FA-29152_48332_CA_MRP_20231208

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
December 11, 2023

Mr. Ken Currie
NCDEQ-UST Section
Fayetteville Regional Office
Systel Building
225 Green Street, Suite 714
Fayetteville, NC 28301-5043

Re: Ground Water Monitoring Report
November 2023
Breeden’s 66
22900 Aberdeen Road
Laurinburg, Scotland County
North Carolina
Facility ID Number: 00-0-0000000347
Incident Number: 48332
GRI Project Number: 5991

Dear Mr. Currie,

Please find attached the referenced report for the abovementioned site.
If you have any questions, please contact William Regenthal at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Quality Oil & Gas Company., file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127

Ground Water Monitoring Report
November 2023
Breeden’s 66
22900 Aberdeen Road
Laurinburg, Scotland County
North Carolina
Facility ID Number: 00-0-000000347
Incident Number: 48332
GRI Project Number: 5991

Prepared for:

Quality Oil & Gas Company
203 West Broad Avenue
Rockingham, North Carolina 28379

December 8, 2023

William Regenthal, P. G.
Project Manager
Asher Knobel
Report Writer

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: December 8, 2023 Breeden’s 66
Project Manager: William Regenthal, P. G. GRI Project No. 5991
i
SITE INFORMATION
1. Site Identification
 Breeden’s 66 (Facility ID 00-0-000000347)
 Incident Number 48332 – High Risk (H190A)
 Location of Source Area: 22900 Aberdeen Road
Laurinburg, NC 27824
Scotland County
34.865101°N, 79.455527°W (Topographical Map)
2. Information about Contacts Associated with the Leaking UST System

UST Owner
Quality Oil & Gas
203 West Broad Avenue
Rockingham, NC, 28379
[e-mail]
Phone: [phone]

UST Operator
Quality Oil & Gas
203 West Broad Avenue
Rockingham, NC, 28379
[e-mail]
Phone: [phone]

Property Owner
S&H Rental, Inc.
Post Office Box 2048
Raeford, NC 28376
Email: Unknown
Phone: Unknown

Property Occupant
Breeden’s 66
22900 Aberdeen Road
Laurinburg, NC 28352
E-mail: Unknown
Phone: [phone]
Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-845-4010

Analytical Laboratory
SGS- North America, Inc.
4405 Vineland Road, Suite C-15
Orlando, FL 32811
State Certification No. 573
407-425-6700
3. Information about Release
 Release was discovered on March 18, 2022
 An unknown amount of product was released from the UST System via the damaged/defective
UST spill buckets associated with the 1,000-gallon diesel and 1,500-gallon plus gasoline USTs and
the leaking off-road diesel dispenser.
 One 4,000-gallon regular gasoline, one 1,500-gallon plus gasoline, one 1,000-gallon premium
gasoline and two 1,000-gallon diesel USTs are in use at the site (Tables 1 and 2).

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: December 8, 2023 Breeden’s 66
Project Manager: William Regenthal, P. G. GRI Project No. 5991
ii
EXECUTIVE SUMMARY
Breeden’s 66 is located at 22900 Aberdeen Road in Laurinburg, Scotland County, North Carolina. The site
is currently owned and operated by S&H Rental, Inc. as a petroleum retail facility and convenience store.
One 4,000-gallon regular gasoline, one 1,500-gallon plus gasoline, one 1,000-gallon premium gasoline and
two 1,000-gallon diesel USTs are currently in use at the site with one associated dispenser island. On
November 30, 2021, during routine compliance inspection activities, two damaged/defective UST spill
buckets associated with the 1,000-gallon diesel and 1,500-gallon plus gasoline USTs, as well as a suspected
release beneath the off-road diesel dispenser were reported at the site. The adjoining properties are
agricultural and residential. According to the information determined during receptor survey activities
conducted on April 13, 2022, five potable water supply wells were identified within 1,500 feet of the site.
Of the identified water supply wells, two of the wells were located within a 1,000-foot radius of the site,
and one of the wells was located within a 250-foot radius of the site. Municipal water is available to the
site and some of surrounding properties. Water lines run along Aberdeen Road and Monroe Road.

A CSA was completed in January 2023. A CAP has not been developed for this incident.

On November 13, 2023, eight Type II monitoring wells (MW-1 through MW-8) and one Type III monitoring
well (TW-1) were gauged, purged and/or sampled in accordance with NCDEQ guidelines. A free product
thickness of 0.01 feet was measured in MW-3 during the November 2023 sampling and gauging event.
Concentrations of benzene, ethylbenzene, xylenes, MTBE, naphthalene, tert-amyl alcohol, tert-amyl
methyl ether, tert-butyl alcohol, hexachlorobutadiene, and/or n-propylbenzene that exceeded the MACs
were reported in the ground water samples collected from MW-1, MW-4, MW-7 and TW-1.

Based on the above information, the site risk classification should remain high. A free product evaluation
should be completed on MW-3 to determine the best means of free product recovery for the site. Once
free product is no longer present, a contaminant Fate and Transport Model will be completed once
sufficient data are obtained for plume stability. The purpose of the model is to determine the risk posed
to WSW-2. If the model shows that WSW-2 is not an at risk receptor, then the risk classification should
be reevaluated. In the interim, quarterly ground water sampling activities and free product recovery
should continue at the site. The next sampling event is tentatively scheduled for February 2024.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: December 8, 2023 Breeden’s 66
Project Manager: William Regenthal, P. G. GRI Project No. 5991
iii
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
HERR: HAZMAT Emergency Response and
Remediation, Inc.
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: December 8, 2023 Breeden’s 66
Project Manager: William Regenthal, P. G. GRI Project No. 5991
1
TABLE OF CONTENTS
SITE INFORMATION ............................................................................................................................ i
EXECUTIVE SUMMARY ....................................................................................................................... ii
ACRONYMS ....................................................................................................................................... iii
1.0 SITE HISTORY AND CHARACTERIZATION ...................................................................................1
2.0 PRESENTATION OF CURRENT SITE ASSESSMENT INFORMATION/ COMPARISON TO HISTORICAL
ASSESSMENT INFORMATION ...................................................................................................2
3.0 FREE PRODUCT REMOVAL ........................................................................................................3
4.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS ..................................3
5.0 CONCLUSIONS .........................................................................................................................4
6.0 LIMITATIONS ...........................................................................................................................4
7.0 STATEMENTS AND CERTIFICATION ...........................................................................................4

FIGURES
Figure 1: Site Location Map
Figure 2: Site Vicinity Map
Figure 3: Site Map
Figure 4: Water Table Surface Map
Figure 5: Ground Water Quality Map
Figure 6: Benzene Isoconcentration Map

TABLES
Table 1: UST Owner/Operator Information
Table 2: UST System Information
Table 3: Water Supply Well Information
Table 4: Adjacent Property Owner Information
Table 5: Well Construction and Gauging Information
Table 6: Summary of Ground Water Sample Analytical Results
Table 6A: Summary of Natural Attenuation Parameter Results

APPENDICES
Appendix A: State Correspondence
Appendix B: Laboratory Reports – Ground Water Samples
Appendix C: CSA Cross Section Maps

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: December 8, 2023 Breeden’s 66
Project Manager: William Regenthal, P. G. GRI Project No. 5991
1
1.0 SITE HISTORY AND CHARACTERIZATION
GRI presents the results of the November 2023 ground water sampling event at the Breeden’s 66 site;
located at 22900 Aberdeen Road in Laurinburg, Scotland County, North Carolina (Figure 1). These
activities were conducted in accordance with GRI Proposal No. 23-713, which was submitted to NCDEQ
on October 31, 2023, and was approved as Task Authorization No. 48332-5 on November 3, 2023. State
correspondence has been included as Appendix A.

The site is currently owned and operated by S&H Rental, Inc. as a petroleum retail facility. One 4,000-
gallon regular gasoline, one 1,500-gallon plus gasoline, one 1,000-gallon premium gasoline and two 1,000-
gallon diesel USTs are currently in use at the site with one associated dispenser island. UST
owner/operator information and UST system information are included as Tables 1 and 2, respectively.
The Registered Tank Report is shown below:

The site and surrounding area are a mixture of agricultural and residential properties. The site contains
one building and is primarily capped with concrete. Eight Type II monitoring wells (MW-1 through MW-
8) and one Type III monitoring well (TW-1) were installed at the site during previous ground water
assessment and corrective action activities.

In April 2022, GRI personnel conducted a receptor survey at the site. Five water supply wells were
identified within a 1,500-foot radius of the site. Seven potable water supply wells were identified within
a 1,000-foot radius of the site. Of the identified water supply wells, two (WSW-1 and WSW-2) were
located within a 1,000-foot radius of the site, and one (WSW-1) was located within a 250-foot radius of
the site. No surface water bodies were identified within a 500-foot radius of the site. Municipal water is
available to the site and some of the surrounding properties. Well abandonment agreements were mailed
to the owners of WSW-1 and WSW-2. On August 17, 2023, GRI abandoned WSW-1. The owner of WSW-
2 has decided not to abandon their water supply well at this time. Water supply well owner information
is included as Table 3. Adjacent property owner information is presented in Table 4. A Site Vicinity Map

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: December 8, 2023 Breeden’s 66
Project Manager: William Regenthal, P. G. GRI Project No. 5991
2
showing the adjacent properties has been included as Figure 2. A Site Map showing the locations of the
monitoring wells and the structures on-site has been included as Figure 3.

A CSA was completed in January 2023. To date, a CAP has not been developed for this incident.
2.0 PRESENTATION OF CURRENT SITE ASSESSMENT INFORMATION/ COMPARISON TO HISTORICAL
ASSESSMENT INFORMATION
On November 13, 2023, eight Type II monitoring wells (MW-1 through MW-8) and one Type III monitoring
well (TW-1) were gauged, purged and/or sampled in accordance with NCDEQ guidelines. A free product
thickness of 0.01 feet was observed in MW-3 during the November 2023 gauging event. Depths to ground
water in the Type II monitoring wells ranged from 17.44 feet to 19.96 feet below TOC. Well construction
and gauging information is presented in Table 5. Ground water elevations in the Type II monitoring wells
relative to a temporary benchmark with an assumed datum of 100.00 feet ranged from 79.74 to 81.03
feet. Based on this information, ground water flow direction was generally toward the northeast. The
average horizontal hydraulic gradient across the site was approximately 0.01 feet per foot. The vertical
hydraulic gradient between paired wells MW-1/TW-1 was approximately 0.07 feet per foot downward. A
Water Table Surface Map is included as Figure 4. A summary of the current ground water gauging data is
shown below:

Well ID
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(feet)
Free
Product
Thickness
(ft.)
Ground
Water
Elevation
(ft.)
MW-1 10 - 25 25 100.00 19.03 --- 80.97
MW-2 10 - 25 25 100.98 19.96 --- 81.02
MW-3 10 - 25 25 99.50 18.70 0.01 80.81
MW-4 10 - 25 25 100.50 19.47 --- 81.03
MW-5 10 - 25 25 99.13 19.39 --- 79.74
MW-6 10 - 25 25 98.41 17.76 --- 80.65
MW-7 10 - 25 25 98.08 17.44 --- 80.64
MW-8 10 - 25 25 99.98 19.08 --- 80.90
TW-1 50 - 55 55 99.81 21.10 --- 78.71

Collected ground water samples were submitted for laboratory analyses of VOCs using EPA Method 6200B
and natural attenuation parameters (nitrate, ferrous iron, sulfate and methane). Field parameters
(dissolved oxygen, oxidation reduction potential, temperature, pH and conductivity) were measured upon
sample collection. Concentrations of benzene, ethylbenzene, xylenes, MTBE, naphthalene, tert-amyl
alcohol, tert-amyl methyl ether, tert-butyl alcohol, hexachlorobutadiene, and/or n-propylbenzene that
exceeded the MACs were reported in the ground water samples collected from MW-1, MW-4, MW-7 and
TW-1. A summary of the analytical results for ground water samples collected on November 13, 2023, is
presented in Table 6. A Ground Water Quality Map based on the November 2023 data is included as
Figure 5. Contaminant specific isoconcentration maps for benzene is included as Figure 6. A complete
report of laboratory analyses of the ground water samples collected from the monitoring wells during the

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: December 8, 2023 Breeden’s 66
Project Manager: William Regenthal, P. G. GRI Project No. 5991
3
August 2023 sampling event has been included as Appendix B. A summary of the current ground water
analytical data is shown below:

Contaminant
of Concern  Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Well
ID
MACs (µg/l) 1 600 600 500 20 6
GCL (µg/l) 5,000 260,000 80,000 50,000 20,000 6,000
MW-1 1,010 188 734 711 1,610 123
MW-2 <0.13 <0.13 <0.13 <0.25 0.16 J <0.13
MW-3 FP FP FP FP FP FP
MW-4 <0.13 0.39 J 0.34 J 1.14 J 45.9 0.55
MW-5 0.14 J <0.13 <0.13 0.34 J 0.53 0.16 J
MW-6 0.16 J <0.13 <0.13 0.46 J 5.8 0.13 J
MW-7 27.0 1.7 2.5 31.2 47.4 8.7
MW-8 <0.13 <0.13 <0.13 <0.25 <0.13 0.23 J
TW-1 0.43 J 1.8 1.8 14.2 0.38 J 21.9

The baseline contaminant mass at the site was determined based on the total BTEX, MTBE, and
naphthalene concentrations from the January 10, 2023, ground water sampling event, as well as the
maximum historical water column height observed in each area. The contaminant plume consists of one
area (Area 1) based on total BTEX, MTBE, and naphthalene concentrations during the January 2023 ground
water sampling event. Contaminant mass calculations were not completed during this sampling event
due to the presence of free product in MW-3.

The site is in the Coastal Plain Physiographic Region of North Carolina. The water table has a seasonal
high depth to water of approximately 14 to 19 feet BGS. Since a CAP has not been developed for the site,
remediation milestones have not been established. Cross section maps completed during the CSA phase
of site investigation have been included as Appendix C.
3.0 FREE PRODUCT REMOVAL
Free product thickness of 0.01 feet was observed in MW-3 during this sampling event.
4.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS
No natural attenuation monitoring plan is currently in place at the site. During the November 2023
sampling event, ground water samples collected from MW-1, MW-2, MW-4 through MW-8 and TW-1
were submitted for laboratory analyses of natural attenuation parameters. Field parameters were
measured upon sample collection. A summary of natural attenuation analytical results is presented in
Table 6A. Since contaminant concentrations have increased since the baseline sampling event in January
2023 and free product was observed in MW-3, the Contaminant Fate and Transport model proposed for
the November 2023 sampling event has been postponed. The model will be completed once free product
is eliminated and the contaminant plume appears to stabilize during a subsequent quarterly ground water
monitoring event.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: December 8, 2023 Breeden’s 66
Project Manager: William Regenthal, P. G. GRI Project No. 5991
4
5.0 CONCLUSIONS
 On November 13, 2023, eight Type II monitoring wells and one Type III monitoring well were
gauged, purged and/or sampled. Ground water flow direction is generally toward the northeast.
The horizontal hydraulic gradient across the site was approximately 0.01 feet per foot. The
average vertical gradient between paired wells MW-1 and TW-1 was approximately 0.07 feet per
foot downward.
 Free product was observed in MW-3 at a thickness of 0.01 ft.
 Concentrations of benzene, ethylbenzene, xylenes, MTBE, naphthalene, tert-amyl alcohol, tert-
amyl methyl ether, tert-butyl alcohol, hexachlorobutadiene, and/or n-propylbenzene that
exceeded the MACs were reported in the ground water samples collected from MW-1, MW-4,
MW-7, and TW-1.
 Based on the above information, the site risk classification should remain high. A free product
evaluation should be completed on MW-3 to determine the best means of free product recovery
for the site. Once free product is no longer present, a contaminant Fate and Transport Model will
be completed once sufficient data are obtained for plume stability. The purpose of the model is
to determine the risk posed to WSW-2. If the model shows that WSW-2 is not an at risk receptor,
then the risk classification should be reevaluated. In the interim, quarterly ground water sampling
activities and free product recovery should continue at the site. The next sampling event is
tentatively scheduled for February 2024.
6.0 LIMITATIONS
This report has been prepared for the exclusive use of Quality Oil and Gas for specific application to the
referenced site in Scotland County, North Carolina. The assessment was conducted based on the scope
of work and level of effort desired by NCDEQ and with resources adequate only for that scope of work.
Our findings have been developed in accordance with generally accepted standards of environmental
practices in the State of North Carolina, available information, and our professional judgment. No other
warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.
7.0 STATEMENTS AND CERTIFICATION
1 Enter the date the monitoring report was due. N/A Will this report be submitted after the
established due date?
YES NO
2 Was any required information from the above template missing from this report? YES NO
IF the answer to question #1 or# 2 is “YES”, please provide additional information in this cell to explain
what was missing and why.

FIGURES
SITE LOCATIONFigure 1 Site LocationBreeden’s 6622900 Aberdeen RoadLaurinburg, North CarolinaScotland CountyIncident No. 48332GRI Project No. 5991500 M2000 FTDate: 07/20/2022Location: 34.865101° N -79.455527° W Dad
"J
"J
"J
"J
"J
SITE
020316 01001
020314 01024
020322 01033
020314 01033
020314 01034
020314 01036020314 01037020314 0103401
WSW-5
WSW-4
WSW-3
WSW-2
WSW-1
Sources: Esri, HERE, Garmin, USGS, Intermap, INCREMENT P, NRCan, Esri Japan, METI, Esri China (Hong Kong), Esri Korea, Esri (Thailand), NGCC, ©OpenStreetMap contributors, and the GIS User Community
³
0 300150Feet
1 inch = 300 feet
FIGURE 2: SITE VICINITY MAPBREEDEN'S 6622900 ABERDEEN ROADLAURINBURG, SCOTLAND COUNTYNORTH CAROLINAINCIDENT NO. 48332GRI NO. 5991
PREPARED BY:GEOLOGICAL RESOURCES, INC.APRIL 8, 20221,500-FOOT RADIUS
1,000-FOOT RADIUS
250-FOOT RADIUS
500-FOOT RADIUS
LEGEND
"J Water Supply Well
ncrivers
Well Owners and Adjacent Properties
nc_scotland_parcels_poly

TABLES
UST ID Number 1-5 Facility ID Number
Owner or Operator?
Owner
TABLE 1
UST OWNER/OPERATOR INFORMATION
BREEDEN'S 66 (INCIDENT NO. 48332)
00-0-000000347
Address Telephone Number
203 West Broad Avenue, Rockingham, NC 28379 910-997-3101
Name of Owner or Operator Dates of Ownership / Operation
4/4/1968 - CurrentQuality Oil Company
Page 1 of 1
Date: 04/28/2022 Facility ID #: 00-0-000000347
Was Release
Associated
with UST
System?
(Yes / No)
5 Off-Road
Diesel 1,000 4/4/1968 Single Wall Steel 46" x 12'Single Wall FRP Current Yes
4 Diesel 1,000 4/4/1968 Single Wall Steel 46" x 12'Single Wall FRP Current No
3 Gasoline 1,500 4/4/1968 Single Wall Steel 64" x 9'Single Wall FRP Current No
2 Gasoline 1,000 4/4/1968 Single Wall Steel 46" x 12'Single Wall FRP Current No
1 Gasoline 4,000 4/4/1968 Single Wall Steel 64" x 24'Single Wall FRP Current No
UST
ID
No.
TABLE 2
UST SYSTEM INFORMATION
BREEDEN'S 66 (INCIDENT NO. 48332)
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
Current
or Most
Recent
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Page 1 of 1
Well ID.Parcel ID No.Well Owner Mailing Address Well Address Well Status
(Active/In-Active)
Well Use
(Potable / Non-
Potable
etc.)
Municpal
Water
Available
Yes/No
Connected
to
Municipal
Water
Yes/No
Distance
from source
area of
release
(ft.)
WSW-1 020314 01034 David Breeden 22920 Aberdeen Road,
Laurinburg, NC 28352
22920 Aberdeen Road,
Laurinburg, NC 28352 In-Active Non-Potable Yes Yes ~180 NW
WSW-2 020314 01033 Janet Stack 15900 Monroe Road
Laurinburg, NC 28352
15900 Monroe Road
Laurinburg, NC 28352 Active Potable Yes No ~460 W
WSW-3 020314 01036 Harry E Clark 15825 Monroe Road
Laurinburg, NC 28352
15825 Monroe Road
Laurinburg, NC 28352 Active Potable No No ~1,060 NW
WSW-4 020314 01037 Sharon Monroe 15781 Monroe Road
Laurinburg, NC 28352
15781 Monroe Road
Laurinburg, NC 28352 Active Potable No No ~1,120 NW
WSW-5 020322 01033 Thomas C Tapp
Patricia McMillan Tapp
23040 Aberdeen Road
Laurinburg, NC 28352
23040 Aberdeen Road
Laurinburg, NC 28352 Active Potable No No ~1,070 NW
Notes:
• Receptors are shown on Figure 3A.
• N/A: Not Applicable.
TABLE 3
RECEPTOR INFORMATION
BREEDEN'S 66 (INCIDENT NO. 48332)
Date: 04/28/22
Well Construction Details
(Depth, Screened Interval, Type of Well, ect.)
Facility ID #: 00-0-000000347
Unknown
Unknown
Unknown
Unknown
Unknown
Page 1 of 1
Date: 04/28/22 Facility ID #: 00-0-000000347
PIN Number Property Owner Name Property Owner Address
020314 0103401
(site)S & H Rental Inc. P.O. Box 2048 Raeford, NC 28376
020314 01034
020314 01039
020314 01033 Janet Stack 15900 Monroe Road
Laurinburg, NC 28352
020314 01024
020316 01001
Note:
• Properties are keyed to Figure 3a.
TABLE 4
ADJACENT PROPERTY OWNER INFORMATION
BREEDEN'S 66 (INCIDENT NO. 48332)
Howell Land Co. 2 LLC.P.O. Box 1151,
Laurinburg, NC 28353
David Breeden 22900 Aberdeen Road
Laurinburg, NC 28352
Page 1 of 1
Date: 12/01/2023
Well ID
Date
Installed
(mm/dd/yy)
Date Water
Level
Measured
(mm/dd/yy)
Well
Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(ft.)
Free Product
Thickness
(ft.)
Groundwater
Elevation
(ft.)
Comments
04/13/22 16.79 ---83.21
06/23/22 17.53 ---82.47
01/10/23 19.58 ---80.42
05/09/23 16.09 ---83.91
08/24/23 17.16 ---82.84
11/13/23 19.03 ---80.97
06/23/22 19.03 ---81.95
01/10/23 20.54 ---80.44
05/09/23 17.08 ---83.90
08/24/23 18.19 ---82.79
11/13/23 19.96 ---81.02
06/23/22 17.72 ---81.78
01/10/23 19.20 ---80.30
05/09/23 15.77 ---83.73
08/24/23 16.83 ---82.67
11/13/23 18.70 0.01 80.81
06/23/22 18.41 ---82.09
01/10/23 20.07 ---80.43
05/09/23 16.91 ---83.59
08/24/23 17.55 ---82.95
11/13/23 19.47 ---81.03
01/10/23 18.90 ---80.23
05/09/23 15.51 ---83.62
08/24/23 16.55 ---82.58
11/13/23 19.39 ---79.74
01/10/23 18.24 ---80.17
05/09/23 14.82 ---83.59
08/24/23 15.57 ---82.84
11/13/23 17.76 ---80.65
01/10/23 17.93 ---80.15
05/09/23 14.55 ---83.53
08/24/23 15.60 ---82.48
11/13/23 17.44 ---80.64
01/10/23 19.65 ---80.33
05/09/23 16.14 ---83.84
08/24/23 17.13 ---82.85
11/13/23 19.08 ---80.90
01/10/23 22.15 ---77.66
05/09/23 19.56 ---80.25
08/24/23 18.89 ---80.92
11/13/23 21.10 ---78.71
Notes:
• ft BGS : feet below ground surface.
• NA: Not available.
• NM: Not measured.
TABLE 5
WELL CONSTRUCTION AND GAUGING INFORMATION
BREEDEN'S 66 (INCIDENT NO. 48332)
Facility ID #: 00-0-000000347
MW-1
06/23/22 99.502510 - 2510
01/04/23
01/03/23
25 98.41
06/23/22
99.132510 - 2510
10 10 - 25 25 100.50
TW-1 01/06/23
MW-7
MW-8 01/05/23
01/04/23
MW-2
MW-3
MW-4
MW-5
MW-6
06/23/22
04/13/22
99.815550 - 5550
10 10 - 25 25 99.98
98.082510 - 2510
10 10 - 25
10 10 - 25 25 100.98
100.002510 - 2510
Page 1 of 1
Date: 12/01/2023
EPA
504.1 EPA 6010
Well
ID
Date Sampled
(mm/dd/yy)
1 600 600 500 20 6 40 10 70 70 70 400 400 0.02 1 30 15 400 700 200 700 10,000 200
5,000 260,000 80,000 50,000 20,000 6,000 40,000 10,000 5,900 30,500 26,100 28,500 24,100 50 1,000 12,000 15,000 NE NE NE NE NE NE
04/13/22 303 180 170 420 419 27.9 266 <20 6.2 16.9 33.6 120 70.2 <0.018 3.9 J 7.4 212 662 61.5 J 365 <50 <50 172 J
01/10/23 550 362 361 1,360 864 40.5 1,350 187 9.97 22.2 40.6 343 150 NR NR NR NR NR NR NR NR NR NR
05/09/23 1,050 340 709 1,320 1,300 74.7 1,560 827 8.3 J 26.3 71.4 447 262 NR NR NR NR NR NR NR NR NR NR
08/24/23 841 177 569 763 1,160 86.6 1,540 623 7.0 J 26.1 64.2 251 241 NR NR NR NR NR NR NR NR NR NR
11/13/23 1,010 188 734 711 1,610 123 1,890 821 14.6 41.1 93.8 313 376 NM NM NM NM NM NM NM NM NM NM
06/23/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <1.90 <1.60 <0.180 <0.180 <0.190 <0.190 <0.180 0.0219 <1.27 <7.96 0.049 <11.5 <25.8 <4.02 <38.1 <168 <82.7
01/10/23 0.239 J <0.220 <0.170 <0.210 <0.140 <0.470 <1.90 6.00 J <0.180 <0.180 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR NR NR
05/09/23 <0.13 0.31 J 0.14 J 0.35 J <0.13 <0.13 <2.0 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR
08/24/23 <0.13 0.18 J <0.13 0.45 J <0.13 <0.13 <2.0 <2.0 <0.13 <0.13 <0.13 0.14 J <0.13 NR NR NR NR NR NR NR NR NR NR
11/13/23 <0.13 <0.13 <0.13 <0.25 0.16 J <0.13 <2.0 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 NM NM NM NM NM NM NM NM NM NM
06/23/22 587 15,500 3,680 20,000 111 851 <190 <160 61.3 251 760 5,520 1,550 0.0360 66.5 132 0.269 23,400 15,900 12,400 783 <177 771
01/10/23 168 1,910 522 2,860 43.3 65 76.1 18.6 81.8 34.3 92.3 810 251 NR NR NR NR NR NR NR NR NR NR
05/09/23 1,350 17,800 3,310 19,300 158 474 <500 <500 <31 105 J 381 3,050 757 NR NR NR NR NR NR NR NR NR NR
08/24/23 505 5,620 1,550 9,080 341 368 433 J <200 33.1 J 100 325 2,600 719 NR NR NR NR NR NR NR NR NR NR
11/13/23 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
06/23/22 2.08 52.6 17.8 102 175 <0.470 <1.90 <1.60 1.25 1.99 6.98 52.9 15.5 0.0407 1.64 J <8.51 0.022 412 332 429 <36.4 <160 <79.1
01/10/23 0.638 <0.220 <0.170 <0.210 249 <0.470 68.8 15.6 <0.180 <0.180 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR NR NR
05/09/23 <0.63 <0.63 <0.63 <1.3 147 <0.63 24.8 J <10 <0.63 <0.63 <0.63 <0.63 <0.63 NR NR NR NR NR NR NR NR NR NR
08/24/23 1.5 0.61 1.9 3.0 60.2 0.57 3.6 J <2.0 <0.13 <0.13 0.19 J 0.84 0.51 NR NR NR NR NR NR NR NR NR NR
11/13/23 <0.13 0.39 J 0.34 J 1.14 J 45.9 0.55 <2.0 <2.0 <0.13 <0.13 <0.13 0.61 0.27 J NM NM NM NM NM NM NM NM NM NM
01/10/23 14.6 62.8 68.3 413 15.6 25.5 98.2 88.6 2.1 4.67 8.63 109 28.9 <0.00337 2.63 5.05 <10.0 545 644 475 NA*NA*NA*
05/09/23 <0.13 0.82 0.25 J 1.2 J 0.49 J <0.13 <2.0 <2.0 <0.13 <0.13 <0.13 0.14 J <0.13 NR NR NR NR NR NR NR NR NR NR
08/24/23 9.9 130 105 577 3.3 39.4 36.1 3.4 J 2.1 8.1 24.7 206 74.1 NR NR NR NR NR NR NR NR NR NR
11/13/23 0.14 J <0.13 <0.13 0.34 J 0.53 0.16 J <2.0 <2.0 <0.13 <0.13 <0.13 0.19 J <0.13 NM NM NM NM NM NM NM NM NM NM
01/10/23 26.0 148.0 48.9 206 38.9 13.5 71.8 15.7 0.319 J 3.90 4.60 44.7 9.10 <0.00342 <1.26 1.53 J 18.9 266 189 114 <29.4 <129 <63.6
05/09/23 1.1 0.34 J 0.21 J 2.0 15.0 0.31 J 14.5 5.0 J <0.13 <0.13 <0.13 0.58 0.15 J NR NR NR NR NR NR NR NR NR NR
08/24/23 <0.13 <0.13 <0.13 <0.25 7.5 <0.13 <2.0 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR
11/13/23 0.16 J <0.13 <0.13 0.46 J 5.8 0.13 J <2.0 <2.0 <0.13 <0.13 <0.13 0.25 J <0.13 NM NM NM NM NM NM NM NM NM NM
01/10/23 382 2,130 448 2,620 440 157 532 J 139 4.96 19.1 37.4 594 171 0.0133 8.67 15.3 <10.0 1,550 1,060 1,240 58.1 J <124 208
05/09/23 134 193 24.4 778 152 45.1 271 <20 <1.3 <1.3 1.8 J 186 42.1 NR NR NR NR NR NR NR NR NR NR
08/24/23 44.3 7.1 15.2 106 37.7 14.0 76.5 10.4 0.64 2.8 4.6 23.2 9.8 NR NR NR NR NR NR NR NR NR NR
11/13/23 27.0 1.7 2.5 31.2 47.4 8.7 64.0 <2.0 <0.13 0.35 J 0.44 J 1.8 7.6 NM NM NM NM NM NM NM NM NM NM
01/10/23 2.28 4.19 4.83 20.7 0.228 J <0.470 <1.90 4.44 J <0.180 0.364 J 0.89 5.61 2.30 <0.00333 <1.17 <0.682 34.8 <11.5 55.3 J 13.6 J NA*NA*NA*
05/09/23 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR
08/24/23 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR
11/13/23 <0.13 <0.13 <0.13 <0.25 <0.13 0.23 J <2.0 <2.0 <0.13 <0.13 <0.13 0.26 J <0.13 NM NM NM NM NM NM NM NM NM NM
GCL (μg/l)MTBENaphthaleneContaminant of Concern

MAC (μg/l)1-Methylnaphthalenetert-Amyl alcohol(TAA)BenzeneTolueneEthylbenzene1,3,5-Trimethylbenzene1,2,4-TrimethylbenzeneEDBn-PropylbenzeneIsopropylbenzenetert-Butyl alcohol(TBA)n-ButylbenzeneMADEP EPH
C9-C18 AliphaticsC19-C36 AliphaticsC11-C22 AromaticsTABLE 6
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
BREEDEN'S 66 (INCIDENT NO. 48332)
Facility ID #: 00-0-000000347
XylenesC9-C10 AromaticsC9-C12 AliphaticsAnalytical Method
MADEP VPHEPA 625.1
LeadC5-C8 Aliphatics2-MethylnaphthaleneEPA 6200B
MW-8
MW-7
MW-6
MW-1
MW-5
MW-4
MW-3
MW-2
Page 1 of 2
Date: 12/01/2023
EPA
504.1 EPA 6010
Well
ID
Date Sampled
(mm/dd/yy)
1 600 600 500 20 6 40 10 70 70 70 400 400 0.02 1 30 15 400 700 200 700 10,000 200
5,000 260,000 80,000 50,000 20,000 6,000 40,000 10,000 5,900 30,500 26,100 28,500 24,100 50 1,000 12,000 15,000 NE NE NE NE NE NEGCL (μg/l)MTBENaphthaleneContaminant of Concern

MAC (μg/l)1-Methylnaphthalenetert-Amyl alcohol(TAA)BenzeneTolueneEthylbenzene1,3,5-Trimethylbenzene1,2,4-TrimethylbenzeneEDBn-PropylbenzeneIsopropylbenzenetert-Butyl alcohol(TBA)n-ButylbenzeneMADEP EPH
C9-C18 AliphaticsC19-C36 AliphaticsC11-C22 AromaticsTABLE 6
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
BREEDEN'S 66 (INCIDENT NO. 48332)
Facility ID #: 00-0-000000347
XylenesC9-C10 AromaticsC9-C12 AliphaticsAnalytical Method
MADEP VPHEPA 625.1
LeadC5-C8 Aliphatics2-MethylnaphthaleneEPA 6200B
01/10/23 0.566 0.697 0.473 J 2.03 0.972 J <0.470 3.08 J 5.47 J <0.180 <0.180 <0.190 0.918 0.305 J <0.00343 <1.26 <0.735 <10.0 <11.5 <25.8 <4.02 <29.1 <128 <63.2
05/09/23 0.73 1.2 0.46 J 1.3 J 0.41 J <0.13 <2.0 <2.0 <0.13 <0.13 <0.13 0.16 J <0.13 NR NR NR NR NR NR NR NR NR NR
08/24/23 0.52 0.62 0.30 J 0.91 J 0.27 J <0.13 <2.0 <2.0 <0.13 <0.13 <0.13 0.22 J <0.13 NR NR NR NR NR NR NR NR NR NR
11/13/23 0.43 J 1.80 1.8 14.2 0.38 J 21.9 <2.0 <2.0 1.3 0.34 J 1.8 30.7 7.0 NM NM NM NM NM NM NM NM NM NM
WSW-2 08/24/23 <0.13 0.15 J <0.13 <0.25 <0.13 <0.13 <2.0 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR
06/23/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 NR NA <0.180 <0.180 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR NR NR
01/10/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <1.90 <1.60 <0.180 <0.180 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR NR NR
05/09/23 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR
08/24/23 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 ------<0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR
11/13/23 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NM NM <0.13 <0.13 <0.13 <0.13 <0.13 NM NM NM NM NM NM NM NM NM NM
Notes:
• Concentrations of tert-amyl methyl ether (136 µg/l) and hexachlorobutadiene 6.3 J (µg/l) reported in MW-1 exceeded the MACs.
• Results reported in micrograms per liter (µg/l).
• MAC: Maximum Allowable Concentration as specified in T15A NCAC 2L.0202.
• < : Less than the method detection limit specified in the laboratory report.
• GCL: Gross contamination level.
• Concentrations in bold face type indicate the reported contaminant concentration exceeded the MAC.
• Results in italics indicate the reported contaminant concentration exceeded the GCL.
• J: Estimated value.
• J: Relative percent difference >40% dual column results.
• NE: Not established.
• NA: Not analyzed.
• NR: Not reported.
• Refer to laboratory report for other detectable concentrations which did not exceed the MAC.
Trip Blank
TW-1
Page 2 of 2
Well No.Sampled Date
(mm/dd/yy)
DO
(mg/L)Temp (oC)pH ORP
(mv)
Methane
(μg/l)
Ferrous
Iron
(μg/l)
Nitrate
(μg/l)
Sulfate
(μg/l)
05/09/23 1.81 20.42 6.16 71.0 34.2 1,400 <100 <2,000
08/24/23 1.86 22.19 6.18 75.9 28.3 4,900 <100 <2,000
11/13/23 6.58 NM NM 23.3 31.2 3,200 <100 <2,000
05/09/23 2.00 19.79 4.52 290.7 <0.16 <100 22,500 <10,000
08/24/23 1.29 20.98 4.62 264.3 0.32 J <100 19,800 3,100
11/13/23 7.46 NM NM 258.8 0.23 260 6,700 5,100
05/09/23 1.22 20.31 4.41 250.6 63.4 2,700 360 73,800
08/24/23 2.09 22.43 5.67 146.1 23.1 1,700 2,900 3,500
05/09/23 1.65 20.92 5.95 156.2 0.31 J 510 1,200 3,800
08/24/23 1.80 21.96 6.21 78.0 0.22 J 1,700 1,100 8,400
11/13/23 5.21 NM NM 257.9 0.46 250 1,500 <2,000
05/09/23 2.17 19.69 4.88 143.1 15.9 <100 3,000 <2,000
08/24/23 1.89 21.78 5.69 213.6 14.3 120 2,700 19,000
11/13/23 7.43 NM NM 274.8 64.5 <100 3,700 <2,000
05/09/23 1.21 20.69 6.41 -98.5 71.2 <100 2,400 17,900
08/24/23 1.78 22.11 5.60 175.2 15.5 <100 2,900 <2,000
11/13/23 7.39 NM NM 81.9 7.6 120 3,100 <2,000
05/09/23 1.21 20.13 5.68 49.4 8.6 3,200 <100 <2,000
08/24/23 1.70 22.09 5.57 186.0 5.7 1,800 420 <2,000
11/13/23 6.34 NM NM 49.4 6.3 120 210 <2,000
05/09/23 2.21 20.88 5.60 213.5 0.16 J <100 2,900 <2,000
08/24/23 1.99 22.62 5.39 202.1 <0.50 170 2,900 <2,000
11/13/23 5.16 NM NM 263.9 0.18 J 5,600 2,700 3,500
05/09/23 1.67 20.59 9.29 127.8 3.3 <100 <100 4,700
08/24/23 1.59 21.86 7.71 120.7 3.3 110 120 23,200
11/13/23 7.57 NM NM 18.1 19.5 <100 <100 5,700
Notes:
• Field measurements of dissolved oxygen, temperature, pH and ORP were collected during
sampling using a field meter.
• NM: Not Measured. Low volume of groundwater for final reading.
MW-3
TW-1
MW-4
MW-8
MW-7
MW-6
MW-5
MW-2
Date: 12/04/23
BREEDEN'S 66 (INCIDENT NO. 48332)
SUMMARY OF FIELD PARAMETER RESULTS
TABLE 6A
Facility ID #: 00-0-000000347
MW-1

APPENDICES

APPENDIX A
State Correspondence

North Carolina Department of Environmental Quality | Division of Waste Management
Fayetteville Regional Office | 225 Green Street | Suite 714 | Fayetteville, NC 28301 | [phone]

October 30, 2023

DELIVERED BY EMAIL ATTACHMENT

Mr. Jimmy McDonald
Quality Oil & Gas
203 West Broad Avenue
Rockingham, NC 28379

Re: Acknowledgment of Report Receipt
15A NCAC 2L .0407(c)
Risk-based Assessment and Corrective Action
for Petroleum Underground Storage Tanks

Breeden’s 66
22900 Aberdeen Road
Laurinburg, Scotland County
Incident Number: 48332
Risk Classification: High
Rank: H-190-A

Dear Mr. McDonald:

The Monitoring Report dated September 25, 2023, has been reviewed. The UST Section agrees with your consultant’s recommendation to conduct quarterly sampling events until a concentration history and plume
stability can be obtained. The next sampling event is understood to be tentatively scheduled for November
2023.

If you have questions regarding the information contained in this letter, please contact me at the Fayetteville
Regional Office address below or at [phone].

Sincerely,

Kenneth E. Currie
Hydrogeologist
Fayetteville Regional Office
UST Section, Division of Waste Management

c: Mr. William Regenthal, P.G., Geological Resources, Inc., Winterville, NC (email copy)
FRO Electronic Incident File #48332
5991 Received OCT 31 2023
5991 Received NOV 03 2023

APPENDIX B
Laboratory Report – Ground Water Samples

12/01/23
Technical Report for
GRI (Geological Resources Inc.)
Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
5991
SGS Job Number: FC11199
Sampling Date: 11/13/23
Report to:
[e-mail]
[e-mail]
[e-mail]
ATTN: Distribution6
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AL, AK, AR, CT, IA, KY, MA, MI. MS, ND, NH, NV, OK, OR, IL, UT, VT, WA, WI, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] •
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable unless noted
in the narrative, comments or footnotes.
Client Service contact: Muna Mohammed 407-425-6700
Norm Farmer
Technical Director
Orlando, FL 12/01/23
e-Hardcopy 2.0
Automated Report
81
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
1 of 81
FC11199
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................7
3.1: FC11199-1: MW-1 ........................................................................................................8
3.2: FC11199-2: MW-2 ........................................................................................................13
3.3: FC11199-3: MW-4 ........................................................................................................18
3.4: FC11199-4: MW-5 ........................................................................................................23
3.5: FC11199-5: MW-6 ........................................................................................................28
3.6: FC11199-6: MW-7 ........................................................................................................33
3.7: FC11199-7: MW-8 ........................................................................................................38
3.8: FC11199-8: TW-1 .........................................................................................................43
3.9: FC11199-9: TB .............................................................................................................48
Section 4: Misc. Forms ............................................................................................................50
4.1: Chain of Custody ...........................................................................................................51
Section 5: MS Volatiles - QC Data Summaries .....................................................................53
5.1: Method Blank Summary ................................................................................................54
5.2: Blank Spike Summary ...................................................................................................60
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................66
Section 6: GC Volatiles - QC Data Summaries .....................................................................72
6.1: Method Blank Summary ................................................................................................73
6.2: Blank Spike/Blank Spike Duplicate Summary ..............................................................74
6.3: Matrix Spike Summary ..................................................................................................75
6.4: Duplicate Summary .......................................................................................................76
Section 7: General Chemistry - QC Data Summaries ..........................................................77
7.1: Method Blank and Spike Results Summary ..................................................................78
7.2: Duplicate Results Summary ..........................................................................................79
7.3: Matrix Spike Results Summary .....................................................................................80
7.4: Matrix Spike Duplicate Results Summary ....................................................................81 12345672 of 81
FC11199
SGS LabLink@06:43 01-Dec-2023
Sample Summary
GRI (Geological Resources Inc.)
Job No:FC11199
Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Project No: 5991
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the MDL
FC11199-1 11/13/23 13:10 JB 11/14/23 AQ Ground Water MW-1
FC11199-2 11/13/23 09:00 JB 11/14/23 AQ Ground Water MW-2
FC11199-3 11/13/23 09:32 JB 11/14/23 AQ Ground Water MW-4
FC11199-4 11/13/23 09:10 JB 11/14/23 AQ Ground Water MW-5
FC11199-5 11/13/23 13:40 JB 11/14/23 AQ Ground Water MW-6
FC11199-6 11/13/23 13:53 JB 11/14/23 AQ Ground Water MW-7
FC11199-7 11/13/23 09:50 JB 11/14/23 AQ Ground Water MW-8
FC11199-8 11/13/23 13:30 JB 11/14/23 AQ Ground Water TW-1
FC11199-9 11/13/23 08:15 JB 11/14/23 AQ Trip Blank Water TB
3 of 81
FC111991
Summary of Hits Page 1 of 3
Job Number:FC11199
Account:GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Collected:11/13/23
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FC11199-1 MW-1
Benzene 1010 13 3.1 ug/l SM 6200B
n-Butylbenzene 14.6 13 3.1 ug/l SM 6200B
sec-Butylbenzene 12.1 J 13 3.1 ug/l SM 6200B
Chloroform 6.2 J 13 3.1 ug/l SM 6200B
Di-Isopropyl Ether 11.4 J 13 3.1 ug/l SM 6200B
Ethylbenzene 734 13 3.1 ug/l SM 6200B
Hexachlorobutadiene 6.3 J 13 3.1 ug/l SM 6200B
Isopropylbenzene 41.1 13 3.1 ug/l SM 6200B
p-Isopropyltoluene 9.0 J 13 3.1 ug/l SM 6200B
Methyl Tert Butyl Ether 1610 13 3.1 ug/l SM 6200B
Naphthalene 123 13 3.1 ug/l SM 6200B
n-Propylbenzene 93.8 13 3.1 ug/l SM 6200B
Tert-Amyl Alcohol 1890 250 50 ug/l SM 6200B
Tert-Amyl Methyl Ether 136 25 5.0 ug/l SM 6200B
Tert-Butyl Alcohol 821 250 50 ug/l SM 6200B
Toluene 188 13 3.1 ug/l SM 6200B
1,2,3-Trichlorobenzene 3.6 J 13 3.1 ug/l SM 6200B
1,2,4-Trichlorobenzene 3.4 J 13 3.1 ug/l SM 6200B
1,2,4-Trimethylbenzene 313 13 3.1 ug/l SM 6200B
1,3,5-Trimethylbenzene 376 13 3.1 ug/l SM 6200B
m,p-Xylene 407 25 3.1 ug/l SM 6200B
o-Xylene 304 13 3.1 ug/l SM 6200B
Methane 31.2 0.50 0.16 ug/l RSKSOP-147/175
Iron, Ferrous a 3.2 0.50 mg/l SM3500FE B-11
FC11199-2 MW-2
Methyl Tert Butyl Ether b 0.16 J 0.50 0.13 ug/l SM 6200B
Methane 0.23 J 0.50 0.16 ug/l RSKSOP-147/175
Iron, Ferrous a 0.26 0.10 mg/l SM3500FE B-11
Nitrogen, Nitrate c 6.7 0.10 mg/l EPA 300/SW846 9056A
Sulfate 5.1 2.0 mg/l EPA 300/SW846 9056A
FC11199-3 MW-4
Chloroform 0.31 J 0.50 0.13 ug/l SM 6200B
Di-Isopropyl Ether 0.21 J 0.50 0.13 ug/l SM 6200B
Ethylbenzene 0.34 J 0.50 0.13 ug/l SM 6200B
Methyl Tert Butyl Ether 45.9 0.50 0.13 ug/l SM 6200B
Naphthalene 0.55 0.50 0.13 ug/l SM 6200B
Toluene 0.39 J 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 0.61 0.50 0.13 ug/l SM 6200B
1,3,5-Trimethylbenzene 0.27 J 0.50 0.13 ug/l SM 6200B
4 of 81
FC111992
Summary of Hits Page 2 of 3
Job Number:FC11199
Account:GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Collected:11/13/23
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
m,p-Xylene 0.77 J 1.0 0.13 ug/l SM 6200B
o-Xylene 0.37 J 0.50 0.13 ug/l SM 6200B
Methane 0.46 J 0.50 0.16 ug/l RSKSOP-147/175
Iron, Ferrous a 0.25 0.10 mg/l SM3500FE B-11
Nitrogen, Nitrate c 1.5 0.10 mg/l EPA 300/SW846 9056A
FC11199-4 MW-5
Benzene 0.14 J 0.50 0.13 ug/l SM 6200B
Methyl Tert Butyl Ether 0.53 0.50 0.13 ug/l SM 6200B
Naphthalene 0.16 J 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 0.19 J 0.50 0.13 ug/l SM 6200B
m,p-Xylene 0.34 J 1.0 0.13 ug/l SM 6200B
Methane 64.5 0.50 0.16 ug/l RSKSOP-147/175
Nitrogen, Nitrate c 3.7 0.10 mg/l EPA 300/SW846 9056A
FC11199-5 MW-6
Benzene 0.16 J 0.50 0.13 ug/l SM 6200B
Methyl Tert Butyl Ether 5.8 0.50 0.13 ug/l SM 6200B
Naphthalene 0.13 J 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 0.25 J 0.50 0.13 ug/l SM 6200B
m,p-Xylene 0.27 J 1.0 0.13 ug/l SM 6200B
o-Xylene 0.19 J 0.50 0.13 ug/l SM 6200B
Methane 7.6 0.50 0.16 ug/l RSKSOP-147/175
Iron, Ferrous a 0.12 0.10 mg/l SM3500FE B-11
Nitrogen, Nitrate 3.1 0.10 mg/l EPA 300/SW846 9056A
FC11199-6 MW-7
Benzene 27.0 0.50 0.13 ug/l SM 6200B
Di-Isopropyl Ether 0.36 J 0.50 0.13 ug/l SM 6200B
Ethylbenzene 2.5 0.50 0.13 ug/l SM 6200B
Isopropylbenzene 0.35 J 0.50 0.13 ug/l SM 6200B
Methyl Tert Butyl Ether 47.4 0.50 0.13 ug/l SM 6200B
Naphthalene 8.7 0.50 0.13 ug/l SM 6200B
n-Propylbenzene 0.44 J 0.50 0.13 ug/l SM 6200B
Tert-Amyl Alcohol 64.0 10 2.0 ug/l SM 6200B
Tert-Amyl Methyl Ether 4.8 1.0 0.20 ug/l SM 6200B
Toluene 1.7 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 1.8 0.50 0.13 ug/l SM 6200B
1,3,5-Trimethylbenzene 7.6 0.50 0.13 ug/l SM 6200B
m,p-Xylene 6.3 1.0 0.13 ug/l SM 6200B
o-Xylene 24.9 0.50 0.13 ug/l SM 6200B
Methane 6.3 0.50 0.16 ug/l RSKSOP-147/175
5 of 81
FC111992
Summary of Hits Page 3 of 3
Job Number:FC11199
Account:GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Collected:11/13/23
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
Iron, Ferrous a 0.12 0.10 mg/l SM3500FE B-11
Nitrogen, Nitrate 0.21 0.10 mg/l EPA 300/SW846 9056A
FC11199-7 MW-8
Naphthalene 0.23 J 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 0.26 J 0.50 0.13 ug/l SM 6200B
Methane 0.18 J 0.50 0.16 ug/l RSKSOP-147/175
Iron, Ferrous a 5.6 0.50 mg/l SM3500FE B-11
Nitrogen, Nitrate c 2.7 0.10 mg/l EPA 300/SW846 9056A
Sulfate 3.5 2.0 mg/l EPA 300/SW846 9056A
FC11199-8 TW-1
Benzene 0.43 J 0.50 0.13 ug/l SM 6200B
n-Butylbenzene 1.3 0.50 0.13 ug/l SM 6200B
sec-Butylbenzene 0.37 J 0.50 0.13 ug/l SM 6200B
Ethylbenzene 1.8 0.50 0.13 ug/l SM 6200B
Isopropylbenzene 0.34 J 0.50 0.13 ug/l SM 6200B
p-Isopropyltoluene 0.36 J 0.50 0.13 ug/l SM 6200B
Methyl Tert Butyl Ether 0.38 J 0.50 0.13 ug/l SM 6200B
Naphthalene 21.9 0.50 0.13 ug/l SM 6200B
n-Propylbenzene 1.8 0.50 0.13 ug/l SM 6200B
Toluene 1.8 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 30.7 0.50 0.13 ug/l SM 6200B
1,3,5-Trimethylbenzene 7.0 0.50 0.13 ug/l SM 6200B
m,p-Xylene 8.8 1.0 0.13 ug/l SM 6200B
o-Xylene 5.4 0.50 0.13 ug/l SM 6200B
Methane 19.5 0.50 0.16 ug/l RSKSOP-147/175
Sulfate 5.9 2.0 mg/l EPA 300/SW846 9056A
FC11199-9 TB
No hits reported in this sample.
(a) Field analysis required. Received out of hold time and analyzed by request.
(b) Sample vial(s) contained bubbles greater than 6mm.
(c) Originally ran in hold. Re-run out of hold due to CCV failure.
6 of 81
FC111992
SGS LabLink@06:43 01-Dec-2023
Sample Results
Report of Analysis
Orlando, FL
Section 3
7 of 81
FC111993
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 3
Client Sample ID:MW-1
Lab Sample ID:FC11199-1 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A4516.D 25 11/22/23 17:46 TD n/a n/a V3A215
Run #2 a 3A4573.D 25 11/28/23 19:24 TD n/a n/a V3A218
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 1010 13 3.1 ug/l
108-86-1 Bromobenzene ND 13 3.1 ug/l
74-97-5 Bromochloromethane ND 13 3.1 ug/l
75-27-4 Bromodichloromethane ND 13 3.1 ug/l
75-25-2 Bromoform ND 13 3.1 ug/l
104-51-8 n-Butylbenzene 14.6 13 3.1 ug/l
135-98-8 sec-Butylbenzene 12.1 13 3.1 ug/l J
98-06-6 tert-Butylbenzene ND 13 3.1 ug/l
56-23-5 Carbon Tetrachloride ND 13 3.1 ug/l
108-90-7 Chlorobenzene ND 13 3.1 ug/l
75-00-3 Chloroethane ND 13 5.0 ug/l
67-66-3 Chloroform 6.2 13 3.1 ug/l J
95-49-8 o-Chlorotoluene ND 13 3.1 ug/l
106-43-4 p-Chlorotoluene ND 13 3.1 ug/l
124-48-1 Dibromochloromethane ND 13 3.1 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 13 6.2 ug/l
106-93-4 1,2-Dibromoethane ND 13 3.1 ug/l
75-71-8 Dichlorodifluoromethane ND 13 5.0 ug/l
95-50-1 1,2-Dichlorobenzene ND 13 3.1 ug/l
541-73-1 1,3-Dichlorobenzene ND 13 3.1 ug/l
106-46-7 1,4-Dichlorobenzene ND 13 3.1 ug/l
75-34-3 1,1-Dichloroethane ND 13 3.1 ug/l
107-06-2 1,2-Dichloroethane ND 13 3.1 ug/l
75-35-4 1,1-Dichloroethylene ND 13 3.1 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 13 3.1 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 13 3.1 ug/l
78-87-5 1,2-Dichloropropane ND 13 3.1 ug/l
142-28-9 1,3-Dichloropropane ND 13 3.1 ug/l
594-20-7 2,2-Dichloropropane ND 13 3.1 ug/l
563-58-6 1,1-Dichloropropene ND 13 3.1 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 13 3.1 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 13 3.1 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 81
FC1119933.1
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 2 of 3
Client Sample ID:MW-1
Lab Sample ID:FC11199-1 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 11.4 13 3.1 ug/l J
100-41-4 Ethylbenzene 734 13 3.1 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 13 3.1 ug/l
87-68-3 Hexachlorobutadiene 6.3 13 3.1 ug/l J
98-82-8 Isopropylbenzene 41.1 13 3.1 ug/l
99-87-6 p-Isopropyltoluene 9.0 13 3.1 ug/l J
74-83-9 Methyl Bromide ND 13 5.0 ug/l
74-87-3 Methyl Chloride ND 13 5.0 ug/l
74-95-3 Methylene Bromide ND 13 3.1 ug/l
75-09-2 Methylene Chloride ND 50 25 ug/l
1634-04-4 Methyl Tert Butyl Ether 1610 13 3.1 ug/l
91-20-3 Naphthalene 123 13 3.1 ug/l
103-65-1 n-Propylbenzene 93.8 13 3.1 ug/l
100-42-5 Styrene ND 13 3.1 ug/l
75-85-4 Tert-Amyl Alcohol 1890 250 50 ug/l
994-05-8 Tert-Amyl Methyl Ether 136 25 5.0 ug/l
75-65-0 Tert-Butyl Alcohol 821 250 50 ug/l
762-75-4 Tert-Butyl Formate ND 250 50 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 13 3.1 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 13 3.1 ug/l
127-18-4 Tetrachloroethylene ND 13 3.1 ug/l
108-88-3 Toluene 188 13 3.1 ug/l
87-61-6 1,2,3-Trichlorobenzene 3.6 13 3.1 ug/l J
120-82-1 1,2,4-Trichlorobenzene 3.4 13 3.1 ug/l J
71-55-6 1,1,1-Trichloroethane ND 13 3.1 ug/l
79-00-5 1,1,2-Trichloroethane ND 13 3.1 ug/l
79-01-6 Trichloroethylene ND 13 3.1 ug/l
75-69-4 Trichlorofluoromethane ND 13 5.0 ug/l
96-18-4 1,2,3-Trichloropropane ND 13 3.1 ug/l
95-63-6 1,2,4-Trimethylbenzene 313 13 3.1 ug/l
108-67-8 1,3,5-Trimethylbenzene 376 13 3.1 ug/l
75-01-4 Vinyl Chloride ND 13 3.1 ug/l
m,p-Xylene 407 25 3.1 ug/l
95-47-6 o-Xylene 304 13 3.1 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 97%97%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%100%70-130%
2037-26-5 Toluene-D8 99%99%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
9 of 81
FC1119933.1
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 3 of 3
Client Sample ID:MW-1
Lab Sample ID:FC11199-1 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 99%99%70-130%
(a) Sample analyzed beyond hold time. Confirmation run.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
10 of 81
FC1119933.1
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 1
Client Sample ID:MW-1
Lab Sample ID:FC11199-1 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL86475.D 1 11/21/23 13:04 SS n/a n/a GLL2995
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane 31.2 0.50 0.16 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
11 of 81
FC1119933.1
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 1
Client Sample ID:MW-1
Lab Sample ID:FC11199-1 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a 3.2 0.50 mg/l 5 11/15/23 12:30 FN SM3500FE B-11
Nitrogen, Nitrate <0.10 0.10 mg/l 1 11/14/23 20:55 JR EPA 300/SW846 9056A
Sulfate <2.0 2.0 mg/l 1 11/14/23 20:55 JR EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
RL = Reporting Limit
12 of 81
FC1119933.1
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 3
Client Sample ID:MW-2
Lab Sample ID:FC11199-2 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 3A4433.D 1 11/18/23 00:22 TD n/a n/a V3A212
Run #2 a 3A4517.D 1 11/22/23 18:10 TD n/a n/a V3A215
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND b 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane c ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
13 of 81
FC1119933.2
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 2 of 3
Client Sample ID:MW-2
Lab Sample ID:FC11199-2 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND b 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 0.16 0.50 0.13 ug/l J
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate d ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 100%97%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%101%70-130%
2037-26-5 Toluene-D8 100%100%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
14 of 81
FC1119933.2
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 3 of 3
Client Sample ID:MW-2
Lab Sample ID:FC11199-2 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 99%100%70-130%
(a) Sample vial(s) contained bubbles greater than 6mm.
(b) Result is from Run# 2
(c) Associated ICV outside control limits high, however sample ND.
(d) Associated BS recovery outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
15 of 81
FC1119933.2
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 1
Client Sample ID:MW-2
Lab Sample ID:FC11199-2 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL86476.D 1 11/21/23 13:18 SS n/a n/a GLL2995
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane 0.23 0.50 0.16 ug/l J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
16 of 81
FC1119933.2
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 1
Client Sample ID:MW-2
Lab Sample ID:FC11199-2 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a 0.26 0.10 mg/l 1 11/15/23 12:30 FN SM3500FE B-11
Nitrogen, Nitrate b 6.7 0.10 mg/l 1 11/15/23 11:27 JR EPA 300/SW846 9056A
Sulfate 5.1 2.0 mg/l 1 11/14/23 21:56 JR EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
(b) Originally ran in hold. Re-run out of hold due to CCV failure.
RL = Reporting Limit
17 of 81
FC1119933.2
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 3
Client Sample ID:MW-4
Lab Sample ID:FC11199-3 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A4518.D 1 11/22/23 18:34 TD n/a n/a V3A215
Run #2 a 3A4574.D 1 11/28/23 19:49 TD n/a n/a V3A218
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform 0.31 0.50 0.13 ug/l J
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
18 of 81
FC1119933.3
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 2 of 3
Client Sample ID:MW-4
Lab Sample ID:FC11199-3 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 0.21 0.50 0.13 ug/l J
100-41-4 Ethylbenzene 0.34 0.50 0.13 ug/l J
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 45.9 0.50 0.13 ug/l
91-20-3 Naphthalene 0.55 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 0.39 0.50 0.13 ug/l J
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene 0.61 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene 0.27 0.50 0.13 ug/l J
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 0.77 1.0 0.13 ug/l J
95-47-6 o-Xylene 0.37 0.50 0.13 ug/l J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 97%96%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%100%70-130%
2037-26-5 Toluene-D8 101%100%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
19 of 81
FC1119933.3
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 3 of 3
Client Sample ID:MW-4
Lab Sample ID:FC11199-3 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 100%100%70-130%
(a) Confirmation run beyond holdtime.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
20 of 81
FC1119933.3
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 1
Client Sample ID:MW-4
Lab Sample ID:FC11199-3 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL86477.D 1 11/21/23 13:27 SS n/a n/a GLL2995
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane 0.46 0.50 0.16 ug/l J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
21 of 81
FC1119933.3
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 1
Client Sample ID:MW-4
Lab Sample ID:FC11199-3 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a 0.25 0.10 mg/l 1 11/15/23 12:30 FN SM3500FE B-11
Nitrogen, Nitrate b 1.5 0.10 mg/l 1 11/15/23 11:47 JR EPA 300/SW846 9056A
Sulfate <2.0 2.0 mg/l 1 11/14/23 22:17 JR EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
(b) Originally ran in hold. Re-run out of hold due to CCV failure.
RL = Reporting Limit
22 of 81
FC1119933.3
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 3
Client Sample ID:MW-5
Lab Sample ID:FC11199-4 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A4519.D 1 11/22/23 18:57 TD n/a n/a V3A215
Run #2 a 3A4575.D 1 11/28/23 20:12 TD n/a n/a V3A218
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 0.14 0.50 0.13 ug/l J
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
23 of 81
FC1119933.4
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 2 of 3
Client Sample ID:MW-5
Lab Sample ID:FC11199-4 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 0.53 0.50 0.13 ug/l
91-20-3 Naphthalene 0.16 0.50 0.13 ug/l J
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene 0.19 0.50 0.13 ug/l J
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 0.34 1.0 0.13 ug/l J
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 97%97%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%103%70-130%
2037-26-5 Toluene-D8 101%100%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
24 of 81
FC1119933.4
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 3 of 3
Client Sample ID:MW-5
Lab Sample ID:FC11199-4 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 99%99%70-130%
(a) Confirmation run beyond holdtime.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
25 of 81
FC1119933.4
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 1
Client Sample ID:MW-5
Lab Sample ID:FC11199-4 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL86478.D 1 11/21/23 13:34 SS n/a n/a GLL2995
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane 64.5 0.50 0.16 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
26 of 81
FC1119933.4
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 1
Client Sample ID:MW-5
Lab Sample ID:FC11199-4 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a <0.10 0.10 mg/l 1 11/15/23 12:30 FN SM3500FE B-11
Nitrogen, Nitrate b 3.7 0.10 mg/l 1 11/15/23 12:08 JR EPA 300/SW846 9056A
Sulfate <2.0 2.0 mg/l 1 11/14/23 23:18 JR EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
(b) Originally ran in hold. Re-run out of hold due to CCV failure.
RL = Reporting Limit
27 of 81
FC1119933.4
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 3
Client Sample ID:MW-6
Lab Sample ID:FC11199-5 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A4520.D 1 11/22/23 19:21 TD n/a n/a V3A215
Run #2 a 3A4576.D 1 11/28/23 20:36 TD n/a n/a V3A218
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 0.16 0.50 0.13 ug/l J
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
28 of 81
FC1119933.5
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 2 of 3
Client Sample ID:MW-6
Lab Sample ID:FC11199-5 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 5.8 0.50 0.13 ug/l
91-20-3 Naphthalene 0.13 0.50 0.13 ug/l J
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene 0.25 0.50 0.13 ug/l J
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 0.27 1.0 0.13 ug/l J
95-47-6 o-Xylene 0.19 0.50 0.13 ug/l J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 96%96%70-130%
17060-07-0 1,2-Dichloroethane-D4 102%101%70-130%
2037-26-5 Toluene-D8 100%100%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
29 of 81
FC1119933.5
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 3 of 3
Client Sample ID:MW-6
Lab Sample ID:FC11199-5 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 100%100%70-130%
(a) Confirmation run beyond holdtime.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
30 of 81
FC1119933.5
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 1
Client Sample ID:MW-6
Lab Sample ID:FC11199-5 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL86479.D 1 11/21/23 13:41 SS n/a n/a GLL2995
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane 7.6 0.50 0.16 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
31 of 81
FC1119933.5
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 1
Client Sample ID:MW-6
Lab Sample ID:FC11199-5 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a 0.12 0.10 mg/l 1 11/15/23 12:30 FN SM3500FE B-11
Nitrogen, Nitrate 3.1 0.10 mg/l 1 11/15/23 13:09 JR EPA 300/SW846 9056A
Sulfate <2.0 2.0 mg/l 1 11/15/23 00:20 JR EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
RL = Reporting Limit
32 of 81
FC1119933.5
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 3
Client Sample ID:MW-7
Lab Sample ID:FC11199-6 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A4521.D 1 11/22/23 19:45 TD n/a n/a V3A215
Run #2 a 3A4577.D 1 11/28/23 21:00 TD n/a n/a V3A218
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 27.0 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
33 of 81
FC1119933.6
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 2 of 3
Client Sample ID:MW-7
Lab Sample ID:FC11199-6 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 0.36 0.50 0.13 ug/l J
100-41-4 Ethylbenzene 2.5 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 0.35 0.50 0.13 ug/l J
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 47.4 0.50 0.13 ug/l
91-20-3 Naphthalene 8.7 0.50 0.13 ug/l
103-65-1 n-Propylbenzene 0.44 0.50 0.13 ug/l J
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol 64.0 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether 4.8 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 1.7 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene 1.8 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene 7.6 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 6.3 1.0 0.13 ug/l
95-47-6 o-Xylene 24.9 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 97%98%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%102%70-130%
2037-26-5 Toluene-D8 101%100%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
34 of 81
FC1119933.6
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 3 of 3
Client Sample ID:MW-7
Lab Sample ID:FC11199-6 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 99%99%70-130%
(a) Confirmation run beyond holdtime.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
35 of 81
FC1119933.6
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 1
Client Sample ID:MW-7
Lab Sample ID:FC11199-6 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL86480.D 1 11/21/23 13:48 SS n/a n/a GLL2995
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane 6.3 0.50 0.16 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
36 of 81
FC1119933.6
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 1
Client Sample ID:MW-7
Lab Sample ID:FC11199-6 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a 0.12 0.10 mg/l 1 11/15/23 12:30 FN SM3500FE B-11
Nitrogen, Nitrate 0.21 0.10 mg/l 1 11/15/23 13:30 JR EPA 300/SW846 9056A
Sulfate <2.0 2.0 mg/l 1 11/15/23 00:41 JR EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
RL = Reporting Limit
37 of 81
FC1119933.6
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 3
Client Sample ID:MW-8
Lab Sample ID:FC11199-7 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A4438.D 1 11/18/23 02:21 TD n/a n/a V3A212
Run #2 3A4522.D 1 11/22/23 20:09 TD n/a n/a V3A215
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND a 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane b ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
38 of 81
FC1119933.7
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 2 of 3
Client Sample ID:MW-8
Lab Sample ID:FC11199-7 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene 0.23 0.50 0.13 ug/l J
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate c ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene 0.26 0.50 0.13 ug/l J
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 100%97%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%101%70-130%
2037-26-5 Toluene-D8 100%100%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
39 of 81
FC1119933.7
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 3 of 3
Client Sample ID:MW-8
Lab Sample ID:FC11199-7 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 99%100%70-130%
(a) Result is from Run# 2
(b) Associated ICV outside control limits high, however sample ND.
(c) Associated BS recovery outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
40 of 81
FC1119933.7
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 1
Client Sample ID:MW-8
Lab Sample ID:FC11199-7 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL86481.D 1 11/21/23 13:56 SS n/a n/a GLL2995
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane 0.18 0.50 0.16 ug/l J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
41 of 81
FC1119933.7
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 1
Client Sample ID:MW-8
Lab Sample ID:FC11199-7 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a 5.6 0.50 mg/l 5 11/15/23 12:30 FN SM3500FE B-11
Nitrogen, Nitrate b 2.7 0.10 mg/l 1 11/15/23 13:50 JR EPA 300/SW846 9056A
Sulfate 3.5 2.0 mg/l 1 11/15/23 01:01 JR EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
(b) Originally ran in hold. Re-run out of hold due to CCV failure.
RL = Reporting Limit
42 of 81
FC1119933.7
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 3
Client Sample ID:TW-1
Lab Sample ID:FC11199-8 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A4523.D 1 11/22/23 20:33 TD n/a n/a V3A215
Run #2 a 3A4578.D 1 11/28/23 21:24 TD n/a n/a V3A218
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 0.43 0.50 0.13 ug/l J
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene 1.3 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene 0.37 0.50 0.13 ug/l J
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
43 of 81
FC1119933.8
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 2 of 3
Client Sample ID:TW-1
Lab Sample ID:FC11199-8 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene 1.8 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 0.34 0.50 0.13 ug/l J
99-87-6 p-Isopropyltoluene 0.36 0.50 0.13 ug/l J
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 0.38 0.50 0.13 ug/l J
91-20-3 Naphthalene 21.9 0.50 0.13 ug/l
103-65-1 n-Propylbenzene 1.8 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 1.8 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene 30.7 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene 7.0 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 8.8 1.0 0.13 ug/l
95-47-6 o-Xylene 5.4 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 96%96%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%102%70-130%
2037-26-5 Toluene-D8 101%99%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FC1119933.8
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Report of Analysis Page 3 of 3
Client Sample ID:TW-1
Lab Sample ID:FC11199-8 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 99%100%70-130%
(a) Confirmation run beyond holdtime.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FC1119933.8
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 1
Client Sample ID:TW-1
Lab Sample ID:FC11199-8 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL86482.D 1 11/21/23 14:03 SS n/a n/a GLL2995
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane 19.5 0.50 0.16 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FC1119933.8
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 1
Client Sample ID:TW-1
Lab Sample ID:FC11199-8 Date Sampled:11/13/23
Matrix:AQ - Ground Water Date Received:11/14/23
Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a <0.10 0.10 mg/l 1 11/15/23 12:30 FN SM3500FE B-11
Nitrogen, Nitrate <0.10 0.10 mg/l 1 11/15/23 01:22 JR EPA 300/SW846 9056A
Sulfate 5.9 2.0 mg/l 1 11/15/23 01:22 JR EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
RL = Reporting Limit
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FC1119933.8
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 1 of 2
Client Sample ID:TB
Lab Sample ID:FC11199-9 Date Sampled:11/13/23
Matrix:AQ - Trip Blank Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A4440.D 1 11/18/23 03:08 TD n/a n/a V3A212
Run #2 3A4524.D 1 11/22/23 20:57 TD n/a n/a V3A215
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND a 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane b ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FC1119933.9
SGS LabLink@06:43 01-Dec-2023
Report of Analysis Page 2 of 2
Client Sample ID:TB
Lab Sample ID:FC11199-9 Date Sampled:11/13/23
Matrix:AQ - Trip Blank Water Date Received:11/14/23
Method:SM 6200B Percent Solids:n/a
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 99%95%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%100%70-130%
2037-26-5 Toluene-D8 100%100%70-130%
460-00-4 4-Bromofluorobenzene 97%100%70-130%
(a) Result is from Run# 2
(b) Associated ICV outside control limits high, however sample ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
49 of 81
FC1119933.9
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Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Orlando, FL
Section 4
50 of 81
FC111994
FC11199: Chain of Custody
Page 1 of 2
51 of 81
FC1119944.1
Job Number:fc11199 Client:GRI
Date / Time Received:11/14/2023 9:15:00 AM Delivery Method:FED EX
Project:5991
Airbill #'s:6840 3320 1610
Cooler Information
1. Custody Seals Present:
Y or N
2. Custody Seals Intact:
4. Cooler temp verification:
3. Temp criteria achieved:
5. Cooler media:
IR Gun
Ice (Bag)
Trip Blank Information Y or N N/A
1. Trip Blank present / cooler:
2. Trip Blank listed on COC:
Sample Information
1. Sample labels present on bottles:
2. Samples presented properly
3. Suffiient volume/containers recv'd for analysis
4. Condition of sample:
5. Sample recv'd within HT
6. Dates/Times/IDs on COC match sample label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
Intact
Comments
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (2.2);
Cooler 1: (2.6);
SM001Rev. Date 05/04/17
SGS Sample Receipt Summary
Test Strip Lot #s:pH 0-3:226422 pH 10-12:Other: (Specify)pH 1.0 - 12.0 222221
3. Type of TB Received
W or S N/A
Y or N N/A
11. % Solids Jar Received?
12. Residual Chlorine Present?
Misc Information
Number of Encores:25 Gram 5 Gram
Residual Chlorine Test Strip Lot #
Number of Lab Filtered Metals:
Technician:SHAYLAP Date:11/14/2023 10:52:01 AM Reviewer:Date:
FC11199: Chain of Custody
Page 2 of 2
52 of 81
FC1119944.1
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MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
53 of 81
FC111995
Method Blank Summary Page 1 of 3
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A212-MB 3A4431.D 1 11/17/23 TD n/a n/a V3A212
The QC reported here applies to the following samples:Method: SM 6200B
FC11199-2, FC11199-7, FC11199-9
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
54 of 81
FC1119955.1.1
Method Blank Summary Page 2 of 3
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A212-MB 3A4431.D 1 11/17/23 TD n/a n/a V3A212
The QC reported here applies to the following samples:Method: SM 6200B
FC11199-2, FC11199-7, FC11199-9
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride 1.0 2.0 1.0 ug/l J
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 101%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%70-130%
2037-26-5 Toluene-D8 99%70-130%
55 of 81
FC1119955.1.1
Method Blank Summary Page 3 of 3
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A212-MB 3A4431.D 1 11/17/23 TD n/a n/a V3A212
The QC reported here applies to the following samples:Method: SM 6200B
FC11199-2, FC11199-7, FC11199-9
CAS No.Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 98%70-130%
56 of 81
FC1119955.1.1
Method Blank Summary Page 1 of 3
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A215-MB 3A4511.D 1 11/22/23 TD n/a n/a V3A215
The QC reported here applies to the following samples:Method: SM 6200B
FC11199-1, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-8
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
57 of 81
FC1119955.1.2
Method Blank Summary Page 2 of 3
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A215-MB 3A4511.D 1 11/22/23 TD n/a n/a V3A215
The QC reported here applies to the following samples:Method: SM 6200B
FC11199-1, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-8
CAS No.Compound Result RL MDL Units Q
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 98%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%70-130%
58 of 81
FC1119955.1.2
Method Blank Summary Page 3 of 3
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A215-MB 3A4511.D 1 11/22/23 TD n/a n/a V3A215
The QC reported here applies to the following samples:Method: SM 6200B
FC11199-1, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-8
CAS No.Surrogate Recoveries Limits
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 100%70-130%
59 of 81
FC1119955.1.2
Blank Spike Summary Page 1 of 3
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A212-BS 3A4429.D 1 11/17/23 TD n/a n/a V3A212
The QC reported here applies to the following samples:Method: SM 6200B
FC11199-2, FC11199-7, FC11199-9
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 9.5 95 70-130
108-86-1 Bromobenzene 10 9.8 98 70-130
74-97-5 Bromochloromethane 10 9.8 98 70-130
75-27-4 Bromodichloromethane 10 8.7 87 70-130
75-25-2 Bromoform 10 9.4 94 70-130
104-51-8 n-Butylbenzene 10 9.2 92 70-130
135-98-8 sec-Butylbenzene 10 8.8 88 70-130
98-06-6 tert-Butylbenzene 10 9.2 92 70-130
56-23-5 Carbon Tetrachloride 10 9.1 91 70-130
108-90-7 Chlorobenzene 10 9.3 93 70-130
67-66-3 Chloroform 10 9.7 97 70-130
95-49-8 o-Chlorotoluene 10 9.3 93 70-130
106-43-4 p-Chlorotoluene 10 9.1 91 70-130
124-48-1 Dibromochloromethane 10 9.6 96 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 8.8 88 70-130
106-93-4 1,2-Dibromoethane 10 9.6 96 70-130
75-71-8 Dichlorodifluoromethane 10 12.6 126 60-140
95-50-1 1,2-Dichlorobenzene 10 9.2 92 70-130
541-73-1 1,3-Dichlorobenzene 10 9.1 91 70-130
106-46-7 1,4-Dichlorobenzene 10 9.2 92 70-130
75-34-3 1,1-Dichloroethane 10 9.0 90 70-130
107-06-2 1,2-Dichloroethane 10 9.4 94 70-130
75-35-4 1,1-Dichloroethylene 10 9.2 92 70-130
156-59-2 cis-1,2-Dichloroethylene 10 9.6 96 70-130
156-60-5 trans-1,2-Dichloroethylene 10 9.2 92 70-130
78-87-5 1,2-Dichloropropane 10 9.7 97 70-130
142-28-9 1,3-Dichloropropane 10 10.1 101 70-130
594-20-7 2,2-Dichloropropane 10 9.0 90 70-130
563-58-6 1,1-Dichloropropene 10 9.8 98 70-130
10061-01-5 cis-1,3-Dichloropropene 10 9.1 91 70-130
10061-02-6 trans-1,3-Dichloropropene 10 8.6 86 70-130
108-20-3 Di-Isopropyl Ether 10 9.3 93 70-130
100-41-4 Ethylbenzene 10 9.4 94 70-130
637-92-3 Ethyl Tert Butyl Ether 10 9.9 99 70-130
87-68-3 Hexachlorobutadiene 10 9.3 93 70-130
98-82-8 Isopropylbenzene 10 9.3 93 70-130
* = Outside of Control Limits.
60 of 81
FC1119955.2.1
Blank Spike Summary Page 2 of 3
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A212-BS 3A4429.D 1 11/17/23 TD n/a n/a V3A212
The QC reported here applies to the following samples:Method: SM 6200B
FC11199-2, FC11199-7, FC11199-9
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 9.0 90 70-130
74-83-9 Methyl Bromide 10 10.4 104 60-140
74-87-3 Methyl Chloride 10 9.7 97 60-140
74-95-3 Methylene Bromide 10 9.7 97 70-130
75-09-2 Methylene Chloride 10 11.1 111 70-130
1634-04-4 Methyl Tert Butyl Ether 10 9.9 99 70-130
91-20-3 Naphthalene 10 8.9 89 70-130
103-65-1 n-Propylbenzene 10 9.2 92 70-130
100-42-5 Styrene 10 9.2 92 70-130
75-85-4 Tert-Amyl Alcohol 100 91.7 92 70-130
994-05-8 Tert-Amyl Methyl Ether 10 9.6 96 70-130
75-65-0 Tert-Butyl Alcohol 100 112 112 70-130
762-75-4 Tert-Butyl Formate 50 66.5 133*70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 8.7 87 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 9.0 90 70-130
127-18-4 Tetrachloroethylene 10 9.7 97 70-130
108-88-3 Toluene 10 9.5 95 70-130
87-61-6 1,2,3-Trichlorobenzene 10 9.3 93 70-130
120-82-1 1,2,4-Trichlorobenzene 10 9.0 90 70-130
71-55-6 1,1,1-Trichloroethane 10 9.7 97 70-130
79-00-5 1,1,2-Trichloroethane 10 9.3 93 70-130
79-01-6 Trichloroethylene 10 9.5 95 70-130
75-69-4 Trichlorofluoromethane 10 7.1 71 60-140
96-18-4 1,2,3-Trichloropropane 10 9.9 99 70-130
95-63-6 1,2,4-Trimethylbenzene 10 9.2 92 70-130
108-67-8 1,3,5-Trimethylbenzene 10 9.4 94 70-130
75-01-4 Vinyl Chloride 10 9.6 96 60-140
m,p-Xylene 20 18.9 95 70-130
95-47-6 o-Xylene 10 9.1 91 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 100%70-130%
17060-07-0 1,2-Dichloroethane-D4 98%70-130%
2037-26-5 Toluene-D8 100%70-130%
* = Outside of Control Limits.
61 of 81
FC1119955.2.1
Blank Spike Summary Page 3 of 3
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A212-BS 3A4429.D 1 11/17/23 TD n/a n/a V3A212
The QC reported here applies to the following samples:Method: SM 6200B
FC11199-2, FC11199-7, FC11199-9
CAS No.Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 98%70-130%
* = Outside of Control Limits.
62 of 81
FC1119955.2.1
Blank Spike Summary Page 1 of 3
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A215-BS 3A4508.D 1 11/22/23 TD n/a n/a V3A215
The QC reported here applies to the following samples:Method: SM 6200B
FC11199-1, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-8
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.1 101 70-130
108-86-1 Bromobenzene 10 10.4 104 70-130
74-97-5 Bromochloromethane 10 10.3 103 70-130
75-27-4 Bromodichloromethane 10 9.1 91 70-130
75-25-2 Bromoform 10 9.4 94 70-130
104-51-8 n-Butylbenzene 10 11.3 113 70-130
135-98-8 sec-Butylbenzene 10 10.3 103 70-130
98-06-6 tert-Butylbenzene 10 10.4 104 70-130
56-23-5 Carbon Tetrachloride 10 9.7 97 70-130
108-90-7 Chlorobenzene 10 10.1 101 70-130
75-00-3 Chloroethane 10 11.7 117 60-140
67-66-3 Chloroform 10 10.2 102 70-130
95-49-8 o-Chlorotoluene 10 10.3 103 70-130
106-43-4 p-Chlorotoluene 10 10.2 102 70-130
124-48-1 Dibromochloromethane 10 10 100 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 9.9 99 70-130
106-93-4 1,2-Dibromoethane 10 10.3 103 70-130
75-71-8 Dichlorodifluoromethane 10 13.1 131 60-140
95-50-1 1,2-Dichlorobenzene 10 10.2 102 70-130
541-73-1 1,3-Dichlorobenzene 10 9.8 98 70-130
106-46-7 1,4-Dichlorobenzene 10 10.1 101 70-130
75-34-3 1,1-Dichloroethane 10 9.7 97 70-130
107-06-2 1,2-Dichloroethane 10 9.8 98 70-130
75-35-4 1,1-Dichloroethylene 10 10.0 100 70-130
156-59-2 cis-1,2-Dichloroethylene 10 10 100 70-130
156-60-5 trans-1,2-Dichloroethylene 10 10.3 103 70-130
78-87-5 1,2-Dichloropropane 10 10.5 105 70-130
142-28-9 1,3-Dichloropropane 10 10.9 109 70-130
594-20-7 2,2-Dichloropropane 10 11.0 110 70-130
563-58-6 1,1-Dichloropropene 10 10.7 107 70-130
10061-01-5 cis-1,3-Dichloropropene 10 10.4 104 70-130
10061-02-6 trans-1,3-Dichloropropene 10 9.2 92 70-130
108-20-3 Di-Isopropyl Ether 10 10.2 102 70-130
100-41-4 Ethylbenzene 10 10.1 101 70-130
637-92-3 Ethyl Tert Butyl Ether 10 10.7 107 70-130
87-68-3 Hexachlorobutadiene 10 11.3 113 70-130
* = Outside of Control Limits.
63 of 81
FC1119955.2.2
Blank Spike Summary Page 2 of 3
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A215-BS 3A4508.D 1 11/22/23 TD n/a n/a V3A215
The QC reported here applies to the following samples:Method: SM 6200B
FC11199-1, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-8
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
98-82-8 Isopropylbenzene 10 10.4 104 70-130
99-87-6 p-Isopropyltoluene 10 10.6 106 70-130
74-83-9 Methyl Bromide 10 14.8 148*60-140
74-87-3 Methyl Chloride 10 11.0 110 60-140
74-95-3 Methylene Bromide 10 10.3 103 70-130
75-09-2 Methylene Chloride 10 10 100 70-130
1634-04-4 Methyl Tert Butyl Ether 10 10.6 106 70-130
91-20-3 Naphthalene 10 10.6 106 70-130
103-65-1 n-Propylbenzene 10 10.3 103 70-130
100-42-5 Styrene 10 9.7 97 70-130
75-85-4 Tert-Amyl Alcohol 100 117 117 70-130
994-05-8 Tert-Amyl Methyl Ether 10 10.6 106 70-130
75-65-0 Tert-Butyl Alcohol 100 116 116 70-130
762-75-4 Tert-Butyl Formate 50 71.3 143*70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 9.6 96 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 10.2 102 70-130
127-18-4 Tetrachloroethylene 10 10.5 105 70-130
108-88-3 Toluene 10 10.4 104 70-130
87-61-6 1,2,3-Trichlorobenzene 10 10.6 106 70-130
120-82-1 1,2,4-Trichlorobenzene 10 10.8 108 70-130
71-55-6 1,1,1-Trichloroethane 10 10.4 104 70-130
79-00-5 1,1,2-Trichloroethane 10 10.1 101 70-130
79-01-6 Trichloroethylene 10 10.2 102 70-130
75-69-4 Trichlorofluoromethane 10 12.1 121 60-140
96-18-4 1,2,3-Trichloropropane 10 10.5 105 70-130
95-63-6 1,2,4-Trimethylbenzene 10 10.6 106 70-130
108-67-8 1,3,5-Trimethylbenzene 10 10.7 107 70-130
75-01-4 Vinyl Chloride 10 12.0 120 60-140
m,p-Xylene 20 21.2 106 70-130
95-47-6 o-Xylene 10 10.2 102 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 100%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%70-130%
* = Outside of Control Limits.
64 of 81
FC1119955.2.2
Blank Spike Summary Page 3 of 3
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A215-BS 3A4508.D 1 11/22/23 TD n/a n/a V3A215
The QC reported here applies to the following samples:Method: SM 6200B
FC11199-1, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-8
CAS No.Surrogate Recoveries BSP Limits
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 99%70-130%
* = Outside of Control Limits.
65 of 81
FC1119955.2.2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC11199-1MS 3A4450.D 25 11/18/23 TD n/a n/a V3A212
FC11199-1MSD 3A4451.D 25 11/18/23 TD n/a n/a V3A212
FC11199-1 a 3A4432.D 25 11/17/23 TD n/a n/a V3A212
The QC reported here applies to the following samples:Method: SM 6200B
FC11199-2, FC11199-7, FC11199-9
FC11199-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene ND 250 1200 480*250 1210 484*1 70-130/20
108-86-1 Bromobenzene ND 250 260 104 250 258 103 1 70-130/20
74-97-5 Bromochloromethane ND 250 249 100 250 244 98 2 70-130/20
75-27-4 Bromodichloromethane ND 250 208 83 250 214 86 3 70-130/20
75-25-2 Bromoform ND 250 211 84 250 225 90 6 70-130/20
104-51-8 n-Butylbenzene ND 250 257 103 250 264 106 3 70-130/20
135-98-8 sec-Butylbenzene ND 250 252 101 250 253 101 0 70-130/20
98-06-6 tert-Butylbenzene ND 250 248 99 250 251 100 1 70-130/20
56-23-5 Carbon Tetrachloride ND 250 225 90 250 231 92 3 70-130/20
108-90-7 Chlorobenzene ND 250 251 100 250 250 100 0 70-130/20
67-66-3 Chloroform 8.3 J 250 257 99 250 258 100 0 70-130/20
95-49-8 o-Chlorotoluene ND 250 286 114 250 287 115 0 70-130/20
106-43-4 p-Chlorotoluene ND 250 239 96 250 241 96 1 70-130/20
124-48-1 Dibromochloromethane ND 250 224 90 250 234 94 4 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 250 211 84 250 216 86 2 70-130/20
106-93-4 1,2-Dibromoethane ND 250 242 97 250 245 98 1 70-130/20
75-71-8 Dichlorodifluoromethane ND 250 342 137 250 378 151*10 60-140/20
95-50-1 1,2-Dichlorobenzene ND 250 244 98 250 240 96 2 70-130/20
541-73-1 1,3-Dichlorobenzene ND 250 243 97 250 244 98 0 70-130/20
106-46-7 1,4-Dichlorobenzene ND 250 240 96 250 240 96 0 70-130/20
75-34-3 1,1-Dichloroethane ND 250 236 94 250 234 94 1 70-130/20
107-06-2 1,2-Dichloroethane ND 250 236 94 250 235 94 0 70-130/20
75-35-4 1,1-Dichloroethylene ND 250 253 101 250 250 100 1 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 250 248 99 250 248 99 0 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 250 246 98 250 245 98 0 70-130/20
78-87-5 1,2-Dichloropropane ND 250 250 100 250 251 100 0 70-130/20
142-28-9 1,3-Dichloropropane ND 250 258 103 250 260 104 1 70-130/20
594-20-7 2,2-Dichloropropane ND 250 191 76 250 192 77 1 70-130/20
563-58-6 1,1-Dichloropropene ND 250 263 105 250 265 106 1 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 250 216 86 250 223 89 3 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 250 203 81 250 208 83 2 70-130/20
108-20-3 Di-Isopropyl Ether 5.0 J 250 251 98 250 247 97 2 70-130/20
100-41-4 Ethylbenzene 8.4 J 250 926 367*250 942 373*2 70-130/20
637-92-3 Ethyl Tert Butyl Ether ND 250 248 99 250 246 98 1 70-130/20
87-68-3 Hexachlorobutadiene ND 250 251 100 250 256 102 2 70-130/20
98-82-8 Isopropylbenzene ND 250 288 115 250 293 117 2 70-130/20
* = Outside of Control Limits.
66 of 81
FC1119955.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC11199-1MS 3A4450.D 25 11/18/23 TD n/a n/a V3A212
FC11199-1MSD 3A4451.D 25 11/18/23 TD n/a n/a V3A212
FC11199-1 a 3A4432.D 25 11/17/23 TD n/a n/a V3A212
The QC reported here applies to the following samples:Method: SM 6200B
FC11199-2, FC11199-7, FC11199-9
FC11199-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene ND 250 254 102 250 255 102 0 70-130/20
74-83-9 Methyl Bromide ND 250 229 92 250 261 104 13 60-140/20
74-87-3 Methyl Chloride ND 250 263 105 250 291 116 10 60-140/20
74-95-3 Methylene Bromide ND 250 239 96 250 243 97 2 70-130/20
75-09-2 Methylene Chloride ND 250 282 113 250 289 116 2 70-130/20
1634-04-4 Methyl Tert Butyl Ether 1100 250 1730 252* b 250 1750 260* b 1 70-130/20
91-20-3 Naphthalene 13.4 250 337 129 250 344 132*2 70-130/20
103-65-1 n-Propylbenzene ND 250 332 133*250 338 135*2 70-130/20
100-42-5 Styrene ND 250 250 100 250 250 100 0 70-130/20
75-85-4 Tert-Amyl Alcohol ND 2500 4010 160*2500 4010 160*0 70-130/20
994-05-8 Tert-Amyl Methyl Ether 16.1 J 250 371 142*250 376 144*1 70-130/20
75-65-0 Tert-Butyl Alcohol ND 2500 3520 141*2500 3580 143*2 70-130/20
762-75-4 Tert-Butyl Formate ND 1250 1580 126 1250 1970 158*22*70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 250 217 87 250 226 90 4 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 250 235 94 250 233 93 1 70-130/20
127-18-4 Tetrachloroethylene ND 250 267 107 250 272 109 2 70-130/20
108-88-3 Toluene 9.3 J 250 428 167*250 432 169*1 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 250 240 96 250 245 98 2 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 250 239 96 250 240 96 0 70-130/20
71-55-6 1,1,1-Trichloroethane ND 250 249 100 250 253 101 2 70-130/20
79-00-5 1,1,2-Trichloroethane ND 250 242 97 250 244 98 1 70-130/20
79-01-6 Trichloroethylene ND 250 250 100 250 253 101 1 70-130/20
75-69-4 Trichlorofluoromethane ND 250 189 76 250 212 85 11 60-140/20
96-18-4 1,2,3-Trichloropropane ND 250 254 102 250 248 99 2 70-130/20
95-63-6 1,2,4-Trimethylbenzene 15.8 250 512 198*250 518 201*1 70-130/20
108-67-8 1,3,5-Trimethylbenzene 7.1 J 250 584 231*250 592 234*1 70-130/20
75-01-4 Vinyl Chloride ND 250 259 104 250 286 114 10 60-140/20
m,p-Xylene 18.8 J 500 859 168*500 869 170*1 70-130/20
95-47-6 o-Xylene 9.0 J 250 502 197*250 512 201*2 70-130/20
CAS No.Surrogate Recoveries MS MSD FC11199-1 Limits
1868-53-7 Dibromofluoromethane 98%98%70-130%
17060-07-0 1,2-Dichloroethane-D4 98%96%70-130%
2037-26-5 Toluene-D8 101%101%70-130%
* = Outside of Control Limits.
67 of 81
FC1119955.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC11199-1MS 3A4450.D 25 11/18/23 TD n/a n/a V3A212
FC11199-1MSD 3A4451.D 25 11/18/23 TD n/a n/a V3A212
FC11199-1 a 3A4432.D 25 11/17/23 TD n/a n/a V3A212
The QC reported here applies to the following samples:Method: SM 6200B
FC11199-2, FC11199-7, FC11199-9
CAS No.Surrogate Recoveries MS MSD FC11199-1 Limits
460-00-4 4-Bromofluorobenzene 97%97%70-130%
(a) Sample used for QC purposes only.
(b) Outside control limits due to high level in sample relative to spike amount.
* = Outside of Control Limits.
68 of 81
FC1119955.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC11199-2MS 3A4525.D 5 11/22/23 TD n/a n/a V3A215
FC11199-2MSD 3A4526.D 5 11/22/23 TD n/a n/a V3A215
FC11199-2 a 3A4517.D 1 11/22/23 TD n/a n/a V3A215
The QC reported here applies to the following samples:Method: SM 6200B
FC11199-1, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-8
FC11199-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene ND 50 51.5 103 50 53.9 108 5 70-130/20
108-86-1 Bromobenzene ND 50 51.8 104 50 52.8 106 2 70-130/20
74-97-5 Bromochloromethane ND 50 50.6 101 50 53.0 106 5 70-130/20
75-27-4 Bromodichloromethane ND 50 42.8 86 50 45.2 90 5 70-130/20
75-25-2 Bromoform ND 50 39.0 78 50 41.4 83 6 70-130/20
104-51-8 n-Butylbenzene ND 50 54.0 108 50 57.0 114 5 70-130/20
135-98-8 sec-Butylbenzene ND 50 51.6 103 50 53.4 107 3 70-130/20
98-06-6 tert-Butylbenzene ND 50 53.0 106 50 55.2 110 4 70-130/20
56-23-5 Carbon Tetrachloride ND 50 46.8 94 50 49.2 98 5 70-130/20
108-90-7 Chlorobenzene ND 50 49.7 99 50 52.7 105 6 70-130/20
75-00-3 Chloroethane ND 50 44.2 88 50 56.5 113 24*60-140/20
67-66-3 Chloroform ND 50 51.0 102 50 53.1 106 4 70-130/20
95-49-8 o-Chlorotoluene ND 50 52.0 104 50 53.5 107 3 70-130/20
106-43-4 p-Chlorotoluene ND 50 50.7 101 50 52.3 105 3 70-130/20
124-48-1 Dibromochloromethane ND 50 43.4 87 50 46.0 92 6 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 50 41.3 83 50 43.4 87 5 70-130/20
106-93-4 1,2-Dibromoethane ND 50 49.2 98 50 50.9 102 3 70-130/20
75-71-8 Dichlorodifluoromethane ND 50 53.1 106 50 64.3 129 19 60-140/20
95-50-1 1,2-Dichlorobenzene ND 50 48.8 98 50 50.2 100 3 70-130/20
541-73-1 1,3-Dichlorobenzene ND 50 48.3 97 50 50.5 101 4 70-130/20
106-46-7 1,4-Dichlorobenzene ND 50 49.0 98 50 51.2 102 4 70-130/20
75-34-3 1,1-Dichloroethane ND 50 50.0 100 50 52.0 104 4 70-130/20
107-06-2 1,2-Dichloroethane ND 50 48.9 98 50 51.4 103 5 70-130/20
75-35-4 1,1-Dichloroethylene ND 50 52.4 105 50 54.9 110 5 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 50 51.2 102 50 52.2 104 2 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 50 52.1 104 50 54.6 109 5 70-130/20
78-87-5 1,2-Dichloropropane ND 50 52.9 106 50 55.5 111 5 70-130/20
142-28-9 1,3-Dichloropropane ND 50 53.7 107 50 55.3 111 3 70-130/20
594-20-7 2,2-Dichloropropane ND 50 48.0 96 50 50.7 101 5 70-130/20
563-58-6 1,1-Dichloropropene ND 50 54.8 110 50 57.6 115 5 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 50 47.0 94 50 49.1 98 4 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 50 40.5 81 50 42.6 85 5 70-130/20
108-20-3 Di-Isopropyl Ether ND 50 51.1 102 50 53.2 106 4 70-130/20
100-41-4 Ethylbenzene ND 50 51.6 103 50 53.8 108 4 70-130/20
637-92-3 Ethyl Tert Butyl Ether ND 50 52.5 105 50 55.1 110 5 70-130/20
87-68-3 Hexachlorobutadiene ND 50 52.7 105 50 56.9 114 8 70-130/20
* = Outside of Control Limits.
69 of 81
FC1119955.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC11199-2MS 3A4525.D 5 11/22/23 TD n/a n/a V3A215
FC11199-2MSD 3A4526.D 5 11/22/23 TD n/a n/a V3A215
FC11199-2 a 3A4517.D 1 11/22/23 TD n/a n/a V3A215
The QC reported here applies to the following samples:Method: SM 6200B
FC11199-1, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-8
FC11199-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
98-82-8 Isopropylbenzene ND 50 52.7 105 50 55.3 111 5 70-130/20
99-87-6 p-Isopropyltoluene ND 50 52.7 105 50 54.4 109 3 70-130/20
74-83-9 Methyl Bromide ND 50 45.7 91 50 56.9 114 22*60-140/20
74-87-3 Methyl Chloride ND 50 43.6 87 50 52.0 104 18 60-140/20
74-95-3 Methylene Bromide ND 50 49.0 98 50 50.6 101 3 70-130/20
75-09-2 Methylene Chloride ND 50 51.8 104 50 53.2 106 3 70-130/20
1634-04-4 Methyl Tert Butyl Ether ND 50 51.4 103 50 53.9 108 5 70-130/20
91-20-3 Naphthalene ND 50 48.5 97 50 50.3 101 4 70-130/20
103-65-1 n-Propylbenzene ND 50 52.3 105 50 54.8 110 5 70-130/20
100-42-5 Styrene ND 50 46.7 93 50 49.4 99 6 70-130/20
75-85-4 Tert-Amyl Alcohol ND 500 466 93 500 488 98 5 70-130/20
994-05-8 Tert-Amyl Methyl Ether ND 50 50.6 101 50 52.5 105 4 70-130/20
75-65-0 Tert-Butyl Alcohol ND 500 589 118 500 644 129 9 70-130/20
762-75-4 Tert-Butyl Formate ND 250 134 54*250 158 63*16 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 50 44.4 89 50 46.9 94 5 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 50 48.7 97 50 50.4 101 3 70-130/20
127-18-4 Tetrachloroethylene ND 50 52.1 104 50 55.8 112 7 70-130/20
108-88-3 Toluene ND 50 52.0 104 50 54.3 109 4 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 50 49.0 98 50 50.5 101 3 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 50 49.3 99 50 51.1 102 4 70-130/20
71-55-6 1,1,1-Trichloroethane ND 50 52.7 105 50 55.0 110 4 70-130/20
79-00-5 1,1,2-Trichloroethane ND 50 48.7 97 50 50.3 101 3 70-130/20
79-01-6 Trichloroethylene ND 50 50.0 100 50 52.6 105 5 70-130/20
75-69-4 Trichlorofluoromethane ND 50 45.2 90 50 56.4 113 22*60-140/20
96-18-4 1,2,3-Trichloropropane ND 50 50.0 100 50 52.3 105 4 70-130/20
95-63-6 1,2,4-Trimethylbenzene ND 50 52.1 104 50 54.4 109 4 70-130/20
108-67-8 1,3,5-Trimethylbenzene ND 50 54.0 108 50 56.0 112 4 70-130/20
75-01-4 Vinyl Chloride ND 50 49.0 98 50 59.5 119 19 60-140/20
m,p-Xylene ND 100 106 106 100 111 111 5 70-130/20
95-47-6 o-Xylene ND 50 50.9 102 50 53.4 107 5 70-130/20
CAS No.Surrogate Recoveries MS MSD FC11199-2 Limits
1868-53-7 Dibromofluoromethane 99%99%97%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%101%101%70-130%
* = Outside of Control Limits.
70 of 81
FC1119955.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC11199-2MS 3A4525.D 5 11/22/23 TD n/a n/a V3A215
FC11199-2MSD 3A4526.D 5 11/22/23 TD n/a n/a V3A215
FC11199-2 a 3A4517.D 1 11/22/23 TD n/a n/a V3A215
The QC reported here applies to the following samples:Method: SM 6200B
FC11199-1, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-8
CAS No.Surrogate Recoveries MS MSD FC11199-2 Limits
2037-26-5 Toluene-D8 100%101%100%70-130%
460-00-4 4-Bromofluorobenzene 100%100%100%70-130%
(a) Sample vial(s) contained bubbles greater than 6mm.
* = Outside of Control Limits.
71 of 81
FC1119955.3.2
SGS LabLink@06:43 01-Dec-2023
GC Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 6
72 of 81
FC111996
Method Blank Summary Page 1 of 1
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GLL2995-MB LL86461.D 1 11/21/23 SS n/a n/a GLL2995
The QC reported here applies to the following samples:Method: RSKSOP-147/175
FC11199-1, FC11199-2, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-7, FC11199-8
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane ND 0.50 0.16 ug/l
73 of 81
FC1119966.1.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GLL2995-BS LL86458.D 1 11/21/23 SS n/a n/a GLL2995
GLL2995-BSD LL86459.D 1 11/21/23 SS n/a n/a GLL2995
The QC reported here applies to the following samples:Method: RSKSOP-147/175
FC11199-1, FC11199-2, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-7, FC11199-8
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
74-82-8 Methane 108 116 107 121 112 4 62-139/30
* = Outside of Control Limits.
74 of 81
FC1119966.2.1
Matrix Spike Summary Page 1 of 1
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC11170-2MS LL86470.D 1 11/21/23 SS n/a n/a GLL2995
FC11170-2 LL86468.D 1 11/21/23 SS n/a n/a GLL2995
The QC reported here applies to the following samples:Method: RSKSOP-147/175
FC11199-1, FC11199-2, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-7, FC11199-8
FC11170-2 Spike MS MS
CAS No.Compound ug/l Q ug/l ug/l %Limits
74-82-8 Methane 42.8 108 168 116 62-139
* = Outside of Control Limits.
75 of 81
FC1119966.3.1
Duplicate Summary Page 1 of 1
Job Number:FC11199
Account:GRINCC GRI (Geological Resources Inc.)
Project:Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC11170-2DUP LL86469.D 1 11/21/23 SS n/a n/a GLL2995
FC11170-2 LL86468.D 1 11/21/23 SS n/a n/a GLL2995
The QC reported here applies to the following samples:Method: RSKSOP-147/175
FC11199-1, FC11199-2, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-7, FC11199-8
FC11170-2 DUP
CAS No.Compound ug/l Q ug/l Q RPD Limits
74-82-8 Methane 42.8 46.2 8 30
* = Outside of Control Limits.
76 of 81
FC1119966.4.1
SGS LabLink@06:43 01-Dec-2023
General Chemistry
QC Data Summaries
Includes the following where applicable:
• Method Blank and Blank Spike Summaries
• Duplicate Summaries
• Matrix Spike Summaries
Orlando, FL
Section 7
77 of 81
FC111997
METHOD BLANK AND SPIKE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: FC11199
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
MB Spike BSP BSP QC
Analyte Batch ID RL Result Units Amount Result %Recov Limits
Chloride GP39376/GN95899 2.0 0.0 mg/l 50 51.3 102.6 90-110%
Chloride GP39377/GN95899 2.0 0.0 mg/l 50 51.9 103.8 90-110%
Chloride GP39382/GN95910 2.0 0.0 mg/l 50 52.0 104.0 90-110%
Iron, Ferrous GN95903 0.10 0.0 mg/l 0.500 0.51 101.0 82-115%
Nitrogen, Nitrate GP39376/GN95899 0.10 0.0 mg/l 2.5 2.46 98.4 90-110%
Nitrogen, Nitrate GP39377/GN95899 0.10 0.0 mg/l 2.5 2.48 99.2 90-110%
Nitrogen, Nitrate GP39382/GN95910 0.10 0.0 mg/l 2.5 2.49 99.6 90-110%
Nitrogen, Nitrite GP39376/GN95899 0.10 0.0 mg/l 2.5 2.55 102.0 90-110%
Nitrogen, Nitrite GP39377/GN95899 0.10 0.0 mg/l 2.5 2.60 104.0 90-110%
Nitrogen, Nitrite GP39382/GN95910 0.10 0.0 mg/l 2.5 2.60 104.0 90-110%
Sulfate GP39376/GN95899 2.0 0.0 mg/l 50 49.6 99.2 90-110%
Sulfate GP39377/GN95899 2.0 0.0 mg/l 50 49.8 99.6 90-110%
Sulfate GP39382/GN95910 2.0 0.0 mg/l 50 50.4 100.8 90-110%
Associated Samples:
Batch GN95903: FC11199-1, FC11199-2, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-7, FC11199-8
Batch GP39376: FC11199-1
Batch GP39377: FC11199-2, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-7, FC11199-8
Batch GP39382: FC11199-2, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-7
(*) Outside of QC limits
__________________________________________________________________________________________________________________________
Page 1
78 of 81
FC1119977.1
DUPLICATE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: FC11199
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
QC Original DUP QC
Analyte Batch ID Sample Units Result Result RPD Limits
Iron, Ferrous GN95903 FC11199-1 mg/l 3.2 3.1 1.4 0-31%
Associated Samples:
Batch GN95903: FC11199-1, FC11199-2, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-7, FC11199-8
(*) Outside of QC limits
__________________________________________________________________________________________________________________________
Page 1
79 of 81
FC1119977.2
MATRIX SPIKE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: FC11199
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
QC Original Spike MS QC
Analyte Batch ID Sample Units Result Amount Result %Rec Limits
Chloride GP39376/GN95899 FC11194-1 mg/l 3.9 50 55.3 102.8 90-110%
Chloride GP39377/GN95899 FC11199-4 mg/l 4.0 50 55.7 103.4 90-110%
Chloride GP39382/GN95910 FC11199-4 mg/l 4.0 50 55.3 102.6 90-110%
Nitrogen, Nitrate GP39376/GN95899 FC11194-1 mg/l 0.16 2.5 2.6 97.6 90-110%
Nitrogen, Nitrate GP39377/GN95899 FC11199-4 mg/l 3.7 2.5 5.7 80.0N(a) 90-110%
Nitrogen, Nitrate GP39382/GN95910 FC11199-4 mg/l 3.7 2.5 5.7 80.0N(a) 90-110%
Nitrogen, Nitrite GP39376/GN95899 FC11194-1 mg/l 0.040 U 2.5 2.6 104.0 90-110%
Nitrogen, Nitrite GP39377/GN95899 FC11199-4 mg/l 0.0 2.5 2.6 104.0 90-110%
Nitrogen, Nitrite GP39382/GN95910 FC11199-4 mg/l 0.0 2.5 2.6 104.0 90-110%
Sulfate GP39376/GN95899 FC11194-1 mg/l 9.6 50 58.4 97.6 90-110%
Sulfate GP39377/GN95899 FC11199-4 mg/l 0.0 50 52.7 105.4 90-110%
Sulfate GP39382/GN95910 FC11199-4 mg/l 0.0 50 52.0 104.0 90-110%
Associated Samples:
Batch GP39376: FC11199-1
Batch GP39377: FC11199-2, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-7, FC11199-8
Batch GP39382: FC11199-2, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-7
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(a) Spike recovery indicates possible matrix interference.
__________________________________________________________________________________________________________________________
Page 1
80 of 81
FC1119977.3
MATRIX SPIKE DUPLICATE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: FC11199
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Breeden's 66; 22900 Aberdeen Hwy, Laurinburg, NC
QC Original Spike MSD QC
Analyte Batch ID Sample Units Result Amount Result RPD Limit
Chloride GP39376/GN95899 FC11194-1 mg/l 3.9 50 54.7 1.1 15%
Chloride GP39377/GN95899 FC11199-4 mg/l 4.0 50 55.5 0.4 15%
Chloride GP39382/GN95910 FC11199-4 mg/l 4.0 50 55.5 0.4 15%
Nitrogen, Nitrate GP39376/GN95899 FC11194-1 mg/l 0.16 2.5 2.6 0.0 15%
Nitrogen, Nitrate GP39377/GN95899 FC11199-4 mg/l 3.7 2.5 5.7 0.0 15%
Nitrogen, Nitrate GP39382/GN95910 FC11199-4 mg/l 3.7 2.5 5.7 0.0 15%
Nitrogen, Nitrite GP39376/GN95899 FC11194-1 mg/l 0.040 U 2.5 2.6 0.0 15%
Nitrogen, Nitrite GP39377/GN95899 FC11199-4 mg/l 0.0 2.5 2.6 0.0 15%
Nitrogen, Nitrite GP39382/GN95910 FC11199-4 mg/l 0.0 2.5 2.6 0.0 15%
Sulfate GP39376/GN95899 FC11194-1 mg/l 9.6 50 57.7 1.2 15%
Sulfate GP39377/GN95899 FC11199-4 mg/l 0.0 50 52.2 1.0 15%
Sulfate GP39382/GN95910 FC11199-4 mg/l 0.0 50 51.9 0.2 15%
Associated Samples:
Batch GP39376: FC11199-1
Batch GP39377: FC11199-2, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-7, FC11199-8
Batch GP39382: FC11199-2, FC11199-3, FC11199-4, FC11199-5, FC11199-6, FC11199-7
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
__________________________________________________________________________________________________________________________
Page 1
81 of 81
FC1119977.4

APPENDIX C
CSA Cross Section Maps