Loading...
HomeMy WebLinkAbout06001_Alamac Lumberton_AWP_20240229NORTH CAROLINA DEQ BROWNFIELDS PROGRAM WORK PLAN FOR EVALUATION OF A REQUESTED PAUSE OF THE GROUNDWATER TREATMENT SYSTEM Alamac American Site Brownfields No. 06001-02-78 1885 Alamac Road Lumberton, North Carolina 28358 February 2024 Revision No. 3 Prepared for: NC Department of Environmental Quality Division of Waste Management Brownfields Program 217 West Jones Street Raleigh, NC 27603 Prepared by: Verdantas LLC 4 Hemisphere Way Bedford, Ohio 44146 Prepared on Behalf of: �Nuu+�rpt Phoenix Investors LLC [OwrtB�`� CqR►.,�� 401 E Kilbourn Av u # �l Milwaukee, Wl' 20 ►0 . ENSF���� •.� r 4:2 2 S 287 N Borton Lawson American Engineering, PC NC PE Firm License No. C-4805 Document Number: 15104.0014 February 2024 r verdantas 01 Document Number 15104.0014 TABLE OF CONTENTS SECTION PAGE SECTION 1.0 INTRODUCTION..................................................................................................I SECTION2.0 BACKGROUND...................................................................................................I SECTION 3.0 SCOPE OF WORK (SOW)...................................................................................3 SECTION 4.0 SAMPLING METHODOLOGY.............................................................................4 4.1 INDOOR AIR SAMPLING...................................................................................4 4.2 SUB -SLAB SOIL VAPOR SAMPLING...................................................................5 4.3 GROUNDWATER GAUGING AND STREAM STAGE MEASUREMENT...............6 4.4 REDEVELOPMENT OF WELLS TO BE SAMPLED.................................................7 4.5 GROUNDWATER SAMPLING............................................................................7 4.6 SURFACE WATER SAMPLING............................................................................8 4.7 SEDIMENT SAMPLING........................................................................................8 SECTION 5.0 LABORATORY ANALYSES...................................................................................8 SECTION 6.0 QUALITY ASSURANCE/QUALITY CONTROL(QA/QC)......................................9 SECTION 7.0 INVESTIGATION DERIVED WASTE (IDW) MANAGEMENT.................................9 SECTION 8.0 RISK EVALUATION...............................................................................................9 TABLES TABLE 1 Property Summary TABLE 2 Sampling Summary TABLE 3 Groundwater Monitoring Wells to be Sampled FIGURES FIGURE 1 Site Location Map FIGURE 2 Proposed Paired Indoor Air/Sub-Slab VAP or Sampling Locations FIGURE 3 Proposed Groundwater Sampling Locations FIGURE 4 Proposed Surface Water and Sediment Sampling Locations (Excepting VSW-6) FIGURE 5 Location of Proposed Surface Water Sampling Location VSW-6 4 Hemisphere Way, Bedford, OH 44146 1 verdantas.com February 2024 Document Number 15104.0014 APPENDICES verdantas APPENDIX A Diagram of Former Manufacturing Building Showing Leased Areas APPENDIX B Letter Summarizing November 30, 2022 Sampling of Recovery Wells APPENDIX C Protocols for PFAS Sampling 4 Hemisphere Way, Bedford, OH 44146 1 verdantas.com February 2024 Document Number 15104.0014 SECTION 1.0 INTRODUCTION verdantas This letter Work Plan Revision No. 3 has been prepared in response to NC DEQ's comments provided on November 8, 2023, in response to the Work Plan Revision 2 (Verdantas Document #15104.0014). The property is located at 1885 Alamac Road, Lumberton, Robeson County, North Carolina (the Subject Property - refer to Figure 1). SECTION 2.0 BACKGROUND Phoenix Investors LLC (Phoenix) acquired the 151.79-acre Subject Property, consisting of Parcel # 101702033 and Parcel # 10170203301, in July 2022. Verdantas reviewed ownership information maintained by the Robeson County Auditor. Historical Subject Property ownership is summarized below. Parcel # 101702033 Date Grantor Grantee 5/31/1971 Not provided West Point-Pepperell Inc. Not Provided West Point-Pepperell Inc. Alamac Knit Fabrics, Inc. 9/28/2001 Alamac Knit Fabrics, Inc. Alamac Acquisition LLC 9/15/2016 Alamac Acquisition LLC Alamac Holdings, LLC 3/26/2019 Alamac Holdings, LLC Lumberton Energy Holdings, LLC Parcel # 10170203301 Date Grantor Grantee 10/10/1994 Not provided Alamac Knit Fabrics, Inc. 8/27/1997 Alamac Knit Fabrics, Inc. Alamac Knit Fabrics Inc. 9/28/2001 Alamac Knit Fabrics Inc. Alamac Acquisition LLC 9/15/2016 Alamac Acquisition LLC Alamac Holdings, LLC 3/26/2019 Alamac Holdings, LLC Lumberton Energy Holdings, LLC Table 1 provides a property summary for the subject Property. Phoenix currently leases a part of the Subject Property to a tenant that occupies only the western portion of the building. A diagram of the leased area is attached at Appendix A. Note that the leased area is not within the area that the North Carolina DEQ Brownfield Program identified in their December 6, 2022, correspondence related to evaluation of indoor air at the Subject Property. Tetrachloroethene (PCE) and its daughter products were detected in environmental media beneath and in the vicinity of a PCE containment pad at the Subject Property in 4 Hemisphere Way, Bedford, OH 44146 1 verdantas.com February 2024 Verdantas Document Number 15104.0014 1997. In 1999 and 2000, environmental remedial efforts were conducted under the direction of S&ME, Inc. (S&ME) to address the contamination, including: 1. removal and disposal of the concrete PCE pad; 2. removal and disposal of underground piping beneath the PCE pad and between the pad and the manufacturing building; 3. excavation and stockpiling of approximately 582 cubic yards of soil to depths slightly below the water table [four to five ft. below ground surface (bgs) in the vicinity of the pad]; 4. thermally treating the soil on -site; 5. construction and use of an infiltration gallery to introduce a water -molasses mixture into contaminated groundwater; 6. installation and operation of three groundwater recovery wells within the monitored source area (refer to Figure 2); 7. discharge of extracted groundwater to the Subject Property's wastewater treatment plant (WWTP); and 8. implementation of monitored natural attenuation downgradient of the monitored source area extending southward to the Jacob Swamp Canal, where S&ME, through head measurements within monitoring wells near the canal and heads within the canal, identified a stream recharge boundary, indicating groundwater north of the canal would not migrate south of the canal. Documentation was provided to Verdantas that indicated that S&ME submitted an injection permit application for direct -push injection of food -grade soybean oil into groundwater within the Monitored Source Area to enhance biodegradation of PCE and daughter products. The groundwater recovery system has operated since November 1999. Between 1999 and June 2004, water was sampled quarterly from the recovery wells, an off -site production well located at 2237 Alamac Road (designated WSW-1) and selected monitoring wells. The samples were tested at an analytical laboratory for volatile organic compounds (VOCs) by U.S. EPA Method 8260B, pursuant to a Water Quality Monitoring Plan prepared by S&ME and approved by the North Carolina Department of Environmental and Natural Resources [currently the North Carolina Department of Environmental Quality (NC DEQ)] on August 16, 1999. Following June 2004, per NC DEQ's approval, sampling became once per year and testing remained as described above. On February 24, 2006, Alamac Knits LLC, then owner of the Subject Property, entered into a Brownfields Agreement with NC DEQ. In September 2008, approval was provided to sample only the three recovery wells and the off -site production well. The recovery wells are operating at present. In February 2022, the NC DEQ sampled surface water from the Jacob Swamp Canal upstream and downstream of the Subject Property, as well as effluent from the WWTP outfall, and tested the samples for polyfluoroalkyl substances (PFAS). PFAS compounds were detected in all samples collected. 4 Hemisphere Way, Bedford, OH 44146 1 verdantas.com 2 February 2024 Document Number 15104.0014 verdantas On November 30, 2022, Verdantas collected groundwater samples from recovery wells RW-1, RW-2 and RW-3 and submitted the samples for analysis of PFAS, VOCs and inorganic analytes for evaluating alternative treatment options for extracted groundwater. Sampling and findings are detailed in a December 9 summary letter (Verdantas Document No. 15104.0016). A copy of that summary letter is attached as Appendix B. SECTION 3.0 SCOPE OF WORK (SOW) Phoenix has asked the Brownfields Program to allow it to pause pumping from the recovery wells for a period of 90 days. The purpose of this work plan is to provide information and analysis to assist in: 1. evaluating whether pausing the recovery system for 90 days would result in an unacceptable increase in risks resulting from potential changes in movement of groundwater; and 2. evaluating whether pausing the recovery system would affect risks to on - site commercial/industrial workers from indoor air conditions at the Subject Property. Verdantas recommends conducting the following activities to support the risk evaluations: Prior to initiating a pause to the system: a. Perform a Brownfields Property Receptor Survey; b. Collect and analyze paired sub slab soil vapor and indoor air samples (SS-1/IA-1A through SS-5/IA-5) in the eastern portion of the former manufacturing building, adjacent to the Monitored Source Area as shown on Figure 2 and described on Table 2. Evaluate the sample results using NC DEQ's Risk Calculator for Non -Residential Worker Indoor Air (February 2024). C. Gauge groundwater levels in all accessible monitoring wells located on the Site to obtain water elevations, as shown on Table 2, locate production well DW-1 A and document conditions of all the wells. d. Collect groundwater samples from a subset of the existing monitoring well network. Groundwater samples will be collected from monitoring wells RW-1, RW-2, RW-3, MW-4, MW-7, MW-8, MW-12, MW-13, MW-15, MW-16, MW-17, MW-18, MW-19, MW-20 and MW-21 for laboratory analysis of VOCs in accordance with U.S. EPA Method 8260 and PFAS in accordance with U.S. EPA Method 537.1 Modified. Samples collected from MW-7, MW-8, MW-19, and MW-20 will also be tested for nitrate and boron by U.S. EPA Methods 300.1 and 200.7, respectively. Samples collected from MW-19 and MW-20 will be analyzed for nitrate and boron to determine potential influences from septic systems and samples from MW-7 and MW-8 will be analyzed for nitrate and boron for comparative purposes. Locations 4 Hemisphere Way, Bedford, OH 44146 1 verdantas.com 3 February 2024 Document Number 15104.0014 verdantas of the wells to be sampled are shown on Figure 3 and described on Table 3. Groundwater samples will be collected prior to system shutdown and 60 days after system shutdown. e. Collect upstream and downstream surface water samples from Jacob Swamp Canal, on -Property ponds and on -Property pond effluent (VSW-1 through VSW-6) for laboratory analysis of VOCs in accordance with U.S. EPA Method 8260 and PFAS in accordance with U.S. EPA Method 537.1 Modified. Proposed sampling locations for surface water locations VSW-1 through VSW-5 are shown on Figure 4. The proposed sampling location for VSW-6 is shown on Figure 5. f. Collect sediment samples from on -Property ponds (VSED-1 through VSED-3) for laboratory analysis of VOCs in accordance with U.S. EPA Method 8260 and PFAS in accordance with U.S. EPA Method 537.1 Modified. Proposed sampling locations are shown on Figure 4. 2. Assuming that NC DEQ approves the 90-day pause, at the end of the 90- day period a complete round of depth to water measurements will be collected. Paired indoor air samples followed by sub slab soil vapor sampling (HVP-1 /IA-1 through HVP-5/IA-5) in the eastern portion of the former manufacturing building, adjacent to the Monitored Source Area collect and analyzed. Evaluate the sample results using NC DEQ's Risk Calculator for Non -Residential Worker Indoor Air (February 2024). SECTION 4.0 4.1 INDOOR AIR SAMPLING SAMPLING METHODOLOGY Indoor air samples (IA-1 through IA-5) will be collected within the occupied portions of the building, biased toward the area of the known groundwater plume. Additionally, an outdoor ambient air sample (AA-2) will also be collected. The sampling locations are shown on Figure 2. At least 24 hours prior to the indoor air sampling activities, a pre -sampling inspection will be performed to document conditions within the building that could potentially affect indoor air analytical results. Any materials that could create interferences with sampling results will be removed from the building and Safety Data Sheets will be provided in an Appendix to the report. The owner will communicate with its on -site employees to request that they do not access the portion of the building to be sampled during the sampling period. The owner will also maintain typical HVAC operation during the sampling period. Also prior to sampling, a photoionization detector (PID - equipped with a 11.7 eV bulb) reading will also be collected prior to sampling from each proposed vapor sample location. 4 Hemisphere Way, Bedford, OH 44146 1 verdantas.com 4 February 2024 Verdantas Document Number 15104.0014 Canisters will be positioned between 3 and 6 feet above the floor within the breathing zone. Based on the anticipated continued use of the Subject Property for commercial/industrial purposes, individually laboratory -certified six -liter Summa canisters for indoor air sampling will be calibrated to fill over an 8-hour sampling period at a flow rate of approximately 12.5 milliliters per minute. The 8-hour sampling period will replicate a commercial/industrial worker's exposure. Summa canisters will be placed approximately 3 to 6 feet above the ground surface to provide representative concentrations with the commercial/industrial worker breathing zone. The ambient air sample will also be collected via a Summa canister over an 8-hour period. A final vacuum reading of at least -5" Hg in each of the canisters will be targeted. One duplicate indoor air sample will be collected during the sampling period. The canister for the indoor air duplicate will be set up within two or three lateral feet of the primary canister. The laboratory will be requested to report received vacuum for all sampling canisters. If the sampling canister is evacuated to 0" Hg in the field or if the laboratory notes that the sampling canister is received at a vacuum of 0" Hg, laboratory analytical results will not be accepted. Following completion of the 90-day pause in groundwater extraction, Verdantas will re- mobilize to the Subject Property to collect additional paired indoor air/soil vapor samples at the same locations, using the same procedures and presenting the same documentation described above. 4.2 SUB -SLAB SOIL VAPOR SAMPLING The proposed locations for paired sub slab soil vapor SS-1 through SS-5 are shown on Figure 2. After the proposed indoor air samples have been collected, a vapor pin will be installed at each of the indoor air sampling locations. The vapor pins are proposed to be installed a minimum of five (5) feet from any walls or cracks in the concrete slab with a 5/8-inch diameter HiltiTM (or equivalent) hammer drill bit to approximately 1-inch below the concrete slab and a 1 1/2-inch diameter HiltiTM (or equivalent) hammer drill bit to create a countersink for the placement of a stainless steel flush mount cover. The vapor pins will then be installed in the pilot holes and following installation, leak testing of the vapor pin construction will be performed using a helium shroud, helium detector, and helium tracer gas. Leak testing methodologies will consist of the connection of the vapor pin to an outlet port on a helium shroud via 1/4-inch or 3/8-inch Teflon® or Teflon® -lined tubing, the introduction of Grade 5 helium tracer gas via the shroud inlet port, and the monitoring of the outlet port with a helium detector to ensure helium is not migrating into the vapor pin. The slab thickness and type of material found under the slab will be documented for each vapor pin location. At least 30 minutes of stabilization below capped vapor pins will be required prior to collection of sub slab vapor samples. In addition to the leak testing of the sub -slab vapor pin to ensure proper construction, leak testing of the sampling train is proposed to be completed with the helium shroud apparatus described above. The sampling trains will be leak tested using a helium shroud 4 Hemisphere Way, Bedford, OH 44146 1 verdantas.com 5 February 2024 Verdantas Document Number 15104.0014 to which a Grade 5 helium source will be connected via '/4-inch or 3/8-inch Teflon® or Teflon® -lined tubing. The sampling train will be connected to the sub -slab vapor pin via tubing ('/4-inch or 3/8-inch Teflon® or Teflon® -lined tubing), secured with appropriate fittings and connections to both the Summa Canister (with the valve closed) and to a tedlar bag equipped with a backflow preventer. Prior to sample collection, purging 3 to 4 system volumes of sub -slab vapor will be completed with a personal air pump at a rate not to exceed 200 ml/min into a tedlar bag for field screening with a PID meter and a calibrated helium detector to ensure helium is not entering the sampling train. Detection of significant amounts of helium during the test will require re -connecting all fittings and re -testing. A second detection of helium will require replacement of tubing and connections and possibly re -seating of the vapor pin. Leak testing will be repeated until no helium is detected. Based on the anticipated continued use of the Subject Property for commercial/industrial purposes, individually laboratory -certified six -liter Summa canisters for indoor air sampling will be calibrated to fill over an 8-hour sampling period at a flow rate of approximately 12.5 milliliters per minute. The 8-hour sampling period will replicate a commercial/industrial worker's exposure. One duplicate sub slab vapor sample will be collected during the period of sampling. A three-way valve, or "T" connecter will provide flow to both the primary and duplicate canisters. A final vacuum reading of at least -5" Hg in each of the canisters will be targeted. The laboratory will be requested to report received vacuum for all sampling canisters. If the sampling canister is evacuated to 0" Hg in the field or if the laboratory notes that the sampling canister is received at a vacuum of 0" Hg, laboratory analytical results will not be accepted. Following sampling, the vapor pins will be secured with sealable caps. Following completion of the 90-day pause in groundwater extraction, Verdantas will re -mobilize to the Subject Property to collect additional sub -slab vapor samples at the same locations, using the same procedures and presenting the same documentation described above. 4.3 GROUNDWATER GAUGING AND STREAM STAGE MEASUREMENT All accessible groundwater monitoring wells at the Subject Property will be gauged using an electrical conductivity sonde attached to a graduated tape that will permit measurement of the well's total depth and the groundwater surface interface to 0.01 inch, using the top of riser for each well as a reference. The condition of the each well will be documented based on visual observation and/or the presence of obstructions within the risers. During the gauging event, production well DW-1 A will also be located. The graduated tape and sonde will be decontaminated by a water/AlconoxTM solution followed by a distilled water rinse between gauging of each monitoring well. Stream stage elevations will be measured within the Jacob Swamp Canal at two locations: near on -site monitoring well MW-12; and near on -site monitoring well MW-13. 4 Hemisphere Way, Bedford, OH 44146 1 verdantas.com 6 February 2024 Verdantas Document Number 15104.0014 Tops of risers for the monitoring wells will be used for reference elevations for a survey level system; a surveyor's rod will be deployed in the surface water. All monitoring wells and the surface water measurement locations will be located by a global positioning unit. This will permit the locations to be accurately shown on Verdantas' base maps. Groundwater gauging and surface water elevation data will be tabulated and contoured on the Subject Property base map. Observations on monitoring well conditions will also be tabulated. Verdantas will evaluate the data and document the extent to which a stream recharge flow boundary is still present along the southern property line for the Subject Property. 4.4 REDEVELOPMENT OF WELLS TO BE SAMPLED All monitoring wells to be sampled (RW-1, RW-2, RW-3, MW-4, MW-7, MW-8, MW-12, MW- 13, MW-15, MW-16, MW-17, MW-18, MW-19, MW-20, and MW-21) will be redeveloped. Monitoring well redevelopment may be performed using a variety of methods, though a combination of surging and purging is expected. Redevelopment may be performed manually with a bailer or surge block or mechanically with a submersible pump. If a submersible pump is used, the pump will be surged (lowered up and down) within the well screen while pumping is on -going. A minimum of five well volumes will be removed. Purged water will be monitored for stability of groundwater indicator parameters including pH, conductivity, temperature, dissolved oxygen (DO), oxygen/reduction potential (ORP) and turbidity. Well development will continue until the water quality parameters have stabilized and the water is visually clear of turbidity or a maximum of 10 well volumes have been removed. If development is implemented using a submersible pump, the aforementioned groundwater indicator parameters will be collected using a multi -parameter sonde and flow through cell. If bailers are used during development, the groundwater indicator parameters will not be collected in a flow through cell. Extracted groundwater will be containerized in Department of Transportation (DOT) approved drums, sampled, and characterized, and either disposed within the facility's water treatment system upon re -activation or sent off -Site to a licensed disposal facility. 4.5 GROUNDWATER SAMPLING A low -flow sampling pump will be used for sampling the selected monitoring well. Clean gloves will be worn by each individual handling the sampling equipment. The following steps will be adhered to during sampling: 1. The pump will not be dropped into the monitoring well, as this may cause degassing of the water on impact; 2. Groundwater will be transferred from the pump into the proper laboratory supplied glassware in a manner which will minimize agitation and aeration; and 4 Hemisphere Way, Bedford, OH 44146 1 verdantas.com 7 February 2024 Verdantas Document Number 15104.0014 3. In order to preserve sample quality, the sampling order will be as follows: volatile organic compounds, non-volatile organic compounds, and in -situ parameters (e.g., pH, temperature, conductivity, and turbidity). Additional protocols for sampling PFAS compounds are described in Appendix C. Water not used for sample make-up will be containerized in a DOT approved drum, sampled, and characterized, and either disposed within the facility's water treatment system upon re -activation or sent off -Site to a licensed disposal facility. 4.6 SURFACE WATER SAMPLING Surface water samples will be collected from banks of surface water bodies shown on Figure 4 using a decontaminated glass container affixed to a rigid pole. Surface water samples will be transferred to laboratory -supplied bottles. Clean gloves will be worn by each individual handling the sampling equipment. Water not used for sample make-up will be containerized in a DOT approved drum, sampled, and characterized, and either disposed within the facility's water treatment system upon re -activation or sent off -Site to a licensed disposal facility. 4.7 SEDIMENT SAMPLING Sediment samples will be collected from a distance of approximately 4 feet from the banks of surface water bodies shown on Figure 4 using a decontaminated ponar sampler. The ponar sampler will be deployed by hand by the Verdantas field personnel. Sediment samples will be transferred from the ponar sampler to laboratory -supplied bottles. Clean gloves will be worn by each individual handling the sampling equipment. SECTION 5.0 LA60RATORY ANALYSES Summa canister samples of sub slab vapors and indoor air, collected prior to and at the end of the 90-day pause, will be tested at the ALS Cincinnati, Ohio laboratory for VOCs in accordance with U.S. EPA Method TO-15 (full analyte list). To the extent feasible, Method Reporting and Detection Limits will meet all applicable screening levels for indoor air. Furthermore, ALS will report the vacuum within each summa canister when received at the laboratory. All J values will be reported by ALS. Groundwater samples collected prior to and at the end of the 90-day pause, will be tested at the ALS Cincinnati, Ohio laboratory for VOCs in accordance with U.S. EPA Method 8260 and PFAS in accordance with U.S. EPA Method 537.1 Modified. Sampled collected from MW-7, MW-8, MW-19, and MW-20 will also be analyzed for nitrate and boron for U.S. EPA Methods 300.1 and 200.7, respectively. All J values will be reported by ALS. Surface water and sediment samples collected prior to the 90-day pause will be tested at the ALS Cincinnati, Ohio laboratory for VOCs in accordance with U.S. EPA Method 8260 and PFAS in accordance with U.S. EPA Method 537.1 Modified. 4 Hemisphere Way, Bedford, OH 44146 1 verdantas.com 8 February 2024 verdantas Document Number 15104.0014 SECTION 6.0 QUALITY ASSURANCE/QUALITY CONTROL (QA/QC) One duplicate sample will be collected per r per day when collecting indoor air and sub slab samples. Following sample collection, Summa canisters will be shipped overnight to ALS laboratory in Cincinnati, Ohio under completed chain -of -custody for log -in and testing. The ALS laboratory will perform testing under Level II QA/QC protocols. One duplicate sample will be collected per day during each groundwater sampling event. A trip blank will accompany all coolers that contain samples for VOC analysis. Additionally, one field blank and one equipment blank will be collected during each sampling event. Following sample collection, sample jars will be shipped overnight to ALS laboratory in Cincinnati, Ohio under completed chain -of -custody for log -in and testing. The ALS laboratory will perform testing under Level II QA/QC protocols. One duplicate sample will be collected per 20 surface water samples per day during each sampling event. A trip blank will accompany all coolers that contain samples for VOC analysis. Additionally, one field blank and one equipment blank will be collected during the sampling event. Following sample collection, sample jars will be shipped overnight to ALS laboratory in Cincinnati, Ohio under completed chain -of -custody for log -in and testing. The ALS laboratory will perform testing under Level II QA/QC protocols. A trip blank will accompany all coolers that contain sediment samples for VOC analysis. Additionally, one field blank and one equipment blank will be collected during the sediment sampling event. Following sample collection, sample jars will be shipped overnight to ALS laboratory in Cincinnati, Ohio under completed chain -of -custody for log -in and testing. The ALS laboratory will perform testing under Level II QA/QC protocols. SECTION 7.0 INVESTIGATION DERIVED WASTE (IDW) MANAGEMENT To the extent that IDW is generated, soil cuttings, purged groundwater, and decontamination water will be drummed and staged on the Subject Property at a location identified by the Client. Verdantas will segregate soil cuttings and decontamination water, which are assumed to be classified as non -hazardous, but will require disposal. Verdantas will arrange for disposal and characterization of this material (consistent with the NC DEQ's Brownfields Assessment Work Plan Assessment Work Plan Checklist); however, the Client will be identified as the generator and will be responsible for signing manifests. Verdantas has included costs for disposal of this material, assuming that it is classified as non -hazardous. SECTION 8.0 RISK EVALUATION Verdantas will perform two risk evaluations as part of this work plan. First, pursuant to conversations with the Brownfields Program, and based on the collected data and proposed modeling, it will assess whether pausing the groundwater recovery system for 90-days would pose an unacceptable risk to potable groundwater users south of the 4 Hemisphere Way, Bedford, OH 44146 1 verdantas.com 9 February 2024 Verdantas Document Number 15104.0014 Jacob Swamp Canal including the Lumberton River and points east. Second, based on the findings from the indoor air/soil vapor sampling, it will assess whether pausing the recovery system affected risks to on -site commercial/industrial workers from indoor air conditions. Risk calculations will be generated based on the NC DEQ's Risk Calculator for Non - Residential Worker Indoor Air (February 2024) and will utilize the maximum concentration for each compound for each media to generate the most conservative risk. The reporting limit concentration will be utilized for non -detect compounds. SECTION 9.0 REPORTING Upon receiving laboratory analytical reports, Verdantas will transmit them to the DEQ. Verdantas will prepare an initial summary report that describes groundwater gauging and the model(s) selected and employed, inputs, simulation results and findings as they pertain to estimated site conditions over the period of the proposed pause in groundwater extraction. This summary report will also describe the initial paired sub -slab vapor/indoor air sampling efforts, groundwater sampling efforts, and findings. Based on the above, risks will be examined in the context of a pause in groundwater recovery. To the extent these risks are determined to be acceptable, the report will include a formal request and schedule for the pause. At the conclusion of the pause, assuming a pause is completed, a report will be prepared documenting field efforts and the findings of the second sub -slab vapor/indoor air sampling event along with an examination of risk as influenced by these findings. All reporting will be completed under the guidance of a North Carolina Professional Engineer/Professional Geologist and will be sealed prior to submittal to the agency. 4 Hemisphere Way, Bedford, OH 44146 1 verdantas.com 10 February 2024 Document Number 15104.0014 TABLES verdantas 4 Hemisphere Way, Bedford, OH 44146 1 verdantas.com NORTH CAROLINA DEQ BROWNFIELDS PROGRAM WORK PLAN FOR EVALUATION OF A REQUESTED PAUSE OF THE GROUNDWATER TREATMENT SYSTEM 1885 ALAMAC ROAD, LUMBERTON, NORTH CAROLINA TABLE 1 PROPERTY SUMMARY Brownfields Project No. Parcel No. Address Site Acreage Former/ Current Use REC Proposed Use Monitored Source Area Textiles 101702033 and 1885 Alamac Road, Lumberton, (chlorinated volatile 06001 02-78 151.79 Manufacturingpping ou Commercial/Industrial 10170203301 North Carolina 28358 organic compounds in sing and Shipping groundwater) VERDANTAS LLC BEDFORD, OHIO Page 1 of 1 FEBRUARY 2024 15104.0008 Revision No.3 NORTH CAROLINA DEQ BROWNFIELDS PROGRAM WORK PLAN FOR EVALUATION OF A REQUESTED PAUSE OF THE GROUNDWATER TREATMENT SYSTEM 1885 ALAMAC ROAD, LUMBERTON, NORTH CAROLINA TABLE 2 SAMPLING SUMMARY Data Gap Parcel/Bldg. No. Sampling Objective Type of Sample Number of Samples Depth of Samples Analytical Program Detection range for TCE Determine Sub Slab Vapor and Six Sub Slab Vapor Several Inches below Slab Sub Slab Vapor and Indoor Air 101702033/Eastern Indoor Air Quality and Risk in Sub Slab Vapor Samples (including (depending on slab thickness) Chemicals of Concern Portion of Former of Former Manufacturing and Indoor duplicate); Six Indoor Air for Sub Slab Samples; and U.S. EPA Method TO- 3 ug/m Adjacent to Monitored Source 1 ManufacturingPortion Building Adjacent to Monitored Air/Outdoor Samples (includingApproximate p Breathing Zone g 15 full anal to list)1.07 ( Y Area Building Source Area Ambient Air duplicate); and One r I for Indoor Air and Ambient Air Ambient Air Sample 1 Samples VERDANTAS LLC FEBRUARY 2024 BEDFORD, OHIO Page 1 of 1 15104.0008 Revision No. 3 NORTH CAROLINA DEQ BROWNFIELDS PROGRAM WORK PLAN FOR EVALUATION OF A REQUESTED PAUSE OF THE GROUNDWATER TREATMENT SYSTEM 1885 ALAMAC ROAD, LUMBERTON, NORTH CAROLINA TABLE 3 PROPOSED MONITORING WELLS TO BE SAMPLED Well ID Top at asing Elevation (ft. MSI Screen Interval (ft. bgs) Analyses RW-1 110.25 10.00 to 20.00 VOCs, U.S. EPA Method 8260 PFAS, U.S. EPA Method 537.1 Modified RW 2 113.55 10.00 to 20.00 VOCs, U.S. EPA Method 8260 PFAS, U.S. EPA Method 537.1 Modified RW 3 110.32 10.00 to 20.00 VOCs, U.S. EPA Method 8260 PFAS, U.S. EPA Method 537.1 Modified MW 4 115.16 8.60 to 18.60 VOCs, U.S. EPA Method 8260PFAS, U.S. EPA Method 537.1 Modified MW-7 115.93 5.21 to 20.21 VOCs, U.S. EPA Method 8260 PFAS, U.S. EPA Method 537.1 Modified Nitrate, U.S. EPA Method 300.1 Boron, U.S. EPA Method 200.7 MW-8 113.86 9.59 to 19.59 VOCs, U.S. EPA Method 8260 PFAS, U.S. EPA Method 537.1 Modified Nitrate, U.S. EPA Method 300.1 Boron, U.S. EPA Method 200.7 MW-12 113.62 26.00 to 31.00 VOCs, U.S. EPA Method 8260 PFAS, U.S. EPA Method 537.1 Modified MW-13 116.32 20.50 to 20.50 VOCs, U.S. EPA Method 8260 PFAS, U.S. EPA Method 537.1 Modified MW-15 113.74 27.50 to 32.50 VOCs, U.S. EPA Method 8260 PFAS, U.S. EPA Method 537.1 Modified MW-16 114.62 27.50 to 32.50 VOCs, U.S. EPA Method 8260 PFAS, U.S. EPA Method 537.1 Modified MW-17 113.46 4.00 to 14.00 VOCs, U.S. EPA Method 8260 PFAS, U.S. EPA Method 537.1 Modified MW-18 112.82 4.00 to 14.00 VOCs, U.S. EPA Method 8260 PFAS, U.S. EPA Method 537.1 Modified MW-19 109.94 8.00 to 18.00 VOCs, U.S. EPA Method 8260 PFAS, U.S. EPA Method 537.1 Modified Nitrate, U.S. EPA Method 300.1 Boron, U.S. EPA Method 200.7 MW-20 112.67 11.50 to 21.50 VOCs, U.S. EPA Method 8260 PFAS, U.S. EPA Method 537.1 Modified Nitrate, U.S. EPA Method 300.1 Boron, U.S. EPA Method 200.7 MW-21 TBD TBD I VOCs, PFAS Note: TBD - To be determined. VERDANTAS LLC FEBRUARY 2024 BEDFORD, OHIO PAGE 1 OF 1 15104.0009 Revision No. 3 February 2024 Document Number 15104.0014 FIGURES verdantas 4 Hemisphere Way, Bedford, OH 44146 1 verdantas.com C: 2023, Verd ,,t s LLC - WmFSO Rask. 1� � fib F • I f I Y o I Rid1o$la 4x � r Mit RM � �-• � ��I Fil� � . Ytrr }}r + Poe } P1Alic 90atr{ _ I t Tower' �S. age — - � �+ R _ � Y� r101 u Subject Property Location 'ter ' 4. - - a DISCLAIMER: 0 Verdantas LLC has furnished this map to the company identified in the title block (Client) for its sole and 1,000 2,000 4'000 Feet North Carolina exclusive use as a preliminary planning and screening tool and field verification is necessary to confirm 1 Inch =2,000 Feet these data. This map is reproduced from geospatial information compiled from third -party sources which ^ may change overtime. Areas depicted by the map are approximate and may not be accurate to mapping, Quadrangle: Southwest Lumberton, NC surveying or engineering standards. Verdantas LLC makes no representation or guarantee as to the content, accuracy, timeliness or completeness of any information or spatial location depicted on this map. This map is provided without warranty of any kind, including but not limited to, the implied warranties of Source: The topographic map was acquired through the USGS Topographic Map Web Service. merchantability or fitness for a particular purpose. In no event will Verdantas LLC, its owners, officers, employees or agents, be liable for damages of any kind arising out of the use of this map by Client or any other party. The aerial photo was acquired through the Esri Imagery Web Service. Aerial photography dated 1/29/2021. Groundwater Treatment Re -Evaluation Work Plan Date: Alamac Road Property October 2023 Verdantas Subject Property Location Map Figure PEOPLE FOCIJ 5E❑ F J T Jr,I File Name: 15104-05—Fig01_SLM.mxd 1885 ARoad Lumberton, Robesonn County, North Carolina ou Edited: 10/17/2023 User: dread I Produced Using Esd's ArCGIS Software ✓a�ob Swap Subject Property Boundary Monitored Source Area Proposed Ambient Air Sample Proposed Indoor Air/Sub-Slab Vapor Recovery Well L F�_ 11!6 Jill 1111�14 4 -IT ­'J IN OV-1-L' AL C J 2 0 Clarifier Supply Sludge Processing Tank _14 ✓ac., Aer'ati in Tank pp. 0' 0 200 L 400 1 4 8DO, 00 () Feet Note: The aerial photo was acquired through the Esri Imagery Web Service. rb r Aerial photography dated 1/29/2021. ih DISCLAIMER February 2024 Verdantas LLC has furnished this map to the company identified in the title block (Client) for its sole and Groundwater Treatment Re -Evaluation Work Plan Figure exclusive use as a preliminary planning and screening tool and field verification is necessary to confirm Alamac Road Property d t these data. This map is reproduced from eospatial information compile, from third -party sources which may change over time. Areas depicted by the map are approximate and may not be accurate to mapping, ve r a n a s surveying or engineering standards. Verdantas LLC makes no representation or guarantee as to the content, Proposed Paired Indoor Air/Sub-Slab Vapor PEOPLE FOCUSED FUTURE accuracy, timeliness or completeness of any information or spatial location depicted on this map. This map is provided without warranty of any kind, including but not limited to, the implied warranties of merchantability Sampling Locations 2 or fitness for a particular purpose. In no event will Verdantas LLC, its owners, officers, employees or agents, 1885 Alamac Road be liable for damages of any kind arising out of the use of this map by Client or any other party. Lumberton, Robeson County, North Carolina � T . F•�� .- 0 200 L 400 800 40 * 5' m' �� �r' - }, Feet wly ti !* gip-' -r 15... R.: ' `'r PW'5 ' PW-1 'k • • `� x t t - t• . MW-1i {' 4 MW-16 ;{ RW-1 F - •+ -VIP, * RW-2 / \ RW-3 ,h • • + ; MW=18 "A MW-14 MW-3 MW-21 a + x vo MW-6 MW-9 MW-5 MW-23 PW-1 A MW., PW-3 , BMW-8 MW'7 ' • • ' • • MW-12 MW-19 MW-20 . MW-13 t. Subject Property Boundary • Monitored Source Area h•' Note: The aerial photo was acquired through the Esri Imagery Web Service. Deep Monitoring Well (20-75 FT BGS) I ter' AD -Aerial photography dated 1/29/2021. Shallow Monitoring Well (0-20 FT BGS) DISCLAIMERFebruary ry2024 Y Verdantas LLC has furnished this map to the company identified in the title block (Client) for its sole and Groundwater Treatment Re -Evaluation Work Plan Figure Property exclusive use as a preliminary planning and screening tool and field verification is necessary to confirm Alamac Road Pro Production Well these data. This map is reproduced from geospatial information compiled from third -party sources which p y may change over time. Areas depicted by the map are approximate and may not be accurate to mapping, Recovery Well r r ve r d a n t a s surveying or engineering standards. Verdantas LLC makes no representation or guarantee as to the content, Proposed Groundwater 3 r PEOPLE FOCUSED FUTURE accuracy, timeliness or completeness of any information or spatial location depicted on this map. This map is Sampling Locations WSJ Wells to be Sampled x provided without warranty of any kind, including but not limited to, the implied warranties of merchantability p w or fitness for a particular purpose. In no event will Verdantas LLC, its owners, officers, employees or agents, 1885 AlamaC Road be liable for damages of any kind arising out of the use of this map by Client or any other party. Lumberton, Robeson County, North Carolina i ✓a�ob Swap a -' tt Subject Property Boundary CO Proposed Sediment Sample A Proposed Surface Water Sample � . 4 nyid I ;L, i ' 0 200 L400 �r r { + * f Y 800 'e .. Feet Note: The aerial photo was acquired through the Esri Imagery Web Service. Aerial photography dated 1/29/2021. do DISCLAIMER: Verdantas LLC has furnished this map to the company identified in the title block (Client) for its sole and February 2024 Groundwater Treatment Re -Evaluation Work Plan Figure exclusive use as a preliminary planning and screening tool and field verification is necessary to confirm Alamac Road Property d t these data. This map is reproduced from ainformation compiled from third -party sources which may chthe m ange over time. Areas depicted by the mapp are approximate and may not accurate to mapping, ve r a n a s surveying or engineering standards. Verdantas LLC makes no representation or guarantee as to the content, Proposed Surface Water and Sediment P E O P L E FOCUSED FUTURE accuracy, timeliness or completeness of any information or spatial location depicted on this map. This map is Sampling Locations (Excepting VSW-6) provided without warranty of any kind, including but not limited to, the implied warranties of merchantability or fitness for a particular purpose. In no event will Verdantas LLC, its owners, officers, employees or agents, 1885 Alamac Road be liable for damages of any kind arising out of the use of this map by Client or any other party. Lumberton, Robeson County, North Carolina * ■ _ P bf x M 0 500 1,000 2,000 -'e Feet +# - + t or r r f 116, OF wal - ; �' ''f _ �-r .► * Tank Adw f - ,' F • # 40- ■ + (7 ). A �� Ind Wast • PondS sk _dk- of NIP— �. P Note: � � Site Boundary The topographic map was acquired through the USGS Topographic Map Web Service. z�, Proposed Surface Water Sample r DISCLAIMER: February 2024 Verdantas LLC has furnished this map to the company identified in the title block (Client) for its sole and Groundwater Treatment Re -Evaluation Work Plan Figure exclusive use as a preliminary planning and screening tool and field verification is necessary to confirm Alamac Road Property these data. This map is reproduced from geospatial information compiled from third -party sources which may ve r d a n t a s change over time. Areas depicted er the map are approximate and may not ar accurate to mapping, surveyingorengineering standards. Verdantas LLC makes no representation or guarantee as map. content, Location Of Proposed Surface Water ' accuracy, timeliness or completeness of any information or spatial location depicted on this map. This map is Sampling Location USW-6 P E O P L E FOCUSED F U T U R E provided without warranty of any kind, including but not limited to, the implied warranties of merchantability or fitness for a particular purpose. In no event will Verdantas LLC, its owners, officers, employees or agents, be liable for damages of any kind arising out of the use of this map by Client or any other party. 1885 Alamac Road Lumberton, Robeson County, North Carolina February 2024 Document Number 15104.0014 APPENDIX A j® verdantas DIAGRAM OF FORMER MANUFACTURING BUILDING SHOWING LEASED AREAS 4 Hemisphere Way, Bedford, OH 44146 1 verdantas.com February 2024 Document Number 15104.0014 APPENDIX B verdantas LETTER SUMMARIZING NOVEMBER 30, 2022, SAMPLING OF RECOVERY WELLS 4 Hemisphere Way, Bedford, OH 44146 1 verdantas.com February 2024 Document Number 15104.0014 APPENDIX C PROTOCOLS FOR PFAS SAMPLING j® verdantas 4 Hemisphere Way, Bedford, OH 44146 1 verdantas.com