FA-831_15440_CA_LTR_20231031

 
WithersRavenel
Our People. Your Success. 

115 MacKenan Drive | Cary, NC 27511 
t: 919.469.3340 | f: 919.467.6008 | www.withersravenel.com | License No. F‐1479 
Asheville | Cary | Charlotte | Greensboro | Lumberton | Pittsboro | Raleigh | Southern Pines | Wilmington 

October 31, 2023 

State of North Carolina 
Department of Environmental Quality 
Federal & State Lead Program 
Division of Waste Management‐Underground Storage Tank Section 
1646 Mail Service Center 
Raleigh, North Carolina 27699‐1646 

Attn:  Mr. Hassan Osman 
Letter Report – Groundwater & Supply Well Sampling 
Former Floyd Carthens Property (Adjacent C‐Store)  
1297 South Old Wire Road 
Red Springs, Hoke County, North Carolina 
Groundwater Incident Number: 15440 
UST Number: FA‐831 
NCDEQ Contract # N70522‐C 
WR Project Number:  23‐0307‐BP 

Mr. Osman: 
WithersRavenel, Inc. (WR) has completed groundwater sampling the location, as described in our 
proposal numbered TA‐01 for the above referenced site under Contract # N75022‐C, approved 
by the UST Section on September 11, 2023.  WR Personnel mobilized to the site (Figure 1) on 
September 29, 2023 to complete activities associated with the current TA.  WR was originally 
tasked with the collection and analysis of a supply well sample from on‐site well WSW‐1, however, 
during WR’s visit to the location the well was inactive.  For this reason, WSW‐1 was not sampled.  
NCDEQ had also requested that WR determine the status of supply wells WSW‐2 and WSW‐3 
and the willingness of the owners of those wells to accept water line connections to the properties.  
WR personnel attempted to contact the owners of these wells while on‐site but neither was 
available to obtain access for sampling of the wells or discussions related to water line connections.   

Groundwater Sampling – MW‐1 
On arrival, WR opened and gauged monitoring well MW‐1 with a decontaminated electronic water 
level indicator.  Groundwater was measured within MW‐1 to lie 8.95‐ft beneath the well’s top of 
casing (TOC).  Following gauging, the well was purged with a new, disposable polyethylene (PE) 
bailer until a total of three volumes of groundwater had been removed.  Following purging and 
after having allowed sufficient time for groundwater recovery within the well, monitoring well 
MW‐1 was sampled with the dedicated bailer.  Samples collected from MW‐1 were submitted to 
Waypoint Analytical, LLC (Waypoint) for laboratory analysis by Standard Method (SM) 6200B.   

Former Floyd Carthens Property (Adjacent C‐Store) WR Project # 23‐0307‐BP 
Letter Report October 2023 
2 

Laboratory results associated with analysis of the sample retained from MW‐1 showed the 
following: 

 Several targeted compounds were reported in the sample from MW‐1. 
 Naphthalene, n‐propylbenzene, 1,2,4‐trimethylbenzene and total xylenes were each reported 
at concentrations exceeding their respective NC 2L Standards. 
 No compounds were reported at levels exceeding their respective Gross Contaminant Levels 
(GCLs).   

Laboratory results are shown in Table B‐4 (attached) and included in Appendix A.  Field Notes and 
site photographs are also included as an attachment.   

WR appreciates the opportunity to be of service in the completion of these assessment activities.  
Should you have questions, comments, or require additional information, please contact WR at 
your earliest convenience. 

Cordially, 
WithersRavenel 

Kevin B. Buchanan  
Project Manager  

FIGURE 

OLD WIRE RD
MUSTANG DRFORMER UST
AREA
FORMER PUMP
ISLAND
1
MW-1 KBBMJDRAWN BY:10/10/202323-0307-BP1SCALE:FIGURE NO.:PROJECT NO.:DATE:APPROVED BY:SITE MAPWithersRavenelEngineers | Planners | Surveyors115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340 license #: F-1479 | www.withersravenel.com1"=30 'LEGEND
SUPPLY WELL LOCATION
NOTES:
1.) 2019 AERIAL OBTAINED FROM THE LOCAL COUNTY GIS DEPARTMENT.FLOYD CARTHENS PROPERTY(ADJACENT FORMER C-STORE)TF # 15440 / UST # FA-8311297 SOUTH OLD WIRE ROADRED SPRINGS, HOKE COUNTY, NC1
GRAPHIC SCALE
1 inch = 30 ft.
0 3015 60

TABLE B‐4  

CalculatedAcetoneBenzenen‐Butylbenzenesec‐ButylbenzeneEthylbenzeneIsopropylbenzene (Cumene)p‐IsopropyltolueneNaphthalenen‐PropylbenzeneToluene1,2,4‐Trimethylbenzene1,3,5‐TrimethylbenzeneTotal XylenesC5‐C8 AliphaticsC9‐C12 AliphaticsC9‐C22 Aromatics67‐64‐171‐43‐2 104‐51‐8 135‐98‐8 100‐41‐498‐82‐899‐87‐691‐20‐3 103‐65‐1 108‐88‐395‐63‐6 108‐67‐8 1330‐20‐7‐‐‐ ‐‐‐ ‐‐‐11/29/2021<10.01.84 5.84 2.82 42.7 8.48 0.867 32.2 22 25.6 491 88 262188 1,470 75510/18/2022<125 <59.47<5157 12.3<5103 37.4 146 367 111 1030NA NA NA9/29/2023<1000 <50.0 <50.0 <50.0400<50.0 <50.02070 120 72 1100 320 2760NA NA NA11/29/2021<10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500NA NA NA10/18/2022 10.2<1 <1 <1 <1 <1 <1 <5 <1 <1 <1 <1 <10NA NA NA6000 1 70 70 600 70 25 6 70 600 400 400 500 400 700 2006,000,000 5,000 5,900 8,800 80,000 30,500 11,700 6,000 26,100 260,000 28,500 24,100 50,000‐‐‐ ‐‐‐ ‐‐‐‐‐‐5‐‐‐ ‐‐‐700‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐1,000‐‐‐ ‐‐‐10,000‐‐‐ ‐‐‐ ‐‐‐Notes:1)2)3)4)5)6)Result=Result Exceeds Laboratory Detection LimitsResult=Result Exceeds 2L StandardResult=Result Exceeds GCL ValueResult=Result Exceeds 2L & MCL Value (Applies only to samples obtained from water supply wells)US EPA MCL = "Maximum Contaminant Level" ‐ The maximum permissible level of a contaminant  as established by the US EPA. MADEP‐VPHRED SPRINGS, HOKE COUNTY, NCOnly those compounds detected in one or more samples shown hereon.Calculated total xylenes concentration is the sum of m,p‐xylenes and o‐xylenes.  See laboratory report for separate values.All results provided in ug/L (micrograms per liter) or parts per billionINCIDENT NUMBER: 15440Date CollectedSM6200BNC 2L Standard ‐ North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L (Comprehensive Tables for Corrective Action Guidelines, September 2022).GCLs for Groundwater = NCDENR UST Section Gross Contamination Levels for Groundwater (Comprehensive Tables for Corrective Action Guidelines, September 2022).NC 2L StandardGCLs for Groundwater    (μg/L)US EPA MCLMW‐1Sample IDTABLE B‐4SUMMARY OF GROUNDWATER ANALYTICAL RESULTSFLOYD CARTHENS PROPERTY (ADJACENT FORMER C‐STORE)1297 SOUTH OLD WIRE ROADWSW‐1

APPENDIX A 

LABORATORY REPORT & CHAIN OF CUSTODY 

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

10/10/2023
Withers & Ravenel Kevin Buchanan
115 Mackenan Dr. BUILDING 117 Cary, NC, 27511
Ref: Analytical Testing
Lab Report Number: 23-276-0017 Client Project Description: Floyd Property
23-0307-BP
Dear Kevin Buchanan:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 10/3/2023 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Angela D Overcash Senior Project Manager
Page 1 of 16
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202437735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202499012State ProgramSouth Carolina
12/31/202399012State ProgramSouth Carolina
Page 1 of 1 00016/23-276-0017
Page 2 of 16
Report Number:
Sample Summary Table
Client Project Description:
23-276-0017
Floyd Property
23-0307-BP
Lab No Client Sample ID Matrix Date Collected Date Received
09/29/2023 11:20Aqueous 96745 MW-1 10/03/2023 13:00
Page 3 of 16
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-276-0017
Report Limit
Project:Floyd Property
V 96745MW-1
400 10/06/2023 08:196200BEthylbenzeneµg/L 50.0
2070 10/06/2023 08:196200BNaphthaleneµg/L 100
120 10/06/2023 08:196200Bn-Propylbenzene µg/L 50.0
72.0 10/06/2023 08:196200BTolueneµg/L 50.0
1100 10/06/2023 08:196200B1,2,4-Trimethylbenzene µg/L 50.0
320 10/06/2023 08:196200B1,3,5-Trimethylbenzene µg/L 50.0
815 10/06/2023 08:196200Bo-Xylene µg/L 50.0
1940 10/06/2023 08:196200Bm,p-Xylene µg/L 100
2760 10/06/2023 08:196200BXylene (Total)µg/L 50.0
Page 4 of 16
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-276-0017
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Kevin Buchanan
Cary
23-0307-BP Received : 10/03/2023
Floyd Property
Report Date : 10/10/2023
Sample ID :
Lab No :
Sampled:MW-1
96745 Matrix:
9/29/2023 11:20
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1000 µg/L 1000Acetone 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0Benzene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0Bromobenzene 100 10/06/23 08:19 6200BMSA
<100 µg/L 100Bromochloromethane 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0Bromodichloromethane 100 10/06/23 08:19 6200BMSA
<500 µg/L 500Bromoform 100 10/06/23 08:19 6200BMSA
<100 µg/L 100Bromomethane 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0n-Butylbenzene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0sec-Butyl benzene 100 10/06/23 08:19 6200BMSA
<200 µg/L 200tert-Butyl benzene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0Carbon Tetrachloride 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0Chlorobenzene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0Chlorodibromomethane 100 10/06/23 08:19 6200BMSA
<100 µg/L 100Chloroethane 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0Chloroform 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0Chloromethane 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.02-Chlorotoluene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.04-Chlorotoluene 100 10/06/23 08:19 6200BMSA
<200 µg/L 2001,2-Dibromo-3-Chloropropane 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.01,2-Dibromoethane 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0Dibromomethane 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.01,2-Dichlorobenzene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.01,3-Dichlorobenzene 100 10/06/23 08:19 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 5 of 16
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-276-0017
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Kevin Buchanan
Cary
23-0307-BP Received : 10/03/2023
Floyd Property
Report Date : 10/10/2023
Sample ID :
Lab No :
Sampled:MW-1
96745 Matrix:
9/29/2023 11:20
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<50.0 µg/L 50.01,4-Dichlorobenzene 100 10/06/23 08:19 6200BMSA
<500 µg/L 500Dichlorodifluoromethane 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.01,1-Dichloroethane 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.01,2-Dichloroethane 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.01,1-Dichloroethene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0cis-1,2-Dichloroethene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0trans-1,2-Dichloroethene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.01,2-Dichloropropane 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.01,3-Dichloropropane 100 10/06/23 08:19 6200BMSA
<200 µg/L 2002,2-Dichloropropane 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.01,1-Dichloropropene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0cis-1,3-Dichloropropene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0trans-1,3-Dichloropropene 100 10/06/23 08:19 6200BMSA
<20000 µg/L 20000Ethanol 100 10/06/23 08:19 6200BMSA
400 µg/L 50.0Ethylbenzene 100 10/06/23 08:19 6200BMSA
<300 µg/L 300Hexachlorobutadiene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0Di-Isopropyl Ether (DIPE)100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0Isopropylbenzene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.04-Isopropyl toluene 100 10/06/23 08:19 6200BMSA
<100 µg/L 1002-Hexanone 100 10/06/23 08:19 6200BMSA
<500 µg/L 500Methyl Ethyl Ketone (MEK)100 10/06/23 08:19 6200BMSA
<200 µg/L 200Methylene Chloride 100 10/06/23 08:19 6200BMSA
<100 µg/L 100Methyl tert-butyl ether (MTBE)100 10/06/23 08:19 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 6 of 16
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-276-0017
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Kevin Buchanan
Cary
23-0307-BP Received : 10/03/2023
Floyd Property
Report Date : 10/10/2023
Sample ID :
Lab No :
Sampled:MW-1
96745 Matrix:
9/29/2023 11:20
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<100 µg/L 1004-Methyl-2-Pentanone 100 10/06/23 08:19 6200BMSA
2070 µg/L 100Naphthalene 100 10/06/23 08:19 6200BMSA
120 µg/L 50.0n-Propylbenzene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0Styrene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.01,1,1,2-Tetrachloroethane 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.01,1,2,2-Tetrachloroethane 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0Tetrachloroethene 100 10/06/23 08:19 6200BMSA
72.0 µg/L 50.0Toluene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.01,2,3-Trichlorobenzene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.01,2,4-Trichlorobenzene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.01,1,1-Trichloroethane 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.01,1,2-Trichloroethane 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0Trichloroethene 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0Trichlorofluoromethane 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.01,2,3-Trichloropropane 100 10/06/23 08:19 6200BMSA
1100 µg/L 50.01,2,4-Trimethylbenzene 100 10/06/23 08:19 6200BMSA
320 µg/L 50.01,3,5-Trimethylbenzene 100 10/06/23 08:19 6200BMSA
<500 µg/L 500Vinyl Acetate 100 10/06/23 08:19 6200BMSA
<50.0 µg/L 50.0Vinyl Chloride 100 10/06/23 08:19 6200BMSA
1940 µg/L 100m,p-Xylene 100 10/06/23 08:19 6200BMSA
815 µg/L 50.0o-Xylene 100 10/06/23 08:19 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 7 of 16
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-276-0017
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Kevin Buchanan
Cary
23-0307-BP Received : 10/03/2023
Floyd Property
Report Date : 10/10/2023
Sample ID :
Lab No :
Sampled:MW-1
96745 Matrix:
9/29/2023 11:20
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
2760 µg/L 50.0Xylene (Total)100 10/06/23 08:19 6200B
Surrogate: 4-Bromofluorobenzene 94.4 Limits: 70-130%10/06/23 08:19100 MSA V38792
Surrogate: Dibromofluoromethane 99.2 Limits: 70-130%10/06/23 08:19100 MSA V38792
Surrogate: 1,2-Dichloroethane - d4 90.8 Limits: 70-130%10/06/23 08:19100 MSA V38792
Surrogate: Toluene-d8 95.8 Limits: 70-130%10/06/23 08:19100 MSA V38792
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 8 of 16
Quality Control Data
23-276-0017Report No:
Project Description:
Client ID:Withers & Ravenel
Floyd Property
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38792QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38791
Associated Lab Samples: 96745
LRB-V38791 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/06/23 02:5710.0< 10.0µg/LAcetone
10/06/23 02:570.500< 0.500µg/LBenzene
10/06/23 02:570.500< 0.500µg/LBromobenzene
10/06/23 02:571.00< 1.00µg/LBromochloromethane
10/06/23 02:570.500< 0.500µg/LBromodichloromethane
10/06/23 02:575.00< 5.00µg/LBromoform
10/06/23 02:571.00< 1.00µg/LBromomethane
10/06/23 02:570.500< 0.500µg/Ln-Butylbenzene
10/06/23 02:570.500< 0.500µg/Lsec-Butyl benzene
10/06/23 02:572.00< 2.00µg/Ltert-Butyl benzene
10/06/23 02:570.500< 0.500µg/LCarbon Tetrachloride
10/06/23 02:570.500< 0.500µg/LChlorobenzene
10/06/23 02:570.500< 0.500µg/LChlorodibromomethane
10/06/23 02:571.00< 1.00µg/LChloroethane
10/06/23 02:570.500< 0.500µg/LChloroform
10/06/23 02:570.500< 0.500µg/LChloromethane
10/06/23 02:570.500< 0.500µg/L2-Chlorotoluene
10/06/23 02:570.500< 0.500µg/L4-Chlorotoluene
10/06/23 02:572.00< 2.00µg/L1,2-Dibromo-3-Chloropropane
10/06/23 02:570.500< 0.500µg/L1,2-Dibromoethane
10/06/23 02:570.500< 0.500µg/LDibromomethane
10/06/23 02:570.500< 0.500µg/L1,2-Dichlorobenzene
10/06/23 02:570.500< 0.500µg/L1,3-Dichlorobenzene
10/06/23 02:570.500< 0.500µg/L1,4-Dichlorobenzene
10/06/23 02:575.00< 5.00µg/LDichlorodifluoromethane
10/06/23 02:570.500< 0.500µg/L1,1-Dichloroethane
10/06/23 02:570.500< 0.500µg/L1,2-Dichloroethane
Page 1 of 6Date:10/10/2023 08:24 AM
Page 9 of 16
Quality Control Data
23-276-0017Report No:
Project Description:
Client ID:Withers & Ravenel
Floyd Property
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38792QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38791
Associated Lab Samples: 96745
LRB-V38791 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/06/23 02:570.500< 0.500µg/L1,1-Dichloroethene
10/06/23 02:570.500< 0.500µg/Lcis-1,2-Dichloroethene
10/06/23 02:570.500< 0.500µg/Ltrans-1,2-Dichloroethene
10/06/23 02:570.500< 0.500µg/L1,2-Dichloropropane
10/06/23 02:570.500< 0.500µg/L1,3-Dichloropropane
10/06/23 02:572.00< 2.00µg/L2,2-Dichloropropane
10/06/23 02:570.500< 0.500µg/L1,1-Dichloropropene
10/06/23 02:570.500< 0.500µg/Lcis-1,3-Dichloropropene
10/06/23 02:570.500< 0.500µg/Ltrans-1,3-Dichloropropene
10/06/23 02:57200< 200µg/LEthanol
10/06/23 02:570.500< 0.500µg/LEthylbenzene
10/06/23 02:573.00< 3.00µg/LHexachlorobutadiene
10/06/23 02:570.500< 0.500µg/LDi-Isopropyl Ether (DIPE)
10/06/23 02:570.500< 0.500µg/LIsopropylbenzene
10/06/23 02:570.500< 0.500µg/L4-Isopropyl toluene
10/06/23 02:571.00< 1.00µg/L2-Hexanone
10/06/23 02:575.00< 5.00µg/LMethyl Ethyl Ketone (MEK)
10/06/23 02:572.00< 2.00µg/LMethylene Chloride
10/06/23 02:571.00< 1.00µg/LMethyl tert-butyl ether (MTBE)
10/06/23 02:571.00< 1.00µg/L4-Methyl-2-Pentanone
10/06/23 02:571.00< 1.00µg/LNaphthalene
10/06/23 02:570.500< 0.500µg/Ln-Propylbenzene
10/06/23 02:570.500< 0.500µg/LStyrene
10/06/23 02:570.500< 0.500µg/L1,1,1,2-Tetrachloroethane
10/06/23 02:570.500< 0.500µg/L1,1,2,2-Tetrachloroethane
10/06/23 02:570.500< 0.500µg/LTetrachloroethene
10/06/23 02:570.500< 0.500µg/LToluene
Page 2 of 6Date:10/10/2023 08:24 AM
Page 10 of 16
Quality Control Data
23-276-0017Report No:
Project Description:
Client ID:Withers & Ravenel
Floyd Property
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38792QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38791
Associated Lab Samples: 96745
LRB-V38791 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/06/23 02:570.500< 0.500µg/L1,2,3-Trichlorobenzene
10/06/23 02:570.500< 0.500µg/L1,2,4-Trichlorobenzene
10/06/23 02:570.500< 0.500µg/L1,1,1-Trichloroethane
10/06/23 02:570.500< 0.500µg/L1,1,2-Trichloroethane
10/06/23 02:570.500< 0.500µg/LTrichloroethene
10/06/23 02:570.500< 0.500µg/LTrichlorofluoromethane
10/06/23 02:570.500< 0.500µg/L1,2,3-Trichloropropane
10/06/23 02:570.500< 0.500µg/L1,2,4-Trimethylbenzene
10/06/23 02:570.500< 0.500µg/L1,3,5-Trimethylbenzene
10/06/23 02:575.00< 5.00µg/LVinyl Acetate
10/06/23 02:570.500< 0.500µg/LVinyl Chloride
10/06/23 02:571.00< 1.00µg/Lm,p-Xylene
10/06/23 02:570.500< 0.500µg/Lo-Xylene
10/06/23 02:574-Bromofluorobenzene (S)94.2 70-130
10/06/23 02:57Dibromofluoromethane (S)99.2 70-130
10/06/23 02:571,2-Dichloroethane - d4 (S)92.2 70-130
10/06/23 02:57Toluene-d8 (S)94.8 70-130
LCS-V38791 LCSD-V38791Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
41.2 10310642.540.0µg/LAcetone 40-160 3.1 20.0
20.1 10110420.720.0µg/LBenzene 70-130 2.9 20.0
18.7 93.594.518.920.0µg/LBromobenzene 70-130 1.0 20.0
19.9 99.510420.820.0µg/LBromochloromethane 70-130 4.4 20.0
18.8 94.097.519.520.0µg/LBromodichloromethane 70-130 3.6 20.0
Page 3 of 6Date:10/10/2023 08:24 AM
Page 11 of 16
Quality Control Data
23-276-0017Report No:
Project Description:
Client ID:Withers & Ravenel
Floyd Property
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38792QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38791
LCS-V38791 LCSD-V38791Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
17.9 89.592.018.420.0µg/LBromoform 70-130 2.7 20.0
24.2 12113827.520.0µg/LBromomethane 60-140 12.7 20.0
19.4 97.098.519.720.0µg/Ln-Butylbenzene 70-130 1.5 20.0
19.1 95.597.019.420.0µg/Lsec-Butyl benzene 70-130 1.5 20.0
18.6 93.094.018.820.0µg/Ltert-Butyl benzene 70-130 1.0 20.0
19.6 98.010520.920.0µg/LCarbon Tetrachloride 70-130 6.4 20.0
19.5 97.598.019.620.0µg/LChlorobenzene 70-130 0.5 20.0
18.3 91.593.518.720.0µg/LChlorodibromomethane 70-130 2.1 20.0
18.7 93.598.019.620.0µg/LChloroethane 60-140 4.6 20.0
19.2 96.099.019.820.0µg/LChloroform 70-130 3.0 20.0
16.8 84.093.018.620.0µg/LChloromethane 60-140 10.1 20.0
19.0 95.095.519.120.0µg/L2-Chlorotoluene 70-130 0.5 20.0
18.8 94.096.519.320.0µg/L4-Chlorotoluene 70-130 2.6 20.0
18.6 93.010320.620.0µg/L1,2-Dibromo-3-Chloropropane 70-130 10.2 20.0
19.5 97.598.019.620.0µg/L1,2-Dibromoethane 70-130 0.5 20.0
19.2 96.097.019.420.0µg/LDibromomethane 70-130 1.0 20.0
19.3 96.599.519.920.0µg/L1,2-Dichlorobenzene 70-130 3.0 20.0
19.4 97.099.019.820.0µg/L1,3-Dichlorobenzene 70-130 2.0 20.0
18.9 94.596.519.320.0µg/L1,4-Dichlorobenzene 70-130 2.0 20.0
14.4 72.076.015.220.0µg/LDichlorodifluoromethane 60-140 5.4 20.0
19.4 97.099.019.820.0µg/L1,1-Dichloroethane 70-130 2.0 20.0
18.4 92.093.018.620.0µg/L1,2-Dichloroethane 70-130 1.0 20.0
19.1 95.599.019.820.0µg/L1,1-Dichloroethene 70-130 3.5 20.0
18.8 94.097.519.520.0µg/Lcis-1,2-Dichloroethene 70-130 3.6 20.0
19.0 95.098.019.620.0µg/Ltrans-1,2-Dichloroethene 70-130 3.1 20.0
19.3 96.510020.020.0µg/L1,2-Dichloropropane 70-130 3.5 20.0
Page 4 of 6Date:10/10/2023 08:24 AM
Page 12 of 16
Quality Control Data
23-276-0017Report No:
Project Description:
Client ID:Withers & Ravenel
Floyd Property
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38792QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38791
LCS-V38791 LCSD-V38791Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.2 96.097.519.520.0µg/L1,3-Dichloropropane 70-130 1.5 20.0
16.6 83.084.516.920.0µg/L2,2-Dichloropropane 70-130 1.7 20.0
20.7 10410721.320.0µg/L1,1-Dichloropropene 70-130 2.8 20.0
18.6 93.095.019.020.0µg/Lcis-1,3-Dichloropropene 70-130 2.1 20.0
18.4 92.097.019.420.0µg/Ltrans-1,3-Dichloropropene 70-130 5.2 20.0
491 98.2104522500µg/LEthanol 60-140 6.1 20.0
18.7 93.596.019.220.0µg/LEthylbenzene 70-130 2.6 20.0
18.5 92.593.018.620.0µg/LHexachlorobutadiene 70-130 0.5 20.0
18.9 94.596.519.320.0µg/LDi-Isopropyl Ether (DIPE)70-130 2.0 20.0
19.6 98.098.519.720.0µg/LIsopropylbenzene 70-130 0.5 20.0
19.0 95.096.519.320.0µg/L4-Isopropyl toluene 70-130 1.5 20.0
16.9 84.589.517.920.0µg/L2-Hexanone 60-140 5.7 20.0
17.0 85.091.518.320.0µg/LMethyl Ethyl Ketone (MEK)60-140 7.3 20.0
18.1 90.593.018.620.0µg/LMethylene Chloride 70-130 2.7 20.0
19.9 99.510220.320.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.9 20.0
18.3 91.594.018.820.0µg/L4-Methyl-2-Pentanone 60-140 2.6 20.0
22.8 11411222.420.0µg/LNaphthalene 70-130 1.7 20.0
19.4 97.098.519.720.0µg/Ln-Propylbenzene 70-130 1.5 20.0
19.0 95.097.019.420.0µg/LStyrene 70-130 2.0 20.0
19.5 97.510020.020.0µg/L1,1,1,2-Tetrachloroethane 70-130 2.5 20.0
18.2 91.093.518.720.0µg/L1,1,2,2-Tetrachloroethane 70-130 2.7 20.0
18.9 94.597.519.520.0µg/LTetrachloroethene 70-130 3.1 20.0
19.9 99.510320.520.0µg/LToluene 70-130 2.9 20.0
23.6 11812124.220.0µg/L1,2,3-Trichlorobenzene 70-130 2.5 20.0
20.5 10310621.120.0µg/L1,2,4-Trichlorobenzene 70-130 2.8 20.0
18.7 93.599.519.920.0µg/L1,1,1-Trichloroethane 70-130 6.2 20.0
Page 5 of 6Date:10/10/2023 08:24 AM
Page 13 of 16
Quality Control Data
23-276-0017Report No:
Project Description:
Client ID:Withers & Ravenel
Floyd Property
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38792QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38791
LCS-V38791 LCSD-V38791Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.3 96.510420.720.0µg/L1,1,2-Trichloroethane 70-130 7.0 20.0
21.0 10510821.520.0µg/LTrichloroethene 70-130 2.3 20.0
21.0 10511022.020.0µg/LTrichlorofluoromethane 60-140 4.6 20.0
18.9 94.597.019.420.0µg/L1,2,3-Trichloropropane 70-130 2.6 20.0
18.9 94.596.019.220.0µg/L1,2,4-Trimethylbenzene 70-130 1.5 20.0
19.1 95.597.019.420.0µg/L1,3,5-Trimethylbenzene 70-130 1.5 20.0
17.3 86.587.517.520.0µg/LVinyl Acetate 60-140 1.1 20.0
18.6 93.096.019.220.0µg/LVinyl Chloride 60-140 3.1 20.0
39.5 98.710140.440.0µg/Lm,p-Xylene 70-130 2.2 20.0
18.5 92.595.019.020.0µg/Lo-Xylene 70-130 2.6 20.0
94.294.04-Bromofluorobenzene (S)70-130
101100Dibromofluoromethane (S)70-130
94.095.41,2-Dichloroethane - d4 (S)70-130
96.894.8Toluene-d8 (S)70-130
Page 6 of 6Date:10/10/2023 08:24 AM
Page 14 of 16
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-276-0017
Withers & Ravenel
01221
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 1.7C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:10/03/2023 16:06:50
Special precautions or instructions included?
Comments:
Page 15 of 16
Page 16 of 16

APPENDIX B 

FIELD NOTES & PHOTOGRAPHIC RECORD 

 PHOTO 1 
MW‐1 

 PHOTO 2 
SAMPLE POINT FOR WSW‐1(INACTIVE)