16063_Renaissance_Place_PIIR_20121221

SIP Form – revised 2/15/11
Mecklenburg County Health Department Groundwater & Wastewater Services 700 N. Tryon St., Suite 211 Charlotte, NC 28202
Phone: [phone] Fax: [phone] http://groundwater.charmeck.org
Permit Issuance Date: _______________
Permit Number: ____________________ 
SUBSURFACE INVESTIGATION PERMIT
I. Well Owner Information
Name: ___________________________________
Attn: _____________________________________
Phone #: _____________________
Address 1: ________________________________
Address 2: ________________________________
City: __________________________ State: _______ Zip: _____________
II. Agent Information (if applicable)

Name: ___________________________________
Attn: _____________________________________
Phone #: _____________________
Address 1: ________________________________
Address 2: ________________________________
City: __________________________ State: _______ Zip: _____________
III. Site Information

Site Name; ________________________________
Parcel ID Number: _____________________
Address: ________________________________
City: __________________________ State: _______ Zip: _____________

General Conditions of This Permit:
• This permit shall be VALID for a period not to exceed twelve (12) months from the date of issuance.
• This permit is VALID for the site specified aboveDQGmust be on-site during the course of the investigation
and made available to a Department representative upon request.
• A North Carolina Certified Well Contrator must perform any well contractor activities associated with this permit.
• All wells shall be constructed and abandoned to the standards of Chapter VI, Section V and Section VIof the Mecklenburg County Groundwater Well Regulations.
• All temporary wells, including those installed using Direct Push Technology, must be abandoned
to the standards of Chapter VI, Section VI of the Mecklenburg County Groundwater Well Regulations.
• Registration information for all wells must be submitted to the Department within thirty (30) days of well completion. If water samples are collected, it is recommended that the well NOT be registered until the
analytical results are received.

Agent
11/14/2012
70002005
Novare Group
George Jones
404-961-7703
817 W. Peachtree St., Suite 400
Atlanta GA 30308
S&ME, Inc.
Dane Horna
704-523-4726
9751 Southern Pine Blvd.
Charlotte NC 28273-5560
North Tryon
07803301
NC
November 28, 2012 GENERAL HEALTH AND SAFETY PLAN

Page 1
A. SITE DESCRIPTION:

Type of Petroleum Hydrocarbon Suspected (Gasoline, Diesel, Kerosene, etc.): Diesel, Gasoline and Fuel Oil

Hazard: Hydrocarbon fumes, skin irritation, explosion, petroleum fumes.

Area Affected: Former Gas Station and Dry Cleaner location; prior assessments at this site by S&ME and
another consultant in 2005-2007 indicated low levels of petroleum hydrocarbons in one soil sample.

Security: Coordinated during site work by the S&ME site supervisor.

Weather Conditions: Anticipate 40-50 degrees F, no precipitation

B. ENTRANCE OBJECTIVES:

The objectives of entry to the site are to examine possible impacts to soil and groundwater of gasoline or diesel
fuel constituents at the former gasoline station UST and dispenser locations.

C. ON-SITE ORGANIZATION AND COORDINATION:

The following personnel are designated to carry out the stated job function on-site (Note: One person may
carry out more than one job function.)

Site Manager: Roger Smith

Site Safety Officer: Roger Smith

Field Team Leader: Roger Smith

S&ME Subcontractor: 3D Environmental Investigations

Client Contact/Phone Number: Charles Campbell, 631 North Tryon LLC (704-523-2652)

Site Contact/Phone Number: None

All personnel arriving or departing the site should check in with the site manager or his/her designated
representative. All activities on the site must be cleared through the site manager.

D. ON-SITE CONTROL:

1. Roger Smith has been designated to coordinate access control and security on-site. A safe perimeter will be
established at limits defined by the Site Safety Officer on location. Unauthorized personnel are not allowed
within this area.

2. The on-site Command Post (i.e., the pickup truck containing respirators) and staging area will be established
by the Site Safety Officer dependent upon site conditions.

3. The location of the Command Post will be established upwind or distant location (20 feet) from the
Exclusion Zone.

4. Control boundaries will be established, and the Exclusion Zone, Hot Line, Contamination Reduction Zone,
and Support Zone will be established by the site safety officer as site conditions dictate.
November 28, 2012 GENERAL HEALTH AND SAFETY PLAN

Page 2

E. HAZARD EVALUATION:

The following substance(s) are known or suspected to be on-site. The primary hazards of each substance is
identified.

FUEL OIL
PEL/TLV: 5 mg/m3 as mist
ACGIH TLV-TWA: 100 mg/m3, skin, A3
IDLH: N/A
Symptoms/Effects of Acute Exposure: Excessive exposure may cause irritation to the nose, throat, lungs, and
respiratory tract. Central nervous system (brain) effects may include headache, dizziness, loss of balance and
coordination, unconsciousness, coma, respiratory failure, and death.

NAPHTHALENE
PEL/TLV: 10 ppm
IDLH: 500 ppm
Symptoms/Effects of Acute Exposure: Eye irritation, confusion, malaise, nausea, vomiting, abdominal pain, profuse
sweating, hematuria, hemoglobinuria, renal shutdown, dermatitis.

Kerosene/Diesel
PEL/TLV: not established
IDLH: N/A
Symptoms/Effects of Acute Exposure: Eye irritation, nose respiratory system irritation, dizziness, nausea, and fatigue.
Respiratory protection not normally required.

GASOLINE
PEL/TLV: 300 ppm
IDLH: N/A
Symptoms/Effects of Acute Exposure: Irritated eyes, nose respiratory system, headache, nausea, fatigue.

The following additional hazards are expected on-site:

Possible on-looker curiosity. Care should be exercised to maintain Exclusion Zone. If on-lookers do not
observe the Site Manager's efforts to respect the Exclusion Zone, on-site activities involving contaminants
should be suspended and the S&ME Project Manager and client contact notified.

F. PERSONAL PROTECTIVE EQUIPMENT:

Based upon evaluation of the potential hazards, the following levels of personal protection have been
designated for the applicable work areas or tasks:

Location Job Function Level of Protection
Exclusion Zone Authorized Personnel Level D

Contamination
Reduction Zone
Authorized Personnel Level D

LEVEL C RESPIRATORY PROTECTION WILL BE AUTHORIZED WHEN THE PERMISSIBLE EXPOSURE
LIMIT (PEL) HAS BEEN REACHED OR EXCEEDED FOR ANY LISTED COMPOUND. DETECTION OF NON-
LISTED COMPOUNDS OR 5 PPM EXPOSURE TO ORGANIC VAPORS DETECTED BY OVA WILL REQUIRE
November 28, 2012 GENERAL HEALTH AND SAFETY PLAN

Page 3
LEVEL C RESPIRATORY PROTECTION.

When conditions warrant the Site Safety Officer or field team leader will upgrade Level of Protection to the appropriate
level for the protection of on-site and off-site health and safety. OPERATIONS WILL CEASE IMMEDIATELY.
PERSONNEL WILL LEAVE THE AREA IMMEDIATELY AND MEET AT THE DESIGNATED LOCATION.
SUBSEQUENT TO INCREASED LEVEL OF PROTECTION IMPLEMENTATION, SITE PERSONNEL WILL
ALLEVIATE ANY THREAT TO THE NON-EXCLUSION ZONES AS DIRECTED BY THE SITE MANAGER.
OPERATIONS OTHER THAN THOSE REQUIRED TO PROTECT HUMAN HEALTH AND SAFETY WILL NOT
PROCEED WITHOUT THE AUTHORIZATION OF THE SITE MANAGER.

Specific protective equipment for each level of protection is as follows:

Level C: Full-face respirator
Impermeable boots with steel toe and shank
Hard hat
Sol-Vex outer gloves/latex inner gloves.

Level D: Sol-Vex gloves
Steel toe and shank boots
Hard hat
Safety Glasses

Stages of personal decontamination for each level are as follows:

Level C:
1. Alconox and potable water scrub for gloves, boots and hard hats.
2. Potable water rinse for gloves, boots and hard hats.
3. Remove Tyveks as needed and place in trash bags.
4. Store trash bags on-site.

Level D:
1. Wash gloves and boots as needed with potable water and soap.
2. Remove gloves and place in plastic trash bags.

If air-purifying respirators are authorized, GMC-S is the appropriate cartridge for use with the MSA respirators provided
given the involved substances and concentrations anticipated. A competent individual has determined that all criteria for
using this type of respiratory protection have been met.

NO CHANGES TO THE SPECIFIED LEVELS OF PROTECTION SHALL BE MADE WITHOUT THE
APPROVAL OF THE SITE SAFETY OFFICER AND THE SITE MANAGER

G. ON-SITE WORK PLAN:

1. Go over Health and Safety Plan and look for overhead utilities and possible underground utilities
2. Perform hand-auger borings in the three areas of concern as stated in Paragraph B of this plan. The drilling
areas have previously been cleared of underground utilities by Priority Underground Locating.

November 28, 2012 GENERAL HEALTH AND SAFETY PLAN

Page 4
H. COMMUNICATION PROCEDURES:

The following standard hand signals will be used if vocal communication is not possible:
Hand gripping throat - I can't breathe.
Grip partners' wrist
or both hands around waist - Leave area immediately
Hands on top of head - Need assistance.
Thumbs up - OK, I'm all right; I understand
Thumbs down - No, negative.

I. DECONTAMINATION PROCEDURES:

Personnel and equipment leaving the Exclusion Zone shall be thoroughly decontaminated as required. The
standard Level D decontamination protocol shall be used with the following decontamination stations:

All procedures will be followed, unless site conditions warrant otherwise. Upgraded decontamination
procedures must be approved by Site Manager. Decontamination procedures are outlined above.

J. SITE AND SAFETY PLAN:

1. Roger Smith is the designated Site Safety Officer and is directly responsible to the Site Manager for safety
recommendations on site.

2. Environmental Monitoring:

The following environmental monitoring instruments shall be used on site at the specified intervals:

Organic Vapor Meters - continuous, 15-minute-interval, or as needed monitoring of breathing air space,
monitor soil cuttings, and samples.

3. Emergency Procedures:

The following standard emergency procedures will be used by on-site personnel. The Department Manager
(Mike Cashio) and Regional Safety Manager (Joe Weatherford) shall be notified of any on-site emergencies
and the Site Safety Officer shall be responsible for ensuring that the appropriate procedures are followed.

3A Emergency Escape Route: the most accessible escape route should be taken to obtain a clear safe distance from
the source of the emergency.

3B Local Emergency Response Assistance: 911.

Personnel Injuries in the Exclusion Zone:

Upon notification of an injury in the Exclusion Zone the Site Safety Officer shall evaluate the nature of the
emergency and determine appropriate action. Decontamination will be based upon the nature of the injury and the
condition of the injured person.

Fire/Explosion:

Upon notification of fire or explosion, on-site, operations shall terminate immediately, the fire department shall
be alerted, and all personnel moved to a safe distance from the involved area.
Personal Protective Equipment Failure:

If any site worker experiences failure or alteration of protective equipment that affects the protection factor
November 28, 2012 GENERAL HEALTH AND SAFETY PLAN

Page 5
that person and his/her buddy shall immediately leave the Exclusion Zone. Re-entry shall not be permitted until the
equipment has been repaired or replaced.

Other Equipment Failure:

If any other equipment on-site fails to operate properly, the Site Manager and Site Safety Officer shall be
notified and then determine the effect of this failure on continuing operation on-site. If the failure affects the safety of
personnel or prevents completion of the work plan tasks, all personnel shall leave the Exclusion Zone until the situation
is evaluated and appropriate actions are taken.

Other Emergencies:

None.

K. SIGNATURES:

By signature indicated below, all site personnel have read this plan and are familiar with its provisions.

Branch Health &
Safety Officer Mike Cashio, Jr.
Date
Project Manager Dane Horna
Date
Site Safety Officer Roger Smith
Date
Site Manager
Date
Other Site Personnel
Date
Other Site Personnel
Date
Other Site Personnel
Date
November 28, 2012 GENERAL HEALTH AND SAFETY PLAN

Page 6
L. CONTACTS:

1. PROJECT MANAGER: Dane Horna (office 704-523-4726 / cell 704-589-8604)

2. DEPARTMENT MANAGER: Mike Cashio (office 704-523-4726 / cell 704-604-6456)

2. BRANCH HEALTH & SAFETY OFFICER: C. Mike Cashio, CIH (cell 704-604-6473)

3. REGIONAL HEALTH & SAFETY OFFICER: Joe Weatherford (cell 684-979-1329)

4. LOCAL SOURCES OF ASSISTANCE:

Hospital Name: Presbyterian Hospital

Phone: [phone]
Address: 200 Hawthorne Lane, Charlotte, NC 28204

See attached map to the hospital. Travel time = 6 minutes, 1.88 mile

M. NATIONAL OR REGIONAL SOURCES OF ASSISTANCE:

1. S&ME, Inc. (Corp Office) 1-919-872-2660
2. S&ME, Inc. (Branch Office) 1-704-523-4726
3. S&ME, Inc. (Corp H&S Officer, Dan Caton) 1-919-872-2660
4. Chemtrec (24-hours) 1-800-424-9300
5. Bureau of Explosives (24-hours) 1-202-293-4048
6. National Response Center (NRS) 1-800-424-8802
(Oil/Hazardous Substances)
7. DOT Office of Hazardous Operations 1-202-426-0656
8. U-LO-CO (underground Utilities location) NC 1-800-632-4949
SC 1-800-922-0983

#=CL#
December 20, 2012
LIMS USE: FR - DANE HORNA
LIMS OBJECT ID: 92141280
92141280
Project:
Pace Project No.:
RE:
Mr. Dane Horna
S&ME, Inc.
9751 Southern Pine Blvd.
Charlotte, NC 28273
Sky House 1351-12-147
Dear Mr. Horna:
Enclosed are the analytical results for sample(s) received by the laboratory on December 10, 2012.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92141280001 MW-102 EPA 625 20 PASI-CPPM
SM 6200B 64 PASI-CMCK
92141280002 B-101 (5-7.5')EPA 8270 21 PASI-CPPM
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CTNM
92141280003 B-101 (12.5-15')EPA 8270 21 PASI-CPPM
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CTNM
92141280004 B-102 (12.5-20')EPA 8270 21 PASI-CPPM
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CTNM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=HO#
HITS ONLY
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92141280001 MW-102
Bromodichloromethane 3.1 ug/L 12/12/12 03:460.50SM 6200B
Chloroform 14.5 ug/L 12/12/12 03:460.50SM 6200B
Dibromochloromethane 1.1 ug/L 12/12/12 03:460.50SM 6200B
Methylene Chloride <2.0 ug/L 12/12/12 03:462.0SM 6200B
1,2,4-Trimethylbenzene 1.4 ug/L 12/12/12 03:460.50SM 6200B
1,3,5-Trimethylbenzene 0.75 ug/L 12/12/12 03:460.50SM 6200B
92141280002 B-101 (5-7.5')
Acetone <98.4 ug/kg 12/16/12 16:5198.4EPA 8260
Percent Moisture 8.6 %12/11/12 14:080.10ASTM D2974-87
92141280003 B-101 (12.5-15')
Acetone <91.7 ug/kg 12/12/12 19:5491.7EPA 8260
2-Butanone (MEK)<91.7 ug/kg 12/12/12 19:5491.7EPA 8260
Percent Moisture 9.4 %12/11/12 14:090.10ASTM D2974-87
92141280004 B-102 (12.5-20')
Percent Moisture 30.1 %12/12/12 12:540.10ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Method:
Client:S&ME, Inc.
EPA 625
Date:December 20, 2012
Description:625 MSSV
General Information:
1 sample was analyzed for EPA 625. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 625 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 5 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Method:
Client:S&ME, Inc.
EPA 8270
Date:December 20, 2012
Description:8270 MSSV PAH Microwave
General Information:
3 samples were analyzed for EPA 8270. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3546 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 6 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Method:
Client:S&ME, Inc.
SM 6200B
Date:December 20, 2012
Description:6200B MSV
General Information:
1 sample was analyzed for SM 6200B. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MSV/21405
A matrix spike and matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92140919010
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• MS (Lab ID: 888022)
• Chloroethane
• Dichlorodifluoromethane
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 7 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Method:
Client:S&ME, Inc.
EPA 8260
Date:December 20, 2012
Description:8260/5035A Volatile Organics
General Information:
3 samples were analyzed for EPA 8260. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
QC Batch: MSV/21420
S0: Surrogate recovery outside laboratory control limits.
• MS (Lab ID: 888650)
• Dibromofluoromethane (S)
• MSD (Lab ID: 888651)
• Dibromofluoromethane (S)
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
QC Batch: MSV/21420
L0: Analyte recovery in the laboratory control sample (LCS) was outside QC limits.
• LCS (Lab ID: 888649)
• Chloromethane
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MSV/21420
A matrix spike and matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92141204007
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• MS (Lab ID: 888650)
• 1,1-Dichloroethene
• MSD (Lab ID: 888651)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 8 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Method:
Client:S&ME, Inc.
EPA 8260
Date:December 20, 2012
Description:8260/5035A Volatile Organics
QC Batch: MSV/21420
A matrix spike and matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92141204007
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• 1,1-Dichloroethene
• Toluene
• Trichloroethene
R1: RPD value was outside control limits.
• MSD (Lab ID: 888651)
• 1,1-Dichloroethene
• Toluene
• Trichloroethene
Additional Comments:
Analyte Comments:
QC Batch: MSV/21420
E: Analyte concentration exceeded the calibration range. The reported result is estimated.
• MS (Lab ID: 888650)
• 1,1-Dichloroethene
• Trichloroethene
• MSD (Lab ID: 888651)
• 1,1-Dichloroethene
• Toluene
• Trichloroethene
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 9 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Sample:MW-102 Lab ID:92141280001 Collected:12/10/12 12:15 Received:12/10/12 16:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene <5.6 ug/L 1 12/12/12 04:25 83-32-912/11/12 10:005.6
Acenaphthylene <5.6 ug/L 1 12/12/12 04:25 208-96-812/11/12 10:005.6
Anthracene <5.6 ug/L 1 12/12/12 04:25 120-12-712/11/12 10:005.6
Benzo(a)anthracene <5.6 ug/L 1 12/12/12 04:25 56-55-312/11/12 10:005.6
Benzo(a)pyrene <5.6 ug/L 1 12/12/12 04:25 50-32-812/11/12 10:005.6
Benzo(b)fluoranthene <5.6 ug/L 1 12/12/12 04:25 205-99-212/11/12 10:005.6
Benzo(g,h,i)perylene <5.6 ug/L 1 12/12/12 04:25 191-24-212/11/12 10:005.6
Benzo(k)fluoranthene <5.6 ug/L 1 12/12/12 04:25 207-08-912/11/12 10:005.6
Chrysene <5.6 ug/L 1 12/12/12 04:25 218-01-912/11/12 10:005.6
Dibenz(a,h)anthracene <5.6 ug/L 1 12/12/12 04:25 53-70-312/11/12 10:005.6
Fluoranthene <5.6 ug/L 1 12/12/12 04:25 206-44-012/11/12 10:005.6
Fluorene <5.6 ug/L 1 12/12/12 04:25 86-73-712/11/12 10:005.6
Indeno(1,2,3-cd)pyrene <5.6 ug/L 1 12/12/12 04:25 193-39-512/11/12 10:005.6
2-Methylnaphthalene <5.6 ug/L 1 12/12/12 04:25 91-57-612/11/12 10:005.6
Naphthalene <5.6 ug/L 1 12/12/12 04:25 91-20-312/11/12 10:005.6
Phenanthrene <5.6 ug/L 1 12/12/12 04:25 85-01-812/11/12 10:005.6
Pyrene <5.6 ug/L 1 12/12/12 04:25 129-00-012/11/12 10:005.6
Surrogates
Nitrobenzene-d5 (S)46 %1 12/12/12 04:25 4165-60-012/11/12 10:0010-120
2-Fluorobiphenyl (S)46 %1 12/12/12 04:25 321-60-812/11/12 10:0015-120
Terphenyl-d14 (S)83 %1 12/12/12 04:25 1718-51-012/11/12 10:0011-131
6200B MSV Analytical Method: SM 6200B
Benzene <0.50 ug/L 1 12/12/12 03:46 71-43-20.50
Bromobenzene <0.50 ug/L 1 12/12/12 03:46 108-86-10.50
Bromochloromethane <0.50 ug/L 1 12/12/12 03:46 74-97-50.50
Bromodichloromethane 3.1 ug/L 1 12/12/12 03:46 75-27-40.50
Bromoform <0.50 ug/L 1 12/12/12 03:46 75-25-20.50
Bromomethane <5.0 ug/L 1 12/12/12 03:46 74-83-95.0
n-Butylbenzene <0.50 ug/L 1 12/12/12 03:46 104-51-80.50
sec-Butylbenzene <0.50 ug/L 1 12/12/12 03:46 135-98-80.50
tert-Butylbenzene <0.50 ug/L 1 12/12/12 03:46 98-06-60.50
Carbon tetrachloride <0.50 ug/L 1 12/12/12 03:46 56-23-50.50
Chlorobenzene <0.50 ug/L 1 12/12/12 03:46 108-90-70.50
Chloroethane <1.0 ug/L 1 12/12/12 03:46 75-00-31.0
Chloroform 14.5 ug/L 1 12/12/12 03:46 67-66-30.50
Chloromethane <1.0 ug/L 1 12/12/12 03:46 74-87-31.0
2-Chlorotoluene <0.50 ug/L 1 12/12/12 03:46 95-49-80.50
4-Chlorotoluene <0.50 ug/L 1 12/12/12 03:46 106-43-40.50
1,2-Dibromo-3-chloropropane <1.0 ug/L 1 12/12/12 03:46 96-12-81.0
Dibromochloromethane 1.1 ug/L 1 12/12/12 03:46 124-48-10.50
1,2-Dibromoethane (EDB)<0.50 ug/L 1 12/12/12 03:46 106-93-40.50
Dibromomethane <0.50 ug/L 1 12/12/12 03:46 74-95-30.50
1,2-Dichlorobenzene <0.50 ug/L 1 12/12/12 03:46 95-50-10.50
1,3-Dichlorobenzene <0.50 ug/L 1 12/12/12 03:46 541-73-10.50
1,4-Dichlorobenzene <0.50 ug/L 1 12/12/12 03:46 106-46-70.50
Dichlorodifluoromethane <0.50 ug/L 1 12/12/12 03:46 75-71-80.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 10 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Sample:MW-102 Lab ID:92141280001 Collected:12/10/12 12:15 Received:12/10/12 16:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
1,1-Dichloroethane <0.50 ug/L 1 12/12/12 03:46 75-34-30.50
1,2-Dichloroethane <0.50 ug/L 1 12/12/12 03:46 107-06-20.50
1,1-Dichloroethene <0.50 ug/L 1 12/12/12 03:46 75-35-40.50
cis-1,2-Dichloroethene <0.50 ug/L 1 12/12/12 03:46 156-59-20.50
trans-1,2-Dichloroethene <0.50 ug/L 1 12/12/12 03:46 156-60-50.50
1,2-Dichloropropane <0.50 ug/L 1 12/12/12 03:46 78-87-50.50
1,3-Dichloropropane <0.50 ug/L 1 12/12/12 03:46 142-28-90.50
2,2-Dichloropropane <0.50 ug/L 1 12/12/12 03:46 594-20-70.50
1,1-Dichloropropene <0.50 ug/L 1 12/12/12 03:46 563-58-60.50
cis-1,3-Dichloropropene <0.50 ug/L 1 12/12/12 03:46 10061-01-50.50
trans-1,3-Dichloropropene <0.50 ug/L 1 12/12/12 03:46 10061-02-60.50
Diisopropyl ether <0.50 ug/L 1 12/12/12 03:46 108-20-30.50
Ethylbenzene <0.50 ug/L 1 12/12/12 03:46 100-41-40.50
Hexachloro-1,3-butadiene <2.0 ug/L 1 12/12/12 03:46 87-68-32.0
Isopropylbenzene (Cumene)<0.50 ug/L 1 12/12/12 03:46 98-82-80.50
Methylene Chloride <2.0 ug/L 1 12/12/12 03:46 75-09-22.0
Methyl-tert-butyl ether <0.50 ug/L 1 12/12/12 03:46 1634-04-40.50
Naphthalene <2.0 ug/L 1 12/12/12 03:46 91-20-32.0
n-Propylbenzene <0.50 ug/L 1 12/12/12 03:46 103-65-10.50
Styrene <0.50 ug/L 1 12/12/12 03:46 100-42-50.50
1,1,1,2-Tetrachloroethane <0.50 ug/L 1 12/12/12 03:46 630-20-60.50
1,1,2,2-Tetrachloroethane <0.50 ug/L 1 12/12/12 03:46 79-34-50.50
Tetrachloroethene <0.50 ug/L 1 12/12/12 03:46 127-18-40.50
Toluene <0.50 ug/L 1 12/12/12 03:46 108-88-30.50
1,2,3-Trichlorobenzene <2.0 ug/L 1 12/12/12 03:46 87-61-62.0
1,2,4-Trichlorobenzene <2.0 ug/L 1 12/12/12 03:46 120-82-12.0
1,1,1-Trichloroethane <0.50 ug/L 1 12/12/12 03:46 71-55-60.50
1,1,2-Trichloroethane <0.50 ug/L 1 12/12/12 03:46 79-00-50.50
Trichloroethene <0.50 ug/L 1 12/12/12 03:46 79-01-60.50
Trichlorofluoromethane <1.0 ug/L 1 12/12/12 03:46 75-69-41.0
1,2,3-Trichloropropane <0.50 ug/L 1 12/12/12 03:46 96-18-40.50
1,2,4-Trimethylbenzene 1.4 ug/L 1 12/12/12 03:46 95-63-60.50
1,3,5-Trimethylbenzene 0.75 ug/L 1 12/12/12 03:46 108-67-80.50
Vinyl chloride <1.0 ug/L 1 12/12/12 03:46 75-01-41.0
m&p-Xylene <1.0 ug/L 1 12/12/12 03:46 179601-23-11.0
o-Xylene <0.50 ug/L 1 12/12/12 03:46 95-47-60.50
Surrogates
1,2-Dichloroethane-d4 (S)102 %1 12/12/12 03:46 17060-07-070-130
Dibromofluoromethane (S)99 %1 12/12/12 03:46 1868-53-770-130
4-Bromofluorobenzene (S)97 %1 12/12/12 03:46 460-00-470-130
Toluene-d8 (S)100 %1 12/12/12 03:46 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 11 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Sample:B-101 (5-7.5')Lab ID:92141280002 Collected:12/10/12 09:20 Received:12/10/12 16:25 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8270 MSSV PAH Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene <361 ug/kg 1 12/12/12 18:21 83-32-912/11/12 16:30361
Acenaphthylene <361 ug/kg 1 12/12/12 18:21 208-96-812/11/12 16:30361
Anthracene <361 ug/kg 1 12/12/12 18:21 120-12-712/11/12 16:30361
Benzo(a)anthracene <361 ug/kg 1 12/12/12 18:21 56-55-312/11/12 16:30361
Benzo(a)pyrene <361 ug/kg 1 12/12/12 18:21 50-32-812/11/12 16:30361
Benzo(b)fluoranthene <361 ug/kg 1 12/12/12 18:21 205-99-212/11/12 16:30361
Benzo(g,h,i)perylene <361 ug/kg 1 12/12/12 18:21 191-24-212/11/12 16:30361
Benzo(k)fluoranthene <361 ug/kg 1 12/12/12 18:21 207-08-912/11/12 16:30361
Chrysene <361 ug/kg 1 12/12/12 18:21 218-01-912/11/12 16:30361
Dibenz(a,h)anthracene <361 ug/kg 1 12/12/12 18:21 53-70-312/11/12 16:30361
Fluoranthene <361 ug/kg 1 12/12/12 18:21 206-44-012/11/12 16:30361
Fluorene <361 ug/kg 1 12/12/12 18:21 86-73-712/11/12 16:30361
Indeno(1,2,3-cd)pyrene <361 ug/kg 1 12/12/12 18:21 193-39-512/11/12 16:30361
1-Methylnaphthalene <361 ug/kg 1 12/12/12 18:21 90-12-012/11/12 16:30361
2-Methylnaphthalene <361 ug/kg 1 12/12/12 18:21 91-57-612/11/12 16:30361
Naphthalene <361 ug/kg 1 12/12/12 18:21 91-20-312/11/12 16:30361
Phenanthrene <361 ug/kg 1 12/12/12 18:21 85-01-812/11/12 16:30361
Pyrene <361 ug/kg 1 12/12/12 18:21 129-00-012/11/12 16:30361
Surrogates
Nitrobenzene-d5 (S)45 %1 12/12/12 18:21 4165-60-012/11/12 16:3023-110
2-Fluorobiphenyl (S)58 %1 12/12/12 18:21 321-60-812/11/12 16:3030-110
Terphenyl-d14 (S)63 %1 12/12/12 18:21 1718-51-012/11/12 16:3028-110
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone <98.4 ug/kg 1 12/16/12 16:51 67-64-198.4
Benzene <4.9 ug/kg 1 12/16/12 16:51 71-43-24.9
Bromobenzene <4.9 ug/kg 1 12/16/12 16:51 108-86-14.9
Bromochloromethane <4.9 ug/kg 1 12/16/12 16:51 74-97-54.9
Bromodichloromethane <4.9 ug/kg 1 12/16/12 16:51 75-27-44.9
Bromoform <4.9 ug/kg 1 12/16/12 16:51 75-25-24.9
Bromomethane <9.8 ug/kg 1 12/16/12 16:51 74-83-99.8
2-Butanone (MEK)<98.4 ug/kg 1 12/16/12 16:51 78-93-398.4
n-Butylbenzene <4.9 ug/kg 1 12/16/12 16:51 104-51-84.9
sec-Butylbenzene <4.9 ug/kg 1 12/16/12 16:51 135-98-84.9
tert-Butylbenzene <4.9 ug/kg 1 12/16/12 16:51 98-06-64.9
Carbon tetrachloride <4.9 ug/kg 1 12/16/12 16:51 56-23-54.9
Chlorobenzene <4.9 ug/kg 1 12/16/12 16:51 108-90-74.9
Chloroethane <9.8 ug/kg 1 12/16/12 16:51 75-00-39.8
Chloroform <4.9 ug/kg 1 12/16/12 16:51 67-66-34.9
Chloromethane <9.8 ug/kg 1 12/16/12 16:51 74-87-39.8
2-Chlorotoluene <4.9 ug/kg 1 12/16/12 16:51 95-49-84.9
4-Chlorotoluene <4.9 ug/kg 1 12/16/12 16:51 106-43-44.9
1,2-Dibromo-3-chloropropane <4.9 ug/kg 1 12/16/12 16:51 96-12-84.9
Dibromochloromethane <4.9 ug/kg 1 12/16/12 16:51 124-48-14.9
1,2-Dibromoethane (EDB)<4.9 ug/kg 1 12/16/12 16:51 106-93-44.9
Dibromomethane <4.9 ug/kg 1 12/16/12 16:51 74-95-34.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 12 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Sample:B-101 (5-7.5')Lab ID:92141280002 Collected:12/10/12 09:20 Received:12/10/12 16:25 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
1,2-Dichlorobenzene <4.9 ug/kg 1 12/16/12 16:51 95-50-14.9
1,3-Dichlorobenzene <4.9 ug/kg 1 12/16/12 16:51 541-73-14.9
1,4-Dichlorobenzene <4.9 ug/kg 1 12/16/12 16:51 106-46-74.9
Dichlorodifluoromethane <9.8 ug/kg 1 12/16/12 16:51 75-71-89.8
1,1-Dichloroethane <4.9 ug/kg 1 12/16/12 16:51 75-34-34.9
1,2-Dichloroethane <4.9 ug/kg 1 12/16/12 16:51 107-06-24.9
1,1-Dichloroethene <4.9 ug/kg 1 12/16/12 16:51 75-35-44.9
cis-1,2-Dichloroethene <4.9 ug/kg 1 12/16/12 16:51 156-59-24.9
trans-1,2-Dichloroethene <4.9 ug/kg 1 12/16/12 16:51 156-60-54.9
1,2-Dichloropropane <4.9 ug/kg 1 12/16/12 16:51 78-87-54.9
1,3-Dichloropropane <4.9 ug/kg 1 12/16/12 16:51 142-28-94.9
2,2-Dichloropropane <4.9 ug/kg 1 12/16/12 16:51 594-20-74.9
1,1-Dichloropropene <4.9 ug/kg 1 12/16/12 16:51 563-58-64.9
cis-1,3-Dichloropropene <4.9 ug/kg 1 12/16/12 16:51 10061-01-54.9
trans-1,3-Dichloropropene <4.9 ug/kg 1 12/16/12 16:51 10061-02-64.9
Diisopropyl ether <4.9 ug/kg 1 12/16/12 16:51 108-20-34.9
Ethylbenzene <4.9 ug/kg 1 12/16/12 16:51 100-41-44.9
Hexachloro-1,3-butadiene <4.9 ug/kg 1 12/16/12 16:51 87-68-34.9
2-Hexanone <49.2 ug/kg 1 12/16/12 16:51 591-78-649.2
Isopropylbenzene (Cumene)<4.9 ug/kg 1 12/16/12 16:51 98-82-84.9
p-Isopropyltoluene <4.9 ug/kg 1 12/16/12 16:51 99-87-64.9
Methylene Chloride <19.7 ug/kg 1 12/16/12 16:51 75-09-219.7
4-Methyl-2-pentanone (MIBK)<49.2 ug/kg 1 12/16/12 16:51 108-10-149.2
Methyl-tert-butyl ether <4.9 ug/kg 1 12/16/12 16:51 1634-04-44.9
Naphthalene <4.9 ug/kg 1 12/16/12 16:51 91-20-34.9
n-Propylbenzene <4.9 ug/kg 1 12/16/12 16:51 103-65-14.9
Styrene <4.9 ug/kg 1 12/16/12 16:51 100-42-54.9
1,1,1,2-Tetrachloroethane <4.9 ug/kg 1 12/16/12 16:51 630-20-64.9
1,1,2,2-Tetrachloroethane <4.9 ug/kg 1 12/16/12 16:51 79-34-54.9
Tetrachloroethene <4.9 ug/kg 1 12/16/12 16:51 127-18-44.9
Toluene <4.9 ug/kg 1 12/16/12 16:51 108-88-34.9
1,2,3-Trichlorobenzene <4.9 ug/kg 1 12/16/12 16:51 87-61-64.9
1,2,4-Trichlorobenzene <4.9 ug/kg 1 12/16/12 16:51 120-82-14.9
1,1,1-Trichloroethane <4.9 ug/kg 1 12/16/12 16:51 71-55-64.9
1,1,2-Trichloroethane <4.9 ug/kg 1 12/16/12 16:51 79-00-54.9
Trichloroethene <4.9 ug/kg 1 12/16/12 16:51 79-01-64.9
Trichlorofluoromethane <4.9 ug/kg 1 12/16/12 16:51 75-69-44.9
1,2,3-Trichloropropane <4.9 ug/kg 1 12/16/12 16:51 96-18-44.9
1,2,4-Trimethylbenzene <4.9 ug/kg 1 12/16/12 16:51 95-63-64.9
1,3,5-Trimethylbenzene <4.9 ug/kg 1 12/16/12 16:51 108-67-84.9
Vinyl acetate <49.2 ug/kg 1 12/16/12 16:51 108-05-449.2
Vinyl chloride <9.8 ug/kg 1 12/16/12 16:51 75-01-49.8
Xylene (Total)<9.8 ug/kg 1 12/16/12 16:51 1330-20-79.8
m&p-Xylene <9.8 ug/kg 1 12/16/12 16:51 179601-23-19.8
o-Xylene <4.9 ug/kg 1 12/16/12 16:51 95-47-64.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 13 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Sample:B-101 (5-7.5')Lab ID:92141280002 Collected:12/10/12 09:20 Received:12/10/12 16:25 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Surrogates
Dibromofluoromethane (S)88 %1 12/16/12 16:51 1868-53-770-130
Toluene-d8 (S)106 %1 12/16/12 16:51 2037-26-570-130
4-Bromofluorobenzene (S)98 %1 12/16/12 16:51 460-00-470-130
1,2-Dichloroethane-d4 (S)86 %1 12/16/12 16:51 17060-07-070-132
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 8.6 %1 12/11/12 14:080.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 14 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Sample:B-101 (12.5-15')Lab ID:92141280003 Collected:12/10/12 09:30 Received:12/10/12 16:25 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8270 MSSV PAH Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene <364 ug/kg 1 12/12/12 18:49 83-32-912/11/12 16:30364
Acenaphthylene <364 ug/kg 1 12/12/12 18:49 208-96-812/11/12 16:30364
Anthracene <364 ug/kg 1 12/12/12 18:49 120-12-712/11/12 16:30364
Benzo(a)anthracene <364 ug/kg 1 12/12/12 18:49 56-55-312/11/12 16:30364
Benzo(a)pyrene <364 ug/kg 1 12/12/12 18:49 50-32-812/11/12 16:30364
Benzo(b)fluoranthene <364 ug/kg 1 12/12/12 18:49 205-99-212/11/12 16:30364
Benzo(g,h,i)perylene <364 ug/kg 1 12/12/12 18:49 191-24-212/11/12 16:30364
Benzo(k)fluoranthene <364 ug/kg 1 12/12/12 18:49 207-08-912/11/12 16:30364
Chrysene <364 ug/kg 1 12/12/12 18:49 218-01-912/11/12 16:30364
Dibenz(a,h)anthracene <364 ug/kg 1 12/12/12 18:49 53-70-312/11/12 16:30364
Fluoranthene <364 ug/kg 1 12/12/12 18:49 206-44-012/11/12 16:30364
Fluorene <364 ug/kg 1 12/12/12 18:49 86-73-712/11/12 16:30364
Indeno(1,2,3-cd)pyrene <364 ug/kg 1 12/12/12 18:49 193-39-512/11/12 16:30364
1-Methylnaphthalene <364 ug/kg 1 12/12/12 18:49 90-12-012/11/12 16:30364
2-Methylnaphthalene <364 ug/kg 1 12/12/12 18:49 91-57-612/11/12 16:30364
Naphthalene <364 ug/kg 1 12/12/12 18:49 91-20-312/11/12 16:30364
Phenanthrene <364 ug/kg 1 12/12/12 18:49 85-01-812/11/12 16:30364
Pyrene <364 ug/kg 1 12/12/12 18:49 129-00-012/11/12 16:30364
Surrogates
Nitrobenzene-d5 (S)56 %1 12/12/12 18:49 4165-60-012/11/12 16:3023-110
2-Fluorobiphenyl (S)71 %1 12/12/12 18:49 321-60-812/11/12 16:3030-110
Terphenyl-d14 (S)79 %1 12/12/12 18:49 1718-51-012/11/12 16:3028-110
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone <91.7 ug/kg 1 12/12/12 19:54 67-64-191.7
Benzene <4.6 ug/kg 1 12/12/12 19:54 71-43-24.6
Bromobenzene <4.6 ug/kg 1 12/12/12 19:54 108-86-14.6
Bromochloromethane <4.6 ug/kg 1 12/12/12 19:54 74-97-54.6
Bromodichloromethane <4.6 ug/kg 1 12/12/12 19:54 75-27-44.6
Bromoform <4.6 ug/kg 1 12/12/12 19:54 75-25-24.6
Bromomethane <9.2 ug/kg 1 12/12/12 19:54 74-83-99.2
2-Butanone (MEK)<91.7 ug/kg 1 12/12/12 19:54 78-93-391.7
n-Butylbenzene <4.6 ug/kg 1 12/12/12 19:54 104-51-84.6
sec-Butylbenzene <4.6 ug/kg 1 12/12/12 19:54 135-98-84.6
tert-Butylbenzene <4.6 ug/kg 1 12/12/12 19:54 98-06-64.6
Carbon tetrachloride <4.6 ug/kg 1 12/12/12 19:54 56-23-54.6
Chlorobenzene <4.6 ug/kg 1 12/12/12 19:54 108-90-74.6
Chloroethane <9.2 ug/kg 1 12/12/12 19:54 75-00-39.2
Chloroform <4.6 ug/kg 1 12/12/12 19:54 67-66-34.6
Chloromethane <9.2 ug/kg 1 12/12/12 19:54 74-87-39.2
2-Chlorotoluene <4.6 ug/kg 1 12/12/12 19:54 95-49-84.6
4-Chlorotoluene <4.6 ug/kg 1 12/12/12 19:54 106-43-44.6
1,2-Dibromo-3-chloropropane <4.6 ug/kg 1 12/12/12 19:54 96-12-84.6
Dibromochloromethane <4.6 ug/kg 1 12/12/12 19:54 124-48-14.6
1,2-Dibromoethane (EDB)<4.6 ug/kg 1 12/12/12 19:54 106-93-44.6
Dibromomethane <4.6 ug/kg 1 12/12/12 19:54 74-95-34.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 15 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Sample:B-101 (12.5-15')Lab ID:92141280003 Collected:12/10/12 09:30 Received:12/10/12 16:25 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
1,2-Dichlorobenzene <4.6 ug/kg 1 12/12/12 19:54 95-50-14.6
1,3-Dichlorobenzene <4.6 ug/kg 1 12/12/12 19:54 541-73-14.6
1,4-Dichlorobenzene <4.6 ug/kg 1 12/12/12 19:54 106-46-74.6
Dichlorodifluoromethane <9.2 ug/kg 1 12/12/12 19:54 75-71-89.2
1,1-Dichloroethane <4.6 ug/kg 1 12/12/12 19:54 75-34-34.6
1,2-Dichloroethane <4.6 ug/kg 1 12/12/12 19:54 107-06-24.6
1,1-Dichloroethene <4.6 ug/kg 1 12/12/12 19:54 75-35-44.6
cis-1,2-Dichloroethene <4.6 ug/kg 1 12/12/12 19:54 156-59-24.6
trans-1,2-Dichloroethene <4.6 ug/kg 1 12/12/12 19:54 156-60-54.6
1,2-Dichloropropane <4.6 ug/kg 1 12/12/12 19:54 78-87-54.6
1,3-Dichloropropane <4.6 ug/kg 1 12/12/12 19:54 142-28-94.6
2,2-Dichloropropane <4.6 ug/kg 1 12/12/12 19:54 594-20-74.6
1,1-Dichloropropene <4.6 ug/kg 1 12/12/12 19:54 563-58-64.6
cis-1,3-Dichloropropene <4.6 ug/kg 1 12/12/12 19:54 10061-01-54.6
trans-1,3-Dichloropropene <4.6 ug/kg 1 12/12/12 19:54 10061-02-64.6
Diisopropyl ether <4.6 ug/kg 1 12/12/12 19:54 108-20-34.6
Ethylbenzene <4.6 ug/kg 1 12/12/12 19:54 100-41-44.6
Hexachloro-1,3-butadiene <4.6 ug/kg 1 12/12/12 19:54 87-68-34.6
2-Hexanone <45.9 ug/kg 1 12/12/12 19:54 591-78-645.9
Isopropylbenzene (Cumene)<4.6 ug/kg 1 12/12/12 19:54 98-82-84.6
p-Isopropyltoluene <4.6 ug/kg 1 12/12/12 19:54 99-87-64.6
Methylene Chloride <18.3 ug/kg 1 12/12/12 19:54 75-09-218.3
4-Methyl-2-pentanone (MIBK)<45.9 ug/kg 1 12/12/12 19:54 108-10-145.9
Methyl-tert-butyl ether <4.6 ug/kg 1 12/12/12 19:54 1634-04-44.6
Naphthalene <4.6 ug/kg 1 12/12/12 19:54 91-20-34.6
n-Propylbenzene <4.6 ug/kg 1 12/12/12 19:54 103-65-14.6
Styrene <4.6 ug/kg 1 12/12/12 19:54 100-42-54.6
1,1,1,2-Tetrachloroethane <4.6 ug/kg 1 12/12/12 19:54 630-20-64.6
1,1,2,2-Tetrachloroethane <4.6 ug/kg 1 12/12/12 19:54 79-34-54.6
Tetrachloroethene <4.6 ug/kg 1 12/12/12 19:54 127-18-44.6
Toluene <4.6 ug/kg 1 12/12/12 19:54 108-88-34.6
1,2,3-Trichlorobenzene <4.6 ug/kg 1 12/12/12 19:54 87-61-64.6
1,2,4-Trichlorobenzene <4.6 ug/kg 1 12/12/12 19:54 120-82-14.6
1,1,1-Trichloroethane <4.6 ug/kg 1 12/12/12 19:54 71-55-64.6
1,1,2-Trichloroethane <4.6 ug/kg 1 12/12/12 19:54 79-00-54.6
Trichloroethene <4.6 ug/kg 1 12/12/12 19:54 79-01-64.6
Trichlorofluoromethane <4.6 ug/kg 1 12/12/12 19:54 75-69-44.6
1,2,3-Trichloropropane <4.6 ug/kg 1 12/12/12 19:54 96-18-44.6
1,2,4-Trimethylbenzene <4.6 ug/kg 1 12/12/12 19:54 95-63-64.6
1,3,5-Trimethylbenzene <4.6 ug/kg 1 12/12/12 19:54 108-67-84.6
Vinyl acetate <45.9 ug/kg 1 12/12/12 19:54 108-05-445.9
Vinyl chloride <9.2 ug/kg 1 12/12/12 19:54 75-01-49.2
Xylene (Total)<9.2 ug/kg 1 12/12/12 19:54 1330-20-79.2
m&p-Xylene <9.2 ug/kg 1 12/12/12 19:54 179601-23-19.2
o-Xylene <4.6 ug/kg 1 12/12/12 19:54 95-47-64.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 16 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Sample:B-101 (12.5-15')Lab ID:92141280003 Collected:12/10/12 09:30 Received:12/10/12 16:25 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Surrogates
Dibromofluoromethane (S)94 %1 12/12/12 19:54 1868-53-770-130
Toluene-d8 (S)100 %1 12/12/12 19:54 2037-26-570-130
4-Bromofluorobenzene (S)97 %1 12/12/12 19:54 460-00-470-130
1,2-Dichloroethane-d4 (S)97 %1 12/12/12 19:54 17060-07-070-132
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 9.4 %1 12/11/12 14:090.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 17 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Sample:B-102 (12.5-20')Lab ID:92141280004 Collected:12/10/12 09:30 Received:12/10/12 16:25 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8270 MSSV PAH Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene <472 ug/kg 1 12/12/12 19:17 83-32-912/11/12 16:30472
Acenaphthylene <472 ug/kg 1 12/12/12 19:17 208-96-812/11/12 16:30472
Anthracene <472 ug/kg 1 12/12/12 19:17 120-12-712/11/12 16:30472
Benzo(a)anthracene <472 ug/kg 1 12/12/12 19:17 56-55-312/11/12 16:30472
Benzo(a)pyrene <472 ug/kg 1 12/12/12 19:17 50-32-812/11/12 16:30472
Benzo(b)fluoranthene <472 ug/kg 1 12/12/12 19:17 205-99-212/11/12 16:30472
Benzo(g,h,i)perylene <472 ug/kg 1 12/12/12 19:17 191-24-212/11/12 16:30472
Benzo(k)fluoranthene <472 ug/kg 1 12/12/12 19:17 207-08-912/11/12 16:30472
Chrysene <472 ug/kg 1 12/12/12 19:17 218-01-912/11/12 16:30472
Dibenz(a,h)anthracene <472 ug/kg 1 12/12/12 19:17 53-70-312/11/12 16:30472
Fluoranthene <472 ug/kg 1 12/12/12 19:17 206-44-012/11/12 16:30472
Fluorene <472 ug/kg 1 12/12/12 19:17 86-73-712/11/12 16:30472
Indeno(1,2,3-cd)pyrene <472 ug/kg 1 12/12/12 19:17 193-39-512/11/12 16:30472
1-Methylnaphthalene <472 ug/kg 1 12/12/12 19:17 90-12-012/11/12 16:30472
2-Methylnaphthalene <472 ug/kg 1 12/12/12 19:17 91-57-612/11/12 16:30472
Naphthalene <472 ug/kg 1 12/12/12 19:17 91-20-312/11/12 16:30472
Phenanthrene <472 ug/kg 1 12/12/12 19:17 85-01-812/11/12 16:30472
Pyrene <472 ug/kg 1 12/12/12 19:17 129-00-012/11/12 16:30472
Surrogates
Nitrobenzene-d5 (S)54 %1 12/12/12 19:17 4165-60-012/11/12 16:3023-110
2-Fluorobiphenyl (S)58 %1 12/12/12 19:17 321-60-812/11/12 16:3030-110
Terphenyl-d14 (S)72 %1 12/12/12 19:17 1718-51-012/11/12 16:3028-110
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone <134 ug/kg 1 12/12/12 20:13 67-64-1134
Benzene <6.7 ug/kg 1 12/12/12 20:13 71-43-26.7
Bromobenzene <6.7 ug/kg 1 12/12/12 20:13 108-86-16.7
Bromochloromethane <6.7 ug/kg 1 12/12/12 20:13 74-97-56.7
Bromodichloromethane <6.7 ug/kg 1 12/12/12 20:13 75-27-46.7
Bromoform <6.7 ug/kg 1 12/12/12 20:13 75-25-26.7
Bromomethane <13.4 ug/kg 1 12/12/12 20:13 74-83-913.4
2-Butanone (MEK)<134 ug/kg 1 12/12/12 20:13 78-93-3134
n-Butylbenzene <6.7 ug/kg 1 12/12/12 20:13 104-51-86.7
sec-Butylbenzene <6.7 ug/kg 1 12/12/12 20:13 135-98-86.7
tert-Butylbenzene <6.7 ug/kg 1 12/12/12 20:13 98-06-66.7
Carbon tetrachloride <6.7 ug/kg 1 12/12/12 20:13 56-23-56.7
Chlorobenzene <6.7 ug/kg 1 12/12/12 20:13 108-90-76.7
Chloroethane <13.4 ug/kg 1 12/12/12 20:13 75-00-313.4
Chloroform <6.7 ug/kg 1 12/12/12 20:13 67-66-36.7
Chloromethane <13.4 ug/kg 1 12/12/12 20:13 74-87-313.4
2-Chlorotoluene <6.7 ug/kg 1 12/12/12 20:13 95-49-86.7
4-Chlorotoluene <6.7 ug/kg 1 12/12/12 20:13 106-43-46.7
1,2-Dibromo-3-chloropropane <6.7 ug/kg 1 12/12/12 20:13 96-12-86.7
Dibromochloromethane <6.7 ug/kg 1 12/12/12 20:13 124-48-16.7
1,2-Dibromoethane (EDB)<6.7 ug/kg 1 12/12/12 20:13 106-93-46.7
Dibromomethane <6.7 ug/kg 1 12/12/12 20:13 74-95-36.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 18 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Sample:B-102 (12.5-20')Lab ID:92141280004 Collected:12/10/12 09:30 Received:12/10/12 16:25 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
1,2-Dichlorobenzene <6.7 ug/kg 1 12/12/12 20:13 95-50-16.7
1,3-Dichlorobenzene <6.7 ug/kg 1 12/12/12 20:13 541-73-16.7
1,4-Dichlorobenzene <6.7 ug/kg 1 12/12/12 20:13 106-46-76.7
Dichlorodifluoromethane <13.4 ug/kg 1 12/12/12 20:13 75-71-813.4
1,1-Dichloroethane <6.7 ug/kg 1 12/12/12 20:13 75-34-36.7
1,2-Dichloroethane <6.7 ug/kg 1 12/12/12 20:13 107-06-26.7
1,1-Dichloroethene <6.7 ug/kg 1 12/12/12 20:13 75-35-46.7
cis-1,2-Dichloroethene <6.7 ug/kg 1 12/12/12 20:13 156-59-26.7
trans-1,2-Dichloroethene <6.7 ug/kg 1 12/12/12 20:13 156-60-56.7
1,2-Dichloropropane <6.7 ug/kg 1 12/12/12 20:13 78-87-56.7
1,3-Dichloropropane <6.7 ug/kg 1 12/12/12 20:13 142-28-96.7
2,2-Dichloropropane <6.7 ug/kg 1 12/12/12 20:13 594-20-76.7
1,1-Dichloropropene <6.7 ug/kg 1 12/12/12 20:13 563-58-66.7
cis-1,3-Dichloropropene <6.7 ug/kg 1 12/12/12 20:13 10061-01-56.7
trans-1,3-Dichloropropene <6.7 ug/kg 1 12/12/12 20:13 10061-02-66.7
Diisopropyl ether <6.7 ug/kg 1 12/12/12 20:13 108-20-36.7
Ethylbenzene <6.7 ug/kg 1 12/12/12 20:13 100-41-46.7
Hexachloro-1,3-butadiene <6.7 ug/kg 1 12/12/12 20:13 87-68-36.7
2-Hexanone <67.2 ug/kg 1 12/12/12 20:13 591-78-667.2
Isopropylbenzene (Cumene)<6.7 ug/kg 1 12/12/12 20:13 98-82-86.7
p-Isopropyltoluene <6.7 ug/kg 1 12/12/12 20:13 99-87-66.7
Methylene Chloride <26.9 ug/kg 1 12/12/12 20:13 75-09-226.9
4-Methyl-2-pentanone (MIBK)<67.2 ug/kg 1 12/12/12 20:13 108-10-167.2
Methyl-tert-butyl ether <6.7 ug/kg 1 12/12/12 20:13 1634-04-46.7
Naphthalene <6.7 ug/kg 1 12/12/12 20:13 91-20-36.7
n-Propylbenzene <6.7 ug/kg 1 12/12/12 20:13 103-65-16.7
Styrene <6.7 ug/kg 1 12/12/12 20:13 100-42-56.7
1,1,1,2-Tetrachloroethane <6.7 ug/kg 1 12/12/12 20:13 630-20-66.7
1,1,2,2-Tetrachloroethane <6.7 ug/kg 1 12/12/12 20:13 79-34-56.7
Tetrachloroethene <6.7 ug/kg 1 12/12/12 20:13 127-18-46.7
Toluene <6.7 ug/kg 1 12/12/12 20:13 108-88-36.7
1,2,3-Trichlorobenzene <6.7 ug/kg 1 12/12/12 20:13 87-61-66.7
1,2,4-Trichlorobenzene <6.7 ug/kg 1 12/12/12 20:13 120-82-16.7
1,1,1-Trichloroethane <6.7 ug/kg 1 12/12/12 20:13 71-55-66.7
1,1,2-Trichloroethane <6.7 ug/kg 1 12/12/12 20:13 79-00-56.7
Trichloroethene <6.7 ug/kg 1 12/12/12 20:13 79-01-66.7
Trichlorofluoromethane <6.7 ug/kg 1 12/12/12 20:13 75-69-46.7
1,2,3-Trichloropropane <6.7 ug/kg 1 12/12/12 20:13 96-18-46.7
1,2,4-Trimethylbenzene <6.7 ug/kg 1 12/12/12 20:13 95-63-66.7
1,3,5-Trimethylbenzene <6.7 ug/kg 1 12/12/12 20:13 108-67-86.7
Vinyl acetate <67.2 ug/kg 1 12/12/12 20:13 108-05-467.2
Vinyl chloride <13.4 ug/kg 1 12/12/12 20:13 75-01-413.4
Xylene (Total)<13.4 ug/kg 1 12/12/12 20:13 1330-20-713.4
m&p-Xylene <13.4 ug/kg 1 12/12/12 20:13 179601-23-113.4
o-Xylene <6.7 ug/kg 1 12/12/12 20:13 95-47-66.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 19 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Sample:B-102 (12.5-20')Lab ID:92141280004 Collected:12/10/12 09:30 Received:12/10/12 16:25 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Surrogates
Dibromofluoromethane (S)98 %1 12/12/12 20:13 1868-53-770-130
Toluene-d8 (S)97 %1 12/12/12 20:13 2037-26-570-130
4-Bromofluorobenzene (S)101 %1 12/12/12 20:13 460-00-470-130
1,2-Dichloroethane-d4 (S)95 %1 12/12/12 20:13 17060-07-070-132
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 30.1 %1 12/12/12 12:540.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 20 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/21405
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92141280001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:888020
Associated Lab Samples:92141280001
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L <0.50 0.50 12/12/12 02:13
1,1,1-Trichloroethane ug/L <0.50 0.50 12/12/12 02:13
1,1,2,2-Tetrachloroethane ug/L <0.50 0.50 12/12/12 02:13
1,1,2-Trichloroethane ug/L <0.50 0.50 12/12/12 02:13
1,1-Dichloroethane ug/L <0.50 0.50 12/12/12 02:13
1,1-Dichloroethene ug/L <0.50 0.50 12/12/12 02:13
1,1-Dichloropropene ug/L <0.50 0.50 12/12/12 02:13
1,2,3-Trichlorobenzene ug/L <2.0 2.0 12/12/12 02:13
1,2,3-Trichloropropane ug/L <0.50 0.50 12/12/12 02:13
1,2,4-Trichlorobenzene ug/L <2.0 2.0 12/12/12 02:13
1,2,4-Trimethylbenzene ug/L <0.50 0.50 12/12/12 02:13
1,2-Dibromo-3-chloropropane ug/L <1.0 1.0 12/12/12 02:13
1,2-Dibromoethane (EDB)ug/L <0.50 0.50 12/12/12 02:13
1,2-Dichlorobenzene ug/L <0.50 0.50 12/12/12 02:13
1,2-Dichloroethane ug/L <0.50 0.50 12/12/12 02:13
1,2-Dichloropropane ug/L <0.50 0.50 12/12/12 02:13
1,3,5-Trimethylbenzene ug/L <0.50 0.50 12/12/12 02:13
1,3-Dichlorobenzene ug/L <0.50 0.50 12/12/12 02:13
1,3-Dichloropropane ug/L <0.50 0.50 12/12/12 02:13
1,4-Dichlorobenzene ug/L <0.50 0.50 12/12/12 02:13
2,2-Dichloropropane ug/L <0.50 0.50 12/12/12 02:13
2-Chlorotoluene ug/L <0.50 0.50 12/12/12 02:13
4-Chlorotoluene ug/L <0.50 0.50 12/12/12 02:13
Benzene ug/L <0.50 0.50 12/12/12 02:13
Bromobenzene ug/L <0.50 0.50 12/12/12 02:13
Bromochloromethane ug/L <0.50 0.50 12/12/12 02:13
Bromodichloromethane ug/L <0.50 0.50 12/12/12 02:13
Bromoform ug/L <0.50 0.50 12/12/12 02:13
Bromomethane ug/L <5.0 5.0 12/12/12 02:13
Carbon tetrachloride ug/L <0.50 0.50 12/12/12 02:13
Chlorobenzene ug/L <0.50 0.50 12/12/12 02:13
Chloroethane ug/L <1.0 1.0 12/12/12 02:13
Chloroform ug/L <0.50 0.50 12/12/12 02:13
Chloromethane ug/L <1.0 1.0 12/12/12 02:13
cis-1,2-Dichloroethene ug/L <0.50 0.50 12/12/12 02:13
cis-1,3-Dichloropropene ug/L <0.50 0.50 12/12/12 02:13
Dibromochloromethane ug/L <0.50 0.50 12/12/12 02:13
Dibromomethane ug/L <0.50 0.50 12/12/12 02:13
Dichlorodifluoromethane ug/L <0.50 0.50 12/12/12 02:13
Diisopropyl ether ug/L <0.50 0.50 12/12/12 02:13
Ethylbenzene ug/L <0.50 0.50 12/12/12 02:13
Hexachloro-1,3-butadiene ug/L <2.0 2.0 12/12/12 02:13
Isopropylbenzene (Cumene)ug/L <0.50 0.50 12/12/12 02:13
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 21 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:888020
Associated Lab Samples:92141280001
Matrix:Water
Analyzed
m&p-Xylene ug/L <1.0 1.0 12/12/12 02:13
Methyl-tert-butyl ether ug/L <0.50 0.50 12/12/12 02:13
Methylene Chloride ug/L <2.0 2.0 12/12/12 02:13
n-Butylbenzene ug/L <0.50 0.50 12/12/12 02:13
n-Propylbenzene ug/L <0.50 0.50 12/12/12 02:13
Naphthalene ug/L <2.0 2.0 12/12/12 02:13
o-Xylene ug/L <0.50 0.50 12/12/12 02:13
sec-Butylbenzene ug/L <0.50 0.50 12/12/12 02:13
Styrene ug/L <0.50 0.50 12/12/12 02:13
tert-Butylbenzene ug/L <0.50 0.50 12/12/12 02:13
Tetrachloroethene ug/L <0.50 0.50 12/12/12 02:13
Toluene ug/L <0.50 0.50 12/12/12 02:13
trans-1,2-Dichloroethene ug/L <0.50 0.50 12/12/12 02:13
trans-1,3-Dichloropropene ug/L <0.50 0.50 12/12/12 02:13
Trichloroethene ug/L <0.50 0.50 12/12/12 02:13
Trichlorofluoromethane ug/L <1.0 1.0 12/12/12 02:13
Vinyl chloride ug/L <1.0 1.0 12/12/12 02:13
1,2-Dichloroethane-d4 (S)%102 70-130 12/12/12 02:13
4-Bromofluorobenzene (S)%95 70-130 12/12/12 02:13
Dibromofluoromethane (S)%98 70-130 12/12/12 02:13
Toluene-d8 (S)%99 70-130 12/12/12 02:13
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
888021LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.950 102 60-140
1,1,1-Trichloroethane ug/L 49.150 98 60-140
1,1,2,2-Tetrachloroethane ug/L 49.850 100 60-140
1,1,2-Trichloroethane ug/L 50.350 101 60-140
1,1-Dichloroethane ug/L 45.750 91 60-140
1,1-Dichloroethene ug/L 45.750 91 60-140
1,1-Dichloropropene ug/L 50.550 101 60-140
1,2,3-Trichlorobenzene ug/L 51.050 102 60-140
1,2,3-Trichloropropane ug/L 50.550 101 60-140
1,2,4-Trichlorobenzene ug/L 52.750 105 60-140
1,2,4-Trimethylbenzene ug/L 49.550 99 60-140
1,2-Dibromo-3-chloropropane ug/L 55.950 112 60-140
1,2-Dibromoethane (EDB)ug/L 52.350 105 60-140
1,2-Dichlorobenzene ug/L 51.950 104 60-140
1,2-Dichloroethane ug/L 49.250 98 60-140
1,2-Dichloropropane ug/L 47.350 95 60-140
1,3,5-Trimethylbenzene ug/L 49.250 98 60-140
1,3-Dichlorobenzene ug/L 49.750 99 60-140
1,3-Dichloropropane ug/L 48.650 97 60-140
1,4-Dichlorobenzene ug/L 49.250 98 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 22 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
888021LABORATORY CONTROL SAMPLE:
LCSSpike
2,2-Dichloropropane ug/L 44.950 90 60-140
2-Chlorotoluene ug/L 48.850 98 60-140
4-Chlorotoluene ug/L 49.850 100 60-140
Benzene ug/L 45.350 91 60-140
Bromobenzene ug/L 48.450 97 60-140
Bromochloromethane ug/L 51.150 102 60-140
Bromodichloromethane ug/L 49.350 99 60-140
Bromoform ug/L 53.050 106 60-140
Bromomethane ug/L 49.750 99 60-140
Carbon tetrachloride ug/L 48.750 97 60-140
Chlorobenzene ug/L 48.850 98 60-140
Chloroethane ug/L 51.850 104 60-140
Chloroform ug/L 47.450 95 60-140
Chloromethane ug/L 50.250 100 60-140
cis-1,2-Dichloroethene ug/L 47.250 94 60-140
cis-1,3-Dichloropropene ug/L 48.950 98 60-140
Dibromochloromethane ug/L 51.050 102 60-140
Dibromomethane ug/L 49.350 99 60-140
Dichlorodifluoromethane ug/L 57.150 114 60-140
Diisopropyl ether ug/L 51.750 103 60-140
Ethylbenzene ug/L 48.650 97 60-140
Hexachloro-1,3-butadiene ug/L 50.450 101 60-140
Isopropylbenzene (Cumene)ug/L 51.350 103 60-140
m&p-Xylene ug/L 99.5100 99 60-140
Methyl-tert-butyl ether ug/L 47.850 96 60-140
Methylene Chloride ug/L 48.650 97 60-140
n-Butylbenzene ug/L 50.750 101 60-140
n-Propylbenzene ug/L 48.050 96 60-140
Naphthalene ug/L 55.250 110 60-140
o-Xylene ug/L 48.650 97 60-140
sec-Butylbenzene ug/L 49.250 98 60-140
Styrene ug/L 54.650 109 60-140
tert-Butylbenzene ug/L 50.050 100 60-140
Tetrachloroethene ug/L 49.750 99 60-140
Toluene ug/L 46.250 92 60-140
trans-1,2-Dichloroethene ug/L 45.250 90 60-140
trans-1,3-Dichloropropene ug/L 49.750 99 60-140
Trichloroethene ug/L 46.150 92 60-140
Trichlorofluoromethane ug/L 48.350 97 60-140
Vinyl chloride ug/L 46.750 93 60-140
1,2-Dichloroethane-d4 (S)%101 70-130
4-Bromofluorobenzene (S)%102 70-130
Dibromofluoromethane (S)%98 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 23 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
888022MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92140919010
888023
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 132 60-140113 1520ND26.3 22.6
1,1,1-Trichloroethane ug/L 20 128 60-140114 1220ND25.6 22.8
1,1,2,2-Tetrachloroethane ug/L 20 113 60-14096 1720ND22.6 19.2
1,1,2-Trichloroethane ug/L 20 121 60-140109 1120ND24.2 21.7
1,1-Dichloroethane ug/L 20 118 60-140102 1420ND23.7 20.5
1,1-Dichloroethene ug/L 20 116 60-140106 920ND23.2 21.2
1,1-Dichloropropene ug/L 20 126 60-140110 1420ND25.3 22.0
1,2,3-Trichlorobenzene ug/L 20 119 60-140107 1120ND23.7 21.3
1,2,3-Trichloropropane ug/L 20 121 60-140104 1520ND24.2 20.9
1,2,4-Trichlorobenzene ug/L 20 120 60-140110 920ND24.0 22.0
1,2,4-Trimethylbenzene ug/L 20 127 60-140115 1020ND25.5 23.2
1,2-Dibromo-3-chloropropane ug/L 20 136 60-140110 2120ND27.1 22.0
1,2-Dibromoethane (EDB)ug/L 20 127 60-140113 1220ND25.4 22.5
1,2-Dichlorobenzene ug/L 20 124 60-140112 1120ND24.8 22.4
1,2-Dichloroethane ug/L 20 123 60-140107 1420ND24.6 21.4
1,2-Dichloropropane ug/L 20 120 60-140105 1320ND23.9 21.1
1,3,5-Trimethylbenzene ug/L 20 126 60-140117 720ND25.2 23.4
1,3-Dichlorobenzene ug/L 20 120 60-140108 1020ND23.9 21.6
1,3-Dichloropropane ug/L 20 123 60-140108 1320ND24.7 21.7
1,4-Dichlorobenzene ug/L 20 118 60-140106 1120ND23.6 21.3
2,2-Dichloropropane ug/L 20 109 60-14097 1220ND21.8 19.4
2-Chlorotoluene ug/L 20 123 60-140113 920ND24.7 22.6
4-Chlorotoluene ug/L 20 127 60-140117 820ND25.4 23.5
Benzene ug/L 20 118 60-140103 1420ND23.6 20.5
Bromobenzene ug/L 20 121 60-140109 1020ND24.1 21.8
Bromochloromethane ug/L 20 123 60-140111 1120ND24.7 22.1
Bromodichloromethane ug/L 20 128 60-140112 1320ND25.6 22.5
Bromoform ug/L 20 134 60-140110 2020ND26.8 22.0
Bromomethane ug/L 20 74 60-14081 1020ND14.7 16.3
Carbon tetrachloride ug/L 20 133 60-140116 1320ND26.5 23.2
Chlorobenzene ug/L 20 126 60-140110 1320ND25.2 22.0
Chloroethane ug/L M02014460-140134 720ND28.8 26.8
Chloroform ug/L 20 119 60-140106 1220ND23.9 21.2
Chloromethane ug/L 20 125 60-140117 720ND25.0 23.4
cis-1,2-Dichloroethene ug/L 20 118 60-140103 1420ND23.6 20.5
cis-1,3-Dichloropropene ug/L 20 116 60-140103 1220ND23.2 20.6
Dibromochloromethane ug/L 20 131 60-140114 1420ND26.2 22.7
Dibromomethane ug/L 20 123 60-140105 1620ND24.6 21.1
Dichlorodifluoromethane ug/L M02014860-140132 1120ND29.5 26.5
Diisopropyl ether ug/L 20 128 60-140108 1720ND25.5 21.6
Ethylbenzene ug/L 20 126 60-140109 1520ND25.2 21.8
Hexachloro-1,3-butadiene ug/L 20 113 60-140103 1020ND22.6 20.5
Isopropylbenzene (Cumene)ug/L 20 126 60-140112 1220ND25.2 22.5
m&p-Xylene ug/L 40 128 60-140111 1440ND51.2 44.3
Methyl-tert-butyl ether ug/L 20 115 60-14098 1620ND23.0 19.7
Methylene Chloride ug/L 20 111 60-14089 2120ND23.1 18.6
n-Butylbenzene ug/L 20 115 60-140106 820ND23.0 21.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 24 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
888022MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92140919010
888023
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Propylbenzene ug/L 20 121 60-140112 820ND24.3 22.4
Naphthalene ug/L 20 124 60-140110 1220ND24.8 22.1
o-Xylene ug/L 20 123 60-140105 1520ND24.5 21.0
sec-Butylbenzene ug/L 20 122 60-140112 920ND24.4 22.4
Styrene ug/L 20 129 60-140114 1320ND25.9 22.8
tert-Butylbenzene ug/L 20 124 60-140116 720ND24.8 23.1
Tetrachloroethene ug/L 20 122 60-140113 820ND24.5 22.7
Toluene ug/L 20 120 60-140105 1320ND23.9 21.0
trans-1,2-Dichloroethene ug/L 20 111 60-14099 1220ND22.3 19.7
trans-1,3-Dichloropropene ug/L 20 118 60-140105 1120ND23.6 21.1
Trichloroethene ug/L 20 119 60-140106 1220ND23.9 21.1
Trichlorofluoromethane ug/L 20 121 60-140110 1020ND24.3 22.0
Vinyl chloride ug/L 20 126 60-140109 1520ND25.3 21.7
1,2-Dichloroethane-d4 (S)%98 70-13098
4-Bromofluorobenzene (S)%101 70-130100
Dibromofluoromethane (S)%94 70-13096
Toluene-d8 (S)%97 70-13098
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 25 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/21420
EPA 8260
EPA 8260
8260 MSV 5035A Volatile Organics
Associated Lab Samples:92141280003, 92141280004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:888648
Associated Lab Samples:92141280003, 92141280004
Matrix:Solid
Analyzed
1,1,1,2-Tetrachloroethane ug/kg <5.1 5.1 12/12/12 11:17
1,1,1-Trichloroethane ug/kg <5.1 5.1 12/12/12 11:17
1,1,2,2-Tetrachloroethane ug/kg <5.1 5.1 12/12/12 11:17
1,1,2-Trichloroethane ug/kg <5.1 5.1 12/12/12 11:17
1,1-Dichloroethane ug/kg <5.1 5.1 12/12/12 11:17
1,1-Dichloroethene ug/kg <5.1 5.1 12/12/12 11:17
1,1-Dichloropropene ug/kg <5.1 5.1 12/12/12 11:17
1,2,3-Trichlorobenzene ug/kg <5.1 5.1 12/12/12 11:17
1,2,3-Trichloropropane ug/kg <5.1 5.1 12/12/12 11:17
1,2,4-Trichlorobenzene ug/kg <5.1 5.1 12/12/12 11:17
1,2,4-Trimethylbenzene ug/kg <5.1 5.1 12/12/12 11:17
1,2-Dibromo-3-chloropropane ug/kg <5.1 5.1 12/12/12 11:17
1,2-Dibromoethane (EDB)ug/kg <5.1 5.1 12/12/12 11:17
1,2-Dichlorobenzene ug/kg <5.1 5.1 12/12/12 11:17
1,2-Dichloroethane ug/kg <5.1 5.1 12/12/12 11:17
1,2-Dichloropropane ug/kg <5.1 5.1 12/12/12 11:17
1,3,5-Trimethylbenzene ug/kg <5.1 5.1 12/12/12 11:17
1,3-Dichlorobenzene ug/kg <5.1 5.1 12/12/12 11:17
1,3-Dichloropropane ug/kg <5.1 5.1 12/12/12 11:17
1,4-Dichlorobenzene ug/kg <5.1 5.1 12/12/12 11:17
2,2-Dichloropropane ug/kg <5.1 5.1 12/12/12 11:17
2-Butanone (MEK)ug/kg <102 102 12/12/12 11:17
2-Chlorotoluene ug/kg <5.1 5.1 12/12/12 11:17
2-Hexanone ug/kg <51.1 51.1 12/12/12 11:17
4-Chlorotoluene ug/kg <5.1 5.1 12/12/12 11:17
4-Methyl-2-pentanone (MIBK)ug/kg <51.1 51.1 12/12/12 11:17
Acetone ug/kg <102 102 12/12/12 11:17
Benzene ug/kg <5.1 5.1 12/12/12 11:17
Bromobenzene ug/kg <5.1 5.1 12/12/12 11:17
Bromochloromethane ug/kg <5.1 5.1 12/12/12 11:17
Bromodichloromethane ug/kg <5.1 5.1 12/12/12 11:17
Bromoform ug/kg <5.1 5.1 12/12/12 11:17
Bromomethane ug/kg <10.2 10.2 12/12/12 11:17
Carbon tetrachloride ug/kg <5.1 5.1 12/12/12 11:17
Chlorobenzene ug/kg <5.1 5.1 12/12/12 11:17
Chloroethane ug/kg <10.2 10.2 12/12/12 11:17
Chloroform ug/kg <5.1 5.1 12/12/12 11:17
Chloromethane ug/kg <10.2 10.2 12/12/12 11:17
cis-1,2-Dichloroethene ug/kg <5.1 5.1 12/12/12 11:17
cis-1,3-Dichloropropene ug/kg <5.1 5.1 12/12/12 11:17
Dibromochloromethane ug/kg <5.1 5.1 12/12/12 11:17
Dibromomethane ug/kg <5.1 5.1 12/12/12 11:17
Dichlorodifluoromethane ug/kg <10.2 10.2 12/12/12 11:17
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 26 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:888648
Associated Lab Samples:92141280003, 92141280004
Matrix:Solid
Analyzed
Diisopropyl ether ug/kg <5.1 5.1 12/12/12 11:17
Ethylbenzene ug/kg <5.1 5.1 12/12/12 11:17
Hexachloro-1,3-butadiene ug/kg <5.1 5.1 12/12/12 11:17
Isopropylbenzene (Cumene)ug/kg <5.1 5.1 12/12/12 11:17
m&p-Xylene ug/kg <10.2 10.2 12/12/12 11:17
Methyl-tert-butyl ether ug/kg <5.1 5.1 12/12/12 11:17
Methylene Chloride ug/kg <20.4 20.4 12/12/12 11:17
n-Butylbenzene ug/kg <5.1 5.1 12/12/12 11:17
n-Propylbenzene ug/kg <5.1 5.1 12/12/12 11:17
Naphthalene ug/kg <5.1 5.1 12/12/12 11:17
o-Xylene ug/kg <5.1 5.1 12/12/12 11:17
p-Isopropyltoluene ug/kg <5.1 5.1 12/12/12 11:17
sec-Butylbenzene ug/kg <5.1 5.1 12/12/12 11:17
Styrene ug/kg <5.1 5.1 12/12/12 11:17
tert-Butylbenzene ug/kg <5.1 5.1 12/12/12 11:17
Tetrachloroethene ug/kg <5.1 5.1 12/12/12 11:17
Toluene ug/kg <5.1 5.1 12/12/12 11:17
trans-1,2-Dichloroethene ug/kg <5.1 5.1 12/12/12 11:17
trans-1,3-Dichloropropene ug/kg <5.1 5.1 12/12/12 11:17
Trichloroethene ug/kg <5.1 5.1 12/12/12 11:17
Trichlorofluoromethane ug/kg <5.1 5.1 12/12/12 11:17
Vinyl acetate ug/kg <51.1 51.1 12/12/12 11:17
Vinyl chloride ug/kg <10.2 10.2 12/12/12 11:17
Xylene (Total)ug/kg <10.2 10.2 12/12/12 11:17
1,2-Dichloroethane-d4 (S)%105 70-132 12/12/12 11:17
4-Bromofluorobenzene (S)%99 70-130 12/12/12 11:17
Dibromofluoromethane (S)%104 70-130 12/12/12 11:17
Toluene-d8 (S)%99 70-130 12/12/12 11:17
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
888649LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 59.656.4 106 70-131
1,1,1-Trichloroethane ug/kg 59.556.4 106 70-141
1,1,2,2-Tetrachloroethane ug/kg 57.656.4 102 70-130
1,1,2-Trichloroethane ug/kg 61.956.4 110 70-132
1,1-Dichloroethane ug/kg 57.056.4 101 70-143
1,1-Dichloroethene ug/kg 60.756.4 108 70-137
1,1-Dichloropropene ug/kg 59.456.4 105 70-135
1,2,3-Trichlorobenzene ug/kg 60.656.4 107 69-153
1,2,3-Trichloropropane ug/kg 59.656.4 106 70-130
1,2,4-Trichlorobenzene ug/kg 62.656.4 111 55-171
1,2,4-Trimethylbenzene ug/kg 59.356.4 105 70-149
1,2-Dibromo-3-chloropropane ug/kg 66.256.4 117 68-141
1,2-Dibromoethane (EDB)ug/kg 61.856.4 110 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 27 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
888649LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichlorobenzene ug/kg 59.256.4 105 70-140
1,2-Dichloroethane ug/kg 57.056.4 101 70-137
1,2-Dichloropropane ug/kg 58.956.4 104 70-133
1,3,5-Trimethylbenzene ug/kg 59.656.4 106 70-143
1,3-Dichlorobenzene ug/kg 59.556.4 105 70-144
1,3-Dichloropropane ug/kg 60.256.4 107 70-132
1,4-Dichlorobenzene ug/kg 59.556.4 105 70-142
2,2-Dichloropropane ug/kg 58.056.4 103 68-152
2-Butanone (MEK)ug/kg 120113 106 70-149
2-Chlorotoluene ug/kg 59.056.4 105 70-141
2-Hexanone ug/kg 120113 106 70-149
4-Chlorotoluene ug/kg 59.456.4 105 70-149
4-Methyl-2-pentanone (MIBK)ug/kg 129113 114 70-153
Acetone ug/kg 133113 118 70-157
Benzene ug/kg 59.456.4 105 70-130
Bromobenzene ug/kg 58.156.4 103 70-141
Bromochloromethane ug/kg 57.956.4 103 70-149
Bromodichloromethane ug/kg 61.356.4 109 70-130
Bromoform ug/kg 60.556.4 107 70-131
Bromomethane ug/kg 72.556.4 128 64-136
Carbon tetrachloride ug/kg 59.456.4 105 70-154
Chlorobenzene ug/kg 59.956.4 106 70-135
Chloroethane ug/kg 75.456.4 134 68-151
Chloroform ug/kg 59.956.4 106 70-130
Chloromethane ug/kg 76.0 L056.4 135 70-132
cis-1,2-Dichloroethene ug/kg 57.656.4 102 70-140
cis-1,3-Dichloropropene ug/kg 61.856.4 109 70-137
Dibromochloromethane ug/kg 63.456.4 112 70-130
Dibromomethane ug/kg 59.056.4 105 70-136
Dichlorodifluoromethane ug/kg 71.456.4 126 36-148
Diisopropyl ether ug/kg 58.156.4 103 70-139
Ethylbenzene ug/kg 60.356.4 107 70-137
Hexachloro-1,3-butadiene ug/kg 64.456.4 114 70-145
Isopropylbenzene (Cumene)ug/kg 58.756.4 104 70-141
m&p-Xylene ug/kg 122113 108 70-140
Methyl-tert-butyl ether ug/kg 61.756.4 109 45-150
Methylene Chloride ug/kg 56.956.4 101 70-133
n-Butylbenzene ug/kg 60.856.4 108 65-155
n-Propylbenzene ug/kg 59.456.4 105 70-148
Naphthalene ug/kg 63.956.4 113 70-148
o-Xylene ug/kg 59.056.4 105 70-141
p-Isopropyltoluene ug/kg 62.556.4 111 70-148
sec-Butylbenzene ug/kg 60.856.4 108 70-145
Styrene ug/kg 61.056.4 108 70-138
tert-Butylbenzene ug/kg 59.056.4 105 70-143
Tetrachloroethene ug/kg 60.756.4 107 70-140
Toluene ug/kg 57.156.4 101 70-130
trans-1,2-Dichloroethene ug/kg 57.656.4 102 70-136
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 28 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
888649LABORATORY CONTROL SAMPLE:
LCSSpike
trans-1,3-Dichloropropene ug/kg 62.956.4 112 70-138
Trichloroethene ug/kg 60.556.4 107 70-132
Trichlorofluoromethane ug/kg 61.756.4 109 69-134
Vinyl acetate ug/kg 156113 138 24-161
Vinyl chloride ug/kg 61.456.4 109 55-140
Xylene (Total)ug/kg 181169 107 70-141
1,2-Dichloroethane-d4 (S)%101 70-132
4-Bromofluorobenzene (S)%102 70-130
Dibromofluoromethane (S)%102 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
888650MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92141204007
888651
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1-Dichloroethene ug/kg E,M0,R142.6 -10542 49-18040091 15346.1ND 3500 26400
Benzene ug/kg 42.6 97 50-166110 2046.1ND 41.3 50.7
Chlorobenzene ug/kg 42.6 101 43-169120 2546.1ND 43.1 55.2
Toluene ug/kg E,M0,R142.6 107 52-1634177 18346.140.3 85.9 1960
Trichloroethene ug/kg E,M0,R142.6 741 49-16715272 18346.1ND 316 7030
1,2-Dichloroethane-d4 (S)%99 70-132117
4-Bromofluorobenzene (S)%102 70-13095
Dibromofluoromethane (S)%S05770-1304
Toluene-d8 (S)%96 70-130104
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 29 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/21465
EPA 8260
EPA 8260
8260 MSV 5035A Volatile Organics
Associated Lab Samples:92141280002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:891579
Associated Lab Samples:92141280002
Matrix:Solid
Analyzed
1,1,1,2-Tetrachloroethane ug/kg <6.5 6.5 12/16/12 13:11
1,1,1-Trichloroethane ug/kg <6.5 6.5 12/16/12 13:11
1,1,2,2-Tetrachloroethane ug/kg <6.5 6.5 12/16/12 13:11
1,1,2-Trichloroethane ug/kg <6.5 6.5 12/16/12 13:11
1,1-Dichloroethane ug/kg <6.5 6.5 12/16/12 13:11
1,1-Dichloroethene ug/kg <6.5 6.5 12/16/12 13:11
1,1-Dichloropropene ug/kg <6.5 6.5 12/16/12 13:11
1,2,3-Trichlorobenzene ug/kg <6.5 6.5 12/16/12 13:11
1,2,3-Trichloropropane ug/kg <6.5 6.5 12/16/12 13:11
1,2,4-Trichlorobenzene ug/kg <6.5 6.5 12/16/12 13:11
1,2,4-Trimethylbenzene ug/kg <6.5 6.5 12/16/12 13:11
1,2-Dibromo-3-chloropropane ug/kg <6.5 6.5 12/16/12 13:11
1,2-Dibromoethane (EDB)ug/kg <6.5 6.5 12/16/12 13:11
1,2-Dichlorobenzene ug/kg <6.5 6.5 12/16/12 13:11
1,2-Dichloroethane ug/kg <6.5 6.5 12/16/12 13:11
1,2-Dichloropropane ug/kg <6.5 6.5 12/16/12 13:11
1,3,5-Trimethylbenzene ug/kg <6.5 6.5 12/16/12 13:11
1,3-Dichlorobenzene ug/kg <6.5 6.5 12/16/12 13:11
1,3-Dichloropropane ug/kg <6.5 6.5 12/16/12 13:11
1,4-Dichlorobenzene ug/kg <6.5 6.5 12/16/12 13:11
2,2-Dichloropropane ug/kg <6.5 6.5 12/16/12 13:11
2-Butanone (MEK)ug/kg <130 130 12/16/12 13:11
2-Chlorotoluene ug/kg <6.5 6.5 12/16/12 13:11
2-Hexanone ug/kg <64.8 64.8 12/16/12 13:11
4-Chlorotoluene ug/kg <6.5 6.5 12/16/12 13:11
4-Methyl-2-pentanone (MIBK)ug/kg <64.8 64.8 12/16/12 13:11
Acetone ug/kg <130 130 12/16/12 13:11
Benzene ug/kg <6.5 6.5 12/16/12 13:11
Bromobenzene ug/kg <6.5 6.5 12/16/12 13:11
Bromochloromethane ug/kg <6.5 6.5 12/16/12 13:11
Bromodichloromethane ug/kg <6.5 6.5 12/16/12 13:11
Bromoform ug/kg <6.5 6.5 12/16/12 13:11
Bromomethane ug/kg <13.0 13.0 12/16/12 13:11
Carbon tetrachloride ug/kg <6.5 6.5 12/16/12 13:11
Chlorobenzene ug/kg <6.5 6.5 12/16/12 13:11
Chloroethane ug/kg <13.0 13.0 12/16/12 13:11
Chloroform ug/kg <6.5 6.5 12/16/12 13:11
Chloromethane ug/kg <13.0 13.0 12/16/12 13:11
cis-1,2-Dichloroethene ug/kg <6.5 6.5 12/16/12 13:11
cis-1,3-Dichloropropene ug/kg <6.5 6.5 12/16/12 13:11
Dibromochloromethane ug/kg <6.5 6.5 12/16/12 13:11
Dibromomethane ug/kg <6.5 6.5 12/16/12 13:11
Dichlorodifluoromethane ug/kg <13.0 13.0 12/16/12 13:11
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 30 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:891579
Associated Lab Samples:92141280002
Matrix:Solid
Analyzed
Diisopropyl ether ug/kg <6.5 6.5 12/16/12 13:11
Ethylbenzene ug/kg <6.5 6.5 12/16/12 13:11
Hexachloro-1,3-butadiene ug/kg <6.5 6.5 12/16/12 13:11
Isopropylbenzene (Cumene)ug/kg <6.5 6.5 12/16/12 13:11
m&p-Xylene ug/kg <13.0 13.0 12/16/12 13:11
Methyl-tert-butyl ether ug/kg <6.5 6.5 12/16/12 13:11
Methylene Chloride ug/kg <25.9 25.9 12/16/12 13:11
n-Butylbenzene ug/kg <6.5 6.5 12/16/12 13:11
n-Propylbenzene ug/kg <6.5 6.5 12/16/12 13:11
Naphthalene ug/kg <6.5 6.5 12/16/12 13:11
o-Xylene ug/kg <6.5 6.5 12/16/12 13:11
p-Isopropyltoluene ug/kg <6.5 6.5 12/16/12 13:11
sec-Butylbenzene ug/kg <6.5 6.5 12/16/12 13:11
Styrene ug/kg <6.5 6.5 12/16/12 13:11
tert-Butylbenzene ug/kg <6.5 6.5 12/16/12 13:11
Tetrachloroethene ug/kg <6.5 6.5 12/16/12 13:11
Toluene ug/kg <6.5 6.5 12/16/12 13:11
trans-1,2-Dichloroethene ug/kg <6.5 6.5 12/16/12 13:11
trans-1,3-Dichloropropene ug/kg <6.5 6.5 12/16/12 13:11
Trichloroethene ug/kg <6.5 6.5 12/16/12 13:11
Trichlorofluoromethane ug/kg <6.5 6.5 12/16/12 13:11
Vinyl acetate ug/kg <64.8 64.8 12/16/12 13:11
Vinyl chloride ug/kg <13.0 13.0 12/16/12 13:11
Xylene (Total)ug/kg <13.0 13.0 12/16/12 13:11
1,2-Dichloroethane-d4 (S)%87 70-132 12/16/12 13:11
4-Bromofluorobenzene (S)%100 70-130 12/16/12 13:11
Dibromofluoromethane (S)%97 70-130 12/16/12 13:11
Toluene-d8 (S)%106 70-130 12/16/12 13:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
891580LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 43.346.9 92 70-131
1,1,1-Trichloroethane ug/kg 46.146.9 98 70-141
1,1,2,2-Tetrachloroethane ug/kg 45.346.9 97 70-130
1,1,2-Trichloroethane ug/kg 48.646.9 104 70-132
1,1-Dichloroethane ug/kg 41.446.9 88 70-143
1,1-Dichloroethene ug/kg 38.746.9 83 70-137
1,1-Dichloropropene ug/kg 44.746.9 95 70-135
1,2,3-Trichlorobenzene ug/kg 47.046.9 100 69-153
1,2,3-Trichloropropane ug/kg 45.846.9 98 70-130
1,2,4-Trichlorobenzene ug/kg 44.646.9 95 55-171
1,2,4-Trimethylbenzene ug/kg 43.146.9 92 70-149
1,2-Dibromo-3-chloropropane ug/kg 48.946.9 104 68-141
1,2-Dibromoethane (EDB)ug/kg 48.646.9 104 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 31 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
891580LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichlorobenzene ug/kg 46.946.9 100 70-140
1,2-Dichloroethane ug/kg 45.546.9 97 70-137
1,2-Dichloropropane ug/kg 47.346.9 101 70-133
1,3,5-Trimethylbenzene ug/kg 44.346.9 94 70-143
1,3-Dichlorobenzene ug/kg 44.346.9 94 70-144
1,3-Dichloropropane ug/kg 48.646.9 104 70-132
1,4-Dichlorobenzene ug/kg 44.746.9 95 70-142
2,2-Dichloropropane ug/kg 42.646.9 91 68-152
2-Butanone (MEK)ug/kg <93.893.8 91 70-149
2-Chlorotoluene ug/kg 46.646.9 99 70-141
2-Hexanone ug/kg 90.093.8 96 70-149
4-Chlorotoluene ug/kg 43.846.9 93 70-149
4-Methyl-2-pentanone (MIBK)ug/kg 90.493.8 96 70-153
Acetone ug/kg <93.893.8 91 70-157
Benzene ug/kg 45.346.9 97 70-130
Bromobenzene ug/kg 46.446.9 99 70-141
Bromochloromethane ug/kg 47.346.9 101 70-149
Bromodichloromethane ug/kg 47.046.9 100 70-130
Bromoform ug/kg 48.946.9 104 70-131
Bromomethane ug/kg 49.046.9 104 64-136
Carbon tetrachloride ug/kg 44.146.9 94 70-154
Chlorobenzene ug/kg 45.746.9 97 70-135
Chloroethane ug/kg 52.046.9 111 68-151
Chloroform ug/kg 41.746.9 89 70-130
Chloromethane ug/kg 55.846.9 119 70-132
cis-1,2-Dichloroethene ug/kg 41.246.9 88 70-140
cis-1,3-Dichloropropene ug/kg 46.246.9 98 70-137
Dibromochloromethane ug/kg 49.746.9 106 70-130
Dibromomethane ug/kg 45.446.9 97 70-136
Dichlorodifluoromethane ug/kg 53.046.9 113 36-148
Diisopropyl ether ug/kg 48.346.9 103 70-139
Ethylbenzene ug/kg 45.446.9 97 70-137
Hexachloro-1,3-butadiene ug/kg 44.246.9 94 70-145
Isopropylbenzene (Cumene)ug/kg 43.146.9 92 70-141
m&p-Xylene ug/kg 88.693.8 94 70-140
Methyl-tert-butyl ether ug/kg 50.946.9 109 45-150
Methylene Chloride ug/kg 40.646.9 87 70-133
n-Butylbenzene ug/kg 44.046.9 94 65-155
n-Propylbenzene ug/kg 42.546.9 91 70-148
Naphthalene ug/kg 48.746.9 104 70-148
o-Xylene ug/kg 43.946.9 94 70-141
p-Isopropyltoluene ug/kg 45.246.9 96 70-148
sec-Butylbenzene ug/kg 44.046.9 94 70-145
Styrene ug/kg 44.846.9 95 70-138
tert-Butylbenzene ug/kg 44.246.9 94 70-143
Tetrachloroethene ug/kg 42.946.9 92 70-140
Toluene ug/kg 43.846.9 93 70-130
trans-1,2-Dichloroethene ug/kg 40.146.9 85 70-136
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 32 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
891580LABORATORY CONTROL SAMPLE:
LCSSpike
trans-1,3-Dichloropropene ug/kg 47.046.9 100 70-138
Trichloroethene ug/kg 44.146.9 94 70-132
Trichlorofluoromethane ug/kg 40.046.9 85 69-134
Vinyl acetate ug/kg 86.393.8 92 24-161
Vinyl chloride ug/kg 39.546.9 84 55-140
Xylene (Total)ug/kg 133141 94 70-141
1,2-Dichloroethane-d4 (S)%93 70-132
4-Bromofluorobenzene (S)%96 70-130
Dibromofluoromethane (S)%95 70-130
Toluene-d8 (S)%94 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 33 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/20046
EPA 625
EPA 625
625 MSS
Associated Lab Samples:92141280001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:887597
Associated Lab Samples:92141280001
Matrix:Water
Analyzed
2-Methylnaphthalene ug/L <5.0 5.0 12/12/12 01:17
Acenaphthene ug/L <5.0 5.0 12/12/12 01:17
Acenaphthylene ug/L <5.0 5.0 12/12/12 01:17
Anthracene ug/L <5.0 5.0 12/12/12 01:17
Benzo(a)anthracene ug/L <5.0 5.0 12/12/12 01:17
Benzo(a)pyrene ug/L <5.0 5.0 12/12/12 01:17
Benzo(b)fluoranthene ug/L <5.0 5.0 12/12/12 01:17
Benzo(g,h,i)perylene ug/L <5.0 5.0 12/12/12 01:17
Benzo(k)fluoranthene ug/L <5.0 5.0 12/12/12 01:17
Chrysene ug/L <5.0 5.0 12/12/12 01:17
Dibenz(a,h)anthracene ug/L <5.0 5.0 12/12/12 01:17
Fluoranthene ug/L <5.0 5.0 12/12/12 01:17
Fluorene ug/L <5.0 5.0 12/12/12 01:17
Indeno(1,2,3-cd)pyrene ug/L <5.0 5.0 12/12/12 01:17
Naphthalene ug/L <5.0 5.0 12/12/12 01:17
Phenanthrene ug/L <5.0 5.0 12/12/12 01:17
Pyrene ug/L <5.0 5.0 12/12/12 01:17
2,4,6-Tribromophenol (S)%63 10-137 12/12/12 01:17
2-Fluorobiphenyl (S)%68 15-120 12/12/12 01:17
2-Fluorophenol (S)%37 10-120 12/12/12 01:17
Nitrobenzene-d5 (S)%71 10-120 12/12/12 01:17
Phenol-d6 (S)%24 10-120 12/12/12 01:17
Terphenyl-d14 (S)%89 11-131 12/12/12 01:17
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
887598LABORATORY CONTROL SAMPLE:
LCSSpike
2-Methylnaphthalene ug/L 38.050 76 25-150
Acenaphthene ug/L 40.950 82 47-145
Acenaphthylene ug/L 38.950 78 33-145
Anthracene ug/L 38.750 77 1-166
Benzo(a)anthracene ug/L 40.250 80 33-143
Benzo(a)pyrene ug/L 41.150 82 17-163
Benzo(b)fluoranthene ug/L 40.550 81 24-159
Benzo(g,h,i)perylene ug/L 36.150 72 1-219
Benzo(k)fluoranthene ug/L 41.350 83 11-162
Chrysene ug/L 37.650 75 17-168
Dibenz(a,h)anthracene ug/L 38.150 76 1-227
Fluoranthene ug/L 38.550 77 26-137
Fluorene ug/L 40.550 81 59-121
Indeno(1,2,3-cd)pyrene ug/L 37.550 75 1-171
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 34 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
887598LABORATORY CONTROL SAMPLE:
LCSSpike
Naphthalene ug/L 34.850 70 21-133
Phenanthrene ug/L 37.350 75 54-120
Pyrene ug/L 40.550 81 52-115
2,4,6-Tribromophenol (S)%72 10-137
2-Fluorobiphenyl (S)%76 15-120
2-Fluorophenol (S)%41 10-120
Nitrobenzene-d5 (S)%80 10-120
Phenol-d6 (S)%28 10-120
Terphenyl-d14 (S)%91 11-131
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
887599MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92141283001
887600
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
2-Methylnaphthalene ug/L 100 83 25-15051 48100ND83.2 50.9
Acenaphthene ug/L 100 86 47-14553 48100ND85.5 52.6
Acenaphthylene ug/L 100 82 33-14551 47100ND81.9 50.9
Anthracene ug/L 100 81 1-16672 12100ND80.9 71.9
Benzo(a)anthracene ug/L 100 73 33-14370 4100ND72.9 70.1
Benzo(a)pyrene ug/L 100 80 17-16376 5100ND80.0 76.5
Benzo(b)fluoranthene ug/L 100 72 24-15967 6100ND71.6 67.4
Benzo(g,h,i)perylene ug/L 100 74 1-21968 8100ND73.7 68.1
Benzo(k)fluoranthene ug/L 100 81 11-16278 4100ND81.5 78.0
Chrysene ug/L 100 76 17-16872 6100ND76.0 71.6
Dibenz(a,h)anthracene ug/L 100 77 1-22770 9100ND76.9 70.3
Fluoranthene ug/L 100 76 26-13773 4100ND76.0 73.3
Fluorene ug/L 100 85 59-12161 33100ND84.6 60.6
Indeno(1,2,3-cd)pyrene ug/L 100 76 1-17170 9100ND76.1 69.6
Naphthalene ug/L 100 76 21-13347 48100ND75.7 46.6
Phenanthrene ug/L 100 74 54-12067 10100ND74.3 67.1
Pyrene ug/L 100 79 52-11578 1100ND78.8 77.8
2,4,6-Tribromophenol (S)%71 10-13762
2-Fluorobiphenyl (S)%76 15-12043
2-Fluorophenol (S)%51 10-12034
Nitrobenzene-d5 (S)%79 10-12046
Phenol-d6 (S)%39 10-12030
Terphenyl-d14 (S)%83 11-13178
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 35 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/20058
EPA 3546
EPA 8270
8270 Solid MSSV Microwave PAH
Associated Lab Samples:92141280002, 92141280003, 92141280004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:888149
Associated Lab Samples:92141280002, 92141280003, 92141280004
Matrix:Solid
Analyzed
1-Methylnaphthalene ug/kg <330 330 12/12/12 15:35
2-Methylnaphthalene ug/kg <330 330 12/12/12 15:35
Acenaphthene ug/kg <330 330 12/12/12 15:35
Acenaphthylene ug/kg <330 330 12/12/12 15:35
Anthracene ug/kg <330 330 12/12/12 15:35
Benzo(a)anthracene ug/kg <330 330 12/12/12 15:35
Benzo(a)pyrene ug/kg <330 330 12/12/12 15:35
Benzo(b)fluoranthene ug/kg <330 330 12/12/12 15:35
Benzo(g,h,i)perylene ug/kg <330 330 12/12/12 15:35
Benzo(k)fluoranthene ug/kg <330 330 12/12/12 15:35
Chrysene ug/kg <330 330 12/12/12 15:35
Dibenz(a,h)anthracene ug/kg <330 330 12/12/12 15:35
Fluoranthene ug/kg <330 330 12/12/12 15:35
Fluorene ug/kg <330 330 12/12/12 15:35
Indeno(1,2,3-cd)pyrene ug/kg <330 330 12/12/12 15:35
Naphthalene ug/kg <330 330 12/12/12 15:35
Phenanthrene ug/kg <330 330 12/12/12 15:35
Pyrene ug/kg <330 330 12/12/12 15:35
2-Fluorobiphenyl (S)%82 30-110 12/12/12 15:35
Nitrobenzene-d5 (S)%65 23-110 12/12/12 15:35
Terphenyl-d14 (S)%87 28-110 12/12/12 15:35
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
888150LABORATORY CONTROL SAMPLE:
LCSSpike
1-Methylnaphthalene ug/kg 14801670 89 45-105
2-Methylnaphthalene ug/kg 14701670 88 39-112
Acenaphthene ug/kg 14501670 87 38-117
Acenaphthylene ug/kg 14301670 86 46-107
Anthracene ug/kg 14401670 87 50-110
Benzo(a)anthracene ug/kg 14701670 88 47-116
Benzo(a)pyrene ug/kg 14701670 88 47-106
Benzo(b)fluoranthene ug/kg 12901670 78 47-109
Benzo(g,h,i)perylene ug/kg 16901670 101 39-115
Benzo(k)fluoranthene ug/kg 13901670 84 45-117
Chrysene ug/kg 14301670 86 49-110
Dibenz(a,h)anthracene ug/kg 16001670 96 43-116
Fluoranthene ug/kg 17301670 104 50-114
Fluorene ug/kg 14701670 88 46-114
Indeno(1,2,3-cd)pyrene ug/kg 16201670 97 42-115
Naphthalene ug/kg 13501670 81 41-110
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 36 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
888150LABORATORY CONTROL SAMPLE:
LCSSpike
Phenanthrene ug/kg 13901670 83 50-110
Pyrene ug/kg 14001670 84 45-114
2-Fluorobiphenyl (S)%83 30-110
Nitrobenzene-d5 (S)%67 23-110
Terphenyl-d14 (S)%82 28-110
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 37 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
PMST/5191
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:92141280002, 92141280003
Parameter Units
Dup
Result QualifiersRPDResult
92141282002
887512SAMPLE DUPLICATE:
Percent Moisture %37.3 338.5
Parameter Units
Dup
Result QualifiersRPDResult
92141280003
887513SAMPLE DUPLICATE:
Percent Moisture %9.9 59.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 38 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
PMST/5192
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:92141280004
Parameter Units
Dup
Result QualifiersRPDResult
92141241001
888507SAMPLE DUPLICATE:
Percent Moisture %22.3 022.3
Parameter Units
Dup
Result QualifiersRPDResult
92141480003
888508SAMPLE DUPLICATE:
Percent Moisture %13.1 113.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 39 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analyte concentration exceeded the calibration range. The reported result is estimated.E
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
RPD value was outside control limits.R1
Surrogate recovery outside laboratory control limits.S0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 40 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92141280
Sky House 1351-12-147
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92141280001 OEXT/20046 MSSV/7101MW-102 EPA 625 EPA 625
92141280002 OEXT/20058 MSSV/7104B-101 (5-7.5')EPA 3546 EPA 8270
92141280003 OEXT/20058 MSSV/7104B-101 (12.5-15')EPA 3546 EPA 8270
92141280004 OEXT/20058 MSSV/7104B-102 (12.5-20')EPA 3546 EPA 8270
92141280001 MSV/21405MW-102 SM 6200B
92141280002 MSV/21465B-101 (5-7.5')EPA 8260
92141280003 MSV/21420B-101 (12.5-15')EPA 8260
92141280004 MSV/21420B-102 (12.5-20')EPA 8260
92141280002 PMST/5191B-101 (5-7.5')ASTM D2974-87
92141280003 PMST/5191B-101 (12.5-15')ASTM D2974-87
92141280004 PMST/5192B-102 (12.5-20')ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/20/2012 10:12 AM Page 41 of 41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]