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HomeMy WebLinkAbout17046_WLewisSt_VIR_20220315Pyramid Environmental & Engineering, P.C. Project #2022-021 Model Linen — W. Lewis Street SUB -SLAB VAPOR (SSV) ASSESSMENT REPORT WEST LEWIS STREET BROWNFIELDS PROJECT AT 109, 111, 117-B1 & MODEL LINEN BROWNFIELDS PROJECTS AT 120 W. LEWIS STREET GREENSBORO, NC (GUILFORD COUNTY) Brownfields Site Name: # 17046-13-041 : West Lewis Street BFA Brownfields Site Name: # 08007-04-041 : Model Linen BFA Report Prepared for: AZ Development, LLC Andy Zimmerman 111 W. Lewis Street, Greensboro, NC 27401 Email: andvz@azdev.biz Phone: (336) 255-4813 Date Prepared: 03-15-2022 Report Submitted to: BP Project Manager: Ms. Sharon Poissant Eckard, PG NCDEQ— DWM - Brownfields Program 1646 Mail Service Center, Raleigh, NC 27699-1646 Email: Sharon.Eckard@ncdenr.gov Phone: (919) 609-2617 Report Prepared By: `````�� AL 1168 Michael G. Jone , P ' License #1 C)tiq X�,`� �0i GA �\` -� % PYRAMID ENVIRONMENTAL & ENGINEERING, P.C. 503 INDUSTRIAL AVE., GREENSBORO, NC 27406 Email: Mike@pvramidenvironmentol.com Phone: (336) 335-3174 NC Geology License C-257 NC Engineering License C-125 Table of Contents 1.0 EXECUTIVE SUMMARY.................................................................................................. 1 2.0 INTRODUCTION............................................................................................................. 2 2.1 NCDEQ REQUESTED WORK............................................................................................. 4 2.2 BROWNFIELDS RECEPTOR SURVEY...................................................................................... 7 2.3 SOIL ASSESSMENT........................................................................................................... 7 2.4 GROUNDWATER ASSESSMENT SUMMARY............................................................................. 7 2.5 SUB -SLAB VAPOR SAMPLING............................................................................................. 8 2.6 DATA GAPS................................................................................................................... 8 3.0 SCOPE OF WORK........................................................................................................... 9 4.0 SSV WORK PLAN SUMMARY....................................................................................... 10 4.1 INDOOR AIR SAMPLING METHODOLOGY............................................................................ 10 4.2 CRAWL SPACE SAMPLING METHODOLOGY.......................................................................... 10 5.0 W. LEWIS STREET SITE - SSV SAMPLING & RESULTS ..................................................... 11 5.1 SSV & CRAWLSPACE SAMPLING....................................................................................... 11 5.2 CRAWL SPACE SAMPLING / 109 & 111 W. LEWIS STREET .................................................... 12 5.3 SSV SAMPLE RESULTS 115 W. LEWIS STREET................................................................... 12 5.4 SSV SAMPLE RESULTS 117 W. LEWIS STREET................................................................... 13 5.5 CRAWL SPACE SAMPLING / 117 B W. LEWIS STREET........................................................... 14 6.0 SAMPLE LOCATIONS & RESULTS - MODEL LINEN......................................................... 15 6.1 SSV SAMPLE RESULTS NORTHERN PART OF 120 W. LEWISSTREET...................................... 16 6.2 SSV SAMPLE RESULTS SOUTHERN PART OF 120 W. LEWISSTREET........................................ 17 7.0 NC BROWNFIELDS RISK ASSESSMENT.......................................................................... 17 8.0 CONCLUSIONS............................................................................................................. 18 9.0 CLOSING......................................................................................................................20 Page 1 Table of Contents (Continued) Figures Figure 1 : Topographic Map Figure 2 : Property Location Aerial Map Figure 3 : Area Map Showing Dry Cleaner Sites Figure 4 : Estimated Groundwater Flow Direction Figure 5 : Aerial Map with Proposed Sample Locations Figure 6 : Locations of CS Samples at 109 — 111 W. Lewis Street Figure 7 : Locations of SSV Samples at 115 — 117 W. Lewis Street Figure 8 : Locations of CS Samples at 117 B-1 W. Lewis Street Figure 9 : Locations of SSV Samples at 120 W. Lewis Street Tables Table 2.1 : Property Use Summary (page 2) Table 2.2 : Chronology of Events : Model Linen & W. Lewis Street Sites (page3) Table 2.3 : Address & Building Use Descriptions (page 5) Table 2.4 : Proposed SSV Sampling Locations (page 6) Table 5.0 : SSV/CS Results - Lewis Street Brownfields Properties Table 5.1 : Crawlspace Sample Results for 109 & 111 W. Lewis Street (page 12) Table 5.2 : SSV results for 115 W. Lewis Street (page 13) Table 5.3 : SSV Results for 117 W. Lewis Street (page 13) Table 5.4 : Crawlspace Results for 117 B W. Lewis Street (page 14) Table 6.0 : SSV Sampling Results for 120 W. Lewis Street Table 6.1 : SSV Sample Results of Northern Half of 120 W. Lewis Street (page 16) Table 6.2 : SSV Sample Results of Southern Half of 120 W. Lewis Street (page 17) Appendices Attachment A: NCDEQ Brownfields Letter (03-26-2021) Attachment B : 1996 to 2020 Assessment Maps & Analytical Tables Attachment C : Site Photos, Sanborn Map 1950, map of Foundation Types Attachment D : Vapor Pin Instructions Attachment E : Work Plan 2.3 Text Attachment F : Field Sheets from Air Sampling (Lewis Street) Attachment G : Pace Analytical Report (Lewis Street) Attachment H : Field Sheets from Air Sampling (Model Linen) Attachment I : Pace Analytical Report (Model Linen) Page 11 Acronyms AA.....................Administrative Agreement (REC Program) BFA ...................Brownfields Agreement BLS....................Below Land Surface CFR ...................Code of Federal Regulations COC ...................Constituent of Concern CS .....................Crawlspace DEQ..................Department of Environment Quality DSCA.................Drycleaner Solvent Cleanup Act EC .....................Environmental Consultant EMP ..................Environmental Management Plan (EMP) HASP ................. Health & Safety Plan HVAC ................Heating Ventilation and Air -Conditioning IHSB..................Inactive Hazardous Sites Branch IASL...................Indoor Air Screening Levels LURs .................Land Use Restrictions MSL...................Mean Sea level NIOSH...............National Institute for Occupational Safety and Health NCBP ................North Carolina Brownfields Program NVLAP...............National Voluntary Laboratory Accreditation Program OSHA ................Occupational Safety and Health Administration OVA ..................Organic Vapor Analyzer PCE...................Tetrachloroethene PDF...................Portable Document Format PID....................Photo-ionization Detector PPM..................Parts Per Million PSRGs ............... Preliminary Soil Remediation Goals PVC ...................Poly -vinyl Chloride QA ....................Quality Assurance QC.....................Quality Control SSV....................Sub-Slab Vapor PCE...................Tetrachloroethylene TICs ...................Tentatively Identified Compounds TCE...................Trichloroethylene USEPA...............United States Environmental Protection Agency VC.....................Vinyl Chloride VI ......................Vapor Intrusion VISLs.................Vapor Intrusion Screening Levels VOC ..................Volatile Organic Compounds US EPA..............United States Environmental Protection Agency Page III Pyramid Environmental & Engineering, PC PYRAMID 1.0 Executive Summary In the Fall of 2021, Pyramid was contacted by AZ Development to plan and complete Sub -Slab Vapor (SSV) and Crawlspace air sampling at the properties located at the Lewis Street and Model Linen Brownfields Sites. The location of these two sites are at addresses 109, 111, 115, 117, 117- -B, & 120 West Lewis Street in Greensboro, Guilford County, NC. The sites were previously operated as laundry and dry cleaning facilities during the 1950s. Since that time, all of the properties were accepted into the NC Brownfields Program (NCBP) under agreements # 17046- 13-041 (for W. Lewis Street) and # 08007-04-041 (for Model Linen). In 2020, during the process of combining Model Linen and West Lewis Street Brownfields Agreements, the NCBP observed that no Vapor Intrusion (VI) assessment was completed for the sites in the prior assessment. Due to this data gap, the NCBP required that a soil vapor survey be conducted for all of the properties under both Brownfields Agreements prior to combining the Brownfields sites. On October 27, 2021, Pyramid completed the final version of the work plan which was approved by the NC Brownfields Project Manager, and Pyramid was authorized to complete the work by AZ Development. The plan included the collection of twenty five (25) air samples (23 samples and two duplicates) as SSV and crawlspace samples in the various buildings. In December, Pyramid conducted the air sampling for 109, 111, 115, 117, and 117-B W. Lewis Street, the properties of the West Lewis Street Brownfields Site. The samples were collected in accordance with the approved work plan and submitted to Pace for analysis. After receiving access to the Model Linen Site, in January 2022, Pyramid collected SSV samples at 120 West Lewis Street. The samples were collected in accordance with the approved work plan for SSV sampling. The Model Linen SSV analytical results indicated high concentrations of Tetrachloroethylene (PCE) were detected above the Non Residential SSV Screening Levels in four of the Model Linen samples (SSV-14, SSV-17, SSV19, & SSV-21). All of the SSV samples showed PCE above the IASL standard. Three low detections of Trichloroethylene (TCE) were detected above the IASL and below the Non Residential SSV Screening Levels. Due to the PCE detections in the SSV and crawlspace samples at both sites, Pyramid reviewed the previous assessment data from 2003, 2004, and 2014 which showed PCE and TCE detections in groundwater. Since PCE concentrations were detected in groundwater and in the SSV completed at both sites, the site should be transferred into the Drycleaner Solvent Cleanup Act (DSCA) Program for further assessment and vapor mitigation. Indoor air sampling is recommended in the Boxcar and events spaces, and additional crawlspace samples are recommended to confirm concentrations in several areas (CS-2, CS-3, CS-12, and CS- 13) at the W. Lewis Street Brownfields Site. AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSVAssessment Report Page 1 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 Pyramid Environmental & Engineering, PC PYRAMID 2.0 Introduction On behalf of AZ Development, Pyramid Environmental & Engineering, PC (Pyramid) reviewed the NCDEQ letter dated March 26, 2021, requesting additional vapor intrusion assessment at the referenced Brownfield site addresses. The NCDEQ letter is presented in Appendix A for your reference. The NC Brownfields Program requested a Work Plan to provide the NCDEQ with details of the proposed sub -slab vapor (SSV) and crawl space (CS) vapor assessment requested by the Department. The site assessment history is summarized in this report. At the time of this report, efforts were underway to merge the Brownfield agreements for the following two Brownfields sites: • # 17046-13-041 : The West Lewis Street BFA is being written to combine the West Lewis Street site with the Model Linen Brownfields Site. • # 08007-04-041 : The Model Linen BFA was previously recorded, and review of the document showed that changes were necessary to the Brownfields Plat. At this time, the sites have not qualified for the Drycleaner Solvent Cleanup Act (DSCA) Program for further assessment and mitigation. A decision whether the sites should be in the DSCA program is being discussed. This SSV assessment addresses the NC Brownfields Program concerns about possible vapor intrusion from solvent or volatile organic contamination, and fills a "data gap". The following table presents the property information for the two sites. Table 2.1 — Property Use Summary NCBP Project # Address Parcel # Acreage Former Use REC Current Use 17046-13-041 109-111 W. Lewis 7864-63-1801 0.24 Furniture Store PCE & TCE in GW Pub & Office Spaces (W. Lewis BF) 115-117 W. Lewis 7864-53-9880 0.48 Dry Cleaners PCE & TCE in GW Pub, Brewery, distillery 08007-04-041 120 W. Lewis St. 7864-64-0041 0.50 Former Laundry PCE & TCE in GW Arcade, Bars, & (Model Linen) I I I I / Dry Cleaners I I Events Center As requested by the NC Brownfield Program (NCBP), this brief summary of the site history was completed as part of the SSV Work Plan. Pyramid met with the building owner at the properties to access each building areas and review what is known about the foundations. The buildings have differing foundation types that affected the collection of vapor samples. The following table presents brief history of the Brownfields Site assessment for the two sites. AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSVAssessment Report Page 2 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 Z Pyramid Environmental & Engineering, PC PYRAMID Table 2.2 Chronology of Assessment : Model Linen & W. Lewis Street Sites Date Description of Activity Decisions Made In September 1996, the former 5,000-gallon heating oil UST was removed from the 1996 courtyard in the NE corner of the Model Linen Site. The site map and analytical UST Pull results table are presented in Appendix B. TPH analyses from T-1 and T-2 showed DRO max 1,120 mg/kg elevated levels of GRO and DRO in soil under the tank. Depth to water was More Assessment approximately 9 feet, and additional assessment was indicated. is Indicated 2003 Soil and Groundwater assessment were completed for the site and identified petroleum contamination in both soil and groundwater above the residential Chlorinated Solvents MSCCs. In addition, several chlorinated compounds were identified in the identified in GW groundwater at location MW-1 at concentrations > the NCAC 2L Standards. including PCE 2004 Additional Groundwater assessment completed with installation of MW-2, MW-3, and MW-4 at the Model Linen Site. These wells were sampled, and groundwater Groundwater concentrations detected PCE in ( MW-1= 2.7 ug/L ), ( MW-2 = ND), ( MW-3 = 18 PCE Confirmed ug/L ), and (MW-4 deeper = 4.8 ug/L ). In addition, TCE and Vinyl Chloride were detected in MW-1 above the NCAC 2L Standards. 2014 The Model Linen Site is accepted into the Brownfields Program and redevelopment is started. Oct 2014 NCBP approval of the Brownfields Program eligibility for West Lewis Street site and expansion parcels. This work was preceded by Phase I And Phase II Assessments NCDEQ Accepted and these data were used in the eligibility application. The Brownfields site was West Lewis St. Into Re -developed starting in 2014. In August 2014, temporary MWs were installed and Brownfields Program sample at the West Lewis site and showed petroleum compounds detected in TMW-1 and TWM-4, and PCE and TCE detected in MW-3 at concentrations > 2L. Aug 2016 Former Odorless Dry Cleaners site is investigated and PCE is detected in 13 of 20 DSCA Site sample soil -gas locations. Dec 2016 groundwater impacts are found at the site, Acceptance for and Odorless is accepted as a DSCA site ( DC-410047 ). The location is Odorless DC topographically lower than Lewis Street, and is 250 feet SW of the site. March 2017 March 2017, PCE detected at former Wades Dry Cleaners in soil and groundwater. DSCA Site April 2017 site accepted in the DSCA program ( DC-410052 ) and is approximately Acceptance for 300 feet east of the Lewis Street Site and is topographically downhill of the Lewis Wades DC Street and Model Linen Brownfields Sites. 2021 - 2022 Additional assessment is completed for the Model Linen and West Lewis Street Brownfields sites to address the data gap of Sub -Slab vapor assessment. This SSV Sampling at both report presents the results of the sampling and analytical results for the site. Brownfields Sites Based on the presence of prior detections of PCE in the groundwater and soil at the site, and the absence of comprehensive SSV and Crawlspace analytical data the NCDEQ required additional assessment to fill the data gap for both Brownfields Sites. Selections of maps and tables from the above -referenced reports are included in Appendix B. AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSVAssessment Report Page 3 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 Z Pyramid Environmental & Engineering, PC PYRAMID 2.1 NCDEQ Requested Work The NC Brownfields Program requested additional sub -slab vapor data for both the Model Linen and West Lewis Street properties based on the detection of petroleum compounds benzene, naphthalene, PCE, TCE, and 1-methylnaphthalene in groundwater at 120 Lewis Street (MW-3). There was also a detection of trichloroethylene (TCE) in the groundwater at MW-3 (1.2 µg/L). Based on these VOC detections, the NCDEQ determined that there was a "data gap" for sub -slab vapor data. The historical data from one sub -slab sample collected in 2014 in the southeast area of 109 W. Lewis indicated a low concentration of TCE and other volatile organic compounds (VOCs), including the daughter products of TCE, which were present in the 2014 SSV sample. The VOCs include chlorinated compounds that are considered contaminants of concern (COCs). The NCDEQ Brownfields program requested SSV/CS sampling in the buildings to assess vapor intrusion risk, and the letter requesting the assessment is presented in Appendix A. Pyramid researched additional site history and has summarized the historical soil and groundwater data with excerpts from the reports in Appendix B. The prior reports show levels of petroleum and chlorinated solvents present on the site in prior soil and groundwater analyses. At this time, no new structures or foundation changes are planned. The current property uses include several pubs with food service, a craft brewery, a distillery, offices, storage, and a video game arcade, and event spaces. The property uses will remain consistent with the current use for the foreseeable future, and no new construction or residential uses are planned. Pyramid planned the SSV sampling with the building owner and tenants. The sample areas are separated by structural walls and differing foundation types. In preparing the SSV and crawl space sampling work plan, these factors were taken into consideration. The owner's information, photographs, and maps were helpful in understanding the foundations, and are included in Appendix C. The following Figures are provided as further explanation of the work. Figure 1 - Topographic Map Figure 2 - Property Location Aerial Map Figure 3 - Surrounding Area Map — Dry Cleaners Figure 4 - Estimated Groundwater Flow Direction Figure 5 - Aerial Map with Proposed Sample Locations Figure 6 - Locations of CS Samples at 109 —111 W. Lewis Street Figure 7 - Locations of SSV Samples at 115 —117 W. Lewis Street Figure 8 - Locations of CS Samples at 117 B-1 W. Lewis Street Figure 9 - Locations of SSV Samples at 120 W. Lewis Street AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSVAssessment Report Page 4 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 Z Pyramid Environmental & Engineering, PC PYRAMID The sampling strategy for each location is explained in the table below, with the foundation type and sample method described. Table 2.3 Address - Building Size & Foundation Descriptions SCOPE of During Work Plan review and discussions, the NCDEQ requested more SSV/CS locations for the SSV Study. WORK The NCDEQ general guidance refers to one sample per 1,000 square feet. Pyramid discussed locations with the DEQ and the agreed upon SSV sample locations are presented on Figure 5. The 109 W. Lewis pub is 2,697 square feet of renovated space, constructed in a foundation wall with post 109 W. and beam construction. The current floor is a thick wooden plank floor which was built using joists, a Lewis plywood deck, and then the 3.5 inch thick wooden plank floor. The wooden floor was constructed over a former concrete floor, and therefore will be considered as crawlspace samples. The DEQ requested ( 2 ) samples which are considered crawlspace samples (CS-1 and CS-2) which are shown on Figure 6. This area is 5,828 square feet of office space, constructed inside a foundation wall with post & beam. The 111 W. current floor is a thick wooden floor which was built using joists, a plywood deck, and then the 3.5 inch Lewis thick wooden plank floor. The wooden floor was constructed over a former concrete floor and therefore will be considered crawlspace samples. For this area, the (4 ) crawlspace vapor samples will be collected (CS-3, CS-4, CS-5, and CS-6) at the locations shown on Figure 6. 115 W. This area is currently the Fainting Goat Distillery which has a new concrete floor. The distillery is separated Lewis by a concrete block wall from the brewery to the west. The distillery is 3,666 sq. ft., and is the eastern half Distillery of the area the Sanborn Map indicated as "Dry Cleaner". The DEQ requires (2) SSV samples (SSV-7 and SSV-8) as shown on Figure 7. It is possible that the new concrete slab may have been poured over the older slab in this area; a crawlspace is not expected. 117 W. This area is currently the South End Brewery which was also has a new concrete floor. The brewery is the Lewis western % of the building, and is separated from the distillery to the east by a concrete block wall. The Brewery brewery is 3,564 sq. ft. of the building, and is the west half of the area the Sanborn Map indicated as "Dry Cleaner'. The DEQ requires (3) SSV samples (SSV-9, SSV-10, & SSV-11) as shown on Figure 7. 117 B-1 The entire pub (3,737 sq. ft.) is constructed over a crawlspace area below the wooden floor. The DEQ Crawlspace requested (2) crawlspace samples (CS-12 and CS-13) as shown on Figure 8. The samples will be collected at least 10 feet from the exterior walls and will be compared with the IASLs. Northern This area was in the middle of a renovation to be used as an events center and bar. The area was cleared, 120 Lewis and the concrete floor was exposed for sampling. The area is slab -on grade construction with an outside Events paved courtyard in the NE corner. The northern part had ( 4 ) proposed SSV samples (SSV-14 through Areas SSV-16) to evaluate the area ( see Figure 9). The small "Courtyard" in the NE corner of the property will be investigated with SSV-15. Southern The Boxcar has an event space, 2 bars, and a game room covering about 70 % of the total area. The 120 Lewis building is slab on grade with plumbing entering on the east side. The SSV points (SSV-18 through SSV- BOXCAR 23) are shown on Figure 9, and cover the Boxcar area of 9,900 square feet with ( 6 ) SSV samples to evaluate this area. The SSV locations are shown on Figure 5 and described on the table below. AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSVAssessment Report Page 5 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 � n N r ro c a, rb rr a° o r3 n \ ro a o R� rp rr r— m rb S. Z' Z3 ro up ro H -v, ^ nrb I s ro Table 3 - proposed S;SV Samples Summary The locations of the Samples are shown on Figure 5 Sample Number Address / Sample Location in Building Sample Objective Sample Type Sample Namat Sample Depth Analytical program TCEAnalyticulRange 1 109 W. Lewis St.: Bar SG%VI Initial Assessment Crawl Space CS-1 61' Level II <0.196, u8Jm3; 2 109 W. Lewis St.: Bar SG%VI Initial Assessment Crawl Space CS-2 C'. Leval II <0.196. ugJm3; 3 111 W. Lewis: Offices SG%VI Initial Assessment Crawl ,';pace CS-3 0- Lew-d II <0.196 ugJm3 4 111 W. Lewis: Offices SG% VI Initial Assem.ment Crawl Rpace CS-4 S"' Leval II <0.196, ug/m3: 5 111 W. Lewis: Offices SG%VI Initial Assessment Crawl Space CS-5 6"' Level II <0.196, u81m3 6 111 W. Lewis: Offices SG/VI Initial Assessment Crawl Space CS-6 C'. Level II <0.196 u„Jm3 7 115 W. Lewis : Distillery SG%VI Initial Asses: ,ment SSV S.;V-7 G"' Level II <0.194. uerJm3; B 115 W. Lewis : Distillery SG%VI Initial Aoe%s:ment SW SSV 8 h'. Level II <0.19h, ugJm3 9 117 W. Lewis St.: Brewery SG%VI Initial Assessment SSV SSV 9 6'. Leval II <0.196, u81m3 10 117 W. Lewis St.: Brewery SG/VI Initial Assessment SSV SSV-10 G"' Level II <0.19G ugJm3; 10 Dup. 117 W. Lewis St.: Brewery Duplicate - Sample Day 1 5SV SSV-10 Dup C"' Level II <0.19f.. ugJm3, 31. 117 W. Lewis St.: Brewery SG%VI Initial A,ses,5:ment SSV SK _11 h"' Lead II <0.19h, ugJm3 3.2: 117 B1 W. Lewis St.: Brew Pub SG%VI Initial A:;ser;�:ment Crawl Space C5 12 Air 1-mol II <0.196, u8Jm3; I 117 B1 W. Lewis St.: Brew Pub SG/VI Initial Assessment Crawl Space CS 13 Air Level II <0.196, ugJm3; 14 120 W. Lewis (N) :: NW Corner SG/VI Initial Assessment SW °"V-14 d" Lvv.c!l II <0.196, ug/m3; 1S 120 W. Lewis (N) :: NE Corner Courtyard SG%VI Initial Assessment SSV SSV-1'5 6'. Level II <0.196. ugJm3; 169 120 W. Lewis (N) :: SE Corner SG/'VI Initial Assessment SSV SSV-1E5 61' Level II <0.196. ugJm3; 17' 120 W. Lewis (N) :: SW Corner SG%VI Initial Assessment 5SV SSV-17 C"' Level II 4.196. ugJm3; 1°s 120 W. Lewis - BOXCAR: NW corner SG/VI Initial Assessment SSV 51SV-'18 61' Lv.va:l II <0.196, ugJm3 153 120 W. Lewis - BOXCAR: N central SG%VI Initial Assessment 55V 5SV-19 6"' Leval II <0.196�JL'3; 20 120 W.Lewis- BOXCAR:NEcorner SG/VlInit:ial Assessment 55V SSV-20 6'. Level11 <0.196�JL3; 21. 120 W. Lewis - BOXCAR : SE corner SG/VI Initial Assessment III' SV SSV-21 Li". Loved II <0.196, ugJm3; 22' 120 W. Lewis - BOXCAR: S Central SG%VI Initial Asse-s:ment Y;V SW_22 h"' Level II <0.196, ud/M:1; 2.l; 120 W. Lewis: BOXCAR: SW Corner SG%VlInitial Asseaaument SW SSV-2:3 h" Lnva^III <0.1Ih.�g/M3; 23 Dup 120 W. Lewis: BOXCAR: SW Corner Duplicate:: Sample Day 2 55V SSV-23 •Dup 6'. Level II <0.1967 ug/m3; There are no basement, stairwells, elevator_, or residential property use in the Brownfields Property Buildings. 0 Pyramid Environmental & Engineering, PC PYRAMID 2.2 Brownfields Receptor Survey The site location is in downtown Greensboro at an approximate elevation of 835 feet above mean sea level (msl). The area is near the topographic high along West Lewis Street, and surface water from the site appears to move to the south and southeast toward a nearby surface water stream. The closest surface water is located about 1,400 feet south of the site, and flows to the south. Pyramid conducted a receptor survey and searched for water supply wells within 1,000 feet of the site. In addition, the Guilford County Water Department was contacted to confirm that all properties within 1,000 feet are connected to City water. Pyramid did not observe any drinking water wells within 1,000 feet of the site and all properties have access to city water. In addition, Pyramid completed a search for other dry cleaner facilities within % mile of this location. The nearest DSCA site is Wades Dry Cleaners located 300 feet east from the Model Linen site and located at a lower elevation. The Model Linen and W. Lewis Brownfields sites are topographically at a high point in the surrounding area and do not receive surface water flow from other properties. The map from Hart& Hickman showing the Wades Dry Cleaner site (DC410052) is presented in Appendix B along with the Former Odorless Dry Cleaners site. The resulting map of locations from the DSCA Program map is presented as Figure 3. 2.3 Soil Assessment The Model Linen UST removed in 1996 was investigated and the details are presented in Appendix B. The 2013 soil assessment prior to Brownfields Program acceptance showed petroleum and chlorinated solvents present at the sites and recommended additional assessment to evaluate volatile organic compounds (VOCs) beneath the buildings. 2.4 Groundwater Assessment Summary Previous groundwater assessment was reported and identified benzene, naphthalene, PCE, TCE, and 1-methylnaphthalene above NCAC 2L groundwater standards. A typical conceptual site model for the site includes shallow groundwater between 8-feet to 11-feet below land surface (BLS), within the surficial aquifer. The near surface soil and saprolite aquifer generally persists to a depth or approximately 45-55 feet and is followed by weathered granitic rock. The bedrock in the Greensboro area is generally encountered between 55 to 65 feet below land surface, depending on differential weathering. Dissolved Constituents of Concern (COCs) were detected in the shallow aquifer zone. The 2013 potentiometric surface map is presented as Figure 4. The VOCs detected in groundwater prompted the NCDEQ to request the SSV sampling work plan. AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSV Assessment Report Page 7 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 Z Pyramid Environmental & Engineering, PC PYRAMID 2.5 Sub -Slab Vapor Sampling The former Model Linen operated on both the north and south sides of Lewis Street at 120 Lewis Street (north side) and 117 Lewis Street (south side). The NC Brownfields Program requested SSV data for both the Model Linen and West Lewis Street properties. The Brownfields Program requirements are based on the detection of petroleum and solvents in the groundwater at the Model Linen Site and the lack of sufficient sub -slab vapor assessment data. The historical data from one sub -slab sample collected in 2014 in the southeast area of 109 W. Lewis Street indicated a low concentration of TCE and other VOCs, including the daughter products of TCE present in that sample. The NC Brownfields Program requested additional SSV sampling in each of the buildings to assess vapor intrusion risk. Future development includes no new buildings on the properties, no planned residential use, nor removal of buildings or foundations. Although there is no current residential use, the Brownfields Agreement was to be written to allow residential use of the properties as a potential future use. Each building is connected to public utilities including water, sewer, Duke Energy electric, telecommunications, and natural gas. 2.6 Data Gaps The Brownfields Program identified the lack of SSV data as a data gap and required additional SSV assessment data to be collected for the buildings at both sites. The Work Plan included the methods, procedures, and quality assurance used for the recent SSV assessment. The property use and additional considerations are presented below. • Redevelopment plans will not include new structures on the properties • No foundation changes are proposed, and each building is connected to public utilities • There are no basements in the buildings • One crawl -space is accessible ( underneath Brew pub at 117-B West Lewis Street ) • There are no elevators or enclosed stairwells in the buildings • Parking is outside on paved surfaces and along the street • Building square footage is report on Figure 5 and no buildings are being added • There are two other dry cleaning facilities reported within 300 feet of the site The subsurface and crawl space sampling locations and rationale are described in the work plan document previously submitted to the NCBP. AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSVAssessment Report Page 8 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 Z Pyramid Environmental & Engineering, PC PYRAMID 3.0 Scope of Work The work scope is to provide SSV/CS sample collection and analysis from the various structures on the two Brownfields sites, and the locations are shown on Figure S. The sample type depends on the floor configuration and whether it is a crawlspace or slab on grade. The primary tool used is the Vapor PinTI which is a stainless steel device which allows penetration of the concrete slab or 4" thick wooden floor, and seals the penetration allowing a vapor sample to be collected from the air -space below. The VaporPinT"^ sample devices were installed and left in place to be used again if needed. Vapor sampling procedures were detailed in the approved work plan, and the methods used were the same as proposed. No sealants or glues were used, and the SSV installations all passed the helium leak check at each location. The materials used were consistent with the work plan and the details of each installation and sampling were recorded in the field form for each location sampled. The PID readings and other observations made during the SSV installations and sampling of the SSV/CS samples were recorded and are presented in this report. The final SSV/CS sample locations are shown on Figure 5. The SSV sampling was completed using Vapor PinT"^ devices in each sample location, and the Vapor PinT"^ description and installation procedures are summarized in Appendix D. Vapor sampling was arranged with the property owners and each tenant, and the work was completed during normal business hours. After installation of the VaporPinsT"^, each pin was purged, sealed, and protected with a stainless steel cover. The sample collection required 25 cylinders from the laboratory which required planning and took several weeks to acquire. The field collection of air samples was documented for each location on the field forms, and a duplicate sample was collected for each field day. The work was scheduled in December and was delayed in the Boxcar (Model Linen site) due to access concerns. A duplicate sample was obtained at location SSV-11 near the words "Dry Cleaners" on the old Sanborn Map. A second Duplicate was collected at SSV-23 which was closest to the groundwater detection of petroleum and TCE in MW-3. These were the most likely areas for detections of chlorinated solvents at the two Brownfields sites. AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSVAssessment Report Page 9 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 Z Pyramid Environmental & Engineering, PC PYRAMID 4.0 SSV Work Plan Summary Pyramid completed the SSV/CS Work Plan which included the comments and changes required by the NCDEQ Brownfields Program. Once the Work Plan was approved, sampling materials and Pace Analytical laboratory sample cylinders and TO-15 analyses were arranged. Each sample point contained a separate vapor pin which was installed by either drilling through the concrete slab of the building, or drilling into the crawl space. Each vapor pin sample point was checked for leaks using helium flooded containment and helium detector prior to being sampled. In addition, duplicate samples were collected for each day air samples were collected. A detailed description of the methodology for SSV Sampling, Indoor Air Sampling, and Crawl Space Sampling is included in the Work Plan presented in Appendix E. The SSV sampling was conducted using separate Vapor PinT" devices installed the concrete or thick wooden floor. Prior to sampling, each vapor pin was purged and checked for leaks. 4.1 Indoor Air Sampling Methodology The initial sampling plans did not include any indoor air samples. The crawlspace samples collected are considered indoor air samples by DEQ for comparison with the appropriate IASLs. It is possible that indoor air samples will be necessary in the future. The work plan in Appendix E lists the details that may be required in the future should indoor air sample be needed. 4.2 Crawl Space Sampling Methodology The accessible crawl space sample locations are designated CS-12 and CS-13. Samples CS-1 through CS-6 were collected below a substantial 4-inch thick wooden floor, and are considered inaccessible crawl space samples. Sampling procedures included : • Under 117 B-1 Lewis Street, the crawl space has a dirt floor and no moisture barrier • The ceiling of the crawl space is wooden joists and a wooden floor below a Pub • The crawl space has 4 foundation vents and a small access door on the western wall • Crawl space height varying from 30 inches to less than 10 inches for CS-12 and CS-13. • There is a perimeter concrete wall and foundation piers in the crawl space area • For CS-1 through CS-6, the thick wooden floor will be penetrated with VaporPins' These samples were all collected as proposed and there were no significant changes from the work plan location or procedures. AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSVAssessment Report Page 10 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 Z Pyramid Environmental & Engineering, PC PYRAMID 5.0 W. Lewis Street Site - SSV Sampling & Results The W. Lewis Street Brownfields site (BFA # 17046-13-041) is located on the south side of W. Lewis Street, and contains several buildings. The site contains one building with a wooden floor (addresses 109 & 111 W. Lewis Street), two building areas separated by a concrete wall with a concrete slab over soil ( 115 & 117 W. Lewis St.), and one building which has a wooden floor over an open crawlspace (117-B W. Lewis Street). Currently these spaces are occupied by transient tenant workers and customers for uses included a co -working and meeting space, a distillery, a brewery, and brew pub. The field forms are presented in Appendix F for each sample location, and the Pace Analytical results are presented in Appendix G. 5.1 SSV & Crawlspace Sampling To access the area beneath the wooden floors and concrete slabs, Pyramid drilled and installed VaporPinT" devices according to manufacturer instructions. Before starting with installation of VaporPinsT"^ in the thick wooden floor area, Pyramid consulted with the manufacturer to confirm that the devices were approved for this purpose. The floor was composed of an upper 3.5-inch thick planking and a %-inch plywood sub -floor over joists. The manufacturer approved the use of the vapor pins for installation in this 4.25 thick wooden floor system, as well as the 4 to 6-inch thick concrete slab floors at the other SSV locations in 115 & 117 West Lewis Street. The SSV/CS sample ports were installed on December 14, 2021. Each vapor pin was secured with a tight- fitting plastic cap on the sample point, and the stainless steel lid was secured at the surface. Pyramid returned on December 15, 2021, to collect the SSV/CS samples as proposed in the workplan. Each sample location was set-up with the tubing secured to the VaporPinT"", the tubing and connections contained in a sealed plastic tote, flooded with helium, and a leak check was performed at each location. Each location was purged using the three-way valve and syringe to remove 1200 milliliters of air which was placed in a TedlarT" Bag. After sealing the tubing, the TedlarT"^ bag was compressed and the helium meter was used to read the helium level in the TedlarT" bag. The leak check for each samples showed no helium was detected in the TedlarT"" bag. Once the leak check was performed, the samples were collected by opening the sample valve and recording the vacuum readings as the samples were collected. The flow -controllers were in place for all 6-liter cylinder sample containers, and the samples were collected over a 20 to 40 minute period. AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSVAssessment Report Page 11 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 Z Pyramid Environmental & Engineering, PC PYRAMID The sample cylinder valves were closed at about 8 inches of vacuum remaining, and were secured with the stainless steel cap on each cylinder. The samples were labelled, and the sample documentation was completed at the site. The samples were packaged in the Pace shipping boxes, and shipped FeclEx using standard chain -of -custody procedures. The analyses requested were the TO-15 Low Level analyses. A summary Table of the West Lewis Street Brownfields Site are summarized in Table 5.0 in the Tables Section of this report. The results for the Lewis Street Brownfields Site samples are discussed further in the following sections. 5.2 Crawl Space Sampling / 109 & 111 W. Lewis Street As defined in the work plan, two (2) samples (CS-1 & CS-2) were collected at 109 W. Lewis Street and four (4) samples (CS-3, CS-4, CS-5, CS-6) were collected at 111 West Lewis Street. The sample location map is presented as Figure 5, and the specific sample locations are shown on Figure 6. Copies of the data sheets documenting the installation, floor thickness, leak check, length of the test, PID readings, and crawl space observations are included in Appendix F. The results from the air samples collected at 109 and 111 W. Lewis Street are presented in Appendix G, and the results are summarized in the table below. Table 5.1 Crawlspace Sample Results / 109 & 111 W. Lewis Street Non -Res. SSV Sample ID CS-1 CS-2 CS-3 CS-4 CS-5 CS-6 Screening levels IASL ug/m3 ug/m3 ug/m3 ug/m3 ug/m3 ug/m3 ug/m3 ug/m3 Benzene 1.5 3.0 2.7 1.1 1.1 1.2 160 1.6 Trichloroethylene (TCE) ND 3.3 ND ND ND ND 180 1.8 ug/m3 = Micrograms per cubic meter Bold — values are above IASL standards ND = Not detected above laboratory reporting standards The concentrations of benzene were detected in CS-2 and CS-3 at concentrations just above the Indoor Air Screening Level (IASL) but below the Non -Residential Soil -Gas / SSV Screening Levels. In CS-2, Trichloroethylene (TCE) was detected concentrations just above the IASLs but below the Non -Residential Soil -Gas / SSV Screening Levels. All other compounds were either non -detect or were detected below the IASL levels. 5.3 SSV Sample Results / 115 W. Lewis Street On December 14, 2021, Pyramid mobilized to 115 W. Lewis Street to install the VaporPinsTm at each location proposed in the Work Plan. Two (2) sample locations (SSV-7 and SSV-8) were collected at 115 W. Lewis Street, and the locations are shown on Figure 5 and Figure 7. AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSVAssessment Report Page 12 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 Pyramid Environmental & Engineering, PC PYRAMID A copy of the field data sheets documenting the installation, development, leak check, PID readings, duration of sample collection, and observations are included in Appendix F. A summary of the compounds detected at 115 W. Lewis Street are summarized in the table below. The Pace Analytical lab report for the samples is included in Appendix G. Table 5.2 SSV Sample Results / 115 W. Lewis Street Sample ID SSV-7 ug/m3 SSV-8 ug/m3 Non Res. SSV Screening level ( ug/m3) Indoor Air Screening level ( IASL) ug/m3 Benzene ND 2.7 160 1.6 Chloroform 3.5 ND 53 0.53 Tetrachloroethylene (PCE) ND 69.1 3500 35 ug/m3 = Micrograms per cubic meter Bold — values are above Non -Res. SSV standards ND = Not detected above laboratory reporting standards The concentrations detected in the SSV samples collected in this concrete slab area were compared with the Non -Residential Screening Levels. Concentrations detected were below the non-residential screening levels for all compounds. The detected levels of benzene, chloroform, and PCE were above the IASLs; however, these lower limits do not apply to this space. In additional, the detection of ethanol in SSV-8 indicates that some level of the distillery products was detected. All detected concentrations were below the Non -Residential Soil -Gas/ SSV Screening Levels. All other compounds were below detections limits or below the IASLs. 5.4 SSV Sample Results / 117 W. Lewis Street On December 15t", 2020, Pyramid also collected SSV-9, SSV-10, SSV-11, and SSV-11 Dup air samples. The duplicate sample collected was near the location of the Sanborn Map label Dry Cleaners. The specific sample locations are shown on Figure 5 and Figure 7. Copies of the data sheets for the samples are included in Appendix F, and the Pace Analytical report for the samples is included in Appendix G. A summary of the compounds detected at 117 W. Lewis Street are summarized in the table below. Table 5.3 SSV Sample Results / 117 W. Lewis Street Sample ID SSV-9 ug/m3 SSv-10 ug/m3 SSV-11 ug/m3 SSV-11 DUP ug/m3 Non Res. SSV Screening levels (ug/m3) (IASL) ug/m3 Chloroform ND 1.9 1.7 1.9 53 0.53 2-Propanol 870 2,690 23.4 28.9 1800 180 Tetrachloroethylene (PCE) 130 177 46.5 52.9 3500 35 Trichloroethylene (TCE) ND ND 2.3 2.5 180 1.8 ug/m3 = Micrograms per cubic meter Bold — values are above Non -Res. SSV standards ND = Not detected above laboratory reporting standards AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSVAssessment Report Page 13 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 Z Pyramid Environmental & Engineering, PC PYRAMID The concentrations of 2-Propanol in SSV-9 is above the Non -Residential Soil -Gas / SSV Screening Levels; however, this isopropyl alcohol concentrations is likely related to the brewing of beer. The presence of the brewery in this space is the most likely source of the isopropanol detected, and may be related to infiltration of liquids into the subsurface from drains or washdown of the slab. Although PCE was detected in all three samples and the duplicate sample the levels were below the SSV non-residential standard. Trichloroethylene (TCE) was present at concentrations and below the Non Residential standards. All other compounds were either not detected, or below the IASL levels. 5.5 Crawl Space Sampling / 117 B W. Lewis Street On December 15th, 2020, Pyramid also collected crawlspace samples under the brew pub located at 117-B W. Lewis Street. As defined in the work plan, two sample CS-12 and CS-13 were collected at the locations shown on Figure 5 and Figure 8. Copies of the field data sheets are included in Appendix F, and the Pace Analytical laboratory report is presented in Appendix G. A summary of the compounds detected is presented in the table below. Table 5.4 Crawlspace Sample Results / 117-B W. Lewis Street Sample ID CS-12 ug/m3 CS-13 ug/m3 Non Res. SSV Screening levels ug/m3 IASL ug/m3 Tetrachloroethylene (PCE) 381 76 3500 35 ug/m3 = Micrograms per cubic meter Bold — values are above IASL standards ND = Not detected above laboratory reporting standards The detected concentrations of PCE in CS-12 and CS-13 were detected at concentrations above the Indoor Air Screening Level (IASL) but below the Non -Residential Soil -Gas / SSV Screening Levels. All other compounds were either not detected or were below the IASL levels. It is important to note that according to DEQ guidance, the overall risk regarding air samples is to be based on the effects to human health as calculated through the July 2020 DEQ Risk Calculator rather than screening levels. AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSVAssessment Report Page 14 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 Pyramid Environmental & Engineering, PC PYRAMID 6.0 Sample Locations & Results — Model Linen The Model Linen Brownfields site (BFA # 08007-04-041 ) is located on the north side of W. Lewis Street. The former Model Linen site contains one building with several dividing walls and a courtyard area at the northeast corner of the property. The flooring over the entire area is slab on grade construction on top of soil. At the time of the SSV assessment, the area was being renovated to serve as an event space in the northern % of the building, and the southern half was still used as the Boxcar Arcade and bar. Currently these spaces are occupied by transient tenant workers and customers. The field forms completed for each sample location installation for the SSV/CS sample devices (VaporPinsT"°) are presented in Appendix H and the Pace analytical results are presented in Appendix I. To access the soil vapors below the slab, Pyramid drilled and installed VaporPinT", devices according to manufacturer instructions. The SSV sample ports were installed on Friday January 14, 2022, and each vapor pin was secured with a tight -fitting plastic cap on the sample point, and the stainless steel lid was secured at the surface. Pyramid returned on January 19, 2022, to collect the SSV/CS samples as proposed in the workplan. Each sample location was set-up with the tubing secured to the VaporPinT"", the tubing and connections contained in a sealed plastic tote, flooded with helium, and a leak check was performed at each location. Each location was purged using the three-way valve and syringe to remove 1200 milliliters of air which was placed in a TedlarT" Bag. After sealing the tubing, the TedlarT"^ bag was compressed and the helium meter was used to read the helium level in the TedlarTm bag. The leak check for each samples showed no helium was detected in the TedlarT"^ bag. Once the leak check was performed, the samples were collected by opening the sample valve and recording the vacuum readings as the samples were collected. The flow -controllers were in place for all 6-liter cylinder sample containers, and the samples were collected over a 20 to 40 minute period. The sample cylinder valves were closed at about 8 inches of vacuum remaining, and were secured with the stainless steel cap on each cylinder. The samples were labelled, and the sample documentation was completed at the site. The samples were repackaged in the Pace shipping boxes, and shipped FeclEx using standard chain -of -custody procedures. The analyses requested were the TO-15 Low Level analyses. The analytical results for 120 Lewis Street are summarized on Table 6.0 included in the Tables Section of this report. The results for the Model Linen Brownfields Site samples are presented in the following sections. AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSVAssessment Report Page 15 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 Z Pyramid Environmental & Engineering, PC PYRAMID 6.1 SSV Sample Results / Northern Part of 120 W. Lewis Street. In December 2021, Pyramid awaited access to the 120 W. Leis Street site before planning the VaporPin'll installations. After receiving property owner approval, installation of the SSV points were completed on January 14, 2022. The SSV locations in the northern area of the Boxcar events center were completed as proposed in the work plan with four locations (SSV-14, SSV-15, SSV-16 and SSV-17) installed in the northern part as shown on Figure 5 and Figure 9. After a holiday delay and an ice delay, on January 19, 2022, Pyramid collected the SSV samples at each location at the site. A copy of the data sheets documenting the installation, purging, leak check, PID readings, length of the test, final vacuum readings, and other observations are included in Appendix H. The analytical lab report for the samples is included in Appendix I. Table 6.1 SSV Sample Results / Northern Part of 120 W. Lewis Street Sample ID SSV-14 ug/m3 SSv-15 ug/m3 SSV-16 ug/m3 SSV-17 ug/m3 Non Res. SSV Screening levels (ug/m3) (IASL) ug/m3 Chloroform ND 2.9 ND ND 53 0.53 Tetra chIoroethylene (PCE) 10,100 254 1,160 10,500 3500 35 Trichloroethylene (TCE) 9.5 ND ND ND 180 1.8 Yellow Values are above Non Residential SSV Screening Levels Bold — values are above IASL standards ND -Not detected above laboratory reporting standards ug/m3= Micrograms per cubic meter The SSV results for the northern half of the former Model Linen site all showed elevated levels of PCE. The concentrations of PCE were above the Non -Residential SSV Screening Level in SSV-14 and SSV-17, with results showing PCE above 10,000 ug/m3 below the concrete slab. These results indicated a former source of PCE used at the site during the time of the former Model Linen Dry Cleaners. The results for all other parameters within the analysis were affected by the dilution required to quantify the elevated PCE concentrations. The results showed few other parameters as shown in the table above. The results were compared to the non-residential SSV Screening Levels and the PCE levels were above the screening levels. A quick calculation was performed using the Brownfields Risk Calculator for the site, and the results were also above the site specific criteria which calculated to the same non-residential screening levels stated above. Trichlorethylene (TCE) was detected in SSV-14, but below the non-residential screening level. Other compounds were below the method detections limits (which were elevated by dilution) or were not detected. AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSVAssessment Report Page 16 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 Pyramid Environmental & Engineering, PC PYRAMID 6.2 SSV Sample Results / Southern Part of 120 W. Lewis Street. On January 14, 2022, six (6) SSV locations were installed in the southern part (Arcade and Event Space of the Boxcar (SSV-18, SSV-19, SSV-20, SSV-21, SSV-22, and SSV-23). These locations are show on Figure 5 and Figure 9. After a holiday delay and an ice delay, on January 19, 2022, Pyramid collected the SSV samples at each location at the site. A copy of the data sheets documenting the installation, purging, leak check, PID readings, length of the test, final vacuum readings, and other observations are included in Appendix H. The analytical lab report for the samples is included in Appendix I. Table 6.2 SSV Sample Results / Boxcar Area - 120 W. Lewis Street Sample ID SSV-18 ug/m3 SSV-19 ug/m3 SSV-20 ug/m3 SSV-21 ug/m3 SSV-22 ug/m3 SSV-23 ug/m3 SSV-23 (Dup) ug/m3 Non Res. Screening levels IASL ug/m3 Chloroform 3.4 ND ND ND ND ND ND 53 0.53 Tetrachloroethylene (PCE) 105 4,020 1,300 3,750 1,710 471 454 3500 35 Trichloroethylene (TCE) ND I ND I ND I ND I ND 1 8.7 1 9.1 180 1.8 Yellow Values are above Non Residential SSV Screening Levels Bold — values are above IASL standards ND -Not detected above laboratory reporting standards ug/m3= Micrograms per cubic meter In all of the SSV Samples in the Boxcar area, concentrations of PCE were detected at levels above the IASL, and only at SSV-19 and SSV-21 were the PCE levels detected above the Non -Residential Screening Levels. The primary and duplicate sample at SSV-23 (SSV-23 and SSV-23 Dup.) were similar in detected compounds and concentrations showing appropriate sample collection was achieved. The compound TCE was present but below the Non -Residential Soil -Gas Screening Levels. All other compounds were either not detected (presumably due to high PCE concentrations and the elevated dilution of the samples), or not detected above method detections limits. 7.0 NC Brownfields Risk Assessment As part of the data evaluation for the two sites, Pyramid processed the data for the site thorough the NC DEQ Risk Calculator for PCE and TCE. The evaluation of the primary two Constituents of Concern (PCE and TCE) resulted in a site risk similar to the Non -Residential Soil -Gas Screening level of 3,500 ug/m3 for PCE and 180 ug/m3 for TCE. AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSVAssessment Report Page 17 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 Z Pyramid Environmental & Engineering, PC PYRAMID The IASLs were also confirmed to be close to 35 ug/m3 for PCE and 1.8 ug/m3 for TCE. Based on the risk data evaluation, and the risk to tenants, workers, and customers, Pyramid recommends collecting additional air samples in each space as described below : West Lewis Street Brownfields Site : • Indoor air samples & repeat crawlspace samples at CS-2 and CS-3 locations due to benzene and TCE concentration detections. • Indoor air samples & repeat crawlspace samples at CS-12 and CS-13 locations due to PCE concentration detections. Model Linen Brownfields Site : • Indoor air samples at Model Linen locations near the SSV Sample locations SSV- 14, SSV- 17, SSV-19, & SSV-21 which displayed elevated PCE concentrations in SSV samples. Due to the prior use of both properties as laundry and drycleaner facilities, and the detected presence of PCE and TCE in groundwater and in the SSV samples, these sites are good candidates for the DSCA program. AZ Development/Pyramid request that the NCDEQ evaluate the data for the Model Linen site and the W. Lewis Street site for possible entry into the DSCA Program for assessment, risk evaluation, and potential vapor mitigation. 8.0 Conclusions Pyramid has completed the Sub Slab Vapor (SSV) assessment of the Model Linen and West Lewis Street Brownfields sites as directed by AZ Development, LLC, and the NCDEQ Brownfields Program. The investigation results are summarized below. • Previous soil and groundwater assessment was conducted at the Model Linen and West Lewis Brownfields sites. In 2004 and 2014, low concentrations of PCE and TCE were detected in the groundwater at each of these Brownfields sites. • The previous assessments also provided a receptor survey of the area indicating that in 2004 there were no sensitive receptors in the area and no water supply wells within 1,000 feet of the properties. • Pyramid confirmed the results of the previous receptor survey and provided additional confirmation from the City or Greensboro that all surrounding properties within 1,000 feet of the site are connected to the municipal water supply. AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSVAssessment Report Page 18 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 Z Pyramid Environmental & Engineering, PC PYRAMID • The research into nearby dry cleaner facilities indicated two nearby DSCA accepted sites. The DCSA sites are Wades Dry Cleaners located 300 feet to the east, and Odorless Dry Cleaners located about 300 feet southwest of the site. • The work plan was prepared as requested by the NCBP for SSV assessment at both Brownfields sites. The work plan was revised as directed by the NCDEQ and approved in October 2021. The work plan implementation required property access to the Boxcar, obtaining the necessary VaporPinsT"° and other equipment, and procuring the cannisters to complete the SSV sampling work. • In December 2021, the installation and SSV sampling was completed for the Model Linen Brownfields site. All activities were in accordance with the approved work plan. • The results of the crawlspace samples at 109 and 111 W. Lewis Street contained levels of benzene and TCE at levels above the Indoor Air Screening Levels (IASLs), and well below the Non -Residential Soil -Gas / SSV Screening Levels. • The SSV samples (slab -on -grade) at 115 and 117 W. Lewis Street contained levels of benzene, Chloroform, 2-Propanol, PCE, and TCE at levels above the IASLs but well below the Non -Residential Soil -Gas / SSV Screening Levels. • The accessible crawlspace samples at 117-B contained levels of PCE above the IASLs in this space, below the Non -Residential Soil -Gas / SSV Screening Levels. • Beneath the slab -on -grade floor in the southern half of 120 W. Lewis St. (Model Linen), SSV-19 and SSV-21 contained levels of PCE above the Non -Residential SSV Screening Levels. The remaining samples contained levels of chloroform, TCE, and PCE above the IASLs and below the Non -Residential Soil -Gas / SSV Screening Levels. • Below the slab -on -grade floor in the northern half of 120 W. Lewis Street (Model Linen) SSV-14 and SSV-17 contained levels of PCE above the Non -Residential Soil -Gas / SSV Screening Levels. The remaining samples contained levels of chloroform, TCE, and PCE above the IASLs but below the Non -Residential Soil -Gas / SSV Screening Levels. • All of the tenant spaces in the development have HVAC systems which circulate air in the buildings. The presence of drycleaner compounds such as PCE and TCE in the groundwater and SSV/CS samples is consistent with the past use of the property as a dry cleaning and laundry facility. AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSVAssessment Report Page 19 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 Z Pyramid Environmental & Engineering, PC PYRAMID 9.0 Closing This report is prepared for and made available solely for the use of AZ Development, LLC and the NCDEQ Brownfields Program. The contents thereof may not be used or relied upon by any other person without the express written consent and authorization of Pyramid Environmental & Engineering, PC. The scope of services for this environmental report relies on documented environmental data provided by others. The subsurface is inherently heterogeneous and subsurface heterogeneities not identified in this limited study may influence COCs in unpredicted ways. Subsurface conditions such as groundwater flow, free product thickness, groundwater elevations, and water quality will vary over time. The opinions and conclusions in this report are in accordance with industry accepted geologic and hydrogeologic practices used at the time and location where the report was prepared. No warranty is expressed or implied. The observations, conclusions, and recommendations documented in this report are based on site conditions and information reviewed at the time of Pyramid's investigation. Pyramid Environmental appreciates the opportunity to provide this environmental service. AZ Development / Model Linen & West Lewis St. Brownfields Sites / SSVAssessment Report Page 20 Pyramid Environmental & Engineering, PC-2022-021 03-15-2022 Figures 51TE: F109/111, 11 7—B1, & 120 W. LEWIS ST. LOCATION: REENSBOR0, NORTH CAROLINA Qy FAIRMONt Sr a �� o + �,• S� •Gt71tFOAbAyE"2 I✓SfARXETS7- - " µcGEE m � y Sr. GAS o ,,`• a SPRING r W GAY'.EGIi1' BtVO $RAGG ST '.�. UNION ST � f fl R SF ST y � IwwrrFrrrcronr sT t l f �DO.dk ST ❑ V _ r� sr � � � Glei><wood _• �� gg � � SafJTil Sr '[t4A'S SrC~ - oCo � BLtrF0i4D Sr � T ] E-PRI kDtY,�Er m -Z _ - _ r S� - ,t .siadNsr �- •GORRELt .- ST - +' - - x . NOCho. Park 1 d TL15C,4tA05A S Ts 71b7 - N a . ;s 455 AVE � 220 LA.n- USGS IDENTIFICATION SCALES USGS 7.5 GREENSBORO, NC 1/2 0 1 MINUTE MAP ORIGINAL DATE: NA MILES: PHOTOREVISION 2019 DATE: 1000 0 2000 40DO 8000 PRIMARY HIGHWAY, HARD SURFACE FEET: 1• = 2000' SECONDARY HIGHWAY. HARD SURFACE NOTES: ►TOPOGRAPHICAL CONTOUR INTERVAL 10 FEET ■ PHOTOREMS IONS DENOTED IN PURPLE 71 LIGHT -DUTY ROAD HARD OR IMPROVEO SURFACE MAGNETIC COUNTY MM OF: UNIMPROVED ROAD NORTH NORTH CAROLINA STATE ROAD U.S. ROUTE F=:] COUNTY: G U I LF O R D INTERSTATE ROUTE APPROXIMATE SITE LOCATION A2 DEVELOPMENT . " + NOTES " 1 a9 1 f 1, 117-81, 120 W. LEWIS 5T.�� �,,� mo �.�w PYRAMID If GREENSBORO 1m NORTH CAROLINA 7/28/21 TIE nAawK � nr.p iwe na.E r�ec Tm srra nx�r110"" ENVIRONMENTAL& ENGINEERING, P.C. TOPOGRAPHIC MAP u5csrnPo Guilford County, NC J ,`r. AP V pj120 BARNHARDT ST i 'i fMji 5eP0+4� 1 5116 51w8-S E ST - 520S,L�LM ST � r 1 532 524 SE MST >JI V. 533 526 S ELM SOIL Y- 120 W LEWIS ST 4 528 SfELM 5T_'L - 535 �530 S ELM.ST cop i1] c c lL N' 532 534 S ELM ST Ts 'r 109 W LEWIS 5T 1 117 B1 W LEWIS ST -- 481621 'ELM'ST May 5, 2021 I • A I• 600 5 ELM 5T 1 3 606 S ELM ST- UN ST ! �� u4 fi10'S!ELM'ST 1:600 0 25 50 100 ft 0 5 10 20 m Guilford County does not certify the authenticity or accuracy of such information. No warranties, express or implied, are provided for the records and/or mapping data herein, or for their use or interpretation by the User. P7f�zF)WARINW-11 A ArcGIS - DryCleaning Contaminated DryCleaning Contaminated North Carolina Dry -Cleaning Solvent Cleanup Act Program, Remediation Unit's site inventory 1 200ft Maxar, Microsoft I Esri Community Maps Contributors, State of North Carolina DOT, © OpenStreetMap, Microsoft, Esri, HERE, Garmin, SafeGraph, GeoTechnologies, Inc., METI/NASA, USGS, EPA, NPS, US Census Bureau, USDA https://www.arcgis.com/home/webmap/print.html 1/1 r � II' r ;;;u5 , uul;-� (90.00) 120 "J'Ve ;t wis 46 MW y (89.50) (90.18) L T _ # (88.50 TM-3 Ll ;" LI (88.86) - + 76'i I r lullu�3 � 1 �• ICJ � TMW-2 (88.22) I F &� r 1 jr F - �I_ TMW-' " MW-4 tFl (88.23) LEGEND (89.00) Potentiometric Contour Line ®Temporary Monitoring Well Location (88.86) Groundwater Elevation (Ft.) Off -site Groundwater Monitoring Well Interpreted Groundwater Flow Direction FD — Floor Drain FIGURE 3 — POTENTIOMETRIC CONTOUR MAP Source: Google Earth Scale: 1 Inch = 40 feet N 9111 Monroe Road, Suite 175 Charlotte, North Carolina 28270 Site Name: 109 — 111 West Lewis Street T 704.846.8853 F 704.846.3271 109 and 111 West Lewis Street enviroassessments.com Greensboro, North Carolina enviroassessments EA Project Number: 14-9927.2 Guilford County, NC J ,`r. AP V pj120 BARNHARDT ST i 'i fMji 5eP0+4� 1 5116 51w8-S E ST - 520S,L�LM ST � r 1 532 524 SE MST >JI V. 533 526 S ELM SOIL Y- 120 W LEWIS ST 4 528 SfELM 5T_'L - 535 �530 S ELM.ST cop i1] c c lL N' 532 534 S ELM ST Ts 'r 109 W LEWIS 5T 1 117 B1 W LEWIS ST -- 481621 'ELM'ST May 5, 2021 I • A I• 600 5 ELM 5T 1 3 606 S ELM ST- UN ST ! �� u4 fi10'S!ELM'ST 1:600 0 25 50 100 ft 0 5 10 20 m Guilford County does not certify the authenticity or accuracy of such information. No warranties, express or implied, are provided for the records and/or mapping data herein, or for their use or interpretation by the User. 14` Tables TABLE 1 West Lewis - Sub -Slab Vapor Sampling Results (12/15/2021) Results Compared to 2021 Residential and Non -Residential VISLs 109, 111, 115, 117 & 117B W. Lewis St. Non -Residential Analytical Parameter Analytical Method SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results Non - Residential Soil -Gas/ SSV Screening Levels Indoor Air Screening Level (IASL) VISL 2021 CS-1 CS-2 CS-3 CS-4 CS-5 CS-6 SSV-7 SSV-8 SSV-9 SSV-10 SSV-11 SSV-11 Duplicate CS-12 CS-13 Units : (ug/m3) (ug/m3) (ug/m3) (ug/m3) (ug/m3) (ug/m3) (ug/m3) (ug/m3) (ug/m3) (ug/m3) (ug/m3) (ug/m3) (ug/m3) (ug/m3) VISL2018 (ug/m3) TO-15 Analytes METHOD (ug/m3) Acetone TO-15 39 65.4 18.4 60.2 97 32.8 ND 342 771 494 40.5 64 ND ND 2700000 27000 Benzene TO-15 1.5 3.0 2.7 1.1 1.1 1.2 ND 2.7 ND ND ND ND 1.5 1.3 160 1.6 2-Butanone(MEK) TO-15 ND 7 ND 7.3 6.4 ND ND 8 16.6 8.9 ND 9.7 ND ND 440000 4400 Carbon Disulfide TO-15 ND 1.1 ND ND ND ND ND ND ND 3.1 ND ND ND ND 61000 610 Chloroform TO-15 ND ND ND ND ND ND 3.5 ND ND 1.9 1.7 1.9 ND ND 53 0.53 Carbon tetrachloride TO-15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 200 2 Chlorobenzene TO-15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4400 44 Chloromethane TO-15 1.1 4.5 1.1 1.7 1.7 1.3 ND 1.2 ND 0.81 ND ND 1.2 1.0 7900 79 CycloHexane TO-15 ND 3.1 4.8 ND ND ND ND ND ND ND ND ND ND ND 61000 610 Dichlorodifluoromethane TO-15 ND 3.0 2.7 3.2 2.9 2.6 2.8 2.8 2.8 2.8 2.6 2.9 3.0 2.8 8800 88 Ethanol TO-15 1050 192 309 1480 1550 1340 102 4580 24,800 22,700 748 873 33.3 74.8 No VISL No VISL Ethylbenzene TO-15 ND 2.5 ND ND ND ND ND 1.7 ND ND ND ND ND ND 490 4.9 1,1-Dichloroethene TO-15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 18000 180 1,2-Dibromoethane TO-15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2 0.02 1,2-Dichloroethane TO-15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 47 0.47 1,2-Dichloropropane TO-15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 330 3.3 Trans-1,2-Dichloroethene TO-15 ND ND ND ND ND ND ND ND ND ND 2.6 2.8 ND ND No VISL No VISL Cis 1,2- Dichloroethene TO-15 ND ND ND ND ND ND ND ND ND ND 47.3 52.7 ND ND No VISL No VISL 2-Propanol (Isopropanol) TO-15 23.4 18.4 5.6 19.9 23 16.1 ND 15.2 870 2,690 23.4 28.9 ND ND 18000 180 n-Hexane TO-15 1.7 3.3 1.5 ND ND 1.2 ND 2 ND ND ND 1.7 ND ND 61000 610 2-Hexanone TO-15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2600 26 Methylene Chloride TO-15 ND 5.3 ND ND ND ND ND ND ND ND ND ND ND ND 53000 530 Methyl-Tert-Butyl-Ether (MTBE) TO-15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4700 47 Naphthalene TO-15 ND ND ND ND 5.8 ND ND NO ND ND ND ND ND ND 36 0.36 Styrene TO-15 ND 1.4 ND ND ND ND ND 1.7 1.8 ND ND ND ND ND 84000 840 Tetrachloroethylene ( PCE) TO-15 ND 2.0 ND ND ND ND 69.1 4.8 130 177 46.5 52.9 381 76 3500 35 1, 1, 1, Trichloroethane TO-15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 440000 4400 Trichloroethylene (TCE) TO-15 ND 3.3 ND ND ND ND ND ND ND ND 2.3 2.5 ND ND 180 1.8 Toluene TO-15 4.1 63.7 5.5 2.8 8.9 3.1 ND 9.3 6.8 6.2 ND ND 2.0 2.2 440000 4400 Trichlorofluoromethane (Freon) TO-15 ND ND ND ND ND ND ND ND 29.7 38.5 2.6 2.5 ND ND No VISL No VISL 1,2,4-Trimethylbenzene TO-15 ND ND ND ND ND ND ND 1.8 18.4 5.2 ND ND ND ND 5300 53 1,3,5-Trimethylbenzene TO-15 ND ND ND ND ND ND ND ND 5.1 ND ND ND ND ND 5300 53 Vinyl Chloride TO-15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 280 2.8 m&p-Xylene TO-15 ND 8.0 ND ND ND ND ND 4.6 4.1 ND ND ND ND ND 8800 88 o-Xylene TO-15 ND 3.0 ND ND ND ND ND 2.6 3.1 2.4 ND ND ND ND 8800 88 Total Xylenes TO-15 ND 11 ND ND ND ND ND 7.2 7.2 2.4 ND ND ND ND 8800 88 All Other TO-15 Parameters TO-15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ug/m3 = Micrograms per Cubic Meter 381 Concentrations above the Non -Residential VISLs for Crawl -space samples ND = Not Detected above MDL or RL TABLE 2 BOXCAR - Sub -Slab Vapor Sampling Results (01/19/2022) Results Compared to 2021 Residential and Non -Residential VISLs 120 W. Lewis St. Non -Residential Analytical Parameter Analytical Method SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results SOIL -GAS Sample Laboratory Results Non - Residential Soil -Gas / SSV Screening Levels Indoor Air Screening Level (IASL) VISL 2021 SSV-14 SSV-15 SSV-16 SSV-17 SSV-18 SSV-19 SSV-20 SSV-21 SSV-22 SSV-23 SSV-23 Dup. Units: (ug/m3) (ug/m3) (ug/ni (ug/m3) I (ug/m3) (ug/m3) (ug/ni (ug/m3) (ug/m3) I (ug/m3) (ug/ni VISL2018 (ug/m3) (ug/m3) TO-15Analytes METHOD I Acetone TO-15 ND 112 29.1 ND 40.4 73.5 < 211 <971 ND ND ND 2700000 27000 Benzene TO-15 NO ND ND ND ND ND ND ND ND ND ND 160 1.6 2-Butanone (MEK) TO-15 ND 5 ND ND 5.8 13.5 ND ND ND ND ND 440000 4400 Carbon Disulfide TO-15 ND 3 ND ND NO ND NO ND NO ND ND 61000 610 Chloroform TO-15 ND 2.9 ND ND ND 3.4 ND ND ND ND ND 53 0.53 Carbon tetrachloride TO-15 ND ND ND ND ND ND ND ND ND ND ND 200 2 Chlorobenzene TO-15 ND ND ND ND ND ND ND ND ND ND ND 4400 44 Chloromethane TO-15 ND NO ND ND ND ND ND ND ND ND ND 7900 79 Cyclohexane TO-15 ND ND ND ND ND ND ND ND ND ND ND 61000 610 Dichlorodifluoromethane TO-15 2.9 2.7 4 NO 2.8 3.1 ND ND ND ND ND 8800 88 Ethanol TO-15 12.9 174 167 NO 175 220 ND ND ND 129 155 No VISL No VISL Ethylbenzene TO-15 ND ND ND ND ND ND ND NO ND ND ND 490 4.9 1,1-Dichloroethene TO-15 ND NO ND ND ND NO ND ND ND NO ND 18000 180 Trans-1,2-Dichloroethene TO-15 ND ND ND ND ND ND ND ND ND ND ND No VISL No VISL Cis 1,2- Dichloroethene TO-15 ND ND ND ND ND ND ND ND ND ND ND No VISL No VISL 2-Propanol (Isopropanol) TO-15 ND 4.5 10.4 ND 4.8 30.1 ND ND ND ND ND 18000 180 n-Hexane TO-15 ND 3 ND ND ND 1.8 ND ND ND ND ND 61000 610 2-Hexanone TO-15 NO ND NO ND ND ND NO ND NO ND ND 2600 26 Methylene Chloride TO-15 ND ND ND ND ND ND ND ND ND ND ND 53000 530 Methyl-Tert-Butyl-Ether (MTBE) TO-15 ND ND ND ND ND ND ND ND ND ND ND 4700 47 Naphthalene TO-15 ND ND ND ND ND ND ND ND ND ND ND 36 0.36 Styrene TO-15 ND 3 ND ND ND ND ND ND ND ND ND 84000 840 Tetrachloroethene (PCE) TO-15 10,100 254 1,160 10,500 105 4,020 1,300 3,750 1,710 471 454 3500 35 1, 1, 1, Trichloroethane TO-15 ND NO ND ND ND NO ND ND ND NO ND 440000 4400 Trichloroethene TO-15 9.5 ND ND ND ND ND ND ND ND 8.7 9.1 180 1.8 Toluene TO-15 ND ND ND ND ND ND ND ND ND ND ND 440000 4400 Trichlorofluoromethane TO-15 ND 4.1 ND NO ND NO ND ND ND NO ND No VISL No VISL 1,2,4-Trimethyl benzene TO-15 ND ND 14.8 NO ND 8.6 ND ND ND NO ND 5300 53 1,3,5-Trimethyl benzene TO-15 ND ND 2.7 ND ND 3.1 ND ND ND NO ND 5300 53 Vinyl Chloride TO-15 ND ND ND ND ND ND ND ND ND ND ND 280 2.8 m&p-Xylene TO-15 ND ND ND ND ND ND ND ND ND ND ND 8800 88 o-Xylene TO-15 ND ND ND ND ND ND ND ND ND ND ND 8800 88 Total Xylenes TO-15 ND ND ND ND ND ND NO ND ND ND ND 8800 88 All Other TO-15 Parameters TO-15 ND ND ND ND ND ND ND ND NO ND ND NA NA ug/m3 = Micrograms per cubic meter 10,500 7 Concentrations above the Non -Residential VISLs ND = Not Detected above MDLs Attachment A ROY COOPER Governor DIONNE DELLI-GATTI Secretary MICHAEL SCOTT Director Sent Via USPS and Email Andrew Zimmerman 3412 Old Onslow Road Greensboro, NC 27407 andyz(cr�,azdev.biz NORTH CAROLINA Environmental Quality March 26, 2021 Subject: Request for Additional Assessment Model Linen & West Lewis Street Brownfields Projects 109/111, 117-B1, and 120 West Lewis Street Greensboro, Guilford County Brownfields Project Numbers 08007-04-041 & 17046-13-041 Dear Mr. Zimmerman: Thank you for your interest in the North Carolina Brownfields Program (the Program). We understand that you are a follow-on owner of the Brownfields Property located at 120 West Lewis Street, Greensboro, which is referred to as the Model Linen Brownfields site, and that you are the Prospective Developer for the Brownfields Property located south of the Model Linen site at 109/111 and 117-B1 West Lewis Street, Greensboro. As you know, there was a discrepancy identified with regards to the land use restrictions on the Model Linen site stemming from its original recordation in 2006. On March 25, 2021, I and Bruce Nicholson, our Program Manager, discussed this and other related issues with your attorney, George House of Brooks Pierce. As a result of that discussion, we have developed the following course of action to not only resolve the outstanding Model Linen issues, but also to efficiently and cost- effectively move forward with the remainder of the brownfields process on the West Lewis Street Brownfields project. Additional Assessment The Program is requesting additional assessment data for both the Model Linen and West Lewis Street properties. This is based on the detection of trichloroethylene (TCE) in the groundwater at the Model Linen site and the lack of sub -slab vapor data at each of these properties with the exception of only one sample collected in the southeastern area of the 109/111 West Lewis Street location. This data request is for representative sub -slab vapor data only from 1) the former Model Linen building, 2) the 109/111 West Lewis Street building, and 3) the 117-B 1 building to evaluate the risk of vapor intrusion into each of these buildings. The basis for the request is that the former Model Linen building may be the source of TCE to groundwater and it is reportedly located upgradient of the 109/111 and 117-B 1 West Lewis Street buildings. Further, drycleaning was reported to have occurred in the 117- B 1 West Lewis Street building (EnviroAssessments, August 8, 2013), but the available data does not include sample points from that area in the building. Only one sub -slab vapor sample was collected from the 109 West Lewis Street building in 2014, and the results indicated that low concentrations of TCE and other volatile organic compounds (VOCs), including the daughter products of TCE were present in that sample. This sample was collected in the southeastern area of this building, which is farther away from the former Model Linen site, the potential source. Additional locations should be sampled therefore to EQ2� North Carolina Department of Environmental Quality I Division of Waste Management 217 West Jones Street 1 1646 Mail Service Center I Raleigh, North Carolina 27699-1646 racy Sri cn�ac��rvu� dePmvnbn m Eavi­wl Ouallh 919.707.8200 Model Linen & West Lewis Street March 26, 2021 Page 2 identify current conditions under the slab and to evaluate the risk of vapor intrusion into each of these buildings. The assessment should be conducted in accordance with a DEQ-approved work plan and the most current DWM vapor intrusion guidance. Please provide a work plan for my review and approval before proceeding with the scope of work. We are also providing the attached Preliminary Vapor Intrusion Work Plan & Report Checklist for your use in preparing this work plan and subsequent report. Please note that this document is under review and may undergo further modification. Sample locations should target known or suspected historical sources of TCE or other VOCs at each of these properties, including drains/utility lines, and if historically present, subgrade structures. The data from this assessment will be evaluated with the DEQ risk calculator; depending on the results, additional sub -slab or indoor air assessment may be required. The sub -slab data collected for this assessment along with the data already submitted to the Program will be used to document site conditions in the brownfields agreement and to develop appropriate land use restrictions. Brownfields Agreements West Lewis Street Brownfields Agreement — We can begin the drafting process on the West Lewis Street Brownfields Agreement (BFA) with the information we have now, but upon receipt will update the draft BFA with the assessment data requested above. To be more efficient and cost-effective, we propose to incorporate the Model Linen property into the West Lewis Street BFA. Upon recordation of this agreement, the existing land use restrictions in the Model Linen BFA would be superseded and all of these properties would be under one agreement and on one survey plat. This will save you transactional costs and make complying with the annual Land Use Restriction Update reporting simpler. Model Linen Brownfields Agreement — the Model Linen BFA was previously recorded, but it has been determined that the land use restrictions of the agreement and those on the accompanying Brownfields survey plat do not match. As discussed above, rather than amend this agreement, we propose that we supersede the recorded Model Linen BFA with the new West Lewis Street BFA that will be written to include the former Model Linen site. Lastly, as you know the Brownfields Project Manager formerly assigned to address the Model Linen plat discrepancy and to the West Lewis Street project has retired from the State. Going forward, I will be handling the project management of this project. For at least the next couple of months, I will be solely teleworking; therefore, the fastest way to reach me is via email at sharon.eckardAncdenr.gov or by my State mobile number 919.609.2617. I look forward to receiving the work plan for this scope of work. Please feel free to contact me if you have any questions. Sincerely, Sharon Poissant Eckard, PG Eastern District Supervisor Brownfields Program Division of Waste Management Enclosure ec: Central Files, DEQ Bruce Nicholson, DEQ George House, Brooks Pierce D Q � North Carolina Department of Environmental Quality I Division of Waste Management 217 West Jones Street 1 1646 Mail Service Center I Raleigh, North Carolina 27699-1646 NORM CAROLiNA DWffhrafft Q„a„ry 919.707.8200 Attachment 6 '10881HSSF1236' IIfl��I�I��I�IIUIIABIflI����� DocumentlD NONCD0002088 Site Name MODEL LINEN SERVICE - B DocumentType Site Assessment Rpt (SAR) t Rpt5egment DocDate 11/4/1996 '��Vll DocRcvd J� 2/20/2007 4 Bo„ SF1236 AccessLevel PUBLIC i D'"is'°" WASTE MANAGEMENT Section SUPERFUND Program IHS (IHS) Doccat FACILITY m m m m m M.m mm m m m mm mmm mm 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 RESEARch & ANALYTICAL ',�% , A �L��r''•°, AbORATORVS, INC. .� :n w NC #34 �+ Analytical/Process Consultstio s --- w �j�j ill 4 October 1946 J1 �,(t`�p�,,,,.`•��G?,,, Aquaterra 4600 Dundas Drive Greensboro, NC 27407 Attention: Henry Kwiecinski Project Number: 6307800 Project Name: Four Seasons Env. (120 W. Lewis) Sample Date Time Sample RAL EPA* Results Number Taken hrs Location Sample# Method (Pl2m) T-1 9/26196 ---- Pit Bottom 281624 5030 31.0 3550 763 T-2 9/26/96 ---- EPA Method 5030 3550 ppm G Pit Bottom 281625 5030 345 3550 1,120 Total Petroleum Hydrocarbons as Gasoline Total Petroleum Hydrocarbons as Diesel parts per million less than or below detection limits P 0. Bax 473. 106 Short Street • Kerner'svil(e. North Camriina 27284. 9101996-2841 FO OR TAZR Return Completed Form To: State Use Only The appropriate OEM Regional Office according to the county of the facility's location. [SEE MAP ON REVERSE SIDE OF OWNER'S COPY [PINK) FOR REGIONAL I.D. Number NOFFICE ADDRESS]. Date Received Complete and return within (M) days following completion of site investigation. 1. Ownership of Tank(s) 11. Location1. f Tank(s) Owner Name: MOM l=acifity Name: Corporation, Individual, Public A e wy, or Other Entdy) (or Comparry) Street Address: f!UJ454 4W1 t5 Facility ID it available: County:_G61-14rd (r Street Address lzowe."4 kwl1 Ci : r5 rull s 6Czr, State i Code: a 7 t 0 forum . ' • r r� � � D / Coup 7" r CI (¢•J� Z i D Code: Q Tele hone Number. •10 ;f Tolachong Number-( & C�7 (Ana Code) (Area Code) Name: a'11 ry rc.r,�,V`r'S CC -- Job Title: {� /' / Tel. No.: Cantractor: r+rJr' 1� L=/1 �- Address; 15R 16.fQ QS.6 !Y� / +� D Tel. No.: 1 -?:PC—,!0Ms08;rr1y9 ConSulEant: J�a 1�L/t-�frY>✓ G Address: 4� ADS, �tZ Si])/tr C• �~`�i7 Tel. No, : V6. tt� ;Lab: 2� �>✓sti /'� , l 4ri Address: rt ��• f 1/l� /Y� Tel. No.: -! c 6 . 911 waler In Fn• Notable Odor or Tank size In Tank Last Excavation product visve Sod Confaminawn No, Gallons Dimensions Contents Yes No Yes No Yes No See reverse side of pink copy t3 �� r I r,� (owner's lion for additional f '� information required by N.C. - DEM in the written report and sketch. NOTE: The site assessment portion of the tank closure must be conducted under the supervision of a Professional Engineer or Licensed Geologist. h1 1 1 PERMANENT C!_OSLIRE (For_Removing or_Abandonfng-In-pfacel Contact local fire marshal. Q23 Notify DEM Regional Office before abandonment ABANDONMENT IN PLACE .® Drain & hush piping Into tank. Fill tank until material overflows tank opening. IR) Remove aft product and residuals from tank [] Plug or cap all openings. Excavate down to tank. Disconnect and cap or remove vent line, Clean and Inspect tank. Solid inert material used - specify, Remove drop tube, rill pipe, gauge pipe, vapor recovery tank connections. submersible pumps and other tank fixtures. 0 Cap or plug all lines except the vent and fill lines, REMOVAaj Purge tank of all product & flammable vapors. �__� Create vent hole. 0 Cut one or more large holes in the tanks. �Label tank. Backriii the area. '%6 /��( Dispose of tank in approve mapper. p- A Date Tank(s) Permanently closed: _ _ / r Final tank destination: .`� s /Y Date of Change•in-Service: Al � C Vill. Certification :d and Sign) certify under penalty of law that I have personally examined and am familiar with the information submitted in this and all attached documents, and that based on my inquiry of those individuals immediately responsible for obtaining the information, I believe that the submitted information is true, accurate, and complete, Print name and official title of owner or owner's authorized representative I Si nature Date Signed lZolz7"< G W/UST 2 (Rev. 9/ i 8/95) 1N tie Copy - Regional Otfi Yellow Copy - Central Office Pink Copy -Owner a e- ervice GW/QST,:�3,� n 16"S FOR Return Completed Form To: ;ANKS The appropriate DEM Regional Office according to the county of the facility's State Use Only IN location. (SEE REVERSE SIDE OF OWNER'S COPY (PINK) FOR REGIONAL 1. D. Number NC OFFICE ADDRESS). Date Received '—INSTRUCTIONS Complete and return five (5) working days prior to closure or change -in-service. `W, S 4 1 C t16kAK A ank Owner Name-, PIC&I Urif-d Facility Name or Company: MDdRi CYtrl orpormion. lndmdual. Public Agency, or 0$hopr Enley) itreet AsWress:_ 177-0 W- Str9l Facility ID # (it available): ,Intwuv; IjFor., Street Address or State Road: 120 W - uw:s S+ro ity: 60M State: A c- Zip Code.40_4.O!_0 County: GL4 I-59"A City:G"(48-4 6"R Zip Code: 21 LWO r ele. No. (Area Code):aP IM9 -"ZZ&'7 Tele. No. (Are a Code): :!Xp P .. ERSON_�� Name*.•Title: OW14w -Telephone IV. TANK- REMOVAL, -CLOSURE IN PLACE; CHANGE -IN-SERVICE 1. Contact Local Fire Marshall. Underground Petroleum Storage Tanks'. 7. The site assessment portion of the tank Plan the entire closure event. 5. Provide a sketch locating piping, closure must be conducted under the Conduct Site Sail Assessments. tanks and soil sampling locations. supervision of a Professional Engineer If Removing Tanks or Closing in 6. Fill out form GW/UST-2"Site or Licensed Geologist. After January 1, Place refer to API Publications Investigation Report for 1994. all closure site assessment 2015 "Cleaning Petroleum Permanent Closure" and return reports must be signed and scaled Storage Tanks" & 1604 "Re- within 30 days following the site by a P.E. or L.G. moval & Disposal of Used investigation, 8. Keep closure records for 3 years. , --WK 0E3e`PEFlFOFlME1',BY:' (Contractor) Name:tur d&ess: State: G-f-* -_1baeo llfc- Zip Code: L I to ontact: 131".. Phone: 914 - Z13-2712 rimaryConsultant: Phone: 1. yll. "Vl. TANK(S) S CHED U LED:! FOR - CLOS UR E;:OACHANGE-IN-SERVICE:e; TANK ID# TANK CAPACITY LAST CONTENTS PROPOSED ACTIVITY CLOSURE j_-5 -- R V I C E MANG&I �V Soov FbpL 1 0: t. C �Fe- L; Removal Abandonment In Place , Now Contents Slored I --A WNER-..OR:OWNER'S"AUTHORIZED:13EPRESENTATIVE-',.;4,,----, rint name and official title Z 0111A j�-�clrASrf 413 -1 Rqiet-i M F &-- 'Scheduled Removal Date: 9 Signature Date Submitted: 9191%. oII scheduled work date changes, notify your appropriate DEM Regionaf Office 43 hours prior to originally scheduled date. '-3 (Rev. 05194) White Copy - Regional Office Yellow Copy - Central 011ice Pink Copy - Owner NCDENR North Carolina Department of Environment and Natural Resources Pat McCrory John E, Skvarla, III Governor Secretary October 23, 2014 Mr. Andrew Zimmerman AZ Development, LLC 3412 Old Onslow Road Greensboro, NC 27407 Subject: REVISED LETTER OF ELIGIBILITY — WEST LEWIS STREET PROJECT 109/111 West Lewis Street Greensboro, Guilford County N.C. Brownfields Program Project No. 17046-13-041 Dear Mr. Zimmerman: The North Carolina Department of Environment and Natural Resources (DENR) received, on October 10, 2014, and has reviewed an Updated/Amended Brownfields Property Application (U/ABPA) prepared and submitted by Michael P. McDermott Jr. of EnviroAssessments, PLLC (EA) on behalf of AZ Development, LLC as the applicant Prospective Developer (PD) seeking entry into the N.C. Brownfields Program (NCBP) and a brownfields agreement regarding a 0.24- acre parcels located at 109/111 West Lewis Street, Greensboro, Guilford County (subject property). On October 25, 2013, AZ Development, LLC was granted eligibility for entry into the NCBP for its "West Lewis Street" redevelopment project, consisting of a single 0.48-acre parcel located at 117-B1 West Lewis Street, immediately east of and contiguous to the subject property. We understand that AZ Development, LLC desires to increase the acreage of its West Lewis Street project by adding the subject property to the original 0.48-acre parcel already deemed eligible. We understand further that AZ Development, LLC desires to purchase the subject property for redevelopment in commercial retail, office and flex space. Upon review of the U/ABPA with respect to the requirements of the Brownfields Property Reuse Act of 1997, DENR has determined that this additional acreage is eligible for entry into the NCBP and for continued evaluation for a Brownfields Agreement (BFA) as part of the West Lewis Street project. The next step in the process will involve a detailed review of available environmental and other relevant data to determine what is currently known about contamination at the site. We are in receipt of a Phase I Environmental Site Assessment (ESA) for the 117-B1 parcel and a Phase I ESA for the 109/111 parcel, both prepared by EA, dated June 12, 2013 and July 30, 2014, respectively, and a Phase II ESA for the 109/111 parcel, dated September 8, 2014 and also prepared by EA. These reports were submitted with the U/ABPA. Any existing historical site information from the files of DENR's Division of Waste Management will also be utilized during the evaluation process. Please forward to your brownfields Project Manager any additional environmental reports, data or site information you may have or can acquire to assist in our evaluation. This should include reports from other DENR agencies or regional offices, if available. 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 Phone: 919-707-82001Internet: http://portal.ncdenr.org/web/wm An Equal Opportunity 1 Affirmative Action Employer — Made in part by recycled paper Mr. Andrew Zimmerman October 23, 2014 Page 2 We agree that the increased footprint of your West Lewis Street project will bring additional public benefits to this emerging part of Greensboro. And, as mentioned in the Letter of Eligibility for the 117-131 parcel, your West Lewis Street project will further advance the redevelopment potential in an area that already has a brownfields agreement - the Model Linen project on property located across the street from the West Lewis Street site. We look forward to working with you to advance this now expanded second brownfields redevelopment project you have brought to the Program, your first being the Burlington Distribution site. Tony Duque will continue to be the brownfields Project Manager for the West Lewis Street project. If you have questions about this correspondence or require additional information, please feel free to contact Tony by phone at 919-707-8380 or by e-mail at tony.duque@ncdenr.gov. Sincerely, �G Michael E. Jott Deputy Director Division of Waste Management cc: Project File ec: Bruce Nicholson, DENR Tony Duque, DENR 9111 Monroe Road, Suite 175 Charlotte, North Carolina 28270 T 704.846.8853 F 704.846.3271 enviroassessments. com enviroassessments 109 -111 WEST LEWIS STREET September 8, 2014 Mr. George House, Attorney -At -Law Brooks Pierce 2000 Renaissance Plaza 230 N. Elm Street Greensboro, North Carolina 27401 (336) 271-3114 Attention: Mr. George House, Attorney -At -law Reference: Phase II Environmental Site Assessment 109-111 West Lewis Street 109 and 111 West Lewis Street Greensboro, Guilford County, North Carolina EA Project No. 14-9927.2 Dear Mr. House: EnviroAssessments (EA) has completed a Phase II Environmental Site Assessment (ESA) of the 109-111 West Lewis Street property (the "Site"), located in Greensboro, Guilford County, North Carolina. A Site Location Map is attached as Figure 1. EA conducted a Phase I Environmental Site Assessment of the Site and a report was submitted to High Point Bank on July 17, 2014 under separate cover. The purpose of the Phase II ESA was to evaluate the Site with respect to potential contamination issues associated with the on - site historic painting operations and auto repair operations and to evaluate the Site for the presence of chlorinated solvents in groundwater which have been identified at the off -site western adjacent property (117 BI West Lewis Street) and the off -site northern Model Linen-B site. 1.0 SITE HISTORY The Site consists of one approximately 0.24 acre rectangular -shaped parcel of land identified as Parcel Identification Number 7864631801 according to the Guilford County Tax Assessor's Office. The Site is improved with one approximately 9,269 square foot vacant commercial building which was constructed in 1910. The Site building is currently unoccupied and was formerly occupied by various tenants including Farmers Horse and Mule Company, Carolina Service Corporation Auto Repairs, and Kindley's Warehouse Storage. The office/warehouse facility was most recently occupied by Kindley's Office Supply, 109 West Lewis Street and Rhyne Warehouse, 111 West Lewis Street. To summarize the Site history, the Site has been improved with the present building since around 1910. Sanborn maps and/or city directories indicate the Site has been improved since at least 1885. The Site formerly existed as a wagon/carriage company from at least 1885 through 1913; as an auto garage and/or auto Phase II Environmental Site Assessment 109-111 West Lewis Street 109 and I I I West Lewis Street Greensboro, Guilford County, North Carolina EA Project No. 14-9927.2 September 8, 2014 2 repair shop and Pepsi Cola Bottling Company in 1919 through at least 1925; as a furniture warehouse from at least 1950 through 1971; also as an auto repair shop from 1962 through 1965; and as a warehouse and/or office supply company from 1969 through 1989. The building is presently vacant. The ESA revealed no evidence of recognized environmental conditions in connection with the Site, except for the following: • The Site contained operations involving painting from at least 1885 through at least 1919 and auto repair shops in 1919 and from at least 1962 through 1965. Historically, auto repair shops have been known to utilize quantities of petroleum products and solvents, and painting operations have used petroleum -based paints and solvents. These activities typically generate wastes associated with the same substances, the disposal and management of which have not been closely regulated in the past. Based on the length of time the Site historically operated with one or more of these uses (intermittently from at least 1885 through the 1960s), a potential exists that undocumented releases of petroleum products and/or solvents have caused an impact to the Site's soil and/or groundwater quality. • West Lewis Street Property, located adjacent to the west and topographically cross -gradient of the Site at 117 West Lewis Street, is listed as a Brownfields Management System/Brownfield Sites, Pending Eligibility property. EA completed a prior Phase I Environmental Site Assessment; West Lewis Street Property prepared by EnviroAssessments and dated June 12, 2013 on this property. According to the report, historical resources indicated the property operated as Greensboro Laundry & Cleaners with suspected on -site "dry cleaning" operations from as early as 1950 through 1971. Additionally, the report identified potential off -site sources of chlorinated solvent contaminants in the area. EA completed a subsequent Phase II assessment of the adjacent property, dated August 8, 2013 which identified Tetrachloroethene (PCE) in soil and groundwater at this property, within 30 feet of the Site's western property boundary. The lateral extent of the contamination has not been defined, including in the direction of the 109-111 West Lewis Street subject Site, and the source(s) of the contamination have not been definitively identified. Therefore, a significant potential exists that similar contamination may also be present in groundwater at the 109-111 West Lewis Street Site. • The property formerly known as Model Linen-B at 120 West Lewis Street, along the north side of West Lewis Street, approximately 40 feet north of the Site property, is listed on the state's (North Carolina Department of Environment and Natural Resources or NCDENR) Incident Management Database (IMD) and Leaking Underground Storage Tanks (LUST) database with two open incident case numbers: Inc. No. 16349 and Inc. No. 86606. The site has contaminants identified in the groundwater which exceed the NCDENR NCAC 2L Ground Water Quality Standards (NCAC 2L Standards). Some of the contaminants which exceed the NCAC 2L Standards include Benzene, Vinyl Chloride, Trichloroethene, and Tetrachloroethene. A Brownfields plat indicates MW-3 is one of the monitoring wells with concentrations of Benzene and Tetrachloroethene which exceed the NCAC 2L Standards. MW-3 is located approximately 40 feet north of the 109-111 West Lewis Street Site property. Available information does not specify groundwater flow direction and does not indicate if the contamination has migrated off -site to the south toward the Site. Considering the proximity of the contamination at the Model Linen site to the Site property (within 40 feet) and the Phase II Environmental Site Assessment 109-111 West Lewis Street 109 and I I I West Lewis Street Greensboro, Guilford County, North Carolina EA Project No. 14-9927.2 September 8, 2014 absence of data detailing contaminant distribution patterns or groundwater flow direction, the Model Linen site is a potential off -site source of contaminants to the 109-111 West Lewis Street subject Site. We note that the recently revised ASTM E-1527-13 Phase I ESA guidance process requires that Phase I ESAs now consider the potential for vapor encroachment onto a Site property from contamination associated with on -site and nearby off -site sources. The possible presence of volatile hydrocarbons from the on -site and off -site concerns noted above are potential sources of vapor encroachment for the Site property and may pose a potential for vapor intrusion into the Site building which could be considered to be a potential health concern in some situations. In addition, the following BERs (Business Environmental Risks) were identified: EA personnel noted evidence of water/moisture intrusions and substantial water damaged ceiling finishes on the wood framing and roof supports throughout the Site building. The moisture issues appear to be the result of roof leaks and/or faulty water piping. A potential exists that substantial water/moisture intrusion has proliferated, damaging the building's interior finishes and potentially its structural materials. No areas of suspect mold growth were observed during EAs physical inspection of the Site building. EA personnel did not observe any areas which were not readily accessible such as attics, crawl spaces, and ventilation systems. Significant damage of the building and the presence of mold are conditions which normally detract from the value and "marketability" of a property. In order to confirm the presence of absence of mold or excessive moisture conditions, particularly in areas that are not readily accessible or visible (i.e.; attics, ventilation systems, etc.), a formal mold and moisture inspection would be necessary. • Considering the age of the Site building (constructed in 1910) a potential exists that asbestos - containing materials (ACMs) could be present in some of the building's construction materials. EA personnel observed no obvious evidence of damaged suspect ACMs. However, in order to confirm the presence or absence of ACMs in any structure, a formal ACM survey would be required. • Based on the age of the Site building (constructed in 1910) a potential exists that lead based paint (LBP) could be present on some of the building's painted surfaces. EA personnel observed no significant amounts of damaged paint at the Site. However, in order to confirm the presence or absence of lead -based paint in any structure, a formal lead -based paint survey would be required. The Client (Brooks Pierce) authorized EA to complete a Phase II ESA to evaluate the Site in order to determine potential on -site impacts from the concerns noted above, the details of which are provided in the following sections of this report. Phase II Environmental Site Assessment 4 109-111 West Lewis Street 109 and I I I West Lewis Street Greensboro, Guilford County, North Carolina EA Project No. 14-9927.2 September 8, 2014 2.0 FIELD ACTIVITIES 2.1 Subsurface Utility Locating EA personnel contacted the North Carolina One Call Center and requested that the local utility services conduct an Electromagnetic (EM) Survey in the area of concern at the Site to determine the orientation and location of underground utility lines for optimal sampling locations. At the time of the assessment, underground utility lines appeared to be marked up to the Site boundaries. However, public utilities are not authorized to locate underground lines on private property. On August 22, 2014, EA and its subcontractor, Sweetwater Utility Exploration (Sweetwater), conducted an on -site ground -penetrating radar (GPR) survey and EM survey at the Site to determine the orientation and location of on -site subsurface utilities (including building interior) in order to determine optimal sampling locations. All items located were marked directly on the surface using paint. 2.2 Soil Assessment On August 22, 2014, EA and its subcontractor utilized a Geoprobe® sampling device to advance soil sample points in six (6) locations (S-1 through S-6) of the Site, as depicted on the attached Figure 2. A total of six (6) on -site soil samples (5-1-2, 5-2-2, 5-3-2, 5-4-2, 5-5-2 and S-6-2) were collected from the six (6) soil boring locations. EA personnel screened the soil columns for Volatile Organic Compounds (VOCs) from each boring at two -foot intervals using a Photo Ionization Detector (PID), and visual and olfactory indicators. Phase II Site Photos are included as Appendix 1. Boring logs are included in Appendix 2 which detail soil descriptions, sampling depths and field screening results. Soil boring S-1 was advanced to a depth of 18 feet below grade (BG) near the western interior wall of the 109 West Lewis Street building. Soils encountered in the boring consisted of concrete at depths of 0-2 inches underlain by tan/red stiff clay and dark browniblack silt at depths of 2 inches to 4 feet BG, tan/red clayey silt at depths of 4-16 feet BG and brown/gray micaceous clayey silt at depths of 16-18 feet BG. Soils were observed to be moist at depths of 8-16 feet BG and saturated at depths of 16-18 feet BG. Petroleum odors were noted in the soil at depths of 8-18 feet BG. Field screening of the soils did not indicate detectable VOC concentrations in the soils at depths of 2-6 feet BG; however, detectable VOC concentrations ranged from 0.5 parts per million (ppm) at a depth of 8 feet BG to 162 ppm at a depth of 18 feet BG. One (1) soil sample (S- 1-2) was collected at a depth of two (2) feet BG from soil boring S-1. Soil boring S-2 was advanced to a depth of 20 feet below grade (BG) near the western interior wall of the 109 West Lewis Street building and to the north of soil boring S-1. Soils encountered in the boring consisted of concrete at depths of 0-2 inches underlain by tan/red clayey silt at depths of 2 inches to 12 feet BG and brown/gray micaceous clayey silt at depths of 12-20 feet BG. Soils were observed to be moist at depths of 12- 14 feet BG and saturated at depths of 14-20 feet BG. Petroleum odors were noted in the soil at depths of 12- 20 feet BG. Field screening of the soils did not indicate detectable VOC concentrations in the soils at depths of 2-6 feet BG. One (1) soil sample (5-2-2) was collected at a depth of two (2) feet BG from soil boring S-2. Phase II Environmental Site Assessment 109-111 West Lewis Street 109 and I I I West Lewis Street Greensboro, Guilford County, North Carolina EA Project No. 14-9927.2 September 8, 2014 5 Soil boring S-3 was advanced to probe refusal, which was encountered at a depth of 18 feet below grade (BG), near the northwestern exterior portion of the 109 West Lewis Street building. Soils encountered in the boring consisted of concrete at depths of 0-2 inches underlain by tan stiff clay at depths of 2 inches to 4 feet BG, tan/red clayey silt at depths of 4-12 feet BG, tan/gray clayey silt at depths of 12-16 feet BG and tan sandy silt at depths of 16-18 feet BG. Soils were observed to be moist at depths of 16-18 feet BG. Petroleum odors were noted in the soil at depths of 12-18 feet BG. Field screening did not indicate detectable VOC concentrations at depths of 2-6 feet BG. One (1) soil sample (5-3-2) was collected at a depth of two (2) feet BG from soil boring S-3. Soil boring S-4 was advanced to a depth of 8 feet below grade (BG) near the southern exterior of the 109 West Lewis Street building. Soils encountered in the boring consisted of tan stiff clay at depths of 0-4 feet BG underlain by tan clayey silt at depths of 4-8 feet BG. The soils were observed to be dry and no solvent or petroleum odors were noted in soil boring S-4. Field screening did not indicate detectable VOC concentrations in the soils at depths of 2-8 feet BG. One (1) soil sample (S-4-2) was collected at a depth of two (2) feet BG from soil boring S-4. Soil boring S-5 was advanced to a depth of 8 feet below grade (BG) near the southern exterior of the 111 West Lewis Street building and to the west of soil boring S-4. Soils encountered in the boring consisted of dark brown stiff clay at depths of 0-2 feet BG underlain by tan/red clayey silt at depths of 2-8 feet BG. The soils were observed to be dry and no solvent or petroleum odors were noted in soil boring S-5. Field screening did not indicate detectable VOC concentrations in the soils at depths of 2-8 feet BG. One (1) soil sample (5-5-2) was collected at a depth of two (2) feet BG from soil boring S-5. Soil boring S-6 was advanced to a depth of 20 feet below grade (BG), near the southwestern exterior portion of the I I I West Lewis Street building and to the west of soil boring S-5. Soils encountered in the boring consisted of dark brown clayey silt at depths of 0-2 feet BG underlain by brown clayey silt at depths of 2-12 feet BG and gray/tan silty sand at depths of 12-20 feet BG. Soils were observed to be moist at depths of 8-16 feet BG and saturated at depths of 16-20 feet BG. Solvent odors were noted in the soils at depths of 12-20 feet BG. Field screening did not indicate detectable VOC concentrations at depths of 2-6 feet BG. One (1) soil sample (5-6-2) was collected at a depth of two (2) feet BG from soil boring S-6. The soil samples were placed into appropriate sample containers and labeled with the Site name, time and date of collection, and analysis to be performed. The filled sample containers were placed in a cooler containing ice and transported to Pace Analytical Services, Inc. in Huntersville, North Carolina (a North Carolina -certified laboratory). A chain -of -custody form was maintained with the samples. All soil samples were submitted and analyzed for volatile organic compounds (VOCs) by EPA Method 8260 and semi -volatile Polynuclear Aromatic Hydrocarbons (PAHs) by EPA Method 8270. A copy of the laboratory analytical report is attached as Appendix 3. The laboratory results are discussed in Section 3.0 of this report. Phase II Environmental Site Assessment 6 109-111 West Lewis Street 109 and I I I West Lewis Street Greensboro, Guilford County, North Carolina EA Project No. 14-9927.2 September 8, 2014 2.3 Groundwater Assessment On August 22, 2013, EA and its subcontractor utilized the Geoprobe sampling device to install a total of four (4) temporary groundwater piezometer wells at the Site (TMW-1 through TMW-4) in the locations of the Site depicted on the attached Figure 2. All groundwater piezometer wells were constructed of 1-inch diameter PVC screen and casing and completed approximately 1-2 feet above grade. Detailed well construction information is included in Table 4. Piezometer well TMW-1 was installed to the termination depth (18 feet BG) in soil boring S-1 and the well was constructed with 10 feet of screen (8-18 feet BG). Piezometer well TMW-2 was installed to the termination depth of soil boring S-2 (20 feet BG) and the well was constructed with 10 feet of screen (10-20 feet BG). Piezometer well TMW-3 was installed to the termination depth of soil boring S-3 (18 feet BG) and the well was constructed with 10 feet of screen (8-18 feet BG). Piezometer well TMW-4 was installed to the termination depth of soil boring S-6 (20 feet BG) and the well was constructed with 10 feet of screen (10-20 feet BG). Upon installation, the piezometer wells were developed/purged and allowed to equilibrate for approximately 1-6 hours prior to collecting groundwater samples. Temporary piezometer well boring/well construction logs are included in Appendix 2. On August 22, 2013, EA personnel collected groundwater samples (TMW-1 through TMW-4) from each of the four (4) piezometer wells using clean, dedicated polypropylene tubing and a peristaltic pump. In addition, EA personnel collected one (1) groundwater sample from an existing off -site groundwater monitoring well (MW-3) located to the northwest of the Site at 120 West Lewis Street (currently Lotus Lounge). Prior to collecting the groundwater sample from MW-3, EA personnel purged the monitoring well of approximately 3 well volumes of water. The groundwater samples were placed into appropriate sample containers and labeled with the Site name, time and date of collection, and analysis to be performed. The filled sample containers were placed in a cooler containing ice and transported to PACE Analytical in Huntersville, North Carolina (a North Carolina - certified laboratory). A chain -of -custody form was maintained with the sample. The groundwater samples were submitted and analyzed for VOCs by EPA Method 8260 and PAHs by EPA Method 8270. A copy of the laboratory analytical report is attached as Appendix 3. The laboratory results are discussed in Section 3.0 of this report. On August 25, 2014, EA personnel returned to the Site to gauge groundwater levels in the temporary piezometer wells and off -site existing groundwater monitoring well MW-3. EA gauged the depth to the groundwater table (from the top of well casings) for each of the on -site groundwater piezometer wells. Using a SpectraVision Laser Level, EA personnel surveyed the elevations of the tops of each well casing. Using an assumed benchmark elevation, EA calculated relative well casing elevations. Using the water table depths, EA then calculated the relative water table elevations at each well point. The well casing and water table data are provided on Table 4. All of the piezometer wells appear to be hydraulically connected as part of the same surficial water table aquifer. The relative water table elevations and groundwater -flow direction are presented on Figure 3. Based on the groundwater elevation measurements taken at the Site, the shallow groundwater flow direction is interpreted to be generally to the southeast across the site. Phase II Environmental Site Assessment 7 109-111 West Lewis Street 109 and I I I West Lewis Street Greensboro, Guilford County, North Carolina EA Project No. 14-9927.2 September 8, 2014 2.4 Sub -Slab Assessment On August 22, 2014, EA and its subcontractor utilized a Geoprobe® sampling device to install one (1) temporary sub -slab vapor probe (VP-1) in the location depicted on the attached Figure 2. The boring was advanced to a depth of 4 feet BG to the north of a floor drain located near the center of the 109 West Lewis Street building. A temporary sub -slab vapor probe constructed of a stainless steel mesh sampling point connected to'/4 inch diameter Teflon tubing was inserted into the boring to a depth of 3 feet BG. Sand was placed around the sampling point at depths of 2.5-4 feet BG and bentonite was utilized to seal the boring to the floor surface. Once a proper seal had been established, at least five (5) volumes of air were purged from the tubing and sand pack interval prior to sample collection. One (1) sub -slab vapor sample (VP-1) was collected by attaching the tubing to a dedicated one -liter Summa vacuum canister and a pre -calibrated ten-minute flow controller with vacuum gauge. The Summa canister was then opened and a sub -slab vapor sample was collected at an approximate flow rate of 70 milliliters per minute for approximately 14 minutes, until the vacuum remaining in the canister measured approximately 3 inches inches of Mercury (Hg). The Summa canister was labeled with the Site name, time and date of collection, canister ID, flow control number and analysis to be performed. The filled canister was transported to Pace Analytical in Huntersville, North Carolina (a North Carolina -certified laboratory). A chain -of -custody form was maintained with the sample. The sub -slab vapor sample was submitted and analyzed for VOCs by EPA Method TO-15. A copy of the laboratory analytical report is attached as Appendix 3. A Field Data Sheet containing detailed sub -slab vapor sampling information is attached as Appendix 4. The laboratory results are discussed in Section 5.0 of this report. 3.0 LABORATORY ANALYTICAL RESULTS 3.1 Soil Assessment EA collected a total of six (6) soil samples (S-1-2, S-2-2, S-3-2, S-4-2, S-5-2 and S-6-2) in the locations shown on Figure 2. A copy of the laboratory analytical report is attached as Appendix 3 and a summary of the soil sampling results is presented in Table 1. In Summary, laboratory analysis did not reveal concentrations of target analytes exceeding North Carolina Department of Environment and Natural Resources (NCDENR), Inactive Hazardous Sites Branch (IHSB) Industrial Health -Based Preliminary Soil Remediation Goals (PSRGs) or Protection of Groundwater PSRGs. Laboratory analysis of soil sample S-1-2 revealed an Acetone concentration of 0.230 milligrams per kilogram (mg/kg), which does not exceed the Protection of Groundwater PSRG of 24 mg/kg of the Industrial Health - Based PSRG of 100,000 mg/kg for Acetone. No target analytes were detected above laboratory reporting limits in the remaining soil samples (S-2-2, S-3-2, S-4-2, S-5-2 and S-6-2). Refer to Sections 4.0 and 5.0 for EA's conclusions and recommendations. Phase II Environmental Site Assessment 8 109-111 West Lewis Street 109 and I I I West Lewis Street Greensboro, Guilford County, North Carolina EA Project No. 14-9927.2 September 8, 2014 3.2 Groundwater Assessment EA collected a total of five (5) groundwater samples (TMW-1, TMW-2, TMW-3, TMW-4 and MW-3) at the locations shown on Figure 2. A copy of the laboratory analytical report is attached as Appendix 3 and a summary of the groundwater sampling results is presented in Table 2. In Summary, four (4) of the five (5) groundwater samples (TMW-1, TMW-2, TMW-4 and MW-3) revealed concentrations of the target analytes exceeding NCAC 2L Groundwater Quality Standards (2L Standards). None of the groundwater samples revealed concentrations of target analytes exceeding Gross Contamination Levels (GCLs). Laboratory analysis of on -site groundwater sample TMW-1 revealed a Benzene concentration of 59.8 micrograms per liter (ug/L), which exceeds the 2L Standard of 1 ug/L for Benzene. Groundwater sample TMW-1 revealed concentrations of Naphthalene (316 ug/L), and 2-Methylnaphthalene (33.0 ug/L) which exceed the 2L Standards of 6 ug/L for Naphthalene and 30 ug/L for 2-Methylnaphthalene. In addition, groundwater sample TMW-1 revealed a 1-Methylnaphthalene concentration of 14.9 ug/L which exceeds the Interim Maximum Allowable Concentration (IMAC) of 1 ug/L for 1-Methylnaphthalene (effective April 1, 2011). No other target analytes were detected in groundwater sample TMW-1 at concentrations exceeding 2L Standards or IMACs. However, several additional target analytes were detected in groundwater sample TMW-1 at concentrations below their respective 2L Standards. Laboratory analysis of on -site groundwater sample TMW-2 revealed a Naphthalene concentration of 99.9 ug/L, which exceeds the 2L Standard of 6 ug/L for Naphthalene. No other target analytes were detected in groundwater sample TMW-2 at concentrations exceeding 2L Standards or IMACs. However, several additional target analytes were detected in groundwater sample TMW-2 at concentrations below their respective 2L Standards. Laboratory analysis of on -site groundwater sample TMW-3 did not reveal any target analyte concentrations exceeding 2L Standards. Groundwater sample TMW-3 revealed a Naphthalene concentration of 4.0 ug/L, which is below the 2L Standard of 6 ug/L for Naphthalene. No other target analytes were detected in groundwater sample TMW-3 at concentrations exceeding laboratory reporting limits. Laboratory analysis of on -site groundwater sample TMW-4 revealed concentrations of Naphthalene (420 ug/L), Ethylbenzene (668 ug/L), Total Xylenes (1,030 ug/L) and 2-Methylnaphthalene (33.7 ug/L), which exceed the 2L Standards of 6 ug/L for Naphthalene, 600 ug/L for Ethylbenzene, 500 ug/L for Total Xylenes and 30 ug/L for 2-Methylnaphthalene. Groundwater sample TMW-4 also revealed a 1-Methylnaphthalene concentration of 16.7 ug/L, which exceeds the IMAC of 1 ug/L for 1-Methylnaphthalene. No other target analytes were detected in groundwater sample TMW-4 at concentrations exceeding 2L Standards or IMACs. However, several additional target analytes were detected in groundwater sample TMW-4 at concentrations below their respective 2L Standards. Laboratory analysis of off -site groundwater sample MW-3 revealed concentrations of Benzene (4.7 ug/L), Naphthalene (53.9 ug/L) and Tetrachloroethene (PCE; 13.1 ug/L), which exceed the 2L Standards of 1 ug/L for Benzene, 6 ug/L for Naphthalene and 0.7 ug/L for PCE. Groundwater sample MW-3 also revealed a 1- Methylnaphthalene concentration of 13.7 ug/L, which exceeds the IMAC of 1 ug/L for 1-Methylnaphthalene. No other target analytes were detected in groundwater sample MW-3 at concentrations exceeding 2L Phase II Environmental Site Assessment 109-111 West Lewis Street 109 and I I I West Lewis Street Greensboro, Guilford County, North Carolina EA Project No. 14-9927.2 September 8, 2014 0 Standards or IMACs. However, several additional target analytes were detected in groundwater sample MW- 3 at concentrations below their respective 2L Standards. Refer to Sections 4.0 and 5.0 for EA's conclusions and recommendations. 3.3 Sub -Slab Assessment EA collected a total of one (1) sub -slab vapor sample (VP-1) for laboratory analysis, the location of which is depicted on Figure 2. The sub -slab vapor sampling analytical results are presented in Table 3 and Figure 2. A copy of the laboratory analytical report is attached as Appendix 3. A Field Data Sheet containing detailed sub -slab vapor sampling information is attached as Appendix 4. In summary, laboratory analysis of sub -slab vapor sample VP-1 did not reveal concentrations of target analytes exceeding NCDENR, Division of Waste Management (DWM), Non -Residential Sub Slab and Exterior Soil Gas Screening Levels (SGSLs), recently updated for June 2014 and used by the IHSB. Laboratory analysis of sub -slab vapor sample VP-1 revealed detectable concentrations of several target analytes; however, none of the detected concentrations exceed DWM Non -Residential SGSLs. Refer to Sections 4.0 and 5.0 for EA's conclusions and recommendations. 4.0 CONCLUSIONS 4.1 Soil Assessment EA collected a total of six (6) soil samples (5-1-2, S-2-2, 5-3-2, 5-4-2, S-5-2 and S-6-2) in the locations shown on Figure 2. In summary, none of the soil samples revealed concentrations of target analytes exceeding IHSB Industrial Health -Based PSRGs or Protection of Groundwater PSRGs. Based on the laboratory analytical results, no significant petroleum or solvent contamination was identified in shallow on -site soils in the areas of the site investigated during this Phase II ESA. However, three (3) of the four (4) on -site groundwater samples (TMW-1, TMW-2 and TMW-4) revealed concentrations of petroleum constituents exceeding 2L Standards. The source area of the identified on -site petroleum -contaminated groundwater plume is currently unknown; however, considering the Site's former automotive repair activities, a potential exists that an on -site source area is associated with the identified on - site petroleum -contaminated groundwater. 4.2 Groundwater Assessment EA collected a total of five (5) groundwater samples (TMW-1 through TMW-4 and MW-3) in the locations shown on Figure 2. In summary, four (4) of the five (5) groundwater samples (TMW-1, TMW-2, TMW-4 and MW-3) revealed concentrations of target analytes exceeding 2L Standards. Phase II Environmental Site Assessment 109-111 West Lewis Street 109 and I I I West Lewis Street Greensboro, Guilford County, North Carolina EA Project No. 14-9927.2 September 8, 2014 10 Groundwater samples TMW-1, TMW-2 and TMW-4 revealed concentrations of petroleum constituents exceeding 2L Standards in on -site groundwater. Groundwater sample TMW-4, collected near the southwestern exterior corner of the Ill West Lewis Street building, generally revealed the highest concentrations of petroleum constituents in on -site groundwater during this Phase II ESA. None of the six (6) soil samples collected during this Phase II ESA revealed detectable concentrations of petroleum constituents in on -site shallow soil and the source area for the identified petroleum -contaminated groundwater is currently unknown. However, considering the Site's former painting and automotive repair activities, a potential exists that an on -site source area is associated with the petroleum -contaminated groundwater. Groundwater sample MW-3, collected from an existing groundwater monitoring well located off -site and approximately 40 feet to the northeast of the Site at 120 West Lewis Street (currently Lotus Lounge), revealed concentrations of petroleum and solvent constituents exceeding 2L Standards. The elevated petroleum and solvent constituent concentrations detected in MW-3 appear to be associated with previously identified and documented release incident numbers 16349 and 86606 at the Model Linen-B site formerly located at 120 West Lewis Street. Based on the groundwater elevation measurements taken at the Site and from off -site groundwater monitoring well MW-3, the shallow groundwater flow direction is interpreted to be generally to the southeast and towards the Site. Therefore, the potential exists that the petroleum contamination identified in on -site groundwater may be associated with the previously documented release incidents associated with the Model -Linen B site. However, based on the lack of solvent constituents detected in the on -site groundwater samples (TMW-1, TMW-2, TMW-3 and TMW-4) and considering the highest concentrations of petroleum constituents were detected in the groundwater sample (TMW-4) located the farthest distance from MW-3, it does not appear likely that the on -site petroleum -contaminated groundwater has been significantly impacted as a result of the release incidents associated with the Model Linen-B site. Two of the groundwater samples (TMW-1 and TMW-4) revealed concentrations of petroleum constituents exceeding NCDENR, DWM Non -Residential Vapor Intrusion Groundwater Screening Levels (GWSLs). Groundwater samples TWM-1 and TMW-4 revealed concentrations of Ethylbenzene and Naphthalene which exceed the DWM Vapor Intrusion GWSLs of 152 ug/L for Ethylbenzene and 146 ug/L for Naphthalene. In addition, groundwater sample TWM-4 revealed a Total Xylenes concentration of 1,030 ug/L, which exceeds the DWM GWSL of 414 ug/L for Total Xylenes. DWM GWSLs are detailed in the Groundwater Sampling Analytical Table (Table 2). Refer to section 4.3 for additional information regarding on -site structural vapor intrusion potential at the Site. 4.3 Sub -Slab Vapor Intrusion Assessment EA collected a total of one (1) sub -slab vapor sample (VP-1) for laboratory analysis, the location of which is depicted on Figure 2. The sub -slab vapor sampling analytical results are presented in Table 3 and Figure 2. A copy of the laboratory analytical report is attached as Appendix 3. In Summary, laboratory analysis of sub -slab vapor sample VP-1 did not reveal concentrations of target analytes exceeding NCDENR, DWM, Non -Residential Sub Slab and Exterior Soil Gas and Screening Levels (SGSLs), recently updated for June 2014. Laboratory analysis of soil -slab vapor sample VP-1 revealed detectable concentrations of several target analytes; however, none of the detected concentrations exceed DWM Non -Residential SGSLs. Phase II Environmental Site Assessment 109-111 West Lewis Street 109 and I I I West Lewis Street Greensboro, Guilford County, North Carolina EA Project No. 14-9927.2 September 8, 2014 11 Based on the laboratory analytical results of sub -slab vapor sample VP-1, no evidence of significant adverse impact associated with potential vapor encroachment/migration from the off -site northwestern Model Linen-B release incidents and/or from the western adjacent 117 B West Main Street property was identified at the Site during this Phase II ESA. However, two (2) of the groundwater samples (TMW-1 and TMW-4) collected at the Site revealed concentrations of target analytes exceeding NCDENR, DWM Non -Residential Vapor Intrusion Groundwater Screening Levels (GWSL). Based on the presence of on -site groundwater exceeding DWM GWSLs and the limited sub -slab vapor sampling conducted during this Phase II ESA, the potential exists for structural vapor intrusion potential to have adversely impacted portions of the Site not investigated during this Phase II ESA. Sub -slab sampling results can vary significantly according to seasonal and temporal weather conditions (rain, snow, barometric pressure changes) along with changes to potential migration pathways such as utilities and surficial cover (impervious surfaces such as pavement, buildings, clay fill). �XI 71[4117u 101111eI 7r Y [Qe1f1 We recommend that this report be forwarded to the Guilford County Department of Public Health (GCDPH) for guidance on whether additional site assessment will be required under State guidelines. The GCDPH will consider the findings with regard to potential on -site and off -site sources and potentially responsible parties. The GCDPH could require additional soil and groundwater assessment at the Site to further evaluate the following: 1. the lateral and vertical extents of potential on -site source areas of petroleum contamination identified in on -site groundwater; 2. more definitive evaluation of potential off -site sources of contamination; 3. potential "worst case" conditions for sub -slab vapors as a function of colder temperatures and various temporal weather conditions. We also recommend that the Client consider determination of eligibility into the Brownfield Program by preparing Brownfields Property Application for the Site and/or inclusion with the adjacent property to the west (117 B1 West Lewis Street). Phase II Environmental Site Assessment 12 109-111 West Lewis Street 109 and I I I West Lewis Street Greensboro, Guilford County, North Carolina EA Project No. 14-9927.2 September 8, 2014 6.0 CLOSURE EA appreciates the opportunity to be of service to you on this Site. Please call the undersigned at (704) 846- 8853 if you desire additional information. Sincerely, EnviroAssessments, PLLC Michael P. McDermott Jr. Project Manager Attachments Gary K. Sawyer, PG, RSM Principal Cliff R. Lundgren, P.G. Senior Project Manager FIGURES II ,' % ,• 51I 5■ 5� �fr .� 1ti k� J •• I jj J - Ly r f _.•r - f I. 3 y 14 1 t lips 4 • f 4 1 i � T J5 � . I� fir• � � '• L.' n f I K;p I 1 \ l # Y ITP Figure g 1 —Site Location Ma p Source: USGS 7.5 Minute Topographic Map Greensboro, North Carolina Quadrangle 1951 (photorevised 1994) Scale: 1:24,000 9111 Monroe Road, Suite 175 Charlotte, North Carolina 28270 T 704.846.8853 F 704.846.3271 Y Site Name: 109 - 111 West Lewis Street 109 and 111 West Lewis Street + enviroassessments.com Greensboro, North Carolina enviroassessments EA Project Number: 14-9927.2 '.:it su t i 04 Benzene: 4.7 _.* Ethylbenzene: 65.8 Naphthalene: 53.9 PCE: 13.1 J TCE: 1.2 (NS) MEK:17.5 Cis-1,2-Dichloroethene: �1 F 4�syrrt �• � 1 S-1-2 I Acetone:0.230 -JI' r' • • ' TMW-1 + " I J "a Acetone:40.7 Benzene:59.8 I Toluene: 4.4 Ethylbenzene: w•I otal Xylenes: 325 Naphthalene:316� ` Styrene: 9.8 D -JJfEK: 29.2 • f MIBK:31.3.. _ (ND) S-4-2 �• T I n : 14. Eth Ibenzene:668 Total Xylenes: 1,030 Na hthalene:420 A 2-Chlorotoluene: 58.3 rl S-3-2 (ND) ` TMW-3 Naphthalene: 4.0 S-2-2 (ND) TMW-2 Acetone: 46.8 Ethylbenzene: 77.5 Total Xylenes: 49.8 Naphthalene: 99.9 �MEK: 30.0 MIBK: 13.2 p-Isoptopyltoluene: 23.4 * `VP-1 No Target Analyte ■ Concentrations exceeded the DMW Non -Residential Sub Slab and Exterior Soil Gas Vapor Intrusion Screening Level. 7. LEGEND FD — Floor Drain Soil Concentrations Are Reported in Milligrams Per Kilogram (mg/kg). O Soil Sample Location Groundwater Concentrations Are Reported in Micrograms Per Liter (ug/L). Soil Sample and Temporary Monitoring Sub -Slab Vapor Concentrations Are Reported in Micrograms Per Cubic Meter (ug/m3) ® Well/Groundwater Sample Location BOLD Concentrations Exceed Soil PSRGs, NCAC 2L Groundwater Standards, or DWM Non -Residential Vapor Intrusion Screening Levels. Sub -Slab Vapor Sample Location PSRG - Preliminary Soil Remediation Goal NS — Nest Samnleri •Off -site Groundwater Monitoring =-Exceeds DWM Non -Residential Vapor Intrusion Groundwater Screening Level (GWSL) Well MEK = 2-Butanone PCE = Tetrachloroethene MIBK = 4-Meth I-2-Pentanone TCE = Trichloroethene FIGURE 2 — SITE PLAN Source: Google Earth Scale: 1 Inch = 40 feet N 9111 Monroe Road, Suite 175 Charlotte, North Carolina 28270 Site Name: 109 - 111 West Lewis Street T 704.846.8853 F 704.846.3271 109 and 111 West Lewis Street enviroassessments.com Greensboro, North Carolina enviroassessments EA Project Number: 14-9927.2 r � II' r ;;;u5 , uul;-� (90.00) 120 "J'Ve ;t wis 46 MW y (89.50) (90.18) L T _ # (88.50 TM-3 Ll ;" LI (88.86) - + 76'i I r lullu�3 � 1 �• ICJ � TMW-2 (88.22) I F &� r 1 jr F - �I_ TMW-' " MW-4 tFl (88.23) LEGEND (89.00) Potentiometric Contour Line ®Temporary Monitoring Well Location (88.86) Groundwater Elevation (Ft.) Off -site Groundwater Monitoring Well Interpreted Groundwater Flow Direction FD — Floor Drain FIGURE 3 — POTENTIOMETRIC CONTOUR MAP Source: Google Earth Scale: 1 Inch = 40 feet N 9111 Monroe Road, Suite 175 Charlotte, North Carolina 28270 Site Name: 109 — 111 West Lewis Street T 704.846.8853 F 704.846.3271 109 and 111 West Lewis Street enviroassessments.com Greensboro, North Carolina enviroassessments EA Project Number: 14-9927.2 TABLES TABLE 1 SOIL SAMPLING ANALYTICAL RESULTS 109-111 WEST LEWIS STREET 109 AND III WEST LEWIS STREET GREENSBORO, GUILFORD COUNTY, NORTH CAROLINA ENVIROASSESSMENTS PROJECT NO. 14-9927.2 Sample ID Analytical Method S-1-2 S-2-2 S-3-2 S-4-2 S-5-8 S-6-2 Preliminary Industrial Health- Based PSRG Protection of Groundwater PSRG Sample Depth (ft, bgs) 2 2 2 2 2 2 Collection Date Ed 8/22/2014 8/22/2014 8/22/2014 8/22/2014 8/22/2014 8/22/2014 Volatile Organic Compounds by EPA Method 8260B Acetone I 8260B 0.230 ND ND ND ND ND 100000 24 Polynuclear Aromatic Hydrocarbons (PAH) by EPA Method 8270C All Target Analytes I 8270C I ND ND ND ND ND ND NA NA Notes: All concentrations are reported in milligrams per kilogram (mg/kg). BOLD results exceed their respective Preliminary Health -Based PSRG and/or Protection of Groundwater PSRG PSRG - Preliminary Soil Remediation ft, bgs - feet below ground surface ND - Not Detected NA - Not Applicable TABLE 2 GROUNDWATER SAMPLING ANALYTICAL RESULTS 109 - 111 WEST LEWIS STREET 109 AND 111 WEST LEWIS STREET GREENSBORO, GUILFORD COUNTY, NORTH CAROLINA ENVIROASSESSMENTS PROJECT NO. 14-9927.2 Sample ID Analytical Method TMW-1 TMW-2 TMW-3 TMW-4 MW-3* NCAC 2L Groundwater Standard Gross Contamiantion Level (GCL) DWM Non -Residential Vapor Intrusion Groundwater Screening Level (GWSL) Collection Date 1 8/22/2014 8/22/2014 8/22/2014 8/22/2014 8/22/2014 Volatile Organic Compounds by EPA Method 8260B Acetone 8260B 40.7 46.8 ND ND ND 6000 6000000 19000000 Benzene 8260B 59.8 ND ND ND 4.7 1 5000 69.3 Toluene 8260B 4.4 ND ND 14.8 ND 600 260000 16100 Ethylbenzene 8260B 352 77.5 ND 668 65.8 600 84500 152 Xylenes, total 8260B 325 49.8 ND 1030 ND 500 85500 414 Naphthalene 8260B 316 99.9 4.0 420 53.9 6 6000 146 Tetrachloroethene (PCE) 8260B ND ND ND ND 13.1 0.7 700 48.4 Trichloroethene (TCE) 8260B ND ND ND ND 1.2 3 3000 4.35 Styrene 8260B 9.8 ND ND ND ND 70 70000 7790 2-Butanone (MEK) 8260B 29.2 30.0 ND ND 17.5 4000 4000000 1880000 Cis-1,2-Dichloroethene 8260B ND ND ND ND 2.8 70 70000 NE p-Isopropyltoluene 8260B ND 23.4 ND ND ND 25 11700 NE 2-Chlorotoluene 8260B ND ND ND 58.3 ND 100 NE NE 4-Methyl-2-Pentanone (MIBK) 8260B 31.3 13.2 ND ND ND 100 100000 466000 Polycyclic Aromatic Hydrocarbons (PAH) by EPA Method 8270C Naphthalene 8270C 102 ND ND 187 24.6 6 6000 146 1-Methylnaphthalene 8270C 14.9 ND ND 16.7 13.7 1** NE NE 2-Methylnaphthalene I 8270C 33.0 ND ND 33.7 ND 30 NE NE Notes: *MW-3 is located off -site to the northwest of the Site at 120 West Lewis Street (currently the Lotus Lounge). **Interim Maximum Allowable Concentration (IMAC) Effective April 1, 2011. All concentrations are reported in micrograms per liter(ug/L). BOLD results exceed their respective NCAC 2L Groundwater Standard or IMAC ND - Not Detected NE - Not Established = Concentration exceeds the NCDENR, DWM Non -Residential Vapor Intrusion Groundwater Screening Level (GWSL). NA - Not Applicable NCDENR - North Carolina Department of Environment and Natural Resources NT - Not Tested DWM - Disvision of Waste Management TABLE 3 SOIL -GAS ANALYTICAL RESULTS 109 - III WEST LEWIS STREET 109 AND III WEST LEWIS STREET GREENSBORO, GUILFORD COUNTY, NORTH CAROLINA ENVIROASSESSMENTS, PLLC PROJECT NO. 14-9900.2 Sample ID Analytical Method VP-1 Non -Residential Sub Slab and Exterior Soil Gas Screening Level (SGSL) Sample Date 8/22/2014 Volatile Organic Compounds by EPA Method T015 Acetone T015 50.4 2720000 Benzene T015 16.5 1570 Bromoform T015 44.4 NE Bromomethane T015 2.3 438 2-Butanone (MEK) T015 16.4 438000 Carbon Disulfide T015 27.3 61300 Chlorobenzene T015 3.2 4380 Chloroethane T015 2.7 876000 Chloromethane T015 4.3 7880 Cyclohexane T015 14.4 526000 Dichlorodifluoromethane T015 2.6 8760 Ethylbenzene T015 12.1 4910 4-Ethyltoluene T015 9.1 NE n-Heptane T015 16.2 NE n-Hexane T015 37.9 6130 2-Hexanone T015 4.6 2630 Methylene Chloride T015 63.2 52600 Naphthalene T015 7.0 263 Styrene T015 2.4 87600 Tetrachloroethene (PCE) T015 8.2 3500 THC as Gas T015 4370 NE Toluene T015 22.9 438000 1, 1, 1 -Trichloroethane T015 2.6 438000 Trichloroethene (TCE) T015 2.2 175 1,2,4-Trimethylbenzene T015 25.9 613 1,3,5-Trimethylbenzene T015 6.9 NE Vinyl Chloride T015 3.6 2790 m&p-Xylene T015 29.5 8760 o-Xylene T015 12.3 8760 Notes: Samples collected 8/22/2014 for approximately 14 minutes. All concentrations are reported in micrograms per cubic meter (ug/m3). ND - Not Detected above laboratory reporting limits NE - Not Established DWM - Division of Waste Management BOLD results exceed Exterior Soil Gas Screening Level established by the DWM (June 2014). J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. TABLE 4 PIEZOMETER WELL CONSTRUCTIONIWATER LEVEL INFORMATION 109-111 WEST LEWIS STREET 109 and 111 WEST LEWIS STREET GREENSBORO, GUILFORD COUNTY, NORTH CAROLINA ENVIROASSESSMENTS PROJECT NO. 14-9927.2 Relative Water Total Well Screened Top of Casing DTW Installation Well Inner Table Well I.D.Depth Interval Relative 8/25/2014 Date Diameter (in.) Elevation (ft.,bgs) (ft., bgs) Elevation (ft.) (ft., TOC) (ft.) 8/25/2014 MW-3 1/5/2003 2 15 5-15 99.72 9.54 90.18 TMW-1 8/22/2014 1 18 8-18 103.33 15.31 88.02 TMW-2 8/22/2014 1 20 10-20 102.41 14.19 88.22 TMW-3 8/22/2014 1 18 8-18 102.81 13.95 88.86 IL TMW-4 8/22/2014 1 20 10-20 1 103.56 15.33 1 88.23 bgs = below ground surface TOC = top of casing. DTW = depth to water. APPENDICES APPENDIX 1 PHASE II SITE PHOTOS Site Photos —Phase II ESA 109-111 West Lewis Street Greensboro, Guilford County, North Carolina EA Project Number: 14-9927.2 Photograph #1- Sub -slab vapor sample (VP-1) boring location (109 W. Lewis St.). Photograph #2- Soil boring / temporary monitoring well (S-1 /TMW-1) boring location. August2014 Site Photos —Phase II ESA August 2014 109-111 West Lewis Street Greensboro, Guilford County, North Carolina EA Project Number: 14-9927.2 Photograph #3- Soil borings & temporary monitoring wells (S-1/TMW-1 & S-2/TMW-2) boring locations. Photograph #4- Soil boring S-3 / temporary monitoring well (S-3/TMW-3) boring location. Site Photos —Phase II ESA 109-111 West Lewis Street Greensboro, Guilford County, North Carolina EA Project Number: 14-9927.2 Photograph #5- Soil borings S-4 and S-5 (soil samples S-4-2 and S-5-2) locations. Photograph #6- Soil borings S-6 / temporary monitoring well (TMW-4) boring location. August2014 Site Photos —Phase II ESA 109-111 West Lewis Street Greensboro, Guilford County, North Carolina EA Project Number: 14-9927.2 August2014 Photograph #7- Off -site groundwater monitoring well MW-3 (Lotus Lounge; 120 W. Lewis St.). Photograph #8- Off -site groundwater monitoring well MW-3 (Lotus Lounge; 120 W. Lewis St.). APPENDIX 2 SOIL BORING AND WELL CONSTRUCTION LOGS Boring /Well Construction Log Well Construction Permit Number I. D. Number Project Name Project No. Geologist Start Date S-1 /TWM-1 109-111 West Lewis Street 14-9927.2 Mike McDermott 812212014 Complete Date 812512014 Purpose Contractor Registration No. Driller Equipment Phase II ESA Regional Probing Services Truck -Mounted Drilling Method: Direct Push Technology Comments Inside 109 W. Lewis St. building, near western wall adjoining III W Lewis St. building. Southwest of vapor sample boring VP-1 OVM Well Construction Information Depth From - To Soil / Rock Description / Comments (pp-) @ Depth (ft.) Borehole Dia. 0 - 2" Concrete 0.0 @ 2-6' Riser Type 2"- 4' Tan/red stiff clay and dark brown/black silt, no petrolum or solvent odor 0.5 @ 8" Diameter 4 - 16' Tan/red clayey silt, petroleum odor @ 8-16, moist @ 8-16' 0.7 @ 10' Screen Type 16 - 18' Brown/gray micaceous clayey silt, wet, strong petroleum odor 1.4 @ 12' Diameter 6.4 @ 14' Riser Interval 70.1 @ 16' Screen Interval Soil Sample S-1-2 collected @ 2' (1020 hrs) 162 @ 18' Slot Size Grout Type Temporarymonitoring well (TMW-1) installed to 18' with screen @ 8-18' Interval DTW = 19.41 below TOC after well installation Bentonite Type Groundwater sample TMW-1 collected (1445 hrs) Interval Filter Pack TWM-1 abandoned on 812512014 Interval Total Depth R.P.* Elevation Datum Water Level Information Date W.L.Below R.P. - R.P. = Reference Point W.L. = Water Level TBM= Temporary Benchmark MSL = Mean Sea Level OVM= Organic Vapor Measurement * TOC = Top of casing GS = Ground surface Boring /Well Construction Log Well Construction Permit Number I. D. Number Project Name Project No. Geologist Start Date S-2 / TWM-2 109-111 West Lewis Street 14-9927.2 Mike McDermott 812212014 Complete Date 812512014 Purpose Contractor Registration No. Driller Equipment Phase II ESA Regional Probing Services Truck -Mounted Drilling Method: Direct Push Technology Comments Inside 109 W. Lewis St. building, near western wall adjoining III W Lewis St. building. North of S-1/TMW--1 boring. OVM Well Construction Information Depth From - To Soil / Rock Description / Comments (pp-) @ Depth (ft.) Borehole Dia. 0 - 2" Concrete 0.0 @ 2-6' Riser Type 2"- 12' Tan/red clayey silt, moist @ 9-12', no petroleum or solvent odor Diameter 12 - 20' Brown/Gray micaceous clayey silt, moist @ 12-14 , wet @ 14-20', petroleum Screen Type odor Diameter Riser Interval Soil Sample S-2-2 collected @ 2' (1100 hrs) Screen Interval Slot Size Grout Type Temporarymonitoring well (TMW-2) installed to 20' with screen @ 10-20' Interval DTW = 15.21 below TOC after well installation Bentonite Type Groundwater sample TMW-2 collected (1500 hrs) Interval Filter Pack TWM-2 abandoned on 812512014 Interval Total Depth R.P.* Elevation Datum Water Level Information Date W.L.Below R.P. - R.P. = Reference Point W.L. = Water Level TBM= Temporary Benchmark MSL = Mean Sea Level OVM= Organic Vapor Measurement * TOC = Top of casing GS = Ground surface Boring /Well Construction Log Well Construction Permit Number I. D. Number Project Name Project No. Geologist Start Date S-3 / TWM-3 109-111 West Lewis Street 14-9927.2 Mike McDermott 812212014 Complete Date 812512014 Purpose Contractor Registration No. Driller Equipment Phase II ESA Regional Probing Services Truck -Mounted Drilling Method: Direct Push Technology Comments Northwest exterior of 109 W. Lewis St. building OVM Well Construction Information Depth From - To Soil / Rock Description / Comments (pp-) @ Depth (ft.) Borehole Dia. 0 - 2" Concrete 0.0 @ 2-6' Riser Type 2"- 4' Tan stiff clay, no petroleum or solvent odor Diameter 4 - 12' Tan/red clayey silt, no petroleum or solvent odor Screen Type 12 - 16' Tan/gray clayey silt, moist, slight petroleum odor Diameter 16 - 18' Tan sandy silt, moist, no petroleum or solvent odor Riser Interval Screen Interval Probe refusal encountered @ 18' Slot Size Grout Type Soil Sample S-3-2 collected @ 2' (1200 hrs) Interval Bentonite Type Temporarymonitoring well (TMW-3) installed to 18' with screen @ 8-18' Interval DTW = 16.42 below TOC after well installation Filter Pack Groundwater sample TMW-3 collected (1530 hrs) Interval Total Depth TWM-3 abandoned on 812512014 R.P.* Elevation Datum Water Level Information Date W.L.Below R.P. - R.P. = Reference Point W.L. =Water Level TBM= Temporary Benchmark MSL = Mean Sea Level OVM= Organic Vapor Measurement * TOC = Top of casing GS = Ground surface Boring /Well Construction Log Well Construction Permit Number I. D. Number Project Name Project No. Geologist Start Date S-4 109-111 West Lewis Street 14-9927.2 Mike McDermott 812212014 Complete Date 812212014 Purpose Contractor Registration No. Driller Equipment Phase II ESA Regional Probing Services Truck -Mounted Drilling Method: Direct Push Technology Comments Southern exterior of 109 W. Lewis St. building OVM Well Construction Information Depth From - To Soil / Rock Description / Comments (pp-) @ Depth (ft.) Borehole Dia. 0 - 4' Tan stiff clay, no petroleum or solvent odor 0.0 @ 2-8' Riser Type 4 - 8' Tan clayey silt, no petroleum or solvent odor Diameter Screen Type Soil Sample 5-4-2 collected @ 2' (1310 hrs) Diameter Riser Interval Boring backfilled with bentonite after sample collection Screen Interval Slot Size Grout Type Interval Bentonite Type Interval Filter Pack Interval Total Depth R.P.* Elevation Datum Water Level Information Date W.L.Below R.P. - R.P. = Reference Point W.L. =Water Level TBM= Temporary Benchmark MSL = Mean Sea Level OVM= Organic Vapor Measurement * TOC = Top of casing GS = Ground surface Boring /Well Construction Log Well Construction Permit Number I. D. Number Project Name Project No. Geologist Start Date S-5 109-111 West Lewis Street 14-9927.2 Mike McDermott 812212014 Complete Date 812212014 Purpose Contractor Registration No. Driller Equipment Phase II ESA Regional Probing Services Truck -Mounted Drilling Method: Direct Push Technology Comments Southern exterior of 111 W. Lewis St. building, west of soil boring S-4 OVM Well Construction Information Depth From - To Soil / Rock Description / Comments (pp-) @ Depth (ft.) Borehole Dia. 0 - 2' Dark brown stiff clay, no petroleum or solvent odor 0.0 @ 2-8' Riser Type 2 - 8' Tan/red clayey silt, no petroleum or solvent odor Diameter Screen Type Soil Sample 5-5-2 collected @ 2' (1330 hrs) Diameter Riser Interval Boring backfilled with bentonite after sample collection Screen Interval Slot Size Grout Type Interval Bentonite Type Interval Filter Pack Interval Total Depth R.P.* Elevation Datum Water Level Information Date W.L.Below R.P. - R.P. = Reference Point W.L. =Water Level TBM= Temporary Benchmark MSL = Mean Sea Level OVM= Organic Vapor Measurement * TOC = Top of casing GS = Ground surface Boring /Well Construction Log Well Construction Permit Number I. D. Number Project Name Project No. Geologist Start Date S-6 / TWM-4 109-111 West Lewis Street 14-9927.2 Mike McDermott 812212014 Complete Date 812512014 Purpose Contractor Registration No. Driller Equipment Phase II ESA Regional Probing Services Truck -Mounted Drilling Method: Direct Push Technology Comments Southern exterior of 111 W. Lewis St. building, west of soil boring S-5. OVM Well Construction Information Depth From - To Soil / Rock Description / Comments (pp-) @ Depth (ft.) Borehole Dia. 0 - 2' Dark brown clayey silt, no petroleum or solvent odor 0.0 @ 2-6' Riser Type 2 - 12' Brown clayey silt, moist @ 8-12', no petroleum or solvent odor Diameter 12 - 20' Gray/tan silty sand, moist @ 12-16, wet @ 16-20 , solvent odor Screen Type Diameter Soil Sample S-6-2 collected @ 2' (1345 hrs) Riser Interval Screen Interval Temporarymonitoring well (TMW-4) installed to 20' with screen @ 10-20' Slot Size DTW = 15.45 below TOC after well installation Grout Type Groundwater sample TMW-4 collected (1430 hrs) Interval Bentonite Type TWM-3 abandoned on 812512014 Interval Filter Pack Interval Total Depth R.P.* Elevation Datum Water Level Information Date W.L.Below R.P. - R.P. = Reference Point W.L. = Water Level TBM= Temporary Benchmark MSL = Mean Sea Level OVM= Organic Vapor Measurement * TOC = Top of casing GS = Ground surface Boring /Well Construction Log Well Construction Permit Number I. D. Number Project Name Project No. Geologist Start Date VP-1 109-111 West Lewis Street 14-9927.2 Mike McDermott 812212014 Complete Date 812212014 Purpose Contractor Registration No. Driller Equipment Phase II ESA Regional Probing Services Truck -Mounted Drilling Method: Direct Push Technology Comments Interior of] 09 W. Lewis St. building, near floor drain near the center of the building. OVM Well Construction Information Depth From - To Soil / Rock Description / Comments (pp-) @ Depth (ft.) Borehole Dia. 0 - 4' Tan stiff clay, no petroleum or solvent odor Riser Type Diameter Vapor sample point and teflon tubing inserted to 3' Screen Type sand @ 2.5 - 4' Diameter Connected 1-Liter summa canister to sampling line Riser Interval Screen Interval Initial vacuum = -27 inches Hg / Sample start time = 0950 hrs Slot Size Final vacuum = -3 inches Hg /sample end time = 1004 hrs Grout Type Interval Bentonite Type Interval Filter Pack Interval Total Depth R.P.* Elevation Datum Water Level Information Date W.L.Below R.P. - R.P. = Reference Point W.L. = Water Level TBM= Temporary Benchmark MSL = Mean Sea Level OVM= Organic Vapor Measurement * TOC = Top of casing GS = Ground surface APPENDIX 4 FIELD DATA SHEETS FOR SUB -SLAB VAPOR SAMPLING FIELD DATA - VAPOR INTRUSION PROJECT NAME: 1 09-1 11 W. Lewis Street PROJECT ADDRESS: 149-11 1 W. Lewis Street CITY, COUNTY, STATE: Greensboro, Guilford County, NC IHSB NUMBER: V/19 EA PROJECT Nl iM A: 14-9927.2 Sample I❑ Sample Type (Circle One) SLib-Slab I qkdoor Air 1 Soil -Gas Sample Location p ,Sol-, Field MeaNuremena Percent (%} Helium - Bucket 1 Time: Percent {q/4} Helium - Tedlar Bag &jh / Time: Canister Number: Canister Pressure (Hg) - START Sample Collection START date I Lf Sample Collection START Time Canister Pressure (1-1g) - END Sample Collection END date a� Sample Collection END Time �,y] Notes: r {r 1 1 ]7rh'r`/, fVfl�` oaf j i-1 .1 fV tl CQs'l f Cr -8j c� S j � r cJ vct vxc C e( 1 p q Monitoring Well Installation Report Former Odorless Cleaners DSCA ID: DC410047 205 West Lewis Street Greensboro, Guilford County North Carolina Dry -Cleaning Solvent Cleanup Act Program H&H Job No. DSO-109G June 7, 2021 1 . hart hickman SMARTER ENVIRONMENTAL SOLUTIONS #C-1269 Engineering #245 Geology 2923 South Tryon Street, Suite 100 3921 Sunset Ridge Rd, Suite 301 Charlotte, NC 28203 Raleigh, NC 27607 www.harthickman.com 704.586.0007 main 919.847.4241 main Table 1: Site Chronology DSCA ID No.: DC410047 Chronology of Events Instructions: Brief description of all significant events that have occurred since a problem was Date suspected at the facility. Commence with the first date a problem was suspected and continue through the most recent activity described in the current report. Hart & Hickman, PC (H&H) completed a passive soil gas survey and receptor survey to determine if a solvent release August - September had occurred at the subject site. twenty passive soil samplers (PS-lthrough PS-20) were collected in the vicinity of the 2016 former dry cleaner. Tetrachloroethylene (PCE) was detected in 13 of the 20 samples with no daughters compounds detected. Other petroleum constituents were detected in samplers. H&H recommended conducting a limited soil and groundwater sampling to evaluate the areas where highest concentrations were identified in the soil gas. H&H completed a limited soil and groundwater sampling event to evaluate the areas where the highest concentrations were identified during the passive soil gas survey. Seven soil samples were collected from four soil borings (SB-1 December 2016 through SB-4) and four groundwater samples (TMW-1 through TMW-4) were collected from temporary monitoring wells. On February 22, 2017, H&H submitted an assessment report to the DSCA Program documenting the sampling activities and results. H&H conducted additional groundwater assessment activities at the site to further delineate the extent of groundwater July 2017 impacts at the site. The additional assessment included the installation of five permanent Type -II monitoring wells (MW 1, MW-2, MW-3, MW-4, and MW-5) and subsequent sampling of the wells. On September 29, 2017, H&H submitted a report to document the groundwater assessment activities and results. H&H conducted additional groundwater assessment activities at the site to further delineate to the extent of groundwater impacts at the site. The additional assessment included the installation and sampling of four permanent shallow August 2018 monitoring wells (MW-6, MW-7, MW-8, and MW-9) and one deep permanent monitoring well (MW-4D). H&H also collected groundwater samples from the existing site monitoring wells with the exception of MW-5, which could not be located. On October 4, 2018, H&H submitted a report to document the groundwater assessment activities and results. H&H collected four soil gas samples (TSG-2 through TSG-5) on the adjacent downgradient property to the west of the former Odorless Cleaners source property to evaluate potential vapor intrusion risks associated with the dry-cleaning January 2019 solvent release. PCE was detected at low concentrations in three of the four samples, and the calculated risks associated with the detected PCE concentrations were acceptable for both residential and non-residential use. On March 7, 2019, H&H submitted a letter report to the DSCA Program documenting the sampling activities and results. H&H conducted a quarterly groundwater monitoring event, which included gauging water levels and collecting March 2019 groundwater samples from the site monitoring wells. In April 2019, H&H provided a brief e-mail update to the DSCA Program with the results. H&H conducted a quarterly groundwater monitoring event, which included gauging water levels and collecting June 2019 groundwater samples from the site monitoring wells. In July 2019, H&H provided a brief e-mail update to the DSCA Program with the results. H&H conducted a quarterly groundwater monitoring event, which included gauging water levels and collecting December 2019 groundwater samples from the site monitoring wells. On March 31, 2020, H&H submitted a groundwater monitoring report to the DSCA Program documenting the March, June, and December groundwater monitoring events. H&H conducted additional groundwater assessment activities at the site to further delineate the lateral and vertical extent of groundwater impacts. The additional assessment included the installation of two off -source permanent top -of - March 2021 bedrock monitoring wells (MW-8D and MW-1 OD) and one source area permanent bedrock monitoring well (MW-4BR). H&H also collected groundwater samples from the newly installed and select existing site monitoring wells (MW-1, MW-4, MW-4D, MW-6, MW-7, and MW-8). On June 7, 2021, H&H submitted a report to document the groundwater assessment activities and results. leW-6 VACANT �MW-10D MW-4BR -01 MW-4 MW-7 MW-4D W (610 S. EUGENE ST) W W MW-8 DRAM & DRAUGHT---"C MW-8D VACANT GREENSBORO CITGO GAS URBAN MINISTRY MW-9 STATION I i i I i LEGEND SOURCE PROPERTY BOUNDARY PARCELBOUNDARY PERMANENT TYPE II MONITORING WELL G PERMANENT TYPE III MONITORING WELL 4 TEMPORARY MONITORING WELL DESTROYED MONITORING WELL NOTES: 1. MONITORING WELLS MW-1 THROUGH MW-5 WERE INSTALLED IN JULY 2017. 2. TEMPORARY MONITORING WELLS TMW-1 THROUGH TMW-4 WERE INSTALLED, SAMPLED, & ABANDONED IN DECEMBER 2016. 3. MONITORING WELLS MW-4D AND MW-6 THROUGH MW-9 WERE INSTALLED IN AUGUST 2018. 4. MONITORING WELLS MW-4BR, MW-8D, & MW-10D WERE INSTALLED IN MARCH 2O21. 5. MONITORING WELL MW-5 FOUND DESTROYED DURING AUGUST 2018 SAMPLING EVENT DUE TO CONSTRUCTION ACTIVITIES ON 300 W. GATE CITY BOULEVARD. FE CITY BLVD) i �MW-3 r` ` TMW-` 1 (205 W. LEWIS ST/ 1 / TMW-2 MW-1 / MW-2 I / TMW-3 1 I 1 I FORGE GREENSBORO TMW-4 1 �1 ELITE CAR AUDIO & AUTO TINT GATE C/TYSOUCEVARD 9 APPROXIMATE 0 100 200 SCALE IN FEET i I i I i TITLE SITE MAP PROJECT FORMER ODORLESS CLEANERS DSCA SITE ID: DC410047 205 W. LEWIS STREET GREENSBORO, NORTH CAROLINA South Tryon Street -Suite 100 hart h i c k m a n Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) SMARTER ENVIRONMENTAL SOLUTIONS License # C-1269 / #C-245 Geology DATE: 5-4-21 REVISION NO. 0 JOB NO. DSO-109 ATTACHMENT NO. 4 Client: DSCA WELL LOG hart ► hickman Project: Former Odorless Cleaners (DSO-109) Well No. MW-10 5MARTFR EWRONWNTAL501l1T1ON5 Address: 205 W. Lewis Street, Greensboro, NC Page: 1 of 1 Drilling Start Date: 03/17/2021 Boring Depth (ft): 50 ft bgs Well Depth (ft): 49.20 ft bgs Drilling End Date: 03/17/2021 Boring Diameter (in): 6.25 Well Diameter (in): 2.0 Drilling Company: Geologic Exploration Sampling Method(s): DP, GR (Drill Cuttings) Screen Slot (in): 0.010 Drilling Method: Hollow Stem Auger DTW During Drilling (ft): Riser Material: Sch 40 PVC Drilling Equipment: Geoprobe 3230 DT DTW After Drilling (ft): 6.78 ft bgs Screen Material: Sch 40 PVC Slotted Driller: Top of Casing Elev. (ft): Seal Material(s): Bent. -Cement Grout/Bent. Chips Logged By: SQM Location (X,Y): Filter Pack: Sand Pack COLLECT MEASURE > w W z w Ep 0 JO w a 4 a, N a $ Z SOIL/ROCK VISUAL DESCRIPTION n E a w = ~ w �2 m E U a 0 n m w J Q O CJ �- 0 0 @ m EL 0 0 DP (0') GRAVEL FILL; some organic -rich Silty Clay 4.4 (1') Silty CLAY (CLML); medium plasticity, soft, moist, dark gray and black, stained, 227.9 some wood fragments 5 (3.5') Clayey SILT (MLCL); medium stiff, moist, dark brown, gray, black, and dull red, 108.4 5 slight odor 6.8 7' Sand SILT MLS medium stiff, wet, tan, gray, and dull yellow, relic structures and ( ) Y ( )� 9 Y, foliations (SAPROLITE) 2.6 10 2.3 10 (115) Clayey SILT (MLCL); trace sand, medium plasticity, stiff, wet, tan, gray, brown, 4.7 and black, relic structures and foliations (SAPROLITE) 15 3.8 15 5.4 5.1 20 (21') Sandy SILT (MLS); trace sand, medium stiff, wet, brown, tan, gray, and black, relic 6.0 20 structures and foliations (SAPROLITE) 3.9 25 4.3 25 (26') Silty CLAY (CLML); stiff, wet, dark brown, dull orange, and gray, relic structures and 3.8 foliations (SAPROLITE) 2.0 30 4.9 30 (32') Silty CLAY (CLML); trace sand, soft, wet, gray, brown, black, and white, abundant relic foliations (SAPROLITE) 35 4.4 35 40 = _ = 2.8 40 == (41') Poorly graded SAND with silt (SP-SM); very dense, wet, dark gray, white, and black, some rock fragments (PARTIALLY WEATHERED ROCK) 45 BEDROCK- Competent slightly weathered (GRANITE) 3 2(49.5') 45 50 50 NOTES: Hole precleared to 5.0' by Geologic Exploration using hand auger. generated using GroundLogs.online V 0 MW-10D (821.67) 00nv M�W_ 7 (822.80) 1 00 VACANT BUILDING S (300 W. GATE / MW_8 DRAM & DRAUGHT-----"o MW-8D (825.57) (825.64) VACANT GREE`O 0 CITGO GAS URBAN MINI ST�1` MW-9 STATION (825.30) I \ I i LEGEND — - - — SOURCE PROPERTY BOUNDARY PARCELBOUNDARY PERMANENT TYPE II MONITORING WELL O PERMANENT TYPE III MONITORING WELL 4 TEMPORARY MONITORING WELL DESTROYED MONITORING WELL (825.30) GROUNDWATER ELEVATION (FT MSL) 826 GROUNDWATER ELEVATION CONTOUR (FT MSL) (DASHED WHERE INFERRED) INFERRED GROUNDWATER FLOW DIRECTION NOTES: 1. MONITORING WELLS GAUGED ON 3/22/21 2. MW-4D, MW-4BR, MW-8D & MW-10D NOT USED IN GROUNDWATER CONTOURS. 3. MONITORING WELL MW-5 FOUND DESTROYED DURING AUGUST 2018 SAMPLING EVENT DUE TO CONSTRUCTION ACTIVITIES ON 300 W. GATE CITY BOULEVARD. P, co MW-6� (825.68) MW-4BR MW-4 (825.44) (825.64) � I MW-4D (825.17) (y s 00 N N 00 0 I I MW-3 (828.10) IF TMW-1 . LE IS ST% TMW-2 h f #MW-1 (827.30) - (827 88) TMW-3 (� J / 1 W PRGE Gk�j SBORO Tv1 � I i I1 ELITE CAR AUDIO I & AUTO TINT GATE C/TySOUCEVARD 9 APPROXIMATE 0 100 200 SCALE IN FEET TITLE SHALLOW GROUNDWATER GRADIENT MAP (MARCH 2O21) PROJECT FORMER ODORLESS CLEANERS DSCA SITE ID: DC410047 205 W. LEWIS STREET GREENSBORO, NORTH CAROLINA 14 hart I hickman 2)33 South 7 n-on Sheet -Suite 100 1 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) SMARTER ENVIRONMENTAL SOLUTIONS License # C-1269 / #C-245 Geologc DATE: 6-1-21 REVISION NO. 0 JOB NO. DSO-109 ATTACHMENT NO. 6 a a a 7 � I I / � 1 I \ 1 M W-6 (0.0254) VAC T MW-3 �MW-10D I (<0.00050)* (<0.0005o0) TMW-1 1 ♦ M4BR (205 W. LE S ST% W-1 / MW-4 # (1.23) TMW-2 -7 (0.248) M W-4D M W-1 (0.588) W (<0.000500) #(0.00380) MW-2 -�_ (<0.00050)* (610 S. EUGENE iT) ; TMW-3� I i Fri W I o I 0 O FORGE GREENSBORO VACANT BUILDING ppA O I(300 W. GA LVD) TM ` � MW-8 DRAM & DRAUGHT \ \ I I MW-81D (<0.000500) (<0.000500) VACANT 1 I IELITE CAR AUDIO ` I & AUTO TINT i I -------- Gg GREENSBORO "- I #MW-9 CITGO GAS TFC/TyBOU�EVgRD �- URBAN MINISTRY i STATION i II I I I 1 LEGEND — — — SOURCE PROPERTY BOUNDARY PARCELBOUNDARY PERMANENT TYPE II MONITORING WELL APPROXIMATE 0 100 200 G PERMANENT TYPE III MONITORING WELL SCALE IN FEET TEMPORARY MONITORING WELL TITTI DESTROYED MONITORING WELL PCE ISOCONCENTRATION MAP (MARCH 2O21) (0.248) PCE CONCENTRATION (mg/L) PROJECT FORMER ODORLESS CLEANERS —0.007— PCE ISOCONCENTRATION CONTOUR (mg/L) DSCA SITE ID: DC410047205 W. LEWIS STREET NOTES: GREENSBORO, NORTH CAROLINA 1. GROUNDWATER SAMPLES COLLECTED ON 3/22/21 & 3/23/21. � 2923 South Tryon Street -Suite 100 hart h i c k m a n Charlotte, North Carolina 28203 2. * INDICATES CONCENTRATION FROM 2019 GROUNDWATER SAMPLING EVENT. 704-586-0007(p) 704-586-0373(f 3. PCE = TETRACHLOROETHYLENE SMARTER ENVIRONMENTAL SOLUTIONS License # C-1269 / #C-245 Geology 4. MONITORING WELL MW-5 FOUND DESTROYED DURING AUGUST 2018 SAMPLING DATE: 6-1-21 REVISION NO. 0 EVENT DUE TO CONSTRUCTION ACTIVITIES ON 300 W. GATE CITY BOULEVARD. JOB NO. DSO-109 ATTACHMENT NO. 7A MW-10D 3/22/21 PCE <0.000500 TCE <0.000500 cis-1,2-DCE <0.000500 # 17 W-10D L M W-7 MW-7 3/22/21 PCE <0.000500 TCE <0.000500 cis-1,2-DCE <0.000500 MW-8 3/22/21 PCE <0.000500 TCE <0.000500 cis-1,2-DCE <0.000500 MW-6 3/23/21 PCE 0.0254 TCE 0.00261 cis-1,2-DCE 0.000401 J MW-4BR 3/23/21 PCE 1.23 TCE 0.0150 cis-1,2-DCE 0.0125 MW-4 3/23/21 PCE 0.248 TCE 0.00599 cis-1,2-DCE 0.00282 MW-41D 3/23/21 PCE 0.588 TCE 0.00577 cis-1,2-DCE 0.00286 J MW-1 3/22/21 PCE 0.00380 TCE 0.00268 cis-1,2-DCE <0.000500 JMW-4BR MW- MW-I4D (610 S. EUGENE IT) I VACANT BUILDING (300 W. GATE CITY BLVD) MW-3 12/12/19 PCE <0.00050 TCE <0.00050 cis-1,2-DCE <0.00050 MW-3 -(�TMW---1 (205 W. LEWIS ¢TM W-2 W MW-1 h CID TMW-3� W MW-2 12/12/19 PCE <0.00050 TCE <0.00050 cis-1,2-DCE <0.00050 u I MW-8 DRAM & DRAUGHT IV I V V -:J� / MW-8D , VACANT MW-8D PCE 3/22/21 <0.000500 MW-9 12/12/19 PCE <0.00050 TCE <0.00050 cis-1,2-DCE <0.00050 TCE <0.000500 cis-1,2-DCE <0.000500 GREENSBORO CITGO GAS T URBAN MINISTRY MW-9 STATION i i I � I � Ii I � i i I LEGEND LEGEND SOURCE PROPERTY BOUNDARY PARCELBOUNDARY PERMANENT TYPE II MONITORING WELL 0 PERMANENT TYPE III MONITORING WELL TEMPORARY MONITORING WELL A. DESTROYED MONITORING WELL SAMPLE ID CONSTITUENT- NOTES W-10D 3/22/21 PCE <0.000500 TCE <0.000500 cis-1,2-DCE <0.00050 SAMPLE DATE -CONCENTRATION (mg/L) 1. ONLY PCE-RELATED CONSTITUENTS ARE SHOWN ON FIGURE. SEE TABLE 8 FOR COMPLETE SUMMARY OF DETECTED CONSTITUENTS 2. PCE = TETRACHLOROETHYLENE; TCE = TRICHOLORETHYLENE DCE = DICHLOROETHYLENE 3. BOLD CONCENTRATION EXCEEDS NC 2L STANDARDS. 4. MONITORING WELL MW-5 FOUND DESTROYED DURING AUGUST 2018 SAMPLING EVENT DUE TO CONSTRUCTION ACTIVITIES ON 300 W. GATE CITY BOULEVARD. TM - � I ITE CAR AUDIO & AUTO TINT Gq TE C/T yBOU�E(rgR� 0 APPROXIMATE 0 100 200 SCALE IN FEET ' =E GROUNDWATER CONTAMINANT CONCENTRATION MAP F "'F FORMER ODORLESS CLEANERS DSCA SITE ID: DC410047 205 W. LEWIS STREET GREENSBORO, NORTH CAROLINA -4 2123100 hart h i c k m a n Char South Tryon StolenStreet-282 3 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f SMARTER ENVIRONMENTAL SOLLTIONS License # C-1269 / #C-245 Geology DATE: 6-1-21 REVISION NO. 0 JOB NO. DSO-109 ATTACHMENT NO. 7B Monitoring Well Installation Report Wades Dry Cleaning DSCA ID: DC410052 607 S. Elm Street Greensboro, Guilford County North Carolina Dry -Cleaning Solvent Cleanup Act Program H&H Job No. DSO-147C November 6, 2020 hart � hickman SMARTER ENVIRONMENTAL SOLUTIONS 2923 South Tryon Street, Suite 100 3921 Sunset Ridge Rd, Suite 301 Charlotte, NC 28203 Raleigh, NC 27607 www.harthickman.com 704.586.0007 main 919.847.4241 main Table 1: Site Chronology DSCA ID No.: I DC410052 Chronology of Events Instructions: Brief description of all significant events that have occurred since a problem was Date suspected at the facility. Commence with the first date a problem was suspected and continue through the most recent activity described in the current report. Terracon conducted a Limited Site Investigation and submitted a report to Range Properties on March 21, 2017. March 2017 Terracon identified tetrachloroethylene (PCE) and its degradation products in soil and groundwater at the former dry- cleaning facility. April 2018 The Wades Dry Cleaning site is certified into the DSCA Program. Hart & Hickman, PC (H&H) conducted initial prioritization assessment activities at the site, which included the collection of soil samples from five soil borings (SB-5 through SB-9), installation and sampling of six temporary November 2018 monitoring wells (TMW-4 through TMW-9), collection of one soil gas sample (TSG-1), collection of one crawlspace air sample (CS-1), and collection of one sub -slab vapor sample (SS-1). H&H also completed a receptor survey within a 0.5- mile radius of the former dry-cleaning facility. On January 31, 2019, H&H submitted a Prioritization Assessment Report to the DSCA Program documenting the results of the assessment activities. H&H conducted additional assessment activities at the site, which included the installation and sampling of three June 2019 permanent monitoring wells (MW-1 through MW-3), collection of one soil gas sample (TSG-2), and collection of two Shelby tubes. On October 3, 2019, H&H submitted a report to the DSCA Program documenting the results of the assessment activities. H&H conducted additional assessment activities at the site, which included the installation and sampling of two new July 2020 permanent monitoring wells (MW-4 through MW-5) and sampling exsiting monitoring wells (MW-1, MW-2, and MW- 3). On November 6, 2020, H&H submitted a report to the DSCA Program documenting the results of the assessment activities. Page 1 of 1 Client: DSCA WELL LOG hart ► hickman Project: Wade's Cleaners (DSO-147) Well No. MW-4 I SMARTER FWRONWWAL5OLLmON5 Address: 60 South Elm Street, Greensboro, Page: 1 of 1 NC Drilling Start Date: 7113120 Boring Depth (ft): 25.0 Well Depth (ft): 25.0 Drilling End Date: 7/13/20 Boring Diameter (in): 2.25 Well Diameter (in): 2.0 Drilling Company: GEX Sampling Method(s): 5 ft Macrocore Sleeves Screen Slot (in): 0.001 Drilling Method: Hollow Stem Auger DTW During Drilling (ft): Riser Material: Sch 40 PVC Drilling Equipment: Geoprobe 3230 DT DTW After Drilling (ft): 7.37 Screen Material: Sch 40 PVC Slotted Driller: Jeremy Ringler Top of Casing Elev. (ft): Seal Material(s): Bent. -Cement Grout/Bent. Chips Logged By: Thomas Vaughan Location (X,Y): Filter Pack: Sand Pack COLLECT MEASURE W z O _ w a O p w J a N Q N o SOIL/ROCK VISUAL DESCRIPTION n E a wo g �' > U w Q O U E o p o m U) m a m 0 0 --(0') Asphalt / 0.6 (0.5') Silty SAND with gravel (SM); little fine -coarse gravel, loose, moist, gray/light 1.7 brown, slight odor 1.5 - 1.0 (S) Silty SAND (SM); little clay, loose, moist, gray/light brown 0.5 (4') Silty SAND (SM); little clay, loose, moist, light brown/tan 5 0.4 5 (5') Silty SAND (SM); medium dense, moist, light brown/gray/light gray 0.4 0.3 10 10 1.0 0.3 (1S) Silty SAND (SM); little clay, medium dense, moist, light brown/gray/light gray, white PWR 15 2 0 15 (15.5') Sandy SILT (ML); medium stiff, wet, light brown/gray 0.0 (17') Silty SAND (SM); dense, wet, light brown/gray/brown/white, PWR 1.6 20 20 0.8 (21') Sandy SILT (ML); medium stiff, wet, brown/light brown/dark gray (23') PWR: very dense, wet, white/light brown/tan VV V V 25 (245) DPT Refusal 25 (25') Boring terminated, HSA Refusal 30 30 NOTES: Hole precleared to 5.0' on 7/13/20 using hand auger. generated using GroundLogs.onhne COMMERCIAL LEGEND MV1 COMMERCIAL GATEWAY CENTER PARKING AREA 620 S. ELM STREET (COMMERCIAL) GATEWAY CENTER OFFICE BUILDING 734 S. ELM STREET (COMMERCIAL) WEST GATE CITY BLVD S. ELM STREET J RESTAURANT) S. ELM STREET (VACANT) W co W ti O co rm:w -1(UST) HORIGAN'S HOUSE OF TAPS & THE BEARDED GOAT 603 S. ELM STREET (COMMERCIAL) MELLOW MUSHROOM 609 S. ELM STREET (COMMERCIAL) COMMERCIAL MW-4 E AL A BITAEl TM44.1- COMMERCIAL EAST LEW/S STREET TMW-6h TMW-3 F1 _ TMW-5� N-2 I M W-2 }TMW-1 �-1 `FORMER WADES DRY CLEANING (DC410052) i i I RESIDENTIAL APARTMENTS COMMERCIAL LOMMERCIA EAST GATE CITY BLVD W co O Z J Q — — — — SOURCE PROPERTY BOUNDARY PROPERTY BOUNDARY BUILDING OUTLINE GROUNDWATER ELEVATION (FT MSL) GROUNDWATER ELEVATION CONTOUR (FT MSL) INFERRED GROUNDWATER FLOW DIRECTION TEMPORARY MONITORING WELL PERMANENT MONITORING WELL NOTES: 1. MONITORING WELLS GAUGED ON 7/14/2020. 0 APPROXIMATE 0 60 120 SCALE IN FEET JULY 2020 ---- WADES DRY CLEANING DSCA SITE NO: DC410052 607 SOUTH ELM STREET GUILFORD COUNTY, NORTH CAROLINA .4 2923 South Tryon Street -Suite 100 haft ,,y L I hICkman Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(t sNunm En EmsDKME WAS sadunons License # C-1269 / #C-245 Geologic DATE: 11-6-20 REVISION NO. 0 JOB NO. DSO-147 ATTACHMENT NO. 6 r-m-w -1(UST) h EAST TMW-Y TMW-6h HORIGAN'S HOUSE OF TAPS S. ELM STREET & THE BEARDED GOAT J RESTAURANT) 603 S. ELM STREET COMMERCIAL) S. ELM STREET (VACANT) MELLOW MUSHROOM W 609 S. ELM STREET (COMMERCIAL) co W MW-3_____� ti J r co COMMERCIAL 620 S. ELM STREET 1�nKANACOOIAi \ M W-3 PCE 0.029 TCE 0.0024 cis-1,2-DCE 0.0014 COMMERCIAL — - - E9MME-RCIAL _ W-3 N-1 TMW-%� AW 2 I COMMERCIAL MW-2 � TMW-1 FORMER WADES DRY CLEANING (DC410052) [COMMERCIAL MW-1 PCE <0.00050 TCE <0.00050 cis-1,2-DCE 0.00033 J I i I I OMMERCIA i M W-2 PCE 0.00054 TCE <0.00050 cis-1,2-DCE <0.00050 RESIDENTIAL APARTMENT: LEGEND — - - — SOURCE PROPERTY BOUNDARY PROPERTY BOUNDARY BUILDING OUTLINE TEMPORARY MONITORING WELL PERMANENT MONITORING WELL r-SAMPLEID MW-1 PCE <0.00050 TCE <0.00050 cis-1,2-DCE 0.00033 J CONSTITUENT CONCENTRATION (mg/L) NOTES: 1. ONLY PCE DRY-CLEANING RELATED CONSTITUENTS SHOWN. 2. SAMPLES COLLECTED ON 7/14/2020 AND 7/15/2020. 3. BOLD CONCENTRATIONS EXCEED NC 2L STANDARDS. 4. PCE=TETRACHLOROETHENE TCE = TRICHLOROETHENE DCE = DICHLOROETHENE 5. IMPACTS IDENTIFIED IN GROUNDWATER MONITORING WELL MW-5 APPEAR TO BE ASSOCIATED WITH NEARBY BROWNFIELDS SITES WEST LEWIS STREET (17046-13-041) AND/OR MODEL LINEN (08007-04-041). 9 APPROXIMATE 60 120 1,Y�7_1��1�■y��l WEST GATE CITY BLVD EAST GATE CITY BLVD •J LEGEND — — — — SOURCE PROPERTY BOUNDARY PROPERTY BOUNDARY BUILDING OUTLINE TEMPORARY MONITORING WELL PERMANENT MONITORING WELL TEMPORARY MONITORING WELL ASSOCIATED WITH BROWNFIELDS SITE ABANDONED MONITORING WELL ASSOCIATED WITH BROWNFIELDS SITE (0.00054) PCE CONCENTRATION (mg/L) -0 0007- PCE ISOCONTOUR (mg/L) (DASHED WHERE INFERRED) NOTES: 1. SAMPLES FROM MW-1 THROUGH MW-5 WERE COLLECTED ON 7/14/2020 AND 7/15/2020. 2. HISTORICAL DATA FROM DSCA SITE TEMPORARY MONITORING WELLS WAS CONSIDERED IN CONTOURING. 3. MW-1 DATA NOT USED IN CONTOURING DUE TO INCONSISTENCY WITH SURROUNDING TEMPORARY WELL DATA. 4. IMPACTS IDENTIFIED IN GROUNDWATER MONITORING WELL MW-5 APPEAR TO BE ASSOCIATED WITH NEARBY BROWNFIELDS SITES WEST LEWIS STREET (17046-13-041) AND/OR MODEL LINEN (08007-04-041). 5. * DATA FROM TEMPORARY AND PERMANENT MONITORING WELLS ASSOCIATED WITH NEARBY BROWNFIELDS SITES WEST LEWIS STREET (17046-13-041) AND MODEL LINEN (08007-04-041) WAS OBTAINED FROM PHASE// ENVIRONMENTAL ASSESSMENT, WEST LEWIS STREET PROPERTY PREPARED BY ENVIROASSESSMENTS, DATED AUGUST 8, 2013 AND PHASE II ENVIRONMENTAL ASSESSMENT, 109-111 WEST LEWIS STREET PREPARED BY ENVIROASSESSMENTS, DATED SEPTEMBER 8, 2014. SAMPLES WERE COLLECTED IN 2013 OR 2014. 9 APPROXIMATE 60 120 SCALE IN FEET WEST GATE CITY BLVD f EAST GATE CITY BLVD Attachment C Ad6 7t I No -ilk 41/ ZJF KiA- m ;-i 16 WALKER A NK I w - ------- Y.V' LEWIS 10 BAIN L I, J W. 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Eanbom field suveys conducted in: vbv EM S.nbon4 kw Revm+ch Aj=c ae 11 P fimm EOA sanboM I= _ H t, Wes: c L L mm - 1) ode"Mof_ 1- 4 rr_ �c . t:^ ob 0 T # 9f pjo it s z 10 N, Itl IF BUMDING RENOVATION 7UNDR4G PROVIDED BY DOWNTOWN GREENSBORO off 7 -s � . - Via• ' � �::: y,, �, -� - ��-� :J � .. �t • - ..� � � - I r ~= �� P OUCAR ''BOX -CAR I!AR ♦ AACAIVS BAR +,LRCA VE —lk r gob" 'gear -*.`'� •. ' ' -�. h -4w 6 -41 'MIL: •'..+"11�'` �i'.:_� !1 : y F,5.:. ��''4�r_ Nw•���•... ,yam ; �" �_. 01r: p f .,r �� - pL � .. il• -�K7N Wit. gF� �� �`, R �y F Attachment D VaporP no Using Vapor Pins® for Source Characterization The Vapor Pin® is ideally suited for locating Volatile Organic Compound (VOC) contamination sources beneath pavement. Our experience is that most sites have sources of contamination that in addition to those associated with underground tanks and degreasing areas. Unsuspected source areas often correspond to former exterior doors that were obscured by later building expansion. Cox -Colvin has located such sources equipped with little more than some Vapor Pins®, a hammer drill, and a multi -gas meter. Cox-Colvin's approach to VOC source investigation consists of installing Vapor Pins® along a grid, allowing the points to equilibrate, and collecting readings with a multi -gas meter. With a team of two people, we've installed as many as 90 Vapor Pins® in one day, and sampled, removed the Vapor Pins®, and plugged the holes on the following day. For source characterization, we normally install brass Vapor Pins® in the stick-up configuration on a grid spacing of 20 to 30 feet. We cover the Vapor Pins® with traffic cones and allow them to equilibrate for at least an hour. We then collect field readings with a hand-held multi -gas meter capable of measuring VOCs via Photo -Ionization Detector (PID), oxygen (02), and Lower Explosive Limits (LEL). The PID indicates VOC sources. 02 in soil gas is normally lower than in air, but unusually low levels (<5%), especially with high LEL readings, are characteristic of methane generation (methanogenesis). Methanogenesis occurs when non -chlorinated solvents or other organic matter degrades at too high a rate for 02 replenishment. After collecting field readings at all of the sample points, samples are collected from locations with elevated PID readings, and submitted to a laboratory for confirmation. Samples can be collected into evacuated glass vials, Bottle Vacs, Tedlar bags, Summa canisters, sorbent tubes, and potentially other devices. Some containers do not offer low enough reporting levels for vapor intrusion sampling, but low levels are probably not needed for locating contaminant sources. At the conclusion of sampling, remove the Vapor Pins® and fill the holes with hydraulic cement or caulk. Urethane and polyurethane caulks are recommended by radon mitigation guidance for filling holes and cracks, but they contain VOCs that could interfere with subsequent sampling. Hydraulic cement does not contain VOCs, but it sets up quickly, making it potentially difficult to fill borings to total depth. After removing the silicone sleeve and other plastic parts from the Vapor Pins®, decontaminated them for reuse. Cox -Colvin has a number of Vapor Pins® that they have used an average of seven or eight times with no breakage or damage. K:\CCA\BD\Vapor Pin\Procedures\Using Vapor Pins for Source Characterization.docx Vapor Pin Enterprises, Inc. ® Standard Operating Procedure VaporP i Use of the VAPOR PIN® Drilling Elowns_ Guide and Secure Cover INNUM5 Updated March 16, 2018 Scope: This standard operating procedure (SOP) describes the methodology to use the VAPOR PIN® Drilling Guide and Secure Cover to install and secure a VAPOR PIN® in a flush mount configuration. Purpose: The purpose of this SOP is to detail the methodology for installing a VAPOR PIN® and Secure Cover in a flush mount configuration. The flush mount configuration reduces the risk of damage to the VAPOR PIN® by foot and vehicular traffic, keeps dust and debris from falling into the flush mount hole, and reduces the opportunity for tampering. This SOP is an optional process performed in conjunction with the SOP entitled "Installation and Extraction of the VAPOR PIN®". However, portions of this SOP should be performed prior to installing the VAPOR PIN®. Equipment Needed: • VAPOR PIN® Secure Cover (Figure 1); 0 VAPOR PIN® Drilling Guide (Figure 2); 0 Hammer drill; • 11/2-inch diameter hammer bit (Hilti' TE- YX 11/2" x 23" #00293032 or equivalent); • 5/8-inch diameter hammer bit (HiltiT" TE- YX 5/8" x 22" #00226514 or equivalent); • assembled VAPOR PIN®; • # 14 spanner wrench; • Wet/Dry vacuum with HEPA filter (optional); and • personal protective equipment (PPE). Figure 1. VAPOR PIN® Secure Cover Figure 2. VAPOR PIN® Drilling Guide Installation Procedure: 1) Check for buried obstacles (pipes, electrical lines, etc.) prior to proceeding. 2) Set up wet/dry vacuum to collect drill cuttings. 3) While wearing PPE, drill a 1 1/2-inch diameter hole into the concrete slab to a depth of approximately 1 3/4 inches. Pre -marking the desired depth on the drill VAPOR PIN' protected under US Patent # 8,220,347 B2, US 9,291,531 B2 and other patents pending Vapor Pin Enterprises, Inc. • 7750 Corporate Blvd., Plain City, Ohio 43064 • (614) 504-6915 • www.vaporpin.com bit with tape will assist in this process. 4) Remove cuttings from the hole and place the Drilling Guide in the hole with the conical end down (Figure 3). The hole is sufficiently deep if the flange of the Drilling Guide lies flush with the surface of the slab. Deepen the hole as necessary, but avoid drilling more than 2 inches into the slab, as the threads on the Secure Cover may not engage properly with the threads on the VAPOR PIN®. Figure 3. Testing Depth with the Drilling Guide 5) When the 11/2-inch diameter hole is drilled to the proper depth, replace the drill bit with a 5/8-inch diameter bit, insert the bit through the Drilling Guide (Figure 4), and drill through the slab. The Drilling Guide will help to center the hole for the VAPOR PIN®, and keep the hole perpendicular to the slab. 6) Remove the bit and drilling guide, clean the hole, and install the VAPOR PIN® in accordance with the SOP "Installation and Extraction of the VAPOR PIN®. Standard Operating Procedure Installation and Removal of the Vapor Pin® Updated March 16, 2018 Pacre 2 Figure 4. Using the Drilling Guide 7) Screw the Secure Cover onto the VAPOR PIN® and tighten using a # 14 spanner wrench by rotating it clockwise (Figure 5). Rotate the cover counter clockwise to remove it for subsequent access. Figure 5. Tightening the Secured Cover 1 imitation -,- On slabs less than 3 inches thick, it may be difficult to obtain a good seal in a flush mount configuration with the VAPOR PIN.® VAPOR PIN' protected under US Patent # 8,220,347 132, US 9,291,531 B2 and other patents pending Vapor Pin Enterprises, Inc. • 7750 Corporate Blvd., Plain City, Ohio 43064 • (614) 504-6915 • VaporPin.CoxColvin.com VaporPMINOMM-_ INNUM�� Scope: The operating procedure describes methodology to test a VAPOR PIN® equivalent sub -slab sampling device leakage of indoor air. Purpose: Standard Operating Procedure Leak Testing the VAPOR PIN® Via Water Dam Updated March 16, 2018 vacuum is recommended. Any remaining dust can be picked up with a piece of the scrap Play -Doh or modeling clay. or for 3) The purpose of this procedure is to assess the potential for indoor air to leak past the VAPOR PIN ® and dilute the sub -slab soil gas sample. 4) Equipment Needed: • VAPOR PIN® water dam • Play -Doh or VOC free modeling clay • distilled water 5) • VAPOR PIN® and associated sample tubing. Procedure: 1) Drill a 5/8" diameter hole in the concrete slab and install the VAPOR PIN® as per the Standard Operating Procedure (SOP). 6) 2) Clean the slab within the VAPOR PIN® to wetting the concrete concrete is dry befc avoid cleaning wil substances. A whisl a 2-inch radius of move dust. Avoid or wait until the e proceeding and VOC-containing broom or shop Roll a 1-inch diameter ball of Play -Doh or modeling clay between your palms to form a "snake" approximately 7 inches long and press it against the end of the pipe couple. Push the couple against the slab to form a seal between the pipe and the concrete. Attach the sample tubing to the top of the VAPOR PIN® and pour enough distilled water into the pipe couple to immerse base of the VAPOR PIN®, and if desired, the tubing connection at the top of the VAPOR PIN®. Purge the sample point as required by the data quality objectives. Concrete will absorb some of the water, which is normal; however, if water is lost to the sub -slab, stop, remove the water from the couple, and reposition the VAPOR PIN® to stop the leakage. Reseat the leak test equipment, if needed. If the VAPOR PIN® is installed in the flush -mount configuration, the larger hole can be filled with water in place of the plastic pipe fitting and Play -Doh or modeling clay. VAPOR PIN't protected under US Patent # 8,220,347 B2 Vapor Pin Enterprises, Inc. • 7750 Corporate Blvd., Plain City, Ohio 43064 • (614) 504-6915 • www.vaporpin.com aceAnalytical Pace Analytical Services, LLC Method Detection Limits and Reporting Limits by EPA TO15 SIM Scan LCS DUP Analyte CAS # MDL (ppbv) PRL (ppbv) MW MDL (Ug/m3) PRL (Ug/m3) Lower Upper RPD 1, 1, 1 -Trichloroethane 71-55-6 0.00448 0.01 133.4047 0.0248 0.0555 56 133 25 1,1,2,2-Tetrachloroethane 79-34-5 0.00552 0.01 167.8498 0.0385 0.0698 57 146 25 1,1,2-Trichloroethane 79-00-5 0.00482 0.01 133.4047 0.0267 0.0555 54 146 25 1,1,2-Trichlorotrifluoroethane 76-13-1 0.0724 0.2 187.3762 0.564 1.56 63 139 25 1,1-Dichloroethane 75-34-3 0.00362 0.01 98.9596 0.0149 0.0411 63 130 25 1,1-Dichloroethene 75-35-4 0.00500 0.01 96.9438 0.0202 0.0403 59 138 25 1,2,4-Trichlorobenzene 120-82-1 0.493 1 181.4487 3.72 7.54 60 133 25 1,2,4-Trimeth (benzene 95-63-6 0.0904 0.2 120.1938 0.452 1.00 70 137 25 1,2-Dibromoethane 106-93-4 0.00483 0.01 187.8616 0.0377 0.0781 55 148 25 1,2-Dichlorobenzene 95-50-1 0.0814 0.2 147.0036 0.498 1.22 70 137 25 1,2-Dichloroethane 107-06-2 0.00732 0.01 98.9596 0.0301 0.0411 61 130 25 1,2-Dichloropropane 78-87-5 0.00262 0.01 112.9864 0.0123 0.0470 60 140 25 1,3,5-Trimethylbenzene 108-67-8 0.0798 0.2 120.1938 0.399 1.00 70 133 25 1,3-Butadiene 106-99-0 0.00956 0.01 54.0914 0.0215 0.0225 65 138 25 1,3-Dichlorobenzene 541-73-1 0.0951 0.2 147.0036 0.581 1.22 70 137 25 1,4-Dichlorobenzene 106-46-7 0.164 0.5 147.0036 1.00 3.06 70 134 25 2-Butanone (MEK) 78-93-3 0.123 1 72.1057 0.369 3.00 65 143 25 2-Hexanone 591-78-6 0.179 1 100.1589 0.745 4.16 60 148 25 2-Propanol 67-63-0 0.279 1 60.1 0.697 2.50 65 135 25 4-Ethyltoluene 622-96-8 0.114 0.5 120.1938 0.570 2.50 70 132 25 4-Methyl-2-pentanone (MIBK) 108-10-1 0.124 1 100.1602 0.518 4.16 70 135 25 Acetone 67-64-1 0.499 1 58.0798 1.21 2.41 59 132 25 Benzene 71-43-2 0.00496 0.01 78.1134 0.0161 0.0325 59 133 25 Benzyl Chloride 100-44-7 0.228 0.5 126.58 1.20 2.63 56 150 25 Bromodichloromethane 75-27-4 0.00412 0.01 163.8289 0.0281 0.0681 60 133 25 Bromoform 75-25-2 0.135 0.5 252.7309 1.42 5.25 69 150 25 Bromomethane 74-83-9 0.0575 0.2 94.9387 0.227 0.789 61 141 25 Carbon Disulfide 75-15-0 0.0692 0.2 76.131 0.219 0.633 66 134 25 Carbon tetrachloride 56-23-5 0.00515 0.01 153.823 0.0329 0.0639 56 138 25 Chlorobenzene 108-90-7 0.0588 0.2 112.5585 0.275 0.936 70 130 25 Chloroethane 75-00-3 0.0969 0.2 64.5145 0.260 0.536 65 143 25 Pace Analytical Services, LLC 612-607-1700 KL 8/2/18 1700 Elm Street SE, Suite 200 Minneapolis, MN 55414 www.pacelabs.com aceAnalytical Pace Analytical Services, LLC Method Detection Limits and Reporting Limits by EPA TO15 SIM Scan LCS DUP Analyte CAS # MDL (ppbv) PRL (ppbv) MW MDL (Ug/m3) PRL (Ug/m3) Lower Upper RPD Chloroform 67-66-3 0.00426 0.01 119.3779 0.0211 0.0496 66 130 25 Chloromethane 74-87-3 0.0742 0.2 50.4877 0.156 0.420 58 140 25 cis-1,2-Dichloroethene 156-59-2 0.00348 0.01 96.9438 0.0140 0.0403 65 130 25 cis-1,3-Dichloropropene 10061-01-5 0.00588 0.01 110.9706 0.0271 0.0461 40 150 25 Cyclohexane 110-82-7 0.101 0.5 84.1608 0.353 1.75 70 133 25 Dibromochloromethane 124-48-1 0.0830 0.2 208.2799 0.719 1.73 46 145 25 DichlorodifIuoromethane 75-71-8 0.0584 0.2 120.9138 0.293 1.01 69 130 25 Dichlorotetrafluoroethane 76-14-2 0.0615 0.2 170.9216 0.437 1.42 68 130 25 Ethanol 64-17-5 0.424 1 46.07 0.812 1.92 65 146 25 Ethyl Acetate 141-78-6 0.0518 0.2 88.106 0.190 0.733 68 136 25 Ethyl Benzene 100-41-4 0.0690 0.2 106.167 0.305 0.883 70 133 25 Hexachlorobutadiene 87-68-3 0.181 0.5 260.762 1.97 5.42 59 140 25 m&p-Xylene 106-42-3 0.158 0.4 106.167 0.699 1.77 70 133 25 Methyl Tert Butyl Ether 1634-04-4 0.181 1 88.1492 0.663 3.66 70 132 25 Methylene chloride 75-0902 0.267 1 84.9328 0.944 3.53 67 132 25 Naphthalene 91-20-3 0.248 0.5 128.1732 1.32 2.66 55 136 25 n-Heptane 142-82-5 0.0913 0.2 100.2034 0.380 0.833 64 136 25 n-Hexane 110-54-3 0.0867 0.2 86.1766 0.311 0.716 70 130 25 o-Xylene 95-47-6 0.0780 0.2 106.167 0.344 0.883 70 132 25 Propylene 115-07-1 0.0816 0.2 42.0804 0.143 0.350 37 150 25 Styrene 100-42-5 0.0794 0.2 104.1512 0.344 0.866 70 139 25 Tetrachloroethene 127-18-4 0.00440 0.01 165.834 0.0303 0.0689 142 25 Tetrahydrofuran 109-99-9 0.0870 0.2 72.1066 0.261 0.600 62 141 25 Toluene 108-88-3 0.0916 0.2 92.1402 0.351 0.766 70 130 25 trans-1,2-dichloroethene 156-60-5 0.00520 0.01 96.9438 0.0210 0.0403 67 131 25 trans-1,3-Dichloropropene 10061-02-6 0.00610 0.01 110.9706 0.0281 0.0461 34 150 25 Trichloroethene 79-01-6 0.00563 0.01 131.3889 0.0308 0.0546 58 141 25 Trichlorofluoromethane 75-69-4 0.0641 0.2 137.3684 0.366 1.14 59 140 25 Vinyl Acetate 108-05-4 0.0754 0.2 86.0902 0.270 0.716 57 150 25 Vinyl chloride 75-01-4 0.00985 0.01 62.4987 0.0256 0.0260 61 136 25 SIM analytes on 10AIR7 only. Pace Analytical Services, LLC 612-607-1700 KL 8/2/18 1700 Elm Street SE, Suite 200 Minneapolis, MN 55414 www.pacelabs.com ace Analytical Pace Analytical Services, LLC Method Detection Limits and Reporting Limits by EPA T015 SIM Scan EXTRA ANALYTES (available upon request at an additional cost) LCS I DUP Analyte CAS # MDL (ppbv) PRL (ppbv) MW MDL (ug/m3) PRL (ug/m3) Lower Upper RPD 1,2,3-Trimethyl benzene 526-73-8 0.0807 0.2 120.19 0.403 1.00 69 150 25 1,4-Dioxane 123-91-1 0.205 1 88.1051 0.751 3.66 70 145 25 2,2,4-Trimethylpentane 540-84-1 0.145 0.5 114.22 0.689 2.37 70 140 25 Acrolein 107-02-8 0.237 0.5 56.06 0.553 1.17 65 150 25 Acrylonitrile 107-13-1 0.145 0.5 53.06 0.320 1.10 64 142 25 Allyl Chloride 107-05-1 0.234 0.5 76.525 0.744 1.59 60 147 25 Chlorodifluoromethane 75-45-6 0.184 0.5 86.47 0.662 1.80 68 142 25 Di -isopropyl Ether 108-20-3 0.0795 1 102.1748 0.338 4.25 70 136 25 Ethyl Tert-Butyl Ether 637-92-3 0.175 1 102.1748 0.741 4.25 70 136 25 Isopentane 78-78-4 0.0997 0.5 72.15 0.299 1.50 44 150 25 Isopropyl benzene 98-82-8 0.0762 0.5 120.194 0.381 2.50 70 133 25 Methyl Methacrylate 80-62-6 0.0951 0.2 100.12 0.396 0.832 47 150 25 Methylcyclohexane 108-87-2 0.0950 0.5 98.186 0.388 2.04 70 137 25 N-Butylbenzene 104-51-8 0.201 0.5 134.2206 1.12 2.79 70 148 25 N-Propylbenzene 103-65-1 0.0805 0.5 120.1938 0.402 2.50 70 145 25 p-Isopropyltoluene 99-87-6 0.0922 0.2 134.22 0.515 1.12 70 143 25 Sec- Butylbenzene 135-98-8 0.155 0.5 134.2206 0.866 2.79 70 142 25 Tert Amyl Methyl Ether 994-05-8 0.243 1 102.1748 1.03 4.25 70 135 25 Tert Butyl Alcohol (TBA) 75-65-0 0.326 1 74.12 1.00 3.08 63 143 25 Tert-Butyl Benzene 98-06-6 0.0959 0.2 134.22 0.535 1.12 70 142 25 Vinyl Bromide 593-60-2 0.0810 0.2 106.95 0.360 0.889 70 140 25 THC as Gas (C4-C12) 11.95 23.90 51.9 104 59 150 25 Xylene (Total) 1330-20-7 0.1583 0.6 106.17 0.699 2.65 70 138 25 Surrogates 1,4-Dichlorobenzene-d4 (S) 3855-82-1 30 150 Hexane-d14 (S) 21666-38-6 30 150 Toluene-d8 (S) 2037-26-5 30 150 Highlighted cells are calculated results Pace Analytical Services, LLC 612-607-1700 KL 8/2/18 1700 Elm Street SE, Suite 200 Minneapolis, MN 55414 www.pacelabs.com aceAnalytical AIR CANISTERS Instructions for canister Grab Sampling (Tools needed: one ended 9/16" wrench) 1. INSPECTION — Inspect your canister shipment upon arrival. Compare the contents with the packing slip and notify Pace Analytical of any discrepancy or dam- age. Familiarize yourself with the contents you received by comparing them to the pictures on the right. Do not open the valve until you are ready to sample. Even a small loss of vacuum will compromise your sample. 2. CONNECTION — Remove the brass cap from the top of the can with a 9/16" wrench. If you are connecting to a predetermined sampling point you may have received the following: 6 inches of '/4 inch OD Teflon tubing, '/4 inch Swagelock® nut, ferrule, spacer nut and moisture filter (if requested). Connect these items in series us- ing the pictures on the right as a guide. The spacer fits between the nut and the ferrule. The ferrule must be pointed down toward the canister. Please note the con- nection to the canisters utilizes Swagelock® threading. For a proper connection, it's important that no cross - threading occurs. The canister connection is made by hand -tightening the Swagelock@ nut. Once connected, use an open ended (9/16") wrench to further tighten the connection. Make sure that the connection is firmly tight- ened. The final connection must be leak tight recognizing also that over -tightening can cause leaks as well. Do not use pliers or adjustable -end wrenches to tighten this Swagelock® connection. Use only open ended wrench- es for tightening. The canister is now ready for sampling. 3. SAMPLING — To begin sampling simply open the canister valve (you may have either a rotary valve or a toggle valve). One full turn counter clockwise for the rotary valve is sufficient. The toggle valve will open by flipping upward. During the initial sampling pro- cess you will hear a rush of air. Without a flow restric- tion the canister will fill in approximately 30-45 seconds. 4. COMPLETION — After sampling is complete, close the canister valve. Disassemble the components and return them in the original shipping package they were received in. Verify the contents for return to the labo- ratory. Complete the Chain -of -Custody form and re- turn with the samples to the laboratory. Be sure to reference the canister ID on the Chain -of -Custody. Grab Sample Configuration '++ — Moisture Filter 1/4" OD Teflon Tubing 1/4" Swagelock® Nut ,w Spacer nut Fe'r. ale Canister lnlef Canister 1D — ;.Rotary Valve -z�jjl!�.F 1 d 1 i H F ¢ E ---3 Sampl&ll) Tag I tM MK www.pacelabs.com ©2009 Pace Analytical Services Air Lab 1700 Elm Street, Minneapolis MN 55414 Questions? Please call the Air Technical phone number 612-607-6386 ...rim --/I1•k;g111c7,rnu.,rir.'I'IakigluS,d„fio„v SamplingInstructions Restricted flow Sampler Intended Applications: 30 minute sampling of 6 Liter Canister 5 minute sampling of 1 Liter Canister All media is pre -assembled for your convenience Do not attempt to remove the gauge from the canister Inspect your media • Remove the protective foam inserts and other packing material from the box. Set these inserts aside for return shipment • Lift and carry the canister by the frame ring near the top. • Review the contents of the package to ensure you have everything you need prior to sampling. • Consult your Pace Project Manager, or call the Air Technical Hotline @ 612-607-6386 if you have any questions. Prepare for Sampling (Figure 1) • Before sampling, you will first verify the initial vacuum. • With the brass cap on the assembly still in place, open the canister to check the initial vacuum. o Rotary Valve requires on full turn counter clockwise o Toggle Valve requires that you flip the valve upwards • Record initial vacuum_ on the Chain of Custody o Initial field reading (-inches of Fig) • Close the canister valve before moving on to next step. Collect Samples (Figure 2) • Remove the brass cap from the side of the sampling assembly by turning counter clockwise with a 9/16 inch wrench. (Figure 2) • Position the canister for sampling o NOTE: If tubing and fittings are required at this site, you will find these items and all instructions in the enclosed plastic bag. • Connect the sampling line as shown in the picture on the right. Open the canister valve to begin sampling • The Decline in vacuum should be proportional to the'collection time. After desired sampling time, close canister valve. o NOTE: The canister will continue to fill until the internal: pressure reaches ambient conditions ftsig). You are responsible for closing the valve on the canister at the desired time. • To end the sampling process close the valve on the canister and replace brass cap to the side of the gauge. • Verify final field vacuum by opening the canister. o Record the —inches of Hg on the COC. o Close canister valve Return Samples • Repackage the canister with the protective foam insert, and other packaging materials, to insure the integrity of your sample as it travels back to the lab. • Complete the shipping and COC documents • Return to Pace Analytical for analysis. • Return all components in the package as you received them. Complete a Chain of Custody record and return with the sample to Pace Analytical for analysis. Figure 1 Verify the initial vacuum. Sample Connection Point Figure 2 Remove the brass cap and connect the sampling line www.pacelabs.com ®®� ® � ® !- o ® ow ® o Analytical = =_ = : =_ -- — — — — -- _® -- —law aw �® -- Sampling Instructions for t-CANS Preassembled Air Canisters UnpaCK EZ-CANS 1. Remove the protective EZ-CANS foam insert from the box and retain it for return shipping. 2. To remove from the box, lift and carry EZ-CANS by the frame ring near the top of the canister. Avoid lifting by the flow controller or any part of the sampling assembly. 3. EZ-CANS are completely preassembled, leak -checked t� and ready to go. Prepare to Sample 1. Review the contents of the package to insure you have everything you need. 2. Remove the brass cap from the top of the sampling assembly by turning counter clockwise. It should be finger tight, if necessary use a 9/16" wrench. 3. Position the EZ-CANS for sampling. NOTE: If tubing and fittings are needed to sample subsurface or a hard to reach area, you will find these items and instructions in an enclosed plastic bag. Begin Sampling 1. Open the canister valve to begin sampling. Pace uses two valve styles: a. Rotary: One full turn counter clockwise b. Toggle: Flip the valve upward 2. The decline in vac;uulii should be directly proportional to the collection time. 3. Record initial vacuum on the Chain Of Custody. "Initial Field reading (-inches of Hg) End Sampling 1. Close the canister valve and record the vacuum gauge reading on the Chain of Custody. Final Field reading (-inches of Hg) 2. Reattach the brass cap to the top of the sampling assembly. 3. Repack the canister using the protective foam insert to insure the integrity of your sample. 4. Complete the shipping and COC documents and call the carrier for pickup. Questions? Call 612-601-6386 %J Brass Cap www. pacelabs. com @2010 Pace Analytical Services Air Lab Return to Pace Analytical @ 1700 Elm Street, Minneapolis MN 55414 Questions? Please call the Air Technical phone number 612-607-6386 Attachment E Pyramid Environmental & Engineering, P.C. Project #2021-132 Model Linen — W. Lewis Street SUB -SLAB VAPOR (SSV) ASSESSMENT WORK PLAN MODEL LINEN & WEST LEWIS STREET BROWNFIELDS PROJECTS 109, 111, 117-131, & 120 W. LEWIS STREET GREENSBORO, NC (GUILFORD COUNTY) Brownfields Site Name : # 17046-13-041 : West Lewis Street BFA Brownfields Site Name: # 08007-04-041 : Model Linen BFA Work Plan Prepared for: AZ Development, LLC Andy Zimmerman 111 W. Lewis Street, Greensboro, NC 27401 Email : andyz@azdev.biz Phone : (336) 255-4813 PVRAM 1 a ENVIRONMENTAL & ENGINEERING, P.C. Work Plan Version : Version 2.3 Date Prepared : 10-27-2021 Work Plan Submitted to : BP Project Manager : Ms. Sharon Poissant Eckard, PG NCDEQ— DWM - Brownfields Program 1646 Mail Service Center, Raleigh, NC 27699-1646 Email: Sharon.Eckard@ncdenr.gov Phone : (919) 609-2617 Work Plan Prepared By: Michael G. Jones, PG License #1168 PYRAMID ENVIRONMENTAL & ENGINEERING, P.C. 503 INDUSTRIAL AVE., GREENSBORO, NC 27406 Email: Mike@pyramidenvironmentol.com Phone: (336) 335-3174 NC Geology License C-257 NC Engineering License : C-1251 Model Linen & West Lewis St. NCBP Sites - Brownfields Soil -Gas Work Plan (Version 2.3) Page 1 Pyramid Environmental & Engineering, PC-2021-132 10-27-2021 Table of Contents 1.0 Introduction 1 1.1 NCDEQ Requested Work 3 1.2 Brownfields Receptor Survey 6 1.3 Soil Assessment 6 1.4 Groundwater Assessment 6 1.5 Sub -Slab Vapor Sampling 6 1.6 Data 7 2.0 Scope of Work 8 3.0 Sampling Methodology 9 3.1 SSV Sampling Methodology 10 3.2 Indoor Air Sampling Methodology 11 3.3 Crawlspace Sampling Methodology 12 4.0 Laboratory Analyses 12 5.0 Quality Assurance / Quality Control Procedures 13 6.0 Investigation Derived Waste 14 7.0 Reporting 14 8.0 Work Plan Closing 15 Figure 1 - Topographic Map Figure 2 - Property Location Aerial Map Figure 3 - Site Aerial Showing 2014 Assessment Results Figure 4 - Estimated Groundwater Flow Direction Figure 5 - Aerial Map with Proposed Sample Locations Figure 6 - Locations of SG Samples at 109 — 111 W. Lewis Street Figure 7 - Locations of SSV Samples at 115 — 117 W. Lewis Street Figure 8 - Locations of SG Samples at 117 B-1 W. Lewis Street Figure 9 - Locations of SSV Samples at 120 W. Lewis Street Table 1 through 4 (in Text) Attachment A : NCDEQ Brownfields Letter (03-26-2021) Attachment B : Site History, Phase II ESA, and 2014 Assessment Results Attachment C : Site Photos, Sanborn Map 1950, map of Foundation Types Attachment D : Vapor PinTI Product Brochure, Installation instructions, and leak check procedure Attachment E : TO-15 Method Reporting Limits for Pace Analytical Attachment F : Pace TO-15 Air Sampling Procedures Model Linen & West Lewis St. NCBP Sites - Brownfields Soil -Gas Work Plan (Version 2.3) Page 2 Pyramid Environmental & Engineering, PC-2021-132 10-27-2021 1.0 Introduction On behalf of AZ Development, Pyramid Environmental & Engineering, PC (Pyramid) reviewed the NCDEQ letter date March 26, 2021, requesting additional assessment at the referenced Brownfield site addresses. The NCDEQ letter is presented in Attachment A for your reference. The NC Brownfields Program (NCBP) requested a Work Plan to provide the NCDEQ with details of the proposed sub -slab vapor (SSV) assessment requested by the Department. The site assessment history is summarized in this work plan with applicable sampling details for the site. This SSV Assessment Work Plan is being submitted while efforts are underway to merge the Brownfield agreements for the following two Brownfields sites : • # 17046-13-041 : The West Lewis Street BFA is being written to combine the West Lewis Street site with the Model Linen Brownfields Site. • # 08007-04-041 : The Model Linen BFA was previously recorded, and review of the document showed that changes were necessary to the Brownfields Plat. The combination of the two sites into one Brownfields Agreement (BFA) is proposed. As far as was reported, there has not been involvement of the DSCA program. The SSV Assessment Work Plan will address the NC Brownfields Program concerns about possible vapor intrusion from solvent or volatile organic contamination. The SSV analytical results will provide additional information for evaluation, will fill a "data gap" , and will allow completion of the BFA. The Following table presents the Property Information for the two sites. Table 1— Property Use Summary NCBP Project # Address Parcel # Acreage Former Use REC Current Use 17046-13-041 109-111 W. Lewis 7864-63-1801 0.24 Furniture Store PCE & TCE in GW Pub & Office Spaces (W. Lewis BF) 115-117 W. Lewis 7864-53-9880 0.48 Dry Cleaners PCE & TCE in GW Pub, Brewery, distillery 08007-04-041 120 W. Lewis St. 7864-64-0041 0.50 Former Laundry PCE & TCE in GW Arcade, Pub, Storage (Model Linen) As requested by the NC Brownfield Program (NCBP), this brief summary of the site history was completed as part of the SSV Work Plan. Pyramid met with the building owner at the properties to access each building areas and review what is known about the foundations. The buildings have differing foundation types that will affect the collection of SSV samples. Model Linen & West Lewis St. NCBP Sites - Brownfields Soil -Gas Work Plan (Version 2.3) Page 3 Pyramid Environmental & Engineering, PC-2021-132 10-27-2021 1.1 NCDEQ Requested Work The NC Brownfields Program requested additional sub -slab vapor data for both the Model Linen and West Lewis Street properties based on the detection of Benzene, Naphthalene, PCE, TCE, and 1-Methyl naphthalene in groundwater at 120 Lewis Street (MW-3). There was a detection of Trichloroethylene (TCE) in the groundwater at MW-3 (1.2 µg/L) on the Model Linen site. Based on these VOC detections, the NCDEQ determined that there was a "data gap" for sub -slab vapor data. The historical data from one sub -slab sample collected in 2014 in the southeast area of 109 W. Lewis indicated a low concentration of TCE and other volatile organic compounds (VOCs), including the daughter products of TCE, which were present in the 2014 SSV sample. The VOCs include chlorinated compounds that are considered contaminants of concern (COCs). Brownfields requested additional SSV sampling in each of the buildings to assess vapor intrusion risk. The NCDEQ Brownfields Program letter requesting the work is presented in Attachment A. The detailed site history prepared in 2014 during a Phase II ESA is included in Attachment B. At this time, no new structures or foundation changes are planned. The current property uses include several pubs with food service, a craft brewery, a distillery, offices, storage, and a video game arcade. The property uses will remain consistent with the current use for the foreseeable future, and no new construction or residential uses are planned. Planning for the SSV sampling began with a site visit and interview with the building owner and a few of the current occupants. The buildings have structural walls separating the building areas, and differing foundation types. In preparing the SSV and crawlspace sampling work plan, the foundation type and wall separations were taken into consideration. The owner's information, photographs, and maps were helpful in understanding the foundations, and are included in Attachment C. The following Figures are provided as further explanation of the work. Figure 1 - Topographic Map Figure 2 - Property Location Aerial Map Figure 3 - Site Aerial Showing 2014 Assessment Results Figure 4 - Estimated Groundwater Flow Direction Figure 5 - Aerial Map with Proposed Sample Locations Figure 6 - Locations of SG Samples at 109 —111 W. Lewis Street Figure 7 - Locations of SSV Samples at 115 —117 W. Lewis Street Figure 8 - Locations of SG Samples at 117 B-1 W. Lewis Street Figure 9 - Locations of SSV Samples at 120 W. Lewis Street The following Table 2 describes the sampling strategy for each sample location. Model Linen & West Lewis St. NCBP Sites - Brownfields Soil -Gas Work Plan (Version 2.3) Page 4 Pyramid Environmental & Engineering, PC-2021-132 10-27-2021 Table 2 - Address - Building Size & Foundation Descriptions SCOPE of During review and discussions, the NCDEQ requested more coverage of the buildings for the SSV Study. WORK The NCDEQ general guidance refers to one sample per 1,000 square feet. Pyramid discussed locations with the DEQ and the agreed upon SSV sample locations are presented on Figure S. The 109 W. Lewis pub is 2,697square feet of renovated space, constructed in a foundation wall with post 109 W. and beam construction. The current floor is a thick wooden plank floor which was built using joists, a Lewis plywood deck, and then the 3.5 inch thick wooden plank floor. The wooden floor was constructed over a former concrete floor, and therefore will be considered as crawlspace samples. The DEQ requested ( 2 ) samples which are considered crawlspace samples (CS-1 and CS-2) which are shown on Figure 6. This area is 5,828 square feet of office space, constructed inside a foundation wall with post & beam. The 111 W. current floor is a thick wooden floor which was built using joists, a plywood deck, and then the 3.5 inch Lewis thick wooden plank floor. The wooden floor was constructed over a former concrete floor and therefore will be considered crawlspace samples. For this area, the (4) crawlspace vapor samples will be collected (CS-3, CS-4, CS-5, and CS-6) at the locations shown on Figure 6. 115 W. This area is currently the Fainting Goat Distillery which has a new concrete floor. The distillery is separated Lewis by a concrete block wall from the brewery to the west. The distillery is 3,666 sq. ft., and is the eastern half Distillery of the area the Sanborn Map indicated as "Dry Cleaner". The DEQ requires (2) SSV samples (SSV-7 and SSV-8) as shown on Figure 7. It is possible that the new concrete slab may have been poured over the older slab in this area; a crawlspace is not expected. 117 W. This area is currently the South End Brewery which was also has a new concrete floor. The brewery is the Lewis western % of the building, and is separated from the distillery to the east by a concrete block wall. The Brewery brewery is 3,564 sq. ft. of the building, and is the west half of the area the Sanborn Map indicated as "Dry Cleaner". The DEQ requires (3) SSV samples (SSV-9, SSV-10, & SSV-11) as shown on Figure 7. 117 B-1 The entire pub (3,737 sq. ft.) is constructed over a crawlspace area below the wooden floor. The DEQ Crawlspace requested (2) crawlspace samples (CS-11 and CS-12) as shown on Figure S. The samples will be collected at least 5 feet from the exterior walls and will be compared with the Indoor Air Quality VISLs. 120 W. The Boxcar has an event space, 2 bars, and a game room covering 70 % of the area. The building is slab Lewis Street on grade with plumbing on the east side. The SSV points (SSV-18 through SSV-23) are shown on Figure 9, BOXCAR and cover the Boxcar area of 9,900 square feet with ( 6) SSV samples to evaluate this area. 120 Lewis This area was not open for our inspection, and will be inspected at the start of work. The owner designated Street the area for office use. The area is slab -on grade construction with a NE courtyard. The 4,475 sq. ft. area has (4) SSV samples (SSV-14 through SSV-16) positioned to evaluate the area. The small "Courtyard" Offices area at the NE corner of the property will be investigated with SSV-15 sample under concrete. The SSV locations are shown on Figure 5 and described on Table 3 below. 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O O O O N 'p N p •. •. •. z ° Q cc w•� U Q V U X X U X x Q V Q V z z x O O 0 0 0 x 0 m a u m w u 3 3 3 3 3 342 h m m m m m m a a a a J 3 z J 3 J u 3 3 _Iv rl N -a a r-i rl N N q m 7 V1 Z O r-I N F_ Model Linen & West Lewis St. NCBP Sites - Brownfields Soil -Gas Work Plan (Version 2.3) Page 6 Pyramid Environmental & Engineering, PC-2021-132 10-27-2021 1.2 Brownfields Receptor Survey The site location is in downtown Greensboro at an approximate elevation of 835 feet above mean sea level (msl). The area is near the topographic high along West Lewis Street, and surface water from the site appears to move to the south and southeast toward a nearby surface water stream. The closest surface water stream is located about 1,400 feet south of the site, and flows to the south. Although no receptor survey has been completed for the site, the site is in the center of Greensboro and no water supply wells are expected in this area. A brownfields Receptor Survey will be conducted as part of this scope of work. The City of Greensboro supplies municipal water to the properties within 1,500 feet of the site. There are no known water supply wells located on the Brownfields properties. 1.3 Soil Assessment Petroleum USTs were reportedly removed from south of 111 W. Lewis although no exact location was given. In addition, a petroleum UST was reportedly removed from the southwest corner of 120 leis street. The 2014 soil assessment summarizing the previous investigations is presented as Attachment B, and showed that the results were below IHSB PSRG levels. This Work Plan includes no soil sampling, but rather sampling of SSV to evaluate volatile organic compounds (VOCs) beneath the buildings. 1.4 Groundwater Assessment Summary Previous groundwater assessment was reported and identified benzene, naphthalene, PCE, TCE, and 1-methylnaphthalene above groundwater standards. A typical conceptual site model would include shallow groundwater between 12 to 16 below land surface (BLS), within the surficial aquifer. The saprolite generally persists to a depth or approximately 45-55 feet and is followed by weathered granitic rock. The bedrock in the Greensboro area is generally between 65 and 85 feet below land surface, depending on differential weathering. The dissolved Constituent of Concern (COC) are present in the shallow zone. The groundwater potentiometric surface map is presented as Figure 4, and the Constituents of Concern map is presented as Figure 3. These groundwater detections prompted the NCDEQ to request the SSV sampling work plan. 1.5 Sub -Slab Vapor Sampling The former Model Linen operated on both the north and south sides of Lewis Street at 120 Lewis Street (north side) and 117 Lewis Street (south side). The NC Brownfields Program requested SSV data for both the Model Linen and West Lewis Street properties. The Program requirements are based on the detection of TCE in the groundwater at the Model Linen Site and the lack of Model Linen & West Lewis St. NCBP Sites - Brownfields Soil -Gas Work Plan (Version 2.3) Page 7 Pyramid Environmental & Engineering, PC-2021-132 10-27-2021 sufficient sub -slab vapor assessment data. The historical data from one sub -slab sample collected in 2014 in the southeast area of 109 W. Lewis Street indicated a low concentration of TCE and other VOCs, including the daughter products of TCE present in that sample. The NC Brownfields Program requested additional SSV sampling in each of the buildings to assess vapor intrusion risk. Future development includes no new builds on the properties, no planned residential use, nor removal of buildings or foundations; although residential use was requested as a potential future use in the Brownfields Agreement. Each building is connected to public utilities. 1.6 Data Gaps The NCDEQ Brownfields Program has identified the lack of SSV data as a data gap and requires additional SSV assessment data to be collected for the buildings at the site. The following Work Plan summarizes the methods, procedures, and quality assurance which will be used in the upcoming SSV assessment. After discussion with the NCDEQ, Pyramid reviewed the preliminary NCDEQ Brownfields Program Guidance for Vapor Intrusion Assessment Work Plan and Report Checklist (July 2021) in preparing this document. Although not all of the checklist items apply to this site, the guidance was adhered to where appropriate. • The property use has been established and is reported in Table 1. • Redevelopment plans will not include new structures on the properties • No foundation changes are proposed, and each building is connected to public utilities • There are no basements in the buildings • There are no elevators or stairwells in the buildings • Parking is outside on paved surfaces and along the street • Building square footage is report on Table 2 and is not changing • Figure 1 - Topographic Map • Figure 2 - Property Aerial Location Map showing all parcels • Figure 3 - Site Aerial Map showing 2014 assessment results • Figure 4 - Estimated Groundwater Flow Direction • Figure 5 - Aerial Map with Proposed Sample Locations • Figure 6 - Locations of SG Samples at 109 —111 W. Lewis Street • Figure 7 - Locations of SSV Samples at 115 —117 W. Lewis Street • Figure 8 - Locations of SG Samples at 117 B-1 W. Lewis Street • Figure 9 - Locations of SSV Samples at 120 W. Lewis Street The subsurface and crawlspace sampling locations and rationale are described in Table 2 and in Table 3 of this work plan. Model Linen & West Lewis St. NCBP Sites - Brownfields Soil -Gas Work Plan (Version 2.3) Page 8 Pyramid Environmental & Engineering, PC-2021-132 10-27-2021 2.0 SCOPE of WORK The work required by the Brownfields Program is to provide SSV sample collection and analysis from the structures on the sites. The locations proposed are shown on Figure 5 and Table 3 indicates the planned sampling technique. The primary tool in the sampling is the Vapor Pin TM which is a stainless steel device which allows penetration of the concrete slab/overlying floor, and seals to the penetration allowing a vapor sample to be collected from the air -space below the slab. The air space below the concrete or wooden flooring systems can be accessed in this way, and the sample locations can be left in place if repeated sampling is desired. Additional vapor sampling procedures are listed in the following sections for each building location and the QA/QC details are also summarized in this SSV Work Plan. No sealants or glues will be applied to the SSV installations or leak check. The materials used will be consistent with the planned VI sampling and observations of the site conditions at each SSV Installation will be recorded during installation. The proposed SSV sample locations are shown on Figure 5. The SSV sampling will be completed using Vapor PinTm devices in each sample location. The Vapor PinTm description, installation procedures, and leak check for the device are summarized in Attachment D. The SSV samples require penetration through the concrete or wood flooring to access the vapor space below. Table 2 describes the building location, address, foundation type, and Table 3 describes the sample numbers and strategy for each sample location. These SG / SSV / Crawlspace sample locations are shown on the site map presented as Figure S. These samples are to determine whether there are vapor intrusion concerns at the Brownfields Properties. SSV sampling will be arranged with the property owner and each tenant after NCDEQ approval of the work plan. The business operations will make it necessary to schedule the work so that it does not interfere with normal business. The installation work for the SSV VaporPinsTM is expected to take two field days, and the installations will be developed, sealed, and covered with stainless steel covers. The sample collection will require 25 cylinders from the laboratory which may take time to acquire. The field collection of air samples will document the conditions at each sample location, and a duplicate sample will be collected for each field day. The work will be scheduled to be completed in two field days and Duplicate samples are proposed at location SSV-10 (SSV-10 Dup) and SSV-23 (SSV-23 Dup). These are the most likely areas for detections of chlorinated solvents at the two brownfields sites. Model Linen & West Lewis St. NCBP Sites - Brownfields Soil -Gas Work Plan (Version 2.3) Page 9 Pyramid Environmental & Engineering, PC-2021-132 10-27-2021 3.0 SAMPLING METHODOLOGY 3.1 SSV Sampling Methodology The SSV sampling will be completed using separate Vapor PinTm devices in each area of the site. The timing of the SSV Sampling will be scheduled within 2 weeks of SSV Work Plan Approval. The Vapor PinTm description, general installation procedures, and leak check for the device use are presented in Attachment D. The proposed assessment activities will be performed in general accordance with DEQ's Inactive Hazardous Sites Branch (IHSB) Guidelines for Assessment and Cleanup of Contaminated Sites (Guidelines) dated January 2020, the DEQ DWM Vapor Intrusion Guidance (VI Guidance) dated March 2018, and most recent versions of the U.S. Environmental Protection Agency (EPA) Region IV Science and Ecosystem Support Division (SESD) Field Branches Quality System and Technical Procedures guidance. The Vapor Intrusion Assessment Checklist will be used in preparation of the final report and is presented in Attachment E. The SSV samples require penetration through the concrete or wood flooring to access the vapor space below. Preparation for the VaporPinT"' installations includes: • Procurement of the Vapor Pins & Installation Kit • Confirm access to the sample areas with building owner and occupants • Schedule Vapor PinT"' Installation and purging • For thick wooden floor install, VaporPinTm agreed the device use was appropriate • Receive Laboratory canisters, check condition, and Teflon tubing for sampling Pyramid plans to complete the coring and installation of the seven Vapor PinT"' installations prior to the final arrangements for SSV sample collection. The procedures for installation are outlined in detail in Attachment D. Pyramid consulted VaporPinT"° about the use of the device, provided photos of the flooring , and received and Email confirming the device is appropriate for this use. Once the SSV sample points are installed, Pyramid will purge the entire sample train (Vapor Pin and tubing) by extracting 5 volumes from the vapor point using the syringe and three-way valve. After stabilization, the purge/leak check will be completed prior to sampling. The installation will be secured with a cap and stainless steel threaded lid fastened to the top and allowed to rest for 20 minutes before sampling. No sealants will be used in the installations. Preparations for the soil -gas sampling and analyses included the following elements: • Arrange for volatile organic TO-15 BATCH -certified 6-liter summa canisters • Helium gas will be used (fully Hooded) for Leak checking of all connections • Slab / floor thickness will be recorded for each location Model Linen & West Lewis St. NCBP Sites - Brownfields Soil -Gas Work Plan (Version 2.3) Page 10 Pyramid Environmental & Engineering, PC-2021-132 10-27-2021 • The Buildings have HVAC systems that will be operated normally during sampling. • Samples will be completed when the buildings are unoccupied or lightly occupied. • Connecting laboratory prepared cylinders & 200 ml/min flow control device • Soil -gas sample collection in laboratory prepared vacuum cylinders • Duplicate soil -gas samples will be collected concurrently with primary samples • Packaging and FeclEx shipment of air samples in lab packaging to Pace • Evaluation of laboratory results relative to commercial and residential VISLs • Reporting of analytical data to the NCDEQ Prior to sample collection, a leak test will be performed on each SSV/SG point by placing a shroud around the point and sampling train including the summa cannister, saturating the air inside the shroud with helium gas, then purging approximately three volumes from the sampling point and tubing using a syringe and three-way valve. The 6-liter summa canister will be connected to in - line flow controllers with the laboratory calibrated vacuum gauge. The flow controller will be connected to the sample tubing at the soil vapor monitoring point using a brass nut and ferrule to form an air -tight seal. Vapor from the monitoring point sample tubing will be purged and sampled outside the shroud into a Tedlar° Bag . A helium gas detector will be used to measure helium concentrations in the shroud and bag. The leak test will be considered successful if the helium concentration measured in the soil gas purged from the sampling point is less than 10% of the concentration measured in the shroud. If the leak test is unsuccessful, measure will be taken to identify and address the source of the leak and additional leak testing will be performed. In total, a minimum of 5 volumes will be purged from the point prior to and during the leak test utilizing a syringe and 3-way valve. After a successful field leak check, the vapor samples will be collected in the laboratory supplied Summa Canisters. The Summa canisters will be batch certified for quality assurance. The vacuum will be checked for appropriate negative pressure. If the initial vacuum prior to sampling is in excess of 10 % lower than the vacuum recorded at sample receiving, the canister will not be used, and a replacement will be obtained. For the 6-liter canisters, the flow regulatory will be set at 200 milliliters per minute (ml/min). For this site, the Duplicate (SSV-2 Dup) will be collected concurrently with the primary sample using a "Tee" connection within the helium hooded area. The intake valve on each canister will be fully opened to begin sample collection. Vacuum readings will be recorded before, during, and at the end of the sample collection. The sample collection start and ending times will also be Model Linen & West Lewis St. NCBP Sites - Brownfields Soil -Gas Work Plan (Version 2.3) Page 11 Pyramid Environmental & Engineering, PC-2021-132 10-27-2021 recorded. A vacuum of between -5 and -8 inches of vacuum will be maintained at the end of the sample collection. After the sample is collected, the intake valve will be closed, and the tubing disconnected from the canister. The starting and ending vacuum will be recorded on the Chain -of -Custody (COC) form and submitted to the laboratory with the canisters. The canisters will be shipped in the lab provided shipping containers under standards COC protocols to Pace Analytical Services. The sample location will be secured and maintained in working order until the analytical results are received, and a decision is made about additional sampling or indoor air analyses. After evaluation, a decision will be made to remove or leave the vapor sampling point in the future. 3.2 Indoor Air Sampling Methodology The initial sampling plans do not include any indoor air sampling locations. The crawl space samples will be considered indoor air samples for comparison with the appropriate VISLs. It is possible that indoor air samples will be necessary in the future. This work plan lists the additional details that may be needed in the future should indoor air sample be needed. • An inventory of chemicals within each building will be conducted if indoor air quality samples are to be collected. The NCDEQ Indoor Air Building Survey and Sampling Form will be completed should IAQ samples be collected. • If compounds that are perceived to be potential interference compounds are found in the building survey, these compounds will be removed at least 48-72 hours before the sampling is completed. • The schedule for IAQ sampling will be planned to minimize potential interference from construction or renovations which may bring in new materials. • The HVAC system will be operated normally before and during the sampling. • Samples will be collected with individually certified 6-liter Summa Cannisters equipped with 200-ml/minute flow controller devices. • The air intake will be elevated on a stand and the intake will be at breathing height , about 5 feet above the floor. • All IAQ Samples will be collected on the ground floor in the work or public areas of the buildings. • The work will be scheduled with the building owners to limit the access of other people to the work areas while sampling. Since no IAQ samples are indicated, these sampling methods are proposed for future use. Model Linen & West Lewis St. NCBP Sites - Brownfields Soil -Gas Work Plan (Version 2.3) Page 12 Pyramid Environmental & Engineering, PC-2021-132 10-27-2021 3.3 Crawlspace Sampling Methodology This sampling work plan includes crawl space sample locations designated CS-12 and CS-13. The Samples CS-1 through CS-6 will be collected below a substantial wooden floor, and are considered crawl space samples. Sampling procedures will include : • Looking for a moisture barrier. None was observed during the site visit • The ceiling of the crawl space is wooden joists and a wooden floor below a Bar • There appeared to be 2 vents and a small access door on the western wall • Crawl space height varying from 30 inches to less than 10 inches for CS-12 and CS-13. • There is a perimeter concrete wall and foundation piers in the crawl space area • The floor is dirt and gravel • For CS-1 through CS-6, the thick wooden floor will be penetrated with VaporPins' The timing of the SSV and crawl space sampling will be scheduled to begin within 2 weeks of SSV Work Plan Approval. 4.0 Laboratory Analyses The analytical laboratory selected for the project is Pace Analytical Services. The air sample analytical method selected is TO-15 for Volatile Organic Compounds (VOCs) with the full list of compounds (excluding Acrolein) and including naphthalene reported for the initial analyses. Pyramid reviewed the method Reporting Limits (RLs) and method detection limits (MDLs) for TO- 15 for the target paramete rs/COCs. The RLS are within the range required to determine the VISLs for each of the target parameters. The detection and reporting limits were well below the regulatory residential VISL levels. The analytical method TO-15 RLs for the method are presented in Attachment F. Pace Analytical Services will prepare the sample containers and certify the evacuated cylinders with flow control devices installed limiting flow to 200 ml/min. The cylinders will be inspected before use, and if the vacuum prior to sampling is 10% lower than the vacuum documented by the laboratory upon shipment, then the cannister is considered compromised and will not be used. The sample collection methods used in the field will comply with the instructions given by the analytical laboratory. The personnel performing the sampling and collecting data at the site are qualified by education, training, and experience. The sample start and end time will be recorded on the Chain -of -Custody for the site. The starting and ending vacuum in each canister will be recorded on the chain -of -custody and submitted to the laboratory along with the samples. Model Linen & West Lewis St. NCBP Sites - Brownfields Soil -Gas Work Plan (Version 2.3) Page 13 Pyramid Environmental & Engineering, PC-2021-132 10-27-2021 5.0 Quality Assurance / Quality Control Procedures Pyramid plans to collect 23 primary vapor samples and two duplicate SSV/crawl space samples. The primary and duplicate samples (SSV-10 & SSV-10 Dup) and (SSV-23 and SSV-23 Dup) will be collected using a brass "Tee" connection between the two samples. These two samples will be collected concurrently, and the analyses used for comparative purposes. Pyramid will review the Laboratory Level II report from Pace Analytical for quality assurance. The laboratory QA/QC procedures will be used to ensure appropriate sample handling and analysis and help with the review of the analytical data and data validation. QA/QC Procedures will be conducted in accordance with the method protocols and will include regular equipment maintenance, equipment calibrations, and adherence to specific sample custody and data management procedures. Samples will be analyzed in conjunction with appropriate blanks, lab duplicates, continued calibration standards, surrogate standards, and matrix spike standards in accordance with approved methodologies to monitor both instrument and analyst performance. Laboratory reporting limits for each analyte will be at or below appropriate screening criteria, where possible. The Summa canisters be packaged and shipped to the laboratory under standard chain of custody protocols for analysis of VOCs by EPA Method TO-15. The sample cylinders will be checked when received by Pace Analytical Services and inspected. The cylinders vacuum readings will be recorded by Pace and compared to the vacuum remaining at the end of the test. The cylinders will be analyzed using TO-15 Method for VOCs and naphthalene, and the results will be checked for accuracy. The NC Brownfields Program requests that the laboratory review the data and report values that are above the Method Detection Limits (MDLs) and below the Reporting Limits (RLs) for TO-15 as "J" flag for estimated concentrations. The TO-15 data will be reviewed for comparative results between the primary and duplicate samples to determine if the comparative results are acceptable. The laboratory report of the SSV air samples will be compared with the IHSB VISL standards, and the results presented in the report with QA/QC results, and chain -of -custody documentation. Laboratory QA data consistent with Level II documentation will be requested for this project. Pace Analytical Services was selected for the Lewis Street/Model Linen Site and the laboratory contact is Ryan Brumfield (704) 734-4234. The SSV analytical data will be reviewed and compared to the Residential and Non -Residential Vapor Intrusion Screening Levels (VISLs) for Sub -Slab and Model Linen & West Lewis St. NCBP Sites - Brownfields Soil -Gas Work Plan (Version 2.3) Page 14 Pyramid Environmental & Engineering, PC-2021-132 10-27-2021 Exterior Soil Gas Vapor Screening Levels (SGSLs). A final report will be prepared with the data and submitted to the NC Brownfields Program for review within 30 days of data receipt from the laboratory. 6.0 Investigation Derived Waste Based on the prior data, investigation derived waste (IDW) generated during the assessment will be minimal and should not encounter contaminated materials. If these activities encounter any contaminated materials, they should be minimal and would be spread near the point of generation in a thin layer. However, if significant impacts are suspected, the materials will be containerized in 55-gallon drum and staged on -site pending analytical results of a composite IDW sample. Based on laboratory analytical results of IDW samples, the drums will be transported off - Site to a permitted facility for disposal, if needed. 7.0 Reporting Following completion of the assessment activities and receipt of the analytical data, Pyramid will prepare a letter report documenting the soil -gas data, and including a description of the sampling activities, Figures showing sample location, a soil boring log, laboratory data, a discussion of the data in comparison to regulatory screening levels, and conclusions and recommendations based on the site history and current SG data. The report will include applicable tables, figures, and appendices. The leak check data will be included in the Report as a table to confirm the leak check data : Sample Time Helium - Shroud (ppm) Helium — Tedlar (ppm) % Helium in Tedlar < 10 % helium ? Initial 5,000 ppm ?? % Yes / No Middle 5,000 ppm ?? % Yes / No Ending 5,000 ppm ?? % Yes / No ppm = parts per million Analytical data will be compared against the applicable NCDEQ screening levels. Figures will include a North arrow, graphic scale, map legend, and other reference information. The report will include the Corporate license information and the individual license information, and appropriate professional seal. The final report will be submitted to the NC Brownfields Project Manager for review and approval, and for use in evaluating vapor intrusion risk and developing a revised Brownfields Agreement for both properties. Model Linen & West Lewis St. NCBP Sites - Brownfields Soil -Gas Work Plan (Version 2.3) Page 15 Pyramid Environmental & Engineering, PC-2021-132 10-27-2021 8.0 Work Plan Closing The schedule for the work is outlined in the following table based on Work Plan Approval. Table 4 — Proposed Schedule Date Activity Description DEQ Work Plan Approval Schedule work Arrange work with property owner, tenants, and legal counsel Week 2 Install Pins Procure & Install VaporPins'", schedule sampling, order cylinders Weeks 3 Collect Samples Collect primary & duplicate SG/SSV samples & ship to Laboratory Weeks 4 & 5 Reporting Prepare sampling report and add SG/SSV data when received Week 6 Report to DEQ After Review the report will be sent to NCDEQ / Brownfields The proposed schedule will be altered if there are delays in receiving the sampling supplies from Vapor Pin, or if the Laboratory has delays with TO-15 sample cylinders availability. These are outside our control and will be mitigated by requesting the materials as soon as the work is approved. Please review this work plan and send any comments, which will be addressed quickly so that we can move forward. Please review this work plan and provide your comments or approval to Pyramid at email : mike@ pyramidenvironmentaLcom. If you have any questions or if you need additional information, please call me (336) 335-3174, ext. 124. Model Linen & West Lewis St. NCBP Sites - Brownfields Soil -Gas Work Plan (Version 2.3) Page 16 Pyramid Environmental & Engineering, PC-2021-132 10-27-2021 Attachment F Project Name: West Lewis Street Brownfields Site Project Number : 2021-336 PYRAMID DWONMEWALA ENGINEERING, P.C. City : Greensboro NC Project Address : 109, 111, 113, 115, 117, & 120 W. Lewis St. SSV j SG Fieldwork Record Weather Expected: Clear and cold am SAMPLE IVAME CS - Category Descriptions Descriptions Address 71 I i I W. Lewis 5t. arth / South Center '/ SG Location E 55V CS Bus. Operations? ��i 1 I G 4—�Q� Floor Type Concrete 1 Waode Crawlspace or 55V 000 r r�� I�I� Vapor Pin � 55V Install date :tfJ� � Floor Thickness ? 4" Installation � l ET__�Locatian on Site Map No Void Space Under Floor HVAC in this Space ? No Unconditioned Space ? + ' Air Sampling �'Za z ED Cylinder Number : 1 Batch Cer / Individ. Cert. ��Flow Controller - 200 ml/min # Helium - Fully Hooded Sample Train Purge ( 5 vols) 20 x 60 ML = 1,200 ML J EI]ZHQod Helium = > 5,000 ppm 19--tedlar Bag Helium = ppm @J Radings of Vacuum (Inch es of Hg } over Sample COLLECTION Time and Vacuum Starting Time: 7 : Ca Vacuum / Pre -Sapling : m_� � 7 5 Mins. / Hg" 25 Mins. Hg" 45 Mins. Hg" 1Q Mins. Hg" 3Q Mins. Hg" 50 Mins. Hg" O� 15 Mins. _Hg Mins. Hg" 55 Mins. Hg" r 20 Mlns. + , S' Hg" 41) Mins. Hg" 60 Mins. Hg" ErSample End Time ff.,0 Sample Cannister Ending Vacuum Hg" Pickup 8y PACE Courier Sample Hg" Vacuum on CaC r Packed in Pace Boxes � —Bete Shipping 1�' �7 Ea Cylinder inspecte [ OK DamagedED FeclEx Ship: Tracking # Q153 2 T Pyramid Environmental & Engineering, P.0 503 Industrial Avenue, Greensboro, NC 27405 Phone - (336) 335-3I74 Ref: 1048368?MR2 Date: 0?DGc21 SHIPPING: 0.00 Dap: AIR Wgi: 40.00 LBS SPECIAL: 0.00 HANDLING: 0.00 ❑V, 0.00 TOTAL 0.00 Svcs: " 2DAY" Maier 9763 8447 6127 TACK; 9753 8447 8127 l Project Name: West Lewis Street Brownfields Site - Project Number.- 2021-336 PYRAMID ENYR"ENTALB ENGNEEFM, P.C- City : Greensboro, NC Project Address : 109 11I 113 115 117 & 120 W. Lewis St. S5V / 5G Fieldwork Record Weather Expected: Clear and cold am SAMPLE NAME CS�Z Category Descriptions Descriptions Address W . Lewis St. North / South / Center SG Location S5V / CS I Bus. Operations? V -'f r4 C �' Floor Type Concrete Wooden ra or SSV aw o 4 Vapor Pin SSV Install Date: Z L 141 2 2 ( �r Floor Thickness? ei'z Installation I� p El -'Location on Site Map ? Ye No Er Void Space Under Floor : Jfl�l.&W f Ql1,- EaHVAC in this Space ? Y s No ED" Unconditioned Space ? NA Air Sampling ❑ate : 2 r' C) �ylinder Number : �— Q 2- l Y Batch Cert / Individ. Cert. Flow Controller - 200 ml/min # V" { Helium - Fully Hooded EY Sample Train Purge { 5 cols) 20 x 60 ML = 1,200 ML "Y HeliumPppmram EYHood �y�., Tedlar Bag Helium = ( '' ED Readings of Vacuum ( inches of Hg ) over Sample COLLECTION Time and Vacuum v�Wfti Starting Time : 7 _1_w Cannister Vacuum / Pre-Samplingaaf : G 5 Mins. Hg" 25 Mins. 2a S Hg" 45 Mins. Hgi " Wf10 e Mins. )-'5 Hg"30 Mins. Hg" 50 Mins. Hg"1 At15 Mins. f� _ Hg" 35 Mins. Hg" 55 Mins. Hg" 20 Mins, �f Hg" 40 Mins. Hg" 60 Mins. Hg" FSample End Time � MIMs I +' I Sample Cannister Ending Vacuum �Hg" r IaL,cG Pickup 8y PACE Courier Sample d Hg" Vacuum on CDC Packed in Pace Boxes Shipping V. D Cylinder inspected OK0 2aged F-1 Fed Ex Ship : Tracking # 44-7 �3 [ Z-i ►J s Pyramid Environmental & Engineering, P.0 ' 503 industrial Avenue, Greensboro, NC 27406 Phone - (336) 335-3I74 ` V t, oi Lrq GL,i'Q._ aA[V ► 4l E'�•i t r ► (010 "" ' mvv- _ , V _ Project Name: West Lewis Street Brownfields Site Project Number : 2021-336 PYRAMID EXOGNMWAL1kENUNEMWP.C. City: Greensboro NC Project Address : 109, 111, 111115, 117, & 120 W. Lewis 5t. SSV / SG Fieldwork Record Weather Expected: Clear and cold am _ SAMPLE r NAME 1 3 Category Descriptions Descriptions Address E3/- i f W. Lewis St. North South Center 5G Location SSV_/ CS E:Bus. Operations? - Floor Type Concrete ooden �f rawlspac or SSV Vapor Pin m/SSV Install Hate : r I J _d. I Floor Thickness ? - ✓ (��iC 'L e 2 " Installation � �Lvcation an Site Map ? � No Void Space Linder Floor VAC in this Space ? 0e, No Lincvnditioned Space ? fVA Air Sampling Date : i AI( Cylinder CNu:.::�Batch Ce / Individ. Cert. Q Flow Con min # Helium - Fully Hooy �� Sample Train Purge ( 5 vols) 20 x 60 ML = 1,200 ML -i6 Hood Helium = 7-5bdCPppm '] Tedlar bag Helium = �. ppm ED— Readings of vacuum ( inches of Hg) over Sample COLLECTION Time and Vacuum Starting Time: 1 Ll Cannister Vacuum / Pre -Sampling : d � 5 Mins. � Hg" 25 Mins. Hg" 45 Mins. Hg" 10 Mins. 3 Hg" 30 Mins. Hg" 50 Mins. Hg" 15 Mins. �} t' Hg" 35 Mins. Hg" 55 Mins- Hg" 20 Mins. I Hg" 40 Mins. Hg" 60 Mins. Hg" r/ ED Sample End Time � I I Sample Cannister Ending Vacuum ` ? Hg" !! 0,.PickupBy PACE Courier Sample Hg" Vacuum on COC Packed in Pace Boxes ate Shipping —7 ICylinder inspected OK j Damaged FedEx Ship: Tracking # i Pyramid Environmental & Engineering, P.C. 503 Industrial Avenue, Greensboro, NC 27446 Phone - (336) 33S-3174 Project Name: West Lewis Street Brownfields Site PYRAMID Project Number: 2021-336 QlV"MW&AUAGNEERWc.P.C. City: Greensboro, NC Project Address : 109,111,_ 113, 115, 117, & 120 W. Lewis St. SSV / SG Fieldwork Record Weather Expected. Clear and cold am SAMPLE c NAME Category Descriptions Descriptions Address { W. Lewis St. EE-_ North / South Center 5G Location SSV _ � CS Bus. Operations? O Floor Type Concrete Wood �Crawlpc�,,r 55V Race 1� rf Vapor Pin 55V Instal! Date: �1� �' Floor Thickness ?�/ Installation Location on on Site Map ? / _Y_ No Void Space Under Floor HVAC in this Space ? Yew No nconditioned Space ? /VA Air Sampling ED`I]ate : L Z lI G/Zf1 u Cylinder Number: 3, Batch Cer Individ. Cert. [�FIow Controller - 200 mllimin # 00 Helium - Fully Hooded �_ Sample Train Purge {5 vo15) 20 x 60 ML = 1,200 Ml` Hood Helium = .� � � Tedlar Bag Helium = ppm ���$�pm 1L) Readings of Vacuum { inches of Hg i over Sample COLLECTION Time and Vacuum - Starting Time : 77- Q 3, [r Cannister Vacuum / Pre -Sampling l� 5 Mins. Hg" -2146 Mins. 10 Hg" 45 Mins. Hg" fi 10 Mins. 21-� Hg" 30 Mins. Hg" 50 Mins. Hg" t y 15 Mins. 1� Hg" 35 Mins. Hg" 55 Mins. Hg" ll__k 20 Mins. T Hg" Mins. Hg" 60 Mins. Hg" j ��40 Sample End Time 7 d � I ''1-Sample Cannister Ending Vacuum Hg" it Pickup By PACE Courier Packed in Pace Boxes --Date _ Sample Hg" Vacuum on CDC Er Shipping Cylinder inspected ki . Damaged FedEx Ship : Tracking # Pyramid Environmental & Engineering, P.C. 503 Industrial Avenue, Greensboro, NC 2740E Phone - (336) 335.3174 Project Name: West Lewis Street Brownfields Site PYRAMID Project Number : 2021-336 ENVRMMrrlaa13MIM ,P.c. City. Greensboro. NC Project Address : 109, 111, 113, 115, 117, & 120 W. Lewis St. SSV / SG Fieldwork Record Weather Expected. Clear and cold am SAMPLE �/f NAME 7,5 ' Category Descriptions Descriptions Address W. Lewis 5t. North / 5out / Center SG Location 55V V CS r Bus. ? �� 4 1 Operations. Floor Type 12� Concrete Erawlspac or 55V Vapor Pin 55V Install Date: Floor Thickness ? J G`� G Installation cation on Site Map ? Y8) N0 Void Space Under Floor : I �HVAC in this Space ? es No Unconditioned Space ? Air Sampling Date : l /L! Cylinder Number: ?J ✓ tch Ce / Individ. Cert. Flow Controller - 200 ml/min # r Helium - Fully Hooded ample Train Purge (5 vols) 20 x 60' ML = 1,200 ML Er Hood Helium = aS,69�pp vvlq El Tedlar Bag Helium = 2�ppm Lc3 `5-B0 Readings of Vacuum ( inches of Hg ) over Sample COLLECTION Time and Vacuum Starting Time :: *` � Cannister Vacuum / Pre -Sampling : q J 5 Mins, . Hg" rIS Mins. Oif Hg" 45 Mins. Hg" rJ 10 Mins. y . Hg" v? f 3ff Mins. �� Hg" 50 Mins. Hg" 15 Mins. ` . d Hg" 35 Mins. Hg" 55 Mins. Hg" 20 Mins. L r Hg" 40 Mins. Hg" 60 Mins. Hg" Sample End Time 7 . 0 0 5ample Cannister Ending Vacuum Hg" � Pickup By PACE Courier Sample [a"Hg" Vacuum on COC Packed in Pace Boxes _ Shipping Cylinder inspected OK Damaged F FedEx Ship : Tracking # Pyramid Environmental & Engineering, P.C. 503 industrial Avenue, Greensbaro, NC 27406 Phone - (336) 335-3174 Ref= 1048369rMR2 Date: 071)ec21 SHIPPING' 0.00 Dep= AIR Wgt: 40.00 LBS SPECIAL: 0.00 HANDLING: 0.00 DV: 0.00 TOTAL 0.00 Sion " 20AY" MvM819763 8447 e1R7 TACK:97636447 8138 Project Name: West Lewis street Brownfields Site PYRAMID ENVIRONMENTAL d ENINNEERM. P.G. Weather Expected: Clear and cold am Project Number 2021-336 City: Greensboro NC Project Address : 109, 111, 113, 115 117, & 120 W. Lewis 5t. SSV / SG Fieldwork Record SAMPLE r NAME Category Descriptions Descriptions Address lit W. Lewis St. Er North South / Center 5G location SSV _ CS Bus. Operations? 0 i P c r floor Type Concrete Wooden Crawlspace or 5SV L%t��-- V Vapor Pin 55V Install Date: �� I Floor Thickness ? �Z " Installation � �' Loeation on Site Map ? Yes No Void Space Under Floor: El VAC in this Space ? GNo unconditioned Space ? ■ " r 1 Air Sampling EY pate : _ 1 ZI (5I z, Z ED' Cylinder Number t Batch Ce / Individ. Cert. 12- Flow Controller - 200 ml/min # rN7 Helium - Fully Hooded 51mple Train Purge { 5 vols] 20 x 60 ML= 1,200 MLL_-- - Hood Helium Tedlar Bag Helium = ppm vJ0 v ElfReadings of Vacuum { inches of Hg j over Sample COLLECTION Time and Vacuum Starting Time :� ri Cannister Vacuum / Pre -Sampling 5 Mins. Hg" 25 Mins. Hg" 45 Mins. Hg " �}-7- • 5 Hg 1D Mins. " L 30 Mins. ` Hg" 50 Mins. Hg" j--� 15 Mins. 11 .5 Hg" G 35 Mins. Hg" 55 Mins. Hg" 20 Mins. i Hg" 40 Mins, Hg" 60 Mins. Hg" F1Sample End Time �G { 1 V F Sample Cannister Ending Vacuum! Hg" !i Pickup By PACE Courier Sample � Hg" Vacuum on CDC -7 Packed in Pace Boxes �_ ❑❑ Shipping dCylinder inspected OK Damaged 1-1 FedEx Ship :Tracking # Pyramid Environmental & Engineering, P.C. 503 industrial Avenue, Greensboro, NC 77406 Phone - (336) 335-3174 JProject Name: West Lewis Street 6rownfields Site Project Number : 2021-336 PYRAMID MIAONMFWALd e4GINEERNG,P.C. City : Greensboro, NC Project Address: 109 111 113 115 117 & 120 W. Lewis St. SSV / SG Fieldwork Record Weather Expected. Clear and cold am SAMPLE C� NAME J V Category Descriptions Descriptions Address FP -1 ` W. Lewis St. O / South / Center ET FT SG Location 3/�SV " C5 Bus. Operations? Floor Type Ei Concrete / Wooden Crawlspace or SV Vapor PinEZ55V Install Date: : � �J 2021f Floor Thickness ? Installation EDLocation on Site Map ? Nq Void Space Linder Floor : ►�" dP^ ElHVAC in this Space ? Yes Na Unconditioned Space ? G e4 N •Vd- /t p Date [. Cylinder Number: Air SamplingE:f B ch Cert. / Individ. Cert, Flow Controller - 200 ml/min # 1.14� 6/Helium Fully Honied �!. �o Sample - Train Purge { 5 volsj 20 x 60 ML = 1,200 ML Hood Helium = � �Tedlar Bag Helium = _� toPpm �rw1 Readings of Vacuum ( inches of Hg fever Sample COLLECTION Time and Vacuum �: � I► Starting Time: Cannister Vacuum / Pre -Sampling! 5 Mins. He" i. 0 p 25 Mins. Hg" 45 Mins. He" ��6]] d, 4r 1fl Mins. He" 3.(9 S 30 Mins. - ® Hg" 50 Mins. He 2: 0 15 Mins. �.0 Hg" 3r (� 35 Mins. Hg" 55 Mins. Hg" 20 Mins. Hg40 Mins. He" 60 Mins. Hg" r Sample End Time ample Cannister Ending Vacuum Hg" IP Pickup By PACE Courier Sample Hg" Vacuum on COC Packed in Pace Boxes Ef Shipping d 4 Cylinder inspected OK Damaged FedEx Ship : Tracking # 4 �] 3 _ 00-1 (] t3{f Pyramid Environmental & Engineering, P.C. 503 Industrial Avenue, Greensboro, NC 27406 Phone - j336j 335-3174 /� PYRAMID IWAONMENTALt MGME PING. P.C. Weather Expected: Clear and cold am Project Name: West Lewis Street Brownfields Site Project Number : 2021-336 City : Greensboro, NC Project Address : 109, 111, 113 1.15, 117, & 120 W. Lewis 5t, SSV / SG Fieldwork Record SAMPLE l' NAME Category Descriptions Descriptions Address W. Lewis 5t. North / South J Center SG Location d 5sV J C5 d Bus. Operations? "?,s. t Floor Type Ca Crete J Wooden Crawlspace or 55V 06n �+��� Vapor Pin 55V install Date: 2- Floor Thickness ? " Installation - n Location on Site Map ? Yes No Void Space Under Floor: �� R.^X Ea' HVAC in this Space ? Yes N❑ Unconditioned Space? Air Sampling 1z Date: I Z-15 _z + Cylinder Number Batch Cert. / Individ. Cert. Er Flow Controller - 200 ml/min # C'4S+ZaL 1 -( Helium - Fully Hooded Ies P �5ampie Train Purge ( 5 volsj 20 x 60 ML = 1,200 ML I �]� dHood Helium = �i Ib ppm dTecllar Bag Helium = 0-0 ppm Readings of Vacuum I inches of Hg ) over Sample COLLECTION Time and Vacuum Starting Time : � _o-7 _ 1� Can ni5ter Vacuum / Pre -Sampling : �� •� 2, � � 5 Mins. Hg" 2,, 25 Mins. Hg" 45 Mins. Hg" `� 10 Mins. Hg" 30 Mins. Hg" 50 Mins. Hg" 15 Mins. 210 Hg" 35 Mins. Hg" 55 Mins. Hg" 20 Mins. [5 Hg" 40 Mins. Hg" 60 Mins, Hg" Sample End Time _ 5'17 --------- J Sample Cannister Ending Vacuum Hg" k � Sample Hg" Vacuum on COC ,v Packed in Pace Boxes Shipping Ef Cylinder inspected Qi( Damaged FedEx Ship: Tracking Pyramid Environmental & Engineering P.C. S03 Industriul Avenue, Greensboro, NC 27406 Phone - (336; 335.3174 Project Name: West Lewis Street Brownfields Site - Project Number : 2021-336 PYRAMID DWONMENTAL&ENGNtERNG,PC_ City : Greensboro, NC Project Address: 104, 111, 113, 115, 117, & 120 W. Lewis St. SSV / SG Fieldwork Record Weather Expected: Clear and cold am SAMPLE NAME r M L Category Descriptions Descriptions Address ❑� III W. Lewis 5t. ID 6;D/ South / Center SG Location Era/ C5 E ' Bus. Operations? Floor Type M Concrete / Wooden Crawlspace or 55V I( Vapor Pin 55V Install Date: 2a Floor Thickness 7 62 installation Location on Site Map ? Yes No 12 Void Space Under Floor NV HVAC in this Space ? Yes No ED' Unconditioned Space ? JE Jam' S Air 5ampling Date : r r 2 } 23 Cylinder Number: Flow Controller - 200 ml/min #,a`-� ` Batch Cert. / Indivld. Cert. Er Helium - Fully Hooded ETSampleTrain Purge ( 5 volsj 20 x 60 ML = 1,200 MIL Hood Helium = > 5,000 ppm �Tedlar Sag Helium = ppm 7i1Q,O40 ppup — 23 Readings of Vacuum 1 inches of Hg j over Sample COLLECTION Time and Vacuum Starting Time : �L Can nister Vacuum / Pre -Sampling : 3d 5 Mins. aq. 0 He 25 Mins. 2131 He" 45 Mins. �b• � He 10 Mins. 2-7-5 •S Hg" 30 Mins. 2-1 He" 50 Mins. I� Hg" 15 Mins. Hg" 35 Mins. LO Hg" 55 Mins. + He" +]7— 20 Mins. A-• • Hg" Mins. 19 Hg" 60 Mins- He �40 Sample End Time 1 2—' T f V I Sample Cannister Ending Vacuum He H Pickup By PACE Courier Sample EfHe" Vacuum on COC +� Packed in Pace Boxes a Shipping r Cylinder inspected t OiC Damaged FedEx Ship ; Tracking # _ 7 � 4- � I C Pyramid Ernvironmental & Engineering, F.C. 5031ndusrrlolAvenue, Greensboro, NC 27405 Phone - f3361335-3174 1z. -70 70 75: to 7g: ' Project Name: West Lewis Street Brownfields Site PYRAM 1 D Project Number . 2021-336 rxv�oweexrxa�nswEa+w�,r.c City: Greensboro. NC Project Address : 109 111 113 115 117 & 120 W. Lewis St. SSV / SG Fieldwork Record Weather Expected: Clear and cold am SAMPLE NAME 3 Category Descriptions Descriptions Address r7l' << r W. Lewis 5t. ID North / South Center SG Location F9 55V " / C5 �r Bus. Operations? ►30-C vL. Floor Type Concrete Wooden �" Crawlspace or Cr sl Vapor Pin 55V Install Date: 6� ED- Floor Thickness ? " Installation WO Location on Site Map ? Ye No - Void Space Under Floor: EfHVAC in this Space ? Yes No Unconditioned Space? 7 '} Air Sampling dDate : _ CVlinder Number �_ atch C rt. Individ. Cert. Flow Controller - 200 ml/min # /` 0,1 Helium - Fully Hooded Yz 5J Sample Train Purge ( 5 volsj 20 x 60 ML = 1,200 MIL a3'_�'Hoocl Helium = awe ppm Ea"Tedlar Bag Helium = 010 ppm -,ist000 ETReadings of Vacuum R inches of Hg } over Sample COLLECTION Time and Vacuum Starting Time ;_: t'L Cannister Vracuum / Pre -Sampling: 1 _" � 5 Mins. Hg 2,7G5 25 Mins. V •� Hg" 45 Mins. Hg" 10 Mins. . Hg" 30 Mins. �� Hg" 50 Mlns. Hg" 15 Mins. Hg" 35 Mins._ Hg" 55 Mins. Hg" j.LG-.- 20 Mins. + -1 Hg"�� 40 Mins. Hg" 60 Mins. Hg" ETSample End Time Z' 4 1 Wk. I " I` Sample Cannister Ending Vacuum 10 Hg" r � tier Sample �Hg" Vacuum on COC Packed in Pace Boxes Pick Shipping "-] dQCylinder inspected OK } Damaged FedEx Ship : Tracking # _ - -7 s 3 f3 d l� { 0 14 Pyramid Environmental & Engineering P. C 503 Industrial Avenue, Greensboro, NC 274as Phone - (336) 335.32 74 Ref: 10483GB/MR2 Date: 07Dec21 SHIPPING: 0.00 Dep: AIR Wgt; 40.00 LBS SPECIAL! 0.00 HANDLING: 0.00 DV: 0.00 TOTAL' 0.00 Svcs: " 2 DAY " MWe? 9753 8447 8127 IBC II: 9753 8447 8149 Project Name: West Lewis Street Brownfields Site Project Number: 2021-336 PYRAMID EWRONMEWk a ENrANU MQ, rc. City : Greensboro, NC Project Address: 109, 111, 113, 115, 117, &_120 W. Lewis St. SSV / SG Fieldwork Record Weather Expected: Clear and cold am SAMPLE 1AME SS v � ' W 11 Category Descriptions Descriptions Center Address 71 117 W. Lewis St. Er North Yre SG Location SSV CS Bus. Operations?r�r Floor Type Concrete j Wooden Crawlspace or 55 �, � Vapor Pin SSV Install Date: }� r ,�-.l ZflZ y I Floor Thickness 2 � S "� Installation ay Location on Site Map ? No � Void Space Under Floor �� 17 HVAC in this Space ? Yes No Unconditioned Space ? AiT, rJJ On 1 +� 15 az I �`�� 47 W43 Air SamplingDate : Cylinder umber QBatc�Cert.)/ Individ. Cert. �Flow Controller - 200 ml/min # ED Helium - Fully Hooded ESample Train Purge 5 volsj 20 x 50 MIL = 1,200 ML Hood Helium = y$90 ppm IV © Tedlar flag Helium ppm Readings of Vacuum( inches of Hg ) over Sample COLLECTION Time and Vacuum q f� Starting Time Cannister - : �� Vacuum / pre -Sampling !!!5 fk��H Mins. �� g" r;y>�1. 25 Mins. �� Hg" 45 Mins. 1JJ"" �• IO Mins. � k Hg" -mot r+ 30 Mins. 1 I Hg" SO Mins. Hg" i t' 15 Mins. Hg" i 35 Mins. Hg" 53 N Mins. Hg" 20 Minr+ s9 Hg" 40 Mins. `J' He 54 Mins. Hg" 7 q � Sample End Time 1? �� Sample Cannister Ending Vacuum L Hell Sample Hg" Vacuum on COC ` Er Packed in Pace Boxes Shipping Q Cylinder inspected 9Damaged FedEx Ship: Tracking ## G- U -12 0 Pyramid Environmental & Engineering, P. VJ 03 industrial Avenue, Greensboro, NC 27406 Phone - 1336) 335-33 74 V I�- �,73 z— -- Project Name: West Lewis Street Brownfields Site PYRAMID Project Humber : 2021-336 EHy1iioWE7rosa£NGNEEFM.F.c. City: Greensboro, NC Project Address : 109 111 113t 115 117 & 120 W. Lewis St. SSV f SG Fieldwork Record Weather Expected: Clear and cold am SAMPLE �� w NAME J Category Descriptions Descriptions Address [21 i—r W. Lewis St. Ea North / South / Center SG Location [a S5V_ CS Bus. Operations PIA 4, h" Floor Type Concrete / e6d Cr wlspace r SSV , E) rti S c i p v 4" Vapor Pin SSV Install Date Floor Thickness ? " Installation Void Space Under Floor: Location on Site Map ? Yes No Ef lzrHVAC in this Space ? Yes No Unconditioned Space ? Air sampling Date : �` l� �� ! Cylinder Number: } 0 1 Batch Cert. j Individ. Cert. Flow Controller - 200 milmin # Helium - Fully Hooded Nik PaSample Train Purge ( 5 vols) 20 x 60 ML = 1,200 MLd Hood Helium = > 5,000 ppm N r 15I Tedlar Bag Helium = N A— ppm Readings of Vacuum ( inches of Hg J over Sample COLLECTION Time and Vacuum J Starting Time : c J pr., Cannister Vacuum / Pre -Sampling 5 Mins. �1Y Hg'' 25 Mins. 4 + Hg" 45 Mins. Hg" 10 Mins. {zHg" 30 Mins. Hg" 50 Mins. Hg" 15 Mins. U • Hg" 35 Mins, Hg" 55 Mins. HE" 20 Mins. Hg" 40 Mins. Hg" 60 Mins. Hg" sample End TimeZ4 Sample Cannister Ending Vacuum Er Hg" —I c� 1 Packed in Pace Boxes Sample Hg" Vacuum on COC r l Er Shipping Ef Cylinder inspected [ OK Damaged 121 FedEx Ship: Tracking Pyramid En viranmen tal & Engineering, P.C. 503Industrial Avenue, Greensboro, NC 27406 Ref: 1048368/MR2 Dataz WDaCRI Dep: AIR Wgt: 40.00 LOS Dv: Svcs: *• 21 0 — Matey 9753 0447 8127 1RC X: 9763 8447 8150 Phone - (336) 335-3174 SHIPPING: 0.00 SPECIAL: 0.00 HANDLING- 0.00 0,00 TOTAL: 0.00 a PYRAMID EWROWENTAi&ENGINEMN. P.G. Weather Expected. Clear and cold am Project Name. West Lewis Street Brownfields Site Project Number : 2021-336 City : Greensboro, NC _ Project Address : 104 111 113 115 117 & 120 W. Lewis St. SSV / SG Fieldwork Record SAMPLE NAME L Category Descriptions Descriptions Address W. Lewis 5t. 21 North /P",Center 5G Location Ea 5sV _ / 5 �Bus. Operations Floor Type Concrete / oaden awlspac or SSV Vapor Pin SSV Install Date: �� JaFloor Thickness ? )V/ " Installation ET"l-,cation on Site Map ? qe� No Void Space Under Floorevi HVAC in this Space ? Yes aUnconditioned Space ? o I �C �.J o v ,- Air Sampling Cylinder Number: Date: _J_ - d I Er Batch Cert. / Individ. Cert. Flow Controller - 200 ml/min # Helium - Fully Hooded Sample Train Purge [ 5 vols) 20 x 60 MIL = 1,200 ML/i A — Hood Helium = > 5,000 ppm NA Tedlar Bag Helium = ppm ❑] Readings of Vacuum [ inches of Hg j over Sample COLLECTION Time and Vacuum Starting Time : : bA Cannister Vacuum / Pre -Sampling : (� 5 Mins. Hg" 6, „� (5 25 Mins. Hg" 45 Mies, Hg" 0 1, 10 Mins Hg" -1, 30 Mins. ) (3 HgQV� 50 +s. Hg' 15 Mins. Hg"35 Mins. Hg" 55 Mins. Hg" ]r 20 Mins. Hg" 40 M!ns. Hg" 60 Mins. Hg" Sample End Time sample Cannister Ending Vacuum •' �7m;'s Sample 1 G varier Hg" Vacuum on COC Packed in Pace Boxes Shipping ff Cylinder inspected ❑K J Damaged � FedEx Ship : Tracking # fe i'7�3 e A I Pyramid Environmento! & Engineering, P.C. 503 Indus tried Avenue, Greensboro, NC 27406 Phone- (336) 335-3174 Enviro-Equipment Inc. 11180 Downs Road Pineville, NC 28134 Phone 704-588-7970 Fax 704-588-51 l9 I:311�r1 Pyramid Environmental, Inc. P.O. Box 16265 Greensboro, NC 27416-0265 Attn: Accounts Payable Invoice Date Invoice # 12/2/2021 75721 P.O. No. Terms Project 2021-336 Net 30 Quantity Description Rate Amount 25 -Way Stopcock Valve with Luer Connect -5 137,50 25 60 nil. Syringe with Luer-Lock Tip 3.00 75.00 3 UHP Helium - 34 Liter 55.00 165.00 30 PURE F EP Teflon Tubing - .187" ID x 114" OD - price per foot 1.99 59.70 t l-landling Charge 5.00 5.00 Project Manager: Mike ]ones Sales Tax 6.7500 29.84 Kayla, Please confirm Redept of the stuff with Brian. The project is AZ Devei. 2021-336 QK to pay 4 we got it all Mike Total $472.04 Vapor!tn Ship To: Michael Jones Pyramid Environmentat 503 Industrial Ave Greensboro, NC 27406 Packing Slip (rh15I= Pot a bill! Bill To Michael Jones Pyramid Environmental 503 Industrial Ave Greensboro, NC 27406 Please remit to: Vapor Pin Enterprises, Inc. 7750 Corporate Blvd. Plain City, Chic 43084 1-614-504-6915 Payment Terms = Net 30 Order Number 15726 Order date November 30, 2p21 Payment Method Credit card Email mike@pyramidenvironmental.com Telephone 3363353/74 Product Quantity Rate Total Contractor VAPOR PING Kits - Brass 2 $792,00 $1,584.00 malenal: Brass SKU: VPKiT - CON Subtotal $1,584.00 Shipping $23.52 Ys FadE. Ground Payment method Credit card Total $1,607.62 Thank you for your order! Please note Payment Terms is 30 ❑ays, NOTE: Ail Items are Non -Returnable For updates and Helpful Hints — Please follow VAPOR PINe an Llnkedlll and Facebook! IF you have any questions. please conlact Laurie Chllcale at 1-614-604.691& F108SO n018 Payment TOMM IS 30 Days, NOTE: A I Items are Non-Retumabla lns4mantslapparatus For measuring or checking the Row, level. pressure or other variables of liquids or gases., includes VAPOR PINSV and related accessories Hermamzed codes 9026.Sa and 9M 90 Enviro-Equipment, Inc. 11180 Downs Road Pineville, NC 28134 704-588-7970 www. enviroequipment. com Quote 62551 August 2nd, 2021 Bill To Ship To PW Mike Jones Attn: Mike Jones 503 Industrial Ave 503 Industrial Ave Greensboro, NC 27406 Greensboro, NC 27406 United States United States 866-545-9507 866-545-9507 Delivery PO Number Job Number UPS Ground TBD SKU Item Quantity Unit Price Total 3-Way Valve 3-Way Stopcock Valve with Luer Connections 10 $5.50 $55.00 60-Syringe 60mL Syringe with Luer-Lock tip 10 $3.00 $30.00 UHP-HE-34L Ultra High Purity (99.999%) Helium, 34 L 1 $55.00 $55.00 FEP-31614-1 3116 x 114 IN. Teflon® FEP Tubing, per foot 20 $1.99 $39.80 114 IN. Ferrule Set PIN: SS-400-SET 4 $4.00 $16.00 114 IN. Ferrule Nut P/W SS-402-1 4 $4.00 $16.00 V r All prices are in US dollars and do not include shipping costs unless otherwise specified. Subtotal $211.80 Shipping $55.00 Sales Tax (6.75%) $18.01 Order Total $284.81 Attachment G lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 January 13, 2022 Brett Higgins Pyramid Environmental 503 Industrial Ave. Greensboro, NC 27406 RE: Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Dear Brett Higgins: Enclosed are the analytical results for sample(s) received by the laboratory on December 20, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Minneapolis If you have any questions concerning this report, please feel free to contact me. Sincerely, r� Carolynne Trout for Matt Ray matt. ray@pacelabs.com (612)607-1700 Project Manager Enclosures cc: Mike Jones, Pyramid Environmental REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 44 laneAnalytical www,pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Pace Analytical Services, LLC - Minneapolis MN 1700 Elm Street SE, Minneapolis, MN 55414 1800 Elm Street SE, Minneapolis, MN 55414--Satellite Air Lab A21LA Certification #: 2926.01 Alabama Certification #: 40770 Alaska Contaminated Sites Certification #: 17-009* Alaska DW Certification #: MN00064 Arizona Certification #: AZ0014* Arkansas DW Certification #: MN00064 Arkansas WW Certification #: 88-0680 California Certification #: 2929 Colorado Certification #: MN00064 Connecticut Certification #: PH-0256 EPA Region 8 Tribal Water Systems+Wyoming DW Certification #: via MN 027-053-137 Florida Certification #: E87605* Georgia Certification #: 959 Hawaii Certification #: MN00064 Idaho Certification #: MN00064 Illinois Certification #: 200011 Indiana Certification #: C-MN-01 Iowa Certification #: 368 Kansas Certification M E-10167 Kentucky DW Certification #: 90062 Kentucky WW Certification #: 90062 Louisiana DEQ Certification #: AI-03086* Louisiana DW Certification #: MN00064 Maine Certification #: MN00064* Maryland Certification #: 322 Michigan Certification #: 9909 Minnesota Certification #: 027-053-137* Minnesota Dept ofAg Approval: via MN 027-053-137 Minnesota Petrofund Registration #: 1240* Mississippi Certification #: MN00064 CERTIFICATIONS Missouri Certification #: 10100 Montana Certification #: CERT0092 Nebraska Certification #: NE-OS-18-06 Nevada Certification #: MN00064 New Hampshire Certification #: 2081* New Jersey Certification #: MN002 New York Certification #: 11647* North Carolina DW Certification #: 27700 North Carolina WW Certification #: 530 North Dakota Certification #: R-036 Ohio DW Certification #: 41244 Ohio VAP Certification (1700) #: CL101 Ohio VAP Certification (1800) #: CL110* Oklahoma Certification #: 9507* Oregon Primary Certification #: MN300001 Oregon Secondary Certification #: MN200001* Pennsylvania Certification #: 68-00563* Puerto Rico Certification #: MN00064 South Carolina Certification #:74003001 Tennessee Certification #: TN02818 Texas Certification #: T104704192* Utah Certification #: MN00064* Vermont Certification #: VT-027053137 Virginia Certification #: 460163* Washington Certification #: C486* West Virginia DEP Certification #: 382 West Virginia DW Certification #: 9952 C Wisconsin Certification #: 999407970 Wyoming UST Certification #: via A21LA 2926.01 USDA Permit #: P330-19-00208 *Please Note: Applicable air certifications are denoted with an asterisk (*). REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 SAMPLE SUMMARY Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Lab ID Sample ID Matrix Date Collected Date Received 10592093001 CS-1 Air 12/15/2119:31 12/20/2110:09 10592093002 CS-2 Air 12/15/2119:46 12/20/2110:09 10592093003 CS-3 Air 12/15/2118:18 12/20/2110:09 10592093004 CS-4 Air 12/15/2119:02 12/20/2110:09 10592093005 CS-5 Air 12/15/2118:43 12/20/2110:09 10592093006 CS-6 Air 12/15/2118:30 12/20/2110:09 10592093007 SSV-7 Air 12/15/2114:35 12/20/2110:09 10592093008 SSV-8 Air 12/15/2117:07 12/20/2110:09 10592093009 SSV-9 Air 12/15/2111:27 12/20/2110:09 10592093010 SSV-10 Air 12/15/2114:07 12/20/2110:09 10592093011 SSV-11 Air 12/15/2115:20 12/20/2110:09 10592093012 SSV-11 DUP Air 12/15/21 15:20 12/20/21 10:09 10592093013 CS-12 Air 12/15/2116:55 12/20/2110:09 10592093014 CS-13 Air 12/15/2116:55 12/20/2110:09 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 SAMPLE ANALYTE COUNT Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Lab ID Sample ID Method Analysts Analytes Reported 10592093001 CS-1 TO-15 SW 61 10592093002 CS-2 TO-15 SW 61 10592093003 CS-3 TO-15 SW 61 10592093004 CS-4 TO-15 SW 61 10592093005 CS-5 TO-15 SW 61 10592093006 CS-6 TO-15 SW 61 10592093007 SSV-7 TO-15 SW 61 10592093008 SSV-8 TO-15 SW 61 10592093009 SSV-9 TO-15 AJA, SW 61 10592093010 SSV-10 TO-15 AJA, SW 61 10592093011 SSV-11 TO-15 SW 61 10592093012 SSV-11 DUP TO-15 SW 61 10592093013 CS-12 TO-15 SW 61 10592093014 CS-13 TO-15 SW 61 PASI-M = Pace Analytical Services - Minneapolis REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: CS-1 Lab ID: 10592093001 Collected: 12/15/21 19:31 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone 39.0 ug/m3 10.1 1.68 01/13/22 00:58 67-64-1 Benzene 1.5 ug/m3 0.55 1.68 01/13/22 00:58 71-43-2 Benzyl chloride ND ug/m3 4.4 1.68 01/13/22 00:58 100-44-7 Bromodichloromethane ND ug/m3 2.3 1.68 01/13/22 00:58 75-27-4 Bromoform ND ug/m3 8.8 1.68 01/13/22 00:58 75-25-2 Bromomethane ND ug/m3 1.3 1.68 01/13/22 00:58 74-83-9 1,3-Butadiene ND ug/m3 0.76 1.68 01/13/22 00:58 106-99-0 2-Butanone (MEK) ND ug/m3 5.0 1.68 01/13/22 00:58 78-93-3 Carbon disulfide ND ug/m3 1.1 1.68 01/13/22 00:58 75-15-0 Carbon tetrachloride ND ug/m3 2.2 1.68 01/13/22 00:58 56-23-5 Chlorobenzene ND ug/m3 1.6 1.68 01/13/22 00:58 108-90-7 Chloroethane ND ug/m3 0.90 1.68 01/13/22 00:58 75-00-3 Chloroform ND ug/m3 0.83 1.68 01/13/22 00:58 67-66-3 Chloromethane 1.1 ug/m3 0.71 1.68 01/13/22 00:58 74-87-3 Cyclohexane ND ug/m3 2.9 1.68 01/13/22 00:58 110-82-7 Dibromochloromethane ND ug/m3 2.9 1.68 01/13/22 00:58 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 1.3 1.68 01/13/22 00:58 106-93-4 1,2-Dichlorobenzene ND ug/m3 5.1 1.68 01/13/22 00:58 95-50-1 1,3-Dichlorobenzene ND ug/m3 5.1 1.68 01/13/22 00:58 541-73-1 1,4-Dichlorobenzene ND ug/m3 5.1 1.68 01/13/22 00:58 106-46-7 Dichlorodifluoromethane 2.7 ug/m3 1.7 1.68 01/13/22 00:58 75-71-8 1,1-Dichloroethane ND ug/m3 1.4 1.68 01/13/22 00:58 75-34-3 1,2-Dichloroethane ND ug/m3 1.4 1.68 01/13/22 00:58 107-06-2 1,1-Dichloroethene ND ug/m3 1.4 1.68 01/13/22 00:58 75-35-4 cis-1,2-Dichloroethene ND ug/m3 1.4 1.68 01/13/22 00:58 156-59-2 trans-1,2-Dichloroethene ND ug/m3 1.4 1.68 01/13/22 00:58 156-60-5 1,2-Dichloropropene ND ug/m3 1.6 1.68 01/13/22 00:58 78-87-5 cis-1,3-Dichloropropene ND ug/m3 3.9 1.68 01/13/22 00:58 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 3.9 1.68 01/13/22 00:58 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 2.4 1.68 01/13/22 00:58 76-14-2 Ethanol 1050 ug/m3 3.2 1.68 01/13/22 00:58 64-17-5 Ethyl acetate 3.1 ug/m3 1.2 1.68 01/13/22 00:58 141-78-6 Ethylbenzene ND ug/m3 1.5 1.68 01/13/22 00:58 100-41-4 4-Ethyltoluene ND ug/m3 4.2 1.68 01/13/22 00:58 622-96-8 n-Heptane ND ug/m3 1.4 1.68 01/13/22 00:58 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 9.1 1.68 01/13/22 00:58 87-68-3 n-Hexane 1.7 ug/m3 1.2 1.68 01/13/22 00:58 110-54-3 2-Hexanone ND ug/m3 7.0 1.68 01/13/22 00:58 591-78-6 Methylene Chloride ND ug/m3 5.9 1.68 01/13/22 00:58 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 7.0 1.68 01/13/22 00:58 108-10-1 Methyl-tert-butyl ether ND ug/m3 6.1 1.68 01/13/22 00:58 1634-04-4 Naphthalene ND ug/m3 4.5 1.68 01/13/22 00:58 91-20-3 2-Propanol 23.4 ug/m3 4.2 1.68 01/13/22 00:58 67-63-0 Propylene ND ug/m3 1.5 1.68 01/13/22 00:58 115-07-1 Styrene ND ug/m3 1.5 1.68 01/13/22 00:58 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 2.4 1.68 01/13/22 00:58 79-34-5 REPORT OF LABORATORY ANALYSIS E This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: CS-1 Lab ID: 10592093001 Collected: 12/15/21 19:31 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene ND ug/m3 1.2 1.68 01/13/22 00:58 127-18-4 Tetrahydrofuran ND ug/m3 1.0 1.68 01/13/22 00:58 109-99-9 Toluene 4.1 ug/m3 1.3 1.68 01/13/22 00:58 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 12.7 1.68 01/13/22 00:58 120-82-1 1,1,1-Trichloroethane ND ug/m3 1.9 1.68 01/13/22 00:58 71-55-6 1,1,2-Trichloroethane ND ug/m3 0.93 1.68 01/13/22 00:58 79-00-5 Trichloroethene ND ug/m3 0.92 1.68 01/13/22 00:58 79-01-6 Trichlorofluoromethane ND ug/m3 1.9 1.68 01/13/22 00:58 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 2.6 1.68 01/13/22 00:58 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 1.7 1.68 01/13/22 00:58 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 1.7 1.68 01/13/22 00:58 108-67-8 Vinyl acetate ND ug/m3 1.2 1.68 01/13/22 00:58 108-05-4 Vinyl chloride ND ug/m3 0.44 1.68 01/13/22 00:58 75-01-4 m&p-Xylene ND ug/m3 3.0 1.68 01/13/22 00:58 179601-23-1 o-Xylene ND ug/m3 1.5 1.68 01/13/22 00:58 95-47-6 Date: 01/13/2022 04:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: CS-2 Lab ID: 10592093002 Collected: 12/15/21 19:46 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone 65.4 ug/m3 8.1 1.34 01/13/22 00:24 67-64-1 Benzene 3.0 ug/m3 0.44 1.34 01/13/22 00:24 71-43-2 Benzyl chloride ND ug/m3 3.5 1.34 01/13/22 00:24 100-44-7 Bromodichloromethane ND ug/m3 1.8 1.34 01/13/22 00:24 75-27-4 Bromoform ND ug/m3 7.0 1.34 01/13/22 00:24 75-25-2 Bromomethane ND ug/m3 1.1 1.34 01/13/22 00:24 74-83-9 1,3-Butadiene ND ug/m3 0.60 1.34 01/13/22 00:24 106-99-0 2-Butanone (MEK) 7.0 ug/m3 4.0 1.34 01/13/22 00:24 78-93-3 Carbon disulfide 1.1 ug/m3 0.85 1.34 01/13/22 00:24 75-15-0 Carbon tetrachloride ND ug/m3 1.7 1.34 01/13/22 00:24 56-23-5 Chlorobenzene ND ug/m3 1.3 1.34 01/13/22 00:24 108-90-7 Chloroethane ND ug/m3 0.72 1.34 01/13/22 00:24 75-00-3 Chloroform ND ug/m3 0.66 1.34 01/13/22 00:24 67-66-3 Chloromethane 4.5 ug/m3 0.56 1.34 01/13/22 00:24 74-87-3 Cyclohexane 3.1 ug/m3 2.3 1.34 01/13/22 00:24 110-82-7 Dibromochloromethane ND ug/m3 2.3 1.34 01/13/22 00:24 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 1.0 1.34 01/13/22 00:24 106-93-4 1,2-Dichlorobenzene ND ug/m3 4.1 1.34 01/13/22 00:24 95-50-1 1,3-Dichlorobenzene ND ug/m3 4.1 1.34 01/13/22 00:24 541-73-1 1,4-Dichlorobenzene ND ug/m3 4.1 1.34 01/13/22 00:24 106-46-7 Dichlorodifluoromethane 3.0 ug/m3 1.4 1.34 01/13/22 00:24 75-71-8 1,1-Dichloroethane ND ug/m3 1.1 1.34 01/13/22 00:24 75-34-3 1,2-Dichloroethane ND ug/m3 1.1 1.34 01/13/22 00:24 107-06-2 1,1-Dichloroethene ND ug/m3 1.1 1.34 01/13/22 00:24 75-35-4 cis-1,2-Dichloroethene ND ug/m3 1.1 1.34 01/13/22 00:24 156-59-2 trans-1,2-Dichloroethene ND ug/m3 1.1 1.34 01/13/22 00:24 156-60-5 1,2-Dichloropropene ND ug/m3 1.3 1.34 01/13/22 00:24 78-87-5 cis-1,3-Dichloropropene ND ug/m3 3.1 1.34 01/13/22 00:24 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 3.1 1.34 01/13/22 00:24 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 1.9 1.34 01/13/22 00:24 76-14-2 Ethanol 192 ug/m3 2.6 1.34 01/13/22 00:24 64-17-5 Ethyl acetate ND ug/m3 0.98 1.34 01/13/22 00:24 141-78-6 Ethylbenzene 2.5 ug/m3 1.2 1.34 01/13/22 00:24 100-41-4 4-Ethyltoluene ND ug/m3 3.4 1.34 01/13/22 00:24 622-96-8 n-Heptane 3.3 ug/m3 1.1 1.34 01/13/22 00:24 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 7.3 1.34 01/13/22 00:24 87-68-3 n-Hexane 8.0 ug/m3 0.96 1.34 01/13/22 00:24 110-54-3 2-Hexanone ND ug/m3 5.6 1.34 01/13/22 00:24 591-78-6 Methylene Chloride 5.3 ug/m3 4.7 1.34 01/13/22 00:24 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 5.6 1.34 01/13/22 00:24 108-10-1 Methyl-tert-butyl ether ND ug/m3 4.9 1.34 01/13/22 00:24 1634-04-4 Naphthalene ND ug/m3 3.6 1.34 01/13/22 00:24 91-20-3 2-Propanol 18.4 ug/m3 3.4 1.34 01/13/22 00:24 67-63-0 Propylene ND ug/m3 1.2 1.34 01/13/22 00:24 115-07-1 Styrene 1.4 ug/m3 1.2 1.34 01/13/22 00:24 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 1.9 1.34 01/13/22 00:24 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: CS-2 Lab ID: 10592093002 Collected: 12/15/21 19:46 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 2.0 ug/m3 0.92 1.34 01/13/22 00:24 127-18-4 Tetrahydrofuran ND ug/m3 0.80 1.34 01/13/22 00:24 109-99-9 Toluene 63.7 ug/m3 1.0 1.34 01/13/22 00:24 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 10.1 1.34 01/13/22 00:24 120-82-1 1,1,1-Trichloroethane ND ug/m3 1.5 1.34 01/13/22 00:24 71-55-6 1,1,2-Trichloroethane ND ug/m3 0.74 1.34 01/13/22 00:24 79-00-5 Trichloroethene 3.3 ug/m3 0.73 1.34 01/13/22 00:24 79-01-6 Trichlorofluoromethane 1.6 ug/m3 1.5 1.34 01/13/22 00:24 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 2.1 1.34 01/13/22 00:24 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 1.3 1.34 01/13/22 00:24 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 1.3 1.34 01/13/22 00:24 108-67-8 Vinyl acetate ND ug/m3 0.96 1.34 01/13/22 00:24 108-05-4 Vinyl chloride ND ug/m3 0.35 1.34 01/13/22 00:24 75-01-4 m&p-Xylene 8.0 ug/m3 2.4 1.34 01/13/22 00:24 179601-23-1 o-Xylene 3.0 ug/m3 1.2 1.34 01/13/22 00:24 95-47-6 Date: 01/13/2022 04:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: CS-3 Lab ID: 10592093003 Collected: 12/15/21 18:18 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone 18.4 ug/m3 11.1 1.83 01/12/22 19:19 67-64-1 Benzene 2.7 ug/m3 0.59 1.83 01/12/22 19:19 71-43-2 Benzyl chloride ND ug/m3 4.8 1.83 01/12/22 19:19 100-44-7 Bromodichloromethane ND ug/m3 2.5 1.83 01/12/22 19:19 75-27-4 Bromoform ND ug/m3 9.6 1.83 01/12/22 19:19 75-25-2 Bromomethane ND ug/m3 1.4 1.83 01/12/22 19:19 74-83-9 1,3-Butadiene ND ug/m3 0.82 1.83 01/12/22 19:19 106-99-0 2-Butanone (MEK) ND ug/m3 5.5 1.83 01/12/22 19:19 78-93-3 Carbon disulfide ND ug/m3 1.2 1.83 01/12/22 19:19 75-15-0 Carbon tetrachloride ND ug/m3 2.3 1.83 01/12/22 19:19 56-23-5 Chlorobenzene ND ug/m3 1.7 1.83 01/12/22 19:19 108-90-7 Chloroethane ND ug/m3 0.98 1.83 01/12/22 19:19 75-00-3 Chloroform ND ug/m3 0.91 1.83 01/12/22 19:19 67-66-3 Chloromethane 1.1 ug/m3 0.77 1.83 01/12/22 19:19 74-87-3 Cyclohexane 4.8 ug/m3 3.2 1.83 01/12/22 19:19 110-82-7 Dibromochloromethane ND ug/m3 3.2 1.83 01/12/22 19:19 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 1.4 1.83 01/12/22 19:19 106-93-4 1,2-Dichlorobenzene ND ug/m3 5.6 1.83 01/12/22 19:19 95-50-1 1,3-Dichlorobenzene ND ug/m3 5.6 1.83 01/12/22 19:19 541-73-1 1,4-Dichlorobenzene ND ug/m3 5.6 1.83 01/12/22 19:19 106-46-7 Dichlorodifluoromethane 2.7 ug/m3 1.8 1.83 01/12/22 19:19 75-71-8 1,1-Dichloroethane ND ug/m3 1.5 1.83 01/12/22 19:19 75-34-3 1,2-Dichloroethane ND ug/m3 1.5 1.83 01/12/22 19:19 107-06-2 1,1-Dichloroethene ND ug/m3 1.5 1.83 01/12/22 19:19 75-35-4 cis-1,2-Dichloroethene ND ug/m3 1.5 1.83 01/12/22 19:19 156-59-2 trans-1,2-Dichloroethene ND ug/m3 1.5 1.83 01/12/22 19:19 156-60-5 1,2-Dichloropropene ND ug/m3 1.7 1.83 01/12/22 19:19 78-87-5 cis-1,3-Dichloropropene ND ug/m3 4.2 1.83 01/12/22 19:19 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 4.2 1.83 01/12/22 19:19 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 2.6 1.83 01/12/22 19:19 76-14-2 Ethanol 309 ug/m3 3.5 1.83 01/12/22 19:19 64-17-5 Ethyl acetate ND ug/m3 1.3 1.83 01/12/22 19:19 141-78-6 Ethylbenzene ND ug/m3 1.6 1.83 01/12/22 19:19 100-41-4 4-Ethyltoluene ND ug/m3 4.6 1.83 01/12/22 19:19 622-96-8 n-Heptane 11.5 ug/m3 1.5 1.83 01/12/22 19:19 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 9.9 1.83 01/12/22 19:19 87-68-3 n-Hexane 1.5 ug/m3 1.3 1.83 01/12/22 19:19 110-54-3 2-Hexanone ND ug/m3 7.6 1.83 01/12/22 19:19 591-78-6 Methylene Chloride ND ug/m3 6.5 1.83 01/12/22 19:19 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 7.6 1.83 01/12/22 19:19 108-10-1 Methyl-tert-butyl ether ND ug/m3 6.7 1.83 01/12/22 19:19 1634-04-4 Naphthalene ND ug/m3 4.9 1.83 01/12/22 19:19 91-20-3 2-Propanol 5.6 ug/m3 4.6 1.83 01/12/22 19:19 67-63-0 Propylene 4.2 ug/m3 1.6 1.83 01/12/22 19:19 115-07-1 Styrene ND ug/m3 1.6 1.83 01/12/22 19:19 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 2.6 1.83 01/12/22 19:19 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: CS-3 Lab ID: 10592093003 Collected: 12/15/21 18:18 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene ND ug/m3 1.3 1.83 01/12/22 19:19 127-18-4 Tetrahydrofuran ND ug/m3 1.1 1.83 01/12/22 19:19 109-99-9 Toluene 5.5 ug/m3 1.4 1.83 01/12/22 19:19 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 13.8 1.83 01/12/22 19:19 120-82-1 1,1,1-Trichloroethane ND ug/m3 2.0 1.83 01/12/22 19:19 71-55-6 1,1,2-Trichloroethane ND ug/m3 1.0 1.83 01/12/22 19:19 79-00-5 Trichloroethene ND ug/m3 1.0 1.83 01/12/22 19:19 79-01-6 Trichlorofluoromethane ND ug/m3 2.1 1.83 01/12/22 19:19 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 2.9 1.83 01/12/22 19:19 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 1.8 1.83 01/12/22 19:19 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 1.8 1.83 01/12/22 19:19 108-67-8 Vinyl acetate ND ug/m3 1.3 1.83 01/12/22 19:19 108-05-4 Vinyl chloride ND ug/m3 0.48 1.83 01/12/22 19:19 75-01-4 m&p-Xylene ND ug/m3 3.2 1.83 01/12/22 19:19 179601-23-1 o-Xylene ND ug/m3 1.6 1.83 01/12/22 19:19 95-47-6 Date: 01/13/2022 04:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: CS-4 Lab ID: 10592093004 Collected: 12/15/21 19:02 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone 60.2 ug/m3 12.8 2.12 01/12/22 23:50 67-64-1 Benzene 1.1 ug/m3 0.69 2.12 01/12/22 23:50 71-43-2 Benzyl chloride ND ug/m3 5.6 2.12 01/12/22 23:50 100-44-7 Bromodichloromethane ND ug/m3 2.9 2.12 01/12/22 23:50 75-27-4 Bromoform ND ug/m3 11.1 2.12 01/12/22 23:50 75-25-2 Bromomethane ND ug/m3 1.7 2.12 01/12/22 23:50 74-83-9 1,3-Butadiene ND ug/m3 0.95 2.12 01/12/22 23:50 106-99-0 2-Butanone (MEK) 7.3 ug/m3 6.4 2.12 01/12/22 23:50 78-93-3 Carbon disulfide ND ug/m3 1.3 2.12 01/12/22 23:50 75-15-0 Carbon tetrachloride ND ug/m3 2.7 2.12 01/12/22 23:50 56-23-5 Chlorobenzene ND ug/m3 2.0 2.12 01/12/22 23:50 108-90-7 Chloroethane ND ug/m3 1.1 2.12 01/12/22 23:50 75-00-3 Chloroform ND ug/m3 1.1 2.12 01/12/22 23:50 67-66-3 Chloromethane 1.7 ug/m3 0.89 2.12 01/12/22 23:50 74-87-3 Cyclohexane ND ug/m3 3.7 2.12 01/12/22 23:50 110-82-7 Dibromochloromethane ND ug/m3 3.7 2.12 01/12/22 23:50 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 1.7 2.12 01/12/22 23:50 106-93-4 1,2-Dichlorobenzene ND ug/m3 6.5 2.12 01/12/22 23:50 95-50-1 1,3-Dichlorobenzene ND ug/m3 6.5 2.12 01/12/22 23:50 541-73-1 1,4-Dichlorobenzene ND ug/m3 6.5 2.12 01/12/22 23:50 106-46-7 Dichlorodifluoromethane 3.2 ug/m3 2.1 2.12 01/12/22 23:50 75-71-8 1,1-Dichloroethane ND ug/m3 1.7 2.12 01/12/22 23:50 75-34-3 1,2-Dichloroethane ND ug/m3 1.7 2.12 01/12/22 23:50 107-06-2 1,1-Dichloroethene ND ug/m3 1.7 2.12 01/12/22 23:50 75-35-4 cis-1,2-Dichloroethene ND ug/m3 1.7 2.12 01/12/22 23:50 156-59-2 trans-1,2-Dichloroethene ND ug/m3 1.7 2.12 01/12/22 23:50 156-60-5 1,2-Dichloropropene ND ug/m3 2.0 2.12 01/12/22 23:50 78-87-5 cis-1,3-Dichloropropene ND ug/m3 4.9 2.12 01/12/22 23:50 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 4.9 2.12 01/12/22 23:50 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 3.0 2.12 01/12/22 23:50 76-14-2 Ethanol 1480 ug/m3 4.1 2.12 01/12/22 23:50 64-17-5 Ethyl acetate 3.5 ug/m3 1.6 2.12 01/12/22 23:50 141-78-6 Ethylbenzene ND ug/m3 1.9 2.12 01/12/22 23:50 100-41-4 4-Ethyltoluene ND ug/m3 5.3 2.12 01/12/22 23:50 622-96-8 n-Heptane ND ug/m3 1.8 2.12 01/12/22 23:50 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 11.5 2.12 01/12/22 23:50 87-68-3 n-Hexane ND ug/m3 1.5 2.12 01/12/22 23:50 110-54-3 2-Hexanone ND ug/m3 8.8 2.12 01/12/22 23:50 591-78-6 Methylene Chloride ND ug/m3 7.5 2.12 01/12/22 23:50 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 8.8 2.12 01/12/22 23:50 108-10-1 Methyl-tert-butyl ether ND ug/m3 7.8 2.12 01/12/22 23:50 1634-04-4 Naphthalene ND ug/m3 5.6 2.12 01/12/22 23:50 91-20-3 2-Propanol 19.9 ug/m3 5.3 2.12 01/12/22 23:50 67-63-0 Propylene ND ug/m3 1.9 2.12 01/12/22 23:50 115-07-1 Styrene ND ug/m3 1.8 2.12 01/12/22 23:50 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 3.0 2.12 01/12/22 23:50 79-34-5 REPORT OF LABORATORY ANALYSIS E This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: CS-4 Lab ID: 10592093004 Collected: 12/15/21 19:02 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene ND ug/m3 1.5 2.12 01/12/22 23:50 127-18-4 Tetrahydrofuran ND ug/m3 1.3 2.12 01/12/22 23:50 109-99-9 Toluene 2.8 ug/m3 1.6 2.12 01/12/22 23:50 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 16.0 2.12 01/12/22 23:50 120-82-1 1,1,1-Trichloroethane ND ug/m3 2.4 2.12 01/12/22 23:50 71-55-6 1,1,2-Trichloroethane ND ug/m3 1.2 2.12 01/12/22 23:50 79-00-5 Trichloroethene ND ug/m3 1.2 2.12 01/12/22 23:50 79-01-6 Trichlorofluoromethane ND ug/m3 2.4 2.12 01/12/22 23:50 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 3.3 2.12 01/12/22 23:50 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 2.1 2.12 01/12/22 23:50 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 2.1 2.12 01/12/22 23:50 108-67-8 Vinyl acetate ND ug/m3 1.5 2.12 01/12/22 23:50 108-05-4 Vinyl chloride ND ug/m3 0.55 2.12 01/12/22 23:50 75-01-4 m&p-Xylene ND ug/m3 3.8 2.12 01/12/22 23:50 179601-23-1 o-Xylene ND ug/m3 1.9 2.12 01/12/22 23:50 95-47-6 Date: 01/13/2022 04:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: CS-5 Lab ID: 10592093005 Collected: 12/15/21 18:43 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Dichlorodifluoromethane 2.9 ug/m3 2.0 1.96 01/12/22 16:30 75-71-8 Chloromethane 1.7 ug/m3 0.82 1.96 01/12/22 16:30 74-87-3 Dichlorotetrafluoroethane ND ug/m3 2.8 1.96 01/12/22 16:30 76-14-2 Vinyl chloride ND ug/m3 0.51 1.96 01/12/22 16:30 75-01-4 Bromomethane ND ug/m3 1.5 1.96 01/12/22 16:30 74-83-9 Chloroethane ND ug/m3 1.1 1.96 01/12/22 16:30 75-00-3 Trichlorofluoromethane ND ug/m3 2.2 1.96 01/12/22 16:30 75-69-4 1,1-Dichloroethene ND ug/m3 1.6 1.96 01/12/22 16:30 75-35-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 3.1 1.96 01/12/22 16:30 76-13-1 Methylene Chloride ND ug/m3 6.9 1.96 01/12/22 16:30 75-09-2 1,1-Dichloroethane ND ug/m3 1.6 1.96 01/12/22 16:30 75-34-3 cis-1,2-Dichloroethene ND ug/m3 1.6 1.96 01/12/22 16:30 156-59-2 Chloroform ND ug/m3 0.97 1.96 01/12/22 16:30 67-66-3 1,1,1-Trichloroethane ND ug/m3 2.2 1.96 01/12/22 16:30 71-55-6 1,1,2-Trichloroethane ND ug/m3 1.1 1.96 01/12/22 16:30 79-00-5 1,2-Dichloroethane ND ug/m3 1.6 1.96 01/12/22 16:30 107-06-2 Benzene 1.1 ug/m3 0.64 1.96 01/12/22 16:30 71-43-2 Carbon tetrachloride ND ug/m3 2.5 1.96 01/12/22 16:30 56-23-5 1,2-Dichloropropene ND ug/m3 1.8 1.96 01/12/22 16:30 78-87-5 Trichloroethene ND ug/m3 1.1 1.96 01/12/22 16:30 79-01-6 cis-1,3-Dichloropropene ND ug/m3 4.5 1.96 01/12/22 16:30 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 4.5 1.96 01/12/22 16:30 10061-02-6 Toluene 8.9 ug/m3 1.5 1.96 01/12/22 16:30 108-88-3 1,2-Dibromoethane (EDB) ND ug/m3 1.5 1.96 01/12/22 16:30 106-93-4 Tetrachloroethene ND ug/m3 1.4 1.96 01/12/22 16:30 127-18-4 Chlorobenzene ND ug/m3 1.8 1.96 01/12/22 16:30 108-90-7 Ethylbenzene ND ug/m3 1.7 1.96 01/12/22 16:30 100-41-4 m&p-Xylene ND ug/m3 3.5 1.96 01/12/22 16:30 179601-23-1 o-Xylene ND ug/m3 1.7 1.96 01/12/22 16:30 95-47-6 Styrene ND ug/m3 1.7 1.96 01/12/22 16:30 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 2.7 1.96 01/12/22 16:30 79-34-5 1,3,5-Trimethylbenzene ND ug/m3 2.0 1.96 01/12/22 16:30 108-67-8 1,2,4-Trimethylbenzene ND ug/m3 2.0 1.96 01/12/22 16:30 95-63-6 1,3-Dichlorobenzene ND ug/m3 6.0 1.96 01/12/22 16:30 541-73-1 1,4-Dichlorobenzene ND ug/m3 6.0 1.96 01/12/22 16:30 106-46-7 1,2-Dichlorobenzene ND ug/m3 6.0 1.96 01/12/22 16:30 95-50-1 1,2,4-Trichlorobenzene ND ug/m3 14.8 1.96 01/12/22 16:30 120-82-1 Hexachloro-1,3-butadiene ND ug/m3 10.6 1.96 01/12/22 16:30 87-68-3 Tetrahydrofuran ND ug/m3 1.2 1.96 01/12/22 16:30 109-99-9 Acetone 97.0 ug/m3 11.8 1.96 01/12/22 16:30 67-64-1 2-Butanone (MEK) 6.4 ug/m3 5.9 1.96 01/12/22 16:30 78-93-3 n-Hexane ND ug/m3 1.4 1.96 01/12/22 16:30 110-54-3 Methyl-tert-butyl ether ND ug/m3 7.2 1.96 01/12/22 16:30 1634-04-4 Dibromochloromethane ND ug/m3 3.4 1.96 01/12/22 16:30 124-48-1 1,3-Butadiene ND ug/m3 0.88 1.96 01/12/22 16:30 106-99-0 Carbon disulfide ND ug/m3 1.2 1.96 01/12/22 16:30 75-15-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: CS-5 Lab ID: 10592093005 Collected: 12/15/21 18:43 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Vinyl acetate ND ug/m3 1.4 1.96 01/12/22 16:30 108-05-4 Cyclohexane ND ug/m3 3.4 1.96 01/12/22 16:30 110-82-7 Ethyl acetate 3.7 ug/m3 1.4 1.96 01/12/22 16:30 141-78-6 4-Methyl-2-pentanone (MIBK) ND ug/m3 8.2 1.96 01/12/22 16:30 108-10-1 2-Hexanone ND ug/m3 8.2 1.96 01/12/22 16:30 591-78-6 Bromoform ND ug/m3 10.3 1.96 01/12/22 16:30 75-25-2 trans-1,2-Dichloroethene ND ug/m3 1.6 1.96 01/12/22 16:30 156-60-5 Bromodichloromethane ND ug/m3 2.7 1.96 01/12/22 16:30 75-27-4 n-Heptane ND ug/m3 1.6 1.96 01/12/22 16:30 142-82-5 Propylene ND ug/m3 1.7 1.96 01/12/22 16:30 115-07-1 4-Ethyltoluene ND ug/m3 4.9 1.96 01/12/22 16:30 622-96-8 Naphthalene 5.8 ug/m3 5.2 1.96 01/12/22 16:30 91-20-3 Ethanol 1550 ug/m3 3.8 1.96 01/12/22 16:30 64-17-5 2-Propanol 23.0 ug/m3 4.9 1.96 01/12/22 16:30 67-63-0 Benzyl chloride ND ug/m3 5.2 1.96 01/12/22 16:30 100-44-7 Date: 01/13/2022 04:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. E Page 14 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: CS-6 Lab ID: 10592093006 Collected: 12/15/21 18:30 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone 32.8 ug/m3 10.3 1.71 01/12/22 17:38 67-64-1 Benzene 1.2 ug/m3 0.56 1.71 01/12/22 17:38 71-43-2 Benzyl chloride ND ug/m3 4.5 1.71 01/12/22 17:38 100-44-7 Bromodichloromethane ND ug/m3 2.3 1.71 01/12/22 17:38 75-27-4 Bromoform ND ug/m3 9.0 1.71 01/12/22 17:38 75-25-2 Bromomethane ND ug/m3 1.3 1.71 01/12/22 17:38 74-83-9 1,3-Butadiene ND ug/m3 0.77 1.71 01/12/22 17:38 106-99-0 2-Butanone (MEK) ND ug/m3 5.1 1.71 01/12/22 17:38 78-93-3 Carbon disulfide ND ug/m3 1.1 1.71 01/12/22 17:38 75-15-0 Carbon tetrachloride ND ug/m3 2.2 1.71 01/12/22 17:38 56-23-5 Chlorobenzene ND ug/m3 1.6 1.71 01/12/22 17:38 108-90-7 Chloroethane ND ug/m3 0.92 1.71 01/12/22 17:38 75-00-3 Chloroform ND ug/m3 0.85 1.71 01/12/22 17:38 67-66-3 Chloromethane 1.3 ug/m3 0.72 1.71 01/12/22 17:38 74-87-3 Cyclohexane ND ug/m3 3.0 1.71 01/12/22 17:38 110-82-7 Dibromochloromethane ND ug/m3 3.0 1.71 01/12/22 17:38 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 1.3 1.71 01/12/22 17:38 106-93-4 1,2-Dichlorobenzene ND ug/m3 5.2 1.71 01/12/22 17:38 95-50-1 1,3-Dichlorobenzene ND ug/m3 5.2 1.71 01/12/22 17:38 541-73-1 1,4-Dichlorobenzene ND ug/m3 5.2 1.71 01/12/22 17:38 106-46-7 Dichlorodifluoromethane 2.6 ug/m3 1.7 1.71 01/12/22 17:38 75-71-8 1,1-Dichloroethane ND ug/m3 1.4 1.71 01/12/22 17:38 75-34-3 1,2-Dichloroethane ND ug/m3 1.4 1.71 01/12/22 17:38 107-06-2 1,1-Dichloroethene ND ug/m3 1.4 1.71 01/12/22 17:38 75-35-4 cis-1,2-Dichloroethene ND ug/m3 1.4 1.71 01/12/22 17:38 156-59-2 trans-1,2-Dichloroethene ND ug/m3 1.4 1.71 01/12/22 17:38 156-60-5 1,2-Dichloropropene ND ug/m3 1.6 1.71 01/12/22 17:38 78-87-5 cis-1,3-Dichloropropene ND ug/m3 4.0 1.71 01/12/22 17:38 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 4.0 1.71 01/12/22 17:38 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 2.4 1.71 01/12/22 17:38 76-14-2 Ethanol 1340 ug/m3 3.3 1.71 01/12/22 17:38 64-17-5 Ethyl acetate 2.7 ug/m3 1.3 1.71 01/12/22 17:38 141-78-6 Ethylbenzene ND ug/m3 1.5 1.71 01/12/22 17:38 100-41-4 4-Ethyltoluene ND ug/m3 4.3 1.71 01/12/22 17:38 622-96-8 n-Heptane 4.9 ug/m3 1.4 1.71 01/12/22 17:38 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 9.3 1.71 01/12/22 17:38 87-68-3 n-Hexane 1.2 ug/m3 1.2 1.71 01/12/22 17:38 110-54-3 2-Hexanone ND ug/m3 7.1 1.71 01/12/22 17:38 591-78-6 Methylene Chloride ND ug/m3 6.0 1.71 01/12/22 17:38 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 7.1 1.71 01/12/22 17:38 108-10-1 Methyl-tert-butyl ether ND ug/m3 6.3 1.71 01/12/22 17:38 1634-04-4 Naphthalene ND ug/m3 4.5 1.71 01/12/22 17:38 91-20-3 2-Propanol 16.1 ug/m3 4.3 1.71 01/12/22 17:38 67-63-0 Propylene ND ug/m3 1.5 1.71 01/12/22 17:38 115-07-1 Styrene ND ug/m3 1.5 1.71 01/12/22 17:38 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 2.4 1.71 01/12/22 17:38 79-34-5 REPORT OF LABORATORY ANALYSIS E This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: CS-6 Lab ID: 10592093006 Collected: 12/15/21 18:30 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene ND ug/m3 1.2 1.71 01/12/22 17:38 127-18-4 Tetrahydrofuran ND ug/m3 1.0 1.71 01/12/22 17:38 109-99-9 Toluene 3.1 ug/m3 1.3 1.71 01/12/22 17:38 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 12.9 1.71 01/12/22 17:38 120-82-1 1,1,1-Trichloroethane ND ug/m3 1.9 1.71 01/12/22 17:38 71-55-6 1,1,2-Trichloroethane ND ug/m3 0.95 1.71 01/12/22 17:38 79-00-5 Trichloroethene ND ug/m3 0.93 1.71 01/12/22 17:38 79-01-6 Trichlorofluoromethane ND ug/m3 1.9 1.71 01/12/22 17:38 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 2.7 1.71 01/12/22 17:38 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 1.7 1.71 01/12/22 17:38 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 1.7 1.71 01/12/22 17:38 108-67-8 Vinyl acetate ND ug/m3 1.2 1.71 01/12/22 17:38 108-05-4 Vinyl chloride ND ug/m3 0.44 1.71 01/12/22 17:38 75-01-4 m&p-Xylene ND ug/m3 3.0 1.71 01/12/22 17:38 179601-23-1 o-Xylene ND ug/m3 1.5 1.71 01/12/22 17:38 95-47-6 Date: 01/13/2022 04:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: SSV-7 Lab ID: 10592093007 Collected: 12/15/21 14:35 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone ND ug/m3 10.8 1.79 01/12/22 18:45 67-64-1 Benzene ND ug/m3 0.58 1.79 01/12/22 18:45 71-43-2 Benzyl chloride ND ug/m3 4.7 1.79 01/12/22 18:45 100-44-7 Bromodichloromethane ND ug/m3 2.4 1.79 01/12/22 18:45 75-27-4 Bromoform ND ug/m3 9.4 1.79 01/12/22 18:45 75-25-2 Bromomethane ND ug/m3 1.4 1.79 01/12/22 18:45 74-83-9 1,3-Butadiene ND ug/m3 0.81 1.79 01/12/22 18:45 106-99-0 2-Butanone (MEK) ND ug/m3 5.4 1.79 01/12/22 18:45 78-93-3 Carbon disulfide ND ug/m3 1.1 1.79 01/12/22 18:45 75-15-0 Carbon tetrachloride ND ug/m3 2.3 1.79 01/12/22 18:45 56-23-5 Chlorobenzene ND ug/m3 1.7 1.79 01/12/22 18:45 108-90-7 Chloroethane ND ug/m3 0.96 1.79 01/12/22 18:45 75-00-3 Chloroform 3.5 ug/m3 0.89 1.79 01/12/22 18:45 67-66-3 Chloromethane ND ug/m3 0.75 1.79 01/12/22 18:45 74-87-3 Cyclohexane ND ug/m3 3.1 1.79 01/12/22 18:45 110-82-7 Dibromochloromethane ND ug/m3 3.1 1.79 01/12/22 18:45 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 1.4 1.79 01/12/22 18:45 106-93-4 1,2-Dichlorobenzene ND ug/m3 5.5 1.79 01/12/22 18:45 95-50-1 1,3-Dichlorobenzene ND ug/m3 5.5 1.79 01/12/22 18:45 541-73-1 1,4-Dichlorobenzene ND ug/m3 5.5 1.79 01/12/22 18:45 106-46-7 Dichlorodifluoromethane 2.8 ug/m3 1.8 1.79 01/12/22 18:45 75-71-8 1,1-Dichloroethane ND ug/m3 1.5 1.79 01/12/22 18:45 75-34-3 1,2-Dichloroethane ND ug/m3 1.5 1.79 01/12/22 18:45 107-06-2 1,1-Dichloroethene ND ug/m3 1.4 1.79 01/12/22 18:45 75-35-4 cis-1,2-Dichloroethene ND ug/m3 1.4 1.79 01/12/22 18:45 156-59-2 trans-1,2-Dichloroethene ND ug/m3 1.4 1.79 01/12/22 18:45 156-60-5 1,2-Dichloropropene ND ug/m3 1.7 1.79 01/12/22 18:45 78-87-5 cis-1,3-Dichloropropene ND ug/m3 4.1 1.79 01/12/22 18:45 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 4.1 1.79 01/12/22 18:45 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 2.5 1.79 01/12/22 18:45 76-14-2 Ethanol 102 ug/m3 3.4 1.79 01/12/22 18:45 64-17-5 Ethyl acetate ND ug/m3 1.3 1.79 01/12/22 18:45 141-78-6 Ethylbenzene ND ug/m3 1.6 1.79 01/12/22 18:45 100-41-4 4-Ethyltoluene ND ug/m3 4.5 1.79 01/12/22 18:45 622-96-8 n-Heptane ND ug/m3 1.5 1.79 01/12/22 18:45 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 9.7 1.79 01/12/22 18:45 87-68-3 n-Hexane ND ug/m3 1.3 1.79 01/12/22 18:45 110-54-3 2-Hexanone ND ug/m3 7.4 1.79 01/12/22 18:45 591-78-6 Methylene Chloride ND ug/m3 6.3 1.79 01/12/22 18:45 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 7.4 1.79 01/12/22 18:45 108-10-1 Methyl-tert-butyl ether ND ug/m3 6.6 1.79 01/12/22 18:45 1634-04-4 Naphthalene ND ug/m3 4.8 1.79 01/12/22 18:45 91-20-3 2-Propanol ND ug/m3 4.5 1.79 01/12/22 18:45 67-63-0 Propylene ND ug/m3 1.6 1.79 01/12/22 18:45 115-07-1 Styrene ND ug/m3 1.6 1.79 01/12/22 18:45 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 2.5 1.79 01/12/22 18:45 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: SSV-7 Lab ID: 10592093007 Collected: 12/15/21 14:35 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 69.1 ug/m3 1.2 1.79 01/12/22 18:45 127-18-4 Tetrahydrofuran ND ug/m3 1.1 1.79 01/12/22 18:45 109-99-9 Toluene ND ug/m3 1.4 1.79 01/12/22 18:45 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 13.5 1.79 01/12/22 18:45 120-82-1 1,1,1-Trichloroethane ND ug/m3 2.0 1.79 01/12/22 18:45 71-55-6 1,1,2-Trichloroethane ND ug/m3 0.99 1.79 01/12/22 18:45 79-00-5 Trichloroethene ND ug/m3 0.98 1.79 01/12/22 18:45 79-01-6 Trichlorofluoromethane ND ug/m3 2.0 1.79 01/12/22 18:45 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 2.8 1.79 01/12/22 18:45 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 1.8 1.79 01/12/22 18:45 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 1.8 1.79 01/12/22 18:45 108-67-8 Vinyl acetate ND ug/m3 1.3 1.79 01/12/22 18:45 108-05-4 Vinyl chloride ND ug/m3 0.47 1.79 01/12/22 18:45 75-01-4 m&p-Xylene ND ug/m3 3.2 1.79 01/12/22 18:45 179601-23-1 o-Xylene ND ug/m3 1.6 1.79 01/12/22 18:45 95-47-6 Date: 01/13/2022 04:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: SSV-8 Lab ID: 10592093008 Collected: 12/15/21 17:07 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone 342 ug/m3 10.8 1.79 01/12/22 22:42 67-64-1 Benzene 2.7 ug/m3 0.58 1.79 01/12/22 22:42 71-43-2 Benzyl chloride ND ug/m3 4.7 1.79 01/12/22 22:42 100-44-7 Bromodichloromethane ND ug/m3 2.4 1.79 01/12/22 22:42 75-27-4 Bromoform ND ug/m3 9.4 1.79 01/12/22 22:42 75-25-2 Bromomethane ND ug/m3 1.4 1.79 01/12/22 22:42 74-83-9 1,3-Butadiene ND ug/m3 0.81 1.79 01/12/22 22:42 106-99-0 2-Butanone (MEK) 8.0 ug/m3 5.4 1.79 01/12/22 22:42 78-93-3 Carbon disulfide ND ug/m3 1.1 1.79 01/12/22 22:42 75-15-0 Carbon tetrachloride ND ug/m3 2.3 1.79 01/12/22 22:42 56-23-5 Chlorobenzene ND ug/m3 1.7 1.79 01/12/22 22:42 108-90-7 Chloroethane ND ug/m3 0.96 1.79 01/12/22 22:42 75-00-3 Chloroform ND ug/m3 0.89 1.79 01/12/22 22:42 67-66-3 Chloromethane 1.2 ug/m3 0.75 1.79 01/12/22 22:42 74-87-3 Cyclohexane ND ug/m3 3.1 1.79 01/12/22 22:42 110-82-7 Dibromochloromethane ND ug/m3 3.1 1.79 01/12/22 22:42 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 1.4 1.79 01/12/22 22:42 106-93-4 1,2-Dichlorobenzene ND ug/m3 5.5 1.79 01/12/22 22:42 95-50-1 1,3-Dichlorobenzene ND ug/m3 5.5 1.79 01/12/22 22:42 541-73-1 1,4-Dichlorobenzene ND ug/m3 5.5 1.79 01/12/22 22:42 106-46-7 Dichlorodifluoromethane 2.8 ug/m3 1.8 1.79 01/12/22 22:42 75-71-8 1,1-Dichloroethane ND ug/m3 1.5 1.79 01/12/22 22:42 75-34-3 1,2-Dichloroethane ND ug/m3 1.5 1.79 01/12/22 22:42 107-06-2 1,1-Dichloroethene ND ug/m3 1.4 1.79 01/12/22 22:42 75-35-4 cis-1,2-Dichloroethene ND ug/m3 1.4 1.79 01/12/22 22:42 156-59-2 trans-1,2-Dichloroethene ND ug/m3 1.4 1.79 01/12/22 22:42 156-60-5 1,2-Dichloropropene ND ug/m3 1.7 1.79 01/12/22 22:42 78-87-5 cis-1,3-Dichloropropene ND ug/m3 4.1 1.79 01/12/22 22:42 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 4.1 1.79 01/12/22 22:42 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 2.5 1.79 01/12/22 22:42 76-14-2 Ethanol 4580 ug/m3 3.4 1.79 01/12/22 22:42 64-17-5 Ethyl acetate 12.3 ug/m3 1.3 1.79 01/12/22 22:42 141-78-6 Ethylbenzene 1.7 ug/m3 1.6 1.79 01/12/22 22:42 100-41-4 4-Ethyltoluene ND ug/m3 4.5 1.79 01/12/22 22:42 622-96-8 n-Heptane ND ug/m3 1.5 1.79 01/12/22 22:42 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 9.7 1.79 01/12/22 22:42 87-68-3 n-Hexane 2.0 ug/m3 1.3 1.79 01/12/22 22:42 110-54-3 2-Hexanone ND ug/m3 7.4 1.79 01/12/22 22:42 591-78-6 Methylene Chloride ND ug/m3 6.3 1.79 01/12/22 22:42 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 7.4 1.79 01/12/22 22:42 108-10-1 Methyl-tert-butyl ether ND ug/m3 6.6 1.79 01/12/22 22:42 1634-04-4 Naphthalene ND ug/m3 4.8 1.79 01/12/22 22:42 91-20-3 2-Propanol 15.2 ug/m3 4.5 1.79 01/12/22 22:42 67-63-0 Propylene 4.4 ug/m3 1.6 1.79 01/12/22 22:42 115-07-1 Styrene 1.7 ug/m3 1.6 1.79 01/12/22 22:42 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 2.5 1.79 01/12/22 22:42 79-34-5 REPORT OF LABORATORY ANALYSIS E This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: SSV-8 Lab ID: 10592093008 Collected: 12/15/21 17:07 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 4.8 ug/m3 1.2 1.79 01/12/22 22:42 127-18-4 Tetrahydrofuran 1.9 ug/m3 1.1 1.79 01/12/22 22:42 109-99-9 Toluene 9.3 ug/m3 1.4 1.79 01/12/22 22:42 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 13.5 1.79 01/12/22 22:42 120-82-1 1,1,1-Trichloroethane ND ug/m3 2.0 1.79 01/12/22 22:42 71-55-6 1,1,2-Trichloroethane ND ug/m3 0.99 1.79 01/12/22 22:42 79-00-5 Trichloroethene ND ug/m3 0.98 1.79 01/12/22 22:42 79-01-6 Trichlorofluoromethane ND ug/m3 2.0 1.79 01/12/22 22:42 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 2.8 1.79 01/12/22 22:42 76-13-1 1,2,4-Trimethylbenzene 2.8 ug/m3 1.8 1.79 01/12/22 22:42 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 1.8 1.79 01/12/22 22:42 108-67-8 Vinyl acetate ND ug/m3 1.3 1.79 01/12/22 22:42 108-05-4 Vinyl chloride ND ug/m3 0.47 1.79 01/12/22 22:42 75-01-4 m&p-Xylene 4.6 ug/m3 3.2 1.79 01/12/22 22:42 179601-23-1 o-Xylene 2.6 ug/m3 1.6 1.79 01/12/22 22:42 95-47-6 Date: 01/13/2022 04:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: SSV-9 Lab ID: 10592093009 Collected: 12/15/21 11:27 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone 771 ug/m3 339 56.1 01/13/2210:58 67-64-1 Benzene ND ug/m3 0.61 1.87 01/12/22 21:01 71-43-2 Benzyl chloride ND ug/m3 4.9 1.87 01/12/22 21:01 100-44-7 Bromodichloromethane ND ug/m3 2.5 1.87 01/12/22 21:01 75-27-4 Bromoform ND ug/m3 9.8 1.87 01/12/22 21:01 75-25-2 Bromomethane ND ug/m3 1.5 1.87 01/12/22 21:01 74-83-9 1,3-Butadiene ND ug/m3 0.84 1.87 01/12/22 21:01 106-99-0 2-Butanone (MEK) 16.6 ug/m3 5.6 1.87 01/12/22 21:01 78-93-3 Carbon disulfide ND ug/m3 1.2 1.87 01/12/22 21:01 75-15-0 Carbon tetrachloride ND ug/m3 2.4 1.87 01/12/22 21:01 56-23-5 Chlorobenzene ND ug/m3 1.8 1.87 01/12/22 21:01 108-90-7 Chloroethane ND ug/m3 1.0 1.87 01/12/22 21:01 75-00-3 Chloroform ND ug/m3 0.93 1.87 01/12/22 21:01 67-66-3 Chloromethane ND ug/m3 0.79 1.87 01/12/22 21:01 74-87-3 Cyclohexane ND ug/m3 3.3 1.87 01/12/22 21:01 110-82-7 Dibromochloromethane ND ug/m3 3.2 1.87 01/12/22 21:01 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 1.5 1.87 01/12/22 21:01 106-93-4 1,2-Dichlorobenzene ND ug/m3 5.7 1.87 01/12/22 21:01 95-50-1 1,3-Dichlorobenzene ND ug/m3 5.7 1.87 01/12/22 21:01 541-73-1 1,4-Dichlorobenzene ND ug/m3 5.7 1.87 01/12/22 21:01 106-46-7 Dichlorodifluoromethane 2.8 ug/m3 1.9 1.87 01/12/22 21:01 75-71-8 1,1-Dichloroethane ND ug/m3 1.5 1.87 01/12/22 21:01 75-34-3 1,2-Dichloroethane ND ug/m3 1.5 1.87 01/12/22 21:01 107-06-2 1,1-Dichloroethene ND ug/m3 1.5 1.87 01/12/22 21:01 75-35-4 cis-1,2-Dichloroethene ND ug/m3 1.5 1.87 01/12/22 21:01 156-59-2 trans-1,2-Dichloroethene ND ug/m3 1.5 1.87 01/12/22 21:01 156-60-5 1,2-Dichloropropene ND ug/m3 1.8 1.87 01/12/22 21:01 78-87-5 cis-1,3-Dichloropropene ND ug/m3 4.3 1.87 01/12/22 21:01 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 4.3 1.87 01/12/22 21:01 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 2.7 1.87 01/12/22 21:01 76-14-2 Ethanol 24800 ug/m3 108 56.1 01/13/2210:58 64-17-5 Ethyl acetate 4.7 ug/m3 1.4 1.87 01/12/22 21:01 141-78-6 Ethylbenzene ND ug/m3 1.7 1.87 01/12/22 21:01 100-41-4 4-Ethyltoluene ND ug/m3 4.7 1.87 01/12/22 21:01 622-96-8 n-Heptane ND ug/m3 1.6 1.87 01/12/22 21:01 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 10.1 1.87 01/12/22 21:01 87-68-3 n-Hexane ND ug/m3 1.3 1.87 01/12/22 21:01 110-54-3 2-Hexanone ND ug/m3 7.8 1.87 01/12/22 21:01 591-78-6 Methylene Chloride ND ug/m3 6.6 1.87 01/12/22 21:01 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 7.8 1.87 01/12/22 21:01 108-10-1 Methyl-tert-butyl ether ND ug/m3 6.8 1.87 01/12/22 21:01 1634-04-4 Naphthalene ND ug/m3 5.0 1.87 01/12/22 21:01 91-20-3 2-Propanol 870 ug/m3 140 56.1 01/13/2210:58 67-63-0 Propylene ND ug/m3 1.6 1.87 01/12/22 21:01 115-07-1 Styrene 1.9 ug/m3 1.6 1.87 01/12/22 21:01 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 2.6 1.87 01/12/22 21:01 79-34-5 REPORT OF LABORATORY ANALYSIS E This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: SSV-9 Lab ID: 10592093009 Collected: 12/15/21 11:27 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 130 ug/m3 1.3 1.87 01/12/22 21:01 127-18-4 Tetrahydrofuran 1.9 ug/m3 1.1 1.87 01/12/22 21:01 109-99-9 Toluene 6.8 ug/m3 1.4 1.87 01/12/22 21:01 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 14.1 1.87 01/12/22 21:01 120-82-1 1,1,1-Trichloroethane ND ug/m3 2.1 1.87 01/12/22 21:01 71-55-6 1,1,2-Trichloroethane ND ug/m3 1.0 1.87 01/12/22 21:01 79-00-5 Trichloroethene ND ug/m3 1.0 1.87 01/12/22 21:01 79-01-6 Trichlorofluoromethane 29.7 ug/m3 2.1 1.87 01/12/22 21:01 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 2.9 1.87 01/12/22 21:01 76-13-1 1,2,4-Trimethylbenzene 18.4 ug/m3 1.9 1.87 01/12/22 21:01 95-63-6 1,3,5-Trimethylbenzene 5.1 ug/m3 1.9 1.87 01/12/22 21:01 108-67-8 Vinyl acetate ND ug/m3 1.3 1.87 01/12/22 21:01 108-05-4 Vinyl chloride ND ug/m3 0.49 1.87 01/12/22 21:01 75-01-4 m&p-Xylene 4.1 ug/m3 3.3 1.87 01/12/22 21:01 179601-23-1 o-Xylene 3.1 ug/m3 1.7 1.87 01/12/22 21:01 95-47-6 Date: 01/13/2022 04:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: SSV-10 Lab ID: 10592093010 Collected: 12/15/21 14:07 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone 494 ug/m3 11.3 1.87 01/12/22 21:35 67-64-1 Benzene ND ug/m3 0.61 1.87 01/12/22 21:35 71-43-2 Benzyl chloride ND ug/m3 4.9 1.87 01/12/22 21:35 100-44-7 Bromodichloromethane ND ug/m3 2.5 1.87 01/12/22 21:35 75-27-4 Bromoform ND ug/m3 9.8 1.87 01/12/22 21:35 75-25-2 Bromomethane ND ug/m3 1.5 1.87 01/12/22 21:35 74-83-9 1,3-Butadiene ND ug/m3 0.84 1.87 01/12/22 21:35 106-99-0 2-Butanone (MEK) 8.9 ug/m3 5.6 1.87 01/12/22 21:35 78-93-3 Carbon disulfide 3.1 ug/m3 1.2 1.87 01/12/22 21:35 75-15-0 Carbon tetrachloride ND ug/m3 2.4 1.87 01/12/22 21:35 56-23-5 Chlorobenzene ND ug/m3 1.8 1.87 01/12/22 21:35 108-90-7 Chloroethane ND ug/m3 1.0 1.87 01/12/22 21:35 75-00-3 Chloroform 1.9 ug/m3 0.93 1.87 01/12/22 21:35 67-66-3 Chloromethane 0.81 ug/m3 0.79 1.87 01/12/22 21:35 74-87-3 Cyclohexane ND ug/m3 3.3 1.87 01/12/22 21:35 110-82-7 Dibromochloromethane ND ug/m3 3.2 1.87 01/12/22 21:35 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 1.5 1.87 01/12/22 21:35 106-93-4 1,2-Dichlorobenzene ND ug/m3 5.7 1.87 01/12/22 21:35 95-50-1 1,3-Dichlorobenzene ND ug/m3 5.7 1.87 01/12/22 21:35 541-73-1 1,4-Dichlorobenzene ND ug/m3 5.7 1.87 01/12/22 21:35 106-46-7 Dichlorodifluoromethane 2.8 ug/m3 1.9 1.87 01/12/22 21:35 75-71-8 1,1-Dichloroethane ND ug/m3 1.5 1.87 01/12/22 21:35 75-34-3 1,2-Dichloroethane ND ug/m3 1.5 1.87 01/12/22 21:35 107-06-2 1,1-Dichloroethene ND ug/m3 1.5 1.87 01/12/22 21:35 75-35-4 cis-1,2-Dichloroethene ND ug/m3 1.5 1.87 01/12/22 21:35 156-59-2 trans-1,2-Dichloroethene ND ug/m3 1.5 1.87 01/12/22 21:35 156-60-5 1,2-Dichloropropene ND ug/m3 1.8 1.87 01/12/22 21:35 78-87-5 cis-1,3-Dichloropropene ND ug/m3 4.3 1.87 01/12/22 21:35 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 4.3 1.87 01/12/22 21:35 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 2.7 1.87 01/12/22 21:35 76-14-2 Ethanol 22700 ug/m3 108 56.1 01/13/2211:29 64-17-5 Ethyl acetate 17.4 ug/m3 1.4 1.87 01/12/22 21:35 141-78-6 Ethylbenzene ND ug/m3 1.7 1.87 01/12/22 21:35 100-41-4 4-Ethyltoluene ND ug/m3 4.7 1.87 01/12/22 21:35 622-96-8 n-Heptane ND ug/m3 1.6 1.87 01/12/22 21:35 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 10.1 1.87 01/12/22 21:35 87-68-3 n-Hexane ND ug/m3 1.3 1.87 01/12/22 21:35 110-54-3 2-Hexanone ND ug/m3 7.8 1.87 01/12/22 21:35 591-78-6 Methylene Chloride ND ug/m3 6.6 1.87 01/12/22 21:35 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 7.8 1.87 01/12/22 21:35 108-10-1 Methyl-tert-butyl ether ND ug/m3 6.8 1.87 01/12/22 21:35 1634-04-4 Naphthalene ND ug/m3 5.0 1.87 01/12/22 21:35 91-20-3 2-Propanol 2690 ug/m3 140 56.1 01/13/2211:29 67-63-0 Propylene ND ug/m3 1.6 1.87 01/12/22 21:35 115-07-1 Styrene ND ug/m3 1.6 1.87 01/12/22 21:35 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 2.6 1.87 01/12/22 21:35 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: SSV-10 Lab ID: 10592093010 Collected: 12/15/21 14:07 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 177 ug/m3 1.3 1.87 01/12/22 21:35 127-18-4 Tetrahydrofuran ND ug/m3 1.1 1.87 01/12/22 21:35 109-99-9 Toluene 6.2 ug/m3 1.4 1.87 01/12/22 21:35 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 14.1 1.87 01/12/22 21:35 120-82-1 1,1,1-Trichloroethane ND ug/m3 2.1 1.87 01/12/22 21:35 71-55-6 1,1,2-Trichloroethane ND ug/m3 1.0 1.87 01/12/22 21:35 79-00-5 Trichloroethene ND ug/m3 1.0 1.87 01/12/22 21:35 79-01-6 Trichlorofluoromethane 38.5 ug/m3 2.1 1.87 01/12/22 21:35 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 2.9 1.87 01/12/22 21:35 76-13-1 1,2,4-Trimethylbenzene 5.2 ug/m3 1.9 1.87 01/12/22 21:35 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 1.9 1.87 01/12/22 21:35 108-67-8 Vinyl acetate ND ug/m3 1.3 1.87 01/12/22 21:35 108-05-4 Vinyl chloride ND ug/m3 0.49 1.87 01/12/22 21:35 75-01-4 m&p-Xylene ND ug/m3 3.3 1.87 01/12/22 21:35 179601-23-1 o-Xylene 2.4 ug/m3 1.7 1.87 01/12/22 21:35 95-47-6 Date: 01/13/2022 04:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: SSV-11 Lab ID: 10592093011 Collected: 12/15/21 15:20 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone 40.5 ug/m3 11.8 1.96 01/12/22 19:53 67-64-1 Benzene ND ug/m3 0.64 1.96 01/12/22 19:53 71-43-2 Benzyl chloride ND ug/m3 5.2 1.96 01/12/22 19:53 100-44-7 Bromodichloromethane ND ug/m3 2.7 1.96 01/12/22 19:53 75-27-4 Bromoform ND ug/m3 10.3 1.96 01/12/22 19:53 75-25-2 Bromomethane ND ug/m3 1.5 1.96 01/12/22 19:53 74-83-9 1,3-Butadiene ND ug/m3 0.88 1.96 01/12/22 19:53 106-99-0 2-Butanone (MEK) ND ug/m3 5.9 1.96 01/12/22 19:53 78-93-3 Carbon disulfide ND ug/m3 1.2 1.96 01/12/22 19:53 75-15-0 Carbon tetrachloride ND ug/m3 2.5 1.96 01/12/22 19:53 56-23-5 Chlorobenzene ND ug/m3 1.8 1.96 01/12/22 19:53 108-90-7 Chloroethane ND ug/m3 1.1 1.96 01/12/22 19:53 75-00-3 Chloroform 1.7 ug/m3 0.97 1.96 01/12/22 19:53 67-66-3 Chloromethane ND ug/m3 0.82 1.96 01/12/22 19:53 74-87-3 Cyclohexane ND ug/m3 3.4 1.96 01/12/22 19:53 110-82-7 Dibromochloromethane ND ug/m3 3.4 1.96 01/12/22 19:53 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 1.5 1.96 01/12/22 19:53 106-93-4 1,2-Dichlorobenzene ND ug/m3 6.0 1.96 01/12/22 19:53 95-50-1 1,3-Dichlorobenzene ND ug/m3 6.0 1.96 01/12/22 19:53 541-73-1 1,4-Dichlorobenzene ND ug/m3 6.0 1.96 01/12/22 19:53 106-46-7 Dichlorodifluoromethane 2.6 ug/m3 2.0 1.96 01/12/22 19:53 75-71-8 1,1-Dichloroethane ND ug/m3 1.6 1.96 01/12/22 19:53 75-34-3 1,2-Dichloroethane ND ug/m3 1.6 1.96 01/12/22 19:53 107-06-2 1,1-Dichloroethene ND ug/m3 1.6 1.96 01/12/22 19:53 75-35-4 cis-1,2-Dichloroethene 47.3 ug/m3 1.6 1.96 01/12/22 19:53 156-59-2 trans-1,2-Dichloroethene 2.6 ug/m3 1.6 1.96 01/12/22 19:53 156-60-5 1,2-Dichloropropene ND ug/m3 1.8 1.96 01/12/22 19:53 78-87-5 cis-1,3-Dichloropropene ND ug/m3 4.5 1.96 01/12/22 19:53 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 4.5 1.96 01/12/22 19:53 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 2.8 1.96 01/12/22 19:53 76-14-2 Ethanol 748 ug/m3 3.8 1.96 01/12/22 19:53 64-17-5 Ethyl acetate ND ug/m3 1.4 1.96 01/12/22 19:53 141-78-6 Ethylbenzene ND ug/m3 1.7 1.96 01/12/22 19:53 100-41-4 4-Ethyltoluene ND ug/m3 4.9 1.96 01/12/22 19:53 622-96-8 n-Heptane ND ug/m3 1.6 1.96 01/12/22 19:53 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 10.6 1.96 01/12/22 19:53 87-68-3 n-Hexane ND ug/m3 1.4 1.96 01/12/22 19:53 110-54-3 2-Hexanone ND ug/m3 8.2 1.96 01/12/22 19:53 591-78-6 Methylene Chloride ND ug/m3 6.9 1.96 01/12/22 19:53 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 8.2 1.96 01/12/22 19:53 108-10-1 Methyl-tert-butyl ether ND ug/m3 7.2 1.96 01/12/22 19:53 1634-04-4 Naphthalene ND ug/m3 5.2 1.96 01/12/22 19:53 91-20-3 2-Propanol 23.4 ug/m3 4.9 1.96 01/12/22 19:53 67-63-0 Propylene ND ug/m3 1.7 1.96 01/12/22 19:53 115-07-1 Styrene ND ug/m3 1.7 1.96 01/12/22 19:53 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 2.7 1.96 01/12/22 19:53 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: SSV-11 Lab ID: 10592093011 Collected: 12/15/21 15:20 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 46.5 ug/m3 1.4 1.96 01/12/22 19:53 127-18-4 Tetrahydrofuran ND ug/m3 1.2 1.96 01/12/22 19:53 109-99-9 Toluene ND ug/m3 1.5 1.96 01/12/22 19:53 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 14.8 1.96 01/12/22 19:53 120-82-1 1,1,1-Trichloroethane ND ug/m3 2.2 1.96 01/12/22 19:53 71-55-6 1,1,2-Trichloroethane ND ug/m3 1.1 1.96 01/12/22 19:53 79-00-5 Trichloroethene 2.3 ug/m3 1.1 1.96 01/12/22 19:53 79-01-6 Trichlorofluoromethane 2.6 ug/m3 2.2 1.96 01/12/22 19:53 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 3.1 1.96 01/12/22 19:53 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 2.0 1.96 01/12/22 19:53 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 2.0 1.96 01/12/22 19:53 108-67-8 Vinyl acetate ND ug/m3 1.4 1.96 01/12/22 19:53 108-05-4 Vinyl chloride ND ug/m3 0.51 1.96 01/12/22 19:53 75-01-4 m&p-Xylene ND ug/m3 3.5 1.96 01/12/22 19:53 179601-23-1 o-Xylene ND ug/m3 1.7 1.96 01/12/22 19:53 95-47-6 Date: 01/13/2022 04:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 26 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: SSV-11 DUP Lab ID: 10592093012 Collected: 12/15/21 15:20 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone 64.0 ug/m3 11.8 1.96 01/12/22 22:08 67-64-1 Benzene ND ug/m3 0.64 1.96 01/12/22 22:08 71-43-2 Benzyl chloride ND ug/m3 5.2 1.96 01/12/22 22:08 100-44-7 Bromodichloromethane ND ug/m3 2.7 1.96 01/12/22 22:08 75-27-4 Bromoform ND ug/m3 10.3 1.96 01/12/22 22:08 75-25-2 Bromomethane ND ug/m3 1.5 1.96 01/12/22 22:08 74-83-9 1,3-Butadiene ND ug/m3 0.88 1.96 01/12/22 22:08 106-99-0 2-Butanone (MEK) 9.7 ug/m3 5.9 1.96 01/12/22 22:08 78-93-3 Carbon disulfide ND ug/m3 1.2 1.96 01/12/22 22:08 75-15-0 Carbon tetrachloride ND ug/m3 2.5 1.96 01/12/22 22:08 56-23-5 Chlorobenzene ND ug/m3 1.8 1.96 01/12/22 22:08 108-90-7 Chloroethane ND ug/m3 1.1 1.96 01/12/22 22:08 75-00-3 Chloroform 1.9 ug/m3 0.97 1.96 01/12/22 22:08 67-66-3 Chloromethane ND ug/m3 0.82 1.96 01/12/22 22:08 74-87-3 Cyclohexane ND ug/m3 3.4 1.96 01/12/22 22:08 110-82-7 Dibromochloromethane ND ug/m3 3.4 1.96 01/12/22 22:08 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 1.5 1.96 01/12/22 22:08 106-93-4 1,2-Dichlorobenzene ND ug/m3 6.0 1.96 01/12/22 22:08 95-50-1 1,3-Dichlorobenzene ND ug/m3 6.0 1.96 01/12/22 22:08 541-73-1 1,4-Dichlorobenzene ND ug/m3 6.0 1.96 01/12/22 22:08 106-46-7 Dichlorodifluoromethane 2.9 ug/m3 2.0 1.96 01/12/22 22:08 75-71-8 1,1-Dichloroethane ND ug/m3 1.6 1.96 01/12/22 22:08 75-34-3 1,2-Dichloroethane ND ug/m3 1.6 1.96 01/12/22 22:08 107-06-2 1,1-Dichloroethene ND ug/m3 1.6 1.96 01/12/22 22:08 75-35-4 cis-1,2-Dichloroethene 52.7 ug/m3 1.6 1.96 01/12/22 22:08 156-59-2 trans-1,2-Dichloroethene 2.8 ug/m3 1.6 1.96 01/12/22 22:08 156-60-5 1,2-Dichloropropene ND ug/m3 1.8 1.96 01/12/22 22:08 78-87-5 cis-1,3-Dichloropropene ND ug/m3 4.5 1.96 01/12/22 22:08 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 4.5 1.96 01/12/22 22:08 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 2.8 1.96 01/12/22 22:08 76-14-2 Ethanol 873 ug/m3 3.8 1.96 01/12/22 22:08 64-17-5 Ethyl acetate ND ug/m3 1.4 1.96 01/12/22 22:08 141-78-6 Ethylbenzene ND ug/m3 1.7 1.96 01/12/22 22:08 100-41-4 4-Ethyltoluene ND ug/m3 4.9 1.96 01/12/22 22:08 622-96-8 n-Heptane ND ug/m3 1.6 1.96 01/12/22 22:08 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 10.6 1.96 01/12/22 22:08 87-68-3 n-Hexane 1.7 ug/m3 1.4 1.96 01/12/22 22:08 110-54-3 2-Hexanone ND ug/m3 8.2 1.96 01/12/22 22:08 591-78-6 Methylene Chloride ND ug/m3 6.9 1.96 01/12/22 22:08 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 8.2 1.96 01/12/22 22:08 108-10-1 Methyl-tert-butyl ether ND ug/m3 7.2 1.96 01/12/22 22:08 1634-04-4 Naphthalene ND ug/m3 5.2 1.96 01/12/22 22:08 91-20-3 2-Propanol 28.9 ug/m3 4.9 1.96 01/12/22 22:08 67-63-0 Propylene ND ug/m3 1.7 1.96 01/12/22 22:08 115-07-1 Styrene ND ug/m3 1.7 1.96 01/12/22 22:08 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 2.7 1.96 01/12/22 22:08 79-34-5 REPORT OF LABORATORY ANALYSIS E This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: SSV-11 DUP Lab ID: 10592093012 Collected: 12/15/21 15:20 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 52.9 ug/m3 1.4 1.96 01/12/22 22:08 127-18-4 Tetrahydrofuran ND ug/m3 1.2 1.96 01/12/22 22:08 109-99-9 Toluene ND ug/m3 1.5 1.96 01/12/22 22:08 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 14.8 1.96 01/12/22 22:08 120-82-1 1,1,1-Trichloroethane ND ug/m3 2.2 1.96 01/12/22 22:08 71-55-6 1,1,2-Trichloroethane ND ug/m3 1.1 1.96 01/12/22 22:08 79-00-5 Trichloroethene 2.5 ug/m3 1.1 1.96 01/12/22 22:08 79-01-6 Trichlorofluoromethane 2.5 ug/m3 2.2 1.96 01/12/22 22:08 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 3.1 1.96 01/12/22 22:08 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 2.0 1.96 01/12/22 22:08 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 2.0 1.96 01/12/22 22:08 108-67-8 Vinyl acetate ND ug/m3 1.4 1.96 01/12/22 22:08 108-05-4 Vinyl chloride ND ug/m3 0.51 1.96 01/12/22 22:08 75-01-4 m&p-Xylene ND ug/m3 3.5 1.96 01/12/22 22:08 179601-23-1 o-Xylene ND ug/m3 1.7 1.96 01/12/22 22:08 95-47-6 Date: 01/13/2022 04:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: CS-12 Lab ID: 10592093013 Collected: 12/15/21 16:55 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone ND ug/m3 11.3 1.87 01/12/22 20:27 67-64-1 Benzene 1.5 ug/m3 0.61 1.87 01/12/22 20:27 71-43-2 Benzyl chloride ND ug/m3 4.9 1.87 01/12/22 20:27 100-44-7 Bromodichloromethane ND ug/m3 2.5 1.87 01/12/22 20:27 75-27-4 Bromoform ND ug/m3 9.8 1.87 01/12/22 20:27 75-25-2 Bromomethane ND ug/m3 1.5 1.87 01/12/22 20:27 74-83-9 1,3-Butadiene ND ug/m3 0.84 1.87 01/12/22 20:27 106-99-0 2-Butanone (MEK) ND ug/m3 5.6 1.87 01/12/22 20:27 78-93-3 Carbon disulfide ND ug/m3 1.2 1.87 01/12/22 20:27 75-15-0 Carbon tetrachloride ND ug/m3 2.4 1.87 01/12/22 20:27 56-23-5 Chlorobenzene ND ug/m3 1.8 1.87 01/12/22 20:27 108-90-7 Chloroethane ND ug/m3 1.0 1.87 01/12/22 20:27 75-00-3 Chloroform ND ug/m3 0.93 1.87 01/12/22 20:27 67-66-3 Chloromethane 1.2 ug/m3 0.79 1.87 01/12/22 20:27 74-87-3 Cyclohexane ND ug/m3 3.3 1.87 01/12/22 20:27 110-82-7 Dibromochloromethane ND ug/m3 3.2 1.87 01/12/22 20:27 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 1.5 1.87 01/12/22 20:27 106-93-4 1,2-Dichlorobenzene ND ug/m3 5.7 1.87 01/12/22 20:27 95-50-1 1,3-Dichlorobenzene ND ug/m3 5.7 1.87 01/12/22 20:27 541-73-1 1,4-Dichlorobenzene ND ug/m3 5.7 1.87 01/12/22 20:27 106-46-7 Dichlorodifluoromethane 3.0 ug/m3 1.9 1.87 01/12/22 20:27 75-71-8 1,1-Dichloroethane ND ug/m3 1.5 1.87 01/12/22 20:27 75-34-3 1,2-Dichloroethane ND ug/m3 1.5 1.87 01/12/22 20:27 107-06-2 1,1-Dichloroethene ND ug/m3 1.5 1.87 01/12/22 20:27 75-35-4 cis-1,2-Dichloroethene ND ug/m3 1.5 1.87 01/12/22 20:27 156-59-2 trans-1,2-Dichloroethene ND ug/m3 1.5 1.87 01/12/22 20:27 156-60-5 1,2-Dichloropropene ND ug/m3 1.8 1.87 01/12/22 20:27 78-87-5 cis-1,3-Dichloropropene ND ug/m3 4.3 1.87 01/12/22 20:27 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 4.3 1.87 01/12/22 20:27 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 2.7 1.87 01/12/22 20:27 76-14-2 Ethanol 33.2 ug/m3 3.6 1.87 01/12/22 20:27 64-17-5 Ethyl acetate ND ug/m3 1.4 1.87 01/12/22 20:27 141-78-6 Ethylbenzene ND ug/m3 1.7 1.87 01/12/22 20:27 100-41-4 4-Ethyltoluene ND ug/m3 4.7 1.87 01/12/22 20:27 622-96-8 n-Heptane ND ug/m3 1.6 1.87 01/12/22 20:27 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 10.1 1.87 01/12/22 20:27 87-68-3 n-Hexane ND ug/m3 1.3 1.87 01/12/22 20:27 110-54-3 2-Hexanone ND ug/m3 7.8 1.87 01/12/22 20:27 591-78-6 Methylene Chloride ND ug/m3 6.6 1.87 01/12/22 20:27 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 7.8 1.87 01/12/22 20:27 108-10-1 Methyl-tert-butyl ether ND ug/m3 6.8 1.87 01/12/22 20:27 1634-04-4 Naphthalene ND ug/m3 5.0 1.87 01/12/22 20:27 91-20-3 2-Propanol ND ug/m3 4.7 1.87 01/12/22 20:27 67-63-0 Propylene ND ug/m3 1.6 1.87 01/12/22 20:27 115-07-1 Styrene ND ug/m3 1.6 1.87 01/12/22 20:27 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 2.6 1.87 01/12/22 20:27 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: CS-12 Lab ID: 10592093013 Collected: 12/15/21 16:55 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 381 ug/m3 1.3 1.87 01/12/22 20:27 127-18-4 Tetrahydrofuran ND ug/m3 1.1 1.87 01/12/22 20:27 109-99-9 Toluene 2.0 ug/m3 1.4 1.87 01/12/22 20:27 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 14.1 1.87 01/12/22 20:27 120-82-1 1,1,1-Trichloroethane ND ug/m3 2.1 1.87 01/12/22 20:27 71-55-6 1,1,2-Trichloroethane ND ug/m3 1.0 1.87 01/12/22 20:27 79-00-5 Trichloroethene ND ug/m3 1.0 1.87 01/12/22 20:27 79-01-6 Trichlorofluoromethane ND ug/m3 2.1 1.87 01/12/22 20:27 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 2.9 1.87 01/12/22 20:27 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 1.9 1.87 01/12/22 20:27 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 1.9 1.87 01/12/22 20:27 108-67-8 Vinyl acetate ND ug/m3 1.3 1.87 01/12/22 20:27 108-05-4 Vinyl chloride ND ug/m3 0.49 1.87 01/12/22 20:27 75-01-4 m&p-Xylene ND ug/m3 3.3 1.87 01/12/22 20:27 179601-23-1 o-Xylene ND ug/m3 1.7 1.87 01/12/22 20:27 95-47-6 Date: 01/13/2022 04:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 30 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: CS-13 Lab ID: 10592093014 Collected: 12/15/21 16:55 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone ND ug/m3 11.6 1.92 01/12/22 23:16 67-64-1 Benzene 1.5 ug/m3 0.62 1.92 01/12/22 23:16 71-43-2 Benzyl chloride ND ug/m3 5.0 1.92 01/12/22 23:16 100-44-7 Bromodichloromethane ND ug/m3 2.6 1.92 01/12/22 23:16 75-27-4 Bromoform ND ug/m3 10.1 1.92 01/12/22 23:16 75-25-2 Bromomethane ND ug/m3 1.5 1.92 01/12/22 23:16 74-83-9 1,3-Butadiene ND ug/m3 0.86 1.92 01/12/22 23:16 106-99-0 2-Butanone (MEK) ND ug/m3 5.8 1.92 01/12/22 23:16 78-93-3 Carbon disulfide ND ug/m3 1.2 1.92 01/12/22 23:16 75-15-0 Carbon tetrachloride ND ug/m3 2.5 1.92 01/12/22 23:16 56-23-5 Chlorobenzene ND ug/m3 1.8 1.92 01/12/22 23:16 108-90-7 Chloroethane ND ug/m3 1.0 1.92 01/12/22 23:16 75-00-3 Chloroform ND ug/m3 0.95 1.92 01/12/22 23:16 67-66-3 Chloromethane 1.0 ug/m3 0.81 1.92 01/12/22 23:16 74-87-3 Cyclohexane ND ug/m3 3.4 1.92 01/12/22 23:16 110-82-7 Dibromochloromethane ND ug/m3 3.3 1.92 01/12/22 23:16 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 1.5 1.92 01/12/22 23:16 106-93-4 1,2-Dichlorobenzene ND ug/m3 5.9 1.92 01/12/22 23:16 95-50-1 1,3-Dichlorobenzene ND ug/m3 5.9 1.92 01/12/22 23:16 541-73-1 1,4-Dichlorobenzene ND ug/m3 5.9 1.92 01/12/22 23:16 106-46-7 Dichlorodifluoromethane 2.8 ug/m3 1.9 1.92 01/12/22 23:16 75-71-8 1,1-Dichloroethane ND ug/m3 1.6 1.92 01/12/22 23:16 75-34-3 1,2-Dichloroethane ND ug/m3 1.6 1.92 01/12/22 23:16 107-06-2 1,1-Dichloroethene ND ug/m3 1.5 1.92 01/12/22 23:16 75-35-4 cis-1,2-Dichloroethene ND ug/m3 1.5 1.92 01/12/22 23:16 156-59-2 trans-1,2-Dichloroethene ND ug/m3 1.5 1.92 01/12/22 23:16 156-60-5 1,2-Dichloropropene ND ug/m3 1.8 1.92 01/12/22 23:16 78-87-5 cis-1,3-Dichloropropene ND ug/m3 4.4 1.92 01/12/22 23:16 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 4.4 1.92 01/12/22 23:16 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 2.7 1.92 01/12/22 23:16 76-14-2 Ethanol 74.8 ug/m3 3.7 1.92 01/12/22 23:16 64-17-5 Ethyl acetate ND ug/m3 1.4 1.92 01/12/22 23:16 141-78-6 Ethylbenzene ND ug/m3 1.7 1.92 01/12/22 23:16 100-41-4 4-Ethyltoluene ND ug/m3 4.8 1.92 01/12/22 23:16 622-96-8 n-Heptane ND ug/m3 1.6 1.92 01/12/22 23:16 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 10.4 1.92 01/12/22 23:16 87-68-3 n-Hexane ND ug/m3 1.4 1.92 01/12/22 23:16 110-54-3 2-Hexanone ND ug/m3 8.0 1.92 01/12/22 23:16 591-78-6 Methylene Chloride ND ug/m3 6.8 1.92 01/12/22 23:16 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 8.0 1.92 01/12/22 23:16 108-10-1 Methyl-tert-butyl ether ND ug/m3 7.0 1.92 01/12/22 23:16 1634-04-4 Naphthalene ND ug/m3 5.1 1.92 01/12/22 23:16 91-20-3 2-Propanol ND ug/m3 4.8 1.92 01/12/22 23:16 67-63-0 Propylene ND ug/m3 1.7 1.92 01/12/22 23:16 115-07-1 Styrene ND ug/m3 1.7 1.92 01/12/22 23:16 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 2.7 1.92 01/12/22 23:16 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 ANALYTICAL RESULTS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Sample: CS-13 Lab ID: 10592093014 Collected: 12/15/21 16:55 Received: 12/20/21 10:09 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 76.0 ug/m3 1.3 1.92 01/12/22 23:16 127-18-4 Tetrahydrofuran ND ug/m3 1.2 1.92 01/12/22 23:16 109-99-9 Toluene 2.2 ug/m3 1.5 1.92 01/12/22 23:16 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 14.5 1.92 01/12/22 23:16 120-82-1 1,1,1-Trichloroethane ND ug/m3 2.1 1.92 01/12/22 23:16 71-55-6 1,1,2-Trichloroethane ND ug/m3 1.1 1.92 01/12/22 23:16 79-00-5 Trichloroethene ND ug/m3 1.0 1.92 01/12/22 23:16 79-01-6 Trichlorofluoromethane ND ug/m3 2.2 1.92 01/12/22 23:16 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 3.0 1.92 01/12/22 23:16 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 1.9 1.92 01/12/22 23:16 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 1.9 1.92 01/12/22 23:16 108-67-8 Vinyl acetate ND ug/m3 1.4 1.92 01/12/22 23:16 108-05-4 Vinyl chloride ND ug/m3 0.50 1.92 01/12/22 23:16 75-01-4 m&p-Xylene ND ug/m3 3.4 1.92 01/12/22 23:16 179601-23-1 o-Xylene ND ug/m3 1.7 1.92 01/12/22 23:16 95-47-6 Date: 01/13/2022 04:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 32 of 44 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 QUALITY CONTROL DATA Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 QC Batch: 793334 Analysis Method: TO-15 QC Batch Method: TO-15 Analysis Description: T015 MSV AIR Low Level Laboratory: Pace Analytical Services - Minneapolis Associated Lab Samples: 10592093001, 10592093002, 10592093003, 10592093004, 10592093005, 10592093006, 10592093007, 10592093008,10592093009,10592093010,10592093011,10592093012,10592093013,10592093014 METHOD BLANK: 4219896 Matrix: Air Associated Lab Samples: 10592093001, 10592093002, 10592093003, 10592093004, 10592093005, 10592093006, 10592093007, 10592093008,10592093009,10592093010,10592093011,10592093012,10592093013,10592093014 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1-Trichloroethane ug/m3 ND 1.1 01/12/22 10:10 1,1,2,2-Tetrachloroethane ug/m3 ND 1.4 01/12/22 10:10 1,1,2-Trichloroethane ug/m3 ND 0.56 01/12/22 10:10 1,1,2-Trichlorotrifluoroethane ug/m3 ND 1.6 01/12/22 10:10 1,1-Dichloroethane ug/m3 ND 0.82 01/12/22 10:10 1,1-Dichloroethene ug/m3 ND 0.81 01/12/22 10:10 1,2,4-Trichlorobenzene ug/m3 ND 7.5 01/12/22 10:10 1,2,4-Trimethylbenzene ug/m3 ND 1.0 01/12/22 10:10 1,2-Dibromoethane (EDB) ug/m3 ND 0.78 01/12/22 10:10 1,2-Dichlorobenzene ug/m3 ND 3.1 01/12/22 10:10 1,2-Dichloroethane ug/m3 ND 0.82 01/12/22 10:10 1,2-Dichloropropane ug/m3 ND 0.94 01/12/22 10:10 1,3,5-Trimethylbenzene ug/m3 ND 1.0 01/12/22 10:10 1,3-Butadiene ug/m3 ND 0.45 01/12/22 10:10 1,3-Dichlorobenzene ug/m3 ND 3.1 01/12/22 10:10 1,4-Dichlorobenzene ug/m3 ND 3.1 01/12/22 10:10 2-Butanone (MEK) ug/m3 ND 3.0 01/12/22 10:10 2-Hexanone ug/m3 ND 4.2 01/12/22 10:10 2-Propanol ug/m3 ND 2.5 01/12/22 10:10 4-Ethyltoluene ug/m3 ND 2.5 01/12/22 10:10 4-Methyl-2-pentanone (MIBK) ug/m3 ND 4.2 01/12/22 10:10 Acetone ug/m3 ND 6.0 01/12/22 10:10 Benzene ug/m3 ND 0.32 01/12/22 10:10 Benzyl chloride ug/m3 ND 2.6 01/12/22 10:10 Bromodichloromethane ug/m3 ND 1.4 01/12/22 10:10 Bromoform ug/m3 ND 5.2 01/12/22 10:10 Bromomethane ug/m3 ND 0.79 01/12/22 10:10 Carbon disulfide ug/m3 ND 0.63 01/12/22 10:10 Carbon tetrachloride ug/m3 ND 1.3 01/12/22 10:10 Chlorobenzene ug/m3 ND 0.94 01/12/22 10:10 Chloroethane ug/m3 ND 0.54 01/12/22 10:10 Chloroform ug/m3 ND 0.50 01/12/22 10:10 Chloromethane ug/m3 ND 0.42 01/12/22 10:10 cis-1,2-Dichloroethene ug/m3 ND 0.81 01/12/22 10:10 cis-1,3-Dichloropropene ug/m3 ND 2.3 01/12/22 10:10 Cyclohexane ug/m3 ND 1.8 01/12/22 10:10 Dibromochloromethane ug/m3 ND 1.7 01/12/22 10:10 Dichlorodifluoromethane ug/m3 ND 1.0 01/12/22 10:10 Dichlorotetrafluoroethane ug/m3 ND 1.4 01/12/22 10:10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 44 lV1.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 QUALITY CONTROL DATA Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 METHOD BLANK: 4219896 Matrix: Air Associated Lab Samples: 10592093001, 10592093002, 10592093003, 10592093004, 10592093005, 10592093006, 10592093007, 10592093008,10592093009,10592093010,10592093011,10592093012,10592093013,10592093014 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Ethanol ug/m3 ND 1.9 01/12/22 10:10 Ethyl acetate ug/m3 ND 0.73 01/12/22 10:10 Ethylbenzene ug/m3 ND 0.88 01/12/22 10:10 Hexachloro-1,3-butadiene ug/m3 ND 5.4 01/12/22 10:10 m&p-Xylene ug/m3 ND 1.8 01/12/22 10:10 Methyl-tert-butyl ether ug/m3 ND 3.7 01/12/22 10:10 Methylene Chloride ug/m3 ND 3.5 01/12/22 10:10 n-Heptane ug/m3 ND 0.83 01/12/22 10:10 n-Hexane ug/m3 ND 0.72 01/12/22 10:10 Naphthalene ug/m3 ND 2.7 01/12/22 10:10 o-Xylene ug/m3 ND 0.88 01/12/22 10:10 Propylene ug/m3 ND 0.88 01/12/22 10:10 Styrene ug/m3 ND 0.87 01/12/22 10:10 Tetrachloroethene ug/m3 ND 0.69 01/12/22 10:10 Tetrahydrofuran ug/m3 ND 0.60 01/12/22 10:10 Toluene ug/m3 ND 0.77 01/12/22 10:10 trans-1,2-Dichloroethene ug/m3 ND 0.81 01/12/22 10:10 trans- 1,3-Dichloropropene ug/m3 ND 2.3 01/12/22 10:10 Trichloroethene ug/m3 ND 0.55 01/12/22 10:10 Trichlorofluoromethane ug/m3 ND 1.1 01/12/22 10:10 Vinyl acetate ug/m3 ND 0.72 01/12/22 10:10 Vinyl chloride ug/m3 ND 0.26 01/12/22 10:10 LABORATORY CONTROL SAMPLE: Parameter 4219897 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1-Trichloroethane ug/m3 59.3 69.3 117 70-130 1,1,2,2-Tetrachloroethane ug/m3 75.4 86.4 115 70-132 1,1,2-Trichloroethane ug/m3 59.6 71.6 120 70-131 1,1,2-Trichlorotrifluoroethane ug/m3 83.6 95.6 114 70-130 1,1-Dichloroethane ug/m3 43.9 51.0 116 70-130 1,1-Dichloroethene ug/m3 43.5 51.7 119 70-130 1,2,4-Trichlorobenzene ug/m3 177 172 97 70-130 1,2,4-Trimethylbenzene ug/m3 54 60.6 112 70-137 1,2-Dibromoethane (EDB) ug/m3 82.5 93.6 114 70-137 1,2-Dichlorobenzene ug/m3 66.2 69.7 105 70-131 1,2-Dichloroethane ug/m3 44.4 51.8 117 70-134 1,2-Dichloropropane ug/m3 50.6 59.3 117 70-130 1,3,5-Trimethylbenzene ug/m3 53.7 60.8 113 70-131 1,3-Butadiene ug/m3 24.2 28.3 117 70-139 1,3-Dichlorobenzene ug/m3 66.3 69.3 104 70-134 1,4-Dichlorobenzene ug/m3 66.3 66.5 100 70-131 2-Butanone (MEK) ug/m3 32.3 35.4 110 70-133 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 LABORATORY CONTROL SAMPLE: 4219897 Parameter QUALITY CONTROL DATA Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 2-Hexanone ug/m3 44.8 50.1 112 70-136 2-Propanol ug/m3 149 168 113 65-133 4-Ethyltoluene ug/m3 53.7 60.7 113 70-130 4-Methyl-2-pentanone (MIBK) ug/m3 44.9 53.9 120 70-130 Acetone ug/m3 128 154 121 60-134 Benzene ug/m3 34.8 39.0 112 70-130 Benzyl chloride ug/m3 57.6 57.7 100 70-130 Bromodichloromethane ug/m3 73.1 86.4 118 70-130 Bromoform ug/m3 114 154 136 70-138 CH Bromomethane ug/m3 42.5 48.4 114 68-131 Carbon disulfide ug/m3 34.4 39.1 114 70-130 Carbon tetrachloride ug/m3 69.4 83.1 120 70-132 Chlorobenzene ug/m3 50.2 59.1 118 70-130 Chloroethane ug/m3 28.8 33.2 115 70-134 Chloroform ug/m3 52.4 60.1 115 70-130 Chloromethane ug/m3 22.6 25.8 114 68-131 cis-1,2-Dichloroethene ug/m3 43.4 50.7 117 70-136 cis-1,3-Dichloropropene ug/m3 49.4 54.0 109 70-130 Cyclohexane ug/m3 37.4 45.6 122 70-131 Dibromochloromethane ug/m3 93.2 113 121 70-134 Dichlorodifluoromethane ug/m3 54.6 62.2 114 70-130 Dichlorotetrafluoroethane ug/m3 71.2 81.4 114 70-130 Ethanol ug/m3 124 138 112 55-145 Ethyl acetate ug/m3 38.9 45.3 117 70-135 Ethylbenzene ug/m3 47.8 60.8 127 70-133 Hexachloro-1,3-butadiene ug/m3 133 139 104 70-132 m&p-Xylene ug/m3 95.4 110 115 70-134 Methyl-tert-butyl ether ug/m3 39.6 48.3 122 70-131 Methylene Chloride ug/m3 190 210 110 65-132 n-Heptane ug/m3 44.6 54.3 122 70-130 n-Hexane ug/m3 38 42.4 111 70-132 Naphthalene ug/m3 65.2 59.4 91 70-130 o-Xylene ug/m3 47.6 55.6 117 70-134 Propylene ug/m3 18.9 21.1 112 69-133 Styrene ug/m3 47 53.3 114 70-135 Tetrachloroethene ug/m3 73.4 84.7 115 70-134 Tetrahydrofuran ug/m3 32.1 39.5 123 70-140 Toluene ug/m3 41.6 51.0 123 70-136 trans-1,2-Dichloroethene ug/m3 43.6 52.4 120 70-134 trans- 1,3-Dichloropropene ug/m3 50.5 56.0 111 70-131 Trichloroethene ug/m3 58.4 65.1 111 70-134 Trichlorofluoromethane ug/m3 62 71.4 115 63-130 Vinyl acetate ug/m3 46.4 53.6 116 70-139 Vinyl chloride ug/m3 28 32.5 116 70-132 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 44 Pace Analytical Services, LLC 1700 Elm Street lCtaac, Analytrcal Minneapolis, MN 55414 www.pacelabs.com (612)607-1700 QUALITY CONTROL DATA Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 SAMPLE DUPLICATE: 4220789 Parameter Units 10592093005 Result Dup Result RPD Max RPD Qualifiers 1,1,1-Trichloroethane ug/m3 ND ND 25 1,1,2,2-Tetrachloroethane ug/m3 ND ND 25 1,1,2-Trichloroethane ug/m3 ND ND 25 1,1,2-Trichlorotrifluoroethane ug/m3 ND .72J 25 1,1-Dichloroethane ug/m3 ND ND 25 1,1-Dichloroethene ug/m3 ND ND 25 1,2,4-Trichlorobenzene ug/m3 ND ND 25 1,2,4-Trimethylbenzene ug/m3 ND 1AJ 25 1,2-Dibromoethane (EDB) ug/m3 ND ND 25 1,2-Dichlorobenzene ug/m3 ND ND 25 1,2-Dichloroethane ug/m3 ND ND 25 1,2-Dichloropropane ug/m3 ND ND 25 1,3,5-Trimethylbenzene ug/m3 ND ND 25 1,3-Butadiene ug/m3 ND ND 25 1,3-Dichlorobenzene ug/m3 ND ND 25 1,4-Dichlorobenzene ug/m3 ND ND 25 2-Butanone (MEK) ug/m3 6.4 ND 25 2-Hexanone ug/m3 ND ND 25 2-Propanol ug/m3 23.0 21.7 5 25 4-Ethyltoluene ug/m3 ND ND 25 4-Methyl-2-pentanone (MIBK) ug/m3 ND 1.5J 25 Acetone ug/m3 97.0 89.9 8 25 Benzene ug/m3 1.1 1.1 3 25 Benzyl chloride ug/m3 ND ND 25 Bromodichloromethane ug/m3 ND ND 25 Bromoform ug/m3 ND ND 25 Bromomethane ug/m3 ND ND 25 Carbon disulfide ug/m3 ND .48J 25 Carbon tetrachloride ug/m3 ND ND 25 Chlorobenzene ug/m3 ND ND 25 Chloroethane ug/m3 ND ND 25 Chloroform ug/m3 ND ND 25 Chloromethane ug/m3 1.7 1.3 22 25 cis-1,2-Dichloroethene ug/m3 ND ND 25 cis-1,3-Dichloropropene ug/m3 ND ND 25 Cyclohexane ug/m3 ND 1.8J 25 Dibromochloromethane ug/m3 ND ND 25 Dichlorodifluoromethane ug/m3 2.9 2.6 10 25 Dichlorotetrafluoroethane ug/m3 ND ND 25 Ethanol ug/m3 1550 1470 6 25 E Ethyl acetate ug/m3 3.7 3.4 10 25 Ethylbenzene ug/m3 ND ND 25 Hexachloro-1,3-butadiene ug/m3 ND ND 25 m&p-Xylene ug/m3 ND 1 AJ 25 Methyl-tert-butyl ether ug/m3 ND ND 25 Methylene Chloride ug/m3 ND ND 25 n-Heptane ug/m3 ND ND 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 QUALITY CONTROL DATA Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 SAMPLE DUPLICATE: 4220789 Parameter Units 10592093005 Result Dup Result n-Hexane ug/m3 ND 1.2J Naphthalene ug/m3 5.8 7.0 o-Xylene ug/m3 ND .74J Propylene ug/m3 ND ND Styrene ug/m3 ND 1.6J Tetrachloroethene ug/m3 ND ND Tetrahydrofuran ug/m3 ND ND Toluene ug/m3 8.9 8.6 trans-1,2-Dichloroethene ug/m3 ND ND trans- 1,3-Dichloropropene ug/m3 ND ND Trichloroethene ug/m3 ND ND Trichlorofluoromethane ug/m3 ND 1.6J Vinyl acetate ug/m3 ND ND Vinyl chloride ug/m3 ND ND SAMPLE DUPLICATE: 4220790 Parameter Units 10592093006 Result Dup Result 1,1,1-Trichloroethane ug/m3 ND ND 1,1,2,2-Tetrachloroethane ug/m3 ND ND 1,1,2-Trichloroethane ug/m3 ND ND 1,1,2-Trichlorotrifluoroethane ug/m3 ND .85J 1,1-Dichloroethane ug/m3 ND ND 1,1-Dichloroethene ug/m3 ND ND 1,2,4-Trichlorobenzene ug/m3 ND ND 1,2,4-Trimethylbenzene ug/m3 ND .85J 1,2-Dibromoethane (EDB) ug/m3 ND ND 1,2-Dichlorobenzene ug/m3 ND ND 1,2-Dichloroethane ug/m3 ND ND 1,2-Dichloropropane ug/m3 ND ND 1,3,5-Trimethylbenzene ug/m3 ND ND 1,3-Butadiene ug/m3 ND ND 1,3-Dichlorobenzene ug/m3 ND ND 1,4-Dichlorobenzene ug/m3 ND ND 2-Butanone (MEK) ug/m3 ND 4.1J 2-Hexanone ug/m3 ND ND 2-Propanol ug/m3 16.1 15.7 4-Ethyltoluene ug/m3 ND ND 4-Methyl-2-pentanone (MIBK) ug/m3 ND ND Acetone ug/m3 32.8 31.8 Benzene ug/m3 1.2 1.3 Benzyl chloride ug/m3 ND ND Bromodichloromethane ug/m3 ND ND Bromoform ug/m3 ND ND Bromomethane ug/m3 ND ND 1'7VN Max RPD 25 17 25 25 25 25 25 25 3 25 25 25 25 25 25 25 Max RPD RPD 2 3 4 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 QUALITY CONTROL DATA Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 SAMPLE DUPLICATE: 4220790 Parameter Units 10592093006 Result Dup Result Carbon disulfide ug/m3 ND ND Carbon tetrachloride ug/m3 ND ND Chlorobenzene ug/m3 ND ND Chloroethane ug/m3 ND ND Chloroform ug/m3 ND ND Chloromethane ug/m3 1.3 1.4 cis-1,2-Dichloroethene ug/m3 ND ND cis-1,3-Dichloropropene ug/m3 ND ND Cyclohexane ug/m3 ND 2.7J Dibromochloromethane ug/m3 ND ND Dichlorodifluoromethane ug/m3 2.6 2.6 Dichlorotetrafluoroethane ug/m3 ND ND Ethanol ug/m3 1340 1260 Ethyl acetate ug/m3 2.7 2.7 Ethylbenzene ug/m3 ND .67J Hexachloro-1,3-butadiene ug/m3 ND ND m&p-Xylene ug/m3 ND 1AJ Methyl-tert-butyl ether ug/m3 ND ND Methylene Chloride ug/m3 ND ND n-Heptane ug/m3 4.9 5.0 n-Hexane ug/m3 1.2 1.3 Naphthalene ug/m3 ND ND o-Xylene ug/m3 ND .61J Propylene ug/m3 ND ND Styrene ug/m3 ND .97J Tetrachloroethene ug/m3 ND ND Tetrahydrofuran ug/m3 ND ND Toluene ug/m3 3.1 3.1 trans-1,2-Dichloroethene ug/m3 ND ND trans- 1,3-Dichloropropene ug/m3 ND ND Trichloroethene ug/m3 ND ND Trichlorofluoromethane ug/m3 ND 1.7J Vinyl acetate ug/m3 ND ND Vinyl chloride ug/m3 ND ND Max RPD RPD Qualifiers 7 0 I 1 7 a 25 25 25 25 25 25 25 25 25 25 25 25 25 E 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 QUALIFIERS Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS CH The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased high. E Analyte concentration exceeded the calibration range. The reported result is estimated. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /13/2022 04:54 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 44 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 1700 Elm Street Minneapolis, MN 55414 (612)607-1700 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2021-336 LEWIS STIR. Pace Project No.: 10592093 Lab ID Sample ID QC Batch Method QC Batch 10592093001 CS-1 TO-15 793334 10592093002 CS-2 TO-15 793334 10592093003 CS-3 TO-15 793334 10592093004 CS-4 TO-15 793334 10592093005 CS-5 TO-15 793334 10592093006 CS-6 TO-15 793334 10592093007 SSV-7 TO-15 793334 10592093008 SSV-8 TO-15 793334 10592093009 SSV-9 TO-15 793334 10592093010 SSV-10 TO-15 793334 10592093011 SSV-11 TO-15 793334 10592093012 SSV-11 DUP TO-15 793334 10592093013 CS-12 TO-15 793334 10592093014 CS-13 TO-15 793334 Date: 01/13/2022 04:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Method Analytical Batch Page 40 of 44 IA7eAnal1�L}ICaj® ;� AIR. CHAIN -OF -CUSTODY / Analytical Request Document Wiew.pacela6s.com The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must he completed accurately. Section A Section B Section C 55440 Page: I of Required Client Information, Required Project Information: Invoice Information: Company: dal i ReportTa: ` �11 r G� Attention: �t , ` f!� D r �VT » program Copy To: %' Company Name: T W R-A Vr Lb F- llST SuperFund F- Emissions r- Clean Air Act Address: C�•� r Voluntary Clean Up r DryClean F RCRA F Other`_ Email T o Pur ase role 0.: Virl y M t� e4y, _ 'h Pace Quote Reference: _ - n un3ss Location of e m mom e: F : �, Project Name: L �l C o S- 3 T tY + f~ Pace Pro]ect ManagerlSales Rep. Sampling by State PeV _ PPhnl — .1_f Requested Due Daterl'AT: ' M ppmA L Project Number: 201X r 3 3 f Pace PtoTile # Report Level ll. III._ IV._ Other 'Section DRequired Client lnformaGvane nwa 3 canes on ME]!R gam COLLECTEDm = Y Method: ►/ a AIR SAMPLE ID 1 UWS Ta Liter swmma Can ,tc Sample IDs MUST BE UNIQUE � �p 6 `"T1�7' �} 2 m a 2 a 5umma Can Flow Control - �" m � Lli vwu" Pwf LvPOLC LDw Vdurx PWl �w � � Z'D2! t MF " d E Frrahvol—Puff F1vP 01h., PM10 o � s S C. .�.. w LL G Number Number w F a a DATE ci _-` 0. Q� n�' ti� +� +t� Pace Lab In q CO3 vi �? - -1 11 .ilk, trri ­2,t 26 '1 2 R � 3'r { � D D l - _ vD_�1 S- �r 61 ot 2 ��9 q Q� 17 3 1 3 S-26L " 6; 3 3" 7'' 4 c� h 2, ID fl — S"N-1 � �, 11 v �.� � � �SS v Jl 31 0� 3Kit 4 3 v 0.5 1 R" to 3 `z 1t -_ elf 2 e ,s Comments : • ■ • ■ ■ • 0111111 ■ SAMP Ct7 ON5 ado lw N I E L.t7,(� 1 r ,Fc - P P,0 F"A r'v) } Z z r i iSAMPLER W0=1D5920930. NAME ANE) SIGNATURE PRINT regime P SAMPLER. �.' ya � i;+,� y � E � o U �0 E t SA ER: DATE Signed (MM i OD+ .,� =� N N - { IT U tll{�l{ A 10592093 ;hnica[ Phone: 612.607.6386 FC046Rev.01. 03Feb2010 AIR. CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section A Section B Section C Pa e: of 1172 Required Client Information Required Project Information Invoice Information Company. .� .,� _,. ! Report 7o r] p ,�y 1 Altenlior: „ �r,j(_ Program Address Copy To �Jy Company Name UST IFXperfund r Emissrons r Clean Air Act Adtlress f— Voluntary Clean Up r Ory Clean 1W RCRA I— ❑:her_ Emed T6 Purchase Order No race Quote Reference: Location of Una Phone: Fax Project Name- Pace Project ManagerlSales Ftep Sampling by "' PPBV rrV. PPMV _ Requested Due DatelTAT: Project Number Pace PrzK3e #: State _ ether T Report Level II._V III._ IV.— Other 'Section D Required Client Information Vold Ueda CoCea yU216 Epp COLLECTED m n m Q Method: AIR SAMPLE I❑ TedW,5! Tg d { = .% tne: s�mma can ,�c - ! �' � a Summa e Leers ra Z I C ��, I 7 m ° v Flow gem q Sample IDs MUST BE UNIQUE a +�' Lm Volume Puff MVP w a m a d ❑ Kghvok—aPurl HVP S m LL Y s Can Control Numbe m w.er PMm7 g ¢ i cc« rre -a .= c Number +a A QU -Z 5� DATE TIME DATE TIME[7 c U Q� ,yG .fl RO rfl .O Pace Lab ID 12 - 5 4' �� 27 z�! 5 c��l D l�-q - -j _ €�I Comments �j • SAMPLE CpHWIONS z z z z � } T } z a z ■ SIGNATUREo m o m a qUq (n ., _.:: �f ;F..�l:> i)ATE Sgnev fhw IEOI YYI ' m m V U m to C n 7 CID C-V ~ 0 r+J A N O A 1700 Elm Street SE, Suite 200, Minneapolis, MN 55414 FC046Rev.01- 03Feb2010 Document Name: Document Revised: 04Jun2020 aceAnalytkal ® Sample Condition Upon Receipt (SCUR) Exception Form Page 1 of 1 Document No.: Pace Analytical Services - ENV-FRM-MIN4-0142 Rev.01 Minneapolis SCUR Exceptions: Workorder #: Container # of PM Notified? ❑Yes ❑No Out of Temp Sample IDS : Type Containers If yes, indicate who was contacted/date/time. If no, indicate reason why. Tracking Number/Temperature 5 q ,4- n<z- g 1,27 lqq R' t_sZa Multiple CoolerProject? ❑Yes ❑No If you answered yes, fill out information to the lefE No Temp Blank Read Temp Corrected Temp Averai; Temp Issue Type: Container # of Sample.ID 1.14 Type Containers PH Adjustment Log for Preserved Samples Sample ID Type of Preserv. pH Upon Receipt Date Adjusted Time Adjusted Amoun t Added (mL) Lot # Added pH After In Compliance after addition? Initials ❑Yes ❑No ❑Yes ❑No ❑Yes ❑No ❑Yes ❑No Comments: Page 43 of 44 Document Name: Condition Upon Receipt (SCIJR) - Air Document No.: ENV-FRM-MIN4-0113 Rev.01 ConditionAir Sample Client Name: , Project #: • Courier: dEx El El ❑ Client Pace ❑ SpeeDee El Commercial el Tracking Number: See Exception Custody Seal on Cooler/Box Present? Seals Intact? ❑ Yes ❑ No Packing Material: ❑ Bubble Wrap ❑ Bubble Bags Foam ❑ None ❑ Tin Can ❑ other: Document Revised: 130ctZ021 Page 1 of 1 { Pace Analytical Services • Minneapofis Wa#:10592093 PM: MR2 flue Date: 12/28/21 CLIENT: PYRAMID Date & Initials of Person Examining Contents: Chain of Custody Present? Yes ❑ No 1 r,:amments: Chain of Custody Filled out? Yes ❑ No 2. Chain of Custody Relinquished? Yes ❑ No 3, Sampler Name and/or Signature on COC? Yes ❑ No ❑ N/A 4_ Samples Arrived within Hold Time? Yes ❑ No 5, Short Hold Time Analysis (c72 hr)? _ ❑ Yes o 6. Rush Turn Around Tlme-Re quested? ❑ Yes No 1 7, Sufficient Volume? es No g, Correct Containers Used? (Tediar hags not acceptable container for TO-15 Yes ❑ No 9• rLs care_ wro.— � a r` C 0[ICOM2C*d he or APH) -Pace Containers Used? es ❑ No Containers Intact? ky es ❑ No (visual i c jno leaks when pressurized) Media: Air Can I Airbag 11. Individually Certified Cans? Y N ist which samples} Is sufficieklatomi5tion available to reconcile samples to Yes ❑ No 12, the COC? Do cans need to be pressurized? 13. (DO NOT PRESSURIZE 3C or ASTM 1946111) s ❑ No Gauge R.- ❑ 10AIR26 ❑ 10AIR34 ❑ 10AIR35 ❑10AIR17 WDAIR47 ❑10AIR48 Canisters Canisters Flow Sample Number Can Ip Controller Initial Pressure Final Pressure Sample Number Flow Initial Final Can ID Controller Pressure Pressure tt- - D53 Cps g �CyII tt -5 �3sr I�t� _ , ,1v(D 3qs,) tt `�S`� Z� � � •5' aDw 716 A3 -k.5 ►i-1 (19� �2 ro r I 3_- 5 -/ i� 12 3611 )1 CLIENT NOTIFICATION/RESOLUTION Field Data Required? ❑ Yes ❑ No Person Contacted: Date/Time: Comments/Resolution ram Project Manager Review: cs Date: 12i21121 Nate: Whenever there is a discrepancy affecting North arolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR CertiFcation Office ft.e., out of hold, incorrect preservative, out of temp, Incorrect cantoiners). Page 44 of 44 Attachment H PYRAMID EWRCY"NTAL. B EN WRING, P.C. Weather Expected: Clear and cold am Project Name: West Lewis Street Brownfields Site Project Number: 2.02-2 —02-f City : Greensboro, NC -- __ __ `-' w• � Project Address : (Zrr0 W • 1�aa1 SSV / SG Fieldwork Record SAMPLE S�. W+ NAME Category Descriptions Descriptions Address I22-y W. Lewis 5t. Ea- North) South / Center SG Location 5V ✓ CS Bus. Operations? Floor Type Concrete / wooden E2r Crawlspace or SSV VN� Vapor Pin SSV Install Date : �� � Z- ►I Er Floor Thickness ? " Installation Location on Site Map ? es No Void Space Under Floor: �HVAC in this Space ? Yes No ERrilnconditioned Space ? Air Sampling �Oate : I C� XD Z Z Cylinder Number : ❑ 2—05 Batch Cert / Individ. Cert. ��Flow Controller - 200 ml/min # pYPi dHelium - Fully Hooded LjJZ6 Sample Train Purge (5,�ak) 20 x 60 MLA 0 ML Hood Helium = prn D--,Tedlar Bag Helium = ppm Readings of Vacuum [ inches of Hg ) over5ample COLLECTION Time and Vacuum r Starting Time : r � .: /C L�] �J Cannister Vacuum /Pte-Sampling rf �.❑ �C i !41e 02~ S Mins. �-� •'D Hg" 7-2 25 Mins_- j • 0 Hg" 45 Mins. Hg" 0? 10 Mins. '•" _ Hg" L . 2w1 30 Minn~ �.� Hg" 50 Min H " {� 15 Mins. ' t� •� Hg" 35 Mins. SS Mins. H " 20 Mins. "" r 0 Hg" 40 Mins. �g" 60 Mins. Hg" H Sample End Time �'1 ' � Sample Cannister Ending Vacuum ' .0 He Sample r% Hg" Vacuum on COC Pick u By PA £ Courier Packed in Pace Boxes Date z Ef 1Er Shipping �Cylinder inspecteCOKDamaged e x Ing Pyromld En vironmen rol & 503 Industrial Avenue, Greensboro, NC 17405 Phone - (336) 335-3I74 Project Name: West Lewis Street Brownfields Site PYRAMID Project Number : 202,2 o z l WKWENrutexESING.P,C. City. Greensboro, NC (',} Project Address: fZ0 k7 • 1,4tX ,1 SSV / SG Fieldwork Record DuT 51 1) C Weather Expected. Clear and cold am SAMPLE NAME kol Category Descriptions Descriptions Address �D W. Lewis St. [EJ <North / South /fr�r Center SG Location SSV CS ED' Bus. Operations?v Floor Type E2` oncrete / Wooden Crawlspace or 55V CF'�'l Vapor Pin SSV Install Date: 2 2 Floor Thickness ? 411 " Installation Location on Site Map? es No E Void Space Under Floor HVAC in this Space? 400 El Unconditioned Space . r T); " s s e ►� vr,� Date ZZ [Er Cylinder Number Air SamplingRr Flaw Controller - 200 ml/min Batch Cert. Individ. Cert. Er 21 Helium -Fully Hooded EDSample Train Purge (S vgisj 2Q x 5U ML = 1, O ML Hood Helium � ppm edlar Bag Helium = _—ppm r Readings of Vacuum (inches of Hg) over Sample COLLECTION Time and Vacuum r Starting Time . ;3) 11 Cannister Vacuum / Pre -Sampling : r Q• G) 5 Mins*- 2 E-2• HE" 25 Mins. •' �pZ • Hg" 45 Mins Hg" 10 Mins. :� HE" 30 Mins. "` `•� Hg" 50 ins. Hg" 15 Mins. 'rQ. Hg" `3 y Mins. HE" 55 Min . g" 20 Mins. ; i0.Q Hg" 40 Mins. HE Mins. g" Sample End Time . 03 r► Sample Cannister Ending Vacuum ^ _7 • HE" Picku By PAJE Courier Sample Er HE" Vacuum on CDC ` 7'� Packed in Pace Boxes Date I Z�ZZ Shipping E/ Cylinder inspecte t OK j Damaged ip : Trac i Pyramid Environmental & SSv r IS P) 0 - 2�- 3 Phone -(336)335.3174 F� PYRAM I D �fNY]FOIIiEIi && QIGpEEW. P.C. Weather Expected: Clear and cold am Project Name: West Lewis Street Brownfields Site Project Number : a 0,2Z ~ 0 2-1 City : Greensboro NC Project Address - 1 Z0 W L4"�S Sv�- SSV / SG Fieldwork Record SAMPLE , f J� NAME V [, Category Descriptions Descriptions Address '� t �-D W. Lewis 5t. North South Center CS Bus. Operations? �0-KCA SG location E2�IR Floor Type d Wooden d Crawlspace or E�1 CC.Y7 Vapor Pin EEF 55V Install Date : ER'lFloor Thickness ?Installation A0`0soD)AT— dLocation on Site Map ? Void Space Under Floor : ! y �J rN EfHVAC in this Space ? Yes No Unconditioned Space 1r Ir i) Air Sampling Ef Date: 2pZ 2 Cylinder Number: 2-0 zl-` a Batch Cert Individ. Cert. Flow Controller - 200 ml/min # e Q-M� 0 Helium - Fully Hooded Sample Train Purge { 5 col 20 x 60 ML = 1,200 MIL 4�o QD ❑ v 4� ��] Hood Heiiun? ppm � Tedlar Bag Helium ppm Readings of Vacuum ( inches of Hg j over Sample COLLECTION Time and Vacuum r Starting Time : � 5 ► 7- E) �. r It Cannister Vacuum / Pre -Sampling 5 Mins. HE" 25 Mins.— 1-2— HE " 45 Min Hg" 1O Mins. � � Hg" 36 Mins. w. • Hg" 50 ins. 15 Mins. Hg" 3, 9+ Mins. 5 Hg" 5 Min Hg" 20 Mins. Hg" 40 Mins, Hg" 60 Mins. F n Sample End Time �+ p 0 Sample Cannister Ending Vacuum =I. Pig I + Picku B PA E Courier ! � Y Sample � Hg" Vacuum ❑n CDC ^` � � � � +i � + Packed in Pace Boxes Date 2 01 Shipping Cylinder inspected OI(} Damaged x ip : rac m # Pyramid Environmental E Engineering, P.C. 5031ndustrialRvenue. Greensdoro. NC 27406 Phone - (335) 335-3I74 SSA - Ka =-�. `�- z PYRAMID EwRo iEWAL & RX&EERN3, P.C. Weather Expected: Clear and cold am Project Name: West Lewis Street Brownfields Site Project Number: 2() 2-2 OZ City: Greensboro, NC Project Address : Z0 SSV / SG Fieldwork Record SAMPLE Ss G ! AfAARE I Category Descriptions Descriptions Address �'� W. Lewis St. E2/ North / South Centeerr+,�� SG Location 55V C5 � Bus. Operations? ri "r L C4,4 Floor Type ErConcrete / Wooden Crawlspace or 55V %• 6 r� Vapor Pin SSV Install Date: Z ET Floor Thickness ? " _r Installation f'� Location No Void Space ND Vol `! Site Map ?gy" on Under Floor : 03 HVAC in this Space ?No ED-Unconditioned Space ? --� NA Air Sampling Date : r Z Cylinder Number: f 2 V Ea Batch Ce / Individ. Cert. M Flow Controller - 200 ml/min # 7 r T r Er Helium - Fully Hooded Sample Train Purge (ols) 20,60 M�,200 ML Hood Helium = >5 "pprn Eil— Tedlar Bag Helium = ppm 710, obo 0 Readings of Vacuum j inches of Hg j over Sample COLLECTION Time and Vacuum StartingTime : rf' Cannister Vacuum / Pre -Sampling : '� 7�•� r' 1>0 5 Mins.- dC Hg" L 20 25 Mins. ^�• Hg" 45 Mins. Hg" I,T. 0S 1D Mins. 2'Z' •J Hg � 2,;F7 30 Mins. i 0 Hg" 50 M- s. H " • 0 1 15 Minim • Hg" 20 Mins. 5 • 0 Hg' 35 Mins. Hg" 55 Mins. H Mins. g" 60 ins-s. Hg" �40 Sample End Time �• 3 1 " I }5ample Cannister Ending Vacuum `• Hg" Pickup By PAC Courier Sample El Vacuum an COC — 0 � Packed in Pace Boxes � Date �� Shipping ►� Cylinder inspecte [ OIC ] Damaged Pyramid Environmental & ssv - ►"7 NC 27406 Phone - (336) 335-3I74 p fo ] C-. 6 PYRAMID E7F RCMENTA1& 24MEBING, P.C. Weather Expected: Clear and cold am Project Name: West Lewis Street Brownfields Site Project Number: 2Zk2�2- - 02,J City: Greensboro, NC �L Project Address: 120 ► -% Le-i/► ic,- `4'• SSV / SG Fieldwork Record SAMPLE NAME LTj Category Descriptions Descriptions Address Eff W. Lewis St. 01'� North / South / Center SG Location M SSV / C5 Bus. Operations? `-'a'- [Ef Floor Type EZ`� oncrete / Wooden 21/ Crawispace or SV VY'+ C��IIt f✓ jC Vapor Pin Er SSV Install Date : � �/ � FlaorThickness ? " Installation �[ f EffLocation on Site Map ? Yes No Er Void Space Under Floor: dHVAC in this Space ? Yes NoUnconditioned Space ? _ Air Sampling El Date : ��"�� Cylinder Number : �� - ` Flow Controller - 200 ml/min # Batch Cert. / Individ. Cert. Er El Er Helium - Fully Hooded Sample Train Purge ( 5 T'` 20 x 60 WJ,-- 1,200 ML Hood Helium = >-57WO ppm EDTedlar Bag Helium = ppm PZ01von F1Readings of Vacuum ( inches of HE ) over Sample COLLECTION Time and Vacuum Starting Time : : 9V Cannister Vacuum / Pre -Sampling: —�"� 5 Mins. b . Hg" 25 Mins. �t Hg" 45 Mins. HE 10 Mins. ` C7 Hg" 30 Mins. g,y Hg" 50 Min Hg" 15 Mins. Hg" 35 Mins. g' 55 ins. g" 20 Mins. -► S r Q Hg" 40 Mins, 60 MinsZ, Hg" st Sample End Time 1 o� I �' I Sample Cannister Ending Vacuum- L •❑ Hg" r� 1 Picku By PIE Courier Sample EE� HE" Vacuum on COC l •D Packed in Pace Boxes Date .2 Shipping Cylinder inspected 0Damaged Pyramid Enviranmen ineering, P.C. 503 Industrial Avenue, Green 7406 Phone - (336) 335-3174 cfSv—IU Pc� - 45.12 Project Name: West Lewis Street Brownfields Site PYRAMID Project Number: -?- o Z 2 — ❑ZJ WROMADrAL6DOMING, P.C. City : Greensboro, NC Project Address : 1 2►0 L W- 5 ill—. SSV / SG Fieldwork Record Weather Expected: Clear and cold am SAMPLE NAME v Category Descriptions Descriptions Address W. Lewis 5t- North / South / Center` _ r 5G Location t S dBus. Operations? &?c �-�'Vi� Fivar Type gFCn,,,tC/ Wooden Crawlspace or C5VCon Cy- �! Vapor Pin ER'sSV Install Date: + � Zy Floor Thickness ? " Installation Location on Site Map ? Yes No Void Space Under Floor : 0� V oL U 16 HVAC in this Space ? Yes No unconditioned Space ? —NA Air Sampling E" Date : 1 �� �EJ Cylinder Number: C./ G 25 9 Er atch Ce Individ. Cert. ER' Flaw Controller - 200 ml/min # Helium - Fully Hooded Er Sample Train Purge 5 v01�sj]�7 20 x 60 M�00 MIL ID Hood Helium = a 5,008 PM In Tedlar Bag Helium = _ _jC/ ppm 10, Readings of Vacuum inches of Hg } over Sample COLLECTION Time and Vacuum Starting Time : 1 .I Cannister Vacuum / Pre -Sampling : 5 Mins. � Hg" 25 Mins, � HE 45 Mins. g" i 10 Mins. Hg" r r Mins,— 3p Mins. Hg" 50 Mins. Hg" rr 15 Mins. Hg" 35 Mins. Hg" 55 Mins. Hg" ry 20 Mins. " Hg" 40 Mins. Hg" 60 Mi Hg" Sample End Time ! —z Sample Cannister Ending Vacuum' I'y et Hg" �7 Pickup By P E Courier Sample Hg" Vacuum on CDC " i r Packed in Pace Boxes L� Oate Shipping Cylinder inspectedleDamaged acking # Pyramid Environmental ns6oro, NC 27406 Phone - (336) 335-3174 SSV — I Ct `" j • �Pm PYRAMID cDWA MEWAL8 MNEER:NG P.C. Weather Expected: Clear and cold am Project Name: West Lewis Street Brownfields Site Project Number: -2 G)Z2 ' ❑Z I City : Greensboro, NC ��77 Project Address : l 4fl SSV / SG Fieldwork Record W . LQt'as SAMPLE NAME 2-0 SS l V � — Category Descriptions Descriptions Address F9 1 2-0 W. Lewis St. Ell, North / South Center G SG Location Ef V CS Bus. Operations? Floor Type ncrete / Wooden Crawlspace or 55V LS�n 1. Vapor Pin Er SSV Install Date: � Z ET Floor Thickness ? " Installation r� Location on Site Map ? Yes No Void Space Under Floor! ND cV ,Dt �HVAC in this Space ? Yes No Er Unconditioned Space ? NA Air Sampling Date : Q 2WCylinder Number: 2-'7 Batch Cert. / Individ. Cert. EEI- Flaw Controller - 200 ml/min # lr'V Helium - Fully Hooded ED�Sample Train Purge ( 5 vols) 20 x 60 ML -1,200 MIL t1� dHood Helium = a 5,000 pm �Tedlar Bag Helium = ppm COI 0oa EIrReadings of Vacuum ( inches of Hg) over Sample COLLECTION Time and Vacuum Starting Time :� Cannister Vacuum / Pre -Samplings 5 Mins. Hg" 25 Mins. 3. Hg" 45 Mins. He 10 Mins. 2J Hg" 30 Mins. `�S Q. Hg" 50 Mins. Hg " 15 Mins. i C1 • 5 Hg" 35 Mins. He 55 Mins. Hg" 20 Mins. — 1 6.5 Hg" 40 Mins. He 60 Mins. Hg" Sample End Time Q Sample Cannister Ending Vacuum Hg" �] [Er Pickup By PA E Courier Sample Hg" Vacuum on COC r' Packed in Pace Boxes © Date � 2� z Shipping EfCylinder inspecte t OK) Damaged e Pyramid Environmental & Engineering, P.C. 503Industrial AVenue, Greensboro, NC 27406 Phone - (336) 335.3174 55V -V ply] = 6 3 . i Pp nn PYRAMID Erm OV&Wru a BiMEFR c, rc. Weather Expected: Clear and cold am Project Name: WestLewisStreet Rrro-�twnfields Site Project Number: L- 22 — v2' City : Greensboro, INC Project Address : t D S -V SSV / SG Fieldwork Record SAMPLE NAp ME V SS — Z Category Descriptions Descriptions Address �" W. Lewis St. North / 5outh4 / Center C SG Location E,) CS Bus. Operations? Floor Type ED' �Concret / Wooden Er Crawlspace or 55V Vapor Pin dS5V Install Date 2-2-[Ef Floor Thickness ? — _ _ lip t r! " Installation ER"Location on Site Map ? Yes No dVoid Space Under Floor HVAC in this Space? Ces No e ?~� Air SamplingDate Cylinder Number: 2.1 e C atch Cent. Individ. Cert.Flow Controller - 200 ml/min # D'Helium - Fully Hooded TVS Sample Train Purge { S voIsj 20 x 60 ML = 1,200 ML } ZD 000 Hood Helium = 5,d00 ppm �Tediar Bag Helium = 55U- ?-1 Readings of Vacuum ( inches of Hg ) over Sample COLLECTION Time and Vacuum pit. A� Starting Time : IZ r : CannisterVacuum / Pre -Sampling : — " S Mins. � Hg" 25 Mins. Hg" 45 Mins. g" 10 Mins. 22 Hg" 30 Mins.` Hg" 50 Mins Hg" 15 Mins. .5 Hg" 4, WMins. Hg" 55 Mins. Hg" .•11 20 Mins. 15 Hg" 40 Mins. Hg" 60 Mins. Hg" 4Sample End Time 2 ; 55 Sample Cannister Ending Vacuum `7 Hg" {{ Picku By PA Courier Sample 1Hg" Vacuum on COC " Packed in Pace Boxes ��Date Shipping ET -Cylinder inspects { ❑K } Damaged # Pyramid fnVlrOnMe in P.C. 5031ndustno Avenue, Greenshora, NC 27406 Phone - (336) 335-3174 SS if D = '7f,4- ,ff V\ Project Name: West Lewis Street Brownfields Site PYRAMID Project Number •E1Mf034UrALA@0ERRID.P.C. City., Greensboro, NC y Project Address : t Uetac, 1 SSV / SG Fieldwork Record Weather Expected: Clear and cold am SR NAME 7E NSS A Category Descriptions Descriptions Address W. Lewis St. North / South / Center Bus. Operations?' C� SG location dSSV CS El Floor Type oncret / Wooden D�' Cratiaihnace or SSV IM COySC1V_ ei-C Vapor Pin 71 SSV Install Date: 01 02,2- Floor Thickness ? �� ��•+''+'L Installation ff"Ll'ation on Site Map ? Yes No Void Space Under Floor [ErHVAC in this Space ? Yes No ncanditianed Space ? Air Sampling E Date : ! 1 1 ZDZZ M___C y1inder Number: 1 � L datch Cert. Individ. Cert. FO FI0W Controller - 200 ml/min 4 Er Helium - Fully Hooded � [ Sample Train Purge {5vols) 20 x 60 ML =y,200 ML Ea Hood Helium =�0O pp d �Tedlar Bag Helium =pp IjSV ^ �Z Readings Hg) Sample COLLECTION Time Vacuum ofVacuum ('inches of over and Starting Time : U M Cannister Vacuum / Pre -Sampling G !� 5 Minsk 2 . -/ Hg" 25 Mins. " Hg" 45 Mins. X Hg" r� q 10 Mins." Hg" Zq &Mins. Hg" 50 Mins. Hg" 15 Mins. . n He 35 Mins. % Ng" 55 Mins. Hg" 20 Mins. Hg" 40 Mins.! Hg" 60 Mins" Hg -. Sample End Time ��i�5ample Cannister Ending Vacuum —7,0 Hg" Picku By PE Courier Sample Hg" Vacuum on COC 01"Packed in Pace Boxes dDateO 42. r02—Z Shipping Cylinder inspected 0Damaged Pyramid Environmental eering, P.C. 5031ndustna oro, NC 27406 Phone - (336) 335.3174 S�v..a2- Ply = &3frr 3 Project Name: West Lewis Street Brownfields Site PYRAMID , Project Number : WFOVEWAL& rr4c_r_ERING,_P.C.. City: Greensboro, NC Project Address : 12-0 14a4N-,�'S 5SV / 5G Fieldwork Record Weather Expected: Clear and cold am SAMPLE NAME SV " 2 3 Category Descriptions Descriptions r7 � K G41ryi.��' Address W. Lewis St. CAW 5G Location EO'SSV CS Er Bus. Operations? ❑ CaAI'- Floor Type Concrete f---Wvr;MT - Craw ace or 5SV wit COWL �'+rCn Vapor Pin 12r�SSV Install Date:.02 Z dFloorThickness ? G C'• . 5 iP r+ Installation Location on Site Map ? Yes No ED" Vold Space Under Floor VAC in this Space ? & No EJ-7n—coed Space ? — 0 A7 Y �3 Air Sampling Date : 1 I «I I��� Cylinder Number :��V������T Q Batch Cert. / Individ. Cert. ❑� Flow Controller - 200 ml/min # Er Helium - Fully Hooded L(F5 Sample Train Purge [ 5 vols) 20 x 60 ML =1,200 ML >- i 57, ()t7p 0 risV _Z3 EirHood Helium = a 5,000 ppm Ef Tedlar Bag Helium = ppm p[ ErReadings of Vacuum { inches of He ] over Sample COLLECTION Time and Vacuum Starting Time : tV : rJ�ri Cannister Vacuum / Pre-1Sampling k 04,1•5 Mins. o �, - He" 1 �.V4 25 Mins. — 21 • � He" {1 : 2-i 45 Mins. 13 s Hg„ l0;.�a� 10 Mins. �� Hg" f �••ag3D Mlns.'` `�D Hg" f�; M50 Mins. _ _12.D He" iC):.0 l�15 Mins."' �`4• � Hg" ] �� I 35 Mins. f l`7,D Hg" JJ-.3X -55 Mins. 0'r1) Hg" 10; 5C720 Mins. Hg" L f i9 40 Mins. ~� 5` Hg" 1 i i 15)(60 Mins. • ❑ Hg" EySample End Time 11 Sample Cannister Ending Vacuum �• V Hg" Pickup By PACE Courier Sample EJO�Hg" Vacuum on COC Packed in Pace Boxes Date Shipping E:r Cylinder inspecte OK j Damaged x i c mg Pyramid Environmental & Engineering, P. ro NC 27406 Phone - (336) 335-3174 SSV 2 3 � 1 � -- � � • fv � p-r� 4,475 sq. ft. J dB 10120 BARNHARDT ST 120 W. Lewis 9,900 sq. ft. •Mai► - I E f ffrr jj! I J. '11 117 B-1 W. Lewis 3,737 sq. ft. 4 IL 1- Guilford County, NC � SSV-14 S -15 s SS -17 � SSV-19 � � �►' I SS 8 120 W LEWIS 5T SSv_zfl SSV-23 v • SSV-21 - MAT 531� 520�ELM 5T = 533 IR UK c ",m 526 S'EC.M.ST�r , �535'E � t � 5325345 ELM ST ssv _. ssv-7 C5-CS -4 .... ' r cs-� V0c 600 MT+� z ,S5 ftEL 117 W. Lewj-6204 3,564 sq. f May 5, 2021 115 W. Lewis 3,666 sq. ft. W. Lewis j 2,fi97 sq, ft, 111 W. Lewis 1:600 5,828 s ft. ° 25 so 100 ft 0 5 10 20 m Figure 5 Locations afSSV/Crawlspace Samples West Lewis &Model Linen Site NC 8rownfrelds Work Plan Version 2.3 3uil}ord County does nat certify the avmentid[y or accuracy of Such infarmapon. No warranties, express or implied. are provided for the records andlor mapping data herein, or for their use or interpretation by the Vssr. Attachment I lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 February 08, 2022 Mr. Mike Jones Pyramid Environmental P.O. Box 16265 503 Industrial Avenue Greensboro, NC 27416 RE: Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Dear Mr. Jones: Enclosed are the analytical results for sample(s) received by the laboratory on January 21, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Minneapolis Revised on 02/08/22 to include results for samples 001, 003, and 006 per client request. If you have any questions concerning this report, please feel free to contact me. Sincerely, �G Lindsey N Wooten lindsey.wooten@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS r O This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 42 laneAnalytical www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Pace Analytical Services, LLC - Minneapolis MN 1700 Elm Street SE, Minneapolis, MN 55414 1800 Elm Street SE, Minneapolis, MN 55414--Satellite Air Lab A2LA Certification #: 2926.01 Alabama Certification #: 40770 Alaska Contaminated Sites Certification #: 17-009* Alaska DW Certification #: MN00064 Arizona Certification #: AZ0014* Arkansas DW Certification #: MN00064 Arkansas WW Certification #: 88-0680 California Certification #: 2929 Colorado Certification #: MN00064 Connecticut Certification #: PH-0256 EPA Region 8 Tribal Water Systems+Wyoming DW Certification #: via MN 027-053-137 Florida Certification #: E87605* Georgia Certification #: 959 Hawaii Certification #: MN00064 Idaho Certification #: MN00064 Illinois Certification #: 200011 Indiana Certification #: C-MN-01 Iowa Certification #: 368 Kansas Certification M E-10167 Kentucky DW Certification #: 90062 Kentucky WW Certification #: 90062 Louisiana DEQ Certification #: AI-03086* Louisiana DW Certification #: MN00064 Maine Certification #: MN00064* Maryland Certification #: 322 Michigan Certification #: 9909 Minnesota Certification #: 027-053-137* Minnesota Dept ofAg Approval: via MN 027-053-137 Minnesota Petrofund Registration #: 1240* Mississippi Certification #: MN00064 Missouri Certification #: 10100 Montana Certification #: CERT0092 Nebraska Certification #: NE-OS-18-06 Nevada Certification #: MN00064 New Hampshire Certification #: 2081* New Jersey Certification #: MN002 New York Certification #: 11647* North Carolina DW Certification #: 27700 North Carolina WW Certification #: 530 North Dakota Certification #: R-036 Ohio DW Certification #: 41244 Ohio VAP Certification (1700) #: CL101 Ohio VAP Certification (1800) #: CL110* Oklahoma Certification #: 9507* Oregon Primary Certification #: MN300001 Oregon Secondary Certification #: MN200001* Pennsylvania Certification #: 68-00563* Puerto Rico Certification #: MN00064 South Carolina Certification #:74003001 Tennessee Certification #: TN02818 Texas Certification #: T104704192* Utah Certification #: MN00064* Vermont Certification #: VT-027053137 Virginia Certification #: 460163* Washington Certification #: C486* West Virginia DEP Certification #: 382 West Virginia DW Certification #: 9952 C Wisconsin Certification #: 999407970 Wyoming UST Certification #: via A2LA 2926.01 USDA Permit #: P330-19-00208 *Please Note: Applicable air certifications are denoted with an asterisk (*). REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Lewis St. Brownfields 2022-021-Revised Report 92583866 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92583866001 SSV-14 TO-15 HMH 61 PASI-M 92583866002 SSV-15 TO-15 HMH 61 PASI-M 92583866003 SSV-16 TO-15 HMH 61 PASI-M 92583866004 SSV-17 TO-15 MA 61 PASI-M 92583866005 SSV-18 TO-15 HMH 61 PASI-M 92583866006 SSV-19 TO-15 HMH 61 PASI-M 92583866007 SSV-20 TO-15 MA 61 PASI-M 92583866008 SSV-21 TO-15 MA 61 PASI-M 92583866009 SSV-22 TO-15 MA 61 PASI-M 92583866010 SSV-23 TO-15 MA 61 PASI-M 92583866011 SSV-23 Dup. TO-15 MA 61 PASI-M PASI-M = Pace Analytical Services - Minneapolis REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-14 Lab ID: 92583866001 Collected: 01/19/22 14:26 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone ND ug/m3 11.1 1.83 01/28/22 21:29 67-64-1 Benzene ND ug/m3 0.59 1.83 01/28/22 21:29 71-43-2 Benzyl chloride ND ug/m3 4.8 1.83 01/28/22 21:29 100-44-7 Bromodichloromethane ND ug/m3 2.5 1.83 01/28/22 21:29 75-27-4 Bromoform ND ug/m3 9.6 1.83 01/28/22 21:29 75-25-2 Bromomethane ND ug/m3 1.4 1.83 01/28/22 21:29 74-83-9 1,3-Butadiene ND ug/m3 0.82 1.83 01/28/22 21:29 106-99-0 2-Butanone (MEK) ND ug/m3 5.5 1.83 01/28/22 21:29 78-93-3 Carbon disulfide ND ug/m3 1.2 1.83 01/28/22 21:29 75-15-0 Carbon tetrachloride ND ug/m3 2.3 1.83 01/28/22 21:29 56-23-5 Chlorobenzene ND ug/m3 1.7 1.83 01/28/22 21:29 108-90-7 Chloroethane ND ug/m3 0.98 1.83 01/28/22 21:29 75-00-3 Chloroform ND ug/m3 0.91 1.83 01/28/22 21:29 67-66-3 Chloromethane ND ug/m3 0.77 1.83 01/28/22 21:29 74-87-3 Cyclohexane ND ug/m3 3.2 1.83 01/28/22 21:29 110-82-7 Dibromochloromethane ND ug/m3 3.2 1.83 01/28/22 21:29 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 1.4 1.83 01/28/22 21:29 106-93-4 1,2-Dichlorobenzene ND ug/m3 5.6 1.83 01/28/22 21:29 95-50-1 1,3-Dichlorobenzene ND ug/m3 5.6 1.83 01/28/22 21:29 541-73-1 1,4-Dichlorobenzene ND ug/m3 5.6 1.83 01/28/22 21:29 106-46-7 Dichlorodifluoromethane 2.9 ug/m3 1.8 1.83 01/28/22 21:29 75-71-8 1,1-Dichloroethane ND ug/m3 1.5 1.83 01/28/22 21:29 75-34-3 1,2-Dichloroethane ND ug/m3 1.5 1.83 01/28/22 21:29 107-06-2 1,1-Dichloroethene ND ug/m3 1.5 1.83 01/28/22 21:29 75-35-4 cis-1,2-Dichloroethene ND ug/m3 1.5 1.83 01/28/22 21:29 156-59-2 trans-1,2-Dichloroethene ND ug/m3 1.5 1.83 01/28/22 21:29 156-60-5 1,2-Dichloropropene ND ug/m3 1.7 1.83 01/28/22 21:29 78-87-5 cis-1,3-Dichloropropene ND ug/m3 4.2 1.83 01/28/22 21:29 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 4.2 1.83 01/28/22 21:29 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 2.6 1.83 01/28/22 21:29 76-14-2 Ethanol 12.9 ug/m3 3.5 1.83 01/28/22 21:29 64-17-5 Ethyl acetate ND ug/m3 1.3 1.83 01/28/22 21:29 141-78-6 Ethylbenzene ND ug/m3 1.6 1.83 01/28/22 21:29 100-41-4 4-Ethyltoluene ND ug/m3 4.6 1.83 01/28/22 21:29 622-96-8 n-Heptane ND ug/m3 1.5 1.83 01/28/22 21:29 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 9.9 1.83 01/28/22 21:29 87-68-3 n-Hexane ND ug/m3 1.3 1.83 01/28/22 21:29 110-54-3 2-Hexanone ND ug/m3 7.6 1.83 01/28/22 21:29 591-78-6 Methylene Chloride ND ug/m3 6.5 1.83 01/28/22 21:29 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 7.6 1.83 01/28/22 21:29 108-10-1 Methyl-tert-butyl ether ND ug/m3 6.7 1.83 01/28/22 21:29 1634-04-4 Naphthalene ND ug/m3 4.9 1.83 01/28/22 21:29 91-20-3 2-Propanol ND ug/m3 4.6 1.83 01/28/22 21:29 67-63-0 Propylene ND ug/m3 1.6 1.83 01/28/22 21:29 115-07-1 Styrene ND ug/m3 1.6 1.83 01/28/22 21:29 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 2.6 1.83 01/28/22 21:29 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-14 Lab ID: 92583866001 Collected: 01/19/22 14:26 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 10100 ug/m3 151 219.6 01/29/2214:44 127-18-4 Tetrahydrofuran 2.0 ug/m3 1.1 1.83 01/28/22 21:29 109-99-9 Toluene ND ug/m3 1.4 1.83 01/28/22 21:29 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 13.8 1.83 01/28/22 21:29 120-82-1 1,1,1-Trichloroethane ND ug/m3 2.0 1.83 01/28/22 21:29 71-55-6 1,1,2-Trichloroethane ND ug/m3 1.0 1.83 01/28/22 21:29 79-00-5 Trichloroethene 9.5 ug/m3 1.0 1.83 01/28/22 21:29 79-01-6 Trichlorofluoromethane ND ug/m3 2.1 1.83 01/28/22 21:29 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 2.9 1.83 01/28/22 21:29 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 1.8 1.83 01/28/22 21:29 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 1.8 1.83 01/28/22 21:29 108-67-8 Vinyl acetate ND ug/m3 1.3 1.83 01/28/22 21:29 108-05-4 Vinyl chloride ND ug/m3 0.48 1.83 01/28/22 21:29 75-01-4 m&p-Xylene ND ug/m3 3.2 1.83 01/28/22 21:29 179601-23-1 o-Xylene ND ug/m3 1.6 1.83 01/28/22 21:29 95-47-6 Date: 02/08/2022 06:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-15 Lab ID: 92583866002 Collected: 01/19/22 17:03 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone 112 ug/m3 9.7 1.61 01/28/22 21:57 67-64-1 Benzene ND ug/m3 0.52 1.61 01/28/22 21:57 71-43-2 Benzyl chloride ND ug/m3 4.2 1.61 01/28/22 21:57 100-44-7 Bromodichloromethane ND ug/m3 2.2 1.61 01/28/22 21:57 75-27-4 Bromoform ND ug/m3 8.5 1.61 01/28/22 21:57 75-25-2 Bromomethane ND ug/m3 1.3 1.61 01/28/22 21:57 74-83-9 1,3-Butadiene ND ug/m3 0.72 1.61 01/28/22 21:57 106-99-0 2-Butanone (MEK) 5.0 ug/m3 4.8 1.61 01/28/22 21:57 78-93-3 Carbon disulfide 3.0 ug/m3 1.0 1.61 01/28/22 21:57 75-15-0 Carbon tetrachloride ND ug/m3 2.1 1.61 01/28/22 21:57 56-23-5 Chlorobenzene ND ug/m3 1.5 1.61 01/28/22 21:57 108-90-7 Chloroethane ND ug/m3 0.86 1.61 01/28/22 21:57 75-00-3 Chloroform 2.9 ug/m3 0.80 1.61 01/28/22 21:57 67-66-3 Chloromethane ND ug/m3 0.68 1.61 01/28/22 21:57 74-87-3 Cyclohexane ND ug/m3 2.8 1.61 01/28/22 21:57 110-82-7 Dibromochloromethane ND ug/m3 2.8 1.61 01/28/22 21:57 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 1.3 1.61 01/28/22 21:57 106-93-4 1,2-Dichlorobenzene ND ug/m3 4.9 1.61 01/28/22 21:57 95-50-1 1,3-Dichlorobenzene ND ug/m3 4.9 1.61 01/28/22 21:57 541-73-1 1,4-Dichlorobenzene ND ug/m3 4.9 1.61 01/28/22 21:57 106-46-7 Dichlorodifluoromethane 2.7 ug/m3 1.6 1.61 01/28/22 21:57 75-71-8 1,1-Dichloroethane ND ug/m3 1.3 1.61 01/28/22 21:57 75-34-3 1,2-Dichloroethane ND ug/m3 1.3 1.61 01/28/22 21:57 107-06-2 1,1-Dichloroethene ND ug/m3 1.3 1.61 01/28/22 21:57 75-35-4 cis-1,2-Dichloroethene ND ug/m3 1.3 1.61 01/28/22 21:57 156-59-2 trans-1,2-Dichloroethene ND ug/m3 1.3 1.61 01/28/22 21:57 156-60-5 1,2-Dichloropropene ND ug/m3 1.5 1.61 01/28/22 21:57 78-87-5 cis-1,3-Dichloropropene ND ug/m3 3.7 1.61 01/28/22 21:57 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 3.7 1.61 01/28/22 21:57 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 2.3 1.61 01/28/22 21:57 76-14-2 Ethanol 174 ug/m3 3.1 1.61 01/28/22 21:57 64-17-5 Ethyl acetate ND ug/m3 1.2 1.61 01/28/22 21:57 141-78-6 Ethylbenzene ND ug/m3 1.4 1.61 01/28/22 21:57 100-41-4 4-Ethyltoluene ND ug/m3 4.0 1.61 01/28/22 21:57 622-96-8 n-Heptane 1.6 ug/m3 1.3 1.61 01/28/22 21:57 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 8.7 1.61 01/28/22 21:57 87-68-3 n-Hexane 3.0 ug/m3 1.2 1.61 01/28/22 21:57 110-54-3 2-Hexanone ND ug/m3 6.7 1.61 01/28/22 21:57 591-78-6 Methylene Chloride ND ug/m3 5.7 1.61 01/28/22 21:57 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 6.7 1.61 01/28/22 21:57 108-10-1 Methyl-tert-butyl ether ND ug/m3 5.9 1.61 01/28/22 21:57 1634-04-4 Naphthalene ND ug/m3 4.3 1.61 01/28/22 21:57 91-20-3 2-Propanol 4.5 ug/m3 4.0 1.61 01/28/22 21:57 67-63-0 Propylene 10.8 ug/m3 1.4 1.61 01/28/22 21:57 115-07-1 Styrene 3.0 ug/m3 1.4 1.61 01/28/22 21:57 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 2.3 1.61 01/28/22 21:57 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-15 Lab ID: 92583866002 Collected: 01/19/22 17:03 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 254 ug/m3 1.1 1.61 01/31/2214:57 127-18-4 Tetrahydrofuran ND ug/m3 0.97 1.61 01/28/22 21:57 109-99-9 Toluene ND ug/m3 1.2 1.61 01/28/22 21:57 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 12.1 1.61 01/28/22 21:57 120-82-1 1,1,1-Trichloroethane ND ug/m3 1.8 1.61 01/28/22 21:57 71-55-6 1,1,2-Trichloroethane ND ug/m3 0.89 1.61 01/28/22 21:57 79-00-5 Trichloroethene ND ug/m3 0.88 1.61 01/28/22 21:57 79-01-6 Trichlorofluoromethane 4.1 ug/m3 1.8 1.61 01/28/22 21:57 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 2.5 1.61 01/28/22 21:57 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 1.6 1.61 01/28/22 21:57 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 1.6 1.61 01/28/22 21:57 108-67-8 Vinyl acetate ND ug/m3 1.2 1.61 01/28/22 21:57 108-05-4 Vinyl chloride ND ug/m3 0.42 1.61 01/28/22 21:57 75-01-4 m&p-Xylene ND ug/m3 2.8 1.61 01/28/22 21:57 179601-23-1 o-Xylene ND ug/m3 1.4 1.61 01/28/22 21:57 95-47-6 Date: 02/08/2022 06:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-16 Lab ID: 92583866003 Collected: 01/19/22 16:00 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone 29.1 ug/m3 10.6 1.75 01/28/22 22:26 67-64-1 Benzene ND ug/m3 0.57 1.75 01/28/22 22:26 71-43-2 Benzyl chloride ND ug/m3 4.6 1.75 01/28/22 22:26 100-44-7 Bromodichloromethane ND ug/m3 2.4 1.75 01/28/22 22:26 75-27-4 Bromoform ND ug/m3 9.2 1.75 01/28/22 22:26 75-25-2 Bromomethane ND ug/m3 1.4 1.75 01/28/22 22:26 74-83-9 1,3-Butadiene ND ug/m3 0.79 1.75 01/28/22 22:26 106-99-0 2-Butanone (MEK) ND ug/m3 5.2 1.75 01/28/22 22:26 78-93-3 Carbon disulfide ND ug/m3 1.1 1.75 01/28/22 22:26 75-15-0 Carbon tetrachloride ND ug/m3 2.2 1.75 01/28/22 22:26 56-23-5 Chlorobenzene ND ug/m3 1.6 1.75 01/28/22 22:26 108-90-7 Chloroethane ND ug/m3 0.94 1.75 01/28/22 22:26 75-00-3 Chloroform ND ug/m3 0.87 1.75 01/28/22 22:26 67-66-3 Chloromethane ND ug/m3 0.74 1.75 01/28/22 22:26 74-87-3 Cyclohexane ND ug/m3 3.1 1.75 01/28/22 22:26 110-82-7 Dibromochloromethane ND ug/m3 3.0 1.75 01/28/22 22:26 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 1.4 1.75 01/28/22 22:26 106-93-4 1,2-Dichlorobenzene ND ug/m3 5.4 1.75 01/28/22 22:26 95-50-1 1,3-Dichlorobenzene ND ug/m3 5.4 1.75 01/28/22 22:26 541-73-1 1,4-Dichlorobenzene ND ug/m3 5.4 1.75 01/28/22 22:26 106-46-7 Dichlorodifluoromethane 4.0 ug/m3 1.8 1.75 01/28/22 22:26 75-71-8 1,1-Dichloroethane ND ug/m3 1.4 1.75 01/28/22 22:26 75-34-3 1,2-Dichloroethane ND ug/m3 1.4 1.75 01/28/22 22:26 107-06-2 1,1-Dichloroethene ND ug/m3 1.4 1.75 01/28/22 22:26 75-35-4 cis-1,2-Dichloroethene ND ug/m3 1.4 1.75 01/28/22 22:26 156-59-2 trans-1,2-Dichloroethene ND ug/m3 1.4 1.75 01/28/22 22:26 156-60-5 1,2-Dichloropropene ND ug/m3 1.6 1.75 01/28/22 22:26 78-87-5 cis-1,3-Dichloropropene ND ug/m3 4.0 1.75 01/28/22 22:26 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 4.0 1.75 01/28/22 22:26 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 2.5 1.75 01/28/22 22:26 76-14-2 Ethanol 167 ug/m3 3.4 1.75 01/28/22 22:26 64-17-5 Ethyl acetate ND ug/m3 1.3 1.75 01/28/22 22:26 141-78-6 Ethylbenzene ND ug/m3 1.5 1.75 01/28/22 22:26 100-41-4 4-Ethyltoluene ND ug/m3 4.4 1.75 01/28/22 22:26 622-96-8 n-Heptane ND ug/m3 1.5 1.75 01/28/22 22:26 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 9.5 1.75 01/28/22 22:26 87-68-3 n-Hexane ND ug/m3 1.3 1.75 01/28/22 22:26 110-54-3 2-Hexanone ND ug/m3 7.3 1.75 01/28/22 22:26 591-78-6 Methylene Chloride ND ug/m3 6.2 1.75 01/28/22 22:26 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 7.3 1.75 01/28/22 22:26 108-10-1 Methyl-tert-butyl ether ND ug/m3 6.4 1.75 01/28/22 22:26 1634-04-4 Naphthalene ND ug/m3 4.7 1.75 01/28/22 22:26 91-20-3 2-Propanol 10.4 ug/m3 4.4 1.75 01/28/22 22:26 67-63-0 Propylene ND ug/m3 1.5 1.75 01/28/22 22:26 115-07-1 Styrene ND ug/m3 1.5 1.75 01/28/22 22:26 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 2.4 1.75 01/28/22 22:26 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-16 Lab ID: 92583866003 Collected: 01/19/22 16:00 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 1160 ug/m3 12.1 17.5 01/29/2213:51 127-18-4 Tetrahydrofuran 3.0 ug/m3 1.0 1.75 01/28/22 22:26 109-99-9 Toluene ND ug/m3 1.3 1.75 01/28/22 22:26 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 13.2 1.75 01/28/22 22:26 120-82-1 1,1,1-Trichloroethane ND ug/m3 1.9 1.75 01/28/22 22:26 71-55-6 1,1,2-Trichloroethane ND ug/m3 0.97 1.75 01/28/22 22:26 79-00-5 Trichloroethene ND ug/m3 0.96 1.75 01/28/22 22:26 79-01-6 Trichlorofluoromethane ND ug/m3 2.0 1.75 01/28/22 22:26 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 2.7 1.75 01/28/22 22:26 76-13-1 1,2,4-Trimethylbenzene 14.8 ug/m3 1.7 1.75 01/28/22 22:26 95-63-6 1,3,5-Trimethylbenzene 2.7 ug/m3 1.7 1.75 01/28/22 22:26 108-67-8 Vinyl acetate ND ug/m3 1.3 1.75 01/28/22 22:26 108-05-4 Vinyl chloride ND ug/m3 0.46 1.75 01/28/22 22:26 75-01-4 m&p-Xylene ND ug/m3 3.1 1.75 01/28/22 22:26 179601-23-1 o-Xylene ND ug/m3 1.5 1.75 01/28/22 22:26 95-47-6 Date: 02/08/2022 06:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-17 Lab ID: 92583866004 Collected: 01/19/22 15:23 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone ND ug/m3 2650 439.2 02/02/22 17:30 67-64-1 Benzene ND ug/m3 143 439.2 02/02/22 17:30 71-43-2 Benzyl chloride ND ug/m3 2310 439.2 02/02/22 17:30 100-44-7 Bromodichloromethane ND ug/m3 597 439.2 02/02/22 17:30 75-27-4 Bromoform ND ug/m3 2310 439.2 02/02/22 17:30 75-25-2 Bromomethane ND ug/m3 347 439.2 02/02/22 17:30 74-83-9 1,3-Butadiene ND ug/m3 198 439.2 02/02/22 17:30 106-99-0 2-Butanone (MEK) ND ug/m3 1320 439.2 02/02/22 17:30 78-93-3 Carbon disulfide ND ug/m3 278 439.2 02/02/22 17:30 75-15-0 Carbon tetrachloride ND ug/m3 562 439.2 02/02/22 17:30 56-23-5 Chlorobenzene ND ug/m3 411 439.2 02/02/22 17:30 108-90-7 Chloroethane ND ug/m3 589 439.2 02/02/22 17:30 75-00-3 Chloroform ND ug/m3 218 439.2 02/02/22 17:30 67-66-3 Chloromethane ND ug/m3 184 439.2 02/02/22 17:30 74-87-3 Cyclohexane ND ug/m3 769 439.2 02/02/22 17:30 110-82-7 Dibromochloromethane ND ug/m3 760 439.2 02/02/22 17:30 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 343 439.2 02/02/22 17:30 106-93-4 1,2-Dichlorobenzene ND ug/m3 1340 439.2 02/02/22 17:30 95-50-1 1,3-Dichlorobenzene ND ug/m3 1340 439.2 02/02/22 17:30 541-73-1 1,4-Dichlorobenzene ND ug/m3 1340 439.2 02/02/22 17:30 106-46-7 Dichlorodifluoromethane ND ug/m3 444 439.2 02/02/22 17:30 75-71-8 1,1-Dichloroethane ND ug/m3 361 439.2 02/02/22 17:30 75-34-3 1,2-Dichloroethane ND ug/m3 361 439.2 02/02/22 17:30 107-06-2 1,1-Dichloroethene ND ug/m3 354 439.2 02/02/22 17:30 75-35-4 cis-1,2-Dichloroethene ND ug/m3 354 439.2 02/02/22 17:30 156-59-2 trans-1,2-Dichloroethene ND ug/m3 354 439.2 02/02/22 17:30 156-60-5 1,2-Dichloropropene ND ug/m3 412 439.2 02/02/22 17:30 78-87-5 cis-1,3-Dichloropropene ND ug/m3 1010 439.2 02/02/22 17:30 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 1010 439.2 02/02/22 17:30 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 624 439.2 02/02/22 17:30 76-14-2 Ethanol ND ug/m3 843 439.2 02/02/22 17:30 64-17-5 Ethyl acetate ND ug/m3 322 439.2 02/02/22 17:30 141-78-6 Ethylbenzene ND ug/m3 388 439.2 02/02/22 17:30 100-41-4 4-Ethyltoluene ND ug/m3 1100 439.2 02/02/22 17:30 622-96-8 n-Heptane ND ug/m3 366 439.2 02/02/22 17:30 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 2380 439.2 02/02/22 17:30 87-68-3 n-Hexane ND ug/m3 314 439.2 02/02/22 17:30 110-54-3 2-Hexanone ND ug/m3 1830 439.2 02/02/22 17:30 591-78-6 Methylene Chloride ND ug/m3 1550 439.2 02/02/22 17:30 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 1830 439.2 02/02/22 17:30 108-10-1 Methyl-tert-butyl ether ND ug/m3 1610 439.2 02/02/22 17:30 1634-04-4 Naphthalene ND ug/m3 2340 439.2 02/02/22 17:30 91-20-3 2-Propanol ND ug/m3 1100 439.2 02/02/22 17:30 67-63-0 Propylene ND ug/m3 384 439.2 02/02/22 17:30 115-07-1 Styrene ND ug/m3 951 439.2 02/02/22 17:30 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 615 439.2 02/02/22 17:30 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-17 Lab ID: 92583866004 Collected: 01/19/22 15:23 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 10500 ug/m3 303 439.2 02/02/22 17:30 127-18-4 Tetrahydrofuran ND ug/m3 264 439.2 02/02/22 17:30 109-99-9 Toluene ND ug/m3 336 439.2 02/02/22 17:30 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 6630 439.2 02/02/22 17:30 120-82-1 1,1,1-Trichloroethane ND ug/m3 488 439.2 02/02/22 17:30 71-55-6 1,1,2-Trichloroethane ND ug/m3 244 439.2 02/02/22 17:30 79-00-5 Trichloroethene ND ug/m3 240 439.2 02/02/22 17:30 79-01-6 Trichlorofluoromethane ND ug/m3 501 439.2 02/02/22 17:30 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 685 439.2 02/02/22 17:30 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 439 439.2 02/02/22 17:30 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 439 439.2 02/02/22 17:30 108-67-8 Vinyl acetate ND ug/m3 314 439.2 02/02/22 17:30 108-05-4 Vinyl chloride ND ug/m3 114 439.2 02/02/22 17:30 75-01-4 m&p-Xylene ND ug/m3 777 439.2 02/02/22 17:30 179601-23-1 o-Xylene ND ug/m3 388 439.2 02/02/22 17:30 95-47-6 Date: 02/08/2022 06:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-18 Lab ID: 92583866005 Collected: 01/19/22 15:00 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone 40.4 ug/m3 11.1 1.83 01/28/22 23:24 67-64-1 Benzene ND ug/m3 0.59 1.83 01/28/22 23:24 71-43-2 Benzyl chloride ND ug/m3 4.8 1.83 01/28/22 23:24 100-44-7 Bromodichloromethane ND ug/m3 2.5 1.83 01/28/22 23:24 75-27-4 Bromoform ND ug/m3 9.6 1.83 01/28/22 23:24 75-25-2 Bromomethane ND ug/m3 1.4 1.83 01/28/22 23:24 74-83-9 1,3-Butadiene ND ug/m3 0.82 1.83 01/28/22 23:24 106-99-0 2-Butanone (MEK) 5.8 ug/m3 5.5 1.83 01/28/22 23:24 78-93-3 Carbon disulfide ND ug/m3 1.2 1.83 01/28/22 23:24 75-15-0 Carbon tetrachloride ND ug/m3 2.3 1.83 01/28/22 23:24 56-23-5 Chlorobenzene ND ug/m3 1.7 1.83 01/28/22 23:24 108-90-7 Chloroethane ND ug/m3 0.98 1.83 01/28/22 23:24 75-00-3 Chloroform ND ug/m3 0.91 1.83 01/28/22 23:24 67-66-3 Chloromethane ND ug/m3 0.77 1.83 01/28/22 23:24 74-87-3 Cyclohexane ND ug/m3 3.2 1.83 01/28/22 23:24 110-82-7 Dibromochloromethane ND ug/m3 3.2 1.83 01/28/22 23:24 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 1.4 1.83 01/28/22 23:24 106-93-4 1,2-Dichlorobenzene ND ug/m3 5.6 1.83 01/28/22 23:24 95-50-1 1,3-Dichlorobenzene ND ug/m3 5.6 1.83 01/28/22 23:24 541-73-1 1,4-Dichlorobenzene ND ug/m3 5.6 1.83 01/28/22 23:24 106-46-7 Dichlorodifluoromethane 2.8 ug/m3 1.8 1.83 01/28/22 23:24 75-71-8 1,1-Dichloroethane ND ug/m3 1.5 1.83 01/28/22 23:24 75-34-3 1,2-Dichloroethane ND ug/m3 1.5 1.83 01/28/22 23:24 107-06-2 1,1-Dichloroethene ND ug/m3 1.5 1.83 01/28/22 23:24 75-35-4 cis-1,2-Dichloroethene ND ug/m3 1.5 1.83 01/28/22 23:24 156-59-2 trans-1,2-Dichloroethene ND ug/m3 1.5 1.83 01/28/22 23:24 156-60-5 1,2-Dichloropropene ND ug/m3 1.7 1.83 01/28/22 23:24 78-87-5 cis-1,3-Dichloropropene ND ug/m3 4.2 1.83 01/28/22 23:24 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 4.2 1.83 01/28/22 23:24 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 2.6 1.83 01/28/22 23:24 76-14-2 Ethanol 175 ug/m3 3.5 1.83 01/28/22 23:24 64-17-5 Ethyl acetate ND ug/m3 1.3 1.83 01/28/22 23:24 141-78-6 Ethylbenzene ND ug/m3 1.6 1.83 01/28/22 23:24 100-41-4 4-Ethyltoluene ND ug/m3 4.6 1.83 01/28/22 23:24 622-96-8 n-Heptane ND ug/m3 1.5 1.83 01/28/22 23:24 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 9.9 1.83 01/28/22 23:24 87-68-3 n-Hexane ND ug/m3 1.3 1.83 01/28/22 23:24 110-54-3 2-Hexanone ND ug/m3 7.6 1.83 01/28/22 23:24 591-78-6 Methylene Chloride ND ug/m3 6.5 1.83 01/28/22 23:24 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 7.6 1.83 01/28/22 23:24 108-10-1 Methyl-tert-butyl ether ND ug/m3 6.7 1.83 01/28/22 23:24 1634-04-4 Naphthalene ND ug/m3 4.9 1.83 01/28/22 23:24 91-20-3 2-Propanol 4.8 ug/m3 4.6 1.83 01/28/22 23:24 67-63-0 Propylene ND ug/m3 1.6 1.83 01/28/22 23:24 115-07-1 Styrene ND ug/m3 1.6 1.83 01/28/22 23:24 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 2.6 1.83 01/28/22 23:24 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-18 Lab ID: 92583866005 Collected: 01/19/22 15:00 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 105 ug/m3 1.3 1.83 01/31/2215:31 127-18-4 Tetrahydrofuran ND ug/m3 1.1 1.83 01/28/22 23:24 109-99-9 Toluene ND ug/m3 1.4 1.83 01/28/22 23:24 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 13.8 1.83 01/28/22 23:24 120-82-1 1,1,1-Trichloroethane ND ug/m3 2.0 1.83 01/28/22 23:24 71-55-6 1,1,2-Trichloroethane ND ug/m3 1.0 1.83 01/28/22 23:24 79-00-5 Trichloroethene ND ug/m3 1.0 1.83 01/28/22 23:24 79-01-6 Trichlorofluoromethane ND ug/m3 2.1 1.83 01/28/22 23:24 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 2.9 1.83 01/28/22 23:24 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 1.8 1.83 01/28/22 23:24 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 1.8 1.83 01/28/22 23:24 108-67-8 Vinyl acetate ND ug/m3 1.3 1.83 01/28/22 23:24 108-05-4 Vinyl chloride ND ug/m3 0.48 1.83 01/28/22 23:24 75-01-4 m&p-Xylene ND ug/m3 3.2 1.83 01/28/22 23:24 179601-23-1 o-Xylene ND ug/m3 1.6 1.83 01/28/22 23:24 95-47-6 Date: 02/08/2022 06:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-19 Lab ID: 92583866006 Collected: 01/19/22 14:17 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone 73.5 ug/m3 10.6 1.75 01/28/22 23:52 67-64-1 Benzene ND ug/m3 0.57 1.75 01/28/22 23:52 71-43-2 Benzyl chloride ND ug/m3 4.6 1.75 01/28/22 23:52 100-44-7 Bromodichloromethane ND ug/m3 2.4 1.75 01/28/22 23:52 75-27-4 Bromoform ND ug/m3 9.2 1.75 01/28/22 23:52 75-25-2 Bromomethane ND ug/m3 1.4 1.75 01/28/22 23:52 74-83-9 1,3-Butadiene ND ug/m3 0.79 1.75 01/28/22 23:52 106-99-0 2-Butanone (MEK) 13.5 ug/m3 5.2 1.75 01/28/22 23:52 78-93-3 Carbon disulfide ND ug/m3 1.1 1.75 01/28/22 23:52 75-15-0 Carbon tetrachloride ND ug/m3 2.2 1.75 01/28/22 23:52 56-23-5 Chlorobenzene ND ug/m3 1.6 1.75 01/28/22 23:52 108-90-7 Chloroethane ND ug/m3 0.94 1.75 01/28/22 23:52 75-00-3 Chloroform 3.4 ug/m3 0.87 1.75 01/28/22 23:52 67-66-3 Chloromethane ND ug/m3 0.74 1.75 01/28/22 23:52 74-87-3 Cyclohexane ND ug/m3 3.1 1.75 01/28/22 23:52 110-82-7 Dibromochloromethane ND ug/m3 3.0 1.75 01/28/22 23:52 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 1.4 1.75 01/28/22 23:52 106-93-4 1,2-Dichlorobenzene ND ug/m3 5.4 1.75 01/28/22 23:52 95-50-1 1,3-Dichlorobenzene ND ug/m3 5.4 1.75 01/28/22 23:52 541-73-1 1,4-Dichlorobenzene ND ug/m3 5.4 1.75 01/28/22 23:52 106-46-7 Dichlorodifluoromethane 3.1 ug/m3 1.8 1.75 01/28/22 23:52 75-71-8 1,1-Dichloroethane ND ug/m3 1.4 1.75 01/28/22 23:52 75-34-3 1,2-Dichloroethane ND ug/m3 1.4 1.75 01/28/22 23:52 107-06-2 1,1-Dichloroethene ND ug/m3 1.4 1.75 01/28/22 23:52 75-35-4 cis-1,2-Dichloroethene ND ug/m3 1.4 1.75 01/28/22 23:52 156-59-2 trans-1,2-Dichloroethene ND ug/m3 1.4 1.75 01/28/22 23:52 156-60-5 1,2-Dichloropropene ND ug/m3 1.6 1.75 01/28/22 23:52 78-87-5 cis-1,3-Dichloropropene ND ug/m3 4.0 1.75 01/28/22 23:52 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 4.0 1.75 01/28/22 23:52 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 2.5 1.75 01/28/22 23:52 76-14-2 Ethanol 220 ug/m3 3.4 1.75 01/28/22 23:52 64-17-5 Ethyl acetate 7.6 ug/m3 1.3 1.75 01/28/22 23:52 141-78-6 Ethylbenzene ND ug/m3 1.5 1.75 01/28/22 23:52 100-41-4 4-Ethyltoluene ND ug/m3 4.4 1.75 01/28/22 23:52 622-96-8 n-Heptane ND ug/m3 1.5 1.75 01/28/22 23:52 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 9.5 1.75 01/28/22 23:52 87-68-3 n-Hexane 1.8 ug/m3 1.3 1.75 01/28/22 23:52 110-54-3 2-Hexanone ND ug/m3 7.3 1.75 01/28/22 23:52 591-78-6 Methylene Chloride ND ug/m3 6.2 1.75 01/28/22 23:52 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 7.3 1.75 01/28/22 23:52 108-10-1 Methyl-tert-butyl ether ND ug/m3 6.4 1.75 01/28/22 23:52 1634-04-4 Naphthalene ND ug/m3 4.7 1.75 01/28/22 23:52 91-20-3 2-Propanol 30.1 ug/m3 4.4 1.75 01/28/22 23:52 67-63-0 Propylene ND ug/m3 1.5 1.75 01/28/22 23:52 115-07-1 Styrene ND ug/m3 1.5 1.75 01/28/22 23:52 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 2.4 1.75 01/28/22 23:52 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-19 Lab ID: 92583866006 Collected: 01/19/22 14:17 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 4020 ug/m3 36.2 52.5 01/29/2214:18 127-18-4 Tetrahydrofuran ND ug/m3 1.0 1.75 01/28/22 23:52 109-99-9 Toluene ND ug/m3 1.3 1.75 01/28/22 23:52 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 13.2 1.75 01/28/22 23:52 120-82-1 1,1,1-Trichloroethane ND ug/m3 1.9 1.75 01/28/22 23:52 71-55-6 1,1,2-Trichloroethane ND ug/m3 0.97 1.75 01/28/22 23:52 79-00-5 Trichloroethene ND ug/m3 0.96 1.75 01/28/22 23:52 79-01-6 Trichlorofluoromethane ND ug/m3 2.0 1.75 01/28/22 23:52 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 2.7 1.75 01/28/22 23:52 76-13-1 1,2,4-Trimethylbenzene 8.6 ug/m3 1.7 1.75 01/28/22 23:52 95-63-6 1,3,5-Trimethylbenzene 3.1 ug/m3 1.7 1.75 01/28/22 23:52 108-67-8 Vinyl acetate ND ug/m3 1.3 1.75 01/28/22 23:52 108-05-4 Vinyl chloride ND ug/m3 0.46 1.75 01/28/22 23:52 75-01-4 m&p-Xylene ND ug/m3 3.1 1.75 01/28/22 23:52 179601-23-1 o-Xylene ND ug/m3 1.5 1.75 01/28/22 23:52 95-47-6 Date: 02/08/2022 06:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-20 Lab ID: 92583866007 Collected: 01/19/22 14:03 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone ND ug/m3 211 35 02/02/22 15:56 67-64-1 Benzene ND ug/m3 11.4 35 02/02/22 15:56 71-43-2 Benzyl chloride ND ug/m3 184 35 02/02/22 15:56 100-44-7 Bromodichloromethane ND ug/m3 47.6 35 02/02/22 15:56 75-27-4 Bromoform ND ug/m3 184 35 02/02/22 15:56 75-25-2 Bromomethane ND ug/m3 27.6 35 02/02/22 15:56 74-83-9 1,3-Butadiene ND ug/m3 15.8 35 02/02/22 15:56 106-99-0 2-Butanone (MEK) ND ug/m3 105 35 02/02/22 15:56 78-93-3 Carbon disulfide ND ug/m3 22.2 35 02/02/22 15:56 75-15-0 Carbon tetrachloride ND ug/m3 44.8 35 02/02/22 15:56 56-23-5 Chlorobenzene ND ug/m3 32.8 35 02/02/22 15:56 108-90-7 Chloroethane ND ug/m3 46.9 35 02/02/22 15:56 75-00-3 Chloroform ND ug/m3 17.4 35 02/02/22 15:56 67-66-3 Chloromethane ND ug/m3 14.7 35 02/02/22 15:56 74-87-3 Cyclohexane ND ug/m3 61.2 35 02/02/22 15:56 110-82-7 Dibromochloromethane ND ug/m3 60.6 35 02/02/22 15:56 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 27.3 35 02/02/22 15:56 106-93-4 1,2-Dichlorobenzene ND ug/m3 107 35 02/02/22 15:56 95-50-1 1,3-Dichlorobenzene ND ug/m3 107 35 02/02/22 15:56 541-73-1 1,4-Dichlorobenzene ND ug/m3 107 35 02/02/22 15:56 106-46-7 Dichlorodifluoromethane ND ug/m3 35.4 35 02/02/22 15:56 75-71-8 1,1-Dichloroethane ND ug/m3 28.8 35 02/02/22 15:56 75-34-3 1,2-Dichloroethane ND ug/m3 28.8 35 02/02/22 15:56 107-06-2 1,1-Dichloroethene ND ug/m3 28.2 35 02/02/22 15:56 75-35-4 cis-1,2-Dichloroethene ND ug/m3 28.2 35 02/02/22 15:56 156-59-2 trans-1,2-Dichloroethene ND ug/m3 28.2 35 02/02/22 15:56 156-60-5 1,2-Dichloropropene ND ug/m3 32.9 35 02/02/22 15:56 78-87-5 cis-1,3-Dichloropropene ND ug/m3 80.8 35 02/02/22 15:56 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 80.8 35 02/02/22 15:56 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 49.7 35 02/02/22 15:56 76-14-2 Ethanol ND ug/m3 67.2 35 02/02/22 15:56 64-17-5 Ethyl acetate ND ug/m3 25.7 35 02/02/22 15:56 141-78-6 Ethylbenzene ND ug/m3 30.9 35 02/02/22 15:56 100-41-4 4-Ethyltoluene ND ug/m3 87.5 35 02/02/22 15:56 622-96-8 n-Heptane ND ug/m3 29.2 35 02/02/22 15:56 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 190 35 02/02/22 15:56 87-68-3 n-Hexane ND ug/m3 25.1 35 02/02/22 15:56 110-54-3 2-Hexanone ND ug/m3 146 35 02/02/22 15:56 591-78-6 Methylene Chloride ND ug/m3 124 35 02/02/22 15:56 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 146 35 02/02/22 15:56 108-10-1 Methyl-tert-butyl ether ND ug/m3 128 35 02/02/22 15:56 1634-04-4 Naphthalene ND ug/m3 186 35 02/02/22 15:56 91-20-3 2-Propanol ND ug/m3 87.5 35 02/02/22 15:56 67-63-0 Propylene ND ug/m3 30.6 35 02/02/22 15:56 115-07-1 Styrene ND ug/m3 75.8 35 02/02/22 15:56 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 49.0 35 02/02/22 15:56 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-20 Lab ID: 92583866007 Collected: 01/19/22 14:03 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 1300 ug/m3 24.1 35 02/02/22 15:56 127-18-4 Tetrahydrofuran ND ug/m3 21.0 35 02/02/22 15:56 109-99-9 Toluene ND ug/m3 26.8 35 02/02/22 15:56 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 528 35 02/02/22 15:56 120-82-1 1,1,1-Trichloroethane ND ug/m3 38.8 35 02/02/22 15:56 71-55-6 1,1,2-Trichloroethane ND ug/m3 19.4 35 02/02/22 15:56 79-00-5 Trichloroethene ND ug/m3 19.1 35 02/02/22 15:56 79-01-6 Trichlorofluoromethane ND ug/m3 39.9 35 02/02/22 15:56 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 54.6 35 02/02/22 15:56 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 35.0 35 02/02/22 15:56 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 35.0 35 02/02/22 15:56 108-67-8 Vinyl acetate ND ug/m3 25.1 35 02/02/22 15:56 108-05-4 Vinyl chloride ND ug/m3 9.1 35 02/02/22 15:56 75-01-4 m&p-Xylene ND ug/m3 62.0 35 02/02/22 15:56 179601-23-1 o-Xylene ND ug/m3 30.9 35 02/02/22 15:56 95-47-6 Date: 02/08/2022 06:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-21 Lab ID: 92583866008 Collected: 01/19/22 12:55 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone ND ug/m3 971 160.8 02/02/22 16:59 67-64-1 Benzene ND ug/m3 52.3 160.8 02/02/22 16:59 71-43-2 Benzyl chloride ND ug/m3 846 160.8 02/02/22 16:59 100-44-7 Bromodichloromethane ND ug/m3 219 160.8 02/02/22 16:59 75-27-4 Bromoform ND ug/m3 844 160.8 02/02/22 16:59 75-25-2 Bromomethane ND ug/m3 127 160.8 02/02/22 16:59 74-83-9 1,3-Butadiene ND ug/m3 72.4 160.8 02/02/22 16:59 106-99-0 2-Butanone (MEK) ND ug/m3 482 160.8 02/02/22 16:59 78-93-3 Carbon disulfide ND ug/m3 102 160.8 02/02/22 16:59 75-15-0 Carbon tetrachloride ND ug/m3 206 160.8 02/02/22 16:59 56-23-5 Chlorobenzene ND ug/m3 151 160.8 02/02/22 16:59 108-90-7 Chloroethane ND ug/m3 216 160.8 02/02/22 16:59 75-00-3 Chloroform ND ug/m3 79.8 160.8 02/02/22 16:59 67-66-3 Chloromethane ND ug/m3 67.5 160.8 02/02/22 16:59 74-87-3 Cyclohexane ND ug/m3 281 160.8 02/02/22 16:59 110-82-7 Dibromochloromethane ND ug/m3 278 160.8 02/02/22 16:59 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 126 160.8 02/02/22 16:59 106-93-4 1,2-Dichlorobenzene ND ug/m3 492 160.8 02/02/22 16:59 95-50-1 1,3-Dichlorobenzene ND ug/m3 492 160.8 02/02/22 16:59 541-73-1 1,4-Dichlorobenzene ND ug/m3 492 160.8 02/02/22 16:59 106-46-7 Dichlorodifluoromethane ND ug/m3 162 160.8 02/02/22 16:59 75-71-8 1,1-Dichloroethane ND ug/m3 132 160.8 02/02/22 16:59 75-34-3 1,2-Dichloroethane ND ug/m3 132 160.8 02/02/22 16:59 107-06-2 1,1-Dichloroethene ND ug/m3 130 160.8 02/02/22 16:59 75-35-4 cis-1,2-Dichloroethene ND ug/m3 130 160.8 02/02/22 16:59 156-59-2 trans-1,2-Dichloroethene ND ug/m3 130 160.8 02/02/22 16:59 156-60-5 1,2-Dichloropropene ND ug/m3 151 160.8 02/02/22 16:59 78-87-5 cis-1,3-Dichloropropene ND ug/m3 371 160.8 02/02/22 16:59 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 371 160.8 02/02/22 16:59 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 228 160.8 02/02/22 16:59 76-14-2 Ethanol ND ug/m3 309 160.8 02/02/22 16:59 64-17-5 Ethyl acetate ND ug/m3 118 160.8 02/02/22 16:59 141-78-6 Ethylbenzene ND ug/m3 142 160.8 02/02/22 16:59 100-41-4 4-Ethyltoluene ND ug/m3 402 160.8 02/02/22 16:59 622-96-8 n-Heptane ND ug/m3 134 160.8 02/02/22 16:59 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 872 160.8 02/02/22 16:59 87-68-3 n-Hexane ND ug/m3 115 160.8 02/02/22 16:59 110-54-3 2-Hexanone ND ug/m3 669 160.8 02/02/22 16:59 591-78-6 Methylene Chloride ND ug/m3 568 160.8 02/02/22 16:59 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 669 160.8 02/02/22 16:59 108-10-1 Methyl-tert-butyl ether ND ug/m3 589 160.8 02/02/22 16:59 1634-04-4 Naphthalene ND ug/m3 857 160.8 02/02/22 16:59 91-20-3 2-Propanol ND ug/m3 402 160.8 02/02/22 16:59 67-63-0 Propylene ND ug/m3 141 160.8 02/02/22 16:59 115-07-1 Styrene ND ug/m3 348 160.8 02/02/22 16:59 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 225 160.8 02/02/22 16:59 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-21 Lab ID: 92583866008 Collected: 01/19/22 12:55 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 3750 ug/m3 111 160.8 02/02/22 16:59 127-18-4 Tetrahydrofuran ND ug/m3 96.5 160.8 02/02/22 16:59 109-99-9 Toluene ND ug/m3 123 160.8 02/02/22 16:59 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 2430 160.8 02/02/22 16:59 120-82-1 1,1,1-Trichloroethane ND ug/m3 178 160.8 02/02/22 16:59 71-55-6 1,1,2-Trichloroethane ND ug/m3 89.2 160.8 02/02/22 16:59 79-00-5 Trichloroethene ND ug/m3 87.8 160.8 02/02/22 16:59 79-01-6 Trichlorofluoromethane ND ug/m3 183 160.8 02/02/22 16:59 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 251 160.8 02/02/22 16:59 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 161 160.8 02/02/22 16:59 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 161 160.8 02/02/22 16:59 108-67-8 Vinyl acetate ND ug/m3 115 160.8 02/02/22 16:59 108-05-4 Vinyl chloride ND ug/m3 41.8 160.8 02/02/22 16:59 75-01-4 m&p-Xylene ND ug/m3 285 160.8 02/02/22 16:59 179601-23-1 o-Xylene ND ug/m3 142 160.8 02/02/22 16:59 95-47-6 Date: 02/08/2022 06:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-22 Lab ID: 92583866009 Collected: 01/19/22 11:39 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone ND ug/m3 317 52.5 02/02/22 16:28 67-64-1 Benzene ND ug/m3 17.1 52.5 02/02/22 16:28 71-43-2 Benzyl chloride ND ug/m3 276 52.5 02/02/22 16:28 100-44-7 Bromodichloromethane ND ug/m3 71.4 52.5 02/02/22 16:28 75-27-4 Bromoform ND ug/m3 276 52.5 02/02/22 16:28 75-25-2 Bromomethane ND ug/m3 41.4 52.5 02/02/22 16:28 74-83-9 1,3-Butadiene ND ug/m3 23.6 52.5 02/02/22 16:28 106-99-0 2-Butanone (MEK) ND ug/m3 158 52.5 02/02/22 16:28 78-93-3 Carbon disulfide ND ug/m3 33.2 52.5 02/02/22 16:28 75-15-0 Carbon tetrachloride ND ug/m3 67.2 52.5 02/02/22 16:28 56-23-5 Chlorobenzene ND ug/m3 49.1 52.5 02/02/22 16:28 108-90-7 Chloroethane ND ug/m3 70.4 52.5 02/02/22 16:28 75-00-3 Chloroform ND ug/m3 26.0 52.5 02/02/22 16:28 67-66-3 Chloromethane ND ug/m3 22.0 52.5 02/02/22 16:28 74-87-3 Cyclohexane ND ug/m3 91.9 52.5 02/02/22 16:28 110-82-7 Dibromochloromethane ND ug/m3 90.8 52.5 02/02/22 16:28 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 41.0 52.5 02/02/22 16:28 106-93-4 1,2-Dichlorobenzene ND ug/m3 161 52.5 02/02/22 16:28 95-50-1 1,3-Dichlorobenzene ND ug/m3 161 52.5 02/02/22 16:28 541-73-1 1,4-Dichlorobenzene ND ug/m3 161 52.5 02/02/22 16:28 106-46-7 Dichlorodifluoromethane ND ug/m3 53.0 52.5 02/02/22 16:28 75-71-8 1,1-Dichloroethane ND ug/m3 43.2 52.5 02/02/22 16:28 75-34-3 1,2-Dichloroethane ND ug/m3 43.2 52.5 02/02/22 16:28 107-06-2 1,1-Dichloroethene ND ug/m3 42.3 52.5 02/02/22 16:28 75-35-4 cis-1,2-Dichloroethene ND ug/m3 42.3 52.5 02/02/22 16:28 156-59-2 trans-1,2-Dichloroethene ND ug/m3 42.3 52.5 02/02/22 16:28 156-60-5 1,2-Dichloropropene ND ug/m3 49.3 52.5 02/02/22 16:28 78-87-5 cis-1,3-Dichloropropene ND ug/m3 121 52.5 02/02/22 16:28 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 121 52.5 02/02/22 16:28 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 74.6 52.5 02/02/22 16:28 76-14-2 Ethanol ND ug/m3 101 52.5 02/02/22 16:28 64-17-5 Ethyl acetate ND ug/m3 38.5 52.5 02/02/22 16:28 141-78-6 Ethylbenzene ND ug/m3 46.4 52.5 02/02/22 16:28 100-41-4 4-Ethyltoluene ND ug/m3 131 52.5 02/02/22 16:28 622-96-8 n-Heptane ND ug/m3 43.7 52.5 02/02/22 16:28 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 285 52.5 02/02/22 16:28 87-68-3 n-Hexane ND ug/m3 37.6 52.5 02/02/22 16:28 110-54-3 2-Hexanone ND ug/m3 218 52.5 02/02/22 16:28 591-78-6 Methylene Chloride ND ug/m3 185 52.5 02/02/22 16:28 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 218 52.5 02/02/22 16:28 108-10-1 Methyl-tert-butyl ether ND ug/m3 192 52.5 02/02/22 16:28 1634-04-4 Naphthalene ND ug/m3 280 52.5 02/02/22 16:28 91-20-3 2-Propanol ND ug/m3 131 52.5 02/02/22 16:28 67-63-0 Propylene ND ug/m3 45.9 52.5 02/02/22 16:28 115-07-1 Styrene ND ug/m3 114 52.5 02/02/22 16:28 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 73.5 52.5 02/02/22 16:28 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-22 Lab ID: 92583866009 Collected: 01/19/22 11:39 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 1710 ug/m3 36.2 52.5 02/02/22 16:28 127-18-4 Tetrahydrofuran ND ug/m3 31.5 52.5 02/02/22 16:28 109-99-9 Toluene ND ug/m3 40.2 52.5 02/02/22 16:28 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 792 52.5 02/02/22 16:28 120-82-1 1,1,1-Trichloroethane ND ug/m3 58.3 52.5 02/02/22 16:28 71-55-6 1,1,2-Trichloroethane ND ug/m3 29.1 52.5 02/02/22 16:28 79-00-5 Trichloroethene ND ug/m3 28.7 52.5 02/02/22 16:28 79-01-6 Trichlorofluoromethane ND ug/m3 59.8 52.5 02/02/22 16:28 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 81.9 52.5 02/02/22 16:28 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 52.4 52.5 02/02/22 16:28 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 52.4 52.5 02/02/22 16:28 108-67-8 Vinyl acetate ND ug/m3 37.6 52.5 02/02/22 16:28 108-05-4 Vinyl chloride ND ug/m3 13.6 52.5 02/02/22 16:28 75-01-4 m&p-Xylene ND ug/m3 92.9 52.5 02/02/22 16:28 179601-23-1 o-Xylene ND ug/m3 46.4 52.5 02/02/22 16:28 95-47-6 Date: 02/08/2022 06:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-23 Lab ID: 92583866010 Collected: 01/19/22 11:41 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone ND ug/m3 52.8 8.75 02/02/22 15:25 67-64-1 Benzene ND ug/m3 2.8 8.75 02/02/22 15:25 71-43-2 Benzyl chloride ND ug/m3 46.0 8.75 02/02/22 15:25 100-44-7 Bromodichloromethane ND ug/m3 11.9 8.75 02/02/22 15:25 75-27-4 Bromoform ND ug/m3 45.9 8.75 02/02/22 15:25 75-25-2 Bromomethane ND ug/m3 6.9 8.75 02/02/22 15:25 74-83-9 1,3-Butadiene ND ug/m3 3.9 8.75 02/02/22 15:25 106-99-0 2-Butanone (MEK) ND ug/m3 26.2 8.75 02/02/22 15:25 78-93-3 Carbon disulfide ND ug/m3 5.5 8.75 02/02/22 15:25 75-15-0 Carbon tetrachloride ND ug/m3 11.2 8.75 02/02/22 15:25 56-23-5 Chlorobenzene ND ug/m3 8.2 8.75 02/02/22 15:25 108-90-7 Chloroethane ND ug/m3 11.7 8.75 02/02/22 15:25 75-00-3 Chloroform ND ug/m3 4.3 8.75 02/02/22 15:25 67-66-3 Chloromethane ND ug/m3 3.7 8.75 02/02/22 15:25 74-87-3 Cyclohexane ND ug/m3 15.3 8.75 02/02/22 15:25 110-82-7 Dibromochloromethane ND ug/m3 15.1 8.75 02/02/22 15:25 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 6.8 8.75 02/02/22 15:25 106-93-4 1,2-Dichlorobenzene ND ug/m3 26.8 8.75 02/02/22 15:25 95-50-1 1,3-Dichlorobenzene ND ug/m3 26.8 8.75 02/02/22 15:25 541-73-1 1,4-Dichlorobenzene ND ug/m3 26.8 8.75 02/02/22 15:25 106-46-7 Dichlorodifluoromethane ND ug/m3 8.8 8.75 02/02/22 15:25 75-71-8 1,1-Dichloroethane ND ug/m3 7.2 8.75 02/02/22 15:25 75-34-3 1,2-Dichloroethane ND ug/m3 7.2 8.75 02/02/22 15:25 107-06-2 1,1-Dichloroethene ND ug/m3 7.1 8.75 02/02/22 15:25 75-35-4 cis-1,2-Dichloroethene ND ug/m3 7.1 8.75 02/02/22 15:25 156-59-2 trans-1,2-Dichloroethene ND ug/m3 7.1 8.75 02/02/22 15:25 156-60-5 1,2-Dichloropropene ND ug/m3 8.2 8.75 02/02/22 15:25 78-87-5 cis-1,3-Dichloropropene ND ug/m3 20.2 8.75 02/02/22 15:25 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 20.2 8.75 02/02/22 15:25 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 12.4 8.75 02/02/22 15:25 76-14-2 Ethanol 129 ug/m3 16.8 8.75 02/02/22 15:25 64-17-5 Ethyl acetate ND ug/m3 6.4 8.75 02/02/22 15:25 141-78-6 Ethylbenzene ND ug/m3 7.7 8.75 02/02/22 15:25 100-41-4 4-Ethyltoluene ND ug/m3 21.9 8.75 02/02/22 15:25 622-96-8 n-Heptane ND ug/m3 7.3 8.75 02/02/22 15:25 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 47.4 8.75 02/02/22 15:25 87-68-3 n-Hexane ND ug/m3 6.3 8.75 02/02/22 15:25 110-54-3 2-Hexanone ND ug/m3 36.4 8.75 02/02/22 15:25 591-78-6 Methylene Chloride ND ug/m3 30.9 8.75 02/02/22 15:25 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 36.4 8.75 02/02/22 15:25 108-10-1 Methyl-tert-butyl ether ND ug/m3 32.0 8.75 02/02/22 15:25 1634-04-4 Naphthalene ND ug/m3 46.6 8.75 02/02/22 15:25 91-20-3 2-Propanol ND ug/m3 21.9 8.75 02/02/22 15:25 67-63-0 Propylene ND ug/m3 7.7 8.75 02/02/22 15:25 115-07-1 Styrene ND ug/m3 18.9 8.75 02/02/22 15:25 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 12.2 8.75 02/02/22 15:25 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-23 Lab ID: 92583866010 Collected: 01/19/22 11:41 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 471 ug/m3 6.0 8.75 02/02/22 15:25 127-18-4 Tetrahydrofuran ND ug/m3 5.2 8.75 02/02/22 15:25 109-99-9 Toluene ND ug/m3 6.7 8.75 02/02/22 15:25 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 132 8.75 02/02/22 15:25 120-82-1 1,1,1-Trichloroethane ND ug/m3 9.7 8.75 02/02/22 15:25 71-55-6 1,1,2-Trichloroethane ND ug/m3 4.9 8.75 02/02/22 15:25 79-00-5 Trichloroethene 8.7 ug/m3 4.8 8.75 02/02/22 15:25 79-01-6 Trichlorofluoromethane ND ug/m3 10 8.75 02/02/22 15:25 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 13.6 8.75 02/02/22 15:25 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 8.7 8.75 02/02/22 15:25 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 8.7 8.75 02/02/22 15:25 108-67-8 Vinyl acetate ND ug/m3 6.3 8.75 02/02/22 15:25 108-05-4 Vinyl chloride ND ug/m3 2.3 8.75 02/02/22 15:25 75-01-4 m&p-Xylene ND ug/m3 15.5 8.75 02/02/22 15:25 179601-23-1 o-Xylene ND ug/m3 7.7 8.75 02/02/22 15:25 95-47-6 Date: 02/08/2022 06:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-23 Dup. Lab ID: 92583866011 Collected: 01/19/22 11:41 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Acetone ND ug/m3 52.8 8.75 02/02/22 14:53 67-64-1 Benzene ND ug/m3 2.8 8.75 02/02/22 14:53 71-43-2 Benzyl chloride ND ug/m3 46.0 8.75 02/02/22 14:53 100-44-7 Bromodichloromethane ND ug/m3 11.9 8.75 02/02/22 14:53 75-27-4 Bromoform ND ug/m3 45.9 8.75 02/02/22 14:53 75-25-2 Bromomethane ND ug/m3 6.9 8.75 02/02/22 14:53 74-83-9 1,3-Butadiene ND ug/m3 3.9 8.75 02/02/22 14:53 106-99-0 2-Butanone (MEK) ND ug/m3 26.2 8.75 02/02/22 14:53 78-93-3 Carbon disulfide ND ug/m3 5.5 8.75 02/02/22 14:53 75-15-0 Carbon tetrachloride ND ug/m3 11.2 8.75 02/02/22 14:53 56-23-5 Chlorobenzene ND ug/m3 8.2 8.75 02/02/22 14:53 108-90-7 Chloroethane ND ug/m3 11.7 8.75 02/02/22 14:53 75-00-3 Chloroform ND ug/m3 4.3 8.75 02/02/22 14:53 67-66-3 Chloromethane ND ug/m3 3.7 8.75 02/02/22 14:53 74-87-3 Cyclohexane ND ug/m3 15.3 8.75 02/02/22 14:53 110-82-7 Dibromochloromethane ND ug/m3 15.1 8.75 02/02/22 14:53 124-48-1 1,2-Dibromoethane (EDB) ND ug/m3 6.8 8.75 02/02/22 14:53 106-93-4 1,2-Dichlorobenzene ND ug/m3 26.8 8.75 02/02/22 14:53 95-50-1 1,3-Dichlorobenzene ND ug/m3 26.8 8.75 02/02/22 14:53 541-73-1 1,4-Dichlorobenzene ND ug/m3 26.8 8.75 02/02/22 14:53 106-46-7 Dichlorodifluoromethane ND ug/m3 8.8 8.75 02/02/22 14:53 75-71-8 1,1-Dichloroethane ND ug/m3 7.2 8.75 02/02/22 14:53 75-34-3 1,2-Dichloroethane ND ug/m3 7.2 8.75 02/02/22 14:53 107-06-2 1,1-Dichloroethene ND ug/m3 7.1 8.75 02/02/22 14:53 75-35-4 cis-1,2-Dichloroethene ND ug/m3 7.1 8.75 02/02/22 14:53 156-59-2 trans-1,2-Dichloroethene ND ug/m3 7.1 8.75 02/02/22 14:53 156-60-5 1,2-Dichloropropene ND ug/m3 8.2 8.75 02/02/22 14:53 78-87-5 cis-1,3-Dichloropropene ND ug/m3 20.2 8.75 02/02/22 14:53 10061-01-5 trans- 1,3-Dichloropropene ND ug/m3 20.2 8.75 02/02/22 14:53 10061-02-6 Dichlorotetrafluoroethane ND ug/m3 12.4 8.75 02/02/22 14:53 76-14-2 Ethanol 155 ug/m3 16.8 8.75 02/02/22 14:53 64-17-5 Ethyl acetate ND ug/m3 6.4 8.75 02/02/22 14:53 141-78-6 Ethylbenzene ND ug/m3 7.7 8.75 02/02/22 14:53 100-41-4 4-Ethyltoluene ND ug/m3 21.9 8.75 02/02/22 14:53 622-96-8 n-Heptane ND ug/m3 7.3 8.75 02/02/22 14:53 142-82-5 Hexachloro-1,3-butadiene ND ug/m3 47.4 8.75 02/02/22 14:53 87-68-3 n-Hexane ND ug/m3 6.3 8.75 02/02/22 14:53 110-54-3 2-Hexanone ND ug/m3 36.4 8.75 02/02/22 14:53 591-78-6 Methylene Chloride ND ug/m3 30.9 8.75 02/02/22 14:53 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/m3 36.4 8.75 02/02/22 14:53 108-10-1 Methyl-tert-butyl ether ND ug/m3 32.0 8.75 02/02/22 14:53 1634-04-4 Naphthalene ND ug/m3 46.6 8.75 02/02/22 14:53 91-20-3 2-Propanol ND ug/m3 21.9 8.75 02/02/22 14:53 67-63-0 Propylene ND ug/m3 7.7 8.75 02/02/22 14:53 115-07-1 Styrene ND ug/m3 18.9 8.75 02/02/22 14:53 100-42-5 1,1,2,2-Tetrachloroethane ND ug/m3 12.2 8.75 02/02/22 14:53 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Sample: SSV-23 Dup. Lab ID: 92583866011 Collected: 01/19/22 11:41 Received: 01/21/22 08:30 Matrix: Air Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual T015 MSV AIR Analytical Method: TO-15 Pace Analytical Services - Minneapolis Tetrachloroethene 454 ug/m3 6.0 8.75 02/02/22 14:53 127-18-4 Tetrahydrofuran ND ug/m3 5.2 8.75 02/02/22 14:53 109-99-9 Toluene ND ug/m3 6.7 8.75 02/02/22 14:53 108-88-3 1,2,4-Trichlorobenzene ND ug/m3 132 8.75 02/02/22 14:53 120-82-1 1,1,1-Trichloroethane ND ug/m3 9.7 8.75 02/02/22 14:53 71-55-6 1,1,2-Trichloroethane ND ug/m3 4.9 8.75 02/02/22 14:53 79-00-5 Trichloroethene 9.1 ug/m3 4.8 8.75 02/02/22 14:53 79-01-6 Trichlorofluoromethane ND ug/m3 10 8.75 02/02/22 14:53 75-69-4 1,1,2-Trichlorotrifluoroethane ND ug/m3 13.6 8.75 02/02/22 14:53 76-13-1 1,2,4-Trimethylbenzene ND ug/m3 8.7 8.75 02/02/22 14:53 95-63-6 1,3,5-Trimethylbenzene ND ug/m3 8.7 8.75 02/02/22 14:53 108-67-8 Vinyl acetate ND ug/m3 6.3 8.75 02/02/22 14:53 108-05-4 Vinyl chloride ND ug/m3 2.3 8.75 02/02/22 14:53 75-01-4 m&p-Xylene ND ug/m3 15.5 8.75 02/02/22 14:53 179601-23-1 o-Xylene ND ug/m3 7.7 8.75 02/02/22 14:53 95-47-6 Date: 02/08/2022 06:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 QC Batch: 796062 Analysis Method: TO-15 QC Batch Method: TO-15 Analysis Description: T015 MSV AIR Low Level Laboratory: Pace Analytical Services - Minneapolis Associated Lab Samples: 92583866001, 92583866002, 92583866003, 92583866005, 92583866006 METHOD BLANK: 4232406 Matrix: Air Associated Lab Samples: 92583866001, 92583866002, 92583866003, 92583866005, 92583866006 Blank Reporting Parameter Units Result Limit Analyzed 1,1,1-Trichloroethane ug/m3 ND 0.56 01/28/22 10:46 1,1,2,2-Tetrachloroethane ug/m3 ND 0.70 01/28/22 10:46 1,1,2-Trichloroethane ug/m3 ND 0.28 01/28/22 10:46 1,1,2-Trichlorotrifluoroethane ug/m3 ND 0.78 01/28/22 10:46 1,1-Dichloroethane ug/m3 ND 0.41 01/28/22 10:46 1,1-Dichloroethene ug/m3 ND 0.40 01/28/22 10:46 1,2,4-Trichlorobenzene ug/m3 ND 3.8 01/28/22 10:46 1,2,4-Trimethylbenzene ug/m3 ND 0.50 01/28/22 10:46 1,2-Dibromoethane (EDB) ug/m3 ND 0.39 01/28/22 10:46 1,2-Dichlorobenzene ug/m3 ND 1.5 01/28/22 10:46 1,2-Dichloroethane ug/m3 ND 0.41 01/28/22 10:46 1,2-Dichloropropane ug/m3 ND 0.47 01/28/22 10:46 1,3,5-Trimethylbenzene ug/m3 ND 0.50 01/28/22 10:46 1,3-Butadiene ug/m3 ND 0.22 01/28/22 10:46 1,3-Dichlorobenzene ug/m3 ND 1.5 01/28/22 10:46 1,4-Dichlorobenzene ug/m3 ND 1.5 01/28/22 10:46 2-Butanone (MEK) ug/m3 ND 1.5 01/28/22 10:46 2-Hexanone ug/m3 ND 2.1 01/28/22 10:46 2-Propanol ug/m3 ND 1.2 01/28/22 10:46 4-Ethyltoluene ug/m3 ND 1.2 01/28/22 10:46 4-Methyl-2-pentanone (MIBK) ug/m3 ND 2.1 01/28/22 10:46 Acetone ug/m3 ND 3.0 01/28/22 10:46 Benzene ug/m3 ND 0.16 01/28/22 10:46 Benzyl chloride ug/m3 ND 1.3 01/28/22 10:46 Bromodichloromethane ug/m3 ND 0.68 01/28/22 10:46 Bromoform ug/m3 ND 2.6 01/28/22 10:46 Bromomethane ug/m3 ND 0.39 01/28/22 10:46 Carbon disulfide ug/m3 ND 0.32 01/28/22 10:46 Carbon tetrachloride ug/m3 ND 0.64 01/28/22 10:46 Chlorobenzene ug/m3 ND 0.47 01/28/22 10:46 Chloroethane ug/m3 ND 0.27 01/28/22 10:46 Chloroform ug/m3 ND 0.25 01/28/22 10:46 Chloromethane ug/m3 ND 0.21 01/28/22 10:46 cis-1,2-Dichloroethene ug/m3 ND 0.40 01/28/22 10:46 cis-1,3-Dichloropropene ug/m3 ND 1.2 01/28/22 10:46 Cyclohexane ug/m3 ND 0.88 01/28/22 10:46 Dibromochloromethane ug/m3 ND 0.86 01/28/22 10:46 Dichlorodifluoromethane ug/m3 ND 0.50 01/28/22 10:46 Dichlorotetrafluoroethane ug/m3 ND 0.71 01/28/22 10:46 Ethanol ug/m3 ND 0.96 01/28/22 10:46 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 METHOD BLANK: 4232406 Matrix: Air Associated Lab Samples: 92583866001, 92583866002, 92583866003, 92583866005, 92583866006 Blank Reporting Parameter Units Result Limit Analyzed Ethyl acetate ug/m3 ND 0.37 01/28/22 10:46 Ethylbenzene ug/m3 ND 0.44 01/28/22 10:46 Hexachloro-1,3-butadiene ug/m3 ND 2.7 01/28/22 10:46 m&p-Xylene ug/m3 ND 0.88 01/28/22 10:46 Methyl-tert-butyl ether ug/m3 ND 1.8 01/28/22 10:46 Methylene Chloride ug/m3 ND 1.8 01/28/22 10:46 n-Heptane ug/m3 ND 0.42 01/28/22 10:46 n-Hexane ug/m3 ND 0.36 01/28/22 10:46 Naphthalene ug/m3 ND 1.3 01/28/22 10:46 o-Xylene ug/m3 ND 0.44 01/28/22 10:46 Propylene ug/m3 ND 0.44 01/28/22 10:46 Styrene ug/m3 ND 0.43 01/28/22 10:46 Tetrachloroethene ug/m3 ND 0.34 01/28/22 10:46 Tetrahydrofuran ug/m3 ND 0.30 01/28/22 10:46 Toluene ug/m3 ND 0.38 01/28/22 10:46 trans-1,2-Dichloroethene ug/m3 ND 0.40 01/28/22 10:46 trans- 1,3-Dichloropropene ug/m3 ND 1.2 01/28/22 10:46 Trichloroethene ug/m3 ND 0.27 01/28/22 10:46 Trichlorofluoromethane ug/m3 ND 0.57 01/28/22 10:46 Vinyl acetate ug/m3 ND 0.36 01/28/22 10:46 Vinyl chloride ug/m3 ND 0.13 01/28/22 10:46 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 4232407 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1-Trichloroethane ug/m3 59.3 50.7 85 70-130 1,1,2,2-Tetrachloroethane ug/m3 75.4 72.1 96 70-132 1,1,2-Trichloroethane ug/m3 59.6 58.7 98 70-131 1,1,2-Trichlorotrifluoroethane ug/m3 83.6 68.5 82 70-130 1,1-Dichloroethane ug/m3 43.9 36.2 82 70-130 1,1-Dichloroethene ug/m3 43.5 37.4 86 70-130 1,2,4-Trichlorobenzene ug/m3 177 175 99 70-130 1,2,4-Trimethylbenzene ug/m3 54 56.6 105 70-137 1,2-Dibromoethane (EDB) ug/m3 82.5 82.3 100 70-137 1,2-Dichlorobenzene ug/m3 66.2 63.3 96 70-131 1,2-Dichloroethane ug/m3 44.4 38.5 87 70-134 1,2-Dichloropropane ug/m3 50.6 45.9 91 70-130 1,3,5-Trimethylbenzene ug/m3 53.7 55.9 104 70-131 1,3-Butadiene ug/m3 24.2 21.4 89 70-139 1,3-Dichlorobenzene ug/m3 66.3 63.5 96 70-134 1,4-Dichlorobenzene ug/m3 66.3 62.3 94 70-131 2-Butanone (MEK) ug/m3 32.3 30.0 93 70-133 2-Hexanone ug/m3 44.8 49.6 111 70-136 2-Propanol ug/m3 149 123 83 65-133 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 LABORATORY CONTROL SAMPLE: Parameter 4232407 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 4-Ethyltoluene ug/m3 53.7 56.5 105 70-130 4-Methyl-2-pentanone (MIBK) ug/m3 44.9 43.7 97 70-130 Acetone ug/m3 128 106 83 60-134 Benzene ug/m3 34.8 29.1 84 70-130 Benzyl chloride ug/m3 57.6 50.0 87 70-130 Bromodichloromethane ug/m3 73.1 66.9 91 70-130 Bromoform ug/m3 114 120 106 70-138 Bromomethane ug/m3 42.5 36.8 87 68-131 Carbon disulfide ug/m3 34.4 29.9 87 70-130 Carbon tetrachloride ug/m3 69.4 63.0 91 70-132 Chlorobenzene ug/m3 50.2 45.6 91 70-130 Chloroethane ug/m3 28.8 27.4 95 70-134 Chloroform ug/m3 52.4 43.8 84 70-130 Chloromethane ug/m3 22.6 19.9 88 68-131 cis-1,2-Dichloroethene ug/m3 43.4 40.7 94 70-136 cis-1,3-Dichloropropene ug/m3 49.4 47.7 97 70-130 Cyclohexane ug/m3 37.4 33.9 91 70-131 Dibromochloromethane ug/m3 93.2 98.0 105 70-134 Dichlorodifluoromethane ug/m3 54.6 44.7 82 70-130 Dichlorotetrafluoroethane ug/m3 71.2 60.7 85 70-130 Ethanol ug/m3 124 117 94 55-145 Ethyl acetate ug/m3 38.9 36.6 94 70-135 Ethylbenzene ug/m3 47.8 44.5 93 70-133 Hexachloro-1,3-butadiene ug/m3 133 146 110 70-132 m&p-Xylene ug/m3 95.4 89.3 94 70-134 Methyl-tert-butyl ether ug/m3 39.6 34.3 87 70-131 Methylene Chloride ug/m3 190 164 86 65-132 n-Heptane ug/m3 44.6 38.2 86 70-130 n-Hexane ug/m3 38 32.8 86 70-132 Naphthalene ug/m3 65.2 53.4 82 70-130 o-Xylene ug/m3 47.6 45.3 95 70-134 Propylene ug/m3 18.9 16.6 88 69-133 Styrene ug/m3 47 46.9 100 70-135 Tetrachloroethene ug/m3 73.4 77.7 106 70-134 Tetrahydrofuran ug/m3 32.1 30.3 94 70-140 Toluene ug/m3 41.6 36.7 88 70-136 trans-1,2-Dichloroethene ug/m3 43.6 40.9 94 70-134 trans- 1,3-Dichloropropene ug/m3 50.5 51.7 102 70-131 Trichloroethene ug/m3 58.4 51.2 88 70-134 Trichlorofluoromethane ug/m3 62 49.3 80 63-130 Vinyl acetate ug/m3 46.4 44.2 95 70-139 Vinyl chloride ug/m3 28 24.6 88 70-132 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 SAMPLE DUPLICATE: 4232774 Parameter Units 10595260001 Result Dup Result 1,1,1-Trichloroethane ug/m3 <0.29 ND 1,1,2,2-Tetrachloroethane ug/m3 <0.58 ND 1,1,2-Trichloroethane ug/m3 <0.31 ND 1,1,2-Trichlorotrifluoroethane ug/m3 <0.45 ND 1,1-Dichloroethane ug/m3 <0.26 ND 1,1-Dichloroethene ug/m3 <0.21 ND 1,2,4-Trichlorobenzene ug/m3 <7.6 ND 1,2,4-Trimethylbenzene ug/m3 0.891 .77J 1,2-Dibromoethane (EDB) ug/m3 <0.46 ND 1,2-Dichlorobenzene ug/m3 <0.63 ND 1,2-Dichloroethane ug/m3 <0.30 ND 1,2-Dichloropropane ug/m3 <0.42 ND 1,3,5-Trimethylbenzene ug/m3 <0.45 ND 1,3-Butadiene ug/m3 <0.19 ND 1,3-Dichlorobenzene ug/m3 <0.79 ND 1,4-Dichlorobenzene ug/m3 <1.4 ND 2-Butanone (MEK) ug/m3 4.8 4.8 2-Hexanone ug/m3 <0.69 ND 2-Propanol ug/m3 51.5 52.8 4-Ethyltoluene ug/m3 0.77J ND 4-Methyl-2-pentanone (MIBK) ug/m3 <0.50 ND Acetone ug/m3 19.4 20.2 Benzene ug/m3 1.5 1.6 Benzyl chloride ug/m3 <1.4 ND Bromodichloromethane ug/m3 <0.37 ND Bromoform ug/m3 <2.5 ND Bromomethane ug/m3 <0.23 ND Carbon disulfide ug/m3 <0.20 ND Carbon tetrachloride ug/m3 <0.43 ND Chlorobenzene ug/m3 <0.24 ND Chloroethane ug/m3 <0.35 ND Chloroform ug/m3 <0.28 ND Chloromethane ug/m3 0.88 0.89 cis-1,2-Dichloroethene ug/m3 4.4 4.3 cis-1,3-Dichloropropene ug/m3 <0.40 ND Cyclohexane ug/m3 2.1 J 1.91 Dibromochloromethane ug/m3 <0.80 ND Dichlorodifluoromethane ug/m3 2.8 2.8 Dichlorotetrafluoroethane ug/m3 <0.31 ND Ethanol ug/m3 82.7 84.2 Ethyl acetate ug/m3 0.48J .511 Ethylbenzene ug/m3 0.891 .83J Hexachloro-1,3-butadiene ug/m3 <1.9 ND m&p-Xylene ug/m3 2.9 3.0 Methyl-tert-butyl ether ug/m3 <0.20 ND Methylene Chloride ug/m3 <0.92 ND n-Heptane ug/m3 1.2J 1.2J RPD Qualifiers 2 4 1 3 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 SAMPLE DUPLICATE: 4232774 Parameter Units 10595260001 Result Dup Result RPD n-Hexane ug/m3 3.0 2.8 5 Naphthalene ug/m3 <3.4 ND o-Xylene ug/m3 1.0J .92J Propylene ug/m3 <0.20 ND Styrene ug/m3 <0.60 ND Tetrachloroethene ug/m3 <0.45 ND Tetrahydrofuran ug/m3 3.6 3.6 0 Toluene ug/m3 4.5 4.4 2 trans-1,2-Dichloroethene ug/m3 <0.26 ND trans- 1,3-Dichloropropene ug/m3 <0.84 ND Trichloroethene ug/m3 <0.30 ND Trichlorofluoromethane ug/m3 4.7 4.7 0 Vinyl acetate ug/m3 <0.32 ND Vinyl chloride ug/m3 <0.13 ND SAMPLE DUPLICATE: 4232775 Parameter Units 10595261001 Result Dup Result RPD 1,1,1-Trichloroethane ug/m3 <0.20 ND 1,1,2,2-Tetrachloroethane ug/m3 <0.39 ND 1,1,2-Trichloroethane ug/m3 <0.21 ND 1,1,2-Trichlorotrifluoroethane ug/m3 0.70J .62J 1,1-Dichloroethane ug/m3 <0.17 ND 1,1-Dichloroethene ug/m3 <0.15 ND 1,2,4-Trichlorobenzene ug/m3 <5.2 ND 1,2,4-Trimethylbenzene ug/m3 2.4 2.3 6 1,2-Dibromoethane (EDB) ug/m3 <0.32 ND 1,2-Dichlorobenzene ug/m3 <0.43 ND 1,2-Dichloroethane ug/m3 <0.21 ND 1,2-Dichloropropane ug/m3 <0.29 ND 1,3,5-Trimethylbenzene ug/m3 0.70J .67J 1,3-Butadiene ug/m3 <0.13 ND 1,3-Dichlorobenzene ug/m3 <0.54 ND 1,4-Dichlorobenzene ug/m3 <0.93 ND 2-Butanone (MEK) ug/m3 1.5J 1.4J 2-Hexanone ug/m3 <0.47 ND 2-Propanol ug/m3 5.3 5.2 2 4-Ethyltoluene ug/m3 0.83J .84J 4-Methyl-2-pentanone (MIBK) ug/m3 <0.34 ND Acetone ug/m3 18.9 18.3 3 Benzene ug/m3 5.3 5.2 2 Benzyl chloride ug/m3 <0.94 ND Bromodichloromethane ug/m3 <0.25 ND Bromoform ug/m3 <1.7 ND Bromomethane ug/m3 <0.16 ND Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 SAMPLE DUPLICATE: 4232775 Parameter Units 10595261001 Result Carbon disulfide ug/m3 <0.14 Carbon tetrachloride ug/m3 0.31J Chlorobenzene ug/m3 <0.16 Chloroethane ug/m3 <0.24 Chloroform ug/m3 0.22J Chloromethane ug/m3 0.95 cis-1,2-Dichloroethene ug/m3 3.3 cis-1,3-Dichloropropene ug/m3 <0.27 Cyclohexane ug/m3 7.5 Dibromochloromethane ug/m3 <0.55 Dichlorodifluoromethane ug/m3 3.0 Dichlorotetrafluoroethane ug/m3 <0.21 Ethanol ug/m3 83.3 Ethyl acetate ug/m3 0.501 Ethylbenzene ug/m3 2.6 Hexachloro-1,3-butadiene ug/m3 <1.3 m&p-Xylene ug/m3 9.6 Methyl-tert-butyl ether ug/m3 <0.13 Methylene Chloride ug/m3 <0.63 n-Heptane ug/m3 4.1 n-Hexane ug/m3 8.9 Naphthalene ug/m3 <2.3 o-Xylene ug/m3 3.2 Propylene ug/m3 <0.14 Styrene ug/m3 <0.41 Tetrachloroethene ug/m3 0.38J Tetrahydrofuran ug/m3 <0.19 Toluene ug/m3 14.4 trans-1,2-Dichloroethene ug/m3 <0.18 trans- 1,3-Dichloropropene ug/m3 <0.58 Trichloroethene ug/m3 <0.21 Trichlorofluoromethane ug/m3 3.1 Vinyl acetate ug/m3 <0.22 Vinyl chloride ug/m3 <0.092 Dup Result RPD Qualifiers ND .36J ND ND .2J 0.95 0 2.9 14 ND 7.4 1 ND 2.8 6 ND 81.7 2 .48J 2.6 1 ND 9.5 1 ND ND 3.9 5 8.8 1 ND 3.2 1 ND ND .33J ND 14.0 3 ND ND ND 3.0 4 ND ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 42 laneAnalytical www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 QC Batch: 796371 Analysis Method: TO-15 QC Batch Method: TO-15 Analysis Description: T015 MSVAIR Low Level Laboratory: Pace Analytical Services - Minneapolis Associated Lab Samples: 92583866004, 92583866007, 92583866008, 92583866009, 92583866010, 92583866011 METHOD BLANK: 4233834 Matrix: Air Associated Lab Samples: 92583866004, 92583866007, 92583866008, 92583866009, 92583866010, 92583866011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1-Trichloroethane ug/m3 ND 1.1 02/02/22 09:36 1,1,2,2-Tetrachloroethane ug/m3 ND 1.4 02/02/22 09:36 1,1,2-Trichloroethane ug/m3 ND 0.56 02/02/22 09:36 1,1,2-Trichlorotrifluoroethane ug/m3 ND 1.6 02/02/22 09:36 1,1-Dichloroethane ug/m3 ND 0.82 02/02/22 09:36 1,1-Dichloroethene ug/m3 ND 0.81 02/02/22 09:36 1,2,4-Trichlorobenzene ug/m3 ND 15.1 02/02/22 09:36 1,2,4-Trimethylbenzene ug/m3 ND 1.0 02/02/22 09:36 1,2-Dibromoethane (EDB) ug/m3 ND 0.78 02/02/22 09:36 1,2-Dichlorobenzene ug/m3 ND 3.1 02/02/22 09:36 1,2-Dichloroethane ug/m3 ND 0.82 02/02/22 09:36 1,2-Dichloropropane ug/m3 ND 0.94 02/02/22 09:36 1,3,5-Trimethyl benzene ug/m3 ND 1.0 02/02/22 09:36 1,3-Butadiene ug/m3 ND 0.45 02/02/22 09:36 1,3-Dichlorobenzene ug/m3 ND 3.1 02/02/22 09:36 1,4-Dichlorobenzene ug/m3 ND 3.1 02/02/22 09:36 2-Butanone (MEK) ug/m3 ND 3.0 02/02/22 09:36 2-Hexanone ug/m3 ND 4.2 02/02/22 09:36 2-Propanol ug/m3 ND 2.5 02/02/22 09:36 4-Ethyltoluene ug/m3 ND 2.5 02/02/22 09:36 4-Methyl-2-pentanone (MIBK) ug/m3 ND 4.2 02/02/22 09:36 Acetone ug/m3 ND 6.0 02/02/22 09:36 Benzene ug/m3 ND 0.32 02/02/22 09:36 Benzyl chloride ug/m3 ND 5.3 02/02/22 09:36 Bromodichloromethane ug/m3 ND 1.4 02/02/22 09:36 Bromoform ug/m3 ND 5.2 02/02/22 09:36 Bromomethane ug/m3 ND 0.79 02/02/22 09:36 Carbon disulfide ug/m3 ND 0.63 02/02/22 09:36 Carbon tetrachloride ug/m3 ND 1.3 02/02/22 09:36 Chlorobenzene ug/m3 ND 0.94 02/02/22 09:36 Chloroethane ug/m3 ND 1.3 02/02/22 09:36 Chloroform ug/m3 ND 0.50 02/02/22 09:36 Chloromethane ug/m3 ND 0.42 02/02/22 09:36 cis- 1,2-Dichloroethene ug/m3 ND 0.81 02/02/22 09:36 cis- 1,3-Dichloropropene ug/m3 ND 2.3 02/02/22 09:36 Cyclohexane ug/m3 ND 1.8 02/02/22 09:36 Dibromochloromethane ug/m3 ND 1.7 02/02/22 09:36 Dichlorodifluoromethane ug/m3 ND 1.0 02/02/22 09:36 Dichlorotetrafluoroethane ug/m3 ND 1.4 02/02/22 09:36 Ethanol ug/m3 ND 1.9 02/02/22 09:36 MN M, MN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 METHOD BLANK: 4233834 Matrix: Air Associated Lab Samples: 92583866004, 92583866007, 92583866008, 92583866009, 92583866010, 92583866011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Ethyl acetate ug/m3 ND 0.73 02/02/22 09:36 Ethylbenzene ug/m3 ND 0.88 02/02/22 09:36 Hexachloro-1,3-butadiene ug/m3 ND 5.4 02/02/22 09:36 m&p-Xylene ug/m3 ND 1.8 02/02/22 09:36 Methyl-tert-butyl ether ug/m3 ND 3.7 02/02/22 09:36 Methylene Chloride ug/m3 ND 3.5 02/02/22 09:36 n-Heptane ug/m3 ND 0.83 02/02/22 09:36 n-Hexane ug/m3 ND 0.72 02/02/22 09:36 Naphthalene ug/m3 ND 5.3 02/02/22 09:36 MN o-Xylene ug/m3 ND 0.88 02/02/22 09:36 Propylene ug/m3 ND 0.88 02/02/22 09:36 Styrene ug/m3 ND 2.2 02/02/22 09:36 MN Tetrachloroethene ug/m3 ND 0.69 02/02/22 09:36 Tetrahydrofuran ug/m3 ND 0.60 02/02/22 09:36 Toluene ug/m3 ND 0.77 02/02/22 09:36 trans-1,2-Dichloroethene ug/m3 ND 0.81 02/02/22 09:36 trans- 1,3-Dichloropropene ug/m3 ND 2.3 02/02/22 09:36 Trichloroethene ug/m3 ND 0.55 02/02/22 09:36 Trichlorofluoromethane ug/m3 ND 1.1 02/02/22 09:36 Vinyl acetate ug/m3 ND 0.72 02/02/22 09:36 Vinyl chloride ug/m3 ND 0.26 02/02/22 09:36 LABORATORY CONTROL SAMPLE: Parameter 4233835 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1-Trichloroethane ug/m3 59.3 58.6 99 70-130 1,1,2,2-Tetrachloroethane ug/m3 75.4 85.4 113 70-132 1,1,2-Trichloroethane ug/m3 59.6 69.9 117 70-131 1,1,2-Trichlorotrifluoroethane ug/m3 83.6 88.1 105 70-130 1,1-Dichloroethane ug/m3 43.9 44.8 102 70-130 1,1-Dichloroethene ug/m3 43.5 44.7 103 70-130 1,2,4-Trichlorobenzene ug/m3 177 160 90 70-130 1,2,4-Trimethylbenzene ug/m3 54 67.4 125 70-137 1,2-Dibromoethane (EDB) ug/m3 82.5 97.7 118 70-137 1,2-Dichlorobenzene ug/m3 66.2 67.2 102 70-131 1,2-Dichloroethane ug/m3 44.4 47.7 107 70-134 1,2-Dichloropropane ug/m3 50.6 52.9 105 70-130 1,3,5-Trimethylbenzene ug/m3 53.7 60.4 112 70-131 1,3-Butadiene ug/m3 24.2 27.5 114 70-139 1,3-Dichlorobenzene ug/m3 66.3 67.1 101 70-134 1,4-Dichlorobenzene ug/m3 66.3 66.1 100 70-131 2-Butanone (MEK) ug/m3 32.3 33.4 103 70-133 2-Hexanone ug/m3 44.8 45.0 100 70-136 2-Propanol ug/m3 149 143 96 65-133 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 LABORATORY CONTROL SAMPLE: Parameter 4233835 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 4-Ethyltoluene ug/m3 53.7 55.9 104 70-130 4-Methyl-2-pentanone (MIBK) ug/m3 44.9 53.6 119 70-130 Acetone ug/m3 128 128 100 60-134 Benzene ug/m3 34.8 34.1 98 70-130 Benzyl chloride ug/m3 57.6 54.3 94 70-130 Bromodichloromethane ug/m3 73.1 78.6 108 70-130 Bromoform ug/m3 114 142 125 70-138 Bromomethane ug/m3 42.5 45.4 107 68-131 Carbon disulfide ug/m3 34.4 36.4 106 70-130 Carbon tetrachloride ug/m3 69.4 73.9 107 70-132 Chlorobenzene ug/m3 50.2 55.1 110 70-130 Chloroethane ug/m3 28.8 31.7 110 70-134 Chloroform ug/m3 52.4 51.5 98 70-130 Chloromethane ug/m3 22.6 23.4 104 68-131 cis-1,2-Dichloroethene ug/m3 43.4 48.1 111 70-136 cis-1,3-Dichloropropene ug/m3 49.4 50.9 103 70-130 Cyclohexane ug/m3 37.4 36.7 98 70-131 Dibromochloromethane ug/m3 93.2 102 109 70-134 Dichlorodifluoromethane ug/m3 54.6 53.9 99 70-130 Dichlorotetrafluoroethane ug/m3 71.2 70.5 99 70-130 Ethanol ug/m3 124 124 100 55-145 Ethyl acetate ug/m3 38.9 40.8 105 70-135 Ethylbenzene ug/m3 47.8 51.1 107 70-133 Hexachloro-1,3-butadiene ug/m3 133 131 98 70-132 m&p-Xylene ug/m3 95.4 102 107 70-134 Methyl-tert-butyl ether ug/m3 39.6 38.1 96 70-131 Methylene Chloride ug/m3 190 190 100 65-132 n-Heptane ug/m3 44.6 43.4 97 70-130 n-Hexane ug/m3 38 41.9 110 70-132 Naphthalene ug/m3 65.2 62.8 96 70-130 o-Xylene ug/m3 47.6 52.2 110 70-134 Propylene ug/m3 18.9 19.9 105 69-133 Styrene ug/m3 47 48.0 102 70-135 Tetrachloroethene ug/m3 73.4 72.1 98 70-134 Tetrahydrofuran ug/m3 32.1 33.6 105 70-140 Toluene ug/m3 41.6 43.3 104 70-136 trans-1,2-Dichloroethene ug/m3 43.6 54.9 126 70-134 trans- 1,3-Dichloropropene ug/m3 50.5 50.6 100 70-131 Trichloroethene ug/m3 58.4 65.0 111 70-134 Trichlorofluoromethane ug/m3 62 63.6 103 63-130 Vinyl acetate ug/m3 46.4 46.6 101 70-139 Vinyl chloride ug/m3 28 31.0 111 70-132 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 SAMPLE DUPLICATE: 4235833 Parameter Units 10595055002 Result Dup Result 1,1,1-Trichloroethane ug/m3 <0.56 ND 1,1,2,2-Tetrachloroethane ug/m3 <1.1 ND 1,1,2-Trichloroethane ug/m3 <0.59 ND 1,1,2-Trichlorotrifluoroethane ug/m3 <0.86 ND 1,1-Dichloroethane ug/m3 <0.49 ND 1,1-Dichloroethene ug/m3 <0.41 ND 1,2,4-Trichlorobenzene ug/m3 <14.6 ND 1,2,4-Trimethylbenzene ug/m3 <1.1 ND 1,2-Dibromoethane (EDB) ug/m3 <0.90 ND 1,2-Dichlorobenzene ug/m3 <1.2 ND 1,2-Dichloroethane ug/m3 <0.58 ND 1,2-Dichloropropane ug/m3 <0.80 ND 1,3,5-Trimethylbenzene ug/m3 <0.87 ND 1,3-Butadiene ug/m3 <0.36 ND 1,3-Dichlorobenzene ug/m3 <1.5 ND 1,4-Dichlorobenzene ug/m3 <2.6 ND 2-Butanone (MEK) ug/m3 3.5J 3AJ 2-Hexanone ug/m3 <1.3 ND 2-Propanol ug/m3 6.2J 6.4J 4-Ethyltoluene ug/m3 <1.4 ND 4-Methyl-2-pentanone (MIBK) ug/m3 <0.96 ND Acetone ug/m3 28.8 29.2 Benzene ug/m3 <0.34 ND Benzyl chloride ug/m3 <2.7 ND Bromodichloromethane ug/m3 <0.71 ND Bromoform ug/m3 <4.8 ND Bromomethane ug/m3 <0.45 ND Carbon disulfide ug/m3 <0.39 ND Carbon tetrachloride ug/m3 <0.84 ND Chlorobenzene ug/m3 <0.46 ND Chloroethane ug/m3 <0.67 ND Chloroform ug/m3 <0.55 ND Chloromethane ug/m3 <0.25 ND cis-1,2-Dichloroethene ug/m3 <0.58 ND cis-1,3-Dichloropropene ug/m3 <0.76 ND Cyclohexane ug/m3 <0.66 ND Dibromochloromethane ug/m3 <1.5 ND Dichlorodifluoromethane ug/m3 <0.56 ND Dichlorotetrafluoroethane ug/m3 <0.60 ND Ethanol ug/m3 77.8 80.2 Ethyl acetate ug/m3 <0.39 ND Ethylbenzene ug/m3 <0.92 ND Hexachloro-1,3-butadiene ug/m3 <3.7 ND m&p-Xylene ug/m3 4AJ 4.5J Methyl-tert-butyl ether ug/m3 <0.38 ND Methylene Chloride ug/m3 <1.8 ND n-Heptane ug/m3 <0.54 ND RPD Qualifiers 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 SAMPLE DUPLICATE: 4235833 Parameter n-Hexane Naphthalene o-Xylene Propylene Styrene Tetrachloroethene Tetrahydrofuran Toluene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride SAMPLE DUPLICATE: 4235834 Parameter 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1,2-Trichlorotrifluoroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2,4-Trichlorobenzene 1,2,4-Trimethylbenzene 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3,5-Trimethylbenzene 1,3-Butadiene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2-Butanone (MEK) 2-Hexanone 2-Propanol 4-Ethyltoluene 4-Methyl-2-pentanone (MIBK) Acetone Benzene Benzyl chloride Bromodichloromethane Bromoform Bromomethane Units ug/m3 ug/m3 ug/m3 ug/m3 ug/m3 ug/m3 ug/m3 ug/m3 ug/m3 ug/m3 ug/m3 ug/m3 ug/m3 ug/m3 10595055002 Result <0.57 <6.5 1.2J <0.39 <1.2 <0.87 <0.54 1.7J <0.50 <1.6 <0.59 2.5J <0.62 <0.26 Dup Result RPD Qualifiers Units 10595055004 Dup Result Result ug/m3 3.8 ug/m3 <0.77 ug/m3 <0.41 ug/m3 <0.60 ug/m3 <0.34 ug/m3 <0.28 ug/m3 <10.1 ug/m3 3.7 ug/m3 <0.62 ug/m3 <0.83 ug/m3 <0.40 ug/m3 <0.55 ug/m3 <0.60 ug/m3 <0.25 ug/m3 <1.0 ug/m3 <1.8 ug/m3 17.5 ug/m3 <0.91 ug/m3 82.3 ug/m3 <0.97 ug/m3 0.86J ug/m3 81.4 ug/m3 0.56J ug/m3 <1.8 ug/m3 <0.49 ug/m3 <3.3 ug/m3 <0.31 ND ND 1.2J ND ND ND ND 1.8J ND ND ND 2.5J ND ND 4.0 ND ND ND ND ND ND 3.7 ND ND ND ND ND ND ND ND 18.0 ND 88.2 ND .97J 87.2 .63J ND ND ND ND RPD 5 U 3 7 7 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 SAMPLE DUPLICATE: 4235834 Parameter Units 10595055004 Result Carbon disulfide ug/m3 1.1J Carbon tetrachloride ug/m3 <0.58 Chlorobenzene ug/m3 <0.32 Chloroethane ug/m3 <0.46 Chloroform ug/m3 <0.38 Chloromethane ug/m3 <0.18 cis-1,2-Dichloroethene ug/m3 7.5 cis-1,3-Dichloropropene ug/m3 <0.53 Cyclohexane ug/m3 <0.46 Dibromochloromethane ug/m3 <1.1 Dichlorodifluoromethane ug/m3 3.4 Dichlorotetrafluoroethane ug/m3 <0.42 Ethanol ug/m3 193 Ethyl acetate ug/m3 1.6 Ethylbenzene ug/m3 1.2J Hexachloro-1,3-butadiene ug/m3 <2.5 m&p-Xylene ug/m3 5.5 Methyl-tert-butyl ether ug/m3 5.3J Methylene Chloride ug/m3 <1.2 n-Heptane ug/m3 <0.37 n-Hexane ug/m3 0.901 Naphthalene ug/m3 11.0 o-Xylene ug/m3 1.5J Propylene ug/m3 <0.27 Styrene ug/m3 <0.79 Tetrachloroethene ug/m3 164 Tetrahydrofuran ug/m3 1.5 Toluene ug/m3 2.3 trans-1,2-Dichloroethene ug/m3 <0.35 trans- 1,3-Dichloropropene ug/m3 <1.1 Trichloroethene ug/m3 13.2 Trichlorofluoromethane ug/m3 2.7 Vinyl acetate ug/m3 <0.43 Vinyl chloride ug/m3 <0.18 Dup Result RPD ND ND ND ND ND ND 8.1 ND ND ND 1.8J ND 207 1.8 1.2J ND 5.5 5.8J ND ND 2.0 11.1 1.5J ND ND 170 1.3 2.6 ND ND 14.3 3.1 ND ND 0 7 10 u 0 8 11 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS MN The reporting limit has been raised in accordance with Minnesota Statutes 4740.2100 Subpart 8. C, D. Reporting Limit Evaluation Rule. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 06:42 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Lewis St. Brownfields 2022-021-Revised Report Pace Project No.: 92583866 Lab ID Sample ID QC Batch Method QC Batch 92583866001 SSV-14 TO-15 796062 92583866002 SSV-15 TO-15 796062 92583866003 SSV-16 TO-15 796062 92583866004 SSV-17 TO-15 796371 92583866005 SSV-18 TO-15 796062 92583866006 SSV-19 TO-15 796062 92583866007 SSV-20 TO-15 796371 92583866008 SSV-21 TO-15 796371 92583866009 SSV-22 TO-15 796371 92583866010 SSV-23 TO-15 796371 92583866011 SSV-23 Dup. TO-15 796371 Date: 02/08/2022 06:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Method Analytical Batch Page 39 of 42 Document Name: Document Revised: November 15, 2021 Analytical n Sample Condition Upon Receipt (SOUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev,08 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood F] Huntersville Raleighf-1 Mechariicsville❑ Atlanta] KernersvilleEl Sample Condition Upon Receipt Client Name: Project # WO1t . 9Z'583866 Courier: ❑Fed Ex ❑UPS ❑U5P5 ❑Client 1111111111111111111111 ❑ Commercial Pace []Other:_ 925831366 Custody Seal Present? []Yes Ea1Go Seats intact? []Yes 51No Date/Initla%Person Examining Contents; Packing Material, ❑Bubble Wrap []Bubble Bags ®None ❑ Other Biological Tissue Frozen? ❑Yes ❑No 4171N/A Thermometer: ❑wet ❑Blue None �IRGun ID: rlZ�(��jlf Type of Ice: Correction Factor: ` � Cooler Temp: n 1�t_ Add/Subtract (°C) V . (� Temp should be above freezing to VC. [:]Samples out of temp criteria. Samples on ice, cooling process Cooler-Temp-CorrectedfQ: �� j ` _ K-3S-begu USDA Regulated Sall (❑ NIA, water sample) Did samples originate in a quarantine zone within the United States; CA, NY, or 5C (check maps)? old samples originate from a foreign source (internationally, IYes MNo inri—lino Nawali and Puprtn Rirn17 F-lVac mrd Comments/Dls crep ancy: Chain of Custody Present? Yes ❑No ❑N/A 1. Samples Arrived within Hold Time? Yes []NO ❑N/A 2. Short Hold Time Analysis (c72 hr.)? yes J@No N/A 3. Rush Turn Around Time Requested? []Yes @No []N/A 4. Sufficient Volume? Yes ❑No ❑N/A S. Correct Containers Used? -Pace Containers Used? byes Yes ❑No ❑No ❑N/A ❑N/A G. Containers Intact? E4Yes []No N/A 7. Dissolved analysis: Samples Feld Filtered? Yes []No jANIA 8. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matriir ]Yes []No ❑N/A s. Headspace in V0A Vials (>5-6mm)? []Yes QNO N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? []Yes []Yes 5(No [:]No ❑N/A /A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers; CLIENT NOTIFICATION/RESOLUTION Person contacted, Date/Time; _ Project Manager SCURF Review: Project Manager SRF Review: Date: Date: Field Data Requlred? ❑Yes [-]NO Page 40 of 42 Document Name: Document Revised: November 15, 2021 �ceAnalXicaii Sample Condition Upon Receipt (SCUR) Page 2 of 2 Document Nb.: Issuing Authority: F-CAR•C5.033-Rev.08 Pace Carolinas Quality pffite *Check mark top half of box If pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions V0A, Coliform, TOC, Oil and Grease, DRO/8015 (water} ©OC, LLHg **Bottom half of box is to list number of bottles Project # + ,01t . 9dM 2663866 PM: LIVW Due Date; 02/04/22 CLIENT: 92-Pyramid v v U U Z 4 u D u a a a m Z Z Z Z ry Q 2 ? ? q Z m A rn w 'a _ a a 13i z v13 e3 7 v v v c z z -_ i i a,z Z a N Gl Ol 61 W W L y�j U Q Q 19 v v N N a V = N N Q C Ul z Q L Z � x 2 N c c c a `^ Z z - c � n IF C z V, a $ o `^ a > ro 2 c c o a c 7 V V 7 c 7 = = rZv Z v 2 ? N — _ U a C a m - V c u t a c Gl a v E z Z x J9 it Y = _ Z A a m A ro p n E a E E o Ln 4 O q ¢ O O Q n ; ¢ c E Q a 7 > > ! Q EEEayJEEJEE �a _ EE aE E E N ✓ 0 ry LM N In N M. CDp O O Y v ry N O O o E 4 M N N Q T C O U. 14 N ,r� .-I Try rn M CI Cn Q% Q ue V7 N M O Vr Ol m m m m m m � 0. 4 _ qap 3 a a a a a ¢ a a a o > > ;Am a > o 1 2 3 } 4 ti 5 \d 6 . 7 \ i I \\N\ N 9 l0 11 12 \LL .\I\\N N .-7-i NN pH Adjustment Log for Preserved Samples Sample ID Type at Preservative pH upon receipt date preservation adjusted Time preservation adjusted Amount of Preservative added Lot h Note: Whenever there is a discrepancy affecting North Carolina compllance samples, a copy of this Form will be sent to the NorthCarofina DEHNR Unification Office (I-e- Out of hold, incorrect preservative, out of temp, incorrect containers. Page 41 of 42 iiQyeil rWlytlol vt zfrAraaAsccrrr AIR: CHAIN -OF -CUSTODY 1 Analytical Request Docum The C� hat of -Custody is a LEGAL DOCUMENT. All relevant fields must he completed accurately. Section A Required Client Information: Section i3 Required Project Information: Section C Invoice Information Company: Pyramid Environmental Report To . 1 { I/� Ir�F l�A I V, }� rJ 1�N�4 Attention: Address; 503 Industrial Avenue �qb; Company Name. h f i kA Ill Greensboro, NC 27406 Tk Address: EInal''Omike@pyramidenvironmental.com Purchase Order No.: Paco Quote Reference: Phone: 336-33&317a IFax: 336.691-0646 Project Name: Lewis St. Brownfields Site ---------------- Pace Project ManagenSales Rep. Lindsey Wooten Pace Profile #: T Requested Due oatelTAT! Project Number. 2022-421 'S2CllOn d Required Client Information VW,d Media CedeaVI IA COLLECTED m o, AIR SAMPLE ID Ttldl"Bw urea summa e.a IL ,Le Summa Sample Ds MUST BE UNIQUE d Lit rsemmraCW eLc o �' a P o, a` ti Can Flow L..W—Puff Lva Hi0 VeWme Puff HVP ❑ ._ W a .°�. �- Number Control Num �P�sd�s,� , er+ecue COMr0.5nE. Omer PM,o 3 re A '� e W ~----------_---_---------- _.`--- cr p a-—_—._ U c Cl DATE TIME DATE I I TIME 5SV 14 6LC 74.3 01/19/2022 13:57 011192422 16;31 t1191202 o11191202 _._----- 14:26 —_ 28- -- 7 2, 2 S SSV-15 61-C 26.3 17:03 30 7 I 2, 3 2 SSV-16 1 42.4 D1/19/2022 15728 0111912022 16:00 30 7 2- b l 0 SSV-17 ------ 6LC 104.6 0111912022 14',55 01MW20 —15:23 _ 30 7 1 !� S$V-18 6LC�43.6 01119/2022 4:30 1/191202 15:00 29.5 7 Z —. ---- .— ---- _ _� 6LC 181-6 - ---- 01f1912022 13:47 111912D22 14;17 29 7 0 1- 59 -- ---... ----SSV-20—._._._ 6LC 53.1 01/1912022 13:29 111912� µ14:D3 28.5 ---- -- -- SSV-21 6LC 99.4 0111912022 12:24 1119120 12:55 29,6 7 "1 A 0 SSV-22 ------------ ---------- 6LC 63.7 01MW2022 11:09 11191202 11:39 29 7 l l r S$V-23 6LG 59 01/19/2022 10:39 1119P202 11:41 - - 30 -- 30 - 7--� SSV-23 Dlip, -________-__.......______.-.-__------------- —____._._—.__ � 59 fiLC —_._ OV19l2022 —.—�...__ 10:39 _--____________ 1/191202 _ 11:41 7 q lPaae7 / of % Program r UST I— Superfund i- Emissions F Clean Air Act r Voluntary Clean Up 7 Dry Clean If RC RA r Other Location of Re ort un es Sampling by G oglm' mgiml_ PPBV PPMV_ State ther Report Level 11.-Z IIL_ IV._ er Methotl: Pace Lab ID x ro x RELIN 11ISH?-D BY /AFFILIATION I DATE I TIME (ACCEPTED BY tAFFILIATION I DATE I TIME � a a • SAMPLER NAME AND SIGNATURE rt / . ff � .� 1700 Elm Street SE, Suite 200, Minneapolis, MN 55414 FC046Rev.01.103Feb2010