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HomeMy WebLinkAbout24017_Cameron Village Condos_EA_20201105#C-1269 Engineering #C-245 Geology Brownfields Assessment Report Cameron Village Condominiums 1801 Cameron Street Raleigh, North Carolina Brownfields Project ID No. 24017-20-092 H&H Job No. CAM-011 November 5, 2020 11/5/2020 i S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Final to DEQ\Brownfields Assessment Report Cameron Village Condominiums.docx Brownfields Assessment Report Cameron Village Condominiums Raleigh, North Carolina Brownfields Project No. 24017-20-092 H&H Job No. CAM-011 Table of Contents 1.0 Introduction .............................................................................................................................1 2.0 Site Background ......................................................................................................................2 2.1 Previous Environmental Assessments ...................................................................................2 3.0 Brownfields Assessment Activities ........................................................................................5 4.0 Receptor Survey ......................................................................................................................7 5.0 Background Soil Assessment Activities ................................................................................9 5.1 Background Soil Sampling Activities ...................................................................................9 5.2 Background Soil Sampling Analytical Results ...................................................................10 6.0 Vapor Intrusion Assessment Activities ...............................................................................11 6.1 Soil Gas Sampling Activities ...............................................................................................11 6.2 Soil Gas Analytical Results .................................................................................................13 6.3 Evaluation of Vapor Intrusion Assessment Results ............................................................14 7.0 Summary and Conclusions...................................................................................................16 ii S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Final to DEQ\Brownfields Assessment Report Cameron Village Condominiums.docx List of Tables Table 1 Summary of Background Soil Analytical Data Table 2 Summary of Soil Gas Analytical Data List of Figures Figure 1 Site Location Map Figure 2 Site Map Figure 3 Receptor Survey Map Figure 4 Sample Location Map List of Appendices Appendix A Brownfields Receptor Survey Form Appendix B Boring Logs Appendix C Laboratory Analytical Reports Appendix D July 2020 DEQ Risk Calculator Results 1 S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Final to DEQ\Brownfields Assessment Report Cameron Village Condominiums.docx Brownfields Assessment Report Cameron Village Condominiums Raleigh, North Carolina Brownfields Project No. 24017-20-092 H&H Job No. CAM-011 1.0 Introduction Hart & Hickman, PC (H&H) has prepared this Brownfields Assessment Report for the Cameron Village Condominiums property (Brownfields Project No. 24017-20-092) located at 1801 Cameron Street in Raleigh, Wake County, North Carolina (Site or subject Site). The Site is comprised of one parcel of land (Wake County Parcel Identification No. [PIN] 1704125771) that totals approximately 4.91 acres in size. A Site location map is provided as Figure 1. Proposed redevelopment for the Brownfields property includes razing the existing Site buildings and constructing two new buildings for mixed-use development that may consist of amenity and retail spaces and up to 400 residential units. A Site map with the proposed redevelopment plans is shown on Figure 2. A brief discussion of the Site history and previous environmental assessment activities conducted on the Brownfields property is provided in the following sections. 2 S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Final to DEQ\Brownfields Assessment Report Cameron Village Condominiums.docx 2.0 Site Background The Site was developed in 1949 with 12 multi-tenant condominiums, asphalt parking areas, concrete sidewalks, and landscaped areas. Since the initial development, the Site has remained residential, with the exception of a periodic use of a condominium building for office space. Up until the 1970s, the condominiums utilized heating oil to fuel the building’s heating systems. The heating oil was stored in on-Site underground storage tanks (USTs) located in the vicinity of four boiler rooms. The heating systems were reported to have been converted from heating oil to natural gas in the 1970s and the USTs were either removed or drained and filled in place at the time of conversation. H&H was unable to obtain documentation of UST closure and/or abandonment procedures. A Site map referencing the boiler room locations is included as Figure 2. A brief discussion of previous assessment activities completed at the Site is provided below. 2.1 Previous Environmental Assessments In December 2019, H&H completed a Phase I Environmental Assessment (ESA) at the subject Site. The results of the December 2019 ESA identified the following potential environmental concerns in connection with the Site: • Potential impacts associated with historically used on-Site heating oil USTs; and • On-Site groundwater impacts associated with the former Medlin-Davis Cleaners dry-cleaning facility at 2028 Cameron Street. Under the purview of the North Carolina Department of Environmental Quality (DEQ) Dry-Cleaning Solvent Cleanup Act (DSCA) Program, groundwater monitoring well MW-20 was installed in 2010 in the northern portion of the Site to evaluate groundwater conditions associated with an upgradient release of dry-cleaning solvent constituents from the former Medlin-Davis Cleaners (DSCA identification number DC920013). Sampling events completed for well MW-20 indicated detections of the dry-cleaning solvent tetrachloroethylene (PCE) at concentrations (up to 6.4 micrograms per liter [μg/L]) above the DEQ 15A North Carolina Administrative Code (NCAC) 3 S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Final to DEQ\Brownfields Assessment Report Cameron Village Condominiums.docx 02L .0202 Groundwater Quality Standard (2L Standard). The DSCA Program concluded that the chlorinated volatile organic compound (cVOC) groundwater plume associated with the off-Site Medlin-Davis Cleaners release is generally stable or is decreasing, and therefore, concentrations detected at the Site are unlikely to increase beyond those detected during sampling events. Monitoring well MW-20 was abandoned in June 2016 as part of DSCA monitoring well closure activities. A closure plan was developed as part of a December 10, 2013 Risk Assessment and a November 6, 2015 Risk Management Plan. Results of the risk assessment indicated impacts could be managed using land-use controls for the source property and 11 downgradient properties, including the Brownfields property. The Risk Assessment included evaluation of vapor intrusion potential for the Site based on groundwater analytical data for well MW-20. The results of the vapor intrusion evaluation indicated no significant risk of vapor intrusion for the Site. Land-use controls were subsequently implemented for the impacted properties, including the Site. The land-use control for the Site consists of a Notice of Dry Cleaning Solvent Remediation (NDCSR) filed on the deed for the Site property prohibiting groundwater use. The Medlin-Davis Cleaners received a No Further Action (NFA) determination on May 5, 2016. It should be noted that there have been some changes to vapor intrusion evaluation procedures since the 2013 Risk Assessment. To confirm that groundwater concentrations do not pose a vapor intrusion risk for the Site, H&H utilized the May 2019 DEQ Risk Calculator to evaluate vapor intrusion for the groundwater to indoor air pathway using the highest concentrations of detected VOCs from former on-Site monitoring well MW-20. The results of the evaluation did not indicate exceedances of acceptable residential risk levels (cumulative lifetime incremental cancer risk [LICR] threshold of 1 x 10-4 and cumulative non-carcinogenic hazard index [HI] threshold of 1). The Site received eligibility into the DEQ Brownfields Program via a Letter of Eligibility dated June 12, 2020. On August 6, 2020, CUSA N.C. Holdings, L.P. (the Brownfields Prospective Developer [PD]), PD’s environmental attorney, and H&H participated in a conference call with DEQ Brownfields personal to discuss Site history, areas of potential environmental concern, proposed redevelopment plans, potential data gaps, and the scope of Brownfields assessment 4 S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Final to DEQ\Brownfields Assessment Report Cameron Village Condominiums.docx activities needed to address the data gaps. As requested by DEQ during the meeting, on August 21, 2020, H&H submitted a Brownfields Assessment Work Plan (Work Plan) to conduct assessment activities to evaluate potential impacts within the redevelopment area. The Work Plan was approved by DEQ Brownfields in an email dated September 2, 2020. A summary of Brownfields assessment activities is provided in the following sections. 5 S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Final to DEQ\Brownfields Assessment Report Cameron Village Condominiums.docx 3.0 Brownfields Assessment Activities In September 2020, H&H completed Brownfields assessment activities at the Site in accordance with the DEQ Brownfields approved Work Plan. The assessment activities included vapor intrusion assessment activities at the Site to evaluate conditions for potential impacts associated with historical on-Site and off-Site operations. The assessment activities also included background soil sampling to assist in future soil management during redevelopment. In addition, receptor survey activities were completed to obtain information about land use, water supply, basements, underground utilities, drains, and surface water bodies in the vicinity of the Site. Prior to conducting the field activities, H&H contacted North Carolina 811, the public utility locator, to mark subsurface utilities located on the Site. H&H also contracted with a private utility locator to screen proposed sample locations for subgrade utilities not marked by the public locator. Additionally, soil gas locations were hand cleared to 5 feet below ground surface (ft bgs) to further screen the boring locations for the presence of subsurface utilities. During the utility locate, a ground penetrating radar (GPR) survey was completed to investigate whether USTs are or were present in the vicinity of the boiler rooms. Results of the GPR survey did not identify any subsurface anomalies (tanks and/or fill material) that would be typical of USTs. If USTs are encountered during redevelopment activities, they can be managed in accordance with a Brownfields approved Environmental Management Plan (EMP). The assessment activities were conducted in general accordance with DEQ Inactive Hazardous Sites Branch (IHSB) Guidelines for Assessment and Cleanup (Guidelines) dated January 2020, the DEQ Division of Waste Management (DWM) Vapor Intrusion Guidance (VI Guidance) dated March 2018, and the most recent versions of the U.S. Environmental Protection Agency (EPA) Region IV Science and Ecosystem Support Division (SESD) Field Branches Quality System and Technical Procedures guidance. Investigative derived waste (IDW) generated during the assessment activities was thin spread on-Site in accordance with DEQ IHSB Guidelines. 6 S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Final to DEQ\Brownfields Assessment Report Cameron Village Condominiums.docx A summary of receptor survey results is provided in Section 4.0; details of background soil assessment activities are provided in Section 5.0; details of vapor intrusion assessment activities are provided in Section 6.0; and summary and conclusions based on the results of the assessment activities are provided in Section 7.0. 7 S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Final to DEQ\Brownfields Assessment Report Cameron Village Condominiums.docx 4.0 Receptor Survey On September 8, 2020, H&H conducted receptor survey activities at the Site and in the nearby area. The receptor survey included a pedestrian and vehicular survey to obtain information about land use, potential water supply wells, basements, utility manways and chases, storm sewers, other underground utilities, drains, and surface water bodies located within a 1,500-ft radius of the Site. H&H also contacted the Wake County Department of Environmental Services and the online DEQ Source Water Assessment Program (SWAP) geographic information system map to obtain information regarding potable water supply wells located within the search radius. In addition, H&H identified land use, zoning, underground utilities using Wake County online resources. The Brownfields Property Receptor Survey Form is included as Appendix A, and a Receptor Survey Map is provided as Figure 3. The results of the receptor survey are summarized below. Zoning The subject Site is zoned as “Residential Mixed Use” (RX-3); the adjacent property to the east is zoned as “Residential-6” (R-6); the adjacent properties to the south are zoned as R-6 and “Office Mixed Use” (OX-3-UL); and the adjacent properties to the west and north are zoned as “Commercial Mixed Use” (CX-5-UL). Municipal Water Availability Municipal water is supplied by the City of Raleigh Public Utilities Department – Raleigh Water and is available to the Site and surrounding area. H&H did not identify sources of public drinking water within 1,500-ft of the Site based on the DEQ SWAP geographic information system map. The City of Raleigh and Wake County obtain their water from the Neuse River and/or Cape Fear River basins, which includes Falls Lake, Lake Wheeler, Benson Lake, and Jordan Lake. The closest drinking water source is an intake for Lake Wheeler and is located approximately 6.8 miles southwest of the Site. Service area maps are not made available by Raleigh Water; however, H&H observed municipal water meters and fire hydrants for the Site and surrounding properties. 8 S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Final to DEQ\Brownfields Assessment Report Cameron Village Condominiums.docx Water Supply Wells H&H contacted the Wake County Department of Environmental Health and conducted a pedestrian and vehicular survey of nearby properties to identify potential water supply wells within a 1,500-ft radius of the Site. No private water supply wells were identified within a 1,500-ft radius of the Site during the pedestrian and vehicular survey of the area. According to the information provided by the Wake County Department of Environmental Health, no active or historic private water supply wells were identified. Surface Water Bodies No surface water bodies were identified on the Site. The nearest surface water body is an unnamed tributary of Pigeon House Branch, a DEQ Class C; Nutrient Sensitive Waters (NSW) surface water body, located approximately 80 feet east of the Site. No other surface water bodies were identified within a 1,500-ft radius of the Site. Subsurface Structures H&H contacted North Carolina 811, the public utility locator, to mark subsurface utilities located on the Site and conducted a visual reconnaissance in the Site area to identify potential subsurface structures within 100 ft of the subject Site. H&H observed evidence of subsurface utilities, including sanitary sewer, municipal water, and natural gas adjacent to the subject Site. The Site’s municipal water, sanitary sewer, and natural gas lines connect to the municipal utility system at multiple access points along Bellwood Drive. H&H did observe structures with obvious basements within a 1,500-ft radius of the Site, which include the Site buildings, residences along Park Drive and W. Johnson Street and a parking deck along Clark Avenue. According to the real estate records, multiple residences with basements or partial basements are present in the vicinity of the Site. 9 S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Final to DEQ\Brownfields Assessment Report Cameron Village Condominiums.docx 5.0 Background Soil Assessment Activities On September 9, 2020, H&H contracted Regional Probing Services to advance two soil borings (SB-1 and SB-2) to assess background conditions at the Site. Based on the results of the geophysical survey, additional soil samples were not collected to evaluate potential impacts associated with the former heating oil UST system(s). The approximate locations of the proposed background soil borings are depicted on Figure 4 and were advanced in the following locations: • In the north-central portion of the Site (SB-1) within the proposed northern building footprint; and • In the proposed courtyard/pool area in the southern portion of the Site (SB-2). Details of the background soil sampling activities and results are provided in the following sections. 5.1 Background Soil Sampling Activities A decontaminated hand auger was used to advance two soil borings to depths of approximately 2 ft bgs at the locations outlined above. Soil samples were logged for lithological description and field screened for indications of potential impacts by observation for staining, unusual odors, and the presence of volatile organic vapors using a calibrated photoionization detector (PID). Based on field observations and field screening, soil samples were collected from each soil boring from approximately 1-2 ft bgs. Boring logs including lithologic descriptions and field screening results are provided in Appendix B. Soil samples selected for laboratory analysis were collected directly into laboratory supplied sample containers and labeled with the sample identification, date, time, and requested analysis and placed in a laboratory supplied cooler with ice. The soil samples were submitted to Con-test Analytical Laboratory (Contest), a North Carolina certified laboratory, under standard chain of custody protocols for analysis of Resource Conservation and Recovery Act (RCRA) metals plus hexavalent chromium by EPA Methods 6020/7471/7199. Estimated values (J-flag reporting) were requested of the laboratory. 10 S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Final to DEQ\Brownfields Assessment Report Cameron Village Condominiums.docx Following sampling activities, the soil sample locations were estimated using a hand-held global positioning system (GPS) unit. Both soil borings were properly abandoned and the surfaces were repaired similar to pre-sampling conditions. 5.2 Background Soil Sampling Analytical Results A tabular summary of soil sample analytical results is presented in Table 1 and the laboratory analytical report and chain of custody record are provided in Appendix C. The laboratory analytical results were compared to the DEQ Residential and Industrial/Commercial Preliminary Soil Remediation Goals (PSRGs) dated July 2020. In addition to the PSRGs, metals results were compared to published background ranges for North Carolina soils published in Elements in North American Soils authored by Dragun and Chekiri (2005). As expected, naturally occurring levels of several metals were detected at concentrations above the laboratory method detection limits in each background soil sample. Arsenic was detected at a concentration of 1.1 milligrams per kilogram (mg/kg) in the soil sample collected from SB-2, which is above the Residential PSRG (0.68 mg/kg) but below the Industrial/Commercial PSRG (3.0 mg/kg) and within published background levels for North Carolina soils. No other metals were detected in the background samples at concentrations exceeding Residential and/or Industrial/Commercial PSRGs. 11 S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Final to DEQ\Brownfields Assessment Report Cameron Village Condominiums.docx 6.0 Vapor Intrusion Assessment Activities On September 9 through 10, 2020, H&H completed vapor intrusion assessment activities at the Site to evaluate the potential for structural vapor intrusion into proposed future buildings. Specifically, seven (7) soil gas monitoring points (SG-1S/D and SG-2 through SG-6) were installed throughout the proposed building footprints and in select areas associated with the former heating oil UST system(s). The approximate locations of the soil gas samples are depicted on Figure 4. Details of the vapor intrusion assessment activities and results are provided in the following sections. 6.1 Soil Gas Sampling Activities The soil gas monitoring points were installed by advancing a boring via decontaminated stainless-steel hand auger and a direct-push technology (DPT) drill rig to depths ranging from approximately 8 to 14 ft bgs. With the exception of soil gas point SG-1D (installed to a depth of approximately 14 ft bgs), soil gas points were installed to a depth of approximately 8 ft bgs. At each location, a 6-inch 0.010-inch stainless steel screen was set at the base of the boring and connected to the ground surface with ¼-inch Teflon® tubing. The annular space of the boring was then filled with filter sand followed by a bentonite seal to prevent short-circuiting of air from the surface. Soil gas monitoring points were allowed to equilibrate for at least two hours following sample point installation. As part of soil gas sample collections procedures, “shut-in” tests and leak checks were performed at each soil gas monitoring point. The purpose of the shut-in test (and helium leak check described below) is to ensure that short circuiting with ambient air does not occur during sampling. A description of the shut-in test and helium leak testing procedures is provided below. The shut-in test was conducted by connecting an in-line airflow controller with a vacuum gauge to a laboratory supplied 1-liter stainless steel Summa® canister and sealing the flow regulator with a laboratory provided brass nut and ferrule assembly to form an air-tight seal. The airflow 12 S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Final to DEQ\Brownfields Assessment Report Cameron Village Condominiums.docx regulator was pre-set by the laboratory to regulate the soil gas intake rate to less than approximately 200 milliliters per minute. Once the sampling train was “closed”, the sample valve on the Summa® canister was opened and the reading on the vacuum gauge was recorded. The Summa® canister sample valve was then closed, and the vacuum gauge was observed to ensure no vacuum loss occurs. Because the vacuum reading remained the same, the shut-in test was considered successful for each soil gas monitoring point. Following successful shut-in tests, leak checks were conducted by constructing a shroud around the sample train at each sampling point and flooding the air with helium gas. Helium concentrations inside the shroud were measured using a calibrated helium gas detector and maintained at concentrations of approximately 15% to 30% for the duration of the leak check. Using a syringe and three-way valve, the Teflon® sample tubing was purged and soil gas was collected outside of the shroud into a Tedlar® bag. Soil gas in the Tedlar® bag was analyzed using the helium gas detector to ensure that helium concentrations were less than 10% of the concentration measured within the shroud. Each sample location passed the helium leak check. Following a successful leak check, the intake valve on the Summa® canister was fully opened to begin collection of the soil gas sample. Vacuum readings on the Summa® canister were recorded prior to and following the sampling period to ensure adequate sample volume was collected. A vacuum was maintained within the canisters at the conclusion of the sampling event. After sample collection, the Summa® canister valves were closed prior to disassembly of the sampling train. The Summa® canisters were then placed in laboratory supplied shipping containers, properly labeled, and shipped under standard chain-of-custody protocols to Contest and for analysis of VOCs by EPA Method TO-15. As discussed below, soil gas sample SG-1S was sent to Enthalpy Analytical, LLC and initially put on hold pending results of laboratory analysis for soil gas sample SG-1D. For quality assurance/quality control (QA/QC) purposes, a duplicate soil gas sample (Dup-1) was collected from soil gas vapor monitoring point SG-1D. Upon receipt of the samples, the laboratories recorded the final received vacuum pressures for each Summa canister. The initial, 13 S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Final to DEQ\Brownfields Assessment Report Cameron Village Condominiums.docx post-sampling, and lab receipt pressures are indicated in the laboratory analytical reports included in Appendix C. Upon completion of the vapor intrusion assessment activities, soil gas monitoring point locations were estimated using a hand-held GPS unit. Soil gas monitoring points were then properly abandoned and surfaces were repaired to generally match pre-drilling conditions. 6.2 Soil Gas Analytical Results Results of soil gas laboratory analyses are summarized in Table 2. The laboratory analytical reports and chain of custody records are provided in Appendix C. Soil gas sample analytical results were compared to the July 2020 DEQ Residential and Non-Residential Sub-slab and Exterior Soil Gas Screening Levels (SGSLs). Laboratory analytical results indicate that low levels of VOCs were detected above laboratory method detection limits in each soil gas sample. Of the compounds detected, PCE was detected at concentrations exceeding the Residential SGSL of 280 micrograms per cubic meter (µg/m3) in soil gas samples SG-2 (380 µg/m3) and SG-3 (370 µg/m3). Based on the presence of low level cVOCs in deep soil gas sample SG-1D, H&H authorized the laboratory to analyze shallow soil gas sample SG-1S. Laboratory analytical results for soil gas samples SG-1S and SG-1D did not indicate detections of cVOCs associated with the off-Site Medlin-Davis Cleaners (specifically PCE and trichloroethylene [TCE]) above Residential SGLS. Based on information collected during DSCA assessment activities conducted in 2010, groundwater in former on-Site monitoring well MW-20 was measured at depths ranging from approximately 18 to 20 ft bgs. Monitoring well MW-20 was formerly located in the northern portion of the Brownfields property and in the vicinity of recently collected soil gas samples SG-1S and SG-1D. Comparison of VOC levels between shallow (8 ft bgs) soil gas sample SG-1S and deep (14 ft bgs) soil gas sample SG-1D indicate generally consistent concentrations which do not appear to increase with depth. 14 S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Final to DEQ\Brownfields Assessment Report Cameron Village Condominiums.docx Other compounds detected above Residential SGSLs include: chloroform in soil gas samples SG-1S (18.6 µg/m3), SG-1D (up to 17 µg/m3), SG-2 (27 µg/m3), and SG-3 (40 µg/m3); ethylbenzene in soil gas sample SG-1D (up to 53 µg/m3); and naphthalene in soil gas samples in SG-1S (4.66 µg/m3), SG-4 (3.5 µg/m3), and SG-5 (2.9 µg/m3). No other compounds were detected above Residential or Non-Residential SGSLs. 6.3 Evaluation of Vapor Intrusion Assessment Results The DEQ SGSLs are conservative and based on a lifetime incremental cancer risk (LICR) for potential carcinogenic risks of 1 x 10-6 and a non-carcinogenic hazard quotient (HQ) of 0.2 for potential non-carcinogenic risks. The DEQ and EPA acceptable risk range for potential carcinogenic risks is 1 x 10-4 to 1 x 10-6 or less and the acceptable level for non-carcinogenic risks is a hazard index (HI) less than 1. H&H utilized the July 2020 DEQ risk calculator assuming residential and non-residential land use scenarios (based on the planned use at the Site) to evaluate calculated cumulative risks for the soil gas to indoor air vapor intrusion pathway at the Site. H&H calculated cumulative risks using the highest concentration of any compound detected in any gas sample collected from within the respective proposed building footprint. In addition, H&H calculated risks from each soil gas sample location. Results of the risk calculations are summarized below and included in Appendix D. Sample ID Resident Non-Residential Worker Carcinogenic Risk Hazard Index Carcinogenic Risk Hazard Index SG-1S 6.0E-06 2.2E-01 5.9E-07 2.1E-02 SG-1D 6.1E-06 3.3E-01 4.7E-07 2.6E-02 SG-2 8.6E-06 3.3E-01 6.5E-07 2.6E-02 SG-3 1.2E-05 3.2E-01 8.8E-07 2.6E-02 SG-4 1.3E-06 3.3E-02 2.0E-07 5.5E-03 SG-5 7.3E-07 3.2E-02 1.4E-07 4.8E-03 SG-6 9.0E-07 3.7E-02 6.8E-08 2.9E-03 Worst Case Scenario 1.5E-05 6.4E-01 1.1E-06 5.1E-02 15 S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Final to DEQ\Brownfields Assessment Report Cameron Village Condominiums.docx As shown in the table above, calculated cumulative risks do not exceed acceptable levels (calculated cumulative carcinogenic risks between 1 x 10-6 and 1 x 10-4 and HI <1) for a resident or non-residential worker. Based on evaluation of the July 2020 DEQ risk calculator results, there is no evidence of a vapor intrusion concern for the proposed buildings and therefore mitigation measures do not appear warranted. 16 S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Final to DEQ\Brownfields Assessment Report Cameron Village Condominiums.docx 7.0 Summary and Conclusions H&H has completed Brownfields assessment activities at the Cameron Village Condominiums Brownfields property located in Raleigh, North Carolina. The assessment activities were conducted in accordance with the DEQ Brownfields approved Work Plan dated August 21, 2020. Brownfields assessment activities included background soil and soil gas sampling activities to evaluate for potential impacts and to assist in management of Site media during proposed redevelopment activities. In addition, a receptor survey was performed to obtain information about land use, water supply, basements, underground utilities, drains, and surface water bodies in the Site vicinity. A brief summary of the Brownfields assessment activities is provided below. • Evidence of current or former USTs was not identified during subsurface investigation activities. • Results of background soil assessment activities indicate that arsenic was detected above the Residential PSRG, but below the DEQ Industrial/Commercial PSRG and is consistent with published background ranges for North Carolina soils. • Results of vapor intrusion assessment activities indicate that PCE, chloroform, ethylbenzene, and naphthalene were detected at concentrations exceeding Residential SGSLs, but below Non-Residential SGSLs. July 2020 DEQ risk calculator results indicate that calculated cumulative risk values for the soil gas to indoor air vapor intrusion pathway for a residential use scenario are within the acceptable carcinogenic risk of 1 x 10-4 to 1 x 10-6 and less than a hazard index of 1. Based on these results, additional assessment does not appear warranted and impacted media or media disturbed during future redevelopment activities can be managed in accordance with a Brownfields EMP. In addition, based on results of vapor intrusion assessment activities, there does not appear to be an unacceptable vapor intrusion risk to future residential building occupants. Table 1Summary of Background Soil Analytical DataCameron Village CondominiumsRaleigh, North CarolinaBrownfields Project No. 24017-20-092H&H Job No. CAM-011Depth (ft bgs)1-2 1-2Sample Date9/9/2020 9/9/2020LocationNorthern Portion of SiteSouthern Portion of SiteRange MeanRCRA Metals (6020/7471/7199) (mg/kg)Arsenic 0.49 1.1 0.68 3.0 1.0-18 4.8Barium 22 38 3,100 47,000 50-1000 356Cadmium<0.053 <0.05714 200 1.0 - 10* 4.3*Chromium (total) 13 29 NE NE 7.0- 300 65Trivalent Chromium 13 29 23,000 350,000 NE NEHexavalent Chromium<0.255 <0.2550.31 6.5 NE NELead 17 14 400 800 ND - 50 16Selenium<0.38 <0.4178 1,200 <0.1 - 0.8 0.42Silver<0.0340.045 J 78 1,200 NE NEMercury<0.00840.024 J 2.3 9.7 0.03 - 0.52 0.121Notes:1) North Carolina Department of Environmental Quality (DEQ) Inactive Hazardous Sites Branch (IHSB) Preliminary Soil Remediation Goals (PSRGs) (July 2020).2) Range and mean values of background metals for North Carolina soils taken from Elements in North American Soils by Dragun and Chekiri, 2005.* = Range and mean values of background metals for Southeastern USA soils.All concentrations are reported in milligrams per kilogram (mg/kg).Laboratory analytical methods are shown in parentheses.RCRA = Resource Conservation and Recovery Act; ft bgs = feet below the ground surface; NE = Not Established.J = Estimated value that is less than the laboratory reporting limit and greater than or equal to the method detection limit.Sample IDResidential PSRGs(1) Industrial/ CommercialPSRGs(1)Regional Background Metals in Soil(2)SB-1 SB-2S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Tables\Data Tables 2020092911/2/2020Table 1 (Page 1 of 1)Hart & Hickman, PC Table 2Summary of Soil Gas Analytical DataCameron Village CondominiumsRaleigh, North CarolinaBrownfields Project No. 24017-20-092H&H Job No. CAM-011SG-1D Dup-1Sample Date9/10/2020 9/10/2020 9/10/2020 9/10/2020 9/10/2020 9/10/2020 9/10/2020 9/10/2020LocationEastern Portion of Proposed Northern Building Southwestern Portion of Proposed Northern Building Northeastern Portion of Proposed Southern Building Central Portion of Proposed Southern Building Southcentral Portion of Proposed Southern Building VOCs (TO-15) (µg/m3)Acetone 23.6 19 J 21 19 130 45<11170 220,000 2,700,000Benzene 4.28 3.5 3.6 3.3 1.5 2.6 3.6 4.9 12 1601,3-Butadiene 0.306<0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.323.1 412-Butanone (MEK) 8.90 5.6 J 7.9 J 4.9 J 22 J 7.8 J 9.0 J 27 35,000 440,000Carbon Disulfide 1.11<1.6 <1.6 <1.6 <1.6 <1.6 <1.6 <1.64,900 61,000Chlorobenzene 0.544<0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22350 4,400Chloroform18.6 16 17 27 403.1<0.24 <0.244.1 53Chloromethane 0.218<0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32630 7,900Cyclohexane 5.79<0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.3442,000 530,0001,3-Dichlorobenzene 1.32<0.44 <0.44 <0.44 <0.44 <0.44 <0.44 <0.44NE NEDichlorodifluoromethane (Freon 12) 2.00<0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31700 8,8001,4-Dioxane 0.360 J<2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.019 250Ethanol 85.8 66 38 56 71 89 45 36 NE NEEthyl Acetate 1.98<4.3 <4.3 <4.3 <4.3 <4.3 <4.3 <4.3490 6,100Ethylbenzene 34.945 5319 16 10 15 17 37 4904-Ethyltoluene 30.1 41 48<0.30 <0.30 <0.30 <0.30 <0.30NE NEHeptane 6.26 8.7 8.5 17 4.4 20 12 11 2,800 35,000Hexane 2.06<1.3 <1.3 <1.3 <1.3 <1.310 J<1.34,900 61,0002-Hexanone (MBK) 0.761<0.46 <0.46 <0.46 <0.46 <0.46 <0.46 <0.46210 2,600Isopropanol 3.92<4.5 <4.5 <4.55.7 J 14 J<4.5 <4.51,400 18,0004-Methyl-2-pentanone (MIBK) 17.6 14 20<0.4320 5.1 9.8 16 21,000 260,000Methylene Chloride 0.645<1.6 <1.6 <1.6 <1.6 <1.6 <1.6 <1.63,400 53,000Naphthalene4.66<0.59 <0.59 <0.59 <0.593.5 2.9<0.592.8 36Propene 3.65<1.2 <1.28.4 J<1.221<1.2 <1.2NE NEStyrene 7.46 5.5 6.7<0.24 <0.24 <0.24 <0.24 <0.247,000 88,000Tetrachloroethylene 26.7 40 46380 3705.4 9.6 12 280 3,500Tetrahydrofuran 11.3 3.6 J 5.1 J<1.518 4.0 J 7.2 24 14,000 180,000Toluene 88.1 110 120 52 34 39 39 52 35,000 440,000Trichloroethylene 1.64 1.8 2.0 1.4 1.5 0.80 J<0.40 <0.4014 180Trichlorofluoromethane (Freon 11) 3.55 3.4 J 3.3 J 2.0 J 2.4 J<0.85 <0.85 <0.85NE NE1,2,4-Trimethylbenzene 146 210 230<0.22 <0.22 <0.22 <0.22 <0.22420 5,3001,3,5-Trimethylbenzene 69.2 89 100<0.26 <0.26 <0.26 <0.26 <0.26420 5,300Xylenes, Total 212 310 351 82 78 43 71 74 700 8,800Notes:1) North Carolina Department of Environmental Quality (DEQ) Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs) (July 2020).Only VOCs detected in at least one sample are shown.Compound concentrations reported to the laboratory method detection limits.Concentrations are reported in micrograms per cubic meter (µg/m3).Laboratory analytical method is shown in parentheses.Bold values indicate compounds detected above DEQ Residential SGSLs (July 2020).J = Estimated value that is less than the laboratory reporting limit and greater than or equal to the method detection limit.VOCs = volatile organic compounds; NE = not established.Non-Residential SGSL(1)Sample IDSG-2 SG-3SG-1DResidential SGSL(1)SG-1SNorthwestern Portion of Proposed Northern BuildingSG-4 SG-5 SG-6S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Tables\Data Tables 2020092911/2/2020Table 2 (Page 1 of 1)Hart & Hickman, PC TITLE PROJECT SITE LOCATION MAP CAMERON VILLAGE CONDOMINIUMS1801 CAMERON STREETRALEIGH, NORTH CAROLINA DATE: JOB NO: REVISION NO: FIGURE: 10-21-2019 0 1CAM-011 SITE 0 2000 4000 APPROXIMATE SCALE IN FEET N U.S.G.S. QUADRANGLE MAP QUADRANGLE 7.5 MINUTE SERIES (TOPOGRAPHIC) RALEIGH WEST, NORTH CAROLINA 2002 3921 Sunset Ridge Road, Ste. 301Raleigh, North Carolina 27607919-847-4241 (p) 919-847-4261 (f)License # C-1269 / #C-245 Geology REVISION NO. 0 JOB NO. CAM-011 DATE: 11-2-20 FIGURE NO. 2 CAMERON VILLAGE CONDOMINIUMS1801 CAMERON STREET RALEIGH, NORTH CAROLINA SITE MAP LEGEND SITE PROPERTY BOUNDARY PARCEL BOUNDARY SURFACE WATER FEATURE POLE-MOUNTED TRANSFORMER PAD-MOUNTED TRANSFORMER BOILER ROOM 3921 Sunset Ridge Road, Suite 301 Raleigh, North Carolina 27607 919-847-4241(p) 919-847-4261(f) License # C-1269 / #C-245 Geology CHIK-FIL-A (2000 CAMERON STREET) CHIK-FIL-A(2000 CAMERON STREET) WALLGREENS PHARMACY(1900 CAMERON STREET) WALLGREENS PHARMACY (1900 CAMERON STREET) CAMERON VILLAGESHOPPING CENTER(422 WOODBURN ROAD) CAMERON VILLAGESHOPPING CENTER(422 WOODBURN ROAD) THE VILLAGE GARDENS CONDOMINIUMS (1901, 1921, AND 1941 CLARK AVENUE) THE VILLAGE GARDENS CONDOMINIUMS(1901, 1921, AND 1941 CLARK AVENUE) JORDAN PRICE WALL GRAYJONES AND CARLTON, PLLC(1951 CLARK AVENUE) JORDAN PRICE WALL GRAYJONES AND CARLTON, PLLC(1951 CLARK AVENUE) CAMERON STREETCAMERON STREET EDNA METZ WELLS PARK (1600 PARK DRIVE) EDNA METZ WELLS PARK(1600 PARK DRIVE)BEL LWOOD DR IVEBELLWOOD DR IVE SMAL LWOOD DR IVESMAL LWOOD DR IVE SUT T O N D RI V E SUT T O N D RI V E WOODBURN ROADWOODBURN ROADCLARK AVENUECLARK AVENUE NOTES: 1.AERIAL IMAGERY OBTAINED FROM ESRI SERVICES. UNDEVELOPED LAND (1800 BELLWOOD DRIVE) UNDEVELOPED LAND(1800 BELLWOOD DRIVE) UST INCIDENT#3409 S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Phase I ESA\Figures\Site Map.dwg, FIG 2, 11/2/2020 10:55:54 AM, SVincent REVISION NO. 0 JOB NO. CAM-011 DATE: 11-2-20 FIGURE NO. 3 RECEPTOR SURVEY MAP LEGEND SITE PROPERTY BOUNDARY PARCEL BOUNDARY SURFACE WATER FEATURE 3921 Sunset Ridge Road, Suite 301 Raleigh, North Carolina 27607 919-847-4241(p) 919-847-4261(f) License # C-1269 / #C-245 Geology CAMERON STREET PEACE STREET CLARK AVENUEOBERLIN ROADSMALLWOOD DRIVEDANIELS STREETSU T TON DR I VE ST. MARYS STREETWOOD B U R N R O A D PARK DRIVE WOODBURN ROADBE N E H A N S T R E E T HIL L S B O R O U G H S T R E E T COLLEGE PLACE W PA R K D RI V E E PA R K D RI V E CALVI N R O A DCHAMBERLAIN STREETBEDFORD AVENUE 1,500 F T NOTES: 1.AERIAL IMAGERY OBTAINED FROM NC ONEMAP. CAMERON VILLAGE CONDOMINIUMS1801 CAMERON STREET RALEIGH, NORTH CAROLINA S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Brownfields Assistance\Brownfields Assessment\Figures\Survey Map.dwg, FIG 3, 11/1/2020 6:38:33 PM, SVincent SB-1 SG-3 SG-2 SG-1S/D SG-4 SG-5 SB-2 SG-6 REVISION NO. 0 JOB NO. CAM-011 DATE: 11-2-20 FIGURE NO. 4 CAMERON VILLAGE CONDOMINIUMS1801 CAMERON STREET RALEIGH, NORTH CAROLINA SAMPLE LOCATION MAP LEGEND SITE PROPERTY BOUNDARY PARCEL BOUNDARY SURFACE WATER FEATURE POLE-MOUNTED TRANSFORMER PAD-MOUNTED TRANSFORMER BOILER ROOM PROPOSED BUILDING FOOTPRINT BACKGROUND SOIL SAMPLELOCATION EXTERIOR SOIL VAPOR SAMPLELOCATION 3921 Sunset Ridge Road, Suite 301 Raleigh, North Carolina 27607 919-847-4241(p) 919-847-4261(f) License # C-1269 / #C-245 Geology CHIK-FIL-A (2000 CAMERON STREET) CHIK-FIL-A(2000 CAMERON STREET) WALLGREENS PHARMACY(1900 CAMERON STREET) WALLGREENS PHARMACY (1900 CAMERON STREET) CAMERON VILLAGESHOPPING CENTER(422 WOODBURN ROAD) CAMERON VILLAGESHOPPING CENTER(422 WOODBURN ROAD) THE VILLAGE GARDENS CONDOMINIUMS (1901, 1921, AND 1941 CLARK AVENUE) THE VILLAGE GARDENS CONDOMINIUMS(1901, 1921, AND 1941 CLARK AVENUE) JORDAN PRICE WALL GRAYJONES AND CARLTON, PLLC(1951 CLARK AVENUE) JORDAN PRICE WALL GRAYJONES AND CARLTON, PLLC(1951 CLARK AVENUE) CAMERON STREETCAMERON STREET EDNA METZ WELLS PARK (1600 PARK DRIVE) EDNA METZ WELLS PARK(1600 PARK DRIVE)BEL LWOOD DR IVEBELLWOOD DR IVE SMAL LWOOD DR IVESMAL LWOOD DR IVE SUT T O N D RI V E SUT T O N D RI V E WOODBURN ROADWOODBURN ROADCLARK AVENUECLARK AVENUE NOTES: 1.AERIAL IMAGERY OBTAINED FROM ESRI SERVICES. UNDEVELOPED LAND (1800 BELLWOOD DRIVE) UNDEVELOPED LAND(1800 BELLWOOD DRIVE) UST INCIDENT#3409 PARKING DECKPARKING DECK COURTYARD / POOL COURTYARD /POOL S:\AAA-Master Projects\Camden - CAM\CAM-011 Cameron Village Condominiums\Phase I ESA\Figures\Site Map.dwg, FIG 4, 11/1/2020 6:40:05 PM, SVincent Appendix A Brownfields Receptor Survey Form North Carolina Department of Environmental Quality Division of Waste Management Brownfields Program Site:Cameron Village Condominiums Address:1801 Cameron Street City:Raleigh, NC County:Wake County Brownfields Project Number:24017-20-092 Date 9/8/2020 Property and Building Characteristics a. Provide occupancy and use information. Concrete, brick, panel siding, and stone. Twelve two-story buidlings. c. Describe the foundation construction. Include details on type, floor construction, and depth below grade. Concrete or brick. All buildings had a crawlspace below grade at approximately 0 to 5 feet. Four buildings had boiler rooms. The boiler rooms were in a partial basement below grade at approximately 10-15 feet. All HVAC systems were outside of each multi-tenant residential building. e. Are any subslab ventilation systems or moisture barriers in place? If so, please provide details. N/A Current occupancy is 12 multi-tenant residetial buildings. If an existing building is on-site, please respond to the following. Information can be provided on additional sheets as needed. If numerous buildings are on-site, consult with your PM as only information on specific buildings may be needed. b. Describe the construction of the builidng including materials (e.g. wood frame, block), type and size of openings (e.g. windows, bay doors), and height (number of stories). % of property that is covered by buildings BROWNFIELDS PROPERTY RECEPTOR SURVEY This form was created to clarify and simplify preparing a receptor survey for a brownfield site. Please provide the information requested below. Distances are measured from the site property boundary unless otherwise indicated by the DEQ Brownfield’s Project Manager (PM). Current Usage Proposed UsageSurface Conditions % of property that is grassed areas % of property that is agricultural crops % of property that is paved 35 NASize of Property (acres) % of property that is wooded/brush 4.91 10 50 d. Describe the HVAC system in the building. Include available details on type, equipment location, source of air return, and design considerations (e.g. positive pressure?). 0 5 Rev. 09/2015 Page 1 of 4 North Carolina Department of Environmental Quality Division of Waste Management Brownfields Program Surrounding Property Land Use North South East West Y 250 East Y <100 North East South Y <50 <250 <250 <250 <1,000 <1,000 West South South South Southeast Southeast Utilities Is there a septic system on-site? (Y or N) ___N______ Please provide the utility providers for the subject property a. Natural Gas ___________________________ b. Sewer ___City of Raleigh c. Electricity ___________________________ d. Other __________________________ For surrounding properties, please complete the following table with available information. Y Y Unknown Y Y Same Same Same Is there a basement within 1,000 ft of the Property Broughton High School 723 St. Marys Street Is there a residence within 1,000 ft of the Property? Utility/Potential Receptor Is a storm water pipe within 100 ft of the Property boundary? Is a sanitary sewer within 100 ft of the Property boundary? Several 1930 Clark Avenue (Parking Deck) 1616 Park Drive (residential) 1622 Park Drive (residential) 1624 Park Drive (residential) 1913 West Johnson Street (residential) 1911 West Johnson Street (residential) Is a water line main within 100 ft of Property boundary? Is a natural gas line main within 100 ft of the Property boundary? Is a septic system leach field within 500 ft of the Property boundary? Direction Commercial and Multi-tenant Residences Undeveloped land with Multi-tenant Residences beyond Multi-tenant Commercial For the subject property, please provide a map of known buried utilites. If available, include depth to top, construction material, and diameter of the utilities. In addition, please provide the following information on utilty providers. If additional assessment is required, the public utility locators should be contacted. This information can then be added to a site map. Y/N * Is a school or daycare center within 1,000 ft of the Property? Specific Land Uses of Interest Y/N * * If numerous facilities of interest are present, their locations can be placed on a map in lieu of providing specific addresses. Distance (ft) DirectionDistance (ft)Address Same Please provide information on the following land uses in the vicinity of the subject site, including a map of the surrounding areas. If specific receptors are present, please provide addresses of the facilities. Commercial with Multi-tenant Residences beyond Zoning/Land Use Proposed Usage Current Use/Occupant Rev. 09/2015 Page 2 of 4 North Carolina Department of Environmental Quality Division of Waste Management Brownfields Program Y YIs a buried electrical cable main within 100 ft of Property boundary? * If yes, please provide a map or detailed information (distance, direction, depth) of the utility in correlation with the subject property. Is a buried telephone/ cable main within 100 ft of the Property boundary? Rev. 09/2015 Page 3 of 4 North Carolina Department of Environmental Quality Division of Waste Management Brownfields Program Water Supply What is the potable water supply for the property? Public __X____ Private ______ N N N Surface Water & Wetlands NA Unnamed Tributary 720 feet south No. Based on U.S. Fish and Wildlife National Wetlands Inventory Review (9/8/20). b. List the uses of the water body. c. What is the source of the water for the water body? d. What is the nature of the bottom of the water body (e.g., rocky or concrete bottom, drainage ways or impoundments) If no on-site surface water features, what is the nearest surface water body? Are there any wetlands present on the property? If no wetlands on-site, are wetlands suspected on adjoining properties? NA NA Is a public water supply well within 1 mile of the Property boundary? Is a private water supply well within 1,500 ft of the Property bd?Is an irrigation well within 1,500 ft of the Property boundary? Response/Comments The purpose of this section is to provide information on the presence of surface waters and/or wetlands on, or in the vicinity of the Property. If Private, please provide details of the water supply source (i.e. well location, well construction, etc). If public, please include the water providers name. The purpose of this section is to provide information on the water supply for the site and surrounding areas. a. Is the water body naturally developed or man-made?NA Y/NWater Supply Wells Please provide the following information regarding water supply wells in the vicinity of the Property. At a minimum, a windshield survey within 1,500 ft of the property boundaries should be completed to determine if water supply or irrigation wells may be present. Information from applicable databases can and should be utilized; however, should not be utilized in lieu of the windshield survey. If multiple wells are present within the requested radius, please provide a map of the well locations. If needed, please attach a separate table to list all wells. Please note, the PM may opt for a more extensive water supply well survey if needed. Are there surface water features on the property? (If yes, please complete a. to d.) Provide Information regarding Surface Water and Wetlands Distance (ft)Direction Address No Rev. 09/2015 Page 4 of 4 Disclaimer iMaps makes every effort to produce and publish the most current and accurate information possible. However, the maps are produced for information purposes, and are NOT surveys. No warranties, expressed or implied ,are provided for the data therein, its use,or its interpretation. 0 850 1,700425 ft 1 inch = 800 feet±APPROXIMATE 1,500-FOOT RADIUS FROM SITE USGS STREAM (ACCORDING TO WAKE COUNTY IMAPS) GPS VERIFIED WELL LOCATION (ACCORDING TO WAKE COUNTY IMAPS) Appendix B Boring Logs NOTES: Hole precleared to 2' using hand auger. Samples were analyzed for RCRA Metals and Hexavalent Chromium. generated using GroundLogs.online Client: Project: Address: Camden CAM-011 1801 Cameron Street, Raleigh, NC BORING LOG Boring No. Page: SB-1 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By:Jayna Sananikone Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Ground Surface Elev. (ft): Location (X,Y): 2.0 DEPTH (ft)LITHOLOGYWATER LEVELBORINGCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 1 2 3 4 5 (0') Poorly graded SAND (SP); loose, dry, brown (0.5') Poorly graded SAND (SP); loose, dry, orange (2') Boring terminated 1.3 1.4 0 1 2 3 4 5 Grab Hand Auger Hand Auger 9/9/20 9/9/20 H&H H&H SB-1 NOTES: Hole precleared on 9/9/2020 using hand auger. Samples were analyzed for RCRA Metals and Hexavalent Chromium. generated using GroundLogs.online Client: Project: Address: Camden CAM-011 1801 Cameron Street, Raleigh, NC BORING LOG Boring No. Page: SB-2 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By:Jayna Sananikone Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Ground Surface Elev. (ft): Location (X,Y): 2.0 DEPTH (ft)LITHOLOGYWATER LEVELBORINGCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 1 2 3 4 5 (0') Poorly graded SAND (SP); loose, dry, brown (1') Poorly graded SAND (SP); loose, dry, reddish, orange (2') Boring terminated 1.2 1.2 SB-1SB-2 0 1 2 3 4 5 9/9/20 9/9/20 H&H Hand Auger Hand Auger H&H Grab NOTES: Hole precleared on 9/9/2020 using hand auger. generated using GroundLogs.online Client: Project: Address: Camden CAM-011 1801 Cameron Street, Raleigh, NC BORING LOG Boring No. Page: SG-1S/1D 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: Direct Push Jayna Sananikone Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Ground Surface Elev. (ft): Location (X,Y): 14.0 DEPTH (ft)LITHOLOGYWATER LEVELBORINGCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 (0') Lean CLAY (CL); medium plasticity, soft, dry, brown (1') Lean CLAY (CL); medium plasticity, hard, dry, orange (4') As Above (6') Sandy SILT (ML); soft, dry, yellowish (8') As Above: reddish (10') Poorly graded SAND with silt (SP-SM); loose, dry, white (14') Boring terminated 0.2 0.2 0.3 0.4 0.2 0.6 0.4 0.5 0.5 0.5 0.4 0.7 0.4 0.3 0 5 10 15 9/9/20 9/9/20 GeoProbe Regional Probing NOTES: Hole precleared on 09/09/2020 using hand auger. generated using GroundLogs.online Client: Project: Address: Camden CAM-011 1801 Cameron Street, Raleigh, NC BORING LOG Boring No. Page: SG-2 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: Direct Push Jayna Sananikone Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Ground Surface Elev. (ft): Location (X,Y): 8.0 DEPTH (ft)LITHOLOGYWATER LEVELBORINGCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 (0') Lean CLAY (CL); medium plasticity, soft, dry, reddish-brown (2') Poorly graded SAND with silt (SP-SM); loose, dry, orange (3') Lean CLAY (CL); medium plasticity, hard, dry, reddish (4') As Above: mica (8') Boring terminated 4.9 5.0 5.1 5.1 4.5 5.6 4.8 4.4 0 5 10 9/9/20 9/9/20 GeoProbe Regional Probing NOTES: Hole precleared on 09/09/2020 using hand auger. generated using GroundLogs.online Client: Project: Address: Camden CAM-011 1801 Cameron Street, Raleigh, NC BORING LOG Boring No. Page: SG-3 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: Direct Push Jayna Sananikone Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Ground Surface Elev. (ft): Location (X,Y): 8.0 DEPTH (ft)LITHOLOGYWATER LEVELBORINGCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 (0') Sandy SILT (ML); soft, dry, reddish, orange (3') Lean CLAY (CL); medium plasticity, soft, dry, reddish, mica (3.5') SILT with sand (ML); soft, dry, orange, mica (5') As Above (7.5') SILT with sand (ML); soft, dry, white, black mottling (8') Boring terminated 10.7 15.6 5.8 8.2 7.6 6.2 5.2 8.4 0 5 10 9/9/20 9/9/20 GeoProbe Regional Probing NOTES: Hole precleared on 9/9/2020 using hand auger. generated using GroundLogs.online Client: Project: Address: Camden CAM-011 1801 Cameron Street, Raleigh, NC BORING LOG Boring No. Page: SG-4 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: Direct Push Jayna Sananikone Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Ground Surface Elev. (ft): Location (X,Y): 8.0 DEPTH (ft)LITHOLOGYWATER LEVELBORINGCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 (0') Poorly graded SAND with silt (SP-SM); loose, dry, brown (0.5') Lean CLAY (CL); medium plasticity, hard, dry, reddish, orange (2') Lean CLAY (CL); medium plasticity, hard, dry, yellowish, orange (4') As Above: soft (6') Lean CLAY (CL); medium plasticity, soft, moist, gray, orange (8') Boring terminated 3.9 4.0 4.0 4.5 5.1 4.4 3.8 3.2 0 5 10 9/9/20 9/9/20 GeoProbe Regional Probing NOTES: Hole precleared on 09/09/2020 using hand auger. generated using GroundLogs.online Client: Project: Address: Camden CAM-011 1801 Cameron Street, Raleigh, NC BORING LOG Boring No. Page: SG-5 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: Direct Push Jayna Sananikone Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Ground Surface Elev. (ft): Location (X,Y): 8.0 DEPTH (ft)LITHOLOGYWATER LEVELBORINGCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 (0') Poorly graded SAND with silt (SP-SM); loose, dry, brown (0.5') Lean CLAY (CL); medium plasticity, hard, dry, reddish, orange (2') Lean CLAY (CL); medium plasticity, hard, dry, yellowish, orange (4') As Above: soft (6') Lean CLAY (CL); medium plasticity, soft, moist, gray, orange (8') Boring terminated 3.9 4.0 4.0 4.5 5.1 4.4 3.8 3.2 0 5 10 9/9/20 9/9/20 GeoProbe Regional Probing NOTES: Hole precleared on 09/09/2020 using hand auger. generated using GroundLogs.online Client: Project: Address: Camden CAM-011 1801 Cameron Street, Raleigh, NC BORING LOG Boring No. Page: SG-6 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: Direct Push Jayna Sananikone Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Ground Surface Elev. (ft): Location (X,Y): 8.0 DEPTH (ft)LITHOLOGYWATER LEVELBORINGCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 (0') SILT (ML); soft, dry, reddish-brown (1') SILT with sand (ML); soft, dry, reddish, orange (4') SILT with sand (ML); soft, dry, gray (5') Poorly graded SAND with silt (SP-SM); loose, dry, brown, gray (6') Poorly graded SAND with silt (SP-SM); loose, dry, white, gray (7.5') SILT with sand (ML); hard, dry, bluish-gray (8') Boring terminated 2.3 2.3 3.1 2.4 3.2 2.7 3.0 2.2 0 5 10 9/9/20 9/9/20 GeoProbe Regional Probing Appendix C Laboratory Analytical Report 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 September 18, 2020 Justin Ballard Hart & Hickman - Raleigh, NC 3921 Sunset Ridge Rd., Suite 301 Raleigh, NC 27607 Project Location: Raleigh, NC Client Job Number: Project Number: CAM-011 Laboratory Work Order Number: 20I0531 Enclosed are results of analyses for samples received by the laboratory on September 9, 2020. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kerry K. McGee Project Manager Page 1 of 28 Table of Contents Table of Contents Sample Summary 3 Case Narrative 4 Sample Results 5 20I0531-01 5 20I0531-02 8 Sample Preparation Information 11 QC Data 12 Metals Analyses (Total) 12 B266230 12 B266283 12 Flag/Qualifier Summary 13 Certifications 14 Chain of Custody/Sample Receipt 15 Page 2 of 28 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY 9/18/2020 Hart & Hickman - Raleigh, NC 3921 Sunset Ridge Rd., Suite 301 Raleigh, NC 27607 ATTN: Justin Ballard CAM-011 20I0531 The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB Raleigh, NC CAM-011 SB-1 (1-2)20I0531-01 Soil Method 7199 CT PH-0197/NY11742 SM 2540G SW-846 CT PH-0197/NY11742 SW-846 6020B SW-846 7471B SB-2 (1-2)20I0531-02 Soil Method 7199 CT PH-0197/NY11742 SM 2540G SW-846 CT PH-0197/NY11742 SW-846 6020B SW-846 7471B [TOC_1]Sample Summary[TOC] Page 3 of 28 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. [TOC_1]Case Narrative[TOC] The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Lisa A. Worthington Technical Representative Page 4 of 28 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 9/9/2020 Work Order: 20I0531Sample Description:Project Location: Raleigh, NC Sample ID: 20I0531-01 Field Sample #: SB-1 (1-2) Sample Matrix: Soil Sampled: 9/9/2020 12:45 [TOC_2]20I0531-01[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Metals Analyses (Total) 0.49 0.19 9/14/20 11:29 QNWmg/Kg dry0.13 9/10/20SW-846 6020B5Arsenic 13 4.7 9/14/20 11:29 QNWmg/Kg dry0.61 9/10/20SW-846 6020B5Chromium 17 1.9 9/14/20 11:29 QNWmg/Kg dry0.15 9/10/20SW-846 6020B5Lead ND 0.028 9/14/20 11:48 CJVmg/Kg dry0.0084 9/11/20SW-846 7471B1Mercury ND 1.5 9/14/20 11:29 QNWmg/Kg dry0.38 9/10/20SW-846 6020B5Selenium ND 0.095 9/14/20 11:29 QNWmg/Kg dry0.034 9/10/20SW-846 6020B5Silver 22 9.5 9/14/20 11:29 QNWmg/Kg dry0.61 9/10/20SW-846 6020B5Barium ND 0.38 9/14/20 11:29 QNWmg/Kg dry0.053 9/10/20SW-846 6020B5Cadmium [TOC_1]Sample Results[TOC] Page 5 of 28 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 9/9/2020 Work Order: 20I0531Sample Description:Project Location: Raleigh, NC Sample ID: 20I0531-01 Field Sample #: SB-1 (1-2) Sample Matrix: Soil Sampled: 9/9/2020 12:45 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Conventional Chemistry Parameters by EPA/APHA/SW-846 Methods (Total) 88.5 9/14/20 7:34 AVF% Wt 9/12/20SM 2540G1% Solids Page 6 of 28 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 9/9/2020 Work Order: 20I0531Sample Description:Project Location: Raleigh, NC Sample ID: 20I0531-01 Field Sample #: SB-1 (1-2) Sample Matrix: Soil Sampled: 9/9/2020 12:45 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Conventional Chemistry Parameters by EPA/APHA/SW-846 Methods (Total) Attached Attached 9/17/20 14:57 PALmg/KgAttached Method 71991Hexavalent Chromium Page 7 of 28 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 9/9/2020 Work Order: 20I0531Sample Description:Project Location: Raleigh, NC Sample ID: 20I0531-02 Field Sample #: SB-2 (1-2) Sample Matrix: Soil Sampled: 9/9/2020 13:25 [TOC_2]20I0531-02[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Metals Analyses (Total) 1.1 0.20 9/14/20 11:32 QNWmg/Kg dry0.14 9/10/20SW-846 6020B5Arsenic 29 5.0 9/14/20 11:32 QNWmg/Kg dry0.65 9/10/20SW-846 6020B5Chromium 14 2.0 9/14/20 11:32 QNWmg/Kg dry0.16 9/10/20SW-846 6020B5Lead 0.024 0.031 9/14/20 11:50 CJVmg/Kg dry0.0092 9/11/20SW-846 7471B1JMercury ND 1.6 9/14/20 11:32 QNWmg/Kg dry0.41 9/10/20SW-846 6020B5Selenium 0.045 0.10 9/14/20 11:32 QNWmg/Kg dry0.036 9/10/20SW-846 6020B5JSilver 38 10 9/14/20 11:32 QNWmg/Kg dry0.65 9/10/20SW-846 6020B5Barium ND 0.40 9/14/20 11:32 QNWmg/Kg dry0.057 9/10/20SW-846 6020B5Cadmium Page 8 of 28 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 9/9/2020 Work Order: 20I0531Sample Description:Project Location: Raleigh, NC Sample ID: 20I0531-02 Field Sample #: SB-2 (1-2) Sample Matrix: Soil Sampled: 9/9/2020 13:25 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Conventional Chemistry Parameters by EPA/APHA/SW-846 Methods (Total) 82.4 9/14/20 7:34 AVF% Wt 9/12/20SM 2540G1% Solids Page 9 of 28 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 9/9/2020 Work Order: 20I0531Sample Description:Project Location: Raleigh, NC Sample ID: 20I0531-02 Field Sample #: SB-2 (1-2) Sample Matrix: Soil Sampled: 9/9/2020 13:25 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Conventional Chemistry Parameters by EPA/APHA/SW-846 Methods (Total) Attached Attached 9/17/20 15:05 PALmg/KgAttached Method 71991Hexavalent Chromium Page 10 of 28 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Sample Extraction Data Prep Method: % Solids Analytical Method: SM 2540G Lab Number [Field ID]Batch Date B266342 09/12/2020I0531-01 [SB-1 (1-2)] B266342 09/12/2020I0531-02 [SB-2 (1-2)] Prep Method: SW-846 3050B Analytical Method: SW-846 6020B Lab Number [Field ID]Batch DateInitial [g]Final [mL] B266230 09/10/201.49 50.020I0531-01 [SB-1 (1-2)] B266230 09/10/201.50 50.020I0531-02 [SB-2 (1-2)] Prep Method: SW-846 7471 Analytical Method: SW-846 7471B Lab Number [Field ID]Batch DateInitial [g]Final [mL] B266283 09/11/200.605 50.020I0531-01 [SB-1 (1-2)] B266283 09/11/200.592 50.020I0531-02 [SB-2 (1-2)] [TOC_1]Sample Preparation Information[TOC] Page 11 of 28 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Metals Analyses (Total) - Quality Control QUALITY CONTROL [TOC_2]Metals Analyses (Total)[TOC] Batch B266230 - SW-846 3050B [TOC_3]B266230[TOC] Blank (B266230-BLK1) Prepared: 09/10/20 Analyzed: 09/14/20 Arsenic mg/Kg wet0.17ND Chromium mg/Kg wet4.2ND Lead mg/Kg wet1.7ND Selenium mg/Kg wet1.3ND Silver mg/Kg wet0.083ND Barium mg/Kg wet8.3ND Cadmium mg/Kg wet0.33ND LCS (B266230-BS1) Prepared: 09/10/20 Analyzed: 09/14/20 Arsenic mg/Kg wet2.0 97.6 82.8-116.897.094.6 Chromium mg/Kg wet50 147 81.6-117.7109160 Lead mg/Kg wet20 105 82.6-117.199.3104 Selenium mg/Kg wet16 93.1 78.9-121.498.791.9 Silver mg/Kg wet0.99 32.0 79.7-12098.631.6 Barium mg/Kg wet99 320 82.5-117.598.9316 Cadmium mg/Kg wet4.0 114 82.8-117.5104119 LCS Dup (B266230-BSD1) Prepared: 09/10/20 Analyzed: 09/14/20 Arsenic mg/Kg wet2.0 97.6 3082.8-116.898.7 1.8196.4 Chromium mg/Kg wet50 147 3081.6-117.7108 0.140159 Lead mg/Kg wet20 105 3082.6-117.1105 5.46110 Selenium mg/Kg wet16 93.1 3078.9-121.4101 2.5094.2 Silver mg/Kg wet1.0 32.0 3079.7-120104 4.8233.1 Barium mg/Kg wet100 320 2082.5-117.5101 2.56325 Cadmium mg/Kg wet4.0 114 2082.8-117.5105 0.812120 Batch B266283 - SW-846 7471 [TOC_3]B266283[TOC] Blank (B266283-BLK1) Prepared: 09/11/20 Analyzed: 09/14/20 Mercury mg/Kg wet0.025ND LCS (B266283-BS1) Prepared: 09/11/20 Analyzed: 09/14/20 Mercury mg/Kg wet0.38 5.99 74.1-1261076.43 LCS Dup (B266283-BSD1) Prepared: 09/11/20 Analyzed: 09/14/20 Mercury mg/Kg wet0.37 5.99 2074.1-126100 6.876.00 [TOC_1]QC Data[TOC] Page 12 of 28 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 FLAG/QUALIFIER SUMMARY *QC result is outside of established limits. Wide recovery limits established for difficult compound. Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. No results have been blank subtracted unless specified in the case narrative section. RL Reporting Limit is at the level of quantitation (LOQ) DL Detection Limit is the lower limit of detection determined by the MDL study MCL Maximum Contaminant Level ND Not Detected Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J [TOC_1]Flag/Qualifier Summary[TOC] Page 13 of 28 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report SW-846 in Soil NY,CT,NH,NC,ME,VAHexavalent Chromium SW-846 6020B in Soil NY,VA,NH,NC,MEArsenic NY,NC,MEChromium NY,NC,MELead NY,VA,NH,NC,MESelenium NY,NC,MESilver NY,NCBarium NY,NC,MECadmium SW-846 7471B in Soil CT,NH,NY,NC,ME,VAMercury [TOC_1]Certifications[TOC] The CON-TEST Environmental Laboratory operates under the following certifications and accreditations: Code Description Number Expires 100033AIHA-LAP, LLC - ISO17025:2017AIHA 03/1/2022 M-MA100Massachusetts DEPMA 06/30/2021 PH-0567Connecticut Department of Publilc HealthCT 09/30/2021 10899 NELAPNew York State Department of HealthNY 04/1/2021 2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2021 LAO00112Rhode Island Department of HealthRI 12/30/2020 652North Carolina Div. of Water QualityNC 12/31/2020 MA007 NELAPNew Jersey DEPNJ 06/30/2021 E871027 NELAPFlorida Department of HealthFL 06/30/2021 LL015036Vermont Department of Health Lead LaboratoryVT 07/30/2021 2011028State of MaineME 06/9/2021 460217Commonwealth of VirginiaVA 12/14/2020 2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2021 VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2021 25703North Carolina Department of HealthNC-DW 07/31/2021 68-05812Commonwealth of Pennsylvania DEPPA 06/30/2021 9100Dept. of Env, Great Lakes, and EnergyMI 10/1/2020 Page 14 of 28 Table of Contents Page 15 of 28 Table of Contents Page 16 of 28 Table of Contents Page 17 of 28 Table of Contents $1$/<7,&$/5(3257 6HSWHPEHU &RQWHVW/DEV 6DPSOH’HOLYHU\*URXS / 6DPSOHV5HFHLYHG 3URMHFW1XPEHU ’HVFULSWLRQ 6LWH , 5HSRUW7R .HUU\0F*HH 6SUXFH6WUHHW (DVW/RQJPHDGRZ0$ (QWLUH5HSRUW5HYLHZHG%\ 6HSWHPEHU >3UHOLPLQDU\5HSRUW@ ’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’*’$7(7,0(3$*( &RQWHVW/DEV /RI 6HSWHPEHU ’DSKQH5LFKDUGV 3URMHFW0DQDJHU $&&2817 352-(&7 6’*’$7(7,0(3$*( &RQWHVW/DEV /RI Page 18 of 28 Table of Contents 21(/$%1$7,21:,’(7$%/(2)&217(176 &S&RYHU3DJH 7F7DEOHRI&RQWHQWV 6V6DPSOH6XPPDU\ &Q&DVH1DUUDWLYH 6U6DPSOH5HVXOWV ,/ ,/ 4F4XDOLW\&RQWURO6XPPDU\ 7RWDO6ROLGVE\0HWKRG* :HW&KHPLVWU\E\0HWKRG *O*ORVVDU\RI7HUPV $O$FFUHGLWDWLRQV/RFDWLRQV 6F6DPSOH&KDLQRI&XVWRG\ &S 7F 6V &Q 6U 4F *O $O 6F $&&2817 352-(&7 6’*’$7(7,0(3$*( &RQWHVW/DEV /RI $&&2817 352-(&7 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21(/$%1$7,21:,’(48$/,7<&21752/6800$5<:*7RWDO6ROLGVE\0HWKRG*/0HWKRG%ODQN0%0%50%5HVXOW0%4XDOLILHU0%0’/0%5’/$QDO\WH7RWDO6ROLGV/2ULJLQDO6DPSOH26^’XSOLFDWH’8326/^’8352ULJLQDO5HVXOW’835HVXOW’LOXWLRQ’8353’’834XDOLILHU’8353’/LPLWV$QDO\WH7RWDO6ROLGV/DERUDWRU\&RQWURO6DPSOH/&6/&656SLNH$PRXQW/&65HVXOW/&65HF5HF/LPLWV/&64XDOLILHU$QDO\WH7RWDO6ROLGV&S7F6V&Q6U4F*O$O6F$&&2817352-(&76’*’$7(7,0(3$*(&RQWHVW/DEV/RI$&&2817352-(&76’*’$7(7,0(3$*(&RQWHVW/DEV/RIPage 24 of 28Table of Contents 21(/$%1$7,21:,’(48$/,7<&21752/6800$5<:*:HW&KHPLVWU\E\0HWKRG/0HWKRG%ODQN0%0%50%5HVXOW0%4XDOLILHU0%0’/0%5’/$QDO\WHPJNJ PJNJ PJNJ+H[DYDOHQW&KURPLXP8/2ULJLQDO6DPSOH26^’XSOLFDWH’8326/^’8352ULJLQDO5HVXOW’835HVXOW’LOXWLRQ’8353’’834XDOLILHU’8353’/LPLWV$QDO\WHPJNJ PJNJ+H[DYDOHQW&KURPLXP8 8/DERUDWRU\&RQWURO6DPSOH/&6/&656SLNH$PRXQW/&65HVXOW/&65HF5HF/LPLWV/&64XDOLILHU$QDO\WHPJNJ PJNJ+H[DYDOHQW&KURPLXP&S7F6V&Q6U4F*O$O6F$&&2817352-(&76’*’$7(7,0(3$*(&RQWHVW/DEV/RI$&&2817352-(&76’*’$7(7,0(3$*(&RQWHVW/DEV/RIPage 25 of 28Table of Contents 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6’*’$7(7,0(3$*( &RQWHVW/DEV /RI $&&2817 352-(&7 6’*’$7(7,0(3$*( &RQWHVW/DEV /RI Page 27 of 28 Table of Contents Page 28 of 28Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 September 17, 2020 Justin Ballard Hart & Hickman - Raleigh, NC 3921 Sunset Ridge Rd., Suite 301 Raleigh, NC 27607 Project Location: Raleigh, NC Client Job Number: Project Number: CAM-011 Laboratory Work Order Number: 20I0754 Enclosed are results of analyses for samples received by the laboratory on September 10, 2020. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kerry K. McGee Project Manager QA Officer Katherine Allen Laboratory Manager Daren Damboragian Page 1 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY 9/17/2020Hart & Hickman - Raleigh, NC 3921 Sunset Ridge Rd., Suite 301 Raleigh, NC 27607 ATTN: Justin Ballard CAM-011 20I0754 The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB Raleigh, NC CAM-011 SG-1D 20I0754-01 Soil Gas EPA TO-15 SG-2 20I0754-02 Soil Gas EPA TO-15 SG-3 20I0754-03 Soil Gas EPA TO-15 SG-4 20I0754-04 Soil Gas EPA TO-15 SG-5 20I0754-05 Soil Gas EPA TO-15 SG-6 20I0754-06 Soil Gas EPA TO-15 DUP-1 20I0754-07 Soil Gas EPA TO-15 Page 2 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Lisa A. Worthington Technical Representative Page 3 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Date Received: 9/10/2020 Work Order: 20I0754Sample Description/Location: Field Sample #: SG-1D Sample ID: 20I0754-01 Sample Matrix: Soil Gas Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -3 Receipt Vacuum(in Hg): -5.6 Sampled: 9/10/2020 09:36 Canister ID: 2316 Flow Controller ID: 4336 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 8.0 8.0 9/17/20 2:13 BRFJ19 4194.8 11 Benzene 1.1 0.20 9/17/20 2:13 BRF3.5 40.640.058 0.19 Benzyl chloride ND 0.20 9/17/20 2:13 BRFND41.00.090 0.47 Bromodichloromethane ND 0.20 9/17/20 2:13 BRFND41.30.056 0.37 Bromoform ND 0.20 9/17/20 2:13 BRFND42.10.069 0.71 Bromomethane ND 0.20 9/17/20 2:13 BRFND40.780.11 0.41 1,3-Butadiene ND 0.20 9/17/20 2:13 BRFND40.440.15 0.32 2-Butanone (MEK)1.9 8.0 9/17/20 2:13 BRFJ5.6 4240.66 2.0 Carbon Disulfide ND 2.0 9/17/20 2:13 BRFND46.20.51 1.6 Carbon Tetrachloride ND 0.20 9/17/20 2:13 BRFND41.30.053 0.33 Chlorobenzene ND 0.20 9/17/20 2:13 BRFND40.920.048 0.22 Chloroethane ND 0.20 9/17/20 2:13 BRFND40.530.20 0.52 Chloroform 3.3 0.20 9/17/20 2:13 BRF16 40.980.048 0.24 Chloromethane ND 0.40 9/17/20 2:13 BRFND40.830.15 0.32 Cyclohexane ND 0.20 9/17/20 2:13 BRFND40.690.098 0.34 Dibromochloromethane ND 0.20 9/17/20 2:13 BRFND41.70.067 0.57 1,2-Dibromoethane (EDB)ND 0.20 9/17/20 2:13 BRFND41.50.052 0.40 1,2-Dichlorobenzene ND 0.20 9/17/20 2:13 BRFND41.20.074 0.44 1,3-Dichlorobenzene ND 0.20 9/17/20 2:13 BRFND41.20.073 0.44 1,4-Dichlorobenzene ND 0.20 9/17/20 2:13 BRFND41.20.045 0.27 Dichlorodifluoromethane (Freon 12)ND 0.20 9/17/20 2:13 BRFND40.990.063 0.31 1,1-Dichloroethane ND 0.20 9/17/20 2:13 BRFND40.810.063 0.25 1,2-Dichloroethane ND 0.20 9/17/20 2:13 BRFND40.810.073 0.30 1,1-Dichloroethylene ND 0.20 9/17/20 2:13 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 9/17/20 2:13 BRFND40.790.068 0.27 trans-1,2-Dichloroethylene ND 0.20 9/17/20 2:13 BRFND40.790.059 0.23 1,2-Dichloropropane ND 0.20 9/17/20 2:13 BRFND40.920.072 0.33 cis-1,3-Dichloropropene ND 0.20 9/17/20 2:13 BRFND40.910.093 0.42 trans-1,3-Dichloropropene ND 0.20 9/17/20 2:13 BRFND40.910.067 0.30 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 9/17/20 2:13 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 9/17/20 2:13 BRFND47.20.56 2.0 Ethanol 35 8.0 9/17/20 2:13 BRF66 4152.4 4.6 Ethyl Acetate ND 2.0 9/17/20 2:13 BRFND47.21.2 4.3 Ethylbenzene 10 0.20 9/17/20 2:13 BRF45 40.870.042 0.18 4-Ethyltoluene 8.3 0.20 9/17/20 2:13 BRF41 40.980.062 0.30 Heptane 2.1 0.20 9/17/20 2:13 BRF8.7 40.820.086 0.35 Hexachlorobutadiene ND 0.20 9/17/20 2:13 BRFND42.10.088 0.94 Hexane ND 8.0 9/17/20 2:13 BRFND4280.36 1.3 2-Hexanone (MBK)ND 0.20 9/17/20 2:13 BRFND40.820.11 0.46 Isopropanol ND 8.0 9/17/20 2:13 BRFND4201.8 4.5 Methyl tert-Butyl Ether (MTBE)ND 0.20 9/17/20 2:13 BRFND40.720.080 0.29 Methylene Chloride ND 2.0 9/17/20 2:13 BRFND46.90.46 1.6 4-Methyl-2-pentanone (MIBK)3.4 0.20 9/17/20 2:13 BRF14 40.820.10 0.43 Naphthalene ND 0.20 9/17/20 2:13 BRFND41.00.11 0.59 Propene ND 8.0 9/17/20 2:13 BRFND4140.67 1.2 Styrene 1.3 0.20 9/17/20 2:13 BRF5.5 40.850.057 0.24 1,1,2,2-Tetrachloroethane ND 0.20 9/17/20 2:13 BRFND41.40.053 0.37 Page 4 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Date Received: 9/10/2020 Work Order: 20I0754Sample Description/Location: Field Sample #: SG-1D Sample ID: 20I0754-01 Sample Matrix: Soil Gas Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -3 Receipt Vacuum(in Hg): -5.6 Sampled: 9/10/2020 09:36 Canister ID: 2316 Flow Controller ID: 4336 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 5.8 0.20 9/17/20 2:13 BRF40 41.40.065 0.44 Tetrahydrofuran 1.2 2.0 9/17/20 2:13 BRFJ3.6 45.90.49 1.5 Toluene 30 0.20 9/17/20 2:13 BRF110 40.750.058 0.22 1,2,4-Trichlorobenzene ND 0.20 9/17/20 2:13 BRFND41.50.12 0.91 1,1,1-Trichloroethane ND 0.20 9/17/20 2:13 BRFND41.10.065 0.36 1,1,2-Trichloroethane ND 0.20 9/17/20 2:13 BRFND41.10.073 0.40 Trichloroethylene 0.34 0.20 9/17/20 2:13 BRF1.8 41.10.074 0.40 Trichlorofluoromethane (Freon 11)0.60 0.80 9/17/20 2:13 BRFJ3.4 44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 9/17/20 2:13 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene 42 0.20 9/17/20 2:13 BRF210 40.980.046 0.22 1,3,5-Trimethylbenzene 18 0.20 9/17/20 2:13 BRF89 40.980.052 0.26 Vinyl Acetate ND 4.0 9/17/20 2:13 BRFND4140.56 2.0 Vinyl Chloride ND 0.20 9/17/20 2:13 BRFND40.510.11 0.29 m&p-Xylene 55 0.40 9/17/20 2:13 BRF240 41.70.070 0.30 o-Xylene 16 0.20 9/17/20 2:13 BRF70 40.870.054 0.23 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)102 9/17/20 2:1370-130 Page 5 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Date Received: 9/10/2020 Work Order: 20I0754Sample Description/Location: Field Sample #: SG-2 Sample ID: 20I0754-02 Sample Matrix: Soil Gas Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -3 Receipt Vacuum(in Hg): -4.6 Sampled: 9/10/2020 12:30 Canister ID: 2342 Flow Controller ID: 4324 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 8.1 8.0 9/17/20 2:54 BRF19 4194.8 11 Benzene 1.0 0.20 9/17/20 2:54 BRF3.3 40.640.058 0.19 Benzyl chloride ND 0.20 9/17/20 2:54 BRFND41.00.090 0.47 Bromodichloromethane ND 0.20 9/17/20 2:54 BRFND41.30.056 0.37 Bromoform ND 0.20 9/17/20 2:54 BRFND42.10.069 0.71 Bromomethane ND 0.20 9/17/20 2:54 BRFND40.780.11 0.41 1,3-Butadiene ND 0.20 9/17/20 2:54 BRFND40.440.15 0.32 2-Butanone (MEK)1.7 8.0 9/17/20 2:54 BRFJ4.9 4240.66 2.0 Carbon Disulfide ND 2.0 9/17/20 2:54 BRFND46.20.51 1.6 Carbon Tetrachloride ND 0.20 9/17/20 2:54 BRFND41.30.053 0.33 Chlorobenzene ND 0.20 9/17/20 2:54 BRFND40.920.048 0.22 Chloroethane ND 0.20 9/17/20 2:54 BRFND40.530.20 0.52 Chloroform 5.5 0.20 9/17/20 2:54 BRF27 40.980.048 0.24 Chloromethane ND 0.40 9/17/20 2:54 BRFND40.830.15 0.32 Cyclohexane ND 0.20 9/17/20 2:54 BRFND40.690.098 0.34 Dibromochloromethane ND 0.20 9/17/20 2:54 BRFND41.70.067 0.57 1,2-Dibromoethane (EDB)ND 0.20 9/17/20 2:54 BRFND41.50.052 0.40 1,2-Dichlorobenzene ND 0.20 9/17/20 2:54 BRFND41.20.074 0.44 1,3-Dichlorobenzene ND 0.20 9/17/20 2:54 BRFND41.20.073 0.44 1,4-Dichlorobenzene ND 0.20 9/17/20 2:54 BRFND41.20.045 0.27 Dichlorodifluoromethane (Freon 12)ND 0.20 9/17/20 2:54 BRFND40.990.063 0.31 1,1-Dichloroethane ND 0.20 9/17/20 2:54 BRFND40.810.063 0.25 1,2-Dichloroethane ND 0.20 9/17/20 2:54 BRFND40.810.073 0.30 1,1-Dichloroethylene ND 0.20 9/17/20 2:54 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 9/17/20 2:54 BRFND40.790.068 0.27 trans-1,2-Dichloroethylene ND 0.20 9/17/20 2:54 BRFND40.790.059 0.23 1,2-Dichloropropane ND 0.20 9/17/20 2:54 BRFND40.920.072 0.33 cis-1,3-Dichloropropene ND 0.20 9/17/20 2:54 BRFND40.910.093 0.42 trans-1,3-Dichloropropene ND 0.20 9/17/20 2:54 BRFND40.910.067 0.30 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 9/17/20 2:54 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 9/17/20 2:54 BRFND47.20.56 2.0 Ethanol 30 8.0 9/17/20 2:54 BRF56 4152.4 4.6 Ethyl Acetate ND 2.0 9/17/20 2:54 BRFND47.21.2 4.3 Ethylbenzene 4.3 0.20 9/17/20 2:54 BRF19 40.870.042 0.18 4-Ethyltoluene ND 0.20 9/17/20 2:54 BRFND40.980.062 0.30 Heptane 4.2 0.20 9/17/20 2:54 BRF17 40.820.086 0.35 Hexachlorobutadiene ND 0.20 9/17/20 2:54 BRFND42.10.088 0.94 Hexane ND 8.0 9/17/20 2:54 BRFND4280.36 1.3 2-Hexanone (MBK)ND 0.20 9/17/20 2:54 BRFND40.820.11 0.46 Isopropanol ND 8.0 9/17/20 2:54 BRFND4201.8 4.5 Methyl tert-Butyl Ether (MTBE)ND 0.20 9/17/20 2:54 BRFND40.720.080 0.29 Methylene Chloride ND 2.0 9/17/20 2:54 BRFND46.90.46 1.6 4-Methyl-2-pentanone (MIBK)ND 0.20 9/17/20 2:54 BRFND40.820.10 0.43 Naphthalene ND 0.20 9/17/20 2:54 BRFND41.00.11 0.59 Propene 4.9 8.0 9/17/20 2:54 BRFJ8.4 4140.67 1.2 Styrene ND 0.20 9/17/20 2:54 BRFND40.850.057 0.24 1,1,2,2-Tetrachloroethane ND 0.20 9/17/20 2:54 BRFND41.40.053 0.37 Page 6 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Date Received: 9/10/2020 Work Order: 20I0754Sample Description/Location: Field Sample #: SG-2 Sample ID: 20I0754-02 Sample Matrix: Soil Gas Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -3 Receipt Vacuum(in Hg): -4.6 Sampled: 9/10/2020 12:30 Canister ID: 2342 Flow Controller ID: 4324 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 55 0.20 9/17/20 2:54 BRF380 41.40.065 0.44 Tetrahydrofuran ND 2.0 9/17/20 2:54 BRFND45.90.49 1.5 Toluene 14 0.20 9/17/20 2:54 BRF52 40.750.058 0.22 1,2,4-Trichlorobenzene ND 0.20 9/17/20 2:54 BRFND41.50.12 0.91 1,1,1-Trichloroethane ND 0.20 9/17/20 2:54 BRFND41.10.065 0.36 1,1,2-Trichloroethane ND 0.20 9/17/20 2:54 BRFND41.10.073 0.40 Trichloroethylene 0.27 0.20 9/17/20 2:54 BRF1.4 41.10.074 0.40 Trichlorofluoromethane (Freon 11)0.36 0.80 9/17/20 2:54 BRFJ2.0 44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 9/17/20 2:54 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene ND 0.20 9/17/20 2:54 BRFND40.980.046 0.22 1,3,5-Trimethylbenzene ND 0.20 9/17/20 2:54 BRFND40.980.052 0.26 Vinyl Acetate ND 4.0 9/17/20 2:54 BRFND4140.56 2.0 Vinyl Chloride ND 0.20 9/17/20 2:54 BRFND40.510.11 0.29 m&p-Xylene 19 0.40 9/17/20 2:54 BRF82 41.70.070 0.30 o-Xylene ND 0.20 9/17/20 2:54 BRFND40.870.054 0.23 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)105 9/17/20 2:5470-130 Page 7 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Date Received: 9/10/2020 Work Order: 20I0754Sample Description/Location: Field Sample #: SG-3 Sample ID: 20I0754-03 Sample Matrix: Soil Gas Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -4 Receipt Vacuum(in Hg): -5.2 Sampled: 9/10/2020 13:06 Canister ID: 2100 Flow Controller ID: 4111 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 55 8.0 9/17/20 4:14 BRF130 4194.8 11 Benzene 0.47 0.20 9/17/20 4:14 BRF1.5 40.640.058 0.19 Benzyl chloride ND 0.20 9/17/20 4:14 BRFND41.00.090 0.47 Bromodichloromethane ND 0.20 9/17/20 4:14 BRFND41.30.056 0.37 Bromoform ND 0.20 9/17/20 4:14 BRFND42.10.069 0.71 Bromomethane ND 0.20 9/17/20 4:14 BRFND40.780.11 0.41 1,3-Butadiene ND 0.20 9/17/20 4:14 BRFND40.440.15 0.32 2-Butanone (MEK)7.4 8.0 9/17/20 4:14 BRFJ22 4240.66 2.0 Carbon Disulfide ND 2.0 9/17/20 4:14 BRFND46.20.51 1.6 Carbon Tetrachloride ND 0.20 9/17/20 4:14 BRFND41.30.053 0.33 Chlorobenzene ND 0.20 9/17/20 4:14 BRFND40.920.048 0.22 Chloroethane ND 0.20 9/17/20 4:14 BRFND40.530.20 0.52 Chloroform 8.1 0.20 9/17/20 4:14 BRF40 40.980.048 0.24 Chloromethane ND 0.40 9/17/20 4:14 BRFND40.830.15 0.32 Cyclohexane ND 0.20 9/17/20 4:14 BRFND40.690.098 0.34 Dibromochloromethane ND 0.20 9/17/20 4:14 BRFND41.70.067 0.57 1,2-Dibromoethane (EDB)ND 0.20 9/17/20 4:14 BRFND41.50.052 0.40 1,2-Dichlorobenzene ND 0.20 9/17/20 4:14 BRFND41.20.074 0.44 1,3-Dichlorobenzene ND 0.20 9/17/20 4:14 BRFND41.20.073 0.44 1,4-Dichlorobenzene ND 0.20 9/17/20 4:14 BRFND41.20.045 0.27 Dichlorodifluoromethane (Freon 12)ND 0.20 9/17/20 4:14 BRFND40.990.063 0.31 1,1-Dichloroethane ND 0.20 9/17/20 4:14 BRFND40.810.063 0.25 1,2-Dichloroethane ND 0.20 9/17/20 4:14 BRFND40.810.073 0.30 1,1-Dichloroethylene ND 0.20 9/17/20 4:14 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 9/17/20 4:14 BRFND40.790.068 0.27 trans-1,2-Dichloroethylene ND 0.20 9/17/20 4:14 BRFND40.790.059 0.23 1,2-Dichloropropane ND 0.20 9/17/20 4:14 BRFND40.920.072 0.33 cis-1,3-Dichloropropene ND 0.20 9/17/20 4:14 BRFND40.910.093 0.42 trans-1,3-Dichloropropene ND 0.20 9/17/20 4:14 BRFND40.910.067 0.30 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 9/17/20 4:14 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 9/17/20 4:14 BRFND47.20.56 2.0 Ethanol 38 8.0 9/17/20 4:14 BRF71 4152.4 4.6 Ethyl Acetate ND 2.0 9/17/20 4:14 BRFND47.21.2 4.3 Ethylbenzene 3.6 0.20 9/17/20 4:14 BRF16 40.870.042 0.18 4-Ethyltoluene ND 0.20 9/17/20 4:14 BRFND40.980.062 0.30 Heptane 1.1 0.20 9/17/20 4:14 BRF4.4 40.820.086 0.35 Hexachlorobutadiene ND 0.20 9/17/20 4:14 BRFND42.10.088 0.94 Hexane ND 8.0 9/17/20 4:14 BRFND4280.36 1.3 2-Hexanone (MBK)ND 0.20 9/17/20 4:14 BRFND40.820.11 0.46 Isopropanol 2.3 8.0 9/17/20 4:14 BRFJ5.7 4201.8 4.5 Methyl tert-Butyl Ether (MTBE)ND 0.20 9/17/20 4:14 BRFND40.720.080 0.29 Methylene Chloride ND 2.0 9/17/20 4:14 BRFND46.90.46 1.6 4-Methyl-2-pentanone (MIBK)4.8 0.20 9/17/20 4:14 BRF20 40.820.10 0.43 Naphthalene ND 0.20 9/17/20 4:14 BRFND41.00.11 0.59 Propene ND 8.0 9/17/20 4:14 BRFND4140.67 1.2 Styrene ND 0.20 9/17/20 4:14 BRFND40.850.057 0.24 1,1,2,2-Tetrachloroethane ND 0.20 9/17/20 4:14 BRFND41.40.053 0.37 Page 8 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Date Received: 9/10/2020 Work Order: 20I0754Sample Description/Location: Field Sample #: SG-3 Sample ID: 20I0754-03 Sample Matrix: Soil Gas Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -4 Receipt Vacuum(in Hg): -5.2 Sampled: 9/10/2020 13:06 Canister ID: 2100 Flow Controller ID: 4111 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 55 0.20 9/17/20 4:14 BRF370 41.40.065 0.44 Tetrahydrofuran 6.3 2.0 9/17/20 4:14 BRF18 45.90.49 1.5 Toluene 9.1 0.20 9/17/20 4:14 BRF34 40.750.058 0.22 1,2,4-Trichlorobenzene ND 0.20 9/17/20 4:14 BRFND41.50.12 0.91 1,1,1-Trichloroethane ND 0.20 9/17/20 4:14 BRFND41.10.065 0.36 1,1,2-Trichloroethane ND 0.20 9/17/20 4:14 BRFND41.10.073 0.40 Trichloroethylene 0.28 0.20 9/17/20 4:14 BRF1.5 41.10.074 0.40 Trichlorofluoromethane (Freon 11)0.43 0.80 9/17/20 4:14 BRFJ2.4 44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 9/17/20 4:14 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene ND 0.20 9/17/20 4:14 BRFND40.980.046 0.22 1,3,5-Trimethylbenzene ND 0.20 9/17/20 4:14 BRFND40.980.052 0.26 Vinyl Acetate ND 4.0 9/17/20 4:14 BRFND4140.56 2.0 Vinyl Chloride ND 0.20 9/17/20 4:14 BRFND40.510.11 0.29 m&p-Xylene 18 0.40 9/17/20 4:14 BRF78 41.70.070 0.30 o-Xylene ND 0.20 9/17/20 4:14 BRFND40.870.054 0.23 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)104 9/17/20 4:1470-130 Page 9 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Date Received: 9/10/2020 Work Order: 20I0754Sample Description/Location: Field Sample #: SG-4 Sample ID: 20I0754-04 Sample Matrix: Soil Gas Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -4 Receipt Vacuum(in Hg): -5.9 Sampled: 9/10/2020 13:40 Canister ID: 2299 Flow Controller ID: 4261 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 19 8.0 9/17/20 4:54 BRF45 4194.8 11 Benzene 0.81 0.20 9/17/20 4:54 BRF2.6 40.640.058 0.19 Benzyl chloride ND 0.20 9/17/20 4:54 BRFND41.00.090 0.47 Bromodichloromethane ND 0.20 9/17/20 4:54 BRFND41.30.056 0.37 Bromoform ND 0.20 9/17/20 4:54 BRFND42.10.069 0.71 Bromomethane ND 0.20 9/17/20 4:54 BRFND40.780.11 0.41 1,3-Butadiene ND 0.20 9/17/20 4:54 BRFND40.440.15 0.32 2-Butanone (MEK)2.6 8.0 9/17/20 4:54 BRFJ7.8 4240.66 2.0 Carbon Disulfide ND 2.0 9/17/20 4:54 BRFND46.20.51 1.6 Carbon Tetrachloride ND 0.20 9/17/20 4:54 BRFND41.30.053 0.33 Chlorobenzene ND 0.20 9/17/20 4:54 BRFND40.920.048 0.22 Chloroethane ND 0.20 9/17/20 4:54 BRFND40.530.20 0.52 Chloroform 0.64 0.20 9/17/20 4:54 BRF3.1 40.980.048 0.24 Chloromethane ND 0.40 9/17/20 4:54 BRFND40.830.15 0.32 Cyclohexane ND 0.20 9/17/20 4:54 BRFND40.690.098 0.34 Dibromochloromethane ND 0.20 9/17/20 4:54 BRFND41.70.067 0.57 1,2-Dibromoethane (EDB)ND 0.20 9/17/20 4:54 BRFND41.50.052 0.40 1,2-Dichlorobenzene ND 0.20 9/17/20 4:54 BRFND41.20.074 0.44 1,3-Dichlorobenzene ND 0.20 9/17/20 4:54 BRFND41.20.073 0.44 1,4-Dichlorobenzene ND 0.20 9/17/20 4:54 BRFND41.20.045 0.27 Dichlorodifluoromethane (Freon 12)ND 0.20 9/17/20 4:54 BRFND40.990.063 0.31 1,1-Dichloroethane ND 0.20 9/17/20 4:54 BRFND40.810.063 0.25 1,2-Dichloroethane ND 0.20 9/17/20 4:54 BRFND40.810.073 0.30 1,1-Dichloroethylene ND 0.20 9/17/20 4:54 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 9/17/20 4:54 BRFND40.790.068 0.27 trans-1,2-Dichloroethylene ND 0.20 9/17/20 4:54 BRFND40.790.059 0.23 1,2-Dichloropropane ND 0.20 9/17/20 4:54 BRFND40.920.072 0.33 cis-1,3-Dichloropropene ND 0.20 9/17/20 4:54 BRFND40.910.093 0.42 trans-1,3-Dichloropropene ND 0.20 9/17/20 4:54 BRFND40.910.067 0.30 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 9/17/20 4:54 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 9/17/20 4:54 BRFND47.20.56 2.0 Ethanol 47 8.0 9/17/20 4:54 BRF89 4152.4 4.6 Ethyl Acetate ND 2.0 9/17/20 4:54 BRFND47.21.2 4.3 Ethylbenzene 2.4 0.20 9/17/20 4:54 BRF10 40.870.042 0.18 4-Ethyltoluene ND 0.20 9/17/20 4:54 BRFND40.980.062 0.30 Heptane 5.0 0.20 9/17/20 4:54 BRF20 40.820.086 0.35 Hexachlorobutadiene ND 0.20 9/17/20 4:54 BRFND42.10.088 0.94 Hexane ND 8.0 9/17/20 4:54 BRFND4280.36 1.3 2-Hexanone (MBK)ND 0.20 9/17/20 4:54 BRFND40.820.11 0.46 Isopropanol 5.7 8.0 9/17/20 4:54 BRFJ14 4201.8 4.5 Methyl tert-Butyl Ether (MTBE)ND 0.20 9/17/20 4:54 BRFND40.720.080 0.29 Methylene Chloride ND 2.0 9/17/20 4:54 BRFND46.90.46 1.6 4-Methyl-2-pentanone (MIBK)1.2 0.20 9/17/20 4:54 BRF5.1 40.820.10 0.43 Naphthalene 0.67 0.20 9/17/20 4:54 BRF3.5 41.00.11 0.59 Propene 12 8.0 9/17/20 4:54 BRF21 4140.67 1.2 Styrene ND 0.20 9/17/20 4:54 BRFND40.850.057 0.24 1,1,2,2-Tetrachloroethane ND 0.20 9/17/20 4:54 BRFND41.40.053 0.37 Page 10 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Date Received: 9/10/2020 Work Order: 20I0754Sample Description/Location: Field Sample #: SG-4 Sample ID: 20I0754-04 Sample Matrix: Soil Gas Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -4 Receipt Vacuum(in Hg): -5.9 Sampled: 9/10/2020 13:40 Canister ID: 2299 Flow Controller ID: 4261 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 0.80 0.20 9/17/20 4:54 BRF5.4 41.40.065 0.44 Tetrahydrofuran 1.4 2.0 9/17/20 4:54 BRFJ4.0 45.90.49 1.5 Toluene 10 0.20 9/17/20 4:54 BRF39 40.750.058 0.22 1,2,4-Trichlorobenzene ND 0.20 9/17/20 4:54 BRFND41.50.12 0.91 1,1,1-Trichloroethane ND 0.20 9/17/20 4:54 BRFND41.10.065 0.36 1,1,2-Trichloroethane ND 0.20 9/17/20 4:54 BRFND41.10.073 0.40 Trichloroethylene 0.15 0.20 9/17/20 4:54 BRFJ0.80 41.10.074 0.40 Trichlorofluoromethane (Freon 11)ND 0.80 9/17/20 4:54 BRFND44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 9/17/20 4:54 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene ND 0.20 9/17/20 4:54 BRFND40.980.046 0.22 1,3,5-Trimethylbenzene ND 0.20 9/17/20 4:54 BRFND40.980.052 0.26 Vinyl Acetate ND 4.0 9/17/20 4:54 BRFND4140.56 2.0 Vinyl Chloride ND 0.20 9/17/20 4:54 BRFND40.510.11 0.29 m&p-Xylene 9.8 0.40 9/17/20 4:54 BRF43 41.70.070 0.30 o-Xylene ND 0.20 9/17/20 4:54 BRFND40.870.054 0.23 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)106 9/17/20 4:5470-130 Page 11 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Date Received: 9/10/2020 Work Order: 20I0754Sample Description/Location: Field Sample #: SG-5 Sample ID: 20I0754-05 Sample Matrix: Soil Gas Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -3 Receipt Vacuum(in Hg): -4.6 Sampled: 9/10/2020 14:15 Canister ID: 2104 Flow Controller ID: 4124 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone ND 8.0 9/17/20 5:35 BRFND4194.8 11 Benzene 1.1 0.20 9/17/20 5:35 BRF3.6 40.640.058 0.19 Benzyl chloride ND 0.20 9/17/20 5:35 BRFND41.00.090 0.47 Bromodichloromethane ND 0.20 9/17/20 5:35 BRFND41.30.056 0.37 Bromoform ND 0.20 9/17/20 5:35 BRFND42.10.069 0.71 Bromomethane ND 0.20 9/17/20 5:35 BRFND40.780.11 0.41 1,3-Butadiene ND 0.20 9/17/20 5:35 BRFND40.440.15 0.32 2-Butanone (MEK)3.0 8.0 9/17/20 5:35 BRFJ9.0 4240.66 2.0 Carbon Disulfide ND 2.0 9/17/20 5:35 BRFND46.20.51 1.6 Carbon Tetrachloride ND 0.20 9/17/20 5:35 BRFND41.30.053 0.33 Chlorobenzene ND 0.20 9/17/20 5:35 BRFND40.920.048 0.22 Chloroethane ND 0.20 9/17/20 5:35 BRFND40.530.20 0.52 Chloroform ND 0.20 9/17/20 5:35 BRFND40.980.048 0.24 Chloromethane ND 0.40 9/17/20 5:35 BRFND40.830.15 0.32 Cyclohexane ND 0.20 9/17/20 5:35 BRFND40.690.098 0.34 Dibromochloromethane ND 0.20 9/17/20 5:35 BRFND41.70.067 0.57 1,2-Dibromoethane (EDB)ND 0.20 9/17/20 5:35 BRFND41.50.052 0.40 1,2-Dichlorobenzene ND 0.20 9/17/20 5:35 BRFND41.20.074 0.44 1,3-Dichlorobenzene ND 0.20 9/17/20 5:35 BRFND41.20.073 0.44 1,4-Dichlorobenzene ND 0.20 9/17/20 5:35 BRFND41.20.045 0.27 Dichlorodifluoromethane (Freon 12)ND 0.20 9/17/20 5:35 BRFND40.990.063 0.31 1,1-Dichloroethane ND 0.20 9/17/20 5:35 BRFND40.810.063 0.25 1,2-Dichloroethane ND 0.20 9/17/20 5:35 BRFND40.810.073 0.30 1,1-Dichloroethylene ND 0.20 9/17/20 5:35 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 9/17/20 5:35 BRFND40.790.068 0.27 trans-1,2-Dichloroethylene ND 0.20 9/17/20 5:35 BRFND40.790.059 0.23 1,2-Dichloropropane ND 0.20 9/17/20 5:35 BRFND40.920.072 0.33 cis-1,3-Dichloropropene ND 0.20 9/17/20 5:35 BRFND40.910.093 0.42 trans-1,3-Dichloropropene ND 0.20 9/17/20 5:35 BRFND40.910.067 0.30 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 9/17/20 5:35 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 9/17/20 5:35 BRFND47.20.56 2.0 Ethanol 24 8.0 9/17/20 5:35 BRF45 4152.4 4.6 Ethyl Acetate ND 2.0 9/17/20 5:35 BRFND47.21.2 4.3 Ethylbenzene 3.4 0.20 9/17/20 5:35 BRF15 40.870.042 0.18 4-Ethyltoluene ND 0.20 9/17/20 5:35 BRFND40.980.062 0.30 Heptane 2.9 0.20 9/17/20 5:35 BRF12 40.820.086 0.35 Hexachlorobutadiene ND 0.20 9/17/20 5:35 BRFND42.10.088 0.94 Hexane 2.9 8.0 9/17/20 5:35 BRFJ10 4280.36 1.3 2-Hexanone (MBK)ND 0.20 9/17/20 5:35 BRFND40.820.11 0.46 Isopropanol ND 8.0 9/17/20 5:35 BRFND4201.8 4.5 Methyl tert-Butyl Ether (MTBE)ND 0.20 9/17/20 5:35 BRFND40.720.080 0.29 Methylene Chloride ND 2.0 9/17/20 5:35 BRFND46.90.46 1.6 4-Methyl-2-pentanone (MIBK)2.4 0.20 9/17/20 5:35 BRF9.8 40.820.10 0.43 Naphthalene 0.55 0.20 9/17/20 5:35 BRF2.9 41.00.11 0.59 Propene ND 8.0 9/17/20 5:35 BRFND4140.67 1.2 Styrene ND 0.20 9/17/20 5:35 BRFND40.850.057 0.24 1,1,2,2-Tetrachloroethane ND 0.20 9/17/20 5:35 BRFND41.40.053 0.37 Page 12 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Date Received: 9/10/2020 Work Order: 20I0754Sample Description/Location: Field Sample #: SG-5 Sample ID: 20I0754-05 Sample Matrix: Soil Gas Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -3 Receipt Vacuum(in Hg): -4.6 Sampled: 9/10/2020 14:15 Canister ID: 2104 Flow Controller ID: 4124 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 1.4 0.20 9/17/20 5:35 BRF9.6 41.40.065 0.44 Tetrahydrofuran 2.4 2.0 9/17/20 5:35 BRF7.2 45.90.49 1.5 Toluene 10 0.20 9/17/20 5:35 BRF39 40.750.058 0.22 1,2,4-Trichlorobenzene ND 0.20 9/17/20 5:35 BRFND41.50.12 0.91 1,1,1-Trichloroethane ND 0.20 9/17/20 5:35 BRFND41.10.065 0.36 1,1,2-Trichloroethane ND 0.20 9/17/20 5:35 BRFND41.10.073 0.40 Trichloroethylene ND 0.20 9/17/20 5:35 BRFND41.10.074 0.40 Trichlorofluoromethane (Freon 11)ND 0.80 9/17/20 5:35 BRFND44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 9/17/20 5:35 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene ND 0.20 9/17/20 5:35 BRFND40.980.046 0.22 1,3,5-Trimethylbenzene ND 0.20 9/17/20 5:35 BRFND40.980.052 0.26 Vinyl Acetate ND 4.0 9/17/20 5:35 BRFND4140.56 2.0 Vinyl Chloride ND 0.20 9/17/20 5:35 BRFND40.510.11 0.29 m&p-Xylene 16 0.40 9/17/20 5:35 BRF71 41.70.070 0.30 o-Xylene ND 0.20 9/17/20 5:35 BRFND40.870.054 0.23 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)106 9/17/20 5:3570-130 Page 13 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Date Received: 9/10/2020 Work Order: 20I0754Sample Description/Location: Field Sample #: SG-6 Sample ID: 20I0754-06 Sample Matrix: Soil Gas Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -3 Receipt Vacuum(in Hg): -5.2 Sampled: 9/10/2020 14:55 Canister ID: 2305 Flow Controller ID: 4115 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 70 8.0 9/17/20 6:15 BRF170 4194.8 11 Benzene 1.5 0.20 9/17/20 6:15 BRF4.9 40.640.058 0.19 Benzyl chloride ND 0.20 9/17/20 6:15 BRFND41.00.090 0.47 Bromodichloromethane ND 0.20 9/17/20 6:15 BRFND41.30.056 0.37 Bromoform ND 0.20 9/17/20 6:15 BRFND42.10.069 0.71 Bromomethane ND 0.20 9/17/20 6:15 BRFND40.780.11 0.41 1,3-Butadiene ND 0.20 9/17/20 6:15 BRFND40.440.15 0.32 2-Butanone (MEK)9.0 8.0 9/17/20 6:15 BRF27 4240.66 2.0 Carbon Disulfide ND 2.0 9/17/20 6:15 BRFND46.20.51 1.6 Carbon Tetrachloride ND 0.20 9/17/20 6:15 BRFND41.30.053 0.33 Chlorobenzene ND 0.20 9/17/20 6:15 BRFND40.920.048 0.22 Chloroethane ND 0.20 9/17/20 6:15 BRFND40.530.20 0.52 Chloroform ND 0.20 9/17/20 6:15 BRFND40.980.048 0.24 Chloromethane ND 0.40 9/17/20 6:15 BRFND40.830.15 0.32 Cyclohexane ND 0.20 9/17/20 6:15 BRFND40.690.098 0.34 Dibromochloromethane ND 0.20 9/17/20 6:15 BRFND41.70.067 0.57 1,2-Dibromoethane (EDB)ND 0.20 9/17/20 6:15 BRFND41.50.052 0.40 1,2-Dichlorobenzene ND 0.20 9/17/20 6:15 BRFND41.20.074 0.44 1,3-Dichlorobenzene ND 0.20 9/17/20 6:15 BRFND41.20.073 0.44 1,4-Dichlorobenzene ND 0.20 9/17/20 6:15 BRFND41.20.045 0.27 Dichlorodifluoromethane (Freon 12)ND 0.20 9/17/20 6:15 BRFND40.990.063 0.31 1,1-Dichloroethane ND 0.20 9/17/20 6:15 BRFND40.810.063 0.25 1,2-Dichloroethane ND 0.20 9/17/20 6:15 BRFND40.810.073 0.30 1,1-Dichloroethylene ND 0.20 9/17/20 6:15 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 9/17/20 6:15 BRFND40.790.068 0.27 trans-1,2-Dichloroethylene ND 0.20 9/17/20 6:15 BRFND40.790.059 0.23 1,2-Dichloropropane ND 0.20 9/17/20 6:15 BRFND40.920.072 0.33 cis-1,3-Dichloropropene ND 0.20 9/17/20 6:15 BRFND40.910.093 0.42 trans-1,3-Dichloropropene ND 0.20 9/17/20 6:15 BRFND40.910.067 0.30 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 9/17/20 6:15 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 9/17/20 6:15 BRFND47.20.56 2.0 Ethanol 19 8.0 9/17/20 6:15 BRF36 4152.4 4.6 Ethyl Acetate ND 2.0 9/17/20 6:15 BRFND47.21.2 4.3 Ethylbenzene 3.9 0.20 9/17/20 6:15 BRF17 40.870.042 0.18 4-Ethyltoluene ND 0.20 9/17/20 6:15 BRFND40.980.062 0.30 Heptane 2.7 0.20 9/17/20 6:15 BRF11 40.820.086 0.35 Hexachlorobutadiene ND 0.20 9/17/20 6:15 BRFND42.10.088 0.94 Hexane ND 8.0 9/17/20 6:15 BRFND4280.36 1.3 2-Hexanone (MBK)ND 0.20 9/17/20 6:15 BRFND40.820.11 0.46 Isopropanol ND 8.0 9/17/20 6:15 BRFND4201.8 4.5 Methyl tert-Butyl Ether (MTBE)ND 0.20 9/17/20 6:15 BRFND40.720.080 0.29 Methylene Chloride ND 2.0 9/17/20 6:15 BRFND46.90.46 1.6 4-Methyl-2-pentanone (MIBK)3.9 0.20 9/17/20 6:15 BRF16 40.820.10 0.43 Naphthalene ND 0.20 9/17/20 6:15 BRFND41.00.11 0.59 Propene ND 8.0 9/17/20 6:15 BRFND4140.67 1.2 Styrene ND 0.20 9/17/20 6:15 BRFND40.850.057 0.24 1,1,2,2-Tetrachloroethane ND 0.20 9/17/20 6:15 BRFND41.40.053 0.37 Page 14 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Date Received: 9/10/2020 Work Order: 20I0754Sample Description/Location: Field Sample #: SG-6 Sample ID: 20I0754-06 Sample Matrix: Soil Gas Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -3 Receipt Vacuum(in Hg): -5.2 Sampled: 9/10/2020 14:55 Canister ID: 2305 Flow Controller ID: 4115 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 1.7 0.20 9/17/20 6:15 BRF12 41.40.065 0.44 Tetrahydrofuran 8.1 2.0 9/17/20 6:15 BRF24 45.90.49 1.5 Toluene 14 0.20 9/17/20 6:15 BRF52 40.750.058 0.22 1,2,4-Trichlorobenzene ND 0.20 9/17/20 6:15 BRFND41.50.12 0.91 1,1,1-Trichloroethane ND 0.20 9/17/20 6:15 BRFND41.10.065 0.36 1,1,2-Trichloroethane ND 0.20 9/17/20 6:15 BRFND41.10.073 0.40 Trichloroethylene ND 0.20 9/17/20 6:15 BRFND41.10.074 0.40 Trichlorofluoromethane (Freon 11)ND 0.80 9/17/20 6:15 BRFND44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 9/17/20 6:15 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene ND 0.20 9/17/20 6:15 BRFND40.980.046 0.22 1,3,5-Trimethylbenzene ND 0.20 9/17/20 6:15 BRFND40.980.052 0.26 Vinyl Acetate ND 4.0 9/17/20 6:15 BRFND4140.56 2.0 Vinyl Chloride ND 0.20 9/17/20 6:15 BRFND40.510.11 0.29 m&p-Xylene 17 0.40 9/17/20 6:15 BRF74 41.70.070 0.30 o-Xylene ND 0.20 9/17/20 6:15 BRFND40.870.054 0.23 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)106 9/17/20 6:1570-130 Page 15 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Date Received: 9/10/2020 Work Order: 20I0754Sample Description/Location: Field Sample #: DUP-1 Sample ID: 20I0754-07 Sample Matrix: Soil Gas Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -3 Receipt Vacuum(in Hg): -3.6 Sampled: 9/10/2020 00:00 Canister ID: 2306 Flow Controller ID: 4325 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 8.8 8.0 9/17/20 6:56 BRF21 4194.8 11 Benzene 1.1 0.20 9/17/20 6:56 BRF3.6 40.640.058 0.19 Benzyl chloride ND 0.20 9/17/20 6:56 BRFND41.00.090 0.47 Bromodichloromethane ND 0.20 9/17/20 6:56 BRFND41.30.056 0.37 Bromoform ND 0.20 9/17/20 6:56 BRFND42.10.069 0.71 Bromomethane ND 0.20 9/17/20 6:56 BRFND40.780.11 0.41 1,3-Butadiene ND 0.20 9/17/20 6:56 BRFND40.440.15 0.32 2-Butanone (MEK)2.7 8.0 9/17/20 6:56 BRFJ7.9 4240.66 2.0 Carbon Disulfide ND 2.0 9/17/20 6:56 BRFND46.20.51 1.6 Carbon Tetrachloride ND 0.20 9/17/20 6:56 BRFND41.30.053 0.33 Chlorobenzene ND 0.20 9/17/20 6:56 BRFND40.920.048 0.22 Chloroethane ND 0.20 9/17/20 6:56 BRFND40.530.20 0.52 Chloroform 3.4 0.20 9/17/20 6:56 BRF17 40.980.048 0.24 Chloromethane ND 0.40 9/17/20 6:56 BRFND40.830.15 0.32 Cyclohexane ND 0.20 9/17/20 6:56 BRFND40.690.098 0.34 Dibromochloromethane ND 0.20 9/17/20 6:56 BRFND41.70.067 0.57 1,2-Dibromoethane (EDB)ND 0.20 9/17/20 6:56 BRFND41.50.052 0.40 1,2-Dichlorobenzene ND 0.20 9/17/20 6:56 BRFND41.20.074 0.44 1,3-Dichlorobenzene ND 0.20 9/17/20 6:56 BRFND41.20.073 0.44 1,4-Dichlorobenzene ND 0.20 9/17/20 6:56 BRFND41.20.045 0.27 Dichlorodifluoromethane (Freon 12)ND 0.20 9/17/20 6:56 BRFND40.990.063 0.31 1,1-Dichloroethane ND 0.20 9/17/20 6:56 BRFND40.810.063 0.25 1,2-Dichloroethane ND 0.20 9/17/20 6:56 BRFND40.810.073 0.30 1,1-Dichloroethylene ND 0.20 9/17/20 6:56 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 9/17/20 6:56 BRFND40.790.068 0.27 trans-1,2-Dichloroethylene ND 0.20 9/17/20 6:56 BRFND40.790.059 0.23 1,2-Dichloropropane ND 0.20 9/17/20 6:56 BRFND40.920.072 0.33 cis-1,3-Dichloropropene ND 0.20 9/17/20 6:56 BRFND40.910.093 0.42 trans-1,3-Dichloropropene ND 0.20 9/17/20 6:56 BRFND40.910.067 0.30 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 9/17/20 6:56 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 9/17/20 6:56 BRFND47.20.56 2.0 Ethanol 20 8.0 9/17/20 6:56 BRF38 4152.4 4.6 Ethyl Acetate ND 2.0 9/17/20 6:56 BRFND47.21.2 4.3 Ethylbenzene 12 0.20 9/17/20 6:56 BRF53 40.870.042 0.18 4-Ethyltoluene 9.7 0.20 9/17/20 6:56 BRF48 40.980.062 0.30 Heptane 2.1 0.20 9/17/20 6:56 BRF8.5 40.820.086 0.35 Hexachlorobutadiene ND 0.20 9/17/20 6:56 BRFND42.10.088 0.94 Hexane ND 8.0 9/17/20 6:56 BRFND4280.36 1.3 2-Hexanone (MBK)ND 0.20 9/17/20 6:56 BRFND40.820.11 0.46 Isopropanol ND 8.0 9/17/20 6:56 BRFND4201.8 4.5 Methyl tert-Butyl Ether (MTBE)ND 0.20 9/17/20 6:56 BRFND40.720.080 0.29 Methylene Chloride ND 2.0 9/17/20 6:56 BRFND46.90.46 1.6 4-Methyl-2-pentanone (MIBK)4.8 0.20 9/17/20 6:56 BRF20 40.820.10 0.43 Naphthalene ND 0.20 9/17/20 6:56 BRFND41.00.11 0.59 Propene ND 8.0 9/17/20 6:56 BRFND4140.67 1.2 Styrene 1.6 0.20 9/17/20 6:56 BRF6.7 40.850.057 0.24 1,1,2,2-Tetrachloroethane ND 0.20 9/17/20 6:56 BRFND41.40.053 0.37 Page 16 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Raleigh, NC Date Received: 9/10/2020 Work Order: 20I0754Sample Description/Location: Field Sample #: DUP-1 Sample ID: 20I0754-07 Sample Matrix: Soil Gas Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -3 Receipt Vacuum(in Hg): -3.6 Sampled: 9/10/2020 00:00 Canister ID: 2306 Flow Controller ID: 4325 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 6.7 0.20 9/17/20 6:56 BRF46 41.40.065 0.44 Tetrahydrofuran 1.7 2.0 9/17/20 6:56 BRFJ5.1 45.90.49 1.5 Toluene 33 0.20 9/17/20 6:56 BRF120 40.750.058 0.22 1,2,4-Trichlorobenzene ND 0.20 9/17/20 6:56 BRFND41.50.12 0.91 1,1,1-Trichloroethane ND 0.20 9/17/20 6:56 BRFND41.10.065 0.36 1,1,2-Trichloroethane ND 0.20 9/17/20 6:56 BRFND41.10.073 0.40 Trichloroethylene 0.37 0.20 9/17/20 6:56 BRF2.0 41.10.074 0.40 Trichlorofluoromethane (Freon 11)0.58 0.80 9/17/20 6:56 BRFJ3.3 44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 9/17/20 6:56 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene 48 0.20 9/17/20 6:56 BRF230 40.980.046 0.22 1,3,5-Trimethylbenzene 21 0.20 9/17/20 6:56 BRF100 40.980.052 0.26 Vinyl Acetate ND 4.0 9/17/20 6:56 BRFND4140.56 2.0 Vinyl Chloride ND 0.20 9/17/20 6:56 BRFND40.510.11 0.29 m&p-Xylene 63 0.40 9/17/20 6:56 BRF270 41.70.070 0.30 o-Xylene 19 0.20 9/17/20 6:56 BRF81 40.870.054 0.23 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)107 9/17/20 6:5670-130 Page 17 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Sample Extraction Data Prep Method: TO-15 Prep-EPA TO-15 Lab Number [Field ID]Batch Date Pressure Dilution Pre Dilution Pre-Dil Initial mL Pre-Dil Final mL Default Injection mL Actual Injection mL 20I0754-01 [SG-1D]B266701 1.5 1 N/A 1000 400 150 09/16/20 20I0754-02 [SG-2]B266701 1.5 1 N/A 1000 400 150 09/16/20 20I0754-03 [SG-3]B266701 1.5 1 N/A 1000 400 150 09/16/20 20I0754-04 [SG-4]B266701 1.5 1 N/A 1000 400 150 09/16/20 20I0754-05 [SG-5]B266701 1.5 1 N/A 1000 400 150 09/16/20 20I0754-06 [SG-6]B266701 1.5 1 N/A 1000 400 150 09/16/20 20I0754-07 [DUP-1]B266701 1.5 1 N/A 1000 400 150 09/16/20 Page 18 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B266701 - TO-15 Prep Blank (B266701-BLK1)Prepared & Analyzed: 09/16/20 0.80NDAcetone 0.020NDBenzene 0.020NDBenzyl chloride 0.020NDBromodichloromethane 0.020NDBromoform 0.020NDBromomethane 0.020ND1,3-Butadiene 0.80ND2-Butanone (MEK) 0.20NDCarbon Disulfide 0.020NDCarbon Tetrachloride 0.020NDChlorobenzene 0.020NDChloroethane 0.020NDChloroform 0.040NDChloromethane 0.020NDCyclohexane 0.020NDDibromochloromethane 0.020ND1,2-Dibromoethane (EDB) 0.020ND1,2-Dichlorobenzene 0.020ND1,3-Dichlorobenzene 0.020ND1,4-Dichlorobenzene 0.020NDDichlorodifluoromethane (Freon 12) 0.020ND1,1-Dichloroethane 0.020ND1,2-Dichloroethane 0.020ND1,1-Dichloroethylene 0.020NDcis-1,2-Dichloroethylene 0.020NDtrans-1,2-Dichloroethylene 0.020ND1,2-Dichloropropane 0.020NDcis-1,3-Dichloropropene 0.020NDtrans-1,3-Dichloropropene 0.020ND1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.20ND1,4-Dioxane 0.80NDEthanol 0.20NDEthyl Acetate 0.020NDEthylbenzene 0.020ND4-Ethyltoluene 0.020NDHeptane 0.020NDHexachlorobutadiene 0.80NDHexane 0.020ND2-Hexanone (MBK) 0.80NDIsopropanol 0.020NDMethyl tert-Butyl Ether (MTBE) 0.20NDMethylene Chloride 0.020ND4-Methyl-2-pentanone (MIBK) 0.020NDNaphthalene 0.80NDPropene 0.020NDStyrene Page 19 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B266701 - TO-15 Prep Blank (B266701-BLK1)Prepared & Analyzed: 09/16/20 0.020ND1,1,2,2-Tetrachloroethane 0.020NDTetrachloroethylene 0.20NDTetrahydrofuran 0.020NDToluene 0.020ND1,2,4-Trichlorobenzene 0.020ND1,1,1-Trichloroethane 0.020ND1,1,2-Trichloroethane 0.020NDTrichloroethylene 0.080NDTrichlorofluoromethane (Freon 11) 0.080ND1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 0.020ND1,2,4-Trimethylbenzene 0.020ND1,3,5-Trimethylbenzene 0.40NDVinyl Acetate 0.020NDVinyl Chloride 0.040NDm&p-Xylene 0.020NDo-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)95.77.66 LCS (B266701-BS1)Prepared & Analyzed: 09/16/20 5.00 70-13085.34.26Acetone 5.00 70-13099.34.96Benzene 5.00 70-1301165.78Benzyl chloride 5.00 70-13098.74.93Bromodichloromethane 5.00 70-1301085.41Bromoform 5.00 70-13078.43.92Bromomethane 5.00 70-13073.63.681,3-Butadiene 5.00 70-13092.64.632-Butanone (MEK) 5.00 70-13087.24.36Carbon Disulfide 5.00 70-1301015.03Carbon Tetrachloride 5.00 70-13098.44.92Chlorobenzene 5.00 70-13074.53.72Chloroethane 5.00 70-13081.84.09Chloroform 5.00 70-13074.83.74Chloromethane 5.00 70-13089.04.45Cyclohexane 5.00 70-1301085.38Dibromochloromethane 5.00 70-13094.54.731,2-Dibromoethane (EDB) 5.00 70-1301145.721,2-Dichlorobenzene 5.00 70-1301125.601,3-Dichlorobenzene 5.00 70-1301095.471,4-Dichlorobenzene 5.00 70-13089.74.49Dichlorodifluoromethane (Freon 12) 5.00 70-13088.24.411,1-Dichloroethane 5.00 70-13081.44.071,2-Dichloroethane 5.00 70-13085.84.291,1-Dichloroethylene 5.00 70-13080.54.02cis-1,2-Dichloroethylene 5.00 70-13086.24.31trans-1,2-Dichloroethylene 5.00 70-13097.34.861,2-Dichloropropane Page 20 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B266701 - TO-15 Prep LCS (B266701-BS1)Prepared & Analyzed: 09/16/20 5.00 70-13090.24.51cis-1,3-Dichloropropene 5.00 70-13099.24.96trans-1,3-Dichloropropene 5.00 70-13079.63.981,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 5.00 70-1301085.401,4-Dioxane 5.00 70-13088.14.41Ethanol 5.00 70-13080.54.02Ethyl Acetate 5.00 70-13097.44.87Ethylbenzene 5.00 70-1301085.394-Ethyltoluene 5.00 70-13097.64.88Heptane 5.00 70-1301025.11Hexachlorobutadiene 5.00 70-13091.04.55Hexane 5.00 70-1301095.462-Hexanone (MBK) 5.00 70-13080.44.02Isopropanol 5.00 70-13085.54.28Methyl tert-Butyl Ether (MTBE) 5.00 70-13077.73.89Methylene Chloride 5.00 70-1301115.534-Methyl-2-pentanone (MIBK) 5.00 70-1301306.49Naphthalene 5.00 70-13085.24.26Propene 5.00 70-13099.24.96Styrene 5.00 70-1301045.211,1,2,2-Tetrachloroethane 5.00 70-13090.44.52Tetrachloroethylene 5.00 70-13090.34.52Tetrahydrofuran 5.00 70-13097.34.87Toluene 5.00 70-1301256.261,2,4-Trichlorobenzene 5.00 70-13089.94.501,1,1-Trichloroethane 5.00 70-13092.34.611,1,2-Trichloroethane 5.00 70-13092.64.63Trichloroethylene 5.00 70-13091.24.56Trichlorofluoromethane (Freon 11) 5.00 70-13085.74.281,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 5.00 70-1301075.361,2,4-Trimethylbenzene 5.00 70-1301025.121,3,5-Trimethylbenzene 5.00 70-13076.13.81Vinyl Acetate 5.00 70-13079.23.96Vinyl Chloride 10.0 70-13010010.0m&p-Xylene 5.00 70-13099.64.98o-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1028.12 Page 21 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Note: Blank Subtraction is not performed unless otherwise noted *QC result is outside of established limits. Wide recovery limits established for difficult compound. Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level RL Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference LCS Laboratory Control Sample Laboratory Control SampleLCS Dup Duplicate Laboratory Control Sample MS Matrix Spike Sample MS Dup Duplicate Matrix Spike Sample REC Recovery QC Quality Control ppbv Parts per billion volume EPA United States Environmental Protection Agency Percent Recovery% REC ND Not Detected Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. Not ApplicableN/A DL Detection Limit Not CalculatedNC LFB/LCS Lab Fortified Blank/Lab Control Sample ORP Oxidation-Reduction Potential Not dry weight correctedwet Percent weight% wt KilogramKg Gramg Milligrammg Microgramg Nanogramng LiterL MillilitermL Microliter L Cubic Meterm3 Extractable Petroleum HydrocarbonsEPH Volatile Petroleum HydrocarbonsVPH Air Petroleum HydrocarbonsAPH Flame Ionization DetectorFID Photo Ionization DetectorPID FLAG/QUALIFIER SUMMARY Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J ANALYST Raisa A. PetraitisRAP PDF Management StationSTATION Kerry K. McGeeKKM Brittany R. FiskBRF Page 22 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Initial Cal Check (S050606-ICV1 )Lab File ID: G2020617.D Analyzed: 07/24/20 19:18 Bromochloromethane (1)517660 8.515 520641 8.521 60 - 14099 -0.0060 +/-0.50 1,4-Difluorobenzene (1)1364277 10.295 1344293 10.295 60 - 140101 0.0000 +/-0.50 Chlorobenzene-d5 (1)1228652 14.673 1216922 14.672 60 - 140101 0.0010 +/-0.50 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Calibration Check (S052464-CCV1 )Lab File ID: G2026004.D Analyzed: 09/16/20 10:54 Bromochloromethane (1)570266 8.515 520641 8.521 60 - 140110 -0.0060 +/-0.50 1,4-Difluorobenzene (1)1224310 10.295 1344293 10.295 60 - 14091 0.0000 +/-0.50 Chlorobenzene-d5 (1)1118907 14.673 1216922 14.672 60 - 14092 0.0010 +/-0.50 LCS (B266701-BS1 )Lab File ID: G2026005.D Analyzed: 09/16/20 11:34 Bromochloromethane (1)573130 8.521 570266 8.515 60 - 140101 0.0060 +/-0.50 1,4-Difluorobenzene (1)1219109 10.295 1224310 10.295 60 - 140100 0.0000 +/-0.50 Chlorobenzene-d5 (1)1122297 14.673 1118907 14.673 60 - 140100 0.0000 +/-0.50 Blank (B266701-BLK1 )Lab File ID: G2026010.D Analyzed: 09/16/20 15:05 Bromochloromethane (1)560363 8.521 570266 8.515 60 - 14098 0.0060 +/-0.50 1,4-Difluorobenzene (1)1153400 10.295 1224310 10.295 60 - 14094 0.0000 +/-0.50 Chlorobenzene-d5 (1)1063882 14.673 1118907 14.673 60 - 14095 0.0000 +/-0.50 SG-1D (20I0754-01 )Lab File ID: G2026025.D Analyzed: 09/17/20 02:13 Bromochloromethane (1)533801 8.521 570266 8.515 60 - 14094 0.0060 +/-0.50 1,4-Difluorobenzene (1)1140057 10.295 1224310 10.295 60 - 14093 0.0000 +/-0.50 Chlorobenzene-d5 (1)1042453 14.673 1118907 14.673 60 - 14093 0.0000 +/-0.50 SG-2 (20I0754-02 )Lab File ID: G2026026.D Analyzed: 09/17/20 02:54 Bromochloromethane (1)559959 8.521 570266 8.515 60 - 14098 0.0060 +/-0.50 1,4-Difluorobenzene (1)1183120 10.295 1224310 10.295 60 - 14097 0.0000 +/-0.50 Chlorobenzene-d5 (1)1092166 14.672 1118907 14.673 60 - 14098 -0.0010 +/-0.50 SG-3 (20I0754-03 )Lab File ID: G2026028.D Analyzed: 09/17/20 04:14 Bromochloromethane (1)553332 8.521 570266 8.515 60 - 14097 0.0060 +/-0.50 1,4-Difluorobenzene (1)1164860 10.295 1224310 10.295 60 - 14095 0.0000 +/-0.50 Chlorobenzene-d5 (1)1082415 14.672 1118907 14.673 60 - 14097 -0.0010 +/-0.50 SG-4 (20I0754-04 )Lab File ID: G2026029.D Analyzed: 09/17/20 04:54 Bromochloromethane (1)612827 8.521 570266 8.515 60 - 140107 0.0060 +/-0.50 1,4-Difluorobenzene (1)1271560 10.295 1224310 10.295 60 - 140104 0.0000 +/-0.50 Chlorobenzene-d5 (1)1169516 14.673 1118907 14.673 60 - 140105 0.0000 +/-0.50 Page 23 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q SG-5 (20I0754-05 )Lab File ID: G2026030.D Analyzed: 09/17/20 05:35 Bromochloromethane (1)630734 8.521 570266 8.515 60 - 140111 0.0060 +/-0.50 1,4-Difluorobenzene (1)1355549 10.295 1224310 10.295 60 - 140111 0.0000 +/-0.50 Chlorobenzene-d5 (1)1234442 14.673 1118907 14.673 60 - 140110 0.0000 +/-0.50 SG-6 (20I0754-06 )Lab File ID: G2026031.D Analyzed: 09/17/20 06:15 Bromochloromethane (1)636468 8.521 570266 8.515 60 - 140112 0.0060 +/-0.50 1,4-Difluorobenzene (1)1390725 10.295 1224310 10.295 60 - 140114 0.0000 +/-0.50 Chlorobenzene-d5 (1)1269394 14.673 1118907 14.673 60 - 140113 0.0000 +/-0.50 DUP-1 (20I0754-07 )Lab File ID: G2026032.D Analyzed: 09/17/20 06:56 Bromochloromethane (1)617889 8.521 570266 8.515 60 - 140108 0.0060 +/-0.50 1,4-Difluorobenzene (1)1406438 10.295 1224310 10.295 60 - 140115 0.0000 +/-0.50 Chlorobenzene-d5 (1)1295601 14.673 1118907 14.673 60 - 140116 0.0000 +/-0.50 Page 24 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S052464-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 0.8765061A -16.8 304.16 1.0535555.00Acetone 0.8787604A 5.6 304.98 0.83181955.00Benzene 1.116365A 14.6 305.73 0.97445395.00Benzyl chloride 0.6676113A -0.7 304.96 0.67229875.00Bromodichloromethane 0.5163839A 9.9 305.50 0.46977585.00Bromoform 0.3865003A -20.6 303.97 0.48682065.00Bromomethane 0.4046533A -26.4 303.68 0.55015895.001,3-Butadiene 1.464574A -9.5 304.53 1.6174615.002-Butanone (MEK) 1.66436A -14.2 304.29 1.9397035.00Carbon Disulfide 0.5734077A 2.6 305.13 0.55861215.00Carbon Tetrachloride 0.8046295A 0.1 305.00 0.80381515.00Chlorobenzene 0.2371777A -27.7 303.62 0.32796055.00Chloroethane 1.275065A -17.7 304.11 1.5500255.00Chloroform 0.5123279A -24.8 303.76 0.68101255.00Chloromethane 0.356971A -10.0 304.50 0.39642335.00Cyclohexane 0.62652A 8.6 305.43 0.5766445.00Dibromochloromethane 0.5540292A -5.0 304.75 0.58312035.001,2-Dibromoethane (EDB) 0.6936055A 12.7 305.63 0.615545.001,2-Dichlorobenzene 0.7464456A 11.5 305.57 0.66956715.001,3-Dichlorobenzene 0.748662A 8.8 305.44 0.68784585.001,4-Dichlorobenzene 1.33504A -12.0 304.40 1.517275.00Dichlorodifluoromethane (Freon 12) 1.17395A -12.6 304.37 1.3431085.001,1-Dichloroethane 0.8905795A -17.3 304.13 1.0775185.001,2-Dichloroethane 1.034369A -12.7 304.37 1.1843885.001,1-Dichloroethylene 0.8914044A -17.9 304.10 1.0858845.00cis-1,2-Dichloroethylene 0.9237935A -13.0 304.35 1.0613685.00trans-1,2-Dichloroethylene 0.3561516A -1.3 304.94 0.36076115.001,2-Dichloropropane 0.5555351A -3.4 304.83 0.57525965.00cis-1,3-Dichloropropene 0.479408A -1.4 304.93 0.48643195.00trans-1,3-Dichloropropene 1.177923A -16.4 304.18 1.4094765.001,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.1707385A 3.7 305.19 0.16460655.001,4-Dioxane 0.1336667A -23.1 303.84 0.17380835.00Ethanol 0.2240554A -14.3 304.28 0.26152255.00Ethyl Acetate 1.441814A 0.2 305.01 1.4395725.00Ethylbenzene 1.51243A 9.3 305.46 1.3840565.004-Ethyltoluene 0.3070151A 0.7 305.04 0.30477745.00Heptane 0.3722533A 7.5 305.38 0.34623555.00Hexachlorobutadiene 0.8665205A -7.5 304.63 1.0641455.00Hexane Page 25 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S052464-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 0.8518542A 9.1 305.45 0.78115325.002-Hexanone (MBK) 0.9800423A -14.7 304.26 1.1489995.00Isopropanol 1.690922A -13.5 304.33 1.9543585.00Methyl tert-Butyl Ether (MTBE) 0.7961758A -22.1 303.90 1.0220025.00Methylene Chloride 0.8607742A 11.7 305.58 0.77094945.004-Methyl-2-pentanone (MIBK) 1.254418A 15.5 305.78 1.0858335.00Naphthalene 0.6027278A -11.8 304.41 0.68310695.00Propene 0.8140873A 2.3 305.12 0.79570255.00Styrene 0.8577971A 3.2 305.16 0.8310555.001,1,2,2-Tetrachloroethane 0.3992525A -7.2 304.64 0.43008225.00Tetrachloroethylene 0.2694434A -12.3 304.38 0.30727435.00Tetrahydrofuran 1.08149A -2.8 304.86 1.1130365.00Toluene 0.4657417A 21.1 306.06 0.38444265.001,2,4-Trichlorobenzene 0.5811574A -2.9 304.86 0.59853515.001,1,1-Trichloroethane 0.3695893A -6.1 304.69 0.39377395.001,1,2-Trichloroethane 0.3644044A -7.6 304.62 0.39422495.00Trichloroethylene 1.095795A -10.0 304.50 1.217035.00Trichlorofluoromethane (Freon 11) 1.099504A -13.6 304.32 1.2727175.001,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 1.245899A 10.1 305.51 1.1311435.001,2,4-Trimethylbenzene 1.267047A 5.8 305.29 1.1975275.001,3,5-Trimethylbenzene 1.855505A -23.7 303.82 2.431065.00Vinyl Acetate 0.513136A -21.6 303.92 0.65415115.00Vinyl Chloride 1.119789A 2.6 3010.3 1.09128110.0m&p-Xylene 1.148751A 1.8 305.09 1.1280795.00o-Xylene * Values outside of QC limits # Column to be used to flag Response Factor and %Diff/Drift values with an asterisk Page 26 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,NY,ME,NHAcetone AIHA,FL,NJ,NY,ME,NH,VABenzene AIHA,FL,NJ,NY,ME,NH,VABenzyl chloride AIHA,NJ,NY,ME,NH,VABromodichloromethane AIHA,NJ,NY,ME,NH,VABromoform AIHA,FL,NJ,NY,ME,NHBromomethane AIHA,NJ,NY,ME,NH,VA1,3-Butadiene AIHA,FL,NJ,NY,ME,NH,VA2-Butanone (MEK) AIHA,NJ,NY,ME,NH,VACarbon Disulfide AIHA,FL,NJ,NY,ME,NH,VACarbon Tetrachloride AIHA,FL,NJ,NY,ME,NH,VAChlorobenzene AIHA,FL,NJ,NY,ME,NH,VAChloroethane AIHA,FL,NJ,NY,ME,NH,VAChloroform AIHA,FL,NJ,NY,ME,NH,VAChloromethane AIHA,NJ,NY,ME,NH,VACyclohexane AIHA,NY,ME,NHDibromochloromethane AIHA,NJ,NY,ME,NH1,2-Dibromoethane (EDB) AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene AIHA,NJ,NY,ME,NH1,3-Dichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,4-Dichlorobenzene AIHA,NY,ME,NHDichlorodifluoromethane (Freon 12) AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene AIHA,FL,NY,ME,NH,VAcis-1,2-Dichloroethylene AIHA,NJ,NY,ME,NH,VAtrans-1,2-Dichloroethylene AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloropropane AIHA,FL,NJ,NY,ME,NH,VAcis-1,3-Dichloropropene AIHA,NY,ME,NHtrans-1,3-Dichloropropene AIHA,NJ,NY,ME,NH,VA1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) AIHA,NJ,NY,ME,NH,VA1,4-Dioxane AIHAEthanol AIHAEthyl Acetate AIHA,FL,NJ,NY,ME,NH,VAEthylbenzene AIHA,NJ4-Ethyltoluene AIHA,NJ,NY,ME,NH,VAHeptane AIHA,NJ,NY,ME,NH,VAHexachlorobutadiene AIHA,FL,NJ,NY,ME,NH,VAHexane AIHA2-Hexanone (MBK) AIHA,NY,ME,NHIsopropanol AIHA,FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE) AIHA,FL,NJ,NY,ME,NH,VAMethylene Chloride AIHA,FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK) NY,ME,NHNaphthalene AIHAPropene AIHA,FL,NJ,NY,ME,NH,VAStyrene AIHA,FL,NJ,NY,ME,NH,VA1,1,2,2-Tetrachloroethane Page 27 of 31 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,FL,NJ,NY,ME,NH,VATetrachloroethylene AIHATetrahydrofuran AIHA,FL,NJ,NY,ME,NH,VAToluene AIHA,NJ,NY,ME,NH,VA1,2,4-Trichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,1,1-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,2-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VATrichloroethylene AIHA,NY,ME,NHTrichlorofluoromethane (Freon 11) AIHA,NJ,NY,ME,NH,VA1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) AIHA,NJ,NY,ME,NH1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH1,3,5-Trimethylbenzene AIHA,FL,NJ,NY,ME,NH,VAVinyl Acetate AIHA,FL,NJ,NY,ME,NH,VAVinyl Chloride AIHA,FL,NJ,NY,ME,NH,VAm&p-Xylene AIHA,FL,NJ,NY,ME,NH,VAo-Xylene The CON-TEST Environmental Laboratory operates under the following certifications and accreditations: Code Description Number Expires 100033AIHA-LAP, LLC - ISO17025:2017AIHA 03/1/2022 M-MA100Massachusetts DEPMA 06/30/2021 PH-0567Connecticut Department of Publilc HealthCT 09/30/2021 10899 NELAPNew York State Department of HealthNY 04/1/2021 2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2021 LAO00112Rhode Island Department of HealthRI 12/30/2020 652North Carolina Div. of Water QualityNC 12/31/2020 MA007 NELAPNew Jersey DEPNJ 06/30/2021 E871027 NELAPFlorida Department of HealthFL 06/30/2021 LL015036Vermont Department of Health Lead LaboratoryVT 07/30/2021 2011028State of MaineME 06/9/2021 460217Commonwealth of VirginiaVA 12/14/2020 2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2021 VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2021 25703North Carolina Department of HealthNC-DW 07/31/2021 68-05812Commonwealth of Pennsylvania DEPPA 06/30/2021 9100Dept. of Env, Great Lakes, and EnergyMI 10/1/2020 Page 28 of 31 Page 29 of 31 Page 30 of 31 Page 31 of 31 Hart & Hickman - Raleigh 3921 Sunset Ridge Road, Suite 301 Raleigh, NC 27607 Cameron Village Condominiums Client Project # CAM-011 Analytical Report (0920-079) EPA Method TO-15 Analysis Client Specified TO-15 Target Compound List Enthalpy Analytical, LLC Phone: (919) 850 - 4392 / Fax: (919) 850 - 9012 / www.enthalpy.com 800-1 Capitola Drive Durham, NC 27713 Results EA Job # 0920-079 Page 3 of 25 Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-1S Sample Info : 0920-079; 500mL load; Can #00161 Data File : T20002736.D Dilution : 1 Pressurization Factor : 2.594 Acquisition Date : 2020-09-30 23:29:37 Instrument Method : TO15-SCN2.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Propylene 2.12 0.0994 0.0908 3.65 0.171 0.156 Freon 12 (CCl2F2)0.404 0.0997 0.0908 2.00 0.493 0.449 Freon 114 (C2Cl2F4)ND 0.103 0.0908 ND 0.722 0.635 Chloromethane 0.105 0.101 0.0908 0.218 0.208 0.187 Chloroethene (Vinyl chloride)ND 0.103 0.0908 ND 0.264 0.232 1,3-Butadiene 0.138 0.100 0.0908 0.306 0.222 0.201 Bromomethane ND 0.102 0.0908 ND 0.395 0.353 Chloroethane ND 0.104 0.0908 ND 0.274 0.240 Freon 11 (CCl3F)0.632 0.107 0.0908 3.55 0.602 0.510 Ethanol 45.6 0.104 0.104 85.8 0.196 0.196 Freon 113 (C2Cl3F3)ND 0.103 0.0908 ND 0.788 0.696 1,1-Dichloroethene ND 0.103 0.0908 ND 0.409 0.360 Acetone 9.93 0.102 0.0908 23.6 0.243 0.216 m Carbon disulfide 0.356 0.103 0.0908 1.11 0.321 0.283 Isopropyl alcohol 1.60 0.103 0.0908 3.92 0.252 0.223 Methylene chloride 0.186 0.104 0.0908 0.645 0.361 0.315 m trans-1,2-Dichloroethene ND 0.105 0.0908 ND 0.416 0.360 Methyl tert-butyl ether ND 0.105 0.0908 ND 0.378 0.327 Hexane 0.584 0.104 0.0908 2.06 0.368 0.320 1,1-Dichloroethane ND 0.101 0.0908 ND 0.409 0.367 Vinyl acetate ND 0.104 0.0908 ND 0.366 0.320 cis-1,2-Dichloroethene ND 0.103 0.0908 ND 0.409 0.360 Methyl ethyl ketone (2-Butanone)3.02 0.105 0.0908 8.90 0.311 0.268 Ethyl acetate 0.549 0.104 0.0908 1.98 0.374 0.327 Chloroform 3.82 0.104 0.0908 18.6 0.509 0.443 Tetrahydrofuran 3.82 0.104 0.0908 11.3 0.305 0.268 1,1,1-Trichloroethane ND 0.102 0.0908 ND 0.558 0.495 Cyclohexane 1.68 0.104 0.0908 5.79 0.359 0.313 m Carbon tetrachloride ND 0.104 0.0908 ND 0.653 0.571 Benzene 1.34 0.102 0.0908 4.28 0.326 0.290 1,2-Dichloroethane ND 0.105 0.0908 ND 0.424 0.367 Heptane 1.53 0.103 0.0908 6.26 0.423 0.372 Trichloroethene 0.305 0.104 0.0908 1.64 0.557 0.488 1,2-Dichloropropane ND 0.102 0.0908 ND 0.469 0.420 1,4-Dioxane 0.100 0.103 0.0908 0.360 0.373 0.327 J Bromodichloromethane ND 0.103 0.0908 ND 0.688 0.608 cis-1,3-Dichloropropene ND 0.101 0.0908 ND 0.460 0.412 Methyl isobutyl ketone 4.30 0.106 0.0908 17.6 0.434 0.372 m Toluene 23.4 0.104 0.0908 88.1 0.394 0.342 trans-1,3-Dichloropropene ND 0.105 0.0908 ND 0.476 0.412 1,1,2-Trichloroethane ND 0.104 0.0908 ND 0.566 0.495 Tetrachloroethene 3.94 0.104 0.0908 26.7 0.704 0.616 2-Hexanone (Methyl butyl ketone)0.186 0.104 0.0908 0.761 0.426 0.372 m Dibromochloromethane ND 0.102 0.0908 ND 0.872 0.773 1,2-Dibromoethane ND 0.105 0.0908 ND 0.804 0.698 Chlorobenzene 0.118 0.106 0.0908 0.544 0.490 0.418 Ethylbenzene 8.04 0.102 0.0908 34.9 0.441 0.394 m-/p-Xylenes 37.3 0.105 0.0908 162 0.455 0.394 o-Xylene 11.5 0.103 0.0908 50.0 0.446 0.394 Styrene 1.75 0.101 0.0908 7.46 0.429 0.387 Bromoform ND 0.104 0.0908 ND 1.07 0.938 1,1,2,2-Tetrachloroethane ND 0.104 0.0908 ND 0.712 0.623 4-Ethyltoluene 6.13 0.104 0.0908 30.1 0.513 0.446 1,3,5-Trimethylbenzene 14.1 0.104 0.0908 69.2 0.512 0.446 1,2,4-Trimethylbenzene 29.6 0.103 0.0908 146 0.506 0.446 1,3-Dichlorobenzene 0.220 0.106 0.0908 1.32 0.634 0.546 m TO15_Quant_Ambient - R1 EA Job # 0920-079 Page 4 of 25 Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-1S Sample Info : 0920-079; 500mL load; Can #00161 Data File : T20002736.D Dilution : 1 Pressurization Factor : 2.594 Acquisition Date : 2020-09-30 23:29:37 Instrument Method : TO15-SCN2.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * 1,4-Dichlorobenzene ND 0.104 0.0908 ND 0.627 0.546 Benzyl chloride ND 0.103 0.0908 ND 0.535 0.470 1,2-Dichlorobenzene ND 0.105 0.0908 ND 0.633 0.546 1,2,4-Trichlorobenzene ND 0.105 0.0908 ND 0.780 0.674 Hexachlorobutadiene ND 0.105 0.0908 ND 1.12 0.968 Naphthalene 0.889 0.108 0.0908 4.66 0.567 0.476 Internal Standards Response Retention Time (min) Concentration (PPBV)Flag * Bromochloromethane (IS)440,311 12.38 5.01 PASS 1,4-Difluorobenzene (IS)1,598,458 14.10 5.03 PASS Chlorobenzene-d5 (IS)1,356,026 18.37 4.84 PASS (ND) = Not Detected * (J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% TO15_Quant_Ambient - R1 EA Job # 0920-079 Page 5 of 25 Lab QC EA Job # 0920-079 Page 6 of 25 Quantitation Report Enthalpy Analytical, LLC Sample Name : Humid Blank #0703 Sample Info : 500mL load; Can #0702 Data File : T20002728.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2020-09-30 17:05:29 Instrument Method : TO15-SCN2.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Propylene ND 0.0383 0.0350 ND 0.0660 0.0602 Freon 12 (CCl2F2)ND 0.0384 0.0350 ND 0.190 0.173 Freon 114 (C2Cl2F4)ND 0.0398 0.0350 ND 0.279 0.245 Chloromethane ND 0.0389 0.0350 ND 0.0803 0.0723 Chloroethene (Vinyl chloride)ND 0.0399 0.0350 ND 0.102 0.0895 1,3-Butadiene ND 0.0386 0.0350 ND 0.0855 0.0774 Bromomethane ND 0.0392 0.0350 ND 0.152 0.136 Chloroethane ND 0.0401 0.0350 ND 0.106 0.0924 Freon 11 (CCl3F)ND 0.0413 0.0350 ND 0.232 0.197 Ethanol 0.0688 0.0400 0.0400 0.130 0.0754 0.0754 m Freon 113 (C2Cl3F3)ND 0.0396 0.0350 ND 0.304 0.268 1,1-Dichloroethene ND 0.0398 0.0350 ND 0.158 0.139 Acetone 0.0452 0.0395 0.0350 0.107 0.0938 0.0831 Carbon disulfide ND 0.0397 0.0350 ND 0.124 0.109 Isopropyl alcohol ND 0.0396 0.0350 ND 0.0973 0.0860 Methylene chloride 0.0364 0.0401 0.0350 0.126 0.139 0.122 m J trans-1,2-Dichloroethene ND 0.0404 0.0350 ND 0.160 0.139 Methyl tert-butyl ether ND 0.0404 0.0350 ND 0.146 0.126 Hexane ND 0.0403 0.0350 ND 0.142 0.123 1,1-Dichloroethane ND 0.0390 0.0350 ND 0.158 0.142 Vinyl acetate ND 0.0401 0.0350 ND 0.141 0.123 cis-1,2-Dichloroethene ND 0.0398 0.0350 ND 0.158 0.139 Methyl ethyl ketone (2-Butanone)ND 0.0406 0.0350 ND 0.120 0.103 Ethyl acetate ND 0.0400 0.0350 ND 0.144 0.126 Chloroform ND 0.0402 0.0350 ND 0.196 0.171 Tetrahydrofuran ND 0.0399 0.0350 ND 0.118 0.103 1,1,1-Trichloroethane ND 0.0394 0.0350 ND 0.215 0.191 Cyclohexane ND 0.0402 0.0350 ND 0.138 0.120 Carbon tetrachloride ND 0.0400 0.0350 ND 0.252 0.220 Benzene ND 0.0393 0.0350 ND 0.126 0.112 1,2-Dichloroethane ND 0.0404 0.0350 ND 0.163 0.142 Heptane ND 0.0398 0.0350 ND 0.163 0.143 Trichloroethene ND 0.0400 0.0350 ND 0.215 0.188 1,2-Dichloropropane ND 0.0392 0.0350 ND 0.181 0.162 1,4-Dioxane ND 0.0399 0.0350 ND 0.144 0.126 Bromodichloromethane ND 0.0396 0.0350 ND 0.265 0.235 cis-1,3-Dichloropropene ND 0.0390 0.0350 ND 0.177 0.159 Methyl isobutyl ketone ND 0.0408 0.0350 ND 0.167 0.143 Toluene ND 0.0403 0.0350 ND 0.152 0.132 trans-1,3-Dichloropropene ND 0.0404 0.0350 ND 0.184 0.159 1,1,2-Trichloroethane ND 0.0400 0.0350 ND 0.218 0.191 Tetrachloroethene ND 0.0400 0.0350 ND 0.271 0.237 2-Hexanone (Methyl butyl ketone)ND 0.0401 0.0350 ND 0.164 0.143 Dibromochloromethane ND 0.0395 0.0350 ND 0.336 0.298 1,2-Dibromoethane ND 0.0403 0.0350 ND 0.310 0.269 Chlorobenzene ND 0.0410 0.0350 ND 0.189 0.161 Ethylbenzene ND 0.0392 0.0350 ND 0.170 0.152 m-/p-Xylenes ND 0.0404 0.0350 ND 0.175 0.152 o-Xylene ND 0.0396 0.0350 ND 0.172 0.152 Styrene ND 0.0388 0.0350 ND 0.165 0.149 Bromoform ND 0.0400 0.0350 ND 0.413 0.362 1,1,2,2-Tetrachloroethane ND 0.0400 0.0350 ND 0.274 0.240 4-Ethyltoluene ND 0.0402 0.0350 ND 0.198 0.172 1,3,5-Trimethylbenzene ND 0.0402 0.0350 ND 0.197 0.172 1,2,4-Trimethylbenzene ND 0.0397 0.0350 ND 0.195 0.172 1,3-Dichlorobenzene ND 0.0407 0.0350 ND 0.245 0.210 TO15_Quant_Ambient - v2 EA Job # 0920-079 Page 7 of 25 Quantitation Report Enthalpy Analytical, LLC Sample Name : Humid Blank #0703 Sample Info : 500mL load; Can #0702 Data File : T20002728.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2020-09-30 17:05:29 Instrument Method : TO15-SCN2.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * 1,4-Dichlorobenzene ND 0.0402 0.0350 ND 0.242 0.210 Benzyl chloride ND 0.0398 0.0350 ND 0.206 0.181 1,2-Dichlorobenzene ND 0.0406 0.0350 ND 0.244 0.210 1,2,4-Trichlorobenzene ND 0.0405 0.0350 ND 0.301 0.260 Hexachlorobutadiene ND 0.0406 0.0350 ND 0.433 0.373 Naphthalene 0.0385 0.0417 0.0350 0.202 0.219 0.183 J Internal Standards Response Retention Time (min) Concentration (PPBV)Flag * Bromochloromethane (IS)509,422 12.37 5.01 PASS 1,4-Difluorobenzene (IS)1,863,661 14.10 5.03 PASS Chlorobenzene-d5 (IS)1,542,078 18.37 4.84 PASS (ND) = Not Detected * (J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% TO15_Quant_Ambient - v2 EA Job # 0920-079 Page 8 of 25 QC Summary Report Enthalpy Analytical, LLC Sample Name : 5ppbv TO15 LCS Sample Info : 125mL load; Can #2075; GCMSPrepPg946 Data File : T20002725.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2020-09-30 14:35:27 Instrument Method : TO15-SCN2.M Matrix : AIR Target Compound Response Concentration (PPBV) Tag Value (PPBV) % Recovery Flag Propylene 502,352 4.57 4.83 94.6 PASS Freon 12 (CCl2F2)1,034,986 4.57 4.90 93.3 PASS Freon 114 (C2Cl2F4)1,100,889 4.70 5.01 93.7 PASS Chloromethane 540,364 4.72 4.95 95.5 PASS Chloroethene (Vinyl chloride)445,930 5.03 5.00 100.7 PASS 1,3-Butadiene 505,459 4.98 4.87 102.4 PASS Bromomethane 373,375 5.17 4.91 105.5 PASS Chloroethane 205,089 4.77 5.08 94.0 PASS Freon 11 (CCl3F)1,153,655 4.88 5.28 92.5 PASS Ethanol 244,996 4.42 4.96 89.3 PASS 1,1-Dichloroethene 760,125 4.55 5.03 90.4 PASS Freon 113 (C2Cl3F3)724,996 4.88 5.08 96.1 PASS Acetone 916,361 4.20 5.01 83.8 PASS Isopropyl alcohol 1,050,113 4.83 4.99 96.9 PASS Carbon disulfide 1,108,771 4.47 4.99 89.7 PASS Methylene chloride 736,175 4.04 5.12 78.8 PASS Methyl tert-butyl ether 1,038,958 4.50 5.14 87.5 PASS trans-1,2-Dichloroethene 671,580 4.57 5.10 89.6 PASS Hexane 736,758 4.72 5.08 92.9 PASS 1,1-Dichloroethane 778,279 4.39 4.97 88.5 PASS Vinyl acetate 1,554,434 5.29 5.12 103.5 PASS Methyl ethyl ketone (2-Butanone)191,019 4.65 5.17 89.9 PASS cis-1,2-Dichloroethene 778,983 4.55 5.05 90.1 PASS Ethyl acetate 215,826 4.86 4.99 97.4 PASS Tetrahydrofuran 177,330 4.58 5.06 90.6 PASS Chloroform 850,181 4.64 5.02 92.6 PASS 1,1,1-Trichloroethane 863,442 4.66 5.05 92.3 PASS Cyclohexane 781,104 4.76 5.13 93.0 PASS Carbon tetrachloride 969,370 4.94 5.04 98.1 PASS Benzene 1,149,730 4.91 5.03 97.6 PASS 1,2-Dichloroethane 622,255 4.95 5.15 96.2 PASS Heptane 476,707 5.00 5.07 98.7 PASS Trichloroethene 589,208 5.57 5.06 110.3 PASS 1,2-Dichloropropane 486,501 4.72 5.04 93.7 PASS 1,4-Dioxane 271,826 5.29 5.02 105.5 PASS Bromodichloromethane 890,473 5.10 5.05 101.0 PASS cis-1,3-Dichloropropene 660,007 4.84 4.97 97.6 PASS Methyl isobutyl ketone 1,563,744 5.57 5.20 107.1 PASS Toluene 1,387,899 5.13 5.09 100.9 PASS trans-1,3-Dichloropropene 680,078 4.78 5.16 92.7 PASS 1,1,2-Trichloroethane 497,062 5.43 5.09 106.8 PASS Tetrachloroethene 767,196 5.32 5.12 103.9 PASS QC_SUM-v2 EA Job # 0920-079 Page 9 of 25 QC Summary Report Enthalpy Analytical, LLC Sample Name : 5ppbv TO15 LCS Sample Info : 125mL load; Can #2075; GCMSPrepPg946 Data File : T20002725.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2020-09-30 14:35:27 Instrument Method : TO15-SCN2.M Matrix : AIR Target Compound Response Concentration (PPBV) Tag Value (PPBV) % Recovery Flag 2-Hexanone (Methyl butyl ketone)1,509,683 5.42 5.12 106.0 PASS Dibromochloromethane 1,012,530 5.78 5.04 114.8 PASS 1,2-Dibromoethane 845,894 5.43 5.12 106.2 PASS Chlorobenzene 1,125,456 5.38 5.15 104.4 PASS Ethylbenzene 1,693,008 4.90 4.97 98.6 PASS m-/p-Xylenes 1,405,159 5.12 5.07 101.0 PASS o-Xylene 1,378,165 4.98 5.01 99.3 PASS Styrene 1,082,727 5.22 4.90 106.6 PASS Bromoform 1,001,025 6.21 5.02 123.9 PASS 1,1,2,2-Tetrachloroethane 1,127,312 5.09 5.06 100.8 PASS 4-Ethyltoluene 2,098,171 5.38 5.09 105.8 PASS 1,3,5-Trimethylbenzene 1,689,882 5.13 5.07 101.2 PASS 1,2,4-Trimethylbenzene 1,718,597 5.17 5.01 103.2 PASS 1,3-Dichlorobenzene 1,277,049 5.46 5.08 107.4 PASS 1,4-Dichlorobenzene 1,267,430 5.21 5.03 103.6 PASS Benzyl chloride 1,662,880 5.51 5.03 109.5 PASS 1,2-Dichlorobenzene 1,262,726 5.44 5.07 107.3 PASS 1,2,4-Trichlorobenzene 1,170,520 5.53 4.98 111.0 PASS Hexachlorobutadiene 988,838 5.47 4.94 110.7 PASS Naphthalene 2,621,203 6.01 5.04 119.5 PASS QC_SUM-v2 EA Job # 0920-079 Page 10 of 25 Quantitation Report Enthalpy Analytical, LLC Sample Name : 5ppbv TO15 LCS Sample Info : 125mL load; Can #2075; GCMSPrepPg946 Data File : T20002725.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2020-09-30 14:35:27 Instrument Method : TO15-SCN2.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Propylene 4.57 0.0383 0.0350 7.86 0.0660 0.0602 Freon 12 (CCl2F2)4.57 0.0384 0.0350 22.6 0.190 0.173 Freon 114 (C2Cl2F4)4.70 0.0398 0.0350 32.8 0.279 0.245 Chloromethane 4.72 0.0389 0.0350 9.76 0.0803 0.0723 Chloroethene (Vinyl chloride)5.03 0.0399 0.0350 12.9 0.102 0.0895 1,3-Butadiene 4.98 0.0386 0.0350 11.0 0.0855 0.0774 Bromomethane 5.17 0.0392 0.0350 20.1 0.152 0.136 Chloroethane 4.77 0.0401 0.0350 12.6 0.106 0.0924 Freon 11 (CCl3F)4.88 0.0413 0.0350 27.4 0.232 0.197 Ethanol 4.42 0.0400 0.0400 8.34 0.0754 0.0754 Freon 113 (C2Cl3F3)4.88 0.0396 0.0350 37.4 0.304 0.268 1,1-Dichloroethene 4.55 0.0398 0.0350 18.0 0.158 0.139 Acetone 4.20 0.0395 0.0350 9.97 0.0938 0.0831 Carbon disulfide 4.47 0.0397 0.0350 13.9 0.124 0.109 Isopropyl alcohol 4.83 0.0396 0.0350 11.9 0.0973 0.0860 Methylene chloride 4.04 0.0401 0.0350 14.0 0.139 0.122 m trans-1,2-Dichloroethene 4.57 0.0404 0.0350 18.1 0.160 0.139 Methyl tert-butyl ether 4.50 0.0404 0.0350 16.2 0.146 0.126 Hexane 4.72 0.0403 0.0350 16.6 0.142 0.123 1,1-Dichloroethane 4.39 0.0390 0.0350 17.8 0.158 0.142 Vinyl acetate 5.29 0.0401 0.0350 18.6 0.141 0.123 m cis-1,2-Dichloroethene 4.55 0.0398 0.0350 18.1 0.158 0.139 m Methyl ethyl ketone (2-Butanone)4.65 0.0406 0.0350 13.7 0.120 0.103 Ethyl acetate 4.86 0.0400 0.0350 17.5 0.144 0.126 Chloroform 4.64 0.0402 0.0350 22.7 0.196 0.171 Tetrahydrofuran 4.58 0.0399 0.0350 13.5 0.118 0.103 1,1,1-Trichloroethane 4.66 0.0394 0.0350 25.4 0.215 0.191 Cyclohexane 4.76 0.0402 0.0350 16.4 0.138 0.120 Carbon tetrachloride 4.94 0.0400 0.0350 31.1 0.252 0.220 Benzene 4.91 0.0393 0.0350 15.7 0.126 0.112 1,2-Dichloroethane 4.95 0.0404 0.0350 20.0 0.163 0.142 Heptane 5.00 0.0398 0.0350 20.5 0.163 0.143 Trichloroethene 5.57 0.0400 0.0350 30.0 0.215 0.188 1,2-Dichloropropane 4.72 0.0392 0.0350 21.8 0.181 0.162 1,4-Dioxane 5.29 0.0399 0.0350 19.1 0.144 0.126 m Bromodichloromethane 5.10 0.0396 0.0350 34.2 0.265 0.235 cis-1,3-Dichloropropene 4.84 0.0390 0.0350 22.0 0.177 0.159 Methyl isobutyl ketone 5.57 0.0408 0.0350 22.8 0.167 0.143 Toluene 5.13 0.0403 0.0350 19.3 0.152 0.132 trans-1,3-Dichloropropene 4.78 0.0404 0.0350 21.7 0.184 0.159 1,1,2-Trichloroethane 5.43 0.0400 0.0350 29.6 0.218 0.191 Tetrachloroethene 5.32 0.0400 0.0350 36.1 0.271 0.237 2-Hexanone (Methyl butyl ketone)5.42 0.0401 0.0350 22.2 0.164 0.143 Dibromochloromethane 5.78 0.0395 0.0350 49.3 0.336 0.298 1,2-Dibromoethane 5.43 0.0403 0.0350 41.7 0.310 0.269 Chlorobenzene 5.38 0.0410 0.0350 24.8 0.189 0.161 Ethylbenzene 4.90 0.0392 0.0350 21.3 0.170 0.152 m-/p-Xylenes 5.12 0.0404 0.0350 22.2 0.175 0.152 o-Xylene 4.98 0.0396 0.0350 21.6 0.172 0.152 Styrene 5.22 0.0388 0.0350 22.3 0.165 0.149 Bromoform 6.21 0.0400 0.0350 64.2 0.413 0.362 1,1,2,2-Tetrachloroethane 5.09 0.0400 0.0350 35.0 0.274 0.240 4-Ethyltoluene 5.38 0.0402 0.0350 26.4 0.198 0.172 1,3,5-Trimethylbenzene 5.13 0.0402 0.0350 25.2 0.197 0.172 1,2,4-Trimethylbenzene 5.17 0.0397 0.0350 25.4 0.195 0.172 1,3-Dichlorobenzene 5.46 0.0407 0.0350 32.8 0.245 0.210 TO15_Quant_Ambient - v2 EA Job # 0920-079 Page 11 of 25 Quantitation Report Enthalpy Analytical, LLC Sample Name : 5ppbv TO15 LCS Sample Info : 125mL load; Can #2075; GCMSPrepPg946 Data File : T20002725.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2020-09-30 14:35:27 Instrument Method : TO15-SCN2.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * 1,4-Dichlorobenzene 5.21 0.0402 0.0350 31.3 0.242 0.210 Benzyl chloride 5.51 0.0398 0.0350 28.5 0.206 0.181 1,2-Dichlorobenzene 5.44 0.0406 0.0350 32.7 0.244 0.210 1,2,4-Trichlorobenzene 5.53 0.0405 0.0350 41.0 0.301 0.260 Hexachlorobutadiene 5.47 0.0406 0.0350 58.3 0.433 0.373 Naphthalene 6.01 0.0417 0.0350 31.5 0.219 0.183 Internal Standards Response Retention Time (min) Concentration (PPBV)Flag * Bromochloromethane (IS)484,836 12.38 5.01 PASS 1,4-Difluorobenzene (IS)1,787,545 14.10 5.03 PASS Chlorobenzene-d5 (IS)1,495,244 18.37 4.84 PASS (ND) = Not Detected * (J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% TO15_Quant_Ambient - v2 EA Job # 0920-079 Page 12 of 25 QC Summary Report Enthalpy Analytical, LLC Sample Name : 5ppbv TO15 LCS LD Sample Info : 125mL load; Can #2075; GCMSPrepPg946 Data File : T20002726.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2020-09-30 15:18:46 Instrument Method : TO15-SCN2.M Matrix : AIR Target Compound Response Concentration (PPBV) Tag Value (PPBV) % Recovery Flag Propylene 510,358 4.58 4.83 94.8 PASS Freon 12 (CCl2F2)1,035,915 4.51 4.90 92.1 PASS Freon 114 (C2Cl2F4)1,146,822 4.83 5.01 96.3 PASS Chloromethane 550,376 4.75 4.95 96.0 PASS Chloroethene (Vinyl chloride)448,349 4.99 5.00 99.9 PASS 1,3-Butadiene 502,398 4.88 4.87 100.4 PASS Bromomethane 365,737 5.00 4.91 102.0 PASS Chloroethane 202,652 4.65 5.08 91.6 PASS Freon 11 (CCl3F)1,157,037 4.83 5.28 91.6 PASS Ethanol 248,668 4.43 4.96 89.4 PASS 1,1-Dichloroethene 766,739 4.53 5.03 90.0 PASS Freon 113 (C2Cl3F3)733,514 4.87 5.08 96.0 PASS Acetone 924,155 4.18 5.01 83.4 PASS Isopropyl alcohol 1,044,825 4.74 4.99 95.1 PASS Carbon disulfide 1,130,012 4.50 4.99 90.2 PASS Methylene chloride 739,278 4.00 5.12 78.1 PASS Methyl tert-butyl ether 1,065,858 4.55 5.14 88.5 PASS trans-1,2-Dichloroethene 686,552 4.61 5.10 90.4 PASS Hexane 748,669 4.73 5.08 93.2 PASS 1,1-Dichloroethane 777,821 4.33 4.97 87.3 PASS Vinyl acetate 1,570,727 5.28 5.12 103.2 PASS Methyl ethyl ketone (2-Butanone)189,334 4.54 5.17 87.9 PASS cis-1,2-Dichloroethene 789,658 4.55 5.05 90.2 PASS Ethyl acetate 215,430 4.79 4.99 95.9 PASS Tetrahydrofuran 182,450 4.65 5.06 92.0 PASS Chloroform 846,157 4.56 5.02 90.9 PASS 1,1,1-Trichloroethane 860,359 4.58 5.05 90.7 PASS Cyclohexane 789,848 4.75 5.13 92.7 PASS Carbon tetrachloride 978,940 4.92 5.04 97.7 PASS Benzene 1,149,825 4.90 5.03 97.4 PASS 1,2-Dichloroethane 619,777 4.92 5.15 95.5 PASS Heptane 482,542 5.05 5.07 99.6 PASS Trichloroethene 585,012 5.52 5.06 109.2 PASS 1,2-Dichloropropane 507,274 4.90 5.04 97.4 PASS 1,4-Dioxane 274,730 5.33 5.02 106.4 PASS Bromodichloromethane 890,528 5.09 5.05 100.7 PASS cis-1,3-Dichloropropene 661,028 4.84 4.97 97.5 PASS Methyl isobutyl ketone 1,564,170 5.55 5.20 106.9 PASS Toluene 1,390,195 5.08 5.09 99.8 PASS trans-1,3-Dichloropropene 691,223 4.81 5.16 93.1 PASS 1,1,2-Trichloroethane 500,640 5.40 5.09 106.3 PASS Tetrachloroethene 767,658 5.26 5.12 102.8 PASS QC_SUM-v2 EA Job # 0920-079 Page 13 of 25 QC Summary Report Enthalpy Analytical, LLC Sample Name : 5ppbv TO15 LCS LD Sample Info : 125mL load; Can #2075; GCMSPrepPg946 Data File : T20002726.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2020-09-30 15:18:46 Instrument Method : TO15-SCN2.M Matrix : AIR Target Compound Response Concentration (PPBV) Tag Value (PPBV) % Recovery Flag 2-Hexanone (Methyl butyl ketone)1,525,641 5.41 5.12 105.8 PASS Dibromochloromethane 1,023,189 5.78 5.04 114.6 PASS 1,2-Dibromoethane 859,483 5.45 5.12 106.6 PASS Chlorobenzene 1,150,903 5.43 5.15 105.5 PASS Ethylbenzene 1,717,277 4.91 4.97 98.8 PASS m-/p-Xylenes 1,394,391 5.02 5.07 99.0 PASS o-Xylene 1,383,293 4.93 5.01 98.5 PASS Styrene 1,095,426 5.22 4.90 106.6 PASS Bromoform 1,008,116 6.18 5.02 123.3 PASS 1,1,2,2-Tetrachloroethane 1,133,849 5.06 5.06 100.2 PASS 4-Ethyltoluene 2,103,100 5.33 5.09 104.7 PASS 1,3,5-Trimethylbenzene 1,703,909 5.11 5.07 100.9 PASS 1,2,4-Trimethylbenzene 1,727,040 5.13 5.01 102.5 PASS 1,3-Dichlorobenzene 1,298,093 5.48 5.08 107.9 PASS 1,4-Dichlorobenzene 1,291,343 5.24 5.03 104.3 PASS Benzyl chloride 1,680,031 5.50 5.03 109.3 PASS 1,2-Dichlorobenzene 1,281,627 5.45 5.07 107.6 PASS 1,2,4-Trichlorobenzene 1,192,279 5.57 4.98 111.8 PASS Hexachlorobutadiene 996,510 5.45 4.94 110.3 PASS Naphthalene 2,692,436 6.11 5.04 121.3 PASS QC_SUM-v2 EA Job # 0920-079 Page 14 of 25 Quantitation Report Enthalpy Analytical, LLC Sample Name : 5ppbv TO15 LCS LD Sample Info : 125mL load; Can #2075; GCMSPrepPg946 Data File : T20002726.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2020-09-30 15:18:46 Instrument Method : TO15-SCN2.M Matrix : AIR Target Compound Concentration(PPBV)RL(PPBV)MDL(PPBV)Concentration(ug/m3)RL(ug/m3)MDL(ug/m3) % Diff Flag * Propylene 4.58 0.0383 0.0350 7.88 0.0660 0.0602 0.2 Freon 12 (CCl2F2) 4.51 0.0384 0.0350 22.3 0.190 0.173 1.3 Freon 114 (C2Cl2F4) 4.83 0.0398 0.0350 33.7 0.279 0.245 2.7 Chloromethane 4.75 0.0389 0.0350 9.80 0.0803 0.0723 0.5 Chloroethene (Vinyl chloride) 4.99 0.0399 0.0350 12.8 0.102 0.0895 0.8 1,3-Butadiene 4.88 0.0386 0.0350 10.8 0.0855 0.0774 1.9 Bromomethane 5.00 0.0392 0.0350 19.4 0.152 0.136 3.4 Chloroethane 4.65 0.0401 0.0350 12.3 0.106 0.0924 2.5 Freon 11 (CCl3F) 4.83 0.0413 0.0350 27.1 0.232 0.197 1.0 Ethanol 4.43 0.0400 0.0400 8.35 0.0754 0.0754 0.1 Freon 113 (C2Cl3F3) 4.87 0.0396 0.0350 37.3 0.304 0.268 0.2 1,1-Dichloroethene 4.53 0.0398 0.0350 17.9 0.158 0.139 0.5 Acetone 4.18 0.0395 0.0350 9.92 0.0938 0.0831 0.5 Carbon disulfide 4.50 0.0397 0.0350 14.0 0.124 0.109 0.6 Isopropyl alcohol 4.74 0.0396 0.0350 11.7 0.0973 0.0860 1.8 Methylene chloride 4.00 0.0401 0.0350 13.9 0.139 0.122 0.9 m trans-1,2-Dichloroethene 4.61 0.0404 0.0350 18.3 0.160 0.139 0.9 Methyl tert-butyl ether 4.55 0.0404 0.0350 16.4 0.146 0.126 1.2 Hexane 4.73 0.0403 0.0350 16.7 0.142 0.123 0.3 1,1-Dichloroethane 4.33 0.0390 0.0350 17.5 0.158 0.142 1.4 Vinyl acetate 5.28 0.0401 0.0350 18.6 0.141 0.123 0.3 m cis-1,2-Dichloroethene 4.55 0.0398 0.0350 18.1 0.158 0.139 0.0 Methyl ethyl ketone (2-Butanone) 4.54 0.0406 0.0350 13.4 0.120 0.103 2.2 Ethyl acetate 4.79 0.0400 0.0350 17.2 0.144 0.126 1.5 Chloroform 4.56 0.0402 0.0350 22.3 0.196 0.171 1.8 Tetrahydrofuran 4.65 0.0399 0.0350 13.7 0.118 0.103 1.5 1,1,1-Trichloroethane 4.58 0.0394 0.0350 25.0 0.215 0.191 1.7 Cyclohexane 4.75 0.0402 0.0350 16.4 0.138 0.120 0.2 Carbon tetrachloride 4.92 0.0400 0.0350 30.9 0.252 0.220 0.4 Benzene 4.90 0.0393 0.0350 15.6 0.126 0.112 0.3 1,2-Dichloroethane 4.92 0.0404 0.0350 19.9 0.163 0.142 0.7 Heptane 5.05 0.0398 0.0350 20.7 0.163 0.143 1.0 Trichloroethene 5.52 0.0400 0.0350 29.7 0.215 0.188 1.0 1,2-Dichloropropane 4.90 0.0392 0.0350 22.7 0.181 0.162 3.9 1,4-Dioxane 5.33 0.0399 0.0350 19.2 0.144 0.126 0.8 m Bromodichloromethane 5.09 0.0396 0.0350 34.1 0.265 0.235 0.3 cis-1,3-Dichloropropene 4.84 0.0390 0.0350 22.0 0.177 0.159 0.1 Methyl isobutyl ketone 5.55 0.0408 0.0350 22.7 0.167 0.143 0.2 Toluene 5.08 0.0403 0.0350 19.2 0.152 0.132 1.0 trans-1,3-Dichloropropene 4.81 0.0404 0.0350 21.8 0.184 0.159 0.4 1,1,2-Trichloroethane 5.40 0.0400 0.0350 29.5 0.218 0.191 0.5 Tetrachloroethene 5.26 0.0400 0.0350 35.7 0.271 0.237 1.1 2-Hexanone (Methyl butyl ketone) 5.41 0.0401 0.0350 22.2 0.164 0.143 0.1 Dibromochloromethane 5.78 0.0395 0.0350 49.2 0.336 0.298 0.1 1,2-Dibromoethane 5.45 0.0403 0.0350 41.9 0.310 0.269 0.4 Chlorobenzene 5.43 0.0410 0.0350 25.0 0.189 0.161 1.0 Ethylbenzene 4.91 0.0392 0.0350 21.3 0.170 0.152 0.2 m-/p-Xylenes 5.02 0.0404 0.0350 21.8 0.175 0.152 2.0 o-Xylene 4.93 0.0396 0.0350 21.4 0.172 0.152 0.8 Styrene 5.22 0.0388 0.0350 22.2 0.165 0.149 0.0 Bromoform 6.18 0.0400 0.0350 63.9 0.413 0.362 0.5 1,1,2,2-Tetrachloroethane 5.06 0.0400 0.0350 34.8 0.274 0.240 0.6 4-Ethyltoluene 5.33 0.0402 0.0350 26.2 0.198 0.172 1.0 1,3,5-Trimethylbenzene 5.11 0.0402 0.0350 25.1 0.197 0.172 0.4 1,2,4-Trimethylbenzene 5.13 0.0397 0.0350 25.2 0.195 0.172 0.7 1,3-Dichlorobenzene 5.48 0.0407 0.0350 33.0 0.245 0.210 0.4 1,4-Dichlorobenzene 5.24 0.0402 0.0350 31.5 0.242 0.210 0.7 Benzyl chloride 5.50 0.0398 0.0350 28.5 0.206 0.181 0.2 1,2-Dichlorobenzene 5.45 0.0406 0.0350 32.8 0.244 0.210 0.3 1,2,4-Trichlorobenzene 5.57 0.0405 0.0350 41.3 0.301 0.260 0.6 Hexachlorobutadiene 5.45 0.0406 0.0350 58.1 0.433 0.373 0.4 Naphthalene 6.11 0.0417 0.0350 32.0 0.219 0.183 1.5 TO15_Quant_Ambient - v2 EA Job # 0920-079 Page 15 of 25 Quantitation Report Enthalpy Analytical, LLC Sample Name : 5ppbv TO15 LCS LD Sample Info : 125mL load; Can #2075; GCMSPrepPg946 Data File : T20002726.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2020-09-30 15:18:46 Instrument Method : TO15-SCN2.M Matrix : AIR Target Compound Concentration(PPBV)RL(PPBV)MDL(PPBV)Concentration(ug/m3)RL(ug/m3)MDL(ug/m3) % Diff Flag * Internal Standards Response Retention Time (min) Concentration (PPBV) Flag * Bromochloromethane (IS) 491,380 12.38 5.01 PASS 1,4-Difluorobenzene (IS) 1,792,230 14.10 5.03 PASS Chlorobenzene-d5 (IS) 1,513,182 18.37 4.84 PASS (ND) = Not Detected * (J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% TO15_Quant_Ambient - v2 EA Job # 0920-079 Page 16 of 25 Canister and Controller Data Sheet Enthalpy Analytical, LLC Client Name: Hart & Hickman - Raleigh Client #: CAM-011 Enthalpy Job #: 0920-079 Controller ID Data File Initial Flow (cc/min) Return Flow (cc/min) E-004 T20001094 183.6 181.2 Canister ID Blank Check Datafile Canister Pressure Pre-Sample (mmHg) Canister Pressure Post-Sample (mmHg) Canister Pressure Final (mmHg) Canister Pressurization Factor 161 T20002270 -760 -153 807 2.594 Date Prepared: 9/10/20 Prepared By: AAMDate Received: 9/11/20 Received By: MBL Controller Data Canister Data 0920-079 CanContrDataSheet V6c (complete).xls EA Job # 0920-079 Page 17 of 25 Narrative Summary EA Job # 0920-079 Page 18 of 25 Enthalpy Analytical Narrative Summary Company Hart & Hickman - Raleigh Client #CAM-011 Analyst TDD Job #0920-079 Parameters EPA Method TO-15 # Samples 1 (1.29L) Canister Custody Matt Loftis received the sample on 9/11/20 after being relinquished by Hart & Hickman – Raleigh. The sample was received at ambient temperature and in good condition. Prior to, during, and after analysis, the sample was kept under lock with access only to authorized personnel by Enthalpy Analytical, LLC. Analysis The sample was analyzed for the TO-15 target compound list using the analytical procedures in EPA Method TO-15, Determination of Volatile Organic Compounds (VOCs) In Air Collected In Specially-Prepared Canisters And Analyzed by Gas Chromatography/Mass Spectrometry (GC/MS). Upon receipt, the canister pressure was measured and recorded. The can was then pressurized and a dilution ratio was calculated (see page 17). The Agilent Technologies Model 7890A, Gas Chromatograph "Tobias" (S/N CN10823053) was equipped with a 5973N Inert MSD (S/N US03940689) and a Restek Rxi-624 Sil MS, 60 m x 0.32 mm x 1.8 µm (S/N 1607896) capillary column for this analysis. The sample and standards were introduced directly to the analyzer using an Entech 7100A Preconcentrator. Calibration The associated BFB tunes met method acceptance criteria. The initial calibration (T050520A-TO15) met the 30% RSD criteria. The initial calibration verification met the 30% recovery criteria. The continuing calibration met the 30% difference criteria. Full calibration data is available upon request. Chromatographic Conditions The acquisition method (TO15-SCN2.M) is not included in this report but is available upon request. QC Notes All internal standard area responses and retention time criteria were met for these analyses. The Laboratory Control Standards (LCS) associated with this sample data met 70-130% recovery criteria. EA Job # 0920-079 Page 19 of 25 Enthalpy Analytical Narrative Summary (continued) QC Notes (continued) The Laboratory Duplicate (LD) associated with this sample data met the 25% difference acceptance criteria. No target analytes were identified at concentrations greater than 3 times the MDL in the associated humid blank. The sample was analyzed within the 30-day holding time required by the method. Reporting Notes The LCS was analyzed in duplicate and has been reported as a Laboratory Duplicate in the Lab QC section of this report. These analyses met the requirements of the TNI Standard. Any deviations from the requirements of the reference method or TNI Standard have been stated above. The results presented in this report are representative of the samples as provided to the laboratory. EA Job # 0920-079 Page 20 of 25 General Reporting Notes The following are general reporting notes that are applicable to all Enthalpy Analytical, LLC data reports, unless specifically noted otherwise.  Any analysis which refers to the method as “Type” represents a planned deviation from the reference method. For instance a Hydrogen Sulfide assay from a Tedlar bag would be labeled as “EPA Method 16-Type” because Tedlar bags are not mentioned as one of the collection options in EPA Method 16.  The acronym MDL represents the Minimum Detection Limit. Below this value the laboratory cannot determine the presence of the analyte of interest reliably.  The acronym LOQ represents the Limit of Quantification. Below this value the laboratory cannot quantitate the analyte of interest within the criteria of the method.  The acronym ND following a value indicates a non-detect or analytical result below the MDL.  The letter J in the Qualifier or Flag column in the results indicates that the value is between the MDL and the LOQ. The laboratory can positively identify the analyte of interest as present, but the value should be considered an estimate.  The letter E in the Qualifier or Flag column indicates an analytical result exceeding 100% of the highest calibration point. The associated value should be considered as an estimate.  Sample results are presented ‘as measured’ for single injection methodologies, or an average value if multiple injections are made. If all injections are below the MDL, the sample is considered non-detect and the ND value is presented. If one, but not all, are below the MDL, the MDL value is used for any injections that are below the MDL. For example, if the MDL is 0.500 and LOQ is 1.00, and the instrument measures 0.355, 0.620, and 0.442 - the result reported is the average of 0.500, 0.620, and 0.500 - - - i.e. 0.540 with a J flag.  When a spike recovery (Bag Spike, Collocated Spike Train, or liquid matrix spike) is being calculated, the native (unspiked) sample result is used in the calculations, as long as the value is above the MDL. If a sample is ND, then 0 is used as the native amount (not the MDL value).  The acronym DF represents Dilution Factor. This number represents dilution of the sample during the preparation and/or analysis process. The analytical result taken from a laboratory instrument is multiplied by the DF to determine the final undiluted sample results.  The addition of MS to the Sample ID represents a Matrix Spike. An aliquot of an actual sample is spiked with a known amount of analyte so that a percent recovery value can be determined. The MS analysis indicates what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample matrix interferes with the analysis of the analyte(s). EA Job # 0920-079 Page 21 of 25 General Reporting Notes (continued)  The addition of MSD to the Sample ID represents a Matrix Spike Duplicate. Prepared in the same manner as a MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality by showing the consistency of results gained by performing the same steps multiple times.  The addition of LD to the Sample ID represents a Laboratory Duplicate. The analyst prepares an additional aliquot of sample for testing and the results of the duplicate analysis are compared to the initial result. The result should have a difference value of within 10% of the initial result (if the results of the original analysis are greater than the LOQ).  The addition of AD to the Sample ID represents an Alternate Dilution. The analyst prepares an additional aliquot at a different dilution factor (usually double the initial factor). This analysis helps confirm that no additional compound is present and coeluting or sharing absorbance with the analyte of interest, as they would have a different response/absorbance than the analyte of interest.  The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample matrix, prepared and analyzed by the laboratory using the same reagents, spiking standards and procedures used for the client samples. The LCS is used to assess the control of the laboratory’s analytical system. Whenever spikes are prepared for our client projects, two spikes are retained as LCSs. The LCSs are labeled with the associated project number and kept in-house at the appropriate temperature conditions. When the project samples are received for analysis, the LCSs are analyzed to confirm that the analyte could be recovered from the media, separate from the samples which were used on the project and which may have been affected by source matrix, sample collection, and/or sample transport.  Significant Figures: Where the reported value is much greater than unity (1.00) in the units expressed, the number is rounded to a whole number of units, rather than to 3 significant figures. For example, a value of 10,456.45 ug catch is rounded to 10,456 ug. There are five significant digits displayed, but no confidence should be placed on more than two significant digits. In the case of small numbers, generally 3 significant figures are presented, but still only 2 should be used with confidence. Many neat materials are only certified to 3 digits, and as the mathematically correct final result is always 1 digit less than all its pre-cursors - 2 significant figures are what are most defensible.  Manual Integration: The data systems used for processing will flag manually integrated peaks with an “M”. There are several reasons a peak may be manually integrated. These reasons will be identified by the following two letter designations on sample chromatograms, if provided in the report. The peak was not integrated by the software “NI”, the peak was integrated incorrectly by the software “II” or the wrong peak was integrated by the software “WP”. These codes will accompany the analyst’s manual integration stamp placed next to the compound name on the chromatogram. EA Job # 0920-079 Page 22 of 25 Sample Custody EA Job # 0920-079 Page 23 of 25 7 ~ENTH.AlP)­Air Chain of Custody Record Turn Around Time (rush by advanced notice only)I" .~... Lab No: Standard: 5 Day: 3 Day: A N A L Y T I C A l Page : of 2 Day: 1 Day: Custom TAT: CUSTOMER INFORMATION PROJECT INFORMATION #N/A Company: Hart & Hickman Name: Cameron Village Condominiums #N/A ReportTo: Justin Ballard " Number: CAM-Oll Special Instructions: HOLD SG-1S Email: jballard @harth ickman.com P.O. #: CAM-Oll ~ddress: 3921 Sunset Ridge Rd. #301 Address: Raleigh. NC Phone: 919-847-4241 GloballD: Fax: Sampled By: Jayna Sananikone Analysis Requested g 0 :r H&H VOCs by TO-15 LIl .-t I Type Equipment Information Sampling Information 0 I­ >.0 (I) Indoor Size Flow VI Sample 10 Sample Start Vacuum Sample End Sample End U(A) Ambient Sample Start Vacuum End 0Canister 10 (1L,3L, Controller Start(SV) Soil Vapor Date Time Date Time ("Hg) > (5) Source 6l,1SL) 10 ("Hg) :r o(l :r 1 SG-1S SV 161 1L 9/10/2020 11:40:00 AM 27 9/10/2020 11:50:00 AM 3 X 2 3 4 5 6 7 8 9 10 Signature Print Name Company / Title Date /Time 1 Relinquished By: I~£V-~___ J 1:\'1"1 ~ J~htt.'ll~Y"4-t( ~H cl/lI V) /tOO 1 Received By: -£../Jtt~/A"'" ',,"-'qV_ ,~'~ ~('8Vlt i?t£J ~v b=:P+ 0/1I;;' 0 IL&D 2 Relinquished By: ~,~ ~ Arenf AodJr ~A 'V1l/JO /(Bk 2 Received By: -4"{,A~_ L A.,L-... ... /""tJ1rl'J "GA /D.~~ J): 1/-0........ -' ~,...t-ey:t-II-<-.O 3 Relinquished By : \ 3 Received By: AII'1~"Y"A-r -r~-(). c"ood Lo"l.d,:~.o" 0.,...."-z.C' EA Job # 0920-079 Page 24 of 25 This Is The Last Page Of This Report. EA Job # 0920-079 Page 25 of 25 Appendix D July 2020 DEQ Risk Calculator Results Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Prepared By:Hart & Hickman, PC 3921 Sunset Ridge Road, Suite 301, Raleigh, North Carolina 27529 SG-1S North Carolina Department of Environmental Quality Risk Calculator Cameron Village Condominiums 1801 Cameron Street, Raleigh, Wake County, North Carolina Brownfields Program BPN 24017-20-092 July 2020 May 2020 EPA RSL Table North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-1S Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-1S Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 23.6 SG-1S 67-64-1 Acetone ug/m3 4.28 SG-1S 71-43-2 Benzene ug/m3 0.306 SG-1S 106-99-0 Butadiene, 1,3-ug/m3 1.11 SG-1S 75-15-0 Carbon Disulfide ug/m3 0.544 SG-1S 108-90-7 Chlorobenzene ug/m3 18.6 SG-1S 67-66-3 Chloroform ug/m3 0.218 SG-1S 74-87-3 Chloromethane ug/m3 5.79 SG-1S 110-82-7 Cyclohexane ug/m3 2 75-71-8 Dichlorodifluoromethane ug/m3 0.36 SG-1S 123-91-1 Dioxane, 1,4-J ug/m3 1.98 SG 141-78-6 Ethyl Acetate ug/m3 34.9 SG-1S 100-41-4 Ethylbenzene ug/m3 11.3 SG-1S 109-99-9 ~Tetrahydrofuran ug/m3 6.26 SG-1S 142-82-5 Heptane, N-ug/m3 2.06 SG-1S 110-54-3 Hexane, N-ug/m3 0.761 SG-1S 591-78-6 Hexanone, 2-ug/m3 3.92 SG-1S 67-63-0 Isopropanol ug/m3 8.9 SG-1S 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 17.6 SG-1S 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 4.66 SG-1S 91-20-3 ~Naphthalene ug/m3 3.65 SG-1S 115-07-1 Propylene ug/m3 7.46 SG-1S 100-42-5 Styrene ug/m3 26.7 SG-1S 127-18-4 Tetrachloroethylene ug/m3 88.1 SG-1S 108-88-3 Toluene ug/m3 1.64 SG-1S 79-01-6 Trichloroethylene ug/m3 3.55 SG-1S 75-69-4 Trichlorofluoromethane ug/m3 146 SG-1S 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 69.2 SG-1S 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 212 SG-1S 1330-20-7 Xylenes ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Maximum detected concentrations in soil gas points at the Site North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-1S Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 6.0E-06 2.2E-01 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 5.9E-07 2.1E-02 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-1S CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 23.6 0.708 -6.5E+03 2.2E-05 71-43-2 Benzene 4.28 0.1284 3.6E-01 6.3E+00 3.6E-07 4.1E-03 67-66-3 Chloroform 18.6 0.558 1.2E-01 2.0E+01 4.6E-06 5.5E-03 100-41-4 Ethylbenzene 34.9 1.047 1.1E+00 2.1E+02 9.3E-07 1.0E-03 109-99-9 ~Tetrahydrofuran 11.3 0.339 -4.2E+02 1.6E-04 142-82-5 Heptane, N-6.26 0.1878 -8.3E+01 4.5E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)8.9 0.267 -1.0E+03 5.1E-05 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)17.6 0.528 -6.3E+02 1.7E-04 100-42-5 Styrene 7.46 0.2238 -2.1E+02 2.1E-04 127-18-4 Tetrachloroethylene 26.7 0.801 1.1E+01 8.3E+00 7.4E-08 1.9E-02 108-88-3 Toluene 88.1 2.643 -1.0E+03 5.1E-04 79-01-6 Trichloroethylene 1.64 0.0492 4.8E-01 4.2E-01 1.0E-07 2.4E-02 75-69-4 Trichlorofluoromethane 3.55 0.1065 -- 95-63-6 Trimethylbenzene, 1,2,4-146 4.38 -1.3E+01 7.0E-02 108-67-8 Trimethylbenzene, 1,3,5-69.2 2.076 -1.3E+01 3.3E-02 1330-20-7 Xylenes 212 6.36 -2.1E+01 6.1E-02 Cumulative:6.0E-06 2.2E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-1S CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 23.6 0.236 -2.7E+04 1.7E-06 71-43-2 Benzene 4.28 0.0428 1.6E+00 2.6E+01 2.7E-08 3.3E-04 67-66-3 Chloroform 18.6 0.186 5.3E-01 8.6E+01 3.5E-07 4.3E-04 100-41-4 Ethylbenzene 34.9 0.349 4.9E+00 8.8E+02 7.1E-08 8.0E-05 109-99-9 ~Tetrahydrofuran 11.3 0.113 -1.8E+03 1.3E-05 142-82-5 Heptane, N-6.26 0.0626 -3.5E+02 3.6E-05 110-54-3 Hexane, N-2.06 0.0206 -6.1E+02 6.7E-0667-63-0 Isopropanol 3.92 0.0392 -1.8E+02 4.5E-05 78-93-3 Methyl Ethyl Ketone (2-Butanone)8.9 0.089 -4.4E+03 4.1E-06 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)17.6 0.176 -2.6E+03 1.3E-05 91-20-3 ~Naphthalene 4.66 0.0466 3.6E-01 2.6E+00 1.3E-07 3.5E-03115-07-1 Propylene 3.65 0.0365 -2.6E+03 2.8E-06100-42-5 Styrene 7.46 0.0746 -8.8E+02 1.7E-05127-18-4 Tetrachloroethylene 26.7 0.267 4.7E+01 3.5E+01 5.7E-09 1.5E-03 108-88-3 Toluene 88.1 0.881 -4.4E+03 4.0E-05 79-01-6 Trichloroethylene 1.64 0.0164 3.0E+00 1.8E+00 5.5E-09 1.9E-03 75-69-4 Trichlorofluoromethane 3.55 0.0355 -- 95-63-6 Trimethylbenzene, 1,2,4-146 1.46 -5.3E+01 5.6E-03 108-67-8 Trimethylbenzene, 1,3,5-69.2 0.692 -5.3E+01 2.6E-031330-20-7 Xylenes 212 2.12 -8.8E+01 4.8E-03 Cumulative:5.9E-07 2.1E-02 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Prepared By:Hart & Hickman, PC 3921 Sunset Ridge Road, Suite 301, Raleigh, North Carolina 27529 SG-1D North Carolina Department of Environmental Quality Risk Calculator Cameron Village Condominiums 1801 Cameron Street, Raleigh, Wake County, North Carolina Brownfields Program BPN 24017-20-092 July 2020 May 2020 EPA RSL Table North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-1D Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-1D Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 21 SG-1D 67-64-1 Acetone ug/m3 3.6 SG-1D 71-43-2 Benzene ug/m3 17 SG-1D 67-66-3 Chloroform ug/m3 53 SG-1D 100-41-4 Ethylbenzene ug/m3 5.1 SG-1D 109-99-9 ~Tetrahydrofuran J ug/m3 8.7 SG-1D 142-82-5 Heptane, N-ug/m3 7.9 SG-1D 78-93-3 Methyl Ethyl Ketone (2-Butanone)J ug/m3 20 SG-1D 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 6.7 SG-1D 100-42-5 Styrene ug/m3 46 SG-1D 127-18-4 Tetrachloroethylene ug/m3 120 SG-1D 108-88-3 Toluene ug/m3 2 SG-1D 79-01-6 Trichloroethylene ug/m3 3.4 SG-1D 75-69-4 Trichlorofluoromethane J ug/m3 230 SG-1D 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 100 SG-1D 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 351 SG-1D 1330-20-7 Xylenes ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Maximum detected concentrations in soil gas points at the Site North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-1D Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 6.1E-06 3.3E-01 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 4.7E-07 2.6E-02 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-1D CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 21 0.63 -6.5E+03 1.9E-05 71-43-2 Benzene 3.6 0.108 3.6E-01 6.3E+00 3.0E-07 3.5E-03 67-66-3 Chloroform 17 0.51 1.2E-01 2.0E+01 4.2E-06 5.0E-03 100-41-4 Ethylbenzene 53 1.59 1.1E+00 2.1E+02 1.4E-06 1.5E-03 109-99-9 ~Tetrahydrofuran 5.1 0.153 -4.2E+02 7.3E-05 142-82-5 Heptane, N-8.7 0.261 -8.3E+01 6.3E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)7.9 0.237 -1.0E+03 4.5E-05 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)20 0.6 -6.3E+02 1.9E-04 100-42-5 Styrene 6.7 0.201 -2.1E+02 1.9E-04 127-18-4 Tetrachloroethylene 46 1.38 1.1E+01 8.3E+00 1.3E-07 3.3E-02 108-88-3 Toluene 120 3.6 -1.0E+03 6.9E-04 79-01-6 Trichloroethylene 2 0.06 4.8E-01 4.2E-01 1.3E-07 2.9E-02 75-69-4 Trichlorofluoromethane 3.4 0.102 -- 95-63-6 Trimethylbenzene, 1,2,4-230 6.9 -1.3E+01 1.1E-01 108-67-8 Trimethylbenzene, 1,3,5-100 3 -1.3E+01 4.8E-02 1330-20-7 Xylenes 351 10.53 -2.1E+01 1.0E-01 Cumulative:6.1E-06 3.3E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-1D CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 21 0.21 -2.7E+04 1.5E-06 71-43-2 Benzene 3.6 0.036 1.6E+00 2.6E+01 2.3E-08 2.7E-04 67-66-3 Chloroform 17 0.17 5.3E-01 8.6E+01 3.2E-07 4.0E-04 100-41-4 Ethylbenzene 53 0.53 4.9E+00 8.8E+02 1.1E-07 1.2E-04 109-99-9 ~Tetrahydrofuran 5.1 0.051 -1.8E+03 5.8E-06 142-82-5 Heptane, N-8.7 0.087 -3.5E+02 5.0E-05 110-54-3 Hexane, N--6.1E+0267-63-0 Isopropanol -1.8E+02 78-93-3 Methyl Ethyl Ketone (2-Butanone)7.9 0.079 -4.4E+03 3.6E-06 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)20 0.2 -2.6E+03 1.5E-05 91-20-3 ~Naphthalene 3.6E-01 2.6E+00115-07-1 Propylene -2.6E+03100-42-5 Styrene 6.7 0.067 -8.8E+02 1.5E-05127-18-4 Tetrachloroethylene 46 0.46 4.7E+01 3.5E+01 9.8E-09 2.6E-03 108-88-3 Toluene 120 1.2 -4.4E+03 5.5E-05 79-01-6 Trichloroethylene 2 0.02 3.0E+00 1.8E+00 6.7E-09 2.3E-03 75-69-4 Trichlorofluoromethane 3.4 0.034 -- 95-63-6 Trimethylbenzene, 1,2,4-230 2.3 -5.3E+01 8.8E-03 108-67-8 Trimethylbenzene, 1,3,5-100 1 -5.3E+01 3.8E-031330-20-7 Xylenes 351 3.51 -8.8E+01 8.0E-03 Cumulative:4.7E-07 2.6E-02 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SG-2 North Carolina Department of Environmental Quality Risk Calculator Cameron Village Condominiums 1801 Cameron Street, Raleigh, Wake County, North Carolina Brownfields Program BPN 24017-20-092 July 2020 May 2020 EPA RSL Table Prepared By:Hart & Hickman, PC 3921 Sunset Ridge Road, Suite 301, Raleigh, North Carolina 27529 North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-2 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-2 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 19 SG-2 67-64-1 Acetone ug/m3 3.3 SG-2 71-43-2 Benzene ug/m3 27 SG-2 67-66-3 Chloroform ug/m3 19 SG-2 100-41-4 Ethylbenzene ug/m3 17 SG-2 142-82-5 Heptane, N-ug/m3 4.9 SG-2 78-93-3 Methyl Ethyl Ketone (2-Butanone)J ug/m3 8.4 SG-2 115-07-1 Propylene J ug/m3 380 SG-2 127-18-4 Tetrachloroethylene ug/m3 52 SG-2 108-88-3 Toluene ug/m3 1.4 SG-2 79-01-6 Trichloroethylene ug/m3 2 SG-2 75-69-4 Trichlorofluoromethane J ug/m3 82 SG-2 1330-20-7 Xylenes ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Maximum detected concentrations in soil gas points at the Site North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-2 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 8.6E-06 3.3E-01 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 6.5E-07 2.6E-02 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-2 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 19 0.57 -6.5E+03 1.8E-05 71-43-2 Benzene 3.3 0.099 3.6E-01 6.3E+00 2.8E-07 3.2E-03 67-66-3 Chloroform 27 0.81 1.2E-01 2.0E+01 6.6E-06 7.9E-03 100-41-4 Ethylbenzene 19 0.57 1.1E+00 2.1E+02 5.1E-07 5.5E-04 142-82-5 Heptane, N-17 0.51 -8.3E+01 1.2E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone)4.9 0.147 -1.0E+03 2.8E-05 115-07-1 Propylene 8.4 0.252 -6.3E+02 8.1E-05 127-18-4 Tetrachloroethylene 380 11.4 1.1E+01 8.3E+00 1.1E-06 2.7E-01 108-88-3 Toluene 52 1.56 -1.0E+03 3.0E-04 79-01-6 Trichloroethylene 1.4 0.042 4.8E-01 4.2E-01 8.8E-08 2.0E-02 75-69-4 Trichlorofluoromethane 2 0.06 -- 1330-20-7 Xylenes 82 2.46 -2.1E+01 2.4E-02 Cumulative:8.6E-06 3.3E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-2 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 19 0.19 -2.7E+04 1.4E-06 71-43-2 Benzene 3.3 0.033 1.6E+00 2.6E+01 2.1E-08 2.5E-04 67-66-3 Chloroform 27 0.27 5.3E-01 8.6E+01 5.1E-07 6.3E-04 100-41-4 Ethylbenzene 19 0.19 4.9E+00 8.8E+02 3.9E-08 4.3E-05 109-99-9 ~Tetrahydrofuran -1.8E+03 142-82-5 Heptane, N-17 0.17 -3.5E+02 9.7E-05 110-54-3 Hexane, N--6.1E+0267-63-0 Isopropanol -1.8E+02 78-93-3 Methyl Ethyl Ketone (2-Butanone)4.9 0.049 -4.4E+03 2.2E-06 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)-2.6E+03 91-20-3 ~Naphthalene 3.6E-01 2.6E+00115-07-1 Propylene 8.4 0.084 -2.6E+03 6.4E-06100-42-5 Styrene -8.8E+02127-18-4 Tetrachloroethylene 380 3.8 4.7E+01 3.5E+01 8.1E-08 2.2E-02 108-88-3 Toluene 52 0.52 -4.4E+03 2.4E-05 79-01-6 Trichloroethylene 1.4 0.014 3.0E+00 1.8E+00 4.7E-09 1.6E-03 75-69-4 Trichlorofluoromethane 2 0.02 -- 95-63-6 Trimethylbenzene, 1,2,4--5.3E+01 108-67-8 Trimethylbenzene, 1,3,5--5.3E+011330-20-7 Xylenes 82 0.82 -8.8E+01 1.9E-03 Cumulative:6.5E-07 2.6E-02 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SG-3 North Carolina Department of Environmental Quality Risk Calculator Cameron Village Condominiums 1801 Cameron Street, Raleigh, Wake County, North Carolina Brownfields Program BPN 24017-20-092 July 2020 May 2020 EPA RSL Table Prepared By:Hart & Hickman, PC 3921 Sunset Ridge Road, Suite 301, Raleigh, North Carolina 27529 North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-3 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-3 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 130 SG-3 67-64-1 Acetone ug/m3 1.5 SG-3 71-43-2 Benzene ug/m3 40 SG-3 67-66-3 Chloroform ug/m3 16 SG-3 100-41-4 Ethylbenzene ug/m3 18 SG-3 109-99-9 ~Tetrahydrofuran J ug/m3 4.4 SG-3 142-82-5 Heptane, N-ug/m3 5.7 SG-3 67-63-0 Isopropanol J ug/m3 22 SG-3 78-93-3 Methyl Ethyl Ketone (2-Butanone)J ug/m3 20 SG-3 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 370 SG-3 127-18-4 Tetrachloroethylene ug/m3 34 SG-3 108-88-3 Toluene ug/m3 1.5 SG-3 79-01-6 Trichloroethylene ug/m3 2.4 SG-3 75-69-4 Trichlorofluoromethane J ug/m3 78 SG-3 1330-20-7 Xylenes ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Maximum detected concentrations in soil gas points at the Site North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-3 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.2E-05 3.2E-01 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 8.8E-07 2.6E-02 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-3 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 130 3.9 -6.5E+03 1.2E-04 71-43-2 Benzene 1.5 0.045 3.6E-01 6.3E+00 1.3E-07 1.4E-03 67-66-3 Chloroform 40 1.2 1.2E-01 2.0E+01 9.8E-06 1.2E-02 100-41-4 Ethylbenzene 16 0.48 1.1E+00 2.1E+02 4.3E-07 4.6E-04 142-82-5 Heptane, N-4.4 0.132 -8.3E+01 3.2E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)22 0.66 -1.0E+03 1.3E-04 115-07-1 Propylene -6.3E+02 127-18-4 Tetrachloroethylene 370 11.1 1.1E+01 8.3E+00 1.0E-06 2.7E-01108-88-3 Toluene 34 1.02 -1.0E+03 2.0E-04 79-01-6 Trichloroethylene 1.5 0.045 4.8E-01 4.2E-01 9.4E-08 2.2E-02 75-69-4 Trichlorofluoromethane 2.4 0.072 -- 1330-20-7 Xylenes 78 2.34 -2.1E+01 2.2E-02 Cumulative:1.2E-05 3.2E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-3 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 130 1.3 -2.7E+04 9.6E-06 71-43-2 Benzene 1.5 0.015 1.6E+00 2.6E+01 9.5E-09 1.1E-0467-66-3 Chloroform 40 0.4 5.3E-01 8.6E+01 7.5E-07 9.3E-04100-41-4 Ethylbenzene 16 0.16 4.9E+00 8.8E+02 3.3E-08 3.7E-05109-99-9 ~Tetrahydrofuran 18 0.18 -1.8E+03 2.1E-05 142-82-5 Heptane, N-4.4 0.044 -3.5E+02 2.5E-05 110-54-3 Hexane, N--6.1E+02 67-63-0 Isopropanol 5.7 0.057 -1.8E+02 6.5E-05 78-93-3 Methyl Ethyl Ketone (2-Butanone)22 0.22 -4.4E+03 1.0E-05 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)20 0.2 -2.6E+03 1.5E-05 91-20-3 ~Naphthalene 3.6E-01 2.6E+00 115-07-1 Propylene -2.6E+03 100-42-5 Styrene -8.8E+02 127-18-4 Tetrachloroethylene 370 3.7 4.7E+01 3.5E+01 7.8E-08 2.1E-02 108-88-3 Toluene 34 0.34 -4.4E+03 1.6E-0579-01-6 Trichloroethylene 1.5 0.015 3.0E+00 1.8E+00 5.0E-09 1.7E-0375-69-4 Trichlorofluoromethane 2.4 0.024 --95-63-6 Trimethylbenzene, 1,2,4--5.3E+01 108-67-8 Trimethylbenzene, 1,3,5--5.3E+01 1330-20-7 Xylenes 78 0.78 -8.8E+01 1.8E-03 Cumulative:8.8E-07 2.6E-02 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SG-4 North Carolina Department of Environmental Quality Risk Calculator Cameron Village Condominiums 1801 Cameron Street, Raleigh, Wake County, North Carolina Brownfields Program BPN 24017-20-092 July 2020 May 2020 EPA RSL Table Prepared By:Hart & Hickman, PC 3921 Sunset Ridge Road, Suite 301, Raleigh, North Carolina 27529 North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-4 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-4 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 45 SG-4 67-64-1 Acetone ug/m3 2.6 SG-4 71-43-2 Benzene ug/m3 3.1 SG-4 67-66-3 Chloroform ug/m3 10 SG-4 100-41-4 Ethylbenzene ug/m3 4 SG-4 109-99-9 ~Tetrahydrofuran J ug/m3 20 SG-4 142-82-5 Heptane, N-ug/m3 14 SG-4 67-63-0 Isopropanol J ug/m3 7.8 SG-4 78-93-3 Methyl Ethyl Ketone (2-Butanone)J ug/m3 5.1 SG-4 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 3.5 SG-4 91-20-3 ~Naphthalene ug/m3 21 SG-4 115-07-1 Propylene ug/m3 5.4 SG-4 127-18-4 Tetrachloroethylene ug/m3 39 SG-4 108-88-3 Toluene ug/m3 0.8 SG-4 79-01-6 Trichloroethylene J ug/m3 43 SG-4 1330-20-7 Xylenes ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Maximum detected concentrations in soil gas points at the Site North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-4 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.3E-06 3.3E-02 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 2.0E-07 5.5E-03 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-4 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 45 1.35 -6.5E+03 4.2E-05 71-43-2 Benzene 2.6 0.078 3.6E-01 6.3E+00 2.2E-07 2.5E-03 67-66-3 Chloroform 3.1 0.093 1.2E-01 2.0E+01 7.6E-07 9.1E-04 100-41-4 Ethylbenzene 10 0.3 1.1E+00 2.1E+02 2.7E-07 2.9E-04 142-82-5 Heptane, N-20 0.6 -8.3E+01 1.4E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone)7.8 0.234 -1.0E+03 4.5E-05 115-07-1 Propylene 21 0.63 -6.3E+02 2.0E-04 127-18-4 Tetrachloroethylene 5.4 0.162 1.1E+01 8.3E+00 1.5E-08 3.9E-03 108-88-3 Toluene 39 1.17 -1.0E+03 2.2E-04 79-01-6 Trichloroethylene 0.8 0.024 4.8E-01 4.2E-01 5.0E-08 1.2E-02 75-69-4 Trichlorofluoromethane -- 1330-20-7 Xylenes 43 1.29 -2.1E+01 1.2E-02 Cumulative:1.3E-06 3.3E-02 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-4 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 45 0.45 -2.7E+04 3.3E-06 71-43-2 Benzene 2.6 0.026 1.6E+00 2.6E+01 1.7E-08 2.0E-04 67-66-3 Chloroform 3.1 0.031 5.3E-01 8.6E+01 5.8E-08 7.2E-05 100-41-4 Ethylbenzene 10 0.1 4.9E+00 8.8E+02 2.0E-08 2.3E-05 109-99-9 ~Tetrahydrofuran 4 0.04 -1.8E+03 4.6E-06 142-82-5 Heptane, N-20 0.2 -3.5E+02 1.1E-04 110-54-3 Hexane, N--6.1E+0267-63-0 Isopropanol 14 0.14 -1.8E+02 1.6E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)7.8 0.078 -4.4E+03 3.6E-06 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)5.1 0.051 -2.6E+03 3.9E-06 91-20-3 ~Naphthalene 3.5 0.035 3.6E-01 2.6E+00 9.7E-08 2.7E-03115-07-1 Propylene 21 0.21 -2.6E+03 1.6E-05100-42-5 Styrene -8.8E+02127-18-4 Tetrachloroethylene 5.4 0.054 4.7E+01 3.5E+01 1.1E-09 3.1E-04 108-88-3 Toluene 39 0.39 -4.4E+03 1.8E-05 79-01-6 Trichloroethylene 0.8 0.008 3.0E+00 1.8E+00 2.7E-09 9.1E-04 75-69-4 Trichlorofluoromethane -- 95-63-6 Trimethylbenzene, 1,2,4--5.3E+01 108-67-8 Trimethylbenzene, 1,3,5--5.3E+011330-20-7 Xylenes 43 0.43 -8.8E+01 9.8E-04 Cumulative:2.0E-07 5.5E-03 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SG-5 North Carolina Department of Environmental Quality Risk Calculator Cameron Village Condominiums 1801 Cameron Street, Raleigh, Wake County, North Carolina Brownfields Program BPN 24017-20-092 July 2020 May 2020 EPA RSL Table Prepared By:Hart & Hickman, PC 3921 Sunset Ridge Road, Suite 301, Raleigh, North Carolina 27529 North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-5 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-5 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 3.6 SG-5 71-43-2 Benzene ug/m3 15 SG-5 100-41-4 Ethylbenzene ug/m3 7.2 SG-5 109-99-9 ~Tetrahydrofuran ug/m3 12 SG-5 142-82-5 Heptane, N-ug/m3 10 SG-5 110-54-3 Hexane, N-J ug/m3 9 SG-5 78-93-3 Methyl Ethyl Ketone (2-Butanone)J ug/m3 9.8 SG-5 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 2.9 SG-5 91-20-3 ~Naphthalene ug/m3 9.6 SG-5 127-18-4 Tetrachloroethylene ug/m3 39 SG-5 108-88-3 Toluene ug/m3 71 SG-5 1330-20-7 Xylenes ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Maximum detected concentrations in soil gas points at the Site North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-5 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 7.3E-07 3.2E-02 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.4E-07 4.8E-03 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-5 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone -6.5E+03 71-43-2 Benzene 3.6 0.108 3.6E-01 6.3E+00 3.0E-07 3.5E-03 67-66-3 Chloroform 1.2E-01 2.0E+01 100-41-4 Ethylbenzene 15 0.45 1.1E+00 2.1E+02 4.0E-07 4.3E-04 142-82-5 Heptane, N-12 0.36 -8.3E+01 8.6E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)9 0.27 -1.0E+03 5.2E-05 115-07-1 Propylene -6.3E+02 127-18-4 Tetrachloroethylene 9.6 0.288 1.1E+01 8.3E+00 2.7E-08 6.9E-03 108-88-3 Toluene 39 1.17 -1.0E+03 2.2E-04 79-01-6 Trichloroethylene 4.8E-01 4.2E-01 75-69-4 Trichlorofluoromethane -- 1330-20-7 Xylenes 71 2.13 -2.1E+01 2.0E-02 Cumulative:7.3E-07 3.2E-02 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-5 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone -2.7E+04 71-43-2 Benzene 3.6 0.036 1.6E+00 2.6E+01 2.3E-08 2.7E-0467-66-3 Chloroform 5.3E-01 8.6E+01100-41-4 Ethylbenzene 15 0.15 4.9E+00 8.8E+02 3.1E-08 3.4E-05109-99-9 ~Tetrahydrofuran 7.2 0.072 -1.8E+03 8.2E-06 142-82-5 Heptane, N-12 0.12 -3.5E+02 6.8E-05 110-54-3 Hexane, N-10 0.1 -6.1E+02 3.3E-05 67-63-0 Isopropanol -1.8E+02 78-93-3 Methyl Ethyl Ketone (2-Butanone)9 0.09 -4.4E+03 4.1E-06 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)9.8 0.098 -2.6E+03 7.5E-06 91-20-3 ~Naphthalene 2.9 0.029 3.6E-01 2.6E+00 8.0E-08 2.2E-03 115-07-1 Propylene -2.6E+03 100-42-5 Styrene -8.8E+02 127-18-4 Tetrachloroethylene 9.6 0.096 4.7E+01 3.5E+01 2.0E-09 5.5E-04 108-88-3 Toluene 39 0.39 -4.4E+03 1.8E-0579-01-6 Trichloroethylene 3.0E+00 1.8E+0075-69-4 Trichlorofluoromethane --95-63-6 Trimethylbenzene, 1,2,4--5.3E+01 108-67-8 Trimethylbenzene, 1,3,5--5.3E+01 1330-20-7 Xylenes 71 0.71 -8.8E+01 1.6E-03 Cumulative:1.4E-07 4.8E-03 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SG-6 North Carolina Department of Environmental Quality Risk Calculator Cameron Village Condominiums 1801 Cameron Street, Raleigh, Wake County, North Carolina Brownfields Program BPN 24017-20-092 July 2020 May 2020 EPA RSL Table Prepared By:Hart & Hickman, PC 3921 Sunset Ridge Road, Suite 301, Raleigh, North Carolina 27529 North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-6 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-6 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 170 SG-6 67-64-1 Acetone ug/m3 4.9 SG-6 71-43-2 Benzene ug/m3 17 SG-6 100-41-4 Ethylbenzene ug/m3 24 SG-6 109-99-9 ~Tetrahydrofuran ug/m3 11 SG-6 142-82-5 Heptane, N-ug/m3 27 SG-6 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 16 SG-6 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 12 SG-6 127-18-4 Tetrachloroethylene ug/m3 52 SG-6 108-88-3 Toluene ug/m3 74 SG-6 1330-20-7 Xylenes ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Maximum detected concentrations in soil gas points at the Site North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-6 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 9.0E-07 3.7E-02 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 6.8E-08 2.9E-03 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-6 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 170 5.1 -6.5E+03 1.6E-04 71-43-2 Benzene 4.9 0.147 3.6E-01 6.3E+00 4.1E-07 4.7E-03 67-66-3 Chloroform 1.2E-01 2.0E+01 100-41-4 Ethylbenzene 17 0.51 1.1E+00 2.1E+02 4.5E-07 4.9E-04 142-82-5 Heptane, N-11 0.33 -8.3E+01 7.9E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)27 0.81 -1.0E+03 1.6E-04 115-07-1 Propylene -6.3E+02 127-18-4 Tetrachloroethylene 12 0.36 1.1E+01 8.3E+00 3.3E-08 8.6E-03 108-88-3 Toluene 52 1.56 -1.0E+03 3.0E-04 79-01-6 Trichloroethylene 4.8E-01 4.2E-01 75-69-4 Trichlorofluoromethane -- 1330-20-7 Xylenes 74 2.22 -2.1E+01 2.1E-02 Cumulative:9.0E-07 3.7E-02 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: SG-6 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 170 1.7 -2.7E+04 1.3E-05 71-43-2 Benzene 4.9 0.049 1.6E+00 2.6E+01 3.1E-08 3.7E-04 67-66-3 Chloroform 5.3E-01 8.6E+01 100-41-4 Ethylbenzene 17 0.17 4.9E+00 8.8E+02 3.5E-08 3.9E-05 109-99-9 ~Tetrahydrofuran 24 0.24 -1.8E+03 2.7E-05 142-82-5 Heptane, N-11 0.11 -3.5E+02 6.3E-05 110-54-3 Hexane, N--6.1E+0267-63-0 Isopropanol -1.8E+02 78-93-3 Methyl Ethyl Ketone (2-Butanone)27 0.27 -4.4E+03 1.2E-05 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)16 0.16 -2.6E+03 1.2E-05 91-20-3 ~Naphthalene 3.6E-01 2.6E+00115-07-1 Propylene -2.6E+03100-42-5 Styrene -8.8E+02127-18-4 Tetrachloroethylene 12 0.12 4.7E+01 3.5E+01 2.5E-09 6.8E-04 108-88-3 Toluene 52 0.52 -4.4E+03 2.4E-05 79-01-6 Trichloroethylene 3.0E+00 1.8E+00 75-69-4 Trichlorofluoromethane -- 95-63-6 Trimethylbenzene, 1,2,4--5.3E+01 108-67-8 Trimethylbenzene, 1,3,5--5.3E+011330-20-7 Xylenes 74 0.74 -8.8E+01 1.7E-03 Cumulative:6.8E-08 2.9E-03 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Worst Case Scenario North Carolina Department of Environmental Quality Risk Calculator Cameron Village Condominiums 1801 Cameron Street, Raleigh, Wake County, North Carolina Brownfields Program BPN 24017-20-092 July 2020 May 2020 EPA RSL Table Prepared By:Hart & Hickman, PC 3921 Sunset Ridge Road, Suite 301, Raleigh, North Carolina 27529 North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: Worst Case Scenario Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: Worst Case Scenario Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 170 SG-6 67-64-1 Acetone ug/m3 4.9 SG-6 71-43-2 Benzene ug/m3 0.306 SG-1S 106-99-0 Butadiene, 1,3-J ug/m3 1.11 SG-1S 75-15-0 Carbon Disulfide ug/m3 0.544 SG-1S 108-90-7 Chlorobenzene ug/m3 40 SG-3 67-66-3 Chloroform ug/m3 0.218 SG-1S 74-87-3 Chloromethane ug/m3 5.79 SG-1S 110-82-7 Cyclohexane ug/m3 2 SG-1S 75-71-8 Dichlorodifluoromethane ug/m3 0.36 SG-1S 123-91-1 Dioxane, 1,4-ug/m3 1.98 SG-1S 141-78-6 Ethyl Acetate ug/m3 53 Dup-1 100-41-4 Ethylbenzene ug/m3 24 SG-6 109-99-9 ~Tetrahydrofuran ug/m3 20 SG-4 142-82-5 Heptane, N-ug/m3 10 SG-5 110-54-3 Hexane, N-J ug/m3 0.761 SG-1S 591-78-6 Hexanone, 2-ug/m3 14 SG-4 67-63-0 Isopropanol J ug/m3 27 SG-6 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 20 SG-3, Dup-1 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 0.645 SG-1S 75-09-2 Methylene Chloride ug/m3 4.66 SG-1S 91-20-3 ~Naphthalene ug/m3 21 SG-4 115-07-1 Propylene ug/m3 7.46 SG-1S 100-42-5 Styrene ug/m3 380 SG-2 127-18-4 Tetrachloroethylene ug/m3 120 Dup-1 108-88-3 Toluene ug/m3 2 Dup-1 79-01-6 Trichloroethylene ug/m3 3.55 SG-1S 75-69-4 Trichlorofluoromethane ug/m3 230 Dup-1 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 100 Dup-1 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 351 Dup-1 1330-20-7 Xylenes ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Maximum detected concentrations in soil gas points at the Site. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: Worst Case Scenario Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.5E-05 6.4E-01 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.1E-06 5.1E-02 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: Worst Case Scenario CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 170 5.1 -6.5E+03 1.6E-04 71-43-2 Benzene 4.9 0.147 3.6E-01 6.3E+00 4.1E-07 4.7E-03 106-99-0 Butadiene, 1,3-0.306 0.00918 9.4E-02 4.2E-01 9.8E-08 4.4E-03 75-15-0 Carbon Disulfide 1.11 0.0333 -1.5E+02 4.6E-05 108-90-7 Chlorobenzene 0.544 0.01632 -1.0E+01 3.1E-04 67-66-3 Chloroform 40 1.2 1.2E-01 2.0E+01 9.8E-06 1.2E-02 74-87-3 Chloromethane 0.218 0.00654 -1.9E+01 7.0E-05 110-82-7 Cyclohexane 5.79 0.1737 -1.3E+03 2.8E-05 75-71-8 Dichlorodifluoromethane 2 0.06 -2.1E+01 5.8E-04 123-91-1 Dioxane, 1,4-0.36 0.0108 5.6E-01 6.3E+00 1.9E-08 3.5E-04 141-78-6 Ethyl Acetate 1.98 0.0594 -1.5E+01 8.1E-04 100-41-4 Ethylbenzene 53 1.59 1.1E+00 2.1E+02 1.4E-06 1.5E-03 109-99-9 ~Tetrahydrofuran 24 0.72 -4.2E+02 3.5E-04 142-82-5 Heptane, N-20 0.6 -8.3E+01 1.4E-03 110-54-3 Hexane, N-10 0.3 -1.5E+02 4.1E-04 591-78-6 Hexanone, 2-0.761 0.02283 -6.3E+00 7.3E-04 67-63-0 Isopropanol 14 0.42 -4.2E+01 2.0E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone)27 0.81 -1.0E+03 1.6E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)20 0.6 -6.3E+02 1.9E-04 75-09-2 Methylene Chloride 0.645 0.01935 1.0E+02 1.3E+02 1.9E-10 3.1E-05 91-20-3 ~Naphthalene 4.66 0.1398 8.3E-02 6.3E-01 1.7E-06 4.5E-02 115-07-1 Propylene 21 0.63 -6.3E+02 2.0E-04 100-42-5 Styrene 7.46 0.2238 -2.1E+02 2.1E-04 127-18-4 Tetrachloroethylene 380 11.4 1.1E+01 8.3E+00 1.1E-06 2.7E-01 108-88-3 Toluene 120 3.6 -1.0E+03 6.9E-04 79-01-6 Trichloroethylene 2 0.06 4.8E-01 4.2E-01 1.3E-07 2.9E-02 75-69-4 Trichlorofluoromethane 3.55 0.1065 -- 95-63-6 Trimethylbenzene, 1,2,4-230 6.9 -1.3E+01 1.1E-01 108-67-8 Trimethylbenzene, 1,3,5-100 3 -1.3E+01 4.8E-02 1330-20-7 Xylenes 351 10.53 -2.1E+01 1.0E-01 Cumulative:1.5E-05 6.4E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: BPN 24017-20-092 Exposure Unit ID: Worst Case Scenario CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 170 1.7 -2.7E+04 1.3E-0571-43-2 Benzene 4.9 0.049 1.6E+00 2.6E+01 3.1E-08 3.7E-04106-99-0 Butadiene, 1,3-0.306 0.00306 4.1E-01 1.8E+00 7.5E-09 3.5E-0475-15-0 Carbon Disulfide 1.11 0.0111 -6.1E+02 3.6E-06108-90-7 Chlorobenzene 0.544 0.00544 -4.4E+01 2.5E-0567-66-3 Chloroform 40 0.4 5.3E-01 8.6E+01 7.5E-07 9.3E-0474-87-3 Chloromethane 0.218 0.00218 -7.9E+01 5.5E-06110-82-7 Cyclohexane 5.79 0.0579 -5.3E+03 2.2E-0675-71-8 Dichlorodifluoromethane 2 0.02 -8.8E+01 4.6E-05123-91-1 Dioxane, 1,4-0.36 0.0036 2.5E+00 2.6E+01 1.5E-09 2.7E-05141-78-6 Ethyl Acetate 1.98 0.0198 -6.1E+01 6.5E-05100-41-4 Ethylbenzene 53 0.53 4.9E+00 8.8E+02 1.1E-07 1.2E-04109-99-9 ~Tetrahydrofuran 24 0.24 -1.8E+03 2.7E-05 142-82-5 Heptane, N-20 0.2 -3.5E+02 1.1E-04 110-54-3 Hexane, N-10 0.1 -6.1E+02 3.3E-05591-78-6 Hexanone, 2-0.761 0.00761 -2.6E+01 5.8E-0567-63-0 Isopropanol 14 0.14 -1.8E+02 1.6E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)27 0.27 -4.4E+03 1.2E-05 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)20 0.2 -2.6E+03 1.5E-0575-09-2 Methylene Chloride 0.645 0.00645 1.2E+03 5.3E+02 5.3E-12 2.5E-0691-20-3 ~Naphthalene 4.66 0.0466 3.6E-01 2.6E+00 1.3E-07 3.5E-03115-07-1 Propylene 21 0.21 -2.6E+03 1.6E-05100-42-5 Styrene 7.46 0.0746 -8.8E+02 1.7E-05127-18-4 Tetrachloroethylene 380 3.8 4.7E+01 3.5E+01 8.1E-08 2.2E-02108-88-3 Toluene 120 1.2 -4.4E+03 5.5E-0579-01-6 Trichloroethylene 2 0.02 3.0E+00 1.8E+00 6.7E-09 2.3E-0375-69-4 Trichlorofluoromethane 3.55 0.0355 --95-63-6 Trimethylbenzene, 1,2,4-230 2.3 -5.3E+01 8.8E-03108-67-8 Trimethylbenzene, 1,3,5-100 1 -5.3E+01 3.8E-031330-20-7 Xylenes 351 3.51 -8.8E+01 8.0E-03 Cumulative:1.1E-06 5.1E-02 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator