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HomeMy WebLinkAbout18038_AquairII_VI Evaluation_ West Side_20230613 Via Email June 13, 2023 North Carolina Department of Environmental Quality Division of Waste Management – Brownfields Program 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Attn: Ms. Carolyn Minnich Re: Vapor Intrusion Evaluation – Proposed Southern Building AquAir II Brownfields Site - West Side 13300 Sam Neely Road Charlotte, North Carolina Brownfields Project No. 18038-14-060 H&H Job No. TKC-008 Dear Carolyn: 1.0 Introduction On behalf of TKC CCCX, LLC (the current property owner), Hart & Hickman, PC (H&H) has prepared this letter to evaluate the need for vapor intrusion mitigation measures for the proposed southern warehouse building on the west side of the AquAir II Brownfields property (Brownfields Project No. 18038-14-060) located in the 13300 Sam Neely Road in Charlotte, Mecklenburg County, North Carolina (the Site). The Brownfields agreement for the AquaAir II property includes two contiguous parcels, totaling approximately 154 acres, which are separated by the Southern Railway tracks. The subject Site consists of the portion of the Brownfields property to the west of the railway, which is an approximately 80-acre parcel (Mecklenburg County Parcel ID 20141101). The portion of the Brownfields property to the east of the railroad tracks was previously redeveloped with a warehouse building for Staples, Inc. in 2017/2018 and is currently owned by Gear 3725 Westinghouse LLC. A Site location map is provided as Figure 1. Ms. Carolyn Minnich #C-1269 Engineering June 13, 2023 #C-254 Geology Page 2 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/the keith corporation (tkc)/2021 new building/building 2/18038- vi evaluation_ west side.doc Redevelopment at the Site is being completed in two phases. The first phase of redevelopment includes construction of one industrial warehouse building, a guardhouse, a fire pumphouse, associated outdoor storage areas, roadways and parking, and a railroad extension which are nearing completion in the northern portion of the Site (referred to herein at the “northern warehouse building”). The Site is being prepared for the second phase of redevelopment which will include construction of a second industrial warehouse building, located in the southern portion of the Site and to the south of the future Carowinds Boulevard (referred to herein as the “southern warehouse building”). The two industrial warehouse footprints and associated roadways and parking areas are depicted on Figure 2. As shown on Figure 2, the northern warehouse building, which is nearing completion, was constructed within the “Limits of Groundwater Contamination” and the “Area of Possible Soil Contamination”, as identified on the Brownfields Agreement recorded for the Brownfields property. Due to the proximity to the identified areas of potential soil and groundwater contamination, a vapor intrusion mitigation system was installed in the northern warehouse building in accordance with the DEQ-approved Vapor Intrusion Mitigation Plan dated March 16, 2022. Land Use Restriction “h.” in the Notice of Brownfields Property for the agreement indicates that that no building may be constructed on the property unless DEQ determines in writing that the building would be sufficiently distant from the property’s known soil or groundwater contamination or a plan for vapor mitigation is approved and implemented. The southern warehouse building will be constructed outside of the identified soil and groundwater contamination areas. H&H has prepared this letter to evaluate whether vapor intrusion mitigation controls are warranted for the southern warehouse building in accordance with the Brownfields agreement. A brief discussion of Site conditions and historical sampling in the vicinity of the proposed southern warehouse building is included below. Ms. Carolyn Minnich #C-1269 Engineering June 13, 2023 #C-254 Geology Page 3 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/the keith corporation (tkc)/2021 new building/building 2/18038- vi evaluation_ west side.doc 2.0 Vapor Intrusion Evaluation To evaluate the planned southern warehouse building in relation to the soil and groundwater impacts, H&H compared the proposed building plan, the location of the volatile organic compound (VOC) groundwater plume, the location of the potential soil impacts, and historical groundwater and soil gas analytical data in the vicinity of the planned building. A figure depicting the proposed development in relation to the known areas of soil and groundwater impacts is attached as Figure 2. In addition, tabular summaries of the historical groundwater and soil gas data from sample locations near the southern warehouse building are also attached. Note, the monitoring wells discussed below were abandoned prior to construction of the northern warehouse building with DEQ Brownfields concurrence or were temporary monitoring wells. 2.1 Historical Sampling Activities In 1992, as part of Remedial Site Investigation activities, shallow groundwater monitor wells MW-1 through MW-10 were installed at the Site. Groundwater monitor wells MW-4, MW-5, MW-6, and MW-7 were located along the southern portion of Limits of Groundwater Contamination, which was delineated during later Site activities, and the closest groundwater sample locations to the proposed southern warehouse building. The groundwater monitor wells were first sampled in March 1992, and analytical results indicate that no compounds were detected above the North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02L.0202 Ground Water Quality Standards (2L Standards) with the exception of carbon tetrachloride, tetrachloroethene (PCE), and trichloroethene (TCE) in monitor well MW-6, and methylene chloride, a common laboratory contaminant, in MW-7. Monitor well MW-6 is located downgradient of the former Site operations and away from the proposed southern warehouse. Neither PCE nor TCE were detected in wells MW-4, MW-5, and MW-7 during the 1992 event and no other compounds were detected above the 2L Standards. A Remedial Action Plan (RAP) was prepared for the Site in December 2003 in which a pump and treat system was proposed to address shallow groundwater impacts and a RAP Amendment was submitted in April 2004 to modify the stages of the proposed remedies. In accordance with Ms. Carolyn Minnich #C-1269 Engineering June 13, 2023 #C-254 Geology Page 4 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/the keith corporation (tkc)/2021 new building/building 2/18038- vi evaluation_ west side.doc the RAP and RAP Amendment, groundwater sampling was completed for the Site between 2004 and 2011. Monitor wells MW-4, MW-5, and MW-6 were sampled in 2004, 2005, and 2011, and analytical results from each event indicate that neither PCE nor TCE were detected in the monitor wells during the sampling events. Tabular summaries of historical groundwater analytical results from previous reports are included as Appendix A. In December 2015, Terracon completed soil, groundwater, and soil vapor assessment at the Site and results of the assessment activities indicated that low levels of PCE and TCE were detected in monitoring well MW-5 below what is now the southeast corner of the northern warehouse building. The detected PCE and TCE concentrations in MW-5 exceeded the 2L Standards and are shown on Figure 2. Terracon also installed four soil gas monitoring points, SV-01 through SV-04, for collection of soil gas samples along the southwestern boundary of the soil and groundwater impacts. Soil gas analytical results indicated that no compounds were detected above the DEQ Non-Residential Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs) dated January 2023, and neither PCE nor TCE were detected in the soil gas samples. Tabular summaries of the groundwater and soil gas analytical results from the Terracon report are included in Appendix A. In January 2016, H&H conducted additional groundwater and soil vapor assessment activities south of MW-5 to evaluate groundwater conditions and the potential for soil vapor concerns in the southern portion of the site. The co-located temporary groundwater monitoring wells (TMW-1 through TMW-3) and soil gas monitoring point locations (VMP-1 through VMP-3) were installed at successive, approximately 200 to 250 ft distances between monitoring well MW-5 and the southern Site boundary. In addition, H&H collected one groundwater sample from existing Site monitor well MW-6 located east of what is now the northern warehouse building. Note that direct-push technology drilling refusal was encountered at proposed wells TMW-1 and TMW-2, therefore no groundwater samples were collected at those locations. Ms. Carolyn Minnich #C-1269 Engineering June 13, 2023 #C-254 Geology Page 5 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/the keith corporation (tkc)/2021 new building/building 2/18038- vi evaluation_ west side.doc 2.2 Groundwater Sampling Analytical Results A tabular summary of groundwater sample analytical results for previous monitor wells located near the southern warehouse building sampled by H&H in 2016 is presented in Table 1. The groundwater data is compared to the 2L Standards and the DEQ Non-Residential Vapor Intrusion Groundwater Screening Levels (GWSLs) dated January 2023. A discussion of the analytical results is presented below. Analytical results of the groundwater sample collected from existing monitor well MW-6, located in the northeastern portion of the Site and downgradient of MW-5, indicate that several VOCs were detected above the laboratory method detection limit. PCE (38 µg/L), and TCE (8.2 µg/L) were detected at concentrations exceeding the 2L Standards of 0.7 µg/L and 3.0 µg/L, respectively. Additionally, the TCE concentration exceeds the Non-Residential GWSL of 4.4. No other compounds were detected above the 2L Standards or GWSLs in monitor well MW-6. Analytical results of the groundwater sample collected from temporary monitoring well TMW-3, along the southern Site boundary, indicate that no VOCs were detected above the 2L Standards or the GWSLs. Neither PCE nor TCE were detected above the laboratory method detection limit in the TMW-3 groundwater sample. The groundwater analytical results are consistent with the Limits of Groundwater Contamination as defined in the Brownfields Agreement. Groundwater flow direction is generally to the northeast, and groundwater impacts are limited to the northeastern portion of the Site. Therefore, the groundwater impacts are not located in proximity to the proposed warehouse building in the southern portion of the Site, and groundwater does not flow from the area of groundwater impacts toward the southern warehouse building. 2.3 Soil Gas Sampling Analytical Results A tabular summary of the soil gas sample analytical results collected during the January 2016 assessment is presented in Table 2. The soil gas analytical data is compared to the DEQ Non- Ms. Carolyn Minnich #C-1269 Engineering June 13, 2023 #C-254 Geology Page 6 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/the keith corporation (tkc)/2021 new building/building 2/18038- vi evaluation_ west side.doc Residential Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs) dated January 2023. A discussion of the analytical results is presented below. Analytical results for the soil gas samples indicate that several VOCs including PCE were detected above laboratory reporting limits in each sample. However, no compound concentrations were detected above SGSLs. The highest PCE concentration (20 µg/m3) was detected in VMP-1 which is the most northern sample location and the furthest distance from the proposed southern building. The PCE concentrations indicate a decreasing trend toward the south and away from the impacted groundwater source area. TCE was not detected above laboratory reporting limits in any of the three soil gas samples. 2.4 Vapor Intrusion Evaluation The DEQ Vapor Intrusion SGSLs are conservative and based on a lifetime incremental cancer risk (LICR) of 1 x 10-6 and a hazard quotient (HQ) of 0.2 for potential non-carcinogenic risks. The DEQ and EPA acceptable risk level for potential carcinogenic risks is a cumulative LICR of 1 x 10-4 or less, and the acceptable level for non-carcinogenic risks is a cumulative HI of 1.0 or less. The HI is the sum of hazard quotients (HQs) for each target analyte detected in a sample. To further evaluate soil gas concentrations, H&H utilized the DEQ Risk Calculator (January 2023) to calculate potential vapor intrusion risks for the southern part of the Site. H&H modeled a worst-case scenario by using the highest concentrations of any compound detected in any soil gas sample collected during the January 2016 assessment. Based on the planned uses of the proposed southern warehouse building, H&H calculated risks assuming a non-residential use scenario. A copy of the completed DEQ Risk Calculator is provided in Appendix A. The non-residential worst-case risk calculation for the southern part of the Site using the 2016 soil gas data indicates a calculated cumulative LICR of 1.6 x 10-7 and a HI value of 0.014. The calculated cumulative LICR and HI values are within the acceptable levels established by the DEQ and EPA. Thus, the soil gas analytical results and risk calculations indicate that vapor Ms. Carolyn Minnich #C-1269 Engineering June 13, 2023 #C-254 Geology Page 8 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/the keith corporation (tkc)/2021 new building/building 2/18038- vi evaluation_ west side.doc Attachments: Table 1 Summary of Groundwater Analytical Data Table 2 Summary of Soil Gas Analytical Data Figure 1 Site Location Map Figure 2 Site and Sample Location Map Appendix A Historical Groundwater and Soil Gas Analytical Results Appendix B DEQ Risk Calculator Table 1 Summary of Groundwater Analytical Data AquAir II Brownfields Site - West Side Charlotte, North Carolina H&H Job No. TKC-008 We l l I D Sa m p l e D a t e Ch l o r o f o r m 1, 1 - D i c h l o r o e t h a n e 1, 1 - D i c h l o r o e t h y l e n e ci s - 1 , 2 - D i c h l o r o e t h y l e n e Te t r a c h l o r o e t h y l e n e Tr i c h l o r o e t h y l e n e Ch r o m i u m Va n a d i u m Zi n c MW-6 1/20/2016 <0.22 0.79 J 1.4 0.78 J 38 8.2 <0.89 <3.7 <6.6 TMW-3 1/20/2016 0.25 J <0.16 <0.21 <0.15 <0.17 <0.20 NA NA NA 70 6 350 70 0.7 3 10 7 1,000 3.6 33 160 210 48 4.4 NE NE NE Notes: 1) North Carolina Department of Environmental Quality (DEQ) 15A North Carolina Administrative Code 02L.0202 Groundwater Quality Standard (2L Standard) dated April 2022. 2) DEQ Non-Residential Vapor Intrusion Groundwater Screening Levels (GWSLs) (January 2023). Concentrations are reported in micrograms per liter (µg/L). Compound concentrations are reported to the laboratory method detection limits. Laboratory analytical method is shown in parentheses. Only compounds detected above laboratory method detection limits in at least one sample are shown in this table Bold values indicate an exceedance of the NC 2L Standard . Underlined values indicate an exceedance of the DEQ Non-Residential GWSL. VOC = volatile organic compound; NA = Not Analyzed; NE = Not Established J = Compound was detectedabove the laboratory method detection limit, but below the laboratory reporting limit resulting in a laboratory estimated concentration. Non-Residential GWSL2 VOCs (8260B) (µg/L) NC 2L Groundwater Standard(1) Metals (6010) (µg/L) https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/McGrath - MGR/MGR-002/Tables/McGrath GW TableFile Table 1 (Page 1 of 1) Hart & Hickman, PC Table 2 Summary of Soil Gas Analytical Data AquAir II Brownfields Site - West Side Charlotte, North Carolina H&H Job No. TKC-008 Ac e t o n e Be n z e n e 2- B u t a n o n e ( M E K ) Ca r b o n D i s u l f i d e Ca r b o n T e t r a c h l o r i d e Ch l o r o f o r m Ch l o r o m e t h a n e Cy c l o h e x a n e Dic h l o r o d i f l u o r o m e t h a n e 1. 2 - D i c h l o r o p r o p a n e Et h a n o l Et h y l b e n z e n e 4- E t h y l t o l u e n e He p t a n e He x a n e Me t h y l e n e C h l o r i d e Pr o p e n e ( P r o p y l e n e ) St y r e n e Te t r a c h l o r o e t h e n e ( P C E To l u e n e Tr i c h l o r o f l u o r o m e t h a n e 1, 1 , 2 - T r i c h l o r o - 1 , 2 , 2 - tr i f l u o r o e t h a n e 1, 2 , 4 - T r i m e t h y l b e n z e n e 1, 3 , 5 - T r i m e t h y l b e n z e n e Xy l e n e , m - & p - Xy l e n e , o - VMP-1 01/20/16 TO-15 22 15 1.8 2.9 0.53 <0.98 1.00 <0.69 1.7 <0.92 9.1 31 3.8 27 24 3.3 290 0.36 20 240 2.5 0.64 15 2.1 130 39 VMP-2 01/20/16 TO-15 170 8.9 15 7.2 <1.3 0.23 <0.83 4.9 2.2 5.0 <15 9.9 1.7 550 20 1.1 520 0.65 2.6 700 2.7 0.49 3.1 1.0 30 10 VMP-3 01/20/16 TO-15 11 1.0 1.0 <6.2 0.45 <0.98 1.4 2.8 1.6 <0.92 <15 4.4 0.29 510 2.0 1.6 27 <0.85 0.46 450 1.5 0.58 0.79 0.24 15 4.0 NE 160 440,000 61,000 200 53 7,900 530,000 8,800 330 NE 490 NE 35,000 61,000 53,000 260,000 88,000 3,500 440,000 NE 440,000 5,300 5,300 8,800 8,800 Notes: 1) DEQ Non-Residential Vapor Intrusion Sub-Slab and Exertior Soil Gas Screening Levels (SGSLs) dated January 2023. Concentrations are reported in micrograms per cubic meter (µg/m3). Compound concentrations are reported to the laboratory reporting limits. Non-Residential SGSL(1) Sa m p l e I D Sa m p l i n g D a t e An a l y t i c a l M e t h o d µg/m https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/McGrath - MGR/MGR-002/Tables/McGrath GW Table Table 1 (Page 1 of 1) Hart & Hickman, PC BROWNFIELDS PROPERTY 0 2000 4000 APPROXIMATE SCALE IN FEET N U.S.G.S. QUADRANGLE MAP QUADRANGLE 7.5 MINUTE SERIES (TOPOGRAPHIC) CHARLOTTE WEST, NORTH CAROLINA, 1996 TITLE PROJECT SITE LOCATION MAP AQUAIR II BROWNFIELDS SITE - WEST SIDE 13300 SAM NEELY ROAD CHARLOTTE, NORTH CAROLINA DATE: JOB NO: REVISION NO: FIGURE: 10-28-21 0 1TKC-008 SITE BOUNDARY CR L L L L L L L L L L L L L L L L L L L L L FD EF L CRCR CR VMP-3 VMP-2 VMP-1 TMW-3 TMW-2 TMW-1DRY DRY MW-5 MW-6 MW-7 MW-4 SV-01 SV-02 SV-03 SV-04 SV-04 (μg/m3)12/15/15PCENDTCEND REVISION NO. 0 JOB NO. TKC-008 DATE: 6-13-23 FIGURE NO. 2 AQUAIR II BROWNFIELDS SITE - WEST SIDE 13300 SAM NEELY ROAD CHARLOTTE, NORTH CAROLINA SITE AND SAMPLE LOCATION MAP 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology LEGEND BROWNFIELDS PROPERTY BOUNDARY SITE BOUNDARY LIMITS OF GROUNDWATER CONTAMINATION RAILROAD TRACKS SURFACE WATER FEATURE FENCE LINE COMPLETED NORTHERN BUILDING FOOTPRINT PROPOSED SOUTHERN BUILDING FOOTPRINT AREA OF POSSIBLE SOIL CONTAMINATION GROUNDWATER MONITORING WELL TEMPORARY GROUNDWATER MONITORING WELL TEMPORARY SOIL GAS MONITORING POINT INFERRED GROUNDWATER FLOW DIRECTION SAM NEELY ROAD ALRO STEEL CORP. (12933 SAM NEELY ROAD) LAZY OAK LANE RESIDENTIALRESIDENTIAL TEXAS PIPE & SUPPLY CO. (12910 SAM NEELY ROAD) EXISTING STAPLES WAREHOUSE BUILDING STORMWATER MANAGEMENT POND SOURCES 1.SITE PLAN PROVIDED BY BURTON ENGINEERING. FUTURE CAROWINDS BOULEVARD TMW-3 (μg/L) 1/20/16 PCE ND TCE ND VMP-3 (μg/m3) 1/20/16 PCE 0.46 TCE ND VMP-2 (μg/m3) 1/20/16 PCE 2.6 TCE ND VMP-1 (μg/m3) 1/20/16 PCE 20 TCE ND SAMPLE DATE NOTES: 1.GROUNDWATER CONCENTRATIONS REPORTED IN MICROGRAMS PER LITER (μg/L) AND SOIL GAS CONCENTRATIONS REPORTED IN MICROGRAMS PER CUBIC METER (μg/m3). 2.PCE = TETRACHLOROETHENE TCE = TRICHLOROETHENE 3.BOLD INDICATES CONCENTRATION EXCEEDS NORTH CAROLINA DEQ 15A NCAC 02L.0202 GROUNDWATER STANDARD (2L STANDARDS) 4.UNDERLINE INDICATES CONCENTRATION EXCEEDS NON-RESIDENTIAL GROUNDWATER SCREENING LEVEL. 5.MW-5 GROUNDWATER SAMPLE COLLECTED BY TERRACON ON DECEMBER 22, 2015. MW-6 (μg/L) 1/20/16 PCE 38 TCE 8.2 MW-5 (μg/L) 12/22/15 PCE 69.1 TCE 4.9 MW-6 1/20/16 PCE 38 TCE 8.2 COMPOUND CONCENTRATION (SEE NOTE 1) SAMPLE ID MW-7 (μg/L) 9/29/92 PCE ND TCE ND MW-4 3/2/05 PCE ND TCE ND SV-04 (μg/m3) 12/15/15 PCE ND TCE ND SV-01 (μg/m3) 12/15/15 PCE ND TCE ND SV-02 (μg/m3) 12/15/15 PCE ND TCE ND SV-03 (μg/m3) 12/15/15 PCE ND TCE ND Appendix A Historical Groundwater and Soil Gas Analytical Results Contaminant of Concern To t a l V o l a t i l e O r g a n i c Co m p o u n d s Sample ID Date Collected (m/dd/yy)mg/L 15A NCAC 2L Groundwater Stds. or IMAC *0.0006 *NS 1,2 d i c h l o r o b e n z e n e Na p h t h a l e n e Me r c u r y mg/l 0.02 mg/l 0.006 Th a l l i u m mg/L 0.0002 mg/l 0.001 Se l e n i u m mg/L mg/L 0.02 Ma n g a n e s e mg/L 0.05 mg/L 0.1 Nic k e l Sil v e r mg/L 0.015 Le a d 0.020.7 Co p p e r mg/L 1.0 Ba r i u m mg/L 0.01 mg/L Ch r o m i u m mg/l mg/l 0.001 0.004 mg/L 0.01 mg/L 1.0 Va n a d i u m mg/L 0.0003 Zi n c mg/L Be r y l l i u m mg/L 0.002 Vin y l c h l o r i d e mg/L 0.00003 An t i m o n y Ars e n i c Ca d m i u m 0.003 To l u e n e mg/L 0.6 1,1 , 1 - T r i c h l o r o e t h a n e mg/L 0.2 1,1 , 2 - T r i c h l o r o e t h a n e mg/L Tri c h l o r o e t h e n e 1,1 , 2 , 2 - T e t r a c h l o r o e t h a n e mg/L 0.0002 Te t r a c h l o r o e t h e n e mg/L 0.0007 To t a l 1 , 2 - D i c h l o r o e t h e n e mg/L 0.06 Me t h y l e n e c h l o r i d e mg/L 0.005 1,2 - D i c h l o r o e t h a n e mg/L 0.0004 1,1 - D i c h l o r o e t h e n e mg/L 0.007 Ch l o r o f o r m mg/L 0.07 1,1 - D i c h l o r o e t h a n e mg/L 0.0060.0003 mg/L Ca r b o n t e t r a c h l o r i d e Ch l o r o b e n z e n e mg/L 0.05 Be n z e n e mg/L 0.001 2- B u t a n o n e ( M E K ) mg/L 4 Analytical Method Table 3 Summary of Historical Groundwater Sampling Result AquaAi Incident # 074511361 EPA Method 8260 EPA Method 8270 EPA Method 245.1 EPA Method 3010 DW-2 06/04/04 ND ND 1.500 ND 0.680 ND ND 0.160 0.130 0.220 ND 0.800 ND ND ND 0.420 0.42 J 4.33 NA NA NA NA ND NA 0.078 ND NA NA NA NA NA NA NA NA 0.0035 J NA J 09/14/04 ND ND 0.420 ND 0.210 ND ND 0.060 0.062 ND ND 0.380 ND ND ND 0.490 ND 1.622 NA NA NA NA ND NA 0.08 ND NA NA NA NA NA NA NA NA ND NA 12/13/04 ND ND 0.880 ND 0.510 0.0052 0.019 0.120 0.120 ND 0.011 0.770 ND ND ND 0.840 ND 3.2752 NA NA NA NA ND NA 0.079 ND NA NA NA NA NA NA NA NA ND NA 03/03/05 ND ND 0.990 ND 0.430 ND 0.035 0.087 0.066 0.140 ND 0.610 ND ND ND 0.490 ND 2.848 NA NA NA NA ND NA 0.072 ND NA NA NA NA NA NA NA NA ND NA 09/27/05 ND ND 2.400 ND 1.000 0.018 0.028 0.240 0.160 0.320 0.011 1.300 0.013 0.031 ND 1.300 ND 6.821 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 03/02/06 ND ND 0.580 ND 0.400 ND 0.014 0.110 0.089 ND 0.012 0.920 ND ND ND 0.630 ND 2.755 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 09/21/06 ND ND 0.680 ND 0.400 ND 0.017 0.110 0.130 ND 0.012 0.850 ND ND ND 0.710 ND 2.909 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA DW-3 06/04/04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0 NA NA NA NA 0.011 NA 1.2 0.0028 NA NA NA NA NA NA NA NA 0.076 NA 12/13/04 NS ND NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 0 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA DW-4 06/04/04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.020 ND 0.02 NA NA NA NA ND NA 0.11 ND NA NA NA NA NA NA NA NA 0.0091 NA 09/14/04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.016 ND 0.016 NA NA NA NA ND NA 0.1 ND NA NA NA NA NA NA NA NA 0.0068 NA 12/14/04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.0044 ND 0.0044 NA NA NA NA ND NA 0.098 ND NA NA NA NA NA NA NA NA 0.0062 NA 03/03/05 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0 NA NA NA NA ND NA 0.13 ND NA NA NA NA NA NA NA NA 0.013 NA 09/28/05 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.0062 ND 0.0062 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 03/02/06 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.0018 ND 0.0018 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 09/21/06 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.0010 ND 0.001 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA DW-4 09/14/04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.011 ND 0.011 NA NA NA NA ND NA 0.094 ND NA NA NA NA NA NA NA NA 0.0075 NA Duplicate MW-1 06/04/04 ND ND 0.190 ND 0.290 0.011 0.013 0.013 0.020 ND 0.0085 0.078 ND 0.0075 0.002 0.140 ND 0.773 NA NA NA NA ND NA 0.2 ND NA NA NA NA NA NA NA NA 0.021 NA 09/10/04 ND ND 0.220 ND 0.400 0.019 0.012 0.012 0.033 ND 0.022 0.120 ND 0.012 ND 0.210 ND 1.06 NA NA NA NA ND NA 0.15 ND NA NA NA NA NA NA NA NA 0.0087 NA 12/13/04 ND ND 0.270 ND 0.240 0.01 0.015 0.016 0.019 ND 0.011 0.110 ND 0.02 ND 0.110 ND 0.821 NA NA NA NA ND NA 0.15 ND NA NA NA NA NA NA NA NA 0.015 NA 03/02/05 ND ND 0.080 ND 0.074 0.0038 0.018 0.0057 0.0044 ND 0.058 0.059 ND ND ND 0.052 ND 0.3549 NA NA NA NA ND NA 0.3 ND NA NA NA NA NA NA NA NA 0.04 NA 09/28/05 ND ND 0.600 ND 0.580 0.035 0.019 0.046 0.0518 ND 0.045 0.320 ND 0.034 0.0056 0.360 ND 2.0964 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 03/02/06 ND ND 0.720 ND 0.310 0.013 0.016 0.034 0.0240 ND 0.0045 0.180 ND 0.061 0.0023 0.180 ND 1.5448 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 09/21/06 ND ND 0.029 ND 0.016 ND ND 0.0011 0.0011 ND ND 0.0081 ND 0.0027 ND 0.0086 ND 0.0666 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 07/28/11 ND ND 0.0725 ND 0.246 0.0035 0.0129 ND 0.0045 ND ND 0.0639 ND 0.002 0.0037 0.0231 ND 0.4321 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA MW-1 09/10/04 ND ND 0.200 ND 0.350 0.018 0.013 0.012 0.032 ND 0.021 0.110 ND 0.012 ND 0.170 ND 0.938 NA NA NA NA ND NA 0.31 ND NA NA NA NA NA NA NA NA 0.058 NA Duplicate MW-2 06/04/04 ND ND 0.100 ND 0.053 ND ND 0.073 ND ND 0.01 1.100 ND 0.011 ND 0.066 ND 1.413 NA NA NA NA ND NA 0.13 ND NA NA NA NA NA NA NA NA 0.003 J NA J 09/13/04 ND ND ND ND 0.064 ND ND 0.082 ND ND ND 1.500 ND ND ND 0.077 ND 1.723 NA NA NA NA ND NA 0.13 ND NA NA NA NA NA NA NA NA ND NA 12/13/04 ND ND 0.110 ND 0.056 ND ND 0.042 ND ND ND 1.300 ND ND ND 0.061 ND 1.569 NA NA NA NA ND NA 0.12 ND NA NA NA NA NA NA NA NA ND NA 03/03/05 ND ND 0.170 ND 0.057 ND ND 0.090 ND ND ND 1.900 ND ND ND ND ND 2.217 NA NA NA NA ND NA 0.09 ND NA NA NA NA NA NA NA NA 0.017 NA 09/28/05 ND ND 0.110 ND 0.045 ND ND 0.050 ND ND ND 0.980 ND ND ND 0.088 ND 1.273 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 03/02/06 ND ND 0.081 ND 0.053 ND ND 0.031 ND ND ND 1.500 ND ND ND 0.078 ND 1.743 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 09/21/06 ND ND 0.070 ND 0.051 ND ND 0.029 ND ND ND 1.400 ND ND ND 0.110 ND 1.66 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 07/28/11 ND ND 0.0025 ND 0.0081 ND ND 0.0128 ND ND ND 0.164 ND ND ND 0.0248 ND 0.2122 ND ND ND ND 0.0067 ND NA ND 0.0175 ND ND 0.785 0.0231 ND ND ND NA 0.0251 MW-3 06/04/04 ND ND 0.180 ND 0.310 ND ND 0.130 ND ND 0.095 0.670 ND ND ND 0.083 ND 1.468 NA NA NA NA ND NA 0.22 ND NA NA NA NA NA NA NA NA 0.008 NA 09/13/04 ND ND 0.110 ND 0.200 ND ND 0.140 ND ND 0.055 0.600 ND ND ND 0.063 ND 1.168 NA NA NA NA ND NA 0.48 ND NA NA NA NA NA NA NA NA 0.14 NA 12/13/04 ND ND 0.061 ND 0.140 ND 0.0071 0.110 ND ND 0.02 0.580 ND 0.0086 ND 0.045 ND 0.9717 NA NA NA NA ND NA 0.24 ND NA NA NA NA NA NA NA NA 0.027 NA 03/03/05 ND ND 0.060 ND 0.130 ND 0.019 0.130 ND ND 0.018 0.660 ND 0.010 ND 0.044 ND 1.071 NA NA NA NA ND NA 0.14 ND NA NA NA NA NA NA NA NA 0.015 NA 09/28/05 ND ND 0.120 ND 0.190 ND 0.0090 0.160 ND ND 0.046 0.760 ND ND ND 0.068 ND 1.353 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 03/02/06 ND ND 0.024 ND 0.091 ND 0.0045 0.053 ND ND 0.0010 0.250 ND 0.0029 ND 0.026 ND 0.4524 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 09/21/06 ND ND 0.026 ND 0.094 ND 0.0057 0.021 ND ND 0.011 0.220 ND ND ND 0.020 ND 0.3977 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 07/28/11 ND ND ND ND 0.0036 ND ND 0.001 ND ND ND 0.0031 ND ND ND 0.0018 ND 0.0095 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA MW-4 06/03/04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0 NA NA NA NA ND NA 0.098 ND NA NA NA NA NA NA NA NA 0.011 NA 09/10/04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0 NA NA NA NA ND NA 0.13 ND NA NA NA NA NA NA NA NA 0.013 NA 12/14/04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0 NA NA NA NA ND NA 0.12 ND NA NA NA NA NA NA NA NA 0.013 NA 03/02/05 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0 NA NA NA NA ND NA 0.35 ND NA NA NA NA NA NA NA NA 0.044 NA MW-5 06/03/04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0 NA NA NA NA ND NA 0.14 ND NA NA NA NA NA NA NA NA 0.0095 NA 09/14/04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0 NA NA NA NA ND NA 0.44 ND NA NA NA NA NA NA NA NA 0.048 NA 12/14/04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0 NA NA NA NA ND NA 0.21 ND NA NA NA NA NA NA NA NA 0.015 NA 03/02/05 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0 NA NA NA NA ND NA 0.54 ND NA NA NA NA NA NA NA NA 0.14 NA MW-6 06/04/04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0 NA NA NA NA ND NA 0.11 ND NA NA NA NA NA NA NA NA 0.0089 NA 09/14/04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0 NA NA NA NA ND NA 0.19 ND NA NA NA NA NA NA NA NA 0.02 NA 12/13/04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0 NA NA NA NA ND NA 0.15 ND NA NA NA NA NA NA NA NA 0.012 NA 03/03/05 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0 NA NA NA NA ND NA 0.57 ND NA NA NA NA NA NA NA NA 0.085 NA 07/28/11 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0 ND ND ND ND 0.0054 ND NA ND ND ND ND 0.778 ND ND ND ND NA 0.037 MW-6 06/04/04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0 NA NA NA NA ND NA 0.17 ND NA NA NA NA NA NA NA NA 0.015 NA Duplicate h/2004/1040082-04/oct/table 2 Page 3 of 4 Table 6 Groundwater Analytical Results (December 2015) Aquair II Brownfields Site 13300 Sam Neely Road Charlotte, Mecklenburg County, NC Terracon Project No. 71157779 Sample ID: Sample Date: Volatlie Organic Compounds (EPA Method 8260) 1,1-Dichloroethene 7 <1.0 4.0 <1.0 Carbon tetrachloride 0.3 <1.0 57.2 <1.0 Chloroform 70 1.5 36.6 <1.0 cis-1,2-Dichloroethene 70 <1.0 1.8 4.0 Tetrachloroethene 0.7 69.1 37.7 <1.0 Trichloroethene 3 4.9 24.5 <1.0 Metals (EPA Methods 6010, 7470, and 7196) Aluminum NS 2,350 11,100 <100 Antimony NS <5.0 <5.0 <5.0 Arsenic 10 <10.0 <10.0 <10.0 Barium 700 215 185 71.6 Beryllium NS <1.0 <1.0 <1.0 Boron 700 <50.0 <50.0 <50.0 Cadmium 2 <1.0 <1.0 <1.0 Calcium NS 35,400 27,700 31,400 Chromium, Total 10 <5.0 25.7 <5.0 Chromium, Hexavalent 10 <10.0 <10.0 <10.0 Cobalt NS <5.0 <5.0 <5.0 Copper 1,000 <5.0 7.10 <5.0 Iron 300 4,490 18,200 8,100 Lead 15 <5.0 <5.0 11.2 Magnesium NS 23,600 17,500 19,000 Manganese 50 210 176 69.8 Mercury 1,000 <0.20 <0.20 <0.20 Molybdenum NS <5.0 <5.0 <5.0 Nickel 100 <5.0 <5.0 <5.0 Potassium NS <5,000 <5,000 <5,000 Selenium 20 <10.0 <10.0 <10.0 Silicon NS 25,800 42,200 20,900 Silver 20 <5.0 <5.0 <5.0 Sodium NS 30,200 10,800 13,000 Strontium NS 447 369 292 Thallium NS <10.0 <10.0 <10.0 Tin NS <5.0 <5.0 <5.0 Titanium NS 169 591 <5.0 Vanadium NS 15.4 41.4 <5.0 Zinc 1,000 12.5 56.9 1,870 Notes: Only detected compounds shown for VOCs, all analyzed compounds shown for metals. Concentrations are reported in micrograms per liter (μg/L). 2L Standard - North Carolina Administrative Code Subchapter 2L Groundwater Standard, updated September 2015. Bold indicates a concentration exceeding the laboratory reporting limit. Gray shading indicates a concentration exceeding the 2L Standard. NS - no standard Analyte 2L Standard AMW-405MW-5 MW-9 12/22/15 12/22/15 12/22/15 Table 4 Air and Soil Vapor Sample Results (December 2015) Aquair II Brownfields Site 13300 Sam Neely Road Charlotte, Mecklenburg County, NC Terracon Project No. 71157779 Sample ID: Sample Date: Type: SGSL IASL SGSL IASL Location: Volatile Organic Compounds (EPA Method TO-15) 1,2,4-Trimethylbenzene 48.7 1.460 613 6.13 <23 <15 <6.0 10 <1.0 2,2,4-Trimethylpentane NS NS NS NS <22 <14 <5.7 18 <5.0 4-Ethyltoluene NS NS NS NS <23 <15 <6.0 12 <1.0 Acetone 216,000 6,470 2,720,000 27,200 <110 <72 <29 <29 8.9 Benzene 120 0.360 1,570 1.57 <15 <9.6 <3.9 18 <0.68 Carbon Disulfide 4,870 146 61,300 613 <58 <37 <15 16 <3.3 Cyclohexane 41,700 1,250 526,000 5,260 <16 <10 <4.2 4.2 <0.74 Ethanol NS NS NS NS <35 <23 <9.3 <9.2 2.3 Ethylbenzene 374 1.12 4,910 4.91 <20 <13 <5.3 15 <0.93 Freon 11 (Trichlorofluoromethane)4,870 146 61,300 613 <26 <17 <6.9 <6.9 1.3 Freon 12 (Dichlorodifluoromethane)695 20.9 8,760 87.6 <23 <15 <6.1 <6.0 2.8 Heptane NS NS NS NS <19 <12 <5.0 95 <0.88 Hexane 4,870 146 61,300 613 <16 <11 <4.3 53 <0.75 m,p-Xylene 695 20.9 8,760 87.6 <20 <13 <5.3 67 <0.93 o-Xylene 695 20.9 8,760 87.6 <20 <13 <5.3 17 <0.93 Toluene 34,800 1,040 438,000 4,380 38 270 100 130 0.89 Helium NS NS NS NS 0.12%NA NA NA NA Notes: Concentrations are reported in micrograms per cubic meter (μg/m3) unless otherwise noted. Only compounds that were detected in groundwater are shown. ft ags - feet above ground surface NA - not analyzed NS - no standard DWM - North Carolina Department of Environmental Quality, Division of Waste Management IASL - DWM Indoor Air and Crawlspace Screening Concentration, updated September 2015 SGSL - DWM Sub-slab and Exterior Soil Gas Screening Level, updated September 2015 Concentrations highlighted in yellow exceed their respective residential SGSL or IASL (whichever is applicable). Concentrations highlighted in orange exceed their respective non-residential SGSL or IASL (whichever is applicable). A target carcinogenic risk of 1.0E-06 and target hazard quotient of 0.2 was assumed for the IASL (i.e., IASL(A) on DWM's screening levels table). Other Compounds (QA/QC) Analyte OA-01 Outdoor Air 12/15/15 Site Entrance Non-Residential Soil Gas Soil Gas Soil Gas Soil Gas IC Building IC Building IC Building Office Building SV-03 SV-04 12/15/15 12/15/15 12/15/15 12/15/15Screening LevelsScreening Levels Residential SV-01 SV-02 Appendix B DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 5/18/2023 Prepared By:H&H Worst-Case Soil Gas AquAir II - West Side 13300 Sam Neely Road Charlotte, NC Brownfields Redevelopment Section 18038-14-060 January 2023 November 2022 EPA RSL Table North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 18038-14-060 Exposure Unit ID: Worst-Case Soil Gas Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: January 2023 Basis: November 2022 EPA RSL Table Exposure Unit ID: Worst-Case Soil Gas Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 170 67-64-1 Acetone 15 71-43-2 Benzene 7.2 75-15-0 Carbon Disulfide 0.53 56-23-5 Carbon Tetrachloride 0.23 67-66-3 Chloroform 1.4 74-87-3 Chloromethane 4.9 110-82-7 Cyclohexane 2.2 75-71-8 Dichlorodifluoromethane 5 78-87-5 Dichloropropane, 1,2- 31 100-41-4 Ethylbenzene 550 142-82-5 Heptane, N- 24 110-54-3 Hexane, N- 15 78-93-3 Methyl Ethyl Ketone (2-Butanone) 3.3 75-09-2 Methylene Chloride 520 115-07-1 Propylene 0.65 100-42-5 Styrene 20 127-18-4 Tetrachloroethylene 700 108-88-3 Toluene 0.64 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 2.7 75-69-4 Trichlorofluoromethane 15 95-63-6 Trimethylbenzene, 1,2,4- 2.1 108-67-8 Trimethylbenzene, 1,3,5- 130 108-38-3 Xylene, m- 39 95-47-6 Xylene, o- Input Form 2D Soil Gas Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 18038-14-060 Exposure Unit ID: Worst-Case Soil Gas Receptor Pathway Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.8E-07 1.4E-02 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based Surface Water VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 18038-14-060 Exposure Unit ID: Worst-Case Soil Gas CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 71-43-2 75-15-0 56-23-5 67-66-3 74-87-3 110-82-7 75-71-8 78-87-5 100-41-4 142-82-5 Heptane, N-550 5.5 -3.5E+02 3.1E-03 110-54-3 78-93-3 75-09-2 115-07-1 100-42-5 127-18-4 Tetrachloroethylene 20 0.2 4.7E+01 3.5E+01 4.2E-09 1.1E-03 108-88-3 Toluene 700 7 -4.4E+03 3.2E-04 76-13-1 75-69-4 95-63-6 108-67-8 108-38-3 95-47-6 Cumulative:1.8E-07 1.4E-02 Output Form 3E risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator