IDX SAMPLING OF SOIL STOCKPILE (SF)-OCR

*5901HSSF1066*
1111111111111111111111111111
DocumentlD NONCD0001814
Site Name HAMILTON BEACH/PROCTOR SILEX
oocumentType Site Assessment Rpt (SAR)
RptSegment 1
DocDate
DocRcvd
Box
Accesslevel
Division
Section
Program
DocCat
9/27/1995
2/20/2007
SF1066
PUBLIC
WASTE MANAGEMENT
SUPERFUND
IHS (IHS)
FACILITY
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RADIAN
CORPORATION
September 27, 1995
Mr. Mario Kuhar
Sr. Environmental Engineer
Hamilton Beach<> Proctor-Silex, Inc.
4421 Waterfront Drive
Glen Allen, Virginia 23060
Re: Sampling and An~ysis of Soil Stockpile
Washington, North Carolina
Dear Mario:
(Shipping) 1600 Perimeter Park Drive
Morrisville, NC 27560
(Mailing) P.O. Box 13000
Research Triangle Park, NC 27709
[phone]
·-·~---·-···
RECEIVED WASHINGTON OFFIC2
oi .... -., -. ··~ ,,, vi ~ v 1. .• ·.J
..... ~ .. ·----... --
This letter report describes the methods and results of soil sampling conducted at your
Washington, NC facility on August 22, 1995.
Radian appreciates the opportunity to provide continued service to Hamilton
Beach O Proctor-Silex, Inc. If you have any questions regarding this report, please
contact me at [phone] or Becky Schecter at [phone].
Sincerely,
RADIAN CORPORATION
t;[,~v-
James Narkunas
Sr. Staff Scientist
JN:jq
cc: R. F. Schecter (w/out attachments)
File 650-138-02-01
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RADIAN CORPORATION
HAMILTON BEACH<> PROCTOR-SILEX, INC.
SOIL SAMPLING AND ANALYSIS REPORT
WASHINGTON, NORTH CAROLINA FACILITY
August 1995
1.0 INTRODUCTION
This letter report describes the methods and results of soil sampling conducted at
the Hamilton Beach<> Proctor-Silex, Inc. facility in Washington, North Carolina. Radian
performed sampling at the request of Hamilton Beach<> Proctor-Silex, Inc. to determine
the regulatory status of soil excavated from a drainage ditch following the release of used
oil.
1.1 Site Background
During drainage dit'ch maintenance, an unknown quantity of used oil was
accidently released into a drainage ditch adjoining the Hamilton Beach<> Proctor-Silex,
Inc. facility when a North Carolina Department of Transportation (NCDOT) work c~ew
ruptured a blocked pipe on the facility property. Hamilton Beach<> Proctor-Silex, Inc.
responded to the release by reporting it to the North Carolina Department of
Environmental Management (DEM) and by excavating all visibly affected soil from the
drainage ditch. The .excavated soil was subsequently placed in a plastic-lined and
covered stockpile within a secured area of the facility.
In accordance with directions from DEM and Division of Solid Waste
Management (DSWM) staff, Hamilton Beach <>Proctor-Silex, Inc. is required to
determine the regulatory status of the soil for disposal purposes. Consequently,
Hamilton Beach<> Proctor-Silex, requested that Radian collect soil samples from the
stockpile to provide this determination. Radian completed soil sampling on August 22,
1995.
1.2 Scope of Work
Radian collected grab samples from the approximate top, middle, and bottom of
each of four hand auger borings advanced into the stockpile. The twelve grab samples
were shipped to Radian Analytical Services (RAS) in Austin, Texas where they were
composited and analyzed for gasoline and diesel Total Petroleum Hydrocarbons (TPH)
and for Oil and Grease (O&G). A portion of the composite sample was also prepared
by the Toxicity Characteristic Leaching Procedure (TCLP) and the leachate analyzed for
the Toxicity Characteristic (TC) constituents.
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CORPORATION
2.0 METHODS AND PROCEDURES
2.1 Soil Sampling
Figure 1 sP,ows the boring locations and sampling intervals for each of the 12 grab
samples collected. Each sample was collected in a hand auger bucket and immediately
placed, without headspace, into a separate 250 ml, wide-mouth jar and capped.
2.2 Sample Handling and Analysis
All sample jars were placed in a cooler containing wet ice immediately upon
filling to ensure sample preservation at less than 4° Celsius. After all samples were
collected and properly packaged, the sample cooler was shipped to the laboratory for
next-day delivery. Standard chain-of-custody procedures were followed during sample
shipment to ensure proper sample handling and doc~men~ation.
Upon arrival at the laboratory, a composite sample was prepared using equal-
volume aliquots of the grab samples. The composite sample was analyzed for the
following parameters: TCLP volatiles, semi-volatiles, pesticides, herbicides, and metals;
TPH (gasoline and diesel); and, Oil and Grease.
3.0 ANALYTICAL RESULTS
Tables 1 and 2 summarize the qualified analytical data for the TC constituents
and the petroleum-related analytes, respectively. A copy of the entire laboratory report
including qualified da~a is attached.
4.0 CONCLUSIONS
Based on the analytical results for the composite sample, the stockpiled soil is not
characteristically hazardous for the TC constituents. The stockpiled soil does, however,
exhibit several petroleum constituents. These constituents include principally Oil and
Grease; a multi-component hydrocarbon eluting uniformly throughout the established
integration range for gasoline but which does not correspond to known gasoline patterns;
and, unidentified organic compounds eluting within the established range for lubricating
oil.
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I TABLES
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TABLE 2. RESULTS OF TPH AND O&G ANALYSIS
Hamilton Beach~Proctor-Silex, Inc.
Washington, North Carolina
August 22, 1995
\:\\l\\\\\\~1::::~:j\\\l::~~~\\:;;i::;~~:,.\;~~~lllll\l\\\ll\~!I\\\'.\'.\\:; ,\i;,i~::j~::::fl.fil~'~\\ll\\!\!\!\!!!1!\1\:!\!l!!\!!!\!!)ll\1::11:111111:11'.\llll\\\\lll\l:\\'.\\:::1!::1:::::~1:1:;;:i~ :~\i:~\:r=;;1;,:~;::;\~~::1;,:;,::;:::~1:::\i\;{:)!l!ll\j\\::1:~!\\\l\lll\!\!!!\~!!!!!!!::\~\i!\r.~:~~Y1t.~:1;::~~:11::\\l!llllllil\:\::~~!!ll!lll!!!\l\\!:~;:\~l!!l\!\!\l\::~:;l\l\ii::!!!!!'.
TPH -Gasoline (µg/kg)
Benzene ND (7.14)
Ethylbenzene 70.5
Gasoline ND (1530)
Toluene 147
Unidentified organics 24,100
Xylenes (total) ND (170)
TPH -Diesel (µg/ g)
Diesel ND (0.00518)
Jet Fuel (JP4) ND (0.00611)
Kerosene ND (0.00549)
Unidentified Organics 150
Oil and Grease (mg/kg)
Oil and Grease 1440
ND =· Analyte not detected at a concentration equal to or greater than stated detection limit.
Note different reporting units for various analytical groups: µg/kg = ppb; µg/g = ppm; mg/kg = ppm.
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IABORATORY REPORTS
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QC Summary
Radian Corporation collected twelve containers of sample (STKPILE) from the stockpile
at Hamilton Beach-Proctor Silex on August 22, 1995. The sample was submitted to
Radian Analytical Services Laboratory in Austin, Texas for compositing prior to TCLP
organic and inorganic, total petroleum hydrocarbons (TPH) as gasoline and diesel, and
oil and grease analyses. The analytical results for the composite stockpile sample were
reported by the laboratory under work orders 9508429 through 9508440.
Radian Corporation reviewed the data for accuracy and precision. The evaluation of
accuracy was based on holding times, blank contamination, spike results, and calibration.
Precision was based on the results of laboratory duplicate analyses.
The sample was received in good condition at a temperature of 2C on August 23, 1995
by Radian Analytical Services. The composite sample was leached, prepared, and
analyzed within holding times.
Toluene, a common laboratory contaminant, was detected during the TPH as gasoline
analysis in laboratory blanks. Benzene, xylenes, heptachlor epoxide, unidentified volatile
and extractable TPHs, oil and grease, arsenic, barium, cadmium, chromium, selenium,
and mercury were also detected in laboratory blanks. Sample results that were not
substantially (10 times for common contaminants such as toluene, five times for all
others) greater than the maximum amount detected in the blanks have been· qualified as
non-detect and the sample detection limit elevated to the amount detected in the
sample.
The results of the laboratory control sample (LCS) and LSC duplicate analyses met lab
specification limits for accuracy and precision.
All surrogate recoveries fell within quality control (QC) limits for sample STKPILE.
Sample STKPILE was subjected to a matrix spike (MS) anci MS duplicate analysis. With
the exception of the TCLP semi-volatile organic MS /MSD analyses, acceptable results
were obtained for accuracy and precision. A low recovery was obtained during the
TCLP semi-volatile organic analysis of sample STKPILE for 2,4-dinitro.toluene (54, 50%)
and 4-nitrophenol (19%). In addition, the relative percent difference (37%) between
pentachlorophenol results exceeded the QC limit of 26%. The nondetect TCLP result
for 2,4-dinitrotoluene was qualified as estimated (UJ) in sample STKPILE because of
matrix interferences. Qualification of the pentachlorophenol data due to poor precision
is not required because the analyte was not detected in sample STKPILE. In addition, it
was not necessary to qualify 4-nitrophenol data because it is not a target analyte.
With the exception of the volatile organic continuing calibration of August 31st, the
organic and inorganic results for the initial and continuing calibrations met laboratory
specifications. The percent recovery ,for 1,2-dichloropropane (122%) slightly exceeded
the upper control limit of 120% during the volatile organic continuing calibration of
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August 31st at 12:48. No action is required because 1,2-dichloropropane is not a target
analyte.
Acceptable precision was obtained during the laboratory duplicate analysis for oil and
grease on sample STKPILE.
Inorganic values less than samp~e detection limits have been flagged non-detect because
of method limitations. Non-confirmed pesticide results, flagged by the laboratory with a
"k", have been qualified as non-detect.
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SUMMARY OF ANALYTICAL RESULTS1
--TCLP Volatile Organics (SW-846 8260A), µgfL
1, 1-Dichloroethene
Tetrachloroethene
Trichloroethene
TCLP Semi-volatile Organics (SW-846 8270)
2,4-Dinitrotoluene
TCLP Pesticides {SW-846 8080), µgfL
Primary Column:
Heptachlor Epoxide
Secondary Column:
Gamma-BHC
TCLP Herbicides (SW-846 8150)
TCLP Metals (SW-846 6010/7470A), mg~
Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Selenium
Silver
TPH-Gasoline {~odified 8015), µg/Kg
Ethylbenzene
Toluene
Xylenes
Unidentified Organics2
TPH-Diesel (Modified 8015), µg/g
Unidentified Organics3
Oil and Grease (SW-846 9071), mg/Kg
10.4 (8.02)
68.8 (6.74)
54.2 (4.38)
AllND
ND (2.82 UJ)
ND (1.86 U)
ND (0.057)
AllND
ND (0.00313)
0.270 {0.00078)
0.00572 (0.00023)
ND (0.0019 U)
0.0366 (0.00116)
ND (0.00003 U)
ND (0.00924 U)
ND (0.00111)
70.5 (7.07)
147 (7.04)
ND (170 U)
24,100 (1530)
150
1440 (156)
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Footnotes
1 Only detected results and those qualified as a result of the data validation process
are summarized in the table. Detection limits (DL) have been reported in parenthesis.
2 The hydrocarbon value indicates the presence of a multi-component hydrocarbon
eluting uniformly throughout the established integration range for gasoline but which
dqes not correspond to known gasoline patterns.
3 The hydrocarbon value indicates the presence of compounds eluting within the
established integration range for lubricating ·Oil.
ND Not detected
U Not detected at associated level due to the presence of blank contamination.
UJ Analyte not detected and the detection limit is uncertain.
---
09/07/95 10:05:08
- --
Report Form
------
RADIAN ANALYTICAL SERVICES
F P A S R E P 0 R T
T A B L E 0 F C 0 N T E N T S
Client HAMILTON BEACH
Facility WASHINGTON NC
Client Code· HAM BEACH NC
Analytical Batch ID
Work Order Sunmary
Flag Definitions
Protocol Sunmary for Volatile Organics SW8260A
Results Sunmary
Initial Calibration
Analysis Batch Sunmary MSMSDA5D831121102
Results
Laboratory Blank Information
Laboratory Control Samples
Matrix Spikes
Calibration Verification
Corrments/Narrative
----- --
Work ~;Jr # 9508430
~~L7'm· ,.,ur;:~. ~ V</-. .U/f'f/
Pages
From To
1 1
2 2
3 3
4 5
6 11
12 12
13 13
14 15
16 16
17 17
18 26
27 27
- - ----
09/07/95 10:05:08
Report RADIAN CORPORATION
To 3200 E. CHAPEL HILL RD.
P.O. BOX 13000
Attention JIM NARKUNAS
Phone RTP -----------
Prepared
By
Radian Analytical Services
14046 Sunmit Or., Bldg. B
P. O. Box. 201088
Austin, TX 78720-1088
512/244-0855
CSC JALINDSEY
Project Sample
Description
STKPILE
TBLK953700
STKPILE
ID/
---,---··-----
WORK ORDER SUMMARY
Client Code HAM BEACH NC
Client HAMILTON BEACH
Facility WASHINGTON NC
Work ID WASHINGTON.NC
Case II :.;;NA:.:__ _____ _
SDG # "'"'N'"'"A ______ _
RAS # 5081 lAJAL
Lab Sample ID Test Code(s)
01A LEACHATE 826SWBTL
02A LEACHATE 826SWBTL
03A LEACHATE HS 826SWBHS
04A LEACHATE HSD 826S>IBHS
Work Order I 9508430
Page _1 _
RCN 650-138-02-01
Method Desciption
Volatile Organics S\.18260A
Volatile Organics S\.18260A
Volatile Organics SW8260A
Volatile Organics S>l8260A
--
-
09/07/95 10:05:08 ANALYTICAL PROTOCOL SUMMARY
f l A G D E f I N I T I O N S
Flag Definition
< DL
NA
NC
ND
NR
NS
Result less than stated Detection Limit and greater than or equal to zero.
Analyte concentration not available for this analysis.
RPO and/or i Recovery not calculated. See Narrative for explanation.
Not detected. No instrument response for analyte or result less than zero.
Not reported. Result greater than or equal to stated Detection Limit and less than specified Reporting Limit.
Analyte not spiked.
B
c
Analyte detected in method blank at concentration greater than the Reporting Limit (a~d greater than zero).
Confirming data obtained using second GC colLmn or GCHS.
E Analyte concentration exceeded calibration range.
F Interference or coelution suspected. See Narrative for explanation.
H Presence of analyte previously confirmed by historical data.
I Analyte identification suspect. See Narrative for explanation.
J Result is less than stated Detection Limit but greater than or equal to specified Reporting Limit.
K Peak did not meet method identification criteria. Analyte not detected on other GC colunn.
M Result modified from previous Report. See Narrative for explanation.
P Analyte not confirmed. Results from primary and secondary GC columns differ by greater than a factor of 3.
Q QC result does not meet tolerance in Protocol Specification.
R Result reported elsewhere.
s Analyte concentration obtained using Method of Standard Additions (HSA).
T Second column confirmational analysis not performed.
X See Narrative for explanation.
Y See Narrative for explanation.
Z See Narrative for explanation.
\Jerk Order # 9508430
Page L
- - - - - -- - - - - --- - - -
- - -- -
09/07/95 10:05:08
Method Volatile Organics SW8260A
Test Code 826SWBTL
Project Sample ID:
Lab ID:
Fi le ID:
Date Collected:
Date Pr:-epared:
Date Analyzed:
Dilution Factor:
Matrix:
Uni ts:
Report as:
Column:
Analyte
Surrogate ls)
1,4-Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
--
STKPILE
9508430-0lA LEACHA
F0831517
08/29/95
08/31/95 19:41:00
10
Water
ug/L
received
Cone. DL
Recovery
x
94
111
97
-.. --
R E S U L T S S U M M A R Y (Qint 'd)
Cone. DL Cone.
Recovery Recovery
x x
..
DL
--
~rk Order # 9508430
Page2._
Cone. DL
Recovery
x
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--
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09/07/95 10:05:08
Sol'n # #MS-VOA-STD-2 p.75
Method Volatile Organics SW8240
Test Code 824SWAT1
Analytes
Carbon disulfide
Acrylonitrile
lrichlorofluoromethane
1, 1-Dichloroethene
CCC
3-Chloropropene
Acetoni tri Le
1,1-Dichloroethane
SPCC
trans-1,2-Dichloroethene
Methyl ethyl ketone
Chloroform
CCC
- --
-
- ----------
INITIAL C A L I 8 R A T I 0 N OJnt'd Work Order # 9508430
Page L
Initial Calibration #.MSDA950503000000
Calibration Date 05/03/95 OO:OO:OO
Response Response Response .
Factor Factor Factor
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
5.416 4.649 4.930
10 20 50
0.568 0.564 0.573
10 20 50
2.827 2.228 1.696
10 20 50
1. 561 1.382 1.379
10 20 50
2.534 2.291 2. 195
10 20 50
o. 178 0.136 0.124
50 100 250
2.482 2".263 2.245
10 20 50
1.543 1.382 1.413
10 20 50
0.647 0.524 0.554
10 20 50
2.293 2.086 2.055
10 20 50
Response
Factor
Reference
Cone.
ug/L
4.478
100
0.530.
100
2.359
100
1.314
100
2.108
100
0.115
500
2.104
100
1.355
100
0,551
100
1.933
100
Response
Factor
Reference
Cone.
ug/L
4.949
200
0.555
200
1.604
200
1.400
200
2. 174
200
0.122
1000
2.203
200
1.443
200
0.534
200
2.018
200
Instrument HSDA
Analyst TLS
Reviewer .:..:A'""'PS"----
Response
Reference
Cone. -RF
4.88
'
. 0.558
2. 14
1.41
'
2.26
0.135
2.26
1.43
0.562
2.08
Specification Limits for avg. RF of SPCC, system performance check compounds, ~ 0.050C8270l; ~ 0.300 (~ 0.250 bromofonn, 8240)
--
'l RSD
7.31
3.04
23.5
6.53
7.36
18.7
6.14
5.09
8.73
6.43
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09/07/95 10:05:08
Sol'n # #MS-VOA-STD-2 p.75
Method Volatile Organics 5~8240
Test Code 824S~AT1
Analytes
Benzene
1, 1,2-Trichloroethane
1,2-Dibromoethane
2-Chloroethyl vinyl ether
Methyl methacrylate .
Tribromomethane(Bromoforml
SPCC
1, 1, 1,2-Tetrachloroethane
2-Hexanone
4-Methyl-2-pentanone(MIBKl
1,2,3-Trichloropropane
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I N I T I A L C A L I B R A T I 0 N Cont'd Work Order I 9508'.30
Page2..._
Initial Calibration# MSDA950503000000
Calibration Date 05/03/95 00:00:00
Response Response Response
Factor Factor Factor
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
1.260 1. 136 1. 113
10 20 50
0.596 0.542 0.555
10 20 50
0.642 0.599 0.619
10 20 50
0.197 0.189 0. 181
10 20 50
o. 194 0.188 0.192
10 20 50
0.454 0.407 0.435
10 20 50
0.612 0~559 0.570
10 20 50
0.395 0.361 0.405
10 20 50
0.285 0.261 0.277
10 20 50
0.609 0.544 0.558
10 20 50
Response
Factor
Reference
Cone.
ug/L
1.060
100
0.541
100
0.596
100
o. 18'.
100
0.185
100
0.426
100
0.552
100
0.38'.
100
0.256
100
0.524
100
Response
Factor
Reference
Cone.
ug/L
1.101
200
0.585
200
0.650
200
0.209
200
0.202
200
0.481
200
0.607
200
0.425
200
0.275
200
0.569
200
Instrument MSDA
Analyst TLS
Reviewer ~A~PS~--
Response
Reference
Cone. -RF
1. 13
'
0.564
0.621
' 0.192
0.192
0.441
0.580
0.394
0.271
0.561
Specification Limits for avg. RF of SPCC, system performance check compounds, ~ 0.050(8270l; ~ 0.300 (~ 0.250 bromoform, 8240)
--
t RSD
6.67
4.49
3.94
5.87
3.38
6.40
4.78
6.05
4.42
5.66
- ---
09/07/95 10:05:08
Sol'n # #HS-VOA-STD-2 p.75
Method Volatile Organics SW8240
Test Code 824SWAT1
Analytes
m&p-Xylene
Propaneni tri le -
1, 1,2-Trichlorotrifluoroethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
cis-1,2-Dichloroethene
Tetrahydrofuran
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I N I T I A l C A l I B R A T I 0 N C.(]flt'd
Initial Calibratiqn # HSDA950503000000
Calibration Date 05/03/95 00:00:00
Response Response Response
Factor Factor Factor
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
1.224 1.089 1. 105
20 40 100
0.189 o. 185 IJ.181
50 100 250
1.873 1. 520 1.571
10 20 50
1.416 1.243 1.336
10 20 50
1.498 1.305 1.385
10 20 50
l.322 1. 172 1.267
10 20 50
1.482 l.384 1.368
10 20 50
0.205 0.173 o. 195
10 20 50
Response
Factor
Reference
Cone.
ug/L
1.045
200
0.169
500
1.408
100
1.259
100
1.322
100
1.214
100
1.287
100
0.165
100
- - --
Response
Factor
Reference
Cone.
ug/L
1. 112
400
0.177
1000
1. 552
200
1.399
200
1.425
200
1.337
200
1.346
200
0.157
200
\.Jerk Order # 9508430
Page 1L
Instrument HSDA
Analyst TLS
Reviewer ~A_PS~--
Response
Reference
Cone. -RF
1. 12
0.180
1.58
1.33
1.39
1. 26
.
1.37
0.179
Specification Limits for avg. RF of s~cc, system performance check compounds, ~ 0.050(8270); ~ 0,300 (~ 0.250 bromoform, 8240)
--
'l RSD
5.94
4.27
10.9
5.92
5.67
5.55
5. 17
11. 3
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09/07/95 10:05:08
Method Volatile Organics S\.18260A
Test Code 826SWBOO
Initial Calibration# HSDA950503000000
calibration Date .-.05"-'/-=0=3/'"""'9"""5 ___ _
Sequence/Analysis Time
1 08/31/95 12:11:00
2 08/31/95 12:24:DO
3 08/31/95 12:48:00
5 08/31/95 14:13:00
6 08/31/95 14:37:00
7 08/31/95 15:32:00
8 08/31/95 15:56:00
16 08/31/95 19:17:00
17 08/31/95 19:41:00
18 08/31/95 20:06:00
19 08/31/95 20:30:00
21 08/31/95 21:30:00
22 08/31/95 21:43:00
23 08/31/95 22:07:00
36 09/01/95 09:22:00
37 09/01/95 09:35:00
38 09/01/95 10:00:00
- ---
ANALYSIS BATCH SUMMARY
Analysis Batch# HSHSDA50831121102
Analysis Start Date/Time 08/31/95 12:11:00
Analysis Stop Date/Time 09/01/95 11:12:00
\.Jork Order I 9508430
Page .1L
Instrument HSDA
Analyst HER
Reviewer '"'A'-'PS=--------
Project Sample ID Lab Sample ID Sample Type Analysis File I
BFB GCHS Tune F0831501
SB Laboratory Blank F0831502
VSTDCAL Continuing Calibration Check F0831503
LCS955515 Lab Control Sample F0831505
LCSD955516 Lab Control Sample Dup F0831506
SB Laboratory Blank F0831507
BLK953563 Laboratory Blank F0831508
TBLK953700 9508430-02A Laboratory Blank F0831516
STKPILE 9508430-0lA Sample F0831517
STKPILE 9508430-03A Matrix Spike F0831518
STKPILE 9508430-04A Matrix Spike Dup F0831519
BFB GCHS Tune F0831521
SB Laboratory Blank F0831522
VSTOCAL Continuing Calibration Check F0831523
BFB GCHS Tune F0831536
SB Laboratory Blank F0831537
VSTDCAL Continuing Calibration Check F0831538
--------- -- - --
-- --- -
09/07/95 10:05:08
Project Sample ID .:::S_,_TK"'P'"-'I'-"L'-"'E _______ _
Lab Sample ID 9508430-0lA LEACHA
Fi le# F0831517
Method Volatile Organics SW8260A
Test Code 826SWBTL
Analyte
Benzene
2-Butanone(MEKl
Carbon tetrachloride
Chlorobenzene
Chloroform
1,2-Dichloroethane
1, 1-Dichloroethene ·
Tetrachloroethene
Trichloroethene
Vinyl chloride
Surrogate(s)
1,4-Bromofluorobenzene
CAS #
71-43-2
78-93-3
56-23-5
108-90-7
67-66-3
107-06-2
75-35-4
127-18-4
79-01-6
75-01-4
CAS #
460-00-4
---- -
RESULTS
Extraction Batch #
Analysis Batch # MSMSDA50831121102
TCLP Batch# ·TCTCLP508281600
Date Collected 08/29/95
Date Received 08/23/95
Date Prepared
Instrument MSDA
Column ___ _
Date Analyzed 08/31/95 19:41:00
Analyst MER
Reviewer !.!A!....:PS~--
Aliquot Mass/Voll.MTle
5.0 (mU
Extract/Digestate Volume
5.0 (ml)
Dilution Factor 10
Measured Concentration
ug/L
ND
ND
ND
ND
ND
ND
10.4
68.8
54.2
ND
Spiked
Cone. Measured Concentration
ug/L ug/L
50D 468
1,2-Dichloroethane-d4 17070-07-0 500 557
Toluene-dB 2D37-26-5 500 486
-----
\.Jork Order # 9508430
Page 11_
Reporting Subset _ Matrix H
Spikes Subset_ Report As received
Specs Subset _ i Moisture
Detection Limit Reporting LimH
ug/L ug/L
5.03 0
23.2 0
5.66 0
5.91 D
6.78 0
7.91 0
8.02 0 '
6.74 0
4.38 0
7.38 0
i Specification Limits
Recovery Low High
i i i
94 75 113
111 56 141,
97 85 115
--
-
09/07/95 10:05:08 LABORATORY BLANK INFORMATION \.lork Order # 9508430
Page ll_
Lab Sample ID BLK953563
File # F0831508
Date Prepared
Extraction Batch It--------
Analysis Batch# MSMSDA50831121101
Date Analyzed 08/31/95 15:56:00
Instrument MSDA
Column ----Analyst MER
Reporting Subse~ _
Spikes Subset _
Specs Subset _
11ctLl'ix H
Method Volatile Organics S~260A
Test Code 826SWBTL Reviewer '-'A::...;PS=-----
Aliquot Mass/Volume
5.0 (mll
Extract/Oigestate Volume
5.0 (ml l
Dilution Factor 1
Measured Cone. ·Detection Limit Reporting Limit
Analyte ug/L ug/L ug/L
Benzene ND 0.503 0
2-Butanone(MEK) ND 2.32 0
Carbon tetrachloride ND 0.566 0
Chlorobenzene ND 0.591 0
Chloroform NO 0.678 0
1,2-Dichloroethane ND 0.791 0
1, 1-Dichloroethene ND 0.802 0
Tetrachloroethene NO 0.674 0
Trichloroethene NO 0.438 0
yinyl chloride NO 0.738 0
Specification Li.mits
Spiked
Cone. Measured Cone. Recovery Low High
surrogate(sl ug/L ug/L l l l
1,4-Bromofluorobenzene 50.0 45.9 92 83 113
1,2-0ichloroethane-d4 50.0 54.9 110 59 135
Toluene-dB 50.0 48.5 97 87 113
--- ----... ·----- ----·-
--.. ----.. .. .. ----
09/07/95 10:05:08 LABORAJORY BLANK INFORMATION Work Order # 9508430
Page 12_
Lab Sample ID 9508430-02A LEACHA
Fi le # F0831516
Method Volatile Organics S~8260A
Test Code 826S~BTL
Date Prepared
Extraction Batch II--------
Analysis Batch# HSHSDA50831121102
TCLP Batch # TCTCLP508281600
Instrument HSDA
Date Analyzed 08/31/95 19:17:00 Column ___ _
Analyst HER
Reviewer :..:A~PS=----
Aliquot Hass/Volume
5.0 (ml)
Extract/Digestate Volume
5. O (ml)
Dilution Factor 10
Reporting Subset _
Spikes Subset_
Specs Subset _
Matrix H
Measured Cone. Detection Limit Reporting Limit
Analyte ug/L ug/L ug/L
Benzene ND 5.03 0
2-Butanone(HEK) ND 23.2 0
Carbon tetrachloride ND 5.66 0
Chlorobenzene ND 5.91 0
Chloroform ND 6.78 0
1,2-Dichloroethane ND 7.91 0
1, 1-Dichloroethene ND 8.02 0
Tetrachloroethene ND 6.74 0
Trichloroethene ND 4.38 0
Vinyl chloride ND 7.38 0
Specification .Limits
Spiked
Cone. Measured Cone. Recovery Low High
Surrogate(s) ug/L ug/L l l l
1,4-Bromofluorobenzene 500 472 94 75 113
1,2-Dichloroethane-d4 500 552 110 56 144
Toluene-dB 500 486 97 85 115
--
09/07/95 10:05:08
Method Volatile Organics SW8260A
Test Code 826SWBTL
Control Std. # Vol. Added
lCS _5 __ !!!:.._
----
----
Analyte
Benzene
2-Butanone(MEK)
Carbon tetrachloride
Chlorobenzene
Chloroform
1,2-Dichloroethane
1, 1-Dichloroethene
Tetrachloroethene
Trichloroethene
Vinyl chloride
surrogate(s)
1,4-Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
---..
Date Prepared
LABORATORY CONTROL SAMPLE
Extraction Batch # --------
Analysis Batch # MSMSDA50831121100
York Order I 9508430
Page ].L
Instrument MSDA Reporting Subset _ _ Matrix ~
. Date Analyzed D8/31/95 14:37:00 Column ___ _ Spikes Subset _ _ Report As received
Specs Subset __ l Moisture
Surrogate Sol'n # Vol. Added
1 2-DCA-d4 _5 __ !!!:.._
Toluene-dB _5_ !!!:.._
1 4-BFB _5 __ !!!:.._
--.. -
Analyst MER
Reviewer ._AP __ s..__ __
LCS
lab Sample ID
LCS955515
Fi le ID F0831505
-
Spiked Measured
Cone. Cone.
ug/L ug/L
20.0 21.2
100 107
20.0 20.9
20.0 20.8
20.0 20.4
20.0 23.0
20.0 20.8
20.0 19. 1
20.0 20.3
20.0 19.3
50.0 47.6
50.0 55. i
50.0 48.2
Rec.
i
106
107
104
104
102
115
104
96
102
97
95
110
96
.. .. ..
File
Spiked
Cone.
ug/L
20.0
100
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
so.a
50.0
50.0
-
LCS Duplicate
Lab Sample ID
LCSD955516
ID F0831506
Measured
Cone.
ug/L
21.4
123
21.3
21.0
20.3
23.4
20.6
19.0
20.6
19.7
48.2
55. 1
48.5
Aliquot Mass or Vol
Extract Mass or Vol
Recovery
Spec.
Limits
Rec. Low High
l l l
107 77 135
123 o. 1 182
107 70 140
105 74 124
101 66 130
117 58 142
103 45 149
95 68 126
103 75 119
99 37 146
96 83 113
110 59 135
97 87 113
!
--~5.~D (ml)
__ 5::..:·=o <mll
RPO
Spec.
Result Limit
l l
0.94 10
14 50
2.8 10
0.96 12
0.98 16
1. 7 26
0.97 29
1. 0 11
0.98 11
2.0 38
'
-- ---.. -
-...... ..
09/07/95 10:0~:0B
-.. ..... -..
" A T R I X S P I K E ( S )
Extraction Batch ft--------
Analysis Bate~# MSMSOA50B31121102
TCLP Batch # TCTCLP50B2B1600
-- --
Work Order I 950B430
Page 1L
-
Project Sample ID """S"'"'TK""P~I""'L=E-------­
Method Volatile Organics SWB260A
Date Collected OB/29/95
Date Received OB/23/95
Instrument MSD11
Column ----
Reporting Subset _ _ Matrix H
Spikes Subset__ Repcirt As received
Specs Subset__ t Hoist <i Test Code B26SWBMS Date Prepared Analyst HER
Date Analyzed OB/31/95 20:30:00 Reviewer ,_,A'"'PS=----
Spike Sol 'n II Vol. Added Sample Spiked Sample Spiked Sample Dup
Matrix SQike _5 __ .!:!..L Lab Sample ID Lab Sample ID Lab Sample ID
9508430-0lA LEACHA 9508430-03A l.EACHA 9508430-04A LEACHA ----Fi le I FOB31517 Fi le # FDB31518 Fi le I FOB31519 ----Surrogate Sol 'n Vol. Added Aliquot Mass/Vol Aliquot Hass/Vol Aliquot Hass/Vol
1 2-DCA-d4 L_ .!:!..L 5.0 (ml) 5.0 (ml) 5.0 Cmll .Recovery
Toluene-dB _5 __ .!:!..L Extract Hass/Vol Extract Hass/Vol Extract Hass/Vol Specifi-
1 4-BFB _5 __ .!:!..L 5.0 (ml) 5.0 (ml) 5.0 Cmll cation
Di l Fact. 10 Di l Fact. 10 Di l Fact. 10 Limits RPO -I
Spike Specifi-
Sol 'n Measured Spiked Measured Spiked Measured cation
Analyte Cone. Cone. Cone. Cone. Rec. Cone. Cone. Rec. Low High Result Limit
ug/L ug/L ug/L ug/L t ug/L ug/L t t t t t
Benzene 50000 ND 500 547 109 500 563 113 n 135 3.6 10
Chlorobenzene 50000 ND 500 567 113 500 580 116 74 124 2.6 12
1, 1-Dichloroethene 50000 10.4 500 51B 101 500 538 106 45 149 4.B 29
Toluene 50000 7.30 500 546 10B 500 563 111 79 131 2.7 12
Tri ch loroethene 50000 54.2 500 613 112 500 623 114 75 119 1.B 11
Surrogate(sl
1,4-Bromofluorobenzene 50000 468 500 470 94 500 475 95 75 113
1,2-Dichloroethane-d4 50000 557 500 553 111 500 565 113 56 144
Toluene-dB 50000 486 500 489 9B 500 493 99 85 115
-
-
09/07/95 10:05:08 C 0 N T I N U I N G ( 0 R D A I L Y ) C A L I 8 R A T I 0 N
VERIFICATION
\.Jork Order I 9508430
Page~
Lab Sample ID VSTDCAL
Fi Le I F0831503
Method Volatile Organics Slr/8260A
Test Code 826SWBOO
Analyte
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Benzene
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone(HEK)
Carbon disulfide
Carbon tetrachloride
Ch Lorobenzene
Chloroethane
2-Chloroethyl vinyl ether
Chloroform
Chloromethane
3-Ch Loropropene-
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
.. ... .. ..
Analysis Batch# HSHSDA50831121100
Initial Calibration# HSDA950503000000
Date Analyzed 08/31/95 12:48:00 Reporting Subset_
Spikes Subset _
Specs Subset _
Measured Reference
Concentration Concentration Recovery
ug/L ug/L ~
58.7 50.0 117
257 250 103
305 250 122
58.6 50.0 117
53.3 50.0 107
55.0 50.0 110
53.3 50.0 107
46.7 50.0 93
50.0 50.0 100
55.2 50.0 110
59.3 50.0 119
55.3 50.0 111
43. 1 50.0 86
60.9 50.0 122
53.6 50.0 107
55.4 50.0 111
57.5 50.0 115
54.6 50.0 109
57.0 50.0 114
58.5 50.0 117
55.5 50.0 111
61. 9 50.0 124
50.8 50.[l 102
51.0 50.0 102
49.3 50.0 99
·----
•• .. .... - -
Instrument ~
Analyst HER
Reviewer "-'A~PS~--
Recovery
Specification
Limits
Low High
~ ~
80 120
--.. .. -
-............. .. ... ........
09/07/9S 10:05:08 C 0 N T I N U I N G ( 0 R D A I L Y ) C A L I B R A T I 0 N
VERIFICATION
Analysis Batch I MSMSDAS0831121100
Initial Calibration I MSDA9SOS03000000
Lab Sample ID VSTDCAL Date Analyzed 08/31/9S 22:07:00 Reporting Subset _
Spikes Subset _
Specs Subset
file # F0831S23
Method Volatile Organics SW8260A
Test Code 826SWBOO
_ _,_ -
Work Order I 9S08430
Page IL
Instrument ~
Analyst MER
Reviewer :.:A.:..;PS::.---
Recovery
Specification
Limits
Measured Reference
Concentration Concentration Recovery Low High
Analyi:e ug/L ug/L 'X 'X 'X
Acetone 62.2 so.a 124
Acetonitrile 280 2SO 112
Acrolein 304 2SO 122
Acrylonitrile 62.6 50.0 125
Benzene S6. 1 so.a 112
Bromodichloromethane S7.0 50.0 114
BrOOX>form S3.6 so.a 107
Bromomethane 48.6 so.a· 97
2-ButanoneCMEK) 57.6 50.ci 11 S.
carbon disulfide S7.8 so.a 116
carbon tetrachloride 59.6 50.0 119
Chlorobenzene S7.4 so.a 115
Ch l oroe thane 46.0 so.a 92
2-Chloroethyl vinyl ether 62.6 so.a 12S
chloroform S6.4 so.a 113 80 120
Chloromethane S7.8 so.a 116
3-Ch loropropene S8.9 so.a 118
1,2-Dibronio-3-chloropropane S7.3 so.o 11S
DibrOOX>chloromethane S7.8 so.a 116
1,2-Dibromoethane 61.6 so.a 123
Dibromomethane S7.7 sa.a 11S
· trans-1,4-Dichloro-2-butene 66.S sa.o 133
1,2-Dichlorobenzene 53. 1 so.a 106
1,3-Dichlorobenzene 53.9 so.a 108
1,4-Dichlorobenzene 52.1 so.o 104
.. -
- -
___ . ___ .. _________ .. _
09/05/95 17:28:27
Method Semivolatiles by SW846
Test Code 827SWAMG
Initial Calibration# MSD2950703111400
Calibration Date ~07~/~0~3/"-'9~5 ___ _
Sequence/Analysis Time
1 09/01/95 10:33
2 09/01/95 10:54
3 09/01/95 11:33
4 09/01/95 12:43
5 09/01/95 13:23
6 09/01/95 14:02
9 09/01/95 15:56
10 09/01/95 16:15
24 09/02/95 01:09
25 09/02/95 01:47
26 09/02/95 02:25
27 09/02/95 03:04
ANALYSIS BATCH SUMMARY
Analysis Batch# MSMSD250901103302
Analysis Start Date/Time 09/01/95 10:33:00
Analysis Stop Date/Time 09/02/95 03:04:00
\.lark Order # 9508434
Page .fl_
Instrument MSD2
Analyst MCL
Reviewer --------
Project Sample ID Lab Sample ID Sample Type Analysis File#
TUNE GCMS Tune M9672
SSTD050 Continuing Calibration Check M9673
LCS954261 Lab Control Sample M9674
LCS955683 Lab Control Sample M9675
LCSD955683 Lab Control Sample Dup M9676
BLK953709 Laboratory Blank M9677
TUNE GCMS Tune M9680
SSTD050 Continuing Calibration Check M9681
STKPILE 9508434-01A Sample M9695
STKPILE 9508434-03A Matrix Spike M9696
STKPILE 9508434-04A Matrix Spike Dup M9697
TBLK953699 9508434-02A Laboratory Blank M9698
------ -.... - -------.... _
09/05/95 17:28:27
Project Sample ID _ST_K_P~I~L~E ______ _
Lab Sample ID 9508434-01A LEACHA
Fi le # ~M9~6~9~5 ___ _
Method Semivolatiles by S~8270A
Test Code 827S~ATL
Surrogate(sl
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d5
Terphenyl-d14
2,4,6-Tribromophenol
CAS #
321-60-8
367-12-4
4165-60-0
4165-62-2
1718-51-0
118-79-6
R E S U L T S (c.ont'd)
Extraction Batch# 3520950830111500
Analysis Batch # MSMSD250901103302
TCLP Batch # TCTCLP508281645
Date Collected 08/29/95 Instrument
Date Received 08/23/95 Column
Date Prepared 08/30/95 Analyst MCL
Date Analyzed 09/02/95 01:09 Reviewer
Spiked
MSD2
Cone. Measurea Concentration
ug/L ug/L
122 61.0 x
244 204
122 86.5
244 224
122 117
244 147
\.lork Order # 9508434
Page .f.L
Reporting Subset_ Matrix H
Spikes Subset _ Report As received
Specs Subset _ 'X Moisture
Specification Limits
Recovery Low tligh
'X 'X 'X
50 43 116
84 60 124
71 45 114
92 28 122
96 66 1'22
60 26 123
.... ' .• c .... ~ .... ............ .. .. ~ ....
09/07/95 10:05:08 CONTINUING(OR DAILY) CALIBRAT~ON WOrk Order # 9508430
Page~ Y E R I F I C A T I 0 N (CClnt'd)
Analysis Batch# HSHSDA50831121100
Initial Calibration# HSDA950503000000
Lab Sample ID VSTDCAL Date Analyzed 09/01/95 10:00:00 Reporting Subset_
Spikes Subset _
Specs Subset _
File # F0831538
Method Volatile Organics S~8260A
Test Code 826~00
Analyte
Oichlorodifluoromethane
1, 1-Dichloroethane
1,2-Dichloroethane
1, 1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
ci~-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethyl methacrylate
Ethylbenzene
2-Hexanone
Iodomethane
'He thy l methacry late
4-Hethyl-2-pentanone(HIBK)
Methylene chloride
Propanenitrile
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,1, 1-Trichloroethane
1, 1,2-Trichloroethane
Measured Reference
concentration Concentration Recovery
ug/L ug/L ~
48.0 50.0 96
53.4 50.0 107
56.7 50.D 113
55.8 50.0 112
49.3 50.0 99
51. 1 '.>0.0 102
59.6 50.0 119
60.7 50.0 121
58.2 50.0 116
60.2 50.b 120
56.6 50.0 113
69. 1 50.0 138
57.5 50.0 115
59.8 50.0 120
61.6 50.0 123
67.1 50.0 134
233 250 93
57.5 50.0 115
55.9 50.0 112
S4.S 50.0 109
S4.4 so.a 109
62,'6 so.a 125
53.6 50.0 107
56.S 50.0 113
58.2 50.0 116
Recovery
Instrument HSDA
Analyst HER
Reviewer ""A'"'PS=----
Spec if i cat ion
Limits
Low High
~ ~
80 120
80 120
80 120
80 120
----
.... .. ......... , ..
09/07/95 10:05:08
Method Vo la ti le Organics S'n'8260A Specification# __ _
Lab Sample ID
Fi le ID
Project Sample
ID/Description Analyte
-.. ..,, ~1111 ......... ) .... •· -·
ANALYTICAL PROTOCOL SUMMARY
COMMENTS/NARRATIVE
Flag Corrrnent/Narrative Corrective Action
\.lork Order f 9508430
Page lL
--.... ,. -.. ........ , .. -... -eai .. -
09/05/95 17:28:27
Report Form
Work Order Summary
Work Order Comments
Flag Definitions
RADIAN ANALYTICAL SERVICES
FPAS REPORT
TABLE OF CONTENTS
Client HAMILTON BEACH
Facility WASHINGTON NC
Client Code HAM BEACH NC
Analytical Batch ID
Protocol Summary for Semivolatiles by SW846
Results Summary
Initial Calibration
Extraction Batch Summary
Analysis Batch Summary MSMSD250901103302
Results
Laboratory Blank Information
Laboratory Control Samples
Matrix Spikes
Calibration Verification
Comments/Narrative
Work Order # 9508434
~.1l
Certified By ---t;P-_-'z'.;'-..,.;•Jil-.,---
Date --------
Pages
From To
1 1
2 2
3 3
4 4
5 6
7 19
20 2D
21 21
22 23
24 27
28 29
30 31
32 41
42 42
-
-· ........ ..... ..
09/05/95 17:28:27
Report RADIAN CORPORATION
To 3200 E. CHAPEL HILL RD.
P. 0. BOX 13000
Attention JIM NARKUNAS
Phone "'"'R""'TP,,_ _________ _
Prepared
By
Radian Analytical Services
14046 Sunmit Dr., Bldg. B.
P. O. Box 201088
Austin, TX 78720-1088
512/244-0855
CSC JALINDSEY
Project Sample ID/
Description
STKPILE
TBLK953699
STKPHE
STKPILE
...... .. , .. .. , ...... ! ....
WORK ORDER SUMMARY
Client Code HAM BEACH NC
Client HAMILTON BEACH
Facility WASHINGTON NC
\.lork ID WASHINGTON.NC
Case # .:.::NA'-'--------
SDG # ""NA""-------
RAS # 50811AJAL
Lab Sample ID Test Code(s)
01A LEACHATE 352SWAOO
827SWATL
CK1SWAOO
02A LEACHATE 352SWAOO
827SWATL
CK1SWAOO
03A LEACHATE MS 352SWAOO
827SWAMS
CK1SWAOO
04A LEACHATE MSD 352SWAOO
827SWAMS
CK1SWAOO
\.lork Order # 9508434
Page _1 _
RCN 650-132-01-02
Method Desciption
Liquid/liq. extract SW3520
Semivolatiles by SW846
Primary KO cone. SW846
Liquid/liq. extract SW3520
Semivolatiles by SW846
Primary KD cone. SW846
Liquid/liq. extract SW3520
Semivolatiles by SW846
Primary KD cone. SW846
Liquid/liq. extract SW3520
Semivolatiles by SW846
Primary KD cone. SW846
-
09/05/95 17:28:27 \I 0 R K 0 R D E R C 0 H H E N T S
The X flag indicates that the analyte did not meet the specified tolerance for
LCS955683 and LCSD955683.
The samples were analyzed at the lowest dilution possible due to the matrix of
a TCLP leachate.
Work Order # 9508434
. Page L
-.............. .. .. (Jim .................. , .... _
-· -... -.. .. .... -... ...... .. -.. -09/05/95 17:28:27 ANALYTICAL PROTOCOL SUMMARY \.lork Order I 9508434
Pagel_
Flag
< DL
NA
NC
ND
NR
NS
B
c
E
F
H
I
J
K
M
p
Q
R
s
T
x
y
z
FLAG DEFINITIONS
Definition
Result less than stated Detection Limit and greater than or equal to zero.
Analyte concentration not available for this analysis.
RPO and/or i Recovery not calculated. See Narrative for explanation.
Not detected. No instrument response for analyte or result less than zero.
Not reported. Result greater than or equal to stated Detection Limit and less than specified Reporting Limit.
Analyte not spiked.
Analyte detected in method blank at concentration greater than the Reporting Limit (and greater than zero).
Confirming data obtained using second GC column or GCMS.
Analyte concentration exceeded calibration range.
Interference or coelution suspected. See Narrative for explanation.
Presence of analyte previously confirmed by historical data.
Analyte identification suspect. See Narrative for explanation.
Result is less than stated Detection Limit but greater than or equal to specified Reporting Limit.
Peak did not meet method identification criteria. Analyte not detected on other GC column.
Result modified from previous Report. See Narrative for explanation.
Analyte not confirmed. Results from primary and secondary GC columQs differ by greater than a factor of 3.
QC result does not meet tolerance in Protocol Specification.
Result reported elsewhere.
Analyte concentration obtained using Method of Standard Addi ti'ons (MSA).
Second column confirmational analysis not performed.
See Narrative for explanation.
See Narrative for explanation.
See Narrative for explanation.
--
·-
09/05/95 17:28:27
Method Semivolatiles by SW8270A
Test Code 827SWATL
Project Sample ID:
Lab ID:
Fi le ID:
Date Collected:
Date Prepared:
Date Analyzed:
Dilution Factor:
Matrix:
Units:
Report as:
Column:
Analyte
Surrogate Cs)
2-Fl uorobi phenyl
2-Fluoropheno l
Nitrobenzene-d5
Phenol-d5
Terphenyl-d14
2,4,6-Tribromophenol
.... ... -
STKPILE
9508434-01A LEACHA
M9695
08/29/95
08/30/95
09/02/95 01:09
5
Water
ug/L
received
Cone. DL
Recovery
%
50 x
84
71
92
96
60
.....
R E S U L T S S U H H A R Y (Cont'd)
Cone. DL Cone.
Recovery Recovery
% %
.. -.. .. ....
DL
Work Order It 9508434
Page.Q_
Cone. DL
Recovery
%
....... .. , ... ·-
-... ..
09/05/95 17:28:27
Sol 'n # 20182-49
Method Semivolatiles by SW846
Test Code 827SWAOO
Analytes
Hexachlorophene
-
.. .. .. .. . .. .. ....
I N I T I A l CALIBRATION
Initial Calibration# MSD2950623084000
Calibration Date 06/23/95 08:40:00
Response Response Response
Factor
Reference Reference Reference
Cone. Cone. Cone.
ug/ml
o. 111
500
Response
Reference
Cone.
_ ........
Response
Reference
Cone.
..
~rk Order I 9508434
Page!.._
Instrument MSD2
Analyst HCL
Reviewer .... co""'z'----
Response
Reference
Cone. -RF
o. 111
'
Specification Limits for .avg. RF of SPCC, system performance check compounds, ~ 0.050(8270); ~ 0.300 (~ 0.250 bromoform, 8240)
.. -
'l RSD
0
•: --..
09/05/95 17:28:27
Sol'n # 20182-45
Method Semivolatiles by SW846
Test Code 827SWAOO
Analytes
Pentachloroethane
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
CCC
Benzyl alcohol
1,2-Dichlorobenzene
bis(2-Chloroisopropyl)ether
2-Methylphenol
N-Nitroso-di-n-propylamine
SPCC
4-Methylphenol/3-Methylphenol
, .... ,_
---
.. , -.. -....
INITIAL C A L I B R A T I 0 N Cont'd
Initial Calibration# MSD2950703111400
Calibration Date 07/03/95 11:14:00
Resporyse Response Response
Factor Factor Factor
Reference Reference Reference
Cone. Cone. Cone.
ug/mL ug/mL ug/mL
0.540 0.545 0.544
20 50 80
1.406 1.425 1.413
20 50 80
1.575 1. 595 1.578
20 50 80
1. 619 1.632 1. 595
20 50 80
0.820 0.845 0.839
20 50 80
1.529 1. 513 1. 503
20 50 80
1.832 1.847 1.829
20 50 80
1.139 1.145 1.132
20 50 80
0.967 0.969 0.953
20 50 80'
1.324 1.319 1.314
20 50 80 .
Response
Factor
Reference
Cone.
ug/mL
0.532
120
1.356
120
1. 512
120
1. 531
120
0.817
120
1.427
120
1.757
120
1.091
120
0.909
120
1.235
120
-.. ....
Response
Factor
Reference
Cone.
ug/mL
0.550
160
1.403
160
1.568
160
1.587
160
0.851
160
1.471
160
1.832
160
1. 148
160
0.938
160
1. 261
160
Work Order # 9508434
Page,2_
Instrument MSD2
Analyst MCL
Reviewer _CD~Z~--
Response
Reference
Cone. -RF
0.542
1.40
1.57
1. 59
0.834
1.49
1.82
1. 13
0.947
1. 29
Specification Limits for avg. RF of SPCC, system performance check compounds, ~ 0.050(8270>: ~ 0.300 C~ 0.250 bromoform, 8240)
.. -
'X RSD
1.24
, 1.88
2.02
2.45
1.82
2.72 ,
1. 96
2.05
2.61
3.11
-.. .. ..
09/05/95 17:28:27
Sol 'n # 20182-45
Method Semivolatiles by SW846
T~st Code 827SWAOO
Analytes
bisC2-Chloroethoxy)methane
13enzoic acid
'
2,4-Dichlorophenol
CCC
Dimethylphenethylamine
1,2,4-Trichlorobenzene
Naphthalene
2,6-Dichlorophenol
Hexachloropropene
p-Chloroani line
Hexachlorobutadiene
CCC
.... -.. -...... _ ....... .. ..
I N I T I A l C A l I B RA T I 0 N Cont'd
Initial Calibration# MSD2950703111400
Calibration Date 07/03/95 11:14:00
Response Response Response
Factor Factor Factor
Reference Reference Reference
Cone. Cone. Cone.
ug/mL ug/mL ug/ml
0.458 0.455 . 0.455
20 50 80
0.156 o. 172 0.194
50 BO 120
0.321 0.327 0.324
20 50 BO
0.914 0.94B 0.926
20 50 BO
0.365 0.358 0.353
20 50 80
1.040 1 .026 1 .022
20 50 BO
0.321 0.319 0.31B
20 50 80
0.206 0.224 0.224
20 50 80
0.466 0.465 0.453
20 50 BO
0.218 0.211 0.208
20 50 80
Response
Factor
Reference
Cone.
ug/ml
0.444
120
0.219
160
0.314
120
0.906
120
0.341
120
0.987
120
0,308
120
0.217
120
0.443
120
0.201
120
Response
Factor
Reference
Cone.
ug/mL
0.457
160
0.321
160
1.024
160
0.347
160
1 .020
160
0.31'6
160
0.226
160
0.452
160
0.201
160
\.lork order # 9508434
Page J.L
Instrument MSD2
Analyst MCL
Reviewer ~C=DZ~--
Response
Reference
Cone. -RF
0.454
o. 185
0.321
0.944
0.353
1.02
0.316
0.219
0.456
0.208
Specification Limits for avg. RF of SPCC, system performance check compounds, ~ 0.050(8270); ~ 0.300 (~ 0.250 bromofonn, 8240)
.. -
l RSD
1.24
14.8
1.50
5.05
2.65
1. 92
1.59
3.75
2. 12
3.46
.. -.. --.. .. .. -_ .. _ ... --........ _
09/05/95 17:28:27
Sol 'n # 20182-45
Method Semivolatiles by SW846
Test Code 827SWA00
Analytes
1,4-Naphthoquinone
2-Nitroaniline
Dimethylphthalate
1,3-Dinitrobenzene
Acenaphthylene
2,6-Dinitrotoluene
3-Ni troani line
Oibenzofuran
Pentachlorobenzene
2,4-Dinitrotoluene
I N I T I A l C A L I B R A T I 0 N Cont'd
Initial Calibration# MSD2950703111400
Calibration Date 07/03/95 11:14:00
Response Response Response
Factor Factor Factor
Reference Reference Reference
Cone. Cone. Cone.
ug/ml ug/ml ug/ml
0.472 0.450 0.424
20 50 80
0.428 0.454 0.447
20 50 80
1.503 1. 512 1.470
20 50 80
0.222 0.244 0.244
20 50 80
1.964 1.972 1. 926
20 50 80
0.327 0.342 0.336
20 50 80
0.359 0.375 0.371
20 50 80
1.661 1.676 1.633
20 50 80
0.578 0.567 0.543
20 50 80
0.445 0.472 0.462
20 50 80
Response
Factor
Reference
Cone.
ug/ml
0.396
120
0.447
120
1.427
120
0.241·
120
1.877
120
0.331
120
0.367
120
1. 595
120
0.520
120
0.452
120
Response
Factor
Reference
Cone.
ug/ml
0.366
160
0.472
160
1.470
160
0.256
160
1.917
160
0.341
160
0.391
160
1.639
160
D.530
160
0.466
160
Specification Li~its for avg. RF of SPCC, system performance check compounds, ~ 0.050(8270); ~ 0.300 (~ 0.250 bromoform, 8240)
Work Order # 9508434
Page .1L
Instrument MSD2
Analyst MCL
Reviewer .:::C~DZ:.._ __
Response
Reference
Cone. -RF
0.422
0.450
1.48
0.241
1.93
0.335
0.373
1.64
0.548
0.459
l RSD
9.99
3.52
2.27
5.99
1.99
1.92
3.18
1.88
4.47
2.36
--.. -09/05/95 17:28:27
Sol 'n # 20182-45
Method Semivolatiles by 5~846
Test Code 827S~A00
Analytes
4-Nitroaniline
4,6-Dinitro-2-methylphenol
Diphenylamine/N-NitrosoDPA
CCC
4-Bromophenylphenyl ether
Phenacetin
Hexachlorobenzene
4-Aminobiphenyl
Pentachlorophenol
CCC
Pentachloronitrobenzene
Pronamide
--.. .. - - --·---.. -·-I N I T I A l CA l I B R A T I 0 N Qint'd
Initial Calibration# MSD2950703111400
Calibration Date 07/03/95 11:14:00
Respo~se Response Response
Factor Factor Factor
Reference Reference Reference
Cone. Cone. Cone.
ug/ml ug/mL ug/ml
0.359 0.378 0.367
20 50 80
0.113 o. 144 0.148
20 50 80
0.667 0.675 0.660
40 100 160
0.251 0.243 o. 241
20 50. 80
0.513 0.538 0.539
20 50 80
0.310 0.301 0.300
20 50 80
0.766 0.818 0.817
20 50 80
o. 171 0.190 0.199
20 50 80
0.0527 0.0507 0.0519
20 50 80.
0.368 0.370 0.370
20 50 80
Response
Factor
Reference
Cone.
ug/ml
0.362
120
o. 152
120
0.647
240
0.234
120
0.532
120
0.288
120
0.809
120
0.193
120
0.0510
120
0.360
120
Response
Factor
Reference
Cone.
ug/mL
0.378
160
o. 167
160
0.696
320
0.244
160
0.563
160
0.298
160
0.834
160
0.204
160
0.0528
160
0.372
160
Work Order # 9508434
Page .12_
Instrument •MSD2
Analyst MCL
Reviewer _c_oz __ _
Response
Reference
Cone. -RF
0.369
0.145
0.669
0.243
0.537
0.299
0.809
o. 191
0.0518
0.368
Specification Limits for avg. RF of SPCC, system performance check compounds, ~ 0.050(8270>; ~ 0,300 (~ 0.250 bromoform, 8240)
... _
i RSD
2.41
. 13. 7
2.73
2.52
3.33
2.63
3.16
6.59
1.85
1.27
09/05/95 17:28:27 EXTRACTION BATCH SUMMARY
Extraction Batch# 3520950830111500
Method Liquid/liq. extract S\.13520
Test Code 352S~AOO
Extraction Start Date/Time 08/30/95 11:15:00
Extraction Stop Date/Time 09/01/95 08:05:00
Sample Project Sample ID Lab Sample ID
1 STKPILE 9508434-01A
2 TBLK953699 9508434-02A
3 9508511-0lA
4 9508511-02A
5 9508514-01A
6 9508514-02A
7 9508514-03A
8 9508514-04A
9 9508514-05A
10 9508514-06A
11 9508514-09A
12 9508514-lOA
13 9508514-11A
14 9508514-12A
15 9508514-13A
16
17
18
19
20
Quality Control Project Sample ID Lab Sample ID
Blank BLK953709
Laboratory Control Sample LCS955683
Laboratory Control Sample Duplicate LCSD955683
Matrix Spike STKPILE 9508434-03A
Matrix Spike Duplicate STKPILE 9508434-04A
Matrix Spike 9508514-07A
Matrix Spike Duplicate 9508514-0BA
Work Order # 9508434
Page £Q_ ·
Analyst RJB
Reviewer --------
Sample Size
ml Cleanup Method
820
940
910
990
990
1020
840
980
1010
1000
970
980
980
1020
1010
Sample Size
ml Cleanup Method
1000
1000 '
1000
840
850 '
1020
1000 I
I -:-.. - - - -.. - - - _ .... - - -..... -
------------~-~----09/05/95 17:28:27
Lab Sample ID BLK953709
File# M9677 ------Method Semivolatiles by S~8270A
Test Code 827S~ATL
Surrogate ls)
2-Fluorobi phenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d5
Terphenyl-d14
2,4,6-Tribromophenol
L A B 0 R A T 0 R Y B L A N K I N F 0 R M A T I 0 N (cont'd) ~ork Order # 9508434
Page l2_
Extraction Batch# 3520950830111500
Analysis Batch# MSMSD250901103300
Date Prepared 08/30/95
Date Analyzed 09/01/95 14:02
Spiked
Cone.
ug/L
100
200
100
200
100
200
Instrument MSD2
Column ___ _
Analyst MCL
Reviewer
Measured Cone.
ug/L
29.4
177
83.5
206
105
181
Reporting Subset _
Spikes Subset _
Specs Subset _
Matrix H
Specification Limits
Recovery Low High
% % %
29 Q 43 116
88 60 124
84 45 114
103 28 122
105 66 122
90 26 123
- - - - -09/05/95 17:28:27
Lab Sample ID 9508434-02A LEACHA
Fi le # ~M9'"""'6""'"9"""8 ___ _
Method Semivolatiles by SW8270A
Test Code 827SWATL
Surrogate Cs)
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d5
Terphenyl-d14
2,4,6-Tribromophenol
------------
L A 8 0 R A T 0 R Y 8 L A N K I N F 0 R M A T I 0 N (C01t'd) Work Order # 9508434
Page 'fl_
Extraction Batch# 3520950830111500
Analysis Batch # MSMS0250901103302
TCLP Batch # TCTCLP508281645
Date Prepared 08/30/95 Instrument MSD2
Date Analyzed 09/02/95 03:04
Spiked
Cone.
ug/L
106
213
106
213
106
213
Column ___ _
Analyst 119.
Reviewer
Measured Cone.
ug/L
45.7 x
177
78.1
197
104
28.0
Reporting Subset_
Spikes Subset_
Specs Subset_
Matrix H
Specification Limits
Recovery Low High
'X 'X 'X
43 43 116
83 60 124
74 45 114
92 28 122
98 66 122
13 Q 26 123
---
09/05/95 17:28:27
Method Semivolatiles by S~8270A
Test Code 827S~ATL
Control Std. # Vol. Added
SP-1-681 .lQQ_ !!!:.___
SP-1-682 £2.Q__ !!!:.___
----
Analyte
1,4-Dichlorobenzene
2,4-Dinitrotoluene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
4-Methylphenol/3-Methylphenol
2-Methylphenol
Nitrobenzene
Pentachlorophenol
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Surrogate(s)
, 2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d5
Terphenyl-d14
2,4,6-Tribromophenol
-·---
LABORATORY CONTROL SAMPLE
Extraction Batch # 3520950623123500
Work Order # 9508434
Page£!!..
Analysis Batch # MSMSD250901103300
Date Prepared 06/23/95
Date Analyzed 09/01/95 11:33
Instrument MSD2
Column ----Analyst MCL
Reporting Subset _ _ Matrix !:{
Spikes Subset __ Report As received'
Specs Subset _ _ 'X Moisture
Reviewer Aliquot Mass or Vol
Extract Mass or Vol
----'-1 o=o=o !mU
__ 1~·-0 (ml)
Surrogate Sol'n # Vol. Added LCS LCS Duplicate Recovery
SP-1-606 .lQQ_ !!!:.___ Lab Sample ID Lab Sample ID Spec.
LCS954261 Limits ' RPO ----File ID M9674 File ID ----
Spiked Measured Spiked Measured Spec.
Cone. Cone. Rec. Cone. Cone. Rec. Low High Result Limit
ug/L ug/L % ug/L ug/L % % % % %
100 94.7 95 55 119
100 101 101 61 123
100 96.3 96 54 138
100 97.4 97 54 128
100 90.0 90 61 121
100 82.9 83 20 135
100 93.4 93 29 133
100 99. 1 99 52 129
100 106 106 22 124
100 101 101 37 121
100 102 102 48 104
100 43.8 44 43 116
200 197 98 60 124
100 99.4 99 45 114
200 228 114 28 122
100 115 115 66 122
200 199 100 26 123
-------------- -
- -- -
09/05/95 17:28:27
Method Semivolatiles by SW8270A
Test Code 827SWATL
Control Std. # Vol. Added
SP-1-687 .1.QQ_~
SP-1-688 250 ~
----
Analyte
-1,4-Dichlorobenzene
2,4-Dinitrotoluene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
4-Methylphenol/3-Methylphenol
2-Methylphenol
Nitrobenzene
Pentachlorophenol
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Surrogate(s)
2-Fluorobiphenyl
2-Fl uoropheno l
Nitrobenzene-d5
Phenol-d5
Terphenyl-d14
2,4,6-Tribromophenol
---________ .. _
LABORATORY CONTROL SAMPLE
Extraction Batch# 3520950830111500
Analysis Batch# MSMSD250901103300
Work Order # 9508434
Page l2._
Date Prepared 08/30/95 Instrument MSD2 Reporting Subset _ _ Matrix H
Date Analyzed 09/01/95 13:23 Column ___ _ Spikes Subset __ Report As received
Specs Subset__ % Moisture
-
Analyst MCL
Reviewer Aliquot Mass or Vol
Extract Mass or Vol
---'-1 o=o=o emu
--~1.~0 (ml)
Surrogate Sol'n # Vol. Added LCS LCS Duplicate Recovery
SP-1-606 .1.QQ_~ Lab Sample ID Lab Sample ID Spec.
LCS955683 LCSD955683 Limits RPO ----File ID M9675 File ID M9676 ----
Spiked Measured Spiked Measured Spec.
Cone. Cone. Rec. Cone. Cone. Rec. Low High Result Limit
ug/L ug/L % ug/L ug/L % % % % %
100 100 100 100 93.3 93 55 119 ' 7.2 21
100 118 118 100 109 109 61 123 7.9 17
100 112 112 100 103 103 54 138 8.4 18
100 101 101 100 95.8 96 54 128 5. 1 62
100 96.7 97 100 89.6 90 61 121 7.5 23
100 83.8 84 100 78.1 78 20 135 7.4 50
100 93.6 94 100 87.6 88 29 133 6.6 40
100 106 106 100 99.4 99 52 129 6.8 20
100 107 107 100 95.6 96 22 124 11 26
190 108 108 100 99.8 100 37 121 7.7 62
100 104 104 100 96.7 97 48 104 7.0 17
I
100 29.7 30 a 100 30.6 31 a 43 116
200 172 86 200 159 79 60 124
100 82.2 82 100 78.3 78 45 114
200 200 100 200 186 93 28 122 I
I 100 104 104 100 95.4 95 66 122
200 179 89 200 169 85 26 123
-
09/05/95 17:28:27 "ATRII SPIKE(S)
Extraction Batch# 3520950830111500
Analysis Batch # MSMS0250901103302
TCLP Batch # TCTCLP508281645
\.lork Order # 9508434
Page 1Q_
Project Sample ID _S_TK_P_I_L_E ______ _ Date Collected 08/29/95 Instrument MSD2 Reporting Subset _ _ Matrix !t
Method Semivolatiles by S~8270A
Test Code 827S~AMS
Spike Sol 'n # Vol, Added
SP-1-592 .1QQ_ 111_
SP-1-593 .1QQ_ 111_
----Surrogate Sol 'n Vol. Added
SP-1-606 .1QQ_ 111_
----
----
Spike
Sol 'n
Analyte Cone.
ug/ml
Acenaphthene 1000
4-Chloro-3-methylphenol 2000
2-Chlorophenol 2000
1,4-Dichlorobenzene 1000
2,4-Dinitrotoluene 1000
N-Nitroso-di-n-propylamine 1000
4-Nitrophenol 2000
Pentachlorophenol 2000
Phenol 2000
Pyrene 1000
1,2,4-Trichlorobenzene 1000
- - - - -
Date Received 08/23/95 Column ___ _ Spikes Subset__ Report As received
Specs Subset__ % Moisture Date Prepared 08/30/95 Analyst MCL
Date Analyzed 09/02/95 02:25 Reviewer
Sample Spiked Sample Spiked Sample Dup
Lab Sample ID Lab Sample ID Lab Sample ID
9508434-01A LEACHA 9508434-03A LEACHA 9508434-04A LEACHA
File# M9695 Fi le # M9696 File II M9697
Aliquot Mass/Vol Aliquot Mass/Vol Aliquot Mass/Vol
820 CmLJ 840 CmLJ 850 (ml) Recovery
Extract Mass/Vol Extract Mass/Vol Extract Mass/Vol Spedfi-
1.0 (ml) 1.0 (ml) 1.0 CmU cation
Di l Fact; 5 Di l Fact. 5 Di l Fact. 5 Limits ' RPO
Specifi-
Measured Spiked Measured Spiked Measured cation
Cone. Cone. Cone. Rec. Cone. Cone. Rec. Low High Result Limit
ug/L ug/L ug/L % ug/L ug/L % % % % %
'
ND 119 108 90 118 105 89 65 109 1.1 16
ND 238 190 80 235 178 76 59 129 5. 1 20
ND 238 215 90 235 207 BB 62 118 2.2 22
ND 119 98.0 82 118 97.5 83 55 119 1.2 21
ND 119 6 ... 6 54 Q 118 59. 1 50 Q 61 123 7.7 17
ND 119 102 86 118 99.7 85 56 118 1.2 17
ND 238 72.7 31 235 45.6 19 Q 26 132 48 Q 21
ND 238 99.3 42 235 67.3 29 22 124 37 Q 26
ND 238 184 77 235 177 75 63 129 2.6 18
ND 119 115 96 118 108 92 65 115 4.3 17
ND 119 107 90 118 100 85 65 121 5.7 19
------------- -
-- - - -- -09/05/95 17:28:27 -_______ .. -
MAT.RIX SPIKE ( S) (Cont'd)
Extraction Batch# 3520950830111500
Analysis Batch# MSMSD250901103302
TCLP Batch # TCTCLP508281645
\.lork Order # 9508434
Page lL
-
Project Sample ID _ST_K_P_I_LE _______ _ Date Collected 08/29/95
Date Received 08/23/95
Date Prepared 08/30/95
Instrument MSD2
Column
Reporting Subset _ _ Matrix !{
Method Semivolatiles by S~8270A
Test Code 827S~AMS
Spike Sol 'n # Vol. Added
SP-1-592 1QQ_ Yb_
SP-1-593 1QQ_ Yb_
----Surrogate Sol' n Vol. Added
SP-1-606 1QQ_ Yb_
----
----
Spike
Sol 'n
Analyte Cone.
ug/mL
Surrogate Cs)
2-Fluorobi phenyl 1000
2-Fluoropheno l 2000
Nitrobenzene-d5 1000
Phenol-d5 2000
Terphenyl-d14 1000
2,4,6-Tribromophenol 2000
----Spikes Subset__ Report As received
Specs Subset _ _ X Moisture Analyst MCL
Date Analyzed 09/02/95 02:25 Reviewer
Sample Spiked Sample Spiked Sample Dup
Lab Sample ID Lab sample ID Lab Sample ID
9508434-0lA LEACHA 9508434-03A LEACHA 9508434-04A LEACHA
File# M9695 File# M9696 File II M9697
Aliquot Mass/Vol Aliquot Mass/Vol Aliquot Mass/Vol
820 (ml) 840 (ml) 850 . (ml) Recovery
Extract Mass/Vol Extract Mass/Vol Extract Mass/Vol Specifi-
1.0 (ml) 1.0 (ml) 1.0 (ml) cation
Di l Fact. 5 Di l Fact. 5 Di l Fact. 5 Limits RPD
Speci fi-
Measured Spiked Measured Spiked Measured cation
Cone. Cone. Cone. Rec. Cone. Cone. Rec. Low High Result Limit
ug/L ug/L ug/L x Ug/L ug/L x ·x x ' x x
61.0 x. 119 85.4 x 72 118 67. 1 x 57 43 116 '
204 238 201 85 235 196 83 60 124
86.5 119 95.7 80 118 90.1 77 45 114
224 238 228 96 235 221 94 28 122
117 119 118 99 118 116 98 66 122
147 238 175 74 235 179 76 26 123
-
-
09/05/95 17:28:27 c·o NT I Nu ING ( 0 R 0 A I Ly) c AL I BR AT I 0 N Work Order I 9508434
Page.R
-
Lab Sample ID SSTD050
Fi le # .:.:M.:;..:96::..:.7..::3 ___ _
Method Semivolatiles by SW8270A
Test Code 827SWAOO
Analyte
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Aniline
Anthracene
Benz(a)anthracene
Benz(a)pyrene
Benzi dine
Benzo(blfluoranthene
Benzo(g,h,i)perylene
Benzo(klfluoranthene
Benzoic acid
Benzyl alcohol
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methylphenol
p-Chloroaniline
Chlorobenzi late
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl)ether
bisC2-Chloroisopropyl)ether
2-Chloronaphthalene
2-Chlorophenol
----
VERIFICATION
Analysis Batch# MSMSD250901103300
Initial Calibration# MSD2950703111400
Date Analyzed 09/01/95 10:54
Measured Reference
Concentration Concentration
ug/mL ug/mL
47.8 50.0
48.3 50.0
47.5 50.0
47.0 50.0
44.6 50.0
47. 1 50.0
49.6 50.0
49.2 5o.n
49.6 50.0
30.8 50.0
44.9 50.0
47.1 50.0
46.5 50.0
32. 1 50.0
47.8 50.0
52.3 50.0
47.4 50.0
48.9 50.0
49.4 50.0
48.5 50.0
50.9 50.0
49.7 50.0
48.3 50.0
47.6 50.0
48.8 50.0
Reporting Subset _
Spikes Subset_
Specs Subset_
Recovery
~
96
97
95
94
89
94
99
98
99
62
90
94
93
64
96
105
95
98
99
97
102
99
97
95
98
Instrument MSD2
. Analyst MCL
Reviewer
Recovery
Specification
Limits
Low High
t ~
70 130
70 130
70 130
-- -----------
-- ---- --_______ .. --
09/05/95 17:28:27 CONTINUING(OR DAILY) CALIBRATION \.lork Order # 9508434
Page TI_ V E R I F I C A T I 0 N (Cont'd)
Analysis Batch# MSMSD250901103300
Initial Calibration# MSD2950703111400
Lab Sample ID SSJD050 Date Analyzed 09/01/95 10:54 Reporting Subset _
Spikes Subset _
Specs Subset _
Fi le # :..;Mc:..:96,,_,7..::3c__ ___ _
Method Semivolatiles by SW8270A
Test Code 827SWA00
Analyte
4-Chlorophenylphenyl ether
Chrysene
Di-n-butylphthalate
Di-n-octylphthalate
Dial late
Dibenz(a,h)anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
2,4-Dichlorophenol
2,6-Dichlorophenol
Diethylphthalate
p-Dimethylaminoazobenzene
7, 12-Dimethylbenz(a)anthracene
3,3'-Dimethylbenzidine
Dimethylphenethylamine
2,4-Dimethylphenol
Dimethylphthalate
4,6-Dinitro-2-methylphenol
1,3-Dinitrobenzene
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Measured Reference
Concentration Concentration Recovery
ug/mL ug/mL ~
49. 1 50.0 98
49.4 50.0 99
48.5 50.0 97
47.3 50.0 95
49.4 50.0 99
47.1 50.0 94
48.7 50.0 97
48.3 50.0 96
48.7 50.0 98
48.7 50.0 98
46.6 50.0 93
50.2 50.0 100
49.6 50.0 99
46.9 50.0 94
47.6 50.0 95
51.0 50.0 102
44.7 50.0 89
49.3 J 50.0 99
48.5 50.0 97
48.3 50.0 97
54.3 50.0 109
52.2 50.0 104
44.7 50.0 89
50.8 50.0 102
51.5 50.0 103
Instrument MSD2
Analyst MCL
Reviewer
Recovery
Specification
Limits
Low High
~ ~
70 130
70 130
70 130
-
-
09/05/95 17:28:27 CONTINUING(OR DAILY) CALIBRATION Work Order # 9508434
Page li_
-
V E R I F I C A T I 0 N Cc.mt 'd)
Analysis Batch# MSMSD250901103300
Initial Calibration# MSD2950703111400
Lab Sample ID SSTD050 Date Analyzed 09/01/95 10:54 Reporting Subset_
Spikes Subset _
Specs Subset _
Instrument MSD2
Analyst MCL
Reviewer
File# .:..:M~96:..:.7..::;3 ___ _
Method Semivolatiles by SW8270A
Test Code 827SWAOO
Analyte
Diphenylamine/N-NitrosoDPA
Ethyl methanesulfonate
bis(2-Ethylhexyllphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Hexachlorophene
Hexachloropropene
Indeno(1,2,3-cdlpyrene
Isophorone
Isosaf role
Methapyrilene
Methyl methanesulfonate
3-Methylcholanthrene
2-Methylnaphthalene
4-Methylphenol/3-Methylphenol
2-Methylphenol
N-Nitroso-di-n-butylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiethylamine
N-Nitrosodimethylamine
N-Nitrosomethylethylamine
•
- ----
Measured
Concentration
ug/mL
102
49.6
46.6
49.0
48.9
52. 1
50.1
32.6
47.0
ND
46.0
48.2
49.3
47.7
47.0 J
49.7 J
47.6
49.8
47.5
48.9
50.4
48.0
51. 2
46.0
51.8 ,-
Recovery
Specification
Limits
Reference
Concentration Recovery Low High
ug/mL ~ i %
100 102 70 130
50.0 99
50.0 93
50.0 98 70 130
50.0 98
50.0 104
50.0 100 70 130
50.0 65
50.0 94
50.0 NC
50.0 92
50.0 96
50.0 98
50.0 95
50.0 94
50.0 99
50.0 95
50.0 100
50.0 95
50.0 98
50.0 101
50.0 96
50.0 102
50.0 92
50.0 104
--·---------
-- ----09/05/95 17:28:27
Lab Sample ID SSTD050
File# .:..:M.:;...;96:;.;.7..:.3 ___ _
Method Semivolatiles by SW8270A
Test Code 827SWA00
Analyte
N-Nitrosomorpholine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
Naphthalene
1,4-Naphthoquinone
1-Naphthylamine
2-Naphthylamine
5-Nitro-o-toluidine
2-Ni troani line
3-Ni troani Line
4-Ni troani Line
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
4-Nitroquinoline-1-oxide
Pentachlorobenzene
Pentachloroethane
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
p-Phenylenediamine
2-Picol ine
Pronamide
----- - - - --·-
C 0 N T I N U I N G ( 0 R D A I L Y ) C A L I B R A T I O N
V E R I F I C A T I 0 N (Cont'd)
Work Order # 9508434
Page .22.._
Analysis Batch# MSMSD250901103300
Initial Ca~ibration # MSD2950703111400
Date Analyzed 09/01/95 10:54
Measured Reference
Concentration Concentration
ug/ml ug/mL
49. 1 50.0
49.3 50.0
50.4 50.0
50.2 50.0
45.4 50.0
48.4 50.0
45.7 50.0
49.8 50.0
47.6 50.0
49.0 50.0
49.0 50.0
49.7 50.0
51.4 50.0
43.0 50.0
41. 1 50.0
51.0 50.0
50.0 50.0
52.5 50.0
51.8 50.0
48.5 50.0
48.8 50.0
45.0 50.0
51.8 J 50.0
50.4 50.0
48.3 50.0
Reporting Subset _
Spikes Subset
Specs Subset_·
. Recovery
i
98
99
101
100
91
97
92
100
95
98
98
99
103
86
82
102
10D
105
104
97
98
90
104
101
97
Instrument MSD2
Analyst MCL
Reviewer
Recovery
Spec~fication
Li mi ts
Low High·
i i
70 130
70 130
70 130
--
-
09/05/95 17:28:27 CONTINUING(OR DAILY) CALIBRATION
V E R I F I C A T I 0 N (Cont'd)
Analysis Batch# MSMSD250901103300
Initial Calibration# MS02950703111400
\./ork Order # 9S08434
Page .li_
Lab Sample ID SSTD050 Date Analyzed 09/01/95 10:54 Reporting Subset_
Spikes Subset _
Specs Subset_
Instrument MSD2
Analyst MCL
Reviewer
-
Fi le # .:..oM9=-=6:..:.7..:::.3 ___ _
Method Semivolatiles by SW8270A
Test Code 827S~A00
Analyte
Pyrene
Pyridine
Sa fro le
1,2,4,5-Tetrachlorobenzene
2,3,4,6-Tetrachlorophenol
o-Toluidine
1,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
sym-Trinitrobenzene
Surrogate Cs)
2-Fluorobiphenyl
2-Fluorophenol .
Nitrobenzene-dS
Phenol-dS
Terphenyl-d14
2,4,6-Tribromophenol
--- --
Recovery
Specification
Limits
Measured Reference
Concentration Concentration Recovery Low High
ug/mL ug/mL " " "
50.3 50.0 101
51.6 so.a 103
47.7 50.0 95
51.2 50.0 102
49.6 50.0 99
47.0 50.0 94
51.2 50.0 102
50.0 50.0 100
50.7 50.0 101 70 130
47.5 so.o 9S
49.2 so.o 98
101 100 101
so. 1 so.o 100
98.3 100 98
48.7 so.a 97
100 100 100
------------
------
09/05/95 17:28:27
Lab Sample ID SSTD050
Fi le # ""'M.:...;96""'8:..:.1 ___ _
Method Semivolatiles by S\./8270A
Test Code 827SWA00
Analyte
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Aniline
Anthracene
Benz(alanthracene
Benz(alpyrene
Benzidine
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(klfluoranthene
Benzoic acid
Benzyl alcohol
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methylphenol
p-Chloroani line
Chlorobenzilate
bis(2-Chloroethoxylmethane
bisC2-Chloroethyl)ether
----- - - - --·-
CONTINUING(OR DAILY) CALIBRATION Work Order # 9508434
Page IL VERIFICATION
Analysis Ba.tch # MSMSD250901103300
Initial Calibration# MSD2950703111400
Date Analyzed 09/01/95 16:15
Measured Reference
!=oncentration Concentration
ug/ml ug/ml
49.2 50.0
48.9 50.0
49.0 50.0
48.2 50.0
45.3 50.0
46.0 50.0
48.8 50.0
49.4 50.0
50.6 50.0
35.2 50.0
48.0 50.0
48.0 50.0
44.3 50.0
26.6 50.0
49.3 50.0
50.2 50.0
49.2 50.0
48.7 50.0
49.7 50.0
49.2 50.0
49.8 50.0
51.7 50.0
Reporting Subset _
Spikes Subset_
Specs Subset _
Recovery
x
98
98
98
96
91
92
98
99
101
70
96
96
89
53
99
100
98
97
100
98
100
103
Instrument MSD2
Analyst MCL
Reviewer
Recovery
Specification
Limits
Low High
x x
70 130
70 130
70 130
bis(2-Chloroisopropyl)ether 47.2 50.0 94
2-Chloronaphthalene 48.7 50.0 97
2-Chlorophenol 50.6 50.0 101
--
-
09/05/95 17:28:27
Lab Sample ID SSTD050
Fi le # .;..;M.;..;96=8'-'"1 ___ _
Method Semivolatiles by SW8270A
Test Code 827SWA00
Analyte
4-Chlorophenylphenyl ether
Chrysene
Di-n-butylphthalate
Di-n-octylphthalate
Di all ate
Dibenz(a,hlanthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
2,4-Dichlorophenol
2,6-Dichlorophenol
Diethylphthalate
p-Dimethytaminoazobenzene
C 0 N T I N U I N G ( 0 R D A I L Y ) C A L I B R A T I 0 N
V E R I F I C A T I 0 N (Ccnt'dJ
\./ork Order # 9508434
Page. ML
Analysis Batch# MSMSD250901103300
Initial Calibration# MSD2950703111400
Date Analyzed 09/01/95 16:15
Measured Reference
Concentration Conc-'?ntration
ug/mL ug/mL
48.8 50.0
50.0 50.0
48.3 50.0
49.1 50.0
47.9 50.0
48.2 50.0
49.1 50.0
49.9 50.0
49.5 50.0
50.7 50.0
47.9 50.0
49.6 50.0
50.2 50.0
47.7 50.0
48.3 50.0
Reporting Subset_
Spikes Subset _
Specs Subset _
Recovery
"
98
100
96
98
96
96
98
100
99
101
96
99
100
95
97
Recovery
Instrument MSD2
Analyst MCL
Reviewer
Specification
Limits
Low High
" ~
70 130
70 130
70 130
7,12-Dimethylbenz(a)anthracene 51. 1 50.0 102
3,3'-Dimethylbenzidine 45.6 50.0 91
Dimethylphenethylamine 47.2 J 50.0 94
2,4-Dimethylphenol 48.2 50.0 96
Dimethylphthalate 48.8 50.0 98
4,6-Dinitro-2-methylphenol 52.0 50.0 104
1,3-Dinitrobenzene 51.3 50.0 103
2,4-Dinitrophenol 43.7 50.0 87
2,4-Dinitrotoluene 50.5 50.0 101
2,6-Dinitrototuene 51.8 50.0 104
- -----------------
----- -09/05/95 17:28:27
Lab Sample ID SSTD050
Fi le # ~M9~6~8_,_1 ___ _
Method Semivolatiles by SW8270A
Test Code 827SWA00
Analyte
Diphenylamine/N-NitrosoDPA
Ethyl methanesulfonate
bis(2-Ethylhexyl)phthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Hexachlorophene
Hexachloropropene
Indeno(1,2,3-cd)pyrene
Isophorone
Isosafrole
Methapyrilene
Methyl methanesulfonate
3-Methylcholanthrene
2-Methylnaphthalene
-----------
CONTINUING(OR DAILY) CALIBRATION \.lork Order # 9508434
Page~ V E R I F I C A T I 0 N (Coot'd)
Analysis Batch# MSMSD250901103300
Initial Calibration# MSD2950703111400
Date Analyzed 09/01/95 16:15
Measured Reference
Concentration Concentration
ug/mL ug/mL
100 100
49.9 50.0
48.5 50.0
48.6 50.0
49.9 50.0
50.4 50.0
48.5 50.0
31.6 50.0.
48.2 50.0·
ND 50.0
44.2 50.0
49.8 50.0
49.0 50.0
48.5 50.0
46.5 J 50.0
49.9 J 50.0
48.3 50.0
50.2 50.0
Reporting Subset_
Spikes Subset _
Specs Subset _
Recovery
t
100
100
97
97
100
101
97
63
96
NC
88
100
98
97
93
100
97
100
Instrument MSD2
Analyst MCL
Reviewer
Recovery
Specification
Limits
Low High
t t
70 130
70 130
70 130
4-Methylphenol/3-Methylphenol 48.4 50.0 97
2-Methylphenol 50. 1 50.0 100
N-Nitroso-di-n-butylamine 48.6 50.0 97
N-Nitroso-di-n-propylamine 48.9 50.0 98
N-Nitrosodiethylamine 50.3 50.0 101
N-Nitrosodimethylamine 45.7 50.0 92
N-Nitrosomethylethylamine 50.5 50.0 101
--
-
09/05/95 17:28:27
-
Lab Sample ID SSTD050
Fi le tt ;..;M9;..;6;;.;;8:..:..1 ___ _
Method Semivolatiles by S\.18270A
Test Code 827SWA00
Analyte
N-Nitrosomorpholine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
Naphthalene
1,4-Naphthoquinone
1-Naphthylamine
2-Naphthylamine
S-Nitro-o-toluidine
2-Ni troani line
3-Nitroani line
4-Nitroaniline
Nitrobenzene
2-Ni trophenol
4-Nitrophenol
4-Nitroquinoline-1-oxide
Pentachlorobenzene
Pentachloroethane
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
p-Phenylenediamine
2-Picol ine
Pronamide
-- - -
CONTINUING(OR DAILY) CALIBRATION Work Order I 95a8434
Page~ V E R I F I CA T I 0 N (COOt'd)
Analysis Batch I MSMSD250901103300
Initial Calibration# MSD2950703111400
Date Analyzed a9/01/95 16:15
Measured Reference
Concentration Concentration
ug/ml ug/ml
48.9 50.0
47.1 50.0
51.D 50.0
49.7 5a.o
46.5 sa.o
49.9 so.a
48.0 so.a
S0.8 so.a
47.4 50.0
sa.7 so.a
49.0 so.a
48.6 so.a
S0.4 so.a
4S.O so.a
43.8 so.a
49.7 so.a
S0.6 so.a
S1. 1 so.a
49.4 so.a
48.2 so.a
49.6 sa.o
4S.7 so.a
34.8 J 50.0
50.4 so.a
47.8 so.a
Reporting Subset_
Spikes Subset_
Specs Subset_
Recovery
'1.
98
94
102
99
93
100
96
102
9S
101
98
97
101
90
88
99
101
102
99
96
99
92
7a
101
96
Instrument MSD2
Analyst MCL
Reviewer
Recovery
Specification
Limits
Low High
'1. '1.
70 13a
7a 130
70 130
-- -----------
--- ---09/05/95 17:28:27
Lab Sample ID SSTD050
File# ""M9'"""'6""'8'"'"1 ___ _
Method Semivolatiles by SW8270A
Test Code 827SWAOO
Analyte
Pyrene
Pyridine
Sa fro le
1,2,4,S-Tetrachlorobenzene
2,3,4,6-Tetrachlorophenol
o-Toluidine
1,2,4-Trichlorobenzene
2,4,S-Trichlorophenol
2,4,6-Trichl~rophenol
sym-Trinitrobenzene
Surrogate Cs)
2-.fluorobiphenyl
2-Fluorophenol
Nitrobenzene-dS
Phenol-dS
Terphenyl-d14
2,4,6-Tribromophenol
---.--------CONTINUING(OR DAILY) CALIBRATION Work Order # 9S08434
Page~ V E R I F I C A T I 0 N (Cont'd)
Analysis Batch# MSMS0250901103300
Initial Calibration# MSD2950703111400
Date Analyzed 09/01/95 16:15
Measured Reference
Concentration Concentration
ug/ml ug/ml
so. 1 so.a
S1.4 so.a
48.4 so.a
so.s so.a
48.9 so.a
49.8 so.a
S0.3 so.a
S0.3 so.a
49.9 so.a
48.8 so.a
49.8 so.a
102 100
49.0 so.a
100 100
49.3 so.a
99.4 100
Reporting Subset _
Spikes Subset _
Specs Subset _
Recovery
,;
100
103
97
101
98
100
101
101
100
98
100
102
98
100
99
99
Instrument MSD2
Analyst MCL
Reviewer
Recovery
Specification
Limits
Low High
,; ,;
70 130
--
09/05/95 17:28:27
Method Semivolatiles by SW846 Specification# 827S
Lab Sample ID
Fi le ID
LCSD955683
M9676
--
Project Sample
ID/Description Analyte
2-Fluorobiphenyl
- --- -
ANALYTICAL PROTOCOL SUMMARY
COMMENTS/NARRATIVE
Flag Conment/Narrative
Q The recoveries for this analyte did not meet
the specified tolerance for the LCS/LCSD.
Sample results for this analyte were flagged
with an X.
Corrective Action
Work Order I 9508434
Page _iL
A third LCS (LCS954261l was analyzed and the
recovery for this analyte was within the
specified tolerance.
-----·-------
I
IER # 950901-06
QUALITY.CONTROL EXCEPTION.REPORT
LEVEL 2 -ANALYTICAL
REPORT COPY 9508434
Revised: 09/05/95
Analyst: CAROL LOVETT Instrument: =m=s=d~#~2"--~~ Date Analyzed: 09/01/95
Status: ~
'
Batch #: MSD2950901103300 Matrix: liquid
ot Spec: 827S oo.oo Analysis File #: ~~~~~~~~
I Lab Sample ID:
9508434
I
Client ID:
HAM BEACH NC
-~PLE PREPARATION:
~OBLEM IDENTIFICATION
·sample Went Dry
I Loss of ~~ %
of Sample
Emulsion Formed
Blank Contamination
I Instrument
Hold Time
MS/MSD Not Available
I Instrument
Other (Describe)
lmrnents:
CSC:
JAL
Project Sample ID:
CORRECTIVE ACTION TAKEN
Reprepare Sample
Sample Sent for Analysis
Resample
Other (Describe)
~PLE ANA_L_Y_S_I_S_:~~~~~~~~~~~~~~~~~~,--~~~~~~~~~~~~
PROBLEM IDENTIFICATION
I Surrogate Recovery X
MS/MSD Recovery X
LCS/LCSD. Recovery
MS/MSD Precision X ·I LCS/LCSD Precision
standard
Blank Contamination.
I Instrument
Hold Time
No MS/MSD Available
I for Batch
.Sample pH
Dil. Due to Hi-Level
Non-Target Analytes
I Serial Dilution
Analytical Spike
Internal Standard I Other (Describe)
PROBABLE CAUSE
Matrix Effect X
Instrument
Spiking Error
Contamination
coelution
Unknown X
Other(Describe)
CORRECTIVE ACTION TAKEN
Reprepare Sample
Reanalyze Sample
Reanalyze LCS/LCSD
Recalibrate Instrument
Analyze out of Hold Time
Prepare New Standard
Flag Data
Res ample
Analyze by MSA _
Perform Analytical Spike _
No Action Required X
Level 3 QCER to Follow
Other (Describe) X
SEE BELOW
rmments: lcs/d955683, blk953709: 2-fluorobiphenyl was low in these samples
. 3rd lcs was analyzed with this compound falling within tolerances
-03as/04as: Several compounds were outside of tolerances for both
precision and accuracy due probably to matrix effect. 2,4,6-
~stribution: csc, Lab, Report
------
09/07/95 13:44:34
Report RADIAN CORPORATION
To 3200 E. CHAPEL HILL RD.
P. 0. BOX 13000
Attention JIM NARKUNAS
Phone ~R..-TP'------------
Prepared
By
Radian Analytical Services
14046 Sulllllit Dr., Bldg. B
P. 0. Box 201088
Austin, TX 78720-1088
512/244-0855
CSC JALINDSEY
Project Sample
Description
STKPILE
TBLK953699
STKPILE
STKPILE
ID/
-----
MORK ORDER SUHHARY
Client Code HAM BEACH NC
Client HAMILTON BEACH
Facility WASHINGTON NC
\.lork ID WASHINGTON,NC
Case # :.:.NA:..:..._ _____ _
SDG II '""NA"'-------
RAS II 5081 lAJAL
Lab Sample ID Test Code(s)
OlA LEACHATE 351SWA00
808SWATC
CK1SWAOO
02A LEACHATE 351SWAOO
808SWATC
CKlSWAOO
03A LEACHATE MS 351SWAOO -808SWAMS
CK1SWAOO
04A LEACHATE MSD 351SWAOO
808SWAMS
CK1SWA00
--.. --
~rk Order I 9508435
Page _1 _
RCN 650-138-02-01
Method Desciption
Sep-funnel Extract. S\.1846
Pesticides/PCBs by SY8080
Primary KO cone. S\.1846
Sep-funnel Extract. S\.J846
Pesticides/PCBs by S\.18080
Primary KD cone. sW846
Sep-funnel Extract. S\.1846
Pesticides/PCBs by S\.18080
Primary KD cone. S\.1846
Sep-funnel Extract. S\.J846
Pesticides/PCBs by S\.18080
Primary KD cone. S\.J846
---
-
09/07/95 13:44:34 ANALYTICAL PROTOCOL SUMMARY
f L A G D E f l N I T I 0 N S
Flag Definition
< DL Result less than stated Detection Limit and greater than or equal to zero.
NA Analyte concentration not available for this analysis.
NC RPO and/or i Recovery not calculated. See Narrative for explanation.
~D Not detected. No instrument response for analyte or result less than zero.
NR Not reported. Result greater than or equal to stated Detection Limit and less than specified Reporting Limit.
NS Analyte not spiked.
B Analyte detected in method blank at concentration greater than the Reporting Limit (and greater than zero).
c Confirming data obtained using second GC column or GCHS.
E Analyte concentration exceeded calibration range.
F Interference or coelution suspected. See Narrative for explanation.
H Presence of analyte previously confirmed by h·istorical data.
I Analyte identification suspect. See Narrative for explanation.
J Result is less than stated Detection Limit but greater than or equal to specified Reporting Limit.
K Peak did not meet method identification criteria. Analyte not detected on other GC column.
H Result modified from previous Report. See Narrative for explanation.
P Analyte not confirmed. Results from primary and secondary GC coll.lllns differ by greater than a factor of 3.
Q QC result does not meet tolerance in Protocol Specification.
R Result reported elsewhere.
s Analyte concentration obtained using Method of Standard Additions (HSAl.
T Second column confirmational analysis not performed.
X See Narr~tive for explanation.
Y See Narrative for explanation.
Z See Narrative for explanation.
Work Order I 9508435
Page£_
-------- - - -- ---· --
-.... -
09/07/95 13:44:34
Client HAMILTON BEACH
Facility ~ASHINGTON NC
Client Code HAM BEACH NC
-
Method Pesticides/PCBs by S~8080
~·
Project Sample ID/Description
STKPILE
STKPILE
TBLK953699
TBLK953699
- -
.. ---·-.. - --... -
ANALYTICAL PROTOCOL su""ARY
Spec i f i cation II !:'.8!:'.:08::::S:.__ ____ _
Extraction/Digestion
Lab Sample ID Test Code(s) Batch I
9508435-01A 808S~ATC 3510950831093600
9508435-01A 808S~ATC 3510950831093600
9508435-0ZA 808~ATC 3510950831093600
9508435-0ZA 808S~ATC 3510950831093600
\.lork Order I 9508435
PageL
Analysis Batch I
CHGC1A50905120001
CHGC1B50905120001
CHGC1A50905120001
CHGC1 B50905120001 '
-
-
09/07/95 13:44:34
Method Pesticides/PCBs by SW8080
Test Code 808SWATC
Project Sample ID:
Lab IO:
Fi le IO:
Date Collected:
Date Prepcired:
Date Analyzed:
Dilution Factor:
Matrix:
Units:
Report as:
Column:
Analyte
ganrna-BHC
Chlordane
Endrin
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogate Cs)
Dibutylchlorendate
2,4,5,6-Tetrachloro-m-xylene
- - -
..
STKPILE
9508435-0lA LEACHA
A15IE13
08/29/95
08/31/95
09/06/95 00:03
1.00
Water
ug/L
received
PRIMARY
Cone. DL
ND 0.0200
ND 0.225
ND 0.0933
ND 0.0250
1.86 K 0.0492
ND 0.317
ND 0.482
Recovery
"
92
88
--
RESULTS su""ARY
STKPILE
9508435-0lA LEACHA
B15IE13
08/29/95
08/31/95
09/06/95 00: 03 .
1.00
Water
ug/L
received
SECONDARY
Cone. DL
0.0570 K 0.0142
ND 0.224
ND 0.0942
ND 0.0200
ND 0.0217
ND 0.300
ND 0.555
Recovery
"
91
89
-----
TBLK953699
9508435-02A LEACHA
A15IE17
08/29/95
08/31/95
09/06/95 02:43
1.00
Water
ug/L
received
PRIMARY
Cone. DL
ND 0.0214
ND 0.241
ND 0.1000
ND 0.0268
0.0241 KJ 0.0527
ND 0.339
ND 0.516
Recovery
"
98
87
Work Order # 9508435
Pagei_
TBLK953699
9508435-02A LEACHA
B15IE17
08/29/95
08/31/95
09/06/95 02:43
1.00
Water
ug/L
received
SECONDARY
Cone. DL
ND 0.0152
ND 0.240
ND o. 101
ND 0.0214
ND 0.0232
ND 0.321
ND 0.595
Recovery
i
94 '
87
·-----.... -
__ .. .. -· --·-
09/07/95 .13:44:34
Sol 'n # ------------------
Method Pesticides/PCBs by SW8080
Test Code 808SWA01
Response Response
Area Counts Area Counts
Reference Reference
Cone. Cone.
Analytes ug/L ug/L
Chlordane 89918 181547
50 100
PCB-1016 72705.633 138539.84
50 100
PCB-1221 18206 34037
50 100
PCB-1232 37422 70253
50 100
PCB-1242 64490 120133
50 100
PCB-1248 93803 168913
50 100
PCB-1254 126358 219859
50 100
PCB-1260 152187.50 271289.41
50 100
Toxaphene 24170 51240
50 100
Dibutylchlorendate 36273 73121
Surrogate 10 20
-
-........
I N I T I A l CALIBRATION
Initial Calibration# GC1A950530120000
Calibration Date 05/30/95 12:00:00
Response Response Response
Area Counts Area Counts Area Counts
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
427277 847857 1321478
250 500 750
315394.25 589883.62 842161.88
250 500 750
80126 147097 204152
250 500 750
164994 301269 432341
250 500 750
272606 4IT828 715098
250 500 750
382415 667394 996586
250 500 750
496943 908882 1238465
250 500 750
589020. 12 1155969.2 158IT58.1
250 500 750
131423 288125 423460
250 500 750'
178621 359700 537067
50 100 150
Specification Limits '.tRSD < 20~ or correlation coefficient~ 0.995
--~-_ .. _
Response Response
Area Counts
Reference Reference
Cone. Cone.
ug/L
1760353
1000
1048517.8
1000
262513
1000
541127
1000
899716
1000
1226611
1000
1591073,
1000
1992030.2
1000
540028
1000
693485
200
Work Order # 9508435
Pagei_
InstrlJllent GClA
Analyst HAW
Reviewer . .;,,;H;;:.JD"'----
Correlation -RF % RSD Coefficient
(J.000570 2.84 1.000
0.000816 12.5 o .. 998
0.00328 12.8 0.998
0.00159 12.3 0.998
0.000955 14.1 0.999
0.000682 15.9 0.998
0.000523 17. 1 0.998
0.000421 15.4 0.998
0.00188 6.59 0.999
0.000279 3.24 1.000
-
-- --.. -.. .. -..... -.. .. - -
.. _
09/07/95 13:44:34 I N I T I A l C A l I B R A T I O N UPDATE
Sol 'n #
~~~~~~~~~~~~~~----
Method Pesticides/PCBs by S\.18080
Test Code 808S\.IA01
I
Response Response .
Area Counts Area Counts
Reference Reference
Cone. Cone.
. Analytes ug/L ug/L
Aldrin 9766 25434
2 5
alpha-BHC ' 4442 11309
1 2.5
beta-BHC 12764 33361
4 10
del ta-BHC 8260 21705
2 5
garmia-BHC 4713 12700
1.0 2.5
alpha-Chlordane . 11182 28790
2 5
,
garmia-Chlordane 11474 29233
2 5
4,4'-DDD 12092 32516
4 10
4,4'-DDE 8783 22103
2 5
4,4'-DDT 13545 36827
4.0 10.0
Initial Calibration# GC1A950703120000
Calibration Date 07/03/95 12:00:00
Response Response Response
Area Counts Area Counts Area Counts
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
52548 111558 3-20457
10 20 50
23864 53677 176227
5 10 25
66871 132310 335782
20 40 100
48564 112983 347012
10 20 50
26705 58957 175940
5.0 10.0 25
57075 113196 297078
10 20 50
57308 112910 298254
10 20 50
67394 142379 407518
20 40 100
44142 91300 262351
10 20 50
76790 162337 435521
20.0 40.0 100 .
Specification Limits ~RSD < 2oi or. correlation coefficient~ 0.995
Response
Area Counts
Reference
Cone.
ug/L
616443
100
364343
50
606383
200
674740
100
363937
50.0
548095
100
558286
100
772036
200
506003
100
859075
200.0
Response
Area Counts
Reference
Cone.
ug/L
1203931
200
744240
100
1133037
400
.1328415
200
727911
100
1049594
200
1074861
200
1511818
400
1003552
200
1671738
400
\.lork Order I 9508435
PageL
Instrument GC1A
Analyst MA\.I
Reviewer :.:.MJ;:.,,D:;..._ __
Correl at ion -
RF ~ RSD Coefficient
·0.000179 10.9 1.000
0.000179 22.8 1.000
0.000314 '6.95 1.000
0.000185 22. 1 1.000
0.000169 18.2 1.000
0.000178 4.20 1.000
0.000176 4.13 1.000
0.000284 10. 6 1.000
0.000212 8.15 1.000
0.000254 9.35 1.000
-
----.. -.. -........ -.. -..... ,..,._
09/07/95 13:44:34 I N I T I A l C A l I 8 R A T I O N U P D A T E e.ont•d
Sol 'n # ~~~--------------~ Method Pesticides/PCBs by SW8080
Test Code 808SWA01
Response Response
Area Counts Area Counts
Reference Reference
Cone. Cone.
Analytes ug/L ug/L
Methoxychlor 37783 101518
16.0 40.0
Mirex 25512 61835
5 12.5
Dibutylchlorendate 28382 72966
Surrogate 8 20
2,4,5,6-Tetrachloro-m-xylene 21616 55882
Surrogate 4 10
Decachlorobiphenyl 66508 128813
Surrogate 10 20
Initial Calibration# GC1A950703120000
Calibration Date 07/03/95 12:00:00
Response Response Response
Area Counts Area Counts Area Counts
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
198109 382695 911031
80.0 160.0 400
114365 209075 479489
25 50 125
144897 284832 723748
40 80 200
110350 214353 526007
20 40 100
289437 536829 757330
50 100 150
Specification-Limits ~RSD < 201 or correlation coefficient ;?: 0.995
Response Response
Area Counts Area Counts
Reference Reference
Cone. Cone.
ug/L ug/L
1690063 3178575
800.0 1600
828849 1515566
250 500
1319153 2516664
400 800
946539 1742649
200 400
940988
200
\./ork Order # 9508435
Page L
Instrument GC1A
Analyst MAW
Reviewer ""MJ""'D'----
Correlation -RF 1 RSD Coefficient
0.000436 8.98 1.000
0.000250 20.5 1.000
0.000287 6. 12 1.000
0.000195 9.87 1.000
' 0.000179 13.8 1.00
09/07/95 13:44:34
Sol 'n It------------------
Method Pesticides/PCBs by SW8080
Test Code 808SWA01
--
Response Response
Area Counts Area Counts
Reference Reference
Cone. Cone.
Analytes ug/L ug/L
Chlordane 67870 143633
50 100
PCB-1016 71055. 133 132790. 90
50 100
PCB-1221 15789 29359
50 100
PCB-1232 35692 66154
50 100
-
PCB-1242 72661 134589
50 100
PCB-1248 64832 116831
50 100
PCB-1254 119349 217855
50 100
PCB-1260 114306.25 215326.37
50 100
Toxaphene 30086 63663
50 100
Dibutylchlorendate 64620 138083
surrogate 10 20
INITIAL t A L I B R A T I 0 Ill
Initial Calibration# GC1B950530120000
Calibration Date 05/30/95 12:00:00
Response Response Response
Area Counts Area Counts Area Counts
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
358392 728303 1156800
250 500 750.
305470.97 567239.81 806704.62
250 500 750
68855 125277 173691
250 500 750
155648 282596 407834
250 500 750
305890 533965 785063
250 500 750
266698 447463 665745
250 500 750
483188 918695 1253485
250 500 750
473104.53 895946.69 1282524.0
250 500 750
165737 374806 574599
250 500 750
335635 670138 972846
50 100 150
Response Response
Area Counts Area Counts
Reference Reference
Cone. Cone.
ug/L ug/L
1542676
1000
996442.62
1000
222542
1000
511584
1000
998600
1000
823157
1000
1606121
1000
1573037.7
1000
748609
1000
1229161
200
Work Order I 9508435
·Page 1Q_
Instrument GClB
Analyst MAW
Reviewer "'""'H;:..:JD=----
Correl at ion -Rf X RSD Coefficient
0.000686 5. 14 1.000
0.000848 13.3 0,998
0.00383 13.6 0.998
0.00168 12.5 0.998
0.000857 14.8 0,999
0.00100 17.5 0.998
0.000527 15.0 0.998
0.000535 14.0 0.998
0.00145 10.3 1.000
0.000152 4.09 0.999
-Sp~tio .. ts ..-2oi..,rre ... cod•-.· ~nt .. 5 -... .. .. _ .. _ ... _..,_
-.. .. .. ·• .. ..
09/07/95 13:44:34
Sol 'n II-------------------
Method Pesticides/PCBs by SW8080
Test Code 808SWA01
Response Response
Area Counts Area Counts
Reference Reference
Cone. Cone.
Analytes ug/L ug/L
2,4,5,6-Tetrachloro-m-xylene 54933 110005
Surrogate 10 20
Decachlorobiphenyl 62772 122675
Surrogate 10 20
.. ·-.. \ .... .. _ ........ I,-
I N I T I A L C A L I B R A T I 0 N Cont'd
Initial Calibration# GC1B950530120000
Calibration Date 05/30/95 12:00:00
Response Response Response
Area Counts Area Counts Area Counts
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
274080 531935 761133
50 100 150
279765 526569 746899
50 100 150
Response
Area Counts
Reference
Cone.
ug/L
959122
200
929725
200
Response
Area Counts
Reference
Cone.
ug/L
\.lork Order # 9508435
Page lL
Instrument GClB
Analyst HAW
Reviewer '"'"MJ""'O"----
Correl at ion -RF X RSD Coefficient
0,000190 6.05 0.998
0.000184 12.1 0:998
I
Specification Limits XRSO < 20'1 or correlation coefficient~ 0.995
09/07/95 13:44:34 INITIAL C A l I B R A T I 0 N UPDATE
Sol 'n # ------------------
Method Pesticides/PCBs by SY8080
Test Code 808SYA01
Response Response .
Area Counts Area Counts
Reference Reference
Cone. Cone.
. Analytes ug/L ug/L
-
Aldrin 9765 26325
2 5
alpha-BHC 3965 10886
1 2.5
beta-BHC 13064 33341
4 lO
delta-BHC 7595 21212
2 5
ganma-BHC 4536 12357
1.0 2.5 .
alpha-Chlordane 1063•2 27667
2 5
ganma-Chlordane 11293 28801
2 5
'•.4'·000 10286 31833
4 10
(, ,4 '-ODE 8388 22020
2 5
4,4 '-DDT 14948 39654
4.0 10.0
Initial Calibration I GC1B950703120000
Calibration Date 07/03/95 12:00:00
Response Response Response
Area Counts Area Counts Area Counts
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
55669 119963 351354
10 20 50
23804 53332 177284
5 10 25
66835 130364 327369
20 40 100
48553 115513 358744
10 20 50
26359 59219 180195
5.0 10.0 25
54670 114294 307053
10 20 50
57788 117160 318435
10 20 50
68868 151647 432811
20 40 100
46208 98869 286230
10 20 50
81173 172184 460873
20.0 40.0 100
Response
Area Counts
Reference
Cone,
ug/L
675931
100
375050
50
603996
200
698689
100
371351
so.a
578162
100
597247
100
820392
200
549232
100
895231
200.0
Response
Area Counts
Reference
Cone.
ug/L
1319334
200
760278
100
1123334
400
1386367
200
745400
100
1093808
200
1161231
200
1600367
400
1081755
200 .
1734453
400
Work Order I 9508435
PageR_
Instnrnent GC1B
Analyst MA\J
Reviewer .:..:H~JD=----
Correl at ion -Rf 'X. RSD Coefficient
6.000169 14.2 1.000
0.000184 27. 1 1,000
0.000315 6,84 1,000
0.000186 26.8 1.000
0.000170 21. 1 1.000
0,000178 5.63 1.000
0,000170 4.52 1.000
0.000283 19.5 1.000
0.000204 12. 1 1. 000
0.000238 7.71 1.000
-Sp~ticWts .. 20~~rre-coc[ :nt .. 5 ·-.. t.W ... - -.... -.. ,, -
___ ... _!_ ...... -..... _ .............. --
09/07/95 13:44:34 EXTRACTION BATCH SUMMARY
Extraction Batch # 3510950831093600
Method Sep-funnel Extract. S~846
Test Code 351S~A00
Extraction Start Date/Time 08/31/95 09:36:00
Extraction Stop Date/Time 08/31/95 10:40:00
Sample Project Sample ID Lab Sample ID
1 STKPILE 9508435-0lA
'2 TBLK953699 9508435-0ZA
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Quality Control Project Sample ID Lab Sample ID
Blank BLK953712
Laboratory Control Sample LCS955686
Laboratory Control Salll>le Duplicate LCSD955686
Matrix Spike STKPILE 9508435-03A
Hatrix Spike Duplicate STKPILE 9508435-04A
\.lork Order # 9508435
Page .12_
Analyst KP\4
Reviewer--------
Sample Size
ml Cleanup Method
120
112
Sample Size
ml Cleanup Method
1000
1000
1000
116
120
-
09/07/95 13:44:34
Method Pesticides/PCBs by S\./8080
Test Code 808SWATC
Initial Calibration# GC1A950703120000
Calibration Date =07;....;./-"'0=3/:...:9....::;5 ___ _
Sequence/Analysis Time
1 09/05/95 16:00
2 09/05/95 16:41
~ 09/05/95 17: 21
4 09/05/95 18:01
5 09/05/95 18:41
6 09/05/95 19:22
7 09/05/95 20:02
8 09/05/95 20:42
9 09/05/95 21:22
10 09/05/95 22:02
11 09/05/95 22:42
12 09/05/95 23:23
13 09/06/95 00:03
14 09/06/95 00:43
15 09/06/95 01:23
16 09/06/95 02:03
17 09/06/95 02:43
18 09/06/95 03:22
19 09/06/95 04:02
20 09/06/95 04:41
21 09/06/95 05:22
22 09/06/95 06:02
23 09/06/95 06:42
ANALYSIS BATCH SUMMARY
Analysis Batch # CHGC1A50905120001
Analysis Start Date/Time 09/05/95 12:00:00
Analysis Stop Date/Time
Work Order I 9508435
Page 1.Q_.
Instrument GC1A
Analyst MAW
Reviewer .:..oMJ:..:D::__ ___ ~--
Project Sample ID Lab Sample ID Sample Type Analysis Fi le I
PRIMER AtB Pri.mer A15IE1
HB, BC_ Laboratory Blank A15IE2
EVAL CB Ini l 1al Calibration Al 5I E3 -AE\.I PESl A Continuing Calibration Check A 151 E4
BEW PEST B Continuing Calibration Check A15IE5
81M TOXAPHE Continuing Calibration Check A15IE6
91M CHLORDA Continuing Calibration Check A15IE7
HB, BC_ Laboratory Blank A15IE8
BLK953712 Laboratory Blank A15IE9
LCS955686 Lab Control Sample A15IE10
LCSD955686 Lab Control Sample Dup A15IE11
HB, BC_ Laboratory Blank A15IE12
STKPILE 9508435-0lA Sample A15IE13
STKPILE 9508435-03A Matrix Spike A15IE14
STKPILE 9508435-04A Matrix Spike Dup A15IE15
HB, BC_ Laboratory Blank A15IE16
TBLK953699 9508435-02A Sample A15IE17
HB, BC_ Laboratory Blank A15IE18
HB, BC_ Laboratory Blank A15IE19
AEW _PE~T A Continuing Calibration Check A15IE20
BEW Pl:.S r B Continuing Calibration Check A15IE21 -8[},.J TOXAPHE Continuing Calibration Check A15IE22
91M CHLORDA Continuing Calibration Check A15IE23
_,_._ '• .. -.. -.... -.......... -... --
- - ---
09/07/95 13:44:34
---·---·-.... --.. .. -
H A T R I X S P I K E ( S )
Extraction Batch # 3510950831093600
Analysis Batch # CHGC1A50905120001
TCLP Batch # TCTCLP508281645
~rk Order # 9508435
Page f.L
Project Sample ID _S_TK_P_I_L~E ______ _ Date Collected 08/29/95
Date Received· 08/23/95
Date Prepared 08/31/95
Instrument GC1A
Column PRIMARY
Analyst MAW
Reviewer ""'M""'JD"----
Reporting Subset __
Spikes Subset __
Matrix !:[
Method Pesticides/PCBs by S\./8080 Report As received
Test Code 808SWAMS Specs Subset _ _ i Hoi s ture
Date Analyzed 09/06/95 01:23
Spike Sol 'n # Vol. Added Sample Spiked Sample Spiked Sample Dup
SP-1-652 PEST lQQ_ !LL Lab ~ample ID Lab Sample ID Lab Sample ID
SP-1 ··657 PCB lQQ_ !LL 9508435-0lA LEACHA 9508435-03A LEACHA 9508435-04A LEACHA
Fi le# A15IE13 Fi le# A15IE14 File I A15IE15 ----Surrogate Sol 'n Vol. Added Aliquot Hass/Vol Aliquot Hass/Vol Aliquot Hass/Vol
SP-1-651 lQQ_ !LL 120 Cmll 116 (ml) 120 (ml) Recovery
----Extract Hass/Vol Extract Mass/Vol Extract Mass/Vol Specifi-
5 (ml) 5 (ml) 5 (ml) cation ----Di l Fact. 1.00 Oil Fact. 1.00 Di l Fact. 1.00 Limits RPD
Spike Specif i-
Sol 'n Measured Spiked Measured Spiked Measured cation
Analyte Cone. Cone. Cone. Cone. Rec. Cone. Cone. Rec. Low High Result Limit
ug/L ug/L ug/L ug/L i ug/L ug/l x i x ' x 1.
Aldrin 2.0 0.0275 1.72 1.46 83 1.67 1.47 86 42 122 3.6 55
gamma-BHC 2.0 ND 1. 72 1. 54 89 1.67 1.54 93 32 127 4.4 63
4,4'-DDT 5.0 ND 4.31 4.06 94 4.17 4.15 100 25 160 6.2 85
Dieldrin 5.0 ND 4.31 4.06 94 4. 17 4.08 98 36 146 4.2 44
Endrin 5.0 ND 4.31 4. 15 96 4.17 4. 16 100 30 147 4. 1 67
Heptachlor 2.0 ND 1. 72 1.53 89 1.67 1.53 92 34 120 3.3 43
Surrogate(s)
Dibutylchlorendate 10 7.64 8.62 7.90 92 8.33 8.00 96 20 150
2,4,5,6-Tetrachloro-m-xylene 10 7.35 8.62 7.38 86 8.33 7.48 90 20 150
-
-
09/07/95 13:44:34 C O N T I N U I N G ( 0 R 0 A I L Y ) C A L I B R A T I 0 N
V E R I f I C A T I 0 N
\.Jerk Order # 9508435
Page R
-
Lab Sample ID AE\J PEST A
Fi le # :..:.A 1.:..:5:.:.I.::.E4.:.._ __ _
Method Pesticides/PCBs by SW8080
Test Code 808SWATC
Analyte
ganma-BHC
Heptachlor
Heptachlor epoxide
Methoxychlor
surrogate Cs)
--
Dibutylchlorendate
2,4,5,6-Tetrachloro-m-xylene
Analysis Batch # CHGC1A50905120001
Initial Calibration# GC1A950703120000
Date Analyzed 09/05/95 18:01
Measured Reference
Concentration Concentration
ug/L ug/L
25.1 25.0
54.7 50.0
52.0 50.0
406 400
205 200
108 100
Reporting subset_
Spikes Subset_
Specs Subset _
Recovery
·i
1"00
109
104
101
102
108
·Instrument GClA
Analyst MAW
Reviewer ""'MJ""D"----
Recovery
Specification
Limits
LCM High
l l
85 115
85 115
85 115
85 . 115
-
85 115
85 115
·-·--.... - --·-.. ... --.. ' -·--
-
09/07/95 13:44:34 C 0 N T I N U I N G ( 0 R D A I L Y ) C A L I 8 R A T I 0 N
VERIFICATION
Work Order # 9508435
Page ~
·-
Lab Sample ID AEW PEST A
Fi le# A15IE20
Method Pesticides/PCBs by S\.18080
Test Code 808S\.IATC
Analyte
ganrna-BHC
Heptachlor
Heptachlor epoxide
Methoxychlor
Surrogate Cs>
Di~tylchlorendate
2,t,, ',,6-Tetrachloro-m-xylene
Analysis Batch # CHGC1A50905120001
Initial Calibration# GC1A9507031i:'()(!QQ__
Date Analyzed 09/06/95 04:41
Measured Reference
Concentration Concentration
ug/L ug/L
25. 1 25.0
54.8 50.0
51.9 50.0
410 400
204 200
109 100
Reporting Subset_
Spikes Subset _
Specs Subset_
Recovery
\
100
110
104
102
102
109
Recovery
Instrument GClA
Analyst HA\./
Reviewer .,_M=J"--D __
Spec if i cat ion
Limits
Low High
\ \
85 115
85 115
85 115
85 115
85 115
85 115
----... - ---·-----·---:-
-
09/07/95 13:44:34 C 0 N T I N U I N G ( 0 R D A I L Y ) C A L I 8 R A T I 0 N
V E R I F I C A T I 0 N
Work Order # 9508435
Page~
-
Lab Sample ID 81Jr/ TOXAPHE
File# A15IE22
Method Pesticides/PCBs by SW8080
Test Code 808SWATC
Analyte
Toxaphene
Analysis Batch # CHGC1A50905120001
Initial Calibration# GC1A950703120000
Date Analyzed 09/06/95 06:02
Measured Ret~rence
Concentration Concentration
ug/L ug/L
534 500
Reporting Subset _
Spikes Subset_
Specs Subset_
Recovery
-l
107
.Instrunent GC1A
Analyst ~
Reviewer _:_,HJ:::;D"----
Recovery
Specification
Limits
Low High
i i
85 115
-- --·-_, ___ .. _______ _
- -- -- ---~----·-------
09/07/95 13:44:34 C 0 N T I N U I N G ( 0 R D A I L Y J C A L I 8 R A T I 0 N
VERIFICATION
Work Order # 9508435
Page~
Lab Sample ID 9[A.I CHLORDA
File# A15IE23
Method Pesticides/PCBs by S\.J8080
Test Code 808S~ATC
Analyte
Chlordane
Analysis Batch # CHGC1A50905120001
Initial Calibration# GC1A950703120000
Date Analyzed 09/06/95 06:42
Measured Reference
Concentration Concentration
ug/L ug/L
513 500
Reporting Subset_
Spikes Subset _
Specs Subset_
Recovery
1.
103
Recovery
Instrument GClA
Analyst HA~
Reviewer ~H~JD __ _
Specification
Limits
Low High
1. 1.
85 115
09/07/95 13:44:34
Lab Sample ID EVAL CB
Fi le # '-'A""-'15::..::I.::.E3"-----
Hethod Pesticides/PCBs by S\-18080
Test Code 808S\JATC
Analyte
4,4'-DDD
4,4'-DDE
4,4'-DDT
Endrin
Endrin Aldehyde
Endrin Ketone
DDT Breakdown
Endrin Breakdown
DDT\ ENDRIN BREAKDO\IN
Analysis Batch # CHGC1A50905120001
Date Analyzed 09/05/95 17:21
Area Counts i
3956
2995
235484
312173
4962
9838
2.87
4.53
Work Order # 9508435
Page 1Q_
Instrument GClA
Analyst HA\./
Reviewer .;..;.HJ=D--__
Speci ficat_ion
Limits
i
20
20
--------~--~---~---
-
09/07/95 13:44:34
Project Sample ID .:::S.!-'TK~P_.I-"'L.::.E ______ _
Lab Sample ID 9508435-01A LEACHA
Fi le I "'"B"""15"""I""'E"""13'-----
Method Pesticides/PCBs by S\48080
Test Code 808SWATC
Analyte
gamma-BHC
Chlordane
Endrin
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogate(s)
Dibutylchlorendate
CAS #
58-89-9
57-74-9
72-20-8
76-44-8
1024-57-3
72-43-5
8001-35-2
CASI
1770-80-5
RESULTS
Extraction Batch # 3510950831093600
Analysis Batch I CHGC1B50905120001
TCLP Batch # TCTCLP508281645
Date Collected 08/29/95 Instrument GC1B
Date Received 08/23/95 Column SECONDARY
Date Prepared 08/31/95 Analyst HAW
Date Analyzed 09/06/95 00:03 Reviewer MJD
Aliquot Mass/Volume
120 (ml)
Extract/Digestate Volume
5 (ml)
Dilution Factor 1.00
Measured Concentration
ug/L
0.0570 K
ND
ND
ND
ND
ND
ND
Spiked
Cone. Measured Concentration
ug/L ug/L
8.33 7.60
2,4,5,6-Tetrachloro-m-xylene 88077-09-8 8.33 7.41
Work Order I 9508435
Page R
Reporting Subset _ Matrix H
Spikes Subset _ Report As received
Specs Subset _ Y. Moisture
Detection Limit Reporting Limit
ug/L ug/L
0.0142 o
0.224 o
0.0942 o
0.0200 0
0.0217 o
0.300 0
0.555 0
Specification Limits
Recovery Low High
Y. Y. Y.
91 20 150
89 20 150
- -----------------
- - --- - -----------
09/07/95 13:44:34
Project Sample ID -=-T=Bl"'"K'"'-9=53:;..o6'"'"9-'-9 _____ _
Lab Sample ID 9508435-02A LEACHA
Fi le # =B-'-'15~I-=E-'-'17 ___ _
Method Pesticides/PCBs by S~8080
Test Code 808S~ATC
Analyte
ganma-BHC
Chlordane
Endrin
Heptachlor
Heptachlor epoxid~
Hethoxychlor
Toxaphene
Surrogate(s)
Dibutylchlorendate
CAS #
58-89-9
57-74-9
72-20-8
76-44-8
1024-57-3
72-43-5
8001-35-2
CAS #
1770-80-5
R E S U L T S
Extraction Batch # 3510950831093600
Analysis Batch # CHGC1B50905120001
TCLP Batch #. TCTCLP508281645
Date Collected 08/29/95 Instrument GClB
Date Received 08/23/95 Column· SECONDARY
Date Prepared 08/31/95 Analyst HA~
Date Analyzed 09/06/95 02:43 Reviewer HJD
Aliquot Hass/Volume
112 (ml)
Extract/Digestate Volume
5 Cml)
Dilution Factor 1.00
Measured Concentration
ug/L
ND
ND
ND
ND
ND
·-ND
ND
Spiked
Cone. Measured Concentration
ug/L ug/L
8.93 8.40
2,4,5,6-Tetrachloro-m-xylene 88077-09-8 8.93 7.79
i
work Order # 9508435
Page n_
Reporting Subset _ Matrix H
Spikes Subset _ Report As received
Specs Subset _ X Moisture
Detection Limit Reporting Limit
ug/L ug/L
0.0152 0
0.240 0
0.101 0
0.0214 0
0.0232 0
0.321 0
0.595 0
Specification Limits
Recovery Law High
l l l
94 20 150
87 20 150
--
·-
09/07/95 13:44:34
Lab Sample ID BLK953712
Fi le# .,_B1""'5"""I""'E9'------
Method Pesticides/PCBs by SW8080
Test Code 808SWATC
Analyte
ganma-BHC
Chlordane
Endrin
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogate Cs)
Dibutylchlorendate
LABORATORY BLANK INFORMATION \./ork Order # 9508435
Page li._
Extraction Batch # 35'.~950831093600
Analysis Batch # CHGC1B50905120001
TCLP Batch # TCTCLP508281645
Date Prepared 08/31/95 Instrument GC1B
Date Analyzed 09/05/95 21:22 Column SECONDARY
Analyst MAW
Reviewer :.::MJ==D'----
Aliquot Mass/Volume
1000 Cmll
Extract/Digestate Volume
5 (ml)
Dilution Factor 1.00
Measured Cone.
ug/L
ND
ND
ND
ND
ND
ND
ND
Spiked
Cone. Measured Cone.
ug/L Ug/L
1.00 0.919
Reporting Subset_
Spikes Subset_
Specs Subset
Matrix }!
Detection Limit Reporting Limit
ug/L ug/L
0.00170 0
0.0269 0
0.0113 0
0.00240 0
0.00260 0
0.0360 0
0.0666 0
Specification Limits
Recovery Low lligh
" l l
92 20 150
'
2,4, 5, 6-Te,trach Loro-m-xy Lene 1.00 0.872 87 20 150
--- -- ----·------·---
-... --
09/07/95 13:44:34
Method Pesticides/PCBs by S~8080
Test Code 808S~ATC
Control Std. # Vol. Added
SP-1-653 PCB .lQQ_ .\!!.__
SP-1-654 PEST .lQQ_ .!!!:.__
----
Analyte
ganma-BHC
Endrin
Heptachlor
Heptachlor epoxide
Surrogate(s)
Dibutylchlorendate
2,4,5,6-Tetrachloro-m-xylene
---- ----
LABORATORY CONTROL SAMPL~
Extraction Batch # 3510950831093600
Analysis Batch # CHGC1B50905120001
-----
Work Order I 9508435
Page 12_
Date Prepared 08/31/95 Instrument !!fl.!L_
Column SECONDARY
Analyst MA~
Reporting Subset _· _ __ Matrix H
Date Analyzed 09/05/95 22:42
Reviewer ~MJ_D __ _
Surrogate Sol'n # Vol. Added LCS
SP-1-651 .lQQ_ .!!!:.__ Lab Sample ID
LCS955686 -----File ID B15IE10 -----. Spiked Measured
Cone. Cone. Rec.
ug/L ug/L ~
0.250 0.244 98
0.500 0.497 99
0.250 0.231 93
0.250 0.252 101
1.00 0.911 91
1.00 0.808 81
Spikes Subset__ Report As received
Specs Subset __ ~ Moisture
LCS Duplicate
Lab Sample ID
LCSD955686
File ID B15IE11
Spiked Measured
Cone. Cone.
ug/L ug/L
0.250 0.249
0.500 0.480
0.250 0.239
0.250 0.248
1.00 0.941
1.00 0.896
Aliquot Mass or Vol
Extra~1 Mass or Vol
Recovery
Spec.
Limits
Rec. Low High
" " "
100 32 127
96 30 147
96 34 120
99 37 142
94 20 150
90 20 150
1000 (ml)
___ 5 <mll
RPO
Spec.
Result Limit
" ~
2.0 63
3. 1 67
3.2 43
2.0 68
--
09/07/95 13:44:34 "ATRIX SPIKE(S)
Extraction Batch I 3510950831093600
Analysis Batch I CHGC1B50905120001
TCLP Batch I TCTCLP508281645
Work Order # 9508435
Page 12.._
Project Sample ID .::S..:.;TKC!!P...!l"""L.::..E ______ _ Date Collected 08/29/95
Date Received 08/23/95
Date Prepared 08/31/95
Instrument GC1B
Column SECONDARY
Analyst HAW
Reviewer !.::HJ~D:.._ __
Reporting Subset _ _ Matrix H
Method Pesticides/PCBs by SW8080
Test Code 808SWAHS
Date Analyzed 09/06/95 01:23
Spike Sol 'n It Vol. Added Sample Spiked Sample
SP-1-652 PEST .1QQ_ .\!!.._ Lab Sample ID Lab Sample ID
SP-1-657 PCB .1QQ_ .\!!.._ 9508435-0lA LEACHA 9508435-03A LEACHA
File# B151E13 File I B15IE14 ----surrogate Sol 'n Vol. Added Aliquot Hass/Vol Aliquot Hass/Vol
SP-1-651 .1QQ_ .\!!.._ 120 (ml} 116 (ml)
Extract Hass/Vol Extract Hass/Vol ----5 (ml) 5 (ml} ----Oil Fact. 1.00 Di l Fact. 1.00
Spike
Sol 'n Measured Spiked Measured
Analyte Cone. Cone. Cone. Cone. Rec.
ug/L ug/L ug/L ug/L i
Aldrin 2.0 0.0707 c 1.72 1.42 78
gamma-BHC 2.0 0.0570 K 1.72 1. 50 84
4,4'-DDT 5.0 ND 4.31 4.03 94
Dieldrin 5.0 0.0674 K 4.31 3.94 90
Endrin 5.0 ND 4.31 4.17 97
Heptachlor 2.0 ND 1. 72 1.48 86
Surrogate Cs)
Dibutylchlorendate 10 7.60 8.62 7.90 92
2,4,5,6-Tetrachloro-m-xylene 10 7.41 8.62 7.34 85
-- ---------
Spikes Subset _ _ Report As received
Specs Subst:l _ _ i Moisture
Spiked Sample Dup .
Lab Sample ID
9508435-04A LEACHA
File I B15IE15
Aliquot Hass/Vol
120 (mll Recovery
Extract Hass/Vol Specifi-
5 (ml) cation
Di l Fact. 1.00 Limits RPll
Specifi-
Spiked Measured cation
Cone. Cone. Rec. Low High Resu Limit
ug/L ug/L i l l l l
1.67 1.45 83 42 122 6.2 55
1.67 1.52 88 32 127 4.6 63
4.17 4.10 98 25 160 4.2 85
4.17 3.98 94 36 146 4.4 44
4.17 4.23 101 30 147 4.0 67
1.67 1.50 90 34 120 4.6 43
8.33 8.02 96 20 150
8.33 7.50 90 20 150
--------
- -- --- -- ----------
09/07/95 13:44:34 CONTINUING(OR DAILY) CALIBRATION 1.Jork Order # 9508435
Page IL.
Lab Sample IO ABI PEST A
Fi le Ii B15IE4 ------Method Pesticides/PCBs by SW8080
Test Code 808SWATC
Analyte
ga11111a-BHC
Heptachlor
Heptachlor epoxide
Methoxychlor
Surrogate<s)
Dibutylchlorendate
2,4,5,6-Tetrachloro-m-xylene
VERIFICATION
Analysis Batch # CHGC1B50905120001
Initial Calibration# GC1B950703120000
Oate Analyzed 09/05/95 18:01
Measured Reference
Concentration Concentration
ug/L ug/L
24.9 25.0
53.6 50.0
52.1 50.0
395 400
204 200
110 100
Reporting Subset _
Spikes Subset _
Specs subset _
·Recovery
i
100
107
104
99
102
110
Instrument GC1B
Analyst MAW
Reviewer ""MJ.-D.__ __
Recovery
Spec if icat ion
Limits
Low High
i t
80 120
80 120
80 120
80 120
80 120
80 120
-
-
09/07/95 13:44:34 C O N T I N U I N G ( 0 R D A I l Y ) C A l I 8 R A T I 0 N
Y E R I f I C A T I O N
Work Order # 9508435
Page 1!L
-
Lab Sample ID BE\.J PEST B
Fi le # ""B"""15;.:I..:E~5 ___ _
Method Pesticides/PCBs by SW8080
Test Code 808SWATC
Analyte
Endrin
Surrogate(sl
Dibutylchlorendate
2,4,5,6-Tetrachloro-m-xylene
Analysis Batch # CHGC1B50905120001
Initial Calibration# GC1B950703120000
Date Analyzed 09/05/95 18:41
Measured Reference
Concentration Concentration
ug/L ug/L
105 100
206 200
107 100
Reporting Subset_
Spikes Subset _
Specs Subset _
Recovery
'X
105
103
107
Instrument GClB
Analyst HAW
Reviewer :...:M""JD"----
Recovery
Spec If lea ti on
Limits
Low High
'X 'X
80 120
80 120
80 120
----------------
-
09/07/95 13:44:34 c· 0 11 T I II U I II G ( 0 R D A I L Y ) C A L I B R A T I 0 II Work Order I 9508435
Page 5Q_
-
Lab Sample ID 9CM CHLORDA
Fi Le # :::.B.:.:15:..:I.=E7,__ __ _
Method Pesticides/PCBs by SW8080
Test Code 808SWATC
Analyte
Chlordane
---
VERIFICATION
Analysis Batch# CHGC1B50905120001
Initial Calibration# GC1B950703120000
Date Analyzed 09/05/95 20:02 Reporting Subset _
Spikes Subset_
Specs Subset_
' Measured Reference
Concentration Concentration Recovery
ug/L ug/L i
497 500 99
Instn.ment GC1B
·Analyst ~
Reviewer "'"'MJ""D"----
Recovery
Specification
Limits
Low High
i i
80 120
-- --------·---
-- -- -- -----------
09/07/95 13:44:34 C 0 N T I N U I N G ( 0 R D A I l Y ) C A l I B R A T I 0 N
VERIFICATION
Work Order # 9508435
Page .il_
Lab Sample ID AE\J PEST A
File# B151E20
·Method Pesticides/PCBs by SW8080
Test Code 808SWATC
Analyte
gamma-BHC
Heptachlor
Heptachlor epoxide
Methoxychlor
Surrogate Cs)
Dibutylchlorendate
2,4,5,6-Tetrachloro-m-xylene
Analysis Batch # CHGC1B50905120001
Initial Calibration# GC1B950703120000.
Date Analyzed 09/06/95 04:41
Measured Reference
Concentration Concentration
ug/L ug/L
24.5 25.0
52.9 50.0
51.4 50.0
402 400
201 200
108 100
Reporting Subset _
Spikes Subset
Specs Subset
Recovery
x
98
106
103
100
101
108
Instrument GC1B
Analyst MAW
Reviewer ,_,HJ::.:D~---'-
Recovery
Specification
Limits
Low High
x x
80 120
80 120
80 120
80 .120
80 120
80 120
--
-
09/07/95 13:44:34 C 0 N T I N U I N G ( 0 R D A I L Y ) C A L I B R A T I 0 N
VERIFICATION
Work Order # 9508435
Page£__
-
Lab Sample ID BEW PEST B
File# B15IE21
Method Pesticides/PCBs by S\.18080
Test Code 808SWATC
Analyte
Endrin
Surrogate(s)
Dibutylchlorendate
2,4,5,6-Tetrachloro-m-xylene
- ---
Analysis Batch # CHGC1B50905120001
Initial Calibration# GC1B950703120000
Date Analyzed 09/06/95 05:22
Measured Reference
Concentration Concentration
ug/L ug/L
106 100
209 200
106 100
Reporting Subset _
Spikes Subset _
Specs Subset_
Recovery
t
106
104
106
Instrument GC1B
Analyst HAW
Reviewer .:.:H""'JD::;._ __
Recovery
Specification
Limits
Low High
t t
80 120
80 120
80 120
-- -
__ .. ____ _ --
----- --- ---.. -I-... - - -
09/07/95 13:44:34 C O N T I N U I N G ( 0 R D A I l Y ) C A l I B R A T I 0 N
VERIFICATION
\.lork Order I 9508435
Page !!L
Analysis Batch # CHGC1B50905120001
Initial Calibration# GC1B950703120000
Lab Sample ID BOW TOXAPHE Date Analyzed 09/06/95 06:02 Reporting Subset _
Spikes Subset_
Specs Subset
File I B15IE22
Method Pesticides/PCBs by S\.18080
Test Code 808SWATC
Analyte
Toxaphene
Measured
Concentration
ug/L
522
Reference
Concentration Recovery
ug/L x
500 104
Recovery
Instrument GC1B
Analyst MA\./
Reviewer !.!HJ,,_,D~--
Specification
Limits
Low High
'L 'L
80 120
-
-
09/07/95 13:44:34 COllTillUillG(OR DAILY) CALIBRATION \.Jerk Order I 9508435
Page~
-
Lab Sample JD 91J.1 CHLORDA
File# B15JE23
Method Pesticides/PCBs by SW8080
Test Code 808SWATC
Analyte
Chlordane
----
VERIFICATION
Analysis Batch I CHGC1B50905120001
Initial Calibration# GC1B950703120000
Date Analyzed 09/06/95 06:42
Measured Reference
Concentration Concentration
ug/L ug/L
494 500
Reporting Subset_
Spikes Subset _
Specs Subset_
Recovery
"
99
Recovery
Instrunent GClB
Analyst MAW
Reviewer .:.:HJ::.:D;::__ __
Specification
Limits
Low High
" "
80 120
----..... \_ .. ----
---- -- - -
________ ... ___ _
09/07/95 13:44:34
Lab Sample ID EVAL CB
Fi le I ;;;;.B1_,__,5'-"I-=E3~---
Method Pesticides/PCBs by SW8080
Test Code 808SWATC
Analyte
4,4'-DDD
4,4'-DDE
4,4'-DDT
Endrin
Endrin Aldehyde
Endrin Ketone
DDT Breakdown
Endrin Breakdown
D D T \ E N D R I N 8 R E A K D 0 \I N
Analysis Batch # CHGC1B50905120001
Date Analyzed 09/05/95 17:21
Area Counts 'x.
3751
1861
240088
283005
4868
8414
2.28
4.48
Specification
Limits
'x.
20
20
\Jerk Order I 9508435
Page~
Instrument GC1B
Analyst HAW
Reviewer ~HJ~D __ _
09/07/95 13:44:34
Method Pesticides/PCBs by SW8080 Specification# 808S
Lab Sample JD
Fi le JD
- -
Project Sample
ID/Description Analyte
- - - - -
ANALYTICAL PROTOCOL SUMMARY
COMMENTS/NARRATIVE
Flag CCJ0111ent/Narrative Corrective Action
Work Order I 9508435
Page !!.§__
- - - -.. - -... -·-- -
-·--
09/07/95 08:21:19
- --------------
RADIAN ANALYTICAL SERVICES
F P A S R E P 0 R T
Report Form
Work Order Sunmary
Flag Definitions
TABLE OF CONTENTS
Client HAMILTON BEACH
facility WASHINGTON NC
Client Code HAM BEACH NC
Analytical Batch ID
Protocol Sunmary for Herbicides by SW8150
Results Sunmary
Initial Calibration
Extraction Batch Sunmary
Analys·is Batch Sunmary CHGC5A50905120001
Results
Laboratory Blank Information
Laboratory Control Samples
Matrix Spikes
Calibration Verification
Analysis Batch Sunmary CHGC5B50905120001
Results
Laboratory Blank Information
Laboratory Control Samples
Matrix Spikes
Calibration Verification
Conments/Narrative
Work Order # 9508436
cectifi'" By&~
Date o/-'o -c(J
?
Pages
From To
1 1
2 2
3 3
4 4
5 8
9 9
10-10
11 12
13 13
14 14
15 15
16 17
18 18
19 20
21 21
22 22
23 23
24 25
26 26
-
-- - - -
09/07/95 08:21:19
Report RADIAN CORPORATION
To 3200 E." CHAPEL HI LL RD.
P.O. BOX 13000
Attention JIM NARKUNAS
Phone ~R~TP'------------
Prepared
By
Radian Analytical Services
14046 Sunmit Dr., Bldg. B
P. 0. Box 201088
Austin, TX 78720-1088
512/244-0855
CSC JALINDSEY
-
Project Sample ID/
Description
STKPILE
TBLK953699
STKPILE
STKPI LE .
-- -- -
MORK ORDER su""ARY
Client Code HAM BEACH NC
Client HAMILTON BEACH
facility WASHINGTON NC
Work ID WASHINGTON.NC
Case # '"'"NA;..;.._ _____ _
SDG # .:..:;NAc:.._ _____ _
RAS# 50811AJAL
Lab Sample ID Test Code(s)
01A LEACHATE 351SWAOO
815SWBTC
CK1SWAOO
02A LEACHATE 351SWAOO
815SWl.s;L
CK1SWAOO
03A LEACHATE MS 351SWAOO
815SWBMS
CK1SWA00
04A LEACHATE MSD 351SWAOO
815SWBMS
CK1SWA00
- -- ---
Work Order # 9508436
Page _1 _
RCN 650-138-02-01
Method Desciption
Sep-funnel Extract. SW846
Herbicides by SW8150
Primary KD cone. S\.1846
Sep-funnel Extract. S\.1846
Herbicides by SW81~0
Primary KD cone. S\.1846
Sep-funnel Extract. S\.1846
Herbicides by S\.18150
Primary KO cone. SW846
Sep-funnel Extract. SW846
Herbicides by S\.18150
Primary KD cone. SW846
--
-
09/07/95 08:21:19 ANALYTICAL PROTOCOL SUMMARY
Flag
( DL
NA
NC
ND
NR
NS
B
c
E
F
H
I
J
K
H
p
Q
R
s
T
x
y
z
-
F L A G D E F I N I T I 0 N S
Definition
Result less than stated Detection Limit and greater than or equal to zero.
Analyte concentration not available for this analysis.
RPD and/or X Recovery not calculated. See Narrative for explanation.
Not detected. No instrument response for analyte or result less than zero.
Not reported. Result greater than or equal to stated Detection Limit and less than specified Reporting Limit.
Analyte not spiked.
Analyte detected in method blank at concentration greater than the Reporting Limit (and greater than zero).
Confirming data obtained using second GC column or GCHS.
Analyte concentration exceeded calibration range.
Interference or coelution suspected. See Narrative for explanation.
Presence of analyte previously confirmed by historical data.
Analyte identification suspect. See Narrative for explanation.
Result is less than stated Detection Limit but greater than or equal to specified Reporting Limit.
Peak did not meet method identification criteria. Analyte not detected on other GC column.
Result modified from previous Report. See Narrative for explanation.
Analyte not confirmed. Results from primary and secondary GC columns differ by greater than a factor of 3.
QC result does not meet tolerance in Protocol Specification.
Result reported elsewhere.
Analyte concentration obtained using Method of Standard Additions CMSAl.
Second column confirmational analysis not performed.
See Narrative for explanation.
See Narrative for explanation.
See Narrative for explanation.
-- ---- - ---- -
Work Order # 9508436
Page L
-- - --
- -
....
09/07/95 08:21:19
Client HAMILTON BEACH
Facility \.IASHINGTON NC
Client Code HAM BEACH NC
Method Herbicides by S\.18150
-
Project Sample ID/Description
STKPilE
STKPILE
TBLK953699
TBLK953699
--------
ANALYTICAL PROTOCOL SUMMARY
Specification# .::;.8.:...:15:.:::Sc..-::...D ____ _
- -
--
\.lork Order # 9508436
PageL
Extraction/Digestion
Lab Sample ID Test Codelsl Batch # Analysis Batch #
9508436-0lA 815S\.IBTC 3510950831093500 CHGC5A50905120001
9508436-0lA 815S\.IBTC 3510950831093500 CHGC5B50905120001
9508436-0ZA 815S\.IBTC 3510950831093500 CHGC5A50905120001
9508436-0ZA 815S\.IBTC 3510950831093500 CHGC5B50905120001
--
-
09/07/95 08:21:19
Method Herbicides by S\.18150
Test Code 815SWBTC
Project Sample ID:
Lab ID:
Fi Le ID:
Date Col Lected:
Date Prepared:
Date Analyzed:
Di Lution Factor:
Matrix:
Uni ts:
Report as:
Column:
Analyte
2,4-D
2,4,5-TP (Silvex)
Surrogate Cs)
2,4-Dichlorophenylacetic acid
-... -
STKPILE
9508436-0lA LEACHA
I55IE15
08/29/95
08/31/95
09/05/95 22: 17
1.00
Water
ug/L
received
PRIMARY
Cone. DL
NO 3.00
ND 0.421
Recovery
'X.
98
.. -
RESULTS SUMMARY
STKPILE
9508436-01A LEACHA
J55IE15
08/29/95
08/31/95
09/05/95 22: 17
1.00
Water·
ug/L
received
SECONDARY
Cone. OL
ND 2°. 58
NO 0.237
Recovery
'X.
91
-.. .. -
TBLK953699
9508436-02A LEACHA
I55IE20
08/29/95
08/31/95
09/06/95 00:47
1.00
Water
ug/L
received
PRIMARY
Cone. OL
NO 3.03
NO 0.425
Recovery
'X.
96
\.lark Order # 9508436
Page.i_
TBLK953699
9508436-02A 0LEACHA
J55IE20
08/29/95
08/31/95
09/06/95 00:47
1.00
Water
ug/L
received
SECONDARY
Cone. OL
NO 2.60
NO 0.239
Recovery
'X.
90
--- - ----
-.. -- ---
09/07/95 08:21:19
Sol 'n #
~~-~-~~~-~--~~-~~~
Method Herbicides by s~8150
Test Code 815S~BT1
Response Response
Area Counts Area Counts
Reference Reference
Cone. Cone.
Analytes ug/L ug/L
2,4-D 100298 188297
60 120
2,4-DB 48544 84891
50 100
2,4,5-T 63052 126186
10 20
2,4,5-TP (Silvexl 65155 132781
10 20
Dalapon 111291 198982
60 120
Oicamba 72510 140230
15 30
Dichloroprop 53117 101573
35 70
Dinoseb 97756 185932
15 30
MCPA 69222 114835
10000 20000
MCPP 48699 91251
10000 20000
---.. ··-
I N I T I A l CALIBRATION
Initial Calibration# GC5A950804120000
Calibration Date 08/04/95 12:00:00
Response Response Response
Area Counts Area Counts Area Counts
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
340342 775848 3188525
240 600 3000
167686 319639 584912
200 400 800
237251 583711 2418303
40 100 500
256926 626376 2681241
40 100 500
344781 775689 2733788
240 600 3000
261095 620936 2515721
60 150 750
183088 397570 1639032
140 350 1750
339497 785581 3318887
60 150 750
213326 373640 663445
40000 80000 160000.
166212 299468 547861
40000 80000 160000
Response
Area Counts
Reference
Cone.
ug/L
5506610
6000
728641
1000
4417779
1000
4786264
1000
3513233
6000
4370845
1500
2816571
3500
5587488
1500
794779
200000
647761
200000
Specification Limits XRSD < 20X or correlation coefficient~ 0.995
.... _ ... -
Response
Reference
Cone.
\.lork Order I 9508436
Page L
Instrument GC5A
Analyst TCN
Reviewer ~M~JD~--
Correl at ion -
RF X RSD Coefficient
0.000791 24.0 1.000
0.00123 10.5 1:000
0,000182 15.6 1.000
0.000169 14.3 1.000
0.000903 48.8 1.000
0,000256 21. 1 1.000
0.000884 26.1 1.000
0,000196 22.3 1.00
0.202 20.3 1.000
0.256 16.0 1.000
-
--.. -.. .. ..
09/07/95 08:21:19
Sol 'n # ~~-~~~--~~--~-~~~-
Method Herbicides by S~8150
Test Code 815S~BT1
Response Response
Area Counts Area Counts
Reference Reference
Cone. Cone.
Analytes ug/L ug/L
2,4-D 110639 .210575
60 120
2,4-DB 55495 102385
-50 100
2,4,5-T 82543 157763
10 20
2,4,5-:TP (Sil vexl 81155 159134
10 20
Dalapon 116083 243125
60 120
Dicamba 72283 145478
15 30
Dichlor'oprop 57108 113461
35 70
Dinoseb 141941 257321
15 30
MCPA 85275 137956
10000 20000
;
MCPP 47055 87918
10000 20000
-... -.. '!Ill -
I N I T I A L CALIBRATION
Initial Calibration# GC5B950804120000
Calibration Date 08/04/95 12:00:00
Response Response Response
Area Counts Area Counts Area Counts
Reference Reference Reference
cone. Cone. Cone.
ug/L ug/L . ug/L
376257 924673 3415028
240 600 3000
201924 406649 737462
200 400 800
290807 686480 2636814
40 100 500
292817 686059 2709469
40 100 500
416407 931538 3488401
240 600 3000
263545 619844 2385629
60 150 750
206080 452913 1783916
140 350 1750
466653 1012638 3703293
60 150 750
244204 457528 849132
40000 80000 160000
16941,0 33H57 640923
40000 80000 160000
Response
Area Counts
Reference
Cone.
ug/L
5885247
6000
937002
1000
4653444
1000
4717314
1000
4972093
6000
4214496
1500
2996203
3500
5866644
1500
1080846
200000
772994
200000
Specification Limits 'X.RSD < 20'X. or correlation coefficient~ 0.995
-.. -...... -
Response
Reference
Cone.
~ork Order I 9508436
Pagel_
Instrument GC5B
Analyst TCN
Reviewer '"'MJ""D'----
Correlation -RF 'X. RSD Coefficient
0.000716 26.5 1.000
0.00100 6.69 0.999
0.000156 24.5 1.000
'
0.000154 23.4 1.000
0.000716 38.3 1.000
0.000259 23.9 1.000
0.000805 27.9 1.000
0.000159 36.6 1.000
0.162 16.7 1.000
0.237 6.87 1.000
__ .. .. .......
09/07/95 08:21:19
Project Sample ID .::S..:.TK'°'P'-'I'-'=L'-"E'---------
Lab Sample ID 9508436-0lA LEACHA
Fi le # .:.l.:<.:55~I""E-'-'15"-----
Method Herbicides by S\48150
Test Code 815SWBTC
Analyte CAS I
2,4-D 94-75-7
2,4,5-TP (Si lvex> 93-72-1
Surrogate Cs) CAS #
.. .. ... _ ..
RESULTS
Extraction Batch # 3510950831093500
Analysis Batch # CHGC5A50905120001
TCLP Batch # TCTCLP508281645
..
Date Collected 08/29/95 Instrument GC5A
Date Received 08/23/95 Column PRIMARY
Date Prepared 08/31/95 . Analyst LOB
Date Analyzed 09/05/95 22:17 Reviewer MJD
Aliquot Hass/Volume
118 Cmll
Extract/Digestate Volume
10 Cmll
Dilution Factor 1.00
Measured Concentration
ug/L
ND
ND
Spiked
Cone. Measured Concentration
ug/L ug/L
2,4-Dichlorophenylacetic acid 19719-28-9 72.0 70.7
-.. .. -· 91> .. ·-
Work Order # 9508436
Page lL
Reporting Subset _ Matrix H
Spikes Subset_ Report As received
Specs Subset i Moisture
Detection Limit Reporting Limit
ug/L ug/L
3.00 0
0.421 0
Specification Limits
Recovery Luw High
i i i
98 50 150
-
09/07/95 08:21:19
Project Sample ID .:.T.:::.BL"-'K;.:.9.:.5::.:36::.:9..!.9 _____ _
Lab Sample ID 9508436-02A LEACHA
Fi le I -=-I5""'5'"""I""'E=20"------
Method Herbicides by SY8150
Test Code 815SYBTC
Analyte CAS I
2,4-D 94-75-7
2,4,5-TP (~i lvex) 93-72-1
surrogate(sl CAS I
RESULTS
Extraction Batch I 3510950831093500
Analysis Batch I CHGC5A50905120001
Date Collected 08/29/95 Instrument GC5A
Date Received 08/23/95 Column PRIMARY
Date Prepared 08/31/95 Analyst LOB
Date Analyzed 09/06/95 00:47 Reviewer HJD
Aliquot Mass/Volume
117 (ml)
Extract/Digestate Volume
10 (ml)
Dilution Factor 1.00
Measured Concentration
ug/L
ND
ND
Spiked
Cone. Measured Concentration
ug/L ug/L
2,4-Dichlorophenylacetic acid 19719-28-9 72.6 69.4
-.. ...... -.. -·-..
Work Order I 9508436
Page 1L
Reporting Subset _ Matrix !t
Spikes Subset_ Report As received
Specs Subset _ 'X. Moisture
'
Detection Limit Reporting Limit
ug/L ug/L
3.03 0
0.425 0
Specification Limits
Recovery Low High
'X. 'X. 'X.
96 50 150
-.... _ ...... _
-.. .. ....
09/07/95 08:21:19
Lab Sample ID BLK953711 B
Fi le # """!=55"-"I-=E"'-'12=-----
Method Herbicides by S~8150
Test Code 815S~BTC
2,4-D
2,4,5-TP
Analyte
(Si lvexl
Surrogate Cs)
.. ....... ,, . .. .... -.... -
LABORATORY BLANK INFOR"ATION \.lork Order I 9508436
Page .1L
Extraction Batch # 3510950831093500
Analysis Batch'# CHGC5A50905120001
TCLP Batch # TCTCLP508281645
Date Prepared 08/31/95 Instrument GC5A
Date Analyzed 09/05/95 20:46 Column PRIMARY
Analyst JJm
Reviewer .:.;H::;JD"----
Aliquot Mass/Volume
1000 Cmll
Extract/Dig~state Volume
10 Cmll
Dilution Factor 1.00.
Reporting Subset _
Spikes Subset
Specs Subset
Matrix H
Measured Cone. Detection Limit Reporting Limit
ug/L ug/L ug/L
ND 0.354 0
ND 0.0497 0
Specification Limits
Spiked
Cone. Measured Cone. Recovery Low High
ug/L ug/L " i "
2,4-Dichlorophenylacetic acid 8.50 6.85 81 50 150
09/07/9S 08:21:19
Method Herbicides by SW81SO
Test Code 81SSWBTC
Control Std. # Vol. Added
SP-1-S32 .!illL .!:!!:._
SP-1-618 .!illL .!:!!:._
----
Analyte
2,4-D
2,4,S-TP (Si lvex)
Surrogate<s>
2,4-Dichlorophenylacetic acid
-......
LABORATORY CONTROL SAMPLE
Extraction Batch # 3S109S0831093SOO
Work Order # 9S08436
Page 1.i_
Analysis Batch # CHGCSAS090S120001
Date Prepared ·o8/31/9S Instrument GCSA
Column PRIMARY
Analyst LDB
Reviewer '"'MJ=D'----
Reporting Subset _ _ Matrix ~
Date Analyzed 09/0S/9S 21:47
Surrogate Sol'n # vo'l. Added LCS
SP-1-637 .1illL .!:!!:._ Lab Sample ID
LCS9SS68S K ----Fi le ID ISSIE13 ----
Spiked ~·easured
Cone. Cone. Rec.
ug/L ug/L x
2.00 1. 74 87
2.00 1.78 89
8.SO 7.77 91
..... .........
Spikes Subset _ _ Report As received
Specs Subset _ _ X Moisture
LCS Duplicate
Lab Sample ID
LCSD9SS68S
Fi le ID ISSI E14
Spiked Measured
Cone. Cone.
ug/L ug/L
2.00 1.66
2.00 1.67
8.SO 7.50
Aliquot Hass or Vol 1000 (ml)
Extract Hass or Vol · ---'1=0 <mll
Recovery
Spec •
Limits RPD
' Spec.
Rec. Low High Result Limit
x x t. x x
83 so lSO 4.7 50
83 so lSO 7.0 50
88 so lSO
-...... , .... _
09/07/95 08:21:19 CONTINUING(OR DAILY) CALIBRATION \Jork Order I 9508436
Page~
Lab Sample ID 815 STOA TC
Fi le# !55JE10
Method Herbicides by SW8150
Test Code 815SWBTC
Analyte
2,4-D
2,4,5-TP (Silvexl
Surrogate Cs)
2,4-Dichlorophenylacetic acid
V E R I F I C A T I 0 N
Analysis Batch # CHGC5A50905120001
Initial Calibration# GC5A950804120000
Date Analyzed 09/05/95 19:46
Measured Reference
Concentration Concentration
ug/L ug/L
589 600
101 100
Reporting Subset _
Spikes Subset _
Specs Subset _
Recovery
. "
98
101
Recovery
Instrument GC5A
Analyst LOB
Reviewer _M_JD __ _
Specification
Limits
Low High
" "
85 115
85 115
I 251 .I 250 I 100 I 85 1.. 115
-.. ~ .. ............... -............ ,: .. _
09/07/95 08:21:19
Method Herbicides by S\48150
Test Code 815S~BTC
Initial Calibration# GC5B950804120000
Calibration Date """08""'/""""0""4/'""'9""""5 ___ _
Sequence/Analysis Time
1 09/05/95 15: 14
2 09/05/95 15:44
3 09/05/95 16:15
4 09/05/95 16:45
5 09/05/95 17: 15
6 09/05/95 17:45
7 09/05/95 18:15
8 09/05/95 18:46
9 09/05/95 19:16
10 09/0~/95 19:46
11 09/05/95 20:16
12 09/05/95 20:46
13 09/05/95 21: 17
14 09/05/95 21:47
15 09/05/95 22:17
16 09/05/95 22:47
17 09/05/95 23:17
18 09/05/95 23:47
19 09/06/95 00:17
20 09/06/95 00:47
21 09/06/95 01: 18
22 09/06/95 01:48
23 09/06/95 02:18
24 09/06/95 02:48
AlllALYSIS BATCH SUMMARY
Analysis Batch # CHGC5B50905120001
Analysis Start Date/Time 09/05/95 12:00:00
Analysis Stop Date/Time
Work Order # 9508436
Page .1!L
InstnJ11ent GC5B
Analyst LOB
Reviewer .... M.._.JD"--------
Project Sample ID Lab Sample ID Sample Type Analysis File I
PRIMER CP Initial Calibration J55I E1
HB BC Laboratory Blank J55IE2
815 STOA TC Continuing Calibration Check J55!E3
HB BC Laboratory Blank J55IE4
HB BC Laboratory Blank J55IE5
HB BC Laboratory Blank J55IE6 -HB BC Laboratory Blank J55IE7
HB BC Laboratory Blank J55IE8
HB BC Laboratory Blank J55IE9
815 STOA TC Continuing Calibration Check J55! E10
DER. BLK BR Laboratory Blank J55IE11
BLK953711 B Laboratory Blank J55!E12 '
LCS955685 K Lab Control Sample J55IE13
LCSD955685 Lab Control Sample OUp J55IE14
STKPILE 9508436-0lA Sample J55IE15
HB BC Laboratory _Blank 1551 E16 -STKPILE 9508436-03A Matrix Spike J~51E17
STKPILE 9508436-04A Matrix Spike Dup J55IE18
HB BC Laboratory Blank J55IE19
TBLK953699 9508436-02A Sample J55IE20
HB BC Laboratory Blank J55I E21
ALIQUOT CC Initial Calibration J55!E22
HB BC Laboratory Blank J55JE23
815 STOA TC Continuing Calibration Check J55IE24
-· .. ., .. . ....... -.... -......... _ .. _ .. _
---.. ... .. ~ .... ........ ..
09/07/95 08:21:19
Project Sample ID "'"S"'""TK""P-'I'""L-=E _______ _
Lab Sample ID 9508436-0lA LEACHA
Fi le # -.J"-'55'""'1-=E-'"'15'-----
Hethod Herbicides by S~8150
Test Code 815S~BTC
, Analyte CAS #
2,4-D 94-75-7
2,4,5-TP (Silvexl 93-72-1
Surrogate(s) CAS #
RESULTS
Extraction Batch # 3510950831093500
Analysis Batch # CHGC5B50905120001
TCLP Batch # TCTCLP508281645
Date Collected 08/29/95
Date Received 08/23/95
Date Prepared 08/31/95
Date Analyzed 09/05/95 22:17
Instrument GC5B
Column SECONDARY
Analyst LOB
Reviewer HJD ----
Aliquot Hass/Volume
118 (ml)
Extract/Digestate Volume
10 (ml)
Dilution Factor 1.00
Measured Concentration
ug/L
ND
ND
Spiked
Cone. Measured Concentration
ug/L ug/L
2,4-Dichlorophenylacetic acid 19719-28-9 72.D 65.7
.. .. ( .... ....
Work Order # 9508436
Page .12_
Reporting Subset_ Matrix ~ '
Spikes Subset _
Specs Subset
:
Detect ion Limit
ug/L
2.58
0.237
Recovery
i
91
Report As received
i Moisture
Reporting Limit
. ug/L
0
D
-
Specification Limits
Low High
i i
50 150
-
- -
.. ... .. ._ .... ....... ........ ..
09/07/95 08:21:19
Lab Sample ID BLK953711 B
Fi le# =J5o.:5:.:I..:.E.:..::12,__ __ _
Hethcxl Herbicides by SW8150
Test Ccxle 815SWBTC
2,4-D
2,4,5-TP
Analyte
(Silvex)
Surrogate(s)
L A B 0 R A T 0 R ·y B L A N K I N F 0 R M A T I 0 N \.Jork Order # 9508436
Page n_
Extraction Batch # 3510950831093500·
Analysis Batch # CHGC5B50905120001
TCLP Batch I TCTCLP508281645
Date Prepared 08/31/95 Instrument GC5B
Date Analyzed 09/05/95 20:46 Collll10 SECONDARY
Analyst LOB
Reviewer .;..;H=JD'----
Aliquot Hass/Volume
1000 (ml)
Extract/Digestate Volume
10 <mll
Dilution Factor 1.00
Reporting Subset _
Spikes Subset _
Specs Subset_
Matrix ~
Measured Cone. Detection Limit Reporting Limit
ug/L ug/L ug/L
ND 0.304 0
ND 0.0280 0
. Specification Limits
Spiked
Cone. Measured Cone. Recovery Low High
ug/L ug/L x x x
.
2,4-Dichlorophenylacetic acid 8.50 7. 11 84 50 150
.. .....
09/07/95 08:21:19
Method Herbicides by SW8150
Test Code 815SWBTC
Control Std. # Vol. Added
SP-1-532 lQ!L !!.h._
SP-1-618 lQ!L !!.h._
----
Analyte
2,4-D
2,4,5-TP (Si lvex)
Surrogate(s)
2,4-Dichlorophenylacetic acid
LABORATORY CONTROL SAMPLE
Extraction Batch # 35109r·0831093500
\./ork Order # 9508436
Page ll_
Analysis Batch # CHGC5B50905120001
Date Prepared 08/31/95
Date Analyzed D9/05/95 21:47
Surrogate Sol'n I Vol. Added
SP-1-637 lQ!L~
--------
Instrument GCSB
Column SECONDARY
Analyst 1Q!:!
Reviewer '""HJ-.D'----
LCS
Lab Sample ID
LCS955685 K
Fi le ID J551 E13
Spiked Measured
Cone. Cone.
ug/L ug/L
2.00 1. 71
2.00 1. 73
8.50 8.01
Reporting Subset__ Matrix }!
Rec.
t
85
87
94
Spikes Subset __ Report As received
Specs Subset _ _ i Moisture
LCS Oupl icate
Lab Sample ID
LCSD955685
Fi le ID J55I E14
Spiked Measured
Cone. Cone.
ug/L ug/L
2.00 1.60
2.00 1.63
8,50 7.39
Aliquot Hass or Vol
Extract Hass or Vol
Recovery
Spec.
Limits
Rec. Low High
i t i
80 50 150
82 50 150
87 50 150
_ _..;..;1 o_o=o <mu
__ _,lc.::O (mll
RPO
Spec.
Result Limit
i 1
6, 1 so
5.9 50
- -
... -.... , .... .... .. ..... _ .. --....
09/07/95 08:21:19 ANALYTICAL PROTOCOL SUMMARY
COMMENTS/NARRATIVE
Method Herbicides by SW8150 Specification# 815S-D
Lab Sample ID
Fi le ID
--
Project Sample
IO/Description Analyte
.. -.. .•
Flag Conrnent/Narrative Corrective Action
.. .. .... -,-_., .. ,-
Work Order I 9508436
Page M._
-1-.. -
-.. ---..
08/31/95 15:55:10
Report RADIAN CORPORATION
To 3200 E. CHAPEL HILL RD.
P.O. BOX 13000
Attention JIM NARKUNAS
Phone ~R~T~P ____________ _
Prepared Radian Analytical Services
By 14046 Summit Dr., Bldg. B
P. 0. Box 201088
Austin, TX 78720-1088
512£'.244-0855
csc JALINDSEY
Project Sample ID/
Description
STKPILE
TBLK953699
STKPILE
-.. --WORK ORDER SUMMARY
Client Code HAM BEACH NC
Client HAMILTON BEACH
Facility WASHINGTON NC
Work ID WASHINGTON,NC
Case fl ~N~A~--------
SDG fl _N_A _______ _
RAS # 50811AJAL
Lab Sample ID Test Code(s)
OlA LEACHATE DGTSWAOO
ICTSWSLO
02A LEACHATE DGTSWAOO
ICTSW5LO
03A LEACHATE_MS DGTSWAOO
ICTSWSLO
04A LEACHATE_MSD DGTSWAOO
ICTSWSLO
.. -.. .. - -
Digestion
Metals by
Digestion
Metals by
Digestion
Metals by
Digestion
Metals by
Work Order # 9508437
Page _1_
RCN 650-132-0l-02i
Method Desciption
by SW846
ICP
by SW846
ICP
by SW846
ICP
by SW846
ICP
.. -
-
08/31/95 15:55:10 ANALYTICAL PROTOCOL SUMMARY
Flag
l'liAG DBFillITIOHS
Definition
Result less than stated Detection Limit and greater than or equal to zero.
Analyte concentration not available for this analysis.
RPO and/or % Recovery not calculat~d. See Narrative for explanation.
Not detected. No instrument response for analyte or result less than zero.
< DL
NA
NC
ND
NR
NS
Not reported. Result greater than or equal to stated Detection Limit and less than specified Reporting Limit.
Analyte not spiked.
-
B
c
E
F
H
I
J
K
Analyte detected in method blank at concentration greater than the Reporting Limit (and greater than zero) .
Confirming data obtained using second GC column or GCMS.
Analyte concentration exceeded calibration range.
Interference or coelution suspected. See Narrative for explanation.
Presence of analyte previously confirmed by historical data.
Analyte identification suspect. See Narrative for explanation.
Result is less than stated Detection Limit but greater than or equal to specified Reporting Limit.
Peak did not meet method identification criteria. Analyte not detected on other GC column.
M Result modified from previous Report. See Narrative for explanation.
P Analyte not confirmed. Results from primary and secondary GC columns differ by greater than a factor of 3.
Q QC result do7s not meet tolerance in Protocol Specification.
R Result reported elsewhere.
S Analyte concentration obtained using Method of Standard Additions (MSA) .
T Second column confirmational analysis not performed.
X See Narrative for explanation.
Y See Narrative for explanation.
Z See Narrative for explanation .
.. - ----.. .. .. .. -..
Work Order # 9508437
Page L
-.. ---
-- -
..
08/31/95 15:55:10
Client HAMILTON BEACH
Facility WASHINGTON NC
Client Code HAM BEACH NC
Method Metals hy ICP
-·-.. .. .. --..
ANALYTICAL PROTOCOL SUMMARY
Specification # =I~C=T~S'--------~
Extraction/Digestion
Project Sample ID/Description Lab Sample ID Test Code(s) Batch #
STKPILE 9508437-0lA ICTSW5LO IDIG950829080000
.. --Work Order # 9508437
Page _3_
Analysis Batch #
EMJ61E50830190001
--
-
08/31/95 15:55:10
Method ICP Analysis by SW6010A
Test Code ICTSW5LO
Project Sample ID:
Lab ID:
File IO:
Date Collected:
Date Prepared:
Date Analyzed:
!Jilut.irm F<Jc:tor:
Matrix:
Units:
Report as:
Column:
Analyte
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
--- -
RESULTS
STKPILE
9508437-0lA LEACHA
J61E0830-20
08/29/95
08/29/95
08/30/95
1
Water
mg/L
received
Cone. DL Cone.
0.00234 BJ 0.00313
0.270 B 0.000780
0.00572 B 0.000230
0.00190 B 0.000510
0.0366 0.00116
0.00924 0.00203
-0.000030 BJ 0.00111
----
SUMMARY
DL Cone. DL
---\-
work Order # 9508437
Page _4_
Cone. DL
.. -- --
----08/31/9S lS:SS:lO
Method Digestion by SW846
Test Code DGTSWAOO
Sample
1
2
3
4
s
6
7
8
9
10
11
12
13
14
lS
16
17
18
19
20
Quality Control
Blank
Matrix Spike
Matrix Spike Duplicate
Matrix Spike
Matrix Spike Duplicate
Laboratory Control Sample
Laboratory Control Sample Duplicate
---.. -.. .. -- ---DIGESTION BATCH SUMMARY
Digestion Batch # IDIG950829080000
Extraction Start Date/Time OB/29/9S 08:00:00
Extraction Stop Date/Time
Project Sample ID Lab Sample ID
9S08472-01A
STKPILE 9S08437-01A
TBLK 9S08437-02A
9S08466-01A
Project Sample ID Lab Sample ID
BLK9S3707
9S08472-02A
9S08472-03A
STKPILE 9S08437-03A
STKPILE 9S08437-04A
t.CS9S5681
LCSD95S681
Work Order # 9S08437
Page _s_
Analyst CMB
Reviewer ~---------
'
Sample Size
mL Cleanup Method
so
so
so
so
Sample Size
mL Cleanup Method
so
so
so
so
so
so
so
-
-
08/31/95 15:55:10
Method Metals by ICP
Test Code ICTSW5LO
Initial Calibration ff ~N~A~~~~~~~­
Calibration Date ~N~A'---~~~~~~
ANALYSIS BATCll SUMMARY
Analysis Batch ff EMJ61E50830190001
Analysis Start Date/Time 08/30/95 19:00:00
Analysis Stop Date/Time 08/30/95 22:00:00
Work Order ff 9508437
Page _6 _
Instrument J61E
Analyst MCG
Reviewer ~~~~~~~~~-
Sequence/Analysis Time Project Sample ID Lab Sample ID Sample Type Analysis File ff
l 08/30/95 STD_2 Continuing Calibration Check J61E0830-l
3 08/30/95 CI CSA Continuing Calibration Check J61E0830-3
4 08/30/95 CICSAB Continuing Calibration Check J61E0830-4
5 08/30/95 CCV-1 Continuing Calibration Check J6,1E0830-5
7 08/30/95 CCV-2 Continuing Calibration Check J61E0830-7
9 08/30/95 CCB Laboratory Blank J61E0830-9
10 08/30/95 BLK953707 Laboratory Blank J61E0830-10
11 08/30/95 LCS955681 Lab Control Sample J61E0830-11
12 08/30/95 LCSD955681 Lab Control Sample Dup J61E0830-12
14 08/30/95 9508472-0lA Serial Dilution J61E0830-14
15 08/30/95 9508472-0lA Sample J61E0830-15
16 08/30/95 9508472-0lA Spike J61E0830-16
17 08/30/95 9508472-02A Matrix Spike J61E0830-17
18 08/30/95 95084 72-03A Matrix Spike Dup J61E0830-18
20 08/30/95 STKPILE 9508437-0lA Sample J61E0830-20
21 08/30/95 STKPILE 9508437-0lA Spike J61E0830-21 •
22 08/30/95 STKPILE 9508437-03A Matrix Spike J61E0830-22
23 08/30/95 STKPILE 9508437-04A Matrix Spike Dup J61E0830-23
25 08/30/95 TBLK953699 9508437-02A Laboratory Blank J61E0830-25
26 08/30/95 CI CSA Continuing Calibration Check J61E0830-26
27 08/30/95 CICSAB Continuing Calibration Check J61E0830-27 ,
28 08/30/95 CCV-1 Continuing Calibration Check J61E0830-28
30 08/30/95 CCV-2 Continuing Calibration Check J61E0830-30
34 08/30/95 CCB Laboratory Blank J61E0830-34
-.. ------ ----- ---
------ --.. - --08/31/95 15:55:10 RH SULT S
Project Sample ID STKPILE
Lab Sample ID 9508437-0lA LEACHA
File # J61E0830-20
Method ICP Analx:sis by SW6010A
Test Code 1CTSW5J,O
Analyte CAS #
Arsenic 7440-38-2
Barium 7440-39-3
Cadmium 7440-43-9
Chromium 7440-47-3
Lead 7439-92-1
Selenium 7782-49-2
Silver 7440-22-4
Digestion Batch # IDIG950829080000
Analysis Batch # EMJ61E50830190001
TCLP Batch # TCTCLP9508281645
Date Collected 08[29[95 Instrument ~
Date Received 08[23[95 Column
Date Prepared 08[29[95 Analyst MCG
Date Analyzed 08[30[95 Reviewer PLS
Aliquot Mass/Volume
50 (tnL)
Extract/Digestate Volume
50 (tnL)
Dilution Factor 1
Measured Concentration
mg/L
0.00234 BJ
0.270 B
0.00572 B
0.00190 B
0.0366
0. 00924
~0.000030 BJ
.. ----Work Order # 9508437
Page ']__
Reporting Subset __ Matrix .!'.!'
Spikes Subset __ Report As received
Specs Subset __ % Moisture
Detection Limit Reporting Limit
mg/L mg/L
0.00313 -1000
0. 000780 -1000
0.000230 -1000
0.000510 -1000
0. 00116 -1000
0.00203 -1000
0. 00111 -1000
--
-
08/31/95 15:55:10
Lab Sample ID ~C~C~B'--------­
F i le # J61E0830-34
Method ICP Analysis by SW6010A
Test Code ICTSW5LO
Analyte
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
----
Date
Date
-
LABORATORY BLAH~ IHFORMATIOH
Digestion Batch #
Analysis Batch # EMJ61E50830190001
Prepared Instrument J61E Reporting Subset
Analyzed 08L30L95 Column Spikes Subset
Analyst MCG Specs Subset
Reviewer PLS
Aliquot Mass/Volume
(mL)
Kxlrdct/Uigestate Volume
(mL)
Dilution Factor 1
Measured Cone. Detection Limit
mg/L mg/L
-0.00278 J 0.00313
-0.000020 J 0.000780
-0.000100 J 0.000230
0.0000500 J 0.000510
-0.000420 J 0. 00116
0.000590 J 0.00203
0.000270 J 0.00111
--.. ---.. -
Work Order # 9508437
Page _8_
Matrix !'.!
Reporting Limit
mg/L
-1000
-1000
-1000
-1000
-1000
-1000
-1000
-----
---· --08/31/95 15:55:10
Lab Sample ID ,,,C:.:C::B'---------
File It J61E0830-9
Method ICP Analysis by SW6010A
Test Code ICTSW5LO
Analyte
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
-
Date
Date
-.. - -----LABORATORY BLANK INFORMATION
Digestion Batch #
Analysis Batch # EMJ61E50830190001
Prepared Instrument J61E Reporting Subset
Analyzed 08[30{95 Column spikes Subset
Analyst ~ Specs Subset
Reviewer PLS
Aliquot Mass/Volume
(mL)
Extract/Digestate Volume
(mL)
Dilution Factor 1
Measured Cone. Detection Limit
mg/L mg/L
-0.00125 J 0.00313
0.000150 J 0.000780
0.0000100 J 0.000230
-0.000060 J 0.000510
-0.000780 J 0. 00116
-0.000880 J 0.00203
0.00106 J. 0.00111
- -
Work Order # 9508437
Page _9_
Matrix Ji
'
Reporting Limit
mg/L·
-1000
-1000
-1000
-1000
-1000
-1000
-1000
-- -
-
08/31/95 15:55:10
Lab Sample ID ,,B,,,L,,,K"'9.::.5.::.3.:..7,,_07,:.._ ___ _
File # J61E0830-10
Method ICP Analysis by SW6010A
Test Code ICTSW5LO
Analyte
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Sil~er
--- -
Date
Date
-
LABORATORY BLANK INFORMATION
Prepared
Analyzed
-
Digestion Batch ff IDIG950829080000
Analysis Batch ff EMJ61E50830190001
081'.'.291'.'.95 Instrument J61E Reporting Subset
081'.'.301'.'.95 Column Spikes Subset
Analyst !.1£Q Specs Subset
Reviewer PLS
Aliquot Mass/Volume
50 (mL)
Extract/Digestate Volume
50 (mL)
Dilution Factor 1
Measured Cone. Detection Limit
mg/L mg/L
0.000990 J 0. 00313
0.000170 J 0.000780
0.0000300 J 0.000230
0.000150 J 0.000510
-0.000560 J o. 00116
-0.00230 J 0.00203
0.00174 0. 00111
----- -
..
Work Order # 9508437
Page lQ_
Matrix !i
Reporting Limit
mg/L
-1000
-1000
-1000
~1000
-1000
-1000
-1000
---
------------- --------08/31/95 15:55:10 LABORATO Ry B LANK IHFORMATI OH Work Order # 9508437
Page 1L
Digestion Batch # IDIG950829080000
Analysis Batch # EMJ61E50830190001
TCLP Batch II TCTCLP9508281645
Lab Sample ID 9508437-02A LEA CHA Date Prepared OBL29L95 Instrument J61E Reporting Subset Matrix !'.!
File U J61E0830-25 Date Analyzed OBL30L9S Column Spikes Subset
Method ICP Analysis by SW6010A Analyst MCG -Specs Subset
Test Code ICTSW5LO Reviewer PLS
Aliquot Mass/Volume
so (mL)
Extract/Digestate Volume
so (mL)
Dilution Factor 1
Measured Cone. Detection Limit Reporting Limit
Analyte mg/L mg/L mg/L
Arsenic -0.00102 J 0.00313 -1000
Barium 0.0215 0.000780 -1000
Cadmium 0.000430 0.000230 -1000
Chromium 0.000690 0.000510 -1000
Lead -0.000660 J 0.00116 -1000
Selenium 0.00793 0.00203 -1000
Silver 0.000840 J 0. 00111 -1000
08/31/95 15:55:10
Method ICP Analysis by SW6010A
Test Code ICTSW5LO
Control Std. ff Vol. Added
------
------
------
Ar1dlyte
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
----
LABORATORY CONTROL SAMPLE
Digestion Batch # IDIG950829080000
Analysis Batch # EMJ61E50830190001
Date Prepared 08/29/95-Instrument J61E Reporting Subset ----
Date Analyzed ~0~8~/~30~/~9~5.,_ ___ _ Column Spikes Subset ----
Analyst MCG Specs Subset ----
Reviewer PLS
Surrogate Sol'n ff Vol. Added LCS LCS Duplicate
------Lab Sample ID Lab Sample ID
t.C8955681 f,CSD955681 ------
File ID J61E0830-11 File ID J61E0830-12 ------
Spiked Measured Spiked Measured
Cone. Cone. Rec. Cone. Cone.
mg/L mg/L % mg/L mg/L
1. 00 1. 02 102 1. 00 1. 02
1. 00 1. 04 104 1. 00 1. 04
1. 00 0.990 99 1. 00 0.988
1. 00 0.999 100 1. 00 0.998
1. 00 0.979 98 1. 00 0.978
1. 00 0. 994 99 1. 00 0.997
1. 00 1. 04 104 1.00 1. 02
·work Order # 9508437
Page lL
Matrix !'.!.
Report As received
% Moisture
Aliquot Mass or Vol
Extract Mass or Vol
Recovery
Spec.
Limits RPO
Rec. Low High Result
\ % % %
102 80 120 0
104 80 120 0
99 80 120 0
100 80 120 0
98 80 120 0
100 80 120 1. 0
102 80 120 1. 9
50 (mL)
50 (mL)
Spec.
Limit
%
20
20
20
20
20
20
20
----- ---.. - -·----
------------.. --- - -08/31/95 15:55:10 MA'l'RIX SPIKB(S)
Digestion Batch II IDIG950829080000
Analysis Batch ti EMJ61ES0830190001
TCLP Batch ti TCTCLP9S0828164S
Project Sample ID ~S~T~K~P~I~L~E'----------­
Method ICP Analysis by SW6010A
Date Collected 08l29l95 Instrument ill.§_ Reporting Subset
Date Received OBl23l9S Column ·Spikes Subset
Test Code ICTSW5LO Date Prepared 08l29l95 Analyst MCG Specs Subset
Date Analyzed 08£'.'.30l95 Reviewer PLS
Spike Sol'n II Vol. Added Sample Spiked Sample Spiked Sample Dup
------Lab Sample ID Lab Sample ID Lab Sample ID
9508437-0lA LEACHA 9508437-03A LEACHA 9S08437-04A LEACHA ------
------File ti J61E0830-20 File II J61E0830-22 File II J61E0830-23
Surrogate Sol'n Vol. Added Aliquot Mass/Vol Aliquot Mass/Vol Aliquot Mass/Vol
50 (mL) so (mL) so (mL) ------
Extract ------Mass/Vol Extract Mass/Vol Extract Mass/Vol
so ------(mL) 50 (mL) so (mL)
Dil Fact. 1 Dil Fact. 1 Dil Fact. 1
Spike
Sol'n Measured Spiked Measured Spiked Measured
Analyte Cone. Cone. Cone. Cone. Rec. Cone. Cone. Rec.
mg/L mg/L mg/L mg/L · \ mg/L mg/L \
Arsenic 0.00234 BJ 0.0500 O.OS2S 100 0.0500 O.OS42 104
Barium 0.270 B l. 00 1.28 101 l. 00 1.28 101
Cadmium O.OOS72 B 0.0400 0.0438 9S 0.0400 0. 0449 98
Chromium 0.00190 B 0.0400 0.0432 103 0.0400 0.0432 103
Lead 0.0366 o.osoo 0.0851 97 0.0500 0.0866 100
Selenium 0.00924 o.osoo 0.0608 103 0.0500 0.0S94 100
Silver -0.000030 BJ 0.0400 0.0445 111 0.0400 0.0442 110
Work Order ti 9508437
Page 1L
Matrix !:l.
Report As
\ Moisture
Recovery
Specifi-
ca.ti on
Limits
Low High Result
\ \ \
80 120 3 .. 9
80 120 0
80 120 3.1
80 120 0
80 120· 3.0
80 120 3.0
80 120 0.90
received
RPD
Specifi-
cation
Limit
\
20
20
20
20
20
20
20
-
08/31/95 15:55:10
Project Sample ID
Method ICP Analysis by SW6010A
Test Code ICTSWSLO
Spike Sol'n II Vol. Added
------
------
------
Surrogate Sol'n Vol. Added
------
------------
Spike
Sol'n
Analyte Cone.
mg/L
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
--- --
MATRIX
Digestion Batch II
SPIKB(S)
IDIG950829080000
Analysis Batch II EMJ61E50830190001
TCTCLP9508280900
Date Collected
Date Received
Date Prepared
Date Analyzed
Sample
Lab Sample ID
9508472-0lA LEACHA
File II J61E0830-15
Aliquot Mass/Vol
50 (mL)
Extract Mass/Vol
50 (mL)
Oil Fact. 1
Measured
Cone.
mg/L
-0.000700 BJ
0.699 B
0.0135 B
0.00488 B
0.0734
0. 00145 J
TCLP Batch II
081'.281'.95
081'.241'.95
081'.29z'.95
08/301'.95
Instrument
Column ~----
Analyst
Reviewer ~P=L=S ___ _
Spiked Sample
Lab Sample ID
9508472-02A LEACHA
Reporting Subset
Spikes Subset
Specs Subset
Spiked Sample Dup
Lab Sample ID
9508472-03A LEACHA
File II J61E0830-17 File # J61E0830-18
Aliquot Mass/Vol Aliquot Mass/Vol
50 (mL) 50 (mL)
Extract Mass/Vol Extract Mass/Vol
50 (mL) 50 (mL)
Dil Fact. 1 Oil Fact. 1
Spiked Measured Spiked Measured
Cone. Cone. Rec. Cone. Cone. Rec.
mg/L mg/L t mg/L mg/L %
0. 0500 0.0468 95 0.0500 0.0451 92
1. 00 1.65 95 1. 00 1.62 92
0.0400 0.0519 96 0.0400 0.0517 95
0. 0400 0.0456 102 0.0400 0.0456 102
0.0500 0.120 94 0.0500 0.122 96
0.0500 0. 0493 96 0.0500 0.0495 96
Work Order II 9508437
Page .ll_
Matrix !!
Report As
t Moisture
Recovery
Specifi-
cation
Limits
Low High Result
% % t
80 120 3.2
80 120 3.2
80 120 1. 0
80 120 0
80 120 2.1
80 120 0
received
RPO
Specifi-
cation
Limit
t
20
20
20
20
20
20
0.00434 B 0.0400 0.0326 71 Q 0. 0400 0.0304 65 Q 80 120 8.8 20
- -- ----.. .. -I - - - -
----- -08/31/95 15:55:10
Lab Sample ID =c=c~v_-~1~~~
File # J61E0830-28
Method ICP Analysis by SW6010A
Test Code ICTSW5LO
Analyte
Cadmium
Lead
Selenium
Silver
----- --.. -- -CONTINUING(OR DAILY CALIBRATION Work Order # 9508437
Page ~ VERIFICATION
Analysis Batch # EMJ61E50830190001
Initial Calibration #
Date Analyzed ~O~B~/~3~0~/~9~5'--~~~-
Measured Reference
Concentration Concentration
mg/L mg/L
5.05 5.00
4.96 5.00
5.14 5.00
5.16 5.00
Reporting Subset ~­
Spikes Subset ~­
Specs Subset ~-
Recovery
%
101
99
103
103
Instrument ~
Analyst ~
Reviewer ~P~L~S~~~-
Recovery
Specification
Limits
Low High
% %
90 110
90 110
90 ~10
90 110
--
-
08/31/95 15:55:10
--
Lab Sample ID ~C~CIJ'"'--=l'--~~
File # J61E0830-5
Method ICP Analysis by SW6010A
Test Code ICTSW5LO
Analyte
Cadmium
Lead
Selenium
Silver
---
CONTINUIHG(OR DAILY) CALIBRATION Work Order # 9508437
Page li._ VERIFICATION
Analysis Batch # EMJ61E50830190001
Initial Calibration #
Date Analyzed ~0~8L/~3~0~/~95"--~~~~ Reporting Subset ~­
Spikes Subset ~­
Specs Subset ~-
Measured Reference
Concentration Concentration Recovery
mg/L mg/L \
4.99 5.00 100
4. 90 5.00 98
5.06 5.00 101
5.15 5.00 103
-------
Instrument ~
Analyst ~
Reviewer ~P=L=S~~~-
Recovery
Specification
Limits
Low High
\ %
90 110
90 110
90 110
90 110
.. -----
------08/31/95 15:55:10
Lab Sample Ip :::C:::C:.:V..:-.!'2'----
File # J61E0830-30
Method ICP Analysis by SW6010A
Test Code ICTSW5LO
Analyte
Arsenic
Barium
Chromium
---- --- ----CONTINUING OR DAILY CALIBRATION Work Order # 9508437
Page 11.... VERIFICATION
Analysis Batch # EMJ61E50830190001
Initial Calibration #
Date Analyzed ~0~8~/~3~0~/9~5"-----
Measured Reference
Concentration Concentration
mg/L mg/J,
5.16 5.00
5.10 5.00
4.94 5.00
Reporting Subset __
Spikes Subset __
Specs Subset __
Recovery
%
103
102
99
Instrument ~
Analyst ~
Reviewer ~P~L~S'-----
Recovery
Specification
Limits
Low High
\ \
90 110
90 110
90 110
--
-
08/31/95 15:55:10
--
Lab Sample ID ~c~c~v_-=2~~­
File # J61E0830-7
Method ICP Analysis by SW6010A
Test Code ICTSW5LO
Analyte
Arsenic
Barium
Chromium
- --
CONTINUING(OR DAILY) CALIBRATION work Order # 9508437
Page 1!!_ VERIFICATION
Analysis Batch # EMJ61E50830190001
Initial Calibration #
Date Analyzed ~0~8~/~30~/~9~5"---~--Reporting Subset ~­
Spikes Subset ~­
Specs Subset __
Measured Reference
Concentration Concentration Recovery .
mg/I, mg/L "
5.08 5.00 102
5.12 5.00 102
4.96 5.00 99
-------
Instrument J61E
Analyst MCG
Reviewer ~P=L~S-~~,...
Recovery
Specification
Limits
Low High
" "
90 110
90 110
90 110
.. -----
--- ---08/31/95 15:55:10
Lab Sample ID CICSAB
File # J6lE0830-27
Method ICP Analysis by SW6010A
Test Code ICTSW5LO
Analyte
Barium
Cadmium
Chromium
Lead
Silver
--- - ------ -
CONTINUING(OR DAILY CALIBRATION Work Order # 9508437
Page 12.... VERIFICATION
Analysis Batch # EMJ61E5083019000l
Initial Calibration #
Date Analyzed ~0~8~/~3~0/~9~5~~~~-
Measured Reference
Concentration Concentration
mg/L mg/L
0.530 0.481
0.958 0.969
0.517 0.471
0.961 0.926
l.10 0.948
Reporting Subset ~­
Spikes Subset ~­
Specs Subset ~-
Recovery
\
110
99
110
104
116
Instrument ~
Analyst Ms;;Q
Reviewer ~P=L=S~~~-
Recovery
Specification
Limits
Low High
\ \
80 120
80 120
80 120
80 120
80 120
--
-
08/31/95 15:55:10
-
Lab Sample ID CICSAB
File # J61E0830-4
Method ICP Analysis by SW6010A
Test Code ICTSW5LO
Analyte
Barium
Cadmium
Chromium
Lead
Silver
----
CONTIN.UING(OR DAILY) CALIBRATION · Work Order # 9508437
Page~ VERIFICATION
Analysis Batch # EMJ61E50830190001
Initial Calibration #
Date Analyzed ~0~8L/~3~0/~9~5"'--~~~-Reporting Subset ~­
Spikes Subset ~­
Specs Subset ~-
Measured Reference
Concentration Concentration Recovery
mg/L mg/L %
0.534 0.481 111
0.950 0.969 98
0.515 0.471 109
0.953 0.926 103
1.10 0.948 116
-------
Instrument ~
Analyst MCG
Reviewer ~P~L~S'--~~-
Recovery
Specification
Limits
Low High
\ \
80 120
80 120
80 120
80 120
80 120
.. -----
----- -08/31/95 15:55:10
Lab Sample ID =S~T~D'-"2'--~~
File # J61E0830-l
Method ICP Analysis by SW6010A
Test Code ICTSW5LO
Analyte
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
-----------COHTIHUIHG(OR DAILY CALIBRATION Work Order # 9508437
Page£!_ VERIFICATION
Analysis Batch # EMJ61E50830190001
Initial Calibration #
Date Analyzed ~0~8~/~3~0~/~95=--~~~~
Measured Reference
Concentration Concentration
mg/L mg/L
9.97 10.0
10.2 10.0
9.93 10.0
10.1 10.0
9.92 10.0
10.3 10.0
10.2 10.0
Reporting Subset ~­
Spikes Subset ~­
Specs Subset ~-
Recovery
\
100
102
99
101
99
103
102
Instrument J61E
Analyst MCG
Reviewer ~P~L~S=--~~-
Recovery
Specification
Limits
Low High
•\ \
95 105
95 105
95 105
95 105
95 105
95 105
95 105
--
08/31/95 15:55:10 AHALYTlCAL SPl~B(S
Digestion Batch # IDIG950829080000
Analysis Batch # EMJ61E5083019000l
Work Order # 9S08437
Page iL
Project Sample ID ~S~T~K~P~I=L~E'----------­
Method ICP Analysis by SW6010A
Date Collected 08L29L9S Instrument J61E Reporting Subset
Spikes Subset
Specs Subset
Matrix !f
Report As
% Moisture
Date Received 08L23L9S Column received
Test Code lCTSWSLO Date Prepared 08L29L9S Analyst !:1£2
Date Analyzed 08(3oL95 Reviewer PLS
Spike Sol'n fl Vol. Added Sample Spiked Sample Spiked Sample Dup
------Lab Sample ID Lab Sample ID Lab Sample ID
9S08437-01A LEACHA 9508437-0lA LEACHA ------
------File fl J61E0830-20 File ff J61E0830-21 File fl
Surrogate Sol' n Vol. Added Aliquot Mass/Vol Aliquot Mass/Vol Aliquot Mass/Vol
------so (mL) so (mL) Recovery
------Extract Mass/Vol Extract Mass/Vol Extract Mass/Vol 'Specifi-
so (mL) ------so (mL) cation
Dil Fact. 1 Dil Fact. 1. 0417 Dil Fact. Limits RPD
Spike Specifi-
Sol'n Measured Spiked Measured Spiked Measured cation
Analyte Cone. Cone. Cone. Cone. Rec. Cone. Cone. Rec. Low High Result Limit
mg/L mg/L mg/L mg/L % % '% % % %
Arsenic 0.00234 BJ O.OS2l 0.0613 113 7S l2S
Barium 0.270 B 1.04 1.33 101 7S 12S
Cadmium 0.00S72 B 0.0417 0.0486 103 7S 12S
Chromium 0.00190 B 0.0417 0. 0449 103 7S 125
Lead 0.0366 0.0521 0.0877 98 75 125
Selenium 0.00924 0.0521 0.0640 105 75 125
Silver -0.000030 BJ 0.0417 0.0467 112 7S 125 .
-------------------
--·---08/31/9S lS:SS:lO
Project Sample ID
Method ICP Analysis by SW6010A
Test Code ICTSWSLO
Spike Sol'n # Vol. Added
------
------
------
Surrogate Sol'n Vol. Added
------
------
------
Spike
Sol'n
Analyte Cone.
mg/L
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
---- --
Date
Date
Date
ANALYTICAL SPIKR(S
Digestion Batch # IDIG9S0829080000
Analysis Batch # EMJ61ES083019000l
Collected 08[28l'.9S Instrument
Received 08[24[9S Column
Prepared 08[29[9S Analyst MCG
-
~
--- - - -
Reporting Subset
Spikes Subset
Specs Subset
Work Order # 9S08437
Page ;u_
----Matrix !:!
----Report As
% Moisture ----
received
Date Analyzed 08[30[9S Reviewer PLS
Sample Spiked Sample Spiked Sample Dup
Lab Sample ID Lab Sample ID Lab Sample ID
9S08472-01A LEACHA 9508472-0lA LEACHA
File # J61E0830-1S File U J61E0830-16 File #
Aliquot Mass/Vol Aliquot Mass/Vol Aliquot Mass/Vol
so (mL) so (mL) Recovery
Extract Mass/Vol Extract Mass/Vol Extract Mass/Vol Specifi-
so (mL) so (mL) cation
Dil Fact. 1 Dil Fact. 1. 0417 Dil Fact. Limits RPD
Spedf i-
Measured Spiked Measured Spiked Measured cation
Cone. Cone. Cone. Rec. Cone. Cone. Rec. Low High Result Limit
mg/L mg/L mg/L % % % % % %
-0.000700 BJ O.OS2l 0.0S81 113 7S 12S
0.699 B 1. 04 1. 78 103 7S 12S
0. 013S B 0.0417 0. OS49 99 7S 12S
0.00488 B 0.0417 0.0484 105 75 125
0.0734 0.0S21 0.12S 100 7S 12S
0. 00l4S J 0.0521 0. OS40 101 7S 12S
0.00434 B 0.0417 0.0486 106 7S 12S
-
08/31/95 15:55:10
Project Sample ID
Method ICP Analysis by SW6010A
Test Code ICTSW5LO
Analyte
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
-----
SERIAL DILUTION CHBC~
Digestion Batch #
Analysis Batch #
Date Prepared ~0~8~/:2~9~/~9~5 ____ _
Date Analyzed ~0~8~/~3~0/~9~5"---~~-
Sample Result
Lab Sample ID
9508472-0lA LEACHA
Dilution Factor 1
Measured Detection
Concentration Limit
mg/L mg/L
-0.000700 BJ 0.00313
0.699 B 0. 000780
0.0135 B 0.000230
0.00488 B 0.000510
0.0734 0. 00116
0. 00145 J 0.00203
0.00434 B 0.00111
----
IDIG950829080000
EMJ61E50830190001
Instrument ~
Analyst MCG
lj.eviewer :.P.!:L'-"S:__ __ _
Reporting Subset
Spikes Subset
Specs Subset
Diluted Sample Result
Lab Sample ID
9508472-0lA LEACHA
Dilution Factor 5
Measured Detection
Concentration Limit
mg/L mg/L
0.00680 J 0.0156
0.705 0.00390
0.0144 0.00115
0.00420 0.00255
0.0688 0.00580
-0.0118 J 0.0102
0.00540 J 0.00555
--.. --
Work Order # 9508437
Page~
Matrix Ji
Report As received
\ Difference
Specification
Result Limit
\
0 10
0.83 10
6.4 10
14 Q 10
6.4 10
0 10
24 Q 10
-----
- ---08/31/95 15:55:10
Method Metals by ICP
Lab Sample ID
File ID
Project Sample
ID/Description
- -
..
Specification#
Analyte
------ANALYTICAL PROTOCOL SUMMARY
COMMENTS/NARRATIVE
Flag Comment/Narrative
--
Corrective Action
- - -
Work Order ff 9508437
Page~
-
------08/31/95 16:48:43
Report RADIAN CORPORATION
To 3200 E. CHAPEL HILL RD.
P.O. BOX 13000
Attention JIM NARKUNAS
Phone ~R,_,T""P-------------
Prepared Radian Analytical Services
By --"'l_.4.::0c:4.::6-"S"'u"'m"'m""i"'t-"D"'r-'.-''-"B"'l"'d:.;:;q._,.-"B'-
P. 0. Box 201088
Austin, TX 78720-1088
512/244-0855
CSC JALINDSEY
Project Sample
Description
STKPILE
TBLK953699
STKPILE
ID/
-----W 0 R It ORDER SUMMARY
Client Code HAM Bf!ACll NC
Client HAMILTON BEACH
Facility WASHINGTON NC
Work ID WASHINGTON,NC
Cuse ff ~N~A ________ _
SDG ff ~N~A _______ _
RAS U 508llAJAL
~----4-~---·~·. -----
Lab Sample ID Test Code (s)
OlA LEACHATE HGCSWAOO
02A LEACHATE HGCSWAOO
03A LEACHATE._ MS HGCSWAOO
04A LEACHATE_MSD HGCSWAOO
-
Mercury
Mercury
Mercury
Mercury
-----I
Work Order ff 9508438
Page,_l_
RCN 650-132-01-02
-:---
Method Desciption
by CVAAs
by CVAAs
by CVAAs
by CVAAs
- -
-
08/31/95 lb:48:43 ANALYTICAi. PROTOCOi, SUMMARY
F L A G D B F I JI I T I 0 JI S
Flag Definition
< DL Result less than stated Detection Limit and greater than or equal to zero.
Analyte concentration not available for this analysis.
RPD and/or % Recovery not calculated. See Narrative for explanation.
Nol detected. No instrument response for analyte or l'l~!lull ltoss than ze10.
NA
NC
ND
NR
NS
Not reported. Result greater than or equal to stated Detection Limit and less than specified Reporting Limit.
Analyte not spiked.
B Arldlyte detected in method blank at concentration greater Lhan the Reporting Limit (and greater than zero).
c Confirming data obtained using second GC column or GCMS.
E Analyte concentration exceeded calibration range.
F Interference or coelution suspected. See Narrative for explanation.
H Presence of analyte previously confirmed by historical data.
I Analyte identification suspect. See"Narrative for explanation.
J Result is less than stated Detection Limit but greater than or equal to specified Reporting Limit.
K Peak did not meet method identification criteria. Analyte not detected on other GC column.
See Narrative for explanation. M
p
Result modified from previous Report.
Analyte not confirmed. Results from primary and secondary GC columns differ by greater than a factor of 3.
Q QC result does not meet tolerance in Protocol Specification.
R Result reported elsewhere.
s Analyte concentration obtained using Method of Standard Additions (MSA) .
T Second column confirmational analysis not performed.
X See Narrative for explanation.
Y See Narrative for explanation.
Z See Narrative for explanation.
- -- ------ -- --
Work Order II 9508438
Page L
---- -
--..
08/31/95 16:48:43
Client HAMILTON BEACH
Facility WASHINGTON NC
Client Code HAM BEACH NC
Method Mercury by CVAAs
-
Project Sample ID/Description
S'l'KPILE
- - -----...
ANALYTICAL PROTOCOL SUMMARY
SpecificaLion U ~H~G~C~S~~-~-~-~
Extraction/Digestion
Lab Sample ID '!'est Code (s) Batch II
9508438-0lA HGCSWAOO GDIG950829151000
----Work Order II 9508438
Page _3_
Analysis Batch II
AAZ4 50829202701 -
--
-
08/31/95 16:48:43
Method Mercury by SW7470A
Test Code HGCSWAOO
Project Sample ID:
Lab ID:
File ID:
Date Collected:
Date Prepared:
Date Analyzed:
!Jilut.ion Factor:
Matrix:
Units:
Repurt as:
Column:
Analyte
Mercury
--
STKPILE
9508438-0lA LEACHA
Z4082920-13
08/29/95
08/29/95
08/29/95 20:56:00
1
Water
mg/L
received
Cone. DL
0.0000300 0.000028
---
RBSUI.TS SUMMARY
Cone. DL Cone.
-----
DL
-
Work Order # 9508438
Page _4_
Cone. DL
---- -
-.. .. .. -..
08/31/95 16:48:43
Sol'n #
Method Mercury by CVAAs
Test Code HGCSWAOO
Response
Area Counts
Reference
Cone.
Analytes mg/L
Mercury 0.000
0
-.. .. -.. -I N I T I A L CALIBRATION
Initial Calibration # Z4950829202700
Calibration Date 08/29/95 20:27:00
Response Response Response
Area Counts Area Counts Area Counts
Reference Reference Reference
Cone. Cone. Cone.
mg/1. mg/!, mg/L
0.004 U.007 0.015
0.0005 (). 001 0.0020
Response
Area Counts
Reference
Cone.
mg/L
0.032
0.004
Specification Limits for correlation coefficient >0.995
-
Response
Area Counts
Reference
Cone.
mg/L
0.077
0.010
..
Work Order # 9508438
Page _5_
Instrument a_
Analyst .!!Q_
Reviewer =D~L~C'-----
Response
Area Counts
Reference
Cone. Correlation
mg/L Coefficient
0.149 1.000
0.020
I
I
-
-
08/31/95 16:48:43
Method Digestion by SW846
Test Code DHGSWAOO
Sample
1
2·
3
4
s
6
7
8
9
10
11
12
13
14
lS
16
17
18
19
20
Quality Control
Blank
Laboratory Control Sample
Laboratory Control Sample Duplicate
Matrix Spike
Matrix Spike !Jupl icate
Matrix Spike
Matrix Spike Duplicate .. .. .. -
DIGBSTlOH BATCH SUMMARY
Digestion BdtCh # GDIG950829151000
Extraction Start Dat.e/Time '8/29/95 lS:lO:OO
Extraction Slop Date/Time
Project Sample ID Lab Sample ID
STKPILE 9508438-0lA
TBLK9S3699 9S08438-02A
9S08473-01A
Project Sample ID Lab Sample ID
BLK9S3714
LCS9S5688
LCSD9SS688
STKPILE 9S08438-03A
STKPILE 9!>084 l8-04A
9508473-02A
9508473-03A
Work Order ff 9508438
Page _6_
Analyst !!Q_
Reviewer ~---------
Sample Size
mL Cleanup Method
so
so
so
I
'
I
Sample Size
mL Cleanup Method
so
so
so
so
so
50
so .. -- -
.. -----
-
08/31/95 16:48:43
Project Sample ID ~S~T~K~P~I~L~E'----------­
Lab Sample ID 9508438-0lA LEACHA
File # Z4082920-13
Method Mercury by SW7470A
Test Code HGCSWAOO
Analyte
Mercury
-..
CAS #
7439-97-6
.. ..
Digestion Batcn tt
RESULTS
GDIG950829151000
Date
Date
Date
Date
Analysis Batch # AAZ4 50829202701
TCLP Batch # TCTCLP508281645
Collected 08[29[95 Instrument. _Z_4 __
Received 08[23[95 Column
Prepared_ 08[29[95 Analyst !!!L
Analyzed 08[29[95 20:56:00 Reviewer Dl.C
Aliquot Mass/Volume
50 (mI.)
Extract/Digestate Volume
50 (mL)
lli luliun ~·actor l
Measured Concentration
mg/L
0.0000300
.. , .. .. -.. -
Work Order # 9508438
Page _8_
Reporting Subset __ Matrix ~
Spikes Subset __
Specs Subset __
Detection Limit
mg/L
0.000028
-
Report As received
\ Moisture
' Reporting Limit
mg/L
-1000
-
-..
08/31/95 16:48:43
Lab Sample ID ~C=C=B _______ _
File # Z4082920-22
Method Mercury by SW7470A
Test Code HGCSWAOO
Mercury
Analyte
.. --.. --LABORATORY B L A N IC INFORMATION
Digestion Bc.tch # GDIG9508291SOOOO
Analysis Batch tt AAZ4 S0829202701
Date Prepared 08/29/9S Instrument £!_____
Column
Reportin~ Subset
Spikes Subset
Specs Subset
Date Analyzed 08/29/9S 21 :18:00
Analyst !!Q_
Reviewer ~D=L=C ___ _
Aliquot Mass/Volume
so (mL}
Extract/Digestate Volume
so (mL}
Dilution Factor 1
Measured Cone. Detection Limit
mg/L mg/L
-0.000040 J 0.000028
Work Order # 9S0843S
Pc.ge _9_
Matrix .!:!
Reporting Limit
mg/L
-1000
..
-
08/31/95 16:48:43
Lab Sample ID ~I~C~B~~~~~~~­
Fi le # Z4082920-9
Method Mercury by SW'1470A
Tesl Code HGCSWAOO
-
Mercury
.. ..
Analyte
, ..
LABORA'l'ORY BLAlllt I II F 0 R M A T I 0 II
Date Prepared
Date Analyzed
.. ..
Digestion Batch # GDIG950829150000
Analysis Batch fl AAZ4 50829202'101
08[29[95 Instrument ~
08[29[95 20:46:00 Column
Analyst !!!L
Reviewer D[,('
Aliquol Mass/Volume
50 (mL)
ExtracL/DigesLate Volume
50 (mL)
Dilution Factor 1
Measured Cone.
mg/L
-0.000040 J
-..
Reporting Subset
Spikes Subset
Specs Subset
Detection Limit
mg/L
0.000028
-
Work Order # 9508438
Page l.Q_
Matrix !:!
Reporting Limit
mg/L
-1000
, ..
--... .. ~ .. .. ... .. .. .. .. -.. .. .. .. .. ..
08/31/95 16:48:43 LABORATORY CONTROL SAM PL R Work Order II 9508438
Digestion Batch u GDIG950829151000 Page .!.L.
Analysis Bdtch Ii AAZ4 50829202701
Method Mercury by SW7470A Date Prepared 08/'.29/'.95 Instrument _Z_4 __ Reporting Subset Matrix !:!
Test Code HGCSWAOO Date Analyzed 08/'.29/'.95 20:53:00 Column Spikes Subset Report As received
Analyst !!!L Specs Subset \ Moisture
Reviewer DLC Aliquot Mass or Vol 50 (mL)
Extract Mass or Vol so (mL)
-
Control Std. fl Vol. Added Surrogate Sol'n II Vol. Added LCS LCS Duplicate Recovery
J,ab Sample ID Lab Sample ID Spec. ------ ------
J.CS9!>568!1 LC:SD9!>5688 J,,indL::; RPD ------------
File ID Z4082920-11 File ID Z4082920-12 ------------
SpLkt.!d Med sured Spiked Measured Spec.
Andlyte Cone. Cone. Rec. Cone. Cone. Rec. Low High Result Limit
mg/L mg/L \ mg/L mg/L \ \ \ \ \
Mercury 0.0100 0.0103 103 0.0100 0.0105 105 80 120 1. 9 20
08/31/9S 16:48:43 MATRIX SPI.KR(S)
Digestion Batch H GDIG950829151000
Analysis Batch H AAZ4 50829202701
TCLP Batch H TCTCLP508281645
Project Sample ID ,,S'-'"T-"K"-P_,_J-"'l'"'E'-----------
Method Mercury by SW7470A
Date Collected OBL29L95 Instrument ~ Reporting Subset
Spikes Subset
Specs Subset
Date Received 08/'.23L9S Column
Test Code HGCSWAOO Date Prepared 08L29L95 Analyst !!12_
Date Analyzed OBL29L95 21:03:00 Reviewer DLC
Spike Sol'n H Vol. Added Sample Spiked Sample Spiked Sample Dup
Lab Sample ID Lab Sample ------ID Lab Sample ID
9508438~01A LEACllA ------9508418-0JA J,EACHA 9508438-04A LEACHA
------File H Z4U82920-13 1-'i le u ?.4082920 15 ~·J le H Z4082920-16
Surrogate Sol'n Vol. Added Aliquot Mass/Vol Aliquot Mass/Vol Aliquot Mass/Vol
50 (mL) 50 ------(mL) 50 (mL)
Extract Mass/Vol Extract Mass/Vol Extract Mass/Vol ------
50 ------(mL) 50 (mL) 50 (mL)
Dil Fact. 1 Oil Fact. 1 Dil Fact. 1
-
Spike
Sol'n Mea'sured Spiked Measured Spiked Measured
Analyte Cone. Cone. Cone. Cone. Rec. Cone. Cone. Rec.
mg/L mg/L mg/L mg/L \ mg/L mg/L \
Mercury 0.0000300 0.00200 0.00229 113 0.00200 0.00224 110
--.. .. .. .. -..
Work Order H 9508438
Page 1.1_
Matrix ):!
Report As received
\ Moisture
Recovery
Specif i -
cation
Limits RPO
I
Specifi-
cation
Low High ,Result Limit
.\ \ \ \
75 125 I 2.7 20 '
.. ..
.. ... ... ..
08/31/95 16:48:43
Lab Sample ID _I_c_v ___ _
File # Z4082920-8
Method Mercury by SW7470A
Test Code IJGCSWAOO
Analyte
Mercury
... .. ..... .. .. , ... ..: ...
CONTINUING(OR DAILY) CALIBRATION Work Order #!9508438
Page 12-V K R I l' I C A T I 0 N
Analysis Batch # AAZ4 50829202701
Initial Calibration # Z4950829202700
Date Analyzed 08/29/95 20:43:00
Measured Reference
Concentration Concentration
mg/L mg/L
0.0103 0.0100
Reporting Subset __
Spikes Subset __
Specs Subset __
Recovery
\
103
Instrument ~
Analyst .!:!Q_
Reviewer ~D~L~C ___ _
Recovery
Specification
Limits
Low High
\ \
90 110
9f;· ..
-
08/30/9S 16:39:16 ANAi.YT I CAL PROTOCOL SUMMARY
Y L A G D B Y I N 1 T I 0 N S
Flag Definition
< DI. R<!sult l<!ss than stated Detection Limit ai1d gi·,wter LIJ,rn oi· equal to zt:ro.
A11alyte concentration not available for Lhis analysis.
RPD and/or% Recovery not calculated. See Narrative for explanation.
Not detected. No instrument response for analyte or resull less than zero.
NA
Ne
NIJ
NR
NS
Not reported. Result greater than or equal to stated Detect ion J,imit and less than specified Reporting Limit.
Analyte not spiked.
B
c
E
F
H
l
J
Andlyte detected in method blank at concenlration gtedl.e1 Ll1dn the Reporting J,imit (and g1eater than zero).
confirming data obtained using second GC column or GCMS.
Analyte concentration exceeded calibration range.
Interference or coelution suspected. See Narrative for explanatic<.
Presence of analyte previously confirmed by historical daLa.
Analyte identification suspect. See Narrative for explanation.
Result is less than stated Detection Limit but greater than or equal to specified Reporting Limit.
K Peak did not meet method identification criteria. Analyte not detected on other GC column.
M Result modified from previous Report. See Narrative for explanation.
P Analyte not confirmed. Results from primary and secondary GC columns differ by greater than a factor of 3.
Q QC result does not meet tolerance in Protocol Specification.
R Result reported elsewhere.
s Analyte concentration obtained using Method of Standard Additions (MSA).
T Second column confirmational analysis not performed.
x See Narrative for explanation.
Y See Narrative for explanation.
Z See Narrative for explanation .
.. i .. .. I-.... .. .... -
Work Order # 9508431
Page£_
... .. ..
-
08/30/9~ 16:39:16
Method TPH-Gasoline by mod.SW8015
Test Code GASS.SAE!,
Projec:t. Sample ID:
Lab ID:
Fi lt: ID:
Date Collected:
Date Prepared:
!Jate Andly~<:d:.
DiluLion Fdctor:
Matrix:
Units:
Rt:port us:
Column:
Analyte
Benzene
Ethyl benzene
Gasoline
Toluene
Unidentified organics
Xyl~nes (total)
Surrogate(s)
Chlorobenzene
.. ..
RKsu1.·rs SUMMARY
STKPILE S'l'KPII,E
9508431-0lA COMPOS 9508431-0lA COMPOS
PL285 01,285
08/22/95 08/22/95
08/28/9$ 15:36 08/28/95 15:36
50 s~
Solid Solid
ug/kg ug/kg
dry weight dt y wt:ight
PRIMARY SECONDARY
Cone. DL Cone. DL
ND 7 .14 ND 7.15
70.5 7.07 66.5 CB 7.14
NA ND 1530
147 B 7.04 240 CB 8.59
NA 24100 XB 1530
170 B 6. 97 190 CB 9.29
Recovery Recovery
\ \
97 99
,. .. .. , ..
Cone. DL
Recovery
\
... .. -
Work Order U 9508431
Page _4_
Cone. ' DL
'
I
'
Recovery
\
-.. .. ..
-.. -08/30/9~ 16;39:16
Method TPH-Gasoline by mod.SW8015
Test Code GASSSAC:L
.. ..
Initial Calibration U LUK1950614010100
Calibration llate ~0~6~/=1~4~/~9=5 ____ _
--
Sequence/Analysis Time Project Sample
l 011/211/YS 21: o~
2 08/28/95 12:05
3 08/28/95 12;05
4 08/28/95 13; 06
5 08/28/95 13 ;06
6 08/28/95 14;35
7 08/28/95 15:36 STKPlLE
8 08/28/95 16;36 STKPILE
9 08/28/95 17;37 STKPILE
10 08/28/95 18;37
11 08/28/95 19: 3'/ -
-.. ..
A N A L Y S l S 8 A T C H S U M M A R Y
Analysis Batch U GCLUK150828J20501
Analysis Start Date/Time 08/28/95 12:05;00
Aildlysis Stop llate/Time 08/28/95 1Y:37:00
-
Ill 1,ab Sample ID Sample Type
'..!Ml;'J'llYLl'~:NT s.1111plc
-.. ..
Work Order U 9508431
Page _·i_
Instrument LUKl
Analyst cc:s
Reviewer ~K=L=Z ________ _
Analysis File U
PL281
CALCllK Continuing Calibration Check PL282
l,CS955114 I.ab Control Sample PL282
CALGAS Continuing Calibration Check PL283
LCSG955115 Lab Control Sample PL28;3
llJ,K953254 f,aboratory Blank PL284
9508431-0lA Sample PL285 '
9508431-02A Matrix Spike PL286
9508431-03A Matrix Spike Dup PL287
LCS955117 Lab Control Sample Dup PL288 '
LCSG95!>118 Lab Control Sample PL289
I
--
-.. .. -.. ... .. -..
UB/30/9? 16:j9:16 LA H 0 R A T 0 R y
ExtracLion !:latch
Analysis Batch
Lab Sample JD ~B~L~K~9~5~3~2~5~4 ____ _ Date Prepared
File U ~P=L=2~8~4 _____ _ Date A11alyzed 08/28/95 14: 15
II
\ ... ..
J, AN K I N I' 0 R
GCLUK15082Bl205Ul
Instrument LUK!
Column PRIMARY
Analyst C'ES
... .. -MAT ION
Reporting Subset
Spikes Subset
Specs Subset
.. ..
Work Order 9508431
Page 2..._
Matrix .§
Method TPH·Gasoline by mod.SW8015
Tesl Code (;ASSSABL H~v i ewe i: .-K-l ... z ___ _
Aliquot Mass/Volume
2.0 (g)
Bxl1dct/Digestdle Vo!utne
4.0 (mL)
Dilution Factor !>O
'
Measured Cone. Detection Limit Reporting Limit
Analyte ug/kg ug/kg ug/kg
Benzene 9.83 5.76 0
Ethylbenzene ND 5.70 0
Gasoline NA 0
Toluene 11. 7 5.68 0 '
Unidentified organics NA 0
Xylenes (total) 44.4 5.62 0
Specification Limits
Spiked
Cone. Measured Cone. Re~overy Low High
Surrogate(s) ug/kg ug/kg % '!; '!;
Chlorobenzene 2000 2120 106 53 141
.. .. -
-
08/J0/95 16:39:16 CONTINUING(OR DAILY) CALIBRA'l'ION Work Order " 9508431
Page 1L
'-
Lab Sample ID CAJ.CHK
Fi le # .:.P.:L::2-=8-=2'-------
Method TPH-Gasoline by mod.SW8015
Test Code GASSWAEL
A11<.1lyle
Benzene
Ethylbenzene
Toluene
Xylenes (total)
Surrogate(s)
Chlorobenzene
V B R I P I C A T I 0 N
Analysis Batch GCI.UK150828120501
Initial Calibration # I.UK1950614010100
Date Analyzed 08/28/95 12:05 Reporting Subset _
Spikes Subset __
Specs Subset __
Medstired Reference
Concentration Concentration Recovery
t11J/I, ug/l, \
8.91 10.0 •89
9.81 10.0 98
9.07 10.0 91
28.2 30.0 94
I 18.2 I 20.0 I 91 I
Instrument ~
Andlyst CES
Reviewer ~K~l·=z ___ _
Recovery
Specification
I,imits
Low High
\ \
80 120
80 120
80 120
80 120
52 I 140
'-..... -.. ---.. -.... , .. .. .. -
-.. .. -..
08/30/95 16:39:16
Method TPH·Gdsoline by mod.SW8015
Te«t Code GASSSAEL
Initial Calibration U LlJK2950614010100
Cdlih«at. ion Date ~0~6~/~1~4~/~9~5 ____ _
Sequence/Analysis Time
1 08/28/95 11:05
2 08/28/95 12:05
3 08/28/95 12:05
4 UH/28/% 13:06
5 08/28/95 13: 06
6 08/28/95 14:35
7 08/28/95 15:36
8 08/28/95 16:36
9 08/28/95 17:37
10 08/28/95 18:37
11 08/28/95 19:37
-.. -----ANAl.YSIS BATCH SUMMARY
An<1lysi,; lldLch U GCI.lJK25ll828120501
Analysis Start Date/Time 08/28/9" 12: 05: oo
Analysis Stop Date/Time 08/28/95 19:37:00
-.. ... ..
Wotk Order U 9508431
Page ll_
Instrument ~
Analyst ~
Reviewer ~K=L=Z---~
Project Sample ID Lab Sample ID Sample Type Analysis File U
:mETHYLPENT Sample OL281
CALCllK Continuing Calibration Check OL282
LCS955114 Lab Control Sample OL282
<'AI.GAS Continuing CalibraL ion Check 01.28 3
LCSG955115 Lab Control Sample OL283
BLK953254 Laboratory Blank OL284
STKPILE 9508431-0lA Sample OL285
STKPlLE 9508431-02A Matrix Spike OL286
STKPILE 9508431-03A Matrix Spike Dup OL287
LCS955117 Lab Control Sample Dup OL28B
LCSG95511B Lab Control Sample Dup OL2B9
..
-
OH/30/9? 16:39:16
Projc ... :l Samµle IV ,,s"-'·1.!:·K~P-"l"'L"'E'----------­
Lab Sample ID 95084 31-OlA COMPOS
File tt ~0~1·~2~8~5 _____ _
Method 'l'PH·Gasoline by mod.SWBOl5
Test Code GASSSAEI,
Analyte
Benzene
Ethylbenzene
Gasoline
Toluene
Unidentified organics
Xylenes (total)
Surrogate(s)
Chlorobenzene
.. ... -..
CAS II
71-43-2
100-41-4
8006-61-9
108-88-3
NO_CAS
1330-20-7
CAS II
108-90-7
-
RKSUJ,TS Work Order tt 9508431
ExLraction Udtt•h Page ll_
Analysis Batch tt GCr.tJK250828120501
0<1te Colleeled 0HL22L9!> Instrument J,lJK2 Reporting Subset --Mall"ix §.
Date Received OBL2 l/95 Column SECONDARY Spikes Subset --Report As dt·y weight
Date Prepared Analyst CES Specs Subset __ 'Ii Moisture 22.2
Dale Analyzed OBL2BL9!:> !!:>:lb Heviewer Kl,Z
Aliquot M<1ss/Volume
12.44 (g)
Extract/Digestate Volume
24.0 (ml,)
!Ji lul 1011 ~\1<:Lo1· ~()
Measured Concentration Detect ion L.imit Reporting Limit
ug/kg ug/kg ug/kg
ND 7.15 0
66.5 CB 7 .14 0
ND 1530 0
240 CB 8.59 0
' 24100 XB 1530 0
190 CB 9.29 0
_, Specification Limits
Spiked
Cone. Measured Concentration Recovery Low High
ug/kg ug/kg \ \ ' 'I;
2480 2450 99 53 141
-.. -- -·-.. .. .. .. ... --
-.. .. -08/30/95 16:39:16
Lab Sample ID ~B~L~K~9~5~3_2~5~4 ____ _
H le U ~O~L~2~8~4 _____ _
M"'thod TPH-Gasoline by mod.SW8015
Test Code GJ>.SSSAEl.
Analyte
Benzene
Ethylbenzene
Gasoline
Toluene
- -
.. -.. - -LABORATORY BLANK l N F 0 R M A T I 0 N
Date Prepared
Extraction Batch
Analysis Batch
Date Analyzed 08/~6/95 14:35
GCLUK250828120501
Instrument LUK2
Column SECONDARY
Analyst £§2
Reporting Subset
Spikes Subset
Specs Subset
Reviewer _K_l._?. ___ _
Aliquot Mass/Volume
2.0 (g)
Exlcdcl/Digestate Volume
4.0 (mL) . Di lul ion Factor 50
--
Measured Cone. Detection Limit
ug/kg ug/kg
12.0 5.77
6.95 5.76
ND 1230
10.5 6.93
Unidentified organics 560 J 1230
Xylenes (total) 25.2 7.49
... -Work Order U 9508431
Page ,!L
Matrix §
'
Reporting _Limit
ug/kg .
0
0
0
0
0
0
Specification Limits
Spiked
Cone. Measured Cone. Recovery Low High
Surrogate(si ug/kg ug/kg \ '\ \
Chlorobenzene 2000 2170 109 53 141
.. --
08/30/95 16:39:16
Date Prepared
LABORATORY
Extraction Batch U
coa·rROL SAMPl.B
Analysis Batch # GC'l,UK250828 J 2050 l
Method TPH-Gasoline by mod.SW8015
Test Code GASSWAEL Date Analyzed 08/28/95 .18: 37
Instrument .!dlliL
Column SECONDARY
Analyst CES
Reporting Subset
Spikes Subset
Specs Subset
Reviewer "'K~!,~Z ___ _
-
Control Std. ff Vol. Added Surrogate Sol'n n Vol. Added LCS LCS Duplicate
USBTEX _5 __ ~-CllJ,OROBP.NZ _5 __ .'!!!.__ I.ab Sample lD I.ab Sample JD
[,('89!>~ 114 I.CS9!>0, 117 ----------
~'ilc ID OL282 File ID OL288 ------------
Spi.ked Measured Spiked Measured
Analyte Cone. Cone. Rec. Cone. Cone.
ug/L ug/L 'I; ug/L ug/L
Benzene JO.O 9.32 93 10.0 9.61
Ethylbenzene 10.0 9.62 96 10.0 9.91
Toluene 10.0 9.32 93 10.0 9.60
Xylenes (total l 30.0 28.5 95 30.0 29.4
Surrogate(s)
ChloroLenzene 20.0 19.0 95 20.0 18.9
--.. --- -
... ----.. -
Work Order II 9508431
Page 1.2_
Matrix !i
Report As received
\ Moisture
Aliquot Mass or Vol 5.0 (mL)
Extract Mass or Vol 5.0 (mL)
Recovery
Spec.
Li mils RPD
Spec.
Rec. Low High Result Limit
% % 'I; % %
96 62 128 3.2 33
99 67 137 3.1 32
96 61 129 3.2 32
98 64 136 3.1 32
94 52 140
... ---
-- - -- -08/30/95 l6:39:16
Date Prepared
-... -J,ABORATORY
ExtrdCLio11 Batch U
---CONTROL SAMPLR
Analysis Batch U GCLUK250828120501
-
Method TPH-Gasoline by mod.SW8015
Test Code GASSWAEL Date Analyzed 08/28/95 19:37
Instrument .!.ill.!SL_
Column SECONDARY
Analyst CE:S
Reporting Subset
Spikes Subset
Specs Subset
keviewer ~K~L=Z ___ _
Control Std. u Vol. Added Surrogate Sol'n # Vol. Addt!d LCS LCS Duplicate
CALCHK GAS _s __ !!.!!.__ C'HLOROBENZ _5 __ !!.!!.__ I.ab Sample ID J,ab Sample ID
LCSG9!> !:.115 LCSG955118 ------------
File ID OL283 File ID OL289 ------------
Spikt!d Measured Spikt!d Mt!asu1·ed
Analyte Cone. Cone. Rec. Cone. Cone.
ug/L ug/L \ ug/L ug/L
Gasoline sou 572 114 500 580
Surrogate(s)
Chlorobenzene I 20.0 I 22.3 I 111 I 20.0 I 20.7
.. -.. --
Work Ordt?r U 9508431
Page 11._
Matrix !:!
Report As received
\ Moisture
Aliquot Mass or Vol 5.0 {mL)
Extract Mass or Vol 5.0 {mLl
Recovery
Spt!C.
Limits RPD
Spec.
Rec. lJOW High Result Limit
\ \ \ \ \
116 65 135 1. 7 21
I 104 I 52 I 1401
08/30/95 lb:39:lb MATRIX S P I It K ( S ) Work Order U.9508431
Extraction Batch # Page .!L
Analysis Batch U GCLUK25082812050l
ProJect Sample ID =S~T~K~P~I=L=E _________ _ Date Collected OBL22L95 Instrument l.UK2 Reporting Subset
Spikes Subset
Specs Subset
Matrix 2
Method '!'PH-Gasoline by mod.SW8015 Date Received 00L23L95 Column SECONDARY Report As dry weight
Test Codt! GASSSABIJ Date Prepared Analyst CES \ Moisture 22.2
Date Analyzed 001'.20L95 17:37 Reviewer KI,z
-
Spike Sol 'n jj Vol. Added Sample Spiked Sample Spiked Sample Dup
USBTEX _s __ ~ Lab Sample ID Lab Sample ID Lab Sample ID
9S08431-01A COMPOS 9508431-02A MS 9S084 31-03A MSD ------
Pile # 01.285 ------l·'ile II Ol,286 Pile 11 OL287
Surrogate Sol 'n Vol. Added Aliquot Mass/Vol Aliquot Mass/Vol Aliquot Mass/Vol
Chlorobenz _5_. __ ~ 12.44 (g) 12.44 (g) 12.44 (g) Recovery
------Extract Mass/Vol Bxu·,wt Mass/Vol llxt ract Mass/Vo 1 Specif i-
24.0 ------(mL) 24.0 (mL) 24.0 (mL) cation
Dil Fact. 50 Dil Pact. so Dil Pact. so Limits RPD
Spike Specifi-
Sol'n Measured Spiked Measured Spiked Measured cation
Analyte Cone. Cone. Cone. Cone. Rec. Cone. Cone. Rec. Low High Result Limit
ug/kg ug/kg ug/ky ug/kg % ug/kg ug/kg % % % % %
Benzene 10000 ND 1240 1100 89 1240 1130 91 so 150 2.2 50
Ethyl benzene 10000 66.5 CB 1240 1210 92 1240 1200 91 so 150 1.1 so
Toluene 10000 240 CB 1240 1300 85 1240 1330 88 50 150 3.5 so
Xylenes (total) 30000 190 CB 3720 3530 90 3720 3550 90 50 lSO 0 so
Surrogate(s)
Chlorobenzene 20000 2450 2480 2710 109 2480 2610 105 53 141
--- -- --.. -----.. .. .. ... -
-- ----08/30/95 16:39:16
Lab Sample ID CALCHK
Fi 1 e # ~O"'L"'2"'8"'2'------"-
----·-
CONTINOING(OR DAILY) CAJ,IBRATION
V B R I P I C A T I 0 N
Analysis Bat.ch # GCLUK250828l20501
Initial Calibration # LUK2950614010100
Date Analyzed 08/28/95 12:05
-.. -..
Work Order # 9508431
Page .!.2_
Me thod TPH-Gasoline by mod.SW8015
Reporting Subset __
Spikes Subset __
Specs Subset __
Instrument LUK2
Analyst: CES
Reviewer "K"'L"'Z'-----
Test. Code GASSWAEL
Recovery
Specification
Limits
Measured Reference
Concentration Concentration Recovery Low High
Analyte u9/J, ug/J, \ \ \
Benzene 9.32 10.0 93 80 120
Ethyl benzene 9.62 10.0 96 80 120
Toluene 9.32 10.0 93 80 120
Xylenes (total) 28.5 30.0 95 80 120
Surrogate(s)
Chlorobenzene I 19.0 I 20.0 I 95 I 52 I 140
-
-
08/30/95 16:39:16 CONTillUING(OR DAILY) CALIBRATION Work Order # 9508431
Page ll._
- -
Lab Sample ID CALGAS
Fi 1 e ll ~O'-=L"'2"'8"'3'-------
Method TPH-Gasoline by mod.SW8015
Test Code GASSWAEJ,
Anal yl c
Gasoline
Surrogate(s}
Chlorobenzene
V B R I F I C A T l 0 N
Analysis Batch ll Gct,UK250828120501
lnil.ial Calibration ll J,UK2950614010100
Date Analyzed 08/28/95 13:06 Reporting Subset
Spikes Subset
Speci,, <1uset.
Measured Reference
Concentration Concentration Recover}'
U•J/I, uy/I, \
572 500 114
I 22.3 I 20.0 I 111 I
Recovery
Instrument LUK2
Analyst £§§
Reviewer ~K=L~Z ___ _
Specification
Limits
Low High
\ \
80 120
52 I 140
--------.. - --... --
--- -- - -08/30/95 16:39:16
Method '!'PH-Gasoline by mod. SW8015 Specif icationtt GASS-D
Lab Sample ID
File ID
9S08431 OlA
CJ!,285
Project Sample
ID/Description
S'l'KP f !,E
Analyte
UNIDENTIPIED ORGANICS
------ANALYTICAL PROTOCOL SUMMARY
COMMKNTS/NARRATIVB
Flag Comment/Narrative
x The hy<lrocarbou Vdlue iudicates the presence
of a multi-component hydrocarbon eluting
uniformly throughout the established
integration range for gasoline but which does
Ill>L correspond to known gd!lOline patterns.
-
Corrective Action
-.. -Work Order # 9508431
Page £1_
-
-----09/07/95 15:14:19
Report RADIAN CORPORATION
To 3200 E. CHAPEL HILL RD.
P.O. BOX 13000
Attention JIM NARKUNAS
Phone "'"'RT.:..:P __________ _
Prepared
By
Radian Analytical Services
14046 Sunmit Dr., Bldg. B
P. O. Box 201088
Austin, TX 78720-1088
512/244-0855
CSC JALINDSEY
-
Project Sample ID/
Description
STKPILE
-----------WORK ORDER SUMMARY
Client Code HAM BEACH NC
Client HAMILTON BEACH
Facility WASHINGTON NC
Work ID WASHINGTON.NC
Ca~e # ~NA-'-------­
SDG #'"'NA'-'--------
RAS # 50811AJAL
Lab Sample ID Test Code(s)
01A COMPOSITE 354SSA00
CK1SSA00
DSLSSAEL
Work Order # 9508439
Page _1 _
RCN 650-138-02-01
Method Desciption
Soxhlet Extraction SW846
Primary KD cone. SW846
TPH-Diesel by mod. SW8015
--
-
09/07/95 15:14:19 ANALYTICAL PROTOCOL SUMMARY
FLAG DEFINITIONS
Flag Definition
< DL Result Less than stated Detection Limit and greater than or equal to zero.
NA Analyte concentration not available for this analysis.
NC RPD and/or i Recovery not calculated. See Narrative for explanation.
ND Not detected. No instrument response for analyte or result less than zero.
NR Not reported. Result greater than or equal to stated Detection Limit and less than specified Reporting Limit.
NS Analyte not spiked.
B Analyte detected in method blank at concentration greater than the Reporting Limit (and greater than zero).
C Confirming data obtained using second GC column or GCMS.
E Analyte concentration exceeded calibration range.
F Interference or coelution suspected. See Narrative for explanation.
H Presence of analyte previously confirmed by historic.al data.
I Analyte identification suspect. See Narrative for explanation.
J Result is less than stated Detection Limit but greater than or equal to specified Reporting Limit.
K Peak did not meet method identification criteria. Analyte not detected on other GC column.
M . Result modified from previous Report. See Narrative for explanation.
P Analyte not confirmed. Results from primary and secondary GC columns differ by greater than a factor of 3.
Q QC result does not meet tolerance in Protocol Specification.
R Result reported elsewhere.
S Analyte concentration obtained using Method of Standard Additions (MSA).
T Second column confirmational analysis not performed.
X See Narrative for explanation.
Y See Narrative for explanation.
Z See Narrative for explanation.
- ----------
York Order I 9508439
Page L
-----
---... -09/07/95 15:14:19
Client HAMILTON BEACH
Facility WASHINGTON NC
Client Code HAM BEACH NC
Method TPH-Diesel b~ mod. SW8015
Project sample ID/Description
STKPILE
--- - -.. -.. - - -·-- -
ANALYTICAL PROTOCOL SUMMARY
Specification # :::.D:::..SL::.::S=-------
Extraction/Digestion
Lab Sample ID Test Code(sl Batch #
9508439-01A DSLSSAEL 3540950830093000
Work Order # 9508439
PageL
Analysis Batch #
TPGC1250905211301
-
09/07/95 15:14:19
Method TPH-Diesel by mod. SW8015
Test Code DSLSSAEL
Project Sample ID:
Lab ID:
Fi le ID:
Date Collected:
Date Prepared:
Date Analyzed: .
Dilution Factor:
Matrix:
Units:
Report as:
Column:
Analyte
Diesel
Jet fuel (JP4)
Kerosene
Unidentified organics
Surrogate Cs>
Octacosane
---..
STKPILE
9508439-01A COMPOS
M5IE11
08/22/95
08/30/95
09/06/95 01:43
2.00
Sol id
ug/g
dry weight
Cone. DL
ND 0.00518
ND 0.00611
ND 0.00549
150 x
Recovery
~
134
RESULTS SUHHARY
Cone. DL Cone.
Recovery Recovery
~ ~
DL
Work Order # 9508439
Pagei_
'
I I
Cone. DL
Recovery
~
'
- -
------------ - -
-- --' ---09/07/95 15:14:19
Sol 'n # ------------------
Method TPH-Diesel by mod. SW8015
Test Code DSLSSAEL
Res1:xmse Response
Area Counts Area Counts
Reference Reference
Cone. Cone.
Analytes ug/g ug/g
Jet fuel (JP4) 1142334 1726008
200 300
Kerosene 1606489 2446876
200 300
Diesel 1361385 2337438
200 300
Octacosane 140255 287250
Surrogate 20 40
------------I N I T I A L CALIBRATION
Initial Calibration# GC12950719180700
Calibration Date 07/19/95 18:07:00
Resr><?nse Response Response
Area Counts Area Counts Area Counts
Reference Reference Reference
Cone. Cone. Cone.
ug/g ug/g ug/g
3002289 5054837 5942195
500 800 1000
4282069 7226192 8750276
500 800 1000
3945506 7109034 8476319
500 800 1000
359492 603364 744737
50 80 100
Response Response
Reference Reference
Cone. Cone.
Work Order # 9508439
Page2._
Instrument GC12
Analyst TCN
Reviewer ,:,,:M::,;JD"'---
I
Correlation -RF 'X RSD CoeffiCient
I
0.000168 4.68
I I
0.000118 5.28
0.000126 10.9
1.000
I
I
I
Specification Limits 'XRSD < 20'X or correlation coefficient~ 0.995
-
09/07/95 15:14:19
Method Soxhlet Extraction SW846
Test Code 354SSAOO
Sample
1
2
3
4
5
6
7
8
9
10
11
12
13.
14
15
16
17
18
19
20
EXTRACTION BATCH SUMMARY
Extraction Batch # 3540950830093000
Extraction Start Date/Time 08/30/95 09:30:00
Extraction Stop Date/Time 08/31/95 08:00:00
Project Sample ID Lab Sample ID
9508505-01A
STKPILE 9508439-01A
Quality Control Project Sample ID Lab Sample ID
Blank BLK953697
Laboratory Control Sample LCS955670
Laboratory Control Sample Duplicate LCSD955670
Matrix Spike 9508505-02A
Matrix Spike Duplicate 9508505-02A
Work Order # 9508439
PageL
Analyst KPW
Reviewer --------
Sample Size
g Cleanup Method
20.02
20.04
I
I
I I
I
Sample Size
g Cleanup Method
---I
------
20.04
20.01
I
.
-------·-----·--------
-------------------09/07/95 15:14:19
Method TPH-Diesel by mod. S\.18015
Test Code DSLSSA02
Initial Calibration# GC12950719180700
Calibration Date _07~/~1~9/~9~5 ___ _
Sequence/Analysis Time
1 09/05/95 18:12
2 09/05/95 18:58
3 09/05/95 19:43
4 09/05/95 20:28
5 09/05/95 21:13
6 09/05/95 21:58
7 09/05/95 22:44
8 09/05/95 23:29
9 09/06/95 00:13
10 09/06/95 00:58
11 09/06/95 01:43
12 09/06/95 02:28
13 09/06/95 03:13
14 09/06/95 03:59
15 09/06/95 04:44
16 09/06/95 05:28
17 09/06/95 06:13
ANALYSIS BATCH SUMMARY
Analysis Batch# TPGC1250905211301
Analysis Start Date/Time 09/05/95 21:13:00
Analysis Stop Date/Time 09/06/95 06:13:00
Work Order # 9508439
Page!_
Instrument GC12
Analyst TCN
Reviewer _M_JD ______ _
Project Sample ID Lab Sample ID Sample Type Analysis File#
BLK Laboratory Blank M5IE1
CALJET Continuing Calibration Check M5IE2
CALK ER Continuing Calibration Check M5IE3
CALDSL Continuing Calibration Check M5IE4
BLK953697 Laboratory Blank M5IE5
LCS955670 Lab Control Sample M5IE6
LCSD955670 Lab Control Sample Dup· M5IE7
9508505-01A Sample M5IE8
9508505-02A Matrix Spike M5IE9 I
9508505-03A Matrix Spike Dup M5IE10
STKPILE 9508439-01A Sample M5IE11
BLK Laboratory Blank M5IE12 I
ALIQUOT Lab Control Sample M5IE13
ALIQUOT Lab Control Sample M5IE14
CALJET Continuing Calibration Check M5IE15 I I
CALK ER Continuing Calibration Check M5IE16
CALDSL Continuing Calibration Check M5IE17
-
09/07/95 15:14:19
Project Sample ID ,:;S..:..:TKc::.P...:I..::.L.=..E ______ _
Lab Sample ID 9508439-01A COMPOS
Fi le # ~AA'-'=5::...I..::.E_,_11,__ __ _
Method TPH-Diesel by mod. S~8015
Test Code DSLSSAEL
Analyte CASI
RESULTS
Extraction Batch # 3540950830093000
Analysis Batch# TPGC125U905211301
Date Collected 08/22/95 Instrument §£1.L
Date Received 08/23/95 Column
Date Prepared 08/30/95 Analyst TCN
Date Analyzed 09/06/95 01:43 Reviewer MJD
Aliquot Mass/Volume
15.59 (g)
Extract/Digestate Volume
2 (ml)
Dilution Factor 2.00
Measured Concentration
ug/g
Diesel 68334-30-5 ND
Jet fuel (JP4l NO CAS ND
Kerosene 8008-20-6 ND
Unidentified organics NO CAS 150 x
Spiked
Cone. Measured Concentration
Surrogate Cs I CASI ug/g ug/g
Octacosane 630-02-4 6.41 8.60
Work Order I 9508439
Page§_
Reporting Subset _ Matrix ~
Spikes Subset _ Report As dry weight
Specs Subset _ % Moisture 22.2
'
Detection Limit Reporting Limit
ug/g ug/g
0.00518 0
0.00611 0
0.00549 0
0
Specification ,Limits
Recovery Low High
i % %
134 11 161
- ----------·------
---- -09/07/95 15:14:19
Lab Sample ID BLK953697
Fi le # '""M'"""5'-'I=E~5 ___ _
Method TPH-Diesel by mod. SW8015
Test Code DSLSSAEL
Analyte
Diesel
Jet fuel (JP4)
Kerosene
-------.. ---·-LABORATORY BLANK INFORHATION \.lark Order # 9508439
Page L ,
Extraction Batch # 3540950830093000
Analysis Batch # TPGC12509052l1301
Date Prepared 08/30/95 Instrument §£!£__
Date Analyzed 09/05/95 21:13 Column ___ _
Analyst TCN
Reviewer ""M"'JD:;.._ __
Aliquot Mass/Volume
20 (g)
Extract/Digestate Volume
2 (ml)
Dilution Factor 1.00
Measured Cone.
ug/g
ND
ND
ND
Reporting Subset_
Spikes Subset _
Specs Subset _
Matrix ~
Detection Limit Reporting Limit
ug/g ug/g
0.00202 0
0.00238 0
0.00214 0
I
I
Unidentified organics 0.278 0
I Specification Limits
Spiked
Cone. Measured Cone. Recovery Low High
Surrogate(s) ug/g ug/g t t t
Octacosane 5.00 5.09 102 11 161
--
09/07/95 15:14:19
Method TPH-Diesel by mod. SW8015
Test Code DSLSSAEL
Control Std. # Vol. Added
SP-1-558 .lQQ_ .\!l_
----
----
Analyte
Diesel
Surrogate Cs)
Octacosane
-- --
LABORATORY CONTROL SAMPLE
Extraction Batch # 3540950830093000
Analysis Batch# TPGC1250905211301
Work Order # 9508439
Page 1Q_
Date Prepared 08/30/95 Instrument GC12
Column----
Analyst TCN
Reporting Subset _ _ Matrix ~
Date Analyzed 09/05/95 22:44
Surrogate Sol'n # Vol. Added
SP-1-515 .lQQ_ .\!l_
----
----
- --
Reviewer .;.;M:.;cJD"----
LCS
Lab Sample ID
LCS955670
File ID M5IE6
Spiked Measured
Cone. Cone. Rec.
ug/g ug/g i
so.a 42.8 86
5.00 5. 15 103
Spikes Subset__ Report As received
Specs Subset__ % Moisture
LCS Oupl icate
Lab Sample ID
LCSD955670
Fi le ID M5IE7
Spiked Measured
Cone. Cone.
ug/g ug/g
so.o 46. 1
5.00 5.31
Aliquot Mass or Vol
Extract Mass or Vol
Recovery
Spec.
Limits
Rec. Low High
i i i
92 61 157
106 11 161
I
I
___ 2_0 Cgl
__ __,2 (ml)
RPO
Spec.
Result Limit
i i
6.7 22
------------
----09/07/95 15:14:19
Project Sample ID
Method TPH-Diesel by mod. S~8015
Test Code DSLSSAEL
Spike Sol 'n # Vol. Added
SP-1-553 1.QQ_ !!!:__
----
----Surrogate Sol 'n Vol. Added
SP-1-515 1.QQ_ !!!:__
----
----
Analyte
Diesel
Surrogate Cs)
Octacosane
-
Spike
Sol 'n
Cone.
ug/g
12500
1000
- ------------M A T R I X S P I K E ( S )
Extraction Batch # 3540950830093000
Analysis Batch# TPGC1250905211301
Date Collected 08/26/95
Date Received 08/29/95
Date Prepared 08/30/95
Instrument ~
Column ___ _
Analyst TCN
Date Analyzed 09/06/95 00:58 Reviewer _M_JD __ _
Sample Spiked Sample
Lab Sample ID Lab Sample ID
9508505-01A 9508505-02A MS
\.lork Order # 9508439
Page lL
Reporting Subset __
Spikes Subset __
Specs Subset __
Spiked Sample Dup
Lab Sample ID
9508505-03A MSD
Matrix .§
Report As dry weight
l Moisture 11.7
File# M5IE8 File# AA5IE9 File # MS! E10
Aliquot Mass/Vol Aliquot Mass/Vol Aliquot Mass/Vol
17.68 (g) 17.7 (g) 17.67 (g) Recovery ' Extract Mass/Vol Extract Mass/Vol Extract Mass/Vol Specifi-
2 (ml) 2 (ml) 2 (ml) cat-ion
Oil Fact. 1.00 Di l Fact. 1.00 Di l Fact. 1.00 Limits ' RPO
Specifi-:
Measured Spiked Measured Spiked Measured I cation I
Cone. Cone. Cone. Rec. Cone. Cone. Rec. Low High Result Limit
ug/g ug/g ug/g l ug/g ug/g l l l l l
ND 70.6 77.1 x 106 70.7 76.3 x 105 50 150 0.95 50
5.96 5.65 6.23 110 5.66 5.90 104 11 161 I
-
I 09/07/95 15:14:19 CONTINUING(OR DAILY) CALIBRATION Work Order I 9508439
Lab Sample ID CALJET
Fi le # ""M'""5;...:I..::;E2;:::_ __ _
Method TPH-Diesel by mod. SW8015
Test Code DSLSSAEL
Analyte
Jet fuel (JP4)
VERIFICATION
Analysis Batch# TPGC1250905211301
Initial Calibration# GC12950719180700
Date Analyzed 09/05/95 18:58
Measured Reference
Concentration Concentration
ug/g ug/g
499 500
Reporting Subset _
Spikes Subset_
Specs Subset _
Recovery
x
100
Instrument GC12
Analyst TCN
Reviewer .:..::HJ::..::D:....---
Recovery
Specification
Limits
Low High
x x
85 115
PageJL
-------------------
-- --- ---___ .. _ .. __ -09/07/95 15:14:19 C 0 N T I N U I N G ( 0 R D A I L Y ) C A L I 8 R A T I 0 N
VERIFICATION
\/ark Order # 9508439
Page ll._
Lab Sample ID CALKER
Fi le # ~M~5~I'"'"E-.3 ___ _
Method TPH-Diesel by mod. SW8015
Test ·Code DSLSSAEL
Analyte
Kerosene
Analysis Batch# TPGC1250905211301
Initial Calibration# GC12950719180700
Date Analyzed 09/05/95 19:43
Measured Reference
Concentration Concentration
ug/g ug/g
506 500
Reporting Subset _
Spikes Subset_
Specs Subset_
Recovery
t
101
Instrument §91_
Analyst TCN
Reviewer '"'H""JD'----+-
Recovery
Specification
Limits
Low High
t t
85 115
--
-
09/07/95 15:14:19 CONTINUING(OR DAILY) CALIBRATION Work Order # 9508439
-
Lab Sample ID CALDSL
Fi le # '-'M'""5"'"I""'E4_._ __ _
Method TPH-Diesel by mod. S\.J8015
Test Code DSLSSAEL
Analyte
Diesel
Surrogate Cs)
Octacosane
-- --
VERIFICATION , Page .!i._
Analysis Batch # TPGC1250905211301
Initial Calibration# GC12950719180700
Date Analyzed 09/05/95 20:28 Reporting Subset _
Spikes Subset_
Specs Subset _
Instrument GC12
Analyst TCN
Reviewer .:..:M""JD"----
Recovery
Specification
Limits
Measured Reference
Concentration Concentration Recovery Low High
ug/g ug/g t t t
499 500 100 85 115
I 52.9 j so.a I 106 I 85 I . 115
-------------
-------.. _____ .. ____ _
09/07/95 15:14:19 CONTINUING(OR DAILY) CALIBRATION Work Order # 9508439
Page 12_
Lab Sample ID CALJET
File# M5IE15
Method TPH-Diesel by mod. S~8015
Test Code DSLSSAEL
Analyte
Jet fuel CJP4l
VERIFICATION
Analysis Batch# TPGC1250905211301
Initial Calibration# GC12950719180700
Date Analyzed 09/06/95 04:44
Measured Reference
Concentration Concentration
ug/g ug/g
498 500
Reporting Subset_
Spikes Subset _
Specs Subset _
Recovery
%
100
Instrument GC12
Analyst TCN
Reviewer """M=JD"--_...,...
Recovery
Specification
Limits
Low High
% %
85 115
-
09/07/95 15:14:19 CONTINUING(OR DAILY) CALIBRATION Work Order I 9508439
Page 1§_
-
Lab Sample ID CALKER
File# M5IE16
Method TPH-Diesel by mod. 5\.18015
Test Code DSLSSAEL
Analyte
Kerosene
- - - -
VERIFICATION
Analysis Batch# TPGC1250905211301
Initial Calibration# GC12950719180700
Date Analyzed 09/06/95 05:28
Measured Reference
Concentration Concentration
ug/g ug/g
518 500
Reporting Subset _
Spikes Subset_
Specs Subset _
Recovery
i
104
Recovery
Instrument GC12 .
Analyst TCN
Reviewer .-MJ""'D"----
Specification
Limits
Low High
1 i
85 115
-------.. --- --
------ -- ----------09/07/95 15:14:19 C 0 N T I N U I N G ( 0 R D A I L Y ) C A l I B R A T I 0 N
VERIFICATION
Work Order I 9508439
Lab Sample ID CALDSL
Fi le # M5IE17
Method TPH-Diesel by mod. SW8015
Test Code DSLSSAEL
Analyte
Diesel
Surrogate Cs)
Octacosane
Analysis Batch# TPGC1250905211301
Initial Calibration# GC12950719180700
Date Analyzed 09/06/95 06:13
Measured Reference
Concentration Concentration
ug/g ug/g
455 500
Reporting Subset _
Spikes Subset_
Specs Subset _
Recovery
i
91
Recovery
1 Page 1L
Instrument GC12
Analyst TCN
Reviewer .:.;M.=.;JD:o.-__
Specification
Limits
Low High
i i
85 115
I 56.0 I 50.0 I 112 I 85 I 115
-
09/07/95 15:14:19
Method TPH-Diesel by mcxl. SW8015 Specification# DSLS
Lab Sample ID
Fi le ID
9508505-D2A
AA5IE9
9508439-01A
M5IE11
--
Project Sample
ID/Description Analyte
DIESEL
STKPILE UNIDENTIFIED ORGANICS
- ----
ANALYTICAL PROTOCOL su""ARY
co""ENTS/NARRATIVE
Flag Conment/Narrative
X Diesel not detected in parent sample.
Numerical value contributed by non-Diesel
compounds is 1.98 ug/g. This value is used to
calculate MS and MSD recoveries.
X The hydrocarbon value indicates the presence
of compounds eluting within the established
integration range for lubricating oil.
Corrective Action
--------
Work Order I 9508439 ·
Page]§_
- ---
-- -09/15/95 15:14:53 - --
Report Form
---- --
RADIAN ANALYTICAL SERVICES
FPAS REPORT
T A B L E 0 F C 0 N T E N T S
Client HAMILTON BEACH
Facility WASHINGTON NC
Client Code HAM BEACH NC
Analytical Batch ID
Work Order Summary
Work Order Comments
Flag Definitions
Protocol Summary for Oil and grease, Grav SW9071
Results Summary
Extraction Batch Summary
Analysis Batch Summary WLOGG950914120001
Results
Laboratory Blank Information
Laboratory Control Samples
Matrix Spikes
Sample Duplicates
Comments/Narrative
- - --- --
\./ork Order # 9508440
Certified By~@;.f);_;
Date ?/Mfl.5":
Pages
From To
1 1
2 2
3 3
4 4
5 5
6 6
7 7
8 9
10 10
11 11
12 12
13 13
14 14
- ---
09/15/95 15:14:53
Report RADIAN CORPORATION
To 3200 E. CHAPEL HILL RD.
P.O. BOX 13000.
Attention JIM NARKUNAS
Phone RTP
-
------------
Prepared
By
Radian Analytical Services
14046 Surrmit Dr., Bldg. B
P. O. Box 201088
Austin, TX 78720-1088
512/244-0855
CSC JALINDSEY
-
Project Sample ID/
Description
STKPILE
----...
MORK ORDER SUMMARY
Client Code HAM BEACH NC
Client HAMILTON BEACH
Facility WASHINGTON NC
\./ork ID WASHINGTON.NC
Case # .:..:NA'-'--------
SDG # -"'NA'"'--------
RAS # 50811AJAL
Lab Sample ID Test Code(sl
01A COMPOSITE OGG9SA00
OGXRSAOO
02A COMPOSITE MS OGG9SA00
OGXRSAOO
03A COMPOSIT MSD OGG9SAOO -OGXRSAOO
--- --
\./ork Order I 9508440
Page _1 _
RCN 650-138-02-01
Method Desciption
Oil and grease,Grav SW9071
Oil & grease Ext.-soxhlet
Oil and grease,Grav SW9071
Oil & grease Ext.-soxhlet
Oil and grease,Grav SW9071
Oil & grease Ext.-soxhlet
-- -
09/15/95 15:14:53
-- -
\IORK ORDER COMMENTS
The recoveries for the LCS and LCSD were outside of the laboratory-established
80i-120i tolerance limits. Method 9071 does not specify tolerances for Oil and
Grease.
- ----------- -
Work Order # 9508440
Page£_
----
--------------09/15/95 15:14:53 ANALYTICAL PROTOCOL su""ARY
Flag
< DL
NA
NC
ND
NR
NS
B
c
E
F
H
I
J
K
M
p
Q
R
s
T
x
y
z
,_ F L A G D E F I N I T I 0 N S
Definition
Result less than stated Detection Limit and greater than or equal to zero.
Analyte concentration not available for this analysis.
RPD and/or % Recovery not calcµlated. See Narrative for explanation.
Not detected. No instrument response for analyte or result less than zero.
Not reported. Result greater than or equal to stated Detection Limit and less than specified Reporting Limit.
Analyte not spiked.
Analyte detected in method blank at concentration greater than the Reporting Limit (and greater than zero).
Confirming data obtained using second GC column or GCMS.
Analyte concentration exceeded calibration range.
Interference or coelution suspected. See Narrative for explanation.
Presence of analyte previously confirmed by historical data.
Analyte identification suspect. See Narrative for explanation.
Result is less than stated Detection Limit but greater than or equal to specified Reporting Limit.
Peak did not meet method identification criteria. Analyte not detected on other GC column.
Result modified from previous Report. See Narrative for explanation.
Analyte not confirmed. Results from primary and secondary GC columns differ by greater than a factor of 3.
QC result does not meet tolerance in Protocol Specification.
Result reported elsewhere.
Analyte concentration obtained using Method of Standard Additions CMSA). ·
Second column confirmational analysis not performed.
See Narrative for explanation.
See Narrative for explanation.
See Narrative for explanation.
---Work Order # 9508440
Pagel_
--
-
09/15/95 15:14:53
Client HAMILTON BEACH
Facility WASHINGTON NC
Client Code HAM BEACH NC
Method Oil and grease.Grav S\.19071
Project Sample ID/Description
STKPILE
STKPILE
----
ANALYTICAL PROTOCOL SUHHART
Specification II .::O.::;GG:.:cX,_-=D ____ _
Extraction/Digestion
Lab Sample ID Test Code(sl Batch II
9508440-0lA OGG9SAOO 3540950913152000
9508440-0lA OGG9SA00 3540950913152000
-·-- ------
\Kirk Order # 9508440
Page£_
Analysis Batch #
WLOGG950914120001
WLOGG950914120001
I I --- ---
-- - - --·-09/15/95 15:14:53
Method Oil and grease.Grav S\./9071
Test Code OGG9SAOO
Project Sample ID:
Lab ID:
Fi le ID:
Date Collected:
Date Prepared:
Date Analyzed:
Dilution Factor:
Matrix:
Uni ts:
Report as:
Column:
Analyte
Oil and grease
STKPILE
9508440-0lA COMPOS
OGG90914-4
08/22/95
09/13/95
09/14/95 12:00:00
1
Sol id
mg/kg
dry weight
Cone. DL
1440 B 156
-----
RESULTS SUMMARY
STKPILE
9508440-0lA COMPOS
OGG90914-5
08/22/95
09/13/95
09/14/95 12:00:00
1
Sol id
mg/kg
dry weight
Cone. DL Cone.
1310 B 150
-
DL
---
\lork Order # 9508440
Page2_
-
Cone. DL
--
09/15/95 15:14:53
-
Method Hydrocarbons' extraction
Test Code HXSESAOO
Sample
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18 -
19
20
Quality Control
Blank
Laboratory Control Sample
Laboratory Control Sample Duplicate
Matrix Spike
Matrix Spike Duplicate
Sample Duplicate
----
EXTRACTION BATCH SUMMARY
Extraction Batch # 3540950913152000
Extraction Start Date/Time 09/13/95 15:20:00
Extraction Stop Date/Time 09/13/95 19:00:00
Project Sample ID Lab Sample ID
STKPILE 9508440-0lA
Project Sample ID Lab Sample ID
BLK953832
LCS955785
LCSD955785
STKPILE 9508440-02A
STKPILE 95D8440-03A
STKPILE 9508440-0lA
Work Order # 9508440
Page§_
Analyst ~
Reviewer--------
Sample Size '
g Cleanup Method
20.73 I
I
Sample Size
g Cleanup Method
---
---
---
20.88 '
20.01
21.65
---_ .. , .. - - -----
- ----09/15/95 15:14:53
Method Oil and grease.Grav S\.19071
Test Code OGG9SA00
-
Initial Calibration #,!:;NA:..:.-_____ _
Calibration Date -------
----__ ..
ANALYSIS BATCH SUMMARY
Analysis Batch # ~LOGG950914120001
Analysis Start Date/Time 09/14/95 12:00:00
Analysis Stop Date/Time 09/15/95 09:00:00
--.. .. -
Work Order # 9508440
Page I_
Instrument OGG9
~nalyst TDK
Reviewer ..:L:.:;KC=---------
Sequence/Analysis Time Project Sample ID Lab Sample ID Sample Type Analysis File#
1 09/14/95 12:00:00 BLK953832 Laboratory Blank OGG90914-1
2 09/14/95 12:00:00 LCS955785 Lab Control Sample OGG90914-2
3 09/14/95 12:00:00 LCSD955785 Lab Control sample Dup OGG90914-3
4 09/14/95 12:00:00 STKPILE 9508440-01A Sample OGG90914-4
5 09/14/95 12:00:00 STKPILE 9508440-0lA Sample Dup OGG909i4-5 '
6 09/14/95 12:00:00 STKPILE 9508440-02A Matrix Spike OGG90914-6
7 09/14/95 12:00:00 STKPILE 9508440-03A Matrix Spike Dup OGG90914-7
--
-
09/15/95 15:14:53
l'rojl!ct !!ampl!! ID .:::;!!-'-'TK""P....:1..:L.::.I! ______ _
Lab Sample ID 9508440-01A COMPOS
File# OGG90914-5
Method Oil and grease.Grav S~071
Test Code OGG9SA00
Analyte
Oil and grease
CAS #.
NO CAS
RESULTS
Digestion Batch # 3540950913152000
Analysis Batch # ~LOGG950914120001
Date Collected Oa/22/95
Date Received 08/23/95
Date Prepared 09/13/95
Instrument OGG9
Column ___ _
Analyst TDK
Date Analyzed 09/14/95 12:00:00 Reviewer ..::L:..:;KC=----
Aliquot Mass/Volume
21.65 (g)
Extract/Oigestate Volume
1 <mll
Dilution Factor 1
Measured Concentration
mg/kg
1310 B
--·--- -
.. _ --, ..
Work Order # 9508440
Page§_
Reporting Subset _ Matrix ~
Spikes Subset _
Specs Subset _
Detection Limit
mg/kg
150
\_I
Report As dry weight
i Moisture 22.2
I
I
Reporting Limit
mg/kg I
0
-------
- -----
09/15/95 15:14:53
Project Sample ID -=-S"'-"'TK"""'P..;;.I-=-L=-E ______ _
Lab Sample ID 9508440-0lA COMPOS
File# OGG90914-4
Method Oil and grease.Grav S~071
Test Code OGG9SA00
Analyte
Oil and grease
CAS #
NO CAS
-----
RESULTS
Digestion Batch # 3540950913152000
Analysis Batch # ~LOGG950914120001
-
Date Collected 08/22/95
Date Received 08/23/95
Date Prepared 09/13/95
Instrument OGG9
Date Analyzed 09/14/95 12:00:00
Column ___ _
Analyst TDK
Reviewer .:l:..:;KC,,__ __
Aliquot Mass/Volume
20.73 (g)
Extract/Digestate Volume
1 Cmll
Dilution Factor 1
Measured Concentration
mg/kg
144D B
----.. -
\.lark Order # 9508440
Page 2_
Reporting Subset _
Spikes Subset _
Specs Subset _
Matrix ~ •
Report As dry weight
~ Moisture 22.2 I
Detection Limit Reporting Limit
mg/kg mg/kg
156 0
---
-
09/15/95 15:14:53
Lab Sample ID BLK953832
File# OGG90914-1
Method Oil and grease.Grav SW9071
Test Code OGG9SAOO
Analyte
Oil and grease
- ---
LABORATORY BLANK INFORMATION Work Order # 9508440
Page 1.Q_
Digestion Batch # 3540950913152000
Analysis Batch # WLOGG950914120001
Date Prepared 09/13/95 tnstrument OGG9
Date Analyzed 09/14/95 12:00:00 Column ___ _
Analyst TDK
Reviewer ..::LK..:..:C'----
Aliquot Hass/Volume
20.00 (g)
Extract/Digestate Volume
1 (ml)
Dilution Factor 1
Measured Cone.
mg/kg
25.0 J
Reporting Subset _ . Matrix ~
Spikes Subset _
Specs Subset _
Detection Limit Reporting Limit
mg/kg mg/kg
126 0
----.. -----.. ----
----09/15/95 15:14:53
Method Oil and grease.Grav S~071
Test Code OGG9SA00
Control Std. # Vol. Added
30849-92 bQ__ fill_
----
----
Analyte
Oi l and grease
-- -
-----____ .. _
LABPRATORY CONTROL SAMPLE
Digestion Batch # 3540950913152000
Analysis Batch # ~LOGG950914120001
Work Order # 9508440
Page 1L
Date Prepared 09/13/95 Instrument OGG9 Reporting Subset _ _ Matrix §.
Date Analyzed 09/14/95 12:00:00 Column ___ _
Analyst TDK
Reviewer _LK_C __ _
Surrogate Sol 'n # Vol. Added LCS
Lab Sample ID ----LCS955785 ----
File ID OGG90914-2 ----
Spiked Measured
Cone. Cone. Rec.
mg/kg mg/kg %
5060 3280 65 a
Spikes Subset_· _ Report As received
Specs Subset__ % Moisture
LCS Duplicate
Lab Sample ID
LCSD955785
File ID OGG90914-3
Spiked Measured
Cone. Cone.
mg/kg mg/kg
5060 3520
Aliquot Hass or Vol
Extract Hass or Vol
Recovery
Spec.
Limits
Rec. Low -High
% % %
69 a 80 120
20.00 (g)
----'-1 Cmll
RPO
Spec.
Result Limit
% %
6.0 20
--
09/15/95 15:14:53
Project Sample ID ""'S"'"'TK""P-=1-=L=E-------
Method Oil and grease.Grav SW9071
Test Code OGG9SA00
Sp i ke Sol ' n # Vol. Added
30849-92 b_Q_ !!!L
M A T R I X S P I K E ( S )
Digestion Batch # 3540950913152000
Analysis Batch# WLOGG950914120001
Date Collected 08/22/95
Oate Received 08/23/95
Date Prepared 09/13/95
Instrument OGG9
Column ----Analyst TDK
Date Analyzed 09/14/95 12:00:00 Reviewer .:L:..:.;KC::._ __
Sample Spiked Sample
Lab Sample ID Lab Sample ID
Work Order # 9508440
Page 1.L
Reporting Subset __
Spl kes Subset __
Specs Subset __
Spiked Sample Dup
Lab Sample ID
Matrix ~
Report As dry weight
i Moisture 22.2
9508440-01A COMPOS 9508440-02A COMPOS 9508440-03A COMPOS ----File# OGG90914-4 File# OGG90914-6 File# OGG90914-7 I ----Surrogate Sol' n Vol. Added Aliquot Mass/Vol Aliquot Mass/Vol Aliquot Mass/Vol
----20.73 (g) 20.88 (g) 20.01 (g) Recovery
----Extract Mass/Vol Extract Mass/Vol Extract Mass/Vol Specifi-
1 CmU 1 (ml) 1 CmU cation ----Di l Fact. 1 Di l Fact. 1 Di l Fact. 1 Limits RPD
Spike Specifi-
' Sol 'n Measured Spiked Measured Spiked Measured cation
Analyte Cone. Cone. Cone. Cone. Rec. Cone. Cone. Rec. Low High Result Limit
mg/L mg/kg mg/kg mg/kg i mg/kg mg/kg i i i i l
Oi l and grease 50600 1440 B 6230 6980 89 6500 7350 91 80 120 2.2 20
----------'--_ .... _ ---
-----
09/15/95 15:14:53
Project Sample ID _S~TK~P~I~L=E ______ _
Method Oil and grease.Grav SW9071
Test Code OGG9SA00
Analyte
Oi l and grease
- -
- -.... - -.. .. --
S A H P L E D U P L I C A T E S
Digestion Batch # 3540950913152000
Analysis Batch # WLOGG950914120001
Date Collected 08/22/95
Date Received ~08=/-=2=3'-'/9_.5 ___ _
Oate Prepared .=.D.;..:91...:1-=-3,_,/9'-=5'-----
Date Analyzed 09/14/95 12:00:00
Sample
Instrument OGG9
Column
Analyst TDK
Reviewer -=L.:..:.KC;;;._ __
Duplicate
Lab Sample ID Lab Sample ID
Work Order # 9508440
Page .1L'
Reporting Subset _ Matrix ~
Spikes Subset _ Report As dry weight
Specs Subset _
9508440-0lA COMPOS 9508440-0lA COMPOS RPD
Di l Fact. 1 Oil Fact. 1
Measured Measured Specification
Cone. Cone. Result Limit
mg/kg mg/kg ~
1440 B 1310 B 10 20
--
09/15/95 15:14:53
Method Oil and grease.Grav SW9071 Specification# OGGX-D
Lab Sample ID
Fi le ID
--
Project Sample
ID/Description Analyte
--- -
ANALYTICAL PROTOCOL SUMMARY
COMMENTS/NARRATIVE
Flag CO!IYllent/Narrative Corrective Action
Work Order I 9508440
Page ll_
-- -.. ·-- -....... -
- -----08/30/9$ 11:23:49
Report RADIAN CORPORATION
To 3200 E. CHAPEL HILL RD.
P.O. BOX 13000
Attention JIM NARKUNAS
Phone ~R~T~P------------~
Prepared Radian Analytical Services
By 14046 Summit Dr., Bldg. B
P. 0. Box 201088
Austini TX 78720-1088
!>12l'.244 -085!>
csc JALINDSEY
Project Sample ID/
Description
STKPILE
--- - -WORK ORDER SUMMARY
Client Code HAM BEACH NC
Client HAMILTON BEACH
Facility WASHINGTON NC
Work ID WASHINGTON,NC
Case tt ~N~A'---------~
SDG # ~N~A.__ _______ _
RAS # 50811AJAL
Lab Sample ID Test Code (s)
OlA COMPOSITE MOISTVOO
MSRSSAOO
.. -.. - --
Work Order tt 9508~32
Page _1_
RCN 650-132-01-02
Method Desciption
Shared split with volatile
Percent moisture, SW846
--
-
08/30/95 11:23:49 ANALYTICAL PROTOCOL SUMMARY
FLAG DBFINITIONS
Flag Definition
< llL HesulL less than stated Detection Limit and greater than or equal Lo zero.
NA Analyte concentration not available for this analysis.
NC RPO and/or % Recovery not calculateq. See Narrative for explanation.
Nll NCJt detected. No instrument response for analyle or result less than zero.
NR Not reported. Result greater than or equal to stated Detection Limit and less than specified Reporting Limit.
NS Analyte not spiked.
H A11<JJyte dclecl.etl in method blank at conce11lralio11 g1e<1lt!1· lll<.111 lhe Heporlin<J J,hlil (and greater than zero).
C Confirming data obtained using second GC column or GCMS.
E Analyte concentration exceeded calibration range.
F Interference or coelution suspected. See Narrative for explanation.
H Presence of analyte previously confirmed by historical data.
I Analyte identification suspect. Se~ Narrative for explanation.
J Result is less than stated Detection Limit but greater than or equal to specified Reporting Limit.
K Peak did not meet method identification criteria. Analyte not detected on other GC column.
M Result modified from previous Report. See Narrative for explanation.
P Analyte not confirmed. Results from primary and secondary GC columns differ by greater than a factor of 3.
Q QC result does not meet tolerance in Protocol Specification.
R Result reported elsewhere.
s Analyte concentration obtained using Method of Standard Additions (MSA) .
T Second column confirmational analysis not performed.
X See Narrative for explanation.
Y See Narrative for explanation.
Z See Narrative for explanation.
---------'-.. -..
Work Order U 9508432
Page L
I
I
.. --·--
-- ---08/30/95 11:23:49
Client HAMILTON BEACH
Facility WASHINGTON NC
Client Code HAM BEACH NC
Method Percent moisture, SW846
Project Sample ID/Description
S'l'Kl'JJ,B
.. --- - --.. ..
ANALYTICAi, PROTOCOL SUMMARY
Specification # ~M~S~R~S~-~D'-------~
Extraction/Digestion
Lab Sample ID Test Code(s) Batch #
9!.>08432-0lA MSRSSAOO NA
---Work Order # 9508432
Page _3_
Analysis Batch #
BXMSRSSOB29081501
I
--
-
08/30/9~ 11:23:49
Method Percent moisture, SWB46
Test Code MSRSSAOO
Project Sample ID:
Lab ID:
File ID:
Date Collected:
Date Prepared:
Date Analyzed:
Dilution f'ac:tor:
Matrix:
Units:
Report as:
Column:
Analyte
Percent moisture
-·---
RKSu1.·rs
STKPILE
9508432-0lA
MSRS08290B-10
08/22/95
08/29/95 08:15
1
Solid
%
Cone. DL Cone.
22.2
.. ---
SUMMARY
DL Cone. DL
---.. ..
Work Order # 9508432
Page!_
.
Cone. DL .
--- - -
- ----
08/30/95 11:23:49
Method Percent moisture, SW846
Test Code MSRSSAOO
---- --
ANALYSIS BATCH SUMMARY
Analysis Batch U EXMSRS50829081501
Analysis Start Date/Time 08/29/95 08:15:00
Analysis Stop Date/Time 08/30/95 08:00:00
-
Initial Calibration U ~N~A _______ _
Calibration Date NA ---------
Sequence/Analysis Time Project Sample ID Lab Sample ID Sample Type
1 0~/29/95 08:15 9508486-0lA Sample
2 08/29/95 08:15 9508486-02A Sample
3 08/29/95 08:15 9508486-03A Sample
4 08/29/95 08:15 9508486-04A Sample
5 08/29/95 08:15 9508486-05A Sample
6 08/29/95 08:15 9508486-06A Sample
7 08/29/95 08:15 9508486-0?A Sample
8 08/29/95 08:15 9508486-08A Sample
9 08/29/95 08:15:00 9508486-0lA Sample Dup
10 08/29/95 08:15 STKPILE 9508432-0lA Sample
.. -- -
Work Order U 9508432
Page _5_
Instrument ~
Analyst ~
Reviewer ----------
Analysis File U
MSRS082908-1
MSRS082908-2
MSRS082908-3
MSRS082908-4
MSRS082908-5
MSRS082908-6
MSRS082908-7
MSRS082908-B
MSRS082908-9
MSRS082908-10
-· -
-
08/30/95 11:23:49
l'rojecl S,11nvte IIJ ::S.:.T.:.:Kc:.P..:l,,,Lc::Ec..._ ________ _
Lab Sample ID 9508432-0lA
File # MSRS082908-10
Method Percent moisture, SW846
Test Code MSRSSAOO
Analyte
Percent moisture
-- --
CAS #
NO_CAS
·-
RESULTS
Extraction Batch II
Analysis Batch tt EXMSRS50829081501
Date Collected 08[22[95 Instrument ~
Date Received 08[23[95 Column
Date Prepared Analyst ~
Date Analyzed 08[29[95 08:15 Reviewer
Aliquot Mass/Volume
(g)
Extract/Digestate Volume
(mL)
J>i luL ion ~·act or l
Measured Concentration
\
22.2
--- - -·-
Work Order # 9508432
Page _6 _
Reporting Subset __ Matrix §
Spikes Subset __ Report As NA
Specs Subset __ \ Moisture NA
Detection Limit Reporting Limit
-.. ---- -
08/30/95 11:23:49
Method Percent moisture, SW846
Lab Sample ID
File ID
- -
Project Sample
ID/Description
--
Specification# MSRS-D
Analyte
- -
AKALYTICAL PROTOCOL SUMMARY
COMMBHTS/HARRATIVB
Flag Comment/Narrative
- -- - -
Corrective Action
--
Work Order # 9508432
Page _a_
----