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HomeMy WebLinkAboutCamden Grandview_GW_Monitoring_ReportGroundwater Monitoring Report American Dry Cleaning Company DSCA ID: 60-0002 Charlotte, Mecklenburg County North Carolina Dry-Cleaning Solvent Cleanup Act Program H&H Project No. DS0-35C June 2, 2011 2923 South Tryon Street Suite 100 Charlotte, NC 28203 704-586-0007 3334 Hillsborough Street Raleigh, NC 27607 919-847-4241 #C-1269 Engineering #C-245 Geology DSCA ID No.: Submittal Date: Reporting Period:to Type of Report:One-Time Event Quaterly Semi-Annual Annual June 2, 2011 60-0002 May-10 Mar-11 Groundwater Monitoring Report Forms for North Carolina Dry-Cleaning Solvent Cleanup Act Program Prepared By: Facility Name:American Dry Cleaning Company 309 East Morehead Street, Charlotte, Mecklenburg County 2923 South Tryon Street, Suite 100, Charlotte, North Carolina 28203 Hart & Hickman, PC Table of Contents DSCA ID No.: 60-0002 Form/Att . No. Check box if included Form 1 Report Summary Form 2 Quality Assurance/Quality Control Procedures Form 3 Results, Conclusions and Recommendations Att. 1 Att. 2 Att. 3 Att. 4 Att. 5 Att. 6 Att. 7 Att. 8 Att. 9 GWMR TOC Description Grooundwater Monitoring Report Attachments Groundwater Monitoring Report Forms Site Location Map Laboratory Analytical Reports Plume Stability Graph Groundwater PCE Isoconcentration Map Groundwater PCE Concentration Map Site Map Boring Log and Well Construction Record (TDMW-1) Disposal of IDW receipts from receiving facilities, or any required harzardous Groundwater Gradient Map Report Summary DSCA ID No.: 60-0002 Dates samples were collected: Number of existing monitoring wells: List the sampled monitoring wells: List the sampled water supply wells: List surface water samples collected: Date analyses were performed: Were any holding times exceeded? Dates monitoring/supply wells were gauged: disposal? Average depth to groundwater: Groundwater flow direction: Was the static groundwater level above the top of the well screen in any wells? If Yes, indicate which wells: Is the aquifer: Were any existing monitoring wells damaged? If Yes, indicate which wells: Has the groundwater plume been defined? Any ongoing assessment activities? If Yes, provide details in the space below: Any ongoing remediation activites? If Yes, provide details in the space below: Any significant changes in the subsurface conditions? If Yes, provide details in the space below: Previously, water levels were measured for TW-1 through TW-6 on 11/19/2008. No groundwater elevations were obtained. East/Northeast TDMW-1 No supply wells sampled No surface water samples collected during this period 25.53 (Based on 11/19/2008 data) 5/27/10, 8/26/10, 11/22/10, 3/14/11 and 3/16/11 None Temporary wells TW-14, TW-15, TW-16, TW-17, and TDMW-1 6/4/10, 9/4/10, 12/3/10, 3/17/11 and 3/19/11 Does investigation derived waste (IDW) generated during these activities still remain at the site pending GWMR Form 1 Yes No Yes No Confined Unconfined Perched Yes No Yes No Yes No Yes No Yes No Yes No Quality Assurance/Quality Control Procedures DSCA ID No.: 60-0002 Describe the specific sampling technicque employed during the collection of all ground water samples. Groundwater samples were analyzed for volatile organic compounds (VOCs) by EPA Method 8260B. The maximum holding time for VOC analysis is 14 days from the sample collection date (when the sample is preserved with HCL). All samples were preserved with HCL and were analyzed within 14 days of collection. There were no discrepancies noted on the laboratory analytical reports for the sample analyses performed during this period. GWMR Form 2 Describe the standard quality assurance/quality control (QA/QC) procedures which are practiced in order to ensure that the samples are representative of actual conditions and that analytical results are valid. Describe the EPA approved methods used to extract and analyze the samples submitted the laboratory. Reference the maximum holding time for each type of analysis performed. New sample tubing (both polyethylene and silicone) was used at each temporary well. New sterile nitrile gloves were used for sampling of each well. Samples were collected directly into laboratory-prepared sample containers, labeled with the site and sample identifications, time, date, sampler's initials, and analysis method. Samples were secured in protective wrap or bags before being covered with ice and cooled to 4 degrees Celcius in a laboratory-supplied sample cooler. A sample chain-of-custody was completed and placed in the sample cooler. The cooler was delivered by field personnel or picked up by a courier for delivery to a NC certified laboratory. The laboratory ran standard Type II QC measures on each set of samples. Installation of temporary monitoring wells (TW-14, TW-15, TW-16, and TW-17) was completed using a 4- foot, stainless steel, screen-point sampler using a direct-push technology (DPT) rig. A check-valve attached to dedicated polyethylene tubing was used to draw groundwater from the screened-interval into the tubing. Samples were collected from the outflow of the polyethylene tubing. Standard USEPA-approved low stress (low-flow) purge techniques were used to sample the deep temporary monitoring well (TDMW-1). Polyethylene tubing was installed to the middle of the well screen, secured at the top of the well, and connected to a short piece of silicone tubing at the peristaltic pump rotor. Groundwater was drawn through the tubing by the peristaltic pump at a rate that prevented drawdown of the water column in the well (approximately 100 mL/min). Field measurements of temperature, pH, conductivity, and oxidation- reduction potential (ORP) were collected during the low-flow purging and the final readings are included in Table 9. Readings of each parameter were collected at 3 to 5 minute intervals. After field readings stabilized, samples were collected from the outflow tubing of the peristaltic pump. Results, Conclusions and Recommendations DSCA ID No.: Sampling Date Sample ID Concentration [mg/L] Sampling Date Sample ID Concentration [mg/L] 3/16/2011 TDMW-1 0.0053 11/17/2008 TW-2 0.014 NA NA ND NA NA ND NA NA ND NA NA ND 3/16/2011 TDMW-1 0.01 11/17/2008 TW-2 0.012 3/16/2011 TDMW-1 0.00064J 11/17/2008 TW-3 0.0013 NA NA ND 11/18/2008 TW-5 0.00081J NA NA ND 11/18/2008 TW-5 0.0035 NA NA ND 11/22/2010 TW-15 0.068 NA NA ND 11/22/2010 TW-15 0.0028J H&H completed quarterly groundwater monitoring events for the American Dry Cleaning Company site to evaluate PCE concentration trends at the site. Based on the analytical data, PCE concentrations in groundwater appear to be stable. H&H recommends completing a Tier 1 risk assessment and evaluating closure options for the site. Chloroform Methyl tert-butyl ether Benzene Toluene Acetone Methyl Ethyl Ketone Instructions: Discuss any trends or changes noted in analytical results. Conclusions Recommendations Hart & Hickman, PC (H&H) completed quarterly groundwater sampling events for temporary monitoring wells TW-14, TW-15, TW-16, TW-17, and TDMW-1 (March 2011 sampling event) to evaluate groundwater plume stability at the site. TW-14 was dry at refusal depth during the May 2010, November 2010, and March 2011 events. During these events, only PCE has been detected in groundwater above NCAC 2L Standards. PCE was detected in TW-15 and TW- 16 at concentrations above the 2L Standard. A graph depicting the concentration versus time for these two monitoring wells is provided as Attachment 7. In general, PCE concentrations appear to be stable at the site. PCE was not detected above the laboratory reporting limit in TW-14 or TW-17. A concentration of PCE was detected in Type III temporary well TDMW-1 above the 2L Standard during the March 2011 sampling event. The PCE concentration in TDMW-1 was similar in magnitude to the PCE concentrations detected in nearby shallow wells TW-15 and TW-16. GWMR Form 3 Results Maximum Concentration Detected in Groundwater Chemical Most Recent Event Detected at Site To-date Tetrachloroethylene Trichloroethylene Vinyl Chloride ATTACHMENT 1 IDW DOCUMENTS ATTACHMENT 2 SITE LOCATION MAP TITLE PROJECT REVISION NO. 0 ATTACHMENT NO.2 DATE: 5-20-11 SITE SITE LOCATION MAP U.S.G.S. QUADRANGLE MAP QUADRANGLE7.5 MINUTE SERIES (TOPOGRAPHIC) CHARLOTTE EAST, NC 1971 REVISED/ INSPECTED 1988 JOB NO. DS0-35 AMERICAN DRY CLEANING COMPANY DSCA SITE NO. 60-0002 309 EAST MOREHEAD STREET CHARLOTTE, MECKLENBURG COUNTY N 0 2000 4000 APPROXIMATE SCALE IN FEET ATTACHMENT 3 SITE MAP ATTACHMENT 4 GROUNDWATER GRADIENT MAP ATTACHMENT 5 GROUNDWATER PCE CONCENTRATION MAP ATTACHMENT 6 GROUNDWATER PCE ISOCONCENTRATION MAP ATTACHMENT 7 PLUME STABILITY GRAPH 0 0.001 0.002 0.003 0.004 0.005 0.006 May-10 Jun-10 Aug-10 Sep-10 Nov-10 Jan-11 Feb-11 Apr-11 PC E C o n c e n t r a t i o n ( m g / L ) Date PCE Concentration vs. Time Graph Temporary Monitoring Wells TW-15 and TW-16 American Dry Cleaning Company, Charlotte, Mecklenburg CountyDSCA ID: 60-0002 TW-15 TW-16 Note: Non-detect values are graphed as half the laboratory method detection limit. ATTACHMENT 8 LABORATORY ANALYTICAL REPORTS Page 1 of 12 Page 2 of 12 Page 3 of 12 Page 4 of 12 Page 5 of 12 Page 6 of 12 Page 7 of 12 Page 8 of 12 Page 9 of 12 Page 10 of 12 Page 11 of 12 Page 12 of 12 Page 1 of 15 Page 2 of 15 Page 3 of 15 Page 4 of 15 Page 5 of 15 Page 6 of 15 Page 7 of 15 Page 8 of 15 Page 9 of 15 Page 10 of 15 Page 11 of 15 Page 12 of 15 Page 13 of 15 Page 14 of 15 Page 15 of 15 Page 1 of 12 Page 2 of 12 Page 3 of 12 Page 4 of 12 Page 5 of 12 Page 6 of 12 Page 7 of 12 Page 8 of 12 Page 9 of 12 Page 10 of 12 Page 11 of 12 Page 12 of 12 Page 1 of 14 Page 2 of 14 Page 3 of 14 Page 4 of 14 Page 5 of 14 Page 6 of 14 Page 7 of 14 Page 8 of 14 Page 9 of 14 Page 10 of 14 Page 11 of 14 Page 12 of 14 Page 13 of 14 Page 14 of 14 Page 1 of 8 Page 2 of 8 Page 3 of 8 Page 4 of 8 Page 5 of 8 Page 6 of 8 Page 7 of 8 Page 8 of 8 ATTACHMENT 9 BORING LOG AND WELL CONSTRUCTION RECORD (TDMW-1) Analytical Data Tables for North Carolina Dry-Cleaning Solvent Cleanup Act Program DSCA ID No.: Submittal Date: Prepared By: Facility Name:American Dry Cleaning Company 309 E. Morehead Street, Charlotte, Mecklenburg County 2923 S. Tryon Street, Suite 100, Charlotte, NC 28203 Hart & Hickman, PC June 2, 2011 60-0002 Table of Contents DSCA ID No.: 60-0002 Table/ Att. No. Check box if included Table 1 Site Chronology Table 2 Analytical Data for Soil Table 3 Monitoring Well Construction Data Table 4 Groundwater Elevation Data Table 5 Analytical Data for Groundwater Table 6 Analytical Data for Surface Water Table 7 Water Well(s) Survey Data Table 8 Analytical Data for Water Supply Well(s) Table 9 Analytical Data for Natural Attenuation Parameters Att. 1 Site map showing location(s) of soil boring(s). Att. 2 Att. 3 Soil isoconcentration maps. Att. 4 Site map showing location(s) of monitoring well(s). Att. 5 Att. 6 Groundwater gradient map for each sampling event. Att. 7 PCE concentration map showing the concentration at each sampling point and isoconcentration map. However, if there are significant plumes for other dry- cleaning contaminants contaminant concentration maps for each chemical of ADT TOC Description Attachments Tables Soil contaminant concentration maps showing the concentration at each sampling point. Well completion diagrams and records of construction submitted to state. Att. 8 Att. 9 Map showing location(s) of surface water sample(s) (if applicable). Att. 10 Att. 11 Att. 12 Att. 13 Att. 14 Att. 15 Att. 16 Att. 17 Att. 18 Att. 19 Att. 20 Note: 1. All maps must include a bar scale, north arrow, site name, DSCA ID No., and date. USGS Quad map with plotted water well location(s) within the 1,500 foot and 0.5 mile radii of the site (if applicable). Signed laboratory analytical reports including chain-of custody and quality assurance/quality control (QA/QC) documentation (only if not previously submitted). Site map showing location(s) of monitoring well(s) for natural attenuation parameter cleaning contaminants,contaminant concentration maps for each chemical of concern should be included. Surface water concentratin map showing the concentration at each sampling point (if applicable). Groundwater concentration trend plots. Table 1: Site Chronology DSCA ID No.: 60-0002 Chronology of Events September 1997 LAW Engineering and Environmental Services, Inc. (LAW) submitted report documenting Phase I ESA activities. July 1998 LAW submitted Report of Geotechnical Investigation documenting investigation activities during which odors indicative of contamination were observed during soil sampling. October 1998 LAW submitted Notification of Contamination Discovery, Assessment and Proposed Remedial Action Planreport documenting additional investigation activities conducted based on the odors observed during the geotechnical investigation. PCE (1.15 mg/kg) was detected in a soil sample and PCE (0.127 mg/L) was detected in a groundwater sample collected during the activities. Approximately 350 cubic yards of contaminated soils were excavated from the site during these activities. July 2009 LAW submitted Report of Soil Remediation Activities documenting additional soil excavation activities and removal of three USTs. Approximately 1,500 cubic yards of contaminated soils were excavated and removed from the site during these activities. Analysis of the UST contents indicated unidentified hydrocarbons. The report indicated that there were plans for extensive excavation to 28 feet below grade for construction of the sub-grade parking garage which currently exists at the property (2008). September 2008 Site certified into the NCDENR-DSCA Program. January 2009 Hart & Hickman, PC (H&H) submitted Prioritization Assessment Report (PAR) to DSCA. The PAR documents groundwater assessment activities and a receptor survey conducted by H&H during November 2008. The site was assigned a priority ranking of 3.2. As part of the assessment activities, six temporary wells (TW-1 through TW-6) were installed and sampled. The well TOCs were surveyed and groundwater elevations were calculated for each TW location. H&H submitted an Updated Assessment Report to DSCA documenting groundwater assessment activities conducted by H&H during Instructions: Brief description of all significant events that have occurred since a problem was suspected at the facility. Commence with the first date a problem was suspected and continue through the most recent activity described in the current report. Date ADT 1 August 2009 & sub tted a Updated ssess e t epo t to SC docu e t g g ou dwate assess e t act v t es co ducted by & du g May 2009. As part of the assessment activities, seven temporary wells (TW-7 through TW-13) were installed; however, only TW-11 was sampled. The other wells were dry at refusal depth. November 2009 - December 2009 H&H conducted additional assessment activites at the site including the collection of one sub-slab vapor monitoring point (VMP-1) and two ambient air samples (IAS-1 and BAS-1). On May 12, 2010, H&H submited an Ambient Air and Sub-Slab Vapor Sampling Results letter to the DSCA Program documenting the assessment activities. May 2010 - March 2011 H&H completed quarterly groundwater sampling activities in May 2010, August 2010, November 2010, and March 2011. Due to difficulties in obtaining off-site access for the installation of permanent monitoring wells, four temporary direct push technology (DPT) monitoring wells (TW-14 through TW-17) were installed and sampled during each quarterly monitoring event. TW-14 was dry at refusal depth during each sampling event except for August 2010. In March 2011, one Type III temporary monitoring well (TDMW- 1) was installed and sampled to delineate the vertical extent of groundwater impacts at the site. On June 2, 2011, H&H submitted a Groundwater Monitoring Report to the DSCA Program documenting the May 2010 to March 2011 groundwater sampling events. ADT 1 Ta b l e 3 : M o n i t o r i n g W e l l C o n s t r u c t i o n D a t a DS C A I D N o . : 6 0 - 0 0 0 2 We l l I D Da t e I n s t a l l e d Nu m b e r o f S a m p l e s We l l D e p t h W e l l D i a m e t e r S c r e e n I n t e r v a l S t a t u s TW - 1 A 06 / 1 1 / 9 8 1 >4 5 Un k n o w n Un k n o w n Inactive TW - 1 11 / 1 7 / 0 8 1 15 1 10 - 1 5 Inactive TW - 2 11 / 1 7 / 0 8 1 30 2 15 - 3 0 Inactive TW - 3 11 / 1 7 / 0 8 1 31 2 21 - 3 1 Inactive TW - 4 11 / 1 7 / 0 8 1 40 2 30 - 4 0 Inactive TW - 5 11 / 1 8 / 0 8 1 20 2 10 - 2 0 Inactive TW - 6 11 / 1 9 / 0 8 1 48 2 38 - 4 8 Inactive TW - 1 1 05 / 2 2 / 0 9 11 81 8 -1 8I n a c t i v e TW - 1 4 08 / 2 6 / 1 0 1 28 1 24 - 2 8 Inactive 05 / 2 7 / 1 0 1 35 1 31 - 3 5 Inactive 08 / 2 6 / 1 0 1 35 1 31 - 3 5 Inactive 11 / 2 2 / 1 0 1 35 1 31 - 3 5 Inactive 03 / 1 4 / 1 1 1 30 1 26 - 3 0 Inactive 05 / 2 7 / 1 0 1 22 1 18 - 2 2 Inactive 08 / 2 6 / 1 0 1 22 1 18 - 2 2 Inactive 11 / 2 2 / 1 0 1 22 1 18 - 2 2 Inactive 03 / 1 4 / 1 1 1 22 1 18 - 2 2 Inactive 05 / 2 7 / 1 0 1 17 1 13 - 1 7 Inactive TW - 1 5 TW - 1 6 ADT 3 08 / 2 6 / 1 0 1 20 1 16 - 2 0 Inactive 11 / 2 2 / 1 0 1 17 1 13 - 1 7 Inactive 03 / 1 4 / 1 1 1 19 1 15 - 1 9 Inactive TD M W - 1 03 / 1 6 / 1 1 1 64 2 59 - 6 4 Inactive TW - 1 7 No t e s : 1. T W - 1 A i n s t a l l e d b y L A W E n g i n e e r i n g . I n s t a l l a t i o n d a t e b a s e d o n s a m p l e d a t e o b t a i n e d f r o m a n a l y t i c a l d a t a r e p o r t . 2. T D M W - 1 w a s i n s t a l l e d a s a t e m p o r a r y T y p e I I I m o n i t o r i n g w e l l w i t h a 6 - i n c h s u r f a c e c a s i n g s e t a t 5 7 f t b g s . T h e w e l l w a s a b a n d o n e d a f t e r s a m p l e c o l l e c t i o n . ADT 3 Ta b l e 4 : G r o u n d w a t e r E l e v a t i o n D a t a DS C A I D N o . : 6 0 - 0 0 0 2 Gr o u n d w a t e r Sa m p l i n g P o i n t Sa m p l i n g D a t e (m m / d d / y y ) TO C E l e v a t i o n [f e e t ] De p t h t o W a t e r [f e e t b g s ] Gr o u n d w a t e r El e v a t i o n [f e e t ] De p t h t o N A P L [f e e t b g s ] NA P L T h i c k n e s s [f e e t ] Corrected* Groundwater Elevation [feet] TW - 1 11 / 1 9 / 0 8 82 . 2 1 15 . 8 3 66 . 3 8 TW - 2 11 / 1 9 / 0 8 89 . 9 4 19 . 5 0 70 . 4 4 TW - 3 11 / 1 9 / 0 8 10 0 . 0 0 28 . 9 5 71 . 0 5 TW - 4 11 / 1 9 / 0 8 10 9 . 5 0 42 . 1 0 67 . 4 0 TW - 5 11 / 1 9 / 0 8 79 . 1 8 12 . 6 8 66 . 5 0 TW - 6 11 / 1 9 / 0 8 11 0 . 5 9 34 . 1 3 76 . 4 6 No t e s : 1. T O C E l e v a t i o n s m e a s u r e d r e l a t i v e t o a s s u m e d s i t e d a t u m o f 1 0 0 ' a t T W - 3 T O C . 2. T O C e l e v a t i o n s w e r e n o t o b t a i n e d f o r o t h e r t e m p o r a r y m o n i t o r i n g w e l l s i n s t a l l e d a t t h e s i t e . ADT 4 Ta b l e 5 : A n a l y t i c a l D a t a f o r G r o u n d w a t e r DS C A I D N o . : 6 0 - 0 0 0 2 1 , 1 , 1 - T r i c h l o r o e t h a n e 1 , 1 , 2 , 2 - T e t r a c h l o r o e t h a n e 1 , 1 , 2 - T r i c h l o r o e t h a n a e 1 , 1 - D i c h l o r o e t h a n e 1 , 1 - D i c h l o r o e t h y l e n e 1 , 2 - D i c h l o r o e t h a n e ( E D C ) B e n z e n e B e n z o ( a ) p y r e n e C a r b o n t e t r a c h l o r i d e C h l o r o f o r m c i s - 1 , 2 - D i c h l o r o e t h y l e n e E t h y l b e n z e n e M e t h y l t e r t - b u t y l e t h e r ( M T B E ) N a p h t h a l e n e T e t r a c h l o r o e t h y l e n e T o l u e n e trans-1,2-Dichloroethylene Trichloroethylene Vinyl chloride Xylenes (total) TW - 1 11 / 1 7 / 0 8 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 N A < 0 . 0 0 1 0. 0 1 1 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 0. 0 1 2 <0 . 0 0 1 < 0 . 0 0 2 < 0 . 0 0 1 < 0 . 0 0 2 < 0 . 0 0 3 TW - 2 11 / 1 7 / 0 8 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 N A < 0 . 0 0 1 0. 0 1 2 <0 . 0 0 1 < 0 . 0 0 1 0. 0 0 0 8 9 J <0 . 0 0 1 0. 0 1 4 <0 . 0 0 1 < 0 . 0 0 2 < 0 . 0 0 1 < 0 . 0 0 2 < 0 . 0 0 3 TW - 3 11 / 1 7 / 0 8 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 N A < 0 . 0 0 1 0. 0 0 4 <0 . 0 0 1 < 0 . 0 0 1 0. 0 0 1 3 <0 . 0 0 1 0. 0 0 4 1 <0 . 0 0 1 < 0 . 0 0 2 < 0 . 0 0 1 < 0 . 0 0 2 < 0 . 0 0 3 TW - 4 11 / 1 9 / 0 8 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 N A < 0 . 0 0 1 0. 0 0 5 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 2 < 0 . 0 0 1 < 0 . 0 0 2 < 0 . 0 0 3 TW - 5 11 / 1 8 / 0 8 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 0. 0 0 0 8 1 J NA < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 0. 0 0 3 5 <0.002 < 0 . 0 0 1 < 0 . 0 0 2 < 0 . 0 0 3 TW - 6 11 / 1 9 / 0 8 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 N A < 0 . 0 0 1 0. 0 0 0 5 6 J <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 2 < 0 . 0 0 1 < 0 . 0 0 2 < 0 . 0 0 3 TW - 1 1 05 / 2 2 / 0 9 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 N A < 0 . 0 0 2 0. 0 0 8 7 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 0. 0 0 4 3 <0 . 0 0 1 < 0 . 0 0 2 < 0 . 0 0 1 < 0 . 0 0 2 < 0 . 0 0 3 TW - 1 4 08 / 2 6 / 1 0 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 N A < 0 . 0 0 2 0. 0 0 5 0 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 0. 0 0 1 6 <0.002 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 3 05 / 2 7 / 1 0 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 N A < 0 . 0 0 2 0. 0 0 6 3 <0 . 0 0 1 < 0 . 0 0 1 0. 0 0 0 9 7 J <0 . 0 0 1 0. 0 0 4 2 <0 . 0 0 1 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 3 08 / 2 6 / 1 0 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 N A < 0 . 0 0 2 0. 0 0 6 7 <0 . 0 0 1 < 0 . 0 0 1 0. 0 0 0 8 5 J <0 . 0 0 1 0. 0 0 3 9 <0 . 0 0 1 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 3 11 / 2 2 / 1 0 <0. 0 0 1 <0. 0 0 1 <0.0 0 1 <0. 0 0 1 <0. 0 0 1 <0. 0 0 1 <0. 0 0 1 NA <0. 0 0 2 0. 0 0 5 3 <0. 0 0 1 <0. 0 0 1 0. 0 0 0 8 3 J <0. 0 0 1 0. 0 0 3 6 0.0 0 0 8 3 J <0.002 <0.002 <0.002 <0.003 G r o u n d w a t e r S a m p l i n g P o i n t S a m p l i n g D a t e ( m m / d d / y y ) [m g / L ] TW - 1 5 ADT 5 11 / 2 2 / 1 0 <0 .00 1 <0 .00 1 <0 .00 1 <0 .00 1 <0 .00 1 <0 .00 1 <0 .00 1 NA <0 .00 2 0 .00 5 3 <0 .00 1 <0 .00 1 0 .00 0 8 3 J <0 .00 1 0 .00 3 6 0 .00 0 8 3 J <0 .002 <0 .002 <0 .002 <0 .003 03 / 1 4 / 1 1 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 N A < 0 . 0 0 2 0. 0 0 7 4 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 0. 0 0 4 6 <0 . 0 0 1 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 3 05 / 2 7 / 1 0 <0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 N A < 0 . 0 0 4 0. 0 0 5 6 <0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 4 < 0 . 0 0 4 < 0 . 0 0 4 < 0 . 0 0 6 08 / 2 6 / 1 0 <0 . 0 1 0 < 0 . 0 1 0 < 0 . 0 1 0 < 0 . 0 1 0 < 0 . 0 1 0 < 0 . 0 1 0 < 0 . 0 1 0 N A < 0 . 0 2 0 0.0 0 6 6 J <0 . 0 1 0 < 0 . 0 1 0 < 0 . 0 1 0 < 0 . 0 1 0 < 0 . 0 1 0 < 0 . 0 1 0 < 0 . 0 2 0 < 0 . 0 2 0 < 0 . 0 2 0 < 0 . 0 3 0 11 / 2 2 / 1 0 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 N A < 0 . 0 0 2 0. 0 0 7 7 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 0. 0 0 1 8 0.0 0 0 6 4 J <0.002 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 3 03 / 1 4 / 1 1 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 N A < 0 . 0 0 2 0. 0 0 7 9 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 0. 0 0 2 5 <0 . 0 0 1 <0.002 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 3 05 / 2 7 / 1 0 <0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 N A < 0 . 0 0 4 0. 0 0 2 1 <0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 4 < 0 . 0 0 4 < 0 . 0 0 4 < 0 . 0 0 6 08 / 2 6 / 1 0 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 N A < 0 . 0 0 2 0. 0 0 0 7 8 J <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 3 11 / 2 2 / 1 0 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 N A < 0 . 0 0 2 0. 0 0 3 0 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 0 5 0.0 0 0 5 9 J <0.002 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 3 03 / 1 4 / 1 1 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 N A < 0 . 0 0 2 0. 0 0 2 8 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 0 5 <0 . 0 0 1 <0.002 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 3 TD M W - 1 3 / 1 6 / 1 1 <0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 < 0 . 0 0 1 N A < 0 . 0 0 2 0. 0 1 0 <0 . 0 0 1 < 0 . 0 0 1 0. 0 0 0 6 4 J <0 . 0 0 1 0. 0 0 5 3 <0 . 0 0 1 <0.002 < 0 . 0 0 2 < 0 . 0 0 2 < 0 . 0 0 3 0. 2 0 . 0 0 0 2 N E 0 . 0 0 6 0 . 0 0 7 0 . 0 0 0 4 0 . 0 0 1 0 . 0 0 0 0 5 0 . 0 0 0 3 0 . 0 7 0 . 0 7 0 . 6 0 . 0 2 0 . 0 0 6 0 . 0 0 0 7 0 . 6 0 . 1 0 . 0 0 3 0 . 0 0 0 0 3 0 . 5 NC 2 L S t a n d a r d No t e s : Bo l d v a l u e e x c e e d s N C 2 L S t a n d a r d ( J a n u a r y 2 0 1 0 ) . NA d e n o t e s N o t A n a l y z e d ; N E d e n o t e s N o t E s t a b l i s h e d TW - 1 6 TW - 1 7 ADT 5 Ta b l e 5 ( 1 ) : A n a l y t i c a l D a t a f o r G r o u n d w a t e r ( U s e r S p e c i f i e d C h e m i c a l s ) DS C A I D N o . : 6 0 - 0 0 0 2 A c e t o n e M e t h y l E t h y l K e t o n e TW - 1 11 / 1 7 / 0 8 0 . 0 1 1 <0 . 0 0 5 TW - 2 11 / 1 7 / 0 8 <0 . 0 1 < 0 . 0 0 5 TW - 3 11 / 1 7 / 0 8 <0 . 0 1 < 0 . 0 0 5 TW - 4 11 / 1 9 / 0 8 <0 . 0 1 < 0 . 0 0 5 TW - 5 11 / 1 8 / 0 8 <0 . 0 1 < 0 . 0 0 5 TW - 6 11 / 1 9 / 0 8 <0 . 0 1 < 0 . 0 0 5 TW - 1 1 05 / 2 2 / 0 9 <0 . 0 1 < 0 . 0 0 5 TW - 1 4 08 / 2 6 / 1 0 <0 . 0 1 < 0 . 0 0 5 05 / 2 7 / 1 0 <0 . 0 1 < 0 . 0 0 5 08 / 2 6 / 1 0 <0 . 0 1 < 0 . 0 0 5 11 / 2 2 / 1 0 0. 0 6 8 0. 0 0 2 8 J S a m p l i n g D a t e ( m m / d d / y y ) [m g / L ] G r o u n d w a t e r S a m p l i n g P o i n t TW - 1 5 ADT 5 (1 ) 11 / 2 2 / 1 0 0 .06 8 0 .00 2 8 J 03 / 1 4 / 1 1 <0 . 0 1 < 0 . 0 0 5 05 / 2 7 / 1 0 <0 . 0 2 < 0 . 0 1 08 / 2 6 / 1 0 <0 . 1 0 0 < 0 . 0 5 0 11 / 2 2 / 1 0 0 . 0 1 2 <0 . 0 0 5 03 / 1 4 / 1 1 <0 . 0 1 <0 . 0 0 5 05 / 2 7 / 1 0 <0 . 0 2 < 0 . 0 1 08 / 2 6 / 1 0 <0 . 0 1 < 0 . 0 0 5 11 / 2 2 / 1 0 0 . 0 0 9 3 J <0 . 0 0 5 03 / 1 4 / 1 1 <0 . 0 1 < 0 . 0 0 1 TD M W - 1 3 / 1 6 / 1 1 <0 . 0 1 < 0 . 0 0 5 64 - - - - - - - - - - - - - - - - - - NC 2 L S t a n d a r d No t e s : Bo l d v a l u e e x c e e d s N C 2 L S t a n d a r d ( J a n u a r y 2 0 1 0 ) . NA d e n o t e s N o t A n a l y z e d ; N E d e n o t e s N o t E s t a b l i s h e d TW - 1 6 TW - 1 7 ADT 5 (1 ) Ta b l e 9 : A n a l y t i c a l D a t a f o r N a t u r a l A t t e n u a t i o n P a r a m e t e r s DS C A I D N o . : 6 0 - 0 0 0 2 S a m p l i n g D a t e ( m m / d d / y y ) D i s s o l v e d o x y g e n ( D O ) N i t r a t e S u l f a t e M a j o r C a t i o n s M e t h a n e F e r r o u s I r o n O x i d a t i o n r e d u c t i o n p o t e n t i a l ( O R P ) A l k a l i n i t y C h l o r i d e ( o p t i o n a l ) C o n d u c t i v i t y p H T e m p e r a t u r e Total organic carbon (TOC)Ethane Ethene Un i t s mg / L m g / L m g / L m g / L m g / L m g / L mV mg / L m g / L μ s/ c m 2 st d u n i t ° C mg/L m g / L m g / L TD M W - 1 3 / 1 6 / 2 0 1 1 NA N A N A N A N A N A 23 0 NA N A 33 4 . 1 6 . 3 0 1 8 . 2 NA N A N A S a m p l e I D ADT 9 Page 1 of 1