19001_Caroline Courtyard_SW_Stream Sediment Sample Rpt_20150513

!
May 13, 2015
Mr. James Rudder, P.G.
Project Manager
NC Department of Environment and Natural Resources
Division of Waste Management - Brownfields Program
1646 Mail Service Center
Raleigh, North Carolina 27699-1646
Subject: Caroline Courtyard Brownfields Project
Submittal of Stream and Sediment Sampling Results
North Generals Boulevard
Lincolnton, Lincoln County, North Carolina 28092
Brownfields Project No. 19001-15-55
Dear Jim:
We have enclosed herein the results of surface water and stream sediment sampling that was
performed within Walker Branch (Stream Index Number: 11-129-5-10), a perennial stream with
a designation of Water Supply IV. Surface water and sediment samples were collected from
upstream, within, and downstream of the Caroline Courtyard property in order to determine if
identified compounds that are originating from off-site sources have impacted Walker Branch.
On April 24, 2015, surface water and stream sediment samples were collected at locations that
are illustrated in the enclosed attachment in accordance with the procedures and methodologies
that were outlined in our stream and sediment sampling plan that was approved by your office.
Walker Branch borders the southern portion of the Caroline Courtyard property and flows in an
eastern to western direction. Griffith Enterprises collected stream and sediment samples within
crossover reaches of Walker Branch and during dry weather conditions (72 hours of no rainfall),
which was verified through the NC State Climate Office, Lincoln Airport location. Once the
samples were collected and preserved in accordance with 40CFR 136.3, they were shipped to
Pace Analytical Services, Inc, in Huntersville, North Carolina for laboratory analyses.
GRIFFITH ENTERPRISES, INC.
353 JONESTOWN ROAD, #312 WINSTON-SALEM, NC. 27104
TELEPHONE [phone] FAX [phone]
EMAIL [e-mail]
The surface water and stream sediment samples were analyzed by EPA Method 8260 and 8270,
for volatile and semi-volatile organic compounds, as well as RCRA metals by EPA Method 6010.
Results of the surface water and stream sediment samples are listed below.
Surface Water Sampling Results Results Units Applicable Standard
NOTES:
NCAC 2B = 15A NCAC 02B Surface Water, Water Supply Standards, Effective May 1, 2007
PSRG, Residential = Residential IHSB Preliminary Soil Remediation Goals, September 2014
N/A = A surface water standard does not exist for pollutant parameter
GRIFFITH ENTERPRISES, INC.
353 JONESTOWN ROAD, #312 WINSTON-SALEM, NC. 27104
TELEPHONE [phone] FAX [phone]
EMAIL [e-mail]
#1 - Upstream of Caroline Courtyard Courtyard
Barium 18.6 ug/L 1.0 - NCAC 2B
cis-1,2-Dichloroethene 1.8 ug/L N/A NCAC 2B
Tetrachloroethene 3.3 ug/L 0.7 NCAC 2B
#2 - Within Caroline Courtyard
Barium 19.1 ug/L 1.0 NCAC 2B
cis-1,2-Dichloroethene 6.7 ug/L N/A NCAC 2B
Tetrachloroethene 15.8 ug/L 0.7 NCAC 2B
Trichloroethene 1.7 ug/L 2.5 NCAC 2B
#3 Downstream of Caroline Courtyard
Barium 19.0 ug/L 1.0 NCAC 2B
cis-1,2-Dichloroethene 6.0 ug/L N/A NCAC 2B
Tetrachloroethene 16.5 ug/L 0.7 NCAC 2B
Trichloroethene 1.5 ug/L 2.5 NCAC 2B
NOTES:
NCAC 2B = 15A NCAC 02B Surface Water, Water Supply Standards, Effective May 1, 2007
PSRG, Residential = Residential IHSB Preliminary Soil Remediation Goals, September 2014
* = Units converted to mg/kg, since standard is expressed as mg/kg
GRIFFITH ENTERPRISES, INC.
353 JONESTOWN ROAD, #312 WINSTON-SALEM, NC. 27104
TELEPHONE [phone] FAX [phone]
EMAIL [e-mail]
Stream Sediment Sampling Results Results Units Applicable Standard
#1 Upstream of Caroline Courtyard
Barium 39.0 mg/kg 3,000.0 PSRG, Residential
Chromium 1.5 mg/kg 24,000 - PSRG, Residential
Lead 14.2 mg/kg 400.0 PSRG, Residential
Tetrachloroethene 0.0058 mg/kg 16.0 PSRG, Residential
#2 Within Caroline Courtyard
Arsenic 1.4 mg/kg 0.67 PSRG, Residential
Barium 19.4 mg/kg 3,000.0 PSRG, Residential
Cadmium 0.10 mg/kg 14.0 PSRG, Residential
Chromium 4.3 mg/kg 24,000 - PSRG, Residential
Lead 4.6 mg/kg 400.0 PSRG, Residential
Tetrachloroethene 0.0383 mg/kg 16.0 PSRG, Residential
#3 Downstream of Caroline Courtyard
Arsenic 1.3 mg/kg 0.67 PSRG, Residential
Barium 5.1 mg/kg 3,000.0 PSRG, Residential
Chromium 1.0 mg/kg 24,000 - PSRG, Residential
Lead 1.2 mg/kg 400.0 PSRG, Residential
Tetrachloroethene 0.0069 mg/kg 16.0 PSRG, Residential
The results of surface water sampling that are outlined above indicate that barium and
tetrachloroethene were detected above their respective NCAC 2B surface water standards at all
three sampled locations within Walker Branch. The results of stream sediment sampling also
reported the presence of RCRA Metals and tetrachloroethene within the sediments of Walker
Branch at all three sampled locations.
Based on the surface water and stream sediment sampling that is contained herein, it appears that
identified compounds that are originating from off-site sources have impacted Walker Branch at
all three sampling points that were located above, within and below the Caroline Courtyard
property.
If you have any questions, or need any additional information please feel free to contact me
immediately at [phone].
Sincerely,
M. Alan Griffith
M. Alan Griffith, L.G.
Licensed Geologist
Cc: Mr. Bill Scantland, Managing Member, The BTR Communities Group, LLC.
GRIFFITH ENTERPRISES, INC.
353 JONESTOWN ROAD, #312 WINSTON-SALEM, NC. 27104
TELEPHONE [phone] FAX [phone]
EMAIL [e-mail]
Lincoln County and its mapping contractors assume no legal responsibility for the information contained on this map. This map is not to be used for
land conveyance. The map is based on NC State Plane Coordinate System 1983 NAD. Lincoln County, NC Office of the Tax Administrator, GIS Division
Upstream
Sampling
Location #1
Within Project Area -
Sampling Location #2
Downstream
Sampling
Location #3
Walker Branch
Property of Caroline Courtyard
Scale 1 inch = 1 eet
Figure 1: Approximate Sampling Locations at Caroline Courtyard
#=CL#
May 11, 2015
LIMS USE: FR - ALAN GRIFFITH
LIMS OBJECT ID: 92247219
92247219
Project:
Pace Project No.:
RE:
Mr. Alan Griffith
Griffith Enterprises, Inc.
353 Jonestown Rd.
#312
Winston Salem, NC 27104
CAROLINE COURTYARD
Dear Mr. Griffith:
Enclosed are the analytical results for sample(s) received by the laboratory on April 27, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 71
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 71
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92247219001 CC1-UPSTREAM FROM PROJECT EPA 6010 7 PASI-AJMW
EPA 7470 1 PASI-AHVK
EPA 8270 74 PASI-CBPJ
EPA 8260 63 PASI-CDLK
92247219002 CC2- PROJECT AREA EPA 6010 7 PASI-AJMW
EPA 7470 1 PASI-AHVK
EPA 8270 74 PASI-CBPJ
EPA 8260 63 PASI-CDLK
92247219003 CC3-DOWNSTREAM OF PROJECT EPA 6010 7 PASI-AJMW
EPA 7470 1 PASI-AHVK
EPA 8270 74 PASI-CBPJ
EPA 8260 63 PASI-CDLK
92247219004 CC1-UPSTREAM FROM PROJECT EPA 6010 7 PASI-AJMW
EPA 7471 1 PASI-AHVK
EPA 8270 74 PASI-CRES
EPA 8260 70 PASI-CDLK
ASTM D2974-87 1 PASI-CEJK
92247219005 CC2-PROJECT AREA EPA 6010 7 PASI-AJMW
EPA 7471 1 PASI-AHVK
EPA 8270 74 PASI-CRES
EPA 8260 70 PASI-CDLK
ASTM D2974-87 1 PASI-CEJK
92247219006 CC3-DOWNSTREAM OF PROJECT
AREA EPA 6010 7 PASI-AJMW
EPA 7471 1 PASI-AHVK
EPA 8270 74 PASI-CRES
EPA 8260 70 PASI-CDLK
ASTM D2974-87 1 PASI-CEJK
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 71
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92247219001 CC1-UPSTREAM FROM
PROJECT
Barium 18.6 ug/L 04/30/15 17:325.0EPA 6010
cis-1,2-Dichloroethene 1.8 ug/L 05/01/15 23:571.0EPA 8260
Tetrachloroethene 3.3 ug/L 05/01/15 23:571.0EPA 8260
92247219002 CC2- PROJECT AREA
Barium 19.1 ug/L 04/30/15 17:355.0EPA 6010
cis-1,2-Dichloroethene 6.7 ug/L 05/02/15 00:161.0EPA 8260
Tetrachloroethene 15.8 ug/L 05/02/15 00:161.0EPA 8260
Trichloroethene 1.7 ug/L 05/02/15 00:161.0EPA 8260
92247219003 CC3-DOWNSTREAM OF
PROJECT
Barium 19.0 ug/L 04/30/15 17:395.0EPA 6010
cis-1,2-Dichloroethene 6.0 ug/L 05/02/15 00:341.0EPA 8260
Tetrachloroethene 16.5 ug/L 05/02/15 00:341.0EPA 8260
Trichloroethene 1.5 ug/L 05/02/15 00:341.0EPA 8260
92247219004 CC1-UPSTREAM FROM
PROJECT
Barium 39.0 mg/kg 05/01/15 01:490.41EPA 6010
Chromium 1.5 mg/kg 05/01/15 01:490.41EPA 6010
Lead 14.2 mg/kg 05/01/15 01:490.41EPA 6010
Tetrachloroethene 5.8 ug/kg 04/29/15 23:515.0EPA 8260
Percent Moisture 22.1 %04/29/15 13:090.10ASTM D2974-87
92247219005 CC2-PROJECT AREA
Arsenic 1.4 mg/kg 05/01/15 02:010.91EPA 6010
Barium 19.4 mg/kg 05/01/15 02:010.45EPA 6010
Cadmium 0.10 mg/kg 05/01/15 02:010.091EPA 6010
Chromium 4.3 mg/kg 05/01/15 02:010.45EPA 6010
Lead 4.6 mg/kg 05/01/15 02:010.45EPA 6010
Tetrachloroethene 38.3 ug/kg 04/30/15 00:115.7EPA 8260
Percent Moisture 26.6 %04/29/15 13:100.10ASTM D2974-87
92247219006 CC3-DOWNSTREAM OF
PROJECT AREA
Arsenic 1.3 mg/kg 05/01/15 02:040.69EPA 6010
Barium 5.1 mg/kg 05/01/15 02:040.35EPA 6010
Chromium 1.0 mg/kg 05/01/15 02:040.35EPA 6010
Lead 1.2 mg/kg 05/01/15 02:040.35EPA 6010
Tetrachloroethene 6.9 ug/kg 04/30/15 00:31 M15.5EPA 8260
Percent Moisture 25.0 %04/29/15 13:100.10ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC1-UPSTREAM FROM
PROJECT
Lab ID:92247219001 Collected:04/24/15 12:36 Received:04/27/15 15:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Arsenic ND ug/L 04/30/15 17:32 7440-38-204/29/15 15:3010.0 1
Barium 18.6 ug/L 04/30/15 17:32 7440-39-304/29/15 15:305.0 1
Cadmium ND ug/L 04/30/15 17:32 7440-43-904/29/15 15:301.0 1
Chromium ND ug/L 04/30/15 17:32 7440-47-304/29/15 15:305.0 1
Lead ND ug/L 04/30/15 17:32 7439-92-104/29/15 15:305.0 1
Selenium ND ug/L 04/30/15 17:32 7782-49-204/29/15 15:3010.0 1
Silver ND ug/L 04/30/15 17:32 7440-22-404/29/15 15:305.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 05/01/15 12:28 7439-97-604/30/15 12:200.20 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 05/04/15 16:08 83-32-905/01/15 14:1510.0 1
Acenaphthylene ND ug/L 05/04/15 16:08 208-96-805/01/15 14:1510.0 1
Aniline ND ug/L 05/04/15 16:08 62-53-305/01/15 14:1510.0 1
Anthracene ND ug/L 05/04/15 16:08 120-12-705/01/15 14:1510.0 1
Benzo(a)anthracene ND ug/L 05/04/15 16:08 56-55-305/01/15 14:1510.0 1
Benzo(a)pyrene ND ug/L 05/04/15 16:08 50-32-805/01/15 14:1510.0 1
Benzo(b)fluoranthene ND ug/L 05/04/15 16:08 205-99-205/01/15 14:1510.0 1
Benzo(g,h,i)perylene ND ug/L 05/04/15 16:08 191-24-205/01/15 14:1510.0 1
Benzo(k)fluoranthene ND ug/L 05/04/15 16:08 207-08-905/01/15 14:1510.0 1
Benzoic Acid ND ug/L 05/04/15 16:08 65-85-005/01/15 14:1550.0 1
Benzyl alcohol ND ug/L 05/04/15 16:08 100-51-605/01/15 14:1520.0 1
4-Bromophenylphenyl ether ND ug/L 05/04/15 16:08 101-55-305/01/15 14:1510.0 1
Butylbenzylphthalate ND ug/L 05/04/15 16:08 85-68-705/01/15 14:1510.0 1
4-Chloro-3-methylphenol ND ug/L 05/04/15 16:08 59-50-705/01/15 14:1520.0 1
4-Chloroaniline ND ug/L 05/04/15 16:08 106-47-805/01/15 14:1520.0 1
bis(2-Chloroethoxy)methane ND ug/L 05/04/15 16:08 111-91-105/01/15 14:1510.0 1
bis(2-Chloroethyl) ether ND ug/L 05/04/15 16:08 111-44-405/01/15 14:1510.0 1
bis(2-Chloroisopropyl) ether ND ug/L 05/04/15 16:08 108-60-105/01/15 14:1510.0 1
2-Chloronaphthalene ND ug/L 05/04/15 16:08 91-58-705/01/15 14:1510.0 1
2-Chlorophenol ND ug/L 05/04/15 16:08 95-57-805/01/15 14:1510.0 1
4-Chlorophenylphenyl ether ND ug/L 05/04/15 16:08 7005-72-305/01/15 14:1510.0 1
Chrysene ND ug/L 05/04/15 16:08 218-01-905/01/15 14:1510.0 1
Dibenz(a,h)anthracene ND ug/L 05/04/15 16:08 53-70-305/01/15 14:1510.0 1
Dibenzofuran ND ug/L 05/04/15 16:08 132-64-905/01/15 14:1510.0 1
1,2-Dichlorobenzene ND ug/L 05/04/15 16:08 95-50-105/01/15 14:1510.0 1
1,3-Dichlorobenzene ND ug/L 05/04/15 16:08 541-73-105/01/15 14:1510.0 1
1,4-Dichlorobenzene ND ug/L 05/04/15 16:08 106-46-705/01/15 14:1510.0 1
3,3'-Dichlorobenzidine ND ug/L 05/04/15 16:08 91-94-105/01/15 14:1520.0 1
2,4-Dichlorophenol ND ug/L 05/04/15 16:08 120-83-205/01/15 14:1510.0 1
Diethylphthalate ND ug/L 05/04/15 16:08 84-66-205/01/15 14:1510.0 1
2,4-Dimethylphenol ND ug/L 05/04/15 16:08 105-67-905/01/15 14:1510.0 1
Dimethylphthalate ND ug/L 05/04/15 16:08 131-11-305/01/15 14:1510.0 1
Di-n-butylphthalate ND ug/L 05/04/15 16:08 84-74-205/01/15 14:1510.0 1
4,6-Dinitro-2-methylphenol ND ug/L 05/04/15 16:08 534-52-1 L305/01/15 14:1520.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC1-UPSTREAM FROM
PROJECT
Lab ID:92247219001 Collected:04/24/15 12:36 Received:04/27/15 15:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
2,4-Dinitrophenol ND ug/L 05/04/15 16:08 51-28-5 L305/01/15 14:1550.0 1
2,4-Dinitrotoluene ND ug/L 05/04/15 16:08 121-14-205/01/15 14:1510.0 1
2,6-Dinitrotoluene ND ug/L 05/04/15 16:08 606-20-205/01/15 14:1510.0 1
Di-n-octylphthalate ND ug/L 05/04/15 16:08 117-84-005/01/15 14:1510.0 1
bis(2-Ethylhexyl)phthalate ND ug/L 05/04/15 16:08 117-81-705/01/15 14:156.0 1
Fluoranthene ND ug/L 05/04/15 16:08 206-44-005/01/15 14:1510.0 1
Fluorene ND ug/L 05/04/15 16:08 86-73-705/01/15 14:1510.0 1
Hexachloro-1,3-butadiene ND ug/L 05/04/15 16:08 87-68-305/01/15 14:1510.0 1
Hexachlorobenzene ND ug/L 05/04/15 16:08 118-74-105/01/15 14:1510.0 1
Hexachlorocyclopentadiene ND ug/L 05/04/15 16:08 77-47-405/01/15 14:1510.0 1
Hexachloroethane ND ug/L 05/04/15 16:08 67-72-105/01/15 14:1510.0 1
Indeno(1,2,3-cd)pyrene ND ug/L 05/04/15 16:08 193-39-505/01/15 14:1510.0 1
Isophorone ND ug/L 05/04/15 16:08 78-59-105/01/15 14:1510.0 1
1-Methylnaphthalene ND ug/L 05/04/15 16:08 90-12-005/01/15 14:1510.0 1
2-Methylnaphthalene ND ug/L 05/04/15 16:08 91-57-605/01/15 14:1510.0 1
2-Methylphenol(o-Cresol)ND ug/L 05/04/15 16:08 95-48-705/01/15 14:1510.0 1
3&4-Methylphenol(m&p Cresol)ND ug/L 05/04/15 16:0805/01/15 14:1510.0 1
Naphthalene ND ug/L 05/04/15 16:08 91-20-305/01/15 14:1510.0 1
2-Nitroaniline ND ug/L 05/04/15 16:08 88-74-405/01/15 14:1550.0 1
3-Nitroaniline ND ug/L 05/04/15 16:08 99-09-205/01/15 14:1550.0 1
4-Nitroaniline ND ug/L 05/04/15 16:08 100-01-605/01/15 14:1520.0 1
Nitrobenzene ND ug/L 05/04/15 16:08 98-95-305/01/15 14:1510.0 1
2-Nitrophenol ND ug/L 05/04/15 16:08 88-75-505/01/15 14:1510.0 1
4-Nitrophenol ND ug/L 05/04/15 16:08 100-02-705/01/15 14:1550.0 1
N-Nitrosodimethylamine ND ug/L 05/04/15 16:08 62-75-905/01/15 14:1510.0 1
N-Nitroso-di-n-propylamine ND ug/L 05/04/15 16:08 621-64-705/01/15 14:1510.0 1
N-Nitrosodiphenylamine ND ug/L 05/04/15 16:08 86-30-605/01/15 14:1510.0 1
Pentachlorophenol ND ug/L 05/04/15 16:08 87-86-5 L305/01/15 14:1525.0 1
Phenanthrene ND ug/L 05/04/15 16:08 85-01-805/01/15 14:1510.0 1
Phenol ND ug/L 05/04/15 16:08 108-95-205/01/15 14:1510.0 1
Pyrene ND ug/L 05/04/15 16:08 129-00-005/01/15 14:1510.0 1
1,2,4-Trichlorobenzene ND ug/L 05/04/15 16:08 120-82-105/01/15 14:1510.0 1
2,4,5-Trichlorophenol ND ug/L 05/04/15 16:08 95-95-405/01/15 14:1510.0 1
2,4,6-Trichlorophenol ND ug/L 05/04/15 16:08 88-06-205/01/15 14:1510.0 1
Surrogates
Nitrobenzene-d5 (S)46 %05/04/15 16:08 4165-60-005/01/15 14:1521-110 1
2-Fluorobiphenyl (S)40 %05/04/15 16:08 321-60-805/01/15 14:1527-110 1
Terphenyl-d14 (S)91 %05/04/15 16:08 1718-51-005/01/15 14:1531-107 1
Phenol-d6 (S)16 %05/04/15 16:08 13127-88-305/01/15 14:1510-110 1
2-Fluorophenol (S)26 %05/04/15 16:08 367-12-405/01/15 14:1512-110 1
2,4,6-Tribromophenol (S)88 %05/04/15 16:08 118-79-605/01/15 14:1527-110 1
Analytical Method: EPA 82608260 MSV Low Level
Acetone ND ug/L 05/01/15 23:57 67-64-125.0 1
Benzene ND ug/L 05/01/15 23:57 71-43-21.0 1
Bromobenzene ND ug/L 05/01/15 23:57 108-86-11.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC1-UPSTREAM FROM
PROJECT
Lab ID:92247219001 Collected:04/24/15 12:36 Received:04/27/15 15:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
Bromochloromethane ND ug/L 05/01/15 23:57 74-97-51.0 1
Bromodichloromethane ND ug/L 05/01/15 23:57 75-27-41.0 1
Bromoform ND ug/L 05/01/15 23:57 75-25-21.0 1
Bromomethane ND ug/L 05/01/15 23:57 74-83-92.0 1
2-Butanone (MEK)ND ug/L 05/01/15 23:57 78-93-35.0 1
Carbon tetrachloride ND ug/L 05/01/15 23:57 56-23-51.0 1
Chlorobenzene ND ug/L 05/01/15 23:57 108-90-71.0 1
Chloroethane ND ug/L 05/01/15 23:57 75-00-31.0 1
Chloroform ND ug/L 05/01/15 23:57 67-66-31.0 1
Chloromethane ND ug/L 05/01/15 23:57 74-87-31.0 1
2-Chlorotoluene ND ug/L 05/01/15 23:57 95-49-81.0 1
4-Chlorotoluene ND ug/L 05/01/15 23:57 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 05/01/15 23:57 96-12-82.0 1
Dibromochloromethane ND ug/L 05/01/15 23:57 124-48-11.0 1
1,2-Dibromoethane (EDB)ND ug/L 05/01/15 23:57 106-93-41.0 1
Dibromomethane ND ug/L 05/01/15 23:57 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 05/01/15 23:57 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 05/01/15 23:57 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 05/01/15 23:57 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 05/01/15 23:57 75-71-81.0 1
1,1-Dichloroethane ND ug/L 05/01/15 23:57 75-34-31.0 1
1,2-Dichloroethane ND ug/L 05/01/15 23:57 107-06-21.0 1
1,1-Dichloroethene ND ug/L 05/01/15 23:57 75-35-41.0 1
cis-1,2-Dichloroethene 1.8 ug/L 05/01/15 23:57 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 05/01/15 23:57 156-60-51.0 1
1,2-Dichloropropane ND ug/L 05/01/15 23:57 78-87-51.0 1
1,3-Dichloropropane ND ug/L 05/01/15 23:57 142-28-91.0 1
2,2-Dichloropropane ND ug/L 05/01/15 23:57 594-20-71.0 1
1,1-Dichloropropene ND ug/L 05/01/15 23:57 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 05/01/15 23:57 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 05/01/15 23:57 10061-02-61.0 1
Diisopropyl ether ND ug/L 05/01/15 23:57 108-20-31.0 1
Ethylbenzene ND ug/L 05/01/15 23:57 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 05/01/15 23:57 87-68-31.0 1
2-Hexanone ND ug/L 05/01/15 23:57 591-78-65.0 1
p-Isopropyltoluene ND ug/L 05/01/15 23:57 99-87-61.0 1
Methylene Chloride ND ug/L 05/01/15 23:57 75-09-22.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 05/01/15 23:57 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 05/01/15 23:57 1634-04-41.0 1
Naphthalene ND ug/L 05/01/15 23:57 91-20-31.0 1
Styrene ND ug/L 05/01/15 23:57 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 05/01/15 23:57 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 05/01/15 23:57 79-34-51.0 1
Tetrachloroethene 3.3 ug/L 05/01/15 23:57 127-18-41.0 1
Toluene ND ug/L 05/01/15 23:57 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 05/01/15 23:57 87-61-61.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC1-UPSTREAM FROM
PROJECT
Lab ID:92247219001 Collected:04/24/15 12:36 Received:04/27/15 15:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
1,2,4-Trichlorobenzene ND ug/L 05/01/15 23:57 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 05/01/15 23:57 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 05/01/15 23:57 79-00-51.0 1
Trichloroethene ND ug/L 05/01/15 23:57 79-01-61.0 1
Trichlorofluoromethane ND ug/L 05/01/15 23:57 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 05/01/15 23:57 96-18-41.0 1
Vinyl acetate ND ug/L 05/01/15 23:57 108-05-42.0 1
Vinyl chloride ND ug/L 05/01/15 23:57 75-01-41.0 1
Xylene (Total)ND ug/L 05/01/15 23:57 1330-20-72.0 1
m&p-Xylene ND ug/L 05/01/15 23:57 179601-23-12.0 1
o-Xylene ND ug/L 05/01/15 23:57 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)96 %05/01/15 23:57 460-00-470-130 1
1,2-Dichloroethane-d4 (S)113 %05/01/15 23:57 17060-07-070-130 1
Toluene-d8 (S)102 %05/01/15 23:57 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC2- PROJECT AREA Lab ID:92247219002 Collected:04/24/15 12:05 Received:04/27/15 15:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Arsenic ND ug/L 04/30/15 17:35 7440-38-204/29/15 15:3010.0 1
Barium 19.1 ug/L 04/30/15 17:35 7440-39-304/29/15 15:305.0 1
Cadmium ND ug/L 04/30/15 17:35 7440-43-904/29/15 15:301.0 1
Chromium ND ug/L 04/30/15 17:35 7440-47-304/29/15 15:305.0 1
Lead ND ug/L 04/30/15 17:35 7439-92-104/29/15 15:305.0 1
Selenium ND ug/L 04/30/15 17:35 7782-49-204/29/15 15:3010.0 1
Silver ND ug/L 04/30/15 17:35 7440-22-404/29/15 15:305.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 05/01/15 12:35 7439-97-604/30/15 12:200.20 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 05/04/15 16:36 83-32-905/01/15 14:1510.0 1
Acenaphthylene ND ug/L 05/04/15 16:36 208-96-805/01/15 14:1510.0 1
Aniline ND ug/L 05/04/15 16:36 62-53-305/01/15 14:1510.0 1
Anthracene ND ug/L 05/04/15 16:36 120-12-705/01/15 14:1510.0 1
Benzo(a)anthracene ND ug/L 05/04/15 16:36 56-55-305/01/15 14:1510.0 1
Benzo(a)pyrene ND ug/L 05/04/15 16:36 50-32-805/01/15 14:1510.0 1
Benzo(b)fluoranthene ND ug/L 05/04/15 16:36 205-99-205/01/15 14:1510.0 1
Benzo(g,h,i)perylene ND ug/L 05/04/15 16:36 191-24-205/01/15 14:1510.0 1
Benzo(k)fluoranthene ND ug/L 05/04/15 16:36 207-08-905/01/15 14:1510.0 1
Benzoic Acid ND ug/L 05/04/15 16:36 65-85-005/01/15 14:1550.0 1
Benzyl alcohol ND ug/L 05/04/15 16:36 100-51-605/01/15 14:1520.0 1
4-Bromophenylphenyl ether ND ug/L 05/04/15 16:36 101-55-305/01/15 14:1510.0 1
Butylbenzylphthalate ND ug/L 05/04/15 16:36 85-68-705/01/15 14:1510.0 1
4-Chloro-3-methylphenol ND ug/L 05/04/15 16:36 59-50-705/01/15 14:1520.0 1
4-Chloroaniline ND ug/L 05/04/15 16:36 106-47-805/01/15 14:1520.0 1
bis(2-Chloroethoxy)methane ND ug/L 05/04/15 16:36 111-91-105/01/15 14:1510.0 1
bis(2-Chloroethyl) ether ND ug/L 05/04/15 16:36 111-44-405/01/15 14:1510.0 1
bis(2-Chloroisopropyl) ether ND ug/L 05/04/15 16:36 108-60-105/01/15 14:1510.0 1
2-Chloronaphthalene ND ug/L 05/04/15 16:36 91-58-705/01/15 14:1510.0 1
2-Chlorophenol ND ug/L 05/04/15 16:36 95-57-805/01/15 14:1510.0 1
4-Chlorophenylphenyl ether ND ug/L 05/04/15 16:36 7005-72-305/01/15 14:1510.0 1
Chrysene ND ug/L 05/04/15 16:36 218-01-905/01/15 14:1510.0 1
Dibenz(a,h)anthracene ND ug/L 05/04/15 16:36 53-70-305/01/15 14:1510.0 1
Dibenzofuran ND ug/L 05/04/15 16:36 132-64-905/01/15 14:1510.0 1
1,2-Dichlorobenzene ND ug/L 05/04/15 16:36 95-50-105/01/15 14:1510.0 1
1,3-Dichlorobenzene ND ug/L 05/04/15 16:36 541-73-105/01/15 14:1510.0 1
1,4-Dichlorobenzene ND ug/L 05/04/15 16:36 106-46-705/01/15 14:1510.0 1
3,3'-Dichlorobenzidine ND ug/L 05/04/15 16:36 91-94-105/01/15 14:1520.0 1
2,4-Dichlorophenol ND ug/L 05/04/15 16:36 120-83-205/01/15 14:1510.0 1
Diethylphthalate ND ug/L 05/04/15 16:36 84-66-205/01/15 14:1510.0 1
2,4-Dimethylphenol ND ug/L 05/04/15 16:36 105-67-905/01/15 14:1510.0 1
Dimethylphthalate ND ug/L 05/04/15 16:36 131-11-305/01/15 14:1510.0 1
Di-n-butylphthalate ND ug/L 05/04/15 16:36 84-74-205/01/15 14:1510.0 1
4,6-Dinitro-2-methylphenol ND ug/L 05/04/15 16:36 534-52-1 L305/01/15 14:1520.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC2- PROJECT AREA Lab ID:92247219002 Collected:04/24/15 12:05 Received:04/27/15 15:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
2,4-Dinitrophenol ND ug/L 05/04/15 16:36 51-28-5 L305/01/15 14:1550.0 1
2,4-Dinitrotoluene ND ug/L 05/04/15 16:36 121-14-205/01/15 14:1510.0 1
2,6-Dinitrotoluene ND ug/L 05/04/15 16:36 606-20-205/01/15 14:1510.0 1
Di-n-octylphthalate ND ug/L 05/04/15 16:36 117-84-005/01/15 14:1510.0 1
bis(2-Ethylhexyl)phthalate ND ug/L 05/04/15 16:36 117-81-705/01/15 14:156.0 1
Fluoranthene ND ug/L 05/04/15 16:36 206-44-005/01/15 14:1510.0 1
Fluorene ND ug/L 05/04/15 16:36 86-73-705/01/15 14:1510.0 1
Hexachloro-1,3-butadiene ND ug/L 05/04/15 16:36 87-68-305/01/15 14:1510.0 1
Hexachlorobenzene ND ug/L 05/04/15 16:36 118-74-105/01/15 14:1510.0 1
Hexachlorocyclopentadiene ND ug/L 05/04/15 16:36 77-47-405/01/15 14:1510.0 1
Hexachloroethane ND ug/L 05/04/15 16:36 67-72-105/01/15 14:1510.0 1
Indeno(1,2,3-cd)pyrene ND ug/L 05/04/15 16:36 193-39-505/01/15 14:1510.0 1
Isophorone ND ug/L 05/04/15 16:36 78-59-105/01/15 14:1510.0 1
1-Methylnaphthalene ND ug/L 05/04/15 16:36 90-12-005/01/15 14:1510.0 1
2-Methylnaphthalene ND ug/L 05/04/15 16:36 91-57-605/01/15 14:1510.0 1
2-Methylphenol(o-Cresol)ND ug/L 05/04/15 16:36 95-48-705/01/15 14:1510.0 1
3&4-Methylphenol(m&p Cresol)ND ug/L 05/04/15 16:3605/01/15 14:1510.0 1
Naphthalene ND ug/L 05/04/15 16:36 91-20-305/01/15 14:1510.0 1
2-Nitroaniline ND ug/L 05/04/15 16:36 88-74-405/01/15 14:1550.0 1
3-Nitroaniline ND ug/L 05/04/15 16:36 99-09-205/01/15 14:1550.0 1
4-Nitroaniline ND ug/L 05/04/15 16:36 100-01-605/01/15 14:1520.0 1
Nitrobenzene ND ug/L 05/04/15 16:36 98-95-305/01/15 14:1510.0 1
2-Nitrophenol ND ug/L 05/04/15 16:36 88-75-505/01/15 14:1510.0 1
4-Nitrophenol ND ug/L 05/04/15 16:36 100-02-705/01/15 14:1550.0 1
N-Nitrosodimethylamine ND ug/L 05/04/15 16:36 62-75-905/01/15 14:1510.0 1
N-Nitroso-di-n-propylamine ND ug/L 05/04/15 16:36 621-64-705/01/15 14:1510.0 1
N-Nitrosodiphenylamine ND ug/L 05/04/15 16:36 86-30-605/01/15 14:1510.0 1
Pentachlorophenol ND ug/L 05/04/15 16:36 87-86-5 L305/01/15 14:1525.0 1
Phenanthrene ND ug/L 05/04/15 16:36 85-01-805/01/15 14:1510.0 1
Phenol ND ug/L 05/04/15 16:36 108-95-205/01/15 14:1510.0 1
Pyrene ND ug/L 05/04/15 16:36 129-00-005/01/15 14:1510.0 1
1,2,4-Trichlorobenzene ND ug/L 05/04/15 16:36 120-82-105/01/15 14:1510.0 1
2,4,5-Trichlorophenol ND ug/L 05/04/15 16:36 95-95-405/01/15 14:1510.0 1
2,4,6-Trichlorophenol ND ug/L 05/04/15 16:36 88-06-205/01/15 14:1510.0 1
Surrogates
Nitrobenzene-d5 (S)46 %05/04/15 16:36 4165-60-005/01/15 14:1521-110 1
2-Fluorobiphenyl (S)39 %05/04/15 16:36 321-60-805/01/15 14:1527-110 1
Terphenyl-d14 (S)79 %05/04/15 16:36 1718-51-005/01/15 14:1531-107 1
Phenol-d6 (S)16 %05/04/15 16:36 13127-88-305/01/15 14:1510-110 1
2-Fluorophenol (S)25 %05/04/15 16:36 367-12-405/01/15 14:1512-110 1
2,4,6-Tribromophenol (S)84 %05/04/15 16:36 118-79-605/01/15 14:1527-110 1
Analytical Method: EPA 82608260 MSV Low Level
Acetone ND ug/L 05/02/15 00:16 67-64-125.0 1
Benzene ND ug/L 05/02/15 00:16 71-43-21.0 1
Bromobenzene ND ug/L 05/02/15 00:16 108-86-11.0 1
Bromochloromethane ND ug/L 05/02/15 00:16 74-97-51.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC2- PROJECT AREA Lab ID:92247219002 Collected:04/24/15 12:05 Received:04/27/15 15:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
Bromodichloromethane ND ug/L 05/02/15 00:16 75-27-41.0 1
Bromoform ND ug/L 05/02/15 00:16 75-25-21.0 1
Bromomethane ND ug/L 05/02/15 00:16 74-83-92.0 1
2-Butanone (MEK)ND ug/L 05/02/15 00:16 78-93-35.0 1
Carbon tetrachloride ND ug/L 05/02/15 00:16 56-23-51.0 1
Chlorobenzene ND ug/L 05/02/15 00:16 108-90-71.0 1
Chloroethane ND ug/L 05/02/15 00:16 75-00-31.0 1
Chloroform ND ug/L 05/02/15 00:16 67-66-31.0 1
Chloromethane ND ug/L 05/02/15 00:16 74-87-31.0 1
2-Chlorotoluene ND ug/L 05/02/15 00:16 95-49-81.0 1
4-Chlorotoluene ND ug/L 05/02/15 00:16 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 05/02/15 00:16 96-12-82.0 1
Dibromochloromethane ND ug/L 05/02/15 00:16 124-48-11.0 1
1,2-Dibromoethane (EDB)ND ug/L 05/02/15 00:16 106-93-41.0 1
Dibromomethane ND ug/L 05/02/15 00:16 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 05/02/15 00:16 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 05/02/15 00:16 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 05/02/15 00:16 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 05/02/15 00:16 75-71-81.0 1
1,1-Dichloroethane ND ug/L 05/02/15 00:16 75-34-31.0 1
1,2-Dichloroethane ND ug/L 05/02/15 00:16 107-06-21.0 1
1,1-Dichloroethene ND ug/L 05/02/15 00:16 75-35-41.0 1
cis-1,2-Dichloroethene 6.7 ug/L 05/02/15 00:16 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 05/02/15 00:16 156-60-51.0 1
1,2-Dichloropropane ND ug/L 05/02/15 00:16 78-87-51.0 1
1,3-Dichloropropane ND ug/L 05/02/15 00:16 142-28-91.0 1
2,2-Dichloropropane ND ug/L 05/02/15 00:16 594-20-71.0 1
1,1-Dichloropropene ND ug/L 05/02/15 00:16 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 05/02/15 00:16 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 05/02/15 00:16 10061-02-61.0 1
Diisopropyl ether ND ug/L 05/02/15 00:16 108-20-31.0 1
Ethylbenzene ND ug/L 05/02/15 00:16 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 05/02/15 00:16 87-68-31.0 1
2-Hexanone ND ug/L 05/02/15 00:16 591-78-65.0 1
p-Isopropyltoluene ND ug/L 05/02/15 00:16 99-87-61.0 1
Methylene Chloride ND ug/L 05/02/15 00:16 75-09-22.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 05/02/15 00:16 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 05/02/15 00:16 1634-04-41.0 1
Naphthalene ND ug/L 05/02/15 00:16 91-20-31.0 1
Styrene ND ug/L 05/02/15 00:16 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 05/02/15 00:16 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 05/02/15 00:16 79-34-51.0 1
Tetrachloroethene 15.8 ug/L 05/02/15 00:16 127-18-41.0 1
Toluene ND ug/L 05/02/15 00:16 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 05/02/15 00:16 87-61-61.0 1
1,2,4-Trichlorobenzene ND ug/L 05/02/15 00:16 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 05/02/15 00:16 71-55-61.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC2- PROJECT AREA Lab ID:92247219002 Collected:04/24/15 12:05 Received:04/27/15 15:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
1,1,2-Trichloroethane ND ug/L 05/02/15 00:16 79-00-51.0 1
Trichloroethene 1.7 ug/L 05/02/15 00:16 79-01-61.0 1
Trichlorofluoromethane ND ug/L 05/02/15 00:16 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 05/02/15 00:16 96-18-41.0 1
Vinyl acetate ND ug/L 05/02/15 00:16 108-05-42.0 1
Vinyl chloride ND ug/L 05/02/15 00:16 75-01-41.0 1
Xylene (Total)ND ug/L 05/02/15 00:16 1330-20-72.0 1
m&p-Xylene ND ug/L 05/02/15 00:16 179601-23-12.0 1
o-Xylene ND ug/L 05/02/15 00:16 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)97 %05/02/15 00:16 460-00-470-130 1
1,2-Dichloroethane-d4 (S)110 %05/02/15 00:16 17060-07-070-130 1
Toluene-d8 (S)102 %05/02/15 00:16 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC3-DOWNSTREAM OF
PROJECT
Lab ID:92247219003 Collected:04/24/15 11:38 Received:04/27/15 15:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP
Arsenic ND ug/L 04/30/15 17:39 7440-38-204/29/15 15:3010.0 1
Barium 19.0 ug/L 04/30/15 17:39 7440-39-304/29/15 15:305.0 1
Cadmium ND ug/L 04/30/15 17:39 7440-43-904/29/15 15:301.0 1
Chromium ND ug/L 04/30/15 17:39 7440-47-304/29/15 15:305.0 1
Lead ND ug/L 04/30/15 17:39 7439-92-104/29/15 15:305.0 1
Selenium ND ug/L 04/30/15 17:39 7782-49-204/29/15 15:3010.0 1
Silver ND ug/L 04/30/15 17:39 7440-22-404/29/15 15:305.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 05/01/15 12:37 7439-97-604/30/15 12:200.20 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 05/04/15 17:05 83-32-905/01/15 14:1510.0 1
Acenaphthylene ND ug/L 05/04/15 17:05 208-96-805/01/15 14:1510.0 1
Aniline ND ug/L 05/04/15 17:05 62-53-305/01/15 14:1510.0 1
Anthracene ND ug/L 05/04/15 17:05 120-12-705/01/15 14:1510.0 1
Benzo(a)anthracene ND ug/L 05/04/15 17:05 56-55-305/01/15 14:1510.0 1
Benzo(a)pyrene ND ug/L 05/04/15 17:05 50-32-805/01/15 14:1510.0 1
Benzo(b)fluoranthene ND ug/L 05/04/15 17:05 205-99-205/01/15 14:1510.0 1
Benzo(g,h,i)perylene ND ug/L 05/04/15 17:05 191-24-205/01/15 14:1510.0 1
Benzo(k)fluoranthene ND ug/L 05/04/15 17:05 207-08-905/01/15 14:1510.0 1
Benzoic Acid ND ug/L 05/04/15 17:05 65-85-005/01/15 14:1550.0 1
Benzyl alcohol ND ug/L 05/04/15 17:05 100-51-605/01/15 14:1520.0 1
4-Bromophenylphenyl ether ND ug/L 05/04/15 17:05 101-55-305/01/15 14:1510.0 1
Butylbenzylphthalate ND ug/L 05/04/15 17:05 85-68-705/01/15 14:1510.0 1
4-Chloro-3-methylphenol ND ug/L 05/04/15 17:05 59-50-705/01/15 14:1520.0 1
4-Chloroaniline ND ug/L 05/04/15 17:05 106-47-805/01/15 14:1520.0 1
bis(2-Chloroethoxy)methane ND ug/L 05/04/15 17:05 111-91-105/01/15 14:1510.0 1
bis(2-Chloroethyl) ether ND ug/L 05/04/15 17:05 111-44-405/01/15 14:1510.0 1
bis(2-Chloroisopropyl) ether ND ug/L 05/04/15 17:05 108-60-105/01/15 14:1510.0 1
2-Chloronaphthalene ND ug/L 05/04/15 17:05 91-58-705/01/15 14:1510.0 1
2-Chlorophenol ND ug/L 05/04/15 17:05 95-57-805/01/15 14:1510.0 1
4-Chlorophenylphenyl ether ND ug/L 05/04/15 17:05 7005-72-305/01/15 14:1510.0 1
Chrysene ND ug/L 05/04/15 17:05 218-01-905/01/15 14:1510.0 1
Dibenz(a,h)anthracene ND ug/L 05/04/15 17:05 53-70-305/01/15 14:1510.0 1
Dibenzofuran ND ug/L 05/04/15 17:05 132-64-905/01/15 14:1510.0 1
1,2-Dichlorobenzene ND ug/L 05/04/15 17:05 95-50-105/01/15 14:1510.0 1
1,3-Dichlorobenzene ND ug/L 05/04/15 17:05 541-73-105/01/15 14:1510.0 1
1,4-Dichlorobenzene ND ug/L 05/04/15 17:05 106-46-705/01/15 14:1510.0 1
3,3'-Dichlorobenzidine ND ug/L 05/04/15 17:05 91-94-105/01/15 14:1520.0 1
2,4-Dichlorophenol ND ug/L 05/04/15 17:05 120-83-205/01/15 14:1510.0 1
Diethylphthalate ND ug/L 05/04/15 17:05 84-66-205/01/15 14:1510.0 1
2,4-Dimethylphenol ND ug/L 05/04/15 17:05 105-67-905/01/15 14:1510.0 1
Dimethylphthalate ND ug/L 05/04/15 17:05 131-11-305/01/15 14:1510.0 1
Di-n-butylphthalate ND ug/L 05/04/15 17:05 84-74-205/01/15 14:1510.0 1
4,6-Dinitro-2-methylphenol ND ug/L 05/04/15 17:05 534-52-1 L305/01/15 14:1520.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC3-DOWNSTREAM OF
PROJECT
Lab ID:92247219003 Collected:04/24/15 11:38 Received:04/27/15 15:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
2,4-Dinitrophenol ND ug/L 05/04/15 17:05 51-28-5 L305/01/15 14:1550.0 1
2,4-Dinitrotoluene ND ug/L 05/04/15 17:05 121-14-205/01/15 14:1510.0 1
2,6-Dinitrotoluene ND ug/L 05/04/15 17:05 606-20-205/01/15 14:1510.0 1
Di-n-octylphthalate ND ug/L 05/04/15 17:05 117-84-005/01/15 14:1510.0 1
bis(2-Ethylhexyl)phthalate ND ug/L 05/04/15 17:05 117-81-705/01/15 14:156.0 1
Fluoranthene ND ug/L 05/04/15 17:05 206-44-005/01/15 14:1510.0 1
Fluorene ND ug/L 05/04/15 17:05 86-73-705/01/15 14:1510.0 1
Hexachloro-1,3-butadiene ND ug/L 05/04/15 17:05 87-68-305/01/15 14:1510.0 1
Hexachlorobenzene ND ug/L 05/04/15 17:05 118-74-105/01/15 14:1510.0 1
Hexachlorocyclopentadiene ND ug/L 05/04/15 17:05 77-47-405/01/15 14:1510.0 1
Hexachloroethane ND ug/L 05/04/15 17:05 67-72-105/01/15 14:1510.0 1
Indeno(1,2,3-cd)pyrene ND ug/L 05/04/15 17:05 193-39-505/01/15 14:1510.0 1
Isophorone ND ug/L 05/04/15 17:05 78-59-105/01/15 14:1510.0 1
1-Methylnaphthalene ND ug/L 05/04/15 17:05 90-12-005/01/15 14:1510.0 1
2-Methylnaphthalene ND ug/L 05/04/15 17:05 91-57-605/01/15 14:1510.0 1
2-Methylphenol(o-Cresol)ND ug/L 05/04/15 17:05 95-48-705/01/15 14:1510.0 1
3&4-Methylphenol(m&p Cresol)ND ug/L 05/04/15 17:0505/01/15 14:1510.0 1
Naphthalene ND ug/L 05/04/15 17:05 91-20-305/01/15 14:1510.0 1
2-Nitroaniline ND ug/L 05/04/15 17:05 88-74-405/01/15 14:1550.0 1
3-Nitroaniline ND ug/L 05/04/15 17:05 99-09-205/01/15 14:1550.0 1
4-Nitroaniline ND ug/L 05/04/15 17:05 100-01-605/01/15 14:1520.0 1
Nitrobenzene ND ug/L 05/04/15 17:05 98-95-305/01/15 14:1510.0 1
2-Nitrophenol ND ug/L 05/04/15 17:05 88-75-505/01/15 14:1510.0 1
4-Nitrophenol ND ug/L 05/04/15 17:05 100-02-705/01/15 14:1550.0 1
N-Nitrosodimethylamine ND ug/L 05/04/15 17:05 62-75-905/01/15 14:1510.0 1
N-Nitroso-di-n-propylamine ND ug/L 05/04/15 17:05 621-64-705/01/15 14:1510.0 1
N-Nitrosodiphenylamine ND ug/L 05/04/15 17:05 86-30-605/01/15 14:1510.0 1
Pentachlorophenol ND ug/L 05/04/15 17:05 87-86-5 L305/01/15 14:1525.0 1
Phenanthrene ND ug/L 05/04/15 17:05 85-01-805/01/15 14:1510.0 1
Phenol ND ug/L 05/04/15 17:05 108-95-205/01/15 14:1510.0 1
Pyrene ND ug/L 05/04/15 17:05 129-00-005/01/15 14:1510.0 1
1,2,4-Trichlorobenzene ND ug/L 05/04/15 17:05 120-82-105/01/15 14:1510.0 1
2,4,5-Trichlorophenol ND ug/L 05/04/15 17:05 95-95-405/01/15 14:1510.0 1
2,4,6-Trichlorophenol ND ug/L 05/04/15 17:05 88-06-205/01/15 14:1510.0 1
Surrogates
Nitrobenzene-d5 (S)44 %05/04/15 17:05 4165-60-0 1g05/01/15 14:1521-110 1
2-Fluorobiphenyl (S)39 %05/04/15 17:05 321-60-805/01/15 14:1527-110 1
Terphenyl-d14 (S)76 %05/04/15 17:05 1718-51-005/01/15 14:1531-107 1
Phenol-d6 (S)7 %05/04/15 17:05 13127-88-3 S005/01/15 14:1510-110 1
2-Fluorophenol (S)1 %05/04/15 17:05 367-12-4 S005/01/15 14:1512-110 1
2,4,6-Tribromophenol (S)4 %05/04/15 17:05 118-79-6 S005/01/15 14:1527-110 1
Analytical Method: EPA 82608260 MSV Low Level
Acetone ND ug/L 05/02/15 00:34 67-64-125.0 1
Benzene ND ug/L 05/02/15 00:34 71-43-21.0 1
Bromobenzene ND ug/L 05/02/15 00:34 108-86-11.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC3-DOWNSTREAM OF
PROJECT
Lab ID:92247219003 Collected:04/24/15 11:38 Received:04/27/15 15:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
Bromochloromethane ND ug/L 05/02/15 00:34 74-97-51.0 1
Bromodichloromethane ND ug/L 05/02/15 00:34 75-27-41.0 1
Bromoform ND ug/L 05/02/15 00:34 75-25-21.0 1
Bromomethane ND ug/L 05/02/15 00:34 74-83-92.0 1
2-Butanone (MEK)ND ug/L 05/02/15 00:34 78-93-35.0 1
Carbon tetrachloride ND ug/L 05/02/15 00:34 56-23-51.0 1
Chlorobenzene ND ug/L 05/02/15 00:34 108-90-71.0 1
Chloroethane ND ug/L 05/02/15 00:34 75-00-31.0 1
Chloroform ND ug/L 05/02/15 00:34 67-66-31.0 1
Chloromethane ND ug/L 05/02/15 00:34 74-87-31.0 1
2-Chlorotoluene ND ug/L 05/02/15 00:34 95-49-81.0 1
4-Chlorotoluene ND ug/L 05/02/15 00:34 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 05/02/15 00:34 96-12-82.0 1
Dibromochloromethane ND ug/L 05/02/15 00:34 124-48-11.0 1
1,2-Dibromoethane (EDB)ND ug/L 05/02/15 00:34 106-93-41.0 1
Dibromomethane ND ug/L 05/02/15 00:34 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 05/02/15 00:34 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 05/02/15 00:34 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 05/02/15 00:34 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 05/02/15 00:34 75-71-81.0 1
1,1-Dichloroethane ND ug/L 05/02/15 00:34 75-34-31.0 1
1,2-Dichloroethane ND ug/L 05/02/15 00:34 107-06-21.0 1
1,1-Dichloroethene ND ug/L 05/02/15 00:34 75-35-41.0 1
cis-1,2-Dichloroethene 6.0 ug/L 05/02/15 00:34 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 05/02/15 00:34 156-60-51.0 1
1,2-Dichloropropane ND ug/L 05/02/15 00:34 78-87-51.0 1
1,3-Dichloropropane ND ug/L 05/02/15 00:34 142-28-91.0 1
2,2-Dichloropropane ND ug/L 05/02/15 00:34 594-20-71.0 1
1,1-Dichloropropene ND ug/L 05/02/15 00:34 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 05/02/15 00:34 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 05/02/15 00:34 10061-02-61.0 1
Diisopropyl ether ND ug/L 05/02/15 00:34 108-20-31.0 1
Ethylbenzene ND ug/L 05/02/15 00:34 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 05/02/15 00:34 87-68-31.0 1
2-Hexanone ND ug/L 05/02/15 00:34 591-78-65.0 1
p-Isopropyltoluene ND ug/L 05/02/15 00:34 99-87-61.0 1
Methylene Chloride ND ug/L 05/02/15 00:34 75-09-22.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 05/02/15 00:34 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 05/02/15 00:34 1634-04-41.0 1
Naphthalene ND ug/L 05/02/15 00:34 91-20-31.0 1
Styrene ND ug/L 05/02/15 00:34 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 05/02/15 00:34 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 05/02/15 00:34 79-34-51.0 1
Tetrachloroethene 16.5 ug/L 05/02/15 00:34 127-18-41.0 1
Toluene ND ug/L 05/02/15 00:34 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 05/02/15 00:34 87-61-61.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC3-DOWNSTREAM OF
PROJECT
Lab ID:92247219003 Collected:04/24/15 11:38 Received:04/27/15 15:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
1,2,4-Trichlorobenzene ND ug/L 05/02/15 00:34 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 05/02/15 00:34 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 05/02/15 00:34 79-00-51.0 1
Trichloroethene 1.5 ug/L 05/02/15 00:34 79-01-61.0 1
Trichlorofluoromethane ND ug/L 05/02/15 00:34 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 05/02/15 00:34 96-18-41.0 1
Vinyl acetate ND ug/L 05/02/15 00:34 108-05-42.0 1
Vinyl chloride ND ug/L 05/02/15 00:34 75-01-41.0 1
Xylene (Total)ND ug/L 05/02/15 00:34 1330-20-72.0 1
m&p-Xylene ND ug/L 05/02/15 00:34 179601-23-12.0 1
o-Xylene ND ug/L 05/02/15 00:34 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)101 %05/02/15 00:34 460-00-470-130 1
1,2-Dichloroethane-d4 (S)109 %05/02/15 00:34 17060-07-070-130 1
Toluene-d8 (S)101 %05/02/15 00:34 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC1-UPSTREAM FROM
PROJECT
Lab ID:92247219004 Collected:04/24/15 12:28 Received:04/27/15 15:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Arsenic ND mg/kg 05/01/15 01:49 7440-38-204/30/15 10:450.81 1
Barium 39.0 mg/kg 05/01/15 01:49 7440-39-304/30/15 10:450.41 1
Cadmium ND mg/kg 05/01/15 01:49 7440-43-904/30/15 10:450.081 1
Chromium 1.5 mg/kg 05/01/15 01:49 7440-47-304/30/15 10:450.41 1
Lead 14.2 mg/kg 05/01/15 01:49 7439-92-104/30/15 10:450.41 1
Selenium ND mg/kg 05/01/15 01:49 7782-49-204/30/15 10:450.81 1
Silver ND mg/kg 05/01/15 01:49 7440-22-404/30/15 10:450.41 1
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 04/29/15 14:00 7439-97-604/29/15 11:400.0042 1
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
Acenaphthene ND ug/kg 05/03/15 23:42 83-32-905/02/15 14:204241
Acenaphthylene ND ug/kg 05/03/15 23:42 208-96-805/02/15 14:204241
Aniline ND ug/kg 05/03/15 23:42 62-53-305/02/15 14:204241
Anthracene ND ug/kg 05/03/15 23:42 120-12-705/02/15 14:204241
Benzo(a)anthracene ND ug/kg 05/03/15 23:42 56-55-305/02/15 14:204241
Benzo(a)pyrene ND ug/kg 05/03/15 23:42 50-32-805/02/15 14:204241
Benzo(b)fluoranthene ND ug/kg 05/03/15 23:42 205-99-205/02/15 14:204241
Benzo(g,h,i)perylene ND ug/kg 05/03/15 23:42 191-24-205/02/15 14:204241
Benzo(k)fluoranthene ND ug/kg 05/03/15 23:42 207-08-905/02/15 14:204241
Benzoic Acid ND ug/kg 05/03/15 23:42 65-85-005/02/15 14:2021201
Benzyl alcohol ND ug/kg 05/03/15 23:42 100-51-605/02/15 14:208481
4-Bromophenylphenyl ether ND ug/kg 05/03/15 23:42 101-55-305/02/15 14:204241
Butylbenzylphthalate ND ug/kg 05/03/15 23:42 85-68-705/02/15 14:204241
4-Chloro-3-methylphenol ND ug/kg 05/03/15 23:42 59-50-705/02/15 14:208481
4-Chloroaniline ND ug/kg 05/03/15 23:42 106-47-805/02/15 14:2021201
bis(2-Chloroethoxy)methane ND ug/kg 05/03/15 23:42 111-91-105/02/15 14:204241
bis(2-Chloroethyl) ether ND ug/kg 05/03/15 23:42 111-44-405/02/15 14:204241
bis(2-Chloroisopropyl) ether ND ug/kg 05/03/15 23:42 108-60-105/02/15 14:204241
2-Chloronaphthalene ND ug/kg 05/03/15 23:42 91-58-705/02/15 14:204241
2-Chlorophenol ND ug/kg 05/03/15 23:42 95-57-805/02/15 14:204241
4-Chlorophenylphenyl ether ND ug/kg 05/03/15 23:42 7005-72-305/02/15 14:204241
Chrysene ND ug/kg 05/03/15 23:42 218-01-905/02/15 14:204241
Dibenz(a,h)anthracene ND ug/kg 05/03/15 23:42 53-70-305/02/15 14:204241
Dibenzofuran ND ug/kg 05/03/15 23:42 132-64-905/02/15 14:204241
1,2-Dichlorobenzene ND ug/kg 05/03/15 23:42 95-50-105/02/15 14:204241
1,3-Dichlorobenzene ND ug/kg 05/03/15 23:42 541-73-1 L205/02/15 14:204241
1,4-Dichlorobenzene ND ug/kg 05/03/15 23:42 106-46-705/02/15 14:204241
3,3'-Dichlorobenzidine ND ug/kg 05/03/15 23:42 91-94-105/02/15 14:2021201
2,4-Dichlorophenol ND ug/kg 05/03/15 23:42 120-83-205/02/15 14:204241
Diethylphthalate ND ug/kg 05/03/15 23:42 84-66-205/02/15 14:204241
2,4-Dimethylphenol ND ug/kg 05/03/15 23:42 105-67-905/02/15 14:204241
Dimethylphthalate ND ug/kg 05/03/15 23:42 131-11-305/02/15 14:204241
Di-n-butylphthalate ND ug/kg 05/03/15 23:42 84-74-205/02/15 14:204241
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC1-UPSTREAM FROM
PROJECT
Lab ID:92247219004 Collected:04/24/15 12:28 Received:04/27/15 15:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
4,6-Dinitro-2-methylphenol ND ug/kg 05/03/15 23:42 534-52-105/02/15 14:208481
2,4-Dinitrophenol ND ug/kg 05/03/15 23:42 51-28-505/02/15 14:2021201
2,4-Dinitrotoluene ND ug/kg 05/03/15 23:42 121-14-205/02/15 14:204241
2,6-Dinitrotoluene ND ug/kg 05/03/15 23:42 606-20-205/02/15 14:204241
Di-n-octylphthalate ND ug/kg 05/03/15 23:42 117-84-005/02/15 14:204241
bis(2-Ethylhexyl)phthalate ND ug/kg 05/03/15 23:42 117-81-705/02/15 14:204241
Fluoranthene ND ug/kg 05/03/15 23:42 206-44-005/02/15 14:204241
Fluorene ND ug/kg 05/03/15 23:42 86-73-705/02/15 14:204241
Hexachloro-1,3-butadiene ND ug/kg 05/03/15 23:42 87-68-305/02/15 14:204241
Hexachlorobenzene ND ug/kg 05/03/15 23:42 118-74-105/02/15 14:204241
Hexachlorocyclopentadiene ND ug/kg 05/03/15 23:42 77-47-405/02/15 14:204241
Hexachloroethane ND ug/kg 05/03/15 23:42 67-72-105/02/15 14:204241
Indeno(1,2,3-cd)pyrene ND ug/kg 05/03/15 23:42 193-39-505/02/15 14:204241
Isophorone ND ug/kg 05/03/15 23:42 78-59-105/02/15 14:204241
1-Methylnaphthalene ND ug/kg 05/03/15 23:42 90-12-005/02/15 14:204241
2-Methylnaphthalene ND ug/kg 05/03/15 23:42 91-57-605/02/15 14:204241
2-Methylphenol(o-Cresol)ND ug/kg 05/03/15 23:42 95-48-705/02/15 14:204241
3&4-Methylphenol(m&p Cresol)ND ug/kg 05/03/15 23:4205/02/15 14:204241
Naphthalene ND ug/kg 05/03/15 23:42 91-20-305/02/15 14:204241
2-Nitroaniline ND ug/kg 05/03/15 23:42 88-74-405/02/15 14:2021201
3-Nitroaniline ND ug/kg 05/03/15 23:42 99-09-205/02/15 14:2021201
4-Nitroaniline ND ug/kg 05/03/15 23:42 100-01-605/02/15 14:208481
Nitrobenzene ND ug/kg 05/03/15 23:42 98-95-305/02/15 14:204241
2-Nitrophenol ND ug/kg 05/03/15 23:42 88-75-505/02/15 14:204241
4-Nitrophenol ND ug/kg 05/03/15 23:42 100-02-705/02/15 14:2021201
N-Nitrosodimethylamine ND ug/kg 05/03/15 23:42 62-75-905/02/15 14:204241
N-Nitroso-di-n-propylamine ND ug/kg 05/03/15 23:42 621-64-705/02/15 14:204241
N-Nitrosodiphenylamine ND ug/kg 05/03/15 23:42 86-30-605/02/15 14:204241
Pentachlorophenol ND ug/kg 05/03/15 23:42 87-86-505/02/15 14:2021201
Phenanthrene ND ug/kg 05/03/15 23:42 85-01-805/02/15 14:204241
Phenol ND ug/kg 05/03/15 23:42 108-95-205/02/15 14:204241
Pyrene ND ug/kg 05/03/15 23:42 129-00-0 L205/02/15 14:204241
1,2,4-Trichlorobenzene ND ug/kg 05/03/15 23:42 120-82-105/02/15 14:204241
2,4,5-Trichlorophenol ND ug/kg 05/03/15 23:42 95-95-405/02/15 14:204241
2,4,6-Trichlorophenol ND ug/kg 05/03/15 23:42 88-06-205/02/15 14:204241
Surrogates
Nitrobenzene-d5 (S)65 %05/03/15 23:42 4165-60-005/02/15 14:2023-110 1
2-Fluorobiphenyl (S)59 %05/03/15 23:42 321-60-805/02/15 14:2030-110 1
Terphenyl-d14 (S)48 %05/03/15 23:42 1718-51-005/02/15 14:2028-110 1
Phenol-d6 (S)34 %05/03/15 23:42 13127-88-305/02/15 14:2022-110 1
2-Fluorophenol (S)27 %05/03/15 23:42 367-12-405/02/15 14:2013-110 1
2,4,6-Tribromophenol (S)24 %05/03/15 23:42 118-79-6 S005/02/15 14:2027-110 1
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone ND ug/kg 04/29/15 23:51 67-64-11001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC1-UPSTREAM FROM
PROJECT
Lab ID:92247219004 Collected:04/24/15 12:28 Received:04/27/15 15:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260/5035A Volatile Organics
Benzene ND ug/kg 04/29/15 23:51 71-43-25.0 1
Bromobenzene ND ug/kg 04/29/15 23:51 108-86-15.0 1
Bromochloromethane ND ug/kg 04/29/15 23:51 74-97-55.0 1
Bromodichloromethane ND ug/kg 04/29/15 23:51 75-27-45.0 1
Bromoform ND ug/kg 04/29/15 23:51 75-25-25.0 1
Bromomethane ND ug/kg 04/29/15 23:51 74-83-9 M110.0 1
2-Butanone (MEK)ND ug/kg 04/29/15 23:51 78-93-3 M11001
n-Butylbenzene ND ug/kg 04/29/15 23:51 104-51-85.0 1
sec-Butylbenzene ND ug/kg 04/29/15 23:51 135-98-85.0 1
tert-Butylbenzene ND ug/kg 04/29/15 23:51 98-06-65.0 1
Carbon tetrachloride ND ug/kg 04/29/15 23:51 56-23-55.0 1
Chlorobenzene ND ug/kg 04/29/15 23:51 108-90-75.0 1
Chloroethane ND ug/kg 04/29/15 23:51 75-00-310.0 1
Chloroform ND ug/kg 04/29/15 23:51 67-66-35.0 1
Chloromethane ND ug/kg 04/29/15 23:51 74-87-310.0 1
2-Chlorotoluene ND ug/kg 04/29/15 23:51 95-49-85.0 1
4-Chlorotoluene ND ug/kg 04/29/15 23:51 106-43-45.0 1
1,2-Dibromo-3-chloropropane ND ug/kg 04/29/15 23:51 96-12-85.0 1
Dibromochloromethane ND ug/kg 04/29/15 23:51 124-48-15.0 1
1,2-Dibromoethane (EDB)ND ug/kg 04/29/15 23:51 106-93-45.0 1
Dibromomethane ND ug/kg 04/29/15 23:51 74-95-35.0 1
1,2-Dichlorobenzene ND ug/kg 04/29/15 23:51 95-50-15.0 1
1,3-Dichlorobenzene ND ug/kg 04/29/15 23:51 541-73-15.0 1
1,4-Dichlorobenzene ND ug/kg 04/29/15 23:51 106-46-75.0 1
Dichlorodifluoromethane ND ug/kg 04/29/15 23:51 75-71-810.0 1
1,1-Dichloroethane ND ug/kg 04/29/15 23:51 75-34-35.0 1
1,2-Dichloroethane ND ug/kg 04/29/15 23:51 107-06-25.0 1
1,1-Dichloroethene ND ug/kg 04/29/15 23:51 75-35-45.0 1
cis-1,2-Dichloroethene ND ug/kg 04/29/15 23:51 156-59-25.0 1
trans-1,2-Dichloroethene ND ug/kg 04/29/15 23:51 156-60-55.0 1
1,2-Dichloropropane ND ug/kg 04/29/15 23:51 78-87-55.0 1
1,3-Dichloropropane ND ug/kg 04/29/15 23:51 142-28-95.0 1
2,2-Dichloropropane ND ug/kg 04/29/15 23:51 594-20-75.0 1
1,1-Dichloropropene ND ug/kg 04/29/15 23:51 563-58-65.0 1
cis-1,3-Dichloropropene ND ug/kg 04/29/15 23:51 10061-01-55.0 1
trans-1,3-Dichloropropene ND ug/kg 04/29/15 23:51 10061-02-65.0 1
Diisopropyl ether ND ug/kg 04/29/15 23:51 108-20-35.0 1
Ethylbenzene ND ug/kg 04/29/15 23:51 100-41-45.0 1
Hexachloro-1,3-butadiene ND ug/kg 04/29/15 23:51 87-68-35.0 1
2-Hexanone ND ug/kg 04/29/15 23:51 591-78-6 M150.2 1
Isopropylbenzene (Cumene)ND ug/kg 04/29/15 23:51 98-82-85.0 1
p-Isopropyltoluene ND ug/kg 04/29/15 23:51 99-87-65.0 1
Methylene Chloride ND ug/kg 04/29/15 23:51 75-09-220.1 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 04/29/15 23:51 108-10-1 M150.2 1
Methyl-tert-butyl ether ND ug/kg 04/29/15 23:51 1634-04-45.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC1-UPSTREAM FROM
PROJECT
Lab ID:92247219004 Collected:04/24/15 12:28 Received:04/27/15 15:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260/5035A Volatile Organics
Naphthalene ND ug/kg 04/29/15 23:51 91-20-35.0 1
n-Propylbenzene ND ug/kg 04/29/15 23:51 103-65-15.0 1
Styrene ND ug/kg 04/29/15 23:51 100-42-55.0 1
1,1,1,2-Tetrachloroethane ND ug/kg 04/29/15 23:51 630-20-65.0 1
1,1,2,2-Tetrachloroethane ND ug/kg 04/29/15 23:51 79-34-55.0 1
Tetrachloroethene 5.8 ug/kg 04/29/15 23:51 127-18-45.0 1
Toluene ND ug/kg 04/29/15 23:51 108-88-35.0 1
1,2,3-Trichlorobenzene ND ug/kg 04/29/15 23:51 87-61-65.0 1
1,2,4-Trichlorobenzene ND ug/kg 04/29/15 23:51 120-82-15.0 1
1,1,1-Trichloroethane ND ug/kg 04/29/15 23:51 71-55-65.0 1
1,1,2-Trichloroethane ND ug/kg 04/29/15 23:51 79-00-55.0 1
Trichloroethene ND ug/kg 04/29/15 23:51 79-01-65.0 1
Trichlorofluoromethane ND ug/kg 04/29/15 23:51 75-69-45.0 1
1,2,3-Trichloropropane ND ug/kg 04/29/15 23:51 96-18-4 M15.0 1
1,2,4-Trimethylbenzene ND ug/kg 04/29/15 23:51 95-63-65.0 1
1,3,5-Trimethylbenzene ND ug/kg 04/29/15 23:51 108-67-85.0 1
Vinyl acetate ND ug/kg 04/29/15 23:51 108-05-4 M150.2 1
Vinyl chloride ND ug/kg 04/29/15 23:51 75-01-410.0 1
Xylene (Total)ND ug/kg 04/29/15 23:51 1330-20-710.0 1
m&p-Xylene ND ug/kg 04/29/15 23:51 179601-23-110.0 1
o-Xylene ND ug/kg 04/29/15 23:51 95-47-65.0 1
Surrogates
Toluene-d8 (S)103 %04/29/15 23:51 2037-26-570-130 1
4-Bromofluorobenzene (S)101 %04/29/15 23:51 460-00-470-130 1
1,2-Dichloroethane-d4 (S)119 %04/29/15 23:51 17060-07-070-132 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 22.1 %04/29/15 13:090.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC2-PROJECT AREA Lab ID:92247219005 Collected:04/24/15 12:00 Received:04/27/15 15:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Arsenic 1.4 mg/kg 05/01/15 02:01 7440-38-204/30/15 10:450.91 1
Barium 19.4 mg/kg 05/01/15 02:01 7440-39-304/30/15 10:450.45 1
Cadmium 0.10 mg/kg 05/01/15 02:01 7440-43-904/30/15 10:450.091 1
Chromium 4.3 mg/kg 05/01/15 02:01 7440-47-304/30/15 10:450.45 1
Lead 4.6 mg/kg 05/01/15 02:01 7439-92-104/30/15 10:450.45 1
Selenium ND mg/kg 05/01/15 02:01 7782-49-204/30/15 10:450.91 1
Silver ND mg/kg 05/01/15 02:01 7440-22-404/30/15 10:450.45 1
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 04/29/15 14:08 7439-97-604/29/15 11:400.0048 1
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
Acenaphthene ND ug/kg 05/04/15 00:10 83-32-905/02/15 14:204501
Acenaphthylene ND ug/kg 05/04/15 00:10 208-96-805/02/15 14:204501
Aniline ND ug/kg 05/04/15 00:10 62-53-305/02/15 14:204501
Anthracene ND ug/kg 05/04/15 00:10 120-12-705/02/15 14:204501
Benzo(a)anthracene ND ug/kg 05/04/15 00:10 56-55-305/02/15 14:204501
Benzo(a)pyrene ND ug/kg 05/04/15 00:10 50-32-805/02/15 14:204501
Benzo(b)fluoranthene ND ug/kg 05/04/15 00:10 205-99-205/02/15 14:204501
Benzo(g,h,i)perylene ND ug/kg 05/04/15 00:10 191-24-205/02/15 14:204501
Benzo(k)fluoranthene ND ug/kg 05/04/15 00:10 207-08-905/02/15 14:204501
Benzoic Acid ND ug/kg 05/04/15 00:10 65-85-005/02/15 14:2022501
Benzyl alcohol ND ug/kg 05/04/15 00:10 100-51-605/02/15 14:209001
4-Bromophenylphenyl ether ND ug/kg 05/04/15 00:10 101-55-305/02/15 14:204501
Butylbenzylphthalate ND ug/kg 05/04/15 00:10 85-68-705/02/15 14:204501
4-Chloro-3-methylphenol ND ug/kg 05/04/15 00:10 59-50-705/02/15 14:209001
4-Chloroaniline ND ug/kg 05/04/15 00:10 106-47-805/02/15 14:2022501
bis(2-Chloroethoxy)methane ND ug/kg 05/04/15 00:10 111-91-105/02/15 14:204501
bis(2-Chloroethyl) ether ND ug/kg 05/04/15 00:10 111-44-405/02/15 14:204501
bis(2-Chloroisopropyl) ether ND ug/kg 05/04/15 00:10 108-60-105/02/15 14:204501
2-Chloronaphthalene ND ug/kg 05/04/15 00:10 91-58-705/02/15 14:204501
2-Chlorophenol ND ug/kg 05/04/15 00:10 95-57-805/02/15 14:204501
4-Chlorophenylphenyl ether ND ug/kg 05/04/15 00:10 7005-72-305/02/15 14:204501
Chrysene ND ug/kg 05/04/15 00:10 218-01-905/02/15 14:204501
Dibenz(a,h)anthracene ND ug/kg 05/04/15 00:10 53-70-305/02/15 14:204501
Dibenzofuran ND ug/kg 05/04/15 00:10 132-64-905/02/15 14:204501
1,2-Dichlorobenzene ND ug/kg 05/04/15 00:10 95-50-105/02/15 14:204501
1,3-Dichlorobenzene ND ug/kg 05/04/15 00:10 541-73-1 L205/02/15 14:204501
1,4-Dichlorobenzene ND ug/kg 05/04/15 00:10 106-46-705/02/15 14:204501
3,3'-Dichlorobenzidine ND ug/kg 05/04/15 00:10 91-94-105/02/15 14:2022501
2,4-Dichlorophenol ND ug/kg 05/04/15 00:10 120-83-205/02/15 14:204501
Diethylphthalate ND ug/kg 05/04/15 00:10 84-66-205/02/15 14:204501
2,4-Dimethylphenol ND ug/kg 05/04/15 00:10 105-67-905/02/15 14:204501
Dimethylphthalate ND ug/kg 05/04/15 00:10 131-11-305/02/15 14:204501
Di-n-butylphthalate ND ug/kg 05/04/15 00:10 84-74-205/02/15 14:204501
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC2-PROJECT AREA Lab ID:92247219005 Collected:04/24/15 12:00 Received:04/27/15 15:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
4,6-Dinitro-2-methylphenol ND ug/kg 05/04/15 00:10 534-52-105/02/15 14:209001
2,4-Dinitrophenol ND ug/kg 05/04/15 00:10 51-28-505/02/15 14:2022501
2,4-Dinitrotoluene ND ug/kg 05/04/15 00:10 121-14-205/02/15 14:204501
2,6-Dinitrotoluene ND ug/kg 05/04/15 00:10 606-20-205/02/15 14:204501
Di-n-octylphthalate ND ug/kg 05/04/15 00:10 117-84-005/02/15 14:204501
bis(2-Ethylhexyl)phthalate ND ug/kg 05/04/15 00:10 117-81-705/02/15 14:204501
Fluoranthene ND ug/kg 05/04/15 00:10 206-44-005/02/15 14:204501
Fluorene ND ug/kg 05/04/15 00:10 86-73-705/02/15 14:204501
Hexachloro-1,3-butadiene ND ug/kg 05/04/15 00:10 87-68-305/02/15 14:204501
Hexachlorobenzene ND ug/kg 05/04/15 00:10 118-74-105/02/15 14:204501
Hexachlorocyclopentadiene ND ug/kg 05/04/15 00:10 77-47-405/02/15 14:204501
Hexachloroethane ND ug/kg 05/04/15 00:10 67-72-105/02/15 14:204501
Indeno(1,2,3-cd)pyrene ND ug/kg 05/04/15 00:10 193-39-505/02/15 14:204501
Isophorone ND ug/kg 05/04/15 00:10 78-59-105/02/15 14:204501
1-Methylnaphthalene ND ug/kg 05/04/15 00:10 90-12-005/02/15 14:204501
2-Methylnaphthalene ND ug/kg 05/04/15 00:10 91-57-605/02/15 14:204501
2-Methylphenol(o-Cresol)ND ug/kg 05/04/15 00:10 95-48-705/02/15 14:204501
3&4-Methylphenol(m&p Cresol)ND ug/kg 05/04/15 00:1005/02/15 14:204501
Naphthalene ND ug/kg 05/04/15 00:10 91-20-305/02/15 14:204501
2-Nitroaniline ND ug/kg 05/04/15 00:10 88-74-405/02/15 14:2022501
3-Nitroaniline ND ug/kg 05/04/15 00:10 99-09-205/02/15 14:2022501
4-Nitroaniline ND ug/kg 05/04/15 00:10 100-01-605/02/15 14:209001
Nitrobenzene ND ug/kg 05/04/15 00:10 98-95-305/02/15 14:204501
2-Nitrophenol ND ug/kg 05/04/15 00:10 88-75-505/02/15 14:204501
4-Nitrophenol ND ug/kg 05/04/15 00:10 100-02-705/02/15 14:2022501
N-Nitrosodimethylamine ND ug/kg 05/04/15 00:10 62-75-905/02/15 14:204501
N-Nitroso-di-n-propylamine ND ug/kg 05/04/15 00:10 621-64-705/02/15 14:204501
N-Nitrosodiphenylamine ND ug/kg 05/04/15 00:10 86-30-605/02/15 14:204501
Pentachlorophenol ND ug/kg 05/04/15 00:10 87-86-505/02/15 14:2022501
Phenanthrene ND ug/kg 05/04/15 00:10 85-01-805/02/15 14:204501
Phenol ND ug/kg 05/04/15 00:10 108-95-205/02/15 14:204501
Pyrene ND ug/kg 05/04/15 00:10 129-00-0 L205/02/15 14:204501
1,2,4-Trichlorobenzene ND ug/kg 05/04/15 00:10 120-82-105/02/15 14:204501
2,4,5-Trichlorophenol ND ug/kg 05/04/15 00:10 95-95-405/02/15 14:204501
2,4,6-Trichlorophenol ND ug/kg 05/04/15 00:10 88-06-205/02/15 14:204501
Surrogates
Nitrobenzene-d5 (S)67 %05/04/15 00:10 4165-60-005/02/15 14:2023-110 1
2-Fluorobiphenyl (S)59 %05/04/15 00:10 321-60-805/02/15 14:2030-110 1
Terphenyl-d14 (S)43 %05/04/15 00:10 1718-51-005/02/15 14:2028-110 1
Phenol-d6 (S)33 %05/04/15 00:10 13127-88-305/02/15 14:2022-110 1
2-Fluorophenol (S)32 %05/04/15 00:10 367-12-405/02/15 14:2013-110 1
2,4,6-Tribromophenol (S)26 %05/04/15 00:10 118-79-6 S005/02/15 14:2027-110 1
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone ND ug/kg 04/30/15 00:11 67-64-11141
Benzene ND ug/kg 04/30/15 00:11 71-43-25.7 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC2-PROJECT AREA Lab ID:92247219005 Collected:04/24/15 12:00 Received:04/27/15 15:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260/5035A Volatile Organics
Bromobenzene ND ug/kg 04/30/15 00:11 108-86-15.7 1
Bromochloromethane ND ug/kg 04/30/15 00:11 74-97-55.7 1
Bromodichloromethane ND ug/kg 04/30/15 00:11 75-27-45.7 1
Bromoform ND ug/kg 04/30/15 00:11 75-25-25.7 1
Bromomethane ND ug/kg 04/30/15 00:11 74-83-911.4 1
2-Butanone (MEK)ND ug/kg 04/30/15 00:11 78-93-31141
n-Butylbenzene ND ug/kg 04/30/15 00:11 104-51-85.7 1
sec-Butylbenzene ND ug/kg 04/30/15 00:11 135-98-85.7 1
tert-Butylbenzene ND ug/kg 04/30/15 00:11 98-06-65.7 1
Carbon tetrachloride ND ug/kg 04/30/15 00:11 56-23-55.7 1
Chlorobenzene ND ug/kg 04/30/15 00:11 108-90-75.7 1
Chloroethane ND ug/kg 04/30/15 00:11 75-00-311.4 1
Chloroform ND ug/kg 04/30/15 00:11 67-66-35.7 1
Chloromethane ND ug/kg 04/30/15 00:11 74-87-311.4 1
2-Chlorotoluene ND ug/kg 04/30/15 00:11 95-49-85.7 1
4-Chlorotoluene ND ug/kg 04/30/15 00:11 106-43-45.7 1
1,2-Dibromo-3-chloropropane ND ug/kg 04/30/15 00:11 96-12-85.7 1
Dibromochloromethane ND ug/kg 04/30/15 00:11 124-48-15.7 1
1,2-Dibromoethane (EDB)ND ug/kg 04/30/15 00:11 106-93-45.7 1
Dibromomethane ND ug/kg 04/30/15 00:11 74-95-35.7 1
1,2-Dichlorobenzene ND ug/kg 04/30/15 00:11 95-50-15.7 1
1,3-Dichlorobenzene ND ug/kg 04/30/15 00:11 541-73-15.7 1
1,4-Dichlorobenzene ND ug/kg 04/30/15 00:11 106-46-75.7 1
Dichlorodifluoromethane ND ug/kg 04/30/15 00:11 75-71-811.4 1
1,1-Dichloroethane ND ug/kg 04/30/15 00:11 75-34-35.7 1
1,2-Dichloroethane ND ug/kg 04/30/15 00:11 107-06-25.7 1
1,1-Dichloroethene ND ug/kg 04/30/15 00:11 75-35-45.7 1
cis-1,2-Dichloroethene ND ug/kg 04/30/15 00:11 156-59-25.7 1
trans-1,2-Dichloroethene ND ug/kg 04/30/15 00:11 156-60-55.7 1
1,2-Dichloropropane ND ug/kg 04/30/15 00:11 78-87-55.7 1
1,3-Dichloropropane ND ug/kg 04/30/15 00:11 142-28-95.7 1
2,2-Dichloropropane ND ug/kg 04/30/15 00:11 594-20-75.7 1
1,1-Dichloropropene ND ug/kg 04/30/15 00:11 563-58-65.7 1
cis-1,3-Dichloropropene ND ug/kg 04/30/15 00:11 10061-01-55.7 1
trans-1,3-Dichloropropene ND ug/kg 04/30/15 00:11 10061-02-65.7 1
Diisopropyl ether ND ug/kg 04/30/15 00:11 108-20-35.7 1
Ethylbenzene ND ug/kg 04/30/15 00:11 100-41-45.7 1
Hexachloro-1,3-butadiene ND ug/kg 04/30/15 00:11 87-68-35.7 1
2-Hexanone ND ug/kg 04/30/15 00:11 591-78-656.9 1
Isopropylbenzene (Cumene)ND ug/kg 04/30/15 00:11 98-82-85.7 1
p-Isopropyltoluene ND ug/kg 04/30/15 00:11 99-87-65.7 1
Methylene Chloride ND ug/kg 04/30/15 00:11 75-09-222.8 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 04/30/15 00:11 108-10-156.9 1
Methyl-tert-butyl ether ND ug/kg 04/30/15 00:11 1634-04-45.7 1
Naphthalene ND ug/kg 04/30/15 00:11 91-20-35.7 1
n-Propylbenzene ND ug/kg 04/30/15 00:11 103-65-15.7 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC2-PROJECT AREA Lab ID:92247219005 Collected:04/24/15 12:00 Received:04/27/15 15:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260/5035A Volatile Organics
Styrene ND ug/kg 04/30/15 00:11 100-42-55.7 1
1,1,1,2-Tetrachloroethane ND ug/kg 04/30/15 00:11 630-20-65.7 1
1,1,2,2-Tetrachloroethane ND ug/kg 04/30/15 00:11 79-34-55.7 1
Tetrachloroethene 38.3 ug/kg 04/30/15 00:11 127-18-45.7 1
Toluene ND ug/kg 04/30/15 00:11 108-88-35.7 1
1,2,3-Trichlorobenzene ND ug/kg 04/30/15 00:11 87-61-65.7 1
1,2,4-Trichlorobenzene ND ug/kg 04/30/15 00:11 120-82-15.7 1
1,1,1-Trichloroethane ND ug/kg 04/30/15 00:11 71-55-65.7 1
1,1,2-Trichloroethane ND ug/kg 04/30/15 00:11 79-00-55.7 1
Trichloroethene ND ug/kg 04/30/15 00:11 79-01-65.7 1
Trichlorofluoromethane ND ug/kg 04/30/15 00:11 75-69-45.7 1
1,2,3-Trichloropropane ND ug/kg 04/30/15 00:11 96-18-45.7 1
1,2,4-Trimethylbenzene ND ug/kg 04/30/15 00:11 95-63-65.7 1
1,3,5-Trimethylbenzene ND ug/kg 04/30/15 00:11 108-67-85.7 1
Vinyl acetate ND ug/kg 04/30/15 00:11 108-05-4 L356.9 1
Vinyl chloride ND ug/kg 04/30/15 00:11 75-01-411.4 1
Xylene (Total)ND ug/kg 04/30/15 00:11 1330-20-711.4 1
m&p-Xylene ND ug/kg 04/30/15 00:11 179601-23-111.4 1
o-Xylene ND ug/kg 04/30/15 00:11 95-47-65.7 1
Surrogates
Toluene-d8 (S)103 %04/30/15 00:11 2037-26-570-130 1
4-Bromofluorobenzene (S)97 %04/30/15 00:11 460-00-470-130 1
1,2-Dichloroethane-d4 (S)122 %04/30/15 00:11 17060-07-070-132 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 26.6 %04/29/15 13:100.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC3-DOWNSTREAM OF
PROJECT AREA
Lab ID:92247219006 Collected:04/24/15 11:28 Received:04/27/15 15:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Arsenic 1.3 mg/kg 05/01/15 02:04 7440-38-204/30/15 10:450.69 1
Barium 5.1 mg/kg 05/01/15 02:04 7440-39-304/30/15 10:450.35 1
Cadmium ND mg/kg 05/01/15 02:04 7440-43-904/30/15 10:450.069 1
Chromium 1.0 mg/kg 05/01/15 02:04 7440-47-304/30/15 10:450.35 1
Lead 1.2 mg/kg 05/01/15 02:04 7439-92-104/30/15 10:450.35 1
Selenium ND mg/kg 05/01/15 02:04 7782-49-204/30/15 10:450.69 1
Silver ND mg/kg 05/01/15 02:04 7440-22-404/30/15 10:450.35 1
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 04/29/15 14:10 7439-97-604/29/15 11:400.0042 1
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
Acenaphthene ND ug/kg 05/05/15 12:13 83-32-905/04/15 10:254401
Acenaphthylene ND ug/kg 05/05/15 12:13 208-96-805/04/15 10:254401
Aniline ND ug/kg 05/05/15 12:13 62-53-305/04/15 10:254401
Anthracene ND ug/kg 05/05/15 12:13 120-12-705/04/15 10:254401
Benzo(a)anthracene ND ug/kg 05/05/15 12:13 56-55-305/04/15 10:254401
Benzo(a)pyrene ND ug/kg 05/05/15 12:13 50-32-805/04/15 10:254401
Benzo(b)fluoranthene ND ug/kg 05/05/15 12:13 205-99-205/04/15 10:254401
Benzo(g,h,i)perylene ND ug/kg 05/05/15 12:13 191-24-205/04/15 10:254401
Benzo(k)fluoranthene ND ug/kg 05/05/15 12:13 207-08-905/04/15 10:254401
Benzoic Acid ND ug/kg 05/05/15 12:13 65-85-005/04/15 10:2522001
Benzyl alcohol ND ug/kg 05/05/15 12:13 100-51-605/04/15 10:258801
4-Bromophenylphenyl ether ND ug/kg 05/05/15 12:13 101-55-305/04/15 10:254401
Butylbenzylphthalate ND ug/kg 05/05/15 12:13 85-68-705/04/15 10:254401
4-Chloro-3-methylphenol ND ug/kg 05/05/15 12:13 59-50-705/04/15 10:258801
4-Chloroaniline ND ug/kg 05/05/15 12:13 106-47-805/04/15 10:2522001
bis(2-Chloroethoxy)methane ND ug/kg 05/05/15 12:13 111-91-105/04/15 10:254401
bis(2-Chloroethyl) ether ND ug/kg 05/05/15 12:13 111-44-405/04/15 10:254401
bis(2-Chloroisopropyl) ether ND ug/kg 05/05/15 12:13 108-60-1 L305/04/15 10:254401
2-Chloronaphthalene ND ug/kg 05/05/15 12:13 91-58-705/04/15 10:254401
2-Chlorophenol ND ug/kg 05/05/15 12:13 95-57-805/04/15 10:254401
4-Chlorophenylphenyl ether ND ug/kg 05/05/15 12:13 7005-72-305/04/15 10:254401
Chrysene ND ug/kg 05/05/15 12:13 218-01-905/04/15 10:254401
Dibenz(a,h)anthracene ND ug/kg 05/05/15 12:13 53-70-305/04/15 10:254401
Dibenzofuran ND ug/kg 05/05/15 12:13 132-64-905/04/15 10:254401
1,2-Dichlorobenzene ND ug/kg 05/05/15 12:13 95-50-105/04/15 10:254401
1,3-Dichlorobenzene ND ug/kg 05/05/15 12:13 541-73-105/04/15 10:254401
1,4-Dichlorobenzene ND ug/kg 05/05/15 12:13 106-46-705/04/15 10:254401
3,3'-Dichlorobenzidine ND ug/kg 05/05/15 12:13 91-94-105/04/15 10:2522001
2,4-Dichlorophenol ND ug/kg 05/05/15 12:13 120-83-205/04/15 10:254401
Diethylphthalate ND ug/kg 05/05/15 12:13 84-66-205/04/15 10:254401
2,4-Dimethylphenol ND ug/kg 05/05/15 12:13 105-67-905/04/15 10:254401
Dimethylphthalate ND ug/kg 05/05/15 12:13 131-11-305/04/15 10:254401
Di-n-butylphthalate ND ug/kg 05/05/15 12:13 84-74-205/04/15 10:254401
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC3-DOWNSTREAM OF
PROJECT AREA
Lab ID:92247219006 Collected:04/24/15 11:28 Received:04/27/15 15:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
4,6-Dinitro-2-methylphenol ND ug/kg 05/05/15 12:13 534-52-105/04/15 10:258801
2,4-Dinitrophenol ND ug/kg 05/05/15 12:13 51-28-505/04/15 10:2522001
2,4-Dinitrotoluene ND ug/kg 05/05/15 12:13 121-14-205/04/15 10:254401
2,6-Dinitrotoluene ND ug/kg 05/05/15 12:13 606-20-205/04/15 10:254401
Di-n-octylphthalate ND ug/kg 05/05/15 12:13 117-84-005/04/15 10:254401
bis(2-Ethylhexyl)phthalate ND ug/kg 05/05/15 12:13 117-81-705/04/15 10:254401
Fluoranthene ND ug/kg 05/05/15 12:13 206-44-005/04/15 10:254401
Fluorene ND ug/kg 05/05/15 12:13 86-73-705/04/15 10:254401
Hexachloro-1,3-butadiene ND ug/kg 05/05/15 12:13 87-68-305/04/15 10:254401
Hexachlorobenzene ND ug/kg 05/05/15 12:13 118-74-105/04/15 10:254401
Hexachlorocyclopentadiene ND ug/kg 05/05/15 12:13 77-47-405/04/15 10:254401
Hexachloroethane ND ug/kg 05/05/15 12:13 67-72-105/04/15 10:254401
Indeno(1,2,3-cd)pyrene ND ug/kg 05/05/15 12:13 193-39-505/04/15 10:254401
Isophorone ND ug/kg 05/05/15 12:13 78-59-105/04/15 10:254401
1-Methylnaphthalene ND ug/kg 05/05/15 12:13 90-12-005/04/15 10:254401
2-Methylnaphthalene ND ug/kg 05/05/15 12:13 91-57-605/04/15 10:254401
2-Methylphenol(o-Cresol)ND ug/kg 05/05/15 12:13 95-48-705/04/15 10:254401
3&4-Methylphenol(m&p Cresol)ND ug/kg 05/05/15 12:1305/04/15 10:254401
Naphthalene ND ug/kg 05/05/15 12:13 91-20-305/04/15 10:254401
2-Nitroaniline ND ug/kg 05/05/15 12:13 88-74-4 L305/04/15 10:2522001
3-Nitroaniline ND ug/kg 05/05/15 12:13 99-09-205/04/15 10:2522001
4-Nitroaniline ND ug/kg 05/05/15 12:13 100-01-6 L305/04/15 10:258801
Nitrobenzene ND ug/kg 05/05/15 12:13 98-95-305/04/15 10:254401
2-Nitrophenol ND ug/kg 05/05/15 12:13 88-75-505/04/15 10:254401
4-Nitrophenol ND ug/kg 05/05/15 12:13 100-02-705/04/15 10:2522001
N-Nitrosodimethylamine ND ug/kg 05/05/15 12:13 62-75-905/04/15 10:254401
N-Nitroso-di-n-propylamine ND ug/kg 05/05/15 12:13 621-64-705/04/15 10:254401
N-Nitrosodiphenylamine ND ug/kg 05/05/15 12:13 86-30-605/04/15 10:254401
Pentachlorophenol ND ug/kg 05/05/15 12:13 87-86-505/04/15 10:2522001
Phenanthrene ND ug/kg 05/05/15 12:13 85-01-805/04/15 10:254401
Phenol ND ug/kg 05/05/15 12:13 108-95-205/04/15 10:254401
Pyrene ND ug/kg 05/05/15 12:13 129-00-005/04/15 10:254401
1,2,4-Trichlorobenzene ND ug/kg 05/05/15 12:13 120-82-105/04/15 10:254401
2,4,5-Trichlorophenol ND ug/kg 05/05/15 12:13 95-95-405/04/15 10:254401
2,4,6-Trichlorophenol ND ug/kg 05/05/15 12:13 88-06-205/04/15 10:254401
Surrogates
Nitrobenzene-d5 (S)73 %05/05/15 12:13 4165-60-005/04/15 10:2523-110 1
2-Fluorobiphenyl (S)70 %05/05/15 12:13 321-60-805/04/15 10:2530-110 1
Terphenyl-d14 (S)68 %05/05/15 12:13 1718-51-005/04/15 10:2528-110 1
Phenol-d6 (S)77 %05/05/15 12:13 13127-88-305/04/15 10:2522-110 1
2-Fluorophenol (S)57 %05/05/15 12:13 367-12-405/04/15 10:2513-110 1
2,4,6-Tribromophenol (S)67 %05/05/15 12:13 118-79-605/04/15 10:2527-110 1
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone ND ug/kg 04/30/15 00:31 67-64-1 M11091
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC3-DOWNSTREAM OF
PROJECT AREA
Lab ID:92247219006 Collected:04/24/15 11:28 Received:04/27/15 15:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260/5035A Volatile Organics
Benzene ND ug/kg 04/30/15 00:31 71-43-25.5 1
Bromobenzene ND ug/kg 04/30/15 00:31 108-86-1 M15.5 1
Bromochloromethane ND ug/kg 04/30/15 00:31 74-97-55.5 1
Bromodichloromethane ND ug/kg 04/30/15 00:31 75-27-4 M15.5 1
Bromoform ND ug/kg 04/30/15 00:31 75-25-25.5 1
Bromomethane ND ug/kg 04/30/15 00:31 74-83-910.9 1
2-Butanone (MEK)ND ug/kg 04/30/15 00:31 78-93-3 M11091
n-Butylbenzene ND ug/kg 04/30/15 00:31 104-51-8 M15.5 1
sec-Butylbenzene ND ug/kg 04/30/15 00:31 135-98-8 M15.5 1
tert-Butylbenzene ND ug/kg 04/30/15 00:31 98-06-6 M15.5 1
Carbon tetrachloride ND ug/kg 04/30/15 00:31 56-23-5 M15.5 1
Chlorobenzene ND ug/kg 04/30/15 00:31 108-90-75.5 1
Chloroethane ND ug/kg 04/30/15 00:31 75-00-3 M110.9 1
Chloroform ND ug/kg 04/30/15 00:31 67-66-3 M15.5 1
Chloromethane ND ug/kg 04/30/15 00:31 74-87-3 M110.9 1
2-Chlorotoluene ND ug/kg 04/30/15 00:31 95-49-8 M15.5 1
4-Chlorotoluene ND ug/kg 04/30/15 00:31 106-43-4 M15.5 1
1,2-Dibromo-3-chloropropane ND ug/kg 04/30/15 00:31 96-12-85.5 1
Dibromochloromethane ND ug/kg 04/30/15 00:31 124-48-1 M15.5 1
1,2-Dibromoethane (EDB)ND ug/kg 04/30/15 00:31 106-93-45.5 1
Dibromomethane ND ug/kg 04/30/15 00:31 74-95-35.5 1
1,2-Dichlorobenzene ND ug/kg 04/30/15 00:31 95-50-1 M15.5 1
1,3-Dichlorobenzene ND ug/kg 04/30/15 00:31 541-73-1 M15.5 1
1,4-Dichlorobenzene ND ug/kg 04/30/15 00:31 106-46-7 M15.5 1
Dichlorodifluoromethane ND ug/kg 04/30/15 00:31 75-71-8 M110.9 1
1,1-Dichloroethane ND ug/kg 04/30/15 00:31 75-34-3 M15.5 1
1,2-Dichloroethane ND ug/kg 04/30/15 00:31 107-06-25.5 1
1,1-Dichloroethene ND ug/kg 04/30/15 00:31 75-35-4 M15.5 1
cis-1,2-Dichloroethene ND ug/kg 04/30/15 00:31 156-59-2 M15.5 1
trans-1,2-Dichloroethene ND ug/kg 04/30/15 00:31 156-60-5 M15.5 1
1,2-Dichloropropane ND ug/kg 04/30/15 00:31 78-87-5 M15.5 1
1,3-Dichloropropane ND ug/kg 04/30/15 00:31 142-28-95.5 1
2,2-Dichloropropane ND ug/kg 04/30/15 00:31 594-20-7 M15.5 1
1,1-Dichloropropene ND ug/kg 04/30/15 00:31 563-58-6 M15.5 1
cis-1,3-Dichloropropene ND ug/kg 04/30/15 00:31 10061-01-5 M15.5 1
trans-1,3-Dichloropropene ND ug/kg 04/30/15 00:31 10061-02-65.5 1
Diisopropyl ether ND ug/kg 04/30/15 00:31 108-20-35.5 1
Ethylbenzene ND ug/kg 04/30/15 00:31 100-41-4 M15.5 1
Hexachloro-1,3-butadiene ND ug/kg 04/30/15 00:31 87-68-3 M15.5 1
2-Hexanone ND ug/kg 04/30/15 00:31 591-78-6 M154.6 1
Isopropylbenzene (Cumene)ND ug/kg 04/30/15 00:31 98-82-8 M15.5 1
p-Isopropyltoluene ND ug/kg 04/30/15 00:31 99-87-6 M15.5 1
Methylene Chloride ND ug/kg 04/30/15 00:31 75-09-221.8 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 04/30/15 00:31 108-10-154.6 1
Methyl-tert-butyl ether ND ug/kg 04/30/15 00:31 1634-04-45.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 71
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Sample:CC3-DOWNSTREAM OF
PROJECT AREA
Lab ID:92247219006 Collected:04/24/15 11:28 Received:04/27/15 15:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260/5035A Volatile Organics
Naphthalene ND ug/kg 04/30/15 00:31 91-20-35.5 1
n-Propylbenzene ND ug/kg 04/30/15 00:31 103-65-1 M15.5 1
Styrene ND ug/kg 04/30/15 00:31 100-42-5 M15.5 1
1,1,1,2-Tetrachloroethane ND ug/kg 04/30/15 00:31 630-20-6 M15.5 1
1,1,2,2-Tetrachloroethane ND ug/kg 04/30/15 00:31 79-34-55.5 1
Tetrachloroethene 6.9 ug/kg 04/30/15 00:31 127-18-4 M15.5 1
Toluene ND ug/kg 04/30/15 00:31 108-88-3 M15.5 1
1,2,3-Trichlorobenzene ND ug/kg 04/30/15 00:31 87-61-6 M15.5 1
1,2,4-Trichlorobenzene ND ug/kg 04/30/15 00:31 120-82-1 M15.5 1
1,1,1-Trichloroethane ND ug/kg 04/30/15 00:31 71-55-6 M15.5 1
1,1,2-Trichloroethane ND ug/kg 04/30/15 00:31 79-00-55.5 1
Trichloroethene ND ug/kg 04/30/15 00:31 79-01-6 M15.5 1
Trichlorofluoromethane ND ug/kg 04/30/15 00:31 75-69-4 M15.5 1
1,2,3-Trichloropropane ND ug/kg 04/30/15 00:31 96-18-45.5 1
1,2,4-Trimethylbenzene ND ug/kg 04/30/15 00:31 95-63-6 M15.5 1
1,3,5-Trimethylbenzene ND ug/kg 04/30/15 00:31 108-67-8 M15.5 1
Vinyl acetate ND ug/kg 04/30/15 00:31 108-05-4 L354.6 1
Vinyl chloride ND ug/kg 04/30/15 00:31 75-01-4 M110.9 1
Xylene (Total)ND ug/kg 04/30/15 00:31 1330-20-7 MS10.9 1
m&p-Xylene ND ug/kg 04/30/15 00:31 179601-23-1 M110.9 1
o-Xylene ND ug/kg 04/30/15 00:31 95-47-6 M15.5 1
Surrogates
Toluene-d8 (S)103 %04/30/15 00:31 2037-26-570-130 1
4-Bromofluorobenzene (S)99 %04/30/15 00:31 460-00-470-130 1
1,2-Dichloroethane-d4 (S)127 %04/30/15 00:31 17060-07-070-132 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 25.0 %04/29/15 13:100.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/7784
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92247219001, 92247219002, 92247219003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1447141
Associated Lab Samples:92247219001, 92247219002, 92247219003
Matrix:Water
Analyzed
Mercury ug/L ND 0.20 05/01/15 12:07
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1447142LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1447143MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92247303001
1447144
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Mercury ug/L 2.5 100 75-125101 02.5ND 2.5 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/7782
EPA 7471
EPA 7471
7471 Mercury
Associated Lab Samples:92247219004, 92247219005, 92247219006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1445816
Associated Lab Samples:92247219004, 92247219005, 92247219006
Matrix:Solid
Analyzed
Mercury mg/kg ND 0.0050 04/29/15 13:53
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1445817LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/kg 0.067.067 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1445818MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92247219004
1445819
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Mercury mg/kg .062 97 75-12598 0.062ND 0.061 0.062
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/18380
EPA 3050
EPA 6010
6010 MET
Associated Lab Samples:92247219004, 92247219005, 92247219006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1446990
Associated Lab Samples:92247219004, 92247219005, 92247219006
Matrix:Solid
Analyzed
Arsenic mg/kg ND 1.0 05/01/15 01:31
Barium mg/kg ND 0.50 05/01/15 01:31
Cadmium mg/kg ND 0.10 05/01/15 01:31
Chromium mg/kg ND 0.50 05/01/15 01:31
Lead mg/kg ND 0.50 05/01/15 01:31
Selenium mg/kg ND 1.0 05/01/15 01:31
Silver mg/kg ND 0.50 05/01/15 01:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1446991LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic mg/kg 48.250 96 80-120
Barium mg/kg 49.350 99 80-120
Cadmium mg/kg 49.850 100 80-120
Chromium mg/kg 49.550 99 80-120
Lead mg/kg 48.650 97 80-120
Selenium mg/kg 48.550 97 80-120
Silver mg/kg 24.625 98 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1446992MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92247132002
1446993
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Arsenic mg/kg 36.8 94 75-12596 534.2ND 34.6 33.0
Barium mg/kg 36.8 96 75-12599 534.2ND 35.4 33.8
Cadmium mg/kg 36.8 97 75-125100 534.2ND 35.8 34.1
Chromium mg/kg 36.8 97 75-12599 534.2ND 35.6 33.9
Lead mg/kg 36.8 94 75-12596 534.2ND 34.6 32.9
Selenium mg/kg 36.8 95 75-12597 534.2ND 34.9 33.3
Silver mg/kg 18.4 96 75-12598 517.1ND 17.7 16.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/18370
EPA 3010
EPA 6010
6010 MET
Associated Lab Samples:92247219001, 92247219002, 92247219003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1446188
Associated Lab Samples:92247219001, 92247219002, 92247219003
Matrix:Water
Analyzed
Arsenic ug/L ND 10.0 04/30/15 16:58
Barium ug/L ND 5.0 04/30/15 16:58
Cadmium ug/L ND 1.0 04/30/15 16:58
Chromium ug/L ND 5.0 04/30/15 16:58
Lead ug/L ND 5.0 04/30/15 16:58
Selenium ug/L ND 10.0 04/30/15 16:58
Silver ug/L ND 5.0 04/30/15 16:58
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1446189LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic ug/L 456500 91 80-120
Barium ug/L 456500 91 80-120
Cadmium ug/L 463500 93 80-120
Chromium ug/L 448500 90 80-120
Lead ug/L 469500 94 80-120
Selenium ug/L 462500 92 80-120
Silver ug/L 230250 92 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1446190MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92246727006
1446191
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Arsenic ug/L 500 96 75-12589 7500ND481448
Barium ug/L 500 99 75-12590 950049.4 543 499
Cadmium ug/L 500 98 75-12590 8500ND489451
Chromium ug/L 500 96 75-12589 750024.4 506 470
Lead ug/L 500 96 75-12588 8500ND481444
Selenium ug/L 500 97 75-12589 9500ND484444
Silver ug/L 250 98 75-12590 8250ND247227
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/31459
EPA 8260
EPA 8260
8260 MSV Low Level
Associated Lab Samples:92247219001, 92247219002, 92247219003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1447823
Associated Lab Samples:92247219001, 92247219002, 92247219003
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 1.0 05/01/15 15:29
1,1,1-Trichloroethane ug/L ND 1.0 05/01/15 15:29
1,1,2,2-Tetrachloroethane ug/L ND 1.0 05/01/15 15:29
1,1,2-Trichloroethane ug/L ND 1.0 05/01/15 15:29
1,1-Dichloroethane ug/L ND 1.0 05/01/15 15:29
1,1-Dichloroethene ug/L ND 1.0 05/01/15 15:29
1,1-Dichloropropene ug/L ND 1.0 05/01/15 15:29
1,2,3-Trichlorobenzene ug/L ND 1.0 05/01/15 15:29
1,2,3-Trichloropropane ug/L ND 1.0 05/01/15 15:29
1,2,4-Trichlorobenzene ug/L ND 1.0 05/01/15 15:29
1,2-Dibromo-3-chloropropane ug/L ND 2.0 05/01/15 15:29
1,2-Dibromoethane (EDB)ug/L ND 1.0 05/01/15 15:29
1,2-Dichlorobenzene ug/L ND 1.0 05/01/15 15:29
1,2-Dichloroethane ug/L ND 1.0 05/01/15 15:29
1,2-Dichloropropane ug/L ND 1.0 05/01/15 15:29
1,3-Dichlorobenzene ug/L ND 1.0 05/01/15 15:29
1,3-Dichloropropane ug/L ND 1.0 05/01/15 15:29
1,4-Dichlorobenzene ug/L ND 1.0 05/01/15 15:29
2,2-Dichloropropane ug/L ND 1.0 05/01/15 15:29
2-Butanone (MEK)ug/L ND 5.0 05/01/15 15:29
2-Chlorotoluene ug/L ND 1.0 05/01/15 15:29
2-Hexanone ug/L ND 5.0 05/01/15 15:29
4-Chlorotoluene ug/L ND 1.0 05/01/15 15:29
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 05/01/15 15:29
Acetone ug/L ND 25.0 05/01/15 15:29
Benzene ug/L ND 1.0 05/01/15 15:29
Bromobenzene ug/L ND 1.0 05/01/15 15:29
Bromochloromethane ug/L ND 1.0 05/01/15 15:29
Bromodichloromethane ug/L ND 1.0 05/01/15 15:29
Bromoform ug/L ND 1.0 05/01/15 15:29
Bromomethane ug/L ND 2.0 05/01/15 15:29
Carbon tetrachloride ug/L ND 1.0 05/01/15 15:29
Chlorobenzene ug/L ND 1.0 05/01/15 15:29
Chloroethane ug/L ND 1.0 05/01/15 15:29
Chloroform ug/L ND 1.0 05/01/15 15:29
Chloromethane ug/L ND 1.0 05/01/15 15:29
cis-1,2-Dichloroethene ug/L ND 1.0 05/01/15 15:29
cis-1,3-Dichloropropene ug/L ND 1.0 05/01/15 15:29
Dibromochloromethane ug/L ND 1.0 05/01/15 15:29
Dibromomethane ug/L ND 1.0 05/01/15 15:29
Dichlorodifluoromethane ug/L ND 1.0 05/01/15 15:29
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1447823
Associated Lab Samples:92247219001, 92247219002, 92247219003
Matrix:Water
Analyzed
Diisopropyl ether ug/L ND 1.0 05/01/15 15:29
Ethylbenzene ug/L ND 1.0 05/01/15 15:29
Hexachloro-1,3-butadiene ug/L ND 1.0 05/01/15 15:29
m&p-Xylene ug/L ND 2.0 05/01/15 15:29
Methyl-tert-butyl ether ug/L ND 1.0 05/01/15 15:29
Methylene Chloride ug/L ND 2.0 05/01/15 15:29
Naphthalene ug/L ND 1.0 05/01/15 15:29
o-Xylene ug/L ND 1.0 05/01/15 15:29
p-Isopropyltoluene ug/L ND 1.0 05/01/15 15:29
Styrene ug/L ND 1.0 05/01/15 15:29
Tetrachloroethene ug/L ND 1.0 05/01/15 15:29
Toluene ug/L ND 1.0 05/01/15 15:29
trans-1,2-Dichloroethene ug/L ND 1.0 05/01/15 15:29
trans-1,3-Dichloropropene ug/L ND 1.0 05/01/15 15:29
Trichloroethene ug/L ND 1.0 05/01/15 15:29
Trichlorofluoromethane ug/L ND 1.0 05/01/15 15:29
Vinyl acetate ug/L ND 2.0 05/01/15 15:29
Vinyl chloride ug/L ND 1.0 05/01/15 15:29
Xylene (Total)ug/L ND 2.0 05/01/15 15:29
1,2-Dichloroethane-d4 (S)%107 70-130 05/01/15 15:29
4-Bromofluorobenzene (S)%95 70-130 05/01/15 15:29
Toluene-d8 (S)%98 70-130 05/01/15 15:29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1447824LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 53.350 107 70-130
1,1,1-Trichloroethane ug/L 49.050 98 70-130
1,1,2,2-Tetrachloroethane ug/L 54.550 109 70-130
1,1,2-Trichloroethane ug/L 49.550 99 70-130
1,1-Dichloroethane ug/L 50.550 101 70-130
1,1-Dichloroethene ug/L 46.150 92 70-132
1,1-Dichloropropene ug/L 55.350 111 70-130
1,2,3-Trichlorobenzene ug/L 58.550 117 70-135
1,2,3-Trichloropropane ug/L 55.850 112 70-130
1,2,4-Trichlorobenzene ug/L 58.650 117 70-134
1,2-Dibromo-3-chloropropane ug/L 60.250 120 70-130
1,2-Dibromoethane (EDB)ug/L 56.850 114 70-130
1,2-Dichlorobenzene ug/L 56.950 114 70-130
1,2-Dichloroethane ug/L 48.250 96 70-130
1,2-Dichloropropane ug/L 50.050 100 70-130
1,3-Dichlorobenzene ug/L 57.050 114 70-130
1,3-Dichloropropane ug/L 55.950 112 70-130
1,4-Dichlorobenzene ug/L 55.350 111 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1447824LABORATORY CONTROL SAMPLE:
LCSSpike
2,2-Dichloropropane ug/L 52.450 105 58-145
2-Butanone (MEK)ug/L 108100 108 70-145
2-Chlorotoluene ug/L 58.250 116 70-130
2-Hexanone ug/L 125100 125 70-144
4-Chlorotoluene ug/L 57.950 116 70-130
4-Methyl-2-pentanone (MIBK)ug/L 105100 105 70-140
Acetone ug/L 104100 104 50-175
Benzene ug/L 50.050 100 70-130
Bromobenzene ug/L 59.550 119 70-130
Bromochloromethane ug/L 57.750 115 70-130
Bromodichloromethane ug/L 44.550 89 70-130
Bromoform ug/L 44.550 89 70-130
Bromomethane ug/L 49.850 100 54-130
Carbon tetrachloride ug/L 48.850 98 70-132
Chlorobenzene ug/L 51.750 103 70-130
Chloroethane ug/L 44.450 89 64-134
Chloroform ug/L 46.850 94 70-130
Chloromethane ug/L 45.350 91 64-130
cis-1,2-Dichloroethene ug/L 52.150 104 70-131
cis-1,3-Dichloropropene ug/L 52.250 104 70-130
Dibromochloromethane ug/L 50.050 100 70-130
Dibromomethane ug/L 45.750 91 70-131
Dichlorodifluoromethane ug/L 40.550 81 56-130
Diisopropyl ether ug/L 54.650 109 70-130
Ethylbenzene ug/L 53.450 107 70-130
Hexachloro-1,3-butadiene ug/L 55.550 111 70-130
m&p-Xylene ug/L 110100 110 70-130
Methyl-tert-butyl ether ug/L 50.050 100 70-130
Methylene Chloride ug/L 54.550 109 63-130
Naphthalene ug/L 62.750 125 70-138
o-Xylene ug/L 54.450 109 70-130
p-Isopropyltoluene ug/L 58.350 117 70-130
Styrene ug/L 55.950 112 70-130
Tetrachloroethene ug/L 50.450 101 70-130
Toluene ug/L 47.450 95 70-130
trans-1,2-Dichloroethene ug/L 48.950 98 70-130
trans-1,3-Dichloropropene ug/L 50.750 101 70-132
Trichloroethene ug/L 46.750 93 70-130
Trichlorofluoromethane ug/L 42.350 85 62-133
Vinyl acetate ug/L 117100 117 66-157
Vinyl chloride ug/L 48.250 96 50-150
Xylene (Total)ug/L 164150 109 70-130
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%92 70-130
Toluene-d8 (S)%98 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1447825MATRIX SPIKE SAMPLE:
MSSpike
Result
92247428006
1,1,1,2-Tetrachloroethane ug/L 18.420 92 70-130ND
1,1,1-Trichloroethane ug/L 19.920 99 70-130ND
1,1,2,2-Tetrachloroethane ug/L 17.520 88 70-130ND
1,1,2-Trichloroethane ug/L 17.020 85 70-130ND
1,1-Dichloroethane ug/L 19.020 95 70-130ND
1,1-Dichloroethene ug/L 19.120 96 70-166ND
1,1-Dichloropropene ug/L 21.520 107 70-130ND
1,2,3-Trichlorobenzene ug/L 17.120 86 70-130ND
1,2,3-Trichloropropane ug/L 17.820 89 70-130ND
1,2,4-Trichlorobenzene ug/L 17.720 88 70-130ND
1,2-Dibromo-3-chloropropane ug/L 17.320 86 70-130ND
1,2-Dibromoethane (EDB)ug/L 18.520 92 70-130ND
1,2-Dichlorobenzene ug/L 18.020 90 70-130ND
1,2-Dichloroethane ug/L 17.820 89 70-130ND
1,2-Dichloropropane ug/L 17.920 90 70-130ND
1,3-Dichlorobenzene ug/L 18.320 92 70-130ND
1,3-Dichloropropane ug/L 17.720 88 70-130ND
1,4-Dichlorobenzene ug/L 18.220 91 70-130ND
2,2-Dichloropropane ug/L 18.420 92 70-130ND
2-Butanone (MEK)ug/L 33.140 83 70-130ND
2-Chlorotoluene ug/L 18.520 92 70-130ND
2-Hexanone ug/L 34.440 86 70-130ND
4-Chlorotoluene ug/L 18.720 94 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 33.040 83 70-130ND
Acetone ug/L 32.940 82 70-130ND
Benzene ug/L 18.820 94 70-148ND
Bromobenzene ug/L 18.020 90 70-130ND
Bromochloromethane ug/L 20.520 103 70-130ND
Bromodichloromethane ug/L 16.120 81 70-130ND
Bromoform ug/L 15.220 76 70-130ND
Bromomethane ug/L 12.7 M1206470-130ND
Carbon tetrachloride ug/L 19.820 99 70-130ND
Chlorobenzene ug/L 18.620 93 70-146ND
Chloroethane ug/L 24.520 123 70-130ND
Chloroform ug/L 20.520 86 70-1303.2
Chloromethane ug/L 23.620 118 70-130ND
cis-1,2-Dichloroethene ug/L 19.420 97 70-130ND
cis-1,3-Dichloropropene ug/L 17.120 85 70-130ND
Dibromochloromethane ug/L 16.220 81 70-130ND
Dibromomethane ug/L 16.820 84 70-130ND
Dichlorodifluoromethane ug/L 43.5 M12021870-130ND
Diisopropyl ether ug/L 18.120 91 70-130ND
Ethylbenzene ug/L 19.420 97 70-130ND
Hexachloro-1,3-butadiene ug/L 21.920 109 70-130ND
m&p-Xylene ug/L 40.040 100 70-130ND
Methyl-tert-butyl ether ug/L 17.720 88 70-130ND
Methylene Chloride ug/L 18.920 95 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1447825MATRIX SPIKE SAMPLE:
MSSpike
Result
92247428006
Naphthalene ug/L 17.920 89 70-130ND
o-Xylene ug/L 19.320 97 70-130ND
p-Isopropyltoluene ug/L 19.520 98 70-130ND
Styrene ug/L 19.120 95 70-130ND
Tetrachloroethene ug/L 19.120 95 70-130ND
Toluene ug/L 18.020 90 70-155ND
trans-1,2-Dichloroethene ug/L 18.220 91 70-130ND
trans-1,3-Dichloropropene ug/L 16.820 84 70-130ND
Trichloroethene ug/L 18.820 94 69-151ND
Trichlorofluoromethane ug/L 22.520 113 70-130ND
Vinyl acetate ug/L 37.640 94 70-130ND
Vinyl chloride ug/L 24.820 124 70-130ND
1,2-Dichloroethane-d4 (S)%101 70-130
4-Bromofluorobenzene (S)%108 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
Dup
Result QualifiersRPDResult
92247436002
1447826SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L NDND
1,1,1-Trichloroethane ug/L NDND
1,1,2,2-Tetrachloroethane ug/L NDND
1,1,2-Trichloroethane ug/L NDND
1,1-Dichloroethane ug/L NDND
1,1-Dichloroethene ug/L NDND
1,1-Dichloropropene ug/L NDND
1,2,3-Trichlorobenzene ug/L NDND
1,2,3-Trichloropropane ug/L NDND
1,2,4-Trichlorobenzene ug/L NDND
1,2-Dibromo-3-chloropropane ug/L NDND
1,2-Dibromoethane (EDB)ug/L NDND
1,2-Dichlorobenzene ug/L NDND
1,2-Dichloroethane ug/L NDND
1,2-Dichloropropane ug/L NDND
1,3-Dichlorobenzene ug/L NDND
1,3-Dichloropropane ug/L NDND
1,4-Dichlorobenzene ug/L NDND
2,2-Dichloropropane ug/L NDND
2-Butanone (MEK)ug/L NDND
2-Chlorotoluene ug/L NDND
2-Hexanone ug/L NDND
4-Chlorotoluene ug/L NDND
4-Methyl-2-pentanone (MIBK)ug/L NDND
Acetone ug/L NDND
Benzene ug/L NDND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
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[phone]
Page 37 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result QualifiersRPDResult
92247436002
1447826SAMPLE DUPLICATE:
Bromobenzene ug/L NDND
Bromochloromethane ug/L NDND
Bromodichloromethane ug/L NDND
Bromoform ug/L NDND
Bromomethane ug/L NDND
Carbon tetrachloride ug/L NDND
Chlorobenzene ug/L NDND
Chloroethane ug/L NDND
Chloroform ug/L NDND
Chloromethane ug/L NDND
cis-1,2-Dichloroethene ug/L NDND
cis-1,3-Dichloropropene ug/L NDND
Dibromochloromethane ug/L NDND
Dibromomethane ug/L NDND
Dichlorodifluoromethane ug/L NDND
Diisopropyl ether ug/L NDND
Ethylbenzene ug/L NDND
Hexachloro-1,3-butadiene ug/L NDND
m&p-Xylene ug/L NDND
Methyl-tert-butyl ether ug/L NDND
Methylene Chloride ug/L NDND
Naphthalene ug/L NDND
o-Xylene ug/L NDND
p-Isopropyltoluene ug/L NDND
Styrene ug/L NDND
Tetrachloroethene ug/L NDND
Toluene ug/L NDND
trans-1,2-Dichloroethene ug/L NDND
trans-1,3-Dichloropropene ug/L NDND
Trichloroethene ug/L NDND
Trichlorofluoromethane ug/L NDND
Vinyl acetate ug/L NDND
Vinyl chloride ug/L NDND
Xylene (Total)ug/L NDND
1,2-Dichloroethane-d4 (S)%102 6109
4-Bromofluorobenzene (S)%109 999
Toluene-d8 (S)%100 0101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 38 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/31430
EPA 8260
EPA 8260
8260 MSV 5035A Volatile Organics
Associated Lab Samples:92247219004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1445879
Associated Lab Samples:92247219004
Matrix:Solid
Analyzed
1,1,1,2-Tetrachloroethane ug/kg ND 4.2 04/29/15 17:14
1,1,1-Trichloroethane ug/kg ND 4.2 04/29/15 17:14
1,1,2,2-Tetrachloroethane ug/kg ND 4.2 04/29/15 17:14
1,1,2-Trichloroethane ug/kg ND 4.2 04/29/15 17:14
1,1-Dichloroethane ug/kg ND 4.2 04/29/15 17:14
1,1-Dichloroethene ug/kg ND 4.2 04/29/15 17:14
1,1-Dichloropropene ug/kg ND 4.2 04/29/15 17:14
1,2,3-Trichlorobenzene ug/kg ND 4.2 04/29/15 17:14
1,2,3-Trichloropropane ug/kg ND 4.2 04/29/15 17:14
1,2,4-Trichlorobenzene ug/kg ND 4.2 04/29/15 17:14
1,2,4-Trimethylbenzene ug/kg ND 4.2 04/29/15 17:14
1,2-Dibromo-3-chloropropane ug/kg ND 4.2 04/29/15 17:14
1,2-Dibromoethane (EDB)ug/kg ND 4.2 04/29/15 17:14
1,2-Dichlorobenzene ug/kg ND 4.2 04/29/15 17:14
1,2-Dichloroethane ug/kg ND 4.2 04/29/15 17:14
1,2-Dichloropropane ug/kg ND 4.2 04/29/15 17:14
1,3,5-Trimethylbenzene ug/kg ND 4.2 04/29/15 17:14
1,3-Dichlorobenzene ug/kg ND 4.2 04/29/15 17:14
1,3-Dichloropropane ug/kg ND 4.2 04/29/15 17:14
1,4-Dichlorobenzene ug/kg ND 4.2 04/29/15 17:14
2,2-Dichloropropane ug/kg ND 4.2 04/29/15 17:14
2-Butanone (MEK)ug/kg ND 83.2 04/29/15 17:14
2-Chlorotoluene ug/kg ND 4.2 04/29/15 17:14
2-Hexanone ug/kg ND 41.6 04/29/15 17:14
4-Chlorotoluene ug/kg ND 4.2 04/29/15 17:14
4-Methyl-2-pentanone (MIBK)ug/kg ND 41.6 04/29/15 17:14
Acetone ug/kg ND 83.2 04/29/15 17:14
Benzene ug/kg ND 4.2 04/29/15 17:14
Bromobenzene ug/kg ND 4.2 04/29/15 17:14
Bromochloromethane ug/kg ND 4.2 04/29/15 17:14
Bromodichloromethane ug/kg ND 4.2 04/29/15 17:14
Bromoform ug/kg ND 4.2 04/29/15 17:14
Bromomethane ug/kg ND 8.3 04/29/15 17:14
Carbon tetrachloride ug/kg ND 4.2 04/29/15 17:14
Chlorobenzene ug/kg ND 4.2 04/29/15 17:14
Chloroethane ug/kg ND 8.3 04/29/15 17:14
Chloroform ug/kg ND 4.2 04/29/15 17:14
Chloromethane ug/kg ND 8.3 04/29/15 17:14
cis-1,2-Dichloroethene ug/kg ND 4.2 04/29/15 17:14
cis-1,3-Dichloropropene ug/kg ND 4.2 04/29/15 17:14
Dibromochloromethane ug/kg ND 4.2 04/29/15 17:14
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
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Huntersville, NC 28078
[phone]
Page 39 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1445879
Associated Lab Samples:92247219004
Matrix:Solid
Analyzed
Dibromomethane ug/kg ND 4.2 04/29/15 17:14
Dichlorodifluoromethane ug/kg ND 8.3 04/29/15 17:14
Diisopropyl ether ug/kg ND 4.2 04/29/15 17:14
Ethylbenzene ug/kg ND 4.2 04/29/15 17:14
Hexachloro-1,3-butadiene ug/kg ND 4.2 04/29/15 17:14
Isopropylbenzene (Cumene)ug/kg ND 4.2 04/29/15 17:14
m&p-Xylene ug/kg ND 8.3 04/29/15 17:14
Methyl-tert-butyl ether ug/kg ND 4.2 04/29/15 17:14
Methylene Chloride ug/kg ND 16.6 04/29/15 17:14
n-Butylbenzene ug/kg ND 4.2 04/29/15 17:14
n-Propylbenzene ug/kg ND 4.2 04/29/15 17:14
Naphthalene ug/kg ND 4.2 04/29/15 17:14
o-Xylene ug/kg ND 4.2 04/29/15 17:14
p-Isopropyltoluene ug/kg ND 4.2 04/29/15 17:14
sec-Butylbenzene ug/kg ND 4.2 04/29/15 17:14
Styrene ug/kg ND 4.2 04/29/15 17:14
tert-Butylbenzene ug/kg ND 4.2 04/29/15 17:14
Tetrachloroethene ug/kg ND 4.2 04/29/15 17:14
Toluene ug/kg ND 4.2 04/29/15 17:14
trans-1,2-Dichloroethene ug/kg ND 4.2 04/29/15 17:14
trans-1,3-Dichloropropene ug/kg ND 4.2 04/29/15 17:14
Trichloroethene ug/kg ND 4.2 04/29/15 17:14
Trichlorofluoromethane ug/kg ND 4.2 04/29/15 17:14
Vinyl acetate ug/kg ND 41.6 04/29/15 17:14
Vinyl chloride ug/kg ND 8.3 04/29/15 17:14
Xylene (Total)ug/kg ND 8.3 04/29/15 17:14
1,2-Dichloroethane-d4 (S)%110 70-132 04/29/15 17:14
4-Bromofluorobenzene (S)%94 70-130 04/29/15 17:14
Toluene-d8 (S)%101 70-130 04/29/15 17:14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1445880LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 38.641.7 93 74-137
1,1,1-Trichloroethane ug/kg 38.741.7 93 67-140
1,1,2,2-Tetrachloroethane ug/kg 32.641.7 78 72-141
1,1,2-Trichloroethane ug/kg 39.941.7 96 78-138
1,1-Dichloroethane ug/kg 37.541.7 90 69-134
1,1-Dichloroethene ug/kg 37.141.7 89 67-138
1,1-Dichloropropene ug/kg 43.841.7 105 69-139
1,2,3-Trichlorobenzene ug/kg 39.841.7 95 70-146
1,2,3-Trichloropropane ug/kg 38.641.7 93 69-144
1,2,4-Trichlorobenzene ug/kg 40.141.7 96 68-148
1,2,4-Trimethylbenzene ug/kg 39.241.7 94 74-137
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1445880LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dibromo-3-chloropropane ug/kg 38.041.7 91 65-140
1,2-Dibromoethane (EDB)ug/kg 39.141.7 94 77-135
1,2-Dichlorobenzene ug/kg 38.741.7 93 77-141
1,2-Dichloroethane ug/kg 37.441.7 90 65-137
1,2-Dichloropropane ug/kg 39.441.7 95 72-136
1,3,5-Trimethylbenzene ug/kg 39.541.7 95 76-133
1,3-Dichlorobenzene ug/kg 37.741.7 91 74-138
1,3-Dichloropropane ug/kg 41.241.7 99 71-139
1,4-Dichlorobenzene ug/kg 38.041.7 91 76-138
2,2-Dichloropropane ug/kg 38.541.7 92 68-137
2-Butanone (MEK)ug/kg 76.7J83.3 92 58-147
2-Chlorotoluene ug/kg 37.341.7 90 73-139
2-Hexanone ug/kg 83.983.3 101 62-145
4-Chlorotoluene ug/kg 37.741.7 91 76-141
4-Methyl-2-pentanone (MIBK)ug/kg 81.483.3 98 64-149
Acetone ug/kg 66.3J83.3 80 53-153
Benzene ug/kg 39.441.7 95 73-135
Bromobenzene ug/kg 39.041.7 94 75-133
Bromochloromethane ug/kg 39.841.7 95 73-134
Bromodichloromethane ug/kg 35.341.7 85 71-135
Bromoform ug/kg 36.241.7 87 66-141
Bromomethane ug/kg 43.741.7 105 53-160
Carbon tetrachloride ug/kg 38.741.7 93 60-145
Chlorobenzene ug/kg 39.441.7 94 78-130
Chloroethane ug/kg 36.741.7 88 64-149
Chloroform ug/kg 35.041.7 84 70-134
Chloromethane ug/kg 39.141.7 94 52-150
cis-1,2-Dichloroethene ug/kg 39.441.7 95 70-133
cis-1,3-Dichloropropene ug/kg 41.641.7 100 68-134
Dibromochloromethane ug/kg 36.441.7 87 71-138
Dibromomethane ug/kg 38.541.7 92 74-130
Dichlorodifluoromethane ug/kg 32.341.7 78 40-160
Diisopropyl ether ug/kg 37.241.7 89 69-141
Ethylbenzene ug/kg 40.141.7 96 75-133
Hexachloro-1,3-butadiene ug/kg 38.341.7 92 68-143
Isopropylbenzene (Cumene)ug/kg 41.841.7 100 76-143
m&p-Xylene ug/kg 75.583.3 91 75-136
Methyl-tert-butyl ether ug/kg 37.641.7 90 68-144
Methylene Chloride ug/kg 40.541.7 97 45-154
n-Butylbenzene ug/kg 39.541.7 95 72-137
n-Propylbenzene ug/kg 39.141.7 94 76-136
Naphthalene ug/kg 42.741.7 103 68-151
o-Xylene ug/kg 38.941.7 93 76-141
p-Isopropyltoluene ug/kg 38.841.7 93 76-140
sec-Butylbenzene ug/kg 41.241.7 99 79-139
Styrene ug/kg 40.741.7 98 79-137
tert-Butylbenzene ug/kg 38.341.7 92 74-143
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1445880LABORATORY CONTROL SAMPLE:
LCSSpike
Tetrachloroethene ug/kg 38.741.7 93 71-138
Toluene ug/kg 38.641.7 93 74-131
trans-1,2-Dichloroethene ug/kg 37.241.7 89 67-135
trans-1,3-Dichloropropene ug/kg 41.141.7 99 65-146
Trichloroethene ug/kg 41.241.7 99 67-135
Trichlorofluoromethane ug/kg 37.141.7 89 59-144
Vinyl acetate ug/kg 11683.3 140 40-160
Vinyl chloride ug/kg 36.141.7 87 56-141
Xylene (Total)ug/kg 114125 92 76-137
1,2-Dichloroethane-d4 (S)%97 70-132
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1446956MATRIX SPIKE SAMPLE:
MSSpike
Result
92247219004
1,1,1,2-Tetrachloroethane ug/kg 21.121.1 100 70-130ND
1,1,1-Trichloroethane ug/kg 21.621.1 103 70-130ND
1,1,2,2-Tetrachloroethane ug/kg 23.721.1 113 70-130ND
1,1,2-Trichloroethane ug/kg 26.121.1 124 70-130ND
1,1-Dichloroethane ug/kg 22.621.1 107 70-130ND
1,1-Dichloroethene ug/kg 20.621.1 98 49-180ND
1,1-Dichloropropene ug/kg 24.321.1 115 70-130ND
1,2,3-Trichlorobenzene ug/kg 17.121.1 81 70-130ND
1,2,3-Trichloropropane ug/kg 27.8 M121.1 132 70-130ND
1,2,4-Trichlorobenzene ug/kg 16.821.1 80 70-130ND
1,2,4-Trimethylbenzene ug/kg 19.721.1 93 70-130ND
1,2-Dibromo-3-chloropropane ug/kg 23.921.1 114 70-130ND
1,2-Dibromoethane (EDB)ug/kg 25.321.1 121 70-130ND
1,2-Dichlorobenzene ug/kg 20.221.1 96 70-130ND
1,2-Dichloroethane ug/kg 25.521.1 121 70-130ND
1,2-Dichloropropane ug/kg 24.121.1 115 70-130ND
1,3,5-Trimethylbenzene ug/kg 20.021.1 95 70-130ND
1,3-Dichlorobenzene ug/kg 18.921.1 90 70-130ND
1,3-Dichloropropane ug/kg 24.721.1 117 70-130ND
1,4-Dichlorobenzene ug/kg 18.621.1 88 70-130ND
2,2-Dichloropropane ug/kg 20.621.1 98 70-130ND
2-Butanone (MEK)ug/kg 61.2J M14214670-130ND
2-Chlorotoluene ug/kg 21.521.1 103 70-130ND
2-Hexanone ug/kg 86.3 M14220570-130ND
4-Chlorotoluene ug/kg 19.821.1 94 70-130ND
4-Methyl-2-pentanone (MIBK)ug/kg 63.5 M14215170-130ND
Acetone ug/kg 83.8J42 115 70-130ND
Benzene ug/kg 22.521.1 107 50-166ND
Bromobenzene ug/kg 21.921.1 104 70-130ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 42 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1446956MATRIX SPIKE SAMPLE:
MSSpike
Result
92247219004
Bromochloromethane ug/kg 23.421.1 111 70-130ND
Bromodichloromethane ug/kg 20.621.1 98 70-130ND
Bromoform ug/kg 22.921.1 109 70-130ND
Bromomethane ug/kg 28.0 M121.1 133 70-130ND
Carbon tetrachloride ug/kg 20.621.1 98 70-130ND
Chlorobenzene ug/kg 20.921.1 99 43-169ND
Chloroethane ug/kg 24.721.1 118 70-130ND
Chloroform ug/kg 20.621.1 98 70-130ND
Chloromethane ug/kg 22.521.1 107 70-130ND
cis-1,2-Dichloroethene ug/kg 26.821.1 111 70-130ND
cis-1,3-Dichloropropene ug/kg 23.821.1 113 70-130ND
Dibromochloromethane ug/kg 21.921.1 104 70-130ND
Dibromomethane ug/kg 24.421.1 116 70-130ND
Dichlorodifluoromethane ug/kg 19.921.1 95 70-130ND
Diisopropyl ether ug/kg 24.921.1 119 70-130ND
Ethylbenzene ug/kg 21.021.1 100 70-130ND
Hexachloro-1,3-butadiene ug/kg 14.721.1 70 70-130ND
Isopropylbenzene (Cumene)ug/kg 21.521.1 102 70-130ND
m&p-Xylene ug/kg 39.642 94 70-130ND
Methyl-tert-butyl ether ug/kg 26.621.1 127 70-130ND
Methylene Chloride ug/kg 25.321.1 120 70-130ND
n-Butylbenzene ug/kg 18.121.1 86 70-130ND
n-Propylbenzene ug/kg 20.521.1 97 70-130ND
Naphthalene ug/kg 25.521.1 117 70-130ND
o-Xylene ug/kg 21.321.1 101 70-130ND
p-Isopropyltoluene ug/kg 19.021.1 90 70-130ND
sec-Butylbenzene ug/kg 20.621.1 98 70-130ND
Styrene ug/kg 19.021.1 90 70-130ND
tert-Butylbenzene ug/kg 19.521.1 93 70-130ND
Tetrachloroethene ug/kg 23.221.1 83 70-1305.8
Toluene ug/kg 21.821.1 104 52-163ND
trans-1,2-Dichloroethene ug/kg 21.421.1 102 70-130ND
trans-1,3-Dichloropropene ug/kg 25.221.1 120 70-130ND
Trichloroethene ug/kg 21.821.1 97 49-167ND
Trichlorofluoromethane ug/kg 21.021.1 100 70-130ND
Vinyl acetate ug/kg 70.3 M14216770-130ND
Vinyl chloride ug/kg 22.221.1 105 70-130ND
1,2-Dichloroethane-d4 (S)%114 70-132
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%102 70-130
Parameter Units
Dup
Result QualifiersRPDResult
92247190005
1446955SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/kg NDND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
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Page 43 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result QualifiersRPDResult
92247190005
1446955SAMPLE DUPLICATE:
1,1,1-Trichloroethane ug/kg NDND
1,1,2,2-Tetrachloroethane ug/kg NDND
1,1,2-Trichloroethane ug/kg NDND
1,1-Dichloroethane ug/kg NDND
1,1-Dichloroethene ug/kg NDND
1,1-Dichloropropene ug/kg NDND
1,2,3-Trichlorobenzene ug/kg NDND
1,2,3-Trichloropropane ug/kg NDND
1,2,4-Trichlorobenzene ug/kg NDND
1,2,4-Trimethylbenzene ug/kg 24.2 D6320.017 mg/kg
1,2-Dibromo-3-chloropropane ug/kg NDND
1,2-Dibromoethane (EDB)ug/kg NDND
1,2-Dichlorobenzene ug/kg NDND
1,2-Dichloroethane ug/kg NDND
1,2-Dichloropropane ug/kg NDND
1,3,5-Trimethylbenzene ug/kg 7.5 D6310.0055 mg/kg
1,3-Dichlorobenzene ug/kg NDND
1,3-Dichloropropane ug/kg NDND
1,4-Dichlorobenzene ug/kg NDND
2,2-Dichloropropane ug/kg NDND
2-Butanone (MEK)ug/kg NDND
2-Chlorotoluene ug/kg NDND
2-Hexanone ug/kg NDND
4-Chlorotoluene ug/kg NDND
4-Methyl-2-pentanone (MIBK)ug/kg NDND
Acetone ug/kg 27.6JND
Benzene ug/kg NDND
Bromobenzene ug/kg NDND
Bromochloromethane ug/kg NDND
Bromodichloromethane ug/kg NDND
Bromoform ug/kg NDND
Bromomethane ug/kg NDND
Carbon tetrachloride ug/kg NDND
Chlorobenzene ug/kg NDND
Chloroethane ug/kg NDND
Chloroform ug/kg NDND
Chloromethane ug/kg NDND
cis-1,2-Dichloroethene ug/kg NDND
cis-1,3-Dichloropropene ug/kg NDND
Dibromochloromethane ug/kg NDND
Dibromomethane ug/kg NDND
Dichlorodifluoromethane ug/kg NDND
Diisopropyl ether ug/kg NDND
Ethylbenzene ug/kg 4.2JND
Hexachloro-1,3-butadiene ug/kg NDND
Isopropylbenzene (Cumene)ug/kg 2.8JND
m&p-Xylene ug/kg 11.3JND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 44 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result QualifiersRPDResult
92247190005
1446955SAMPLE DUPLICATE:
Methyl-tert-butyl ether ug/kg NDND
Methylene Chloride ug/kg NDND
n-Butylbenzene ug/kg 3.1JND
n-Propylbenzene ug/kg 4.4JND
Naphthalene ug/kg 32.8 D6560.018 mg/kg
o-Xylene ug/kg 8.1 200.0066 mg/kg
p-Isopropyltoluene ug/kg 7.4 300.0055 mg/kg
sec-Butylbenzene ug/kg 3.8JND
Styrene ug/kg NDND
tert-Butylbenzene ug/kg NDND
Tetrachloroethene ug/kg NDND
Toluene ug/kg NDND
trans-1,2-Dichloroethene ug/kg NDND
trans-1,3-Dichloropropene ug/kg NDND
Trichloroethene ug/kg NDND
Trichlorofluoromethane ug/kg NDND
Vinyl acetate ug/kg NDND
Vinyl chloride ug/kg NDND
Xylene (Total)ug/kg 8.1JND
1,2-Dichloroethane-d4 (S)%127 30113
4-Bromofluorobenzene (S)%98 1899
Toluene-d8 (S)%102 17104
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/31431
EPA 8260
EPA 8260
8260 MSV 5035A Volatile Organics
Associated Lab Samples:92247219005, 92247219006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1445885
Associated Lab Samples:92247219005, 92247219006
Matrix:Solid
Analyzed
1,1,1,2-Tetrachloroethane ug/kg ND 3.7 04/29/15 16:54
1,1,1-Trichloroethane ug/kg ND 3.7 04/29/15 16:54
1,1,2,2-Tetrachloroethane ug/kg ND 3.7 04/29/15 16:54
1,1,2-Trichloroethane ug/kg ND 3.7 04/29/15 16:54
1,1-Dichloroethane ug/kg ND 3.7 04/29/15 16:54
1,1-Dichloroethene ug/kg ND 3.7 04/29/15 16:54
1,1-Dichloropropene ug/kg ND 3.7 04/29/15 16:54
1,2,3-Trichlorobenzene ug/kg ND 3.7 04/29/15 16:54
1,2,3-Trichloropropane ug/kg ND 3.7 04/29/15 16:54
1,2,4-Trichlorobenzene ug/kg ND 3.7 04/29/15 16:54
1,2,4-Trimethylbenzene ug/kg ND 3.7 04/29/15 16:54
1,2-Dibromo-3-chloropropane ug/kg ND 3.7 04/29/15 16:54
1,2-Dibromoethane (EDB)ug/kg ND 3.7 04/29/15 16:54
1,2-Dichlorobenzene ug/kg ND 3.7 04/29/15 16:54
1,2-Dichloroethane ug/kg ND 3.7 04/29/15 16:54
1,2-Dichloropropane ug/kg ND 3.7 04/29/15 16:54
1,3,5-Trimethylbenzene ug/kg ND 3.7 04/29/15 16:54
1,3-Dichlorobenzene ug/kg ND 3.7 04/29/15 16:54
1,3-Dichloropropane ug/kg ND 3.7 04/29/15 16:54
1,4-Dichlorobenzene ug/kg ND 3.7 04/29/15 16:54
2,2-Dichloropropane ug/kg ND 3.7 04/29/15 16:54
2-Butanone (MEK)ug/kg ND 73.7 04/29/15 16:54
2-Chlorotoluene ug/kg ND 3.7 04/29/15 16:54
2-Hexanone ug/kg ND 36.9 04/29/15 16:54
4-Chlorotoluene ug/kg ND 3.7 04/29/15 16:54
4-Methyl-2-pentanone (MIBK)ug/kg ND 36.9 04/29/15 16:54
Acetone ug/kg ND 73.7 04/29/15 16:54
Benzene ug/kg ND 3.7 04/29/15 16:54
Bromobenzene ug/kg ND 3.7 04/29/15 16:54
Bromochloromethane ug/kg ND 3.7 04/29/15 16:54
Bromodichloromethane ug/kg ND 3.7 04/29/15 16:54
Bromoform ug/kg ND 3.7 04/29/15 16:54
Bromomethane ug/kg ND 7.4 04/29/15 16:54
Carbon tetrachloride ug/kg ND 3.7 04/29/15 16:54
Chlorobenzene ug/kg ND 3.7 04/29/15 16:54
Chloroethane ug/kg ND 7.4 04/29/15 16:54
Chloroform ug/kg ND 3.7 04/29/15 16:54
Chloromethane ug/kg ND 7.4 04/29/15 16:54
cis-1,2-Dichloroethene ug/kg ND 3.7 04/29/15 16:54
cis-1,3-Dichloropropene ug/kg ND 3.7 04/29/15 16:54
Dibromochloromethane ug/kg ND 3.7 04/29/15 16:54
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
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[phone]
Page 46 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1445885
Associated Lab Samples:92247219005, 92247219006
Matrix:Solid
Analyzed
Dibromomethane ug/kg ND 3.7 04/29/15 16:54
Dichlorodifluoromethane ug/kg ND 7.4 04/29/15 16:54
Diisopropyl ether ug/kg ND 3.7 04/29/15 16:54
Ethylbenzene ug/kg ND 3.7 04/29/15 16:54
Hexachloro-1,3-butadiene ug/kg ND 3.7 04/29/15 16:54
Isopropylbenzene (Cumene)ug/kg ND 3.7 04/29/15 16:54
m&p-Xylene ug/kg ND 7.4 04/29/15 16:54
Methyl-tert-butyl ether ug/kg ND 3.7 04/29/15 16:54
Methylene Chloride ug/kg ND 14.7 04/29/15 16:54
n-Butylbenzene ug/kg ND 3.7 04/29/15 16:54
n-Propylbenzene ug/kg ND 3.7 04/29/15 16:54
Naphthalene ug/kg ND 3.7 04/29/15 16:54
o-Xylene ug/kg ND 3.7 04/29/15 16:54
p-Isopropyltoluene ug/kg ND 3.7 04/29/15 16:54
sec-Butylbenzene ug/kg ND 3.7 04/29/15 16:54
Styrene ug/kg ND 3.7 04/29/15 16:54
tert-Butylbenzene ug/kg ND 3.7 04/29/15 16:54
Tetrachloroethene ug/kg ND 3.7 04/29/15 16:54
Toluene ug/kg ND 3.7 04/29/15 16:54
trans-1,2-Dichloroethene ug/kg ND 3.7 04/29/15 16:54
trans-1,3-Dichloropropene ug/kg ND 3.7 04/29/15 16:54
Trichloroethene ug/kg ND 3.7 04/29/15 16:54
Trichlorofluoromethane ug/kg ND 3.7 04/29/15 16:54
Vinyl acetate ug/kg ND 36.9 04/29/15 16:54
Vinyl chloride ug/kg ND 7.4 04/29/15 16:54
Xylene (Total)ug/kg ND 7.4 04/29/15 16:54
1,2-Dichloroethane-d4 (S)%106 70-132 04/29/15 16:54
4-Bromofluorobenzene (S)%97 70-130 04/29/15 16:54
Toluene-d8 (S)%102 70-130 04/29/15 16:54
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1445886LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 40.642.4 96 74-137
1,1,1-Trichloroethane ug/kg 42.042.4 99 67-140
1,1,2,2-Tetrachloroethane ug/kg 37.842.4 89 72-141
1,1,2-Trichloroethane ug/kg 41.942.4 99 78-138
1,1-Dichloroethane ug/kg 42.042.4 99 69-134
1,1-Dichloroethene ug/kg 40.642.4 96 67-138
1,1-Dichloropropene ug/kg 47.942.4 113 69-139
1,2,3-Trichlorobenzene ug/kg 43.542.4 103 70-146
1,2,3-Trichloropropane ug/kg 43.842.4 103 69-144
1,2,4-Trichlorobenzene ug/kg 43.742.4 103 68-148
1,2,4-Trimethylbenzene ug/kg 43.442.4 102 74-137
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1445886LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dibromo-3-chloropropane ug/kg 42.742.4 101 65-140
1,2-Dibromoethane (EDB)ug/kg 42.342.4 100 77-135
1,2-Dichlorobenzene ug/kg 42.742.4 101 77-141
1,2-Dichloroethane ug/kg 41.842.4 98 65-137
1,2-Dichloropropane ug/kg 43.442.4 102 72-136
1,3,5-Trimethylbenzene ug/kg 43.842.4 103 76-133
1,3-Dichlorobenzene ug/kg 42.242.4 99 74-138
1,3-Dichloropropane ug/kg 43.342.4 102 71-139
1,4-Dichlorobenzene ug/kg 42.842.4 101 76-138
2,2-Dichloropropane ug/kg 43.642.4 103 68-137
2-Butanone (MEK)ug/kg 80.6J84.9 95 58-147
2-Chlorotoluene ug/kg 41.242.4 97 73-139
2-Hexanone ug/kg 88.184.9 104 62-145
4-Chlorotoluene ug/kg 42.442.4 100 76-141
4-Methyl-2-pentanone (MIBK)ug/kg 87.684.9 103 64-149
Acetone ug/kg 70.3J84.9 83 53-153
Benzene ug/kg 42.842.4 101 73-135
Bromobenzene ug/kg 42.842.4 101 75-133
Bromochloromethane ug/kg 43.342.4 102 73-134
Bromodichloromethane ug/kg 38.342.4 90 71-135
Bromoform ug/kg 39.942.4 94 66-141
Bromomethane ug/kg 45.142.4 106 53-160
Carbon tetrachloride ug/kg 42.742.4 101 60-145
Chlorobenzene ug/kg 41.942.4 99 78-130
Chloroethane ug/kg 43.442.4 102 64-149
Chloroform ug/kg 39.142.4 92 70-134
Chloromethane ug/kg 43.542.4 103 52-150
cis-1,2-Dichloroethene ug/kg 42.642.4 100 70-133
cis-1,3-Dichloropropene ug/kg 45.442.4 107 68-134
Dibromochloromethane ug/kg 40.142.4 95 71-138
Dibromomethane ug/kg 42.442.4 100 74-130
Dichlorodifluoromethane ug/kg 39.142.4 92 40-160
Diisopropyl ether ug/kg 40.842.4 96 69-141
Ethylbenzene ug/kg 42.642.4 100 75-133
Hexachloro-1,3-butadiene ug/kg 42.942.4 101 68-143
Isopropylbenzene (Cumene)ug/kg 44.642.4 105 76-143
m&p-Xylene ug/kg 81.384.9 96 75-136
Methyl-tert-butyl ether ug/kg 41.242.4 97 68-144
Methylene Chloride ug/kg 45.442.4 107 45-154
n-Butylbenzene ug/kg 43.842.4 103 72-137
n-Propylbenzene ug/kg 43.742.4 103 76-136
Naphthalene ug/kg 45.642.4 107 68-151
o-Xylene ug/kg 42.442.4 100 76-141
p-Isopropyltoluene ug/kg 43.442.4 102 76-140
sec-Butylbenzene ug/kg 46.242.4 109 79-139
Styrene ug/kg 44.142.4 104 79-137
tert-Butylbenzene ug/kg 42.642.4 100 74-143
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 48 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1445886LABORATORY CONTROL SAMPLE:
LCSSpike
Tetrachloroethene ug/kg 41.842.4 99 71-138
Toluene ug/kg 41.842.4 98 74-131
trans-1,2-Dichloroethene ug/kg 41.342.4 97 67-135
trans-1,3-Dichloropropene ug/kg 44.842.4 106 65-146
Trichloroethene ug/kg 43.642.4 103 67-135
Trichlorofluoromethane ug/kg 42.542.4 100 59-144
Vinyl acetate ug/kg 161 L084.9 189 40-160
Vinyl chloride ug/kg 41.542.4 98 56-141
Xylene (Total)ug/kg 124127 97 76-137
1,2-Dichloroethane-d4 (S)%98 70-132
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1446964MATRIX SPIKE SAMPLE:
MSSpike
Result
92247219006
1,1,1,2-Tetrachloroethane ug/kg 11.4 M120.5 56 70-130ND
1,1,1-Trichloroethane ug/kg 10.3 M120.5 50 70-130ND
1,1,2,2-Tetrachloroethane ug/kg 17.520.5 85 70-130ND
1,1,2-Trichloroethane ug/kg 17.920.5 87 70-130ND
1,1-Dichloroethane ug/kg 12.2 M120.5 60 70-130ND
1,1-Dichloroethene ug/kg 9.5 M120.5 46 49-180ND
1,1-Dichloropropene ug/kg 10.5 M120.5 51 70-130ND
1,2,3-Trichlorobenzene ug/kg 9.4 M120.5 45 70-130ND
1,2,3-Trichloropropane ug/kg 23.220.5 113 70-130ND
1,2,4-Trichlorobenzene ug/kg 8.6 M120.5 42 70-130ND
1,2,4-Trimethylbenzene ug/kg 9.0 M120.5 44 70-130ND
1,2-Dibromo-3-chloropropane ug/kg 20.420.5 99 70-130ND
1,2-Dibromoethane (EDB)ug/kg 16.920.5 82 70-130ND
1,2-Dichlorobenzene ug/kg 11.7 M120.5 57 70-130ND
1,2-Dichloroethane ug/kg 16.520.5 80 70-130ND
1,2-Dichloropropane ug/kg 13.5 M120.5 66 70-130ND
1,3,5-Trimethylbenzene ug/kg 8.5 M120.5 42 70-130ND
1,3-Dichlorobenzene ug/kg 9.6 M120.5 47 70-130ND
1,3-Dichloropropane ug/kg 16.420.5 80 70-130ND
1,4-Dichlorobenzene ug/kg 10.1 M120.5 49 70-130ND
2,2-Dichloropropane ug/kg 9.5 M120.5 46 70-130ND
2-Butanone (MEK)ug/kg 56.1J M141.1 137 70-130ND
2-Chlorotoluene ug/kg 10.3 M120.5 50 70-130ND
2-Hexanone ug/kg 58.5 M141.1 142 70-130ND
4-Chlorotoluene ug/kg 9.4 M120.5 46 70-130ND
4-Methyl-2-pentanone (MIBK)ug/kg 49.7J41.1 121 70-130ND
Acetone ug/kg 82.1J M141.1 145 70-130ND
Benzene ug/kg 11.320.5 55 50-166ND
Bromobenzene ug/kg 12.0 M120.5 59 70-130ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
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Huntersville, NC 28078
[phone]
Page 49 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1446964MATRIX SPIKE SAMPLE:
MSSpike
Result
92247219006
Bromochloromethane ug/kg 16.020.5 78 70-130ND
Bromodichloromethane ug/kg 12.5 M120.5 61 70-130ND
Bromoform ug/kg 15.420.5 75 70-130ND
Bromomethane ug/kg 14.320.5 70 70-130ND
Carbon tetrachloride ug/kg 8.8 M120.5 43 70-130ND
Chlorobenzene ug/kg 10.620.5 52 43-169ND
Chloroethane ug/kg 12.1 M120.5 59 70-130ND
Chloroform ug/kg 11.7 M120.5 57 70-130ND
Chloromethane ug/kg 11.7 M120.5 57 70-130ND
cis-1,2-Dichloroethene ug/kg 13.4 M120.5 63 70-130ND
cis-1,3-Dichloropropene ug/kg 14.0 M120.5 68 70-130ND
Dibromochloromethane ug/kg 14.1 M120.5 69 70-130ND
Dibromomethane ug/kg 17.320.5 84 70-130ND
Dichlorodifluoromethane ug/kg 8.6J M120.5 42 70-130ND
Diisopropyl ether ug/kg 14.820.5 72 70-130ND
Ethylbenzene ug/kg 9.8 M120.5 48 70-130ND
Hexachloro-1,3-butadiene ug/kg 6.9 M120.5 33 70-130ND
Isopropylbenzene (Cumene)ug/kg 9.4 M120.5 46 70-130ND
m&p-Xylene ug/kg 18.2 M141.1 44 70-130ND
Methyl-tert-butyl ether ug/kg 20.220.5 99 70-130ND
Methylene Chloride ug/kg 15.3J20.5 74 70-130ND
n-Butylbenzene ug/kg 8.0 M120.5 39 70-130ND
n-Propylbenzene ug/kg 8.7 M120.5 43 70-130ND
Naphthalene ug/kg 15.720.5 75 70-130ND
o-Xylene ug/kg 9.8 M120.5 48 70-130ND
p-Isopropyltoluene ug/kg 7.9 M120.5 38 70-130ND
sec-Butylbenzene ug/kg 9.2 M120.5 45 70-130ND
Styrene ug/kg 8.9 M120.5 43 70-130ND
tert-Butylbenzene ug/kg 8.5 M120.5 41 70-130ND
Tetrachloroethene ug/kg 11.2 M120.5 21 70-1306.9
Toluene ug/kg 10.5 M120.5 51 52-163ND
trans-1,2-Dichloroethene ug/kg 10.5 M120.5 51 70-130ND
trans-1,3-Dichloropropene ug/kg 15.720.5 76 70-130ND
Trichloroethene ug/kg 9.8 M120.5 47 49-167ND
Trichlorofluoromethane ug/kg 9.6 M120.5 47 70-130ND
Vinyl acetate ug/kg 50.6J41.1 123 70-130ND
Vinyl chloride ug/kg 9.6J M120.5 47 70-130ND
1,2-Dichloroethane-d4 (S)%132 70-132
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
Dup
Result QualifiersRPDResult
92247164032
1446963SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/kg NDND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
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Huntersville, NC 28078
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Page 50 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result QualifiersRPDResult
92247164032
1446963SAMPLE DUPLICATE:
1,1,1-Trichloroethane ug/kg NDND
1,1,2,2-Tetrachloroethane ug/kg NDND
1,1,2-Trichloroethane ug/kg NDND
1,1-Dichloroethane ug/kg NDND
1,1-Dichloroethene ug/kg NDND
1,1-Dichloropropene ug/kg NDND
1,2,3-Trichlorobenzene ug/kg NDND
1,2,3-Trichloropropane ug/kg NDND
1,2,4-Trichlorobenzene ug/kg NDND
1,2,4-Trimethylbenzene ug/kg NDND
1,2-Dibromo-3-chloropropane ug/kg NDND
1,2-Dibromoethane (EDB)ug/kg NDND
1,2-Dichlorobenzene ug/kg NDND
1,2-Dichloroethane ug/kg NDND
1,2-Dichloropropane ug/kg NDND
1,3,5-Trimethylbenzene ug/kg NDND
1,3-Dichlorobenzene ug/kg NDND
1,3-Dichloropropane ug/kg NDND
1,4-Dichlorobenzene ug/kg NDND
2,2-Dichloropropane ug/kg NDND
2-Butanone (MEK)ug/kg NDND
2-Chlorotoluene ug/kg NDND
2-Hexanone ug/kg NDND
4-Chlorotoluene ug/kg NDND
4-Methyl-2-pentanone (MIBK)ug/kg NDND
Acetone ug/kg 23.9J16.8J
Benzene ug/kg NDND
Bromobenzene ug/kg NDND
Bromochloromethane ug/kg NDND
Bromodichloromethane ug/kg NDND
Bromoform ug/kg NDND
Bromomethane ug/kg NDND
Carbon tetrachloride ug/kg NDND
Chlorobenzene ug/kg NDND
Chloroethane ug/kg NDND
Chloroform ug/kg NDND
Chloromethane ug/kg NDND
cis-1,2-Dichloroethene ug/kg NDND
cis-1,3-Dichloropropene ug/kg NDND
Dibromochloromethane ug/kg NDND
Dibromomethane ug/kg NDND
Dichlorodifluoromethane ug/kg NDND
Diisopropyl ether ug/kg NDND
Ethylbenzene ug/kg NDND
Hexachloro-1,3-butadiene ug/kg NDND
Isopropylbenzene (Cumene)ug/kg NDND
m&p-Xylene ug/kg NDND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 51 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result QualifiersRPDResult
92247164032
1446963SAMPLE DUPLICATE:
Methyl-tert-butyl ether ug/kg NDND
Methylene Chloride ug/kg ND4.5J
n-Butylbenzene ug/kg NDND
n-Propylbenzene ug/kg NDND
Naphthalene ug/kg 1.2JND
o-Xylene ug/kg NDND
p-Isopropyltoluene ug/kg NDND
sec-Butylbenzene ug/kg NDND
Styrene ug/kg NDND
tert-Butylbenzene ug/kg NDND
Tetrachloroethene ug/kg NDND
Toluene ug/kg 2.7J2.5J
trans-1,2-Dichloroethene ug/kg NDND
trans-1,3-Dichloropropene ug/kg NDND
Trichloroethene ug/kg NDND
Trichlorofluoromethane ug/kg NDND
Vinyl acetate ug/kg NDND
Vinyl chloride ug/kg NDND
Xylene (Total)ug/kg NDND
1,2-Dichloroethane-d4 (S)%127 6130
4-Bromofluorobenzene (S)%95 597
Toluene-d8 (S)%101 3100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 52 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/34726
EPA 3546
EPA 8270
8270 Solid MSSV Microwave
Associated Lab Samples:92247219004, 92247219005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1448968
Associated Lab Samples:92247219004, 92247219005
Matrix:Solid
Analyzed
1,2,4-Trichlorobenzene ug/kg ND 330 05/03/15 13:41
1,2-Dichlorobenzene ug/kg ND 330 05/03/15 13:41
1,3-Dichlorobenzene ug/kg ND 330 05/03/15 13:41
1,4-Dichlorobenzene ug/kg ND 330 05/03/15 13:41
1-Methylnaphthalene ug/kg ND 330 05/03/15 13:41
2,4,5-Trichlorophenol ug/kg ND 330 05/03/15 13:41
2,4,6-Trichlorophenol ug/kg ND 330 05/03/15 13:41
2,4-Dichlorophenol ug/kg ND 330 05/03/15 13:41
2,4-Dimethylphenol ug/kg ND 330 05/03/15 13:41
2,4-Dinitrophenol ug/kg ND 1650 05/03/15 13:41
2,4-Dinitrotoluene ug/kg ND 330 05/03/15 13:41
2,6-Dinitrotoluene ug/kg ND 330 05/03/15 13:41
2-Chloronaphthalene ug/kg ND 330 05/03/15 13:41
2-Chlorophenol ug/kg ND 330 05/03/15 13:41
2-Methylnaphthalene ug/kg ND 330 05/03/15 13:41
2-Methylphenol(o-Cresol)ug/kg ND 330 05/03/15 13:41
2-Nitroaniline ug/kg ND 1650 05/03/15 13:41
2-Nitrophenol ug/kg ND 330 05/03/15 13:41
3&4-Methylphenol(m&p Cresol)ug/kg ND 330 05/03/15 13:41
3,3'-Dichlorobenzidine ug/kg ND 1650 05/03/15 13:41
3-Nitroaniline ug/kg ND 1650 05/03/15 13:41
4,6-Dinitro-2-methylphenol ug/kg ND 660 05/03/15 13:41
4-Bromophenylphenyl ether ug/kg ND 330 05/03/15 13:41
4-Chloro-3-methylphenol ug/kg ND 660 05/03/15 13:41
4-Chloroaniline ug/kg ND 1650 05/03/15 13:41
4-Chlorophenylphenyl ether ug/kg ND 330 05/03/15 13:41
4-Nitroaniline ug/kg ND 660 05/03/15 13:41
4-Nitrophenol ug/kg ND 1650 05/03/15 13:41
Acenaphthene ug/kg ND 330 05/03/15 13:41
Acenaphthylene ug/kg ND 330 05/03/15 13:41
Aniline ug/kg ND 330 05/03/15 13:41
Anthracene ug/kg ND 330 05/03/15 13:41
Benzo(a)anthracene ug/kg ND 330 05/03/15 13:41
Benzo(a)pyrene ug/kg ND 330 05/03/15 13:41
Benzo(b)fluoranthene ug/kg ND 330 05/03/15 13:41
Benzo(g,h,i)perylene ug/kg ND 330 05/03/15 13:41
Benzo(k)fluoranthene ug/kg ND 330 05/03/15 13:41
Benzoic Acid ug/kg ND 1650 05/03/15 13:41
Benzyl alcohol ug/kg ND 660 05/03/15 13:41
bis(2-Chloroethoxy)methane ug/kg ND 330 05/03/15 13:41
bis(2-Chloroethyl) ether ug/kg ND 330 05/03/15 13:41
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
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Page 53 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1448968
Associated Lab Samples:92247219004, 92247219005
Matrix:Solid
Analyzed
bis(2-Chloroisopropyl) ether ug/kg ND 330 05/03/15 13:41
bis(2-Ethylhexyl)phthalate ug/kg ND 330 05/03/15 13:41
Butylbenzylphthalate ug/kg ND 330 05/03/15 13:41
Chrysene ug/kg ND 330 05/03/15 13:41
Di-n-butylphthalate ug/kg ND 330 05/03/15 13:41
Di-n-octylphthalate ug/kg ND 330 05/03/15 13:41
Dibenz(a,h)anthracene ug/kg ND 330 05/03/15 13:41
Dibenzofuran ug/kg ND 330 05/03/15 13:41
Diethylphthalate ug/kg ND 330 05/03/15 13:41
Dimethylphthalate ug/kg ND 330 05/03/15 13:41
Fluoranthene ug/kg ND 330 05/03/15 13:41
Fluorene ug/kg ND 330 05/03/15 13:41
Hexachloro-1,3-butadiene ug/kg ND 330 05/03/15 13:41
Hexachlorobenzene ug/kg ND 330 05/03/15 13:41
Hexachlorocyclopentadiene ug/kg ND 330 05/03/15 13:41
Hexachloroethane ug/kg ND 330 05/03/15 13:41
Indeno(1,2,3-cd)pyrene ug/kg ND 330 05/03/15 13:41
Isophorone ug/kg ND 330 05/03/15 13:41
N-Nitroso-di-n-propylamine ug/kg ND 330 05/03/15 13:41
N-Nitrosodimethylamine ug/kg ND 330 05/03/15 13:41
N-Nitrosodiphenylamine ug/kg ND 330 05/03/15 13:41
Naphthalene ug/kg ND 330 05/03/15 13:41
Nitrobenzene ug/kg ND 330 05/03/15 13:41
Pentachlorophenol ug/kg ND 1650 05/03/15 13:41
Phenanthrene ug/kg ND 330 05/03/15 13:41
Phenol ug/kg ND 330 05/03/15 13:41
Pyrene ug/kg ND 330 05/03/15 13:41
2,4,6-Tribromophenol (S)%72 27-110 05/03/15 13:41
2-Fluorobiphenyl (S)%76 30-110 05/03/15 13:41
2-Fluorophenol (S)%74 13-110 05/03/15 13:41
Nitrobenzene-d5 (S)%79 23-110 05/03/15 13:41
Phenol-d6 (S)%86 22-110 05/03/15 13:41
Terphenyl-d14 (S)%82 28-110 05/03/15 13:41
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1448969LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/kg 8221670 49 36-120
1,2-Dichlorobenzene ug/kg 10001670 60 41-120
1,3-Dichlorobenzene ug/kg 923 L016705566-120
1,4-Dichlorobenzene ug/kg 9591670 58 42-120
1-Methylnaphthalene ug/kg 8901670 53 40-120
2,4,5-Trichlorophenol ug/kg 11401670 68 37-120
2,4,6-Trichlorophenol ug/kg 11201670 67 40-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 54 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1448969LABORATORY CONTROL SAMPLE:
LCSSpike
2,4-Dichlorophenol ug/kg 8571670 51 33-120
2,4-Dimethylphenol ug/kg 8611670 52 36-120
2,4-Dinitrophenol ug/kg 61608330 74 22-121
2,4-Dinitrotoluene ug/kg 14301670 86 60-120
2,6-Dinitrotoluene ug/kg 12801670 77 54-120
2-Chloronaphthalene ug/kg 9621670 58 41-120
2-Chlorophenol ug/kg 10301670 62 39-120
2-Methylnaphthalene ug/kg 8141670 49 26-120
2-Methylphenol(o-Cresol)ug/kg 10301670 62 41-120
2-Nitroaniline ug/kg 30503330 91 45-120
2-Nitrophenol ug/kg 7441670 45 35-120
3&4-Methylphenol(m&p Cresol)ug/kg 9681670 58 35-120
3,3'-Dichlorobenzidine ug/kg 22303330 67 16-125
3-Nitroaniline ug/kg 29303330 88 45-120
4,6-Dinitro-2-methylphenol ug/kg 24703330 74 46-120
4-Bromophenylphenyl ether ug/kg 10901670 65 36-120
4-Chloro-3-methylphenol ug/kg 22503330 67 37-120
4-Chloroaniline ug/kg 17503330 52 35-120
4-Chlorophenylphenyl ether ug/kg 12001670 72 30-120
4-Nitroaniline ug/kg 34603330 104 48-120
4-Nitrophenol ug/kg 79608330 96 43-120
Acenaphthene ug/kg 11201670 67 46-120
Acenaphthylene ug/kg 10601670 64 46-120
Aniline ug/kg 8571670 51 33-120
Anthracene ug/kg 12701670 76 63-120
Benzo(a)anthracene ug/kg 11101670 66 61-120
Benzo(a)pyrene ug/kg 11801670 71 59-120
Benzo(b)fluoranthene ug/kg 11701670 70 55-120
Benzo(g,h,i)perylene ug/kg 13301670 80 57-120
Benzo(k)fluoranthene ug/kg 11001670 66 56-120
Benzoic Acid ug/kg 40508330 49 13-120
Benzyl alcohol ug/kg 20203330 61 34-120
bis(2-Chloroethoxy)methane ug/kg 9021670 54 21-120
bis(2-Chloroethyl) ether ug/kg 10801670 65 25-120
bis(2-Chloroisopropyl) ether ug/kg 12301670 74 13-120
bis(2-Ethylhexyl)phthalate ug/kg 12901670 77 56-123
Butylbenzylphthalate ug/kg 12401670 75 57-120
Chrysene ug/kg 11501670 69 64-120
Di-n-butylphthalate ug/kg 15901670 96 58-120
Di-n-octylphthalate ug/kg 13501670 81 47-121
Dibenz(a,h)anthracene ug/kg 13201670 79 56-120
Dibenzofuran ug/kg 12001670 72 43-120
Diethylphthalate ug/kg 15901670 96 55-120
Dimethylphthalate ug/kg 14501670 87 54-120
Fluoranthene ug/kg 13901670 83 61-120
Fluorene ug/kg 12701670 76 51-120
Hexachloro-1,3-butadiene ug/kg 8251670 50 22-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 55 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1448969LABORATORY CONTROL SAMPLE:
LCSSpike
Hexachlorobenzene ug/kg 10401670 62 53-120
Hexachlorocyclopentadiene ug/kg 5011670 30 18-150
Hexachloroethane ug/kg 9741670 58 39-120
Indeno(1,2,3-cd)pyrene ug/kg 13301670 80 58-120
Isophorone ug/kg 9831670 59 38-120
N-Nitroso-di-n-propylamine ug/kg 11301670 68 30-120
N-Nitrosodimethylamine ug/kg 10601670 64 32-120
N-Nitrosodiphenylamine ug/kg 11901670 71 50-120
Naphthalene ug/kg 8441670 51 38-120
Nitrobenzene ug/kg 9301670 56 37-120
Pentachlorophenol ug/kg 19203330 58 10-120
Phenanthrene ug/kg 12701670 76 62-120
Phenol ug/kg 10801670 65 37-120
Pyrene ug/kg 984 L016705963-120
2,4,6-Tribromophenol (S)%72 27-110
2-Fluorobiphenyl (S)%54 30-110
2-Fluorophenol (S)%54 13-110
Nitrobenzene-d5 (S)%50 23-110
Phenol-d6 (S)%65 22-110
Terphenyl-d14 (S)%71 28-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1448970MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92247164036
1448971
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/kg 1740 60 18-11956 61740ND1030973
1,2-Dichlorobenzene ug/kg 1740 66 50-11064 31740ND11401100
1,3-Dichlorobenzene ug/kg 1740 65 27-11062 31740ND11201080
1,4-Dichlorobenzene ug/kg 1740 66 28-11063 41740ND11401100
1-Methylnaphthalene ug/kg 1740 57 24-11659 31740ND9891020
2,4,5-Trichlorophenol ug/kg 1740 74 28-11074 11740ND12901280
2,4,6-Trichlorophenol ug/kg 1740 75 17-11773 21740ND13001270
2,4-Dichlorophenol ug/kg 1740 59 21-12858 01740ND10201020
2,4-Dimethylphenol ug/kg 1740 61 10-12058 51740ND10601010
2,4-Dinitrophenol ug/kg 8680 70 10-10768 38680ND61205910
2,4-Dinitrotoluene ug/kg 1740 80 36-10979 21740ND13901370
2,6-Dinitrotoluene ug/kg 1740 73 32-11074 21740ND12701290
2-Chloronaphthalene ug/kg 1740 67 30-10765 31740ND11601120
2-Chlorophenol ug/kg 1740 67 14-10666 11740ND11601150
2-Methylnaphthalene ug/kg 1740 52 10-13551 21740ND901884
2-Methylphenol(o-Cresol)ug/kg 1740 61 10-12462 31740ND10501080
2-Nitroaniline ug/kg 3470 90 26-11689 13470ND31303110
2-Nitrophenol ug/kg 1740 57 28-10357 01740ND995996
3&4-Methylphenol(m&p
Cresol)ug/kg 1740 55 10-10957 41740ND958999
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 56 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1448970MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92247164036
1448971
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
3,3'-Dichlorobenzidine ug/kg 3470 66 10-15065 03470ND22802270
3-Nitroaniline ug/kg 3470 80 22-11078 23470ND27902730
4,6-Dinitro-2-methylphenol ug/kg 3470 70 13-12166 53470ND24402310
4-Bromophenylphenyl ether ug/kg 1740 62 31-10959 41740ND10701030
4-Chloro-3-methylphenol ug/kg 3470 63 13-12866 43470ND21902280
4-Chloroaniline ug/kg 3470 52 18-10253 23470ND18201860
4-Chlorophenylphenyl ether ug/kg 1740 70 29-11270 01740ND12101210
4-Nitroaniline ug/kg 3470 91 16-11189 23470ND31503080
4-Nitrophenol ug/kg 8680 93 14-13589 48680ND80407720
Acenaphthene ug/kg 1740 72 26-11470 21740ND12501220
Acenaphthylene ug/kg 1740 70 32-10868 31740ND12201180
Aniline ug/kg 1740 56 10-10754 21740ND964943
Anthracene ug/kg 1740 72 32-11169 41740ND12501200
Benzo(a)anthracene ug/kg 1740 61 25-11761 11740ND10701060
Benzo(a)pyrene ug/kg 1740 64 25-10664 01740ND11101110
Benzo(b)fluoranthene ug/kg 1740 59 24-11062 51740ND10201070
Benzo(g,h,i)perylene ug/kg 1740 81 19-11277 61740ND14101330
Benzo(k)fluoranthene ug/kg 1740 62 24-11460 31740ND10801050
Benzoic Acid ug/kg 8680 54 10-11057 58680ND46504910
Benzyl alcohol ug/kg 3470 63 24-10665 43470ND21802260
bis(2-Chloroethoxy)methane ug/kg 1740 65 13-11963 31740ND11301100
bis(2-Chloroethyl) ether ug/kg 1740 76 10-13470 71740ND13201220
bis(2-Chloroisopropyl) ether ug/kg 1740 84 10-11383 11740ND14501440
bis(2-Ethylhexyl)phthalate ug/kg 1740 72 10-12571 21740ND12601240
Butylbenzylphthalate ug/kg 1740 71 18-11069 21740ND12301210
Chrysene ug/kg 1740 65 30-11064 11740ND11201110
Di-n-butylphthalate ug/kg 1740 88 19-11283 61740ND15301450
Di-n-octylphthalate ug/kg 1740 77 17-10575 21740ND13401310
Dibenz(a,h)anthracene ug/kg 1740 80 23-11175 71740ND13901300
Dibenzofuran ug/kg 1740 73 35-10372 21740ND12701250
Diethylphthalate ug/kg 1740 88 27-11387 21740ND15301510
Dimethylphthalate ug/kg 1740 82 26-11180 21740ND14201390
Fluoranthene ug/kg 1740 77 33-10973 51740ND13301270
Fluorene ug/kg 1740 74 32-11373 21740ND12901260
Hexachloro-1,3-butadiene ug/kg 1740 59 16-11658 21740ND10201000
Hexachlorobenzene ug/kg 1740 58 27-12055 51740ND1010956
Hexachlorocyclopentadiene ug/kg 1740 44 10-10839 121740ND758671
Hexachloroethane ug/kg 1740 69 10-11766 41740ND12001140
Indeno(1,2,3-cd)pyrene ug/kg 1740 79 10-12274 71740ND13801280
Isophorone ug/kg 1740 62 28-11464 21740ND10801110
N-Nitroso-di-n-propylamine ug/kg 1740 67 27-11367 01740ND11601160
N-Nitrosodimethylamine ug/kg 1740 72 10-10965 101740ND12501130
N-Nitrosodiphenylamine ug/kg 1740 68 10-12867 21740ND11801160
Naphthalene ug/kg 1740 57 25-11056 31740ND996971
Nitrobenzene ug/kg 1740 67 18-11463 61740ND11701100
Pentachlorophenol ug/kg 3470 59 10-12255 73470ND20501920
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 57 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1448970MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92247164036
1448971
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Phenanthrene ug/kg 1740 72 30-11469 41740ND12401190
Phenol ug/kg 1740 68 11-10269 11740ND11801190
Pyrene ug/kg 1740 53 25-11653 01740ND923922
2,4,6-Tribromophenol (S)%64 27-11062
2-Fluorobiphenyl (S)%64 30-11057
2-Fluorophenol (S)%64 13-11058
Nitrobenzene-d5 (S)%59 23-11053
Phenol-d6 (S)%64 22-11062
Terphenyl-d14 (S)%61 28-11059
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 58 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/34748
EPA 3546
EPA 8270
8270 Solid MSSV Microwave
Associated Lab Samples:92247219006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1449269
Associated Lab Samples:92247219006
Matrix:Solid
Analyzed
1,2,4-Trichlorobenzene ug/kg ND 330 05/05/15 09:57
1,2-Dichlorobenzene ug/kg ND 330 05/05/15 09:57
1,3-Dichlorobenzene ug/kg ND 330 05/05/15 09:57
1,4-Dichlorobenzene ug/kg ND 330 05/05/15 09:57
1-Methylnaphthalene ug/kg ND 330 05/05/15 09:57
2,4,5-Trichlorophenol ug/kg ND 330 05/05/15 09:57
2,4,6-Trichlorophenol ug/kg ND 330 05/05/15 09:57
2,4-Dichlorophenol ug/kg ND 330 05/05/15 09:57
2,4-Dimethylphenol ug/kg ND 330 05/05/15 09:57
2,4-Dinitrophenol ug/kg ND 1650 05/05/15 09:57
2,4-Dinitrotoluene ug/kg ND 330 05/05/15 09:57
2,6-Dinitrotoluene ug/kg ND 330 05/05/15 09:57
2-Chloronaphthalene ug/kg ND 330 05/05/15 09:57
2-Chlorophenol ug/kg ND 330 05/05/15 09:57
2-Methylnaphthalene ug/kg ND 330 05/05/15 09:57
2-Methylphenol(o-Cresol)ug/kg ND 330 05/05/15 09:57
2-Nitroaniline ug/kg ND 1650 05/05/15 09:57
2-Nitrophenol ug/kg ND 330 05/05/15 09:57
3&4-Methylphenol(m&p Cresol)ug/kg ND 330 05/05/15 09:57
3,3'-Dichlorobenzidine ug/kg ND 1650 05/05/15 09:57
3-Nitroaniline ug/kg ND 1650 05/05/15 09:57
4,6-Dinitro-2-methylphenol ug/kg ND 660 05/05/15 09:57
4-Bromophenylphenyl ether ug/kg ND 330 05/05/15 09:57
4-Chloro-3-methylphenol ug/kg ND 660 05/05/15 09:57
4-Chloroaniline ug/kg ND 1650 05/05/15 09:57
4-Chlorophenylphenyl ether ug/kg ND 330 05/05/15 09:57
4-Nitroaniline ug/kg ND 660 05/05/15 09:57
4-Nitrophenol ug/kg ND 1650 05/05/15 09:57
Acenaphthene ug/kg ND 330 05/05/15 09:57
Acenaphthylene ug/kg ND 330 05/05/15 09:57
Aniline ug/kg ND 330 05/05/15 09:57
Anthracene ug/kg ND 330 05/05/15 09:57
Benzo(a)anthracene ug/kg ND 330 05/05/15 09:57
Benzo(a)pyrene ug/kg ND 330 05/05/15 09:57
Benzo(b)fluoranthene ug/kg ND 330 05/05/15 09:57
Benzo(g,h,i)perylene ug/kg ND 330 05/05/15 09:57
Benzo(k)fluoranthene ug/kg ND 330 05/05/15 09:57
Benzoic Acid ug/kg ND 1650 05/05/15 09:57
Benzyl alcohol ug/kg ND 660 05/05/15 09:57
bis(2-Chloroethoxy)methane ug/kg ND 330 05/05/15 09:57
bis(2-Chloroethyl) ether ug/kg ND 330 05/05/15 09:57
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 59 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1449269
Associated Lab Samples:92247219006
Matrix:Solid
Analyzed
bis(2-Chloroisopropyl) ether ug/kg ND 330 05/05/15 09:57
bis(2-Ethylhexyl)phthalate ug/kg ND 330 05/05/15 09:57
Butylbenzylphthalate ug/kg ND 330 05/05/15 09:57
Chrysene ug/kg ND 330 05/05/15 09:57
Di-n-butylphthalate ug/kg ND 330 05/05/15 09:57
Di-n-octylphthalate ug/kg ND 330 05/05/15 09:57
Dibenz(a,h)anthracene ug/kg ND 330 05/05/15 09:57
Dibenzofuran ug/kg ND 330 05/05/15 09:57
Diethylphthalate ug/kg ND 330 05/05/15 09:57
Dimethylphthalate ug/kg ND 330 05/05/15 09:57
Fluoranthene ug/kg ND 330 05/05/15 09:57
Fluorene ug/kg ND 330 05/05/15 09:57
Hexachloro-1,3-butadiene ug/kg ND 330 05/05/15 09:57
Hexachlorobenzene ug/kg ND 330 05/05/15 09:57
Hexachlorocyclopentadiene ug/kg ND 330 05/05/15 09:57
Hexachloroethane ug/kg ND 330 05/05/15 09:57
Indeno(1,2,3-cd)pyrene ug/kg ND 330 05/05/15 09:57
Isophorone ug/kg ND 330 05/05/15 09:57
N-Nitroso-di-n-propylamine ug/kg ND 330 05/05/15 09:57
N-Nitrosodimethylamine ug/kg ND 330 05/05/15 09:57
N-Nitrosodiphenylamine ug/kg ND 330 05/05/15 09:57
Naphthalene ug/kg ND 330 05/05/15 09:57
Nitrobenzene ug/kg ND 330 05/05/15 09:57
Pentachlorophenol ug/kg ND 1650 05/05/15 09:57
Phenanthrene ug/kg ND 330 05/05/15 09:57
Phenol ug/kg ND 330 05/05/15 09:57
Pyrene ug/kg ND 330 05/05/15 09:57
2,4,6-Tribromophenol (S)%79 27-110 05/05/15 09:57
2-Fluorobiphenyl (S)%78 30-110 05/05/15 09:57
2-Fluorophenol (S)%73 13-110 05/05/15 09:57
Nitrobenzene-d5 (S)%80 23-110 05/05/15 09:57
Phenol-d6 (S)%104 22-110 05/05/15 09:57
Terphenyl-d14 (S)%86 28-110 05/05/15 09:57
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1449270LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1449271
1,2,4-Trichlorobenzene ug/kg 11101670 66 36-120651080 2 30
1,2-Dichlorobenzene ug/kg 14801670 89 41-120831380 7 30
1,3-Dichlorobenzene ug/kg 13301670 80 66-120731220 8 30
1,4-Dichlorobenzene ug/kg 13601670 82 42-120791320 3 30
1-Methylnaphthalene ug/kg 12101670 73 40-120691150 5 30
2,4,5-Trichlorophenol ug/kg 15801670 95 37-1201011690 7 30
2,4,6-Trichlorophenol ug/kg 14701670 88 40-1201011690 14 30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 60 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1449270LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1449271
2,4-Dichlorophenol ug/kg 12601670 76 33-120731210 4 30
2,4-Dimethylphenol ug/kg 12501670 75 36-120701170 6 30
2,4-Dinitrophenol ug/kg 77008330 92 22-1211058720 12 30
2,4-Dinitrotoluene ug/kg 16901670 101 60-1201091810 7 30
2,6-Dinitrotoluene ug/kg 15401670 93 54-1201011680 9 30
2-Chloronaphthalene ug/kg 13601670 82 41-120841390 2 30
2-Chlorophenol ug/kg 16201670 97 39-120981640 1 30
2-Methylnaphthalene ug/kg 11101670 67 26-120641070 4 30
2-Methylphenol(o-Cresol)ug/kg 16101670 97 41-120971620 0 30
2-Nitroaniline ug/kg 3630 L0333010945-1201274230 15 30
2-Nitrophenol ug/kg 11601670 70 35-120671110 5 30
3&4-Methylphenol(m&p Cresol)ug/kg 16601670 99 35-120971620 2 30
3,3'-Dichlorobenzidine ug/kg 28103330 84 16-125933090 9 30
3-Nitroaniline ug/kg 34703330 104 45-1201093640 5 30
4,6-Dinitro-2-methylphenol ug/kg 32903330 99 46-1201003340 2 30
4-Bromophenylphenyl ether ug/kg 13601670 82 36-120761270 7 30
4-Chloro-3-methylphenol ug/kg 28403330 85 37-120842810 1 30
4-Chloroaniline ug/kg 23703330 71 35-120732440 3 30
4-Chlorophenylphenyl ether ug/kg 15001670 90 30-120951590 6 30
4-Nitroaniline ug/kg 4010 L0333012048-1201264200 5 30
4-Nitrophenol ug/kg 91908330 110 43-1201199940 8 30
Acenaphthene ug/kg 14501670 87 46-120891480 2 30
Acenaphthylene ug/kg 13401670 80 46-120901490 11 30
Aniline ug/kg 14201670 85 33-120881460 3 30
Anthracene ug/kg 15301670 92 63-120881470 4 30
Benzo(a)anthracene ug/kg 14101670 84 61-120861430 2 30
Benzo(a)pyrene ug/kg 14301670 86 59-120881460 2 30
Benzo(b)fluoranthene ug/kg 14201670 85 55-120871450 2 30
Benzo(g,h,i)perylene ug/kg 15401670 93 57-120931550 1 30
Benzo(k)fluoranthene ug/kg 13601670 81 56-120841390 3 30
Benzoic Acid ug/kg 55508330 67 13-120594930 12 30
Benzyl alcohol ug/kg 34003330 102 34-1201043470 2 30
bis(2-Chloroethoxy)methane ug/kg 13101670 79 21-120711190 10 30
bis(2-Chloroethyl) ether ug/kg 17001670 102 25-120981630 4 30
bis(2-Chloroisopropyl) ether ug/kg 2010 L0167012113-1201051750 14 30
bis(2-Ethylhexyl)phthalate ug/kg 16601670 99 56-1231011690 2 30
Butylbenzylphthalate ug/kg 16501670 99 57-1201061770 7 30
Chrysene ug/kg 14401670 86 64-120871450 1 30
Di-n-butylphthalate ug/kg 18601670 112 58-1201091820 2 30
Di-n-octylphthalate ug/kg 17901670 107 47-1211091810 1 30
Dibenz(a,h)anthracene ug/kg 17201670 103 56-120941570 9 30
Dibenzofuran ug/kg 14901670 90 43-120951580 5 30
Diethylphthalate ug/kg 18301670 110 55-1201161940 6 30
Dimethylphthalate ug/kg 17001670 102 54-1201131890 11 30
Fluoranthene ug/kg 15401670 93 61-120921530 1 30
Fluorene ug/kg 15101670 91 51-120981630 7 30
Hexachloro-1,3-butadiene ug/kg 10301670 62 22-120601000 3 30
REPORT OF LABORATORY ANALYSIS
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Page 61 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1449270LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1449271
Hexachlorobenzene ug/kg 12101670 73 53-120731210 0 30
Hexachlorocyclopentadiene ug/kg 8321670 50 18-150621030 21 30
Hexachloroethane ug/kg 14301670 86 39-120771280 11 30
Indeno(1,2,3-cd)pyrene ug/kg 17101670 103 58-120931550 10 30
Isophorone ug/kg 13501670 81 38-120721210 11 30
N-Nitroso-di-n-propylamine ug/kg 18301670 110 30-1201081800 2 30
N-Nitrosodimethylamine ug/kg 13601670 81 32-120851420 4 30
N-Nitrosodiphenylamine ug/kg 14201670 85 50-120851420 0 30
Naphthalene ug/kg 11101670 67 38-120641070 4 30
Nitrobenzene ug/kg 12101670 73 37-120721190 2 30
Pentachlorophenol ug/kg 32003330 96 10-120973250 1 30
Phenanthrene ug/kg 14801670 89 62-120921530 3 30
Phenol ug/kg 18001670 108 37-1201051750 3 30
Pyrene ug/kg 13101670 79 63-120891480 13 30
2,4,6-Tribromophenol (S)%89 27-11085
2-Fluorobiphenyl (S)%77 30-11080
2-Fluorophenol (S)%83 13-11087
Nitrobenzene-d5 (S)%67 23-11064
Phenol-d6 (S)%102 22-110102
Terphenyl-d14 (S)%84 28-11085
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
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[phone]
Page 62 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/34718
EPA 3510
EPA 8270
8270 Water MSSV
Associated Lab Samples:92247219001, 92247219002, 92247219003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1448513
Associated Lab Samples:92247219001, 92247219002
Matrix:Water
Analyzed
1,2,4-Trichlorobenzene ug/L ND 10.0 05/04/15 15:11
1,2-Dichlorobenzene ug/L ND 10.0 05/04/15 15:11
1,3-Dichlorobenzene ug/L ND 10.0 05/04/15 15:11
1,4-Dichlorobenzene ug/L ND 10.0 05/04/15 15:11
1-Methylnaphthalene ug/L ND 10.0 05/04/15 15:11
2,4,5-Trichlorophenol ug/L ND 10.0 05/04/15 15:11
2,4,6-Trichlorophenol ug/L ND 10.0 05/04/15 15:11
2,4-Dichlorophenol ug/L ND 10.0 05/04/15 15:11
2,4-Dimethylphenol ug/L ND 10.0 05/04/15 15:11
2,4-Dinitrophenol ug/L ND 50.0 05/04/15 15:11
2,4-Dinitrotoluene ug/L ND 10.0 05/04/15 15:11
2,6-Dinitrotoluene ug/L ND 10.0 05/04/15 15:11
2-Chloronaphthalene ug/L ND 10.0 05/04/15 15:11
2-Chlorophenol ug/L ND 10.0 05/04/15 15:11
2-Methylnaphthalene ug/L ND 10.0 05/04/15 15:11
2-Methylphenol(o-Cresol)ug/L ND 10.0 05/04/15 15:11
2-Nitroaniline ug/L ND 50.0 05/04/15 15:11
2-Nitrophenol ug/L ND 10.0 05/04/15 15:11
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 05/04/15 15:11
3,3'-Dichlorobenzidine ug/L ND 20.0 05/04/15 15:11
3-Nitroaniline ug/L ND 50.0 05/04/15 15:11
4,6-Dinitro-2-methylphenol ug/L ND 20.0 05/04/15 15:11
4-Bromophenylphenyl ether ug/L ND 10.0 05/04/15 15:11
4-Chloro-3-methylphenol ug/L ND 20.0 05/04/15 15:11
4-Chloroaniline ug/L ND 20.0 05/04/15 15:11
4-Chlorophenylphenyl ether ug/L ND 10.0 05/04/15 15:11
4-Nitroaniline ug/L ND 20.0 05/04/15 15:11
4-Nitrophenol ug/L ND 50.0 05/04/15 15:11
Acenaphthene ug/L ND 10.0 05/04/15 15:11
Acenaphthylene ug/L ND 10.0 05/04/15 15:11
Aniline ug/L ND 10.0 05/04/15 15:11
Anthracene ug/L ND 10.0 05/04/15 15:11
Benzo(a)anthracene ug/L ND 10.0 05/04/15 15:11
Benzo(a)pyrene ug/L ND 10.0 05/04/15 15:11
Benzo(b)fluoranthene ug/L ND 10.0 05/04/15 15:11
Benzo(g,h,i)perylene ug/L ND 10.0 05/04/15 15:11
Benzo(k)fluoranthene ug/L ND 10.0 05/04/15 15:11
Benzoic Acid ug/L ND 50.0 05/04/15 15:11
Benzyl alcohol ug/L ND 20.0 05/04/15 15:11
bis(2-Chloroethoxy)methane ug/L ND 10.0 05/04/15 15:11
bis(2-Chloroethyl) ether ug/L ND 10.0 05/04/15 15:11
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
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Huntersville, NC 28078
[phone]
Page 63 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1448513
Associated Lab Samples:92247219001, 92247219002
Matrix:Water
Analyzed
bis(2-Chloroisopropyl) ether ug/L ND 10.0 05/04/15 15:11
bis(2-Ethylhexyl)phthalate ug/L ND 6.0 05/04/15 15:11
Butylbenzylphthalate ug/L ND 10.0 05/04/15 15:11
Chrysene ug/L ND 10.0 05/04/15 15:11
Di-n-butylphthalate ug/L ND 10.0 05/04/15 15:11
Di-n-octylphthalate ug/L ND 10.0 05/04/15 15:11
Dibenz(a,h)anthracene ug/L ND 10.0 05/04/15 15:11
Dibenzofuran ug/L ND 10.0 05/04/15 15:11
Diethylphthalate ug/L ND 10.0 05/04/15 15:11
Dimethylphthalate ug/L ND 10.0 05/04/15 15:11
Fluoranthene ug/L ND 10.0 05/04/15 15:11
Fluorene ug/L ND 10.0 05/04/15 15:11
Hexachloro-1,3-butadiene ug/L ND 10.0 05/04/15 15:11
Hexachlorobenzene ug/L ND 10.0 05/04/15 15:11
Hexachlorocyclopentadiene ug/L ND 10.0 05/04/15 15:11
Hexachloroethane ug/L ND 10.0 05/04/15 15:11
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 05/04/15 15:11
Isophorone ug/L ND 10.0 05/04/15 15:11
N-Nitroso-di-n-propylamine ug/L ND 10.0 05/04/15 15:11
N-Nitrosodimethylamine ug/L ND 10.0 05/04/15 15:11
N-Nitrosodiphenylamine ug/L ND 10.0 05/04/15 15:11
Naphthalene ug/L ND 10.0 05/04/15 15:11
Nitrobenzene ug/L ND 10.0 05/04/15 15:11
Pentachlorophenol ug/L ND 25.0 05/04/15 15:11
Phenanthrene ug/L ND 10.0 05/04/15 15:11
Phenol ug/L ND 10.0 05/04/15 15:11
Pyrene ug/L ND 10.0 05/04/15 15:11
2,4,6-Tribromophenol (S)%73 27-110 05/04/15 15:11
2-Fluorobiphenyl (S)%32 27-110 05/04/15 15:11
2-Fluorophenol (S)%22 12-110 05/04/15 15:11
Nitrobenzene-d5 (S)%40 21-110 05/04/15 15:11
Phenol-d6 (S)%14 10-110 05/04/15 15:11
Terphenyl-d14 (S)%73 31-107 05/04/15 15:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1448514LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 28.850 58 31-120
1,2-Dichlorobenzene ug/L 34.550 69 38-120
1,3-Dichlorobenzene ug/L 30.650 61 30-122
1,4-Dichlorobenzene ug/L 31.850 64 37-120
1-Methylnaphthalene ug/L 31.850 64 34-113
2,4,5-Trichlorophenol ug/L 50.550 101 43-113
2,4,6-Trichlorophenol ug/L 53.250 106 42-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
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Huntersville, NC 28078
[phone]
Page 64 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1448514LABORATORY CONTROL SAMPLE:
LCSSpike
2,4-Dichlorophenol ug/L 35.250 70 30-120
2,4-Dimethylphenol ug/L 34.150 68 29-111
2,4-Dinitrophenol ug/L 510 L025020419-132
2,4-Dinitrotoluene ug/L 51.550 103 58-128
2,6-Dinitrotoluene ug/L 58.850 118 54-129
2-Chloronaphthalene ug/L 49.450 99 43-117
2-Chlorophenol ug/L 43.350 87 37-120
2-Methylnaphthalene ug/L 28.550 57 33-120
2-Methylphenol(o-Cresol)ug/L 36.550 73 31-120
2-Nitroaniline ug/L 119100 119 48-121
2-Nitrophenol ug/L 55.250 110 25-116
3&4-Methylphenol(m&p Cresol)ug/L 33.250 66 23-120
3,3'-Dichlorobenzidine ug/L 87.2100 87 10-154
3-Nitroaniline ug/L 101100 101 43-115
4,6-Dinitro-2-methylphenol ug/L 191 L010019144-124
4-Bromophenylphenyl ether ug/L 40.550 81 34-113
4-Chloro-3-methylphenol ug/L 75.2100 75 31-110
4-Chloroaniline ug/L 68.6100 69 20-120
4-Chlorophenylphenyl ether ug/L 45.050 90 34-116
4-Nitroaniline ug/L 107100 107 46-128
4-Nitrophenol ug/L 134250 54 11-120
Acenaphthene ug/L 42.350 85 48-114
Acenaphthylene ug/L 39.650 79 48-112
Aniline ug/L 32.450 65 26-120
Anthracene ug/L 41.350 83 57-118
Benzo(a)anthracene ug/L 42.350 85 56-121
Benzo(a)pyrene ug/L 41.750 83 55-127
Benzo(b)fluoranthene ug/L 41.450 83 53-128
Benzo(g,h,i)perylene ug/L 39.250 78 54-125
Benzo(k)fluoranthene ug/L 41.250 82 51-123
Benzoic Acid ug/L 93.4250 37 10-120
Benzyl alcohol ug/L 79.2100 79 27-120
bis(2-Chloroethoxy)methane ug/L 34.050 68 32-120
bis(2-Chloroethyl) ether ug/L 41.250 82 33-111
bis(2-Chloroisopropyl) ether ug/L 49.050 98 15-120
bis(2-Ethylhexyl)phthalate ug/L 51.150 102 50-145
Butylbenzylphthalate ug/L 52.250 104 54-138
Chrysene ug/L 42.250 84 58-127
Di-n-butylphthalate ug/L 50.450 101 56-125
Di-n-octylphthalate ug/L 48.750 97 50-134
Dibenz(a,h)anthracene ug/L 40.250 80 53-129
Dibenzofuran ug/L 43.550 87 45-120
Diethylphthalate ug/L 50.350 101 53-120
Dimethylphthalate ug/L 47.550 95 55-116
Fluoranthene ug/L 47.050 94 57-125
Fluorene ug/L 44.050 88 53-118
Hexachloro-1,3-butadiene ug/L 26.450 53 23-120
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 65 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1448514LABORATORY CONTROL SAMPLE:
LCSSpike
Hexachlorobenzene ug/L 38.350 77 49-116
Hexachlorocyclopentadiene ug/L 39.950 80 26-158
Hexachloroethane ug/L 36.850 74 30-114
Indeno(1,2,3-cd)pyrene ug/L 40.350 81 55-128
Isophorone ug/L 34.050 68 31-118
N-Nitroso-di-n-propylamine ug/L 44.650 89 32-119
N-Nitrosodimethylamine ug/L 28.550 57 13-120
N-Nitrosodiphenylamine ug/L 39.250 78 43-120
Naphthalene ug/L 29.150 58 32-120
Nitrobenzene ug/L 35.750 71 33-110
Pentachlorophenol ug/L 138 L010013810-137
Phenanthrene ug/L 40.150 80 57-117
Phenol ug/L 18.650 37 10-120
Pyrene ug/L 39.050 78 55-122
2,4,6-Tribromophenol (S)%S011627-110
2-Fluorobiphenyl (S)%73 27-110
2-Fluorophenol (S)%50 12-110
Nitrobenzene-d5 (S)%67 21-110
Phenol-d6 (S)%33 10-110
Terphenyl-d14 (S)%86 31-107
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
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[phone]
Page 66 of 71
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
PMST/7788
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:92247219004, 92247219005, 92247219006
Parameter Units
Dup
Result QualifiersRPDResult
92247031001
1445230SAMPLE DUPLICATE:
Percent Moisture %29.5 330.4
Parameter Units
Dup
Result QualifiersRPDResult
92247219006
1445231SAMPLE DUPLICATE:
Percent Moisture %23.4 725.0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
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[phone]
Page 67 of 71
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Reanalysis conducted outside EPA hold time. Results of this analysis confirm original extration performed within hold
time.1g
The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.L2
Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.L3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Analyte recovery in the matrix spike was outside QC limits for one or more of the constituent analytes used in the
calculated result.MS
Surrogate recovery outside laboratory control limits.S0
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 68 of 71
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92247219
CAROLINE COURTYARD
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92247219004 MPRP/18380 ICP/16498CC1-UPSTREAM FROM
PROJECT
EPA 3050 EPA 6010
92247219005 MPRP/18380 ICP/16498CC2-PROJECT AREA EPA 3050 EPA 6010
92247219006 MPRP/18380 ICP/16498CC3-DOWNSTREAM OF
PROJECT AREA
EPA 3050 EPA 6010
92247219001 MPRP/18370 ICP/16490CC1-UPSTREAM FROM
PROJECT
EPA 3010 EPA 6010
92247219002 MPRP/18370 ICP/16490CC2- PROJECT AREA EPA 3010 EPA 6010
92247219003 MPRP/18370 ICP/16490CC3-DOWNSTREAM OF
PROJECT
EPA 3010 EPA 6010
92247219001 MERP/7784 MERC/7468CC1-UPSTREAM FROM
PROJECT
EPA 7470 EPA 7470
92247219002 MERP/7784 MERC/7468CC2- PROJECT AREA EPA 7470 EPA 7470
92247219003 MERP/7784 MERC/7468CC3-DOWNSTREAM OF
PROJECT
EPA 7470 EPA 7470
92247219004 MERP/7782 MERC/7467CC1-UPSTREAM FROM
PROJECT
EPA 7471 EPA 7471
92247219005 MERP/7782 MERC/7467CC2-PROJECT AREA EPA 7471 EPA 7471
92247219006 MERP/7782 MERC/7467CC3-DOWNSTREAM OF
PROJECT AREA
EPA 7471 EPA 7471
92247219004 OEXT/34726 MSSV/10620CC1-UPSTREAM FROM
PROJECT
EPA 3546 EPA 8270
92247219005 OEXT/34726 MSSV/10620CC2-PROJECT AREA EPA 3546 EPA 8270
92247219006 OEXT/34748 MSSV/10631CC3-DOWNSTREAM OF
PROJECT AREA
EPA 3546 EPA 8270
92247219001 OEXT/34718 MSSV/10622CC1-UPSTREAM FROM
PROJECT
EPA 3510 EPA 8270
92247219002 OEXT/34718 MSSV/10622CC2- PROJECT AREA EPA 3510 EPA 8270
92247219003 OEXT/34718 MSSV/10622CC3-DOWNSTREAM OF
PROJECT
EPA 3510 EPA 8270
92247219001 MSV/31459CC1-UPSTREAM FROM
PROJECT
EPA 8260
92247219002 MSV/31459CC2- PROJECT AREA EPA 8260
92247219003 MSV/31459CC3-DOWNSTREAM OF
PROJECT
EPA 8260
92247219004 MSV/31430CC1-UPSTREAM FROM
PROJECT
EPA 8260
92247219005 MSV/31431CC2-PROJECT AREA EPA 8260
92247219006 MSV/31431CC3-DOWNSTREAM OF
PROJECT AREA
EPA 8260
92247219004 PMST/7788CC1-UPSTREAM FROM
PROJECT
ASTM D2974-87
92247219005 PMST/7788CC2-PROJECT AREA ASTM D2974-87
92247219006 PMST/7788CC3-DOWNSTREAM OF
PROJECT AREA
ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/11/2015 03:45 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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