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HomeMy WebLinkAboutRA-2181_13379_CA_LTTRPT_20231003_RDC_Report WithersRavenel Our People. Your Success.    115 MacKenan Drive | Cary, NC 27511  t: 919.469.3340 | f: 919.467.6008 | www.withersravenel.com | License No. F‐1479  Asheville | Cary | Charlotte | Greensboro | Lumberton | Pittsboro | Raleigh | Southern Pines | Wilmington     October 3, 2023    State of North Carolina  Department of Environmental Quality  Federal & State Lead Program  Division of Waste Management‐Underground Storage Tank Section  1646 Mail Service Center  Raleigh, North Carolina 27699‐1646    Attn: Mr. Mark Petermann    Reference:   Letter Report – Remedial Design Characterization  Arvin Oil Company  5837 & 5839 Fayetteville Road (US Hwy. 401)   Raleigh, Wake County, North Carolina  Groundwater Incident Number: 13379  UST Number: RA‐2181  NCDEQ Contract # N70522‐C  WR Project Number:  23‐0307‐N    Mr. Petermann:     WithersRavenel, Inc. (WR) has prepared this Letter Report documenting the completion of a  Remedial Design Characterization (RDC) at the referenced site in Raleigh, Wake County, North  Carolina.  Activities outlined herein were completed under NCDEQ Contract # N70522‐C, Task  Authorization (TA) 02 for the site, issued by NCDEQ on April 28, 2023.  WR Requested an  extension to the due date for this TA awaiting receipt of ASTs completed RDC, and the due date  was extended to October 20, 2023.  WR Did not receive ASTs report until September 29, 2023.      Remedial Design Characterization – June 2023    On June 16, 2023, WR personnel, along with AST Environmental, Inc. (AST) and South Atlantic  Environmental Drilling and Construction Co. Inc. (SAEDACCO) mobilized to the site and completed  a remedial design characterization focused on determining the optimal future use of BOS200®  activated carbon as a remedial treatment for groundwater contamination related to the site.    The RDC included the installation and sampling of a total of 2 soil borings (RDC‐01 & RDC‐02),  extending from surface grade to terminal depths between 32‐ and 33‐ft beneath surface grade.   Characterization also included the collection of groundwater samples through a screen point  sampler at discreet depths within borings.  Existing monitoring wells MW‐3R, MW‐4, MW‐8 and  MW‐8R were also developed and sampled.  Soil and groundwater samples collected in association  with the RDC were submitted by AST for laboratory analysis by the RPI Project Support Laboratory  in Golden, CO.        Findings of the RDC and recommendations based on those findings are discussed in ASTs report,  a copy of which is attached.      WithersRavenel Our People. Your Success.    Arvin Oil Company – Incident # 13379 WR Project # 23‐0307‐N  Letter Report – Remedial Design Characterization  October 2023  2        ASTs Investigation mapped contaminant concentrations in soil and groundwater at depth showing  the extents of the petroleum contaminant plume.  Based on their characterization, AST generated  a remedial plan utilizing their BOS 200 injectable treatment product.  The treatment plan consists  of a treatment area generally centered on monitoring well MW‐3R and ASTs pricing associated  with the treatment area are show below:    Treatment Area (See attached AST Report) Estimated Injection  Cost  Area A $61,890    Locations and extents of the proposed treatment area as well as treatment volume calculations  are shown in the attached AST RDC report.    As AST was unable to complete the originally proposed RDC in a single day, WR attempted to  obtain authorization (both via phone and in‐person) from the site owner’s son (Michael Arvin) to  complete the additional borings initially proposed.  Mr. Arvin flatly denied further access to the  property and stated that no access would be considered unless the NCDEQ Incident Manager (Mr.  Mark Petermann) personally came to the site to discuss the matter.  According to Mr. Petermann  he contacted Mr. Michael Arvin by telephone on September 27, 2023, to discuss his concerns and  arrange for a mutually acceptable meeting date. Mr. Arvin stated that a site meeting would not be  necessary. Mr. Arvin further stated there would be no future access allowed to the property for  any additional assessment, remediation or monitoring.     WithersRavenel appreciates the opportunity to be of service to the Federal & State Lead Program.  Should you have any questions regarding the attached, please do not hesitate to contact  WithersRavenel at (919) 469‐3340.    Cordially,  WithersRavenel   Kevin B. Buchanan G. Matthew James, P.G.  Project Manager Director of Geosciences    Enclosures: AST Environmental RDC Report, Site Photographs                             ATTACHMENT A    AST Environmental RDC Report                     1567 CF Pours Harrisonburg, VA 22802 www.astenvironmental.com September 29, 2023 Mr. Kevin Buchanan Withers Ravenel 115 Mackenan Dr. Cary, NC 27511 RE: Quantitative High Resolution Site Characterization Report Arvin Oil Co. 711 N Main Street Wake Forest, North Carolina Dear Mr. Buchanan, AST Environmental, Inc. (AST) appreciates the opportunity to collaborate with Withers Ravenel and NCDEQ to complete the Quantitative High Resolution Site Characterization (qHRSC) at the above referenced location. The proposed scope of work was to complete 4 soil borings to approximately 45 ft-bgs. The overall goal of this qHRSC program is to: 1. Quantify the TVPH and benzene soil concentrations, on site and off. 2. Provide a visual interpolation of a high-resolution data set to aid in future investigation and remedial activities. 3. Design a BOS 200+ injection plan to bring groundwater concentrations in compliance with regulatory requirements. This letter report provides a summary of field activities during the RDC and an overview of analytical soil and groundwater data. REMEDIAL DESIGN CHARACTERIZATION On June 16, 2023 AST mobilized to the site to begin direct push drilling with the Geologic Exploration (GEX) drilling team. The GEX crew arrived late to the site, causing only two of the planned four borings being advanced. During the RDC event, a total of 2 soil borings were advanced via direct push drilling by GEX using their Geoprobe 3230. At each boring location, a 2.25 inch diameter direct push, dual tube tooling was advanced in five foot runs. Samples were collected every two feet beginning at PID or olfactory presence of hydrocarbon mass. All intervals were logged for lithology and PID readings were collected to guide the sampling process. Soil samples were collected and shipped to the RPI Project Support Laboratory in Golden, CO for VOC and Total Volatile Petroleum Hydrocarbon (TVPH) analysis via EPA method 8260B. Soil data has been tabulated and is included in the attachments as Table 1. Although this data is used for injection design purposes, the lab is not a certified or accredited laboratory, this data should not be used for regulator or compliance purposes. Existing monitoring wells MW-03R, MW-04, MW-08, and MW-08R, along with temporary wells set at RDC-01 (MW-04) and RDC-2 (MW-03R) were developed and sampled. Groundwater samples were shipped to the RPI Project Support Laboratory in Golden, CO for VOC and Total Volatile Petroleum Hydrocarbon (TVPH) analysis via EPA method 8260B, anions via EPA method 300.1 and dissolved gases via EPA method RSK 175. Groundwater data has been tabulated and is included in the attachments as Table 2, Table 3, and Table 4. Boring logs for each location are included in Attachment B. Arvin Oil Co. September 29, 2023 Page 2 Conclusions and Recommendations As indicated above, the ITRC LNAPL Guidance Document states that TVPH concentrations indicative of residual LNAPL in the subsurface are between 250 and 500 mg/kg, depending on the soil type. Based on the data collected during the RDC event, the subsurface distribution of residual LNAPL is minimal and confined to the area immediately surrounding and below the former tank pit. Groundwater in RDC-02 indicate benzene in concentrations greater than 5,000 ug/L, while RDC- 01, MW-03R, MW-04, and MW-08 show concentrations above 1 ug/L. Based on the data generated during this qHRSC, AST recommends that a BOS 200+ injection program be considered to reach the groundwater goal of 2L at this site. Based on the GCL remediation goal of 5,000 ug/L benzene, and the elevated soil mass present in the injection area, a BOS 200+ plan has been completed that includes supplemental additives to increase the rate of degradation on the activated carbon surface and prolong the ability of the facultative microbes to continue the degradation process for years. BOS 200+ INJECTION DESIGN – SEE ATTACHED FOR DESIGN LOADINGS & FIGURE FOR LOCATIONS BOS 200® provides the unique capability (Trap & Treat® process) to utilize two proven and powerful technologies that rapidly and effectively remediate petroleum hydrocarbon sites: 1) Trapping of the contaminants via activated carbon adsorption. 2) Subsequent treatment via biological degradation within the BOS 200® matrix utilizing both aerobic and anaerobic microbial processes. The “Trap” provides the immediate mass reduction and plume control, while the “Treat” provides the continued long-term remedial degradation using synergistic facultative bacteria. No other activated carbon product can emplace a biological treatment mechanism on activated carbon for injection; this intellectual property is protected by RPI patents. AST is designed by RPI as the product design arm and distributor for the RPI Group. BOS 200® is a fine-grained, dry material which consists of activated carbon, calcium sulfate, nitrate, phosphate, and ammonia in a proprietary blend. It is 77% by weight activated carbon and up to 19% gypsum. The gypsum component itself is 79% by weight sulfate, which translates to approximately 15% by weight sulfate in BOS 200®. The product is mixed with water and a facultative blend of aerobic and anaerobic microbes to create a solids suspension. This is now an ideal environment for biological degradation, where hydrocarbons are adsorbed on to BOS 200® particles made up of: • Terminal Electron Acceptors: oxygen, nitrate, ammonia, and sulfate (primary) • Micro- and Macro-Nutrients - phosphorus and nitrogen • Aerobic and anaerobic blend of facultative microbes (over 27 species) On flexibility, with BOS 200® product, the design approach can vary from a treatment objective where complete and immediate contaminant mass removal from the groundwater is achieved, to a partial contaminant mass reduction working in conjunction with biological degradation driving the groundwater cleanup effort, or any combination somewhere in between. The end effect is that the plume can be controlled in a short period of time and treatment can be extended over a longer period. The BOS 200® injection design has been prepared for each area using the following approach/basis: 1. RDC and historical data from soil and groundwater sampling (i.e., analytical results, the Arvin Oil Co. September 29, 2023 Page 3 screened interval of the wells, the soil sampling depth intervals) were used to determine the vertical and horizontal extent of impacts in each area. 2. Using the same data for each area a contaminant mass loading on a unit basis (lb. benzene per ft3 of impacted media) was determined for each of the designated areas. 3. The contaminant mass loadings were then used to determine the BOS 200® loadings (lbs. installed per ft3 of impacted media) necessary to remediate a specific depth interval within each injection area. This is a balance between the need to have an immediate mass reduction or to allow the biological process to be the controlling process. This is specifically discussed for each area below. 4. Quarterly monitoring of the dissolved phase contaminant trends (BTEX, TVPH), along with terminal electron acceptor consumption will dictate if/when a second additional event occurs. POST INJECTION SAMPLING Following the injection, AST will collect groundwater samples from all of the monitoring wells within the injection area prior to demobilizing. AST recommends performance progress groundwater sampling events at intervals of one week, two weeks, one-month post injection and quarterly until remediation goals are obtained. AST understands that this will be performed by others. The performance samples can be sent to Remediation Products, Ince. Laboratory in Golden, CO for no cost of analyses. The cost of shipment will be the responsibility of the consultant. The analyses will be consistent with that described previously. If you have any questions or wish to discuss the information provided herein, please contact me at (540) 820-3465 or via email at nthacker@astenv.com. Sincerely, AST Environmental, Inc. Nathan Thacker Senior Geologist Figures CROWN FLOORING LLC(FORMER GAS STATION)FORMERUSTAREACONCRE T E S L A BMW-2RMW-10MW-7MW-6RMW-3RMWD-7MW-1MWD-9MWD-6WSW-2RESIDENCERESIDENCERESIDENCEFAYETTEVILLE ROAD(HIGHWAY 401)GARAGE/STORAGEBUILDINGWOODENSHEDMWD-14MWD-15MW-11MW-12MWD-13MW-16MW-17MWD-17MW-8MW-4MWD-5FORMER HYDRAULICLIFT AREAESTIMATED EXTENT OF BENZENE ATCONCENTRATIONS EXCEEDING 2LSTANDARD - SURFICIAL AQUIFER1.01.0(<0.5)(0.893)(1,540)(10.9)(<0.5)(<0.5)(5,020)(<0.5)(<0.5)(<0.5)(<0.5)(<0.5)(<0.5)(<0.5)(<0.5)(<0.5)(<0.5)(<0.5)(<0.5)(<0.5)LEGEND WATER SUPPLY WELL TYPE II MONITORING WELL BENZENE CONCENTRATION ESTIMATED EXTENT OF GROUNDWATER BENZENE CONTAMINATION AT LEVELS EXCEEDING NC 2L STANDARD (1.0 ug/L)NOTES: 1.) 2021 AERIAL OBTAINED FROM NC ONE MAP. 2.) ALL DATA SHOWN IN ug/L. 3.) VALUES SHOWN IN RED EXCEED NC GCL FOR BENZENE.(1,540)GROUNDWATER BENZENEISOCONCENTRATION MAP MARCH 2023 DRAWN BY: 5 SCALE:FIGURE NO.: PROJECT NO.:DATE:APPROVED BY: ARVIN OIL COMPANYTF#13379 5837 & 5839 FAYETTEVILLE ROAD (US HIGHWAY 401)RALEIGH, WAKE COUNTY, NC WithersRavenel Engineers | Planners | Surveyors 115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340 | license #: F-1479 | www.withersravenel.com 1"=30 'GRAPHIC SCALE1 inch = 30 ft.0301560KBB MJ 04/05/2023 23-0307-N Tables Table 1 Soil Analytical Results mg/Kg Dimethyl SulfideMTBE1,2-DichloroethaneBenzeneTolueneEthylbenzenem/p-Xyleneo-XyleneTotal Xylene1,2,4-TrimethylbenzeneNaphthaleneTVPHRDC-01 6/8/2023 11 0 <0.5 <0.5 <0.5 <0.5 2.1 0.7 3.3 1.7 5 3.2 <0.5 <0.5 RDC-01 6/8/2023 13 0 <0.5 <0.5 <0.5 <0.5 1.1 <0.5 2.3 1 3.3 3.6 <0.5 <0.5 RDC-01 6/8/2023 15 0 <0.5 <0.5 <0.5 <0.5 1.3 <0.5 2.1 0.9 3 1.5 <0.5 <0.5 RDC-01 6/8/2023 17 0 <0.5 <0.5 <0.5 <0.5 1.2 <0.5 2 0.9 2.9 1.6 <0.5 <0.5 RDC-01 6/8/2023 19 0 <0.5 <0.5 <0.5 <0.5 1.3 <0.5 2.1 0.9 3 1.7 <0.5 <0.5 RDC-01 6/8/2023 21 0 <0.5 <0.5 <0.5 1.9 14 3 14 6.1 20.1 5.4 <0.5 <0.5 RDC-01 6/8/2023 23 0 <0.5 <0.5 <0.5 <0.5 1 <0.5 1.2 0.7 1.9 1.3 <0.5 <0.5 RDC-01 6/8/2023 25 0 <0.5 <0.5 <0.5 3.2 19 4.1 44 23 67 40 8.7 2.4 RDC-01 6/8/2023 27.5 118.2 <10 <10 <10 130 2900 2200 11200 4700 15900 14600 1700 250 RDC-01 6/8/2023 29 98.9 <10 <10 <10 170 2100 710 3100 1300 4400 3600 420 44 RDC-01 6/8/2023 31 594.6 <50 <50 <50 440 11400 6700 26300 10400 36700 22600 2900 340 RDC-01 6/8/2023 32 118.7 <10 <10 <10 530 4900 800 2900 1400 4300 1100 210 24 RDC-02 6/8/2023 11 0 <0.5 23 <0.5 <0.5 3.8 1.1 5.3 2.6 7.9 6.3 3.5 <0.5 RDC-02 6/8/2023 13 0 <0.5 25 <0.5 <0.5 2.6 1 4.8 2.2 7 6 2.8 <0.5 RDC-02 6/8/2023 15 0 <0.5 52 <0.5 <0.5 1.9 0.6 3 1.4 4.4 3.4 1.4 <0.5 RDC-02 6/8/2023 17 0 <0.5 66 <0.5 <0.5 2.2 0.8 4.1 2.1 6.2 4.5 <0.5 <0.5 RDC-02 6/8/2023 19 0 <0.5 140 <0.5 <0.5 1.8 0.6 3 1.2 4.2 3 0.9 0.6 RDC-02 6/8/2023 21 0 <0.5 200 4.2 <0.5 2.2 0.6 2.9 1.4 4.3 2.5 1.4 0.7 RDC-02 6/8/2023 23 0 <0.5 150 <0.5 <0.5 1.9 <0.5 2.2 1 3.2 2.1 <0.5 0.8 RDC-02 6/8/2023 25 8 <10 110 <10 <10 24 <10 25 29 54 43 19 <10 RDC-02 6/8/2023 27 39.3 <10 130 <10 160 1600 330 1600 960 2560 750 150 18 RDC-02 6/8/2023 29 242 <10 51 <10 330 3700 1000 4200 2000 6200 2500 350 41 RDC-02 6/8/2023 31 157 <10 <10 <10 660 4700 710 2700 1300 4000 1100 200 24 RDC-02 6/8/2023 33 122 <10 <10 <10 560 4000 470 1800 950 2750 540 110 15 Facility name: Withers - Arvin Oil Table 1 Soil Analytical Results Chemical of concern (ug/kg) Sample location Sample date Sample depth (ft) PID or OVD reading (ppm) Table 2 Water Analytical Results Dimethyl SulfideMTBE1,2-DichloroethaneBenzeneTolueneEthylbenzenem/p-Xyleneo-XyleneTotal Xylene1,2,4-TrimethylbenzeneNaphthaleneTVPHMW-3R 6/8/2023 30 <0.5 71 <0.5 3900 20000 3200 11200 5800 17000 2500 690 74 MW-4 6/8/2023 30 <10 <10 <10 520 3700 700 2900 1400 4300 1400 880 23 MW-8 6/8/2023 30 <0.5 <0.5 <0.5 5.3 15 6.9 30 19 49 13 8.9 <0.5 MW-8R 6/8/2023 30 <0.5 1.9 <0.5 0.6 3.9 0.8 3.3 2 5.3 2.5 2.8 <0.5 RDC-01 6/8/2023 30 <5 13 <5 2200 12200 2900 8600 4500 13100 3000 960 78 RDC-02 6/8/2023 30 <0.5 <0.5 <0.5 5100 26400 4200 14100 7200 21300 3100 710 91 Facility name: Withers - Arvin Oil Table 2 Water Analytical Results Sample location Sample date Sample Depth Chemical of Concern (mg/L) Attachment A RPI Laboratory Analytical Data Arvin Oil Sample ID. No.RDC-01 RDC-01 RDC-01 Date Sampled 6/8/2023 6/8/2023 6/8/2023 Sample Depth 11 ft 13 ft 15 ft Reporting Limit Units Flags Reporting Limit Units Flags Reporting Limit Units Flags Dimethyl Sulfide ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg MTBE ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg 1,2-Dichloroethane ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg Benzene ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg Toluene 2.1 0.5 ug/Kg 1.1 0.5 ug/Kg 1.3 0.5 ug/Kg Ethylbenzene 0.7 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg m/p-Xylene 3.3 0.5 ug/Kg 2.3 0.5 ug/Kg 2.1 0.5 ug/Kg o-Xylene 1.7 0.5 ug/Kg 1 0.5 ug/Kg 0.9 0.5 ug/Kg 1,2,4-Trimethylbenzene 3.2 0.5 ug/Kg 3.6 0.5 ug/Kg 1.5 0.5 ug/Kg Naphthalene ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg TVPH ND 0.5 mg/Kg ND 0.5 mg/Kg ND 0.5 mg/Kg % Surrogate Recovery 1,2-Dichloroethane-d4 70 86 80 d8-Toluene 97 99 97 p-Bromofluorobenzene 94 97 97 Arvin Oil Sample ID. No. Date Sampled Sample Depth Dimethyl Sulfide MTBE 1,2-Dichloroethane Benzene Toluene Ethylbenzene m/p-Xylene o-Xylene 1,2,4-Trimethylbenzene Naphthalene TVPH % Surrogate Recovery 1,2-Dichloroethane-d4 d8-Toluene p-Bromofluorobenzene RDC-01 RDC-01 6/8/2023 6/8/2023 17 ft 19 ft Reporting Limit Units Flags Reporting Limit Units Flags ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg 1.2 0.5 ug/Kg 1.3 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg 2 0.5 ug/Kg 2.1 0.5 ug/Kg 0.9 0.5 ug/Kg 0.9 0.5 ug/Kg 1.6 0.5 ug/Kg 1.7 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 mg/Kg ND 0.5 mg/Kg 92 85 99 96 99 96 Arvin Oil Sample ID. No. Date Sampled Sample Depth Dimethyl Sulfide MTBE 1,2-Dichloroethane Benzene Toluene Ethylbenzene m/p-Xylene o-Xylene 1,2,4-Trimethylbenzene Naphthalene TVPH % Surrogate Recovery 1,2-Dichloroethane-d4 d8-Toluene p-Bromofluorobenzene RDC-01 RDC-01 6/8/2023 6/8/2023 21 ft 23 ft Reporting Limit Units Flags Reporting Limit Units Flags ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg 1.9 0.5 ug/Kg ND 0.5 ug/Kg 14 0.5 ug/Kg 1 0.5 ug/Kg 3 0.5 ug/Kg ND 0.5 ug/Kg 14 0.5 ug/Kg 1.2 0.5 ug/Kg 6.1 0.5 ug/Kg 0.7 0.5 ug/Kg 5.4 0.5 ug/Kg 1.3 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 mg/Kg ND 0.5 mg/Kg 112 96 100 97 99 96 Sample ID. No.RDC-01 RDC-01 RDC-01 Date Sampled 6/8/2023 6/8/2023 6/8/2023 Sample Depth 25 ft 27.5 ft 29 ft Reporting Limit Units Flags Reporting Limit Units Flags Reporting Limit Units Flags Dimethyl Sulfide ND 0.5 ug/Kg ND 10 ug/Kg ND 10 ug/Kg MTBE ND 0.5 ug/Kg ND 10 ug/Kg ND 10 ug/Kg 1,2-Dichloroethane ND 0.5 ug/Kg ND 10 ug/Kg ND 10 ug/Kg Benzene 3.2 0.5 ug/Kg 130 10 ug/Kg 170 10 ug/Kg Toluene 19 0.5 ug/Kg 2900 10 ug/Kg 2100 10 ug/Kg Ethylbenzene 4.1 0.5 ug/Kg 2200 10 ug/Kg 710 10 ug/Kg m/p-Xylene 44 0.5 ug/Kg 11200 10 ug/Kg 3100 10 ug/Kg o-Xylene 23 0.5 ug/Kg 4700 10 ug/Kg 1300 10 ug/Kg 1,2,4-Trimethylbenzene 40 0.5 ug/Kg 14600 10 ug/Kg E 3600 10 ug/Kg Naphthalene 8.7 0.5 ug/Kg 1700 10 ug/Kg 420 10 ug/Kg TVPH 2.4 0.5 mg/Kg 250 10 mg/Kg 44 10 mg/Kg % Surrogate Recovery 1,2-Dichloroethane-d4 91 101 101 d8-Toluene 102 104 103 p-Bromofluorobenzene 101 105 94 Sample ID. No. Date Sampled Sample Depth Dimethyl Sulfide MTBE 1,2-Dichloroethane Benzene Toluene Ethylbenzene m/p-Xylene o-Xylene 1,2,4-Trimethylbenzene Naphthalene TVPH % Surrogate Recovery 1,2-Dichloroethane-d4 d8-Toluene p-Bromofluorobenzene RDC-01 RDC-01 6/8/2023 6/8/2023 31 ft 32 ft Reporting Limit Units Flags Reporting Limit Units Flags ND 50 ug/Kg ND 10 ug/Kg ND 50 ug/Kg ND 10 ug/Kg ND 50 ug/Kg ND 10 ug/Kg 440 50 ug/Kg 530 10 ug/Kg 11400 50 ug/Kg 4900 10 ug/Kg 6700 50 ug/Kg 800 10 ug/Kg 26300 50 ug/Kg 2900 10 ug/Kg 10400 50 ug/Kg 1400 10 ug/Kg 22600 50 ug/Kg 1100 10 ug/Kg 2900 50 ug/Kg 210 10 ug/Kg 340 50 mg/Kg 24 10 mg/Kg 99 102 103 102 102 96 Sample ID. No. Date Sampled Sample Depth Dimethyl Sulfide MTBE 1,2-Dichloroethane Benzene Toluene Ethylbenzene m/p-Xylene o-Xylene 1,2,4-Trimethylbenzene Naphthalene TVPH % Surrogate Recovery 1,2-Dichloroethane-d4 d8-Toluene p-Bromofluorobenzene Sample ID. No.RDC-02 RDC-02 RDC-02 Date Sampled 6/8/2023 6/8/2023 6/8/2023 Sample Depth 11 ft 13 ft 15 ft Reporting Limit Units Flags Reporting Limit Units Flags Reporting Limit Units Flags Dimethyl Sulfide ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg MTBE 23 0.5 ug/Kg 25 0.5 ug/Kg 52 0.5 ug/Kg 1,2-Dichloroethane ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg Benzene ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg Toluene 3.8 0.5 ug/Kg 2.6 0.5 ug/Kg 1.9 0.5 ug/Kg Ethylbenzene 1.1 0.5 ug/Kg 1 0.5 ug/Kg 0.6 0.5 ug/Kg m/p-Xylene 5.3 0.5 ug/Kg 4.8 0.5 ug/Kg 3 0.5 ug/Kg o-Xylene 2.6 0.5 ug/Kg 2.2 0.5 ug/Kg 1.4 0.5 ug/Kg 1,2,4-Trimethylbenzene 6.3 0.5 ug/Kg 6 0.5 ug/Kg 3.4 0.5 ug/Kg Naphthalene 3.5 0.5 ug/Kg 2.8 0.5 ug/Kg 1.4 0.5 ug/Kg TVPH ND 0.5 mg/Kg ND 0.5 mg/Kg ND 0.5 mg/Kg % Surrogate Recovery 1,2-Dichloroethane-d4 74 66 73 d8-Toluene 99 97 97 p-Bromofluorobenzene 101 97 99 Sample ID. No. Date Sampled Sample Depth Dimethyl Sulfide MTBE 1,2-Dichloroethane Benzene Toluene Ethylbenzene m/p-Xylene o-Xylene 1,2,4-Trimethylbenzene Naphthalene TVPH % Surrogate Recovery 1,2-Dichloroethane-d4 d8-Toluene p-Bromofluorobenzene RDC-02 RDC-02 6/8/2023 6/8/2023 17 ft 19 ft Reporting Limit Units Flags Reporting Limit Units Flags ND 0.5 ug/Kg ND 0.5 ug/Kg 66 0.5 ug/Kg 140 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg 2.2 0.5 ug/Kg 1.8 0.5 ug/Kg 0.8 0.5 ug/Kg 0.6 0.5 ug/Kg 4.1 0.5 ug/Kg 3 0.5 ug/Kg 2.1 0.5 ug/Kg 1.2 0.5 ug/Kg 4.5 0.5 ug/Kg 3 0.5 ug/Kg ND 0.5 ug/Kg 0.9 0.5 ug/Kg ND 0.5 mg/Kg 0.6 0.5 mg/Kg 71 80 94 98 99 99 Sample ID. No. Date Sampled Sample Depth Dimethyl Sulfide MTBE 1,2-Dichloroethane Benzene Toluene Ethylbenzene m/p-Xylene o-Xylene 1,2,4-Trimethylbenzene Naphthalene TVPH % Surrogate Recovery 1,2-Dichloroethane-d4 d8-Toluene p-Bromofluorobenzene RDC-02 RDC-02 6/8/2023 6/8/2023 21 ft 23 ft Reporting Limit Units Flags Reporting Limit Units Flags ND 0.5 ug/Kg ND 0.5 ug/Kg 200 0.5 ug/Kg 150 0.5 ug/Kg 4.2 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg ND 0.5 ug/Kg 2.2 0.5 ug/Kg 1.9 0.5 ug/Kg 0.6 0.5 ug/Kg ND 0.5 ug/Kg 2.9 0.5 ug/Kg 2.2 0.5 ug/Kg 1.4 0.5 ug/Kg 1 0.5 ug/Kg 2.5 0.5 ug/Kg 2.1 0.5 ug/Kg 1.4 0.5 ug/Kg ND 0.5 ug/Kg 0.7 0.5 mg/Kg 0.8 0.5 mg/Kg 83 88 97 98 100 105 Sample ID. No.RDC-02 RDC-02 RDC-02 Date Sampled 6/8/2023 6/8/2023 6/8/2023 Sample Depth 25 ft 27 ft 29 ft Reporting Limit Units Flags Reporting Limit Units Flags Reporting Limit Units Flags Dimethyl Sulfide ND 10 ug/Kg ND 10 ug/Kg ND 10 ug/Kg MTBE 110 10 ug/Kg 130 10 ug/Kg 51 10 ug/Kg 1,2-Dichloroethane ND 10 ug/Kg ND 10 ug/Kg ND 10 ug/Kg Benzene ND 10 ug/Kg 160 10 ug/Kg 330 10 ug/Kg Toluene 24 10 ug/Kg 1600 10 ug/Kg 3700 10 ug/Kg Ethylbenzene ND 10 ug/Kg 330 10 ug/Kg 1000 10 ug/Kg m/p-Xylene 25 10 ug/Kg 1600 10 ug/Kg 4200 10 ug/Kg o-Xylene 29 10 ug/Kg 960 10 ug/Kg 2000 10 ug/Kg 1,2,4-Trimethylbenzene 43 10 ug/Kg 750 10 ug/Kg 2500 10 ug/Kg Naphthalene 19 10 ug/Kg 150 10 ug/Kg 350 10 ug/Kg TVPH ND 10 mg/Kg 18 10 mg/Kg 41 10 mg/Kg % Surrogate Recovery 1,2-Dichloroethane-d4 103 101 98 d8-Toluene 100 102 102 p-Bromofluorobenzene 93 97 96 Sample ID. No. Date Sampled Sample Depth Dimethyl Sulfide MTBE 1,2-Dichloroethane Benzene Toluene Ethylbenzene m/p-Xylene o-Xylene 1,2,4-Trimethylbenzene Naphthalene TVPH % Surrogate Recovery 1,2-Dichloroethane-d4 d8-Toluene p-Bromofluorobenzene RDC-02 RDC-02 6/8/2023 6/8/2023 31 ft 33 ft Reporting Limit Units Flags Reporting Limit Units Flags ND 10 ug/Kg ND 10 ug/Kg ND 10 ug/Kg ND 10 ug/Kg ND 10 ug/Kg ND 10 ug/Kg 660 10 ug/Kg 560 10 ug/Kg 4700 10 ug/Kg 4000 10 ug/Kg 710 10 ug/Kg 470 10 ug/Kg 2700 10 ug/Kg 1800 10 ug/Kg 1300 10 ug/Kg 950 10 ug/Kg 1100 10 ug/Kg 540 10 ug/Kg 200 10 ug/Kg 110 10 ug/Kg 24 10 mg/Kg 15 10 mg/Kg 100 100 101 103 97 96 Sample ID. No. Date Sampled Sample Depth Dimethyl Sulfide MTBE 1,2-Dichloroethane Benzene Toluene Ethylbenzene m/p-Xylene o-Xylene 1,2,4-Trimethylbenzene Naphthalene TVPH % Surrogate Recovery 1,2-Dichloroethane-d4 d8-Toluene p-Bromofluorobenzene Arvin Oil Sample ID. No.MW-3R Date Sampled 6/8/2023 Sample Depth 30 ft Reporting Limit Units Flags Dimethyl Sulfide ND 0.5 ug/L MTBE 71 0.5 ug/L 1,2-Dichloroethane ND 0.5 ug/L Benzene 3900 25 ug/L Toluene 20000 25 ug/L Ethylbenzene 3200 25 ug/L m/p-Xylene 11200 25 ug/L o-Xylene 5800 25 ug/L 1,2,4-Trimethylbenzene 2500 25 ug/L Naphthalene 690 25 ug/L TVPH 74 25 mg/L % Surrogate Recovery 1,2-Dichloroethane-d4 94 d8-Toluene 98 p-Bromofluorobenzene 95 Lactate ND 2 mg/L Acetate ND 2 mg/L Propionate ND 2 mg/L Formate/Isobutyrate ND 2 mg/L Butyrate ND 2 mg/L Pyruvate ND 2 mg/L Chloride 35 2 mg/L Nitrite ND 2 mg/L Succinate ND 10 mg/L Nitrate ND 2 mg/L Sulfate ND 2 mg/L Phosphate NA 2 mg/L Sulfide ND 2 mg/L Methane ND 20 ug/L Ethane ND 2 ug/L Ethylene ND 2 ug/L Propane ND 2 ug/L Propylene ND 2 ug/L Isobutane 2.4 2 ug/L n-Butane 37 2 ug/L Acetylene ND 2 ug/L t-2-Butene ND 2 ug/L 1-Butene ND 2 ug/L Isobutylene ND 2 ug/L cis-2-Butene ND 2 ug/L 1,3-Butadiene ND 2 ug/L Methyl Acetylene ND 2 ug/L Carbon Dioxide 150 2 mg/L Sample ID. No.MW-4 Date Sampled 6/8/2023 Sample Depth 30 ft Reporting Limit Units Flags Dimethyl Sulfide ND 10 ug/L MTBE ND 10 ug/L 1,2-Dichloroethane ND 10 ug/L Benzene 520 10 ug/L Toluene 3700 10 ug/L Ethylbenzene 700 10 ug/L m/p-Xylene 2900 10 ug/L o-Xylene 1400 10 ug/L 1,2,4-Trimethylbenzene 1400 10 ug/L Naphthalene 880 10 ug/L TVPH 23 10 mg/L % Surrogate Recovery 1,2-Dichloroethane-d4 99 d8-Toluene 100 p-Bromofluorobenzene 97 Lactate ND 2 mg/L Acetate ND 2 mg/L Propionate ND 2 mg/L Formate/Isobutyrate ND 2 mg/L Butyrate ND 2 mg/L Pyruvate ND 2 mg/L Chloride 18 2 mg/L Nitrite ND 2 mg/L Succinate ND 10 mg/L Nitrate 4.4 2 mg/L Sulfate 2.1 2 mg/L Phosphate NA 2 mg/L Sulfide ND 2 mg/L Methane 45 20 ug/L Ethane ND 2 ug/L Ethylene ND 2 ug/L Propane ND 2 ug/L Propylene ND 2 ug/L Isobutane ND 2 ug/L n-Butane 4.9 2 ug/L Acetylene ND 2 ug/L t-2-Butene ND 2 ug/L 1-Butene ND 2 ug/L Isobutylene ND 2 ug/L cis-2-Butene ND 2 ug/L 1,3-Butadiene ND 2 ug/L Methyl Acetylene ND 2 ug/L Carbon Dioxide 100 2 mg/L Sample ID. No.MW-8 Date Sampled 6/8/2023 Sample Depth 30 ft Reporting Limit Units Flags Dimethyl Sulfide ND 0.5 ug/L MTBE ND 0.5 ug/L 1,2-Dichloroethane ND 0.5 ug/L Benzene 5.3 0.5 ug/L Toluene 15 0.5 ug/L Ethylbenzene 6.9 0.5 ug/L m/p-Xylene 30 0.5 ug/L o-Xylene 19 0.5 ug/L 1,2,4-Trimethylbenzene 13 0.5 ug/L Naphthalene 8.9 0.5 ug/L TVPH ND 0.5 mg/L % Surrogate Recovery 1,2-Dichloroethane-d4 96 d8-Toluene 101 p-Bromofluorobenzene 104 Lactate ND 2 mg/L Acetate ND 2 mg/L Propionate ND 2 mg/L Formate/Isobutyrate ND 2 mg/L Butyrate ND 2 mg/L Pyruvate ND 2 mg/L Chloride 35 2 mg/L Nitrite ND 2 mg/L Succinate ND 10 mg/L Nitrate 2 2 mg/L Sulfate ND 2 mg/L Phosphate NA 2 mg/L Sulfide ND 2 mg/L Methane ND 20 ug/L Ethane ND 2 ug/L Ethylene ND 2 ug/L Propane ND 2 ug/L Propylene ND 2 ug/L Isobutane ND 2 ug/L n-Butane ND 2 ug/L Acetylene ND 2 ug/L t-2-Butene ND 2 ug/L 1-Butene ND 2 ug/L Isobutylene ND 2 ug/L cis-2-Butene ND 2 ug/L 1,3-Butadiene ND 2 ug/L Methyl Acetylene ND 2 ug/L Carbon Dioxide 160 2 mg/L Sample ID. No.MW-8R Date Sampled 6/8/2023 Sample Depth 30 ft Reporting Limit Units Flags Dimethyl Sulfide ND 0.5 ug/L MTBE 1.9 0.5 ug/L 1,2-Dichloroethane ND 0.5 ug/L Benzene 0.6 0.5 ug/L Toluene 3.9 0.5 ug/L Ethylbenzene 0.8 0.5 ug/L m/p-Xylene 3.3 0.5 ug/L o-Xylene 2 0.5 ug/L 1,2,4-Trimethylbenzene 2.5 0.5 ug/L Naphthalene 2.8 0.5 ug/L TVPH ND 0.5 mg/L % Surrogate Recovery 1,2-Dichloroethane-d4 98 d8-Toluene 100 p-Bromofluorobenzene 102 Lactate ND 2 mg/L Acetate ND 2 mg/L Propionate ND 2 mg/L Formate/Isobutyrate ND 2 mg/L Butyrate ND 2 mg/L Pyruvate ND 2 mg/L Chloride 31 2 mg/L Nitrite ND 2 mg/L Succinate ND 10 mg/L Nitrate 4.3 2 mg/L Sulfate ND 2 mg/L Phosphate NA 2 mg/L Sulfide ND 2 mg/L Methane ND 20 ug/L Ethane ND 2 ug/L Ethylene ND 2 ug/L Propane ND 2 ug/L Propylene ND 2 ug/L Isobutane ND 2 ug/L n-Butane ND 2 ug/L Acetylene ND 2 ug/L t-2-Butene ND 2 ug/L 1-Butene ND 2 ug/L Isobutylene ND 2 ug/L cis-2-Butene ND 2 ug/L 1,3-Butadiene ND 2 ug/L Methyl Acetylene ND 2 ug/L Carbon Dioxide 5.8 2 mg/L Sample ID. No.RDC-01 Date Sampled 6/8/2023 Sample Depth 30 ft Reporting Limit Units Flags Dimethyl Sulfide ND 5 ug/L MTBE 13 5 ug/L 1,2-Dichloroethane ND 5 ug/L Benzene 2200 5 ug/L Toluene 12200 5 ug/L E Ethylbenzene 2900 5 ug/L m/p-Xylene 8600 5 ug/L o-Xylene 4500 5 ug/L 1,2,4-Trimethylbenzene 3000 5 ug/L Naphthalene 960 5 ug/L TVPH 78 5 mg/L % Surrogate Recovery 1,2-Dichloroethane-d4 91 d8-Toluene 103 p-Bromofluorobenzene 98 Lactate ND 2 mg/L Acetate ND 2 mg/L Propionate ND 2 mg/L Formate/Isobutyrate ND 2 mg/L Butyrate ND 2 mg/L Pyruvate ND 2 mg/L Chloride 21 2 mg/L Nitrite ND 2 mg/L Succinate ND 10 mg/L Nitrate ND 2 mg/L Sulfate ND 2 mg/L Phosphate NA 2 mg/L Sulfide ND 2 mg/L Methane 28 20 ug/L Ethane ND 2 ug/L Ethylene ND 2 ug/L Propane ND 2 ug/L Propylene ND 2 ug/L Isobutane 2.8 2 ug/L n-Butane 39 2 ug/L Acetylene ND 2 ug/L t-2-Butene ND 2 ug/L 1-Butene ND 2 ug/L Isobutylene ND 2 ug/L cis-2-Butene ND 2 ug/L 1,3-Butadiene ND 2 ug/L Methyl Acetylene ND 2 ug/L Carbon Dioxide 140 2 mg/L Sample ID. No.RDC-02 Date Sampled 6/8/2023 Sample Depth 30 ft Reporting Limit Units Flags Dimethyl Sulfide ND 0.5 ug/L MTBE ND 0.5 ug/L 1,2-Dichloroethane ND 0.5 ug/L Benzene 5100 25 ug/L Toluene 26400 25 ug/L Ethylbenzene 4200 25 ug/L m/p-Xylene 14100 25 ug/L o-Xylene 7200 25 ug/L 1,2,4-Trimethylbenzene 3100 25 ug/L Naphthalene 710 25 ug/L TVPH 91 25 mg/L % Surrogate Recovery 1,2-Dichloroethane-d4 75 d8-Toluene 99 p-Bromofluorobenzene 82 Lactate ND 2 mg/L Acetate ND 2 mg/L Propionate ND 2 mg/L Formate/Isobutyrate ND 2 mg/L Butyrate ND 2 mg/L Pyruvate ND 2 mg/L Chloride 34 2 mg/L Nitrite ND 2 mg/L Succinate ND 10 mg/L Nitrate ND 2 mg/L Sulfate ND 2 mg/L Phosphate NA 2 mg/L Sulfide ND 2 mg/L Methane 23 20 ug/L Ethane ND 2 ug/L Ethylene 6 2 ug/L Propane ND 2 ug/L Propylene ND 2 ug/L Isobutane 3.7 2 ug/L n-Butane 58 2 ug/L Acetylene ND 2 ug/L t-2-Butene ND 2 ug/L 1-Butene ND 2 ug/L Isobutylene ND 2 ug/L cis-2-Butene ND 2 ug/L 1,3-Butadiene ND 2 ug/L Methyl Acetylene ND 2 ug/L Carbon Dioxide 130 2 mg/L Attachment B Soil Boring Logs 34 32 30 28 26 24 22 20 18 16 14 12 10 8 6 4 2 0 100 100 100 100 100 RDC-01 (11') RDC-01 (13') RDC-01 (15') RDC-01 (17') RDC-01 (19') RDC-01 (21') RDC-01 (23') RDC-01 (25') RDC-01 (27.5') RDC-01 (29') RDC-01 (31') RDC-01 (33') <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 2.4 250 44 340 24 ML SM ML Geological logging not performed Dry red sandy silt Dry tan medium silty sand Dry red sandy silt Moist red sandy silt vertical black streaking 21-25', slight chlorine odor Moist red sandy silt, petroleum odor, gravel lenses at 27.5' and 30' Refusal at 32' <0.5 <0.5 <0.5 <0.5 <0.5 1.9 <0.5 3.2 130 170 440 530 DESCRIPTION NAME (USCS): color, sorting, plasticity, moisture, sorting, grain size, packing Withers Ravenel - Arvin Oil GEX Direct Push Geoprobe 3230 3.25 Dual Tube Nathan Mau Nathan Thacker RDC-01 REC-OVERY(%)LAB I.D.DEPTH(feet)WELL CONSTRUCTION DETAILS AND/OR DRILLING REMARKS TVPH (soil) (ppm) PROJECT MANAGER: PROJECT: BORING IDENTIFICATION: DRILLING CONTRACTOR: DRILLING METHOD: SAMPLING METHOD: DRILLING EQUIPMENT: REG. NO. LOGGED BY: DEPTH TO WATER:CASING: TOTAL DEPTH:SCREEN INTERVAL: DATE FINISHED: DATE STARTED: NORTHING: EASTING: ELEVATION: June 8, 2023 June 8, 2023 32'27-32 Benzene (soil) (ppb) AST Environmental Inc.Project No.Page 1 of 15152399 36 34 32 30 28 26 24 22 20 18 16 14 12 10 8 6 4 2 0 100 100 100 100 100 RDC-02 (11') RDC-02 (13') RDC-02 (15') RDC-02 (17') RDC-02 (19') RDC-02 (21') RDC-02 (23') RDC-02 (25') RDC-02 (27') RDC-02 (29') RDC-02 (31') RDC-02 (33') <0.5 <0.5 <0.5 <0.5 0.6 0.7 0.8 <10 18 41 24 15 ML SM ML GM ML Geological logging not performed Dry red sandy silt, slight chlorine odor Silty fine angular gravel, dry Dry red sandy silt, slight chlorine odor Moist red sandy silt with black streaking throughout Moist gray silty sand Moist red sandy silt with black streaking throughout, slight petroleum odor Refusal at 34' <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 160 330 660 560 DESCRIPTION NAME (USCS): color, sorting, plasticity, moisture, sorting, grain size, packing Withers Ravenel - Arvin Oil GEX Direct Push Geoprobe 3230 3.25 Dual Tube Nathan Mau Nathan Thacker RDC-02 REC-OVERY(%)LAB I.D.DEPTH(feet)WELL CONSTRUCTION DETAILS AND/OR DRILLING REMARKS TVPH (soil) (ppm) PROJECT MANAGER: PROJECT: BORING IDENTIFICATION: DRILLING CONTRACTOR: DRILLING METHOD: SAMPLING METHOD: DRILLING EQUIPMENT: REG. NO. LOGGED BY: DEPTH TO WATER:CASING: TOTAL DEPTH:SCREEN INTERVAL: DATE FINISHED: DATE STARTED: NORTHING: EASTING: ELEVATION: June 8, 2023 June 8, 2023 34'29-34 Benzene (soil) (ppb) AST Environmental Inc.Project No.Page 1 of 15152399 Attachment C BOS 200 Injection Design CROWN FLOORING LLC(FORMER GAS STATION)FORMERUSTAREACONCRE T E S L A BMW-2RMW-10MW-7MW-6RMW-3RMWD-7MW-1MWD-9MWD-6WSW-2RESIDENCERESIDENCERESIDENCEFAYETTEVILLE ROAD(HIGHWAY 401)GARAGE/STORAGEBUILDINGWOODENSHEDMWD-14MWD-15MW-11MW-12MWD-13MW-16MW-17MWD-17MW-8MW-4MWD-5FORMER HYDRAULICLIFT AREAESTIMATED EXTENT OF BENZENE ATCONCENTRATIONS EXCEEDING 2LSTANDARD - SURFICIAL AQUIFER1.01.0(<0.5)(0.893)(1,540)(10.9)(<0.5)(<0.5)(5,020)(<0.5)(<0.5)(<0.5)(<0.5)(<0.5)(<0.5)(<0.5)(<0.5)(<0.5)(<0.5)(<0.5)(<0.5)(<0.5)LEGEND WATER SUPPLY WELL TYPE II MONITORING WELL BENZENE CONCENTRATION ESTIMATED EXTENT OF GROUNDWATER BENZENE CONTAMINATION AT LEVELS EXCEEDING NC 2L STANDARD (1.0 ug/L)NOTES: 1.) 2021 AERIAL OBTAINED FROM NC ONE MAP. 2.) ALL DATA SHOWN IN ug/L. 3.) VALUES SHOWN IN RED EXCEED NC GCL FOR BENZENE.(1,540)GROUNDWATER BENZENEISOCONCENTRATION MAP MARCH 2023 DRAWN BY: 5 SCALE:FIGURE NO.: PROJECT NO.:DATE:APPROVED BY: ARVIN OIL COMPANYTF#13379 5837 & 5839 FAYETTEVILLE ROAD (US HIGHWAY 401)RALEIGH, WAKE COUNTY, NC WithersRavenel Engineers | Planners | Surveyors 115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340 | license #: F-1479 | www.withersravenel.com 1"=30 'GRAPHIC SCALE1 inch = 30 ft.0301560KBB MJ 04/05/2023 23-0307-N Client Name Withers Ravenel Project Location Arvin Oil - Raleigh, NC Area A MW-3R Site Information Predominate Geology of Treatment Zone Saprolite Treatment Zone Area (ft^2)1,460 1,460 Contamination Depth Start (ft bgs)27.0 Contamination Depth End (ft bgs)35.0 Treatment Volume (yd^3)432.6 433 Triangular Grid Spacing (ft)7.5 Number of Injection Points - Design 26 26 Injection Interval Distance (ft)2.0 Number of Injection Intervals per Point - Design 4.5 Total Number of Injection Intervals 117 117 Speciated COC Design Calculations Contaminant of Concern Benzene Design Basis Soil (mg/kg) or Groundwater (mg/L)Groundwater Design Concentration 25.000 Interim Design Endpoint 1.000 Contaminant of Concern Mass Loading (lb/ft^3)4.68E-04 BOS 200 per Injection Interval - Design (lb)40 BOS 200 Slurry Volume per Interval (gal)25 Average BOS 200 per Injection Point (lb)180 BOS 200 Total (lb)4,680 4,700 TPH Design Calculations TPH Groundwater Concentration (mg/L)7 Average TPH Soil Concentration (mg/kg)300 TPH Mass (lb)388 Design Basis Select Speciated or TPH Speciated Design BOS 200 Total per Area (lb)4,680 4,700 Trap & Treat Bacteria Calculations Bacteria Concentrate (gal)9 10 Kinetic Design Additives Supplemental Gypsum per Interval - Design (lb)25 Total Supplemental Gypsum (lb)2,925 2,950 Supplemental Magnesium Sulfate per Interval - Design (lb)25.0 Total Supplemental Magnesium Sulfate (lb)2,925 2,950 Food Grade Starch per Interval (lb)12.5 Total Food Grade Starch (lb)1,463 1,500 Yeast Extract per Interval (lb)0.33 Total Yeast Extract (lb)39 55 Slurry and Water Volumes Slurry Volume per Interval (gal)25 Estimated Water Volume (gal)2,925 2,925 Totals 9/29/2023 Client Name Withers Ravenel Project Location Arvin Oil - Raleigh, NC Summary BOS 200 Total (lb)4,700 BOS 200 Unit Price ($/lb, per RPI website)$6.25 Bacteria Concentrate (gal)10 Bacteria Concentrate Price ($/gal, per RPI website)$115 Supplemental Gypsum Total (lb)2,950 Gypsum Unit Price ($/lb)$0.50 Magnesium Sulfate Total (lb)2,950 Magnesium Sulfate Unit Price ($/lb)$0.65 Food Grade Starch Total (lb)1,500 Food Grade Starch Unit Price ($/lb)$0.50 Yeast Extract Total (lb)55 Yeast Extract Unit Price ($/lb)$13.50 Estimated Shipping and Tax ($/lb)$0.40 Total Material Price ($)$37,290 Number of Field Days to Complete 3 Mobilization ($)$3,000 Injection Location Markout ($)$0 Total Installation Price ($)$24,600 Total Estimated Price ($)$61,890 9/29/2023                 ATTACHMENT B    SITE PHOTOGRAPHS      Arvin Oil Company – Incident # 13379 WR Project # 23‐0307‐N  Letter Report – Remedial Design Characterization  October 2023         PHOTO 1  TYPICAL RDC BORING INSTALLATION (RDC‐01)       PHOTO 2  GENERAL LOCATION OF BORING RDC‐02 (RIGHT OF WELL AT CENTER)