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HomeMy WebLinkAboutCenco_2009 Annual GW Monitoring Report-OCRANNUAL GROUNDWATER MONITORING REPORT (2009) HONBARRIER, INC. FACILITY CHARLOTTE, MECKLENBURG COUNTY, NORTH CAROLINA GROUNDWATER INCIDENT NO.: 8440 DELTA PROJECT NO.: 5E0811448P This report was prepared for: Honbarrier, Inc. P.O. Box 7027 High Point, North Carolina 27263 This report was prepared by: DELTA Delta Consultants 8008 Corporate Center Drive, Suite 100 Charlotte, North Carolina 28226 (704) 543-3928 January 15, 201 O TABLE OF CONTENTS 1 .0 INTRODUCTION ................................................................................... 1 2.0 ACTIVITIES PERFORMED DURING THIS PERIOD .............................. 1 3.0 SITE HISTORY ..................................................................................... 2 4.0 FIELD ACTIVITIES ............................................................................... 3 5.0 GROUNDWATER FLOW ...................................................................... 3 6.0 ANALYTICAL RESULTS ....................................................................... 4 7.0 SUMMARY AND CONCLUSIONS ......................................................... 5 FIGURES Figure 1.1: Topographic Location Map Figure 3.1: Site Map Figure 5.1: Estimated Shallow Groundwater Flow Map Figure 6.1: Total VOC Concentration Map Table 4.1: Table 4.2: Table 6.1: TABLES Physical Characteristics of Existing Monitoring Wells Summary of Groundwater Field Parameters Summary of Chemical Constituents Detected in Groundwater APPENDICES Appendix A: Laboratory Analytical Report and Chain-of Custody Record Appendix B: Historical Groundwater Sample Results ANNUAL GROUNDWATER MONITORING REPORT (2009) HONBARRIER, INC. FACILITY CHARLOTTE, MECKLENBURG COUNTY, NORTH CAROLINA GROUNDWATER INCIDENT NO.: 8440 DELTA PROJECT NO.: 5E0811448P 1.0 INTRODUCTION Delta Consultants (Delta), on behalf of Honbarrier, Inc. (Honbarrier), has prepared this Annual Groundwater Monitoring Report in accordance with the North Carolina Department of Environment and Natural Resources (NCDENR), Division of Water Quality, Groundwater Section correspondence dated May 7, 2002, and titled, Modification of Sampling Plan (MSP). As per the revised sampling plan, monitoring wells MW-2, MW-13, and MW-19 will be sampled on an annual basis and the groundwater samples will be analyzed for volatile organic compounds (VOCs) according to EPA Method 601. In addition, monitoring well MW-7 will be sampled on an annual basis and the groundwater sample will be analyzed for voes according to EPA Methods 601 and 602. This annual report summarizes the monitoring event conducted in December 2009. The location of the subject site is presented in Figure 1.1. 2.0 ACTIVITIES PERFORMED DURING THIS PERIOD The following tasks were completed during the reporting period: • Depth to groundwater was gauged at monitoring wells MW-2, MW-7, MW- 13, and MW-19 on December 22, 2009; • Groundwater samples were collected from monitoring wells MW-2, MW-7, MW-13, and MW-19 on December 22, 2009; and, • Field measurements including dissolved oxygen (DO), pH, specific conductivity, oxidation reduction potential (ORP), and temperature were collected from monitoring wells MW-2, MW-7, MW-13, and MW-19 on December 22, 2009. Annual Groundwater Monitoring Report (2009) Honbarrier, Inc. Charlotte, North Carolina Groundwater Incident No.: 8440 Delta Project No.: 5E0811448P 3.0 SITE HISTORY 2 Honbarrier provided bulk-hauling services to a variety of industries. The entire site consists of 30 acres, approximately six acres of which were actively used for terminal operations. The terminal operations began in 1969, under the name Central Transport Incorporated. The site had been farmed prior to its purchase. The facility consisted of a terminal office, maintenance garage, truck wash bays, a boiler house for steam production, a wastewater pretreatment system, former waste treatment lagoons, and parking facilities for empty tank trucks. The site included a facility for cleaning the inside of empty tank trucks following delivery of bulk chemicals. Rinse waters generated from these washing operations were collected and treated prior to discharge to the Charlotte Mecklenburg Utility District treatment plant in accordance with permit number 0188. Historically, two on-site impoundments were used to treat tank truck rinse waters. During the 1970s and 1980s, site operations resulted in the release of contaminants into the soil and groundwater. Use of the impoundments was terminated in 1985 when a new pretreatment system commenced operation. Closure of the impoundments began in 1991. The impoundments closed as a landfill in 1992 and are capped to meet Resource Conservation and Recovery Act requirements. Figure 3.1 shows the location of site surface features, the regulated unit (closed landfill), and seven site monitoring wells installed during the contamination assessment process. Monitoring wells MW-9, MW-10, MW-11, MW-12, MW-14, MW-15, and MW-17 were abandoned on May 15, 1999 (following approval by the NCDENR) and are no longer represented on the site map. Terminal operations at the site ceased in approximately 1995 and the property was vacated. The subject site is currently leased and utilized as a truck storage terminal. Annual Groundwater Monitoring Report (2009) Honbarrier, Inc. Charlotte, North Carolina Groundwater Incident No.: 8440 Delta Project No.: 5E0811448P 4.0 FIELD ACTIVITIES 3 Delta mobilized to the site on December 22, 2009, to conduct the groundwater sampling activities. The four monitoring wells sampled during the annual event included MW-2, MW-7, MW-13, and MW-19 (Figure 3.1 ). Prior to purging the wells of at least three volumes of water (or to dryness) using new disposable bailers, Delta measured the depth to water in each well to be sampled using a decontaminated electric water level indicator. A new pair of protective, non-reactive gloves was donned at each well prior to collecting water level measurements. The measured depths were subtracted from the casing elevations to determine the groundwater elevation relative to Mean Sea Level. The physical characteristics of the site monitoring wells and groundwater elevation data are summarized in Table 4.1. After purging the wells, water samples were collected from the same bailers used to purge each well and decanted into laboratory-supplied containers. The containers were placed into an ice-filled cooler and transported under chain-of- custody to Pace Analytical Services, Inc. (PACE) of Huntersville, North Carolina. At the laboratory, the four groundwater samples were analyzed for EPA Method 601 VOCs according to Standard Method 6200. The groundwater sample collected from monitoring well MW-7 was also analyzed for the EPA Method 602 VOCs. In addition, groundwater field measurements were collected for DO, pH, electrical conductivity, ORP, and temperature (Table 4.2). 5.0 GROUNDWATER FLOW Groundwater flow direction in the surficial aquifer was estimated based on water level data obtained from the monitoring wells on December 22, 2009 (Figure 5.1). Annual Groundwater Monitoring Report (2009) Honbarricr, Inc. Charlotte, North Carolina Groundwater Incident No.: 8440 Delta Project No.: 5E0811448P 4 Interpretation of the relative water table elevations suggests that groundwater flows generally to the southeast across the site. This flow direction is consistent with previously interpreted flow directions. On average, static water levels measured in the four monitoring wells have increased approximately 1.42 feet since December 2008. 6.0 ANALYTICAL RESULTS The laboratory analytical results for the groundwater samples collected on December 22, 2009 are contained in Appendix A and summarized in Table 6.1. The groundwater sample collected from monitoring well MW-2 exhibited the presence of vinyl chloride at a concentration of 1.3 micrograms per liter (µg/L), which exceeded its established North Carolina Groundwater Quality Standard (NCGQS) of 0.030 ~lg/L. Two additional VOCs were detected in the groundwater sample collected from MW-2 in concentrations below their respective NCGQS. As summarized, benzene, chlorobenzene, and vinyl chloride were detected in the groundwater sample collected from MW-7 at concentrations of 20 µg/L, 190 µg/L, and 1.2 µg/L, respectively, which exceeded their established NCGQS. Three additional VOCs were detected in the groundwater sample collected from MW-7 in concentrations below their respective NCGQS. Vinyl chloride (33 ~Lg/L) and cis-1,2-dichloroethene (376 µg/L) were detected in the groundwater sample collected from monitoring well MW-13 in concentrations which exceeded their respective NCGQS. Three additional VOCs were detected in the groundwater sample collected from MW-13 in concentrations below their respective NCGQS. Annual Groundwater Monitoring Report (2009) Honbarrier, Inc. Charlotte, North Carolina Groundwater Incident No.: 8440 Delta Project No.: 5E0811448P 5 Vinyl chloride (5.7 µg/L) was detected in the groundwater sample collected from monitoring well MW-19 in a concentration which exceeded its established NCGQS. Two additional VOCs were detected in the groundwater sample collected from MW-19 in concentrations below their respective NCGQS. A total VOC concentration map, showing total detectable VOCs, is provided as Figure 6.1. Historical groundwater sample results are presented in Appendix B. 7.0 SUMMARY AND CONCLUSIONS Based on the field and laboratory analytical results, Delta offers the following summary and conclusions. • Shallow groundwater flow is directed toward the southeast across the site. • The groundwater sample collected from monitoring well MW-2 exhibited a concentration of vinyl chloride, which exceeded its established NCGQS. Concentrations of total VOCs detected in the groundwater sample collected from MW-2 continue to decrease and are currently at a historical low. • The groundwater sample collected from monitoring well MW-7 exhibited the presence of benzene, chlorobenzene, and vinyl chloride in concentrations which exceeded their NCGQS. Concentrations of dissolved petroleum-related voes have decreased significantly since the last sampling event conducted in December 2008. Historically, concentrations of total VOCs detected in the groundwater samples collected from MW-7 Annual Groundwater Monitoring Report (2009) Honbarrier, Inc. Charlotte, N011h Carolina Groundwater Incident No.: 8440 Delta Project No.: 5E0811448P 6 exhibit non-static conditions; however, there appears to be a decreasing trend becoming evident. • Vinyl chloride and cis-1,2-dichloroethene were detected in the groundwater sample collected from monitoring well MW-13 in concentrations which exceeded their respective NCGQS. Concentrations of total VOCs detected in the groundwater sample collected from MW-13 have increased since December 2008. • Vinyl chloride was detected in the groundwater sample collected from monitoring well MW-19 in a concentration above its established NCGQS. Low-level concentrations of total VOCs detected in the groundwater samples collected from MW-19 exhibit non-static conditions. Total dissolved VOCs detected in the groundwater samples collected from the four monitoring wells in December 2009 have decreased since the sampling event conducted in December 2008. Based on the information presented in this report and past groundwater analytical data, Delta concludes that the chlorinated VOC groundwater contaminant plume identified at the subject site exhibits characteristics indicative of biodegradation and physical attenuation. No parent compounds (trichloroethene, tetrachloroethene) were detected at concentrations at or above the laboratory reporting limits in the groundwater samples collected from the four monitoring wells sampled in December 2009. The remaining chlorinated daughter compounds (cis-1,2-dichloroethene, vinyl chloride) detected in the groundwater samples are likely the result of degradation of the parent compound(s). The next groundwater sampling event should be conducted in December 2010. TABLES TABLE 4.1 PHYSICAL CHARACTERISTICS OF EXISTING MONITORING WELLS HONBARRIER, INC. FACILITY CHARLOTTE, MECKLENBURG COUNTY, NORTH CAROLINA DEL TA PROJECT NO.: 5E0811448P WELL SCREEN GROUND TOC DEPTH TO GROUNDWATER WELL ID DEPTH INTERVAL SURFACE ELEVATION GROUNDWATER ELEVATION ELEVATION (ft·BLS) (ft-BLS) lft-MSL\ (ft·MSL) (ft·TOC)* {ft-MSL) MW-2 24 14-24 769.8 771.59 17.66 753.93 MW-7 39 29-39 768.7 768.71 16.28 752.43 MW-13 29 19-29 759.5 761.74 13.20 748.54 MW-16 76 66-76 759.7 761.81 NM NM MW-18 130 110-130 768.95 768.81 NM NM MW-19 14 4-14 746.92 746.87 2.33 744.54 NOTES: ft-BLS Feet below land surface ft-MSL Feet above mean sea level TOC Top of casing ft-TOC Feet below top of casing * Measured on December 22, 2009 NM Not measured; well not included as part of this sampling event; deep well TABLE 4.2 SUMMARY OF GROUNDWATER FIELD PARAMETERS HONBARRIER, INC. FACILITY CHARLOTTE, MECKLENBURG COUNTY, NORTH CAROLINA DEL TA PROJECT NO.: 5E0811448P WELL ID FIELD PARAMETERS PH (SU) Temperature (C0) ORP (mV) DO (ma/Ll EC IS/cm) MW-2 6.84 18.23 146 4.68 0.552 MW-7 7.02 18.58 -84 4.78 0.685 MW-13 7.17 17.65 84 6.31 0.537 MW-16 NM NM NA NM NM MW-18 NM NM NA NM NM MW-19 6.49 17.82 103 7.14 0.514 NOTES: SU Standard Units co Degrees Celsius ORP Oxidation Reduction Potential mV Milli-Volts DO Dissolved Oxygen mg/L Milligrams per liter or parts per million EC Electrical Conductivity Siem Siemens per centimeter NM Not measured; well not included as part of this sampling event Measured on December 22, 2009 TABLE 6.1 SUMMARY OF CHEMICAL CONSTITUENTS DETECTED IN GROUNDWATER HONBARRIER, INC. FACILITY CHARLOTTE, MECKLENBURG COUNTY, NORTH CAROLINA DELTA PROJECT NO.: 5E0811448P CONSTITUENT MONITORING WELL IDENTIFICATION NCGQS MW-2 MW-7 MW-13 MW-19 Benzene NS 20 NS NS 1 Chlorobenzene ND 190 8.1 ND 50 1,2-Dichlorobenzene ND ND ND ND 20 1,3-Dichlorobenzene ND 1.1 ND ND 200 1,4-Dichlorobenzene ND 5.3 2 ND 6 1, 1-Dichloroethene ND ND ND ND 7 1, 1-Dichloroethane 2.5 ND ND 4 6 cis-1,2-Dichloroethene 14.6 1.9 376 23.9 70 trans-1,2-Dichloroethene ND ND 16.7 ND 100 Ethyl benzene NS ND NS NS 600 Toluene NS ND NS NS 600 Trichloroethene ND ND ND ND 3 Vinyl Chloride 1.3 1.2 33 5.7 0.030 Xylenes NS ND NS NS 500 Total voes 18.4 219.5 435.8 33.6 NA NOTES: All concentrations in micrograms per liter (µg/L) or parts per billion NS Not sampled for this constituent ND Not detected in a concentration at or above the laboratory Practical Quantitation Limits NA Not applicable NCGQS North Carolina Groundwater Quality Standard BOLD Exceeds the NCGQS Samples collected on December 22, 2009 FIGURES APPENDICES APPENDIX A LABORATORY ANALYTICAL REPORT AND CHAIN-OF- CUSTODY RECORD Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704 )875-9092 January 14, 2010 John Reuscher Delta Environmental Consultant 8008 Corp. Center Drive Suite 100 Charlotte, NC 28226 RE : Project: HONBARRIER 2009 SAMPLING Pace Project No.: 9260108 Dear John Reuscher: Enclosed are the analytical results for sample(s) received by the laboratory on December 22, 2009. The results relate only to the samples included in this report. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All Microbiological analyses were performed at the laboratory where the samples were received. If you have any questions concerning this report, please feel free to contact me. Sincerely, ~ ~--:£:CL-I Kevin Godwin kevin.godwin@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc .. Page 1of13 I ' J, ..... '. f¥J ./ f'5ceAnalyticar 1laln: CHAIN-OF-CUSTODY I Analytical Request Document The Chain-of-Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. .~m Page: \ of \ Section B Section C Required Project Information: Invoice Information: Comp"" \-\ ~("-eJ; :t.,, oC\ ' ) '-. Roport fa ::l .t-, • ~ SL'r..eC Attention: /VlOJI. Tov.1c-w-1356749 A~dressp__, ? '2 Q O)! l"/O CopyTo: t::>e.t\c.. Qr.~~"-Company Name:~\ ' ,_,... . ~("\(;...,. REGULATORY AGENCY \.\i5;...,.;"t, fl'-::t'7a.bS ·,f<.\>~\-er ~ ~'~~\). r-r.-Address: r. Q. ao)t '70'7 2 .·-NPDES ~GROUND WATER r DRINKING WATER Email To: Purchase Order No.: Pace Quote H•gn I>"; --.-1: , ,;<:. :;i7 ::i.IS ,. UST 1-RCRA r OTHER Reference· ~?rl~-t;~/~7'7 IFax: \~jecttiame: .. .:l.COC\ (,,,,,.,I\"• Pace Project Site Location tJC Manager: Requested Due Date/TAT: g~c\._ PmjeciNcmbocS'c08 \\ '\"' &\' Pace Proflle II: 9-'f>--11 STATE: Requested Analysis Filtered (YIN) Sectlon D -rJ Matrlx Codes = 0: z t RequlredClien! Information MA TR!X I QQD~ • ~ COLLECTED Preservatives > g 0 Drinking Water DW j w z Water WT 0 0 ~ Waste Water WW COMPOSffE COMPOSITE 0 ~ ~ z i • START ENOIGRA3 w Product p ~ ::j ;;:_ ~ Soil/Solid SL ' '-' 0 "' ... ..., SAMPLE ID Oil OL " " 0 "' ~ "1 • W]po WP " ,_ w -g c o\\J w < z 1 § (A-Z, 0-9 f ,-) Air AR 0 w ~ ~ n =t Sample IDs MUST BE UNIQUE Tissue TS 0 ~ ~ • .!!l ~ <) ~ w z ~ '-' ~~ Other OT ,_ OQ ~ x w 0 • ( " " c.; <) "' . 0 c 0 °' ~ J: N 0 <I ,. ~ ~ ~o c; " ro " ,_ ~ " ~ ~"' -0 ~~ • c ~ .~ "' w "" < < 0 C N z () ro £ <( • !::: " "' DATE TIME DATE TIME "' " ::> J: J: J: z z " 0 .. a: Pace Project No./ Lab l.D. 1 MW· I°' ViT G "t2 ~2.'1,S, II '.<.\S ~ ./ ./ I"' f 2 f"\, W ·-I -:<. WT G, l'2-.]2~ 1:i:.;io 3 J v tJ _,., (")IN • .;{ ,,if (,, t2-•1l.~t>"\ ,;i.:3S 3 v ./ /J ~ ' ' 3 4 {") vJ -'7 .rI G \.2.-;)2.-J) J;oo 3 ~ J ..; tJ j /U . ' 6 7 8 9 10 11 12 ADDITTONAL COMMENTS RELINQUISHED BY f AFFILIATION DATE TIME ~CEPTED BY I ~FFILtATION DATE TIME SAMPLE CONDITIONS ue_ ~ ,:i ... 22-oi l<toO Y "UJ t4 ,/ fJc.e 1z/!!2b"t flf<x:' l.J. lf '{ /\/ 'i . . // ' ,?/ ORIGINAL SAMPLER NAME AND SIGNATURE ,, c . 1~ o-.g ~ z PRINT Name of SAMPLER: 3. "-Re..u ~"' \...~ ; .~~ .z il' <;:; "O >= -5.~ • • 8-¥,1~ SIGNATURE of SAMPLER: .M.t2.__ .fld", ,..,_ /. DATE Signed ~ u u E (MM/00/YY)' I 2 . .:2 ;;i. -0 q If_-• • "' "' portant Note: By signing this form yotJ are accepting Pace's NET 30 day payment terms and agreeing to late charges of 1.5% per month for any invoices not paid within 30 days. ~-Al I _()_f">?f">...:.u f">7 1i:;_iA,.," """.,. APPENDIX B HISTORICAL GROUNDWATER SAMPLE RES UL TS TABLE S-1 SUMMARY OF voes DETECTED IN GROUNDWATER -MW-2 HONBARRIER, INC. FACILITY CHARLOTTE, MECKLENBURG COUNTY, NORTH CAROLINA DELTA ENVIRONMENTAL PROJECT#: 5E0811448P CONSTITUENT 12/19/97 4/28/98 5/18/99 6/29/99 12/16/99 6/27/00 12/11/00 6/15/01 12/5/01 12/30/02 12/3/03 12/2/04 12/9/05 12112106 12/27107 1216108 12122109 DL Benzene NS NS ND NS ND ND ND NS ND NAG NAG NAG NAG NAG NAG NAG NAG NA Chlorobenzene NS NS 2 NS ND ND ND NS ND ND ND ND ND ND ND ND ND 1 2-Chlorotoluene NS NS ND NS 17.8 18 ND NS 7 NAG NAG NAG NAC NAG NAG NAG NAG NA 1,3-Dichlorobenzene NS NS ND NS ND ND ND NS ND ND ND ND ND ND ND ND ND 1 1,4-Dichlorobenzene NS NS ND NS ND ND ND NS ND ND ND ND ND ND ND ND ND 1 1, 1-Dich!oroethane NS NS 40 NS 35.6 28 22 NS 26 16.4 6.4 6.9 11.0 5.1 5.7 6.6 2.5 1 1, 1-Dich!oroethene NS NS ND NS ND ND ND NS ND ND ND ND ND ND ND ND ND 1 cis-1,2-Dich!oroethene NS NS 194 NS 169 110 85 NS 110 99.8 95 65 71 41 38 34 14.6 1 trans-1,2-Dich!oroethene NS NS ND NS 2.3 ND ND NS ND 1.2 ND ND 1.2 ND ND ND ND 1 1,2,4-Trich!orobenzene NS NS ND NS ND ND ND NS ND NAG NAC NAG NAG NAG NAG NAC NAG NA Trichloroethene NS NS 3 NS 2.2 6.3 ND NS ND 4.4 4.4 1.2 1.6 ND ND ND ND 1 Vinyl Chloride NS NS 53 NS 43.1 28 12 NS 18 21.3 10 4.4 5.9 3.3 1.8 1.7 1.3 1 Xylenes NS NS ND NS ND ND ND NS ND NAG NAG NAG NAG NAG NAG NAG NAC NA T etrachloroethene NS NS ND NS ND ND ND NS ND ND ND ND ND ND ND ND ND 1 Total VOCs NA NA 292 NA 270 190.3 119 NA 161.3 143.1 115.8 77.2 90.7 49.4 45.5 41.8 18.4 NA NOTES: All concentrations in micrograms per liter (.ug/L) or parts per billion ND DL NA NS NAG 300 250 ~ 200 - ~ "' 2: c 0 ~ 150 ~ -c "' " c 0 u 100 0 r5J' r5J' & <ii' 0 ~ ~ !::' '21 'O :::.; TOTAL voe CONCENTRATIONS DETECTED MONITORING WELL MW-2 & ~ " §> & <§ & rs: <g-rv (!? Pi' !? ~ :::.; ~ <V <V <V :::.; :::.; " " " Sample Date ~ ~ <V ~ ~ ~ :::.; " ;§' <§ <V " & rv ~ " TABLE S-1 SUMMARY OF voes DETECTED IN GROUNDWATER -MW-7 HONBARRIER, INC. FACILITY CHARLOTTE, MECKLENBURG COUNTY, NORTH CAROLINA DEL TA ENVIRONMENTAL PROJECT#: 5E0811448P CONSTITUENT 12119197 04128198 05118199 06129199 12116199 06127100 12111100 06115101 12/05/01 12130102 12/03/03 12/02/04 12/09/05 12112106 12127/07 12106108 12122/09 DL Benzene 25 28 23 NS 34.4 48 87 NS ND 56 63 101 2.7 36 134.0 96.4 20.0 5 Chlorobenzene 110 180 190 NS 230 290 420 NS 300 246 510 204 6.2 200 518.0 214.0 190.0 25 2-Chloroto!uene ND ND ND NS ND ND ND NS ND NAC NAG NAG NAG NAG NAG NAG NAG NA 1,2-Dich!orobenzene ND ND ND NS ND ND ND NS ND 2.9 ND ND ND ND ND ND ND 5 1,3-Dichlorobenzene 5.1 ND 8 NS 6.6 8.9 19 NS 13 5.1 11 ND ND ND 11.0 ND 1.1 5 1,4-Dichlorobenzene 29 46 59 NS 55.8 53 110 NS 87 33.2 98 13.2 ND 6.1 33.5 10.4 5.3 5 1, 1-Dichloroethane ND ND 3 NS 7.7 ND 5.1 NS ND ND ND ND ND ND ND ND ND 5 1, 1-Dichloroethene ND ND ND NS 5.4 ND ND NS ND ND ND ND ND ND ND ND ND 5 cis-1,2-Dichloroethene 250 280 530 NS 406 140 220 NS 160 18.4 230 4.4 NS NS 49.9 ND 1.9 5 trans-1,2-Dichloroethene ND ND 6 NS 4.9 ND 5.1 NS ND 1 ND ND ND ND ND ND ND 5 1,2,4-Trichlorobenzene ND ND 20 NS 18.2 13 18 NS 7.5 NAG NAG NAG NAG NAG NAG NAG NAG NA Trichloroethene ND ND ND NS 21 21 6.1 NS ND ND ND ND ND ND ND ND ND 5 Vinyl Chloride 160 100 90 NS 120 70 160 NS 110 55.8 73 2.5 ND ND 11.3 ND 1.2 5 Xy!enes ND ND 3 NS 4.3 ND ND NS ND ND ND 3.3 ND ND 91.3 40.7 ND 10 Ethylbenzene ND ND ND NS ND ND ND NS ND 27 ND 4.1 ND ND ND 53.8 ND 5 Toluene ND ND 2 NS ND ND ND NS ND ND ND ND ND ND ND 10.1 ND 5 Tetrachloroethene ND ND ND NS 21.3 21 ND NS 7.9 ND ND ND ND ND ND ND ND 5 Tota!VOCs 579.1 634 934 NA 935.6 664.9 1,050.3 NA 685.4 445.4 985.0 332.5 8.9 242.1 849.0 425.4 219.5 NA NOTES: Al! concentrations in micrograms per liter (µg/L) or parts per billion ND DL NA NS 1,500 1,400 1,300 . 1,200 1,100 ~ 1,000 ...J -Cl 900 ..:; c: 800 0 :;:: "' ~ 700 -c: ., " 600 c: 0 (.) 500 400 300 200 100 0 ~ ~ & C§ ~ <§ !:-~ '!:' :y (g' (!? & ~ !:-:y TOTAL voe CONCENTRATIONS DETECTED MONITORING WELL MW-7 & & " & "" ~ f' 10 ~ '55 <§ rs rv ~ !:-!2 f:' f:' <§' :y <V :y :y :y " Sample Date !!,> <!? w <V f:' !:-:y :y fi-10 <$' " <:§:> (;§ ~ :y §' rv ~ " TABLE S-1 SUMMARY OF voes DETECTED IN GROUNDWATER -MW-13 HONBARRIER, INC. FACILITY CHARLOTIE, MECKLENBURG COUNTY, NORTH CAROLINA DELTA ENVIRONMENTAL PROJECT#: 5E0811448P CONSTITUENT 12/19/97 04/28/98 05/18/99 06/29/99 12/16/99 06/27/00 12/11/00 06/15/01 12/05/01 12/30/02 12/03/03 12/02/04 12/09/05 12/12/06 12/27/07 12/06/08 12/22/09 DL Benzene ND ND ND NS ND ND ND NS ND NAC NAC NAC NAC NAG NAG NAG NAG NA Chlorobenzene 13 15 14 NS 12.1 15 13 NS 14 4.6 17 16.9 34 31 19.8 10 8.1 5 2-Ch!orotoluene ND ND ND NS ND ND ND NS ND NAG NAG NAG NAG NAG NAG NAG NAG NA 1,3-Dichlorobenzene ND ND ND NS ND ND ND NS ND ND ND ND ND ND ND ND ND 5 1,4-Dichlorobenzene 6.4 6.8 ND NS 4.4 5.2 ND NS ND 1.8 3.3 3.1 6.7 ND ND ND 2 5 1 , 1-Dichloroethane 16 9.6 5 NS 7.5 ND ND NS ND 2 4.8 1.8 ND ND ND ND ND 5 1, 1-0ichloroethene 13 6.9 5 NS 4.1 ND ND NS ND ND ND ND ND ND ND ND ND 5 cis-1, 2-0ichloroethene 150 140 131 NS 138 83 84 NS 83 43.1 77 98.5 170 240 223 249 376 5 trans-1,2-0lchloroethene ND ND ND NS ND ND ND NS ND ND 2.3 ND 3.1 6.7 9.6 12.2 16.7 5 1,2,4-Trichlorobenzene ND ND ND NS 2.1 ND ND NS ND NAG NAG NAG NAG NAG NAG NAC NAG NA Trichloroethene 6 ND 2.5 NS ND ND ND NS ND ND ND ND ND ND ND ND ND 5 Vinyl Chloride 36 29 20 NS 13.5 12 10 NS 16 8.4 17 16.3 17 17 32.2 27.8 33 5 Xy!enes ND ND ND NS ND ND ND NS ND NAG NAC NAG NAC NAG NAC NAG NAG NA Ethylbenzene ND ND ND NS ND ND ND NS ND NAG NAG NAG NAG NAG NAG NAC NAG NA Toluene ND ND ND NS ND ND ND NS ND NAG NAG NAG NAG NAG NAG NAG NAG NA Tetrachloroethene ND ND ND NS ND ND ND NS ND ND ND ND ND ND ND ND ND 5 Total voes 240.4 207.3 177.5 NA 181.7 115.2 107 NA 113 59.9 121.4 136.6 230.8 294.7 284.6 299.0 435.8 NA NOTES: Al! concentrations in micrograms per liter (µgfl) or parts per billion ND DL NA NS NAC :J a, 300 -~~--'ff±f±'fff 2: c: 0 "" 250 e -c: .. § 2001~~~~ (.) 150 0 L.2lZ:c22'.J~~ G;-cy ;::' :y ,§' Rt $i <:::; & <§ :S:' ~ & id ;::' :y TOTAL voe CONCENTRATIONS DETECTED MONITORING WELL MW-13 § ,:: " §' & !:? !'§ ~ § ;::: ,f;' <:::; ;::' :y ,!!} <V " !:? 5? .:y fJI rk f:V ? :y fS' w ? :y Sample Date ff <V ;::' :y !'.. ~ <$' " ~ >& "" :y (!; r\} ~ " TABLE S-1 SUMMARY OF voes DETECTED IN GROUNDWATER -MW-19 HONBARRIER, INC. FACILITY CHARLOTTE, MECKLENBURG COUNTY, NORTH CAROLINA DELTA ENVIRONMENTAL PROJECT#: 5E0811448P CONSTITUENT 12119197 04128/98 05/18199 06/29199 12/16/99 06/27/00 12111/00 06/15/01 12/05/01 12/30/02 12/03/03 12102104 12109/05 12112/06 12127/07 12106/08 12122/09 DL Benzene NP NS ND ND ND ND ND ND ND NAC NAC NAC NAC NAC NAC NAC NAC NA Chlorobenzene NP NS ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 2HChlorotoluene NP NS ND ND ND ND ND ND ND NAC NAC NAC NAC NAC NAC NAC NAC NA 1,3-Dichlorobenzene NP NS ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 1,4-Dichlorobenzene NP NS ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 1, 1-Dich!oroethane NP NS 11 3.5 7.5 9.1 5.6 8.4 ND 4.3 5.0 2.3 11 6.0 ND ND ND 1 1, 1-Dichloroethene NP NS 9.4 ND 5.5 7.3 ND 4.2 ND ND ND ND 2.7 1.1 1.9 3.5 4 1 cis-1,2-Dichloroethene NP NS 26 16.3 18.5 23 8.3 21.9 8.7 6.9 15 8.2 13 18 4.7 15.3 23.9 1 trans-1,2-Dichloroethene NP NS ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 1,2,4-Trichlorobenzene NP NS ND ND ND ND ND ND ND NAC NAC NAC NAC NAC NAC NAC NAC NA Trichloroethene NP NS ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 Vinyl Chloride NP NS ND ND ND ND ND 6.2 ND 2.8 3.1 ND 11 3.3 ND 1.9 5.7 1 Xylenes NP NS ND ND ND ND ND ND ND NAC NAC NAC NAC NAC NAC NAC NAC NA Ethy!benzene NP NS ND ND ND ND ND ND ND NAC NAC NAG NAC NAC NAC NAC NAC NA Toluene NP NS ND ND ND ND ND ND ND NAC NAC NAC NAC NAC NAC NAC NAG NA T etrachloroethene NP NS ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 Total voes NA NA 46.4 19.8 31.5 39.4 13.9 40.7 8.7 14.0 23.1 10.5 37.7 28.4 6.6 20.7 33.6 NA NOTES: All concentrations in micrograms per liter (ugll) or parts per billion ND DL NA NS NP NAC