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HomeMy WebLinkAbout23055 - Battery and Ignition_Area C and D VIMS Install VIMS Installation Report – Area C and Area D Ello House Battery & Ignition Distribution Tryclan Drive and Ellenwood Place Charlotte, North Carolina Brownfields Project No. 23055-19-060 March 26, 2024 H&H Job No. PDP.001 #C-1269 Engineering #C-245 Geology i https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/proffitt dixon - pdp/pdp-001 - tryclan avenue/vims install report/areas c and d/23055 - battery and ignition_area c and d vims install.docx VIMS Installation Report – Area C and Area D Battery & Ignition Distribution Ello House Tryclan Drive and Ellenwood Place Charlotte, North Carolina Brownfields Project No. 23055-19-060 H&H Job No. PDP.001 Table of Contents 1.0 Introduction ................................................................................................................ 1  2.0 VIMS Installation Inspections and Influence Testing ............................................ 4  2.1 VIMS Installation......................................................................................................4  2.2 VIMS Pilot Influence Testing ...................................................................................6  3.0 VIMS Effectiveness Sampling Activities .................................................................. 8  3.1 Indoor Air Sampling .................................................................................................8  3.2 Indoor Air Sampling Results ....................................................................................9  3.3 Sub-Slab Soil Gas Sampling ...................................................................................10  3.4 Sub-Slab Soil Gas Sampling Results ......................................................................12  3.5 Vapor Intrusion Risk Evaluation ............................................................................12  4.0 Summary and Conclusions ..................................................................................... 14  List of Tables Table 1 Summary of Indoor Air Analytical Results (Area C & D) Table 2 Summary of Sub-Slab Soil Gas Analytical Results (Area C & D) List of Figures Figure 1 Site Location Map Figure 2 Site Map ii https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/proffitt dixon - pdp/pdp-001 - tryclan avenue/vims install report/areas c and d/23055 - battery and ignition_area c and d vims install.docx List of Appendices Appendix A Site Development Phasing Plan Appendix B VIMS As-Built Drawings (VM-1, VM-2, VM-3, and VM-4) Appendix C Product Specifications Appendix D Photographic Log and Inspection Checklist Appendix E VIMS Influence Testing Forms and Sampling Field Forms Appendix F Laboratory Analytical Report Appendix G Safety Data Sheets Appendix H DEQ Risk Calculators 1 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/proffitt dixon - pdp/pdp-001 - tryclan avenue/vims install report/areas c and d/23055 - battery and ignition_area c and d vims install.docx VIMS Installation Report – Area C and Area D Battery & Ignition Distribution Ello House Tryclan Drive and Ellenwood Place Charlotte, North Carolina Brownfields Project No. 23055-19-060 H&H Job No. PDP.001 1.0 Introduction On behalf of 3615 Tryclan, LP (Prospective Developer or PD), Hart & Hickman, PC (H&H) has prepared this report to document vapor intrusion mitigation system (VIMS) installation inspections, VIMS influence testing, and VIMS efficacy sampling activities completed for Area C and Area D of the Ello House apartment building on the Battery & Ignition Distribution Brownfields Property (Brownfields Project No. 23055-19-060) located at 3615 Tryclan Drive in Charlotte, Mecklenburg, North Carolina (Site). A Site location map is included as Figure 1, and the Site and surrounding area are shown in Figure 2. Redevelopment of the Site is nearing completion and includes construction of a residential apartment building. The apartment building is one interconnected building, but it is being completed in stages due to turnover timelines. For simplicity, the building has been divided into five separate turnover areas named A1, A2, B, C, and D, which are depicted on the Site development phasing plan in Appendix A and on Sheets VM-3 and VM-4 in Appendix B. Areas A1, A2, and B have been completed, as documented in the VIMS Installation Report-Area A1 LoSo Village Apartments, dated August 14, 2023, and the VIMS Installation Report-Area A2 and Area B Ello House, dated February 9, 2024. Occupancy compliance approval was received for Area A1 in a letter dated September 15, 2023, and for Areas A2 and B in a letter dated February 13, 2024. This report applies to the VIMS installation in the Area C and Area D portions of the building. To address potential environmental concerns in connection with the Site, a Brownfields Agreement between the North Carolina Department of Environmental Quality (DEQ) and the PD was recorded on January 19, 2022. Land Use Restriction (LUR) 14.h. included in the Brownfields Agreement generally states that no enclosed building may be constructed on the property until DEQ 2 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/proffitt dixon - pdp/pdp-001 - tryclan avenue/vims install report/areas c and d/23055 - battery and ignition_area c and d vims install.docx determines in writing that the building would be protective of users from risks of potential vapor intrusion. In accordance with LUR 14.h. in the Brownfields Agreement for the Site, H&H prepared a Vapor Intrusion Mitigation Plan (VIMP) – Revision 1 dated September 3, 2021, which was subsequently approved by DEQ Brownfields on September 9, 2021. The DEQ-approved VIMP includes installation of a VIMS during construction of the building to minimize the potential for vapor intrusion into the building using a passive sub-slab vapor extraction system. The VIMS consists of a network of sub-slab horizontal collection piping, vertical exhaust risers connected to syphon ventilators on the building roof, and vapor barrier below the concrete slabs and along retaining walls. The VIMS as-built drawings depicting the installed VIMS components are included as Appendix B. H&H completed VIMS inspections, VIMS influence testing, and VIMS efficacy testing for the Area C and Area D building spaces in general accordance with the DEQ-approved VIMP. A summary of the VIMS installation and influence testing activities is provided in Section 2.0. The VIMS efficacy sampling activities and results are detailed in Section 3.0, and a summary and conclusions based on the installation activities, influence testing, and efficacy sampling are provided in Section 4.0. Engineer’s Certification According to the DWM Vapor Intrusion Guidance: “Risk-based screening is used to identify sites or buildings likely to pose a health concern, to identify buildings that may warrant immediate action, to help focus site-specific investigation activities or to provide support for building mitigation and other risk management options including remediation.” In addition, the VIMP for this Site was prepared to satisfy the standard vapor intrusion mitigation provisions in the Brownfields Agreement. Per the North Carolina Brownfields Property Reuse Act 130A-310.32, a prospective developer, with the assistance of H&H for this project, is to provide DEQ with “information necessary to demonstrate that as a result of the implementation of the brownfields agreement, the brownfields property will be suitable for the uses specified in the agreement while fully protecting public health and the environment instead of being remediated to unrestricted use 3 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/proffitt dixon - pdp/pdp-001 - tryclan avenue/vims install report/areas c and d/23055 - battery and ignition_area c and d vims install.docx standards.” It is in the context of these risk-based concepts that the H&H professional engineer makes the following statement: The Vapor Intrusion Mitigation System (VIMS) detailed herein is designed to mitigate intrusion of subsurface vapors into the subject building from known Brownfields Property contaminants in a manner that is in accordance with the most recent and applicable guidelines including, but not limited to, DWM Vapor Intrusion Guidance, Interstate Technology & Regulatory Council (ITRC) guidance, and American National Standards Institute (ANSI)/American Association of Radon Scientists and Technologists (AARST) standards. The sealing professional engineer below is satisfied that the design and its installation are fully protective of public health from known Brownfields Property contaminants. [SEAL] 4 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/proffitt dixon - pdp/pdp-001 - tryclan avenue/vims install report/areas c and d/23055 - battery and ignition_area c and d vims install.docx 2.0 VIMS Installation Inspections and Influence Testing The VIMS in Area C and Area D each operate as separate, interconnected sub-slab vapor extraction mitigation areas. The VIMS mitigation areas include a permeable gravel layer, sub-slab vapor collection piping, a vapor barrier (vapor liner), riser piping, and wind-driven syphon ventilators. As-built drawings depicting the layout of the VIMS (VM-4) and the system specifications and details (VM-1 and VM-2) are provided in Appendix B. Product specifications for the VIMS components are included in Appendix C. 2.1 VIMS Installation Between September 2022 and August 2023, H&H conducted inspections under direction of a North Carolina (NC) Professional Engineer (PE) during various phases of construction to verify that the VIMS was installed in accordance with the DEQ-approved VIMP. Inspections were completed for the VIMS during the following phases of installation: (1) Inspection of the base course gravel layer, sub-slab piping layout, and monitoring points prior to installing the vapor barrier; (2) Inspection of the vapor barrier prior to pouring concrete; (3) Inspection of above-grade vertical riser piping; and (4) Inspection of syphon ventilators and riser pipe connections. A representative photographic log of installed VIMS components along with inspection checklists are provided in Appendix D. Based on observations made during the VIMS inspections, the VIMSs for the Area C and Area D portions of the building were installed in general accordance with the DEQ-approved VIMP. A brief summary of the main VIMS components is provided in the following paragraphs for the Area C and Area D portions of the building. The DEQ-approved VIMP included installation of Vaporblock® Plus 20 (VBP20) vapor barrier manufactured by Viaflex Inc. (Viaflex), beneath the concrete slab-on-grade in Area C and Area D. VBP20 is an ASTM-certified 20-mil, multi-layer, chemically resistant vapor barrier, designed to 5 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/proffitt dixon - pdp/pdp-001 - tryclan avenue/vims install report/areas c and d/23055 - battery and ignition_area c and d vims install.docx prevent the migration of volatile organic compounds. Technical specifications and installation instructions obtained from Viaflex for the VBP20 vapor barrier are provided in Appendix C. The vapor barrier was installed per manufacturer installation instructions (Appendix C). Briefly, VBP20 was installed by the construction contractor to cover the ground surface below the entire area of the ground floor slab. Seams within the building footprint have a minimum 12-inch overlap and were sealed with VaporSeal™ tape. Small puncture holes and utility penetrations were sealed with VaporSeal™ tape. In addition to the vapor barrier, the VIMS also includes vapor extraction components beneath the ground-level concrete slab to reduce the potential for vapor intrusion into the building. Sub-slab vapor extraction is accomplished using 3-inch schedule 40 PVC piping. The sub-slab vapor extraction piping is connected to riser piping which extends to the roof. The passive VIMS is enhanced with Empire Model SV04SS (Stainless Steel) syphon ventilators installed on the discharge end of the exhaust stacks on the roof. The vent systems in each area are interconnected to allow for continued depressurization below the building slabs in the event that active fans are installed in the future or the syphon ventilator is damaged between yearly inspections. Product specification sheets for the stationary ventilator and slotted piping are included in Appendix C. To further enhance sub-slab vapor transmission and collection effectiveness, a uniform layer of high permeability stone (clean #57) was installed directly below the concrete slab to allow for air movement beneath the entirety of the slab. Sub-slab 3-inch Schedule 40 PVC piping was installed within the high permeability stone layer. The thickness of the high permeability stone around the PVC piping extends a minimum of 2 inches below the piping, and the top of the PVC piping is set flush with the completed stone layer, or approximately 1-inch below the top of the stone. In areas without piping, a minimum thickness of 4 inches of clean stone was installed. To complete influence testing and in the event the system needs to be activated with electric fans, vacuum monitoring points were installed in Area C and Area D to measure the pressure differential between indoor air and the sub-slab, and for collection of sub-slab soil gas samples. Area C has two permanent monitoring points (MP-4 and MP-5) and one temporary monitoring point (TMP- 6 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/proffitt dixon - pdp/pdp-001 - tryclan avenue/vims install report/areas c and d/23055 - battery and ignition_area c and d vims install.docx 3); Area D has one permanent vacuum monitoring point installed (MP-3) and one temporary monitoring point (TMP-4). The locations of the monitoring points are depicted on as-built drawing VM-4 provided in Appendix B. Based on inspections completed during the VIMS installation activities, the VIMS was installed in general accordance with the DEQ-approved VIMP. VIMS details and specifications and VIMS as-built drawings are included in Appendix B. A representative photographic log of the installed VIMS components is provided in Appendix D. 2.2 VIMS Pilot Influence Testing In accordance with the DEQ-approved VIMP, on March 29, March 30, and August 24, 2023, post- installation VIMS pilot influence testing was conducted after the concrete slabs had been poured to evaluate sub-slab vacuum communication across mitigated areas and verify that sufficient depressurization can be achieved should electric fans be needed in the future. During testing, H&H connected electric fans to the vertical riser piping to model an active sub-slab depressurization system. Differential pressure measurements were collected at corresponding vacuum monitoring points using a Dwyer series 475 Mark III digital manometer (capable of measuring to 0.001 inches of water column [in-WC] or 0.25 Pa) to establish baseline conditions prior to use of the electric fans. Following collection of baseline differential pressure measurements, the electric fans were turned on and differential pressure measurements were collected at each monitoring point and fan. A pressure differential resulting in depressurization below the slab of at least 4 pascals (approximately 0.016 in-WC) at remote distances from riser locations in each VIMS treatment area is generally considered sufficient evidence for adequate sub-slab depressurization. The pilot influence test results are provided in Appendix E. Please note that the influence testing for Area C and Area D was conducted concurrently with testing in other portions of the building. The table below identifies the fans and monitoring points used to evaluate the two areas and provides a summary of the monitoring point differential pressure ranges observed in the Area C and Area D portions of the building during the pilot testing. Fan and monitoring point locations are depicted on VM-4 in Appendix B. 7 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/proffitt dixon - pdp/pdp-001 - tryclan avenue/vims install report/areas c and d/23055 - battery and ignition_area c and d vims install.docx Test Area Associated Fan Locations Associated Monitoring Points Differential Pressure Range (in-WC) Area C E-5, E-6, and E-7 MP-4, MP-5, and TMP-3 -0.232 to -1.292 Area D E-3, E-4 MP-3, TMP-4 -0.363 to -0.810 The influence test results indicate that adequate connection from the risers to each corresponding area of the sub-slab annular space is present and that adequate sub-slab communication with vacuum influence greater 0.016 in-WC (4 pascals) is achievable in each area should active sub- slab depressurization be warranted in the future. 8 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/proffitt dixon - pdp/pdp-001 - tryclan avenue/vims install report/areas c and d/23055 - battery and ignition_area c and d vims install.docx 3.0 VIMS Effectiveness Sampling Activities Following successful installation of the VIMS, H&H collected co-located indoor air and sub-slab soil gas samples from select locations within the footprint of the Area C and Area D portions of the building to evaluate risks to future building occupants. The samples were collected in general accordance with the DEQ-approved VIMP and the DEQ DWM Vapor Intrusion Guidance (Guidance) dated March 2018. Details of the indoor air and sub-slab soil gas sampling activities and results are provided in the following sections. 3.1 Indoor Air Sampling On February 20 to February 21, 2024, H&H collected two (2) indoor air samples (C-IAS-1 and D- IAS-1) from the Area C and Area D portions of the building after the building was enclosed (all exterior doors and windows installed) and the VIMS was installed. In accordance with the DEQ- approved VIMP, the indoor air sampling was conducted prior to installation of the heating, ventilation, and air conditioning (HVAC) equipment. The indoor air samples were collected using a laboratory-supplied individually-certified 6-liter Summa canister over a 24-hour period and were analyzed for select volatile organic compounds (VOCs) by EPA Method TO-15. The select VOC list was based on the compounds detected within the sub-slab vapor samples and compounds previously detected on the property. DEQ approved the indoor air analyte list via e-mail on March 4, 2024. The indoor air samples were collected prior to the sub-slab soil gas sampling described in Section 3.3 below. The indoor air samples were collected from residential units 148 (C-IAS-1) and 133 (D-IAS-1). The syphon ventilators were installed a minimum of two weeks prior to the sampling event. For QA/QC purposes, one duplicate indoor air sample (IAS-DUP) was collected during the sampling event using a laboratory-supplied stainless-steel sample “T” fitting. One background ambient air sample (IAS-BKG) was also collected. The location of the outdoor background air sample was determined on the day of sampling based on the prevailing wind direction on that day and was collected south of the Area D portion of the building. 9 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/proffitt dixon - pdp/pdp-001 - tryclan avenue/vims install report/areas c and d/23055 - battery and ignition_area c and d vims install.docx The Summa canisters were deployed on raised sampling platforms which placed the sample intake at a height consistent with the breathing zone (approximately 5 ft above grade). The approximate locations of the pre-occupancy indoor air samples are depicted on the as-built drawing (VM-4 in Appendix B). Periodic checks were conducted by H&H to monitor the pressure within the Summa canisters to confirm adequate sample volume was collected. During the sampling activities, indoor/outdoor air pressure differential was measured several times, including at the start and end of the 24-hour sampling period using a manometer sensitive to 0.001 inches of water column. In addition, exterior wind speed, wind direction, barometric pressure, indoor/outdoor temperature, and precipitation (if any) were recorded near the start and end of the sampling period. H&H also completed a DEQ Indoor Air Building Survey and Sampling Form (Appendix C of the DWM VI Guidance) to record sample information and building and individual unit conditions at the time of sampling. The canisters were labeled with the sample identification, beginning and ending times, and the requested analysis. The canisters were then placed in laboratory-supplied shipping containers and delivered to Waypoint Analytical, LLC (Waypoint) under standard chain of custody protocols for analysis of select VOCs. As indicated in the laboratory reports, J-flag estimated concentrations were reported by the laboratory. The completed building survey and sampling forms are included in Appendix E, and the laboratory analytical report and chain of custody form are included in Appendix F. 3.2 Indoor Air Sampling Results The indoor air sample analytical results are summarized in Table 1, and the laboratory analytical report with chain of custody record is provided in Appendix F. The indoor air sample laboratory analytical results were compared to the DEQ Residential Indoor Air Screening Levels (IASLs) dated February 2024. The indoor air analytical results indicate that several compounds were detected above laboratory method detection limits (MDLs) in the Area C and Area D portions of the building. Four 10 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/proffitt dixon - pdp/pdp-001 - tryclan avenue/vims install report/areas c and d/23055 - battery and ignition_area c and d vims install.docx constituents (benzene, ethylbenzene, naphthalene, and total xylenes) were detected at concentrations above the Residential IASLs. Benzene (ranging from 1.20 J micrograms per cubic meter [µg/m3] to 2.29 µg/m3) was detected at estimated concentrations in each of the indoor air samples above the Residential IASL of 0.36 µg/m3. Benzene was also detected above the Residential IASL in the background air sample (0.897 J µg/m3) and is likely attributed to vehicular traffic. Ethylbenzene (ranging from 1.81 J µg/m3 to 3.23 µg/m3) was detected in each of the indoor air samples at concentrations above the Residential IASL of 1.1 µg/m3. Naphthalene (0.571 J µg/m3 and 0.560 J µg/m3) was detected at estimated concentrations in the Area C indoor air sample (C-IAS-1) and associated duplicate sample (IAS-DUP) above the Residential IASL of 0.083 µg/m3. Total xylenes (23.5 µg/m3 and 23.9 µg/m3) were detected in the Area C indoor air sample (C-IAS-1) and associated duplicate sample (IAS-DUP) at concentrations above the Residential IASL of 21 µg/m3. Tetrachloroethylene (PCE) and trichloroethylene (TCE) were not detected at concentrations above the laboratory method detection limits in the indoor air samples (or duplicate) collected from Area C and Area D. Benzene, ethylbenzene, naphthalene, and xylenes are common components of building materials and/or gasoline products, as listed in the Safety Data Sheets (SDS) that were provided to H&H for building materials and products used during construction of the building (Appendix G). The use of these materials likely contributed to the detected indoor air concentrations of benzene, ethylbenzene, naphthalene, and xylenes. In addition, these compounds were detected at lower (or similar) concentrations in the sub-slab soil gas samples (see Table 2) suggesting the indoor air concentrations are attributable to an above-slab source and are not associated with vapor intrusion. 3.3 Sub-Slab Soil Gas Sampling The DEQ-approved VIMP specified the collection of two sub-slab soil gas samples from monitoring points MP-4 and MP-5 in Area C and one sub-slab soil gas sample from MP-3 in Area D. However, immediately before the sampling event, MP-4 was observed to have been recently repaired with PVC glue, which would impact the sampling results and laboratory reporting limits. H&H contacted DEQ, and DEQ agreed that MP-4 could be omitted from the pre- 11 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/proffitt dixon - pdp/pdp-001 - tryclan avenue/vims install report/areas c and d/23055 - battery and ignition_area c and d vims install.docx occupancy sampling event and sampled during the first-occupancy sampling event. H&H collected the sub-slab vapor samples from Area C (MP-5) and Area D (MP-3) on February 21, 2024 (after indoor air sampling was completed). The sub-slab soil gas sample locations are shown on Sheet VM-4 in Appendix B. During the sub-slab soil gas sampling event, one duplicate sub-slab soil gas sample was collected for quality assurance/quality control (QA/QC) purposes. MP-DUP was collected from location MP-5 for Area D. The duplicate sub-slab soil gas sample was collected utilizing a laboratory- supplied stainless-steel sampling “T” which allows for the simultaneous collection of two sub-slab soil gas samples from a monitoring point. At each sample location, a temporary expandable plug with a quick-connect sampling port was placed within the monitoring point to create an air-tight seal. Teflon sample tubing was then secured to the sampling port and connected to an airflow regulator and laboratory-supplied batch-certified 1.4-liter stainless steel Summa canister. The airflow regulator was preset by the laboratory to collect the sample at a flow rate of approximately 140 milliliters per minute. Prior to sample collection, H&H conducted a leak test at each monitoring point by placing a shroud around the monitoring point and sampling train including the Summa canister. The air within the shroud was flooded with helium vapor and concentrations were measured with a calibrated helium detector. Helium concentrations within the shroud were maintained between approximately 12% and 13%. A small air pump was connected to the sample tubing outside of the shroud and used to purge a minimum of three sample train volumes into a Tedlar® bag at each sampling point. The helium detector was used to measure helium concentrations within the Tedlar® bag sample to confirm helium concentrations in the sample were less than 10% of that measured within the shroud. Results of the helium leak checks indicate that short-circuiting at the monitoring points or within the sampling train was not present. Sub-slab soil gas sampling field forms completed by sampling personnel are included in Appendix E. Following a successful leak check, the air flow regulators were opened to allow collection of the sub-slab soil gas samples. Vacuum in the Summa canisters was monitored during the sampling 12 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/proffitt dixon - pdp/pdp-001 - tryclan avenue/vims install report/areas c and d/23055 - battery and ignition_area c and d vims install.docx event to confirm adequate sample volume was collected at each monitoring point. Upon completion of sample collection, the air flow regulator to the Summa canister was closed. The canisters were labeled with the sample identification, the beginning and ending times, the pressure measurements, and the requested analysis. The canisters were then placed in laboratory-supplied shipping containers and delivered to Waypoint under standard chain of custody protocols for analysis of VOCs by EPA Method TO-15 (full list). 3.4 Sub-Slab Soil Gas Sampling Results The sub-slab soil gas sample analytical results are summarized in Table 2, and the laboratory analytical report with chain of custody record are provided in Appendix F. The sub-slab soil gas sample laboratory analytical results were compared to the DEQ Residential Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs) dated February 2024. Several VOCs were detected in each sample collected from Areas C and D at concentrations above laboratory MDLs but below the Residential SGSLs. One constituent, tetrahydrofuran, was detected at a concentration of 14,200 µg/m3 in the Area D sample location (MP-3), which slightly exceeded the Residential SGSL of 14,000 µg/m3. Tetrahydrofuran is a component of PVC primer and glue, as listed in the Safety Data Sheets (SDS) that were provided to H&H for building materials and products used during construction of the building (Appendix G). The detected concentration of tetrahydrofuran is attributable to the use of these materials. PCE and TCE were not detected at concentrations above the laboratory method detection limits in the sub-slab soil gas samples (or duplicate) collected from Area C and Area D. 3.5 Vapor Intrusion Risk Evaluation The DEQ vapor intrusion screening levels are conservative and based on a target carcinogenic risk (TCR) of 1 x 10-6 and a non-carcinogenic target hazard quotient (THQ) of 0.2. The DEQ acceptable risk level for potential carcinogenic risks is a cumulative lifetime incremental cancer risk (LICR) of 1 x 10-4 or less and the acceptable risk level for non-carcinogenic risks is a cumulative hazard index (HI) of 1 or less. 13 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/proffitt dixon - pdp/pdp-001 - tryclan avenue/vims install report/areas c and d/23055 - battery and ignition_area c and d vims install.docx H&H utilized the DEQ Risk Calculator (February 2024) to further evaluate potential vapor intrusion risks at the Site. H&H modeled a “worst-case” scenario by using the highest concentrations of any compound detected in the February 2024 samples from both Area C and Area D to conservatively evaluate potential vapor intrusion risks for a residential use scenario. The calculated worst-case cumulative LICR and HI values for the indoor air and sub-slab soil gas are provided in Table 1 and Table 2, and a copy of the completed DEQ Risk Calculator is provided in Appendix H. As shown in Table 1 and Table 2, results of the worst-case risk calculations for a residential use scenario in Area C and Area D indicate a calculated cumulative LICR of 5.8 x10-7 and a HI value of 0.23 for sub-slab soil gas and a calculated cumulative LICR of 1.6 x10-5 and a HI value of 0.82 for indoor air. The calculated cumulative residential use LICRs and HI values are within the DEQ acceptable levels. Based on this evaluation, the analytical samples do not indicate that there is unacceptable vapor intrusion risk from Site contaminants to the occupants of the Area C or Area D portions of the building, and no further pre-occupancy sampling is warranted. 14 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/proffitt dixon - pdp/pdp-001 - tryclan avenue/vims install report/areas c and d/23055 - battery and ignition_area c and d vims install.docx 4.0 Summary and Conclusions Installation of the VIMS has been completed for the Area C and Area D turnover portions of the Ello House multi-family apartments on the Battery & Ignition Distribution Brownfields Property. Results of installation inspections, influence testing, and effectiveness sampling activities indicate that the VIMS has been successfully installed in general accordance with the DEQ-approved VIMP. During construction of the Area C and Area D portions of the building, H&H conducted VIMS installation inspections to confirm the system was installed as designed and completed post- installation influence testing and indoor air and/or sub-slab soil gas sampling activities to evaluate the efficacy of the systems. The VIMS installation inspections and post-installation testing activities were completed in general accordance with the DEQ-approved VIMP. A summary of the VIMS installation and post-installation efficacy assessment activities is provided below. VIMS Installation VIMS installation has been completed for the Area C and Area D portions of the building. The VIMS in each area consists of a passive sub-slab venting system with vertical extraction piping to the roof connected to wind-driven syphon ventilators. During installation of the VIMS, H&H personnel, under the direction of a North Carolina licensed Professional Engineer, conducted inspections during each stage of installation. Results of the installation inspections indicate that the VIMS was successfully installed in general accordance with the DEQ-approved VIMP. Sub-Slab Vacuum Influence H&H completed vacuum influence pilot testing in March 2023. Differential pressure measurements collected during the pilot test activities for Area C (ranging from -0.232 in-WC to -1.292 in-WC) and Area D (ranging from -0.363 in-WC to -0.810 in-WC) indicate that adequate vacuum communication beneath the slab was achieved. Based on these results, sufficient vacuum (greater than 0.016 in-WC differential pressure) can be achieved by vacuum fans if an active system is needed in the future. 15 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/proffitt dixon - pdp/pdp-001 - tryclan avenue/vims install report/areas c and d/23055 - battery and ignition_area c and d vims install.docx Indoor Air Assessment Following installation of the VIMS, H&H collected one indoor air sample and one duplicate from the Area C portion of the building and one indoor air sample from the Area D portion of the building to evaluate potential vapor intrusion risks. Laboratory analytical results of the indoor air samples indicated that benzene, ethylbenzene, naphthalene, and total xylenes were detected at concentrations above the Residential IASLs. H&H utilized the DEQ Risk Calculator (February 2024) to calculate the cumulative carcinogenic and non-carcinogenic risks under a hypothetical worst-case residential-use scenario by utilizing the highest concentration of each compound detected from both areas. The hypothetical worst-case residential use risk calculator results indicate a cumulative LICR of 1.6 x 10-5 and a HI value of 0.82. The LICR and HI are within the acceptable risk levels, which indicates that there is no unacceptable vapor intrusion risk from Site contaminants to the occupants of the Area C and Area D portions of the building. No further pre- occupancy sampling is warranted. Sub-Slab Soil Gas Assessment H&H collected one sub-slab soil gas sample (and duplicate) from Area C and one sub-slab soil gas sample from Area D to evaluate potential vapor intrusion risks in each building area. Laboratory analytical results of the sub-slab soil gas samples indicate tetrahydrofuran was detected above the DEQ Residential SGSL in Area D, but is attributable to the recent use of PVC glue and primer at the Site. H&H utilized the DEQ Risk Calculator (February 2024) to calculate the cumulative carcinogenic and non-carcinogenic risks under a hypothetical worst-case residential-use scenario by utilizing the highest concentration of each compound detected in the sub-slab soil gas samples. The hypothetical worst-case risk calculator results indicate a cumulative LICR of 5.8 x 10-7 and a HI value of 0.23 for residential use. The LICR and HI are within the acceptable risk levels. Based on the evaluation, the analytical sample results do not indicate that there is unacceptable vapor intrusion risk from Site contaminants to the occupants of the Area C and Area D portions of the building. No further pre-occupancy sampling is warranted in these areas. Conclusions Based on the VIMS installation inspections, influence testing, and post-installation sub-slab soil gas and indoor air sampling results, the VIMS is effectively mitigating potential vapor intrusion 16 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/proffitt dixon - pdp/pdp-001 - tryclan avenue/vims install report/areas c and d/23055 - battery and ignition_area c and d vims install.docx risks within the Area C and D portions of the building and is operating as designed. In accordance with the DEQ-approved VIMP, post-occupancy sub-slab soil gas sampling for Area C and Area D will be completed in the summer of 2024 and then on a semi-annual basis for future events. The first post-occupancy sampling event for the entire Ello House apartment building is scheduled for May 2024, as approved by DEQ in an email dated March 14, 2024. The post-occupancy sampling events will be performed in accordance with the procedures outlined in the VIMP, and the results will be reported to DEQ. If semi-annual sampling results indicate consistent or decreasing concentrations within acceptable risk levels, a request to modify or terminate sampling will be submitted for DEQ approval. Based on the pre-occupancy sampling results and in accordance with the DEQ-approved VIMP, we are requesting DEQ approval not to conduct post-occupancy indoor air sampling, unless the post-occupancy soil gas sampling results indicate cumulative risks greater than 1 x 10-4 for carcinogenic risks and/or a hazard index greater than 1 for non-carcinogenic risks. If post- occupancy indoor air sampling is deemed to be warranted, DEQ will be notified to discuss the sampling locations and analyte list, and written approval will be obtained prior to proceeding with the sampling. Tables Table 1 Summary of Indoor Air Analytical Results (Area C & D) Battery & Ignition Distribution Tryclan Drive and Ellenwood Place Charlotte, North Carolina Brownfields Project No. 23055-19-060 H&H Job No. PDP-001 Building Area Sample Location Area D Unit #133 Outdoor Ambient Air Sample ID D-IAS-1 IAS-BKG Date Collected VOCs (TO-15) Acetone 118 114 263 9.14 B NE Benzene 2.22 2.29 1.20 J 0.897 0.36 Chloromethane 0.947 J 0.949 J 0.972 J <0.067 19 Dichlorodifluoromethane 2.87 2.89 2.83 2.83 21 Ethylbenzene 3.23 3.20 1.81 J <0.106 1.1 4-Ethyltoluene 1.88 J 1.93 J 0.958 J <0.128 NE 1,1,2-Trichloro-1,2,2-trifluoroethane 0.590 J 0.582 J 0.590 J 0.597 J 1,000 Heptane 2.17 2.41 1.31 J 0.672 J 83 n-Hexane 2.51 2.58 1.32 J 0.676 J 150 Isopropyl Alcohol 6.34 B 6.33 B 9.13 B 2.88 J, B 42 Methyl Ethyl Ketone (MEK) 65.0 65.8 59.3 3.49 1,000 Methylene Chloride 1.08 J 1.63 J 1.47 J 1.28 J 100 Naphthalene 0.571 J 0.560 J <0.183 <0.183 0.083 Styrene 2.11 J 2.14 1.63 J <0.124 210 Tetrachloroethene <0.181 <0.181 <0.181 <0.181 8.3 Tetrahydrofuran 25.0 25.6 23.8 1.66 420 Toluene 9.65 11.4 6.48 3.52 1,000 Trichloroethene <0.199 <0.199 <0.199 <0.199 0.42 Trichlorofluoromethane 1.65 J 1.74 J 1.58 J 1.62 J NE 1,2,4-Trimethylbenzene 10.3 10.2 4.74 <0.110 13 1,3,5-Trimethylbenzene 2.69 2.77 1.23 J <0.236 13 o-Xylene 11.1 11.4 6.24 0.408 J 21 mp-Xylene 12.4 12.5 6.63 0.864 J 21 Xylene (Total)23.5 23.9 12.9 1.27 J 21 DEQ Cumulative Risk Calculator (2)Acceptable Risk Levels (3) LICR (Worst-Case Residential)--≤1.0 x 10-4 HI (Worst-Case Residential)--≤1.0 Notes: 1) North Carolina Department of Environmental Quality (DEQ) Vapor Intrusion Indoor Air Screening Levels (IASLs) dated February 2024. 2) Risks calculated using DEQ Risk Calculator (dated February 2024) and the highest concentration of any compound detected in the samples. 3) Cumulative LICR and HI are compared to the DEQ and Environmental Protection Agency (EPA) acceptable levels for carcinogenic and non-carcinogenic risks. Only constituents detected in at least one sample and select chlorinated compounds are shown in the table above. Compound concentrations and IASLs are reported in micrograms per cubic meter (µg/m3). Compound concentrations are reported to the laboratory method detection limits. Laboratory analytical method is shown in parentheses. Bold values exceed the Residential IASL. LICR = Lifetime Incremental Cancer Risk; HI = Hazard Index VOCs = volatile organic compounds; -- = not applicable; NE = not established J = Estimated concentration between laboratory reporting limit and method detection limit. B = Compound was detected in laboratory method blank. 1.6 X 10-5 0.82 2/20/24 to 2/21/24 Area C & D Residential IASLs (1)Area C Unit #148 C-IAS-1 / IAS-DUP https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Proffitt Dixon - PDP/PDP-001 - Tryclan Avenue/VIMS install report/Areas C and D/Tables/Area C&D Data Tables 3/26/2024 Table 1 (Page 1 of 1) Hart & Hickman, PC Table 2 Summary of Sub-Slab Soil Gas Analytical Results (Area C & D) Battery & Ignition Distribution Tryclan Drive and Ellenwood Place Charlotte, North Carolina Brownfields Project No. 23055-19-060 H&H Job No. PDP-001 Building Area Sample ID MP-3 Date Collected VOCs (TO-15) Acetone 17,400 66.0 67.4 NE Benzene <1.46 2.47 2.44 12 Carbon Disulfide <1.22 0.747 J 0.737 J 4,900 Chloroform <1.73 0.522 J 0.517 J 4.1 Cyclohexane 28.7 J <0.161 <0.161 42,000 Dichlorodifluoromethane <2.68 2.84 2.90 700 Ethylbenzene <2.12 1.44 J 1.44 J 37 4-Ethyltoluene <2.56 0.408 J 0.408 J NE 1,1,2-Trichloro-1,2,2-trifluoroethane <11.2 0.597 J 0.643 J 35,000 Heptane <2.86 0.401 J 0.368 J 2,800 n-Hexane <0.942 1.42 J 1.11 J 4,900 Isopropyl Alcohol 55.1 J 3.83 J, B 3.52 J, B 1,400 Methyl Ethyl Ketone (MEK)<4.48 76.2 79.0 35,000 Methylene Chloride 12.4 J 3.94 1.55 J 3,400 Naphthalene <3.66 0.492 J 0.560 J 2.8 Propene <4.84 4.59 4.59 21,000 Styrene <2.48 0.379 J 0.379 J 7,000 Tetrachloroethene <3.62 <0.181 <0.181 280 Tetrahydrofuran 14,200 63.9 63.7 14,000 Toluene <1.80 3.34 3.32 35,000 Trichloroethene <3.98 <0.199 <0.199 14 Trichlorofluoromethane <2.60 1.80 J 1.74 J NE 1,2,4-Trimethylbenzene <2.20 1.85 J 1.82 J 420 1,3,5-Trimethylbenzene <4.72 0.565 J 0.535 J 420 o-Xylene <3.14 2.73 2.62 700 m,p-Xylene 7.47 J 5.53 J 5.47 J 700 Xylene (Total) 7.47 J 8.26 J 8.09 J 700 DEQ Cumulative Risk Calculator (2)Acceptable Risk Levels (3) LICR (Worst-Case Residential)≤1.0 x 10-4 HI (Worst-Case Residential)≤1.0 Notes: 1) North Carolina Department of Environment Quality (DEQ) Residential Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs) dated February 2024. 2) Risks calculated using DEQ Risk Calculator (dated February 2024) and the highest concentration of any compound detected in the samples 3) Cumulative LICR and HI are compared to the DEQ and Environmental Protection Agency (EPA) acceptable levels for carcinogenic and non-carcinogenic risks. Only constituents detected in at least one sample and select chlorinated compounds are shown in the table above. Compound concentrations and SGSLs are reported in micrograms per cubic meter (µg/m3). Compound concentrations are reported to the laboratory method detection limits. Laboratory analytical method is shown in parentheses. Bold values exceed the Residential SGSL. LICR = Lifetime Incremental Cancer Risk; HI = Hazard Index VOCs = volatile organic compounds; NE = not established J = Estimated concentration between laboratory reporting limit and method detection limit. B = Compound was detected in laboratory method blank. Residential SGSLs (1) Area C & D 0.23 5.8 X 10-7 MP-5 / MP-DUP 2/21/2024 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Proffitt Dixon - PDP/PDP-001 - Tryclan Avenue/VIMS install report/Areas C and D/Tables/Area C&D Data Tables 3/26/2024 Table 2 (Page 1 of 1) Hart & Hickman, PC Figures REVISION NO. 0 JOB NO. PDP-001 DATE: 6-15-23 FIGURE NO. 2 BATTERY & IGNITION DISTRIBUTION TRYCLAN DRIVE AND ELLENWOOD PLACE CHARLOTTE, NORTH CAROLINA SITE MAP LEGEND BROWNFIELDS PROPERTY BOUNDARY PARCEL BOUNDARY 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology DEUTSCHE PROCESS (3642 & 3630 TRYCLAN DRIVE) RESIDENCE (3701 ELLENWOOD PLACE) RESIDENCE (3709 ELLENWOOD PLACE) RESIDENCE (3715 ELLENWOOD PLACE) RESIDENCE (3706 ELLENWOOD PLACE) RESIDENCE (3712 ELLENWOOD PLACE) ELL E N W O O D P L A C E S. T R Y O N S T R E E T TRYC L A N D R I V E DE W I T T L A N E GILDE BREWERY (3530 DEWITT LANE) BSR MODERN MARTIAL ARTS (3539-3543 DEWITT LANE) MAA LOSO (4107-4115 CRAFT STREET) RESIDENTIAL DEW I T T L A N E YORKSHIRE DRIVE BROWNFIELDS PROPERTY (BPN 22033-18-60) GLE A S O N W A Y YORK S H I R E D R I V E NOTES: 1.AERIAL IMAGERY AND PARCEL DATA OBTAINED FROM MECKLENBURG COUNTY GIS (2022). 2.BPN = BROWNFIELDS PROJECT NUMBER MAKE A MOVE / BEKINS (3520 DEWITT LANE) PARKING DECK S:\ A A A - M a s t e r P r o j e c t s \ P r o f f i t t D i x o n - P D P \ P D P - 0 0 1 - T r y c l a n A v e n u e \ M W A b a n d o n m e n t \ S i t e M a p . d w g , F I G 2 , 6 / 1 5 / 2 0 2 3 3 : 4 5 : 5 6 P M , k m c k i n n e y Appendix A Site Development Phasing Plan 9$1 9$1 9$ 1 (9 &(9 & & (9 (9 9$1 FDFD FD FD FD FD FD FD FD DN DNDN DN FD FD FD FD 83 '1 '1 83       UP             DN UP  DN    GARAGE VENTILATION SHAFT   DN  THE FRONT PORCH  DN DN GARAGE VENTILATION SHAFT     %8,/',1* 3+$6( %8,/',1*3$57, 3+$6( %8,/',1* 3+$6( %8,/',1*3$57,, 3+$6( 3-HR FIREWALL 3-HR FIREWALL 3-HR FIREWALL %8,/',1*3$57, 3+$6( %8,/',1*3$57,, 3+$6( 3-HR FIREWALL PROVIDED FOR PHASING ONLY. FIREWALL DOES NOT CREATE A NEW FIRE AREA OR CONSTITUTE A HORIZONTAL EXIT 3-HR FIREWALL PROVIDED FOR PHASING ONLY. FIREWALL DOES NOT CREATE A NEW FIRE AREA OR CONSTITUTE A HORIZONTAL EXIT. 50'-0'' MAX. 50'-0'' MAX. TEMP. CONST. BARRIER TO PREVENT DEAD END CONDITION UNTIL PHASE 2 IS COMPLETE. %/'*&216758&7,213+$6,1*1$55$7,9( MECHANICAL 1. PRIOR TO RECEIVING TCO PER FLOOR, ALL OPENINGS FOR AIR SHAFTS SHALL HAVE FIRE / SMOKE DAMPERS IN PLACE ON OTHER FLOORS. PLUMBING 1. CONSTRUCTION SHALL BE PHASED SUCH THAT THE INITIAL PHASE INCLUDES ALL PLUMBING PIPING INSTALLED UP TO BUT NOT INCLUDING FIXTURES. THE ONLY FIXTURE TO BE INSTALLED SHALL BE THE TUBS WITH CAPPED CW AND HW IN PREPARATION FOR TRIM INSTALLATION. ELECTRICAL 1. WHEN ENERGIZING A FLOOR FOR TURN OVER, ALL BRANCH CIRCUITS SERVING OTHER AREAS FROM THE SAME PANEL SHALL BE TAGGED/LOCKED OUT AT THE PANEL. 2. ALL NORMAL/EGRESS LIGHTING AND SIGNAGE SHALL BE INSTALLED AND OPERATIONAL FROM THE AREA BEING OCCUPIED DOWN TO THE BUILDING EXIT. 3. FIRE ALARM SYSTEM SHALL BE WIRED AND PROGRAMMED TO ALLOW EACH FLOOR AND EACH PHASE TO BE OCCUPIED SEPARATELY. LIFE SAFETY 1. ELEVATORS WILL BE OPERATIONAL. ELEVATORS WILL BE AVAILABLE TO CONSTRUCTION TRAFFIC UNTIL THE ADJACENT BUILDING PHASE (APARTMENTS) IS COMPLETED. AT THAT TIME, USE OF ELEVATORS WILL BE FOR RESIDENT TRAFFIC ONLY. 2. STAIRWELLS TO BE COMPLETE AND USABLE BY TENANTS. CONTRACTOR TO MAINTAIN STAIRWELLS TO MAKE SURE THERE IS NO CONSTRUCTION DEBRIS AND THAT A CONTINUOUS PATH OF EGRESS IS PROVIDED AT ALL TIMES. SIGNAGE WILL BE PROVIDED AT EACH FLOOR LEVEL UNDER CONSTRUCTION RESTRICTING ACCESS TO AUTHORIZED CONSTRUCTION PERSONNEL ONLY. 3. AN UNOBSTRUCTED PATH OF EGRESS MUST BE MAINTAINED FROM EACH POINT OF EXIT FROM THE BUILDING OUT TO THE PUBLIC WAY. 4. TEMPORARY CONSTRUCTION BARRIERS SHALL BE PLACED AS SHOWN ON THE PHASING PLANS TO PREVENT TENANT ACCESS TO AREAS THAT HAVE NOT RECEIVED TCO'S AND/OR PREVENT DEAD END CORRIDOR CONDITIONS LONGER THAN 50'-0" FROM A POINT OF DECISION. CONSTRUCTION OF THIS BUILDING TO BE PHASED. OVERALL BUILDING WILL BE COMPLETED IN 4 SEPARATE PHASES, SEPARATED BY FIRE WALLS. BUILDINGS WILL BE COMPLETED FROM THE BOTTOM UP WITH BOTTOM FLOOR RECEIVING TCO'S FIRST AND FLOORS ABOVE FOLLOWING SEQUENTIALLY. PARKING GARAGE IS PERMITTED SEPARATELY AND WILL BE FULLY COMPLETE AT THE END OF PHASE 1 TCO TO ALLOW FOR RESIDENT PARKING. POOL & COURTYARD WILL ALSO HAVE A SEPARATE PERMIT.. MINIMUM LIFE SAFETY MUST BE IN PLACE AND OPERATIONAL THROUGHOUT THE BUILDING BEFORE TCO'S WILL BE APPROVED. THE FOLLOWING IS A NARRATIVE TO ADDRESS CONSTRUCTION PHASING: FIRE/SPRINKLER 1. FIRE ALARM WILL BE OPERATIONAL THROUGHOUT THE BUILDING AT THE TIME OF PARKING GARAGE/PHASE 1 TCO. 2. SPRINKLER SYSTEM WILL BE OPERATIONAL THROUGHOUT THE BUILDING AT THE TIME OF PARKING GARAGE/PHASE 1 TCO. %/'*&216758&7,213+$6,1*3/$1.(< PHASE 1 (BUILDING 1 - PARKING GARAGE): TYPE 1A • INCLUDES ALL LEVELS OF PARKING GARAGE (TYPE 1A) (BLDG 2 PART I- RESIDENTIAL BUILDING) TYPE 3A • INCLUDES LEASING OFFICE • INCLUDES RESIDENTIAL FLOORS (LEVEL 1-5 W/96 UNITS) WHICH WILL BE PERMITTED BY FLOOR AND RECEIVE TCO'S FROM BOTTOM UP. • BASEMENT LEVEL OF RESIDENTIAL BUILDING PHASE 3 (BLDG 3 - RESIDENTIAL BUILDING): TYPE 3A • INCLUDES RESIDENTIAL FLOORS (LEVEL 1-5 W/110 UNITS) WHICH WILL BE PERMITTED BY FLOOR AND RECEIVE TCO'S FROM BOTTOM UP. PHASE 5 (BLDG 4 PART II - RESIDENTIAL BUILDING) TYPE 3A • INCLUDES RESIDENTIAL FLOORS (LEVEL 1-5 W/45 UNITS) WHICH WILL BE PERMITTED BY FLOOR AND RECEIVE TCO'S FROM BOTTOM UP. PHASE 4 (BLDG 4 PART I - RESIDENTIAL BUILDING) TYPE 3A • INCLUDES RESIDENTIAL FLOORS (LEVEL 1-5 W/59 UNITS) WHICH WILL BE PERMITTED BY FLOOR AND RECEIVE TCO'S FROM BOTTOM UP. PHASE 2 (BLDG 2 PART II - RESIDENTIAL BUILDING): TYPE 3A • INCLUDES RESIDENTIAL FLOORS (LEVEL 1-5 W/33 UNITS) WHICH WILL BE PERMITTED BY FLOOR AND RECEIVE TCO'S FROM BOTTOM UP. • INCLUDES CLUBHOUSE, FITNESS AREAS, 5TH FLOOR AMENITY A 333 WEST TRADE STREET R C H I T E C T U R E SUITE 200CHARLOTTE, NC 28202 T 704.927.9900 w w w. a x i o m a r c h i t e c t u r e . c o m REVISIONS PROJECT A-2011 DECEMBER 9, 2021 A0.12 LEVEL 1 PHASING PLAN 75 < & / $ 1  ' 5 , 9 (  $ 1 '  ' H : , 7 7  / $ 1 ( &+ $ 5 / 2 7 7 (   1 2 5 7 +  & $ 5 2 / , 1 $ Lo S o V I L L A G E A P A R T M E N T S 35 2 ) ) , 7 7 ', ; 2 1  3 $ 5 7 1 ( 5 6 ISSUED FOR CONSTRUCTION 12/9/2021 1/16" = 1'-0"A0.12 1 /(9(/3+$6,1*)/2253/$1 12/9/2021 A1 - Parking Garage A2 PARKING GARAGE C B D A2 B C D Appendix B VIMS As-Built Drawings (VM-1, VM-2, VM-3, and VM-4) A 333 WEST TRADE STREET R C H I T E C T U R E SUITE 200CHARLOTTE, NC 28202 T 704.927.9900 w w w. a x i o m a r c h i t e c t u r e . c o m REVISIONS VM-1 TR Y C L A N D R I V E A N D D e W I T T L A N E CH A R L O T T E , N O R T H C A R O L I N A PR O F F I T T - D I X O N P A R T N E R S VAPOR INTRUSION MITIGATION SYSTEM (VIMS) SPECIFICATIONS 1.THIS VAPOR INTRUSION MITIGATION PLAN WAS USED FOR DIRECTION OF VIMS COMPONENT INSTALLATION ONLY AND WAS NOT USED TO GUIDE CONSTRUCTION OF STRUCTURAL COMPONENTS NOT RELATED TO THE VIMS. CONSTRUCTION CONTRACTOR WAS RESPONSIBLE FOR VERIFYING CONSISTENCY OF VIMS DETAILS WITH APPLICABLE STRUCTURAL, ARCHITECTURAL, MECHANICAL, AND PLUMBING PLANS AND RESOLVED INCONSISTENCIES WITH THE DESIGN ENGINEER PRIOR TO VIMS INSTALLATION. THE CONSTRUCTION CONTRACTOR WAS RESPONSIBLE FOR INSTALLING THE VIMS IN ACCORDANCE WITH APPLICABLE BUILDING CODES. 2.CONSTRUCTION CONTRACTORS AND SUB-CONTRACTORS USED "LOW OR NO VOC" PRODUCTS AND MATERIALS, WHEN POSSIBLE. BASED ON INFORMATION PROVIDED BY THE CONTRACTORS, NO PRODUCTS CONTAINING TETRACHLOROETHENE OR TRICHLOROETHENE WERE USED. 3.VIMS VAPOR LINER IS VAPORBLOCK PLUS 20 VAPOR BARRIER MANUFACTURED BY VIAFLEX. THE VAPOR LINER WAS INSTALLED AS SPECIFIED HEREIN AND PER MANUFACTURER INSTALLATION INSTRUCTIONS TO CREATE A CONTINUOUS LINER BELOW GROUND FLOOR SLABS. A BASE COURSE CONSISTING OF CLEAN #57 (OR SIMILAR HIGH PERMEABILITY STONE APPROVED BY THE ENGINEER) WAS INSTALLED BENEATH THE VIMS VAPOR LINER. IN AREAS AROUND THE SUB-SLAB PIPING AND SOIL GAS COLLECTOR MAT, THE BASE COURSE LAYER IS THICK ENOUGH TO COVER THE SUB-SLAB PIPING AND SOIL GAS COLLECTOR MAT WITH A MINIMUM 1-INCH LAYER BELOW THE PIPING AND MAT. IN AREAS WITHOUT PIPING OR SOIL GAS COLLECTOR MAT, THE BASE COURSE IS A MINIMUM OF 3-INCHES THICK. 4.ALL PENETRATIONS WERE SEALED ACCORDING TO VAPOR LINER MANUFACTURER INSTALLATION INSTRUCTIONS AS FOUND IN THE MANUFACTURER INSTALLATION GUIDELINES. SMALL PUNCTURE HOLES WERE SEALED WITH THE VAPORSEAL™TAPE, BUTYL SEAL DOUBLE SIDED TAPE, OR POUR-N-SEAL™AND LARGER HOLES, TEARS, OR DAMAGE WERE REPAIRED USING A PATCH THAT OVERLAPS THE DAMAGED AREA AND THEN TAPED ALONG THE SEAMS. IN AREAS WHERE UTILITY PENETRATIONS (I.E. PIPING, DUCTS, ETC) ARE PRESENT AND THE USE OF TAPING WAS NOT PRACTICAL OR DEEMED AS "INEFFECTIVE" BY THE DESIGN ENGINEER, POUR-N-SEAL WAS POURED INTO FORM TO PATCH THE PENETRATION WITH AN AIRTIGHT SEAL. POUR-N-SEAL™ WAS USED AT ELECTRICAL CONDUIT BANKS ONLY. 5.CONSTRUCTION CONTRACTORS AND SUB-CONTRACTORS AVOIDED THE USE OF TEMPORARY FORM BOARDS THAT PENETRATE THE VAPOR LINER WHERE POSSIBLE. WHERE TEMPORARY FORM BOARDS WERE USED, THE SIZE AND NUMBER OF PENETRATIONS THROUGH THE VAPOR LINER WERE LIMITED AND SMALL DIAMETER STAKES (I.E. SOLID METAL STAKES) WERE USED. IN ALL CASES, AS FORM BOARDS WERE REMOVED, THE CONTRACTOR OR SUB-CONTRACTORS SEALED ALL PENETRATIONS IN ACCORDANCE WITH VAPOR LINER MANUFACTURER INSTALLATION INSTRUCTIONS. NO HOLLOW PIPING WAS USED. 6.VIMS BELOW AND ABOVE GRADE PIPING IS NOT TRAPPED AND IS SLOPED A MINIMUM OF 18 UNIT VERTICAL IN 12 UNITS HORIZONTAL (1% SLOPE) TO GRAVITY DRAIN. SOLID SECTIONS OF HORIZONTAL COLLECTION PIPE WERE SUPPORTED TO PREVENT PIPE SAG OR LOW POINT AND MAINTAIN 1% SLOPE TOWARD SLOTTED SECTIONS TO DRAIN CONDENSATION. HORIZONTAL COLLECTION PIPE CONSISTS OF BOTH THREADED FLUSH JOINT OR GLUE JOINT 3" SCH 40 PVC PIPE WITH 0.020" TO 0.060" SLOT WIDTH AND 1 8" SLOT SPACING AND SOIL GAS COLLECTOR MAT (1" x 12") WITH 3" SCH 40 PVC AT SUB-GRADE FOUNDATION. FOAM PIPE SLEEVES, OR SIMILAR, WERE INSTALLED AROUND HORIZONTAL PORTIONS OF PIPES THAT PENETRATE CONCRETE FOOTERS AND WALLS PER APPLICABLE STRUCTURAL PLANS AND BUILDING CODES, OR AS OTHERWISE DIRECTED BY THE APPLICABLE PLANS AND CONSTRUCTION ENGINEERS. PIPE SLEEVES WERE SEALED TO PREVENT A PREFERENTIAL AIR PATHWAY FROM BELOW THE SLAB INTO THE BUILDING. PLEASE REFER TO SHEET S3.03 IN THE STRUCTURAL DRAWINGS FOR FOOTING DETAILS ADDRESSING VIMS PIPING. 7.3" SCH 40 PVC RISER DUCT PIPING WAS INSTALLED TO CONNECT EACH SLAB PENETRATION LOCATION TO A ROOFTOP EXHAUST DISCHARGE POINT WITH A SYPHON VENTILATOR (SEE DETAIL #15). ABOVE-SLAB RISER DUCT PIPE RUNS BETWEEN THE SLAB PENETRATION AND THE ROOFTOP EXHAUST DISCHARGE WERE INSTALLED PER APPLICABLE NORTH CAROLINA PLUMBING AND BUILDING CODES AND AS SPECIFIED IN THE CONSTRUCTION DOCUMENTS AND DRAWINGS. 8.RISER DUCT PIPING EXTENDS IN A VERTICAL ORIENTATION THROUGH THE BUILDING ROOF AND TERMINATES A MINIMUM OF 2 FT ABOVE THE BUILDING ROOF LINE. AN EMPIRE MODEL STAINLESS STEEL SYPHON VENTILATOR WAS INSTALLED ON THE EXHAUST DISCHARGE END OF EACH RISER DUCT PIPE. AN ADAPTOR COUPLING WAS INSTALLED AT THE DISCHARGE END OF THE 3" RISER DUCT PIPE AND THE VENTILATOR WAS SECURED TO THE PVC RISER IN A VERTICAL ORIENTATION. EXHAUST DISCHARGE LOCATIONS ARE A MINIMUM OF 10 FT FROM ANY OPERABLE OPENING OR AIR INTAKE INTO THE BUILDING. NOTE THAT SOME DISCHARGE LOCATIONS ON THE ROOFTOP DEPICTED IN THE VAPOR INTRUSION MITIGATION PLAN WERE REPOSITIONED AND THE NEW POSITIONS MEET THE REQUIREMENTS PRESENTED ABOVE. AN ELECTRICAL JUNCTION BOX (120V, 60Hz AC REQUIRED) WAS INSTALLED NEAR THE FAN LOCATION ON THE ROOFTOP FOR CONVERSION TO ELECTRIC FANS, IF REQUIRED. ALL WIRING AND ELECTRICAL WAS INSTALLED PER APPLICABLE BUILDING AND ELECTRICAL CODES. VIMS ROOF VENTILATORS WERE INSTALLED IN ACCORDANCE WITH THE MANUFACTURER'S WRITTEN INSTRUCTIONS. 9.ABOVE-SLAB ACCESSIBLE RISER DUCT PIPING IS PERMANENTLY IDENTIFIED BY MEANS OF A TAG OR STENCIL AT A MINIMUM OF ONCE EVERY 10-LINEAR FT WITH "VAPOR MITIGATION - CONTACT MAINTENANCE". THE SYPHON VENTILATORS ARE LABELED WITH "VAPOR MITIGATION SYSTEM - CONTACT MAINTENANCE". 10.INSPECTIONS OF EACH COMPONENT OF THE VIMS WAS CONDUCTED BY THE ENGINEER, OR ENGINEER'S DESIGNEE, TO CONFIRM VIMS COMPONENTS WERE INSTALLED PER THE APPROVED DESIGN. THE INSPECTIONS INCLUDED: (1) INSPECTION OF SUB-SLAB PIPING LAYOUT AND GRAVEL PLACEMENT PRIOR TO INSTALLING VAPOR LINER; (2) INSPECTION OF VAPOR LINER PRIOR TO POURING CONCRETE; (3) INSPECTION OF ABOVE-GRADE PIPING LAYOUT; AND (4) INSPECTION OF FAN AND VENT PIPE CONNECTIONS. THE CONSTRUCTION CONTRACTOR(S) COORDINATED WITH THE ENGINEER TO PERFORM THE REQUIRED INSPECTIONS. NO VIMS COMPONENTS WERE COVERED WITHOUT BEING INSPECTED. PDP-001 VAPOR MITIGATION PLAN SPECIFICATIONS AS-BUILTS ISSUED FOR CONSTRUCTION VAPOR MITIGATION PLAN PREPARED BY: 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology EL L O A P A R T M E N T S FEBRUARY 6, 2024 S:\ A A A - M a s t e r P r o j e c t s \ P r o f f i t t D i x o n - P D P \ P D P - 0 0 1 - T r y c l a n A v e n u e \ V I M S i n s t a l l r e p o r t \ F i g u r e s \ V M P A s - B u i l t s _ 2 . 6 . 2 4 . d w g , v m - 1 s p e c s , S V i n c e n t VIMS VAPOR LINER AND BASE COURSE (TYP)1 BASE COURSE - CLEAN #57 STONE MIN 3" THICK BENEATH VIMS VAPOR LINER VAPOR LINER (SEE SPECIFICATION #3) CONCRETE FLOOR SLAB NTSVM2 SUBBASE SECTION THROUGH EXTERIOR WALL NTSVM2 BRICK OR BUILDING SIDING EXTERNAL WALL (NOT PRESENT AT ALL LOCATIONS) STUD WALL BASE COARSE (SEE SPECIFICATION #3) VAPOR LINER SEALED TO CONCRETE PER MANUFACTURER INSTRUCTIONS. SUBBASE 3 VAPOR LINER EXTENDS ALONG FOOTING EXTERIOR WHERE POSSIBLE AT LOCATIONS WHERE EXTERIOR GRADE IS HIGHER THAN INTERIOR GRADE 4A NTSVM2 2" SCH 40 PVC 90 DEGREE ELBOW VAPOR LINER PENETRATION SEALED TO PIPE PER MANUFACTURER INSTRUCTIONS 2" VENT SCREEN AT END OF PIPE EXTERNAL/STUD WALL (NOT PRESENT IN ALL LOCATIONS) 2" SOLID SCH 40 PVC VACUUM MEASURING POINT VACUUM MONITORING POINT IS POSITIONED SO VENT SCREEN IS AT LEAST 5 FT FROM AN EXTERNAL WALL 2' MIN EXTERNAL/STUD WALL (NOT PRESENT IN ALL LOCATIONS) FLOOR CLEANOUT, ADJUSTABLE, 4" DIA ZURN INDUSTRIES MODEL #CO2450-PV4FLUSH WITH FINISHED FLOOR 4B NTSVM2 2" SCH 40 PVC 90 DEGREE ELBOW VAPOR LINER PENETRATION SEALED TO PIPE PER MANUFACTURER INSTRUCTIONS 2" VENT SCREEN AT END OF PIPE STUD WALL (NOT PRESENT IN ALL LOCATIONS) VACUUM MEASURING POINT THROUGH THICKENED SLAB FLOOR CLEANOUT, ADJUSTABLE, 4" DIA ZURN INDUSTRIES MODEL #CO2450-PV4 FLUSH WITH FINISHED FLOOR 2" SOLID SCH 40 PVC - PIPE SLEEVES INCLUDED WHEN APPLICABLE; SEE SPECIFICATION #6 VAPOR LINER PENETRATION SEALED TO PIPE PER MANUFACTURER INSTRUCTIONS STUD WALL (NOT PRESENT IN ALL LOCATIONS) VAPOR LINER BENEATH THICKENED SLAB HORIZONTAL PIPE THROUGH THICKENED SLAB TOP OF THICKENED SLAB TURNDOWN FIRE WALL (NOT PRESENT IN ALL LOCATIONS) 3" SOLID SCH 40 PVC - INCLUDE PIPE SLEEVES WHEN APPLICABLE; SEE SPECIFICATION #6 6 VM2 NTS SLOTTED 3" SCH 40 PVC SOLID TO SLOTTED 3" SCH 40 PVC PIPE TRANSITION (SLIP COUPLING OR THREADED JOINT) VIMS VACUUM MEASURING POINT - DETAIL VIEW NTSVM2 5 FINISHED FLOOR SLAB 2" SCH 40 PVC SET WITHIN GRAVEL LAYER (SEE DETAILS 4A & 4B) 2" DRAIN EXPANSION TEST PLUG BASE COURSE (SEE SPECIFICATION #3) FLOOR CLEANOUT, ADJUSTABLE, 4" DIA ZURN INDUSTRIES MODEL #CO2450-PV4 FLUSH WITH FINISHED FLOOR 4" x 2" FLUSH REDUCER BUSHING VAPOR BARRIER PENETRATION SEALED TO PIPE PER MANUFACTURER INSTRUCTIONS 2" SCH 40 PVC 90 DEGREE STREET ELBOW VERTICAL RISER AT SLAB PENETRATION WITH 90 DEGREE ELBOW NTS VAPOR LINER PENETRATION SEALED TO PIPE PER MANUFACTURER INSTRUCTIONS 3" SCH 40 PVC 90 DEGREE ELBOW STUD WALL 3" SCH 40 PVC RISER DUCT PIPE (SEE SPECIFICATION #8 & #9) BASE COARSE (SEE SPECIFICATION #3) THICKENED SLAB MAY NOT BE PRESENT IN ALL LOCATIONS 3" SOLID SCH 40 PVC (SEE SPECIFICATION #6) VM2 8A SOIL GAS COLLECTOR MAT TO SOLID 3" SCH 40 PVC CONNECTION VERTICAL RISER AT SLAB PENETRATION WITH TEE NTS VAPOR LINER PENETRATION SEALED TO PIPE PER MANUFACTURER INSTRUCTIONS 3" TO 4" SCH 40 PVC 90 DEGREE TEE STUD WALL 3" SCH 40 PVC RISER DUCT PIPE (SEE SPECIFICATION #8 & #9) THICKENED SLAB MAY NOT BE PRESENT IN ALL LOCATIONS 3" SOLID SCH 40 PVC (SEE SPECIFICATION #6) 10 VM2 SOLID TO SLOTTED 3" SCH 40 PVC PIPE TRANSITION (SLIP COUPLING OR THREADED JOINT) BASE COURSE BASE COURSE (SEE SPECIFICATION #3) VAPOR BARRIER SEALED TO CONCRETE PER MANUFACTURER INSTRUCTIONS VAPOR LINER SEALED TO COLUMN PER MANUFACTURER INSTRUCTIONS TYPICAL VIMS LINER ABOVE COLUMN FOOTING11 NTSVM2 TYPICAL VIMS LINER AT ELEVATOR PIT12 NTSVM2 ELEVATOR PARKING GARAGE (BASEMENT) STAIRWELL PARKING GARAGE (BASEMENT) VAPOR LINER SUB-BASE VAPOR LINER SEALED TO WATERPROOFING VAPOR LINER VIMS SYPHON VENTILATOR & EXHAUST (TYP)15 VM2 NTS ELECTRICAL JUNCTION BOX FOR POTENTIAL FUTURE VACUUM FAN (REFER TO SPECIFICATION #8) RISER DUCT PIPE THROUGH ROOF FLASHING ROOFTOP 4" X3" HEAVY DUTY NO HUB COUPLING 4" SYPHON VENTILATOR (EMPIRE SYPHON VENTILATOR OR ENGINEER APPROVED EQUIVALENT) GROUND FLOOR INTERIOR SPACE BASEMENT LEVEL HALLWAY SUB-BASE CONCRETE FLOOR SLAB BASE COURSE (SEE SPECIFICATION #3) VAPOR LINER (SEE SPECIFICATION #3) VAPOR LINER SEALED TO OUTSIDE OF CONCRETE AND WATERPROOFING/INSULATION (WHERE PRESENT) PER MANUFACTURER INSTRUCTIONS WATERPROOFING AND RIGID INSULATION DRAIN STUD/SHEAR WALL VIMS AT RETAINING WALL13 NTSVM2 THICKENED SLAB TRANSITION7 NTSVM2 BASE COARSE (SEE SPECIFICATION #3) FIRE WALL PRESENT IN SOME AREAS STUD WALL VAPOR LINER PENETRATION SEALED TO PIPE PER MANUFACTURER INSTRUCTIONS 3" SCH 40 PVC 45 DEGREE ELBOW SLAB STEP HEIGHT VARIES 3" SOLID SCH 40 PVC (SEE SPECIFICATION #6) SOLID TO SLOTTED 3" SCH 40 PVC PIPE TRANSITION (SLIP COUPLING OR THREADED JOINT) SOLID TO SLOTTED 3" SCH 40 PVC PIPE TRANSITION (SLIP COUPLING OR THREADED JOINT) VIMS PIPING THROUGH SLAB DROP WITH RISER DUCT PIPING (TYP) NTS 9 VM2 SUB-BASE VAPOR LINER BASE COURSE (SEE SPECIFICATION #3) SOLID TO SLOTTED 3" SCH 40 PVC PIPE TRANSITION (SLIP COUPLING OR THREADED JOINT) 3" SCH 40 PVC 90-DEGREE ELBOW VAPOR LINER SEALED TO PIPE PER MANUFACTURER INSTRUCTIONS SOLID 3" SCH 40 PVC (SEE SPECIFICATION #7)STUD WALLS SOLID 3" SCH 40 PVC RISER DUCT PIPE (SEE SPECIFICATION #2) 3" SCH 40 PVC 90-DEGREE TEE SECTION THROUGH SLAB EDGE AT PARKING GARAGE NTSVM2 STUD WALL BASE COARSE (SEE SPECIFICATION #3) VAPOR LINER SEALED TO CONCRETE PER MANUFACTURER INSTRUCTIONS. SUBBASE 14 VAPOR LINER SHALL EXTEND ALONG FOOTING EXTERIOR TO SLAB GRADE CONDITION VARIES AT PARKING GARAGE SUB-BASE SLOTTED COLLECTION PIPE (TYP)2 NTSVM-2 PVC TERMINATION SCREEN CONCRETE FLOOR SLAB VAPOR BARRIER (SPECIFICATION #3) 3" SCH 40 THREADED FLUSH JOINT SLOTTED PVC PIPE OR SOIL GAS COLLECTOR MAT SET WITHIN MIN 4" BASE COURSE (SEE SPECIFICATION #3) VERTICAL RISER AT SLAB PENETRATION WITH 90 DEGREE ELBOW NTS VAPOR LINER PENETRATION SEALED TO PIPE PER MANUFACTURER INSTRUCTIONS 3" SCH 40 PVC 90 DEGREE ELBOW STUD WALL 3" SCH 40 PVC RISER DUCT PIPE (SEE SPECIFICATION #8 & #9) BASE COARSE (SEE SPECIFICATION #3) THICKENED SLAB MAY NOT BE PRESENT IN ALL LOCATIONS 3" SOLID SCH 40 PVC (SEE SPECIFICATION #7) VM2 8 SOLID TO SLOTTED 3" SCH 40 PVC PIPE TRANSITION (SLIP COUPLING OR THREADED JOINT) A 333 WEST TRADE STREET R C H I T E C T U R E SUITE 200CHARLOTTE, NC 28202 T 704.927.9900 w w w. a x i o m a r c h i t e c t u r e . c o m REVISIONS PDP-001 VM-2 VAPOR MITIGATION PLAN DETAILS AS-BUILTS TR Y C L A N D R I V E A N D D e W I T T L A N E CH A R L O T T E , N O R T H C A R O L I N A EL L O A P A R T M E N T S PR O F F I T T - D I X O N P A R T N E R S VAPOR MITIGATION PLAN PREPARED BY: 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology ISSUED FOR CONSTRUCTION FEBRUARY 7, 2024 S:\ A A A - M a s t e r P r o j e c t s \ P r o f f i t t D i x o n - P D P \ P D P - 0 0 1 - T r y c l a n A v e n u e \ V I M S i n s t a l l r e p o r t \ F i g u r e s \ V M P A s - B u i l t s _ 2 . 6 . 2 4 . d w g , v m - 2 d e t a i l s , S V i n c e n t C C UP 10' X 25' LOADING SPACE BUILDING ABOVE BUILDING ABOVE BUILDING ABOVE GARAGE VENTILATION SHAFT 715.00 715.00 UP POOL EQUIP. CH E M S T O R TRASH ROOM MAIN ELEC ROOM MAINTENANCE OFFICE TLT BIKE STORAGE 720.50 DOG SPA BASEMENT ENTRY LOBBY MP-1 MP-2/ MP-DUP TMP-1 TMP-2 E-1 E-2 A1B-IAS-2 A1B-IAS-1/ IAS-DUP A 333 WEST TRADE STREET R C H I T E C T U R E SUITE 200CHARLOTTE, NC 28202 T 704.927.9900 REVISIONS VM-3 TR Y C L A N D R I V E A N D D e W I T T L A N E CH A R L O T T E , N O R T H C A R O L I N A PR O F F I T T - D I X O N P A R T N E R S 1/16" = 1'-0"A2.1 1 BASEMENT FLOOR PLAN N LEGEND EXTENT OF VAPOR LINER 3" DIA SCH 40 SLOTTED PVC PIPE 3" DIA SCH 40 SOLID PVC VERTICAL RISER WITH FAN IDENTIFICATION NUMBER (REFER TO DETAIL #15 ON VM-2) 2" DIA SOLID PVC PRESSURE MONITORING POINT WITH FLUSH-MOUNTED COVER 2" DIA SOLID PVC PRESSURE MONITORING POINT WITH FLUSH-MOUNTED COVER - SUB-SLAB SOIL GAS SAMPLE LOCATION INDOOR AIR SAMPLE LOCATION VIMS INSTALLATION COMPLETE. VIMS INSTALLATION REPORT PREVIOUSLY PROVIDED TO NCDEQ E-7 TMP-2 MP-1 w w w. a x i o m a r c h i t e c t u r e . c o m PDP-001 VAPOR MITIGATION PLAN SUB-SLAB LAYOUT - BASEMENT AS-BUILTS VAPOR MITIGATION PLAN PREPARED BY: 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology 3 VM2 2 VM2 1 VM2 4A VM2 12 VM2 13 VM2 8 VM2 8 VM2 14 VM2 ISSUED FOR CONSTRUCTION EL L O A P A R T M E N T S FEBRUARY 6, 2024 S:\ A A A - M a s t e r P r o j e c t s \ P r o f f i t t D i x o n - P D P \ P D P - 0 0 1 - T r y c l a n A v e n u e \ V I M S i n s t a l l r e p o r t \ F i g u r e s \ V M P A s - B u i l t s _ 2 . 6 . 2 4 . d w g , v m - 3 b a s e m e n t , S V i n c e n t UP UP UP DN DN DN DN BA C K F L O W / SP R I N K L E R PU M P R O O M DN DN 725.40 725.10 GARAGE VENTILATION SHAFT ELECT/D MECH MECH ELEC TRASH MECH T/D 725.92 725.00 DN 725.00 THE FRONT PORCH 727.00 ELEC. MECH TELE/DATA DN DN GARAGE VENTILATION SHAFT A3.2 158 A1.4 163 A1.4 161 C2.3-HC 159 A8 157 A3.5 129 B1 127 C2.2 125 A1.3 123 A7 121 A1.3 119 A6 117 A6 115 C2 113 B1 105 A3 111 A1 100 A2 102 A2.2 104 A2 106 C2 107 C6 108A6 110A6 112 A6.1 134 A1.1 150C5 149 A1.2 145 A1.2 144 A1.2 139 A6.2 135 C4 137 C4 136 A1.2 140 A3.1 141 A3.1 147 A3.1 142 A1.2 146 A1.2 143 A3.1 148 A3.6 118 C7 138 C2.3 126 A5 120 A3.6 116 C2 151 A3.6 114 A3.2 160 A3.2 162 A3.2 164 A3.4 101 A3.4 103 A3.5 128 A3.4-HC 124 A3.4 122 LEASING 141 LOUNGE 153 725.30 726.50 724.30 A3 130 DSDS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS DS A1.3 133 A1.3 132 A1.3 131 726.00 726.00 OVERSIZED PACKAGE MECH PACKAGE STAIR 5 MECH EL E C . CO R R I D O R CORRIDOR CORRIDOR CO R R I D O R STAIR 1 ELEV LOBBY STAIR 4 CORRIDOR STAIR 3 STAIR 2 ELEV LOBBY A1.5 109 FITNESS YOGA RYTEK HIGH SPEED ROLL UP AUTOMOBILE GATES POOL COURTYARD DR Y SP R I N K L E R RO O M COWORKING MECH AWNING ABOVE AWNING ABOVE TE L / DA T A BUILDING PLAN NOTES1.2.3.4.ALL UNDESIGNATED DIMENSIONED INTERIOR WALLS TO BE 31/2" WOOD STUD.EXTERIOR WALLS & PLUMBING WALLS TO BE 5 1/2".ALL UNDIMENSIONED DOORS TO BE CENTERED OR TO BELOCATED 4 1/2" OFF SIDE WALL FRAMING TO FACE OF DOOR.SEE 1/4" UNIT PLANS FOR INTERIOR WALL LOCATIONS ANDADDITIONAL DETAILS.REFERENCE WALL TYPE SHEET (A7.0 - A7.15) FOR ALLINFORMATION ON CORRESPONDING WALL TAGS.11.REFER TO FINISH SCHEDULE FOR ALL INTERIOR WALL FINISHMATERIALS.12.SEE INTERIOR DESIGN DRAWINGS FOR ALL CEILING HEIGHTS,FINISHES, ETC. AT ALL AMENITY AREAS.13.PROVIDE TRANSITION STRIPS (SCHLUTER OR EQUAL) BETWEENDISSIMILAR FLOOR MATERIALS, ELEVATION CHANGE BETWEENTWO MATERIALS IS 1/2" MAX.14. SEE A12.2 FOR ALL TYPICAL ACCESSIBILITY DETAILS FOR ALLCOMMON AREAS.15.PROVIDE BLOCKING IN WALLS AS REQUIRED TO MEET ALLACCESSIBILITY REQUIREMENTS (SEE A12.0 - A12.2), AND ASNEEDED FOR SUPPORT OF CABINETS, SHELVES, HANDRAILS,ETC.5.ALL INTERIOR WOOD BEARING WALLS TO BE 1 HOUR FIRERATED (UL #305) - REFERENCE STRUCTURAL DRAWINGS FORALL LOCATIONS.6.ALL CORRIDOR TO UNIT WALLS TO BE 1 HOUR FIRE RATED -SEE WALL TYPE DESIGNATIONS AND SEE STRUCTURALDRAWINGS FOR SHEAR WALL LOCATIONS.7. ALL WOOD FRAME BALCONIES TO SLOPE 1/4" PER FOOT TOBALCONY EDGE SCUPPER OR DRAIN. ALL CONCRETEBALCONIES / TERRACES TO SLOPE 1/8" PER FOOT TOBALCONYEDGE, SCUPPER OR DRAIN.8.EXTERIOR FACE OF MASONRY VENEER SHALL BE 5 1/2” FROMEXTERIOR FACE OF FRAMING / CMU, UNLESS OTHERWISENOTED. MAINTAIN 1” MIN. AIRSPACE AT ALL MASONRYVENEER.9.SEE GRADING PLAN (CIVIL SHEETS) FOR BUILDING ENTRYELEVATION AND SITE WALL DIMENSIONS AND LOCATIONS.10.SEE ELECTRICAL PLANS FOR BUILDING ELECTRICAL LAYOUTS. MP-7 MP-5 MP-4 MP-3 TMP-5 MP-6/SS-DUP MP-8 MP-9 MP-10 MP-12 MP-13 MP-14 MP-11 VAN VAN VA N SPRINKLER/ PUMP ROOM UP UP DN GARAGE VENTILATION SHAFT GARAGE VENTILATION SHAFT 732.39 TMP-4 E-11 E-10 E-22 E-8 E-9 E-19 E-16 E-13 E-14 E-15 E-17 E-18 E-3 E-4 E-5 E-6 E-7 E-12 E-21 E-20 A1-IAS-1 A1-IAS-2/IAS-DUP B-IAS-1 B-IAS-BKG IAS-BKG D-IAS-1 C-IAS-1 / IAS-DUP TMP-3 A 333 WEST TRADE STREET R C H I T E C T U R E SUITE 200CHARLOTTE, NC 28202 T 704.927.9900 w w w. a x i o m a r c h i t e c t u r e . c o m REVISIONS VM-4 TR Y C L A N D R I V E A N D D e W I T T L A N E CH A R L O T T E , N O R T H C A R O L I N A PR O F F I T T - D I X O N P A R T N E R S 1/16" = 1'-0"A2.1 1 LEVEL 1 FLOOR PLAN N LEGEND EXTENT OF VAPOR LINER 3" DIA SCH 40 SLOTTED PVC PIPE SOIL GAS COLLECTOR MAT (1" THICK AND 12" WIDE) 3" DIA SCH 40 SOLID PVC VERTICAL RISER WITH FAN IDENTIFICATION NUMBER (REFER TO DETAIL #15 ON VM-2) 2" DIA SOLID PVC PRESSURE MONITORING POINT WITH FLUSH-MOUNTED COVER 2" DIA SOLID PVC TEMPORARY MONITORING POINT 2" DIA SOLID PVC PRESSURE MONITORING POINT WITH FLUSH-MOUNTED COVER - SUB-SLAB SOIL GAS SAMPLE LOCATION INDOOR AIR SAMPLE LOCATION AREA C & D BUILDING CONSTRUCTION PHASE VIMS INSTALLATION COMPLETE. VIMS INSTALLATION REPORT PREVIOUSLY PROVIDED TO NCDEQ E-5 MP-4 MP-5 MARCH 26, 2024 PDP-001 VAPOR MITIGATION PLAN SUB-SLAB LAYOUT - FIRST FLOOR AS-BUILTS VAPOR MITIGATION PLAN PREPARED BY: 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology 1 VM2 1 VM2 2 VM2 2 VM2 3 VM2 3 VM2 4A VM2 4A VM2 4B VM2 4B VM2 6 VM2 6 VM2 10 VM2 10 VM2 8 VM2 8A VM2 11 VM2 13 VM2 9 VM2 7 VM2 14 VM2 ISSUED FOR CONSTRUCTION 7 VM2 D-IAS-1 EL L O A P A R T M E N T S TMP-3 S:\ A A A - M a s t e r P r o j e c t s \ P r o f f i t t D i x o n - P D P \ P D P - 0 0 1 - T r y c l a n A v e n u e \ V I M S i n s t a l l r e p o r t \ F i g u r e s \ V M P A s - B u i l t s _ 2 . 6 . 2 4 _ C D . d w g , v m - 4 f l o o r 1 , S V i n c e n t Appendix C Product Specifications PRODUCT PART # VaporBlock® Plus™ 20 ................................................................ VBP20 UNDER-SLAB VAPOR / GAS BARRIER Under-Slab Vapor/Gas Retarder VAPORBLOCK® PLUS™VBP20 PRODUCT DESCRIPTION VaporBlock® Plus™ is a seven-layer co-extruded barrier made using high quality virgin-grade polyethylene and EVOH resins to provide unmatched impact strength as well as superior resistance to gas and moisture transmission. VaporBlock® Plus™ 20 is more than 100 times less permeable than typical high-performance polyethylene vapor retarders against Methane, Radon, and other harmful VOCs. Tested and verified for unsurpassed protection against BTEX, HS, TCE, PCE, methane, radon, other toxic chemicals and odors. VaporBlock® Plus™ 20 multi-layer gas barrier is manufactured with the latest EVOH barrier technology to mitigate hazardous vapor intrusion from damaging indoor air quality, and the safety and health of building occupants. VBP20 is one of the most effective underslab gas barriers in the building industry today far exceeding ASTM E-1745 (Plastic Water Vapor Retarders Used in Contact with Soil or Granular Fill Under Concrete Slabs) Class A, B and C requirements. Available in a 20 (Class A) mil thicknesses designed to meet the most stringent requirements. VaporBlock® Plus™ 20 is produced within the strict guidelines of our ISO 9001 Certified Management System. PRODUCT USE VaporBlock® Plus™ 20 resists gas and moisture migration into the building envelop when properly installed to provide protection from toxic/harmful chemicals. It can be installed as part of a passive or active control system extending across the entire building including floors, walls and crawl spaces. When installed as a passive system it is recommended to also include a ventilated system with sump(s) that could be converted to an active control system with properly designed ventilation fans. VaporBlock® Plus™ 20 works to protect your flooring and other moisture-sensitive furnishings in the building’s interior from moisture and water vapor migration, greatly reducing condensation, mold and degradation. SIZE & PACKAGING VaporBlock® Plus™ 20 is available in 10’ x 150’ rolls to maximize coverage. All rolls are folded on heavy-duty cores for ease in handling and installation. Other custom sizes with factory welded seams are available based on minimum volume requirements. Installation instructions and ASTM E-1745 classifications accompany each roll. © 2022 VIAFLEX, INC. All rights reserved. APPLICATIONS Radon Barrier Methane Barrier VOC Barrier Brownfields Barrier Vapor Intrusion Barrier Under-Slab Vapor Retarder Foundation Wall Vapor Retarder VaporBlock® Plus™ is a seven-layer co-extruded barrier made using high quality virgin-grade polyethylene and EVOH resins to provide unmatched impact strength as well as superior resistance to gas and moisture transmission. VaporBlock® Plus™ Placement All instructions on architectural or structural drawings should be reviewed and followed. Detailed installation instructions accompany each roll of VaporBlock® Plus™ and can also be located at www.ravenefd.com. ASTM E-1643 also provides general installation information for vapor retarders. VAPORBLOCK® PLUS™ 20 PROPERTIES TEST METHOD IMPERIAL METRIC AppeArAnce White/Gold Thickness, nominAl 20 mil 0.51 mm WeighT 102 lbs/MSF 498 g/m² clAssificATion ASTM E 1745 CLASS A, B & C ³ Tensile sTrengTh ASTM E 154Section 9(D-882)58 lbf 102 N impAcT resisTAnce ASTM D 1709 2600 g permeAnce (neW mATeriAl) ASTM E 154Section 7ASTM E 96Procedure B 0.0098 Perms grains/(ft²·hr·in·Hg) 0.0064 Perms g/(24hr·m²·mm Hg) permeAnce (AfTer condiTioning) (sAme meAsuremenT As Above permeAnce) ASTM E 154Section 8, E96Section 11, E96Section 12, E96Section 13, E96 0.00790.00790.00970.0113 0.00520.00520.00640.0074 WvTr ASTM E 96Procedure B 0.0040 grains/hr-ft²0.0028 gm/hr-m² benzene permeAnce See Note ⁶1.13 x 10-¹⁰ m²/sec or 3.62 x 10-¹³ m/s Toluene permeAnce See Note ⁶1.57 x 10-¹⁰ m²/sec or 1.46 x 10-¹³ m/s eThylbenzene permeAnce See Note ⁶1.23 x 10-¹⁰ m²/sec or 3.34 x 10-¹⁴ m/s m & p-Xylenes permeAnce See Note ⁶1.17 x 10-¹⁰ m²/sec or 3.81 x 10-¹⁴ m/s o-Xylene permeAnce See Note ⁶1.10 x 10-¹⁰ m²/sec or 3.43 x 10-¹⁴ m/s hydrogen sulfide See Note 9 1.92E-⁰⁹ m/s TrichloroeThylene (Tce) See Note ⁶7.66 x 10-¹¹ m²/sec or 1.05 x 10-¹⁴ m/s perchloroeThylene (pce)See Note ⁶7.22 x 10-¹¹ m²/sec or 1.04 x 10-¹⁴ m/s rAdon diffusion coeffiecienT K124/02/95 < 1.1 x 10-13 m2/s meThAne permeAnce ASTM D 1434 3.68E-¹² m/sGas Transmission Rate (GTR):0.32 mL/m²•day•atm mAXimum sTATic use TemperATure 180° F 82° C minimum sTATic use TemperATure - 70° F - 57° C UNDER-SLAB VAPOR / GAS BARRIER VAPORBLOCK® PLUS™VBP20 ³ Tests are an average of machine and transverse directions.5 Raven Industries performs seam testing at 20” per minute.6 Aqueous Phase Film Permeance. Permeation of Volatile Organic Compounds through EVOH Thin Film Membranes and Coextruded LLDPE/EVOH/ LLDPE Geomembranes, McWatters and Rowe, Journal of Geotechnical and Geoenvironmental Engineering© ASCE/ September 2015. (Permeation is the Permeation Coefficient adjusted to actual film thickness - calculated at 1 kg/m³.) The study used to determine PCE and TCE is titled: Evaluation of diffusion of PCE & TCE through high performance geomembranes by Di Battista and Rowe, Queens University 8 Feb 2018.9 The study used to determine diffusion coefficients is titled: Hydrogen Sulfide (H₂S) Transport through Simulated Interim Covers with Conventional and Co-Extruded Ethylene-Vinyl Alcohol (EVOH) Geomembranes. Scan QR Code to download technical data sheets. Note: To the best of our knowledge, unless otherwise stated, these are typical property values and are intended as guides only, not as specification limits. Chemical resistance, odor transmission, longevity as well as other performance criteria is not implied or given and actual testing must be performed for applicability in specific applications and/or conditions. VIAFLEX MAKES NO WARRANTIES AS TO THE FITNESS FOR A SPECIFIC USE OR MERCHANTABILITY OF PRODUCTS REFERRED TO, no guarantee of satisfactory results from reliance upon contained information or recommendations and disclaims all liability for resulting loss or damage. Limited Warranty available at www.viaflex.com VIAFLEX, INC.821 W Algonquin Street Sioux Falls, SD 57104 Ph: +1 (605) 335-0174 • TF: +1 (800) 635-3456© 2022 VIAFLEX, INC. All rights reserved.27-0123 09/22 sales@viaflex.com www.viaflex.com INSTALLATION GUIDELINES - With VaporSeal™ Tape VaporSeal™ 4” Tape Optional Butyl Seal 2-Sided Tape Elements of a moisture/gas-resistant floor system. General illustration only.(Note: This example shows multiple options for waterstop placement. VaporSeal™ 4” Tape VaporSeal™ 4” Tape Fig. 2: VaporBlock® Plus™ Overlap Joint Sealing Methods Fig. 1: VaporBlock® Plus™ Overlapping Roll-out Method Please Note: Read these instructions thoroughly before installation to ensure proper use of VaporBlock® Plus™. ASTM E 1465, ASTM E 2121 and, ASTM E 1643 also provide valuable information regarding the installation of vapor / gas barriers. When installing this product, contractors shall conform to all applicable local, state and federal regulations and laws pertaining to residential and commercial building construction. • When VaporBlock® Plus™ gas barrier is usedas part of an active control system for radon orother gas, a ventilation system will be required. • If designed as a passive system, it is recommended to install a ventilation system that could beconverted to an active system if needed. Materials List:VaporBlock® Plus™ Vapor / Gas BarrierVaporSeal™* 4” Seaming TapeVaporSeal™* 12” Seaming/Repair TapeButyl Seal 2-Sided TapeVaporBoot Plus Pipe Boots 12/Box (recommended)VaporBoot Tape (optional)POUR-N-SEAL™ (optional)1” Foam Weather Stripping (optional)Mako® Screed Supports (optional) VAPORBLOCK® PLUS™ PLACEMENT 1.1. Level and tamp or roll granular base as specified. A base for a gas-reduction system may require a 4” to 6” gas permeable layer of clean coarse aggregate as specified by your architectural or structural drawings after installation of the recommended gas collection system. In this situation, a cushion layer consisting of a non-woven geotextile fabric placed directly under VaporBlock® Plus™ will help protect the barrier from damage due to possible sharp coarse aggregate. 1.2. Unroll VaporBlock® Plus™ running the longest dimension parallel with the direction of the pour and pull open all folds to full width. (Fig. 1) 1.3. Lap VaporBlock® Plus™ over the footings and seal with VIAFLEX Butyl Seal tape at the footing-wall connection. Prime concrete surfaces, when necessary, and assure they are dry and clean prior to applying VIAFLEX Butyl Seal Tape. Apply even and firm pressure with a rubber roller. Overlap joints a minimum of 6” and seal overlap with 4” VaporSeal™ Tape. When used as a gas barrier, overlap joints a minimum of 12” and seal in-between overlap with an optional 2-sided VIAFLEX Butyl Seal Tape. Then seal with 4” VaporSeal™ Tape centered on the overlap seam. (Fig. 2) Page 1 of 4 To p o r i g i n a l d i a g r a m a n d f i g u r e # 1 w e r e r e p r i n t e d w i t h p e r m i s s i o n b y t h e P o r t l a n d C e m e n t A s s o c i a t i o n . Re f e r e n c e : K a n a r e , H o w a r d M . , C o n c r e t e F l o o r s a n d M o i s t u r e , E B 11 9 , P o r t l a n d C e m e n t A s s o c i a t i o n , S k o k i e , I l l i n o i s , a n d N a t i o n a l R e a d y M i x e d C o n c r e t e A s s o c i a t i o n , S i l v e r S p r i n g , M a r y l a n d , U S A , 2 0 0 8 , 1 7 6 p a g e s . 1.4. Seal around all plumbing, conduit, support columns or other penetrations that come through the VaporBlock® Plus™ membrane. 1.4a. Method 1: Pipes four inches or smaller can be sealed with VIAFLEX VaporBoot Plus preformed pipe boots. VaporBoot Plus preformed pipe boots are formed in steps for 1”, 2”, 3” and 4” PVC pipe or IPS size and are sold in units of 12 per box (Fig. 3 & 5). Pipe boots may also be fabricated from excess VaporBlock® Plus™ membrane (Fig. 4 & 6) and sealed with VaporBoot Tape or VaporSeal™ Tape (sold separately). 1.4b. Method 2: To fabricate pipe boots from VaporBlock® Plus™ excess material (see Fig. 4 & 6 for A-F): A)Cut a square large enough to overlap 12” in all directions. B) Mark where to cut opening on the center of the square and cut four to eight slices about 3/8” less than the diameter of the pipe. C) Force the square over the pipe leaving the tightly stretched cut area around the bottom of the pipe with approximately a 1/2” of the boot material running vertically up the pipe. (no more than a 1/2” of stretched boot material is recommended) D) Once boot is positioned, seal the perimeter to the membrane by applying 2-sided VIAFLEX Butyl Seal Tape in between the two layers. Secure boot down firmly over the membrane taking care not to have any large folds or creases. E) Use VaporBoot Tape or VaporSeal™ Tape to secure the boot to the pipe. VaporBoot Tape (option) – fold tape in half lengthwise, remove half of the release liner and wrap around the pipe allowing 1” extra for overlap sealing. Peel off the second half of the release liner and work the tape outward gradually forming a complete seal. VaporSeal™ Tape (option) - Tape completely around pipe overlapping the VaporBlock® Plus™ square to create a tight seal against the pipe. F) Complete the process by taping over the boot perimeter edge with VaporSeal™ Tape to create a monolithic membrane between the surface of the slab and gas/moisture sources below and at the slab perimeter. (Fig. 4 & 6) Preformed Pipe Boot Square Material Pipe Boot Fig. 3 SINGLE PENETRATION PIPE BOOT INSTALLATION Fig. 5 Fig. 6 1. Cut a square of VaporBlock® Plus™ barrier to extend at least12” from the pipe in all directions. 2. Cut four to eight slices about 3/8”less than the diameter of the pipe. 5. Use VIAFLEX VaporBoot orVaporSeal™ Tape andoverlap 1” at the seam. 4. Tape over the bootperimeter edge withVaporSeal™ Tape. 1. Cut out one of thepreformed boot steps(1” to 4”). 2. Tape the underside bootperimeter with 2-sidedButyl Seal Tape. 3. Force the boot overpipe and press tapefirmly in place. 4. Use VaporSeal™ Tape to secure boot to thepipe. 5. Tape around entire bootedge with VaporSeal™Tape. VaporBoot Flexible Tapeor VaporSeal™ 4” TapeVaporSeal™ 4” Tape VaporBlock® Plus™Material VaporSeal™ 4” Tape VIAFLEX Butyl Seal2-Sided Tape VIAFLEX Butyl Seal2-Sided Tape VaporBoot PlusPreformed Boot 12”(minimum) 3. Force over pipe and tape theunderside boot perimeter toexisting barrier with 2-sidedButyl Seal Tape. Fig. 4 Page 2 of 4 Or i g i n a l f i g u r e # 4 d i a g r a m i s r e p r i n t e d w i t h p e r m i s s i o n b y t h e P or t l a n d C e m e n t A s s o c i a t i o n . Method 1 Method 2 VaporSeal™4” Tape VaporBoot PlusPerformed Boot VIAFLEX Butyl Seal 2-sided Tape VIAFLEX Butyl Seal 2-sided Tape 1.5. Sealing side-by-side multiple penetrations (option 1); A) Cut a patch large enough to overlap 12” in all directions (Fig. 7) of penetrations. B) Mark where to cut openings and cut four to eight slices about 3/8” less than the diameter of the penetration for each. C)Force patch material over penetration to achieve a tight fit and form a lip. D) Once patch is positioned, seal the perimeter to the membrane by applying 2-sided VIAFLEX Butyl Seal Tape in-between the two layers. (Fig. 8) E) After applying VIAFLEX Butyl Seal Tape between the patch and membrane, tape around each of the penetrations and the patch with VaporSeal™ 4” tape. (Fig. 9) For additional protection apply POUR-N-SEAL™ or an acceptable polyurethane elastomeric sealant around the penetrations. (Fig. 10) Fig. 7 Fig. 8 Fig. 9 Fig. 10 MULTIPLE PENETRATION PIPE BOOT INSTALLATION Fig. 6 Cut a patch large enough to overlap 12” in all directions and slide over penetrations (Make openings as tight as possible.) Once the overlay patch is positioned, seal the perimeter to the membrane by applying 2-sided VIAFLEX Butyl Seal Tape in-between the two layers. After applying VIAFLEX Butyl Seal Tape between the patch and membrane, tape around the perimeter of the penetration and the patch with VaporSeal™ 4” Tape. For additional protection apply POUR-N-SEAL™ or an acceptable polyurethane elastomeric sealant around the penetrations. VaporSeal™ 4” Tape VaporSeal™ 4” Tape Page 3 of 4 Option 1 VIAFLEX Butyl Seal 2-sided Tape 1.6. POUR-N-SEAL™ method of sealing side-by-side multiple penetrations (option 2); A) Install the vapor barrier as closely as possible to pipe penetrations tominimize the amount of POUR-N-SEAL™ necessary to seal around allpenetrations. B) Once barrier is in place, remove soil or other particles with a dry clothor a fine broom to allow for improved adhesion to the POUR-N-SEAL™ liquid. C) Create a dam around the penetration area approximately 2” awayfrom the pipe or other vertical penetrations by removing the releaseliner from the back of a 1” weather stripping foam and adhere to thevapor barrier. Form a complete circle to contain the POUR-N-SEAL™materials (Fig. 11). D) Once mixed, pour contents around the pipe penetrations. If needed,a brush or a flat wooden stick can be used to direct the sealantcompletely around penetrations creating a complete seal (Fig. 12-13). E) DO NOT leave excess POUR-N-SEAL™ in plastic container for longerthan the time it takes to pour sealant. Fig. 12 Fig. 13 Fig. 11 Option 2 VAPORBLOCK® PLUS™ REPAIR INSTRUCTIONS 1.7. Proper installation requires all holes and openings are repaired prior to placing concrete. When patching small holes, simply cut a 12” long piece of 12” wide VaporSeal™ tape. Remove release liner and center over the opening. Apply pressure to create a seal (Fig. 14-15). 1.8. When installing VaporBlock® Plus™ around pipe penetrations, vertical columns, electrical ducts and other obstructions, you will find it necessary to cut it to the nearest outside edge. This cut can be easily sealed with 12” wide VaporSeal™ tape, by simply centering it over the cut, 6” on either side. Once the tape is placed correctly, apply pressure to assure a complete seal (Fig. 16). Reminder Note: All holes or penetrations through the membrane will need to be patched with 12” VaporSeal™ Tape. Fig. 14 Page 4 of 5 Fig. 15 2.1. When installing reinforcing steel and utilities, in addition to the placement of concrete, take precaution to protect VaporBlock® Plus™. Carelessness during installation can damage the most puncture–resistant membrane. Sheets of plywood cushioned with geotextile fabric temporarily placed on VaporBlock® Plus™ provide for additional protection in high traffic areas including concrete buggies. 2.2. Use only brick-type or chair-type reinforcing bar supports to protect VaporBlock® Plus™ from puncture. 2.3. Avoid driving stakes through VaporBlock® Plus™. If this cannot be avoided, each individual hole must be repaired per section 1.7. 2.4. To avoid penetrating VaporBlock® Plus™ when installing screed supports, utilize non-penetrating support, such as the Mako® Screed Support System (Fig. 17). Avoid driving stakes through VaporBlock® Plus™. If this cannot be avoided, each individual hole must be repaired per figures 14-15. 2.5. If a cushion or blotter layer is required in the design between VaporBlock® Plus™ and the slab, additional care should be given if sharp crushed rock is used. Washed rock will provide less chance of damage during placement. Care must be taken to protect blotter layer from precipitation before concrete is placed. VaporBlock® Plus™ Gas & Moisture Barrier can be identified on site as gold/white in color printed in black ink with following logo and classification listing (Fig. 18) Page 5 of 5 VaporBlock® Plus™ Gas & Moisture Barrier VAPORBLOCK® PLUS™ PROTECTION Fig. 16 Fig. 18 Fig. 17 *Patent Pending Note: To the best of our knowledge, unless otherwise stated, these are typical property values and are intended as guides only, not as specification limits. Chemical resistance, odor transmission, longevity as well as other performance criteria is not implied or given and actual testing must be performed for applicability in specific applications and/or conditions. VIAFLEX MAKES NO WARRANTIES AS TO THE FITNESS FOR A SPECIFIC USE OR MERCHANTABILITY OF PRODUCTS REFERRED TO, no guarantee of satisfactory results from reliance upon contained information or recommendations and disclaims all liability for resulting loss or damage. Limited Warranty available at www.viaflex.com VIAFLEX, INC. 821 W Algonquin Street Sioux Falls, SD 57104 Ph: +1 (605) 335-0174 • TF: +1 (800) 635-3456© 2022 VIAFLEX, INC. All rights reserved.27-0126 09/22 sales@viaflex.com www.viaflex.com ACCESSORIES SEAMING TAPES & OTHER ACCESSORIES FOR PLASTIC SHEETING Butyl Seal Tape (TP2BR / TP6BR) Butyl Seal is a double-sided reinforced aggressive black butyl rubber tape used to join panels of polyethylene and polypropylene together by overlapping the edges and applying Butyl Seal in between. It is also used to adhere to concrete walls and footings when properly prepared. Butyl Seal is non-hardening and flexible. Available in 2” x 50’ and 6” x 50’ rolls. R25B Tape (R25B) R25B Tape is a single-sided aggressive synthetic elastomeric adhesive that bonds instantly to properly prepared polyethylene and polypropylene. The black polymer backing and adhesive is specially formulated to provide years of performance even in direct sunlight. A poly release liner provides for ease of installation. Available in 4” x 100’ roll. ACCESSORY TAPES AND EPOXY VaporBond™ Tape (TVB4) VaporBond™ Tape is a white single-sided tape that combines a heavy-duty, weather-resistant polyethylene backing with an aggressive rubber adhesive. VaporBond™ Tape offers excellent seaming capabilities for our materials with an “Easy Tear” feature to reduce installation time. TVB4 has a WVTR of 0.18 perms per ASTM D3833. Typical applications include vapor retarders, covers and liners. Available in 4” x 210’ roll. VaporSeal™ Tape (TVSP4/TVSP12) VaporSeal™ Tape is a patent pending single-sided 7-layer gas barrier tape with a release liner for ease of installation. The backing contains a layer of highly impermeable EVOH designed to block migration of radon, methane, and VOC’s. An aggressive acrylic adhesive provides outstanding adhesion to polyethylene over a wide temperature range. Typical uses include joining, repairing and sealing gas/moisture barriers. Available in 4” x 160’ and 12” x 50’ rolls. VaporBoot™ Tape (TBOOT) VaporBoot™ Tape is a single-sided elastomeric butyl tape used to complete pipe boot installations (sealing the boot to the pipe). The 100% stretchable butyl adhesive features excellent adhesion values and 3-D stretching that can be easily molded to multiple surfaces without any creases and folds. Available in 2” x 16.4’ roll. ADDITIONAL ACCESSORIES VaporBoot™ System (VBOOT) The VaporBoot™ System is designed to assist in securing pipe and other penetrations that run vertically through the vapor reta rder material. The VaporBoot™ System offers a quick solution and is delivered to the jobsite in a complete package. VaporBoots are produced from high performance VaporBlock® material. Package Contents: 25 - VaporBoots (18” x 18”, w/precut center marker) 1 Roll VaporBoot (TBOOT)Tape 2‘x16.4‘1 roll of Vapor Bond Tape (TVB4) 4‘x210 VaporBoot™ Plus Preformed Pipe Boots (VBPBT) VaporBoot™ Plus Preformed Pipe Boots are produced from heavy 40 mil co-extruded polyethylene and barrier resins for excellent strength and durability. The preformed boots are stepped to fit 1” to 4” wide pipe penetrations. VaporBoot™ Plus Preformed Pipe Boots are available in quantities of 12 per box. From tie-d own fasteners to field seaming tape, Viaflex has the accessories you need to maximize your film’s versatility and minimize installation time on the job. POUR-N-SEAL™ (PNS1G) POUR-N-SEAL™ is a gray two part epoxy used to seal around multi-pipe penetrations in areas where pipe boots are not practical, when installing underslab barriers. The POUR-N-SEAL™ system installation guide references a 1” x 25 lineal feet adhesive-backed foam to form a dam around multi-pipe penetrations to contain POUR-N-SEAL™ during the setting process. The 1” x 25 ft. adhesive-backed foam is sold seperately as FOAM25. © 2022 VIAFLEX, INC. All rights reserved. ACCESSORIES Tie-Down Buttons (BUTI) & Tarp Grabbers (BUTEZ) Tie-Down Buttons and Tarp Grabbers help keep plastic sheeting securely in place. Tie-Down Buttons are designed to eliminate traditional grommets in plastic sheeting up to 10 mil thick and are reusable plastic fittings that are easy to install in any position. Tarp Grabbers are up to 4 times stronger than a brass grommet and are typically used in heavier plastic sheeting from 10 mil to 30 mil thick. Great for equipment covers, large storage covers and truck tarps. ADDITIONAL ACCESSORIES (CONTINUED) Dura♦Skrim® Reinforced Sandbags Dura♦Skrim® reinforced sandbags are used to secure large covers and liners to prevent wind damage. Sandbags are produced with strong Dura♦Skrim® 8 & 12 mil reinforced polyethylene. These 15” wide x 24” long bags are designed to hold 35 lbs. Sandbags are also available in other VIAFLEX reinforced materials with minimum order requirements. 11.8” Cable Ties are also available. Dura-Clip™ (CLIP11) VIAFLEX Welding Rod These full size clips are 11” long and fit most commercial scaffolding. Dura-Clip™ will securely fasten your poly sheeting to scaffolding, reducing wind whip and increasing the life of your enclosure. The Dura-Clip™ is normally placed about every 3’ onto the enclosure. VIAFLEX Welding Rod is used for field seaming, repairs and detail work, such as installing pipe boots. Packaged in 25 lb spools, it is available in 4mm and 5mm sizes to fit most brands of extrusion guns. VIAFLEX Welding Rod is made from a thermally UV stabilized LLDPE resin and is available in both black and white to correspond with the color of geomembranes being utilized. SEAMING TAPES & OTHER ACCESSORIES FOR PLASTIC SHEETING TAPE ACCESSORY PROPERTIES PROPERTIES VaporBond Tape(TVB4)VaporSeal Tape(TVSP4 / TVSP12)VaporBoot Tape(TBOOT)R25B Tape(R25B)Butyl Seal Tape(TP2BR / TP6BR) Backing 6.7 mil Polyethylene 7 mil EVOH/LLDPE 30 mil EPDM 8 mil Multi-Polymer N/A Adhesive 3.3 mil Rubber Based Pressure-Sensitive 2 mil Acrylic Adhesive Pressure-Sensitive 20 mil Butyl Rubber 17 mil Synthetic Elastomeric 40 mil Butyl Rubber Color White Silver Black Black Black Type Single Sided Single Sided Single Sided Single Sided Double Sided Size 4” x 210’4” x 160’ / 12” x 50’2” x 16.4’4” x 100’2” x 50’ / 6” x 50’ Rolls per Case 12 12 / 4 64 6 16 / 4 Weight per Case 45 lbs 50 lbs / 18 lbs 45 lbs 33 lbs 47 lbs / 20 lbs Adhesion Values 35 oz. / in. (to steel)80 oz. / in. (to steel)145 oz. / in. (to steel)144 oz. / in. (to steel)88 oz. / in. (to steel) Perms 0.081 g/(24h*100 in²)0.014 g/(24h*100 in²)N/A <0.005 g/(24h*100 in²)0.82 g/(24h*100 in²) Service Temp.-40° F to +180° F -40° F to +190° F +14° F to +122° F +20° F to +180° F 0° F to +170° F Min.Application Temp.50° F 50° F 14° F 35° F 35° F Ideal StorageTemp. / Humidity 70° F w/ 40-50 %60°-80° F w/ 40-60 %70° F w/ 70 %70° F w/ 40-50 %70° F w/ 40-50 % Note: To the best of our knowledge, unless otherwise stated, these are typical property values and are intended as guides only, not as specification limits. Chemical resistance, odor transmission, longevity as well as other performance criteria is not implied or given and actual testing must be performed for applicability in specific applications and/or conditions. VIAFLEX MAKES NO WARRANTIES AS TO THE FITNESS FOR A SPECIFIC USE OR MERCHANTABILITY OF PRODUCTS REFERRED TO, no guarantee of satisfactory results from reliance upon contained information or recommendations and disclaims all liability for resulting loss or damage. Limited Warranty available at www.viaflex.com 27-0016 05/23 sales@viaflex.com www.viaflex.comScan QR Code to download technical data sheets. VIAFLEX, INC. 821 W Algonquin Street Sioux Falls, SD 57104 Ph: +1 (605) 335-0174 • TF: +1 (800) 635-3456© 2022 VIAFLEX, INC. All rights reserved.       !"#$%&'(()'))*+'&"'%),-./01 , .. ,01 ,0.   , 234567589 :;<=>?;<@AB=;>;>;BCD<E<;FGHBIH;>BAHBJ=K:;;BLA>G?AHBG<=>KMNNOPONQMRSTUVWXYZXXR[\O]^_]`Q^Ma[b cd;BBDFIH<DD>IHA>eD?Ae<=HABDF?<;@BCDd=KCBDIBHdAIIfg2B;BCDCDAh=DIB5iDHA>Id;BE=ED?<;@jklmBC<;GKCjnmF=A@DBD<A>FGEB;lopdD>KBCI5cd;`ars^rON`NO`t`^u`vuOs^Qw`t`N^OQxMP]Ma_yzI=edD|FDED>F=>K;>Id;BI=qD|IEAH=>KA>F>G@eId;BI53<;}H;>I=IBI;?Id;BI|>;<@Add~IEAHDFAhAdI|HGBED<ED>F=HGdA<B;BCDA=I;?BCDE=EDA>?<;@;>DD>F;?BCDE=EDB;BCD;BCD<5L;IBE=EDGEB;B};<;}I@;<DBCA>BCDIBABDFF=A@DBD<;s^QwMzQ[^ya^_]`aQ[QNz]QzN`usO` Oa^aybS]NOOa]`avOPzNa^[wOrs^Qw‚z[wZQwNO`rOrMN[u^\ƒM^a]MatOaQ^Ma`u_QQ^ay[b„…†‡ˆ‰Š‡‹Œ „…†‡ˆ‰Š‡ Œ „Ž  ‘ „•–—–˜™š#$››•–—–˜™š#$››•–—–˜™š#$››•–—–j9 mjj {{j59jšj5žžoj58ool59Ÿš95šooœ5šoo{ž5žlšn5žlšjo5Ÿšojl5Ÿšo {{{{{{{{š5šž9{{{{5nœoj5ošoj59jšj5žžoj58ool59Ÿš95šooœ5šoo{ž5žlšn5žlš{{5jœŸ5jšœ5jŸ85j8j5loo5ljn59oo599Ÿ{5œ9l5šoo{{{{5j995jœo5jœš5jšœ5ljž5l9Ÿ{5lno59ll59žš5œož {{{{{{{{59lŸ{{{{{{{{{{{œ5šooš5šž9{{{{          !"+,-$ 3 467/86190:23.;60<=>9?8;9=?946050<50A9?4546GIJKLMNOPLGQJRSTUDEVNKKDWXdaea`f[eg]_h[`[eZ]Z[_i_]j_kj[deahl]mnaa`o_bpd_\`pe]bmq (uv&wywxz#(uv&wywxz#X++Q X+G+ X+GI X+G{X+I+ X+I{ X+IQ X+*+X+|+3::33}}~~~3::33}}~~~ €€3:3:}3}3::::  ::::3~3~}}}}~:~::€:€ ~: ~:333333:3€3€}}}}€~3€~3:::}}}}~~}}}}}~ 3~ 3:: 3  3  3 ~3 ~}3~}3 ~ ~:3:3:3~~:}:}:3:3: : : :~3              ! !"#$ ! !" %&'()(**+,,                                 !  "#        $       %% &'()*' '+,)-./-012+,(2. %% &'()*3 3+,04./3)1-4+,2(. %% &'()*( (+,-*'./3)1-4+,2(. %% &'()*' '+,)-./ -012+,(2. %% &'()*3 3+,04./ 3)1-4+,2(. %% &'()*( (+,-*'./3)1-4+,2(.                     ! "" #  5 " "" $          Appendix D Photographic Log and Inspection Checklist Photograph Nos. 1 & 2: Representative views of sub-slab gravel and vapor conveyance piping in Area C. PD P . 0 0 1 2923 S. Tryon Street, Suite 100 Charlotte, NC 28203 704.586.0007(p) 704.586.0373(f) BATTERY AND IGNITION DISTRIBUTION TRYCLAN DRIVE AND ELLENWOOD PLACE CHARLOTTE, NORTH CAROLINA Photograph Nos. 3 & 4: Representative view of sub-slab gravel and vapor conveyance piping in Area D. Photograph Nos. 7 & 8: Representative views of Viaflex VBP-20 vapor barrier system in Area D. PD P . 0 0 1 2923 S. Tryon Street, Suite 100 Charlotte, NC 28203 704.586.0007(p) 704.586.0373(f) BATTERY AND IGNITION DISTRIBUTION TRYCLAN DRIVE AND ELLENWOOD PLACE CHARLOTTE, NORTH CAROLINA Photograph Nos. 5 & 6: Representative view of Viaflex VBP-20 vapor barrier system in Area C. 2923 S. Tryon Street, Suite 100 Charlotte, NC 28203 704.586.0007(p) 704.586.0373(f)PD P . 0 0 1 BATTERY AND IGNITION DISTRIBUTION TRYCLAN DRIVE AND ELLENWOOD PLACE CHARLOTTE, NORTH CAROLINA Photograph Nos. 9 & 10: Representative riser installations in interior wall. Photograph Nos. 11 & 12: Representative views of rooftop exhaust vents and labeling. 2923 S. Tryon Street, Suite 100 Charlotte, NC 28203 704.586.0007(p) 704.586.0373(f)PD P . 0 0 1 BATTERY AND IGNITION DISTRIBUTION TRYCLAN DRIVE AND ELLENWOOD PLACE CHARLOTTE, NORTH CAROLINA Category Example Criteria Proper base layer (i.e., gravel, aerated flooring) and thickness Proper placement, type, and pitch of VIMS vent piping Proper placement, type, and pitch of monitoring points Correct vapor barrier type elevators, etc.) Good condition of vapor barrier Riser pipe material and fitting connections Proper pitch towards sub-slab (gravity drain) Appropriate VIMS labels Correct fan/ventilator Fan/ventilator operation Proper fittings and protection (varmint screens, electrical covers, etc.) Appropriate VIMS labels Proper distance from roof intakes and parapets Pilot test completed Monitoring points finished and accessible Vapor Intrusion Mitigation System - Inspection Checklist Building/Area ID: Area C and Area D Start Date and End Date: October 2022 - July 2023 Proper Installation (Initial below) Site Name and H&H Project #: Battery & Ignition Distribution - Ello House; PDP.001 DEQ Brownfields ID: 23055-19-060 Sub-Slab Vapor Barrier Vent Riser Piping JCG JCG JCG JCG JCG JCG Pilot Test / Checkout JCG JCG JCG JCG JCG JCG JCG Fan/Ventilator JCG JCG JCG JCG Appendix E VIMS Influence Testing Forms and Sampling Field Forms Table E-1Summary of Influence Testing Results Ello House Tryclan Drive and Ellenwood Place Charlotte, North Carolina H&H Job No. PDP.001 Point ID Baseline Initial 10-minute Point ID Baseline Initial 10-minute Point ID Baseline Initial 10-minute E-8 0.000 -3.142 -3.096 E-9 0.000 -3.094 -2.870 E-14 0.000 -2.973 -3.002 E-11 0.000 -4.201 -3.877 E-10 0.000 -3.288 -3.542 **MP-9 0.000 -0.110 -0.109 E-14*0.000 -2.921 -2.853 E-12 0.000 -3.270 -3.080 E-16*0.000 -2.782 -2.573 E-13*0.000 -2.718 -2.512 E-18 0.000 -2.828 -2.642 E-15*0.000 -2.607 -2.729 E-20 0.000 -3.703 -2.956 E-17*0.000 -2.671 -2.754 E-22 0.000 -3.011 -2.988 E-19 0.000 -3.110 -3.135 TMP-5 0.000 -0.005 -0.004 E-21 0.000 -3.150 -3.028 MP-6 0.000 -0.117 -0.120 TMP-5 0.000 -0.171 -0.175 MP-7 0.000 -0.137 -0.138 MP-6 0.000 -0.043 -0.043 MP-8 0.000 -0.003 0.000 MP-7 0.000 -0.076 -0.074 MP-9**NM NM NM MP-8 0.000 -0.279 -0.285 MP-10 0.000 -0.181 -0.182 **MP-9 NM NM NM MP-11 0.000 -0.077 -0.078 MP-10 0.000 -0.114 -0.260 MP-12 0.000 -0.070 -0.073 MP-11 0.000 -0.448 -0.544 MP-13 0.000 -0.124 -0.123 MP-12 0.000 -0.022 -0.039 MP-14 0.000 -0.124 -0.124 MP-13 0.000 -0.182 -0.181 MP-14 0.000 -0.249 -0.281 Notes: **MP-9 was tested on 8/24/23 after repairs were made to the monitoring point. Fans Utilized: AMG Eagle Extreme, Legend, and Legend Extreme MP-9 RE-TEST 8/24/20233/29/2023 Test 2Test 1 3/29/2023 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Proffitt Dixon - PDP/PDP-001 - Tryclan Avenue/VIMS install report/Areas C and D/Tables/PDP-001 Pilot Test Data Hart & Hickman, PC Table E-1 Summary of Influence Testing Results Ello House Tryclan Drive and Ellenwood Place Charlotte, North Carolina H&H Job No. PDP.001 Point ID Baseline Initial 10-minute Point ID Baseline Initial 10-minute E-3 0.000 -2.376 -2.438 E-1 0.000 -3.662 -3.207 E-4 0.000 -3.041 -3.055 TMP-1 0.000 -0.986 -1.102 E-5 0.000 -3.077 -3.079 MP-1 0.000 -1.106 -1.145 E-6 0.000 -4.819 -4.838 E-7 0.000 -3.020 -3.053 TMP-3 0.000 -0.233 -0.232 TMP-4 0.000 -0.336 -0.363 Point ID Baseline Initial 10-minute MP-3 0.000 -0.795 -0.810 E-2 0.000 -4.421 -4.436 MP-4 0.000 -1.249 -1.292 TMP-2 0.000 -0.324 -0.326 MP-5 0.000 -0.518 -0.516 MP-2 0.000 -0.224 -0.225 Basement (North) 3/30/2023 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Proffitt Dixon - PDP/PDP-001 - Tryclan Avenue/VIMS install report/Areas C and D/Tables/PDP-001 Pilot Test Data Page 2 of 2 Hart & Hickman, PC MP-3 13711 SS Perm.Conc Full 50 Pump 13.0 Yes 17727 MP-5/MP-DUP 13694/15804 Conc 13110 PDP-001 JL 50s F & sunny MP-3 1 L13711 2/21/24 10 0.1 L/min 1155 -16 50 44 32 17727 1200 -5 1150 -28 57 MP-5 / MP-DUP 1 L 1557 -29 13694/15804 2/21/24 10 1602 -16 59 32 60 28 0.1 L/min13110 1607 -5 50s F & sunny C-IAS-1 / IAS-DUP 6 L37239 / 36110 2/20/24- 2/21/24 1702 -25 64 0.25 L/min 1132 -7 64 D-IAS-1 1124 -30 636 L IAS-BKG 46855 1707 -24 NA 1130 1700 30.35 30.29 E E 6 6 INDOOR AIR BUILDING SURVEY and SAMPLING FORM Site Name: ____________________________________ Preparer’s name: ________________________________ Preparer’s affiliation: ____________________________ #: ______________________ Date: __________________________ Phone #: _______________________ Part I - Occupants Building Address: ____________________________________________________________________ Property Contact: _______________________________ Owner / Renter / other: ______________ Contact’s Phone: home ( )__________ work ( )______________ cell ( )____________ # of Building occupants: Children under age 13 _____ Children age 13-18 ______ Adults _____ Part II – Building Characteristics Building type: Describe building: ________________________________________ Year constructed: _________ Sensitive population:(specify): _______________ Number of floors below grade: ______ Number of floors at or above grade: ______ Depth of basement below grade surface: ______ ft. Basement size: _______ ft2 Basement floor construction: Foundation walls: Basement sump present?Sump pump? ther (specify): ________________ other (specify)_______________ Water in sump? Type of heating system (c all that apply): hot air circulation hot air radiation wood steam radiation heat pump hot water radiation kerosene heater electric baseboard other (specify): ________________________ Type of ventilation system (c all that apply): bathroom ventilation fans outside air intake central air conditioning mechanical fans individual air conditioning units kitchen range hood fan other (specify): _________________ Type of fuel utilized (c all that apply): Natural gas electric fuel oil wood coal solar kerosene Are the basement walls or floor sealed with waterproof paint or epoxy coatings? other (specify) _____________ Is there a whole house fan? Septic system? Irrigation/private well? Type of ground cover outside of building: Existing subsurface depressurization (radon) system in place? Sub-slab vapor/moisture barrier in place? Type of barrier: ____________________________ Part III - Outside Contaminant Sources Other stationary sources nearby (gas stations, emission stacks, etc.): _____________________________ Heavy vehicular traffic nearby (or other mobile sources): ______________________________________ Part IV – Indoor Contaminant Sources Identify all potential indoor sources found in the building (including attached garages), the location of the source (floor and room), and whether the item was removed from the building 48 hours prior to indoor air sampling event. Any ventilation implemented after removal of the items should be completed at least 24 hours prior to the commencement of the indoor air sampling event. Potential Sources Location(s)Removed (Yes / No / NA) Gasoline storage cans Gas-powered equipment Kerosene storage cans Paints / thinners / strippers Cleaning solvents Oven cleaners Carpet / upholstery cleaners Other house cleaning products Moth balls Polishes / waxes Insecticides Furniture / floor polish Nail polish / polish remover Hairspray Cologne / perfume Air fresheners Fuel tank (inside building) Wood stove or fireplace New furniture / upholstery New carpeting / flooring Hobbies - glues, paints, etc. Part V – Miscellaneous Items Do any occupants of the building smoke?How often? ______________ Last time someone smoked in the building? ____________ hours days ago Does the building have an attached garage directly connected to living space? If so, is a car usually parked in the garage? Are gas-powered equipment or cans of gasoline/fuels stored in the garage? Do the occupants of the building have their clothes dry cleaned? If yes, how often? Do any of the occupants use solvents in work? If yes, what types of solvents are used? _______________________________________ If yes, are their clothes washed at work? If so, when and which chemicals? _________________________________________________ Has there ever been a fire in the building?If yes, when? _____________ Has painting or staining been done in the building in the last 6 months?Yes No If yes, when __________________ and where? ____________________________ Part VI – Sampling Information Sample Technician: ____________________________ Phone number:) _______ - __________ Sample Source Sampler Type Other (specify): _________________ Analytical Method:ther: _____________ Cert. Laboratory: Sample locations (floor, room): Field ID # _____ - ________________________ Field ID # _____-__________________________ Field ID # Were “Instructions for Occupants” followed? Provide Drawing of Sample Location(s) in Building Part VII - Meteorological Conditions Was there significant precipitation within 12 hours prior to (or during) the sampling event?Yes No Describe the general weather conditions: _________________________________________________ _____________________________________________________________________________________ Part VIII – General Observations Provide any information that may be pertinent to the sampling event and may assist in the data interpretation process (e.g., observed that drycleaner operated with door or windows propped open for ventilation). (Adapted from the NJDEP Vapor Intrusion Guidance, October 2005) Sunny, 50's F; no precipitation Appendix F Laboratory Analytical Report   Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.   3/8/2024 Hart & Hickman (Charlotte) David Kahn 2923 South Tryon St. Ste 100 Charlotte, NC, 28203 Ref: Analytical Testing Lab Report Number: 24-053-0009 Client Project Description: PDP-001 Dear David Kahn: Waypoint Analytical, LLC (Charlotte) received sample(s) on 2/22/2024 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Angela D Overcash Senior Project Manager Page 1 of 38 Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date 07/31/202437735State ProgramNorth Carolina 12/31/2024402State ProgramNorth Carolina 07/31/202499012State ProgramSouth Carolina 12/31/202399012State ProgramSouth Carolina Page 1 of 1 00016/24-053-0009 Page 2 of 38 Report Number: Sample Summary Table Client Project Description: 24-053-0009 PDP-001 Lab No Client Sample ID Matrix Date Collected Date Received 02/20/2024Air 97578 IAS-DUP 02/22/2024 09:50 02/20/2024 11:32Air 97579 C-IAS-1 02/22/2024 09:50 02/20/2024 11:24Air 97580 D-IAS-1 02/22/2024 09:50 02/20/2024 11:23Air 97581 IAS-BKG 02/22/2024 09:50 02/21/2024Air 97582 MP-DUP 02/22/2024 09:50 02/21/2024 15:57Air 97583 MP-5 02/22/2024 09:50 02/21/2024 11:50Air 97584 MP-3 02/22/2024 09:50 Page 3 of 38 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 24-053-0009 Report Limit Project:PDP-001 V 97578IAS-DUP 114 02/28/2024 03:02TO-15 Acetone µg/m3 2.02 2.29 02/26/2024 23:12TO-15 Benzene µg/m3 0.073 J0.949 02/26/2024 23:12TO-15 Chloromethane µg/m3 0.067 2.89 02/26/2024 23:12TO-15 Dichlorodifluoromethane µg/m3 0.134 3.20 02/26/2024 23:12TO-15 Ethylbenzene µg/m3 0.106 J1.93 02/26/2024 23:12TO-15 4-Ethyltoluene µg/m3 0.128 J0.582 02/26/2024 23:12TO-15 1,1,2-Trichloro-1,2,2-trifluoroethane µg/m3 0.561 2.41 02/26/2024 23:12TO-15 Heptane µg/m3 0.143 2.58 02/26/2024 23:12TO-15 n-Hexane µg/m3 0.047 B6.33 02/26/2024 23:12TO-15 Isopropyl Alcohol µg/m3 0.139 65.8 02/26/2024 23:12TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J1.63 02/26/2024 23:12TO-15 Methylene Chloride µg/m3 0.488 J0.560 02/26/2024 23:12TO-15 Naphthalene µg/m3 0.183 2.14 02/26/2024 23:12TO-15 Styrene µg/m3 0.124 25.6 02/26/2024 23:12TO-15 Tetrahydrofuran µg/m3 0.107 11.4 02/26/2024 23:12TO-15 Toluene µg/m3 0.090 J1.74 02/26/2024 23:12TO-15 Trichlorofluoromethane µg/m3 0.130 10.2 02/26/2024 23:12TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 2.77 02/26/2024 23:12TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 11.4 02/26/2024 23:12TO-15 o-Xylene µg/m3 0.157 12.5 02/26/2024 23:12TO-15 m,p-Xylene µg/m3 0.217 23.9 02/26/2024 23:12TO-15 Xylene (Total)µg/m3 0.157 V 97579C-IAS-1 118 02/28/2024 03:38TO-15 Acetone µg/m3 2.02 2.22 02/27/2024 00:02TO-15 Benzene µg/m3 0.073 J0.947 02/27/2024 00:02TO-15 Chloromethane µg/m3 0.067 2.87 02/27/2024 00:02TO-15 Dichlorodifluoromethane µg/m3 0.134 3.23 02/27/2024 00:02TO-15 Ethylbenzene µg/m3 0.106 J1.88 02/27/2024 00:02TO-15 4-Ethyltoluene µg/m3 0.128 J0.590 02/27/2024 00:02TO-15 1,1,2-Trichloro-1,2,2-trifluoroethane µg/m3 0.561 2.17 02/27/2024 00:02TO-15 Heptane µg/m3 0.143 2.51 02/27/2024 00:02TO-15 n-Hexane µg/m3 0.047 B6.34 02/27/2024 00:02TO-15 Isopropyl Alcohol µg/m3 0.139 65.0 02/27/2024 00:02TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J1.08 02/27/2024 00:02TO-15 Methylene Chloride µg/m3 0.488 J0.571 02/27/2024 00:02TO-15 Naphthalene µg/m3 0.183 Page 4 of 38 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 24-053-0009 Report Limit Project:PDP-001 V 97579C-IAS-1 J2.11 02/27/2024 00:02TO-15 Styrene µg/m3 0.124 25.0 02/27/2024 00:02TO-15 Tetrahydrofuran µg/m3 0.107 9.65 02/27/2024 00:02TO-15 Toluene µg/m3 0.090 J1.65 02/27/2024 00:02TO-15 Trichlorofluoromethane µg/m3 0.130 10.3 02/27/2024 00:02TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 2.69 02/27/2024 00:02TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 11.1 02/27/2024 00:02TO-15 o-Xylene µg/m3 0.157 12.4 02/27/2024 00:02TO-15 m,p-Xylene µg/m3 0.217 23.5 02/27/2024 00:02TO-15 Xylene (Total)µg/m3 0.157 V 97580D-IAS-1 263 02/28/2024 04:14TO-15 Acetone µg/m3 4.04 J1.20 02/27/2024 00:49TO-15 Benzene µg/m3 0.073 J0.972 02/27/2024 00:49TO-15 Chloromethane µg/m3 0.067 2.83 02/27/2024 00:49TO-15 Dichlorodifluoromethane µg/m3 0.134 J1.81 02/27/2024 00:49TO-15 Ethylbenzene µg/m3 0.106 J0.958 02/27/2024 00:49TO-15 4-Ethyltoluene µg/m3 0.128 J0.590 02/27/2024 00:49TO-15 1,1,2-Trichloro-1,2,2-trifluoroethane µg/m3 0.561 J1.31 02/27/2024 00:49TO-15 Heptane µg/m3 0.143 J1.32 02/27/2024 00:49TO-15 n-Hexane µg/m3 0.047 B9.13 02/27/2024 00:49TO-15 Isopropyl Alcohol µg/m3 0.139 59.3 02/27/2024 00:49TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J1.47 02/27/2024 00:49TO-15 Methylene Chloride µg/m3 0.488 J1.63 02/27/2024 00:49TO-15 Styrene µg/m3 0.124 23.8 02/27/2024 00:49TO-15 Tetrahydrofuran µg/m3 0.107 6.48 02/27/2024 00:49TO-15 Toluene µg/m3 0.090 J1.58 02/27/2024 00:49TO-15 Trichlorofluoromethane µg/m3 0.130 4.74 02/27/2024 00:49TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J1.23 02/27/2024 00:49TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 6.24 02/27/2024 00:49TO-15 o-Xylene µg/m3 0.157 6.63 02/27/2024 00:49TO-15 m,p-Xylene µg/m3 0.217 12.9 02/27/2024 00:49TO-15 Xylene (Total)µg/m3 0.157 V 97581IAS-BKG B9.14 02/27/2024 01:36TO-15 Acetone µg/m3 0.202 J0.897 02/27/2024 01:36TO-15 Benzene µg/m3 0.073 2.83 02/27/2024 01:36TO-15 Dichlorodifluoromethane µg/m3 0.134 J0.597 02/27/2024 01:36TO-15 1,1,2-Trichloro-1,2,2-trifluoroethane µg/m3 0.561 Page 5 of 38 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 24-053-0009 Report Limit Project:PDP-001 V 97581IAS-BKG J0.672 02/27/2024 01:36TO-15 Heptane µg/m3 0.143 J0.676 02/27/2024 01:36TO-15 n-Hexane µg/m3 0.047 JB2.88 02/27/2024 01:36TO-15 Isopropyl Alcohol µg/m3 0.139 3.49 02/27/2024 01:36TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J1.28 02/27/2024 01:36TO-15 Methylene Chloride µg/m3 0.488 1.66 02/27/2024 01:36TO-15 Tetrahydrofuran µg/m3 0.107 3.52 02/27/2024 01:36TO-15 Toluene µg/m3 0.090 J1.62 02/27/2024 01:36TO-15 Trichlorofluoromethane µg/m3 0.130 J0.408 02/27/2024 01:36TO-15 o-Xylene µg/m3 0.157 J0.864 02/27/2024 01:36TO-15 m,p-Xylene µg/m3 0.217 J1.27 02/27/2024 01:36TO-15 Xylene (Total)µg/m3 0.157 V 97582MP-DUP 67.4 02/26/2024 20:51TO-15 Acetone µg/m3 0.202 2.44 02/26/2024 20:51TO-15 Benzene µg/m3 0.073 J0.737 02/26/2024 20:51TO-15 Carbon Disulfide µg/m3 0.060 J0.517 02/26/2024 20:51TO-15 Chloroform µg/m3 0.086 2.90 02/26/2024 20:51TO-15 Dichlorodifluoromethane µg/m3 0.134 J1.44 02/26/2024 20:51TO-15 Ethylbenzene µg/m3 0.106 J0.408 02/26/2024 20:51TO-15 4-Ethyltoluene µg/m3 0.128 J0.643 02/26/2024 20:51TO-15 1,1,2-Trichloro-1,2,2-trifluoroethane µg/m3 0.561 J0.368 02/26/2024 20:51TO-15 Heptane µg/m3 0.143 J1.11 02/26/2024 20:51TO-15 n-Hexane µg/m3 0.047 JB3.52 02/26/2024 20:51TO-15 Isopropyl Alcohol µg/m3 0.139 79.0 02/26/2024 20:51TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J1.55 02/26/2024 20:51TO-15 Methylene Chloride µg/m3 0.488 J0.560 02/26/2024 20:51TO-15 Naphthalene µg/m3 0.183 4.59 02/26/2024 20:51TO-15 Propene µg/m3 0.242 J0.379 02/26/2024 20:51TO-15 Styrene µg/m3 0.124 63.7 02/26/2024 20:51TO-15 Tetrahydrofuran µg/m3 0.107 3.32 02/26/2024 20:51TO-15 Toluene µg/m3 0.090 J1.74 02/26/2024 20:51TO-15 Trichlorofluoromethane µg/m3 0.130 J1.82 02/26/2024 20:51TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J0.535 02/26/2024 20:51TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 2.62 02/26/2024 20:51TO-15 o-Xylene µg/m3 0.157 J5.47 02/26/2024 20:51TO-15 m,p-Xylene µg/m3 0.217 J8.09 02/26/2024 20:51TO-15 Xylene (Total)µg/m3 0.157 Page 6 of 38 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 24-053-0009 Report Limit Project:PDP-001 V 97583MP-5 66.0 02/26/2024 21:43TO-15 Acetone µg/m3 0.202 2.47 02/26/2024 21:43TO-15 Benzene µg/m3 0.073 J0.747 02/26/2024 21:43TO-15 Carbon Disulfide µg/m3 0.060 J0.522 02/26/2024 21:43TO-15 Chloroform µg/m3 0.086 2.84 02/26/2024 21:43TO-15 Dichlorodifluoromethane µg/m3 0.134 J1.44 02/26/2024 21:43TO-15 Ethylbenzene µg/m3 0.106 J0.408 02/26/2024 21:43TO-15 4-Ethyltoluene µg/m3 0.128 J0.597 02/26/2024 21:43TO-15 1,1,2-Trichloro-1,2,2-trifluoroethane µg/m3 0.561 J0.401 02/26/2024 21:43TO-15 Heptane µg/m3 0.143 J1.42 02/26/2024 21:43TO-15 n-Hexane µg/m3 0.047 JB3.83 02/26/2024 21:43TO-15 Isopropyl Alcohol µg/m3 0.139 76.2 02/26/2024 21:43TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 3.94 02/26/2024 21:43TO-15 Methylene Chloride µg/m3 0.488 J0.492 02/26/2024 21:43TO-15 Naphthalene µg/m3 0.183 4.59 02/26/2024 21:43TO-15 Propene µg/m3 0.242 J0.379 02/26/2024 21:43TO-15 Styrene µg/m3 0.124 63.9 02/26/2024 21:43TO-15 Tetrahydrofuran µg/m3 0.107 3.34 02/26/2024 21:43TO-15 Toluene µg/m3 0.090 J1.80 02/26/2024 21:43TO-15 Trichlorofluoromethane µg/m3 0.130 J1.85 02/26/2024 21:43TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J0.565 02/26/2024 21:43TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 2.73 02/26/2024 21:43TO-15 o-Xylene µg/m3 0.157 J5.53 02/26/2024 21:43TO-15 m,p-Xylene µg/m3 0.217 J8.26 02/26/2024 21:43TO-15 Xylene (Total)µg/m3 0.157 V 97584MP-3 17400 02/27/2024 15:05TO-15 Acetone µg/m3 40.4 J28.7 02/26/2024 22:19TO-15 Cyclohexane µg/m3 3.22 J55.1 02/26/2024 22:19TO-15 Isopropyl Alcohol µg/m3 2.78 J12.4 02/26/2024 22:19TO-15 Methylene Chloride µg/m3 9.75 14200 02/27/2024 15:05TO-15 Tetrahydrofuran µg/m3 21.4 J7.47 02/26/2024 22:19TO-15 m,p-Xylene µg/m3 4.34 J7.47 02/26/2024 22:19TO-15 Xylene (Total)µg/m3 3.14 Page 7 of 38   Client: Hart & Hickman (Charlotte) CASE NARRATIVE Project: PDP-001 Lab Report Number: 24-053-0009 Date: 2/28/2024 Volatile Organic Compounds in Air- GC/MS Method TO-15 Sample 97584 (MP-3) QC Batch No: V44133/V44132 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly. Page 8 of 38 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-053-0009 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 David Kahn Charlotte Received : 02/22/2024 PDP-001 Report Date : 03/08/2024 Sample ID : Lab No : Sampled:IAS-DUP 97578 Matrix: 2/20/2024 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V44513 02/29/24 09:00 V44549 02/27/24 09:00 114 µg/m3 2.02 47.5Acetone 10 02/28/24 03:02 V44550ENM 2.29 µg/m3 0.073 1.60Benzene 1 02/26/24 23:12 V44517ENM <0.060 µg/m3 0.060 6.23Carbon Disulfide 1 02/26/24 23:12 V44517ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 02/26/24 23:12 V44517ENM <0.086 µg/m3 0.086 2.44Chloroform 1 02/26/24 23:12 V44517ENM 0.949 J µg/m3 0.067 1.03Chloromethane 1 02/26/24 23:12 V44517ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 02/26/24 23:12 V44517ENM 2.89 µg/m3 0.134 2.47Dichlorodifluoromethane 1 02/26/24 23:12 V44517ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 02/26/24 23:12 V44517ENM 3.20 µg/m3 0.106 2.17Ethylbenzene 1 02/26/24 23:12 V44517ENM 1.93 J µg/m3 0.128 2.464-Ethyltoluene 1 02/26/24 23:12 V44517ENM 0.582 J µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 02/26/24 23:12 V44517ENM 2.41 µg/m3 0.143 2.05Heptane 1 02/26/24 23:12 V44517ENM 2.58 µg/m3 0.047 1.76n-Hexane 1 02/26/24 23:12 V44517ENM 6.33 B µg/m3 0.139 4.92Isopropyl Alcohol 1 02/26/24 23:12 V44517ENM 65.8 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 02/26/24 23:12 V44517ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 02/26/24 23:12 V44517ENM 1.63 J µg/m3 0.488 1.74Methylene Chloride 1 02/26/24 23:12 V44517ENM 0.560 J µg/m3 0.183 2.62Naphthalene 1 02/26/24 23:12 V44517ENM <0.242 µg/m3 0.242 0.860Propene 1 02/26/24 23:12 V44517ENM 2.14 µg/m3 0.124 2.13Styrene 1 02/26/24 23:12 V44517ENM <0.181 µg/m3 0.181 3.39Tetrachloroethene 1 02/26/24 23:12 V44517ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 9 of 38 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-053-0009 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 David Kahn Charlotte Received : 02/22/2024 PDP-001 Report Date : 03/08/2024 Sample ID : Lab No : Sampled:IAS-DUP 97578 Matrix: 2/20/2024 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V44513 02/29/24 09:00 V44549 02/27/24 09:00 25.6 µg/m3 0.107 1.47Tetrahydrofuran 1 02/26/24 23:12 V44517ENM 11.4 µg/m3 0.090 1.88Toluene 1 02/26/24 23:12 V44517ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 02/26/24 23:12 V44517ENM 1.74 J µg/m3 0.130 2.81Trichlorofluoromethane 1 02/26/24 23:12 V44517ENM 10.2 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 02/26/24 23:12 V44517ENM 2.77 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 02/26/24 23:12 V44517ENM 11.4 µg/m3 0.157 2.17o-Xylene 1 02/26/24 23:12 V44517ENM 12.5 µg/m3 0.217 5.65m,p-Xylene 1 02/26/24 23:12 V44517ENM 23.9 µg/m3 0.157 2.17Xylene (Total)1 02/26/24 23:12 V44517 Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%02/26/24 23:121 ENM V44133 Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%02/26/24 23:121 ENM V44517 Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%02/28/24 03:0210 ENM V44148 Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%02/28/24 03:0210 ENM V44550 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 10 of 38 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-053-0009 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 David Kahn Charlotte Received : 02/22/2024 PDP-001 Report Date : 03/08/2024 Sample ID : Lab No : Sampled:C-IAS-1 97579 Matrix: 2/20/2024 11:32 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V44513 02/29/24 09:00 V44549 02/27/24 09:00 118 µg/m3 2.02 47.5Acetone 10 02/28/24 03:38 V44550ENM 2.22 µg/m3 0.073 1.60Benzene 1 02/27/24 00:02 V44517ENM <0.060 µg/m3 0.060 6.23Carbon Disulfide 1 02/27/24 00:02 V44517ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 02/27/24 00:02 V44517ENM <0.086 µg/m3 0.086 2.44Chloroform 1 02/27/24 00:02 V44517ENM 0.947 J µg/m3 0.067 1.03Chloromethane 1 02/27/24 00:02 V44517ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 02/27/24 00:02 V44517ENM 2.87 µg/m3 0.134 2.47Dichlorodifluoromethane 1 02/27/24 00:02 V44517ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 02/27/24 00:02 V44517ENM 3.23 µg/m3 0.106 2.17Ethylbenzene 1 02/27/24 00:02 V44517ENM 1.88 J µg/m3 0.128 2.464-Ethyltoluene 1 02/27/24 00:02 V44517ENM 0.590 J µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 02/27/24 00:02 V44517ENM 2.17 µg/m3 0.143 2.05Heptane 1 02/27/24 00:02 V44517ENM 2.51 µg/m3 0.047 1.76n-Hexane 1 02/27/24 00:02 V44517ENM 6.34 B µg/m3 0.139 4.92Isopropyl Alcohol 1 02/27/24 00:02 V44517ENM 65.0 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 02/27/24 00:02 V44517ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 02/27/24 00:02 V44517ENM 1.08 J µg/m3 0.488 1.74Methylene Chloride 1 02/27/24 00:02 V44517ENM 0.571 J µg/m3 0.183 2.62Naphthalene 1 02/27/24 00:02 V44517ENM <0.242 µg/m3 0.242 0.860Propene 1 02/27/24 00:02 V44517ENM 2.11 J µg/m3 0.124 2.13Styrene 1 02/27/24 00:02 V44517ENM <0.181 µg/m3 0.181 3.39Tetrachloroethene 1 02/27/24 00:02 V44517ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 11 of 38 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-053-0009 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 David Kahn Charlotte Received : 02/22/2024 PDP-001 Report Date : 03/08/2024 Sample ID : Lab No : Sampled:C-IAS-1 97579 Matrix: 2/20/2024 11:32 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V44513 02/29/24 09:00 V44549 02/27/24 09:00 25.0 µg/m3 0.107 1.47Tetrahydrofuran 1 02/27/24 00:02 V44517ENM 9.65 µg/m3 0.090 1.88Toluene 1 02/27/24 00:02 V44517ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 02/27/24 00:02 V44517ENM 1.65 J µg/m3 0.130 2.81Trichlorofluoromethane 1 02/27/24 00:02 V44517ENM 10.3 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 02/27/24 00:02 V44517ENM 2.69 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 02/27/24 00:02 V44517ENM 11.1 µg/m3 0.157 2.17o-Xylene 1 02/27/24 00:02 V44517ENM 12.4 µg/m3 0.217 5.65m,p-Xylene 1 02/27/24 00:02 V44517ENM 23.5 µg/m3 0.157 2.17Xylene (Total)1 02/27/24 00:02 V44517 Surrogate: 4-Bromofluorobenzene 99.7 Limits: 70-130%02/27/24 00:021 ENM V44133 Surrogate: 4-Bromofluorobenzene 99.7 Limits: 70-130%02/27/24 00:021 ENM V44517 Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%02/28/24 03:3810 ENM V44148 Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%02/28/24 03:3810 ENM V44550 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 12 of 38 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-053-0009 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 David Kahn Charlotte Received : 02/22/2024 PDP-001 Report Date : 03/08/2024 Sample ID : Lab No : Sampled:D-IAS-1 97580 Matrix: 2/20/2024 11:24 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V44513 02/29/24 09:00 V44549 02/27/24 09:00 263 µg/m3 4.04 95.0Acetone 20 02/28/24 04:14 V44550ENM 1.20 J µg/m3 0.073 1.60Benzene 1 02/27/24 00:49 V44517ENM <0.060 µg/m3 0.060 6.23Carbon Disulfide 1 02/27/24 00:49 V44517ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 02/27/24 00:49 V44517ENM <0.086 µg/m3 0.086 2.44Chloroform 1 02/27/24 00:49 V44517ENM 0.972 J µg/m3 0.067 1.03Chloromethane 1 02/27/24 00:49 V44517ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 02/27/24 00:49 V44517ENM 2.83 µg/m3 0.134 2.47Dichlorodifluoromethane 1 02/27/24 00:49 V44517ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 02/27/24 00:49 V44517ENM 1.81 J µg/m3 0.106 2.17Ethylbenzene 1 02/27/24 00:49 V44517ENM 0.958 J µg/m3 0.128 2.464-Ethyltoluene 1 02/27/24 00:49 V44517ENM 0.590 J µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 02/27/24 00:49 V44517ENM 1.31 J µg/m3 0.143 2.05Heptane 1 02/27/24 00:49 V44517ENM 1.32 J µg/m3 0.047 1.76n-Hexane 1 02/27/24 00:49 V44517ENM 9.13 B µg/m3 0.139 4.92Isopropyl Alcohol 1 02/27/24 00:49 V44517ENM 59.3 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 02/27/24 00:49 V44517ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 02/27/24 00:49 V44517ENM 1.47 J µg/m3 0.488 1.74Methylene Chloride 1 02/27/24 00:49 V44517ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 02/27/24 00:49 V44517ENM <0.242 µg/m3 0.242 0.860Propene 1 02/27/24 00:49 V44517ENM 1.63 J µg/m3 0.124 2.13Styrene 1 02/27/24 00:49 V44517ENM <0.181 µg/m3 0.181 3.39Tetrachloroethene 1 02/27/24 00:49 V44517ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 13 of 38 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-053-0009 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 David Kahn Charlotte Received : 02/22/2024 PDP-001 Report Date : 03/08/2024 Sample ID : Lab No : Sampled:D-IAS-1 97580 Matrix: 2/20/2024 11:24 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V44513 02/29/24 09:00 V44549 02/27/24 09:00 23.8 µg/m3 0.107 1.47Tetrahydrofuran 1 02/27/24 00:49 V44517ENM 6.48 µg/m3 0.090 1.88Toluene 1 02/27/24 00:49 V44517ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 02/27/24 00:49 V44517ENM 1.58 J µg/m3 0.130 2.81Trichlorofluoromethane 1 02/27/24 00:49 V44517ENM 4.74 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 02/27/24 00:49 V44517ENM 1.23 J µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 02/27/24 00:49 V44517ENM 6.24 µg/m3 0.157 2.17o-Xylene 1 02/27/24 00:49 V44517ENM 6.63 µg/m3 0.217 5.65m,p-Xylene 1 02/27/24 00:49 V44517ENM 12.9 µg/m3 0.157 2.17Xylene (Total)1 02/27/24 00:49 V44517 Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%02/27/24 00:491 ENM V44133 Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%02/27/24 00:491 ENM V44517 Surrogate: 4-Bromofluorobenzene 98.3 Limits: 70-130%02/28/24 04:1420 ENM V44148 Surrogate: 4-Bromofluorobenzene 98.3 Limits: 70-130%02/28/24 04:1420 ENM V44550 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 14 of 38 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-053-0009 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 David Kahn Charlotte Received : 02/22/2024 PDP-001 Report Date : 03/08/2024 Sample ID : Lab No : Sampled:IAS-BKG 97581 Matrix: 2/20/2024 11:23 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V44513 02/29/24 09:00 9.14 B µg/m3 0.202 4.75Acetone 1 02/27/24 01:36 V44517ENM 0.897 J µg/m3 0.073 1.60Benzene 1 02/27/24 01:36 V44517ENM <0.060 µg/m3 0.060 6.23Carbon Disulfide 1 02/27/24 01:36 V44517ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 02/27/24 01:36 V44517ENM <0.086 µg/m3 0.086 2.44Chloroform 1 02/27/24 01:36 V44517ENM <0.067 µg/m3 0.067 1.03Chloromethane 1 02/27/24 01:36 V44517ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 02/27/24 01:36 V44517ENM 2.83 µg/m3 0.134 2.47Dichlorodifluoromethane 1 02/27/24 01:36 V44517ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 02/27/24 01:36 V44517ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 02/27/24 01:36 V44517ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 02/27/24 01:36 V44517ENM 0.597 J µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 02/27/24 01:36 V44517ENM 0.672 J µg/m3 0.143 2.05Heptane 1 02/27/24 01:36 V44517ENM 0.676 J µg/m3 0.047 1.76n-Hexane 1 02/27/24 01:36 V44517ENM 2.88 JB µg/m3 0.139 4.92Isopropyl Alcohol 1 02/27/24 01:36 V44517ENM 3.49 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 02/27/24 01:36 V44517ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 02/27/24 01:36 V44517ENM 1.28 J µg/m3 0.488 1.74Methylene Chloride 1 02/27/24 01:36 V44517ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 02/27/24 01:36 V44517ENM <0.242 µg/m3 0.242 0.860Propene 1 02/27/24 01:36 V44517ENM <0.124 µg/m3 0.124 2.13Styrene 1 02/27/24 01:36 V44517ENM <0.181 µg/m3 0.181 3.39Tetrachloroethene 1 02/27/24 01:36 V44517ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 15 of 38 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-053-0009 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 David Kahn Charlotte Received : 02/22/2024 PDP-001 Report Date : 03/08/2024 Sample ID : Lab No : Sampled:IAS-BKG 97581 Matrix: 2/20/2024 11:23 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V44513 02/29/24 09:00 1.66 µg/m3 0.107 1.47Tetrahydrofuran 1 02/27/24 01:36 V44517ENM 3.52 µg/m3 0.090 1.88Toluene 1 02/27/24 01:36 V44517ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 02/27/24 01:36 V44517ENM 1.62 J µg/m3 0.130 2.81Trichlorofluoromethane 1 02/27/24 01:36 V44517ENM <0.110 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 02/27/24 01:36 V44517ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 02/27/24 01:36 V44517ENM 0.408 J µg/m3 0.157 2.17o-Xylene 1 02/27/24 01:36 V44517ENM 0.864 J µg/m3 0.217 5.65m,p-Xylene 1 02/27/24 01:36 V44517ENM 1.27 J µg/m3 0.157 2.17Xylene (Total)1 02/27/24 01:36 V44517 Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%02/27/24 01:361 ENM V44133 Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%02/27/24 01:361 ENM V44517 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 16 of 38 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-053-0009 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 David Kahn Charlotte Received : 02/22/2024 PDP-001 Report Date : 03/08/2024 Sample ID : Lab No : Sampled:MP-DUP 97582 Matrix: 2/21/2024 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V44132 02/26/24 09:00 67.4 µg/m3 0.202 4.75Acetone 1 02/26/24 20:51 V44133ENM 2.44 µg/m3 0.073 1.60Benzene 1 02/26/24 20:51 V44133ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 02/26/24 20:51 V44133ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 02/26/24 20:51 V44133ENM <0.153 µg/m3 0.153 5.17Bromoform 1 02/26/24 20:51 V44133ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 02/26/24 20:51 V44133ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 02/26/24 20:51 V44133ENM 0.737 J µg/m3 0.060 6.23Carbon Disulfide 1 02/26/24 20:51 V44133ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 02/26/24 20:51 V44133ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 02/26/24 20:51 V44133ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 02/26/24 20:51 V44133ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 02/26/24 20:51 V44133ENM 0.517 J µg/m3 0.086 2.44Chloroform 1 02/26/24 20:51 V44133ENM <0.067 µg/m3 0.067 1.03Chloromethane 1 02/26/24 20:51 V44133ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 02/26/24 20:51 V44133ENM <0.151 µg/m3 0.151 3.841,2-Dibromoethane 1 02/26/24 20:51 V44133ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 02/26/24 20:51 V44133ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 02/26/24 20:51 V44133ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 02/26/24 20:51 V44133ENM 2.90 µg/m3 0.134 2.47Dichlorodifluoromethane 1 02/26/24 20:51 V44133ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 02/26/24 20:51 V44133ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 02/26/24 20:51 V44133ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 17 of 38 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-053-0009 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 David Kahn Charlotte Received : 02/22/2024 PDP-001 Report Date : 03/08/2024 Sample ID : Lab No : Sampled:MP-DUP 97582 Matrix: 2/21/2024 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V44132 02/26/24 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 02/26/24 20:51 V44133ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 02/26/24 20:51 V44133ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 02/26/24 20:51 V44133ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 02/26/24 20:51 V44133ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 02/26/24 20:51 V44133ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 02/26/24 20:51 V44133ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 02/26/24 20:51 V44133ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 02/26/24 20:51 V44133ENM <0.136 µg/m3 0.136 1.80Ethyl Acetate 1 02/26/24 20:51 V44133ENM 1.44 J µg/m3 0.106 2.17Ethylbenzene 1 02/26/24 20:51 V44133ENM 0.408 J µg/m3 0.128 2.464-Ethyltoluene 1 02/26/24 20:51 V44133ENM 0.643 J µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 02/26/24 20:51 V44133ENM 0.368 J µg/m3 0.143 2.05Heptane 1 02/26/24 20:51 V44133ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 02/26/24 20:51 V44133ENM 1.11 J µg/m3 0.047 1.76n-Hexane 1 02/26/24 20:51 V44133ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 02/26/24 20:51 V44133ENM 3.52 JB µg/m3 0.139 4.92Isopropyl Alcohol 1 02/26/24 20:51 V44133ENM 79.0 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 02/26/24 20:51 V44133ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 02/26/24 20:51 V44133ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 02/26/24 20:51 V44133ENM 1.55 J µg/m3 0.488 1.74Methylene Chloride 1 02/26/24 20:51 V44133ENM 0.560 J µg/m3 0.183 2.62Naphthalene 1 02/26/24 20:51 V44133ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 18 of 38 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-053-0009 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 David Kahn Charlotte Received : 02/22/2024 PDP-001 Report Date : 03/08/2024 Sample ID : Lab No : Sampled:MP-DUP 97582 Matrix: 2/21/2024 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V44132 02/26/24 09:00 4.59 µg/m3 0.242 0.860Propene 1 02/26/24 20:51 V44133ENM 0.379 J µg/m3 0.124 2.13Styrene 1 02/26/24 20:51 V44133ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 02/26/24 20:51 V44133ENM <0.181 µg/m3 0.181 3.39Tetrachloroethene 1 02/26/24 20:51 V44133ENM 63.7 µg/m3 0.107 1.47Tetrahydrofuran 1 02/26/24 20:51 V44133ENM 3.32 µg/m3 0.090 1.88Toluene 1 02/26/24 20:51 V44133ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 02/26/24 20:51 V44133ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 02/26/24 20:51 V44133ENM <0.087 µg/m3 0.087 2.731,1,2-Trichloroethane 1 02/26/24 20:51 V44133ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 02/26/24 20:51 V44133ENM 1.74 J µg/m3 0.130 2.81Trichlorofluoromethane 1 02/26/24 20:51 V44133ENM 1.82 J µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 02/26/24 20:51 V44133ENM 0.535 J µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 02/26/24 20:51 V44133ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 02/26/24 20:51 V44133ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 02/26/24 20:51 V44133ENM 2.62 µg/m3 0.157 2.17o-Xylene 1 02/26/24 20:51 V44133ENM 5.47 J µg/m3 0.217 5.65m,p-Xylene 1 02/26/24 20:51 V44133ENM 8.09 J µg/m3 0.157 2.17Xylene (Total)1 02/26/24 20:51 V44133 Surrogate: 4-Bromofluorobenzene 98.9 Limits: 70-130%02/26/24 20:511 ENM V44133 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 19 of 38 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-053-0009 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 David Kahn Charlotte Received : 02/22/2024 PDP-001 Report Date : 03/08/2024 Sample ID : Lab No : Sampled:MP-5 97583 Matrix: 2/21/2024 15:57 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V44132 02/26/24 09:00 66.0 µg/m3 0.202 4.75Acetone 1 02/26/24 21:43 V44133ENM 2.47 µg/m3 0.073 1.60Benzene 1 02/26/24 21:43 V44133ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 02/26/24 21:43 V44133ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 02/26/24 21:43 V44133ENM <0.153 µg/m3 0.153 5.17Bromoform 1 02/26/24 21:43 V44133ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 02/26/24 21:43 V44133ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 02/26/24 21:43 V44133ENM 0.747 J µg/m3 0.060 6.23Carbon Disulfide 1 02/26/24 21:43 V44133ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 02/26/24 21:43 V44133ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 02/26/24 21:43 V44133ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 02/26/24 21:43 V44133ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 02/26/24 21:43 V44133ENM 0.522 J µg/m3 0.086 2.44Chloroform 1 02/26/24 21:43 V44133ENM <0.067 µg/m3 0.067 1.03Chloromethane 1 02/26/24 21:43 V44133ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 02/26/24 21:43 V44133ENM <0.151 µg/m3 0.151 3.841,2-Dibromoethane 1 02/26/24 21:43 V44133ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 02/26/24 21:43 V44133ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 02/26/24 21:43 V44133ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 02/26/24 21:43 V44133ENM 2.84 µg/m3 0.134 2.47Dichlorodifluoromethane 1 02/26/24 21:43 V44133ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 02/26/24 21:43 V44133ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 02/26/24 21:43 V44133ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 20 of 38 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-053-0009 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 David Kahn Charlotte Received : 02/22/2024 PDP-001 Report Date : 03/08/2024 Sample ID : Lab No : Sampled:MP-5 97583 Matrix: 2/21/2024 15:57 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V44132 02/26/24 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 02/26/24 21:43 V44133ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 02/26/24 21:43 V44133ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 02/26/24 21:43 V44133ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 02/26/24 21:43 V44133ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 02/26/24 21:43 V44133ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 02/26/24 21:43 V44133ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 02/26/24 21:43 V44133ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 02/26/24 21:43 V44133ENM <0.136 µg/m3 0.136 1.80Ethyl Acetate 1 02/26/24 21:43 V44133ENM 1.44 J µg/m3 0.106 2.17Ethylbenzene 1 02/26/24 21:43 V44133ENM 0.408 J µg/m3 0.128 2.464-Ethyltoluene 1 02/26/24 21:43 V44133ENM 0.597 J µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 02/26/24 21:43 V44133ENM 0.401 J µg/m3 0.143 2.05Heptane 1 02/26/24 21:43 V44133ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 02/26/24 21:43 V44133ENM 1.42 J µg/m3 0.047 1.76n-Hexane 1 02/26/24 21:43 V44133ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 02/26/24 21:43 V44133ENM 3.83 JB µg/m3 0.139 4.92Isopropyl Alcohol 1 02/26/24 21:43 V44133ENM 76.2 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 02/26/24 21:43 V44133ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 02/26/24 21:43 V44133ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 02/26/24 21:43 V44133ENM 3.94 µg/m3 0.488 1.74Methylene Chloride 1 02/26/24 21:43 V44133ENM 0.492 J µg/m3 0.183 2.62Naphthalene 1 02/26/24 21:43 V44133ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 21 of 38 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-053-0009 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 David Kahn Charlotte Received : 02/22/2024 PDP-001 Report Date : 03/08/2024 Sample ID : Lab No : Sampled:MP-5 97583 Matrix: 2/21/2024 15:57 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V44132 02/26/24 09:00 4.59 µg/m3 0.242 0.860Propene 1 02/26/24 21:43 V44133ENM 0.379 J µg/m3 0.124 2.13Styrene 1 02/26/24 21:43 V44133ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 02/26/24 21:43 V44133ENM <0.181 µg/m3 0.181 3.39Tetrachloroethene 1 02/26/24 21:43 V44133ENM 63.9 µg/m3 0.107 1.47Tetrahydrofuran 1 02/26/24 21:43 V44133ENM 3.34 µg/m3 0.090 1.88Toluene 1 02/26/24 21:43 V44133ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 02/26/24 21:43 V44133ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 02/26/24 21:43 V44133ENM <0.087 µg/m3 0.087 2.731,1,2-Trichloroethane 1 02/26/24 21:43 V44133ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 02/26/24 21:43 V44133ENM 1.80 J µg/m3 0.130 2.81Trichlorofluoromethane 1 02/26/24 21:43 V44133ENM 1.85 J µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 02/26/24 21:43 V44133ENM 0.565 J µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 02/26/24 21:43 V44133ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 02/26/24 21:43 V44133ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 02/26/24 21:43 V44133ENM 2.73 µg/m3 0.157 2.17o-Xylene 1 02/26/24 21:43 V44133ENM 5.53 J µg/m3 0.217 5.65m,p-Xylene 1 02/26/24 21:43 V44133ENM 8.26 J µg/m3 0.157 2.17Xylene (Total)1 02/26/24 21:43 V44133 Surrogate: 4-Bromofluorobenzene 98.9 Limits: 70-130%02/26/24 21:431 ENM V44133 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 22 of 38 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-053-0009 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 David Kahn Charlotte Received : 02/22/2024 PDP-001 Report Date : 03/08/2024 Sample ID : Lab No : Sampled:MP-3 97584 Matrix: 2/21/2024 11:50 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V44132 02/26/24 09:00 V44146 02/27/24 09:00 17400 µg/m3 40.4 950Acetone 200 02/27/24 15:05 V44148ENM <1.46 µg/m3 1.46 31.9Benzene 20 02/26/24 22:19 V44133ENM <2.94 µg/m3 2.94 207Benzyl Chloride 20 02/26/24 22:19 V44133ENM <3.00 µg/m3 3.00 67.0Bromodichloromethane 20 02/26/24 22:19 V44133ENM <3.05 µg/m3 3.05 103Bromoform 20 02/26/24 22:19 V44133ENM <2.30 µg/m3 2.30 38.8Bromomethane 20 02/26/24 22:19 V44133ENM <6.53 µg/m3 6.53 22.11,3-Butadiene 20 02/26/24 22:19 V44133ENM <1.22 µg/m3 1.22 125Carbon Disulfide 20 02/26/24 22:19 V44133ENM <3.10 µg/m3 3.10 62.9Carbon Tetrachloride 20 02/26/24 22:19 V44133ENM <2.14 µg/m3 2.14 46.0Chlorobenzene 20 02/26/24 22:19 V44133ENM <4.16 µg/m3 4.16 85.2Chlorodibromomethane 20 02/26/24 22:19 V44133ENM <3.28 µg/m3 3.28 26.4Chloroethane 20 02/26/24 22:19 V44133ENM <1.73 µg/m3 1.73 48.8Chloroform 20 02/26/24 22:19 V44133ENM <1.34 µg/m3 1.34 20.6Chloromethane 20 02/26/24 22:19 V44133ENM 28.7 J µg/m3 3.22 68.8Cyclohexane 20 02/26/24 22:19 V44133ENM <3.02 µg/m3 3.02 76.81,2-Dibromoethane 20 02/26/24 22:19 V44133ENM <1.92 µg/m3 1.92 60.11,2-Dichlorobenzene 20 02/26/24 22:19 V44133ENM <3.48 µg/m3 3.48 2411,3-Dichlorobenzene 20 02/26/24 22:19 V44133ENM <3.72 µg/m3 3.72 60.11,4-Dichlorobenzene 20 02/26/24 22:19 V44133ENM <2.68 µg/m3 2.68 49.4Dichlorodifluoromethane 20 02/26/24 22:19 V44133ENM <2.02 µg/m3 2.02 40.51,1-Dichloroethane 20 02/26/24 22:19 V44133ENM <2.58 µg/m3 2.58 40.51,2-Dichloroethane 20 02/26/24 22:19 V44133ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 23 of 38 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-053-0009 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 David Kahn Charlotte Received : 02/22/2024 PDP-001 Report Date : 03/08/2024 Sample ID : Lab No : Sampled:MP-3 97584 Matrix: 2/21/2024 11:50 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V44132 02/26/24 09:00 V44146 02/27/24 09:00 <2.14 µg/m3 2.14 39.61,1-Dichloroethene 20 02/26/24 22:19 V44133ENM <1.91 µg/m3 1.91 39.6cis-1,2-Dichloroethene 20 02/26/24 22:19 V44133ENM <2.16 µg/m3 2.16 39.6trans-1,2-Dichloroethene 20 02/26/24 22:19 V44133ENM <4.10 µg/m3 4.10 46.21,2-Dichloropropane 20 02/26/24 22:19 V44133ENM <12.4 µg/m3 12.4 69.91,2-Dichlorotetrafluoroethane 20 02/26/24 22:19 V44133ENM <3.56 µg/m3 3.56 45.4cis-1,3-Dichloropropene 20 02/26/24 22:19 V44133ENM <3.56 µg/m3 3.56 45.4trans-1,3-Dichloropropene 20 02/26/24 22:19 V44133ENM <8.69 µg/m3 8.69 36.01,4-Dioxane 20 02/26/24 22:19 V44133ENM <2.72 µg/m3 2.72 36.0Ethyl Acetate 20 02/26/24 22:19 V44133ENM <2.12 µg/m3 2.12 43.4Ethylbenzene 20 02/26/24 22:19 V44133ENM <2.56 µg/m3 2.56 49.24-Ethyltoluene 20 02/26/24 22:19 V44133ENM <11.2 µg/m3 11.2 76.61,1,2-Trichloro-1,2,2-trifluoroethane 20 02/26/24 22:19 V44133ENM <2.86 µg/m3 2.86 41.0Heptane 20 02/26/24 22:19 V44133ENM <6.62 µg/m3 6.62 107Hexachlorobutadiene 20 02/26/24 22:19 V44133ENM <0.942 µg/m3 0.942 35.2n-Hexane 20 02/26/24 22:19 V44133ENM <5.71 µg/m3 5.71 41.02-Hexanone 20 02/26/24 22:19 V44133ENM 55.1 J µg/m3 2.78 98.3Isopropyl Alcohol 20 02/26/24 22:19 V44133ENM <4.48 µg/m3 4.48 29.5Methyl Ethyl Ketone (MEK)20 02/26/24 22:19 V44133ENM <0.672 µg/m3 0.672 36.1Methyl tert-butyl ether (MTBE)20 02/26/24 22:19 V44133ENM <2.42 µg/m3 2.42 41.04-Methyl-2-Pentanone 20 02/26/24 22:19 V44133ENM 12.4 J µg/m3 9.75 34.7Methylene Chloride 20 02/26/24 22:19 V44133ENM <3.66 µg/m3 3.66 52.4Naphthalene 20 02/26/24 22:19 V44133ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 24 of 38 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-053-0009 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 David Kahn Charlotte Received : 02/22/2024 PDP-001 Report Date : 03/08/2024 Sample ID : Lab No : Sampled:MP-3 97584 Matrix: 2/21/2024 11:50 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V44132 02/26/24 09:00 V44146 02/27/24 09:00 <4.84 µg/m3 4.84 17.2Propene 20 02/26/24 22:19 V44133ENM <2.48 µg/m3 2.48 42.6Styrene 20 02/26/24 22:19 V44133ENM <2.08 µg/m3 2.08 68.61,1,2,2-Tetrachloroethane 20 02/26/24 22:19 V44133ENM <3.62 µg/m3 3.62 67.8Tetrachloroethene 20 02/26/24 22:19 V44133ENM 14200 µg/m3 21.4 295Tetrahydrofuran 200 02/27/24 15:05 V44148ENM <1.80 µg/m3 1.80 37.7Toluene 20 02/26/24 22:19 V44133ENM <4.18 µg/m3 4.18 74.21,2,4-Trichlorobenzene 20 02/26/24 22:19 V44133ENM <2.88 µg/m3 2.88 54.61,1,1-Trichloroethane 20 02/26/24 22:19 V44133ENM <1.75 µg/m3 1.75 54.61,1,2-Trichloroethane 20 02/26/24 22:19 V44133ENM <3.98 µg/m3 3.98 43.0Trichloroethene 20 02/26/24 22:19 V44133ENM <2.60 µg/m3 2.60 56.2Trichlorofluoromethane 20 02/26/24 22:19 V44133ENM <2.20 µg/m3 2.20 49.21,2,4-Trimethylbenzene 20 02/26/24 22:19 V44133ENM <4.72 µg/m3 4.72 49.21,3,5-Trimethylbenzene 20 02/26/24 22:19 V44133ENM <4.48 µg/m3 4.48 35.2Vinyl Acetate 20 02/26/24 22:19 V44133ENM <2.54 µg/m3 2.54 25.6Vinyl Chloride 20 02/26/24 22:19 V44133ENM <3.14 µg/m3 3.14 43.4o-Xylene 20 02/26/24 22:19 V44133ENM 7.47 J µg/m3 4.34 113m,p-Xylene 20 02/26/24 22:19 V44133ENM 7.47 J µg/m3 3.14 43.4Xylene (Total)20 02/26/24 22:19 V44133 Surrogate: 4-Bromofluorobenzene 102 Limits: 70-130%02/26/24 22:1920 ENM V44133 Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%02/27/24 15:05200 ENM V44148 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 25 of 38 Quality Control Data 24-053-0009Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PDP-001 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V44133QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V44132 Associated Lab Samples: 97582, 97583, 97584 LRB-V44132 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/26/24 13:174.750.2021.05µg/m3Acetone 02/26/24 13:171.600.073<0.073µg/m3Benzene 02/26/24 13:1710.40.147<0.147µg/m3Benzyl Chloride 02/26/24 13:173.350.150<0.150µg/m3Bromodichloromethane 02/26/24 13:175.170.153<0.153µg/m3Bromoform 02/26/24 13:171.940.115<0.115µg/m3Bromomethane 02/26/24 13:171.110.328<0.328µg/m31,3-Butadiene 02/26/24 13:176.230.060<0.060µg/m3Carbon Disulfide 02/26/24 13:173.150.155<0.155µg/m3Carbon Tetrachloride 02/26/24 13:172.300.107<0.107µg/m3Chlorobenzene 02/26/24 13:174.260.208<0.208µg/m3Chlorodibromomethane 02/26/24 13:171.320.164<0.164µg/m3Chloroethane 02/26/24 13:172.440.086<0.086µg/m3Chloroform 02/26/24 13:171.030.067<0.067µg/m3Chloromethane 02/26/24 13:173.440.161<0.161µg/m3Cyclohexane 02/26/24 13:173.840.151<0.151µg/m31,2-Dibromoethane 02/26/24 13:173.010.096<0.096µg/m31,2-Dichlorobenzene 02/26/24 13:1712.00.174<0.174µg/m31,3-Dichlorobenzene 02/26/24 13:173.010.186<0.186µg/m31,4-Dichlorobenzene 02/26/24 13:172.470.134<0.134µg/m3Dichlorodifluoromethane 02/26/24 13:172.020.101<0.101µg/m31,1-Dichloroethane 02/26/24 13:172.020.129<0.129µg/m31,2-Dichloroethane 02/26/24 13:171.980.107<0.107µg/m31,1-Dichloroethene 02/26/24 13:171.980.095<0.095µg/m3cis-1,2-Dichloroethene 02/26/24 13:171.980.108<0.108µg/m3trans-1,2-Dichloroethene 02/26/24 13:172.310.205<0.205µg/m31,2-Dichloropropane 02/26/24 13:173.500.622<0.622µg/m31,2-Dichlorotetrafluoroethane Page 1 of 10Date:03/08/2024 10:03 AM Page 26 of 38 Quality Control Data 24-053-0009Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PDP-001 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V44133QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V44132 Associated Lab Samples: 97582, 97583, 97584 LRB-V44132 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/26/24 13:172.270.178<0.178µg/m3cis-1,3-Dichloropropene 02/26/24 13:172.270.178<0.178µg/m3trans-1,3-Dichloropropene 02/26/24 13:171.800.435<0.435µg/m31,4-Dioxane 02/26/24 13:171.800.136<0.136µg/m3Ethyl Acetate 02/26/24 13:172.170.106<0.106µg/m3Ethylbenzene 02/26/24 13:172.460.128<0.128µg/m34-Ethyltoluene 02/26/24 13:173.830.561<0.561µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 02/26/24 13:172.050.143<0.143µg/m3Heptane 02/26/24 13:175.330.330<0.330µg/m3Hexachlorobutadiene 02/26/24 13:171.760.047<0.047µg/m3n-Hexane 02/26/24 13:172.050.285<0.285µg/m32-Hexanone 02/26/24 13:174.920.1391.54µg/m3Isopropyl Alcohol 02/26/24 13:171.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 02/26/24 13:171.800.033<0.033µg/m3Methyl tert-butyl ether (MTBE) 02/26/24 13:172.050.121<0.121µg/m34-Methyl-2-Pentanone 02/26/24 13:171.740.488<0.488µg/m3Methylene Chloride 02/26/24 13:172.620.183<0.183µg/m3Naphthalene 02/26/24 13:170.8600.242<0.242µg/m3Propene 02/26/24 13:172.130.124<0.124µg/m3Styrene 02/26/24 13:173.430.104<0.104µg/m31,1,2,2-Tetrachloroethane 02/26/24 13:173.390.181<0.181µg/m3Tetrachloroethene 02/26/24 13:171.470.107<0.107µg/m3Tetrahydrofuran 02/26/24 13:171.880.090<0.090µg/m3Toluene 02/26/24 13:173.710.209<0.209µg/m31,2,4-Trichlorobenzene 02/26/24 13:172.730.144<0.144µg/m31,1,1-Trichloroethane 02/26/24 13:172.730.087<0.087µg/m31,1,2-Trichloroethane 02/26/24 13:172.150.199<0.199µg/m3Trichloroethene Page 2 of 10Date:03/08/2024 10:03 AM Page 27 of 38 Quality Control Data 24-053-0009Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PDP-001 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V44133QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V44132 Associated Lab Samples: 97582, 97583, 97584 LRB-V44132 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/26/24 13:172.810.130<0.130µg/m3Trichlorofluoromethane 02/26/24 13:172.460.110<0.110µg/m31,2,4-Trimethylbenzene 02/26/24 13:172.460.236<0.236µg/m31,3,5-Trimethylbenzene 02/26/24 13:171.760.224<0.224µg/m3Vinyl Acetate 02/26/24 13:171.280.127<0.127µg/m3Vinyl Chloride 02/26/24 13:172.170.157<0.157µg/m3o-Xylene 02/26/24 13:175.650.217<0.217µg/m3m,p-Xylene 02/26/24 13:174-Bromofluorobenzene (S)94.1 70-130 LCS-V44132Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 93.211.111.9µg/m3Acetone 70-130 88.114.116.0µg/m3Benzene 70-130 98.025.425.9µg/m3Benzyl Chloride 70-130 87.729.433.5µg/m3Bromodichloromethane 70-130 93.848.551.7µg/m3Bromoform 70-130 95.318.519.4µg/m3Bromomethane 70-130 95.410.611.1µg/m31,3-Butadiene 70-130 97.415.215.6µg/m3Carbon Disulfide 70-130 87.627.631.5µg/m3Carbon Tetrachloride 70-130 95.622.023.0µg/m3Chlorobenzene 70-130 93.139.742.6µg/m3Chlorodibromomethane 70-130 93.912.413.2µg/m3Chloroethane 70-130 90.922.224.4µg/m3Chloroform 70-130 10310.610.3µg/m3Chloromethane 70-130 88.915.317.2µg/m3Cyclohexane 70-130 Page 3 of 10Date:03/08/2024 10:03 AM Page 28 of 38 Quality Control Data 24-053-0009Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PDP-001 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V44133QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V44132 LCS-V44132Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 95.536.738.4µg/m31,2-Dibromoethane 70-130 10130.530.1µg/m31,2-Dichlorobenzene 70-130 10030.130.1µg/m31,3-Dichlorobenzene 70-130 10130.330.1µg/m31,4-Dichlorobenzene 70-130 93.923.224.7µg/m3Dichlorodifluoromethane 70-130 98.519.920.2µg/m31,1-Dichloroethane 70-130 89.118.020.2µg/m31,2-Dichloroethane 70-130 98.419.519.8µg/m31,1-Dichloroethene 70-130 96.919.219.8µg/m3cis-1,2-Dichloroethene 70-130 98.419.519.8µg/m3trans-1,2-Dichloroethene 70-130 88.720.523.1µg/m31,2-Dichloropropane 70-130 95.433.435.0µg/m31,2-Dichlorotetrafluoroethane 70-130 86.719.722.7µg/m3cis-1,3-Dichloropropene 70-130 85.919.522.7µg/m3trans-1,3-Dichloropropene 70-130 85.515.418.0µg/m31,4-Dioxane 70-130 92.716.718.0µg/m3Ethyl Acetate 70-130 94.420.521.7µg/m3Ethylbenzene 70-130 96.323.724.6µg/m34-Ethyltoluene 70-130 97.637.438.3µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 70-130 90.218.520.5µg/m3Heptane 70-130 91.148.653.3µg/m3Hexachlorobutadiene 70-130 97.717.217.6µg/m3n-Hexane 70-130 93.119.120.5µg/m32-Hexanone 70-130 95.111.712.3µg/m3Isopropyl Alcohol 70-130 93.913.914.8µg/m3Methyl Ethyl Ketone (MEK)70-130 94.417.018.0µg/m3Methyl tert-butyl ether (MTBE)70-130 87.818.020.5µg/m34-Methyl-2-Pentanone 70-130 Page 4 of 10Date:03/08/2024 10:03 AM Page 29 of 38 Quality Control Data 24-053-0009Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PDP-001 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V44133QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V44132 LCS-V44132Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 89.615.617.4µg/m3Methylene Chloride 70-130 10226.726.2µg/m3Naphthalene 70-130 93.38.048.61µg/m3Propene 70-130 92.419.721.3µg/m3Styrene 70-130 94.732.534.3µg/m31,1,2,2-Tetrachloroethane 70-130 89.330.333.9µg/m3Tetrachloroethene 70-130 89.713.214.7µg/m3Tetrahydrofuran 70-130 88.216.618.8µg/m3Toluene 70-130 97.536.237.1µg/m31,2,4-Trichlorobenzene 70-130 88.224.127.3µg/m31,1,1-Trichloroethane 70-130 93.425.527.3µg/m31,1,2-Trichloroethane 70-130 91.024.526.9µg/m3Trichloroethene 70-130 98.227.628.1µg/m3Trichlorofluoromethane 70-130 10124.824.6µg/m31,2,4-Trimethylbenzene 70-130 10225.024.6µg/m31,3,5-Trimethylbenzene 70-130 92.616.317.6µg/m3Vinyl Acetate 70-130 96.012.312.8µg/m3Vinyl Chloride 70-130 96.320.921.7µg/m3o-Xylene 70-130 96.742.043.4µg/m3m,p-Xylene 70-130 1014-Bromofluorobenzene (S)70-130 Page 5 of 10Date:03/08/2024 10:03 AM Page 30 of 38 Quality Control Data 24-053-0009Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PDP-001 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V44148QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V44146 Associated Lab Samples: 97584 LRB-V44146 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/27/24 14:294.750.2021.04µg/m3Acetone 02/27/24 14:291.470.107<0.107µg/m3Tetrahydrofuran 02/27/24 14:294-Bromofluorobenzene (S)98.3 70-130 LCS-V44146Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 94.911.311.9µg/m3Acetone 70-130 91.113.414.7µg/m3Tetrahydrofuran 70-130 1054-Bromofluorobenzene (S)70-130 Page 6 of 10Date:03/08/2024 10:03 AM Page 31 of 38 Quality Control Data 24-053-0009Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PDP-001 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V44517QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V44513 Associated Lab Samples: 97578, 97579, 97580, 97581 LRB-V44513 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/26/24 13:174.750.2021.05µg/m3Acetone 02/26/24 13:171.600.073<0.073µg/m3Benzene 02/26/24 13:176.230.060<0.060µg/m3Carbon Disulfide 02/26/24 13:173.150.155<0.155µg/m3Carbon Tetrachloride 02/26/24 13:172.440.086<0.086µg/m3Chloroform 02/26/24 13:171.030.067<0.067µg/m3Chloromethane 02/26/24 13:173.440.161<0.161µg/m3Cyclohexane 02/26/24 13:172.470.134<0.134µg/m3Dichlorodifluoromethane 02/26/24 13:171.980.095<0.095µg/m3cis-1,2-Dichloroethene 02/26/24 13:172.170.106<0.106µg/m3Ethylbenzene 02/26/24 13:172.460.128<0.128µg/m34-Ethyltoluene 02/26/24 13:173.830.561<0.561µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 02/26/24 13:172.050.143<0.143µg/m3Heptane 02/26/24 13:171.760.047<0.047µg/m3n-Hexane 02/26/24 13:174.920.1391.54µg/m3Isopropyl Alcohol 02/26/24 13:171.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 02/26/24 13:171.800.033<0.033µg/m3Methyl tert-butyl ether (MTBE) 02/26/24 13:171.740.488<0.488µg/m3Methylene Chloride 02/26/24 13:172.620.183<0.183µg/m3Naphthalene 02/26/24 13:170.8600.242<0.242µg/m3Propene 02/26/24 13:172.130.124<0.124µg/m3Styrene 02/26/24 13:173.390.181<0.181µg/m3Tetrachloroethene 02/26/24 13:171.470.107<0.107µg/m3Tetrahydrofuran 02/26/24 13:171.880.090<0.090µg/m3Toluene 02/26/24 13:172.150.199<0.199µg/m3Trichloroethene 02/26/24 13:172.810.130<0.130µg/m3Trichlorofluoromethane 02/26/24 13:172.460.110<0.110µg/m31,2,4-Trimethylbenzene Page 7 of 10Date:03/08/2024 10:03 AM Page 32 of 38 Quality Control Data 24-053-0009Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PDP-001 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V44517QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V44513 Associated Lab Samples: 97578, 97579, 97580, 97581 LRB-V44513 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/26/24 13:172.460.236<0.236µg/m31,3,5-Trimethylbenzene 02/26/24 13:172.170.157<0.157µg/m3o-Xylene 02/26/24 13:175.650.217<0.217µg/m3m,p-Xylene 02/26/24 13:174-Bromofluorobenzene (S)94.1 70-130 LCS-V44513Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 93.211.111.9µg/m3Acetone 70-130 88.114.116.0µg/m3Benzene 70-130 97.415.215.6µg/m3Carbon Disulfide 70-130 87.627.631.5µg/m3Carbon Tetrachloride 70-130 90.922.224.4µg/m3Chloroform 70-130 10310.610.3µg/m3Chloromethane 70-130 88.915.317.2µg/m3Cyclohexane 70-130 93.923.224.7µg/m3Dichlorodifluoromethane 70-130 96.919.219.8µg/m3cis-1,2-Dichloroethene 70-130 94.420.521.7µg/m3Ethylbenzene 70-130 96.323.724.6µg/m34-Ethyltoluene 70-130 97.637.438.3µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 70-130 90.218.520.5µg/m3Heptane 70-130 97.717.217.6µg/m3n-Hexane 70-130 95.111.712.3µg/m3Isopropyl Alcohol 70-130 93.913.914.8µg/m3Methyl Ethyl Ketone (MEK)70-130 94.417.018.0µg/m3Methyl tert-butyl ether (MTBE)70-130 89.615.617.4µg/m3Methylene Chloride 70-130 10226.726.2µg/m3Naphthalene 70-130 Page 8 of 10Date:03/08/2024 10:03 AM Page 33 of 38 Quality Control Data 24-053-0009Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PDP-001 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V44517QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V44513 LCS-V44513Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 93.38.048.61µg/m3Propene 70-130 92.419.721.3µg/m3Styrene 70-130 89.330.333.9µg/m3Tetrachloroethene 70-130 89.713.214.7µg/m3Tetrahydrofuran 70-130 88.216.618.8µg/m3Toluene 70-130 91.024.526.9µg/m3Trichloroethene 70-130 98.227.628.1µg/m3Trichlorofluoromethane 70-130 10124.824.6µg/m31,2,4-Trimethylbenzene 70-130 10225.024.6µg/m31,3,5-Trimethylbenzene 70-130 96.320.921.7µg/m3o-Xylene 70-130 96.742.043.4µg/m3m,p-Xylene 70-130 1014-Bromofluorobenzene (S)70-130 Page 9 of 10Date:03/08/2024 10:03 AM Page 34 of 38 Quality Control Data 24-053-0009Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PDP-001 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V44550QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V44549 Associated Lab Samples: 97578, 97579, 97580 LRB-V44549 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/27/24 14:294.750.2021.04µg/m3Acetone 02/27/24 14:294-Bromofluorobenzene (S)98.3 70-130 LCS-V44549Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 94.911.311.9µg/m3Acetone 70-130 1054-Bromofluorobenzene (S)70-130 Page 10 of 10Date:03/08/2024 10:03 AM Page 35 of 38 Fed Ex UPS US Postal Client Lab Courier Other : Shipment Receipt Form Customer Number: Customer Name: Report Number:24-053-0009 Hart & Hickman (Charlotte) 01102 Shipping Method Shipping container/cooler uncompromised? Thermometer ID:N/A Chain of Custody (COC) present?Yes No Yes No Not Present Yes No Not Present Yes No COC agrees with sample label(s)? Yes No COC properly completed Samples in proper containers? Sample containers intact? Sufficient sample volume for indicated test(s)? All samples received within holding time? Cooler temperature in compliance? Yes No Yes No Yes No Yes No Yes No Yes NoCooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes No Yes No N/A Yes No N/A Yes No N/ASoil VOA method 5035 – compliance criteria met Water - Sample containers properly preserved Water - VOA vials free of headspace Yes No N/A Trip Blanks received with VOAs Low concentration EnCore samplers (48 hr) High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d) High concentration container (48 hr) Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Number of coolers/boxes received Yes No 1 Signature:Angelo Norvell Date & Time:02/22/2024 12:06:35 Special precautions or instructions included? Comments: Page 36 of 38 Page 37 of 38 Page 38 of 38 Select List VOCs TO-15 28-Feb-24 Acetone Benzene Carbon Disulfide Carbon Tetrachloride Chloroform Chloromethane Cyclohexane cis-1,2-Dichloroethene Dichlorodifluoromethane Ethylbenzene 4-Ethyllouene Heptane n-Hexane Isopropyl Alcohol Methyl Ethyl Ketone (MEK) Methyl tert butyl ether Methylene Chloride Naphthalene Propene Styrene Tetrachloroethene Tetrahydrofuran Toluene Trichloroethene Trichlorofluoromethane 1,1,2-Trichloro-1,2,2-Trifluoroethane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene o-Xylene m,p-Xylene Xylene (Total) Page 1 Appendix G Safety Data Sheets MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No. 9950 Revision Date: 09/25/2007 Page 1 of 9 NFPA 704 (Section 16) EMERGENCY OVERVIEW DANGER! EXTREMELY FLAMMABLE - EYE AND MUCOUS MEMBRANE IRRITANT - EFFECTS CENTRAL NERVOUS SYSTEM - HARMFUL OR FATAL IF SWALLOWED - ASPIRATION HAZARD High fire hazard. Keep away from heat, spark, open flame, and other ignition sources. If ingested, do NOT induce vomiting, as this may cause chemical pneumonia (fluid in the lungs). Contact may cause eye, skin and mucous membrane irritation. Harmful if absorbed through the skin. Avoid prolonged breathing of vapors or mists. Inhalation may cause irritation, anesthetic effects (dizziness, nausea, headache, intoxication), and respiratory system effects. Long-term exposure may cause effects to specific organs, such as to the liver, kidneys, blood, nervous system, and skin. Contains benzene, which can cause blood disease, including anemia and leukemia. 1. CHEMICAL PRODUCT and COMPANY INFORMATION Hess Corporation 1 Hess Plaza Woodbridge, NJ 07095-0961 EMERGENCY TELEPHONE NUMBER (24 hrs): CHEMTREC (800)424-9300 COMPANY CONTACT (business hours): Corporate Safety (732)750-6000 MSDS (Environment, Health, Safety) Internet Website www.hess.com SYNONYMS: Hess Conventional (Oxygenated and Non-oxygenated) Gasoline; Reformulated Gasoline (RFG); Reformulated Gasoline Blendstock for Oxygenate Blending (RBOB); Unleaded Motor or Automotive Gasoline See Section 16 for abbreviations and acronyms. 2. COMPOSITION and INFORMATION ON INGREDIENTS * INGREDIENT NAME (CAS No.) CONCENTRATION PERCENT BY WEIGHT Gasoline (86290-81-5) 100 Benzene (71-43-2) 0.1 - 4.9 (0.1 - 1.3 reformulated gasoline) n-Butane (106-97-8) < 10 Ethyl Alcohol (Ethanol) (64-17-5) 0 - 10 Ethyl benzene (100-41-4) < 3 n-Hexane (110-54-3) 0.5 to 4 Methyl-tertiary butyl ether (MTBE) (1634-04-4) 0 to 15.0 Tertiary-amyl methyl ether (TAME) (994-05-8) 0 to 17.2 Toluene (108-88-3) 1 - 25 1,2,4- Trimethylbenzene (95-63-6) < 6 Xylene, mixed isomers (1330-20-7) 1 - 15 A complex blend of petroleum-derived normal and branched-chain alkane, cycloalkane, alkene, and aromatic hydrocarbons. May contain antioxidant and multifunctional additives. Non-oxygenated Conventional Gasoline and RBOB do not have oxygenates (Ethanol or MTBE and/or TAME). MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No. 9950 Revision Date: 09/25/2007 Page 2 of 9 Oxygenated Conventional and Reformulated Gasoline will have oxygenates for octane enhancement or as legally required. 3. HAZARDS IDENTIFICATION EYES Moderate irritant. Contact with liquid or vapor may cause irritation. SKIN Practically non-toxic if absorbed following acute (single) exposure. May cause skin irritation with prolonged or repeated contact. Liquid may be absorbed through the skin in toxic amounts if large areas of skin are exposed repeatedly. INGESTION The major health threat of ingestion occurs from the danger of aspiration (breathing) of liquid drops into the lungs, particularly from vomiting. Aspiration may result in chemical pneumonia (fluid in the lungs), severe lung damage, respiratory failure and even death. Ingestion may cause gastrointestinal disturbances, including irritation, nausea, vomiting and diarrhea, and central nervous system (brain) effects similar to alcohol intoxication. In severe cases, tremors, convulsions, loss of consciousness, coma, respiratory arrest, and death may occur. INHALATION Excessive exposure may cause irritations to the nose, throat, lungs and respiratory tract. Central nervous system (brain) effects may include headache, dizziness, loss of balance and coordination, unconsciousness, coma, respiratory failure, and death. WARNING: the burning of any hydrocarbon as a fuel in an area without adequate ventilation may result in hazardous levels of combustion products, including carbon monoxide, and inadequate oxygen levels, which may cause unconsciousness, suffocation, and death. CHRONIC EFFECTS and CARCINOGENICITY Contains benzene, a regulated human carcinogen. Benzene has the potential to cause anemia and other blood diseases, including leukemia, after repeated and prolonged exposure. Exposure to light hydrocarbons in the same boiling range as this product has been associated in animal studies with systemic toxicity. See also Section 11 - Toxicological Information. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Irritation from skin exposure may aggravate existing open wounds, skin disorders, and dermatitis (rash). Chronic respiratory disease, liver or kidney dysfunction, or pre-existing central nervous system disorders may be aggravated by exposure. 4. FIRST AID MEASURES EYES In case of contact with eyes, immediately flush with clean, low-pressure water for at least 15 min. Hold eyelids open to ensure adequate flushing. Seek medical attention. SKIN Remove contaminated clothing. Wash contaminated areas thoroughly with soap and water or waterless hand cleanser. Obtain medical attention if irritation or redness develops. INGESTION MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No. 9950 Revision Date: 09/25/2007 Page 3 of 9 DO NOT INDUCE VOMITING. Do not give liquids. Obtain immediate medical attention. If spontaneous vomiting occurs, lean victim forward to reduce the risk of aspiration. Small amounts of material which enter the mouth should be rinsed out until the taste is dissipated. INHALATION Remove person to fresh air. If person is not breathing, ensure an open airway and provide artificial respiration. If necessary, provide additional oxygen once breathing is restored if trained to do so. Seek medical attention immediately. 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES: FLASH POINT: -45 oF (-43oC) AUTOIGNITION TEMPERATURE: highly variable; > 530 oF (>280 oC) OSHA/NFPA FLAMMABILITY CLASS: 1A (flammable liquid) LOWER EXPLOSIVE LIMIT (%): 1.4% UPPER EXPLOSIVE LIMIT (%): 7.6% FIRE AND EXPLOSION HAZARDS Vapors may be ignited rapidly when exposed to heat, spark, open flame or other source of ignition. Flowing product may be ignited by self-generated static electricity. When mixed with air and exposed to an ignition source, flammable vapors can burn in the open or explode in confined spaces. Being heavier than air, vapors may travel long distances to an ignition source and flash back. Runoff to sewer may cause fire or explosion hazard. EXTINGUISHING MEDIA SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, CO2, water spray, fire fighting foam, or Halon. LARGE FIRES: Water spray, fog or fire fighting foam. Water may be ineffective for fighting the fire, but may be used to cool fire-exposed containers. During certain times of the year and/or in certain geographical locations, gasoline may contain MTBE and/or TAME. Firefighting foam suitable for polar solvents is recommended for fuel with greater than 10% oxygenate concentration - refer to NFPA 11 “Low Expansion Foam - 1994 Edition.” FIRE FIGHTING INSTRUCTIONS Small fires in the incipient (beginning) stage may typically be extinguished using handheld portable fire extinguishers and other fire fighting equipment. Firefighting activities that may result in potential exposure to high heat, smoke or toxic by-products of combustion should require NIOSH/MSHA- approved pressure-demand self-contained breathing apparatus with full facepiece and full protective clothing. Isolate area around container involved in fire. Cool tanks, shells, and containers exposed to fire and excessive heat with water. For massive fires the use of unmanned hose holders or monitor nozzles may be advantageous to further minimize personnel exposure. Major fires may require withdrawal, allowing the tank to burn. Large storage tank fires typically require specially trained personnel and equipment to extinguish the fire, often including the need for properly applied fire fighting foam. See Section 16 for the NFPA 704 Hazard Rating. MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No. 9950 Revision Date: 09/25/2007 Page 4 of 9 6. ACCIDENTAL RELEASE MEASURES ACTIVATE FACILITY SPILL CONTINGENCY or EMERGENCY PLAN. Evacuate nonessential personnel and remove or secure all ignition sources. Consider wind direction; stay upwind and uphill, if possible. Evaluate the direction of product travel, diking, sewers, etc. to confirm spill areas. Spills may infiltrate subsurface soil and groundwater; professional assistance may be necessary to determine the extent of subsurface impact. Carefully contain and stop the source of the spill, if safe to do so. Protect bodies of water by diking, absorbents, or absorbent boom, if possible. Do not flush down sewer or drainage systems, unless system is designed and permitted to handle such material. The use of fire fighting foam may be useful in certain situations to reduce vapors. The proper use of water spray may effectively disperse product vapors or the liquid itself, preventing contact with ignition sources or areas/equipment that require protection. Take up with sand or other oil absorbing materials. Carefully shovel, scoop or sweep up into a waste container for reclamation or disposal - caution, flammable vapors may accumulate in closed containers. Response and clean-up crews must be properly trained and must utilize proper protective equipment (see Section 8). 7. HANDLING and STORAGE HANDLING PRECAUTIONS ******USE ONLY AS A MOTOR FUEL****** ******DO NOT SIPHON BY MOUTH****** Handle as a flammable liquid. Keep away from heat, sparks, and open flame! Electrical equipment should be approved for classified area. Bond and ground containers during product transfer to reduce the possibility of static-initiated fire or explosion. Special slow load procedures for "switch loading" must be followed to avoid the static ignition hazard that can exist when higher flash point material (such as fuel oil) is loaded into tanks previously containing low flash point products (such as this product) - see API Publication 2003, "Protection Against Ignitions Arising Out Of Static, Lightning and Stray Currents. STORAGE PRECAUTIONS Keep away from flame, sparks, excessive temperatures and open flame. Use approved vented containers. Keep containers closed and clearly labeled. Empty product containers or vessels may contain explosive vapors. Do not pressurize, cut, heat, weld or expose such containers to sources of ignition. Store in a well-ventilated area. This storage area should comply with NFPA 30 "Flammable and Combustible Liquid Code". Avoid storage near incompatible materials. The cleaning of tanks previously containing this product should follow API Recommended Practice (RP) 2013 "Cleaning Mobile Tanks In Flammable and Combustible Liquid Service" and API RP 2015 "Cleaning Petroleum Storage Tanks". WORK/HYGIENIC PRACTICES Emergency eye wash capability should be available in the near proximity to operations presenting a potential splash exposure. Use good personal hygiene practices. Avoid repeated and/or prolonged skin exposure. Wash hands before eating, drinking, smoking, or using toilet facilities. Do not use as a cleaning solvent on the skin. Do not use solvents or harsh abrasive skin cleaners for washing this product from exposed skin areas. Waterless hand cleaners are effective. Promptly remove contaminated clothing and launder before reuse. Use care when laundering to prevent the formation of flammable vapors which could ignite via washer or dryer. Consider the need to discard contaminated leather shoes and gloves. MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No. 9950 Revision Date: 09/25/2007 Page 5 of 9 8. EXPOSURE CONTROLS and PERSONAL PROTECTION EXPOSURE LIMITS Component (CAS No.) Exposure Limits Source TWA (ppm) STEL (ppm) Note Gasoline (86290-81-5) ACGIH 300 500 A3 Benzene (71-43-2) OSHA ACGIH USCG 1 0.5 1 5 2.5 5 Carcinogen A1, skin n-Butane (106-97-8) ACGIH 1000 -- Aliphatic Hydrocarbon Gases Alkane (C1-C4) Ethyl Alcohol (ethanol) (64-17-5) OSHA ACGIH 1000 1000 -- -- A4 Ethyl benzene (100-41-4) OSHA ACGIH 100 100 -- 125 A3 n-Hexane (110-54-3) OSHA ACGIH 500 50 -- -- Skin Methyl-tertiary butyl ether [MTBE] (1634-04-4) ACGIH 50 A3 Tertiary-amyl methyl ether [TAME] (994-05-8) None established Toluene (108-88-3) OSHA ACGIH 200 20 -- Ceiling: 300 ppm; Peak: 500 ppm (10 min.) A4 1,2,4- Trimethylbenzene (95-63-6) ACGIH 25 -- Xylene, mixed isomers (1330-20-7) OSHA ACGIH 100 100 -- 150 A4 ENGINEERING CONTROLS Use adequate ventilation to keep vapor concentrations of this product below occupational exposure and flammability limits, particularly in confined spaces. EYE/FACE PROTECTION Safety glasses or goggles are recommended where there is a possibility of splashing or spraying. SKIN PROTECTION Gloves constructed of nitrile or neoprene are recommended. Chemical protective clothing such as that made of of E.I. DuPont Tychem ®, products or equivalent is recommended based on degree of exposure. Note: The resistance of specific material may vary from product to product as well as with degree of exposure. Consult manufacturer specifications for further information. RESPIRATORY PROTECTION A NIOSH-approved air-purifying respirator with organic vapor cartridges or canister may be permissible under certain circumstances where airborne concentrations are or may be expected to exceed exposure limits or for odor or irritation. Protection provided by air-purifying respirators is limited. Refer to OSHA 29 CFR 1910.134, NIOSH Respirator Decision Logic, and the manufacturer for additional guidance on respiratory protection selection and limitations. Use a positive pressure, air-supplied respirator if there is a potential for uncontrolled release, exposure levels are not known, in oxygen-deficient atmospheres, or any other circumstance where an air-purifying respirator may not provide adequate protection. 9. PHYSICAL and CHEMICAL PROPERTIES APPEARANCE A translucent, straw-colored or light yellow liquid MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No. 9950 Revision Date: 09/25/2007 Page 6 of 9 ODOR A strong, characteristic aromatic hydrocarbon odor. Oxygenated gasoline with MTBE and/or TAME may have a sweet, ether-like odor and is detectable at a lower concentration than non-oxygenated gasoline. ODOR THRESHOLD Odor Detection Odor Recognition Non-oxygenated gasoline: 0.5 - 0.6 ppm 0.8 - 1.1 ppm Gasoline with 15% MTBE: 0.2 - 0.3 ppm 0.4 - 0.7 ppm Gasoline with 15% TAME: 0.1 ppm 0.2 ppm BASIC PHYSICAL PROPERTIES BOILING RANGE: 85 to 437 oF (39 to 200 oC) VAPOR PRESSURE: 6.4 - 15 RVP @ 100 oF (38 oC) (275-475 mm Hg @ 68 oF (20 oC) VAPOR DENSITY (air = 1): AP 3 to 4 SPECIFIC GRAVITY (H2O = 1): 0.70 – 0.78 EVAPORATION RATE: 10-11 (n-butyl acetate = 1) PERCENT VOLATILES: 100 % SOLUBILITY (H2O): Non-oxygenated gasoline - negligible (< 0.1% @ 77 oF). Gasoline with 15% MTBE - slight (0.1 - 3% @ 77 oF); ethanol is readily soluble in water 10. STABILITY and REACTIVITY ) STABILITY: Stable. Hazardous polymerization will not occur. CONDITIONS TO AVOID Avoid high temperatures, open flames, sparks, welding, smoking and other ignition sources INCOMPATIBLE MATERIALS Keep away from strong oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke). Contact with nitric and sulfuric acids will form nitrocresols that can decompose violently. 11. TOXICOLOGICAL PROPERTIES ACUTE TOXICITY Acute Dermal LD50 (rabbits): > 5 ml/kg Acute Oral LD50 (rat): 18.75 ml/kg Primary dermal irritation (rabbits): slightly irritating Draize eye irritation (rabbits): non-irritating Guinea pig sensitization: negative CHRONIC EFFECTS AND CARCINOGENICITY Carcinogenicity: OSHA: NO IARC: YES - 2B NTP: NO ACGIH: YES (A3) IARC has determined that gasoline and gasoline exhaust are possibly carcinogenic in humans. Inhalation exposure to completely vaporized unleaded gasoline caused kidney cancers in male rats and liver tumors in female mice. The U.S. EPA has determined that the male kidney tumors are species-specific and are irrelevant for human health risk assessment. The significance of the tumors seen in female mice is not known. Exposure to light hydrocarbons in the same boiling range as this product has been associated in animal studies with effects to the central and peripheral nervous systems, liver, and kidneys. The significance of these animal models to predict similar human response to gasoline is uncertain. This product contains benzene. Human health studies indicate that prolonged and/or repeated overexposure to benzene may cause damage to the blood-forming system (particularly bone marrow), and serious blood disorders such as aplastic anemia and leukemia. Benzene is listed as a human carcinogen by the NTP, IARC, OSHA and ACGIH. MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No. 9950 Revision Date: 09/25/2007 Page 7 of 9 This product may contain methyl tertiary butyl ether (MTBE ): animal and human health effects studies indicate that MTBE may cause eye, skin, and respiratory tract irritation, central nervous system depression and neurotoxicity. MTBE is classified as an animal carcinogen (A3) by the ACGIH. 12. ECOLOGICAL INFORMATION Keep out of sewers, drainage areas and waterways. Report spills and releases, as applicable, under Federal and State regulations. If released, oxygenates such as ethers and alcohols will be expected to exhibit fairly high mobility in soil, and therefore may leach into groundwater. The API (www.api.org) provides a number of useful references addressing petroleum and oxygenate contamination of groundwater. 13. DISPOSAL CONSIDERATIONS Consult federal, state and local waste regulations to determine appropriate disposal options. 14. TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME: Gasoline DOT HAZARD CLASS and PACKING GROUP: 3, PG II DOT IDENTIFICATION NUMBER: UN 1203 DOT SHIPPING LABEL: FLAMMABLE LIQUID PLACARD: 15. REGULATORY INFORMATION U.S. FEDERAL, STATE, and LOCAL REGULATORY INFORMATION This product and its constituents listed herein are on the EPA TSCA Inventory. Any spill or uncontrolled release of this product, including any substantial threat of release, may be subject to federal, state and/or local reporting requirements. This product and/or its constituents may also be subject to other federal, state, or local regulations; consult those regulations applicable to your facility/operation. CLEAN WATER ACT (OIL SPILLS) Any spill or release of this product to "navigable waters" (essentially any surface water, including certain wetlands) or adjoining shorelines sufficient to cause a visible sheen or deposit of a sludge or emulsion must be reported immediately to the National Response Center (1-800-424-8802) as required by U.S. Federal Law. Also contact appropriate state and local regulatory agencies as required. CERCLA SECTION 103 and SARA SECTION 304 (RELEASE TO THE ENVIRONMENT) The CERCLA definition of hazardous substances contains a “petroleum exclusion” clause which exempts crude oil, refined, and unrefined petroleum products and any indigenous components of such. However, other federal reporting requirements (e.g., SARA Section 304 as well as the Clean Water Act if the spill occurs on navigable waters) may still apply. SARA SECTION 311/312 - HAZARD CLASSES ACUTE HEALTH CHRONIC HEALTH FIRE SUDDEN RELEASE OF PRESSURE REACTIVE X X X -- -- SARA SECTION 313 - SUPPLIER NOTIFICATION This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372: INGREDIENT NAME (CAS NUMBER) CONCENTRATION WT. PERCENT Benzene (71-43-2) 0.1 to 4.9 (0.1 to 1.3 for reformulated gasoline) Ethyl benzene (100-41-4) < 3 MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No. 9950 Revision Date: 09/25/2007 Page 8 of 9 n-Hexane (110-54-3) 0.5 to 4 Methyl-tertiary butyl ether (MTBE) (1634-04-4) 0 to 15.0 Toluene (108-88-3) 1 to 15 1,2,4- Trimethylbenzene (95-63-6) < 6 Xylene, mixed isomers (1330-20-7) 1 to 15 US EPA guidance documents (www.epa.gov/tri) for reporting Persistent Bioaccumulating Toxics (PBTs) indicate this product may contain the following deminimis levels of toxic chemicals subject to Section 313 reporting: INGREDIENT NAME (CAS NUMBER) CONCENTRATION - Parts per million (ppm) by weight Polycyclic aromatic compounds (PACs) Benzo (g,h,i) perylene (191-24-2) Lead (7439-92-1) 17 2.55 0.079 CALIFORNIA PROPOSITION 65 LIST OF CHEMICALS This product contains the following chemicals that are included on the Proposition 65 “List of Chemicals” required by the California Safe Drinking Water and Toxic Enforcement Act of 1986: INGREDIENT NAME (CAS NUMBER) Date Listed Benzene 2/27/1987 Ethyl benzene 6/11/2004 Toluene 1/1/1991 CANADIAN REGULATORY INFORMATION (WHMIS) Class B, Division 2 (Flammable Liquid) Class D, Division 2A (Very toxic by other means) and Class D, Division 2B (Toxic by other means) 16. OTHER INFORMATION NFPA® HAZARD RATING HEALTH: 1 Slight FIRE: 3 Serious REACTIVITY: 0 Minimal HMIS® HAZARD RATING HEALTH: 1 * Slight FIRE: 3 Serious PHYSICAL: 0 Minimal * CHRONIC SUPERSEDES MSDS DATED: 07/01/06 ABBREVIATIONS: AP = Approximately < = Less than > = Greater than N/A = Not Applicable N/D = Not Determined ppm = parts per million ACRONYMS: ACGIH American Conference of Governmental Industrial Hygienists AIHA American Industrial Hygiene Association ANSI American National Standards Institute (212)642-4900 API American Petroleum Institute (202)682-8000 CERCLA Comprehensive Emergency Response, Compensation, and Liability Act DOT U.S. Department of Transportation [General Info: (800)467-4922] EPA U.S. Environmental Protection Agency HMIS Hazardous Materials Information System MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No. 9950 Revision Date: 09/25/2007 Page 9 of 9 IARC International Agency For Research On Cancer MSHA Mine Safety and Health Administration NFPA National Fire Protection Association (617)770-3000 NIOSH National Institute of Occupational Safety and Health NOIC Notice of Intended Change (proposed change to ACGIH TLV) NTP National Toxicology Program OPA Oil Pollution Act of 1990 OSHA U.S. Occupational Safety & Health Administration PEL Permissible Exposure Limit (OSHA) RCRA Resource Conservation and Recovery Act REL Recommended Exposure Limit (NIOSH) SARA Superfund Amendments and Reauthorization Act of 1986 Title III SCBA Self-Contained Breathing Apparatus SPCC Spill Prevention, Control, and Countermeasures STEL Short-Term Exposure Limit (generally 15 minutes) TLV Threshold Limit Value (ACGIH) TSCA Toxic Substances Control Act TWA Time Weighted Average (8 hr.) WEEL Workplace Environmental Exposure Level (AIHA) WHMIS Workplace Hazardous Materials Information System (Canada) DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES Information presented herein has been compiled from sources considered to be dependable, and is accurate and reliable to the best of our knowledge and belief, but is not guaranteed to be so. Since conditions of use are beyond our control, we make no warranties, expressed or implied, except those that may be contained in our written contract of sale or acknowledgment. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material, even if reasonable safety procedures are followed. Furthermore, vendee assumes the risk in their use of the material. SAFETY DATA SHEET 1. Identification Product identifier Oatey PVC Heavy Duty Clear or Gray Cement Other means of identification SDS number 1102E Synonyms Part Numbers: Clear 30850, 30863, 30876(TV), 30882, 31008(TV), 31011, 31950, 31951, 31952, 31953 Gray 30349, 31093, 31094, 31095, 31105, 31118, 31978, 31979, 31980, 31981, 32050, 32051, 32052, 32210, 32211 Recommended use Joining PVC Pipes Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Company Name Oatey Co. Address 4700 West 160th St. Cleveland, OH 44135 Telephone 216-267-7100 E-mail info@oatey.com Transport Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887) Emergency First Aid 1-877-740-5015 Contact person MSDS Coordinator 2. Hazard(s) identification Category 2Flammable liquidsPhysical hazards Category 4Acute toxicity, oralHealth hazards Category 2Skin corrosion/irritation Category 2ASerious eye damage/eye irritation Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure Category 3 narcotic effectsSpecific target organ toxicity, single exposure Category 1Aspiration hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only outdoors or in a well-ventilated area. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. Response Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use appropriate media to extinguish. Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Oatey PVC Heavy Duty Clear or Gray Cement SDS US 920700 Version #: 02 Revision date:12-5-2017 Issue date:8-4-2014 1 / 10 Hazard(s) not otherwise classified (HNOC) Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected possible carcinogen. Supplemental information Not applicable. 3. Composition/information on ingredients Mixtures 109-99-9 30-60Furan, Tetrahydro- CAS number %Chemical name 67-64-1 10-302-Propanone 108-94-1 10-30Cyclohexanone 9002-86-2 10-30Polyvinyl chloride 78-93-3 5-10Methyl ethyl ketone 112945-52-5 1-5Colloidal silicon dioxide *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis. Most important symptoms/effects, acute and delayed Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. May cause redness and pain. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed. General information Take off all contaminated clothing immediately. IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. 5. Fire-fighting measures Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire fighting equipment/instructions In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or with age. SDS USOatey PVC Heavy Duty Clear or Gray Cement 920700 Version #: 02 Revision date: 12-5-2017 Issue date: 8-4-2014 2 / 10 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation of vapors or mists. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not taste or swallow. Avoid breathing mist or vapor. Avoid contact with skin. Avoid contact with eyes. Avoid prolonged exposure. Avoid contact with clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. When using, do not eat, drink or smoke. Wash hands thoroughly after handling. Conditions for safe storage, including any incompatibilities Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in original tightly closed container. Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Keep in an area equipped with sprinklers. 8. Exposure controls/personal protection Occupational exposure limits U.S. - OSHA ValueType FormComponents TWA 0.8 mg/m3 Unspecified.Colloidal silicon dioxide (CAS 112945-52-5) 20 mppcf Unspecified. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) ValueTypeComponents STEL 5 ppmPolyvinyl chloride (CAS 9002-86-2) TWA 1 ppm US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueType FormComponents PEL 2400 mg/m32-Propanone (CAS 67-64-1) 1000 ppm PEL 200 mg/m3Cyclohexanone (CAS 108-94-1) 50 ppm PEL 590 mg/m3Furan, Tetrahydro- (CAS 109-99-9) 200 ppm SDS USOatey PVC Heavy Duty Clear or Gray Cement 920700 Version #: 02 Revision date: 12-5-2017 Issue date: 8-4-2014 3 / 10 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueType FormComponents PEL 590 mg/m3Methyl ethyl ketone (CAS 78-93-3) 200 ppm PEL 5 mg/m3 Respirable fraction.Polyvinyl chloride (CAS 9002-86-2) 15 mg/m3 Total dust. US. OSHA Table Z-3 (29 CFR 1910.1000) ValueTypeComponents TWA 0.8 mg/m3Colloidal silicon dioxide (CAS 112945-52-5) 20 mppcf US. ACGIH Threshold Limit Values ValueType FormComponents STEL 750 ppm2-Propanone (CAS 67-64-1) TWA 500 ppm STEL 50 ppmCyclohexanone (CAS 108-94-1) TWA 20 ppm STEL 100 ppmFuran, Tetrahydro- (CAS 109-99-9) TWA 50 ppm STEL 300 ppmMethyl ethyl ketone (CAS 78-93-3) TWA 200 ppm TWA 1 mg/m3 Respirable fraction.Polyvinyl chloride (CAS 9002-86-2) U.S. - NIOSH ValueType FormComponents REL 6 mg/m3 Unspecified.Colloidal silicon dioxide (CAS 112945-52-5) US. NIOSH: Pocket Guide to Chemical Hazards ValueTypeComponents TWA 590 mg/m32-Propanone (CAS 67-64-1) 250 ppm TWA 6 mg/m3Colloidal silicon dioxide (CAS 112945-52-5) TWA 100 mg/m3Cyclohexanone (CAS 108-94-1) 25 ppm STEL 735 mg/m3Furan, Tetrahydro- (CAS 109-99-9) 250 ppm TWA 590 mg/m3 200 ppm STEL 885 mg/m3Methyl ethyl ketone (CAS 78-93-3) 300 ppm TWA 590 mg/m3 200 ppm SDS USOatey PVC Heavy Duty Clear or Gray Cement 920700 Version #: 02 Revision date: 12-5-2014 Issue date: 8-4-2014 4 / 10 Biological limit values ACGIH Biological Exposure Indices Value Sampling TimeDeterminant SpecimenComponents 50 mg/l Acetone Urine *2-Propanone (CAS 67-64-1) 80 mg/l 1,2-Cyclohexan ediol,with hydrolysis Urine *Cyclohexanone (CAS 108-94-1) 8 mg/l Cyclohexanol, with hydrolysis Urine * 2 mg/l Tetrahydrofura n Urine *Furan, Tetrahydro- (CAS 109-99-9) 2 mg/l MEK Urine *Methyl ethyl ketone (CAS 78-93-3) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Cyclohexanone (CAS 108-94-1)Skin designation applies. US - Tennessee OELs: Skin designation Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin. Furan, Tetrahydro- (CAS 109-99-9)Can be absorbed through the skin. US. NIOSH: Pocket Guide to Chemical Hazards Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin. Appropriate engineering controls Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear appropriate chemical resistant gloves. Other Wear appropriate chemical resistant clothing. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using, do not eat, drink or smoke. Wash hands after handling and before eating. 9. Physical and chemical properties Appearance Opaque.or Translucent. Physical state Liquid. Form Liquid. Color Gray or Clear. Odor Solvent. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 151 °F (66.11 °C) Flash point 14.0 - 23.0 °F (-10.0 - -5.0 °C) Evaporation rate 5.5 - 8 SDS USOatey PVC Heavy Duty Clear or Gray Cement 920700 Version #: 02 Revision date: 12-5-2017 Issue date: 8-4-2014 5 / 10 Flammability (solid, gas)Not available. Upper/lower flammability or explosive limits Flammability limit - lower (%) Not available. Flammability limit - upper (%) Not available. Explosive limit - lower (%)Not available. Explosive limit - upper (%)Not available. Vapor pressure 145 mm Hg @ 20 C Vapor density 2.5 Relative density 0.88 - 0.92 Solubility(ies) Solubility (water)Negligible Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Bulk density VOC (Weight %) 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Not available. Not available. Not available. 1200 - 2500 cP 7.5 lb/gal <510 g/l SQACMD 1168/M316A The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. No dangerous reaction known under conditions of normal use. Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics. No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Inhalation May be fatal if swallowed and enters airways. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. May cause irritation to the respiratory system. Skin contact Causes skin irritation. Eye contac Causes serious eye irritation. Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed. Symptoms related to the physical, chemical and toxicological characteristics Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Information on toxicological effects Acute toxicit May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation. Test ResultsComponentsSpecies Cyclohexanone (CAS 108-94-1) LD50 Rabbit Dermal Acute 948 mg/kg LC50 Rat Inhalation 8000 ppm, 4 hours SDS USOatey PVC Heavy Duty Clear or Gray Cement 920700 Version #: 02 Revision date: 12-5-2017 Issue date: 8-4-2014 6 / 10 Test ResultsComponents Species LD50 Rat Oral 1540 mg/kg * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Causes serious eye irritation. Respiratory or skin sensitization Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity Suspected of causing cancer. In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation lifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and female mice developed liver tumors while neither the female rats nor the male mice showed similar results. Because the carcinogenic mechanisms could not be identified clearly in either species for either tumor, the EPA determined that the male rat and female mouse findings are relevant to the assessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that these data in aggregate indicate that there is "suggestive evidence of carcinogenic potential" following exposure to THF by all routes of exposure. This product contains polyvinyl chloride (PVC) that is not a fabricated product, and is therefore, defined and regulated as a toxic and hazardous substance under 29 C.F.R. § 1910.1017 due to the presumed presence of residual vinyl chloride monomer. The concentrations of residual vinyl chloride calculated to be contained in this product are well below the threshold for classification in accordance with 29 C.F.R. § 1910.1200. IARC Monographs. Overall Evaluation of Carcinogenicity Colloidal silicon dioxide (CAS 112945-52-5) 3 Not classifiable as to carcinogenicity to humans. Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans. Polyvinyl chloride (CAS 9002-86-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Polyvinyl chloride (CAS 9002-86-2) Cancer Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Respiratory tract irritation. Narcotic effects. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard May be fatal if swallowed and enters airways. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components Test ResultsSpecies * Estimates for product may be based on additional component data not shown. Cyclohexanone (CAS 108-94-1) Aquatic LC50Fish 481 - 578 mg/l, 96 hoursFathead minnow (Pimephales promelas) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Propanone (CAS 67-64-1)-0.24 Cyclohexanone (CAS 108-94-1)0.81 Furan, Tetrahydro- (CAS 109-99-9)0.46 Methyl ethyl ketone (CAS 78-93-3)0.29 Mobility in soil No data available. SDS USOatey PVC Heavy Duty Clear or Gray Cement 920700 Version #: 02 Revision date: 12-5-2017 Issue date: 8-4-2014 7 / 10 Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN1133UN number AdhesivesUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIPacking group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user T11, TP1, TP8, TP27Special provisions 150Packaging exceptions 201Packaging non bulk 243Packaging bulk IATA UN1133UN number AdhesivesUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk IIPacking group No.Environmental hazards 3LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IMDG UN1133UN number ADHESIVESUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk IIPacking group No.Marine pollutant Environmental hazards F-E, S-DEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not available.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SDS USOatey PVC Heavy Duty Clear or Gray Cement 920700 Version #: 02 Revision date: 12-5-2017 Issue date: 8-4-2014 8 / 10 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Polyvinyl chloride (CAS 9002-86-2)Cancer Central nervous system Liver Blood Flammability CERCLA Hazardous Substance List (40 CFR 302.4) 2-Propanone (CAS 67-64-1)LISTED Cyclohexanone (CAS 108-94-1)LISTED Furan, Tetrahydro- (CAS 109-99-9)LISTED Methyl ethyl ketone (CAS 78-93-3)LISTED Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number 2-Propanone (CAS 67-64-1)6532 Methyl ethyl ketone (CAS 78-93-3)6714 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) 2-Propanone (CAS 67-64-1)35 %WV Methyl ethyl ketone (CAS 78-93-3)35 %WV DEA Exempt Chemical Mixtures Code Number 2-Propanone (CAS 67-64-1)6532 Methyl ethyl ketone (CAS 78-93-3)6714 US state regulations US. Massachusetts RTK - Substance List 2-Propanone (CAS 67-64-1) Colloidal silicon dioxide (CAS 112945-52-5) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. New Jersey Worker and Community Right-to-Know Act 2-Propanone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) SDS USOatey PVC Heavy Duty Clear or Gray Cement 920700 Version #: 02 Revision date: 12-5-2017 Issue date: 8-4-2014 9 / 10 Polyvinyl chloride (CAS 9002-86-2) US. Pennsylvania Worker and Community Right-to-Know Law 2-Propanone (CAS 67-64-1) Colloidal silicon dioxide (CAS 112945-52-5) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. Rhode Island RTK 2-Propanone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. This product contains trace amounts of chemicals known to the state of California to cause cancer. Under normal use conditions, exposure to these chemicals at levels above the State of California “No significant Risk Level” (NSRL) are unlikely. The use of proper personal protective equipment (PPE) and ventilation guidelines noted in Section 8 will minimize exposure levels to these chemicals. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australian Inventory of Chemical Substances (AICS) YesAustralia Domestic Substances List (DSL) YesCanada Non-Domestic Substances List (NDSL) NoCanada Inventory of Existing Chemical Substances in China (IECSC) YesChina European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoEurope Inventory of Existing and New Chemical Substances (ENCS) YesJapan Existing Chemicals List (ECL) YesKorea New Zealand Inventory YesNew Zealand Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesPhilippines *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico 16. Other information, including date of preparation or last revision Issue date 04-August-2014 Revision date 15-December-2014 Version #02 HMIS® ratings Health: 2 Flammability: 3 Physical hazard: 0 Disclaimer The information in the sheet was written based on the best knowledge and experience currently available. Oatey PVC Heavy Duty Clear or Gray Cement SDS US 920700 Version #: 02 Revision date: 12-5-2017 Issue date: 8-4-2014 10 / 10 SAFETY DATA SHEET 1. Identification Oatey Purple Primer- NSF Listed for PVC and CPVCProduct identifier Other means of identification 1402EProduct code Part Numbers: 30755(TV), 30756(TV), 30757(TV), 30758, 30759, 30927Synonyms Joining PVC PipesRecommended use None known.Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Company Name Oatey Co. Address 4700 West 160th St. Cleveland, OH 44135 Telephone 216-267-7100 E-mail info@oatey.com Transport Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887) Emergency First Aid 1-877-740-5015 Contact person MSDS Coordinator 2. Hazard(s) identification Category 2Flammable liquidsPhysical hazards Category 4Acute toxicity, oralHealth hazards Category 2Skin corrosion/irritation Category 2ASerious eye damage/eye irritation Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure Category 3 narcotic effectsSpecific target organ toxicity, single exposure Category 1Aspiration hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Response If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use appropriate media to extinguish. SDS USOatey Purple Primer- NSF Listed for PVC and CPVC 926733 Version #: 01 Revision date: 12-5-2017 Issue date: 5-27-2015 1 / 10 Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected possible carcinogen. Supplemental information Not applicable. 3. Composition/information on ingredients Mixtures 67-64-1 25-40Acetone CAS number %Chemical name 108-94-1 25-40Cyclohexanone 109-99-9 15-30Furan, Tetrahydro- 78-93-3 15-30Methyl ethyl ketone *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Eye contact Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis. Ingestion Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Skin irritation. May cause redness and pain. Most important symptoms/effects, acute and delayed Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed. Indication of immediate medical attention and special treatment needed Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. General information 5. Fire-fighting measures Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing media Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment and precautions for firefighters In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk.Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or with age. General fire hazards SDS USOatey Purple Primer- NSF Listed for PVC and CPVC 926733 Version #: 01 Revision date: 12-5-2017 Issue date: 5-27-2015 2 / 10 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid discharge into drains, water courses or onto the ground.Environmental precautions 7. Handling and storage Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof general and local exhaust ventilation. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Precautions for safe handling Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueTypeComponents PEL 2400 mg/m3Acetone (CAS 67-64-1) 1000 ppm PEL 200 mg/m3Cyclohexanone (CAS 108-94-1) 50 ppm PEL 590 mg/m3Furan, Tetrahydro- (CAS 109-99-9) 200 ppm PEL 590 mg/m3Methyl ethyl ketone (CAS 78-93-3) 200 ppm US. ACGIH Threshold Limit Values ValueTypeComponents STEL 750 ppmAcetone (CAS 67-64-1) TWA 500 ppm STEL 50 ppmCyclohexanone (CAS 108-94-1) TWA 20 ppm STEL 100 ppmFuran, Tetrahydro- (CAS 109-99-9) Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US 926733 Version #: 01 Revision date: 12-5-2017 Issue date: 5-27-2015 3 / 10 US. ACGIH Threshold Limit Values ValueTypeComponents TWA 50 ppm STEL 300 ppmMethyl ethyl ketone (CAS 78-93-3) TWA 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards ValueTypeComponents TWA 590 mg/m3Acetone (CAS 67-64-1) 250 ppm TWA 100 mg/m3Cyclohexanone (CAS 108-94-1) 25 ppm STEL 735 mg/m3Furan, Tetrahydro- (CAS 109-99-9) 250 ppm TWA 590 mg/m3 200 ppm STEL 885 mg/m3Methyl ethyl ketone (CAS 78-93-3) 300 ppm TWA 590 mg/m3 200 ppm Biological limit values ACGIH Biological Exposure Indices Value Sampling TimeDeterminant SpecimenComponents 50 mg/l Acetone Urine *Acetone (CAS 67-64-1) 80 mg/l 1,2-Cyclohexanediol,with hydrolysis Urine *Cyclohexanone (CAS 108-94-1) 8 mg/l Cyclohexanol, with hydrolysis Urine * 2 mg/l Tetrahydrofura n Urine *Furan, Tetrahydro- (CAS 109-99-9) 2 mg/l MEK Urine *Methyl ethyl ketone (CAS 78-93-3) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Cyclohexanone (CAS 108-94-1)Skin designation applies. US - Tennessee OELs: Skin designation Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin. Furan, Tetrahydro- (CAS 109-99-9)Can be absorbed through the skin. US. NIOSH: Pocket Guide to Chemical Hazards Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin. Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Appropriate engineering controls Individual protection measures, such as personal protective equipment Face shield is recommended. Wear safety glasses with side shields (or goggles).Eye/face protection SDS USOatey Purple Primer- NSF Listed for PVC and CPVC 926733 Version #: 01 Revision date: 12-5-2017 Issue date: 5-27-2015 4 / 10 Skin protection Wear appropriate chemical resistant gloves.Hand protection Wear appropriate chemical resistant clothing.Other If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Liquid.Physical state Translucent liquid.Form PurpleColor Solvent.Odor Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 151 °F (66.11 °C) Flash point 14.0 - 23.0 °F (-10.0 - -5.0 °C) Evaporation rate 5.5 - 8 Not available.Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) 1.8 Flammability limit - upper (%) 11.8 Explosive limit - lower (%)Not available. Explosive limit - upper (%)Not available. Vapor pressure 145 mm Hg @ 20 C Vapor density 2.5 Relative density 0.84 +/- 0.02 @20°C Solubility(ies) Solubility (water)Negligible Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Viscosity Other information Bulk density VOC (Weight %) 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Not available. Not available. 7 lb/gal < 550 g/l SQACMD Method 24 The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. No dangerous reaction known under conditions of normal use. Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics.Incompatible materials SDS USOatey Purple Primer- NSF Listed for PVC and CPVC 926733 Version #: 01 Revision date: 12-5-2017 Issue date: 5-27-2015 5 / 10 No hazardous decomposition products are known.Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritation to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. Eye contac Causes serious eye irritation. Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed. Harmful if swallowed. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Symptoms related to the physical, chemical and toxicological characteristics Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. Symptoms of overex osure ma be headache, dizziness, tiredness, nausea and vomitin . Information on toxicological effects Acute toxicit May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation. Test ResultsComponentsSpecies Acetone (CAS 67-64-1) LD50 Rabbit Dermal Acute 20 ml/kg LC50 Rat Inhalation 50 mg/l, 8 Hours LD50 Rat Oral 5800 mg/kg Cyclohexanone (CAS 108-94-1) LD50 Rabbit Dermal Acute 948 mg/kg LC50 Rat Inhalation 8000 ppm, 4 hours LD50 Rat Oral 1540 mg/kg * Estimates for product may be based on additional component data not shown. Causes skin irritation.Skin corrosion/irritation Causes serious eye irritation.Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not available. This product is not expected to cause skin sensitization.Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation lifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and female mice developed liver tumors while neither the female rats nor the male mice showed similar results. Because the carcinogenic mechanisms could not be identified clearly in either species for either tumor, the EPA determined that the male rat and female mouse findings are relevant to the assessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that these data in aggregate indicate that there is "suggestive evidence of carcinogenic potential" following exposure to THF by all routes of exposure. IARC Monographs. Overall Evaluation of Carcinogenicity Cyclohexanone (CAS 108-94-1)3 Not classifiable as to carcinogenicity to humans. SDS USOatey Purple Primer- NSF Listed for PVC and CPVC 926733 Version #: 01 Revision date: 12-5-2017 Issue date: 5-27-2015 6 / 10 OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. This product is not expected to cause reproductive or developmental effects.Reproductive toxicity Specific target organ toxicity - single exposure Narcotic effects. May cause drowsiness and dizziness. Respiratory tract irritation. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard May be fatal if swallowed and enters airways. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Ecotoxicity Components Test ResultsSpecies Acetone (CAS 67-64-1) Aquatic LC50Fish > 100 mg/l, 96 hoursFathead minnow (Pimephales promelas) * Estimates for product may be based on additional component data not shown. Cyclohexanone (CAS 108-94-1) Aquatic LC50Fish 481 - 578 mg/l, 96 hoursFathead minnow (Pimephales promelas) No data is available on the degradability of this product.Persistence and degradability No data available.Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Acetone (CAS 67-64-1)-0.24 Cyclohexanone (CAS 108-94-1)0.81 Furan, Tetrahydro- (CAS 109-99-9)0.46 Methyl ethyl ketone (CAS 78-93-3)0.29 No data available.Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations.Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Contaminated packaging 14. Transport information DOT UN1993UN number Flammable liquids, n.o.s. (Methyl ethyl ketone RQ = 26274 LBS, Acetone RQ = 13130 LBS)UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIPacking group SDS USOatey Purple Primer- NSF Listed for PVC and CPVC 926733 Version #: 01 Revision date: 12-5-2017 Issue date: 5-27-2015 7 / 10 Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IB2, T7, TP1, TP8, TP28Special provisions 150Packaging exceptions 202Packaging non bulk 242Packaging bulk IATA UN1993UN number Flammable liquid, n.o.s. (Methyl ethyl ketone, Acetone)UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk IIPacking group No.Environmental hazards 3HERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IMDG UN1993UN number FLAMMABLE LIQUID, N.O.S. (Methyl ethyl ketone, Acetone)UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk IIPacking group No.Marine pollutant Environmental hazards F-E, S-EEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not available.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1)LISTED Cyclohexanone (CAS 108-94-1)LISTED Furan, Tetrahydro- (CAS 109-99-9)LISTED Methyl ethyl ketone (CAS 78-93-3)LISTED Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. NoSARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Not regulated. SDS USOatey Purple Primer- NSF Listed for PVC and CPVC 926733 Version #: 01 Revision date: 12-5-2017 Issue date: 5-27-2015 8 / 10 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Methyl ethyl ketone (CAS 78-93-3) 6714 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 %WV Methyl ethyl ketone (CAS 78-93-3) 35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 Methyl ethyl ketone (CAS 78-93-3) 6714 US state regulations US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. Pennsylvania Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. Rhode Island RTK Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Domestic Substances List (DSL) YesCanada *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico 16. Other information, including date of preparation or last revision 27-May-2015Issue date -Revision date Version #01 Health: 2 Flammability: 3 Physical hazard: 0 HMIS® ratings SDS USOatey Purple Primer- NSF Listed for PVC and CPVC 926733 Version #: 01 Revision date: 12-5-2017 Issue date: 5-27-2015 9 / 10 NFPA ratings 02 3 The information in the sheet was written based on the best knowledge and experience currently available. Oatey Co. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. Disclaimer SDS USOatey Purple Primer- NSF Listed for PVC and CPVC 926733 Version #: 01 Revision date: 12-5-2017 Issue date: 5-27-2015 10 / 10 Industrial Enamel Pure White Not available. Liquid. US / Canada: (800) 424-9300 Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer :THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. B54W101 B54W101Product code : Product Information Telephone Number :US / Canada: (800) 524-5979 Mexico: Not Available Regulatory Information Telephone Number :US / Canada: (216) 566-2902 Mexico: Not Available Transportation Emergency Telephone Number :US / Canada: (800) 424-9300 Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 3 SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 ASPIRATION HAZARD - Category 1 Classification of the substance or mixture : Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 39.1% (oral), 39.1% (dermal), 39.1% (inhalation) OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 1/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US Section 2. Hazards identification Signal word :Danger Precautionary statements Prevention :Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or doctor. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified :DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue may spontaneously catch fire if improperly discarded. Immediately place rags, steel wool, other waste soaked with this product, and sanding residue in a sealed, water-filled, metal container. Dispose of in accordance with local fire regulations. Flammable liquid and vapor. May be fatal if swallowed and enters airways. May cause an allergic skin reaction. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure. (lungs) :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY. : Section 3. Composition/information on ingredients Other means of identification :Not available. Substance/mixture CAS number/other identifiers :Mixture Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 2/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US Section 3. Composition/information on ingredients Light Aliphatic Hydrocarbon ≥25 - ≤50 64742-47-8 Titanium Dioxide ≥10 - ≤25 13463-67-7 Talc ≤5 14807-96-6 Xylene, mixed isomers <1 1330-20-7 Hydrotreated Heavy Petroleum Naphtha <1 64742-48-9 Methyl Ethyl Ketoxime <1 96-29-7 Zirconium 2-Ethylhexanoate ≤1 22464-99-9 Med. Aliphatic Hydrocarbon Solvent ≤0.3 64742-88-7 Methyl Isobutyl Ketone ≤0.3 108-10-1 Ethylbenzene ≤0.3 100-41-4 Calcium 2-Ethylhexanoate ≤0.3 136-51-6 2-(2-Methoxyethoxy)-ethanol ≤0.3 111-77-3 Ingredient name CAS number% by weight Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Skin contact :May cause an allergic skin reaction. No known significant effects or critical hazards.:Eye contact Potential acute health effects Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 3/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments :No specific treatment. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact :No specific data. See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Specific hazards arising from the chemical Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Use dry chemical, CO₂, water spray (fog) or foam. Extinguishing media : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 4/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away : Precautions for safe handling Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 5/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. Light Aliphatic Hydrocarbon 64742-47-8 ACGIH TLV (United States, 1/2021). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 1/2021). TWA: 10 mg/m³ 8 hours. OSHA PEL (United States, 5/2018). TWA: 15 mg/m³ 8 hours. Form: Total dust Talc 14807-96-6 NIOSH REL (United States, 10/2020). TWA: 2 mg/m³ 10 hours. Form: Respirable fraction ACGIH TLV (United States, 1/2021). TWA: 2 mg/m³ 8 hours. Form: Respirable fraction Xylene, mixed isomers 1330-20-7 ACGIH TLV (United States, 1/2021). TWA: 100 ppm 8 hours. TWA: 434 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours. Hydrotreated Heavy Petroleum Naphtha 64742-48-9 None. Methyl Ethyl Ketoxime 96-29-7 OARS WEEL (United States, 1/2021). Skin sensitizer. TWA: 10 ppm 8 hours. Zirconium 2-Ethylhexanoate 22464-99-9 ACGIH TLV (United States, 1/2021). TWA: 5 mg/m³, (as Zr) 8 hours. STEL: 10 mg/m³, (as Zr) 15 minutes. NIOSH REL (United States, 10/2020). TWA: 5 mg/m³, (as Zr) 10 hours. STEL: 10 mg/m³, (as Zr) 15 minutes. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) CAS # Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 6/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection OSHA PEL (United States, 5/2018). TWA: 5 mg/m³, (as Zr) 8 hours. Med. Aliphatic Hydrocarbon Solvent 64742-88-7 OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 400 mg/m³ 8 hours. Methyl Isobutyl Ketone 108-10-1 ACGIH TLV (United States, 1/2021). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes. NIOSH REL (United States, 10/2020). TWA: 50 ppm 10 hours. TWA: 205 mg/m³ 10 hours. STEL: 75 ppm 15 minutes. STEL: 300 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 410 mg/m³ 8 hours. Ethylbenzene 100-41-4 ACGIH TLV (United States, 1/2021). TWA: 20 ppm 8 hours. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 435 mg/m³ 10 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours. Calcium 2-Ethylhexanoate 136-51-6 None. 2-(2-Methoxyethoxy)-ethanol 111-77-3 None. Petroleum refining, hydrotreated light distillate 64742-47-8 CA British Columbia Provincial (Canada, 6/2021). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapour) 8 hours. CA Alberta Provincial (Canada, 6/2018). Absorbed through skin. 8 hrs OEL: 200 mg/m³, (as total hydrocarbon vapour) 8 hours. CA Ontario Provincial (Canada, 6/2019). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapour) 8 hours. Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada, 6/2021). TWA: 10 mg/m³ 8 hours. Form: Total dust TWA: 3 mg/m³ 8 hours. Form: respirable fraction CA Quebec Provincial (Canada, 6/2021). TWAEV: 10 mg/m³ 8 hours. Form: Total dust. CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 10 mg/m³ 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 10 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). Ingredient name Exposure limits Occupational exposure limits (Canada) CAS # Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 7/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection STEL: 20 mg/m³ 15 minutes. TWA: 10 mg/m³ 8 hours. talc (none asbestiform)14807-96-6 CA British Columbia Provincial (Canada, 6/2021). TWA: 2 mg/m³ 8 hours. Form: Respirable CA Quebec Provincial (Canada, 6/2021). TWAEV: 2 mg/m³ 8 hours. Form: Respirable dust. CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 2 mg/m³ 8 hours. Form: Respirable particulate CA Ontario Provincial (Canada, 6/2019). TWA: 2 mg/m³ 8 hours. Form: Respirable particulate matter. TWA: 2 f/cc 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). TWA: 2 mg/m³ 8 hours. Form: respirable fraction Xylene 1330-20-7 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 100 ppm 8 hours. 15 min OEL: 651 mg/m³ 15 minutes. 15 min OEL: 150 ppm 15 minutes. 8 hrs OEL: 434 mg/m³ 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 100 ppm 8 hours. STEL: 150 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 100 ppm 8 hours. TWAEV: 434 mg/m³ 8 hours. STEV: 150 ppm 15 minutes. STEV: 651 mg/m³ 15 minutes. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. 2-Butoxyethanol 111-76-2 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 97 mg/m³ 8 hours. 8 hrs OEL: 20 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 20 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 20 ppm 8 hours. CA Quebec Provincial (Canada, 6/2021). TWAEV: 20 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 30 ppm 15 minutes. TWA: 20 ppm 8 hours. Methyl Ethyl Ketoxime 96-29-7 OARS WEEL (United States, 1/2021). Skin sensitizer. TWA: 10 ppm 8 hours. Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 8/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Zirconium 2-Ethylhexanoate 22464-99-9 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 5 mg/m³, (as Zr) 8 hours. 15 min OEL: 10 mg/m³, (as Zr) 15 minutes. CA British Columbia Provincial (Canada, 6/2021). TWA: 5 mg/m³, (as Zr) 8 hours. STEL: 10 mg/m³, (as Zr) 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 5 mg/m³, (as Zr) 8 hours. STEV: 10 mg/m³, (as Zr) 15 minutes. CA Ontario Provincial (Canada, 6/2019). STEL: 10 mg/m³, (as Zr) 15 minutes. TWA: 5 mg/m³, (as Zr) 8 hours. Methyl isobutyl ketone 108-10-1 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 205 mg/m³ 8 hours. 8 hrs OEL: 50 ppm 8 hours. 15 min OEL: 75 ppm 15 minutes. 15 min OEL: 307 mg/m³ 15 minutes. CA British Columbia Provincial (Canada, 6/2021). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 20 ppm 8 hours. STEV: 75 ppm 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 75 ppm 15 minutes. TWA: 50 ppm 8 hours. Ethylbenzene 100-41-4 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 100 ppm 8 hours. 8 hrs OEL: 434 mg/m³ 8 hours. 15 min OEL: 543 mg/m³ 15 minutes. 15 min OEL: 125 ppm 15 minutes. CA British Columbia Provincial (Canada, 6/2021). TWA: 20 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 20 ppm 8 hours. CA Quebec Provincial (Canada, 6/2021). TWAEV: 20 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 125 ppm 15 minutes. TWA: 100 ppm 8 hours. Occupational exposure limits (Mexico) Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 9/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Environmental exposure controls : Light Aliphatic Hydrocarbon 64742-47-8 ACGIH TLV (United States, 1/2021). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. Zirconium 2-Ethylhexanoate 22464-99-9 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 5 mg/m³, (as Zr) 8 hours. STEL: 10 mg/m³, (as Zr) 15 minutes. Methyl Isobutyl Ketone 108-10-1 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 50 ppm 8 hours. STEL: 75 ppm 15 minutes. Exposure limitsCAS # Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 10/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US Section 9. Physical and chemical properties Physical state Melting point/freezing point Vapor pressure Relative density Solubility Liquid. Not available. 1.05 5 [Air = 1] Not available. Not available.Odor pH Not available.Color Evaporation rate 0.13 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 38°C (100.4°F) [Pensky-Martens Closed Cup] Not applicable. Not applicable. Viscosity Kinematic (40°C (104°F)): <20.5 mm2/s (<20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance :148°C (298.4°F) :Not available. :Lower: 1% Upper: 6% Decomposition temperature :Not available. Heat of combustion :17.879 kJ/g Aerosol product Molecular weight :Not applicable. Boiling point, initial boiling point, and boiling range Flammability Lower and upper explosion limit/flammability limit Relative vapor density The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. 0.17 kPa (1.27 mm Hg) Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 11/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US Section 11. Toxicological information Acute toxicity Xylene, mixed isomers LC50 Inhalation Gas.Rat 6700 ppm 4 hours LD50 Oral Rat 4300 mg/kg - Hydrotreated Heavy Petroleum Naphtha LC50 Inhalation Vapor Rat 8500 mg/m³4 hours LD50 Oral Rat >6 g/kg - Methyl Ethyl Ketoxime LD50 Oral Rat 930 mg/kg - Zirconium 2-Ethylhexanoate LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat >5 g/kg - Methyl Isobutyl Ketone LD50 Oral Rat 2080 mg/kg - Ethylbenzene LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat 3500 mg/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity Not available. Mutagenicity Not available. Irritation/Corrosion Titanium Dioxide Skin - Mild irritant Human -72 hours 300 ug I - Talc Skin - Mild irritant Human -72 hours 300 ug I - Xylene, mixed isomers Eyes - Mild irritant Rabbit -87 mg - Eyes - Severe irritant Rabbit -24 hours 5 mg - Skin - Mild irritant Rat -8 hours 60 uL - Skin - Moderate irritant Rabbit -24 hours 500 mg - Skin - Moderate irritant Rabbit -100 %- Methyl Ethyl Ketoxime Eyes - Severe irritant Rabbit -100 uL - Methyl Isobutyl Ketone Eyes - Moderate irritant Rabbit -24 hours 100 uL - Eyes - Severe irritant Rabbit -40 mg - Skin - Mild irritant Rabbit -24 hours 500 mg - Ethylbenzene Eyes - Severe irritant Rabbit -500 mg - Skin - Mild irritant Rabbit -24 hours 15 mg - 2-(2-Methoxyethoxy)-ethanol Eyes - Mild irritant Rabbit -24 hours 500 mg - Eyes - Moderate irritant Rabbit -500 mg - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Information on toxicological effects Classification Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 12/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US Section 11. Toxicological information Teratogenicity Not available. Reproductive toxicity Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Light Aliphatic Hydrocarbon Category 3 -Respiratory tract irritation Category 3 Narcotic effects Xylene, mixed isomers Category 3 -Respiratory tract irritation Hydrotreated Heavy Petroleum Naphtha Category 3 -Respiratory tract irritation Category 3 Narcotic effects Methyl Ethyl Ketoxime Category 1 -upper respiratory tract Category 3 Narcotic effects Med. Aliphatic Hydrocarbon Solvent Category 3 -Respiratory tract irritation Category 3 Narcotic effects Methyl Isobutyl Ketone Category 3 -Respiratory tract irritation Category 3 Narcotic effects Ethylbenzene Category 3 -Respiratory tract irritation Category 3 Narcotic effects 2-(2-Methoxyethoxy)-ethanol Category 3 -Respiratory tract irritation Category 3 Narcotic effects Name Category Name Category Light Aliphatic Hydrocarbon Category 2 -- Talc Category 1 inhalation lungs Xylene, mixed isomers Category 2 -- Hydrotreated Heavy Petroleum Naphtha Category 2 -- Methyl Ethyl Ketoxime Category 2 -blood system Med. Aliphatic Hydrocarbon Solvent Category 1 -- Methyl Isobutyl Ketone Category 2 -- Ethylbenzene Category 2 -- 2-(2-Methoxyethoxy)-ethanol Category 2 -- Aspiration hazard Route of exposure Target organs Route of exposure Target organs Titanium Dioxide -2B - Talc -3 - Xylene, mixed isomers -3 - Methyl Isobutyl Ketone -2B - Ethylbenzene -2B - Product/ingredient name NTPIARCOSHA Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 13/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US Section 11. Toxicological information Name Result Light Aliphatic Hydrocarbon ASPIRATION HAZARD - Category 1 Xylene, mixed isomers ASPIRATION HAZARD - Category 1 Hydrotreated Heavy Petroleum Naphtha ASPIRATION HAZARD - Category 1 Med. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1 Ethylbenzene ASPIRATION HAZARD - Category 1 Information on the likely routes of exposure Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact :May cause an allergic skin reaction. No known significant effects or critical hazards.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact :No specific data. Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure :Not available. Potential acute health effects Potential immediate effects :Not available. Short term exposure Potential delayed effects :Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 14/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US Section 11. Toxicological information Not available. Causes damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : Suspected of damaging the unborn child.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :Suspected of damaging fertility. Numerical measures of toxicity Not available. Acute toxicity estimates Section 12. Ecological information Bioaccumulative potential Product/ingredient name Aquatic half-life Photolysis Biodegradability Xylene, mixed isomers --Readily Methyl Isobutyl Ketone --Readily Ethylbenzene --Readily Toxicity Light Aliphatic Hydrocarbon Acute LC50 2200 µg/l Fresh water Fish - Lepomis macrochirus 4 days Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours Xylene, mixed isomers Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours Methyl Ethyl Ketoxime Acute LC50 843000 µg/l Fresh water Fish - Pimephales promelas 96 hours Methyl Isobutyl Ketone Acute LC50 505000 µg/l Fresh water Fish - Pimephales promelas 96 hours Chronic NOEC 78 mg/l Fresh water Daphnia - Daphnia magna 21 days Chronic NOEC 168 mg/l Fresh water Fish - Pimephales promelas - Embryo 33 days Ethylbenzene Acute EC50 4900 µg/l Marine water Algae - Skeletonema costatum 72 hours Acute EC50 7700 µg/l Marine water Algae - Skeletonema costatum 96 hours Acute EC50 6.53 mg/l Marine water Crustaceans - Artemia sp. - Nauplii 48 hours Acute EC50 2.93 mg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours 2-(2-Methoxyethoxy)-ethanol Acute EC50 >930 ppm Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 7500000 µg/l Fresh water Fish - Lepomis macrochirus 96 hours Product/ingredient name SpeciesResult Exposure Persistence and degradability Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 15/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US Section 12. Ecological information LogPow BCF Potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name Xylene, mixed isomers -8.1 to 25.9 low Hydrotreated Heavy Petroleum Naphtha -10 to 2500 high Methyl Ethyl Ketoxime -2.5 to 5.8 low Zirconium 2-Ethylhexanoate -2.96 low Calcium 2-Ethylhexanoate -2.96 low Soil/water partition coefficient (KOC) :Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 14. Transport information PAINT 3 III PAINT. Marine pollutant (Light Aliphatic Hydrocarbon) 3 III UN1263 UN1263 DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No.Yes. TDG Classification UN1263 PAINT 3 III No. Mexico Classification UN1263 PAINT 3 III No. IATA UN1263 PAINT 3 III Yes. The environmentally hazardous substance mark is not required. Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 16/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US Section 14. Transport information This product may be re-classified as "Combustible Liquid," unless transported by vessel or aircraft. Non-bulk packages (less than or equal to 119 gal) of combustible liquids are not regulated as hazardous materials in package sizes less than the product reportable quantity. The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg. Emergency schedules F-E, S- E Additional information Special precautions for user Transport in bulk according to IMO instruments Not available. : Proper shipping name : Not available. : Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). - Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. The environmentally hazardous substance mark may appear if required by other transportation regulations. 128 ERG No. 128 128 ERG No.ERG No. Section 15. Regulatory information SARA 313 SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. International regulations International lists : Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 17/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US Section 15. Regulatory information Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. Section 16. Other information 7/19/2022 History Date of printing Date of issue/Date of revision Version Date of previous issue : : : : Indicates information that has changed from previously issued version. Key to abbreviations : 7/19/2022 6/11/2022 29.01 Hazardous Material Information System (U.S.A.) 3 2 0 *Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. FLAMMABLE LIQUIDS - Category 3 On basis of test data SKIN SENSITIZATION - Category 1 Calculation method CARCINOGENICITY - Category 2 Calculation method TOXIC TO REPRODUCTION - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 Calculation method ASPIRATION HAZARD - Category 1 Calculation method Procedure used to derive the classification Classification Justification Notice to reader ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 18/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of issue/Date of revision :7/19/2022 Date of previous issue :6/11/2022 Version :29.01 19/19 B54W101 Industrial Enamel Pure White SHW-85-NA-GHS-US PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White Not available. Liquid. US / Canada: (800) 424-9300 Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer :THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. B54W151 B54W151Product code : Product Information Telephone Number :US / Canada: (800) 524-5979 Mexico: Not Available Regulatory Information Telephone Number :US / Canada: (216) 566-2902 Mexico: Not Available Transportation Emergency Telephone Number :US / Canada: (800) 424-9300 Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 3 SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1 Classification of the substance or mixture : Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 24.3% (oral), 24.3% (dermal), 24.3% (inhalation) OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision :6/18/2022 Date of previous issue :4/14/2022 Version :24 1/18 B54W151 PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White SHW-85-NA-GHS-US Section 2. Hazards identification Signal word :Danger Precautionary statements Prevention :Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Contaminated work clothing must not be allowed out of the workplace. Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or doctor. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified :DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue may spontaneously catch fire if improperly discarded. Immediately place rags, steel wool, other waste soaked with this product, and sanding residue in a sealed, water-filled, metal container. Dispose of in accordance with local fire regulations. Flammable liquid and vapor. May be fatal if swallowed and enters airways. May cause an allergic skin reaction. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY. : Section 3. Composition/information on ingredients Light Aliphatic Hydrocarbon ≥10 - ≤25 64742-47-8 Titanium Dioxide ≥10 - ≤25 13463-67-7 Xylene, mixed isomers <1 1330-20-7 Hydrotreated Heavy Petroleum Naphtha <1 64742-48-9 Methyl Ethyl Ketoxime <1 96-29-7 Methyl Isobutyl Ketone <1 108-10-1 Calcium 2-Ethylhexanoate ≤0.3 136-51-6 2-(2-Methoxyethoxy)-ethanol ≤0.3 111-77-3 Ingredient name CAS number% by weight Other means of identification :Not available. Substance/mixture CAS number/other identifiers :Mixture Date of issue/Date of revision :6/18/2022 Date of previous issue :4/14/2022 Version :24 2/18 B54W151 PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White SHW-85-NA-GHS-US Section 3. Composition/information on ingredients Zirconium 2-Ethylhexanoate ≤0.3 22464-99-9 Ethylbenzene ≤0.3 100-41-4 Med. Aliphatic Hydrocarbon Solvent ≤0.3 64742-88-7 2-Ethyl-2-(hydroxymethyl)-1,3-propanediol ≤0.3 77-99-6 Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact :May cause an allergic skin reaction. No known significant effects or critical hazards.:Eye contact Over-exposure signs/symptoms Eye contact :No specific data. Potential acute health effects Date of issue/Date of revision :6/18/2022 Date of previous issue :4/14/2022 Version :24 3/18 B54W151 PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments :No specific treatment. Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Use dry chemical, CO₂, water spray (fog) or foam. Extinguishing media : : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision :6/18/2022 Date of previous issue :4/14/2022 Version :24 4/18 B54W151 PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White SHW-85-NA-GHS-US Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Date of issue/Date of revision :6/18/2022 Date of previous issue :4/14/2022 Version :24 5/18 B54W151 PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White SHW-85-NA-GHS-US Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Light Aliphatic Hydrocarbon 64742-47-8 ACGIH TLV (United States, 1/2021). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 1/2021). TWA: 10 mg/m³ 8 hours. OSHA PEL (United States, 5/2018). TWA: 15 mg/m³ 8 hours. Form: Total dust Xylene, mixed isomers 1330-20-7 ACGIH TLV (United States, 1/2021). TWA: 100 ppm 8 hours. TWA: 434 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours. Hydrotreated Heavy Petroleum Naphtha 64742-48-9 None. Methyl Ethyl Ketoxime 96-29-7 OARS WEEL (United States, 1/2021). Skin sensitizer. TWA: 10 ppm 8 hours. Methyl Isobutyl Ketone 108-10-1 ACGIH TLV (United States, 1/2021). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes. NIOSH REL (United States, 10/2020). TWA: 50 ppm 10 hours. TWA: 205 mg/m³ 10 hours. STEL: 75 ppm 15 minutes. STEL: 300 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 410 mg/m³ 8 hours. Calcium 2-Ethylhexanoate 136-51-6 None. 2-(2-Methoxyethoxy)-ethanol 111-77-3 None. Zirconium 2-Ethylhexanoate 22464-99-9 ACGIH TLV (United States, 1/2021). TWA: 5 mg/m³, (as Zr) 8 hours. STEL: 10 mg/m³, (as Zr) 15 minutes. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) CAS # Date of issue/Date of revision :6/18/2022 Date of previous issue :4/14/2022 Version :24 6/18 B54W151 PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection NIOSH REL (United States, 10/2020). TWA: 5 mg/m³, (as Zr) 10 hours. STEL: 10 mg/m³, (as Zr) 15 minutes. OSHA PEL (United States, 5/2018). TWA: 5 mg/m³, (as Zr) 8 hours. Ethylbenzene 100-41-4 ACGIH TLV (United States, 1/2021). TWA: 20 ppm 8 hours. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 435 mg/m³ 10 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours. Med. Aliphatic Hydrocarbon Solvent 64742-88-7 OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 400 mg/m³ 8 hours. 2-Ethyl-2-(hydroxymethyl)-1,3-propanediol 77-99-6 None. Petroleum refining, hydrotreated light distillate 64742-47-8 CA British Columbia Provincial (Canada, 6/2021). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapour) 8 hours. CA Alberta Provincial (Canada, 6/2018). Absorbed through skin. 8 hrs OEL: 200 mg/m³, (as total hydrocarbon vapour) 8 hours. CA Ontario Provincial (Canada, 6/2019). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapour) 8 hours. Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada, 6/2021). TWA: 10 mg/m³ 8 hours. Form: Total dust TWA: 3 mg/m³ 8 hours. Form: respirable fraction CA Quebec Provincial (Canada, 6/2021). TWAEV: 10 mg/m³ 8 hours. Form: Total dust. CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 10 mg/m³ 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 10 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 20 mg/m³ 15 minutes. TWA: 10 mg/m³ 8 hours. Xylene 1330-20-7 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 100 ppm 8 hours. 15 min OEL: 651 mg/m³ 15 minutes. 15 min OEL: 150 ppm 15 minutes. 8 hrs OEL: 434 mg/m³ 8 hours. CA British Columbia Provincial (Canada, 6/2021). Ingredient name Exposure limits Occupational exposure limits (Canada) CAS # Date of issue/Date of revision :6/18/2022 Date of previous issue :4/14/2022 Version :24 7/18 B54W151 PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection TWA: 100 ppm 8 hours. STEL: 150 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 100 ppm 8 hours. TWAEV: 434 mg/m³ 8 hours. STEV: 150 ppm 15 minutes. STEV: 651 mg/m³ 15 minutes. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. Methyl Ethyl Ketoxime 96-29-7 OARS WEEL (United States, 1/2021). Skin sensitizer. TWA: 10 ppm 8 hours. Methyl isobutyl ketone 108-10-1 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 205 mg/m³ 8 hours. 8 hrs OEL: 50 ppm 8 hours. 15 min OEL: 75 ppm 15 minutes. 15 min OEL: 307 mg/m³ 15 minutes. CA British Columbia Provincial (Canada, 6/2021). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 20 ppm 8 hours. STEV: 75 ppm 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 75 ppm 15 minutes. TWA: 50 ppm 8 hours. Zirconium 2-Ethylhexanoate 22464-99-9 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 5 mg/m³, (as Zr) 8 hours. 15 min OEL: 10 mg/m³, (as Zr) 15 minutes. CA British Columbia Provincial (Canada, 6/2021). TWA: 5 mg/m³, (as Zr) 8 hours. STEL: 10 mg/m³, (as Zr) 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 5 mg/m³, (as Zr) 8 hours. STEV: 10 mg/m³, (as Zr) 15 minutes. CA Ontario Provincial (Canada, 6/2019). STEL: 10 mg/m³, (as Zr) 15 minutes. TWA: 5 mg/m³, (as Zr) 8 hours. Ethylbenzene 100-41-4 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 100 ppm 8 hours. 8 hrs OEL: 434 mg/m³ 8 hours. 15 min OEL: 543 mg/m³ 15 minutes. 15 min OEL: 125 ppm 15 minutes. CA British Columbia Provincial (Canada, 6/2021). TWA: 20 ppm 8 hours. Date of issue/Date of revision :6/18/2022 Date of previous issue :4/14/2022 Version :24 8/18 B54W151 PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection : : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection CA Ontario Provincial (Canada, 6/2019). TWA: 20 ppm 8 hours. CA Quebec Provincial (Canada, 6/2021). TWAEV: 20 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 125 ppm 15 minutes. TWA: 100 ppm 8 hours. Environmental exposure controls : Light Aliphatic Hydrocarbon 64742-47-8 ACGIH TLV (United States, 1/2021). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. Methyl Isobutyl Ketone 108-10-1 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 50 ppm 8 hours. STEL: 75 ppm 15 minutes. Zirconium 2-Ethylhexanoate 22464-99-9 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 5 mg/m³, (as Zr) 8 hours. STEL: 10 mg/m³, (as Zr) 15 minutes. Exposure limits Occupational exposure limits (Mexico) CAS # Date of issue/Date of revision :6/18/2022 Date of previous issue :4/14/2022 Version :24 9/18 B54W151 PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Respiratory protection : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point/freezing point Vapor pressure Relative density Solubility Liquid. Not available. 1.18 5 [Air = 1] Not available. Not available.Odor pH Not available.Color Evaporation rate 0.13 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 39°C (102.2°F) [Pensky-Martens Closed Cup] Not applicable. Not applicable. Viscosity Kinematic (40°C (104°F)): <20.5 mm2/s (<20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance :148°C (298.4°F) :Not available. :Lower: 1% Upper: 6% Decomposition temperature :Not available. Heat of combustion :12.112 kJ/g Aerosol product Molecular weight :Not applicable. Boiling point, initial boiling point, and boiling range Flammability Lower and upper explosion limit/flammability limit Relative vapor density The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. 0.17 kPa (1.27 mm Hg) Date of issue/Date of revision :6/18/2022 Date of previous issue :4/14/2022 Version :24 10/18 B54W151 PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White SHW-85-NA-GHS-US Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Xylene, mixed isomers LC50 Inhalation Gas.Rat 6700 ppm 4 hours LD50 Oral Rat 4300 mg/kg - Hydrotreated Heavy Petroleum Naphtha LC50 Inhalation Vapor Rat 8500 mg/m³4 hours LD50 Oral Rat >6 g/kg - Methyl Ethyl Ketoxime LD50 Oral Rat 930 mg/kg - Methyl Isobutyl Ketone LD50 Oral Rat 2080 mg/kg - Zirconium 2-Ethylhexanoate LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat >5 g/kg - Ethylbenzene LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat 3500 mg/kg - 2-Ethyl-2-(hydroxymethyl) -1,3-propanediol LD50 Oral Rat 14000 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Titanium Dioxide Skin - Mild irritant Human -72 hours 300 ug I - Xylene, mixed isomers Eyes - Mild irritant Rabbit -87 mg - Eyes - Severe irritant Rabbit -24 hours 5 mg - Skin - Mild irritant Rat -8 hours 60 uL - Skin - Moderate irritant Rabbit -24 hours 500 mg - Skin - Moderate irritant Rabbit -100 %- Methyl Ethyl Ketoxime Eyes - Severe irritant Rabbit -100 uL - Methyl Isobutyl Ketone Eyes - Moderate irritant Rabbit -24 hours 100 uL - Eyes - Severe irritant Rabbit -40 mg - Skin - Mild irritant Rabbit -24 hours 500 mg - 2-(2-Methoxyethoxy)-ethanol Eyes - Mild irritant Rabbit -24 hours 500 - Product/ingredient name Result Score Exposure ObservationSpecies Information on toxicological effects Date of issue/Date of revision :6/18/2022 Date of previous issue :4/14/2022 Version :24 11/18 B54W151 PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White SHW-85-NA-GHS-US Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. mg Eyes - Moderate irritant Rabbit -500 mg - Ethylbenzene Eyes - Severe irritant Rabbit -500 mg - Skin - Mild irritant Rabbit -24 hours 15 mg - Sensitization Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Light Aliphatic Hydrocarbon Category 3 -Respiratory tract irritation Category 3 Narcotic effects Xylene, mixed isomers Category 3 -Respiratory tract irritation Hydrotreated Heavy Petroleum Naphtha Category 3 -Respiratory tract irritation Category 3 Narcotic effects Methyl Ethyl Ketoxime Category 1 -upper respiratory tract Category 3 Narcotic effects Methyl Isobutyl Ketone Category 3 -Respiratory tract irritation Category 3 Narcotic effects 2-(2-Methoxyethoxy)-ethanol Category 3 -Respiratory tract irritation Category 3 Narcotic effects Ethylbenzene Category 3 -Respiratory tract irritation Category 3 Narcotic effects Med. Aliphatic Hydrocarbon Solvent Category 3 -Respiratory tract irritation Category 3 Narcotic effects Name Category Route of exposure Target organs Classification Titanium Dioxide -2B - Xylene, mixed isomers -3 - Methyl Isobutyl Ketone -2B - Ethylbenzene -2B - Product/ingredient name NTPIARCOSHA Date of issue/Date of revision :6/18/2022 Date of previous issue :4/14/2022 Version :24 12/18 B54W151 PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White SHW-85-NA-GHS-US Section 11. Toxicological information Name Category Light Aliphatic Hydrocarbon Category 2 -- Xylene, mixed isomers Category 2 -- Hydrotreated Heavy Petroleum Naphtha Category 2 -- Methyl Ethyl Ketoxime Category 2 -blood system Methyl Isobutyl Ketone Category 2 -- 2-(2-Methoxyethoxy)-ethanol Category 2 -- Ethylbenzene Category 2 -- Med. Aliphatic Hydrocarbon Solvent Category 1 -- Aspiration hazard Name Result Light Aliphatic Hydrocarbon ASPIRATION HAZARD - Category 1 Xylene, mixed isomers ASPIRATION HAZARD - Category 1 Hydrotreated Heavy Petroleum Naphtha ASPIRATION HAZARD - Category 1 Ethylbenzene ASPIRATION HAZARD - Category 1 Med. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1 Route of exposure Target organs Information on the likely routes of exposure Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact :May cause an allergic skin reaction. No known significant effects or critical hazards.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact :No specific data. :Not available. Potential acute health effects Date of issue/Date of revision :6/18/2022 Date of previous issue :4/14/2022 Version :24 13/18 B54W151 PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White SHW-85-NA-GHS-US Section 11. Toxicological information Not available. May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : Suspected of damaging the unborn child.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :Suspected of damaging fertility. Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Not available. Acute toxicity estimates Potential immediate effects :Not available. Short term exposure Potential delayed effects :Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Section 12. Ecological information Toxicity Light Aliphatic Hydrocarbon Acute LC50 2200 µg/l Fresh water Fish - Lepomis macrochirus 4 days Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours Xylene, mixed isomers Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours Methyl Ethyl Ketoxime Acute LC50 843000 µg/l Fresh water Fish - Pimephales promelas 96 hours Methyl Isobutyl Ketone Acute LC50 505000 µg/l Fresh water Fish - Pimephales promelas 96 hours Chronic NOEC 78 mg/l Fresh water Daphnia - Daphnia magna 21 days Chronic NOEC 168 mg/l Fresh water Fish - Pimephales promelas - Embryo 33 days 2-(2-Methoxyethoxy)-ethanol Acute EC50 >930 ppm Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 7500000 µg/l Fresh water Fish - Lepomis macrochirus 96 hours Ethylbenzene Acute EC50 4900 µg/l Marine water Algae - Skeletonema costatum 72 hours Acute EC50 7700 µg/l Marine water Algae - Skeletonema costatum 96 hours Acute EC50 6.53 mg/l Marine water Crustaceans - Artemia sp. - Nauplii 48 hours Acute EC50 2.93 mg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours 2-Ethyl-2-(hydroxymethyl) -1,3-propanediol Acute EC50 13000000 µg/l Fresh water Daphnia - Daphnia magna 48 hours Product/ingredient name SpeciesResult Exposure Date of issue/Date of revision :6/18/2022 Date of previous issue :4/14/2022 Version :24 14/18 B54W151 PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White SHW-85-NA-GHS-US Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name Xylene, mixed isomers -8.1 to 25.9 low Hydrotreated Heavy Petroleum Naphtha -10 to 2500 high Methyl Ethyl Ketoxime -2.5 to 5.8 low Calcium 2-Ethylhexanoate -2.96 low Zirconium 2-Ethylhexanoate -2.96 low 2-Ethyl-2-(hydroxymethyl) -1,3-propanediol -<1 low Product/ingredient name Aquatic half-life Photolysis Biodegradability Xylene, mixed isomers --Readily Methyl Isobutyl Ketone --Readily Ethylbenzene --Readily Acute LC50 14400000 µg/l Marine water Fish - Cyprinodon variegatus 96 hours Persistence and degradability Soil/water partition coefficient (KOC) :Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 14. Transport information PAINT PAINT UN1263 UN1263 DOT Classification IMDG UN number UN proper shipping name TDG Classification UN1263 PAINT Mexico Classification UN1263 PAINT IATA UN1263 PAINT Date of issue/Date of revision :6/18/2022 Date of previous issue :4/14/2022 Version :24 15/18 B54W151 PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White SHW-85-NA-GHS-US Section 14. Transport information 3 III 3 III This product may be re-classified as "Combustible Liquid," unless transported by vessel or aircraft. Non-bulk packages (less than or equal to 119 gal) of combustible liquids are not regulated as hazardous materials in package sizes less than the product reportable quantity. Emergency schedules F-E, S- E Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to IMO instruments No.No. Not available. : Proper shipping name : Not available. : 3 III No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). 3 III No. - Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. 3 III No. - 128 ERG No. 128 128 ERG No.ERG No. Date of issue/Date of revision :6/18/2022 Date of previous issue :4/14/2022 Version :24 16/18 B54W151 PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White SHW-85-NA-GHS-US Section 15. Regulatory information SARA 313 TSCA 5(a)2 proposed significant new use rules: 5-Chloro-2-methylisothiazolinone; 2-Methyl-4-isothiazolin-3-one SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International regulations International lists : Section 16. Other information 6/18/2022 History Date of printing Date of issue/Date of revision Date of previous issue : : : 6/18/2022 4/14/2022 Hazardous Material Information System (U.S.A.) 3 2 0 *Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. FLAMMABLE LIQUIDS - Category 3 On basis of test data SKIN SENSITIZATION - Category 1 Calculation method CARCINOGENICITY - Category 2 Calculation method TOXIC TO REPRODUCTION - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method ASPIRATION HAZARD - Category 1 Calculation method Procedure used to derive the classification Classification Justification Date of issue/Date of revision :6/18/2022 Date of previous issue :4/14/2022 Version :24 17/18 B54W151 PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White SHW-85-NA-GHS-US Section 16. Other information Version It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. : Indicates information that has changed from previously issued version. Key to abbreviations : 24 Notice to reader ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision :6/18/2022 Date of previous issue :4/14/2022 Version :24 18/18 B54W151 PRO INDUSTRIAL™ Urethane Alkyd Enamel Extra White SHW-85-NA-GHS-US Pecora 895 NST Page 1 of 9 November 9, 2017 SAFETY DATA SHEET 1. PRODUCT IDENTIFICATION IDENTIFICATION of the SUBSTANCE or PREPARATION TRADE NAME (AS LABELED): Pecora 895 NST Non-Staining Technology™ PRODUCT DESCRIPTION: Structural Silicone Glazing &Weatherproofing Sealant CHEMICAL NAME/CLASS: Silicone OTHER MEANS OF IDENTIFICATION/SYNONYMS 895 NST RELEVANT USE: Structural Silicone Glazing &Weatherproofing Sealant/Caulking Compound USES ADVISED AGAINST: Other Than Relevant Use COMPANY/UNDERTAKING IDENTIFICATION: SUPPLIER/MANUFACTURER'S NAME: Pecora Corporation ADDRESS: 165 Wambold Road, Harleysville, PA 19438 EMERGENCY PHONE: 800-424-9300 (CHEMTREC, 24-hours) BUSINESS PHONE: 215-723-6051 (Mon–Fri, 8 AM–5 PM ET) PREPARATION DATE: July 13, 2007 REVISION DATE: November 9, 2017 This product is sold for commercial use. This SDS has been developed to address safety concerns of those individuals working with bulk quantities of this material, as well as those of potential users of this product in industrial/occupational settings. ALL United States Occupational Safety and Health Administration Standard (29 CFR 1910.1200), U.S. State equivalent Standards, Canadian WHMIS 2015 and the Global Harmonization required information is included in appropriate sections based on the Global Harmonization Standard format. This product has been classified in accordance with the hazard criteria of the countries listed above and the SDS contains all the information required by the Canadian WHMIS 2015 [HPR-GHS] , the Global Harmonization Standard and OSHA 1910.120. 2. HAZARD IDENTIFICATION GLOBAL HARMONIZATION LABELING AND CLASSIFICATION: Classified in accordance with Global Harmonization Standard under U.S. OSHA Hazard Communication Standard, Canadian WHMIS HPR-GHS 2015 Classification: Reproductive Toxicity Cat. 2, Acute Oral Toxicity Cat. 5, Acute Dermal Toxicity Cat. 5, Eye Irritation Cat. 2A, Skin Irritation Cat. 2, Skin Sensitization Cat. 1B, STOT (Blood Effects) RE Cat. 2, Aquatic Chronic Toxicity Cat. 3 Signal Word: Warning Hazard Statement Codes: H361f, H303 + H313, H319, H315, H317, H373, H413 Precautionary Statement Codes: P201, P202, P260, P264, P273, P280, P308 + P313, P305 + P351 + P338, P337 + P313, P302 + P352, P321, P333 + P313, P362 + P364, P405, P501 Hazard Symbols/Pictogram: GHS07, GHS08 EMERGENCY OVERVIEW: Physical Description: This product is a smooth paste with a slightly medicinal odor and comes in various colors, including Black, Tru-White, Aluminum Stone, Translucent, Bronze and Clear. Health Hazards: WARNING! Contains trace compound that may cause adverse effects on fertility (based on animal data). May cause eye, skin, and respiratory tract irritation, especially if exposure is prolonged. May be harmful if ingested or in contact with skin. May cause skin sensitization in susceptible individuals. Contains compound that may cause adverse effects to the blood system with repeated exposure. Contains a trace compound (Crystalline Silica), a known human carcinogen by inhalation of particles. Contains a trace compound (Crystalline Silica), a known human carcinogen by inhalation of particles. Contains a trace compound (Crystalline Silica), a known human carcinogen by inhalation of particles; however, due to the form of this product, this hazard is expected to be negligible. Flammability Hazard: This product is combustible and can ignite if exposed to high temperature for a prolonged period or to direct flame. Reactivity Hazard: This product is not reactive. Environmental Hazard: This product has not been tested for environmental impact. This product contains compounds that can cause chronic aquatic toxicity. HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS®) Health 2* See Section 16 for definitions of ratings 0 = Minimal 3 = Serious 1 = Slight 4 = Severe 2 = Moderate * = Chronic Flammability 1 Physical Hazard 0 HMIS® is a registered trademark of the National Paint and Coatings Association. CANADIAN WHMIS (HPR-GHS) 2015 CLASSIFICATION AND SYMBOLS: See Section 16 for in Classification and Symbols under HPR-GHS 2015. U.S. OSHA REGULATORY STATUS: This product has a classification under the Global Harmonization Standard, as applied under OSHA regulations, as given earlier in this Section. See Section 16 for full classification details. Pecora 895 NST Page 2 of 9 November 9, 2017 3. COMPOSITION and INFORMATION ON INGREDIENTS Chemical Name CAS # W/W% LABEL ELEMENTS GHS Classification under U.S. OSHA Hazard Communication Standard & Canadian WHMIS (HPR-GHS) 2015 Hazard Statement Codes Proprietary Polydimethyl Siloxane 35.0-80.0 NOTIFIED CLASSIFICATION Classification: Eye Irritation Cat. 2A Hazard Statement Codes: H319 Calcium Carbonate (Natural) Calcium Carbonate (synthetic) 1317-65-3 471-34-0 0.0-70.0 SELF CLASSIFICATION Classification: Not Applicable Organic Methyl Silane 0.0-8.0 NOTIFIED CLASSIFICATION Classification: Skin Sensitization Cat. 1B, Eye Irritation Cat. 2A, STOT (Blood Effects) RE Cat. 2 Hazard Statement Codes: H317, H319, H373 Proprietary Mineral Spirits (contains less than 0.1% benzene) 0.0–6.0 HARMONISED CLASSIFICATION - ANNEX VI OF REGULATION (EC) NO 1272/2008 (CLP REGULATION) Classification: Aspiration Hazard Cat. 1 Hazard Statement Codes: H304 ADDITIONAL SELF-CLASSIFICATION Classification: Flammable Liquid Cat. 3, Skin Irritation Cat. 2, STOT (Central Nervous System) SE Cat. 3, Aquatic Chronic Cat. 2 Hazard Statement Codes: H226, H315, H336, H411 Proprietary Cyclosiloxane 0.0-4.0 HARMONISED CLASSIFICATION AND LABELLING (CLP00) Classification: Reproductive Toxicity Cat. 2, Aquatic Chronic Toxicity Cat. 4 Hazard Statement Codes: H361f, H413 ADDITIONAL SELF-CLASSIFICATION Classification: Flammable Liquid Cat. 3, Acute Oral Toxicity Cat. 4, Acute Dermal Toxicity Cat. 4 Hazard Statement Codes: H226, H302 + H312 Proprietary Phenylated Ketoxomio Silane 0.0-3.0 NOTIFIED CLASSIFICATION Classification: Skin Sensitization Cat. 1B Hazard Statement Codes: H317 ADDITIONAL MFG CLASSIFICATION Classification: STOT RE Cat. 2, Aquatic Chronic Toxicity Cat. 3 Hazard Statement Codes: H373, H412 Crystalline Silica Quartz 14808-60-7 0.0-0.1 SELF CLASSIFICATION Classification: Carcinogenic Cat. 1B Hazard Statement Codes: H350i The following are pigments that can be in the product, depending on coloration: Carbon Black 13463-67-7 0.0-5.0 SELF-CLASSIFICATION Classification: Carcinogenic Cat. 2 Hazard Statement Codes: H351i Other trace components. Each of the other components is present in less than 1 percent concentration (0.1% concentration for potential carcinogens, reproductive toxins, respiratory tract sensitizers, and mutagens). Balance Classification: Not Applicable The specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST-AID MEASURES PROTECTION OF FIRST AID RESPONDERS: Rescuers should not attempt to retrieve victims of exposure to this product without adequate personal protective equipment. Rescuers should be taken for medical attention, if necessary. DESCRIPTION OF FIRST AID MEASURES: Remove victim(s) to fresh air, as quickly as possible. Only trained personnel should administer supplemental oxygen and/or cardio-pulmonary resuscitation, if necessary. Remove and isolate contaminated clothing and shoes. Seek medical attention if adverse effects occur after decontamination efforts or if contaminated individual is not breathing or unconscious. Take copy of label and SDS to physician or other health professional with victim(s). Inhalation: If aerosols from the product are inhaled, contaminated individual to fresh air. If necessary, use artificial respiration to support vital functions. Seek medical attention if adverse effects occur/continue after removal to fresh air. Skin Exposure: If the product contaminates the skin, immediately begin decontamination with running water. Minimum flushing is for 20 minutes. Do not interrupt flushing. Remove exposed or contaminated clothing, taking care not to contaminate eyes. Contaminated individual must seek immediate medical attention if adverse effect continues after flushing. Eye Exposure: If this product enters the eyes, open contaminated eyes while under gently running water. Use sufficient force to open eyelids. Have individual "roll" eyes. Minimum flushing is for 20 minutes. Do not interrupt flushing. Seek medical attention if adverse effect continues after flushing. Ingestion: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. DO NOT INDUCE VOMITING, unless directly by medical personnel. Have victim rinse mouth with water or give several cupfuls of water, if conscious. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or unable to swallow. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Dermatitis or other pre-existing skin disorders may be aggravated by exposure to this product. INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT IF NEEDED: Treat symptoms and eliminate exposure. Persons suffering allergic reactions must seek immediate medical attention. Pecora 895 NST Page 3 of 9 November 9, 2017 5. FIRE-FIGHTING MEASURES FLASH POINT: > 140°C (> 300°F) AUTOIGNITION: Unknown. FLAMMABLE LIMITS IN AIR: Unknown. EXTINGUISHING MEDIA: Suitable Extinguishing Media: Use extinguishing material suitable to the surrounding fire, including foam, halon, carbon dioxide and dry chemical. Unsuitable Extinguishing Media: None known. PROTECTION OF FIREFIGHTERS: Special Hazards Arising from the Product: This product is combustible and can be ignited when exposed to its flashpoint. Not sensitive to mechanical impact under normal conditions. Not sensitive to static discharge under normal conditions. Closed containers may develop pressure and rupture in event of fire. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS: Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment. Move containers from fire area if it can be done without risk to personnel. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS AND EMERGENCY PROCEDURES: An accidental release may result in a fire in the presence of an ignition source. Uncontrolled releases should be responded to by trained personnel using pre-planned procedures. Proper protective equipment should be used. Eliminate any possible sources of ignition, and provide maximum explosion-proof ventilation. Use only non- sparking tools and equipment during the response. The atmosphere must at least 19.5 percent Oxygen before non-emergency personnel can be allowed in the area without Self-Contained Breathing Apparatus and fire protection. PERSONAL PROTECTIVE EQUIPMENT: Responders should wear the level of protection appropriate to the type of chemical released, the amount of the material spilled, and the location where the incident has occurred. Small Spills: For releases of 1 drum or less, Level D Protective Equipment (gloves, chemical resistant apron, boots, and eye protection) should be worn. Large Spills: Minimum Personal Protective Equipment should be rubber gloves, rubber boots, face shield, and Tyvek suit. Minimum level of personal protective equipment for releases in which the level of oxygen is less than 19.5% or is unknown must be Level B: triple-gloves (rubber gloves and nitrile gloves over latex gloves), chemical resistant suit, fire-retardant clothing and boots, hard hat, and Self-Contained Breathing Apparatus. METHODS FOR CLEAN-UP AND CONTAINMENT: All Spills: Access to the spill area should be restricted. Spread should be limited by gently covering the spill with polypads. Scrape up or pick-up spilled material, placing in suitable containers. Absorb any residual on appropriate material, such as sand. All contaminated absorbents and other materials should be placed in an appropriate container and seal. Do not mix with wastes from other materials. Dispose of in accordance with applicable Federal, State, and local procedures (see Section 13, Disposal Considerations). Dispose of recovered material and report spill per regulatory requirements. Remove all residue before decontamination of spill area. Clean spill area with soap and copious amounts of water. ENVIRONMENTAL PRECAUTIONS: Minimize use of water to prevent environmental contamination. Prevent spill or rinsate from contaminating storm drains, sewers, soil or groundwater. Place all spill residues in a suitable container and seal. Do not discharge effluent containing this product into streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. OTHER INFORMATION: U.S. regulations may require reporting of spills of this material that reach surface waters if a sheen is formed. If necessary, the toll-free phone number for the US Coast Guard National Response Center is 1-800-424-8802. REFERENCE TO OTHER SECTIONS: See information in Section 8 (Exposure Controls – Personal Protection) and Section 13 (Disposal Considerations) for additional information. 7. HANDLING and STORAGE PRECAUTIONS FOR SAFE HANDLING: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly after handling this product. Do not eat or drink while handling this material. Avoid contact with eyes, skin, and clothing. Avoid breathing fumes, dusts, vapors or mist. Do not taste or swallow. Use only with adequate ventilation. Keep away from heat and flame. In the event of a spill, follow practices indicated in Section 6: ACCIDENTAL RELEASE MEASURES. CONDITIONS FOR SAFE STORAGE: This product is stable under ordinary conditions of handling, use and storage. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials (see Section 10: STABILITY AND REACTIVITY). Keep container tightly closed when not in use. Inspect all incoming containers before storage, to ensure containers are properly labeled and not damaged. To prolong shelf life, store at temperatures below 26°C (80°F). PRODUCT END USE: This product is used as a silicone sealant. Follow all industry standards for use of this product. 2 HEALTH FLAMMABILITY INSTABILITY OTHER See Section 16 for Definitions of Ratings NFPA RATING 1 0 Pecora 895 NST Page 4 of 9 November 9, 2017 8. EXPOSURE CONTROLS - PERSONAL PROTECTION EXPOSURE LIMITS/CONTROL PARAMETERS: Ventilation and Engineering Controls: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided below. Occupational/Workplace Exposure Limits/Guidelines: Chemical Name CAS # Guideline Value Calcium Carbonate, Natural Calcium Carbonate, Synthetic 1317-65-3 471-34-0 OSHA PEL TWA NIOSH REL TWA 15 mg/m3 total dust 5 mg/m3 respirable fraction 10 mg/m3 total dust 5 mg/m3 respirable fraction Carbon Black 1333-86-4 ACGIH TLV TWA OSHA PEL TWA NIOSH REL TWA DFG MAK TWA 3 mg/m3 (inhalable fraction) 3.5 mg/m3 3.5 mg/m3 (0.1 in the presence of PAHs, as PAHs: 10-hr TWA); See ACGIH Pocket Guide Appendices A and C As inhalable dust Crystalline Silica (Quartz) 14808-60-7 ACGIH TLV TWA OSHA PEL TWA NIOSH REL TWA 0.025 mg/m3 respirable fraction 30 mg/m3 / % Sio2 + 2 total dust; 10 mg/m3 / % Sio2 + 2 respirable dust 0.05 mg/m3 respirable dust, See ACGIH Pocket Guide Appendix A Organic Methyl Silane NE NE Proprietary Cyclosiloxane NE NE Proprietary Phenylated Ketoxomio Silane Exposure limits given are for decomposition product methylethyl ketoxime AIHA WEEL TWA DFG MAK TWA 10 ppm (Dermal Sensitizer) Skin, Danger of Sensitization of the Skin Proprietary Polydimethyl Siloxane NE NE Proprietary Fumed Silicon Dioxide NE NE Proprietary Mineral Spirits Exposure limits given are for Mineral Spirits CAS # 8052-41-3 ACGIH TLV TWA OSHA PEL TWA NIOSH REL TWA NIOSH REL STEL 525 mg/m3 2900 mg/m3 350 mg/m3 1800 mg/m3 (15 min.) The following are exposure limits for a possible decomposition product, Methanol. Methanol 67-56-1 ACGIH TLV TWA ACGIH TLV STEL OSHA PEL TWA OSHA PEL STEL NIOSH REL TWA NIOSH REL STEL NIOSH IDLH DFG MAK TWA DFG MAK PEAK DFG MAK Pregnancy Risk 200 ppm (skin) 250 ppm (skin) 200 ppm Vacated 1989 PEL: 250 ppm (skin) 200 (skin) 250 (skin) 6000 ppm 200 ppm (skin) 2 ●MAK 15 min. average value, 15 min. interval, 4-per shift Classification C NE = Not Established. See Section 16 for Definitions of Terms Used. Biological Exposure Indices (BEIs): Currently, no BEI’s have been established for components of this product. PERSONAL PROTECTIVE EQUIPMENT (PPE): The following information on appropriate Personal Protective Equipment is provided to assist employers in complying with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132, including the Respiratory Protection Standard (29 CFR 1910.134), Eye Protection Standard 29 CFR 1910.13, the Hand Protection Standard 29 CFR 1910.138, and the Foot Protection Standard 29 CFR 1910.136), equivalent standards of Canada (including the Canadian CSA Respiratory Standard Z94.4-93-02, the CSA Eye Protection Standard Z94.3-M1982, Industrial Eye and Face Protectors and the Canadian CSA Foot Protection Standard Z195-M1984, Protective Footwear). Please reference applicable regulations and standards for relevant details. Eye/Face Protection: Use approved safety goggles or safety glasses. If necessary, refer to appropriate regulations and standards. Skin Protection: Wear chemical impervious gloves (e.g., Nitrile or Neoprene). Use triple gloves for spill response. If necessary, refer to appropriate regulations and standards. Body Protection: Use body protection appropriate for task (e.g., lab coat, coveralls, Tyvek suit). If necessary, refer to the OSHA Technical Manual (Section VII: Personal Protective Equipment) or appropriate Standards of Canada. If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce the soles of the feet or where employee’s feet may be exposed to electrical hazards, use foot protection, as described in appropriate regulations and standards. Respiratory Protection: If mists or sprays from this product are created during use, use appropriate respiratory protection. If necessary, use only respiratory protection authorized in appropriate regulations. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is required under appropriate regulations and standards. 9. PHYSICAL and CHEMICAL PROPERTIES FORM: Smooth paste. COLORS: Black, Tru-White, Aluminum Stone, Translucent, Bronze, Clear MOLECULAR WEIGHT: Mixture. MOLECULAR FORMULA: Mixture. ODOR: Mildly medicinal. ODOR THRESHOLD: Not available. SPECIFIC GRAVITY: 1.1-1.4 VAPOR PRESSURE, mm Hg @ 20°C: Not established. RELATIVE VAPOR DENSITY (air = 1): Heavier than air. EVAPORATION RATE (BuAc = 1): < 1 SOLUBILITY IN WATER: Insoluble. OTHER SOLUBILITIES: Not available. MELTING/FREEZING POINT: Not available. BOILING POINT: Not established. VOC (less water and exempt): < 100 g/L WEIGHT % VOC: ~ 10% FLASH POINT: > 140°C (> 300°F) AUTOIGNITION TEMPERATURE: Not established. FLAMMABLE LIMITS (in air by volume, %): Lower: Not established; Upper: Not established. Pecora 895 NST Page 5 of 9 November 9, 2017 9. PHYSICAL and CHEMICAL PROPERTIES (Continued) pH: Not available. COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not established. HOW TO DETECT THIS SUBSTANCE (IDENTIFYING PROPERTIES): The appearance of this product may act as an identifying property in the event of an accidental release. 10. STABILITY and REACTIVITY CHEMICAL STABILITY: Stable under normal circumstances of use and handling. Methylethyl Ketoxime is generated during curing. Methanol can be generated from curing and contact with water. CONDITIONS TO AVOID: Avoid contact with incompatible chemicals and exposure to extreme temperatures. INCOMPATIBLE MATERIALS: This product is not compatible with strong acids and oxidizers and may have some compatibility with aluminum, ammonium salts and mercury/hydrogen mixtures. HAZARDOUS DECOMPOSITION PRODUCTS: Combustion: Thermal decomposition of this product can generate dusts, irritating fumes, and toxic gases (e.g., carbon, nitrogen and silicone oxides, formaldehyde, various hydrocarbons). Hydrolysis: Methylethyl ketoxime, methanol. POSSIBILITY OF HAZARDOUS REACTIONS/POLYMERIZATION: This product is not expected to undergo hazardous polymerization, decomposition, condensation, or self-reactivity. 11. TOXICOLOGICAL INFORMATION POTENTIAL HEALTH EFFECTS: The most significant routes of occupational exposure are inhalation and contact with skin and eyes. The symptoms of exposure to this product are as follows: Contact with Skin or Eyes: Contact may irritate the skin and cause redness and discomfort, depending on duration of contact. Prolonged or repeated skin contact may cause dermatitis (dry, red skin). Eye contact may cause redness, pain, and tearing. Skin contact may cause sensitization and allergic reaction in susceptible individuals. Symptoms may include redness, itching and rash. Skin Absorption: Some components of this product are known to be absorbed through intact skin. Skin contact may cause some systemic effects if a large area of skin is contaminated. Ingestion: If the product is swallowed, it may mildly irritate the mouth, throat, and other tissues of the gastro-intestinal system and may cause nausea, vomiting, and diarrhea. Due to the Organic Methyl Silane component, ingestion may produce blood effects, reducing the blood’s ability to transport oxygen (methemoglobinemia and anemia). Reversible narcotic effects may occur. Inhalation: Exposure to vapors of this product generated during curing, or dusts of this product generated during use after curing may mildly irritate the respiratory tract and cause coughing and sneezing. Vapors or fumes when used in an enclosed space, if heated or during curing may cause irritation of the respiratory system. Symptoms include nose irritation, dry or sore or burning throat, runny nose, shortness of breath, dizziness, incoordination. Vapors from decomposition or exposure to atmospheric moisture may produce reversible narcotic effect due to formation of methanol. Narcotic effects can include dizziness, headache, nausea, vomiting, chest tightness, limb weakness, staggering gait, confusion. In severe cases, there may be restlessness, convulsions, coma. Injection: Accidental injection of this product (e.g. puncture with a contaminated object) may cause burning, redness, and swelling in addition to the wound. Target Organs: Acute: Skin, eyes. Chronic: Skin, blood. Chronic Effects: Prolonged or repeated skin contact may cause dermatitis (dry, red skin). TOXICITY DATA: There are currently no toxicity data available for this product; the following toxicology information is available for components greater than 1% in concentration. Due to large amount of data for some components, only Human data, Irritancy data, LD50 Oral-Rat, LD50 Oral-Mouse, LD50 Skin-Rat, LD50 Skin-Rabbit, LC50 Inhalation-Rat, LC50 Inhalation-Mouse and select reproductive toxicity data are provided in this SDS for those components. Contact Pecora for information on additional data. CALCIUM CARBONATE, NATURAL: TDLo (Intravenous-Rat) 30 mg/kg: Vascular: BP lowering not characterized in autonomic section; Lungs, Thorax, or Respiration: changes in lung weight; Blood: other changes TCLo (Inhalation-Rat) 84 mg/m3/4 hours/40 weeks-intermittent: Lungs, Thorax, or Respiration: fibrosis (interstitial); Liver: other changes; Kidney/Ureter/Bladder: other changes TCLo (Inhalation-Rat) 250 mg/m3/2 hours/24 weeks-intermittent: Lungs, Thorax, or Respiration: fibrosis, focal (pneumoconiosis) CARBON BLACK: LD50 (Oral-Rat) > 15 400 mg/kg: Behavioral: somnolence (general depressed activity) LD50 (Skin-Rabbit) > 3 gm/kg PROPRIETARY FUMED SILICA: LD50 (Oral-Rat) 3160 mg/kg MINERAL SPIRITS: Standard Draize Test (Eye-Human) 100 ppm: Mild Standard Draize Test (Eye-Rabbit) 500 mg/24 hours: Moderate LC50 (Inhalation-Rat) > 1400 ppm/8 hours LD (Oral-Rat) > 5 gm/kg: Behavioral: somnolence (general depressed activity) LD (Skin-Rabbit) > 3 gm/kg LC (Inhalation-Rat) > 5500 mg/m3/4 hours: Behavioral: somnolence (general depressed activity) PROPRIETARY CYCLOSIOLXANE: Standard Draize Test (Skin-Rabbit) 500 mg/24 hours: Mild Standard Draize Test (Eye-Rabbit) 500 mg/24 hours: Mild LC50 (Inhalation-Rat) 36 gm/m3/4 hours: Behavioral: excitement; Lungs, Thorax, or Respiration: dyspnea Skin and Appendages: hair LD50 (Oral-Rat) 1540 mg/kg: Behavioral: tremor LD50 (Skin-Rat) 1770 mg/kg: Behavioral: tremor; Gastrointestinal: changes in structure or function of salivary glands; Liver: other changes LD50 (Skin-Rabbit) 794 µL/kg: Kidney/Ureter/Bladder: hematuria PROPRIETARY PHENYLATED KETOXIMO SILANE: LD50 (Oral-Rat) > 8000 mg/kg LD50 (Dermal-Rat) > 4000 mg/kg LC50 (Inhalation-Rat) > 8000 mg/m3, 4 hours PROPRIETARY POLYMDIMETHYLSILOXANE DIOL: LD50 (Oral-Rat) 3160 mg/kg CARCINOGENIC POTENTIAL: The following table summarizes the carcinogenicity listing for the components of this product. “NO” indicates that the substance is not considered to be or suspected to be a carcinogen by the listed agency, see section 16 for definitions of other ratings. CHEMICAL EPA IARC NTP NIOSH ACGIH OSHA MAK PROP 65 Calcium Carbonate (Natural, Synthetic) No No No No No No No No Carbon Black No 2B No Ca (in presence of PAHs) A3 No No Yes (airborne, unbound particles of respirable size) Pecora 895 NST Page 6 of 9 November 9, 2017 11. TOXICOLOGICAL INFORMATION (Continued) CARCINOGENIC POTENTIAL (continued): CHEMICAL EPA IARC NTP NIOSH ACGIH OSHA MAK PROP 65 Crystalline Silica (quartz) No 1 K* Ca A2 No 1* Yes (airborne unbound particles of respirable size) Organic Methyl Silane No No No No No No No No Mineral Spirits No No No No No No No No Proprietary Cyclosiloxane No No No No No No No No Proprietary Phenylated Ketoxomio Silane No No No No No No No No Proprietary Polydimethyl Siloxane No No No No No No No No Proprietary Fumed Silicon Dioxide No No No No No No No No The following is a compound from reaction with water and generated during curing: Methyl Alcohol No No No No No No No No Methyl Ethyl Ketoxime No No No No No No No No *Respirable. ACGIH TLV-A2: Suspected Human Carcinogen. ACGIH TLV-A3: Confirmed Animal Carcinogen with Unknown Relevance to Humans. IARC 1: Carcinogenic to Humans. IARC-2B: Possibly Carcinogenic to Humans. MAK-1 Substances that Cause Cancer in Man and Can Be Assumed to Make a Significant Contribution to Cancer Risk. NTP-K: Known to Be a Human Carcinogen. NIOSH-Ca: Potential Occupational Carcinogen, with No Further Categorization. IRRITANCY OF PRODUCT: This product may irritate contaminated tissue, especially if contact is prolonged. SENSITIZATION TO THE PRODUCT: This product may cause skin sensitization and allergic reaction in susceptible individuals due to the Proprietary Phenylated Ketoximo Silane and Organic Methyl Silane components. TOXICOLOGICAL SYNERGISTIC PRODUCTS: None known. REPRODUCTIVE TOXICITY INFORMATION: This product has not been tested for reproductive toxicity. Information for some components is given, as follows. Mutagenicity/Embryotoxicity/ Teratogenicity/Reproductive Toxicity: In a developmental and reproductive toxicity study involving female rats and the trace Proprietary Cyclosiloxane component, a significant percentage of female rats exposed experienced reduction of proestrus LH levels, a reduction of ovulation and decreased FSH hormone levels. 12. ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. MOBILITY: This product has not been tested for mobility in soil. PERSISTENCE AND BIODEGRADABILITY: This product has not been tested for persistence or biodegradability. BIO-ACCUMULATION POTENTIAL: This product has not been tested for bio-accumulation potential. ECOTOXICITY: This product has not been tested for aquatic or animal toxicity. Data are available for the trace Octamethylcyclotetrasiloxane component. Although no data is available, under the Global Harmonization Standard, the Proprietary Phenylated Ketoximo Silane component is classified as having chronic aquatic toxicity. PROPRIETARY CYCLOSILOXANE: LC50 (Oncorhynchus mykiss Rainbow trout) 14 days = 10 µg/L LC50 (Lepomis macrochirus Bluegill) 96 hours = > 1000 mg/L LC50 (Brachydanio rerio Zebra danio) 96 hours = >500 mg/L OTHER ADVERSE EFFECTS: Components of this product are not reported to have any ozone depletion potential. ENVIRONMENTAL EXPOSURE CONTROLS: Controls should be engineered to prevent release to the environment, including procedures to prevent spills, atmospheric release and release to waterways. 13. DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL: As supplied, this product would not be a hazardous waste as defined by U.S. federal regulation (40 CFR 261) if discarded or disposed. State and local regulations may differ from federal regulations. The generator of the waste is responsible for proper waste determination and management. U.S. EPA WASTE NUMBER: Not applicable. 14. TRANSPORTATION INFORMATION U.S. DEPARTMENT OF TRANSPORTATION: This product is NOT classified as Dangerous Goods, per U.S. DOT regulations, under 49 CFR 172.101. TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is NOT classified as Dangerous Goods, per regulations of Transport Canada. INTERNATIONAL AIR TRANSPORT ASSOCIATION SHIPPING INFORMATION (IATA): This product is NOT classified as dangerous goods, per the International Air Transport Association. INTERNATIONAL MARITIME ORGANIZATION SHIPPING INFORMATION (IMO): This product is not classified as dangerous goods, per the International Maritime Organization. Pecora 895 NST Page 7 of 9 November 9, 2017 15. REGULATORY INFORMATION U.S. REGULATIONS: U.S. SARA Reporting Requirements: No component of this product is subject to the reporting requirements of Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act. U.S. SARA Hazard Categories (Section 311/312, 40 CFR 370-21): ACUTE: Yes; CHRONIC: Yes; FIRE: No; REACTIVE: No; SUDDEN RELEASE: No U.S. TSCA Inventory Status: All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. U.S. CERCLA Reportable Quantity (RQ): Not applicable. U.S. Clean Air Act (CA 112r) Threshold Quantity (TQ): Not applicable. California Safe Drinking Water and Toxic Enforcement Act (Proposition 65): The trace Quartz component (airborne, unbound particles of respirable size) is found on the Proposition 65 List of chemicals known to the state to cause cancer. The Carbon Black component is also on the Proposition 65v lists as compounds that may cause cancer by inhalation of unbound particles. Due to the form of the product, the Proposition 65 warning for these compounds are not applicable to this product. CANADIAN REGULATIONS: Canadian DSL/NDSL Inventory Status: The components of this product listed by CAS# in Section 3 (MATERIAL IDENTIFICATION) are listed on the DSL Inventory. Canadian Environmental Protection Act (CEPA) Priorities Substances Lists: Not applicable. Canadian WHMIS (HPR-GHS) 2015 Classification and Symbols: See Section 16 for in Classification and Symbols under HPR-GHS 2015. MEXICAN REGULATIONS: Mexican Workplace Regulations (NOM-018-STPS-2000): This product is not classified as hazardous. 16. OTHER INFORMATION WARNINGS (per ANSI Z129.1): WARNING! CONTAINS TRACE COMPONENT THAT MAY CAUSE ADVERSE EFFECTS ON FERTILITY, BASED ON ANIMAL DATA. MAY CAUSE EYE, SKIN, AND RESPIRATORY TRACT IRRITATION, ESPECIALLY IF EXPOSURE IS PROLONGED. MAY BE HARMFUL IF ACCIDENTALLY INGESTED OR IN CONTACT WITH THE SKIN. MAY CAUSE SKIN SENSITIZATION AND ALLERGIC REACTION IN SUSCEPTIBLE INDIVIDUALS. REPEATED EXPOSURE MAY CAUSE ADVERSE SYSTEMIC EFFECTS. COMBUSTIBLE – CAN IGNITE IF EXPOSED TO DIRECT FLAME. CONTAINS COMPOUNDS ACUTELY AND CHRONICALLY TOXIC TO AQUATIC ORGANISMS. Avoid contact with eyes, skin, and clothing. Avoid breathing fumes, dusts, vapors or mist. Do not taste or swallow. Wash thoroughly after handling. Keep container tightly closed. Use only with adequate ventilation. Keep away from heat and flame. Wear gloves, eye protection, respiratory protection, and appropriate body protection. FIRST-AID: In case of contact, immediately flush skin and eyes with plenty of water. Remove contaminated clothing and shoes. Get medical attention if irritation develops or persists. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If swallowed, do not induce vomiting. Get medical attention. IN CASE OF FIRE: Use water fog, foam, dry chemical, or CO2. IN CASE OF SPILL: Absorb spilled product with polypads or other suitable absorbing material. Place all spill residue in an appropriate container and seal. Dispose of in accordance with U.S. Federal, State, and local hazardous waste disposal regulations and those of Canada. GLOBAL HARMONIZATION LABELING AND CLASSIFICATION: Classified in accordance with Global Harmonization Standard under U.S. OSHA Hazard Communication Standard, Canadian WHMIS HPR-GHS 2015. Classification: Reproductive Toxicity Category 2, Acute Oral Toxicity Category 5, Acute Dermal Toxicity Category 5, Eye Irritation Category 2A, Skin Irritation Category 2, Skin Sensitization Category 1, Specific Organ Toxicity (Blood Effects) Repeated Exposure Category 3, Aquatic Chronic Toxicity Category 4 Signal Word: Warning Hazard Statements: H361f: Suspected of damaging fertility. H303 + H313: May be harmful if ingested or in contact with skin. H315: Causes skin irritation. H319: Causes serious eye irritation. H317: May cause an allergic skin reaction. H373: May cause damage to blood through prolonged or repeated exposure. H413: May be harmful to aquatic life with long-lasting effects. Precautionary Statements: Prevention: P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P260: Do not breathe dust/gas/mist/vapours/spray. P264: Wash thoroughly after handling. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection. Response: P308 + P313: IF exposed or concerned: Get medical advice/attention. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. P337 + P313: If eye irritation persists: Get medical advice/attention. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P333 + P313: If skin irritation or rash occurs: Get medical advice/attention. P362 + P364: Take off contaminated clothing and wash it before reuse. P321: Specific treatment (remove from exposure and treat symptoms). Storage: P405: Store locked up. Disposal: P501: Dispose of contents/containers in accordance with all local, regional, national and international regulations. Hazard Symbols/Pictogram: GHS07, GHS08 DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES The information presented in this Safety Data Sheet is presented in good faith based on data believed to be accurate as of the date this Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. In no case shall the descriptions, information, data or designs provided be considered a part of our terms and conditions of sale. Pecora 895 NST Page 8 of 9 November 9, 2017 16. OTHER INFORMATION (Continued) DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES (continued) All materials may present hazards and should be used with caution. Because many factors may affect processing or application/use, we recommend that you make tests to determine the suitability of a product for your particular purpose prior to use. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices or applicable federal, state, or local laws or regulations. The information provided above, and the product, are furnished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any patented invention without a license. REFERENCES AND DATA SOURCES: Contact the supplier for information. METHODS OF EVALUATING INFORMATION FOR THE PURPOSE OF CLASSIFICATION: Bridging principles were used to classify this product. REVISION DETAILS: July 2012: Up-date and revise entire SDS to include current GHS requirements. November 2017: Up-date of entire SDS for formulation change and most current format and regulations. DATE OF PRINTING January 5, 2018 DEFINITIONS OF TERMS A large number of abbreviations and acronyms appear on a SDS. Some of these, which are commonly used, include the following: KEY ACRONYMS: CHEMTREC: Chemical Transportation Emergency Center, a 24-hour emergency information and/or emergency assistance to emergency responders. CEILING LEVEL: The concentration that shall not be exceeded during any part of the working exposure. DFG MAKs: Federal Republic of Germany Maximum Concentration Values in the workplace. Exposure limits are given as TWA (Time-Weighted Average) or PEAK (short-term exposure) values. DFG MAK Germ Cell Mutagen Categories: 1: Germ cell mutagens that have been shown to increase the mutant frequency in the progeny of exposed humans. 2: Germ cell mutagens that have been shown to increase the mutant frequency in the progeny of exposed mammals. 3A: Substances that have been shown to induce genetic damage in germ cells of human of animals, or which produce mutagenic effects in somatic cells of mammals in vivo and have been shown to reach the germ cells in an active form. 3B: Substances that are suspected of being germ cell mutagens because of their genotoxic effects in mammalian somatic cell in vivo; in exceptional cases, substances for which there are no in vivo data, but that are clearly mutagenic in vitro and structurally related to known in vivo mutagens. 4: Not applicable (Category 4 carcinogenic substances are those with non-genotoxic mechanisms of action. By definition, germ cell mutagens are genotoxic. Therefore, a Category 4 for germ cell mutagens cannot apply. At some time in the future, it is conceivable that a Category 4 could be established for genotoxic substances with primary targets other than DNA [e.g. purely aneugenic substances] if research results make this seem sensible.) 5: Germ cell mutagens, the potency of which is considered to be so low that, provided the MAK value is observed, their contribution to genetic risk for humans is expected not to be significant. DFG MAK Pregnancy Risk Group Classification: Group A: A risk of damage to the developing embryo or fetus has been unequivocally demonstrated. Exposure of pregnant women can lead to damage of the developing organism, even when MAK and BAT (Biological Tolerance Value for Working Materials) values are observed. Group B: Currently available information indicates a risk of damage to the developing embryo or fetus must be considered to be probable. Damage to the developing organism cannot be excluded when pregnant women are exposed, even when MAK and BAT values are observed. Group C: There is no reason to fear a risk of damage to the developing embryo or fetus when MAK and BAT values are observed. Group D: Classification in one of the groups A–C is not yet possible because, although the data available may indicate a trend, they are not sufficient for final evaluation. IDLH: Immediately Dangerous to Life and Health. This level represents a concentration from which one can escape within 30-minutes without suffering escape-preventing or permanent injury. LOQ: Limit of Quantitation. NE: Not Established. When no exposure guidelines are established, an entry of NE is made for reference. NIC: Notice of Intended Change. NIOSH CEILING: The exposure that shall not be exceeded during any part of the workday. If instantaneous monitoring is not feasible, the ceiling shall be assumed as a 15-minute TWA exposure (unless otherwise specified) that shall not be exceeded at any time during a workday. NIOSH RELs: NIOSH’s Recommended Exposure Limits. PEL: OSHA's Permissible Exposure Limits. This exposure value means exactly the same as a TLV, except that it is enforceable by OSHA. The OSHA Permissible Exposure Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs are indicated. The phrase, “Vacated 1989 PEL” is placed next to the PEL that was vacated by Court Order. SKIN: Used when a there is a danger of cutaneous absorption. STEL: Short Term Exposure Limit, usually a 15-minute time-weighted average (TWA) exposure that should not be exceeded at any time during a workday, even if the 8-hr TWA is within the TLV-TWA, PEL-TWA or REL-TWA. TLV: Threshold Limit Value. An airborne concentration of a substance that represents conditions under which it is generally believed that nearly all workers may be repeatedly exposed without adverse effect. The duration must be considered, including the 8-hour. TWA: Time Weighted Average exposure concentration for a conventional 8-hr (TLV, PEL) or up to a 10-hr (REL) workday and a 40-hr workweek. WEEL: Workplace Environmental Exposure Limits from the AIHA. HAZARD RATINGS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD RATINGS: This rating system was developed by the National Paint and Coating Association and has been adopted by industry to identify the degree of chemical hazards. HEALTH HAZARD: 0 Minimal Hazard: No significant health risk, irritation of skin or eyes not anticipated. Skin Irritation: Essentially non-irritating. Mechanical irritation may occur. PII or Draize = 0. Eye Irritation: Essentially non-irritating, minimal effects clearing in < 24 hours. Mechanical irritation may occur. Draize = 0. Oral Toxicity LD50 Rat: > 5000 mg/kg. Dermal Toxicity LD50 Rat or Rabbit: > 2000 mg/kg. Inhalation Toxicity 4-hrs LC50 Rat: > 20 mg/L. 1 Slight Hazard: Minor reversible injury may occur; may irritate the stomach if swallowed; may defat the skin and exacerbate existing dermatitis. Skin Irritation: Slightly or mildly irritating. PII or Draize > 0 < 5. Eye Irritation: Slightly to mildly irritating, but reversible within 7 days. Draize > 0 ≤ 25. Oral Toxicity LD50 Rat: > 500–5000 mg/kg. Dermal Toxicity LD50 Rat or Rabbit: > 1000–2000 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 2–20 mg/L. 2 Moderate Hazard: Temporary or transitory injury may occur; prolonged exposure may affect the CNS. Skin Irritation: Moderately irritating; primary irritant; sensitizer. PII or Draize ≥ 5, with no destruction of dermal tissue. Eye Irritation: Moderately to severely irritating; reversible corneal opacity; corneal involvement or irritation clearing in 8–21 days. Draize = 26–100, with reversible effects. Oral Toxicity LD50 Rat: > 50–500 mg/kg. Dermal Toxicity LD50 Rat or Rabbit: > 200–1000 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 0.5–2 mg/L. HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD RATINGS (continued): HEALTH HAZARD (continued): 3 Serious Hazard: Major injury likely unless prompt action is taken and medical treatment is given; high level of toxicity; corrosive. Skin Irritation: Severely irritating and/or corrosive; may cause destruction of dermal tissue, skin burns, and dermal necrosis. PII or Draize > 5–8, with destruction of tissue. Eye Irritation: Corrosive, irreversible destruction of ocular tissue; corneal involvement or irritation persisting for more than 21 days. Draize > 80 with effects irreversible in 21 days. Oral Toxicity LD50 Rat: > 1–50 mg/kg. Dermal Toxicity LD50 Rat or Rabbit: > 20–200 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 0.05–0.5 mg/L.4 Severe Hazard: Life-threatening; major or permanent damage may result from single or repeated exposure; extremely toxic; irreversible injury may result from brief contact. Skin Irritation: Not appropriate. Do not rate as a 4, based on skin irritation alone. Eye Irritation: Not appropriate. Do not rate as a 4, based on eye irritation alone. Oral Toxicity LD50 Rat: ≤ 1 mg/kg. Dermal Toxicity LD50 Rat or Rabbit: ≤ 20 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: ≤ 0.05 mg/L. FLAMMABILITY HAZARD: 0 Minimal Hazard: Materials that will not burn in air when exposure to a temperature of 815.5°C (1500°F) for a period of 5 minutes. 1 Slight Hazard: Materials that must be pre-heated before ignition can occur. Material requires considerable pre-heating, under all ambient temperature conditions before ignition and combustion can occur. This usually includes the following: Materials that will burn in air when exposed to a temperature of 815.5°C (1500°F) for a period of 5 minutes or less; Liquids, solids and semisolids having a flash point at or above 93.3°C (200°F) (i.e. OSHA Class IIIB); and Most ordinary combustible materials (e.g. wood, paper, etc.). 2 Moderate Hazard: Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. Materials in this degree would not, under normal conditions, form hazardous atmospheres in air, but under high ambient temperatures or moderate heating may release vapor in sufficient quantities to produce hazardous atmospheres with air. This usually includes the following: Liquids having a flash-point at or above 37.8°C (100°F); Solid materials in the form of course dusts that may burn rapidly but that generally do not form explosive atmospheres; Solid materials in a fibrous or shredded form that may burn rapidly and create flash fire hazards (e.g. cotton, sisal, hemp); and Solids and semisolids (e.g. viscous and slow flowing as asphalt) that readily give off flammable vapors. 3 Serious Hazard: Liquids and solids that can be ignited under almost all ambient temperature conditions. Materials in this degree produce hazardous atmospheres with air under almost all ambient temperatures, or, unaffected by ambient temperature, are readily ignited under almost all conditions. This usually includes the following: Liquids having a flash point below 22.8°C (73°F) and having a boiling point at or above 38°C (100°F) and those liquids having a flash point at or above 22.8°C (73°F) and below 37.8°C (100°F) (i.e. OSHA Class IB and IC); Materials that on account of their physical form or environmental conditions can form explosive mixtures with air and are readily dispersed in air (e.g., dusts of combustible solids, mists or droplets of flammable liquids); and Materials that burn extremely rapidly, usually by reason of self-contained oxygen (e.g. dry nitrocellulose and many organic peroxides). 4 Severe Hazard: Materials that will rapidly or completely vaporize at atmospheric pressure and normal ambient temperature or that are readily dispersed in air, and that will burn readily. This usually includes the following: Flammable gases; Flammable cryogenic materials; Any liquid or gaseous material that is liquid while under pressure and has a flash point below 22.8°C (73°F) and a boiling point below 37.8°C (100°F) (i.e. OSHA Class IA); and Materials that ignite spontaneously when exposed to air at a temperature of 54.4°C (130°F) or below (pyrophoric). PHYSICAL HAZARD: 0 Water Reactivity: Materials that do not react with water. Organic Peroxides: Materials that are normally stable, even under fire conditions and will not react with water. Explosives: Substances that are Non-Explosive. Compressed Gases: No Rating. Pyrophorics: No Rating. Oxidizers: No 0 rating. Unstable Reactives: Substances that will not polymerize, decompose, condense, or self- react.). 1 Water Reactivity: Materials that change or decompose upon exposure to moisture. Organic Peroxides: Materials that are normally stable, but can become unstable at high temperatures and pressures. These materials may react with water, but will not release energy violently. Explosives: Division 1.5 & 1.6 explosives. Substances that are very insensitive explosives or that do not have a mass explosion hazard. Compressed Gases: Pressure below OSHA definition. Pyrophorics: No Rating. Oxidizers: Packaging Group III oxidizers; Solids: any material that in either concentration tested, exhibits a mean burning time less than or equal to the mean burning time of a 3:7 potassium bromate/cellulose mixture and the criteria for Packing Group I and II are not met. Liquids: any material that exhibits a mean pressure rise time less than or equal to the pressure rise time of a 1:1 nitric acid (65%)/cellulose mixture and the criteria for Packing Group I and II are not met. Unstable Reactives: Substances that may decompose condense, or self-react, but only under conditions of high temperature and/or pressure and have little or no potential to cause significant heat generation or explosion hazard. Substances that readily undergo hazardous polymerization in the absence of inhibitors. 2 Water Reactivity: Materials that may react violently with water. Organic Peroxides: Materials that, in themselves, are normally unstable and will readily undergo violent chemical change, but will not detonate. These materials may also react violently with water. Explosives: Division 1.4 explosives. Explosive substances where the explosive effects are largely confined to the package and no projection of fragments of appreciable size or range are expected. An external fire must not cause virtually instantaneous explosion of almost the entire contents of the package. Compressed Gases: Pressurized and meet OSHA definition but < 514.7 psi absolute at 21.1°C (70°F) [500 psig]. Pyrophorics: No Rating. Oxidizers: Packing Group II oxidizers. Solids: any material that, either in concentration tested, exhibits a mean burning time of less than or equal to the mean burning time of a 2:3 potassium bromate/cellulose mixture and the criteria for Packing Group I are not met. Liquids: any material that exhibits a mean pressure rise time less than or equal to the pressure rise of a 1:1 aqueous sodium chlorate solution (40%)/cellulose mixture and the criteria for Packing Group I are not met. Reactives: Substances that may polymerize, decompose, condense, or self-react at ambient temperature and/or pressure, but have a low potential (or low risk) for significant heat generation or explosion. Substances that readily form peroxides upon exposure to air or oxygen at room temperature. Pecora 895 NST Page 9 of 9 November 9, 2017 DEFINITIONS OF TERMS (Continued) HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD RATINGS (continued): PHYSICAL HAZARD (continued): 3 Water Reactivity: Materials that may form explosive reactions with water. Organic Peroxides: Materials that are capable of detonation or explosive reaction, but require a strong initiating source or must be heated under confinement before initiation; or materials that react explosively with water. Explosives: Division 1.3 explosives. Explosive substances that have a fire hazard and either a minor blast hazard or a minor projection hazard or both, but do not have a mass explosion hazard. Compressed Gases: Pressure ≥ 514.7 psi absolute at 21.1°C (70°F) [500 psig]. Pyrophorics: No Rating. Oxidizers: Packing Group I oxidizers. Solids: any material that, in either concentration tested, exhibits a mean burning time less than the mean burning time of a 3:2 potassium bromate/cellulose mixture. Liquids: any material that spontaneously ignites when mixed with cellulose in a 1:1 ratio, or which exhibits a mean pressure rise time less than the pressure rise time of a 1:1 perchloric acid (50%)/cellulose mixture. Unstable Reactives: Substances that may polymerize, decompose, condense, or self-react at ambient temperature and/or pressure and have a moderate potential (or moderate risk) to cause significant heat generation or explosion. 4 Water Reactivity: Materials that react explosively with water without requiring heat or confinement. Organic Peroxides: Materials that are readily capable of detonation or explosive decomposition at normal temperature and pressures. Explosives: Division 1.1 & 1.2 explosives. Explosive substances that have a mass explosion hazard or have a projection hazard. A mass explosion is one that affects almost the entire load instantaneously. Compressed Gases: No Rating. Pyrophorics: Add to the definition of Flammability 4. Oxidizers: No 4 rating. Unstable Reactives: Substances that may polymerize, decompose, condense, or self-react at ambient temperature and/or pressure and have a high potential (or high risk) to cause significant heat generation or explosion. Pyrophorics: Add to the definition of Flammability 4. Oxidizers: No 4 rating. Unstable Reactives: Substances that may polymerize, decompose, condense, or self-react at ambient temperature and/or pressure and have a high potential (or high risk) to cause significant heat generation or explosion. NATIONAL FIRE PROTECTION ASSOCIATION HAZARD RATINGS HEALTH HAZARD: 0 Materials that, under emergency conditions, would offer no hazard beyond that of ordinary combustible materials. Gases and vapors with an LC50 for acute inhalation toxicity greater than 10,000 ppm. Dusts and mists with an LC50 for acute inhalation toxicity greater than 200 mg/L. Materials with an LD50 for acute dermal toxicity greater than 2000 mg/kg. Materials with an LD50 for acute oral toxicity greater than 2000 mg/kg. Materials essentially non-irritating to the respiratory tract, eyes, and skin. 1 Materials that, under emergency conditions, can cause significant irritation. Gases and vapors with an LC50 for acute inhalation toxicity greater than 5,000 ppm but less than or equal to 10,000 ppm. Dusts and mists with an LC50 for acute inhalation toxicity greater than 10 mg/L but less than or equal to 200 mg/L. Materials with an LD50 for acute dermal toxicity greater than 1000 mg/kg but less than or equal to 2000 mg/kg. Materials that slightly to moderately irritate the respiratory tract, eyes and skin. Materials with an LD50 for acute oral toxicity greater than 500 mg/kg but less than or equal to 2000 mg/kg. 2 Materials that, under emergency conditions, can cause temporary incapacitation or residual injury. Gases with an LC50 for acute inhalation toxicity greater than 3,000 ppm but less than or equal to 5,000 ppm. Any liquid whose saturated vapor concentration at 20°C (68°F) is equal to or greater than one-fifth its LC50 for acute inhalation toxicity, if its LC50 is less than or equal to 5000 ppm and that does not meet the criteria for either degree of hazard 3 or degree of hazard 4. Dusts and mists with an LC50 for acute inhalation toxicity greater than 2 mg/L but less than or equal to 10 mg/L. Materials with an LD50 for acute dermal toxicity greater than 200 mg/kg but less than or equal to 1000 mg/kg. Compressed liquefied gases with boiling points between -30°C (-22°F) and -55°C (-66.5°F) that cause severe tissue damage, depending on duration of exposure. Materials that are respiratory irritants. Materials that cause severe, but reversible irritation to the eyes or are lachrymators. Materials that are primary skin irritants or sensitizers. Materials whose LD50 for acute oral toxicity is greater than 50 mg/kg but less than or equal to 500 mg/kg. 3 Materials that, under emergency conditions, can cause serious or permanent injury. Gases with an LC50 for acute inhalation toxicity greater than 1,000 ppm but less than or equal to 3,000 ppm. Any liquid whose saturated vapor concentration at 20°C (68°F) is equal to or greater its LC50 for acute inhalation toxicity, if its LC50 is less than or equal to 3000 ppm and that does not meet the criteria for degree of hazard 4. Dusts and mists with an LC50 for acute inhalation toxicity greater than 0.5 mg/L but less than or equal to 2 mg/L. Materials with an LD50 for acute dermal toxicity greater than 40 mg/kg but less than or equal to 200 mg/kg. Materials that are corrosive to the respiratory tract. Materials that are corrosive to the eyes or cause irreversible corneal opacity. Materials corrosive to the skin. Cryogenic gases that cause frostbite and irreversible tissue damage. Compressed liquefied gases with boiling points below -55°C (-66.5°F) that cause frostbite and irreversible tissue damage. Materials with an LD50 for acute oral toxicity greater than 5 mg/kg but less than or equal to 50 mg/kg. 4 Materials that, under emergency conditions, can be lethal. Gases with an LC50 for acute inhalation toxicity less than or equal to 1,000 ppm. Any liquid whose saturated vapor concentration at 20°C (68°F) is equal to or greater than ten times its LC50 for acute inhalation toxicity, if its LC50 is less than or equal to 1000 ppm. Dusts and mists whose LC50 for acute inhalation toxicity is less than or equal to 0.5 mg/L. Materials whose LD50 for acute dermal toxicity is less than or equal to 40 mg/kg. Materials whose LD50 for acute oral toxicity is less than or equal to 5 mg/kg. FLAMMABILITY HAZARD: 0 Materials that will not burn under typical fire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. Materials that will not burn in air when exposed to a temperature of 816°C (1500°F) for a period of 5 minutes in according with Annex D of NFPA 704. 1 Materials that must be preheated before ignition can occur. Materials in this degree require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur: Materials that will burn in air when exposed to a temperature of 816°C (1500°F) for a period of 5 minutes in according with Annex D of NFPA 704. Liquids, solids, and semisolids having a flash point at or above 93.4°C (200°F) (i.e. Class IIIB liquids). Liquids with a flash point greater than 35°C (95°F) that do not sustain combustion when tested using the Method of Testing for Sustained Combustibility, per 49 CFR 173, Appendix H or the UN Recommendations on the Transport of Dangerous Goods, Model Regulations (current edition) and the related Manual of Tests and Criteria (current edition). Liquids with a flash point greater than 35°C (95°F) in a water-miscible solution or dispersion with a water non-combustible liquid/solid content of more than 85% by weight. Liquids that have no fire point when tested by ASTM D 92, Standard Test Method for Flash and Fire Points by Cleveland Open Cup, up to the boiling point of the liquid or up to a temperature at which the sample being tested shows an obvious physical change. Combustible pellets with a representative diameter of greater than 2 mm (10 mesh). Most ordinary combustible materials. Solids containing greater than 0.5% by weight of a flammable or combustible solvent are rated by the closed cup flash point of the solvent. 2 Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. Materials in this degree would not under normal conditions form hazardous atmospheres with air, but under high ambient temperatures or under moderate heating could release vapor in sufficient quantities to produce hazardous atmospheres with air. Liquids having a flash point at or above 37.8°C (100°F) and below 93.4°C (200°F) (i.e. Class II and Class IIIA liquids.) Solid materials in the form of powders or coarse dusts of representative diameter between 420 microns (40 mesh) and 2 mm (10 mesh) that burn rapidly but that generally do not form explosive mixtures with air. NATIONAL FIRE PROTECTION ASSOCIATION HAZARD RATINGS (continued): FLAMMABILITY HAZARD (continued): 2 (continued): Solid materials in fibrous or shredded form that burn rapidly and create flash fire hazards, such as cotton, sisal, and hemp. Solids and semisolids that readily give off flammable vapors. Solids containing greater than 0.5% by weight of a flammable or combustible solvent are rated by the closed cup flash point of the solvent. 3 Liquids and solids that can be ignited under almost all ambient temperature conditions. Materials in this degree produce hazardous atmospheres with air under almost all ambient temperatures or, though unaffected by ambient temperatures, are readily ignited under almost all conditions. Liquids having a flash point below 22.8°C (73°F) and having a boiling point at or above 37.8°C (100°F) and those liquids having a flash point at or above 22.8°C (73°F) and below 37.8°C (100°F) (i.e. Class IB and IC liquids). Materials that on account of their physical form or environmental conditions can form explosive mixtures with air and are readily dispersed in air. Flammable or combustible dusts with representative diameter less than 420 microns (40 mesh). Materials that burn with extreme rapidity, usually by reason of self-contained oxygen (e.g. dry nitrocellulose and many organic peroxides). Solids containing greater than 0.5% by weight of a flammable or combustible solvent are rated by the closed cup flash point of the solvent. 4 Materials that will rapidly or completely vaporize at atmospheric pressure and normal ambient temperature or that are readily dispersed in air and will burn readily. Flammable gases. Flammable cryogenic materials. Any liquid or gaseous materials that is liquid while under pressure and has a flash point below 22.8°C (73°F) and a boiling point below 37.8°C (100°F) (i.e. Class IA liquids). Materials that ignite when exposed to air, Solids containing greater than 0.5% by weight of a flammable or combustible solvent are rated by the closed cup flash point of the solvent. INSTABILITY HAZARD: 0 Materials that in themselves are normally stable, even under fire conditions. Materials that have an instantaneous power density (product of heat of reaction and reaction rate) at 250°C (482°F) below 0.01 W/mL. Materials that do not exhibit an exotherm at temperatures less than or equal to 500°C (932°F) when tested by differential scanning calorimetry.1 Materials that in themselves are normally stable, but that can become unstable at elevated temperatures and pressures. Materials that have an instantaneous power density (product of heat of reaction and reaction rate) at 250°C (482°F) at or above 0.01 W/mL and below 10 W/mL. 2 Materials that readily undergo violent chemical change at elevated temperatures and pressures. Materials that have an instantaneous power density (product of heat of reaction and reaction rate) at 250°C (482°F) at or above 10 W/mL and below 100W/mL. 3 Materials that in themselves are capable of detonation or explosive decomposition or explosive reaction, but that require a strong initiating source or that must be heated under confinement before initiation. Materials that have an estimated instantaneous power density (product of heat of reaction and reaction rate) at 250°C (482°F) at or above 100 W/mL and below 1000 W/mL. Materials that are sensitive to thermal or mechanical shock at elevated temperatures and pressures. 4 Materials that in themselves are readily capable of detonation or explosive decomposition or explosive reaction at normal temperatures and pressures. Materials that are sensitive to localized thermal or mechanical shock at normal temperatures and pressures. Materials that have an estimated instantaneous power density (product of heat of reaction and reaction rate) at 250°C (482°F) of 1000 W/mL or greater. FLAMMABILITY LIMITS IN AIR: Much of the information related to fire and explosion is derived from the National Fire Protection Association (NFPA). Flash Point: Minimum temperature at which a liquid gives off sufficient vapor to form an ignitable mixture with air near the surface of the liquid or within the test vessel used. Autoignition Temperature: Minimum temperature of a solid, liquid, or gas required to initiate or cause self-sustained combustion in air with no other source of ignition. LEL: Lowest concentration of a flammable vapor or gas/air mixture that will ignite and burn with a flame. UEL: Highest concentration of a flammable vapor or gas/air mixture that will ignite and burn with a flame. TOXICOLOGICAL INFORMATION: Human and Animal Toxicology: Possible health hazards as derived from human data, animal studies, or from the results of studies with similar compounds are presented. LD50: Lethal Dose (solids & liquids) that kills 50% of the exposed animals. LC50: Lethal Concentration (gases) that kills 50% of the exposed animals. ppm: Concentration expressed in parts of material per million parts of air or water. mg/m3: Concentration expressed in weight of substance per volume of air. mg/kg: Quantity of material, by weight, administered to a test subject, based on their body weight in kg. TDLo: Lowest dose to cause a symptom. TCLo: Lowest concentration to cause a symptom. TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo: Lowest dose (or concentration) to cause lethal or toxic effects. Cancer Information: IARC: International Agency for Research on Cancer. NTP: National Toxicology Program. RTECS: Registry of Toxic Effects of Chemical Substances. IARC and NTP rate chemicals on a scale of decreasing potential to cause human cancer with rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used. Other Information: BEI: ACGIH Biological Exposure Indices, represent the levels of determinants which are most likely to be observed in specimens collected from a healthy worker who has been exposed to chemicals to the same extent as a worker with inhalation exposure to the TLV. REPRODUCTIVE INFORMATION: A mutagen is a chemical that causes permanent changes to genetic material (DNA) such that the changes will propagate through generational lines. An embryotoxin is a chemical that causes damage to a developing embryo (i.e. within the first eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical that causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance that interferes in any way with the reproductive process. ECOLOGICAL INFORMATION: EC: Effect concentration in water. BCF: Bioconcentration Factor, which is used to determine if a substance will concentrate in life forms that consume contaminated plant or animal matter. TLm: Median threshold limit. log KOW or log KOC: Coefficient of Oil/Water Distribution is used to assess a substance’s behavior in the environment. REGULATORY INFORMATION: This section explains the impact of various laws and regulations on the material. U.S.: EPA: U.S. Environmental Protection Agency. ACGIH: American Conference of Governmental Industrial Hygienists, a professional association that establishes exposure limits. OSHA: U.S. Occupational Safety and Health Administration. NIOSH: National Institute of Occupational Safety and Health, which is the research arm of OSHA. DOT: U.S. Department of Transportation. TC: Transport Canada. SARA: Superfund Amendments and Reauthorization Act. TSCA: U.S. Toxic Substance Control Act. CERCLA: Comprehensive Environmental Response, Compensation, and Liability Act. Marine Pollutant status according to the DOT; CERCLA or Superfund; and various state regulations. This section also includes information on the precautionary warnings that appear on the material’s package label. CANADA: WHMIS: Canadian Workplace Hazardous Materials Information System. TC: Transport Canada. DSL/NDSL: Canadian Domestic/Non-Domestic Substances List. GAF Safety Data Sheet SDS #2029 SDS Date: December 2014 _________________________________________________________________________ Page 1 of 8 SECTION 1: PRODUCT AND COMPANY INFORMATION Everguard® TPO Seam Cleaner N/A N/A N/A GAF 1 Campus Drive, Parsippany, NJ 07054 800–424–9300 800–766–3411 Corporate EHS Corporate EHS SECTION 2: HAZARD IDENTIFICATION NFPA and HMIS RATINGS: NFPA Hazard Rating HMIS Hazard Rating Health 2 Health 2 Flammable 3 Flammable 3 Reactive 0 Reactive 0 Special Hazards - Personal Protection X GHS LABEL ELEMENTS: GHS CLASSIFICATION: Flammable Liquid - Category 2 Eye Irritant - Category 2A Skin Irritant - Category 2 Acute Toxicity - Category 4 Target Organ (SE) - Category 3 Target Organ (RE) - Category 2 Aspiration Toxicity - Category 1 Hazardous to the Aquatic Environment - Category 2 GAF SDS # 2029 Page 2 of 8 Inhalation, Skin Absorption, Skin Contact, Eye Contact, Ingestion Can cause eye irritation. Symptoms include stinging, tearing, redness, swelling of the eyes and/or blurred vision. Can cause skin irritation. Prolonged or repeated contact may dry the skin. Symptoms may include redness, burning, and drying and cracking of skin, burns and other skin damage such as blistering. Passage of this material into the body through the skin is possible, but it is unlikely that this would result in harmful effects during safe handling and use. Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. This material can get into the lungs during swallowing or while vomiting. This results in lung inflammation and other lung injury. Breathing of vapor or mist is possible. Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. Symptoms are not expected at air concentrations below the recommended exposure limits. Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include; metallic taste, redness of the skin, stomach or intestinal upset (nausea, vomiting, diarrhea, irritation (nose, throat, airways), discomfort in the chest, central nervous system excitation (giddiness, liveliness, light-headed feeling), followed by central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness), and other central nervous system effects, temporary changes in mood and behavior, effects on memory, weakness, respiratory depression (slowing of GHS PICTOGRAMS: SIGNAL WORD: Danger HAZARD STATEMENTS: Highly flammable liquid and vapor May cause damage to organs through prolonged or repeated exposure Causes skin irritation Causes serious eye irritation May cause respiratory irritation Harmful if inhaled May be fatal if swallowed and enters airways Toxic to aquatic life with long lasting effects GAF SDS # 2029 Page 3 of 8 the breathing rate), shortness of breath, lack of coordination, confusion, irregular heartbeat, narcosis (dazed or sluggish feeling), coma, and death. CHRONIC HEALTH HAZARDS: Overexposure to this material, (or its components), has been suggested as a cause of the following effects in laboratory animals: mild, reversible liver effects, mild, reversible kidney effects, cardiac sensitization, and kidney damage. This material, (or a component), has been shown to cause birth defects in laboratory animal studies. The relevance of these findings to humans is uncertain. This material is not expected to cause cancer in humans since it did not cause cancer in laboratory animals. CARCINOGENICITY: Ethyl Benzene has been shown to cause cancer in laboratory animals. The relevance of this finding in humans is uncertain. The International Agency for Research on Cancer (IARC) has classified ethyl benzene as a possible human carcinogen. Toluene may be harmful to the human fetus based on positive test results with laboratory animals. Case studies show that prolonged intentional abuse of toluene during pregnancy can cause birth defects in humans. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Xylene 1330-20-7 >=77% 100 ppm 100 ppm REL 100 ppm Ethyl Benzene 100-41-4 >=22% 100 ppm 100 ppm REL 100 ppm SECTION 4: FIRST AID MEASRURES If symptoms develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. Remove contaminated clothing. Flush exposed areas with large amounts of water. If skin is damaged, seek immediate medical attention. If skin is not damaged and symptoms persist, seek medical attention. Launder clothing before reuse. If symptoms develop, move individual away form exposure and into fresh air. If symptoms persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warn and quiet; seek immediate medical attention. GAF SDS # 2029 Page 4 of 8 INGESTION: Seek medical attention immediately. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: Inhalation of high concentrations of this material, as could occur in enclosed spaces or during deliberate abuse, may be associated with cardiac arrhythmias. Sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed to this material. This material is an aspiration hazard. Potential danger form aspiration must be weighed against possible oral toxicity when deciding whether to induce vomiting. SECTION 5: FIRE FIGHTING PROCEDURES Dry chemical, Foam, Carbon Dioxide (CO2) Carbon dioxide and carbon monoxide, hydrocarbons Wear full fire fighting turn-out gear, (full bunker gear), and respiratory protection, (SCBA). Material is volatile and readily gives off vapors which may travel along the ground or be moved by ventilation and ignited by pilot lights, flames, sparks, heaters, smoking, electric motors, static discharge or other ignition sources at locations near the material handling pint. Never use welding or cutting torch on or near drum, (even empty), because product, (even just residue), can ignite explosively. SECTION 6: ACCIDENTAL RELEASE MEASURES Wear appropriate protective equipment as described in section 8. Eliminate all sources of ignition. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at the source. Prevent spill from spreading and entering drains, sewers, streams, or other bodies of water. If runoff occurs, notify authorities as required. Pump or vacuum transfer spilled product to clean containers for recovery. Absorb unrecoverable product. Transfer contaminated absorbent, soil and other materials to containers for disposal. SECTION 7: HANDLING AND STORAGE Containers of this material may be hazardous when emptied. Since emptied containers retain product residues, (vapors, liquid, GAF SDS # 2029 Page 5 of 8 and/or solid), all hard precautions given in the data sheet must be observed. Static ignition hazard can result from handling and use. Electrically bond and ground all containers, personnel and equipment before transfer or use of material. Special precautions may be necessary to dissipate static electricity for non- conductive containers. Use proper bonding and grounding during product transfer as described in National Fire Protection Association document NFPA 77. OTHER PRECAUTIONS: Absorb liquid of vermiculite, floor absorbent or other absorbent material. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Provide sufficient mechanical ventilation to maintain exposure below exposure limits. If workplace exposure limit(s) of product or any component is exceeded, a NIOSH-approved air supplied respirator is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH respirators, (negative pressure type), under specified conditions. Engineering or administrative controls should be implemented to reduce exposure. Chemical splash goggles. Wear resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots. N/A N/A SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Colorless liquid. Mild Aromatic odor. 79.90F / 26.660C 1.0% N/A 6.6% .86 (N-Butyl Acetate) 137.000F / 278.600C 7 -52.600F / -47.000C Negligible in water N/A GAF SDS # 2029 Page 6 of 8 VAPOR DENSITY: 3.66 (AIR=1) PERCENT VOLATILE: N/A VAPOR PRESSURE: 1.06 kPa @ 77oF / 25oC MOLECULAR WEIGHT: N/A VOC WITH WATER (LBS/GAL): 7.25 lb/gal @ 77oF / 25oC WITHOUT WATER (LBS/GAL): N/A SECTION 10: STABILITY AND REACTIVITY N/A Strong oxidizing agents. Carbon Dioxide and carbon monoxide, hydrocarbons None __________________________________________________________________________________________ SECTION 11: TOXICOLOGICAL INFORMATION Xylene LD 50 Rat: 4,300 mg/kg Ethyl Benzene LD 50 Rat: 3,500 mg/kg Ethyl Benzene LC Lo Rat: 4000 ppm, 4 h Xylene LD 50 Rabbit: > 2,000 mg/kg Ethyl Benzene LD 50 Rabbit: 15,433 mg/kg SECTION 12: ECOLOGICAL INFORMATION GAF SDS # 2029 Page 7 of 8 ECOLOGICAL INFORMATION: Aquatic toxicity Acute and Prolonged Toxicity to Fish 96 h LC 50 Rainbow trout, Donaldson trout (Oncorhynchus mykiss): 6.7 – 10 mg/1 Mortality 96 h LC 50 Fathead minnow (Pimephales promelas): 23.53 – 29.97 mg/1 Mortality Acute Toxicity to Aquatic Invertebrates 24 h LC 50 Water flea (Daphnia magna),: > 100-<1,000 mg/l Mortality __________________________________________________________________________________________ SECTION 13: DISPOSAL CONSIDERATIONS This product, as supplied, is regulated as a hazardous waste by the U.S. Environmental Protection Agency (EPA) under Resource Conservation and Recovery Act (RCRA) regulations. If discarded in its purchased form, this product is a RCRA hazardous waste. It is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or residue of the product remains classified a hazardous waste as per 40 CFR 261, Subpart C. State or local regulations may also apply if they differ from the federal regulation. D001, Ignitable Hazardous Waste SECTION 14: TRANSPORTATION INFORMATION Xylenes 3 UN 1307 III N/A Dangerous goods descriptions, (if indicated above), may not reflect package size, quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. GAF SDS # 2029 Page 8 of 8 SECTION 15: REGULATORY INFORMATION This product and its components are listed on the TSCA 8(b) inventory. N/A Fire hazard, acute health hazard, chronic health hazard Xylene 1330-20-7 77% Ethyl Benzene 100-41-4 22% This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm. Other state regulations may apply. Check individual state requirements. The following components appear on one or more of the following state hazardous substances list: Chemical Name CAS # CA MA MN PA NJ RI SECTION 16: OTHER INFORMATION N/A September 2013 Headquarters Address Change This information relates to the specific material designated and may not be valid for such material used on combination with any other materials or in any process. Such information is to the best of our knowledge and belief accurate and reliable as of the date compiled. However, no representation, warranty or guarantee, expressed or implied, is made as to its accuracy, reliability, or completeness. It is the user’s responsibility to satisfy himself as to the suitability and completeness of such information for his particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending a license of valid patents. GAF Safety Data Sheet SDS # 1079C _________________________________________________________________________ Page 1 of 13 SECTION 1: PRODUCT AND COMPANY INFORMATION EverGuard® 1121 TPO Bonding Adhesive N/A N/A GAF 1 Campus Drive, Parsippany, NJ 07054 PHONE: (CHEMTREC) 800–424–9300 INFORMATION ONLY: PREPARED BY: APPROVED BY: SECTION 2: HAZARD IDENTIFICATION NFPA and HMIS RATINGS: Rating Rating 2 Health Flammable Flammable Reactive Reactive Special Hazards - Personal Protection X GAF SDS # 1079C Page 2 of 13 GHS LABEL ELEMENTS: GHS CLASSIFICATION: Flammable Liquid - Category 2 Eye Irritant - Category 2A Skin Irritant - Category 2 Acute Toxicity - Category 4 Target Organ (SE) - Category 3 Target Organ (RE) - Category 2 Reproductive Toxicity - Category 2 ADDITIONAL HAZARD IDENTIFICATION INFORMATION: Inhalation, Skin absorption, Skin contact, Eye contact, Ingestion Can cause eye irritation. Symptoms include stinging, tearing, redness, and swelling of eyes. Skin: May cause mild skin irritation. Prolonged or repeated contact may dry the skin. Symptoms may include redness, burning, drying and GHS PICTOGRAMS: SIGNAL WORD: Danger HAZARD STATEMENTS: PRECAUTIONARY STATEMENTS: Highly flammable liquid and vapor. Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. May cause damage to organs (Neurologic: other (neuropsycho vision)) through prolonged or repeated exposure if inhaled. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. GAF SDS # 1079C Page 3 of 13 body through the skin is possible, but it is unlikely that this would result in harmful effects during safe handling and use. Ingestion: Swallowing this material is harmful. This material can get into the lungs during swallowing or vomiting. This can cause lung inflammation and other lung injury. Inhalation: Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. ACUTE HEALTH HAZARDS: Inhalation of high concentrations of this material, as could occur in enclosed spaces or during deliberate abuse, may be associated with cardiac arrhythmias. Sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed to this material. This material (or a component) has produced hyperglycemia and ketosis following substantial ingestion. Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose, throat, airways) temporary changes in mood and behavior confusion irregular heartbeat. Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure if inhaled. CHRONIC HEALTH HAZARDS: This material (or a component) shortens the time of onset or worsens the liver and kidney damage induced by other chemicals. Prolonged and repeated exposure to n-hexane may cause peripheral neuropathy by damaging peripheral nerve tissue (that of the arms and legs) and result in muscular weakness and loss of sensation. Prolonged and repeated inhalation of high levels of mixed isomers of hexane resulted in kidney damage in male rats. The effects observed are the same as those seen in male rats exposed to other hydrocarbons. The mechanism by which these chemicals cause the characteristic kidney toxicity is unique to the male rat and the kidney effects are not expected to occur in man. Prolonged intentional toluene abuse may lead to damage to many organ systems having effects on: central and peripheral nervous systems, vision, hearing, liver, kidneys, heart and blood. Such abuse has been associated with brain damage characterized by disturbances in gait, personality changes and loss of memory. Comparable central nervous system effects have not been shown to result from occupational exposure to toluene. Prolonged intentional toluene abuse may lead to hearing loss progressing to deafness. In addition, while noise is known to cause hearing loss in humans, it has been suggested that workers GAF SDS # 1079C Page 4 of 13 suffer greater hearing loss than would be expected from exposure to noise alone. Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals: mild, reversible liver effects, mild, reversible kidney effects, blood abnormalities, liver abnormalities, nasal damage, respiratory tract damage (nose, throat, and airways), spleen damage, eye damage, kidney damage, effects on hearing, testis damage, lung damage, central nervous system damage, Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans: liver abnormalities, visual impairment, kidney damage and central nervous system effects CARCINOGENICITY: Based on the available information, this material cannot be classified with regard to carcinogenicity. This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA). SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Toluene 108-88-3 30 – 40 200 ppm 300 ppm – ceiling (Petroleum), Light Aliphatic 300 ppm 96-14-0 1.5 – 5 1000 ppm - STEL 510 ppm - Ceiling 96-37-7 NE = Not Established GAF SDS # 1079C Page 5 of 13 SECTION 4: FIRST AID MEASURES If symptoms develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. SKIN: Remove contaminated clothing. Wash exposed area with soap and water. If symptoms persist, seek medical attention. Launder clothing before reuse. INHALATION: If symptoms develop, move individual away from exposure and into fresh air. If symptoms persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention. INGESTION: Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: Inhalation of high concentrations of this material, as could occur in enclosed spaces or during deliberate abuse, may be associated with cardiac arrhythmias. Sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed to this material. This material is an aspiration hazard. Potential danger from aspiration must be weighed against possible oral toxicity (see Section 11 – Toxicological Information) when deciding whether to induce vomiting. This material (or a component) has produced hyperglycemia and ketosis following substantial ingestion. SECTION 5: FIRE FIGHTING PROCEDURES Water spray, dry powder, foam, carbon dioxide (CO2). Carbon dioxide and carbon monoxide, phenols, various hydrocarbons. RECOMMENDED FIRE FIGHTING PROCEDURES: Material is volatile and readily gives off vapors which may travel along the ground or be moved by ventilation and ignited by pilot lights, flames, sparks, heaters, smoking, electric GAF SDS # 1079C Page 6 of 13 near the material handling point. Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively. Wear full firefighting turn- out gear (full Bunker gear), and respiratory protection (SCBA). UNUSUAL FIRE & EXPLOSION HAZARDS: None. SECTION 6: ACCIDENTAL RELEASE MEASURES For personal protection see section 8. Eliminate all ignition sources (flames including pilot lights, electrical sparks). Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source. Prevent from entering drains, sewers, streams or other bodies of water. Prevent from spreading. If runoff occurs, notify authorities as required. Pump or vacuum transfer spilled product to clean containers for recovery. Absorb unrecoverable product. Transfer contaminated absorbent, soil and other materials to containers for disposal. SECTION 7: HANDLING AND STORAGE Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Static ignition hazard can result from handling and use. Electrically bond and ground all containers, personnel and equipment before transfer or use of material. Special precautions may be necessary to dissipate static electricity for non-conductive containers. Use proper bonding and grounding during product transfer as described in National Fire Protection Association document NFPA 77. OTHER PRECAUTIONS: Store in closed containers in a dry, well-ventilated area. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. GAF SDS # 1079C Page 7 of 13 SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION VENTILATION: Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below TLV(s). RESPIRATORY PROTECTION: If workplace exposure limit(s) of product or any component is exceeded (see exposure guidelines), a NIOSH-approved air supplied respirator is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH respirators (negative pressure type) under specified conditions (see your industrial hygienist). Engineering or administrative controls should be implemented to reduce exposure. EYE PROTECTION: SKIN PROTECTION: Wear chemical resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots. OTHER PROTECTIVE EQUIPMENT: WORK HYGIENIC PRACTICES: Wash exposed skin prior to eating, drinking or smoking and at the end of each shift. EXPOSURE GUIDELINES: SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Liquid with a solvent odor. <0 °F / -18 °C No data Seta closed cup No data No data No data No data No data No data 0.873 g/cm3 @ 77 °F / 25 °C 7.3 lb/gal @ 77 VAPOR DENSITY: PERCENT VOLATILE: GAF SDS # 1079C Page 8 of 13 VAPOR PRESSURE: 307.96 hPa @ 77 °F / 25 °C MOLECULAR WEIGHT: No data No data No data SECTION 10: STABILITY AND REACTIVITY None known. AVOID): Acids, strong alkalis, strong mineral acids, strong oxidizing agents. HAZARDOUS DECOMPOSITION OR BY- PRODUCTS: Carbon dioxide and carbon monoxide, phenols, various hydrocarbons. HAZARDOUS POLYMERIZATION: _________________________________________________________________________________________ SECTION 11: TOXICOLOGICAL INFORMATION TOLUENE: Acute oral toxicity: LD50 (Rat, male): 5,580 mg/kg Acute inhalation toxicity: LC50 (Rat): 28.1 mg/l Exposure time: 4 h Test atmosphere: vapor Method: OECD Test Guideline 403 Acute dermal toxicity: LD50 (Rabbit): 12,267 mg/kg ACETONE: Acute oral toxicity: LD50 (Rat, female): 5,800 mg/kg Acute inhalation toxicity: LC50 (Rat, female): 76 mg/l Exposure time: 4 h Test atmosphere: vapor Acute dermal toxicity: LD50 (Rabbit): > 7,426 mg/kg GAF SDS # 1079C Page 9 of 13 N-HEXANE: Acute oral toxicity: LD50 (Rat, male and female): ca. 16 g/kg Acute inhalation toxicity: LC50 (Rat, male): > 5000 ppm Exposure time: 24 h Test atmosphere: vapor Acute dermal toxicity: LD50 (Rabbit, male and female): > 2,000 mg/kg Assessment: No adverse effect has been observed in acute dermal toxicity tests. SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC: Acute oral toxicity: LD50 (Rat): > 8,000 mg/kg Acute inhalation toxicity: LC50 (Rat): > 7,630 mg/m3 Exposure time: 4 h Test atmosphere: vapor Method: OECD Test Guideline 403 Assessment: No adverse effect has been observed in acute inhalation toxicity tests. Acute dermal toxicity: LD50 (Rat): > 4,000 mg/kg Assessment: Not classified as acutely toxic by dermal absorption under GHS. METHYL-3-PENTANE: Acute oral toxicity: LD50 (Rat): 16,000 mg/kg Remarks: Information given is based on data obtained from similar substances. Acute inhalation toxicity: LC50 (Rat): 73680 ppm Exposure time: 4 h Test atmosphere: vapour Remarks: Information given is based on data obtained from similar substances. Acute dermal toxicity: LD50 (Rabbit): 3,350 mg/kg Assessment: No adverse effect has been observed in acute dermal toxicity tests. Remarks: Information given is based on data obtained from similar substances. METHYLCYCLOPENTANE: Acute oral toxicity: LD50 (Rat): > 2,000 mg/kg Skin corrosion/irritation Causes skin irritation. Product: Remarks: May cause skin irritation and/or dermatitis. GAF SDS # 1079C Page 10 of 13 Result: Repeated exposure may cause skin dryness or cracking. Further information Product: nausea and vomiting., Concentrations substantially above the TLV value may cause SECTION 12: ECOLOGICAL INFORMATION An environmental hazard cannot be excluded in the event of unprofessional handling or disposal., Toxic to aquatic life., Harmful to aquatic life with long lasting effects. _________________________________________________________________________________________ SECTION 13: DISPOSAL CONSIDERATIONS METHOD: Dispose of in accordance with all applicable local, state and federal regulations. Contaminated packaging: Empty remaining contents. Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. SECTION 14: TRANSPORTATION INFORMATION Adhesives 3 ID NUMBER: PACKING GROUP: GAF SDS # 1079C Page 11 of 13 LABEL STATEMENT: N/A OTHER: N/A IATA PROPER SHIPPING NAME: Adhesive HAZARD CLASS: 3 ID NUMBER: UN1133 PACKING GROUP: II LABEL STATEMENT: N/A OTHER: N/A IMDG PROPER SHIPPING NAME: Adhesive HAZARD CLASS: 3 ID NUMBER: UN1133 PACKING GROUP: II LABEL STATEMENT: N/A OTHER: EMS: FE,SE SECTION 15: REGULATORY INFORMATION All components are listed on the TSCA inventory. CERCLA Hazardous Substances (40 CFR 302) Reportable Quantity – Components GAF SDS # 1079C Page 12 of 13 Acetone: 67-64-1, 5000 lbs n-Hexane: 110-54-3, 5000 lbs Cyclohexane: 110-82-7, 1000 lbs SARA: 311/312 HAZARD CATEGORIES: 313 REPORTABLE INGREDIENTS: Toluene 108-88-3 n-Hexane 110-54-3 Cyclohexane 110-82-7 CALIFORNIA PROPOSITION 65: This product contains toluene, a chemical known to the state of California to cause birth defects, or other reproductive harm. Other state regulations may apply. Check individual state requirements. The following components appear on one or more of the following state hazardous substances lists: Chemical Name CAS # CA MA MN NJ PA RI Light Aliphatic SECTION 16: OTHER INFORMATION None December 2014 Updates to Sections 2, 3., 9 and 11. GAF SDS # 1079C Page 13 of 13 This information relates to the specific material designated and may not be valid for such material used on combination with any other materials or in any process. Such information is to the best of our knowledge and belief accurate and reliable as of the date compiled. However, no representation, warranty or guarantee, expressed or implied, is made as to its accuracy, reliability, or completeness. It is the user’s responsibility to satisfy himself as to the suitability and completeness of such information for his particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending a license of valid patents. Appendix H DEQ Risk Calculators Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Worst Case Indoor Air and Sub Slab (Area C & D) North Carolina Department of Environmental Quality Risk Calculator Battery & Ignition Distribution (Ello House) Tryclan Drive and Ellenwood Place, Charlotte, NC Brownfields Redevelopment Section 23055-19-060 February 2024 November 2023 EPA RSL Table Prepared By:Hart & Hickman, PC Hart & Hickman, PC North Carolina DEQ Risk Calculator Table of Contents Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 23055-19-060 Exposure Unit ID: Worst Case Indoor Air and Sub Slab (Area C & D) Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 23055-19-060 Exposure Unit ID: Worst Case Indoor Air and Sub Slab (Area C & D) Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 17400 MP-3 67-64-1 Acetone ug/m3 2.47 MP-5 71-43-2 Benzene ug/m3 0.747 J flag, MP-5 75-15-0 Carbon Disulfide ug/m3 0.522 J flag, MP-5 67-66-3 Chloroform ug/m3 28.7 J flag, MP-3 110-82-7 Cyclohexane ug/m3 2.9 MP-DUP 75-71-8 Dichlorodifluoromethane ug/m3 1.44 J flag, MP-5 100-41-4 Ethylbenzene ug/m3 14200 MP-3 109-99-9 ~Tetrahydrofuran ug/m3 0.401 J flag, MP-5 142-82-5 Heptane, N-ug/m3 1.42 J flag, MP-5 110-54-3 Hexane, N-ug/m3 55.1 J flag, MP-3 67-63-0 Isopropanol ug/m3 79 MP-DUP 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 12.4 J flag, MP-3 75-09-2 Methylene Chloride ug/m3 0.56 J flag, MP-DUP 91-20-3 ~Naphthalene ug/m3 4.59 MP-5/MP-DUP 115-07-1 Propylene ug/m3 0.379 J flag, MP-5/MP-DUP 100-42-5 Styrene ug/m3 3.34 MP-5 108-88-3 Toluene ug/m3 0.643 J flag, MP-DUP 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 1.8 J flag, MP-5 75-69-4 Trichlorofluoromethane ug/m3 1.85 J flag, MP-5 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0.565 J flag, MP-5 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 8.26 J flag, MP-5 1330-20-7 Xylenes ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 23055-19-060 Exposure Unit ID: Worst Case Indoor Air and Sub Slab (Area C & D) Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 263 D-IAS-1 67-64-1 Acetone ug/m3 2.29 IAS-DUP 71-43-2 Benzene ug/m3 0.972 J flag, D-IAS-1 74-87-3 Chloromethane ug/m3 2.89 IAS-DUP 75-71-8 Dichlorodifluoromethane ug/m3 3.23 C-IAS-1 100-41-4 Ethylbenzene ug/m3 25.6 IAS-DUP 109-99-9 ~Tetrahydrofuran ug/m3 2.41 IAS-DUP 142-82-5 Heptane, N-ug/m3 2.58 IAS-DUP 110-54-3 Hexane, N-ug/m3 9.13 B flag, D-IAS-1 67-63-0 Isopropanol ug/m3 65.8 IAS-DUP 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 1.63 J flag, D-IAS-1 75-09-2 Methylene Chloride ug/m3 0.571 J flag, C-IAS-1 91-20-3 ~Naphthalene ug/m3 2.14 IAS-DUP 100-42-5 Styrene ug/m3 11.4 IAS-DUP 108-88-3 Toluene ug/m3 0.59 J flag, C-IAS-1 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 1.74 J flag, IAS-DUP 75-69-4 Trichlorofluoromethane ug/m3 10.3 C-IAS-1 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 2.77 IAS-DUP 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 23.9 IAS-DUP 1330-20-7 Xylenes ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 23055-19-060 Exposure Unit ID: Worst Case Indoor Air and Sub Slab (Area C & D) Receptor Pathway Carcinogenic Ris Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use* NC NC NC Soil NC NC NC Groundwater Use* NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water* NC NC NC Receptor Pathway Carcinogenic Ris Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 5.8E-07 2.3E-01 NO Indoor Air 1.6E-05 8.2E-01 NO Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: 3. NM = Not modeled, user did not check this pathway as complete. 4. NC = Pathway not calculated, required contaminant migration parameters were not entered. DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 23055-19-060 Exposure Unit ID: Worst Case Indoor Air and Sub Slab (Area C & D) CAS # Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 17400 522 - - 71-43-2 Benzene 2.47 0.0741 3.6E-01 6.3E+00 2.1E-07 2.4E-03 75-15-0 Carbon Disulfide 0.747 0.02241 - 1.5E+02 3.1E-05 67-66-3 Chloroform 0.522 0.01566 1.2E-01 2.0E+01 1.3E-07 1.5E-04 110-82-7 Cyclohexane 28.7 0.861 - 1.3E+03 1.4E-04 75-71-8 Dichlorodifluoromethane 2.9 0.087 - 2.1E+01 8.3E-04 100-41-4 Ethylbenzene 1.44 0.0432 1.1E+00 2.1E+02 3.8E-08 4.1E-05 109-99-9 ~Tetrahydrofuran 14200 426 - 4.2E+02 2.0E-01 142-82-5 Heptane, N- 0.401 0.01203 - 8.3E+01 2.9E-05 110-54-3 Hexane, N- 1.42 0.0426 - 1.5E+02 5.8E-05 67-63-0 Isopropanol 55.1 1.653 - 4.2E+01 7.9E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone) 79 2.37 - 1.0E+03 4.5E-04 75-09-2 Methylene Chloride 12.4 0.372 1.0E+02 1.3E+02 3.7E-09 5.9E-04 91-20-3 ~Naphthalene 0.56 0.0168 8.3E-02 6.3E-01 2.0E-07 5.4E-03 115-07-1 Propylene 4.59 0.1377 - 6.3E+02 4.4E-05 100-42-5 Styrene 0.379 0.01137 - 2.1E+02 1.1E-05 108-88-3 Toluene 3.34 0.1002 - 1.0E+03 1.9E-05 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 0.643 0.01929 - 1.0E+03 3.7E-06 75-69-4 Trichlorofluoromethane 1.8 0.054 - - 95-63-6 Trimethylbenzene, 1,2,4- 1.85 0.0555 - 1.3E+01 8.9E-04 108-67-8 Trimethylbenzene, 1,3,5- 0.565 0.01695 - 1.3E+01 2.7E-04 1330-20-7 Xylenes 8.26 0.2478 - 2.1E+01 2.4E-03 Cumulative: 5.8E-07 2.3E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 23055-19-060 Exposure Unit ID: Worst Case Indoor Air and Sub Slab (Area C & D) CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 263 - - 71-43-2 Benzene 2.29 3.6E-01 6.3E+00 6.4E-06 7.3E-02 74-87-3 Chloromethane 0.972 - 1.9E+01 1.0E-02 75-71-8 Dichlorodifluoromethane 2.89 - 2.1E+01 2.8E-02 100-41-4 Ethylbenzene 3.23 1.1E+00 2.1E+02 2.9E-06 3.1E-03 109-99-9 ~Tetrahydrofuran 25.6 - 4.2E+02 1.2E-02 142-82-5 Heptane, N- 2.41 - 8.3E+01 5.8E-03 110-54-3 Hexane, N- 2.58 - 1.5E+02 3.5E-03 67-63-0 Isopropanol 9.13 - 4.2E+01 4.4E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone) 65.8 - 1.0E+03 1.3E-02 75-09-2 Methylene Chloride 1.63 1.0E+02 1.3E+02 1.6E-08 2.6E-03 91-20-3 ~Naphthalene 0.571 8.3E-02 6.3E-01 6.9E-06 1.8E-01 100-42-5 Styrene 2.14 - 2.1E+02 2.1E-03 108-88-3 Toluene 11.4 - 1.0E+03 2.2E-03 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 0.59 - 1.0E+03 1.1E-04 75-69-4 Trichlorofluoromethane 1.74 - - 95-63-6 Trimethylbenzene, 1,2,4- 10.3 - 1.3E+01 1.6E-01 108-67-8 Trimethylbenzene, 1,3,5- 2.77 - 1.3E+01 4.4E-02 1330-20-7 Xylenes 23.9 - 2.1E+01 2.3E-01 Cumulative: 1.6E-05 8.2E-01 All concentrations are in ug/m3 Output Form 3C ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator