Loading...
HomeMy WebLinkAbout24007_Wrights Executive Sales II_4th Water Sampling Event Letter Report_20221213ECS SOUTHEAST, LLP "Setting the Standard for Service" Geotechnical • Construction Materials • Environmental • Facilities NC Registered Engineering Firm F NC Registered Geologists Firm C-553-553 SC Registered Engineering Firm 3239 December 13, 2022 Ms. Holly Samaha-Smith North Carolina Department of Environmental Quality Division of Waste Management Brownfields Program 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Reference: Water Sampling Letter Report — 4t" Sampling Event Wright's Executive Sales II 721 and 723 Rigsbee Avenue; 620 and 616 Foster Street Durham, Durham County, North Carolina Brownfields Project No. 24007-20-032 ECS Project No. 49-10039-B Dear Ms. Samaha-Smith: ECS Southeast, LLP (ECS) is pleased to present the results of water sampling conducted in support of ongoing Brownfield redevelopment activity at the above -referenced site (Figures 1 and 2). ECS's water sampling services were provided in accordance with the North Carolina Department of Environmental Quality (NCDEQ) Division of Waste Management (DWM) Brownfields Program (the Program) June 7, 2022, approved Environmental Management Plan (EMP). Included in this report is a description of the field activities, and the results obtained. On November 28, 2022, ECS mobilized to the subject site to collect one (1) water sample, identified as WS-4. The water sample was collected from an onsite 8,400-gallon FRAC tank utilizing new powder free nitrile gloves and a new dedicated disposable polyethylene bailer. The location of the FRAC tank is illustrated on Figure 3. Water in the FRAC tank was circulated with pumps and hosing just prior to the sampling event in order to provide for a representative water quality sample from the FRAC tank. The FRAC tank, was observed to be near 100% capacity at the time of sampling on November 28, 2022. The water contained in the FRAC tank was generated from precipitation which had accumulated in various open excavations on the Brownfields site and was not reinfiltrating at a rate which supported ongoing redevelopment activities in those areas. Following collection, the water sample, identified as WS-4, was submitted to Eurofins, a North Carolina certified laboratory located in Savannah, Georgia (NC Certification No. 269) for analysis of volatile organic compounds (VOCs) using EPA Method 8260 and semi -volatile organic compounds (SVOCs) using EPA Method 8270. ECS maintained chain of custody (COC) procedures throughout the sample collection and transportation process. Laboratory analysis of WS-4 did not report targeted VOCs or SVOCs at concentrations above their respective laboratory method detection limits (MDLs). The laboratory analytical reports and a copy of the COC documentation are included as attachments. ECS Capitol Services, PLLC • ECS Florida, LLC • ECS Mid -Atlantic, LLC • ECS Midwest, LLC • ECS Southeast, LLP • ECS Southwest, LLP www.ecslimited.com Water Sampling Letter Report Wrights Executive Sales 11 Brownfield Project No. 24007-20-032 ECS Project No. 49-10039-B Based on this summary report's findings, ECS concluded that the laboratory analytical results of the water sample collected on November 28, 2022, and identified as WS-4, did not report targeted compounds above their respective North Carolina Administrative Code (NCAC) 2B Surface Water Standards. Therefore, based upon these results and in accordance with the Brownfields approved EMP, ECS recommended this water be managed on the site or discharged to the storm sewer in accordance with municipal, state, and federal requirements. ECS appreciates the opportunity to work with the Brownfields Program. If you have any questions concerning this report or this project, please contact us. Sincerely, ECS SOUTHEAST, LLP Samantha M. zakasits, G.I.T. Assistant Staff Project Manager sszakasits@ecslimited.com (919) 861-9832 Scott M. Werley, P.G. Principal Geologist NC License No. 2354 swerlev@ecslimited.com (919) 861-9846 Attachments— Figures 1-3 Photo Documentation Laboratory Analytical Reports and Chain of Custody Cc: Mr. John Sunter, GeerHouse Owner, LLC, c/o isunter@fourpointsllc.com 2 F �pr awl { L f J 1110 } Mir -, Mf . r V WN _ y y� APPROXIMATE BROWNFIELD PROPERTY BOUNDARYN USGS TOPOGRAPHIC MAP SITE TOPOGRAPHIC LOCATION MAP SOURCE: FIGURE 1 NORTHWEST7.5 — MINUTE SERIES •• Sales SOUTHWEST DURHAM, NC (BOTTOM) Brownfields Project Number 24007-20-032 111 Durham, Durham County,•Carolina CONTOUR INVERVAL = 1 • - •- 4911 • E i ■Ar L � J � L r r + .0 1' warehouse space. 2. Acme ofl5oe on 2nif Mcar, vacant on t st flax .3. ACMe starage space r I 4. BaEe yoga B 113 1 $. 1Afi0K100 REC ' ,A Relarl and restaurant prop•$rtiss r i 3 I ww ch a _ - '+ 40 r5eerSt The M re•steu rani * -d *i Urtxan AX9'O '� � Elrr'qr}'•r r3L1[ I, Aui0 R9pah Ropoh I t3feY591'� 7 * 'T. 7RTENEW r 1 Pupa 5! ' •0 rp f `Merl Image M A All t d AL. 46 r: _ 4 JN FIGURE 2 SOURCE: wN SITE FEATURES MAP ECS Southeast, LLP Phase I ESA, December 6, 2019 Wright's Executive Sales Eg Brownfields Project Number 24007-20-032 APPROXIMATE SCALE: 721 & 723 Rigsbee Ave; 620 & 616 Foster St. 100 FT. Durham, Durham County, North Carolina TM ECS Project Number: 49-10039-B z— #'A t h 4 7 1 � lot w 5 4 4 J ` FRAC Tank R __. .r L•JLi_L. at- 1N SOURCE: NI I FIGURE 3 ECS Southeast, LLP -+ FRAC TANK LOCATION MAP Phase I ESA, December 6, 2019 Report of Environmental Assessment Rev.0.0, Wright's Executive Sales December 18, 2020 Brownfields Project Number 24007-20-032 721 & 723 Rigsbee Ave; 620 & 616 Foster St. APPROXIMATE SCALE: Durham, Durham County, North Carolina 50 FT. TM ECS Project Number: 49-10039-B Photo 1— View of the FRAC tank used to pump precipitation accumulated in open excavations/trenches across the subject property. Photo 2 — View of the interior of the FRAC tank at the time of the second sampling event on November 28, 2022. f Wright's Executive Sales Photo DocumentationFf! Brownfields Project Number 24007-20-032 721 & 723 Rigsbee Ave; 620 & 616 Foster St. Durham, Durham County, North Carolina GS ECS Project Number: 49-10039-B a ! �, -- -- -. _ - Photo 3 - Additional view of the FRAC tank used to pump precipitation accumulated in open excavations/trenches across the subject property. SABRE MFG., LLC M!-,rements taken from the top mapwsw 5420 phoneE a 888 7r1 5580 46534 " InrPtIon @ Center Une of Tank _ t 98.8 3.q 33 32T2.6 2 197.6 4.7 24 2371A 3 2%.4 7.1 25 24]0.2 56.6 9 396.2 9.4 26 I569.0 61.3 5 g94.0 11.8 3) 366].8 63.5 6 592.8 14.1 38 2766.E 65.9 ) 691.7 l6.5 29 2865.4 68.3 8 T90.5 18,8 JO 2964.I T1.6 9 889.3 31.2 31 3063.0 72.9 10 988.1 23.E 32 3161.8 75.3 tt 1086.9 25.9 3J 3260.E 7].6 12 1185.] 38.3 M11=11111=11156 13 1284.5 30.Eiimii-iiimiii5) t4 1383.3 32.9 J6 356].1 eb.7 15 1483.1 35.3 J) 3655.9 8/.0 t6 1580.9 31.E 38 3)Sq.) 69A IMMIN t8 1]78.6 42.31101INTME111=111 =I=MIIIMIII 30 19)6.1 4).1 43 d149.9 98.8 31 2075.0 49.4 43 0248.] 101.3 22 2l)3.8 .51.8 44 434].:. ' 303,5 .3 IS).6 .9 1600 4) 4 69 6811.] � 362.3 48 4742.8 112.9 ]0 6916.5 164.] 49 484L6 119.3 ]t ]OI83 161.0 50 0940.0 117.E )2 ]114.1 169A 51 60392 1I0.0 )] 731i.9 1]i.] 52 5138.0 122.3 ]4 I311] I]4.1 53 5236.8 124.] ]5 ]430.6 1)6A Sd 6335.E 12'7.0 )6 )509.4 1)H.8 55 5434.4 129.4 ]) ]608.2 1BL1 6533.2 131.] ]8 TS07.0 183.5 563I.0 134.1 ]9 )806.8 186.9 68 5]30.8 136.0 80 ]904.6 188.2 59 5829.E 138.8 81 800 60 5938.4 141.2 62 8l MIM.- IMPMMMII* 6q 6323.) 150.E 9 .4 66 6423.E 153.9 66 6621.3 155.3 Photo 4 - View of the FRAC tank measurement chart located on the side of the FRAC tank. Wright's Executive Sales Photo Documentation Brownfields Project Number 24007-20-032 721 & 723 Rigsbee Ave; 620 & 616 Foster St. Durham, Durham County, North Carolina ECS Project Number: 49-10039-B • % eurofins Environment Testing ANALYTICAL REPORT C PREPARED FOR Attn: Samantha Szakasits ECS Southeast LLP 5260 Greens Dairy Road C Raleigh, North Carolina 27616 Generated 12/7/2022 5:50:30 PM JOB DESCRIPTION Wrights Executive Sales JOB NUMBER 680-226360-1 The test results in this report meet NELAP requirements for parameters for which accreditation is required or available. Any exceptions to the NELAP requirements are noted. Results pertain only to samples listed in this report. This report may not be reproduced, except in full, without the written approval of the laboratory. Questions should be directed to the person who signed this report. The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project Manager. F a Generated 12/7/2022 5:50:30 PM Authorized for release by Chad Bechtold, Project Manager Chad. Bechtold(d).et.eurofinsus.com (813)690-3563 Eurofins Savannah is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies Page 2 of 28 12/7/2022 Definitions/Glossary Client: ECS Southeast LLP Project/Site: Wrights Executive Sales Qualifiers GC/MS VOA Qualifier Qualifier Description *+ LCS and/or LCSD is outside acceptance limits, high biased. J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. GC/MS Semi VOA Qualifier Qualifier Description *+ LCS and/or LCSD is outside acceptance limits, high biased. Glossary Abbreviation These commonly used abbreviations may or may not be present in this report. n Listed under the "D" column to designate that the result is reported on a dry weight basis %R Percent Recovery CFL Contains Free Liquid CFU Colony Forming Unit CNF Contains No Free Liquid DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit (DoD/DOE) DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOQ Limit of Quantitation (DoD/DOE) MCL EPA recommended "Maximum Contaminant Lever' MDA Minimum Detectable Activity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) MPN Most Probable Number MQL Method Quantitation Limit NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) NEG Negative / Absent POS Positive / Present PQL Practical Quantitation Limit PRIES Presumptive QC Quality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) TNTC Too Numerous To Count Job ID: 680-226360-1 Eurofins Savannah Page 3 of 28 12/7/2022 Sample Summary Client: ECS Southeast LLP Project/Site: Wrights Executive Sales Lab Sample ID Client Sample ID 680-226360-1 WS-4 Matrix Water Collected Received 11 /28/22 10:30 11 /29/22 07:00 Job ID: 680-226360-1 Page 4 of 28 Eurofins Savannah 12/7/2022 Case Narrative Client: ECS Southeast LLP Project/Site: Wrights Executive Sales Job ID: 680-226360-1 Laboratory: Eurofins Savannah Narrative Job Narrative 680-226360-1 Job ID: 680-226360-1 Receipt The sample was received on 11/29/2022 7:00 AM. Unless otherwise noted below, the sample arrived in good condition, and, where required, properly preserved and on ice. The temperature of the cooler at receipt time was 1.4°C GC/MS VOA Method 8260D: The laboratory control sample (LCS) for analytical batch 680-753755 recovered outside control limits for the following analytes: 1,2,3-Trichlorobenzene, 1,2,4-Trichlorobenzene, 1,2-Dibromo-3-Chloropropane, Naphthalene and Vinyl chloride. These analytes were biased high in the LCS and were not detected in the associated samples; therefore, the data have been reported. Method 8260D: The laboratory control sample duplicate (LCSD) for analytical batch 680-753755 recovered outside control limits for the following analytes: 1,2,3-Trichlorobenzene, 1,2,4-Trichlorobenzene, 1,2-Dibromo-3-Chloropropane, Dichlorodifluoromethane, Naphthalene and Vinyl chloride. These analytes were biased high in the LCSD and were not detected in the associated samples; therefore, the data have been reported. Method 8260D: The method blank for analytical batch 680-753755 contained 1,2,3-Trichlorobenzene and 1,2,4-Trichlorobenzene above the method detection limit (MDL). None of the samples associated with this method blank contained these target compounds; therefore, re -extraction and/or re -analysis of samples were not performed. No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page. GC/MS Semi VOA Method 8270E: The following samples listed formed emulsions during the extraction procedure: WS-4 (680-226360-1). The emulsions were broken up using Sodium Sulfate. Method 8270E: The laboratory control sample (LCS) and / or laboratory control sample duplicate (LCSD) for preparation batch 680-753436 and analytical batch 680-753876 recovered outside control limits for the following analytes: 3,3'-Dichlorobenzidine. These analytes were biased high in the LCS and were not detected in the associated samples; therefore, the data have been reported. No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page. Eurofins Savannah Page 5 of 28 12/7/2022 Detection Summary Client: ECS Southeast LLP Job ID: 680-226360-1 Project/Site: Wrights Executive Sales Client Sample ID: WS-4 Lab Sample ID: 680-226360-1 No Detections. This Detection Summary does not include radiochemical test results. Eurofins Savannah Page 6 of 28 12/7/2022 Client Sample Results Client: ECS Southeast LLP Project/Site: Wrights Executive Sales Job ID: 680-226360-1 Client Sample ID: WS-4 Lab Sample ID: 680-226360-1 Date Collected: 11/28/22 10:30 Matrix: Water Date Received: 11/29/22 07:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier 1,1,1, 2-Tetrachloroetha ne ND 1,1,1-Trichloroethane ND 1,1,2,2-Tetrachloroethane ND 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1,1,2-Trichloroethane ND 1,1-Dichloroethane ND 1,1-Dichloroethene ND 1,1-Dichloropropene ND 1,2,3-Trichlorobenzene ND ,+ 1,2,3-Trichloropropane ND 1,2,4-Trichlorobenzene ND .+ 1,2,4-Trimethylbenzene ND 1,2-Dibromo-3-Chloropropane ND <+ 1,2-Dichlorobenzene ND 1,2-Dichloroethane ND 1,2-Dichloropropane ND 1, 3, 5-Tri methyl be nze ne ND 1,3-Dichlorobenzene ND 1,3-Dichloropropane ND 1,4-Dichlorobenzene ND 2,2-Dichloropropane ND 2-Butanone (MEK) ND 2-Chlorotoluene ND 2-Hexanone ND 4-Chlorotoluene ND 4-I sopropyltol uene ND 4-Methyl-2-pentanone (MIBK) ND Acetone ND Acrylonitrile ND Benzene ND Bromobenzene ND Bromoform ND Bromomethane ND Carbon disulfide ND Carbon tetrachloride ND Chlorobenzene ND Chlorobromomethane ND Chlorodibromomethane ND Chloroethane ND Chloroform ND Chloromethane ND cis-1,2-Dichloroethene ND cis- 1,3-Dichloropropene ND Dibromomethane ND Dichlorobromomethane ND Dichlorodifluoromethane ND '+ Ethyl acetate ND Ethylbenzene ND Ethylene Dibromide ND RL MDL Unit D Prepared Analyzed Dil Fac 1.00 0.360 ug/L 12/06/2216:37 1 1.00 0.210 ug/L 12/06/2216:37 1 1.00 0.400 ug/L 12/06/2216:37 1 1.00 0.230 ug/L 12/06/2216:37 1 1.00 0.320 ug/L 12/06/2216:37 1 1.00 0.330 ug/L 12/06/2216:37 1 1.00 0.330 ug/L 12/06/2216:37 1 1.00 0.280 ug/L 12/06/2216:37 1 5.00 0.810 ug/L 12/06/2216:37 1 1.00 0.480 ug/L 12/06/2216:37 1 5.00 0.530 ug/L 12/06/2216:37 1 1.00 0.430 ug/L 12/06/2216:37 1 5.00 1.80 ug/L 12/06/2216:37 1 1.00 0.310 ug/L 12/06/2216:37 1 1.00 0.250 ug/L 12/06/2216:37 1 1.00 0.220 ug/L 12/06/2216:37 1 1.00 0.280 ug/L 12/06/2216:37 1 1.00 0.310 ug/L 12/06/2216:37 1 1.00 0.360 ug/L 12/06/2216:37 1 1.00 0.310 ug/L 12/06/2216:37 1 1.00 0.350 ug/L 12/06/2216:37 1 10.0 6.40 ug/L 12/06/2216:37 1 1.00 0.250 ug/L 12/06/2216:37 1 10.0 3.20 ug/L 12/06/2216:37 1 1.00 0.410 ug/L 12/06/2216:37 1 1.00 0.440 ug/L 12/06/2216:37 1 10.0 2.70 ug/L 12/06/2216:37 1 10.0 3.70 ug/L 12/06/2216:37 1 20.0 5.50 ug/L 12/06/2216:37 1 1.00 0.270 ug/L 12/06/2216:37 1 1.00 0.240 ug/L 12/06/2216:37 1 1.00 0.590 ug/L 12/06/2216:37 1 5.00 3.70 ug/L 12/06/2216:37 1 2.00 0.430 ug/L 12/06/2216:37 1 1.00 0.300 ug/L 12/06/2216:37 1 1.00 0.150 ug/L 12/06/2216:37 1 1.00 0.340 ug/L 12/06/2216:37 1 1.00 0.390 ug/L 12/06/2216:37 1 5.00 4.60 ug/L 12/06/2216:37 1 1.00 0.270 ug/L 12/06/2216:37 1 1.00 0.540 ug/L 12/06/2216:37 1 1.00 0.250 ug/L 12/06/2216:37 1 1.00 0.260 ug/L 12/06/2216:37 1 1.00 0.340 ug/L 12/06/2216:37 1 1.00 0.250 ug/L 12/06/2216:37 1 1.00 0.360 ug/L 12/06/2216:37 1 10.0 5.00 ug/L 12/06/2216:37 1 1.00 0.200 ug/L 12/06/2216:37 1 1.00 0.330 ug/L 12/06/2216:37 1 0 Eurofins Savannah Page 7 of 28 12/7/2022 Client Sample Results Client: ECS Southeast LLP Project/Site: Wrights Executive Sales Client Sample ID: WS-4 Date Collected: 11/28/22 10:30 Date Received: 11/29/22 07:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL Hexachlorobutadiene ND 5.00 Hexane ND 5.00 lodomethane ND 10.0 Isopropyl ether ND 10.0 Isopropyl benzene ND 1.00 Methyl tert-butyl ether ND 5.00 Methylene Chloride ND 5.00 m-Xylene & p-Xylene ND 1.00 Naphthalene ND .+ 5.00 n-Butylbenzene ND 1.00 n-Heptane ND 1.00 N-Propylbenzene ND 1.00 o-Xylene ND 1.00 sec-Butylbenzene ND 1.00 Styrene ND 1.00 tert-Butylbenzene ND 1.00 Tetrachloroethene ND 0.500 Toluene ND 1.00 trans-1,2-Dichloroethene ND 1.00 trans-1,3-Dichloropropene ND 1.00 trans-1,4-Dichloro-2-butene ND 2.00 Trichloroethene ND 1.00 Trichlorofluoromethane ND 1.00 Vinyl acetate ND 2.00 Vinyl chloride ND .+ 1.00 Xylenes, Total ND 1.00 Job ID: 680-226360-1 Lab Sample ID: 680-226360-1 Matrix: Water MDL Unit D Prepared Analyzed Dil Fac 0.220 ug/L 12/06/22 16:37 1 0.650 ug/L 12/06/22 16:37 1 3.90 ug/L 12/06/22 16:37 1 0.700 ug/L 12/06/22 16:37 1 0.260 ug/L 12/06/22 16:37 1 0.810 ug/L 12/0612216:37 1 3.20 ug/L 12/0612216:37 1 0.490 ug/L 12/0612216:37 1 2.40 ug/L 12/06/22 16:37 1 0.520 ug/L 12/06/22 16:37 1 0.430 ug/L 12/06/22 16:37 1 0.410 ug/L 12/06/22 16:37 1 0.260 ug/L 12/06/22 16:37 1 0.530 ug/L 12/06/22 16:37 1 0.270 ug/L 12/06/22 16:37 1 0.430 ug/L 12/06/22 16:37 1 0.350 ug/L 12/06/22 16:37 1 0.250 ug/L 12/06/22 16:37 1 0.340 ug/L 12/06/22 16:37 1 0.230 ug/L 12/06/22 16:37 1 1.25 ug/L 12/0612216:37 1 0.200 ug/L 12/0612216:37 1 0.330 ug/L 12/0612216:37 1 0.690 ug/L 12/06/22 16:37 1 0.400 ug/L 12/06/22 16:37 1 0.230 ug/L 12/06/22 16:37 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 96 60- 124 12/06/22 16:37 1 4-Bromofluorobenzene (Surr) 109 70 - 130 12/06/22 16:37 1 Dibromofluoromethane (Surr) 103 70 - 130 12106122 16:37 1 Toluene-d8 (Surr) 112 70 - 130 12/06/22 16:37 1 Method: SW846 8270E - Semivolatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1'-Biphenyl ND 9.37 4.31 ug/L 12/03/22 20:43 12/06/22 23:34 1 2,4,5-Trichlorophenol ND 9.37 3.09 ug/L 12/03/22 20:43 12/06/22 23:34 1 2,4,6-Trichlorophenol ND 9.37 2.06 ug/L 12/03/22 20:43 12/06/22 23:34 1 2,4-Dichlorophenol ND 9.37 3.47 ug/L 12/03/22 20:43 12/06/22 23:34 1 2,4-Dimethylphenol ND 9.37 2.81 ug/L 12/03/22 20:43 12/06/22 23:34 1 2,4-Dinitrophenol ND 46.9 15.0 ug/L 12/03/22 20:43 12/06/22 23:34 1 2,4-Dinitrotoluene ND 9.37 2.16 ug/L 12/03/22 20:43 12/06/22 23:34 1 2,6-Dinitrotoluene ND 9.37 2.62 ug/L 12/03/22 20:43 12/06/22 23:34 1 2-Chloronaphthalene ND 9.37 4.50 ug/L 12/03/22 20:43 12/06/22 23:34 1 2-Chlorophenol ND 9.37 3.00 ug/L 12/03/22 20:43 12/06/22 23:34 1 2-Methylnaphthalene ND 9.37 4.31 ug/L 12/03/22 20:43 12/06/22 23:34 1 2-Methylphenol ND 9.37 1.69 ug/L 12/03/22 20:43 12/06/22 23:34 1 2-Nitroaniline ND 46.9 2.72 ug/L 12/03/22 20:43 12/06/22 23:34 1 2-Nitrophenol ND 9.37 3.66 ug/L 12/03/22 20:43 12/06/22 23:34 1 3 & 4 Methylphenol ND 9.37 1.31 ug/L 12/03/22 20:43 12/06/22 23:34 1 Eurofins Savannah Page 8 of 28 12/7/2022 Client Sample Results Client: ECS Southeast LLP Project/Site: Wrights Executive Sales Client Sample ID: WS-4 Date Collected: 11/28/22 10:30 Date Received: 11/29/22 07:00 Method: SW846 8270E - Semivolatile Organic Compounds (GC/MS) (Continued) Job ID: 680-226360-1 Lab Sample ID: 680-226360-1 Matrix: Water Analyte Result Qualifier RL MDL Unit D Prepared Analyzed 3,3'-Dichlorobenzidine ND .+ 56.2 9.37 ug/L 12/03/22 20:43 12/06/22 23:34 3-Nitroaniline ND 46.9 2.81 ug/L 12/03/22 20:43 12/06/22 23:34 4,6-Dinitro-2-methylphenol ND 46.9 4.97 ug/L 12/03/22 20:43 12/06/22 23:34 4-Bromophenyl phenyl ether ND 9.37 4.40 ug/L 12/03/22 20:43 12/06/22 23:34 4-Chloro-3-methylphenol ND 9.37 2.34 ug/L 12/03/22 20:43 12/06/22 23:34 4-Chloroaniline ND 18.7 0.937 ug/L 12/03/22 20:43 12/06/22 23:34 4-Chlorophenyl phenyl ether ND 9.37 4.97 ug/L 12/03/22 20:43 12/06/22 23:34 4-Nitroaniline ND 46.9 2.81 ug/L 12/03/22 20:43 12/06/22 23:34 4-Nitrophenol ND 46.9 7.59 ug/L 12/03/22 20:43 12/06/22 23:34 Acenaphthene ND 9.37 4.12 ug/L 12/03/22 20:43 12/06/22 23:34 Acenaphthylene ND 9.37 3.37 ug/L 12/03/22 20:43 12/06/22 23:34 Acetophenone ND 9.37 2.06 ug/L 12/03/22 20:43 12/06/22 23:34 Anthracene ND 9.37 3.37 ug/L 12/03/22 20:43 12/06/22 23:34 Atrazine ND 9.37 2.06 ug/L 12/03/22 20:43 12/06/22 23:34 Benzaldehyde ND 9.37 4.50 ug/L 12/03/22 20:43 12/06/22 23:34 Benzo[a]anthracene ND 9.37 3.94 ug/L 12/03/22 20:43 12/06/22 23:34 Benzo[a]pyrene ND 9.37 2.62 ug/L 12/03/22 20:43 12/06/22 23:34 Benzo[b]fuoranthene ND 9.37 2.91 ug/L 12/03/22 20:43 12/06/22 23:34 Benzo[g,h,i]perylene ND 9.37 2.81 ug/L 12/03/22 20:43 12/06/22 23:34 Benzo[k]fluoranthene ND 9.37 2.72 ug/L 12/03/22 20:43 12/06/22 23:34 bis (2-chloroisopropyl) ether ND 9.37 2.91 ug/L 12/03/22 20:43 12/06/22 23:34 Bis(2-chloroethoxy)methane ND 9.37 1.69 ug/L 12/03/22 20:43 12/06/22 23:34 Bis(2-chloroethyl)ether ND 9.37 3.37 ug/L 12/03/22 20:43 12/06/22 23:34 Bis(2-ethylhexyl) phthalate ND 9.37 2.81 ug/L 12/03/22 20:43 12/06/22 23:34 Butyl benzyl phthalate ND 9.37 2.62 ug/L 12/03/22 20:43 12/06/22 23:34 Caprolactam ND 9.37 2.62 ug/L 12/03/22 20:43 12/06/22 23:34 Carbazole ND 9.37 1.69 ug/L 12/03/22 20:43 12/06/22 23:34 Chrysene ND 9.37 3.56 ug/L 12/03/22 20:43 12/06/22 23:34 Dibenz(a,h)anthracene ND 9.37 2.81 ug/L 12/03/22 20:43 12/06/22 23:34 Dibenzofuran ND 9.37 1.78 ug/L 12/03/22 20:43 12/06/22 23:34 Diethyl phthalate ND 9.37 2.06 ug/L 12/03/22 20:43 12/06/22 23:34 Dimethyl phthalate ND 9.37 1.97 ug/L 12/03/22 20:43 12/06/22 23:34 Di-n-butyl phthalate ND 9.37 2.16 ug/L 12/03/22 20:43 12/06/22 23:34 Di-n-octyl phthalate ND 9.37 2.62 ug/L 12/03/22 20:43 12/06/22 23:34 Fluoranthene ND 9.37 1.50 ug/L 12/03/22 20:43 12/06/22 23:34 Fluorene ND 9.37 3.19 ug/L 12/03/22 20:43 12/06/22 23:34 Hexachlorobenzene ND 9.37 1.50 ug/L 12/03/22 20:43 12/06/22 23:34 Hexachlorobutadiene ND 9.37 3.75 ug/L 12/03/22 20:43 12/06/22 23:34 Hexachlorocyclopentadiene ND 9.37 3.28 ug/L 12/03/22 20:43 12/06/22 23:34 Hexachloroethane ND 9.37 3.37 ug/L 12/03/22 20:43 12/06/22 23:34 Indeno[1,2,3-cd]pyrene ND 9.37 4.03 ug/L 12/03/22 20:43 12/06/22 23:34 Isophorone ND 9.37 1.87 ug/L 12/03/22 20:43 12/06/22 23:34 Naphthalene ND 9.37 3.28 ug/L 12/03/22 20:43 12/06/22 23:34 Nitrobenzene ND 9.37 3.28 ug/L 12/03/22 20:43 12/06/22 23:34 N-Nitrosodi-n-propylamine ND 9.37 2.25 ug/L 12/03/22 20:43 12/06/22 23:34 N-Nitrosodiphenylamine ND 9.37 2.72 ug/L 12/03/22 20:43 12/06/22 23:34 Pentachlorophenol ND 46.9 9.28 ug/L 12/03/22 20:43 12/06/22 23:34 Phenanthrene ND 9.37 4.03 ug/L 12/03/22 20:43 12/06/22 23:34 Phenol ND 9.37 1.41 ug/L 12/03/22 20:43 12/06/22 23:34 Dil Fac 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Eurofins Savannah Page 9 of 28 12/7/2022 Client Sample Results Client: ECS Southeast LLP Job ID: 680-226360-1 Project/Site: Wrights Executive Sales Client Sample ID: WS-4 Lab Sample ID: 680-226360-1 Date Collected: 11/28/22 10:30 Matrix: Water Date Received: 11/29/22 07:00 Method: SW846 8270E - Semivolatile Organic Compounds (GC/MS) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Pyrene ND 9.37 3.47 ug/L 12/03/22 20:43 12/06/22 23:34 1 • Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 2,4,6-Tribromophenol (Surr) 108 30 - 130 12103122 20:43 12106122 23:34 1 2-Fluorobiphenyl (Surr) 86 25 - 130 12103122 20:43 12106122 23:34 1 2-Fluorophenol (Surr) 37 10 - 130 12103122 20:43 12106122 23:34 1 Nitrobenzene-d5 (Surr) 80 30 - 130 12103122 20:43 12106122 23:34 1 Phenol-d5 (Surr) 27 10 - 130 12103122 20:43 12106122 23:34 1 Terphenyl-04 (Surr) 102 35 - 131 12103122 20:43 12106122 23:34 1 Eurofins Savannah Page 10 of 28 12/7/2022 QC Sample Results Client: ECS Southeast LLP Project/Site: Wrights Executive Sales Method: 8260D - Volatile Organic Compounds by GUMS Job ID: 680-226360-1 FLab Sample ID: LB 680-75311311-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 753755 LB LB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane ND 20.0 7.20 ug/L 12/06/22 18:59 20 1,1,1-Trichloroethane ND 20.0 4.20 ug/L 12/06/22 18:59 20 1,1,2,2-Tetrachloroethane ND 20.0 8.00 ug/L 12/06/22 18:59 20 1,1,2-Trichloro-1,2,2-trifluoroethane ND 20.0 4.60 ug/L 12/0612218:59 20 1,1,2-Trichloroethane ND 20.0 6.40 ug/L 12/0612218:59 20 1,1-Dichloroethane ND 20.0 6.60 ug/L 12/0612218:59 20 1,1-Dichloroethene ND 20.0 6.60 ug/L 12/06/22 18:59 20 1,1-Dichloropropene ND 20.0 5.60 ug/L 12/06/22 18:59 20 1,2,3-Trichlorobenzene ND 100 16.2 ug/L 12/06/22 18:59 20 1,2,3-Trichloropropane ND 20.0 9.60 ug/L 12/06/22 18:59 20 1,2,4-Trichlorobenzene ND 100 10.6 ug/L 12/06/22 18:59 20 1,2,4-Trimethylbenzene ND 20.0 8.60 ug/L 12/06/22 18:59 20 1,2-Dibromo-3-Chloropropane ND 100 36.0 ug/L 12/06/22 18:59 20 1,2-Dichlorobenzene ND 20.0 6.20 ug/L 12/06/22 18:59 20 1,2-Dichloroethane ND 20.0 5.00 ug/L 12/06/22 18:59 20 1,2-Dichloropropane ND 20.0 4.40 ug/L 12/06/22 18:59 20 1,3,5-Trimethylbenzene ND 20.0 5.60 ug/L 12/06/22 18:59 20 1,3-Dichlorobenzene ND 20.0 6.20 ug/L 12/06/22 18:59 20 1,3-Dichloropropane ND 20.0 7.20 ug/L 12/0612218:59 20 1,4-Dichlorobenzene ND 20.0 6.20 ug/L 12/0612218:59 20 2,2-Dichloropropane ND 20.0 7.00 ug/L 12/0612218:59 20 2-Butanone (MEK) ND 200 128 ug/L 12/06/22 18:59 20 2-Chlorotoluene ND 20.0 5.00 ug/L 12/06/22 18:59 20 2-Hexanone ND 200 64.0 ug/L 12/06/22 18:59 20 4-Chlorotoluene ND 20.0 8.20 ug/L 12/06/22 18:59 20 4-Isopropyltoluene ND 20.0 8.80 ug/L 12/06/22 18:59 20 4-Methyl-2-pentanone (MIBK) ND 200 54.0 ug/L 12/06/22 18:59 20 Acetone ND 200 74.0 ug/L 12/06/22 18:59 20 Acrylonitrile ND 400 110 ug/L 12/06/22 18:59 20 Benzene ND 20.0 5.40 ug/L 12/06/22 18:59 20 Bromobenzene ND 20.0 4.80 ug/L 12/06/22 18:59 20 Bromoform ND 20.0 11.8 ug/L 12/06/22 18:59 20 Bromomethane ND 100 74.0 ug/L 12/06/22 18:59 20 Carbon disulfide ND 40.0 8.60 ug/L 12/06/22 18:59 20 Carbon tetrachloride ND 20.0 6.00 ug/L 12/06/22 18:59 20 Chlorobenzene ND 20.0 3.00 ug/L 12/06/22 18:59 20 Chlorobromomethane ND 20.0 6.80 ug/L 12/06/22 18:59 20 Chlorodibromomethane ND 20.0 7.80 ug/L 12/06/22 18:59 20 Chloroethane ND 100 92.0 ug/L 12/06/22 18:59 20 Chloroform ND 20.0 5.40 ug/L 12/06/22 18:59 20 Chloromethane ND 20.0 10.8 ug/L 12/06/22 18:59 20 cis-1,2-Dichloroethene ND 20.0 5.00 ug/L 12/06/22 18:59 20 cis-1,3-Dichloropropene ND 20.0 5.20 ug/L 12/06/22 18:59 20 Dibromomethane ND 20.0 6.80 ug/L 12/06/22 18:59 20 Dichlorobromomethane ND 20.0 5.00 ug/L 12/06/22 18:59 20 Dichlorodifluoromethane ND 20.0 7.20 ug/L 12/06/22 18:59 20 Ethyl acetate ND 200 100 ug/L 12/06/22 18:59 20 Ethylbenzene ND 20.0 4.00 ug/L 12/06/22 18:59 20 Eurofins Savannah Page 11 of 28 12/7/2022 QC Sample Results Client: ECS Southeast LLP Project/Site: Wrights Executive Sales Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Job ID: 680-226360-1 Lab Sample ID: LB 680-75311311-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 753755 LB LB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Ethylene Dibromide ND 20.0 6.60 ug/L 12/06/22 18:59 20 Hexachlorobutadiene ND 100 4.40 ug/L 12/06/22 18:59 20 Hexane ND 100 13.0 ug/L 12/06/22 18:59 20 lodomethane ND 200 78.0 ug/L 12/06/22 18:59 20 Isopropyl ether ND 200 14.0 ug/L 12/06/22 18:59 20 Isopropyl benzene ND 20.0 5.20 ug/L 12/06/22 18:59 20 Methyl tert-butyl ether ND 100 16.2 ug/L 12/06/22 18:59 20 Methylene Chloride ND 100 64.0 ug/L 12/06/22 18:59 20 m-Xylene & p-Xylene ND 20.0 9.80 ug/L 12/06/22 18:59 20 Naphthalene ND 100 48.0 ug/L 12/06/22 18:59 20 n-Butylbenzene ND 20.0 10.4 ug/L 12/06/22 18:59 20 n-Heptane ND 20.0 8.60 ug/L 12/06/22 18:59 20 N-Propylbenzene ND 20.0 8.20 ug/L 12/06/22 18:59 20 o-Xylene ND 20.0 5.20 ug/L 12/06/22 18:59 20 sec-Butylbenzene ND 20.0 10.6 ug/L 12/06/22 18:59 20 Styrene ND 20.0 5.40 ug/L 12/06/22 18:59 20 tert-Butylbenzene ND 20.0 8.60 ug/L 12/06/22 18:59 20 Tetrachloroethene ND 10.0 7.00 ug/L 12/06/22 18:59 20 Toluene ND 20.0 5.00 ug/L 12/06/22 18:59 20 trans-1,2-Dichloroethene ND 20.0 6.80 ug/L 12/06/22 18:59 20 trans-1,3-Dichloropropene ND 20.0 4.60 ug/L 12/06/22 18:59 20 trans-1,4-Dichloro-2-butene ND 40.0 25.0 ug/L 12/0612218:59 20 Trichloroethene ND 20.0 4.00 ug/L 12/0612218:59 20 Trichlorofluoromethane ND 20.0 6.60 ug/L 12/06/22 18:59 20 Vinyl acetate ND 40.0 13.8 ug/L 12/06/22 18:59 20 Vinyl chloride ND 20.0 8.00 ug/L 12/06/22 18:59 20 Xylenes, Total ND 20.0 4.60 ug/L 12/06/22 18:59 20 LB LB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 97 60- 124 12/06/22 18:59 20 4-Bromofluorobenzene (Surr) 110 70 - 130 12/06/22 18:59 20 Dibromofluoromethane (Surr) 109 70 - 130 12/06/22 18:59 20 Toluene-d8 (Surr) 113 70 - 130 12106122 18:59 20 Lab Sample ID: MB 680-753755/9 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 753755 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed oil Fac 1,1,1,2-Tetrachloroethane ND 1.00 0.360 ug/L 12/06/2213:30 1 1,1,1-Trichloroethane ND 1.00 0.210 ug/L 12/06/2213:30 1 1,1,2,2-Tetrachloroethane ND 1.00 0.400 ug/L 12/06/2213:30 1 1,1,2-Trichloro-1,2,2-trifluoroethane ND 1.00 0.230 ug/L 12/06/2213:30 1 1,1,2-Trichloroethane ND 1.00 0.320 ug/L 12/06/2213:30 1 1,1-Dichloroethane ND 1.00 0.330 ug/L 12/06/2213:30 1 1,1-Dichloroethene ND 1.00 0.330 ug/L 12/06/2213:30 1 1,1-Dichloropropene ND 1.00 0.280 ug/L 12/06/2213:30 1 1,2,3-Trichlorobenzene 0.9131 J 5.00 0.810 ug/L 12/06/2213:30 1 Eurofins Savannah Page 12 of 28 12/7/2022 QC Sample Results Client: ECS Southeast LLP Project/Site: Wrights Executive Sales Job ID: 680-226360-1 Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: MB 680-753755/9 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 753755 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,2,3-Trichloropropane ND 1.00 0.480 ug/L 12/06/22 13:30 1 1,2,4-Trichlorobenzene 0.6304 J 5.00 0.530 ug/L 12/06/22 13:30 1 1,2,4-Trimethylbenzene ND 1.00 0.430 ug/L 12/06/22 13:30 1 1,2-Dibromo-3-Chloropropane ND 5.00 1.80 ug/L 12/06/22 13:30 1 1,2-Dichlorobenzene ND 1.00 0.310 ug/L 12/06/22 13:30 1 1,2-Dichloroethane ND 1.00 0.250 ug/L 12/06/22 13:30 1 1,2-Dichloropropane ND 1.00 0.220 ug/L 12/06/22 13:30 1 1,3,5-Trimethylbenzene ND 1.00 0.280 ug/L 12/06/22 13:30 1 1,3-Dichlorobenzene ND 1.00 0.310 ug/L 12/06/22 13:30 1 1,3-Dichloropropane ND 1.00 0.360 ug/L 12/06/22 13:30 1 1,4-Dichlorobenzene ND 1.00 0.310 ug/L 12/06/22 13:30 1 2,2-Dichloropropane ND 1.00 0.350 ug/L 12/06/22 13:30 1 2-Butanone (MEK) ND 10.0 6.40 ug/L 12/06/22 13:30 1 2-Chlorotoluene ND 1.00 0.250 ug/L 12/06/22 13:30 1 2-Hexanone ND 10.0 3.20 ug/L 12/06/22 13:30 1 4-Chlorotoluene ND 1.00 0.410 ug/L 12/06/22 13:30 1 4-Isopropyltoluene ND 1.00 0.440 ug/L 12/06/22 13:30 1 4-Methyl-2-pentanone (MIBK) ND 10.0 2.70 ug/L 12/06/22 13:30 1 Acetone ND 10.0 3.70 ug/L 12/06/22 13:30 1 Acrylonitrile ND 20.0 5.50 ug/L 12/06/22 13:30 1 Benzene ND 1.00 0.270 ug/L 12/06/22 13:30 1 Bromobenzene ND 1.00 0.240 ug/L 12/06/22 13:30 1 Bromoform ND 1.00 0.590 ug/L 12/06/22 13:30 1 Bromomethane ND 5.00 3.70 ug/L 12/06/22 13:30 1 Carbon disulfide ND 2.00 0.430 ug/L 12/06/22 13:30 1 Carbon tetrachloride ND 1.00 0.300 ug/L 12/06/22 13:30 1 Chlorobenzene ND 1.00 0.150 ug/L 12/06/22 13:30 1 Chlorobromomethane ND 1.00 0.340 ug/L 12/06/22 13:30 1 Chlorodibromomethane ND 1.00 0.390 ug/L 12/06/22 13:30 1 Chloroethane ND 5.00 4.60 ug/L 12/06/22 13:30 1 Chloroform ND 1.00 0.270 ug/L 12/06/22 13:30 1 Chloromethane ND 1.00 0.540 ug/L 12/06/22 13:30 1 cis-1,2-Dichloroethene ND 1.00 0.250 ug/L 12/06/22 13:30 1 cis- 1,3-Dichloropropene ND 1.00 0.260 ug/L 12/06/22 13:30 1 Dibromomethane ND 1.00 0.340 ug/L 12/06/22 13:30 1 Dichlorobromomethane ND 1.00 0.250 ug/L 12/06/22 13:30 1 Dichlorodifluoromethane ND 1.00 0.360 ug/L 12/06/22 13:30 1 Ethyl acetate ND 10.0 5.00 ug/L 12/06/22 13:30 1 Ethylbenzene ND 1.00 0.200 ug/L 12/06/22 13:30 1 Ethylene Dibromide ND 1.00 0.330 ug/L 12/06/22 13:30 1 Hexachlorobutadiene ND 5.00 0.220 ug/L 12/06/22 13:30 1 Hexane ND 5.00 0.650 ug/L 12/06/22 13:30 1 lodomethane ND 10.0 3.90 ug/L 12/06/22 13:30 1 Isopropyl ether ND 10.0 0.700 ug/L 12/06/22 13:30 1 Isopropylbenzene ND 1.00 0.260 ug/L 12/06/22 13:30 1 Methyl tert-butyl ether ND 5.00 0.810 ug/L 12/06/22 13:30 1 Methylene Chloride ND 5.00 3.20 ug/L 12/06/22 13:30 1 m-Xylene & p-Xylene ND 1.00 0.490 ug/L 12/06/22 13:30 1 Naphthalene ND 5.00 2.40 ug/L 12/06/22 13:30 1 Eurofins Savannah Page 13 of 28 12/7/2022 QC Sample Results Client: ECS Southeast LLP Project/Site: Wrights Executive Sales Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Job ID: 680-226360-1 Lab Sample ID: MB 680-753755/9 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 753755 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac n-Butylbenzene ND 1.00 0.520 ug/L 12/06/22 13:30 1 n-Heptane ND 1.00 0.430 ug/L 12/06/22 13:30 1 N-Propylbenzene ND 1.00 0.410 ug/L 12/06/22 13:30 1 o-Xylene ND 1.00 0.260 ug/L 12/06/22 13:30 1 sec-Butylbenzene ND 1.00 0.530 ug/L 12/06/22 13:30 1 Styrene ND 1.00 0.270 ug/L 12/06/22 13:30 1 tert-Butylbenzene ND 1.00 0.430 ug/L 12/06/22 13:30 1 Tetrachloroethene ND 0.500 0.350 ug/L 12/06/22 13:30 1 Toluene ND 1.00 0.250 ug/L 12/0612213:30 1 trans-1,2-Dichloroethene ND 1.00 0.340 ug/L 12/0612213:30 1 trans-1,3-Dichloropropene ND 1.00 0.230 ug/L 12/06/22 13:30 1 trans-1,4-Dichloro-2-butene ND 2.00 1.25 ug/L 12/06/22 13:30 1 Trichloroethene ND 1.00 0.200 ug/L 12/06/22 13:30 1 Trichlorofluoromethane ND 1.00 0.330 ug/L 12/06/22 13:30 1 Vinyl acetate ND 2.00 0.690 ug/L 12/06/22 13:30 1 Vinyl chloride ND 1.00 0.400 ug/L 12/06/22 13:30 1 Xylenes, Total ND 1.00 0.230 ug/L 12/06/22 13:30 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 98 60- 124 12106122 13:30 1 4-Bromofluorobenzene (Surr) 113 70 - 130 12106122 13:30 1 Dibromotluoromethane (Surr) 108 70 - 130 12106122 13:30 1 Toluene-d8 (Surr) 111 70 - 130 12/06/22 13:30 1 Lab Sample ID: LCS 680-753755/5 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 753755 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,1,1,2-Tetrachloroethane 50.0 54.32 ug/L 109 70-130 1,1,1-Trichloroethane 50.0 51.51 ug/L 103 70-130 1,1,2,2-Tetrachloroethane 50.0 51.49 ug/L 103 70-130 1,1,2-Trichloro-1,2,2-trifluoroetha 50.0 56.65 ug/L 113 63-141 ne 1,1,2-Trichloroethane 50.0 50.33 ug/L 101 70-130 1,1-Dichloroethane 50.0 55.20 ug/L 110 70-130 1,1-Dichloroethene 50.0 53.32 ug/L 107 70-130 1,1-Dichloropropene 50.0 53.63 ug/L 107 70-130 1,2,3-Trichlorobenzene 50.0 78.05 *+ ug/L 156 61 - 141 1,2,3-Trichloropropane 50.0 50.07 ug/L 100 70 - 130 1,2,4-Trichlorobenzene 50.0 68.97 *+ ug/L 138 70 - 130 1,2,4-Trimethylbenzene 50.0 51.38 ug/L 103 70 - 130 1,2-Dibromo-3-Chloropropane 50.0 66.11 *+ ug/L 132 70 - 130 1,2-Dichlorobenzene 50.0 56.81 ug/L 114 70 - 130 1,2-Dichloroethane 50.0 51.56 ug/L 103 70 - 130 1,2-Dichloropropane 50.0 55.58 ug/L ill 70-130 1,3,5-Trimethylbenzene 50.0 51.66 ug/L 103 70 - 130 1,3-Dichlorobenzene 50.0 54.84 ug/L 110 70 - 130 1,3-Dichloropropane 50.0 51.45 ug/L 103 70 - 130 Eurofins Savannah Page 14 of 28 12/7/2022 QC Sample Results Client: ECS Southeast LLP Job ID: 680-226360-1 Project/Site: Wrights Executive Sales Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCS 680-753755/5 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 753755 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,4-Dichlorobenzene 50.0 51.00 ug/L 102 70 - 130 2,2-Dichloropropane 50.0 52.91 ug/L 106 70 - 130 2-Butanone (MEK) 250 282.5 ug/L 113 69 - 120 2-Chlorotoluene 50.0 50.71 ug/L 101 70 - 130 2-Hexanone 250 276.0 ug/L 110 70 - 130 4-Chlorotoluene 50.0 49.51 ug/L 99 70 - 130 4-Isopropyltoluene 50.0 57.52 ug/L 115 70 - 130 4-Methyl-2-pentanone (MIBK) 250 284.6 ug/L 114 68 - 120 Acetone 250 265.3 ug/L 106 67 - 120 Acrylonitrile 500 588.1 ug/L 118 70 - 130 Benzene 50.0 53.19 ug/L 106 70 - 130 Bromobenzene 50.0 51.60 ug/L 103 70 - 130 Bromoform 50.0 42.44 ug/L 85 69 - 129 Bromomethane 50.0 51.53 ug/L 103 28 - 192 Carbon disulfide 50.0 58.82 ug/L 118 70 - 130 Carbon tetrachloride 50.0 54.63 ug/L 109 70 - 130 Chlorobenzene 50.0 52.22 ug/L 104 70 - 130 Chlorobromomethane 50.0 51.06 ug/L 102 70 - 130 Chlorodibromomethane 50.0 51.79 ug/L 104 70 - 130 Chloroethane 50.0 52.97 ug/L 106 31 - 213 Chloroform 50.0 54.15 ug/L 108 70 - 130 Chloromethane 50.0 53.56 ug/L 107 59 - 127 cis-1,2-Dichloroethene 50.0 54.33 ug/L 109 70 - 130 cis-1,3-Dichloropropene 50.0 54.63 ug/L 109 70 - 130 Dibromomethane 50.0 53.07 ug/L 106 70 - 130 Dichlorobromomethane 50.0 55.76 ug/L 112 70 - 130 Dichlorodifluoromethane 50.0 62.25 ug/L 124 70 - 130 Ethylbenzene 50.0 54.46 ug/L 109 70 - 130 Ethylene Dibromide 50.0 51.20 ug/L 102 70 - 130 Hexachlorobutadiene 50.0 59.83 ug/L 120 70 - 130 Hexane 50.0 49.92 ug/L 100 70 - 130 lodomethane 50.0 45.27 ug/L 91 52 - 129 Isopropyl benzene 50.0 53.74 ug/L 107 70 - 130 Methyl tert-butyl ether 50.0 56.53 ug/L 113 70 - 130 Methylene Chloride 50.0 57.77 ug/L 116 70 - 130 m-Xylene & p-Xylene 50.0 54.04 ug/L 108 70 - 130 Naphthalene 50.0 85.23 .+ ug/L 170 57 - 149 n-Butylbenzene 50.0 57.52 ug/L 115 70 - 130 n-Heptane 50.0 46.79 ug/L 94 65 - 120 N-Propylbenzene 50.0 53.92 ug/L 108 70 - 130 o-Xylene 50.0 54.58 ug/L 109 70 - 130 sec-Butylbenzene 50.0 52.41 ug/L 105 70 - 130 Styrene 50.0 54.41 ug/L 109 70 - 130 tert-Butylbenzene 50.0 51.71 ug/L 103 70 - 130 Tetrachloroethene 50.0 48.43 ug/L 97 70 - 130 Toluene 50.0 49.45 ug/L 99 70 - 130 trans-1,2-Dichloroethene 50.0 57.50 ug/L 115 70 - 130 trans-1,3-Dichloropropene 50.0 54.03 ug/L 108 70 - 130 trans-1,4-Dichloro-2-butene 50.0 48.11 ug/L 96 67 - 120 Eurofins Savannah Page 15 of 28 12/7/2022 QC Sample Results Client: ECS Southeast LLP Project/Site: Wrights Executive Sales Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Job ID: 680-226360-1 Lab Sample ID: LCS 680-753755/5 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 753755 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Trichloroethene 50.0 51.83 ug/L 104 70 - 130 Trichlorofluoromethane 50.0 33.78 ug/L 68 63 - 142 Vinyl acetate 100 130.5 ug/L 131 67 - 135 Vinyl chloride 50.0 69.49 *+ ug/L 139 66 - 129 Xylenes, Total 100 108.6 ug/L 109 70 - 130 LCS LCS Surrogate %Recovery Qualifier Limits 1,2-Dichloroethane-d4 (Surr) 103 60- 124 4-Bromofluorobenzene (Surr) 109 70 - 130 Dibromofluoromethane (Surr) ill 70- 130 Toluene-d8 (Surr) 112 70 - 130 Lab Sample ID: LCSD 680-75375516 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 753755 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit 1,1,1,2-Tetrachloroethane 50.0 54.05 ug/L 108 70-130 1 30 1,1,1-Trichloroethane 50.0 51.52 ug/L 103 70-130 0 30 1,1,2,2-Tetrachloroethane 50.0 50.92 ug/L 102 70-130 1 30 1,1,2-Trichloro-1,2,2-trifluoroetha 50.0 59.16 ug/L 118 63-141 4 30 ne 1,1,2-Trichloroethane 50.0 48.24 ug/L 96 70-130 4 30 1,1-Dichloroethane 50.0 54.35 ug/L 109 70-130 2 30 1,1-Dichloroethene 50.0 53.78 ug/L 108 70-130 1 20 1,1-Dichloropropene 50.0 53.29 ug/L 107 70-130 1 20 1,2,3-Trichlorobenzene 50.0 78.77 *+ ug/L 158 61 - 141 1 30 1,2,3-Trichloropropane 50.0 49.28 ug/L 99 70 - 130 2 30 1,2,4-Trichlorobenzene 50.0 69.63 *+ ug/L 139 70 - 130 1 30 1,2,4-Trimethylbenzene 50.0 52.12 ug/L 104 70 - 130 1 30 1,2-Dibromo-3-Chloropropane 50.0 71.20 *+ ug/L 142 70 - 130 7 30 1,2-Dichlorobenzene 50.0 56.12 ug/L 112 70 - 130 1 30 1,2-Dichloroethane 50.0 53.13 ug/L 106 70 - 130 3 50 1,2-Dichloropropane 50.0 54.48 ug/L 109 70 - 130 2 20 1,3,5-Trimethylbenzene 50.0 51.98 ug/L 104 70 - 130 1 30 1,3-Dichlorobenzene 50.0 54.41 ug/L 109 70 - 130 1 30 1,3-Dichloropropane 50.0 51.19 ug/L 102 70 - 130 1 20 1,4-Dichlorobenzene 50.0 50.93 ug/L 102 70 - 130 0 30 2,2-Dichloropropane 50.0 53.06 ug/L 106 70 - 130 0 20 2-Butanone (MEK) 250 270.5 ug/L 108 69 - 120 4 30 2-Chlorotoluene 50.0 51.16 ug/L 102 70 - 130 1 30 2-Hexanone 250 276.6 ug/L ill 70 - 130 0 20 4-Chlorotoluene 50.0 49.82 ug/L 100 70 - 130 1 30 4-Isopropyltoluene 50.0 57.27 ug/L 115 70 - 130 0 30 4-Methyl-2-pentanone (MIBK) 250 282.4 ug/L 113 68 - 120 1 30 Acetone 250 275.2 ug/L 110 67 - 120 4 30 Acrylonitrile 500 582.5 ug/L 117 70 - 130 1 30 Benzene 50.0 52.83 ug/L 106 70 - 130 1 30 Bromobenzene 50.0 52.10 ug/L 104 70 - 130 1 30 Eurofins Savannah Page 16 of 28 12/7/2022 QC Sample Results Client: ECS Southeast LLP Project/Site: Wrights Executive Sales Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Lab Sample ID: LCSD 680-753755/6 Matrix: Water Analysis Batch: 753755 Analvte Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorobromomethane Ch lorod i bromo methane Chloroethane Chloroform Chloromethane cis-1,2-Dichloroethene cis-1,3-Dichloropropene Dibromomethane Dichlorobromomethane Dichlorodifluoromethane Ethylbenzene Ethylene Dibromide Hexachlorobutadiene Hexane lodomethane Isopropyl benzene Methyl tert-butyl ether Methylene Chloride m-Xylene & p-Xylene Naphthalene n-Butylbenzene n-Heptane N-Propylbenzene o-Xylene sec-Butylbenzene Styrene tert-Butylbenzene Tetrachloroethene Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene trans-1,4-Dichloro-2-butene Trichloroethene Tri c h l o rof I u o ro m eth a n e Vinyl acetate Vinyl chloride Xylenes, Total Surrogate 1,2-Dichloroefhane-d4 (Surr) 4-Bromofluorobenzene (Surr) Dibromofluoromethane (Surr) Toluene-d8 (Surr) LCSD LCSD %Recovery Qualifier 102 108 107 114 Job ID: 680-226360-1 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA Spike LCSD LCSD %Rec RPD Added Result Qualifier Unit D %Rec Limits RPD Limit 50.0 42.81 ug/L 86 69 - 129 1 30 50.0 52.17 ug/L 104 28 - 192 1 30 50.0 58.06 ug/L 116 70 - 130 1 30 50.0 54.73 ug/L 109 70 - 130 0 30 50.0 52.59 ug/L 105 70 - 130 1 30 50.0 47.83 ug/L 96 70 - 130 7 30 50.0 51.62 ug/L 103 70 - 130 0 30 50.0 52.34 ug/L 105 31 - 213 1 30 50.0 53.66 ug/L 107 70 - 130 1 30 50.0 54.81 ug/L 110 59 - 127 2 30 50.0 54.36 ug/L 109 70 - 130 0 30 50.0 55.59 ug/L ill 70 - 130 2 20 50.0 51.21 ug/L 102 70 - 130 4 30 50.0 55.53 ug/L 111 70 - 130 0 30 50.0 69.10 *+ ug/L 138 70 - 130 10 40 50.0 55.59 ug/L 111 70 - 130 2 20 50.0 50.65 ug/L 101 70 - 130 1 30 50.0 59.16 ug/L 118 70 - 130 1 20 50.0 50.79 ug/L 102 70 - 130 2 30 50.0 46.27 ug/L 93 52 - 129 2 30 50.0 55.20 ug/L 110 70 - 130 3 30 50.0 56.61 ug/L 113 70 - 130 0 30 50.0 54.38 ug/L 109 70 - 130 6 30 50.0 53.60 ug/L 107 70 - 130 1 30 50.0 88.39 *+ ug/L 177 57 - 149 4 30 50.0 57.12 ug/L 114 70 - 130 1 30 50.0 45.77 ug/L 92 65 - 120 2 30 50.0 54.79 ug/L 110 70 - 130 2 30 50.0 54.74 ug/L 109 70 - 130 0 30 50.0 52.58 ug/L 105 70 - 130 0 30 50.0 54.40 ug/L 109 70 - 130 0 30 50.0 50.87 ug/L 102 70 - 130 2 30 50.0 47.89 ug/L 96 70 - 130 1 30 50.0 49.88 ug/L 100 70 - 130 1 30 50.0 56.55 ug/L 113 70 - 130 2 30 50.0 55.59 ug/L 111 70 - 130 3 30 50.0 46.86 ug/L 94 67 - 120 3 30 50.0 53.63 ug/L 107 70 - 130 3 30 50.0 35.58 ug/L 71 63 - 142 5 30 100 104.5 ug/L 104 67 - 135 22 30 50.0 70.46 *+ ug/L 141 66 - 129 1 30 100 108.3 ug/L 108 70 - 130 0 30 Limits 60 - 124 70 - 130 70 - 130 70 - 130 Page 17 of 28 Eurofins Savannah 12/7/2022 QC Sample Results Client: ECS Southeast LLP Project/Site: Wrights Executive Sales Method: 8270E - Semivolatile Organic Compounds (GC/MS) Job ID: 680-226360-1 FLab Sample ID: MB 680-753436/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 753876 Prep Batch: 753436 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1'-Biphenyl ND 10.0 4.60 ug/L 12/03/22 20:43 12/06/22 17:33 1 2,4,5-Trichlorophenol ND 10.0 3.30 ug/L 12/03/22 20:43 12/06/22 17:33 1 2,4,6-Trichlorophenol ND 10.0 2.20 ug/L 12/03/22 20:43 12/06/22 17:33 1 2,4-Dichlorophenol ND 10.0 3.70 ug/L 12/03/22 20:43 12/06/22 17:33 1 2,4-Dimethylphenol ND 10.0 3.00 ug/L 12/03/22 20:43 12/06/22 17:33 1 2,4-Dinitrophenol ND 50.0 16.0 ug/L 12/03/22 20:43 12/06/22 17:33 1 2,4-Dinitrotoluene ND 10.0 2.30 ug/L 12/03/22 20:43 12/06/22 17:33 1 2,6-Dinitrotoluene ND 10.0 2.80 ug/L 12/03/22 20:43 12/06/22 17:33 1 2-Chloronaphthalene ND 10.0 4.80 ug/L 12/03/22 20:43 12/06/22 17:33 1 2-Chlorophenol ND 10.0 3.20 ug/L 12/03/22 20:43 12/06/22 17:33 1 2-Methylnaphthalene ND 10.0 4.60 ug/L 12/03/22 20:43 12/06/22 17:33 1 2-Methylphenol ND 10.0 1.80 ug/L 12/03/22 20:43 12/06/22 17:33 1 2-Nitroaniline ND 50.0 2.90 ug/L 12/03/22 20:43 12/06/22 17:33 1 2-Nitrophenol ND 10.0 3.90 ug/L 12/03/22 20:43 12/06/22 17:33 1 3 & 4 Methylphenol ND 10.0 1.40 ug/L 12/03/22 20:43 12/06/22 17:33 1 3,3'-Dichlorobenzidine ND 60.0 10.0 ug/L 12/03/22 20:43 12/06/22 17:33 1 3-Nitroaniline ND 50.0 3.00 ug/L 12/03/22 20:43 12/06/22 17:33 1 4,6-Dinitro-2-methylphenol ND 50.0 5.30 ug/L 12/03/22 20:43 12/06/22 17:33 1 4-Bromophenyl phenyl ether ND 10.0 4.70 ug/L 12/03/22 20:43 12/06/22 17:33 1 4-Chloro-3-methylphenol ND 10.0 2.50 ug/L 12/03/22 20:43 12/06/22 17:33 1 4-Chloroaniline ND 20.0 1.00 ug/L 12/03/22 20:43 12/06/22 17:33 1 4-Chlorophenyl phenyl ether ND 10.0 5.30 ug/L 12/03/22 20:43 12/06/22 17:33 1 4-Nitroaniline ND 50.0 3.00 ug/L 12/03/22 20:43 12/06/22 17:33 1 4-Nitrophenol ND 50.0 8.10 ug/L 12/03/22 20:43 12/06/22 17:33 1 Acenaphthene ND 10.0 4.40 ug/L 12/03/22 20:43 12/06/22 17:33 1 Acenaphthylene ND 10.0 3.60 ug/L 12/03/22 20:43 12/06/22 17:33 1 Acetophenone ND 10.0 2.20 ug/L 12/03/22 20:43 12/06/22 17:33 1 Anthracene ND 10.0 3.60 ug/L 12/03/22 20:43 12/06/22 17:33 1 Atrazine ND 10.0 2.20 ug/L 12/03/22 20:43 12/06/22 17:33 1 Benzaldehyde ND 10.0 4.80 ug/L 12/03/22 20:43 12/06/22 17:33 1 Benzo[a]anthracene ND 10.0 4.20 ug/L 12/03/22 20:43 12/06/22 17:33 1 Benzo[a]pyrene ND 10.0 2.80 ug/L 12/03/22 20:43 12/06/22 17:33 1 Benzo[b]fluoranthene ND 10.0 3.10 ug/L 12/03/22 20:43 12/06/22 17:33 1 Benzo[g,h,i]perylene ND 10.0 3.00 ug/L 12/03/22 20:43 12/06/22 17:33 1 Benzo[k]fluoranthene ND 10.0 2.90 ug/L 12/03/22 20:43 12/06/22 17:33 1 bis (2-chloroisopropyl) ether ND 10.0 3.10 ug/L 12/03/22 20:43 12/06/22 17:33 1 Bis(2-chloroethoxy)methane ND 10.0 1.80 ug/L 12/03/22 20:43 12/06/22 17:33 1 Bis(2-chloroethyl)ether ND 10.0 3.60 ug/L 12/03/22 20:43 12/06/22 17:33 1 Bis(2-ethylhexyl) phthalate ND 10.0 3.00 ug/L 12/03/22 20:43 12/06/22 17:33 1 Butyl benzyl phthalate ND 10.0 2.80 ug/L 12/03/22 20:43 12/06/22 17:33 1 Caprolactam ND 10.0 2.80 ug/L 12/03/22 20:43 12/06/22 17:33 1 Carbazole ND 10.0 1.80 ug/L 12/03/22 20:43 12/06/22 17:33 1 Chrysene ND 10.0 3.80 ug/L 12/03/22 20:43 12/06/22 17:33 1 Dibenz(a,h)anthracene ND 10.0 3.00 ug/L 12/03/22 20:43 12/06/22 17:33 1 Dibenzofuran ND 10.0 1.90 ug/L 12/03/22 20:43 12/06/22 17:33 1 Diethyl phthalate ND 10.0 2.20 ug/L 12/03/22 20:43 12/06/22 17:33 1 Dimethyl phthalate ND 10.0 2.10 ug/L 12/03/22 20:43 12/06/22 17:33 1 Di-n-butyl phthalate ND 10.0 2.30 ug/L 12/03/22 20:43 12/06/22 17:33 1 Eurofins Savannah Page 18 of 28 12/7/2022 QC Sample Results Client: ECS Southeast LLP Project/Site: Wrights Executive Sales Job ID: 680-226360-1 Method: 8270E - Semivolatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: MB 680-753436/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 753876 Prep Batch: 753436 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Di-n-octyl phthalate ND 10.0 2.80 ug/L 12/03/22 20:43 12/06/22 17:33 1 Fluoranthene ND 10.0 1.60 ug/L 12/03/22 20:43 12/06/22 17:33 1 Fluorene ND 10.0 3.40 ug/L 12/03/22 20:43 12/06/22 17:33 1 Hexachlorobenzene ND 10.0 1.60 ug/L 12/03/22 20:43 12/06/22 17:33 1 Hexachlorobutadiene ND 10.0 4.00 ug/L 12/03/22 20:43 12/06/22 17:33 1 Hexachlorocyclopentadiene ND 10.0 3.50 ug/L 12/03/22 20:43 12/06/22 17:33 1 Hexachloroethane ND 10.0 3.60 ug/L 12/03/22 20:43 12/06/22 17:33 1 Indeno[1,2,3-cd]pyrene ND 10.0 4.30 ug/L 12/03/22 20:43 12/06/22 17:33 1 Isophorone ND 10.0 2.00 ug/L 12/03/22 20:43 12/06/22 17:33 1 Naphthalene ND 10.0 3.50 ug/L 12/03/22 20:43 12/06/22 17:33 1 Nitrobenzene ND 10.0 3.50 ug/L 12/03/22 20:43 12/06/22 17:33 1 N-Nitrosodi-n-propylamine ND 10.0 2.40 ug/L 12/03/22 20:43 12/06/22 17:33 1 N-Nitrosodiphenylamine ND 10.0 2.90 ug/L 12/03/22 20:43 12/06/22 17:33 1 Pentachlorophenol ND 50.0 9.90 ug/L 12/03/22 20:43 12/06/22 17:33 1 Phenanthrene ND 10.0 4.30 ug/L 12/03/22 20:43 12/06/22 17:33 1 Phenol ND 10.0 1.50 ug/L 12/03/22 20:43 12/06/22 17:33 1 Pyrene ND 10.0 3.70 ug/L 12/03/22 20:43 12/06/22 17:33 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 2, 4, 6-Tribromophenol (Surr) 93 30 - 130 12103122 20:43 12106122 17:33 1 2-Fluorobiphenyl (Surr) 81 25 - 130 12103122 20:43 12106122 17:33 1 2-Fluorophenol (Surr) 36 10 - 130 12103122 20:43 12106122 17:33 1 Nitrobenzene-d5 (Surr) 74 30 - 130 12103122 20:43 12106122 17:33 1 Phenol-d5 (Surr) 27 10 - 130 12103122 20:43 12106122 17:33 1 Terphenyl-d14 (Surr) 101 35 - 131 12103122 20:43 12106122 17:33 1 Lab Sample ID: LCS 680-753436/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 753876 Prep Batch: 753436 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,1'-Biphenyl 200 160.8 ug/L 80 26-130 2,4,5-Trichlorophenol 200 167.6 ug/L 84 26 - 130 2,4,6-Trichlorophenol 200 173.7 ug/L 87 28 - 130 2,4-Dichlorophenol 200 152.3 ug/L 76 27 - 130 2,4-Dimethyl phenol 200 143.9 ug/L 72 26 - 130 2,4-Dinitrophenol 400 449.8 ug/L 112 23 - 130 2,4-Dinitrotoluene 200 217.9 ug/L 109 37 - 130 2,6-Dinitrotoluene 200 195.1 ug/L 98 35 - 130 2-Chloronaphthalene 200 159.9 ug/L 80 25 - 130 2-Chlorophenol 200 128.4 ug/L 64 24 - 130 2-Methylnaphthalene 200 159.7 ug/L 80 22 - 130 2-Methylphenol 200 115.6 ug/L 58 21 - 130 2-Nitroaniline 200 200.0 ug/L 100 36 - 130 2-Nitrophenol 200 176.4 ug/L 88 27. 130 3 & 4 Methylphenol 200 108.9 ug/L 54 19. 130 3,3'-Dichlorobenzidine 200 276.6 *+ ug/L 138 35 - 130 3-Nitroaniline 200 177.4 ug/L 89 14 - 130 Eurofins Savannah Page 19 of 28 12/7/2022 QC Sample Results Client: ECS Southeast LLP Project/Site: Wrights Executive Sales Job ID: 680-226360-1 Method: 8270E - Semivolatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: LCS 680-753436/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 753876 Prep Batch: 753436 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 4,6-Dinitro-2-methylphenol 400 432.6 ug/L 108 38 - 130 4-Bromophenyl phenyl ether 200 163.9 ug/L 82 34 - 130 4-Chloro-3-methylphenol 200 171.1 ug/L 86 28 - 130 4-Chloroaniline 200 114.0 ug/L 57 10 - 130 4-Chlorophenyl phenyl ether 200 177.1 ug/L 89 31 - 130 4-Nitroaniline 200 197.4 ug/L 99 36 - 130 4-Nitrophenol 400 146.5 ug/L 37 10 - 130 Acenaphthene 200 179.2 ug/L 90 28 - 130 Acenaphthylene 200 174.6 ug/L 87 31 - 130 Acetophenone 200 155.9 ug/L 78 28 - 130 Anthracene 200 167.0 ug/L 83 36 - 130 Atrazine 200 191.6 ug/L 96 10 - 142 Benzaldehyde 200 159.0 ug/L 79 22 - 130 Benzo[a]anthracene 200 192.4 ug/L 96 34 - 130 Benzo[a]pyrene 200 173.6 ug/L 87 36 - 130 Benzo[b]fluoranthene 200 184.9 ug/L 92 35 - 130 Benzo[g,h,i]perylene 200 165.4 ug/L 83 35-130 Benzo[k]fluoranthene 200 161.8 ug/L 81 34 - 130 bis (2-chloroisopropyl) ether 200 158.6 ug/L 79 33 - 130 Bis(2-chloroethoxy)methane 200 156.6 ug/L 78 31 - 130 Bis(2-chloroethyl)ether 200 136.8 ug/L 68 30 - 130 Bis(2-ethylhexyl) phthalate 200 220.0 ug/L 110 33 - 138 Butyl benzyl phthalate 200 232.4 ug/L 116 35 - 135 Caprolactam 200 53.88 ug/L 27 10 - 130 Carbazole 200 174.0 ug/L 87 36 - 130 Chrysene 200 192.7 ug/L 96 33 - 130 Dibenz(a,h)anthracene 200 166.5 ug/L 83 35 - 130 Dibenzofuran 200 172.0 ug/L 86 31 - 130 Diethyl phthalate 200 187.4 ug/L 94 36 - 130 Dimethyl phthalate 200 179.0 ug/L 90 34 - 130 Di-n-butyl phthalate 200 188.7 ug/L 94 35 - 130 Di-n-octyl phthalate 200 239.8 ug/L 120 34 - 139 Fluoranthene 200 179.8 ug/L 90 35 - 130 Fluorene 200 173.3 ug/L 87 33 - 130 Hexachlorobenzene 200 165.9 ug/L 83 30 - 130 Hexachlorobutadiene 200 142.0 ug/L 71 12 - 130 Hexachlorocyclopentadiene 200 141.5 ug/L 71 15 - 130 Hexachloroethane 200 133.5 ug/L 67 12 - 130 Indeno[1,2,3-cd]pyrene 200 208.2 ug/L 104 34 - 130 Isophorone 200 165.4 ug/L 83 27 - 130 Naphthalene 200 143.8 ug/L 72 19 - 130 Nitrobenzene 200 154.0 ug/L 77 32 - 130 N-Nitrosodi-n-propylamine 200 168.7 ug/L 84 33 - 130 N-Nitrosodiphenylamine 200 162.3 ug/L 81 35 - 130 Pentachlorophenol 400 336.1 ug/L 84 24 - 130 Phenanthrene 200 164.0 ug/L 82 36 - 130 Phenol 200 70.96 ug/L 35 10 - 130 Pyrene 200 197.3 ug/L 99 33 - 130 Eurofins Savannah Page 20 of 28 12/7/2022 QC Sample Results Client: ECS Southeast LLP Job ID: 680-226360-1 Project/Site: Wrights Executive Sales Method: 8270E - Semivolatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: LCS 680-753436/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 753876 Prep Batch: 753436 LCS LCS Surrogate %Recovery Qualifier Limits 2, 4, 6-Tribromophenol (Surr) 104 30 - 130 2-Fluorobiphenyl (Surr) 78 25 - 130 2-Fluorophenol (Surr) 36 10 - 130 Nitrobenzene-d5 (Surr) 78 30 - 130 Phenol-d5 (Surr) 27 10 - 130 Terphenyl-d14 (Surr) 103 35 - 131 Lab Sample ID: LCSD 680-753436/3-A Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 753876 Prep Batch: 753436 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit 1,1'-Biphenyl 200 166.5 ug/L 83 26-130 3 50 2,4,5-Trichlorophenol 200 174.8 ug/L 87 26 - 130 4 50 2,4,6-Trichlorophenol 200 180.1 ug/L 90 28 - 130 4 50 2,4-Dichlorophenol 200 159.0 ug/L 79 27 - 130 4 50 2,4-Dimethyl phenol 200 150.0 ug/L 75 26 - 130 4 50 2,4-Dinitrophenol 400 463.3 ug/L 116 23 - 130 3 50 2,4-Dinitrotoluene 200 224.5 ug/L 112 37 - 130 3 50 2,6-Dinitrotoluene 200 203.5 ug/L 102 35 - 130 4 50 2-Chloronaphthalene 200 166.0 ug/L 83 25 - 130 4 50 2-Chlorophenol 200 134.5 ug/L 67 24 - 130 5 50 2-Methylnaphthalene 200 164.2 ug/L 82 22 - 130 3 50 2-Methylphenol 200 123.9 ug/L 62 21 - 130 7 50 2-Nitroaniline 200 211.7 ug/L 106 36 - 130 6 50 2-Nitrophenol 200 182.0 ug/L 91 27 - 130 3 50 3 & 4 Methylphenol 200 112.7 ug/L 56 19 - 130 3 50 3,3'-Dichlorobenzidine 200 329.4 *+ ug/L 165 35 - 130 17 50 3-Nitroaniline 200 185.8 ug/L 93 14 - 130 5 50 4,6-Dinitro-2-methyl phenol 400 457.6 ug/L 114 38 - 130 6 50 4-Bromophenyl phenyl ether 200 172.8 ug/L 86 34 - 130 5 50 4-Chloro-3-methylphenol 200 174.7 ug/L 87 28 - 130 2 50 4-Chloroaniline 200 126.2 ug/L 63 10 - 130 10 50 4-Chlorophenyl phenyl ether 200 184.5 ug/L 92 31 - 130 4 50 4-Nitroaniline 200 200.2 ug/L 100 36 - 130 1 50 4-Nitrophenol 400 151.1 ug/L 38 10 - 130 3 50 Acenaphthene 200 186.5 ug/L 93 28 - 130 4 50 Acenaphthylene 200 181.9 ug/L 91 31 - 130 4 50 Acetophenone 200 159.8 ug/L 80 28 - 130 2 50 Anthracene 200 175.4 ug/L 88 36 - 130 5 50 Atrazine 200 195.6 ug/L 98 10 - 142 2 50 Benzaldehyde 200 157.8 ug/L 79 22 - 130 1 50 Benzo[a]anthracene 200 201.4 ug/L 101 34 - 130 5 50 Benzo[a]pyrene 200 180.2 ug/L 90 36 - 130 4 50 Benzo[b]fluoranthene 200 187.6 ug/L 94 35 - 130 1 50 Benzo[g,h,i]perylene 200 174.4 ug/L 87 35-130 5 50 Benzo[k]fluoranthene 200 169.8 ug/L 85 34 - 130 5 50 bis (2-chloroisopropyl) ether 200 166.4 ug/L 83 33 - 130 5 50 Eurofins Savannah Page 21 of 28 12/7/2022 QC Sample Results Client: ECS Southeast LLP Project/Site: Wrights Executive Sales Job ID: 680-226360-1 Method: 8270E - Semivolatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: LCSD 680-75343613-A Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 753876 Prep Batch: 753436 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Bis(2-chloroethoxy)methane 200 161.7 ug/L 81 31 - 130 3 50 Bis(2-chloroethyl)ether 200 145.6 ug/L 73 30 _ 130 6 50 Bis(2-ethylhexyl) phthalate 200 225.1 ug/L 113 33. 138 2 50 Butyl benzyl phthalate 200 238.6 ug/L 119 35. 135 3 50 Caprolactam 200 58.02 ug/L 29 10 _ 130 7 50 Carbazole 200 179.0 ug/L 90 36 _ 130 3 50 Chrysene 200 198.7 ug/L 99 33 _ 130 3 50 Dibenz(a,h)anthracene 200 174.7 ug/L 87 35. 130 5 50 Dibenzofuran 200 177.5 ug/L 89 31 _ 130 3 50 Diethyl phthalate 200 192.6 ug/L 96 36 - 130 3 50 Dimethyl phthalate 200 185.6 ug/L 93 34 - 130 4 50 Di-n-butyl phthalate 200 195.1 ug/L 98 35 - 130 3 50 Di-n-octyl phthalate 200 248.2 ug/L 124 34. 139 3 50 Fluoranthene 200 182.9 ug/L 91 35. 130 2 50 Fluorene 200 178.4 ug/L 89 33. 130 3 50 Hexachlorobenzene 200 174.4 ug/L 87 30 _ 130 5 50 Hexachlorobutadiene 200 147.1 ug/L 74 12 _ 130 3 50 Hexachlorocyclopentadiene 200 149.6 ug/L 75 15. 130 6 50 Hexachloroethane 200 139.4 ug/L 70 12 _ 130 4 50 Indeno[1,2,3-cd]pyrene 200 217.4 ug/L 109 34 _ 130 4 50 Isophorone 200 170.9 ug/L 85 27. 130 3 50 Naphthalene 200 142.8 ug/L 71 19. 130 1 50 Nitrobenzene 200 157.0 ug/L 78 32 _ 130 2 50 N-Nitrosodi-n-propylamine 200 175.2 ug/L 88 33 _ 130 4 50 N-Nitrosodiphenylamine 200 173.5 ug/L 87 35 - 130 7 50 Pentachlorophenol 400 349.6 ug/L 87 24 - 130 4 50 Phenanthrene 200 171.0 ug/L 85 36 - 130 4 50 Phenol 200 76.40 ug/L 38 10. 130 7 50 Pyrene 200 208.6 ug/L 104 33. 130 6 50 LCSD LCSD Surrogate %Recovery Qualifier Limits 2,4,6-Tribromophenol (Surr) 105 30. 130 2-Fluorobiphenyl (Surr) 82 25. 130 2-Fluorophenol (Surr) 37 10. 130 Nitrobenzene-d5 (Surr) 80 30 - 130 Phenol-d5 (Surr) 30 10 - 130 Terphenyl-d14 (Surr) 108 35 - 131 Eurofins Savannah Page 22 of 28 12/7/2022 QC Association Summary Client: ECS Southeast LLP Project/Site: Wrights Executive Sales GC/MS VOA Leach Batch: 753113 Lab Sample ID Client Sample ID LB 680-753113/1-A Method Blank Analysis Batch: 753755 Lab Sample ID Client Sample ID 680-226360-1 WS4 LB 680-753113/1-A Method Blank MB 680-753755/9 Method Blank LCS 680-753755/5 Lab Control Sample LCSD 680-753755/6 Lab Control Sample Dup GC/MS Semi VOA Prep Batch: 753436 Lab Sample ID 680-226360-1 MB 680-753436/1-A LCS 680-753436/2-A LCSD 680-753436/3-A Analysis Batch: 753876 rLab Sample ID 680-226360-1 MB 680-753436/1-A LCS 680-753436/2-A LCSD 680-753436/3-A F Job ID: 680-226360-1 Prep Type Matrix Method Prep Batch Total/NA Water 1311 L Prep Type Matrix Total/NA Water Total/NA Water Total/NA Water Total/NA Water Total/NA Water Method 8260D 8260D 8260D 8260D 8260D Prep Batch 753113 i Client Sample ID Prep Type Matrix Method Prep Batch WS-4 Total/NA Water 3510C Method Blank Total/NA Water 3510C Lab Control Sample Total/NA Water 3510C Lab Control Sample Dup Total/NA Water 3510C E: Client Sample ID Prep Type Matrix Method Prep Batch WS4 Total/NA Water 8270E 753436 Method Blank Total/NA Water 8270E 753436 Lab Control Sample Total/NA Water 8270E 753436 Lab Control Sample Dup Total/NA Water 8270E 753436 Eurofins Savannah Page 23 of 28 12/7/2022 Lab Chronicle Client: ECS Southeast LLP Project/Site: Wrights Executive Sales F Job ID: 680-226360-1 Client Sample ID: WS-4 Lab Sample ID: 680-226360-1 Date Collected: 11/28/22 10:30 Matrix: Water Date Received: 11/29/22 07:00 Batch Batch Dil Initial Prep Type Type Method Run Factor Amount Total/NA Analysis 8260D 1 5 mL Instrument ID: CMS02 Total/NA Prep 3510C 533.5 mL Total/NA Analysis 8270E 1 1 mL Instrument ID: CMSN Laboratory References: EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL (912)354-7858 Final Batch Prepared Amount Number or Analyzed Analyst Lab 5mL 753755 12/06/2216:37 Y1S EET SAV 1 mL 753436 12/03/22 20:43 MR EET SAV 1 mL 753876 12/06/22 23:34 T1 C EET SAV Page 24 of 28 Eurofins Savannah 12/7/2022 Accreditation/Certification Summary Client: ECS Southeast LLP Project/Site: Wrights Executive Sales Laboratory: Eurofins Savannah The accreditations/certifications listed below are applicable to this report. FAuthority Progi North Carolina (WW/SW) State Identification Number Expiration Date 269 12-31-22 Job ID: 680-226360-1 Eurofins Savannah Page 25 of 28 12/7/2022 Method Summary Client: ECS Southeast LLP Project/Site: Wrights Executive Sales Job ID: 680-226360-1 Method Method Description Protocol Laboratory 8260D Volatile Organic Compounds by GC/MS SW846 EET SAV 8270E Semivolatile Organic Compounds (GC/MS) SW846 EET SAV 3510C Liquid -Liquid Extraction (Separatory Funnel) SW846 EET SAV 5030B Purge and Trap SW846 EET SAV Protocol References: SW846 ='Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. Laboratory References: EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL (912)354-7858 Eurofins Savannah Page 26 of 28 12/7/2022 rya ui E� G W rQr««) cc E T u N N � OZ 91 _) c E U o N O 4- C 07 Z O o 7 a U E O p E c E E z U a`�E m N O @ a C] o @ A a @ @ @ U cn U- J o - `— a O O O _ N y ,`o o > a L ❑ (o (o O @ T\\l\ @ T @ o � E U E U E U v � ❑ U m a m o T ❑ N a O @ U d ,F v a n Q � o io w o o u p o o O a J N c U >+ T C m m p a J7 a a rx ZS s n N / A ) OSW I SW wJO{Jad in J (N ( A) aldweg paJall!d y 0 o c a E E Q E z M— m h o O o Q Q o F V f17 N Li m N N a T� @ @ d Zo Q Z a co �� 2 "W ,_ o o T .� _ El(� J ❑ O O a I r Z u� M 0 N � U O U U O U z a = cam. a 'E .� r e{ N c N { ( J O @ co E E o z r 19 ° n O o ❑ L o6 ❑ N M o m v y } c o'�j Ili N r wn Q a E E w El c �� C w o 2 N LL V C n. a N ❑ U`n�U S ro i1'c @Y cl _ c0 c N m N @ z a i N V) N C oyEN N To T ,n @ _� 1 O7 c = G o in r L yroy N E O> c O U a) o N N C E y@ N E Z - U U_ u C O ' C C3 i C) a C) a -a cn a — aa� 27 clfi _.a _ _ a a a ci o ' rr 1 %712 22 Login Sample Receipt Checklist Client: ECS Southeast LLP Job Number: 680-226360-1 Login Number: 226360 List Number: 1 Creator: Padayao, Abigail Question List Source: Eurofins Savannah Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey N/A meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. True There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A Eurofins Savannah Page 28 of 28 12/7/2022