IDX GW Monitoring Rpt Feb 2002 (SF)-OCR

*6031HSSF1066*
" 1111111111111111111111111111
DocumentlD NONCD0001814
Site Name HAMILTON BEACH/PROCTOR SILEX
oocumentType Progress/Monitoring Rpt (PRGMON)
RptSegment 1
DocDate
DocRcvd
Box
Access Level
Division
Section
Program
DocCat
3/18/2002
2/20/2007
SF1066
PUBLIC
WASTE MANAGEMENT
SUPERFUND
IHS (IHS)
FACILITY
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GROUNDWATER MONITORING REPORT
FOR FEBRUARY 2002
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Groundwater Incident No. 14338
Site Priority Ranking B
Prepared for:
Hamilton Beach<> Proctor-Silex, fuc.
4421 Waterfront Drove
Glen Allen, Virginia 23060
Prepared by:
URS Corporation
1600 Perimeter Park Drive
Morrisville, North Carolina 27560
March2002
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CERTIFICATION PAGE
GROUNDWATER MONITORING REPORT
FOR FEBRUARY 2002
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Groundwater Incident No. 14338
Site Priority Ranking B
I, Craig L. Kennedy, a Licensed Geologist in the State of North Carolina, certify that
this report and its contents have been prepared under my direct control and personal
superv1s10n.
Craig L. Kennedy
NC 1614
80396913.01 Feb2002GW _Rpt.doc(03/14/02) 11
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TABLE OF CONTENTS
C 'fj . p .. ert1 1catlon age ................................................................................................................ u
List of Figures·.: .................................................................................................................. iv
List of Tables ...................................................................................................................... v
I 1.0 INTRODUCTION ........................................................................................................... 1-1
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2. 0 FIELD METHODS .......................................................................................................... 2-1
3.0 RESULTS ........................................................................................................................ 3-1
3.1 Water Level Measurements ................................................................................. 3-1
3.2 Analytical Results ................................................................................................ 3-1
APPENDIX A GROUNDWATER SAMPLING ANALYTICAL REPORTS
80396913.01 Feb2002GW _Rpt.doc(03/14/02) 111
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1-1
2-1
3-1
3-2
3-3
LIST OF FIGURES
Topographic Map, Hamilton Beach<> Proctor-Silex, Inc.
Site Map, Washington Facility, Hamilton Beach<> Proctor-Silex, Inc.
Generalized Groundwater Flow Direction for Hydro geologic Unit A,
Washington Facility
Generalized Groundwater Flow Direction for Hydro geologic Unit B,
Washington Facility
Location of Surrounding Water Supply Wells
80396913.01 Feb2002GW _Rpt.doc(03/l 4/02) iv
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LIST OF TABLES
2-1 Monitoring Well Construction Data for Sampled We~ls
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
3-1 Water Level Measurements and Elevations, February 12, 2002
Hamilton Beach<> Proctor-Silex, Inc., Washington, North Carolina
3-2 Historical Water Level Elevations at MW-220
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
3-3 Historical Water Level Elevations at MW-222
Hamilton Beach<> Proctor-Silex, Inc., Washington, North Carolina
3-4 Historical Water Level Elevations at MW-224
Hamilton Beach<> Proctor-Silex, Inc., Washington, North Carolina
3-5 Historical Water Level Elevations at MW-225
Hamilton Beach<> Proctor-Silex, Inc., Washington, North Carolina
3-6 Historical Water Level Elevations at MW-226
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
3-7 Historical Water Level Elevations at MW-230
Hamilton Beach<> Proctor-Silex, Inc., Washington, North Carolina
3-8 Historical Water Level Elevations at MW-234
Hamilton Beach<> Proctor-Silex, Inc., Washington, North Carolina
3-9 Field Measurements, February 12, 2002
Hamilton Beach<> Proctor-Silex, Inc., Washington, North Carolina
3-10 Summary of Qualified Groundwater Analytical Results: February 2002
Volatile Organic Compounds by Method 8260B
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
3-11 Historical Analytical Results for MW-220
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
3-12 Historical Analytical Results for MW-222
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
3-13 Historical Analytical Results for MW-224
Hamilton Beach<> Proctor-Silex, Inc., Washington, North Carolina
80396913.01 Feb2002GW _Rptdoc(03/14/02) v
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LIST OF TABLES (Continued)
3-14 Historical Analytical Results for MW-225 .
Hamilton Beach<> Proctor-Silex, Inc., Washington, North Carolina
3-15 Historical Analytical Results for MW-226
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
3-16 Historical Analytical Results for MW-230
Hamilton Beach<> Proctor-Silex, Inc., Washington, North Carolina
3-17 Historical Analytical Results for MW-234
Hamilton Beach<> Proctor-Silex, Inc., Washington, North Carolina
80396913.01 Feb2002GW _Rpt.doc(03/14/02) VI
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1.0 INTRODUCTION
The Hamilton Beach<> Proctor-Silex (HB<>PS). facility is located at 234 Springs
Road, north of the City of Washington, in Beaufort County, North Carolina (Figure 1-1). The
facility and surrounding land parcel are owned by the City of Washington and have been leased
by HB<>PS since 1990 and previously leased by predecessor companies. The facility was
formerly involved in the final assembly, packaging, and warehousing of small electrical
household appliances.
Since 1992, when organic compounds were initially detected in groundwater at
the site, several phases of investigation have been performed, including a comprehensive site
assessment (CSA). The results of the CSA indicated that a plume of organic compounds is
present in groundwater underlying the site. The specific nature, volume, and time period of any
releases contributing to the plume are unknown. However, the principal constituents of the
plume are no longer used at the facility.
A plan for corrective action at the site has been proposed. Until corrective action
is implemented, groundwater will be sampled and analyzed on a quarterly schedule according to
a monitoring program requested by the North Carolina Department of Environment and Natural
Resources, Groundwater Section. Quarterly groundwater monitoring is being conducted in
February, May, August, and November at seven wells: MW-220, -222, -224, -225, -226, -230,
and-234. These monitoring wells are located outside of the contaminant plume. In August, six
additional wells: MW-213, -214, -215, -216, -227, and -228 are sampled. These wells are
located within the contaminant plume. The purpose of the monitoring program is to detect
potential migration of the plume.
URS Corporation (URS) conducted groundwater sampling at the facility on
February 12, 2002. The sampling event included the measurement of water levels, temperature,
pH, and specific conductance; and the collection and analysis of samples from seven monitoring
wells. Water levels were measured in ten additional wells. This report describes the sampling
methods and presents the results for the quarterly sampling event.
80396913.01 Feb2002GW _Rpt.doc(03/14/02) 1-1
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2.0 FIELD METHODS
Groundwater was sampled on February 12, 2Q02 in general accordance with the
methods outlined in the_Field Sampling and Analysis Plan prepared in April 1997 for this site.
Seven monitoring wells were sampled. They included MW-220, MW-222,
MW-224, MW-225, MW-226, MW-230, and MW-234. The locations of the monitoring wells
are shown in Figure 2-1. Details of well construction are provided in Table 2-1.
Prior to sampling, the water level in each well was measured using an electric
water-level indicator. The wells were then purged using inertial foot-valve pumps. Temperature
and specific conductance were measured and the data were recorded in a field notebook. Due to
equipment malfunction, pH was not measured during this sampling event. Purging continued
until temperature, and specific conductance stabilized; a minimum of three well volumes was
extracted; or the well was pumped dry. Each of the wells was then sampled immediately
following well purging using the inertial foot-valve pump. For QNQC purposes, a duplicate
sample was collected at well MW-226.
The groundwater samples were sent by overnight courier to STL in Austin, Texas,
for analysis of volatile organic compounds by EPA Method 8260B.
80396913.01 Feb2002GW _Rpt.doc(03/14/02) 2-1
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3.0 RESULTS
3.1 Water Level Measurements
Table 3-1 presents the depth to groundwater and static water-level elevations
measured in the seven wells sampled, and in ten additional monitoring wells. Maps showing the
generalized direction of groundwater flow in hydrogeologic units A and B are included as
Figures 3-1 and 3-2, respectively. Historical water-level elevations in sampled wells are
included in Tables 3-2 to 3-8.
3.2 Analytical Results
Field measurements of water temperature and specific conductance are
summarized in Table 3-9. Qualified analytical results are summarized in Table 3-10. Qualified
data sheets and laboratory reports are included in Appendix A.
No analytes were detected above the groundwater standards in samples from
wells located near the perimeter of the site (MW-220, MW-222, MW-224, MW-225, MW-230,
and MW-234), nor were any analytes detected above the groundwater standards in the sample
from well MW-226, which is completed in the confined Limestone Aquifer.
Historical analytical results for the sampled wells are presented in Tables 3-17
to 3-23. A comparison of the record for wells located near the perimeter of the site suggests that
the plume remains on-site. Locations of surrounding water-supply wells are shown in
Figure 3-3.
80396913.01 Feb2002GW _Rptdoc(03/14/02) 3-1
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I FIGURES
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TABLES
-------------------
Table 2-1
Monitoring Well Construction Data for Sampled Wells
Hamilton Beach¢Proctor-Silex, Inc.
Washington, North Carolina
Top of Casing
Jµstallatipµ Elevation Total Depth Screen Interval
Well No. Date (ft. above MSL) (ft. be;s) (ft. bgs)
MW-220 5/5/98 31.50 34 25 -34
MW-222 5/6/98 35.11 40 31 -40
MW-224 11/13/98 33.43 34 25 -34
MW-225 11113/98 33.43 10 4-10
MW-226 9/30/98 28.46 75 70-75
MW-230 10/26/98 33.47 14 8 -14
MW-234 6/23/99 35.03 26 17 -26
Monitoring wells 220 and 222 installed by Radian Mobile Field Services.
Monitoring wells 226 was installed by Parratt Wolff, Inc.
Monitoring wells 224, 225, 230, and 234 installed by Probe Technology, Inc.
80396913.01 Feb2002GW_Rpt.doc (03/14/02)
Filter Pack
(ft. bgs)
24-34
30-40
24-34
3 -10
69-75
7 -14
16-26
Rentonite Seal Grout Seal
(ft. bf!s) (ft. bf!S)
23 -24 o D 23
29-30 0-29
23 -24 0-23
2-3 0-2
67 -69 0-67
5-7 0-5
13 -16 0-13
Well
MW-2018
MW-213
MW-214
MW-216
MW-217
MW-220
MW-221
MW-222
MW-223
MW-224
MW-225
MW-226
MW-227
MW-228
MW-230
MW-233
MW-234
msl = mean sea level
Table 3-1
Water Level Measurements and Elevations
February 12, 2002 .
Hamilton Beach¢Proctor-Silex, Inc.
Washington, North Carolina
Measuring Point
Elevation Water Level Elevation
(ft above msl)) Deoth to Water (ft) (ft above msl)
29.74 1.49 28.25
28.44 4.07 24.37
27.93 4.78 23.15
32.82 9.10 23.72
32.75 7.49 25.26
31.50 9.07 22.43
31.39 8.47 22.92
35.11 14.27 20.84
35.15 3.20 31.95
33.43 7.80 25.63
33.43 6.95 26.48
28.46 19.58 8.88
28.47 5.11 23.36
28.71 4.17 24.54
33.47 11.31 22.16
34.55 11.20 23.35
35.03 8.69 26.34
80396913.01 Feb2002GW _ Rptdoc(03/l 4/02)
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Table 3-2
Historical Water Level Elevations at MW-220
Hamilton Beach¢ Proctor-Sile~, Inc.
Washington, North Carolina
Water Level Elevation
Date (ft. above msl)
May 13, 1998 25.13
November 16, 1998 20.55
July 1, 1999 21.50
October 20, 1999 25.63
Februarv 2, 2000 25.85
May2, 2000 25.81
September 6, 2000 22.90
November 28, 2000 21.71
February 19, 2001 23.45
May 16, 2001 21.95
August 14, 2001 21.80
November 26, 2001 18.46
February 12, 2002 22.43
msl = mean sea level
80396913.01 Feb2002GW _Rpt.doc (03/14/02)
Table 3-5
Historical Water Level Elevations at MW-225
Hamilton BeachO Proctor-Sile~, Inc.
Washington, North Carolina
Date
Mav 13, 1998
November 16, 1998
July 1, 1999
October 20, 1999
Februarv 2, 2000
May2, 2000
September 6, 2000
November 28, 2000
February 19, 2001
May 16, 2001
August 14, 2001
November 26, 2001
Februarv 12, 2002
msl = mean sea level
NM= Not measured
80396913.01 Feb2002GW _Rptdoc (03/14/02)
Water Level Elevation
(ft. above msl)
NM
24.36
24.50
27.24
26.59
26.40
27.22
24.38
25.01
24.21
24.57
22.55
26.48
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Table 3-6
Historical Water Level Elevations at MW-226
Hamilton Beach¢Proctor-Sile~, Inc.
Washington, North Carolina
Date
May 13, 1998
November 16, 1998
July 1, 1999
October 20, 1999
February 2, 2000
May2, 2000
September 6, 2000
November 28, 2000
February 19, 2001
May 16, 2001
August 14, 2001
November 26, 2001
February 12, 2002
msl = mean sea level
NM= Not measured
80396913.01 Feb2002GW _Rpt.doc (03/14/02)
Water Level Elevation
(ft. above msl)
NM
8.43
8.54
11.11
10.23
10.81
9.41
9.19
9.20
9.31
8.71
8.04
8.88
\
Table 3-7
Historical Water Level Elevations at MW-230
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Date
May 13, 1998
November 16, 1998
July 1, 1999
October 20, 1999
February 2, 2000
Mav2, 2000
September 6, 2000
November 28, 2000
Februarv 19, 2001
May 16, 2001
August 14, 2001
November 26, 2001
Februarv 12, 2002
msl = mean sea level
NM= Not measured
80396913.01 Feb2002GW _Rptdoc (03/14/02)
Water Level Elevation
(ft. above msl)
NM
21.14
21.80
27.71
27.44
26.53
23.07
21.87
23.17
22.17
22.20
18.89
22.16
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Table 3-8
Historical Water Level Elevations at MW-234
Hamilton BeachOProctor-Sile~, Inc.
Washington, North Carolina
Date
May 13, 1998
November 16, 1998
July 1, 1999
October 20, 1999
February 2, 2000
May2, 2000
September 6, 2000
November 28, 2000
Februarv 19, 2001
May 16, 2001
August 14, 2001
November 26, 2001
Februarv 12, 2002
iµsl = mean sea level
NM = Not measured
80396913.01 Feb2002GW _Rpt.doc (03/14/02)
Water Level Elevation
(ft. above msl)
NM
NM
23.24
25.71
25.67
25.56
25.04
23.23
24.20
23.53
23.94
21.29
26.34
Well Date Time
MW-220 02/12/02 14:10
MW-222 02/12/02 15:15
MW-224 02112/02 14:30
MW-225 02/12/02 14:22
13:25
MW-226 02/12/02 13:30
13:35
13:45
MW-230 02/12/02 11:55
MW-234 02/12/02 14:55
Table 3-9
Field Measurements
February 12, 2002
Hamilton Beach¢Proctor-Silex, Inc.
Washington, North Carolina
Volume Purged
(Gal) Pure:ine: Criteria
0.75 3 well volumes
0.75 3 well volumes
0.75 3 well volumes
0.01 Dry
8.0
10.0 Stabilized parameters
12.0
14.0
0.1 3 well volumes
0.5 3 well volumes
NM =Not measured, pH was not measured due to equipment malfunction.
80396913.01 Feb2002GW _Rpt.doc (03/14/02)
Specific
Temperature Conductance '
(OC) tuS) DH
17.0 85 NM
17.5 350 NM
17.0 290 NM
19.0 110 NM
18.5 435 NM
18.5 450 NM
18.5 450 NM
18.5 450 NM
25.0 75 NM
17.0 130 NM
-------------------
-----~-------------
Table 3-10
Summary of Qualified Groundwater Analytical Results: February 2002
Volatile Organic Compounds by Method 8260B
Hamilton BeachOProctor-Silex, Washington, North Carolina
Sample ID MW-22Q
Date of Sampling 2112/2002
..
Analyte (µg/L)
Carbon Disulfide ND (0.0415)
1,1-Dichloroethane 0.607
Target analytes not listed were not detected.
Bold values exceed Standards.
MW-222
2/12/2002
ND (0.0415)
ND (0.0445)
ND ( ) =Not detected at specified detection limit.
J = Estimated value.
80396913.01 Feb2002GW _Rptdoc (03/14/02)
MW-224 MW-225 MW-226
2/12/2002 2/12/2002 2/12/2002
0.640 J ND (0.0415) ND(0.0415)
ND (0.0445) ND (0.0445) ND (0.0445)
MW-230
2/12/2002
ND (0.0415)
ND (0.0445)
MW-234
2/12/2002
ND (0.0415)
ND (0.0445)
Groundwater May
Analyte Standard 1998
Carbon disulfide 700 ND (0.0547)
1, 1-Dichloroethane 700 ND (0.0576)
Methyl t-butyl ether 200 ND (0.0365)
Groundwater November
Analvte Standard 2000
Carbon disulfide 700 ND (0.0684)
1, 1-Dichloroethane 700 0.426J
Methyl t-butyl ether 200 ND (0.116)
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
J = Estimated value.
ND= Not detected at (detection limit).
Table 3-11
Historical Analytical Results for MW-220
Hamilton Beach¢Proctor-Silex, Inc.
Washington, North Carolina
November July October
1998 1999 1999
ND (0.0547) 0.426 J 0.162
ND (0.0576) ND (0.0736) ND (0.0588)
ND (0.0365) UJ ND (0.0334) ND (0.0512)
February May August
2001 2001 2001
ND (0.0684) UJ ND (0.0684) ND (0.0684) UJ
0.456 J ND (0.124) 0.530
ND (0.116) ND (0.116) ND (0.116)
UJ = Not detected and the detection limit is estimated.
80396913.01 Feb2002GW _Rpt.doc (03/14/02)
February May Septerµber
2000 2000 ' 2000
ND (0.0484) UJ ND (0.0484) ND (0.0484)UJ
ND (0.0487) ND (0.0487) ND(0.0487)
ND (0.0469) 0.441 J ND (0.0469)
November February
2001 2002
ND (0.0415) ND (0.0415)
0.550 0.607
ND (0.0619) ND (0.0619)
-------------------
-------------------
(;roundwa~e_r
Analvte Standard
Carbon disulfide 700
1, 1-Dichloroethane 700
1, 1-Dichloroethene 7
cis-1,2-Dichloroethene 70
Toluene 1,000
Groundwater
Analyte Standard
Carbon disulfide 700
1, 1-Dichloroethane 700
1, 1-Dichloroethene 7
cis-1,2-Dichloroethene 70
Toluene 1,000
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
J = Estimated value.
ND= Not detected at (detection limit).
Table 3-12
Historical Analytical Results for MW-222
Hamilton Beach¢Proctor-Silex, Inc.
Washington, North Carolina
May November July October
1998 1998 1999 1999
ND (0.0547) ND (0.0547) 0.388 J 0.0944
ND (0.0576) ND (0.0576) ND (0.0736) ND (0.0588)
0.0908 J ND (0.0715) ND (0.102) ND (0.0819)
ND (0.0383) ND(0.223)U ND (0.0595) ND (0.0407)
0.156 J ND (0.0522) ND (0.0766) ND (0.0645)
November February May August
2000 2001 2001 2()01
ND (0.0684) ND (0.0684) UJ ND (0.0684) ND (0.0684) UJ
ND (0.124) 0.589 0.536 ND (0.124)
0.0668 J 0.102 J 0.0793 J ND (0.122)
0.124 J 0.222 J 0.260 J 0.157 J
ND (0.137) ND (0.0637) ND (0.0637) ND (0.0637)
UJ =Not detected and the detection limit is estimated.
U =Not present above the associated level, blank contamination present.
80396913.01 Feb2002GW_Rpt.doc (03/14/02)
February May September 2000 2000. 2000
ND (0.0484) UJ ND (0.0484) ND (0.0484) UJ
ND (0.0487) 0.338 J 0.328 J
ND (0.0697) ND (0.279)U 0.0766 J
ND (0.0603) ND (0.0603) 0.139 J
ND (0.0680) ND (0.0680) ND (0.0680)
November February
2001 2002
ND (0.0415) ND (0.0415)
0.375 J ND (0.0445)
0.130 J ND (0.0492)
0.126 J ND (0.0353)
ND (0.0236) ND (0.0236)
Table 3-13
Historical Analytical Results for MW-224
Hamilton Beach¢Proctor-Silex, Inc.
Groundwater November
Analyte Standard 1998
Carbon disulfide 700 ND (0.0547)
Toluene 1,000 ND (0.0522)
Groundwater February
Analvte Standard 2001
Carbon disulfide 700 ND (0.571) UJ
Toluene 1,000 ND (0.0637)
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
J = Estimated value.
ND= Not detected at (detection limit).
UJ =Not detected and the detection limit is estimated.
80396913.01 Feb2002GW_Rpt.doc (03/14/02)
Washington, North Carolina
July October February
1999 1999 2000
2.22 2.72 ND (l.05)UJ
ND (0.0766) ND (0.0645) ND (0.0680)
May August November
2001 2001 2001
0.715 J 0.515 J 0.531 J
ND (0.0637) ND (0.0637) ND (0.0236)
May September November
2000 2000 2000
ND (0.334) U 0.350 J 0.697 J
0.0542 J ND (0.0680) ND (0.0637)
February
2002
0.640J
ND (0.0236)
- - --·-·--·-·-- -·-- - - -·-·--
-------------------
Table 3-14
Historical Analytical Results for MW-225
Hamilton BeachOProctor-Silex, Inc.
Groundwat~r November
Analvte Standard 1998
Carbon disulfide 700 ND (0.0547)
Chloroform 0.19 ND (0.0480)
Groundwater February
Analvte Standard 2001
Carbon disulfide 700 ND (0.511) UJ
Chloroform 0.19 ND (0.0896)
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
ND = Not detected at (detection limit).
UJ =Not detected and the detection limit is estimated.
80396913.01 Feb2002GW_Rpt.doc (03/14/02)
Washington, North Carolina
July October February
1999 1999 2000
ND (0.864) 0.0691 ND (0.0484) UJ
ND (0.0424) 0.171 ND (0.0670)
May August November
2001 2001 2001
ND(0.0684) ND (0.0684) ND (0.0415)
ND (0.0896) ND (0.0896) ND (0.0338)
September Noveipbei;
May2000 2000 2000
ND (0.0484) ND (0.0484) UJ · ND (0.0684)
ND (0.0670) ND (0.0670) ND (0.0896)
February
2002
ND (0.0415)
ND (0.0338)
Groundwater November
Analyte Standard 1998
Carbon disulfide 700 ND (0.0547)
Groundwater February
Analvte Standard 2001
Table 3-15
Historical Analytical Results for MW-226
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
July October February
1999 1999 2000
ND (0.864) 0.0950 ND (0.0484) UJ
May August November
2001 2001 2001
Carbon disulfide 700 ND (0.0684) UJ ND (0.0684) ND (0.0684) UJ ND (0.0415)
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
J = Estimated value.
ND= Not detected at (detection limit).
UJ =Not detected and the detection limit is estimated.
80396913.01 Feb2002GW _Rpt.doc (03/14/02)
May September November
2000 2000 2000
ND (0.0484) UJ 0.210 J ND (0.0684)
February
2002
ND (0.0415)
-------------------
-------------------
Gro.un<hv~ter
Analyte Standard
1, 1-Dichloroethane 700
1, 1-Dichloroethene 7
Cis-1,2-Dichloroethene 70
Methyl methacrylate PQL
Toluene 1,000
Trichloroethene 2.8
Groundwater
Analyte Standard
1, 1-Dichloroethane 700
1, 1-Dichloroethene 7
Cis-1,2-Dichloroethene 70
Methvlmethacrvlate POL
Toluene 1,000
Trichloroethene 2.8
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
J = Estimated value.
ND = Not detected at (detection limit).
Table 3-16
Historical Analytical Results for MW-230
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
November July October February
1998 1999 1999 2000
ND (0.0576) ND (0.0736) 0.265 0.189 J
ND (0.306)U ND (0.102) 0.133 0.148 J
ND(2.67)U ND (0.0595) 0.304 0.354 J
ND (0.130) ND (0.156) ND (0.0916) ND (0.114)
ND (0.0522) 0.286 ND (0.309)U 0.284 J
ND(2.05) U ND (0.0929) 0.921 0.661 J
February May August November
2001 2001 2001 2001
ND (0.124) ND (0.124) ND (0.124) ND (0.0445)
ND (0.122) ND (0.122) ND (0.122) ND (0.0492)
0.0969 J 0.288 J 0.119 J ND (0.0353)
ND (0.131) ND (0.131) ND(0.131) 0.148 J
ND (0.0637) ND (0.0637) ND (0.0637) ND (0.0236)
0.160 J 0.292 J 0.140 J ND (0.0506)
U = Not present above the associated level; blank contamination is present.
80396913.01 Feb2002GW_Rpt.doc (03/14/02)
May September November
2000 2000 2000
ND (0.348) U ND (0.0487) ND (0.124)
0.593 N.D (0.0697) ND (0.122)
0.573 0.102 J 0.142 J
ND (0.114) UJ ND (0.114) ND (0.131)
0.0826 J 0.126 J ND (0.0637)
1.11 ND (0.355)U 0.235 J
February
2002
ND (0.0445)
ND (0.0492)
ND (0.0353)
ND(0.175)
ND (0.0236)
ND (0.0506)
Table 3-17
Historical Analytical Results for MW-234
Hamilton BeacbOProctor-Silex, Inc.
Washington, North Carolina
Groundwater July October February
Analvte Standard 1999 1999 2000
Carbon disulfide 700 ND (0.864) 0.0600 ND (0.0484) UJ
1, 1-Dichloroethene 7 ND (0.102) ND (0.0819) ND (0.0697)
Groundwater February May August
Analvte Standard 2001 2001 2001
Carbon disulfide 700 ND (0.0684) UJ ND (0.0684) ND (0.0684)
1, 1-Dichloroethene 7 ND (0.122)
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
J = Estimated value.
ND =Not detected at (detection limit).
UJ =Not detected and the detection limit is estimated.
80396913.01 Feb2002GW _Rpt.doc (03/14/02)
ND (0.122) ND (0.122)
May
2000
ND <0.0484)
0.145 J
November
2001
ND (0.0415)
ND-(0.0492)
September November
2000 2000
ND (0.0484) UJ ND (0.0684)
ND (0.0697) ND (0.122)
February
2002
ND (0.0415)
ND -(0.0492)
-------------------
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APPENDIX A
GROUNDWATER SAMPLING ANALYTICAL REPORTS
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QUALIFIED DATA
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Introduction
Hamilton Beach<>Proctor-Silex, Washington, NC
Data Evaluation Report
URS Corporation, March 2002
URS Corporation (URS) collected eight groundwater samples (0202HBWW-220, -222, -224 through
-226, -230, and -234) and a field duplicate at the Hamilton Beach<> Proctor Silex facility in Washington,
NC on February 12, 2002. The samples were submitted to Severn Trent Laboratories (STL) in Austin,
Texas for the determination of volatile organic compounds (VOC) by SW-846 Method 8260B. A trip
blank was included with the shipment of samples to the laboratory for the analysis of voe.
URS reviewed the analytical results, which were reported by the laboratory under work order number
20202098. The data evaluation was modeled after the National Functional Guidelines for Organic Data
Review (EPA, October 1999). Qualitative and quantitative limitations associated with the analytical
results were identified and defined based on the results of specific quality control (QC) criteria. Accuracy
was determined from the review of spike recoveries. Precision was based on the evaluation of laboratory
duplicate results. Sensitivity was evaluated by comparing reported detection limits to project-specific
maximum reporting limits. Representativeness was evaluated from the review of holding time and blank
data. Sample results have been qualified based on the results of the data review process, as described
below.
Sample Condition upon Receipt and Holding Times
All samples were received intact and in good condition by STL on February 13, 2002. The temperature
(2.3°C) of the sample containers upon receipt at the laboratory was within laboratory specification limits
of 1-4°C. Air bubbles were not observed in any volatile organic analysis (VOA) vials.
Technical hold times were assessed by comparing the sampling dates with that of the analysis date.
Samples were analyzed for VOC within EPA-established holding times of seven days for unpreserved
samples.
Calibration
Gas chromatograph/mass spectrometer (GC/MS) instrument tuning and performance checks are
performed to ensure the instrument's ability to provide appropriate mass-resolution, identification, and
sensitivity. All samples were analyzed for VOC within twelve hours of the performance check standard.
The tuning compound mass-ion abundance criteria for the VOA were reported within control limits.
Control limits for initial and continuing calibrations are established to ensure that the instrument is
capable of producing accurate quantitative and qualitative data at the beginning and throughout each of
the analyses. Since the results of the initial calibration were not included in the laboratory report, the
evaluation was based on the review of the continuing calibration data. Laboratory specifications were
met during all volatile organic continuing calibrations conducted on instrument MSDA. In addition, the
0202 HB-PS Wash DE.doc
Page I of3
03/06/02
recovery for all target analytes, except those noted below associated with sample analyses, fell within
80-120% of the continuing calibration standard's true value.
• 02/18/02 @11:08 on instrument MSDA-acetone (63%), trichlorofluoromethane (127%)
Results for compounds where the recovery was less than 80% during the continuing calibration have been
qualified as estimated (J, UJ) in associated samples. Positive sample results were qualified as estimated
(J) when the recovery exceeded 120% in the continuing calibration.
Laboratory Control Samples
Laboratory control samples (LCS) are blank samples fortified (spiked) with known concentrations of
analyte of interest. The percent recoveries and/or duplicate results of the LCS and their duplicates are
used to assess extraction efficiencies and overall analytical accuracy and precision.
Laboratory specifications were met during the LCS analysis of February 18, 2002; however, project1
specifications were not met for vinyl acetate. LCS and LCSD recoveries for vinyl acetate (18 and 20%)
were less than project sp~cification limits but within laboratory specifications (0 .1-164 % ) . Non-detect
sample results for vinyl acetate were qualified as unusable (R) because of poor purging efficiency.
Blank Contamination
Laboratory blanks are clean liquid and/or solid matrix samples prepared by the analytical laboratory and
analyzed in the same manner as the field samples. Laboratory blanks are used to ensure that the field
samples are not contaminated during the sample preparation, sample analysis, or from previous samples
(instrument carry-over). Trip blanks are analyte-free water samples that accompany volatile investigative
samples during all stages of shipment, storage, and analysis. The trip blanks are used to assess the
potential for artificial introduction of volatile compounds into the investigative samples during the
transportation and sample handling processes.
Methylene chloride, a common laboratory blank contaminant, was detected below the practical
quantitation limit in the trip blank at a concentration of 0.175 micrograms per liter (µg/L). VOC were not
detected in the method blank. Qualification of the data is not required since methylene chloride was not
detected in any sample.
Surrogate Spikes
Surrogate compound percent recoveries are used to assess extraction efficiencies, possible matrix effects,
and overall analytical accuracy during organic analyses. Acceptable sample results were obtained for the
surrogate spikes during the VOA of all samples.
1 The recovery of either the LCS or LCSD must be within 60-140%.
0202 HB-PS Wash DE.doc
Page 2 of3
03106102
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Matrix Spikes
Matrix spikes (MS) are samples spiked with known concentrations of analytes of interest. MS percent
recoveries and duplicate results are used to assess extraction efficiencies, possible matrix effects, and
overall analytical accuracy and precision.
Matrix interference was observed during the MS analysis of sample 0202HBWW230 for VOC. MS
recoveries and RPD did not meet laboratory control limits for the following target analytes:
• n-Butyl benzene -47%RPD (<30)
• sec-Butyl benzene -41 %RPD ( <31)
• tert-Butyl benzene -32%RPD (<27)
• 1-Chlorohexane-29%RPD (<25)
• 1,4-Dichlorobenzene -17%RPD (<13)
• 1,2-Dichlorobenzene-16%RPD (<14)
• l,3-Dichlorobenzene-19 %RPD (<14)
• Hexachloro-1,3-budadiene-42%R (46-150), 59%RPD (<34)
• 4-Isopropyl toluene-40%RPD (<28)
• Naphthalene-29%RPD (<22)
• l,2,3-Trichlorobenzene-50%R (66-140), 48%RPD (<20)
• 1,2,4-Trichlorobenzene -53%R (66-144), 46%RPD (<22)
• l,3,5-Trimethylbenzene-27%RPD (<25)
Non-detected results for the above-mentioned analytes have been qualified as estimated (UJ) because of
matrix interference.
Field Duplicates
Field duplicate samples are used to demonstrate acceptable precision during the sample collection
process. Acceptable precision was observed during the analysis of field duplicate samples
0202HBWW226 and 0202HBWWD999.
Sample Results
The laboratory provided volatile organic results for all North Carolina groundwater quality standards
presented in 15A NCAC 2L.0202. Detection limits were less than or equal to Class GA standard or
practical quantitation limits.
The laboratory flagged sample results less than the practical quantitation limit and sample detection limit
with a J and U, respectively. All positive sample results that are less than the practical quantitation limit
are considered estimated (J).
0202 HB-PS Wash DE.doc
Page 3 of3
03/06/02
-------------------SECTION IV
Analytical Results
MS-VOA
SW8260B
Parameter
Acetone
Acetonitrile
Acrolein
Acl}'lonitriie
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone <MEK)
n-Butvlbenzene
sec-Butvlbenzene
tert-Butvlbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1.3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
DatefTime Collected
DatefTime Prepared
DatefTime Analyzed
Dilution Factor
Instrument
Units
CAS, ,.
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
SECTION IV -Analytical Results -02/24/2002 18:08
0202HBWD999
2020209803
Aqueous
Received
NA
02/12/2002 13:55
02/18/2002 15:22
02118/2002 15:22
1.0000
MSDA
ug/L
Cone Flaa
ND 11'--'S .
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396913 [20202098) Hamilton Beach-Proctor Silex
STl. Austin
DL RL
1.26 0.00
5.34 0.00
2.85 0.00
0.290 0.00
0.0465 0.00
0.0643 0.00
0.0449 0.00
0.0528 0.00
0.106 0.00
0.0454 0.00
2.83 0.00
0.0888 0.00
0.104 0.00
0.0934 0.00
0.0415 0.00
0.0553 0.00
0.0596 0.00
0.0404 0.00
0.0755 0.00
0.0338 0.00
0.0798 0.00
0202HBWW220 0202HBWW222
2020209804 2020209808
ACJueous Aqueous
Received Received
NA NA
02/12/2002 14:12 02/12/2002 I 5:20
02/18/2002 IS:5 I 02/18/2002 17:43
02/18/2002 15:51 02/18/2002 17:43
1.0000 1.0000
MSDA MSDA
ug/L ug/L
Cone Flaa DL RL Cone Flag DL
ND lA.":S 1.26 0.00 ND lA:S 1.26
ND 5.34 0.00 ND 5.34
ND 2.85 0.00 ND 2.85
ND 0.290 0.00 ND 0.290
ND 0.0465 0.00 ND 0.0465
ND 0.0643 0.00 ND 0.0643
ND 0.0449 0.00 ND 0.0449
ND 0.0528 0.00 ND 0.0528
ND 0.106 0.00 ND 0.106
ND 0.0454 0.00 ND 0.0454
ND 2.83 0.00 ND 2.83
ND 0.0888 0.00 ND 0.0888
ND 0.104 0.00 ND 0.104
·' ND 0.0934 0.00 ND 0.0934
ND 0.0415 0.00 ND 0.0415
ND 0.0553 0.00 ND 0.0553
ND 0.0596 0.00 ND 0.0596
ND 0.0404 0.00 ND 0.0404
ND 0.0755 0.00 ND 0.0755
ND 0.0338 0.00 ND 0.0338
·ND 0.0798 0.00 ND 0.0798
Page 4
• • 0 •• d· b· d th e ·ulls of the dala review process, which is moJeled aflcr 1/ie Na1io1111/ ri111ctio11a/ G11itleli11es for Organic tllld J11org1111ic D111a Re1•iew <;am 1le re~ulls have bct:n qualified by URS-,... 1an ase on e r 5 ~ ------------------------~-----c ' -
RL
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
of 45
-------------------SECTION IV
Analytical Results
MS-VOA
SW82608·
Client Sample ID
Lab Sample ID
Continued
Parameter CAS
lodomethane 74-88-4
lsopropylbenzene 98-82-8
4-lsopropyltoluene 99-87-6
Methyl methacrvlate 80-62-6
Methyl tert-butvl ether (MTBE) 1634-04-4
4-Methyl-2-nentanone (MIBK) 108-10-1
Methylene chloride 75-09-2
Naphthalene 91-20-3
Propanen itrile 107-12-0
n-Prooylbenzene 103-65-1
Styrene 100-42-5
I I I 2-Tetrachloroethane 630-20-6
I I 2,2-Tetrachloroethane 79-34-5
Tetrachloroethene 127-18-4
Tetrahydrofuran 109-99-9
Toluene 108-88-3
l 2,3-Trichlorobenzene 87-61-6
1.2.4-Trichlorobenzene 120-82-1
1.1. l-Trichloroethane 71-55-6
l 1,2-Trichloroethane 79-00-5
Trichloroethene 79-01-6
Trichlorofluoromethane 75-69-4
l 2 3-Trichloroorooane 96-18-4
I I 2-Trichlorotrifluoroethane 76-13-1
I 2 4-Trimethvlbenzene 95-63-6
I 3 5-Trimethvlbenzene 108-67-8
Vinyl acetate 108-05-4
Vinvl chloride 75-01-4
SECTION IV -Analytical Results -02124/2002 ·18:08
0202HBWD999
2020209803
Cone Flag
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
\ ND
ND
ND
ND
ND
~ R
ND
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
DL RL
0.0452 0.00
0.0769 0.00
0.0899 0.00
0.175 0.00
0.0619 0.00
0.473 0.00
0.0210 0.00
0.0708 0.00
0.652 0.00
0.0698 0.00
0.0295 0.00
0.0578 0.00
0.109 0.00
0.103 0.00
1.28 0.00
0.0236 0.00
0.110 0.00
0.140 0.00
0.0511 0.00
0.0489 0.00
0.0506 0.00
0.0495 0.00
0.117 0.00
0.0529 0.00
0.0744 0.00
0.0616 0.00
Q.l:;i~ 8.GG
0.0501 0.00
0202HBWW220 0202HBWW222
2020209804 2020209808
Cone Flaa DL RL Cone Flag DL
ND 0.0452 0.00 ND 0.0452
ND 0.0769 0.00 ND 0.0769
ND 0.0899 0.00 ND 0.0899
ND 0.175 0.00 ND 0.175
ND 0.0619 0.00 ND 0.0619
ND 0.473 0.00 ND 0.473
ND 0.0210 0.00 ND 0.0210
ND 0.0708 0.00 ND 0.0708
ND 0.652 0.00 ND 0.652
ND 0;0698 0.00 ND 0.0698
ND 0.0295 0.00 ND 0.0295
ND 0.0578 0.00 ND 0.0578
ND 0.109 0.00 ND 0.109
ND 0.103 0.00 ND 0.103
ND 1.28 0.00 ND 1.28
ND 0.0236 0.00 ND 0.0236
ND 0.110 0.00 ND 0.110
ND 0.140 0.00 ND 0.140
ND 0.0511 0.00 ND 0.0511
ND 0.0489 0.00 ND 0.0489
• ND 0.0506 0.00 ND 0.0506
ND 0.0495 0.00 ND 0.0495
ND 0.117 0.00 ND 0.117
ND 0.0529 0.00 ND 0.0529
ND 0.0744 0.00 ND 0.0744
ND 0.0616 0.00 ND 0.0616
N& R o.1n e.ee NB-K O. l+J
ND 0.0501 0.00 ND 0.0501
Page 6
• • .1 b URS Ra·'·. b· s ·d on the resulls uf thc data l'cvicw process, which is modeled after the Nt11io1111/ fi111c1io11a/ G11iile/i11es fur Orgm1ic 1111d lnorg11111c Data Re1•iew <:-rmlt: !C:~lllls ~a\'t: ~c;i:11 <jlj~h!1cu y -u1an a c
RL
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Q.QO
0.00
of 45
-------------------SECTION IV
Analytical Results
Surrogates
MS-VOA
SW8260B
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
Surroaate Comoound · . , .. . . '•,.
l-Bromo-4-fluorobenzene
I .2-Dichloroethane-d4
Toluene-d8
SECTION IV -Analytical Results -02/2412002 18:08
0202HBWD999
2020209803
Aaueous
Received
NA
02/12/2002 13:55
02/18/2002 15:22
02/18/2002 15:22
l.0000
MSDA
ul?/L
0k Recovery
96
103
105
UMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STL Austin
Limits F
77-117
61-143
87-113
0202HBWW220 0202HBWW222
2020209804 2020209808
Aqueous Aaueous
Received Received
NA NA
02/12/2002 14: 12 02/12/2002 15:20
02/18/2002 15:51 02/18/2002 17:43
02/18/2002 15:5 l 02/18/2002 17:43
l.0000 l.0000
MSDA MSDA
ug/L ul?/L
% Recoverv Limits F % Recovery Limits
99 77-117 97 77-117
99 61-143 99 61-143
103 87-113 105 87-113
Page 8
. - . " b· . ·d h. . . It. r the data .-cvicw process, which is modeled alicr the Natiu1111/ J·i111ctio1111/ G11ille/i11es for Orgm1ic m11f /norgmuc IJ11111 Re1·iew Sample results have bccn quahllcd by URS-Radian asc on t c rcsu s u
__ - _ ___ _ __ -_ • ~ "'rl~ • .,~..,I 10],,i
F
of 45
I
SECTION IV
Analytical Results
MS-VOA
SWB260B
Parameter
Acetone
Acetonitrile
Acrolein
Acrvlonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone <MEK)
n-Butylbenzene
sec-Butvlbenzene
tert-Butvlbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1 3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Dateffime Collected
Dateff ime Prepared
Dateffime Analyzed
Dilution Factor
Instrument
Units
CAS
67-64-l
75-05-8
107-02-8
107-13-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
SECTION IV -Analytical Results -02/24/2002 18:08
~---------020211BWW224
2020209805
AtlUCOUS
Received
NA
02/12/2002 14:35
02/18/2002 16: 19
02/18/2002 16:19
1.0000
MSDA
ug/L
Cone Flag
ND IA.:S
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.640 J
ND
ND
ND
ND
ND
ND
I.IMS Workorder: 80396913 [20202098) Hamilton Beach-Proctor Silex
DL RL
1.26 0.00
5.34 0.00
2.85 0.00
0.290 0.00
0.0465 0.00
0.0643 0.00
0.0449 0.00
0.0528 0.00
0.106 0.00
0.0454 0.00
2.83 0.00
0.0888 0.00
0.104 0.00
0.0934 0.00
0.0415 0.00
0.0553 0.00
0.0596 0.00
0.0404 0.00
0.0755 0.00
0.0338 0.00
0.0798 0.00
-·-·---·--·--·--4. -------· -. ·-·--· ----· --·
02021 IBWW_~25 ________________ --·--·-·-~J~!1J.!..!!2 \~W226 _
2020209806 ]!!1!!-2J11!~~2 ·-··· --·-----------------. Aqueous ----·· -. -~~·tlll-". __
Received Rt:cc:i\t:d
NA NA
02/12/2002 14:23 CP'l2'2002 13:50
02/18/2002 16:47 02/18/2002 14:54
02/18/2002 16:47 02/18/2002 14:54
1.0000 1.0000
MSDA MSDA
ug/L ug/L
Cone Flaa DL RL Cone Flaa DL
ND lA-:S 1.26 0.00 ND t.A.3 1.26
ND 5.34 0.00 ND 5.34
ND 2.85 0.00 ND 2.85
ND 0.290 0.00 ND 0.290
ND 0.0465 0.00 ND 0.0465
ND 0.0643 0.00 ND 0.0643
ND 0.0449 0.00 ND 0.0449
ND 0.0528 0.00 ND 0.0528
ND 0.106 0.00 ND 0.106
ND 0.0454 0.00 ND 0.0454
ND 2.83 0.00 ND 2.83
ND 0.0888 0.00 ND 0.0888
ND 0.104 0.00 ND 0.104 . ND 0.0934 0.00 ND 0.0934
ND 0.0415 0.00 ND 0.0415
ND 0.0553 0.00 ND 0.0553
ND 0.0596 0.00 ND 0.0596
ND 0.0404 0.00 ND 0.0404
ND 0.0755 0.00 ND 0.0755
ND 0.0338 0.00 ND 0.0338
ND 0.0798 0.00 ND 0.0798
STL Austin Page 9
-~1tc: i:C!~lllt~ t:i\'~ IJ.:~n 9~alifi~~ ~~ Qk:':'{a~cd ~r~ults ~ata rc--oces~ is n--aftcr~io1111._-01111/ ... nesf11i11711ic ''11irg1111i1'ii1Re1•ie ..
RL
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
of 45 -
--------------SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
Chloromethane
3-Chloroprooene
2-Chlorotoluene
4-Chlorotoluene
Client Sample ID
Lab Sample ID
CAS
74-87-3
107-05-1
95-49-8
106-43-4
I 2-Dibromo-3-chloroorooane 96-12-8
Dibromochloromethane 124-48-1
I 2-Dibromoethane 106-93-4
Dibromomethane 74-95-3
trans-1,4-Dichloro-2-butene 110-57-6
1 4-Dichlorobenzene 106-46-7
I 2-Dichlorobenzene 95-50-1
I 3-Dichlorobenzene 541-73-1
Dichlorodifluoromethane 75-71-8
1.1-Dichloroethane 75-34-3
1,2-Dichloroethane 107-06-2
1.1-Dichloroethene 75-35-4
cis-1,2-Dichloroethene 156-59-2
trans-I 2-Dichloroethene 156-60-5
1,2-Dichloroorooane 78-87-5
L3-Dichloronronane 142-28-9
2,2-Dichloroorooane 594-20-7
I 1-Dichloroorooene 563-58-6
cis-1 3-Dichloroorooene 10061-01-5
trans-l,3-Dichloronrooene 10061-02-6
Ethvl methacrvlate 97-63-2
Ethyl benzene 100-41-4
Hexachloro-1.3-butadiene 87-68-3
2-Hexanone 591-78-6
SECTION IV -Analytical Results -02/24/2002 18:08
0202HBWW224
2020209805
': ·~: . ·cone Flag
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396913 [20202098) Hamilton Beach-Proctor Silex
STL Austin
0202HBWW225
2020209806
DL RL Cone Flag DL RL
0.0509 0.00 ND 0.0509 0.00
0.0785 0.00 ND 0.0785 0.00
0.0359 0.00 ND 0.0359 0.00
0.0684 0.00 ND 0.0684 0.00
0.777 0.00 ND 0.777 0.00
0.0946 0.00 ND 0.0946 0.00
0.0895 0.00 ND 0.0895 0.00
0.0550 0.00 ND 0.0550 0.00
0.0596 0.00 ND 0.0596 0.00
0.0495 0.00 ND 0.0495 0.00
0.0596 0.00 ND 0.0596 0.00
0.0591 0.00 ND 0.0591 0.00
0.0930 0.00 ND 0.0930 0.00
0.0445 0.00 ND 0.0445 0.00
0.0632 0.00 ND 0.0632 0.00
0.0492 0.00 ND 0.0492 0.00
0.0353 0.00 ND 0.0353 0.00
0.0430 0.00 ND 0.0430 0.00
0.0519 0.00 ND 0.0519 0.00
0.0401 0.00 ND 0.0401 0.00
0.0492 0.00 , ND 0.0492 0.00
0.0374 0.00 ND 0.0374 0.00
0.0526 0.00 ND 0.0526 0.00
0.0486 0.00 ND 0.0486 0.00
0.0822 0.00 ND 0.0822 0.00
0.0469 0.00 ND 0.0469 0.00
0.155 0.00 ND 0.155 0.00
0.838 0.00 ND 0.838 0.00
- - - - -
0202HBWW226
2020209802
Cone Flag DL RL
ND 0.0509 0.00
ND 0.0785 0.00
ND 0.0359 0.00
ND 0.0684 0.00
ND 0.777 0.00
ND -0.0946 0.00
ND 0.0895 0.00
ND 0.0550 0.00
ND 0.0596 0.00
ND 0.0495 0.00
ND 0.0596 0.00
ND 0.0591 0.00
ND 0.0930 0.00
ND 0.0445 0.00
ND 0.0632 0.00
ND 0.0492 0.00
ND 0.0353 0.00
ND 0.0430 0.00
ND 0.0519 0.00
ND 0.0401 0.00
ND 0.0492 0.00
ND 0.0374 0.00
ND 0.0526 0.00
ND 0.0486 0.00
ND 0.0822 0.00
ND 0.0469 0.00
ND 0.155 0.00
ND 0.838 0.00
Page 10 of 45
I b I. 1-d b LJRS Rad'iari based on the results of the data 1cvicw process which is modeled a tier th£' N111iv1wl l-imc1io11a/ ll11ideli11es fur Orgm1ic 111111 lnurg1111ic l>111a Re1•iew Sample 1esu ts have ccn qua 1 1c y • •
~------~--r-"" ~ II
- - - - ------------- - -SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
p-Xv lene/m-X vlene
o-Xvlene
Client Sample ID
Lab Sample ID
CAS
106-42-3
95-47-6
SECTION IV -Analytical Results -02/24/2002 18:08
0202HBWW2?4
2020209805
Cone Flaa
ND
ND
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
DL RL
0.0869 0.00
0.0409 0.00
0202HBWW225 . .!>2021 l!}_W~W'.!.:::c?_2:;:e6:'.__ _______ I
--~!11!~2l)l~Q2 -----------' 20?0209806
Cone Flaa DL RL Cone Flaa DL RL
ND 0.0869 0.00 ND 0.0869 0.00
ND 0.0409 0.00 ND 0.0409 0.00
Page I2 STLAustin . .
. . S R· d" b· . ·do the results of the data review process, which is modeled after tlw Natiomii Fi111ctio11al Guitlelines fur Organic and lnorg11mc D111a Rei•iew Sample results have bcc:n qualified by UR • a 1an asc n
of 45
~-~ ~---~ ---.... n ,.,.,,), -... ~ ......... ~ ... I \
SECTION IV
Analytical Results
Surrogates
MS-VOA
SW8260B
Surrogate Comoound
l-Bromo-4-fluorobenzene
I 2-Dichloroethane-d4
Toluene-dB
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
SECTION IV· Analytical Results· 0212412002 18:08
0202HBWW224
2020209805
Aqueous
Received
NA
02112/2002 14:35
02118/2002 16: 19
02/18/2002 16:19
1.0000
MSDA
ug/L
% Recovery
99
102
105
LIMS Workorder: 80396913 [20202098) Hamilton Beach-Proctor Silex
STLAustin
Limits F
77-117
61-143
87-113
0202HBWW225 0202HBWW226
2020209806 2020209802
Aqueous Aqueous
Received Received
NA NA
02/12/2002 14:23 02/12/2002 13:50
02/ 18/2002 16 :4 7 02/18/2002 14:54
02/18/2002 16:47 02/18/2002 14:54
1.0000 1.0000
MSDA MSDA
ug/L ug/L
% Recoverv Limits F % Recoverv Limits
97 77-117 98 77-117
103 61-143 103 61-143
104 87-113 104 87-113
Page 13 --.. -· -Rad .. d -II • .-1a rc~ess .. is ~ftcr ~01111/ ~ma/ <iMillldi/lesfo~11ic atJJi..!!!Jll:gcmic D11ta Re,•iew ~lere vebc...,_dicd · on us..._. ._--- - - - - - - -_ ~ -~ _,.... _ "--~ nrnn _ ~ n 1r_:!~' .,,~, 11C"1tt 1r•1;"1~1•1 .. 11fi~~~I~·'
F
of 45 -
-------------------SECTION IV
Analytical Results
MS-VOA
SW8260B
Parameter
Acetone
Acetonitrile
Acrolein
Aci:ylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
n-Butvlbenzene
sec-Butvlbenzene
tert-Butvlbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1.3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-i =chlorohexane
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
CAS
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
SECTION IV· Analytical Results -02/24/2002 18:08
0202HBWW230
2020209801
Aqueous
Received
NA
02/12/2002 12:00
02/18/2002 14:26
02/18/2002 14:26
LOOOO
MSDA
ug/L
Cone Flaa
ND lA:3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND vS
ND \AJ
ND IA.. '.S
ND
ND
ND
ND
ND
ND
ND \A-J
LIMS Workorder: 80396913 [20202098} Hamilton Beach-Proctor Silex
STL Austin
DL RL
1.26 0.00
5.34 0.00
2.85 0.00
0.290 0.00
0.0465 0.00
0.0643 0.00
0.0449 0.00
0.0528 0.00
0.106 0.00
0.0454 0.00
2.83 0.00
0.0888 0.00
0.104 0.00
0.0934 0.00 ,
0.0415 0.00
0.0553 0.00
0.0596 o_oo
0.0404 o_oo
0.0755 0.00
0.0338 0.00
0.0798 O.Ou
0202HRWW234 -· TRIP BLANK_------·-
202020980/ 20'J0209809
Aqueous Aqueous
Received Received
NA NA
02/12/2002 15:00 02/ 12/2002 00:00
02/18/2002 17: 15 02/18/2002 13:29
02/18/2002 17: 15 02/18/2002 13 :2 9
1.0000 1.0000
MSDA MSDA
ug/L ug/L
Cone Flaa DL RL Cone Flaa DL RL
ND lA~ 1.26 0.00 ND lA.:J 1.26 0.00
ND 5.34 0.00 ND 5.34 0.00
ND 2.85 0.00 ND 2.85 0.00
ND 0.290 0.00 ND 0.290 0.00
ND 0.0465 0.00 ND 0.0465 0.00
ND 0.0643 0.00 ND 0.0643 0.00
ND 0.0449 0.00 ND 0.0449 0.00
ND 0.0528 0.00 ND 0.0528 0.00
ND 0.106 0.00 ND 0.106 0.00
ND 0.0454 0.00 ND 0.0454 0.00
ND 2.83 0.00 ND 2.83 0.00
ND 0.0888 0.00 ND 0.0888 0.00
ND 0.104 0.00 ND 0.104 0.00
ND 0.0934 0.00 ND 0.0934 0.00
ND 0.0415 0.00 ND 0.0415 0.00
ND 0.0553 0.00 ND 0.0553 0.00
ND 0.0596 0.00 ND 0_0596 0.00
ND 0.0404 0.00 ND 0.0404 0.00
ND 0.0755 0.00 ND 0_0755 0.00
ND 0.0338 0.00 ND 0.0338 0.00 ---ND u.0 796 0.00 ;·m 0.07~& J.c.u
Page 14 of 45
I I I 1·1-d I lJl'S I'· dia11 based on the results of 1hc daia 1cvicw process which is modeled alit:r tliL' Nmio1111/ F1111ctio1111/ G11itle/i11esfur Urg1111ic 11111/ lnorg11111c 1>11111 Re1•it•11· Sample 1csu I~ iavc iccn qua 1 1c >y '· -,a '
_,...., 1 ,,111 ... 1'1,.. ..,,....,,1('1C1lt l1 ... ~l,~'•('lly1h•'
------~-~----~-----SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
.--••M ___
Client Sample ID
Lab Sample ID
Parameter ·cAs· ~-~ 't· ' '. •' ~ ' .
Iodornethane 74-88-4
Iso_Qropylbenzene 98-82-8
4-Isopronvltoluene 99-87-6
Methyl rnethacrylate 80-62-6
Methyl tert-butvl ether (MTBE) 1634-04-4
4-Methvl-2-oentanone (MIBK) 108-10-1
Meth1lene chloride 75-09-2
Naphthalene 91-20-3
Propanenitrile 107-12-0
n-Proovlbenzene 103-65-1
Styrene 100-42-5
1 l 1 2-Tetrachloroethane 630-20-6
1 1 2,2-Tetrachloroethane 79-34-5
Tetrachloroethene 127-18-4
Tetrahvdrofuran 109-99-9
Toluene 108-88-3
I 2 3-Trichlorobenzene 87-61-6
I 2,4-Trichlorobenzene 120-82-1
I, I, I -Trichloroethane 71-55-6
1.1.2-Trichloroethane 79-00-5
Trichloroethene 79-01-6
Trichlorofluoromethane 75-69-4
1,2,3-Trichloropropane 96-18-4
l, 1,2-Trichlorotrifluoroethane 76-13-1
l,2,4-Trirnethvlbenzene 95-63-6
1 3 5-Trimethvlbenzene 108-67-8
Vinyl acetate 108-05-4
Vinyl chloride 75-01-4
SECTION IV -Analytical Results -02/24/2002 18:08
0202HBWW230
2020209801
Cone Flan
ND
ND
ND \A::S
ND
ND
ND
ND
ND LA.:S
ND
ND
ND
ND
ND
ND
ND
ND
ND IA\
ND \.h.::'5
ND
ND
ND
ND
ND
ND
ND
ND 1.A."S
.NJJ..-~
ND
LIMS Workordcr: 80396913 (20202098] Hamilton Beach-Proctor Silex
STl. Austin
DL
0.0452
0.0769
0.0899
0.175
0.0619
0.473
0.0210
0.0708
0.652
0.0698
0.0295
0.0578
0.109
0.103
l.28
0.0236
0.110
0.140
0.0511
0.0489
0.0506
0.0495
0.117
0.0529
. 0.0744
0.0616
0.172
0.0501
0202HBWW234 TRIP BLANK
2020209807 2020209809
-·-· -RL Cone Flaa DL RL Cone Flaa DL
0.00 ND 0.0452 0.00 ND 0.0452
0.00 ND 0.0769 0.00 ND 0.0769
0.00 ND 0.0899 0.00 ND 0.0899
0.00 ND 0.175 0.00 ND 0.175
0.00 ND 0.0619 0.00 ND 0.0619
0.00 ND 0.473 0.00 ND 0.473
0.00 ND 0.0210 0.00 0.175 J 0.0210
0.00 ND 0.0708 0.00 ND 0.0708
0.00 ND 0.652 0.00 ND 0.652
0.00 ND 0.0698 0.00 ND 0.0698
0.00 ND 0.0295 0.00 ND 0.0295
0.00 ND 0.0578 0.00 ND 0.0578
0.00 ND 0.109 0.00 ND 0.!09
0.00 ND 0.103 0.00 ND 0.103
0.00 ND l.28 0.00 ND l.28
0.00 ND 0.0236 0.00 ND 0.0236
0.00 ND 0.110 0.00 ND 0.110
0.00 ND 0.140 0.00 ND 0.140
0.00 ND 0.0511 0.00 ND 0.0511
0.00 ND 0.0489 0.00 ND 0.0489
0.00 , ND 0.0506 0.00 ND 0.0506
0.00 ND 0.0495 0.00 ND 0.0495
0.00 ND 0.117 0.00 ND 0.117
0.00 ND 0.0529 0.00 ND 0.0529
0.00 ND 0.0744 0.00 ND 0.0744
0.00 ND 0.0616 0.00 ND 0.0616
6.66 -NB ~ e.1+:;i 9.99 #&--~ e.!Tz
0.00 ND 0.0501 0.00 ND 0.0501
Page 16
1 · r d 1 URS Radian based 011 ihc results uf ihc da1a 1cvicw process, which is moddcd a lier th<' Nmiv1111/ J-i111c1iv11al G11i<leli11es for 01g1111ic11111/ Invrg1111ic /Jt1111 Rni<'ll" ~Jlll~k1~~111l!;l1avc~L:l!n~ua 11c iy ,,,-• ···''•·' .
---~L
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
9.-00
0.00
of 45
SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
o-X vlene/m-X vlene
o-Xvlene
Client Sample ID
Lab Sample ID
CAS
106-42-3
95-47-6
SECTION IV -Analytical Results -02/24/2002 18:08
0202HBWW230
2020209801
Cone Flaa
ND
ND
LIMS Workorder: 80396913 (20202098) Hamilton Beach-Proctor Silex
STLAustin
DL RL
0.0869 0.00
0.0409 0.00
0202HBWW234 TRIP BLANK
2020209807 2020209809
Cone Flaa DL RL Cone Flaa DL RL
ND 0.0869 0.00 ND 0.0869 0.00
ND 0.0409 0.00 ND 0.0409 0.00
Page 17 of ----·--· . -·d -I· _1• ,.,_,icess-· ism1~flcr~io1111/~1111/(~wsfo .. 01-vr111ic11111/fttori;1111icl>11111Rem•w """3'!Tl'Tljlcic:!'!!'!'!!!IP.!vcb.:!!Wll!!"'!"ll11.:d..,.._,-Rad c on <115< tac~ ------~-_ ~ _ ~ ,..,, _ ~ 11~ t _ .., 1 ('1(1,A1 9""'.:''"•"''~1 i,1,1•Jv~ -4S
--------~---~-~---­SECTION IV
Analytical Results
Surrogates
MS-VOA
SW8260B
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
DateITime Collected
DateITime Prepared
DateITime Analyzed
Dilution Factor
Instrument
Units
surronate Comi>ouncr · . "':" · .. ''·i::"?';_i : ~---'
I-Bromo-4-fluorobenzene
I 2-Dichloroethane-d4
Toluene-d8
SECTION IV· Analytical Results· 02/24/2002 18:08
0202HBWW230
2020209801
Aaueous
Received
NA
02/12/2002 12:00
02/18/2002 14:26
02/18/2002 14:26
1.0000
MSDA
ul?!L
.. %.Recfoverv: ·
95
100
104
LIMS Workorder: 80396913 [20202098) Hamilton Beach-Proctor Silex
STLAustin
Limits F
77-117
61-143
87-113
0202HBWW234 TRIP BLANK
2020209807 2020209809
Aqueous Aqueous
Received Received
NA NA
02112/2002 15:00 02/12/2002 00:00
02/18/2002 17: 15 02/18/2002 13:29
02/18/2002 17:15 02/18/2002 13 :29
1.0000 1.0000
MSDA MSDA
ug/L ug/L
% Recoverv Limits F % Recoverv Limits
96 77-117 98 77-117
IOI 61-143 103 61-143
104 87-113 108 87-113
Page 18
I I b I 'Ii ti b URS Ra<lia 1 based on the results of the <lala 1cvicw process which is mo<lcled aflcr th£' Ni11io1111/ F1111ctio11a/ G11itle/inesfur Organic mtd lnurgm1ic D11U1 R111•it•w S;irnPl~ ·~~~ ts 1~~~ -~~n ~~a 1 1c_ -~ __ -~-_ • -'-' _ ,
F
of 45
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LABORATORY REPORTS
SECTION I
Table of Contents
Section
I.
MS-VOA
II.
III.
IV.
v.
VI.
VII.
Form
Cover Page -Laboratory Analytical Report
Table of Contents . . . . . . . . . . . . . . . . . . . . . . .
Report Surrmaries . . . . .
Workorder Surrmary .
Protocol Surrmary •
Corrments and Flag Definitions . . .
Standard Flag Definitions
Analyst Ccmnents . . . .
Sarrple Condition Corrments Analytical Results • • · SW8260B . . : • . . . . . .
Calibration and Quality C;ntr;l·R~s~lts.
SW8260B .. . . . . . . . . . . . . . . . .
Calibration Verification Results
Mass Spectrometer Tune
Method Blank Results .
Spiked Sarrple Results .
. . . . . . . . . Batch Surrmaries . Control Sarrple Results
SW8260B .. . . . . . . . . . . . . . . . . .
Extraction/Digestion Batch Surrmary
Analysis Batch Surrmary . . . . . Certifications . . .
• • • • Ill • • • .. • • • • • •
Section I -Table of Content~ -02/24/2002 18:08
LIMS Workorder: 803'>'" . ··' -· _IJ\18] Hamilton Beach-Proctor Silex
Pa e
. . i
1
. . 1
1
. . 1
3
3
3
3
4
4
19
19
19
. 27
29
33
38
42
42
. . 42
44
45
-------------------
-------------------SECTION II
Report Summaries
MS-VOA
Client Name: Hamilton Beach-Proctor Silex
Client Code: HB-PS
Workorder Summary
Lab:: ::·.
Client Sample ID , "I
Samoleio
0202HBWW230 2020209801
0202HBWW226 2020209802
0202HBWD999 2020209803
0202HBWW220 2020209804
0202HBWW224 2020209805
0202HBWW225 2020209806
0202HBWW234 2020209807
0202HBWW222 2020209808
TRIP BLANK 2020209809
Protocol Summary
..
. ' . Lab -. ·"' Client Sample ID Samole:ID
Method: SW8260B
0202HBWW230 2020209801
0202HBWW226 2020209802
0202HBW0999 2020209803
0202HBWW220 2020209804
0202HBWW224 2020209805
SECTION II -Report Summaries -02/24/2002 18:08
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
Project Name: 80396913 [20202098] Hamilton Beach-Proctor Silex
Facility Name: NC
Samele Matrix Method Citation Method Description
Aqueous SW8260B Volatiles bv GC/MS
Aaueous SW8260B Volatiles bv GC/MS
Aqueous SW8260B Volatiles bv GC/MS
Aaueous SW8260B Volatiles bv GC/MS
Aqueous SW8260B Volatiles by GC/MS
Aaueous SW8260B Volatiles bv GC/MS
Aqueous SW8260B Volatiles by GC/MS
Aaueous SW8260B Volatiles bv GC/MS
Aqueous SW8260B Volatiles bv GC/MS
Date & Tirpe Date & Time Prep Date& Time Analysis Date & Ti!lle
Collected Received Batch ID Preoared Batch ID Analvzed
,,
02/12/02 12:00 02/13/02 16:08 16586 02/18/02 14:26 16586 02/18/02 14:26
02112/02 13:50 02/13/02 16:08 16586 02118/02 14:54 16586 02/18/02 14:54
02112/02 13:55 02/13/02 16:08 16586 02/18/02 15 :22 16586 02118/02 15:22
02112/02 14:12 02/13/02 16:08 16586 02/18/02 15:51 16586 02/18/02 15:51
02112/02 14:35 02/13/02 16:08 16586 02/18/02 16: 19 16586 02/18/02 16: 19
' •""
''"
Hold Time S >ec
Prep Amilvsis
Spec Actua Snee ·Actual
7D 6D 7D 60
70 60 70 60
70 60 70 60
7D 60 70 60
70 60 70 60
Page I of 45
SECTION II
Report Summaries
MS-VOA
Protocol Summary continued -
Lab
Client Samole ID SamolelD
Method: SW8260B continued -
0202HBWW225 2020209806
-·0202HBWW234 2020209807
0202HBWW222 2020209808
TRIP BLANK 2020209809
SECTION II -Report Summaries -02/24/2002 18:08
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
Date& Time Date& Time Prep Date& Time
Collected Received Batch ID Preoared
02/12/02 14:23 02/13/02 16:08 16586 02/18/02 16:47
02/12/02 15:00 02/13/02 16:08 16586 02/18/02 17:15
02/12/02 15:20 02/13/02 16:08 16586 02/18/02 17:43
02/12/02 00:00 02/13/02 16:08 16586 02/18/02 13:29
Hold Time S :>ec
Analysis Date&Time PreD' Analvsis
Batch ID Analvzed Spec Actua Soec Actua
16586 02/18/02 16:47 7D 6D 7D 60
16586 02/18/02 17: 15 7D 6D 70 6D
16586 02/18/02 17:43 7D 6D 7D 6D
16586 02/ 18/02 13 :29 7D 6D 7D 6D
Page 2 of 45
-------------------
--------SECTION Ill
Comments and Flag Definitions
MS-VOA
Standard Data Qualifiers
-Flaa oetinitiO:n '">''A . ',, ·~:\_>:: '.; '~~> , ', ;, ! I ~.
J Result> or -MDL and <POL
NA Not analvzed/Not available
ND Not detected at the soecified reoortinl! limit
0 Result does not meet tolerance in Protocol Soecification
u Result less than samole snecific method detection limit
Analyst Comments
I Flag I Affected 'sample, _ -1 Method
Sample Condition Comments
I Affected Sample :1-comment
SECTION Ill -Comments and Flag Definitions -02/24/2002 18:08
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
- -
-.. - - -- - - -
I Comment
Page 3 of 45
SECTION IV
Analytical Results
MS-VOA
SW8260B
Parameter
Acetone
Acetonitrile
Acrolein
Acrvlonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
n-Butvlbenzene
sec-Butvlbenzene
tert-Butvlbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1.3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
CAS
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
SECTION IV -Analytical Results -02/24/2002 18:08
0202HBWD999
2020209803
Aqueous
Received
NA
02/12/2002 13:55
02/18/2002 15:22
02/18/2002 15:22
l.0000
MSDA
ug/L
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
DL RL
1.26 0.00
5.34 0.00
2.85 0.00
0.290 0.00
0.0465 0.00
0.0643 0.00
0.0449 0.00
0.0528 0.00
0.106 0.00
0.0454 0.00
2.83 0.00
0.0888 0.00
0.104 0.00
0.0934 0.00 ,,
0.0415 0.00
0.0553 0.00
0.0596 0.00
0.0404 0.00
0.0755 0.00
0.0338 0.00
0.0798 0.00
0202HBWW220 0202HBWW222
2020209804 2020209808
Aaueous Aqueous
Received Received
NA NA
02/12/2002 14:12 02/12/2002 15:20
02/18/2002 15:51 02/18/2002 '17:43
02/18/2002 15:51 02/18/2002 17:43
1.0000 l.0000
MSDA MSDA
ug/L ug/L
Cone Fi a a DL RL Cone Flaa DL RL
ND 1.26 0.00 ND 1.26 0.00
ND 5.34 0.00 ND 5.34 0.00
ND 2.85 0.00 ND 2.85 0.00
ND 0.290 0.00 ND 0.290 0.00
ND 0.0465 0.00 ND 0.0465 0.00
ND 0.0643 0.00 ND 0.0643 0.00
ND 0.0449 0.00 ND 0.0449 0.00
ND 0.0528 0.00 ND 0.0528 0.00
ND 0.106 0.00 ND 0.106 0.00
ND 0.0454 0.00 ND 0.0454 0.00
ND 2.83 0.00 ND 2.83 0.00
ND 0.0888 0.00 ND 0.0888 0.00
ND 0.104 0.00 ND 0.104 0.00
ND 0.0934 0.00 ND 0.0934 0.00
ND 0.0415 0.00 ND 0.0415 0.00
ND 0.0553 0.00 ND 0.0553 0.00
ND 0.0596 0.00 ND 0.0596 0.00
ND 0.0404 0.00 ND 0.0404 0.00
ND 0.0755 0.00 ND 0.0755 0.00
ND 0.0338 0.00 ND 0.0338 0.00
ND 0.0798 0.00 ND 0.0798 0.00
Page 4 of 45
-----------~-------
-----------~------­SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
Chloromethane
3-Chloronronene
2-Chlorotoluene
4-Chlorotoluene
Client Sample ID
Lab Sample ID
<' CAS
74-87-3
107-05-1
95-49-8
·106-43-4
l 2-Dibromo-3-chloroorooane 96-12-8
Dibromochloromethane 124-48-1
l 2-Dibromoethane 106-93-4
Dibromomethane 74-95-3
trans-1.4-Dichloro-2-butene 110-57-6
1 .4-Dichlorobenzene 106-46-7
1 2-Dichlorobenzene 95-50-1
I 3-Dichlorobenzene 541-73-1
Dichlorodifluoromethane 75-71-8
1 1-Dichloroethane 75-34-3
1.2-Dichloroethane 107-06-2
1.1-Dichloroethene 75-35-4
cis-1 2-Dichloroethene 156-59-2
trans-I 2-Dichloroethene 156-60-5
l .2-Dichloronronane 78-87-5
l 3-Dichloronrooane 142-28-9
2 2-Dichloronronane 594-20-7
1.1-Dichloronrooene 563-58-6
cis-1 3-Dichloronrooene 10061-01-5
trans-1.3-Dichloroorooene 10061-02-6
Ethvl methacrvlate 97-63-2
Ethvlbenzene 100-41-4
Hexachloro-1 3-butadiene 87-68-3
2-Hexanone 591-78-6
SECTION IV -Analytical Results -02/24/2002 18:08
0202HBWD999
2020209803
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
DL
0.0509
0.0785
0.0359
0.0684
0.777
0.0946
0.0895
0.0550
0.0596
0.0495
0.0596
0.0591
0.0930
0.0445
0.0632
0.0492
0.0353
0.0430
0.0519
0.0401
0.0492
0.0374
0.0526
0.0486
0.0822
0.0469
0.155
0.838
0202HBWW220 0202HBWW222
2020209804 2020209808
RL Cone Flaa DL RL Cone Flaa DL RL
0.00 ND 0.0509 0.00 ND 0.0509 0.00
0.00 ND 0.0785 0.00 ND 0.0785 0.00
0.00 ND 0.0359 0.00 ND 0.0359 0.00
0.00 ND 0.0684 0.00 ND 0.0684 0.00
0.00 ND 0.777 0.00 ND 0.777 0.00
0.00 ND 0.0946 0.00 ND 0.0946 0.00 ... 0.00 ND 0.0895 0.00 ND 0.0895 0.00
0.00 ND 0.0550 0.00 ND 0.0550 0.00
0.00 ND 0.0596 0.00 ND 0.0596 0.00
0.00 ND 0.0495 0.00 ND 0.0495 0.00
0.00 ND 0.0596 0.00 ND 0.0596 0.00
0.00 ND 0.0591 0.00 ND 0.0591 0.00
0.00 ND 0.0930 0.00 ND 0.0930 0.00
0.00 0.607 0.0445 0.00 ND 0.0445 0.00
0.00 ND 0.0632 0.00 . ND 0.0632 0.00
0.00 ND 0.0492 0.00 ND 0.0492 0.00
0.00 ND 0.0353 0.00 ND 0.0353 0.00
0.00 ND 0.0430 0.00 ND 0.0430 0.00
0.00 ND 0.0519 0.00 ND 0.0519 0.00
0.00 ND 0.0401 0.00 ND 0.0401 0.00
0.00 ,, ND 0.0492 0.00 ND 0.0492 0.00
0.00 ND 0.0374 0.00 ND 0.0374 0.00
0.00 ND 0.0526 0.00 ND. 0.0526 0.00
0.00 ND 0.0486 0.00 ND 0.0486 0.00
0.00 ND 0.0822 0.00 ND 0.0822 0.00
0.00 ND 0.0469 0.00 ND 0.0469 0.00
0.00 ND 0.155 0.00 ND 0.155 0.00
0.00 ND 0.838 0.00 ND 0.838 0.00
Page 5 of 45
SECTION IV
Analytical Results
MS-VOA
SW8260B
Client Sample ID
Lab Sample ID
Continued
Parameter CAS
Iodomethane 74-88-4
lsoorooylbenzene 98-82-8
4-lsopropyltoluene 99-87-6
Methyl methacrvlate 80-62-6
Methyl tert-butyl ether (MTBE) 1634-04-4
4-MethYl-2-oentanone (MIBK) 108-10-1
Methylene chloride 75-09-2
Naphthalene 91-20-3
Prooanenitrile 107-12-0
n-Propy !benzene 103-65-1
Styrene 100-42-5
I I 1,2-Tetrachloroethane 630-20-6
I I 2 2-Tetrachloroethane 79-34-5
Tetrachloroethene 127-18-4
Tetrahydrofuran 109-99-9
Toluene 108-88-3
1 2 3-Trichlorobenzene 87-61-6
1 2 4-Trichlorobenzene 120-82-1
1.1.1-Trichloroethane 71-55-6
1.1.2-Trichloroethane 79-00-5
Trichloroethene 79-01-6
Trichlorofluoromethane 75-69-4
1.2.3-Trichloroorooane 96-18-4
1.1.2-Trichlorotrifluoroethane 76-13-1
1,2 4-Trimethylbenzene 95-63-6
I 3,5-Trimethylbenzene 108-67-8
Vinyl acetate 108-05-4
Vinyl chloride 75-01-4
SECTION IV -Analytical Results -02/24/2002 18:08
0202HBWD999
2020209803
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396913 (20202098] Hamilton Beach-Proctor Silex
STLAustin
DL
0.0452
0.0769
0.0899
0.175
0.0619
0.473
0.0210
0.0708
0.652
0.0698
0.0295
0.0578
0.109
0.103
1.28
0.0236
0.110
0.140
0.0511
0.0489
0.0506
0.0495
0.117
0.0529
0.0744
0.0616
0.172
0.0501
0202HBWW220 0202HBWW222
2020209804 2020209808
RL Cone Flaa DL RL ·cone .Flaa DL RL
0.00 ND 0.0452 0.00 ND 0.0452 0.00
0.00 ND 0.0769 0.00 ND 0.0769 0.00
0.00 ND 0.0899 0.00 ND 0.0899 0.00
0.00 ND 0.175 0.00 ND 0.175 0.00
0.00 ND 0.0619 0.00 ND 0.0619 0.00
0.00 ND 0.473 0.00 ND 0.473 0.00
0.00 ND 0.0210 0.00 ND 0.0210 0.00
0.00 ND 0.0708 0.00 ND 0.0708 0.00
0.00 ND 0.652 0.00 ND 0.652 0.00
0.00 ND 0.0698 0.00 ND 0.0698 0.00
0.00 ND 0.0295 0.00 ND 0.0295 0.00
0.00 ND 0.0578 0.00 ND 0.0578 0.00
0.00 ND 0.109 0.00 ND 0.109 0.00
0.00 ND 0.103 0.00 ND 0.103 0.00
0.00 ND 1.28 0.00 ND 1.28 0.00
0.00 ND 0.0236 0.00 ND 0.0236 0.00
0.00 ND 0.110 0.00 ND 0.110 0.00
0.00 ND 0.140 0.00 ND 0.140 0.00
0.00 ND 0.0511 0.00 ND 0.0511 0.00
0.00 ND 0.0489 0.00 ND 0.0489 0.00
0.00 ' ND 0.0506 0.00 ND 0.0506 0.00
0.00 ND 0.0495 0.00 ND 0.0495 0.00
0.00 ND 0.117 0.00 ND 0.117 0.00
0.00 ND 0.0529 0.00 ND 0.0529 0.00
0.00 ND 0.0744 0.00 ND 0.0744 0.00
0.00 ND 0.0616 0.00 ND 0.0616 0.00
0.00 ND 0.172 0.00 ND 0.172 0.00
0.00 ND 0.0501 0.00 ND 0.0501 0.00
Page 6 of 45
-------------------
-------------------SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
n-Xvlene/m-Xvlene
o-Xvlene
Client Sample ID
Lab Sample ID
CAS
106-42-3
95-47-6
SECTION IV -Analytical Results -02/24/2002 18:08
0202HBWD999
2020209803
·-. .Coric -·Flaa
ND
ND
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
DL RL
0.0869 0.00
0.0409 0.00
·'
0202HBWW220 0202HBWW222
2020209804 2020209808
Cone Flaa DL RL Cone Flaa DL RL
ND 0.0869 0.00 ND 0.0869 0.00
ND 0.0409 O.GO ND (;.0409 0.00
Page 7 of 45
SECTION IV
Analytical Results
Surrogates
MS-VOA
SW8260B
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
Surroaate Compound
I -Bromo-4-fluorobenzene
I 2-Dichloroethane-d4
Toluene-d8
SECTION IV -Analytical Results-02/24/2002 18:08
0202HBWD999
2020209803
Aoueous
Received
NA
02/12/2002 13:55
02/18/2002 15:22
02/18/2002 15:22
1.0000
MSDA
ug/L
% Racoverv
96
103
105
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
Limits F
77-117
61-143
87-113
0202HBWW220 0202HBWW222
2020209804 2020209808
Aqueous Aaueous
Received Received
NA NA
02/12/2002 14: 12 02/12/2002 15:20
02/18/2002 15:51 02/18/2002°17:43
02/18/2002 15:51 02/18/2002 17:43
1.0000 1.0000
MSDA MSDA
ug/L ug/L
% Recoverv Limits F % Recoverv Limits F
99 77-117 97 77-117
99 61-143 99 61-143
103 87-113 105 87-113
Page 8 of 45 -------------------
------------~------SECTION IV
Analytical Results
MS-VOA
SW8260B
Parameter
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
n-Butvlbenzene
sec-Butyl benzene
tert-Butvlbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1,3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
DatefTime Collected
DatefTime Prepared
DatefTime Analyzed
Dilution Factor
Instrument
Units
CAS, ..
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
SECTION IV -Analytical Results -02/24/2002 18:08
0202HBWW224
2020209805
Aaueous
Received
NA
02/12/2002 14:35
02/18/2002 16:19
02/18/2002 16:19
1.0000
MSDA
ugfL
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.640 J
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STL Austin
DL . RL
1.26 0.00
5.34 0.00
2.85 0.00
0.290 0.00
0.0465 0.00
0.0643 0.00
0.0449 0.00
0.0528 0.00
0.106 0.00
0.0454 0.00
2.83 0.00
0.0888 0.00
0.104 0.00
0.0934 0.00
0.0415 0.00
0.0553 0.00
0.0596 0.00
0.0404 0.00
0.0755 0.00
0.0338 0.00
0.0798 0.00
0202HBWW225 0202HBWW226
2020209806 2020209802
Aqueous Aaueous
Received Received
NA NA
02/12/2002 14:23 02/12/2002 13:50
02/18/2002 16:47 02/18/2002 14:54
02/18/2002 16:47 02/18/2002 14:54
1.0000 1.0000
MSDA MSDA
ug/L ug/L
Cone Flaa DL RL Cone Flaa DL RL ·-ND 1.26 0.00 ND 1.26 0.00
ND 5.34 0.00 ND 5.34 0.00
ND 2.85 0.00 ND 2.85 0.00
ND 0.290 0.00 ND 0.290 0.00
ND 0.0465 0.00 ND 0.0465 0.00
ND 0.0643 0.00 ND 0.0643 0.00
ND 0.0449 0.00 ND 0.0449 0.00
ND 0.0528 0.00 ND 0.0528 0.00
ND 0.106 0.00 ND 0.106 0.00
ND 0.0454 0.00 ND 0.0454 0.00
ND 2.83 0.00 ND 2.83 0.00
ND 0.0888 0.00 ND 0.0888 0.00
ND 0.104 0.00 ND 0.104 0.00
I ND 0.0934 0.00 ND 0.0934 0.00
ND 0.0415 0.00 ND 0.0415 0.00
ND 0.0553 0.00 ND 0.0553 0.00
ND 0.0596 0.00 ND 0.0596 0.00
ND 0.0404 0.00 ND 0.0404 0.00
ND 0.0755 0.00 ND 0.0755 0.00
ND 0.0338 0.00 ND 0.0338 0.00
ND 0.0798 0.00 ND 0.0798 0.00
Page 9 of 45
SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
Chloromethane
3-Chloropropene
2-Chlorotoluene
4-Chlorotoluene
Client Sample ID
Lab Sample ID
CAS_
74-87-3
107-05-1
95-49-8
106-43-4
I 2-Dibromo-3-chloropropane 96-12-8
Dibromochloromethane 124-48-1
I.2-Dibromoethane 106-93-4
Dibromomethane 74-95-3
trans-I 4-Dichloro-2-butene 110-57-6
1.4-Dichlorobenzene 106-46-7
1 2-Dichlorobenzene 95-50-1
l 3-Dichlorobenzene 541-73-1
Dichlorodifluoromethane 75-71-8
I. 1-Dichloroethane 75-34-3
I 2-Dichloroethane 107-06-2
1.1-Dichloroethene 75-35-4
cis-I .2-Dichloroethene 156-59-2
trans-I 2-Dichloroethene 156-60-5
l .2-Dichloropropane 78-87-5
1.3-Dichloroorooane 142-28-9
2,2-Dichlorooropane 594-20-7
1 1-Dichloroprooene 563-58-6
cis-1 3-Dichloroorooene 10061-01-5
trans-1,3-Dichloropropene 10061-02-6
Ethvl methacrvlate 97-63-2
Ethvlbenzene 100-41-4
Hexachloro-1 3-butadiene 87-68-3
2-Hexanone 591-78-6
SECTION IV -Analytical Results -02/24/2002 18:08
0202HBWW224
2020209805
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
DL
0.0509
0.0785
0.0359
0.0684
0.777
0.0946
0.0895
0.0550
0.0596
0.0495
0.0596
0.0591
0.0930
0.0445
0.0632
0.0492
0.0353
0.0430
0.0519
0.0401
0.0492
0.0374
0.0526
0.0486
0.0822
0.0469
0.155
0.838
0202HBWW225 0202HBWW226
2020209806 2020209802
RL Cone Flaa DL RL Cone f.laa DL RL
0.00 ND 0.0509 0.00 ND 0.0509 0.00
0.00 ND 0.0785 0.00 ND 0.0785 0.00
0.00 ND 0.0359 0.00 ND 0.0359 0.00
0.00 ND 0.0684 0.00 ND 0.0684 0.00
0.00 ND 0.777 0.00 ND 0.777 0.00
0.00 ND 0.0946 0.00 ND 0.0946 0.00
0.00 ND 0.0895 0.00 ND 0.0895 0.00
0.00 ND 0.0550 0.00 ND 0.0550 0.00
0.00 ND 0.0596 0.00 ND 0.0596 0.00
0.00 ND 0.0495 0.00 ND 0.0495 0.00
0.00 ND 0.0596 0.00 ND 0.0596 0.00
0.00 ND 0.0591 0.00 ND 0.0591 0.00
0.00 ND 0.0930 0.00 ND 0.0930 0.00
0.00 ND 0.0445 0.00 ND 0.0445 0.00
0.00 ND 0.0632 0.00 ND 0.0632 0.00
0.00 ND 0.0492 0.00 ND 0.0492 0.00
0.00 ND 0.0353 0.00 ND 0.0353 0.00
0.00 ND 0.0430 0.00 ND 0.0430 0.00
0.00 ND 0.0519 0.00 ND 0.0519 0.00
0.00 ND 0.0401 0.00 ND 0.0401 0.00
0.00 I ND 0.0492 0.00 ND 0.0492 0.00
0.00 ND 0.0374 0.00 ND 0.0374 0.00
0.00 ND 0.0526 0.00 ND 0.0526 0.00
0.00 ND 0.0486 0.00 ND 0.0486 0.00
0.00 ND 0.0822 0.00 ND 0.0822 0.00
0.00 ND 0.0469 0.00 ND 0.0469 0.00
0.00 ND 0.155 0.00 ND 0.155 0.00
0.00 ND 0.838 0.00 ND 0.838 0.00
Page IO of 45
------------~------
-------------------SECTION IV
Analytical Results
MS-VOA
SW8260B
Client Sample ID
Lab Sample ID
Continued
Parameter CAS . :~· : ~
lodomethane 74-88-4
lsoorooylbenzene 98-82-8
4-lsooronvltoluene 99-87-6
Methvl methacrvlate 80-62-6
Methyl tert-butvl ether (MTBE) 1634-04-4
4-Methvl-2-oentanone <MIBK) 108-10-1
Methylene chloride 75-09-2
Naohthalene 91-20-3
Prooanenitrile 107-12-0
n-Proovlbenzene 103-65-1
Stvrene 100-42-5
1 1 1 2-Tetrachloroethane 630-20-6
I 1 2 2-Tetrachloroethane 79-34-5
Tetrach loroethene 127-18-4
Tetrahvdrofuran 109-99-9
Toluene 108-88-3
1.2.3-Trichlorobenzene 87-61-6
1.2.4-Trichlorobenzene 120-82-1
1 L1 -Trichloroethane 71-55-6
l I 2-Trichloroethane 79-00-5
Trichloroethene 79-01-6
Trichlorofluoromethane 75-69-4
1.2.3-Trichloronronane 96-18-4
1 1 2-Trichlorotrifluoroethane 76-13-1
I 2 4-Trimethvlbenzene 95-63-6
1.3 .5-Trimethvlbenzene 108-67-8
Vinvl acetate 108-05-4
Vinyl chloride 75-01-4
SECTION IV -Analytical Results -02/24/2002 18:08
0202HBWW224
2020209805
: _cone Ffaa·
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
DL
0.0452
0.0769
0.0899
0.175
0.0619
0.473
0.0210
0.0708
0.652
0.0698
0.0295
0.0578
0.109
0.103
1.28
0.0236
0.110
0.140
0.0511
0.0489
0.0506
0.0495
0.117
0.0529
0.0744
0.0616
0.172
0.0501
0202HBWW225 0202HBWW226
2020209806 2020209802
RL Cone Flaa . DL RL Cone Flaa ... 01.:: ': '' "RL
0.00 ND 0.0452 0.00 ND 0.0452 0.00
0.00 ND 0.0769 0.00 ND 0.0769 0.00
0.00 ND 0.0899 0.00 ND 0.0899 0.00
0.00 ND 0.175 0.00 ND 0.175 0.00
0.00 ND 0.0619 0.00 ND 0.0619 0.00
0.00 ND 0.473 0.00 ND . _0.473 0.00
0.00 ND 0.0210 0.00 ND .. .. 0.0210 0.00
0.00 ND 0.0708 0.00 ND 0.0708 0.00
0.00 ND 0.652 0.00 ND 0.652 0.00
0.00 ND 0.0698 0.00 ND 0.0698 0.00
0.00 ND 0.0295 0.00 ND 0.0295 0.00
0.00 ND 0.0578 0.00 ND 0.0578 0.00
0.00 ND 0.109 0.00 ND 0.109 0.00
0.00 ND 0.103 0.00 ND . -0.103 0.00
0.00 ND 1.28 0.00 ND -J.28 0.00
0.00 ND 0.0236 0.00 ND 0.0236 0.00
0.00 ND 0.110 0.00 ND 0.110 0.00
0.00 ND 0.140 0.00 ND 0.140 0.00
0.00 ND 0.0511 0.00 ND 0.0511 0.00
0.00 ND 0.0489 0.00 ND 0.0489 0.00
0.00 ,, ND 0.0506 0.00 ND 0.0506 0.00
0.00 ND 0.0495 0.00 ND 0.0495 0.00
0.00 ND 0.117 0.00 ND 0.117 0.00
0.00 ND 0.0529 0.00 ND 0.0529 0.00
0.00 ND 0.0744 0.00 ND 0.0744 0.00
0.00 ND 0.0616 0.00 ND 0.0616 0.00
0.00 ND 0.172 0.00 ND 0.172 0.00
0.00 ND 0.0501 0.00 ND 0.0501 0.00
Page II of 45
SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
o-Xvlene/m-Xvlene
o-Xvlene
Client Sample ID
Lab Sample ID
CAS
106-42-3
95-47-6
SECTION IV -Analytical Results -02/24/2002 18:08
0202HBWW224
2020209805
Cone Flaa
ND
ND
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
DL RL
0.0869 0.00
0.0409 0.00
0202HBWW225 0202HBWW226
2020209806 2020209802
·Cone Flaa DL RL Cone Flaa DL RL
ND 0.0869 0.00 ND 0.0869 0.00
ND 0.0409 0.00 ND 0.0409 0.00
Page 12 of 45 -------------·------
-------------------SECTION IV
Analytical Results
Surrogates
MS-VOA
SW82608
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
Surroaate Combound .. '• <<', , .·· ',-; -~: , ~: ,. ·~ ~ ~ > •
I-Bromo-4-fluorobenzene
1.2-Dichloroethane-d4
Toluene-d8
SECTION IV -Analytical Results -02/24/2002 18:08
0202HBWW224
2020209805
Aqueous
Received
NA
02/12/2002 14:35
02/18/2002 16: 19
02/18/2002 16: 19
1.0000
MSDA
ug/L
: ~·Raco.veiv ·
99
102
105
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
·Limits ..
77-117
61-143
87-113
0202HBWW225 0202HBWW226
2020209806 2020209802
Aqueous Aqueous
Received Received
NA NA
02/12/2002 14:23 02/12/2002 13:50
02118/2002 16:47 02/18/2002 14:54
02/18/2002 16:47 02118/2002 14:54
1.0000 1.0000
MSDA MSDA
ug/L ug/L
F %Recoverv Limits· F % ·Recoverv ' . ·Limits F ..
97 77-117 98 77-117
103 61-143 103 61-143
104 87-113 104 87-113
Page 13 of 45
SECTION IV
Analytical Results
MS-VOA
SW8260B
Parameter
Acetone
Acetonitrile
Acrolein
Acrvlonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
n-Butvlbenzene
sec-Butvlbenzene
tert-Butvlbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-l ,3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
CAS
67-64-1
75-05-8
107-02-8
l 07-13-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
SECTION IV -Analytical Results -02/24/2002 18:08
0202HBWW230
2020209801
Aaueous
Received
NA
02/12/2002 12:00
02/18/2002 14:26
02/18/2002 14:26
1.0000
MSDA
ug/L
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
DL RL
1.26 0.00
5.34 0.00
2.85 0.00
0.290 0.00
0.0465 0.00
0.0643 0.00
0.0449 0.00
0.0528 0.00
0.106 0.00
0.0454 0.00
2.83 0.00
0.0888 0.00
0.104 0.00
0.0934 0.00
0.0415 0.00
0.0553 0.00
0.0596 0.00
0.0404 0.00
0.0755 0.00
0.0338 0.00
0.0798 0.00
0202HBWW234 __ TRIP BLANK-· ____ --·-
202020980/ 2020209809
Aaueous Aaueous
Received Received
NA NA
02/12/2002 15:00 02/12/2002 00:00
02/18/2002 17: 15 02/18/2002 13:29
02/18/2002 17: 15 02/18/2002 13 :29
l.0000 1.0000
MSDA MSDA
ug/L ug/L
Cone Flaa DL RL Cone Flaa DL RL
ND 1.26 0.00 ND 1.26 0.00
ND 5.34 0.00 ND 5.34 0.00
ND 2.85 0.00 ND 2.85 0.00
ND 0.290 0.00 ND 0.290 0.00
ND 0.0465 0.00 ND 0.0465 0.00
ND 0.0643 0.00 ND 0.0643 0.00
ND 0.0449 0.00 ND 0.0449 0.00
ND 0.0528 0.00 ND 0.0528 0.00
ND 0.106 0.00 ND 0.106 0.00
ND 0.0454 0.00 ND 0.0454 0.00
ND 2.83 0.00 ND 2.83 0.00
ND 0.0888 0.00 ND 0.0888 0.00
ND 0.104 0.00 ND 0.104 0.00
" ND 0.0934 0.00 ND 0.0934 0.00
ND 0.0415 0.00 ND 0.0415 0.00
ND 0.0553 0.00 ND 0.0553 0.00
ND 0.0596 0.00 ND 0.0596 0.00
ND 0.0404 0.00 ND 0.0404 0.00
ND 0.0755 0.00 ND 0.0755 0.00
ND 0.0338 0.00 ND 0.0338 0.00 --ND IJ.O 79d 0.1.lO ND 0.07~8 0.Gu
Page 14 of 45
-------------------
-------------------SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
Chloromethane
3-Chloronronene
2-Chlorotoluene
4-Chlorotoluene
'' "
Client Sample ID
Lab Sample ID
' . ., _,CA$).'':_'.:'-;
74-87-3
107-05-1
95-49-8
106-43-4
l .2-Dibromo-3-chloroorooane 96-12-8
Dibromochloromethane 124-48-1
I 2-Dibromoethane 106-93-4
Dibromomethane 74-95-3
trans-I 4-Dichloro-2-butene 110-57-6
I 4-Dichlorobenzene 106-46-7
1 2-Dichlorobenzene 95-50-1
1.3-Dichlorobenzene 541-73-1
Dichlorodifluoromethane 75-71-8
1 1-Dichloroethane 75-34-3
l .2-Dichloroethane 107-06-2
1.1-Dichloroethene 75-35-4
cis-1 2-Dichloroethene 156-59-2
trans-I 2-Dichloroethene 156-60-5
I 2-Dichloronronane 78-87-5
I 3-Dichloronronane 142-28-9
2 2-Dichloronronane 594-20-7
1.1-Dichloronronene 563-58-6
cis-1.3-Dichloronronene 10061-01-5
trans-1.3-Dichloronronene 10061-02-6
Ethvl methacrvlate 97-63-2
Ethvlbenzene 100-41-4
Hexachloro-1 3-butadiene 87-68-3
2-Hexanone 591-78-6
SECTION IV -Analytical Results -02/24/2002 18:08
0202HBWW230
2020209801
:cone· ·, Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
" DL RL
0.0509 0.00
0.0785 0.00
0.0359 0.00
0.0684 0.00
0.777 0.00
0.0946 0.00
0.0895 0.00
0.0550 0.00
0.0596 0.00
0.0495 0.00
0.0596 0.00
0.0591 0.00
0.0930 0.00
0.0445 0.00
0.0632 0.00
0.0492 0.00
0.0353 0.00
0.0430 0.00
0.0519 0.00
0.0401 0.00
0.0492 0.00
0.0374 0.00
0.0526 0.00
0.0486 0.00
0.0822 0.00
0.0469 0.00
0.155 0.00
0.838 0.00
0202HBWW234 TRIP BLANK
2020209807 2020209809
,. Cone Flaa DL .RL : DL' "' . RL, Cone ·Flaa :
ND 0.0509 0.00 ND 0.0509 0.00
ND 0.0785 0.00 ND 0.0785 0.00
ND 0.0359 0.00 ND 0.0359 0.00
ND 0.0684 0.00 ND 0.0684 0.00
ND 0.777 0.00 ND 0.777 0.00
ND 0.0946 0.00 ND ji.0946 0.00
ND 0.0895 0.00 ND _0.0895 0.00
ND 0.0550 0.00 ND 0.0550 0.00
ND 0.0596 0.00 ND 0.0596 0.00
ND 0.0495 0.00 ND 0.0495 0.00
ND 0.0596 0.00 ND 0.0596 0.00
ND 0.0591 0.00 ND 0.0591 0.00
ND 0.0930 0.00 ND 0.0930 0.00
ND 0.0445 0.00 ND . 0.0445 0.00
ND 0.0632 0.00 ND . 0.0632 0.00
ND 0.0492 0.00 ND 0.0492 0.00
ND 0.0353 0.00 ND 0.0353 0.00
ND 0.0430 0.00 ND 0.0430 0.00
ND 0.0519 0.00 ND 0.0519 0.00
ND 0.0401 0.00 ND 0.0401 0.00 ,, ND 0.0492 0.00 ND 0.0492 0.00
ND 0.0374 0.00 ND 0.0374 0.00
ND 0.0526 0.00 ND. 0.0526 0.00
ND 0.0486 0.00 ND 0.0486 0.00
ND 0.0822 0.00 ND 0.0822 0.00
ND 0.0469 0.00 ND 0.0469 0.00
ND 0.155 0.00 ND 0.155 0.00
ND 0.838 0.00 ND 0.838 0.00
Page 15 of 45
SECTION IV
Analytical Results
MS-VOA
SW82608
Client Sample ID
Lab Sample ID
Continued
,-·Parameter CAS
Iodomethane 74-88-4
Isooroovlbenzene 98-82-8
4-Isooroovltoluene 99-87-6
Methvl methacrvlate 80-62-6
Methyl tert-butvl ether (MTBE) 1634-04-4
4-Methvl-2-pentanone (MIBK) 108-10-1
Methvlene chloride 75-09-2
Naohthalene 91-20-3
Propanenitrile 107-12-0
n-Proovlbenzene 103-65-1
Stvrene 100-42-5
1 1.1.2-Tetrachloroethane 630-20-6
1 1 2 2-Tetrachloroethane 79-34-5
Tetrachloroethene 127-18-4
Tetrahvdrofuran 109-99-9
Toluene 108-88-3
I 2.3-Trichlorobenzene 87-61-6
1,2 4-Trichlorobenzene 120-82-1
I 1.1-Trichloroethane 71-55-6
1 1 2-Trichloroethane 79-00-5
Trichloroethene 79-01-6
Trichlorofluoromethane 75-69-4
1 2.3-Trichloropropane 96-18-4
1.1.2-Trichlorotrifluoroethane 76-13-1
1 2.4-Trimethvlbenzene 95-63-6
1 3 5-Trimethylbenzene 108-67-8
Vinvl acetate 108-05-4
Vinyl chloride 75-01-4
SECTION IV -Analytical Resulls • 02/24/2002 18:08
0202HBWW230
2020209801
-' Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
--·-· DL RL
0.0452 0.00
0.0769 0.00
0.0899 0.00
0.175 0.00
0.0619 0.00
0.473 0.00
0.0210 0.00
0.0708 0.00
0.652 0.00
0.0698 0.00
0.0295 0.00
0.0578 0.00
0.109 0.00
0.103 0.00
1.28 0.00
0.0236 0.00
0.110 0.00
0.140 0.00
0.0511 0.00
0.0489 0.00
0.0506 0.00
0.0495 0.00
0.117 0.00
0.0529 0.00
0.0744 0.00
0.0616 0.00
0.172 0.00
0.0501 0.00
0202HBWW234 TRIP BLANK
2020209807 2020209809
-Flaa ---Cone Flaa DL f<L Cone DL ~L
ND 0.0452 0.00 ND 0.0452 0.00
ND 0.0769 0.00 ND 0.0769 0.00
ND 0.0899 0.00 ND 0.0899 0.00
ND 0.175 0.00 ND 0.175 0.00
ND 0.0619 0.00 ND 0.0619 0.00
ND 0.473 0.00 ND 0.473 0.00
ND 0.0210 0.00 0.175 J 0.0210 0.00
ND 0.0708 0.00 ND 0.0708 0.00
ND 0.652 0.00 ND 0.652 0.00
ND 0.0698 0.00 ND 0.0698 0.00
ND 0.0295 0.00 ND 0.0295 0.00
ND 0.0578 0.00 ND 0.0578 0.00
ND 0.109 0.00 ND 0.109 0.00
ND 0.103 0.00 ND 0.103 0.00
ND 1.28 0.00 ND 1.28 0.00
ND 0.0236 0.00 ND 0.0236 0.00
ND 0.110 0.00 ND 0.110 0.00
ND 0.140 0.00 ND 0.140 0.00
ND 0.0511 0.00 ND 0.0511 0.00
ND 0.0489 0.00 ND 0.0489 0.00 , ND 0.0506 0.00 ND 0.0506 0.00
ND 0.0495 0.00 ND 0.0495 0.00
ND 0.117 0.00 ND 0.117 0.00
ND 0.0529 0.00 ND 0.0529 0.00
ND 0.0744 0.00 ND 0.0744 0.00
ND 0.0616 0.00 ND 0.0616 0.00
ND 0.172 0.00 ND 0.172 0.00
ND 0.0501 0.00 ND 0.0501 0.00
Page 16 of 45 -------------------
-------------------SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Client Sample ID
Lab Sample ID
0202HBWW230
2020209801
Parameter .:cAs .. :. ,, :·Cone. .Flaa · DL
a-Xvlene/m-Xvlene 106-42-3 ND
o-Xvlene 95-47-6 ND
SECTION IV -Analytical Results -02/24/2002 18:08
LIMS Workorder: 80396913 [20202098} Hamilton Beach-Proctor Silex
STLAustin
0.0869
0.0409
RL
0.00
0.00
0202HBWW234 TRIP BLANK
2020209807 2020209809
.. Cone ·Flaa DL RL Cone l!iaa .. DL '' Rl.
ND 0.0869 0.00 ND 0.0869 0.00
ND 0.0409 0.00 ND 0.0409 0.00
Page 17 of 45
SECTION IV
Analytical Results
Surrogates
MS-VOA
SW8260B
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
Surroaate Comoound
l-Bromo-4-fluorobenzene
l .2-Dichloroethane-d4
Toluene-d8
SECTION IV -Analytical Results -02/24/2002 18:08
0202HBWW230
2020209801
Aaueous
Received
NA
02/12/2002 12:00
02/18/2002 14:26
02/18/2002 14:26
1.0000
MSDA
ug/L
%Recoverv
95
100
104
LIMS Workorder: 80396913 [20202098) Hamilton Beach-Proctor Silex
STLAustin
Limits F
77-ll7
61-143
87-113
0202HBWW234 TRIP BLANK
2020209807 2020209809
Aaueous Aaueous
Received Received
NA NA
02/12/2002 15:00 02/12/2002 00:00
02/18/2002 17:15 02/18/2002 i3:29
02/18/2002 17:15 02/18/2002 13:29
1.0000 1.0000
MSDA MSDA
ug/L ug/L
.% Recoverv Limits F % Recoverv Limits F
96 77-117 98 77-117
101 61-143 103 61-143
104 87-113 108 87-113
Page 18 of 45
-------------------
- - - -- - - - - - - - - - - - -'--SECTION V
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW82608
Sample Type: Continuing Calibration Check
Analysis Batch ID: 16586 Instrument Data File: A0218203.D
Instrument ID: MSDA Analyst: BJP
Parameter Refer.enc& Vallie
Acetone 20
Acetonitrile 100
Acrolein 100
Acrvlonitrile 100
Benzene 20
Bromobenzene 20
Bromochloromethane 20
Bromodichloromethane 20
Bromoform 20
Bromomethane 20
2-Butanone (MEK) 20
n-Butvlbenzene 20
sec-Butvlbenzene 20
tert-Butvlbenzene 20
Carbon disulfide 20
Carbon tetrachloride 20
2-Chloro-I-3-butadiene 20
Chiorobenzene 20
Chloroethane 20
Chloroform 20
1-Chlorohexane 20
Chloromethane 20
3-Chloroorooene 20
2-Chlorotoluene 20
4-Chlorotoluene 20
1.2-Dibromo-3-chloroorooane 20
SECTION V -Calibration and QC Information -02/24/2002 I 8:08
LIMS Workorder: 80396913 [20202098) Hamilton Beach-Proctor Silex
STLAustin
Measured Cone Flaa
I2.5
103
83.7
90.3
19.7
19.2
19.9
19.5
17.9
20.3
17.8
20.8
20.2
19.9
I9.9
19.9
20.0
I9.7
21. I
19.3
19.7
21.2
19.4
19.3
19.9
16.9
Dateffime Analyzed:02/l 8/2002 I I :08
Units: ug/L
%Recoverv Flaa QC Limits %Recoverv
63
I03
84
90
98
96
99
98
89
102
89
104
lOI
99
99
99 ---·· 100
99
105
97 80-120
99
106
97
97
99
85
Page 19 of 45
SECTIONV
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW8260B
Sample Type: Continuing Calibration Check
Analysis Batch ID: 16586 Instrument Data File: A02 l 8203.D
Instrument ID: MSDA Analyst: BJP
Continued
Parameter Reference Value
Dibromochloromethane 20
1.2-Dibromoethane 20
Dibromomethane 20
trans-l.4-Dichloro-2-butene 20
I 4-Dichlorobenzene 20
I 2-Dichlorobenzene 20
1.3-Dichlorobenzene 20
Dichlorodifluoromethane 20
1.1-Dichloroethane 20
I 2-Dichloroethane 20
1.1-Dichloroethene 20
cis-1.2-Dichloroethene 20
trans-I 2-Dichloroethene 20
l 2-Dichloroorooane 20
I.3-Dichloroorooane 20
2.2-Dichloroorooane 20
1.1-Dichloroorooene 20
cis-1.3-Dichlorooropene 20
trans-1.3-Dichloroorooene 20
Ethvl methacrvlate 20
Ethvlbenzene 20
Hexachloro-1.3-butadiene 20
2-Hexanone 20
lodomethane 20
lsooroovlbenzene 20
4-lsooroovltoluene 20
SECTION V -Calibration and QC Information -02/24/2002 18:08
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
Measured Cone Flaa
19.2
19.8
18.7
18.0
19.4
18.9
19.0
22.3
20.4
18.8
20.9
19.4
20.7
19.l
18.3
20.9
20.6
19.0
18.3
17.0
20.2
20.8
17.0
19.6
19.9
20.2
Dateffime Analyzed:02/l 8/2002 11 :08
Units: ug/L
%Recoveni Flaa QC Limits %Recoverv ·.
96
99
94
90
97
95
95
111
102
94
104 80-120
97
104
96 80-120
92
104
103
95
92
85
101 80-120
104
85
98
100
101
Page 20
- - - -- - - - - - - -- - - - -
of 45 - -
-------------------SECTIONV
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW82608
Sample Type: Continuing Calibration Check
Analysis Batch ID: 16586 Instrument Data File: A0218203.D
Instrument ID: MSDA Analyst: BJP
Continued
Parameter· ' .. Refer,ance Value
Methvl methacrvlate 20
Methvl tert-butvl ether <MTBE) 20
4-Methvl-2-oentanone <MIBK) 20
Methvlene chloride 20
Nanhthalene 20
Prooanenitrile 100
n-Proovlbenzene 20
Stvrene 20
1. l. l .2-Tetrachloroethane 20
1 I 22-Tetrachloroethane 20
Tetrachloroethene 20
Tetrahvdrofuran 20
Toluene 20
1.2.3-Trichlorobenzene 20
1.2 4-Trichlorobenzene 20
1 l I -Trichloroethane 20
1.1 2-Trichloroethane 20
Trichloroethene 20
Trichlorofluoromethane 20
,_ ! , 2,3-Trichloronrooane 20
J. I 2-Trichlorotrifluoroethane 20
1.2.4-Trimethvlbenzene 20
I 3.5-Tririlethvlbenzene 20
Vinvl acetate 20
Vinvl chloride 20
n-Xvlene/m-Xvlene 40
SECTION V -Calibration and QC Information -02/24/2002 18:08
UMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
Measured Cone Flaa
17.3
18.8
17.8
20.0
17.2
99.6
20.3
19.6
18.8
18.6
20.9
17.0
19.9
16.9
18.3
20.0
19.1
20.6
25.4
18.5
20.9
20.0
19.6
16.5
21.6
39.9
Dateffime Analyzed:02/l 8/2002 11 :08
Units: ug/L
%Recoveni Flaa QC Limits %Reco.verv
87
94
89
100
86
100
101
98
94
93
105
85
100 80-120
84
91
100
96.
103
127
93
104
100
98
83
108 80-120
100
Page 21 of 45
- - - -SECTION V ----------- - - - -
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW82608
Sample Type: Continuing Calibration Check
Analysis Batch ID: 16586
MSDA
Instrument Data File: A0218230.D
Instrument ID: Analyst: BJP
_,,
Parameter 'Referenc&:v.a1ue
Acetone 20
Acetonitrile 100
Acrolein 100
Acrvlonitrile 100
Benzene 20
Bromobenzene 20
Bromochloromethane 20
Bromodichloromethane 20
Bromofonn 20
Bromomethane 20
2-Butanone (MEK) 20
n-Butvlbenzene 20
sec-Butvlbenzene 20
tert-Butvlbenzene 20
Carbon disulfide 20
Carbon tetrachloride 20
2-Chloro-1 3-butadiene 20
Chlorobenzene 20
Chloroethane 20
Chloroform 20
1-Chlorohexane 20
Chloromethane 20
3-Chlorooronene 20
2-Chlorotoluene 20
4-Chlorotoluene 20
I 2-Dibromo-3-chloropropane 20
SECTION V -Calibration and QC lnfonnation -02/24/2002 18:08
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
Measured Cone Flan
15.2
102
83.1
94.5
20.6
19.9
20.5
19.6
15.4
21.2
14.2
22.3
21.6
21.0
18.6
20.2
20.7
20.7
22.1
20.4
20.6
21.9
19.6
20.9
21.0
17.3
Date/Time Analyzed:02/19/2002 09:34
Units: ug/L
%Recovei:v Flaa QC Limits %Recoverv '
76
102
83
94
103
100
103
98
77
106
71
112
108
105
93
IOI
103
103
111
~ 102 80-120
103
109
98
104
105
87
Page 23 of 45
SECTIONV
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW8260B
Sample Type: Continuing Calibration Check
Analysis Batch ID: 16586 Instrument Data File: A0218230.D
Instrument ID: MSDA Analyst: BJP
Continued
Parameter Reference Value
Dibromochloromethane 20
I 2-Dibromoethane 20
Dibromomethane 20
trans-I 4-Dichloro-2-butene 20
1 4-Dichlorobenzene 20
I 2-Dichlorobenzene 20
1.3-Dichlorobenzene 20
Dichlorodifluoromethane 20
1.1-Dichloroethane 20
1.2-Dichloroethane 20
I 1-Dichloroethene 20
cis-1 2-Dichloroethene 20
trans-I 2-Dichloroethene 20
1.2-Dichloroorooane 20
1.3-Dichloroorooane 20
2 2-Dichloroorooane 20
l. l-Dichloropropene 20
cis-1.3-Dichloroorooene 20
trans-1.3-Dichloropropene 20
Ethvl methacrvlate 20
Ethvlbenzene 20
Hexachloro-l .3-butadiene 20
2-Hexanone 20
lodomethane 20
lsooroovlbenzene 20
4-lsooroovltoluene 20
SECTION V -Calibration and QC Information -02/24/2002 18:08
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
Measured Cone Flaa
19.2
20.1
19.9
18.7
19.8
19.7
20.0
22.8
21.6
19.6
21.9
20.l
21.6
20.4
18.9
21.0
21.2
19.3
18.4
17.0
21.1
21.5
17.5
20.l
21.0
21.7
Dateffime Analyzed:02/19/2002 09:34
Units: ug/L
%Recoverv Flaa QC Limits %Recovery '
96
100
99
94
99
98
100
114
108
98
110 80-120
101
108
102 80-120
95
105
106
96
92
85
106 80-120
107
87
100
105
108
Page 24 -------- - - - - - - - - -
of 45 - -
-------------------SECTION V
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW8260B
Sample Type: Continuing Calibration Check
Analysis Batch ID: 16586 Instrument Data File: A0218230.D
Instrument ID: MSDA Analyst: BJP
Continued
Parameter Reference' Value
Methvl methacrvlate 20
Methvl tert-butvl ether <MTBE) 20
4-Methvl-2-nentanone (MIBK) 20
Methvlene chloride 20
Naohthalene 20
Prooanenitrile 100
n-Pronvlbenzene 20
Stvrene 20
L1 1 2-Tetrachloroethane 20
1.1.2 2-Tetrachloroethane 20
Tetrachloroethene 20
Tetrahvdrofuran 20
Toluene 20
I 2.3-Trichlorobenzene 20
I 2 4-Trichlorobenzene 20
Ll I -Trichloroethane 20
L 1 2-Trichloroethane 20
Trichloroethene 20
Trichlorofluoromethane 20
1.2.3-Trichloroorooane 20
I. I 2-Trichlorotrifluoroethane 20
1.2 4-Trimethvlbenzene 20
l.3 5-Trimethvlbenzene 20
Vinvl acetate 20
Vinvl chloride 20
n-Xvlene/m-Xvlene 40
SECTION V -Calibration and QC Information -02/24/2002 18:08
LIMS Workorder: 80396913 (20202098] Hamilton Beach-Proctor Silex
STLAustin
Measured Cone Flaa
17.8
17.7
17.8
20.5
17.8
119
21.7
20.7
19.6
19.0
23.7
20.1
20.9
17.8
19.3
21.0
19.6
22.l
27.6
18.9
22.3
21.1
21.4
16.6
22.6
42.3
Date!fime Analyzed:02/l 9/2002 09:34
Units: ug/L
'%Recoverv Flaa QC Limits %Recoverv
89
88
89
103
89
119
108
103
98
95
118
101
105 80-120
89
97
105
98
111
138
94
111
106
107
83
113 80-120
106
Page 25 of 45
-------------------SECTIONV
Calibration and QC Information
Mass Spectrometer Tune
MS-VOA
SW8260B
BFB
Analysis Batch ID: 16586
Instrument ID: MSDA
Instrument Data File:
Injection Time:
"' • < ..... < -!'"/ ~ .::. : ilon Abundance Criteria·
A0218203.D
02/18/2002 11 :08
~· .~: .. ;· '. ,._~ ,,
Mass/Enerav. \ :.~;,. · : .. r:::.-~.: :tower ·L1m1t ~ <: :. : ·· Unner-Limit ·
50 15
75 30
95 100
96 5
173 0
174 50
175 5
176 95
177 5
SECTION V -Calibration and QC lnfonnation -02/24/2002 18:08
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
40
60
100
9
2
9
101
9
Date Analyzed: 02/18/2002 11 :08
Analyst: BJP
% Relative Abundance
20.3
42.6
100
6.8
0
79.3
7.6
98
6.3
Page 27 of 45
SECTIONV
Calibration and QC Information
Mass Spectrometer Tune
MS-VOA
SW8260B
BFB
Analysis Batch ID: 16586
Instrument ID: MSDA
, ~· ,,
. ,
,,,
Instrument Data File:
Injection Time:
Ion Abundance Criteria
A0218230.D
02/19/2002 09:34
Mass/Enerov, '',>'':-;:;,,·;{, ·1Lower Ltrritt '' , , Onner Limit
50 15
75 30
95 100
96 5
173 0
174 50
175 5
176 95
177 5
SECTION V -Calibration and QC Information -02/24/2002 18:08
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
40
60
100
9
2
9
101
9
Date Analyzed: 02/19/2002 09:34
Analyst: BJP
% Relative Abundance
20.4
43.8
100
6.9
0
67.1
7.5
95.2
7.5
Page 28 of 45
-------------------
-------------------SECTIONV
Calibration and QC Information
Method Blank Results
MS-VOA
SW8260B
Parameter
Acetone
Acetonitrile
Acrolein
Acrvlonitrile
Benzene
Bromobenzene
·.
Bromochloromethane
Bromodichloromethane
Bromofonn
Bromomethane
2-Butanone (MEK)
n-Butvlbenzene
sec-Butylbenzene
tert-Butvlbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1,3-butadiene
Chlorobenzene
Chloroethane
Chlorofonn
1-Chlorohexane
Chloromethane
3-Chloroorooene
2-Chlorotoluene
4-Chlorotoluene
Method Blank ID
Sample Type
Matrix
Date/Time Prepared
Date/Time Analyzed
Instrument
Units
; "·eAS~·;r:;;;~~i,;
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
74-87-3
107-05-1
95-49-8
106-43-4
1035519
Method Blank
Aoueous
02/18/2002 13:01
02/18/2002 13:01
MSDA
ug/L
:;.Cone,· . Flag
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
SECTION V -Calibration and QC Information -02/24/2002 18:08
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STL Austin
'
DL RL ·.Coric Flaa DL RL Cone Flaa ,oL·. ··RL, ..
1.26 0.00
5.34 0.00
2.85 0.00
0.290 0.00
0.0465 0.00
0.0643 0.00
0.0449 0.00
0.0528 0.00
0.106 0.00
0.0454 0.00
2.83 0.00
0.0888 0.00 -
0.104 0.00
0.0934 0.00
0.0415 0.00
0.0553 0.00
0.0596 0.00
0.0404 0.00 ,I
0.0755 0.00
0.0338 0.00
0.0798 0.00
0.0509 0.00
0.0785 0.00
0.0359 0.00
0.0684 0.00 '-
Page 29 of 45
SECTIONV
Calibration and QC Information
Method Blank Results
MS-VOA
SW8260B
Method Blank ID
Continued
Parameter :,CAS:· , ,,
I 2-Dibromo-3-chloroorooane 96-12-8
Dibromochloromethane 124-48-1
I .2-Dibromoethane 106-93-4
Dibromomethane 74-95-3
trans-1,4-Dichloro-2-butene 110-57-6
1.4-Dichlorobenzene I06-46-7
1.2-Dichlorobenzene 95-50-I
I 3-Dichlorobenzene 54 I-73-1
Dichlorodifluoromethane 75-71-8
l. I -Dichloroethane 75-34-3
I .2-Dichloroethane 107-06-2
I .1-Dichloroethene 75-35-4
cis-I .2-Dichloroethene 156-59-2
trans-I 2-Dichloroethene I56-60-5
I 2-Dichloroorooane 78-87-5
I 3-Dichlorooropane 142-28-9
2 2-Dichlorooropane 594-20-7
I I-Dichlorooropene 563-58-6
cis-I 3-Dichloroorooene I006I-Ol-5
trans-I 3-Dichloropropene I0061-02-6
Ethyl methacrvlate 97-63-2
Ethvlbenzene 100-41-4
Hexachloro-1.3-butadiene 87-68-3
2-Hexanone 591-78-6
Iodomethane 74-88-4
Isooroovlbenzene 98-82-8
4-Isoorooyltoluene 99-87-6
Methyl methacrvlate 80-62-6
Methyl tert-butyI ether (MTBE) I634-04-4
l0355I9
Cone
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
SECTION V -Calibration and QC Information -02/24/2002 18:08
LIMS Workorder: 80396913 (20202098] Hamilton Beach-Proctor Silex
STLAustin
Flaa DL RL Cone Flaa DL RL Cone Flaa DL RL
0.777 0.00
0.0946 0.00
0.0895 0.00
0.0550 0.00
0.0596 0.00
0.0495 0.00
0.0596 0.00
0.0591 0.00
0.0930 0.00
0.0445 0.00
0.0632 0.00
0.0492 0.00
0.0353 0.00
0.0430 0.00
0.05I9 0.00
0.0401 0.00
0.0492 0.00
0.0374 0.00
0.0526 0.00
0.0486 0.00
0.0822 0.00
0.0469 0.00 ,
0.155 0.00
0.838 0.00
0.0452 0.00
0.0769 0.00
0.0899 0.00
0.175 0.00
0.0619 0.00
Page 30 of 45
-------------------
-------------------SECTIONV
Calibration and QC Information
Method Blank Results
MS-VOA
SW8260B
Method Blank ID
Continued
Parameter ' OAS, . , : ;_;,,
4-Methvl-2-pentanone (MIBK) 108-10-1
Methylene chloride 75-09-2
Naohthalene 91-20-3
Propanenitrile 107-12-0
n-Proovlbenzene 103-65-1
Stvrene 100-42-5
I, I I 2-Tetrachloroethane 630-20-6
I I 2 2-Tetrachloroethane 79-34-5
Tetrachloroethene 127-18-4
Tetrahvdrofuran 109-99-9
Toluene 108-88-3
1.2.3-Trichlorobenzene 87-61-6
1,2 4-Trichlorobenzene 120-82-1
1 I.I -Trichloroethane 71-55-6
I, 1,2-Trichloroethane 79-00-5
Trichloroethene 79-01-6
Trichlorofluoromethane 75-69-4
I 2 3-Trichloroorooane 96-18-4
I I 2-Trichlorotrifluoroethane 76-13-1
I 2 4-Trimethylbenzene , 95-63-6
I 3.5-Trimethvlbenzene 108-67-8
Vinyl acetate 108-05-4
Vinvl chloride 75-01-4
o-Xvlene/m-Xvlene 106-42-3
o-Xylene 95-47-6
1035519
«,,:cone
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
SECTION V -Calibration and QC Information -02/24/2002 18:08
LlMS Workorder: 80396913 (20202098] Hamilton Beach-Proctor Silex
STLAustin
Flaa DL RL Cone Flaa DL RL Cone Flaa DL '< RL
0.473 0.00
0.0210 0.00
0.0708 0.00
0.652 0.00
0.0698 0.00
0.0295 0.00
0.0578 0.00 --
0.109 0.00 ...
0.103 0.00
1.28 0.00
0.0236 0.00
0.110 0.00
0.140 0.00
0.0511 0.00
0.0489 0.00
0.0506 0.00 '
0.0495 0.00
0.117 0.00
0.0529 0.00
0.0744 0.00
0.0616 0.00
0.172 0.00 '
0.0501 0.00
0.0869 0.00
0.0409 0.00
Page 31 of 45
SECTIONV
Calibration and QC Information
Method Blank Results
MS-VOA
SW8260B
Surroaate Comoound
l-Bromo-4-fluorobenzene
l .2-Dichloroethane-d4
Toluene-d8
Method Blank ID
Sample Type
Matrix
Date/Time Prepared
Date/Time Analyzed
Instrument
Units
1035519
Method Blank
Aaueous
02/18/2002 13:01
02/18/2002 13:01
MSDA
ug/L
o/o Recoverv
98
99
105
SECTION V -Calibration and QC lnfomtation -02/24/2002 18:08
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
Limits F %Recoverv Limits F' % Recoverv Limits F
77-117
61-143
87-113
Page 32 of 45
-------------------
SECTIONV
Calibration and QC Information
Spiked Sample Results
MS-VOA
SW8260B
Parameter
1-Chlorohexane
Chloromethane
3-Chloroorooene
2-Chlorotoluene
4-Chlorotoluene
I ,2-Dibromo-3-chloropropane
Dibromochloromethane
I 2-Dibromoethane
Dibromomethane
trans-I 4-Dichloro-2-butene
1.4-Dichlorobenzene
1,2-Dichlorobenzene
I 3-Dichlorobenzene
Dichlorodifluoromethane
1.1-Dichloroethane
1,2-Dichloroethane
1 1-Dichloroethene
cis-1 2-Dichloroethene
trans-1.2-Dichloroethene
I 2-Dichloroorooane
I 3-Dichloropropane
2.2-Dichloroorooane
I 1-Dichloropropene
cis-1 3-Dichloropropene
trans-I 3-Dichlorooropene
p t f d aren con mue
2020209801
Qil ~ac: ·
1.0000 cone·,: . ·.Fla·
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Sniked Sample continued
Lab ID: 1035520
Oil Fae: 1.0000
File JD: A0218227.D
SpkConc Cone %Rec Fig
20 14.8 74
20 22.3 111
20 17.8 89
20 17.2 86
20 17.2 ·86
20 16. l 80
20 17.2 86
20 20.4 102
20 19.8 99
20 14.3 71
20 15.8 79
20 15.7 79
20 15.4 77
20 23.8 119
20 22.6 113
20 20.1 100
20 22.9 115
20 20.6 103
20 22.2 111
20 21.2 106 •
20 19.3 96
20 19.7 99
20 21.4 107
20 17.9 89
20 16.9 85
Note: Spike Concentration for solid matrices not adjusted for percent moisture.
SECTION V -Calibration and QC Information -02/24/2002 18:08
LIMS Workorder: 80396913 [20202098) Hamilton Beach-Proctor Silex
STL Austin
iDI e amp1e UP' 1ca econ mue S 'k d S I D I' t f d
Lab ID: 1035521
Oil Fae: 1.0000 QC l,.imits
File ID: A0218228.D
SpkConc Cone %Rec Fig RPO Fla %Rec RPO
20 19.7 99 29 0 70-130 25
20 22.0 110 0.9 18-140 26
20 17.1 86 3.4 70-130 25
20 19.6 98 13 70-136 24
20 19.7 98 13 74-132 23
20 15.9 79 1.3 39-171 25
20 16.6 83 3.6 45-137 15
20 19.6 98 4 19-187 19
20 19.8 99 0 52-138 21
20 14.2 71 0 70-130 25
20 18.8 94 17 0 70-132 13
20 18.5 93 16 0 67-135 14
20 18.5 93 19 0 68-134 14
20 24.2 121 l.7 0.1-166 26
20 22.1 111 1.8 66-138 19
20 20.0 100 0 48-152 23
20 22.7 114 0.9 47-175 25
20 21.3 107 3.8 66-144 18
20 21.9 109 1.8 62-146 22
20 20.9 104 1.9 61-133 17
20 19.1 96 0 70-128 16
20 20.1 100 1 40-168 30
20 21.4 107 0 71-155 31
20 18.0 90 I.I 36-142 16
20 16.7 83 2.4 34-138 21
Page 34 of 45 -------------------
--------------------SECTIONV
Calibration and QC Information
Spiked Sample Results
MS-VOA
SW8260B
... . .
Parameter
·.
'.
Ethvl methacrvlate
Ethvlbenzene
,,
:
Hexachloro-1.3-butadiene
2-Hexanone
lodomethane
Jsopropylbenzene
4-Jsopropvltoluene
Methvl methacrvlate
Methyl tert-butvl ether (MTBE)
4-Methvl-2-pentanone (MIBK)
Methylene chloride
Naphthalene
Propanenitrile
n-Proovlbenzene
Styrene
I. I I .2-Tetrachloroethane
l.1.2 2-Tetrachloroethane
Tetrachloroethene
Tetrahvdrofuran
Toluene
I .2 3-Trichlorobenzene
l 2 4-Trichlorobenzene
I l I-Trichloroethane
IJ 2-Trichloroethane
Trichloroethene
p t aren contmue d
. 202020980f :, .. bil:.Ey<~;;.~~i{\~1~:. A. '
•«• .. \'~~..:,;.,. .•;:'\·: .: .... . ·1:00t10~.::,j,~~;~ ;..,. __
,. • <'; ~" -~"· ' .. .; ' ' ~ ':cone:.,~r::~:~:.~·.~rs1a ·:.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Soiked Samole continued
l..!ib ~Q: 1035540.
:Pil F~c: 1.0000 · Fiie JO:.· ·. A021822'7.D
.":tlllk"Conc :·cone .. %Rec Fla
20 16.6 83
20 19.3 97
20 8.40 42 0
20 17.4 87
20 20.7 104
20 16.4 82
20 13.0 65
20 17.4 87
20 18.8 94
20 17.9 90
20 21.3 107
20 13.I 65
100 103 103
20 I5.7 79
20 18.4 92
20 I8.6 93
20 I9.0 95
20 I9.7 98
20 17.4 87
20 21.0 105 •
20 10.l 50 (l
20 10.7 53 0
20 21.2 106
20 19.9 99
20 22.7 114
Note: Spike Concentration for solid matrices not adjusted for percent moisture.
SECTION V -Calibration and QC Information -02/24/2002 18:08
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STL Austin
Soiked Sample D r uo 1cate contmue d .. Lab ID: 1035521 ' .
'" '-,, · ·ac-Limits Oil Fae;;: 1.00QO ,
,,:~~j ·j~.:·;:· . ' File ID: A0218228.D ,'>:.'
'',,• .
SpkConc ·cone %Rec Fla RPO.Fla .. %Rec. RPO
20 16.7 83 0 70-130 25
20 20.9 105 7.9 75-131 14
20 15.4 77 59 0 46-150 34
20 16.7 84 3.5 22-164 34
20 20.7 104 0 . 70-130 25
20 20.5 102 22 ".; ..... 54-152 26
20 19.3 97 40 Q 41-165 28
20 17. i 88 1.1 7G-130 2)
20 17.8 89 5.5 70-130 25
20 17.8 89 I. I 27-149 36
20 21.1 105 1.9 36-I66 23
20 I7.4 87 29 0 32-172 22
100 IOI IOI 2 70-I30 25
20 20.4 102 25 ... 6I-143 28
20 20.0 100 8.3 68-I36 I4
20 I8.6 93 0 63-141 20
20 18.6 93 2. I 47-143 20
20 21.2 I06 7.8 69-137 16
20 19.3 97 I I
20 20.9 105 0 70-I32 17
20 16.3 82 48 Q 66-I40 20
20 I7.0 85 46 0 66-144 22
20 21.1 105 0.9 49-155 24
20 19.6 98 l 67-135 I7
20 23.2 I 16 1.7 71-129 17
Page 35 of 45
SECTIONV
Calibration and QC Information
Spiked Sample Results
MS-VOA
SW8260B
Parameter
Trichlorofluoromethane
1.2.3-Trichloronropane
l 1.2-Trichlorotrifluoroethane
I 2 4-Trimethvlbenzene
I 3 5-Trimethvlbenzene
Vinvl acetate
Vinvl chloride
n-Xvlene/m-Xvlene
o-Xvlene
Pare t f d n con mue
2029~osaof . Dii;F._c·'.<· -. · . .,. " ' ' 1.0000·.' ~' ' ' ~
Cone: ": .. ; s1t1:.
ND
ND
ND
ND
ND
ND
ND
ND
ND
s iniked Samnle continued
Lab 10: 1035520
011 Fae: 1.0000
Fila ID: A0218227.D
Sok Cone Cone %Rec Fla
20 26.4 132
20 19.0 95
20 21.5 107
20 15.7 78
20 15.3 76
20 16.2 81
20 23.6 ll8
40 38.1 95
20 19.0 95
Note: Spike Concentration for solid matrices not adjusted for percent moisture.
SECTION V -Calibration and QC Information -02/24/2002 18:08
LIMS Workorder: 80396913 [20202098) Hamilton Beach-Proctor Silex
STL Austin
Sniked amne un 1cate con mue S I D r f d
Lab ID: 1035521
Oil Fae: 1.0000 QQ Limits
File ID: A0218228.D : • • • ~ >
Sok Cone cone -%Rae Fla RPO· Fla 0kRec RPO
20 26.4 132 0 39-147 29
20 18.2 91 4.3 64-140 18
20 22.6 ll3 5.5
20 20.0 100 25 54-156 25
20 20.0 100 27 0 62-144 25
20 16.6 83 2.4 0.1-164 31
20 23.4 117 0.9 24-138 27
40 41.5 104 9 76-134 15
20 20.7 104 9 77-131 15
Page 36 of 45
-------------------
-------SECTIONV
Calibration and QC Information
Spiked Sample Results
MS-VOA
SW8260B
------------
Surroaate Comooiinds
Lab ID: 1035520 Lab ID: 1035521 ,,
: %Recov'erv
l-Bromo-4-fluorobenzene 97
I .2-Dichloroethane-d4 100
Toluene-ct& 104
Note: Spike Concentration for solid matrices not adjusted for percent moisture.
SECTION V -Calibration and QC Information -02/24/2002 J 8:08
LlMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STL Austin
Flaas %Reto:Verv Fla as QC Recoverv. Limits
98 77-117
100 61-143
104 87-113
Page 37 of 45
SECTIONV
Calibration and QC Information
Control Sample Results
MS-VOA
SW82608
Client Sample ID:
Prep Batch ID:
Analysis Batch ID:
Parameter
Acetone
Benzene
Bromobenzene
Bromochloromethane
LCS for HBN 16586 [MSV/1774]
16586
16586
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone <MEK)
n-Butvlbenzene
sec-Butvlbenzene
tert-Butvlbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1.2-Dibromo-3-chloroorooane.
Dibromochloromethane
I 2-Dibromoethane
Dibromomethane
I 4-Dichlorobenzene
SECTION V -Calibration and QC Information -02/24/2002 18:08
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STLAustin
Instrument ID: MSDA
Units: ug/L
Matrix: Aqueous
Control Samole
Lab ID: 1035517
File ID: A0218204.D
Sok Amt Cone %Rec Fig
20 16.6 83
20 22.5 112
20 19.7 99
20 20.6 103
20 19.7 99
20 19.4 97
20 18. l 91
20 17.2 86
20 21.3 106
20 20.6 103
20 20.3 101
20 18.4 92
20 19.8 99
20 20.4 102
20 20.3 102
20 20.2 101
20 17.5 88 •
20 19.9 100
20 20.2 101
20 18.3 91
20 20.8 104
20 21.0 105
20 20.5 102
20 20.1 IOI
Lab ID:
File ID:
SpkAmt
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
2Q__
20
20
20
20
% Moisture: NA
BJP Analyst:
r Control Samole Duo 1cate
1035518
A0218205.D
Cone %Rec Fla
19.0 95
21.6 108
19.0 95
19.5 98
18.6 93
17.5 87
16.9 85
14.7 73
20.6 103
19.9 99
19.6 98
17.7 89
19.1 96
19.8 99
19.9 99
19.1 95
16.6 83
18.8 94
19.4 97
16.2 81
19.8 99
19.7 98
19.2 96
19. I 95
QC Limits
RPO fig %Rec RPO
13 0.1-240 71
3.6 71-133 17
4.1 67-127 12
5 61-145 21
6.3 57-135 19
11 23-151 17
6.8 34-128 25
16 O.l-214 39
2.9 28-184 30
4 45-160 31
3 65-148 27
3.3 29-223 23
3.1 46-150 23
3 77-129 14
3 39-133 27
6.1 64-146 16
5.8 18-140 26
6.2 70-136 24
4 74-132 23
12 -·~39-ll!__25_
4.9 45-137 15
6.9 I 9-187 19
6. I 52-138 21
6. l 70-132 13
Page 38 of 45
-------------------
-------------------SECTIONV
Calibration and QC Information
Control Sample Results
MS-VOA
SW8260B
..
Parameter
I 2-Dichlorobenzene
I 3-Dichlorobenzene
Dichlorodifluoromethane
I 1-Dichloroethane
I 2-Dichloroethane
I 1-Dichloroethene
cis-1 2-Dichloroethene .
trans-1,2-Dichloroethene
I 2-Dichloroprooane
1,3-Dichloroorooane
2,2-Dichloroprooane
I 1-Dichloroorooene
cis-1,3-Dichloroorooene
trans-I 3-Dichloroorooene
Ethvlbenzene
Hexachloro-1 3-butadiene
2-Hexanone
Iodomethane
Isooroovlbenzene
4-lsopropyltoluene
4-Methvl-2-pentanone <MIBK)
Methylene chloride
Naohthalene
n-Proovlbenzene
Styrene
I I 1,2-Tetrachloroethane
I I 2,2-Tetrachloroethane
Tetrachloroethene
Toluene
I 2 3-Trichlorobenzene
I 2 4-Trichlorobenzene
-~ ~ (, ; J
" -~ ~-:-. .. . .. ' < "t , -'
SECTION V -Calibration and QC lnfonnation -02/24/2002 18:08
LIMS Workorder: 80396913 (20202098] Hamilton Beach-Proctor Silex
STLAustin
Lab ID:
File.ID:
· S'okAmt
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
Control Samnle continued
1935517 .. .
A0218204.D cone %Rec Fla
19.3 97
19.2 96
16.5 82
21.1 106
19.7 99
20.0 100
20.4 102
20.7 103
20.6 103
19.5 97
21.4 107
20.5 103
19.7 99
18.5 93
20.7 104
J9.5 98
18.4 92
19.6 98
20.l 100
21.l 105
18.7 94
20.2 101
18.8 94
20.8 104 '
20.6 103
J9. I 96
18.4 92
22.2 111
20.3 J02
18. J 90
19.3 97
Control Sample D r f d un 1cate con mue ·-. Lab ID: 1035518
File ID: A0218205.D · QC Limits
SpkAmt Cone %Rec.Fla RPO Fla ~oRec "RPO
20 18.4 92 5.3 67-135 14
20 18.8 94 2.1 68-134 14
20 15.7 78 5 0.1-166 26
20 19.6 98 7.8 ' 66-138 19
20 18.5 92 7.3 48-152 23
20 19.0 95 5.1 47-175 25
20 19.4 97 5 66-144 18
20 19.5 97 6 62-146 22
20 19.3 96 7 61-133 17
20 18.6 93 4.2 70-128 16
20 20.1 101 5.8 40-168 30
20 19.7 99 4 71-155 31
20 18.8 94 5.2 36-142 16
20 J8.0 90 3.3 34-J38 21
20 20.0 JOO 3.9 75-131 14
20 J8.8 94 4.2 46-150 34
20 J6.8 84 9.1 22-164 34
20 18.7 93 5.2 -· 20 J9.5 97 3 54-152 26
20 20.3 101 3.9 41-165 28
20 17.2 86 8.9 27-149 36
20 19. J 95 6.J 36-166 23
20 17.8 89 5.5 32-172 22
20 20.2 lOJ 2.9 61-143 28
20 19.9 99 4 68-J36 J4
20 J8.2 91 5.3 63-J41 20
20 17.5 88 4.4 47-J43 20
20 23.4 117 5.3 69-J37 J6
20 J9.9 JOO 2 70-132 J7
20 J7.3 87 3.4 66-J40 20
20 J8. J 91 6.4 66-144 22
Page 39 of 45
SECTIONV
Calibration and QC Information
Control Sample Results
MS-VOA
SW8260B
' Parameter
1.1.1-Trichloroethane
I. I 2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1.2.3-Trichloronrooane
1 2.4-Trimethvlbenzene
I 3 5-Trimethvlbenzene
Vinvl acetate
Vinvl chloride
o-X vlene/m-Xvlene
o-Xvlene
SECTION V -Calibration and QC Information -02/24/2002 18:08
LIMS Workorder: 80396913 [20202098) Hamilton Beach-Proctor Silex
STLAustin
Lab IP:
File ID:
Sok Amt
20
20
20
20
20
20
20
20
20
40
20
s Control amole continued
1035517 Lab ID:
A0218204.D File ID:
Cone %Rec Fla Sok.~mt
20.2 101 20
19.1 96 20
21.5 108 20
23.1 116 20
18.4 92 20
20.0 100 20
20.4 102 20
3.93 20 20
19.2 96 20
41.1 103 40
20.3 101 20
Control s r amo e Duo 1cate contmue d
1035518 _J QC l-imits A0218205.D
Cone %Rec Fla R.PD f ia %Rec RllD
19.3 96 5.1 49-155 24
18.3 92 4.3 67-135 17
20.7 104 3.8 71-129 17
22.1 111 4.4 39-147 29
17.9 90 2.2 64-140 18
19.3 96 4.1 54-156 25
19.7 98 4 62-144 25
3.64 18 11 0.1-164 31
18.3 92 4.3 24-138 27
39.3 98 5 76-134 15
19.4 97 4 77-131 15
Page 40 of 45
-------------------
-------------------SECTIONV
Calibration and QC Information
Control Sample Results
MS-VOA
SW82608
Surroaate Compounds
l-Bromo-4-fluorobenzene
I 2-Dichloroethane-d4
Toluene-d8
,· ~' . '"
.. '•
SECTION V -Calibration and QC lnfonnation -02/24/2002 18:08
LIMS Workorder: 80396913 (20202098] Hamilton Beach-Proctor Silex
STL Austin
Lab ID: 1035517
%Recoverv Flaas
101
103
106
Lab ID: 1035518 , < •'''
%Recoverv
.. Fla as QC Recove..V-UmitS
100 77-117
100 61-143
105 87-113
Page 41 of 45
SECTION VI
Batch Summaries
ExtractionlDigestion Batch Summary
MS-VOA
SW82608
Extraction Batch ID: 16586
. ,·
: Client Samole ID · · Lab Samole ID
INSTRUMENT QC 1000
INSTRUMENT QC 1406
LCS for HBN 16586 fMSV/17741 1035517
LCSD for HBN 16586 fMSV/17741 1035518
MB for HBN 16586 rMSV/17741 1035519
TRIP BLANK 2020209809 zzzzzzzzzz 2020208304
0202HBWW230 2020209801
0202HBWW226 2020209802
0202HBWD999 2020209803
0202HBWW220 2020209804
0202HBWW224 2020209805
0202HBWW225 2020209806
0202HBWW234 2020209807
0202HBWW222 2020209808 zzzzzzzzzz 2020206301 zzzzzzzzzz 2020208301 zzzzzzzzzz 2020208302 -zzzzzzzzzz 2020206501 zzzzzzzzzz 2020206701 zzzzzzzzzz 2020206301 zzzzzzzzzz 2020206601 zzzzzzzzzz 2020208303
0202HB WW230(2020209801 MS) 1035520
0202HBWW230(2020209801MSD) 1035521
INSTRUMENT QC 1000
INSTRUMENT QC 1406 zzzzzzzzzz 2020206601
SECTION VI -Batch Summaries -02/24/2002 18:08
I.IMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STL Austin
Start Date/Time:
Stop Date/Time:
02/18/2002 11 :08
02/19/2002 11:02
SamoleTvoe Matrix
GC/MS Tune Aqueous
Continuine: Calibration Check Aqueous
Lab Control Samoie Aqueous
Lab Control Samole Duplicate Aqueous
Method Blank Aqueous
Field Sample Aqueous
Field Samole Aqueous
Field Sample Aqueous
Field Samole Aqueous
Field Samole Aqueous
Field Samole Aqueous
Field Sample Aqueous
Field Samole Aqueous
Field Sample Aqueous
Field Samole Aqueous
Field Samole Aqueous
Field Sample Aqueous
Field Samole Aqueous
Field Sample Aqueous
Field Samole Aqueous
Field Sample • Aqueous
Field Samole Aqueous
Field Sample Aqueous
Matrix Soike Agueous
Matrix Spike Duplicate Aqueous
GC/MS Tune Aqueous
Continuinl! Calibration Check Aqueous
Field Sample Aqueous
Analyst: BJP
SamoleSize
Initial Final Preoaration Method
15 mL 15mL SW8260B
15 mL 15mL SW8260B
IS n1L 15 mL SW8260B
15 mL 15mL SW8260B
15 mL 15mL SW8260B
15mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15mL 15 mL SW8260B
15mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
Page 42 of 45
-------------------
SECTION VI
Batch Summaries
Analysis Batch Summary
MS-VOA
SW82608
Analysis Batch ID: 16586
Seauence Client Sample ID
1 INSTRUMENT OC
2 INSTRUMENT OC
-,
3 LCS for HBN 16586 rMSV/17741
4 LCSD for HBN 16586 rMSV/17741
5 MB for HBN 16586 rMSV/17741
6 TRIP BLANK
7 zzzzzzzzzz
8 0202HBWW230
9 0202HBWW226
10 0202HBWD999
11 0202HBWW220
12 0202HBWW224
13 0202HBWW225
14 0202HBWW234
15 0202HBWW222
16 zzzzzzzzzz
17 zzzzzzzzzz
18 zzzzzzzzzz
19 zzzzzzzzzz
20 zzzzzzzzzz
21 zzzzzzzzzz
22 zzzzzzzzzz
23 zzzzzzzzzz
24 0202HBWW230(202020980 IMS)
26 0202HBWW230(2020209801 MSD)
27 INSTRUMENT QC
28 INSTRUMENT OC
29 zzzzzzzzzz
30 zzzzzzzzzz
SECTION VI -Batch Summaries -02/24/2002 18:08
LIMS Workorder: 80396913 [20202098] Hamilton Beach-Proctor Silex
STL Austin
Instrument ID: MSDA Analyst: BJP
Anaiysis Sub-
Lab_ Samole ID Date Time SamoleTvoe Analysis File ID Batch ID
1000 02/18/2002 11:08:00 GC/MS Tune A0218203.D 0
1406 02/18/2002 11:08:00 Continuing Calibration Check A0218203:D 0
1035517 02/18/2002 11:36:00 Lab Control Sample A0218204.D 0
1035518 02/18/2002 12:04:00 Lab Control Sample Duplicate A0218205.D 0
1035519 02/18/2002 13:01 :00 Method Blank A0218207.D 0
2020209809 02/18/2002 13:29:00 Field Sample A0218208.D 0
2020208304 02/18/2002 13:57:00 Field Samole A0218209.D 0
2020209801 02/18/2002 14:26:00 Field Sample A0218210.D 0
2020209802 02/18/2002 14:54:00 Field Sample A0218211.D 0
2020209803 02/18/2002 15:22:00 Field Sample A0218212.D 0
2020209804 02/18/2002 15:51:00 Field Samole A0218213.D 0
2020209805 02/18/2002 16:19:00 Field Sample A0218214.D 0
2020209806 02/18/2002 16:47:00 Field Samole A0218215.D 0
2020209807 02/18/2002 17:15:00 Field Sample A0218216.D 0
2020209808 02/18/2002 17:43:00 Field Sample A0218217.D 0
2020206301 02/18/2002 18:12:00 Field Samole A0218218.D 0
2020208301 02/l8/2002 18:43:00 Field Sample A0218219.D 0
2020208302 02/18/2002 19:11:00 Field Samole A0218220.D 0
2020206501 02/18/2002 19:41:00 Field Sample A0218221.D 0
2020206701 02/18/2002 20:11:00 Field Samole A0218222.D 0
2020206301 02/18/2002 20:41:00 Field Sample A0218223.D 0
2020206601 02/18/2002 "21: 11 :00 Field Samole A0218224.D 0
2020208303 02/18/2002 21:41:00 Field Sample A0218225.D 0
1035520 02/18/2002 22:37:00 Matrix Soike A0218227.D 0
1035521 02/18/2002 23:06:00 Matrix Spike Duplicate A0218228.D 0
1000 02/19/2002 09:34:00 GC/MS Tune A0218230.D 0
1406 02/19/2002 09:34:00 Continuing Calibration Check A0218230.D 0
2020206601 02/19/2002 10:32:00 Field Samole A0218232.D 0
2020206501 02/19/2002 11:02:00 Field Sample A0218233.D 0
Page 44 of 45
-------------------
- -SECTION VII
Certifications
State/Agency
---
Arkansas Department of Environmental Quality
--- -- -
-,
California Environmental Laboratory Accreditation Program I Waste Water/Hazardous Waste
Connecticut Deoartment of Health/Waste Water/Trade Waste Sewage/Effluent Soil
Florida Department of Environmental Protection ComnOAP
Kansas Department of Health and Environment I Solid and Hazardous Waste
Louisiana Department of Environmental Quality ELAP I Waste Water/Hazardous Waste/Air Emissions
Montana Department ofEnvironmental_Quality/Petroleum Release Section
New Jersey Deoartment of Environmental Protection
New York State Department of Health /Waste Water/Hazardous Waste/Air
North Carolina Dept. of Natural Resources & Community Development I Waste Water
Oklahoma DeQ.artment of Environmental Quality/General Water Quality/Sludge
Rhode Island Deoartment of Health/Potable Water/Non-Potable and Waste Water
South Carolina Dept. of Health & Environmental Control
Tennessee UST
Texas(TNRCC)
Texas Department of Public Safety/Precursor Chemical and Lab Annaratus
Utah Department of Health I Solid and Hazardous Waste
Wisconsin Department ofNatural Resources
US Air Force/ AFC EE
US Army Corps ofEn!!ineers (MRD ACE)
US Department of Agriculture I Restricted Soils Permit
US Navy(NFESC)
SECTION VII -Certifications -02/24/2002 18:08
LIMS Workorder: 80396913 (20202098] Hamilton Beach-Proctor Silex
STLAustin
"
- --- ----
,, 'iD #
2411
PH-0761
OA Plan #900481
E-10165
Interim Accreditation
82005
10915
302
8720
127
82003
Participating Laboratory
3039
RADC
999885260
Participating Laboratory
Participating Laboratory
S-42350
Participating Laboratory
Page 45 of 45
Page2of2 I
4.0 CONDITION OF BOTTLES/CONTAINERf VERIFIED BY: ~
Samples received match COC: tYl YES [)No Bottles received in~ d~s nko I
See additional discrepancies/~omments section: D YES G'.f NO Samples received from USDA restricted area: D YES ~NO
VOA(_trip blanks included:@ YES D NO D N/A 4~A ~ I
5.0 ADDITIONAL DISCREPANCIES I
Appears on COC Appears on Label
Sample ID Date!fime Sample ID Dateffime Comments
6.0 SHIPPING DOCUMENTATION d YES D NO Air bill#:-----------Air/freight bill is available and attached to COC:
Hand-delivered Carrier: _________________ _ Date: _______ Time:------
7.0 OTHER COMMENTS:
~-cc..V 1 ~ 4 .~ J~ Oaj F0-Q,..--'l ~ ~blA ~k..I c..o C-CA I k J::=-PJC, gx/~
Client COC is signed, dated with time ofreceipt, and addendwn number is noted in the comments section. DYES
CORRECTIVE ACTION:
Client's Name: ----------Informed verbally on: -------By: ________ _
Client's Name: ----------Informed verbally on: ------By: ________ _
Sample(s) processed "as is" comments: -------------------------------
Samples(s) on hold until: -------------Ifreleased, notify: ------------
REVIEW:
C'\L Project Management: ----------------------++--:J __. I u_ 'v-· ~'.:( Date: _v,,_ __ r ___ '----
SIGNED ORIGINAL MUST BE RETAINED IN THE PROJECT FILE
Revised 12/8//2000
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