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HomeMy WebLinkAbout20051_Travis Knits_Soil and GW Assmt Rpt_2016.03.15 i S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\SoilGWAssessment\Report\Final to Client\Soil and GW Assessment.docx Soil and Groundwater Assessment Report Former Knitronics Facility 1515 W Academy Street Cherryville, North Carolina H&H Job No. MOH-001 Table of Contents 1.0 Introduction and Background .............................................................................................. 1 2.0 Assessment Activities ............................................................................................................. 4 2.1 Soil Sampling Activities ...................................................................................................... 4 2.2 Groundwater Assessment Activities .................................................................................... 5 2.3 Quality Control .................................................................................................................... 7 2.4 Investigation Derived Waste ................................................................................................. 7 3.0 Analytical Results................................................................................................................... 8 3.1 Soil Sample Results ............................................................................................................. 8 3.2 Groundwater Levels and Flow Direction ............................................................................. 8 3.3 Groundwater Sample Results ............................................................................................... 9 3.4 Extent of Groundwater Impacts ......................................................................................... 10 3.5 Quality Control Results...................................................................................................... 11 4.0 Summary ............................................................................................................................... 12 ii S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\SoilGWAssessment\Report\Final to Client\Soil and GW Assessment.docx List of Tables Table 1 Summary of Groundwater Elevation Measurements Table 2 Summary of Soil Analytical Data Table 3 Summary of Groundwater Analytical Data List of Figures Figure 1 Site Location Map Figure 2 Site Vicinity and Water Supply Well Location Map Figure 3 Site Map Figure 4 Soil Sample Locations Map Figure 5 Potentiometric Map – Shallow Wells (February 18, 2016) Figure 6 Potentiometric Map – Deeper Wells (February 18, 2016) Figure 7 Groundwater Impacts – Shallow Wells Figure 8 Groundwater Impacts – Deeper Wells List of Appendices Appendix A Boring Logs and Well Construction Diagrams Appendix B Laboratory Analytical Reports 1 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\SoilGWAssessment\Report\Final to Client\Soil and GW Assessment.docx Soil and Groundwater Assessment Former Knitronics Facility 1515 W Academy Street Cherryville, North Carolina H&H Job No. MOH-001 1.0 Introduction and Background This report presents the methods and results of limited soil and groundwater assessment activities at the former Knitronics facility located at 1515 W Academy Street, in Cherryville, North Carolina. A site location map is provided as Figure 1. The facility building is on a parcel approximately 12.13 acres in size. An adjacent parcel containing 4.64 acres consists of undeveloped wooded land to the east of the facility building. Both of these parcels are owned by Mohican Mills, Inc. via merger with Travis Knits, Inc. The facility contains a 197,000 sq ft warehouse building built in 1971, which was formerly used as a textile dyeing mill. The warehouse building is currently partially vacant and partially used for warehouse space. In July 2015, Phase II Environmental Site Assessment soil and groundwater samples were collected by others for a potential purchase to assess for subsurface impacts in the eastern portion of the developed property. The results of the soil analyses indicated that tetrachloroethene (PCE) was detected above the North Carolina Department of Environmental Quality (DEQ) Soil-to- Groundwater Maximum Soil Contaminant Concentration (MSCC). Additionally, PCE, trichloroethene (TCE), cis,1,2-dichloroethene (1,2-DCE), chromium, and lead were detected in groundwater above the DEQ 15A NCAC 2L Groundwater Quality Standards (2L Standards). PCE was detected in groundwater at concentrations up to 110,000 µg/l. The metal detections are likely naturally occurring as there is no mention in the Phase II ESA report that care was taken to collect low turbidity samples, and the samples were collected using a direct push technology (DPT) rig. In October and November 2015, Hart & Hickman, PC (H&H) completed a preliminary potential receptor survey for the area near the former Knitronics facility. H&H identified 64 potential water supply wells within the 0.5-mile search radius. Water supply wells used for drinking water 2 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\SoilGWAssessment\Report\Final to Client\Soil and GW Assessment.docx are located west and south of the subject property. Water supply wells WSW-1 through WSW-5 were sampled in October 2015 with results submitted to NC DEQ and mailed to the water supply well owners. No analyzed compounds were detected above laboratory reporting limits in these water supply well samples. After reviewing the receptor survey and initial water supply well results, DEQ requested that water supply wells WSW-17, WSW-18, WSW-31, WSW-32, WSW- 33, and WSW-34 be sampled. The additional water supply wells were sampled in November 2015 for target volatile organic compounds (VOCs). No analyzed compounds were detected above laboratory reporting limits in the additional water supply well samples. The second round of water supply well results were also submitted to NC DEQ and mailed to the water supply well owners. A Site Vicinity Map depicting nearby water supply wells is provided as Figure 2. Areas served by public water lines are also indicated on this figure. Additional documentation for the receptor survey and water supply well sampling is provided in H&H’s Potential Receptor Survey Report dated November 16, 2015 and H&H’s Water Supply Well Sampling Report dated December 1, 2015. The potential receptor survey identified vapor intrusion as a concern for the on-site building. On November 5, 2015, subslab vapor (SSV) and indoor air assessment activities were completed by H&H at the facility. Two SSV samples on the eastern end of the building contained PCE concentrations above the NC DEQ Inactive Hazardous Sites Branch (IHSB) Non-Residential Soil Gas Screening Level (SGSL) and one SSV sample on the eastern end of the building contained TCE at a concentration above the Non-Residential SGSL. Four indoor air samples collected in the central and eastern portion of the building contained PCE concentrations above the NC DEQ IHSB Non-Residential Indoor Air and Crawlspace Screening Concentration (IASL). These data indicate on-going volatilization of contaminants from the subsurface to the indoor air. Only the western portion of the building is currently used and the eastern portion of the building is vacant. The western portion of the building is used for warehousing purposes. Based on the one indoor air dataset, a risk assessor with Hazardous Substance and Waste Management Research, Inc. evaluated that data and concluded that the potential for increased health risks from exposure to indoor air at the former Knitronics facility is low, particularly in the active portion of the site. NC DEQ also conducted a Health Risk Evaluation and concluded 3 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\SoilGWAssessment\Report\Final to Client\Soil and GW Assessment.docx that further assessment may be necessary (see January 22, 2016 letter from Mr. George Adams of NC DEQ). In the Notice of Request for Remedial Investigation letter dated January 19, 2016, DEQ IHSB requested that a Remedial Investigation (RI) Work Plan for additional assessment activities be submitted for the site. It is our understanding that Mohican has decided not to proceed with the RI based on the history of the site. The assessment activities discussed in this report were developed as an initial limited phase to better define the extent of soil and groundwater impacts at the site and to assist in developing a Brownfields Agreement. 4 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\SoilGWAssessment\Report\Final to Client\Soil and GW Assessment.docx 2.0 Assessment Activities 2.1 Soil Sampling Activities On January 28 and 29, 2016, H&H contracted with Geologic Exploration, Inc., as a NC Certified Well Driller, to advance six soil borings at the site using a Direct Push technology (DPT) drill rig or a hand auger. The soil boring locations are presented in Figure 4. The limited soil assessment activities were intended to identify potential soil impacts in select areas. Other source areas may be present on-site. Soil samples were collected from the following locations: • Interior wastewater manhole/sewer line adjacent to a former “PCE washer” used by the former Knitronics textile facility as reported by a former employee of the property owner (SB-1). • Reported location of former Knitronics PCE washer and certain dyeing machines (SB-2 and SB-3). • Former dyeing machine location (SB-4). • Former exterior chemical tank containment area and wastewater sewer junction box located near the loading dock (SB-5). • Former aboveground fuel oil storage tank (AST) containment area adjacent to the location where a PCE AST was reported by an employee of the property owner (SB-6). During sampling, the recovered soil was screened in the field for the presence of odors, staining, and/or elevated photoionization detector (PID) readings. Based on elevated field screening readings, soil samples for laboratory analysis were collected at the following intervals: SB-1 at 7-9 feet (ft) below ground surface (bgs); SB-2 at 15-17 ft bgs and 25 to 27 ft bgs; SB-3 at 7-9 ft bgs; SB-4 at 5-7 ft bgs and 27 to 30 ft bgs; SB-5 at 9-11 ft bgs and 25 to 27 ft bgs; and SB-6 at 7-10 ft bgs. These depths were based on field screening results and the anticipated depths of subsurface features and/or likely depth of impacts associated with the building. Soil boring logs are included in Appendix A. 5 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\SoilGWAssessment\Report\Final to Client\Soil and GW Assessment.docx The soil samples collected from each boring were analyzed for VOCs by EPA Method 8260. In addition, shallow soil samples collected from SB-1 through SB-5 were analyzed for Hazardous Substance List (HSL) Metals by EPA Method 6010C/7471B and semi-volatile organic compounds (SVOCs) by EPA Method 8270. The samples were collected into laboratory supplied sample containers, placed on ice in a cooler, and sent to Prism Laboratories, Inc (Prism) for analysis using standard chain of custody protocol. Following boring advancement and sample collection, the soil borings were abandoned with bentonite grout, and the surfaces were patched with concrete. 2.2 Groundwater Assessment Activities On January 25 through February 5, 2016, five permanent shallow groundwater monitoring wells (MW-1, MW-2, MW-3S, MW-4S, and MW-5S) and four permanent deep monitoring wells (MW-2D, MW-3D, MW-4D, and MW-5D) were installed at the site to help define the extent of shallow and deeper groundwater impacts. Prior to well installation activities, H&H obtained a well permit from Gaston County Health Department. The shallow wells were installed using a hollow stem auger (HSA) and the deep wells were installed using HSA, air rotary, and mud rotary drilling techniques. During well installation, a stainless steel split-spoon soil sampler was utilized at five-to ten foot intervals (above rock) for lithology review and for field screening for the presence of odors, staining, and/or elevated PID readings. Soil boring logs and well construction logs are included in Appendix A. The locations of the monitoring wells are presented in Figure 3. Apart from the source area shallow well MW-3S, the shallow monitoring wells were constructed with two-inch diameter PVC riser with 15 feet of 0.010-inch slotted screen installed to bracket the water table. The shallow wells depths ranged from 28 to 37 ft bgs. Due to the high concentrations of PCE near the source area (>100,000 ppb), MW-3S was constructed using a galvanized steel riser and well screen. 6 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\SoilGWAssessment\Report\Final to Client\Soil and GW Assessment.docx The deep monitoring wells were constructed of two-inch diameter PVC casing with 5 to 10 feet of 0.010-inch slotted screen installed to interface the first water bearing zone in partially weathered rock (PWR). With the exception of MW-3D, the deep wells were constructed with a 6-inch diameter outer PVC casing set into PWR. Due to potential high PCE concentrations near the source area, the outer casing for MW-3D was constructed of galvanized steel. Surface casing depths are provided in Table 1. The depth to partially weathered rock as determined by hollow- stem auger refusal ranged from 55 ft bgs (MW-4D) to 105 ft bgs (MW-2D). Site wells located in asphalt or grass were completed at the surface with locking flushed- mounted steel vaults. Wells located in wooded areas were completed with locking steel stick-up vaults. After installation, the well top-of-casing elevations were estimated using surveying techniques in order to develop shallow and deep groundwater contour maps. Monitoring well latitude/longitude coordinates were also mapped using a Trimble GPS unit. Top-of-casing elevations and latitude/longitude coordinates are presented in Table 1. Following installation, the monitoring wells were developed using standard protocols. Prior to sample collection, the monitoring wells were purged with dedicated bailers or pump until pH, temperature, and conductivity field measurements stabilized. Groundwater samples collected from the monitoring wells were labeled and shipped under standard chain-of-custody procedures to Prism for analysis of VOCs by EPA Method 8260. To evaluate prior metal detections in groundwater, the source area shallow monitoring well (MW-3S) also was sampled for Resource Conservation and Recovery Act (RCRA) metals by EPA Method 6010C/7470A after attempting to reduce turbidity levels below 10 NTU using low flow purging techniques with a submersible pump. The lowest turbidity level that H&H could achieve for MW-3S was 18.6 NTUs, which is slightly above the EPA recommended turbidity value of 10 NTU. 7 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\SoilGWAssessment\Report\Final to Client\Soil and GW Assessment.docx 2.3 Quality Control For quality control purposes, one duplicate soil sample was collected from SB-5 (9-11’) and analyzed for VOCs by EPA Method 8260, SVOCs by EPA Method 8270, and HSL Metals by EPA Method 6010C/7471B. Additionally, one duplicate groundwater sample was collected from MW-3D and analyzed VOCs by EPA Method 8260. The duplicate samples were collected to allow determination of analytical repeatability. H&H also submitted one laboratory-prepared trip blank sample (Trip Blank) and one field blank sample (Field Blank) for laboratory analysis of VOCs by EPA Method 8260. 2.4 Investigation Derived Waste Due to elevated compound concentrations near the source area, soil cuttings and development/purge water generated during the installation and sampling of soil borings SB-1 through SB-6 and near source area shallow and deep wells MW-3S and MW-3D were containerized in 55-gallon drums. Soil cuttings from the remaining wells were spread in the vicinity of the wells. Development and purge water generated during the installation and sampling of the monitoring wells were containerized in 55-gallon drums. Composite samples were collected from the drum materials for waste disposal purposes. The investigation derived waste (IDW) drums will be profiled and properly disposed at permitted facilities. 8 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\SoilGWAssessment\Report\Final to Client\Soil and GW Assessment.docx 3.0 Analytical Results 3.1 Soil Sample Results The results of the limited soil assessment activities indicate widespread low level PCE soil impacts were detected in each assessed area. Impacts were detected below the floor of the former dyehouse and also outside the eastern portion of the building. PCE was detected in the soil samples SB-1 through SB-6 at concentrations above its IHSB Preliminary Soil Remediation Goals (PSRGs) for Protection of Groundwater of 0.005 mg/kg (IHSB PSRG Table, September 2015). The concentrations of PCE ranged from 0.056 mg/kg (SB-6) to 57 mg/kg (SB-1). The Residential PSRG for PCE (32 mg/kg) was also exceeded in SB-1. Additionally, 1,1,1,2- tetrachloroethane (1,1,1,2-TCA) was detected in SB-1 (7-9’) and SB-5 (25-27’) at concentrations above its Protection of Groundwater PSRG of 0.0059 mg/kg, but below its Residential PSRG of 2 mg/kg. No other VOCs were detected above their respective PSRGs. No SVOC or metal impacts were detected in the soil samples, although metals consistent with naturally occurring levels were detected. Based on these results, SVOCs and metals are not considered to be constituents of concern for this site. The analytical results are summarized on Table 2 and analytical detections in soil are shown on Figure 4. The soil laboratory report along with chain-of-custody are included in Appendix B. 3.2 Groundwater Levels and Flow Direction Water levels in site monitoring wells were gauged using an electronic water level meter on February 9, 2016 (Table 1). After allowing ample time for water levels to reach static equilibrium, water levels were again gauged on February 18, 2016. The estimated potentiometric surface maps for the shallow and deeper aquifers for the February 2016 groundwater elevation data are presented in Figures 5 and 6, respectively. The groundwater flow directions in the shallow (saprolite) and deeper (PWR) aquifers are generally to the east toward an unnamed tributary of Muddy Fork Creek located approximately 700 ft southeast of the 9 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\SoilGWAssessment\Report\Final to Client\Soil and GW Assessment.docx southeast corner of the site. The easterly flow direction is away from the locations of properties with drinking water supply wells. 3.3 Groundwater Sample Results The laboratory analytical results for the shallow wells indicated PCE was detected in MW-1 (97 µg/L), MW-2S (7.0 µg/L), MW-3S (120,000 µg/L), MW-4S (17 µg/L), and MW-5S (11 µg/L) above its 2L Groundwater Standard of 0.7 µg/L. TCE (260 µg/L) and cis-1,2-DCE (140 µg/L) were also detected in MW-3S at concentrations above the 2L Groundwater Standards of 3 µg/L and 70 µg/L, respectively. No other compounds were detected above 2L Groundwater Standards in the shallow monitoring wells. Because of the detection of PCE in the upgradient monitoring well MW-1, this well was resampled on February 18, 2016 to confirm the PCE concentration detected in this well on February 5, 2016. Prior to sample collection, the monitoring well was thoroughly purged with a dedicated bailer. Approximately thirty gallons of water were purged from the well. PCE was detected in the sample at a concentration of 16 µg/L which is below but on the same order of magnitude as the February 5, 2016 concentration. The presence of PCE in the upgradient well may be related to the off-site property to the west, which was formerly occupied by a textile operation. Using low turbidity sampling methods, no RCRA metals were detected above the 2L Groundwater Standards in near source area monitoring well MW-3S. Based on these results, the metals detected by others during the July 2015 sampling event were not confirmed, and the prior metal detections in groundwater are attributed to samples that were collected without attention to turbidity. The laboratory analytical results for the PWR (deeper aquifer) wells indicated PCE was detected in MW-3D (460 µg/L), MW-4D (95 µg/L), and MW-5D (1,700 µg/L) above its 2L Groundwater Standard. Additionally, TCE was detected in MW-3D (8.4 µg/L) and MW-5D (5.5 µg/L) above 10 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\SoilGWAssessment\Report\Final to Client\Soil and GW Assessment.docx its 2L Groundwater Standard. No other compounds were detected above 2L Groundwater Standards in the deeper wells. PCE concentrations in monitoring wells MW-1 (2/5/16 sample), MW-3S, MW-3D, MW-4D, and MW-5D exceeded its DEQ Division of Waste Management (DWM) Residential and Non- Residential Vapor Intrusion Groundwater Screening Levels (GWSLs) of 48.4 µg/L and 11.5 µg/L. The PCE concentration in downgradient shallow well MW-4S only exceeds the Residential GWSL. Additionally, the TCE concentration detected in MW-3S, MW-3D, and MW-5D exceeded its Residential and Non-Residential GWSLs. There are no GWSLs specified for cis-1,2-DCE. Vapor intrusion sampling and risk calculations for the on-site building were addressed in H&H’s Sub-Slab/Indoor Air Assessment report dated December 16, 2015. No buildings are currently located within 500 ft downgradient of the well pairs MW-4S/D and MW-5S/D which are located near the downgradient property line. In addition, PCE levels in shallow groundwater near the downgradient property line are close to or below residential GSWLs. Additionally, Residential GWSLs were not exceeded in the cross-gradient wells MW-2S and MW-2D, which are situated between the site building and residences to the south. Based on these results, the potential for a vapor intrusion risk to off-site properties is considered to be low. Groundwater sample results are summarized on Table 3. Groundwater analytical concentrations detected in the shallow and deeper monitoring wells are shown on Figures 7 and 8, respectively. The groundwater laboratory report along with chain-of-custody are included in Appendix B. 3.4 Extent of Groundwater Impacts The horizontal and vertical extent of groundwater impacts was not defined by this assessment work. PCE was detected above its groundwater standard in both shallow (saprolite) groundwater and deeper (PWR) groundwater. Low concentrations were detected in upgradient shallow groundwater (MW-1) and cross-gradient shallow groundwater (MW-2S). The detection of PCE in the upgradient monitoring well may indicate an off-site source of PCE to the west of the site. 11 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\SoilGWAssessment\Report\Final to Client\Soil and GW Assessment.docx Importantly, no PCE impacts were detected in the PWR well MW-2D which is situated between the source area and off-site bedrock water supply wells to the south. Relatively higher levels of PCE in shallow and deeper groundwater extend downgradient and likely beyond the property limits in the east and southeast directions. Source area PCE concentrations (120,000 µg/L) are relatively high in shallow groundwater just east of the facility building. Groundwater impacts have migrated from the source area in a hydraulically downgradient direction to the east and southeast. The highest downgradient concentration is 1,700 µg/L in PWR well MW-5D. These concentrations compare to the groundwater standard for PCE of 0.7 µg/L. Monitoring well MW-5D is situated approximately 500 ft downgradient of the source area. The relatively higher PCE levels in the deeper well of the MW-5S/D well pair indicates that PWR is likely a more transmissive zone in the area which is common in the Piedmont. In addition, because MW-5D is slightly cross-gradient of the flow direction based on the potentiometic surface, the impacts may be moving by fracture controlled flow and under the influence of the stream to the southeast. 3.5 Quality Control Results The quality control sample results indicate good quality datasets were collected. The soil and groundwater duplicate sample results were similar to the original samples. No constituents were detected in the field blank or trip blank samples at concentrations above the laboratory reporting limits. Duplicate, field blank, and trip blank sample results are summarized in Tables 2 and 3. 12 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\SoilGWAssessment\Report\Final to Client\Soil and GW Assessment.docx 4.0 Summary H&H completed limited soil and groundwater sampling activities at the former Knitronics facility located in Cherryville, North Carolina. The assessment activities included the collection of nine soil samples from six soil borings, and the installation and sampling of nine permanent groundwater monitoring wells. The results of the assessment activities are summarized below. • VOC impacts were detected in each soil sample collected and the primary VOC detected was PCE. PCE was detected in the nine soil samples at concentrations above the PSRGs for Protection of Groundwater. Additionally, the Residential PSRG for PCE was also exceeded one soil sample. The Industrial PSRG for PCE was not exceeded in the analyzed soil samples. The extent of soil impacts is not defined and other source areas may be present. • No SVOC or metal impacts were detected in the soil samples. These compounds are not considered to be constituents of concern for the site. • PCE was detected at concentrations exceeding its 2L Groundwater Standard in five shallow monitoring wells and three deeper monitoring wells. Compound concentrations in two shallow monitoring wells and three deeper monitoring exceeded Non-Residential Vapor Intrusion GWSLs. The extents of shallow and deeper groundwater impacts are not defined and appear to be migrating off-site to the east and southeast. PCE detected in upgradient well MW-1 may indicate the existence of an upgradient off-site source. • The shallow and deeper groundwater flow direction is to the east which is away from the drinking water supply wells. • No RCRA metals were detected above the 2L Groundwater Standards in near source area monitoring well MW-3S and metals are not considered to be constituents of concern for site groundwater. Table 1 (Page 1 of 1) Hart & Hickman, PC Table 1 Summary of Groundwater Elevation Measurements Former Knitronics Facility Cherryville, North Carolina H&H Job No. MOH-001 Monitoring Well ID MW-1 35 Saprolite N/A 20-35 900.00 866-881 35.36882513 -81.40399212 29.83 870.17 29.63 870.37 MW-2S 33 Saprolite N/A 20-35 894.99 860-875 35.36862052 -81.40202866 26.19 868.80 26.18 868.81 MW-2D 120 PWR 105 115-120 894.74 775-780 35.36861309 -81.40206154 25.55 869.19 25.45 869.29 MW-3S 37 Saprolite N/A 22-37 894.34 858-873 35.36987441 -81.40084700 30.76 863.58 30.49 863.85 MW-3D 102 PWR 92 97-102 893.90 792-797 35.36975209 -81.40052283 30.22 863.68 29.90 864.00 MW-4S 28 Saprolite N/A 13-28 883.46 852-867 35.37057144 -81.39922473 21.21 862.25 21.23 862.23 MW-4D 67 PWR 56 57-67 883.37 813-823 35.37055682 -81.39921518 21.39 861.98 21.43 861.94 MW-5S 28 Saprolite N/A 13-28 883.18 852-867 35.36914936 -81.39925070 20.70 862.48 20.75 862.43 MW-5D 84 PWR 74 79-84 883.04 796-801 35.36915859 -81.39925809 20.87 862.17 20.80 862.24 Notes:TOC = Top of PVC well casing; DTW = Depth to water from TOC ft bgs = Feet below ground surface; MSL = mean sea level; N/A = Not ApplicableMW-1 through MW-3D were constructed with lockable flush-mounted well pads MW-4S through MW-5D constructed with lockable steel stick-up covers TOC measurements completed by H&H on February 9, 2016TOC elevation referenced to estimated location of 900 ft msl topograohic contour February 18, 2016 Total Depth (ft bgs) Screened Interval (ft bgs) TOC Elevation (ft msl) Groundwater Elevation (ft msl) Approximate Screened Interval (ft msl) Lithology of Screened Interval DTW (ft) February 9, 2016 DTW (ft) Groundwater Elevation (ft msl) Latitude LongitudeSurface Casing Depth (ft bgs) Table 2 Summary of Soil Analytical Data Former Knitronics Facility Cherryville, North Carolina H&H Job No. MOH-001 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\SoilGWAssessment\GWSoil Table 3/10/2016 Table 2 (Page 1 of 1) Hart & Hickman, PC Sample Location Adjacent to Wastewater Manhole Adjacent to Former PCE Washer Area Adjacent to Former PCE Washer Area Adjacent to Former PCE Washer Area East Portion Near Former Dye Area East Portion Near Former Dye Area Near Exterior Loading Dock Near Exterior Loading Dock Near Exterior Loading Dock AST Containment Area Sample ID SB-1 7-9'SB-2 15-17'SB-2 25-27'SB-3 7-9'SB-4 5-7'SB-4 27-30'SB-5 9-11'Dup-1 (SB-5 9-11')SB-5 25-27'SB-6 7-10 Depth (ft bgs)7-9 15-17 25-27 7-9 5-7 27-30 9-11 9-11 25-27 7-10 Sample Date 1/28/2016 1/28/2016 1/28/2016 1/28/2016 1/28/2016 1/28/2016 1/29/2016 1/29/2016 1/29/2016 1/29/2016 Protection of Groundwater Residential Industrial Range Mean Units (mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg) VOCs (8260B) Acetone <0.072 0.099 0.083 0.067 <0.066 <0.062 <0.064 <0.082 <0.057 <0.061 24 12,000 100,000 NS NS 1,1,1,2-Tetrachloroethane 0.020 <0.0089 <0.0082 <0.0059 <0.0066 <0.0062 <0.0064 <0.0082 0.0086 <0.0061 0.0059 2.0 8.8 NS NS 1,2,3-Trichlorobenzene 0.11 <0.0089 <0.0082 <0.0059 <0.0066 <0.0062 <0.0064 <0.0082 0.0064 <0.0061 NS 13 190 NS NS 1,2,4-Trichlorobenzene 0.11 <0.0089 <0.0082 <0.0059 <0.0066 <0.0062 <0.0064 <0.0082 0.013 <0.0061 2.2 12 52 NS NS 1,2-Dichlorobenzene 0.013 <0.0089 <0.0082 <0.0059 <0.0066 <0.0062 <0.0064 <0.0082 <0.0057 <0.0061 0.24 360 380 NS NS 1,4-Dichlorobenzene 0.0094 <0.0089 <0.0082 <0.0059 <0.0066 <0.0062 <0.0064 <0.0082 <0.0057 <0.0061 0.070 2.6 11 NS NS Chlorobenzene 0.0076 <0.0089 <0.0082 <0.0059 <0.0066 <0.0062 <0.0064 <0.0082 <0.0057 <0.0061 0.44 56 260 NS NS cis-1,2-Dichloroethene <0.0072 <0.0089 0.017 0.041 0.013 0.024 <0.0064 <0.0082 0.0078 <0.0061 0.36 32 460 NS NS Tetrachloroethene 57 5.4 0.92 7.1 1.8 2.9 0.072 0.049 1.9 0.056 0.0050 16 78 NS NS Trichloroethene 0.0090 <0.0089 <0.0082 0.0078 <0.0066 <0.0062 <0.0064 <0.0082 0.012 <0.0061 0.018 0.82 3.8 NS NS SVOCs (8270C) SVOC Analytes BRL BRL NA BRL BRL NA BRL BRL NA NA --------------- HSL Metals (6010C/7471B) Antimony 3.9 <0.38 NA <0.36 <0.33 NA <0.30 <0.40 NA NA 0.9 6.2 94 <1.0 - 8.8*0.76 Arsenic 2.7 1.5 NA 5.0 4.6 NA 5.5 7.7 NA NA 5.8 0.68 3 1.0 - 18 4.80 Beryllium <0.36 0.58 NA 0.59 0.97 NA 1.5 2.4 NA NA 63 32 460 ND-2.0 0.11 Chromium 16 6.0 NA 20 41 NA 32 42 NA NA 360,000 24,000 100,000 7.0-300 65 Copper 27 3.5 NA 14 40 NA 38 60 NA NA 700 620 9,400 3.0-100 34 Lead 11 42 NA 30 14 NA 30 42 NA NA 270 400 800 ND - 50 16 Manganese 99 570 NA 21 31 NA 78 240 NA NA 65 360 5,200 8.0-3,394 594 Mercury <0.026 <0.028 NA 0.036 0.036 NA <0.026 <0.030 NA NA 1 1.9 3.1 0.03-0.52 0.121 Nickel 4.3 20 NA 10 6.3 NA 6.2 8.5 NA NA 130 300 4,400 ND-150 23 Silver <0.36 <0.38 NA 0.37 0.66 NA 0.49 0.85 NA NA 3.4 78 1,200 ND - 5.0 NS Zinc 25 14 NA 14 21 NA 36 45 NA NA 1,200 4,600 70,000 500-50,000 7,800 Notes: 1) NC DEQ Inactive Hazardous Sites Branch (IHSB) Protection of Groundwater and Residential and Industrial Health Based Preliminary Soil Remediation Goals (PSRGs) - September 2015Range and Mean background values for North Carolina or Southeast soils taken from Elements in North American Soils by Dragun and Chekiri, 2005 * = Range and mean values of background metals for Southeastern USA soils. Method number follows parameter in parenthesis Bold concentration indicates exceedance of IHSB Protection of Groundwater PSRG (or exceedance of an IHSB PSRG and Background Range in the case of metals)Bold and highlighted concentration indicates exceedance of IHSB Residential PSRGVOCs = volatile organic compounds; SVOCs = semi-volatile organic compounds; HSL = Hazardous Substance List NA = Not Analyzed; BRL = Below Laboratory Reporting Limit; --- = Not Applicable; NS = Screening Criteria Not Specified IHSB PSRGs1 Screening Criteria Background* Table 3Summary of Groundwater Analytical Data Former Knitronics FacilityCherryville, North Carolina H&H Job No. MOH-001 S:\AAA-Master Projects\Mohican Mills - MOH\MOH-001 Knitronics\SoilGWAssessment\GWSoil Table3/10/2016 Table 3 (Page 1 of 1) Hart & Hickman, PC Sample ID MW-2S MW-2D MW-3S MW-3D Dup-1 (MW-3D)MW-4S MW-4D MW-5S MW-5D Field Blank Sample Date 2/5/2016 2/18/2016 2/5/2016 2/5/2016 2/5/2016*2/5/2016 2/5/2016 2/5/2016 2/5/2016 2/5/2016 2/5/2016 2/5/2016 Units (µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L) VOCs (8260B)Acetone <5.0 <5.0 <5.0 <5.0 <500 <5.0 <5.0 <5.0 6.7 <5.0 <50 <5.0 6,000 4,520,000 19,000,000 Chloroform <0.50 <0.50 <0.50 <0.50 <50 <0.50 <0.50 0.62 <0.50 <0.50 <5.0 <0.50 70 8.14 35.5 cis-1,2-Dichloroethene <0.50 <0.50 <0.50 <0.50 140 1.2 1.2 <0.50 <0.50 <0.50 <5.0 <0.50 70 NS NSTetrachloroethene97167.0 <0.50 120,000 460 450 17 95 11 1,700 <0.50 0.7 11.5 48.4 Toluene <0.50 <0.50 <0.50 <0.50 <50 <0.50 <0.50 <0.50 2.2 <0.50 <5.0 <0.50 600 3,840 16,100 Trichloroethene <0.50 <0.50 <0.50 <0.50 260 8.4 8.4 <0.50 <0.50 <0.50 5.5 <0.50 3 1.04 4.35Trichlorofluoromethane<0.50 <0.50 <0.50 3.7 <50 <0.50 <0.50 <0.50 <0.50 <0.50 <5.0 <0.50 2,000 36.8 155 RCRA Metals (6010C/7470A)Mercury NA NA NA NA <0.20 NA NA NA NA NA NA NA 1 NS NSArsenicNANANANA<10 NA NA NA NA NA NA NA 10 NS NS Barium NA NA NA NA 25 NA NA NA NA NA NA NA 700 NS NSCadmiumNANANANA<1.0 NA NA NA NA NA NA NA 2 NS NSChromiumNANANANA<5.0 NA NA NA NA NA NA NA 10 NS NS Lead NA NA NA NA <5.0 NA NA NA NA NA NA NA 15 NS NSSeleniumNANANANA<20 NA NA NA NA NA NA NA 20 NS NSSilverNANANANA<5.0 NA NA NA NA NA NA NA 20 NS NS Notes: Only those compounds detected in at least one sample shown above 1) 15A North Carolina Administrative Code 2L Groundwater Standards 2) Division of Waste Management Residential and Non-Residential Vapor Intrusion Groundwater Screening Levels* - RCRA Metals collected from MW-3S on 2/9/16 Bold indicates an exceedance of the NCAC 2L Standard Bold Italic indicates an exceedance of the NCAC 2L Standard and the Division of Waste Management Residential Vapor Intrusion Groundwater Screening Level. Bold Italic and highlighted indicates an exceedance of NCAC 2L Standard and the Division of Waste Management Residential and Non-Residential Vapor Intrusion Groundwater Screening Levels. Method number follows parameter in parenthesis VOCs = volatile organic compounds; RCRA = Resource Conservation and Recovery Act; NS = screening criteria not specified; NA = Not Analyzedµg/L = micrograms per liter 15A NCAC 2L1 DWM VI Non-Residential Groundwater Screening Level2 Screening Critera MW-1 DWM VI Residential Groundwater Screening Level2 SITE 0 2000 4000 APPROXIMATE SCALE IN FEET N U.S.G.S. QUADRANGLE MAP QUADRANGLE 7.5 MINUTE SERIES (TOPOGRAPHIC) WACO, NORTH CAROLINA, 1976 TITLE PROJECT SITE LOCATION MAP FORMER KNITRONICS 1515 WEST ACADEMY STREETCHERRYVILLE, NC DATE: JOB NO: REVISION NO: FIGURE: 3-8-16 0 1MOH-001 WSW-22 WSW-21 WSW-26 WSW-47 WSW-1 WSW-2 WSW-3 WSW-4 WSW-5 WSW-16 WSW-17 WSW-18 WSW-19 WSW-23WSW-25 WSW-6 WSW-7 WSW-28 WSW-29 WSW-30 WSW-31 WSW-32 WSW-35 WSW-36 WSW-37 A/B WSW-33 WSW-34 WSW-38 WSW-39 WSW-41 WSW-40 WSW-43 WSW-42 WSW-44WSW-46 WSW-45 WSW-48 WSW-61 WSW-20 P A U L H B E A M R O A D BROWN WAT E R S O N R O A D W. ACA D E M Y S T R E E T SHEL B Y H I G H W A Y L E S T E R S T R E E T GRO V E R O A D WESTGATE PARK TRIBUTARY OF MUDDY FORK CREEK WSW-8 WSW-9 WSW-10 WSW-14 WSW-15 WSW-24 WSW-27 GROUNDWATERIMPACTS DETECTED 2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 Geology JOB NO. MOH-001 REVISION NO. 0DATE: 3-8-16 FIGURE NO. 2 FORMER KNITRONICS FACILITY 1515 WEST ACADEMY STREET CHERRYVILLE, NC SITE VICINITY AND WATER SUPPLY WELL LOCATION MAPLEGEND SITE PROPERTY BOUNDARY WATER SUPPLY WELL OBSERVED CITY WATER NOT AVAILABLE; SUPPLY WELL LOCATION UNKNOWN PROPERTY ON CITY WATER;SUPPLY WELL NOT USED CITY WATER AVAILABLE ON STREET APPENDIX A Boring Logs and Well Construction Diagrams APPENDIX B Laboratory Analytical Reports Page 1 of 65 Page 2 of 65 Page 3 of 65 Page 4 of 65 Page 5 of 65 Page 6 of 65 Page 7 of 65 Page 8 of 65 Page 9 of 65 Page 10 of 65 Page 11 of 65 Page 12 of 65 Page 13 of 65 Page 14 of 65 Page 15 of 65 Page 16 of 65 Page 17 of 65 Page 18 of 65 Page 19 of 65 Page 20 of 65 Page 21 of 65 Page 22 of 65 Page 23 of 65 Page 24 of 65 Page 25 of 65 Page 26 of 65 Page 27 of 65 Page 28 of 65 Page 29 of 65 Page 30 of 65 Page 31 of 65 Page 32 of 65 Page 33 of 65 Page 34 of 65 Page 35 of 65 Page 36 of 65 Page 37 of 65 Page 38 of 65 Page 39 of 65 Page 40 of 65 Page 41 of 65 Page 42 of 65 Page 43 of 65 Page 44 of 65 Page 45 of 65 Page 46 of 65 Page 47 of 65 Page 48 of 65 Page 49 of 65 Page 50 of 65 Page 51 of 65 Page 52 of 65 Page 53 of 65 Page 54 of 65 Page 55 of 65 Page 56 of 65 Page 57 of 65 Page 58 of 65 Page 59 of 65 Page 60 of 65 Page 61 of 65 Page 62 of 65 Page 63 of 65 Page 64 of 65 Page 65 of 65 Page 1 of 49 Page 2 of 49 Page 3 of 49 Page 4 of 49 Page 5 of 49 Page 6 of 49 Page 7 of 49 Page 8 of 49 Page 9 of 49 Page 10 of 49 Page 11 of 49 Page 12 of 49 Page 13 of 49 Page 14 of 49 Page 15 of 49 Page 16 of 49 Page 17 of 49 Page 18 of 49 Page 19 of 49 Page 20 of 49 Page 21 of 49 Page 22 of 49 Page 23 of 49 Page 24 of 49 Page 25 of 49 Page 26 of 49 Page 27 of 49 Page 28 of 49 Page 29 of 49 Page 30 of 49 Page 31 of 49 Page 32 of 49 Page 33 of 49 Page 34 of 49 Page 35 of 49 Page 36 of 49 Page 37 of 49 Page 38 of 49 Page 39 of 49 Page 40 of 49 Page 41 of 49 Page 42 of 49 Page 43 of 49 Page 44 of 49 Page 45 of 49 Page 46 of 49 Page 47 of 49 Page 48 of 49 Page 49 of 49 Page 1 of 7 Page 2 of 7 Page 3 of 7 Page 4 of 7 Page 5 of 7 Page 6 of 7 Page 7 of 7 Page 1 of 11 Page 2 of 11 Page 3 of 11 Page 4 of 11 Page 5 of 11 Page 6 of 11 Page 7 of 11 Page 8 of 11 Page 9 of 11 Page 10 of 11 Page 11 of 11