WS-4363_14151_CA_HRE_20131119_Bowman-POE-data

#=CL#
December 02, 2013
LIMS USE: FR - LINDA BLALOCK
LIMS OBJECT ID: 92180624
92180624
Project:
Pace Project No.:
RE:
Linda Blalock
NCDENR-UST Section
1637 Mail Service Canter
Raleigh, NC 276991637
HOWARD BOWMAN TF14151
Dear Linda Blalock:
Enclosed are the analytical results for sample(s) received by the laboratory on November 22, 2013.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
cc:Amber Shelor, Carbonair
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 1 of 16
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92180624
HOWARD BOWMAN TF14151
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 2 of 16
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92180624
HOWARD BOWMAN TF14151
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92180624001 D1 SM 6200B 63 PASI-CCAH
92180624002 D3 SM 6200B 63 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 3 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92180624
HOWARD BOWMAN TF14151
Sample:D1 Lab ID:92180624001 Collected:11/19/13 08:10 Received:11/22/13 09:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene 290 ug/L 11/23/13 13:55 71-43-22.0 4
Bromobenzene ND ug/L 11/23/13 13:55 108-86-12.0 4
Bromochloromethane ND ug/L 11/23/13 13:55 74-97-52.0 4
Bromodichloromethane ND ug/L 11/23/13 13:55 75-27-42.0 4
Bromoform ND ug/L 11/23/13 13:55 75-25-22.0 4
Bromomethane ND ug/L 11/23/13 13:55 74-83-920.0 4
n-Butylbenzene ND ug/L 11/23/13 13:55 104-51-82.0 4
sec-Butylbenzene ND ug/L 11/23/13 13:55 135-98-82.0 4
tert-Butylbenzene ND ug/L 11/23/13 13:55 98-06-62.0 4
Carbon tetrachloride ND ug/L 11/23/13 13:55 56-23-52.0 4
Chlorobenzene ND ug/L 11/23/13 13:55 108-90-72.0 4
Chloroethane ND ug/L 11/23/13 13:55 75-00-34.0 4
Chloroform ND ug/L 11/23/13 13:55 67-66-32.0 4
Chloromethane ND ug/L 11/23/13 13:55 74-87-34.0 4
2-Chlorotoluene ND ug/L 11/23/13 13:55 95-49-82.0 4
4-Chlorotoluene ND ug/L 11/23/13 13:55 106-43-42.0 4
1,2-Dibromo-3-chloropropane ND ug/L 11/23/13 13:55 96-12-84.0 4
Dibromochloromethane ND ug/L 11/23/13 13:55 124-48-12.0 4
1,2-Dibromoethane (EDB)ND ug/L 11/23/13 13:55 106-93-42.0 4
Dibromomethane ND ug/L 11/23/13 13:55 74-95-32.0 4
1,2-Dichlorobenzene ND ug/L 11/23/13 13:55 95-50-12.0 4
1,3-Dichlorobenzene ND ug/L 11/23/13 13:55 541-73-12.0 4
1,4-Dichlorobenzene ND ug/L 11/23/13 13:55 106-46-72.0 4
Dichlorodifluoromethane ND ug/L 11/23/13 13:55 75-71-82.0 4
1,1-Dichloroethane ND ug/L 11/23/13 13:55 75-34-32.0 4
1,2-Dichloroethane 10.0 ug/L 11/23/13 13:55 107-06-22.0 4
1,1-Dichloroethene ND ug/L 11/23/13 13:55 75-35-42.0 4
cis-1,2-Dichloroethene ND ug/L 11/23/13 13:55 156-59-22.0 4
trans-1,2-Dichloroethene ND ug/L 11/23/13 13:55 156-60-52.0 4
1,2-Dichloropropane ND ug/L 11/23/13 13:55 78-87-52.0 4
1,3-Dichloropropane ND ug/L 11/23/13 13:55 142-28-92.0 4
2,2-Dichloropropane ND ug/L 11/23/13 13:55 594-20-72.0 4
1,1-Dichloropropene ND ug/L 11/23/13 13:55 563-58-62.0 4
cis-1,3-Dichloropropene ND ug/L 11/23/13 13:55 10061-01-52.0 4
trans-1,3-Dichloropropene ND ug/L 11/23/13 13:55 10061-02-62.0 4
Diisopropyl ether 326 ug/L 11/23/13 13:55 108-20-32.0 4
Ethylbenzene ND ug/L 11/23/13 13:55 100-41-42.0 4
Hexachloro-1,3-butadiene ND ug/L 11/23/13 13:55 87-68-38.0 4
Isopropylbenzene (Cumene)5.0 ug/L 11/23/13 13:55 98-82-82.0 4
Methylene Chloride 8.7 ug/L 11/23/13 13:55 75-09-28.0 4
Methyl-tert-butyl ether 3.2 ug/L 11/23/13 13:55 1634-04-42.0 4
Naphthalene 24.3 ug/L 11/23/13 13:55 91-20-38.0 4
n-Propylbenzene 5.8 ug/L 11/23/13 13:55 103-65-12.0 4
Styrene ND ug/L 11/23/13 13:55 100-42-52.0 4
1,1,1,2-Tetrachloroethane ND ug/L 11/23/13 13:55 630-20-62.0 4
1,1,2,2-Tetrachloroethane ND ug/L 11/23/13 13:55 79-34-52.0 4
Tetrachloroethene ND ug/L 11/23/13 13:55 127-18-42.0 4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/02/2013 11:21 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 4 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92180624
HOWARD BOWMAN TF14151
Sample:D1 Lab ID:92180624001 Collected:11/19/13 08:10 Received:11/22/13 09:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene 2.4 ug/L 11/23/13 13:55 108-88-32.0 4
1,2,3-Trichlorobenzene ND ug/L 11/23/13 13:55 87-61-68.0 4
1,2,4-Trichlorobenzene ND ug/L 11/23/13 13:55 120-82-18.0 4
1,1,1-Trichloroethane ND ug/L 11/23/13 13:55 71-55-62.0 4
1,1,2-Trichloroethane ND ug/L 11/23/13 13:55 79-00-52.0 4
Trichloroethene ND ug/L 11/23/13 13:55 79-01-62.0 4
Trichlorofluoromethane ND ug/L 11/23/13 13:55 75-69-44.0 4
1,2,3-Trichloropropane ND ug/L 11/23/13 13:55 96-18-42.0 4
1,2,4-Trimethylbenzene 88.9 ug/L 11/23/13 13:55 95-63-62.0 4
1,3,5-Trimethylbenzene 14.9 ug/L 11/23/13 13:55 108-67-82.0 4
Vinyl chloride ND ug/L 11/23/13 13:55 75-01-44.0 4
m&p-Xylene 152 ug/L 11/23/13 13:55 179601-23-14.0 4
o-Xylene 100 ug/L 11/23/13 13:55 95-47-62.0 4
Surrogates
1,2-Dichloroethane-d4 (S)112 %11/23/13 13:55 17060-07-070-130 4
4-Bromofluorobenzene (S)100 %11/23/13 13:55 460-00-470-130 4
Toluene-d8 (S)95 %11/23/13 13:55 2037-26-570-130 4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/02/2013 11:21 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 5 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92180624
HOWARD BOWMAN TF14151
Sample:D3 Lab ID:92180624002 Collected:11/19/13 08:20 Received:11/22/13 09:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 11/23/13 12:19 71-43-20.50 1
Bromobenzene ND ug/L 11/23/13 12:19 108-86-10.50 1
Bromochloromethane ND ug/L 11/23/13 12:19 74-97-50.50 1
Bromodichloromethane ND ug/L 11/23/13 12:19 75-27-40.50 1
Bromoform ND ug/L 11/23/13 12:19 75-25-20.50 1
Bromomethane ND ug/L 11/23/13 12:19 74-83-95.0 1
n-Butylbenzene ND ug/L 11/23/13 12:19 104-51-80.50 1
sec-Butylbenzene ND ug/L 11/23/13 12:19 135-98-80.50 1
tert-Butylbenzene ND ug/L 11/23/13 12:19 98-06-60.50 1
Carbon tetrachloride ND ug/L 11/23/13 12:19 56-23-50.50 1
Chlorobenzene ND ug/L 11/23/13 12:19 108-90-70.50 1
Chloroethane ND ug/L 11/23/13 12:19 75-00-31.0 1
Chloroform ND ug/L 11/23/13 12:19 67-66-30.50 1
Chloromethane ND ug/L 11/23/13 12:19 74-87-31.0 1
2-Chlorotoluene ND ug/L 11/23/13 12:19 95-49-80.50 1
4-Chlorotoluene ND ug/L 11/23/13 12:19 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 11/23/13 12:19 96-12-81.0 1
Dibromochloromethane ND ug/L 11/23/13 12:19 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 11/23/13 12:19 106-93-40.50 1
Dibromomethane ND ug/L 11/23/13 12:19 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 11/23/13 12:19 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 11/23/13 12:19 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 11/23/13 12:19 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 11/23/13 12:19 75-71-80.50 1
1,1-Dichloroethane ND ug/L 11/23/13 12:19 75-34-30.50 1
1,2-Dichloroethane ND ug/L 11/23/13 12:19 107-06-20.50 1
1,1-Dichloroethene ND ug/L 11/23/13 12:19 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 11/23/13 12:19 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 11/23/13 12:19 156-60-50.50 1
1,2-Dichloropropane ND ug/L 11/23/13 12:19 78-87-50.50 1
1,3-Dichloropropane ND ug/L 11/23/13 12:19 142-28-90.50 1
2,2-Dichloropropane ND ug/L 11/23/13 12:19 594-20-70.50 1
1,1-Dichloropropene ND ug/L 11/23/13 12:19 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 11/23/13 12:19 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 11/23/13 12:19 10061-02-60.50 1
Diisopropyl ether ND ug/L 11/23/13 12:19 108-20-30.50 1
Ethylbenzene ND ug/L 11/23/13 12:19 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 11/23/13 12:19 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 11/23/13 12:19 98-82-80.50 1
Methylene Chloride ND ug/L 11/23/13 12:19 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 11/23/13 12:19 1634-04-40.50 1
Naphthalene ND ug/L 11/23/13 12:19 91-20-32.0 1
n-Propylbenzene ND ug/L 11/23/13 12:19 103-65-10.50 1
Styrene ND ug/L 11/23/13 12:19 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 11/23/13 12:19 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 11/23/13 12:19 79-34-50.50 1
Tetrachloroethene ND ug/L 11/23/13 12:19 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/02/2013 11:21 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 6 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92180624
HOWARD BOWMAN TF14151
Sample:D3 Lab ID:92180624002 Collected:11/19/13 08:20 Received:11/22/13 09:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene ND ug/L 11/23/13 12:19 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 11/23/13 12:19 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 11/23/13 12:19 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 11/23/13 12:19 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 11/23/13 12:19 79-00-50.50 1
Trichloroethene ND ug/L 11/23/13 12:19 79-01-60.50 1
Trichlorofluoromethane ND ug/L 11/23/13 12:19 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/23/13 12:19 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 11/23/13 12:19 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 11/23/13 12:19 108-67-80.50 1
Vinyl chloride ND ug/L 11/23/13 12:19 75-01-41.0 1
m&p-Xylene ND ug/L 11/23/13 12:19 179601-23-11.0 1
o-Xylene ND ug/L 11/23/13 12:19 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)118 %11/23/13 12:19 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %11/23/13 12:19 460-00-470-130 1
Toluene-d8 (S)97 %11/23/13 12:19 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/02/2013 11:21 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 7 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92180624
HOWARD BOWMAN TF14151
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/25016
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92180624001, 92180624002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1093108
Associated Lab Samples:92180624001, 92180624002
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 11/23/13 12:03
1,1,1-Trichloroethane ug/L ND 0.50 11/23/13 12:03
1,1,2,2-Tetrachloroethane ug/L ND 0.50 11/23/13 12:03
1,1,2-Trichloroethane ug/L ND 0.50 11/23/13 12:03
1,1-Dichloroethane ug/L ND 0.50 11/23/13 12:03
1,1-Dichloroethene ug/L ND 0.50 11/23/13 12:03
1,1-Dichloropropene ug/L ND 0.50 11/23/13 12:03
1,2,3-Trichlorobenzene ug/L ND 2.0 11/23/13 12:03
1,2,3-Trichloropropane ug/L ND 0.50 11/23/13 12:03
1,2,4-Trichlorobenzene ug/L ND 2.0 11/23/13 12:03
1,2,4-Trimethylbenzene ug/L ND 0.50 11/23/13 12:03
1,2-Dibromo-3-chloropropane ug/L ND 1.0 11/23/13 12:03
1,2-Dibromoethane (EDB)ug/L ND 0.50 11/23/13 12:03
1,2-Dichlorobenzene ug/L ND 0.50 11/23/13 12:03
1,2-Dichloroethane ug/L ND 0.50 11/23/13 12:03
1,2-Dichloropropane ug/L ND 0.50 11/23/13 12:03
1,3,5-Trimethylbenzene ug/L ND 0.50 11/23/13 12:03
1,3-Dichlorobenzene ug/L ND 0.50 11/23/13 12:03
1,3-Dichloropropane ug/L ND 0.50 11/23/13 12:03
1,4-Dichlorobenzene ug/L ND 0.50 11/23/13 12:03
2,2-Dichloropropane ug/L ND 0.50 11/23/13 12:03
2-Chlorotoluene ug/L ND 0.50 11/23/13 12:03
4-Chlorotoluene ug/L ND 0.50 11/23/13 12:03
Benzene ug/L ND 0.50 11/23/13 12:03
Bromobenzene ug/L ND 0.50 11/23/13 12:03
Bromochloromethane ug/L ND 0.50 11/23/13 12:03
Bromodichloromethane ug/L ND 0.50 11/23/13 12:03
Bromoform ug/L ND 0.50 11/23/13 12:03
Bromomethane ug/L ND 5.0 11/23/13 12:03
Carbon tetrachloride ug/L ND 0.50 11/23/13 12:03
Chlorobenzene ug/L ND 0.50 11/23/13 12:03
Chloroethane ug/L ND 1.0 11/23/13 12:03
Chloroform ug/L ND 0.50 11/23/13 12:03
Chloromethane ug/L ND 1.0 11/23/13 12:03
cis-1,2-Dichloroethene ug/L ND 0.50 11/23/13 12:03
cis-1,3-Dichloropropene ug/L ND 0.50 11/23/13 12:03
Dibromochloromethane ug/L ND 0.50 11/23/13 12:03
Dibromomethane ug/L ND 0.50 11/23/13 12:03
Dichlorodifluoromethane ug/L ND 0.50 11/23/13 12:03
Diisopropyl ether ug/L ND 0.50 11/23/13 12:03
Ethylbenzene ug/L ND 0.50 11/23/13 12:03
Hexachloro-1,3-butadiene ug/L ND 2.0 11/23/13 12:03
Isopropylbenzene (Cumene)ug/L ND 0.50 11/23/13 12:03
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/02/2013 11:21 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 8 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92180624
HOWARD BOWMAN TF14151
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1093108
Associated Lab Samples:92180624001, 92180624002
Matrix:Water
Analyzed
m&p-Xylene ug/L ND 1.0 11/23/13 12:03
Methyl-tert-butyl ether ug/L ND 0.50 11/23/13 12:03
Methylene Chloride ug/L ND 2.0 11/23/13 12:03
n-Butylbenzene ug/L ND 0.50 11/23/13 12:03
n-Propylbenzene ug/L ND 0.50 11/23/13 12:03
Naphthalene ug/L ND 2.0 11/23/13 12:03
o-Xylene ug/L ND 0.50 11/23/13 12:03
sec-Butylbenzene ug/L ND 0.50 11/23/13 12:03
Styrene ug/L ND 0.50 11/23/13 12:03
tert-Butylbenzene ug/L ND 0.50 11/23/13 12:03
Tetrachloroethene ug/L ND 0.50 11/23/13 12:03
Toluene ug/L ND 0.50 11/23/13 12:03
trans-1,2-Dichloroethene ug/L ND 0.50 11/23/13 12:03
trans-1,3-Dichloropropene ug/L ND 0.50 11/23/13 12:03
Trichloroethene ug/L ND 0.50 11/23/13 12:03
Trichlorofluoromethane ug/L ND 1.0 11/23/13 12:03
Vinyl chloride ug/L ND 1.0 11/23/13 12:03
1,2-Dichloroethane-d4 (S)%118 70-130 11/23/13 12:03
4-Bromofluorobenzene (S)%101 70-130 11/23/13 12:03
Toluene-d8 (S)%98 70-130 11/23/13 12:03
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1093109LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 53.750 107 60-140
1,1,1-Trichloroethane ug/L 55.950 112 60-140
1,1,2,2-Tetrachloroethane ug/L 48.950 98 60-140
1,1,2-Trichloroethane ug/L 51.850 104 60-140
1,1-Dichloroethane ug/L 47.650 95 60-140
1,1-Dichloroethene ug/L 55.650 111 60-140
1,1-Dichloropropene ug/L 53.650 107 60-140
1,2,3-Trichlorobenzene ug/L 53.250 106 60-140
1,2,3-Trichloropropane ug/L 52.350 105 60-140
1,2,4-Trichlorobenzene ug/L 51.550 103 60-140
1,2,4-Trimethylbenzene ug/L 53.350 107 60-140
1,2-Dibromo-3-chloropropane ug/L 55.150 110 60-140
1,2-Dibromoethane (EDB)ug/L 51.950 104 60-140
1,2-Dichlorobenzene ug/L 51.750 103 60-140
1,2-Dichloroethane ug/L 50.450 101 60-140
1,2-Dichloropropane ug/L 48.750 97 60-140
1,3,5-Trimethylbenzene ug/L 53.050 106 60-140
1,3-Dichlorobenzene ug/L 51.250 102 60-140
1,3-Dichloropropane ug/L 52.450 105 60-140
1,4-Dichlorobenzene ug/L 51.450 103 60-140
2,2-Dichloropropane ug/L 40.750 81 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/02/2013 11:21 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 9 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92180624
HOWARD BOWMAN TF14151
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1093109LABORATORY CONTROL SAMPLE:
LCSSpike
2-Chlorotoluene ug/L 51.750 103 60-140
4-Chlorotoluene ug/L 53.850 108 60-140
Benzene ug/L 50.850 102 60-140
Bromobenzene ug/L 51.950 104 60-140
Bromochloromethane ug/L 45.350 91 60-140
Bromodichloromethane ug/L 54.750 109 60-140
Bromoform ug/L 52.950 106 60-140
Bromomethane ug/L 74.5 CU,F3,L35014960-140
Carbon tetrachloride ug/L 56.550 113 60-140
Chlorobenzene ug/L 50.450 101 60-140
Chloroethane ug/L 41.450 83 60-140
Chloroform ug/L 49.250 98 60-140
Chloromethane ug/L 53.950 108 60-140
cis-1,2-Dichloroethene ug/L 47.250 94 60-140
cis-1,3-Dichloropropene ug/L 50.850 102 60-140
Dibromochloromethane ug/L 54.750 109 60-140
Dibromomethane ug/L 52.050 104 60-140
Dichlorodifluoromethane ug/L 53.150 106 60-140
Diisopropyl ether ug/L 49.250 98 60-140
Ethylbenzene ug/L 51.350 103 60-140
Hexachloro-1,3-butadiene ug/L 55.450 111 60-140
Isopropylbenzene (Cumene)ug/L 53.050 106 60-140
m&p-Xylene ug/L 103100 103 60-140
Methyl-tert-butyl ether ug/L 51.450 103 60-140
Methylene Chloride ug/L 51.450 103 60-140
n-Butylbenzene ug/L 53.950 108 60-140
n-Propylbenzene ug/L 53.250 106 60-140
Naphthalene ug/L 53.850 108 60-140
o-Xylene ug/L 51.450 103 60-140
sec-Butylbenzene ug/L 53.350 107 60-140
Styrene ug/L 52.350 105 60-140
tert-Butylbenzene ug/L 54.050 108 60-140
Tetrachloroethene ug/L 52.450 105 60-140
Toluene ug/L 51.250 102 60-140
trans-1,2-Dichloroethene ug/L 52.350 105 60-140
trans-1,3-Dichloropropene ug/L 51.950 104 60-140
Trichloroethene ug/L 51.450 103 60-140
Trichlorofluoromethane ug/L 50.650 101 60-140
Vinyl chloride ug/L 51.750 103 60-140
1,2-Dichloroethane-d4 (S)%106 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%106 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/02/2013 11:21 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 10 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92180624
HOWARD BOWMAN TF14151
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1093536MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92180624002
1093537
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 106 60-140120 1220ND21.2 24.0
1,1,1-Trichloroethane ug/L 20 105 60-140130 2220ND21.0 26.1
1,1,2,2-Tetrachloroethane ug/L 20 111 60-140113 220ND22.1 22.5
1,1,2-Trichloroethane ug/L 20 112 60-140116 420ND22.4 23.2
1,1-Dichloroethane ug/L 20 99 60-140119 1820ND19.8 23.7
1,1-Dichloroethene ug/L 20 100 60-140135 3020ND20.0 27.0
1,1-Dichloropropene ug/L 20 101 60-140131 2520ND20.3 26.2
1,2,3-Trichlorobenzene ug/L 20 106 60-140114 720ND21.3 22.8
1,2,3-Trichloropropane ug/L 20 113 60-140114 120ND22.6 22.8
1,2,4-Trichlorobenzene ug/L 20 100 60-140111 1020ND20.1 22.2
1,2,4-Trimethylbenzene ug/L 20 101 60-140136 2920ND20.2 27.1
1,2-Dibromo-3-chloropropane ug/L 20 109 60-140119 920ND21.8 23.9
1,2-Dibromoethane (EDB)ug/L 20 111 60-140122 920ND22.2 24.4
1,2-Dichlorobenzene ug/L 20 105 60-140116 1020ND21.0 23.2
1,2-Dichloroethane ug/L 20 112 60-140121 820ND22.4 24.2
1,2-Dichloropropane ug/L 20 99 60-140116 1520ND19.8 23.2
1,3,5-Trimethylbenzene ug/L 20 98 60-140116 1720ND19.6 23.1
1,3-Dichlorobenzene ug/L 20 99 60-140113 1320ND19.8 22.6
1,3-Dichloropropane ug/L 20 114 60-140121 620ND22.8 24.2
1,4-Dichlorobenzene ug/L 20 101 60-140111 1020ND20.1 22.3
2,2-Dichloropropane ug/L 20 101 60-140136 2920ND20.3 27.2
2-Chlorotoluene ug/L 20 96 60-140115 1820ND19.2 23.1
4-Chlorotoluene ug/L 20 102 60-140117 1420ND20.3 23.5
Benzene ug/L 20 101 60-140116 1420ND20.1 23.2
Bromobenzene ug/L 20 99 60-140112 1220ND19.8 22.5
Bromochloromethane ug/L 20 105 60-140110 520ND21.0 22.1
Bromodichloromethane ug/L 20 117 60-140117 020ND23.5 23.4
Bromoform ug/L 20 114 60-140119 520ND22.7 23.9
Bromomethane ug/L M02016060-140195 1920ND32.1 38.9
Carbon tetrachloride ug/L 20 101 60-140118 1620ND20.2 23.6
Chlorobenzene ug/L 20 102 60-140114 1120ND20.4 22.7
Chloroethane ug/L 20 82 60-140104 2420ND16.3 20.9
Chloroform ug/L 20 100 60-140118 1620ND20.1 23.6
Chloromethane ug/L 20 107 60-140128 1820ND21.5 25.7
cis-1,2-Dichloroethene ug/L 20 95 60-140115 1820ND19.1 22.9
cis-1,3-Dichloropropene ug/L 20 106 60-140114 720ND21.2 22.8
Dibromochloromethane ug/L 20 112 60-140126 1220ND22.5 25.2
Dibromomethane ug/L 20 109 60-140112 220ND21.8 22.3
Dichlorodifluoromethane ug/L 20 85 60-140114 3020ND17.0 22.9
Diisopropyl ether ug/L 20 110 60-140122 1120ND21.9 24.5
Ethylbenzene ug/L 20 100 60-140117 1620ND19.9 23.3
Hexachloro-1,3-butadiene ug/L 20 97 60-140132 3020ND19.5 26.3
Isopropylbenzene (Cumene)ug/L 20 100 60-140119 1720ND19.9 23.8
m&p-Xylene ug/L 40 102 60-140120 1640ND40.9 47.8
Methyl-tert-butyl ether ug/L 20 119 60-140129 820ND23.8 25.8
Methylene Chloride ug/L 20 128 60-140109 1620ND25.5 21.8
n-Butylbenzene ug/L 20 96 60-140120 2220ND19.2 23.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/02/2013 11:21 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 11 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92180624
HOWARD BOWMAN TF14151
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1093536MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92180624002
1093537
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Propylbenzene ug/L 20 98 60-140118 1820ND19.6 23.6
Naphthalene ug/L 20 109 60-140110 220ND21.7 22.1
o-Xylene ug/L 20 104 60-140118 1220ND20.8 23.5
sec-Butylbenzene ug/L 20 96 60-140119 2220ND19.2 23.9
Styrene ug/L 20 102 60-140119 1520ND20.4 23.8
tert-Butylbenzene ug/L 20 97 60-140119 2020ND19.4 23.7
Tetrachloroethene ug/L 20 98 60-140120 2120ND19.5 24.1
Toluene ug/L 20 98 60-140109 1120ND19.6 21.9
trans-1,2-Dichloroethene ug/L 20 102 60-140130 2420ND20.5 26.0
trans-1,3-Dichloropropene ug/L 20 110 60-140117 620ND22.0 23.4
Trichloroethene ug/L 20 98 60-140117 1820ND19.6 23.4
Trichlorofluoromethane ug/L 20 88 60-140117 2920ND17.5 23.5
Vinyl chloride ug/L R1209160-140132 3620ND18.3 26.3
1,2-Dichloroethane-d4 (S)%110 70-130104
4-Bromofluorobenzene (S)%99 70-130100
Toluene-d8 (S)%105 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/02/2013 11:21 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 12 of 16
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92180624
HOWARD BOWMAN TF14151
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The continuing calibration for this compound is outside of Pace Analytical acceptance limits. Analyte presence below
reporting limits in associated samples. Results unaffected by high bias.CU
The recovery of the second source standard used to verify the initial calibration curve for this analyte is outside the
laboratory's control limits. The result is estimated.F3
Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.L3
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/02/2013 11:21 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 13 of 16
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92180624
HOWARD BOWMAN TF14151
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92180624001 MSV/25016D1SM 6200B
92180624002 MSV/25016D3SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/02/2013 11:21 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 14 of 16
Page 15 of 16
Page 16 of 16