IDX GW Monitoring Rpt May 2001 (SF)-OCR

*6021 HSSF1066*
1111111111111111111111111111
DocumentlD NONCD0001814
Site Name HAMILTON BEACH/PROCTOR SILEX
oocumentType Progress/Monitoring Rpt (PRGMON)
RptSegment 1
DocDate
DocRcvd
Box
Access Level
Division
Section
Program
DocCat
7 /3/2001
2/20/2007
SF1066
PUBLIC
WASTE MANAGEMENT
SUPERFUND
IHS {IHS)
FACILITY
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GROUNDWATER MONITORING REPORT
FORMAY2001
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Groundwater Incident No. 14338
Site Priority Ranking B
Prepared for:
Hamilton BeachOProctor-Silex, fuc.
4421 Waterfront Drove
Glen Allen, Virginia 23060
Prepared by:
Radian futemational
P.O. Box 13000
Research Triangle Park, North Carolina 27709
July 2001
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CERTIFICATION PAGE
GROUNDWATER MONITORING REPORT
FORMAY2001
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Groundwater Incident No. 14338
Site Priority Ranking B
I, Craig L. Kennedy, a Licensed Geologist in the State of North Carolina, certify that
this report and its contents have been prepared under my direct control and personal
superv1s1on.
Craig L. Kennedy
NC 1614
80396909.0 I May200 I GW _Rpt.doc(07 /03/0 I) 1
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TABLE OF CONTENTS
Certification Page ................................................................................................................. i
L. fF' ... 1st o 1gures .................................................................................................................... 111
List of Tables .................. : ................................................................................................. iv
1.0 INTRODUCTION ........................................................................................................... 1-1
2.0 FIELD METHODS .......................................................................................................... 2-1
3.0 RESULTS ........................................................................................................................ 3-1
3.1 Water Level Measurements ................................................................................. 3-1
3.2 Analytical Results ................................................................................................ 3-1
APPENDIX A GROUNDWATER SAMPLING ANALYTICAL REPORTS
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1-1
2-1
3-1
3-2
3-3
LIST OF FIGURES
Topographic Map, Hamilton BeachOProctor-Silex, Inc.
Site Map, Washington Facility, Hamilton BeachOProctor-Silex, Inc.
Generalized Groundwater Flow Direction for Hydrogeologic Unit A,
Washington Facility
Generalized Groundwater Flow Direction for Hydrogeologic Unit B,
Washington Facility
Location of Surrounding Water Supply Wells
80396909.01 May2001 GW _ Rpt.doc(07/03/01) 111
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LIST OF TABLES
2-1 Monitoring Well Construction Data for Sampled Wells
Hamilton BeachOProctor-Silex, Inc., Washington, North Carolina
3-1 Water Level Measurements and Elevations, May 16, 2001
Hamilton BeachOProctor-Silex, Inc., Washington, North Carolina
3-2 Historical Water Level Elevations at MW-220
Hamilton BeachOProctor-Silex, Inc., Washington, North Carolina
3-3 Historical Water Level Elevations at MW-222
Hamilton BeachOProctor-Silex, Inc., Washington, North Carolina
3-4 Historical Water Level Elevations at MW-224
Hamilton BeachOProctor-Silex, Inc., Washington, North Carolina
3-5 Historical Water Level Elevations at MW-225
Hamilton BeachOProctor-Silex, Inc., Washington, North Carolina
3-6 Historical Water Level Elevations at MW-226
Hamilton BeachOProctor-Silex, Inc., Washington, North Carolina
3-7 Historical Water Level Elevations at MW-230
Hamilton BeachOProctor-Silex, Inc., Washington, North Carolina
3-8 Historical Water Level Elevations at MW-234
Hamilton BeachOProctor-Silex, Inc., Washington, North Carolina
3-9 Field Measurements, May 16, 2001
Hamilton BeachOProctor-Silex, Inc., Washington, North Carolina
3-10 Summary of Qualified Groundwater Analytical Results: May 2001
Volatile Organic Compounds by Method 8260B
Hamilton BeachOProctor-Silex, Inc., Washington, North Carolina
3-11 Historical Analytical Results for MW-220
Hamilton BeachOProctor-Silex, Inc., Washington, North Carolina
3-12 Historical Analytical Results for MW-222
Hamilton BeachOProctor-Silex, Inc., Washington, North Carolina
3-13 Historical Analytical Results for.MW-224
Hamilton BeachOProctor-Silex, Inc., Washington, North Carolina
80396909.01 May2001 GW _Rpt.doc(07!03101) lV
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LIST OF TABLES (Continued)
3-14 Historical Analytical Results for MW-225
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
3-15 Historical Analytical Results for MW-226
Hamilton Beach<> Proctor-Silex, Inc., Washington, North Carolina
3-16 Historical Analytical Results for MW-230
Hamilton Beach<> Proctor-Silex, Inc., Washington, North Carolina
3-17 Historical Analytical Results for MW-234
Hamilton Beach<> Proctor-Silex, Inc., Washington, North Carolina
80396909.01 May2001 GW _Rpt.doc(07 /03/0l) v
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1.0 INTRODUCTION
The Hamilton Beach<> Proctor-Silex (HB<>PS) facility is located at 234 Springs
Road, north of the City of Washington, in Beaufort County, North Carolina (Figure 1-1). The
facility and surrounding land parcel are owned by the City of Washington and have been leased
by HB<>PS since 1990 and previously leased by predecessor companies. The facility was
formerly involved in the final assembly, packaging, and warehousing of small electrical
household appliances.
Since 1992, when organic compounds were initially detected in groundwater at
the site, several phases of investigation have been performed, including a comprehensive site
assessment (CSA). The results of the CSA indicated that a plume of organic compounds is
present in groundwater underlying the site. The specific nature, volume, and time period of any
releases contributing to the plume are unknown. However, the principal constituents of the
plume are no longer used at the facility.
A plan for corrective action at the site has been proposed. Until corrective action
is implemented, groundwater will be sampled and analyzed on a quarterly schedule according to
a monitoring program requested by the North Carolina Department of Environment and Natural
Resources, Groundwater Section. Quarterly groundwater monitoring is being conducted in
February, May, .August, and November at seven wells: MW-220, -222, -224, -225, -226, -230,
and -234. These monitoring wells are located outside of the contaminant plume. In February
and August, six additional wells: MW-213, -214, -215, -216, -227, and -228 will be sampled.
These wells are located within the contaminant plume. The purpose of the monitoring program
is to detect potential migration of the plume.
Radian International (Radian) conducted groundwater sampling at the facility on
May 16, 2001. The sampling event included the measurement of water levels, temperature, pH,
and specific conductance; and the collection and analysis of samples from seven monitoring
wells. This report describes the sampling methods and presents the results for the quarterly
sampling event.
80396909.01 May2001 OW _Rpt.doc(07/03/01) 1-1
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2.0 FIELD METHODS
Groundwater was sampled on May 16, 2001 in general accordance with the
methods outlined in the Field Sampling and Analysis Plan prepared in April 1997 for this site.
Seven monitoring wells were sampled. They included MW-220, MW-222,
MW-224, MW-225, MW-226, MW-230, and MW-234. The locations of the monitoring wells
are shown in Figure 2-1. Details of well construction are provided in Table 2-1.
Prior to sampling, the water level in each well was measured using an electric
water-level indicator. The wells were then purged using inertial foot-valve pumps. Temperature,
pH, and specific conductance were measured and the data were recorded in a field notebook.
Purging continued until temperature, pH, and specific conductance stabilized; a minimum of
three well volumes was extracted; or the well was pumped dry. Each of the wells was then
sampled immediately following well purging using the inertial foot-valve pump. For QA/QC
purposes, a duplicate sample was collected at well MW-226.
The groundwater samples were sent by overnight courier to STL in Austin, Texas,
for analysis of volatile organic compounds by EPA Method 8260B.
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3.0 RESULTS
3.1 Water Level Measurements
Table 3-1 presents the depth to groundwater and static water-level elevations
measured in the seven wells sampled. Maps showing the generalized direction of groundwater
flow in hydrogeologic units A and B are included as Figures 3-1 and 3-2, respectively.
Historical water-level elevations in sampled wells are included in Tables 3-2 to 3-8.
3.2 Analytical Results
Field measurements of water temperature, pH, and specific conductance are
summarized in Table 3-9. Qualified analytical results are summarized in Table 3-10. Qualified
data sheets and laboratory reports are included in Appendix A.
No analytes were detected above the groundwater standards in samples from
wells located near the perimeter of the site (MW-220, MW-222, MW-224, MW-225, MW-230,
and MW-234), nor were any analytes detected above the groundwater standards in the sample
from well MW-226, which is completed in the confined Limestone Aquifer.
Historical analytical results for the sampled wells are presented in Tables 3-17 to
3-23. A comparison of the record for wells located near the perimeter of the site suggests that
the plume remains on-site, at least 200 feet from potential receptors located north of Spring Road
(Figure 3-3).
80396909.0 I May200 I GW _ Rpt.doc(07 /03/0 I) 3-1
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FIGURES
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TABLES
-------------------
Table 2-1
Monitoring Well Construction Data for Sampled Wells
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Top of Casing
Installation Elevation Total Depth Screen Interval
Well No. Date (ft. above MSL) (ft. bgs) (ft. bgs)
MW-220 5/5/98 31.50 34 25 -34
MW-222 5/6/98 35.11 40 31-40
MW-224 11/13/98 33.43 34 25 -34
MW-225 11/13/98 33.43 10 4-10
MW-226 9/30/98 28.46 75 70-75
MW-230 10/26/98 33.47 14 8 -14
MW-234 6/23/99 35.03 26 17 -26
Monitoring wells 220 and 222 installed by Radian Mobile Field Services.
Monitoring wells 226 was installed by Parratt Wolff, Inc.
Monitoring wells 224, 225, 230, and 234 installed by Probe Technology, Inc.
80396909.01 May2001GW_Rpt.doc (07/03/01)
Filter Pack
· <ft. bl!s)
24-34
30 -40
24-34
3 -10
69 -75
7 -14
16-26
Bentonite Seal Grout Seal
(ft. bl!S) {ft, bl!S)
23 -24 o D 23
29-30 0-29
23 -24 0 -23
2-3 0-2
67 -69 0 -67
5-7 0-5
13 -16 0-13
Well
MW-201S
MW-208
MW-213
MW-216
MW-217
MW-219
MW-220
MW-221
MW-222
MW-223
MW-224
MW-225
MW-226
MW-227
MW-230
MW-233
MW-234
msl = mean sea level
Table 3-1
Water Level Measurements and Elevations
May 16, 2001
Hamilton BeachOPr-octor-Silex, Inc.
Washington, North Carolina
Measuring Point
Elevation Water Level Elevation
(ft above msl)) Deoth to Water (ft) (ft above msl)
29.74 3.93 25.81
32.11 7.44 24.67
28.44 4.24 24.20
32.82 9.62 23.20
32.75 8.73 24.02
31.83 8.29 23.54
31.50 9.55 21.95
31.39 9.12 22.27
35.11 14.20 20.91
35.15 7.20 27.95
33.43 9.20 24.23
33.43 9.22 24.21
28.46 19.15 9.31
28.47 5.80 22.67
33.47 11.30 22.17
34.55 11.51 23.04
35.03 11.50 23.53
80396909.01 May200 I GW _Rpt.doc(07 /03/01)
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Table 3-2
Historical Water Level Elevations at MW-220
HamiltoJ.J, BeachOProctor-Silex, Inc.
Washington, North Carolina
Water Level Elevation
Date (ft. above msl)
May 13, 1998 25.13
November 16, 1998 20.55
July 1, 1999 21.50
October 20, 1999 25.63
February 2, 2000 25.85
Mav2, 2000 25.81
September 6, 2000 22.90
November 28, 2000 21.71
February 19, 2001 23.45
May 16, 2001 21.95
msl = mean sea level
80396909.01 May2001GW_Rpt.doc (07/03/01)
Table 3-3
Historical Water Level Elevations at MW-222
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Water Level Elevation
Date (ft. above msl)
May 13, 1998 22.34
November 16, 1998 19.99
July 1, 1999 20.61
October 20, 1999 24.22
February 2, 2000 23.34
May2, 2000 23.58
September 6, 2000 21.50
November 28, 2000 20.52
February 19, 2001 21.34
May 16, 2001 20.91
msl = mean sea level
80396909.01 May2001GW_Rpt.doc (07/03/01)
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Table 3-6
Historical Water Level Elevations at MW-226
Hamilton Beach¢Proctor-Silex, Inc.
Washington, North Carolina
Date
May 13, 1998
November 16, 1998
July 1, 1999
October 20, 1999
February 2, 2000
May 2, 2000
September 6, 2000
November 28, 2000
February 19, 2001
May 16, 2001
msl = mean sea level
NM= Not measured
80396909.01 May200!GW _Rpt.doc (07/03/01)
Water Level Elevation
(ft. above msl)
NM
8.43
8.54
11.11
10.23
10.81
9.41
9.19
9.20
9.31
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Table 3-8
Historical Water Level Elevations at MW-234
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Date
Mav 13, 1998
November 16, 1998
July 1, 1999
October 20, 1999
February 2, 2000
Mav2, 2000
September 6, 2000
November 28, 2000
Februarv 19, 2001
May 16, 2001
msl = mean sea level
NM= Not measured
80396909.01 May2001GW_Rpt.doc (07/03/01)
Water Level Elevation
(ft. above msl)
NM
NM
23.24
25.71
25.67
25.56
25.04
23.23
24.20
23.53
Well Date Time
MW-220 5/16/01 11:45
MW-222 5/16/01 12:05
MW-224 5/16/01 11:20
MW-225 5/16/01 11:10
10:05
10:10
MW-226 5/16/01 10:12
10:14
10:15
10:17
MW-230 5/16/01 09:34
MW-234 5/16/01 10:52
803%909.01 May2001 GW _ Rpt.doc (07 /03/0 I)
Table 3-9
Field Measurements
May 16, 2001
Hamilton Beach¢Proctor-Silex, Inc.
Washington, North Carolina
Volume Purged
(Gal) Pur2ine: Criteria
0.75 3 well volumes
0.80 3 well volumes
0.75 3 well volumes
0.01 Drv
9.0
12.0
13.0 Stabilized parameters
14.0
15.0
16.0
0.08 Drv
0.5 3 well volumes
Specific
Temperature Conductance
(OC) (µS) nH
17.5 120 6.2
18.5 340 7.1
17.5 320 7.1
20.0 195 4.8
19.0 440 7.5
19.0 440 7.4
19.0 435 7.6
19.0 450 7.5
19.0 450 7.4
19.0 450 7.4
16.0 220 4.7
18.0 140 6.4
-~-----~~---~------
-ma>• - - - - ---.. ----.... •· .. - -
Table 3-10
Summary of Qualified Groundwater Analytical Results: May 2001
Volatile Organic Compounds by Method 8260B .
Hamilton BeachOProctor-Silex, Washington, North Carolina
Sample ID MW-220
Date of Sampling 5/16/2001
Analyte
Carbon Disulfide ND (0.0684)
1, 1-Dichloroethane ND (0.124)
1, 1-Dichloroethene ND (0.122)
cis-1,2-Dichloroethene ND (0.112)
Trichloroethene ND (0.137)
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
Bold values exceed Standards.
ND ( ) =Not detected at specified detection limit.
J = Estimated value.
80396909.01 May2001GW_Rpt.doc (07/03/01)
MW-222
5/16/2001
ND (0.0684)
0.536
0.0793 J
0.260 J
ND (0.137)
MW-224 MW-225 MW-226
5/16/2001 5/16/2001 5/16/2001
0.715 J ND (0.0684) ND (0.0684)
ND (0.124) ND (0.124) ND (0.124)
ND (0.122) ND (0.122) ND (0.122)
ND (0.112) ND (0.112) ND (0.112)
ND (0.137) ND (0.137) ND (0.137)
MW-230 MW-234
5/16/2001 5/16/2001
ND (0.0684) ND (0.0684)
ND (0.124) ND (0.124)
ND (0.122) ND (0.122)
0.288 J NE> (0.112)
0.292 J ND (0.137) -.-
Table 3-11
Historical Analytical Results for MW-220
Hamilton BeachOProctor-Silex, Inc.
Groundwater May
Analvte Standard 1998
Carbon disulfide 700 ND (0.0547)
1, 1-Dichloroethane 700 ND (0.0576)
Methyl t-butyl ether 200 ND (0.0365)
Groundwater September
Analvte Standard 2000
Carbon disulfide 700 ND (0.0484)UJ
1, 1-Dichloroethane 700 ND (0.0487)
Methyl t-butyl ether 200 ND (0.0469)
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
J = Estimated value.
ND =Not detected at (detection limit).
UJ = Not detected and the detection limit is estimated.
80396909.01 May2001 GW _Rpt.doc (07/03/01)
Washington, North Carolina
November July October
1998 1999 1999
ND (0.0547) 0.426 J 0.162
ND (0.0576) ND (0.0736) ND (0.0588)
ND (0.0365) UJ ND (0.0334) ND (0.0512)
November February May
2000 2001 2001
ND (0.0684) ND (0.0684) UJ ND (0.0684)
0.426 J 0.456 J ND (0.124)
ND (0.116) ND (0.116) ND (0.116)
February May
2000 2000
ND (0.0484) UJ ND (0.0484)
ND (0.0487) ND (0.0487)
ND (0.0469) 0.441 J
-~ - - - ----.. -~ ,-' .. --' - - -
-~------~----~-~~--
Groundwater
Analyte Standard
Carbon disulfide 700
1, 1-Dichloroethane 700
l, 1-Dichloroethene 7
cis-1 ,2-Dichloroethene 70
Toluene 1,000
Groundwater
Analvte Standard
Carbon disulfide 700
1, 1-Dichloroethane 700
1, 1-Dichloroethene 7
cis-1,2-Dichloroethene 70
Toluene 1,000
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
J = Estimated value.
ND= Not detected at (detection limit).
Table 3-12
Historical Analytical Results for MW-222
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
May November July
1998 1998 1999
ND (0.0547) ND (0.0547) 0.388 J
ND (0.0576) ND (0.0576) ND (0.0736)
0.0908 J ND (0.0715) ND (0.102)
ND (0.0383) ND (0.223) U ND (0.0595)
0.156 J ND (0.0522) ND (0.0766)
September November February
2000 2000 2001
ND (0.0484) UJ ND (0.0684) ND (0.0684) UJ
0.328 J ND (0.124) 0.589
0.0766 J 0.0668 J 0.102 J
0.139 J 0.124 J 0.222 J
ND (0.0680) ND (0.137) ND (0.0637)
UJ =Not detected and the detection limit is estimated.
U =Not present above the associated level, blank contamination present.
80396909.01 May2001GW_Rpt.doc (07/03/01)
October February May
1999 2000 2000
0.0944 ND (0.0484) ND (0.0484)
UJ
ND (0.0588) ND (0.0487) 0.338 J
ND (0.0819) ND (0.0697) ND (0.279) U
ND (0.0407) ND (0.0603) ND (0.0603)
ND (0.0645) ND (0.0680) ND (0.0680)
May
2001
ND (0.0684)
0.536
0.0793 J
0.260 J
ND (0.0637)
Table 3-13
Historical Analytical Results for MW-224
Hamilton BeachOProctor-Silex, Inc.
Groundwater November
Analvte Standard 1998
Carbon disulfide 700 ND (0.0547)
Toluene 1,000 ND (0.0522)
Groundwater November
Analvte Standard 2000
Carbon disulfide 700 0.697 J
Toluene 1,000 ND (0.0637)
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
J = Estimated value.
ND =Not detected at (detection limit).
UJ =Not detected and the detection limit is estimated.
80396909.0 I May200 I GW _ Rpt.doc (07 /03/0 I)
Washington, North Carolina
July October February
1999 1999 2000
2.22 2.72 ND (1.05) UJ
ND (0.0766) ND (0.0645) ND (0.0680)
February May
2001 2001
ND (0.571) UJ 0.715 J
ND (0.0637) ND (0.0637)
May September
2000 2000
ND (0.334) U . 0.350 J
0.0542 J ND (0.0680)
--· - -.. ·• -.. - - --- - -.. - - -
-~-~~--~----~---~--
Table 3-14
Historical Analytical Results for MW-225
Hamilton BeachOProctor-Silex, Inc.
Groundwater November
Analvte Standard 1998
Carbon disulfide 700 ND (0.0547)
Chloroform 0.19 ND (0.0480)
Groundwater November
Analvte Standard 2000
Carbon disulfide 700 ND (0.0684)
Chloroform 0.19 ND (0.0896)
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
ND = Not detected at (detection limit).
UJ =Not detected and the detection limit is estimated.
80396909.01 May2001GW _Rpt.doc (07/03/01)
Washington, North Carolina
July October February
1999 1999 2000
ND (0.864) 0.0691 ND 70.0484) UJ
ND (0.0424) 0.171 ND (0.0670)
February May
2001 2001
ND (0.511) UJ ND (0.0684)
ND (0.0896) ND (0.0896)
September
Mav2000 2000
ND <o.0484) ND (0.0484) UJ
ND (0.0670) ND (0.0670)
Table 3-15
Historical Analytical Results for MW-226
Hamilton BeachOProctor-Silex, Inc.
Groundwater November
Analvte Standard 1998
Carbon disulfide 700 ND (0.0547)
Groundwater November
Analvte Standard 2000
Carbon disulfide 700 ND (0.0684)
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
J = Estimated value.
ND =Not detected at (detection limit).
UJ =Not detected and the detection limit is estimated.
80396909.01 May2001GW _Rpt.doc (07/03/01)
Washington, North Carolina
July October February
1999 1999 200
ND (0.864) 0.0950 ND (0.0484) UJ
February May
2001 2001
ND (0.0684) UJ ND (0.0684)
May September
2000 2000
ND (0.0484) UJ 0.210 J
--· - -.. - - - --- - -.. - -.. - -
-----------~-~--~--
Groundwater
Analvte Standard
1, 1-Dichloroethane 700
1, 1-Dichloroethene 7
Cis-1,2-Dichloroethene 70
Toluene 1,000
Trichloroethene 2.8
Groundwater
Analyte Standard
1, 1-Dichloroethane 700
1, 1-Dichloroethene 7
Cis-1,2-Dichloroethene 70
Toluene 1,000
Trichloroethene 2.8
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
I = Estimated value.
ND= Not detected at (detection limit).
Table 3-16
Historical Analytical Results for MW-230
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
November July October
1998 1999 1999
ND (0.0576) ND (0.0736) 0.265
ND (0.306) U ND (0.102) 0.133
ND (2.67)U ND (0.0595) 0.304
ND (0.0522) 0.286 ND (0.309) U
ND (2.05)U ND (0.0929) 0.921
November February May
2000 2001 2001
ND (0.124) ND (0.124) · ND (0.124)
ND (0.122) ND (0.122) ND (0.122)
0.142 I 0.0969 I 0.288 I
ND (0.0637) ND (0.0637) ND (0.0637)
0.235 I 0.160 J 0.292J
U = Not present above the associated level; blank contamination is present.
80396909.01 May2001GW_Rpt.doc (07/03/01)
February May September
2000 2000 2000
0.189 I ND (0.348) U ND (0.0487)
0.148 I 0.593 ND (0.0697)
0.354 I 0.573 0.102 I
0.284 I 0.0826 I 0.126 J
0.661 I 1.11 ND (0.355) U
Groundwater
Analvte Standard
Carbon disulfide 700
1, 1-Dicbloroethene 7
Groundwater
Analyte Standard
Carbon disulfide 700
1, 1-Dichloroethene 7
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
J = Estimated value.
ND= Not detected at (detection limit).
Table 3-17
Historical Analytical Results for MW-234
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
July October February
1999 1999 2000
ND (0.864) 0.0600 ND (0.0484) UJ
ND (0.102) ND (0.0819) ND (0.0697)
November February May
2000 2001 . 2001
ND (0.0684) ND (0.0684) UJ ND (0.0684)
ND (0.122) ND (0.122) ND (0.122)
UJ =Not detected and the detection limit is estimated.
80396909.01 May2001GW_Rpt.doc (07/03/01)
May September
2000 2000
ND (0.0484) ND (0.0484) UJ
0.145 J ND (0.0697)
----~-~-~--~-~-~---
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APPENDIX A
GROUNDWATER SAMPLING ANALYTICAL REPORTS
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QUALIFIED DATA
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Hamilton Beach<>Proctor-Silex, Washington, NC
Data Evaluation Report
Radian International, June 2001
Introduction
Radian International (Radian) collected seven groundwater samples (0501HBWW-220, -222, -224 through
-226, -230, and -234) and a field duplicate at the Hamilton Beach<>Proctor Silex facility in Washington,
NC on May 16, 2001. The samples were submitted to Severn Trent Laboratories (STL) in Austin, Texas
for the determination of volatile organic compounds (VOC) by SW-846 Method 8260B. A trip blank was
included with the shipment of samples to the laboratory for the analysis of voe.
Radian reviewed the analytical results, which were reported by the laboratory under work order number
20105139. The data evaluation was modeled after the National Functional Guidelines for Organic Data
Review (EPA, October 1999). Qualitative and quantitative limitations associated with the analytical results
were identified and defined based on the results of specific quality control (QC) criteria. Accuracy was
determined from the review of spike recoveries. Precision was based on the evaluation of laboratory
duplicate results. Sensitivity was evaluated by comparing reported detection limits to project-specific
maximum reporting limits. Representativeness was evaluated from the review of holding time and blank
data. Sample results have been qualified based on the results of the data review process, as described
below.
Sample Condition upon Receipt and Holding Times
All samples were received intact and in good condition by STL on May 17, 2001. The temperature of the
sample containers upon receipt at the laboratory was within laboratory specification limits of 1-4°C. Air
bubbles were not observed any volatile organic analysis (VOA) vials.
Technical hold times were assessed by comparing the sampling dates with that of the analysis date.
Samples were analyzed for VOC within EPA-established holding times of seven days for unpreserved
samples.
Calibration
Gas chromatograph/mass spectrometer (GC/MS) instrument tuning and performance checks are performed
to ensure the instrument's ability to provide appropriate mass-resolution, identification, and sensitivity. All
samples were analyzed for VOC within twelve hours of the performance check standard. The tuning
compound mass-ion abundance criteria for the VOA were reported within control limits.
Control limits for initial and continuing calibrations are established to ensure that the instrument is capable
of producing accurate quantitative and qualitative data at the beginning and throughout each of the
analyses. Since the results of the initial calibration were not included in the laboratory report, the
evaluation was based on the review of the continuing calibration data. Laboratory specifications were met
during all volatile organic continuing calibrations conducted on instrument MSDA. In addition, the
recovery for all target analytes, except those noted below associated with sample analyses, fell within 80-
120% of the continuing calibration standard's true value.
• Continuing calibration of05/21/0l @15:37-acrolein (130%R) and iodomethane (74%).
• Continuing calibration of 05/22/01 @03: 19 -trans-1,4-dichoro-2-butene (73 %R), 2,2-dichloropropane
(68%R), tetrachloroethene (129%), and vinyl acetate (57%R)
0501 HB-PS Wash DE.doc
Page 1 of3
06/14/01
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Field Duplicates
Field duplicate samples are used to demonstrate acceptable precision during the sample collection process.
Acceptable precision was observed during the analysis of field duplicate samples 0501HBWW226 and
0501HBWWD999.
Sample Results
The laboratory provided volatile organic results for all North Carolina groundwater quality standards
presented in 15A NCAC 2L.0202. Detection limits were less than or equal to Class GA standard or
practical quantitation limits.
The laboratory flagged sample results less than the practical quantitation limit and sample detection limit
with a J and U, respectively. All positive sample results that are less than the practical quantitation limit
are considered estimated (J).
0501 HB-PS Wash DE.doc
Page3 of3
06/14/01
-- - -- --·-- --- - -SECTION IV
Analytical Results
MS-VOA
SW8260B
Parameter
Acetone
Acetonitrile
Acrolein
Acrvlonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
n-Butvlbenzene
sec-Butvlbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-l ,3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
CAS
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
SECTION IV -Analytical Results -05/30/2001 13:23
050IHBWW230
2010513901
Aaueous
Received
NA
05/16/2001 09:40
05/21/2001 22: I 0
05/21/2001 22:10
I
MSDA
uidL
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
050 I HBWW226
2010513902
Aaueous
Received
NA
05/16/2001 10:20
05/21/2001 22:38
05/21/2001 22:38
I
MSDA
ug/L
DL RL Cone Flaa DL RL
0.438 0.000 ND 0.438 0.000
6.82 0.000 ND 6.82 0.000
3.79 0.000 ND. 3.79 0.000
0.446 0.000 ND 0.446 0.000
0.0641 0.000 ND 0.0641 0.000
0.0998 0.000 ND 0.0998 0.000
0.131 0.000 ND 0.131 0.000
0.118 0.000 ND 0.118 0.000
0.170 0.000 ND 0.170 0.000
0.199 0.000 ND 0.199 0.000
0.200 0.000 ND 0.200 0.000
0.102 0.000 ND 0.102 0.000
0.105 0.000 ND 0.105 0.000
0.0911 0.000 ND 0.0911 0.000
0.0684 0.000 ND 0.0684 0.000
0.0652 0.000 ND 0.0652 0.000
0.114 0.000 ND 0.114 0.000
0.0842 0.000 ND 0.0842 0.000
0.0925 0.000 ND 0.0925 0.000
0.0896 0.000 ND 0.0896 0.000
0.0938 0.000 ND 0.0938 0.000
---
0501HBWW224
2010513904
Aaueous
Received
NA
05/16/200 I 11 :25
05/21/2001 23:06
05/21/2001 23 :06
l
MSDA
ul!IL
Cone Flaa DL
ND 0.438
ND 6.82
ND 3.79
ND 0.446
ND 0.0641
ND 0.0998
ND 0.131
ND 0.118
ND 0.170
ND 0.199
ND 0.200
ND 0.102
ND 0.105
ND 0.0911
0.715 J 0.0684
ND 0.0652
ND 0.114
ND 0.0842
ND 0.0925
ND 0.0896
ND 0.0938
Page 4
Sample results have been qualified by URS-Radian based on the results of the data review process, which is modeled after 1/te N111io1111/ F1111clio11al G11ide/i11es for Organic mu/ lnorg1111ic lJa111 Rel'ie11•
f1 I~ f.'P .\ nr·f,,h, .. r 1 ()l)C) ·•nit f:,•hrw1n• l ClQ4 n•<:-r"11,., .. ,;"'''"'
- -
RL
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
of 46
SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
Chloromethane
3-Chloropropene
2-Chlorotoluene
4-Chlorotoluene
Client Sample ID
Lab Sample ID
CAS
74-87-3
107-05-1
95-49-8
106-43-4
l .2-Dibromo-3-chlorooropane 96-12-8
Dibromochloromethane 124-48-1
1 2-Dibromoethane 106-93-4
Dibromomethane 74-95-3
trans-I 4-Dichloro-2-butene 110-57-6
1.4-Dichlorobenzene 106-46-7
I 2-Dichlorobenzene 95-50-1
I 3-Dichlorobenzene 541-73-1
Dich lorodifluoromethane 75-71-8
1.1-Dichloroethane 75-34-3
1,2-Dichloroethane 107-06-2
1.1-Dichloroethene 75-35-4
cis-1.2-Dichloroethene 156-59-2
trans-I 2-Dichloroethene 156-60-5
I 2-Dichloroorooane 78-87-5
1.3-Dichloroorooane 142-28-9
2 2-Dichloropropane 594-20-7
1.1-Dichloroorooene 563-58-6
cis-I .3-Dichloroorooene 10061-01-5
trans-I 3-Dichloroorooene 10061-02-6
Ethvl methacrvlate 97-63-2
Ethvlbenzene 100-41-4
Hexachloro-1 3-butadiene 87-68-3
2-Hexanone 591-78-6
SECTION IV -Analytical Results -05/30/2001 13:23
0501HBWW230
2010513901
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Hfr ~
ND
ND
ND
0.288 J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396907.01 [20105139) Hamilton Beach-Proctor Silex
STLAustiu
DL
0.127
0.0777
0.178
0.0974
0.548
0.140
0.137
0.148
0.780
0.150
0.0965
0.0846
0.~37
0.124
0.102
0.122
0.112
0.119
0.0869
0.135
0.160
0.0994
0.0818
0.0908
0.101
0.136
0.331
0.169
0501HBWW226 0501HBWW224
2010513902 2010513904
..
RL Cone Flaa DL RL Cone Flaa . DL
0.000 ND 0.127 0.000 ND 0.127
0.000 ND 0.0777 0.000 ND 0.0777
0.000 ND 0.178 0.000 ND 0.178
0.000 ND 0.0974 0.000 ND 0.0974
0.000 ND 0.548 0.000 ND 0.548
0.000 ND 0.140 0.000 ND 0.140
0.000 ND 0.137 0.000 ND 0.137
0.000 ND 0.148 0.000 ND 0.148
0.000 ND 0.780 0.000 ND 0.780
0.000 ND 0,150 0.000 ND 0.150
0.000 ND 0.0965 0.000 ND 0.0965
0.000 ND 0.0846 0.000 ND 0.0846
6.666 .WQ R. G.~~+ 0 000 -Nfi e o.zJ'7
0.000 ND 0.124 0.000 ND 0.124
0.000 ND 0.102 0.000 ND 0.102
0.000 ND 0.122 0.000 ND 0.122
0.000 ND 0.112 0.000 ND 0.112
0.000 ND 0.119 0.000 ND 0.119
0.000 ND 0.0869 0.000 ND 0.0869
0.000 ND 0.135 0.000 ND 0.135
0.000 ND 0.160 0.000 ND 0.160
0.000 ND 0.0994 0.000 ND 0.0994
0.000 ND 0.0818 0.000 ND 0.0818
0.000 ND 0.0908 0.000 ND 0.0908
0.000 ND 0.101 0.000 ND 0.101
0.000 ND 0.136 0.000 ND 0.136
0.000 ND 0.331 0.000 ND 0.331
0.000 ND 0.169 0.000 ND 0.169
Page 5
Sample results have been qualified by URS-Radian based on the results of the data review process, which is modeled alicr 1/ie N111io1111/ F1111ctio11a/ G11ide/i1w~Jor Org1111ic 111ui bwrg1111ic 011111 Re1•h•11• --\().-Oon.-.... , ... ·~·1--·-- -·-- - - - - -
. RL
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
of 46
·--
--------·-----------SECTION IV
Analytical Results
MS-VOA
SW8260B
Client Sample ID
Lab Sample ID
Continued
Parameter CAS
lodomethane 74-88-4
lsoorooylbenzene 98-82-8
4-lsooronvltoluene 99-87-6
Methyl methacrvlate 80-62-6
Methvl tert-butvl ether (MTBE) 1634-04-4
4-Methyl-2-oentanone (MIBK) 108-10-1
Methvlene chloride 75-09-2
Naohthalene 91-20-3
Prooanenitrile 107-12-0
n-Prooylbenzene 103-65-1
Styrene 100-42-5
1 1 1.2-Tetrachloroethane 630-20-6
I.I 2 2-Tetrachloroethane 79-34-5
Tetrachloroethene 127-18-4
Tetrahydrofuran 109-99-9
Toluene 108-88-3
1.2 3-Trichlorobenzene 87-61-6
1 2 4-Trichlorobenzene 120-82-1
I, 1, I-Trichloroethane 71-55-6
1 I 2-Trichloroethane 79-00-5
Trich loroethene 79-01-6
Trichlorofluoromethane 75-69-4
1.2 3-Trichloronronane 96-18-4
I 1 2-Trichlorotrifluoroethane 76-13-1
I 2 4-Trimethylbenzene 95-63-6
I 3 5-Trimethvlbenzene 108-67-8
Vinyl acetate 108-05-4
Vinvl chloride -75-01-4
SECTION IV -Analytical Results -05/30/200 I 13:23
0501HBWW230
2010513901
Cone Flaa
ND t>.::r
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.292 J
ND
ND
ND
ND
ND
Nf7 ~
ND
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
DL RL
0.109 0.000
0.0931 0.000
0.115 0.000
0.131 0.000
0.116 0.000
0.178 0.000
0.126 0.000
0.0801 0.000
1.59 0.000
0.140 0.000
0.0977 0.000
0.111 0.000
0.0870 0.000
0.144 0.000
0.900 0.000
0.0637 0.000
0.551 0.000
0.135 0.000
0.169 0.000
0.0821 0.000
0.137 0.000
0.106 0.000
0.288 0.000
0.123 0.000
0.124 0.000
0.0905 0.000
0.0948 tumo
0.114 0.000
0501HBWW226 0501HBWW224
2010513902 2010513904
Cone Flai:a DL RL Cone Flaa DL
ND ',:r 0.109 0.000 ND vs 0.109
ND 0.0931 0.000 ND 0.0931
ND 0.115 0.000 ND 0.115
ND 0.131 0.000 ND 0.131
ND 0.116 0.000 ND 0.116
ND 0.178 0.000 ND 0.178
ND 0.126 0.000 ND , .. (J.126
ND 0.0801 0.000 ND 0.0801
ND 1.59 0.000 ND 1.59
ND 0.140 0.000 ND 0.140
ND 0.0977 0.000 ND 0.0977
ND 0.111 0.000 ND 0.111
ND 0.0870 0.000 ND 0.0870
ND 0.144 0.000 ND 0.144
ND 0.900 0.000 ND .. 0.900
ND 0.0637 0.000 ND 0.0637
ND 0.551 0.000 ND 0.551
ND 0.135 0.000 ND 0.135
ND 0.169 0.000 ND 0.169
ND 0.0821 0.000 ND 0.0821
ND 0.137 0.000 ND 0.137
ND 0.106 0.000 ND 0.106
ND 0.288 0.000 ND 0.288
ND 0.123 0.000 ND 0.123
ND 0.124 0.000 ND 0.124
ND 0.0905 0.000 ND 0.0905
Mf) R 6.6948 0.000 Nf) f!-{l.Q948
ND 0.114 0.000 ND 0.114
Page 6
Sample results have been qualified by URS-Radian based on the results of the data review process, which is modeled after 1/1e N111io11al F1111c1io11a/ G'11ideli11es for Org1111ic mu/ /11orgm11c IJalil Re1•ie11•
fl 1<.:' f.'fl-'\ ()1-1 .. h.~r 1000 ••n·I f.',•hrw1f"'\• 10()1 r1•<·f..,, .. ,•ti•• •I••)
RL
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
6.600
0.000
of 46
SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
p-Xvlene/m-Xvlene
o-Xvlene
Client Sample ID
Lab Sample ID
CAS
106-42-3
95-47-6
SECTION IV -Analytical Results -05/30/2001 13:23
0501 HBWW230
2010513901
Cone Flaa
ND
ND
LIMS Workorder: 80396907 .0 I [20 I 05139) Hamilton Beach-Proctor Silex
DL RL
0.167 0.000
0.0844 0.000
050 l HBWW226 0501HBWW224
2010513902 2010513904
Cone Flaa DL RL Cone Flaa OL RL
ND 0.167 0.000 ND 0.167 0.000
ND 0.0844 0.000 ND 0.0844 0.000
STL Austin Page 7 of 46
-
~results have been gualilicd by URS-Radian based on the results of the data review process, winch is modeled alicr the N11tio1111/ F1111cti01wl G11ide/i11esfor Organic 11111/ ltwrg1111ic /)11111 Rc1•iell' --· {),-()()()._.,.,.. ,.,.,.,. -I~ '-I-- - - --· - - - -
--------------- - - - -SECTION IV
Analytical Results
Surrogates
MS-VOA
SW8260B
Surroaate Comoound
1-Bromo-4-tluorobenzene
l ,2-Dichloroethane-d4
Toluene-d8
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
SECTION IV -Analytical Results -05/30/2001 13:23
050IHBWW230
2010513901
AQueous
Received
NA
05/16/200 I 09:40
05/21/200 l 22: I 0
05/21/200 l 22: l 0
l
MSDA
ug/L
% Recovery
103
106
99
LIMS Workorder: 80396907 .0 I [20 I 05 I 39J llamilton Beach-Proctor Silex
STL Austin
Limits F
77-117
61-143
87-113
050 I HBWW226 0501HBWW224
2010513902 2010513904
AQueous AQueous
Received Received
NA NA
05/16/2001 10:20 05/ 16/200 I 11 :25
05/21/2001 22:38 05/21/2001 23:06
05/21/2001 22:38 05/21/2001 23:06
l l
MSDA MSDA
ug/L uvL
% Recovery Limits F % Recoverv Limits
104 77-117 103 77-117
108 61-143 108 61-143
100 87-113 98 87-113
Page 8
Sample results have been qualified by URS-Radian based on 1hc rcsulls of the dala review process, which is modeled aflcr 1he N111io1111/ F1111c1io11al G11ide/i11es for Organic 11111/ /Jlorg1111ic [)11111 Re1•ie11•
fl )I" f'n-. (),.f 1~, r lC)f)C). ,,,1 r.+1•!1fl' )1){)1 r0u">•' -ti,.•1••)
F
of 46
SECTION IV
Analytical Results
MS-VOA
SW8260B
Parameter
Acetone
Acetonitrile
Acrolein
Acrvlonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
n-Butvlbenzene
sec-Butvlbenzene
tert-Butvlbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-l .3-butadiene
Chlorobenzene
Chloroethane
Chlorofonn
1-Chlorohexane
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
CAS
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-5 l-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
SECTION IV -Analylical Resulls -05/30/2001 13:23
050 I HBWW225
2010513905
Aqueous
Received
NA
05/16/200 I 11 :30
05/21/200 l 23 :34
05/21 /200 l 23 :34
I
MSDA
u!!IL
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
DL RL
0.438 0.000
6.82 0.000
3.79 0.000
0.446 0.000
0.0641 0.000
0.0998 0.000
0.131 0.000
0.118 0.000
0.170 0.000
0.199 0.000
0.200 0.000
0.102 0.000
0.105 0.000
0.091 l 0.000
0.0684 0.000
0.0652 0.000
O.l 14 0.000
0.0842 0.000
0.0925 0.000
0.0896 0.000
0.0938 0.000
0501HBWW234 0501HBWW220
2010513906 2010513907
Aqueous Aqueous
Received Received
NA NA
05/16/200 I 10:55 05/16/2001 11:50
05/22/200 I 00:02 05/22/200 l 00:29
05/22/200 l 00:02 05/22/200 I 00:29
1 1
MSDA MSDA
ue:/L u!!IL
Cone Flaa DL RL Cone Flaa DL RL
ND 0.438 0.000 ND 0.438 0.000
ND 6.82 0.000 ND 6.82 0.000
ND 3.79 0.000 ND 3.79 0.000
ND 0.446 0.000 ND 0.446 0.000
ND 0.0641 0.000 ND 0.0641 0.000
ND 0.0998 0.000 ND 0.0998 0.000
ND 0.131 0.000 ND 0.131 0.000
ND 0. I 18 0.000 ND 0.118 0.000
ND 0.170 0.000 ND 0.170 0.000
ND 0.199 0.000 ND 0.199 0.000
ND 0.200 0.000 ND 0.200 0.000
ND 0.102 0.000 ND 0.102 0.000
ND 0.105 0.000 ND 0.105 0.000
ND 0.091 l 0.000 ND 0.0911 0.000
ND 0.0684 0.000 ND 0.0684 0.000
ND 0.0652 0.000 ND 0.0652 0.000
ND 0.114 0.000 ND 0.114 0.000
ND 0.0842 0.000 ND 0.0842 0.000
ND 0.0925 0.000 ND 0.0925 0.000
ND 0.0896 0.000 ND 0.0896 0.000
ND 0.0938 0.000 ND 0.0938 0.000
STL Austin Page 9 of 46
-
•
resul~ been rwified by URS-Radian based on the results of thc data review process, which is modeled a lier rhe N111io1111/ F1111c1iom1/ G11ideli11es for Org11111c 111ul l11org1111ic 011111 Re1·u·11· ~· (\ __ """ ...... -... - - - - - - - - - - -·-·--~--~ --~--~ ~----
-------------------SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
Chloromethane
3-Chloroorooene
2-Chlorotoluene
4-Chlorotoluene
Client Sample ID
Lab Sample ID
CAS
74-87-3
107-05-1
95-49-8
106-43-4
1.2-Dibromo-3-chloroprooane 96-12-8
Dibromochloromethane 124-48-1
1.2-Dibromoethane 106-93-4
Dibromomethane 74-95-3
trans-I 4-Dichloro-2-butene 110-57-6
1.4-Dichlorobenzene 106-46-7
I 2-Dichlorobenzene 95-50-1
I 3-Dichlorobenzene 541-73-l
Dichlorodilluoromelhane 75-71-8
I 1-Dichloroethane 75-34-3
I 2-Dichloroethane 107-06-2
I 1-Dichloroethene 75-35-4
cis-1,2-Dichloroethene 156-59-2
trans-I 2-Dichloroethene 156-60-5
I 2-Dichloroorooane 78-87-5
1,3-Dichloropropane 142-28-9
2.2-Dichloroorooane 594-20-7
I, 1-Dichloroprooene 563-58-6
cis-l 3-Dichloroorooene 10061-01-5
trans-1.3-Dichloropropene 10061-02-6
Ethvl methacrvlate 97-63-2
Ethvlbenzene 100-41-4
Hexachloro-1 3-butadiene 87-68-3
2-Hexanone 591-78-6
SECTION IV -Analytical Results-05/30/2001 13:23
0501HBWW225
2010513905
Cone Fiag
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
W-9-p....
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396907 .0 I [20 I 05139) I lamilton Beach-Proctor Silex
STL Austin
DL RL
0.127 0.000
0.0777 0.000
0.178 0.000
0.0974 0.000
0.548 0.000
0.140 0.000
0.137 0.000
0.148 0.000
0.780 0.000
0.150 0.000
0.0965 0.000
0.0846 0.000
a.z37 0.999
0.124 0.000
0.102 0.000
0.122 0.000
0.112 0.000
0.119 0.000
0.0869 0.000
0.135 0.000
0.160 0.000
0.0994 0.000
0.0818 0.000
0.0908 0.000
0.101 0.000
0.136 0.000
0.331 0.000
0.169 0.000
0501HBWW234 050 I HBWW220
2010513906 2010513907
Cone Flag DL RL -.-Cone Flaa DL .
ND 0.127 0.000 ND 0.127
ND 0.0777 0.000 ND 0.0777
ND 0.178 0.000 ND 0.178
ND 0.0974 0.000 ND 0.0974
ND 0.548 0.000 ND 0.548
ND 0.140 0.000 ND 0.140
ND 0.137 0.000 ND (U37
ND 0.148 0.000 ND 0.148
ND 0.780 0.000 ND 0.780
ND 0.150 0.000 ND 0.150
ND 0.0965 0.000 ND 0.0965
ND 0.0846 0.000 ND 0.0846
NH--K Q.;!311 6.660 NB R o.~3=7
ND 0.124 0.000 ND 0.124
ND 0.102 0.000 ND 0.102
ND 0.122 0.000 ND 0.122
ND 0.112 0.000 ND 0.112
ND 0.119 0.000 ND 0.119
ND 0.0869 0.000 ND 0.0869
ND 0.135 0.000 ND 0.135
ND 0.160 0.000 ND 0.160
ND 0.0994 0.000 ND 0.0994
ND 0.0818 0.000 ND 0.0818
ND 0.0908 0.000 ND 0.0908
ND 0.101 0.000 ND 0.101
ND 0.136 0.000 ND 0.136
ND 0.33 l 0.000 ND 0.331
ND 0.169 0.000 ND 0.169
Page 10
Sample results have bcc:n qualified by URS-Radian based on the rcsulls of the data rc:vicw process, which is.modeled alic:r 1/ie Nt11iom1/ J-imclio11al G11ideli1ws for Orgm1ic mu/ bwrg1111ic D11111 Re1•iell'
f11C." f:ll 'i (),.f, }· .. ~r 1000 • •ld r. •I" P'H"' I <H)1 r1•"t' ••tit• .f.,,
RL
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
9.900.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
of 46
SECTION IV
Analytical Results
MS-VOA
SW8260B
Client Sample ID
Lab Sample ID
Continued
Parameter CAS·
lodomethane 74-88-4
Isooroovlbenzene 98-82-8
4-Isopropylto luene 99-87-6
Methvl methacrvlate 80-62-6
Methyl tert-butvl ether <MTBE) 1634-04-4
4-Methvl-2-oentanone (MIBK) 108-10-1
Methvlene chloride 75-09-2
Naohthalene 91-20-3
Propanenitrile 107-12-0
n-Propylbenzene 103-65-1
Stvrene 100-42-5
I 1.1 2-Tetrachloroethane 630-20-6
1.1.2 2-Tetrachloroethane 79-34-5
Tetrachloroethene 127-18-4
Tetrahvdrofuran 109-99-9
Toluene 108-88-3
I 2 3-Trichlorobenzene 87-61-6
I 2.4-Trichlorobenzene 120-82-1
I. I. I-Trichloroethane 71-55-6
I 1.2-Trichloroethane 79-00-5
Trichloroethene 79-01-6
Trichlorofluoromethane 75-69-4
I 2 3-Trichloroorooane 96-18-4
l 1.2-Trichlorotrifluoroethane 76-13-1
I 2.4-Trimethvlbenzene 95-63-6
I 3.5-Trimethvlbenzene 108-67-8
Vinvl acetate 108-05-4
Vinvl chloride 75-01-4
SECTION IV -Analytical Results -05/30/2001 13:23
0501HBWW225
2010513905
Cone Flaa
ND \A-:!
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Nt7 R.
ND
LIMS Workorder: 80396907.01 (20105139] Hamilton Beach-Proctor Silex
DL RL
0.109 0.000
0.0931 0.000
0.115 0.000
0.13 l 0.000
0.116 0.000
0.178 0.000
0.126 0.000
0.0801 0.000
l.59 0.000
0.140 0.000
0.0977 0.000
0.111 0.000
0.0870 0.000
0.144 0.000
0.900 0.000
0.0637 0.000
0.551 0.000
0.135 0.000
0.169 0.000
0.0821 0.000
0.137 0.000
0.106 0.000
0.288 0.000
0.123 0.000
0.124 0.000
0.0905 0.000
0.8948 8.080
0.114 0.000
0501HBWW234 0501HBWW220
2010513906 2010513907
Cone Flaa DL RL Cone Flaa DL RL
ND I 1::S 0.109 0.000 ND Lt:f 0.109 0.000
ND 0.0931 0.000 ND 0.0931 0.000
ND 0.115 0.000 ND 0.115 0.000
ND 0.131 0.000 ND 0.131 0.000
ND 0.116 0.000 ND 0.116 0.000
ND 0.178 0.000 ND 0.178 0.000
ND 0.126 0.000 ND 0.126 0.000
ND 0.0801 0.000 ND 0.0801 0.000
ND l.59 0.000 ND l.59 0.000
ND 0.140 0.000 ND 0.140 0.000
ND 0.0977 0.000 ND 0.0977 0.000
ND 0.111 0.000 ND 0.111 0.000
ND 0.0870 0.000 ND 0.0870 0.000
ND 0.144 0.000 ND 0.144 0.000
ND 0.900 0.000 ND 0.900 0.000
ND 0.0637 0.000 ND 0.0637 0.000
ND 0.551 0.000 ND 0.551 0.000
ND 0.135 0.000 ND 0.135 0.000
ND 0.169 0.000 ND 0.169 0.000
ND 0.0821 0.000 ND 0.0821 0.000
ND 0.137 0.000 ND 0.137 0.000
ND 0.106 0.000 ND 0.106 0.000
ND 0.288 0.000 ND 0.288 0.000
ND 0.123 0.000 ND 0.123 0.000
ND 0.124 0.000 ND 0.124 0.000
ND 0.0905 0.000 ND 0.0905 0.000
-W-1) ~ 0:9948 e.0ee -Ni7-R_ 0..0948 8.8Q~
ND 0.114 0.000 ND 0.114 0.000
STL Austin Page 11 of 46
Sample results have been qualified by URS-Radian based on the results of the data review process, which is modeled alier th<' N111io1wl Fw1ctio11a/ Ci11ideli11esfor Organic 11111/ bwrg11111c D11111 ll.e1•icll' - _ .. "-'"'"'-... _ .. - - - - - - - - - - - - - -
-------·-
SECTION IV
Analytical Results
MS-VOA
SW82608
Continued
Parameter
o-Xvlene/m-Xvlene
o-Xvlene
Client Sample ID
Lab Sample ID
CAS
106-42-3
95-47-6
SECTION IV -Analytical Results -05/30/2001 13:23
0501HBWW225
2010513905
Cone Flaa
ND
ND
LIMS Workordcr: 80396907.01 [20105139) Hamilton Beach-Proctor Silex
STLAustin
DL
0.167
0.0844
- --------
0501HBWW234 050lHBWW220
2010513906 2010513907
RL Cone Flaa DL RL Cone Fla" DL
0.000 ND 0.167 0.000 ND 0.167
0.000 ND 0.0844 0.000 ND 0.0844
Page 12
Sample results have bct:n qualified by URS-Radian based on the resulls of the data review process, which is modeled a lier th<' N111i<11111/ i'imc1io1111/ G11it/eli11es for Organic 1111d lnorg1111ic I>11111 R<•1•u·w
r1wr-n4 r, .• 1., 1onn .• ,1r.1 .... "' 11)01 , .... ";,·I·'
--
RL
0.000
0.000
of 46
-------------------SECTION IV
Analytical Results
MS-VOA
SW8260B
Parameter
Acetone
Acetonitrile
Acrolein
Acrvlonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
n-Butvlbenzene
sec-Butvlbenzene
tert-Butvlbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-l 3-butadiene
Chlorobenzene
Chloroethane
Chlorofonn
1-Chlorohexane
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
CAS
67-64-1
75-05-8
I07-02-8
107-13-1
7I-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
I08-90-7
75-00-3
67-66-3
544-10-5
SECTION IV -Analytical Results -05/30/200 I 13:23
0501HBWW222
2010513908
Aaueous
Received
NA
05/16/200 I I 2: I 0
05/22/200 I 00:58
05/22/200 I 00:58
1
MSDA
ug/L
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workordcr: 80396907 .0 I [20 I 05139) Hamilton Beach-Proctor Silex
STLAustin
DL RL
0.438 0.000
6.82 0.000
3.79 0.000
0.446 0.000
0.0641 0.000
0.0998 0.000
0.131 0.000
0.118 0.000
0.170 0.000
0.199 0.000
0.200 0.000
0.102 0.000
0.105 0.000
0.0911 0.000
0.0684 0.000
0.0652 0.000
O.l I4 0.000
0.0842 0.000
0.0925 0.000
0.0896 0.000
0.0938 0.000
TRIP BLANK 0501HBWD999
2010513909 20105I3903
Aaueous Aaueous
Received Received
NA NA
05/16/200 I 00:00 05/16/200 I I 0:30
05/22/200 I 0 I :26 05/22/200 I 11 :36
05/22/2001 01 :26 05/22/2001 I I :36
1 I
MSDA MSDA
ug/L ug/L
Cone Flaa DL RL Cone Flaa DL
ND 0.438 0.000 ND 0.438
ND 6.82 0.000 ND 6.82
ND 3.79 0.000 ND 3.79
ND 0.446 0.000 ND 0.446
ND 0.064 I 0.000 ND 0.0641
ND 0.0998 0.000 ND 0.0998
ND 0.131 0.000 ND 0.131
ND 0.118 0.000 ND OJl8
ND 0.170 0.000 ND 0.170
ND 0.199 0.000 ND 0.199
ND 0.200 0.000 ND 0.200
ND 0.102 0.000 ND 0.102
ND 0.105 0.000 ND 0.105
ND 0.0911 0.000 ND 0.0911
ND 0.0684 0.000 ND 0.0684
ND 0.0652 0.000 ND 0.0652
ND 0.114 0.000 ND 0.114
ND 0.0842 0.000 ND 0.0842
ND 0.0925 0.000 ND 0.0925
ND 0.0896 0.000 ND 0.0896
ND 0.0938 0.000 ND 0.0938
Page 14
Sample results have been qualified by URS-Radian based on the results of the data review process, which is modeled after the N111io1111/ F1111c1iu11al G11itleli11es for Orgtmic wul /11orgt111ic Daw Re1•icl1'
f1 ,, .. f'Jl" ('\,., 1~ .. ,-1onn. 11 I r.,,., .. q-p 10<)'1 r ....... •ti1••f1·'
RL
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
of 46
SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
Chloromethane
3-Chloroorooene
2-Chlorotoluene
4-Chlorotoluene
Client Sample ID
Lab Sample ID
CAS
74-87-3
107-05-1
95-49-8
106-43-4
1.2-Dibromo-3-chloroorooane 96-12-8
Dibromochloromethane 124-48-1
I 2-Dibromoethane 106-93-4
Dibromomethane 74-95-3
trans-I 4-Dichloro-2-butene 110-57-6
l ,4-Dichlorobenzene 106-46-7
I 2-Dichlorobenzene 95-50-1
1.3-Dichlorobenzene 541-73-l
Dichlorodifluoromethane 75-71-8
1.1-Dichloroethane 75-34-3
1.2-Dichloroethane 107-06-2
I, 1-Dichloroethene 75-35-4
cis-1.2-Dichloroethene 156-59-2
trans-I 2-Dichloroethene 156-60-5
I 2-Dichloroorooane 78-87-5
1,3-Dichloropropane 142-28-9
2 2-Dichloroorooane 594-20-7
1.1-Dichloropropene 563-58-6
cis-1.3-Dichloroorooene 10061-01-5
trans-I 3-Dichloroorooene 10061-02-6
Ethvl methacrvlate 97-63-2
Ethyl benzene 100-41-4
Hexachloro-1 3-butadiene 87-68-3
2-Hexanone 591-78-6
SECTION IV -Analytical Results -05/30/2001 13:23
0501HBWW222
2010513908
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Ne-tz
0.536
ND
0.0793 sllf
0.260 J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
DL RL
0.127 0.000
0.0777 0.000
0.178 0.000
0.0974 0.000
0.548 0.000
0.140 0.000
0.137 0.000
0.148 0.000
0.780 0.000
0.150 0.000
0.0965 0.000
0.0846 0.000
9.;!a;t 9.990
0.124 0.000
0.102 0.000
0.122 0.000
0.112 0.000
0.119 0.000
0.0869 0.000
0.135 0.000
0.160 0.000
0.0994 0.000
0.0818 0.000
0.0908 0.000
0.101 0.000
0.136 0.000
0.331 0.000
0.169 0.000
TRIP BLANK 0501HBWD999
2010513909 2010513903
Cone Flaa DL RL Cone Flaa DL RL
ND 0.127 0.000 ND 0.127 0.000
ND 0.0777 0.000 ND 0.0777 0.000
ND 0.178 0.000 ND 0.178 0.000
ND 0.0974 0.000 ND 0.0974 0.000
ND 0.548 0.000 ND 0.548 0.000
ND 0.140 0.000 ND 0.140 0.000
ND 0.137 0.000 ND 0.137 0.000
ND 0.148 0.000 ND 0.148 0.000
ND 0.780 0.000 ND l,L:S 0.780 0.000
ND 0.150 0.000 ND 0.150 0.000
ND 0.0965 0.000 ND 0.0965 0.000
ND 0.0846 0.000 ND 0.0846 0.000
rm:> K Q.~~:;z 0.660 -Nt> CZ. G.~~=7 0.9QO
ND 0.124 0.000 ND 0.124 0.000
ND 0.102 0.000 ND 0.102 0.000
ND 0.122 0.000 ND 0.122 0.000
ND 0.112 0.000 ND 0.112 0.000
ND 0.119 0.000 ND 0.119 0.000
ND 0.0869 0.000 ND 0.0869 0.000
ND 0.135 0.000 ND 0.135 0.000
ND 0.160 0.000 ND I A:-\ 0.160 0.000
ND 0.0994 0.000 ND 0.0994 0.000
ND 0.0818 0.000 ND 0.0818 0.000
ND 0.0908 0.000 ND 0.0908 0.000
ND 0.101 0.000 ND 0.101 0.000
ND 0.136 0.000 ND 0.136 0.000
ND 0.331 0.000 ND 0.331 0.000
ND 0.169 0.000 ND 0.169 0.000
STL Austin Page 15 of 46
Samrle resulls have been qualified by URS-Radian based on the results or the dala review process, which is modeled after the N111i01111/ Fi111c1io11t1/ G11itieli11es for Org1111ic 111111/11org1111ic1>11111 Re1•1<·11·
-_·()-000_ .. .,.,_ ..... _ - - - - - - - - - - - - -
-------------------SECTION IV
Analytical Results
MS-VOA
SW8260B
Client Sample ID
Lab Sample ID
Continued
Parameter CAS
lodomethane 74-88-4
Isopropylbenzene 98-82-8
4-lsooroovltoluene 99-87-6
Methyl methacrvlate 80-62-6
Methvl tert-butyl ether (MTBE) 1634-04-4
4-Methyl-2-oentanone (MIBK) 108-10-1
Methvlene chloride 75-09-2
Naphthalene 91-20-3
Propanenitrile 107-12-0
n-Proovlbenzene 103-65-1
Styrene 100-42-5
I.I l 2-Tetrachloroethane 630-20-6
l I 2 2-Tetrachloroethane 79-34-5
Tetrachloroethene 127-18-4
Tetrahydrofuran 109-99-9
Toluene 108-88-3
I 2.3-Trichlorobenzene 87-61-6
I 2 4-Trichlorobenzene 120-82-1
I I. I-Trichloroethane 71-55-6
I 1,2-Trichloroethane 79-00-5
Trichloroethene 79-01-6
Trichlorofluoromethane 75-69-4
1.2 3-Trichloropropane 96-18-4
1.1 2-Trichlorotrifluoroethane 76-13-1
1.2 4-Trimethylbenzene 95-63-6
I .3 5-Trimethvlbenzene 108-67-8
Vinyl acetate 108-05-4
Vinyl chloride 75-01-4
SECTION IV -Analytical Results -05/30/2001 13:23
0501HBWW222
2010513908
Cone Flaa
ND lA::\
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NQ-.. K
ND
LIMS Workorder: 80396907.01 [20105139) llamilton Beach-Proctor Silex
STLAustin
DL RL
0.109 0.000
0.093 I 0.000
0.115 0.000
0.131 0.000
0.116 0.000
0.178 0.000
0.126 0.000
0.080 I 0.000
1.59 0.000
0.140 0.000
0.0977 0.000
0.111 0.000
0.0870 0.000
0.144 0.000
0.900 0.000
0.0637 0.000
0.551 0.000
0.135 0.000
0.169 0.000
0.0821 0.000
0.137 0.000
0.!06 0.000
0.288 0.000
0.123 0.000
0.124 0.000
0.0905 0.000
0.1~948 8.880-
0.114 0.000
TRIP BLANK 0501HBWD999
2010513909 2010513903
Coric ·Flaa DL RL . , Coric· 'Flaa·· DL
ND lA.::r 0.109 0.000 ND 0.109
ND 0.0931 0.000 ND 0.0931
ND 0.115 0.000 ND 0.115
ND 0.131 0.000 ND 0.131
ND 0.116 0.000 ND 0.116
ND 0.178 0.000 ND 0.178
0.295 J 0.126 0.000 ND 0.126
ND 0.0801 0.000 ND 0.0801
ND 1.59 0.000 ND 1.59
ND 0.140 0.000 ND 0.140
ND 0.0977 0.000 ND 0.0977
ND 0.111 0.000 ND 0.111
ND 0.0870 0.000 ND 0.0870
ND 0.144 0.000 ND 0.144
ND 0.900 0.000 ND 0 .. 900
ND 0.0637 0.000 ND 0.0637
ND 0.551 0.000 ND 0.551
ND 0.135 0.000 ND 0.135
ND 0.169 0.000 ND 0.169
ND 0.0821 0.000 ND 0.0821
ND 0.137 0.000 ND 0.137
ND 0.106 0.000 ND 0.106
ND 0.288 0.000 ND 0.288
ND 0.123 0.000 ND 0.123
ND 0.124 0.000 ND 0.124
ND 0.0905 0.000 ND 0.0905
N9-~ O.G94g G.GW NB-\JtZS" R 0.G94g
ND 0.114 0.000 ND 0.114
Page 16
Sample results have been qualified by URS-Radian based on the results of 1hc dala review process, which is modeled af1t:r the N111imwl J-i111ctio11a/ Guidelines for Orgm1ic tmd lnorgm1ic D11111 llc1•1e11•
q 1<.~ r.o" n .. 1. h·''" 1 nnn. ,, I r. .. h •. , .. ,.., 1 c)(}'1 r•'"""" .,; ... , .. ,
RL
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
of 46
SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
p-Xvlene/m-Xvlene
o-Xvlene
Client Sample ID
Lab Sample ID
CAS
106-42-3
95-47-6
SECTION IV -Analytical Results -05/30/2001 13:23
0501HBWW222
2010513908
Cone Flag
ND
ND
LIMS Workorder: 80396907.01 (20105139] llamilton Beach-Proctor Silex
STL Austin
DL RL
0.167 0.000
0.0844 0.000
TRJPBLANK 0501HBWD999
2010513909 2010513903
Cone Flaa DL . RL Cone Flaa DL RL
ND 0.167 0.000 ND 0.167 0.000
ND 0.0844 0.000 ND 0.0844 0.000
Page 17 of
-Sample results have been qualified by URS-Radian based on the results of the data review process, which is modeled after 1/ie N111im111/ F1111c1io11n/ G11itle/i11csfor Org1111ic' mu/ bwrgm11c Daw Re1•ie11• -" n-111rin_ ..... ,_ ........ _ - - - - - - - - - - - -
46
-
----------------SECTION IV
Analytical Results
Surrogates
MS-VOA
SW8260B
Surrogate Compound
l-Bromo-4-fluorobenzene
l 2-Dichloroethane-d4
Toluene-dB ·
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
SECTION IV -Analytical Results -05/30/200i 13:23
050 I HBWW222
2010513908
Aqueous
Received
NA
05/16/2001 12:10
05/22/2001 00:58
05/22/200 l 00:58
l
MSDA
ug/L
% Recoverv
103
11 l
97
LIMS Workorder: 80396907.01 (20105139] Hamilton Beach-Proctor Silex
STLAuslin
Limits F
77-117
61-143
87-113
TRIP BLANK 050 l HBWD999
2010513909 2010513903
Aqueous Aqueous
Received Received
NA NA
05/16/200 I 00:00 05/16/2001 10:30
05/22/200 I 0 l :26 05/22/2001 11:36
05/22/200 l 0 I :26 05/22/200 I l l :36
l l
MSDA MSDA
ug/L ug/L
% Recoverv Limits F % Recoverv
IOI 77-117 105
105 61-143 107
99 87-113 103
- - -
Limits F
77-117
61-143
87-113
Page 18 of 46
Sample results have been qualified by URS-Radian based on the rcsuhs of the data review process, which is modeled after the N111io1111/ l-i111ctio11a/ G11ideli11es for Organic mui ltwrgmuc 011111 Re1•i£·11·
fl 1<" rn" n,.,, 1~ ... l ono .. .,,, r ''" , ... , l 001 ,.,,,., ... ~,,,. ·1··'
I
I
I
I·
I
I
I
I
I
I
I
I
I
I
I
I
1·
I
I
LABORATORY REPORTS
SECTION I
Table of Contents
Section
I.
MS-VOA
II.
III.
IV.
v.
VI.
VII.
Form
Cover Page -Laboratory Analytical Report
Table of Contents .
Report Surrmaries . . . . .
Workorder Surrmary
Protocol Surrmary
Ccmnents and Flag Definitions .
Standard Flag Definitions
Analyst Ccmnents . . . .
Sample Condition Ccmnents
Analytical Results . . . . . . . . .
SW8260B . . . . . . . . .
Calibration and Quality Control Results
SW8260B .......... .
Batch Surrmaries . .
SW8260B .
Certifications • . .
Calibration Verification Results
Mass Spectrcmeter Tune
Method Blank Results
Control Sample Results
Extraction/Digestion Batch Surrmary
Analysis Batch Surrmary
Section I -Table of Contents -05/30/2001 13:23
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
Page
. i
1
1
. 1
1
3
3
3
. . 3
4
4
. 19
19
19
31
34
38
42
. 42
. 42
44
46
-------------------
SECTION II
Report Summaries
MS-VOA
Protocol Summary continued -
•.
Lab : Date&·Time Date&Time Prep
Client Samole ID Samole.ID Collected Received , ·Batch ID
Method: SW8260B continued -
0501HBWW222 2010513908 05/16/01 12:10 05/17/01 10:30 12204
TRIP BLANK 2010513909 05/16/01 00:00 05/17/01 10:30 12204
SECTION II -Report Summaries -05/30/2001 13:23
LIMS Workorder: 80396907.01 [20105139) Hamilton Beach-Proctor Silex
STLAustin
0 · · Hold Time S1Jec
Date& Time Analysis Date& Time· ·Preo. , . Analvsis
Pre oared Batch ID Analvzed · · "Soe.c·:. Actua . Soec Actua
05/22/0 I 00:58 12204 05/22/0 I 00:58 7D 6D 70 60
05/22/01 01:26 12204 05/22/01 01:26 7D 6D 70 60
Page 2 of 46
-------------------
SECTION IV
Analytical Results
MS-VOA
SW8260B
Parame.ter
Acetone
Acetonitrile
Acrolein
Acrvlonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
n-Butvlbenzene
sec-Butvlbenzene
tert-Butvlbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-l .3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
" CAS • .. . '
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
SECTION IV -Analytical Results -05/30/2001 13:23
050 IHBWW230
2010513901
Aaueous
Received
NA
05/16/2001 09:40
05/21/2001 22:10
05/21/2001 22: IO
l
MSDA
u2/L
Cone· :Flaa·
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
DL, RL ..
0.438 0.000
6.82 0.000
3.79 0.000
0.446 0.000
0.0641 0.000
0.0998 0.000
0.131 0.000
0.118 0.000
0.170 0.000
0.199 0.000
0.200 0.000
0.102 0.000
0.105 0.000
0.0911 0.000
0.0684 0.000
0.0652 0.000
0.114 0.000
0.0842 0.000
0.0925 0.000
0.0896 0.000
0.0938 0.000
0501HBWW226 0501HBWW224
2010513902 2010513904
Aaueous Aaueous
Received Received
NA NA
05/16/2001 10:20 05/16/2001 11 :25
05/21/2001 22:38 05/21/2001 23:06
05/21/2001 22:38 05/21/2001 23:06
1 1
MSDA MSDA
ug/L ug/L
Cone·· Flaa. DL : RL .. ·Cone-.·~~ .. Flaa · DL RL . .
ND 0.438 0.000 ND 0.438 0.000
ND 6.82 0.000 ND 6.82 0.000
ND 3.79 0.000 ND 3.79 0.000
ND 0.446 0.000 ND 0.446 0.000
ND 0.0641 0.000 ND 0.0641 0.000
ND 0.0998 0.000 ND 0.0998 0.000
ND 0.131 0.000 ND 0.131 0.000
ND 0.118 0.000 ND 0.118 0.000
ND 0.170 0.000 ND 0.170 0.000
ND 0.199 0.000 ND 0.199 0.000
ND 0.200 0.000 ND 0.200 0.000
ND 0.102 0.000 ND 0.102 0.000
ND 0.105 0.000 ND 0.105 0.000
ND 0.0911 0.000 ND 0.0911 0.000
ND 0.0684 0.000 0.715 J 0.0684 0.000
ND 0.0652 0.000 ND 0.0652 0.000
ND 0.114 0.000 ND 0.114 0.000
ND 0.0842 0.000 ND 0.0842 0.000
ND 0.0925 0.000 ND 0.0925 0.000
ND 0.0896 0.000 ND 0.0896 0.000
ND 0.0938 0.000 ND 0.0938 0.000
Page 4 of 46
---·----------------
-------------------
SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter·
Chloromethane
3-Chloroorooene
2-Chlorotoluene
4-Chlorotoluene
..
Client Sample ID
Lab Sample ID
-··. CAS
74-87-3
107-05-l
95-49-8
106-43-4
l 2-Dibromo-3-chloroorooane 96-12-8
Dibromochloromethane 124-48-1
1.2-Dibromoethane 106-93-4
Dibromomethane 74-95-3
trans-1.4-Dichloro-2-butene 110-57-6
1 4-Dichlorobenzene 106-46-7
l 2-Dichlorobenzene 95-50-1
l 3-Dichlorobenzene 541-73-1
Dichlorodifluoromethane 75-71-8
1 1-Dichloroethane 75-34-3
l 2-Dichloroethane 107-06-2
l. l-Dichloroethene 75-35-4
cis-1.2-Dichloroethene 156-59-2
trans-I 2-Dichloroethene 156-60-5
1.2-Dichloroorooane 78-87-5
1,3-Dichloropropane 142-28-9
2.2-Dichloroorooane 594-20-7
1.1-Dichloropropene 563-58-6
cis-1 3-Dichlorooropene 10061-01-5
trans-1.3-Dichloroorooene 10061-02-6
Ethvl methacrvlate 97-63-2
Ethvlbenzene 100-41-4
Hexachloro-1.3-butadiene 87-68-3
2-Hexanone 591-78-6
SECTION IV -Analytical Results -05/30/2001 13:23
050lHBWW230
2010513901
Cone .Fla~
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.288 J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
DL RL
0.127 0.000
0.0777 0.000
0.178 0.000
0.0974 0.000
0.548 0.000
0.140 0.000
0.137 0.000
0.148 0.000
0.780 0.000
0.150 0.000
0.0965 0.000
0.0846 0.000
0.237 0.000
0.124 0.000
0.102 0.000
0.122 0.000
0.112 0.000
0.119 0.000
0.0869 0.000
0.135 0.000
0.160 0.000
0.0994 0.000
0.0818 0.000
0.0908 0.000
0.101 0.000
0.136 0.000
0.331 0.000
0.169 0.000
050 IHBWW226 050IHBWW224
2010513902 2010513904
Cone. Fla11 DL RL. '.·.c.onc:. " Ffad·.·· .DL' . RL
ND 0.127 0.000 ND 0.127 0.000
ND 0.0777 0.000 ND 0.0777 0.000
ND 0.178 0.000 ND 0.178 0.000
ND 0.0974 0.000 ND 0.0974 0.000
ND 0.548 0.000 ND 0.548 0.000
ND 0.140 0.000 ND 0 .. .140 0.000
ND 0.137 0.000 ND 0 . ..137 0.000
ND 0.148 0.000 ND 0.148 0.000
ND 0.780 0.000 ND 0.780 0.000
ND 0.150 0.000 ND 0.150 0.000
ND 0.0965 0.000 ND 0.0965 0.000
ND 0.0846 0.000 ND 0.0846 0.000
ND 0.237 0.000 ND 0.237 0.000
ND 0.124 0.000 ND 0,.124 0.000
ND 0.102 0.000 ND 0_102 0.000
ND 0.122 0.000 ND 0.122 0.000
ND O.l 12 0.000 ND 0.112 0.000
ND O. l 19 0.000 ND O.l 19 0.000
ND 0.0869 0.000 ND 0.0869 0.000
ND 0.135 0.000 ND 0.135 0.000
ND 0.160 0.000 ND 0.160 0.000
ND 0.0994 0.000 ND 0.0994 0.000
ND 0.0818 0.000 ND 0.0818 0.000
ND 0.0908 0.000 ND 0.0908 0.000
ND O.lOl 0.000 ND 0.101 0.000
ND 0.136 0.000 ND 0.136 0.000
ND 0.331 0.000 ND 0.331 0.000
ND 0.169 0.000 ND 0.169 0.000
Page 5 of 46
SECTION IV
Analytical Results
MS-VOA
SW8260B
Client Sample ID
Lab Sample ID
Continued
Parameter CAS
Iodomethane 74-88-4
lsooroovlbenzene 98-82-8
4-lsooroovltoluene 99-87-6
Methvl methacrvlate 80-62-6
Methvl tert-butvl ether (MTBE) 1634-04-4
4-Methvl-2-oentanone (MIBK) 108-10-1
Methvlene chloride 75-09-2
Naohthalene 91-20-3
Prooanenitrile 107-12-0
n-Proov I benzene 103-65-1
Stvrene 100-42-5
1.1 1.2-Tetrachloroethane 630-20-6
1.1 2.2-Tetrachloroethane 79-34-5
Tetrachloroethene 127-18-4
Tetrahvdrofuran 109-99-9
Toluene 108-88-3
l 2.3-Trichlorobenzene 87-61-6
l 2.4-Trichlorobenzene 120-82-1
1.1 1-Trichloroethane 71-55-6
1.1 2-Trichloroethane 79-00-5
Trichloroethene 79-01-6
Trichlorofluoromethane 75-69-4
1.2 3-Trichloroorooane 96-18-4
1 1 2-Trichlorotrifluoroethane 76-13-1
I 2 4-Trimethvlbenzene 95-63-6
1.3 5-Trimethvlbenzene 108-67-8
Vinvl acetate 108-05-4
Vinvl chloride 75-01-4
SECTION IV -Analytical Results -05/30/2001 13:23
0501 HBWW230
2010513901
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.292 J
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396907.01 [20105139) Hamilton Beach-Proctor Silex
STLAustin
DL RL
0.109 0.000
0.0931 0.000
0.115 0.000
0.131 0.000
0.116 0.000
0.178 0.000
0.126 0.000
0.0801 0.000
l.59 0.000
0.140 0.000
0.0977 0.000
0.111 0.000
0.0870 0.000
0.144 0.000
0.900 0.000
0.0637 0.000
0.551 0.000
0.135 0.000
0.169 0.000
0.0821 0.000
0.137 0.000
0.106 0.000
0.288 0.000
0.123 0.000
0.124 0.000
0.0905 0.000
0.0948 0.000
0.114 0.000
0501HBWW226 0501 HBWW224
2010513902 2010513904
Cone Flaa DL RL Cone Flaa DL RL
ND 0.109 0.000 ND 0.109 0.000
ND 0.0931 0.000 ND 0.0931 0.000
ND 0.115 0.000 ND 0.115 0.000
ND 0.131 0.000 ND 0.131 0.000
ND 0.116 0.000 ND 0.116 0.000
ND 0.178 0.000 ND 0.178 0.000
ND 0.126 0.000 ND 0.126 0.000
ND 0.0801 . 0.000 ND 0.0801 0.000
ND l.59 0.000 ND 1.59 0.000
ND 0.140 0.000 ND 0.140 0.000
ND 0.0977 0.000 ND 0.0977 0.000
ND 0.111 0.000 ND 0.111 0.000
ND 0.0870 0.000 ND 0.0870 0.000
ND 0.144 0.000 ND 0.144 0.000
ND 0.900 0.000 ND 0.900 0.000
ND 0.0637 0.000 ND 0.0637 0.000
ND 0.551 0.000 ND 0.551 0.000
ND 0.135 0.000 ND 0.135 0.000
ND 0.169 0.000 ND 0.169 0.000
ND 0.0821 0.000 ND 0.0821 0.000
ND 0.137 0.000 ND 0.137 0.000
ND 0.106 0.000 ND 0.106 0.000
ND 0.288 0.000 ND 0.288 0.000
ND 0.123 0.000 ND 0.123 0.000
ND 0.124 0.000 ND 0.124 0.000
ND 0.0905 0.000 ND 0.0905 0.000
ND 0.0948 0.000 ND 0.0948 0.000
ND 0.114 0.000 ND 0.114 0.000
Page 6 of 46
-------------------
-------------------SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
. J~arameter. ·-
n-Xvlene/m-Xvlene
o-Xvlene
" ..
Client Sample ID
Lab Sample ID
CAS ..
106-42-3
95-47-6
SECTION IV -Analytical Results -05/30/2001 13:23
0501HBWW230
2010513901
.Cone Flaa
ND
ND
LIMS Workorder: 80396907 .. 01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
DL RL
0.167 0.000
0.0844 0.000
0501HBWW226 0501HBWW224
2010513902 2010513904
Cone Flaa DL RL ·cone Flaa ... ·OL RL
ND 0.167 0.000 ND 0.167 0.000
ND 0.0844 0.000 ND 0.0844 0.000
Page 7 of 46
SECTION IV
Analytical Results
Surrogates
MS-VOA
SW8260B
Surroaate Compound
1-Bromo-4-fluorobenzene
1 2-Dichloroethane-d4
Toluene-d8
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
SECTION IV -Analytical Results -05/30/2001 13:23
0501HBWW230
2010513901
Aqueous
Received
NA
05/16/2001 09:40
05/21/2001 22: 10
05/21/2001 22: 10
1
MSDA
ug/L
% Recoverv
103
106
99
LJMS Workorder: 80396907 .0 I [20 I 05139} Hamilton Beach-Proctor Silex
STLAustin
Limits F
77-117
61-143
87-113
050 I HBWW226 0501HBWW224
2010513902 2010513904
Aqueous Aqueous
Received Received
NA NA
05/16/2001 10:20 05/16/2001 11 :25
05/21/2001 22:38 05/21/2001 23:06
05/21/2001 22:38 05/21/2001 23 :06
1 1
MSDA MSDA
ug/L ug/L
.. % Recoverv Limits .. F. %·Recoverv Limits F
104 77-117 103 77-117
108 61-143 108 61-143
100 87-113 98 87-113
Page 8 of 46
-------------------
-~-------~-~----~--
SECTION IV
Analytical Results
MS-VOA
SW8260B
·. , ·Parameter
Acetone
Acetonitrile
Acrolein
Acrvlonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
n-Butvlbenzene
sec-Butvlbenzene
tert-Butvlbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-l 3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
CAS
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
SECTION IV -Analytical Results -05/30/200 I 13:23
0501HBWW225
2010513905
Aaueous
Received
NA
05/16/2001 11:30
05/21/2001 23:34
05/21/2001 23:34
1
MSDA
ug/L
Cone .. Flaa· DL
ND 0.438
ND 6.82
ND 3.79
ND 0.446
ND 0.0641
ND 0.0998
ND. 0.131
ND 0.118
ND 0.170
ND 0.199
ND 0.200
ND 0.102
ND 0.105
ND 0.0911
ND 0.0684
ND 0.0652
ND 0.114
ND 0.0842
ND 0.0925
ND 0.0896
ND 0.0938
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
RL
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0501HBWW234 050lHBWW220
2010513906 2010513907
Aaueous Aaueous
Received Received
NA NA
05/16/2001 10:55 05/16/2001 11:50
05/22/2001 00:02 05/22/2001 00:29
05/22/2001 00:02 05/22/2001 00:29
l 1
MSDA MSDA
ue:/L ug/L
Cone· Flaa DL RL .:!.. ,. :ComV·>; Flaci·.:·'>.[)L. .RL
ND 0.438 0.000 ND 0.438 0.000
ND 6.82 0.000 ND 6.82 0.000
ND 3.79 0.000 ND 3.79 0.000
ND 0.446 0.000 ND 0.446 0.000
ND 0.0641 0.000 ND 0.0641 0.000
ND 0.0998 0.000 ND 0.0998 0.000
ND 0.131 0.000 ND 0.131 0.000
ND 0.118 0.000 ND O:-tl8 0.000
ND 0.170 0.000 ND O:t70 0.000
ND 0.199 0.000 ND 0.199 0.000
ND 0.200 0.000 ND 0.200 0.000
ND 0.102 0.000 ND 0.102 0.000
ND 0.105 0.000 ND 0.105 0.000
ND 0.0911 0.000 ND 0.0911 0.000
ND 0.0684 0.000 ND 0.0684 0.000
ND 0.0652 0.000 ND 0.0652 0.000
ND 0.114 0.000 ND 0.114 0.000
ND 0.0842 0.000 ND 0.0842 0.000
ND 0.0925 0.000 ND 0.0925 0.000
ND 0.0896 0.000 ND 0.0896 0.000
ND 0.0938 0.000 ND 0.0938 0.000
Page 9 of 46
SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
Chloromethane
3-Chloroorooene
2-Chlorotoluene
4-Chlorotoluene
Client Sample ID
Lab Sample ID
CAS ..
74-87-3
107-05-1
95-49-8
106-43-4
1.2-Dibromo-3-chloropropane 96-12-8
Dibromochloromethane 124-48-1
1.2-Dibromoethane 106-93-4
Dibromomethane 74-95-3
trans-I 4-Dichloro-2-butene 110-57-6
1,4-Dichlorobenzene 106-46-7
1.2-Dichlorobenzene 95-50-1
1.3-Dichlorobenzene 541-73-1
Dichlorodifluoromethane 75-71-8
1.1-Dichloroethane 75-34-3
1.2-Dichloroethane 107-06-2
1.1-Dichloroethene 75-35-4
cis-1.2-Dichloroethene 156-59-2
trans-1.2-Dichloroethene 156-60-5
1.2-Dichloropropane 78-87-5
1,3-Dichloroorooane 142-28-9
2 2-Dichloroorooane 594-20-7
1 1-Dichloroorooene 563-58-6
cis-1 3-Dichloropropene 10061-01-5
trans-1.3-Dichloroorooene 10061-02-6
Ethvl methacrvlate 97-63-2
Ethylbenzene 100-41-4
Hexachloro-1.3-butadiene 87-68-3
2-Hexanone 591-78-6
SECTION IV -Analytical Results -05/30/2001 13:23
050 I HBWW225
2010513905
Cone Flag
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396907.01 [201OS139] Hamilton Beach-Proctor Silex
STLAustin
DL RL
0.127 0.000
0.0777 0.000
0.178 0.000
0.0974 0.000
0.548 0.000
0.140 0.000
0.137 0.000
0.148 0.000
0:780 0.000
0.150 0.000
0.0965 0.000
0.0846 0.000
0.237 0.000
0.124 0.000
0.102 0.000
0.122 0.000
0.112 0.000
0.119 0.000
0.0869 0.000
0.135 0.000
0.160 0.000
0.0994 0.000
0.0818 0.000
0.0908 0.000
0.101 0.000
0.136 0.000
0.331 0.000
0.169 0.000
0501HBWW234 0501HBWW220
2010513906 2010513907
Coric Flag DL RL ·cone Flaa. ·-Dl RL
ND 0.127 0.000 ND 0.127 0.000
ND 0.0777 0.000 ND 0.0777 0.000
ND 0.178 0.000 ND 0.178 0.000
ND 0.0974 0.000 ND 0.0974 0.000
ND 0.548 0.000 ND 0.548 0.000
ND 0.140 0.000 ND 0.140 0.000
ND 0.137 0.000 ND 0.137 0.000
ND 0.148 0.000 ND 0.148 0.000
ND 0.780 0.000 ND 0.780 0.000
ND 0.150 0.000 ND 0.150 0.000
ND 0.0965 0.000 ND 0.0965 0.000
ND 0.0846 0.000 ND 0.0846 0.000
ND 0.237 0.000 ND 0.237 0.000
ND 0.124 0.000 ND 0.124 0.000
ND 0.102 0.000 ND 0.102 0.000
ND 0.122 0.000 ND 0.122 0.000
ND 0.112 0.000 ND 0.112 0.000
ND 0.119 0.000 ND 0.119 0.000
ND 0.0869 0.000 ND 0.0869 0.000
ND 0.135 0.000 ND 0.135 0.000
ND 0.160 0.000 ND 0.160 0.000
ND 0.0994 0.000 ND 0.0994 0.000
ND 0.0818 0.000 ND 0.0818 0.000
ND 0.0908 0.000 ND 0.0908 0.000
ND 0.101 0.000 ND 0.101 0.000
ND 0.136 0.000 ND 0.136 0.000
ND 0.331 0.000 ND 0.331 0.000
ND 0.169 0.000 ND 0.169 0.000
Page 10 of 46
-------------------
-~--~------~~--~~--
SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Client Sample ID
Lab Sample ID
0501HBWW225
2010513905
«··· .. Parameter . ,, ,. .. : ·"··cAs~·:." .. -~t ·cone· .. -Flaa. DL. ..
Iodomethane 74-88-4 ND
Isopropylbenzene 98-82-8 ND
4-Isooroovltoluene 99-87-6 ND
Methyl methacrvlate 80-62-6 ND
Methyl tert-butvl ether <MTBE) 1634-04-4 ND
4-Methvl-2-pentanone (MIBK) 108-10-1 ND
Methylene chloride 75-09-2 ND
Naphthalene 91-20-3 ND
Propanenitrile 107-12-0 ND
n-Propylbenzene 103-65-1 ND
Stvrene 100-42-5 ND
I.I l 2-Tetrachloroethane 630-20-6 ND
I I 2,2-Tetrachloroethane 79-34-5 ND
Tetrachloroethene 127-18-4 ND
Tetrahydrofuran 109-99-9 ND
Toluene 108-88-3 ND
I 2.3-Trichlorobenzene 87-61-6 ND
l 2,4-Trichlorobenzene 120-82-1 ND
I I.I-Trichloroethane 71-55-6 ND
1.1.2-Trichloroethane 79-00-5 ND
Trichloroethene 79-01-6 ND
Trichlorofluoromethane 75-69-4 ND
1,2,3-Trichloropropane 96-18-4 ND
1.1 2-Trichlorotrifluoroethane 76-13-1 ND
1.2 4-Trimethvlbenzene 95-63-6 ND
1.3 5-Trimethylbenzene 108-67-8 ND
Vinyl acetate 108-05-4 ND
Vinvl chloride 75-01-4 ND
SECTION IV -Analytical Results -05/30/2001 13:23
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
0.109
0.0931
0.115
0.131
0.116
0.178
0.126
0.0801
1.59
0.140
0.0977
0.111
0.0870
0.144
0.900
0.0637
0.551
0.135
0.169
0.0821
0.137
0.106
0.288
0.123
0.124
0.0905
0.0948
0.114
RL
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0501HBWW234 0501HBWW220
2010513906 2010513907
" Coric :~:. ··Flaa DL RL'i' .iY.· .Cone·::_ .. ·Flaa;, ;:;DL.•:: •":Rl . -._
ND 0.109 0.000 ND 0.109 0.000
ND 0.0931 0.000 ND 0.0931 0.000
ND 0.115 0.000 ND 0.115 0.000
ND 0.131 0.000 ND 0.131 0.000
ND 0.116 0.000 ND 0.116 0.000
ND 0.178 0.000 ND 0.1.78 0.000
ND 0.126 0.000 ND 0;t26 0.000
ND 0.0801 0.000 ND 0.0801 0.000
ND 1.59 0.000 ND 1.59 0.000
ND 0.140 0.000 ND 0.140 0.000
ND 0.0977 0.000 ND 0.0977 0.000
ND 0.111 0.000 ND 0.111 0.000
ND 0.0870 0.000 ND 0.0870 0.000
ND 0.144 0.000 ND 0.144 0.000
ND 0.900 0.000 ND 0.900 0.000
ND 0.0637 0.000 ND 0.0637 0.000
ND 0.551 0.000 ND 0.551 0.000
ND 0.135 0.000 ND 0.135 0.000
ND 0.169 0.000 ND 0.169 0.000
ND 0.0821 0.000 ND 0.0821 0.000
ND 0.137 0.000 ND 0.137 0.000
ND 0.106 0.000 ND 0.106 0.000
ND 0.288 0.000 ND 0.288 0.000
ND 0.123 0.000 ND 0.123 0.000
ND 0.124 0.000 ND 0.124 0.000
ND 0.0905 0.000 ND 0.0905 0.000
ND 0.0948 0.000 ND 0.0948 0.000
ND 0.114 0.000 ND 0.114 0.000
Page 11 of 46
SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
o-X vlene/m-X vlene
o-Xvlene
Client Sample ID
Lab Sample ID
cAS'
106-42-3
95-47-6
SECTION IV -Analytical Results -05/30/2001 13:23
050 l HBWW225
2010513905
Cone Flaa
ND
ND
LIMS Workorder: 80396907.01 [20105139) Hamilton Beach-Proctor Silex
STLAustin
DL RL
0.167 0.000
0.0844 0.000
0501HBWW234 0501HBWW220
2010513906 2010513907
Cone Flaa DL RL Cone l. Fia~f .DL·' · ··RL
ND 0.167 0.000 ND 0.167 0.000
ND 0.0844 0.000 ND 0.0844 0.000
Page 12 of 46
------------~--~---
----~---~------~--­SECTION IV
Analytical Results
Surrogates
MS-VOA
SW8260B
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
0501HBWW225
2010513905
Aaueous
Received
NA
05/16/2001I1:30
05/21/200 l 23 :34
05/21/200 l 23 :34
1
MSDA
ug/L
: ::sufro!iateJ:~o'inrio.ln:ld : .~~··:L~.:;~+:: ;;.~·~. :~. ,., ~% Recov.en; :» : : :Limits .. :".
l-Bromo-4-fluorobenzene 102
l ,2-Dichloroethane-d4 110
Toluene-d8 100
SECTION IV -Analytical Results -05/30/2001 13:23
LIMS Workorder: 80396907.01 [20I05139] Hamilton Beach-Proctor Silex
STLAustin
77-117
61-143
87-113
... ;:'.'-:-.,·F".
0501HBWW234 0501HBWW220
2010513906 2010513907
Aaueous Aaueous
Received Received
NA NA
05/16/200 I I 0:55 051161200 l 11 :50
05/22/200 I 00:02 05/22/200 l 00:29
05/22/2001 00:02 05/22/200 l 00:29
1 I
MSDA MSDA
ug/L ug/L
% ·Recoverv ;: ·· Limits . :.:, .. ~--:; ~:.f.~ ;% .. Recoveiv, ~·;,~;_',Limits ... .. F .. ..
102 77-117 103 77-117
108 61-143 111 61-143
100 87-113 101 87-113
Page 13 of 46
SECTION IV
Analytical Results
MS-VOA
SW8260B
. . Parameter
Acetone
Acetonitrile
Acrolein
Acrvlonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromofonn
Bromomethane
2-Butanone (MEK)
n-Butvlbenzene
sec-Butvlbenzene
tert-Butvlbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1.3-butadiene
Chlorobenzene
Chloroethane
Chlorofonn
1-Chlorohexane
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
..
CAS
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
SECTION IV -Analytical Results -05/30/2001 13:23
0501HBWW222
2010513908
Aaueous
Received
NA
05/16/2001 12:10
05/22/200 l 00:58
05/22/200 l 00:58
l
MSDA
ug/L
Cone Flaa·
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
DL RL
0.438 0.000
6.82 0.000
3.79 0.000
0.446 0.000
0.0641 0.000
0.0998 0.000
0.131 0.000
0.118 0.000
0.170 0.000
0.199 0.000
0.200 0.000
0.102 0.000
0.105 0.000
0.0911 0.000
0.0684 0.000
0.0652 0.000
0.114 0.000
0.0842 0.000
0.0925 0.000
0.0896 0.000
0.0938 0.000
TRIP BLANK 050IHBWD999
2010513909 2010513903
Aaueous Aaueous
Received Received
NA NA
05/16/2001 00:00 05/16/2001 10:30
05/22/2001 01:26 05/22/2001 11 :36
05/22/2001 01 :26 05/22/2001 11:36
1 1
MSDA MSDA
ug/L ug/L
Cone Flaa DL ·RL Cone· Flaa DL RL
ND 0.438 0.000 ND 0.438 0.000
ND 6.82 0.000 ND 6.82 0.000
ND 3.79 0.000 ND 3.79 0.000
ND 0.446 0.000 ND 0.446 0.000
ND 0.0641 0.000 ND 0.0641 0.000
ND 0.0998 0.000 ND 0.0998 0.000
ND 0.131 0.000 ND 0.131 0.000
ND 0.118 0.000 ND 0.118 0.000
ND 0.170 0.000 ND 0.170 0.000
ND 0.199 0.000 ND 0.199 0.000
ND 0.200 0.000 ND 0.200 0.000
ND 0.102 0.000 ND 0.102 0.000
ND 0.105 0.000 ND 0.105 0.000
ND 0.0911 0.000 ND 0.0911 0.000
ND 0.0684 0.000 ND 0.0684 0.000
ND 0.0652 0.000 ND 0.0652 0.000
ND 0.114 0.000 ND 0.114 0.000
ND 0.0842 0.000 ND 0.0842 0.000
ND 0.0925 0.000 ND 0.0925 0.000
ND 0.0896 0.000 ND 0.0896 0.000
ND 0.0938 0.000 ND 0.0938 0.000
Page 14 of 46
----~---~--~----~--
----------------~--SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
.. . Parameter:
Chloromethane
3-Chloroorooene
2-Chlorotoluene
4-Chlorotoluene
·J, . .
·,.
Client Sample ID
Lab Sample ID
., .. : ·CA~f·:' ..
74-87-3
107-05-1
95-49-8
106-43-4
l 2-Dibromo-3-chloroorooane 96-12-8
Dibromochloromethane 124-48-1
1.2-Dibromoethane 106-93-4
Dibromomethane 74-95-3
trans-1.4-Dichloro-2-butene 110-57-6
1 4-Dichlorobenzene 106-46-7
1,2-Dichlorobenzene 95-50-1
1 3-Dichlorobenzene 541-73-1
Dichlorodifluoromethane 75-71-8
1 1-Dichloroethane 75-34-3
1 2-Dichloroethane 107-06-2
l, 1-Dichloroethene 75-35-4
cis-1 2-Dichloroethene 156-59-2
trans-1.2-Dichloroethene 156-60-5
1 2-Dichloroorooane 78-87-5
l 3-Dichloroorooane 142-28-9
2.2-Dichloroorooane 594-20-7
I, 1-Dichloroorooene 563-58-6
cis-1.3-Dichloroorooene l 0061-01-5
trans-I 3-Dichloroorooene 10061-02-6
Ethvl methacrvlate 97-63-2
Ethvlbenzene 100-41-4
Hexachloro-1 3-butadiene 87-68-3
2-Hexanone 591-78-6
SECTION IV -Analytical Results -05/30/2001 13:23
0501HBWW222
2010513908
.. Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.536
ND
0.0793 u
0.260 J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
DL
0.127
0.0777
0.178
0.0974
0.548
0.140
0.137
0.148
0.780
0.150
0.0965
0.0846
0.237
0.124
0.102
0.122
0.112
0.119
0.0869
0.135
0.160
0.0994
0.0818
0.0908
0.101
0.136
0.331
0.169
TRIP BLANK 050 lHBWD999
2010513909 2010513903
RC: Cone Flaa DL RL··::. ··,':: .cone ' -.Flaa'. OL:· :' .· .. RL
0.000 ND 0.127 0.000 ND 0.127 0.000
0.000 ND 0.0777 0.000 ND 0.0777 0.000
0.000 ND 0.178 0.000 ND 0.178 0.000
0.000 ND 0.0974 0.000 ND 0.0974 0.000
0.000 ND 0.548 0.000 ND 0.548 0.000
0.000 ND 0.140 0.000 ND O.J40 0.000
0.000 ND 0.137 0.000 ND o::n1 0.000
0.000 ND 0.148 0.000 ND O.T48 0.000
0.000 ND 0.780 0.000 ND 0.780 0.000
0.000 ND 0.150 0.000 ND 0.150 0.000
0.000 ND 0.0965 0.000 ND 0.0965 0.000
0.000 ND 0.0846 0.000 ND 0.0846 0.000
0.000 ND 0.237 0.000 ND 0.237 0.000
0.000 ND 0.124 0.000 ND 0.124 0.000
0.000 ND 0.102 0.000 ND ff.l02 0.000
0.000 ND 0.122 0.000 ND 0.122 0.000
0.000 ND 0.112 0.000 ND 0.112 0.000
0.000 ND 0.119 0.000 ND 0.119 0.000
0.000 ND 0.0869 0.000 ND 0.0869 0.000
0.000 ND 0.135 0.000 ND 0.135 0.000
0.000 ND 0.160 0.000 ND 0.160 0.000
0.000 ND 0.0994 0.000 ND 0.0994 0.000
0.000 ND 0.0818 0.000 ND 0.0818 0.000
0.000 ND 0.0908 0.000 ND 0.0908 0.000
0.000 ND 0.101 0.000 ND 0.101 0.000
0.000 ND 0.136 0.000 ND 0.136 0.000
0.000 ND 0.331 0.000 ND 0.331 0.000
0.000 ND 0.169 0.000 ND 0.169 0.000
Page 15 of 46
SECTION IV
Analytical Results
MS-VOA
SW8260B
Client Sample ID
Lab Sample ID
Continued
· . Parameter· .: ','• :-: .CAS: ·, ·: ··. -. ..
Iodomethane 74-88-4
Isooroovlbenzene 98-82-8
4-Isooroovltoluene 99-87-6
Methyl methacrvlate 80-62-6
Methvl tert-butvl ether (MTBE) 1634-04-4
4-Methvl-2-oentanone (MIBK) 108-10-1
Methvlene chloride 75-09-2
Naphthalene 91-20-3
Prooanenitrile 107-12-0
n-Proovlbenzene 103-65-1
Styrene 100-42-5
l 1.1 2-Tetrachloroethane 630-20-6
l l,2 2-Tetrachloroethane 79-34-5
Tetrachloroethene 127-18-4
Tetrahvdrofuran 109-99-9
Toluene 108-88-3
I .2.3-Trichlorobenzene 87-61-6
1.2 4-Trichlorobenzene 120-82-1
l, 1.1-Trichloroethane 71-55-6
l 1.2-Trichloroethane 79-00-5
Trichloroethene 79-01-6
Trichlorofluoromethane 75-69-4
l 2.3-Trichloroorooane 96-18-4
l 1.2-Trichlorotrifluoroethane 76-13-1
l 2.4-Trimethvlbenzene 95-63-6
l 3.5-Trimethvlbenzene 108-67-8
Vinvl acetate 108-05-4
Vinvl chloride 75-01-4
SECTION IV -Analytical Results -05/30/2001 13:23
0501HBWW222
2010513908
·Cone Flaa . Di..:
ND 0.109
ND 0.0931
ND 0.115
ND 0.131
ND 0.116
ND 0.178
ND 0.126
ND 0.0801
ND 1.59
ND 0.140
ND 0.0977
ND 0.111
ND 0.0870
ND 0.144
ND 0.900
ND 0.0637
ND 0.551
ND 0.135
ND 0.169
ND 0.0821
ND 0.137
ND 0.106
ND 0.288
ND 0.123
ND 0.124
ND 0.0905
ND 0.0948
ND 0.114
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
. RL· .
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TRIP BLANK 0501 HBWD999
2010513909 2010513903
" Cone .. ·Flaa DL' RL Coric. Flaa~ .oL· RL
ND 0.109 0.000 ND 0.109 0.000
ND 0.0931 0.000 ND 0.0931 0.000
ND 0.115 0.000 ND 0.115 0.000
ND 0.131 0.000 ND 0.131 0.000
ND 0.116 0.000 ND 0.116 0.000
ND 0.178 0.000 ND 0.178 0.000
0.295 J 0.126 0.000 ND 0.126 0.000
ND 0.0801 0.000 ND 0.0801 0.000
ND 1.59 0.000 ND 1.59 0.000
ND 0.140 0.000 ND 0.140 0.000
ND 0.0977 0.000 ND 0.0977 0.000
ND 0.111 0.000 ND 0.111 0.000
ND 0.0870 0.000 ND 0.0870 0.000
ND 0.144 0.000 ND 0.144 0.000
ND 0.900 0.000 ND 0.900 0.000
ND 0.0637 0.000 ND 0.0637 0.000
ND 0.551 0.000 ND 0.551 0.000
ND 0.135 0.000 ND 0.135 0.000
ND 0.169 0.000 ND 0.169 0.000
ND 0.0821 0.000 ND 0.0821 0.000
ND 0.137 0.000 ND 0.137 0.000
ND 0.106 0.000 ND 0.106 0.000
ND 0.288 0.000 ND 0.288 0.000
ND 0.123 0.000 ND 0.123 0.000
ND 0.124 0.000 ND 0.124 0.000
ND 0.0905 0.000 ND 0.0905 0.000
ND 0.0948 0.000 ND 0.0948 0.000
ND 0. I 14 0.000 ND 0.114 0.000
Page 16 of 46
----------------~--
-------------------SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
-'. Parameter -_
n-Xvlene/m-Xvlene
o-Xvlene
Client Sample ID
Lab Sample ID
'CAS:_
106-42-3
95-47-6
SECTION IV -Analytical Results -05/30/2001 13:23
0501HBWW222
2010513908
'· ... _ Cone -Fiaa ---ND
ND
LIMS' Workorder: 80396907.0 I [20 I 05139] Hamilton Beach-Proctor Silex
STLAustin
'DL
0.167
0.0844
TRIP BLANK 0501HBWD999
2010513909 2010513903
RL-_'_ _Cone_ -_Flaa -oL -. RL'---: -.cone> " . Flaa~ ~J)L ,, RL
0.000 ND 0.167 0.000 ND 0.167 0.000
0.000 ND 0.0844 0~000 ND 0.0844 0.000
Page 17 of 46
SECTION IV
Analytical Results
Surrogates
MS-VOA
SW8260B
Surroaate Comoound
l-Bromo-4-fluorobenzene
l-2-Dichloroethane-d4
Toluene-d8
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
..
SECTION IV -Analytical Results -05/30/2001 13:23
0501HBWW222
2010513908
Aaueous
Received
NA
05/16/200 l 12: 10
05/22/200 I 00:58
05/22/2001 00:58
1
MSDA
u!!IL
% Recoverv
103
111
97
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
Limits '· . F.
77-117
61-143
87-113
TRIP BLANK 0501HBWD999
2010513909 2010513903
Aaueous Aaueous
Received Received
NA NA
05/16/2001 00:00 05/16/200I I0:30
05/22/200 I 0 I :26 05/22/2001 I I :36
05/22/200 I 0 I :26 05/22/200 I I I :36
1 1
MSDA MSDA
u!!IL Ull/L
% Recoverv Limits F % Recoverv· .: Limits· F
101 77-117 105 77-117
105 61-143 107 61-143
99 87-113 103 87-113
Page 18 of 46
------~------------
_____ , __ _ --·-------SECTIONV
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW82608
Sample Type: Continuing Calibration Check
Analysis Batch ID: 12204 Instrument Data File: A0521102.D
Instrument ID: MSDA Analyst: BJP
Parameter -. Reference Value Measured Cone,
Acetone 20 20.7
Acetonitrile 100 107
Acrolein 100 130
Acrvlonitrile 20 19.6
Benzene 20 18.8
Bromobenzene 20 20.4
Bromochloromethane 20 18.9
Bromodichloromethane 20 21.1
Bromoform 20 20.0
Bromomethane 20 23.3
2-Butanone fMEK) 20 17.6
n-Butv !benzene 20 18.4
sec-Butvlbenzene 20 18.0
tert-Butvlbenzene 20 18.6
Carbon disulfide 20 16.2
Carbon tetrachloride 20 20.0
2-Chloro-l 3-butadiene 20 17.4
Chlorobenzene 20 19.8
Chloroethane 20 19.4
Chloroform 20 19.5
1-Chlorohexane 20 17.6
Chloromethane 20 17.3
3-Chloronronene 20 16.9
2-Chlorotoluene 20 19.4
4-Chlorotoluene 20 19.0
1 2-Dibromo-3-chloroorooane 20 22.l
SECTION V -Calibration and QC Infomiation -05/30/2001 13:23
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
Flatt
Date/Time Analyzed:05/21/2001 15:37
Units: · ug/L
%Recoverv Flaa QC Limits. %Recover:v
104
107
130
98
94
102
95
105.
100
117
88
92
90
93
81
100
87
99
97
98 80-120
88
86
84
97
95
111
Page 19
- -
of 46
SECTIONV
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW82608
Sample Type: Continuing Calibration Check
Analysis Batch ID: 12204 Instrument Data File: A052 l 102.D
Instrument ID: MSDA Analyst: BJP
Continued
Parameter Reference Value Measured Cone
Dibromochloromethane 20 19.4
1-2-Dibromoethane 20 20.3
Dibromomethane 20 22.1
trans-1 4-Dichloro-2-butene 20 17.6
1 4-Dichlorobenzene 20 18.9
1 2-Dichlorobenzene 20 19.6
1 3-Dichlorobenzene 20 19.3
Dichlorodifluoromethane 20 22.0
Ll-Dich1oroethane 20 21.5
l .2-Dich1oroethane 20 19.4
1.1-Dichloroethene 20 18.2
cis-1 2-Dichloroethene 20 19. l
trans-1.2-Dichloroethene 20 19.4
1 2-Dichloronronane 20 19.7
1 3-Dichloronronane 20 20.6
2.2-Dichloronronane 20 19.7
1 1-Dichloronronene 20 20.5
cis-1 3-Dichloronrooene 20 19.7
trans-1.3-Dichloronronene 20 20.0
Ethv1 methacrvlate 20 19.4
Ethvlbenzene 20 18.9
Hexachloro-1 3-butadiene 20 19.4
2-Hexanone 20 18.9
lodomethane 20 14.9
lsonronvlbenzene 20 18.3
4-Isonronv1toluene 20 18.9
SECTION V -Calibration and QC Information -05/30/2001 13:23
LIMS Workorder: 80396907 .0 I [20 I 05139) Hamilton Beach-Proctor Silex
STL Austin
Flaa
Dateffime Analyzed:05/2 l/2001 15:37
Units: ug/L
%Recoverv Flaa QC Limits %Recoverv
97
102
110
88
95
98
97
110
108
97
91 80-120
96
97
98 80-120
103
98
102
99
100
97
94 80-120
97
95
74
92
95
Page 20
----------·-------
of 46
- -
----------·---__ .. __ _
SECTIONV
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW8260B
Sample Type: Continuing Calibration Check
Analysis Batch ID: I2204 Instrument Data File: A052 I I 02.D
Instrument ID: MSDA Analyst: BJP
Continued
:~Parameter>,;~-~-"·~->~:/<:<·:>;·~:. . :-Retetencti<Value:t ·· Measured. Cone--.~
Methvl methacrvlate 20 I9.7
Methvl tert-butvl ether <MTBE) 20 18.9
4-Methvl-2-nentanone fMlBK) 20 18.9
Methvlene chloride 20 20.4
Nanhthalene 20 16.8
Pronanenitrile 100 97.9
n-Pronvlbenzene 20 19.0
Stvrene 20 19. I
I I. I 2-Tetrachloroethane 20 19.8
I. I 2 2-Tetrachloroethane 20 21.1
Tetrachloroethene 20 I6.0
Tetrahvdrofuran 20 22.6
Toluene 20 I8.8
I 2 3-Trichlorobenzene 20 19.4
1.2 4-Trichlorobenzene 20 18.8
I. I I-Trichloroethane 20 I9.6
I. I 2-Trichloroethane 20 20.5
Trichloroethene 20 19.9
Trichlorofluoromethane 20 19.8
I 2 3-Trichloronronane 20 21.0
I I .2-Trichlorotrifluoroethane 20 20.9
L2.4-Trimethvlbenzene 20 I8.4
I 3.5-Trimethvlbenzene 20 18.4
Vinvl acetate 20 20.4
Vinvl chloride 20 19.5
n-X vlene/m-X vlene 40 37.8
SECTION V -Calibration and QC Information -05/30/200 I 13:23
LIMS Workorder: 80396907 .0 I (20 I 05139] Hamilton Beach-Proctor Silex
STL Austin
~
.Flaa"';::·:~ ...
Date/Time Analyzed:05/21/200I I5:37
Units: ug/L
.%Recovei:v Flaa.·-:. '• oc Limits .%Recovet:V .-: ·
99
95
94
102
84
98
95
96
99
105
80
II3
94 80-I20
97
94
98
103
99
99
105
105
92
92
102
98 80-I20
94
Page 21 of 46
- --_____ .. _______ _
SECTIONV
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW82608
Sample Type: Continuing Calibration Check
Analysis Batch ID: 12204 Instrument Data File: A0521125.D
Instrument ID: MSDA Analyst: BJP
.~·Parameter· -~ . _ .. ·~-. ' ' ·Reference va1.ue:': Measured .co.nc. ', ..
Acetone 20 19.9
Acetonitrile 100 112
Acrolein 100 116
Acrvlonitrile 20 18.9
Benzene 20 19.8
Bromobenzene 20 20.5
Bromochloromethane 20 19.4
Bromodichloromethane 20 21.2
Bromoform 20 17.9
Bromomethane 20 22.5
2-Butanone fMEK) 20 17.3
n-Butvlbenzene 20 18.4
sec-Butvlbenzene 20 17.7
tert-Butvlbenzene 20 18.7
Carbon disulfide 20 16.0
Carbon tetrachloride 20 18.6
2-Chloro-1.3-butadiene 20 17.4
Chlorobenzene 20 20.5
Chloroethane 20 18.4
Chloroform 20 19.6
1-Chlorohexane 20 17.8
Chloromethane 20 16.4
3-Chloronronene 20 16.6
2-Chlorotoluene 20 19.3
4-Chlorotoluene 20 18.8
1 2-Dibromo-3-chloroorooane 20 20.2
SECTION V -Calibration and QC Information -05/30/2001 13:23
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
.. Flaa· 'i-
Date/Time Analyzed:05/22/2001 03:19
Units: ug/L
.%Recoverv Ffaa : QC Limits %Recoverv
99
112
116
95
99
102
97
106
90
113
87
92
88
93
80
93
87
103
92
98 80-120
89
82
83
97
94
101
Page 23
- -
of 46
SECTIONV
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW8260B
Sample Type: Continuing Calibration Check
Analysis Batch ID: 12204 Instrument Data File: A0521125.D
Instrument ID: MSDA Analyst: BJP
Continued
.. Parameter ... "· · ,. Refer.ence Value Measured Cone.
Dibromochloromethane 20 18.3
l 2-Dibromoethane 20 21.0
Dibromomethane 20 22.3
trans-L4-Dichloro-2-butene 20 14.7
1.4-Dichlorobenzene 20 19.1
l 2-Dichlorobenzene 20 20.1
l .3-Dichlorobenzene 20 19.6
Dichlorodifluoromethane 20 17.1
1.1-Dichloroethane 20 16.7
I 2-Dichloroethane 20 20.2
1.1-Dichloroethene 20 18.0
cis-1 2-Dichloroethene 20 19.0
trans-1 2-Dichloroethene 20 19.5
I 2-Dichloronronane 20 20.7
L3-Dichloronronane 20 21.4
2.2-Dichloronrooane 20 13.7
I 1-Dichloronronene 20 20.9
cis-1 3-Dichloronronene 20 19.5
trans-I 3-Dichloroorooene 20 18.4
Ethvl methacrvlate 20 19.9
Ethvlbenzene 20 19.5
Hexachloro-L3-butadiene 20 17.8
2-Hexanone 20 19.6
Iodomethane 20 19.0
Isooronvlbenzene 20 18.6
4-Isonronvltoluene 20 18.6
SECTION V -Calibration and QC Information -05/30/200 I 13:23
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
·Flaa
Dateffime Analyzed:05/22/2001 03: 19
Units: ug/L
%Recoverv .Flaa QC Limits %Recoverv
92
105
112
73
95
IOI
98
85
84
101
90 80-120
95
98
104 80-120
107
68
105
97
92
99
97 80-120
89
98
95
93
93
Page 24 - - -
_____ .. _______ _ of 46
- -
-------------------SECTIONV
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW82608
Sample Type: Continuing Calibration Check
Analysis Batch ID: 12204 Instrument Data File: A0521125.D
Instrument ID: MSDA Analyst: BJP
Continued
Parameter " Reference Value Measured Cone ... ,
Methvl methacrvlate 20 20.4
Methvl tert-butvl ether <MTBE) 20 20.2
4-Methvl-2-nentanone <MIBK) 20 19.7
Methvlene chloride 20 21.0
Nanhthalene 20 18.8
Pronanenitrile 100 92.l
n-Pronvlbenzene 20 18.8
Stvrene 20 19.6
1 1.1.2-Tetrachloroethane 20 18.8
I 1.2.2-Tetrachloroethane 20 19.9
Tetrachloroethene 20 25.7
Tetrahvdrofuran 20 21.2
Toluene 20 19.2
1 2 3-Trichlorobenzene 20 20.7
1 2.4-Trichlorobenzene 20 I9.2
I LI-Trichloroethane 20 18.8
I. I 2-Trichloroethane 20 21.4
Trichloroethene 20 21.4
Trichlorofluoromethane 20 18.7
l 2.3-Trichloronronane 20 22.1
l 1.2-Trichlorotrifluoroethane 20 17.9
1.2.4-Trimethvlbenzene 20 18.4
1.3 5-Trimethvlbenzene 20 18.5
Vinvl acetate 20 11.4
Vinvl chloride 20 18.2
n-Xvlene/m-Xvlene 40 38.4
SECTION V -Calibration and QC Information -05/30/2001 13:23
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
Flaa
Dateffime Analyzed:OS/22/2001 03:I9
Units: ug/L
%Recoveni Flaa QC Limits. %Recoverv .
102
IOI
99
105
94
92
94
98
94
100
129
106
96 80-120
103
96
94
107
107
94
110
90
92
92
57
91 80-120
96
Page 25 of 46
-------------------SECTIONV
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW8260B
Sample Type: Continuing Calibration Check
Analysis Batch ID: 12204 Instrument Data File: A052 l 142.D
Instrument ID: MSDA Analyst: BJP
f>aranieter. .. Reference Value · Measured Cone
Acetone 20 19.8
Acetonitrile 100 98.0
Acrolein 100 127
Acrvlonitrile 20 20.5
Benzene 20 20.1
Bromobenzene 20 20.3
Bromochloromethane 20 20.0
Bromodichloromethane 20 21.6
Bromoform 20 20.4
Bromomethane 20 23.3
2-Butanone <MEK) 20 21.9
n-Butvlbenzene 20 19.0
sec-Butvlbenzene 20 17.9
tert-Butvlbenzene 20 19.0
Carbon disulfide 20 18.8
Carbon tetrachloride 20 19.4
2-Chloro-l .3-butadiene 20 18.1
Chlorobenzene 20 20.2
Chloroethane 20 19.6
Chloroform 20 19.9
1-Chlorohexane 20 18.8
Chloromethane 20 16.9
3-Chloronronene 20 19. l
2-Chlorotoluene 20 19.0
4-Chlorotoluene 20 19.1
1 2-Dibromo-3-chloroorooane 20 21.5
SECTION V -Calibration and QC Information -05/3012001 13:23
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
Flaa·. -.
Date/Time Analyzed:05/22/2001 16:54
Units: ug/L
-%Recoverv Flaa QC Llmits'%Recoverv ·
99
98
127
102
100
102
100
108
102
116
109
95
90
95
94
97
91
101
98
100 80-120
94
85
96
95
96
107
Page 27 of 46
SECTIONV
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW8260B
Sample Type: Continuing Calibration Check
Analysis Batch ID: 12204 Instrument Data File: A0521142.D
Instrument ID: MSDA Analyst: BJP
Continued
Parameter: .. ... Reference Vaiue Measured .Cone .. . . . . . . ..
Dibromochloromethane 20 20.2
l 2-Dibromoethane 20 20.8
Dibromomethane 20 22.5
trans-1 .4-Dichloro-2-butene 20 19.8
1.4-Dichlorobenzene 20 19.4
1.2-Dichlorobenzene 20 19.8
1 3-Dichlorobenzene 20 19.7
Dichloroditluoromethane 20 21.2
I. 1-Dichloroethane 20 17.4
l 2-Dichloroethane 20 20.2
1 1-Dichloroethene 20 18.5
cis-1 2-Dichloroethene 20 19.7
trans-1.2-Dichloroethene 20 20.0
l 2-Dichloronronane 20 21.0
1 3-Dichloroorooane 20 21.7
2.2-Dichloroorooane 20 17.4
l. l-Dichloronrooene 20 21.0
cis-1.3-Dichloroorooene 20 20.3
trans-I 3-Dichloronronene 20 19.8
Ethvl methacrvlate 20 20.l
Etlwlbenzene 20 20.3
Hexachloro-1.3-butadiene 20 18.6
2-Hexanone 20 19.9
Iodomethane 20 20.3
lsooroovlbenzene 20 19.3
4-Isonronvltoluene 20 18.9
SECTION V -Calibration and QC Information -05/30/2001 13:23
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STL Austin
Flaa·
Dateffime Analyzed:05/22/2001 16:54
Units: ug/L
%Recoverv Flaa · QC Limit8'%Recoverv.
101
104
113
99
97
99
98
106.
87
101
93 80-120
98
100
105 80-120
108
87
105
101
99
101
101 80-120
93
99
102
96
94
Page 28 of 46 - - - - -
__________ .. __ _
-------------------SECTIONV
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW8260B
Sample Type: Continuing Calibration Check
Analysis Batch ID: 12204 Instrument Data File: A052 l 142.D
Instrument ID: MSDA Analyst: BJP
Continued
: Parameter:· .. :/:'.::~.~-··:_ ... ·:.:. :·Refere.nce. Value · : Measured .Cone
Methvl methacrvlate 20 20.l
Methvl tert-butvl ether <MTBE) 20 18.6
4-Methvl-2-nentanone <MIBK) 20 19.8
Methvlene chloride 20 20.7
Nanhthalene 20 19. l
Pronanenitrile 100 97.7
n-Pronvlbenzene 20 18.4
Stvrene 20 19.8
l. l I 2-Tetrachloroethane 20 19.7
I .1.2 2-Tetrachloroethane 20 21.8
Tetrachloroethene 20 16.2
Tetrahvdrofuran 20 21.1
Toluene 20 19.2
1 2 3-Trichlorobenzene 20 21.1
I 2.4-Trichlorobenzene 20 19.8
I I. I-Trichloroethane 20 18.7
1.1.2-Trichloroethane 20 21.8
Trichloroethene 20 20.5
Trichlorotluoromethane 20 19.6
I 2 3-Trichloronrooane 20 21.8
1 L2-Trichlorotrifluoroethane 20 19.0
1.2.4-Trimethv !benzene 20 18.9
L3 5-Trimethvlbenzene . 20 18.4
Vinvl acetate 20 20.7
Vinvl chloride 20 19.5
n-Xvlene/m-Xvlene 40 39.6
SECTION V ·Calibration and QC Information· 05/30/2001 13:23
LIMS Workorder: 80396907.01 [20105139) Hamilton Beach-Proctor Silex
STLAustin
:1=1aa.·· ,r,
Date/Time Analyzed:05/22/2001 16:54
Units: ug/L
%Recoverv ".Flaa·: '. Qc Lfrnits· %RecoveiV ...
101
93
99
104
95
98
92
99.
98
109
81
105
96 80-120
106
99
93
109
103 .
98
109
95
95
92
103
97 80-120
99
Page 29 of 46
-------------------SECTIONV
Calibration and QC Information
Mass Spectrometer Tune
MS-VOA
SW82608
BFB
Analysis Batch ID: 12204
Instrument ID: MSDA
Instrument Data File: A0521102.D Date Analyzed: 05/21/2001 15:37
Injection Time: 05/21/2001 15:37 Analyst: BJP
'. ·· .• · .. ";.'. ·1. ··,:'..: ·,:~':::ti·,~i\ :\:;.'~ Ion Abundance Criteria.· .· :: . · '.::'.:' · · · "
:.-Mass/Etierciv))(;_:s; :(:,·~~ ·t lowef Limit> ~: .' lJnner Limit .. :·· ·::" · · . :i' : ,:· ~%· Relative Abundance:
50 15 40 20.5
75 30 60 42.9
95 100 100 100
96 5 9 6.9
173 0 2 0
174 50 59.3
175 5 9 6.8
176 95 101 98
ITI 5 9 6
SECTION V -Calibration and QC Information -05/30/2001 13:23
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin Page 31 of 46
SECTIONV
Calibration and QC Information
Mass Spectrometer Tune
MS-VOA
SW8260B
BFB
Analysis Batch ID: 12204
Instrument ID: MSDA
Mass/Enerav
50
75
95
96
173
174
175
176
177
Instrument Data File: A052 l 125.D
Injection Time: 05/22/200 l 03: 19
Ion Abundance Criteria
Lower Limit Unnerlimit
15 40
30 60
100 100
5 9
0 2
50
5 9
95 101
5 '9
SECTION V -Calibration and QC Information -05/30/200 l 13:23
LIMS Workorder: 80396907 .0 I [20 I 05139) Hamilton Beach-Proctor Silex
STLAustin
Date Analyzed: 05/22/2001 03:19
Analyst: BJP
% Relative Abundance
22.6
41.5
100
6.6
0
72.6
7
98
6.9
Page 32 of 46
-------------------
-------------------SECTIONV
Calibration and QC Information
Mass Spectrometer Tune
MS-VOA
SW8260B
BFB
Analysis Batch ID: 12204
lnstr.ument ID: MSDA
Mass Spectrometer Tune
. MasslEnei'av
50
75
95
96
173
174
175
176
177
'.
. --
Instrument Data File: A0521142.D
Injection Time: 05/22/2001 16:54
Ion Abundance Criteria
Lower Limit · Unner Limit
15 . 40
30 60
100 100
5 9
0 2
50
5 9
95 101
5 9
SECTION V -Calibration and QC Information -05/30/2001 13:23
LIMS Workorder: 80396907.01 [20105139] H!!milton Beach-Proctor Silex
STLAustin
Date Analyzed: 05/22/2001 16:54
Analyst: BJP
% Relative Abundance
20.5
40.7
100
7.4
0
61.2
7.4
99.5
6.8
Page 33 of 46
SECTIONV
Calibration and QC Information
Method Blank Results
MS-VOA
SW8260B
Parameter.
Acetone
Acetonitrile
Acrolein
Acrvlonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromofonn
Bromomethane
2-Butanone (MEK)
n-Butvlbenzene
sec-Butvlbenzene
tert-Butvlbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-l 3-butadiene
Chlorobenzene
Chloroethane
Chlorofonn
1-Chlorohexane
Chloromethane
3-Chloropropene
2-Chlorotoluene
4-Chlorotoluene
Method Blank ID
Sample Type
Matrix
Date/Time Prepared
Date/Time Analyzed
Instrument
Units
-.CAS _·,
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
74-87-3
107-05-1
95-49-8
106-43-4
SECTION Y -Calibration and QC Information -05/30/2001 13:23
1024637
Method Blank
Aqueous
05/21/200 I 17:41
05/21/200 I 17 :41
MSDA
ug/L
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396907.0 I [20 I 05139) Hamilton Beach-Proctor Silex
STLAustin
DL RL Cone Flag DL RL ·Cone Flag DL RL
0.438 0.000
6.82 0.000
3.79 0.000
0.446 0.000
0.0641 0.000
0.0998 0.000
0.131 0.000
0.118 0.000
0.170 0.000
0.199 0.000
0.200 0.000
0.102 0.000
0.105 0.000
0.0911 0.000
0.0684 0.000
0.0652 0.000
0.114 0.000
0.0842 0.000
0.0925 0.000
0.0896 0.000
0.0938 0.000
0.127 0.000
0.0777 0.000
0.178 0.000
0.0974 0.000
Page 34 of 46
-------------------
-------------------SECTIONV
Calibration and QC Information
Method Blank Results
MS-VOA
SW8260B
Method Blank ID
Continued
Parameter CAS
I 2-Dibromo-3-chloroorooane 96-12-8
Dibromochloromethane 124-48-1
I 2-Dibromoethane 106-93-4
Dibromomethane 74-95-3
trans-I 4-Dichloro-2-butene 110-57-6
I 4-Dichlorobenzene 106-46-7
I 2-Dichlorobenzene 95-50-1
1.3-Dichlorobenzene 541-73-1
Dichlorodifluoromethane 75-71-8
I 1-Dichloroethane 75-34-3
I 2-Dichloroethane 107-06-2
I 1-Dichloroethene 75-35-4
cis-1 2-Dichloroethene 156-59-2
trans-I 2-Dichloroethene 156-60-5
I 2-Dichloronronane 78-87-5
I 3-Dichloroorooane I-42-28-9
2.2-Dichloronronane 594-20-7
1.1-Dichloroorooene 563-58-6
cis-1 3-Dichloronrooene 10061-01-5
trans-1.3-Dichloronrooene 10061-02-6
Ethvl methacrvlate 97-63-2
Ethvlbenzene 100-41-4
Hexachloro-1 3-butadiene 87-68-3
2-Hexanone 591-78-6
Iodomethane 74-88-4
Isonronvlbenzene 98-82-8
4-Isonronv Ito luene 99-87-6
Methvl methacrvlate 80-62-6
Methvl tert-butvl ether (MTBE) 1634-04-4
SECTION V -Calibration and QC Information -05/30/2001 13:23
1024637
Cone
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396907 .0 I (20 I 05139] Hamilton Beach-Proctor Silex
STLAustin
Flaa DL .RL Cone Flaa DL RL. .. Cone Flaa.· DL RL ...
0.548 0.000
0.140 0.000
0.137 0.000
0.148 0.000
0.780 0.000
0.150 0.000
0.0965 0.000
0.0846 0.000 ':..;... ...
0.237 0.000
0.124 0.000
0.102 0.000
0.122 0.000
0.112 0.000
0.119 0.000
0.0869 0.000 .· 0.135 0.000
0.160 0.000 "'
0.0994 0.000
0.0818 0.000
0.0908 0.000
0.101 0.000
0.136 0.000
0.331 0.000
0.169 0.000
0.109 0.000
0.0931 0.000
0.115 0.000
0.131 0.000
0.116 0.000
Page 35 of 46
SECTIONV
Calibration and QC Information
Method Blank Results
MS-VOA
SW8260B
Method Blank ID
Continued
;:: . Parameter . cAs
4-MethYl-2-oentanone (MIBK) 108-10-I
Methylene chloride 75-09-2
Naohthalene 91-20-3
Prooanenitrile 107-I2-0
n-ProoYlbenzene I03-65-I
Stvrene I00-42-5
1.1 I 2-Tetrachloroethane 630-20-6
I. l.2 2-Tetrachloroethane 79-34-5
Tetrachloroethene 127-18-4
Tetrahydrofuran 109-99-9
Toluene 108-88-3
l 2 3-Trichlorobenzene 87-61-6
I .2 4-Trichlorobenzene I20-82-I
1.1 I-Trichloroethane 71-55-6
I. I 2-Trichloroethane 79-00-5
Trichloroethene 79-0I-6
Trichlorofluoromethane 75-69-4
I .2.3-Trichloroorooane 96-I8-4
I. I 2-Trichlorotrifluoroethane 76-I3-l
1.2 4-Trimethylbenzene 95-63-6
1,3 5-Trimethvlbenzene 108-67-8
Vinyl acetate 108-05-4
Vinyl chloride 75-01-4
o-Xvlene/m-Xvlene 106-42-3
o-Xylene 95-47-6
SECTION V -Calibration and QC Information -05/30/2001 13:23
1024637
Cone
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
Flaa DL RL Cone Flaa DL RL ., Cone . Flaa·. DL. RL
0.178 0.000
0.126 0.000
0.0801 0.000
1.59 0.000
O.I40 0.000
0.0977 0.000
O.I I l 0.000
0.0870 0.000
0.144 0.000
0.900 0.000
0.0637 0.000
0.55I 0.000
O.I35 0.000
0.169 0.000
0.082I 0.000
O.I37 0.000
0.106 0.000
0.288 0.000
O.I23 0.000
0.124 0.000
0.0905 0.000
0.0948 0.000
0.1 I4 0.000
0.167 0.000
0.0844 0.000
Page 36 of 46
-------------------
-------------------SECTIONV
Calibration and QC Information
Method Blank Results
MS-VOA
SW82608
Surroaate. Compound
l-Bromo-4-fluorobenzene
I 2-Dichloroethane-d4
Toluene-d8
Method Blank ID
Sample Type
Matrix
Date/Time Prepared
Date/Time Analyzed
Instrument
Units
'. ·-' .. '" ,_
SECTION V -Calibration and QC Information -05/30/200 I 13:23
1024637
Method Blank
Aaueous
05/21/200 I 17:41
05/21/200 I 17:41
MSDA
u!dL
% Recovery
105
108
104
LIMS Workorder: 80396907.01 (20105139] Hamilton Beach-Proctor Silex
STLAustin
Limits F .% Recoverv Limits . ·; .. f -% Recoverv.';;;· ·:limits·· F
77-117
61-143
~ 87-113 -
Page 37 of 46
SECTIONV
Calibration and QC Information
Control Sample Results
MS-VOA
SW8260B
Client Sample ID:
Prep Batch ID:
Analysis Batch ID:
" ~ . -, ' -..
LCS for HBN 12204 [MSV/1561]
12204
12204
" " .. . ,'
-.... ; ' . '• ':., .,
i\
Instrument ID: MSDA
Units: ug/L
Matrix: Aqueous
c ontro IS ampe
Lab ID: 1024635 ' '~.
File ID: A0521103.D' · .. . -·-
. --Parameter-':·.:' ; .. SokAmt. cone :%Rec Fla ..
Acetone 20
Benzene 20
Bromobenzene 20
Bromochloromethane 20
Bromodichloromethane 20
Bromoform 20
Bromomethane 20
2-Butanone (MEK) 20
n-Butvlbenzene 20
sec-Butvlbenzene 20
tert-Butvlbenzene 20
Carbon disulfide 20
Carbon tetrachloride 20
Chlorobenzene 20
Chloroethane 20
Chloroform 20
Chloromethane 20
2-Chlorotoluene 20
4-Chlorotoluene 20
l .2-Dibromo-3-chloroprooane 20
Dibromochioromethane 20
I 2-Dibromoethane 20
Dibromomethane 20
SECTION V -Calibration and QC Information -05/30/2001 13:23
LIMS Workorder: 80396907.01 [20 I 05139) Hamilton Beach-Proctor Silex
STLAustin
20.6 103
21.4 107
20.1 100
18.2 91
20.6 103
20.8 104
18.9 94
19.4 97
19.8 99
19.8 99
19.7 98
17.7 88
21.2 106
20.4 102
18.0 90
20.1 100
14.1 71
19.6 98
19.2 96
21.6 108
20.2 IOI
I9.7 98
20.2 101
L~blb:
File ID: .
_Sok.Amt
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
% Moisture:
Analyst:
NA
BJP
C t IS on ro ampe uo 1ca e I D r t
1024636 ~ "~ -~· • ·? .. . ~--~ ·~~ : •' . ,. ;' ~ ... , •. ..·-~;. A0521104.D '/ .. " !'' ,. Cone . %Rec Fla· .. RPO Fla-'.
22.1 l ll 7.5
22.2 l ll 3.7
20.4 102 2
18.0 90 1.1
21.5 108 4.7
22.3 111 6.5
18.0 90 4.3
20.5 102 5
19.5 98 1
19.8 99 0
19.7 99 1
16.7 84 4.7
21.3 107 0.9
20.6 103 1
17.2 86 4.5
19.7 99 1
13.0 65 8.8
19.7 99 1
19.6 98 2.1
22.4 112 3.6
20.8 104 2.9
20.7 104 5.9
21.3 I07 5.8
' QC Limits .. %Rec·, RPO
0.1-240 71
71-133 17
67-127 12
61-145 21
57-135 19
23-151 17
34-128 25
0.1-214 39
28-184 30
45-160 31
65-148 27
29-223 23
46-150 23
77-129 14
39-133 27
64-146 16
18-140 26
70-136 24
74-132 23
39-I 71 25
45-137 15
I 9-I 87 I9
52-I38 21
Page 38 of 46
-------------------
-------------------SECTIONV
Calibration and QC Information
Control Sample Results
MS-VOA
SW8260B
c ontro IS amp e contmue d
.• ' . ·,: -.. ,· ' .. Lab ID:.·: 1024635 .. •I', '!: ,, ( ,'_ ·:· '\, :, _,· ', Lab-ID:. .' •' : ' . .. [ File ID: '
Parameter Sok Amt
l 4-Dichlorobenzene 20
1 2-Dichlorobenzene 20
1 3-Dichlorobenzene 20
Dichlorodifluoromethane 20
1.1-Dichloroethane 20
1 2-Dichloroethane 20
1 1-Dichloroethene 20
cis-1 2-Dichloroethene 20
trans-I 2-Dichloroethene 20
l 2-Dichloroorooane 20
l 3-Dichloropropane 20
2 2-Dichloroorooane 20
1.1-Dichloroorooene 20
cis-1,3-Dichloroorooene 20
trans-1.3-Dichloroorooene 20
Ethvlbenzene 20
Hexachloro-1 3-butadiene 20
2-Hexanone 20
Iodomethane 20
Isooropy !benzene 20
4-Isooroovltoluene 20
4-Methvl-2-oentanone (MlBK) 20
Methvlene chloride 20
Naphthalene 20
n-Proovlbenzene 20
Stvrene 20
1.1, I 2-Tetrachloroethane 20
1 1.2 2-Tetrachloroethane 20
Tetrachloroethene 20
Toluene 20
1 2,3-Trichlorobenzene 20
SECTION V -Calibration and QC Infonnation -05/30/2001 13:23
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
A0521103.D · : File ID:
cone· %Recf'la Sok Amt
19.1 96 20
19.6 98 20
19.0 95 20
9.59 48 20
17.4 87 20
18.5 93 20
19.7 98 20
19.0 95 20
20.6 103 20
18.8 94 20
20.2 101 20
18.0 90 20
20.7 104 20
19.3 97 20
19.8 99 20
19.8 99 20
19.2 96 20
19.8 99 20
i6.5 83 20
19.6 98 20
20.0 100 20
18.8 94 20
20.l 101 20
16.2 81 20
18.7 93 20
19.6 98 20
20.2 101 20
20.8 104 20
17.l 86 20
19.7 98 20
19.6 98 20
c ontro IS ampe up. tea e con mue I D I' t f d
1024636. ,,'t, 'I'•,' " "' . , ., . .. ··.' ·,-' , ~ ... : ', ': ':· -A0521104.D ',. •' QC Limits .. .. -. -~
Cone. %Rec'Fla.· • RPO -Fia: ·: :,~· .%Rec RPO
19.6 98 2.1 70-132 13
19.7 99 1 67-135 14
19.7 99 4.1 68-134 14
8.01 40 18 0.1-166 26
16.6 83 4.7 66-138 19
18.8 94 1.1 48-152 23
18.7 93 5.2 47-175 25
19.0 95 0 66-144 18
20.0 100 3 62-146 22
20.4 102 8.2 '""61-133 17
21.5 107 5.8 --70-128 16
19.4 97 7.5 40-168 30
21.0 105 1 71-155 31
20.8 104 7 36-142 16
20.2 101 2 34-138 21
20.0 100 1 75-131 14
19. l 95 1 46-150 34
20.4 102 3 •"'-· 22-164 34
15.9 79 4.9 -· .
19.9 99 l 54-152 26
19.8 99 l 41-165 28
20.2 101 7.2 27-149 36
19.5 98 3 36-166 23
16.9 85 4.8 32-172 22
19. l 95 2.1 61-143 28
19.2 96 2.1 68-136 14
20.3 102 1 63-141 20
21.4 107 2.8 47-143 20
16.6 83 3.6 69-137 16
19.7 98 0 70-132 17
20.7 103 5 66-140 20
Page 39 of 46
SECTIONV
Calibration and QC Information
Control Sample Results
MS-VOA
SW8260B
Parameter
1,2.4-Trichlorobenzene
l. l . l -Trichloroethane
1 1.2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
l 2 3-Trichloroorooane
1 2 4-Trimethvlbenzene
l 3,5-Trimethvlbenzene
Vinvl acetate
Vinvl chloride
p-X vlene/m-Xvlene
o-Xvlene
SECTION V -Calibration and QC Information -05/30/2001 13:23
Lab ID:
File ID:
Sok Amt
20
20
20
20
20
20
20
20
20
20
40
20
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
C t IS on ro f d ampe con mue
1024635. .. -·Lab ID:
A0521103.D File.ID:
Cone %Rec Fla Sok Amt
18.7 93 20
19.4 97 20
19.7 98 20
19.6 98 20
20.8 104 20
20.8 104 20
19.0 95 20
19.4 97 20
8.49 42 20
14.0 70 20
39.7 99 40
20.2 101 20
C t IS on ro ampe up 1ca e con mue I D I' t f d
1024636 .
A0521104.D QC Limits
Cone %Rec Fla RPO.Fla %Rec RPO
19.0 95 2.1 66-144 22
19.7 99 2 49-155 24
20.0 100 2 67-135 17
20.2 101 3 71-129 17
19.6 98 5.9 39-147 29
21.4 107 2.8 64-140 18
19.3 96 1 54-156 25
19.l 96 1 62-144 25
9.06 45 6.9 0.1-164 31
13.0 65 7.4 24-138 27
39.7 99 0 76-134 15
20.0 100 1 77-131 15
Page 40 of 46
-------------------
-------------------
SECTION V
Calibration and QC Information
Control Sample Results
MS-VOA
SW8260B
.. Lab ID: 1024635
Surroaate Compounds .. -~ -%Recoverv
l-Bromo-4-fluorobenzene 102
1 2-Dichloroethane-d4 101
Toluene-d8 98
SECTION V -Calibration and QC Information -05/30/2001 13:23
LIMS Workorder: 80396907.01 [20!05139] Hamilton Beach-Proctor Silex
STLAustin
.. Fla as
" .. ., ·, .
" Lab ID: 1024636
%Recoverv Flaas 'QC Recoverv Limits
103 77-117
100 61-143
101 87-113
Page 41 of 46
SECTION VI
Batch Summaries
Extraction/Digestion Batch Summary
MS-VOA
SW8260B
Extraction Batch ID: 12204
Client Samole ID '~'. ~ . ' ': ' Laa>· Samole ID
INSTRUMENT QC 1000
INSTRUMENT QC 1406
LCS for HBN 12204 fMSV/15611 1024635
LCSD for HBN 12204 fMSV/15611 1024636
MB for HBN 12204 fMSV/15611 1024637
zzzzzzzzzz 2010513711
zzzzzzzzzz 1024638
zzzzzzzzzz 1024639 zzzzzzzzzz 2010513702 zzzzzzzzzz 2010513709 zzzzzzzzzz 2010513710
050 IHBWW230 2010513901
050 l HBWW226 2010513902
0501HBWW224 2010513904
0501HBWW225 2010513905
050 l HBWW234 2010513906
0501HBWW220 2010513907
0501HBWW222 2010513908
TRIP BLANK 2010513909
zzzzzzzzzz 2010507301
INSTRUMENT QC 1000
INSTRUMENT QC 1406
zzzzzzzzzz 2010507302 zzzzzzzzzz 2010514601 zzzzzzzzzz 2010514701 zzzzzzzzzz 2010514801 zzzzzzzzzz 2010514901
0501HBWD999 2010513903
SECTION VI -Balch Summaries -05/30/200I 13:23
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
Start Dateffime: 05/21/2001 15:37 Analyst: BJP
Stop Dateffime: 05/22/2001 20:45
. Sample Size '
'· Samoleivoe Matrix Initial : ··Final" .. • . Preoaration ·Method ..
GC/MS Tune Aaueous 15 mL I5mL SW8260B
Continuing Calibration Check Aqueous 15 mL 15mL SW8260B
Lab Control Samole Aqueous 15mL 15mL SW8260B
Lab Control Sample Duplicate Aqueous 15mL 15 mL SW8260B
Method Blank Aaueous 15 mL 15 mL SW8260B
Field Sample Aqueous 15 mL 15mL SW8260B
Matrix Spike Aqueous 15 mL 15mL SW8260B
Matrix Spike Duplicate Aqueous 15 mL 15mL SW8260B
Field Sample Aqueous 15 mL 15mL SW8260B
Field Samole Aaueous 15 mL 15mL SW8260B
Field Sample Aqueous 15 mL 15mL SW8260B
Field Samole Aaueous 15mL 15mL SW8260B
Field Sample Aqueous 15 mL 15mL SW8260B
Field Samole Aqueous 15mL 15 mL SW8260B
Field Samole Aqueous 15 mL 15 mL SW8260B
Field Sample Aqueous 15 mL 15 mL SW8260B
Field Samole Aaueous 15 mL 15 mL SW8260B
Field Sample Aqueous 15 mL 15 mL SW8260B
Field Sample Aqueous 15 mL 15 mL SW8260B
Field Sample Aqueous 15 mL 15 mL SW8260B
GC/MS Tune Aqueous 15 mL 15 mL SW8260B
Continuing Calibration Check Aaueous 15 mL 15 mL SW8260B
Field Sample Aqueous 15 mL 15 mL SW8260B
Field Sample Aaueous 15 mL 15 mL SW8260B
Field Sample Aqueous 15 mL 15 mL SW8260B
Field Samole Aaueous 15 mL 15 mL SW8260B
Field Sample Aqueous 15mL 15 mL SW8260B
Field Samole Aaueous 15 mL 15 mL SW8260B
Page 42 of 46
-------------------
-------------------SECTION VI
Batch Summaries
Extraction/Digestion Batch Summary
MS-VOA
SW8260B
Extraction Batch ID: 12204 continued
: ..
Client ·samnle ID · Lab s·amnle ID zzzzzzzzzz 2010507302 zzzzzzzzzz 2010514701 zzzzzzzzzz 2010514801 zzzzzzzzzz 2010514701 zzzzzzzzzz 2010514601
INSTRUMENT OC 1000
INSTRUMENT OC 1406 zzzzzzzzzz 2010514901 zzzzzzzzzz 2010514801
SECTION VI -Batch Summaries -05/30/2001 13:23
LIMS Workorder: 80396907 .0 I [20 I 05139] Hamilton Beach-Proctor Silex
STLAustin
'
Sainole Tvne .
Field Samole
Field Samole
Field Samole
Field Samole
Field Samole
GC/MS Tune
Continuin!! Calibration Check
Field Samole
Field Samole
. Sample Size·· . . . . . ' ~ "\ _. .. .., ~ ' . . ~~ --Initial Firiaf',·. PrenaraHon:Method. .Matrix . .
Aaueous 15 mL 15 mL SW8260B
Aqueous 15 mL 15mL SW8260B
Aaueous 15 mL 15 mL SW8260B
Aqueous 15 mL 15 mL SW8260B
Aaueous 15 mL 15 mL SW8260B
Aqueous 15 mL 15mL SW8260B
Aoueous 15 mL 15mL SW8260B .
Aqueous 15 mL 15mL SW8260B 0
'::
Aaueous 15 mL 15mL SW8260B ,.,_
Page 43 of 46
SECTION VI
Batch Summaries
Analysis Batch Summary
MS-VOA
SW8260B
Analysis Batch ID: 12204 Instrument ID: MSDA
,"~ ,, t'~,·~·'~.
Seauericei · CUent·S~molelD ·, » :. "': ,/::,: · , Lab Samoie ID
l INSTRUMENT OC 1000
2 INSTRUMENT QC 1406
3 LCS for HBN 12204 fMSV/15611 1024635
4 LCSD for HBN 12204 fMSV /1561 l 1024636
5 MB for HBN 12204 fMSV/15611 1024637
6 zzzzzzzzzz 2010513711
7 zzzzzzzzzz 1024638
8 zzzzzzzzzz 1024639
9 zzzzzzzzzz 2010513702
IO ZZZZZZZZZZ 2010513709
11 zzzzzzzzzz 2010513710
12 0501HBWW230 2010513901
13 0501HBWW226 2010513902
14 0501HBWW224 2010513904
15 0501HBWW225 2010513905
16 0501HBWW234 2010513906
17 0501HBWW220 2010513907
18 050 IHBWW222 2010513908
19 TRIP BLANK 2010513909
20 zzzzzzzzzz 2010507301
22 INSTRUMENT QC 1000
23 INSTRUMENT QC 1406
24 zzzzzzzzzz 2010507302
25 zzzzzzzzzz 2010514601
26 zzzzzzzzzz 2010514701
27 zzzzzzzzzz 2010514801
28 zzzzzzzzzz 2010514901
29 050IHBWD999 2010513903
30 zzzzzzzzzz 2010507302
SECTION VI -Batch Summaries -05/30/2001 13:23
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
Analysis
Date Time
05/21/2001 15:37:00
05/21/2001 15:37:00
05/21/2001 16:12:00
05/21/2001 16:45:00
05/21/2001 17:41:00
05/21/2001 18:54:00
05/21/2001 19:24:00
05/21/2001 19:51:00
05/21/2001 20:47:00
05/21/2001 21:15:00
05/21/2001 21:43:00
05/21/2001 22:10:00
05/21/2001 22:38:00
05/21/2001 23:06:00
05/21/2001 23:34:00
05/22/2001 00:02:00
05/22/2001 00:29:00
05/22/2001 00:58:00
05/22/2001 01:26:00
05/22/2001 01:54:00
05/22/2001 03:19:00
05/22/2001 03:19:00
05/22/2001 04:17:00
05/22/2001 04:45:00
05/22/2001 05:14:00
05/22/2001 05:42:00
05/22/2001 06:10:00
05/22/2001 11:36:00
05/22/2001 12:06:00
Analyst: BJP
Samole Tvoe . Sub-Batch ID
GC/MS Tune A052ll02.D 0
Continuing Calibration Check A0521102.D 0
Lab Control Samole A052l 103.D 0
Lab Control Sample Duplicate A052ll04.D 0
Method Blank A0521 l06.D 0
Field Sample A0521107.D 0
Matrix Soike A0521108.D 0
Matrix Spike Duplicate A0521109.D 0
Field Sample A052ll 1 l.D 0
Field Samole A0521l12.D 0
Field Sample A0521I13.D 0
Field Sample A0521114.D 0
Field Sample A0521115.D 0
Field Sample A0521I16.D 0
Field Sample A0521 ll7.D 0
Field Sample A0521l18.D 0
Field Sample A0521l19.D 0
Field Sample A0521120.D 0
Field Sample A0521121.D 0
Field Samole A0521122.D 0
GC/MS Tune A0521125.D 0
Continuing Calibration Check A0521125.D 0
Field Sample A0521127.D 0
Field Samole A0521128.D 0
Field Sample A0521129.D 0
Field Sample A0521130.D 0
Field Sample A052113 l.D 0
Field Samole A0521 l34.D 0
Field Sample A0521135.D 0
Page 44 or 46
-------------------
-------------------SECTION VI
Batch Summaries
Analysis Batch Summary
MS-VOA
SW8260B
Analysis Batch ID: 12204
.. '
Seauence Client Sample ID
31 zzzzzzzzzz
32 zzzzzzzzzz
33 zzzzzzzzzz
34 zzzzzzzzzz
35 INSTRUMENT OC
36 INSTRUMENT QC
37 zzzzzzzzzz
38 zzzzzzzzzz
continued
, ,
~;;._ '
..
SECTION VI -Batch Summaries -05/30/200 I 13:23
. ..
··' Lab Sample ID
2010514701
2010514801
2010514701
2010514601
1000
1406
2010514901
2010514801
LIMS Workorder: 80396907.01 [20105139] Hamilton Beach-Proctor Silex
STLAustin
Analysis · · · " ,. . ..
' Time· SampleTvoe
..
.Analysis File:1b ', ·Sub-Batch ID Date.· ..
05/22/2001 12:50:00 Field Samole A0521136.D 0
05/22/2001 13:18:00 Field Sample A052l 137.D 0
05/22/2001 14:14:00 Field Samole A052l l39.D 0
05/22/2001 14:44:00 Field Sample A052l l40.D 0
05/22/2001 16:54:00 GC/MS Tune A0521142.D 0
05/22/2001 16:54:00 Continuing Calibration Check A052l 142.D 0
05/22/2001 19:55:00 Field Samole A0521145.D --0
05/22/2001 20:45:00 Field Sample A0521146.D >-;: 0 --
Page 45 of 46
SECTION VII
Certifications
State/Aaencv '
Arkansas Department of Pollution Control and Ecology
California Environmental Laboratorv Accreditation Program I Waste Water/Hazardous Waste
Kansas Department of Health and Environment I Solid and Hazardous Waste/Drinking Water
Louisiana Department of Environmental Oualitv, ELAP I Waste Water/Hazardous Waste/Air/Emissions
New Jersev Department of Environmental Protection
New York State Department of Health I Waste Water/Hazardous Waste
North Carolina Deot. of Natural Resources & Community Development I Waste Water
Oklahoma Water Resources Board I Waste Water
South Carolina Deot. of Health & Environmental Control
Utah Deoartment of Health I Solid and Hazardous Waste
Wisconsin Deoartment of Natural Resources
US Air Force/ AFCEE
US Army Corps ofEn!!ineers (ACE)
US Deoartment of A!!riculture I Restricted Soils Permit
SECTION VII -Certifications -05/30/2001 13:23
LIMS Workorder: 80396907 .0 I [20 I 05139] Hamilton Beach-Proctor Silex
STLAuslin
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iD #
2257
E-10165
82005
10915
302
8720
82003002
RADC
999885260
Particioatin!! Laboratorv
S-42350
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