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HomeMy WebLinkAboutWS-4667_15111_CA_MRP_20230914SUBSEQUENT MONITORING REPORT WHITE ROCK SERVICE STATION (INCIDENT NO. 15111) 11601 NC-86 SOUTH PROSPECT HILL, CASWELL COUNTY, NORTH CAROLINA ESP Project No. 23-00200-102 Prepared For: North Carolina Department of Environmental Quality Division of Waste Management 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Prepared By: ESP Associates, Inc. P. O. Box 7030 Charlotte, North Carolina 28241 September 14, 2023 ESP Associates, Inc. P.O. Box 7030 • Charlotte, NC 28241 1.800.960.7317 • NC: 704.583.4949, fax 704.583.4950 • SC: 803.802.2440, fax 803.802.2515 www.espassociates.com September 14, 2023 Mr. Thomas Chapman North Carolina Department of Environmental Quality Division of Waste Management 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Email: thomas.chapman@deq.nc.gov Reference:SUBSEQUENT MONITORING REPORT White Rock Service Station (Incident #15111) 11601 NC-86 South Prospect Hill, Caswell County, North Carolina ESP Project No. 23-00200-102 Dear Mr. Chapman: ESP Associates, Inc. (ESP) is pleased to present this Subsequent Monitoring Report documenting activities performed at the subject site, White Rock Service Station, in accordance with North Carolina Department of Environmental Quality (NCDEQ), Task Authorization No. 1, approved on May 19, 2023. The subject site is located at 11601 NC-86 South in Prospect Hill, Caswell County, North Carolina. We appreciate the opportunity to provide environmental services on this project. If you should have any questions, please do not hesitate to contact us at (704) 583-4949. Sincerely, ESP Associates, Inc. Matthew R. Craig Christopher J. Ward, PG, RSM Project Manager Senior Geologist Attachment – Subsequent Monitoring Report TABLE OF CONTENTS Section Page SITE INFORMATION .....................................................................................................................i EXECUTIVE SUMMARY..............................................................................................................iii 1.0 INTRODUCTION ...............................................................................................................1 1.1 SITE SETTING............................................................................................................1 1.2 SITE GEOLOGY AND HYDROGEOLOGY..................................................................1 1.3 SURFACE WATER .....................................................................................................2 1.4 WATER SUPPLY WELLS ...........................................................................................2 2.0 SITE HISTORY...................................................................................................................3 3.0 FIELD ACTIVITIES ...........................................................................................................5 3.1 WATER LEVEL GAUGING ........................................................................................5 3.2 GROUNDWATER SAMPLING....................................................................................6 3.3 FREE PRODUCT EVALUATION ................................................................................6 3.4 WATER SUPPLY WELL SAMPLING..........................................................................7 3.5 FIELD QUALITY CONTROL SAMPLING AND ANALYSIS........................................7 4.0 ANALYTICAL RESULTS...................................................................................................8 5.0 CONCLUSIONS AND RECOMMENDATIONS..................................................................9 6.0 REFERENCES..................................................................................................................10 FIGURES Figure 1 USGS Topographic Site Location Map Figure 2 Site Map Figure 3 Groundwater Elevation Map Figure 4 Groundwater Results Map Figure 5 Benzene Isoconcentration Map Figure 6 Water Supply Well Radius Map TABLES Table 1 Water Supply Well Information Table 2 Monitoring Well Construction and Groundwater Elevation Data Table 3 Summary of Groundwater Analytical Results APPENDICES Appendix A Tables of Previous Groundwater Elevations and Analytical Results Appendix B Photographs and Field Documentation Appendix C Laboratory Data Reports Subsequent Monitoring Report ESP Project No. 23-00200-102 White Rock Service Station (Incident #15111) September 14, 2023 i SITE INFORMATION Date of Report:September 14, 2023 NCDEQ Incident No:15111 NCDEQ UST No.:WS-4667 Site Name:White Rock Service Station Site Location:11601 NC-86 South Prospect Hill, Caswell County, NC 27314 Latitude:N 36.298330 Longitude:W -79.214860 UST Owner/ Operator:Foust Oil Company, Inc. (Defunct) Current Property Owner:Nancy G. Hooper 752 Atwater Road Burlington, NC 27217 (356) 584-6707 Current Property Occupant:Currently Unoccupied Consultant:ESP Associates, Inc. P.O. Box 7030 Charlotte, NC 28241 (704) 583-4949 Laboratory:Pace Analytical Services, LLC NCDEQ No. 5342 9800 Kincey Avenue Huntersville, NC 28028 (704) 875-9092 Release Information:Release Discovery Date: June 6, 1989. Estimate Quantity: Unknown. Cause of Release: Corrosion of USTs and ASTs. Source of Release: Two 1,000-gallon gasoline USTs, two 1,000-gallon orphan USTs, one 550-gallon kerosene UST, and one 550-gallon diesel UST. Currently Active Tanks: None. Tanks Removed in June 1989. Subsequent Monitoring Report ESP Project No. 23-00200-102 White Rock Service Station (Incident #15111) September 14, 2023 ii I, Christopher J. Ward, a Professional Geologist for ESP Associates, Inc., do certify that the information contained in this report is correct and accurate to the best of my knowledge. ESP Associates, Inc. is licensed to practice both geology and engineering in North Carolina. ESP Associates, Inc.’ certification numbers are: Geology: C-556 / Engineering: F-1407 Subsequent Monitoring Report ESP Project No. 23-00200-102 White Rock Service Station (Incident #15111) September 14, 2023 iii EXECUTIVE SUMMARY This executive summary section provides an abbreviated reporting of our Site observations and findings. Refer to the main text and appendices for a complete reporting of our observations and findings. ESP Associates, Inc. (ESP) has completed a Subsequent Monitoring Report documenting assessment activity performed at the White Rock Service Station site (Incident No. 15111). The site is an undeveloped site (Tax Parcel PIN. 0117003) located at 11601 NC Highway 86 South, Prospect Hill, Caswell County, North Carolina. This report was completed to summarize the findings of assessment activities performed on July 11, 2023, in accordance with North Carolina Department of Environmental Quality (NCDEQ), Task Authorization No. 1, approved on May 19, 2023. The work was performed as part of the State Lead Contract #N70522-D between NCDEQ and ESP. This report was prepared in general accordance with the 15A NCAC 2L .0115 regulations and the NCDEQ Underground Storage Tank (UST) Section Guidelines for Assessment and Corrective Action for UST Releases, January 2021, under the supervision of Christopher J. Ward, North Carolina registered professional geologist (North Carolina License No. 1600). On July 11, 2023, ESP performed the following field activities: Gauged static water levels in site monitoring wells MW-1 through MW-13. Although planned, ESP was unable to gauge MW-7 or MW-9 as they were lost during previous site events. Mapped locations of the wells indicate they may have been lost during re-paving and graveling of the lot. MW-10 was also unable to be gauged as the well was part of a sealed system of pipes and could not be accessed; Collected groundwater samples from monitoring wells MW-1 through MW-13, including a field duplicate of MW-12. Although planned, ESP was unable to sample MW-7, MW-9, and MW-10, for the reasons listed above; Replaced Oxygen Release Compound (ORC) Socks in MW-11, MW-12, and MW-13; Obtained water supply well sampling agreements from water supply wells WSW-1 and WSW-2 property owners; and Collected water supply well samples from WSW-1 and WSW-2. Collected water samples were analyzed for volatile organic compounds (VOCs) for comparison to both North Carolina Groundwater Quality Standards 15A NCAC 2L .0202 (2L Standards) and Gross Contaminant Levels (GCLs). Subsequent Monitoring Report ESP Project No. 23-00200-102 White Rock Service Station (Incident #15111) September 14, 2023 iv Based on results of the above field activities and previous reporting, ESP concludes the following:  Two water supply wells (WSW-1 and WSW-2) are located within 500 feet of the source area and two water supply wells (WSW-3 and WSW-4) are located within 1,000 feet of the source area; Municipal water is reportedly not available in the area surrounding the site; Static water level depths ranged from 24.35 to 27.75 ft bTOC; Shallow groundwater flow at the site was estimated to be radial from the source area; Free product was not detected in any sampled monitoring well; No Analytes were detected above the GCL in any monitoring well or supply well samples; All analytes were below MDLs in MW-1 through 6, MW-8, WSW-1, and WSW-2; All analytes were equal to or less than 2L standards in MW-11 and MW-13 except for 1,2- dichloroethane in MW-13; Benzene and 1,2-dichloroethane were detected above 2L standards in MW-12; 1,2-dichloroethane was detected above its 2L standard in MW-13; and ORC Socks were replaced in MW-11, MW-12, and MW-13. Contaminant concentrations at the site have been steadily decreasing since 2020 with significant decreases in contaminant concentrations since June 1, 2021 sampling event. Groundwater concentrations in MW-12 and MW-13 have remained above 2L standards while all analytes continue to be below MDLs in WSW-1 and WSW-2. Based on the above results, ESP offers the following recommendations: Continue to sample site monitoring wells and water supply wells WSW-1 and WSW-2 on a semiannual basis to further understand concentration trends with the goals of obtaining below 2L standard concentrations in all site wells; Continue to maintain ORC socks in MW-11, MW-12, and MW-13 to further reduce constituent concentrations on site; and Repair well vaults for MW-1 and MW-2 to make them water proof and replace the well caps. Subsequent Monitoring Report ESP Project No. 23-00200-102 White Rock Service Station (Incident #15111) September 14, 2023 1 1.0 INTRODUCTION 1.1 Site Setting The White Rock Service Station site (Tax Parcel ID. 0117003) is located at 11601 NC-86 Highway South in Prospect Hill, Caswell County, North Carolina (see Figures 1 and 2). The site is presently unoccupied, containing a shed with a groundwater recovery system, which was not in operation at the time of our site visit. The site formerly operated as a gasoline and diesel fuel storage and dispensing facility owned by Exxon. Prior to its removal on June 1989, the underground storage tank (UST) network consisted of two 1,000-gallon gasoline USTs, one 550-gallon kerosene UST, and one 550- gallon diesel UST. During the excavation of the system in 1989, two additional 1,000-gallon USTs of unknown contents were also discovered and removed. 1.2 Site Geology and Hydrogeology Consideration of surface and subsurface drainage and geology are of interest since they provide an indication of the direction that contamination, if present on-site or off-site, could be transported. The site is located within the Piedmont Physiographic Province. The Piedmont Physiographic Province generally consists of low to medium elevation, rounded hills, and long rolling northeast to southwest trending ridges with incised creeks and river channels. Rock at the site is described as metamorphosed granitic rock, locally comprised of hornblende. In-place chemical and physical weathering of parent rocks typically form residual soils in the Piedmont region. Weathering is facilitated by the presence of fractures, joints, and less resistant minerals in the rock. In areas not altered by erosion, alluvial deposition or the activities of man, the typical residual soil profile consists of clay-rich unconsolidated materials at the surface, transitioning to sandy silts and silty sands at depth. Typically, the boundary between soil and rock is not sharply defined. This transitional zone is termed “partially weathered rock” or saprolite. Information obtained from the Web Soil Survey for Caswell County depicts soils on the site as Louisburg coarse sandy loam, 2 to 6 percent slopes (LoB) and Louisburg coarse sandy loam, 10 to 15 percent slopes (LoD). In the Piedmont, groundwater generally occurs in pore spaces within soils and in the structural features present in the underlying rock (i.e., joints, fractures, and faults). Recharge to the water table is primarily by precipitation infiltrating the surficial soils and percolating downward under the influence of gravity to the water table. Typically, the water table is not a level surface, but a subdued reflection of the land surface. The depth to the water table is not consistent and is dependent upon several factors that include the amount of rainfall, permeability of the soil, the extent of fracturing in the underlying rock and the influences of groundwater pumping. The direction and movement of groundwater through soil is generally dependent on soil type, the presence of relict structures, and the textures of the underlying rock. Fractures, faults, folds, and Subsequent Monitoring Report ESP Project No. 23-00200-102 White Rock Service Station (Incident #15111) September 14, 2023 2 foliation planes affect the migration of groundwater in rock. No major geologic features (faults, etc.) are present at or near the site. Groundwater typically flows in directions parallel to the ground surface and under the influence of gravity, migrates to discharge points such as surface water features, the toes of slopes or natural springs. Fluctuations in the depth of the water table can be expected depending on variations in precipitation, surface water run-off and other factors. Normally, the highest levels of the water table occur in late winter and spring and the lowest levels occur in the late summer and fall. Based on historical data and the July 11, 2023, water level measurements, shallow groundwater flow at the site was estimated to be radial from the source area. 1.3 Surface Water A small stream and pond are located approximately 700 feet southwest of the site while a small pond is located approximately 700 ft west of the site (see Figures 1 and 6). The stream serves as a tributary for Lunch Creek. No other surface water features are located within 1,000 feet of the site. 1.4 Water Supply Wells Based on previous receptor surveys conducted by others, four water supply wells have been identified within a 1,000 ft radius of the site (see Table 1 and Figure 6). Two of the water supply wells (WSW-1 and WSW-2) are located within 500 feet of the source area and two water supply wells (WSW-3 and WSW-4) are located within 1,000 feet of the source area. Municipal water is reportedly not available in the area surrounding the site Subsequent Monitoring Report ESP Project No. 23-00200-102 White Rock Service Station (Incident #15111) September 14, 2023 3 2.0 SITE HISTORY The following description of historical site activities was obtained from a report titled “Annual Monitoring Report, White Rock Service Station” dated July 29, 2022, by Terracon Consultants Inc. (Terracon). In June 1989, the entire UST network present on site was closed in place and removed. The network consisted of two 1,000-gallon gasoline USTs, one 550-gallon kerosene UST, and one 550-gallon diesel UST. During this excavation, two additional 1,000- gallon orphan USTs of unknown contents were discovered and removed. Several holes were discovered in these USTs upon excavation, and an unknown amount of petroleum impacted soil was subsequently removed. On April 27, 1994, water samples from water supply well WSW-1 revealed petroleum constituents above 2L standards. On February 16, 1995, Turner Environmental Consultants (TEC) mobilized to advance several soil borings around each former tank basin and the former dispenser station. The soil samples collected from this mobilization did not indicate any constituents above MDLs. Between December 5 and 6, 1994, TEC advanced an additional 17 soil borings throughout the site. Soil samples were collected from each bore, along with a water supply well sample from WSW-1. Total Petroleum Hydrocarbons-Diesel Range Organics (TPH-DRO) analysis indicated several diesel range organics in exceedance of the NCDEQ Action Levels. VOC analysis of the water supply well sample indicated the presence of benzene above its 2L standard. On December 3, 1996, TEC conducted a Comprehensive Site Assessment (CSA), and installed thirteen monitoring wells throughout the site. Each well was sampled following its installation, for VOC contaminants. Laboratory analysis indicated benzene concentrations above its GCL in MW-1, MW-2, and MW-3. Soil borings were also installed and sampled for constituents. TPH-DRO analysis indicated diesel range organics above NCDEQ Action Levels. Between 1997 and 1999, Omega Environmental Services (Omega) installed four recovery wells, RW-1, RW-2, RW-3, and RW-4 on site. Omega also performed Aggressive Fluid Vapor Recovery (AFVR) on MW-1 through MW-11. On March 18, 2001, Omega mobilized to install a dual-phase extraction remediation system on site. Groundwater sampling events continued to be performed on site between 2008 and 2019 by Paragon Environmental Consultants (Paragon). These events showed a steady decrease of benzene concentrations throughout the site from 2007 to 2019. Except for MW-11 through MW-13, constituents were not detected above MDLs in any monitoring well or recovery well from 2009 to 2019. In August 2020, Terracon mobilized to perform a sampling event of monitoring wells MW-4, MW-5, MW-12, MW-13, and RW-2. Water supply wells WSW-1 and WSW-2 Subsequent Monitoring Report ESP Project No. 23-00200-102 White Rock Service Station (Incident #15111) September 14, 2023 4 were also sampled. Only MW-12 and MW-13 contained petroleum constituents above 2L standards. A receptor survey was also carried out during this event. Terracon identified ten water supply wells within 1,500 feet of the site. WSW-1 and WSW-2 are located within 500 feet of the site, while WSW-3 and WSW-4 are located within 1,000 feet of the site. Between June 1 and 2, 2022, Terracon mobilized to conduct a groundwater sampling event on monitoring wells MW-1 through MW-13, recovery wells RW-1 through RW- 4, and water supply wells WSW-1 and WSW-2. Terracon had also performed an inspection on the on-site dual-phase extraction remediation system which had at that point fallen to disuse. Historical groundwater elevations and analytical results are provided in Appendix A. Subsequent Monitoring Report ESP Project No. 23-00200-102 White Rock Service Station (Incident #15111) September 14, 2023 5 3.0 FIELD ACTIVITIES On July 11, 2023, ESP performed the following field activities: Gauged static water levels in site monitoring wells MW-1 through MW-13. Although planned, ESP was unable to gauge MW-7 or MW-9 as they were lost during previous site events. Mapped locations of the wells indicate they may have been lost during re-paving and graveling of the lot. MW-10 was also unable to be gauged as the well was part of a sealed system of pipes and could not be accessed; Collected groundwater samples from monitoring wells MW-1 through MW-13, including a field duplicate of MW-12. Although planned, ESP was unable to sample MW-7, MW-9, and MW-10, for the reasons listed above; Replaced Oxygen Release Compound (ORC) Socks in MW-11, MW-12, and MW-13; Obtained water supply well sampling agreements from water supply wells WSW-1 and WSW-2 property owners; and Collected water supply well samples from WSW-1 and WSW-2. Sample locations are depicted on Figure 2. Field logbook entries along with water level survey, groundwater sampling, and field instrument calibration forms were completed in the field to document site activities (see Appendix B). Photographs are also provided in Appendix B. Details of field activities are provided below. 3.1 Water Level Gauging On July 11, 2023, prior to purging or collecting groundwater samples, depth to groundwater from the top of casing (TOC) within each monitoring well was measured and recorded using a decontaminated electronic water level meter. The water level measurements were collected by first removing covers and plunger caps from all site monitoring wells and allowing water within the wells to stabilize. The electronic water level meter probe was then lowered into the well and the depth to water measured relative to the well’s TOC. As noted on Table 2, static water level depths ranged from 24.35 to 27.75 ft below top of casing (ft bTOC). It should be noted that the well vaults for MW-1 and MW-2 were full of rain water when ESP arrived to gauge and sample site monitoring wells. The day prior to the gauging/sampling event, heavy rainfall occurred within the area. No well caps were found for either MW-1 and MW-2 and the wells appeared to be filled with rainwater as water levels were at or close to the TOC. Based on this, water levels for these two wells were not noted on Table 2 or used in the preparation of Figure 3. Groundwater elevations, based off TOC elevations obtained by others using a VRS device in June 2022, depict a shallow groundwater flow at the site to be radial from the source area (see Figure 3). Subsequent Monitoring Report ESP Project No. 23-00200-102 White Rock Service Station (Incident #15111) September 14, 2023 6 3.2 Groundwater Sampling On July 11, 2023, monitoring wells MW-1 through MW-6, MW-8, MW-11, MW-12, and MW-13 were sampled for VOC concentrations. Although planned, ESP was unable to sample MW-7 or MW-9 as they were lost during previous site events. Mapped locations of the wells indicate they may have been lost during re-paving and graveling of the lot. Also, MW-10 was also unable to be sampled as the well was part of a sealed system of remedial system pipes and could not be accessed. Groundwater samples were collected using dedicated and disposable polyvinyl chloride (PVC) bailers (1.5” x 3’) attached to braided nylon rope. Prior to groundwater sample collection, each well was purged using the bailer. During purging, water quality parameters including pH, conductivity, temperature, and turbidity were measured using calibrated field water quality instruments. Readings were taken at the start of purging and periodically until a minimum of three well volumes were removed from the well or water quality parameters stabilized. Following purging, a groundwater sample for laboratory analysis was collected from the well using the bailer. The water quality parameters were recorded on groundwater sampling forms along with time, water level depth, and cumulative volume of water purged (see groundwater sampling forms in Appendix B). Due to the apparent presence of surface water within MW-1 and MW-2, approximately 19 gallons of water was purged from each well to attempt to remove some of the surface water that likely infiltrated into the well (i.e., to obtain more accurate samples). Groundwater samples were collected following Guidelines for Sampling by the Underground Storage Tank Section, Division of Waste Management, North Carolina Department of Environmental Quality (NCDEQ, 2022). Groundwater samples were placed in laboratory- prepared vials preserved with hydrochloric acid (HCl), labeled, and stored on ice in a cooler for subsequent delivery under standard chain-of-custody (COC) procedures to Pace Analytical (Pace), a North Carolina-certified laboratory, located in Huntersville, North Carolina, for analysis. The groundwater samples were analyzed for VOCs by EPA Method 6200B including MTBE, ethylene dibromide (EDB), and isopropyl ether (IPE). 3.3 Free Product Evaluation During the July 11, 2023, event, no free product was measured or observed in any of the sampled wells. Subsequent Monitoring Report ESP Project No. 23-00200-102 White Rock Service Station (Incident #15111) September 14, 2023 7 3.4 Water Supply Well Sampling The access agreement for water supply well WSW-2 was obtained via mail prior to the July 11, 2023 sampling event. The access agreement for WSW-1 was obtained in person during the July 11, 2023 sampling event. Both access agreements are provided in Appendix B. On July 11, 2023, groundwater samples were collected from water supply wells WSW-1 and WSW-2. WSWs were sampled by locating a spigot as close to the supply well head as possible. The spigot was turned on and allowed to purge for at least 15 minutes. Following the purge, flow was reduced, and samples were collected directly into laboratory-preserved vial preserved with HCL, labeled, and stored on ice in a cooler for subsequent delivery under standard COC procedures to Pace for analysis of VOCs by EPA Method 6200B including MTBE, EDB and IPE. 3.5 Field Quality Control Sampling and Analysis A field duplicate groundwater sample was collected on July 11, 2023, from MW-12 and analyzed for VOCs by EPA Method 6200B including MTBE, EDB, and IPE to assess variance between collected samples. Subsequent Monitoring Report ESP Project No. 23-00200-102 White Rock Service Station (Incident #15111) September 14, 2023 8 4.0 ANALYTICAL RESULTS Results of the laboratory analysis of groundwater samples from monitoring wells MW-1 through MW-6, MW-8, MW-11, MW-12, and MW-13, plus duplicate along with water supply wells WSW-1 and WSW-2, are tabulated in Table 3. The analytical results are compared to both 2L standards and GCLs. The Pace laboratory analytical report is provided in Appendix C. No analytes were detected at concentrations exceeding their respective GCLs; however, various analytes were detected at concentrations greater than their respective 2L standards in MW-11, MW-12, and MW-13. No analytes were detected above 2L standards in the remaining monitoring wells, or either water supply well (see Table 3 and Figures 4 and 5). A summary of the analytical results is as follows: MW-1 through 6, MW-8 - all analytes were below MDLs; MW-11 and MW-13 - all analytes were equal to or less than 2L standards except for 1,2- dichloroethane in MW-13; In MW-12 - benzene (35.4 µg/L) and 1,2-dichloroethane (0.98 µg/L) were both detected above their respective 2L standards; In MW-13 - 1,2-dichloroethane (0.65 µg/L) was detected above its 2L standard; and WSW-1 and WSW-2 - all analytes were below MDLs. The general trend in groundwater contaminant concentrations at the site have been steadily decreasing since 2020 with significant decreases in contaminant concentrations since June 1, 2021 sampling event. Groundwater concentrations in MW-12 and MW-13 have remained above 2L standards. All analytes continue to be below MDLs in WSW-1 and WSW-2. Subsequent Monitoring Report ESP Project No. 23-00200-102 White Rock Service Station (Incident #15111) September 14, 2023 9 5.0 CONCLUSIONS AND RECOMMENDATIONS Based on results of the above field activities and previous reporting, ESP concludes the following:  Two water supply wells (WSW-1 and WSW-2) are located within 500 feet of the source area and two water supply wells (WSW-3 and WSW-4) are located within 1,000 feet of the source area; Municipal water is reportedly not available in the area surrounding the site; Static water level depths ranged from 24.35 to 27.75 ft bTOC; Shallow groundwater flow at the site was estimated to be radial from the source area; Free product was not detected in any sampled monitoring well; No Analytes were detected above the GCL in any monitoring well or supply well samples; All analytes were below MDLs in MW-1 through 6, MW-8, WSW-1, and WSW-2; All analytes were equal to or less than 2L standards in MW-11 and MW-13 except for 1,2- dichloroethane in MW-13; Benzene and 1,2-dichloroethane were detected above 2L standards in MW-12; 1,2-dichloroethane was detected above its 2L standard in MW-13; and ORC Socks were replaced in MW-11, MW-12, and MW-13. Contaminant concentrations at the site have been steadily decreasing since 2020 with significant decreases in contaminant concentrations since June 1, 2021 sampling event. Groundwater concentrations in MW-12 and MW-13 have remained above 2L standards while all analytes continue to be below MDLs in WSW-1 and WSW-2. Based on the above results, ESP offers the following recommendations: Continue to sample site monitoring wells and water supply wells WSW-1 and WSW-2 on a semiannual basis to further understand concentration trends with the goals of obtaining below 2L standard concentrations in all site wells; Continue to maintain ORC socks in MW-11, MW-12, and MW-13 to further reduce constituent concentrations on site; and Repair well vaults for MW-1 and MW-2 to make them water proof and replace the well caps. Subsequent Monitoring Report ESP Project No. 23-00200-102 White Rock Service Station (Incident #15111) September 14, 2023 10 6.0 REFERENCES Caswell County NC WebGIS, https://www.webgis.net/nc/caswell/ 1985 Geologic Map of North Carolina, The North Carolina Geological Survey, Phillip M. Brown, 1985. Guideline for Sampling Underground Storage Tank Section, Division of Waste Management, North Carolina Division of Environmental Quality, March 7, 2022, Change 4. Terracon, July 29, 2022, Semi-Annual Monitoring Report: White Rock Service Station (Incident #15111), Prospect Hill, Caswell County, North Carolina. Terracon, September 25, 2020, Initial Monitoring Report: White Rock Service Station (Incident #15111), Prospect Hill, Caswell County, North Carolina Paragon Environmental Consultants, Inc, April 12, 2017, White Rock Service Station, 11601 NC Highway 86 Sout, Prospect Hill, Caswell County, North Carolina, Groundwater Incident: 15111, Facility ID: 0-031180. FIGURES 0 350 700Feet ESP Associates, Inc. P.O. Box 7030Charlotte, NC 28241 Phone 704.583.4949 www.espassociates.com SHEET TITLE PROJECT PROJECT NO. SCALE DRAWN BY CHECKED BY 23-00200-102 ET CWDATE08/04/2023 FIGURE 1USGS TOPOGRAPHIC SITE LOCATION MAPµAs Shown PROSPECT HILL, NORTH CAROLINA SITE BOUNDARY All locations are approximate. WHITE ROCK SERVICE STATION LEGEND: < < << < < < < < < < < < << MW-10 MW-3 MW-9 MW-8 RW-3 MW-7 RW-4 MW-4 RW-1 RW-2 MW-12 MW-2 MW-1MW-5 MW-6 < MW-13<MW-11 EDWSW-1 ON-SITE RECOVERY SYSTEM 0 20 40Feet ESP Associates, Inc. P.O. Box 7030Charlotte, NC 28241 Phone 704.583.4949 www.espassociates.com SHEET TITLE PROJECT PROJECT NO. SCALE DRAWN BY CHECKED BY 23-00200-102 ET CWDATE08/04/2023 FIGURE 2SITE MAPµAs Shown PROSPECT HILL, NORTH CAROLINA SITE BOUNDARYMONITORING WELLMONITORING WELL (NOT LOCATED)WATER SUPPLY WELLFORMER UST All locations are approximate. WHITE ROCK SERVICE STATION LEGEND: < ED < < < << < < < < < < < < < << MW-10 MW-3 MW-9 MW-8 RW-3 MW-7 RW-4 MW-4 RW-1 RW-2 MW-12 MW-2 MW-1MW-5 MW-6 < MW-13<MW-11 EDWSW-1 ON-SITE RECOVERY SYSTEM 0 20 40Feet ESP Associates, Inc. P.O. Box 7030Charlotte, NC 28241 Phone 704.583.4949 www.espassociates.com SHEET TITLE PROJECT PROJECT NO. SCALE DRAWN BY CHECKED BY 23-00200-102 ET CWDATE08/04/2023 FIGURE 3GROUNDWATER ELEVATION MAPJULY 11, 2023µAs Shown PROSPECT HILL, NORTH CAROLINA SITE BOUNDARYMONITORING WELLMONITORING WELL (NOT LOCATED)WATER SUPPLY WELLFORMER USTESTIMATED GROUNDWATER ELEVATION CONTOURESTIMATED GROUNDWATER FLOW DIRECTION All locations are approximate. WHITE ROCK SERVICE STATION LEGEND: < ED < < < << < < < < < < < < < << MW-10 MW-3 MW-9 MW-8 RW-3 MW-7 RW-4 MW-4 RW-1 RW-2 MW-12 MW-2 MW-1MW-5 MW-6 < MW-13<MW-11 EDWSW-1 0 20 40Feet ESP Associates, Inc. P.O. Box 7030Charlotte, NC 28241 Phone 704.583.4949 www.espassociates.com SHEET TITLE PROJECT PROJECT NO. SCALE DRAWN BY CHECKED BY 23-00200-102 ET CWDATE08/04/2023 FIGURE 4GROUNDWATER RESULTS MAPJULY 11, 2023µAs Shown PROSPECT HILL, NORTH CAROLINA SITE BOUNDARYMONITORING WELLMONITORING WELL (NOT LOCATED)WATER SUPPLY WELLFORMER UST All locations are approximate. WHITE ROCK SERVICE STATION LEGEND: < ED < < < << < < < < < < < < < << MW-10 MW-3 MW-9 MW-8 RW-3 MW-7 RW-4 MW-4 RW-1 RW-2 MW-12 MW-2 MW-1MW-5 MW-6 < MW-13<MW-11 EDWSW-1 0 20 40Feet ESP Associates, Inc. P.O. Box 7030Charlotte, NC 28241 Phone 704.583.4949 www.espassociates.com SHEET TITLE PROJECT PROJECT NO. SCALE DRAWN BY CHECKED BY 23-00200-102 ET CWDATE08/04/2023 FIGURE 5BENZENE ISOCONCENTRATION MAPJULY 11, 2023µAs Shown PROSPECT HILL, NORTH CAROLINA SITE BOUNDARYMONITORING WELLMONITORING WELL (NOT LOCATED)WATER SUPPLY WELLFORMER USTCONCENTRATION CONTOUR All locations are approximate. WHITE ROCK SERVICE STATION LEGEND: < ED < ED WSW-1 ED WSW-2 WSW-4ED ED WSW-3 500-ft 1,000-ft 0 110 220Feet ESP Associates, Inc. P.O. Box 7030Charlotte, NC 28241 Phone 704.583.4949 www.espassociates.com SHEET TITLE PROJECT PROJECT NO. SCALE DRAWN BY CHECKED BY 23-00200-102 ET CWDATE08/04/2023 FIGURE 6WATER SUPPLY WELL RADIUS MAPµAs Shown PROSPECT HILL, NORTH CAROLINA SITE BOUNDARYWATER SUPPLY WELL RIVERINE WETLAND FRESHWATER PONDFRESHWATER FORESTED/SHRUB WETLAND All locations are approximate. WHITE ROCK SERVICE STATION LEGEND: ED TABLES Table 1 Water Supply Well Information White Rock Service Station Prospect Hill, North Carolina NCDEQ Incident No. 15111 Well No.Property Owner Mailing Address Property Address Distance from Source Area (ft) Hydraulic Relationship to Source Area Well Status/Use Municpal Water Parcel No. WSW-1 Prospect Hill Fire Department 11621 NC Highway 86 S Prospect Hill, NC 27314 11621 NC Highway 86 S Prospect Hill, NC 27314 ~140 feet south Upgradient Active No ..0117004 WSW-2 Donald & Juanita Penny 11535 NC Highway 86 S Prospect Hill, NC 27314 11535 NC Highway 86 S Prospect Hill, NC 27314 ~440 feet northwest Downgradient Active No ..0117071 WSW-3 Harold Jr & Paula Stone 11741 NC Highway 86 S Prospect Hill, NC 27314 11741 NC Highway 86 S Prospect Hill, NC 27314 ~680 feet southeast Upgradient Active No ..0117005 WSW-4 Dustin Wrenn 4977 Sartin Rd Burlington, NC 27217 11600 NC Highway 86 S Prospect Hill, NC 27314 ~875 feet west Upgradient Active No ..0117010 Notes: Information obtained from previous monitoring report. Table 2 Monitoring Well Construction and Groundwater Elevation Data White Rock Service Station Prospect Hill, North Carolina NCDEQ Incident No. 15111 Well ID Date Installed Screened Interval (ft BGS) a Bottom of Well (ft BGS) a Top of Casing Elevation (ft) a,b Date Water Level Measured Depth to Water from Top of Casing (ft bTOC) Groundwater Elevation (ft) Free Product Thickness (ft) 8/18/2020 NM NM --- 6/30/2021 20.87 79.13 --- 6/1/2022 NM NM --- 7/11/2023 NM NM --- 8/18/2020 NM NM --- 6/30/2021 13.39 85.92 --- 6/1/2022 NM NM --- 7/11/2023 NM NM --- 8/18/2020 NM NM --- 6/30/2021 21.75 76.62 --- 6/1/2022 24.30 596.36 --- 7/11/2023 24.35 596.31 --- 8/18/2020 22.03 77.88 --- 6/30/2021 22.54 77.37 --- 6/1/2022 24.97 597.67 --- 7/11/2023 25.00 597.64 --- 8/18/2020 24.54 75.82 --- 6/30/2021 24.21 76.15 --- 6/1/2022 26.81 594.82 --- 7/11/2023 26.40 595.23 --- 8/18/2020 20.20 77.60 --- 6/30/2021 20.08 77.72 --- 6/1/2022 23.35 600.84 --- 7/11/2023 27.75 596.44 --- 8/18/2020 6/30/2021 6/1/2022 7/11/2023 8/18/2020 26.69 72.92 --- 6/30/2021 26.57 73.04 --- 6/1/2022 28.40 602.97 --- 7/11/2023 27.60 603.77 --- 8/18/2020 6/30/2021 6/1/2022 7/11/2023 8/18/2020 6/30/2021 6/1/2022 7/11/2023 8/18/2020 NM NM --- 6/30/2021 22.01 78.14 --- 6/1/2022 17.54 604.15 --- 7/11/2023 25.50 596.19 --- 8/18/2020 23.80 78.36 --- 6/30/2021 24.29 77.87 --- 6/1/2022 26.41 597.19 --- 7/11/2023 26.70 596.90 --- 8/18/2020 22.28 79.82 --- 6/30/2021 24.04 78.06 --- 6/1/2022 26.15 597.39 --- 7/11/2023 27.00 596.54 --- Notes: a Top of casing elevations, screened intervals, and bottom of well measurements are from previous consultants' monitoring reports. b Top of casing elevations are based off of an assumed benchmark elevation of 100.00 ft given to MW-1. -- - no measureable free product BGS - below ground surface ft - feet ft bTOC - feet below TOC FP - free product TOC - top of casing 33.0 33.0 33.0 Well Missing Well Missing Well Obstructed 40.0 33.0 33.5 34.0 102.16 623.6 631.37 89.93 612.69 100.15 621.69 40.0 20.0-33.0 7/29/1996 7/29/1996 9/17/1996 18.50-33.50 33.5 18.5-33.5 19.5-33.5 19.0-34.0 7/29/1996 7/29/1996 7/29/1996 7/29/1996 7/29/1996 20.0-40.0 20.0-40.0 20.0-40.0 20.0-33.0 19.0-34.0 c Groundwater elevation adjusted for measureable free product by using the following calculation: (TOC Elevation - Depth to water) + (FP thickness * 0.729), where 0.729 is the specific gravity for automotive gasoline. MW-1 MW-2 MW-3 MW-4 MW-5 MW-6 MW-7 MW-8 MW-10 MW-11 MW-12 MW-9 2/19/1996 2/19/1996 2/19/1996 621.63 97.80 624.19 MW-13 9/17/1996 18.0-33.0 102.10 623.54 9/17/1996 18.0-33.0 18.0-33.0 97.95 93.87 99.61 40.0 33.5 34.0 33.5 100.00 621.52 99.31 621.7 98.37 620.66 99.91 622.64 100.36 Table 3 Summary of Groundwater Analytical Results White Rock Service Station Prospect Hill, North Carolina NCDEQ Incident No. 15111 (Page 1 of 2) 1 70 70 70 70 0.40 0.60 0.02 70 600 70 20 6 70 600 400 400 500 500 500 5,000 5,900 8,800 14,750 70,000 400 600 50 70,000 80,000 30,500 20,000 6,000 26,100 260,000 28,500 24,100 50,000 50,000 50,000 8/18/20 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR 6/30/21 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.80 <0.40 <0.40 6/1/22 <0.09 <0.16 <0.13 <0.13 <0.11 <0.08 <0.15 <0.13 <0.11 <0.14 <0.11 <0.10 <1.0 <0.10 <0.28 <0.32 <0.10 <0.60 <0.17 <0.43 7/11/23 <0.079 <0.066 <0.085 <0.086 <0.069 <0.11 <0.14 <0.15 <0.072 <0.081 <0.11 <0.053 <0.10 <0.10 <0.09 <0.031 <0.071 <0.234 <0.094 <0.14 8/18/20 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR 6/30/21 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.80 <0.40 <0.40 6/1/22 <0.09 <0.16 <0.13 <0.13 <0.11 <0.08 <0.15 <0.13 <0.11 <0.14 <0.11 <0.10 <1.00 <0.10 <0.28 <0.32 <0.10 <0.60 <0.17 <0.43 7/11/23 <0.079 <0.066 <0.085 <0.086 <0.069 <0.11 <0.14 <0.15 <0.072 <0.081 <0.11 <0.053 <0.10 <0.10 <0.09 <0.031 <0.071 <0.234 <0.094 <0.14 8/18/20 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR 6/30/21 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.80 <0.40 <0.40 6/1/22 <0.09 <0.16 <0.13 <0.13 <0.11 <0.08 <0.15 <0.13 <0.11 <0.14 <0.11 <0.10 <1.00 <0.10 <0.28 <0.32 <0.10 <0.60 <0.17 <0.43 7/11/23 <0.079 <0.066 <0.085 <0.086 <0.069 <0.11 <0.14 <0.15 <0.072 <0.081 <0.11 <0.053 <0.10 <0.10 <0.09 <0.031 <0.071 <0.234 <0.094 <0.14 8/18/20 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <3.0 <2.0 <1.0 6/30/21 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.80 <0.40 <0.40 6/1/22 <0.09 <0.16 <0.13 <0.13 <0.11 <0.08 <0.15 <0.13 <0.11 <0.14 <0.11 <0.10 <1.00 <0.10 <0.28 <0.32 <0.10 <0.60 <0.17 <0.43 7/11/23 <0.079 <0.066 <0.085 <0.086 <0.069 <0.11 <0.14 <0.15 <0.072 <0.081 <0.11 <0.053 <0.10 <0.10 <0.09 <0.031 <0.071 <0.234 <0.094 <0.14 8/18/20 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <3.0 <2.0 <1.0 6/30/21 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.80 <0.40 <0.40 6/1/22 <0.09 <0.16 <0.13 <0.13 <0.11 <0.08 <0.15 <0.13 <0.11 <0.14 <0.11 <0.10 <1.00 <0.10 <0.28 <0.32 <0.10 <0.60 <0.17 <0.43 7/11/23 <0.079 <0.066 <0.085 <0.086 <0.069 <0.11 <0.14 <0.15 <0.072 <0.081 <0.11 <0.053 <0.10 <0.10 <0.09 <0.031 <0.071 <0.234 <0.094 <0.14 8/18/20 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR 6/30/21 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.80 <0.40 <0.40 6/1/22 <0.09 <0.16 <0.13 <0.13 <0.11 <0.08 <0.15 <0.13 <0.11 <0.14 <0.11 <0.10 <1.00 <0.10 <0.28 <0.32 <0.10 <0.60 <0.17 <0.43 7/11/23 <0.079 <0.066 <0.085 <0.086 <0.069 <0.11 <0.14 <0.15 <0.072 <0.081 <0.11 <0.053 <0.10 <0.10 <0.09 <0.031 <0.071 <0.234 <0.094 <0.14 8/18/20 6/30/21 6/1/22 7/11/23 8/18/20 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR 6/30/21 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.80 <0.40 <0.40 6/1/22 <0.09 <0.16 <0.13 <0.13 <0.11 <0.08 <0.15 <0.13 <0.11 <0.14 <0.11 <0.10 <1.00 <0.10 <0.28 <0.32 <0.10 <0.60 <0.17 <0.43 7/11/23 <0.079 <0.066 <0.085 <0.086 <0.069 <0.11 <0.14 <0.15 <0.072 <0.081 <0.11 <0.053 <0.10 <0.10 <0.09 <0.031 <0.071 <0.234 <0.094 <0.14 8/18/20 6/30/21 6/1/22 7/11/23 8/18/20 6/30/21 6/1/22 7/11/23 m&p-XyleneMW-4 MW-6 MW-5 GCL (µg/L) Sample ID Collection Date MW-1 MW-2 MW-3 Benzenen-Butylbenzeneo-Xylene1,2-Dibromoethane (EDB)Diisopropyl ether (IPE)Chloroform1,2-Dichloroethane1,2-DichloropropaneToluene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneXylene (Total)n-PropylbenzeneNaphthaleneIsopropylbenzene (cumene)Methyl Tert-Butyl Ether (MTBE)sec-Butylbenzenetert-Butylbenzene2L Standard (µg/L)EthylbenzeneMW-8 MW-7 MW-9 MW-10 Well Not Sampled Well Not Sampled - Not Located Well Not Sampled - Not Located Well Not Sampled - Not Located Well Not Sampled Well Not Sampled - Not Located Well Not Sampled - Not Located Well Not Sampled - Not Located Well Not Sampled Well Not Sampled - Not Located Well Not Sampled - Not Located Well Not Sampled - Obstructed Table 3 Summary of Groundwater Analytical Results White Rock Service Station Prospect Hill, North Carolina NCDEQ Incident No. 15111 (Page 2 of 2) 1 70 70 70 70 0.40 0.60 0.02 70 600 70 20 6 70 600 400 400 500 500 500 5,000 5,900 8,800 14,750 70,000 400 600 50 70,000 80,000 30,500 20,000 6,000 26,100 260,000 28,500 24,100 50,000 50,000 50,000m&p-XyleneGCL (µg/L) Sample ID Collection Date MW-1 Benzenen-Butylbenzeneo-Xylene1,2-Dibromoethane (EDB)Diisopropyl ether (IPE)Chloroform1,2-Dichloroethane1,2-DichloropropaneToluene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneXylene (Total)n-PropylbenzeneNaphthaleneIsopropylbenzene (cumene)Methyl Tert-Butyl Ether (MTBE)sec-Butylbenzenetert-Butylbenzene2L Standard (µg/L)Ethylbenzene8/18/20 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR 6/30/21 <0.40 1.4 0.42J <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 0.80 0.60 <0.40 0.40J 1.6 <0.40 7.3 1.7 1.5 1.5 <0.40 6/1/22 1.2 <0.16 <0.13 <0.13 <0.11 <0.08 <0.15 <0.13 0.13J <0.14 0.12J <0.10 <1.00 <0.10 0.66 1.7 0.58 1.8 1.1 0.71 7/11/23 1.0 <0.066 <0.085 <0.086 <0.069 <0.11 <0.14 <0.15 <0.072 <0.081 <0.11 <0.053 <0.10 <0.10 1.5 0.50 <0.071 0.34J <0.094 0.34J 8/18/20 523 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 106 232 28.2 <10.0 93.8 37.0 16.8 <10.0 <10.0 86.0 86.0 <10.0 6/30/21 1,400 <8.0 <8.0 <8.0 <8.0 <8.0 <8.0 <8.0 27.0 420 33.0 <8.0 170 40.0 49.0 74.0 <8.0 277 240 37.0 6/1/22 918 2.1 3.2 2.3 <0.11 <0.08 <0.15 <0.13 59.6 293 22.8 <0.10 104 38.2 31.7 16.6 <0.10 132 109 23.3 7/11/23 35.4 <0.066 0.62 0.52 <0.069 0.89 0.60 <0.15 20.1 0.33J 1.9 <0.053 0.72J <0.10 0.87 <0.031 <0.071 0.73 <0.094 0.73 8/18/20 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 5.4 44.3 7.6 <1.0 187 9.0 1.81 95.1 48.8 57.0 52.2 4.8 6/30/21 180 0.77 0.55 0.70 <0.40 1.9 0.58 <0.40 18.0 52.0 4.1 <0.40 21.0 5.0 6.3 10.0 0.55 35.5 31.0 4.5 6/1/22 <0.09 <0.16 <0.13 <0.13 <0.11 0.35 <0.15 <0.13 2.14 0.89 0.16 <0.10 3.7 0.18 <0.28 1.5 <0.10 1.0 1.0 <0.17 7/11/23 <0.079 <0.066 <0.085 <0.086 <0.069 0.65 <0.14 <0.15 11.4 <0.081 <0.11 <0.053 0.36J <0.10 <0.09 <0.03 <0.071 <0.234 <0.094 <0.14 8/18/20 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <3.0 <2.0 <1.0 6/30/21 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.80 <0.40 <0.40 6/1/22 <0.09 <0.16 <0.13 <0.13 <0.11 <0.08 <0.15 <0.13 <0.11 <0.14 <0.11 <0.10 <1.00 <0.10 <0.28 <0.32 <0.10 <0.60 <0.17 <0.43 7/11/23 <0.079 <0.066 <0.085 <0.086 <0.069 <0.11 <0.14 <0.15 <0.072 <0.081 <0.11 <0.053 <0.10 <0.10 <0.09 <0.03 <0.071 <0.234 <0.094 <0.14 8/18/20 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <3.0 <2.0 <1.0 6/30/21 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.80 <0.40 <0.40 6/1/22 <0.09 <0.16 <0.13 <0.13 <0.11 <0.08 <0.15 <0.13 <0.11 <0.14 <0.11 <0.10 <1.00 <0.10 <0.28 <0.32 <0.10 <0.60 <0.17 <0.43 7/11/23 <0.079 <0.066 <0.085 <0.086 <0.069 <0.11 <0.14 <0.15 <0.072 <0.081 <0.11 <0.053 <0.10 <0.10 <0.09 <0.03 <0.071 <0.234 <0.094 <0.14 Notes: Bold values indicate constituent concentrations were greater than the 2L Standard. Yellow highlighted values indicate constituent concentrations were greater than the GCL. Samples presented prior to the May 31, 2023 event were obtained from prevous consultants reports. <## - less than the method detection limit µg/L - micrograms per liter 2L Standard - North Carolina 02L standard for groundwater GCL - Gross Contaminant Level J - Estimated concentration above the method detection limit and below the reporting limit. NR - not reported WSW-2 WSW-1 MW-12 MW-11 MW-13 Field Duplicate (MW-12)7/11/23 33.7 <0.066 0.55 0.50 <0.069 0.98 0.56 <0.15 19.1 0.30J 1.8 <0.053 0.69J <0.094 0.71<0.10 0.81 <0.031 <0.071 0.71 APPENDICES APPENDIX A APPENDIX B APPENDIX C ESP Corporate Office 3475 Lakemont Boulevard Fort Mill, SC 29708 803.802.2440 Mailing Address: P.O. Box 7030 Charlotte, NC 28241 800.960.7317 | www.espassociates.com Concord 7144 Weddington Rd. NW Suite 110 Concord, NC 28027 704.793.9855 Cornelius 20484 Chartwell Center Dr. Suite D Cornelius, NC 28031 704.649.2863 Raleigh 2200 Gateway Centre Blvd. Suite 216 Morrisville, NC 27560 919.678.1070 Greensboro 7011 Albert Pick Rd Suite E Greensboro, NC 27409 336.334.7724 Wilmington 211 Racine Drive Suite 101 Wilmington, NC 28403 910.313.6648 Charleston 2154 North Center Street Suite E-503 North Charleston, SC 29406 843.714.2040 Nashville 500 Wilson Pike Circle Suite 310 Brentwood, TN 37027 615.760.8300 Pittsburgh One Williamsburg Place Suite G-5, Box 13 Warrendale, PA 15086 724.462.6606 Bradenton 518 13th Street West Bradenton, FL 34205 941.345.5451 Indianapolis 8673 Bash Street Indianapolis, IN 46256 317.537.6979 Albuquerque 1203 West Ella Drive Corrales, NM 87048 505.314.1322 Birmingham 291 Cahaba Valley Parkway North Suite A Pelham, AL 35124 205.664.8498 Vickrey & Associates, LLC - An ESP Company San Antonio 12970 Country Parkway San Antonio TX 78216 210.349.3271 Austin 3600 West Parmer Lane Suite 175 Austin, TX 78727 512.494.8014 McAllen 1216 East Jasmine Avenue Suite C McAllen, TX 78501 956.340.0045