Loading...
HomeMy WebLinkAbout20051_Travis Knits_Sub Slab-Indoor Air Assmt_2015.12.16 Via Email December 16, 2015 NC DEQ 610 East Center Avenue, Suite 301 Mooresville, NC 28115 Attn: Mr. George Adams Subject: Sub-Slab/Indoor Air Assessment Former Knitronics Facility Cherryville, North Carolina H&H Project No. MOH-001 Dear George: 1.0 Introduction This revised Sub-Slab/Indoor Air Assessment report has been prepared by Hart & Hickman, P.C. (H&H) on behalf of Mohican Mills, Inc. (Mohican) for the former Knitronics facility located at 1515 West Academy Street in Cherryville, North Carolina (Figure 1). The subject property is owned by Mohican and contains a 197,000 square feet warehouse building on approximately 12.13 acres. A separate wooded parcel, also owned by Mohican, contains 4.64 acres which abuts the 12.13 acre property on the east side. The warehouse building was built in 1971 for Knitronics Knitting Mills, Inc. (“Knitronics”) and served as a former textile mill for Knitronics and others. It is currently vacant in the eastern portion and used for warehouse space in the western portion. As described below, Hart & Hickman, PC (H&H) has completed sub-slab vapor (SSV) and indoor air assessment activities to evaluate vapor intrusion at the former Knitronics facility. The assessment included in the collection and analysis of five SSV sampling points, six indoor air samples, and one background air sample. The air sampling activities were completed in general accordance with the North Carolina Department of Environmental Quality (DEQ) Vapor Intrusion Guidance dated April 2014 (VI Guidance). Mr. George Adams December 16, 2015 Page 2 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\Air Assessment\SS_IA_Reportrevised.docx Based on the August 20, 2015 report, soil and groundwater samples were collected at the site in July 2015 by the current tenant as part of its due diligence for a potential purchase to assess for potential impacts in the eastern portion of the developed property. The results of the soil analyses indicated that tetrachloroethene (PCE) was detected above the DEQ Soil-to-Groundwater Maximum Soil Contaminant Concentration (MSCC). Additionally, cis,1,2-dichloroethene (1,2- DCE), PCE, trichloroethene (TCE), chromium, and lead were detected in groundwater above DEQ standards. PCE was detected in groundwater at concentrations up to 110,000 µg/l. These chlorinated volatile organic compound (VOC) impacts were detected near the eastern portion of the facility which is currently vacant. The metal concentrations detected in groundwater were low concentrations and may be naturally occurring and/or an artifact of the sampling methods used. 2.0 Air Assessment Activities 2.1 Sub-Slab Sampling Methods On November 5, 2015, H&H collected five SSV samples (SS-1 through SS-5) from the locations shown on Figure 2. The SSV samples were collected from permanent Vapor Pin™ sample points installed throughout the facility in areas of potential concern. For each SSV sample point, an initial 1 ½-inch diameter hole was drilled into the concrete slab to a depth of approximately 1 ¾ inches using a hammer drill. Then, a drill guide was placed in the hole and a hammer drill, equipped with a 5/8-inch diameter bit, was utilized to advance the borehole through the concrete slab and approximately 6 inches into the underlying soil to form a void and penetrate any existing moisture barrier plastic sheeting. Following concrete borehole advancement, loose cuttings were removed using a bottle brush and HEPA vacuum. Then, a Vapor Pin™ assembly (brass sampling point and silicone sleeve) was placed and seated in the drilled hole by tapping the Vapor Pin™ assembly using an installation/extraction tool and a “dead blow” hammer. The sampling points were installed as flush mounted points and a protective cap was placed on the Vapor Pin™ sampling barb fitting. Each SSV monitoring point was covered using a secure stainless steel cover. Mr. George Adams December 16, 2015 Page 3 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\Air Assessment\SS_IA_Reportrevised.docx Following installation and prior to collection of the vapor samples, a leak check of each SSV monitoring point was conducted. The leak check was performed by first placing a shroud over each sample point, filling the shroud with helium gas, and using a helium gas detector to verify that the shroud was saturated with helium gas. Then, each sample point was purged using a syringe and a three-way valve to collect purged vapor into a Tedlar® bag. The purged vapor was subsequently analyzed using the helium gas detector to ensure that helium concentrations were less than 20% of the helium concentrations in the shroud. Following successful leak checks, the SSV samples were collected using one-liter stainless steel Summa canisters. The Summa canisters were allowed to fill slowly using an airflow regulator over a period of approximately one hour at each location. Vacuum readings were recorded prior to and following the sampling period to ensure adequate sample volume collected. H&H collected measurements of ambient temperature at the beginning, middle, and end of the sample collection period in the general areas of the SSV samples. In addition, outside weather was noted during the sampling period. Weather conditions consisted of cloudy skies and temperatures in the 70s °F. Following sample collection, the Summa canisters were properly labeled, placed into laboratory-supplied shipping containers, and shipped under standard chain-of- custody protocol to Con-Test Analytical Laboratory in East Longmeadow, MA for analysis of the select VOCs cis/trans-1,2-DCE, PCE, TCE, 1,1-DCE, vinyl chloride, and 1,2-dichloroethane (1,2- DCA) by EPA Method TO-15. This compound list includes chlorinated VOCs and daughter products that may be present based on the results of prior soil and groundwater sampling at the site. 2.2 Indoor Air Sampling Methods On November 5, 2015, H&H collected five indoor air samples (IA-1 through IA-5) in the site building coincident with the SSV sampling points. In addition, one exterior background sample (labeled OA-1) was collected south of the building, which was upwind of the facility during the indoor air sampling event. An additional sample (IAS-6) was collected from an active office located on the western end of the building on November 20, 2015. The samples were collected Mr. George Adams December 16, 2015 Page 4 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\Air Assessment\SS_IA_Reportrevised.docx under normal/current operating conditions. Approximately two employees work in the office and warehouse space in the western portion of the building. The approximate locations of the indoor air samples are depicted on Figure 2. The indoor and background air samples were collected using laboratory-supplied, six-liter stainless steel Summa canisters which were connected to in-line flow controllers with a built-in vacuum gauge (also laboratory-supplied). The flow controller was set by the laboratory to restrict flow to approximately 12.5 ml/min such that the samples were collected over an 8-hr period with the exception of IAS-6. Due to the warehouse closing early when IAS-6 was collected, this sample period was 6.5 hrs. A 3 ft long laboratory-supplied sampling cane was connected to the flow controller so that the sample intake point was positioned approximately 5 ft above grade (typical breathing zone height) when the sample canister was set on its base. Prior to and after the indoor and background air samples were collected, vacuum in the canisters was measured using a laboratory-supplied vacuum gauge and recorded by sampling personnel. The starting and ending vacuums in each canister were recorded on the sample chain-of-custody. At the end of the sample period, the in-door sir sample canister’s valve was closed to stop sample collection. The sample canisters were then labeled and shipped under standard chain-of-custody procedures to Con-Test Analytical Laboratory for analysis of the select VOCs cis/trans-1,2-DCE, PCE, TCE, 1,1-DCE, vinyl chloride, and 1,2-DCA by EPA Method TO-15. As part of the indoor air sampling activities, H&H conducted a survey of stored materials and products in the warehouse building, and periodically noted outside weather conditions. Rolls of synthetic fiber were stored in the central and western portions of the warehouse building. H&H did not identify materials or products in the office building which would likely affect chlorinated VOC indoor air sample results. During the November 5, 2015 indoor air sampling event, weather conditions consisted of cloudy skies and temperatures in the 70s °F, and during the November 20, 2105 indoor air sampling event, weather conditions consisted of clear skies and temperatures in the low 50s °F to high 60s °F. The warehouse portion of the building does not have an operable Mr. George Adams December 16, 2015 Page 5 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\Air Assessment\SS_IA_Reportrevised.docx heating, ventilating, and air conditioning (HVAC) system. Small floor/area fans are sometimes used. Indoor air sampling forms are included in Appendix B. 2.3 Quality Control For quality assurance purposes, one duplicate sample was collected from SSV sample point SS-1 and one duplicate sample was collected from an indoor air sampling location IA-2. The duplicate samples were collected to allow determination of analytical repeatability. Additionally, H&H submitted two trip blank samples (Trip Blank-1 and Trip Blank-2) for laboratory analysis on November 5, 2015. The duplicate and trip blank samples were analyzed for the same select VOCs as the SSV and indoor air samples. 3.0 Air Assessment Results 3.1 Sub-Slab Vapor Sampling Results Laboratory analytical results indicated that two of the six SSV samples contained compound concentrations above the NC DEQ Inactive Hazardous Sites Branch (IHSB) Non-Residential Sub- Slab and Exterior Soil Gas Screening Levels (SGSLs). PCE was detected in vapor samples SS-1 and SS-2, and TCE was detected in SS-1 above the IHSB Non-Residential SGSLs. The maximum SSV PCE concentration detected was 27,000,000 µg/m3 which exceeds the Non-Residential SGSL of 3,500 µg/m3. No other VOCs exceeded Non-Residential SGSLs in these samples, and no VOCs were detected above the Non-Residential SGSLs in SSV samples SS-3 through SS-5. A summary of the SSV detections is provided in Table 1. The laboratory analytical report is included in Appendix A. Mr. George Adams December 16, 2015 Page 6 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\Air Assessment\SS_IA_Reportrevised.docx 3.2 Indoor Air and Outdoor Air Sampling Results The indoor air analytical results indicated that PCE was detected in four (IA-1 through IA-4) of six sample locations above the IHSB Non-Residential Indoor Air and Crawlspace Screening Concentration (IASL) for PCE of 35.0 µg/m3. The maximum indoor air PCE concentration was 610 µg/m3. These samples were collected in the central and eastern portions of the building. No other VOCs exceeded IASLs in these samples, and no VOCs were detected above the IASLs in air samples IA-5 and IAS-6 which were collected in the western portion of the building and in the active office. Outdoor background air sample OA-1, collected in an upwind location, contained a low concentration PCE. Considering the predominant wind direction the day of the sampling event, it appears that this compound is present in ambient outdoor air near the facility. A summary of the indoor and outdoor air detections is provided in Table 2 and Figure 2. The laboratory analytical reports are included in Appendix A. 3.3 Calculated Cumulative Risks The default DEQ IHSB IASLs are conservative and are based upon a Lifetime Incremental Cancer Risk (LICR) of 1 x 10-5 for potential carcinogenic effects and a Hazard Quotient (HQ) of 0.2 for potential non-carcinogenic effects. Vapor intrusion mitigation for occupied industrial/commercial structures are not typically considered unless the LICR exceeds 1 x 10-4 for potential carcinogenic effects and/or a HQ of 1 for potential non-carcinogenic effects. Therefore, to further evaluate the risks posed by the detected indoor air compounds, H&H calculated cumulative potential carcinogenic and non-carcinogenic risks for each of the sample locations. The calculations are summarized in Tables 3 and 4. Please note that the assumptions used in the calculations are based upon standard, conservative, default exposure scenarios which include a person working at the site 250 days per year for 25 years and 8 hours per day. Mr. George Adams December 16, 2015 Page 7 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\Air Assessment\SS_IA_Reportrevised.docx As indicated in Table 3, none of the calculated LICRs for the November 2015 sampling event exceeded a 1 x 10-4 risk level, and the LICRs were equal to or less than 1.34 x 10-5. As shown in Table 4, the calculated non-carcinogenic HQs were greater than 1 in sample locations IA-1, IA-2, and IA-3 and less than 1 in sample locations IA-4, IA-5, and IAS-6. Air samples IA-1, IA-2, and IA-3 were collected in the central and eastern portions of the building, which is currently mostly vacant. There is some material storage in the central portion of the warehouse near IA-3. The areas near IA-1 and IA-2 are not occupied. 3.4 Quality Control Results The quality control sample results indicate good quality datasets were collected. Duplicate and trip blank sample results are summarized in Tables 1 and 2. The duplicate sample results were similar to the original samples. No constituents were detected in the trip blank samples at concentrations above the laboratory reporting limits. 4.0 Summary and Recommendations H&H completed subslab vapor and indoor air assessment activities at the former Knitronics facility located in Cherryville, North Carolina in November 2015. The assessment activities included the collection and analysis of five SSV samples, six indoor air samples, and one background air sample. The results of the assessment activities are summarized below. • Two SSV samples on the eastern end of the building contained PCE concentrations above the Non-Residential SGSL and one SSV sample on the eastern end of the building contained TCE at a concentration above the Non-Residential SGSL. No other VOCs exceeded SGSLs in these samples, and no VOCs were detected above the SGSLs in the remaining samples. Mr. George Adams December 16, 2015 Page 8 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\Air Assessment\SS_IA_Reportrevised.docx • Four indoor air samples collected in the central and eastern portion of the building contained PCE concentrations above the Non-Residential IASL. No other VOCs exceeded IASLs in these samples, and no VOCs were detected above the IASLs in the remaining air samples. • Calculated cancer risks did not exceed a LICR of 1.34 x 10-5 in the indoor air samples, and calculated non-carcinogenic HQs were greater than 1 in indoor air sample locations IA-1, IA-2, and IA-3 and less than 1 in indoor air sample locations IA-4, IA-5, and IAS-6. Air samples IA-1, IA-2, and IA-3 were collected in the central and eastern portions of the building, which is currently mostly vacant. There is some synthetic fiber storage in the central portion of the building near sample IA-3. Based upon the results of the sub-slab vapor and indoor air assessment activities, additional assessment appears to be warranted. Vapor mitigation should be evaluated for the building, particularly if the eastern portion of the building will be utilized in the future. Ta b l e 1 Su m m a r y o f S u b - S l a b A i r A n a l y t i c a l D a t a Fo r m e r K n i t r o n i c s Ch e r r y v i l l e , N o r t h C a r o l i n a H& H J o b N o . M O H - 0 0 1 1 , 2 - D i c h l o r o e t h a n e 1 , 1 - D i c h l o r o e t h e n e c i s - 1 , 2 - D i c h l o r o e t h e n e t r a n s - 1 , 2 - D i c h l o r o e t h e n e ( t r a n s - 1 , 2 - D C E ) T e t r a c h l o r o e t h e n e ( P C E ) Trichloroethene (TCE)Vinyl Chloride SS - 1 <3 2 , 0 0 0 < 3 2 , 0 0 0 3 6 , 0 0 0 < 3 2 , 0 0 0 27 , 0 0 0 , 0 0 0 4 0 , 0 0 0 <20,000 DU P - 2 <3 2 , 0 0 0 < 3 2 , 0 0 0 3 4 , 0 0 0 < 3 2 , 0 0 0 25 , 0 0 0 , 0 0 0 3 6 , 0 0 0 <20,000 SS - 2 Wa r e h o u s e ( e a s t ) 11 / 0 5 / 1 5 T O - 1 5 < 1 6 < 1 6 < 1 6 < 1 6 15 0 , 0 0 0 <21 < 1 0 SS - 3 In a c t i v e O f f i c e ( e a s t ) 11 / 0 5 / 1 5 T O - 1 5 < 0 . 8 1 < 0 . 7 9 < 0 . 7 9 < 0 . 7 9 1 6 0 2 . 1 < 0 . 5 1 SS - 4 Wa r e h o u s e ( c e n t r a l ) 11 / 0 5 / 1 5 T O - 1 5 < 0 . 8 1 < 0 . 7 9 < 0 . 7 9 < 0 . 7 9 9 8 5 . 3 < 0 . 5 1 SS - 5 Wa r e h o u s e ( w e s t ) 11 / 0 5 / 1 5 T O - 1 5 < 0 . 8 1 < 0 . 7 9 < 0 . 7 9 < 0 . 7 9 1 4 0 2 . 0 < 0 . 5 1 Tr i p B l a n k - 2 NA 11 / 0 5 / 1 5 T O - 1 5 < 0 . 1 4 < 0 . 1 4 < 0 . 1 4 < 0 . 1 4 < 0 . 2 4 < 0 . 1 9 < 0 . 0 9 0 47 2 1 7 , 5 0 0 N S N S 3 , 5 0 0 1 7 5 2 , 7 9 0 No t e s : 1) N o r t h C a r o l i n a D e p a r t m e n t o f E n v i r o n m e n t a l Q u a l i t y ( D E Q ) D i v i s i o n o f W a s t e M a n a g e m e n t ( D W M ) N o n - R e s i d e n t i a l V a p o r I n t r u s i o n Sc r e e n i n g C o n c e n t r a t i o n s ( S e p t e m b e r 2 0 1 5 ) Bo l d in d i c a t e s c o n c e n t r a t i o n e x c e e d s N o n - R e s i d e n t i a l S u b - S l a b a n d E x t e r i o r S o i l G a s S c r e e n i n g L e v e l ( S e p t e m b e r 2 0 1 5 ) On l y c o m p o u n d s d e t e c t e d i n a t l e a s t o n e s a m p l e s h o w n NS = N o t S p e c i f i e d ; - - = N o t A p p l i c a b l e µg / m 3 = m i c r o g r a m s p e r c u b i c m e t e r J = d e t e c t e d a b o v e m e t h o d d e t e c t i o n l i m i t b u t b e l o w l a b o r a t o r y r e p o r t i n g l i m i t r e s u l t i n g i n a n e s t i m a t e d v a l u e Fo r m e r F i n i s h i n g R o o m 1 1 / 0 5 / 1 5 T O - 1 5 µg / m 3 No n - R e s i d e n t i a l S u b - S l a b a n d S o i l - G a s S c r e e n i n g L e v e l (1 ) S a m p l e I D S a m p l e L o c a t i o n S a m p l i n g D a t e A n a l y t i c a l M e t h o d Fil e : S : \ A A A - M a s t e r P r o j e c t s \ M o h i c a n M i l l s - M O H \ M O H - 0 0 1 K n i t r o n i c s \ A i r A s s e s s m e n t \ D a t a T a b l e s . x l s S S O A A n a l y t i c a l D a t a Da t e : 1 2 / 8 / 2 0 1 5 Table 1 (Page 1 of 1)Hart & Hickman, PC Ta b l e 2 Su m m a r y o f I n d o o r A i r a n d O u t d o o r A i r A n a l y t i c a l D a t a Fo r m e r K n i t r o n i c s Ch e r r y v i l l e , N o r t h C a r o l i n a H& H J o b N o . M O H - 0 0 1 1 , 2 - D i c h l o r o e t h a n e 1 , 1 - D i c h l o r o e t h e n e c i s - 1 , 2 - D i c h l o r o e t h e n e t r a n s - 1 , 2 - D i c h l o r o e t h e n e ( t r a n s - 1 , 2 - D C E ) T e t r a c h l o r o e t h e n e ( P C E ) Trichloroethene (TCE)Vinyl Chloride IA - 1 Fo r m e r F i n i s h i n g R o o m 1 1 / 0 5 / 1 5 T O - 1 5 < 0 . 1 4 < 0 . 1 4 0 . 8 3 < 0 . 1 4 61 0 1.5 < 0 . 0 9 0 IA - 2 <0 . 1 4 < 0 . 1 4 0 . 4 6 < 0 . 1 4 31 0 0.89 < 0 . 0 9 0 DU P - 1 <0 . 1 4 < 0 . 1 4 0 . 4 6 < 0 . 1 4 37 0 0.90 < 0 . 0 9 0 IA - 3 In a c t i v e O f f i c e ( e a s t ) 1 1 / 0 5 / 1 5 T O - 1 5 < 0 . 1 4 < 0 . 1 4 0 . 2 6 < 0 . 1 4 21 0 0.59 < 0 . 0 9 0 IA - 4 Wa r e h o u s e ( c e n t r a l ) 1 1 / 0 5 / 1 5 T O - 1 5 < 0 . 1 4 < 0 . 1 4 0 . 1 0 J < 0 . 1 4 71 0.42 < 0 . 0 9 0 IA - 5 Wa r e h o u s e ( w e s t ) 11 / 0 5 / 1 5 T O - 1 5 0 . 0 7 1 J < 0 . 1 4 < 0 . 1 4 < 0 . 1 4 6 . 5 0 . 1 3 J < 0 . 0 9 0 OA - 1 Ex t e r i o r ( s o u t h - c e n t r a l ) 1 1 / 0 5 / 1 5 T O - 1 5 < 0 . 1 4 < 0 . 1 4 < 0 . 1 4 < 0 . 1 4 0 . 2 2 J < 0 . 1 9 < 0 . 0 9 0 Tr i p B l a n k - 1 NA 11 / 0 5 / 1 5 T O - 1 5 < 0 . 1 4 < 0 . 1 4 < 0 . 1 4 < 0 . 1 4 < 0 . 2 4 < 0 . 1 9 < 0 . 0 9 0 IA S - 6 Ac t i v e O f f i c e ( w e s t ) 1 1 / 2 0 / 1 5 T O - 1 5 0 . 0 5 7 J < 0 . 1 4 < 0 . 1 4 < 0 . 1 4 5 . 3 0 . 1 3 J < 0 . 0 9 0 4. 7 2 1 7 5 N S N S 3 5 . 0 1 . 7 5 2 7 . 9 No t e s : Sa m p l e s w e r e c o l l e c t e d a t a h e i g h t o f a p p r o x i m a t e l y 5 f t a b o v e g r a d e 1) N o r t h C a r o l i n a D e p a r t m e n t o f E n v i r o n m e n t a l Q u a l i t y ( D E Q ) D i v i s i o n o f W a s t e M a n a g e m e n t ( D W M ) N o n - R e s i d e n t i a l V a p o r I n t r u s i o n Sc r e e n i n g C o n c e n t r a t i o n s ( S e p t e m b e r 2 0 Bo l d i n d i c a t e s c o n c e n t r a t i o n e x c e e d s N o n - R e s i d e n t i a l I n d o o r A i r a n d C r a w l s a p c e S c r e e n i n g C o n c e n t r a t i o n ( S e p t e m b e r 2 0 1 5 ) NS = N o t S p e c i f i e d ; N o t A p p l i c a b l e TC R = T a r g e t C a n c e r R i s k ; T H Q = T a r g e t H a z a r d Q u o t i e n t µg / m 3 = m i c r o g r a m s p e r c u b i c m e t e r J = d e t e c t e d a b o v e m e t h o d d e t e c t i o n l i m i t b u t b e l o w l a b o r a t o r y r e p o r t i n g l i m i t r e s u l t i n g i n a n e s t i m a t e d v a l u e No n - R e s i d e n t i a l I n d o o r A i r a n d C r a w l s p a c e S c r e e n i n g C o n c e n t r a t i o n (1 ) (T C R = 1 x 1 0 -5 a n d T H Q = 0 . 2 ) S a m p l e I D S a m p l e L o c a t i o n A n a l y t i c a l M e t h o d µg / m 3 Wa r e h o u s e ( e a s t ) T O - 1 5 S a m p l e D a t e 11 / 0 5 / 1 5 Fil e : S : \ A A A - M a s t e r P r o j e c t s \ M o h i c a n M i l l s - M O H \ M O H - 0 0 1 K n i t r o n i c s \ A i r A s s e s s m e n t \ D a t a T a b l e s . x l s I A S A n a l y t i c a l D a t a Da t e : 1 2 / 8 / 2 0 1 5 Table 2 (Page 1 of 1)Hart & Hickman, PC Table 3 Calculated Additive Carcinogenic Risks Indoor Air Sampling November 2015 Former Knitronics Cherryville, North Carolina H&H Job No. MOH-001 File: S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\Air Assessment\Data TablesRisk Calculator CAR Date: 12/15/2015 Figure 3 (Page 1 of 1) Hart & Hickman, PC Carcinogenic Risks Unit Location Compound Exposure Conc.IUR AT EF ED ET ug/m3 (ug/m3)-1 days days/yr years hr/hr IA-1 Tetrachloroethene 610 2.60E-07 25550.00 250.00 25.00 0.33 0.00001292 Trichloroethene 1.5 4.10E-06 25550.00 250.00 25.00 0.33 0.00000050 Total 1.34E-05 IA-2 Tetrachloroethene 310 2.60E-07 25550.00 250.00 25.00 0.33 0.00000657 Trichloroethene 0.89 4.10E-06 25550.00 250.00 25.00 0.33 0.00000030 Total 6.86E-06 IA-3 Tetrachloroethene 210 2.60E-07 25550.00 250.00 25.00 0.33 0.00000445 Trichloroethene 0.59 4.10E-06 25550.00 250.00 25.00 0.33 0.00000020 Total 4.64E-06 IA-4 Tetrachloroethene 71 2.60E-07 25550.00 250.00 25.00 0.33 0.00000150 Trichloroethene 0.42 4.10E-06 25550.00 250.00 25.00 0.33 0.00000014 Total 1.64E-06 IA-5 Tetrachloroethene 6.5 2.60E-07 25550.00 250.00 25.00 0.33 0.00000014 Trichloroethene 0.13 4.10E-06 25550.00 250.00 25.00 0.33 0.00000004 1,2-Dichloroethane 0.071 2.60E-05 25550.00 250.00 25.00 0.33 0.00000015 Total 3.31E-07 IAS-6 Tetrachloroethene 5.3 2.60E-07 25550.00 250.00 25.00 0.33 0.00000011 Trichloroethene 0.13 4.10E-06 25550.00 250.00 25.00 0.33 0.00000004 1,2-Dichloroethane 0.057 2.60E-05 25550.00 250.00 25.00 0.33 0.00000012 Total 2.76E-07 Notes: IUR = Inhalation Unit Rate; AT = Averaging Time; EF = Exposure Frequency; ED = Exposure Duration; ET = Exposure Time µg/m3 = microgram per cubic meter IUR values taken from Regional Screening Level (RSL) Composite Worker Ambient Air Table dated June 2015 Risk Former Finishing Room Warehouse (east) Inactive Office (east) Warehouse (central) Active Office (west) Warehouse (West) Table 4 Calculated Additive Non-Carcinogenic Risks Indoor Air Sampling November 2015 Former Knitronics Cherryville, North Carolina H&H Job No. MOH-001 File: S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\Air Assessment\Data TablesRisk Calculator NONCAR Date: 12/15/2015 Figure 4 (Page 1 of 1) Hart & Hickman, PC Non-Carcinogenic Risks Unit Location Compound Exposure Conc.Rfc AT EF ED ET ug/m3 mg/m3 days days/yr years hr/hr IA-1 Tetrachloroethene 610 4.00E-02 9125.00 250.00 25.00 0.33 3.47825342 Trichloroethene 1.5 2.00E-03 9125.00 250.00 25.00 0.33 0.17106164 Total 3.65E+00 IA-2 Tetrachloroethene 310 4.00E-02 9125.00 250.00 25.00 0.33 1.76763699 Trichloroethene 0.89 2.00E-03 9125.00 250.00 25.00 0.33 0.10149658 Total 1.87E+00 IA-3 Tetrachloroethene 210 4.00E-02 9125.00 250.00 25.00 0.33 1.19743151 Trichloroethene 0.59 2.00E-03 9125.00 250.00 25.00 0.33 0.06728425 Total 1.26E+00 IA-4 Tetrachloroethene 71 4.00E-02 9125.00 250.00 25.00 0.33 0.40484589 Trichloroethene 0.42 2.00E-03 9125.00 250.00 25.00 0.33 0.04789726 Total 4.53E-01 IA-5 Tetrachloroethene 6.5 4.00E-02 9125.00 250.00 25.00 0.33 0.03706336 Trichloroethene 0.13 2.00E-03 9125.00 250.00 25.00 0.33 0.01482534 1,2-Dichloroethane 0.071 7.00E-03 9125.00 250.00 25.00 0.33 0.00231341 Total 5.42E-02 IAS-6 Tetrachloroethene 5.3 4.00E-02 9125.00 250.00 25.00 0.33 0.03022089 Trichloroethene 0.13 2.00E-03 9125.00 250.00 25.00 0.33 0.01482534 1,2-Dichloroethane 0.057 7.00E-03 9125.00 250.00 25.00 0.33 0.00185724 Total 4.69E-02 Notes: Rfc = Reference Concentration; AT = Averaging Time; EF = Exposure Frequency; ED = Exposure Duration; ET = Exposure Time mg/m3 = milligram per cubic meter µg/m3 = microgram per cubic meter Rfc values taken from Regional Screening Level (RSL) Composite Worker Ambient Air Table dated June 2015 Active Office (west) Hazard Quotient Former Finishing Room Warehouse (east) Inactive Office (east) Warehouse (central) Warehouse (West) SITE 0 2000 4000 APPROXIMATE SCALE IN FEET N U.S.G.S. QUADRANGLE MAP QUADRANGLE 7.5 MINUTE SERIES (TOPOGRAPHIC) WACO, NORTH CAROLINA, 1976 TITLE PROJECT SITE LOCATION MAP FORMER KNITRONICS1515 WEST ACADEMY STREETCHERRYVILLE, NC DATE: JOB NO: REVISION NO: FIGURE: 12-1-15 0 1MOH-001 P A U L H B E A M R O A D GRO V E R O A D WEST A C A D E M Y S T R E E T JOB NO. MOH-001 REVISION NO. 0DATE: 12-8-15 FIGURE NO. 2 2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 Geology LEGEND SITE PROPERTY BOUNDARY SUB-SLAB AND/OR INDOOR AIR SAMPLE LOCATION BACKGROUND AIR SAMPLE LOCATION ASSUMED SHALLOW GROUNDWATERFLOW DIRECTION FORMER KNITRONICS 1515 WEST ACADEMY STREET CHERRYVILLE, NC INDOOR/BACKGROUND AIR SAMPLE RESULTS ACTIVE OFFICE FENCE CONCENTRATION (μg/m3) SAMPLE ID NOTES: 1. ONLY COMPOUNDS DETECTED IN AT LEAST ONE SAMPLE SHOWN.2. RED VALUE = CONCENTRATION EXCEEDS DEQ INDOOR AIR AND CRAWLSPACE SCREENING CONCENTRATION. IA-1 TETRACHLOROETHENE 610 COMPOUND SS-1/IA-1 1,2-DICHLOROETHANE <0.14 cis-1,2-DICHLOROETHENE 0.83 TETRACHLOROETHENE 610 TRICHLOROETHENE 1.5 INACTIVE OFFICES SS-2/IA-2 1,2-DICHLOROETHANE <0.14 cis-1,2-DICHLOROETHLENE 0.46 TETRACHLOROETHENE 310 TRICHLOROETHENE 0.89 SS-4/IA-4 1,2-DICHLOROETHANE <0.14 cis-1,2-DICHLOROETHENE 010 J TETRACHLOROETHENE 71 TRICHLOROETHENE 0.42 SS-5/IA-5 1,2-DICHLOROETHANE 0.071 J cis-1,2-DICHLOROETHENE <0.14 TETRACHLOROETHENE 6.5 TRICHLOROETHENE 0.13 J IAS-6 1,2-DICHLOROETHANE 0.057 J cis-1,2-DICHLOROETHENE <0.14 TETRACHLOROETHENE 5.3 TRICHLOROETHENE 0.13 J OA-1 1,2-DICHLOROETHANE <0.14 cis-1,2-DICHLOROETHENE <0.14 TETRACHLOROETHENE 0.22 J TRICHLOROETHENE <0.19 SS-3/IA-3 1,2-DICHLOROETHANE <0.14 cis-1,2-DICHLOROETHENE 0.26 TETRACHLOROETHENE 210 TRICHLOROETHENE 0.59 VACANT S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\Air Assessment\SS_IA_Report.docx Appendix A Laboratory Analytical Data Page 1 of 28 Page 2 of 28 Page 3 of 28 Page 4 of 28 Page 5 of 28 Page 6 of 28 Page 7 of 28 Page 8 of 28 Page 9 of 28 Page 10 of 28 Page 11 of 28 Page 12 of 28 Page 13 of 28 Page 14 of 28 Page 15 of 28 Page 16 of 28 Page 17 of 28 Page 18 of 28 Page 19 of 28 Page 20 of 28 Page 21 of 28 Page 22 of 28 Page 23 of 28 Page 24 of 28 Page 25 of 28 Page 26 of 28 Page 27 of 28 Page 28 of 28 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 November 30, 2015 Steve Libbey Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 Project Location: Cherryville, NC Client Job Number: Project Number: MOH-001 Laboratory Work Order Number: 15K1004 Enclosed are results of analyses for samples received by the laboratory on November 20, 2015. If you have any questions concerning this report, please feel free to contact me. Sincerely, Lisa A. Worthington Project Manager Page 1 of 12 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY 11/30/2015Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 ATTN: Steve Libbey MOH-001 15K1004 The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB Cherryville, NC IAS-6 15K1004-01 Indoor air EPA TO-15 Page 2 of 12 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Johanna K. Harrington Manager, Laboratory Reporting Page 3 of 12 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Cherryville, NC Date Received: 11/20/2015 Work Order: 15K1004Sample Description/Location: Field Sample #: IAS-6 Sample ID: 15K1004-01 Sample Matrix: Indoor air Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -10 Receipt Vacuum(in Hg): -10.1 Sampled: 11/20/2015 15:15 Canister ID: 1138 Flow Controller ID: 3170 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlagRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL 1,2-Dichloroethane 0.014 0.035 11/21/15 11:57 TPHJ0.057 0.7020.140.0098 1,1-Dichloroethylene ND 0.035 11/21/15 11:57 TPHND0.7020.140.0086 cis-1,2-Dichloroethylene ND 0.035 11/21/15 11:57 TPHND0.7020.140.013 trans-1,2-Dichloroethylene ND 0.035 11/21/15 11:57 TPHND0.7020.140.0093 Tetrachloroethylene 0.79 0.035 11/21/15 11:57 TPH5.3 0.7020.240.010 Trichloroethylene 0.025 0.035 11/21/15 11:57 TPHJ0.13 0.7020.190.010 Vinyl Chloride ND 0.035 11/21/15 11:57 TPHND0.7020.0900.015 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)112 11/21/15 11:5770-130 Page 4 of 12 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Sample Extraction Data Prep Method: TO-15 Prep-EPA TO-15 Lab Number [Field ID]Batch Date Pressure Dilution Pre Dilution Pre-Dil Initial mL Pre-Dil Final mL Default Injection mL Actual Injection mL 15K1004-01 [IAS-6]B136451 1.5 1 N/A 1000 400 855 11/20/15 Page 5 of 12 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B136451 - TO-15 Prep Blank (B136451-BLK1)Prepared & Analyzed: 11/20/15 0.020ND1,2-Dichloroethane 0.020ND1,1-Dichloroethylene 0.020NDcis-1,2-Dichloroethylene 0.020NDtrans-1,2-Dichloroethylene 0.020 J0.019Tetrachloroethylene 0.020NDTrichloroethylene 0.020NDVinyl Chloride 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1159.18 LCS (B136451-BS1)Prepared & Analyzed: 11/20/15 5.00 70-13094.84.741,2-Dichloroethane 5.00 70-13095.74.781,1-Dichloroethylene 5.00 70-13092.24.61cis-1,2-Dichloroethylene 5.00 70-13083.14.16trans-1,2-Dichloroethylene 5.00 70-1301175.84Tetrachloroethylene 5.00 70-1301015.03Trichloroethylene 5.00 70-1301185.88Vinyl Chloride 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1229.78 Page 6 of 12 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 FLAG/QUALIFIER SUMMARY *QC result is outside of established limits. †Wide recovery limits established for difficult compound. ‡Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J Page 7 of 12 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,FL,NJ,NY,VA,ME1,2-Dichloroethane AIHA,FL,NJ,NY,VA,ME1,1-Dichloroethylene AIHA,FL,NY,VA,MEcis-1,2-Dichloroethylene AIHA,NJ,NY,VA,MEtrans-1,2-Dichloroethylene AIHA,FL,NJ,NY,VA,METetrachloroethylene AIHA,FL,NJ,NY,VA,METrichloroethylene AIHA,FL,NJ,NY,VA,MEVinyl Chloride The CON-TEST Environmental Laboratory operates under the following certifications and accreditations: Code Description Number Expires 100033AIHA-LAP, LLCAIHA 02/1/2016 M-MA100Massachusetts DEPMA 06/30/2016 PH-0567Connecticut Department of Publilc HealthCT 09/30/2017 10899 NELAPNew York State Department of HealthNY 04/1/2016 2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2016 LAO00112Rhode Island Department of HealthRI 12/30/2015 652North Carolina Div. of Water QualityNC 12/31/2015 MA007 NELAPNew Jersey DEPNJ 06/30/2016 E871027 NELAPFlorida Department of HealthFL 06/30/2016 LL015036Vermont Department of Health Lead LaboratoryVT 07/30/2016 C2065State of Washington Department of EcologyWA 02/23/2016 2011028State of MaineME 06/9/2017 460217Commonwealth of VirginiaVA 12/14/2015 2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2016 Page 8 of 12 Page 9 of 12 Page 10 of 12 Page 11 of 12 Page 12 of 12 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\Air Assessment\SS_IA_Report.docx Appendix B Indoor Air Building Survey and Sampling Forms