IDX GW Monitoring Report Nov 2000 (SF)-OCR

*6001HSSF1066*
1111111111111111111111111111
DocumentlD NONCD0001814
Site Name HAMILTON BEACH/PROCTOR SILEX
oocumentrype Progress/Monitoring Rpt (PRGMON)
RptSegment 1
DocDate
DocRcvd
Box
Accesslevel
Division
Section
Program
DocCat
1/4/2001
2/20/2007
SF1066
PUBLIC
WASTE MANAGEMENT
SUPERFUND
IHS (IHS}
FACILITY
January 4, 2001 . I
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. JI ~
Mr. Willie Hardison I [ JAN -5 2001
I North Carolina Department of Environ]jhentWI :. lti · • · ·
and Natural Resources t___ ____ _
934 Washington Square Mall
Washington, North Carolina 27889
RE: Groundwater Monitoring Report for November 2000
Groundwater Incident No. 14338
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Dear Mr. Hardison:
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Mailing Address:
Post Office Box 13000
Research Triangle Park,
North Carolina 27709
Physical! Shipping Address:
1600 Perimeter Park Drive
Morrisville, North Carolina 27560
919 4611100 Tel
919 4611415 Fax
On behalf of Hamilton Beach<> Proctor-Silex, Inc., Radian International is submitting one
copy of the referenced report.
If you have any questions, please contact Mario Kuhar at [phone]
Sincerely,
RADIAN INTERNATIONAL
~~
Craig L. Kennedy, L.G.
Geologist
CK:Ia.cvr_ltr.doc
Enclosure
cc: Mario Kuhar, Hamilton BeachOProctor-Silex
Bradford A. De Vore, Womble Carlyle Sandridge & Rice
Project File
Engineering Services in North Carolina are performed through Radian lntemational's wholly owned subsidiary, Radian Engineering, Inc.
Offices Worldwide
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~ IQ! RADIAN INTERNATIONAL
~ A DAMES&. MOORE GROUP COMPANY
GROUNDWATER
MONITORING REPORT
FOR NOVEMBER 2000
Hamilton Beach OProctor-Silex, Inc.
Washington, North Carolina Facility
..----·-,,,_ ..... -~---_·-·-
! r-·,, [r \pl rs n "" '1'· i I ,.,. I i_s ~ i~ ·' \: -~ : ~ ---·------. --· ,
! JAN - 5 2001 \ ~ ... :· ....
I L .. --------·--· ______ 1 \1
i W~.SHINGTON RCGIONAL Of FICE l____ D\'_'.~ ---·-__ J
Prepared for:
Hamilton Beach <>Proctor-Silex, Inc.
4421 Waterfront Drive
Glen Allen, Virginia 23060
Prepared by:
Radian International
1600 Perimeter Park Drive
Morrisville, North Carolina 27709
January 2001
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GROUNDWATER MONITORING REPORT
FOR NOVEMBER 2000
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Groundwater Incident No. 14338
Site Priority Ranking B
Prepared for:
Hamilton Beach<>Proctor-Silex, Inc.
4421 Waterfront Drove
Glen Allen, Virginia 23060
Prepa;red by:
Radian International
P.O. Box 13000
Research Triangle Park, North Carolina 27709
January 2001
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CERTIFICATION PAGE
GROUNDWATER MONITORING REPORT
FOR NOVEMBER 2000
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Groundwater Incident No. 14338
Site Priority Ranking B
I, Craig L. Kennedy, a Licensed Geologist in the State of North Carolina, certify that
this report and its contents have been prepared under my direct control and personal
superv1s10n.
80396906.0 I Nov2000GW _ Rpt.doc (01/04/0 l) 11
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TABLE OF CONTENTS
Certification Page ................................................................................................................ ii
List of Figures .................................................................................................................... iv
List of Tables ...................................................................................................................... v
1.0 INTRODUCTION ........................................................................................................... 1-1
2.0 FIELD METHODS .......................................................................................................... 2-1
3.0 RESULTS ........................................................................................................................ 3-1
3 .1 Water Level Measurements ................................................................................. 3-1
3 .2 Analytical Results ................................................................................................ 3-1
APPENDIX A GROUNDWATER SAMPLING ANALYTICAL REPORTS
80396906.01 Nov2000GW _Rpt.doc (01/04/01) iii
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LIST OF FIGURES
1-1 Topographic Map, Hamilton Beach<>Proctor-Silex, Inc.
2-1 Site Map, Washington Facility, Hamilton Beach<>Proctor-Silex, Inc.
3-1 Generalized Groundwater Flow Direction for Hydrogeologic Unit A, Washington Facility
3-2 Generalized Groundwater Flow Direction for Hydrogeologic Unit B, Washington Facility
3-3 Location of Surrounding Water Supply Wells
80396906.01 Nov2000GW_Rpt.doc (01/04/01) iv
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2-1
3-1
3-2
3-3
3-4
LIST OF TABLES
Monitoring Well Construction Data for Sampled Wells
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
Water Level Measurements and Elevations, November 28, 2000
Hamilton Beach<> Proctor-Silex, Inc., Washington, North Carolina
Historical Water Level Elevations at MW-220
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
Historical Water Level Elevations at MW-222
Hamilton ~each<>Proctor-Silex, Inc., Washington, North Carolina
Historical Water Level Elevations at MW-224
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
3-5 Historical Water Level Elevations at MW-225
Hamilton BeachOProctor-Silex, Inc., Washington, North Carolina
3-6 Historical Water Level Elevations at MW-226
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
3-7 Historical Water Level Elevations at MW-230
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
3-8 Historical Water Level Elevations at MW-234
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
3-9 Field Measurements, November 28, 2000
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
3-10 Summary of Qualified Groundwater Analytical Results: November 2000
Volatile Organic Compounds by Method 8260B
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
3-11 Historical Analytical Results for MW-220
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
3-12 Historical Analytical Results forMW-222
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
3-13 Historical Analytical Results for MW-224
Hamilton BeachOProctor-Silex, Inc., Washington, North Carolina
80396906.01 Nov2000GW _Rpt.doc (01/04/01) v
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LIST OF TABLES (Continued)
3-14 Historical Analytical Results for MW-225
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
3-15 Historical Analytical Results for MW-226
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
3-16 Historical Analytical Results for MW-230
Hamilton Beach<> Proctor-Silex, Inc., Washington, North Carolina
3-17 Historical Analytical Results for MW-234
Hamilton Beach<>Proctor-Silex, Inc., Washington, North Carolina
80396906.0 I Nov2000GW _Rpt.doc (01/04/0 I) Vl
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1.0 INTRODUCTION
The Hamilton BeachOProctor-Silex (HBO PS) facility is located at 234 Springs
Road, north of the City of Washington, in Beaufort County, North Carolina (Figure 1-1). The
facility and surrounding land parcel are owned by the City of Washington and have been leased
by HBoPS since 1990 and previously leased by predecessor companies. The facility was
formerly involved in the final assembly, packaging, and warehousing of small electrical
household appliances. I
I Since 1992, when organic compounds wer~ initially detected in groundwater at
the site, several phases of investigation have been performed, including a comprehensive site I assessment (CSA). The results of the CSA indicated that a plume of organic compounds is
present in groundwater underlying the site. The specific nature, volume, and time period of any
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releases contributing to the plume are unknown. However, the principal constituents of the
plume are no longer used at the facility.
A plan for corrective action at the site has been proposed. Until corrective action
is implemented, groundwater will be sampled and analyzed on a quarterly schedule according to
a monitoring program requested by the North Carolina Department of Environment and Natural ---Resources, Groundwater Section. Quarterly groundwater monitoring is to be conducted in
February, May, August, and November at seven wells: MW-220, -222, -2_24, -225, -226, -230,
and -234. These monitor:ing wells are located outside of the contaminant plume. In February -~
and August, six additional wells: MW-213, -214, ~_215, -216, -227, and-228 will be sampled.
These wells are located within the contaminant plume. The purpose of the monitoring program
is to detect potential migration of the plume.
Radian International (Radian) conducted groundwater sampling_at the facility on
November 28, 2090. The sampling event included the measurement of water levels,
temperature, pH, and specific conductance; and the collection and analysis of samples from
seven monitoring wells. This report describes the sampling methods and presents the results for
the ql;larterly sampling event.
80396906.01 Nov2000GW _Rpt.doc (01/04/01) 1-1
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2.0 FIELD METHODS
Groundwater was sampled on November 28, 2000, in general accordance with the
methods outlined in the Field Sampling and Analysis Plan prepared in April 1997 for this site.
Seven monitoring wells were sampled. They included MW-220, MW-222,
MW-224, MW-225, MW-226, MW-230, and MW-234. The locations of the monitoring wells
are shown in Figure 2-1. Details of well construction are provided in Table 2-1.
Prior to sampling, the water level in each well was measured using an electric
water-level indicator. The wells were then purged using inertial foot-valve pumps. Temperature,
pH, and specific conductance were measured and the data were recorded in a field notebook.
Purging continued until temperature, pH, and specific conductance stabilized; a minimum of
three well volumes was extracted; or the well was pumped dry. Each of the welis was then
sampled immediately following well purging using the inertial foot-valve pump. For QNQC
purposes, a duplicate sample was collected at well MW-226.
The groundwater samples were sent by overnight courier to STL in Austin, Texas,
for analysis of volatile organic compounds by EPA Method 8260B.
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3.0 RESULTS
3.1 Water Level Measurements
Table 3-1 presents the depth to groundwater and static water-level elevations
measured in the seven wells .sampled and several additional wells. Maps showing the
generalized direction of groundwater flow in hydrogeologic units A and Bare included as
Figures 3-1 and 3-2, respectively. Historical water-level elevations in sampled wells are
included in Tables 3-2 to 3-8.
3.2 Analytical Results
Field measurements of water temperature, pH, and specific conductance are
summarized in Table 3-9. Qualified analytical results are summarized in Table 3-10. Qualified
data sheets and laboratory reports are included in Appendix A.
No analytes were detected above the groundwater standards in samples from
wells located near the perimeter of the site (MW-220, MW-222, MW-224, MW-225, MW-230,
and MW-234), nor were any analytes detected above the groundwater standards in the sample
from well MW-226, which is completed in the confined Limestone Aquifer.
Historical analytical results for the sampled wells are presented in Tables 3-11 to
3-17. A comparison of the record for wells located near the perimeter of the site suggests that
the plume remains on-site, at least 200 feet from potential receptors located north of Spring Road
(Figure 3-3).
80396906.01 Nov2000GW_Rpt.doc (01/04/01) 3-1
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FIGURES
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TABLES
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------------------·---
Table 2-1
Monitoring Well Construction Data for Sampled Wells
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Top of Casing
Installation Elevation Total Depth Screen Interval Filter Pack Bentonite Seal
Well No. Date (ft. above MSL) (ft. be:s) (ft. bgs)
MW-220 5/5/98 31.50 34 25 -34
MW-222 5/6/98 35.11 40 31 -40
MW-224 11113/98 33.43 34 25 -34
MW-225 11/13/98 33.43 10 4-10
MW-226 9/30/98 28.46 75 70-75
MW-230 10/26/98 33.47 14 8 -14
MW-234 6/23/99 35.03 26 17 -26
Monitoring wells 220 and 222 were installed by Radian Mobile Field Services.
Monitoring wells 226 was installed by Parratt Wolff, Inc.
Monitoring wells 224, 225, 230, and 234 were installed by Probe Technology, Inc.
80396906.0 I Nov2000GW _Rpt.doc (01/04/0 I)
(ft. be:s) (ft. bgs)
24-34 23 -24
30-40 29-30
24-34 23 -24
3 -10 2-3
69-75 67-69
7 -14 5-7
16-26 13 -16
Grout Seal
(ft. be:s)
0 23
0-29
0 -23
0-2
0-67
0-5
0-13
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Table 3-3
Historical Water Level Elevations at MW-222
Hamilton BeachOProctor-Silex, Inc.
Washin~ton, North Carolina
Water Level Elevation
Date (ft. above msl)
May 13, 1998 22.34
November 16, 1998 19.99
July 1, 1999 20.61
October 20, 1999 24.22
February 2, 2000 23.34
May 2, 2000 . 23.58
September 6, 2000 21.50
November 28, 2000 20.52
msl = mean sea level
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Table 3-4
Historical Water Level Elevations at MW-224
Hamilton Beach¢Proctor-Silex, Inc.
Washington, North Carolina
Date
May 13, 1998
November 16, 1998
July 1, 1999
October 20, 1999
February 2, 2000
May2, 2000
September 6, 2000
November 28, 2000
msl = mean sea level
NM =Not measured
80396906.0 I Nov2000GW _Rpt.doc (01/04/0 I)
Water Level Elevation
(ft. above msl)
NM
23.64
24.39
26.88
26.73
26.48
25.99
24.36
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Table 3-5
Historical Water Level Elevations at MW-225
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Date
May 13, 1998
November 16, 1998
July 1, 1999
October 20, 1999
February 2, 2000
Mav2, 2000
September 6, 2000
November 28, 2000
msl = mean sea level
NM= Not measured
80396906.01 Nov2000GW _Rpt.doc (01/04/01)
Water Level Elevation
(ft. above msl)
NM
24.36
24.50
27.24
26.59
26.40
27.22
24.38
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Table 3-7
Historical Water Level Elevations at MW-230
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Date
Mav 13, 1998
November 16, 1998
July 1, 1999
October 20, 1999
February 2, 2000
May2, 2000
September 6, 2000
November 28, 2000
msl = mean sea level
NM = Not measured
80396906.0 I Nov2000GW _Rptdoc (01104/0 I)
Water Level Elevation
(ft. above msl)
NM
21.14
21.80
27.71
27.44
26.53
23.07
21.87
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Table 3-8
Historical Water Level Elevations at MW-234
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Date
May 13, 1998
. November 16, 1998
July 1, 1999
October 20, 1999
February 2, 2000
May 2, 2000
September 6, 2000
November 28, 2000
msl = mean sea level
NM= Not measured
Water Level Elevation
(ft. above msl)
NM
NM
23.24
25.71
25.67
25.56
25.04
23.23
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-----~~--~~--~~~--~
Well Date Time
MW-220 11/28/00 13:00
MW-222 11128/00 14:25
MW-224 11/28/00 13:27
MW-225 11128/00 13:23
12:18
12:23
MW-226 11128/00 12:28
12:33
12:38
MW-230 11128/00 11:05
MW-234 11128/00 14:00
80396906.0 I Nov2000GW _Rpt.doc (0110410 I)
Table 3-9
Field Measurements
November 28, 2000
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Volume Purge~
(Gall Pun?:inl!: Criteria
0.75 3 well volumes
0.75 3 well volumes
0.75 3 well volumes
0.01 Drv
9.0
15.0
18.0 Stabilized parameters
20.0
22.0
0.07 Drv
0.5 3 well volumes
Specific
Temperature Conductance
(oC) (µS) pH
17.5 120 6.1
16.5 355 6.9
16.5 315 7.2
16.0 220 4.4
18.5 465 7.2
18.0 470 7.3
18.0 470 7.4
18.0 460 7.5
18.0 460 7.5
14.0 190 4.1
17.0 150 5.9
-------~~-~~-~~~-~~
Groundwater May
Analyte Standard 1998
Carbon disulfide 700 ND (0.0547)
Methyl t-butyl ether 200 ND (0.0365)
Target analytes not listed were not detected.
All results reported in micrograms per liter.
J = Estimated value.
ND= Not detected at (detection limit).
UJ = Not detected and the detection limit is estimated.
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Table 3-11
Historical Analytical Results for MW-220
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
November July October February
1998 1999 1999 2000
ND (0.0547) 0.426 J ( 0.162)' ND (0.0484) UJ
ND (0.0365) UJ .·ND (0.0334) :NU"(cr.0512) ND (0.0469)
May September November
2000 2000 2000
ND (0.0484) ND (0.0484)UJ ND (0.0684) -
0.441 J ND (0.0469) ND (0.116)
---~--~--~~~-~--~-~
Groundwater
Analyte Standard
Carbon disulfide 700
1, 1-Dichloroethane 700
1, 1-Dichloroethene 7
cis-1,2-Dichloroethene 70
Toluene 1,000
Target analytes not listed were not detected.
All results reported in micrograms per liter.
J = Estimated value.
ND= Not detected at (detection limit).
May
1998
ND (0.0547)
ND (0.0576)
0.0908 J
ND (0.0383)
0.156 J
UJ = Not detected and the detection limit is estimated.
Table 3-12
Historical Analytical Results for MW-222
Hamilton BeachOProctor-Silex,. Inc.
Washington, North Carolina
November July Oi;tober February
1998 1999 1999 2000
ND (0.0547) 0.388 J 0.0944 ND (0.0484) UJ
ND (0.0576) ND (0.0736) ND (0.0588) ND (0.0487)
ND (0.0715) ND (0.102) ND (0.0819) ND (0.0697)
ND (0.223) U ND (0.0595) ND (0.0407) ND (0.0603)
ND (0.0522) ND (0.0766) ND (0.0645) ND (0.0680)
U = Not present above the associated level, blank contamination present.
80396906.0 I Nov2000GW _Rpt.doc (0110410 I)
May September November
2000 2000 2000
ND (0.0484) ND (0.0484) UJ ND (0.0684)
0.338 J 0.328 J ND (0.124)
ND (0.279) U 0.0766 J 0.,0668 J
ND (0.0603) 0.139 J 0.124 J
ND (0.0680) ND (0.0680) ND (0.137)
--~---~---~----~~~-
Groundwater
Analvte Standard
Table 3-13
Historical Analytical Results for MW-224
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
November July October February
1998 1999 1999 2000
May
2000
Carbon disulfide 700 ND (0.0547) 2.22 2.72 ND (1.05) UJ ND<0.334)U
Toluene 1,000 ND (0.0522)
Target analytes not listed were not detected.
All results reported in micrograms per liter.
J = Estimated value.
ND =Not detected at (detection limit).
UJ = Not detected and the detection limit is estimated.
80396906:01 Nov2000GW _Rpt.doc (01/04/01)
ND (0.0766) ND (0.0645) ND (0.0680) 0.0542 J
September November
2000 2000
0.350 J 0.697 J
ND <0.0680) ND <0.0637)
---------~~----~---
Table 3-14
Historical Analytical Results for MW-225
Hamilton BeachOProctor-Silex, Inc.
Groundwater November
Analvte Standard 1998
Carbon disulfide 700 ND (0.0547)
Chloroform 0.19 ND (0.0480)
Target analytes not listed were not detected.
All results reported in micrograms per liter.
ND= Not detected at (detection limit).
NS = Not sampled.
UJ = Not detected and the detection limit is estimated.
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Washington, North Carolina
July October February
1999 1999 2000 Mav2000
ND C0.864) 0.0691 ND (0.0484) UJ ND (0.0484)
ND (0.0424) 0.171 ND (0.0670) ND70.0670)
September November
2000 2000
ND (0.0484) UJ ND (0.0684)
ND (0.0670) ND (0.0896)
------~---~--------
Groundwater
Analvte Standard
Table 3-15
Historical Analytical Results for MW-226
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
November July October February
1998 1999 1999 200
May
2000
Carbon disulfide 700 ND (0.0547) ND (0.864) 0.0950 ND (0.0484) UJ ND (0.0484) UJ
Target analytes not listed were not detected.
All results reported in micrograms per liter.
J = Estimated value.
ND= Not detected at (detection limit).
UJ = Not detected and the detection limit is estiIJ!ated.
80396906.01 Nov2000GW _Rpt.doc (01/04/01)
September November
2000 2000
0.210 J ND <0.0684)
-------------------
Groundwater
Analyte Standard
1, 1-Dichloroethane 700
1, 1-Dichloroethene 7
Cis-1,2-Dichloroethene 70
Toluene 1,000
Trichloroethene 2.8
Target analytes not listed were not detected.
All results reported in micrograms per liter.
J = Estimated value.
ND= Not detected at (detection limit).
Table 3-16
Historical Analytical Results for MW-230
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
November July October February
1998 1999 1999 2000
ND (0.0576) ND (0.0736) 0.265 0.189 J
ND (0.306)U ND (Q.102) 0.133 0.148 J
ND (2.67) U ND (0.0595) 0.304 0.354 J
ND (0.0522) 0.286 ND (0.309) U 0.284 J
ND (2.05)U ND (0.0929) 0.921 0.661 J
U = Not present above the associated level; blank contamination is present.
80396906.0 I Nov2000GW _ Rpt.doc (0I10410 I)
May · September _ November
2000 2000 2000
ND (0.348) U ND (0.0487) ND (0.124)
0.593 ND (0.0697) ND (0.122)
0.573 0.102 J 0.142 J
0.0826 J 0.126 J ND (0.0637)
1.11 ND (0.355) U 0.235 J
-------------------
Groundwater
Analvte Standard
Carbon disulfide 700
l, 1-Dichloroethene 7
Target analytes not listed were not detected.
All results reported in micrograms per liter.
J = Estimated value.
ND= Not detected at (detection limit).
Table 3-17
Historical Analytical Results for MW-234
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
July October February May
1999 1999 2000 2000
ND C0.864) 0.0600 ND (0.0484) UJ ND <0.0484)
ND C0.102) ND (0.0819) ND (0.0697) 0.145 J
UJ = Not detected and the detection limit is estimated.
80396906.01 Nov2000GW _Rpt.doc (01/04/01)
September November
2000 2000
ND <0.0484) UJ ND <0.0684)
ND <0.0697) ND <0.122)
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APPENDIX A
GROUNDWATER SAMPLING ANALYTICAL REPORTS
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QUALIFIED DATA
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Introduction
Hamilton Beach<>Proctor-Silex, Washington, NC
Data Validation Report
URS-Radian, December 2000
URS-Radian collected eight groundwater samples (l lOOHBWW-220, -222, -224 through -226,
-230, and -234) and a field duplicate at the Hamilton Beach<> Proctor Silex facility in
Washington, NC on November 28, 2000. The samples were submitted to Severn Trent
Laboratories (STL) in Austin, Texas for the determination of volatile organic compounds (VOC)
by SW-846 Method 8260B. A trip blank was included with the shipment of samples to the
laboratory for the analysis ofVOC.
URS-Radian reviewed the analytical results, which were reported by the laboratory under work
order number 20011217. The data evaluation was modeled after the National Functional
Guidelines for Organic Data Review (EPA, October 1999). Accuracy was determined from the
review of holding times, spike recoveries, tuning result, continuing calibration results, and blank
contamination. Precision was based on the evaluation of field and laboratory duplicate results.
Sample results have been appropriately qualified based on the criteria of the data review process.
The results of the data review are summarized below.
Sample Condition upon Receipt and Holding Times
All samples were received intact and in good condition by STL on November 29, 2000. The
temperature of the sample containers upon receipt at the labor~tory was within laboratory
specification limits of 2-6°C. Air bubbles were not observed in any volatile organic analysis
(VOA) vials.
Technical hold times were assessed by comparing the sampling dates with that of the analysis
date. Samples were analyzed for VOC within EPA-established holding times of seven days for
unpreserved samples.
Calibration
Gas chromatograph/mass spectrometer (GC/MS) instrument tuning and performance checks are
performed to ensure the instrument's ability to provide appropriate mass-resolution,
identification, and sensitivity. All samples were analyzed for VOC within twelve hours of the
performance check standard. The tuning compound mass-ion abundance criteria for the VOA
were reported within control limits.
Control limits for initial and continuing calibrations are established to ensure that the instrument
is capable of producing accurate quantitative and qualitative data at the beginning and
throughout each of the analyses. Since the results of the initial calibration were not included in
the laboratory report, the evaluation was based on the review of the November 30 @09:01
continuing calibration data. Laboratory specifications were met during the volatile organic
1100 HB-PS Wash DE.doc
12/19/00
Page 1 of3
continuing calibration conducted on instrument MSDA; however, project specifications of 80-
120% recovery were not met for bromoform (76%), 2-butanone (127%), 4-methyl-2-pentanone
(126%), tetrahydrofuran (125%), and vinyl acetate (138%). Results for compounds where the
recovery was less than 80% during the continuing calibration have been qualified as estimated
(J, UJ) in associated samples. Positive sample results were qualified as estimated (J) when the
recovery exceeded 120% in the continuing calibration.
Blank Contamination
Laboratory blanks are clean liquid and/or solid matrix samples prepared by the analytical
laboratory and analyzed in the same manner as the field samples. Laboratory blanks are used to
ensure that the field samples are not contaminated during the sample preparation, sample
analysis, or from previous samples (instrument carry-over). Trip blanks are analyte-free water
samples that accompany volatile investigative samples during all stages of shipment, storage, and
analysis. The trip blanks are used to assess the potential for artificial introduction of volatile
compounds into the investigative samples during the transportation and sample handling
processes. voe were not detected in the method and trip blanks.
Surrogate Spikes
Surrogate compound percent recoveries are used to assess extraction efficiencies, possible matrix
effects, and overall analytical accuracy during organic analyses. Acceptable sample results were
obtained for the surrogate spikes during the VOA of all samples.
Laboratory Control Samples
Laboratory control samples (LCS) are blank samples fortified (spiked) with known
concentrations of analyte of interest. The percent recoveries and/or duplicate results of the LCS
and their duplicates are used to asse~s extraction efficiencies and overall analytical accuracy and
precision.
Laboratory specifications were met during the LCS analysis of November 29; however, project1
specifications were not met for vinyl acetate. The LCS and LCSD recovery for vinyl acetate was
8.1 and 8.3%, which is less than project specification limits but within laboratory specifications
(0. l-164%R). Non-detect sample results for vinyl acetate were qualified as unusable (R).
Matrix Spikes
Matrix spikes (MS) are samples spiked with known concentrations of analytes of interest. MS
percent recoveries and duplicate results are used to assess extraction efficiencies, possible matrix
effects, and overall analytical accuracy and precision. ·
A batch sample was selected for the MS and MS duplicate VOA. Therefore, an evaluation of
matrix interference is not possible since the results of the batch sample may not be representative
of conditions at the site.
1 The recovery of either the LCS or LCSD must be within 60-140%.
1100 HB-PS Wash DE.doc
12/19/00
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Field Duplicates
Field duplicate samples are used to demonstrate acceptable precision during the sample
collection process. Acceptable precision was observed during the analysis of field duplicate
samples 1100HBWW226andl100HBWWD999. •
Sample Results
The laboratory provided volatile organic results for all North Carolina groundwater quality
standards presented in 15A NCAC 2L.0202. Detection limits were less than or equal to Class
GA standard or practical quantitation limits.
The laboratory flagged sample results less than the practical quantitation limit and sample
detection limit with a J and U, respectively. All positive sample results that are less than the
practical quantitation limit are considered estimated (J).
1100 HB-PS Wash DE.doc
12/19/00
Page 3.of3
-------------------SECTION IV
Analytical Results
MS-VOA
SW8260B
Parameter
Acetone
Acetonitrile
Acrolein
Acrvlonitrile
Benzene
Bromobenzene
Bromochlorometnane
Bromodichloromethane
Bromoform
Brom om ethane
2-Butanone (MEK)
n-Butvlbenzene
sec-Butvlbenzene
tert-Butvlbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1 3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
CAS
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
SECTION IV -Analytical Results, 12/04/2000 15:24
11 OOHBWW220
2001121701
Aaueous
Received
NA
11/28/2000 13:05
11/30/2000 10:58
11/30/2000 10:58
1.0000
MSDA
ug/L
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND lA.:S
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
DL RL
0.438 0.000
6.82 0.000
3.79 0.000
0.446 0.000
0.0641 0.000
0.0998 0.000
0.131 0.000
0.118 0.000
0.170 0.000
0.199 . 0.000
0.200 0.000
0.102 0.000
0.105 0.000
0.0911 0.000
/'0.0684.,. 0.000 ..... ~ ' 0.000 IT.U0:1/.
0.114 0.000
0.0842 0.000
0.0925 0.000
0.0896 0.000
0.0938 0.000
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l 100HBWW222 l 100HBWW224
2001121702 2001121703
Aaueous Aaueous
Received 'Received
NA NA
11/28/2000 14:25 11/28/2000 13:30
11130/2000 11 :26 11/30/2000 11 :54
11/30/2000 11 :26 11/30/2000 11:54
1.0000 1.0000
MSDA MSDA
ug/L u2/L
Cone Flag DL RL Cone Flag DL RL
ND 0.438 0.000 ND 0.438 0.000
ND 6.82 0.000 ND 6.82 0.000
ND 3.79 0.000 ND 3.79 0.000
ND 0.446 0.000 ND 0.446 0.000
ND 0.0641 0.000 ND 0.0641 0.000
ND 0.0998 0.000 ND 0.0998 0.000
ND 0.131 0.000 ND 0.131 0.000
ND 0.118 0.000 ND 0.118 0.000
ND \}...J 0.170 0.000 ND \,\..:S 0.170 0.000 .
ND 0.199 0.000 ND 0.199 0.000
ND 0.200 0.000 ND 0.200 0.000
ND 0.102 0.000 ND 0.102 0.000
ND 0.105 0.000 ND 0.105 0.000
ND 0.0911 0.000 ND 0.0911 0.000
ND 0.0684 0.000 0.697 J 0.0684 0.000
ND 0.0652 0.000 ND 0.0652 0.000
ND 0.114 0.000 ND 0.114 0.000
ND 0.0842 0.000 ND 0.0842 0.000
ND 0.0925 0.000 ND 0.0925 0.000
ND 0.0896 0.000 ND 0.0896 0.000
ND 0.0938 0.000 ND 0.0938 0.000
STPP!t~finesu/ts have been qualified by Radilm !111ematio11a/ based 011 the criteria oj the datt1 re1'iew process. which is modeled after the ( 'oll(ract l.aboratu1J' Program Natio11t1/ F1111ctio11al G11idC'li11es jipag\!:\!411ic 11111br 39
Inorganic Daw Review (U.:C.'. EPA. October 1999 .11111 •·. '•mmJ' 1994, respectii·e(i•J
SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
Chloromethane
3-Chloroorooene
2-Chlorotoluene
4-Chlorotoluene
Client Sample ID
Lab Sample ID
CAS
74-87-3
107-05-1
95-49-8
106-43-4
1.2-Dibromo-3-chloropropane 96-12-8
Dibromochloromethane 124-48-1
1.2-Dibromoethane 106-93-4
Dibromomethane 74-95-3
trans-I 4-Dichloro-2-butene 110-57-6
1 .4-Dich lorobenzene 106-46-7
1.2-Dichlorobenzene 95-50-1
1,3-Dichlorobenzene 541-73-1
Dichlorodifluoromethane 75-71-8
l .1-Dich1oroettiane 75-34-3
1,2-Dichloroethane 107-06-2
1.1-Dichloroethene 75-35-4
cis-1.2-Dichloroethene 156-59-2
trans-1 2-Dichloroethene 156-60-5
1 2-Dichloroorooane 78-87-5
1 3-Dichloroprooane 142-28-9
2 2-Dichloropropane 594-20-7
1 1-Dichloroorooene 563-58-6
cis-1 3-Dichloroorooene 10061-01-5
trans-1.3-Dichloroorooene 10061-02-6
Ethvl methacrvlate 97-63-2
Ethvlbenzene 100-41-4
Hexachloro-1 3-butadiene 87-68-3
2-Hexanone 591-78-6
SECTION IV -Analytical Results -12/04/2000 15:24
11 OOHBWW220
2001121701
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.426 J
ND
ND
ND
ND.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
I '
1100HBWW222 1100HBWW224
2001121702 2001121703
DL RL Cone Flaa DL RL Cone Flaa DL RL
0.127 0.000 ND 0.127 0.000 ND 0.127 0.000
0.0777 0.000 ND 0.0777 0.000 ND 0.0777 0.000
0.178 0.000 ND 0.178 0.000 ND 0.178 0.000
0.0974 0.000 ND 0.0974 0.000 ND 0.0974 0.000
0.548 0.000 ND 0.548 0.000 ND 0.548 0.000
0.140 0.000 ND 0.140 0.000 ND 0.140 0.000
0.137 0.000 ND 0.137 0.000 ND 0.137 0.000
0.148 0.000 ND 0.148 0.000 ND 0.148 0.000
0.780 0.000 ND 0.780 0.000 ND 0.780 0.000
0.150 0.000 ND 0.150 0.000 ND 0.150 0.000
0.0965 0.000 ND 0.0965 0.000 ND 0.0965 0.000
0.0846 0.000 ND 0.0846 0.000 ND 0.0846 0.000
0.237 0.000 ND 0.237 0.000 ND 0.237 0.000
0.124 0.000 ND 0.124 0.000 ND 0.124 0.000
0.102 0.000 ND 0.102 0.000 ND 0.102 0.000
0.122 0.000 0.0668 Jd:r 0.122 0.000 ND 0.122 0.000
0.112 0.000 0.124 J 0.112 0.000 ND 0.112 0.000
0.119 0.000 ND 0.119 0.000 ND 0.119 0.000
0.0869 0.000 ND 0.0869 0.000 ND 0.0869 0.000
0.135 0.000 ND 0.135 0.000 ND 0.135 0.000
0.160 0.000 ND 0.160 0.000 ND 0.160 0.000
0.0994 0.000 ND 0.0994 0.000 ND 0.0994 0.000
0.0818 0.000 ND 0.0818 0.000 ND 0.0818 0.000
0.0908 0.000 ND 0.0908 0.000 ND 0.0908 0.000
0.101 0.000 ND 0.101 0.000 ND 0.101 0.000
0.136 0.000 ND 0.136 0.000 ND 0.136 0.000
0.331 0.000 ND 0.331 0.000 ND 0.331 0.000
0.169 0.000 ND 0.169 0.000 ND 0.169 0.000
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
ST~·"~G"i·res11/ts have been q1111/ijied by Rmlit111 b11ema1iomd based 011 1/re cri1eri11 of 1/re d111a review procels, 11•/ric/r fa modeled after /he Cv111mc1 I.abornlv1J' /'rvgrm11 Na1io1111/ F1111c1io11al Ci111dl'li11es J1ip·. 01;g~11ic mu/ f 39 1iiorg~11m· D11111 Review (U.S. EPA. Oc10ber 1999 and Febr11mJ' /994. respec1i1•ezvJ age 0
-~-----------------
--·-----------------SECTION IV
Analytical Results
MS-VOA
SW8260B
Client Sample ID
Lab Sample ID
Continued
Parameter CAS
lodomethane 74-88-4
lsooroovlbenzene 98-82-8
4-lsooroovltoluene 99-87-6
Methvl methacrvlate 80-62-6
Methyl tert-butvl ether (MTBE) 1634-04-4
4-Methvl-2-oentanone (MIBK) 108-10-1
Methylene chloride 75-09-2
Naohthalene 91-20-3
Prooanenitrile 107-12-0
n-Proovlbenzene 103-65-1
Styrene 100-42-5
l 1 1.2-Tetrachloroethane 630-20-6
1 1 2,2-Tetrachloroethane 79-34-5
Tetrachloroethene 127-18-4
Tetrahvdrofuran 109-99-9 -Toluene 108-88-3
1,2 3-Trichlorobenzene 87-61-6
1 2 4-Trichlorobenzene 120-82-1
l, 1 I-Trichloroethane 71-55-6
1 I 2-Trichldroethane 79-00-5
Trichloroethene 79-01-6
Trichlorofluoromethane 75-69-4
1,2 3-Trich loropropane 96-18-4
1.1 2-Trichlorotrifluoroethane 76-13-1
l ,2 4-Trimethvlbenzene 95-63-6
1 3 5-Trimethvlbenzene 108-67-8
Vinvl acetate 108-05-4
Vinvl chloride 75-01-4
SECTION IV -Analytical Results -12/04/2000 15:24
l lOOHBWW220
2001121701
Cone Flaa DL
ND 0.109
ND 0.0931
ND 0.115
ND 0.131
ND 0.116
ND 0.178
ND 0.126
ND 0.0801
ND 1.59
ND 0.140
ND 0.0977
ND 0.111
ND 0.0870
ND 0.144
ND 0.900
ND 0.0637
ND 0.551
ND 0.135
ND 0.169
ND 0.0821"
ND 0.137
ND 0.106
ND 0.288
ND 0.123
ND 0.124
ND 0.0905
~ (<. 0.094 g
ND 0.114
'
l lOOHBWW222 l 100HBWW224
2001121702 2001121703 .
RL Cone Flaa DL RL Cone Flag DL RL
0.000 ND 0.109 0.000 ND 0.109 0.000
0.000 ND 0.0931. 0.000 ND 0.0931 0.000
0.000 ND 0.115 0.000 ND 0.115 0.000
0.000 ND 0.131 0.000 ND 0:131 0.000
0.000 ND 0.116 0.000 ND 0.116 0.000
0.000 ND 0.178 0.000 ND 0.178 0.000
0.000 ND 0.126 0.000 ND 0.126 0.000
0.000 ND 0.0801 0.000 ND 0.0801 0.000
0.000 ND 1.59 0.000 ND 1.59 0.000
0.000 ND 0.140 0.000 ND 0.140 0.000
0.000 ND 0.0977 0.000 ND 0.0977 0.000
0.000 ND 0.111 0.000 ND 0.111 0.000
0.000 ND 0.0870 0.000 ND 0.0870 0.000
0.000 ND 0.144 0.000 ND 0.144 0.000 ..
0.000 ND 0.900 0.000 ND . 0.900 . 0.000
0.000 ND ' 0.0637 0.000 ND 0.0637 0.000
0.000 ND 0.551 0.000 ND 0.551 0.000
0.000 ND 0.135 0.000 ND 0.135 0.000
0.000 ND 0.169 0.000 ND 0.169 0.000
0.000 ND 0.{)821 0.000 ND 0.0821 0.000
0.000 ND 0.137 0.000 ND 0.137 0.000
0.000 ND 0.106 0.000 ND 0.106 0.000
0.000 ND 0.288 0.000 ND 0.288 0.000
0.000 ND 0.123 0.000 ND 0.123 0.000
0.000 ND 0.124 0.000 ND 0.124 0.000
0.000 ND 0.0905 0.000 ND 0.0905 0.000
0.000 NB fZ. 0.0948 O.OQO N9-(Z 0.8948 8.888
0.000 ND 0.114 0.000 ND 0.114 0.000
LIMS Workordcr: Little Washington, NC 120011217) l lamilton Beach-Proctor Silex ST$a111e.le.res11/ts have been q11a1ifieil by /{adi1111 /111em111io11lll bllsed 0111/ie cmerill of lit<! dllta re1•ie11· procl!ss. wlti"lt is 11wdel<!d after lite Co111ract l.llbora/01:i• l'rogrn111 Natiu11a/ F1111l'tio11a/ G11itleli11esji1r Orgw11c w11/ • 't11~'/!;~IJ1?l' Daw Rel'iew (U.S. EPr1. Oc1ober 1999 mu/ February 1994. rl!SJH!ctii'c•M Page 6 of
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SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
o-Xvlene/m-Xvlene
o-Xvlene
Client Sample ID
Lab Sample ID
CAS
106-42-3
95-47-6
SECTION IV -Analytical Results -12/04/2000 15:24
l 100HBWW220
2001121701
Cone Flaa
ND
ND
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
DL RL
0.167 0.000
0.0844 0.000
' I
l IOOHBWW222 I IOOHBWW224
2001121702 2001121703
Cone Flaa DL RL Cone Flaa DL RL
ND 0.167 0.000 ND 0.167 0.000
ND 0.0844 0.000 ND 0.0844 0.000
s-ri'a~6L1iiffS11lts have been q11a/ijied !~1· R1ulia11 lntemlllio1111/ bused OJI the critl!ria uj the dt1111 re1•ie11' process, ll'lticlt is 111odel1!d tlfter lit<! CO!'f/"/IC/ Lt1boratu1:r l'rogmm Nllf/IJ//tll F111wtio1111/ G11ideli11es Jit•igf)!.fJllic llllt{>f 39
• h10rgm11c Data Rel'/ew (U.S. EPA, October 1999 1111d Febr11111J' 1994, respffti1·elv) --- -------------- --
------- ---- ---- ---SECTION IV
Analytical Results
Surrogates
MS-VOA
SW8260B
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
. Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
Surroaate Comoound
l-Bromo-4-fluorobenzene
I .2-Dichloroethane-d4
Toluene-d8
SECTION IV -Analytical Results -12/04/2000 15:24
I IOOHBWW220
2001121701
Aaueous
Received I
NA
11/28/2000 13:05
11/30/2000 10:58
11/30/2000 10:58
1.0000
MSDA
U!!/L
% Recoverv Limits F
103 77-117
106 61-143
106 87-113
I 100HBWW222 I IOOHBWW224
2001121702 2001121703
Aaueous Aaueous
Received Received
NA NA
11/28/2000 14:25 11/28/2000 13:30
I 1/30/2000 11 :26 11/30/2000 11 :54
11/30/2000 11 :26 11/30/200011:54
1.0000 1.0000
MSDA MSDA
ug/L ue:/L
% Recoverv Limits F % Recoverv ·Limits
105 .77-117 99 77-117
107 61-143 107 61-143
106 87-113 105 87-113
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex ST~'11111e£e.res11/1s have been q1111lified by Et11di1111 llllen1111io1111/ based 011 !he cri1eri11 of1he dalll rei•iew process. 11•hich is 111ode/ed after Jhe Cmuract L11bora1u1y Program N111iu1111/ F111w1io1111/ Ci11itle/111e; f<W Orgg11ic 1111tl . t11ii\~1h~c Dalo ReNew (U.S. EPA. Ocwber 1999 and FebrumJ' /994. respec1frel.1•) age ot
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39
SECTION IV
Analytical Results
MS-VOA
SW8260B
Parameter
Acetone
Acetonitrile
Acrolein
Acrvlonitrile
Benzene
Bromobenzene
Bromochloromett\ane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
n-Butvlbenzene
sec-Butyl benzene
tert-Butv !benzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1 3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
..
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
CAS
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
SECTION IV -Analytical Results -12/04/2000 15:24
11 OOHBWW225
2001121704
Aqueous
Received
NA
11/28/2000 13:45
11/30/2000 12:22
11/30/2000 12:22
1.0000
MSDA
ug/L
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND "'-:s
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
DL
0.438
6.82
3.79
0.446
0.0641
0.0998
0.131
0.118
0.170
0.199
0.200
0.102
0.105
0.0911
0.0684
0.0652
0.114
0.0842
0.0925
0.0896
0.0938
I I
1100HBWW226 I 100HBWW230
2001121705 2001121706
Aqueous Aqueous
Received Received
NA NA
11/28/2000 12:40 11/28/2000 11 : 15
11/30/2000 12:50 I 1/30/2000 13: 19
11/30/2000 12:50 11/30/2000 13: 19
1.0000 1.0000
MSDA MSDA
ug/L ug/L
RL Cone Flag DL RL Cone Flag DL RL
0.000 ND 0.438 0.000 ND 0.438 0.000
0.000 ND 6.82 0.000 ND 6.82 0.000
0.000 ND 3.79 0.000 ND 3.79 0.000
0.000 ND 0.446 0.000 ND 0.446 0.000
0.000 ND 0.0641 0.000 ND 0.064 I 0.000
0.000 ND 0.0998 0.000 ND 0.0998 0.000
0.000 ND 0.131 0.000 ND 0.131 0.000
0.000 ND 0.118 0.000 ND 0.118 0.000
0.000 ND IA.'"J 0.170 0.000 ND lk°"! 0.170 0.000
0.000 ND 0.199 0.000 ND 0.199 0.000
0.000 ND 0.200 0.000 ND 0.200 0.000
0.000 ND 0.102 0.000 ND 0.102 0.000
0.000 ND 0.105 0.000 ND 0.105 0.000
0.000 ND 0.0911 0.000 ND 0.0911 0.000
0.000 ND 0.0684 0.000 ND 0.0684 0.000
0.000 ND 0.0652 0.000 ND 0.0652 0.000
0.000 ND 0.114 0.000 ND 0.114 0.000
0.000 ND 0.0842 0.000 ND 0.0842 0.000
0.000 ND 0.0925 0.000 ND 0.0925 0.000
0.000 ND 0.0896 0.000 ND 0.0896 0.000
0.000 ND 0.0938 0.000 ND 0.0938 0.000
ST~·"fl((/folfSlllls have been qualified by Radian llltema1io11a/ based 011 !he criteria uj 1/ie du/a n:1-ie11· proce5s. ll'hich i5 modeled afier 1/ie Cv111rac1 Labora1u1y /'rugra111 N111w11ttl Fwrc1io11al G11ide/111<,5 Jip: <1c-gg11ic ""'bf 39 ?110rg11nic Daill Rel'iew (U.S. EPA. Oc1ober 1999 and FebrnmJ' 1994. resp£'Clfre/)') ag -------------------
-------------------SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
Chloromethane
3-Chloropropene
2-Chlorotoluene
4-Chlorotoluene
Client Sample ID
Lab Sample ID
CAS
74-87-3
107-05-1
95-49-8
106-43-4
1 2-Dibromo-3-chloroorooane 96-12-8
Dibromochloromethane 124-48-1
1 2-Dibromoethane 106-93-4
Dibromomethane · 74-95-3
trans-I 4-Dichloro-2-butene 110-57-6
1.4-Dichlorobenzene 106-46-7
1,2-Dichlorobenzene 95-50-1
1.3-Dichlorobenzene 541-73-1
Dichlorodifluoromethane 75-71-8
1.1-Dichloroetharie 75-34-3
1,2-Dichloroethane 107-06-2
I, 1-Dichloroethene 75-35-4
cis-1 2-Dichloroethene 156-59-2
trans-1,2-Dichloroethene 156-60-5
1 2-Dichloroorooane 78-87-5
1 3-Dichloropropane 142-28-9
2 2-Dichloroorooane 594-20-7
I 1-Dichloropropene 563-58-6
cis-1 3-Dichloropropene 10061-01-5
trans-1.3-Dichloroorooene 10061-02-6
Ethyl methacrvlate 97-63-2
Ethvlbenzene 100-41-4
Hexachloro-1 3-butadiene 87-68-3
2-Hexanone 591-78-6
SECTION IV -Analytical Results -12/04/2000 15:24
I lOOHBWW225
2001121704
Cone Flag DL RL
ND 0.127 0.000
ND 0.0777 0.000
ND 0.178 0.000
ND 0.0974 0.000
ND 0.548 0.000
ND 0.140 0.000
ND 0.137 0.000
ND 0.148 0.000
ND 0.780 0.000
ND 0.150 0.000
ND 0.0965 0.000
ND 0.0846 0.000
ND 0.237 0.000
ND 0.124 0.000
ND 0.102 0.000
ND 0.122 0.000
ND 0.112 0.000
ND 0.119 0.000
ND 0.0869 0.000
ND 0.135 0.000
ND 0.160 0.000
ND 0.0994 0.000
ND 0.0818 0.000
ND 0.0908 0.000
ND 0.101 0.000
ND 0.136 0.000
ND 0.331 0.000
ND 0.169 0.000
I I
I lOOHBWW226 11 OOHBWW230
2001121705 2001121706
Cone Flag DL RL Cone Flag DL RL
ND 0.127 0.000 ND 0.127 0.000
ND 0.0777 0.000 ND 0.0777 0.000
ND 0.178 0.000 ND 0.178 0.000
ND 0.0974 0.000 ND 0.0974 0.000
ND 0.548 0.000 ND 0.548 0.000
ND 0.140 0.000 ND 0.140 0.000
ND 0.137 0.000 ND ~-:~0.131 0.000
'-"-ND 0.148 0.000 ND 0.148 0.000
ND 0.780 0.000 ND 0.780 0.000
ND 0.150 0.000 ND 0.150 0.000
ND 0.0965 0.000 ND 0.0965 0.000
ND 0.0846 0.000 ND 0.0846 0.000
ND 0.237 0.000 ND 0.237 0.000
ND 0.124 0.000 ND 0.124 0.000
ND 0.102 0.000 ND 0.102 0.000
ND 0.122 0.000 ND 0.122 0.000
ND 0.112 0.000 0.142 J 0.112 0.000
ND 0.119 0.000 ND 0.119 0.000
ND 0.0869 0.000 ND 0.0869 0.000
ND 0.135 0.000 ND 0.135 0.000
ND 0.160 0.000 ND 0.160 0.000
ND 0.0994 0.000 ND 0.0994 0.000
ND 0.0818 0.000 ND 0.0818 0.000
ND 0.0908 0.000 ND 0.0908 0.000
ND 0.101 0.000 ND 0.101 0.000
ND 0.136 0.000 ND 0.136 . 0.000
ND 0.331 0.000 ND 0.331 0.000
ND 0.169 0.000 ND 0.169 0.000
Ll~,,)};fl~~·~J~rl.i; MjllJeb~nsq,ii?Jh_lftP11W,~n,W191lzlh,F),Milmil1P/Ja~51J'ii~irfzP.11,%~·i!f~t 1he tla111 re1•ic11· process, ll'iiicli is 111otle/ed ajil'I' '"" Co1111·11c1 l.11bora1w;1• /'rogra111 N111io1111/ Fw1ctio1111/ G11ideli11cs /in· Or~t111ic awl
Sl tm~'!111Mlc Dmll Re1•iell' (U.S. EPA. October 1999 """ Fl!/muttJ' 1994. rc•spec1ii·eM Page I 0 of 39
SECTION IV
Analytical Results
MS-VOA
SW8260B
Client Sample ID
Lab Sample ID
Continued
Parameter CAS
lodomethane 74-88-4
lsooroovlbenzene 98-82-8
4-lsopropvltoluene 99-87-6
Methvl methacrvlate 80-62-6
Methyl tert-butvl ether <MTBE) 1634-04-4
4-Methvl-2-pentanone (MIBK) 108-10-1
Methvlene chloride 75-09-2
Naohthalene 91-20-3
Prooanenitrile 107-12-0
n-Proovlbenzene 103-65-1
Stvrene 100-42-5
l l ,l ,2-Tetrachloroethane 630-20-6
l l.2.2-Tetrachloroethane 79-34-5
Tetrachloroethene 127-18-4
Tetrahvdrofuran 109-99-9
Toluene 108-88-3
1.2 3-Trichlorobenzene 87-61-6
1.2.4-Trichlorobenzene 120-82-1
1.1. l-Trichloroethane 71-55-6
l, I 2-Trichloroethane 79-00-5
Trichloroethene 79-01-6
Trichlorofluoromethane 75-69-4
1.2.3-Trichlorooropane 96-18-4
l 1.2-Trichlorotrifluoroethane 76-13-1
l 2.4-Trimethvlbenzene 95-63-6
l 3.5-Trimethylbenzene 108-67-8
Vinvl acetate 108-05-4
Vinyl chloride 75-01-4
SECTION JV -Analytical Results -12/04/2000 15:24
l 100HBWW225
2001121704
Cone Flag DL
ND 0.109
ND 0.0931
ND 0.115.
ND 0.131
ND 0.116
ND 0.178
ND 0.126
ND 0.0801
ND l.59
ND 0.140
ND 0.0977
ND 0.111
ND 0.0870
ND 0.144
ND 0.900
ND 0.0637
ND 0.551
ND 0.135
ND 0.169
ND 0.0821
ND 0.137
ND 0.106
ND 0.288
ND 0.123
ND 0.124
ND 0.0905
1'tS-f<---e.0948
ND 0.114
I I
l 100HBWW226 I IOOHBWW230
2001121705 2001121706 .
RL Cone Flag DL RL Cone Flaa DL RL
0.000 ND 0.109 0.000 ND 0.109 0.000
0.000 ND 0.0931 0.000 ND 0.0931 0.000
0.000 ND 0.115 0.000 ND 0.115 0.000
0.000 ND 0.131 0.000 ND 0.131 0.000
0.000 ND 0.116 0.000 ND 0.116 0.000
0.000 ND 0.178 0.000 ND 0.178 0.000
0.000 ND 0.126 0.000 ND 0.126 0.000
0.000 ND 0.0801 0.000 ND 0.0801 0.000
0.000 ND l.59 0.000 ND l.59 0.000
0.000 ND 0.140 0.000 ND 0.140 0.000
0.000 ND 0.0977 0.000 ND 0.0977 0.000
0.000 ND O.ll l 0.000 ND 0.111 0.000
0.000 ND 0.0870 0.000 ND 0.0870 0.000
0.000 ND 0.144 .0.000 ND 0.144 0.000
0.000 ND 0.900 0.000 ND 0.900 0.000
0.000 ND 0.0637 0.000 ND 0.0637 0.000
0.000 ND 0.551 0.000 ND 0.551 0.000
0.000 ND 0.135 0.000 ND 0.135 0.000
0.000 ND 0.169 0.000 ND 0.169 0.000
0.000 ND 0.0821 0.000 ND 0.0821 0.000
0.000 ND 0.137 0.000 0.235 J 0.137 0.000
0.000 ND 0.106 0.000 ND 0.106 0.000
0.000 ND 0.288 0.000 ND 0.288 0.000
0.000 ND 0.123 0.000 ND 0.123 0.000
0.000 ND 0.124 0.000 ND 0.124 0.000
0.000 ND 0.0905 0.000 ND 0.0905 0.000
6.000 Nf)-£<.. Q.Q948 Q.QQQ NB rz. 0.0948 8.88Q...
0.000 ND 0.114 0.000 ND 0.114 0.000
LIMS Workorder: Little Washington, NC [20011217) Hamilton Beach-Proctor Silex . . · STt'~lfi'f~ results have been q11111ijied by Radian lnt<!l'llalio11a/ based 011 t/1e cril<!ria of tile t/11111 r<!l'il'll' prnc<!H, which i; 111odeled tifter tile Co111rnc1 Laboratot:J' l'rogr11111 N111w11a/ Fwtcti1m11/ G11idd111e.1 jiir 01 gp11ic l/l/(I . 39 'fnor{ali?c Daw Re1•iew (U.S. EP.1, October 1999 and Vebm111J' 1994. respeuh·ely) Page· l I ol -------------------
---SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
n-Xvlene/m-Xvlene
o-Xvlene
--
Client Sample ID
Lab Sample ID
CAS
106-42-3
95-47-6
SECTION IV -Analytical Results -12/04/2000 15:24
---
11 OOHBWW225
2001121704
Cone Flaa DL
ND 0.167
ND 0.0844
---------
l IOOHBWW226 l IOOHBWW230
2001121705 2001121706
RL Cone Flaa DL RL Cone Flaa DL
0.000 ND 0.167 0.000 ND 0.167
0.000 ND 0.0844 0.000 ND 0.0844
LIMS Workorder: I .ittle. Washin11Jpn NC_f200112J71 Hamilton Beach-Proctm Silex . . . . . . . · . . . .
--
RL
0.000
0.000
·samp1e.res1111s nave oeen q1t{(f'IJ1e"itby l?aaum fi1 el'na11011a1 oasert on Ille cmerw 0/1/ie dma re1•1L•w process. ll'l11cli 1s modeled after 1he ( 0111rac1 labormo1r Program Na11011a/ h111clw11a/ G1111/elt11esjor Orga111<· mu/ . STJn~M!I:· Dala Review (U.S. EPA. Ocwber 1999 and February 1994, respec1ii'e/y) · Page 12 ol 39
SECTION IV
Analytical Results
Surrogates
MS-VOA
SW8260B
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
DatefTime Collected
DatefTime Prepared
DatefTime Analyzed
Dilution Factor
Instrument
Units ·
Surroaate Compound
I-Bromo-4-fluorobenzene
1.2-Di ch loroethane-d4
Toluene-d8
SECTION IV -Analytical Results -12/04/2000 15:24
11 OOHBWW225
2001121704
Aqueous
Received
NA
11/28/2000 13:45
11/30/2000 12:22
11/30/2000 12:22
1.0000
MSDA
ug/L
% Recoverv Limits F
103 77-117
107 61-143
107 87-113
l IOOHBWW226 11 OOHBWW230
2001121705 2001121706
Aqueous Aaueous
Received Received
NA NA
11/28/2000 12:40 11 /28/2000 11 : 15
11/30/2000 12:50 11130/2000 13: 19
11/30/2000 12:50 11/30/2000 13:19
1.0000 1.0000
MSDA MSDA
ug/L ug/L
% Recoverv Limits F % Recoverv Limits
104 77-117 104 77-117
108 61-143 110 61-143
105 87-113 108 87-113
LIMS Workorder: J ittle Washin~n NCI2001l?J71 Hamillon Beach-Proctor Silex . . . . . . . . . .
F
·sample res1111s Fil1ve Deen <Jllllnj1e<l l1j• Jeiulum m l!l~Ul//OllllrDmea 011 lhe l'rill!rtll of the dl//ll /'C'l'H'll' proces~. w/11cli IS modeled lljier ihe ( (}}///'(/('/ l.aboralolJ' Program Na1w11al hmc//OJ/((/ Guulc/111c~ for Orga11ic a111/ STJnD.~Min· Dllla Review (U.S. EPt1. Ocrober 1999 and Febr11111J' 1994, respecti1·ez)') Page 13 of 39 -- - ---- ----- - -- -- --
-------------------SECTION IV
Analytical Results
MS-VOA
SW8260B
Parameter
Acetone
Acetonitrile
Acrolein
Acrvlonitrile
Benzene
Bromobenzene
Bromochlorometllane
Bromodichloromethane
Bromoform
Brom om ethane
2-Butanone (MEK)
n-Butvlbenzene
sec-Butvlbenzene
tert-Butv I benzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1,3-butadiene
Chlorobenzene
Ch1oroethane
Chloroform
1-Chlorohexane
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
CAS
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
SECTION IV -Analytical Results -12/04/2000 15:24
I 100HBWW234
2001121707
Aaueous
Received
NA
11/28/2000 14:00
11/30/2000 13:47
11/30/2000 13:47
1.0000
MSDA
ug/L
Cone Flaa DL RL
ND 0.438 0.000
ND 6.82 0.000
ND 3.79 0.000
ND 0.446 0.000
ND 0.0641 0.000
ND 0.0998 0.000
ND 0.131 0.000
ND 0.118 0.000
ND v...:s 0.170 0.000
ND 0.199 0.000
ND 0.200 0.000
ND 0.102 0.000
ND 0.105 0.000
ND 0.0911 0.000
ND 0.0684 0.000
ND 0.0652 0.000
ND 0.114 0.000
ND 0.0842 0.000
ND 0.0925 0.000
ND 0.0896 0.000
ND 0.0938 0.000
11 OOHBWWD999 TRIP BLANK
2001121708 2001121709
Aaueous Aaueous
Received Received
NA NA
11/28/2000 12:45 11/28/2000 00:00
11/30/2000 14:15 11/30/2000 14:43
I 1/30/2000 14:15 11/30/2000 14:43
1.0000 1.0000
MSDA MSDA
ug/L ug/L
Cone Flaa DL RL Cone Flaa· DL RL
ND 0.438 0.000 ND 0.438 0.000
ND 6.82 0.000 ND 6.82 0.000
ND 3.79 0.000 ND 3.79 0.000
ND 0.446 0.000 ND 0.446 0.000
ND 0.0641 0.000 ND 0.0641 0.000
ND 0.0998 0.000 ND 0.0998 0.000
ND 0.131 0.000 ND 0.131 0.000
ND 0. 118 0.000 ND 0.118 0.000
ND \;\.-::S 0.170 0.000 ND LA.::S 0.170 0.000
ND 0.199 0.000 ND 0.199 0.000
ND 0.200 0.000 ND 0.200 0.000
ND 0.102 0.000 ND 0.102 0.000
ND 0.105 0.000 ND 0.105 0.000
ND 0.0911 0.000 ND 0.0911 0.000
ND 0.0684 0.000 ND 0.0684 0.000
ND 0.0652 0.000 ND 0.0652 0.000
ND 0.114 0.000 ND 0.114 0.000
ND 0.0842 0.000 ND 0.0842 0.000
ND 0.0925 0.000 ND 0.0925 0.000
ND 0.0896 0.000 ND 0.0896 0.000
ND 0.0938 0.000 ND 0.0938 0.000
LIMS Workorder: I .ittle. Washimzt.on NCJ20DI PJ 71 Hamilmn Beach-P.roctQr SJ' lex . . . . , . . . . . . ' 'S11111p1e.res11{(s lfi1ve·oee11 lflllltljle{/ b)1 'ffiilTum 'fil en1111101111rvaseno11 Ille c111er II uj the da/i/ 1'1!1'/ell' process, 1vl11ch IS mode(ed after the Co11tract L11bomtu1J• l'rugrn111 N1111111111/ hllll'flllllld 01111/e/111esjor Orga11t£' 1111d STJn~~Mll:· Daw Review (U.S. EPA. October 1999 <md Febrn11ry 1994, respectfr£'1)~ Page 14 of 39
SECTION IV
Analytical Results
MS-VOA
SW82608
Continued
Parameter
Chloromethane
3-Chloropropene
2-Chlorotoluene
4-Chlorotoluene
Client Sample ID
Lab Sample ID
CAS
74-87-3
. 107-05-1
95-49-8
106-43-4
1 2-Dibromo-3-chloroorooane 96-12-8
Dibromochloromethane 124-48-1
1,2-Dibromoethane 106-93-4
Dibromomethane 74-95-3
trans-I 4-Dichloro-2-butene 110-57-6
1.4-Dichlorobenzene 106-46-7
1.2-Dich lorobenzene 95-50-1
1.3-Dichlorobenzene 541-73-1
Dichloroditluoromethane 75-71-8
1, 1-Dichloroethane 75-34-3
1.2-Dichloroethane 107-06-2
1.1-Dich Ioroethene 75-35-4
cis-1.2-Dichloroethene 156-59-2
trans-I 2-Dichloroethene 156-60-5
1.2-Dich loroorooane 78-87-5
1 3-Dichloroprooane 142-28-9
2 2-Dichloroorooane 594-20-7
I 1-Dichloroorooene 563-58-6
cis-1 3-Dichloroorooene 10061-01-5
trans-1.3-Dichloroorooene 10061-02-6
Ethvl methacrvlate 97-63-2
Ethvlbenzene 100-41-4
Hexachloro-1 3-butadiene 87-68-3
2-Hexanone 591-78-6
SECTION IV -Analytical Results -12/04/2000 15:24
11 OOHBWW234
2001121707
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1100HBWWD999 TRIP BLANK
2001121708 2001121709
DL RL Cone Flaa DL RL Cone Flag DL RL
0.127 0.000 ND 0.127 0.000 ND 0.127 0.000
0.0777 0.000 ND 0.0777 0.000 ND 0.0777 0.000
0.178 0.000 ND 0.178 0.000 ND 0.178 0.000
0.0974 0.000 ND 0.0974 0.000 ND 0.0974 0.000
0.548 0.000 ND 0.548 0.000 ND 0.548 0.000
0.140 0.000 ND 0.140 0.000 ND 0.140 0.000
0.137 0.000 ND 0,137 0.000 ND 0.137 0.000
0.148 0.000 ND 0.148 0.000 ND 0.148 0.000
0.780 0.000 ND 0.780 0.000 ND 0.780 0.000
0.150 0.000 ND 0.150 0.000 ND 0.150 0.000
0.0965 0.000 1ND 0.0965 0.000 ND 0.0965 0.000
0.0846 0.000 ND 0.0846 0.000 ND 0.0846 0.000
0.237 0.000 ND 0.237 0.000 ND 0.237 0.000
0.124 0.000 ND 0.124 0.000 ND 0.124 0.000
0.102 0.000 ND 0.102 0.000 ND 0.102 0.000
0.122 0.000 ND 0.122 0.000 ND 0.122 0.000
0.112 0.000 ND 0.112 0.000 ND 0.112 0.000
0.119 0.000 ND 0.119 0.000 ND 0.119 0.000
0.0869 0.000 ND 0.0869 0.000 ND 0.0869 0.000
0.135 0.000 ND 0.135 0.000 ND 0.135 0.000
0.160 0.000 ND 0.160 0.000 ND 0.160 0.000
0.0994 0.000 ND 0.0994 0.000 ND 0.0994 0.000
0.0818 0.000 ND 0.0818 0.000 ND 0.0818 0.000
0.0908 0.000 ND 0.0908 0.000 ND 0.0908 0.000
0.101 0.000 ND 0.101 0.000 ND 0.101 0.000
0.136 0.000 ND 0.136 0.000 ND 0.136 0.000
0.331 0.000 ND 0.331 0.000 ND 0.331 0.000
0.169 0.000 ND 0.169 0.000 ND 0.169 0.000
LIMS Workorder: Little. Washingtpn NCJ200112171 Hamilton Beach-Proctor Silex . . . . . . . • . . . ·Sample res11//s FU1ve Deen q11tm;1e1Y b)' Kadta11 fi11et11atto11111 Dasea 011 //le cruerw of tire dalll re1•ie11• process, wl11c/1 1s modeled afler tire ( 0111rac1 l.aborato1J' Progmm Na11011a/ h111c/to11a/ G1111/e/111esjor Orgt1111c a111/ STJn~~ Data Review (U.S. EPA, Ocwber 1999 and February 1994. respectii'e~1~ Page IS of 39
-------------------
---------~------~-­SECTION IV
Analytical Results
MS-VOA
SW8260B
Client Sample ID
Lab Sample ID
Continued
Parameter CAS
lodomethane 74-88-4
lsopropylbenzene 98-82-8
4-lsoorooYltoluene 99-87-6
Methyl methacrvlate 80-62-6
Methyl tert-butyl ether (MTBE) 1634-04-4
4-Methyl-2-pentanone (MIBK) 108-10-1
Methylene chloride 75-09-2
Naphthalene 91-20-3
Prooanenitrile 107-12-0
n-Proovlbenzene 103-65-1
Styrene 100-42-5
1 1.1 2-Tetrachloroethane 630-20-6
l 1.2 2-Tetrachloroethane 79-34-5
Tetrachloroethene 127-18-4
Tetrahydrofuran 109-99-9
Toluene 108-88-3
l 2.3-Trichlorobenzene 87-61-6
l ,2.4-Trichlorobenzene 120-82-1
l l.l-Trichloroethane 71-55-6
I 1.2-Trichloroethane 79-00-5
Trichloroethene 79-01-6
Trichlorofluoromethane 75-69-4
1.2.3-Trichloroorooane 96-18-4
l 1,2-Trich lorotrifluoroethane 76-13-1
l 2.4-Trimethylbenzene 95-63-6
l 3.5-Trimethvlbenzene 108-67-8
Vinyl acetate 108-05-4
Vinvl chloride 75-01-4
SECTION IV -Analytical Results -12/04/2000 15:24
l 100HBWW234
2001121707
Cone Flag DL RL
ND 0.109 0.000
ND 0.0931 0.000
ND 0.115· 0.000
ND 0.131 0.000
ND 0.116 0.000
ND 0.178 0.000
ND 0.126 0.000
ND 0.0801 0.000
ND 1.59 0.000
ND 0.140 0.000
ND 0.0977 0.000
ND 0.111 0.000
ND 0.0870 0.000
ND 0.144 0.000
ND 0.900 0.000
ND 0.0637 0.000
ND 0.551 0.000
ND 0.135 0.000
ND 0.169 0.000
ND 0.0821 0.000
ND 0.137 0.000
ND 0.106 0.000
ND 0.288 0.000
ND 0.123 0.000
ND 0.124 0.000
ND 0.0905 0.000
·Nf:) (Z -O.Q948 8.000
ND 0.114 0.000
I I
I lOOHBWWD999 TRIP BLANK
200ll21708 2001121709
Cone Flag DL RL Cone Flag DL RL
ND 0.109 0.000 ND 0.109 0.000
ND 0.0931 0.000 ND 0.0931 0.000
ND 0.115 0.000 ND 0.115 0.000
ND 0.131 0.000 ND 0.131 0.000
ND 0.116 0.000 ND 0.116 0.000
ND 0.178 0.000 ND ·-0.178 0.000
ND 0.126 0.000 ND ~-0.126 0.000
ND 0.0801 0.000 ND 0.0801 0.000
ND 1.59 0.000 ND 1.59 0.000
ND 0.140 0.000 ND 0.140 0.000
ND 0.0977 0.000 ND 0.0977 0.000
ND 0.1 ll 0.000 ND 0.111 0.000
ND 0.0870 0.000 ND 0.0870 0.000
ND 0.144 0.000 ND .. 0.144 0.000
ND 0.900 0.000 ND . ·~· 0.900 0.000
ND 0.0637 0.000 ND 0.0637 0.000
ND 0.551 0.000 ND 0.551 0.000
ND 0.135 0.000 ND 0.135 0.000
ND 0.169 0.000 ND 0.169 0.000
ND 0.0821 0.000 ND 0.0821 0.000
ND 0.137 0.000 ND 0.137 0.000
ND 0.106 0.000 ND 0.106 0.000
ND 0.288 0.000 ND 0.288 0.000
ND 0.123 0.000 ND 0.123 0.000
ND 0.124 0.000 ND 0.124 0.000
ND 0.0905 0.000 ND 0.0905 0.000
-N& ;(_ 8.Q948 Q.Q98 NIT {<._ "0.8948 8.88()
ND 0.114 0.000 ND 0.114 0.000
u~,j);?J~Hflrfj JrJvJeb~IT5Qii?HiYWt1~fnbt9lbl11h1lJ),1~ilIDH1P!JiJ}M'IJJif~VilPi~L~-l!r~j the ilata re\•iew process. ll'hich is modeled after the Cmuract l.abormo1:i· Program Natio11a/ F1111ctio11al G1iideli11esjiJr 01~~a11ic llllli ST~1~IJN.:· Da/a Review (U.S. EPA. October 1999 and February 1994, respectil•e/y). . Pagt: 16 of 39
··'
,.,_
---.. _ ...... , .. 91 ... ______ _ _. (-
SECTION IV
Analytical Results
Surrogates
MS-VOA
SW8260B
Surroaate Comoound
l -Bromo-4-fluorobenzene
1 2-Dichloroethane-d4
Toluene-d8
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
SECTION IV -Analytical Results -12/04/2000 15:24
1100HBWW234
2001121707
Aaueous
Received
NA
11/28/2000 14:00
11/30/2000 13:47
11/30/2000 13:47
1.0000
MSDA
ue:/L
% Recoverv Limits F
106 77-117
115 61-143
104 87-113
1 lOOHBWWD999 TRIP BLANK
200ll21708 2001121709
Aaueous Aaueous
Received Received
NA NA
11/28/2000 12:45 11/28/2000 00:00
11/30/2000 14: 15 11/30/2000 14:43
11/30/2000 14:15 11/30/2000 14:43
1.0000 l.0000
MSDA MSDA
ug/L UQ"/L
% Recoverv Limits F % Recoverv Limits
102 77-117 102 77-117
110 61-143 105 61-143
108 87-113 105 87-113
- -
I I
F
LIM,S Workorder: Little Washin2t9n, NC f20(JI 1217] Hamilton Beiich-Proctor Silex . . . . . . . . . . . · Sample. results nave been q1ui11ped by Radum lntema/101111/ baself 011 tile cr//erw oj the daltl re1•1e11• proce~s. ll'l11ch 1s modeled after the ( 011/l't1Ct Laborn101J' Progrnm Na1io1111/ J-111u·1w11ttl G11u/eill1<·s }IJ!" 01~~1ic· a11d .
ST'tiiM!illfflc Dalll Re1•iew (U.S. EPA, Oc1ober 1999 and Pebruary /994, respec1fre(1•J 1•age of 39
I
I
I
I ''',"
' '
I
I .
. 1
I
I
I
I. ,,
I
I
I
I
I
I
I~
. LABORATORY REPORTS .
SECTION I
Table of Contents
Section
I.
MS-VOA
II.
III.
IV.
v.
VI.
VII.
Form
Cover Page -Laboratory Analytical Report
Table of Contents • . . . . . . . . . . . . . . .
Report Surrmaries . . . .
Workorder Surrmary .
Protocol Surrmary
Carments and Flag Definitions .
Standard Flag Definitions
Analyst Corrments . . . . .
Sarrple Condition Corrments
Analytical Results . . . . . . . . . .
SW8260B . . . . . . . . .
Calibration and Quality Control Results
SW8260B . . . . . . . . . . .
Batch Surrmaries .
SW8260B •
Certifications . . .
Calibration Verification Results
Mass Spectrometer Tune
Method Blank Results
Control Sanple Results
Extraction/Digestion Batch Surrmary
Analysis Batch Surrmary
Section I -Table of Contents -12/04/2000 15:24
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
STLAustin
Page
. i
1
1
1
1
3
3
3
3
•• 4
. . . . 4
. 19
. 19
. . 19
. 27
• • 29
• 33
37
37
37
38
39
---.. -\~ ie.t .. :-.... -..... ., .... - - -
-~~~~~~~~~~~-~~~~~-
SECTION II
Report Summaries
MS-VOA
Client Name: Hamilton Beach-Proctor Silex
Client Code: HB-PS
Workorder Summary
Lab
Client Samole ID Sample ID
l 100HBWW220 2001121701
I IOOHBWW222 2001121702
I I OOHBWW224 2001 I2I703
I I OOHBWW225 2001121704
I 100HBWW226 2001121705
l 100HBWW230 2001121706
l 100HBWW234 2001121707
l 100HBWWD999 200112I708
TRIP BLANK 2001I2I709
Protocol Summary
·Lab
Client Samole ID Samole ID
Method: SW8260B
I 100HBWW220 200II2I701
I IOOHBWW222 200II2I702
l 100HBWW224 200112I703
I IOOHBWW225 2001121704
I I OOHBWW226 200I 12I705
SECTION II -Report Summaries -12/04/2000 15:24
Project Name: Little Washington, NC [200I 1217] Hamilton Beach-Proctor Silex
Facility Name: NC
Samole Matrix ·. Method Citation Method Descriotion
Aaueous SW8260B ~, Volatiles by GC/MS
Aaueous SW8260B Volatiles bv GC/MS
Aaueous SW8260B Volatiles by GC/MS
Aaueous SW8260B Volatiles bv GC/MS
Aaueous SW8260B Volatiles by GC/MS
Aaueous SW8260B Volatiles bv GC/MS
Aaueous SW8260B Volatiles by GC/MS
Aaueous SW8260B Volatiles bv GC/MS
Aaueous SW8260B Volatiles b.y GC/MS
Date& Time Date&Time Prep Date & Time Analysis Date& Time
Collected Received Batch ID Preoared Batch ID Analvzed
11/28/00 13 :05 11/29/00 10:30 9563 I l/30/00 10:58 9563 l I/30/00 10:58
I l/28/00 I4:25 11/29/00 I 0:30 9563 11/30/00 I I :26 9563 11/30/00 I l :26
11/28/00 13:30 11/29/00 10:30 9563 I l/30/00 I 1:54 9563 I l/30/00 l I :54
11/28/00 13:45 11/29/00 10:30 9563 11/30/00 12:22 9563 I I/30/00 I2:22
I 1128/00 12:40 I 1/29/00 10:30 9563 l I/30/00 12:50 9563 I I/30/00 I2:50
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
STL Austin
Hold Time S >ec
Preo Analysis
Soec Actua Soec Actua
70 2D 7D 20
70 2D 70 20
70 20 7D 20
70 20 7D 20
7D 2D 70 20
Page 1 of 39
~~~~~-~~~~-~-~~~~-~
SECTION Ill
Comments and Flag Definitions
MS-VOA
Standard Data Qualifiers
Flaa Definition
J Result> or= MDL and <POL
NA Not analvzed/Not available
ND Not detected at the soecified renortiM limit
0 Result does not meet tolerance in Protocol Soecification
u Result less than samnle snecific method detection limit
Analyst Comments
I Flag I Affected Sample Method
Sample Condition Comments
1 Affected Sample I Comment
•
SECTION Ill -Comments and Flag Definitions -12/04/2000 15:24
LIMS Workorder: Little Washington, NC (20011217] Hamilton Beach-Proctor Silex
STLAustin
I Comment
Page 3 of 39
SECTION IV
Analytical Results
Surrogates
MS-VOA
SW8260B
Surroaate Comoound
1-Bromo-4-tluorobenzene
I .2-Dichloroethane-d4
Toluene-d8
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
SECTION IV -Analytical ResuI~ -I2/04/2000 I5:24
11 OOHBWW220
2001121701
Aaueous
Received
NA
11/28/2000 13:05
11/30/2000 10:58
11/30/2000 I 0:58
1.0000
MSDA
ug/L
% Recoverv
103
106
106
LIMS Workorder: Little Washington, NC (200I 12I 7] Hamilton Beach-Proctor Silex
STL Austin
Limits F
77-117
61-143
87-113
11 OOHBWW222 I IOOHBWW224
2001121702 2001121703
Aaueous Aaueous
Received Received
NA NA
11/28/2000 14:25 11/28/2000 13:30
11/30/2000 11 :26 11/30/2000 11 :54
11/30/2000 11 :26 11/30/2000 11 :54
1.0000 1.0000
MSDA MSDA
ug/L ug/L
% Recoverv Limits F % Recoverv Limits F
105 77-117 99 77-117
107 61-143 107 61-143
106 87-113 105 87-113
Page 8 of 39 - -..... --............. _, ............. ..
--~--~~~~~~~~~~-~-~
SECTION IV
Analytical Results
MS-VOA
SW8260B
Parameter
Acetone
Acetonitrile
Acrolein
Acrvlonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Brom om ethane
2-Butanone (MEK)
n-Butvlbenzene
sec-Butvlbenzene
tert-Butvlbenzene
. Carbon disulfide
Carbon tetrachloride
2-Chloro-1.3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
CAS
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
SECTION IV -Analytical Results -12/04/2000 15:24
11 OOHBWW225
2001121704
Aaueous
Received
NA
11128/2000 13:45
11/30/2000 12:22
11/30/2000 12:22
1.0000
MSDA
ug/L
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
STLAustin
DL RL
0.438 0.000
6.82 0.000
3.79 0.000
0.446 0.000
0.0641 0.000
0.0998 0.000
0.131 0.000
0.118 0.000
0.170 0.000
0.199 0.000
0.200 0.000
0.102 0.000
0.105 0.000
0.0911 0.000
0.0684 0.000
0.0652 0.000
0.114 0.000
0.0842 0.000
0.0925 0.000
0.0896 0.000
0.0938 0.000
I 100HBWW226 l 100HBWW230
2001121705 2001121706
Aqueous Aaueous
Received Received
NA NA
11/28/2000 12:40 11/28/2000 11: 15
11/30/2000 12:50 11/30/2000 13:19
11/30/2000 12:50 11/30/2000 13: 19
1.0000 1.0000
MSDA MSDA
ug/L ug/L
Cone Flaa DL RL Cone Flaa DL RL
ND 0.438 0.000 ND 0.438 0.000
ND 6.82 0.000 ND 6.82 0.000
ND 3.79 0.000 ND 3.79 0.000
ND 0.446 0.000 ND 0.446 0.000
ND 0.0641 0.000 ND 0.0641 0.000
ND 0.0998 0.000 ND 0.0998 0.000
ND 0.131 0.000 ND 0.131 0.000
ND 0.118 0.000 ND 0.118 0.000
ND 0.170 0.000 ND 0.170 0.000
ND 0.199 0.000 ND 0.199 0.000
ND 0.200 0.000 ND 0.200 0.000
ND 0.102 0.000 ND 0.102 0.000
ND 0.105 0.000 ND 0.105 0.000
ND 0.09J 1 0.000 ND 0.0911 0.000
ND 0.0684 0.000 ND 0.0684 0.000
ND 0.0652 0.000 ND 0.0652 0.000
ND 0.114 0.000 ND 0.114 0.000
ND 0.0842 0.000 ND 0.0842 0.000
ND 0.0925 0.000 ND 0.0925 0.000
ND 0.0896 0.000 ND 0.0896 0.000
ND 0.0938 0.000 ND 0.0938 0.000
Page 9 of 39
SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
Chloromethane
3-Chloroorooene
2-Chlorotoluene
4-Chlorotoluene
Client Sample ID
Lab Sample ID
CAS
74-87-3
107-05-1
95-49-8
106-43-4
I .2-Dibromo-3-chloroorooane 96-12-8
Dibromochloromethane I24-48-I
I .2-Dibromoethane I06-93-4
Dibromomethane 74-95-3
trans-I 4-Dichloro-2-butene 110-57-6
1.4-Dichlorobenzene 106-46-7
I .2-Dich lorobenzene 95-50-I
I .3-Dichlorobenzene 54I-73-I
Dichlorodifluoromethane 75-7I-8
I. l-Dichloroethane 75-34-3
1.2-Dichloroethane 107-06-2
1.1-Dichloroethene 75-35-4
cis-1.2-Dichloroethene I56-59-2
trans-I 2-Dichloroethene I56-60-5
I 2-Dichloroorooane 78-87-5
I 3-Dichloroorooane 142-28-9
2 2-Diehloroorooane 594-20-7
1 I-Dichlorooropene 563-58-6
cis-1.3-Dichloroorooene l006I-Ol-5
trans-I 3-Dichloroorooene 10061-02-6
Ethvl methacrvlate 97-63-2
Ethvlbenzene I00-41-4
Hexachloro-1.3-butadiene 87-68-3
2-Hexanone 59I-78-6
SECTION IV -Analytical Results -12/04/2000 15:24
l lOOHBWW225
2001121704
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
STL Austin
DL
O.I27
0.0777
O.I78
0.0974
0.548
0.140
0.137
0.148
0.780
0.150
0.0965
0.0846
0.237
0.124
0.102
0.122
O. l I2
0.119
0.0869
0.135
0.160
0.0994
0.0818
0.0908
0.101
0.136
0.331
0.169
I 100HBWW226 l lOOHBWW230
200l12I705 200Il21706
RL Cone Flag DL. RL Cone Flag DL RL
0.000 ND 0.127 0.000 ND 0.127 0.000
0.000 ND 0.0777 0.000 ND 0.0777 0.000
0.000 ND 0.178 0.000 ND O.I78 0.000
0.000 ND 0.0974 0.000 ND 0.0974 0.000
0.000 ND 0.548 0.000 ND 0.548 0.000
0.000 ND O.I40 0.000 ND 0.140 0.000
0.000 ND 0.137 0.000 ND 0.137 0.000
0.000 ND O.I48 0.000 ND O.I48 0.000
0.000 ND 0.780 0.000 ND 0.780 0.000
0.000 ND O.I50 0.000 ND O.I50 0.000
0.000 ND 0.0965 0.000 ND 0.0965 0.000
0.000 ND 0.0846 0.000 ND 0.0846 0.000
0.000 ND 0.237 0.000 ND 0.237 0.000
0.000 ND O.I24 0.000 ND O.I24 0.000
0.000 ND 0.102 0.000 ND 0.102 0.000
0.000 ND O.I22 0.000 ND O.I22 0.000
0.000 ND O.I I2 0.000 0.142 J 0.112 0.000
0.000 ND O.II9 0.000 ND O.l I9 0.000
0.000 ND 0.0869 0.000 ND 0.0869 0.000
0.000 ND O.I35 0.000 ND O.I35 0.000
0.000 ND 0.160 0.000 ND O.I60 0.000
0.000 ND 0.0994 0.000 ND 0.0994 0.000
0.000 ND 0.0818 0.000 ND 0.0818 0.000
0.000 ND 0.0908 0.000 ND 0.0908 0.000
0.000 ND 0.101 0.000 ND 0.101 0.000
0.000 Nb 0.136 0.000 ND 0.136 0.000
0.000 ND 0.33 I 0.000 ND 0.331 0.000
0.000 ND 0.169 0.000 ND 0.169 0.000
Page 10 of 39 ___ .... ,_._ ... _. .. __ ,..,_: ___ ......
SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
p-Xylene/m-Xvlene
o-Xvlene
Client Sample ID
Lab Sample ID
CAS
106-42-3
95-47-6
SECTION IV -Analytical Results -12/04/2000 15:24
11 OOHBWW225
2001121704
Cone Flaa
ND
ND
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
STLAustin
DL RL
0.167 0.000
0.0844 0.000
--- --. .... .. ..
l 100HBWW226 l 100HBWW230
2001121705 2001121706 .
Cone Flaa DL RL Cone Flaa DL RL
ND 0.167 0.000 ND 0.167 0.000
ND 0.0844 0.000 ND 0.0844 0.000
Page 12 of 39 ......... (--... .........
-~--~~-~-~~~-~~~~~~
SECTION IV
Analytical Results
Surrogates
MS-VOA
SW8260B
Surrogate Comoound
1-Bromo-4-fluorobenzene
1 2-Dichloroethane-d4
Toluene-d8
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units ·
SECTION IV -Analytical Results -12/04/2000 15:24
1100HBWW225
2001121704
Aaueous
Received
NA
11/28/2000 13:45
11/30/2000 12:22
11/30/2000 12:22
1.0000
MSDA
ug/L
% Recoverv
103
107·
107
LIMS Workorder: Little Washington, NC (200 I 1217] Hamilton Beach-Proctor Silex
STLAustin
Limits F
77-117
61-143
87-113
1100HBWW226 1100HBWW230
2001121705 2001121706
Aaueous Aaueous
Received Received
NA NA
11/28/2000 12:40 11/28/2000 11: 15
11/30/2000 12:50 11/30/2000 13: 19
11/30/2000 12:50 11/30/2000 13:19
1.0000 1.0000
MSDA MSDA
ug/L ug/L
% Recoverv Limits F % Recoverv Limits F
104 77-117 104 77-117
108 61-143 110 61-143
105 87-113 108 87-113
Page 13 of 39
- - -.. -· ...... -........ ~ ..... : - -..
SECTION IV
Analytical Results
MS-VOA
SW8260B
Continued
Parameter
Chloromethane
3-Chloroorooene
2-Chlorotoluene
4-Chlorotoluene
Client Sample ID
Lab Sample ID
CAS
74-87-3
107-05-1
95-49-8
106-43-4
1 2-Dibromo-3-chloroorooane 96-12-8
Dibromochloromethane 124-48-1
I 2-Dibromoethane 106-93-4
Dibromomethane 74-95-3
trans-I 4-Dichloro-2-butene 110-57-6
1.4-Dichlorobenzene 106-46-7
1.2-Dichlorobenzene 95-50-1
1,3-Dichlorobenzene 541-73-1
Dichlorodifluoromethane 75-71-8
I, 1-Dichloroethane 75-34-3
1.2-Dichloroethane 107-06-2
I, 1-Dichloroethene 75-35-4
cis-1 2-Dichloroethene 156-59-2
trans-1,2-Dich loroethene 156-60-5
1.2-Dichloroorooane 78-87-5
1.3-Dichloropropane 142-28-9
2,2-Dichloroorooane 594-20-7
1.1-Dichlorooropene 563-58-6
cis-1 3-Dichloroorooene 10061-01-5
trans-1,3-Dichloroorooene 10061-02-6
Ethvl methacrvlate 97-63-2
Ethyl benzene 100-41-4
Hexachloro-1 3-butadiene 87-68-3
2-Hexanone 591-78-6
SECTION IV -Analytical Results -12/04/2000 15:24
1100HBWW234
2001121707
Cone Flag
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: Little Washington, NC (20011217] Hamilton Beach-Proctor Silex
STL Austin
DL RL
0.127 0.000
0.0777 0.000
0.178 0.000
0.0974 0.000
0.548 0.000
0.140 0.000
0.137 0.000
0.148 0.000
0.780 0.000
0.150 0.000
0.0965 0.000
0.0846 0.000
0.237 0.000
0.124 0.000
0.102 0.000
0.122 0.000
0.112 0.000
0.119 0.000
0.0869 0.000
0.135 0.000
0.160 0.000
0.0994 0.000
0.0818 0.000
0.0908 0.000
0.101 0.000
0.136 0.000
0.331 0.000
0.169 0.000
I 100HBWWD999 TRIP BLANK
2001121708 2001121709
Cone Flag DL RL Cone Flaa DL RL
ND 0.127 0.000 ND 0.127 0.000
ND 0.0777 0.000 ND 0.0777 0.000
ND 0.178 0.000 ND 0.178 0.000
ND 0.0974 0.000 ND 0.0974 0.000
ND 0.548 0.000 ND 0.548 0.000
ND 0.140 0.000 ND 0.140 0.000
ND 0.137 0.000 ND 0.137 0.000
ND 0.148 0.000 ND 0.148 0.000
ND 0.780 0.000 ND 0.780 0.000
ND 0.150 0.000 ND 0.150 0.000
ND 0.0965 0.000 ND 0.0965 0.000
ND 0.0846 0.000 ND 0.0846 0.000
ND 0.237 0.000 ND 0.237 0.000
ND 0.124 0.000 ND 0.124 0.000
ND 0.102 0.000 ND 0.102 0.000
ND 0.122 0.000 ND 0.122 0.000
ND 0.112 0.000 ND 0.112 0.000
ND 0.119 0.000 ND 0.119 0.000
ND 0.0869 0.000 ND 0.0869 0.000
ND 0.135 0.000 ND 0.135 0.000
ND 0.160 0.000 ND 0.160 0.000
ND 0.0994 0.000 ND 0.0994 0.000
ND 0.0818 0.000 ND 0.0818 0.000
ND 0.0908 0.000 ND 0.0908 0.000
ND 0.101 0.000 ND 0.101 0.000
ND 0.136 0.000 ND 0.136 0.000
ND 0.331 0.000 ND 0.331 0.000
ND 0.169 0.000 ND 0.169 0.000
Page 15 of 39
SECTION IV
Analytical Results
Surrogates
MS-VOA
SW8260B
Client Sample ID
Lab Sample ID
Matrix
Reported As
% Moisture
Date/Time Collected
Date/Time Prepared
Date/Time Analyzed
Dilution Factor
Instrument
Units
Surroaate Comoound
l -Bromo-4-fluorobenzene
l .2-Dichloroethane-d4
Toluene-d8
SECTION IV -Analytical Results -12/04/2000 15:24
11 OOHBWW234
2001121707
Aqueous
Received
NA
11/28/2000 14:00
11/30/2000 13:47
11/30/2000 13:47
1.0000
MSDA
ug/L
% Recovery
106
115
104
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
STLAustin
Limits F
77-117.
61-143
87-113
l 100HBWWD999 TRIP BLANK
2001121708 2001121709
Aaueous Aqueous
Received Received
NA NA
11/28/2000 12:45 11/28/2000 00:00
11/30/2000 14:15 11/30/2000 14:43
11/30/2000 14:15 11/30/2000 14:43
1.0000 1.0000
MSDA MSDA
ug/L ug/L
% Recovery Limits F % Recovery Limits F
102 77-117 102 77-117
110 61-143 105 61-143
108 87-113 105 87-113
Page 18 of 39 - -.... ----..... ,_ - - -; .. -· - -..
--~--~~--~-~~~~~--~
SECTIONV
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW8260B
Sample Type: Continuing Calibration Check -·
Analysis Batch ID: 9563 Instrument Data File: Al 129002.D
Instrument ID: MSDB Analyst: JEC
Parameter Reference Value Measured Cone
Acetone 20 22.7
Acetonitrile 100 97.2
Acrolein 100 101
Acrvlonitrile 20 22.9
Benzene 20 22.4
Bromobenzene 20 18.4
Bromochloromethane 20 20.7
Bromodichloromethane 20 21.9
Bromoform 20 16.0
Brom om ethane 20 21.4
2-Butanone (MEK) 20 24.5
n-Butvlbenzene 20 19.1
sec-Butvlbenzene 20 18.6
tert-Butv !benzene 20 19.0
Carbon disulfide 20 19.1
Carbon tetrachloride 20 23.1
2-Chloro-l 3-butadiene 20 23.4
Chlorobenzene 20 18.4
Chloroethane 20 22.6
Chloroform 20 23.0
1-Chlorohexane 20 20.5
Chloromethane 20 24.7
3-Chloroorooene 20 25.4
2-Chlorotoluene 20 19.1
4-Chlorotoluene 20 18.4
1 2-Dibromo-3-chloropropane 20 16.6
SECTION V -Calibration and QC Information -12/04/2000 15:24
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
STLAustin
Flag
Date/Time Analyzed:l 1/29/2000 13:19
Units: ug/L
%Recoverv Flaa QC Limits %Recoverv
113
97
101
115
112
92
104
110
80
107
123
95
93
95
96
116
117
92
113
115 80-120
103
123
127
96
92
83
Page 19 of 39
SECTIONV
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW8260B
Sample Type: Continuing Calibration Check
Analysis Batch ID: 9563 Instrument Data File: Al 129002.D
Instrument ID: MSDB Analyst: JEC
Continued
Parameter Reference Value Measured Cone
Dibromochloromethane 20 17.7
1.2-Dibromoethane 20 18.3
Dibromomethane 20 21.6
trans-1,4-Dichloro-2-butene 20 18.2
1,4-Dichlorobenzene 20 18.4
1.2-Dichlorobenzene 20 17.8
1,3-Dichlorobenzene 20 18.6
Dichlorodifluoromethane 20 17.8
1, 1-Dich Joroethane 20 23.6
1 2-Dichloroethane 20 23.4
1 1-Dichloroethene 20 23.2
cis-1.2-Dich Ioroethene 20 21.0
trans-I 2-Dichloroethene 20 22.9
1.2-Dichloroorooane 20 24.0
1 3-Dichloroorooane 20 19.1
2 2-Dichloroorooane 20 25.3
1 1-Dichloroorooene 20 23.9
cis-1 3-Dichloropropene 20 21.2
trans-1.3-Dichloroorooene 20 18.8
Ethyl methacrvlate 20 19.3
Ethvlbenzene 20 18.9
Hexachloro-1 3-butadiene 20 21.9
2-Hexanone 20 21.1
Iodomethane 20 20.3
lsooroovlbenzene 20 19.4
4-Isooroovltoluene 20 19.7
SECTION V -Calibration and QC lnfonnation -12/04/2000 15:24
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
STL Austin
Flaa
Dateffime Analyzed:l 1/29/2000 13:19
Units: ug/L
%Recovery Flaa QC Limits %Recovery
88
91
108
91
92
89
93
89
118
117
116 80-120
105
115
120 80-120
96
127
119
106
94
96
95 80-120
110
105
101
97
98
Page 20
---------~---~---
of 39 -..
--~-----~~-~-~----~ SECTIONV
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW8260B
Sample Type: Continuing Calibration Check
Analysis Batch ID: 9563 Instrument Data File: A 1129002.D
Instrument ID: MSDB Analyst: JEC
Continued
Parameter Reference Value Measured Cone
Methvl methacrvlate 20 21.4
Methvl tert-butvl ether (MTBE) 20 22.8
4-Methvl-2-oentanone (MIBK) 20 23.3
Methylene chloride 20 22.5
Naohthalene 20 17.4
Propanenitrile 100 111
n-Prooylbenzene 20 19.6
Styrene 20 19.3
I I. I 2-Tetrachloroethane 20 18.6
I 1,2,2-Tetrachloroethane 20 17.9
Tetrachloroethene 20 20.0
Tetrahydrofuran 20 21.2
Toluene 20 19.2
I 2,3-Trichlorobenzene 20 17.9
I 2.4-Trichlorobenzene 20 18.3
I I, I -Trichloroethane 20 23.3
1 I .2-Trichloroethane 20 18.5
Trichloroethene 20 22.0
Trichlorofluoromethane 20 23.3
. I 2.3-Trichlorooropane 20 19.7
1 I .2-Trichlorotrifluoroethane 20 24.9
1 2.4-Trimethvlbenzene 20 18.5
1,3 5-Trimethvlbenzene 20 18.4
Vinyl acetate 20 27.8
Vinyl chloride 20 22.6
P-Xylene/m-Xvlene 40 38.9
SECTION V -Calibration and QC Information -12/04/2000 15:24
LIMS Workorder: Lillie Washington, NC (20011217] Hamilton Beach-Proctor Silex
STLAustin
Flaa
Dateffime Analyzed:l 1/29/2000 13:19
Units: ug/L
%Recoverv Flag QC Limits %Recoverv
107
114
117
112
87
111
98
96
93
89
100
106
96 80-120
90
91
117
92
110
117
98
124
92
92
139
113 80-120
97
Page 21 of 39
--~----~-~~~-----~-~ SECTIONV
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW8260B
Sample Type: Continuing Calibration Check
Analysis Batch ID: 9563 Instrument Data File: Al 129013.D
Instrument ID: MSDA Analyst: JEC
Parameter Reference Value Measured Cone
Acetone 20 22.9
Acetonitrile 100 104
Acrolein 100 103
Acrvlonitrile 20 24.0
Benzene 20 22.2
Bromobenzene 20 17.0
Bromochloromethane 20 20.5
Bromodichloromethane 20 21.8
Bromoform 20 15.1
Bromomethane 20 19.2
2-Butanone (MEK) 20 25.5
n-Butvlbenzene 20 17. l
sec-Butvlbenzene 20 17.2
tert-Butvlbenzene 20 17.7
Carbon disulfide 20 16.0
Carbon tetrachloride 20 21.1
2-Chloro-1 3-butadiene 20 21.4
Chlorobenzene 20 17.0
· Chloroethane 20 21.3
Chloroform 20 21.5
1-Chlorohexane 20 18.8
Chloromethane 20 21.l
3-Chloroorooene 20 21.5
2-Chlorotoluene 20 17.5
4-Chlorotoluene 20 17.0
1,2-Dibromo-3-chloroorooane 20 18.2
SECTION V -Calibration and QC Information -12/04/2000 15:24
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
STLAustin
Flag
Date/Time Analyzed: 11/30/2000 09:0 l
Units: ug/L
%Recovery Flag QC Limits %Recoverv
114
104
103
120
111
85
102
109
76
96
127
85
86
89
80
106
107
85
107
108 80-120
94
105
107
88
85
91
Page 23 of 39
SECTIONV
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW8260B
Sample Type: Continuing Calibration Check .
Analysis Batch ID: 9563 Instrument Data File: Al 129013.D
Instrument ID: MSDA Analyst: JEC
Continued
Parameter Reference Value Measured Cone
Dibromochloromethane 20 16.4
I 2-Dibromoethane 20 17.8
Dibromomethane 20 22.l
trans-1,4-Dichloro-2-butene 20 16.7
1 4-Dichlorobenzene 20 17.4
I 2-Dichlorobenzene 20 17.2
1 3-Dichlorobenzene 20 17.0
Dichlorodifluoromethane 20 16. l
I 1-Dichloroethane 20 22.0
1.2-Dichloroethane 20 23.l
1.1-Dichloroethene 20 21.6
cis-1 2-Dichloroethene 20 19.8
trans-1.2-Dichloroethene 20 21.6
1 2-Dichloropropane 20 23.8
1 3-Dichloroprooane 20 18.8
2 2-Dichloroorooane 20 22.4
1.1-Dichloropropene 20 23.5
cis-1 3-Dichloroorooene 20 21.l
trans-I 3-Dichloropropene 20 18.0
Ethvl methacrvlate 20 19. l
Ethvlbenzene 20 17.9
Hexachloro-1 3-butadiene 20 18.9
2-Hexanone 20 21.8
lodomethane 20 18.5
lsopropylbenzene 20 18.0
4-Isooi:oovltoluene 20 17.5
SECTION V -Calibration and QC Information -12/04/2000 15:24
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
STLAustin
Flaa
Dateffime Analyzed:l l/30/2000 09:01
Units: ug/L
%Recoverv Flaa QC Limits %Recoverv
82
89
111
83
87
86
85
80
110
116
108 80-120
99
108
119 80-120
94
112
117
106
90
95
90 80-120
95
109
93
90
88
Page 24 of 39
---~-----~-~------~
--~------~------~~-SECTIONV
Calibration and QC Information
Calibration Verification Results
MS-VOA
SW8260B
Sample Type: Continuing Calibration Check
Analysis Batch ID: 9563 Instrument Data File: Al 129013.D
Instrument ID: MSDA Analyst: JEC
Continued
Parameter Reference Value Measured Cone
Methvl methacrvlate 20 23.6
Methvl tert-butvl ether (MTBE) 20 20.9
4-Methvl-2-nentanone <MIBK) 20 25.3
Methvlene chloride 20 21.8
Nanhthalene 20 17.9
Pronanenitrile 100 109
n-Pronvlbenzene 20 17.7
Stvrene 20 18.3
l l 1.2-Tetrachloroethane 20 17.6
l l 2.2-Tetrachloroethane 20 18. l
Tetrachloroethene 20 18.9
Tetrahvdrofuran 20 25. l
Toluene 20 17.8
l 2.3-Trichlorobenzene 20 18.8
l 2.4-Trichlorobenzene 20 17.2
l 1.1-Trichloroethane 20 21.0
l I 2-Trichloroethane 20 . 18.2
Trichloroethene 20 21.5
Trichlorofluoromethane 20 21.4
I 2.3-Trichloronronane 20 19.4
l l .2-Trichlorotrifluoroethane 20 20.9
l 2.4-Trimethvlbenzene 20 17.1
1.3 5-Trimethvlbenzene 20 17.3
Vinvl acetate 20 27.7
Vinvl chloride 20 20.9
n-Xvlene/m-Xvlene 40 35.9
SECTION V -Calibration and QC Information -12/04/2000 15:24
LIMS Workorder: Little Washington, NC .[20011217] Hamilton Beach-Proctor Silex
STL Austin
Flaa
Dateffime Analyzed:l l/30/2000 09:01
Units: ug/L
%Recoveni Flaa QC Limits %Recoverv
118
105
126
109
89
109 ,,-
89
92
88
91
94
125
89 80-120
94
86
105.
91
107
107
97
105
86
87
138
105 80-120
90
Page 25 of 39
--~--------------~-SECTIONV
Calibration and QC Information
Mass Spectrometer Tune
MS-VOA
SW8260B
BFB
Analysis Batch ID: 9563
Instrument ID: MSDA
Mass/Enerav
50
75
95
96
173
174
175
176
177
Instrument Data File: Al 129002.D
Injecti«:>n Time: 11/29/2000 l3: 19
Ion Abundance Criteria
Lower Limit Unner Limit
15 40
30 60
100 100
5 9
0 2
50
5 9
95 101
5 9
SECTION V -Calibration and QC Information -12/04/2000 15:24
LIMS Workorder: Little Washington, NC (20011217] Hamilton Beach-Proctor Silex
STLAustin
Date Analyzed: 11/29/2000 13: 19
Analyst: JEC
% Relative Abundance
24.9
40.4
100
6
0
71.4
7.1
96.2
6.3
Page 27 of 39
SECTIONV
Calibration and QC Information
Mass Spectrometer Tune
MS-VOA
SW8260B
BFB
Analysis Batch ID: 9563
Instrument ID: MSDA
Mass/Enerav
50
75
95
96
173
174
175
176
177
Instrument Data File: Al 129013.D
Injection Time: l l/30/2000 09:01
Ion Abundance Criteria
Lower limit Unnarlimit
15 40
30 60
100 100
5 9
0 2
50
5 9
95 101
5 9
SECTION V -Calibration and QC Information -12/04/2000 15:24
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
STLAustin
Date Analyzed: l l/30/2000 09:01
Analyst: JEC
.
% Relative Abundance
29.8
40.l
100
6.4
0
80.5
6.2
98.6
6.5
Page 28 of 39
-------~-~---------
---------~---------SECTIONV
Calibration and QC Information
Method Blank Results
MS-VOA
SW8260B
Parameter
Acetone
Acetonitrile
Acrolein
Acrvlonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Brom om ethane
2-Butanone (MEK)
n-Butylbenzene
sec-Butvlbenzene
tert-Butvlbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1.3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Chloromethane
3-Chloropropene
2-Chlorotoluene
4-Chlorotoluene
Method Blank ID
Sample Type
Matrix
Date/Time Prepared
Date/Time Analyzed
Instrument
Units
CAS
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
74-87-3
107-05-1
95-49-8
106-43-4
SECTION V -Calibration and QC Information -1210412000 15:24
1018207
Method Blank
Aaueous
11/29/2000 14:44
11/29/2000 14:44
MSDA
ug/L
Cone Flan
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
STL Austin
DL RL Cone Flan DL RL Cone Flaa DL RL
0.438 0.000
6.82 0.000
3.79 0.000
0.446 0.000
0.0641 0.000
0.0998 0.000
0.131 0.000
0.118 0.000
0.170 0.000
0.199 0.000
0.200 0.000 -0.102 0.000 ·~
0.105 0.000
0.0911 0.000
0.0684 0.000
0.0652 0.000
0.114 0.000
0.0842 0.000
0.0925 0.000
0.0896 0.000
0.0938 0.000
0.127 0.000
0.0777 0.000
0.178 0.000
0.0974 0.000
Page 29 of 39
SECTIONV
Calibration and QC Information
Method Blank Results
MS-VOA
SW8260B
Method Blank ID
Continued
Parameter CAS
l ,2-Dibromo-3-chloroprooane 96-12-8
Dibromochloromethane .124-48-1
1.2-Dibromoethane 106-93-4
Dibromomethane 74-95-3
trans-1.4-Dichloro-2-butene 110-57-6
1 4-Dichlorobenzene 106-46-7
1.2-Dichlorobenzene 95-50-1
1.3-Dichlorobenzene 541-73-1
Dichlorodifluoromethane 75-71-8
l 1-Dichloroethane 75-34-3
1 2-Dichloroethane 107-06-2
1.1-Dichloroethene 75-35-4
cis-1 2-Dichloroethene 156-59-2
trans-I 2-Dichloroethene 156-60-5
1.2-Dichloroprooane 78-87-5
1.3-Dichloroorooane 142-28-9
2.2-Dichloroprooane 594-20-7
1.1-Dichloroorooene 563-58-6
cis-1.3-Dichloroorooene 10061-01-5
trans-I 3-Dichloroorooene 10061-02-6
Ethyl methacrylate 97-63-2
Ethylbenzene 100-41-4
Hexachloro-1.3-butadiene 87-68-3
2-Hexanone 591-78-6
Iodomethane 74-88-4
lsopropyJbenzene 98-82-8
4-lsooroovltoluene 99-87-6
Methyl methacrylate 80-62-6
Methyl tert-butyl ether (MTBE) 1634-04-4
SECTION V -Calibration and QC Information -12/04/2000 15:24
1018207
Cone Flaa
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
STLAustin
DL RL Cone Flaa DL RL Cone Flaa DL RL
0.548 0.000
0.140 0.000
0.137 0.000
0.148. 0.000
0.780 0.000
0.150 0.000
0.0965 0.000
0.0846 0.000
0.237 0.000
0.124 0.000
0.102 0.000
0.122 0.000
0.112 0.000
0.119 0.000
0.0869 0.000
0.135 0.000
0.160 0.000
0.0994 0.000
0.0818 0.000
0.0908 0.000
0.101 0.000
0.136 0.000
0.331 0.000
0.169 0.000
0.109 0.000
0.0931 0.000
0.115 0.000
0.131 0.000
0.116 0.000
Page 30 of 39
-------------------
-------------------SECTIONV
Calibration and QC Information
Method Blank Results
MS-VOA
SW8260B
Method Blank ID
Continued
Parameter CAS
4-Methvl-2-nentanone (MJBK) 108-10-1
Methvlene chloride 75-09-2
Nanhthalene 91-20-3
Pronanenitrile ·107-12-0
n-Pronvlbenzene 103-65-1
Stvrene 100-42-5
1 l. I .2-Tetrachloroethane 630-20-6
I 1.2.2-Tetrachloroethane 79-34-5
Tetrachloroethene 127-18-4
Tetrahvdrofuran 109-99-9
Toluene 108-88-3
I 23-Trichlorobenzene 87-61-6
I 2.4-Trichlorobenzene 120-82-1
I I. I-Trichloroethane 71-55-6
1 1.2-Trichloroethane 79-00-5
Trichloroethene 79-01-6
Trichlorofluoromethane 75-69-4
1.23-Trichloronronane 96-18-4
1.1.2-Trichlorotrifluoroethane 76-13-1
1 2.4-Trimethvlbenzene 95-63-6
I 3.5-Trimethvlbenzene 108-67-8
Vinvl acetate 108-05-4
Vinvl chloride 75-01-4
n-X.vlene/m-X vlene 106-42-3
o-Xvlene 95-47-6
SECTION V -Calibration and QC Information -12/04/2000 15:24
1018207
Cone Flaa
ND
ND
ND
ND
ND
ND
"ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
UMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
STLAustin
DL RL Cone Flaa DL RL Cone Flaa DL RL
0.178 0.000
0.126 0.000
0.0801 0.000
1.59 0.000
0.140 0.000
0.0977 0.000
0.111 0.000 . ~ ~.
0.0870 0.000
0.144 0.000
0.900 0.000
0.0637 0.000
0.551 0.000
0.135 0.000
0.169 0.000
0.0821 0.000
0.137 0.000
0.106 0.000
0.288 0.000
0.123 0.000
0.124 0.000
0.0905 0.000
0.0948 0.000
0.114 0.000
0.167 0.000
0.0844 0.000
Page 31 of 39
SECTIONV
Calibration and QC Information
Method Blank Results
MS-VOA
SW8260B
Surroaate Comoound
1-Bromo-4-tluorobenzene
I 2-Dichloroethane-d4
Toluene-d8
Method Blank ID
Sample Type
Matrix
Date/Time Prepared
Date/Time Analyzed
Instrument
Units
SECTION V -Calibration and QC Information -12/04/2000 15:24
1018207
Method Blank
Aaueous
11/2912000 14:44
11/29/2000 14:44
MSDA
U!!/L
% Recoverv
102
107
104
LIMS Workorder: Little Washington, NC [20011217) Hamilton Beach-Proctor Silex
STLAustin
Limits F % Recoverv Limits F % Recoverv Limits F
77-117
61-143
87-113
Page 32 of 39
-------------------
-------------------SECTIONV
Calibration and QC Information
Control Sample Results
MS-VOA
SW82608
Client Sample ID:
Prep Batch ID:
Analysis Batch ID:
LCS for HBN 9563 [MSV/1417]
9563
9563
Lab ID:
File ID:
Instrument ID: MSDB
Units: ug/L
Matrix: Aqueous
c ontrol s amne
1018205 .
A1129003.D
Parameter Sok Amt Cone %Rec Fla
Acetone 20
Benzene 20
Bromobenzene 20
Bromochloromethane 20
· Bromodichloromethane 20
Bromoform 20
Bromomethane . 20
2-Butanone (MEK) 20
n-Butvlbenzene l 20
sec-Butvlbenzene 20
tert-Butvlbenzene 20
Carbon disulfide 20
Carbon tetrachloride 20
Chlorobenzene 20
Chloroethane 20
Chloroform 20
Chloromethane 20
2-Chlorotoluene 20
4-Chlorotoluene 20
I 2-Dibromo-3-chloroorooane 20
Dibromochloromethane 20
1 2-Dibromoethane 20
Dibromomethane 20
I 4-Dichlorobenzene 20
SECTION V -Calibration and QC Information -12/04/2000 15:24
LIMS Workorder: Little Washington, NC (20011217] Hamilton Beach-Proctor Silex
STL Austin
23.3 116
21.8 109
19.l 96
21.2 106
23.7 118
18.0 90
19.3 96
24.1 120
19.2 96
19.6 98
19.5 98
16.5 83
23.3 117
18.4 92
20.2 101
22.4 112
19.0 95
19.2 96
18.7 94
20.0 100
19.0 95
19.3 97
23.0 115
19.3 96
Lab ID:
File ID:
Sok Amt
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
% Moisture:
Analyst:
c ontro IS I D amoe
1018206
A1129004.D
NA
JEC
uolicate
Cone %Rec Fin
24.7 123
23.4 117
18.7 94
21.3 106
24.2 121
18.4 92
21.0 105
25.7 129
19.6 98
20.3 IOI
19.9 100
19.5 97
24.4 122
18.7 93
20.9 105
23.5 118
20.0 100
19.4 97
19.3 97
19.3 96
19.4 97
18.7 94
23.4 117
19.7 98
QC Limits
RPO Fla %Rec RPO
5.9 0.1-240 71
7.1 71-133 17
2.1 67-127 12
0 61-145 21
2.5 57-135 19
2.2 23-151 17
9 34-128· 25
7.2 0.1-214 39
2.1 28-184 30
3 45-160 31
2 65-148 27
16 29-223 23
4.2 46-150 23
I.I 77-129 14
3.9 39-133 27
5.2 64-146 16
5.1 18-140 26.
I 70-136 24
3.1 74-132 23
4.1 39-171 25
2.1 45-137 15
3.1 19-187 19
1.7 52-138 21
2.1 70-132 13
Page 33 of 39
SECTIONV
Calibration and QC Information
Control Sample Results
MS-VOA
SW8260B
Parameter
I 2-Dichlorobenzene
I 3-Dichlorobenzene
Dichlorodifluoromethane
I 1-Dichloroethane
1.2-Dichloroethane
I 1-Dichloroethene
cis-1 2-Dichloroethene •
trans-I 2-Dichloroethene
1.2-Dichloropropane
1.3-Dichloroorooane
2.2-Dichloropropane
1.1-Dichloroorooene
cis-1.3-Dichloropropene
trans-I 3-Dichloroorooene
Ethvlbenzene
Hexachloro-1.3-butadiene
2-Hexanone
Iodomethane
Isopropylbenzene
4-Isooroovltoluene
4-Methvl-2-oentanone (MIBK)
Methvlene chloride
Naohthalene
n-Propvlbenzene
Stvrene
1 1.1.2-Tetrachloroethane
I 1.2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1 2 3-Trichlorobenzene
1 2 4-Trichlorobenzene
.
SECTION V -Calibration and QC Information -12/04/2000 15:24
LablO:
File ID:
SpkAmt
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
LIMS Workorder: Little Washington, NC [200112 I 7] Hamilton Beach-Proctor Silex
STLAustin
c ontrol Samo e continue d
1018205 Lab ID:
A1129003.D FilelO:
Cone %Rec fig Sok Amt
19.1 96 20
18.7 93 20
14.5 72 20
23.4 117 20
24.1 120 20
22.6 113 20
20.6 103 20
22.8 114 20
25.3 126 20
20.5 103 20
23.3 117 20
23.2 116 20
22.2 111 20
19.9 100 20
18.9 95 20
21.7 108 20
22.2 111 20
17.9 89 20
19.3 96 20
19.8 99 20
24.8 124 20
22.9 115 20
21.9 109 20
19.9 100 20
19.9 100 20
19.0 95 20
19.6 98 20
20.3 102 20
18.9 94 20
23.9 119 20
20.l 100 20
c ontro IS amoe uo 1cate contmue I D I' d
1018206
A1129004.D QC Limits
Cone %Rec fig RPO Fla %Rec RPO
19.2 96 0 67-135 14
18.9 94 1.1 68-134 14
15.0 75 4.1 0.1-166 26
23.5 117 0 66-138 19
24.8 124 3.3 48-152 23
21.8 109 3.6 47-175 25
21.0 105 1.9 66-144 18
21.7 108 5.4 62-146 22
25.7 129 2.4 61-133 17
20.1 101 2 70-128 16
23.l 116 0.9 40-168 30
24.2 121 4.2 71-155 31
23.0 115 3.5 36-142 16
20.1 100 0 34-138 21
19.6 98 3.1 75-131 14
22.5 112 3.6 46-150 34
22.4 112 0.9 22-164 34
19.5 97 8.6
19.6 98 2.1 54-152 26
20.l 101 2 41-165 28
25.9 129 4 27-149 36
24.0 120 4.3 36-166 23
22.1 111 1.8 32-172 22
20.3 102 2 61-143 28
19.9 99 I 68-136 14
19.2 96 I 63-141 20
19.3 97 1 47-143 20
20.3 101 I 69-137 16
18.9 95 1.l 70-132 17
23.9 120 0.8 66-140 20
20.6 103 3 66-144 22
Page 34 of 39 -------------------
-----------------·--SECTIONV
Calibration and QC Information
Control Sample Results
MS-VOA
SW8260B
Parameter
1.1 I -Trichloroethane
1 1 2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1 2 3-Trichloronronane
1 2 4-Trimethvlbenzene
1 3 5-Trimethvlbenzene
Vinvl acetate
Vinvl chloride
n-Xvlene/m-Xvlene
o-Xvlene
SECTION V -Calibration and QC Information -12/04/2000 15:24
Lab ID:
File ID:
Sok Amt
20
20
20
20
20
20
20
20
20
40
20
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
STLAustin
Control Sample continued
1018205 Lab ID:
A1129003.D File ID:
Cone %Rec Fin Sok Amt
22.9 115 20
19.0 95 20
22.4 112 20
19.1 96 20
21.9 109 20
19. l 95 20
19.5 97 20
1.61 8.1 20
19.6 98 20
39.0 98 40
18.0 90 20
Control Samole Duohcate continue d
1018206
A1129004.D QC Limits
Cone %Rec Fla RPO Fla %Rec RPO
22.9 114 0.9 49-155 24
18.9 95 0 67-135 17
23.0 115 2.6 71-129 17
18.8 94 2.1 39-147 29
21.l 105 3.7 64-140 18
19.3 96 1 54-156 25
19.7 98 1 62-144 25
1.76 8.8 8.3 0.1-164 31
20.7 103 5 24-138 27
38.8 97 1 ' 76-134 15
18.2 91 I.I 77-131 15
Page 35 of 39
SECTIONV
Calibration and QC Information
Control Sample Results
MS-VOA
SW8260B
Lab ID: 1018205
Surroaate Comoounds %Recoverv
1-Bromo-4-fluorobenzene 104
I 2-Dichloroethane-d4 105
Toluene-d8 103
SECTION V -Calibration and QC Information -12/04/2000 15:24
LIMS Workorder: Little Washington, NC (20011217] Hamilton Beach-Proctor Silex
STL Austin
Lab ID: 1018206
Flaas %Recovery Flags QC Recovery Limits
103 77-117
108 61-143
105 87-113
Page 36 of 39 -------------------
-------------------SECTION VI
Batch Summaries
Extraction/Digestion Batch Summary
MS-VOA
SW8260B
Extraction Batch ID: 9563
Client Sample ID
INSTRUMENT QC
INSTRUMENT QC
LCS for HBN 9563 rMSV/14171
LCSD for HBN 9563 rMSV /14171
MB for HBN 9563 rMSV /14171 zzzzzzzzzz zzzzzzzzzz
zzzzzzzzzz
zzzzzzzzzz
zzzzzzzzzz
zzzzzzzzzz
INSTRUMENT QC
INSTRUMENT OC
l 100HBWW220
l 100HBWW222
l 100HBWW224
l 100HBWW225
11 OOHBWW226
11 OOHBWW230
1100HBWW234
I 100HBWWD999
TRIP BLANK
SECTION VI -Batch Summaries -12/04/2000 15:24
Lab Sample ID
1000
1406
1018205
1018206
1018207
2001114705
2001114706
2001115401
1018208
1018209
2001115402
1000
1406
2001121701
2001121702
2001121703
2001121704
2001121705
2001121706
2001121707
2001121708
2001121709
Start Date/Time:
Stop Date/Time:
11129/2000 13: 19
11/30/2000 14:43
Sample Tvpe · Matrix
GC/MS Tune Aaueous
Continuing Calibration Check Aqueous
Lab Control Samole Aaueous
Lab Control Samole Duplicate Aqueous
Method Blank Aaueous
Field Sample Aqueous
Field Samole Aaueous
Field Sample Aqueous
Matrix Soike Aaueous
Matrix Spike Duplicate Aqueous
Field Samole Aaueous
GC/MS Tune Aqueous
Continuing Calibration Check Aaueous
Field Sample Aqueous
Field Samole Aaueous
Field Sample Aqueous
Field Samole Aaueous
Field Sample Aqueous
Field Samole Aaueous
Field Sample Aqueous
Field Samole Aaueous
Field Sample Aqueous
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
STLAustin
Analyst: JEC
Sample Size
Initial Final Preparation Method
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
15 mL 15 mL SW8260B
Page 37 of 39
SECTION VI
Batch Summaries
Analysis Batch Summary
MS-VOA
SW8260B
Analysis Batch ID: 9563 Instrument ID: MSDA
Seauence Client Sample ID Lab Samole ID
I INSTRUMENT OC 1000
2 INSTRUMENT OC 1406
3 LCS for HBN 9563 fMSV /14171 1018205
4 LCSD for HBN 9563 fMSV/14171 1018206
5 MB for HBN 9563 fMSV/14171 1018207
6 zzzzzzzzzz 2001114705
7 zzzzzzzzzz 2001114706
8 zzzzzzzzzz 2001115401
9 zzzzzzzzzz 1018208
10 zzzzzzzzzz 1018209
11 zzzzzzzzzz 2001115402
12 INSTRUMENT QC 1000
13 INSTRUMENT QC 1406
14 11 OOHBWW220 2001121701
15 1 IOOHBWW222 2001121702
16 11 OOHBWW224 2001121703
17 11 OOHBWW225 2001121704
18 l 100HBWW226 2001121705
19 l 100HBWW230 2001121706
20 11 OOHBWW234 2001121707
21 1100HBWWD999 2001121708
22 TRIP BLANK 2001121709
SECTION VI -Batch Summaries-12/04/2000 15:24
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
STLAustin
Analvsis
Date Time
11129/2000 13:19:00
11/29/2000 13: 19:00
11/29/2000 13:47:00
l 1/29/2000 14:16:00
11/29/2000 14:44:00
11/29/2000 15:14:00
11/29/2000 15:44:00
11129/2000 16:12:00
l 1129/2000 16:40:00
11129/2000 17:08:00
l 1129/2000 17:36:00
I 1130/2000 09:01 :00
11/30/2000 09:01:00
11/30/2000 10:58:00
I 1130/2000 11:26:00
11/30/2000 11:54:00
11130/2000 12:22:00
11/30/2000 12:50:00
11/30/2000 13:19:00
11/30/2000 13:47:00
11/30/2000 14:15:00
11130/2000 14:43:00
Analyst: JEC
SamoleTvoe Analvsis File ID Sub-Batch ID
GC/MS Tune Al 129002.D 0
Continuing Calibration Check Al 129002.D 0
Lab Control Sample Al 129003.D 0
Lab Control Sample Duplicate Al 129004.D 0
Method Blank Al 129005.D 0
Field Sample Al 129006.D 0
Field Sample Al129007.D 0
Field Sample Al 129008.D 0
Matrix Spike Al129009.D 0
Matrix SPike Duplicate Al 129010.D 0
Field Sample Al12901 l.D 0
GC/MS Tune Al 129013.D 0
Continuing Calibration Check Al 129013.D 0
Field Sample Al 129017.D 0
Field Sample Al 129018.D 0
Field Sample Al 129019.D 0
Field Sample Al 129020.D 0
Field Sample Al 129021.D 0
Field Sample Al 129022.D 0
Field Sample Al 129023.D 0
Field Sample Al 129024.D 0
Field Samole Al129025.D 0
Page 38 of 39
-------------------
- -SECTION VII
Certifications
State/Aaencv
- ---
Arkansas Denartment of Pollution Control and Ecology
- - --
California Environmental Laboratorv Accreditation Program I Waste Water/Hazardous Waste
Kansas Denartment of Health and Environment I Solid and Hazardous Waste/Drinking Water
-
Louisiana Denartment of Environmental Oualitv ELAP I Waste Water/Hazardous Waste/Air/Emissions
New Jersev Denartment of Environmental Protection
New York State Denartment of Health I Waste Water/Hazardous Waste
North Carolina Dent. ofNatural Resources & Communitv Develooment I Waste Water
Oklahoma Water Resources Board I Waste Water
South Carolina Dent. of Health & Environmental Control
Utah Denartment of Health I Solid and Hazardous Waste
Wisconsin Denartment ofNatural Resources
US Air Force/AFCEE
US Armv Corns of Engineers (ACE)
US Denartment of Agriculture I Restricted Soils Permit
SECTION VII -Certifications -12/04/2000 15:24
LIMS Workorder: Little Washington, NC [20011217] Hamilton Beach-Proctor Silex
STL Austin
----- -- -
ID#
2257
E-10165
82005
10915
302
8720
82003002
RADC
999885260
Particinatin1_1 Laboratorv
S-42350
Page 39 of 39
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