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HomeMy WebLinkAboutMO-7050_27776_CA_RPTS_20230728_RDC 1567 CF Pours Harrisonburg, VA 22802 www.astenvironmental.com July 28, 2023 Mr. Ben Ashba Catlin Engineers 220 Old Dairy Road Wilmington, NC 28405 RE: Quantitative High Resolution Site Characterization Report Best Stop #2 10018 Lancaster Highway Waxhaw, Monroe County, North Carolina Dear Mr. Ashba, AST Environmental, Inc. (AST) appreciates the opportunity collaborate with Catlin and NCDEQ to the complete the Quantitative High Resolution Site Characterization (qHRSC) at the above referenced location. The proposed scope of work was to complete 7 soil borings to approximately 50 ft-bgs. The overall goal of this qHRSC program is to: 1. Quantify the TVPH and benzene soil concentrations. 2. Provide a visual interpolation of a high-resolution data set to aide in future investigation and remedial activities. 3. Design a BOS 200+ injection plan to bring groundwater concentrations in compliance with regulatory requirements. This letter report provides a summary of field activities during the RDC and an overview of analytical soil and groundwater data. REMEDIAL DESIGN CHARACTERIZATION On May 17, 2023 AST mobilized to the site to begin direct push drilling with the Geologic Exploration (GEX) drilling team. During the RDC event, a total of 7 soil borings were advanced via direct push drilling by GEX using their Geoprobe 3230DT. At each boring location, a 3.75 inch diameter direct push, dual tube tooling was advanced in five foot runs. Samples were collected every two feet beginning at PID or olfactory presence of hydrocarbon mass. All intervals were logged for lithology and PID readings were collected to guide the sampling process. Soil samples were collected and shipped to the RPI Project Support Laboratory in Golden, CO for VOC and Total Volatile Petroleum Hydrocarbon (TVPH) analysis via EPA method 8260B. Although this data is used for injection design purposes, the lab is not a certified or accredited laboratory, this data should not be used for regulator or compliance purposes. Existing monitoring wells MW-01, MW-02, MW-04, MW-05, MW-07R, OW-04N and RW-01 were developed and sampled. Groundwater samples were shipped to the RPI Project Support Laboratory in Golden, CO for VOC and Total Volatile Petroleum Hydrocarbon (TVPH) analysis via EPA method 8260B, anions via EPA method 300.1 and dissolved gases via EPA method RSK 175. Groundwater data has been tabulated and is included in the attachments as Table 2. Historically, MW-01 has consistently shown benzene concentrations greater than 5,000 ug/L, with the remaining wells in the network consistently above 1 ug/L. Select results from the RDC have been tabulated within this report and can be found below. According to the ITRC LNAPL Guidance Document, TVPH concentrations indicative of residual LNAPL in the subsurface are Mr. Ben Ashba July 28, 2023 Page 2 between 250 and 500 mg/kg, depending on the soil type. TVPH concentrations observed at this site range from less than 0.5 to over 16,000 mg/kg TVPH, with RDC-01, RDC-03 and RDC-06 displaying the highest concentrations. Boring logs for each location are included in Attachment B. RDC-01 Soil Concentrations Sample Depth Benzene (ug/kg) TVPH (mg/kg) 11 <10 <10 13 <10 <10 15 <10 <10 17 <10 <10 19 <10 <10 21 <10 <10 23 <10 <10 25 <10 <10 27 <10 <10 29 <250 700 31 <250 590 33 <500 1900 35 750 1300 37 5000 1300 39 1400 68 41 130 <50 43 33 10 45 26 <10 47 <10 <10 49 <0.5 <0.5 RDC-03 Soil Concentrations Sample Depth Benzene (ug/kg) TVPH (mg/kg) 11 <0.5 <0.5 13 <0.5 <0.5 15 <0.5 <0.5 17 <0.5 0.7 19 0.8 2.1 21 4.6 5 23 <0.5 0.9 25 <0.5 <0.5 27 <0.5 1 29 <10 <10 31 110 330 33 170 1400 35 1100 650 37 770 370 39 690 70 41 220 7.7 43 72 16 45 35 5.3 47 5.1 2.5 49 9.5 3.3 Mr. Ben Ashba July 28, 2023 Page 3 RDC-06 Soil Concentrations Sample Depth Benzene (ug/kg) TVPH (mg/kg) 11 <0.5 <0.5 13 <0.5 <0.5 15 <0.5 <0.5 17 <0.5 <0.5 19 <0.5 <0.5 21 <0.5 <0.5 23 <10 <10 25 <0.5 <0.5 27 <10 <10 29 <0.5 <0.5 31 <10 <10 33 <10 <10 35 <0.5 <0.5 37 <0.5 <0.5 39 <0.5 <0.5 41 <0.5 <0.5 43 <0.5 <0.5 45 <10 <10 47 110 <50 49 160 <50 3-Dimensional Quantitative Model The soil data collected from the RDC program was loaded into Ejlskov Environmental Site Model (ESM), a proprietary data visualization and acquisition software developed by Ejlskov A/S, a RPI Group member. Once entered in the software, a 3-dimensional interpolation of the benzene and TVPH soil data was produced by using the ESM inverse distance algorithm. From the review of this data, 2-dimensional figures of the benzene and TVPH maximum soil concentrations, benzene groundwater isoconcentration map, and cross sections of both contaminant plumes were created and are included in the Figures attachment. A total of approximately 8,600 lbs of TVPH and 1,800 lbs of benzene are estimated in the subsurface based on the ESM 3-d interpolation of the data. This mass total should only be used viewed as an estimate to possibly generate rough order of magnitude estimate for potential remediation costs. Conclusions and Recommendations As indicated above, the ITRC LNAPL Guidance Document states that TVPH concentrations indicative of residual LNAPL in the subsurface are between 250 and 500 mg/kg, depending on the soil type. Based on the data collected during the RDC event and the subsequent interpolation of the data, the subsurface distribution of residual LNAPL is confined to the area immediately surrounding and below the former tank pit. In addition to the quantification of residual LNAPL using the TVPH concentrations, the saturated benzene soil concentrations are also used for determination of injection locations and depths in order to meet the 2L groundwater standard. Using the state of Washington three phase partitioning model (https://www.ezview.wa.gov/Portals/_1987/Documents/Documents/WAC_173-340- 747_SoilDefaultHydrogeologicParameterData_2001.pdf), to be protective of groundwater at 1 ug/L benzene, soil concentrations of benzene must be below 0.411 ug/kg. Considering detection limits for soil are at 0.5 ug/kg, AST has targeted benzene concentrations with reportable concentrations in excess of 1 ug/kg or above the detection limit listed at or above 50 ug/kg. Mr. Ben Ashba July 28, 2023 Page 4 The vertical distribution of elevated soil concentrations were generally observed with peak concentrations near the water table, ~35’-37’’ bgs. In addition to the elevated concentrations observed at the water table near the former tank pit, vertical migration deeper into the saturated zone is also observed in the data, specifically the elevated benzene concentrations at termination depths of RDC-06. The transport mechanism allowing the vertical migration of LNAPL appears to be vertical to subvertical remnant foliation and fracture structure from the parent rock. Based on the data generated during this qHRSC, AST recommends that a BOS 200+ injection program be considered for this site, particularly in Area A and Area D, due to the residual LNAPL concentrations present and deep soil benzene present near MW-02. Based on the 2L remediation goal of 1 ug/L benzene, and the elevated soil mass present in the injection area, a BOS 200 plan has been completed that includes supplemental additives to increase the rate of degradation on the activated carbon surface and prolong the ability of the facultative microbes to continue the degradation process for years. BOS 200+ INJECTION DESIGN – SEE ATTACHED FOR DESIGN LOADINGS & FIGURE FOR LOCATIONS BOS 200® provides the unique capability (Trap & Treat® process) to utilize two proven and powerful technologies that rapidly and effectively remediate petroleum hydrocarbon sites: 1) Trapping of the contaminants via activated carbon adsorption. 2) Subsequent treatment via biological degradation within the BOS 200® matrix utilizing both aerobic and anaerobic microbial processes. The “Trap” provides the immediate mass reduction and plume control, while the “Treat” provides the continued long-term remedial degradation using synergistic facultative bacteria. No other activated carbon product can emplace a biological treatment mechanism on activated carbon for injection; this intellectual property is protected by RPI patents. AST is designed by RPI as the product design arm and distributor for the RPI Group. BOS 200® is a fine-grained, dry material which consists of activated carbon, calcium sulfate, nitrate, phosphate, and ammonia in a proprietary blend. It is 77% by weight activated carbon and up to 19% gypsum. The gypsum component itself is 79% by weight sulfate, which translates to approximately 15% by weight sulfate in BOS 200®. The product is mixed with water and a facultative blend of aerobic and anaerobic microbes to create a solids suspension. This is now an ideal environment for biological degradation, where hydrocarbons are adsorbed on to BOS 200® particles made up of: • Terminal Electron Acceptors: oxygen, nitrate, ammonia, and sulfate (primary) • Micro- and Macro-Nutrients - phosphorus and nitrogen • Aerobic and anaerobic blend of facultative microbes (over 27 species) On flexibility, with BOS 200® product, the design approach can vary from a treatment objective where complete and immediate contaminant mass removal from the groundwater is achieved, to a partial contaminant mass reduction working in conjunction with biological degradation driving the groundwater cleanup effort, or any combination somewhere in between. The end effect is that the plume can be controlled in a short period of time and treatment can be extended over a longer period. The revised BOS 200® injection design has been prepared for each area using the following approach/basis: 1. RDC and historical data from soil and groundwater sampling (i.e., analytical results, the Mr. Ben Ashba July 28, 2023 Page 5 screened interval of the wells, the soil sampling depth intervals) were used to determine the vertical and horizontal extent of impacts in each area. 2. Using the same data for each area a contaminant mass loading on a unit basis (lb. benzene per ft3 of impacted media) was determined for each of the designated areas. 3. The contaminant mass loadings were then used to determine the BOS 200® loadings (lbs. installed per ft3 of impacted media) necessary to remediate a specific depth interval within each injection area. This is a balance between the need to have an immediate mass reduction or to allow the biological process to be the controlling process. This is specifically discussed for each area below. 4. Based on the recent RDC soil data discovered, a second injection event is necessary to reach the remediation goal of 1 ug/L benzene and may be needed for Area A. However, quarterly monitoring of the terminal electron acceptor consumption will dictate if/when that additional event occurs. Based on the total saturated soil mass present, a second injection event may be necessary in Area A to achieve closure levels at this site. Tracking the dissolved phase contaminant trends (BTEX, TVPH), along with the terminal electron acceptor trend post injection, specifically sulfate, will determine the necessity and timing of the second injection. POST INJECTION SAMPLING Following the injection, AST will collect groundwater samples from all of the monitoring wells within the injection area prior to demobilizing. AST recommends performance progress groundwater sampling events at intervals of one week, two weeks, one-month post injection and quarterly until remediation goals are obtained. AST understands that this will be performed by others. The performance samples can be sent to Remediation Products, Ince. Laboratory in Golden, CO for no cost of analyses. The cost of shipment will be the responsibility of the consultant. The analyses will be consistent with that described previously. If you have any questions or wish to discuss the information provided herein, please contact me at (540) 820-3465 or via email at nthacker@astenv.com. Sincerely, AST Environmental, Inc. Nathan Thacker Senior Geologist Figures Monitoring Well Recovery Well RDC Soil Boring Legend AST Environmental 1567 CF Pours Drive Harrisonburg, Virginia www.astenv.com Best Stop 2 10014 Lancaster Highway Waxhaw, North Carolina NCDEQ Incident #27776 Monitoring Well Recovery Well RDC Soil Boring Legend AST Environmental 1567 CF Pours Drive Harrisonburg, Virginia www.astenv.com Best Stop 2 10014 Lancaster Highway Waxhaw, North Carolina NCDEQ Incident #27776 Monitoring Well Recovery Well RDC Soil Boring Legend AST Environmental 1567 CF Pours Drive Harrisonburg, Virginia www.astenv.com Best Stop 2 10014 Lancaster Highway Waxhaw, North Carolina NCDEQ Incident #27776 Monitoring Well Recovery Well RDC Soil Boring Legend AST Environmental 1567 CF Pours Drive Harrisonburg, Virginia www.astenv.com Best Stop 2 10014 Lancaster Highway Waxhaw, North Carolina NCDEQ Incident #27776 Monitoring Well Recovery Well RDC Soil Boring Legend AST Environmental 1567 CF Pours Drive Harrisonburg, Virginia www.astenv.com Best Stop 2 10014 Lancaster Highway Waxhaw, North Carolina NCDEQ Incident #27776 AST Environmental 1567 CF Pours Drive Harrisonburg, Virginia www.astenv.com Best Stop 2 10014 Lancaster Highway Waxhaw, North Carolina NCDEQ Incident #27776 AST Environmental 1567 CF Pours Drive Harrisonburg, Virginia www.astenv.com Best Stop 2 10014 Lancaster Highway Waxhaw, North Carolina NCDEQ Incident #27776 Tables mg/Kg Dimethyl SulfideMTBE1,2-DichloroethaneBenzeneTolueneEthylbenzenem/p-Xyleneo-XyleneTotal Xylene1,2,4-TrimethylbenzeneNaphthaleneTVPH1,2-Dichloroethane-d4d8-Toluenep-BromofluorobenzeneRDC-01 5/17/2023 11 43 <10 510 <10 <10 <10 <10 <10 <10 0 14 <10 <10 98 102 89 RDC-01 5/17/2023 13 6.3 <10 89 <10 <10 <10 <10 <10 <10 0 <10 <10 <10 98 100 91 RDC-01 5/17/2023 15 25.4 <10 260 <10 <10 <10 <10 <10 <10 0 <10 19 <10 99 99 95 RDC-01 5/17/2023 17 5 <10 70 <10 <10 <10 <10 <10 <10 0 <10 43 <10 99 102 94 RDC-01 5/17/2023 19 36.1 <10 350 <10 <10 <10 <10 <10 <10 0 12 65 <10 100 100 93 RDC-01 5/17/2023 21 83.2 <10 970 <10 <10 <10 <10 <10 <10 0 15 71 <10 94 102 80 RDC-01 5/17/2023 23 9.6 <10 220 <10 <10 <10 <10 <10 <10 0 15 64 <10 99 100 93 RDC-01 5/17/2023 25 17.2 <10 160 <10 <10 <10 <10 <10 <10 0 11 71 <10 96 99 96 RDC-01 5/17/2023 27 82.9 <10 <10 <10 <10 <10 <10 <10 <10 0 <10 13 <10 95 98 100 RDC-01 5/17/2023 29 1487 <250 1300 <250 <250 7400 7700 40500 21800 62300 62700 8600 700 91 100 99 RDC-01 5/17/2023 31 1365 <250 650 <250 <250 1600 4600 27000 16200 43200 54400 8800 590 90 101 99 RDC-01 5/17/2023 33 2000 <500 2000 <500 <500 49000 30100 152000 75000 227000 149000 21100 1900 90 101 100 RDC-01 5/17/2023 35 1478 <250 4300 <250 750 54900 26600 108000 49600 157600 79800 10300 1300 93 99 102 RDC-01 5/17/2023 37 747 <250 4100 <250 5000 85900 26900 97800 42100 139900 64000 7600 1300 94 100 101 RDC-01 5/17/2023 39 302 <50 2800 <50 1400 9500 1500 5300 2500 7800 2500 270 68 100 101 98 RDC-01 5/17/2023 41 125 <50 260 <50 130 2400 430 1400 830 2230 440 92 <50 97 101 98 RDC-01 5/17/2023 43 71 <10 69 <10 33 550 190 920 520 1440 340 47 10 99 100 94 RDC-01 5/17/2023 45 35 <10 35 <10 26 14 72 24 14 38 28 38 <10 99 102 98 RDC-01 5/17/2023 47 25 <10 <10 <10 <10 <10 <10 <10 <10 0 9.6 25 <10 97 101 94 RDC-01 5/17/2023 49 12 <0.5 21 <0.5 <0.5 3.4 0.9 3.8 1.9 5.7 2.3 1 <0.5 82 98 96 % Surrogate Recovery Facility name: Catlin - Best Stop #2 Table 1 Soil Analytical Results Chemical of concern (ug/kg) Sample location Sample date Sample depth (ft) PID or OVD reading (ppm) mg/Kg Dimethyl SulfideMTBE1,2-DichloroethaneBenzeneTolueneEthylbenzenem/p-Xyleneo-XyleneTotal Xylene1,2,4-TrimethylbenzeneNaphthaleneTVPH1,2-Dichloroethane-d4d8-Toluenep-Bromofluorobenzene% Surrogate Recovery Facility name: Catlin - Best Stop #2 Table 1 Soil Analytical Results Chemical of concern (ug/kg) Sample location Sample date Sample depth (ft) PID or OVD reading (ppm) RDC-02 5/17/2023 11 24.5 <10 34 <10 <10 <10 <10 <10 <10 0 22 41 <10 75 93 89 RDC-02 5/17/2023 13 23.7 <0.5 100 <0.5 1 1.9 0.6 2.3 1 3.3 1.8 17 <0.5 104 96 82 RDC-02 5/17/2023 15 67.6 <0.5 160 <0.5 <0.5 1.2 0.6 3.1 1.4 4.5 5.3 76 <0.5 103 97 80 RDC-02 5/17/2023 17 55.5 <10 120 <10 <10 <10 <10 <10 <10 0 13 110 <10 76 92 87 RDC-02 5/17/2023 19 44.4 <0.5 670 <0.5 <0.5 2.7 0.9 7.5 12 19.5 89 270 3.4 99 97 83 RDC-02 5/17/2023 21 50.8 <0.5 360 <0.5 <0.5 1.1 <0.5 2.6 3.2 5.8 29 190 2.1 90 95 85 RDC-02 5/17/2023 23 15.2 <0.5 300 <0.5 <0.5 0.9 <0.5 1.2 0.7 1.9 2.9 110 0.7 83 94 84 RDC-02 5/17/2023 25 19.3 <0.5 78 <0.5 <0.5 2.2 <0.5 1.8 0.7 2.5 1.6 46 <0.5 82 92 81 RDC-02 5/17/2023 27 69 <10 390 <10 <10 <10 <10 <10 <10 0 15 78 <10 77 93 88 RDC-02 5/17/2023 29 185 <50 1000 <50 56 <50 86 99 <50 99 68 120 <50 82 93 85 RDC-02 5/17/2023 31 692 <50 250 87 150 <50 210 520 310 830 3900 730 98 82 93 87 RDC-02 5/17/2023 33 401 <10 140 <10 <10 <10 <10 18 24 42 690 250 27 79 93 88 RDC-02 5/17/2023 35 441 <50 70 86 250 1300 2300 10300 3500 13800 36000 460 1100 78 93 89 RDC-02 5/17/2023 37 35 <0.5 3.3 <0.5 2.3 9.2 21 110 50 160 470 11 7.8 83 97 88 RDC-02 5/17/2023 39 23.6 <0.5 0.9 <0.5 <0.5 1.3 1.4 9.9 3.9 13.8 130 3.6 2.1 82 92 88 RDC-02 5/17/2023 41 13.7 <0.5 0.9 <0.5 <0.5 0.8 <0.5 1.4 0.6 2 17 1.1 <0.5 100 93 84 RDC-02 5/17/2023 43 10.9 <0.5 13 <0.5 <0.5 1.9 <0.5 1.2 0.7 1.9 1.1 <0.5 <0.5 95 92 82 mg/Kg Dimethyl SulfideMTBE1,2-DichloroethaneBenzeneTolueneEthylbenzenem/p-Xyleneo-XyleneTotal Xylene1,2,4-TrimethylbenzeneNaphthaleneTVPH1,2-Dichloroethane-d4d8-Toluenep-Bromofluorobenzene% Surrogate Recovery Facility name: Catlin - Best Stop #2 Table 1 Soil Analytical Results Chemical of concern (ug/kg) Sample location Sample date Sample depth (ft) PID or OVD reading (ppm) RDC-03 5/17/2023 11 2.1 <0.5 11 <0.5 <0.5 1.4 <0.5 1.4 0.8 2.2 1.5 <0.5 <0.5 87 91 75 RDC-03 5/17/2023 13 4.2 <0.5 3.5 <0.5 <0.5 0.6 <0.5 0.7 <0.5 0.7 0.9 <0.5 <0.5 106 92 81 RDC-03 5/17/2023 15 19.4 <0.5 15 <0.5 <0.5 0.9 <0.5 1.4 0.7 2.1 2.3 8.5 <0.5 105 95 84 RDC-03 5/17/2023 17 7.1 <0.5 20 <0.5 <0.5 0.9 <0.5 0.9 0.5 1.4 2.2 17 0.7 102 95 86 RDC-03 5/17/2023 19 25.4 <0.5 160 <0.5 0.8 7.1 1.3 10 15 25 58 76 2.1 94 95 88 RDC-03 5/17/2023 21 16.3 <0.5 220 <0.5 4.6 44 9.2 65 72 137 220 140 5 83 93 88 RDC-03 5/17/2023 23 34 <0.5 73 <0.5 <0.5 2 <0.5 2.2 1.3 3.5 4.3 61 0.9 84 91 85 RDC-03 5/17/2023 25 7.3 <0.5 3.9 <0.5 <0.5 1 <0.5 0.9 <0.5 0.9 1 10 <0.5 83 91 84 RDC-03 5/17/2023 27 17.1 <0.5 66 <0.5 <0.5 1.4 <0.5 1.4 0.8 2.2 2.3 75 1 86 92 85 RDC-03 5/17/2023 29 28.1 <10 37 <10 <10 <10 <10 14 <10 14 24 18 <10 105 102 90 RDC-03 5/17/2023 31 163.7 <50 150 <50 110 73 930 5000 3200 8200 26000 3900 330 100 102 99 RDC-03 5/17/2023 33 1330 <50 200 <50 170 10700 18300 68200 33900 102100 63700 11600 1400 99 102 102 RDC-03 5/17/2023 35 233.4 <50 580 <50 1100 18700 10600 38400 16200 54600 36500 4000 650 93 100 99 RDC-03 5/17/2023 37 122.9 <10 530 <10 770 10300 5700 14700 7300 22000 17200 1300 370 94 105 96 RDC-03 5/17/2023 39 100 <50 310 <50 690 3000 840 2700 1100 3800 3900 440 70 98 100 97 RDC-03 5/17/2023 41 31.2 <0.5 83 <0.5 220 140 160 460 150 610 470 36 7.7 81 95 85 RDC-03 5/17/2023 43 24.2 <10 26 <10 72 28 120 450 160 610 1200 54 16 99 100 93 RDC-03 5/17/2023 45 NC <0.5 7 <0.5 35 71 89 290 120 410 410 12 5.3 81 93 85 RDC-03 5/17/2023 47 NC <0.5 2.9 <0.5 5.1 11 20 74 26 100 130 3.9 2.5 83 93 87 RDC-03 5/17/2023 49 NC <0.5 1.5 <0.5 9.5 2.1 22 84 26 110 170 2.2 3.3 83 94 88 mg/Kg Dimethyl SulfideMTBE1,2-DichloroethaneBenzeneTolueneEthylbenzenem/p-Xyleneo-XyleneTotal Xylene1,2,4-TrimethylbenzeneNaphthaleneTVPH1,2-Dichloroethane-d4d8-Toluenep-Bromofluorobenzene% Surrogate Recovery Facility name: Catlin - Best Stop #2 Table 1 Soil Analytical Results Chemical of concern (ug/kg) Sample location Sample date Sample depth (ft) PID or OVD reading (ppm) RDC-04 5/18/2023 11 0 <0.5 0.6 <0.5 <0.5 0.8 <0.5 1.4 0.6 2 1.9 0.5 <0.5 82 91 83 RDC-04 5/18/2023 13 0 <0.5 <0.5 <0.5 <0.5 0.7 <0.5 0.9 <0.5 0.9 1.4 0.6 <0.5 85 91 83 RDC-04 5/18/2023 15 0 <0.5 <0.5 <0.5 <0.5 0.9 <0.5 1 0.6 1.6 1.1 <0.5 <0.5 92 93 81 RDC-04 5/18/2023 17 0 <0.5 <0.5 <0.5 <0.5 1.7 <0.5 1.4 0.8 2.2 1.2 <0.5 <0.5 97 92 81 RDC-04 5/18/2023 19 0 <0.5 <0.5 <0.5 <0.5 2.3 <0.5 0.8 1.7 2.5 0.9 <0.5 <0.5 90 88 70 RDC-04 5/18/2023 21 0 <0.5 <0.5 <0.5 <0.5 0.7 <0.5 0.7 <0.5 0.7 <0.5 <0.5 <0.5 102 95 75 RDC-04 5/18/2023 23 0 <0.5 <0.5 <0.5 <0.5 1.3 <0.5 1 0.5 1.5 0.8 <0.5 <0.5 116 95 78 RDC-04 5/18/2023 25 0 <0.5 0.5 <0.5 <0.5 1.8 <0.5 1.7 0.9 2.6 2.2 1 0.7 122 98 87 RDC-04 5/18/2023 27 0 <0.5 <0.5 <0.5 <0.5 1.1 0.7 1.7 5.8 7.5 1.8 <0.5 12 102 100 112 RDC-04 5/18/2023 29 0 <0.5 <0.5 <0.5 <0.5 2.3 2 3.3 12 15.3 19 4.2 16 85 95 92 RDC-04 5/18/2023 31 0 <0.5 <0.5 <0.5 <0.5 <0.5 6.4 13 43 56 210 17 15 78 92 88 RDC-04 5/18/2023 33 2.6 <0.5 <0.5 <0.5 <0.5 1 19 47 110 157 630 89 37 76 89 96 RDC-04 5/18/2023 35 0 <0.5 <0.5 <0.5 1.9 0.9 3.8 38 77 115 250 33 4.6 72 91 84 RDC-04 5/18/2023 37 0 <0.5 <0.5 <0.5 5.6 <0.5 <0.5 50 92 142 120 40 2 75 91 85 mg/Kg Dimethyl SulfideMTBE1,2-DichloroethaneBenzeneTolueneEthylbenzenem/p-Xyleneo-XyleneTotal Xylene1,2,4-TrimethylbenzeneNaphthaleneTVPH1,2-Dichloroethane-d4d8-Toluenep-Bromofluorobenzene% Surrogate Recovery Facility name: Catlin - Best Stop #2 Table 1 Soil Analytical Results Chemical of concern (ug/kg) Sample location Sample date Sample depth (ft) PID or OVD reading (ppm) RDC-05 5/18/2023 11 0 <0.5 <0.5 <0.5 <0.5 0.8 <0.5 1.4 0.5 1.9 1.4 <0.5 <0.5 77 98 99 RDC-05 5/18/2023 13 0 <0.5 <0.5 <0.5 <0.5 1.1 <0.5 1.8 0.9 2.7 2.1 0.5 <0.5 80 96 93 RDC-05 5/18/2023 15 0 <0.5 <0.5 <0.5 <0.5 0.8 <0.5 1.6 0.8 2.4 1.8 <0.5 <0.5 67 94 94 RDC-05 5/18/2023 17 0 <0.5 <0.5 <0.5 <0.5 1.7 0.6 3 1.6 4.6 3.4 <0.5 <0.5 71 96 92 RDC-05 5/18/2023 19 0 <0.5 <0.5 <0.5 <0.5 0.7 <0.5 1.4 0.5 1.9 1.5 <0.5 <0.5 69 94 96 RDC-05 5/18/2023 21 0 <0.5 <0.5 <0.5 <0.5 1.3 <0.5 1.7 0.8 2.5 1.7 <0.5 <0.5 65 98 95 RDC-05 5/18/2023 23 0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0.6 <0.5 0.6 0.7 <0.5 <0.5 95 98 96 RDC-05 5/18/2023 25 0 <0.5 <0.5 <0.5 <0.5 1.4 <0.5 2.5 1 3.5 2.1 <0.5 <0.5 62 96 92 RDC-05 5/18/2023 27 0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0 0.5 <0.5 <0.5 100 100 96 RDC-05 5/18/2023 29 0 <10 <10 <10 <10 8.8 <10 24 13 37 140 24 8.4 100 101 92 RDC-05 5/18/2023 31 0 <0.5 <0.5 <0.5 <0.5 0.6 <0.5 0.9 0.5 1.4 1.3 <0.5 <0.5 80 98 99 RDC-05 5/18/2023 33 0 <0.5 <0.5 <0.5 <0.5 0.5 <0.5 0.9 <0.5 0.9 1.4 <0.5 <0.5 73 97 91 RDC-05 5/18/2023 35 0 <0.5 <0.5 <0.5 <0.5 1.2 <0.5 2 1 3 2.1 <0.5 <0.5 80 97 94 RDC-05 5/18/2023 37 0 <0.5 <0.5 <0.5 <0.5 2.8 1 4.4 2 6.4 3.2 <0.5 <0.5 83 95 93 RDC-05 5/18/2023 39 0 <0.5 <0.5 <0.5 <0.5 2.1 0.7 3 1.4 4.4 2 <0.5 <0.5 82 97 94 RDC-05 5/18/2023 41 0 <0.5 <0.5 <0.5 <0.5 2.1 0.7 2.7 1.4 4.1 1.9 <0.5 <0.5 88 97 96 RDC-05 5/18/2023 43 0 <0.5 <0.5 <0.5 <0.5 1 0.5 1.1 0.6 1.7 0.9 <0.5 <0.5 97 100 98 RDC-05 5/18/2023 45 0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0 <0.5 <0.5 <0.5 101 93 85 RDC-05 5/18/2023 47 0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0 <0.5 <0.5 <0.5 98 99 93 RDC-05 5/18/2023 49 0 <0.5 3.8 <0.5 <0.5 1.3 <0.5 1.6 0.7 2.3 1.2 <0.5 <0.5 88 99 93 mg/Kg Dimethyl SulfideMTBE1,2-DichloroethaneBenzeneTolueneEthylbenzenem/p-Xyleneo-XyleneTotal Xylene1,2,4-TrimethylbenzeneNaphthaleneTVPH1,2-Dichloroethane-d4d8-Toluenep-Bromofluorobenzene% Surrogate Recovery Facility name: Catlin - Best Stop #2 Table 1 Soil Analytical Results Chemical of concern (ug/kg) Sample location Sample date Sample depth (ft) PID or OVD reading (ppm) RDC-06 5/18/2023 11 0 <0.5 <0.5 <0.5 <0.5 1.2 0.5 2.4 1.1 3.5 2.6 <0.5 <0.5 75 99 90 RDC-06 5/18/2023 13 0 <0.5 <0.5 <0.5 <0.5 1 0.5 1.8 0.9 2.7 1.8 <0.5 <0.5 76 95 92 RDC-06 5/18/2023 15 0 <0.5 <0.5 <0.5 <0.5 1.3 0.6 2.5 1.1 3.6 2.7 <0.5 <0.5 67 96 93 RDC-06 5/18/2023 17 0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 1.1 0.6 1.7 2 <0.5 <0.5 68 97 90 RDC-06 5/18/2023 19 0 <0.5 <0.5 <0.5 <0.5 0.6 <0.5 1.1 0.6 1.7 1.9 <0.5 <0.5 75 95 91 RDC-06 5/18/2023 21 0 <0.5 <0.5 <0.5 <0.5 0.7 <0.5 2.2 0.8 3 5 <0.5 <0.5 64 96 91 RDC-06 5/18/2023 23 0 <10 <10 <10 <10 <10 <10 15 <10 15 59 13 <10 105 97 95 RDC-06 5/18/2023 25 0 <0.5 <0.5 <0.5 <0.5 0.8 <0.5 1.4 0.7 2.1 1.9 <0.5 <0.5 72 97 88 RDC-06 5/18/2023 27 0 <10 <10 <10 <10 <10 <10 11 <10 11 33 <10 <10 101 102 95 RDC-06 5/18/2023 29 0 <0.5 <0.5 <0.5 <0.5 1.2 <0.5 1.9 0.9 2.8 2 <0.5 <0.5 90 95 91 RDC-06 5/18/2023 31 0 <10 <10 <10 <10 <10 <10 <10 <10 0 22 <10 <10 99 99 94 RDC-06 5/18/2023 33 0 <10 <10 <10 <10 <10 <10 10 <10 10 22 <10 <10 100 102 94 RDC-06 5/18/2023 35 0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0.8 <0.5 0.8 0.7 <0.5 <0.5 96 98 94 RDC-06 5/18/2023 37 0 <0.5 <0.5 <0.5 <0.5 1.8 0.6 2.8 1.3 4.1 2.5 0.5 <0.5 83 96 95 RDC-06 5/18/2023 39 0 <0.5 <0.5 <0.5 <0.5 0.9 <0.5 1.2 0.7 1.9 1.1 <0.5 <0.5 95 96 94 RDC-06 5/18/2023 41 0 <0.5 <0.5 <0.5 <0.5 1.3 0.6 2.1 0.8 2.9 2.1 <0.5 <0.5 90 96 95 RDC-06 5/18/2023 43 0 <0.5 <0.5 <0.5 <0.5 1.5 <0.5 2 0.9 2.9 1.3 <0.5 <0.5 92 98 94 RDC-06 5/18/2023 45 0 <10 28 <10 <10 <10 <10 <10 <10 0 18 <10 <10 100 101 95 RDC-06 5/18/2023 47 0 <50 160 <50 110 270 360 930 390 1320 410 <50 <50 96 99 94 RDC-06 5/18/2023 49 0 <50 <50 <50 160 <50 230 290 61 351 150 <50 <50 98 101 97 mg/Kg Dimethyl SulfideMTBE1,2-DichloroethaneBenzeneTolueneEthylbenzenem/p-Xyleneo-XyleneTotal Xylene1,2,4-TrimethylbenzeneNaphthaleneTVPH1,2-Dichloroethane-d4d8-Toluenep-Bromofluorobenzene% Surrogate Recovery Facility name: Catlin - Best Stop #2 Table 1 Soil Analytical Results Chemical of concern (ug/kg) Sample location Sample date Sample depth (ft) PID or OVD reading (ppm) RDC-07 5/18/2023 11 0 <0.5 <0.5 <0.5 <0.5 0.7 0.8 1.9 0.5 2.4 1.8 <0.5 <0.5 76 97 90 RDC-07 5/18/2023 13 0 <10 <10 <10 <10 <10 <10 <10 <10 0 13 <10 <10 101 100 93 RDC-07 5/18/2023 15 0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0.9 <0.5 0.9 1.3 <0.5 <0.5 79 96 91 RDC-07 5/18/2023 17 0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0 <0.5 <0.5 <0.5 108 96 92 RDC-07 5/18/2023 19 0 <0.5 <0.5 <0.5 <0.5 0.6 <0.5 1.2 0.5 1.7 1.5 <0.5 <0.5 76 97 89 RDC-07 5/18/2023 25 0 <0.5 <0.5 <0.5 2.5 10 1.4 6.7 2.3 9 3 <0.5 <0.5 80 97 92 RDC-07 5/18/2023 27 0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0.6 <0.5 0.6 0.7 <0.5 <0.5 80 97 92 RDC-07 5/18/2023 29 0 <0.5 <0.5 <0.5 <0.5 0.5 <0.5 1.9 0.7 2.6 2.2 <0.5 <0.5 97 97 94 RDC-07 5/18/2023 31 0 <10 <10 <10 <10 <10 <10 <10 <10 0 15 <10 <10 100 101 94 RDC-07 5/18/2023 33 0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0.7 <0.5 0.7 1 <0.5 <0.5 106 94 89 RDC-07 5/18/2023 35 0 <0.5 <0.5 <0.5 <0.5 1 0.5 5.7 1.4 7.1 2 <0.5 <0.5 79 97 94 RDC-07 5/18/2023 37 0 <0.5 <0.5 <0.5 <0.5 0.6 <0.5 1 0.5 1.5 1.2 <0.5 <0.5 83 98 92 RDC-07 5/18/2023 39 0 <0.5 <0.5 <0.5 <0.5 1.1 0.6 2.5 0.6 3.1 2.5 <0.5 <0.5 85 98 92 RDC-07 5/18/2023 41 0 <0.5 <0.5 <0.5 <0.5 2.3 1.2 5.7 2.6 8.3 4.2 <0.5 <0.5 89 97 88 RDC-07 5/18/2023 43 0 <0.5 <0.5 <0.5 <0.5 1.1 0.5 2.3 0.9 3.2 2.1 <0.5 <0.5 103 100 91 RDC-07 5/18/2023 45 0 <0.5 <0.5 <0.5 <0.5 1.7 0.6 2.6 1.3 3.9 2.1 <0.5 <0.5 80 98 94 RDC-07 5/18/2023 47 0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 1 <0.5 1 1 <0.5 <0.5 91 97 95 RDC-07 5/18/2023 49 0 <0.5 <0.5 <0.5 0.6 <0.5 1 <0.5 1 0.8 <0.5 <0.5 99 98 97 mg/L Dimethyl SulfideMTBE1,2-DichloroethaneBenzeneTolueneEthylbenzenem/p-Xyleneo-XyleneTotal Xylene1,2,4-TrimethylbenzeneNaphthaleneTVPH1,2-Dichloroethane-d4d8-Toluenep-BromofluorobenzeneMW-01 5/18/2023 25-45 <10 28300 <10 4200 24900 2400 10100 6000 16100 3000 540 120 84 95 88 MW-02 5/18/2023 25-45 <5 810 <5 50 1700 1100 3300 1700 5000 1400 230 33 85 94 86 MW-04 5/18/2023 30-50 <0.5 <0.5 <0.5 0.8 1.6 0.7 11 15 26 13 2.8 0.5 89 93 88 MW-05 5/18/2023 35-45 <5 660 <5 2000 5100 1700 5100 2300 7400 3100 400 63 84 94 87 MW-07R 5/18/2023 40-50 <0.5 59 <0.5 0.8 2.2 0.5 2.2 1 3.2 1.9 0.5 <0.5 89 93 86 OW-04N 5/18/2023 30-40 <50 8800 <50 1900 9300 2300 9400 4100 13500 4100 310 110 89 94 86 RW-01 5/18/2023 40-50 <50 4100 <50 2300 14900 1800 7700 3900 11600 3300 340 100 94 95 89 RDC-04 5/18/2023 32-37 <0.5 <0.5 <0.5 19 2.2 1.4 160 260 420 360 140 4.8 91 94 85 Facility name: Catlin - Best Stop #2 Table 2 Water Analytical Results Sample location Sample date Sample Depth % Surrogate RecoveryChemical of Concern (ug/L) Attachment B Soil Boring Logs 52 48 44 40 36 32 28 24 20 16 12 8 4 0 100 100 100 100 100 100 100 100 RDC-01 (11') RDC-01 (13') RDC-01 (15') RDC-01 (17') RDC-01 (19') RDC-01 (21') RDC-01 (23') RDC-01 (25') RDC-01 (27') RDC-01 (29') RDC-01 (31') RDC-01 (33') RDC-01 (35') RDC-01 (37') RDC-01 (39') RDC-01 (41') RDC-01 (43') RDC-01 (45') RDC-01 (47') RDC-01 (49') <10 <10 <10 <10 <10 <10 <10 <10 <10 <250 <250 <500 750 5000 1400 130 33 26 <10 <0.5 ML CL ML CL Geological logging not performed Red silty clay, dry, slight petroleum odor, some fine tan sand throughout Red clayey silt, dry, slight odor, fine tan sand in horizontal bands from 13-15' Red silty clay, dry, slight petroleum odor, sand in horizontal bands White/tan clayey silt, dry, some sand, slight odor, red banding throughout White/tan clayey silt, some fine sand, dry White/tan clayey silt, some fine sand, moist, moderate odor Tan/white clayey silt, moist, some fine sands, moderate odor, sand lense 32.5-33', dark brown mineralization 34-35' Tan/white clayey silt, moist, some fine sands, moderate odor, dark brown mineralization throughout, saturated 36-37', Silt, white, wet, slight odor Tan clayey silt, saturated, some sand, coarse sand lense at 44' Saturated tan clayey silt, some sand Moist tan sandy silt, slight odor throughout Moist tan sandy silt, coarse sand present, slight odor throughout Boring Terminated 50' <10 <10 <10 <10 <10 <10 <10 <10 <10 700 590 1900 1300 1300 68 <50 10 <10 <10 <0.5 DESCRIPTION NAME (USCS): color, sorting, plasticity, moisture, sorting, grain size, packing Catlin - Best Stop #2 GEX Direct Push Geoprobe 7822 3.25 Dual Tube Nathan Mau Nathan Thacker RDC-01 REC-OVERY(%)LAB I.D.DEPTH(feet)WELL CONSTRUCTION DETAILS AND/OR DRILLING REMARKS Benzene (soil)(ppb) PROJECT MANAGER: PROJECT: BORING IDENTIFICATION: DRILLING CONTRACTOR: DRILLING METHOD: SAMPLING METHOD: DRILLING EQUIPMENT: REG. NO. LOGGED BY: DEPTH TO WATER:CASING: TOTAL DEPTH:SCREEN INTERVAL: DATE FINISHED: DATE STARTED: NORTHING: EASTING: ELEVATION: May 17, 2023 May 17, 2023 50' TVPH (soil) (ppm) AST Environmental Inc.Project No.Page 1 of 15152388 44 40 36 32 28 24 20 16 12 8 4 0 100 100 100 100 100 100 100 RDC-02 (11') RDC-02 (13') RDC-02 (15') RDC-02 (17') RDC-02 (19') RDC-02 (21') RDC-02 (23') RDC-02 (25') RDC-02 (27') RDC-02 (29') RDC-02 (31') RDC-02 (33') RDC-02 (35') RDC-02 (37') RDC-02 (39') RDC-02 (41') RDC-02 (43') <10 1 <0.5 <10 <0.5 <0.5 <0.5 <0.5 <10 56 150 <10 250 2.3 <0.5 <0.5 <0.5 ML CL Geological logging not performed Red silty clay, dry, hard, slight odor, some fine sand Dry crumbly gray/red silty clay, slight odor Dry crumbly gray/red silty clay, moderate odor 17-20' Dry gray/tan clayey silt, slight odor, red mottling throughout Tan clayey silt, moderate odor, horizontal and vertical black streaking throughout, some sand Tan clayey silt, moderate odor, horizontal and vertical black streaking throughout, some sand, moist Black streaked gray/brown clayey silt, slight odor, wet Black streaked gray/brown clayey silt, slight odor, dry Brown clayey silt, moist Brown clayey silt, saturated Brown clayey silt, dry Refusal at 43' <10 <0.5 <0.5 <10 3.4 2.1 0.7 <0.5 <10 <50 98 27 1100 7.8 2.1 <0.5 <0.5 DESCRIPTION NAME (USCS): color, sorting, plasticity, moisture, sorting, grain size, packing Catlin - Best Stop #2 GEX Direct Push Geoprobe 7822 3.25 Dual Tube Nathan Mau Nathan Thacker RDC-02 REC-OVERY(%)LAB I.D.DEPTH(feet)WELL CONSTRUCTION DETAILS AND/OR DRILLING REMARKS Benzene (soil)(ppb) PROJECT MANAGER: PROJECT: BORING IDENTIFICATION: DRILLING CONTRACTOR: DRILLING METHOD: SAMPLING METHOD: DRILLING EQUIPMENT: REG. NO. LOGGED BY: DEPTH TO WATER:CASING: TOTAL DEPTH:SCREEN INTERVAL: DATE FINISHED: DATE STARTED: NORTHING: EASTING: ELEVATION: May 17, 2023 May 17, 2023 43' TVPH (soil) (ppm) AST Environmental Inc.Project No.Page 1 of 15152388 52 48 44 40 36 32 28 24 20 16 12 8 4 0 100 100 100 100 100 100 100 100 RDC-03 (11') RDC-03 (13') RDC-03 (15') RDC-03 (17') RDC-03 (19') RDC-03 (21') RDC-03 (23') RDC-03 (25') RDC-03 (27') RDC-03 (29') RDC-03 (31') RDC-03 (33') RDC-03 (35') RDC-03 (37') RDC-03 (39') RDC-03 (41') RDC-03 (43') RDC-03 (45') RDC-03 (47') RDC-03 (49') <0.5 <0.5 <0.5 <0.5 0.8 4.6 <0.5 <0.5 <0.5 <10 110 170 1100 770 690 220 72 35 5.1 9.5 CL ML CL ML CL Geological logging not performed Dry, hard, red silty clay, small gravel ~12-12.5', crumbly from 14'-15' Dry, crumbly red silty clay with gray mottling, slight odor Dry gray/tan clayey silt, moderate odor, red mottling, some fine sand Tan/gray silty clay, some sand, dry dark banding 28'-30' Gray/brown sandy silt, moist, moderate odor, dark brown/black banding 33'-35' Brown sandy silt, wet, black streaking throughout, moderate odorBrown sandy silt, saturated, black streaking throughout, moderate odorBrown sandy silt, moist, black streaking throughout, moderate odorWhite/brown sandy silt, wet, slight odor, black banding 41' Gray/brown sandy silt, moist, black banding 44' Gray/brown sandy clay, saturated, slight odor Gray/brown sandy clay, moist, some fine gravel, black banding throughout Boring Terminated 50' <0.5 <0.5 <0.5 0.7 2.1 5 0.9 <0.5 1 <10 330 1400 650 370 70 7.7 16 5.3 2.5 3.3 DESCRIPTION NAME (USCS): color, sorting, plasticity, moisture, sorting, grain size, packing Catlin - Best Stop #2 GEX Direct Push Geoprobe 7822 3.25 Dual Tube Nathan Mau Nathan Thacker RDC-03 REC-OVERY(%)LAB I.D.DEPTH(feet)WELL CONSTRUCTION DETAILS AND/OR DRILLING REMARKS Benzene (soil)(ppb) PROJECT MANAGER: PROJECT: BORING IDENTIFICATION: DRILLING CONTRACTOR: DRILLING METHOD: SAMPLING METHOD: DRILLING EQUIPMENT: REG. NO. LOGGED BY: DEPTH TO WATER:CASING: TOTAL DEPTH:SCREEN INTERVAL: DATE FINISHED: DATE STARTED: NORTHING: EASTING: ELEVATION: May 17, 2023 May 17, 2023 50' TVPH (soil) (ppm) AST Environmental Inc.Project No.Page 1 of 15152388 40 38 36 34 32 30 28 26 24 22 20 18 16 14 12 10 8 6 4 2 0 100 100 100 100 100 100 RDC-04 (11') RDC-04 (13') RDC-04 (15') RDC-04 (17') RDC-04 (19') RDC-04 (21') RDC-04 (23') RDC-04 (25') RDC-04 (27') RDC-04 (29') RDC-04 (31') RDC-04 (33') RDC-04 (35') RDC-04 (37') <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 1.9 5.6 CL Geological logging not performed Stiff, dry red silty clay, some tan mottling Stiff, dry red silty clay, some tan mottling, more tan silt present 17'-20' Red/brown silty clay, moist, medium firm, some white mottling, black banding at 22' and 24' Brown, dry sandy clay Red/brown sandy clay with white mottling, moist, black banding both horizontal and vertical throughout, slight odor from 28'-30' Red/brown sandy clay with white mottling, moist, black banding both horizontal and vertical throughout, slight odor Sandy brown clay, wet, moderate odor, more gray/white clay present 33'-35' Tan/red silty clay, wet Tan/red silty clay, dry, some coarse sand/gravel at 38' Refusal at 38' <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0.7 12 16 15 37 4.6 2 DESCRIPTION NAME (USCS): color, sorting, plasticity, moisture, sorting, grain size, packing Catlin - Best Stop #2 GEX Direct Push Geoprobe 7822 3.25 Dual Tube Nathan Mau Nathan Thacker RDC-04 REC-OVERY(%)LAB I.D.DEPTH(feet)WELL CONSTRUCTION DETAILS AND/OR DRILLING REMARKS Benzene (soil)(ppb) PROJECT MANAGER: PROJECT: BORING IDENTIFICATION: DRILLING CONTRACTOR: DRILLING METHOD: SAMPLING METHOD: DRILLING EQUIPMENT: REG. NO. LOGGED BY: DEPTH TO WATER:CASING: TOTAL DEPTH:SCREEN INTERVAL: DATE FINISHED: DATE STARTED: NORTHING: EASTING: ELEVATION: May 18, 2023 May 18, 2023 38'32'-37' TVPH (soil) (ppm) AST Environmental Inc.Project No.Page 1 of 15152388 52 48 44 40 36 32 28 24 20 16 12 8 4 0 100 100 100 90 100 100 100 100 RDC-05 (11') RDC-05 (13') RDC-05 (15') RDC-05 (17') RDC-05 (19') RDC-05 (21') RDC-05 (23') RDC-05 (25') RDC-05 (27') RDC-05 (29') RDC-05 (31') RDC-05 (33') RDC-05 (35') RDC-05 (37') RDC-05 (39') RDC-05 (41') RDC-05 (43') RDC-05 (45') RDC-05 (47') RDC-05 (49') <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <10 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 CL SM CL Geological logging not performed Red/tan clay, dry, sandy, some coarse sand from 12'-13' Red/tan clay, dry, sandy, some coarse sand White/tan sandy clay, dry, red mottling Red sandy clay, dry, ~4" band of white sandy clay at 19' Red/tan sandy clay, dry with white mottling White silty sand, dry gravel 27'-29', dry Red sandy clay, some gravel ~34', moist from 32'-35', brown mottling throughout Red sandy clay, moist, brown mottling throughout, sand/gravel lenses at 36.5', 38', 39', with dark mineralization Tan sandy clay, moist, with vertical black banding Red/gray sandy clay, moist, ~2" small gravel lense at 41', dark mineralization Red/brown sandy clay, wet, some small gravel White/brown sandy clay, moist, more gravel, black banding throughout Boring Terminated 50' <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 8.4 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 DESCRIPTION NAME (USCS): color, sorting, plasticity, moisture, sorting, grain size, packing Catlin - Best Stop #2 GEX Direct Push Geoprobe 7822 3.25 Dual Tube Nathan Mau Nathan Thacker RDC-05 REC-OVERY(%)LAB I.D.DEPTH(feet)WELL CONSTRUCTION DETAILS AND/OR DRILLING REMARKS Benzene (soil)(ppb) PROJECT MANAGER: PROJECT: BORING IDENTIFICATION: DRILLING CONTRACTOR: DRILLING METHOD: SAMPLING METHOD: DRILLING EQUIPMENT: REG. NO. LOGGED BY: DEPTH TO WATER:CASING: TOTAL DEPTH:SCREEN INTERVAL: DATE FINISHED: DATE STARTED: NORTHING: EASTING: ELEVATION: May 18, 2023 May 18, 2023 50' TVPH (soil) (ppm) AST Environmental Inc.Project No.Page 1 of 15152388 52 48 44 40 36 32 28 24 20 16 12 8 4 0 100 100 100 100 60 50 70 70 RDC-06 (11') RDC-06 (13') RDC-06 (15') RDC-06 (17') RDC-06 (19') RDC-06 (21') RDC-06 (23') RDC-06 (25') RDC-06 (27') RDC-06 (29') RDC-06 (31') RDC-06 (33') RDC-06 (35') RDC-06 (37') RDC-06 (39') RDC-06 (41') RDC-06 (43') RDC-06 (45') RDC-06 (47') RDC-06 (49') <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <10 <0.5 <10 <0.5 <10 <10 <0.5 <0.5 <0.5 <0.5 <0.5 <10 110 160 CL SC CL Geological logging not performed Dry red sandy clay with tan mottling Dry tan clayey sand Dry tan/red sandy clay, white sand from 18'-19' Dry tan/red sandy clay, some white mottling Dry tan/white sandy clay, some red mottling, black streaks from 26'-30' Dry tan/white sandy clay, some red mottling, black streaks Gravelly clay, dark brown, dry, small < 5mm gravel Gray/tan sandy clay, moist, some white horizontal striations Tan sandy clay, moist, with some small gravel, white horizontal striations Tan/white sandy clay, saturated, moderate odor Tan sandy clay, moist, with some gravel, slight odor Boring Terminated 50' <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <10 <0.5 <10 <0.5 <10 <10 <0.5 <0.5 <0.5 <0.5 <0.5 <10 <50 <50 DESCRIPTION NAME (USCS): color, sorting, plasticity, moisture, sorting, grain size, packing RDC-06 REC-OVERY(%)LAB I.D.DEPTH(feet)WELL CONSTRUCTION DETAILS AND/OR DRILLING REMARKS Benzene (soil)(ppb) PROJECT MANAGER: PROJECT: BORING IDENTIFICATION: DRILLING CONTRACTOR: DRILLING METHOD: SAMPLING METHOD: DRILLING EQUIPMENT: REG. NO. LOGGED BY: DEPTH TO WATER:CASING: TOTAL DEPTH:SCREEN INTERVAL: DATE FINISHED: DATE STARTED: NORTHING: EASTING: ELEVATION: May 18, 2023 May 18, 2023 50' TVPH (soil) (ppm) Catlin - Best Stop #2 GEX Direct Push Geoprobe 7822 3.25 Dual Tube (10'-25') / Macrocore (25'-50') Nathan Mau Nathan Thacker AST Environmental Inc.Project No.Page 1 of 15152388 52 48 44 40 36 32 28 24 20 16 12 8 4 0 80 0 50 80 70 50 90 RDC-07 (11') RDC-07 (13') RDC-07 (15') RDC-07 (17') RDC-07 (19') RDC-07 (25') RDC-07 (27') RDC-07 (29') RDC-07 (31') RDC-07 (33') RDC-07 (35') RDC-07 (37') RDC-07 (39') RDC-07 (41') RDC-07 (43') RDC-07 (45') RDC-07 (47') RDC-07 (49') <0.5 <10 <0.5 <0.5 <0.5 2.5 <0.5 <0.5 <10 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 CL SC CL CL Geological logging not performed Red sandy clay, dry, with tan mottling Red sandy clay, dry, with tan mottling, more tan sandy clay 18'-20' No recovery Tan/white sandy clay, dry, some small gravel at 27' Red/gray sandy clay, dry, some small gravel 30'-32', white mottling and black streaking throughout Gray/tan sandy clay, thick (~9") zone of black staining/mineralization at 37', more red present below that Gray/tan/red sandy clay, moist Small gravel and black mineralization over brown clayey sand Red/tan sandy clay, moist Red/tan sandy clay, moist, some horizontal black striations throughout Red/tan sandy clay, wet, white mottling and moist 49'-50', some horizontal black striations throughout, gravel interspersed Boring Terminated 50' <0.5 <10 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <10 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 DESCRIPTION NAME (USCS): color, sorting, plasticity, moisture, sorting, grain size, packing RDC-07 REC-OVERY(%)LAB I.D.DEPTH(feet)WELL CONSTRUCTION DETAILS AND/OR DRILLING REMARKS Benzene (soil)(ppb) PROJECT MANAGER: PROJECT: BORING IDENTIFICATION: DRILLING CONTRACTOR: DRILLING METHOD: SAMPLING METHOD: DRILLING EQUIPMENT: REG. NO. LOGGED BY: DEPTH TO WATER:CASING: TOTAL DEPTH:SCREEN INTERVAL: DATE FINISHED: DATE STARTED: NORTHING: EASTING: ELEVATION: May 18, 2023 May 18, 2023 50' TVPH (soil) (ppm) Catlin - Best Stop #2 GEX Direct Push Geoprobe 7822 Macrocore Nathan Mau Nathan Thacker AST Environmental Inc.Project No.Page 1 of 15152388 Attachment C BOS 200 Injection Design Monitoring Well Recovery Well RDC Soil Boring Legend AST Environmental 1567 CF Pours Drive Harrisonburg, Virginia www.astenv.com Best Stop 2 10014 Lancaster Highway Waxhaw, North Carolina NCDEQ Incident #27776 Client Name NCDEQ Project Location Best Stop #2, Waxhaw, NC Area A MW-01 Site Information Predominate Geology of Treatment Zone Treatment Zone Area (ft^2)1,770 1,770 Contamination Depth Start (ft bgs)29.0 Contamination Depth End (ft bgs)45.0 Treatment Volume (yd^3)1,048.9 1,049 Triangular Grid Spacing (ft)7.5 Number of Injection Points - Design 32 32 Injection Interval Distance (ft)1.5 Number of Injection Intervals per Point - Design 12.0 Total Number of Injection Intervals 384 384 Effective Porosity 30% Pore Volume (L)240,607 Soil Density (lb/ft^3)110 Speciated COC Design Calculations Contaminant of Concern Benzene Design Basis Soil (mg/kg) or Groundwater (mg/L)Groundwater Design Concentration 4.200 Design Endpoint (Interim)0.050 Contaminant of Concern Mass Loading (lb/ft^3)7.86E-05 BOS 200 per Injection Interval - Design (lb)50 BOS 200 Slurry Volume per Interval (gal)25 Average BOS 200 per Injection Point (lb)600 BOS 200 Total (lb)19,200 19,200 TPH Design Calculations TPH Groundwater Concentration (mg/L)120 TPH Soil Concentration (mg/kg)1,900 TPH Mass (lb)5,995 BOS 200 per Injection Interval - Design (lb)30 BOS 200 Slurry Volume per Interval (gal)25 Average BOS 200 per Injection Point (lb)360 BOS 200 Total (lb)11,520 11,550 Design Basis Select Speciated or TPH Speciated Design BOS 200 Total per Area (lb)19,200 19,200 Trap & Treat Bacteria Calculations Bacteria Concentrate (gal)38 40 Kinetic Design Additives Supplemental Gypsum per Interval - Design (lb)25 Total Supplemental Gypsum (lb)9,600 9,600 Supplemental Magnesium Sulfate per Interval - Design (lb)25 Total Supplemental Magnesium Sulfate (lb)9,600 9,600 Food Grade Starch per Interval (lb)12.5 Total Food Grade Starch (lb)4,800 4,800 Yeast Extract per Interval (lb)0.33 Total Yeast Extract (lb)127 165 Slurry and Water Volumes Slurry Volume per Interval (gal)25 Estimated Water Volume (gal)9,600 9,600 Totals 7/13/2023 Client Name NCDEQ Project Location Best Stop #2, Waxhaw, NC Area B MW-05 Site Information Predominate Geology of Treatment Zone Treatment Zone Area (ft^2)1,450 1,450 Contamination Depth Start (ft bgs)30.0 Contamination Depth End (ft bgs)49.0 Treatment Volume (yd^3)1,020.4 1,020 Triangular Grid Spacing (ft)7.5 Number of Injection Points - Design 26 26 Injection Interval Distance (ft)1.5 Number of Injection Intervals per Point - Design 13.5 Total Number of Injection Intervals 351 351 Effective Porosity 30% Pore Volume (L)234,065 Soil Density (lb/ft^3)110 Speciated COC Design Calculations Contaminant of Concern Benzene Design Basis Soil (mg/kg) or Groundwater (mg/L)Groundwater Design Concentration 2.000 Design Endpoint (Interim)0.025 Contaminant of Concern Mass Loading (lb/ft^3)3.74E-05 BOS 200 per Injection Interval - Design (lb)40 BOS 200 Slurry Volume per Interval (gal)25 Average BOS 200 per Injection Point (lb)540 BOS 200 Total (lb)14,040 14,050 TPH Design Calculations TPH Groundwater Concentration (mg/L)63 TPH Soil Concentration (mg/kg)1,400 TPH Mass (lb)4,284 BOS 200 per Injection Interval - Design (lb)30 BOS 200 Slurry Volume per Interval (gal)25 Average BOS 200 per Injection Point (lb)405 BOS 200 Total (lb)10,530 10,550 Design Basis Select Speciated or TPH Speciated Design BOS 200 Total per Area (lb)14,040 14,050 Trap & Treat Bacteria Calculations Bacteria Concentrate (gal)28 30 Kinetic Design Additives Supplemental Gypsum per Interval - Design (lb)25 Total Supplemental Gypsum (lb)8,775 8,800 Supplemental Magnesium Sulfate per Interval - Design (lb)25 Total Supplemental Magnesium Sulfate (lb)8,775 8,800 Food Grade Starch per Interval (lb)12.5 Total Food Grade Starch (lb)4,388 4,400 Yeast Extract per Interval (lb)0.33 Total Yeast Extract (lb)116 165 Slurry and Water Volumes Slurry Volume per Interval (gal)25 Estimated Water Volume (gal)8,775 8,775 Totals 7/13/2023 Client Name NCDEQ Project Location Best Stop #2, Waxhaw, NC Area C RDC-04 Site Information Predominate Geology of Treatment Zone Saprolite Treatment Zone Area (ft^2)1,100 1,100 Contamination Depth Start (ft bgs)33.0 Contamination Depth End (ft bgs)38.0 Treatment Volume (yd^3)203.7 204 Triangular Grid Spacing (ft)7.5 Number of Injection Points - Design 20 20 Injection Interval Distance (ft)1.5 Number of Injection Intervals per Point - Design 4.0 Total Number of Injection Intervals 80 80 Effective Porosity 30% Pore Volume (L)46,728 Soil Density (lb/ft^3)110 Speciated COC Design Calculations Contaminant of Concern Benzene Design Basis Soil (mg/kg) or Groundwater (mg/L)Groundwater Design Concentration 0.019 Design Endpoint 0.001 Contaminant of Concern Mass Loading (lb/ft^3)3.56E-07 BOS 200 per Injection Interval - Design (lb)25 BOS 200 Slurry Volume per Interval (gal)25 Average BOS 200 per Injection Point (lb)100 BOS 200 Total (lb)2,000 2,000 Design Basis Select Speciated or TPH Speciated Design BOS 200 Total per Area (lb)2,000 2,000 Trap & Treat Bacteria Calculations Bacteria Concentrate (gal)4 5 Slurry and Water Volumes Slurry Volume per Interval (gal)25 Estimated Water Volume (gal)2,000 2,000 Summary BOS 200 Total (lb)2,000 BOS 200 Unit Price ($, per RPI website)$6.25 Bacteria Concentrate (gal)5 Bacteria Concentrate Price ($, per RPI website)$115.00 Estimated Shipping and Tax ($/lb)$0.35 Total Material Price ($)$13,775 Number of Field Days to Complete 3 Mobilization ($)$3,500 Injection Location Markout ($) Total Installation Price ($)$26,000 Total Estimated Price ($)$39,775 Totals 7/13/2023 Client Name NCDEQ Project Location Best Stop #2, Waxhaw, NC Area D MW-02 Site Information Predominate Geology of Treatment Zone Saprolite Treatment Zone Area (ft^2)1,370 1,370 Contamination Depth Start (ft bgs)46.0 Contamination Depth End (ft bgs)50.0 Treatment Volume (yd^3)203.0 203 Triangular Grid Spacing (ft)7.5 Number of Injection Points - Design 24 24 Injection Interval Distance (ft)1.5 Number of Injection Intervals per Point - Design 3.5 Total Number of Injection Intervals 84 84 Effective Porosity 30% Pore Volume (L)46,558 Soil Density (lb/ft^3)110 Speciated COC Design Calculations Contaminant of Concern Benzene Design Basis Soil (mg/kg) or Groundwater (mg/L)Groundwater Design Concentration 0.067 Design Endpoint 0.001 Contaminant of Concern Mass Loading (lb/ft^3)1.25E-06 BOS 200 per Injection Interval - Design (lb)35 BOS 200 Slurry Volume per Interval (gal)25 Average BOS 200 per Injection Point (lb)123 BOS 200 Total (lb)2,940 2,950 Design Basis Select Speciated or TPH Speciated Design BOS 200 Total per Area (lb)2,940 2,950 Trap & Treat Bacteria Calculations Bacteria Concentrate (gal)6 10 Slurry and Water Volumes Slurry Volume per Interval (gal)25 Estimated Water Volume (gal)2,100 2,100 Summary BOS 200 Total (lb)2,950 BOS 200 Unit Price ($, per RPI website)$6.25 Bacteria Concentrate (gal)10 Bacteria Concentrate Price ($, per RPI website)$115.00 Estimated Shipping and Tax ($/lb)$0.35 Total Material Price ($)$20,620 Number of Field Days to Complete 4 Mobilization ($)$3,500 Injection Location Markout ($) Total Installation Price ($)$33,500 Total Estimated Price ($)$54,120 Totals 7/13/2023