,1,2-Trichloroethane ug/m3 ND 0.55 01/27/12 09:34
1,1,2-Trichlorotrifluoroethane ug/m3 ND 1.6 01/27/12 09:34
1,1-Dichloroethane ug/m3 ND 0.82 01/27/12 09:34
1,1-Dichloroethene ug/m3 ND 0.81 01/27/12 09:34
1,2,4-Trichlorobenzene ug/m3 ND 0.99 01/27/12 09:34
1,2,4-Trimethylbenzene ug/m3 ND 1.0 01/27/12 09:34
1,2-Dibromoethane (EDB) ug/m3 ND 1.6 01/27/12 09:34
1,2-Dichlorobenzene ug/m3 ND 1.2 01/27/12 09:34
1,2-Dichloroethane ug/m3 ND 0.41 01/27/12 09:34
1,2-Dichloropropane ug/m3 ND 0.94 01/27/12 09:34
1,3,5-Trimethylbenzene ug/m3 ND 1.0 01/27/12 09:34
1,3-Butadiene ug/m3 ND 0.45 01/27/12 09:34
1,3-Dichlorobenzene ug/m3 ND 1.2 01/27/12 09:34
1,4-Dichlorobenzene ug/m3 ND 1.2 01/27/12 09:34
2-Butanone (MEK) ug/m3 ND 0.60 01/27/12 09:34
2-Hexanone ug/m3 ND 0.83 01/27/12 09:34
4-Ethyltoluene ug/m3 ND 2.5 01/27/12 09:34
4-Methyl-2-pentanone (MIBK) ug/m3 ND 0.83 01/27/12 09:34
Acetone ug/m3 ND 0.48 01/27/12 09:34
Benzene ug/m3 ND 0.32 01/27/12 09:34
Bromodichloromethane ug/m3 ND 1.4 01/27/12 09:34
Bromoform ug/m3 ND 2.1 01/27/12 09:34
Bromomethane ug/m3 ND 0.79 01/27/12 09:34
Carbon disulfide ug/m3 ND 0.63 01/27/12 09:34
Carbon tetrachloride ug/m3 ND 0.64 01/27/12 09:34
Chlorobenzene ug/m3 ND 0.94 01/27/12 09:34
Chloroethane ug/m3 ND 0.54 01/27/12 09:34
Chloroform ug/m3 ND 0.99 01/27/12 09:34
Chloromethane ug/m3 ND 0.42 01/27/12 09:34
cis-1,2-Dichloroethene ug/m3 ND 0.81 01/27/12 09:34
cis-1,3-Dichloropropene ug/m3 ND 0.92 01/27/12 09:34
Cyclohexane ug/m3 ND 0.68 01/27/12 09:34
Dibromochloromethane ug/m3 ND 1.7 01/27/12 09:34
Dichlorodifluoromethane ug/m3 ND 1.0 01/27/12 09:34
Dichlorotetrafluoroethane ug/m3 ND 1.4 01/27/12 09:34
Ethyl acetate ug/m3 ND 0.73 01/27/12 09:34
Ethylbenzene ug/m3 ND 0.88 01/27/12 09:34
Hexachloro-1,3-butadiene ug/m3 ND 2.2 01/27/12 09:34
m&p-Xylene ug/m3 ND 1.8 01/27/12 09:34
Methyl-tert-butyl ether ug/m3 ND 0.73 01/27/12 09:34
Methylene Chloride ug/m3 ND 0.71 01/27/12 09:34
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/31/2012 08:49 AM Page 14 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1132793
Associated Lab Samples:92110595001, 92110595002, 92110595003, 92110595004, 92110595005, 92110595006
Matrix: Air
Analyzed
n-Heptane ug/m3 ND 0.83 01/27/12 09:34
n-Hexane ug/m3 ND 0.72 01/27/12 09:34
Naphthalene ug/m3 ND 2.7 01/27/12 09:34
o-Xylene ug/m3 ND 0.88 01/27/12 09:34
Propylene ug/m3 ND 0.35 01/27/12 09:34
Styrene ug/m3 ND 0.87 01/27/12 09:34
Tetrachloroethene ug/m3 ND 0.69 01/27/12 09:34
Tetrahydrofuran ug/m3 ND 0.60 01/27/12 09:34
THC as Gas ug/m3 ND 60.8 01/27/12 09:34
Toluene ug/m3 ND 0.77 01/27/12 09:34
trans-1,2-Dichloroethene ug/m3 ND 0.81 01/27/12 09:34
trans-1,3-Dichloropropene ug/m3 ND 0.92 01/27/12 09:34
Trichloroethene ug/m3 ND 0.55 01/27/12 09:34
Trichlorofluoromethane ug/m3 ND 1.1 01/27/12 09:34
Vinyl acetate ug/m3 ND 0.71 01/27/12 09:34
Vinyl chloride ug/m3 ND 0.26 01/27/12 09:34
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1132794LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1-Trichloroethane ug/m3 59.655.5 107 72-129
1,1,2,2-Tetrachloroethane ug/m3 67.269.8 96 73-131
1,1,2-Trichloroethane ug/m3 60.455.5 109 71-128
1,1,2-Trichlorotrifluoroethane ug/m3 89.377.9 115 65-132
1,1-Dichloroethane ug/m3 43.841.2 106 67-132
1,1-Dichloroethene ug/m3 40.840.3 101 68-134
1,2,4-Trichlorobenzene ug/m3 200 CH,L375.5 266 48-150
1,2,4-Trimethylbenzene ug/m3 54.250 108 72-127
1,2-Dibromoethane (EDB) ug/m3 82.178.1 105 75-130
1,2-Dichlorobenzene ug/m3 85.7 CH,L361.2 140 71-132
1,2-Dichloroethane ug/m3 42.241.2 103 70-131
1,2-Dichloropropane ug/m3 46.847 100 73-130
1,3,5-Trimethylbenzene ug/m3 53.850 108 70-133
1,3-Butadiene ug/m3 24.022.5 107 69-132
1,3-Dichlorobenzene ug/m3 70.461.2 115 71-128
1,4-Dichlorobenzene ug/m3 62.561.2 102 72-131
2-Butanone (MEK) ug/m3 37.330 124 69-131
2-Hexanone ug/m3 46.241.7 111 71-134
4-Ethyltoluene ug/m3 54.350 109 71-129
4-Methyl-2-pentanone (MIBK) ug/m3 45.641.7 109 69-135
Acetone ug/m3 29.324.2 121 61-139
Benzene ug/m3 36.232.5 112 69-134
Bromodichloromethane ug/m3 67.368.2 99 71-130
Bromoform ug/m3 128105 121 70-130
Bromomethane ug/m3 40.739.5 103 69-125
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/31/2012 08:49 AM Page 15 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1132794LABORATORY CONTROL SAMPLE:
LCSSpike
Carbon disulfide ug/m3 34.231.7 108 66-131
Carbon tetrachloride ug/m3 73.764 115 68-128
Chlorobenzene ug/m3 44.546.8 95 75-128
Chloroethane ug/m3 26.926.8 100 66-131
Chloroform ug/m3 50.949.7 102 68-132
Chloromethane ug/m3 20.621 98 60-139
cis-1,2-Dichloroethene ug/m3 48.040.3 119 73-130
cis-1,3-Dichloropropene ug/m3 58.746.2 127 74-134
Cyclohexane ug/m3 43.635 125 67-136
Dibromochloromethane ug/m3 92.586.6 107 69-131
Dichlorodifluoromethane ug/m3 49.950.3 99 67-131
Dichlorotetrafluoroethane ug/m3 78.471.1 110 66-130
Ethyl acetate ug/m3 42.236.6 115 71-131
Ethylbenzene ug/m3 48.244.2 109 69-139
Hexachloro-1,3-butadiene ug/m3 336 CH,L3108 310 41-150
m&p-Xylene ug/m3 96.988.3 110 66-137
Methyl-tert-butyl ether ug/m3 41.636.7 113 70-132
Methylene Chloride ug/m3 34.535.3 98 73-134
n-Heptane ug/m3 47.841.7 115 70-134
n-Hexane ug/m3 39.335.8 110 65-133
Naphthalene ug/m3 154 CH,L353.3 289 57-150
o-Xylene ug/m3 56.344.2 127 69-138
Propylene ug/m3 18.817.5 108 70-134
Styrene ug/m3 47.143.3 109 72-132
Tetrachloroethene ug/m3 69.869 101 70-130
Tetrahydrofuran ug/m3 28.8 SS30 96 74-128
THC as Gas ug/m3 31203030 103 66-131
Toluene ug/m3 41.538.3 108 71-132
trans-1,2-Dichloroethene ug/m3 41.440.3 103 72-128
trans-1,3-Dichloropropene ug/m3 54.346.2 118 73-130
Trichloroethene ug/m3 56.154.6 103 72-131
Trichlorofluoromethane ug/m3 59.057.1 103 66-129
Vinyl acetate ug/m3 43.235.8 121 71-131
Vinyl chloride ug/m3 25.426 98 70-131
Parameter Units
Dup
Result QualifiersRPDResult
92110376006
1133433SAMPLE DUPLICATE:
1,1,1-Trichloroethane ug/m3 NDND
1,1,2,2-Tetrachloroethane ug/m3 NDND
1,1,2-Trichloroethane ug/m3 NDND
1,1,2-Trichlorotrifluoroethane ug/m3 NDND
1,1-Dichloroethane ug/m3 NDND
1,1-Dichloroethene ug/m3 NDND
1,2,4-Trichlorobenzene ug/m3 NDND
1,2,4-Trimethylbenzene ug/m3 NDND
1,2-Dibromoethane (EDB) ug/m3 NDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/31/2012 08:49 AM Page 16 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
Parameter Units
Dup
Result QualifiersRPDResult
92110376006
1133433SAMPLE DUPLICATE:
1,2-Dichlorobenzene ug/m3 NDND
1,2-Dichloroethane ug/m3 NDND
1,2-Dichloropropane ug/m3 NDND
1,3,5-Trimethylbenzene ug/m3 NDND
1,3-Butadiene ug/m3 NDND
1,3-Dichlorobenzene ug/m3 NDND
1,4-Dichlorobenzene ug/m3 NDND
2-Butanone (MEK) ug/m3 9.0 28.8
2-Hexanone ug/m3 NDND
4-Ethyltoluene ug/m3 NDND
4-Methyl-2-pentanone (MIBK) ug/m3 NDND
Acetone ug/m3 20.7 .320.6
Benzene ug/m3 1.4 .41.4
Bromodichloromethane ug/m3 NDND
Bromoform ug/m3 NDND
Bromomethane ug/m3 NDND
Carbon disulfide ug/m3 1.7 41.8
Carbon tetrachloride ug/m3 NDND
Chlorobenzene ug/m3 NDND
Chloroethane ug/m3 NDND
Chloroform ug/m3 NDND
Chloromethane ug/m3 NDND
cis-1,2-Dichloroethene ug/m3 NDND
cis-1,3-Dichloropropene ug/m3 NDND
Cyclohexane ug/m3 45.9 347.6
Dibromochloromethane ug/m3 NDND
Dichlorodifluoromethane ug/m3 2.8 22.9
Dichlorotetrafluoroethane ug/m3 NDND
Ethyl acetate ug/m3 18.3 .318.3
Ethylbenzene ug/m3 .96JND
Hexachloro-1,3-butadiene ug/m3 NDND
m&p-Xylene ug/m3 NDND
Methyl-tert-butyl ether ug/m3 NDND
Methylene Chloride ug/m3 38.8 239.6
n-Heptane ug/m3 17.0 .717.1
n-Hexane ug/m3 11.3 411.8
Naphthalene ug/m3 NDND
o-Xylene ug/m3 NDND
Propylene ug/m3 NDND
Styrene ug/m3 NDND
Tetrachloroethene ug/m3 NDND
Tetrahydrofuran ug/m3 NDND
THC as Gas ug/m3 1010 21030
Toluene ug/m3 122 1123
trans-1,2-Dichloroethene ug/m3 NDND
trans-1,3-Dichloropropene ug/m3 NDND
Trichloroethene ug/m3 3.0 53.2
Trichlorofluoromethane ug/m3 7.7 .57.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/31/2012 08:49 AM Page 17 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
Parameter Units
Dup
Result QualifiersRPDResult
92110376006
1133433SAMPLE DUPLICATE:
Vinyl acetate ug/m3 NDND
Vinyl chloride ug/m3 NDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/31/2012 08:49 AM Page 18 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALIFIERS
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution ofthe sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
LABORATORIES
Pace Analytical Services - MinneapolisPASI-M
ANALYTE QUALIFIERS
The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biasedhigh.CH
Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits inassociated samples. Results unaffected by high bias.L3
This analyte did not meet the secondary source verification criteria for the initial calibration. The reported result should beconsidered an estimated value.SS
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/31/2012 08:49 AM Page 19 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92110595
PLIANA 6228-09-5055
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92110595001 AIR/14108SG-1 Method 3C Gases
92110595002 AIR/14108SG-2 Method 3C Gases
92110595003 AIR/14108SG-3 Method 3C Gases
92110595004 AIR/14108SG-4 Method 3C Gases
92110595005 AIR/14108SG-5 Method 3C Gases
92110595006 AIR/14108SG-6 Method 3C Gases
92110595001 AIR/14137SG-1 TO-15
92110595002 AIR/14137SG-2 TO-15
92110595003 AIR/14137SG-3 TO-15
92110595004 AIR/14137SG-4 TO-15
92110595005 AIR/14137SG-5 TO-15
92110595006 AIR/14137SG-6 TO-15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/31/2012 08:49 AM Page 20 of 20
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Former Pliana Facility – Report of Environmental Assessment March 16, 2012 1016 and 1024 Montana Drive, Charlotte, North Carolina AMEC Project 6228-09-5055

APPENDIX E RECEPTOR SURVEY REGISTERED-MAIL RECEIPTS AND RETURNED SURVEY
FORMS