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HomeMy WebLinkAbout23067_Blythe Isenhour_VIMS Install Report_Bldg 1007_20240206 VIMS Installation Completion Report Townes at LoSo Building 1007 (Units 31, 32, & 33) Blythe Isenhour Brownfields Site 4920 Old Pineville Road Charlotte, North Carolina Brownfields Project No. 23067-19-060 H&H Job No. NVR-013 February 6, 2024 #C-1269 Engineering #C-245 Geology i https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/VIMS Install Report_Bldg 1007.docx VIMS Installation Completion Report Townes at LoSo – Building 1007 Blythe Isenhour Charlotte, North Carolina Brownfields Project No. 23067-19-060 H&H Job No. NVR-013 Table of Contents 1.0 Introduction ..............................................................................................................................1 2.0 VIMS Installation and Influence Testing ..............................................................................4 2.1 VIMS Installation ...................................................................................................................4 2.2 VIMS Influence Testing .........................................................................................................6 3.0 Sub-Slab Soil Gas Assessment Activities ...............................................................................8 3.1 Sub-Slab Soil Gas Sampling ..................................................................................................8 3.2 Sub-Slab Soil Gas Sampling Results ......................................................................................9 4.0 Methane Gas Screening .........................................................................................................11 5.0 Summary and Conclusions ...................................................................................................13 6.0 Engineer’s Certification ........................................................................................................15 List of Tables Table 1 Summary of Sub-Slab Soil Gas Analytical Data Table 2 Summary of Methane Screening Data List of Figures Figure 1 Site Location Map Figure 2 Site Plan ii https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/VIMS Install Report_Bldg 1007.docx List of Appendices Appendix A Historical Data Summary Tables and Sample Location Map Appendix B Product Specification Sheets Appendix C VIMS As-Built Drawings Appendix D VIMS Installation Photographs Appendix E Field Forms and Field Data Appendix F Laboratory Analytical Report Appendix G PVC Primer and PVC Glue Material Safety Data Sheets Appendix H DEQ Risk Calculator Summary Pages 1 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/VIMS Install Report_Bldg 1007.docx VIMS Installation Completion Report Townes at LoSo – Building 1007 Blythe Isenhour Charlotte, North Carolina Brownfields Project No. 23067-19-060 H&H Job No. NVR-013 1.0 Introduction Hart & Hickman, PC (H&H) has prepared this report to document vapor intrusion mitigation system (VIMS) installation, influence testing, and post-construction sub-slab soil gas (vapor) assessment activities completed for Building 1007 at the Townes at LoSo development (formally known as Old Pineville Road – Phase II) at the Blythe Isenhour North Carolina Department of Environmental Quality (DEQ) Brownfields property (Brownfields Project No. 23067-19-060). The property is located at 4920 Old Pineville Road in Charlotte, Mecklenburg County, North Carolina (Site or subject Site) and totals approximately 1.67 acres of land. The Townes at LoSo development plan includes construction of 12 buildings consisting of 46 for- sale townhome units by Ryan Homes, an NVR, Inc. (NVR) company. The buildings include eight 3-unit townhome complexes, two 4-unit townhome complexes, and two 8-unit townhome complexes. This report has been prepared for Townes at LoSo Building 1007 which includes a total of three townhome units (Units 31, 32, & 33) constructed in the central portion of the Site. A Site location map is provided as Figure 1, and a Site Plan that identifies Building 1007 is shown in Figure 2. A table listing the unit numbers, associated monitoring point identifications (see Section 2.0), and unit addresses for Building 1007 is included below. Building 1007 Unit Number Address Associated Monitoring Point ID 31 6111 Cleburne Court MP-1007-31 32 6107 Cleburne Court MP-1007-32 33 6103 Cleburne Court MP-1007-33 2 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/VIMS Install Report_Bldg 1007.docx H&H previously completed soil, groundwater, soil gas, and sub-slab soil gas sampling assessment activities for the Site in Mach 2020 to evaluate subsurface conditions for potential impacts. Results of previous groundwater assessment activities completed in hydraulically upgradient and downgradient portions of the Site did not identify volatile organic compounds (VOCs) at concentrations above the DEQ 2L Groundwater Standards or the DEQ Division of Waste Management (DWM) Residential Vapor Intrusion Groundwater Screening Levels (VISL). Results of previous exterior soil gas assessment activities completed at the Site identified benzene, ethylbenzene, naphthalene, 1,2,4-trimethylbenzene, and 1,3,5-trimethylbenzene in soil gas samples at concentrations above their respective DWM Residential Soil Gas Screening Levels (SGSLs). For ease of reference, the March 2020 data summary tables and a sample location map are included in Appendix A. A Brownfields Agreement between Boulevard at 4920 Old Pineville Road, LLC and DEQ was recorded for the Site on December 10, 2021. Boulevard has since sold a portion of the property to NVR. Although results of the assessment do not indicate the potential for structural vapor intrusion, based on the DEQ Brownfields requirements for townhome developments, installation of a minimum of a vapor intrusion mitigation system (VIMS) is needed for each townhome building. In accordance with the DEQ Brownfields Program Minimum Requirements for Townhome Developments (Townhome Checklist) document, and to be in general compliance with the Brownfields Agreement, the prospective developer (PD) will install a passive VIMS during construction of each proposed townhome building. H&H prepared the Vapor Intrusion Mitigation Plan (VIMP) and revisions to the VIMP based on DEQ comments. The final VIMP dated February 7, 2022, was approved by DEQ in a letter dated March 3, 2022. The DEQ-approved VIMP includes installation of a passive VIMS in each of the townhome buildings and post-installation sub-slab soil gas sampling. Note, for this building, DEQ also requested screening for methane below the slab of the building as described in Section 4.0. This report documents installation of the VIMS for Building 1007 at the Townes at LoSo development. Following installation of the VIMS in other Site townhome buildings and completion of post- 3 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/VIMS Install Report_Bldg 1007.docx construction sampling, additional VIMS installation completion reports will be submitted under separate cover. A discussion of VIMS installation activities and influence testing is provided in Section 2.0, a summary of sub-slab soil gas assessment activities is provided in Section 3.0, a summary of methane screening activities is provided in Section 4.0, a summary and conclusions based on the results of the VIMS installation, soil gas assessment activities, and methane screening are provided in Section 5.0, and the engineer’s certification is provided in Section 6.0. 4 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/VIMS Install Report_Bldg 1007.docx 2.0 VIMS Installation and Influence Testing Building 1007 consists of three individually owned three-story townhomes that contain a monolithic slab on-grade foundation with concrete footings below load bearing walls. Each unit includes a stairwell, two car garage, and a foyer located on the ground floor of the structure. The ground floor for each townhome unit is approximately 640 square feet. The second and third floors contain residential livings spaces. Each building also contains a sloped roof with an attic space located above the third floor that is used to house mechanical equipment. The attic is not designed nor constructed to be a living space. 2.1 VIMS Installation The DEQ-approved VIMP included installation of Vaporblock® Plus 20 (VBP20) vapor barrier manufactured by Viaflex Inc., (Viaflex), previously known as Raven Industries, beneath the concrete slab-on-grade and blocks walls of the townhouse buildings. VBP20 is an ASTM-certified 20-mil, multi-layer, chemically resistant vapor barrier, designed to prevent the migration of VOCs. Technical specifications and installation instructions obtained from Viaflex for the VBP20 vapor barrier are provided in Appendix B. Based on the inspections described below, the vapor barrier was installed per manufacturer installation instructions (Appendix B). Briefly, VBP20 was installed by the construction contractor to cover the ground surface below the entire area of the buildings’ ground floor slabs. The exterior edges of the VBP20 were set under the concrete foundations and installed below the monolithic footings at the tenant separation walls. Seams within the building footprint have a minimum 12-inch overlap and were sealed with VaporSeal™ tape. Small puncture holes and utility penetrations were sealed with VaporSeal™ tape. The VIMP also included installation of a passive mitigation system beneath the ground-level slab to reduce the potential for vapor intrusion into the townhome units by vapor extraction. The units contain ground floor garages adjacent to the foyer so the VIMS and sub-slab vapor extraction piping was extended below the ground-level garages of the townhomes. Sub-slab vapor extraction 5 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/VIMS Install Report_Bldg 1007.docx is accomplished using soil gas collector mats manufactured by Radon Professional Discount Supply (Radon PDS). The soil gas collector mat is a polystyrene plastic rectangular conduit with a geotextile fabric covering that is 1-inch thick and 12-inches wide specifically designed for collecting soil gas from below a building. The soil gas collector mat was connected to the vertical risers using Radon PDS manufactured riser connector fittings in accordance with the manufacturer installation instructions. The vertical risers consist of 3-inch diameter Sch 40 PVC pipes and fittings that run from the slab through the upper floors and the attic space, then terminate above the building’s roofline. The passive VIMS is also enhanced with an Active Ventilation Aura AV-3-PVC (aluminum) stationary wind ventilator that is designed to promote air exhaust from the conveyance piping. Each townhome unit contains an individual sub-slab vent system, riser conveyance piping, monitoring point, and a stationary ventilator. Product specification sheets for the stationary ventilator and soil gas collector mat are included in Appendix B. To further enhance sub-slab vapor transmission and collection effectiveness, a uniform layer of high permeability stone (clean #57) was installed directly below the concrete slab to allow for air movement beneath the entirety of the slab. Soil gas collector mats were installed within the high permeability stone layer. The thickness of the high permeability stone around the collector mats extends a minimum of 2-inches below the mats, and the top of the mat is set flush with the completed stone layer, or approximately 1-inch below the top of the stone. In areas without soil gas mat, a minimum thickness of 4 inches of clean #57 stone was installed. In the event the system needs to be activated with electric fans, one vacuum monitoring point was installed for each townhome unit to measure the pressure differential between indoor air and the sub-slab, and for collection of sub-slab soil gas samples. The locations of the monitoring points are depicted in the as-built drawings provided in Appendix C. During installation of the VIMS in Building 1007, H&H conducted inspections during various phases of construction to confirm the VIMS was installed in accordance with the VIMP. Inspections were completed during the following phases: 6 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/VIMS Install Report_Bldg 1007.docx • after installation of sub-slab soil gas collector mat and monitoring points within the gravel base; • following placement and sealing of the vapor barrier and prior to pouring the concrete building slab; and • after installation of vertical exhaust riser pipe and ventilators. Based upon inspections completed during the VIMS installation activities, the VIMS was installed in general accordance with the DEQ-approved VIMP. VIMS details and specifications, and a VIMS as-built drawing which depicts the VIMS layout are included in Appendix C. A representative photographic log of the installed VIMS components is provided in Appendix D. 2.2 VIMS Influence Testing On November 9, 2023, H&H completed influence testing for Building 1007 to evaluate system sub-slab communication and to confirm that adequate vacuum can be obtained should an active depressurization system be needed in the future. DEQ considers 4 Pascals (Pa), or 0.016-inches of water column (in-WC), differential pressure the minimum vacuum needed for an active depressurization system to effectively treat potential structural vapor intrusion. H&H connected standard electric radon-style RadonAway RP-145c and Festa Radon AMG Eagle Extreme fans to the vertical riser piping to model an active depressurization system. Differential pressure measurements were collected at each vacuum monitoring point using a Dwyer series 475 Mark III Digital manometer (capable of measuring to 0.001 in-WC or 0.25 Pa) to establish baseline conditions prior to use of the electric fans. Following collection of baseline differential pressure measurements, the electric fans were turned on and differential pressure measurements were collected at each riser and monitoring point over varied time intervals. Results of the influence tests indicated sub-slab vacuum measured at the monitoring points ranged from 0.045 in-WC to 0.210 in-WC while using the RadonAway RP 145c fan, and from 0.087 in- WC to 0.427 in-WC when using a higher vacuum Festa Radon AMG Eagle Extreme fan. Both sets of results demonstrates adequate sub-slab system communication and that sufficient vacuum 7 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/VIMS Install Report_Bldg 1007.docx can easily be achieved below the slab of each unit with a standard electric fan. The locations of the permanent monitoring points (denoted by MP nomenclature) are shown on Sheet VM-2 (Appendix C). The summary table of the influence test results is included in Appendix E. 8 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/VIMS Install Report_Bldg 1007.docx 3.0 Sub-Slab Soil Gas Assessment Activities Following successful installation of the VIMS, H&H collected two sub-slab soil gas samples for laboratory analysis from Building 1007. The sub-slab assessment activities were conducted in accordance with the DEQ-approved VIMP and DEQ Division of Waste Management (DWM) Vapor Intrusion Guidance (Guidance) dated March 2018. 3.1 Sub-Slab Soil Gas Sampling On December 28, 2023, H&H collected two sub-slab soil gas samples from permanent monitoring points in Building 1007. The sampling was performed following VIMS installation activities and more than two weeks after installation of the stationary ventilators. The sub-slab soil gas samples were collected from permanent monitoring point locations MP-1007-31 (sample ID SS-1007-31) and MP-1007-33 (sample ID SS-1007-33) as shown on VM-2 (Appendix C). One duplicate sub- slab soil gas sample (SS-1007-DUP) was collected for quality assurance/quality control (QA/QC) purposes during the event from the SS-1007-33 parent location. The duplicate sample was collected utilizing a laboratory supplied stainless-steel sampling “T” which allows for the simultaneous collection of two sub-slab soil gas samples from a single location. To collect the sub-slab soil gas samples, Teflon sample tubing was attached to a 2-inch expandable well cap with a sampling port that was secured onto the 2-inch diameter PVC monitoring point. The tubing was connected to an airflow regulator and laboratory-supplied batch-certified 1-liter stainless steel Summa canister. The air flow regulator was preset by the laboratory to collect a soil gas sample at a flow rate no greater than approximately 100 milliliters per minute. Prior to sample collection, H&H conducted a leak test at each monitoring point by placing a shroud around the monitoring point, expandable well cap, and sampling train including the Summa canister. The air within the shroud was flooded with helium gas and concentrations were measured with a calibrated helium detector. Helium concentrations within the shroud were maintained at approximately 10% to 12%. A GilAir vacuum pump was connected to the sample tubing outside of the shroud and used to purge a minimum of three volumes (monitoring point and sample train) 9 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/VIMS Install Report_Bldg 1007.docx of soil gas into a Tedlar® bag at each sampling point. The helium gas detector was used to measure helium concentrations within the Tedlar bag sample to confirm helium concentrations in the sample were less than 10% of that measured within the shroud. Results of the helium leak checks indicate that helium was not detected in the purge air above the threshold which indicates unacceptable short-circuiting at the monitoring points or within the sampling train were not present. Soil gas sampling field forms completed by sampling personnel are included in Appendix E. Following a successful leak check, the air flow regulators were opened to allow collection of the sub-slab soil gas samples. Vacuum in the Summa canisters was monitored during the sampling event to confirm adequate sample volume was collected at each monitoring point location. Upon completion of sample collection, the air flow regulator was closed to the Summa canister. The canisters were labeled with the sample identification, beginning and ending times, pressure measurements, and the requested analysis. The canisters were then placed in laboratory supplied shipping containers and delivered to Waypoint Analytical (Waypoint) under standard chain of custody protocols for analysis of volatile organic compounds (VOCs) by Environmental Protection Agency (EPA) Method TO-15. 3.2 Sub-Slab Soil Gas Sampling Results The sub-slab soil gas sample analytical results are summarized in Table 1. The results were compared to the DEQ DWM Residential Vapor Intrusion Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs) dated July 2023. The laboratory analytical report with chain of custody record is provided as Appendix F. The parent and duplicate sample concentrations indicated comparable concentrations were detected by the laboratory for these samples. The sub-slab soil gas sample analytical results indicate that multiple compounds were detected above the laboratory method detection limits (MDLs), but below the respective Residential SGSLs, in each sample except for the VOC chloroform. Chloroform was detected at concentrations in samples SS-1007-31 (4.95 μg/m3), SS-1007-33 (31.3 μg/m3), and SS-1007-DUP (31.3 μg/m3 ) above the Residential SGSL of 4.1 μg/m3. No other compounds exceeded their 10 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/VIMS Install Report_Bldg 1007.docx respective Residential SGSL. The chlorinated solvent compounds tetrachloroethene (PCE) and trichloroethene (TCE) were not detected above the laboratory MDL in either sub-slab soil gas sample. Acetone, 2-butanone (methyl ethyl ketone), and tetrahydrofuran were detected at concentrations up to two orders of magnitude above the other compounds detected in each sample, but each detection is well below its respective Residential SGSL. Acetone and 2-butanone are two of the main components in PVC primer, and tetrahydrofuran is one of the main components in PVC glue. PVC primer and glue are common construction materials used throughout construction of the townhome units, including on the sub-slab plumbing pipes. Material safety data sheets for PVC glue and primer used during construction are included as Appendix G. The DEQ DWM Vapor Intrusion SGSLs are very conservative and based on a target carcinogenic risk (TCR) for potential carcinogenic risks of 1 x 10-6 and a hazard quotient (HQ) of 0.2 for potential non-carcinogenic risks. The DEQ and EPA acceptable risk level for potential carcinogenic risks is a cumulative lifetime incremental cancer risk (LICR) of 1 x 10-4 or less and the acceptable level for non-carcinogenic risks is a cumulative hazard index (HI) of 1 or less. The HI is the sum of HQs for each target analyte. H&H utilized the DEQ Risk Calculator (July 2023) to confirm there are no potential vapor intrusion risks at unacceptable levels. H&H modeled a worst-case scenario by using the highest concentrations of any compound detected below Building 1007 in a residential use scenario to conservatively evaluate potential vapor intrusion risks. The calculated cumulative LICR and HI values are provided in Table 1, and a copy of the completed DEQ Risk Calculator is provided in Appendix H. As shown in Table 1, results of the worst-case risk calculations indicate a calculated cumulative LICR of 7.8 x 10-6 and a HI value of 0.021. The calculated cumulative residential use LICR and HI values are well within the DEQ and EPA acceptable levels. These risk calculator results confirm that compound concentrations detected below the slab do not pose vapor intrusion risks at unacceptable levels within the townhome units at Building 1007. 11 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/VIMS Install Report_Bldg 1007.docx 4.0 Methane Gas Screening During previous geotechnical testing activities in the western portion of the Site, buried debris was observed in three areas that appeared to be associated with historical filling activities. The debris was primarily comprised of wood (e.g. plywood, wood planks, etc.), bricks, ceramic tiles, and organic debris. The debris was excavated and disposed off-site in December 2021 and the excavations were subsequently backfilled with clean fill material. Following backfilling activities, H&H measured methane at three temporary methane gas probes (MGP-1, MGP-2, and MGP-3) installed in the former areas of the observed debris. The methane screening indicated that methane was detected at up to 0.7% by volume in one methane gas probe, MGP-3, but no methane was detected in the two other methane gas probes. The methane concentrations were below the NCDEQ Brownfields Program Threshold Criteria for Methane Site Development threshold of 1.25% by volume. However, as a precautionary measure due to the presence of methane in the western portion of the Site, methane screening of sub-slab soil gas was conducted on December 28 and 29, 2023, during the pre-occupancy sampling event in accordance with the email request from the DEQ Brownfields Program Project Manager, Peter Doorn, dated March 25, 2023. The previous methane assessment activities are documented in the H&H Soil Gas Methane Sampling Report, dated March 15, 2022, and a summary table of methane concentrations with sample location maps are included in Appendix A for reference. The December 28, 2023 methane screening was conducted prior to the sub-slab vapor sample collection for VOCs (see Section 3.0) to prevent interference of the methane screening with the purging process for the vapor sample collection. The following day, on December 29, 2023, additional methane readings were collected. The methane screening was conducted by measuring methane below the slab using the existing sub-slab monitoring points in the corresponding units. These points are constructed with 2-inch diameter PVC pipes that were sealed with an expandable well cap and self-sealing quick-connect fitting. A calibrated Landtec Gem 5000® device was then connected to the expandable well cap to take initial differential and static pressure readings. Following collection of the differential pressure readings, a leak check was conducted at each monitoring point by constructing a shroud around the sampling system and flooding the air within the shroud with helium gas. Helium concentrations within the shroud were maintained at 12 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/VIMS Install Report_Bldg 1007.docx approximately 10-15% at each point. A GilAir vacuum pump was connected to the sample tubing outside of the shroud and used to purge a minimum of three volumes (monitoring point and sample train) of soil gas into a Tedlar® bag at each sampling point. The helium concentrations in the shroud are not expected to have influenced the methane results from within the monitoring points. The helium gas detector was used to measure helium concentrations within the Tedlar bag sample to confirm helium concentrations in the sample were less than 10% of that measured within the shroud. Results of the helium leak checks indicate that helium was not detected above 10% of the shroud concentration in the purge air which indicates unacceptable short-circuiting at the monitoring points or within the sampling train were not present. Sampling field forms completed by sampling personnel are included in Appendix E. Following subsurface equilibration after approximately 45-60 seconds, the calibrated Landtec Gem 5000® device was connected to the sample tubing and field measurements of oxygen, carbon dioxide, carbon monoxide, hydrogen sulfide, barometric and static differential pressure, and methane (percent by volume and percent lower explosive limit) were collected for each sample location and recorded by sampling personnel. After completion of the first round of measurements, H&H capped the points with an airtight valve for a minimum of 24-hours. After this period, H&H prior collected the second round of readings using the same procedures as described above. Results of the methane screening are summarized on Table 2. Methane was not detected in any of the screening samples. Based on the methane screening below the slab at Building 1007, methane is not present and thus does not pose a vapor intrusion risk to occupants of Building 1007. 13 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/VIMS Install Report_Bldg 1007.docx 5.0 Summary and Conclusions Construction of townhome Building 1007 of the Townes at LoSo development has been completed at the Blythe Isenhour Brownfields property (Brownfields Project No. 23067-19-060) located in Charlotte, North Carolina. The Townes at LoSo redevelopment includes construction of 12 townhome buildings at the Brownfield property, and separate reports will be submitted to document installation of the VIMS in the other buildings. VIMS Installation and Sub-Slab Soil Vapor Assessment During construction of Building 1007, H&H conducted VIMS installation inspections to confirm the system was installed as designed and completed post-installation sub-slab soil gas sampling activities to evaluate efficacy of the system. The VIMS installation inspections and post- installation sampling activities were completed in general accordance with the DEQ-approved VIMP. Based on the VIMS installation inspections, influence testing, and post-installation sub-slab soil gas sampling results, the VIMS is effectively mitigating potential vapor intrusion risks from Site contaminants. The sub-slab soil gas to indoor air risk calculator results confirms that the cumulative LICR risk and the noncarcinogenic HI risk are within DEQ and EPA acceptable levels. Based on the evaluation, the analytical samples do not indicate that there is unacceptable vapor intrusion risk from Site contaminants to the occupants of Building 1007 and no further pre- occupancy sampling is recommended for this building. Methane Screening Methane screening was conducted below the slab in Building 1007. Methane was not detected in any of the samples and thus does not pose a vapor intrusion risk to occupants of Building 1007. Post-Occupancy Activities In accordance with the DEQ approved VIMP, two post-occupancy sub-slab soil gas sampling events will be completed on an annual basis with the first annual event for Building 1007 expected to be conducted in late 2024 or early 2025. The post-occupancy sub-slab soil gas sampling will 14 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/VIMS Install Report_Bldg 1007.docx include analysis of VOCs by EPA Method TO-15. In accordance with DEQ request, the first post- occupancy sampling event will also include screening for methane below the slab of the building. After the first post-occupancy event, the methane data will be evaluated to determine if additional methane screening would be warranted or if methane screening can be terminated during future sampling events. Note, depending upon the future sub-slab soil gas analytical data, indoor air sampling may also be warranted during future monitoring events. Upon completion of each sampling event, a report will be submitted to DEQ along with an evaluation of the analytical data and VIMS effectiveness. Based on the post-occupancy analytical data and in accordance with the Townhome Checklist, a request to reduce sampling to once every five years, or as otherwise approved by DEQ, may be submitted for DEQ review and approval. In addition, in accordance with the VIMP, an Operations & Maintenance (O&M) Plan will be prepared near the end of construction of the Townes at LoSo development which will describe further on-going maintenance activities for the VIMS as warranted. 15 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/VIMS Install Report_Bldg 1007.docx 6.0 Engineer’s Certification According to the DWM Vapor Intrusion Guidance: “Risk-based screening is used to identify sites or buildings likely to pose a health concern, to identify buildings that may warrant immediate action, to help focus site-specific investigation activities or to provide support for building mitigation and other risk management options including remediation.” In addition, this VIMP was prepared to satisfy the standard vapor intrusion mitigation provisions anticipated to be included in the Brownfields Agreement. Per the North Carolina Brownfields Property Reuse Act 130A- 310.32, a prospective developer, with the assistance of H&H for this project, is to provide DEQ with “information necessary to demonstrate that as a result of the implementation of the brownfields agreement, the brownfields property will be suitable for the uses specified in the agreement while fully protecting public health and the environment instead of being remediated to unrestricted use standards.” It is in the context of these risk-based concepts that the H&H professional engineer makes the following statement: The Vapor Intrusion Mitigation System (VIMS) detailed herein was designed to mitigate intrusion of subsurface vapors into the subject building from known Brownfields Property contaminants in a manner that is in accordance with the most recent and applicable guidelines including, but not limited to, DWM Vapor Intrusion Guidance, Interstate Technology & Regulatory Council (ITRC) guidance, and American National Standards Institute (ANSI)/American Association of Radon Scientists and Technologists (AARST) standards. The sealing professional engineer below is satisfied that the design and its installation are fully protective of public health from known Brownfields Property contaminants. [SEAL] Trinh DeSa North Carolina PE (#044470) Hart & Hickman, PC (#C-1269) Table 1 Summary of Sub-Slab Soil Gas Analytical Data Townes at LoSo - Building 1007 Blythe Isenhour Charlotte, North Carolina Brownfields Project No. 23067-19-060 H&H Project No. NVR-013 Building Number Screening Criteria Sample ID SS-1007-31 Sample Date Units VOCs (TO-15) Acetone 366 407 389 NE Benzene 0.444 J <0.073 0.230 J 12 Carbon Disulfide 2.08 B,J 1.86 B,J 1.75 B,J 4,900 Carbon Tetrachloride <0.155 0.572 J 0.610 J 16 Chloroform 4.95 31.3 31.3 4.1 Cyclohexane 3.90 <0.161 <0.161 42,000 Dichlorodifluoromethane (Freon 12)3.06 3.13 3.02 700 Ethylbenzene <0.106 0.894 J 1.05 J 37 1,1,2-Trichloro-1,2,2-trifluoroethane 0.628 J 0.620 J 0.636 J 35,000 Heptane 0.344 J <0.143 <0.143 2,800 Hexane 1.50 J <0.047 <0.047 4,900 Isopropanol 2.25 B,J 1.09 B,J <0.139 1,400 2-Butanone (MEK)1,010 1,360 1,300 35,000 Methylene Chloride 2.08 2.24 2.11 3,400 Styrene 0.387 J <0.124 <0.124 7,000 Tetrachloroethylene <0.181 <0.181 <0.181 280 Tetrahydrofuran 8.20 8.10 8.46 14,000 Toluene 1.89 0.459 J 0.459 J 35,000 Trichloroethylene <0.199 <0.199 <0.199 14 Trichlorofluoromethane (Freon 11)1.94 J 1.87 J 1.84 J NE 1,2,4-Trimethylbenzene 0.427 J <0.110 0.353 J 420 o-Xylene 0.334 J 1.10 J 1.12 J 700 m&p-Xylene 0.790 J 3.44 J 3.78 J 700 Xylene (Total)1.12 J 4.54 J 4.90 J 700 DEQ Risk Calculator (2)Acceptable Risk Levels Cumulative LICR <1.0 x 10-4 Cumulative HI <1.0 Notes: 1) North Carolina Department of Environmental Quality (NCDEQ) Residential Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs) dated July 2023 and based on a TCR of 1 x 10-6 and a THQ of 0.2. 2) NCDEQ Cumulative Risk Calculator dated July 2023. EPA analytical method shown in parenthesis. Compound concentrations are reported to the laboratory method detection limit (MDL). Only compounds detected in at least one sample and select compounds are shown in the table above. Refer to laboratory analytical report for all compounds. Compound concentrations are reported in micrograms per cubic meter (µg/m3) Worst case risk calculations include highest the concentration of any compound detected in any sample. Bold value indicates an exceedance of the Residential SGSL. NE = not established; VOCs = volatile organic compounds; TCR = target cancer risk; THQ = target hazard quotient LICR = lifetime incremental cancer risk; HI = noncarcinogenic hazard index B = analyte was detected in laboratory blank. J = detected concentration is above the laboratory method detection limit, but below the laboratory calibrated reporting limit resulting in a laboratory estimated value. 0.021 7.8 x 10-6 Worst Case Residential - Soil Gas to Indoor Air Residential SGSLs(1) Building 1007 12/28/2023 µg/m3 SS-1007-33 / SS-1007-DUP https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/Tables & Risk Calc/Table 1 - Bldg 1007 Data Summary Table 1 Hart & Hickman, PC Table 2 Summary of Methane Screening DataTownes at LoSo - Building 1007Blythe Isenhour Charlotte, North CarolinaBrownfields Project No. 23067-19-060H&H Project No. NVR-013% % LELBarometric (in. Hg)Static(in. H₂O)12/28/2023 11:20 21.2 0.1 1.0 0.0 0.0 0.0 29.02 -0.0312/29/2023 16:04 21.8 0.1 0.0 0.0 0.0 0.0 28.95 0.0012/28/2023 11:23 21.1 0.1 0.0 0.0 0.0 0.0 29.03 0.0212/29/2023 16:11 21.9 0.1 0.0 0.0 0.0 0.0 28.96 0.0212/28/2023 11:39 21.4 0.1 0.0 0.0 0.0 0.0 29.04 0.0012/29/2023 16:25 21.4 0.1 0.0 0.0 0.0 0.0 28.95 0.01Notes:Positive differential pressure values indicate that subsurface pressure is greater than ambient air pressure. O2= Oxygen; CO2 = Carbon Dioxide; CO = Carbon Monoxide; H2S = Hydrogen Sulfide;% = Percent By Volume of Air; LEL = Lower Explosive Limit; in Hg = Inch of Mercury; in H₂O = Inch of WaterCO (ppm)Sample ID Sample Date Sample TimeO2 (%) CO2 (%)Building 1007 Unit 31Building 1007 Unit 33Building 1007 Unit 33 (Duplicate)H2S (ppm)Methane Pressurehttps://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/Tables & Risk Calc/Table 2 - Bld. 1007 Methane Data2/7/2024Table 2 (Page 1 of 1)Hart & Hickman, PC USGS The National Map: National Boundaries Dataset, 3DEP ElevationProgram, Geographic Names Information System, National HydrographyDataset, National Land Cover Database, National Structures Dataset,and National Transportation Dataset; USGS Global Ecosystems; U.S. Census Bureau TIGER/Line data; USFS Road Data; Natural Earth Data;U.S. Department of State Humanitarian Information Unit; and NOAANational Centers for Environmental Information, U.S. Coastal ReliefModel. Data refreshed May, 2020. SITE LOCATION MAP OLD PINEVILLE TOWNS PHASE II 4920 OLD PINEVILLE ROADCHARLOTTE, NORTH CAROLINA DATE: 10-29-21 JOB NO: NVR-013 REVISION NO: 0 FIGURE NO: 1 2923 South Tryon Street - Suite 100Charlotte, North Carolina 28203704-586-0007 (p) 704-586-0373 (f)License # C-1269 / # C-245 Geology TITLE PROJECT 0 2,000 4,000 SCALE IN FEET Path: \\HHFS01\Redirectedfolders\sperry\My Documents\ArcGIS\PROJECTS\NVR-013\Figure-1.mxdN U.S.G.S. QUADRANGLE MAP CHARLOTTE, NORTH CAROLINA 2013 QUADRANGLE7.5 MINUTE SERIES (TOPOGRAPHIC) SITE REVISION NO. 0 JOB NO. NVR-013 DATE: 02-06-24 FIGURE NO. 2 BLYTHE ISENHOUR (TOWNES AT LOSO) 4920 OLD PINEVILLE ROAD CHARLOTTE, NORTH CAROLINA SITE DEVELOPMENT PLAN 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology LEGEND SITE PROPERTY BOUNDARY PARCEL BOUNDARY PROPOSED PHASE II BUILDING FOOTPRINT UNIT NUMBER44 33 ANSTON DR I V EBIRCHAM DRIVETHORNDALE LANEOLD PINEVILLE ROADNOTES: 1.AERIAL IMAGERY OBTAINED FROM MECKLENBURG COUNTY GIS (2023). 2.DEVELOPMENT PLAN BASED ON SITE PLAN PROVIDED BY BOHLER ENGINEERING (STAMPED 09/09/21).32 31 36 35 34 39 38 37 42 41 40 45 44 43 48 47 46 8 7 5 4 3 2 1 6 91011121314151617181920212223 24252627282930 BIRCHAM DRIVECLEBURNE C O U R T COLQUITT COURTTHORNDALE LANEBUILDING 1006 BUILDING 1005 BUILDING 1004 BUILDING 1003 BUILDING 1002 BUILDING 1001 BUILDING 1012 BUILDING 1011 BUILDING 1010 BUILDING 1009 BUILDING 1008 BUILDING 1007ATLANTIS LANES:\AAA-Master Projects\NVR, Inc\NVR-013 Blythe-Isenhour\Figures\VIMS Site Map\Site Plan.dwg Appendix A Historical Data Summary Tables and Sample Location Maps Table 1Summary of Soil Analytical DataOld Pineville Towns Phase IIBlythe Isenhour Brownfields Property Charlotte, North CarolinaH&H Job No. NVR-013Evaluation AreaDispenser Island Sample ID1-W 1-E HA-L1 HA-L2 HA-D1 1 2 3 B-1 (1) B-1 (3) Date9/24/2003 10/14/2003 9/24/2003Depth (ft bgs)8855513Sample TypeRange MeanUnitsPCBs (8082)NA NA NA NA NANANA NA NA NA -- -- -- -- -- --TPH (3550/5030) DRO <2 <2 NA NA NANaNA NA4,10079 100-- -- -- -- --GRO<2 <2 <10 <10 <10 NA NA NA3402.8 50-- -- -- -- --Oil and Grease (9071A)NA NA NA NA NA<50120 100NA NANE-- -- -- -- --VOCs (8260B)AcetoneNA NA NA NA NA NA NA NA NA NA --12,000 140,000-- -- --n-ButylbenzeneNA NA NA NA NA NA NA NA NA NA --780 12,000-- -- --sec-Butylbenzene NA NA NA NA NA NA NA NA NA NA --1,600 23,000-- -- --EthylbenzeneNA NA NA NA NA NA NA NA NA NA --6.1 27-- -- --Isopropylbenzene (Cumene)NA NA NA NA NA NA NA NA NA NA --410 2,100-- -- --p-Isopropyltoluene NA NA NA NA NA NA NA NA NA NA --NE NE-- -- --4-Methyl-2-pentanone (MIBK)NA NA NA NA NA NA NA NA NA NA --7,000 30,000-- -- --Naphthalene NA NA NA NA NA NA NA NA NA NA --2.1 8.8-- -- --n-PropylbenzeneNA NA NA NA NA NA NA NA NA NA --780 5,100-- -- --1,2,4-TrimethylbenzeneNA NA NA NA NA NA NA NA NA NA --63 370-- -- --1,3,5-TrimethylbenzeneNA NA NA NA NA NA NA NA NA NA --56 320-- -- --SVOCs (8270D)NaphthaleneNA NA NA NA NA NA NA NA NA NA --2.1 8.8-- -- --Metals (6020/7471/7196A)ArsenicNA NA NA NA NA NA NA NA NA NA --0.68 3--1.0 - 18 4.8BariumNA NA NA NA NA NA NA NA NA NA --3,100 47,000--50 - 1,000 356CadmiumNA NA NA NA NA NA NA NA NA NA --14 200--1.0 - 10 4.3Chromium (total)NA NA NA NA NA NA NA NA NA NA --NE NE--7.0 - 300 65Hexavalent ChromiumNA NA NA NA NA NA NA NA NA NA --0.31 6.5--NS NSTrivalent ChromiumNA NA NA NA NA NA NA NA NA NA --23,000 350,000--NS NSLeadNA NA NA NA NA NA NA NA NA NA --400 800--ND - 50 16MercuryNA NA NA NA NA NA NA NA NA NA --2.3 9.7--0.03 - 0.52 0.121SeleniumNA NA NA NA NA NA NA NA NA NA --78 1,200-- <0.1 - 0.80.42SilverNA NA NA NA NA NA NA NA NA NA --78 1,200--ND - 5.0 NSMetals (6010D TCLP)ChromiumNA NA NA NA NA NA NA NA NA NA -- -- --5 mg/L-- --Notes:1) NC Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Underground Storage Tank (UST) Section Action Levels dated July 20162) NC DEQ Inactive Hazardous Sites Branch (IHSB) Preliminary Soil Remediation Goals (PSRGs) dated July 20203) Environmental Protection Agency (EPA) Maximum Concentration of Contaminants for Toxicity Characteristic Leaching Procedure (TCLP) regulatory level dated November 20044) Range & mean values of background metals for North Carolina soils taken from Elements in North American Soils by Dragun and Chekiri, 2005. Cd and Ag concentrations were taken from Southeastern & Conterminous US soils.Concentrations are reported in milligrams per kilogram (mg/kg).Concentrations are reported to the laboratory method detection limits.Laboratory analytical methods are shown in parentheses.Aside from metals, only those compounds detected in at least one sample are shown in the table above.Bold values exceed the UST Action Levels. VOCs = Volatile Organic Compounds; SVOCs = Semi-Volatile Organic Compounds; PCBs = Polychlorinated Biphenyls; ft bgs = Feet Below Ground Surface; mg/L = Milligrams per Liter NE = Not Established; NS= Not Specified; NA = Not Analyzed; -- = Not Applicable; BDL = Below Laboratory Method Detection Limits; ND = Not Detected; SGP = Soil Gas Point boring; AST = Aboveground Storage Tank; UST = Underground Storage TankJ = Compound was detected above the laboratory method detection limit, but below the laboratory reporting limit resulting in a laboratory estimated concentration. Screening Criteria UST Action Level (1) Residential PSRGs (2)Industrial/ Commercial PSRGs (2)Regional Background Metals in Soil (4)Maximum Concentraion for TCLP (3)Tank Spill Area 5/28/2003Grab Grab3-4GrabProduct Line Former Diesel Pump 8/8/2003mg/kg4/27/1990UST Basinhttps://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/Tables/Blythe Isenhour_Tables 3-19-02.xlsx11/1/2021Table 1 (Page 1 of 2)Hart & Hickman, PC Table 1Summary of Soil Analytical DataOld Pineville Towns Phase IIBlythe Isenhour Brownfields Property Charlotte, North CarolinaH&H Job No. NVR-013Evaluation AreaStorage ShedSample IDCOMP-1 SB-1A COMP-2 SB-2A SB-DUP SGP-5 BG-1 BG-2Date3/4/2020 3/4/2020 3/4/2020 3/4/2020 3/3/2020 3/3/2020Depth (ft bgs)2-3 2-3 2-3 2-4 0-3 0-3Sample Type4-point Grab 3-point GrabRange MeanUnitsPCBs (8082)NAALL BDLNANANANANANA------ ------TPH (3550/5030) DRONA NA NA NA NA NA NA NA100-- -- -- -- --GRONA NA NA NA NA NA NA NA50-- -- -- -- --Oil and Grease (9071A)NA NA NA NA NA NA NA NANE-- -- -- -- --VOCs (8260B)AcetoneNA0.0166 JNA0.0782 J 0.0144 J 0.0592 JNA NA --12,000 140,000-- -- --n-ButylbenzeneNA <0.0027 NA <0.0029 <0.00280.0488NA NA --780 12,000-- -- --sec-Butylbenzene NA <0.002 NA <0.0022 <0.00210.0739NA NA --1,600 23,000-- -- --EthylbenzeneNA <0.001 NA <0.0011 <0.00100.0015 JNA NA --6.1 27-- -- --Isopropylbenzene (Cumene)NA <0.0014 NA <0.0015 <0.00140.0674NA NA --410 2,100-- -- --p-Isopropyltoluene NA <0.0023 NA <0.0025 <0.00240.143NA NA --NE NE-- -- --4-Methyl-2-pentanone (MIBK)NA <0.0036 NA <0.0038 <0.00360.156NA NA --7,000 30,000-- -- --Naphthalene NA <0.0041 NA <0.0043 <0.00420.0131NA NA --2.1 8.8-- -- --n-PropylbenzeneNA <0.0016 NA <0.0017 <0.00160.163NA NA --780 5,100-- -- --1,2,4-TrimethylbenzeneNA <0.0019 NA <0.0020 <0.001918.3NA NA --63 370-- -- --1,3,5-TrimethylbenzeneNA <0.0016 NA <0.0017 <0.00167.0NA NA --56 320-- -- --SVOCs (8270D)Naphthalene<0.0986 NA <0.0992 NA NA0.110 JNA NA--2.1 8.8-- -- --Metals (6020/7471/7196A)Arsenic 2.46NA3.19NA NA1.73 3.676.47--0.68 3--1.0 - 18 4.8Barium 116NA30.6NA NA7.81 48.616.8--3,100 47,000--50 - 1,000 356Cadmium<0.110 NA <0.101 NA NA <0.109 <0.104<0.103--14 200--1.0 - 10 4.3Chromium (total) 32.1NA31.4NA NA25.1 47.4122--NE NE--7.0 - 300 65Hexavalent Chromium<0.349 NA <0.321 NA NA <0.3480.415 J0.584 J--0.31 6.5--NS NSTrivalent Chromium 32.1NA31.4NA NA25.1 47.0121.4--23,000 350,000--NS NSLead 7.93NA11.0NA NA7.34 15.16.44--400 800--ND - 50 16Mercury 0.0585NA0.0675NA NA0.0478 0.08420.139--2.3 9.7--0.03 - 0.52 0.121Selenium 0.818NA0.523 JNA NA0.581 J 0.9880.673--78 1,200-- <0.1 - 0.80.42Silver<0.212 NA <0.195 NA NA <0.211 <0.202<0.200--78 1,200--ND - 5.0 NSMetals (6010D TCLP) Chromium NA NA NA NA NA NA NA<0.100 mg/L-- -- --5 mg/L-- --Notes:1) NC Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Underground Storage Tank (UST) Section Action Levels dated July 20162) NC DEQ Inactive Hazardous Sites Branch (IHSB) Preliminary Soil Remediation Goals (PSRGs) dated July 20203) Environmental Protection Agency (EPA) Maximum Concentration of Contaminants for Toxicity Characteristic Leaching Procedure (TCLP) regulatory level dated November 20044) Range & mean values of background metals for North Carolina soils taken from Elements in North American Soils by Dragun and Chekiri, 2005. Cd and Ag concentrations were taken from Southeastern & Conterminous US soils.Concentrations are reported in milligrams per kilogram (mg/kg).Concentrations are reported to the laboratory method detection limits.Laboratory analytical methods are shown in parentheses.Aside from metals, only those compounds detected in at least one sample are shown in the table above.Bold values exceed the UST Action Levels. VOCs = Volatile Organic Compounds; SVOCs = Semi-Volatile Organic Compounds; PCBs = Polychlorinated Biphenyls; ft bgs = Feet Below Ground Surface; mg/L = Milligrams per Liter NE = Not Established; NS= Not Specified; NA = Not Analyzed; -- = Not Applicable; BDL = Below Laboratory Method Detection Limits; ND = Not Detected; SGP = Soil Gas Point boring; AST = Aboveground Storage Tank; UST = Underground Storage TankJ = Compound was detected above the laboratory method detection limit, but below the laboratory reporting limit resulting in a laboratory estimated concentration. Residential PSRGs (2)Industrial/ Commercial PSRGs (2)Regional Background Metals in Soil (4)UST Action Level (1) Maximum Concentration for TCLP (3) mg/kgCompositeConcrete Storage Pad AST Containment Area Background 3/4/20202-3GrabScreening Criteria https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/Tables/Blythe Isenhour_Tables 3-19-02.xlsx11/1/2021Table 1 (Page 2 of 2)Hart & Hickman, PC Table 2Summary of Groundwater Analytical DataOld Pineville Towns Phase IIBlythe Isenhour Brownfields Property Charlotte, North CarolinaH&H Job No. NVR-013Sample LocationBackground Cross-Gradient DowngradientSample IDTMW-2 TMW-3 TMW-4DateUnitsVOCs (8260B)Toluene<0.24 <0.240.28 J 1.7<0.24600 3,800 16,000SVOCs (8270D)All BDL All BDL All BDL All BDL All BDL -- -- --Metals (6010D/7470A)Arsenic0.646 J <0.250 <0.2500.317 J<0.25010-- --Barium52.8 53.4 94.0 29.1 11.5700-- --Cadmium<0.160 <0.1600.173 J<0.160 <0.1602-- --Chromium (Total) 1.12 J 1.12 J 0.861 J 2.32 0.635 J10-- --Lead<0.240 <0.240 <0.240 <0.240 <0.24015-- --Mercury<0.0490 <0.0490<0.0490<0.0490<0.04901 0.18 0.75Selenium0.410 J<0.3800.393 J<0.380 <0.38020-- --Silver<0.310 <0.310 <0.310 <0.310 <0.31020-- --Notes:1) NC Department of Environmental Quality (DEQ) 15A North Carolina Administrative Code 02L.0202 Groundwater Quality Standard (2L Standard) dated April 20132) DEQ Division of Waste Management (DWM) Vapor Intrusion Groundwater Screening Levels (GWSLs) dated June 2021Concentrations are reported in micrograms per liter (μg/L).Concentrations are reported to the laboratory method detection limits. Laboratory analytical methods are shown in parentheses.Aside from metals, only those compounds detected in at least one sample are shown in the table above.TMW = Temporary Monitoring Well; DUP = Duplicate; VOCs = Volatile Organic Compounds; SVOCs = Semi-Volatile Organic CompoundsBDL = Below Laboratory Method Detection Limits; -- = Not ApplicableJ = Compound was detected above the laboratory method detection limit, but below the laboratory reporting limit resulting in a laboratory estimated concentration.1/22/2019µg/L µg/LConcrete Storage PadTMW-1/TMW-DUPScreening Criteria 2L Standard (1)Residential GWSLs (2)Non-Residential GWSLs (2)https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/Tables/Blythe Isenhour_Tables 3-19-02.xlsx10/28/2021Table 2 (Page 1 of 1)Hart & Hickman, PC Table 3Summary of Soil Gas Analytical DataOld Pineville Towns Phase IIBlythe Isenhour Brownfields Property Charlotte, North CarolinaH&H Job No. NVR-013Sample LocationSample IDSGP-1 SGP-2 SGP-3 SGP-4 SGP-5 SGP-6Date3/5/2020 3/5/2020 3/5/2020 3/9/2020 3/9/2020 3/9/2020Depth (ft bgs)55105812UnitsVOCs (TO-15)Acetone<6.663 31 25<66 <6.624 24220,000 2,700,000Benzene1.2 3.1 2.7 0.37 J314.0 3.3 3.312 1601,3-Butadiene<0.32 <0.32 <0.32 <0.32 <3.2 <0.329.4 9.43.1 412-Butanone (MEK)8.7 J 6.1 J 5.4 J 8.0 J<113.1 J 3.9 J 4.0 J35,000 440,000Carbon Disulfide<0.43 <0.437.1<0.43 <4.3110 7.5 7.44,900 61,000Chloroform0.64 J 1.0<0.36 <0.36 <3.6 <0.36 <0.36 <0.364.1 53Cyclohexane6.5<0.495.8 11 79 12<0.49 <0.4942,000 530,000Dichlorodifluoromethane (Freon 12)<0.431.8 1.6<0.43 <4.3 <0.431.7 1.8700 8,800Ethanol180 59 57 140<6735 30 26NE NEEthyl Acetate<0.54 <0.54 <0.5469<5.4 <0.54 <0.54 <0.54490 6,100Ethylbenzene2.7 7.0 9.9 1.53705.7 4.7 4.637 4904-Ethyltoluene1.1<0.6063 2.4 1,500<0.601.3 1.3NE NEHeptane41 67 79<0.48230 460 84 842,800 35,000Hexane4.7 J<1.2 <1.2 <1.2 <1227 J<1.28.5 J4,900 61,000Isopropanol<0.90 <0.908.0 J 14 J<9.0 <0.90 <0.90 <0.901,400 18,000Methylene Chloride3.7 J<0.844.0 J<0.84 <8.4 <0.84 <0.84 <0.844,200 53,0004-Methyl-2-pentanone (MIBK)<0.43 <0.43 <0.432.7<4.3 <0.43 <0.43 <0.4321,000 260,000Naphthalene<0.80 <0.80220 V-055.1 V-05<8.00.84 J, V-05<0.80 <0.802.8 36Propene<0.64 <0.644.8 J<0.64 <6.4100 110 110NE NETetrachloroethylene1.8 3.9 2.0<0.75 <7.5140 1.8 4.1280 3,500Toluene16 47 52 2.6 55 53 35 3635,000 440,000Trichlorofluoromethane (Freon 11)<0.851.1 J 1.1 J 1.5 J<8.546 2.2 J 2.3 JNE NE1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)<1.2 <1.2 <1.22.2 J<123.2 J<1.2 <1.235,000 440,0001,2,4-Trimethylbenzene3.3 6.6 360 7.54,200<0.634.6<0.63420 5,3001,3,5-Trimethylbenzene1.0 1.9 150 5.93,700<0.621.3 1.2420 5,300m&p-Xylene9.7 26 29 4.3 470 17 17 17700 8,800o-Xylene3.0 8.4 13 2.1 360 4.2 5.7 5.4700 8,800Notes:1) NC Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Vapor Intrusion Sub-slab and Exterior Soil Gas Screening Levels (SGSLs) dated July 2020 Compound concentrations are reported in micrograms per cubic meter (μg/m3).Compound concentrations are reported to the laboratory method detection limits.Laboratory analytical methods are shown in parentheses.Only those compounds detected in at least one sample are shown in the table above.Bold indicates concentration exceeds Residential SGSL.Underlined indicated concentration exceeds Non-Residential SGSL. VOCs = volatile organic compounds; ft bgs= feet below ground surface; NE = Not EstablishedJ = Compound was detected above the laboratory method detection limit, but below the laboratory reporting limit resulting in a laboratory estimated concentration. V-05 = Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound.µg/m3Northern Townhome Footprint Southern Townhome FootprintSGP-7 / SG-DUP123/5/2020Eastern Townhome FootprintScreening Criteria Residential SGSLs (1)Non-Residential SGSLs (1)https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/Tables/Blythe Isenhour_Tables 3-19-02.xlsx11/1/2021Table 3 (Page 1 of 1)Hart & Hickman, PC Table 1Summary of Methane Gas MeasurementsBlythe IsenhourCharlotte, North CarolinaH&H Job No. BOU-014% % LELBarometric (in. Hg)Static (in. H₂O)1/17/2022 10:1621.70.30.00.00.00.028.85 -0.021/18/2022 15:1318.30.80.00.00.00.029.35 -0.041/17/2022 10:0621.40.60.00.00.00.028.85 -0.011/18/2022 15:0818.00.60.00.00.00.029.34 -0.041/17/2022 10:314.65.90.00.00.714.028.860.001/18/2022 14:5810.05.00.00.00.12.029.340.041/17/2022 10:2121.90.60.00.00.00.028.860.001/18/2022 15:2218.50.50.00.00.00.029.340.00Notes:1)MGP-DUP collected at ethane gas probe MGP-2.Positive static pressure values indicate that subsurface pressure is greater than ambient air pressure.O2= Oxygen; CO2 = Carbon Dioxide; CO = Carbon Monoxide; H2S = Hydrogen Sulfide;in H₂O = Inches of Water; % = Percent By Volume of AirMGP-DUP1MGP-2MethanePressureSample ID Sample Date Sample TimeH2S (%)CO (%)O2 (%)MGP-1MGP-3CO2 (%)https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Boulevard Realty Estate Advisors (BOU)/BOU-014 4920 Old Pineville Rd/Supplemental Methane Sampling/Tables/Methane_Tables.xlsx2/8/2022Table 1 (Page 1 of 1)Hart & Hickman, PC SGP-2 SGP-1 SGP-4 TMW-4/BG-2 1 2 3 TMW-1 SB-1D SB-1C SB-1B COMP-1 SB-2A SB-1A TMW-3 SGP-7 TMW-2/BG-1 SGP-6 SGP-3 SGP-5 B-1 COMP-2 SB-2B SB-2C 1-E HA-L1 HA-L2 1-W HA-D1 REVISION NO. 0 JOB NO. NVR-013 DATE: 10-29-21 FIGURE NO. 2 OLD PINEVILLE TOWNS PHASE II 4920 OLD PINEVILLE ROAD CHARLOTTE, NORTH CAROLINA SITE MAP 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology 720 AST CONTAINMENT AREA OLD PINEVILLE ROADNOTES: 1.SOIL BORINGS 1-W AND 1-E WERE COLLECTED BY AQUATERRA IN APRIL 1990. 2.SOIL BORING B-1 WAS ADVANCED BY MACTEC IN APRIL 2003. 3.SOIL BORINGS 1 THROUGH 3 WERE ADVANCED BY MACTEC IN MAY 2003. 4.SOIL BORINGS HA-L1, HA-L2, AND HA-D1 WERE ADVANCED BY FROELING & ROBERTSON, INC. IN SEPTEMBER AND OCTOBER 2003. 5.PARCEL BOUNDARIES OBTAINED FROM MECKLENBURG COUNTY GIS 2019. 6.ELEVATION CONTOURS OBTAINED FROM MECKLENBURG COUNTY LIDAR, 2012. 7.PROPOSED REDEVELOPMENT PLAN WAS PREPARED BY BOHLER ENGINEERING NC, PLLC AND PROVIDED BY THE PROSPECTIVE DEVELOPER. 8.FT. MSL = FEET ABOVE MEAN SEA LEVEL AST = ABOVEGROUND STORAGE TANK UST = UNDERGROUND STORAGE TANK BPN = BROWNFIELDS PROJECT NUMBER LEGEND BROWNFIELDS PROPERTY BOUNDARY LYNX LIGHT RAIL PARCEL BOUNDARY 2' ELEVATION CONTOURS (FT. MSL) PROPOSED BUILDING FOOTPRINT SOIL BORING TEMPORARY MONITORING WELL CO-LOCATED TEMPORARY MONITORING WELL AND SOIL BORING ALIQUOT SOIL BORING LOCATION TEMPORARY SOIL GAS MONITORING POINT CO-LOCATED TEMPORARY SOIL GAS MONITORING POINT AND SOIL BORING B-1 SELF STORAGE FACILITY (4914 OLD PINEVILLE ROAD) CONCRETE PAD: FORMER WASTE STORAGE AND SOLIFICATION AREA 722 7 2 4 7 2 6 728 726724718716714712720 OLD PINEVILLE ROAD BROWNFIELDS PROPERTY FORMER QUEEN CITY BOILER BPN 10061-06-060 (4928 OLD PINEVILLE ROAD) AREA OF FORMER UST SYSTEM S:\AAA-Master Projects\NVR, Inc\NVR-013 Blythe-Isenhour\Figures\Site and Surround Map.dwg, FIG.2 102921, 10/29/2021 3:56:28 PM, sperry REVISION NO. 0 JOB NO. BOU-014 DATE: 11-9-21 FIGURE NO. 3 BLYTHE ISENHOUR 4920 OLD PINEVILLE ROAD CHARLOTTE, NORTH CAROLINA TRENCH AND TEST PIT LOCATION MAP 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology FORMER AST CONTAINMENT AREA OLD PINEVILLE ROADNOTES: 1.AERIAL IMAGERY OBTAINED FROM MECKLENBURG COUNTY GIS, 2020. 2.LIMITS OF THE 2003 EXCAVATION OBTAINED FROM THE SOIL CLEANUP REPORT PREPARED BY MACTEC AND DATED JUNE 20, 2003. 3.TRENCH AND TEST PIT SCREENING ACTIVITIES WERE COMPLETED BY H&H AND GEOSCIENCE ON DECEMBER 30, 2020. SELF STORAGE FACILITY (4914 OLD PINEVILLE ROAD) OLD PINEVILLE ROAD BROWNFIELDS PROPERTY FORMER QUEEN CITY BOILER BPN 10061-06-060 (4928 OLD PINEVILLE ROAD) LEGEND BROWNFIELDS PROPERTY BOUNDARY LYNX LIGHT RAIL PARCEL BOUNDARY LIMITS OF 2003 EXCAVATION TRENCH/TEST PIT LOCATION WITH SECTION NUMBER APPROXIMATE LOCATION OF DEBRIS FORMER CONCRETE PAD AREA OF FORMER UST SYSTEM A B C D TEST PIT E 1 2 3 1 2 3 1 2 3 4 1 2 3 4 A 1 S:\AAA-Master Projects\Boulevard Realty Estate Advisors (BOU)\BOU-014 4920 Old Pineville Rd\Additional Brownfields Assessment\Work Plan\Figures\Figures_20211109.dwg, FIG 3, 11/10/2021 7:42:41 AM, shaynes REVISION NO. 0 JOB NO. BOU-014 DATE: 2-8-22 FIGURE NO. 4 BLYTHE ISENHOUR 4920 OLD PINEVILLE ROAD CHARLOTTE, NORTH CAROLINA SAMPLE LOCATION MAP 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 GeologyOLD PINEVILLE ROADNOTES: 1. AERIAL IMAGERY OBTAINED FROM MECKLENBURG COUNTY GIS, 2020. 2. LIMITS OF THE 2003 EXCAVATION OBTAINED FROM THE SOIL CLEANUP REPORT PREPARED BY MACTEC AND DATED JUNE 20, 2003. SELF STORAGE FACILITY (4914 OLD PINEVILLE ROAD) OLD PINEVILLE ROAD BROWNFIELDS PROPERTY FORMER QUEEN CITY BOILER BPN 10061-06-060 (4928 OLD PINEVILLE ROAD) LEGEND BROWNFIELDS PROPERTY BOUNDARY LYNX LIGHT RAIL PARCEL BOUNDARY LIMITS OF 2003 EXCAVATION APPROXIMATE LOCATION OF DEBRIS APPROXIMATE EXTENT OF EXCAVATION AREA METHANE GAS PROBE LOCATION AREA OF FORMER UST SYSTEM FORMER AST CONTAINMENT AREAFORMER CONCRETE PAD MGP-1 MGP-2 MGP-3 S:\AAA-Master Projects\Boulevard Realty Estate Advisors (BOU)\BOU-014 4920 Old Pineville Rd\Additional Brownfields Assessment\Work Plan\Figures\Figures_20211109.dwg, FIG 4, 11/10/2021 8:08:57 AM, shaynes Appendix B Product Specifications Separation Page Intentionally Left Blank Active Ventilation Products Inc 800-Roof-Vent (766-3836) • 845-565-7770roofvents.com • sales@roofvents.com Aura PVC Pipe Cap Model Number: AV-3-PVC | 3” Diameter • Vent Pipe Cap ventilates out vapors and particulates from the PVC pipe • Used exclusively to cover PVC pipes • Suitable for all climate zones • Designed to prevent rain, snow and wildlife from entering the PVC pipe • Constructed of durable rust-free aluminum • Colors are available • 5 year warranty Dimensions & Specifications CFM Performance Product Weight 1 lb Net Free Vent Area 7 4 mph 26 5.6 mph 38 7.4 mph 51 9.8 mph 59 11 mph 62 0.05 (sq. inches)(sq. feet) Separation Page Intentionally Left Blank SOIL GAS COLLECTOR MAT Installation Guide Radon Ready New Construction Time-saving, low-cost solution Easy Installation Reduce Liability! Used in all 50 states and Internationally Complian under multiple codes: AARST-ANSI, ASTM, IRC Appendix F, EPA, HUD, and more! Simple, modern solutions for soil gases: radon, vapor, and VOCs www.RadonMat.comPhotos, videos, & more @ MADE IN THE USA SOIL GAS COLLECTOR MAT FOR RADON READY NEW CONSTRUCTION According to the US EPA’s model stan-dards for radon control systesm in new building construction, a means for col-lecting soil gas should be installed be-neath the slab. More and more mitigators and buildiers are using PDS’ soil gas collector mat because its installation does not entail any special coordination with plumb-ers or other site contractors. Low pro-file mat saves time as it removes the need for trenching. Just lay radon mat down around the inside perimeter of the foundation, secure it with spikes or landscaping staples, and pour the con-crete. SGC mat is superior to other mat sys-tems because of its thickness and it has a geotextile fabric cloth surround-ing the entire mat material. This fea-ture eliminates the ened to lay a plas-tic barrier or sheet on top of the mat to protect the matrix. Using plastic sheeting can cause concrete cracking due to differential dewatering. The full fabric design greatly enhances both the installation as well as the quality of the concrete slab. When SGC mat is in-stalled below the slab, you’re providing an airspace that intercepts radon--and other soil gases and vapors--before it seeps into the building through the slab. SGC mat also works well as a soil gas collector beneath crawlspace bar-rier due to its low-profile. WHY & HOW IT WORKS The matting is a one inch high by twelve inch wide matrix enveloped in a geotextile filter fabric. 90% of the geomatrix is airspace, which means soil gas has room to move to the col-lection point. This creates incredible pressure field extension for post con-struction system activation. The mat can support concrete without com-pressing, yet is extremely lightweight and easy to handle. This system allows for radon to flow through teh filter fabric and into the airspace. The airspace does not clog because the filter fabric retains teh underlying gravel and soil. The natural airflow through the mat then channels the radon to the T riser to pipe connec-tion. From there, hazardous gas can be vented safely through the roof of the building. Another key element of a soil gas col-lection system is attaching the 4” riser to the mat, such that airflow is not restricted at this critical juncture. The soil gas T riser is unique as it has three ports, two redundant mat entries and one PVC connection to outside air. This unique fitting connects all three sides without special connections or fittings. common duct tape and caulk does the trick. 2 Appendix C VIMS As-Built Drawings VIMS VAPOR BARRIER AND BASE COURSE1 BASE COURSE - CLEAN #57 STONE MIN 4" THICK BENEATH VIMS VAPOR BARRIER VAPOR BARRIER (SEE SPECIFICATION #4) CONCRETE FLOOR SLAB SUBBASE NTSVM1 SECTION THROUGH TURNED DOWN SLAB AT DRIVEWAY4 NTSVM1 VAPOR BARRIER SEALED TO CONCRETE PER MANUFACTURER INSTRUCTIONS. GARAGE DRIVEWAY STUD WALL OR EXTERNAL WALL (NOT PRESENT IN ALL LOCATIONS) BASE COURSE VIMS SUB-SLAB VENT2 NTSVM1 SUBBASE RYAN HOMES, AN NVR, INC COMPANY 10710 SIKES PLACE SUITE 200 CHARLOTTE, NORTH CAROLINA 28277 VAPOR MITIGATION PLAN PREPARED BY 2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology PROFESSIONAL APPROVAL / SEAL H&H NO. NVR-013 VAPOR INTRUSION MITIGATION SYSTEM PLAN SECTION DETAILS VM-1 3" SCH 40 PVC RISER LOCATION FOR ELECTRICAL JUNCTION BOX FOR FUTURE VACUUM FAN IN ENCLOSED ATTIC VIMS STATIONARY VENTILATOR EXHAUST9 NTSVM1 3" HEAVY DUTY NO HUB COUPLING 3" STATIONARY VENTILATOR (ACTIVE VENTILATION PRODUCTS AURA AV-3-PVC ALUMINUM VENTILATOR) RISER DUCT PIPE THROUGH ROOF FLASHING ROOFTOP, SLOPED COMPACTED FILL BELOW DRIVEWAY EXTEND VAPOR BARRIER TO OUTSIDE OF FOOTER, WHERE POSSIBLE 4920 OLD PINEVILLE ROAD CHARLOTTE, NORTH CAROLINABROWNFIELDS PROJECT NUMBER 23067-19-060TOWNES AT LOSOSOIL GAS COLLECTOR MAT WITHIN BASE COURSE - MIN 4" THICKNESS WITH MIN 1-INCH BELOW (SEE SPECIFICATIONS #4 & #5) VAPOR BARRIER (SEE SPECIFICATION #4) SUBBASE CONCRETE FLOOR SLAB SECTION THROUGH EXTERIOR WALL NTSVM1 BRICK OR HOUSE SIDING EXTERNAL WALL (NOT PRESENT AT ALL LOCATIONS) STUD WALL BASE COURSE VAPOR BARRIER SEALED TO CONCRETE PER MANUFACTURER INSTRUCTIONS. SUBBASE 3 FOOTER FULLY GROUTED CMU BLOCK WALL SECTION THROUGH TENANT SEPARATION BLOCK WALL NTSVM1 BRICK OR HOUSE SIDING EXTERNAL WALL (NOT PRESENT AT ALL LOCATIONS) STUD WALL BASE COURSE VAPOR BARRIER SEALED TO CONCRETE PER MANUFACTURER INSTRUCTIONS (SEE SPECIFICATION #3) SUBBASE 5 SECTION THROUGH TENANT SEPARATION BLOCK WALL WITH MAT NTSVM1 BASE COURSE VAPOR BARRIER SEALED TO CONCRETE PER MANUFACTURER INSTRUCTIONS (SEE SPECIFICATION #4) SUBBASE 6 SINGLE OR DOUBLE STUD SEPARATION WALL SOIL GAS COLLECTOR MAT (SEE SPECIFICATION #6) VAPOR BARRIER BENEATH CONCRETE FOUNDATION FOOTER FOOTER VIMS RISER AT VERTICAL SLAB PENETRATION7 VM1 NTS BRICK OR HOUSE SIDING EXTERNAL WALL (NOT PRESENT AT ALL LOCATIONS) STUD WALL BASE COURSE VAPOR BARRIER SEALED TO PIPE AND CONCRETE PER MANUFACTURER INSTRUCTIONS. SUBBASE RUN RISER PIPE TO ROOF (SEE DETAIL #7) INSIDE (OCCUPIED SPACE) OUTSIDE/ ADJACENT UNIT SOIL GAS COLLECTOR MAT 3" SCH 40 PVC RISER DUCT PIPE (SEE SPECIFICATION #6) FOOTER INSIDE (MECH. ROOM) FLOOR SYSTEM, SEE FRAMING PLANS 4" TO 3" PVC REDUCER 4" SCH 40 PVC RISER DUCT PIPE SOIL GAS COLLECTOR MAT CONNECTION BLOCK TO PVC (ONE 0.5" DIAMETER HOLE DRILLED IN BOTTOM FOR MOISTURE DRAINAGE) SOIL GAS COLLECTOR MAT CONNECTION SEALED TO 4" SCH 40 PVC RISER WITH POLYURETHANE SEALANT IF EXTERIOR GRADE IS HIGHER THAN THE SLAB ELEVATION, WRAP VAPOR BARRIER UP THE SIDE OF THE FOOTER 8 NTSVM1 BRICK OR SIDING EXTERNAL WALL (NOT PRESENT AT ALL LOCATIONS) STUD WALL BASE COURSE 2" SCH 40 PVC ELBOW 2" OPEN ENDED PIPE, PLACED AT A MINIMUM OF 3' FROM EXTERIOR TURN-DOWN SLABS 2" SOLID SCH 40 PVC LOCKABLE WEATHERPROOF ENCLOSURE ON OUTSIDE OF HOUSE WALL. REMOVABLE PIPE PLUG AT END OF 2" PIPE. PERMANENT VACUUM MONITORING POINT FEBRUARY 6, 2024 AS-BUILT DRAWING BUILDING 1007 02/06/24 S:\AAA-Master Projects\NVR, Inc\NVR-013 Blythe-Isenhour\VIMS Install Reports\Building 1007\Figures\Building1007_AsBuilt.dwg, 2/6/2024 9:29:55 PM,DWG To PDF.pc3 RYAN HOMES, AN NVR, INC COMPANY 10710 SIKES PLACE SUITE 200 CHARLOTTE, NORTH CAROLINA 28277 VAPOR MITIGATION PLAN PREPARED BY 2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology PROFESSIONAL APPROVAL / SEAL H&H NO. NVR-013 VAPOR INTRUSION MITIGATION SYSTEM PLAN SPECIFICATIONS VM-1A4920 OLD PINEVILLE ROAD CHARLOTTE, NORTH CAROLINABROWNFIELDS PROJECT NUMBER 23067-19-060TOWNES AT LOSOFEBRUARY 6, 2024 VAPOR INTRUSION MITIGATION SYSTEM (VIMS) SPECIFICATIONS 1.THE AS-BUILT DRAWINGS ARE INTENDED TO DOCUMENT THE VIMS COMPONENT INSTALLATION ONLY AND IS NOT INTENDED TO DOCUMENT CONSTRUCTION OF STRUCTURAL COMPONENTS NOT RELATED TO THE VIMS. CONSTRUCTION CONTRACTORS VERIFIED CONSISTENCY OF VIMS DETAILS WITH APPLICABLE STRUCTURAL, ARCHITECTURAL, MECHANICAL, AND PLUMBING PLANS AND RESOLVED INCONSISTENCIES WITH THE DESIGN ENGINEER PRIOR TO VIMS INSTALLATION. 2.INSPECTIONS: INSPECTIONS OF EACH COMPONENT OF THE VIMS WERE CONDUCTED BY THE ENGINEER, OR ENGINEER'S DESIGNEE, TO CONFIRM VIMS COMPONENTS WERE INSTALLED PER THE APPROVED DESIGN. THE INSPECTIONS INCLUDED: (1) INSPECTION OF SUB-SLAB PIPING LAYOUT AND GRAVEL PLACEMENT PRIOR TO INSTALLING VAPOR BARRIER (LINER); (2) INSPECTION OF VAPOR BARRIER PRIOR TO POURING CONCRETE; (3) INSPECTION OF ABOVE-GRADE PIPING LAYOUT; AND (4) INSPECTION OF FAN AND VENT PIPE CONNECTIONS. 3.CONSTRUCTION CONTRACTORS AND SUB-CONTRACTORS WERE INSTRUCTED TO USE "LOW OR NO VOC" (INCLUDING NO PCE OR TCE) PRODUCTS AND MATERIALS, WHEN POSSIBLE. THE CONSTRUCTION CONTRACTOR AND SUB-CONTRACTORS PROVIDED SELECT SAFETY DATA SHEETS (SDS) TO THE ENGINEER FOR PRODUCTS AND MATERIALS USED DURING CONSTRUCTION. 4.VIMS VAPOR BARRIER IS VAPORBLOCK PLUS 20 VAPOR BARRIER MANUFACTURED BY VIAFLEX,INC. THE VAPOR BARRIER WAS INSTALLED AS SPECIFIED HEREIN AND PER MANUFACTURER INSTALLATION INSTRUCTIONS TO CREATE A CONTINUOUS BARRIER BELOW GROUND FLOOR SLABS AND FOOTERS. A BASE COURSE CONSISTING OF CLEAN #57 STONE WAS INSTALLED BENEATH THE VIMS VAPOR BARRIER. IN AREAS AROUND THE SOIL GAS COLLECTOR MAT, THE BASE COURSE LAYER WAS INSTALLED WITH A MINIMUM 2-INCH LAYER BELOW THE MAT AND A MINIMUM THICKNESS OF 4-INCHES ACROSS THE ENTIRE SLAB. PENETRATIONS WERE SEALED IN GENERAL ACCORDANCE TO VAPOR BARRIER MANUFACTURER INSTALLATION INSTRUCTIONS AS FOUND IN THE MANUFACTURER INSTALLATION GUIDELINES. SMALL PUNCTURE HOLES WERE SEALED WITH THE VAPORSEALTM TAPE OR BUTYL SEAL DOUBLE SIDED TAPE AND LARGER TEARS OR DAMAGE WERE REPAIRED USING A PATCH THAT OVERLAPS THE DAMAGED AREA AND THEN WAS TAPED ALONG THE SEAMS. 5.CONSTRUCTION CONTRACTORS AND SUB-CONTRACTORS WERE INSTRUCTED TO AVOID THE USE OF TEMPORARY FORM BOARDS THAT PENETRATE THE VAPOR BARRIER WHERE POSSIBLE. AS FORM BOARDS WERE REMOVED, THE CONTRACTOR OR SUB-CONTRACTORS WERE INSTRUCTED TO SEAL PENETRATIONS IN ACCORDANCE WITH VAPOR BARRIER MANUFACTURER INSTALLATION INSTRUCTIONS. 6.VIMS BELOW AND ABOVE GRADE PIPING WAS SLOPED A MINIMUM OF 18 UNIT VERTICAL IN 12 UNITS HORIZONTAL (1% SLOPE) TO GRAVITY DRAIN. SOLID SECTIONS OF HORIZONTAL COLLECTION PIPE WERE SUPPORTED TO PREVENT PIPE SAG OR LOW POINT AND MAINTAIN 1% SLOPE TOWARD SLOTTED SECTIONS TO DRAIN CONDENSATION. HORIZONTAL SUB-SLAB COLLECTION SYSTEM CONSISTS SOIL GAS COLLECTOR MAT WHICH IS APPROXIMATELY 1-INCH THICK BY 12-INCHES WIDE RECTANGULAR CONDUIT. 7.3” SCH 40 PVC RISER DUCT PIPING EXTENDS IN A VERTICAL ORIENTATION THROUGH THE BUILDING ROOF AND TERMINATES A MINIMUM OF 1 FT ABOVE THE BUILDING ROOF LINE. ACTIVE VENTILATION PRODUCTS AURA AV-3-PVC ALUMINUM VENTILATORS WERE INSTALLED ON THE EXHAUST DISCHARGE END OF EACH RISER DUCT PIPE. A 3" PVC COUPLING WAS INSTALLED AT THE DISCHARGE END OF THE 3" RISER DUCT PIPE AND THE VENTILATOR WAS SECURED TO THE PVC RISER IN A VERTICAL ORIENTATION. EXHAUST DISCHARGE IS NOT LESS THAN 10 FT (IN ANY DIRECTION) FROM AIR INTAKE OPENINGS INCLUDE WINDOWS, DOORS, AND OTHER GRAVITY AIR INTAKE OPENINGS. AN ELECTRICAL JUNCTION BOX (120VAC) WAS INSTALLED NEAR THE RISER WITHIN THE ATTIC SPACE FOR CONVERSION TO ELECTRIC FANS, IF REQUIRED. 8.ABOVE-SLAB ACCESSIBLE RISER DUCT PIPING WAS PERMANENTLY IDENTIFIED BY MEANS OF A LABEL AT A MINIMUM OF ONCE EVERY 10-LINEAR FT WITH "VAPOR MITIGATION - CONTACT HOA". THE RISER PIPE NEAR THE VENTILATOR WAS LABELED WITH "VAPOR MITIGATION SYSTEM - CONTACT HOA IF DAMAGED" IN AN ACCESSIBLE LOCATION IN THE ATTIC. AS-BUILT DRAWING BUILDING 1007 02/06/24 S:\AAA-Master Projects\NVR, Inc\NVR-013 Blythe-Isenhour\VIMS Install Reports\Building 1007\Figures\Building1007_AsBuilt.dwg MP-1007-32 MP-1007-33MP-1007-31 RYAN HOMES, AN NVR, INC COMPANY 10710 SIKES PLACE SUITE 200 CHARLOTTE, NORTH CAROLINA 28277 VAPOR MITIGATION PLAN PREPARED BY 2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology PROFESSIONAL APPROVAL / SEAL VAPOR INTRUSION MITIGATION SYSTEM PLAN PLAN VIEW VM-2 LEGEND EXTENT OF VAPOR BARRIER - SEE SPECIFICATION #3 ON SHEET VM-1A SOIL GAS COLLECTOR MAT VERTICAL RISER (3" SCH 40 PVC) AND EXHAUST LOCATION VACUUM MONITORING POINT (2" SCH 40 PVC WITH OPEN END) LOAD BEARING WALL NOTES: 1.ONE VACUUM MONITORING POINT WAS INSTALLED PER UNIT. THE VACUUM MONITORING POINTS WERE INSTALLED ON THE FRONT SIDE OF THE UNITS. 2.REFER TO SPECIFICATIONS 1 THROUGH 8 AND SECTION DETAILS ON SHEETS VM-1 AND VM-1A. 3.EACH UNIT IS APPROXIMATELY 640 SQ FT (16 FT X 40 FT). H&H NO. NVR-0134920 OLD PINEVILLE ROAD CHARLOTTE, NORTH CAROLINABROWNFIELDS PROJECT NUMBER 23067-19-060TOWNES AT LOSO4 VM1 7/9 VM1 7/9 VM1 8 VM1 3 VM1 6 VM1 8 VM1 8 VM1 7/9 VM1 3 VM1 5 VM1 2 VM1 1 VM1 FEBRUARY 6, 2024CLEBURNE COURTAS-BUILT DRAWING BUILDING 1007 UNIT 33 6103 CLEBURNE COURT UNIT 32 6107 CLEBURNE COURT UNIT 31 6111 CLEBURNE COURT ATLANTIS LANE 02/06/24 S:\AAA-Master Projects\NVR, Inc\NVR-013 Blythe-Isenhour\VIMS Install Reports\Building 1007\Figures\Building1007_AsBuilt.dwg Appendix D VIMS Installation Photographs Photograph 2: Representative photograph of the monitoring point installation prior to vapor barrier installation.NVR-0132923 S. Tryon Street, Suite 100 Charlotte, NC 28203 704.586.0007(p) 704.586.0373(f) Photograph 1: Representative photograph of the gravel base and sub-slab soil gas collector mats and riser pipes. TOWNES AT LOSO – BUILDING 1007 4920 OLD PINEVILLE ROAD CHARLOTTE, NORTH CAROLINA Photographs 3 & 4: Representative photograph of the Viaflex, Inc. VaporBlock Plus 20 vapor barrier installed prior to the slab pour.NVR-0132923 S. Tryon Street, Suite 100 Charlotte, NC 28203 704.586.0007(p) 704.586.0373(f) TOWNES AT LOSO – BUILDING 1007 4920 OLD PINEVILLE ROAD CHARLOTTE, NORTH CAROLINA 2923 S. Tryon Street, Suite 100 Charlotte, NC 28203 704.586.0007(p) 704.586.0373(f) Photographs 5 & 6: Representative photograph of properly pitched and labeled riser pipe.NVR-013Vapor mitigation label on riser Photograph 7: Representative photograph of buildings with stationary ventilators installed on the roof. TOWNES AT LOSO – BUILDING 1007 4920 OLD PINEVILLE ROAD CHARLOTTE, NORTH CAROLINA Appendix E Field Forms and Field Data Category Example Criteria Correct vapor barrier type Proper vapor barrier overlap and seals around penetrations per manufacturer instructions Good condition of vapor barrier Proper base layer (i.e., gravel, aerated flooring) and thickness Proper placement, type, and pitch of VIMS vent piping Proper placement, type, and pitch of monitoring points Correct vapor barrier type Proper vapor barrier overlap and seals around penetrations per manufacturer instructions Proper vapor barrier installation along vertical walls (e.g. retaining walls, elevators, etc.) Good condition of vapor barrier Riser pipe material and fitting connections Proper pitch towards sub-slab (gravity drain) Appropriate VIMS labels Correct fan/ventilator Fan/ventilator operation Proper fittings and protection (varmint screens, electrical covers, etc.) Appropriate VIMS labels Proper distance from roof intakes and parapets Pilot Test Pilot test completed Checkout Monitoring points finished and accessible (Can perform pilot test before MPs are fully finished) MP Sampling Sub-slab sampling completed SMS Vent Riser Piping SMS SMS SMS Fan/Ventilator SMS SMS SMS SMS SMS SMS Sub-Slab SMS SMS SMS SMS Vapor Barrier SMS SMS SMS SMS Vapor Intrusion Mitigation System - Inspection Checklist Site Name and H&H Project #: Townes at LoSo, NVR-013 DEQ Brownfields ID: 23067-19-060 Building/Area ID: Bldg. 1007 Start Date and End Date: November 2023 - February 2024 H&H Construction Manager: Shannon Switch Footers Vapor Barrier (If poured separate) SMS SMS SMS Proper Installation (Initial below) https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/Field Forms/VIMS Inspection Checklist_Reporting\1012 Table E-1VIMS Installation Completion ReportTownes at LoSo – Building 1007Blythe IsenhourCharlotte, North CarolinaBrownfields Project No. 23067-19-060H&H Job No. NVR-013Baseline Initial Follow-upFan0.0001.4081.402MP-1007-31 0.0000.0450.046Fan0.0003.7663.756MP-1007-31 0.0000.0890.087Fan0.0001.3961.390MP-1007-32 0.0000.1110.113Fan0.0003.2203.211MP-1007-32 0.0000.2260.228Fan0.0001.4551.448MP-1007-33 0.0000.2100.205Fan0.0003.3323.342MP-1007-33 0.0000.4270.425NotesVacuum measurements are reported in inches of water column (in-WC). Vacuum measurements were collected from above slab. Follow-up reading collected approximately 5 minutes after initial reading. MP = Monitoring PointRP 145cAMG Eagle ExtremeRP 145cVacuum (in-WC)Fan TypeBuilding 100733323111/9/2023AMG Eagle ExtremeRP 145cPoint TypeDateUnit NumberBuildingAMG Eagle Extremehttps://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NVR, Inc/NVR-013 Blythe-Isenhour/VIMS Install Reports/Building 1007/Field Forms/Pilot Test_report1/5/2024Table E-1 (Page 1 of 1) Hart & Hickman, PC &Žƌŵ^sͲϭ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͗͗Z͗^͗͗Z͗^͗͗Z͗^͗͗Z͗^͗͗Z͗^͗͗Z͗6 VDPSOH,'& FDQLVWHU,'5 UHJXODWRU,'66 VXEVODE6* VRLOJDV3HUP SHUPDQHQW7HPS WHPSRUDU\ 9ROXPH3XUJHG [SXUJHYROXPHV  / D/DVWXSGDWHG+J LQFKHVRIPHUFXU\SSP SDUWVSHUPLOOLRQ1RWHVBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBB6DPSOH,'7\SH9DSRU0RQLWRULQJ3RLQW&RQVWUXFWLRQ +HOLXP/HDN7HVWEŽƚĞ͗>ĞĂŬdĞƐƚZĞƋƵŝƌĞŵĞŶƚƐWĞƌEYtDsĂƉŽƌ/ŶƚƌƵƐŝŽŶ'ƵŝĚĂŶĐĞ͕ůĞĂŬƚĞƐƚƉĂƐƐĞƐŝĨŚĞůŝƵŵĐŽŶĐĞŶƚƌĂƚŝŽŶŝŶƉƵƌŐĞĂŝƌŝƐůĞƐƐƚŚĂŶϭϬйŽĨŚĞůŝƵŵĐŽŶĐĞŶƚƌĂƚŝŽŶŝŶƐŚƌŽƵĚ͘/ OHQJWKRIWXELQJSLSH IW D IRUGLDPHWHU /IW D IRUGLDPHWHU /IW ͗ͰhƐĞƌƐͰŵǀĂǁƚĞƌͰƌŽƉďŽdžͰLJKƚŚĞƌͰ&ŽƌŵĚŝƚƐͰ/YͲ^^sͰsĂƉŽƌ^ĂŵƉůŝŶŐ&ŽƌŵƐͺsϲ͘Ϭ^ƵďͲ^ůĂďͬ^Žŝů'ĂƐ^ĂŵƉůŝŶŐsĂƉŽƌ/ŶƐƚĂůůĂƚŝŽŶ&ŝĞůĚ&Žƌŵ,ĂƌƚΘ,ŝĐŬŵĂŶ͕WNVR-013 SMS 50's, overcastBld. 1007 Unit 31--SS Perm. Conc. 5 Gravel NA Full12/28/23 11:1555 Pump 10 10.2 0 ppm Yes--Bld. 1007 Unit 33 & DUP--SS Perm. Conc. 5 Gravel NA Full12/28/23 11:2055 Pump 10 10.8 0 ppm Yes--SS-1007-315976SS Perm. Conc. 5 Gravel NA Full12/28/23 12:1055 Pump 15 10.5 0 ppm Yes16213SS-1007-33 / DUP13687 / 11377SS Perm. Conc. 5 Gravel NA Full12/28/23 12:4055 Pump 15 11.6 0 ppm Yes13132Bld. 1007 Unit 31--SS Perm. Conc. 5 Gravel NA Full12/29/23 16:0045 Pump 10 12.3 0 ppm Yes--Bld. 1007 Unit 33 & DUP--SS Perm. Conc. 5 Gravel NA Full12/29/23 16:0545 Pump 10 11.7 0 ppm Yes-- &Žƌŵ^sͲϮ6XE6ODE6RLO*DV9DSRU6DPSOLQJ)LHOG)RUP3URMHFW1RBBBBBBBBBBBBBBBBBBB 6DPSOHUBBBBBBBBBBBBBBBBBBBBBB :HDWKHUBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBB'DWH3URSRVHG6DPSOLQJ'XUDWLRQ7LPH&DQLVWHU3UHVVXUH2XWGRRU7HPSHUDWXUH2XWGRRU+XPLGLW\,QGRRU7HPSHUDWXUH,QGRRU+XPLGLW\PPGG\\ 0LQXWHV KU +JR)R)^͗%HJLQQLQJ͗0LGGOHZ͗(QG^͗%HJLQQLQJ͗0LGGOHZ͗(QG^͗%HJLQQLQJ͗0LGGOHZ͗(QG^͗%HJLQQLQJ͗0LGGOHZ͗(QG^͗%HJLQQLQJ͗0LGGOHZ͗(QG^͗%HJLQQLQJ͗0LGGOHZ͗(QG6 VDPSOH,'& FDQLVWHU,'5 UHJXODWRU,'66 VXEVODE6* VRLOJDV3HUP SHUPDQHQW7HPS WHPSRUDU\/DVWXSGDWHG+J LQFKHVRIPHUFXU\1RWHVBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBB^ŝnjĞ͗&ůŽǁZĂƚĞ͗^ŝnjĞ͗&ůŽǁZĂƚĞ͗6DPSOH,'^ŝnjĞ͗&ůŽǁZĂƚĞ͗^ŝnjĞ͗&ůŽǁZĂƚĞ͗^ŝnjĞ͗&ůŽǁZĂƚĞ͗^ŝnjĞ͗&ůŽǁZĂƚĞ͗6DPSOLQJ,QIRUPDWLRQ ,QGRRU3DUDPHWHUV2XWGRRU3DUDPHWHUV6DPSOLQJ3HULRGEŽƚĞ͗WĞƌEYtDsĂƉŽƌ/ŶƚƌƵƐŝŽŶ'ƵŝĚĂŶĐĞ͕ƐŚƵƚͲŝŶƚĞƐƚĂŶĚŚĞůŝƵŵůĞĂŬĐŚĞĐŬŵƵƐƚďĞƉĂƐƐĞĚďĞĨŽƌĞƐĂŵƉůŝŶŐ͗͘ͰhƐĞƌƐͰŵǀĂǁƚĞƌͰƌŽƉďŽdžͰLJKƚŚĞƌͰ&ŽƌŵĚŝƚƐͰ/YͲ^^sͰsĂƉŽƌ^ĂŵƉůŝŶŐ&ŽƌŵƐͺsϲ͘Ϭ^ƵďͲ^ůĂďͬ^Žŝů'ĂƐ^ĂŵƉůŝŶŐsĂƉŽƌ^ĂŵƉůŝŶŐ&ŝĞůĚ&Žƌŵ,ĂƌƚΘ,ŝĐŬŵĂŶ͕WNVR-013 SMS 50s, overcastSS-1007-311 L597612/28/23 100.1 L/min12:20 -1755 45 --1621312:26 -512:15 -29--SS-1007-33 / SS-1007-DUP1 L12:45 -2913687 / 1137712/28/23 1012:50 -1855 45 -- --0.1 L/min1313212:57 -5 -- = not applicable Appendix F Laboratory Analytical Report   Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.   1/5/2024 Hart & Hickman (Charlotte) Shannon Switch 2923 South Tryon St. Ste 100 Charlotte, NC, 28203 Ref: Analytical Testing Lab Report Number: 23-362-0019 Client Project Description: Townes At Laso Dear Shannon Switch: Waypoint Analytical, LLC (Charlotte) received sample(s) on 12/28/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Angela D Overcash Senior Project Manager Page 1 of 22 Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date 07/31/202437735State ProgramNorth Carolina 12/31/2024402State ProgramNorth Carolina 07/31/202499012State ProgramSouth Carolina 12/31/202399012State ProgramSouth Carolina Page 1 of 1 00016/23-362-0019 Page 2 of 22 Report Number: Sample Summary Table Client Project Description: 23-362-0019 Townes At Laso Lab No Client Sample ID Matrix Date Collected Date Received 12/28/2023 12:45Air 92818 SS-1007-33 12/28/2023 16:00 12/28/2023Air 92819 SS-1007-DUP 12/28/2023 16:00 12/28/2023 12:15Air 92820 SS-1007-31 12/28/2023 16:00 Page 3 of 22 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-362-0019 Report Limit Project:Townes At Laso V 92818SS-1007-33 407 01/02/2024 17:28TO-15 Acetone µg/m3 4.04 JB1.86 01/03/2024 19:38TO-15 Carbon Disulfide µg/m3 0.060 J0.572 01/03/2024 19:38TO-15 Carbon Tetrachloride µg/m3 0.155 31.3 01/03/2024 19:38TO-15 Chloroform µg/m3 0.086 3.13 01/03/2024 19:38TO-15 Dichlorodifluoromethane µg/m3 0.134 J0.894 01/03/2024 19:38TO-15 Ethylbenzene µg/m3 0.106 J0.620 01/03/2024 19:38TO-15 1,1,2-Trichloro-1,2,2-trifluoroethane µg/m3 0.561 JB1.09 01/03/2024 19:38TO-15 Isopropyl Alcohol µg/m3 0.139 1360 01/02/2024 17:28TO-15 Methyl Ethyl Ketone (MEK)µg/m3 4.48 2.24 01/03/2024 19:38TO-15 Methylene Chloride µg/m3 0.488 8.10 01/03/2024 19:38TO-15 Tetrahydrofuran µg/m3 0.107 J0.459 01/03/2024 19:38TO-15 Toluene µg/m3 0.090 J1.87 01/03/2024 19:38TO-15 Trichlorofluoromethane µg/m3 0.130 J1.10 01/03/2024 19:38TO-15 o-Xylene µg/m3 0.157 J3.44 01/03/2024 19:38TO-15 m,p-Xylene µg/m3 0.217 J4.54 01/03/2024 19:38TO-15 Xylene (Total)µg/m3 0.157 V 92819SS-1007-DUP 389 01/02/2024 18:05TO-15 Acetone µg/m3 4.04 J0.230 01/03/2024 20:30TO-15 Benzene µg/m3 0.073 JB1.75 01/03/2024 20:30TO-15 Carbon Disulfide µg/m3 0.060 J0.610 01/03/2024 20:30TO-15 Carbon Tetrachloride µg/m3 0.155 31.3 01/03/2024 20:30TO-15 Chloroform µg/m3 0.086 3.02 01/03/2024 20:30TO-15 Dichlorodifluoromethane µg/m3 0.134 J1.05 01/03/2024 20:30TO-15 Ethylbenzene µg/m3 0.106 J0.636 01/03/2024 20:30TO-15 1,1,2-Trichloro-1,2,2-trifluoroethane µg/m3 0.561 1300 01/02/2024 18:05TO-15 Methyl Ethyl Ketone (MEK)µg/m3 4.48 2.11 01/03/2024 20:30TO-15 Methylene Chloride µg/m3 0.488 8.46 01/03/2024 20:30TO-15 Tetrahydrofuran µg/m3 0.107 J0.459 01/03/2024 20:30TO-15 Toluene µg/m3 0.090 J1.84 01/03/2024 20:30TO-15 Trichlorofluoromethane µg/m3 0.130 J0.353 01/03/2024 20:30TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J1.12 01/03/2024 20:30TO-15 o-Xylene µg/m3 0.157 J3.78 01/03/2024 20:30TO-15 m,p-Xylene µg/m3 0.217 J4.90 01/03/2024 20:30TO-15 Xylene (Total)µg/m3 0.157 V 92820SS-1007-31 366 01/02/2024 18:41TO-15 Acetone µg/m3 4.04 Page 4 of 22 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-362-0019 Report Limit Project:Townes At Laso V 92820SS-1007-31 J0.444 01/03/2024 21:21TO-15 Benzene µg/m3 0.073 JB2.08 01/03/2024 21:21TO-15 Carbon Disulfide µg/m3 0.060 4.95 01/03/2024 21:21TO-15 Chloroform µg/m3 0.086 3.90 01/03/2024 21:21TO-15 Cyclohexane µg/m3 0.161 3.06 01/03/2024 21:21TO-15 Dichlorodifluoromethane µg/m3 0.134 J0.628 01/03/2024 21:21TO-15 1,1,2-Trichloro-1,2,2-trifluoroethane µg/m3 0.561 J0.344 01/03/2024 21:21TO-15 Heptane µg/m3 0.143 J1.50 01/03/2024 21:21TO-15 n-Hexane µg/m3 0.047 JB2.25 01/03/2024 21:21TO-15 Isopropyl Alcohol µg/m3 0.139 1010 01/02/2024 18:41TO-15 Methyl Ethyl Ketone (MEK)µg/m3 4.48 2.08 01/03/2024 21:21TO-15 Methylene Chloride µg/m3 0.488 J0.387 01/03/2024 21:21TO-15 Styrene µg/m3 0.124 8.20 01/03/2024 21:21TO-15 Tetrahydrofuran µg/m3 0.107 1.89 01/03/2024 21:21TO-15 Toluene µg/m3 0.090 J1.94 01/03/2024 21:21TO-15 Trichlorofluoromethane µg/m3 0.130 J0.427 01/03/2024 21:21TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J0.334 01/03/2024 21:21TO-15 o-Xylene µg/m3 0.157 J0.790 01/03/2024 21:21TO-15 m,p-Xylene µg/m3 0.217 J1.12 01/03/2024 21:21TO-15 Xylene (Total)µg/m3 0.157 Page 5 of 22 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-362-0019 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 12/28/2023 Townes At Laso Report Date : 01/05/2024 Sample ID : Lab No : Sampled:SS-1007-33 92818 Matrix: 12/28/2023 12:45 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V41929 01/03/24 09:00 V41979 01/02/24 09:00 407 µg/m3 4.04 95.0Acetone 20 01/02/24 17:28 V42005ENM <0.073 µg/m3 0.073 1.60Benzene 1 01/03/24 19:38 V41932ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 01/03/24 19:38 V41932ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 01/03/24 19:38 V41932ENM <0.153 µg/m3 0.153 5.17Bromoform 1 01/03/24 19:38 V41932ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 01/03/24 19:38 V41932ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 01/03/24 19:38 V41932ENM 1.86 JB µg/m3 0.060 6.23Carbon Disulfide 1 01/03/24 19:38 V41932ENM 0.572 J µg/m3 0.155 3.15 Carbon Tetrachloride 1 01/03/24 19:38 V41932ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 01/03/24 19:38 V41932ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 01/03/24 19:38 V41932ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 01/03/24 19:38 V41932ENM 31.3 µg/m3 0.086 2.44Chloroform 1 01/03/24 19:38 V41932ENM <0.067 µg/m3 0.067 1.03Chloromethane 1 01/03/24 19:38 V41932ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 01/03/24 19:38 V41932ENM <0.151 µg/m3 0.151 3.84 1,2-Dibromoethane 1 01/03/24 19:38 V41932ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 01/03/24 19:38 V41932ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 01/03/24 19:38 V41932ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 01/03/24 19:38 V41932ENM 3.13 µg/m3 0.134 2.47Dichlorodifluoromethane 1 01/03/24 19:38 V41932ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 01/03/24 19:38 V41932ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 01/03/24 19:38 V41932ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 6 of 22 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-362-0019 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 12/28/2023 Townes At Laso Report Date : 01/05/2024 Sample ID : Lab No : Sampled:SS-1007-33 92818 Matrix: 12/28/2023 12:45 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V41929 01/03/24 09:00 V41979 01/02/24 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 01/03/24 19:38 V41932ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 01/03/24 19:38 V41932ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 01/03/24 19:38 V41932ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 01/03/24 19:38 V41932ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 01/03/24 19:38 V41932ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 01/03/24 19:38 V41932ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 01/03/24 19:38 V41932ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 01/03/24 19:38 V41932ENM <0.136 µg/m3 0.136 1.80 Ethyl Acetate 1 01/03/24 19:38 V41932ENM 0.894 J µg/m3 0.106 2.17Ethylbenzene 1 01/03/24 19:38 V41932ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 01/03/24 19:38 V41932ENM 0.620 J µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 01/03/24 19:38 V41932ENM <0.143 µg/m3 0.143 2.05Heptane 1 01/03/24 19:38 V41932ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 01/03/24 19:38 V41932ENM <0.047 µg/m3 0.047 1.76n-Hexane 1 01/03/24 19:38 V41932ENM <0.285 µg/m3 0.285 2.05 2-Hexanone 1 01/03/24 19:38 V41932ENM 1.09 JB µg/m3 0.139 4.92Isopropyl Alcohol 1 01/03/24 19:38 V41932ENM 1360 µg/m3 4.48 29.5Methyl Ethyl Ketone (MEK)20 01/02/24 17:28 V42005ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 01/03/24 19:38 V41932ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 01/03/24 19:38 V41932ENM 2.24 µg/m3 0.488 1.74Methylene Chloride 1 01/03/24 19:38 V41932ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 01/03/24 19:38 V41932ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 7 of 22 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-362-0019 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 12/28/2023 Townes At Laso Report Date : 01/05/2024 Sample ID : Lab No : Sampled:SS-1007-33 92818 Matrix: 12/28/2023 12:45 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V41929 01/03/24 09:00 V41979 01/02/24 09:00 <0.242 µg/m3 0.242 0.860Propene 1 01/03/24 19:38 V41932ENM <0.124 µg/m3 0.124 2.13Styrene 1 01/03/24 19:38 V41932ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 01/03/24 19:38 V41932ENM <0.181 µg/m3 0.181 3.39Tetrachloroethene 1 01/03/24 19:38 V41932ENM 8.10 µg/m3 0.107 1.47Tetrahydrofuran 1 01/03/24 19:38 V41932ENM 0.459 J µg/m3 0.090 1.88Toluene 1 01/03/24 19:38 V41932ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 01/03/24 19:38 V41932ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 01/03/24 19:38 V41932ENM <0.087 µg/m3 0.087 2.73 1,1,2-Trichloroethane 1 01/03/24 19:38 V41932ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 01/03/24 19:38 V41932ENM 1.87 J µg/m3 0.130 2.81Trichlorofluoromethane 1 01/03/24 19:38 V41932ENM <0.110 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 01/03/24 19:38 V41932ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 01/03/24 19:38 V41932ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 01/03/24 19:38 V41932ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 01/03/24 19:38 V41932ENM 1.10 J µg/m3 0.157 2.17 o-Xylene 1 01/03/24 19:38 V41932ENM 3.44 J µg/m3 0.217 5.65m,p-Xylene 1 01/03/24 19:38 V41932ENM 4.54 J µg/m3 0.157 2.17Xylene (Total)1 01/03/24 19:38 V41932 Surrogate: 4-Bromofluorobenzene 105 Limits: 70-130%01/03/24 19:381 ENM V41932 Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%01/02/24 17:2820 ENM V42005 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 8 of 22 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-362-0019 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 12/28/2023 Townes At Laso Report Date : 01/05/2024 Sample ID : Lab No : Sampled:SS-1007-DUP 92819 Matrix: 12/28/2023 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V41929 01/03/24 09:00 V41979 01/02/24 09:00 389 µg/m3 4.04 95.0Acetone 20 01/02/24 18:05 V42005ENM 0.230 J µg/m3 0.073 1.60Benzene 1 01/03/24 20:30 V41932ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 01/03/24 20:30 V41932ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 01/03/24 20:30 V41932ENM <0.153 µg/m3 0.153 5.17Bromoform 1 01/03/24 20:30 V41932ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 01/03/24 20:30 V41932ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 01/03/24 20:30 V41932ENM 1.75 JB µg/m3 0.060 6.23Carbon Disulfide 1 01/03/24 20:30 V41932ENM 0.610 J µg/m3 0.155 3.15 Carbon Tetrachloride 1 01/03/24 20:30 V41932ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 01/03/24 20:30 V41932ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 01/03/24 20:30 V41932ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 01/03/24 20:30 V41932ENM 31.3 µg/m3 0.086 2.44Chloroform 1 01/03/24 20:30 V41932ENM <0.067 µg/m3 0.067 1.03Chloromethane 1 01/03/24 20:30 V41932ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 01/03/24 20:30 V41932ENM <0.151 µg/m3 0.151 3.84 1,2-Dibromoethane 1 01/03/24 20:30 V41932ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 01/03/24 20:30 V41932ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 01/03/24 20:30 V41932ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 01/03/24 20:30 V41932ENM 3.02 µg/m3 0.134 2.47Dichlorodifluoromethane 1 01/03/24 20:30 V41932ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 01/03/24 20:30 V41932ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 01/03/24 20:30 V41932ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 9 of 22 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-362-0019 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 12/28/2023 Townes At Laso Report Date : 01/05/2024 Sample ID : Lab No : Sampled:SS-1007-DUP 92819 Matrix: 12/28/2023 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V41929 01/03/24 09:00 V41979 01/02/24 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 01/03/24 20:30 V41932ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 01/03/24 20:30 V41932ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 01/03/24 20:30 V41932ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 01/03/24 20:30 V41932ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 01/03/24 20:30 V41932ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 01/03/24 20:30 V41932ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 01/03/24 20:30 V41932ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 01/03/24 20:30 V41932ENM <0.136 µg/m3 0.136 1.80 Ethyl Acetate 1 01/03/24 20:30 V41932ENM 1.05 J µg/m3 0.106 2.17Ethylbenzene 1 01/03/24 20:30 V41932ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 01/03/24 20:30 V41932ENM 0.636 J µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 01/03/24 20:30 V41932ENM <0.143 µg/m3 0.143 2.05Heptane 1 01/03/24 20:30 V41932ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 01/03/24 20:30 V41932ENM <0.047 µg/m3 0.047 1.76n-Hexane 1 01/03/24 20:30 V41932ENM <0.285 µg/m3 0.285 2.05 2-Hexanone 1 01/03/24 20:30 V41932ENM <0.139 µg/m3 0.139 4.92Isopropyl Alcohol 1 01/03/24 20:30 V41932ENM 1300 µg/m3 4.48 29.5Methyl Ethyl Ketone (MEK)20 01/02/24 18:05 V42005ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 01/03/24 20:30 V41932ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 01/03/24 20:30 V41932ENM 2.11 µg/m3 0.488 1.74Methylene Chloride 1 01/03/24 20:30 V41932ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 01/03/24 20:30 V41932ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 10 of 22 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-362-0019 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 12/28/2023 Townes At Laso Report Date : 01/05/2024 Sample ID : Lab No : Sampled:SS-1007-DUP 92819 Matrix: 12/28/2023 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V41929 01/03/24 09:00 V41979 01/02/24 09:00 <0.242 µg/m3 0.242 0.860Propene 1 01/03/24 20:30 V41932ENM <0.124 µg/m3 0.124 2.13Styrene 1 01/03/24 20:30 V41932ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 01/03/24 20:30 V41932ENM <0.181 µg/m3 0.181 3.39Tetrachloroethene 1 01/03/24 20:30 V41932ENM 8.46 µg/m3 0.107 1.47Tetrahydrofuran 1 01/03/24 20:30 V41932ENM 0.459 J µg/m3 0.090 1.88Toluene 1 01/03/24 20:30 V41932ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 01/03/24 20:30 V41932ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 01/03/24 20:30 V41932ENM <0.087 µg/m3 0.087 2.73 1,1,2-Trichloroethane 1 01/03/24 20:30 V41932ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 01/03/24 20:30 V41932ENM 1.84 J µg/m3 0.130 2.81Trichlorofluoromethane 1 01/03/24 20:30 V41932ENM 0.353 J µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 01/03/24 20:30 V41932ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 01/03/24 20:30 V41932ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 01/03/24 20:30 V41932ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 01/03/24 20:30 V41932ENM 1.12 J µg/m3 0.157 2.17 o-Xylene 1 01/03/24 20:30 V41932ENM 3.78 J µg/m3 0.217 5.65m,p-Xylene 1 01/03/24 20:30 V41932ENM 4.90 J µg/m3 0.157 2.17Xylene (Total)1 01/03/24 20:30 V41932 Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%01/03/24 20:301 ENM V41932 Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%01/02/24 18:0520 ENM V42005 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 11 of 22 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-362-0019 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 12/28/2023 Townes At Laso Report Date : 01/05/2024 Sample ID : Lab No : Sampled:SS-1007-31 92820 Matrix: 12/28/2023 12:15 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V41929 01/03/24 09:00 V41979 01/02/24 09:00 366 µg/m3 4.04 95.0Acetone 20 01/02/24 18:41 V42005ENM 0.444 J µg/m3 0.073 1.60Benzene 1 01/03/24 21:21 V41932ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 01/03/24 21:21 V41932ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 01/03/24 21:21 V41932ENM <0.153 µg/m3 0.153 5.17Bromoform 1 01/03/24 21:21 V41932ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 01/03/24 21:21 V41932ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 01/03/24 21:21 V41932ENM 2.08 JB µg/m3 0.060 6.23Carbon Disulfide 1 01/03/24 21:21 V41932ENM <0.155 µg/m3 0.155 3.15 Carbon Tetrachloride 1 01/03/24 21:21 V41932ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 01/03/24 21:21 V41932ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 01/03/24 21:21 V41932ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 01/03/24 21:21 V41932ENM 4.95 µg/m3 0.086 2.44Chloroform 1 01/03/24 21:21 V41932ENM <0.067 µg/m3 0.067 1.03Chloromethane 1 01/03/24 21:21 V41932ENM 3.90 µg/m3 0.161 3.44Cyclohexane 1 01/03/24 21:21 V41932ENM <0.151 µg/m3 0.151 3.84 1,2-Dibromoethane 1 01/03/24 21:21 V41932ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 01/03/24 21:21 V41932ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 01/03/24 21:21 V41932ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 01/03/24 21:21 V41932ENM 3.06 µg/m3 0.134 2.47Dichlorodifluoromethane 1 01/03/24 21:21 V41932ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 01/03/24 21:21 V41932ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 01/03/24 21:21 V41932ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 12 of 22 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-362-0019 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 12/28/2023 Townes At Laso Report Date : 01/05/2024 Sample ID : Lab No : Sampled:SS-1007-31 92820 Matrix: 12/28/2023 12:15 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V41929 01/03/24 09:00 V41979 01/02/24 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 01/03/24 21:21 V41932ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 01/03/24 21:21 V41932ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 01/03/24 21:21 V41932ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 01/03/24 21:21 V41932ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 01/03/24 21:21 V41932ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 01/03/24 21:21 V41932ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 01/03/24 21:21 V41932ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 01/03/24 21:21 V41932ENM <0.136 µg/m3 0.136 1.80 Ethyl Acetate 1 01/03/24 21:21 V41932ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 01/03/24 21:21 V41932ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 01/03/24 21:21 V41932ENM 0.628 J µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 01/03/24 21:21 V41932ENM 0.344 J µg/m3 0.143 2.05Heptane 1 01/03/24 21:21 V41932ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 01/03/24 21:21 V41932ENM 1.50 J µg/m3 0.047 1.76n-Hexane 1 01/03/24 21:21 V41932ENM <0.285 µg/m3 0.285 2.05 2-Hexanone 1 01/03/24 21:21 V41932ENM 2.25 JB µg/m3 0.139 4.92Isopropyl Alcohol 1 01/03/24 21:21 V41932ENM 1010 µg/m3 4.48 29.5Methyl Ethyl Ketone (MEK)20 01/02/24 18:41 V42005ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 01/03/24 21:21 V41932ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 01/03/24 21:21 V41932ENM 2.08 µg/m3 0.488 1.74Methylene Chloride 1 01/03/24 21:21 V41932ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 01/03/24 21:21 V41932ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 13 of 22 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-362-0019 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 12/28/2023 Townes At Laso Report Date : 01/05/2024 Sample ID : Lab No : Sampled:SS-1007-31 92820 Matrix: 12/28/2023 12:15 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V41929 01/03/24 09:00 V41979 01/02/24 09:00 <0.242 µg/m3 0.242 0.860Propene 1 01/03/24 21:21 V41932ENM 0.387 J µg/m3 0.124 2.13Styrene 1 01/03/24 21:21 V41932ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 01/03/24 21:21 V41932ENM <0.181 µg/m3 0.181 3.39Tetrachloroethene 1 01/03/24 21:21 V41932ENM 8.20 µg/m3 0.107 1.47Tetrahydrofuran 1 01/03/24 21:21 V41932ENM 1.89 µg/m3 0.090 1.88Toluene 1 01/03/24 21:21 V41932ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 01/03/24 21:21 V41932ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 01/03/24 21:21 V41932ENM <0.087 µg/m3 0.087 2.73 1,1,2-Trichloroethane 1 01/03/24 21:21 V41932ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 01/03/24 21:21 V41932ENM 1.94 J µg/m3 0.130 2.81Trichlorofluoromethane 1 01/03/24 21:21 V41932ENM 0.427 J µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 01/03/24 21:21 V41932ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 01/03/24 21:21 V41932ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 01/03/24 21:21 V41932ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 01/03/24 21:21 V41932ENM 0.334 J µg/m3 0.157 2.17 o-Xylene 1 01/03/24 21:21 V41932ENM 0.790 J µg/m3 0.217 5.65m,p-Xylene 1 01/03/24 21:21 V41932ENM 1.12 J µg/m3 0.157 2.17Xylene (Total)1 01/03/24 21:21 V41932 Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%01/03/24 21:211 ENM V41932 Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%01/02/24 18:4120 ENM V42005 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 14 of 22 Quality Control Data 23-362-0019Report No: Project Description: Client ID:Hart & Hickman (Charlotte) Townes At Laso QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V41932QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V41929 Associated Lab Samples: 92818, 92819, 92820 LRB-V41929 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 01/03/24 14:081.600.073<0.073µg/m3Benzene 01/03/24 14:0810.40.147<0.147µg/m3Benzyl Chloride 01/03/24 14:083.350.150<0.150µg/m3Bromodichloromethane 01/03/24 14:085.170.153<0.153µg/m3Bromoform 01/03/24 14:081.940.115<0.115µg/m3Bromomethane 01/03/24 14:081.110.328<0.328µg/m31,3-Butadiene 01/03/24 14:086.230.0600.239µg/m3Carbon Disulfide 01/03/24 14:083.150.155<0.155µg/m3Carbon Tetrachloride 01/03/24 14:082.300.107<0.107µg/m3Chlorobenzene 01/03/24 14:084.260.208<0.208µg/m3Chlorodibromomethane 01/03/24 14:081.320.164<0.164µg/m3Chloroethane 01/03/24 14:082.440.086<0.086µg/m3Chloroform 01/03/24 14:081.030.067<0.067µg/m3Chloromethane 01/03/24 14:083.440.161<0.161µg/m3Cyclohexane 01/03/24 14:083.840.151<0.151µg/m31,2-Dibromoethane 01/03/24 14:083.010.096<0.096µg/m31,2-Dichlorobenzene 01/03/24 14:0812.00.174<0.174µg/m31,3-Dichlorobenzene 01/03/24 14:083.010.186<0.186µg/m31,4-Dichlorobenzene 01/03/24 14:082.470.134<0.134µg/m3Dichlorodifluoromethane 01/03/24 14:082.020.101<0.101µg/m31,1-Dichloroethane 01/03/24 14:082.020.129<0.129µg/m31,2-Dichloroethane 01/03/24 14:081.980.107<0.107µg/m31,1-Dichloroethene 01/03/24 14:081.980.095<0.095µg/m3cis-1,2-Dichloroethene 01/03/24 14:081.980.108<0.108µg/m3trans-1,2-Dichloroethene 01/03/24 14:082.310.205<0.205µg/m31,2-Dichloropropane 01/03/24 14:083.500.622<0.622µg/m31,2-Dichlorotetrafluoroethane 01/03/24 14:082.270.178<0.178µg/m3cis-1,3-Dichloropropene Page 1 of 6Date:01/05/2024 03:12 PM Page 15 of 22 Quality Control Data 23-362-0019Report No: Project Description: Client ID:Hart & Hickman (Charlotte) Townes At Laso QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V41932QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V41929 Associated Lab Samples: 92818, 92819, 92820 LRB-V41929 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 01/03/24 14:082.270.178<0.178µg/m3trans-1,3-Dichloropropene 01/03/24 14:081.800.435<0.435µg/m31,4-Dioxane 01/03/24 14:081.800.136<0.136µg/m3Ethyl Acetate 01/03/24 14:082.170.106<0.106µg/m3Ethylbenzene 01/03/24 14:082.460.128<0.128µg/m34-Ethyltoluene 01/03/24 14:083.830.561<0.561µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 01/03/24 14:082.050.143<0.143µg/m3Heptane 01/03/24 14:085.330.330<0.330µg/m3Hexachlorobutadiene 01/03/24 14:081.760.047<0.047µg/m3n-Hexane 01/03/24 14:082.050.285<0.285µg/m32-Hexanone 01/03/24 14:084.920.1390.575µg/m3Isopropyl Alcohol 01/03/24 14:081.800.033<0.033µg/m3Methyl tert-butyl ether (MTBE) 01/03/24 14:082.050.121<0.121µg/m34-Methyl-2-Pentanone 01/03/24 14:081.740.488<0.488µg/m3Methylene Chloride 01/03/24 14:082.620.183<0.183µg/m3Naphthalene 01/03/24 14:080.8600.242<0.242µg/m3Propene 01/03/24 14:082.130.124<0.124µg/m3Styrene 01/03/24 14:083.430.104<0.104µg/m31,1,2,2-Tetrachloroethane 01/03/24 14:083.390.181<0.181µg/m3Tetrachloroethene 01/03/24 14:081.470.107<0.107µg/m3Tetrahydrofuran 01/03/24 14:081.880.090<0.090µg/m3Toluene 01/03/24 14:083.710.209<0.209µg/m31,2,4-Trichlorobenzene 01/03/24 14:082.730.144<0.144µg/m31,1,1-Trichloroethane 01/03/24 14:082.730.087<0.087µg/m31,1,2-Trichloroethane 01/03/24 14:082.150.199<0.199µg/m3Trichloroethene 01/03/24 14:082.810.130<0.130µg/m3Trichlorofluoromethane 01/03/24 14:082.460.110<0.110µg/m31,2,4-Trimethylbenzene Page 2 of 6Date:01/05/2024 03:12 PM Page 16 of 22 Quality Control Data 23-362-0019Report No: Project Description: Client ID:Hart & Hickman (Charlotte) Townes At Laso QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V41932QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V41929 Associated Lab Samples: 92818, 92819, 92820 LRB-V41929 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 01/03/24 14:082.460.236<0.236µg/m31,3,5-Trimethylbenzene 01/03/24 14:081.760.224<0.224µg/m3Vinyl Acetate 01/03/24 14:081.280.127<0.127µg/m3Vinyl Chloride 01/03/24 14:082.170.157<0.157µg/m3o-Xylene 01/03/24 14:085.650.217<0.217µg/m3m,p-Xylene 01/03/24 14:084-Bromofluorobenzene (S)98.6 70-130 LCS-V41929Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 11217.916.0µg/m3Benzene 70-130 98.025.425.9µg/m3Benzyl Chloride 70-130 11739.233.5µg/m3Bromodichloromethane 70-130 10353.051.7µg/m3Bromoform 70-130 11221.819.4µg/m3Bromomethane 70-130 10011.111.1µg/m31,3-Butadiene 70-130 11317.615.6µg/m3Carbon Disulfide 70-130 11636.631.5µg/m3Carbon Tetrachloride 70-130 10724.623.0µg/m3Chlorobenzene 70-130 10544.942.6µg/m3Chlorodibromomethane 70-130 10513.813.2µg/m3Chloroethane 70-130 11828.824.4µg/m3Chloroform 70-130 10010.310.3µg/m3Chloromethane 70-130 10918.717.2µg/m3Cyclohexane 70-130 10640.838.4µg/m31,2-Dibromoethane 70-130 11133.430.1µg/m31,2-Dichlorobenzene 70-130 11334.030.1µg/m31,3-Dichlorobenzene 70-130 Page 3 of 6Date:01/05/2024 03:12 PM Page 17 of 22 Quality Control Data 23-362-0019Report No: Project Description: Client ID:Hart & Hickman (Charlotte) Townes At Laso QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V41932QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V41929 LCS-V41929Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 11233.830.1µg/m31,4-Dichlorobenzene 70-130 12029.624.7µg/m3Dichlorodifluoromethane 70-130 11222.620.2µg/m31,1-Dichloroethane 70-130 12625.520.2µg/m31,2-Dichloroethane 70-130 11422.619.8µg/m31,1-Dichloroethene 70-130 11622.919.8µg/m3cis-1,2-Dichloroethene 70-130 11623.019.8µg/m3trans-1,2-Dichloroethene 70-130 10724.823.1µg/m31,2-Dichloropropane 70-130 11740.935.0µg/m31,2-Dichlorotetrafluoroethane 70-130 11325.622.7µg/m3cis-1,3-Dichloropropene 70-130 11225.422.7µg/m3trans-1,3-Dichloropropene 70-130 11120.018.0µg/m31,4-Dioxane 70-130 10619.118.0µg/m3Ethyl Acetate 70-130 10522.721.7µg/m3Ethylbenzene 70-130 10826.524.6µg/m34-Ethyltoluene 70-130 11945.538.3µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 70-130 10722.020.5µg/m3Heptane 70-130 10556.253.3µg/m3Hexachlorobutadiene 70-130 10418.317.6µg/m3n-Hexane 70-130 93.619.220.5µg/m32-Hexanone 70-130 90.211.112.3µg/m3Isopropyl Alcohol 70-130 11320.318.0µg/m3Methyl tert-butyl ether (MTBE)70-130 10221.020.5µg/m34-Methyl-2-Pentanone 70-130 10318.017.4µg/m3Methylene Chloride 70-130 10928.526.2µg/m3Naphthalene 70-130 90.57.808.61µg/m3Propene 70-130 10221.721.3µg/m3Styrene 70-130 Page 4 of 6Date:01/05/2024 03:12 PM Page 18 of 22 Quality Control Data 23-362-0019Report No: Project Description: Client ID:Hart & Hickman (Charlotte) Townes At Laso QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V41932QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V41929 LCS-V41929Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10937.434.3µg/m31,1,2,2-Tetrachloroethane 70-130 11739.533.9µg/m3Tetrachloroethene 70-130 10215.014.7µg/m3Tetrahydrofuran 70-130 11421.418.8µg/m3Toluene 70-130 11040.937.1µg/m31,2,4-Trichlorobenzene 70-130 11732.027.3µg/m31,1,1-Trichloroethane 70-130 10628.927.3µg/m31,1,2-Trichloroethane 70-130 11731.626.9µg/m3Trichloroethene 70-130 12334.528.1µg/m3Trichlorofluoromethane 70-130 11327.924.6µg/m31,2,4-Trimethylbenzene 70-130 11227.624.6µg/m31,3,5-Trimethylbenzene 70-130 97.117.117.6µg/m3Vinyl Acetate 70-130 10713.712.8µg/m3Vinyl Chloride 70-130 11023.821.7µg/m3o-Xylene 70-130 10947.343.4µg/m3m,p-Xylene 70-130 1034-Bromofluorobenzene (S)70-130 Page 5 of 6Date:01/05/2024 03:12 PM Page 19 of 22 Quality Control Data 23-362-0019Report No: Project Description: Client ID:Hart & Hickman (Charlotte) Townes At Laso QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V42005QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V41979 Associated Lab Samples: 92818, 92819, 92820 LRB-V41979 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 01/02/24 13:174.750.2020.382µg/m3Acetone 01/02/24 13:171.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 01/02/24 13:174-Bromofluorobenzene (S)99.1 70-130 LCS-V41979Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10112.011.9µg/m3Acetone 70-130 10014.814.8µg/m3Methyl Ethyl Ketone (MEK)70-130 1054-Bromofluorobenzene (S)70-130 Page 6 of 6Date:01/05/2024 03:12 PM Page 20 of 22 Fed Ex UPS US Postal Client Lab Courier Other : Shipment Receipt Form Customer Number: Customer Name: Report Number:23-362-0019 Hart & Hickman (Charlotte) 01102 Shipping Method Shipping container/cooler uncompromised? Thermometer ID:NA Chain of Custody (COC) present?Yes No Yes No Not Present Yes No Not Present Yes No COC agrees with sample label(s)? Yes No COC properly completed Samples in proper containers? Sample containers intact? Sufficient sample volume for indicated test(s)? All samples received within holding time? Cooler temperature in compliance? Yes No Yes No Yes No Yes No Yes No Yes NoCooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes No Yes No N/A Yes No N/A Yes No N/ASoil VOA method 5035 – compliance criteria met Water - Sample containers properly preserved Water - VOA vials free of headspace Yes No N/A Trip Blanks received with VOAs Low concentration EnCore samplers (48 hr) High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d) High concentration container (48 hr) Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Number of coolers/boxes received Yes No 1 Signature:Angelo Norvell Date & Time:12/28/2023 16:30:48 Special precautions or instructions included? Comments: Page 21 of 22 Page 22 of 22 Appendix G PVC Primer and PVC Glue Material Safety Data Sheets SAFETY DATA SHEET 1. Identification Oatey Purple Primer- NSF Listed for PVC and CPVCProduct identifier Other means of identification 1402CSDS number Part Numbers: 30755(TV), 30756(TV), 30757(TV), 30758, 30759, 30927, 31480, 31481, 31482, 31483Synonyms Joining PVC PipesRecommended use None known.Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Company Name Oatey Co. Address 4700 West 160th St. Cleveland, OH 44135 Telephone 216-267-7100 E-mail info@oatey.com Transport Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887) Emergency First Aid 1-877-740-5015 Contact person MSDS Coordinator 2. Hazard(s) identification Category 2Flammable liquidsPhysical hazards Category 1Physical hazards not otherwise classified Category 4Acute toxicity, oralHealth hazards Category 2Skin corrosion/irritation Category 2ASerious eye damage/eye irritation Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure Category 3 narcotic effectsSpecific target organ toxicity, single exposure Category 1Aspiration hazard Category 1Health hazards not otherwise classified Not classified.Environmental hazards Label elements Signal word Danger Hazard statement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Precautionary statement Prevention Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use non-sparking tools. Take action to prevent static discharges. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Oatey Purple Primer- NSF Listed for PVC and CPVC SDS Canada 926733 Version #: 01 Revision date: - Issue date: 21-December-2015 1 / 9 Response IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Do NOT induce vomiting. Take off contaminated clothing and wash it before reuse. In case of fire: Use appropriate media to extinguish. Storage Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Other hazards Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. May form explosive peroxides. Supplemental information Not applicable. 3. Composition/information on ingredients Mixtures 67-64-1 25-40Acetone CAS number %Chemical name 108-94-1 25-40Cyclohexanone 78-93-3 15-30Methyl ethyl ketone All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Eye contact Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis. Ingestion Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Skin irritation. May cause redness and pain. Most important symptoms/effects, acute and delayed Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed. Indication of immediate medical attention and special treatment needed Take off all contaminated clothing immediately. IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. General information 5. Fire-fighting measures Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing media Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment and precautions for firefighters In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Cool containers exposed to flames with water until well after the fire is out.Specific methods Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or with age. General fire hazards Oatey Purple Primer- NSF Listed for PVC and CPVC SDS Canada 926733 Version #: 01 Revision date: - Issue date: 21-December-2015 2 / 9 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation of vapors or mists. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Use water spray to reduce vapors or divert vapor cloud drift. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. This product is miscible in water. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid discharge into drains, water courses or onto the ground.Environmental precautions 7. Handling and storage Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not taste or swallow. Avoid breathing mist or vapor. Avoid contact with skin. Avoid contact with eyes. Avoid prolonged exposure. Avoid contact with clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. When using, do not eat, drink or smoke. Wash hands thoroughly after handling. Precautions for safe handling Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in original tightly closed container. Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Keep in an area equipped with sprinklers. Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values ValueTypeComponents STEL 500 ppmAcetone (CAS 67-64-1) TWA 250 ppm STEL 50 ppmCyclohexanone (CAS 108-94-1) TWA 20 ppm STEL 300 ppmMethyl ethyl ketone (CAS 78-93-3) TWA 200 ppm Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) ValueTypeComponents STEL 1800 mg/m3Acetone (CAS 67-64-1) 750 ppm TWA 1200 mg/m3 500 ppm STEL 200 mg/m3Cyclohexanone (CAS 108-94-1) 50 ppm TWA 80 mg/m3 20 ppm Oatey Purple Primer- NSF Listed for PVC and CPVC SDS Canada 926733 Version #: 01 Revision date: - Issue date: 21-December-2015 3 / 9 Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) ValueTypeComponents STEL 885 mg/m3Methyl ethyl ketone (CAS 78-93-3) 300 ppm TWA 590 mg/m3 200 ppm Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) ValueTypeComponents STEL 500 ppmAcetone (CAS 67-64-1) TWA 250 ppm STEL 50 ppmCyclohexanone (CAS 108-94-1) TWA 20 ppm STEL 100 ppmMethyl ethyl ketone (CAS 78-93-3) TWA 50 ppm Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act) ValueTypeComponents STEL 500 ppmAcetone (CAS 67-64-1) TWA 250 ppm STEL 50 ppmCyclohexanone (CAS 108-94-1) TWA 20 ppm STEL 300 ppmMethyl ethyl ketone (CAS 78-93-3) TWA 200 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) ValueTypeComponents STEL 750 ppmAcetone (CAS 67-64-1) TWA 500 ppm STEL 50 ppmCyclohexanone (CAS 108-94-1) TWA 20 ppm STEL 300 ppmMethyl ethyl ketone (CAS 78-93-3) TWA 200 ppm Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) ValueTypeComponents STEL 2380 mg/m3Acetone (CAS 67-64-1) 1000 ppm TWA 1190 mg/m3 500 ppm TWA 100 mg/m3Cyclohexanone (CAS 108-94-1) 25 ppm STEL 300 mg/m3Methyl ethyl ketone (CAS 78-93-3) 100 ppm TWA 150 mg/m3 50 ppm Oatey Purple Primer- NSF Listed for PVC and CPVC SDS Canada 926733 Version #: 01 Revision date: - Issue date: 21-December-2015 4 / 9 Biological limit values ACGIH Biological Exposure Indices Value Sampling TimeDeterminant SpecimenComponents 25 mg/l Acetone Urine *Acetone (CAS 67-64-1) 80 mg/l 1,2-Cyclohexan ediol,with hydrolysis Urine *Cyclohexanone (CAS 108-94-1) 8 mg/l Cyclohexanol, with hydrolysis Urine * 2 mg/l MEK Urine *Methyl ethyl ketone (CAS 78-93-3) * - For sampling details, please see the source document. Exposure guidelines Canada - Alberta OELs: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Canada - British Columbia OELs: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Canada - Manitoba OELs: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Canada - Ontario OELs: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Canada - Quebec OELs: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Canada - Saskatchewan OELs: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles).Eye/face protection Skin protection Wear appropriate chemical resistant gloves.Hand protection Wear appropriate chemical resistant clothing.Other If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Liquid.Physical state Translucent liquid.Form PurpleColor Solvent.Odor Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 151 °F (66.11 °C) Oatey Purple Primer- NSF Listed for PVC and CPVC SDS Canada 926733 Version #: 01 Revision date: - Issue date: 21-December-2015 5 / 9 Flash point 14.0 - 23.0 °F (-10.0 - -5.0 °C) Evaporation rate 5.5 - 8 Not available.Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) 1.8 Flammability limit - upper (%) 11.8 Explosive limit - lower (%)Not available. Explosive limit - upper (%)Not available. Vapor pressure 145 mm Hg @ 20 C Vapor density 2.5 Relative density 0.84 +/- 0.02 @20°C Solubility(ies) Solubility (water)Negligible Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Bulk density 7 lb/gal VOC (Weight %)505 g/l SQACMD Method 24 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability No dangerous reaction known under conditions of normal use.Possibility of hazardous reactions Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Conditions to avoid Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics.Incompatible materials No hazardous decomposition products are known.Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May be fatal if swallowed and enters airways. May cause irritation to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. Eye contact Causes serious eye irritation. Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed. Symptoms related to the physical, chemical and toxicological characteristics Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation. Oatey Purple Primer- NSF Listed for PVC and CPVC SDS Canada 926733 Version #: 01 Revision date: - Issue date: 21-December-2015 6 / 9 Test ResultsComponents Species Acetone (CAS 67-64-1) LD50 Rabbit Dermal Acute 20 ml/kg LC50 Rat Inhalation 50 mg/l, 8 Hours LD50 Rat Oral 5800 mg/kg Cyclohexanone (CAS 108-94-1) LD50 Rabbit Dermal Acute 948 mg/kg LC50 Rat Inhalation 8000 ppm, 4 hours LD50 Rat Oral 800 mg/kg * Estimates for product may be based on additional component data not shown. Causes skin irritation.Skin corrosion/irritation Causes serious eye irritation.Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not available. This product is not expected to cause skin sensitization.Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation lifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and female mice developed liver tumors while neither the female rats nor the male mice showed similar results. Because the carcinogenic mechanisms could not be identified clearly in either species for either tumor, the EPA determined that the male rat and female mouse findings are relevant to the assessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that these data in aggregate indicate that there is "suggestive evidence of carcinogenic potential" following exposure to THF by all routes of exposure. ACGIH Carcinogens Acetone (CAS 67-64-1) A4 Not classifiable as a human carcinogen. Cyclohexanone (CAS 108-94-1) A3 Confirmed animal carcinogen with unknown relevance to humans. Canada - Manitoba OELs: carcinogenicity ACETONE (CAS 67-64-1) Not classifiable as a human carcinogen. CYCLOHEXANONE (CAS 108-94-1) Confirmed animal carcinogen with unknown relevance to humans. IARC Monographs. Overall Evaluation of Carcinogenicity Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans. This product is not expected to cause reproductive or developmental effects.Reproductive toxicity Specific target organ toxicity - single exposure Narcotic effects. Respiratory tract irritation. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard May be fatal if swallowed and enters airways. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Ecotoxicity Oatey Purple Primer- NSF Listed for PVC and CPVC SDS Canada 926733 Version #: 01 Revision date: - Issue date: 21-December-2015 7 / 9 Components Test ResultsSpecies Acetone (CAS 67-64-1) Aquatic LC50Fish > 100 mg/l, 96 hoursFathead minnow (Pimephales promelas) * Estimates for product may be based on additional component data not shown. Cyclohexanone (CAS 108-94-1) Aquatic LC50Fish 481 - 578 mg/l, 96 hoursFathead minnow (Pimephales promelas) No data is available on the degradability of this product.Persistence and degradability No data available.Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Acetone (CAS 67-64-1) -0.24 Cyclohexanone (CAS 108-94-1) 0.81 Methyl ethyl ketone (CAS 78-93-3) 0.29 No data available.Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations.Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information TDG UN1993UN number FLAMMABLE LIQUID, N.O.S. (Methyl ethyl ketone, Acetone)UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk IIPacking group DEnvironmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IATA UN1993UN number Flammable liquid, n.o.s. (Methyl ethyl ketone, Acetone)UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk IIPacking group No.Environmental hazards 3HERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IMDG UN1993UN number FLAMMABLE LIQUID, N.O.S. (Methyl ethyl ketone, Acetone)UN proper shipping name Oatey Purple Primer- NSF Listed for PVC and CPVC SDS Canada 926733 Version #: 01 Revision date: - Issue date: 21-December-2015 8 / 9 3Class Transport hazard class(es) -Subsidiary risk IIPacking group No.Marine pollutant Environmental hazards F-E, S-EEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not available.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product has been classified in accordance with the hazard criteria of the HPR and the SDS contains all the information required by the HPR. Canadian regulations Controlled Drugs and Substances Act Not regulated. Export Control List (CEPA 1999, Schedule 3) Not listed. Greenhouse Gases Not listed. Precursor Control Regulations Acetone (CAS 67-64-1) Class B Methyl ethyl ketone (CAS 78-93-3) Class B International regulations Stockholm Convention Not applicable. Rotterdam Convention Not applicable. Kyoto protocol Not applicable. Montreal Protocol Not applicable. Basel Convention Not applicable. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Domestic Substances List (DSL) YesCanada Non-Domestic Substances List (NDSL) NoCanada *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico 16. Other Information 21-December-2015Issue date -Revision date Version #01 Oatey Co. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. Disclaimer Oatey Purple Primer- NSF Listed for PVC and CPVC SDS Canada 926733 Version #: 01 Revision date: - Issue date: 21-December-2015 9 / 9 SAFETY DATA SHEET 1. Identification PVC Regular Clear CementProduct identifier Other means of identification 1100EProduct code Part Numbers: 31012, 31013, 31014, 31015, 31016, 31958, 31959, 31960, 31961Synonyms Joining PVC PipesRecommended use None known.Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Company Name Oatey Co. Address 4700 West 160th St. Cleveland, OH 44135 Telephone 216-267-7100 E-mail info@oatey.com Transport Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887) Emergency First Aid 1-877-740-5015 Contact person MSDS Coordinator 2. Hazard(s) identification Category 2Flammable liquidsPhysical hazards Category 4Acute toxicity, oralHealth hazards Category 2Skin corrosion/irritation Category 2ASerious eye damage/eye irritation Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure Category 3 narcotic effectsSpecific target organ toxicity, single exposure Category 1Aspiration hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Response If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use appropriate media to extinguish. SDS USPVC Regular Clear Cement 927170 Version #: 01 Revision date: 11-22-2017 Issue date: 05-27-2015 1 / 10 Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected possible carcinogen. Supplemental information Not applicable. 3. Composition/information on ingredients Mixtures 78-93-3 25-40Methyl ethyl ketone CAS number %Chemical name 108-94-1 10-25Cyclohexanone 109-99-9 10-25Furan, Tetrahydro- 67-64-1 5-15Acetone 9002-86-2 5-15Polyvinyl chloride *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.Inhalation Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.Eye contact Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis. Ingestion Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Skin irritation. May cause redness and pain. Most important symptoms/effects, acute and delayed Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed. Indication of immediate medical attention and special treatment needed Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. General information 5. Fire-fighting measures Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing media Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment and precautions for firefighters In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or with age.General fire hazards SDS USPVC Regular Clear Cement 927170 Version #: 01 Revision date: 11-22-2017 Issue date: 05-27-2015 2 / 10 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid discharge into drains, water courses or onto the ground.Environmental precautions 7. Handling and storage Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof general and local exhaust ventilation. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Precautions for safe handling Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) ValueTypeComponents STEL 5 ppmPolyvinyl chloride (CAS 9002-86-2) TWA 1 ppm US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueType FormComponents PEL 2400 mg/m3Acetone (CAS 67-64-1) 1000 ppm PEL 200 mg/m3Cyclohexanone (CAS 108-94-1) 50 ppm PEL 590 mg/m3Furan, Tetrahydro- (CAS 109-99-9) 200 ppm PEL 590 mg/m3Methyl ethyl ketone (CAS 78-93-3) 200 ppm PEL 5 mg/m3 Respirable fraction.Polyvinyl chloride (CAS 9002-86-2) 15 mg/m3 Total dust. PVC Regular Clear Cement SDS US 927170 Version #: 01 Revision date: 11-22-2017 Issue date: 05-27-2015 3 / 10 US. ACGIH Threshold Limit Values ValueType FormComponents STEL 750 ppmAcetone (CAS 67-64-1) TWA 500 ppm STEL 50 ppmCyclohexanone (CAS 108-94-1) TWA 20 ppm STEL 100 ppmFuran, Tetrahydro- (CAS 109-99-9) TWA 50 ppm STEL 300 ppmMethyl ethyl ketone (CAS 78-93-3) TWA 200 ppm TWA 1 mg/m3 Respirable fraction.Polyvinyl chloride (CAS 9002-86-2) US. NIOSH: Pocket Guide to Chemical Hazards ValueTypeComponents TWA 590 mg/m3Acetone (CAS 67-64-1) 250 ppm TWA 100 mg/m3Cyclohexanone (CAS 108-94-1) 25 ppm STEL 735 mg/m3Furan, Tetrahydro- (CAS 109-99-9) 250 ppm TWA 590 mg/m3 200 ppm STEL 885 mg/m3Methyl ethyl ketone (CAS 78-93-3) 300 ppm TWA 590 mg/m3 200 ppm Biological limit values ACGIH Biological Exposure Indices Value Sampling TimeDeterminant SpecimenComponents 50 mg/l Acetone Urine *Acetone (CAS 67-64-1) 80 mg/l 1,2-Cyclohexanediol,with hydrolysis Urine *Cyclohexanone (CAS 108-94-1) 8 mg/l Cyclohexanol, with hydrolysis Urine * 2 mg/l Tetrahydrofura n Urine *Furan, Tetrahydro- (CAS 109-99-9) 2 mg/l MEK Urine *Methyl ethyl ketone (CAS 78-93-3) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Cyclohexanone (CAS 108-94-1)Skin designation applies. US - Tennessee OELs: Skin designation Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin. Furan, Tetrahydro- (CAS 109-99-9)Can be absorbed through the skin. US. NIOSH: Pocket Guide to Chemical Hazards Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin. SDS USPVC Regular Clear Cement 927170 Version #: 01 Revision date: 11-22-2017 Issue date: 05-27-2015 4 / 10 Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Appropriate engineering controls Individual protection measures, such as personal protective equipment Face shield is recommended. Wear safety glasses with side shields (or goggles).Eye/face protection Skin protection Wear appropriate chemical resistant gloves.Hand protection Wear appropriate chemical resistant clothing.Other If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Liquid.Physical state Translucent liquid.Form Clear.Color Solvent.Odor Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 151 °F (66.11 °C) Flash point -4.0 °F (-20.0 °C) Evaporation rate 5.5 - 8 Not available.Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) 1.8 Flammability limit - upper (%) 11.8 Explosive limit - lower (%)Not available. Explosive limit - upper (%)Not available. Vapor pressure 145 mm Hg @ 20 C Vapor density 2.5 Relative density 0.9 +/- 0.02 Solubility(ies) Solubility (water)Negligible Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity 80 - 500 cP Other information VOC (Weight %)<510 g/l SCAQMD 1168/M316A 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity SDS USPVC Regular Clear Cement 927170 Version #: 01 Revision date: 11-22-2017 Issue date: 05-27-2015 5 / 10 Material is stable under normal conditions.Chemical stability No dangerous reaction known under conditions of normal use.Possibility of hazardous reactions Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials.Conditions to avoid Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics.Incompatible materials No hazardous decomposition products are known.Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritation to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. Eye contact Causes serious eye irritation. Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed. Harmful if swallowed. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Symptoms related to the physical, chemical and toxicological characteristics Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation. Test ResultsComponentsSpecies Acetone (CAS 67-64-1) LD50 Rabbit Dermal Acute 20 ml/kg LC50 Rat Inhalation 50 mg/l, 8 Hours LD50 Rat Oral 5800 mg/kg Cyclohexanone (CAS 108-94-1) LD50 Rabbit Dermal Acute 948 mg/kg LC50 Rat Inhalation 8000 ppm, 4 hours LD50 Rat Oral 1540 mg/kg * Estimates for product may be based on additional component data not shown. Causes skin irritation.Skin corrosion/irritation Causes serious eye irritation.Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not available. This product is not expected to cause skin sensitization.Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.Germ cell mutagenicity SDS USPVC Regular Clear Cement 927170 Version #: 01 Revision date: 11-22-2017 Issue date: 05-27-2015 6 / 10 Carcinogenicity In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation lifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and female mice developed liver tumors while neither the female rats nor the male mice showed similar results. Because the carcinogenic mechanisms could not be identified clearly in either species for either tumor, the EPA determined that the male rat and female mouse findings are relevant to the assessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that these data in aggregate indicate that there is "suggestive evidence of carcinogenic potential" following exposure to THF by all routes of exposure. IARC Monographs. Overall Evaluation of Carcinogenicity Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans. Polyvinyl chloride (CAS 9002-86-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Polyvinyl chloride (CAS 9002-86-2) Cancer This product is not expected to cause reproductive or developmental effects.Reproductive toxicity Specific target organ toxicity - single exposure Narcotic effects. May cause drowsiness and dizziness. Respiratory tract irritation. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard May be fatal if swallowed and enters airways. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Ecotoxicity Components Test ResultsSpecies Acetone (CAS 67-64-1) Aquatic LC50Fish > 100 mg/l, 96 hoursFathead minnow (Pimephales promelas) * Estimates for product may be based on additional component data not shown. Cyclohexanone (CAS 108-94-1) Aquatic LC50Fish 481 - 578 mg/l, 96 hoursFathead minnow (Pimephales promelas) No data is available on the degradability of this product.Persistence and degradability No data available.Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Acetone (CAS 67-64-1)-0.24 Cyclohexanone (CAS 108-94-1)0.81 Furan, Tetrahydro- (CAS 109-99-9)0.46 Methyl ethyl ketone (CAS 78-93-3)0.29 No data available.Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations.Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Contaminated packaging SDS USPVC Regular Clear Cement 927170 Version #: 01 Revision date: 11-22-2017 Issue date: 05-27-2015 7 / 10 14. Transport information DOT UN1133UN number AdhesivesUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIPacking group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user T11, TP1, TP8, TP27Special provisions Packaging exceptions Packaging non bulk 150 201 243Packaging bulk IATA UN1133UN number AdhesivesUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk IIPacking group No.Environmental hazards 3LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IMDG UN number UN1133 ADHESIVESUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk IIPacking group Environmental hazards Marine pollutant No. EmS F-E, S-D Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Not available.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Polyvinyl chloride (CAS 9002-86-2)Cancer Central nervous system Liver Blood Flammability CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1)LISTED Cyclohexanone (CAS 108-94-1)LISTED Furan, Tetrahydro- (CAS 109-99-9)LISTED Methyl ethyl ketone (CAS 78-93-3)LISTED SDS USPVC Regular Clear Cement 927170 Version #: 01 Revision date: 11-22-2017 Issue date: 05-27-2015 8 / 10 Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. NoSARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1)6532 Methyl ethyl ketone (CAS 78-93-3)6714 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1)35 %WV Methyl ethyl ketone (CAS 78-93-3)35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1)6532 Methyl ethyl ketone (CAS 78-93-3)6714 US state regulations US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) Polyvinyl chloride (CAS 9002-86-2) US. Pennsylvania Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. Rhode Island RTK Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Domestic Substances List (DSL)YesCanada SDS USPVC Regular Clear Cement 927170 Version #: 01 Revision date: 11-22-2017 Issue date: 05-27-2015 9 / 10 Country(s) or region Inventory name On inventory (yes/no)* *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory NoUnited States & Puerto Rico 16. Other information, including date of preparation or last revision 05-27-2015Issue date -Revision date Version #01 Health: 2 Flammability: 3 Physical hazard: 0 HMIS® ratings NFPA ratings 02 3 The information in the sheet was written based on the best knowledge and experience currently available. Oatey Co. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. Disclaimer SDS USPVC Regular Clear Cement 927170 Version #: 01 Revision date: 11-22-2017 Issue date: 05-27-2015 10 / 10 Appendix H DEQ Risk Calculator Summary Pages Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Building 1007 Worst Case Residential Scenario North Carolina Department of Environmental Quality Risk Calculator Townes at LoSo 4920 Old Pineville Road DWM Brownfields 23067-19-060 July 2023 May 2023 EPA RSL Table Prepared By:Hart & Hickman, PC Hart & Hickman, PC North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: 23067-19-060 Exposure Unit ID: Building 1007 Worst Case Residential Scenario Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: 23067-19-060 Exposure Unit ID: Building 1007 Worst Case Residential Scenario Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: 23067-19-060 Exposure Unit ID: Building 1007 Worst Case Residential Scenario Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 407 SS-1007-33 67-64-1 Acetone ug/m3 0.444 SS-1007-31 71-43-2 Benzene ug/m3 2.08 SS-1007-31 75-15-0 Carbon Disulfide ug/m3 0.61 SS-1007-DUP 56-23-5 Carbon Tetrachloride ug/m3 31.3 SS-1007-33 / SS-1007-DUP 67-66-3 Chloroform ug/m3 3.9 SS-1007-31 110-82-7 Cyclohexane ug/m3 3.13 SS-1007-33 75-71-8 Dichlorodifluoromethane ug/m3 1.05 SS-1007-DUP 100-41-4 Ethylbenzene ug/m3 8.46 SS-1007-DUP 109-99-9 ~Tetrahydrofuran ug/m3 0.344 SS-1007-31 142-82-5 Heptane, N-ug/m3 1.5 SS-1007-31 110-54-3 Hexane, N-ug/m3 2.25 SS-1007-31 67-63-0 Isopropanol ug/m3 1360 SS-1007-33 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 2.24 SS-1007-33 75-09-2 Methylene Chloride ug/m3 0.387 SS-1007-31 100-42-5 Styrene ug/m3 1.89 SS-1007-31 108-88-3 Toluene ug/m3 0.636 SS-1007-DUP 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 1.94 SS-1007-31 75-69-4 Trichlorofluoromethane ug/m3 0.427 SS-1007-31 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 3.78 SS-1007-DUP 108-38-3 Xylene, m-ug/m3 1.12 SS-1007-DUP 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: 23067-19-060 Exposure Unit ID: Building 1007 Worst Case Residential Scenario CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 407 12.21 -- 71-43-2 Benzene 0.444 0.01332 3.6E-01 6.3E+00 3.7E-08 4.3E-04 75-15-0 Carbon Disulfide 2.08 0.0624 -1.5E+02 8.5E-0556-23-5 Carbon Tetrachloride 0.61 0.0183 4.7E-01 2.1E+01 3.9E-08 1.8E-0467-66-3 Chloroform 31.3 0.939 1.2E-01 2.0E+01 7.7E-06 9.2E-03110-82-7 Cyclohexane 3.9 0.117 -1.3E+03 1.9E-05 75-71-8 Dichlorodifluoromethane 3.13 0.0939 -2.1E+01 9.0E-04 100-41-4 Ethylbenzene 1.05 0.0315 1.1E+00 2.1E+02 2.8E-08 3.0E-05 109-99-9 ~Tetrahydrofuran 8.46 0.2538 -4.2E+02 1.2E-04 142-82-5 Heptane, N-0.344 0.01032 -8.3E+01 2.5E-05 110-54-3 Hexane, N-1.5 0.045 -1.5E+02 6.2E-0567-63-0 Isopropanol 2.25 0.0675 -4.2E+01 3.2E-0478-93-3 Methyl Ethyl Ketone (2-Butanone)1360 40.8 -1.0E+03 7.8E-0375-09-2 Methylene Chloride 2.24 0.0672 1.0E+02 1.3E+02 6.6E-10 1.1E-04 100-42-5 Styrene 0.387 0.01161 -2.1E+02 1.1E-05 108-88-3 Toluene 1.89 0.0567 -1.0E+03 1.1E-05 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-0.636 0.01908 -1.0E+03 3.7E-06 75-69-4 Trichlorofluoromethane 1.94 0.0582 -- 95-63-6 Trimethylbenzene, 1,2,4-0.427 0.01281 -1.3E+01 2.0E-04 108-38-3 Xylene, m-3.78 0.1134 -2.1E+01 1.1E-0395-47-6 Xylene, o-1.12 0.0336 -2.1E+01 3.2E-04 Cumulative:7.8E-06 2.1E-02 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: 23067-19-060 Exposure Unit ID: Building 1007 Worst Case Residential Scenario Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 7.8E-06 2.1E-02 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: 3. NM = Not modeled, user did not check this pathway as complete. 4. NC = Pathway not calculated, required contaminant migration parameters were not entered. DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? North Carolina DEQ Risk Calculator