18038_AquAir II_final Grade Sampling Compliance and Report 20230929

September 29, 2023 Sent Via E-mail
Robert Combs TKC Land Development II, LLC
4500 Cameron Valley Parkway, Suite 400 Charlotte, NC 28211 [e-mail]
Subject: Final Grade Sampling Compliance Review AquAir II Brownfields Project Charlotte, Mecklenburg County Brownfields Project Number 18038-14-060 Dear Mr. Combs,
The North Carolina Department of Environmental Quality Brownfields Redevelopment Section (DEQ Brownfields) received and reviewed the Final Grade Soil Assessment Report (Report) dated August 25, 2023, prepared by Hart & Hickman on your behalf.
DEQ Brownfields has reviewed the Report and evaluated the analytical data using the DEQ Risk
Calculator. The results of this evaluation for soil were below the DEQ thresholds for non-residential use. DEQ Brownfields has found this Report to be in compliance with Environmental Management Plan (EMP) dated November 18, 2021, and the previously approved work plan dated June 5, 2023.
Please be advised that this compliance review from DEQ Brownfields does not waive any applicable requirement to obtain any necessary permits, licenses or certifications which may be required from other state or local entities. If you have any questions, please contact me at (704) 661-10330, or via e-mail at [e-mail]. Sincerely,
Carolyn Minnich Project Manager
Brownfields Redevelopment Section ec: Steve Hart [e-mail] BFPropertyManagement [e-mail]
i
https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/the keith corporation (tkc)/2021 new
building/final grade/final grade report/18038 - fg soil assessment report - aquair ii.doc

Final Grade Soil Assessment Work Plan
AquAir II Brownfields Site – West Side
13300 Sam Neely Road
Charlotte, North Carolina
Brownfields Project No. 18038-14-060
H&H Job No. TKC-008

Table of Contents

1.0 Introduction .............................................................................................................................1
2.0 Final Grade Soil Assessment Activities ..................................................................................3
2.1 Final Grade Soil Sampling Activities ....................................................................................3
2.2 Soil Analytical Results ..........................................................................................................5
2.3 Risk Evaluation .....................................................................................................................6
3.0 Summary and Conclusions ....................................................................................................7

Tables

Table 1 Summary of Final Grade Soil Sample Analytical Results

Figures

Figure 1 Site Location Map
Figure 2 Final Grade Soil Sample Location Map

Appendices

Appendix A Soil Boring Log Summary
Appendix B Laboratory Analytical Report
Appendix C DEQ Risk Calculator
1
https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/the keith corporation (tkc)/2021 new
building/final grade/final grade report/18038 - fg soil assessment report - aquair ii.doc

Final Grade Soil Assessment Work Plan
AquAir II Brownfields Site – West Side
13300 Sam Neely Road
Charlotte, North Carolina
Brownfields Project No. 18038-14-060
H&H Job No. TKC-008

1.0 Introduction

On behalf of TKC CCCX, LLC (the current Site owner), Hart & Hickman, PC (H&H) has
prepared this report to document final grade soil assessment activities for the west side of the
AquAir II Brownfields property (Brownfields Project No. 18038-14-060). The west side of the
Brownfields property is located at 13300 Sam Neely Road in Charlotte, Mecklenburg County,
North Carolina (Site). The Brownfields agreement for the AquaAir II property includes two
contiguous parcels, totaling approximately 154 acres, which are separated by the Southern
Railway tracks. The subject Site consists of the portion of the Brownfields property to the west
of the railway, which is an approximately 80-acre parcel (Mecklenburg County Parcel ID
20141101). The portion of the Brownfields property to the east of the railroad tracks was
previously redeveloped with a warehouse building for Staples, Inc. in 2017/2018 and is currently
owned by Gear 3725 Westinghouse LLC. A Site location map is provided as Figure 1.

The North Carolina Department of Environmental Quality (DEQ) approved Environmental
Management Plan (EMP) for the Site dated November 18, 2021 includes a requirement for the
collection of final grade soil samples in areas of the Site that are not covered with buildings,
sidewalks, concrete or asphaltic paved (hardscape) surfaces, or a minimum of two feet of
demonstrably clean fill. To assist with final grade soil sampling, H&H prepared and submitted
the Final Grade Soil Assessment Work Plan (Work Plan) to DEQ on June 5, 2023. The Work
Plan was subsequently approved by DEQ on June 5, 2023.

As discussed in the Work Plan, redevelopment at the Site is being completed in two phases. The
first phase of redevelopment includes construction of one industrial warehouse building, a
guardhouse, a fire pumphouse, associated outdoor storage areas, roadways and parking, and a
railroad extension. The first phase of construction is nearing completion and the Site is currently
2
https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/the keith corporation (tkc)/2021 new
building/final grade/final grade report/18038 - fg soil assessment report - aquair ii.doc

being prepared for the second phase of redevelopment. The second phase of redevelopment will
include the construction of a second industrial warehouse building located in the southern
portion of the Site (Figure 2). Because redevelopment on the northern portion of the Site is
nearing completion and the southern portion of the Site is still underway, the DEQ-approved
Work Plan was prepared only for the northern portion of the Site. A Final Grade Soil
Assessment Work Plan will be prepared and submitted for the southern portion of the Site under
separate cover. A description of the final grade soil sampling activities is included in the
following sections.

3
https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/the keith corporation (tkc)/2021 new
building/final grade/final grade report/18038 - fg soil assessment report - aquair ii.doc

2.0 Final Grade Soil Assessment Activities

Final grade soil assessment activities were conducted at the Site to evaluate potential direct
exposure risks to future Site occupants and workers from shallow soil in landscaped areas. The
soil sampling activities were conducted in general accordance with the DEQ Inactive Hazardous
Sites Branch (IHSB) Guidelines for Assessment and Cleanup (Guidelines) dated September
2022, the most recent versions of U.S. Environmental Protection Agency (EPA) Region IV
Laboratory Services and Applied Science Division (LSASD) Field Branches Quality System and
Technical Procedures guidance, and the DEQ-approved Work Plan.

The purpose of the final grade soil sampling activities described herein was to evaluate the
potential for impacts in shallow soil within unpaved areas in the northern portion of the Site
where final grade elevations have been achieved. Areas of the Site that are not hardscape
include wetlands, surface water and retaining ponds, and landscaped areas along the Site
boundaries. An overlay of the Site development with landscaped areas shown in green shading,
wetlands shown in brown, and surface water features shown in blue is provided in Figure 2.
Please note, the Area of Possible Soil Contamination, as outlined on the recorded Brownfields
Plat and shown on Figure 2, is under the building footprint and the associated paved parking and
storage areas; therefore, no soil aliquots were collected from that area as part of the final grade
soil assessment.

2.1 Final Grade Soil Sampling Activities

Based on review of the Site Plan and observations at the Site, landscaped areas were divided into
five (5) final grade evaluation areas (FG-1 through FG-5). Four to five shallow soil borings were
advanced within each final grade evaluation area for the collection of aliquot soil samples. As
discussed further below, the soil sample aliquots were combined and homogenized to form a
composite soil sample representative of shallow soil conditions in each evaluation area. The
final grade evaluation areas and approximate locations of the aliquot soil borings are shown in
Figure 2.

4
https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/the keith corporation (tkc)/2021 new
building/final grade/final grade report/18038 - fg soil assessment report - aquair ii.doc

Aliquot soil borings were advanced from the surface to approximately two feet below the ground
surface (ft bgs) using a decontaminated stainless-steel hand auger. During boring advancement,
continuous soil samples were collected from the center of the hand auger bucket. Soil samples
were described for lithologic purposes and observed for obvious evidence of staining and
unusual odors. Soil lithology at the aliquot locations generally consisted of moist clayey silt. A
summary of aliquot soil boring lithology and PID readings is provided in Appendix A. The
aliquot soil sample locations for each final grade area are shown in Figure 2.

Remaining portions of the aliquot soil samples were homogenized to form a composite soil
sample representative of each evaluation area for a total of five (5) composite final grade soil
samples. Soil samples were collected directly into laboratory-supplied glassware, labeled with
the sample identification, date, and requested analysis, and placed in a laboratory-supplied cooler
with ice. The samples will be delivered to a North Carolina-certified laboratory under standard
chain of custody protocols for the analyses outlined below.

The composite soil samples were submitted for laboratory analysis of semi-volatile organic
compounds (SVOCs) by EPA Method 8270, Resource Conservation and Recovery Act (RCRA)
metals plus copper, nickel, vanadium, zinc, and hexavalent chromium by EPA Methods
6020/7471/7199.

In addition to the composite samples, one grab sample was collected from each evaluation area
for analysis of volatile organic compounds (VOCs) by EPA Method 8260. The grab sample was
collected from an undisturbed portion of an aliquot soil sample. Because field screening did not
indicate the obvious evidence of impacts, the grab samples were collected from a randomly
selected aliquot soil boring location in each evaluation area as indicated in the tabular summary
included in Appendix A.

For quality assurance and quality control purposes (QA/QC), H&H collected one duplicate
composite samples (FG-DUP) from sample location FG-1 for SVOCs and RCRA metals plus
copper, nickel, vanadium, zinc, and hexavalent chromium by EPA Methods 6020/7471/7199.
H&H also collected a duplicate grab sample from the same FG-1 aliquot location where the
5
https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/the keith corporation (tkc)/2021 new
building/final grade/final grade report/18038 - fg soil assessment report - aquair ii.doc

parent VOC sample was collected. A tabular summary of the duplicate sample result along with
the final grade sample analytical results are provided in Table 1. Review of the duplicate sample
laboratory analytical data in comparison to the parent samples indicate comparable results that
are within typical laboratory variability. The analytical results suggest satisfactory laboratory
analytical reproducibility.

Following sampling activities, the soil borings were abandoned and the surfaces were repaired
similar to pre-drilling conditions. Additionally, the soil boring locations were estimated using a
hand-held global positioning system (GPS) unit.

2.2 Soil Analytical Results

A tabular summary of final grade soil sample analytical results is presented in Table 1, and the
laboratory analytical reports and chain of custody records are provided in Appendix B. The
laboratory analytical results included in were compared to the DEQ Industrial/Commercial
PSRGs dated July 2023. In addition to the PSRGs, metals results were compared to published
concentrations for naturally occurring metals in North Carolina soil.

Laboratory analytical results indicate that several low-level concentrations of organic compounds
were detected in FG-1/FG-DUP, FG-3, and FG-4 above laboratory method detection limits. The
compounds included 2-butanene, acetone, chloromethane, and p-isopropyltoluene, and the
detected concentrations are well below the Industrial/Commercial PSRGs. No other organic
compounds were detected above laboratory method detection limits.

As expected, several metals were detected at concentrations above laboratory method detection
limits in each final grade sample collected at the Site. The detected metal concentrations did not
exceed the DEQ Industrial/Commercial PSRGs and were generally consistent with published
background concentrations and are considered representative of naturally occurring levels.

6
https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/the keith corporation (tkc)/2021 new
building/final grade/final grade report/18038 - fg soil assessment report - aquair ii.doc

2.3 Risk Evaluation

DEQ PSRGs are very conservative and based upon a Target Cancer Risk (TCR) of 1 x 10-6 for
potential carcinogenic effects and a Hazard Quotient (HQ) of 0.2 for potential non-carcinogenic
effects. Additional assessment or remediation is not typically warranted if the calculated
cumulative lifetime incremental carcinogenic risk (LICR) is 1 x 10-4 or less and the acceptable
level for non-carcinogenic risk is a calculated cumulative hazard index (HI) of 1.0 or less.

Although no compounds were detected above the Industrial/Commercial PSRGs, H&H utilized
the DEQ Risk Calculator (July 2023) to further evaluate potential cumulative risks for the direct
exposure pathway assuming a non-residential use scenario. To model the potential for exposure
risk under a hypothetical “worst-case” scenario, H&H conservatively calculated the cumulative
risks using the highest concentration of any compound detected in any final grade soil sample
collected from the Site. Please note that although most of the metal concentrations are likely
naturally occurring, the concentration of metals detected were included as a conservative
measure. Risk calculator results are summarized in the table below and a copy of the completed
risk calculator is provided in Appendix C.

Land Use Scenario Calculated
Cumulative LICR
Calculated
Cumulative HI
Calculated LICR or
HI Exceeds
Acceptable Risk
Levels?
Non-Residential 1.6 x 10-6 0.049 No

The results of the risk calculation indicate that the calculated cumulative risks do not exceed
acceptable carcinogenic or noncarcinogenic risk levels for a non-residential use exposure
scenario. As such, additional assessment or remediation is not warranted.
7
https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/the keith corporation (tkc)/2021 new
building/final grade/final grade report/18038 - fg soil assessment report - aquair ii.doc

3.0 Summary and Conclusions

H&H has completed final grade soil sampling activities for the first redevelopment phase on the
west side of the AquAir II Brownfields property located at 13300 Sam Neely Road in Charlotte,
Mecklenburg County, North Carolina. The final grade soil sampling activities were conducted in
accordance with the DEQ Brownfields approved Work Plan. Final grade soil sampling activities
included the collection of soil samples to evaluate the potential for impacts in landscaped areas at
the Site not covered by impervious surfaces following redevelopment.

Laboratory analytical results indicate that several VOCs and metals were detected at
concentrations above the laboratory method detection limits in the final grade soil samples
collected at the Site, but the detected concentrations did not exceed DEQ Industrial/Commercial
PSRGs.

Potential cumulative risks for the direct exposure soil pathway for a non-residential use scenario
was conservatively calculated using the highest concentrations detected in the final grade soil
samples. The results of the risk calculation indicate that the calculated LICR is 1.6 x 10-6 and the
HI is 0.049. The calculated carcinogenic and noncarcinogenic risks do not exceed acceptable
levels for a non-residential use exposure scenario and additional assessment or remediation is not
warranted.

Tables
Table 1Summary of Final Grade Soil Sample Analytical ResultsAquaAir II Brownfields Site - West SideCharlotte, North CarolinaH&H Job No. TKC-008Evaluation AreaBackground MetalsSample IDDateDepth (ft bgs)1-2 0-2 1-2 0-2 1-2 0-2 1-2 0-2 1-2 0-2 1-2 0-2Sample Type Grab Composite Grab Composite Grab Composite Grab Composite Grab Composite Grab Composite UnitsVOCs (8260D)2-Butanone (MEK)<0.0275 NA <0.0419 NA <0.0314 NA0.0369 JNA <0.0321 NA <0.0342 NA40,000--Acetone0.0579 JNA <0.0560 NA <0.0420 NA0.119 JNA <0.0430 NA <0.0458 NA210,000--Chloromethane<0.0048 NA0.0168 JNA <0.0055 NA <0.0053 NA <0.0056 NA <0.0060 NA99--p-Isopropyltoluene<0.0028 NA <0.0043 NA <0.0032 NA0.437NA0.0076NA <0.0035 NANE--SVOCs (8270E)NA ALL BDL NA ALL BDL NA ALL BDL NA ALL BDL NA ALL BDL NA ALL BDL-- --Metals (6020B/7471B/7199)ArsenicNA2.3NA2.4NA1.2NA2.5NA2.4NA1.9 3.0 1.0 - 18BariumNA115NA184NA105NA103NA192NA142 47,000 50 - 1,000CadmiumNA0.078 JNA0.043 JNA0.040 JNA0.061 JNA0.051 JNA0.094 J 20 1.0 - 10Chromium (total)NA94.4NA54.2NA18.7NA51.9NA197NA59.1 NE 7.0 - 300Hexavalent ChromiumNA0.663 JNA1.40NA0.939 JNA2.02NA5.31NA1.16 J 6.5 NSTrivalent ChromiumNA93.7NA52.8NA17.8NA49.9NA192NA57.9 350,000 NSCopperNA15.6NA21.4NA20.5NA21.8NA21.8NA15.8 9,300 3.0 - 100LeadNA15.0NA11.3NA2.8NA11.4NA10.6NA7.9 800 ND - 50MercuryNA0.031NA0.015 JNA <0.010 NA0.025NA0.033NA0.020 J 70 0.03 - 0.52NickelNA41.0NA29.2NA17.4NA26.5NA62.0NA32.1 4,700 ND - 150SeleniumNA0.62NA0.68NA0.36 JNA0.55NA0.47 JNA0.47 J 1,200 <0.1 - 0.8SilverNA <0.23 NA <0.27 NA <0.25 NA <0.22 NA <0.24 NA <0.251,200 ND - 5.0VanadiumNA198NA188NA93.3NA209NA215NA218 1,200 15 - 300ZincNA32.9NA49.0NA40.6NA31.1NA35.6NA34.5 70,000 25 - 124Notes:1) North Carolina Department of Environmental Quality (DEQ) Residential Preliminary Soil Remediation Goals (PSRGs) dated July 2023. 2) Range values of background metals for North Carolina soils taken from Elements in North American Soils by Dragun and Chekiri, 2005. Cd and Ag concentrations were taken from Southeastern & Conterminous US soils. Concentrations are reported in milligrams per kilogram (mg/kg).Concentrations are reported to the laboratory method detection limits.Laboratory analytical methods are shown in parentheses. With the exception of metals, only those compounds detected in at least one sample are shown in the table above. VOCs = volatile organic compounds; SVOCs = semi-volatile organic compounds; ft bgs = feet below ground surface; NS = not specified; NE = not established; -- = not applicable; ND = not detected; NA = not analyzed; BDL = below laboratory method detection limitJ = Compound was detected above the laboratory method detection limit but below the laboratory reporting limit resulting in a laboratory estimated concentration. FG-1 / FG-DUP FG-2 FG-3 FG-4 FG-5Final GradeScreening CriteriaIndustrial/CommericalPSRGs (1)Published Range(2)6/14/2023 6/14/2023 6/14/2023 6/14/2023 6/14/2023mg/kghttps://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/The Keith Corporation (TKC)/2021 New Building/Final Grade/Final Grade Report/Analytical/Final Grade Sample Analytical Results 18/24/2023Table 1 (Page 1 of 1) Hart & Hickman, PC

Figures
BROWNFIELDS
PROPERTY
0 2000 4000
APPROXIMATE
SCALE IN FEET
N
U.S.G.S. QUADRANGLE MAP
QUADRANGLE
7.5 MINUTE SERIES (TOPOGRAPHIC)
CHARLOTTE WEST, NORTH CAROLINA, 1996
TITLE
PROJECT
SITE LOCATION MAP
AQUAIR II BROWNFIELDS SITE - WEST SIDE 13300 SAM NEELY ROAD
CHARLOTTE, NORTH CAROLINA
DATE:
JOB NO:
REVISION NO:
FIGURE:
10-28-21 0
1TKC-008
SITE
BOUNDARY
CR
L
L
L
L
L
L
L
L
L
L
L
L
L
L
L
L
L
L
L
L
L
FD
EF
L
CRCR
CR
REVISION NO. 0
JOB NO. TKC-008
DATE: 8-24-23
FIGURE NO. 2
AQUAIR II BROWNFIELDS SITE - WEST SIDE
13300 SAM NEELY ROAD
CHARLOTTE, NORTH CAROLINA
FINAL GRADE SOIL
SAMPLE LOCATION MAP
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
LEGEND
BROWNFIELDS PROPERTY BOUNDARY
SITE BOUNDARY
LIMITS OF GROUNDWATER CONTAMINATION
RAILROAD TRACKS
SURFACE WATER FEATURE
FENCE LINE
BUILDING FOOTPRINT
AREA OF POSSIBLE SOIL
CONTAMINATION
APPROXIMATE SOIL STOCKPILE LOCATION
LANDSCAPED AREA
SURFACE WATER AREA / POND
WETLANDS AREA
ALIQUOT SOIL SAMPLE LOCATION
SAM NEELY ROAD
ALRO STEEL CORP.
(12933 SAM NEELY ROAD)
LAZY OAK LANE
RESIDENTIALRESIDENTIAL
TEXAS PIPE & SUPPLY CO.
(12910 SAM NEELY ROAD)
EXISTING STAPLES
WAREHOUSE BUILDING
STORMWATER MANAGEMENT
POND
SOURCES
1.
2.
SITE PLAN PROVIDED BY BURTON ENGINEERING.
AERIAL PHOTOGRAPH FROM MECKLENBURG
COUNTY GIS.
APPROXIMATE
STOCKPILE LOCATION
FUTURE
CAROWINDS
BOULEVARD
FG-3
FG-5
FG-2
FG-1
FG-4
E
D
A
B
C
A
A
A
A
B
B
B
B
C
C
C
C
D
D D
D
E
E
E
PHASE II
REDEVELOPMENT AREA
S:\AAA-Master Projects\The Keith Corporation (TKC)\2021 New Building\EMP\figures\Final Grade_R1.dwg, FINAL GRADE, SVincent

Appendix A

Soil Boring Log Summary
Appendix A
Soil Boring Log Summary
AquaAir II Brownfields Site - West Side
Charlotte, North Carolina
H&H Job No. TKC-008
Evaluation Area &
Composite Sample ID Aliquot Location Date
Depth
(ft bgs)Lithology PID Reading
(ppm)Notes
0-1 Wet, Soft, Brown Sandy Clay, Few Fine Gravel 1.0
1-2 Wet, Stiff, Brown, Sandy Clay 1.1
0-1 Moist, Medium Stiff, Brown Sandy Clay 1.8
1-2 Moist, Medium Stiff, Brown Sandy Clay 2.2 Grab VOC sample collected for laboratory analysis
0-1 Moist, Medium Stiff, Brown Sandy Clay 2.2
1-2 Moist, Medium Stiff, Brown Sandy Clay 2.0
0-1 Wet, Stiff, Brown Sandy Clay 1.9
1-2 Wet, Loose, Brown-Gray Clayey Gravel 1.8
0-1 Wet, Soft, Brown Sandy Clay 0.9
1-2 Moist, Soft, Brown Sandy Silt, Trace Fine Gravel 2.0
0-1 Wet, Soft, Brown Sandy Clay, Trace Fine Gravel 1.2
1-2 Wet, Soft, Brown Sandy Clay, Trace Fine Gravel 1.8
0-1 Wet, Soft, Brown Sandy Clay 2.5
1-2 Wet, Soft, Brown Sandy Clay 2.4
0-1 Wet, Soft, Brown Sandy Clay 2.4
1-2 Wet, Soft, Brown Sandy Clay 2.4
0-1 Wet, Soft, Brown Sandy Clay 2.8
1-2 Wet, Soft, Brown Sandy Clay 2.3 Grab VOC sample collected for laboratory analysis
0-1 Moist, Medium Stiff, Brown Sandy Clay 2.2
1-2 Moist, Medium Stiff, Brown Sandy Clay 3.4
0-1 Moist, Medium Stiff, Brown-Gray Sandy Clay 3.2
1-2 Moist, Medium Stiff, Brown-Gray Sandy Clay 7.8 Grab VOC sample collected for laboratory analysis
0-1 Moist, Medium Stiff, Brown Sandy Clay 4.0
1-2 Moist, Medium Stiff, Brown Sandy Clay 4.2
0-1 Moist, Medium Stiff, Brown Sandy Clay 2.2
1-2 Moist, Medium Stiff, Brown Sandy Clay 2.7
0-1 Moist, Medium Stiff, Brown Sandy Clay 1.3
1-2 Wet, Medium Stiff, Brown Sandy Clay 2.3
0-1 Wet, Medium Stiff, Brown Sandy Clay, Few Silt, Trace Fine Gravel 1.8
1-2 Wet, Medium Stiff, Brown Sandy Clay, Few Silt, Trace Fine Gravel 2.0 Grab VOC sample collected for laboratory analysis
0-1 Moist, Stiff, Brown Silty Clay 0.8
1-2 Moist, Medium Stiff, Brown Silty Clay, Few Gravel 1.2
0-1 Wet, Medium Stiff, Brown Sandy Clay, Few Silt, Trace Fine Gravel 1.3
1-2 Wet, Medium Stiff, Brown Sandy Clay, Few Silt, Trace Fine Gravel 1.6
0-1 Moist, Soft, Brown Sandy Silt, Few Clay 2.0
1-2 Moist, Soft, Brown Sandy Silt, Few Clay 1.8
0-1 Wet, Medium Stiff, Brown Sandy Clay, Few Silt, Trace Fine Gravel 1.9
1-2 Wet, Medium Stiff, Brown Sandy Clay, Few Silt, Trace Fine Gravel 1.0
0-1 Wet, Soft, Brown Sandy Clay, Few Silt, Trace Fine Gravel 0.9
1-2 Moist, Soft, Brown Sandy Clay, Few Silt, Trace Fine Gravel 1.6
0-1 Wet, Soft, Brown Sandy Clay, Few Silt, Trace Fine Gravel 0.9
1-2 Moist, Soft, Brown Sandy Silt, Few Clay 1.1
0-1 Wet, Soft, Brown Sandy Clay, Few Silt, Trace Fine Gravel 1.8
1-2 Moist, Stiff, Brown Sandy Clay 0.5
0-1 Wet, Soft, Brown Sandy Clay, Few Silt, Trace Fine Gravel 1.7
1-2 Moist, Soft, Brown Sandy Clay, Few Silt, Trace Fine Gravel 2.0 Grab VOC sample collected for laboratory analysis
0-1 Wet, Soft, Brown Sandy Clay, Few Silt, Trace Fine Gravel 0.4
1-2 Moist, Soft, Brown Sandy Clay, Few Silt, Trace Fine Gravel 0.8
Notes:
1) Composite sample collected for laboratory analysis of semi-VOCs, RCRA metals, and hexavalent chromium
PID = photoionization detector; VOC = volatile organic compound; ppm = parts per million; ft bgs = feet below ground surface
FG-5
FG-4
FG-3
FG-2
6/14/2023
FG-5A
FG-5B
FG-5C
FG-5D
FG-5E
6/14/2023
6/14/2023
6/14/2023
6/14/2023
FG-4A
FG-4B
FG-4C
FG-4D
FG-4E
6/14/2023
6/14/2023
6/14/2023
6/14/2023
6/14/2023
FG-3B
FG-3C
FG-3D
FG-3E
6/14/2023
6/14/2023
6/14/2023
6/14/2023
6/14/2023
6/14/2023
6/14/2023
6/14/2023
6/14/2023
6/14/2023
FG-3A
FG-1
FG-2A
FG-2B
FG-2C
FG-2D
FG-2E
FG-1A
FG-1B
FG-1C
FG-1D
6/14/2023
6/14/2023
6/14/2023
6/14/2023
Appendix A (Page 1 of 1)
Hart & Hickman

Appendix B

Laboratory Analytical Report
#=CL#
June 29, 2023
LIMS USE: FR - ALEXIS MCKENZIE
LIMS OBJECT ID: 92672976
92672976
Project:
Pace Project No.:
RE:
Alexis McKenzie
Hart & Hickman
2923 S Tryon Street
Suite 100
Charlotte, NC 28203
TKC.008
Dear Alexis McKenzie:
Enclosed are the analytical results for sample(s) received by the laboratory on June 15, 2023. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace National - Mt. Juliet
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Minneapolis
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor M Cannon
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 75
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92672976
TKC.008
Pace Analytical Services, LLC - Minneapolis MN
1700 Elm Street SE, Minneapolis, MN 55414
A2LA Certification #: 2926.01
Alabama Certification #: 40770
Alaska Contaminated Sites Certification #: 17-009
Alaska DW Certification #: MN00064
Arizona Certification #: AZ0014
Arkansas DW Certification #: MN00064
Arkansas WW Certification #: 88-0680
California Certification #: 2929
Colorado Certification #: MN00064
Connecticut Certification #: PH-0256
EPA Region 8 Tribal Water Systems+Wyoming DW
Certification #: via MN 027-053-137
Florida Certification #: E87605
Georgia Certification #: 959
GMP+ Certification #: GMP050884
Hawaii Certification #: MN00064
Idaho Certification #: MN00064
Illinois Certification #: 200011
Indiana Certification #: C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky DW Certification #: 90062
Kentucky WW Certification #: 90062
Louisiana DEQ Certification #: AI-03086
Louisiana DW Certification #: MN00064
Maine Certification #: MN00064
Maryland Certification #: 322
Michigan Certification #: 9909
Minnesota Certification #: 027-053-137
Minnesota Dept of Ag Approval: via MN 027-053-137
Minnesota Petrofund Registration #: 1240
Mississippi Certification #: MN00064
Missouri Certification #: 10100
Montana Certification #: CERT0092
Nebraska Certification #: NE-OS-18-06
Nevada Certification #: MN00064
New Hampshire Certification #: 2081
New Jersey Certification #: MN002
New York Certification #: 11647
North Carolina DW Certification #: 27700
North Carolina WW Certification #: 530
North Dakota Certification (A2LA) #: R-036
North Dakota Certification (MN) #: R-036
Ohio DW Certification #: 41244
Ohio VAP Certification (1700) #: CL101
Oklahoma Certification #: 9507
Oregon Primary Certification #: MN300001
Oregon Secondary Certification #: MN200001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification #: MN00064
South Carolina Certification #:74003001
Tennessee Certification #: TN02818
Texas Certification #: T104704192
Utah Certification #: MN00064
Vermont Certification #: VT-027053137
Virginia Certification #: 460163
Washington Certification #: C486
West Virginia DEP Certification #: 382
West Virginia DW Certification #: 9952 C
Wisconsin Certification #: 999407970
Wyoming UST Certification #: via A2LA 2926.01
USDA Permit #: P330-19-00208
Pace Analytical Services National
12065 Lebanon Road, Mt. Juliet, TN 37122
Alabama Certification #: 40660
Alaska Certification 17-026
Arizona Certification #: AZ0612
Arkansas Certification #: 88-0469
California Certification #: 2932
Canada Certification #: 1461.01
Colorado Certification #: TN00003
Connecticut Certification #: PH-0197
DOD Certification: #1461.01
EPA# TN00003
Florida Certification #: E87487
Georgia DW Certification #: 923
Georgia Certification: NELAP
Idaho Certification #: TN00003
Illinois Certification #: 200008
Indiana Certification #: C-TN-01
Iowa Certification #: 364
Kansas Certification #: E-10277
Kentucky UST Certification #: 16
Kentucky Certification #: 90010
Louisiana Certification #: AI30792
Louisiana DW Certification #: LA180010
Maine Certification #: TN0002
Maryland Certification #: 324
Massachusetts Certification #: M-TN003
Michigan Certification #: 9958
Minnesota Certification #: 047-999-395
Mississippi Certification #: TN00003
Missouri Certification #: 340
Montana Certification #: CERT0086
Nebraska Certification #: NE-OS-15-05
Nevada Certification #: TN-03-2002-34
New Hampshire Certification #: 2975
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 75
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92672976
TKC.008
Pace Analytical Services National
New Jersey Certification #: TN002
New Mexico DW Certification
New York Certification #: 11742
North Carolina Aquatic Toxicity Certification #: 41
North Carolina Drinking Water Certification #: 21704
North Carolina Environmental Certificate #: 375
North Dakota Certification #: R-140
Ohio VAP Certification #: CL0069
Oklahoma Certification #: 9915
Oregon Certification #: TN200002
Pennsylvania Certification #: 68-02979
Rhode Island Certification #: LAO00356
South Carolina Certification #: 84004
South Dakota Certification
Tennessee DW/Chem/Micro Certification #: 2006
Texas Certification #: T 104704245-17-14
Texas Mold Certification #: LAB0152
USDA Soil Permit #: P330-15-00234
Utah Certification #: TN00003
Vermont Dept. of Health: ID# VT-2006
Virginia Certification #: VT2006
Virginia Certification #: 460132
Washington Certification #: C847
West Virginia Certification #: 233
Wisconsin Certification #: 998093910
Wyoming UST Certification #: via A2LA 2926.01
A2LA-ISO 17025 Certification #: 1461.01
A2LA-ISO 17025 Certification #: 1461.02
AIHA-LAP/LLC EMLAP Certification #:100789
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 75
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92672976
TKC.008
Lab ID Sample ID Matrix Date Collected Date Received
92672976001 FG-1 (0-2)Solid 06/14/23 16:15 06/15/23 14:10
92672976002 FG-2 (0-2)Solid 06/14/23 14:00 06/15/23 14:10
92672976003 FG-3 (0-2)Solid 06/14/23 15:00 06/15/23 14:10
92672976004 FG-4 (0-2)Solid 06/14/23 12:55 06/15/23 14:10
92672976005 FG-5 (0-2)Solid 06/14/23 11:10 06/15/23 14:10
92672976006 FG-DUP (0-2)Solid 06/14/23 00:00 06/15/23 14:10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 75
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92672976
TKC.008
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92672976001 FG-1 (0-2)EPA 6020B 11 PASI-MNN2
EPA 7471B 1 PASI-MDJM
EPA 8270E 75 PASI-CBPJ
EPA 8260D 70 PASI-CLMB
SW-846 1 PASI-CKDF
SM 2540G 1 PANCMK
EPA 7199 1 PANSET
92672976002 FG-2 (0-2)EPA 6020B 11 PASI-MNN2
EPA 7471B 1 PASI-MDJM
EPA 8270E 75 PASI-CBPJ
EPA 8260D 70 PASI-CLMB
SW-846 1 PASI-CKDF
SM 2540G 1 PANCMK
EPA 7199 1 PANSET
92672976003 FG-3 (0-2)EPA 6020B 11 PASI-MNN2
EPA 7471B 1 PASI-MDJM
EPA 8270E 75 PASI-CBPJ
EPA 8260D 70 PASI-CLMB
SW-846 1 PASI-CKDF
SM 2540G 1 PANCMK
EPA 7199 1 PANSET
92672976004 FG-4 (0-2)EPA 6020B 11 PASI-MNN2
EPA 7471B 1 PASI-MDJM
EPA 8270E 75 PASI-CBPJ
EPA 8260D 70 PASI-CLMB
SW-846 1 PASI-CKDF
SM 2540G 1 PANCMK
EPA 7199 1 PANSET
92672976005 FG-5 (0-2)EPA 6020B 11 PASI-MNN2
EPA 7471B 1 PASI-MDJM
EPA 8270E 75 PASI-CBPJ
EPA 8260D 70 PASI-CLMB
SW-846 1 PASI-CKDF
SM 2540G 1 PANCMK
EPA 7199 1 PANSET
92672976006 FG-DUP (0-2)EPA 6020B 11 PASI-MNN2
EPA 7471B 1 PASI-MDJM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 75
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92672976
TKC.008
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 8270E 75 PASI-CBPJ
EPA 8260D 70 PASI-CLMB
SW-846 1 PASI-CKDF
SM 2540G 1 PANCMK
EPA 7199 1 PANSET
PAN = Pace National - Mt. Juliet
PASI-C = Pace Analytical Services - Charlotte
PASI-M = Pace Analytical Services - Minneapolis
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-1 (0-2)Lab ID:92672976001 Collected:06/14/23 16:15 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020B Preparation Method: EPA 3050B
Pace Analytical Services - Minneapolis
6020B MET ICPMS
Arsenic 2.3 mg/kg 06/27/23 15:53 7440-38-206/26/23 05:160.57 0.16 1
Barium 115 mg/kg 06/27/23 15:53 7440-39-306/26/23 05:160.34 0.086 1
Cadmium 0.078J mg/kg 06/27/23 15:53 7440-43-906/26/23 05:160.091 0.034 1
Chromium 94.4 mg/kg 06/27/23 15:53 7440-47-3 P6,R106/26/23 05:162.3 0.44 1
Copper 15.6 mg/kg 06/27/23 15:53 7440-50-806/26/23 05:161.1 0.35 1
Lead 15.0 mg/kg 06/27/23 15:53 7439-92-106/26/23 05:160.57 0.11 1
Nickel 41.0 mg/kg 06/27/23 15:53 7440-02-0 R106/26/23 05:160.57 0.26 1
Selenium 0.62 mg/kg 06/27/23 15:53 7782-49-206/26/23 05:160.57 0.12 1
Silver <0.23 mg/kg 06/27/23 15:53 7440-22-406/26/23 05:160.57 0.23 1
Vanadium 198 mg/kg 06/27/23 15:53 7440-62-2 P606/26/23 05:161.1 0.27 1
Zinc 32.9 mg/kg 06/27/23 15:53 7440-66-606/26/23 05:165.7 1.3 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B
Pace Analytical Services - Minneapolis
7471B Mercury
Mercury 0.031 mg/kg 06/27/23 18:35 7439-97-606/22/23 17:290.023 0.0099 1
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Acenaphthene <141 ug/kg 06/20/23 21:38 83-32-906/19/23 11:314001411
Acenaphthylene <141 ug/kg 06/20/23 21:38 208-96-806/19/23 11:314001411
Aniline <156 ug/kg 06/20/23 21:38 62-53-306/19/23 11:314001561
Anthracene <131 ug/kg 06/20/23 21:38 120-12-706/19/23 11:314001311
Benzo(a)anthracene <133 ug/kg 06/20/23 21:38 56-55-306/19/23 11:314001331
Benzo(a)pyrene <138 ug/kg 06/20/23 21:38 50-32-806/19/23 11:314001381
Benzo(b)fluoranthene <133 ug/kg 06/20/23 21:38 205-99-206/19/23 11:314001331
Benzo(g,h,i)perylene <155 ug/kg 06/20/23 21:38 191-24-206/19/23 11:314001551
Benzo(k)fluoranthene <141 ug/kg 06/20/23 21:38 207-08-906/19/23 11:314001411
Benzoic Acid <859 ug/kg 06/20/23 21:38 65-85-006/19/23 11:3120008591
Benzyl alcohol <303 ug/kg 06/20/23 21:38 100-51-606/19/23 11:317993031
4-Bromophenylphenyl ether <154 ug/kg 06/20/23 21:38 101-55-306/19/23 11:314001541
Butylbenzylphthalate <168 ug/kg 06/20/23 21:38 85-68-706/19/23 11:314001681
4-Chloro-3-methylphenol <281 ug/kg 06/20/23 21:38 59-50-706/19/23 11:317992811
4-Chloroaniline <314 ug/kg 06/20/23 21:38 106-47-806/19/23 11:317993141
bis(2-Chloroethoxy)methane <166 ug/kg 06/20/23 21:38 111-91-106/19/23 11:314001661
bis(2-Chloroethyl) ether <150 ug/kg 06/20/23 21:38 111-44-406/19/23 11:314001501
2-Chloronaphthalene <159 ug/kg 06/20/23 21:38 91-58-706/19/23 11:314001591
2-Chlorophenol <150 ug/kg 06/20/23 21:38 95-57-806/19/23 11:314001501
4-Chlorophenylphenyl ether <149 ug/kg 06/20/23 21:38 7005-72-306/19/23 11:314001491
Chrysene <145 ug/kg 06/20/23 21:38 218-01-906/19/23 11:314001451
Dibenz(a,h)anthracene <154 ug/kg 06/20/23 21:38 53-70-306/19/23 11:314001541
Dibenzofuran <144 ug/kg 06/20/23 21:38 132-64-906/19/23 11:314001441
1,2-Dichlorobenzene <144 ug/kg 06/20/23 21:38 95-50-106/19/23 11:314001441
1,3-Dichlorobenzene <142 ug/kg 06/20/23 21:38 541-73-106/19/23 11:314001421
1,4-Dichlorobenzene <153 ug/kg 06/20/23 21:38 106-46-706/19/23 11:314001531
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-1 (0-2)Lab ID:92672976001 Collected:06/14/23 16:15 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
3,3'-Dichlorobenzidine <270 ug/kg 06/20/23 21:38 91-94-106/19/23 11:317992701
2,4-Dichlorophenol <156 ug/kg 06/20/23 21:38 120-83-206/19/23 11:314001561
Diethylphthalate <147 ug/kg 06/20/23 21:38 84-66-206/19/23 11:314001471
2,4-Dimethylphenol <166 ug/kg 06/20/23 21:38 105-67-906/19/23 11:314001661
Dimethylphthalate <145 ug/kg 06/20/23 21:38 131-11-306/19/23 11:314001451
Di-n-butylphthalate <134 ug/kg 06/20/23 21:38 84-74-206/19/23 11:314001341
4,6-Dinitro-2-methylphenol <373 ug/kg 06/20/23 21:38 534-52-1 v206/19/23 11:317993731
2,4-Dinitrophenol <1240 ug/kg 06/20/23 21:38 51-28-506/19/23 11:31200012401
2,4-Dinitrotoluene <154 ug/kg 06/20/23 21:38 121-14-206/19/23 11:314001541
2,6-Dinitrotoluene <147 ug/kg 06/20/23 21:38 606-20-206/19/23 11:314001471
Di-n-octylphthalate <157 ug/kg 06/20/23 21:38 117-84-006/19/23 11:314001571
bis(2-Ethylhexyl)phthalate <155 ug/kg 06/20/23 21:38 117-81-706/19/23 11:314001551
Fluoranthene <137 ug/kg 06/20/23 21:38 206-44-006/19/23 11:314001371
Fluorene <141 ug/kg 06/20/23 21:38 86-73-706/19/23 11:314001411
Hexachloro-1,3-butadiene <173 ug/kg 06/20/23 21:38 87-68-306/19/23 11:314001731
Hexachlorobenzene <156 ug/kg 06/20/23 21:38 118-74-106/19/23 11:314001561
Hexachlorocyclopentadiene <229 ug/kg 06/20/23 21:38 77-47-4 v206/19/23 11:314002291
Hexachloroethane <153 ug/kg 06/20/23 21:38 67-72-106/19/23 11:314001531
Indeno(1,2,3-cd)pyrene <157 ug/kg 06/20/23 21:38 193-39-506/19/23 11:314001571
Isophorone <178 ug/kg 06/20/23 21:38 78-59-106/19/23 11:314001781
1-Methylnaphthalene <141 ug/kg 06/20/23 21:38 90-12-006/19/23 11:314001411
2-Methylnaphthalene <160 ug/kg 06/20/23 21:38 91-57-606/19/23 11:314001601
2-Methylphenol(o-Cresol)<164 ug/kg 06/20/23 21:38 95-48-706/19/23 11:314001641
3&4-Methylphenol(m&p Cresol)<161 ug/kg 06/20/23 21:38 15831-10-406/19/23 11:314001611
Naphthalene <136 ug/kg 06/20/23 21:38 91-20-306/19/23 11:314001361
2-Nitroaniline <327 ug/kg 06/20/23 21:38 88-74-406/19/23 11:3120003271
3-Nitroaniline <314 ug/kg 06/20/23 21:38 99-09-206/19/23 11:3120003141
4-Nitroaniline <304 ug/kg 06/20/23 21:38 100-01-606/19/23 11:317993041
Nitrobenzene <185 ug/kg 06/20/23 21:38 98-95-306/19/23 11:314001851
2-Nitrophenol <173 ug/kg 06/20/23 21:38 88-75-506/19/23 11:314001731
4-Nitrophenol <773 ug/kg 06/20/23 21:38 100-02-706/19/23 11:3120007731
N-Nitrosodimethylamine <134 ug/kg 06/20/23 21:38 62-75-906/19/23 11:314001341
N-Nitroso-di-n-propylamine <150 ug/kg 06/20/23 21:38 621-64-706/19/23 11:314001501
N-Nitrosodiphenylamine <142 ug/kg 06/20/23 21:38 86-30-606/19/23 11:314001421
2,2'-Oxybis(1-chloropropane)<190 ug/kg 06/20/23 21:38 108-60-106/19/23 11:314001901
Pentachlorophenol <391 ug/kg 06/20/23 21:38 87-86-506/19/23 11:317993911
Phenanthrene <131 ug/kg 06/20/23 21:38 85-01-806/19/23 11:314001311
Phenol <178 ug/kg 06/20/23 21:38 108-95-206/19/23 11:314001781
Pyrene <162 ug/kg 06/20/23 21:38 129-00-006/19/23 11:314001621
Pyridine <126 ug/kg 06/20/23 21:38 110-86-106/19/23 11:314001261
1,2,4-Trichlorobenzene <157 ug/kg 06/20/23 21:38 120-82-106/19/23 11:314001571
2,4,5-Trichlorophenol <183 ug/kg 06/20/23 21:38 95-95-406/19/23 11:314001831
2,4,6-Trichlorophenol <165 ug/kg 06/20/23 21:38 88-06-206/19/23 11:314001651
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-1 (0-2)Lab ID:92672976001 Collected:06/14/23 16:15 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Surrogates
Nitrobenzene-d5 (S)61 %06/20/23 21:38 4165-60-006/19/23 11:3110-130 1
2-Fluorobiphenyl (S)50 %06/20/23 21:38 321-60-806/19/23 11:3110-130 1
Terphenyl-d14 (S)54 %06/20/23 21:38 1718-51-006/19/23 11:3110-130 1
Phenol-d6 (S)64 %06/20/23 21:38 13127-88-306/19/23 11:3110-130 1
2-Fluorophenol (S)62 %06/20/23 21:38 367-12-406/19/23 11:3110-130 1
2,4,6-Tribromophenol (S)64 %06/20/23 21:38 118-79-606/19/23 11:3110-131 1
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone 57.9J ug/kg 06/19/23 16:23 67-64-106/19/23 14:0011536.8 1
Benzene <2.3 ug/kg 06/19/23 16:23 71-43-206/19/23 14:005.7 2.3 1
Bromobenzene <1.9 ug/kg 06/19/23 16:23 108-86-106/19/23 14:005.7 1.9 1
Bromochloromethane <1.7 ug/kg 06/19/23 16:23 74-97-506/19/23 14:005.7 1.7 1
Bromodichloromethane <2.2 ug/kg 06/19/23 16:23 75-27-406/19/23 14:005.7 2.2 1
Bromoform <2.0 ug/kg 06/19/23 16:23 75-25-206/19/23 14:005.7 2.0 1
Bromomethane <17.8 ug/kg 06/19/23 16:23 74-83-906/19/23 14:0022.9 17.8 1
2-Butanone (MEK)<27.5 ug/kg 06/19/23 16:23 78-93-306/19/23 14:0011527.5 1
n-Butylbenzene <3.6 ug/kg 06/19/23 16:23 104-51-806/19/23 14:005.7 3.6 1
sec-Butylbenzene <2.5 ug/kg 06/19/23 16:23 135-98-806/19/23 14:005.7 2.5 1
tert-Butylbenzene <2.0 ug/kg 06/19/23 16:23 98-06-606/19/23 14:005.7 2.0 1
Carbon tetrachloride <2.1 ug/kg 06/19/23 16:23 56-23-506/19/23 14:005.7 2.1 1
Chlorobenzene <3.3 ug/kg 06/19/23 16:23 108-90-706/19/23 14:005.7 3.3 1
Chloroethane <4.4 ug/kg 06/19/23 16:23 75-00-3 v106/19/23 14:0011.5 4.4 1
Chloroform <4.8 ug/kg 06/19/23 16:23 67-66-306/19/23 14:005.7 4.8 1
Chloromethane <4.8 ug/kg 06/19/23 16:23 74-87-3 v106/19/23 14:0011.5 4.8 1
2-Chlorotoluene <2.0 ug/kg 06/19/23 16:23 95-49-806/19/23 14:005.7 2.0 1
4-Chlorotoluene <3.2 ug/kg 06/19/23 16:23 106-43-406/19/23 14:005.7 3.2 1
1,2-Dibromo-3-chloropropane <2.2 ug/kg 06/19/23 16:23 96-12-806/19/23 14:005.7 2.2 1
Dibromochloromethane <3.2 ug/kg 06/19/23 16:23 124-48-106/19/23 14:005.7 3.2 1
1,2-Dibromoethane (EDB)<2.5 ug/kg 06/19/23 16:23 106-93-406/19/23 14:005.7 2.5 1
Dibromomethane <1.2 ug/kg 06/19/23 16:23 74-95-306/19/23 14:005.7 1.2 1
1,2-Dichlorobenzene <2.1 ug/kg 06/19/23 16:23 95-50-106/19/23 14:005.7 2.1 1
1,3-Dichlorobenzene <1.8 ug/kg 06/19/23 16:23 541-73-106/19/23 14:005.7 1.8 1
1,4-Dichlorobenzene <1.5 ug/kg 06/19/23 16:23 106-46-706/19/23 14:005.7 1.5 1
Dichlorodifluoromethane <5.8 ug/kg 06/19/23 16:23 75-71-806/19/23 14:0011.5 5.8 1
1,1-Dichloroethane <2.4 ug/kg 06/19/23 16:23 75-34-306/19/23 14:005.7 2.4 1
1,2-Dichloroethane <3.8 ug/kg 06/19/23 16:23 107-06-206/19/23 14:005.7 3.8 1
1,1-Dichloroethene <2.4 ug/kg 06/19/23 16:23 75-35-406/19/23 14:005.7 2.4 1
cis-1,2-Dichloroethene <2.0 ug/kg 06/19/23 16:23 156-59-206/19/23 14:005.7 2.0 1
trans-1,2-Dichloroethene <4.9 ug/kg 06/19/23 16:23 156-60-506/19/23 14:005.7 4.9 1
1,2-Dichloropropane <1.7 ug/kg 06/19/23 16:23 78-87-506/19/23 14:005.7 1.7 1
1,3-Dichloropropane <1.8 ug/kg 06/19/23 16:23 142-28-906/19/23 14:005.7 1.8 1
2,2-Dichloropropane <4.3 ug/kg 06/19/23 16:23 594-20-706/19/23 14:005.7 4.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-1 (0-2)Lab ID:92672976001 Collected:06/14/23 16:15 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
1,1-Dichloropropene <2.8 ug/kg 06/19/23 16:23 563-58-606/19/23 14:005.7 2.8 1
cis-1,3-Dichloropropene <1.6 ug/kg 06/19/23 16:23 10061-01-506/19/23 14:005.7 1.6 1
trans-1,3-Dichloropropene <2.0 ug/kg 06/19/23 16:23 10061-02-606/19/23 14:005.7 2.0 1
Diisopropyl ether <1.5 ug/kg 06/19/23 16:23 108-20-306/19/23 14:005.7 1.5 1
Ethylbenzene <2.7 ug/kg 06/19/23 16:23 100-41-406/19/23 14:005.7 2.7 1
Hexachloro-1,3-butadiene <9.4 ug/kg 06/19/23 16:23 87-68-306/19/23 14:0011.5 9.4 1
2-Hexanone <5.5 ug/kg 06/19/23 16:23 591-78-606/19/23 14:0057.3 5.5 1
Isopropylbenzene (Cumene)<1.9 ug/kg 06/19/23 16:23 98-82-806/19/23 14:005.7 1.9 1
p-Isopropyltoluene <2.8 ug/kg 06/19/23 16:23 99-87-606/19/23 14:005.7 2.8 1
Methylene Chloride <15.7 ug/kg 06/19/23 16:23 75-09-206/19/23 14:0022.9 15.7 1
4-Methyl-2-pentanone (MIBK)<5.5 ug/kg 06/19/23 16:23 108-10-106/19/23 14:0057.3 5.5 1
Methyl-tert-butyl ether <2.1 ug/kg 06/19/23 16:23 1634-04-406/19/23 14:005.7 2.1 1
Naphthalene <3.0 ug/kg 06/19/23 16:23 91-20-306/19/23 14:005.7 3.0 1
n-Propylbenzene <2.0 ug/kg 06/19/23 16:23 103-65-106/19/23 14:005.7 2.0 1
Styrene <1.5 ug/kg 06/19/23 16:23 100-42-506/19/23 14:005.7 1.5 1
1,1,1,2-Tetrachloroethane <2.2 ug/kg 06/19/23 16:23 630-20-606/19/23 14:005.7 2.2 1
1,1,2,2-Tetrachloroethane <1.5 ug/kg 06/19/23 16:23 79-34-506/19/23 14:005.7 1.5 1
Tetrachloroethene <1.8 ug/kg 06/19/23 16:23 127-18-406/19/23 14:005.7 1.8 1
Toluene <4.0 ug/kg 06/19/23 16:23 108-88-306/19/23 14:005.7 4.0 1
1,2,3-Trichlorobenzene <4.6 ug/kg 06/19/23 16:23 87-61-606/19/23 14:005.7 4.6 1
1,2,4-Trichlorobenzene <4.8 ug/kg 06/19/23 16:23 120-82-106/19/23 14:005.7 4.8 1
1,1,1-Trichloroethane <3.0 ug/kg 06/19/23 16:23 71-55-606/19/23 14:005.7 3.0 1
1,1,2-Trichloroethane <1.9 ug/kg 06/19/23 16:23 79-00-506/19/23 14:005.7 1.9 1
Trichloroethene <4.6 ug/kg 06/19/23 16:23 79-01-606/19/23 14:005.7 4.6 1
Trichlorofluoromethane <3.2 ug/kg 06/19/23 16:23 75-69-406/19/23 14:005.7 3.2 1
1,2,3-Trichloropropane <2.9 ug/kg 06/19/23 16:23 96-18-406/19/23 14:005.7 2.9 1
1,2,4-Trimethylbenzene <3.4 ug/kg 06/19/23 16:23 95-63-606/19/23 14:005.7 3.4 1
1,3,5-Trimethylbenzene <1.9 ug/kg 06/19/23 16:23 108-67-806/19/23 14:005.7 1.9 1
Vinyl acetate <11.8 ug/kg 06/19/23 16:23 108-05-406/19/23 14:0057.3 11.8 1
Vinyl chloride <2.9 ug/kg 06/19/23 16:23 75-01-4 v106/19/23 14:0011.5 2.9 1
Xylene (Total)<3.3 ug/kg 06/19/23 16:23 1330-20-706/19/23 14:0011.5 3.3 1
m&p-Xylene <3.9 ug/kg 06/19/23 16:23 179601-23-106/19/23 14:0011.5 3.9 1
o-Xylene <2.5 ug/kg 06/19/23 16:23 95-47-606/19/23 14:005.7 2.5 1
Surrogates
Toluene-d8 (S)103 %06/19/23 16:23 2037-26-506/19/23 14:0070-130 1
4-Bromofluorobenzene (S)106 %06/19/23 16:23 460-00-406/19/23 14:0070-130 1
1,2-Dichloroethane-d4 (S)110 %06/19/23 16:23 17060-07-006/19/23 14:0070-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 16.9 %06/16/23 15:01 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-1 (0-2)Lab ID:92672976001 Collected:06/14/23 16:15 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 2540G Preparation Method: SM 2540 G
Pace National - Mt. Juliet
Total Solids 2540 G-2011
Total Solids 74.9 %06/21/23 12:0506/21/23 11:391
Analytical Method: EPA 7199 Preparation Method: 3060A
Pace National - Mt. Juliet
Wet Chemistry 7199
Chromium, Hexavalent 0.663J mg/kg 06/22/23 12:32 18540-29-9 J06/21/23 05:231.34 0.340 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-2 (0-2)Lab ID:92672976002 Collected:06/14/23 14:00 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020B Preparation Method: EPA 3050B
Pace Analytical Services - Minneapolis
6020B MET ICPMS
Arsenic 1.2 mg/kg 06/27/23 16:09 7440-38-206/26/23 05:160.61 0.17 1
Barium 105 mg/kg 06/27/23 16:09 7440-39-306/26/23 05:160.37 0.091 1
Cadmium 0.040J mg/kg 06/27/23 16:09 7440-43-906/26/23 05:160.098 0.036 1
Chromium 18.7 mg/kg 06/27/23 16:09 7440-47-306/26/23 05:162.4 0.47 1
Copper 20.5 mg/kg 06/27/23 16:09 7440-50-806/26/23 05:161.2 0.37 1
Lead 2.8 mg/kg 06/27/23 16:09 7439-92-106/26/23 05:160.61 0.11 1
Nickel 17.4 mg/kg 06/27/23 16:09 7440-02-006/26/23 05:160.61 0.28 1
Selenium 0.36J mg/kg 06/27/23 16:09 7782-49-206/26/23 05:160.61 0.13 1
Silver <0.25 mg/kg 06/27/23 16:09 7440-22-406/26/23 05:160.61 0.25 1
Vanadium 93.3 mg/kg 06/27/23 16:09 7440-62-206/26/23 05:161.2 0.29 1
Zinc 40.6 mg/kg 06/27/23 16:09 7440-66-606/26/23 05:166.1 1.4 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B
Pace Analytical Services - Minneapolis
7471B Mercury
Mercury <0.010 mg/kg 06/27/23 18:42 7439-97-606/22/23 17:290.023 0.010 1
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Acenaphthene <143 ug/kg 06/20/23 22:06 83-32-906/19/23 11:314071431
Acenaphthylene <143 ug/kg 06/20/23 22:06 208-96-806/19/23 11:314071431
Aniline <159 ug/kg 06/20/23 22:06 62-53-306/19/23 11:314071591
Anthracene <133 ug/kg 06/20/23 22:06 120-12-706/19/23 11:314071331
Benzo(a)anthracene <136 ug/kg 06/20/23 22:06 56-55-306/19/23 11:314071361
Benzo(a)pyrene <141 ug/kg 06/20/23 22:06 50-32-806/19/23 11:314071411
Benzo(b)fluoranthene <136 ug/kg 06/20/23 22:06 205-99-206/19/23 11:314071361
Benzo(g,h,i)perylene <158 ug/kg 06/20/23 22:06 191-24-206/19/23 11:314071581
Benzo(k)fluoranthene <143 ug/kg 06/20/23 22:06 207-08-906/19/23 11:314071431
Benzoic Acid <874 ug/kg 06/20/23 22:06 65-85-006/19/23 11:3120408741
Benzyl alcohol <308 ug/kg 06/20/23 22:06 100-51-606/19/23 11:318143081
4-Bromophenylphenyl ether <157 ug/kg 06/20/23 22:06 101-55-306/19/23 11:314071571
Butylbenzylphthalate <171 ug/kg 06/20/23 22:06 85-68-706/19/23 11:314071711
4-Chloro-3-methylphenol <286 ug/kg 06/20/23 22:06 59-50-706/19/23 11:318142861
4-Chloroaniline <319 ug/kg 06/20/23 22:06 106-47-806/19/23 11:318143191
bis(2-Chloroethoxy)methane <169 ug/kg 06/20/23 22:06 111-91-106/19/23 11:314071691
bis(2-Chloroethyl) ether <153 ug/kg 06/20/23 22:06 111-44-406/19/23 11:314071531
2-Chloronaphthalene <162 ug/kg 06/20/23 22:06 91-58-706/19/23 11:314071621
2-Chlorophenol <153 ug/kg 06/20/23 22:06 95-57-806/19/23 11:314071531
4-Chlorophenylphenyl ether <152 ug/kg 06/20/23 22:06 7005-72-306/19/23 11:314071521
Chrysene <148 ug/kg 06/20/23 22:06 218-01-906/19/23 11:314071481
Dibenz(a,h)anthracene <157 ug/kg 06/20/23 22:06 53-70-306/19/23 11:314071571
Dibenzofuran <147 ug/kg 06/20/23 22:06 132-64-906/19/23 11:314071471
1,2-Dichlorobenzene <147 ug/kg 06/20/23 22:06 95-50-106/19/23 11:314071471
1,3-Dichlorobenzene <144 ug/kg 06/20/23 22:06 541-73-106/19/23 11:314071441
1,4-Dichlorobenzene <155 ug/kg 06/20/23 22:06 106-46-706/19/23 11:314071551
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-2 (0-2)Lab ID:92672976002 Collected:06/14/23 14:00 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
3,3'-Dichlorobenzidine <275 ug/kg 06/20/23 22:06 91-94-106/19/23 11:318142751
2,4-Dichlorophenol <159 ug/kg 06/20/23 22:06 120-83-206/19/23 11:314071591
Diethylphthalate <149 ug/kg 06/20/23 22:06 84-66-206/19/23 11:314071491
2,4-Dimethylphenol <169 ug/kg 06/20/23 22:06 105-67-906/19/23 11:314071691
Dimethylphthalate <148 ug/kg 06/20/23 22:06 131-11-306/19/23 11:314071481
Di-n-butylphthalate <137 ug/kg 06/20/23 22:06 84-74-206/19/23 11:314071371
4,6-Dinitro-2-methylphenol <380 ug/kg 06/20/23 22:06 534-52-1 v206/19/23 11:318143801
2,4-Dinitrophenol <1260 ug/kg 06/20/23 22:06 51-28-506/19/23 11:31204012601
2,4-Dinitrotoluene <157 ug/kg 06/20/23 22:06 121-14-206/19/23 11:314071571
2,6-Dinitrotoluene <149 ug/kg 06/20/23 22:06 606-20-206/19/23 11:314071491
Di-n-octylphthalate <160 ug/kg 06/20/23 22:06 117-84-006/19/23 11:314071601
bis(2-Ethylhexyl)phthalate <158 ug/kg 06/20/23 22:06 117-81-706/19/23 11:314071581
Fluoranthene <139 ug/kg 06/20/23 22:06 206-44-006/19/23 11:314071391
Fluorene <143 ug/kg 06/20/23 22:06 86-73-706/19/23 11:314071431
Hexachloro-1,3-butadiene <176 ug/kg 06/20/23 22:06 87-68-306/19/23 11:314071761
Hexachlorobenzene <159 ug/kg 06/20/23 22:06 118-74-106/19/23 11:314071591
Hexachlorocyclopentadiene <233 ug/kg 06/20/23 22:06 77-47-4 v206/19/23 11:314072331
Hexachloroethane <155 ug/kg 06/20/23 22:06 67-72-106/19/23 11:314071551
Indeno(1,2,3-cd)pyrene <160 ug/kg 06/20/23 22:06 193-39-506/19/23 11:314071601
Isophorone <181 ug/kg 06/20/23 22:06 78-59-106/19/23 11:314071811
1-Methylnaphthalene <143 ug/kg 06/20/23 22:06 90-12-006/19/23 11:314071431
2-Methylnaphthalene <163 ug/kg 06/20/23 22:06 91-57-606/19/23 11:314071631
2-Methylphenol(o-Cresol)<167 ug/kg 06/20/23 22:06 95-48-706/19/23 11:314071671
3&4-Methylphenol(m&p Cresol)<164 ug/kg 06/20/23 22:06 15831-10-406/19/23 11:314071641
Naphthalene <138 ug/kg 06/20/23 22:06 91-20-306/19/23 11:314071381
2-Nitroaniline <333 ug/kg 06/20/23 22:06 88-74-406/19/23 11:3120403331
3-Nitroaniline <319 ug/kg 06/20/23 22:06 99-09-206/19/23 11:3120403191
4-Nitroaniline <310 ug/kg 06/20/23 22:06 100-01-606/19/23 11:318143101
Nitrobenzene <189 ug/kg 06/20/23 22:06 98-95-306/19/23 11:314071891
2-Nitrophenol <176 ug/kg 06/20/23 22:06 88-75-506/19/23 11:314071761
4-Nitrophenol <787 ug/kg 06/20/23 22:06 100-02-706/19/23 11:3120407871
N-Nitrosodimethylamine <137 ug/kg 06/20/23 22:06 62-75-906/19/23 11:314071371
N-Nitroso-di-n-propylamine <153 ug/kg 06/20/23 22:06 621-64-706/19/23 11:314071531
N-Nitrosodiphenylamine <144 ug/kg 06/20/23 22:06 86-30-606/19/23 11:314071441
2,2'-Oxybis(1-chloropropane)<194 ug/kg 06/20/23 22:06 108-60-106/19/23 11:314071941
Pentachlorophenol <398 ug/kg 06/20/23 22:06 87-86-506/19/23 11:318143981
Phenanthrene <133 ug/kg 06/20/23 22:06 85-01-806/19/23 11:314071331
Phenol <181 ug/kg 06/20/23 22:06 108-95-206/19/23 11:314071811
Pyrene <165 ug/kg 06/20/23 22:06 129-00-006/19/23 11:314071651
Pyridine <128 ug/kg 06/20/23 22:06 110-86-106/19/23 11:314071281
1,2,4-Trichlorobenzene <160 ug/kg 06/20/23 22:06 120-82-106/19/23 11:314071601
2,4,5-Trichlorophenol <186 ug/kg 06/20/23 22:06 95-95-406/19/23 11:314071861
2,4,6-Trichlorophenol <168 ug/kg 06/20/23 22:06 88-06-206/19/23 11:314071681
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-2 (0-2)Lab ID:92672976002 Collected:06/14/23 14:00 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Surrogates
Nitrobenzene-d5 (S)50 %06/20/23 22:06 4165-60-006/19/23 11:3110-130 1
2-Fluorobiphenyl (S)52 %06/20/23 22:06 321-60-806/19/23 11:3110-130 1
Terphenyl-d14 (S)83 %06/20/23 22:06 1718-51-006/19/23 11:3110-130 1
Phenol-d6 (S)48 %06/20/23 22:06 13127-88-306/19/23 11:3110-130 1
2-Fluorophenol (S)46 %06/20/23 22:06 367-12-406/19/23 11:3110-130 1
2,4,6-Tribromophenol (S)63 %06/20/23 22:06 118-79-606/19/23 11:3110-131 1
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone <42.0 ug/kg 06/19/23 16:41 67-64-106/19/23 14:0013142.0 1
Benzene <2.6 ug/kg 06/19/23 16:41 71-43-206/19/23 14:006.5 2.6 1
Bromobenzene <2.1 ug/kg 06/19/23 16:41 108-86-106/19/23 14:006.5 2.1 1
Bromochloromethane <1.9 ug/kg 06/19/23 16:41 74-97-506/19/23 14:006.5 1.9 1
Bromodichloromethane <2.5 ug/kg 06/19/23 16:41 75-27-406/19/23 14:006.5 2.5 1
Bromoform <2.3 ug/kg 06/19/23 16:41 75-25-206/19/23 14:006.5 2.3 1
Bromomethane <20.3 ug/kg 06/19/23 16:41 74-83-906/19/23 14:0026.2 20.3 1
2-Butanone (MEK)<31.4 ug/kg 06/19/23 16:41 78-93-306/19/23 14:0013131.4 1
n-Butylbenzene <4.1 ug/kg 06/19/23 16:41 104-51-806/19/23 14:006.5 4.1 1
sec-Butylbenzene <2.9 ug/kg 06/19/23 16:41 135-98-806/19/23 14:006.5 2.9 1
tert-Butylbenzene <2.3 ug/kg 06/19/23 16:41 98-06-606/19/23 14:006.5 2.3 1
Carbon tetrachloride <2.4 ug/kg 06/19/23 16:41 56-23-506/19/23 14:006.5 2.4 1
Chlorobenzene <3.8 ug/kg 06/19/23 16:41 108-90-706/19/23 14:006.5 3.8 1
Chloroethane <5.1 ug/kg 06/19/23 16:41 75-00-3 v106/19/23 14:0013.1 5.1 1
Chloroform <5.5 ug/kg 06/19/23 16:41 67-66-306/19/23 14:006.5 5.5 1
Chloromethane <5.5 ug/kg 06/19/23 16:41 74-87-3 v106/19/23 14:0013.1 5.5 1
2-Chlorotoluene <2.3 ug/kg 06/19/23 16:41 95-49-806/19/23 14:006.5 2.3 1
4-Chlorotoluene <3.6 ug/kg 06/19/23 16:41 106-43-406/19/23 14:006.5 3.6 1
1,2-Dibromo-3-chloropropane <2.5 ug/kg 06/19/23 16:41 96-12-806/19/23 14:006.5 2.5 1
Dibromochloromethane <3.7 ug/kg 06/19/23 16:41 124-48-106/19/23 14:006.5 3.7 1
1,2-Dibromoethane (EDB)<2.9 ug/kg 06/19/23 16:41 106-93-406/19/23 14:006.5 2.9 1
Dibromomethane <1.4 ug/kg 06/19/23 16:41 74-95-306/19/23 14:006.5 1.4 1
1,2-Dichlorobenzene <2.4 ug/kg 06/19/23 16:41 95-50-106/19/23 14:006.5 2.4 1
1,3-Dichlorobenzene <2.0 ug/kg 06/19/23 16:41 541-73-106/19/23 14:006.5 2.0 1
1,4-Dichlorobenzene <1.7 ug/kg 06/19/23 16:41 106-46-706/19/23 14:006.5 1.7 1
Dichlorodifluoromethane <6.7 ug/kg 06/19/23 16:41 75-71-806/19/23 14:0013.1 6.7 1
1,1-Dichloroethane <2.7 ug/kg 06/19/23 16:41 75-34-306/19/23 14:006.5 2.7 1
1,2-Dichloroethane <4.3 ug/kg 06/19/23 16:41 107-06-206/19/23 14:006.5 4.3 1
1,1-Dichloroethene <2.7 ug/kg 06/19/23 16:41 75-35-406/19/23 14:006.5 2.7 1
cis-1,2-Dichloroethene <2.2 ug/kg 06/19/23 16:41 156-59-206/19/23 14:006.5 2.2 1
trans-1,2-Dichloroethene <5.6 ug/kg 06/19/23 16:41 156-60-506/19/23 14:006.5 5.6 1
1,2-Dichloropropane <2.0 ug/kg 06/19/23 16:41 78-87-506/19/23 14:006.5 2.0 1
1,3-Dichloropropane <2.0 ug/kg 06/19/23 16:41 142-28-906/19/23 14:006.5 2.0 1
2,2-Dichloropropane <5.0 ug/kg 06/19/23 16:41 594-20-706/19/23 14:006.5 5.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-2 (0-2)Lab ID:92672976002 Collected:06/14/23 14:00 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
1,1-Dichloropropene <3.1 ug/kg 06/19/23 16:41 563-58-606/19/23 14:006.5 3.1 1
cis-1,3-Dichloropropene <1.8 ug/kg 06/19/23 16:41 10061-01-506/19/23 14:006.5 1.8 1
trans-1,3-Dichloropropene <2.3 ug/kg 06/19/23 16:41 10061-02-606/19/23 14:006.5 2.3 1
Diisopropyl ether <1.8 ug/kg 06/19/23 16:41 108-20-306/19/23 14:006.5 1.8 1
Ethylbenzene <3.1 ug/kg 06/19/23 16:41 100-41-406/19/23 14:006.5 3.1 1
Hexachloro-1,3-butadiene <10.7 ug/kg 06/19/23 16:41 87-68-306/19/23 14:0013.1 10.7 1
2-Hexanone <6.3 ug/kg 06/19/23 16:41 591-78-606/19/23 14:0065.5 6.3 1
Isopropylbenzene (Cumene)<2.2 ug/kg 06/19/23 16:41 98-82-806/19/23 14:006.5 2.2 1
p-Isopropyltoluene <3.2 ug/kg 06/19/23 16:41 99-87-606/19/23 14:006.5 3.2 1
Methylene Chloride <17.9 ug/kg 06/19/23 16:41 75-09-206/19/23 14:0026.2 17.9 1
4-Methyl-2-pentanone (MIBK)<6.3 ug/kg 06/19/23 16:41 108-10-106/19/23 14:0065.5 6.3 1
Methyl-tert-butyl ether <2.4 ug/kg 06/19/23 16:41 1634-04-406/19/23 14:006.5 2.4 1
Naphthalene <3.4 ug/kg 06/19/23 16:41 91-20-306/19/23 14:006.5 3.4 1
n-Propylbenzene <2.3 ug/kg 06/19/23 16:41 103-65-106/19/23 14:006.5 2.3 1
Styrene <1.7 ug/kg 06/19/23 16:41 100-42-506/19/23 14:006.5 1.7 1
1,1,1,2-Tetrachloroethane <2.5 ug/kg 06/19/23 16:41 630-20-606/19/23 14:006.5 2.5 1
1,1,2,2-Tetrachloroethane <1.7 ug/kg 06/19/23 16:41 79-34-506/19/23 14:006.5 1.7 1
Tetrachloroethene <2.1 ug/kg 06/19/23 16:41 127-18-406/19/23 14:006.5 2.1 1
Toluene <4.5 ug/kg 06/19/23 16:41 108-88-306/19/23 14:006.5 4.5 1
1,2,3-Trichlorobenzene <5.3 ug/kg 06/19/23 16:41 87-61-606/19/23 14:006.5 5.3 1
1,2,4-Trichlorobenzene <5.5 ug/kg 06/19/23 16:41 120-82-106/19/23 14:006.5 5.5 1
1,1,1-Trichloroethane <3.4 ug/kg 06/19/23 16:41 71-55-606/19/23 14:006.5 3.4 1
1,1,2-Trichloroethane <2.2 ug/kg 06/19/23 16:41 79-00-506/19/23 14:006.5 2.2 1
Trichloroethene <5.3 ug/kg 06/19/23 16:41 79-01-606/19/23 14:006.5 5.3 1
Trichlorofluoromethane <3.6 ug/kg 06/19/23 16:41 75-69-406/19/23 14:006.5 3.6 1
1,2,3-Trichloropropane <3.3 ug/kg 06/19/23 16:41 96-18-406/19/23 14:006.5 3.3 1
1,2,4-Trimethylbenzene <3.9 ug/kg 06/19/23 16:41 95-63-606/19/23 14:006.5 3.9 1
1,3,5-Trimethylbenzene <2.2 ug/kg 06/19/23 16:41 108-67-806/19/23 14:006.5 2.2 1
Vinyl acetate <13.5 ug/kg 06/19/23 16:41 108-05-406/19/23 14:0065.5 13.5 1
Vinyl chloride <3.3 ug/kg 06/19/23 16:41 75-01-4 v106/19/23 14:0013.1 3.3 1
Xylene (Total)<3.7 ug/kg 06/19/23 16:41 1330-20-706/19/23 14:0013.1 3.7 1
m&p-Xylene <4.5 ug/kg 06/19/23 16:41 179601-23-106/19/23 14:0013.1 4.5 1
o-Xylene <2.9 ug/kg 06/19/23 16:41 95-47-606/19/23 14:006.5 2.9 1
Surrogates
Toluene-d8 (S)103 %06/19/23 16:41 2037-26-506/19/23 14:0070-130 1
4-Bromofluorobenzene (S)106 %06/19/23 16:41 460-00-406/19/23 14:0070-130 1
1,2-Dichloroethane-d4 (S)108 %06/19/23 16:41 17060-07-006/19/23 14:0070-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 18.6 %06/16/23 15:02 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-2 (0-2)Lab ID:92672976002 Collected:06/14/23 14:00 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 2540G Preparation Method: SM 2540 G
Pace National - Mt. Juliet
Total Solids 2540 G-2011
Total Solids 76.1 %06/21/23 12:0506/21/23 11:391
Analytical Method: EPA 7199 Preparation Method: 3060A
Pace National - Mt. Juliet
Wet Chemistry 7199
Chromium, Hexavalent 0.939J mg/kg 06/22/23 12:37 18540-29-9 J06/21/23 05:231.31 0.335 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-3 (0-2)Lab ID:92672976003 Collected:06/14/23 15:00 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020B Preparation Method: EPA 3050B
Pace Analytical Services - Minneapolis
6020B MET ICPMS
Arsenic 2.5 mg/kg 06/27/23 16:13 7440-38-206/26/23 05:160.54 0.16 1
Barium 103 mg/kg 06/27/23 16:13 7440-39-306/26/23 05:160.33 0.081 1
Cadmium 0.061J mg/kg 06/27/23 16:13 7440-43-906/26/23 05:160.087 0.032 1
Chromium 51.9 mg/kg 06/27/23 16:13 7440-47-306/26/23 05:162.2 0.42 1
Copper 21.8 mg/kg 06/27/23 16:13 7440-50-806/26/23 05:161.1 0.33 1
Lead 11.4 mg/kg 06/27/23 16:13 7439-92-106/26/23 05:160.54 0.10 1
Nickel 26.5 mg/kg 06/27/23 16:13 7440-02-006/26/23 05:160.54 0.25 1
Selenium 0.55 mg/kg 06/27/23 16:13 7782-49-206/26/23 05:160.54 0.11 1
Silver <0.22 mg/kg 06/27/23 16:13 7440-22-406/26/23 05:160.54 0.22 1
Vanadium 209 mg/kg 06/27/23 16:13 7440-62-206/26/23 05:161.1 0.26 1
Zinc 31.1 mg/kg 06/27/23 16:13 7440-66-606/26/23 05:165.4 1.3 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B
Pace Analytical Services - Minneapolis
7471B Mercury
Mercury 0.025 mg/kg 06/27/23 18:44 7439-97-606/22/23 17:290.020 0.0088 1
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Acenaphthene <138 ug/kg 06/20/23 22:34 83-32-906/19/23 11:313911381
Acenaphthylene <138 ug/kg 06/20/23 22:34 208-96-806/19/23 11:313911381
Aniline <153 ug/kg 06/20/23 22:34 62-53-306/19/23 11:313911531
Anthracene <128 ug/kg 06/20/23 22:34 120-12-706/19/23 11:313911281
Benzo(a)anthracene <130 ug/kg 06/20/23 22:34 56-55-306/19/23 11:313911301
Benzo(a)pyrene <135 ug/kg 06/20/23 22:34 50-32-806/19/23 11:313911351
Benzo(b)fluoranthene <130 ug/kg 06/20/23 22:34 205-99-206/19/23 11:313911301
Benzo(g,h,i)perylene <152 ug/kg 06/20/23 22:34 191-24-206/19/23 11:313911521
Benzo(k)fluoranthene <138 ug/kg 06/20/23 22:34 207-08-906/19/23 11:313911381
Benzoic Acid <841 ug/kg 06/20/23 22:34 65-85-006/19/23 11:3119608411
Benzyl alcohol <296 ug/kg 06/20/23 22:34 100-51-606/19/23 11:317822961
4-Bromophenylphenyl ether <151 ug/kg 06/20/23 22:34 101-55-306/19/23 11:313911511
Butylbenzylphthalate <165 ug/kg 06/20/23 22:34 85-68-706/19/23 11:313911651
4-Chloro-3-methylphenol <275 ug/kg 06/20/23 22:34 59-50-706/19/23 11:317822751
4-Chloroaniline <307 ug/kg 06/20/23 22:34 106-47-806/19/23 11:317823071
bis(2-Chloroethoxy)methane <162 ug/kg 06/20/23 22:34 111-91-106/19/23 11:313911621
bis(2-Chloroethyl) ether <147 ug/kg 06/20/23 22:34 111-44-406/19/23 11:313911471
2-Chloronaphthalene <155 ug/kg 06/20/23 22:34 91-58-706/19/23 11:313911551
2-Chlorophenol <147 ug/kg 06/20/23 22:34 95-57-806/19/23 11:313911471
4-Chlorophenylphenyl ether <146 ug/kg 06/20/23 22:34 7005-72-306/19/23 11:313911461
Chrysene <142 ug/kg 06/20/23 22:34 218-01-906/19/23 11:313911421
Dibenz(a,h)anthracene <151 ug/kg 06/20/23 22:34 53-70-306/19/23 11:313911511
Dibenzofuran <141 ug/kg 06/20/23 22:34 132-64-906/19/23 11:313911411
1,2-Dichlorobenzene <141 ug/kg 06/20/23 22:34 95-50-106/19/23 11:313911411
1,3-Dichlorobenzene <139 ug/kg 06/20/23 22:34 541-73-106/19/23 11:313911391
1,4-Dichlorobenzene <149 ug/kg 06/20/23 22:34 106-46-706/19/23 11:313911491
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-3 (0-2)Lab ID:92672976003 Collected:06/14/23 15:00 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
3,3'-Dichlorobenzidine <264 ug/kg 06/20/23 22:34 91-94-106/19/23 11:317822641
2,4-Dichlorophenol <153 ug/kg 06/20/23 22:34 120-83-206/19/23 11:313911531
Diethylphthalate <143 ug/kg 06/20/23 22:34 84-66-206/19/23 11:313911431
2,4-Dimethylphenol <162 ug/kg 06/20/23 22:34 105-67-906/19/23 11:313911621
Dimethylphthalate <142 ug/kg 06/20/23 22:34 131-11-306/19/23 11:313911421
Di-n-butylphthalate <132 ug/kg 06/20/23 22:34 84-74-206/19/23 11:313911321
4,6-Dinitro-2-methylphenol <365 ug/kg 06/20/23 22:34 534-52-1 v206/19/23 11:317823651
2,4-Dinitrophenol <1210 ug/kg 06/20/23 22:34 51-28-506/19/23 11:31196012101
2,4-Dinitrotoluene <151 ug/kg 06/20/23 22:34 121-14-206/19/23 11:313911511
2,6-Dinitrotoluene <143 ug/kg 06/20/23 22:34 606-20-206/19/23 11:313911431
Di-n-octylphthalate <154 ug/kg 06/20/23 22:34 117-84-006/19/23 11:313911541
bis(2-Ethylhexyl)phthalate <152 ug/kg 06/20/23 22:34 117-81-706/19/23 11:313911521
Fluoranthene <134 ug/kg 06/20/23 22:34 206-44-006/19/23 11:313911341
Fluorene <138 ug/kg 06/20/23 22:34 86-73-706/19/23 11:313911381
Hexachloro-1,3-butadiene <170 ug/kg 06/20/23 22:34 87-68-306/19/23 11:313911701
Hexachlorobenzene <153 ug/kg 06/20/23 22:34 118-74-106/19/23 11:313911531
Hexachlorocyclopentadiene <224 ug/kg 06/20/23 22:34 77-47-4 v206/19/23 11:313912241
Hexachloroethane <149 ug/kg 06/20/23 22:34 67-72-106/19/23 11:313911491
Indeno(1,2,3-cd)pyrene <154 ug/kg 06/20/23 22:34 193-39-506/19/23 11:313911541
Isophorone <174 ug/kg 06/20/23 22:34 78-59-106/19/23 11:313911741
1-Methylnaphthalene <138 ug/kg 06/20/23 22:34 90-12-006/19/23 11:313911381
2-Methylnaphthalene <156 ug/kg 06/20/23 22:34 91-57-606/19/23 11:313911561
2-Methylphenol(o-Cresol)<160 ug/kg 06/20/23 22:34 95-48-706/19/23 11:313911601
3&4-Methylphenol(m&p Cresol)<158 ug/kg 06/20/23 22:34 15831-10-406/19/23 11:313911581
Naphthalene <133 ug/kg 06/20/23 22:34 91-20-306/19/23 11:313911331
2-Nitroaniline <320 ug/kg 06/20/23 22:34 88-74-406/19/23 11:3119603201
3-Nitroaniline <307 ug/kg 06/20/23 22:34 99-09-206/19/23 11:3119603071
4-Nitroaniline <298 ug/kg 06/20/23 22:34 100-01-606/19/23 11:317822981
Nitrobenzene <181 ug/kg 06/20/23 22:34 98-95-306/19/23 11:313911811
2-Nitrophenol <170 ug/kg 06/20/23 22:34 88-75-506/19/23 11:313911701
4-Nitrophenol <756 ug/kg 06/20/23 22:34 100-02-706/19/23 11:3119607561
N-Nitrosodimethylamine <132 ug/kg 06/20/23 22:34 62-75-906/19/23 11:313911321
N-Nitroso-di-n-propylamine <147 ug/kg 06/20/23 22:34 621-64-706/19/23 11:313911471
N-Nitrosodiphenylamine <139 ug/kg 06/20/23 22:34 86-30-606/19/23 11:313911391
2,2'-Oxybis(1-chloropropane)<186 ug/kg 06/20/23 22:34 108-60-106/19/23 11:313911861
Pentachlorophenol <383 ug/kg 06/20/23 22:34 87-86-506/19/23 11:317823831
Phenanthrene <128 ug/kg 06/20/23 22:34 85-01-806/19/23 11:313911281
Phenol <174 ug/kg 06/20/23 22:34 108-95-206/19/23 11:313911741
Pyrene <159 ug/kg 06/20/23 22:34 129-00-006/19/23 11:313911591
Pyridine <123 ug/kg 06/20/23 22:34 110-86-106/19/23 11:313911231
1,2,4-Trichlorobenzene <154 ug/kg 06/20/23 22:34 120-82-106/19/23 11:313911541
2,4,5-Trichlorophenol <179 ug/kg 06/20/23 22:34 95-95-406/19/23 11:313911791
2,4,6-Trichlorophenol <161 ug/kg 06/20/23 22:34 88-06-206/19/23 11:313911611
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-3 (0-2)Lab ID:92672976003 Collected:06/14/23 15:00 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Surrogates
Nitrobenzene-d5 (S)55 %06/20/23 22:34 4165-60-006/19/23 11:3110-130 1
2-Fluorobiphenyl (S)56 %06/20/23 22:34 321-60-806/19/23 11:3110-130 1
Terphenyl-d14 (S)82 %06/20/23 22:34 1718-51-006/19/23 11:3110-130 1
Phenol-d6 (S)56 %06/20/23 22:34 13127-88-306/19/23 11:3110-130 1
2-Fluorophenol (S)53 %06/20/23 22:34 367-12-406/19/23 11:3110-130 1
2,4,6-Tribromophenol (S)68 %06/20/23 22:34 118-79-606/19/23 11:3110-131 1
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone 119J ug/kg 06/19/23 17:00 67-64-106/19/23 14:0012740.7 1
Benzene <2.5 ug/kg 06/19/23 17:00 71-43-206/19/23 14:006.3 2.5 1
Bromobenzene <2.1 ug/kg 06/19/23 17:00 108-86-106/19/23 14:006.3 2.1 1
Bromochloromethane <1.9 ug/kg 06/19/23 17:00 74-97-506/19/23 14:006.3 1.9 1
Bromodichloromethane <2.4 ug/kg 06/19/23 17:00 75-27-406/19/23 14:006.3 2.4 1
Bromoform <2.2 ug/kg 06/19/23 17:00 75-25-206/19/23 14:006.3 2.2 1
Bromomethane <19.6 ug/kg 06/19/23 17:00 74-83-906/19/23 14:0025.3 19.6 1
2-Butanone (MEK)36.9J ug/kg 06/19/23 17:00 78-93-306/19/23 14:0012730.4 1
n-Butylbenzene <4.0 ug/kg 06/19/23 17:00 104-51-806/19/23 14:006.3 4.0 1
sec-Butylbenzene <2.8 ug/kg 06/19/23 17:00 135-98-806/19/23 14:006.3 2.8 1
tert-Butylbenzene <2.3 ug/kg 06/19/23 17:00 98-06-606/19/23 14:006.3 2.3 1
Carbon tetrachloride <2.4 ug/kg 06/19/23 17:00 56-23-506/19/23 14:006.3 2.4 1
Chlorobenzene <3.6 ug/kg 06/19/23 17:00 108-90-706/19/23 14:006.3 3.6 1
Chloroethane <4.9 ug/kg 06/19/23 17:00 75-00-3 v106/19/23 14:0012.7 4.9 1
Chloroform <5.3 ug/kg 06/19/23 17:00 67-66-306/19/23 14:006.3 5.3 1
Chloromethane <5.3 ug/kg 06/19/23 17:00 74-87-3 v106/19/23 14:0012.7 5.3 1
2-Chlorotoluene <2.2 ug/kg 06/19/23 17:00 95-49-806/19/23 14:006.3 2.2 1
4-Chlorotoluene <3.5 ug/kg 06/19/23 17:00 106-43-406/19/23 14:006.3 3.5 1
1,2-Dibromo-3-chloropropane <2.5 ug/kg 06/19/23 17:00 96-12-806/19/23 14:006.3 2.5 1
Dibromochloromethane <3.6 ug/kg 06/19/23 17:00 124-48-106/19/23 14:006.3 3.6 1
1,2-Dibromoethane (EDB)<2.8 ug/kg 06/19/23 17:00 106-93-406/19/23 14:006.3 2.8 1
Dibromomethane <1.4 ug/kg 06/19/23 17:00 74-95-306/19/23 14:006.3 1.4 1
1,2-Dichlorobenzene <2.3 ug/kg 06/19/23 17:00 95-50-106/19/23 14:006.3 2.3 1
1,3-Dichlorobenzene <2.0 ug/kg 06/19/23 17:00 541-73-106/19/23 14:006.3 2.0 1
1,4-Dichlorobenzene <1.6 ug/kg 06/19/23 17:00 106-46-706/19/23 14:006.3 1.6 1
Dichlorodifluoromethane <6.4 ug/kg 06/19/23 17:00 75-71-806/19/23 14:0012.7 6.4 1
1,1-Dichloroethane <2.6 ug/kg 06/19/23 17:00 75-34-306/19/23 14:006.3 2.6 1
1,2-Dichloroethane <4.2 ug/kg 06/19/23 17:00 107-06-206/19/23 14:006.3 4.2 1
1,1-Dichloroethene <2.6 ug/kg 06/19/23 17:00 75-35-406/19/23 14:006.3 2.6 1
cis-1,2-Dichloroethene <2.2 ug/kg 06/19/23 17:00 156-59-206/19/23 14:006.3 2.2 1
trans-1,2-Dichloroethene <5.4 ug/kg 06/19/23 17:00 156-60-506/19/23 14:006.3 5.4 1
1,2-Dichloropropane <1.9 ug/kg 06/19/23 17:00 78-87-506/19/23 14:006.3 1.9 1
1,3-Dichloropropane <2.0 ug/kg 06/19/23 17:00 142-28-906/19/23 14:006.3 2.0 1
2,2-Dichloropropane <4.8 ug/kg 06/19/23 17:00 594-20-706/19/23 14:006.3 4.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-3 (0-2)Lab ID:92672976003 Collected:06/14/23 15:00 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
1,1-Dichloropropene <3.0 ug/kg 06/19/23 17:00 563-58-606/19/23 14:006.3 3.0 1
cis-1,3-Dichloropropene <1.7 ug/kg 06/19/23 17:00 10061-01-506/19/23 14:006.3 1.7 1
trans-1,3-Dichloropropene <2.2 ug/kg 06/19/23 17:00 10061-02-606/19/23 14:006.3 2.2 1
Diisopropyl ether <1.7 ug/kg 06/19/23 17:00 108-20-306/19/23 14:006.3 1.7 1
Ethylbenzene <3.0 ug/kg 06/19/23 17:00 100-41-406/19/23 14:006.3 3.0 1
Hexachloro-1,3-butadiene <10.4 ug/kg 06/19/23 17:00 87-68-306/19/23 14:0012.7 10.4 1
2-Hexanone <6.1 ug/kg 06/19/23 17:00 591-78-606/19/23 14:0063.4 6.1 1
Isopropylbenzene (Cumene)<2.2 ug/kg 06/19/23 17:00 98-82-806/19/23 14:006.3 2.2 1
p-Isopropyltoluene 437 ug/kg 06/19/23 17:00 99-87-606/19/23 14:006.3 3.1 1
Methylene Chloride <17.4 ug/kg 06/19/23 17:00 75-09-206/19/23 14:0025.3 17.4 1
4-Methyl-2-pentanone (MIBK)<6.1 ug/kg 06/19/23 17:00 108-10-106/19/23 14:0063.4 6.1 1
Methyl-tert-butyl ether <2.4 ug/kg 06/19/23 17:00 1634-04-406/19/23 14:006.3 2.4 1
Naphthalene <3.3 ug/kg 06/19/23 17:00 91-20-306/19/23 14:006.3 3.3 1
n-Propylbenzene <2.3 ug/kg 06/19/23 17:00 103-65-106/19/23 14:006.3 2.3 1
Styrene <1.7 ug/kg 06/19/23 17:00 100-42-506/19/23 14:006.3 1.7 1
1,1,1,2-Tetrachloroethane <2.4 ug/kg 06/19/23 17:00 630-20-606/19/23 14:006.3 2.4 1
1,1,2,2-Tetrachloroethane <1.7 ug/kg 06/19/23 17:00 79-34-506/19/23 14:006.3 1.7 1
Tetrachloroethene <2.0 ug/kg 06/19/23 17:00 127-18-406/19/23 14:006.3 2.0 1
Toluene <4.4 ug/kg 06/19/23 17:00 108-88-306/19/23 14:006.3 4.4 1
1,2,3-Trichlorobenzene <5.1 ug/kg 06/19/23 17:00 87-61-606/19/23 14:006.3 5.1 1
1,2,4-Trichlorobenzene <5.3 ug/kg 06/19/23 17:00 120-82-106/19/23 14:006.3 5.3 1
1,1,1-Trichloroethane <3.3 ug/kg 06/19/23 17:00 71-55-606/19/23 14:006.3 3.3 1
1,1,2-Trichloroethane <2.1 ug/kg 06/19/23 17:00 79-00-506/19/23 14:006.3 2.1 1
Trichloroethene <5.1 ug/kg 06/19/23 17:00 79-01-606/19/23 14:006.3 5.1 1
Trichlorofluoromethane <3.5 ug/kg 06/19/23 17:00 75-69-406/19/23 14:006.3 3.5 1
1,2,3-Trichloropropane <3.2 ug/kg 06/19/23 17:00 96-18-406/19/23 14:006.3 3.2 1
1,2,4-Trimethylbenzene <3.8 ug/kg 06/19/23 17:00 95-63-606/19/23 14:006.3 3.8 1
1,3,5-Trimethylbenzene <2.1 ug/kg 06/19/23 17:00 108-67-806/19/23 14:006.3 2.1 1
Vinyl acetate <13.0 ug/kg 06/19/23 17:00 108-05-406/19/23 14:0063.4 13.0 1
Vinyl chloride <3.2 ug/kg 06/19/23 17:00 75-01-4 v106/19/23 14:0012.7 3.2 1
Xylene (Total)<3.6 ug/kg 06/19/23 17:00 1330-20-706/19/23 14:0012.7 3.6 1
m&p-Xylene <4.3 ug/kg 06/19/23 17:00 179601-23-106/19/23 14:0012.7 4.3 1
o-Xylene <2.8 ug/kg 06/19/23 17:00 95-47-606/19/23 14:006.3 2.8 1
Surrogates
Toluene-d8 (S)102 %06/19/23 17:00 2037-26-506/19/23 14:0070-130 1
4-Bromofluorobenzene (S)108 %06/19/23 17:00 460-00-406/19/23 14:0070-130 1
1,2-Dichloroethane-d4 (S)112 %06/19/23 17:00 17060-07-006/19/23 14:0070-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 14.5 %06/16/23 15:02 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-3 (0-2)Lab ID:92672976003 Collected:06/14/23 15:00 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 2540G Preparation Method: SM 2540 G
Pace National - Mt. Juliet
Total Solids 2540 G-2011
Total Solids 83.2 %06/21/23 12:0506/21/23 11:391
Analytical Method: EPA 7199 Preparation Method: 3060A
Pace National - Mt. Juliet
Wet Chemistry 7199
Chromium, Hexavalent 2.02 mg/kg 06/22/23 12:43 18540-29-906/21/23 05:231.20 0.306 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-4 (0-2)Lab ID:92672976004 Collected:06/14/23 12:55 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020B Preparation Method: EPA 3050B
Pace Analytical Services - Minneapolis
6020B MET ICPMS
Arsenic 2.4 mg/kg 06/27/23 16:16 7440-38-206/26/23 05:160.58 0.17 1
Barium 192 mg/kg 06/27/23 16:16 7440-39-306/26/23 05:160.35 0.088 1
Cadmium 0.051J mg/kg 06/27/23 16:16 7440-43-906/26/23 05:160.093 0.034 1
Chromium 197 mg/kg 06/27/23 16:16 7440-47-306/26/23 05:162.3 0.45 1
Copper 21.8 mg/kg 06/27/23 16:16 7440-50-806/26/23 05:161.2 0.36 1
Lead 10.6 mg/kg 06/27/23 16:16 7439-92-106/26/23 05:160.58 0.11 1
Nickel 62.0 mg/kg 06/27/23 16:16 7440-02-006/26/23 05:160.58 0.27 1
Selenium 0.47J mg/kg 06/27/23 16:16 7782-49-206/26/23 05:160.58 0.12 1
Silver <0.24 mg/kg 06/27/23 16:16 7440-22-406/26/23 05:160.58 0.24 1
Vanadium 215 mg/kg 06/27/23 16:16 7440-62-206/26/23 05:161.2 0.28 1
Zinc 35.6 mg/kg 06/27/23 16:16 7440-66-606/26/23 05:165.8 1.4 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B
Pace Analytical Services - Minneapolis
7471B Mercury
Mercury 0.033 mg/kg 06/27/23 18:45 7439-97-606/22/23 17:290.025 0.011 1
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Acenaphthene <148 ug/kg 06/20/23 23:02 83-32-906/19/23 11:314211481
Acenaphthylene <148 ug/kg 06/20/23 23:02 208-96-806/19/23 11:314211481
Aniline <165 ug/kg 06/20/23 23:02 62-53-306/19/23 11:314211651
Anthracene <138 ug/kg 06/20/23 23:02 120-12-706/19/23 11:314211381
Benzo(a)anthracene <140 ug/kg 06/20/23 23:02 56-55-306/19/23 11:314211401
Benzo(a)pyrene <146 ug/kg 06/20/23 23:02 50-32-806/19/23 11:314211461
Benzo(b)fluoranthene <140 ug/kg 06/20/23 23:02 205-99-206/19/23 11:314211401
Benzo(g,h,i)perylene <163 ug/kg 06/20/23 23:02 191-24-206/19/23 11:314211631
Benzo(k)fluoranthene <148 ug/kg 06/20/23 23:02 207-08-906/19/23 11:314211481
Benzoic Acid <905 ug/kg 06/20/23 23:02 65-85-006/19/23 11:3121109051
Benzyl alcohol <319 ug/kg 06/20/23 23:02 100-51-606/19/23 11:318433191
4-Bromophenylphenyl ether <162 ug/kg 06/20/23 23:02 101-55-306/19/23 11:314211621
Butylbenzylphthalate <178 ug/kg 06/20/23 23:02 85-68-706/19/23 11:314211781
4-Chloro-3-methylphenol <296 ug/kg 06/20/23 23:02 59-50-706/19/23 11:318432961
4-Chloroaniline <331 ug/kg 06/20/23 23:02 106-47-806/19/23 11:318433311
bis(2-Chloroethoxy)methane <175 ug/kg 06/20/23 23:02 111-91-106/19/23 11:314211751
bis(2-Chloroethyl) ether <158 ug/kg 06/20/23 23:02 111-44-406/19/23 11:314211581
2-Chloronaphthalene <167 ug/kg 06/20/23 23:02 91-58-706/19/23 11:314211671
2-Chlorophenol <158 ug/kg 06/20/23 23:02 95-57-806/19/23 11:314211581
4-Chlorophenylphenyl ether <157 ug/kg 06/20/23 23:02 7005-72-306/19/23 11:314211571
Chrysene <153 ug/kg 06/20/23 23:02 218-01-906/19/23 11:314211531
Dibenz(a,h)anthracene <162 ug/kg 06/20/23 23:02 53-70-306/19/23 11:314211621
Dibenzofuran <152 ug/kg 06/20/23 23:02 132-64-906/19/23 11:314211521
1,2-Dichlorobenzene <152 ug/kg 06/20/23 23:02 95-50-106/19/23 11:314211521
1,3-Dichlorobenzene <149 ug/kg 06/20/23 23:02 541-73-106/19/23 11:314211491
1,4-Dichlorobenzene <161 ug/kg 06/20/23 23:02 106-46-706/19/23 11:314211611
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-4 (0-2)Lab ID:92672976004 Collected:06/14/23 12:55 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
3,3'-Dichlorobenzidine <285 ug/kg 06/20/23 23:02 91-94-106/19/23 11:318432851
2,4-Dichlorophenol <165 ug/kg 06/20/23 23:02 120-83-206/19/23 11:314211651
Diethylphthalate <155 ug/kg 06/20/23 23:02 84-66-206/19/23 11:314211551
2,4-Dimethylphenol <175 ug/kg 06/20/23 23:02 105-67-906/19/23 11:314211751
Dimethylphthalate <153 ug/kg 06/20/23 23:02 131-11-306/19/23 11:314211531
Di-n-butylphthalate <142 ug/kg 06/20/23 23:02 84-74-206/19/23 11:314211421
4,6-Dinitro-2-methylphenol <393 ug/kg 06/20/23 23:02 534-52-1 v206/19/23 11:318433931
2,4-Dinitrophenol <1300 ug/kg 06/20/23 23:02 51-28-506/19/23 11:31211013001
2,4-Dinitrotoluene <162 ug/kg 06/20/23 23:02 121-14-206/19/23 11:314211621
2,6-Dinitrotoluene <155 ug/kg 06/20/23 23:02 606-20-206/19/23 11:314211551
Di-n-octylphthalate <166 ug/kg 06/20/23 23:02 117-84-006/19/23 11:314211661
bis(2-Ethylhexyl)phthalate <163 ug/kg 06/20/23 23:02 117-81-706/19/23 11:314211631
Fluoranthene <144 ug/kg 06/20/23 23:02 206-44-006/19/23 11:314211441
Fluorene <148 ug/kg 06/20/23 23:02 86-73-706/19/23 11:314211481
Hexachloro-1,3-butadiene <183 ug/kg 06/20/23 23:02 87-68-306/19/23 11:314211831
Hexachlorobenzene <165 ug/kg 06/20/23 23:02 118-74-106/19/23 11:314211651
Hexachlorocyclopentadiene <241 ug/kg 06/20/23 23:02 77-47-4 v206/19/23 11:314212411
Hexachloroethane <161 ug/kg 06/20/23 23:02 67-72-106/19/23 11:314211611
Indeno(1,2,3-cd)pyrene <166 ug/kg 06/20/23 23:02 193-39-506/19/23 11:314211661
Isophorone <188 ug/kg 06/20/23 23:02 78-59-106/19/23 11:314211881
1-Methylnaphthalene <148 ug/kg 06/20/23 23:02 90-12-006/19/23 11:314211481
2-Methylnaphthalene <169 ug/kg 06/20/23 23:02 91-57-606/19/23 11:314211691
2-Methylphenol(o-Cresol)<172 ug/kg 06/20/23 23:02 95-48-706/19/23 11:314211721
3&4-Methylphenol(m&p Cresol)<170 ug/kg 06/20/23 23:02 15831-10-406/19/23 11:314211701
Naphthalene <143 ug/kg 06/20/23 23:02 91-20-306/19/23 11:314211431
2-Nitroaniline <345 ug/kg 06/20/23 23:02 88-74-406/19/23 11:3121103451
3-Nitroaniline <331 ug/kg 06/20/23 23:02 99-09-206/19/23 11:3121103311
4-Nitroaniline <321 ug/kg 06/20/23 23:02 100-01-606/19/23 11:318433211
Nitrobenzene <195 ug/kg 06/20/23 23:02 98-95-306/19/23 11:314211951
2-Nitrophenol <183 ug/kg 06/20/23 23:02 88-75-506/19/23 11:314211831
4-Nitrophenol <815 ug/kg 06/20/23 23:02 100-02-706/19/23 11:3121108151
N-Nitrosodimethylamine <142 ug/kg 06/20/23 23:02 62-75-906/19/23 11:314211421
N-Nitroso-di-n-propylamine <158 ug/kg 06/20/23 23:02 621-64-706/19/23 11:314211581
N-Nitrosodiphenylamine <149 ug/kg 06/20/23 23:02 86-30-606/19/23 11:314211491
2,2'-Oxybis(1-chloropropane)<201 ug/kg 06/20/23 23:02 108-60-106/19/23 11:314212011
Pentachlorophenol <413 ug/kg 06/20/23 23:02 87-86-506/19/23 11:318434131
Phenanthrene <138 ug/kg 06/20/23 23:02 85-01-806/19/23 11:314211381
Phenol <188 ug/kg 06/20/23 23:02 108-95-206/19/23 11:314211881
Pyrene <171 ug/kg 06/20/23 23:02 129-00-006/19/23 11:314211711
Pyridine <133 ug/kg 06/20/23 23:02 110-86-106/19/23 11:314211331
1,2,4-Trichlorobenzene <166 ug/kg 06/20/23 23:02 120-82-106/19/23 11:314211661
2,4,5-Trichlorophenol <193 ug/kg 06/20/23 23:02 95-95-406/19/23 11:314211931
2,4,6-Trichlorophenol <174 ug/kg 06/20/23 23:02 88-06-206/19/23 11:314211741
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-4 (0-2)Lab ID:92672976004 Collected:06/14/23 12:55 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Surrogates
Nitrobenzene-d5 (S)53 %06/20/23 23:02 4165-60-006/19/23 11:3110-130 1
2-Fluorobiphenyl (S)53 %06/20/23 23:02 321-60-806/19/23 11:3110-130 1
Terphenyl-d14 (S)81 %06/20/23 23:02 1718-51-006/19/23 11:3110-130 1
Phenol-d6 (S)53 %06/20/23 23:02 13127-88-306/19/23 11:3110-130 1
2-Fluorophenol (S)51 %06/20/23 23:02 367-12-406/19/23 11:3110-130 1
2,4,6-Tribromophenol (S)61 %06/20/23 23:02 118-79-606/19/23 11:3110-131 1
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone <43.0 ug/kg 06/19/23 17:37 67-64-106/19/23 14:0013443.0 1
Benzene <2.7 ug/kg 06/19/23 17:37 71-43-206/19/23 14:006.7 2.7 1
Bromobenzene <2.2 ug/kg 06/19/23 17:37 108-86-106/19/23 14:006.7 2.2 1
Bromochloromethane <2.0 ug/kg 06/19/23 17:37 74-97-506/19/23 14:006.7 2.0 1
Bromodichloromethane <2.6 ug/kg 06/19/23 17:37 75-27-406/19/23 14:006.7 2.6 1
Bromoform <2.4 ug/kg 06/19/23 17:37 75-25-206/19/23 14:006.7 2.4 1
Bromomethane <20.7 ug/kg 06/19/23 17:37 74-83-906/19/23 14:0026.8 20.7 1
2-Butanone (MEK)<32.1 ug/kg 06/19/23 17:37 78-93-306/19/23 14:0013432.1 1
n-Butylbenzene <4.2 ug/kg 06/19/23 17:37 104-51-806/19/23 14:006.7 4.2 1
sec-Butylbenzene <2.9 ug/kg 06/19/23 17:37 135-98-806/19/23 14:006.7 2.9 1
tert-Butylbenzene <2.4 ug/kg 06/19/23 17:37 98-06-606/19/23 14:006.7 2.4 1
Carbon tetrachloride <2.5 ug/kg 06/19/23 17:37 56-23-506/19/23 14:006.7 2.5 1
Chlorobenzene <3.8 ug/kg 06/19/23 17:37 108-90-706/19/23 14:006.7 3.8 1
Chloroethane <5.2 ug/kg 06/19/23 17:37 75-00-3 v106/19/23 14:0013.4 5.2 1
Chloroform <5.6 ug/kg 06/19/23 17:37 67-66-306/19/23 14:006.7 5.6 1
Chloromethane <5.6 ug/kg 06/19/23 17:37 74-87-3 v106/19/23 14:0013.4 5.6 1
2-Chlorotoluene <2.4 ug/kg 06/19/23 17:37 95-49-806/19/23 14:006.7 2.4 1
4-Chlorotoluene <3.7 ug/kg 06/19/23 17:37 106-43-406/19/23 14:006.7 3.7 1
1,2-Dibromo-3-chloropropane <2.6 ug/kg 06/19/23 17:37 96-12-806/19/23 14:006.7 2.6 1
Dibromochloromethane <3.8 ug/kg 06/19/23 17:37 124-48-106/19/23 14:006.7 3.8 1
1,2-Dibromoethane (EDB)<2.9 ug/kg 06/19/23 17:37 106-93-406/19/23 14:006.7 2.9 1
Dibromomethane <1.4 ug/kg 06/19/23 17:37 74-95-306/19/23 14:006.7 1.4 1
1,2-Dichlorobenzene <2.4 ug/kg 06/19/23 17:37 95-50-106/19/23 14:006.7 2.4 1
1,3-Dichlorobenzene <2.1 ug/kg 06/19/23 17:37 541-73-106/19/23 14:006.7 2.1 1
1,4-Dichlorobenzene <1.7 ug/kg 06/19/23 17:37 106-46-706/19/23 14:006.7 1.7 1
Dichlorodifluoromethane <6.8 ug/kg 06/19/23 17:37 75-71-806/19/23 14:0013.4 6.8 1
1,1-Dichloroethane <2.8 ug/kg 06/19/23 17:37 75-34-306/19/23 14:006.7 2.8 1
1,2-Dichloroethane <4.4 ug/kg 06/19/23 17:37 107-06-206/19/23 14:006.7 4.4 1
1,1-Dichloroethene <2.8 ug/kg 06/19/23 17:37 75-35-406/19/23 14:006.7 2.8 1
cis-1,2-Dichloroethene <2.3 ug/kg 06/19/23 17:37 156-59-206/19/23 14:006.7 2.3 1
trans-1,2-Dichloroethene <5.7 ug/kg 06/19/23 17:37 156-60-506/19/23 14:006.7 5.7 1
1,2-Dichloropropane <2.0 ug/kg 06/19/23 17:37 78-87-506/19/23 14:006.7 2.0 1
1,3-Dichloropropane <2.1 ug/kg 06/19/23 17:37 142-28-906/19/23 14:006.7 2.1 1
2,2-Dichloropropane <5.1 ug/kg 06/19/23 17:37 594-20-706/19/23 14:006.7 5.1 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-4 (0-2)Lab ID:92672976004 Collected:06/14/23 12:55 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
1,1-Dichloropropene <3.2 ug/kg 06/19/23 17:37 563-58-606/19/23 14:006.7 3.2 1
cis-1,3-Dichloropropene <1.8 ug/kg 06/19/23 17:37 10061-01-506/19/23 14:006.7 1.8 1
trans-1,3-Dichloropropene <2.3 ug/kg 06/19/23 17:37 10061-02-606/19/23 14:006.7 2.3 1
Diisopropyl ether <1.8 ug/kg 06/19/23 17:37 108-20-306/19/23 14:006.7 1.8 1
Ethylbenzene <3.1 ug/kg 06/19/23 17:37 100-41-406/19/23 14:006.7 3.1 1
Hexachloro-1,3-butadiene <10.9 ug/kg 06/19/23 17:37 87-68-306/19/23 14:0013.4 10.9 1
2-Hexanone <6.5 ug/kg 06/19/23 17:37 591-78-606/19/23 14:0066.9 6.5 1
Isopropylbenzene (Cumene)<2.3 ug/kg 06/19/23 17:37 98-82-806/19/23 14:006.7 2.3 1
p-Isopropyltoluene 7.6 ug/kg 06/19/23 17:37 99-87-606/19/23 14:006.7 3.3 1
Methylene Chloride <18.3 ug/kg 06/19/23 17:37 75-09-206/19/23 14:0026.8 18.3 1
4-Methyl-2-pentanone (MIBK)<6.5 ug/kg 06/19/23 17:37 108-10-106/19/23 14:0066.9 6.5 1
Methyl-tert-butyl ether <2.5 ug/kg 06/19/23 17:37 1634-04-406/19/23 14:006.7 2.5 1
Naphthalene <3.5 ug/kg 06/19/23 17:37 91-20-306/19/23 14:006.7 3.5 1
n-Propylbenzene <2.4 ug/kg 06/19/23 17:37 103-65-106/19/23 14:006.7 2.4 1
Styrene <1.8 ug/kg 06/19/23 17:37 100-42-506/19/23 14:006.7 1.8 1
1,1,1,2-Tetrachloroethane <2.6 ug/kg 06/19/23 17:37 630-20-606/19/23 14:006.7 2.6 1
1,1,2,2-Tetrachloroethane <1.8 ug/kg 06/19/23 17:37 79-34-506/19/23 14:006.7 1.8 1
Tetrachloroethene <2.1 ug/kg 06/19/23 17:37 127-18-406/19/23 14:006.7 2.1 1
Toluene <4.6 ug/kg 06/19/23 17:37 108-88-306/19/23 14:006.7 4.6 1
1,2,3-Trichlorobenzene <5.4 ug/kg 06/19/23 17:37 87-61-606/19/23 14:006.7 5.4 1
1,2,4-Trichlorobenzene <5.6 ug/kg 06/19/23 17:37 120-82-106/19/23 14:006.7 5.6 1
1,1,1-Trichloroethane <3.5 ug/kg 06/19/23 17:37 71-55-606/19/23 14:006.7 3.5 1
1,1,2-Trichloroethane <2.2 ug/kg 06/19/23 17:37 79-00-506/19/23 14:006.7 2.2 1
Trichloroethene <5.4 ug/kg 06/19/23 17:37 79-01-606/19/23 14:006.7 5.4 1
Trichlorofluoromethane <3.7 ug/kg 06/19/23 17:37 75-69-406/19/23 14:006.7 3.7 1
1,2,3-Trichloropropane <3.4 ug/kg 06/19/23 17:37 96-18-4 IK06/19/23 14:006.7 3.4 1
1,2,4-Trimethylbenzene <4.0 ug/kg 06/19/23 17:37 95-63-606/19/23 14:006.7 4.0 1
1,3,5-Trimethylbenzene <2.2 ug/kg 06/19/23 17:37 108-67-806/19/23 14:006.7 2.2 1
Vinyl acetate <13.8 ug/kg 06/19/23 17:37 108-05-406/19/23 14:0066.9 13.8 1
Vinyl chloride <3.4 ug/kg 06/19/23 17:37 75-01-4 v106/19/23 14:0013.4 3.4 1
Xylene (Total)<3.8 ug/kg 06/19/23 17:37 1330-20-706/19/23 14:0013.4 3.8 1
m&p-Xylene <4.6 ug/kg 06/19/23 17:37 179601-23-106/19/23 14:0013.4 4.6 1
o-Xylene <3.0 ug/kg 06/19/23 17:37 95-47-606/19/23 14:006.7 3.0 1
Surrogates
Toluene-d8 (S)102 %06/19/23 17:37 2037-26-506/19/23 14:0070-130 1
4-Bromofluorobenzene (S)103 %06/19/23 17:37 460-00-406/19/23 14:0070-130 1
1,2-Dichloroethane-d4 (S)110 %06/19/23 17:37 17060-07-006/19/23 14:0070-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 20.4 %06/16/23 15:26 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-4 (0-2)Lab ID:92672976004 Collected:06/14/23 12:55 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 2540G Preparation Method: SM 2540 G
Pace National - Mt. Juliet
Total Solids 2540 G-2011
Total Solids 77.1 %06/21/23 12:0506/21/23 11:391
Analytical Method: EPA 7199 Preparation Method: 3060A
Pace National - Mt. Juliet
Wet Chemistry 7199
Chromium, Hexavalent 5.31 mg/kg 06/22/23 12:58 18540-29-906/21/23 05:231.30 0.331 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-5 (0-2)Lab ID:92672976005 Collected:06/14/23 11:10 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020B Preparation Method: EPA 3050B
Pace Analytical Services - Minneapolis
6020B MET ICPMS
Arsenic 1.9 mg/kg 06/27/23 16:30 7440-38-206/26/23 05:160.60 0.17 1
Barium 142 mg/kg 06/27/23 16:30 7440-39-306/26/23 05:160.36 0.091 1
Cadmium 0.094J mg/kg 06/27/23 16:30 7440-43-906/26/23 05:160.097 0.036 1
Chromium 59.1 mg/kg 06/27/23 16:30 7440-47-306/26/23 05:162.4 0.47 1
Copper 15.8 mg/kg 06/27/23 16:30 7440-50-806/26/23 05:161.2 0.37 1
Lead 7.9 mg/kg 06/27/23 16:30 7439-92-106/26/23 05:160.60 0.11 1
Nickel 32.1 mg/kg 06/27/23 16:30 7440-02-006/26/23 05:160.60 0.28 1
Selenium 0.47J mg/kg 06/27/23 16:30 7782-49-206/26/23 05:160.60 0.13 1
Silver <0.25 mg/kg 06/27/23 16:30 7440-22-406/26/23 05:160.60 0.25 1
Vanadium 218 mg/kg 06/27/23 16:30 7440-62-206/26/23 05:161.2 0.29 1
Zinc 34.5 mg/kg 06/27/23 16:30 7440-66-606/26/23 05:166.0 1.4 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B
Pace Analytical Services - Minneapolis
7471B Mercury
Mercury 0.020J mg/kg 06/27/23 18:46 7439-97-606/22/23 17:290.022 0.0097 1
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Acenaphthene <147 ug/kg 06/20/23 23:30 83-32-906/19/23 11:314181471
Acenaphthylene <147 ug/kg 06/20/23 23:30 208-96-806/19/23 11:314181471
Aniline <163 ug/kg 06/20/23 23:30 62-53-306/19/23 11:314181631
Anthracene <137 ug/kg 06/20/23 23:30 120-12-706/19/23 11:314181371
Benzo(a)anthracene <139 ug/kg 06/20/23 23:30 56-55-306/19/23 11:314181391
Benzo(a)pyrene <144 ug/kg 06/20/23 23:30 50-32-806/19/23 11:314181441
Benzo(b)fluoranthene <139 ug/kg 06/20/23 23:30 205-99-206/19/23 11:314181391
Benzo(g,h,i)perylene <162 ug/kg 06/20/23 23:30 191-24-206/19/23 11:314181621
Benzo(k)fluoranthene <147 ug/kg 06/20/23 23:30 207-08-906/19/23 11:314181471
Benzoic Acid <898 ug/kg 06/20/23 23:30 65-85-006/19/23 11:3120908981
Benzyl alcohol <317 ug/kg 06/20/23 23:30 100-51-606/19/23 11:318363171
4-Bromophenylphenyl ether <161 ug/kg 06/20/23 23:30 101-55-306/19/23 11:314181611
Butylbenzylphthalate <176 ug/kg 06/20/23 23:30 85-68-706/19/23 11:314181761
4-Chloro-3-methylphenol <294 ug/kg 06/20/23 23:30 59-50-706/19/23 11:318362941
4-Chloroaniline <328 ug/kg 06/20/23 23:30 106-47-806/19/23 11:318363281
bis(2-Chloroethoxy)methane <173 ug/kg 06/20/23 23:30 111-91-106/19/23 11:314181731
bis(2-Chloroethyl) ether <157 ug/kg 06/20/23 23:30 111-44-406/19/23 11:314181571
2-Chloronaphthalene <166 ug/kg 06/20/23 23:30 91-58-706/19/23 11:314181661
2-Chlorophenol <157 ug/kg 06/20/23 23:30 95-57-806/19/23 11:314181571
4-Chlorophenylphenyl ether <156 ug/kg 06/20/23 23:30 7005-72-306/19/23 11:314181561
Chrysene <152 ug/kg 06/20/23 23:30 218-01-906/19/23 11:314181521
Dibenz(a,h)anthracene <161 ug/kg 06/20/23 23:30 53-70-306/19/23 11:314181611
Dibenzofuran <151 ug/kg 06/20/23 23:30 132-64-906/19/23 11:314181511
1,2-Dichlorobenzene <151 ug/kg 06/20/23 23:30 95-50-106/19/23 11:314181511
1,3-Dichlorobenzene <148 ug/kg 06/20/23 23:30 541-73-106/19/23 11:314181481
1,4-Dichlorobenzene <160 ug/kg 06/20/23 23:30 106-46-706/19/23 11:314181601
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-5 (0-2)Lab ID:92672976005 Collected:06/14/23 11:10 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
3,3'-Dichlorobenzidine <282 ug/kg 06/20/23 23:30 91-94-106/19/23 11:318362821
2,4-Dichlorophenol <163 ug/kg 06/20/23 23:30 120-83-206/19/23 11:314181631
Diethylphthalate <153 ug/kg 06/20/23 23:30 84-66-206/19/23 11:314181531
2,4-Dimethylphenol <173 ug/kg 06/20/23 23:30 105-67-906/19/23 11:314181731
Dimethylphthalate <152 ug/kg 06/20/23 23:30 131-11-306/19/23 11:314181521
Di-n-butylphthalate <141 ug/kg 06/20/23 23:30 84-74-206/19/23 11:314181411
4,6-Dinitro-2-methylphenol <390 ug/kg 06/20/23 23:30 534-52-1 v206/19/23 11:318363901
2,4-Dinitrophenol <1290 ug/kg 06/20/23 23:30 51-28-506/19/23 11:31209012901
2,4-Dinitrotoluene <161 ug/kg 06/20/23 23:30 121-14-206/19/23 11:314181611
2,6-Dinitrotoluene <153 ug/kg 06/20/23 23:30 606-20-206/19/23 11:314181531
Di-n-octylphthalate <165 ug/kg 06/20/23 23:30 117-84-006/19/23 11:314181651
bis(2-Ethylhexyl)phthalate <162 ug/kg 06/20/23 23:30 117-81-706/19/23 11:314181621
Fluoranthene <143 ug/kg 06/20/23 23:30 206-44-006/19/23 11:314181431
Fluorene <147 ug/kg 06/20/23 23:30 86-73-706/19/23 11:314181471
Hexachloro-1,3-butadiene <181 ug/kg 06/20/23 23:30 87-68-306/19/23 11:314181811
Hexachlorobenzene <163 ug/kg 06/20/23 23:30 118-74-106/19/23 11:314181631
Hexachlorocyclopentadiene <239 ug/kg 06/20/23 23:30 77-47-4 v206/19/23 11:314182391
Hexachloroethane <160 ug/kg 06/20/23 23:30 67-72-106/19/23 11:314181601
Indeno(1,2,3-cd)pyrene <165 ug/kg 06/20/23 23:30 193-39-506/19/23 11:314181651
Isophorone <186 ug/kg 06/20/23 23:30 78-59-106/19/23 11:314181861
1-Methylnaphthalene <147 ug/kg 06/20/23 23:30 90-12-006/19/23 11:314181471
2-Methylnaphthalene <167 ug/kg 06/20/23 23:30 91-57-606/19/23 11:314181671
2-Methylphenol(o-Cresol)<171 ug/kg 06/20/23 23:30 95-48-706/19/23 11:314181711
3&4-Methylphenol(m&p Cresol)<168 ug/kg 06/20/23 23:30 15831-10-406/19/23 11:314181681
Naphthalene <142 ug/kg 06/20/23 23:30 91-20-306/19/23 11:314181421
2-Nitroaniline <342 ug/kg 06/20/23 23:30 88-74-406/19/23 11:3120903421
3-Nitroaniline <328 ug/kg 06/20/23 23:30 99-09-206/19/23 11:3120903281
4-Nitroaniline <318 ug/kg 06/20/23 23:30 100-01-606/19/23 11:318363181
Nitrobenzene <194 ug/kg 06/20/23 23:30 98-95-306/19/23 11:314181941
2-Nitrophenol <181 ug/kg 06/20/23 23:30 88-75-506/19/23 11:314181811
4-Nitrophenol <808 ug/kg 06/20/23 23:30 100-02-706/19/23 11:3120908081
N-Nitrosodimethylamine <141 ug/kg 06/20/23 23:30 62-75-906/19/23 11:314181411
N-Nitroso-di-n-propylamine <157 ug/kg 06/20/23 23:30 621-64-706/19/23 11:314181571
N-Nitrosodiphenylamine <148 ug/kg 06/20/23 23:30 86-30-606/19/23 11:314181481
2,2'-Oxybis(1-chloropropane)<199 ug/kg 06/20/23 23:30 108-60-106/19/23 11:314181991
Pentachlorophenol <409 ug/kg 06/20/23 23:30 87-86-506/19/23 11:318364091
Phenanthrene <137 ug/kg 06/20/23 23:30 85-01-806/19/23 11:314181371
Phenol <186 ug/kg 06/20/23 23:30 108-95-206/19/23 11:314181861
Pyrene <170 ug/kg 06/20/23 23:30 129-00-006/19/23 11:314181701
Pyridine <132 ug/kg 06/20/23 23:30 110-86-106/19/23 11:314181321
1,2,4-Trichlorobenzene <165 ug/kg 06/20/23 23:30 120-82-106/19/23 11:314181651
2,4,5-Trichlorophenol <191 ug/kg 06/20/23 23:30 95-95-406/19/23 11:314181911
2,4,6-Trichlorophenol <172 ug/kg 06/20/23 23:30 88-06-206/19/23 11:314181721
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-5 (0-2)Lab ID:92672976005 Collected:06/14/23 11:10 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Surrogates
Nitrobenzene-d5 (S)45 %06/20/23 23:30 4165-60-006/19/23 11:3110-130 1
2-Fluorobiphenyl (S)43 %06/20/23 23:30 321-60-806/19/23 11:3110-130 1
Terphenyl-d14 (S)81 %06/20/23 23:30 1718-51-006/19/23 11:3110-130 1
Phenol-d6 (S)44 %06/20/23 23:30 13127-88-306/19/23 11:3110-130 1
2-Fluorophenol (S)43 %06/20/23 23:30 367-12-406/19/23 11:3110-130 1
2,4,6-Tribromophenol (S)59 %06/20/23 23:30 118-79-606/19/23 11:3110-131 1
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone <45.8 ug/kg 06/19/23 17:55 67-64-106/19/23 14:0014345.8 1
Benzene <2.8 ug/kg 06/19/23 17:55 71-43-206/19/23 14:007.1 2.8 1
Bromobenzene <2.3 ug/kg 06/19/23 17:55 108-86-106/19/23 14:007.1 2.3 1
Bromochloromethane <2.1 ug/kg 06/19/23 17:55 74-97-506/19/23 14:007.1 2.1 1
Bromodichloromethane <2.8 ug/kg 06/19/23 17:55 75-27-406/19/23 14:007.1 2.8 1
Bromoform <2.5 ug/kg 06/19/23 17:55 75-25-206/19/23 14:007.1 2.5 1
Bromomethane <22.1 ug/kg 06/19/23 17:55 74-83-906/19/23 14:0028.5 22.1 1
2-Butanone (MEK)<34.2 ug/kg 06/19/23 17:55 78-93-306/19/23 14:0014334.2 1
n-Butylbenzene <4.5 ug/kg 06/19/23 17:55 104-51-806/19/23 14:007.1 4.5 1
sec-Butylbenzene <3.1 ug/kg 06/19/23 17:55 135-98-806/19/23 14:007.1 3.1 1
tert-Butylbenzene <2.5 ug/kg 06/19/23 17:55 98-06-606/19/23 14:007.1 2.5 1
Carbon tetrachloride <2.7 ug/kg 06/19/23 17:55 56-23-506/19/23 14:007.1 2.7 1
Chlorobenzene <4.1 ug/kg 06/19/23 17:55 108-90-706/19/23 14:007.1 4.1 1
Chloroethane <5.5 ug/kg 06/19/23 17:55 75-00-3 v106/19/23 14:0014.3 5.5 1
Chloroform <6.0 ug/kg 06/19/23 17:55 67-66-306/19/23 14:007.1 6.0 1
Chloromethane <6.0 ug/kg 06/19/23 17:55 74-87-3 v106/19/23 14:0014.3 6.0 1
2-Chlorotoluene <2.5 ug/kg 06/19/23 17:55 95-49-806/19/23 14:007.1 2.5 1
4-Chlorotoluene <4.0 ug/kg 06/19/23 17:55 106-43-406/19/23 14:007.1 4.0 1
1,2-Dibromo-3-chloropropane <2.8 ug/kg 06/19/23 17:55 96-12-806/19/23 14:007.1 2.8 1
Dibromochloromethane <4.0 ug/kg 06/19/23 17:55 124-48-106/19/23 14:007.1 4.0 1
1,2-Dibromoethane (EDB)<3.1 ug/kg 06/19/23 17:55 106-93-406/19/23 14:007.1 3.1 1
Dibromomethane <1.5 ug/kg 06/19/23 17:55 74-95-306/19/23 14:007.1 1.5 1
1,2-Dichlorobenzene <2.6 ug/kg 06/19/23 17:55 95-50-106/19/23 14:007.1 2.6 1
1,3-Dichlorobenzene <2.2 ug/kg 06/19/23 17:55 541-73-106/19/23 14:007.1 2.2 1
1,4-Dichlorobenzene <1.9 ug/kg 06/19/23 17:55 106-46-706/19/23 14:007.1 1.9 1
Dichlorodifluoromethane <7.3 ug/kg 06/19/23 17:55 75-71-806/19/23 14:0014.3 7.3 1
1,1-Dichloroethane <2.9 ug/kg 06/19/23 17:55 75-34-306/19/23 14:007.1 2.9 1
1,2-Dichloroethane <4.7 ug/kg 06/19/23 17:55 107-06-206/19/23 14:007.1 4.7 1
1,1-Dichloroethene <2.9 ug/kg 06/19/23 17:55 75-35-406/19/23 14:007.1 2.9 1
cis-1,2-Dichloroethene <2.4 ug/kg 06/19/23 17:55 156-59-206/19/23 14:007.1 2.4 1
trans-1,2-Dichloroethene <6.1 ug/kg 06/19/23 17:55 156-60-506/19/23 14:007.1 6.1 1
1,2-Dichloropropane <2.1 ug/kg 06/19/23 17:55 78-87-506/19/23 14:007.1 2.1 1
1,3-Dichloropropane <2.2 ug/kg 06/19/23 17:55 142-28-906/19/23 14:007.1 2.2 1
2,2-Dichloropropane <5.4 ug/kg 06/19/23 17:55 594-20-706/19/23 14:007.1 5.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-5 (0-2)Lab ID:92672976005 Collected:06/14/23 11:10 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
1,1-Dichloropropene <3.4 ug/kg 06/19/23 17:55 563-58-606/19/23 14:007.1 3.4 1
cis-1,3-Dichloropropene <1.9 ug/kg 06/19/23 17:55 10061-01-506/19/23 14:007.1 1.9 1
trans-1,3-Dichloropropene <2.5 ug/kg 06/19/23 17:55 10061-02-606/19/23 14:007.1 2.5 1
Diisopropyl ether <1.9 ug/kg 06/19/23 17:55 108-20-306/19/23 14:007.1 1.9 1
Ethylbenzene <3.3 ug/kg 06/19/23 17:55 100-41-406/19/23 14:007.1 3.3 1
Hexachloro-1,3-butadiene <11.7 ug/kg 06/19/23 17:55 87-68-306/19/23 14:0014.3 11.7 1
2-Hexanone <6.9 ug/kg 06/19/23 17:55 591-78-606/19/23 14:0071.3 6.9 1
Isopropylbenzene (Cumene)<2.4 ug/kg 06/19/23 17:55 98-82-806/19/23 14:007.1 2.4 1
p-Isopropyltoluene <3.5 ug/kg 06/19/23 17:55 99-87-606/19/23 14:007.1 3.5 1
Methylene Chloride <19.5 ug/kg 06/19/23 17:55 75-09-206/19/23 14:0028.5 19.5 1
4-Methyl-2-pentanone (MIBK)<6.9 ug/kg 06/19/23 17:55 108-10-106/19/23 14:0071.3 6.9 1
Methyl-tert-butyl ether <2.7 ug/kg 06/19/23 17:55 1634-04-406/19/23 14:007.1 2.7 1
Naphthalene <3.7 ug/kg 06/19/23 17:55 91-20-306/19/23 14:007.1 3.7 1
n-Propylbenzene <2.5 ug/kg 06/19/23 17:55 103-65-106/19/23 14:007.1 2.5 1
Styrene <1.9 ug/kg 06/19/23 17:55 100-42-506/19/23 14:007.1 1.9 1
1,1,1,2-Tetrachloroethane <2.7 ug/kg 06/19/23 17:55 630-20-606/19/23 14:007.1 2.7 1
1,1,2,2-Tetrachloroethane <1.9 ug/kg 06/19/23 17:55 79-34-506/19/23 14:007.1 1.9 1
Tetrachloroethene <2.3 ug/kg 06/19/23 17:55 127-18-406/19/23 14:007.1 2.3 1
Toluene <4.9 ug/kg 06/19/23 17:55 108-88-306/19/23 14:007.1 4.9 1
1,2,3-Trichlorobenzene <5.8 ug/kg 06/19/23 17:55 87-61-606/19/23 14:007.1 5.8 1
1,2,4-Trichlorobenzene <6.0 ug/kg 06/19/23 17:55 120-82-106/19/23 14:007.1 6.0 1
1,1,1-Trichloroethane <3.7 ug/kg 06/19/23 17:55 71-55-606/19/23 14:007.1 3.7 1
1,1,2-Trichloroethane <2.4 ug/kg 06/19/23 17:55 79-00-506/19/23 14:007.1 2.4 1
Trichloroethene <5.7 ug/kg 06/19/23 17:55 79-01-606/19/23 14:007.1 5.7 1
Trichlorofluoromethane <3.9 ug/kg 06/19/23 17:55 75-69-406/19/23 14:007.1 3.9 1
1,2,3-Trichloropropane <3.6 ug/kg 06/19/23 17:55 96-18-406/19/23 14:007.1 3.6 1
1,2,4-Trimethylbenzene <4.2 ug/kg 06/19/23 17:55 95-63-606/19/23 14:007.1 4.2 1
1,3,5-Trimethylbenzene <2.4 ug/kg 06/19/23 17:55 108-67-806/19/23 14:007.1 2.4 1
Vinyl acetate <14.7 ug/kg 06/19/23 17:55 108-05-406/19/23 14:0071.3 14.7 1
Vinyl chloride <3.6 ug/kg 06/19/23 17:55 75-01-4 v106/19/23 14:0014.3 3.6 1
Xylene (Total)<4.1 ug/kg 06/19/23 17:55 1330-20-706/19/23 14:0014.3 4.1 1
m&p-Xylene <4.9 ug/kg 06/19/23 17:55 179601-23-106/19/23 14:0014.3 4.9 1
o-Xylene <3.2 ug/kg 06/19/23 17:55 95-47-606/19/23 14:007.1 3.2 1
Surrogates
Toluene-d8 (S)102 %06/19/23 17:55 2037-26-506/19/23 14:0070-130 1
4-Bromofluorobenzene (S)105 %06/19/23 17:55 460-00-406/19/23 14:0070-130 1
1,2-Dichloroethane-d4 (S)110 %06/19/23 17:55 17060-07-006/19/23 14:0070-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 22.1 %06/16/23 15:26 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-5 (0-2)Lab ID:92672976005 Collected:06/14/23 11:10 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 2540G Preparation Method: SM 2540 G
Pace National - Mt. Juliet
Total Solids 2540 G-2011
Total Solids 77.9 %06/21/23 12:0506/21/23 11:391
Analytical Method: EPA 7199 Preparation Method: 3060A
Pace National - Mt. Juliet
Wet Chemistry 7199
Chromium, Hexavalent 1.16J mg/kg 06/22/23 13:03 18540-29-9 J06/21/23 05:231.28 0.327 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-DUP (0-2)Lab ID:92672976006 Collected:06/14/23 00:00 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020B Preparation Method: EPA 3050B
Pace Analytical Services - Minneapolis
6020B MET ICPMS
Arsenic 2.4 mg/kg 06/27/23 16:33 7440-38-206/26/23 05:160.65 0.19 1
Barium 184 mg/kg 06/27/23 16:33 7440-39-306/26/23 05:160.39 0.097 1
Cadmium 0.043J mg/kg 06/27/23 16:33 7440-43-906/26/23 05:160.10 0.038 1
Chromium 54.2 mg/kg 06/27/23 16:33 7440-47-306/26/23 05:162.6 0.50 1
Copper 21.4 mg/kg 06/27/23 16:33 7440-50-806/26/23 05:161.3 0.40 1
Lead 11.3 mg/kg 06/27/23 16:33 7439-92-106/26/23 05:160.65 0.12 1
Nickel 29.2 mg/kg 06/27/23 16:33 7440-02-006/26/23 05:160.65 0.30 1
Selenium 0.68 mg/kg 06/27/23 16:33 7782-49-206/26/23 05:160.65 0.14 1
Silver <0.27 mg/kg 06/27/23 16:33 7440-22-406/26/23 05:160.65 0.27 1
Vanadium 188 mg/kg 06/27/23 16:33 7440-62-206/26/23 05:161.3 0.31 1
Zinc 49.0 mg/kg 06/27/23 16:33 7440-66-606/26/23 05:166.5 1.5 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B
Pace Analytical Services - Minneapolis
7471B Mercury
Mercury 0.015J mg/kg 06/27/23 18:49 7439-97-606/22/23 17:290.023 0.010 1
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Acenaphthene <157 ug/kg 06/20/23 23:58 83-32-906/19/23 11:314461571
Acenaphthylene <157 ug/kg 06/20/23 23:58 208-96-806/19/23 11:314461571
Aniline <174 ug/kg 06/20/23 23:58 62-53-306/19/23 11:314461741
Anthracene <146 ug/kg 06/20/23 23:58 120-12-706/19/23 11:314461461
Benzo(a)anthracene <149 ug/kg 06/20/23 23:58 56-55-306/19/23 11:314461491
Benzo(a)pyrene <154 ug/kg 06/20/23 23:58 50-32-806/19/23 11:314461541
Benzo(b)fluoranthene <149 ug/kg 06/20/23 23:58 205-99-206/19/23 11:314461491
Benzo(g,h,i)perylene <173 ug/kg 06/20/23 23:58 191-24-206/19/23 11:314461731
Benzo(k)fluoranthene <157 ug/kg 06/20/23 23:58 207-08-906/19/23 11:314461571
Benzoic Acid <959 ug/kg 06/20/23 23:58 65-85-006/19/23 11:3122309591
Benzyl alcohol <338 ug/kg 06/20/23 23:58 100-51-606/19/23 11:318923381
4-Bromophenylphenyl ether <172 ug/kg 06/20/23 23:58 101-55-306/19/23 11:314461721
Butylbenzylphthalate <188 ug/kg 06/20/23 23:58 85-68-706/19/23 11:314461881
4-Chloro-3-methylphenol <314 ug/kg 06/20/23 23:58 59-50-706/19/23 11:318923141
4-Chloroaniline <350 ug/kg 06/20/23 23:58 106-47-806/19/23 11:318923501
bis(2-Chloroethoxy)methane <185 ug/kg 06/20/23 23:58 111-91-106/19/23 11:314461851
bis(2-Chloroethyl) ether <168 ug/kg 06/20/23 23:58 111-44-406/19/23 11:314461681
2-Chloronaphthalene <177 ug/kg 06/20/23 23:58 91-58-706/19/23 11:314461771
2-Chlorophenol <168 ug/kg 06/20/23 23:58 95-57-806/19/23 11:314461681
4-Chlorophenylphenyl ether <166 ug/kg 06/20/23 23:58 7005-72-306/19/23 11:314461661
Chrysene <162 ug/kg 06/20/23 23:58 218-01-906/19/23 11:314461621
Dibenz(a,h)anthracene <172 ug/kg 06/20/23 23:58 53-70-306/19/23 11:314461721
Dibenzofuran <161 ug/kg 06/20/23 23:58 132-64-906/19/23 11:314461611
1,2-Dichlorobenzene <161 ug/kg 06/20/23 23:58 95-50-106/19/23 11:314461611
1,3-Dichlorobenzene <158 ug/kg 06/20/23 23:58 541-73-106/19/23 11:314461581
1,4-Dichlorobenzene <170 ug/kg 06/20/23 23:58 106-46-706/19/23 11:314461701
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-DUP (0-2)Lab ID:92672976006 Collected:06/14/23 00:00 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
3,3'-Dichlorobenzidine <301 ug/kg 06/20/23 23:58 91-94-106/19/23 11:318923011
2,4-Dichlorophenol <174 ug/kg 06/20/23 23:58 120-83-206/19/23 11:314461741
Diethylphthalate <164 ug/kg 06/20/23 23:58 84-66-206/19/23 11:314461641
2,4-Dimethylphenol <185 ug/kg 06/20/23 23:58 105-67-906/19/23 11:314461851
Dimethylphthalate <162 ug/kg 06/20/23 23:58 131-11-306/19/23 11:314461621
Di-n-butylphthalate <150 ug/kg 06/20/23 23:58 84-74-206/19/23 11:314461501
4,6-Dinitro-2-methylphenol <416 ug/kg 06/20/23 23:58 534-52-1 v206/19/23 11:318924161
2,4-Dinitrophenol <1380 ug/kg 06/20/23 23:58 51-28-506/19/23 11:31223013801
2,4-Dinitrotoluene <172 ug/kg 06/20/23 23:58 121-14-206/19/23 11:314461721
2,6-Dinitrotoluene <164 ug/kg 06/20/23 23:58 606-20-206/19/23 11:314461641
Di-n-octylphthalate <176 ug/kg 06/20/23 23:58 117-84-006/19/23 11:314461761
bis(2-Ethylhexyl)phthalate <173 ug/kg 06/20/23 23:58 117-81-706/19/23 11:314461731
Fluoranthene <153 ug/kg 06/20/23 23:58 206-44-006/19/23 11:314461531
Fluorene <157 ug/kg 06/20/23 23:58 86-73-706/19/23 11:314461571
Hexachloro-1,3-butadiene <193 ug/kg 06/20/23 23:58 87-68-306/19/23 11:314461931
Hexachlorobenzene <174 ug/kg 06/20/23 23:58 118-74-106/19/23 11:314461741
Hexachlorocyclopentadiene <256 ug/kg 06/20/23 23:58 77-47-4 v206/19/23 11:314462561
Hexachloroethane <170 ug/kg 06/20/23 23:58 67-72-106/19/23 11:314461701
Indeno(1,2,3-cd)pyrene <176 ug/kg 06/20/23 23:58 193-39-506/19/23 11:314461761
Isophorone <199 ug/kg 06/20/23 23:58 78-59-106/19/23 11:314461991
1-Methylnaphthalene <157 ug/kg 06/20/23 23:58 90-12-006/19/23 11:314461571
2-Methylnaphthalene <178 ug/kg 06/20/23 23:58 91-57-606/19/23 11:314461781
2-Methylphenol(o-Cresol)<183 ug/kg 06/20/23 23:58 95-48-706/19/23 11:314461831
3&4-Methylphenol(m&p Cresol)<180 ug/kg 06/20/23 23:58 15831-10-406/19/23 11:314461801
Naphthalene <151 ug/kg 06/20/23 23:58 91-20-306/19/23 11:314461511
2-Nitroaniline <365 ug/kg 06/20/23 23:58 88-74-406/19/23 11:3122303651
3-Nitroaniline <350 ug/kg 06/20/23 23:58 99-09-206/19/23 11:3122303501
4-Nitroaniline <339 ug/kg 06/20/23 23:58 100-01-606/19/23 11:318923391
Nitrobenzene <207 ug/kg 06/20/23 23:58 98-95-306/19/23 11:314462071
2-Nitrophenol <193 ug/kg 06/20/23 23:58 88-75-506/19/23 11:314461931
4-Nitrophenol <863 ug/kg 06/20/23 23:58 100-02-706/19/23 11:3122308631
N-Nitrosodimethylamine <150 ug/kg 06/20/23 23:58 62-75-906/19/23 11:314461501
N-Nitroso-di-n-propylamine <168 ug/kg 06/20/23 23:58 621-64-706/19/23 11:314461681
N-Nitrosodiphenylamine <158 ug/kg 06/20/23 23:58 86-30-606/19/23 11:314461581
2,2'-Oxybis(1-chloropropane)<212 ug/kg 06/20/23 23:58 108-60-106/19/23 11:314462121
Pentachlorophenol <437 ug/kg 06/20/23 23:58 87-86-506/19/23 11:318924371
Phenanthrene <146 ug/kg 06/20/23 23:58 85-01-806/19/23 11:314461461
Phenol <199 ug/kg 06/20/23 23:58 108-95-206/19/23 11:314461991
Pyrene <181 ug/kg 06/20/23 23:58 129-00-006/19/23 11:314461811
Pyridine <141 ug/kg 06/20/23 23:58 110-86-106/19/23 11:314461411
1,2,4-Trichlorobenzene <176 ug/kg 06/20/23 23:58 120-82-106/19/23 11:314461761
2,4,5-Trichlorophenol <204 ug/kg 06/20/23 23:58 95-95-406/19/23 11:314462041
2,4,6-Trichlorophenol <184 ug/kg 06/20/23 23:58 88-06-206/19/23 11:314461841
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-DUP (0-2)Lab ID:92672976006 Collected:06/14/23 00:00 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Surrogates
Nitrobenzene-d5 (S)59 %06/20/23 23:58 4165-60-006/19/23 11:3110-130 1
2-Fluorobiphenyl (S)53 %06/20/23 23:58 321-60-806/19/23 11:3110-130 1
Terphenyl-d14 (S)84 %06/20/23 23:58 1718-51-006/19/23 11:3110-130 1
Phenol-d6 (S)58 %06/20/23 23:58 13127-88-306/19/23 11:3110-130 1
2-Fluorophenol (S)54 %06/20/23 23:58 367-12-406/19/23 11:3110-130 1
2,4,6-Tribromophenol (S)64 %06/20/23 23:58 118-79-606/19/23 11:3110-131 1
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone <56.0 ug/kg 06/17/23 17:01 67-64-106/16/23 23:1017556.0 1
Benzene <3.5 ug/kg 06/17/23 17:01 71-43-206/16/23 23:108.7 3.5 1
Bromobenzene <2.8 ug/kg 06/17/23 17:01 108-86-106/16/23 23:108.7 2.8 1
Bromochloromethane <2.6 ug/kg 06/17/23 17:01 74-97-506/16/23 23:108.7 2.6 1
Bromodichloromethane <3.4 ug/kg 06/17/23 17:01 75-27-406/16/23 23:108.7 3.4 1
Bromoform <3.1 ug/kg 06/17/23 17:01 75-25-206/16/23 23:108.7 3.1 1
Bromomethane <27.1 ug/kg 06/17/23 17:01 74-83-906/16/23 23:1034.9 27.1 1
2-Butanone (MEK)<41.9 ug/kg 06/17/23 17:01 78-93-306/16/23 23:1017541.9 1
n-Butylbenzene <5.5 ug/kg 06/17/23 17:01 104-51-806/16/23 23:108.7 5.5 1
sec-Butylbenzene <3.8 ug/kg 06/17/23 17:01 135-98-806/16/23 23:108.7 3.8 1
tert-Butylbenzene <3.1 ug/kg 06/17/23 17:01 98-06-606/16/23 23:108.7 3.1 1
Carbon tetrachloride <3.3 ug/kg 06/17/23 17:01 56-23-506/16/23 23:108.7 3.3 1
Chlorobenzene <5.0 ug/kg 06/17/23 17:01 108-90-706/16/23 23:108.7 5.0 1
Chloroethane <6.7 ug/kg 06/17/23 17:01 75-00-3 v106/16/23 23:1017.5 6.7 1
Chloroform <7.3 ug/kg 06/17/23 17:01 67-66-306/16/23 23:108.7 7.3 1
Chloromethane 16.8J ug/kg 06/17/23 17:01 74-87-3 C8,L1,
v106/16/23 23:1017.5 7.3 1
2-Chlorotoluene <3.1 ug/kg 06/17/23 17:01 95-49-806/16/23 23:108.7 3.1 1
4-Chlorotoluene <4.9 ug/kg 06/17/23 17:01 106-43-406/16/23 23:108.7 4.9 1
1,2-Dibromo-3-chloropropane <3.4 ug/kg 06/17/23 17:01 96-12-806/16/23 23:108.7 3.4 1
Dibromochloromethane <4.9 ug/kg 06/17/23 17:01 124-48-106/16/23 23:108.7 4.9 1
1,2-Dibromoethane (EDB)<3.8 ug/kg 06/17/23 17:01 106-93-406/16/23 23:108.7 3.8 1
Dibromomethane <1.9 ug/kg 06/17/23 17:01 74-95-306/16/23 23:108.7 1.9 1
1,2-Dichlorobenzene <3.1 ug/kg 06/17/23 17:01 95-50-106/16/23 23:108.7 3.1 1
1,3-Dichlorobenzene <2.7 ug/kg 06/17/23 17:01 541-73-106/16/23 23:108.7 2.7 1
1,4-Dichlorobenzene <2.3 ug/kg 06/17/23 17:01 106-46-706/16/23 23:108.7 2.3 1
Dichlorodifluoromethane <8.9 ug/kg 06/17/23 17:01 75-71-806/16/23 23:1017.5 8.9 1
1,1-Dichloroethane <3.6 ug/kg 06/17/23 17:01 75-34-306/16/23 23:108.7 3.6 1
1,2-Dichloroethane <5.8 ug/kg 06/17/23 17:01 107-06-206/16/23 23:108.7 5.8 1
1,1-Dichloroethene <3.6 ug/kg 06/17/23 17:01 75-35-406/16/23 23:108.7 3.6 1
cis-1,2-Dichloroethene <3.0 ug/kg 06/17/23 17:01 156-59-206/16/23 23:108.7 3.0 1
trans-1,2-Dichloroethene <7.4 ug/kg 06/17/23 17:01 156-60-506/16/23 23:108.7 7.4 1
1,2-Dichloropropane <2.6 ug/kg 06/17/23 17:01 78-87-506/16/23 23:108.7 2.6 1
1,3-Dichloropropane <2.7 ug/kg 06/17/23 17:01 142-28-906/16/23 23:108.7 2.7 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-DUP (0-2)Lab ID:92672976006 Collected:06/14/23 00:00 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
2,2-Dichloropropane <6.6 ug/kg 06/17/23 17:01 594-20-706/16/23 23:108.7 6.6 1
1,1-Dichloropropene <4.2 ug/kg 06/17/23 17:01 563-58-606/16/23 23:108.7 4.2 1
cis-1,3-Dichloropropene <2.4 ug/kg 06/17/23 17:01 10061-01-506/16/23 23:108.7 2.4 1
trans-1,3-Dichloropropene <3.0 ug/kg 06/17/23 17:01 10061-02-606/16/23 23:108.7 3.0 1
Diisopropyl ether <2.4 ug/kg 06/17/23 17:01 108-20-306/16/23 23:108.7 2.4 1
Ethylbenzene <4.1 ug/kg 06/17/23 17:01 100-41-406/16/23 23:108.7 4.1 1
Hexachloro-1,3-butadiene <14.3 ug/kg 06/17/23 17:01 87-68-306/16/23 23:1017.5 14.3 1
2-Hexanone <8.4 ug/kg 06/17/23 17:01 591-78-6 v106/16/23 23:1087.3 8.4 1
Isopropylbenzene (Cumene)<3.0 ug/kg 06/17/23 17:01 98-82-806/16/23 23:108.7 3.0 1
p-Isopropyltoluene <4.3 ug/kg 06/17/23 17:01 99-87-606/16/23 23:108.7 4.3 1
Methylene Chloride <23.9 ug/kg 06/17/23 17:01 75-09-206/16/23 23:1034.9 23.9 1
4-Methyl-2-pentanone (MIBK)<8.4 ug/kg 06/17/23 17:01 108-10-106/16/23 23:1087.3 8.4 1
Methyl-tert-butyl ether <3.3 ug/kg 06/17/23 17:01 1634-04-406/16/23 23:108.7 3.3 1
Naphthalene <4.6 ug/kg 06/17/23 17:01 91-20-306/16/23 23:108.7 4.6 1
n-Propylbenzene <3.1 ug/kg 06/17/23 17:01 103-65-106/16/23 23:108.7 3.1 1
Styrene <2.3 ug/kg 06/17/23 17:01 100-42-506/16/23 23:108.7 2.3 1
1,1,1,2-Tetrachloroethane <3.4 ug/kg 06/17/23 17:01 630-20-606/16/23 23:108.7 3.4 1
1,1,2,2-Tetrachloroethane <2.3 ug/kg 06/17/23 17:01 79-34-506/16/23 23:108.7 2.3 1
Tetrachloroethene <2.8 ug/kg 06/17/23 17:01 127-18-406/16/23 23:108.7 2.8 1
Toluene <6.0 ug/kg 06/17/23 17:01 108-88-306/16/23 23:108.7 6.0 1
1,2,3-Trichlorobenzene <7.1 ug/kg 06/17/23 17:01 87-61-606/16/23 23:108.7 7.1 1
1,2,4-Trichlorobenzene <7.3 ug/kg 06/17/23 17:01 120-82-106/16/23 23:108.7 7.3 1
1,1,1-Trichloroethane <4.5 ug/kg 06/17/23 17:01 71-55-606/16/23 23:108.7 4.5 1
1,1,2-Trichloroethane <2.9 ug/kg 06/17/23 17:01 79-00-506/16/23 23:108.7 2.9 1
Trichloroethene <7.0 ug/kg 06/17/23 17:01 79-01-606/16/23 23:108.7 7.0 1
Trichlorofluoromethane <4.8 ug/kg 06/17/23 17:01 75-69-406/16/23 23:108.7 4.8 1
1,2,3-Trichloropropane <4.4 ug/kg 06/17/23 17:01 96-18-406/16/23 23:108.7 4.4 1
1,2,4-Trimethylbenzene <5.2 ug/kg 06/17/23 17:01 95-63-606/16/23 23:108.7 5.2 1
1,3,5-Trimethylbenzene <2.9 ug/kg 06/17/23 17:01 108-67-806/16/23 23:108.7 2.9 1
Vinyl acetate <18.0 ug/kg 06/17/23 17:01 108-05-406/16/23 23:1087.3 18.0 1
Vinyl chloride <4.4 ug/kg 06/17/23 17:01 75-01-406/16/23 23:1017.5 4.4 1
Xylene (Total)<5.0 ug/kg 06/17/23 17:01 1330-20-706/16/23 23:1017.5 5.0 1
m&p-Xylene <6.0 ug/kg 06/17/23 17:01 179601-23-106/16/23 23:1017.5 6.0 1
o-Xylene <3.9 ug/kg 06/17/23 17:01 95-47-606/16/23 23:108.7 3.9 1
Surrogates
Toluene-d8 (S)102 %06/17/23 17:01 2037-26-506/16/23 23:1070-130 1
4-Bromofluorobenzene (S)104 %06/17/23 17:01 460-00-406/16/23 23:1070-130 1
1,2-Dichloroethane-d4 (S)106 %06/17/23 17:01 17060-07-006/16/23 23:1070-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 25.3 %06/16/23 15:26 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92672976
TKC.008
Sample:FG-DUP (0-2)Lab ID:92672976006 Collected:06/14/23 00:00 Received:06/15/23 14:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 2540G Preparation Method: SM 2540 G
Pace National - Mt. Juliet
Total Solids 2540 G-2011
Total Solids 83.0 %06/21/23 12:0506/21/23 11:391
Analytical Method: EPA 7199 Preparation Method: 3060A
Pace National - Mt. Juliet
Wet Chemistry 7199
Chromium, Hexavalent 1.40 mg/kg 06/22/23 13:09 18540-29-906/21/23 05:231.20 0.307 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
888922
EPA 7471B
EPA 7471B
7471B Mercury Solids
Laboratory:Pace Analytical Services - Minneapolis
Associated Lab Samples:92672976001, 92672976002, 92672976003, 92672976004, 92672976005, 92672976006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4684186
Associated Lab Samples:92672976001, 92672976002, 92672976003, 92672976004, 92672976005, 92672976006
Matrix:Solid
AnalyzedMDL
Mercury mg/kg <0.0078 0.018 06/27/23 18:320.0078
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4684187LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/kg 0.480.46 105 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4684188MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92672976001
4684189
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury mg/kg 0.541 104 80-120103 4 200.5780.031 0.59 0.62
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
888911
EPA 3050B
EPA 6020B
6020B Solids UPD5
Laboratory:Pace Analytical Services - Minneapolis
Associated Lab Samples:92672976001, 92672976002, 92672976003, 92672976004, 92672976005, 92672976006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4684128
Associated Lab Samples:92672976001, 92672976002, 92672976003, 92672976004, 92672976005, 92672976006
Matrix:Solid
AnalyzedMDL
Arsenic mg/kg <0.14 0.49 06/27/23 15:460.14
Barium mg/kg <0.074 0.30 06/27/23 15:460.074
Cadmium mg/kg <0.029 0.079 06/27/23 15:460.029
Chromium mg/kg <0.38 2.0 06/27/23 15:460.38
Copper mg/kg <0.30 0.98 06/27/23 15:460.30
Lead mg/kg <0.092 0.49 06/27/23 15:460.092
Nickel mg/kg <0.23 0.49 06/27/23 15:460.23
Selenium mg/kg <0.10 0.49 06/27/23 15:460.10
Silver mg/kg <0.20 0.49 06/27/23 15:460.20
Vanadium mg/kg <0.23 0.98 06/27/23 15:460.23
Zinc mg/kg <1.2 4.9 06/27/23 15:461.2
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4684129LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic mg/kg 48.546.9 103 80-120
Barium mg/kg 46.946.9 100 80-120
Cadmium mg/kg 47.946.9 102 80-120
Chromium mg/kg 50.446.9 107 80-120
Copper mg/kg 51.746.9 110 80-120
Lead mg/kg 51.946.9 111 80-120
Nickel mg/kg 49.346.9 105 80-120
Selenium mg/kg 50.446.9 107 80-120
Silver mg/kg 24.823.5 106 80-120
Vanadium mg/kg 48.246.9 103 80-120
Zinc mg/kg 50.046.9 107 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4684130MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92672976001
4684131
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic mg/kg 56.4 92 75-12595 2 2053.72.3 54.3 53.4
Barium mg/kg 56.4 111 75-12582 11 2053.7115 178 159
Cadmium mg/kg 56.4 101 75-125102 4 2053.70.078J 57.0 54.7
Chromium mg/kg P6,R156.4 253 75-12590 50 2053.794.4 237 143
Copper mg/kg 56.4 107 75-125106 4 2053.715.6 75.7 72.5
Lead mg/kg 56.4 104 75-12595 11 2053.715.0 73.6 66.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4684130MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92672976001
4684131
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nickel mg/kg R156.4 123 75-12581 27 2053.741.0 111 84.6
Selenium mg/kg 56.4 94 75-12594 5 2053.70.62 53.8 51.3
Silver mg/kg 28.2 103 75-125104 4 2026.8<0.23 29.2 28.1
Vanadium mg/kg P656.4 70 75-125109 8 2053.7198 237 256
Zinc mg/kg 56.4 108 75-125104 5 2053.732.9 93.6 89.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
781194
EPA 5035A/5030B
EPA 8260D
8260D 5035A 5030B
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92672976006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4053167
Associated Lab Samples:92672976006
Matrix:Solid
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/kg <1.9 5.0 06/17/23 13:011.9
1,1,1-Trichloroethane ug/kg <2.6 5.0 06/17/23 13:012.6
1,1,2,2-Tetrachloroethane ug/kg <1.3 5.0 06/17/23 13:011.3
1,1,2-Trichloroethane ug/kg <1.7 5.0 06/17/23 13:011.7
1,1-Dichloroethane ug/kg <2.1 5.0 06/17/23 13:012.1
1,1-Dichloroethene ug/kg <2.1 5.0 06/17/23 13:012.1
1,1-Dichloropropene ug/kg <2.4 5.0 06/17/23 13:012.4
1,2,3-Trichlorobenzene ug/kg <4.0 5.0 06/17/23 13:014.0
1,2,3-Trichloropropane ug/kg <2.5 5.0 06/17/23 13:012.5
1,2,4-Trichlorobenzene ug/kg <4.2 5.0 06/17/23 13:014.2
1,2,4-Trimethylbenzene ug/kg <3.0 5.0 06/17/23 13:013.0
1,2-Dibromo-3-chloropropane ug/kg <1.9 5.0 06/17/23 13:011.9
1,2-Dibromoethane (EDB)ug/kg <2.2 5.0 06/17/23 13:012.2
1,2-Dichlorobenzene ug/kg <1.8 5.0 06/17/23 13:011.8
1,2-Dichloroethane ug/kg <3.3 5.0 06/17/23 13:013.3
1,2-Dichloropropane ug/kg <1.5 5.0 06/17/23 13:011.5
1,3,5-Trimethylbenzene ug/kg <1.7 5.0 06/17/23 13:011.7
1,3-Dichlorobenzene ug/kg <1.6 5.0 06/17/23 13:011.6
1,3-Dichloropropane ug/kg <1.6 5.0 06/17/23 13:011.6
1,4-Dichlorobenzene ug/kg <1.3 5.0 06/17/23 13:011.3
2,2-Dichloropropane ug/kg <3.8 5.0 06/17/23 13:013.8
2-Butanone (MEK)ug/kg <24.0 100 06/17/23 13:0124.0
2-Chlorotoluene ug/kg <1.8 5.0 06/17/23 13:011.8
2-Hexanone ug/kg <4.8 50.0 v106/17/23 13:014.8
4-Chlorotoluene ug/kg <2.8 5.0 06/17/23 13:012.8
4-Methyl-2-pentanone (MIBK)ug/kg <4.8 50.0 06/17/23 13:014.8
Acetone ug/kg <32.1 100 06/17/23 13:0132.1
Benzene ug/kg <2.0 5.0 06/17/23 13:012.0
Bromobenzene ug/kg <1.6 5.0 06/17/23 13:011.6
Bromochloromethane ug/kg <1.5 5.0 06/17/23 13:011.5
Bromodichloromethane ug/kg <1.9 5.0 06/17/23 13:011.9
Bromoform ug/kg <1.8 5.0 06/17/23 13:011.8
Bromomethane ug/kg <15.5 20.0 06/17/23 13:0115.5
Carbon tetrachloride ug/kg <1.9 5.0 06/17/23 13:011.9
Chlorobenzene ug/kg <2.9 5.0 06/17/23 13:012.9
Chloroethane ug/kg <3.9 10.0 v106/17/23 13:013.9
Chloroform ug/kg <4.2 5.0 06/17/23 13:014.2
Chloromethane ug/kg <4.2 10.0 v106/17/23 13:014.2
cis-1,2-Dichloroethene ug/kg <1.7 5.0 06/17/23 13:011.7
cis-1,3-Dichloropropene ug/kg <1.4 5.0 06/17/23 13:011.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4053167
Associated Lab Samples:92672976006
Matrix:Solid
AnalyzedMDL
Dibromochloromethane ug/kg <2.8 5.0 06/17/23 13:012.8
Dibromomethane ug/kg <1.1 5.0 06/17/23 13:011.1
Dichlorodifluoromethane ug/kg <5.1 10.0 06/17/23 13:015.1
Diisopropyl ether ug/kg <1.4 5.0 06/17/23 13:011.4
Ethylbenzene ug/kg <2.3 5.0 06/17/23 13:012.3
Hexachloro-1,3-butadiene ug/kg <8.2 10.0 06/17/23 13:018.2
Isopropylbenzene (Cumene)ug/kg <1.7 5.0 06/17/23 13:011.7
m&p-Xylene ug/kg <3.4 10.0 06/17/23 13:013.4
Methyl-tert-butyl ether ug/kg <1.9 5.0 06/17/23 13:011.9
Methylene Chloride ug/kg <13.7 20.0 06/17/23 13:0113.7
n-Butylbenzene ug/kg <3.2 5.0 06/17/23 13:013.2
n-Propylbenzene ug/kg <1.8 5.0 06/17/23 13:011.8
Naphthalene ug/kg <2.6 5.0 06/17/23 13:012.6
o-Xylene ug/kg <2.2 5.0 06/17/23 13:012.2
p-Isopropyltoluene ug/kg <2.5 5.0 06/17/23 13:012.5
sec-Butylbenzene ug/kg <2.2 5.0 06/17/23 13:012.2
Styrene ug/kg <1.3 5.0 06/17/23 13:011.3
tert-Butylbenzene ug/kg <1.8 5.0 06/17/23 13:011.8
Tetrachloroethene ug/kg <1.6 5.0 06/17/23 13:011.6
Toluene ug/kg <3.4 5.0 06/17/23 13:013.4
trans-1,2-Dichloroethene ug/kg <4.2 5.0 06/17/23 13:014.2
trans-1,3-Dichloropropene ug/kg <1.7 5.0 06/17/23 13:011.7
Trichloroethene ug/kg <4.0 5.0 06/17/23 13:014.0
Trichlorofluoromethane ug/kg <2.8 5.0 06/17/23 13:012.8
Vinyl acetate ug/kg <10.3 50.0 06/17/23 13:0110.3
Vinyl chloride ug/kg <2.5 10.0 06/17/23 13:012.5
Xylene (Total)ug/kg <2.8 10.0 06/17/23 13:012.8
1,2-Dichloroethane-d4 (S)%116 70-130 06/17/23 13:01
4-Bromofluorobenzene (S)%102 70-130 06/17/23 13:01
Toluene-d8 (S)%104 70-130 06/17/23 13:01
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4053168LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 475500 95 70-130
1,1,1-Trichloroethane ug/kg 496500 99 70-130
1,1,2,2-Tetrachloroethane ug/kg 509500 102 70-130
1,1,2-Trichloroethane ug/kg 470500 94 70-130
1,1-Dichloroethane ug/kg 509500 102 70-130
1,1-Dichloroethene ug/kg 543500 109 70-130
1,1-Dichloropropene ug/kg 515500 103 70-130
1,2,3-Trichlorobenzene ug/kg 470500 94 70-130
1,2,3-Trichloropropane ug/kg 530500 106 70-130
1,2,4-Trichlorobenzene ug/kg 459500 92 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4053168LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/kg 469500 94 70-130
1,2-Dibromo-3-chloropropane ug/kg 450500 90 67-130
1,2-Dibromoethane (EDB)ug/kg 492500 98 70-130
1,2-Dichlorobenzene ug/kg 442500 88 70-130
1,2-Dichloroethane ug/kg 512500 102 70-130
1,2-Dichloropropane ug/kg 504500 101 70-130
1,3,5-Trimethylbenzene ug/kg 476500 95 70-130
1,3-Dichlorobenzene ug/kg 498500 100 70-130
1,3-Dichloropropane ug/kg 496500 99 70-130
1,4-Dichlorobenzene ug/kg 478500 96 70-130
2,2-Dichloropropane ug/kg 443500 89 67-130
2-Butanone (MEK)ug/kg 11601000 116 66-130
2-Chlorotoluene ug/kg 486500 97 70-130
2-Hexanone ug/kg 1220 v1100012270-130
4-Chlorotoluene ug/kg 476500 95 70-130
4-Methyl-2-pentanone (MIBK)ug/kg 11301000 113 70-130
Acetone ug/kg 11601000 116 67-130
Benzene ug/kg 479500 96 70-130
Bromobenzene ug/kg 464500 93 70-130
Bromochloromethane ug/kg 488500 98 70-130
Bromodichloromethane ug/kg 465500 93 70-130
Bromoform ug/kg 476500 95 70-130
Bromomethane ug/kg 428500 86 53-175
Carbon tetrachloride ug/kg 460500 92 70-130
Chlorobenzene ug/kg 480500 96 70-130
Chloroethane ug/kg 622 v150012470-135
Chloroform ug/kg 484500 97 70-130
Chloromethane ug/kg 718 L1,v150014464-130
cis-1,2-Dichloroethene ug/kg 506500 101 70-130
cis-1,3-Dichloropropene ug/kg 475500 95 70-130
Dibromochloromethane ug/kg 467500 93 70-130
Dibromomethane ug/kg 440500 88 70-130
Dichlorodifluoromethane ug/kg 561500 112 63-145
Diisopropyl ether ug/kg 515500 103 68-130
Ethylbenzene ug/kg 447500 89 70-130
Hexachloro-1,3-butadiene ug/kg 407500 81 70-130
Isopropylbenzene (Cumene)ug/kg 485500 97 70-130
m&p-Xylene ug/kg 9571000 96 70-130
Methyl-tert-butyl ether ug/kg 462500 92 70-130
Methylene Chloride ug/kg 580500 116 67-130
n-Butylbenzene ug/kg 454500 91 70-130
n-Propylbenzene ug/kg 474500 95 70-130
Naphthalene ug/kg 499500 100 70-130
o-Xylene ug/kg 492500 98 70-130
p-Isopropyltoluene ug/kg 471500 94 70-130
sec-Butylbenzene ug/kg 470500 94 70-130
Styrene ug/kg 494500 99 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4053168LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butylbenzene ug/kg 506500 101 64-130
Tetrachloroethene ug/kg 469500 94 70-130
Toluene ug/kg 456500 91 70-130
trans-1,2-Dichloroethene ug/kg 516500 103 70-130
trans-1,3-Dichloropropene ug/kg 461500 92 70-130
Trichloroethene ug/kg 458500 92 70-130
Trichlorofluoromethane ug/kg 509500 102 70-130
Vinyl acetate ug/kg 11601000 116 70-134
Vinyl chloride ug/kg 551500 110 68-130
Xylene (Total)ug/kg 14501500 97 70-130
1,2-Dichloroethane-d4 (S)%109 70-130
4-Bromofluorobenzene (S)%104 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4053169MATRIX SPIKE SAMPLE:
MSSpike
Result
92672650019
1,1,1,2-Tetrachloroethane ug/kg 733899 82 58-140ND
1,1,1-Trichloroethane ug/kg 765899 85 58-144ND
1,1,2,2-Tetrachloroethane ug/kg 712899 79 52-139ND
1,1,2-Trichloroethane ug/kg 715899 79 56-140ND
1,1-Dichloroethane ug/kg 740899 82 58-145ND
1,1-Dichloroethene ug/kg 769899 86 57-158ND
1,1-Dichloropropene ug/kg 749899 83 58-151ND
1,2,3-Trichlorobenzene ug/kg 671899 75 48-149ND
1,2,3-Trichloropropane ug/kg 727899 81 54-132ND
1,2,4-Trichlorobenzene ug/kg 642899 71 51-151ND
1,2,4-Trimethylbenzene ug/kg 673899 75 38-170ND
1,2-Dibromo-3-chloropropane ug/kg 625899 69 44-134ND
1,2-Dibromoethane (EDB)ug/kg 717899 80 60-138ND
1,2-Dichlorobenzene ug/kg 657899 73 59-147ND
1,2-Dichloroethane ug/kg 698899 78 57-139ND
1,2-Dichloropropane ug/kg 794899 88 62-145ND
1,3,5-Trimethylbenzene ug/kg 679899 75 47-159ND
1,3-Dichlorobenzene ug/kg 720899 80 58-144ND
1,3-Dichloropropane ug/kg 719899 80 60-142ND
1,4-Dichlorobenzene ug/kg 704899 78 57-143ND
2,2-Dichloropropane ug/kg 642899 71 37-144ND
2-Butanone (MEK)ug/kg 15001800 83 28-146ND
2-Chlorotoluene ug/kg 699899 78 55-158ND
2-Hexanone ug/kg 1530 v118008544-141ND
4-Chlorotoluene ug/kg 675899 75 55-146ND
4-Methyl-2-pentanone (MIBK)ug/kg 15101800 84 50-138ND
Acetone ug/kg 12601800 70 20-136ND
Benzene ug/kg 740899 82 60-145ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4053169MATRIX SPIKE SAMPLE:
MSSpike
Result
92672650019
Bromobenzene ug/kg 698899 78 59-145ND
Bromochloromethane ug/kg 717899 80 57-143ND
Bromodichloromethane ug/kg 706899 78 53-133ND
Bromoform ug/kg 698899 78 48-133ND
Bromomethane ug/kg 151899 17 10-167ND
Carbon tetrachloride ug/kg 715899 79 57-147ND
Chlorobenzene ug/kg 739899 82 61-144ND
Chloroethane ug/kg 219 v18992410-153ND
Chloroform ug/kg 709899 79 58-141ND
Chloromethane ug/kg 1060 v189911854-165ND
cis-1,2-Dichloroethene ug/kg 723899 80 59-144ND
cis-1,3-Dichloropropene ug/kg 714899 79 56-137ND
Dibromochloromethane ug/kg 690899 77 53-139ND
Dibromomethane ug/kg 693899 77 60-136ND
Dichlorodifluoromethane ug/kg 1080899 120 49-177ND
Diisopropyl ether ug/kg 757899 84 53-136ND
Ethylbenzene ug/kg 686899 76 53-150ND
Hexachloro-1,3-butadiene ug/kg 639899 71 42-186ND
Isopropylbenzene (Cumene)ug/kg 751899 83 62-154ND
m&p-Xylene ug/kg 14501800 80 49-156ND
Methyl-tert-butyl ether ug/kg 645899 72 54-133ND
Methylene Chloride ug/kg 805899 86 50-1530.036 mg/kg
n-Butylbenzene ug/kg 604899 67 44-174ND
n-Propylbenzene ug/kg 667899 74 52-157ND
Naphthalene ug/kg 682899 76 37-150ND
o-Xylene ug/kg 763899 85 54-150ND
p-Isopropyltoluene ug/kg 670899 75 50-164ND
sec-Butylbenzene ug/kg 672899 75 58-161ND
Styrene ug/kg 731899 81 60-148ND
tert-Butylbenzene ug/kg 674899 75 44-151ND
Tetrachloroethene ug/kg 676899 75 53-151ND
Toluene ug/kg 711899 79 52-148ND
trans-1,2-Dichloroethene ug/kg 708899 79 60-148ND
trans-1,3-Dichloropropene ug/kg 675899 75 55-133ND
Trichloroethene ug/kg 740899 82 60-148ND
Trichlorofluoromethane ug/kg 216899 24 10-154ND
Vinyl acetate ug/kg 14301800 80 50-149ND
Vinyl chloride ug/kg 920899 102 57-157ND
Xylene (Total)ug/kg 22102690 82 52-153ND
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%104 70-130
Toluene-d8 (S)%101 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92672650020
4053170SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/kg <2.9 30ND
1,1,1-Trichloroethane ug/kg <4.0 30ND
1,1,2,2-Tetrachloroethane ug/kg <2.0 30ND
1,1,2-Trichloroethane ug/kg <2.5 30ND
1,1-Dichloroethane ug/kg <3.1 30ND
1,1-Dichloroethene ug/kg <3.1 30ND
1,1-Dichloropropene ug/kg <3.7 30ND
1,2,3-Trichlorobenzene ug/kg <6.2 30ND
1,2,3-Trichloropropane ug/kg <3.9 30ND
1,2,4-Trichlorobenzene ug/kg <6.4 30ND
1,2,4-Trimethylbenzene ug/kg <4.5 30ND
1,2-Dibromo-3-chloropropane ug/kg <3.0 30ND
1,2-Dibromoethane (EDB)ug/kg <3.4 30ND
1,2-Dichlorobenzene ug/kg <2.7 30ND
1,2-Dichloroethane ug/kg <5.0 30ND
1,2-Dichloropropane ug/kg <2.3 30ND
1,3,5-Trimethylbenzene ug/kg <2.6 30ND
1,3-Dichlorobenzene ug/kg <2.4 30ND
1,3-Dichloropropane ug/kg <2.4 30ND
1,4-Dichlorobenzene ug/kg <2.0 30ND
2,2-Dichloropropane ug/kg <5.8 30ND
2-Butanone (MEK)ug/kg <36.6 30ND
2-Chlorotoluene ug/kg <2.7 30ND
2-Hexanone ug/kg <7.3 v130ND
4-Chlorotoluene ug/kg <4.2 30ND
4-Methyl-2-pentanone (MIBK)ug/kg <7.3 30ND
Acetone ug/kg <48.9 30ND
Benzene ug/kg <3.0 30ND
Bromobenzene ug/kg <2.5 30ND
Bromochloromethane ug/kg <2.3 30ND
Bromodichloromethane ug/kg <2.9 30ND
Bromoform ug/kg <2.7 30ND
Bromomethane ug/kg <23.6 30ND
Carbon tetrachloride ug/kg <2.8 30ND
Chlorobenzene ug/kg <4.4 30ND
Chloroethane ug/kg <5.9 v130ND
Chloroform ug/kg <6.4 30ND
Chloromethane ug/kg <6.4 v130ND
cis-1,2-Dichloroethene ug/kg <2.6 30ND
cis-1,3-Dichloropropene ug/kg <2.1 30ND
Dibromochloromethane ug/kg <4.3 30ND
Dibromomethane ug/kg <1.6 30ND
Dichlorodifluoromethane ug/kg <7.8 30ND
Diisopropyl ether ug/kg <2.1 30ND
Ethylbenzene ug/kg <3.6 30ND
Hexachloro-1,3-butadiene ug/kg <12.5 30ND
Isopropylbenzene (Cumene)ug/kg <2.6 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92672650020
4053170SAMPLE DUPLICATE:
m&p-Xylene ug/kg <5.2 30ND
Methyl-tert-butyl ether ug/kg <2.8 30ND
Methylene Chloride ug/kg <20.9 30ND
n-Butylbenzene ug/kg <4.8 30ND
n-Propylbenzene ug/kg <2.7 30ND
Naphthalene ug/kg <4.0 30ND
o-Xylene ug/kg <3.4 30ND
p-Isopropyltoluene ug/kg <3.7 30ND
sec-Butylbenzene ug/kg <3.4 30ND
Styrene ug/kg <2.0 30ND
tert-Butylbenzene ug/kg <2.7 30ND
Tetrachloroethene ug/kg <2.4 30ND
Toluene ug/kg <5.3 30ND
trans-1,2-Dichloroethene ug/kg <6.5 30ND
trans-1,3-Dichloropropene ug/kg <2.6 30ND
Trichloroethene ug/kg <6.1 30ND
Trichlorofluoromethane ug/kg <4.2 30ND
Vinyl acetate ug/kg <15.7 30ND
Vinyl chloride ug/kg <3.9 30ND
Xylene (Total)ug/kg <4.3 30ND
1,2-Dichloroethane-d4 (S)%109108
4-Bromofluorobenzene (S)%104103
Toluene-d8 (S)%102103
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
781453
EPA 5035A/5030B
EPA 8260D
8260D 5035A 5030B
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92672976001, 92672976002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4054334
Associated Lab Samples:92672976001, 92672976002
Matrix:Solid
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/kg <1.9 5.0 06/19/23 13:181.9
1,1,1-Trichloroethane ug/kg <2.6 5.0 06/19/23 13:182.6
1,1,2,2-Tetrachloroethane ug/kg <1.3 5.0 06/19/23 13:181.3
1,1,2-Trichloroethane ug/kg <1.7 5.0 06/19/23 13:181.7
1,1-Dichloroethane ug/kg <2.1 5.0 06/19/23 13:182.1
1,1-Dichloroethene ug/kg <2.1 5.0 06/19/23 13:182.1
1,1-Dichloropropene ug/kg <2.4 5.0 06/19/23 13:182.4
1,2,3-Trichlorobenzene ug/kg <4.0 5.0 06/19/23 13:184.0
1,2,3-Trichloropropane ug/kg <2.5 5.0 06/19/23 13:182.5
1,2,4-Trichlorobenzene ug/kg <4.2 5.0 06/19/23 13:184.2
1,2,4-Trimethylbenzene ug/kg <3.0 5.0 06/19/23 13:183.0
1,2-Dibromo-3-chloropropane ug/kg <1.9 5.0 06/19/23 13:181.9
1,2-Dibromoethane (EDB)ug/kg <2.2 5.0 06/19/23 13:182.2
1,2-Dichlorobenzene ug/kg <1.8 5.0 06/19/23 13:181.8
1,2-Dichloroethane ug/kg <3.3 5.0 06/19/23 13:183.3
1,2-Dichloropropane ug/kg <1.5 5.0 06/19/23 13:181.5
1,3,5-Trimethylbenzene ug/kg <1.7 5.0 06/19/23 13:181.7
1,3-Dichlorobenzene ug/kg <1.6 5.0 06/19/23 13:181.6
1,3-Dichloropropane ug/kg <1.6 5.0 06/19/23 13:181.6
1,4-Dichlorobenzene ug/kg <1.3 5.0 06/19/23 13:181.3
2,2-Dichloropropane ug/kg <3.8 5.0 06/19/23 13:183.8
2-Butanone (MEK)ug/kg <24.0 100 06/19/23 13:1824.0
2-Chlorotoluene ug/kg <1.8 5.0 06/19/23 13:181.8
2-Hexanone ug/kg <4.8 50.0 06/19/23 13:184.8
4-Chlorotoluene ug/kg <2.8 5.0 06/19/23 13:182.8
4-Methyl-2-pentanone (MIBK)ug/kg <4.8 50.0 06/19/23 13:184.8
Acetone ug/kg <32.1 100 06/19/23 13:1832.1
Benzene ug/kg <2.0 5.0 06/19/23 13:182.0
Bromobenzene ug/kg <1.6 5.0 06/19/23 13:181.6
Bromochloromethane ug/kg <1.5 5.0 06/19/23 13:181.5
Bromodichloromethane ug/kg <1.9 5.0 06/19/23 13:181.9
Bromoform ug/kg <1.8 5.0 06/19/23 13:181.8
Bromomethane ug/kg <15.5 20.0 06/19/23 13:1815.5
Carbon tetrachloride ug/kg <1.9 5.0 06/19/23 13:181.9
Chlorobenzene ug/kg <2.9 5.0 06/19/23 13:182.9
Chloroethane ug/kg <3.9 10.0 v106/19/23 13:183.9
Chloroform ug/kg <4.2 5.0 06/19/23 13:184.2
Chloromethane ug/kg <4.2 10.0 v106/19/23 13:184.2
cis-1,2-Dichloroethene ug/kg <1.7 5.0 06/19/23 13:181.7
cis-1,3-Dichloropropene ug/kg <1.4 5.0 06/19/23 13:181.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4054334
Associated Lab Samples:92672976001, 92672976002
Matrix:Solid
AnalyzedMDL
Dibromochloromethane ug/kg <2.8 5.0 06/19/23 13:182.8
Dibromomethane ug/kg <1.1 5.0 06/19/23 13:181.1
Dichlorodifluoromethane ug/kg <5.1 10.0 06/19/23 13:185.1
Diisopropyl ether ug/kg <1.4 5.0 06/19/23 13:181.4
Ethylbenzene ug/kg <2.3 5.0 06/19/23 13:182.3
Hexachloro-1,3-butadiene ug/kg <8.2 10.0 06/19/23 13:188.2
Isopropylbenzene (Cumene)ug/kg <1.7 5.0 06/19/23 13:181.7
m&p-Xylene ug/kg <3.4 10.0 06/19/23 13:183.4
Methyl-tert-butyl ether ug/kg <1.9 5.0 06/19/23 13:181.9
Methylene Chloride ug/kg <13.7 20.0 06/19/23 13:1813.7
n-Butylbenzene ug/kg <3.2 5.0 06/19/23 13:183.2
n-Propylbenzene ug/kg <1.8 5.0 06/19/23 13:181.8
Naphthalene ug/kg <2.6 5.0 06/19/23 13:182.6
o-Xylene ug/kg <2.2 5.0 06/19/23 13:182.2
p-Isopropyltoluene ug/kg <2.5 5.0 06/19/23 13:182.5
sec-Butylbenzene ug/kg <2.2 5.0 06/19/23 13:182.2
Styrene ug/kg <1.3 5.0 06/19/23 13:181.3
tert-Butylbenzene ug/kg <1.8 5.0 06/19/23 13:181.8
Tetrachloroethene ug/kg <1.6 5.0 06/19/23 13:181.6
Toluene ug/kg <3.4 5.0 06/19/23 13:183.4
trans-1,2-Dichloroethene ug/kg <4.2 5.0 06/19/23 13:184.2
trans-1,3-Dichloropropene ug/kg <1.7 5.0 06/19/23 13:181.7
Trichloroethene ug/kg <4.0 5.0 06/19/23 13:184.0
Trichlorofluoromethane ug/kg <2.8 5.0 06/19/23 13:182.8
Vinyl acetate ug/kg <10.3 50.0 06/19/23 13:1810.3
Vinyl chloride ug/kg <2.5 10.0 v106/19/23 13:182.5
Xylene (Total)ug/kg <2.8 10.0 06/19/23 13:182.8
1,2-Dichloroethane-d4 (S)%106 70-130 06/19/23 13:18
4-Bromofluorobenzene (S)%103 70-130 06/19/23 13:18
Toluene-d8 (S)%102 70-130 06/19/23 13:18
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4054335LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 486500 97 70-130
1,1,1-Trichloroethane ug/kg 464500 93 70-130
1,1,2,2-Tetrachloroethane ug/kg 477500 95 70-130
1,1,2-Trichloroethane ug/kg 451500 90 70-130
1,1-Dichloroethane ug/kg 463500 93 70-130
1,1-Dichloroethene ug/kg 483500 97 70-130
1,1-Dichloropropene ug/kg 496500 99 70-130
1,2,3-Trichlorobenzene ug/kg 491500 98 70-130
1,2,3-Trichloropropane ug/kg 505500 101 70-130
1,2,4-Trichlorobenzene ug/kg 492500 98 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 48 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4054335LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/kg 492500 98 70-130
1,2-Dibromo-3-chloropropane ug/kg 428500 86 67-130
1,2-Dibromoethane (EDB)ug/kg 481500 96 70-130
1,2-Dichlorobenzene ug/kg 451500 90 70-130
1,2-Dichloroethane ug/kg 445500 89 70-130
1,2-Dichloropropane ug/kg 493500 99 70-130
1,3,5-Trimethylbenzene ug/kg 490500 98 70-130
1,3-Dichlorobenzene ug/kg 495500 99 70-130
1,3-Dichloropropane ug/kg 478500 96 70-130
1,4-Dichlorobenzene ug/kg 516500 103 70-130
2,2-Dichloropropane ug/kg 456500 91 67-130
2-Butanone (MEK)ug/kg 9931000 99 66-130
2-Chlorotoluene ug/kg 492500 98 70-130
2-Hexanone ug/kg 10701000 107 70-130
4-Chlorotoluene ug/kg 492500 98 70-130
4-Methyl-2-pentanone (MIBK)ug/kg 10201000 102 70-130
Acetone ug/kg 9141000 91 67-130
Benzene ug/kg 460500 92 70-130
Bromobenzene ug/kg 473500 95 70-130
Bromochloromethane ug/kg 462500 92 70-130
Bromodichloromethane ug/kg 450500 90 70-130
Bromoform ug/kg 494500 99 70-130
Bromomethane ug/kg 399500 80 53-175
Carbon tetrachloride ug/kg 485500 97 70-130
Chlorobenzene ug/kg 490500 98 70-130
Chloroethane ug/kg 641 v150012870-135
Chloroform ug/kg 443500 89 70-130
Chloromethane ug/kg 647 v150012964-130
cis-1,2-Dichloroethene ug/kg 459500 92 70-130
cis-1,3-Dichloropropene ug/kg 466500 93 70-130
Dibromochloromethane ug/kg 470500 94 70-130
Dibromomethane ug/kg 446500 89 70-130
Dichlorodifluoromethane ug/kg 644500 129 63-145
Diisopropyl ether ug/kg 469500 94 68-130
Ethylbenzene ug/kg 460500 92 70-130
Hexachloro-1,3-butadiene ug/kg 476500 95 70-130
Isopropylbenzene (Cumene)ug/kg 511500 102 70-130
m&p-Xylene ug/kg 10001000 100 70-130
Methyl-tert-butyl ether ug/kg 407500 81 70-130
Methylene Chloride ug/kg 492500 98 67-130
n-Butylbenzene ug/kg 475500 95 70-130
n-Propylbenzene ug/kg 482500 96 70-130
Naphthalene ug/kg 480500 96 70-130
o-Xylene ug/kg 510500 102 70-130
p-Isopropyltoluene ug/kg 498500 100 70-130
sec-Butylbenzene ug/kg 486500 97 70-130
Styrene ug/kg 509500 102 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 49 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4054335LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butylbenzene ug/kg 507500 101 64-130
Tetrachloroethene ug/kg 505500 101 70-130
Toluene ug/kg 453500 91 70-130
trans-1,2-Dichloroethene ug/kg 475500 95 70-130
trans-1,3-Dichloropropene ug/kg 461500 92 70-130
Trichloroethene ug/kg 476500 95 70-130
Trichlorofluoromethane ug/kg 576500 115 70-130
Vinyl acetate ug/kg 10501000 105 70-134
Vinyl chloride ug/kg 580 v150011668-130
Xylene (Total)ug/kg 15101500 101 70-130
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%105 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4054336MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92671835003
4054337
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/kg 6510 113 58-140105 7 306510ND73606830
1,1,1-Trichloroethane ug/kg 6510 110 58-144101 9 306510ND71506570
1,1,2,2-Tetrachloroethane ug/kg 6510 98 52-13979 21 306510ND63805150
1,1,2-Trichloroethane ug/kg 6510 111 56-140107 3 306510ND72206990
1,1-Dichloroethane ug/kg 6510 108 58-145103 5 306510ND70306710
1,1-Dichloroethene ug/kg 6510 114 57-158103 10 306510ND73806690
1,1-Dichloropropene ug/kg 6510 117 58-151106 10 306510ND76006890
1,2,3-Trichlorobenzene ug/kg 6510 119 48-149119 0 306510ND77407730
1,2,3-Trichloropropane ug/kg 6510 126 54-132123 2 306510ND82008030
1,2,4-Trichlorobenzene ug/kg 6510 116 51-151116 0 306510ND75607570
1,2,4-Trimethylbenzene ug/kg 6510 108 38-170106 1 30651028772807200
1,2-Dibromo-3-
chloropropane ug/kg 6510 108 44-134108 1 306510ND70407000
1,2-Dibromoethane (EDB)ug/kg 6510 115 60-138107 7 306510ND75006970
1,2-Dichlorobenzene ug/kg 6510 105 59-147105 0 306510ND68106840
1,2-Dichloroethane ug/kg 6510 112 57-139108 4 306510ND72707000
1,2-Dichloropropane ug/kg 6510 116 62-145107 9 306510ND75706950
1,3,5-Trimethylbenzene ug/kg 6510 107 47-159103 4 306510132J70806810
1,3-Dichlorobenzene ug/kg 6510 116 58-144113 2 306510ND75307370
1,3-Dichloropropane ug/kg 6510 116 60-142108 7 306510ND75207020
1,4-Dichlorobenzene ug/kg 6510 119 57-143109 9 306510ND77407080
2,2-Dichloropropane ug/kg 6510 107 37-144100 7 306510ND69406500
2-Butanone (MEK)ug/kg 13000 141 28-146136 4 3013000ND1830017700
2-Chlorotoluene ug/kg 6510 108 55-158104 4 306510ND70106770
2-Hexanone ug/kg 13000 138 44-141128 7 3013000ND1790016600
4-Chlorotoluene ug/kg 6510 108 55-146104 4 306510ND70206780
4-Methyl-2-pentanone
(MIBK)ug/kg 13000 131 50-138124 5 3013000ND1700016200
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 50 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4054336MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92671835003
4054337
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Acetone ug/kg 13000 122 20-136113 7 30130002370J1820017100
Benzene ug/kg 6510 106 60-145100 6 306510ND69106530
Bromobenzene ug/kg 6510 107 59-145103 4 306510ND69706700
Bromochloromethane ug/kg 6510 113 57-143110 3 306510ND73807140
Bromodichloromethane ug/kg 6510 107 53-133101 6 306510ND69906560
Bromoform ug/kg 6510 119 48-133112 6 306510ND77307270
Bromomethane ug/kg 6510 33 10-16727 18 306510ND21401790
Carbon tetrachloride ug/kg 6510 109 57-147101 8 306510ND71106550
Chlorobenzene ug/kg 6510 114 61-144103 10 306510ND74006690
Chloroethane ug/kg v165105710-15358 1 306510ND37003750
Chloroform ug/kg 6510 106 58-141101 5 306510ND68706550
Chloromethane ug/kg v1651015054-165143 5 306510ND97409310
cis-1,2-Dichloroethene ug/kg 6510 110 59-144102 7 306510ND71506660
cis-1,3-Dichloropropene ug/kg 6510 113 56-137106 7 306510ND73706870
Dibromochloromethane ug/kg 6510 110 53-139102 7 306510ND71606650
Dibromomethane ug/kg 6510 109 60-136105 3 306510ND70706830
Dichlorodifluoromethane ug/kg 6510 165 49-177144 14 306510ND107009340
Diisopropyl ether ug/kg 6510 114 53-136104 9 306510ND74406800
Ethylbenzene ug/kg 6510 105 53-15097 8 306510ND68406300
Hexachloro-1,3-butadiene ug/kg 6510 119 42-186113 6 306510ND77507320
Isopropylbenzene
(Cumene)ug/kg 6510 117 62-154107 9 306510ND75906970
m&p-Xylene ug/kg 13000 114 49-156105 8 3013000133J1490013700
Methyl-tert-butyl ether ug/kg 6510 102 54-13397 6 306510ND66406280
Methylene Chloride ug/kg 6510 122 50-153117 3 306510126091808870
n-Butylbenzene ug/kg 6510 108 44-174104 4 30651020372606960
n-Propylbenzene ug/kg 6510 105 52-157102 3 306510ND68206640
Naphthalene ug/kg 6510 117 37-150117 0 306510127J77107750
o-Xylene ug/kg 6510 117 54-150108 8 306510ND76207040
p-Isopropyltoluene ug/kg 6510 108 50-164106 2 30651018372007060
sec-Butylbenzene ug/kg 6510 107 58-161103 4 306510ND69506690
Styrene ug/kg 6510 117 60-148107 8 306510ND75806980
tert-Butylbenzene ug/kg 6510 99 44-15196 3 306510ND64206220
Tetrachloroethene ug/kg 6510 110 53-15199 11 306510ND71706440
Toluene ug/kg 6510 104 52-14897 7 306510115J68806420
trans-1,2-Dichloroethene ug/kg 6510 108 60-148103 5 306510ND70506690
trans-1,3-Dichloropropene ug/kg 6510 109 55-133103 5 306510ND70906720
Trichloroethene ug/kg E,M1651044960-148381 3 306510150000179000175000
Trichlorofluoromethane ug/kg 6510 129 10-154122 5 306510ND83607950
Vinyl acetate ug/kg M1,R1130002050-14914 34 3013000ND26101860
Vinyl chloride ug/kg v1651013157-157121 8 306510ND85307890
Xylene (Total)ug/kg 19500 115 52-153106 8 3019500133J2250020800
1,2-Dichloroethane-d4 (S)%99 70-13098
4-Bromofluorobenzene (S)%107 70-130104
Toluene-d8 (S)%100 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 51 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
781504
EPA 5035A/5030B
EPA 8260D
8260D 5035A 5030B
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92672976003, 92672976004, 92672976005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4054590
Associated Lab Samples:92672976003, 92672976004, 92672976005
Matrix:Solid
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/kg <1.9 5.0 06/19/23 13:371.9
1,1,1-Trichloroethane ug/kg <2.6 5.0 06/19/23 13:372.6
1,1,2,2-Tetrachloroethane ug/kg <1.3 5.0 06/19/23 13:371.3
1,1,2-Trichloroethane ug/kg <1.7 5.0 06/19/23 13:371.7
1,1-Dichloroethane ug/kg <2.1 5.0 06/19/23 13:372.1
1,1-Dichloroethene ug/kg <2.1 5.0 06/19/23 13:372.1
1,1-Dichloropropene ug/kg <2.4 5.0 06/19/23 13:372.4
1,2,3-Trichlorobenzene ug/kg <4.0 5.0 06/19/23 13:374.0
1,2,3-Trichloropropane ug/kg <2.5 5.0 06/19/23 13:372.5
1,2,4-Trichlorobenzene ug/kg <4.2 5.0 06/19/23 13:374.2
1,2,4-Trimethylbenzene ug/kg <3.0 5.0 06/19/23 13:373.0
1,2-Dibromo-3-chloropropane ug/kg <1.9 5.0 06/19/23 13:371.9
1,2-Dibromoethane (EDB)ug/kg <2.2 5.0 06/19/23 13:372.2
1,2-Dichlorobenzene ug/kg <1.8 5.0 06/19/23 13:371.8
1,2-Dichloroethane ug/kg <3.3 5.0 06/19/23 13:373.3
1,2-Dichloropropane ug/kg <1.5 5.0 06/19/23 13:371.5
1,3,5-Trimethylbenzene ug/kg <1.7 5.0 06/19/23 13:371.7
1,3-Dichlorobenzene ug/kg <1.6 5.0 06/19/23 13:371.6
1,3-Dichloropropane ug/kg <1.6 5.0 06/19/23 13:371.6
1,4-Dichlorobenzene ug/kg <1.3 5.0 06/19/23 13:371.3
2,2-Dichloropropane ug/kg <3.8 5.0 06/19/23 13:373.8
2-Butanone (MEK)ug/kg <24.0 100 06/19/23 13:3724.0
2-Chlorotoluene ug/kg <1.8 5.0 06/19/23 13:371.8
2-Hexanone ug/kg <4.8 50.0 06/19/23 13:374.8
4-Chlorotoluene ug/kg <2.8 5.0 06/19/23 13:372.8
4-Methyl-2-pentanone (MIBK)ug/kg <4.8 50.0 06/19/23 13:374.8
Acetone ug/kg <32.1 100 06/19/23 13:3732.1
Benzene ug/kg <2.0 5.0 06/19/23 13:372.0
Bromobenzene ug/kg <1.6 5.0 06/19/23 13:371.6
Bromochloromethane ug/kg <1.5 5.0 06/19/23 13:371.5
Bromodichloromethane ug/kg <1.9 5.0 06/19/23 13:371.9
Bromoform ug/kg <1.8 5.0 06/19/23 13:371.8
Bromomethane ug/kg <15.5 20.0 06/19/23 13:3715.5
Carbon tetrachloride ug/kg <1.9 5.0 06/19/23 13:371.9
Chlorobenzene ug/kg <2.9 5.0 06/19/23 13:372.9
Chloroethane ug/kg <3.9 10.0 v106/19/23 13:373.9
Chloroform ug/kg <4.2 5.0 06/19/23 13:374.2
Chloromethane ug/kg <4.2 10.0 v106/19/23 13:374.2
cis-1,2-Dichloroethene ug/kg <1.7 5.0 06/19/23 13:371.7
cis-1,3-Dichloropropene ug/kg <1.4 5.0 06/19/23 13:371.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 52 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4054590
Associated Lab Samples:92672976003, 92672976004, 92672976005
Matrix:Solid
AnalyzedMDL
Dibromochloromethane ug/kg <2.8 5.0 06/19/23 13:372.8
Dibromomethane ug/kg <1.1 5.0 06/19/23 13:371.1
Dichlorodifluoromethane ug/kg <5.1 10.0 06/19/23 13:375.1
Diisopropyl ether ug/kg <1.4 5.0 06/19/23 13:371.4
Ethylbenzene ug/kg <2.3 5.0 06/19/23 13:372.3
Hexachloro-1,3-butadiene ug/kg <8.2 10.0 06/19/23 13:378.2
Isopropylbenzene (Cumene)ug/kg <1.7 5.0 06/19/23 13:371.7
m&p-Xylene ug/kg <3.4 10.0 06/19/23 13:373.4
Methyl-tert-butyl ether ug/kg <1.9 5.0 06/19/23 13:371.9
Methylene Chloride ug/kg <13.7 20.0 06/19/23 13:3713.7
n-Butylbenzene ug/kg <3.2 5.0 06/19/23 13:373.2
n-Propylbenzene ug/kg <1.8 5.0 06/19/23 13:371.8
Naphthalene ug/kg <2.6 5.0 06/19/23 13:372.6
o-Xylene ug/kg <2.2 5.0 06/19/23 13:372.2
p-Isopropyltoluene ug/kg <2.5 5.0 06/19/23 13:372.5
sec-Butylbenzene ug/kg <2.2 5.0 06/19/23 13:372.2
Styrene ug/kg <1.3 5.0 06/19/23 13:371.3
tert-Butylbenzene ug/kg <1.8 5.0 06/19/23 13:371.8
Tetrachloroethene ug/kg <1.6 5.0 06/19/23 13:371.6
Toluene ug/kg <3.4 5.0 06/19/23 13:373.4
trans-1,2-Dichloroethene ug/kg <4.2 5.0 06/19/23 13:374.2
trans-1,3-Dichloropropene ug/kg <1.7 5.0 06/19/23 13:371.7
Trichloroethene ug/kg <4.0 5.0 06/19/23 13:374.0
Trichlorofluoromethane ug/kg <2.8 5.0 06/19/23 13:372.8
Vinyl acetate ug/kg <10.3 50.0 06/19/23 13:3710.3
Vinyl chloride ug/kg <2.5 10.0 v106/19/23 13:372.5
Xylene (Total)ug/kg <2.8 10.0 06/19/23 13:372.8
1,2-Dichloroethane-d4 (S)%106 70-130 06/19/23 13:37
4-Bromofluorobenzene (S)%102 70-130 06/19/23 13:37
Toluene-d8 (S)%102 70-130 06/19/23 13:37
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4054591LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 487500 97 70-130
1,1,1-Trichloroethane ug/kg 473500 95 70-130
1,1,2,2-Tetrachloroethane ug/kg 488500 98 70-130
1,1,2-Trichloroethane ug/kg 458500 92 70-130
1,1-Dichloroethane ug/kg 472500 94 70-130
1,1-Dichloroethene ug/kg 496500 99 70-130
1,1-Dichloropropene ug/kg 496500 99 70-130
1,2,3-Trichlorobenzene ug/kg 494500 99 70-130
1,2,3-Trichloropropane ug/kg 518500 104 70-130
1,2,4-Trichlorobenzene ug/kg 497500 99 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 53 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4054591LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/kg 488500 98 70-130
1,2-Dibromo-3-chloropropane ug/kg 437500 87 67-130
1,2-Dibromoethane (EDB)ug/kg 487500 97 70-130
1,2-Dichlorobenzene ug/kg 454500 91 70-130
1,2-Dichloroethane ug/kg 448500 90 70-130
1,2-Dichloropropane ug/kg 496500 99 70-130
1,3,5-Trimethylbenzene ug/kg 486500 97 70-130
1,3-Dichlorobenzene ug/kg 507500 101 70-130
1,3-Dichloropropane ug/kg 485500 97 70-130
1,4-Dichlorobenzene ug/kg 503500 101 70-130
2,2-Dichloropropane ug/kg 470500 94 67-130
2-Butanone (MEK)ug/kg 10301000 103 66-130
2-Chlorotoluene ug/kg 494500 99 70-130
2-Hexanone ug/kg 11001000 110 70-130
4-Chlorotoluene ug/kg 489500 98 70-130
4-Methyl-2-pentanone (MIBK)ug/kg 10601000 106 70-130
Acetone ug/kg 9591000 96 67-130
Benzene ug/kg 471500 94 70-130
Bromobenzene ug/kg 478500 96 70-130
Bromochloromethane ug/kg 475500 95 70-130
Bromodichloromethane ug/kg 463500 93 70-130
Bromoform ug/kg 489500 98 70-130
Bromomethane ug/kg 420500 84 53-175
Carbon tetrachloride ug/kg 490500 98 70-130
Chlorobenzene ug/kg 493500 99 70-130
Chloroethane ug/kg 645 v150012970-135
Chloroform ug/kg 450500 90 70-130
Chloromethane ug/kg 648 v150013064-130
cis-1,2-Dichloroethene ug/kg 466500 93 70-130
cis-1,3-Dichloropropene ug/kg 481500 96 70-130
Dibromochloromethane ug/kg 480500 96 70-130
Dibromomethane ug/kg 466500 93 70-130
Dichlorodifluoromethane ug/kg 674500 135 63-145
Diisopropyl ether ug/kg 476500 95 68-130
Ethylbenzene ug/kg 463500 93 70-130
Hexachloro-1,3-butadiene ug/kg 479500 96 70-130
Isopropylbenzene (Cumene)ug/kg 514500 103 70-130
m&p-Xylene ug/kg 10101000 101 70-130
Methyl-tert-butyl ether ug/kg 416500 83 70-130
Methylene Chloride ug/kg 505500 101 67-130
n-Butylbenzene ug/kg 480500 96 70-130
n-Propylbenzene ug/kg 489500 98 70-130
Naphthalene ug/kg 481500 96 70-130
o-Xylene ug/kg 518500 104 70-130
p-Isopropyltoluene ug/kg 506500 101 70-130
sec-Butylbenzene ug/kg 484500 97 70-130
Styrene ug/kg 512500 102 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 54 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4054591LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butylbenzene ug/kg 513500 103 64-130
Tetrachloroethene ug/kg 509500 102 70-130
Toluene ug/kg 466500 93 70-130
trans-1,2-Dichloroethene ug/kg 481500 96 70-130
trans-1,3-Dichloropropene ug/kg 466500 93 70-130
Trichloroethene ug/kg 484500 97 70-130
Trichlorofluoromethane ug/kg 592500 118 70-130
Vinyl acetate ug/kg 10501000 105 70-134
Vinyl chloride ug/kg 587 v150011768-130
Xylene (Total)ug/kg 15301500 102 70-130
1,2-Dichloroethane-d4 (S)%96 70-130
4-Bromofluorobenzene (S)%106 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4054593MATRIX SPIKE SAMPLE:
MSSpike
Result
92672976004
1,1,1,2-Tetrachloroethane ug/kg 528669 79 58-140<2.6
1,1,1-Trichloroethane ug/kg 536669 80 58-144<3.5
1,1,2,2-Tetrachloroethane ug/kg 540669 81 52-139<1.8
1,1,2-Trichloroethane ug/kg 530669 79 56-140<2.2
1,1-Dichloroethane ug/kg 547669 82 58-145<2.8
1,1-Dichloroethene ug/kg 521669 78 57-158<2.8
1,1-Dichloropropene ug/kg 542669 81 58-151<3.2
1,2,3-Trichlorobenzene ug/kg 522669 78 48-149<5.4
1,2,3-Trichloropropane ug/kg 513 IK6697754-132<3.4
1,2,4-Trichlorobenzene ug/kg 448669 67 51-151<5.6
1,2,4-Trimethylbenzene ug/kg 522669 78 38-170<4.0
1,2-Dibromo-3-chloropropane ug/kg 435669 65 44-134<2.6
1,2-Dibromoethane (EDB)ug/kg 521669 78 60-138<2.9
1,2-Dichlorobenzene ug/kg 547669 82 59-147<2.4
1,2-Dichloroethane ug/kg 518669 77 57-139<4.4
1,2-Dichloropropane ug/kg 536669 80 62-145<2.0
1,3,5-Trimethylbenzene ug/kg 519669 78 47-159<2.2
1,3-Dichlorobenzene ug/kg 492669 73 58-144<2.1
1,3-Dichloropropane ug/kg 514669 77 60-142<2.1
1,4-Dichlorobenzene ug/kg 499669 75 57-143<1.7
2,2-Dichloropropane ug/kg 483669 72 37-144<5.1
2-Butanone (MEK)ug/kg 9371340 70 28-146<32.1
2-Chlorotoluene ug/kg 510669 76 55-158<2.4
2-Hexanone ug/kg 9641340 72 44-141<6.5
4-Chlorotoluene ug/kg 525669 78 55-146<3.7
4-Methyl-2-pentanone (MIBK)ug/kg 10101340 76 50-138<6.5
Acetone ug/kg 8811340 64 20-136<43.0
Benzene ug/kg 569669 85 60-145<2.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 55 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4054593MATRIX SPIKE SAMPLE:
MSSpike
Result
92672976004
Bromobenzene ug/kg 510669 76 59-145<2.2
Bromochloromethane ug/kg 555669 83 57-143<2.0
Bromodichloromethane ug/kg 520669 78 53-133<2.6
Bromoform ug/kg 510669 76 48-133<2.4
Bromomethane ug/kg 418669 62 10-167<20.7
Carbon tetrachloride ug/kg 517669 77 57-147<2.5
Chlorobenzene ug/kg 512669 76 61-144<3.8
Chloroethane ug/kg 216669 32 10-153<5.2
Chloroform ug/kg 555669 83 58-141<5.6
Chloromethane ug/kg 604669 90 54-165<5.6
cis-1,2-Dichloroethene ug/kg 556669 83 59-144<2.3
cis-1,3-Dichloropropene ug/kg 538669 80 56-137<1.8
Dibromochloromethane ug/kg 509669 76 53-139<3.8
Dibromomethane ug/kg 517669 77 60-136<1.4
Dichlorodifluoromethane ug/kg 695 IH,v166910449-177<6.8
Diisopropyl ether ug/kg 495669 74 53-136<1.8
Ethylbenzene ug/kg 541669 81 53-150<3.1
Hexachloro-1,3-butadiene ug/kg 498669 74 42-186<10.9
Isopropylbenzene (Cumene)ug/kg 541669 81 62-154<2.3
m&p-Xylene ug/kg 9821340 73 49-156<4.6
Methyl-tert-butyl ether ug/kg 469669 70 54-133<2.5
Methylene Chloride ug/kg 509 IK,v36697650-153<18.3
n-Butylbenzene ug/kg 475669 71 44-174<4.2
n-Propylbenzene ug/kg 498669 74 52-157<2.4
Naphthalene ug/kg 486669 73 37-150<3.5
o-Xylene ug/kg 507669 76 54-150<3.0
p-Isopropyltoluene ug/kg 507669 75 50-1647.6
sec-Butylbenzene ug/kg 509669 76 58-161<2.9
Styrene ug/kg 532669 80 60-148<1.8
tert-Butylbenzene ug/kg 515669 77 44-151<2.4
Tetrachloroethene ug/kg 455669 68 53-151<2.1
Toluene ug/kg 504669 75 52-148<4.6
trans-1,2-Dichloroethene ug/kg 540669 81 60-148<5.7
trans-1,3-Dichloropropene ug/kg 509669 76 55-133<2.3
Trichloroethene ug/kg 539669 81 60-148<5.4
Trichlorofluoromethane ug/kg 212669 32 10-154<3.7
Vinyl acetate ug/kg 8831340 66 50-149<13.8
Vinyl chloride ug/kg 568669 85 57-157<3.4
Xylene (Total)ug/kg 14902010 74 52-153<3.8
1,2-Dichloroethane-d4 (S)%96 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 56 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92672976003
4054592SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/kg <2.4 30<2.4
1,1,1-Trichloroethane ug/kg <3.3 30<3.3
1,1,2,2-Tetrachloroethane ug/kg <1.7 30<1.7
1,1,2-Trichloroethane ug/kg <2.1 30<2.1
1,1-Dichloroethane ug/kg <2.6 30<2.6
1,1-Dichloroethene ug/kg <2.6 30<2.6
1,1-Dichloropropene ug/kg <3.0 30<3.0
1,2,3-Trichlorobenzene ug/kg <5.1 30<5.1
1,2,3-Trichloropropane ug/kg <3.2 30<3.2
1,2,4-Trichlorobenzene ug/kg <5.3 30<5.3
1,2,4-Trimethylbenzene ug/kg <3.8 30<3.8
1,2-Dibromo-3-chloropropane ug/kg <2.5 30<2.5
1,2-Dibromoethane (EDB)ug/kg <2.8 30<2.8
1,2-Dichlorobenzene ug/kg <2.3 30<2.3
1,2-Dichloroethane ug/kg <4.2 30<4.2
1,2-Dichloropropane ug/kg <1.9 30<1.9
1,3,5-Trimethylbenzene ug/kg <2.1 30<2.1
1,3-Dichlorobenzene ug/kg <2.0 30<2.0
1,3-Dichloropropane ug/kg <2.0 30<2.0
1,4-Dichlorobenzene ug/kg <1.6 30<1.6
2,2-Dichloropropane ug/kg <4.8 30<4.8
2-Butanone (MEK)ug/kg 35.5J 3036.9J
2-Chlorotoluene ug/kg <2.2 30<2.2
2-Hexanone ug/kg <6.1 30<6.1
4-Chlorotoluene ug/kg <3.5 30<3.5
4-Methyl-2-pentanone (MIBK)ug/kg <6.1 30<6.1
Acetone ug/kg 99.2J 30119J
Benzene ug/kg <2.5 30<2.5
Bromobenzene ug/kg <2.1 30<2.1
Bromochloromethane ug/kg <1.9 30<1.9
Bromodichloromethane ug/kg <2.4 30<2.4
Bromoform ug/kg <2.2 30<2.2
Bromomethane ug/kg <19.6 30<19.6
Carbon tetrachloride ug/kg <2.4 30<2.4
Chlorobenzene ug/kg <3.6 30<3.6
Chloroethane ug/kg <4.9 v130<4.9
Chloroform ug/kg <5.3 30<5.3
Chloromethane ug/kg <5.3 v130<5.3
cis-1,2-Dichloroethene ug/kg <2.2 30<2.2
cis-1,3-Dichloropropene ug/kg <1.7 30<1.7
Dibromochloromethane ug/kg <3.6 30<3.6
Dibromomethane ug/kg <1.4 30<1.4
Dichlorodifluoromethane ug/kg <6.4 30<6.4
Diisopropyl ether ug/kg <1.7 30<1.7
Ethylbenzene ug/kg <3.0 30<3.0
Hexachloro-1,3-butadiene ug/kg <10.4 30<10.4
Isopropylbenzene (Cumene)ug/kg <2.2 30<2.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 57 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92672976003
4054592SAMPLE DUPLICATE:
m&p-Xylene ug/kg <4.3 30<4.3
Methyl-tert-butyl ether ug/kg <2.4 30<2.4
Methylene Chloride ug/kg <17.4 30<17.4
n-Butylbenzene ug/kg <4.0 30<4.0
n-Propylbenzene ug/kg <2.3 30<2.3
Naphthalene ug/kg <3.3 30<3.3
o-Xylene ug/kg <2.8 30<2.8
p-Isopropyltoluene ug/kg 433 1 30437
sec-Butylbenzene ug/kg <2.8 30<2.8
Styrene ug/kg <1.7 30<1.7
tert-Butylbenzene ug/kg <2.3 30<2.3
Tetrachloroethene ug/kg <2.0 30<2.0
Toluene ug/kg <4.4 30<4.4
trans-1,2-Dichloroethene ug/kg <5.4 30<5.4
trans-1,3-Dichloropropene ug/kg <2.2 30<2.2
Trichloroethene ug/kg <5.1 30<5.1
Trichlorofluoromethane ug/kg <3.5 30<3.5
Vinyl acetate ug/kg <13.0 30<13.0
Vinyl chloride ug/kg <3.2 v130<3.2
Xylene (Total)ug/kg <3.6 30<3.6
1,2-Dichloroethane-d4 (S)%109112
4-Bromofluorobenzene (S)%107108
Toluene-d8 (S)%101102
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 58 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
781331
EPA 3546
EPA 8270E
8270E Solid MSSV Microwave
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92672976001, 92672976002, 92672976003, 92672976004, 92672976005, 92672976006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4053527
Associated Lab Samples:92672976001, 92672976002, 92672976003, 92672976004, 92672976005, 92672976006
Matrix:Solid
AnalyzedMDL
1,2,4-Trichlorobenzene ug/kg <129 328 06/20/23 15:36129
1,2-Dichlorobenzene ug/kg <118 328 06/20/23 15:36118
1,3-Dichlorobenzene ug/kg <116 328 06/20/23 15:36116
1,4-Dichlorobenzene ug/kg <125 328 06/20/23 15:36125
1-Methylnaphthalene ug/kg <115 328 06/20/23 15:36115
2,2'-Oxybis(1-chloropropane)ug/kg <156 328 06/20/23 15:36156
2,4,5-Trichlorophenol ug/kg <150 328 06/20/23 15:36150
2,4,6-Trichlorophenol ug/kg <135 328 06/20/23 15:36135
2,4-Dichlorophenol ug/kg <128 328 06/20/23 15:36128
2,4-Dimethylphenol ug/kg <136 328 06/20/23 15:36136
2,4-Dinitrophenol ug/kg <1010 1640 06/20/23 15:361010
2,4-Dinitrotoluene ug/kg <126 328 06/20/23 15:36126
2,6-Dinitrotoluene ug/kg <120 328 06/20/23 15:36120
2-Chloronaphthalene ug/kg <130 328 06/20/23 15:36130
2-Chlorophenol ug/kg <123 328 06/20/23 15:36123
2-Methylnaphthalene ug/kg <131 328 06/20/23 15:36131
2-Methylphenol(o-Cresol)ug/kg <134 328 06/20/23 15:36134
2-Nitroaniline ug/kg <268 1640 06/20/23 15:36268
2-Nitrophenol ug/kg <142 328 06/20/23 15:36142
3&4-Methylphenol(m&p Cresol)ug/kg <132 328 06/20/23 15:36132
3,3'-Dichlorobenzidine ug/kg <222 656 06/20/23 15:36222
3-Nitroaniline ug/kg <257 1640 06/20/23 15:36257
4,6-Dinitro-2-methylphenol ug/kg <306 656 v206/20/23 15:36306
4-Bromophenylphenyl ether ug/kg <126 328 06/20/23 15:36126
4-Chloro-3-methylphenol ug/kg <230 656 06/20/23 15:36230
4-Chloroaniline ug/kg <257 656 06/20/23 15:36257
4-Chlorophenylphenyl ether ug/kg <122 328 06/20/23 15:36122
4-Nitroaniline ug/kg <249 656 06/20/23 15:36249
4-Nitrophenol ug/kg <634 1640 06/20/23 15:36634
Acenaphthene ug/kg <115 328 06/20/23 15:36115
Acenaphthylene ug/kg <115 328 06/20/23 15:36115
Aniline ug/kg <128 328 06/20/23 15:36128
Anthracene ug/kg <107 328 06/20/23 15:36107
Benzo(a)anthracene ug/kg <109 328 06/20/23 15:36109
Benzo(a)pyrene ug/kg <113 328 06/20/23 15:36113
Benzo(b)fluoranthene ug/kg <109 328 06/20/23 15:36109
Benzo(g,h,i)perylene ug/kg <127 328 06/20/23 15:36127
Benzo(k)fluoranthene ug/kg <115 328 06/20/23 15:36115
Benzoic Acid ug/kg <704 1640 06/20/23 15:36704
Benzyl alcohol ug/kg <248 656 06/20/23 15:36248
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 59 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4053527
Associated Lab Samples:92672976001, 92672976002, 92672976003, 92672976004, 92672976005, 92672976006
Matrix:Solid
AnalyzedMDL
bis(2-Chloroethoxy)methane ug/kg <136 328 06/20/23 15:36136
bis(2-Chloroethyl) ether ug/kg <123 328 06/20/23 15:36123
bis(2-Ethylhexyl)phthalate ug/kg <127 328 06/20/23 15:36127
Butylbenzylphthalate ug/kg <138 328 06/20/23 15:36138
Chrysene ug/kg <119 328 06/20/23 15:36119
Di-n-butylphthalate ug/kg <110 328 06/20/23 15:36110
Di-n-octylphthalate ug/kg <129 328 06/20/23 15:36129
Dibenz(a,h)anthracene ug/kg <126 328 06/20/23 15:36126
Dibenzofuran ug/kg <118 328 06/20/23 15:36118
Diethylphthalate ug/kg <120 328 06/20/23 15:36120
Dimethylphthalate ug/kg <119 328 06/20/23 15:36119
Fluoranthene ug/kg <112 328 06/20/23 15:36112
Fluorene ug/kg <115 328 06/20/23 15:36115
Hexachloro-1,3-butadiene ug/kg <142 328 06/20/23 15:36142
Hexachlorobenzene ug/kg <128 328 06/20/23 15:36128
Hexachlorocyclopentadiene ug/kg <188 328 v206/20/23 15:36188
Hexachloroethane ug/kg <125 328 06/20/23 15:36125
Indeno(1,2,3-cd)pyrene ug/kg <129 328 06/20/23 15:36129
Isophorone ug/kg <146 328 06/20/23 15:36146
N-Nitroso-di-n-propylamine ug/kg <123 328 06/20/23 15:36123
N-Nitrosodimethylamine ug/kg <110 328 06/20/23 15:36110
N-Nitrosodiphenylamine ug/kg <116 328 06/20/23 15:36116
Naphthalene ug/kg <111 328 06/20/23 15:36111
Nitrobenzene ug/kg <152 328 06/20/23 15:36152
Pentachlorophenol ug/kg <321 656 06/20/23 15:36321
Phenanthrene ug/kg <107 328 06/20/23 15:36107
Phenol ug/kg <146 328 06/20/23 15:36146
Pyrene ug/kg <133 328 06/20/23 15:36133
Pyridine ug/kg <103 328 06/20/23 15:36103
2,4,6-Tribromophenol (S)%59 10-131 06/20/23 15:36
2-Fluorobiphenyl (S)%53 10-130 06/20/23 15:36
2-Fluorophenol (S)%47 10-130 06/20/23 15:36
Nitrobenzene-d5 (S)%50 10-130 06/20/23 15:36
Phenol-d6 (S)%51 10-130 06/20/23 15:36
Terphenyl-d14 (S)%86 10-130 06/20/23 15:36
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4053528LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/kg 11201640 68 43-130
1,2-Dichlorobenzene ug/kg 11401640 69 43-130
1,3-Dichlorobenzene ug/kg 10901640 67 43-130
1,4-Dichlorobenzene ug/kg 11001640 67 44-130
1-Methylnaphthalene ug/kg 11701640 71 47-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 60 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4053528LABORATORY CONTROL SAMPLE:
LCSSpike
2,2'-Oxybis(1-chloropropane)ug/kg 10601640 64 29-130
2,4,5-Trichlorophenol ug/kg 11801640 71 47-130
2,4,6-Trichlorophenol ug/kg 12001640 73 47-130
2,4-Dichlorophenol ug/kg 12501640 76 45-130
2,4-Dimethylphenol ug/kg 15301640 93 45-130
2,4-Dinitrophenol ug/kg 39908220 49 27-140
2,4-Dinitrotoluene ug/kg 12701640 77 46-130
2,6-Dinitrotoluene ug/kg 12401640 76 48-130
2-Chloronaphthalene ug/kg 11101640 67 46-130
2-Chlorophenol ug/kg 11801640 72 43-130
2-Methylnaphthalene ug/kg 11201640 68 47-130
2-Methylphenol(o-Cresol)ug/kg 11801640 72 42-130
2-Nitroaniline ug/kg 23003290 70 41-130
2-Nitrophenol ug/kg 11701640 71 48-130
3&4-Methylphenol(m&p Cresol)ug/kg 11901640 73 39-130
3,3'-Dichlorobenzidine ug/kg 22803290 69 41-130
3-Nitroaniline ug/kg 22203290 67 37-130
4,6-Dinitro-2-methylphenol ug/kg 1870 v332905738-141
4-Bromophenylphenyl ether ug/kg 11301640 68 47-130
4-Chloro-3-methylphenol ug/kg 24003290 73 44-130
4-Chloroaniline ug/kg 20003290 61 41-130
4-Chlorophenylphenyl ether ug/kg 11701640 71 45-130
4-Nitroaniline ug/kg 24003290 73 42-130
4-Nitrophenol ug/kg 57908220 70 39-131
Acenaphthene ug/kg 11801640 72 49-130
Acenaphthylene ug/kg 11701640 71 50-130
Aniline ug/kg 8441640 51 38-130
Anthracene ug/kg 12101640 74 49-130
Benzo(a)anthracene ug/kg 12801640 78 51-130
Benzo(a)pyrene ug/kg 16101640 98 51-130
Benzo(b)fluoranthene ug/kg 16801640 102 49-130
Benzo(g,h,i)perylene ug/kg 16701640 102 48-140
Benzo(k)fluoranthene ug/kg 17501640 106 51-130
Benzoic Acid ug/kg 19008220 23 22-130
Benzyl alcohol ug/kg 21203290 64 43-130
bis(2-Chloroethoxy)methane ug/kg 9941640 60 43-130
bis(2-Chloroethyl) ether ug/kg 10301640 62 42-130
bis(2-Ethylhexyl)phthalate ug/kg 15101640 92 43-130
Butylbenzylphthalate ug/kg 15201640 93 44-131
Chrysene ug/kg 13301640 81 51-130
Di-n-butylphthalate ug/kg 11701640 71 46-130
Di-n-octylphthalate ug/kg 14201640 86 45-130
Dibenz(a,h)anthracene ug/kg 16901640 103 48-130
Dibenzofuran ug/kg 11801640 72 10-130
Diethylphthalate ug/kg 11801640 72 48-130
Dimethylphthalate ug/kg 11301640 69 48-130
Fluoranthene ug/kg 12801640 78 48-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 61 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4053528LABORATORY CONTROL SAMPLE:
LCSSpike
Fluorene ug/kg 12301640 75 48-130
Hexachloro-1,3-butadiene ug/kg 10401640 64 39-130
Hexachlorobenzene ug/kg 11901640 72 47-130
Hexachlorocyclopentadiene ug/kg 366 v316402217-130
Hexachloroethane ug/kg 10801640 66 40-130
Indeno(1,2,3-cd)pyrene ug/kg 16701640 102 50-130
Isophorone ug/kg 10101640 62 41-130
N-Nitroso-di-n-propylamine ug/kg 10601640 64 36-130
N-Nitrosodimethylamine ug/kg 10501640 64 34-130
N-Nitrosodiphenylamine ug/kg 11301640 69 48-130
Naphthalene ug/kg 11101640 68 46-130
Nitrobenzene ug/kg 10501640 64 39-130
Pentachlorophenol ug/kg 18803290 57 42-130
Phenanthrene ug/kg 12701640 77 50-130
Phenol ug/kg 12401640 75 42-130
Pyrene ug/kg 15701640 96 50-130
Pyridine ug/kg 7501640 46 26-130
2,4,6-Tribromophenol (S)%69 10-131
2-Fluorobiphenyl (S)%63 10-130
2-Fluorophenol (S)%65 10-130
Nitrobenzene-d5 (S)%64 10-130
Phenol-d6 (S)%66 10-130
Terphenyl-d14 (S)%90 10-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4053529MATRIX SPIKE SAMPLE:
MSSpike
Result
92672615004
1,2,4-Trichlorobenzene ug/kg 14502010 72 16-130ND
1,2-Dichlorobenzene ug/kg 14902010 74 19-130ND
1,3-Dichlorobenzene ug/kg 14602010 72 19-130ND
1,4-Dichlorobenzene ug/kg 15002010 74 20-130ND
1-Methylnaphthalene ug/kg 15102010 75 19-130ND
2,2'-Oxybis(1-chloropropane)ug/kg 14602010 72 10-130ND
2,4,5-Trichlorophenol ug/kg 16002010 79 19-130ND
2,4,6-Trichlorophenol ug/kg 15902010 79 18-130ND
2,4-Dichlorophenol ug/kg 16302010 81 16-130ND
2,4-Dimethylphenol ug/kg 21502010 107 10-130ND
2,4-Dinitrophenol ug/kg 455010100 45 10-143ND
2,4-Dinitrotoluene ug/kg 15102010 75 19-130ND
2,6-Dinitrotoluene ug/kg 15802010 78 22-130ND
2-Chloronaphthalene ug/kg 14402010 72 18-130ND
2-Chlorophenol ug/kg 16402010 82 20-130ND
2-Methylnaphthalene ug/kg 14202010 70 18-130ND
2-Methylphenol(o-Cresol)ug/kg 16002010 79 13-130ND
2-Nitroaniline ug/kg 29104040 72 18-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 62 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4053529MATRIX SPIKE SAMPLE:
MSSpike
Result
92672615004
2-Nitrophenol ug/kg 15702010 78 19-130ND
3&4-Methylphenol(m&p Cresol)ug/kg 16002010 79 13-130ND
3,3'-Dichlorobenzidine ug/kg 24304040 60 10-130ND
3-Nitroaniline ug/kg 28604040 71 22-130ND
4,6-Dinitro-2-methylphenol ug/kg 2100 v340405210-144ND
4-Bromophenylphenyl ether ug/kg 14202010 70 18-130ND
4-Chloro-3-methylphenol ug/kg 31104040 77 16-130ND
4-Chloroaniline ug/kg 25704040 64 17-130ND
4-Chlorophenylphenyl ether ug/kg 14202010 70 17-130ND
4-Nitroaniline ug/kg 29904040 74 21-130ND
4-Nitrophenol ug/kg 698010100 69 13-131ND
Acenaphthene ug/kg 14402010 71 20-130ND
Acenaphthylene ug/kg 14602010 73 21-130ND
Aniline ug/kg 9972010 49 10-130ND
Anthracene ug/kg 13702010 68 19-130ND
Benzo(a)anthracene ug/kg 14502010 72 17-130ND
Benzo(a)pyrene ug/kg 18202010 90 14-130ND
Benzo(b)fluoranthene ug/kg 18902010 94 11-134ND
Benzo(g,h,i)perylene ug/kg 18902010 94 12-130ND
Benzo(k)fluoranthene ug/kg 20002010 99 15-130ND
Benzoic Acid ug/kg 666010100 66 10-130ND
Benzyl alcohol ug/kg 28304040 70 20-130ND
bis(2-Chloroethoxy)methane ug/kg 13702010 68 16-130ND
bis(2-Chloroethyl) ether ug/kg 14402010 72 18-130ND
bis(2-Ethylhexyl)phthalate ug/kg 18402010 91 11-130ND
Butylbenzylphthalate ug/kg 18202010 90 10-130ND
Chrysene ug/kg 15302010 76 17-130ND
Di-n-butylphthalate ug/kg 13902010 69 16-130ND
Di-n-octylphthalate ug/kg 16002010 79 16-130ND
Dibenz(a,h)anthracene ug/kg 19202010 95 13-130ND
Dibenzofuran ug/kg 14202010 70 19-130ND
Diethylphthalate ug/kg 14502010 72 22-130ND
Dimethylphthalate ug/kg 14802010 73 23-130ND
Fluoranthene ug/kg 12902010 64 14-130ND
Fluorene ug/kg 14702010 73 19-130ND
Hexachloro-1,3-butadiene ug/kg 14102010 70 12-130ND
Hexachlorobenzene ug/kg 14102010 70 17-130ND
Hexachlorocyclopentadiene ug/kg 552 v320102710-130ND
Hexachloroethane ug/kg 14302010 71 14-130ND
Indeno(1,2,3-cd)pyrene ug/kg 19202010 95 13-130ND
Isophorone ug/kg 13902010 69 17-130ND
N-Nitroso-di-n-propylamine ug/kg 14102010 70 10-130ND
N-Nitrosodimethylamine ug/kg 14202010 71 16-130ND
N-Nitrosodiphenylamine ug/kg 14502010 72 19-130ND
Naphthalene ug/kg 14402010 71 18-130ND
Nitrobenzene ug/kg 14502010 72 15-130ND
Pentachlorophenol ug/kg 24604040 61 10-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 63 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4053529MATRIX SPIKE SAMPLE:
MSSpike
Result
92672615004
Phenanthrene ug/kg 14702010 73 17-130ND
Phenol ug/kg 16502010 82 15-130ND
Pyrene ug/kg 18002010 89 31-130ND
Pyridine ug/kg 11802010 59 10-130ND
2,4,6-Tribromophenol (S)%73 10-131
2-Fluorobiphenyl (S)%68 10-130
2-Fluorophenol (S)%75 10-130
Nitrobenzene-d5 (S)%72 10-130
Phenol-d6 (S)%74 10-130
Terphenyl-d14 (S)%87 10-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92672615005
4053530SAMPLE DUPLICATE:
1,2,4-Trichlorobenzene ug/kg <163 30ND
1,2-Dichlorobenzene ug/kg <149 30ND
1,3-Dichlorobenzene ug/kg <147 30ND
1,4-Dichlorobenzene ug/kg <158 30ND
1-Methylnaphthalene ug/kg <146 30ND
2,2'-Oxybis(1-chloropropane)ug/kg <197 30ND
2,4,5-Trichlorophenol ug/kg <189 30ND
2,4,6-Trichlorophenol ug/kg <171 30ND
2,4-Dichlorophenol ug/kg <162 30ND
2,4-Dimethylphenol ug/kg <172 30ND
2,4-Dinitrophenol ug/kg <1280 30ND
2,4-Dinitrotoluene ug/kg <159 30ND
2,6-Dinitrotoluene ug/kg <152 30ND
2-Chloronaphthalene ug/kg <164 30ND
2-Chlorophenol ug/kg <156 30ND
2-Methylnaphthalene ug/kg <166 30ND
2-Methylphenol(o-Cresol)ug/kg <169 30ND
2-Nitroaniline ug/kg <339 30ND
2-Nitrophenol ug/kg <179 30ND
3&4-Methylphenol(m&p Cresol)ug/kg <167 30ND
3,3'-Dichlorobenzidine ug/kg <280 30ND
3-Nitroaniline ug/kg <325 30ND
4,6-Dinitro-2-methylphenol ug/kg <386 v230ND
4-Bromophenylphenyl ether ug/kg <159 30ND
4-Chloro-3-methylphenol ug/kg <291 30ND
4-Chloroaniline ug/kg <325 30ND
4-Chlorophenylphenyl ether ug/kg <154 30ND
4-Nitroaniline ug/kg <315 30ND
4-Nitrophenol ug/kg <800 30ND
Acenaphthene ug/kg <146 30ND
Acenaphthylene ug/kg <146 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 64 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92672615005
4053530SAMPLE DUPLICATE:
Aniline ug/kg <162 30ND
Anthracene ug/kg <135 30ND
Benzo(a)anthracene ug/kg <138 30ND
Benzo(a)pyrene ug/kg <143 30ND
Benzo(b)fluoranthene ug/kg <138 30ND
Benzo(g,h,i)perylene ug/kg <161 30ND
Benzo(k)fluoranthene ug/kg <146 30ND
Benzoic Acid ug/kg <889 30ND
Benzyl alcohol ug/kg <314 30ND
bis(2-Chloroethoxy)methane ug/kg <172 30ND
bis(2-Chloroethyl) ether ug/kg <156 30ND
bis(2-Ethylhexyl)phthalate ug/kg <161 30ND
Butylbenzylphthalate ug/kg <174 30ND
Chrysene ug/kg <151 30ND
Di-n-butylphthalate ug/kg <139 30ND
Di-n-octylphthalate ug/kg <163 30ND
Dibenz(a,h)anthracene ug/kg <159 30ND
Dibenzofuran ug/kg <149 30ND
Diethylphthalate ug/kg <152 30ND
Dimethylphthalate ug/kg <151 30ND
Fluoranthene ug/kg <142 30ND
Fluorene ug/kg <146 30ND
Hexachloro-1,3-butadiene ug/kg <179 30ND
Hexachlorobenzene ug/kg <162 30ND
Hexachlorocyclopentadiene ug/kg <237 v230ND
Hexachloroethane ug/kg <158 30ND
Indeno(1,2,3-cd)pyrene ug/kg <163 30ND
Isophorone ug/kg <184 30ND
N-Nitroso-di-n-propylamine ug/kg <156 30ND
N-Nitrosodimethylamine ug/kg <139 30ND
N-Nitrosodiphenylamine ug/kg <147 30ND
Naphthalene ug/kg <140 30ND
Nitrobenzene ug/kg <192 30ND
Pentachlorophenol ug/kg <405 30ND
Phenanthrene ug/kg <135 30ND
Phenol ug/kg <184 30ND
Pyrene ug/kg <168 30ND
Pyridine ug/kg <130 30ND
2,4,6-Tribromophenol (S)%6764
2-Fluorobiphenyl (S)%5655
2-Fluorophenol (S)%5563
Nitrobenzene-d5 (S)%5965
Phenol-d6 (S)%5765
Terphenyl-d14 (S)%8564
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 65 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
781133
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92672976001, 92672976002, 92672976003
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92672250005
4052495SAMPLE DUPLICATE:
Percent Moisture %22.3 N262521.0
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92672438004
4052496SAMPLE DUPLICATE:
Percent Moisture %18.1 N292516.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 66 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
781144
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92672976004, 92672976005, 92672976006
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92672976004
4052544SAMPLE DUPLICATE:
Percent Moisture %22.9 N2122520.4
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92672798002
4052545SAMPLE DUPLICATE:
Percent Moisture %15.2 N282516.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 67 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
2081517
SM 2540 G
SM 2540G
Total Solids 2540 G-2011
Laboratory:Pace National - Mt. Juliet
Associated Lab Samples:92672976001, 92672976002, 92672976003, 92672976004, 92672976005, 92672976006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:R3939791-1
Associated Lab Samples:92672976001, 92672976002, 92672976003, 92672976004, 92672976005, 92672976006
Matrix:Solid
AnalyzedMDL
Total Solids %ND 06/21/23 12:05
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
R3939791-2LABORATORY CONTROL SAMPLE:
LCSSpike
Total Solids %50.050.0 100 85.0-115
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
L1627684-01
R3939791-3SAMPLE DUPLICATE:
Total Solids %77.9 0.142 1078.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 68 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92672976
TKC.008
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
2081408
3060A
EPA 7199
Wet Chemistry 7199
Laboratory:Pace National - Mt. Juliet
Associated Lab Samples:92672976001, 92672976002, 92672976003, 92672976004, 92672976005, 92672976006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:R3940208-1
Associated Lab Samples:92672976001, 92672976002, 92672976003, 92672976004, 92672976005, 92672976006
Matrix:Solid
AnalyzedMDL
Chromium, Hexavalent mg/kg <0.255 1.00 06/22/23 10:510.255
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
R3940208-2LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent mg/kg 11.710.0 117 80.0-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
R3940208-3MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
L1627262-05
R3940208-4
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent mg/kg ML,R120.0 0.00 75.0-12519.5 200 2020.0ND <0.255 3.89
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
R3940208-5MATRIX SPIKE SAMPLE:
MSSpike
Result
L1627262-05
Chromium, Hexavalent mg/kg 398 ML65161.1 75.0-125ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
L1627637-01
R3940208-7SAMPLE DUPLICATE:
Chromium, Hexavalent mg/kg 3.32 7.81 203.07
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
L1627751-01
R3940208-8SAMPLE DUPLICATE:
Chromium, Hexavalent mg/kg <0.258 0.00 20ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 69 of 75
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92672976
TKC.008
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Result may be biased high due to carryover from previously analyzed sample.C8
Analyte concentration exceeded the calibration range. The reported result is estimated.E
This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.IH
The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.IK
Analyte detected below the reporting limit, therefore result is an estimate. This qualifier is also used for all TICs.J
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.L1
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike recovery and/or matrix spike duplicate recovery was below laboratory control limits. Result may be biased
low.ML
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
Matrix spike recovery was outside laboratory control limits due to a parent sample concentration notably higher than the
spike level.P6
RPD value was outside control limits.R1
The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.v1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 70 of 75
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92672976
TKC.008
ANALYTE QUALIFIERS
The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.v2
The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.v3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 71 of 75
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92672976
TKC.008
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92672976001 888911 889958FG-1 (0-2)EPA 3050B EPA 6020B
92672976002 888911 889958FG-2 (0-2)EPA 3050B EPA 6020B
92672976003 888911 889958FG-3 (0-2)EPA 3050B EPA 6020B
92672976004 888911 889958FG-4 (0-2)EPA 3050B EPA 6020B
92672976005 888911 889958FG-5 (0-2)EPA 3050B EPA 6020B
92672976006 888911 889958FG-DUP (0-2)EPA 3050B EPA 6020B
92672976001 888922 889594FG-1 (0-2)EPA 7471B EPA 7471B
92672976002 888922 889594FG-2 (0-2)EPA 7471B EPA 7471B
92672976003 888922 889594FG-3 (0-2)EPA 7471B EPA 7471B
92672976004 888922 889594FG-4 (0-2)EPA 7471B EPA 7471B
92672976005 888922 889594FG-5 (0-2)EPA 7471B EPA 7471B
92672976006 888922 889594FG-DUP (0-2)EPA 7471B EPA 7471B
92672976001 781331 781742FG-1 (0-2)EPA 3546 EPA 8270E
92672976002 781331 781742FG-2 (0-2)EPA 3546 EPA 8270E
92672976003 781331 781742FG-3 (0-2)EPA 3546 EPA 8270E
92672976004 781331 781742FG-4 (0-2)EPA 3546 EPA 8270E
92672976005 781331 781742FG-5 (0-2)EPA 3546 EPA 8270E
92672976006 781331 781742FG-DUP (0-2)EPA 3546 EPA 8270E
92672976001 781453 781483FG-1 (0-2)EPA 5035A/5030B EPA 8260D
92672976002 781453 781483FG-2 (0-2)EPA 5035A/5030B EPA 8260D
92672976003 781504 781517FG-3 (0-2)EPA 5035A/5030B EPA 8260D
92672976004 781504 781517FG-4 (0-2)EPA 5035A/5030B EPA 8260D
92672976005 781504 781517FG-5 (0-2)EPA 5035A/5030B EPA 8260D
92672976006 781194 781409FG-DUP (0-2)EPA 5035A/5030B EPA 8260D
92672976001 781133FG-1 (0-2)SW-846
92672976002 781133FG-2 (0-2)SW-846
92672976003 781133FG-3 (0-2)SW-846
92672976004 781144FG-4 (0-2)SW-846
92672976005 781144FG-5 (0-2)SW-846
92672976006 781144FG-DUP (0-2)SW-846
92672976001 2081517 2081517FG-1 (0-2)SM 2540 G SM 2540G
92672976002 2081517 2081517FG-2 (0-2)SM 2540 G SM 2540G
92672976003 2081517 2081517FG-3 (0-2)SM 2540 G SM 2540G
92672976004 2081517 2081517FG-4 (0-2)SM 2540 G SM 2540G
92672976005 2081517 2081517FG-5 (0-2)SM 2540 G SM 2540G
92672976006 2081517 2081517FG-DUP (0-2)SM 2540 G SM 2540G
92672976001 2081408 2081408FG-1 (0-2)3060A EPA 7199
92672976002 2081408 2081408FG-2 (0-2)3060A EPA 7199
92672976003 2081408 2081408FG-3 (0-2)3060A EPA 7199
92672976004 2081408 2081408FG-4 (0-2)3060A EPA 7199
92672976005 2081408 2081408FG-5 (0-2)3060A EPA 7199
92672976006 2081408 2081408FG-DUP (0-2)3060A EPA 7199
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/29/2023 11:51 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 72 of 75
Page 73 of 75
Page 74 of 75
Page 75 of 75

Appendix C

DEQ Risk Calculator
Version Date:
Basis:
Site Name:
Site Address:
DEQ Section:
Site ID:
Exposure Unit ID:
Submittal Date:
Reviewed By:
Worst Case - Final Grade Soil Samples
North Carolina Department of Environmental Quality
Risk Calculator
AquaAir II Brownfiels Site - West Side
Charlotte, North Carolina
Division of Waste Management - Brownfields Program
Brownfields Project No. 18038-14-060
July 2023
May 2023 EPA RSL Table
Prepared By:Hart & Hickman, PC
North Carolina DEQ Risk Calculator
Complete Exposure Pathways
Version Date: July 2023
Basis: May 2023 EPA RSL Table
Site ID: Brownfields Project No. 18038-14-060
Exposure Unit ID: Worst Case - Final Grade Soil Samples
Note: Risk output will only be calculated for complete exposure pathways.
Receptor Pathway
Check box if
pathway
complete
Soil
Groundwater Use
Soil
Groundwater Use
Construction Worker Soil
Soil
Surface Water
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Source Soil
Source Groundwater
Source Soil
Source Groundwater
Resident
Non-Residential Worker
CONTAMINANT MIGRATION PATHWAYS
Groundwater
Surface Water
Input Form 1A
VAPOR INTRUSION PATHWAYS
DIRECT CONTACT SOIL AND WATER PATHWAYS
Resident
Non-Residential Worker
Recreator/Trespasser
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: July 2023
Basis: May 2023 EPA RSL Table
Site ID: Brownfields Project No. 18038-14-060
Exposure Unit ID: Worst Case - Final Grade Soil Samples
NOTE: If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations
Exposure Point
Concentration
(mg/kg)
Notes:CAS Number
Chemical
For the chemicals highlighted in blue, data entry notes are provided in the
PSRG Table link on the Main Menu
Minimum
Concentration
(Qualifier)
Maximum
Concentration
(Qualifier)
Units
Location of
Maximum
Concentration
Detection
Frequency
Range of
Detection Limits
Concentration
Used for
Screening
Background
Value
Screening
Toxicity Value
(Screening
Level) (n/c)
Potential
ARAR/TBC
Value
Potential
ARAR/TBC
Source
COPC
Flag
(Y/N)
Rationale for
Selection or
Deletion
0.119 FG-3 67-64-1 Acetone mg/kg
2.5 FG-3 7440-38-2 Arsenic, Inorganic mg/kg
192 FG-4 7440-39-3 Barium mg/kg
0.094 FG-5 7440-43-9 Cadmium (Diet)mg/kg
0.0168 FG-DUP 74-87-3 Chloromethane mg/kg
191.7 FG-4 16065-83-1 Chromium(III), Insoluble Salts mg/kg
5.31 FG-4 18540-29-9 Chromium(VI)mg/kg
21.8 FG-3/FG-4 7440-50-8 Copper mg/kg
15 FG-1 7439-92-1 ~Lead and Compounds mg/kg
0.033 FG-4 7487-94-7 ~Mercuric Chloride (and other Mercury salts)mg/kg
0.0369 FG-3 78-93-3 Methyl Ethyl Ketone (2-Butanone)mg/kg
62 FG-4 7440-02-0 Nickel Soluble Salts mg/kg
0.68 FG-DUP 7782-49-2 Selenium mg/kg
218 FG-5 7440-62-2 Vanadium and Compounds mg/kg
49 FG-DUP 7440-66-6 Zinc and Compounds mg/kg
Input Form 2A
Soil Exposure Point Concentration Table
Description of Exposure Point Concentration Selection:
North Carolina DEQ Risk Calculator
Risk for Individual Pathways Output Form 1A
Version Date: July 2023
Basis: May 2023 EPA RSL Table
Site ID: Brownfields Project No. 18038-14-060
Exposure Unit ID: Worst Case - Final Grade Soil Samples
Receptor Pathway Carcinogenic
Risk Hazard Index Risk exceeded?
Soil NC NC NC
Groundwater Use*NC NC NC
Soil 1.6E-06 4.9E-02 NO
Groundwater Use*NC NC NC
Construction Worker Soil NC
Soil NC
Surface Water*NC NC NC
Receptor Pathway Carcinogenic
Risk Hazard Index Risk exceeded?
Groundwater to Indoor Air NC NC NC
Soil Gas to Indoor Air NC NC NC
Indoor Air NC NC NC
Groundwater to Indoor Air NC NC NC
Soil Gas to Indoor Air NC NC NC
Indoor Air NC NC NC
Pathway Source
Source Soil NC
Source Groundwater NC
Source Soil NC
Source Groundwater NC
Groundwater Exceedence of 2L at Receptor?
Exceedence of 2L at Receptor?
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
Notes:
3. NM = Not modeled, user did not check this pathway as complete.
4. NC = Pathway not calculated, required contaminant migration parameters were not entered.
DIRECT CONTACT SOIL AND WATER CALCULATORS
Resident
Non-Residential Worker
Recreator/Trespasser
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based
closure.
Surface Water Exceedence of 2B at Receptor?
Exceedence of 2B at Receptor?
VAPOR INTRUSION CALCULATORS
Resident
Non-Residential Worker
CONTAMINANT MIGRATION CALCULATORS
Target Receptor Concentrations Exceeded?
North Carolina DEQ Risk Calculator
NC
NC
NC
NC
DEQ Risk Calculator - Direct Contact - Non-Residential Worker Soil
Version Date: July 2023
Basis: May 2023 EPA RSL Table
Site ID: Brownfields Project No. 18038-14-060
Exposure Unit ID: Worst Case - Final Grade Soil Samples
* - Note that inhalation on this calculator refers to outdoor inhalation of volatiles and particulates, not indoor inhalation associated with vapor intrusion.
CAS #Chemical Name:
Ingestion
Concentration
(mg/kg)
Dermal
Concentration
(mg/kg)
Inhalation
Concentration
(mg/kg)*
Ingestion
Carcinogenic
Risk
Dermal
Carcinogenic
Risk
Inhalation
Carcinogenic
Risk
Calculated
Carcinogenic
Risk
Ingestion
Hazard
Quotient
Dermal
Hazard
Quotient
Inhalation
Hazard
Quotient
Calculated
Non-
Carcinogenic
Hazard
Quotient
67-64-1 Acetone 0.119 0.119 0.119 1.1E-07 1.1E-07
7440-38-2 Arsenic, Inorganic 2.5 2.5 2.5 6.9E-07 1.5E-07 1.5E-11 8.3E-07 4.3E-03 9.1E-04 6.4E-07 5.2E-03
7440-39-3 Barium 192 192 192 8.2E-04 1.5E-06 8.2E-04
7440-43-9 Cadmium (Diet)0.094 0.094 0.094 2.3E-13 2.3E-13 8.0E-04 1.4E-04 3.6E-08 9.4E-04
74-87-3 Chloromethane 0.0168 0.0168 0.0168 1.4E-05 1.4E-05
16065-83-1 Chromium(III), Insoluble Salts 191.7 191.7 191.7 1.1E-04 1.1E-04
18540-29-9 Chromium(VI)5.31 5.31 5.31 8.1E-07 6.1E-10 8.1E-07 1.5E-03 2.0E-07 1.5E-03
7440-50-8 Copper 21.8 21.8 21.8 4.7E-04 4.7E-04
7439-92-1 ~Lead and Compounds 15 15 15 <SL**<SL**<SL**
7487-94-7 ~Mercuric Chloride (and other Mercury salts)0.033 0.033 0.033 9.4E-05 4.2E-10 9.4E-05
78-93-3 Methyl Ethyl Ketone (2-Butanone)0.0369 0.0369 0.0369 5.3E-08 1.3E-07 1.8E-07
7440-02-0 Nickel Soluble Salts 62 62 62 2.2E-11 2.2E-11 2.7E-03 2.7E-06 2.7E-03
7782-49-2 Selenium 0.68 0.68 0.68 1.2E-04 1.3E-10 1.2E-04
7440-62-2 Vanadium and Compounds 218 218 218 3.7E-02 8.4E-06 3.7E-02
7440-66-6 Zinc and Compounds 49 49 49 1.4E-04 1.4E-04
Cumulative:1.6E-06 4.9E-02
Output Form 2C
** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate cancer risk or hazard quotient. Lead concentrations are compared to the EPA screening level of 800
mg/kg for commercial/industrial soil.
North Carolina DEQ Risk Calculator