WS-7551_30907_CA_OTH_20240324_soil Sampling

F.BRYAN BRICE,JR.
CATHERINECRALLE JONES
ANDREA C.BONVECCHIO
NEIL K.SANYAL
ROBERTR.GELBLUM,OF COUNSEL
LAW OFFICES OF
F.BRYAN BRICE,JR.
April 3,2024
130 S SALISBURY ST.
RALEIGH,NC 27601
TEL:[phone]
FAX:[phone]
WWW.ATTYBRYANBRICE.COM
Ragsdale Brothers,LLC
Attn:William G.Ragsdale,IV;Seborn Ragsdale
3401 Healy Drive
Winston Salem,NC 27103
Sent via USPS and via electronic mail to:[e-mail]
and [e-mail]
RE:Follow-Up Regarding Unreported Underground Storage Tank (UST)
and Related Contamination Issues Located at 302 E.Main St.,
Jamestown,NC (PIN 7821384974)
Dear Mr.Ragsdale:
This letter serves as a follow-up to our December 7,2023,letter and discussions
concerning contamination resulting from unreported and past underground storage tank ("UST")
breaches on your property located at 302 E.Main St.As you know,our office has been retained
by Mr.George Ragsdale,who owns property adjacent to and directly downgradient from 302 E.
Main St.As previously communicated to you,our client is concerned about contamination on his
property due to known historical releases of petroleum and other pollutants emanating from your
property.Recent findings have raised additional concerns about undisclosed activities prior to
and during the construction of Black Powder Smokehouse.
Our client has expended considerable time and resources related to understanding the
extent ofthe contamination migrating from your property onto his property.Attached,as Exhibit
A,is a limited Phase II Environmental Site Assessment ("ESA")report prepared by Waters Edge
Environmental,LLC,which documents the results of recent groundwater sampling and site
investigations.
To date,you have denied knowledge of contamination from past and remaining USTs on
your property,or efforts to conceal the same,during Black Powder Smokehouse's construction.
Given the results of recent testing on our client's property,this follow-up letter is offered as a
final good faith attempt to resolve potential legal claims related to the environmental issues
described herein and outlined in the attached report.
I.Contamination of Our Client's Property is Inextricably Linked to 302 E.Main Street.
The attached Phase II ESA report shows that petroleum hydrocarbons such as benzene
were found on our client's property and in groundwater monitoring wells at concentrations above
those permitted by the N.C. Administrative Code 2L Groundwater Standards.No onsite sources
of petroleum impact were identified on our client's property;however,as summarized in our
December 2023 letter and further detailed in the attached report,the 302 E.Main St.property has
an extensive documented record of significant petroleum releases and contamination at
concentrations surpassing designated action levels.
Furthermore,there is no historical evidence of petroleum product usage on our client's
property.However,documented evidence points to impacted up-gradient monitoring wells and
significant soil volumes containing petroleum constituents on the 302 E.Main St.property.
Based on this data,the Phase II ESA findings validate that the source of our client's onsite
petroleum impact stems from past and ongoing releases on your property,resulting in migration
to our client's property and contamination of the subsurface with pollutant levels exceeding
regulatory thresholds.Compare 15A NCAC 2L.0202 (designating standard for benzene at 1
Jlg/L)with Exhibit A (identifying exceedance for benzene at 9.6 Jlg/L).
II.Claims Related to Past and Ongoing Environmental Contamination of Our Client's
Property.
As explained in our December 2023 letter,deliberately concealing a breached UST during
the construction of Black Powder Smokehouse and failing to make any reasonable efforts to stop
or mitigate migrating contaminants from your property gives rise to claims of trespass,nuisance,
negligence,negligence per se,and violations of the Oil Pollution and Hazardous Substances
Control Act ("OPHSCA"),among others.
The ongoing and recurrent contamination flowing from your property to our client's
adjacent agricultural land constitutes both trespass and nuisance,as affirmed in legal precedents
such as Wilson v.McLeod Oil Co.,327 N.C.491,511,398 S.E.2d 586,596 (1990),and Ruddv.
Electrolux Corp.,982 F.Supp.355,369 (M.D.N.C.1997).As the current property owner,it's
imperative to take immediate action to abate the flow of contaminants onto our client's property
and remediate all remaining contamination to prevent further trespass and mitigate any potential
further harm.
Furthermore,North Carolina's General Assembly has expressed a clear intent to provide
broad protection of the land and waters of North Carolina from pollution.Since elevated levels
of regulated substances have been detected and linked to property owned by Ragsdale Brothers,
LLC,it is strictly liable under OPHSCA,without regard to fault,for damages to our client's
property caused by the entry of hazardous substances.An obligation under the statutory scheme
of OPHSCA and the claims detailed herein exists to contain, control,remove,and maintain
contaminants in such a manner as to prevent the further migration of hazardous substances.As
the current property owner,Ragsdale Brothers,LLC bears responsibility for remediating and
mitigating the groundwater contaminants affecting our client's property.See N.C.Gen.Stat.§
143-215.93 (providing for liability for damage caused by oil or other hazardous substances).
In light of the issues described herein,we request a meeting at your earliest convenience
to address these and other concerns.Ifwe cannot resolve this amicably,and soon,we will initiate
legal proceedings in Guilford County Superior Court.Additionally,we will contact local and
2
state regulators,including the Guilford County Health Department and the NCDEQ to apprise
them of these issues ifwe cannot resolve them.
We look forward to hearing from you.Please do not hesitate to call if you have any
immediate questions or concerns.
Sincerely,
Enclosure(s)
3

EXHIBIT A
January/February 2024 Limited Phase II Environmental Site Assessment George Ragsdale Property 304 E. Main Street Jamestown, North Carolina March 28, 2024 Lat 35.99659 N Long -79.93434 W
Prepared For
Mr. George Wrenn Ragsdale B. R. Foxx & Company 404 East Main Street Jamestown, NC 27282
Prepared By
Mr. Phillip Rahn P.G. #386-RSM #94 Waters Edge Environmental, LLC 1434 Chester Road
Raleigh, North Carolina 919.219.5820

1434 CHESTER ROAD • RALEIGH, NC 27608 • PHONE [phone]
March 28, 2024

Mr. George Wrenn Ragsdale
B. R. Foxx & Company 404 East Main Street Jamestown, NC 27282
Reference: January/February 2024 Limited Phase II Environmental Site Assessment George Ragsdale Property
304 E. Main Street Jamestown, North Carolina 27565
Waters Edge Job No. R23-56 Dear Mr. Ragsdale: Based on a request by Mr. George Ragsdale, Waters Edge conducted a limited Phase II ESA at the
above-mentioned property. The following report documents the results of our groundwater sampling investigation and presents our conclusions and recommendations for the property. There was an exceedance of NC 2L Groundwater Standards for benzene in one of the temporary
groundwater monitoring wells.

Waters Edge appreciates the opportunity to provide environmental consulting services to B.R. Foxx & Company. If you have any questions regarding the information contained herein, please do not hesitate to contact our office at 919.219.5820.
Sincerely, WATERS EDGE ENVIRONMENTAL, LLC
Phillip L Rahn, P.G.
President

24-027/PLR/aht

Table of Contents
1 Introduction 1
2 January/February 2024 Limited Phase II ESA Investigation 2 2.1 January 2024 Soil and Groundwater Assessment 2
2.2 February 2024 Groundwater Assessment 3
3 January/February 2024 Soil and Groundwater Assessment Conclusions and Recommendations 4
Figures
1 Project Location Map
2 Site Location Map with NC 2L Exceedances

Tables
1 Groundwater Analytical Results

Appendix A Summary of Laserfiche Findings – 302 E Main Street
B SOPs
C Borelogs
D Laboratory Analytical Results
E Photograph

Acronym List

BGS Below Ground Surface

DEQ Division of Environmental Quality
ESA Environmental Site Assessment
LSA Limited Site Assessment ND Non-detect
NFA No Further Action
NORR Notice of Regulatory Requirements
NOV Notice of Violation NRP Notice of Residual Petroleum
PID Photoionization Detector PWR Partially Weathered Rock

SSE Site Sensitivity Evaluation
SOP Standard Operating Procedure
SVOCs Semivolatile Organic Compounds TPH Total Petroleum Hydrocarbons
UST Underground Storage Tank
VOCs Volatile Organic Compounds

Page 1 of 4
January/February 2024 Limited Phase II Environmental Site Assessment George Ragsdale Property 304 E. Main Street
Jamestown, North Carolina 27565 March 28, 2024 1 Introduction

There is a concern that topographically upgradient petroleum USTs on an abutting property may have had releases which could have impacted the subject property located at 304 E. Main Street. Waters Edge researched the abutting property at 302 E. Main Street on the
NCDEQ Laserfische website. Below is a list of highlighted activities (see more detailed activities in Appendix A):
• 1960s - Tank 1 (5,000-gallon), Tank 2 (3,000-gallon) and Tank 3 (3,000-gallon
were installed, all gasoline; however, there is some information in the files that there may have been previous UST on the parcel before this date (see timeline in Appendix A).
• 1986 - Tank 4 and Tank 5 were installed.
• February 1994 - 10.000-gallon UST installed
• March 14, 1994 - Precision Environmental removed UST Tanks 1-3.
• October 1994 - R&A Environmental Assessment Phase 1 (B-1 soil sample and
observation well)
• November 30, 1994 - R&A Environmental Assessment Phase 2 (B-2 detected 698
ppm (mg/kg) TPH reported as gasoline. SSE later determined a site specific remediation threshold of 240 mg/kg TPH.
• June 21-22, 1995 - Soil Excavation for Contaminated Soil
• July 12, 1995 - Tanks 4 and 5 Removed (minor contamination found, excavated, and “no impacted soil remains”)
• July 19, 1995 - UST System Closure and Soil Remediation Report - B.J. Hughes Service (Fac. No. 0-017559) dated July 19, 1995 conducted by Mr. Andrew Raring This report documents that Hughes Service Station had five (5) USTs removed along with impacted soil. Two of the USTs (1,000-gallon kerosene and diesel),
referenced as tanks 4 and 5, were located on the eastern property line which abuts the subject property. Tanks 4 and 5 were removed on July 12, 1995. Some soil was excavated for the first three UST removals in 1994, but we found no indications of
the volume of soil. Based on additional soil assessment discussed in this closure
report, there was reportedly additional excavation below UST #2 located north of
service bay building. The excavation area was listed as being L-shaped with dimensions of 16’(L) x 16’ (W) x 16’ (D) with the L appendage being 8’ (L) x 6’ (W) x 14’ (L). This would roughly be the equivalent to 176 cubic yards or 265 tons
(1.5 conversion factor). Soil was reportedly removed based on a SSE risk based TPH cleanup threshold set at 240 mg/kg. No groundwater sampling was conducted since they encountered PWR at 30’ bgs and reportedly two monitoring wells installed were dry.
• August 15, 1995 - DEHNR correspondence to BJ Hughes indicating UST System Closure determined complete. Does not absolve any contamination.
January/February 2024 Limited Phase II Environmental Site Assessment George Ragsdale Property Jamestown, North Carolina 24-027 March 28, 2024

Page 2 of 4
• 2006 Trigon Engineering conducted a Phase II ESA (No Report Found on
Laserfiche but provided later by Mr. George Ragsdale. Detected soil contamination from the former 5,000 gallon UST as well as the AST area and hydraulic oil lift area.)
• January 2007 – Two Waste oil UST tanks were removed. 24-Hour Release Form
submitted.
• Limited Site Assessment dated February 19, 2007
• Soil Remediation for Hydraulic Oil Release dated October 5, 2007 by Paragon
• Soil Cleanup Report dated October 8, 2007 conducted for Hughes Enterprises by Paragon Environmental Consultants - This report detailed the removal of two (2) waste oil USTs listed as 1,000-gallon and 560-gallon located on the south side of the Main Building. It reported that 51 cubic yards or 71.42 tons were excavated in
the waste oil UST area. NCDEQ issued a NFA correspondence on October 16, 2007.
• NRP filed on October 11, 2007. On October 16, 2007 - Notice of NFA
• Based on a May 31, 2019 24-Hour Release Report, “A UST was removed on May 14, 2019.” This is assumed to be the remaining 10,000-gallon UST. NCDEQ issued a July 15, 2019 response indicating the site could be considered for a NRP and receive a conditional NFA.
• The facility did file a NRP on July 15, 2019 and NCDEQ issued a NFA correspondence on August 30, 2021. To investigate conditions on the subject property, Waters Edge was authorized to install up
to three temporary groundwater monitoring wells on the subject property owned by Mr. Ragsdale and conduct both soil and groundwater assessment activities. Herein is contained an account of our field investigation, laboratory analytical results and our conclusions and
recommendations.

2 January/February 2024 Limited Phase II ESA Investigation
2.1 January 2024 Soil and Groundwater Assessment On January 24, 2024, Waters Edge mobilized to the site with a senior environmental technician, a Geoprobe, a PID, and a peristaltic pump. Two (2) borings (B-1 and B-2) were
located in the field at locations shown in Figure 2. A third boring was located further south of B-2; however, we were ultimately unable to install that boring due to the proximity of a
municipal water line in that area. City of Jamestown municipal employees instructed Waters Edge to discontinue drilling. We would add that we had contacted No Cuts, but
they did not arrive to do their investigation until the day of the drilling. As such, the third temporary groundwater monitoring well was not installed.
January/February 2024 Limited Phase II Environmental Site Assessment George Ragsdale Property Jamestown, North Carolina 24-027 March 28, 2024

Page 3 of 4
Both borings were located topographically downgradient of where we initially understood
the offsite UST was located. Through additional research it was determined that there were many additional USTs that had been removed from the abutting upgradient property. Both
borings were assessed in the field with a PID. There were no detectable readings, so we did not collect any soil samples for laboratory corroboration. The borings were advance to
29’ bgs at B-1 and 27’ bgs at B-2 which could not be advanced any deeper due to encountering PWR. A temporary well was installed in each boring at 29’ bgs for B-1 and 27’ bgs at B-2. Each well had 10’ of screening followed by blank casing to the ground surface. Formation stabilized was introduced in the annular space outside of the screen
and the borehole to approximately 2’ above the screen section. On January 24, 2024, temporary well B-1 was sampled with a peristaltic pump using low
flow techniques. B-2 was dry and could not be sampled. We returned on January 29, 2024
after a rainfall event and were able to collect a limited amount of sample volume. The
samples were submitted to the laboratory according to EPA accepted procedures and analyzed for the following:
• VOCs according to either Method 6200 or 8260D to obtain the lowest reporting
limits.
• SVOCs according to Method 8270E (B-1 only since only a limited volume could
be collected from B-2)
• MADEP VPH/EPH (B-1 only since only a limited volume could be collected from B-2)
SOPs are described in Appendix B, borelogs are contained in Appendix C, analytical results are summarized in Table 1 and documented in Appendix D. There were no
exceedances of NC 2L Groundwater Standards. Benzene was detected at 1.0 µg/L which is the actual NC 2L Standard, therefore it did not exceed the standard.
2.2 February 2024 Groundwater Assessment On February 29, 2024, Waters Edge remobilized to the site with a senior environmental
technician and a peristaltic pump. Both B-1 and B-2 were sampled again using low flow techniques. The samples were submitted to the laboratory according to EPA accepted procedures and analyzed for the following:

• VOCs according to 8260D to obtain the lowest reporting limits
• SVOCs according to Method 8270E
• MADEP VPH/EPH (B-1 could only be sampled for MADEP VPH since only a
limited volume could be collected from B-2)
SOPs are described in Appendix B, analytical results are summarized in Table 1 and documented in Appendix C. There was one NC 2L Groundwater Standard exceedance for
January/February 2024 Limited Phase II Environmental Site Assessment George Ragsdale Property Jamestown, North Carolina 24-027 March 28, 2024

Page 4 of 4
benzene at 9.6 µg/L versus a NC 2L Standard at 1.0 µg/L. All remaining constituents were
either ND or below NC 2L Standards.
Subsequent to sampling, both temporary wells were abandoned by removing the surficial casing, filling the boring with pelletized bentonite followed by hydration.
3 January/February 2024 Soil and Groundwater Assessment Conclusions and Recommendations
We have the following conclusions and recommendations:
• Based on the field readings, we would conclude the unsaturated soil on the subject property is not adversely impacted.
• The detection of benzene above its NC 2L Standard in groundwater would constitute a release or discharge under the Oil Pollution and Hazardous Substance Control and Discharge Act - Discharges 143-215.83 that is reportable to the NCDEQ-Winston-Salem Regional Office. At this point in time, we would have to
conclude the upgradient property, which is the former Hughes Service Station located at 302 E. Main Street and owner of numerous former USTs/ASTs would be considered the Responsible Party.
• The upgradient property has what appears to be several separate UST release
incidents at 302 E. Main Street. It appears they all have either received a NFA determination or more than one NRP with a NFA determination. In light of the recent discovery of impacted groundwater at 304. E. Main Street, we would
conclude the NCDEQ incident manager needs to be contacted in order to determine whether additional assessment needs to be conducted on the 304 E. Main Street
subject property and the NRP potentially reopened. Further assessment would be conducted according to the NCDEQ UST Assessment and Cleanup Guidance.
• If feasible, Waters Edge would conclude that at least one additional well needs to be installed south of B-2. Due to the shallow PWR, this well and potentially B-2
needs to be installed to a deeper total depth with an air rotary drill rig since the water column in B-2 was limited. If there is still an open groundwater monitoring
well on the 302 E. Main Street property, it may help if that was assessed to determine the existing conditions of the groundwater on that property.
Figures
Job No.Topo Quad Date Title
R23-56 Guilford/High Point E 3.20.2024
File Name Figure Scale Project
24-027 1 unknown
Project Location Map
SITE
WATERS EDGE ENVIRONMENTAL, LLC
Job No.Image/Photo Date Title
R23-56 Guilford Co GIS 3.20.2024
File Name Figure Scale Project
24-027.xls 2 bar scale shown
WATERS EDGE ENVIRONMENTAL, LLC
LEGEND
Jan 2024 Soil Boring/Temp MW Location
Topographic Slope
Former UST Areas (per past reports)
Former Waste Oil USTs (1,000 gal & 560 gal)
Waste Oil AST (per Trigon Phase II 2006)
Area of Hydraulic Oil Release (per past report)
AST (per Trigon Phase II 2006)
ID UST DESCRIPTION
1 5,000 gallon Gasoline
2 3,000 gallon Gasoline
3 3,000 gallon Gasoline
4 1,000 gallon Diesel
5 1,000 gallon Kerosene
6 10,000 gallon Gasoline
2.29.24
B-1 GW Results
Benzene-9.6 µg/L vs. NC 2L at 1.0 µg/L

Tables
Table 1
Groundwater Analytical Results
304 E. Main Street
Jamestown, North Carolina
Soil Sample Location:Method Units 2L B-1 B-1 B-2 B-2
Sample Date:m/d/y -1.24.24 2.29.24 1.29.24 2.29.24
Volatile Organic Compounds *
Acetone 8260D µg/L 6000 <25 26.9 <25 <25
Benzene 8260D µg/L 1.0 1.0 9.6 <1.0 <1.0
sec-Butylbenzene 8260D µg/L 70 1.3 NA NA NA
Diisopropyl Ether 8260D µg/L 70 5.1 5.2 <1.0 <1.0
MTBE 8260D µg/L 20 4.0 4.0 <1.0 <1.0
Toluene 8260D µg/L 600 <1.0 1.1 <1.0 <1.0
Total VOCs µg/L NS 11.4 46.8 ND ND
Semivolatile Organic Compounds- Method 8270E
Total SVOCs 8270E ug/L NS ND ND NA ND
MADEP Volatile Petroleum Hydrocarbons*
C5-C8 Aliphatics MADEP µg/L -<100 138 NA <100
C9-C12 Aliphatics MADEP µg/L -<100 <100 NA <100
C9-C10 Aromatics MADEP µg/L -<100 <100 NA <100
MADP Extractable Petroleum Hydrocarbons *
C9-C18 Aliphatics MADEP µg/L -<100 <98 NA NA
C19-C36 Aliphatics MADEP µg/L -199 <98 NA NA
C11-C22 Aromatics MADEP µg/L -<100 <98 NA NA
MADEP VPH & EPH Totals
Total C5-C8 Aliphatics MADEP µg/L 400 ND 138 NA ND
Total C9-C18 Aliphatics MADEP µg/L 700 ND ND NA NA
Total C19-C36 Aliphatics MADEP µg/L 10,000 199 ND NA NA
Total C9-C22 Aromatics MADEP µg/L 200 ND ND NA NA
Notes:
NS - No Standard Available
NA - Not Analyzed
ND - Not Detected
Bold font represents exceedance
* The 1.24.24 VOC Analysis for B-1 was conducted via both Methods 6200 and 8260D. The highest concentration
is depicted in the table

Appendix A
Appexdix A
Summary of Findings - NC Laserfiche File Research
Hughes Service Station
302 E Main Street, Jamestown, North Carolina
Date of Site
Activity
Correspondence
Date From To Description
1919-1920 Filling Station Built (per interview in WFMY2 News).
Existance of USTs not documented but the possibility exist.
1952 BJ Hughes began operating the service station at 302 E. Main Street.
1958 BJ Hughes purchased 302 E. Main Street Property
1960s Gasoline Tank 1 (5,000 gal), Tank 2 (3,000 gal) and Tank 3
(3,000 gal) installed
1986 Tanks 4 & 5 installed
7/21/1992 Register of Deeds Michael Hughes, Daniel Hughes, Dana Hughes & Rita Hughes
granted ownership of 302 E. Maint Street.
12/10/1993 BJ Hughes DEHNR Letter - Intent to remove 3 Gasoline USTs.
February 1994 10,000 gallon, three companrtment UST installed
2/10/1994 Precision Env DEHNR 30-Day Notice of Tank Closure
2/16/1994 DEHNR BJ Hughes Notification of Tank Closure Received
3/14/1994 Precision Environmental Removed Tanks 1-3 (two 3,000 gal UST and
one 5,000 gal UST) Contamination found.
3/15/1994 Handwritten letter saying tanks were pulled without notification.
Reported to fire chief by a citizen.
3/15/1994 Precision Env Fire Inspector Application to remove UST (late)
4/6/1994 Precision Env UST Closure Report (contamination confirmed)
June 1994 10,000 gallon UST in service
Appexdix A
Summary of Findings - NC Laserfiche File Research
Hughes Service Station
302 E Main Street, Jamestown, North Carolina
Date of Site
Activity
Correspondence
Date From To Description
6/13/1994 DEHNR BJ Hughes NOV - Failure to submit site investigation results following closure
July 1994 Precision Env UST Closure Report Filed (Contamination Tanks 1 and 2)
7/7/1994 DEHNR File Pollution Incident / UST Leaking Form (Removal of Tanks 1-3)
7/13/1994 DEHNR BJ Hughes NORR - Standard Notification Confirming Release
7/13/1994 Guilford Co Health BJ Hughes Site Sensitivity Evaluation Required
September 1994 UST Compliance Inspection
9/6/1994 DEHNR BJ Hughes Request for Financial Information
9/13/1994 R & A Env Guilford Co Healt Proposed Assessment/Remediation Activities
10/24/1994 NC DEM BJ Hughes NOV (4 violations)
ctober 12 or 20 R & A Environmental Assessment (B-1 at Tank 2 location and
Observation Well) Phase I Assessment
11/7/1994 R&A Env BJ Hughes Site Assessment Activities Report (recommends remediation and/or
sampling)
11/30/1994 R & A Environmental Assessment (B-2 detected 698 ppm TPH
gasoline) Phase 2 Assessment
12/1/1994 R & A Env BJ Hughes Addendum to Report of Site Assement Activities
2/28/1995 DEHNR BJ Hughes NOV - Failure to report CSA after 7.13.1994 NORR
6/10/1995 Andrew Raring DEHNR Letter - Application to Move Petroleum Contamimated Soil (Tank 2)
Appexdix A
Summary of Findings - NC Laserfiche File Research
Hughes Service Station
302 E Main Street, Jamestown, North Carolina
Date of Site
Activity
Correspondence
Date From To Description
6/19/1995 Teague Pump DEHNR GW/UST-3 Notice of Intent to Permanently Close UST
(Tank 4 Diesel & Tank 5 Kerosene)
6/21/1995 Shuying Wang Granted Approval to dispose soils (Tank 2)
une 21-22, 1995 Soil Excavation for Contaminated Soil at Tank 2
7/7/1995 DEHNR BJ Hughes Acknowledge Receipt of Notification of Tank Closure
7/10/1995 Teague Pump Fire Inspector UST Removal Application (Tanks 4 & 5) / Permit Granted
7/12/1995 Tanks 4 and 5 Removed (minor contamination found, excavated,
no impacted soil remains from 4 & 5)
7/19/1995 Andrew Raring Teague Pump UST Closure & Soil Remediaiton Report
8/4/1995 DEHNR File Pollution Incident / UST Leaking Form (July 12, 1995 removal
activities)
8/7/1995 Guilford Co Health DEHNR Memo - Site closed after soil contamination remediated
8/15/1995 DEHNR BJ Hughes Letter - UST System Closure determined complete. Does not absolve
any contamination.
5/19/2006 Trigon Engineering Phase I ESA
September 2006 Trigon conducted Phase II investigation activities.
2006 Trigon Engineering Phase II ESA (Soil contamination was detected. Should be reported.)
December 2006 USTs last in Operation
1/4/2007 Paragon DENR Notice of Intent: UST Permanent Closure (2 Waste Oil Tanks)
Appexdix A
Summary of Findings - NC Laserfiche File Research
Hughes Service Station
302 E Main Street, Jamestown, North Carolina
Date of Site
Activity
Correspondence
Date From To Description
Early January Hydraulic Lift Removed
1/10/2007 Waste Oil UST Tanks Removed (one 560 gallon & one 1,000 gallon -
previously stated two 550 gallon)
1/10/2007 Removal of waste oil impacted soil & gasoline impacted soil
identified in 2006 Phase II ESA
1/10/2007 UST Closure Inspection (Waste Oil) - Strong odor from soil beneath
tanks
1/17/2007 Meritech Analytical Report
1/19/2007 MW-1 and MW-2 Installed
1/26/2007 DENR File Pollution Incident File Created
1/26/2007 Paragon DENR 24-Hour Release and UST Leaking Form (Waste Oil)
1/30/2007 DENR Hughes EnterprisesAcknowledge receipt of 24-Hour Form - LSA Due
2/5/2007 Paragon Hughes EnterprisesUST Closure and 20-Day Report
2/19/2007 Paragon Hughes EnterprisesLimited Site Assessment (GW above 2L not GCL)
2/13/2007 DENR Hughes EnterprisesAcknowledge receipt of UST Closure and 20-Day Report - LSA Due
3/6/2007 DENR Hughes EnterprisesNORR - Notice of Residual Petroleum be filed with Register of Deeds
6/29/2007 Register of Deeds Ragsdale Brothers, LLC granted ownership of 302 E Main Street
9/18/2007 OK Enterprises and Paragon removed remaining petroleum impacted
soil.
Appexdix A
Summary of Findings - NC Laserfiche File Research
Hughes Service Station
302 E Main Street, Jamestown, North Carolina
Date of Site
Activity
Correspondence
Date From To Description
10/5/2007 Paragon George Ragsdale Soil Remediation for Hydraulic Oil Release
10/8/2007 Paragon Ragsdale Brothers Soil Cleanup Report (Request NFA)
10/16/2007 DENR Hughes EnterprisesNotice of NFA (GW Restricted)
10/18/2007 Paragon Guilford Co Healt Notice of NFA. NRP filed with Guilford County for one of first three
UST (possibly Tank 2)
10/31/2007 Paragon Guilford Co Healt Public Notification Return Receipts
5/14/2019 UST Removed (Assuming 10,000 gallon remaining tank. Soil
contamination found.)
5/31/2019 Paragon 24-Hour Release
6/10/2019 NCDEQ Hughes EnterprisesNORR - LSA Risk-Based Assessment & Corrective Action
June 2019 DEQ DWM
UST Closure Report/Site Closure Report (Report not found on
Laserfiche. Soil Contamination Exceeds MSCC and GW exceeds
standards)
7/15/2019 NCDEQ Ragsdale Brothers Conditional Notice of NFA
7/15/2019 Register of Deeds Notice of Residual Petroleum filed Guilford County Register of Deeds
8/30/2021 NCDEQ Ragsdale Brothers Notice of NFA (Also confirms GW contamination and water not for
use as water supply)

Appendix B

Waters Edge Environmental, LLC.
Standard Procedures: February 2001
Geoprobe ™ Sample Collection

he Geoprobe ™ consists of a truck-mounted hydraulic system with a stainless
steel sampling probe that is directly pushed into the subsurface. The sampling
probe is made up of a stainless steel hollow core body with an internal Teflon
™ or polyethylene sample liner. Once the probe has been advanced to the
desired depth, a dummy tip is withdrawn from the core body. The sample is collected by
advancing the opened core body over a discrete interval, thereby filling the sample liner
with soil. The probe is subsequently withdrawn from the boring, and the liner containing
the soil sample removed and opened. Once the soil has been retrieved from the liner,
each soil sample may be split into two portions; one portion designated for headspace soil
gas screening to determine the presence, and the second portion transferred to a 100-ml
pre-cleaned glass jar, designated for potential laboratory analysis.
Headspace Screening:
Soils are typically screened with an organic vapor analyzer (OVA) for total volatile organic compounds
(VOCs), which may indicate organic or petroleum hydrocarbon contamination. A typical procedure for
screening soils involves filling a clean container (e.g., glass jar or plastic baggie) approximately halfway
with soil and sealing the container. This creates a headspace in which the VOCs in the soil accumulate and
equilibrate. After allowing approximately 10 to 15 minutes for this process to occur, the probe of the OVA
is inserted through the container’s seal into the headspace of the container to obtain a VOC reading.

Soil Sample Collection for Analysis:
Geoprobe ™ soil samples selected for laboratory analysis are placed into pre-cleaned containers supplied
by the laboratory for the analysis proposed for the particular site. The jars are the labeled appropriately
with the sampler’s name, date of collection, sample number, analysis to be preformed, and project
designation before being stored and transported to the analytical laboratory in an insulated cooler chilled to
approximately 4.0 oC. To ensure sample integrity, all samples are transported in accordance with EPA
chain-of-custody protocols. All samples are typically transported to the laboratory within 48 hours of
sample collection, if possible.

Geoprobe ™ Groundwater Sample Collection:
Groundwater samples are collected directly from the Geoprobe ™. During the sampling event, the sampler
is typically pushed to the desired depth with a screened unit sealed inside the sampler. At the desired
sampling depth, the screen is exposed by retracting the push rod. Once the open sampler fills with
groundwater, we use a peristaltic pump attached to either Teflon of polyethylene tubing which is advanced
inside the drill rods to the desired depth. During the purging process, we will typically initially purge until
the sample aliquot is relatively free of sediment. We then use low flow methodologies to collect field
parameter readings (pH, conductivity and temperature) and ultimately collect a sample for laboratory
analysis. During the purging process, we attempt to achieve repeat readings within 5% before collecting a
laboratory sample. The only exception to this methodology is if it appears that the boring is going dry
which would prevent obtaining any sample. If we believe the boring will purge to dryness, we will
immediately collect a sample.
All groundwater samples are decanted into laboratory provided containers appropriate for the parameters
being analyzed, preserved as required by the analytical technique, and labeled with the following
information: sampler’s name, date of collection, sample number, analysis to be preformed, and project
designation. Samples are stored and transported to the analytical laboratory in an insulated cooler chilled to
approximately 4.0 oC. To ensure sample integrity, all samples are transported in accordance with EPA
chain-of-custody protocols. All samples are typically transported to the laboratory within 48 hours of
sample collection, if possible.
Appendix C
Well Construction Permit Number N/A
I. D. Number Purpose
Project Name Contractor
Project No.Registration No.
Geologist Driller
Start Date 1.24.24 Complete Date 1.24.24 Equipment
Drilling Method:
Comments Lat 35 degrees 59' 48"N/Long 79 degrees 56' 04"W
FID / PID
Well Construction Depth (ppm)
Information From - To Soil / Rock Description / Comments @ Depth (ft.)
Borehole Dia.2"0-0.2'0
Riser Type PVC 0.2-5.0'0
Diameter 1"5.0-10.0'0
Screen Type PVC 10-15'0
Diameter 1"15-20'0
Riser Interval 0-19'20-27'0
Screen Interval 19-29'27-29'0
Slot Size 10 Slot
Grout Type N/A
Interval N/A
Bentonite Type N/A
Interval N/A
Filter Pack Sand
Interval 17-29'
Total Depth 29'
R.P. Elevation N/A
Datum
Date W.L. Below R.P.
27.43'
R.P. = Reference Point W.L. = Water Level TBM = Temporary Benchmark MSL = Mean Sea Level
Refer to Standard Well Construction Schematic Type II - Style 1.
Boring / Well Construction Log
Waters Edge Doc-24-027 304 S. Main St-Jamestown Report, Page1
Well Construction Permit Number N/A
I. D. Number Purpose
Project Name Contractor
Project No.Registration No.
Geologist Driller
Start Date 1.24.24 Complete Date 1.24.24 Equipment
Drilling Method:
Comments Lat 35 degrees 59' 48"N/Long 79 degrees 56' 04"W
FID / PID
Well Construction Depth (ppm)
Information From - To Soil / Rock Description / Comments @ Depth (ft.)
Borehole Dia.2"0-0.2'0
Riser Type PVC 0.2-5.0'0
Diameter 1"5.0-10.0'0
Screen Type PVC 10-15'0
Diameter 1"15-20'0
Riser Interval 0-17'20-27'0
Screen Interval 17-27'
Slot Size 10 Slot
Grout Type N/A
Interval N/A
Bentonite Type N/A
Interval N/A
Filter Pack Sand
Interval 15-27'
Total Depth 29'
R.P. Elevation N/A
Datum
Date W.L. Below R.P.
Moist at 25'
R.P. = Reference Point W.L. = Water Level TBM = Temporary Benchmark MSL = Mean Sea Level
Refer to Standard Well Construction Schematic Type II - Style 1.
Boring / Well Construction Log
Waters Edge Doc-24-027 304 S. Main St-Jamestown Report, Page1

Appendix D
#=CL#
February 05, 2024
LIMS USE: FR - PHIL RAHN
LIMS OBJECT ID: 92710045
92710045
Project:
Pace Project No.:
RE:
Mr. Phil Rahn
Waters Edge Environmental
1434 Chester Road
Raleigh, NC 27606
R23-56
Dear Mr. Rahn:
Enclosed are the analytical results for sample(s) received by the laboratory on January 25, 2024. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace National - Mt. Juliet
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
Project Manager
704-977-0942
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 1 of 34
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92710045
R23-56
Pace Analytical Services National
12065 Lebanon Road, Mt. Juliet, TN 37122
Alabama Certification #: 40660
Alaska Certification 17-026
Arizona Certification #: AZ0612
Arkansas Certification #: 88-0469
California Certification #: 2932
Canada Certification #: 1461.01
Colorado Certification #: TN00003
Connecticut Certification #: PH-0197
DOD Certification: #1461.01
EPA# TN00003
Florida Certification #: E87487
Georgia DW Certification #: 923
Georgia Certification: NELAP
Idaho Certification #: TN00003
Illinois Certification #: 200008
Indiana Certification #: C-TN-01
Iowa Certification #: 364
Kansas Certification #: E-10277
Kentucky UST Certification #: 16
Kentucky Certification #: 90010
Louisiana Certification #: AI30792
Louisiana DW Certification #: LA180010
Maine Certification #: TN0002
Maryland Certification #: 324
Massachusetts Certification #: M-TN003
Michigan Certification #: 9958
Minnesota Certification #: 047-999-395
Mississippi Certification #: TN00003
Missouri Certification #: 340
Montana Certification #: CERT0086
Nebraska Certification #: NE-OS-15-05
Nevada Certification #: TN-03-2002-34
New Hampshire Certification #: 2975
New Jersey Certification #: TN002
New Mexico DW Certification
New York Certification #: 11742
North Carolina Aquatic Toxicity Certification #: 41
North Carolina Drinking Water Certification #: 21704
North Carolina Environmental Certificate #: 375
North Dakota Certification #: R-140
Ohio VAP Certification #: CL0069
Oklahoma Certification #: 9915
Oregon Certification #: TN200002
Pennsylvania Certification #: 68-02979
Rhode Island Certification #: LAO00356
South Carolina Certification #: 84004
South Dakota Certification
Tennessee DW/Chem/Micro Certification #: 2006
Texas Certification #: T 104704245-17-14
Texas Mold Certification #: LAB0152
USDA Soil Permit #: P330-15-00234
Utah Certification #: TN00003
Virginia Certification #: VT2006
Vermont Dept. of Health: ID# VT-2006
Virginia Certification #: 460132
Washington Certification #: C847
West Virginia Certification #: 233
Wisconsin Certification #: 998093910
Wyoming UST Certification #: via A2LA 2926.01
A2LA-ISO 17025 Certification #: 1461.01
A2LA-ISO 17025 Certification #: 1461.02
AIHA-LAP/LLC EMLAP Certification #:100789
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 2 of 34
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92710045
R23-56
Lab ID Sample ID Matrix Date Collected Date Received
92710045001 B-1 Water 01/24/24 13:00 01/25/24 09:17
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 3 of 34
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92710045
R23-56
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92710045001 B-1 MADEP EPH 8 PANDMG
MADEP VPH 5 PASI-CTEG
EPA 8270E 74 PASI-CPKS
SM 6200B 63 PASI-CJJK
EPA 8260D 63 PASI-CTMH
PAN = Pace National - Mt. Juliet
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 4 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92710045
R23-56
Sample:B-1 Lab ID:92710045001 Collected:01/24/24 13:00 Received:01/25/24 09:17 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: MADEP EPH Preparation Method: MA DEP/NJ DEP
Pace National - Mt. Juliet
TPH by Method MADEPE
Aliphatic (C09-C18),Unadjusted ND ug/L 02/01/24 13:2401/30/24 08:1610033.3 1
Aliphatic (C19-C36),Unadjusted 199 ug/L 02/01/24 13:2401/30/24 08:1610033.3 1
Aromatic (C11-C22), Unadjusted ND ug/L 02/01/24 12:58 TPHC11C2201/30/24 08:1610033.3 1
TEH, Unadjusted 300 ug/L 02/01/24 12:5801/30/24 08:1610033.3 1
Surrogates
o-Terphenyl (S)50.3 %02/01/24 12:58 84-15-101/30/24 08:1640.0-140 1
1-Chloro-octadecane (S)29.1 %02/01/24 13:24 3386-33-2 SR01/30/24 08:1640.0-140 1
2-Fluorobiphenyl (S)77.9 %02/01/24 12:58 321-60-801/30/24 08:1640.0-140 1
2-Bromonaphthalene (S)82.2 %02/01/24 12:58 580-13-201/30/24 08:1640.0-140 1
Analytical Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Water
Aliphatic (C05-C08),Unadjusted ND ug/L 02/02/24 08:58 N21001001
Aliphatic(C09-C12) Adjusted ND ug/L 02/02/24 08:58 N21001001
Aromatic (C09-C10)ND ug/L 02/02/24 08:58 N21001001
Surrogates
2,5-Dibromotoluene (FID)(S)103 %02/02/24 08:5870-130 1
2,5-Dibromotoluene (PID)(S)87 %02/02/24 08:5870-130 1
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8270E RVE
Acenaphthene ND ug/L 01/28/24 20:01 83-32-901/28/24 09:338.3 1.7 1
Acenaphthylene ND ug/L 01/28/24 20:01 208-96-801/28/24 09:338.3 1.6 1
Aniline ND ug/L 01/28/24 20:01 62-53-301/28/24 09:338.3 1.4 1
Anthracene ND ug/L 01/28/24 20:01 120-12-701/28/24 09:338.3 1.9 1
Benzo(a)anthracene ND ug/L 01/28/24 20:01 56-55-301/28/24 09:338.3 2.2 1
Benzo(a)pyrene ND ug/L 01/28/24 20:01 50-32-801/28/24 09:338.3 2.3 1
Benzo(b)fluoranthene ND ug/L 01/28/24 20:01 205-99-201/28/24 09:338.3 2.2 1
Benzo(g,h,i)perylene ND ug/L 01/28/24 20:01 191-24-201/28/24 09:338.3 2.4 1
Benzo(k)fluoranthene ND ug/L 01/28/24 20:01 207-08-901/28/24 09:338.3 2.3 1
Benzoic Acid ND ug/L 01/28/24 20:01 65-85-001/28/24 09:3341.7 18.3 1
Benzyl alcohol ND ug/L 01/28/24 20:01 100-51-601/28/24 09:3316.7 2.4 1
4-Bromophenylphenyl ether ND ug/L 01/28/24 20:01 101-55-301/28/24 09:338.3 1.5 1
Butylbenzylphthalate ND ug/L 01/28/24 20:01 85-68-701/28/24 09:338.3 2.6 1
4-Chloro-3-methylphenol ND ug/L 01/28/24 20:01 59-50-701/28/24 09:338.3 2.8 1
4-Chloroaniline ND ug/L 01/28/24 20:01 106-47-801/28/24 09:3316.7 3.0 1
bis(2-Chloroethoxy)methane ND ug/L 01/28/24 20:01 111-91-101/28/24 09:338.3 1.5 1
bis(2-Chloroethyl) ether ND ug/L 01/28/24 20:01 111-44-401/28/24 09:338.3 1.6 1
2-Chloronaphthalene ND ug/L 01/28/24 20:01 91-58-701/28/24 09:338.3 1.4 1
2-Chlorophenol ND ug/L 01/28/24 20:01 95-57-801/28/24 09:338.3 1.0 1
4-Chlorophenylphenyl ether ND ug/L 01/28/24 20:01 7005-72-301/28/24 09:338.3 1.7 1
Chrysene ND ug/L 01/28/24 20:01 218-01-901/28/24 09:338.3 2.3 1
Dibenz(a,h)anthracene ND ug/L 01/28/24 20:01 53-70-301/28/24 09:338.3 2.5 1
Dibenzofuran ND ug/L 01/28/24 20:01 132-64-901/28/24 09:338.3 1.8 1
1,2-Dichlorobenzene ND ug/L 01/28/24 20:01 95-50-101/28/24 09:338.3 1.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 5 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92710045
R23-56
Sample:B-1 Lab ID:92710045001 Collected:01/24/24 13:00 Received:01/25/24 09:17 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8270E RVE
1,3-Dichlorobenzene ND ug/L 01/28/24 20:01 541-73-101/28/24 09:338.3 1.3 1
1,4-Dichlorobenzene ND ug/L 01/28/24 20:01 106-46-701/28/24 09:338.3 1.4 1
3,3'-Dichlorobenzidine ND ug/L 01/28/24 20:01 91-94-101/28/24 09:3316.7 6.8 1
2,4-Dichlorophenol ND ug/L 01/28/24 20:01 120-83-201/28/24 09:338.3 1.2 1
Diethylphthalate ND ug/L 01/28/24 20:01 84-66-201/28/24 09:338.3 1.7 1
2,4-Dimethylphenol ND ug/L 01/28/24 20:01 105-67-901/28/24 09:338.3 1.4 1
Dimethylphthalate ND ug/L 01/28/24 20:01 131-11-301/28/24 09:338.3 1.8 1
Di-n-butylphthalate ND ug/L 01/28/24 20:01 84-74-201/28/24 09:338.3 1.8 1
4,6-Dinitro-2-methylphenol ND ug/L 01/28/24 20:01 534-52-101/28/24 09:3316.7 6.5 1
2,4-Dinitrophenol ND ug/L 01/28/24 20:01 51-28-501/28/24 09:3341.7 21.7 1
2,4-Dinitrotoluene ND ug/L 01/28/24 20:01 121-14-201/28/24 09:338.3 1.4 1
2,6-Dinitrotoluene ND ug/L 01/28/24 20:01 606-20-201/28/24 09:338.3 1.4 1
Di-n-octylphthalate ND ug/L 01/28/24 20:01 117-84-001/28/24 09:338.3 3.3 1
bis(2-Ethylhexyl)phthalate ND ug/L 01/28/24 20:01 117-81-701/28/24 09:335.0 3.1 1
Fluoranthene ND ug/L 01/28/24 20:01 206-44-001/28/24 09:338.3 1.8 1
Fluorene ND ug/L 01/28/24 20:01 86-73-701/28/24 09:338.3 1.7 1
Hexachloro-1,3-butadiene ND ug/L 01/28/24 20:01 87-68-301/28/24 09:338.3 1.5 1
Hexachlorobenzene ND ug/L 01/28/24 20:01 118-74-101/28/24 09:338.3 1.8 1
Hexachlorocyclopentadiene ND ug/L 01/28/24 20:01 77-47-401/28/24 09:338.3 1.3 1
Hexachloroethane ND ug/L 01/28/24 20:01 67-72-101/28/24 09:338.3 1.2 1
Indeno(1,2,3-cd)pyrene ND ug/L 01/28/24 20:01 193-39-501/28/24 09:338.3 2.4 1
Isophorone ND ug/L 01/28/24 20:01 78-59-101/28/24 09:338.3 1.4 1
1-Methylnaphthalene ND ug/L 01/28/24 20:01 90-12-001/28/24 09:338.3 1.7 1
2-Methylnaphthalene ND ug/L 01/28/24 20:01 91-57-601/28/24 09:338.3 1.6 1
2-Methylphenol(o-Cresol)ND ug/L 01/28/24 20:01 95-48-701/28/24 09:338.3 1.6 1
3&4-Methylphenol(m&p Cresol)ND ug/L 01/28/24 20:01 15831-10-401/28/24 09:338.3 1.0 1
Naphthalene ND ug/L 01/28/24 20:01 91-20-301/28/24 09:338.3 1.7 1
2-Nitroaniline ND ug/L 01/28/24 20:01 88-74-401/28/24 09:3316.7 2.5 1
3-Nitroaniline ND ug/L 01/28/24 20:01 99-09-201/28/24 09:3316.7 3.1 1
4-Nitroaniline ND ug/L 01/28/24 20:01 100-01-601/28/24 09:3316.7 4.2 1
Nitrobenzene ND ug/L 01/28/24 20:01 98-95-301/28/24 09:338.3 1.6 1
2-Nitrophenol ND ug/L 01/28/24 20:01 88-75-501/28/24 09:338.3 1.2 1
4-Nitrophenol ND ug/L 01/28/24 20:01 100-02-701/28/24 09:3341.7 5.5 1
N-Nitrosodimethylamine ND ug/L 01/28/24 20:01 62-75-901/28/24 09:338.3 1.6 1
N-Nitroso-di-n-propylamine ND ug/L 01/28/24 20:01 621-64-701/28/24 09:338.3 1.1 1
N-Nitrosodiphenylamine ND ug/L 01/28/24 20:01 86-30-601/28/24 09:338.3 2.5 1
2,2'-Oxybis(1-chloropropane)ND ug/L 01/28/24 20:01 108-60-101/28/24 09:338.3 0.96 1
Pentachlorophenol ND ug/L 01/28/24 20:01 87-86-501/28/24 09:3316.7 3.1 1
Phenanthrene ND ug/L 01/28/24 20:01 85-01-801/28/24 09:338.3 1.7 1
Phenol ND ug/L 01/28/24 20:01 108-95-201/28/24 09:338.3 1.1 1
Pyrene ND ug/L 01/28/24 20:01 129-00-001/28/24 09:338.3 1.8 1
1,2,4-Trichlorobenzene ND ug/L 01/28/24 20:01 120-82-101/28/24 09:338.3 1.4 1
2,4,5-Trichlorophenol ND ug/L 01/28/24 20:01 95-95-401/28/24 09:338.3 1.2 1
2,4,6-Trichlorophenol ND ug/L 01/28/24 20:01 88-06-201/28/24 09:338.3 1.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 6 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92710045
R23-56
Sample:B-1 Lab ID:92710045001 Collected:01/24/24 13:00 Received:01/25/24 09:17 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8270E RVE
Surrogates
Nitrobenzene-d5 (S)48 %01/28/24 20:01 4165-60-001/28/24 09:3310-133 1
2-Fluorobiphenyl (S)45 %01/28/24 20:01 321-60-801/28/24 09:3310-130 1
Terphenyl-d14 (S)90 %01/28/24 20:01 1718-51-001/28/24 09:3310-193 1
Phenol-d6 (S)21 %01/28/24 20:01 13127-88-301/28/24 09:3310-130 1
2-Fluorophenol (S)35 %01/28/24 20:01 367-12-401/28/24 09:3310-130 1
2,4,6-Tribromophenol (S)63 %01/28/24 20:01 118-79-601/28/24 09:3310-166 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 1.0 ug/L 01/31/24 19:02 71-43-20.50 0.079 1
Bromobenzene ND ug/L 01/31/24 19:02 108-86-10.50 0.14 1
Bromochloromethane ND ug/L 01/31/24 19:02 74-97-50.50 0.094 1
Bromodichloromethane ND ug/L 01/31/24 19:02 75-27-40.50 0.17 1
Bromoform ND ug/L 01/31/24 19:02 75-25-20.50 0.20 1
Bromomethane ND ug/L 01/31/24 19:02 74-83-95.0 0.22 1
n-Butylbenzene ND ug/L 01/31/24 19:02 104-51-80.50 0.066 1
sec-Butylbenzene 1.3 ug/L 01/31/24 19:02 135-98-80.50 0.085 1
tert-Butylbenzene ND ug/L 01/31/24 19:02 98-06-60.50 0.086 1
Carbon tetrachloride ND ug/L 01/31/24 19:02 56-23-50.50 0.17 1
Chlorobenzene ND ug/L 01/31/24 19:02 108-90-70.50 0.085 1
Chloroethane ND ug/L 01/31/24 19:02 75-00-31.0 0.17 1
Chloroform ND ug/L 01/31/24 19:02 67-66-30.50 0.069 1
Chloromethane ND ug/L 01/31/24 19:02 74-87-31.0 0.18 1
2-Chlorotoluene ND ug/L 01/31/24 19:02 95-49-80.50 0.13 1
4-Chlorotoluene ND ug/L 01/31/24 19:02 106-43-40.50 0.096 1
1,2-Dibromo-3-chloropropane ND ug/L 01/31/24 19:02 96-12-81.0 0.18 1
Dibromochloromethane ND ug/L 01/31/24 19:02 124-48-10.50 0.15 1
1,2-Dibromoethane (EDB)ND ug/L 01/31/24 19:02 106-93-40.50 0.15 1
Dibromomethane ND ug/L 01/31/24 19:02 74-95-30.50 0.19 1
1,2-Dichlorobenzene ND ug/L 01/31/24 19:02 95-50-10.50 0.094 1
1,3-Dichlorobenzene ND ug/L 01/31/24 19:02 541-73-10.50 0.098 1
1,4-Dichlorobenzene ND ug/L 01/31/24 19:02 106-46-70.50 0.090 1
Dichlorodifluoromethane ND ug/L 01/31/24 19:02 75-71-80.50 0.12 1
1,1-Dichloroethane ND ug/L 01/31/24 19:02 75-34-30.50 0.056 1
1,2-Dichloroethane ND ug/L 01/31/24 19:02 107-06-20.50 0.11 1
1,1-Dichloroethene ND ug/L 01/31/24 19:02 75-35-40.50 0.079 1
cis-1,2-Dichloroethene ND ug/L 01/31/24 19:02 156-59-20.50 0.11 1
trans-1,2-Dichloroethene ND ug/L 01/31/24 19:02 156-60-50.50 0.10 1
1,2-Dichloropropane ND ug/L 01/31/24 19:02 78-87-50.50 0.14 1
1,3-Dichloropropane ND ug/L 01/31/24 19:02 142-28-90.50 0.085 1
2,2-Dichloropropane ND ug/L 01/31/24 19:02 594-20-70.50 0.12 1
1,1-Dichloropropene ND ug/L 01/31/24 19:02 563-58-60.50 0.066 1
cis-1,3-Dichloropropene ND ug/L 01/31/24 19:02 10061-01-50.50 0.090 1
trans-1,3-Dichloropropene ND ug/L 01/31/24 19:02 10061-02-60.50 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 7 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92710045
R23-56
Sample:B-1 Lab ID:92710045001 Collected:01/24/24 13:00 Received:01/25/24 09:17 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Diisopropyl ether 5.1 ug/L 01/31/24 19:02 108-20-30.50 0.072 1
Ethylbenzene ND ug/L 01/31/24 19:02 100-41-40.50 0.081 1
Hexachloro-1,3-butadiene ND ug/L 01/31/24 19:02 87-68-32.0 0.35 1
Isopropylbenzene (Cumene)ND ug/L 01/31/24 19:02 98-82-80.50 0.11 1
Methylene Chloride ND ug/L 01/31/24 19:02 75-09-22.0 1.9 1
Methyl-tert-butyl ether 4.0 ug/L 01/31/24 19:02 1634-04-40.50 0.053 1
Naphthalene ND ug/L 01/31/24 19:02 91-20-32.0 0.10 1
n-Propylbenzene ND ug/L 01/31/24 19:02 103-65-10.50 0.10 1
Styrene ND ug/L 01/31/24 19:02 100-42-50.50 0.14 1
1,1,1,2-Tetrachloroethane ND ug/L 01/31/24 19:02 630-20-60.50 0.091 1
1,1,2,2-Tetrachloroethane ND ug/L 01/31/24 19:02 79-34-50.50 0.074 1
Tetrachloroethene ND ug/L 01/31/24 19:02 127-18-40.50 0.086 1
Toluene ND ug/L 01/31/24 19:02 108-88-30.50 0.090 1
1,2,3-Trichlorobenzene ND ug/L 01/31/24 19:02 87-61-62.0 0.12 1
1,2,4-Trichlorobenzene ND ug/L 01/31/24 19:02 120-82-12.0 0.16 1
1,1,1-Trichloroethane ND ug/L 01/31/24 19:02 71-55-60.50 0.11 1
1,1,2-Trichloroethane ND ug/L 01/31/24 19:02 79-00-50.50 0.096 1
Trichloroethene ND ug/L 01/31/24 19:02 79-01-60.50 0.17 1
Trichlorofluoromethane ND ug/L 01/31/24 19:02 75-69-41.0 0.14 1
1,2,3-Trichloropropane ND ug/L 01/31/24 19:02 96-18-40.50 0.17 1
1,2,4-Trimethylbenzene ND ug/L 01/31/24 19:02 95-63-60.50 0.031 1
1,3,5-Trimethylbenzene ND ug/L 01/31/24 19:02 108-67-80.50 0.071 1
Vinyl chloride ND ug/L 01/31/24 19:02 75-01-41.0 0.15 1
m&p-Xylene ND ug/L 01/31/24 19:02 179601-23-11.0 0.094 1
o-Xylene ND ug/L 01/31/24 19:02 95-47-60.50 0.14 1
Surrogates
1,2-Dichloroethane-d4 (S)102 %01/31/24 19:02 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %01/31/24 19:02 460-00-470-130 1
Toluene-d8 (S)100 %01/31/24 19:02 2037-26-570-130 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
Acetone ND ug/L 01/27/24 01:35 67-64-125.0 5.1 1
Benzene ND ug/L 01/27/24 01:35 71-43-21.0 0.34 1
Bromobenzene ND ug/L 01/27/24 01:35 108-86-11.0 0.29 1
Bromochloromethane ND ug/L 01/27/24 01:35 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 01/27/24 01:35 75-27-41.0 0.31 1
Bromoform ND ug/L 01/27/24 01:35 75-25-21.0 0.34 1
Bromomethane ND ug/L 01/27/24 01:35 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 01/27/24 01:35 78-93-35.0 4.0 1
Carbon tetrachloride ND ug/L 01/27/24 01:35 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 01/27/24 01:35 108-90-71.0 0.28 1
Chloroethane ND ug/L 01/27/24 01:35 75-00-31.0 0.65 1
Chloroform ND ug/L 01/27/24 01:35 67-66-31.0 0.43 1
Chloromethane ND ug/L 01/27/24 01:35 74-87-3 v21.0 0.54 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 8 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92710045
R23-56
Sample:B-1 Lab ID:92710045001 Collected:01/24/24 13:00 Received:01/25/24 09:17 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
2-Chlorotoluene ND ug/L 01/27/24 01:35 95-49-81.0 0.32 1
4-Chlorotoluene ND ug/L 01/27/24 01:35 106-43-41.0 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 01/27/24 01:35 96-12-82.0 0.34 1
Dibromochloromethane ND ug/L 01/27/24 01:35 124-48-11.0 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 01/27/24 01:35 106-93-41.0 0.27 1
Dibromomethane ND ug/L 01/27/24 01:35 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 01/27/24 01:35 95-50-11.0 0.34 1
1,3-Dichlorobenzene ND ug/L 01/27/24 01:35 541-73-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 01/27/24 01:35 106-46-71.0 0.33 1
Dichlorodifluoromethane ND ug/L 01/27/24 01:35 75-71-81.0 0.35 1
1,1-Dichloroethane ND ug/L 01/27/24 01:35 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 01/27/24 01:35 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 01/27/24 01:35 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 01/27/24 01:35 156-59-21.0 0.38 1
trans-1,2-Dichloroethene ND ug/L 01/27/24 01:35 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 01/27/24 01:35 78-87-51.0 0.36 1
1,3-Dichloropropane ND ug/L 01/27/24 01:35 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 01/27/24 01:35 594-20-71.0 0.39 1
1,1-Dichloropropene ND ug/L 01/27/24 01:35 563-58-61.0 0.43 1
cis-1,3-Dichloropropene ND ug/L 01/27/24 01:35 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 01/27/24 01:35 10061-02-61.0 0.36 1
Diisopropyl ether 3.7 ug/L 01/27/24 01:35 108-20-31.0 0.31 1
Ethylbenzene ND ug/L 01/27/24 01:35 100-41-41.0 0.30 1
Hexachloro-1,3-butadiene ND ug/L 01/27/24 01:35 87-68-32.0 1.5 1
2-Hexanone ND ug/L 01/27/24 01:35 591-78-65.0 0.48 1
p-Isopropyltoluene ND ug/L 01/27/24 01:35 99-87-61.0 0.41 1
Methylene Chloride ND ug/L 01/27/24 01:35 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 01/27/24 01:35 108-10-15.0 2.7 1
Methyl-tert-butyl ether 3.0 ug/L 01/27/24 01:35 1634-04-41.0 0.42 1
Naphthalene ND ug/L 01/27/24 01:35 91-20-31.0 0.64 1
Styrene ND ug/L 01/27/24 01:35 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 01/27/24 01:35 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 01/27/24 01:35 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 01/27/24 01:35 127-18-41.0 0.29 1
Toluene ND ug/L 01/27/24 01:35 108-88-31.0 0.24 1
1,2,3-Trichlorobenzene ND ug/L 01/27/24 01:35 87-61-61.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 01/27/24 01:35 120-82-11.0 0.64 1
1,1,1-Trichloroethane ND ug/L 01/27/24 01:35 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 01/27/24 01:35 79-00-51.0 0.32 1
Trichloroethene ND ug/L 01/27/24 01:35 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 01/27/24 01:35 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 01/27/24 01:35 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 01/27/24 01:35 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 01/27/24 01:35 75-01-41.0 0.39 1
Xylene (Total)ND ug/L 01/27/24 01:35 1330-20-71.0 0.34 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 9 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92710045
R23-56
Sample:B-1 Lab ID:92710045001 Collected:01/24/24 13:00 Received:01/25/24 09:17 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
m&p-Xylene ND ug/L 01/27/24 01:35 179601-23-12.0 0.71 1
o-Xylene ND ug/L 01/27/24 01:35 95-47-61.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)98 %01/27/24 01:35 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %01/27/24 01:35 17060-07-070-130 1
Toluene-d8 (S)104 %01/27/24 01:35 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 10 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
2216809
MA DEP/NJ DEP
MADEP EPH
TPH by Method MADEPE
Laboratory:Pace National - Mt. Juliet
Associated Lab Samples:92710045001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:R4029025-1
Associated Lab Samples:92710045001
Matrix:Water
AnalyzedMDL
Aliphatic (C09-C18),Unadjusted ug/L ND 100 02/01/24 07:4633.3
Aliphatic (C19-C36),Unadjusted ug/L ND 100 02/01/24 07:4633.3
1-Chloro-octadecane (S)%50.7 40.0-140 02/01/24 07:46
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:R4029029-1
Associated Lab Samples:92710045001
Matrix:Water
AnalyzedMDL
Aromatic (C11-C22), Unadjusted ug/L ND 100 02/01/24 07:4533.3
o-Terphenyl (S)%63.9 40.0-140 02/01/24 07:45
2-Fluorobiphenyl (S)%78.3 40.0-140 02/01/24 07:45
2-Bromonaphthalene (S)%82 40.0-140 02/01/24 07:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
R4029025-2LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
R4029025-3
Aliphatic (C09-C18),Unadjusted ug/L 378600 63.0 40.0-14055.5333 12.7 25
Aliphatic (C19-C36),Unadjusted ug/L 744800 93.0 40.0-14078.0624 17.5 25
1-Chloro-octadecane (S)%64.9 40.0-14053.9
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
R4029029-2LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
R4029029-3
Aromatic (C11-C22), Unadjusted ug/L 13501700 79.4 40.0-14071.81220 10.1 25
o-Terphenyl (S)%78.4 40.0-14068.6
2-Fluorobiphenyl (S)%86.3 40.0-14079.6
2-Bromonaphthalene (S)%93.4 40.0-14086.5
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
R4029025-4MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
L1698907-07
R4029025-5
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Aliphatic (C09-
C18),Unadjusted ug/L 600 43.5 40.0-14047.0 6.72 5060040.9 302 323
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 11 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
R4029025-4MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
L1698907-07
R4029025-5
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Aliphatic (C19-
C36),Unadjusted ug/L 800 66.2 40.0-14072.2 7.67 5080072.1 602 650
1-Chloro-octadecane (S)%40.9 40.0-14041.8
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
R4029029-4MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
L1698907-07
R4029029-5
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Aromatic (C11-C22),
Unadjusted ug/L 1700 51.2 40.0-14067.9 26.6 50170055.3 926 1210
o-Terphenyl (S)%56.9 40.0-14069.1
2-Fluorobiphenyl (S)%72.1 40.0-14083.0
2-Bromonaphthalene (S)%76.5 40.0-14089.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 12 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
829497
MADEP VPH
MADEP VPH
VPH NC Water
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92710045001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4287395
Associated Lab Samples:92710045001
Matrix:Water
AnalyzedMDL
Aliphatic (C05-C08),Unadjusted ug/L ND 100 N202/02/24 07:27100
Aromatic (C09-C10)ug/L ND 100 N202/02/24 07:27100
2,5-Dibromotoluene (FID)(S)%107 70-130 02/02/24 07:27
2,5-Dibromotoluene (PID)(S)%92 70-130 02/02/24 07:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4287396LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
4287397
Aliphatic (C05-C08),Unadjusted ug/L 311 N230010470-130108323 4 25
Aromatic (C09-C10)ug/L ND N21008170-13083ND 25
2,5-Dibromotoluene (FID)(S)%114 70-130116
2,5-Dibromotoluene (PID)(S)%101 70-130102
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 13 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
829190
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92710045001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4285884
Associated Lab Samples:92710045001
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 01/31/24 16:180.091
1,1,1-Trichloroethane ug/L ND 0.50 01/31/24 16:180.11
1,1,2,2-Tetrachloroethane ug/L ND 0.50 01/31/24 16:180.074
1,1,2-Trichloroethane ug/L ND 0.50 01/31/24 16:180.096
1,1-Dichloroethane ug/L ND 0.50 01/31/24 16:180.056
1,1-Dichloroethene ug/L ND 0.50 01/31/24 16:180.079
1,1-Dichloropropene ug/L ND 0.50 01/31/24 16:180.066
1,2,3-Trichlorobenzene ug/L ND 2.0 01/31/24 16:180.12
1,2,3-Trichloropropane ug/L ND 0.50 01/31/24 16:180.17
1,2,4-Trichlorobenzene ug/L ND 2.0 01/31/24 16:180.16
1,2,4-Trimethylbenzene ug/L ND 0.50 01/31/24 16:180.031
1,2-Dibromo-3-chloropropane ug/L ND 1.0 01/31/24 16:180.18
1,2-Dibromoethane (EDB)ug/L ND 0.50 01/31/24 16:180.15
1,2-Dichlorobenzene ug/L ND 0.50 01/31/24 16:180.094
1,2-Dichloroethane ug/L ND 0.50 01/31/24 16:180.11
1,2-Dichloropropane ug/L ND 0.50 01/31/24 16:180.14
1,3,5-Trimethylbenzene ug/L ND 0.50 01/31/24 16:180.071
1,3-Dichlorobenzene ug/L ND 0.50 01/31/24 16:180.098
1,3-Dichloropropane ug/L ND 0.50 01/31/24 16:180.085
1,4-Dichlorobenzene ug/L ND 0.50 01/31/24 16:180.090
2,2-Dichloropropane ug/L ND 0.50 01/31/24 16:180.12
2-Chlorotoluene ug/L ND 0.50 01/31/24 16:180.13
4-Chlorotoluene ug/L ND 0.50 01/31/24 16:180.096
Benzene ug/L ND 0.50 01/31/24 16:180.079
Bromobenzene ug/L ND 0.50 01/31/24 16:180.14
Bromochloromethane ug/L ND 0.50 01/31/24 16:180.094
Bromodichloromethane ug/L ND 0.50 01/31/24 16:180.17
Bromoform ug/L ND 0.50 01/31/24 16:180.20
Bromomethane ug/L ND 5.0 01/31/24 16:180.22
Carbon tetrachloride ug/L ND 0.50 01/31/24 16:180.17
Chlorobenzene ug/L ND 0.50 01/31/24 16:180.085
Chloroethane ug/L ND 1.0 01/31/24 16:180.17
Chloroform ug/L ND 0.50 01/31/24 16:180.069
Chloromethane ug/L ND 1.0 01/31/24 16:180.18
cis-1,2-Dichloroethene ug/L ND 0.50 01/31/24 16:180.11
cis-1,3-Dichloropropene ug/L ND 0.50 01/31/24 16:180.090
Dibromochloromethane ug/L ND 0.50 01/31/24 16:180.15
Dibromomethane ug/L ND 0.50 01/31/24 16:180.19
Dichlorodifluoromethane ug/L ND 0.50 01/31/24 16:180.12
Diisopropyl ether ug/L ND 0.50 01/31/24 16:180.072
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 14 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4285884
Associated Lab Samples:92710045001
Matrix:Water
AnalyzedMDL
Ethylbenzene ug/L ND 0.50 01/31/24 16:180.081
Hexachloro-1,3-butadiene ug/L ND 2.0 01/31/24 16:180.35
Isopropylbenzene (Cumene)ug/L ND 0.50 01/31/24 16:180.11
m&p-Xylene ug/L ND 1.0 01/31/24 16:180.094
Methyl-tert-butyl ether ug/L ND 0.50 01/31/24 16:180.053
Methylene Chloride ug/L ND 2.0 01/31/24 16:181.9
n-Butylbenzene ug/L ND 0.50 01/31/24 16:180.066
n-Propylbenzene ug/L ND 0.50 01/31/24 16:180.10
Naphthalene ug/L ND 2.0 01/31/24 16:180.10
o-Xylene ug/L ND 0.50 01/31/24 16:180.14
sec-Butylbenzene ug/L ND 0.50 01/31/24 16:180.085
Styrene ug/L ND 0.50 01/31/24 16:180.14
tert-Butylbenzene ug/L ND 0.50 01/31/24 16:180.086
Tetrachloroethene ug/L ND 0.50 01/31/24 16:180.086
Toluene ug/L ND 0.50 01/31/24 16:180.090
trans-1,2-Dichloroethene ug/L ND 0.50 01/31/24 16:180.10
trans-1,3-Dichloropropene ug/L ND 0.50 01/31/24 16:180.13
Trichloroethene ug/L ND 0.50 01/31/24 16:180.17
Trichlorofluoromethane ug/L ND 1.0 01/31/24 16:180.14
Vinyl chloride ug/L ND 1.0 01/31/24 16:180.15
1,2-Dichloroethane-d4 (S)%103 70-130 01/31/24 16:18
4-Bromofluorobenzene (S)%96 70-130 01/31/24 16:18
Toluene-d8 (S)%100 70-130 01/31/24 16:18
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4285885LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 20.620 103 60-140
1,1,1-Trichloroethane ug/L 20.620 103 60-140
1,1,2,2-Tetrachloroethane ug/L 20.820 104 60-140
1,1,2-Trichloroethane ug/L 20.220 101 60-140
1,1-Dichloroethane ug/L 20.620 103 60-140
1,1-Dichloroethene ug/L 21.220 106 60-140
1,1-Dichloropropene ug/L 21.820 109 60-140
1,2,3-Trichlorobenzene ug/L 16.320 82 60-140
1,2,3-Trichloropropane ug/L 20.020 100 60-140
1,2,4-Trichlorobenzene ug/L 16.720 83 60-140
1,2,4-Trimethylbenzene ug/L 21.920 109 60-140
1,2-Dibromo-3-chloropropane ug/L 19.520 97 60-140
1,2-Dibromoethane (EDB)ug/L 21.020 105 60-140
1,2-Dichlorobenzene ug/L 20.620 103 60-140
1,2-Dichloroethane ug/L 20.220 101 60-140
1,2-Dichloropropane ug/L 21.320 107 60-140
1,3,5-Trimethylbenzene ug/L 21.920 109 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 15 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4285885LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 20.620 103 60-140
1,3-Dichloropropane ug/L 20.620 103 60-140
1,4-Dichlorobenzene ug/L 20.120 101 60-140
2,2-Dichloropropane ug/L 21.120 106 60-140
2-Chlorotoluene ug/L 21.320 106 60-140
4-Chlorotoluene ug/L 21.620 108 60-140
Benzene ug/L 20.520 103 60-140
Bromobenzene ug/L 20.320 102 60-140
Bromochloromethane ug/L 19.720 99 60-140
Bromodichloromethane ug/L 20.220 101 60-140
Bromoform ug/L 20.420 102 60-140
Bromomethane ug/L 18.620 93 60-140
Carbon tetrachloride ug/L 21.620 108 60-140
Chlorobenzene ug/L 20.420 102 60-140
Chloroethane ug/L 22.720 114 60-140
Chloroform ug/L 19.820 99 60-140
Chloromethane ug/L 23.820 119 60-140
cis-1,2-Dichloroethene ug/L 20.620 103 60-140
cis-1,3-Dichloropropene ug/L 20.920 105 60-140
Dibromochloromethane ug/L 20.520 103 60-140
Dibromomethane ug/L 19.320 97 60-140
Dichlorodifluoromethane ug/L 22.920 114 60-140
Diisopropyl ether ug/L 19.520 97 60-140
Ethylbenzene ug/L 20.920 104 60-140
Hexachloro-1,3-butadiene ug/L 19.820 99 60-140
Isopropylbenzene (Cumene)ug/L 21.520 107 60-140
m&p-Xylene ug/L 42.340 106 60-140
Methyl-tert-butyl ether ug/L 18.420 92 60-140
Methylene Chloride ug/L 20.620 103 60-140
n-Butylbenzene ug/L 21.320 107 60-140
n-Propylbenzene ug/L 21.320 106 60-140
Naphthalene ug/L 16.720 84 60-140
o-Xylene ug/L 21.020 105 60-140
sec-Butylbenzene ug/L 21.620 108 60-140
Styrene ug/L 21.520 108 60-140
tert-Butylbenzene ug/L 21.120 105 60-140
Tetrachloroethene ug/L 20.920 105 60-140
Toluene ug/L 20.220 101 60-140
trans-1,2-Dichloroethene ug/L 20.820 104 60-140
trans-1,3-Dichloropropene ug/L 21.420 107 60-140
Trichloroethene ug/L 20.320 102 60-140
Trichlorofluoromethane ug/L 21.320 107 60-140
Vinyl chloride ug/L 21.420 107 60-140
1,2-Dichloroethane-d4 (S)%101 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 16 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4285886MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92710665005
4285887
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 114 60-140111 3 3020ND22.8 22.1
1,1,1-Trichloroethane ug/L 20 118 60-140113 4 3020ND23.5 22.6
1,1,2,2-Tetrachloroethane ug/L 20 113 60-140113 1 3020ND22.7 22.5
1,1,2-Trichloroethane ug/L 20 113 60-140109 4 3020ND22.7 21.8
1,1-Dichloroethane ug/L 20 113 60-140109 3 3020ND22.6 21.9
1,1-Dichloroethene ug/L 20 119 60-140117 2 3020ND23.8 23.3
1,1-Dichloropropene ug/L 20 125 60-140121 3 3020ND25.0 24.2
1,2,3-Trichlorobenzene ug/L 20 110 60-140108 2 3020ND22.0 21.5
1,2,3-Trichloropropane ug/L 20 108 60-140107 1 3020ND21.6 21.4
1,2,4-Trichlorobenzene ug/L 20 111 60-140106 4 3020ND22.1 21.2
1,2,4-Trimethylbenzene ug/L 20 105 60-140112 7 3020ND21.0 22.5
1,2-Dibromo-3-
chloropropane ug/L 20 106 60-140108 2 3020ND21.2 21.7
1,2-Dibromoethane (EDB)ug/L 20 114 60-140112 1 3020ND22.7 22.5
1,2-Dichlorobenzene ug/L 20 110 60-140108 2 3020ND22.0 21.7
1,2-Dichloroethane ug/L 20 114 60-140109 4 3020ND22.8 21.8
1,2-Dichloropropane ug/L 20 111 60-140108 3 3020ND22.2 21.6
1,3,5-Trimethylbenzene ug/L 20 98 60-140111 13 3020ND19.6 22.2
1,3-Dichlorobenzene ug/L 20 112 60-140109 3 3020ND22.4 21.7
1,3-Dichloropropane ug/L 20 111 60-140109 2 3020ND22.2 21.8
1,4-Dichlorobenzene ug/L 20 107 60-140108 1 3020ND21.4 21.5
2,2-Dichloropropane ug/L 20 127 60-140122 3 3020ND25.3 24.5
2-Chlorotoluene ug/L 20 113 60-140109 3 3020ND22.6 21.9
4-Chlorotoluene ug/L 20 111 60-140109 2 3020ND22.2 21.9
Benzene ug/L 20 113 60-140111 1 3020ND22.6 22.3
Bromobenzene ug/L 20 110 60-140108 2 3020ND22.1 21.6
Bromochloromethane ug/L 20 119 60-140114 4 3020ND23.7 22.9
Bromodichloromethane ug/L 20 109 60-140107 2 3020ND21.8 21.4
Bromoform ug/L 20 106 60-140107 0 3020ND21.3 21.3
Bromomethane ug/L 20 100 60-140112 12 3020ND19.9 22.4
Carbon tetrachloride ug/L 20 115 60-140113 2 3020ND23.0 22.6
Chlorobenzene ug/L 20 113 60-140109 4 3020ND22.6 21.8
Chloroethane ug/L 20 121 60-140119 1 3020ND24.1 23.9
Chloroform ug/L 20 113 60-140107 6 3020ND22.6 21.3
Chloromethane ug/L 20 129 60-140118 9 3020ND25.7 23.6
cis-1,2-Dichloroethene ug/L 20 114 60-140111 3 3020ND22.9 22.2
cis-1,3-Dichloropropene ug/L 20 112 60-140109 3 3020ND22.5 21.9
Dibromochloromethane ug/L 20 109 60-140108 1 3020ND21.9 21.6
Dibromomethane ug/L 20 115 60-140111 3 3020ND23.0 22.3
Dichlorodifluoromethane ug/L 20 91 60-14088 3 3020ND18.2 17.6
Diisopropyl ether ug/L 20 109 60-140106 3 3020ND21.8 21.1
Ethylbenzene ug/L 20 112 60-140110 1 3020ND22.4 22.0
Hexachloro-1,3-butadiene ug/L 20 117 60-140109 6 3020ND23.3 21.9
Isopropylbenzene
(Cumene)
ug/L 20 117 60-140115 2 3020ND23.4 22.9
m&p-Xylene ug/L 40 108 60-140110 2 3040ND43.2 44.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 17 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4285886MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92710665005
4285887
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methyl-tert-butyl ether ug/L 20 108 60-140104 3 3020ND21.5 20.9
Methylene Chloride ug/L 20 109 60-140106 4 3020ND21.9 21.1
n-Butylbenzene ug/L 20 117 60-140116 1 3020ND23.5 23.2
n-Propylbenzene ug/L 20 112 60-140111 1 3020ND22.3 22.1
Naphthalene ug/L 20 114 60-140112 2 3020ND22.9 22.4
o-Xylene ug/L 20 109 60-140110 1 3020ND21.8 22.0
sec-Butylbenzene ug/L 20 114 60-140113 1 3020ND22.8 22.7
Styrene ug/L 20 98 60-140111 12 3020ND19.6 22.2
tert-Butylbenzene ug/L 20 98 60-14096 2 3020ND19.6 19.1
Tetrachloroethene ug/L 20 113 60-140111 2 3020ND22.6 22.2
Toluene ug/L 20 112 60-140109 2 3020ND22.3 21.8
trans-1,2-Dichloroethene ug/L 20 118 60-140114 4 3020ND23.6 22.8
trans-1,3-Dichloropropene ug/L 20 110 60-140109 2 3020ND22.1 21.8
Trichloroethene ug/L 20 113 60-140111 2 3020ND22.7 22.2
Trichlorofluoromethane ug/L 20 120 60-140116 3 3020ND23.9 23.2
Vinyl chloride ug/L 20 106 60-140102 3 3020ND21.2 20.5
1,2-Dichloroethane-d4 (S)%101 70-130101
4-Bromofluorobenzene (S)%100 70-130100
Toluene-d8 (S)%97 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 18 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
828303
EPA 8260D
EPA 8260D
8260D MSV Low Level
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92710045001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4282538
Associated Lab Samples:92710045001
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 01/26/24 23:150.31
1,1,1-Trichloroethane ug/L ND 1.0 01/26/24 23:150.33
1,1,2,2-Tetrachloroethane ug/L ND 1.0 01/26/24 23:150.22
1,1,2-Trichloroethane ug/L ND 1.0 01/26/24 23:150.32
1,1-Dichloroethane ug/L ND 1.0 01/26/24 23:150.37
1,1-Dichloroethene ug/L ND 1.0 01/26/24 23:150.35
1,1-Dichloropropene ug/L ND 1.0 01/26/24 23:150.43
1,2,3-Trichlorobenzene ug/L ND 1.0 01/26/24 23:150.81
1,2,3-Trichloropropane ug/L ND 1.0 01/26/24 23:150.26
1,2,4-Trichlorobenzene ug/L ND 1.0 01/26/24 23:150.64
1,2-Dibromo-3-chloropropane ug/L ND 2.0 01/26/24 23:150.34
1,2-Dibromoethane (EDB)ug/L ND 1.0 01/26/24 23:150.27
1,2-Dichlorobenzene ug/L ND 1.0 01/26/24 23:150.34
1,2-Dichloroethane ug/L ND 1.0 01/26/24 23:150.32
1,2-Dichloropropane ug/L ND 1.0 01/26/24 23:150.36
1,3-Dichlorobenzene ug/L ND 1.0 01/26/24 23:150.34
1,3-Dichloropropane ug/L ND 1.0 01/26/24 23:150.28
1,4-Dichlorobenzene ug/L ND 1.0 01/26/24 23:150.33
2,2-Dichloropropane ug/L ND 1.0 01/26/24 23:150.39
2-Butanone (MEK)ug/L ND 5.0 01/26/24 23:154.0
2-Chlorotoluene ug/L ND 1.0 01/26/24 23:150.32
2-Hexanone ug/L ND 5.0 01/26/24 23:150.48
4-Chlorotoluene ug/L ND 1.0 01/26/24 23:150.32
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 01/26/24 23:152.7
Acetone ug/L ND 25.0 01/26/24 23:155.1
Benzene ug/L ND 1.0 01/26/24 23:150.34
Bromobenzene ug/L ND 1.0 01/26/24 23:150.29
Bromochloromethane ug/L ND 1.0 01/26/24 23:150.47
Bromodichloromethane ug/L ND 1.0 01/26/24 23:150.31
Bromoform ug/L ND 1.0 01/26/24 23:150.34
Bromomethane ug/L ND 2.0 v201/26/24 23:151.7
Carbon tetrachloride ug/L ND 1.0 01/26/24 23:150.33
Chlorobenzene ug/L ND 1.0 01/26/24 23:150.28
Chloroethane ug/L ND 1.0 01/26/24 23:150.65
Chloroform ug/L ND 1.0 01/26/24 23:150.43
Chloromethane ug/L ND 1.0 v201/26/24 23:150.54
cis-1,2-Dichloroethene ug/L ND 1.0 01/26/24 23:150.38
cis-1,3-Dichloropropene ug/L ND 1.0 01/26/24 23:150.36
Dibromochloromethane ug/L ND 1.0 01/26/24 23:150.36
Dibromomethane ug/L ND 1.0 01/26/24 23:150.39
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 19 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4282538
Associated Lab Samples:92710045001
Matrix:Water
AnalyzedMDL
Dichlorodifluoromethane ug/L ND 1.0 01/26/24 23:150.35
Diisopropyl ether ug/L ND 1.0 01/26/24 23:150.31
Ethylbenzene ug/L ND 1.0 01/26/24 23:150.30
Hexachloro-1,3-butadiene ug/L ND 2.0 01/26/24 23:151.5
m&p-Xylene ug/L ND 2.0 01/26/24 23:150.71
Methyl-tert-butyl ether ug/L ND 1.0 01/26/24 23:150.42
Methylene Chloride ug/L ND 5.0 01/26/24 23:152.0
Naphthalene ug/L ND 1.0 01/26/24 23:150.64
o-Xylene ug/L ND 1.0 01/26/24 23:150.34
p-Isopropyltoluene ug/L ND 1.0 01/26/24 23:150.41
Styrene ug/L ND 1.0 01/26/24 23:150.29
Tetrachloroethene ug/L ND 1.0 01/26/24 23:150.29
Toluene ug/L ND 1.0 01/26/24 23:150.24
trans-1,2-Dichloroethene ug/L ND 1.0 01/26/24 23:150.40
trans-1,3-Dichloropropene ug/L ND 1.0 01/26/24 23:150.36
Trichloroethene ug/L ND 1.0 01/26/24 23:150.38
Trichlorofluoromethane ug/L ND 1.0 01/26/24 23:150.30
Vinyl acetate ug/L ND 2.0 01/26/24 23:151.3
Vinyl chloride ug/L ND 1.0 01/26/24 23:150.39
Xylene (Total)ug/L ND 1.0 01/26/24 23:150.34
1,2-Dichloroethane-d4 (S)%101 70-130 01/26/24 23:15
4-Bromofluorobenzene (S)%98 70-130 01/26/24 23:15
Toluene-d8 (S)%103 70-130 01/26/24 23:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4282539LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 21.320 106 70-130
1,1,1-Trichloroethane ug/L 19.920 100 70-130
1,1,2,2-Tetrachloroethane ug/L 20.720 103 70-130
1,1,2-Trichloroethane ug/L 19.120 96 70-130
1,1-Dichloroethane ug/L 20.320 102 70-130
1,1-Dichloroethene ug/L 22.120 111 69-131
1,1-Dichloropropene ug/L 21.420 107 70-132
1,2,3-Trichlorobenzene ug/L 20.220 101 70-132
1,2,3-Trichloropropane ug/L 19.720 98 70-130
1,2,4-Trichlorobenzene ug/L 21.420 107 70-130
1,2-Dibromo-3-chloropropane ug/L 19.120 96 70-130
1,2-Dibromoethane (EDB)ug/L 21.020 105 70-130
1,2-Dichlorobenzene ug/L 20.420 102 70-130
1,2-Dichloroethane ug/L 19.120 96 70-130
1,2-Dichloropropane ug/L 19.820 99 70-130
1,3-Dichlorobenzene ug/L 20.720 104 70-130
1,3-Dichloropropane ug/L 21.120 106 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 20 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4282539LABORATORY CONTROL SAMPLE:
LCSSpike
1,4-Dichlorobenzene ug/L 20.420 102 70-130
2,2-Dichloropropane ug/L 20.220 101 69-130
2-Butanone (MEK)ug/L 34.740 87 67-133
2-Chlorotoluene ug/L 21.320 107 70-130
2-Hexanone ug/L 38.740 97 70-133
4-Chlorotoluene ug/L 21.320 106 70-130
4-Methyl-2-pentanone (MIBK)ug/L 35.740 89 70-130
Acetone ug/L 37.440 93 67-130
Benzene ug/L 19.220 96 70-130
Bromobenzene ug/L 21.120 105 70-130
Bromochloromethane ug/L 20.120 100 70-130
Bromodichloromethane ug/L 19.220 96 70-130
Bromoform ug/L 20.020 100 70-133
Bromomethane ug/L 15.1 v3207541-148
Carbon tetrachloride ug/L 19.620 98 70-130
Chlorobenzene ug/L 20.420 102 70-130
Chloroethane ug/L 17.620 88 41-157
Chloroform ug/L 19.220 96 70-130
Chloromethane ug/L 16.3 v3208159-141
cis-1,2-Dichloroethene ug/L 19.620 98 70-130
cis-1,3-Dichloropropene ug/L 20.320 102 70-130
Dibromochloromethane ug/L 21.320 106 70-130
Dibromomethane ug/L 19.120 96 70-130
Dichlorodifluoromethane ug/L 18.620 93 54-147
Diisopropyl ether ug/L 17.820 89 70-130
Ethylbenzene ug/L 20.520 102 70-130
Hexachloro-1,3-butadiene ug/L 20.920 104 70-134
m&p-Xylene ug/L 40.540 101 70-130
Methyl-tert-butyl ether ug/L 17.620 88 70-130
Methylene Chloride ug/L 18.620 93 62-130
Naphthalene ug/L 21.320 106 70-135
o-Xylene ug/L 20.320 102 70-130
p-Isopropyltoluene ug/L 21.420 107 70-130
Styrene ug/L 20.520 103 70-130
Tetrachloroethene ug/L 19.720 99 70-130
Toluene ug/L 18.620 93 70-130
trans-1,2-Dichloroethene ug/L 20.520 102 70-130
trans-1,3-Dichloropropene ug/L 19.420 97 70-130
Trichloroethene ug/L 19.620 98 70-130
Trichlorofluoromethane ug/L 18.720 93 57-130
Vinyl acetate ug/L 36.540 91 70-141
Vinyl chloride ug/L 15.620 78 66-140
Xylene (Total)ug/L 60.860 101 70-130
1,2-Dichloroethane-d4 (S)%104 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%99 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 21 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4282540MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92710420002
4282541
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 97 70-14698 1 3020ND19.3 19.6
1,1,1-Trichloroethane ug/L 20 116 70-150107 8 3020ND23.2 21.4
1,1,2,2-Tetrachloroethane ug/L 20 93 66-14493 0 3020ND18.6 18.7
1,1,2-Trichloroethane ug/L 20 100 70-14298 2 3020ND20.0 19.5
1,1-Dichloroethane ug/L 20 108 68-150100 7 3020ND21.6 20.1
1,1-Dichloroethene ug/L 20 115 64-162107 7 3020ND23.1 21.4
1,1-Dichloropropene ug/L 20 118 70-160114 4 3020ND23.5 22.7
1,2,3-Trichlorobenzene ug/L 20 95 66-15199 3 3020ND19.1 19.7
1,2,3-Trichloropropane ug/L 20 87 66-14489 2 3020ND17.4 17.8
1,2,4-Trichlorobenzene ug/L 20 98 69-14799 1 3020ND19.6 19.8
1,2-Dibromo-3-
chloropropane ug/L 20 80 62-14691 13 3020ND16.0 18.2
1,2-Dibromoethane (EDB)ug/L 20 93 70-14394 0 3020ND18.7 18.7
1,2-Dichlorobenzene ug/L 20 96 70-14295 0 3020ND19.1 19.1
1,2-Dichloroethane ug/L 20 105 68-14596 9 3020ND21.1 19.2
1,2-Dichloropropane ug/L 20 101 70-14495 6 3020ND20.2 19.0
1,3-Dichlorobenzene ug/L 20 97 70-14296 2 3020ND19.5 19.2
1,3-Dichloropropane ug/L 20 90 70-14193 3 3020ND18.0 18.5
1,4-Dichlorobenzene ug/L 20 98 70-14096 2 3020ND19.6 19.2
2,2-Dichloropropane ug/L 20 114 58-160110 4 3020ND22.8 22.0
2-Butanone (MEK)ug/L 40 92 57-15696 4 3040ND36.6 38.2
2-Chlorotoluene ug/L 20 98 70-14898 0 3020ND19.5 19.6
2-Hexanone ug/L 40 89 62-15394 6 3040ND35.4 37.5
4-Chlorotoluene ug/L 20 98 70-14496 2 3020ND19.5 19.2
4-Methyl-2-pentanone
(MIBK)ug/L 40 87 65-14491 4 3040ND34.8 36.4
Acetone ug/L 40 91 49-16293 2 3040ND36.5 37.1
Benzene ug/L 20 103 68-14498 5 3020ND20.5 19.5
Bromobenzene ug/L 20 95 70-14492 4 3020ND19.0 18.3
Bromochloromethane ug/L 20 111 70-148103 8 3020ND22.3 20.6
Bromodichloromethane ug/L 20 100 70-14196 4 3020ND19.9 19.2
Bromoform ug/L 20 94 59-14494 0 3020ND18.9 18.8
Bromomethane ug/L v3208223-19079 3 3020ND16.3 15.9
Carbon tetrachloride ug/L 20 112 70-147106 5 3020ND22.4 21.3
Chlorobenzene ug/L 20 96 70-14394 2 3020ND19.3 18.8
Chloroethane ug/L 20 116 55-190112 3 3020ND23.2 22.4
Chloroform ug/L 20 108 67-14899 9 3020ND21.6 19.8
Chloromethane ug/L 20 107 38-18099 8 3020ND21.4 19.8
cis-1,2-Dichloroethene ug/L 20 109 67-151101 7 3020ND21.7 20.2
cis-1,3-Dichloropropene ug/L 20 102 70-14298 4 3020ND20.4 19.5
Dibromochloromethane ug/L 20 98 68-14097 1 3020ND19.7 19.5
Dibromomethane ug/L 20 97 70-14293 4 3020ND19.4 18.6
Dichlorodifluoromethane ug/L 20 101 15-20093 8 3020ND20.2 18.5
Diisopropyl ether ug/L 20 97 62-14995 2 3020ND19.4 19.0
Ethylbenzene ug/L 20 97 70-14596 1 3020ND19.4 19.2
Hexachloro-1,3-butadiene ug/L 20 103 64-164105 2 3020ND20.6 21.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
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[phone]
Page 22 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4282540MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92710420002
4282541
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
m&p-Xylene ug/L 40 99 70-14896 3 3040ND39.7 38.6
Methyl-tert-butyl ether ug/L 20 98 64-14696 3 3020ND19.6 19.2
Methylene Chloride ug/L 20 107 54-14999 8 3020ND21.4 19.9
Naphthalene ug/L 20 92 62-15496 4 3020ND18.5 19.2
o-Xylene ug/L 20 95 70-14592 3 3020ND19.0 18.5
p-Isopropyltoluene ug/L 20 108 70-153105 2 3020ND21.5 21.1
Styrene ug/L 20 97 70-14793 5 3020ND19.4 18.5
Tetrachloroethene ug/L 20 101 70-14598 3 3020ND20.2 19.6
Toluene ug/L 20 97 65-14694 4 3020ND19.5 18.7
trans-1,2-Dichloroethene ug/L 20 113 69-155104 8 3020ND22.6 20.7
trans-1,3-Dichloropropene ug/L 20 100 70-14297 3 3020ND20.0 19.4
Trichloroethene ug/L 20 104 70-152101 3 3020ND20.8 20.2
Trichlorofluoromethane ug/L 20 120 60-158109 10 3020ND24.0 21.8
Vinyl acetate ug/L 40 102 56-157102 0 3040ND40.7 40.6
Vinyl chloride ug/L 20 104 51-17896 8 3020ND20.9 19.3
Xylene (Total)ug/L 60 98 70-14695 3 3060ND58.6 57.0
1,2-Dichloroethane-d4 (S)%109 70-130101
4-Bromofluorobenzene (S)%102 70-130101
Toluene-d8 (S)%100 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 23 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
828334
EPA 3510C
EPA 8270E
8270E Water MSSV RVE
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92710045001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4282600
Associated Lab Samples:92710045001
Matrix:Water
AnalyzedMDL
1,2,4-Trichlorobenzene ug/L ND 10.0 01/27/24 16:581.7
1,2-Dichlorobenzene ug/L ND 10.0 01/27/24 16:581.8
1,3-Dichlorobenzene ug/L ND 10.0 01/27/24 16:581.6
1,4-Dichlorobenzene ug/L ND 10.0 01/27/24 16:581.7
1-Methylnaphthalene ug/L ND 10.0 01/27/24 16:582.0
2,2'-Oxybis(1-chloropropane)ug/L ND 10.0 01/27/24 16:581.2
2,4,5-Trichlorophenol ug/L ND 10.0 01/27/24 16:581.4
2,4,6-Trichlorophenol ug/L ND 10.0 01/27/24 16:581.6
2,4-Dichlorophenol ug/L ND 10.0 01/27/24 16:581.4
2,4-Dimethylphenol ug/L ND 10.0 01/27/24 16:581.7
2,4-Dinitrophenol ug/L ND 50.0 01/27/24 16:5826.0
2,4-Dinitrotoluene ug/L ND 10.0 01/27/24 16:581.6
2,6-Dinitrotoluene ug/L ND 10.0 01/27/24 16:581.7
2-Chloronaphthalene ug/L ND 10.0 01/27/24 16:581.7
2-Chlorophenol ug/L ND 10.0 01/27/24 16:581.2
2-Methylnaphthalene ug/L ND 10.0 01/27/24 16:581.9
2-Methylphenol(o-Cresol)ug/L ND 10.0 01/27/24 16:581.9
2-Nitroaniline ug/L ND 20.0 v201/27/24 16:583.0
2-Nitrophenol ug/L ND 10.0 01/27/24 16:581.4
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 01/27/24 16:581.2
3,3'-Dichlorobenzidine ug/L ND 20.0 01/27/24 16:588.1
3-Nitroaniline ug/L ND 20.0 01/27/24 16:583.8
4,6-Dinitro-2-methylphenol ug/L ND 20.0 v101/27/24 16:587.8
4-Bromophenylphenyl ether ug/L ND 10.0 01/27/24 16:581.8
4-Chloro-3-methylphenol ug/L ND 10.0 01/27/24 16:583.3
4-Chloroaniline ug/L ND 20.0 01/27/24 16:583.6
4-Chlorophenylphenyl ether ug/L ND 10.0 01/27/24 16:582.0
4-Nitroaniline ug/L ND 20.0 01/27/24 16:585.1
4-Nitrophenol ug/L ND 50.0 01/27/24 16:586.6
Acenaphthene ug/L ND 10.0 01/27/24 16:582.0
Acenaphthylene ug/L ND 10.0 01/27/24 16:582.0
Aniline ug/L ND 10.0 01/27/24 16:581.6
Anthracene ug/L ND 10.0 01/27/24 16:582.3
Benzo(a)anthracene ug/L ND 10.0 01/27/24 16:582.7
Benzo(a)pyrene ug/L ND 10.0 01/27/24 16:582.8
Benzo(b)fluoranthene ug/L ND 10.0 01/27/24 16:582.6
Benzo(g,h,i)perylene ug/L ND 10.0 01/27/24 16:582.8
Benzo(k)fluoranthene ug/L ND 10.0 01/27/24 16:582.7
Benzoic Acid ug/L ND 50.0 01/27/24 16:5822.0
Benzyl alcohol ug/L ND 20.0 01/27/24 16:582.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 24 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4282600
Associated Lab Samples:92710045001
Matrix:Water
AnalyzedMDL
bis(2-Chloroethoxy)methane ug/L ND 10.0 01/27/24 16:581.8
bis(2-Chloroethyl) ether ug/L ND 10.0 01/27/24 16:581.9
bis(2-Ethylhexyl)phthalate ug/L ND 6.0 01/27/24 16:583.7
Butylbenzylphthalate ug/L ND 10.0 01/27/24 16:583.1
Chrysene ug/L ND 10.0 01/27/24 16:582.8
Di-n-butylphthalate ug/L ND 10.0 01/27/24 16:582.2
Di-n-octylphthalate ug/L ND 10.0 01/27/24 16:583.9
Dibenz(a,h)anthracene ug/L ND 10.0 01/27/24 16:583.0
Dibenzofuran ug/L ND 10.0 01/27/24 16:582.1
Diethylphthalate ug/L ND 10.0 01/27/24 16:582.0
Dimethylphthalate ug/L ND 10.0 01/27/24 16:582.1
Fluoranthene ug/L ND 10.0 01/27/24 16:582.2
Fluorene ug/L ND 10.0 01/27/24 16:582.1
Hexachloro-1,3-butadiene ug/L ND 10.0 v101/27/24 16:581.8
Hexachlorobenzene ug/L ND 10.0 01/27/24 16:582.2
Hexachlorocyclopentadiene ug/L ND 10.0 01/27/24 16:581.6
Hexachloroethane ug/L ND 10.0 01/27/24 16:581.4
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 01/27/24 16:582.9
Isophorone ug/L ND 10.0 01/27/24 16:581.7
N-Nitroso-di-n-propylamine ug/L ND 10.0 01/27/24 16:581.3
N-Nitrosodimethylamine ug/L ND 10.0 01/27/24 16:581.9
N-Nitrosodiphenylamine ug/L ND 10.0 01/27/24 16:583.0
Naphthalene ug/L ND 10.0 01/27/24 16:582.1
Nitrobenzene ug/L ND 10.0 01/27/24 16:581.9
Pentachlorophenol ug/L ND 20.0 01/27/24 16:583.8
Phenanthrene ug/L ND 10.0 01/27/24 16:582.0
Phenol ug/L ND 10.0 01/27/24 16:581.4
Pyrene ug/L ND 10.0 01/27/24 16:582.2
2,4,6-Tribromophenol (S)%98 10-166 01/27/24 16:58
2-Fluorobiphenyl (S)%69 10-130 01/27/24 16:58
2-Fluorophenol (S)%63 10-130 01/27/24 16:58
Nitrobenzene-d5 (S)%82 10-133 01/27/24 16:58
Phenol-d6 (S)%49 10-130 01/27/24 16:58
Terphenyl-d14 (S)%105 10-193 01/27/24 16:58
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4282601LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 44.050 88 14-130
1,2-Dichlorobenzene ug/L 38.450 77 10-130
1,3-Dichlorobenzene ug/L 37.350 75 10-130
1,4-Dichlorobenzene ug/L 37.950 76 10-130
1-Methylnaphthalene ug/L 44.150 88 26-131
2,2'-Oxybis(1-chloropropane)ug/L 36.250 72 23-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 25 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4282601LABORATORY CONTROL SAMPLE:
LCSSpike
2,4,5-Trichlorophenol ug/L 49.550 99 36-150
2,4,6-Trichlorophenol ug/L 48.650 97 30-151
2,4-Dichlorophenol ug/L 45.750 91 36-140
2,4-Dimethylphenol ug/L 51.350 103 36-155
2,4-Dinitrophenol ug/L 232250 93 10-169
2,4-Dinitrotoluene ug/L 47.250 94 46-160
2,6-Dinitrotoluene ug/L 45.450 91 47-161
2-Chloronaphthalene ug/L 46.250 92 29-134
2-Chlorophenol ug/L 42.850 86 29-130
2-Methylnaphthalene ug/L 43.650 87 26-130
2-Methylphenol(o-Cresol)ug/L 41.150 82 32-130
2-Nitroaniline ug/L 77.3 v31007741-150
2-Nitrophenol ug/L 48.650 97 31-145
3&4-Methylphenol(m&p Cresol)ug/L 37.950 76 29-130
3,3'-Dichlorobenzidine ug/L 96.1100 96 46-153
3-Nitroaniline ug/L 93.1100 93 47-156
4,6-Dinitro-2-methylphenol ug/L 108 v110010823-161
4-Bromophenylphenyl ether ug/L 51.950 104 45-143
4-Chloro-3-methylphenol ug/L 90.0100 90 42-143
4-Chloroaniline ug/L 81.3100 81 37-135
4-Chlorophenylphenyl ether ug/L 49.350 99 43-140
4-Nitroaniline ug/L 81.8100 82 47-157
4-Nitrophenol ug/L 118250 47 10-130
Acenaphthene ug/L 40.350 81 38-138
Acenaphthylene ug/L 40.550 81 39-139
Aniline ug/L 28.550 57 16-130
Anthracene ug/L 46.550 93 45-136
Benzo(a)anthracene ug/L 51.450 103 52-151
Benzo(a)pyrene ug/L 53.150 106 46-165
Benzo(b)fluoranthene ug/L 53.550 107 44-170
Benzo(g,h,i)perylene ug/L 49.850 100 39-171
Benzo(k)fluoranthene ug/L 53.850 108 43-168
Benzoic Acid ug/L 134250 54 10-130
Benzyl alcohol ug/L 83.2100 83 33-134
bis(2-Chloroethoxy)methane ug/L 46.050 92 37-140
bis(2-Chloroethyl) ether ug/L 45.850 92 33-136
bis(2-Ethylhexyl)phthalate ug/L 54.350 109 50-169
Butylbenzylphthalate ug/L 51.250 102 50-174
Chrysene ug/L 50.750 101 52-148
Di-n-butylphthalate ug/L 49.750 99 51-154
Di-n-octylphthalate ug/L 55.750 111 44-170
Dibenz(a,h)anthracene ug/L 50.150 100 41-171
Dibenzofuran ug/L 42.250 84 42-157
Diethylphthalate ug/L 45.950 92 50-149
Dimethylphthalate ug/L 43.950 88 47-146
Fluoranthene ug/L 48.750 97 51-152
Fluorene ug/L 43.450 87 46-143
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 26 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4282601LABORATORY CONTROL SAMPLE:
LCSSpike
Hexachloro-1,3-butadiene ug/L 47.2 v1509410-130
Hexachlorobenzene ug/L 49.650 99 40-139
Hexachlorocyclopentadiene ug/L 48.350 97 10-130
Hexachloroethane ug/L 36.150 72 10-130
Indeno(1,2,3-cd)pyrene ug/L 49.450 99 40-172
Isophorone ug/L 45.350 91 37-143
N-Nitroso-di-n-propylamine ug/L 45.150 90 38-145
N-Nitrosodimethylamine ug/L 39.050 78 30-130
N-Nitrosodiphenylamine ug/L 44.150 88 46-144
Naphthalene ug/L 42.150 84 21-130
Nitrobenzene ug/L 44.850 90 33-136
Pentachlorophenol ug/L 92.2100 92 19-156
Phenanthrene ug/L 46.550 93 49-143
Phenol ug/L 30.050 60 18-130
Pyrene ug/L 52.350 105 48-156
2,4,6-Tribromophenol (S)%131 10-166
2-Fluorobiphenyl (S)%119 10-130
2-Fluorophenol (S)%87 10-130
Nitrobenzene-d5 (S)%115 10-133
Phenol-d6 (S)%68 10-130
Terphenyl-d14 (S)%134 10-193
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4282602MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92710202001
4282603
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L 100 58 10-13055 6 30100ND58.1 54.6
1,2-Dichlorobenzene ug/L 100 52 10-13048 7 30100ND51.7 48.1
1,3-Dichlorobenzene ug/L 100 51 10-13048 6 30100ND50.6 47.8
1,4-Dichlorobenzene ug/L 100 53 10-13047 12 30100ND54.4 48.3
1-Methylnaphthalene ug/L 100 69 10-13061 13 30100ND70.0 61.7
2,2'-Oxybis(1-
chloropropane)
ug/L 100 75 10-13266 14 30100ND75.5 65.9
2,4,5-Trichlorophenol ug/L 100 90 10-17473 20 30100ND89.9 73.3
2,4,6-Trichlorophenol ug/L R11008810-17364 32 30100ND88.5 64.3
2,4-Dichlorophenol ug/L 100 76 10-15362 21 30100ND75.9 61.5
2,4-Dimethylphenol ug/L 100 83 12-15768 19 30100ND82.8 68.5
2,4-Dinitrophenol ug/L 500 31 10-16512 30500ND15459.2J
2,4-Dinitrotoluene ug/L 100 80 29-16867 17 30100ND79.7 67.5
2,6-Dinitrotoluene ug/L 100 85 28-16870 19 30100ND84.6 70.3
2-Chloronaphthalene ug/L 100 76 11-13662 20 30100ND76.5 62.5
2-Chlorophenol ug/L 100 78 10-13465 18 30100ND78.3 65.1
2-Methylnaphthalene ug/L 100 70 10-13160 14 30100ND71.1 61.6
2-Methylphenol(o-Cresol)ug/L 100 75 10-13062 19 30100ND74.8 61.6
2-Nitroaniline ug/L 200 77 19-15663 20 30200ND153126
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/05/2024 01:55 PM
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 27 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4282602MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92710202001
4282603
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2-Nitrophenol ug/L 100 79 10-16066 19 30100ND79.4 65.6
3&4-Methylphenol(m&p
Cresol)ug/L 100 74 10-13260 21 30100ND73.8 59.9
3,3'-Dichlorobenzidine ug/L 200 77 10-17372 6 30200ND154145
3-Nitroaniline ug/L 200 73 19-16966 9 30200ND145133
4,6-Dinitro-2-methylphenol ug/L R12006110-17837 50 30200ND12273.0
4-Bromophenylphenyl ether ug/L 100 83 28-14970 17 30100ND82.7 69.8
4-Chloro-3-methylphenol ug/L 200 80 18-14867 17 30200ND160134
4-Chloroaniline ug/L 200 76 10-14165 16 30200ND151129
4-Chlorophenylphenyl ether ug/L 100 83 24-14465 24 30100ND83.2 65.4
4-Nitroaniline ug/L 200 73 18-17067 8 30200ND146135
4-Nitrophenol ug/L 500 36 10-13019 30500ND18295.5J
Acenaphthene ug/L 100 76 18-14261 22 30100ND75.8 60.8
Acenaphthylene ug/L 100 78 18-14362 22 30100ND77.6 62.2
Aniline ug/L 100 70 10-13057 20 30100ND70.1 57.4
Anthracene ug/L 100 72 32-13863 14 30100ND72.0 62.7
Benzo(a)anthracene ug/L 100 76 41-15575 2 30100ND76.4 74.8
Benzo(a)pyrene ug/L 100 79 10-16775 5 30100ND78.8 75.1
Benzo(b)fluoranthene ug/L 100 76 31-17276 1 30100ND75.9 76.3
Benzo(g,h,i)perylene ug/L 100 77 26-17775 3 30100ND77.0 74.6
Benzo(k)fluoranthene ug/L 100 74 31-16874 0 30100ND73.8 73.5
Benzoic Acid ug/L M1500510-1304 30500NDNDND
Benzyl alcohol ug/L 200 80 10-13666 18 30200ND159133
bis(2-
Chloroethoxy)methane
ug/L 100 81 12-14367 19 30100ND80.5 66.6
bis(2-Chloroethyl) ether ug/L 100 79 10-13967 15 30100ND78.6 67.3
bis(2-Ethylhexyl)phthalate ug/L 100 88 41-17382 7 30100ND87.9 81.9
Butylbenzylphthalate ug/L 100 89 38-18282 8 30100ND88.7 82.1
Chrysene ug/L 100 75 41-15269 8 30100ND74.8 69.2
Di-n-butylphthalate ug/L 100 79 37-16274 6 30100ND78.7 74.4
Di-n-octylphthalate ug/L 100 88 36-17683 6 30100ND88.2 82.8
Dibenz(a,h)anthracene ug/L 100 77 29-17573 5 30100ND76.7 73.2
Dibenzofuran ug/L 100 76 23-14462 19 30100ND75.5 62.2
Diethylphthalate ug/L 100 77 33-15464 18 30100ND76.5 64.1
Dimethylphthalate ug/L 100 80 29-15065 20 30100ND79.8 65.1
Fluoranthene ug/L 100 74 40-15670 5 30100ND73.5 69.8
Fluorene ug/L 100 77 26-14862 22 30100ND76.5 61.6
Hexachloro-1,3-butadiene ug/L 100 55 10-13052 6 30100ND55.1 51.8
Hexachlorobenzene ug/L 100 77 27-14566 15 30100ND77.1 66.1
Hexachlorocyclopentadiene ug/L v11005810-13047 20 30100ND57.5 46.8
Hexachloroethane ug/L 100 49 10-13045 9 30100ND48.9 44.5
Indeno(1,2,3-cd)pyrene ug/L 100 74 28-17671 3 30100ND73.7 71.4
Isophorone ug/L 100 76 14-14562 20 30100ND76.5 62.3
N-Nitroso-di-n-propylamine ug/L 100 83 12-14967 21 30100ND82.6 66.7
N-Nitrosodimethylamine ug/L 100 63 10-13052 18 30100ND62.8 52.5
N-Nitrosodiphenylamine ug/L 100 79 29-14969 13 30100ND78.7 68.9
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710045
R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4282602MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92710202001
4282603
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Naphthalene ug/L 100 67 10-13052 24 30100ND72.5 57.2
Nitrobenzene ug/L 100 73 10-14562 16 30100ND72.8 62.1
Pentachlorophenol ug/L 200 67 10-17850 28 30200ND133101
Phenanthrene ug/L 100 74 36-14666 12 30100ND73.9 65.8
Phenol ug/L 100 54 10-13040 27 30100ND55.8 42.4
Pyrene ug/L 100 81 42-15673 12 30100ND81.5 72.6
2,4,6-Tribromophenol (S)%107 10-16692
2-Fluorobiphenyl (S)%97 10-13080
2-Fluorophenol (S)%74 10-13062
Nitrobenzene-d5 (S)%95 10-13381
Phenol-d6 (S)%61 10-13051
Terphenyl-d14 (S)%98 10-19395
REPORT OF LABORATORY ANALYSIS
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92710045
R23-56
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
SAMPLE QUALIFIERS
Sample: 92710045001
TPH by Method MADEPE - Surrogate failure due to matrix interference during extraction procedure.[1]
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
RPD value was outside control limits.R1
Surrogate recovery was below laboratory control limits. Results may be biased low.SR
The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.v1
The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.v2
The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.v3
REPORT OF LABORATORY ANALYSIS
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92710045
R23-56
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92710045001 2216809 2216809B-1 MA DEP/NJ DEP MADEP EPH
92710045001 829497B-1 MADEP VPH
92710045001 828334 828393B-1 EPA 3510C EPA 8270E
92710045001 829190B-1 SM 6200B
92710045001 828303B-1 EPA 8260D
REPORT OF LABORATORY ANALYSIS
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Page 32 of 34
Page 33 of 34
Page 34 of 34
#=CL#
February 08, 2024
LIMS USE: FR - PHIL RAHN
LIMS OBJECT ID: 92710776
92710776
Project:
Pace Project No.:
RE:
Mr. Phil Rahn
Waters Edge Environmental
1434 Chester Road
Raleigh, NC 27606
304 E Main - Jamestown 1/29
Dear Mr. Rahn:
Enclosed are the analytical results for sample(s) received by the laboratory on January 30, 2024. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
Project Manager
704-977-0942
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Eden, NC 27288
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Page 1 of 17
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92710776
304 E Main - Jamestown 1/29
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92710776
304 E Main - Jamestown 1/29
Lab ID Sample ID Matrix Date Collected Date Received
92710776001 B-2 Water 01/29/24 11:00 01/30/24 14:42
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92710776
304 E Main - Jamestown 1/29
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92710776001 B-2 EPA 8260D 63 PASI-CLMB
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
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Eden, NC 27288
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92710776
304 E Main - Jamestown 1/29
Sample:B-2 Lab ID:92710776001 Collected:01/29/24 11:00 Received:01/30/24 14:42 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
Acetone ND ug/L 02/06/24 19:48 67-64-125.0 5.1 1
Benzene ND ug/L 02/06/24 19:48 71-43-21.0 0.34 1
Bromobenzene ND ug/L 02/06/24 19:48 108-86-11.0 0.29 1
Bromochloromethane ND ug/L 02/06/24 19:48 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 02/06/24 19:48 75-27-41.0 0.31 1
Bromoform ND ug/L 02/06/24 19:48 75-25-21.0 0.34 1
Bromomethane ND ug/L 02/06/24 19:48 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 02/06/24 19:48 78-93-35.0 4.0 1
Carbon tetrachloride ND ug/L 02/06/24 19:48 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 02/06/24 19:48 108-90-71.0 0.28 1
Chloroethane ND ug/L 02/06/24 19:48 75-00-31.0 0.65 1
Chloroform ND ug/L 02/06/24 19:48 67-66-31.0 0.43 1
Chloromethane ND ug/L 02/06/24 19:48 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 02/06/24 19:48 95-49-81.0 0.32 1
4-Chlorotoluene ND ug/L 02/06/24 19:48 106-43-41.0 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 02/06/24 19:48 96-12-82.0 0.34 1
Dibromochloromethane ND ug/L 02/06/24 19:48 124-48-11.0 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 02/06/24 19:48 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/06/24 19:48 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 02/06/24 19:48 95-50-11.0 0.34 1
1,3-Dichlorobenzene ND ug/L 02/06/24 19:48 541-73-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 02/06/24 19:48 106-46-71.0 0.33 1
Dichlorodifluoromethane ND ug/L 02/06/24 19:48 75-71-81.0 0.35 1
1,1-Dichloroethane ND ug/L 02/06/24 19:48 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 02/06/24 19:48 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 02/06/24 19:48 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 02/06/24 19:48 156-59-21.0 0.38 1
trans-1,2-Dichloroethene ND ug/L 02/06/24 19:48 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 02/06/24 19:48 78-87-51.0 0.36 1
1,3-Dichloropropane ND ug/L 02/06/24 19:48 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/06/24 19:48 594-20-71.0 0.39 1
1,1-Dichloropropene ND ug/L 02/06/24 19:48 563-58-61.0 0.43 1
cis-1,3-Dichloropropene ND ug/L 02/06/24 19:48 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 02/06/24 19:48 10061-02-61.0 0.36 1
Diisopropyl ether ND ug/L 02/06/24 19:48 108-20-31.0 0.31 1
Ethylbenzene ND ug/L 02/06/24 19:48 100-41-41.0 0.30 1
Hexachloro-1,3-butadiene ND ug/L 02/06/24 19:48 87-68-32.0 1.5 1
2-Hexanone ND ug/L 02/06/24 19:48 591-78-65.0 0.48 1
p-Isopropyltoluene ND ug/L 02/06/24 19:48 99-87-61.0 0.41 1
Methylene Chloride ND ug/L 02/06/24 19:48 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/06/24 19:48 108-10-15.0 2.7 1
Methyl-tert-butyl ether ND ug/L 02/06/24 19:48 1634-04-41.0 0.42 1
Naphthalene ND ug/L 02/06/24 19:48 91-20-31.0 0.64 1
Styrene ND ug/L 02/06/24 19:48 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 02/06/24 19:48 630-20-61.0 0.31 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/08/2024 07:58 PM
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92710776
304 E Main - Jamestown 1/29
Sample:B-2 Lab ID:92710776001 Collected:01/29/24 11:00 Received:01/30/24 14:42 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
1,1,2,2-Tetrachloroethane ND ug/L 02/06/24 19:48 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 02/06/24 19:48 127-18-41.0 0.29 1
Toluene ND ug/L 02/06/24 19:48 108-88-31.0 0.24 1
1,2,3-Trichlorobenzene ND ug/L 02/06/24 19:48 87-61-61.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 02/06/24 19:48 120-82-11.0 0.64 1
1,1,1-Trichloroethane ND ug/L 02/06/24 19:48 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 02/06/24 19:48 79-00-51.0 0.32 1
Trichloroethene ND ug/L 02/06/24 19:48 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 02/06/24 19:48 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 02/06/24 19:48 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 02/06/24 19:48 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 02/06/24 19:48 75-01-41.0 0.39 1
Xylene (Total)ND ug/L 02/06/24 19:48 1330-20-71.0 0.34 1
m&p-Xylene ND ug/L 02/06/24 19:48 179601-23-12.0 0.71 1
o-Xylene ND ug/L 02/06/24 19:48 95-47-61.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)96 %02/06/24 19:48 460-00-470-130 1
1,2-Dichloroethane-d4 (S)91 %02/06/24 19:48 17060-07-070-130 1
Toluene-d8 (S)99 %02/06/24 19:48 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710776
304 E Main - Jamestown 1/29
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
830164
EPA 8260D
EPA 8260D
8260D MSV Low Level
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92710776001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4290658
Associated Lab Samples:92710776001
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 02/06/24 17:080.31
1,1,1-Trichloroethane ug/L ND 1.0 02/06/24 17:080.33
1,1,2,2-Tetrachloroethane ug/L ND 1.0 02/06/24 17:080.22
1,1,2-Trichloroethane ug/L ND 1.0 02/06/24 17:080.32
1,1-Dichloroethane ug/L ND 1.0 02/06/24 17:080.37
1,1-Dichloroethene ug/L ND 1.0 02/06/24 17:080.35
1,1-Dichloropropene ug/L ND 1.0 02/06/24 17:080.43
1,2,3-Trichlorobenzene ug/L ND 1.0 02/06/24 17:080.81
1,2,3-Trichloropropane ug/L ND 1.0 02/06/24 17:080.26
1,2,4-Trichlorobenzene ug/L ND 1.0 02/06/24 17:080.64
1,2-Dibromo-3-chloropropane ug/L ND 2.0 02/06/24 17:080.34
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/06/24 17:080.27
1,2-Dichlorobenzene ug/L ND 1.0 02/06/24 17:080.34
1,2-Dichloroethane ug/L ND 1.0 02/06/24 17:080.32
1,2-Dichloropropane ug/L ND 1.0 02/06/24 17:080.36
1,3-Dichlorobenzene ug/L ND 1.0 02/06/24 17:080.34
1,3-Dichloropropane ug/L ND 1.0 02/06/24 17:080.28
1,4-Dichlorobenzene ug/L ND 1.0 02/06/24 17:080.33
2,2-Dichloropropane ug/L ND 1.0 02/06/24 17:080.39
2-Butanone (MEK)ug/L ND 5.0 02/06/24 17:084.0
2-Chlorotoluene ug/L ND 1.0 02/06/24 17:080.32
2-Hexanone ug/L ND 5.0 02/06/24 17:080.48
4-Chlorotoluene ug/L ND 1.0 02/06/24 17:080.32
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 02/06/24 17:082.7
Acetone ug/L ND 25.0 02/06/24 17:085.1
Benzene ug/L ND 1.0 02/06/24 17:080.34
Bromobenzene ug/L ND 1.0 02/06/24 17:080.29
Bromochloromethane ug/L ND 1.0 02/06/24 17:080.47
Bromodichloromethane ug/L ND 1.0 02/06/24 17:080.31
Bromoform ug/L ND 1.0 02/06/24 17:080.34
Bromomethane ug/L ND 2.0 v202/06/24 17:081.7
Carbon tetrachloride ug/L ND 1.0 02/06/24 17:080.33
Chlorobenzene ug/L ND 1.0 02/06/24 17:080.28
Chloroethane ug/L ND 1.0 02/06/24 17:080.65
Chloroform ug/L ND 1.0 02/06/24 17:080.43
Chloromethane ug/L ND 1.0 02/06/24 17:080.54
cis-1,2-Dichloroethene ug/L ND 1.0 02/06/24 17:080.38
cis-1,3-Dichloropropene ug/L ND 1.0 02/06/24 17:080.36
Dibromochloromethane ug/L ND 1.0 02/06/24 17:080.36
Dibromomethane ug/L ND 1.0 02/06/24 17:080.39
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710776
304 E Main - Jamestown 1/29
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4290658
Associated Lab Samples:92710776001
Matrix:Water
AnalyzedMDL
Dichlorodifluoromethane ug/L ND 1.0 02/06/24 17:080.35
Diisopropyl ether ug/L ND 1.0 02/06/24 17:080.31
Ethylbenzene ug/L ND 1.0 02/06/24 17:080.30
Hexachloro-1,3-butadiene ug/L ND 2.0 02/06/24 17:081.5
m&p-Xylene ug/L ND 2.0 02/06/24 17:080.71
Methyl-tert-butyl ether ug/L ND 1.0 02/06/24 17:080.42
Methylene Chloride ug/L ND 5.0 02/06/24 17:082.0
Naphthalene ug/L ND 1.0 02/06/24 17:080.64
o-Xylene ug/L ND 1.0 02/06/24 17:080.34
p-Isopropyltoluene ug/L ND 1.0 02/06/24 17:080.41
Styrene ug/L ND 1.0 02/06/24 17:080.29
Tetrachloroethene ug/L ND 1.0 02/06/24 17:080.29
Toluene ug/L ND 1.0 02/06/24 17:080.24
trans-1,2-Dichloroethene ug/L ND 1.0 02/06/24 17:080.40
trans-1,3-Dichloropropene ug/L ND 1.0 02/06/24 17:080.36
Trichloroethene ug/L ND 1.0 02/06/24 17:080.38
Trichlorofluoromethane ug/L ND 1.0 02/06/24 17:080.30
Vinyl acetate ug/L ND 2.0 02/06/24 17:081.3
Vinyl chloride ug/L ND 1.0 02/06/24 17:080.39
Xylene (Total)ug/L ND 1.0 02/06/24 17:080.34
1,2-Dichloroethane-d4 (S)%88 70-130 02/06/24 17:08
4-Bromofluorobenzene (S)%93 70-130 02/06/24 17:08
Toluene-d8 (S)%97 70-130 02/06/24 17:08
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4290659LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 20.920 105 70-130
1,1,1-Trichloroethane ug/L 19.220 96 70-130
1,1,2,2-Tetrachloroethane ug/L 22.520 113 70-130
1,1,2-Trichloroethane ug/L 21.720 108 70-130
1,1-Dichloroethane ug/L 20.520 102 70-130
1,1-Dichloroethene ug/L 20.920 105 69-131
1,1-Dichloropropene ug/L 20.720 104 70-132
1,2,3-Trichlorobenzene ug/L 23.820 119 70-132
1,2,3-Trichloropropane ug/L 19.720 99 70-130
1,2,4-Trichlorobenzene ug/L 22.420 112 70-130
1,2-Dibromo-3-chloropropane ug/L 19.020 95 70-130
1,2-Dibromoethane (EDB)ug/L 20.520 103 70-130
1,2-Dichlorobenzene ug/L 22.620 113 70-130
1,2-Dichloroethane ug/L 18.520 92 70-130
1,2-Dichloropropane ug/L 20.620 103 70-130
1,3-Dichlorobenzene ug/L 22.820 114 70-130
1,3-Dichloropropane ug/L 20.720 104 70-130
REPORT OF LABORATORY ANALYSIS
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Page 8 of 17
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710776
304 E Main - Jamestown 1/29
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4290659LABORATORY CONTROL SAMPLE:
LCSSpike
1,4-Dichlorobenzene ug/L 22.320 112 70-130
2,2-Dichloropropane ug/L 21.120 105 69-130
2-Butanone (MEK)ug/L 37.140 93 67-133
2-Chlorotoluene ug/L 21.820 109 70-130
2-Hexanone ug/L 40.140 100 70-133
4-Chlorotoluene ug/L 21.920 110 70-130
4-Methyl-2-pentanone (MIBK)ug/L 37.540 94 70-130
Acetone ug/L 36.640 92 67-130
Benzene ug/L 21.020 105 70-130
Bromobenzene ug/L 21.120 105 70-130
Bromochloromethane ug/L 21.720 109 70-130
Bromodichloromethane ug/L 18.720 94 70-130
Bromoform ug/L 17.620 88 70-133
Bromomethane ug/L 14.9 v3207541-148
Carbon tetrachloride ug/L 19.620 98 70-130
Chlorobenzene ug/L 21.520 107 70-130
Chloroethane ug/L 21.320 106 41-157
Chloroform ug/L 19.320 96 70-130
Chloromethane ug/L 22.120 110 59-141
cis-1,2-Dichloroethene ug/L 20.220 101 70-130
cis-1,3-Dichloropropene ug/L 20.120 101 70-130
Dibromochloromethane ug/L 21.020 105 70-130
Dibromomethane ug/L 19.720 98 70-130
Dichlorodifluoromethane ug/L 18.020 90 54-147
Diisopropyl ether ug/L 18.620 93 70-130
Ethylbenzene ug/L 21.120 106 70-130
Hexachloro-1,3-butadiene ug/L 21.520 107 70-134
m&p-Xylene ug/L 42.340 106 70-130
Methyl-tert-butyl ether ug/L 19.120 96 70-130
Methylene Chloride ug/L 19.420 97 62-130
Naphthalene ug/L 23.420 117 70-135
o-Xylene ug/L 21.420 107 70-130
p-Isopropyltoluene ug/L 23.320 116 70-130
Styrene ug/L 21.920 110 70-130
Tetrachloroethene ug/L 21.220 106 70-130
Toluene ug/L 20.720 103 70-130
trans-1,2-Dichloroethene ug/L 21.120 105 70-130
trans-1,3-Dichloropropene ug/L 19.420 97 70-130
Trichloroethene ug/L 21.020 105 70-130
Trichlorofluoromethane ug/L 18.920 94 57-130
Vinyl acetate ug/L 39.340 98 70-141
Vinyl chloride ug/L 19.820 99 66-140
Xylene (Total)ug/L 63.760 106 70-130
1,2-Dichloroethane-d4 (S)%88 70-130
4-Bromofluorobenzene (S)%95 70-130
Toluene-d8 (S)%98 70-130
REPORT OF LABORATORY ANALYSIS
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Page 9 of 17
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710776
304 E Main - Jamestown 1/29
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4290660MATRIX SPIKE SAMPLE:
MSSpike
Result
92711055002
1,1,1,2-Tetrachloroethane ug/L 23.420 117 70-146ND
1,1,1-Trichloroethane ug/L 23.020 115 70-150ND
1,1,2,2-Tetrachloroethane ug/L 23.520 118 66-144ND
1,1,2-Trichloroethane ug/L 23.020 115 70-142ND
1,1-Dichloroethane ug/L 24.220 121 68-150ND
1,1-Dichloroethene ug/L 25.220 126 64-162ND
1,1-Dichloropropene ug/L 24.420 122 70-160ND
1,2,3-Trichlorobenzene ug/L 23.020 115 66-151ND
1,2,3-Trichloropropane ug/L 21.820 109 66-144ND
1,2,4-Trichlorobenzene ug/L 22.720 114 69-147ND
1,2-Dibromo-3-chloropropane ug/L 18.620 93 62-146ND
1,2-Dibromoethane (EDB)ug/L 22.720 114 70-143ND
1,2-Dichlorobenzene ug/L 23.520 117 70-142ND
1,2-Dichloroethane ug/L 20.720 104 68-145ND
1,2-Dichloropropane ug/L 22.920 115 70-144ND
1,3-Dichlorobenzene ug/L 24.1 v12012070-142ND
1,3-Dichloropropane ug/L 22.920 114 70-141ND
1,4-Dichlorobenzene ug/L 23.820 117 70-140ND
2,2-Dichloropropane ug/L 25.020 125 58-160ND
2-Butanone (MEK)ug/L 41.540 104 57-156ND
2-Chlorotoluene ug/L 23.620 118 70-148ND
2-Hexanone ug/L 45.040 113 62-153ND
4-Chlorotoluene ug/L 23.420 117 70-144ND
4-Methyl-2-pentanone (MIBK)ug/L 39.940 100 65-144ND
Acetone ug/L 57.840 100 49-162ND
Benzene ug/L 24.120 121 68-144ND
Bromobenzene ug/L 22.220 111 70-144ND
Bromochloromethane ug/L 24.320 122 70-148ND
Bromodichloromethane ug/L 21.720 104 70-141ND
Bromoform ug/L 18.920 95 59-144ND
Bromomethane ug/L 19.6 v3209823-190ND
Carbon tetrachloride ug/L 23.320 116 70-147ND
Chlorobenzene ug/L 24.220 121 70-143ND
Chloroethane ug/L 25.520 127 55-190ND
Chloroform ug/L 34.420 116 67-14811.2
Chloromethane ug/L 26.620 133 38-180ND
cis-1,2-Dichloroethene ug/L 23.020 115 67-151ND
cis-1,3-Dichloropropene ug/L 22.320 112 70-142ND
Dibromochloromethane ug/L 22.720 113 68-140ND
Dibromomethane ug/L 22.120 111 70-142ND
Dichlorodifluoromethane ug/L 21.120 105 15-200ND
Diisopropyl ether ug/L 20.920 104 62-149ND
Ethylbenzene ug/L 23.720 119 70-145ND
Hexachloro-1,3-butadiene ug/L 24.820 124 64-164ND
m&p-Xylene ug/L 47.740 119 70-148ND
Methyl-tert-butyl ether ug/L 20.020 100 64-146ND
Methylene Chloride ug/L 22.120 111 54-149ND
REPORT OF LABORATORY ANALYSIS
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Page 10 of 17
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710776
304 E Main - Jamestown 1/29
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4290660MATRIX SPIKE SAMPLE:
MSSpike
Result
92711055002
Naphthalene ug/L 21.620 108 62-154ND
o-Xylene ug/L 24.020 120 70-145ND
p-Isopropyltoluene ug/L 26.120 131 70-153ND
Styrene ug/L 24.120 121 70-147ND
Tetrachloroethene ug/L 24.320 122 70-145ND
Toluene ug/L 23.120 115 65-146ND
trans-1,2-Dichloroethene ug/L 24.720 124 69-155ND
trans-1,3-Dichloropropene ug/L 20.720 104 70-142ND
Trichloroethene ug/L 23.720 119 70-152ND
Trichlorofluoromethane ug/L 23.120 116 60-158ND
Vinyl acetate ug/L 41.740 104 56-157ND
Vinyl chloride ug/L 24.620 123 51-178ND
Xylene (Total)ug/L 71.760 120 70-146ND
1,2-Dichloroethane-d4 (S)%90 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92711413001
4290661SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,1-Dichloropropene ug/L ND 30ND
1,2,3-Trichlorobenzene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2,4-Trichlorobenzene ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichlorobenzene ug/L ND v130ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2,2-Dichloropropane ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Chlorotoluene ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Chlorotoluene ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92710776
304 E Main - Jamestown 1/29
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92711413001
4290661SAMPLE DUPLICATE:
Benzene ug/L ND 30ND
Bromobenzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND v230ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Diisopropyl ether ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Hexachloro-1,3-butadiene ug/L ND 30ND
m&p-Xylene ug/L ND 30ND
Methyl-tert-butyl ether ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Naphthalene ug/L ND 30ND
o-Xylene ug/L ND 30ND
p-Isopropyltoluene ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L 2.0 4 301.9
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%9290
4-Bromofluorobenzene (S)%9591
Toluene-d8 (S)%9897
REPORT OF LABORATORY ANALYSIS
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Page 12 of 17
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92710776
304 E Main - Jamestown 1/29
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.v1
The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.v2
The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.v3
REPORT OF LABORATORY ANALYSIS
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205 East Meadow Road - Suite A
Eden, NC 27288
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Page 13 of 17
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92710776
304 E Main - Jamestown 1/29
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92710776001 830164B-2 EPA 8260D
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/08/2024 07:58 PM
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Page 14 of 17
Page 15 of 17
Page 16 of 17
Page 17 of 17
#=CL#
March 18, 2024
LIMS USE: FR - PHIL RAHN
LIMS OBJECT ID: 92716288
92716288
Project:
Pace Project No.:
RE:
Mr. Phil Rahn
Waters Edge Environmental
1434 Chester Road
Raleigh, NC 27606
304 E.MAIN R23-56
Dear Mr. Rahn:
Enclosed are the analytical results for sample(s) received by the laboratory on March 01, 2024. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
Project Manager
704-977-0942
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 1 of 31
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
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Eden, NC 27288
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Page 2 of 31
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Lab ID Sample ID Matrix Date Collected Date Received
92716288001 B-1 Water 02/29/24 09:45 03/01/24 08:00
92716288002 B-2 Water 02/29/24 11:00 03/01/24 08:00
REPORT OF LABORATORY ANALYSIS
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Eden, NC 27288
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Page 3 of 31
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92716288001 B-1 MADEP EPH 7 PASI-CBAJ
MADEP VPH 5 PASI-CTEG
EPA 8270E 74 PASI-CPKS
EPA 8260D 63 PASI-CTMH
92716288002 B-2 MADEP VPH 5 PASI-CTEG
EPA 8270E 74 PASI-CPKS
EPA 8260D 63 PASI-CTMH
PASI-C = Pace Analytical Services - Charlotte
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Eden, NC 27288
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Page 4 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Sample:B-1 Lab ID:92716288001 Collected:02/29/24 09:45 Received:03/01/24 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Pace Analytical Services - Charlotte
MADEP EPH NC Water
Aliphatic (C09-C18)ND ug/L 03/07/24 13:30 N203/05/24 17:3198.0 98.0 1
Aliphatic (C19-C36)ND ug/L 03/07/24 13:30 N203/05/24 17:3198.0 98.0 1
Aromatic (C11-C22)ND ug/L 03/07/24 13:30 N203/05/24 17:3198.0 98.0 1
Surrogates
1-Chlorooctadecane (S)48 %03/07/24 13:30 3386-33-203/05/24 17:3140-140 1
o-Terphenyl (S)92 %03/07/24 13:30 84-15-103/05/24 17:3140-140 1
2-Fluorobiphenyl (S)101 %03/07/24 13:30 321-60-803/05/24 17:3140-140 1
2-Bromonaphthalene (S)102 %03/07/24 13:30 580-13-203/05/24 17:3140-140 1
Analytical Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Water
Aliphatic (C05-C08),Unadjusted 138 ug/L 03/15/24 17:17 H1,N21001001
Aliphatic(C09-C12) Adjusted ND ug/L 03/15/24 17:17 N21001001
Aromatic (C09-C10)ND ug/L 03/15/24 17:17 H1,N21001001
Surrogates
2,5-Dibromotoluene (FID)(S)97 %03/15/24 17:1770-130 1
2,5-Dibromotoluene (PID)(S)92 %03/15/24 17:1770-130 1
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8270E RVE
Acenaphthene ND ug/L 03/07/24 13:36 83-32-903/06/24 13:5510.0 2.0 1
Acenaphthylene ND ug/L 03/07/24 13:36 208-96-803/06/24 13:5510.0 2.0 1
Aniline ND ug/L 03/07/24 13:36 62-53-303/06/24 13:5510.0 1.6 1
Anthracene ND ug/L 03/07/24 13:36 120-12-703/06/24 13:5510.0 2.3 1
Benzo(a)anthracene ND ug/L 03/07/24 13:36 56-55-303/06/24 13:5510.0 2.7 1
Benzo(a)pyrene ND ug/L 03/07/24 13:36 50-32-803/06/24 13:5510.0 2.8 1
Benzo(b)fluoranthene ND ug/L 03/07/24 13:36 205-99-203/06/24 13:5510.0 2.6 1
Benzo(g,h,i)perylene ND ug/L 03/07/24 13:36 191-24-203/06/24 13:5510.0 2.8 1
Benzo(k)fluoranthene ND ug/L 03/07/24 13:36 207-08-903/06/24 13:5510.0 2.7 1
Benzoic Acid ND ug/L 03/07/24 13:36 65-85-003/06/24 13:5550.0 22.0 1
Benzyl alcohol ND ug/L 03/07/24 13:36 100-51-603/06/24 13:5520.0 2.9 1
4-Bromophenylphenyl ether ND ug/L 03/07/24 13:36 101-55-303/06/24 13:5510.0 1.8 1
Butylbenzylphthalate ND ug/L 03/07/24 13:36 85-68-703/06/24 13:5510.0 3.1 1
4-Chloro-3-methylphenol ND ug/L 03/07/24 13:36 59-50-703/06/24 13:5510.0 3.3 1
4-Chloroaniline ND ug/L 03/07/24 13:36 106-47-803/06/24 13:5520.0 3.6 1
bis(2-Chloroethoxy)methane ND ug/L 03/07/24 13:36 111-91-103/06/24 13:5510.0 1.8 1
bis(2-Chloroethyl) ether ND ug/L 03/07/24 13:36 111-44-403/06/24 13:5510.0 1.9 1
2-Chloronaphthalene ND ug/L 03/07/24 13:36 91-58-703/06/24 13:5510.0 1.7 1
2-Chlorophenol ND ug/L 03/07/24 13:36 95-57-803/06/24 13:5510.0 1.2 1
4-Chlorophenylphenyl ether ND ug/L 03/07/24 13:36 7005-72-303/06/24 13:5510.0 2.0 1
Chrysene ND ug/L 03/07/24 13:36 218-01-903/06/24 13:5510.0 2.8 1
Dibenz(a,h)anthracene ND ug/L 03/07/24 13:36 53-70-303/06/24 13:5510.0 3.0 1
Dibenzofuran ND ug/L 03/07/24 13:36 132-64-903/06/24 13:5510.0 2.1 1
1,2-Dichlorobenzene ND ug/L 03/07/24 13:36 95-50-103/06/24 13:5510.0 1.8 1
1,3-Dichlorobenzene ND ug/L 03/07/24 13:36 541-73-103/06/24 13:5510.0 1.6 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Sample:B-1 Lab ID:92716288001 Collected:02/29/24 09:45 Received:03/01/24 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8270E RVE
1,4-Dichlorobenzene ND ug/L 03/07/24 13:36 106-46-703/06/24 13:5510.0 1.7 1
3,3'-Dichlorobenzidine ND ug/L 03/07/24 13:36 91-94-103/06/24 13:5520.0 8.1 1
2,4-Dichlorophenol ND ug/L 03/07/24 13:36 120-83-203/06/24 13:5510.0 1.4 1
Diethylphthalate ND ug/L 03/07/24 13:36 84-66-203/06/24 13:5510.0 2.0 1
2,4-Dimethylphenol ND ug/L 03/07/24 13:36 105-67-903/06/24 13:5510.0 1.7 1
Dimethylphthalate ND ug/L 03/07/24 13:36 131-11-303/06/24 13:5510.0 2.1 1
Di-n-butylphthalate ND ug/L 03/07/24 13:36 84-74-203/06/24 13:5510.0 2.2 1
4,6-Dinitro-2-methylphenol ND ug/L 03/07/24 13:36 534-52-103/06/24 13:5520.0 7.8 1
2,4-Dinitrophenol ND ug/L 03/07/24 13:36 51-28-503/06/24 13:5550.0 26.0 1
2,4-Dinitrotoluene ND ug/L 03/07/24 13:36 121-14-203/06/24 13:5510.0 1.6 1
2,6-Dinitrotoluene ND ug/L 03/07/24 13:36 606-20-203/06/24 13:5510.0 1.7 1
Di-n-octylphthalate ND ug/L 03/07/24 13:36 117-84-003/06/24 13:5510.0 3.9 1
bis(2-Ethylhexyl)phthalate ND ug/L 03/07/24 13:36 117-81-703/06/24 13:556.0 3.7 1
Fluoranthene ND ug/L 03/07/24 13:36 206-44-003/06/24 13:5510.0 2.2 1
Fluorene ND ug/L 03/07/24 13:36 86-73-703/06/24 13:5510.0 2.1 1
Hexachloro-1,3-butadiene ND ug/L 03/07/24 13:36 87-68-303/06/24 13:5510.0 1.8 1
Hexachlorobenzene ND ug/L 03/07/24 13:36 118-74-103/06/24 13:5510.0 2.2 1
Hexachlorocyclopentadiene ND ug/L 03/07/24 13:36 77-47-4 v103/06/24 13:5510.0 1.6 1
Hexachloroethane ND ug/L 03/07/24 13:36 67-72-103/06/24 13:5510.0 1.4 1
Indeno(1,2,3-cd)pyrene ND ug/L 03/07/24 13:36 193-39-503/06/24 13:5510.0 2.9 1
Isophorone ND ug/L 03/07/24 13:36 78-59-103/06/24 13:5510.0 1.7 1
1-Methylnaphthalene ND ug/L 03/07/24 13:36 90-12-003/06/24 13:5510.0 2.0 1
2-Methylnaphthalene ND ug/L 03/07/24 13:36 91-57-603/06/24 13:5510.0 1.9 1
2-Methylphenol(o-Cresol)ND ug/L 03/07/24 13:36 95-48-703/06/24 13:5510.0 1.9 1
3&4-Methylphenol(m&p Cresol)ND ug/L 03/07/24 13:36 15831-10-403/06/24 13:5510.0 1.2 1
Naphthalene ND ug/L 03/07/24 13:36 91-20-303/06/24 13:5510.0 2.1 1
2-Nitroaniline ND ug/L 03/07/24 13:36 88-74-403/06/24 13:5520.0 3.0 1
3-Nitroaniline ND ug/L 03/07/24 13:36 99-09-203/06/24 13:5520.0 3.8 1
4-Nitroaniline ND ug/L 03/07/24 13:36 100-01-603/06/24 13:5520.0 5.1 1
Nitrobenzene ND ug/L 03/07/24 13:36 98-95-303/06/24 13:5510.0 1.9 1
2-Nitrophenol ND ug/L 03/07/24 13:36 88-75-503/06/24 13:5510.0 1.4 1
4-Nitrophenol ND ug/L 03/07/24 13:36 100-02-703/06/24 13:5550.0 6.6 1
N-Nitrosodimethylamine ND ug/L 03/07/24 13:36 62-75-903/06/24 13:5510.0 1.9 1
N-Nitroso-di-n-propylamine ND ug/L 03/07/24 13:36 621-64-703/06/24 13:5510.0 1.3 1
N-Nitrosodiphenylamine ND ug/L 03/07/24 13:36 86-30-603/06/24 13:5510.0 3.0 1
2,2'-Oxybis(1-chloropropane)ND ug/L 03/07/24 13:36 108-60-103/06/24 13:5510.0 1.2 1
Pentachlorophenol ND ug/L 03/07/24 13:36 87-86-503/06/24 13:5520.0 3.8 1
Phenanthrene ND ug/L 03/07/24 13:36 85-01-803/06/24 13:5510.0 2.0 1
Phenol ND ug/L 03/07/24 13:36 108-95-203/06/24 13:5510.0 1.4 1
Pyrene ND ug/L 03/07/24 13:36 129-00-003/06/24 13:5510.0 2.2 1
1,2,4-Trichlorobenzene ND ug/L 03/07/24 13:36 120-82-103/06/24 13:5510.0 1.7 1
2,4,5-Trichlorophenol ND ug/L 03/07/24 13:36 95-95-403/06/24 13:5510.0 1.4 1
2,4,6-Trichlorophenol ND ug/L 03/07/24 13:36 88-06-203/06/24 13:5510.0 1.6 1
Surrogates
Nitrobenzene-d5 (S)19 %03/07/24 13:36 4165-60-003/06/24 13:5510-133 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 6 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Sample:B-1 Lab ID:92716288001 Collected:02/29/24 09:45 Received:03/01/24 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8270E RVE
Surrogates
2-Fluorobiphenyl (S)16 %03/07/24 13:36 321-60-803/06/24 13:5510-130 1
Terphenyl-d14 (S)32 %03/07/24 13:36 1718-51-003/06/24 13:5510-193 1
Phenol-d6 (S)9 %03/07/24 13:36 13127-88-3 S003/06/24 13:5510-130 1
2-Fluorophenol (S)13 %03/07/24 13:36 367-12-403/06/24 13:5510-130 1
2,4,6-Tribromophenol (S)25 %03/07/24 13:36 118-79-603/06/24 13:5510-166 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
Acetone 26.9 ug/L 03/05/24 10:13 67-64-125.0 5.1 1
Benzene 9.6 ug/L 03/05/24 10:13 71-43-21.0 0.34 1
Bromobenzene ND ug/L 03/05/24 10:13 108-86-11.0 0.29 1
Bromochloromethane ND ug/L 03/05/24 10:13 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 03/05/24 10:13 75-27-41.0 0.31 1
Bromoform ND ug/L 03/05/24 10:13 75-25-21.0 0.34 1
Bromomethane ND ug/L 03/05/24 10:13 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 03/05/24 10:13 78-93-35.0 4.0 1
Carbon tetrachloride ND ug/L 03/05/24 10:13 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 03/05/24 10:13 108-90-71.0 0.28 1
Chloroethane ND ug/L 03/05/24 10:13 75-00-31.0 0.65 1
Chloroform ND ug/L 03/05/24 10:13 67-66-31.0 0.43 1
Chloromethane ND ug/L 03/05/24 10:13 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 03/05/24 10:13 95-49-81.0 0.32 1
4-Chlorotoluene ND ug/L 03/05/24 10:13 106-43-41.0 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 03/05/24 10:13 96-12-82.0 0.34 1
Dibromochloromethane ND ug/L 03/05/24 10:13 124-48-11.0 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 03/05/24 10:13 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/05/24 10:13 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 03/05/24 10:13 95-50-11.0 0.34 1
1,3-Dichlorobenzene ND ug/L 03/05/24 10:13 541-73-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 03/05/24 10:13 106-46-71.0 0.33 1
Dichlorodifluoromethane ND ug/L 03/05/24 10:13 75-71-81.0 0.35 1
1,1-Dichloroethane ND ug/L 03/05/24 10:13 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 03/05/24 10:13 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 03/05/24 10:13 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 03/05/24 10:13 156-59-21.0 0.38 1
trans-1,2-Dichloroethene ND ug/L 03/05/24 10:13 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 03/05/24 10:13 78-87-51.0 0.36 1
1,3-Dichloropropane ND ug/L 03/05/24 10:13 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 03/05/24 10:13 594-20-71.0 0.39 1
1,1-Dichloropropene ND ug/L 03/05/24 10:13 563-58-61.0 0.43 1
cis-1,3-Dichloropropene ND ug/L 03/05/24 10:13 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 03/05/24 10:13 10061-02-61.0 0.36 1
Diisopropyl ether 5.2 ug/L 03/05/24 10:13 108-20-31.0 0.31 1
Ethylbenzene ND ug/L 03/05/24 10:13 100-41-41.0 0.30 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 7 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Sample:B-1 Lab ID:92716288001 Collected:02/29/24 09:45 Received:03/01/24 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
Hexachloro-1,3-butadiene ND ug/L 03/05/24 10:13 87-68-32.0 1.5 1
2-Hexanone ND ug/L 03/05/24 10:13 591-78-65.0 0.48 1
p-Isopropyltoluene ND ug/L 03/05/24 10:13 99-87-61.0 0.41 1
Methylene Chloride ND ug/L 03/05/24 10:13 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/05/24 10:13 108-10-15.0 2.7 1
Methyl-tert-butyl ether 4.0 ug/L 03/05/24 10:13 1634-04-41.0 0.42 1
Naphthalene ND ug/L 03/05/24 10:13 91-20-31.0 0.64 1
Styrene ND ug/L 03/05/24 10:13 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 03/05/24 10:13 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 03/05/24 10:13 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 03/05/24 10:13 127-18-41.0 0.29 1
Toluene 1.1 ug/L 03/05/24 10:13 108-88-31.0 0.24 1
1,2,3-Trichlorobenzene ND ug/L 03/05/24 10:13 87-61-61.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 03/05/24 10:13 120-82-11.0 0.64 1
1,1,1-Trichloroethane ND ug/L 03/05/24 10:13 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 03/05/24 10:13 79-00-51.0 0.32 1
Trichloroethene ND ug/L 03/05/24 10:13 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 03/05/24 10:13 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 03/05/24 10:13 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 03/05/24 10:13 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 03/05/24 10:13 75-01-41.0 0.39 1
Xylene (Total)ND ug/L 03/05/24 10:13 1330-20-71.0 0.34 1
m&p-Xylene ND ug/L 03/05/24 10:13 179601-23-12.0 0.71 1
o-Xylene ND ug/L 03/05/24 10:13 95-47-61.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)101 %03/05/24 10:13 460-00-470-130 1
1,2-Dichloroethane-d4 (S)119 %03/05/24 10:13 17060-07-070-130 1
Toluene-d8 (S)104 %03/05/24 10:13 2037-26-570-130 1
Sample:B-2 Lab ID:92716288002 Collected:02/29/24 11:00 Received:03/01/24 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Water
Aliphatic (C05-C08),Unadjusted ND ug/L 03/15/24 16:47 H1,N21001001
Aliphatic(C09-C12) Adjusted ND ug/L 03/15/24 16:47 N21001001
Aromatic (C09-C10)ND ug/L 03/15/24 16:47 H1,N21001001
Surrogates
2,5-Dibromotoluene (FID)(S)93 %03/15/24 16:4770-130 1
2,5-Dibromotoluene (PID)(S)89 %03/15/24 16:4770-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 8 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Sample:B-2 Lab ID:92716288002 Collected:02/29/24 11:00 Received:03/01/24 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8270E RVE
Acenaphthene ND ug/L 03/07/24 14:01 83-32-903/06/24 13:5510.0 2.0 1
Acenaphthylene ND ug/L 03/07/24 14:01 208-96-803/06/24 13:5510.0 2.0 1
Aniline ND ug/L 03/07/24 14:01 62-53-303/06/24 13:5510.0 1.6 1
Anthracene ND ug/L 03/07/24 14:01 120-12-703/06/24 13:5510.0 2.3 1
Benzo(a)anthracene ND ug/L 03/07/24 14:01 56-55-303/06/24 13:5510.0 2.7 1
Benzo(a)pyrene ND ug/L 03/07/24 14:01 50-32-803/06/24 13:5510.0 2.8 1
Benzo(b)fluoranthene ND ug/L 03/07/24 14:01 205-99-203/06/24 13:5510.0 2.6 1
Benzo(g,h,i)perylene ND ug/L 03/07/24 14:01 191-24-203/06/24 13:5510.0 2.8 1
Benzo(k)fluoranthene ND ug/L 03/07/24 14:01 207-08-903/06/24 13:5510.0 2.7 1
Benzoic Acid ND ug/L 03/07/24 14:01 65-85-003/06/24 13:5550.0 22.0 1
Benzyl alcohol ND ug/L 03/07/24 14:01 100-51-603/06/24 13:5520.0 2.9 1
4-Bromophenylphenyl ether ND ug/L 03/07/24 14:01 101-55-303/06/24 13:5510.0 1.8 1
Butylbenzylphthalate ND ug/L 03/07/24 14:01 85-68-703/06/24 13:5510.0 3.1 1
4-Chloro-3-methylphenol ND ug/L 03/07/24 14:01 59-50-703/06/24 13:5510.0 3.3 1
4-Chloroaniline ND ug/L 03/07/24 14:01 106-47-803/06/24 13:5520.0 3.6 1
bis(2-Chloroethoxy)methane ND ug/L 03/07/24 14:01 111-91-103/06/24 13:5510.0 1.8 1
bis(2-Chloroethyl) ether ND ug/L 03/07/24 14:01 111-44-403/06/24 13:5510.0 1.9 1
2-Chloronaphthalene ND ug/L 03/07/24 14:01 91-58-703/06/24 13:5510.0 1.7 1
2-Chlorophenol ND ug/L 03/07/24 14:01 95-57-803/06/24 13:5510.0 1.2 1
4-Chlorophenylphenyl ether ND ug/L 03/07/24 14:01 7005-72-303/06/24 13:5510.0 2.0 1
Chrysene ND ug/L 03/07/24 14:01 218-01-903/06/24 13:5510.0 2.8 1
Dibenz(a,h)anthracene ND ug/L 03/07/24 14:01 53-70-303/06/24 13:5510.0 3.0 1
Dibenzofuran ND ug/L 03/07/24 14:01 132-64-903/06/24 13:5510.0 2.1 1
1,2-Dichlorobenzene ND ug/L 03/07/24 14:01 95-50-103/06/24 13:5510.0 1.8 1
1,3-Dichlorobenzene ND ug/L 03/07/24 14:01 541-73-103/06/24 13:5510.0 1.6 1
1,4-Dichlorobenzene ND ug/L 03/07/24 14:01 106-46-703/06/24 13:5510.0 1.7 1
3,3'-Dichlorobenzidine ND ug/L 03/07/24 14:01 91-94-103/06/24 13:5520.0 8.1 1
2,4-Dichlorophenol ND ug/L 03/07/24 14:01 120-83-203/06/24 13:5510.0 1.4 1
Diethylphthalate ND ug/L 03/07/24 14:01 84-66-203/06/24 13:5510.0 2.0 1
2,4-Dimethylphenol ND ug/L 03/07/24 14:01 105-67-903/06/24 13:5510.0 1.7 1
Dimethylphthalate ND ug/L 03/07/24 14:01 131-11-303/06/24 13:5510.0 2.1 1
Di-n-butylphthalate ND ug/L 03/07/24 14:01 84-74-203/06/24 13:5510.0 2.2 1
4,6-Dinitro-2-methylphenol ND ug/L 03/07/24 14:01 534-52-103/06/24 13:5520.0 7.8 1
2,4-Dinitrophenol ND ug/L 03/07/24 14:01 51-28-503/06/24 13:5550.0 26.0 1
2,4-Dinitrotoluene ND ug/L 03/07/24 14:01 121-14-203/06/24 13:5510.0 1.6 1
2,6-Dinitrotoluene ND ug/L 03/07/24 14:01 606-20-203/06/24 13:5510.0 1.7 1
Di-n-octylphthalate ND ug/L 03/07/24 14:01 117-84-003/06/24 13:5510.0 3.9 1
bis(2-Ethylhexyl)phthalate ND ug/L 03/07/24 14:01 117-81-703/06/24 13:556.0 3.7 1
Fluoranthene ND ug/L 03/07/24 14:01 206-44-003/06/24 13:5510.0 2.2 1
Fluorene ND ug/L 03/07/24 14:01 86-73-703/06/24 13:5510.0 2.1 1
Hexachloro-1,3-butadiene ND ug/L 03/07/24 14:01 87-68-303/06/24 13:5510.0 1.8 1
Hexachlorobenzene ND ug/L 03/07/24 14:01 118-74-103/06/24 13:5510.0 2.2 1
Hexachlorocyclopentadiene ND ug/L 03/07/24 14:01 77-47-4 v103/06/24 13:5510.0 1.6 1
Hexachloroethane ND ug/L 03/07/24 14:01 67-72-103/06/24 13:5510.0 1.4 1
Indeno(1,2,3-cd)pyrene ND ug/L 03/07/24 14:01 193-39-503/06/24 13:5510.0 2.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 9 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Sample:B-2 Lab ID:92716288002 Collected:02/29/24 11:00 Received:03/01/24 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8270E RVE
Isophorone ND ug/L 03/07/24 14:01 78-59-103/06/24 13:5510.0 1.7 1
1-Methylnaphthalene ND ug/L 03/07/24 14:01 90-12-003/06/24 13:5510.0 2.0 1
2-Methylnaphthalene ND ug/L 03/07/24 14:01 91-57-603/06/24 13:5510.0 1.9 1
2-Methylphenol(o-Cresol)ND ug/L 03/07/24 14:01 95-48-703/06/24 13:5510.0 1.9 1
3&4-Methylphenol(m&p Cresol)ND ug/L 03/07/24 14:01 15831-10-403/06/24 13:5510.0 1.2 1
Naphthalene ND ug/L 03/07/24 14:01 91-20-303/06/24 13:5510.0 2.1 1
2-Nitroaniline ND ug/L 03/07/24 14:01 88-74-403/06/24 13:5520.0 3.0 1
3-Nitroaniline ND ug/L 03/07/24 14:01 99-09-203/06/24 13:5520.0 3.8 1
4-Nitroaniline ND ug/L 03/07/24 14:01 100-01-603/06/24 13:5520.0 5.1 1
Nitrobenzene ND ug/L 03/07/24 14:01 98-95-303/06/24 13:5510.0 1.9 1
2-Nitrophenol ND ug/L 03/07/24 14:01 88-75-503/06/24 13:5510.0 1.4 1
4-Nitrophenol ND ug/L 03/07/24 14:01 100-02-703/06/24 13:5550.0 6.6 1
N-Nitrosodimethylamine ND ug/L 03/07/24 14:01 62-75-903/06/24 13:5510.0 1.9 1
N-Nitroso-di-n-propylamine ND ug/L 03/07/24 14:01 621-64-703/06/24 13:5510.0 1.3 1
N-Nitrosodiphenylamine ND ug/L 03/07/24 14:01 86-30-603/06/24 13:5510.0 3.0 1
2,2'-Oxybis(1-chloropropane)ND ug/L 03/07/24 14:01 108-60-103/06/24 13:5510.0 1.2 1
Pentachlorophenol ND ug/L 03/07/24 14:01 87-86-503/06/24 13:5520.0 3.8 1
Phenanthrene ND ug/L 03/07/24 14:01 85-01-803/06/24 13:5510.0 2.0 1
Phenol ND ug/L 03/07/24 14:01 108-95-203/06/24 13:5510.0 1.4 1
Pyrene ND ug/L 03/07/24 14:01 129-00-003/06/24 13:5510.0 2.2 1
1,2,4-Trichlorobenzene ND ug/L 03/07/24 14:01 120-82-103/06/24 13:5510.0 1.7 1
2,4,5-Trichlorophenol ND ug/L 03/07/24 14:01 95-95-403/06/24 13:5510.0 1.4 1
2,4,6-Trichlorophenol ND ug/L 03/07/24 14:01 88-06-203/06/24 13:5510.0 1.6 1
Surrogates
Nitrobenzene-d5 (S)21 %03/07/24 14:01 4165-60-003/06/24 13:5510-133 1
2-Fluorobiphenyl (S)17 %03/07/24 14:01 321-60-803/06/24 13:5510-130 1
Terphenyl-d14 (S)49 %03/07/24 14:01 1718-51-003/06/24 13:5510-193 1
Phenol-d6 (S)13 %03/07/24 14:01 13127-88-303/06/24 13:5510-130 1
2-Fluorophenol (S)19 %03/07/24 14:01 367-12-403/06/24 13:5510-130 1
2,4,6-Tribromophenol (S)32 %03/07/24 14:01 118-79-603/06/24 13:5510-166 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
Acetone ND ug/L 03/05/24 09:36 67-64-125.0 5.1 1
Benzene ND ug/L 03/05/24 09:36 71-43-21.0 0.34 1
Bromobenzene ND ug/L 03/05/24 09:36 108-86-11.0 0.29 1
Bromochloromethane ND ug/L 03/05/24 09:36 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 03/05/24 09:36 75-27-41.0 0.31 1
Bromoform ND ug/L 03/05/24 09:36 75-25-21.0 0.34 1
Bromomethane ND ug/L 03/05/24 09:36 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 03/05/24 09:36 78-93-35.0 4.0 1
Carbon tetrachloride ND ug/L 03/05/24 09:36 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 03/05/24 09:36 108-90-71.0 0.28 1
Chloroethane ND ug/L 03/05/24 09:36 75-00-31.0 0.65 1
Chloroform ND ug/L 03/05/24 09:36 67-66-31.0 0.43 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 10 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Sample:B-2 Lab ID:92716288002 Collected:02/29/24 11:00 Received:03/01/24 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
Chloromethane ND ug/L 03/05/24 09:36 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 03/05/24 09:36 95-49-81.0 0.32 1
4-Chlorotoluene ND ug/L 03/05/24 09:36 106-43-41.0 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 03/05/24 09:36 96-12-82.0 0.34 1
Dibromochloromethane ND ug/L 03/05/24 09:36 124-48-11.0 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 03/05/24 09:36 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/05/24 09:36 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 03/05/24 09:36 95-50-11.0 0.34 1
1,3-Dichlorobenzene ND ug/L 03/05/24 09:36 541-73-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 03/05/24 09:36 106-46-71.0 0.33 1
Dichlorodifluoromethane ND ug/L 03/05/24 09:36 75-71-81.0 0.35 1
1,1-Dichloroethane ND ug/L 03/05/24 09:36 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 03/05/24 09:36 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 03/05/24 09:36 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 03/05/24 09:36 156-59-21.0 0.38 1
trans-1,2-Dichloroethene ND ug/L 03/05/24 09:36 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 03/05/24 09:36 78-87-51.0 0.36 1
1,3-Dichloropropane ND ug/L 03/05/24 09:36 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 03/05/24 09:36 594-20-71.0 0.39 1
1,1-Dichloropropene ND ug/L 03/05/24 09:36 563-58-61.0 0.43 1
cis-1,3-Dichloropropene ND ug/L 03/05/24 09:36 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 03/05/24 09:36 10061-02-61.0 0.36 1
Diisopropyl ether ND ug/L 03/05/24 09:36 108-20-31.0 0.31 1
Ethylbenzene ND ug/L 03/05/24 09:36 100-41-41.0 0.30 1
Hexachloro-1,3-butadiene ND ug/L 03/05/24 09:36 87-68-32.0 1.5 1
2-Hexanone ND ug/L 03/05/24 09:36 591-78-65.0 0.48 1
p-Isopropyltoluene ND ug/L 03/05/24 09:36 99-87-61.0 0.41 1
Methylene Chloride ND ug/L 03/05/24 09:36 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/05/24 09:36 108-10-15.0 2.7 1
Methyl-tert-butyl ether ND ug/L 03/05/24 09:36 1634-04-41.0 0.42 1
Naphthalene ND ug/L 03/05/24 09:36 91-20-31.0 0.64 1
Styrene ND ug/L 03/05/24 09:36 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 03/05/24 09:36 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 03/05/24 09:36 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 03/05/24 09:36 127-18-41.0 0.29 1
Toluene ND ug/L 03/05/24 09:36 108-88-31.0 0.24 1
1,2,3-Trichlorobenzene ND ug/L 03/05/24 09:36 87-61-61.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 03/05/24 09:36 120-82-11.0 0.64 1
1,1,1-Trichloroethane ND ug/L 03/05/24 09:36 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 03/05/24 09:36 79-00-51.0 0.32 1
Trichloroethene ND ug/L 03/05/24 09:36 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 03/05/24 09:36 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 03/05/24 09:36 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 03/05/24 09:36 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 03/05/24 09:36 75-01-41.0 0.39 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 11 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Sample:B-2 Lab ID:92716288002 Collected:02/29/24 11:00 Received:03/01/24 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
Xylene (Total)ND ug/L 03/05/24 09:36 1330-20-71.0 0.34 1
m&p-Xylene ND ug/L 03/05/24 09:36 179601-23-12.0 0.71 1
o-Xylene ND ug/L 03/05/24 09:36 95-47-61.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)101 %03/05/24 09:36 460-00-470-130 1
1,2-Dichloroethane-d4 (S)122 %03/05/24 09:36 17060-07-070-130 1
Toluene-d8 (S)106 %03/05/24 09:36 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 12 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
839113
MADEP VPH
MADEP VPH
VPH NC Water
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92716288001, 92716288002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4334411
Associated Lab Samples:92716288001, 92716288002
Matrix:Water
AnalyzedMDL
Aliphatic (C05-C08),Unadjusted ug/L ND 100 N203/15/24 13:15100
Aromatic (C09-C10)ug/L ND 100 N203/15/24 13:15100
2,5-Dibromotoluene (FID)(S)%93 70-130 03/15/24 13:15
2,5-Dibromotoluene (PID)(S)%91 70-130 03/15/24 13:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4334412LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
4334413
Aliphatic (C05-C08),Unadjusted ug/L 337 N230011270-130112336 0 25
Aromatic (C09-C10)ug/L ND N21009670-13097ND 25
2,5-Dibromotoluene (FID)(S)%99 70-130100
2,5-Dibromotoluene (PID)(S)%98 70-13097
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 13 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
836610
EPA 8260D
EPA 8260D
8260D MSV Low Level
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92716288001, 92716288002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4321323
Associated Lab Samples:92716288001, 92716288002
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 03/05/24 06:280.31
1,1,1-Trichloroethane ug/L ND 1.0 03/05/24 06:280.33
1,1,2,2-Tetrachloroethane ug/L ND 1.0 03/05/24 06:280.22
1,1,2-Trichloroethane ug/L ND 1.0 03/05/24 06:280.32
1,1-Dichloroethane ug/L ND 1.0 03/05/24 06:280.37
1,1-Dichloroethene ug/L ND 1.0 03/05/24 06:280.35
1,1-Dichloropropene ug/L ND 1.0 03/05/24 06:280.43
1,2,3-Trichlorobenzene ug/L ND 1.0 03/05/24 06:280.81
1,2,3-Trichloropropane ug/L ND 1.0 03/05/24 06:280.26
1,2,4-Trichlorobenzene ug/L ND 1.0 03/05/24 06:280.64
1,2-Dibromo-3-chloropropane ug/L ND 2.0 03/05/24 06:280.34
1,2-Dibromoethane (EDB)ug/L ND 1.0 03/05/24 06:280.27
1,2-Dichlorobenzene ug/L ND 1.0 03/05/24 06:280.34
1,2-Dichloroethane ug/L ND 1.0 03/05/24 06:280.32
1,2-Dichloropropane ug/L ND 1.0 03/05/24 06:280.36
1,3-Dichlorobenzene ug/L ND 1.0 03/05/24 06:280.34
1,3-Dichloropropane ug/L ND 1.0 03/05/24 06:280.28
1,4-Dichlorobenzene ug/L ND 1.0 03/05/24 06:280.33
2,2-Dichloropropane ug/L ND 1.0 03/05/24 06:280.39
2-Butanone (MEK)ug/L ND 5.0 03/05/24 06:284.0
2-Chlorotoluene ug/L ND 1.0 03/05/24 06:280.32
2-Hexanone ug/L ND 5.0 03/05/24 06:280.48
4-Chlorotoluene ug/L ND 1.0 03/05/24 06:280.32
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 03/05/24 06:282.7
Acetone ug/L ND 25.0 03/05/24 06:285.1
Benzene ug/L ND 1.0 03/05/24 06:280.34
Bromobenzene ug/L ND 1.0 03/05/24 06:280.29
Bromochloromethane ug/L ND 1.0 03/05/24 06:280.47
Bromodichloromethane ug/L ND 1.0 03/05/24 06:280.31
Bromoform ug/L ND 1.0 03/05/24 06:280.34
Bromomethane ug/L ND 2.0 v203/05/24 06:281.7
Carbon tetrachloride ug/L ND 1.0 03/05/24 06:280.33
Chlorobenzene ug/L ND 1.0 03/05/24 06:280.28
Chloroethane ug/L ND 1.0 03/05/24 06:280.65
Chloroform ug/L ND 1.0 03/05/24 06:280.43
Chloromethane ug/L ND 1.0 03/05/24 06:280.54
cis-1,2-Dichloroethene ug/L ND 1.0 03/05/24 06:280.38
cis-1,3-Dichloropropene ug/L ND 1.0 03/05/24 06:280.36
Dibromochloromethane ug/L ND 1.0 03/05/24 06:280.36
Dibromomethane ug/L ND 1.0 03/05/24 06:280.39
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 14 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4321323
Associated Lab Samples:92716288001, 92716288002
Matrix:Water
AnalyzedMDL
Dichlorodifluoromethane ug/L ND 1.0 03/05/24 06:280.35
Diisopropyl ether ug/L ND 1.0 03/05/24 06:280.31
Ethylbenzene ug/L ND 1.0 03/05/24 06:280.30
Hexachloro-1,3-butadiene ug/L ND 2.0 03/05/24 06:281.5
m&p-Xylene ug/L ND 2.0 03/05/24 06:280.71
Methyl-tert-butyl ether ug/L ND 1.0 03/05/24 06:280.42
Methylene Chloride ug/L ND 5.0 03/05/24 06:282.0
Naphthalene ug/L ND 1.0 03/05/24 06:280.64
o-Xylene ug/L ND 1.0 03/05/24 06:280.34
p-Isopropyltoluene ug/L ND 1.0 03/05/24 06:280.41
Styrene ug/L ND 1.0 03/05/24 06:280.29
Tetrachloroethene ug/L ND 1.0 03/05/24 06:280.29
Toluene ug/L ND 1.0 03/05/24 06:280.24
trans-1,2-Dichloroethene ug/L ND 1.0 03/05/24 06:280.40
trans-1,3-Dichloropropene ug/L ND 1.0 03/05/24 06:280.36
Trichloroethene ug/L ND 1.0 03/05/24 06:280.38
Trichlorofluoromethane ug/L ND 1.0 03/05/24 06:280.30
Vinyl acetate ug/L ND 2.0 03/05/24 06:281.3
Vinyl chloride ug/L ND 1.0 03/05/24 06:280.39
Xylene (Total)ug/L ND 1.0 03/05/24 06:280.34
1,2-Dichloroethane-d4 (S)%112 70-130 03/05/24 06:28
4-Bromofluorobenzene (S)%100 70-130 03/05/24 06:28
Toluene-d8 (S)%107 70-130 03/05/24 06:28
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4321324LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 19.520 97 70-130
1,1,1-Trichloroethane ug/L 20.720 103 70-130
1,1,2,2-Tetrachloroethane ug/L 19.220 96 70-130
1,1,2-Trichloroethane ug/L 19.620 98 70-130
1,1-Dichloroethane ug/L 20.920 105 70-130
1,1-Dichloroethene ug/L 20.420 102 69-131
1,1-Dichloropropene ug/L 20.320 102 70-132
1,2,3-Trichlorobenzene ug/L 19.520 97 70-132
1,2,3-Trichloropropane ug/L 20.120 100 70-130
1,2,4-Trichlorobenzene ug/L 19.220 96 70-130
1,2-Dibromo-3-chloropropane ug/L 18.020 90 70-130
1,2-Dibromoethane (EDB)ug/L 19.620 98 70-130
1,2-Dichlorobenzene ug/L 20.220 101 70-130
1,2-Dichloroethane ug/L 22.220 111 70-130
1,2-Dichloropropane ug/L 20.920 105 70-130
1,3-Dichlorobenzene ug/L 20.420 102 70-130
1,3-Dichloropropane ug/L 20.020 100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 15 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4321324LABORATORY CONTROL SAMPLE:
LCSSpike
1,4-Dichlorobenzene ug/L 19.420 97 70-130
2,2-Dichloropropane ug/L 20.920 105 69-130
2-Butanone (MEK)ug/L 37.740 94 67-133
2-Chlorotoluene ug/L 20.420 102 70-130
2-Hexanone ug/L 37.140 93 70-133
4-Chlorotoluene ug/L 20.920 105 70-130
4-Methyl-2-pentanone (MIBK)ug/L 35.940 90 70-130
Acetone ug/L 38.840 97 67-130
Benzene ug/L 20.220 101 70-130
Bromobenzene ug/L 19.620 98 70-130
Bromochloromethane ug/L 21.520 108 70-130
Bromodichloromethane ug/L 20.220 101 70-130
Bromoform ug/L 17.520 87 70-133
Bromomethane ug/L 12.0 v3206041-148
Carbon tetrachloride ug/L 20.320 102 70-130
Chlorobenzene ug/L 19.920 100 70-130
Chloroethane ug/L 18.820 94 41-157
Chloroform ug/L 21.320 107 70-130
Chloromethane ug/L 16.220 81 59-141
cis-1,2-Dichloroethene ug/L 21.320 107 70-130
cis-1,3-Dichloropropene ug/L 20.020 100 70-130
Dibromochloromethane ug/L 18.620 93 70-130
Dibromomethane ug/L 19.720 99 70-130
Dichlorodifluoromethane ug/L 13.620 68 54-147
Diisopropyl ether ug/L 19.020 95 70-130
Ethylbenzene ug/L 20.520 102 70-130
Hexachloro-1,3-butadiene ug/L 19.220 96 70-134
m&p-Xylene ug/L 41.240 103 70-130
Methyl-tert-butyl ether ug/L 19.720 99 70-130
Methylene Chloride ug/L 21.620 108 62-130
Naphthalene ug/L 20.020 100 70-135
o-Xylene ug/L 20.020 100 70-130
p-Isopropyltoluene ug/L 20.520 103 70-130
Styrene ug/L 20.120 100 70-130
Tetrachloroethene ug/L 18.420 92 70-130
Toluene ug/L 20.020 100 70-130
trans-1,2-Dichloroethene ug/L 20.820 104 70-130
trans-1,3-Dichloropropene ug/L 20.520 103 70-130
Trichloroethene ug/L 21.020 105 70-130
Trichlorofluoromethane ug/L 19.820 99 57-130
Vinyl acetate ug/L 42.540 106 70-141
Vinyl chloride ug/L 20.320 101 66-140
Xylene (Total)ug/L 61.260 102 70-130
1,2-Dichloroethane-d4 (S)%110 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%102 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 16 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4321325MATRIX SPIKE SAMPLE:
MSSpike
Result
92716437001
1,1,1,2-Tetrachloroethane ug/L 22.320 111 70-146ND
1,1,1-Trichloroethane ug/L 24.920 124 70-150ND
1,1,2,2-Tetrachloroethane ug/L 22.020 110 66-144ND
1,1,2-Trichloroethane ug/L 22.620 113 70-142ND
1,1-Dichloroethane ug/L 24.720 124 68-150ND
1,1-Dichloroethene ug/L 24.820 124 64-162ND
1,1-Dichloropropene ug/L 25.120 125 70-160ND
1,2,3-Trichlorobenzene ug/L 22.120 110 66-151ND
1,2,3-Trichloropropane ug/L 22.020 110 66-144ND
1,2,4-Trichlorobenzene ug/L 22.220 111 69-147ND
1,2-Dibromo-3-chloropropane ug/L 20.520 102 62-146ND
1,2-Dibromoethane (EDB)ug/L 22.620 113 70-143ND
1,2-Dichlorobenzene ug/L 23.620 118 70-142ND
1,2-Dichloroethane ug/L 25.620 128 68-145ND
1,2-Dichloropropane ug/L 23.620 118 70-144ND
1,3-Dichlorobenzene ug/L 24.220 121 70-142ND
1,3-Dichloropropane ug/L 22.720 113 70-141ND
1,4-Dichlorobenzene ug/L 23.220 116 70-140ND
2,2-Dichloropropane ug/L 25.320 127 58-160ND
2-Butanone (MEK)ug/L 45.740 114 57-156ND
2-Chlorotoluene ug/L 24.520 122 70-148ND
2-Hexanone ug/L 43.340 108 62-153ND
4-Chlorotoluene ug/L 24.320 121 70-144ND
4-Methyl-2-pentanone (MIBK)ug/L 41.940 105 65-144ND
Acetone ug/L 44.340 111 49-162ND
Benzene ug/L 23.420 117 68-144ND
Bromobenzene ug/L 22.820 114 70-144ND
Bromochloromethane ug/L 23.420 117 70-148ND
Bromodichloromethane ug/L 22.620 113 70-141ND
Bromoform ug/L 18.720 94 59-144ND
Bromomethane ug/L 16.6 v3208323-190ND
Carbon tetrachloride ug/L 24.520 122 70-147ND
Chlorobenzene ug/L 23.020 115 70-143ND
Chloroethane ug/L 21.220 106 55-190ND
Chloroform ug/L 24.720 124 67-148ND
Chloromethane ug/L 15.9 v3207938-180ND
cis-1,2-Dichloroethene ug/L 23.720 118 67-151ND
cis-1,3-Dichloropropene ug/L 22.420 112 70-142ND
Dibromochloromethane ug/L 21.420 107 68-140ND
Dibromomethane ug/L 21.720 108 70-142ND
Dichlorodifluoromethane ug/L 13.220 66 15-200ND
Diisopropyl ether ug/L 22.020 110 62-149ND
Ethylbenzene ug/L 24.220 121 70-145ND
Hexachloro-1,3-butadiene ug/L 24.420 122 64-164ND
m&p-Xylene ug/L 47.840 119 70-148ND
Methyl-tert-butyl ether ug/L 22.220 111 64-146ND
Methylene Chloride ug/L 23.520 117 54-149ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 17 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4321325MATRIX SPIKE SAMPLE:
MSSpike
Result
92716437001
Naphthalene ug/L 22.720 114 62-154ND
o-Xylene ug/L 23.320 116 70-145ND
p-Isopropyltoluene ug/L 25.220 126 70-153ND
Styrene ug/L 23.320 117 70-147ND
Tetrachloroethene ug/L 21.620 108 70-145ND
Toluene ug/L 23.020 115 65-146ND
trans-1,2-Dichloroethene ug/L 24.420 122 69-155ND
trans-1,3-Dichloropropene ug/L 23.020 115 70-142ND
Trichloroethene ug/L 24.020 120 70-152ND
Trichlorofluoromethane ug/L 25.720 129 60-158ND
Vinyl acetate ug/L 45.740 114 56-157ND
Vinyl chloride ug/L 22.020 110 51-178ND
Xylene (Total)ug/L 71.060 118 70-146ND
1,2-Dichloroethane-d4 (S)%108 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92716437002
4321326SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,1-Dichloropropene ug/L ND 30ND
1,2,3-Trichlorobenzene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2,4-Trichlorobenzene ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichlorobenzene ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2,2-Dichloropropane ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Chlorotoluene ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Chlorotoluene ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
Pace Analytical Services, LLC
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Eden, NC 27288
[phone]
Page 18 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92716437002
4321326SAMPLE DUPLICATE:
Benzene ug/L ND 30ND
Bromobenzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND v230ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L .88J 300.89J
Chloromethane ug/L ND v230ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Diisopropyl ether ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Hexachloro-1,3-butadiene ug/L ND 30ND
m&p-Xylene ug/L ND 30ND
Methyl-tert-butyl ether ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Naphthalene ug/L ND 30ND
o-Xylene ug/L ND 30ND
p-Isopropyltoluene ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%113115
4-Bromofluorobenzene (S)%103101
Toluene-d8 (S)%106105
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 19 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
837012
EPA 3510C
EPA 8270E
8270E Water MSSV RVE
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92716288001, 92716288002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4323360
Associated Lab Samples:92716288001, 92716288002
Matrix:Water
AnalyzedMDL
1,2,4-Trichlorobenzene ug/L ND 10.0 03/07/24 11:531.7
1,2-Dichlorobenzene ug/L ND 10.0 03/07/24 11:531.8
1,3-Dichlorobenzene ug/L ND 10.0 03/07/24 11:531.6
1,4-Dichlorobenzene ug/L ND 10.0 03/07/24 11:531.7
1-Methylnaphthalene ug/L ND 10.0 03/07/24 11:532.0
2,2'-Oxybis(1-chloropropane)ug/L ND 10.0 03/07/24 11:531.2
2,4,5-Trichlorophenol ug/L ND 10.0 03/07/24 11:531.4
2,4,6-Trichlorophenol ug/L ND 10.0 03/07/24 11:531.6
2,4-Dichlorophenol ug/L ND 10.0 03/07/24 11:531.4
2,4-Dimethylphenol ug/L ND 10.0 03/07/24 11:531.7
2,4-Dinitrophenol ug/L ND 50.0 03/07/24 11:5326.0
2,4-Dinitrotoluene ug/L ND 10.0 03/07/24 11:531.6
2,6-Dinitrotoluene ug/L ND 10.0 03/07/24 11:531.7
2-Chloronaphthalene ug/L ND 10.0 03/07/24 11:531.7
2-Chlorophenol ug/L ND 10.0 03/07/24 11:531.2
2-Methylnaphthalene ug/L ND 10.0 03/07/24 11:531.9
2-Methylphenol(o-Cresol)ug/L ND 10.0 03/07/24 11:531.9
2-Nitroaniline ug/L ND 20.0 03/07/24 11:533.0
2-Nitrophenol ug/L ND 10.0 03/07/24 11:531.4
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 03/07/24 11:531.2
3,3'-Dichlorobenzidine ug/L ND 20.0 03/07/24 11:538.1
3-Nitroaniline ug/L ND 20.0 03/07/24 11:533.8
4,6-Dinitro-2-methylphenol ug/L ND 20.0 03/07/24 11:537.8
4-Bromophenylphenyl ether ug/L ND 10.0 03/07/24 11:531.8
4-Chloro-3-methylphenol ug/L ND 10.0 03/07/24 11:533.3
4-Chloroaniline ug/L ND 20.0 03/07/24 11:533.6
4-Chlorophenylphenyl ether ug/L ND 10.0 03/07/24 11:532.0
4-Nitroaniline ug/L ND 20.0 03/07/24 11:535.1
4-Nitrophenol ug/L ND 50.0 03/07/24 11:536.6
Acenaphthene ug/L ND 10.0 03/07/24 11:532.0
Acenaphthylene ug/L ND 10.0 03/07/24 11:532.0
Aniline ug/L ND 10.0 03/07/24 11:531.6
Anthracene ug/L ND 10.0 03/07/24 11:532.3
Benzo(a)anthracene ug/L ND 10.0 03/07/24 11:532.7
Benzo(a)pyrene ug/L ND 10.0 03/07/24 11:532.8
Benzo(b)fluoranthene ug/L ND 10.0 03/07/24 11:532.6
Benzo(g,h,i)perylene ug/L ND 10.0 03/07/24 11:532.8
Benzo(k)fluoranthene ug/L ND 10.0 03/07/24 11:532.7
Benzoic Acid ug/L ND 50.0 03/07/24 11:5322.0
Benzyl alcohol ug/L ND 20.0 03/07/24 11:532.9
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 20 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4323360
Associated Lab Samples:92716288001, 92716288002
Matrix:Water
AnalyzedMDL
bis(2-Chloroethoxy)methane ug/L ND 10.0 03/07/24 11:531.8
bis(2-Chloroethyl) ether ug/L ND 10.0 03/07/24 11:531.9
bis(2-Ethylhexyl)phthalate ug/L ND 6.0 03/07/24 11:533.7
Butylbenzylphthalate ug/L ND 10.0 03/07/24 11:533.1
Chrysene ug/L ND 10.0 03/07/24 11:532.8
Di-n-butylphthalate ug/L ND 10.0 03/07/24 11:532.2
Di-n-octylphthalate ug/L ND 10.0 03/07/24 11:533.9
Dibenz(a,h)anthracene ug/L ND 10.0 03/07/24 11:533.0
Dibenzofuran ug/L ND 10.0 03/07/24 11:532.1
Diethylphthalate ug/L ND 10.0 03/07/24 11:532.0
Dimethylphthalate ug/L ND 10.0 03/07/24 11:532.1
Fluoranthene ug/L ND 10.0 03/07/24 11:532.2
Fluorene ug/L ND 10.0 03/07/24 11:532.1
Hexachloro-1,3-butadiene ug/L ND 10.0 03/07/24 11:531.8
Hexachlorobenzene ug/L ND 10.0 03/07/24 11:532.2
Hexachlorocyclopentadiene ug/L ND 10.0 v103/07/24 11:531.6
Hexachloroethane ug/L ND 10.0 03/07/24 11:531.4
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 03/07/24 11:532.9
Isophorone ug/L ND 10.0 03/07/24 11:531.7
N-Nitroso-di-n-propylamine ug/L ND 10.0 03/07/24 11:531.3
N-Nitrosodimethylamine ug/L ND 10.0 03/07/24 11:531.9
N-Nitrosodiphenylamine ug/L ND 10.0 03/07/24 11:533.0
Naphthalene ug/L ND 10.0 03/07/24 11:532.1
Nitrobenzene ug/L ND 10.0 03/07/24 11:531.9
Pentachlorophenol ug/L ND 20.0 03/07/24 11:533.8
Phenanthrene ug/L ND 10.0 03/07/24 11:532.0
Phenol ug/L ND 10.0 03/07/24 11:531.4
Pyrene ug/L ND 10.0 03/07/24 11:532.2
2,4,6-Tribromophenol (S)%90 10-166 03/07/24 11:53
2-Fluorobiphenyl (S)%80 10-130 03/07/24 11:53
2-Fluorophenol (S)%69 10-130 03/07/24 11:53
Nitrobenzene-d5 (S)%87 10-133 03/07/24 11:53
Phenol-d6 (S)%52 10-130 03/07/24 11:53
Terphenyl-d14 (S)%108 10-193 03/07/24 11:53
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4323361LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 36.150 72 14-130
1,2-Dichlorobenzene ug/L 30.750 61 10-130
1,3-Dichlorobenzene ug/L 29.150 58 10-130
1,4-Dichlorobenzene ug/L 30.050 60 10-130
1-Methylnaphthalene ug/L 46.250 92 26-131
2,2'-Oxybis(1-chloropropane)ug/L 42.250 84 23-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 21 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4323361LABORATORY CONTROL SAMPLE:
LCSSpike
2,4,5-Trichlorophenol ug/L 54.250 108 36-150
2,4,6-Trichlorophenol ug/L 55.150 110 30-151
2,4-Dichlorophenol ug/L 49.050 98 36-140
2,4-Dimethylphenol ug/L 53.250 106 36-155
2,4-Dinitrophenol ug/L 264250 106 10-169
2,4-Dinitrotoluene ug/L 51.550 103 46-160
2,6-Dinitrotoluene ug/L 51.450 103 47-161
2-Chloronaphthalene ug/L 47.850 96 29-134
2-Chlorophenol ug/L 47.350 95 29-130
2-Methylnaphthalene ug/L 46.850 94 26-130
2-Methylphenol(o-Cresol)ug/L 44.850 90 32-130
2-Nitroaniline ug/L 88.5100 88 41-150
2-Nitrophenol ug/L 50.550 101 31-145
3&4-Methylphenol(m&p Cresol)ug/L 41.950 84 29-130
3,3'-Dichlorobenzidine ug/L 107100 107 46-153
3-Nitroaniline ug/L 102100 102 47-156
4,6-Dinitro-2-methylphenol ug/L 117100 117 23-161
4-Bromophenylphenyl ether ug/L 57.050 114 45-143
4-Chloro-3-methylphenol ug/L 95.2100 95 42-143
4-Chloroaniline ug/L 84.5100 84 37-135
4-Chlorophenylphenyl ether ug/L 53.250 106 43-140
4-Nitroaniline ug/L 91.2100 91 47-157
4-Nitrophenol ug/L 129250 51 10-130
Acenaphthene ug/L 51.050 102 38-138
Acenaphthylene ug/L 52.450 105 39-139
Aniline ug/L 28.350 57 16-130
Anthracene ug/L 52.050 104 45-136
Benzo(a)anthracene ug/L 54.950 110 52-151
Benzo(a)pyrene ug/L 56.250 112 46-165
Benzo(b)fluoranthene ug/L 57.050 114 44-170
Benzo(g,h,i)perylene ug/L 56.750 113 39-171
Benzo(k)fluoranthene ug/L 57.750 115 43-168
Benzoic Acid ug/L 143250 57 10-130
Benzyl alcohol ug/L 90.7100 91 33-134
bis(2-Chloroethoxy)methane ug/L 50.150 100 37-140
bis(2-Chloroethyl) ether ug/L 46.950 94 33-136
bis(2-Ethylhexyl)phthalate ug/L 58.350 117 50-169
Butylbenzylphthalate ug/L 58.250 116 50-174
Chrysene ug/L 55.850 112 52-148
Di-n-butylphthalate ug/L 52.550 105 51-154
Di-n-octylphthalate ug/L 59.550 119 44-170
Dibenz(a,h)anthracene ug/L 55.250 110 41-171
Dibenzofuran ug/L 50.250 100 42-157
Diethylphthalate ug/L 51.250 102 50-149
Dimethylphthalate ug/L 49.850 100 47-146
Fluoranthene ug/L 51.450 103 51-152
Fluorene ug/L 52.050 104 46-143
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 22 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4323361LABORATORY CONTROL SAMPLE:
LCSSpike
Hexachloro-1,3-butadiene ug/L 35.750 71 10-130
Hexachlorobenzene ug/L 50.950 102 40-139
Hexachlorocyclopentadiene ug/L 50.2 v15010010-130
Hexachloroethane ug/L 28.450 57 10-130
Indeno(1,2,3-cd)pyrene ug/L 55.250 110 40-172
Isophorone ug/L 48.050 96 37-143
N-Nitroso-di-n-propylamine ug/L 46.550 93 38-145
N-Nitrosodimethylamine ug/L 35.150 70 30-130
N-Nitrosodiphenylamine ug/L 54.950 110 46-144
Naphthalene ug/L 41.350 83 21-130
Nitrobenzene ug/L 44.650 89 33-136
Pentachlorophenol ug/L 103100 103 19-156
Phenanthrene ug/L 52.250 104 49-143
Phenol ug/L 30.250 60 18-130
Pyrene ug/L 59.050 118 48-156
2,4,6-Tribromophenol (S)%107 10-166
2-Fluorobiphenyl (S)%105 10-130
2-Fluorophenol (S)%79 10-130
Nitrobenzene-d5 (S)%101 10-133
Phenol-d6 (S)%57 10-130
Terphenyl-d14 (S)%116 10-193
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4323362MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92716327002
4323363
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L 50 77 10-13067 14 3050ND38.4 33.4
1,2-Dichlorobenzene ug/L 50 60 10-13049 19 3050ND30.0 24.7
1,3-Dichlorobenzene ug/L 50 55 10-13047 16 3050ND27.7 23.6
1,4-Dichlorobenzene ug/L 50 56 10-13049 15 3050ND28.2 24.3
1-Methylnaphthalene ug/L 50 96 10-13076 23 3050ND47.8 37.9
2,2'-Oxybis(1-
chloropropane)
ug/L 50 92 10-13271 26 3050ND45.9 35.4
2,4,5-Trichlorophenol ug/L M150010-1740 3050NDNDND
2,4,6-Trichlorophenol ug/L M150010-1730 3050NDNDND
2,4-Dichlorophenol ug/L M150010-1530 3050NDNDND
2,4-Dimethylphenol ug/L 50 79 12-15759 30 3050ND39.7 29.4
2,4-Dinitrophenol ug/L M1250010-1650 30250NDNDND
2,4-Dinitrotoluene ug/L 50 96 29-16874 26 3050ND48.1 37.2
2,6-Dinitrotoluene ug/L 50 101 28-16878 26 3050ND50.7 39.0
2-Chloronaphthalene ug/L 50 98 11-13676 25 3050ND49.0 38.2
2-Chlorophenol ug/L M150310-1343 3050ND1.5J 1.3J
2-Methylnaphthalene ug/L 50 95 10-13178 19 3050ND47.4 39.0
2-Methylphenol(o-Cresol)ug/L 50 37 10-13029 23 3050ND18.5 14.7
2-Nitroaniline ug/L 100 88 19-15669 25 30100ND88.0 68.5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 23 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4323362MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92716327002
4323363
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2-Nitrophenol ug/L M150010-1600 3050NDNDND
3&4-Methylphenol(m&p
Cresol)ug/L 50 22 10-13218 3050ND10.8 8.8J
3,3'-Dichlorobenzidine ug/L 100 102 10-17384 20 30100ND10283.9
3-Nitroaniline ug/L 100 99 19-16979 22 30100ND98.9 79.2
4,6-Dinitro-2-methylphenol ug/L M1100010-1784 30100NDNDND
4-Bromophenylphenyl ether ug/L 50 114 28-14987 27 3050ND57.2 43.4
4-Chloro-3-methylphenol ug/L M1,R11002318-14815 42 30100ND23.4 15.3
4-Chloroaniline ug/L 100 89 10-14169 26 30100ND89.1 68.6
4-Chlorophenylphenyl ether ug/L 50 103 24-14481 24 3050ND51.4 40.5
4-Nitroaniline ug/L 100 82 18-17064 25 30100ND82.2 63.9
4-Nitrophenol ug/L M1250010-1300 30250NDNDND
Acenaphthene ug/L 50 101 18-14279 24 3050ND50.3 39.6
Acenaphthylene ug/L 50 103 18-14381 24 3050ND51.7 40.4
Aniline ug/L 50 77 10-13061 23 3050ND38.5 30.6
Anthracene ug/L 50 102 32-13880 24 3050ND51.1 40.2
Benzo(a)anthracene ug/L 50 105 41-15583 23 3050ND52.4 41.5
Benzo(a)pyrene ug/L 50 111 10-16783 29 3050ND55.6 41.4
Benzo(b)fluoranthene ug/L R15011331-17282 31 3050ND56.3 41.1
Benzo(g,h,i)perylene ug/L 50 119 26-17794 23 3050ND59.7 47.2
Benzo(k)fluoranthene ug/L R15010831-16877 33 3050ND53.9 38.6
Benzoic Acid ug/L M1250010-1300 30250NDNDND
Benzyl alcohol ug/L 100 92 10-13671 27 30100ND92.4 70.7
bis(2-
Chloroethoxy)methane
ug/L 50 102 12-14379 25 3050ND51.1 39.7
bis(2-Chloroethyl) ether ug/L 50 103 10-13980 26 3050ND51.7 39.9
bis(2-Ethylhexyl)phthalate ug/L 50 111 41-17387 24 3050ND55.4 43.7
Butylbenzylphthalate ug/L 50 121 38-18294 25 3050ND60.4 47.1
Chrysene ug/L 50 104 41-15284 22 3050ND52.2 41.9
Di-n-butylphthalate ug/L 50 103 37-16283 21 3050ND51.7 41.7
Di-n-octylphthalate ug/L 50 115 36-17693 21 3050ND57.6 46.5
Dibenz(a,h)anthracene ug/L 50 116 29-17591 23 3050ND57.8 45.7
Dibenzofuran ug/L 50 98 23-14477 23 3050ND48.8 38.7
Diethylphthalate ug/L 50 99 33-15478 24 3050ND49.7 38.9
Dimethylphthalate ug/L 50 97 29-15078 22 3050ND48.7 38.9
Fluoranthene ug/L 50 98 40-15678 23 3050ND49.2 39.2
Fluorene ug/L 50 101 26-14878 25 3050ND50.4 39.1
Hexachloro-1,3-butadiene ug/L 50 71 10-13067 6 3050ND35.6 33.5
Hexachlorobenzene ug/L 50 103 27-14582 23 3050ND51.5 41.0
Hexachlorocyclopentadiene ug/L v15010410-13082 24 3050ND51.9 40.9
Hexachloroethane ug/L 50 54 10-13047 13 3050ND26.9 23.5
Indeno(1,2,3-cd)pyrene ug/L 50 115 28-17688 26 3050ND57.3 44.2
Isophorone ug/L 50 99 14-14578 24 3050ND49.7 39.1
N-Nitroso-di-n-propylamine ug/L 50 96 12-14974 26 3050ND48.1 37.0
N-Nitrosodimethylamine ug/L 50 78 10-13061 25 3050ND39.1 30.3
N-Nitrosodiphenylamine ug/L 50 111 29-14986 26 3050ND55.7 42.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 24 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4323362MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92716327002
4323363
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Naphthalene ug/L 50 82 10-13070 16 3050ND40.8 34.8
Nitrobenzene ug/L 50 94 10-14573 24 3050ND46.8 36.7
Pentachlorophenol ug/L M1100010-1780 30100NDNDND
Phenanthrene ug/L 50 101 36-14680 23 3050ND50.5 40.2
Phenol ug/L M150610-1304 3050ND3.1J 2.1J
Pyrene ug/L 50 120 42-15690 28 3050ND59.9 45.0
2,4,6-Tribromophenol (S)%S0210-1660
2-Fluorobiphenyl (S)%100 10-13077
2-Fluorophenol (S)%S0110-1301
Nitrobenzene-d5 (S)%99 10-13376
Phenol-d6 (S)%S0410-1304
Terphenyl-d14 (S)%100 10-19378
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 25 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
836827
MADEP EPH
MADEP EPH
MADEP EPH NC Water
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92716288001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4322340
Associated Lab Samples:92716288001
Matrix:Water
AnalyzedMDL
Aliphatic (C09-C18)ug/L ND 100 N203/07/24 09:08100
Aliphatic (C19-C36)ug/L ND 100 N203/07/24 09:08100
Aromatic (C11-C22)ug/L ND 100 N203/07/24 09:08100
1-Chlorooctadecane (S)%76 40-140 03/07/24 09:08
2-Bromonaphthalene (S)%3 40-140 S003/07/24 09:08
2-Fluorobiphenyl (S)%16 40-140 S003/07/24 09:08
o-Terphenyl (S)%84 40-140 03/07/24 09:08
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4322341LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
4322342
Aliphatic (C09-C18)ug/L 137 N23004640-14045135 2 50
Aliphatic (C19-C36)ug/L 310 N24007740-14077308 1 50
Aromatic (C11-C22)ug/L 595 N28507040-14069584 2 50
1-Chlorooctadecane (S)%S014140-140137
2-Bromonaphthalene (S)%96 40-14096
2-Fluorobiphenyl (S)%94 40-14096
o-Terphenyl (S)%S018740-140181
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 26 of 31
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Analysis conducted outside the EPA method holding time.H1
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
RPD value was outside control limits.R1
Surrogate recovery outside laboratory control limits.S0
The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.v1
The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.v2
The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.v3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 27 of 31
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92716288
304 E.MAIN R23-56
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92716288001 836827 837332B-1 MADEP EPH MADEP EPH
92716288001 839113B-1 MADEP VPH
92716288002 839113B-2 MADEP VPH
92716288001 837012 837378B-1 EPA 3510C EPA 8270E
92716288002 837012 837378B-2 EPA 3510C EPA 8270E
92716288001 836610B-1 EPA 8260D
92716288002 836610B-2 EPA 8260D
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/18/2024 09:29 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 28 of 31
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Appendix E
Phase II Environmental Site Assessment Ragsdale Property - 304 E. Main Street Jamestown, NC 24-027

B-1 (in foreground) and B-2 East of Wooden Fence