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HomeMy WebLinkAbout24003_N. Davidson II_VIMS Install_Office Space_20230803 VIMS Installation Report Office Space North Davidson II Brownfields Property Brownfields Project No. 24003-20-060 2315 N. Davidson Street and 421 E. 26th Street Charlotte, North Carolina H&H Job No. PAM-003 August 3, 2023 #C-1269 Engineering #C-245 Geology i https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx VIMS Installation Report North Davidson II Brownfields Property Office Space2315 North Davidson Street Charlotte, North Carolina Brownfields Project No. 24003-20-060 H&H Job No. PAM-003 Table of Contents 1.0 Introduction and Background ...............................................................................................1 2.0 VIMS Installation and Influence Testing .............................................................................5 2.1 VIMS Installation Inspections ..............................................................................................5 2.2 VIMS Influence Testing .......................................................................................................7 3.0 Pre-Occupancy System Effectiveness Testing ......................................................................9 3.1 Sub-Slab Soil Gas Sampling Methodology ..........................................................................9 3.3 Indoor Air Sampling Methodology .....................................................................................10 3.3 Sub-Slab Vapor and Indoor Air Sampling Results .............................................................12 3.3.1 Sub-Slab Vapor Sampling Results .............................................................................. 12 3.3.2 Indoor Air Sampling Results ...................................................................................... 12 3.4 Risk Evaluation ...................................................................................................................13 4.0 Summary and Conclusions ..................................................................................................15 5.0 System Monitoring Activities ................................................................................................16 Figures Figure 1 – Site Location Map Figure 2 – Site Layout Map Tables Table 1 – Summary of Analytical Sampling Data and Risk Calculations ii https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx Appendices Attachment A Excerpts from Previous Assessment Activities Attachment B VIMS Product Specifications Sheets Attachment C VIMS As-Built Drawings – 2315 N. Davidson (Office Space) Attachment D Photographic Log Attachment E Field Sampling Forms and Documents Attachment F Site-Specific Indoor Air Sampling VOC List and Laboratory Analytical Reports Attachment G DEQ Risk Calculator Summary Pages Attachment H Summary of Chemicals in Building Materials 1 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx VIMS Installation Report North Davidson II Brownfields Property Office Space 2315 North Davidson Street Charlotte, North Carolina Brownfields Project No. 24003-20-060 H&H Job No. PAM-003 1.0 Introduction and Background On behalf of Mill District Partners LLC, Hart & Hickman, PC (H&H) has prepared this report to document vapor intrusion mitigation system (VIMS) installation inspections and efficacy testing activities completed at the eastern portion of the 2315 N. Davidson Street building located at the North Davidson II Brownfields property [North Carolina Department of Environmental Quality (DEQ) Brownfields Project No. 24003-20-060]. The property address is listed as 2315 N. Davidson Street and 421 E. 26th Street in Charlotte, Mecklenburg County, North Carolina (Site or subject Site). A Site location map is provided as Figure 1 and the Site layout with the building footprints are depicted on Figure 2. The Site consists of two parcels of land (Parcel Identification Numbers 08305204 and 08305206) that total approximately 3.8 acres. The southeastern parcel (2315 N. Davidson Street) is developed with an approximate 28,700-square foot (sq ft) commercial building for restaurant and office use, and the northwestern parcel (421 E. 26th Street) is developed with an approximate 13,000-sq ft commercial restaurant building. Redevelopment at the Site includes adaptive re-use of the Site buildings. The building located on the southeastern parcel of the Site (2315 N. Davidson Street) has been retrofitted and occupied by commercial (restaurant style) tenants and is known as the Urban District Market (UDM) Food Hall. Commercial offices (Office Space) will be in the eastern portion of this building upon tenant lease. An active VIMS is currently installed in the UDM Food Hall side of the building which was documented in the VIMS Installation Completion Report – UDM Food Hall, dated February 17, 2023 and DEQ provided compliance approval for this area in a letter dated March 2, 2023. The separate building on the northwestern parcel of the Site (421 E. 26th Street) has been retrofitted as a commercial restaurant and entertainment space that is occupied by Seoul Food Company. For 2 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx the 421 E. 26th Street building, the VIMS installation was documented in the VIMS Installation Completion Report – 421 E. 26th Street Building, dated April 4, 2022, and DEQ provided compliance approval in a letter dated April 25, 2022. This report pertains to the eastern portion of the 2315 N. Davidson building which has been retrofitted to be a future office (commercial) space. For simplicity, this area is referred to as the Office Space in this report. As the Office Space construction and VIMS installation were not completed at the time of the UDM construction completion and because a full demising wall is present between UDM and the Office Space that completely separates the two sides, DEQ approved via email on January 20, 2023, that the VIMS installation for each side of the building could be provided in separate submittals. To address potential environmental concerns in connection with the Site, a Brownfields Agreement between the DEQ and the PD was recorded for the Site on June 9, 2021. Land Use Restriction (LUR) h. included in the Brownfields Agreement generally states that no enclosed building on the property may be occupied until DEQ determines in writing that the building would be protective of users from risks of potential vapor intrusion. Previous vapor intrusion assessment activities indicated the presence of trichloroethylene (TCE) and tetrachlorethylene (PCE) at concentrations above respective DEQ Division of Waste Management (DWM) Vapor Intrusion Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs) and Indoor Air Screening Levels (IASLs) in sub-slab vapor and indoor air samples collected in the 2315 N. Davidson Street building. In accordance with LUR h. in the Brownfields Agreement for the Site, H&H prepared a Vapor Intrusion Mitigation Plan (VIMP) for the Site that included both Site buildings. In an email dated May 7, 2021, the DEQ Brownfields Program provided approval for the VIMP – Revision 2 dated May 6, 2021. The DEQ-approved VIMP includes installation of a VIMS during renovation of the buildings to minimize the potential for vapor intrusion into the buildings using an active sub-slab depressurization system. H&H completed VIMS inspections, VIMS influence testing, and VIMS efficacy testing at the Office Space in the 2315 N. Davidson Street building in accordance with the DEQ-approved 3 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx VIMP. Note, some components of the VIMS, such as the telemetric alarm system, are connected between the UDM Food Hall and office areas of the building. Previous site assessment data is included in Attachment A, the VIMS as-built drawings (Sheets VM-1, VM-1A, VM-2, and VM-3) and product specifications for materials and components used during installation of the VIMS are provided in Attachment B and C, respectively. A summary of the VIMS installation and influence testing activities is provided in Section 2.0. The VIMS efficacy sampling activities and results are detailed in Section 3.0, summary and conclusions based on the installation activities, influence testing, and efficacy sampling are provided in Section 4.0, and future monitoring activities are provided in Section 5.0. 4 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx Engineer’s Certification According to the DWM Vapor Intrusion Guidance: “Risk-based screening is used to identify sites or buildings likely to pose a health concern, to identify buildings that may warrant immediate action, to help focus site-specific investigation activities or to provide support for building mitigation and other risk management options including remediation.” In addition, this VIMP was prepared to satisfy the standard vapor intrusion mitigation provisions anticipated to be included in the Brownfields Agreement. Per the North Carolina Brownfields Property Reuse Act 130A- 310.32, a prospective developer, with the assistance of H&H for this project, is to provide DEQ with “information necessary to demonstrate that as a result of the implementation of the brownfields agreement, the brownfields property will be suitable for the uses specified in the agreement while fully protecting public health and the environment instead of being remediated to unrestricted use standards.” It is in the context of these risk-based concepts that the H&H professional engineer makes the following statement: “The Vapor Intrusion Mitigation System (VIMS) detailed herein is designed to mitigate intrusion of subsurface vapors into the subject building from known Brownfields Property contaminants in a manner that is in accordance with the most recent and applicable guidelines including, but not limited to, DWM Vapor Intrusion Guidance, Interstate Technology & Regulatory Council (ITRC) guidance, and American National Standards Institute (ANSI)/American Association of Radon Scientists and Technologists (AARST) standards. The sealing professional engineer below is satisfied that the design and its installation are fully protective of public health from known Brownfields Property contaminants. [SEAL] Trinh DeSa North Carolina PE (#044470) Hart & Hickman, PC (#C-1269) 5 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx 2.0 VIMS Installation and Influence Testing The Office Space is located on the eastern portion of the 2315 N. Davidson Street building and is separated by a demising wall from the adjacent UDM Food Hall located in the western portion of the building. As indicated above, construction of the UDM portion of the building has been completed and is currently occupied by restaurant tenants. The area of the existing slab in the Office Space is approximately 8,500 sq ft. There is a full demising wall located between UDM and the Office Space that does not contain doors, windows, or other openings between the spaces. In addition, the heating, ventilating, and air conditioning (HVAC) systems for both sides are separate. Therefore, UDM and the Office Space do not exchange air between the spaces and thus the VIMS performance and effectiveness on each side of the demising wall are not expected to affect operations on the opposite side of the wall. The VIMS in the Office Space is an active sub-slab vapor depressurization system with electric fans installed on the roof that discharge collected vapors above the building roofline. A brief description of the installed VIMS components, inspection activities, and testing activities is provided below. 2.1 VIMS Installation Inspections Based upon periodic inspections completed during VIMS installation activities, the VIMS was installed in general accordance with the DEQ-approved VIMP. VIMS details and specifications, and VIMS as-built drawings which depict the VIMS layout and details are included in Attachment C, a photographic log with pictures of the VIMS installation activities are provided in Attachment D, and field sampling logs are included as Attachment E. During installation of the VIMS, H&H conducted VIMS inspections in accordance with the DEQ- approved VIMP from June 2021 to May 2023 including: • inspection of suction points and suction trenches prior to concrete repair/replacement; • inspection of suction points and trenches after installation and concrete had been replaced; 6 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx • inspection of above-grade riser duct piping; • inspection of monitoring points and suction trench clean-outs; • inspection of the electric fans; and • inspection of the vacuum sensors and Sensaphone telemetric monitoring system. The VIMS generally includes installation of suction points and suction trenches connected to 3- inch diameter Schedule 40 (Sch 40) PVC risers that are installed from the slab to the building roof. Pressure-Tech PT-16 electric fans are installed on the discharge end of the riser duct piping. In addition, Senva P4 Series vacuum sensors are installed on the risers adjacent to the fans to monitor vacuum levels in the riser. The vacuum readings are transmitted to the Sensaphone Sentinel to monitor for proper function of the fan or determine if troubleshooting is required due to an inoperable or malfunctioning fan. As indicated in the VIMP, portions of the concrete slab were removed and replaced for the installation of utilities and areas specific to the commercial tenants. For the concrete replacement inside the existing building, approximately four inches of washed #57 stone gravel and either the Stego Industries 15-mil Stego-Wrap Vapor Barrier (Stego-Wrap) or the 15-mil Raven VaporBlock-15 Vapor Barrier, which are both ASTM Class A vapor barriers, were installed using manufacturer specified tapes and mastic prior to installation of the new concrete slab sections. Note, a slight change to the VIMP occurred during construction that included installation of an alternative style monitoring point at some locations. Due to difficulty of the contractor to install and seal the monitoring points with the floor clean-out covers in select areas as depicted in the VIMP, several of the monitoring points were switched to Cox-Colvin Vapor Pin® style monitoring points which are installed through the slab. The Vapor Pin monitoring points are a commonly used and accepted method for monitoring points for existing slabs and thus are an equivalent replacement and type of installed monitoring point are depicted in the as-built drawings. For the Office Space, monitoring points MP-12, MP-13, and MP-15 are installed with Vapor Pins. 7 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx 2.2 VIMS Influence Testing On June 7, 2023 post-installation VIMS influence (pilot) testing was conducted at the Office Space of the building after the concrete slab pours were completed to evaluate system sub-slab communication with the installed electric fans operating. After inspection of the fans to verify proper installation, differential pressure measurements were collected at the vacuum monitoring points within the treatment area being tested using a Dwyer series 475 Mark III digital manometer (capable of measuring to 0.001 inches of water column [in-WC] or 0.25 Pascals [Pa]) to establish baseline conditions prior to turning on the electric fans. Following collection of baseline differential pressure measurements, the electric fans were turned on and differential pressure measurements were collected at each monitoring point and fan after approximately 30-minutes. Permanent monitoring points (denoted by MP nomenclature) are shown on the as-built drawings in Attachment B. A summary of the influence testing results is included in Table E-1 in Attachment E. The influence testing in the office space portion of the building indicated that sub-slab vacuum measurements ranged from 0.075 in-WC to 0.617 in-WC at each monitoring point, with vacuum influence greater than 4 Pa (0.016 in-WC) being maintained throughout the slab with the electric fans operating. The vacuum measurements are notably greater than 0.016 in-WC which indicates sufficient vacuum levels are present below the slab. As a follow-up to the pilot test, an additional round of vacuum readings from the Office Space were collected on August 2, 2023. The vacuums during this event ranged from 0.072 in-WC to 1.025 in-WC, which are similar to the vacuums recorded during the pilot test and are notably above the recommended minimum of 0.016 in-WC. Sensaphone Details As indicated in the VIMP, a Sensaphone Sentinel telemetric monitoring system was installed to provide notifications and an online interface to monitor the vacuum sensor data. The Sensaphone is installed within the central portion of the UDM Food Hall (see Sheet VM-1) and is located within a lockable box enclosure. The telemetric monitoring system will alert building maintenance 8 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx staff via email, text, and/or phone notifications if the fans fail to operate correctly based on a drop in vacuum levels from the Senva sensors or if there is a loss of power to the system. Several maintenance staff will be added to the alarm notifications and the Sensaphone is programmed to send multiple notifications if the alarm is not addressed. H&H is currently preparing an operations and maintenance (O&M) Plan for the building maintenance department to describe the VIMS components and alarm notifications and actions. Please note, in late July 2023, H&H observed that there may be an electrical issue with the Sensaphone that transmits data from the three electric fans in the Office Space based on an alert from the Sensaphone monitoring system. On August 2, 2023, H&H performed a Site visit to further investigate and verify operation of the electric fans and sub-slab vacuum levels. The observations indicated an electric transformer for the vacuum sensors that transmit data to the Sensaphone device may not be working properly; therefore, the property owner has been notified to conduct repairs on the transformer. Despite this electrical issue, based on the vacuum readings collected on August 2, 2023 (see above), the VIMS electric fans are working properly, and adequate vacuum is present below the slab of the Office Space. 9 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx 3.0 Pre-Occupancy System Effectiveness Testing Following installation of the VIMS and completion of interior construction activities, H&H collected indoor air samples in accordance with the VIMP for laboratory analysis to evaluate efficacy of the VIMS. Although not required by the VIMP, H&H also collected a concurrent sub-slab soil gas (vapor) sample for comparison to the indoor air data. Comparison of the sub- slab soil gas sample data to the indoor air sample data allows for evaluation of potential above slab interference due to potential off-gassing of vapors from construction materials. The sub-slab vapor and indoor air sampling activities were conducted in general accordance with the DEQ-approved VIMP and the DEQ DWM Vapor Intrusion Guidance (Guidance) dated March 2018. During the analytical sampling, and in the several weeks leading up to the sampling, the HVAC system in the office space and the electric VIMS fans were operating under normal conditions. 3.1 Sub-Slab Soil Gas Sampling Methodology On June 16, 2023, H&H collected one sub-slab vapor sample (MP-15) from monitoring point MP- 15 located in the eastern portion of the building and in an area of generally elevated sub-slab vapor concentrations observed during previous assessment activities prior to renovation of the building. The sub-slab vapor sample was collected one day after the indoor air sampling was completed (see Section 3.3). To collect the sub-slab vapor sample, Teflon® sample tubing secured to the vapor pin sampling port and connected to an airflow regulator and laboratory-supplied batch-certified 1-liter stainless steel Summa canister. The air flow regulator was preset by the laboratory to collect a soil gas sample at a flow rate no greater than approximately 200 milliliters per minute. Upon Summa canister receipt, H&H performed a shut-in test to verify the canister and regulator were properly sealed by the laboratory. Prior to sample collection, H&H conducted a leak test at the monitoring point by placing a shroud around the monitoring point and sampling train including 10 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx the Summa canister. The air within the shroud was flooded with helium gas and concentrations were measured with a calibrated helium detector. The helium concentration within the shroud was maintained at approximately 11%. A small air pump was connected to the sample tubing outside of the shroud and used to purge a minimum of three sample train volumes into a Tedlar® bag. The helium gas detector was used to measure helium concentrations within the Tedlar® bag sample to confirm helium concentrations in the sample were less than 10% of that measured within the shroud. Results of the helium leak check indicate that short-circuiting at the monitoring point or within the sampling train was not present at unacceptable levels. Sub-slab soil gas sample field forms completed by sampling personnel are included in Attachment E. Following a successful leak check, the air flow regulator was opened to allow collection of the sub-slab soil gas samples. Vacuum in the Summa canister was monitored during the sampling event to confirm adequate sample volume was collected at each monitoring point. Upon completion of sample collection, the air flow regulator was closed to the Summa canister. The canister was labeled with the sample identification, the beginning and ending times, the pressure measurements, and the requested analysis. The canister was then placed in a laboratory-supplied shipping container and delivered to Waypoint Analytical (Waypoint) under standard chain of custody protocols for analysis of select VOCs by Environmental Protection Agency (EPA) Method TO-15. The select list of compounds analyzed from the VIMP is included as Table F-1 in Attachment F. 3.3 Indoor Air Sampling Methodology On June 15, 2023, H&H collected two indoor air samples (IAS-OFF-1 and IAS-OFF-2) for laboratory analysis within the office space portions of the building in accordance with the general locations proposed in the VIMP. In addition, H&H collected an upwind exterior background air sample (IAS-OFF-BKG) concurrently during indoor air sampling event to evaluate compound concentrations in ambient outdoor air. These samples were collected the day prior to the sub-slab vapor sampling described above. The indoor air sample and background air sample locations are shown on Figure VM-1 (Attachment C). 11 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx One duplicate indoor air sample (IAS-OFF-DUP) was also collected for QA/QC purposes from indoor air sampling location IAS-OFF-1. The duplicate indoor air sample was collected utilizing a laboratory-supplied stainless-steel sampling “T” which allows for the simultaneous collection of two indoor air samples from a single location. Building conditions during indoor air sampling activities were consistent with anticipated conditions during building occupancy and ingress and egress activities were minimized with the HVAC system operational. The indoor air samples were collected using laboratory-supplied individually-certified 6-liter stainless steel Summa sample canisters connected to in-line flow controllers with a vacuum gauge. The background air sample was collected using a laboratory- supplied batch-certified 6-liter stainless steel Summa sample canister connected to an in-line flow controller with a vacuum gauge. The flow controllers were calibrated by the laboratory to allow for sample collection over an approximate 8-hour period consistent with a non-residential use scenario. Teflon tubing was connected to the flow controller with the Teflon tubing elevated by a laboratory stand so that the sample intake point was positioned approximately 5 ft above grade (typical breathing zone height) when the sample canister was set on its base. For QA/QC purposes, H&H personnel periodically monitored the sample canisters to prevent tampering or damage during the sampling event. Vacuum was measured in each of the Summa canisters prior to and after sampling activities. Per laboratory standard operating procedures, a vacuum was maintained within the canisters at the conclusion of the sampling event. During sampling activities, indoor/outdoor air pressure differential was measured near the start, middle, and end of the sampling period using a manometer sensitive to 0.001 in-WC. In addition, barometric pressure, exterior wind speed, exterior wind direction, and indoor/outdoor temperature were recorded near the start, middle, and end of the sampling period. Results of differential pressure measurements indicated that indoor pressure was the same as the exterior pressure on the day of the indoor air sampling activities. A summary of the field measurement data collected at the time of the indoor air sampling event is included in Attachment E. Upon completion of the indoor air sampling event, the Summa canisters were properly labeled with the sample identification, date, time, starting and ending vacuums, and requested analysis. 12 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx The canisters were then placed in a laboratory-supplied shipping container. The samples were shipped under standard chain-of-custody protocols to Waypoint for analysis of select VOCs by EPA Method TO-15. 3.3 Sub-Slab Vapor and Indoor Air Sampling Results A tabular summary of the sub-slab vapor and indoor air sample analytical results is provided in Table 1, and a copy of the laboratory analytical report with chain of custody record is provided as Attachment F. 3.3.1 Sub-Slab Vapor Sampling Results As the planned use of the building is for commercial (office) purposes, the sub-slab vapor sample laboratory analytical results were compared to the DEQ DWM Non-Residential SGSLs dated January 2023. Laboratory analytical results for the sub-slab vapor sample indicate the presence of several petroleum-related compounds detected above laboratory method detection limits (MDLs). None of the detected compounds were detected at concentrations above Non-Residential SGSLs. Note, TCE, a main contaminant of concern from previous Brownfields assessment activities, was not detected in the sub-slab vapor sample. 3.3.2 Indoor Air Sampling Results The indoor air sample laboratory analytical results were compared to the DEQ DWM Non- Residential IASLs dated January 2023. The indoor air sample analytical results indicate that several compounds were detected at concentrations above laboratory MDLs in the indoor air samples. Only one compound, naphthalene, was detected in one sample (IAS-OFF-DUP) at a concentration (5.08 µg/m3) above the Non-Residential IASL of 0.36 µg/m3. Note, naphthalene was not detected in the sub-slab vapor sample. Naphthalene is a common component of building and construction materials including gasoline products and cleaners used during construction. The field samplers notes that stainless steel cleaner and polish was observed inside of the Office Space during the indoor air sampling. Review of the Safety Data Sheet (SDS) for this this product 13 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx indicates that it contains petroleum and “solvent naphtha”, which is a liquid form of naphthalene. Therefore, the presence of this compound may be attributable to background indoor air sources and the specific cleaners present inside the building. No other compounds were detected at concentrations above the DEQ DWM Non-Residential IASLs in the indoor air samples collected at the Site in June 2023. A low-level estimated value (J-flag) of the chlorinated compound PCE (0.936 J µg/m3) was detected in the background sample at a concentration well below the IASL, and PCE was not detected in any of the indoor air samples. No TCE was detected in the indoor air samples or background sample. 3.4 Risk Evaluation The DEQ DWM Vapor Intrusion screening levels are conservative and based on a total cancer risk (TCR) for potential carcinogenic risks of 1 x 10-6 and a non-carcinogenic hazard quotient (HQ) of 0.2 for potential non-carcinogenic risks. The DEQ and EPA acceptable risk level for potential carcinogenic risks is a cumulative lifetime incremental cancer risk (LICR) of 1 x 10-4 or less, and the acceptable risk level for non-carcinogenic risks is a cumulative hazard index (HI) of 1 or less. The HI is the sum of the HQs of detected compounds. H&H utilized the DEQ Risk Calculator (January 2023) to further evaluate potential health risks posed by sub-slab vapor and indoor air conditions. A “worst-case” non-residential use risk scenario for the indoor air samples was calculated using the highest concentration of each detected compound from any of the indoor air samples (and duplicate). The completed DEQ Risk Calculators are included in Attachment G, and the risk calculator results are summarized in the table below. The worst-case non-residential use risk calculation indicates that the LICR was 1.5 x 10-5 and the HI was 0.45 for the indoor air samples, both of which are within DEQ acceptable risk levels. Therefore, the indoor air sample results and risk calculations indicate that concentrations of compounds within the office spaces are not present at levels that would pose unacceptable risk to the future commercial occupants of the building. 14 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx H&H utilized the DEQ Risk Calculator (January 2023) to further evaluate potential vapor intrusion risks. The sub-slab vapor risk calculations for the sample from MP-15 indicated a LICR of 3.2 x 10-8 and an HI of 0.00041, both of which are orders of magnitude below the unacceptable risk levels. Therefore, the sub-slab soil vapor results and risk calculations indicate that concentrations of compounds below the slab in this area are not present at levels that would pose unacceptable risk to the future commercial occupants of the building. While the risk levels for both the indoor air and sub-slab vapor samples are within acceptable levels, the majority of the calculated indoor air risk is attributed to the concentration of naphthalene detected in the indoor air duplicate sample. Naphthalene is a common component in building materials and petroleum products, such as gasoline and stainless steel cleaner observed during the sampling event. Further, naphthalene was not detected in the sub-slab vapor sample. Therefore, the presence of naphthalene in the duplicate indoor air sample is likely attributable to off-gassing of building materials or an above ground source, and it is not likely a result of vapor intrusion. 15 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx 4.0 Summary and Conclusions Installation of the active VIMS has been completed for the Office Space located within the eastern portion of the building located at 2315 N. Davidson Street on the North Davidson II Brownfields Property in Charlotte, North Carolina. The building is split into two sections, with the UDM Food Hall encompassing the western portion of the building, and the Office Space on the eastern side of the building. The two spaces within the building are separated by a demising wall and they have separate HVAC systems so there is no direct air exchange between the spaces. Based on the indoor air and sub-slab vapor sampling results conducted in June 2023 at the Site, the results of cumulative risk calculations using the sub-slab vapor sample data and the indoor air sample data indicate acceptable DEQ risk levels for the proposed commercial use of the building. The Site contaminant of concern, TCE, was not detected in the sub-slab vapor or indoor air samples. Based on the inspections performed by H&H, the active VIMS was installed in general accordance with the DEQ-approved VIMP, and the vacuum influence data indicates acceptable sub-slab vacuum at each monitoring point with the electric fans operating. Further, based on the analytical sampling data, there does not appear to be unacceptable risk from vapor intrusion of Site contaminants to the future commercial occupants of the building. 16 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx 5.0 System Monitoring Activities VIMS Alarm System In accordance with the DWM VI Guidance, the Sensaphone system was installed to monitor the installed VIMS and provide notifications of potential issues with the system operation. The Sensaphone system consists of a telemetric monitor (Sentinel) that will alert building maintenance staff via email, text, and/or phone notifications if any of the fans fail to operate correctly (see Section 2.0). Operating data for each fan is uploaded to a web interface that stores data and sends electronic notifications of alarms to the proper parties. The Sensaphone is set-up with the online interface and is connected to the internet within the UDM Food Hall. The building management group will be the responsible party for receiving these notifications and will be instructed to notify H&H of alerts or alarm activation if any of the fans fail or cease operation. In addition, the building maintenance staff will perform inspections of the VIMS components. The inspections will include accessible aboveground piping, monitoring points, overall condition of the accessible and floor slab, and inspection of the electric fans and discharges. H&H is currently preparing an O&M Plan for the building maintenance department to describe the VIMS components and alarm notifications and actions. Vacuum Monitoring & Analytical Sampling In accordance with the VIMP, quarterly vacuum monitoring will be conducted after occupancy and reported to DEQ after each event. After the first year of quarterly vacuum monitoring with acceptable vacuum data, a request may be submitted to DEQ for approval to reduce the vacuum monitoring frequency. In addition, post-occupancy indoor air analytical sampling events will be conducted on a semi-annual basis after occupancy and each sampling event will be reported to DEQ Brownfields. After the first year of analytical sampling and evaluation of the data, a request may be submitted to DEQ for approval to reduce the frequency of the analytical sampling events and the vacuum monitoring events. The reporting provisions, if warranted, as outlined in the DEQ TCE Action Levels will be followed upon receipt of the analytical laboratory reports. 17 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/24003_N. Davidson II_VIMS Install_Office Space.docx With both the UDM Food Hall and Office Space VIMS construction complete, the quarterly vacuum monitoring and analytical sampling events are anticipated to be conducted for the entire building during the same sampling events. Therefore, the next quarterly vacuum monitoring event for the building is proposed for September 2023, with the first post-occupancy semi-annual analytical sampling event proposed for December 2023 or January 2024, to align with indoor air sampling to be performed during the heating season. Table 1 Summary of Indoor Air and Sub-Slab Soil Gas Analytical Data North Davidson II Brownfields Site 2315 North Davidson Street Charlotte, North Carolina Brownfields Project No. 24003-20-060 H&H Job No. PAM.003 Building Identification Sample ID IAS-OFF-2 IAS-OFF-BKG MP-15 Date 6/16/2023 VOCs (TO-15) Acetone 40.9 37.8 26.5 19.3 16.8 NE NE Benzene 0.635 J 0.664 J 0.731 J 0.645 J 0.255 J 160 1.6 Carbon Disulfide 0.591 J 0.442 J 0.460 J 0.392 J 0.588 J 61,000 610 Chloroform <0.086 <0.086 <0.086 <0.086 1.60 J 53 0.53 Chloromethane 0.881 J 0.912 J 0.892 J <0.067 <0.067 7,900 79 Cyclohexane <0.161 <0.161 <0.161 <0.161 <0.161 530,000 5,300 Dichlorodifluoromethane 2.97 2.93 3.09 3.01 3.13 8,800 88 Ethanol 19.6 18.0 15.9 7.72 25.0 NE NE Ethylbenzene 1.50 J 1.45 J 0.933 J <0.106 <0.106 490 4.9 4-Ethyltoluene 0.363 J 0.388 J <0.128 <0.128 <0.128 NE NE Heptane 0.749 J 0.790 J 0.725 J <0.143 <0.143 35,000 350 n-Hexane 4.42 4.32 1.88 1.34 J 1.66 J 61,000 610 2-Hexanone <0.285 <0.285 0.532 J <0.285 <0.285 2,600 26 Isopropyl Alcohol 2.64 BJ 2.29 BJ 2.33 BJ 1.28 BJ 6.54 18,000 180 Methyl Ethyl Ketone (MEK)17.0 16.3 10.4 1.88 1.21 J 440,000 4,400 4-Methyl-2-Pentanone <0.121 <0.121 <0.121 <0.121 <0.121 260,000 2,600 Methylene Chloride 0.996 J 0.906 J 1.98 1.74 3.01 53,000 530 Naphthalene <0.183 5.08 <0.183 <0.183 <0.183 36 0.36 Styrene 4.32 4.56 3.31 <0.124 <0.124 88,000 880 Tetrachloroethene <0.181 <0.181 <0.181 0.936 J <0.181 3,500 35 Tetrahydrofuran 2.71 2.60 1.42 J <0.107 0.347 J 180,000 1,800 Toluene 7.20 7.07 4.99 3.26 0.455 J 440,000 4,400 Trichloroethene <0.199 <0.199 <0.199 <0.199 <0.199 180 1.8 Trichlorofluoromethane 1.71 J 1.71 J 1.78 J 1.75 J 2.29 J NE NE 124-Trimethylbenzene 3.70 3.80 3.24 <0.110 3.06 5,300 53 135-Trimethylbenzene 0.496 J 0.614 J <0.236 <0.236 <0.236 5,300 53 o-Xylene 1.65 J 1.68 J 1.18 J <0.157 <0.157 8,800 88 mp-Xylene 6.65 6.66 5.45 J 2.95 J 2.98 J 8,800 88 DEQ Cumulative Risk Calculator (3)Sub-Slab Vapor Carcinogenic Risk (LICR)--3.2 x 10-8 Non-Carcinogenic Hazard Index (HI)-- 0.00041 Notes: 1) North Carolina DEQ Vapor Intrusion Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs) dated January 2023. 2) North Carolina Department of Environmental Quality (DEQ) Vapor Intrusion Indoor Air Screening Levels (IASLs) dated January 2023. 3) North Carolina DEQ Cumulative Risk Calculator dated Janauary 2023 and is based on a TCR = 1 X 10-6 and THQ = 0.2. Compound concentrations are reported in micrograms per cubic meter (μg/m3). Compound concentrations are reported to the laboratory method detection limits. Only those compounds detected in at least one sample, and select chlorinated solvents, are shown in the table above. Laboratory analytical method shown in parentheses. Bold indicates compound concentration exceeds the Non-Residential SGSLs or IASLs. VOCs = Volatile Organic Compounds; -- = Not Applicable; NE = Not Established. TCR = Target Cancer Risk; THQ = Target Hazard Quotient. LICR = Lifetime Incremental Cancer Risk; HI = Hazard Index. J = Compound was detected above the laboratory method detection limit, but below the laboratory reporting limit resulting in a laboratory estimated concentration. B = Compound was detected in the laboratory method blank. Acceptable Risk Levels <1 x 10-4 <1.0 IAS-OFF-1 / IAS-OFF-DUP Non-Residential IASLs (2)Non-Residential SGSLs (1) Office Space 6/15/2023 Indoor Air Worst Case 1.5 x 10-5 0.45 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install Report Office Space/Table 1 - Analytical Data Summary 7/18/2023 Table 1 (Page 1 of 1) Hart & Hickman, PC 0 2000 4000 APPROXIMATE SCALE IN FEETN U.S.G.S. QUADRANGLE MAP QUADRANGLE 7.5 MINUTE SERIES (TOPOGRAPHIC) CHARLOTTE EAST, NORTH CAROLINA 1991 TITLE PROJECT SITE LOCATION MAP NORTH DAVIDSON II BROWNFIELDS PROPERTY2315 N. DAVIDSON STREET & 421 E. 26TH STREETCHARLOTTE, NORTH CAROLINA DATE: JOB NO: REVISION NO: FIGURE: 5-18-20 0 1PAM-003 SITE REVISION NO. 0 JOB NO. PAM-003 DATE: 12-22-20 FIGURE NO. 2 NORTH DAVIDSON II BROWNFIELDS PROPERTY2315 N. DAVIDSON ST. & 421 E. 26TH ST. CHARLOTTE, NORTH CAROLINA SITE LAYOUT MAP LEGEND SITE PROPERTY BOUNDARY FORMER RAIL SPUR LITTLE SUGAR CREEK DRAINAGE FEATURE 2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 GeologyLYNX LIGHT RAILN. DAVIDSON STREETE 2 6 T H S T R E E T JOR D A N P L A C E N. BREVARD STREETFORMERLUMBERSHED NODA SELF STORAGE(FORMER U.S. TEXTILE CORP.)(2401 N. DAVIDSON STREET) YANDLE METAL SHOP(2414 N. DAVIDSON STREET) YANDLE METAL SHOP(FORMER GENERAL LATEX &CHEMICAL CORP.)(2414 N. DAVIDSON STREET) COLLECTIVE APARTMENT COMPLEX(FORMER R.H. BOULIGNY, INC.)(2300 N. DAVIDSON STREET) NODA BREWING COMPANY (FORMER GIBBS ELECTROPLATING) (2229 N. DAVIDSON STREET) PERFORMANCE LOGISTICS (511 E. 25TH STREET) WOODTECH INTERIORS, INC(2228 N. BREVARD STREET) SUPERIOR STONE OF THESOUTHEAST(2310 N. BREVARD STREET) FORMER APPLIED RESEARCH GROUP (2221 N. DAVIDSON STREET) RHINO MARKET & DELI ANDFREE RANGE BREWING(2320 N. DAVIDSON STREET) NOTES: 1. AERIAL IMAGERY OBTAINED FROM MECKLENBURGCOUNTY GIS (2019). 421 E. 26TH STREET BUILDING APPROXIMATE LOCATION OF BUILDING SLAB EXTENSION 2315 N. DAVIDSON STREET BUILDING S:\AAA-Master Projects\PAMAKA - PAM\PAM-003 N. Davidson & E. 26th\VIMS\Figures\Site Map_R1.dwg, 12/22/2020 9:16:05 AM, DWG To PDF.pc3 Attachment A Excerpts from Previous Assessment Activities MW-10 IAS-1/SS-1 MW-1 MW-3 SB-1 SS-6 IAS-3/SS-3 IAS-4/SS-4 SS-5 MW-2 SB-2 SB-3 SB-4 BKG-1 MW-4 SB-5 IAS-2/SS-2 SS-7 SB-9 SS-8 SS-9 SS-10 SS-13 SS-12 SB-7 SB-6 SB-8 SW-2 SW-1 SS-11 SED-1 REVISION NO. 0 JOB NO. PAM-003 DATE: 9-28-20 FIGURE NO. 3 NORTH DAVIDSON II BROWNFIELDS PROPERTY 2315 N. DAVIDSON STREET & 421 E. 26TH STREET CHARLOTTE, NORTH CAROLINA SAMPLE LOCATION MAP LEGEND SITE PROPERTY BOUNDARY FORMER RAIL SPUR LITTLE SUGAR CREEK DRAINAGE FEATURE EXISTING GROUNDWATER MONITORING WELL SOIL BORING SUB-SLAB VAPOR SAMPLE POINT CO-LOCATED SUB-SLAB VAPOR AND INDOOR AIR SAMPLE POINT SURFACE WATER SAMPLE LOCATION SEDIMENT SAMPLE LOCATION ABANDONED MONITORING WELL 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 GeologyLYNX LI G H T R AIL N. D AVI DS O N S T R E ET E 2 6 TH S TRE E T JOR D A N P L A C E APPROXIMATE LOCATION OF FORMER LUMBER WAREHOUSE APPROXIMATE LOCATION OF FORMER AUTO REPAIR SHOP N. B R E V A R D S T R E E T MW-5 SB-1 MW-1 NOTES: 1)MONITORING WELLS MW-1 THROUGH MW-5 WERE INSTALLED IN APRIL 2016 BY SUMMIT ENGINEERING. 2)SOIL SAMPLES WERE COLLECTED BY H&H ON 3/5/-6/2020 AND 8/11-12/2020. 3)SUB-SLAB VAPOR SAMPLES COLLECTED BY H&H ON 8/8/2019 AND 8/11/2020. 4)INDOOR AIR SAMPLES COLLECTED BY H&H ON 11/12/2019. 5)SEDIMENT AND SURFACE WATER SAMPLES COLLECTED BY H&H ON 8/11/2020. IAS-1/SS-1 MW-10 SS-7 SW-1 SED-1 S:\AAA-Master Projects\PAMAKA - PAM\PAM-003 N. Davidson & E. 26th\EMP\Figures\Site Map_R1.dwg, 12/22/2020 1:42:32 PM, DWG To PDF.pc3 Table 3Summary of Groundwater Analytical ResultsNorth Davidson II Brownfields Property2351 N. Davidson Street and 421 E. 26th StreetCharlotte, North CarolinaH&H Job No. PAM-003Sample ID MW-1 MW-2 MW-DUP-1 MW-3 MW-4 MW-5Date 3/5/2020 3/5/2020 3/5/2020 3/6/2020Area of Potential ConcernFormer Lumber ShedFormer Junkyard AreaFormer Auto Repair ShopUpgradient Portion of SiteVOCs (8260D)Chloroform<2.3 <2.3 <2.3 <11.7 <11.73.0J70 0.81 3.6cis-1,2-Dichloroethene<0.29 <0.29 <0.292.2J<1.5 <0.2970 NS NSDiisopropyl ether<0.22 <0.22 <0.2212.8<1.1 <0.2270 1,400 5,900Methyl tert-butyl ether<0.28 <0.28 <0.28636<1.4<0.2820 450 2,000Trichloroethene<0.22 <0.22 <0.22110669<0.223.0 1.0 4.4SVOCs (8270E)-- -- --RCRA Metals (6020B, 7470A)Arsenic0.395J 0.631J<0.2500.403J 0.901J<0.25010 -- --Arsenic (Dissolved)NA <0.250 <0.250 <0.250 NA NA10 -- --Barium92.0 77.0 22.4 28.9 35.3 78.6700 -- --Barium (Dissolved)NA22.5 22.5 29.6NA NA700 -- --Cadmium<0.160 <0.160 <0.1600.424J<0.160 <0.1602.0 -- --Cadmium (Dissolved)NA <0.160 <0.160 <0.160 NA NA2.0 -- --Chromium1.15J17.81.01J13.5 3942.3510 -- --Chromium (Dissolved)NA0.689J 0.738J 1.01JNA NA10 -- --Lead0.970J 2.02 0.482J 1.01J 0.745J 1.21J15 -- --Lead (Dissolved)NA <0.2400.284J<0.240 NA NA15 -- --Selenium<0.380 <0.380 <0.3800.415J 1.33J<0.38020 -- --Selenium (Dissolved)NA <0.380 <0.380 <0.380 NA NA20 -- --Silver<0.310 <0.310 <0.310 <0.310 <0.310 <0.31020 -- --Silver (Dissolved)NA <0.310 <0.310 <0.310 NA NA20 -- --Mercury<0.0490 <0.0490 <0.0490 <0.0490 <0.0490 <0.04901.0 0.18 0.75Mercury (Dissolved)NA <0.0490 <0.0490 <0.0490 NA NA1.0 0.18 0.75Notes:1) North Carolina Department of Environmental Quality (DEQ) 15A NCAC 02L.0202 Groundwater Standards (2L Standards) (April 2013)2) NC DEQ Division of Waste Management (DWM) Residential Vapor Intrusion Groundwater Screening Levels (GWSLs) (July 2020)3) NC DEQ DWM Non-Residential Vapor Intrusion GWSLs (July 2020)With the exception of metals, only constituents detected in at least one sample are shown.Concentrations are reported in micrograms per liter (µg/L).Compound concentrations are reported to the laboratory method detection limitsLaboratory analytical methods are shown in parentheses.Bold concentrations exceed the DEQ 2L Standard and/or the Residential GWSL.Underlined concentrations exceed the DEQ 2L Standard and the Non-Residential GWSL.VOCs = volatile organic compounds; SVOCs = semi-volatile organic compounds, RCRA = Resource Conservation and Recovery ActNA = not analyzed; NS = not specified; -- = not applicableJ = estimated value between the laboratory method detection limit and the laboratory reporting limitAll Below Laboratory Method Detection LimitsNC 2L Groundwater Standards (1) Residential GWSL(2)Non-Residential GWSL(3)3/6/2020Former Junkyard AreaS:\AAA-Master Projects\PAMAKA - PAM\PAM-003 N. Davidson & E. 26th\EMP\Data Tables\GW Data Table_10-12-2010/19/2020Table 3 Hart & Hickman, PC Table 5Summary of Sub-slab Vapor Analytical ResultsNorth Davidson II Brownfields Property2351 N. Davidson Street and 421 E. 26th StreetCharlotte, North CarolinaH&H Job No. PAM-003Sample IDSample LocationSample DateAnalytical MethodAcetoneBenzene2-Butanone (MEK)Carbon DisulfideCarbon TetrachlorideChloroformChloromethaneCyclohexane1,2-Dichlorobenzene1,4-DichlorobenzeneDichlorodifluoromethane (Freon 12)cis-1,2-DichloroethyleneEthanolEthylbenzene4-EthyltolueneHeptaneHexane2-Hexanone (MBK)IsopropanolMethylene Chloride4-Methyl-2-pentanone (MIBK)NaphthalenePropeneStyreneTetrachloroetheneTetrahydrofuranTolueneTrichloroetheneTrichlorofluoromethane (Freon 11)1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenem&p-Xyleneo-XyleneSS-1 8/8/2019 100J<2.6 <9.2 <4.3 <4.1260<2.8 <4.9 <5.8 <7.3 <4.3 <3.2120J<5.0 <6.0 <4.8 <12 <4.8 <6.0 <8.4 <3.9 <8.0 <3.4 <5.3860<3.9 <3.991,000<6.5 <6.3 <6.2 <10 <5.4SS-2 8/8/2019 120 0.5J 7.2J<0.430.63J 1.9<0.28 <0.49 <0.58 <0.732.5<0.32130<0.50 <0.60 <0.48 <1.2 <0.485.4J<0.84 <0.390.86J<0.34 <0.5319<0.390.89272.0J<0.63 <0.62 <1.0 <0.54SS-3 220 0.33J 5.7J 4.3J<0.411.3<0.28 <0.49 <0.58 <0.73 <0.43 <0.32130<0.50 <0.60 <0.48 <1.2 <0.4816J<0.84 <0.39 <0.80 <0.34 <0.533.2<0.390.65J<0.431.9J<0.63 <0.62 <1.0 <0.54DUP-2/SS-3 230 0.42J 7.5J 5.3J<0.41 <0.36 <0.28 <0.49 <0.58 <0.732.3<0.32110<0.50 <0.60 <0.48 <1.2 <0.4811J<0.84 <0.390.86J<0.34 <0.533.1<0.390.83<0.431.9J<0.63 <0.62 <1.0 <0.54SS-4 8/8/2019 260 1.3 9.5J 25<0.41 <0.36 <0.28 <0.49 <0.58 <0.732.9<0.32110 2.2 2.4<0.48 <1.2 <0.4812J 0.85J<0.390.94J 17<0.53 <0.75 <0.393.2<0.431.0J 14 8.9 8.9 3.6SS-5 8/8/2019 72 1.1 10J 8.6<0.41 <0.36 <0.28 <0.49 <0.58 <0.732.8<0.3251 0.94<0.602.6 6.1J<0.489.4J<0.84 <0.391.7<0.34 <0.537.4<0.394.2 1.2 3.2J 2.6 1.4 3.4 1.5SS-6 8/8/2019 56 0.87 6.9J 20<0.41 <0.36 <0.28 <0.49 <0.58 <0.732.7<0.3251 0.64J<0.60 <0.48 <1.2 <0.486.7J<0.84 <0.391.7<0.34 <0.538.4<0.393.4 6.1 2.7J<0.63 <0.622.1 0.82JSS-7<86018J<150 <120 <2592<24 <25 <33 <20 <23 <202,600 22J 32J<27 <96 <35 <340 <120 <3244J<87 <18540<11023J43,000<64120 49J 77J 43JSS-DUP/SS-7<860 <14 <150 <120 <258232J<25 <33 <20 <23 <20600J<14 <23 <27 <96 <35 <340 <120 <32 <44 <87 <18540<110 <1643,000<6431J<1927J<17SS-8 8/11/2020 600 1.8 22J<1.6 <0.33290.45J 2.5 0.53J 1.1J 2.8<0.271,000 34 82 1.2<1.36.5 28 1.7J 3.4J4.7J2.6J 0.44J 170<1.54.05,0006.0 190 40 180 110SS-9 8/11/2020 140J 0.27J 8.7J 34<0.33 <0.24 <0.322.5<0.440.36J<0.31 <0.2752 1.6 51 1.3<1.3 <0.467.6J<1.60.79J3.9<1.20.39J 1.4<1.55.0<0.401.5J 130 88 8.5 7.4SS-10 8/11/2020<860 <14 <150 <120 <2515033J<25 <33 <20 <23 <201,300<1432J<27 <96 <35 <340 <120 <32 <44 <87 <18560<110 <1626,000<6466J 27J 42J 25JSS-11 8/11/2020 170 1.3 44 8.3<0.33 <0.24 <0.321.5<0.44 <0.272.9<0.27150 0.97<0.302.2 2.9J 11 38<1.630 1.5J 6.8J 1.3 8.5<1.54.4<0.402.1J 1.1 0.31J 230 0.76JSS-12 8/11/2020 59 0.58J 16J 4.9J<0.33 <0.24 <0.326.7<0.44 <0.273.0<0.27150 0.28J 0.31J<0.35 <1.33.1 13J<1.6 <0.430.88J<1.20.31J 27 7.1 1.1 1.2 2.7J 0.47J<0.261.1J 0.43JSS-13 8/11/2020 38<0.193.6J<1.60.45J 0.57J<0.322.1<0.44 <0.272.9 1.7 300 0.23J 0.31J<0.35 <1.3 <0.4612J<1.60.67J 0.84J 1.5J 0.77J 4.1<1.50.83 3.1 1.8J 0.37J<0.260.8J 0.33J220,000 120 35,000 4,900 160 41 630 42,000 1,400 85 700 NS NS 370 NS 2,800 4,900210 1,400 4,200 21,000 21 21,000 7,000 280 14,000 35,000 14 NS 420 420 700 7002,700,000 1,600 440,000 61,000 2,000 530 7,900 530,000 18,000 1,100 8,800 NS NS 4,900 NS 35,000 61,000 2,600 18,000 53,000 260,000 260 260,000 88,000 3,500 180,000 440,000 180 NS 5,300 5,300 8,800 8,800Notes:1) North Carolina Department of Environment Quality (DEQ) Division of Waste Management (DWM) Residential Sub-slab and Exterior Soil Gas Screening Levels (SGSLs) (February 2018)2) North Carlolina DEQ DWM Non-Residential SGSLs (February 2018).Bold values exceeds the NCDEQ DWM Residential SGSL.Bold and Underlined value exceeds the NCDEQ DWM Residential and Non-Residential SGSL.Compound concentrations are reported to the laboratory detection limits.Compound concentrations are reported in micrograms per cubic meter (µg/m3).J = estimated concentration between the laboratory method detection limit and the laboratory reporting limitNS = Not SpecifiedDWM Residential SGSL (1)DWM Non-Residential SGSL (2)2315 N. Davidson StreetTO-158/8/2019421 E. 26th Street2315 N. Davidson Street8/11/2020421 E. 26th StreetS:\AAA‐Master Projects\PAMAKA ‐ PAM\PAM‐003 N. Davidson & E. 26th\VIMS\Combined Data Tables (9‐18‐20) RJC.xlsx1/7/2021Table 5Hart & Hickman, PC Table 6 Summary of Indoor Air Analytical Data North Davidson II Brownfields Brownfields Property 2315 N. Davidson Street and 421 E. 26th Street Charlotte, North Carolina H&H Job No. PAM-003 Sample IDSample LocationSample DateAnalytical MethodChloroformTetrachloroethyleneTrichloroethyleneIAS-1 0.10 J <0.13 0.14 J IAS-1 Duplicate (DUP-1)0.20 0.34 <0.076 IAS-2 Southern Portion of 2315 N. Davidson Street Building 11/6/2019 0.086 J <0.13 <0.076 IAS-3 Northern Portion of 2315 N. Davidson Street Building 11/6/2019 0.13 J 0.16 J <0.076 IAS-4 Eastern Portion of 2315 N. Davidson Street Building 11/6/2019 0.12 J <0.23 <0.13 BKG-1 Upwind, West of 2315 N. Davidson Street Building 11/6/2019 <0.11 <0.23 <0.13 0.12 8.3 0.42 0.53 35 1.8 Notes: 1) North Carolina Department of Environment Quality (DEQ) Division of Waste Management (DWM) Residential and Non-Residential Indoor Air Screening Levels (IASLs) dated July 2020. Based on a Total Cumulative Risk of 1x10-6 and a Target Hazard Quotient of 0.2. Compound concentrations are reported in micrograms per cubic meter (µg/m3). Compound concentrations are reported to the laboratory detection limits. J = Compound was detected above the laboratory method detection limit, but below the laboratory reporting limit resulting in a laboratory estimated concentration. IAS = indoor air sample; BKG = background DWM Non-Residential IASL (1) TO-15 DWM Residential IASL (1) Western Portion of 2315 N. Davidson Street Building 11/6/2019 S:\AAA‐Master Projects\PAMAKA ‐ PAM\PAM‐003 N. Davidson & E. 26th\EMP\Data Tables\Indoor Air Data Table (11‐29‐19) 10/12/2020 Table 6 Hart & Hickman, PC Attachment B VIMS As-Built Drawings – 2315 N. Davison Street (Office Space) VM-1, VM-1A, VM-2, and VM-3 Dated August 3, 2023 VIMS PLAN VIEW LAYOUT (2315 N. DAVIDSON STREET)1" = 10'1VM-1F-1F-2F-3F-4F-5F-6F-7F-8F-9F-10F-11MP-7MP-4MP-5MP-1MP-2MP-3MP-13MP-12MP-14MP-7MP-9MP-8MP-10MP-15MP-11MP-6H&H NO. PAM-003VAPOR INTRUSIONMITIGATION SYSTEMPLAN VIEW LAYOUTOFFICE SPACEVM-1NORTH DAVIDSON II BROWNFIELDS PROPERTY (BROWNFIELDS NO. 24003-02-060) OFFICE SPACE 2315 N. DAVIDSON STREET CHARLOTTE, NORTH CAROLINATITLE:SHEET:VAPOR INTRUSION MITIGATIONPLAN PREPARED BY:2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 GeologyLEGENDEXISTING LOAD INTERNAL BEARING WALL AND FOOTERPROPOSED INTERNAL STUD WALLVIMS SUCTION TRENCH (12" WIDE BY 12" DEEP) WITH 3" SCH 40 PVC SLOTTED ORPERFORATED PIPE SET WITHIN CLEAN 57 STONE3" SCH 40 PVC SOLID PIPE SET WITHIN TRENCH WITH SOIL BACKFILLAREA FOR PROPOSED NEW CONCRETE WITH VAPOR BARRIER3" SCH 40 PVC RISER WITH CONNECTED TO TRENCHVACUUM MONITORING POINTSUCTION TRENCH CLEAN-OUTVIMS ELECTRIC FAN DISCHARGE ON ROOF OFF-SET FROM RISERHORIZONTAL 3" SCH 40 PVC PIPING BELOW CEILING FOR FAN OFF-SET FROM RISERWESTERN PORTION OF BUILDING - UDM FOOD HALLINDOOR AIR SAMPLE LOCATIONBACKGROUND AIR SAMPLE LOCATIONNOTES:1.EACH RISER FAN CONTAINS A PRESSURE-TECH PT-16 ELECTRIC FANINSTALLED ON THE ROOFTOP. SEE DETAIL 9 / VM-2.2.VIMS = VAPOR INTRUSION MITIGATION SYSTEM; SCH = SCHEDULE;TYP = TYPICAL3.SENSAPHONE SENTINEL INSTALLED IN CENTRAL LOCATION. REFERTO DETAIL 10/VM-2.4.REFER TO SHEET VM-1A FOR PROPOSED ROOF PLAN DEPICTINGLOCATIONS OF MECHANICAL EQUIPMENT.5.PRE-OCCUPANCY INDOOR AIR AND BACKGROUND SAMPLES WERECOLLECTED ON 6/15/23.6.ONE SUB-SLAB SAMPLE WAS COLLECTED FROM LOCATION MP-15 ON6/16/23.7.VIMS INSTALLATION REPORT FOR UDM FOOD HALL WAS SUBMITTEDUNDER SEPARATE COVER.EXISTING BUILDING EXTERIORWALLREFER TO DETAIL 13 FOR UTILITYPENETRATIONS THROUGHEXTERIOR WALL/FOOTERREFER TO DETAIL 13 FOR UTILITYPENETRATIONS THROUGHEXTERIOR WALL/FOOTERNORTH DAVIDSONSTREETPROFESSIONALAPPROVAL / SEALAUGUST 3, 202308/03/23AS-BUILT DRAWINGIAS-OFF-2SUB-SLAB SAMPLELOCATIONDEMISING WALL WITHNO DOORS, WINDOWS,OR OPENINGSIAS-OFF-BKGIAS-OFF-13VM-23VM-25/6VM-28VM-27VM-27VM-27VM-2LOCATION OF SENSAPHONE FORVACUUM SENSORS THROUGHOUTENTIRE BUILDINGAS-BUILT\\harthick.sharepoint.com@SSL\DavWWWRoot\sites\MasterFiles-1\Shared Documents\AAA-Master Projects\PAMAKA - PAM\PAM-003 N. Davidson & E. 26th\VIMS\2315 N. Davidson VIMS\2315 N.Davidson_VIMS AS-Built_Office Space.dwg VIMS PLAN VIEW LAYOUT (2315 N. DAVIDSON STREET)1" = 10'1VM-1F-1F-2F-3F-4F-5F-6F-7F-8F-9F-10F-11H&H NO. PAM-003VAPOR INTRUSIONMITIGATION SYSTEMROOF PLANOFFICE SPACEVM-1ANORTH DAVIDSON II BROWNFIELDS PROPERTY (BROWNFIELDS NO. 24003-02-060) OFFICE SPACE 2315 N. DAVIDSON STREET CHARLOTTE, NORTH CAROLINATITLE:SHEET:VAPOR INTRUSION MITIGATIONPLAN PREPARED BY:2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 GeologyLEGENDPROPOSED INTERNAL STUD WALLINDIVIDUAL SUCTION POINT WITH 3" SCH 40 PVC RISERINDIVIDUAL SUCTION POINT WITH 3" SCH 40 PVC RISER CONNECTED TO VIMS TRENCHVIMS ELECTRIC FAN DISCHARGE ON ROOF OFF-SET FROM RISERHORIZONTAL 3" SCH 40 PVC PIPING BELOW CEILING FOR FAN OFF-SET FROM RISERWESTERN PORTION OF BUILDING - UDM FOOD HALLNOTES:1.THE DEPICTED ROOF PLAN WAS OBTAINED FROM THE MECHANICAL PERMITDRAWINGS DATED JULY 31, 2020. THE FINAL MECHANICAL DESIGN AND LAYOUTMAY HAVE CHANGED.2.VIMS FAN DISCHARGE LOCATIONS ARE A MINIMUM OF 10 FT FROM HVAC AIRINTAKES, SUCTION FANS, OR OPERABLE OPENINGS INTO THE BUILDING. REFERTO SHEET VM-3 FOR SYSTEM SPECIFICATIONS.3.EACH RISER FAN CONTAINS A PRESSURE-TECH PT-16 ELECTRIC FAN INSTALLEDON THE ROOFTOP. SEE DETAIL 9 ON SHEET VM-2.4.VIMS = VAPOR INTRUSION MITIGATION SYSTEM; SCH = SCHEDULE; TYP = TYPICAL;KEF = KITCHEN EXHAUST FAN; KSF = KITCHEN SUCTION FAN; RTU =ROOF TOPUNIT.5.VIMS INSTALLATION FOR UDM FOOD HALL WAS SUBMITTED UNDER SEPARATECOVER.NORTH DAVIDSONSTREETPROFESSIONALAPPROVAL / SEALAS-BUILT DRAWINGAUGUST 3, 202308/03/23AS-BUILT\\harthick.sharepoint.com@SSL\DavWWWRoot\sites\MasterFiles-1\Shared Documents\AAA-Master Projects\PAMAKA - PAM\PAM-003 N. Davidson & E. 26th\VIMS\2315 N. Davidson VIMS\2315 N.Davidson_VIMS AS-Built_Office Space.dwg BASE COURSE BELOW NEW CONCRETE1NTSVM-2VENTED COLLECTION PIPING BELOW NEW CONCRETE2NTSVM-2BASE COURSE - CLEAN 57 STONE(WASHED WITH NO FINES), MIN 4"THICK BENEATH NEW CONCRETE3" SCH 40 PVC VENT PIPE SET WITHIN MIN 4" BASECOURSE. VENT PIPE SHALL BE 0.020" SLOTTEDPIPE OR 5/8" PERFORATED WITH 5-HOLE SPACED60 DEGREES APART AND 6" OFF CENTERSOIL SUB-BASESOIL SUB-BASEMIN 6" NEW CONCRETE SLAB WITH REBARAND WIRE MESH IN ACCORDANCE WITHSTRUCTURAL DRAWINGS.MIN 6" NEW CONCRETE SLAB WITHREBAR AND WIRE MESH IN ACCORDANCEWITH STRUCTURAL DRAWINGS.15-MIL VAPOR BARRIER15-MIL VAPOR BARRIER BELOWNEW CONCRETE VIMS SUCTION TRENCH WITH RISER AT EXISTING WALL - SIDE VIEWNTS3VM-23" SCH 40 PVC RISERDUCT PIPESOLID TO PERFORATED/SLOTTED 3" SCH 40PVC PIPE TRANSITIONMIN 1% SLOPE TOWARDSLOTTED SECTIONCLEAN 57 STONE, OR SIMILAR, PLACEDWITHIN TRENCH AROUND SLOTTEDPIPE SECTIONEXISTING SOILSMINIMUM 6" CONCRETE SLAB WITH REBARAND WIRE MESH IN ACCORDANCE WITHSTRUCTURAL DRAWINGS15-MIL VAPOR BARRIERPLACED AT INTERFACE OF 57STONE AND NEW CONCRETESOLID 3" SCH 40 PVC.LENGTH VARIES, REFER TOSHEET VM-1SEAL PENETRATION WITH URETHANESEALANT, OR SIMILAR3" SCH 40 PVC 45-DEGREE OR90-DEGREE ELBOW(S) TO AVOIDEXISTING FOOTERVIMS SUCTION TRENCH - SECTION VIEW4NTSVM-2EXISTING SOILS3" SCH 40 PVC PERFORATEDOR SLOTTED PIPE WITH MIN4" STONE BELOW PIPECLEAN 57 STONESEAL COLD JOINT BETWEENEXISTING AND NEW CONCRETE WITHURETHANE SEALANT, OR SIMILARVAPOR BARRIER PLACED ATINTERFACE OF 57 STONE ANDNEW CONCRETEMIN 6" CONCRETE SLAB WITH REBARAND WIRE MESH IN ACCORDANCEWITH STRUCTURAL DRAWINGSEXISTING CONCRETE5NTSVACUUM MONITORING POINTVM-2EXISTING CONCRETE SLABFLOOR CLEAN-OUT SET FLUSHWITH FINISHED FLOOR(SEE DETAIL 9)1" SCH 40 0.020" SLOTTED PVCPIPE WITH OPEN END ON BOTTOM#2 WELLPACK FILTRATIONSAND (OR SIMILAR COARSESAND)EXISTING SUB-SLAB SOILSEAL JOINT WITH URETHANESEALANT, OR SIMILAR (SEE SPEC #)1" EXPANDABLE WELLPLUGPOLY-URETHANESEALANTVAPOR BARRIERSEE DETAIL 9 / VM-2VACUUM MONITORING POINT FINISHING DETAILNTSVM-26FLOOR CLEANOUT, ADJUSTABLE, 4" DIAZURN INDUSTRIES MODEL #CO2450-PV4FLUSH WITH FINISHED FLOOR1" EXPANDABLE WELLPLUG#2 WELLPACK FILTRATION SAND(OR SIMILAR COARSE SAND)SEAL JOINT WITH URETHANESEALANT, OR SIMILAR (SEE SPEC #)POLY-URETHANESEALANTVAPOR BARRIERELECTRIC EXHAUST FAN AND RISER ON ROOFTOPNTS9VM-2PRESSURE-TECH PT-16 HIGH SUCTIONFAN OR SIMILAR FAN APPROVED BY THEDESIGN ENGINEERDISCHARGE POSITIONED MIN 15 FT FROMAIR INTAKES OR OPERABLE BUILDINGOPENINGS AND MINIMUM 3' ABOVEROOFLINELABEL FAN WITH IDENTIFICATION NUMBERAND "VAPOR MITIGATION SYSTEM -CONTACT MAINTENANCE IF NOTOPERATING", OR SIMILARINSTALL WEATHERPROOF BOX FOR 120VACTO DC INVERTER REQUIRED FOR FANRUN ELECTRIC CONDUIT TO CENTRALBREAKER BOX FOR FAN; RUN LOW VOLTAGEWIRE TO CENTRAL ALARM FROMDIFFERENTIAL PRESSURE SENSOR3" SCH 40 PVC TEE WITH THREADEDREDUCER BUSHING FOR BARB INSTALLATION 12" OR 14" BARB INSTALLATION WITH POLYTUBING, OR SIMILAR, CONNECTED TODIFFERENTIAL PRESSURE SENSORSENVA P4-2500-DB1XP DIFFERENTIALPRESSURE TRANSMITTER SENSOR RATEDFOR -25 TO 25 "WC SECURED TO RISERINSTALL RISER SUPPORT CONNECTEDTO ROOFTOP (AS NEEDED)3" SCH 40 PVC RISERSECURE TO ROOF TRUSSES,COLUMNS, OR STUD WALLSDROP CEILING OR EXISTINGCEILING TRUSSESWATERTIGHT ROOF FLASHINGVARMINT GUARD PIPE CAP WITH SCREEN,RADONAWAY #76041-2, OR SIMILARLABEL RISER PIPE EVERY 10-FT WITH"VAPOR MITIGATION SYSTEM - CONTACTMAINTENANCE"ROOFTOPREFER TO ROOF/CEILING PLAN ON SHEETVM-1 AND DETAIL 14 FOR LOCATION OFHORIZONTAL PIPE RUNS WHERE FANEXHAUST IS OFF-SET FROM RISERUTILITY PENETRATION AT EXTERIOR WALLNTS11VM-2EXTERIOR GRADE VARIES.REFER TO CIVIL ANDARCHITECTURAL PLANS SEAL LOCATED AROUND UTILITY THROUGHEXTERIOR WALL OR FOOTERCOMPACTED SOILS AROUNDUTILITY AT EXTERIORPENTRATIONEXISTING EXTERIOR WALLAND FOOTERCRUSHED STONE BACKFILLWITHIN UTILITY TRENCHEXISTING SOILSINTERIOR SPACEEXTERIOR SPACE(OPEN AIR)UTILITIES INSTALLEDBY OTHERSVIMS EXTRACTION TRENCH CLEAN-OUTNTS8VM-2FLOOR CLEANOUT, ADJUSTABLE, 4" DIAZURN INDUSTRIES MODEL #CO2450-PV4FLUSH WITH FINISHED FLOOR2" EXPANDABLE WELL CAP3" SCH 40 PVC ALL-HUB2-WAY CLEANOUT3" SCH 40 PVC SOLID ORPERFORATE/SLOTTED PIPE. REFERTO SHEET VM-12" SCH 40 PVC PIPE WITH 4" X 2"PVC FLUSH REDUCER BUSHINGCLEAN 57 STONE OR COMPACTEDSOIL. REFER TO SHEET VM-1.15-MIL VAPOR BARRIERPLACED AT INTERFACE OF 57STONE AND NEW CONCRETE(IF PRESENT)3" X 2" PVC REDUCERMIN 6" NEW CONCRETE SLAB WITHREBAR AND WIRE MESH IN ACCORDANCEWITH STRUCTURAL DRAWINGSTYPICAL VACUUM ALARM SET-UPNTS10VM-2REMOTE SENSAPHONE SENTINEL(SCD-1200) UNIT IN UDM FOOD HALLSPACE24 VDC POWER SUPPLY ACCESSORY(SENSAPHONE FGD-0070).ELECTRICAL OUTLET (120VAC) OR HARD-WIRED TOBREAKER BOXLOW VOLTAGE WIRESSENVA P4-2500-DB1LP DIFFERENTIALPRESSURE TRANSMITTER SENSOR RATEDFOR -25 TO 25 "WC SECURE TO RISERVIMS HORIZONTAL PIPING FOR EXHAUST FAN OFF-SET FROM RISERNTS12VM-2SEE DETAIL 11(ELECTRIC EXHAUST FAN)SEE DETAILS 3 TO 6(VIMS RISER)MIN 1% SLOPE TOWARDEXTRACTION POINTEXISTING CEILLINGTRUSSESROOFTOPPIPE SUPPORTS PER NCBUILDING CODESOLID 3" SCH 40 PVC.LENGTH VARIES, REFER TOSHEETS VM-1 & VM-1A3" SCH 40 PVC90-DEGREE ELBOW3" SCH 40 PVC90-DEGREE ELBOWSUB-BASECONCRETE FLOOR SLABSILICONE SLEEVEVAPOR PIN BRASSSAMPLING DEVICEVAPOR PIN STAINLESSSTEEL FLUSH-MOUNTCOVER (SCREWS ONTOVAPOR PIN)VAPOR PINSAMPLING BARB(CAPPED)VACUUM MONITORING POINT VAPOR PINNTSVM-27H&H NO. PAM-003VAPOR INTRUSIONMITIGATION SYSTEMSECTION DETAILSOFFICE SPACEVM-2NORTH DAVIDSON II BROWNFIELDS PROPERTY (BROWNFIELDS NO. 24003-02-060) OFFICE SPACE 2315 N. DAVIDSON STREET CHARLOTTE, NORTH CAROLINATITLE:SHEET:VAPOR INTRUSION MITIGATIONPLAN PREPARED BY:2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 GeologyNOTES:1.NTS = NOT TO SCALE;2.SCH = SCHEDULE;3.VIMS = VAPOR INTRUSION MITIGATION SYSTEM4.MIN = MINIMUMPROFESSIONALAPPROVAL / SEALAUGUST 3, 2023AS-BUILT DRAWING08/03/23AS-BUILT\\harthick.sharepoint.com@SSL\DavWWWRoot\sites\MasterFiles-1\Shared Documents\AAA-Master Projects\PAMAKA - PAM\PAM-003 N. Davidson & E. 26th\VIMS\2315 N. Davidson VIMS\2315 N.Davidson_VIMS AS-Built_Office Space.dwg H&H NO. PAM-003VAPOR INTRUSIONMITIGATION SYSTEMNOTES &SPECIFICATIONSOFFICE SPACEVM-3NORTH DAVIDSON II BROWNFIELDS PROPERTY (BROWNFIELDS NO. 24003-02-060) OFFICE SPACE 2315 N. DAVIDSON STREET CHARLOTTE, NORTH CAROLINATITLE:SHEET:VAPOR INTRUSION MITIGATIONPLAN PREPARED BY:2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 GeologyVAPOR INTRUSION MITIGATION SYSTEM (VIMS) NOTES & SPECIFICATIONSA) GENERAL1. THIS VAPOR MITIGATION PLAN WAS USED FOR DIRECTION OF VIMS COMPONENT INSTALLATION ONLY AND WAS NOT INTENDED TO GUIDE CONSTRUCTION OF STRUCTURALCOMPONENTS NOT RELATED TO THE VIMS.2. NOT EVERY CONDITION OR ELEMENT COULD BE EXPLICITLY SHOWN ON THESE DRAWINGS; THEREFORE, THE CONTRACTOR USED INDUSTRY ACCEPTED STANDARD GOODPRACTICE FOR MISCELLANEOUS WORK NOT EXPLICITLY SHOWN.3. THE CONTRACTOR WAS INSTRUCTED TO USE MATERIALS OR PRODUCTS THAT DID NOT CONTAIN THE COMPOUNDS TETRACHLOROETHENE (PCE) OR TRICHLOROETHENE(TCE). THE CONSTRUCTION CONTRACTOR SUPPLIED THE DESIGN ENGINEER SAFETY DATA SHEETS (SDS) FOR ALL MATERIALS USED FOR CONSTRUCTION.4. CHANGES OR MODIFICATIONS TO THE SYSTEM DURING CONSTRUCTION WERE APPROVED BY THE DESIGN ENGINEER. AFTER COMPLETION AND CERTIFICATION OF THEVIMS BY NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY (DEQ ) PROPOSED MODIFICATIONS OR CHANGES TO THE SYSTEM ARE TO BE PROVIDED TO THEDESIGN ENGINEER AND DEQ FOR APPROVAL.B) SUCTION TRENCHES AND SUCTION POINTS1. AT THE SUCTION TRENCHES, A 12" DEEP BY 12" WIDE TRENCH WAS EXCAVATED WITHIN THE EXISTING SOILS BELOW THE EXISTING CONCRETE SLAB AT LOCATIONSDEPICTED ON SHEET VM-1. THE TRENCH WAS FILLED WITH WASHED (CLEAN) #57 STONE GRAVEL, AND A 3" DIA SCH 40 PVC SLOTTED PIPE. A VAPOR BARRIER WASINSTALLED BETWEEN THE 57 STONE AND NEW CONCRETE. WHERE APPLICABLE, THE VAPOR BARRIER USED WAS 15-MIL STEGO INDUSTRIES,LLC STEGO WRAP VAPORINTRUSION BARRIER.2. VIMS PIPE CONSISTS OF 3" SCH 40 PVC. PVC PIPE JOINTS WERE CONNECTED USING PVC SOCKET COUPLINGS AND LOW-VOC PVC GLUE OR THREADED FITTINGS.3. SOILS USED TO BACKFILL AROUND SOLID SECTIONS OF PIPE WAS COMPACTED PRIOR TO COMPLETING THE TRENCH WITH CONCRETE. SOLID SECTIONS OF PIPE WERENOT TRAPPED AND SLOPED A MINIMUM OF 1% (18" PER FOOT) TO ALLOW FOR ACCUMULATED WATER TO GRAVITY DRAIN TO THE SUCTION POINT.4. NEW CONCRETE ON TOP OF THE SUCTION POINTS AND SUCTION TRENCHES IS A MINIMUM 6" THICK WITH REBAR AND WIRE MESH.C) RISER PIPES AND FANS1.VERTICAL PIPE RUNS WERE GENERALLY SUPPORTED AT LEAST EVERY 10 FEET AND AT EVERY PENETRATION THROUGH SLABS, CEILINGS, OR ROOF DECKS ANDINSTALLED APPLICABLE 2018 NORTH CAROLINA STATE PLUMBING CODES.2. MODIFICATIONS TO THE HORIZONTAL RUNS FOR ABOVE GRADE VENT PIPING WERE APPROVED BY THE DESIGN ENGINEER. HORIZONTAL PIPE RUNS ARESUPPORTED ATLEAST EVERY 6 FEET WITH APPROVED HANGERS OR OTHERWISE SPECIFIED PER NORTH CAROLINA BUILDING CODE.3. RISER DUCT PIPING WAS INSTALLED TO CONNECT EACH SLAB PENETRATION LOCATION TO A ROOFTOP EXHAUST DISCHARGE POINT WITH AN ELECTRIC RADON FAN. THERISER PIPE IS 3" SCH 40 PVC.4. 3” SCH 40 PVC RISER DUCT PIPING EXTENDS IN A VERTICAL ORIENTATION THROUGH THE BUILDING ROOF AND TERMINATES A MINIMUM OF 3 FT ABOVE THE BUILDING ROOFLINE. PRESSURE TECH PT-16 FANS WERE INSTALLED ON THE EXHAUST DISCHARGE END OF EACH RISER DUCT PIPE. EXHAUST DISCHARGE LOCATIONS ARE A MINIMUM OF10 FT FROM ANY OPERABLE OPENING OR AIR INTAKE INTO THE BUILDING.5. ABOVE-SLAB ACCESSIBLE RISER DUCT PIPING IS PERMANENTLY IDENTIFIED BY MEANS OF A TAG OR STENCIL AT A MINIMUM OF ONCE EVERY 10-LINEAR FT WITH "VAPORMITIGATION - CONTACT MAINTENANCE". LABELS ARE FIXED TO THE ELECTRIC FANS IN AN ACCESSIBLE LOCATION ON THE ROOFTOP.6. PRESSURE TECH PT-16 ELECTRIC FANS RUN ON DC POWER PROVIDED BY AN INVERTER.7. A VARMINT GUARD WAS INSTALLED ON THE TOP OF THE RISER PIPE AS SPECIFIED ON SHEET VM-2.D) MONITORING POINTS AND CLEAN-OUTS1. PERMANENT MONITORING POINTS CONSIST OF 1" SCH 40 PVC 0.020-INCH SLOTTED PIPE WITH AN OPEN END OR A VAPOR PIN SET WITHIN THECONCRETE SLAB INSTALLED PER THE DETAILS ON SHEET VM-2. A 2" EXPANDABLE WELL PLUG WAS INSTALLED ON THE PIPE WITHIN THE CLEAN-OUT.COARSE SAND (#2 GRAVEL PACK) OR SIMILAR HIGH PERMEABILITY SOIL OR STONE APPROVED BY THE DESIGN ENGINEER WAS PLACED AROUND THESLOTTED PORTION OF THE MONITORING POINT AND PLACED A MINIMUM OF 6" BELOW THE SLOTTED PIPE. A 4" DIA FLOOR CLEAN-OUT (ZURNINDUSTRIES MODEL #CO2450-PV4, OR SIMILAR) WAS INSTALLED FLUSH WITH THE NEW CONCRETE SURFACE.2. PERMANENT CLEAN-OUTS INSTALLED ON THE SUCTION TRENCHES CONSIST OF A 3" PVC ALL-HUB 2-WAY CLEAN-OUT INSTALLED ALONG THE VIMSPIPING. A 2" DIA SCH 40 PVC PIPE WAS INSTALLED TO THE CONCRETE WITH A 2" EXPANDABLE WELL PLUG INSTALLED ON THE CLEAN-OUT. A 4" DIAFLOOR CLEAN-OUT (ZURN INDUSTRIES MODEL #CO2450-PV4, OR SIMILAR) WAS INSTALLED FLUSH WITH THE NEW CONCRETE SURFACE.E) SYSTEM ALARMS AND TELEMETRIC MONITORING1. A SENVA P-4-2500-DB1XP DIFFERENTIAL PRESSURE SENSOR AND TRANSMITTER WAS INSTALLED AT EACH RISER PIPE AND CONNECTED TO ACENTRALIZED SENSAPHONE SENTINEL REMOTE MONITORING DEVICE. AS SHOWN ON SHEETS VM-1 AND VM-2. THE CENTRALIZED SENSAPHONESENTINEL DEVICE WAS INSTALLED IN A SUITABLE MONITORED LOCATION IDENTIFIED BY THE OWNER OR ARCHITECT. THE SENSAPHONE SENTINEL IS NOMORE THAN 200 FT FROM EACH DIFFERENTIAL PRESSURE SENSOR.2. ELECTRICAL CONDUIT WAS INSTALLED FOR THE LOW VOLTAGE WIRE FROM THE DIFFERENTIAL PRESSURE SENSORS AND SENSAPHONE SENTINELDEVICE.3. ALARMS WERE SET TO BE ACTIVATED WHEN VACUUM LEVELS IN THE RISER PIPE DROP BELOW 1.0 INCHES OF WATER COLUMN.F) SEALING OF JOINTS, CRACKS, AND OPENINGS IN THE SLAB1. FLOOR SLAB PENETRATIONS INCLUDING BUT NOT LIMITED TO EXPANSION JOINTS, CONTROL JOINTS, CONSTRUCTION JOINTS, ISOLATION JOINTS, OPENCRACKS IN THE CONCRETE SLAB, PLUMBING AND ELECTRICAL CONDUITS, VENTING SYSTEM PIPES, WERE SEALED USING URETHANE SEALANTACCORDING TO THE MANUFACTURER'S RECOMMENDATIONS, OR SIMILAR SEALANTS.2. NO HOLLOW FORMS OR OPEN CONDUITS WERE LEFT IN PLACE THAT CONNECT SUB-SLAB ANNULAR SPACE TO THE INTERIOR OF THE BUILDING.G) INSPECTIONS1. INSPECTIONS: INSPECTIONS OF EACH COMPONENT OF THE VIMS WERE CONDUCTED BY THE DESIGN ENGINEER, OR ENGINEER'S DESIGNEE, TOCONFIRM VIMS COMPONENTS ARE INSTALLED PER THE APPROVED DESIGN. THE REQUIRED INSPECTION COMPONENTS INCLUDED:1.1. INSPECTION OF SUB-SLAB PIPING LAYOUT AND GRAVEL, INCLUDING WITHIN SUCTION TRENCHES AND SUCTION POINTS1.2. INSPECTION OF MONITORING POINT PLACEMENT AND INSTALLATION;1.3. INSPECTION OF ABOVE-GRADE PIPING LAYOUT;1.4. INSPECTION OF ELECTRIC FANS AND RISER DUCT PIPE CONNECTIONS; AND1.5. INSPECTION OF DIFFERENTIAL PRESSURE SENSORS AND ALARM SYSTEM.H) SYSTEM OPERATION AND MAINTENANCE1. THE CONTRACTOR SHALL ARRANGE FOR THE DESIGN ENGINEER OR APPROVED CONTRACTOR TO CHECK THE OPERATION OF ALL VENTING SYSTEM FANOPERATION, ALARM OPERATION, AND VERIFICATION OF SUB-SURFACE VACUUM MEASUREMENTS BEFORE THE BUILDING IS OCCUPIED.2. THE OWNER, THROUGH CONTRACT WITH A PROFESSIONAL ENGINEER AS WARRANTED, SHALL BE RESPONSIBLE FOR THE ROUTINE OPERATION,INSPECTION, CALIBRATION, AND MONITORING OF THE VENTING SYSTEM ACCORDING TO MANUFACTURER RECOMMENDATIONS AND THE PROVISIONS ASDETAILED IN THE VAPOR INTRUSION MITIGATION PLAN INCLUDING:a. INSPECTION AND REPAIR OF SEALS IN THE SLAB, AND SEALING OF ANY NEW CRACKS OR OPENINGS IN THE SLAB THAT OCCUR FOR ANY REASON;b. NOTIFICATION TO TENANTS AND CONTRACTORS OF THE PRESENCE AND FUNCTION OF THE VIMS, AND TO INSTRUCT TENANTS AND CONTRACTSTO NOTIFY THE OWNER OF PROPOSED ACTIVITIES THAT DAMAGE OR COULD IMPACT THE VIMS;c. NOTIFICATION TO TENANTS AND CONTRACTORS OF THE DISCHARGE EXHAUST REQUIREMENTS; ANDd. IF THE SYSTEM MONITOR (SENSAPHONE SENTINEL) ALARM SOUNDS, IMPLEMENT ACTIONS AS OUTLINED IN THE VAPOR INTRUSION MITIGATIONPLAN FOR EVALUATION OF THE ALARM AND SUBSEQUENT REPAIRS.3. THE OWNER SHALL DESIGNATE A PERSON OR DEPARTMENT RESPONSIBLE FOR THE OPERATION, INSPECTION, MONITORING, AND AS NECESSARY,REPAIR OF THE VENTING SYSTEM AND COORDINATION WITH A NORTH CAROLINA PROFESSIONAL ENGINEER AS DESCRIBED IN THESE DRAWINGS ANDASSOCIATED VAPOR INTRUSION MITIGATION PLAN. THIS PERSON SHALL BE FAMILIAR WITH THESE DRAWINGS AND THE OPERATION OF THE FANS ANDMONITORING EQUIPMENT.PROFESSIONALAPPROVAL / SEALAS-BUILT DRAWINGAUGUST 3, 2023SOME SPECIFICATIONS AND NOTES IN THE AS-BUILTDRAWINGS MAY CONTAIN FUTURE TENSE STATEMENTS ANDREQUIREMENTS, BUT THE REQUIREMENTS, NOTES, ANDDETAILS HEREIN WERE COMPLETED IN GENERALACCORDANCE WITH THE DESIGN DRAWINGS AND DESIGNINTENT.AS-BUILT08/03/23\\harthick.sharepoint.com@SSL\DavWWWRoot\sites\MasterFiles-1\Shared Documents\AAA-Master Projects\PAMAKA - PAM\PAM-003 N. Davidson & E. 26th\VIMS\2315 N. Davidson VIMS\2315 N.Davidson_VIMS AS-Built_Office Space.dwg Attachment C VIMS Product Specifications Sheets PressureTech High Suction Radon Fans PressureTech is changing the game for the radon industry with the introduction of the most effective and energy efficient radon fan ever developed! For the first time ever, a residential radon fan is capable of achieving extraordinary levels of static pressure while operating quietly and efficiently. PressureTech will conquer radon problems under the most challenging conditions including clay soil, compacted sand, and even bedrock. PressureTech has revolutionized the radon fan industry by utilizing DC motor technology which can achieve much higher air flow and suction than typical radon fans. Until PressureTech, radon fans have been made using outdated and inefficient AC motor technology. The PressureTech radon fan is capable to producing over 5 times more static pressure than the leading radon fans and can do so using a fraction of the electricity! At the heart of the PressureTech fan is an ultra-efficient, computer-controlled direct current motor with integrated impeller system for years of trouble-free continuous operation. One of the biggest advantages of PressureTech fans over traditional radon fans is the low voltage motor. In fact, the voltage is so low that most jurisdictions do not require an electrical license or permits to wire the fan! IMPORTANT NOTICE: PressureTech PT Series Fans have low voltage DC motors and must be used with the included power converter when connected to standard voltage (110-120V AC). Connecting fan directly 110/120V power source without power converter will damage fan and void warranty. See wiring instructions on last page of this manual. PressureTech’s fans can be used for virtually any radon mitigation or vapor intrusion application, residential or commercial. The pressure adjustment dial allows you to adjust the flow of the system in conjunction with your diagnostic testing to achieve optimal negative pressure below the slab. With suction capabilities exceeding 10-inches of water column, there is no project that this fan can’t handle! PressureTech is excited to introduce the radon fan that will put an end to problem houses once and for all! So, don’t delay; try a PressureTech radon fan on your next installation and experience for yourself the future of the radon mitigation industry! The extraordinary thing about the PressureTech fan is that you don’t have to wait until you have a problem house to use it. Although it can handle those homes with difficult soil conditions, this fan is quiet and energy-efficient enough to use for your everyday installations. Using the PressureTech product gives the mitigator a clear advantage over their competitors. Not only does it have suction capabilities far beyond anything else on the market, but the motor actually runs on a low voltage current. What this means is that many of the expenses associated with the installation are eliminated. For example, most municipalities do not require a licensed electrician for low voltage wiring. Many of the permits and subsequent inspection fees are not necessary when using this fan. And, quite frankly, the fact that it is low voltage completely eliminates the risk of electrical hazards that are associated with wiring higher voltages. There are a lot of radon contractors out there who are walking a fine line by doing their own wiring of 110volt fans. In most states, this is simply illegal and puts both the homeowner and the installer at risk. This type of liability nightmare can be now be avoided thanks to the low voltage technology PressureTech is bringing to the table. The radon industry simply has never seen a product like this. There’s just nothing else like it on Earth! This product could change the game and make those “nightmare” mitigation jobs a thing of the past. Fan Model Volts Watts Maximum Pressure Maximum Airflow PressureTech PT8 24V (includes 110V converter) 58-80 8.6″ WC 50 CFM PressureTech PT16 36V (includes 110V converter) 110-170 17.4″ WC 67 CFM PressureTech P25 48V (includes 110V converter) 255-298 25.2″ WC 82 CFM PressureTech PT8 With PressureTech’s introduction of the PT8 Radon Fan, the radon industry has finally turned the corner into modern-day technology! The PT8 was designed with two things in mind: unmatched performance and unmatched energy efficiency. Thanks to recent developments in DC motor technology, PressureTech has been able to create an in-line fan that is capable of achieving OVER 8 INCHES OF SUCTION while using only 60 watts of power! The motor is also low voltage, so wiring the fan doesn’t require a licensed electrician or permit in most jurisdictions. The PT8 is ultra-quiet, efficient, and extremely effective at more than doubling the pressure field extension (PFE) you achieve below the slab, compared to the other “high suction” radon fans that are on the market. PressureTech PT16 & PT25 PressureTech has taken “high suction” to another level by introducing the PT16 and PT25 radon mitigation / vapor intrusion fans. With static pressure capabilities up to 25 inches of water column, this compact in-line fan outperforms loud, bulky box fans that are commonly used for commercial radon mitigation and vapor intrusion projects. The PT Series has many advantages over other fans thanks to the revolutionary DC motor technology that PressureTech has introduced. Direct Current (DC) motors are capable of much higher speeds and run more efficiently than traditional fan motors. The result is higher suction, higher airflow, and lower electrical consumption. By using less electricity, these fans save your clients money in operating costs and will outlast traditional motors that tend to burn out much sooner due to excessive heat. Because of lower electrical consumption than Alternating Current (AC) motors, DC motors run at much lower temperatures which extends the running life up to 5 times longer. PressureTech PT Series Radon / Vapor Fan Installation and Operating Instructions Installation Instructions 1. After interior portion of radon system piping is installed and routed to the outdoor wall of the building, the radon fan must be installed in-line with the piping. NOTE: Always install the fan in an upright position to avoid moisture accumulation in the housing. 2. Using an appropriate rubber connector or pipe reducer coupling, securely connect the inlet portion of the fan to the vertical riser of the outdoor piping. Tighten the metal clamps on the both side of the connector to ensure that fan is adequately secured to the pipe. 3. Build the exhaust stack which will be installed on the outlet of the fan. 4. Attach the exhaust stack to the outlet of the fan using an appropriate rubber connector or pipe reducer coupling. Attach the exhaust stack to the exterior of the building so it is securely held by pipe clamps to avoid excess weight/stress being applied to the fan. 5. Install the power converter in appropriate location. Do not connect power to the power converter until the fan is completely wired. 6. Remove the cap from the fan electrical box. 7. Connect the wires from the power converter to the wire terminals in fan electrical box using appropriate connectors. NOTE: Outdoor wiring should be enclosed in outdoor rated conduit. 8. Once all wire connections are secure in the fan electrical box, connect the power converter to the power source and check to make sure the fan is running. 9. Once confirmed that the fan is running, check all connections and electrical cover to ensure that the installation is secure. 10. Activation and troubleshooting: If fan is not running, check any disconnect switches to make sure they are in the ON position. If the fan does not activate from a power switch, check the wiring inside of the fan electrical box to make sure no connections were broken or wired improperly. Also, check the circuit breaker for the outlet that system is plugged into to confirm that it hasn’t tripped. Operating Instructions PressureTech PT Series radon / vapor fans are intended to run continuously to maintain healthy air within the building. Once the radon system is installed and fan is activated, power should never be disconnected except to service or replace the fan. Power Converter The PressureTech PT Series radon / vapor fans have low voltage DC motors, so a power converter must be installed to convert the 110V power source to a low voltage current. The power converter can be wired anywhere between the fan and power source and is rated for both indoor and outdoor applications. Simply connect the positive (red) and negative (black) DC wires to the fan. Then, connect the hot (black), neutral (white) and ground (green) wires to your 110V power source or utilize flexible plugged cord to plug into an outlet when located within 6-feet of the power supply location. Sentinel ALARM NOTIFICATION METHODS: E-Mail, Text Messages, Voice Phone Calls Programmable alarm escalation levels Comprehensive scheduling per input, profile, and alarm destination Unlimited number of User Profiles Multiple contact types per user INPUTS: 12 Universal Inputs • Normally Open / Normally Closed Dry Contact • 2.8K / 10K Thermistor • 4-20mA Current Loop • Pulse Count • 12 Bit Resolution TEMPERATURE SENSING RANGE: -109° to 168°F | -85° to 76°C RELAY OUTPUT: Programmable. Rated for 1A 30VAC/ 1A 30VDC DATA LOGGING: Unlimited samples securely stored on the Sentinel servers Programmable sampling interval - 1 min to 24 hrs User programmable channel selection COMMUNICATION PORTS: Ethernet 10/100Base–T STANDARDS: FCC Part 15 – Class A Compliant BATTERY BACKUP: 4.8V 2000mAHr NiMh Battery pack (included) Provides 8 hours of backup LOCAL INDICATORS: 12 Alarm Status LEDs • Power LED • Online LED • Standby LED • Ethernet link and Activity LEDs POWER REQUIREMENTS: Comes with 12VDC plug-in power supply. (International power options available). ENVIRONMENTAL: Operating Humidity: 0-90% RH, non–condensing Operating Temperature: 32° to 122°F | 0° to 50°C PHYSICAL: In metal enclosure: 5.5 x 5.5 x 1.5” | 140 x 140 x 38mm 1 lb. | .45kg With Weatherproof Enclosure: 12.17 x 10.25 x 3.5” | 309 x 260 x 89mm 3.7 lb. | 1.67 kg ENCLOSURE: Durable powder coated metal housing suitable for wall or panel installation or weatherproof NEMA 4X rated fiberglass enclosure. Technical Specifi cations 901 Tryens Road • Aston, PA 19014 • PH: 877-373-2700 • F: 610-558-0222 • www.sensaphone.com Separation Page Intentionally Left Blank P4 Value Series P4 Value Dry Pressure Range: 0.1 to 25" W.C. 0-5VDC/10VDC or 4-20 mA loop &3-wire powered versions LCD option & LED status indication Remote & manual zero function PATENT PENDING DESCRIPTION The P4 dry media pressure transmitter features fixed ranges optimized for building (zone) pressure, filter measurement, and static duct applications. Innovative static probe integrates with unit or can be mounted remotely for static pressure. PATENT PENDING. APPLICATIONS Building (zone) pressure• Filter condition measurement• Duct/static• OEM HVAC• Innovative probe transforms for duct or remote applications High density DIN mounting saves valuable panel space Conduit ready FEATURES Duct, filter, and room pressure with a single unit with RP-6 probe addition • LCD option for set-up and reference• Non-position sensitive for easy placement accuracy• 0-5VDC/10VDC or 4-20 mA loop or 3-wire powered versions• DIN mount flat or side to conserve panel space• Conduit cover for 3/8” flex connectors...no extra parts required• LED: Power heartbeat, auto-zero complete, 110% over pressure; facilitates locating sensor in ductwork • Higher Reliability, Faster Installation, Superior Accuracy | Sense the Difference 866-660-8864 | fax 503-296-2529 | www.senvainc.com 1A 10/7/2022 1 ORDERING DIMENSIONS Higher Reliability, Faster Installation, Superior Accuracy | Sense the Difference 866-660-8864 | fax 503-296-2529 | www.senvainc.com 1A 10/7/2022 2 SPECIFICATIONS Power Supply 12-30VDC/24VAC(1), 30mA max Output type Outputs Available 4-20mA loop powered, 4-20 mA 3-wire, 0-5VDC, 0-10VDC Fixed Ranges Multiple Fixed Ranges (Inches of w.c. and Pascals)0.1”w.c. up to 25”w.c. models 1250 Pa up to 6250 Pa models Operating Temperature Operating range -4 to 140F (-20 to 60ºC) Compensated range -4 to 140F (-20 to 60ºC) Media compatibility Dry, oil-free air, N2 Sensor Type MEMS silicon piezoresistive; precision calibrated Sensor Performance Accuracy 1.00%±1.00% of range Accuracy 0.25%(2)±0.25% of range; 7-point NIST calibrated Accuracy 0.50%(2)±0.50% of range; 7-point NIST calibrated Zero Tolerance Included in accuracy specification Span Tolerance ±1.00% Zero Drift (1 year) Auto-zero input 0.004”WC/year max. 0.4% for units >0.5”w.c. Push-button and contact closure Thermal Shift (Zero and Span)0.02% FSO/ºC (0.01%FSO/ºF) measured from 22ºC (72ºF Overpressure up to 5” models: 41.5”w.c.; 10” models: 133”w.c.; 25” models: 332”w.c. Max Static Line Pressure up to 5” models: 41.5”w.c.; 10” models: 133”w.c.; 25” models: 332”w.c. Burst Pressure up to 5” models: 83”w.c.; 10” models: 166”w.c.; 25” models: 415”w.c. Position Sensitivity Non-position sensitive Agency Compliance CE, RoHS Enclosure Flammability UL94 5VB Environmental NEMA 1 * Product improvement is a continual process as Senva and product features and specification may change without prior notice. Refer to instructions that accompany the product for installation and wiring. Higher Reliability, Faster Installation, Superior Accuracy | Sense the Difference 866-660-8864 | fax 503-296-2529 | www.senvainc.com 1A 10/7/2022 3 Separation Page Intentionally Left Blank Separation Page Intentionally Left Blank PRODUCT PART # VAPORBLOCK 10 ........................................................................... VB10 VAPORBLOCK 15 ........................................................................... VB15 Vapor Barrier - Commercial APPLICATIONS • Underslab Vapor Retarder/Barrier • Foundation Wall Vapor Retarder • Radon Retarder HIGH PERFORMANCE UNDERSLAB VAPOR BARRIER © 2018 RAVEN INDUSTRIES INC. All rights reserved. PRODUCT DESCRIPTION VaporBlock® is a high performance underslab vapor barrier designed to retard moisture migration through concrete slabs and concrete walls to protect your structure from: • MOLD: VaporBlock® reduces moisture condensation within a structure, impeding the growth of molds, mildews, and fungi. • MOISTURE: VaporBlock® protects flooring materials by maintaining moisture levels well below the requirements of ASTM E-1745-11. • RADON: VaporBlock® is used as a component of radon mitigation systems to protect indoor air quality and occupant health. Raven also offers VaporBlock® Plus™, a highly effective gas and moisture barrier. VaporBlock® is one of the most effective underslab vapor barriers on the market today! Benefits include: • Ultra-low moisture vapor permeability • Superior puncture resistance • High tensile tear strength • Resistance to decay and degradation VaporBlock® is manufactured to strict conformance specifications under our ISO 9001 Certified Management System to consistently exceed ASTM standards and project expectations. Raven's accredited lab ensures VaporBlock® meets the highest possible quality standards across multiple industries. VaporBlock® is supported with independent testing. Results are available upon request, as required under ASTM E-1745-11. VaporBlock® is readily available through nation-wide distribution: • Available in 10 and 15 mil for optimal project flexibility • Larger roll sizes equal lower installation costs Raven Industries manufactures VaporBlock® and controls all aspects from start to finish assuring the final product meets our high performance standards. Raven is a publicly-traded company, with over 60 years of stability and service excellence to stand behind our products with a future of innovation and growth. Note: All instructions on architectural or structural drawings should be reviewed and followed. Detailed installation instructions accompany each roll of VaporBlock and can also be located on our website. ASTM E-1643 also provides general installation information for vapor retarders. All VaporBlock series materials can be installed with print or color facing up or down and will provide the same performance. ASTM E-1745-11, "Plastic Water Vapor Retarders Used in Contact with Soil or Granular Fill Under Concrete Slabs". VAPORBLOCK®VB10 & VB15 HIGH PERFORMANCE UNDERSLAB VAPOR BARRIER PRO-FORMA DATA SHEETFOR VAPORBLOCK® VB15** VAPORBLOCK VB10 VAPORBLOCKVB15**ASTM E 1745-11Class A, B & C1 PROPERTIES TEST METHOD IMPERIAL IMPERIAL IMPERIAL AppeArAnce Blue Blue - Thickness, nominAl 10 mil 15 mil - roll size 15 ft x 200 ft 12 ft x 200 ft - WeighT 49 lbs/MSF 73 lbs/MSF - clAssificATion ASTM E1745-11 CLASS A, B, & C CLASS A, B, & C Class A, B, or C Tensile sTrengThAverAge mD & TD(neW mATeriAl) (AfTer exposure) ASTM E154Section 9, (D882)52 lbs/in 53 lbs/in 60 lbs/in 61 lbs/in Class A = 45 lbs/in Class B = 30 lbs/in Class C = 13.6 lbs/in Minimum puncTure resisTAnce ASTM D1709Method B 2600 g 3000 g Class A = 2200 g Class B = 1700 g Class C = 475 g Minimum permeAnce(neW mATeriAl) (AfTer conDiTioning) ASTM E154 Section 7 ASTM E96 Procedure B ASTM E154 Section 8, E96 Section 11, E96 Section 12, E96 Section 13, E96 0.0146 Perms grains/(ft²•hr•in Hg) 0.0153 0.0151 0.0160 0.0181 0.01 Perms grains/(ft²•hr•in Hg) 0.01 0.01 0.01 0.01 Class A, B, & C 0.1 Permsgrains/(ft²•hr•in Hg) Maximum WVTR ASTM E96Procedure B 0.0084grain/hr-ft²0.004grain/hr-ft²- mAximum sTATic use Temp 180° F 180° F - minimum sTATic use Temp -70° F -70° F - VaporBlock® is a high performance underslab vapor barrier designed to retard moisture migration through concrete slabs and concrete walls. 1 Referencing ASTM E1745-11, Standard Specification for Plastic Water Vapor Retarders Used in Contact with Soil or Granular Fill under Concrete Slabs © 2018 RAVEN INDUSTRIES INC. All rights reserved. Note: To the best of our knowledge, unless otherwise stated, these are typical property values and are intended as guides only, not as specification limits. Chemical resistance, odor transmission, longevity as well as other performance criteria is not implied or given and actual testing must be performed for applicability in specific applications and/or conditions. RAVEN INDUSTRIES MAKES NO WARRANTIES AS TO THE FITNESS FOR A SPECIFIC USE OR MERCHANTABILITY OF PRODUCTS REFERRED TO, no guarantee of satisfactory results from reliance upon contained information or recommendations and disclaims all liability for resulting loss or damage. Limited Warranty available at www.RavenEFD.com 092818 EFD 1092 RAVEN ENGINEERED FILMSP.O. Box 5107 Sioux Falls, SD 57117-5107Ph: +1 (605) 335-0174 • TF: +1 (800) 635-3456 efdsales@ravenind.comwww.ravenefd.com VAPORBLOCK®VB10 & VB15 **PROFORMA Contents: Data listed for VaporBlock® VB15, under ASTM E154, section 11, 12, and 13, is extrapolated from actual section 8 values and is subject to change at any time as additonal test data becomes available. Scan QR Code to download current technical data sheets via the Raven website. P1 OF 2 STEGO® WRAP 15-MIL VAPOR BARRIER A STEGO INDUSTRIES, LLC INNOVATION | VAPOR RETARDERS 07 26 00, 03 30 00 | VERSION: DEC 10, 2018 Continued... Note – legal notice on page 2. 1. PRODUCT NAME STEGO WRAP 15-MIL VAPOR BARRIER 2. MANUFACTURER Stego Industries, LLC 216 Avenida Fabricante, Suite 101 San Clemente, CA 92672 Sales, Technical Assistance Ph: (877) 464-7834 contact@stegoindustries.com www.stegoindustries.com 3. PRODUCT DESCRIPTION USES: Stego Wrap 15-Mil Vapor Barrier is used as a below-slab vapor barrier. COMPOSITION: Stego Wrap 15-Mil Vapor Barrier is a multi-layer plastic extrusion manufactured with only high grade prime, virgin, polyolefin resins. ENVIRONMENTAL FACTORS: Stego Wrap 15-Mil Vapor Barrier can be used in systems for the control of soil gases (radon, methane), soil poisons (oil by-products) and sulfates. 4. TECHNICAL DATA TABLE 1: PHYSICAL PROPERTIES OF STEGO WRAP 15-MIL VAPOR BARRIER PROPERTY TEST RESULTS Under Slab Vapor Retarders ASTM E1745 Class A, B & C– Standard Specification for Water Vapor Retarders Used in Contact with Soil or Granular Fill under Concrete Slabs Exceeds Class A, B & C Water Vapor Permeance ASTM F1249 – Test Method for Water Vapor Transmission Rate Through Plastic Film and Sheeting Using a Modulated Infrared Sensor 0.0086 perms Permeance After Conditioning ASTM E154 Section 8, F1249 – Permeance after wetting, drying, and soaking 0.0098 perms (ASTM E1745 ASTM E154 Section 11, F1249 – Permeance after heat conditioning 0.0091 perms Sections 7.1.2 - 7.1.5) ASTM E154 Section 12, F1249 – Permeance after low temperature conditioning 0.0097 perms ASTM E154 Section 13, F1249 – Permeance after soil organism exposure 0.0095 perms Methane Transmission Rate ASTM D1434 – Standard Test Method for Determining Gas Permeability 192.8 GTR* Characteristics of Plastic Film and Sheeting (mL(STP)/m2*day) Radon Diffusion Coefficient K124/02/95 8.8 x 10-12 m2/second Puncture Resistance ASTM D1709 – Test Method for Impact Resistance of Plastic Film by Free-Falling Dart Method 2,266 grams Tensile Strength ASTM D882 – Test Method for Tensile Properties of Thin Plastic Sheeting 70.6 lbf/in Thickness 15 mil Roll Dimensions width x length: 14' x 140' area: 1,960 ft2 Roll Weight 140 lb Note: perm unit = grains/(ft2*hr*in-Hg) *GTR = Gas Transmission Rate STEGO® WRAP 15-MIL VAPOR BARRIER A STEGO INDUSTRIES, LLC INNOVATION | VAPOR RETARDERS 07 26 00, 03 30 00 | VERSION: DEC 10, 2018 DATA SHEETS ARE SUBJECT TO CHANGE. FOR MOST CURRENT VERSION, VISIT WWW.STEGOINDUSTRIES.COM (877) 464-7834 | www.stegoindustries.com P2 OF 2 5. INSTALLATION UNDER SLAB: Unroll Stego Wrap 15-Mil Vapor Barrier over an aggregate, sand or tamped earth base. Overlap all seams a minimum of 6 inches and tape using Stego® Tape or Stego® Crete Claw® Tape. All penetrations must be sealed using a combination of Stego Wrap and Stego Accessories. For additional information, please refer to Stego’s complete installation instructions. 6. AVAILABILITY & COST Stego Wrap 15-Mil Vapor Barrier is available through our network of building supply distributors. For current cost information, contact your local Stego distributor or Stego Industries’ Sales Representative. 7. WARRANTY Stego Industries, LLC believes to the best of its knowledge, that specifications and recommendations herein are accurate and reliable. However, since site conditions are not within its control, Stego Industries does not guarantee results from the use of the information provided herein. Stego Industries, LLC does offer a limited warranty on Stego Wrap. Please see www.stegoindustries.com/legal. 8. MAINTENANCE None required. 9. TECHNICAL SERVICES Technical advice, custom CAD drawings, and additional information can be obtained by contacting Stego Industries or by visiting the website. Email: contact@stegoindustries.com Contact Number: (877) 464-7834 Website: www.stegoindustries.com 10. FILING SYSTEMS • www.stegoindustries.com Stego, the stegosaurus design logo[s], Crete Claw, StegoTack, StegoCrawl, Beast, and the Beast design logo are all deemed to be registered and/or protect-able trademarks or service marks of Stego Industries, LLC. © 2018 Stego Industries, LLC. All Rights Reserved. Please see www.stegoindustries.com/legal. Attachment D Photographic Log Photograph Nos. 1 through 4: General view of the ventilation piping runs for F-9 through F-11.PAM-0032923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) OFFICE SPACE2315 NORTH DAVIDSON STREETCHARLOTTE, NORTH CAROLINA Photograph Nos. 5 through 8: General view of the 15-mil Stego Wrap vapor barrier with Drago-Tack tape for adhesion to concrete surfaces.PAM-0032923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) OFFICE SPACE2315 NORTH DAVIDSON STREETCHARLOTTE, NORTH CAROLINA Photograph No. 11: View of suction piping installed through the roof of the Office Space. PAM-0032923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph Nos. 9 & 10 : Representative view of final monitoring point installation with floor cleanout (Photo 9) and Vapor Pin (Photo 10). OFFICE SPACE2315 NORTH DAVIDSON STREETCHARLOTTE, NORTH CAROLINA Photograph Nos. 14 & 15: View of the Sensaphone Sentinel Remote monitoring system located within the UDM Food Hall. PAM-0032923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph Nos. 12 & 13 : Representative view of PT-16 fans and Senva alarm control boxes located on the roof of the building. OFFICE SPACE2315 NORTH DAVIDSON STREETCHARLOTTE, NORTH CAROLINA Attachment E Field Sampling Forms and Documents Table E-1North Davidson II Brownfields PropertyVIMS Pilot Test and Vacuum Monitoring 2315 North Davidson Street Charlotte, North Carolina Office Space Brownfields Project No. 24003-02-060 H&H Job No. PAM.003 8/2/2023 Baseline 30 Minute Reading All Fans Operating F‐9 0.000 2.081 ‐‐ F‐10 0.000 6.087 ‐‐ F‐11 0.000 2.257 ‐‐ MP‐12 0.000 0.376 0.383 MP‐13 0.000 0.617 1.052 MP‐14 0.000 0.075 0.072 MP‐15 0.000 0.121 0.158 *Pressuretech PT‐16 Fans installed on extraction risers in‐WC = inches of water column F‐9 = Extraction Fan MP‐12 = Monitoring Point Positive number for vacuum indicates vacuum present at fan and sub‐slab monitoring point. ‐‐ = not measured Vacuum Measurements  (in‐WC) Monitoring Point /  Extraction Fan ID 06/07/2023 Pilot Test https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/2315 N. Davidson VIMS/Install - Office Space/Pilot Test8/2/2023 Table E‐1 Hart & Hickman, PC PAM-003 JAB 70's, Sunny IAS-OFF-1 8:50 -29 0.00 71 80 78 606L468506/15/23 8 13:26 -17 0.00 85 46 79 63 13129 21 ml/min 16:50 -6 0.00 85 45 79 64 IAS-OFF-DUP 8:50 -29 0.00 71 80 78 606L37244 6/15/23 8 13:26 -17 0.00 85 46 79 63 13129 21 ml/min 16:50 -6 0.00 85 45 79 64 IAS-OFF-2 09:05 -29 0.00 71 80 77 666L42651 6/15/23 8 13:28 -17 0.00 85 46 77 63 17725 10.3 ml/min 17:05 -6 0.00 85 45 79 60 IAS-OFF-BKG 09:00 -29 -- 71 80 -- --6L37271 6/15/23 8 13:24 -17 -- 85 46 -- -- 6574 10.4 ml/min 17:00 -6 -- 85 45 -- -- 09:00 13:30 17:00 0 0 0 29.01 29.00 28.95 SW SW SSW 4 7 8 INDOOR AIR BUILDING SURVEY and SAMPLING FORM Site Name: ____________________________________ Preparer’s name: ________________________________ Preparer’s affiliation: ____________________________ #: ______________________ Date: __________________________ Phone #: _______________________ Part I - Occupants Building Address: ____________________________________________________________________ Property Contact: _______________________________ Owner / Renter / other: ______________ Contact’s Phone: home ( )__________ work ( )______________ cell ( )____________ # of Building occupants: Children under age 13 _____ Children age 13-18 ______ Adults _____ Part II – Building Characteristics Building type: Describe building: ________________________________________ Year constructed: _________ Sensitive population:(specify): _______________ Number of floors below grade: ______ Number of floors at or above grade: ______ Depth of basement below grade surface: ______ ft. Basement size: _______ ft 2 Basement floor construction: Foundation walls: Basement sump present?Sump pump? ther (specify): ________________ other (specify)_______________ Water in sump? Type of heating system (c all that apply): hot air circulation hot air radiation wood steam radiation heat pump hot water radiation kerosene heater electric baseboard other (specify): ________________________ Type of ventilation system (c all that apply): bathroom ventilation fans outside air intake central air conditioning mechanical fans individual air conditioning units kitchen range hood fan other (specify): _________________ Type of fuel utilized (c all that apply): Natural gas electric fuel oil wood coal solar kerosene Are the basement walls or floor sealed with waterproof paint or epoxy coatings? Mill District Partners LLC other (specify) _____________ Is there a whole house fan? Septic system? Irrigation/private well? Type of ground cover outside of building: Existing subsurface depressurization (radon) system in place? Sub-slab vapor/moisture barrier in place? Type of barrier: ____________________________ Part III - Outside Contaminant Sources Other stationary sources nearby (gas stations, emission stacks, etc.): _____________________________ Heavy vehicular traffic nearby (or other mobile sources): ______________________________________ Part IV – Indoor Contaminant Sources Identify all potential indoor sources found in the building (including attached garages), the location of the source (floor and room), and whether the item was removed from the building 48 hours prior to indoor air sampling event. Any ventilation implemented after removal of the items should be completed at least 24 hours prior to the commencement of the indoor air sampling event. Potential Sources Location(s)Removed (Yes / No / NA) Gasoline storage cans Gas-powered equipment Kerosene storage cans Paints / thinners / strippers Cleaning solvents Oven cleaners Carpet / upholstery cleaners Other house cleaning products Moth balls Polishes / waxes Insecticides Furniture / floor polish Nail polish / polish remover Hairspray Cologne / perfume Air fresheners Fuel tank (inside building) Wood stove or fireplace New furniture / upholstery New carpeting / flooring Hobbies - glues, paints, etc. Part V – Miscellaneous Items Do any occupants of the building smoke?How often? ______________ Last time someone smoked in the building? ____________ hours days ago Does the building have an attached garage directly connected to living space? If so, is a car usually parked in the garage? Are gas-powered equipment or cans of gasoline/fuels stored in the garage? Do the occupants of the building have their clothes dry cleaned? If yes, how often? Do any of the occupants use solvents in work? If yes, what types of solvents are used? _______________________________________ If yes, are their clothes washed at work? If so, when and which chemicals? _________________________________________________ Has there ever been a fire in the building?If yes, when? _____________ Has painting or staining been done in the building in the last 6 months? Yes No If yes, when __________________ and where? ____________________________ Part VI – Sampling Information Sample Technician: ____________________________ Phone number:) _______ - __________ Sample Source Sampler Type Other (specify): _________________ Analytical Method:ther: _____________ Cert. Laboratory: Sample locations (floor, room): Field ID # _____ - ________________________ Field ID # _____-__________________________ Field ID # Were “Instructions for Occupants” followed? Provide Drawing of Sample Location(s) in Building Part VII - Meteorological Conditions Was there significant precipitation within 12 hours prior to (or during) the sampling event?Yes No Describe the general weather conditions: _________________________________________________ _____________________________________________________________________________________ Part VIII – General Observations Provide any information that may be pertinent to the sampling event and may assist in the data interpretation process (e.g., observed that drycleaner operated with door or windows propped open for ventilation). (Adapted from the NJDEP Vapor Intrusion Guidance, October 2005) F-9 F-10F-11 MP-13 MP-12 MP-14 MP-15 -11 MMP MP P-1 -13 F-9 FF-11 F-110 MPP-1 MP-15 9AVM-2 SUB-SLAB SAMPLELOCATION IAS- IAS- PAM-003 JAB 70's, Sunny MP-15 11361 SS Perm Conc 6 Silt na Full 6/16/23 10:45 77 Pump 8 10.8 0 Yes 6573 PAM-003 JAB 80's, Sunny MP-15 1.4L11361 6/16/23 10 108 ml/Min 10:54 -17 82 54 63 6573 11:00 -5 10:48 -28 79 Attachment F Site-Specific Indoor Air Sampling VOC List and Laboratory Analytical Reports Table F-1Site-Specific Indoor Air Sampling VOC List North Davdison II 2315 N. Davidson Street and 421 E. 26th Street Charlotte, North Carolina H&H Job No. PAM.003 1 Acetone 2 Benzene 3 2-Butanone (MEK) 4 Carbon Disulfide 5 Carbon Tetrachloride 6 Chloroform 7 Chloromethane 8 Cyclohexane 9 1,2-Dichlorobenzene 10 1,4-Dichlorobenzene 11 Dichlorodifluoromethane (Freon 12) 12 cis-1,2-Dichloroethylene 13 Ethanol 14 Ethylbenzene 15 4-Ethyltoluene 16 Heptane 17 Hexane 18 2-Hexanone (MBK) 19 Isopropanol 20 Methylene Chloride 21 4-Methyl-2-pentanone (MIBK) 22 Naphthalene 23 Propene 24 Styrene 25 Tetrachloroethene 26 Tetrahydrofuran 27 Toluene 28 Trichloroethene 29 Trichlorofluoromethane (Freon 11) 30 1,2,4-Trimethylbenzene 31 1,3,5-Trimethylbenzene 32 m&p-Xylene 33 o-Xylene VOC = volatile organic compound Select VOCs by EPA Method TO-15 S:\AAA-Master Projects\PAMAKA - PAM\PAM-003 N. Davidson & E. 26th\VIMS\VIMP\Attachment G - Select VOC TO-15 List12/22/2020 Table F-1 (Page 1 of 1) Hart & Hickman, PC   Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.   6/21/2023 Hart & Hickman (Charlotte) Dave Kahn 2923 South Tryon St. Ste 100 Charlotte, NC, 28203 Ref: Analytical Testing Lab Report Number: 23-167-0023 Client Project Description: PAM-003 Dear Dave Kahn: Waypoint Analytical, LLC (Charlotte) received sample(s) on 6/16/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Angela D Overcash Senior Project Manager Page 1 of 26 Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date 07/31/202337735State ProgramNorth Carolina 12/31/2023402State ProgramNorth Carolina 07/31/202399012State ProgramSouth Carolina 12/31/202299012State ProgramSouth Carolina Page 1 of 1 00016/23-167-0023 Page 2 of 26 Report Number: Sample Summary Table Client Project Description: 23-167-0023 PAM-003 Lab No Client Sample ID Matrix Date Collected Date Received 06/15/2023 08:50Air 98662 IAS-OFF-1 06/16/2023 13:12 06/15/2023Air 98663 IAS-OFF-DUP 06/16/2023 13:12 06/15/2023 09:05Air 98664 IAS-OFF-2 06/16/2023 13:12 06/15/2023 09:00Air 98665 IAS-OFF-BKG 06/16/2023 13:12 06/16/2023 10:48Air 98666 MP-15 06/16/2023 13:12 Page 3 of 26 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-167-0023 Report Limit Project:PAM-003 V 98662IAS-OFF-1 40.9 06/19/2023 20:27TO-15 Acetone µg/m3 0.202 J0.635 06/19/2023 20:27TO-15 Benzene µg/m3 0.073 J0.591 06/19/2023 20:27TO-15 Carbon Disulfide µg/m3 0.060 J0.881 06/19/2023 20:27TO-15 Chloromethane µg/m3 0.067 2.97 06/19/2023 20:27TO-15 Dichlorodifluoromethane µg/m3 0.134 19.6 06/19/2023 20:27TO-15 Ethanol µg/m3 0.169 J1.50 06/19/2023 20:27TO-15 Ethylbenzene µg/m3 0.106 J0.363 06/19/2023 20:27TO-15 4-Ethyltoluene µg/m3 0.128 J0.749 06/19/2023 20:27TO-15 Heptane µg/m3 0.143 4.42 06/19/2023 20:27TO-15 n-Hexane µg/m3 0.047 JB2.64 06/19/2023 20:27TO-15 Isopropyl Alcohol µg/m3 0.139 17.0 06/19/2023 20:27TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J0.996 06/19/2023 20:27TO-15 Methylene Chloride µg/m3 0.488 4.32 06/19/2023 20:27TO-15 Styrene µg/m3 0.124 2.71 06/19/2023 20:27TO-15 Tetrahydrofuran µg/m3 0.107 7.20 06/19/2023 20:27TO-15 Toluene µg/m3 0.090 J1.71 06/19/2023 20:27TO-15 Trichlorofluoromethane µg/m3 0.130 3.70 06/19/2023 20:27TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J0.496 06/19/2023 20:27TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 J1.65 06/19/2023 20:27TO-15 o-Xylene µg/m3 0.157 6.65 06/19/2023 20:27TO-15 m,p-Xylene µg/m3 0.217 V 98663IAS-OFF-DUP 37.8 06/19/2023 21:16TO-15 Acetone µg/m3 0.202 J0.664 06/19/2023 21:16TO-15 Benzene µg/m3 0.073 J0.442 06/19/2023 21:16TO-15 Carbon Disulfide µg/m3 0.060 J0.912 06/19/2023 21:16TO-15 Chloromethane µg/m3 0.067 2.93 06/19/2023 21:16TO-15 Dichlorodifluoromethane µg/m3 0.134 18.0 06/19/2023 21:16TO-15 Ethanol µg/m3 0.169 J1.45 06/19/2023 21:16TO-15 Ethylbenzene µg/m3 0.106 J0.388 06/19/2023 21:16TO-15 4-Ethyltoluene µg/m3 0.128 J0.790 06/19/2023 21:16TO-15 Heptane µg/m3 0.143 4.32 06/19/2023 21:16TO-15 n-Hexane µg/m3 0.047 JB2.29 06/19/2023 21:16TO-15 Isopropyl Alcohol µg/m3 0.139 16.3 06/19/2023 21:16TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J0.906 06/19/2023 21:16TO-15 Methylene Chloride µg/m3 0.488 5.08 06/19/2023 21:16TO-15 Naphthalene µg/m3 0.183 Page 4 of 26 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-167-0023 Report Limit Project:PAM-003 V 98663IAS-OFF-DUP 4.56 06/19/2023 21:16TO-15 Styrene µg/m3 0.124 2.60 06/19/2023 21:16TO-15 Tetrahydrofuran µg/m3 0.107 7.07 06/19/2023 21:16TO-15 Toluene µg/m3 0.090 J1.71 06/19/2023 21:16TO-15 Trichlorofluoromethane µg/m3 0.130 3.80 06/19/2023 21:16TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J0.614 06/19/2023 21:16TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 J1.68 06/19/2023 21:16TO-15 o-Xylene µg/m3 0.157 6.66 06/19/2023 21:16TO-15 m,p-Xylene µg/m3 0.217 V 98664IAS-OFF-2 26.5 06/19/2023 22:07TO-15 Acetone µg/m3 0.202 J0.731 06/19/2023 22:07TO-15 Benzene µg/m3 0.073 J0.460 06/19/2023 22:07TO-15 Carbon Disulfide µg/m3 0.060 J0.892 06/19/2023 22:07TO-15 Chloromethane µg/m3 0.067 3.09 06/19/2023 22:07TO-15 Dichlorodifluoromethane µg/m3 0.134 15.9 06/19/2023 22:07TO-15 Ethanol µg/m3 0.169 J0.933 06/19/2023 22:07TO-15 Ethylbenzene µg/m3 0.106 J0.725 06/19/2023 22:07TO-15 Heptane µg/m3 0.143 1.88 06/19/2023 22:07TO-15 n-Hexane µg/m3 0.047 J0.532 06/19/2023 22:07TO-15 2-Hexanone µg/m3 0.285 JB2.33 06/19/2023 22:07TO-15 Isopropyl Alcohol µg/m3 0.139 10.4 06/19/2023 22:07TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 1.98 06/19/2023 22:07TO-15 Methylene Chloride µg/m3 0.488 3.31 06/19/2023 22:07TO-15 Styrene µg/m3 0.124 J1.42 06/19/2023 22:07TO-15 Tetrahydrofuran µg/m3 0.107 4.99 06/19/2023 22:07TO-15 Toluene µg/m3 0.090 J1.78 06/19/2023 22:07TO-15 Trichlorofluoromethane µg/m3 0.130 3.24 06/19/2023 22:07TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J1.18 06/19/2023 22:07TO-15 o-Xylene µg/m3 0.157 J5.45 06/19/2023 22:07TO-15 m,p-Xylene µg/m3 0.217 V 98665IAS-OFF-BKG 19.3 06/19/2023 22:59TO-15 Acetone µg/m3 0.202 J0.645 06/19/2023 22:59TO-15 Benzene µg/m3 0.073 J0.392 06/19/2023 22:59TO-15 Carbon Disulfide µg/m3 0.060 3.01 06/19/2023 22:59TO-15 Dichlorodifluoromethane µg/m3 0.134 7.72 06/19/2023 22:59TO-15 Ethanol µg/m3 0.169 J1.34 06/19/2023 22:59TO-15 n-Hexane µg/m3 0.047 Page 5 of 26 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-167-0023 Report Limit Project:PAM-003 V 98665IAS-OFF-BKG JB1.28 06/19/2023 22:59TO-15 Isopropyl Alcohol µg/m3 0.139 1.88 06/19/2023 22:59TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 1.74 06/19/2023 22:59TO-15 Methylene Chloride µg/m3 0.488 J0.936 06/19/2023 22:59TO-15 Tetrachloroethene µg/m3 0.181 3.26 06/19/2023 22:59TO-15 Toluene µg/m3 0.090 J1.75 06/19/2023 22:59TO-15 Trichlorofluoromethane µg/m3 0.130 J2.95 06/19/2023 22:59TO-15 m,p-Xylene µg/m3 0.217 V 98666MP-15 16.8 06/20/2023 19:31TO-15 Acetone µg/m3 0.202 J0.255 06/20/2023 19:31TO-15 Benzene µg/m3 0.073 J0.588 06/20/2023 19:31TO-15 Carbon Disulfide µg/m3 0.060 J1.60 06/20/2023 19:31TO-15 Chloroform µg/m3 0.086 3.13 06/20/2023 19:31TO-15 Dichlorodifluoromethane µg/m3 0.134 25.0 06/20/2023 19:31TO-15 Ethanol µg/m3 0.169 J1.66 06/20/2023 19:31TO-15 n-Hexane µg/m3 0.047 6.54 06/20/2023 19:31TO-15 Isopropyl Alcohol µg/m3 0.139 J1.21 06/20/2023 19:31TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 3.01 06/20/2023 19:31TO-15 Methylene Chloride µg/m3 0.488 J0.347 06/20/2023 19:31TO-15 Tetrahydrofuran µg/m3 0.107 J0.455 06/20/2023 19:31TO-15 Toluene µg/m3 0.090 J2.29 06/20/2023 19:31TO-15 Trichlorofluoromethane µg/m3 0.130 3.06 06/20/2023 19:31TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J2.98 06/20/2023 19:31TO-15 m,p-Xylene µg/m3 0.217 Page 6 of 26 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-167-0023 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 06/16/2023 PAM-003 Report Date : 06/21/2023 Sample ID : Lab No : Sampled:IAS-OFF-1 98662 Matrix: 6/15/2023 8:50 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34512 06/19/23 09:00 40.9 µg/m3 0.202 4.75Acetone 1 06/19/23 20:27 V34516ENM 0.635 J µg/m3 0.073 1.60Benzene 1 06/19/23 20:27 V34516ENM 0.591 J µg/m3 0.060 6.23Carbon Disulfide 1 06/19/23 20:27 V34516ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 06/19/23 20:27 V34516ENM <0.086 µg/m3 0.086 2.44Chloroform 1 06/19/23 20:27 V34516ENM 0.881 J µg/m3 0.067 1.03Chloromethane 1 06/19/23 20:27 V34516ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 06/19/23 20:27 V34516ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 06/19/23 20:27 V34516ENM <0.186 µg/m3 0.186 3.01 1,4-Dichlorobenzene 1 06/19/23 20:27 V34516ENM 2.97 µg/m3 0.134 2.47Dichlorodifluoromethane 1 06/19/23 20:27 V34516ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 06/19/23 20:27 V34516ENM 19.6 µg/m3 0.169 5.00Ethanol 1 06/19/23 20:27 V34516ENM 1.50 J µg/m3 0.106 2.17Ethylbenzene 1 06/19/23 20:27 V34516ENM 0.363 J µg/m3 0.128 2.464-Ethyltoluene 1 06/19/23 20:27 V34516ENM 0.749 J µg/m3 0.143 2.05Heptane 1 06/19/23 20:27 V34516ENM 4.42 µg/m3 0.047 1.76 n-Hexane 1 06/19/23 20:27 V34516ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 06/19/23 20:27 V34516ENM 2.64 JB µg/m3 0.139 4.92Isopropyl Alcohol 1 06/19/23 20:27 V34516ENM 17.0 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 06/19/23 20:27 V34516ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 06/19/23 20:27 V34516ENM 0.996 J µg/m3 0.488 1.74Methylene Chloride 1 06/19/23 20:27 V34516ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 06/19/23 20:27 V34516ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 7 of 26 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-167-0023 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 06/16/2023 PAM-003 Report Date : 06/21/2023 Sample ID : Lab No : Sampled:IAS-OFF-1 98662 Matrix: 6/15/2023 8:50 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34512 06/19/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 06/19/23 20:27 V34516ENM 4.32 µg/m3 0.124 2.13Styrene 1 06/19/23 20:27 V34516ENM <0.181 µg/m3 0.181 3.39Tetrachloroethene 1 06/19/23 20:27 V34516ENM 2.71 µg/m3 0.107 1.47Tetrahydrofuran 1 06/19/23 20:27 V34516ENM 7.20 µg/m3 0.090 1.88Toluene 1 06/19/23 20:27 V34516ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 06/19/23 20:27 V34516ENM 1.71 J µg/m3 0.130 2.81Trichlorofluoromethane 1 06/19/23 20:27 V34516ENM 3.70 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 06/19/23 20:27 V34516ENM 0.496 J µg/m3 0.236 2.46 1,3,5-Trimethylbenzene 1 06/19/23 20:27 V34516ENM 1.65 J µg/m3 0.157 2.17o-Xylene 1 06/19/23 20:27 V34516ENM 6.65 µg/m3 0.217 5.65m,p-Xylene 1 06/19/23 20:27 V34516ENM Surrogate: 4-Bromofluorobenzene 98.0 Limits: 70-130%06/19/23 20:271 ENM V34516 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 8 of 26 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-167-0023 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 06/16/2023 PAM-003 Report Date : 06/21/2023 Sample ID : Lab No : Sampled:IAS-OFF-DUP 98663 Matrix: 6/15/2023 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34512 06/19/23 09:00 37.8 µg/m3 0.202 4.75Acetone 1 06/19/23 21:16 V34516ENM 0.664 J µg/m3 0.073 1.60Benzene 1 06/19/23 21:16 V34516ENM 0.442 J µg/m3 0.060 6.23Carbon Disulfide 1 06/19/23 21:16 V34516ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 06/19/23 21:16 V34516ENM <0.086 µg/m3 0.086 2.44Chloroform 1 06/19/23 21:16 V34516ENM 0.912 J µg/m3 0.067 1.03Chloromethane 1 06/19/23 21:16 V34516ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 06/19/23 21:16 V34516ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 06/19/23 21:16 V34516ENM <0.186 µg/m3 0.186 3.01 1,4-Dichlorobenzene 1 06/19/23 21:16 V34516ENM 2.93 µg/m3 0.134 2.47Dichlorodifluoromethane 1 06/19/23 21:16 V34516ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 06/19/23 21:16 V34516ENM 18.0 µg/m3 0.169 5.00Ethanol 1 06/19/23 21:16 V34516ENM 1.45 J µg/m3 0.106 2.17Ethylbenzene 1 06/19/23 21:16 V34516ENM 0.388 J µg/m3 0.128 2.464-Ethyltoluene 1 06/19/23 21:16 V34516ENM 0.790 J µg/m3 0.143 2.05Heptane 1 06/19/23 21:16 V34516ENM 4.32 µg/m3 0.047 1.76 n-Hexane 1 06/19/23 21:16 V34516ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 06/19/23 21:16 V34516ENM 2.29 JB µg/m3 0.139 4.92Isopropyl Alcohol 1 06/19/23 21:16 V34516ENM 16.3 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 06/19/23 21:16 V34516ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 06/19/23 21:16 V34516ENM 0.906 J µg/m3 0.488 1.74Methylene Chloride 1 06/19/23 21:16 V34516ENM 5.08 µg/m3 0.183 2.62Naphthalene 1 06/19/23 21:16 V34516ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 9 of 26 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-167-0023 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 06/16/2023 PAM-003 Report Date : 06/21/2023 Sample ID : Lab No : Sampled:IAS-OFF-DUP 98663 Matrix: 6/15/2023 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34512 06/19/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 06/19/23 21:16 V34516ENM 4.56 µg/m3 0.124 2.13Styrene 1 06/19/23 21:16 V34516ENM <0.181 µg/m3 0.181 3.39Tetrachloroethene 1 06/19/23 21:16 V34516ENM 2.60 µg/m3 0.107 1.47Tetrahydrofuran 1 06/19/23 21:16 V34516ENM 7.07 µg/m3 0.090 1.88Toluene 1 06/19/23 21:16 V34516ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 06/19/23 21:16 V34516ENM 1.71 J µg/m3 0.130 2.81Trichlorofluoromethane 1 06/19/23 21:16 V34516ENM 3.80 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 06/19/23 21:16 V34516ENM 0.614 J µg/m3 0.236 2.46 1,3,5-Trimethylbenzene 1 06/19/23 21:16 V34516ENM 1.68 J µg/m3 0.157 2.17o-Xylene 1 06/19/23 21:16 V34516ENM 6.66 µg/m3 0.217 5.65m,p-Xylene 1 06/19/23 21:16 V34516ENM Surrogate: 4-Bromofluorobenzene 95.8 Limits: 70-130%06/19/23 21:161 ENM V34516 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 10 of 26 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-167-0023 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 06/16/2023 PAM-003 Report Date : 06/21/2023 Sample ID : Lab No : Sampled:IAS-OFF-2 98664 Matrix: 6/15/2023 9:05 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34512 06/19/23 09:00 26.5 µg/m3 0.202 4.75Acetone 1 06/19/23 22:07 V34516ENM 0.731 J µg/m3 0.073 1.60Benzene 1 06/19/23 22:07 V34516ENM 0.460 J µg/m3 0.060 6.23Carbon Disulfide 1 06/19/23 22:07 V34516ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 06/19/23 22:07 V34516ENM <0.086 µg/m3 0.086 2.44Chloroform 1 06/19/23 22:07 V34516ENM 0.892 J µg/m3 0.067 1.03Chloromethane 1 06/19/23 22:07 V34516ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 06/19/23 22:07 V34516ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 06/19/23 22:07 V34516ENM <0.186 µg/m3 0.186 3.01 1,4-Dichlorobenzene 1 06/19/23 22:07 V34516ENM 3.09 µg/m3 0.134 2.47Dichlorodifluoromethane 1 06/19/23 22:07 V34516ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 06/19/23 22:07 V34516ENM 15.9 µg/m3 0.169 5.00Ethanol 1 06/19/23 22:07 V34516ENM 0.933 J µg/m3 0.106 2.17Ethylbenzene 1 06/19/23 22:07 V34516ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 06/19/23 22:07 V34516ENM 0.725 J µg/m3 0.143 2.05Heptane 1 06/19/23 22:07 V34516ENM 1.88 µg/m3 0.047 1.76 n-Hexane 1 06/19/23 22:07 V34516ENM 0.532 J µg/m3 0.285 2.052-Hexanone 1 06/19/23 22:07 V34516ENM 2.33 JB µg/m3 0.139 4.92Isopropyl Alcohol 1 06/19/23 22:07 V34516ENM 10.4 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 06/19/23 22:07 V34516ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 06/19/23 22:07 V34516ENM 1.98 µg/m3 0.488 1.74Methylene Chloride 1 06/19/23 22:07 V34516ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 06/19/23 22:07 V34516ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 11 of 26 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-167-0023 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 06/16/2023 PAM-003 Report Date : 06/21/2023 Sample ID : Lab No : Sampled:IAS-OFF-2 98664 Matrix: 6/15/2023 9:05 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34512 06/19/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 06/19/23 22:07 V34516ENM 3.31 µg/m3 0.124 2.13Styrene 1 06/19/23 22:07 V34516ENM <0.181 µg/m3 0.181 3.39Tetrachloroethene 1 06/19/23 22:07 V34516ENM 1.42 J µg/m3 0.107 1.47Tetrahydrofuran 1 06/19/23 22:07 V34516ENM 4.99 µg/m3 0.090 1.88Toluene 1 06/19/23 22:07 V34516ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 06/19/23 22:07 V34516ENM 1.78 J µg/m3 0.130 2.81Trichlorofluoromethane 1 06/19/23 22:07 V34516ENM 3.24 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 06/19/23 22:07 V34516ENM <0.236 µg/m3 0.236 2.46 1,3,5-Trimethylbenzene 1 06/19/23 22:07 V34516ENM 1.18 J µg/m3 0.157 2.17o-Xylene 1 06/19/23 22:07 V34516ENM 5.45 J µg/m3 0.217 5.65m,p-Xylene 1 06/19/23 22:07 V34516ENM Surrogate: 4-Bromofluorobenzene 99.4 Limits: 70-130%06/19/23 22:071 ENM V34516 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 12 of 26 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-167-0023 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 06/16/2023 PAM-003 Report Date : 06/21/2023 Sample ID : Lab No : Sampled:IAS-OFF-BKG 98665 Matrix: 6/15/2023 9:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34512 06/19/23 09:00 19.3 µg/m3 0.202 4.75Acetone 1 06/19/23 22:59 V34516ENM 0.645 J µg/m3 0.073 1.60Benzene 1 06/19/23 22:59 V34516ENM 0.392 J µg/m3 0.060 6.23Carbon Disulfide 1 06/19/23 22:59 V34516ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 06/19/23 22:59 V34516ENM <0.086 µg/m3 0.086 2.44Chloroform 1 06/19/23 22:59 V34516ENM <0.067 µg/m3 0.067 1.03Chloromethane 1 06/19/23 22:59 V34516ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 06/19/23 22:59 V34516ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 06/19/23 22:59 V34516ENM <0.186 µg/m3 0.186 3.01 1,4-Dichlorobenzene 1 06/19/23 22:59 V34516ENM 3.01 µg/m3 0.134 2.47Dichlorodifluoromethane 1 06/19/23 22:59 V34516ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 06/19/23 22:59 V34516ENM 7.72 µg/m3 0.169 5.00Ethanol 1 06/19/23 22:59 V34516ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 06/19/23 22:59 V34516ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 06/19/23 22:59 V34516ENM <0.143 µg/m3 0.143 2.05Heptane 1 06/19/23 22:59 V34516ENM 1.34 J µg/m3 0.047 1.76 n-Hexane 1 06/19/23 22:59 V34516ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 06/19/23 22:59 V34516ENM 1.28 JB µg/m3 0.139 4.92Isopropyl Alcohol 1 06/19/23 22:59 V34516ENM 1.88 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 06/19/23 22:59 V34516ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 06/19/23 22:59 V34516ENM 1.74 µg/m3 0.488 1.74Methylene Chloride 1 06/19/23 22:59 V34516ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 06/19/23 22:59 V34516ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 13 of 26 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-167-0023 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 06/16/2023 PAM-003 Report Date : 06/21/2023 Sample ID : Lab No : Sampled:IAS-OFF-BKG 98665 Matrix: 6/15/2023 9:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34512 06/19/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 06/19/23 22:59 V34516ENM <0.124 µg/m3 0.124 2.13Styrene 1 06/19/23 22:59 V34516ENM 0.936 J µg/m3 0.181 3.39Tetrachloroethene 1 06/19/23 22:59 V34516ENM <0.107 µg/m3 0.107 1.47Tetrahydrofuran 1 06/19/23 22:59 V34516ENM 3.26 µg/m3 0.090 1.88Toluene 1 06/19/23 22:59 V34516ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 06/19/23 22:59 V34516ENM 1.75 J µg/m3 0.130 2.81Trichlorofluoromethane 1 06/19/23 22:59 V34516ENM <0.110 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 06/19/23 22:59 V34516ENM <0.236 µg/m3 0.236 2.46 1,3,5-Trimethylbenzene 1 06/19/23 22:59 V34516ENM <0.157 µg/m3 0.157 2.17o-Xylene 1 06/19/23 22:59 V34516ENM 2.95 J µg/m3 0.217 5.65m,p-Xylene 1 06/19/23 22:59 V34516ENM Surrogate: 4-Bromofluorobenzene 99.7 Limits: 70-130%06/19/23 22:591 ENM V34516 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 14 of 26 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-167-0023 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 06/16/2023 PAM-003 Report Date : 06/21/2023 Sample ID : Lab No : Sampled:MP-15 98666 Matrix: 6/16/2023 10:48 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34530 06/20/23 09:00 16.8 µg/m3 0.202 4.75Acetone 1 06/20/23 19:31 V34532ENM 0.255 J µg/m3 0.073 1.60Benzene 1 06/20/23 19:31 V34532ENM 0.588 J µg/m3 0.060 6.23Carbon Disulfide 1 06/20/23 19:31 V34532ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 06/20/23 19:31 V34532ENM 1.60 J µg/m3 0.086 2.44Chloroform 1 06/20/23 19:31 V34532ENM <0.067 µg/m3 0.067 1.03Chloromethane 1 06/20/23 19:31 V34532ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 06/20/23 19:31 V34532ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 06/20/23 19:31 V34532ENM <0.186 µg/m3 0.186 3.01 1,4-Dichlorobenzene 1 06/20/23 19:31 V34532ENM 3.13 µg/m3 0.134 2.47Dichlorodifluoromethane 1 06/20/23 19:31 V34532ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 06/20/23 19:31 V34532ENM 25.0 µg/m3 0.169 5.00Ethanol 1 06/20/23 19:31 V34532ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 06/20/23 19:31 V34532ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 06/20/23 19:31 V34532ENM <0.143 µg/m3 0.143 2.05Heptane 1 06/20/23 19:31 V34532ENM 1.66 J µg/m3 0.047 1.76 n-Hexane 1 06/20/23 19:31 V34532ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 06/20/23 19:31 V34532ENM 6.54 µg/m3 0.139 4.92Isopropyl Alcohol 1 06/20/23 19:31 V34532ENM 1.21 J µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 06/20/23 19:31 V34532ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 06/20/23 19:31 V34532ENM 3.01 µg/m3 0.488 1.74Methylene Chloride 1 06/20/23 19:31 V34532ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 06/20/23 19:31 V34532ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 15 of 26 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-167-0023 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 06/16/2023 PAM-003 Report Date : 06/21/2023 Sample ID : Lab No : Sampled:MP-15 98666 Matrix: 6/16/2023 10:48 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34530 06/20/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 06/20/23 19:31 V34532ENM <0.124 µg/m3 0.124 2.13Styrene 1 06/20/23 19:31 V34532ENM <0.181 µg/m3 0.181 3.39Tetrachloroethene 1 06/20/23 19:31 V34532ENM 0.347 J µg/m3 0.107 1.47Tetrahydrofuran 1 06/20/23 19:31 V34532ENM 0.455 J µg/m3 0.090 1.88Toluene 1 06/20/23 19:31 V34532ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 06/20/23 19:31 V34532ENM 2.29 J µg/m3 0.130 2.81Trichlorofluoromethane 1 06/20/23 19:31 V34532ENM 3.06 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 06/20/23 19:31 V34532ENM <0.236 µg/m3 0.236 2.46 1,3,5-Trimethylbenzene 1 06/20/23 19:31 V34532ENM <0.157 µg/m3 0.157 2.17o-Xylene 1 06/20/23 19:31 V34532ENM 2.98 J µg/m3 0.217 5.65m,p-Xylene 1 06/20/23 19:31 V34532ENM Surrogate: 4-Bromofluorobenzene 98.0 Limits: 70-130%06/20/23 19:311 ENM V34532 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Page 16 of 26 Quality Control Data 23-167-0023Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM-003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34516QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34512 Associated Lab Samples: 98662, 98663, 98664, 98665 LRB-V34512 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/19/23 10:564.750.2020.337µg/m3Acetone 06/19/23 10:561.600.073<0.073µg/m3Benzene 06/19/23 10:566.230.060<0.060µg/m3Carbon Disulfide 06/19/23 10:563.150.155<0.155µg/m3Carbon Tetrachloride 06/19/23 10:562.440.086<0.086µg/m3Chloroform 06/19/23 10:561.030.067<0.067µg/m3Chloromethane 06/19/23 10:563.440.161<0.161µg/m3Cyclohexane 06/19/23 10:563.010.096<0.096µg/m31,2-Dichlorobenzene 06/19/23 10:563.010.186<0.186µg/m31,4-Dichlorobenzene 06/19/23 10:562.470.134<0.134µg/m3Dichlorodifluoromethane 06/19/23 10:561.980.095<0.095µg/m3cis-1,2-Dichloroethene 06/19/23 10:565.000.169<0.169µg/m3Ethanol 06/19/23 10:562.170.106<0.106µg/m3Ethylbenzene 06/19/23 10:562.460.128<0.128µg/m34-Ethyltoluene 06/19/23 10:562.050.143<0.143µg/m3Heptane 06/19/23 10:561.760.047<0.047µg/m3n-Hexane 06/19/23 10:562.050.285<0.285µg/m32-Hexanone 06/19/23 10:564.920.1390.855µg/m3Isopropyl Alcohol 06/19/23 10:561.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 06/19/23 10:562.050.121<0.121µg/m34-Methyl-2-Pentanone 06/19/23 10:561.740.488<0.488µg/m3Methylene Chloride 06/19/23 10:562.620.183<0.183µg/m3Naphthalene 06/19/23 10:560.8600.242<0.242µg/m3Propene 06/19/23 10:562.130.124<0.124µg/m3Styrene 06/19/23 10:563.390.181<0.181µg/m3Tetrachloroethene 06/19/23 10:561.470.107<0.107µg/m3Tetrahydrofuran 06/19/23 10:561.880.090<0.090µg/m3Toluene Page 1 of 6Date:06/21/2023 02:47 PM Page 17 of 26 Quality Control Data 23-167-0023Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM-003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34516QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34512 Associated Lab Samples: 98662, 98663, 98664, 98665 LRB-V34512 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/19/23 10:562.150.199<0.199µg/m3Trichloroethene 06/19/23 10:562.810.130<0.130µg/m3Trichlorofluoromethane 06/19/23 10:562.460.110<0.110µg/m31,2,4-Trimethylbenzene 06/19/23 10:562.460.236<0.236µg/m31,3,5-Trimethylbenzene 06/19/23 10:562.170.157<0.157µg/m3o-Xylene 06/19/23 10:565.650.217<0.217µg/m3m,p-Xylene 06/19/23 10:564-Bromofluorobenzene (S)96.0 70-130 LCS-V34512Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 11313.511.9µg/m3Acetone 70-130 10116.116.0µg/m3Benzene 70-130 11317.615.6µg/m3Carbon Disulfide 70-130 10031.631.5µg/m3Carbon Tetrachloride 70-130 10525.524.4µg/m3Chloroform 70-130 11311.610.3µg/m3Chloromethane 70-130 10518.017.2µg/m3Cyclohexane 70-130 11233.630.1µg/m31,2-Dichlorobenzene 70-130 11334.130.1µg/m31,4-Dichlorobenzene 70-130 11227.724.7µg/m3Dichlorodifluoromethane 70-130 11422.619.8µg/m3cis-1,2-Dichloroethene 70-130 1049.839.42µg/m3Ethanol 70-130 10522.721.7µg/m3Ethylbenzene 70-130 10626.024.6µg/m34-Ethyltoluene 70-130 10722.020.5µg/m3Heptane 70-130 11319.917.6µg/m3n-Hexane 70-130 Page 2 of 6Date:06/21/2023 02:47 PM Page 18 of 26 Quality Control Data 23-167-0023Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM-003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34516QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34512 LCS-V34512Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 11022.520.5µg/m32-Hexanone 70-130 11814.512.3µg/m3Isopropyl Alcohol 70-130 11116.514.8µg/m3Methyl Ethyl Ketone (MEK)70-130 10621.720.5µg/m34-Methyl-2-Pentanone 70-130 10818.817.4µg/m3Methylene Chloride 70-130 10126.526.2µg/m3Naphthalene 70-130 1089.318.61µg/m3Propene 70-130 96.720.621.3µg/m3Styrene 70-130 10134.133.9µg/m3Tetrachloroethene 70-130 10715.714.7µg/m3Tetrahydrofuran 70-130 10119.018.8µg/m3Toluene 70-130 10327.626.9µg/m3Trichloroethene 70-130 11432.128.1µg/m3Trichlorofluoromethane 70-130 10225.224.6µg/m31,2,4-Trimethylbenzene 70-130 10726.324.6µg/m31,3,5-Trimethylbenzene 70-130 10422.521.7µg/m3o-Xylene 70-130 94.441.043.4µg/m3m,p-Xylene 70-130 98.84-Bromofluorobenzene (S)70-130 Page 3 of 6Date:06/21/2023 02:47 PM Page 19 of 26 Quality Control Data 23-167-0023Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM-003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34532QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34530 Associated Lab Samples: 98666 LRB-V34530 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/20/23 10:354.750.2020.581µg/m3Acetone 06/20/23 10:351.600.073<0.073µg/m3Benzene 06/20/23 10:356.230.060<0.060µg/m3Carbon Disulfide 06/20/23 10:353.150.155<0.155µg/m3Carbon Tetrachloride 06/20/23 10:352.440.086<0.086µg/m3Chloroform 06/20/23 10:351.030.067<0.067µg/m3Chloromethane 06/20/23 10:353.440.161<0.161µg/m3Cyclohexane 06/20/23 10:353.010.096<0.096µg/m31,2-Dichlorobenzene 06/20/23 10:353.010.186<0.186µg/m31,4-Dichlorobenzene 06/20/23 10:352.470.134<0.134µg/m3Dichlorodifluoromethane 06/20/23 10:351.980.095<0.095µg/m3cis-1,2-Dichloroethene 06/20/23 10:355.000.169<0.169µg/m3Ethanol 06/20/23 10:352.170.106<0.106µg/m3Ethylbenzene 06/20/23 10:352.460.128<0.128µg/m34-Ethyltoluene 06/20/23 10:352.050.143<0.143µg/m3Heptane 06/20/23 10:351.760.047<0.047µg/m3n-Hexane 06/20/23 10:352.050.285<0.285µg/m32-Hexanone 06/20/23 10:354.920.1390.535µg/m3Isopropyl Alcohol 06/20/23 10:351.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 06/20/23 10:352.050.121<0.121µg/m34-Methyl-2-Pentanone 06/20/23 10:351.740.488<0.488µg/m3Methylene Chloride 06/20/23 10:352.620.183<0.183µg/m3Naphthalene 06/20/23 10:350.8600.242<0.242µg/m3Propene 06/20/23 10:352.130.124<0.124µg/m3Styrene 06/20/23 10:353.390.181<0.181µg/m3Tetrachloroethene 06/20/23 10:351.470.107<0.107µg/m3Tetrahydrofuran 06/20/23 10:351.880.090<0.090µg/m3Toluene Page 4 of 6Date:06/21/2023 02:47 PM Page 20 of 26 Quality Control Data 23-167-0023Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM-003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34532QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34530 Associated Lab Samples: 98666 LRB-V34530 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/20/23 10:352.150.199<0.199µg/m3Trichloroethene 06/20/23 10:352.810.130<0.130µg/m3Trichlorofluoromethane 06/20/23 10:352.460.110<0.110µg/m31,2,4-Trimethylbenzene 06/20/23 10:352.460.236<0.236µg/m31,3,5-Trimethylbenzene 06/20/23 10:352.170.157<0.157µg/m3o-Xylene 06/20/23 10:355.650.217<0.217µg/m3m,p-Xylene 06/20/23 10:354-Bromofluorobenzene (S)94.6 70-130 LCS-V34530Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 11013.111.9µg/m3Acetone 70-130 10717.116.0µg/m3Benzene 70-130 11618.115.6µg/m3Carbon Disulfide 70-130 10934.331.5µg/m3Carbon Tetrachloride 70-130 11227.324.4µg/m3Chloroform 70-130 11511.810.3µg/m3Chloromethane 70-130 10818.517.2µg/m3Cyclohexane 70-130 11835.630.1µg/m31,2-Dichlorobenzene 70-130 12236.630.1µg/m31,4-Dichlorobenzene 70-130 11829.124.7µg/m3Dichlorodifluoromethane 70-130 11622.919.8µg/m3cis-1,2-Dichloroethene 70-130 1019.569.42µg/m3Ethanol 70-130 11224.321.7µg/m3Ethylbenzene 70-130 11327.824.6µg/m34-Ethyltoluene 70-130 10922.320.5µg/m3Heptane 70-130 11420.117.6µg/m3n-Hexane 70-130 Page 5 of 6Date:06/21/2023 02:47 PM Page 21 of 26 Quality Control Data 23-167-0023Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM-003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34532QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34530 LCS-V34530Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10922.320.5µg/m32-Hexanone 70-130 11113.612.3µg/m3Isopropyl Alcohol 70-130 10916.114.8µg/m3Methyl Ethyl Ketone (MEK)70-130 10822.120.5µg/m34-Methyl-2-Pentanone 70-130 10618.517.4µg/m3Methylene Chloride 70-130 10627.826.2µg/m3Naphthalene 70-130 1059.078.61µg/m3Propene 70-130 10021.421.3µg/m3Styrene 70-130 10836.533.9µg/m3Tetrachloroethene 70-130 10916.014.7µg/m3Tetrahydrofuran 70-130 10820.318.8µg/m3Toluene 70-130 11129.826.9µg/m3Trichloroethene 70-130 11833.228.1µg/m3Trichlorofluoromethane 70-130 10826.524.6µg/m31,2,4-Trimethylbenzene 70-130 11528.424.6µg/m31,3,5-Trimethylbenzene 70-130 11124.121.7µg/m3o-Xylene 70-130 10043.543.4µg/m3m,p-Xylene 70-130 99.44-Bromofluorobenzene (S)70-130 Page 6 of 6Date:06/21/2023 02:47 PM Page 22 of 26 Fed Ex UPS US Postal Client Lab Courier Other : Shipment Receipt Form Customer Number: Customer Name: Report Number:23-167-0023 Hart & Hickman (Charlotte) 01102 Shipping Method Shipping container/cooler uncompromised? Thermometer ID:N/A Chain of Custody (COC) present?Yes No Yes No Not Present Yes No Not Present Yes No COC agrees with sample label(s)? Yes No COC properly completed Samples in proper containers? Sample containers intact? Sufficient sample volume for indicated test(s)? All samples received within holding time? Cooler temperature in compliance? Yes No Yes No Yes No Yes No Yes No Yes NoCooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes No Yes No N/A Yes No N/A Yes No N/ASoil VOA method 5035 – compliance criteria met Water - Sample containers properly preserved Water - VOA vials free of headspace Yes No N/A Trip Blanks received with VOAs Low concentration EnCore samplers (48 hr) High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d) High concentration container (48 hr) Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Number of coolers/boxes received Yes No 1 Signature:Angelo Norvell Date & Time:06/16/2023 15:49:49 Special precautions or instructions included? Comments: Page 23 of 26 Page 24 of 26 Page 25 of 26 Page 26 of 26 Attachment G DEQ Risk Calculator Summary Pages Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Office Space Indoor Air and Sub-Slab Worst Case North Carolina Department of Environmental Quality Risk Calculator North Davidson II Brownfields Site 2315 North Davidson Street Brownfields 24003-20-060 January 2023 November 2022 EPA RSL Table 6/15/2023 Prepared By:Hart & Hickman, PC H&H North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Office Space Indoor Air and Sub-Slab Worst Case Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Office Space Indoor Air and Sub-Slab Worst Case Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Office Space Indoor Air and Sub-Slab Worst Case Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 16.8 67-64-1 Acetone ug/m3 0.255 J 71-43-2 Benzene ug/m3 0.588 J 75-15-0 Carbon Disulfide ug/m3 1.6 J 67-66-3 Chloroform ug/m3 3.13 75-71-8 Dichlorodifluoromethane ug/m3 0.347 J 109-99-9 ~Tetrahydrofuran ug/m3 1.66 J 110-54-3 Hexane, N-ug/m3 6.54 67-63-0 Isopropanol ug/m3 1.21 J 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 3.01 75-09-2 Methylene Chloride ug/m3 0.455 J 108-88-3 Toluene ug/m3 2.29 J 75-69-4 Trichlorofluoromethane ug/m3 3.06 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 2.98 J 108-38-3 Xylene, m-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Office Space Indoor Air and Sub-Slab Worst Case Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 40.9 IAS-OFF-1 67-64-1 Acetone ug/m3 0.731 IAS-OFF-2, J 71-43-2 Benzene ug/m3 0.591 IAS-OFF-1, J 75-15-0 Carbon Disulfide ug/m3 0.912 IAS-OFF-DUP, J 74-87-3 Chloromethane ug/m3 3.09 IAS-OFF-2, J 75-71-8 Dichlorodifluoromethane ug/m3 1.5 IAS-OFF-1, J 100-41-4 Ethylbenzene ug/m3 2.71 IAS-OFF-1 109-99-9 ~Tetrahydrofuran ug/m3 0.79 IAS-OFF-DUP, J 142-82-5 Heptane, N-ug/m3 4.42 IAS-OFF-1 110-54-3 Hexane, N-ug/m3 0.532 IAS-OFF-2, J 591-78-6 Hexanone, 2-ug/m3 2.64 IAS-OFF-1, BJ 67-63-0 Isopropanol ug/m3 17 IAS-OFF-1 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 1.98 IAS-OFF-2 75-09-2 Methylene Chloride ug/m3 5.08 IAS-OFF-DUP 91-20-3 ~Naphthalene ug/m3 4.56 IAS-OFF-DUP 100-42-5 Styrene ug/m3 7.2 IAS-OFF-1 108-88-3 Toluene ug/m3 1.78 IAS-OFF-2, J 75-69-4 Trichlorofluoromethane ug/m3 3.8 IAS-OFF-DUP 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0.614 IAS-OFF-DUP, J 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 6.66 IAS-OFF-DUP 108-38-3 Xylene, m-ug/m3 1.68 IAS-OFF-DUP, J 95-47-6 Xylene, o-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Office Space Indoor Air and Sub-Slab Worst Case Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 3.2E-08 4.1E-04 NO Indoor Air 1.5E-05 4.5E-01 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: 3. NM = Not modeled, user did not check this pathway as complete. 4. NC = Pathway not calculated, required contaminant migration parameters were not entered. DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Office Space Indoor Air and Sub-Slab Worst Case CAS #Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 40.9 -- 71-43-2 Benzene 0.731 1.6E+00 2.6E+01 4.6E-07 5.6E-03 75-15-0 Carbon Disulfide 0.591 -6.1E+02 1.9E-04 74-87-3 Chloromethane 0.912 -7.9E+01 2.3E-03 75-71-8 Dichlorodifluoromethane 3.09 -8.8E+01 7.1E-03 100-41-4 Ethylbenzene 1.5 4.9E+00 8.8E+02 3.1E-07 3.4E-04 109-99-9 ~Tetrahydrofuran 2.71 -1.8E+03 3.1E-04 142-82-5 Heptane, N-0.79 -3.5E+02 4.5E-04 110-54-3 Hexane, N-4.42 -6.1E+02 1.4E-03 591-78-6 Hexanone, 2-0.532 -2.6E+01 4.0E-03 67-63-0 Isopropanol 2.64 -1.8E+02 3.0E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone)17 -4.4E+03 7.8E-04 75-09-2 Methylene Chloride 1.98 1.2E+03 5.3E+02 1.6E-09 7.5E-04 91-20-3 ~Naphthalene 5.08 3.6E-01 2.6E+00 1.4E-05 3.9E-01 100-42-5 Styrene 4.56 -8.8E+02 1.0E-03 108-88-3 Toluene 7.2 -4.4E+03 3.3E-04 75-69-4 Trichlorofluoromethane 1.78 -- 95-63-6 Trimethylbenzene, 1,2,4-3.8 -5.3E+01 1.4E-02 108-67-8 Trimethylbenzene, 1,3,5-0.614 -5.3E+01 2.3E-03 108-38-3 Xylene, m-6.66 -8.8E+01 1.5E-02 95-47-6 Xylene, o-1.68 -8.8E+01 3.8E-03 Cumulative: 1.5E-05 4.5E-01 All concentrations are in ug/m3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Office Space Indoor Air and Sub-Slab Worst Case CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 16.8 0.168 -- 71-43-2 Benzene 0.255 0.00255 1.6E+00 2.6E+01 1.6E-09 1.9E-05 75-15-0 Carbon Disulfide 0.588 0.00588 -6.1E+02 1.9E-06 67-66-3 Chloroform 1.6 0.016 5.3E-01 8.6E+01 3.0E-08 3.7E-05 75-71-8 Dichlorodifluoromethane 3.13 0.0313 -8.8E+01 7.1E-05 109-99-9 ~Tetrahydrofuran 0.347 0.00347 -1.8E+03 4.0E-07 110-54-3 Hexane, N-1.66 0.0166 -6.1E+02 5.4E-06 67-63-0 Isopropanol 6.54 0.0654 -1.8E+02 7.5E-05 78-93-3 Methyl Ethyl Ketone (2-Butanone)1.21 0.0121 -4.4E+03 5.5E-07 75-09-2 Methylene Chloride 3.01 0.0301 1.2E+03 5.3E+02 2.5E-11 1.1E-05 108-88-3 Toluene 0.455 0.00455 -4.4E+03 2.1E-07 75-69-4 Trichlorofluoromethane 2.29 0.0229 -- 95-63-6 Trimethylbenzene, 1,2,4-3.06 0.0306 -5.3E+01 1.2E-04 108-38-3 Xylene, m-2.98 0.0298 -8.8E+01 6.8E-05 Cumulative: 3.2E-08 4.1E-04 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Attachment H Summary of Chemicals in Building Materials Table H-1 Building Material Safety Data Sheet Summary North Davidson II Brownfields Property 2315 North Davidson Street Charlotte, North Carolina Brownfields Project No. 24003-20-060 H&H Project No. PAM-003 Calcium Carbonate ≥ 10 - < 20 1317-65-3 Heavy Paraffinic Oil ≤ 3 64742-65-0 Gasoline, motor fuel 100 86290-81-5 Toluene 1 - 25 108-88-3 Butane <10 106-97-8 Xylenes (o-, m-, p- Isomers)1 - 15 1330-20-7 1,2,4-Trimethylbenzene <6 95-63-6 Ethyl alcohol 0 - 10 64-17-5 Ethylbenzene <3 100-41-4 Benzene 0.1 - 4.9 71-43-2 White Mineral Oil, petroleum 10-30 8042-47-5 Butane 5-10 106-97-8 Propane 1-5 74-98-6 Solvent Naptha 1-5 64742-88-7 Limestone >60 1317-65-3 Attapulgite <20 12174-11-7 Mica <20 12001-26-2 Starch <5 9005-25-8 Crystalline Silica <5 14808-60-7 Gypsum (Calcium Sulfate)90-99 13397-24-5 Limestone >0.1 1317-65-3 Quartz >0.1 14808-60-7 CAS No. Gasoline Hess Gasoline All Grades Stainless Steel Cleaner and PolishCleaner Paint PROMAR® 200 HP Zero VOC Interior Acrylic Eg-Shel Ultradeep Base Sub Group Product Material Potential Chemical of Concern (COC) Joint Compound Drywall Joint Compound Drywall Lafarge Drywall % COC by Weight Table H-1 (Page 1 of 1) Hart & Hickman, PC Gypsum Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Revision Date: 04/15/15 Date of issue: 04/15/15 Supersedes Date: 12/16/2014 Version: 1.1 04/15/2015 EN (English US) 1/8 SECTION 1: IDENTIFICATION Product Identifier Product Name: Gypsum Synonyms: Gypsum, Alabaster, Gypsum Stone, Land Plaster, Terra Alba, Native Calcium Sulfate, Calcium Sulfate Dihydrate Note:This MSDS covers many types of gypsum. Individual composition of hazardous constituents will vary between types of gypsum. Intended Use of the Product Gypsum is used in the manufacturing of drywall, drywall compounds, and cement, concrete and concrete products. Name, Address, and Telephone of the Responsible Party Company Lafarge North America Inc. 8700 West Bryn Mawr Avenue, Suite 300 Chicago, IL 60631 Information: 773-372-1000 (9am to 5pm CST) email: SDSinfo@Lafarge.com Website: www.lafarge-na.com Emergency Telephone Number Emergency Number : 1-800-451-8346 (3E Hotline) SECTION 2: HAZARDS IDENTIFICATION Classification of the Substance or Mixture Classification (GHS-US) Carc. 1A H350 STOT RE 1 H372 Full text of H-phrases: see section 16 Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) : GHS08 Signal Word (GHS-US) : Danger Hazard Statements (GHS-US) : H350 - May cause cancer (Inhalation). H372 - Causes damage to organs (lung/respiratory system, kidneys) through prolonged or repeated exposure (Inhalation). Precautionary Statements (GHS-US) : P202 - Do not handle until all safety precautions have been read and understood. P260 - Do not breathe dust. P264 - Wash hands, forearms, and face thoroughly after handling. P270 - Do not eat, drink, or smoke when using this product. P280 - Wear respiratory protection, eye protection, protective clothing, protective gloves. P308+P313 - If exposed or concerned: Get medical advice/attention. P405 - Store locked up. P501 - Dispose of contents/container in accordance with local, regional, national, territorial, provincial, and international regulations. Other Hazards Breathing dust may cause nose, throat or lung irritation, including choking, depending on the degree of exposure. Individuals with lung disease (e.g. bronchitis, emphysema, COPD, pulmonary disease) or sensitivity to hexavalent chromium can be aggravated by exposure. Unknown Acute Toxicity (GHS-US) Not available Gypsum Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations 04/15/15 EN (English US) 2/8 SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Mixture Name Product Identifier % (w/w) Classification (GHS-US) Gypsum (Ca(SO4).2H2O)* (CAS No) 13397-24-5 90 - 99 Not classified Limestone (CAS No) 1317-65-3 > 0.1; 0.1 - 1; 1 - 5; 5 - 10 Not classified Quartz (CAS No) 14808-60-7 > 0.1; 0.1 -1; 1 - 5 Carc. 1A, H350 STOT SE 3, H335 STOT RE 1, H372 More than one of the ranges of concentration prescribed by Controlled Products Regulations has been used where necessary, due to varying composition *Gypsum is a naturally occurring, mined rock. Trace amounts of chemical compounds may be detected during chemical analysis. For example, gypsum may contain trace amounts of naturally occurring metals, and other silicates. Full text of H-phrases: see section 16 SECTION 4: FIRST AID MEASURES Description of First Aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label if possible). Inhalation: If inhaled, remove to fresh air and keep at rest in a position comfortable for breathing. Seek medical attention immediately. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with mild soap and water. Obtain medical attention if irritation develops or persists. Wash contaminated clothing before reuse. Eye Contact: Do not rub. Rinse eyes thoroughly with water for at least 15 minutes, including under lids, to remove all particles. Seek medical attention for abrasions. Ingestion: Rinse mouth. Do not induce vomiting. Immediately call a POISON CENTER or doctor/physician. Most Important Symptoms and Effects Both Acute and Delayed General: Causes damage to organs. May cause cancer. Inhalation: The three types of silicosis include: 1) Simple chronic silicosis which results from long-term exposure (more than 20 years) to low amounts of respirable crystalline silica. Nodules of chronic inflammation and scarring provoked by the respirable crystalline silica form in the lungs and chest lymph nodes. This disease may feature breathlessness and may resemble chronic obstructive pulmonary disease (COPD); 2) Accelerated silicosis occurs after exposure to larger amounts of respirable crystalline silica over a shorter period of time (5-15 years); 3) Acute silicosis results from short-term exposure to very large amounts of respirable crystalline silica. The lungs become very inflamed and may fill with fluid, causing severe shortness of breath and low blood oxygen levels. Inflammation, scarring, and symptoms progress faster in accelerated silicosis than in simple silicosis. Progressive massive fibrosis may occur in simple or accelerated silicosis, but is more common in the accelerated form. Progressive massive fibrosis results from severe scarring and leads to the destruction of normal lung structures. Some studies show that exposure to respirable crystalline silica (without silicosis) or that the disease silicosis may be associated with the increased incidence of several autoimmune disorders such as scleroderma (thickening of the skin), systemic lupus erythematosus, rheumatoid arthritis and diseases affecting the kidneys. Silicosis increases the risk of tuberculosis. Some studies show an increased incidence of chronic kidney disease and end-stage renal disease in workers exposed to respirable crystalline silica. Irritating to mouth, nose, throat, and lungs, may cause difficulty in breathing. Skin Contact: Aggregates may cause dry skin, abrasions, discomfort, and irritation. Eye Contact: Airborne dust may cause immediate or delayed irritation or inflammation. Eye contact with large amounts of gypsum can cause moderate eye irritation, redness, and abrasions. Eye exposures require immediate first aid. Ingestion: Ingestion of large quantities can cause an obstruction causing pain and distress in the digestive tract. Chronic Symptoms: If dust is generated, repeated exposure through inhalation may cause cancer or lung disease. Causes damage to organs. Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention. SECTION 5: FIRE-FIGHTING MEASURES Extinguishing Media Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Gypsum Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations 04/15/15 EN (English US) 3/8 Special Hazards Arising From the Substance or Mixture Advice for Firefighters Precautionary Measures Fire: Not available Firefighting Instructions: Do not get water inside containers. Do not apply water stream directly at source of leak. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Hazardous Combustion Products: Decomposes to sulfur oxide and calcium oxide above 1450 °C. Reference to Other Sections Refer to section 9 for flammability properties. SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Avoid all contact with skin, eyes, or clothing. Avoid generating and breathing dust. For Non-Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. For Emergency Personnel Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit. Environmental Precautions Prevent entry to sewers and public waters. Methods and Material for Containment and Cleaning Up For Containment: Place spilled material into a container. Avoid actions that cause dust to become airborne. Avoid inhalation of dust. Wear appropriate protective equipment as described in Section 8. Do not wash gypsum down sewage and drainage systems or into bodies of water (e.g. streams). Methods for Cleaning Up: Avoid actions that cause dust to become airborne during clean-up such as dry sweeping or using compressed air. Use HEPA vacuum or thoroughly wet with water to clean-up dust. Use PPE described in Section 8. Contact competent authorities after a spill. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. Concerning disposal elimination after cleaning, see item 13. SECTION 7: HANDLING AND STORAGE Precautions for Safe Handling Additional Hazards When Processed: Cutting, crushing or grinding gypsum or other crystalline silica-bearing materials will release respirable crystalline silica. Use all appropriate measures of dust control or suppression, and Personal Protective Equipment (PPE) described in Section 8 below.;Do not handle until all safety precautions have been read and understood. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking and again when leaving work. Wash contaminated clothing before reuse. Conditions for Safe Storage, Including Any Incompatibilities Storage Conditions: Handle with care and use appropriate control measures. Keep bulk gypsum dry until used. Engulfment hazard. To prevent burial or suffocation, do not enter a confined space, such as a silo, bin, bulk truck, or other storage container or vessel that stores or contains gypsum. Gypsum can build up or adhere to the walls of a confined space. The gypsum can release, collapse or fall unexpectedly. Do not stand on stockpiles of gypsum, they may be unstable. Use engineering controls (e.g. wetting stockpiles) to prevent windblown dust from stockpiles, which may cause the hazards described in Section 3. Incompatible Materials: Gypsum is incompatible with acids. Gypsum contains silicates which may react with powerful oxidizers such as fluorine, boron trifluoride, chlorine trifluoride, manganese trifluoride, and oxygen difluoride. Specific End Use(s): Gypsum is used in the manufacturing of drywall, drywall compounds, and cement, concrete and concrete products Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. Fire Hazard: Product is not flammable. Explosion Hazard: Product is not explosive. Reactivity: Gypsum is incompatible with acids. Gypsum contains silicates which may react with powerful oxidizers such as fluorine, boron trifluoride, chlorine trifluoride, manganese trifluoride, and oxygen difluoride. Gypsum Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations 04/15/15 EN (English US) 4/8 SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control Parameters For substances listed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL), OSHA (PEL), Canadian provincial governments, or the Mexican government Quartz (14808-60-7) Mexico OEL TWA (mg/m³) 0.1 mg/m³ (respirable fraction) USA ACGIH ACGIH TWA (mg/m³) 0.025 mg/m³ (respirable fraction) USA OSHA OSHA PEL (STEL) (mg/m³) 250 mppcf/%SiO2+5, 10mg/m3/%SiO2+2 USA NIOSH NIOSH REL (TWA) (mg/m³) 0.05 mg/m³ (respirable dust) USA IDLH US IDLH (mg/m³) 50 mg/m³ (respirable dust) Alberta OEL TWA (mg/m³) 0.025 mg/m³ (respirable particulate) British Columbia OEL TWA (mg/m³) 0.025 mg/m³ (respirable) Manitoba OEL TWA (mg/m³) 0.025 mg/m³ (respirable fraction) New Brunswick OEL TWA (mg/m³) 0.1 mg/m³ (respirable fraction) Newfoundland & Labrador OEL TWA (mg/m³) 0.025 mg/m³ (respirable fraction) Nova Scotia OEL TWA (mg/m³) 0.025 mg/m³ (respirable fraction) Nunavut OEL TWA (mg/m³) 0.1 mg/m³ (respirable mass) Northwest Territories OEL TWA (mg/m³) 0.1 mg/m³ (respirable mass) Ontario OEL TWA (mg/m³) 0.10 mg/m³ (designated substances regulation-respirable) Prince Edward Island OEL TWA (mg/m³) 0.025 mg/m³ (respirable fraction) Québec VEMP (mg/m³) 0.1 mg/m³ (respirable dust) Saskatchewan OEL TWA (mg/m³) 0.05 mg/m³ (respirable fraction) Yukon OEL TWA (mg/m³) 300 particle/mL Limestone (1317-65-3) Mexico OEL TWA (mg/m³) 10 mg/m³ Mexico OEL STEL (mg/m³) 20 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³ (total dust) 5 mg/m³ (respirable fraction) USA NIOSH NIOSH REL (TWA) (mg/m³) 10 mg/m³ (total dust) 5 mg/m³ (respirable dust) Alberta OEL TWA (mg/m³) 10 mg/m³ British Columbia OEL STEL (mg/m³) 20 mg/m³ (total dust) British Columbia OEL TWA (mg/m³) 10 mg/m³ (total dust) New Brunswick OEL TWA (mg/m³) 10 mg/m³ (particulate matter containing no Asbestos and <1% Crystalline silica) Nunavut OEL TWA (mg/m³) 5 mg/m³ (respirable mass) Northwest Territories OEL TWA (mg/m³) 5 mg/m³ (respirable mass) Québec VEMP (mg/m³) 10 mg/m³ (Limestone, containing no Asbestos and <1% Crystalline silica-total dust) Saskatchewan OEL STEL (mg/m³) 20 mg/m³ Saskatchewan OEL TWA (mg/m³) 10 mg/m³ Yukon OEL STEL (mg/m³) 20 mg/m³ Yukon OEL TWA (mg/m³) 30 mppcf Gypsum (Ca(SO4).2H2O) (13397-24-5) Mexico OEL TWA (mg/m³) 10 mg/m³ (inhalable fraction) USA ACGIH ACGIH TWA (mg/m³) 10 mg/m³ (inhalable fraction) USA OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³ (total dust) 5 mg/m³ (respirable fraction) USA NIOSH NIOSH REL (TWA) (mg/m³) 10 mg/m³ (total dust) 5 mg/m³ (respirable dust) Gypsum Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations 04/15/15 EN (English US) 5/8 Alberta OEL TWA (mg/m³) 10 mg/m³ British Columbia OEL STEL (mg/m³) 20 mg/m³ (total dust) British Columbia OEL TWA (mg/m³) 10 mg/m³ (total dust) Manitoba OEL TWA (mg/m³) 10 mg/m³ (inhalable fraction) Newfoundland & Labrador OEL TWA (mg/m³) 10 mg/m³ (inhalable fraction) Nova Scotia OEL TWA (mg/m³) 10 mg/m³ (inhalable fraction) Nunavut OEL TWA (mg/m³) 5 mg/m³ (respirable mass) Northwest Territories OEL TWA (mg/m³) 5 mg/m³ (respirable mass) Ontario OEL TWA (mg/m³) 10 mg/m³ (inhalable) Prince Edward Island OEL TWA (mg/m³) 10 mg/m³ (inhalable fraction) Québec VEMP (mg/m³) 10 mg/m³ (containing no Asbestos and <1% Crystalline silica-total dust) Saskatchewan OEL STEL (mg/m³) 20 mg/m³ Saskatchewan OEL TWA (mg/m³) 10 mg/m³ Yukon OEL STEL (mg/m³) 20 mg/m³ Yukon OEL TWA (mg/m³) 30 mppcf Exposure Controls Appropriate Engineering Controls: Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Use local exhaust or general dilution ventilation or other suppression methods to maintain dust levels below exposure limits. Power equipment should be equipped with proper dust collection devices. Personal Protective Equipment: Gloves. In case of dust production: protective goggles. Insufficient ventilation: wear respiratory protection. Protective Clothing. Materials for Protective Clothing: Chemically resistant materials and fabrics. Hand Protection: Impermeable protective gloves. Eye Protection: Wear ANSI approved glasses or safety goggles when handling gypsum to prevent contact with eyes. Wearing contact lenses when using gypsum, under dusty conditions, is not recommended. Skin and Body Protection: Wear gloves, boot covers, and protective clothing impervious to water to prevent skin contact. Respiratory Protection: Wear a NIOSH approved respirator that is properly fitted and is in good condition when exposed to dust above exposure limits. Other Information: When using, do not eat, drink, or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Information on Basic Physical and Chemical Properties Physical State : Solid Appearance : White or off-white Odor : Odorless Odor Threshold : Not available pH : 5 - 8 Evaporation Rate : Not available Melting Point : Not available Freezing Point : Not available Boiling Point : > 1000 °C (1832 °F) Flash Point : Not available Auto-ignition Temperature : Not available Decomposition Temperature : Not available Flammability (solid, gas) : Not available Lower Flammable Limit : Not available Gypsum Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations 04/15/15 EN (English US) 6/8 Upper Flammable Limit : Not available Vapor Pressure : Not available Relative Vapor Density at 20 °C : Not available Relative Density : Not available Specific Gravity : 2.3 g/cm³ Solubility : Negligible Partition Coefficient: N-Octanol/Water : Not available Viscosity : Not available Explosion Data Sensitivity to Mechanical Impact : Not expected to present an explosion hazard due to mechanical impact. Explosion Data Sensitivity to Static Discharge : Not expected to present an explosion hazard due to static discharge. SECTION 10: STABILITY AND REACTIVITY Reactivity: Gypsum is incompatible with acids. Gypsum contains silicates which may react with powerful oxidizers such as fluorine, boron trifluoride, chlorine trifluoride, manganese trifluoride, and oxygen difluoride. Chemical Stability: Stable under recommended handling and storage conditions (see section 7). Possibility of Hazardous Reactions: Hazardous polymerization will not occur. Conditions to Avoid: Extremely high or low temperatures. Incompatible materials. Incompatible Materials: Oxidizers. Acids. Hazardous Decomposition Products: Thermal decomposition generates : Oxides of carbon. Oxides of calcium. Sulfur oxides. SECTION 11: TOXICOLOGICAL INFORMATION Information on Toxicological Effects - Product LD50 and LC50 Data: Not available Skin Corrosion/Irritation: Not classified pH:5 - 8 Serious Eye Damage/Irritation: Not classified pH:5 - 8 Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Teratogenicity: Not available Carcinogenicity: May cause cancer (Inhalation). Specific Target Organ Toxicity (Repeated Exposure): Causes damage to organs (lung/respiratory system, kidneys) through prolonged or repeated exposure (Inhalation). Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: The three types of silicosis include: 1) Simple chronic silicosis which results from long-term exposure (more than 20 years) to low amounts of respirable crystalline silica. Nodules of chronic inflammation and scarring provoked by the respirable crystalline silica form in the lungs and chest lymph nodes. This disease may feature breathlessness and may resemble chronic obstructive pulmonary disease (COPD); 2) Accelerated silicosis occurs after exposure to larger amounts of respirable crystalline silica over a shorter period of time (5-15 years); 3) Acute silicosis results from short-term exposure to very large amounts of respirable crystalline silica. The lungs become very inflamed and may fill with fluid, causing severe shortness of breath and low blood oxygen levels. Inflammation, scarring, and symptoms progress faster in accelerated silicosis than in simple silicosis. Progressive massive fibrosis may occur in simple or accelerated silicosis, but is more common in the accelerated form. Progressive massive fibrosis results from severe scarring and leads to the destruction of normal lung structures. Some studies show that exposure to respirable crystalline silica (without silicosis) or that the disease silicosis may be associated with the increased incidence of several autoimmune disorders such as scleroderma (thickening of the skin), systemic lupus erythematosus, rheumatoid arthritis and diseases affecting the kidneys. Silicosis increases the risk of tuberculosis. Some studies show an increased incidence of chronic kidney disease and end-stage renal disease in workers exposed to respirable crystalline silica. Irritating to mouth, nose, throat, and lungs, may cause difficulty in breathing. Symptoms/Injuries After Skin Contact: Aggregates may cause dry skin, abrasions, discomfort, and irritation. Acute Toxicity: Not classified Gypsum Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations 04/15/15 EN (English US) 7/8 Symptoms/Injuries After Eye Contact: Airborne dust may cause immediate or delayed irritation or inflammation. Eye contact with large amounts of gypsum can cause moderate eye irritation, redness, and abrasions. Eye exposures require immediate first aid. Symptoms/Injuries After Ingestion: Ingestion of large quantities can cause an obstruction causing pain and distress in the digestive tract. Chronic Symptoms: If dust is generated, repeated exposure through inhalation may cause cancer or lung disease. Causes damage to organs. Information on Toxicological Effects - Ingredient(s) LD50 and LC50 Data: Quartz (14808-60-7) LD50 Oral Rat > 5000 mg/kg LD50 Dermal Rat > 5000 mg/kg Quartz (14808-60-7) IARC Group 1 National Toxicology Program (NTP) Status Known Human Carcinogens. SECTION 12: ECOLOGICAL INFORMATION Toxicity No additional information available Persistence and Degradability Not available Bioaccumulative Potential Not available Mobility in Soil Not available Other Adverse Effects Not available SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, state, national, provincial, territorial and international regulations. Additional Information: If discarded in its purchased form, this product would not be a hazardous waste either by listing or characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. SECTION 14: TRANSPORT INFORMATION In Accordance with DOT Not regulated for transport In Accordance with IMDG Not regulated for transport In Accordance with IATA Not regulated for transport In Accordance with TDG Not regulated for transport SECTION 15: REGULATORY INFORMATION US Federal Regulations Quartz (14808-60-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory Limestone (1317-65-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory US State Regulations Quartz (14808-60-7) U.S. - California - Proposition 65 - Carcinogens List WARNING: This product contains chemicals known to the State of California to cause cancer. Quartz (14808-60-7) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Gypsum SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Gypsum Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations 04/15/15 EN (English US) 8/8 Limestone (1317-65-3) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Gypsum (Ca(SO4).2H2O) (13397-24-5) U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Canadian Regulations Quartz (14808-60-7) Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List) IDL Concentration 1 % WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Limestone (1317-65-3) Listed on the Canadian NDSL (Non-Domestic Substances List) WHMIS Classification Uncontrolled product according to WHMIS classification criteria This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision Date : 04/15/15 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200. GHS Full Text Phrases: ------ Carc. 1A Carcinogenicity Category 1A ------ STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1 ------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3 ------ H335 May cause respiratory irritation ------ H350 May cause cancer ------ H372 Causes damage to organs through prolonged or repeated exposure Party Responsible for the Preparation of This Document Lafarge North America Inc. +1 773-372-1000 (9am to 5pm CST) An electronic version of this SDS is available at: www.lafarge-na.com under the Sustainability and Products sections. Please direct any inquiries regarding the content of this SDS to SDSinfo@Lafarge.com. Lafarge North America Inc. (LNA) believes the information contained herein is accurate; however, LNA makes no guarantees with respect to such accuracy and assumes no liability in connection with the use of the information contained herein which is not intended to be and should not be construed as legal advice or as insuring compliance with any federal, state or local laws or regulations. Any party using this product should review all such laws, rules, or regulations prior to use, including but not limited to US and Canada Federal, Provincial and State regulations. NO WARRANTY IS MADE, EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, OR OTHERWISE. North America GHS US 2012 & WHMIS 2 Gypsum WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Safety Data Sheet Material Name: Gasoline All Grades SDS No. 9950 US GHS Synonyms: Hess Conventional (Oxygenated and Non-oxygenated) Gasoline; Reformulated Gasoline (RFG); Reformulated Gasoline Blendstock for Oxygenate Blending (RBOB); Unleaded Motor or Automotive Gasoline ____________________________________________________________ Page 1 of 16 Revision Date 8/30/12 * * * Section 1 - Product and Company Identification * * * Manufacturer Information Hess Corporation Phone: 732-750-6000 Corporate EHS 1 Hess Plaza Emergency # 800-424-9300 CHEMTREC Woodbridge, NJ 07095-0961 www.hess.com (Environment, Health, Safety Internet Website) * * * Section 2 - Hazards Identification * * * GHS Classification: Flammable Liquid - Category 2 Skin Corrosion/Irritation - Category 2 Germ Cell Mutagenicity - Category 1B Carcinogenicity - Category 1B Toxic to Reproduction - Category 1A Specific Target Organ Toxicity (Single Exposure) - Category 3 (respiratory irritation, narcosis) Specific Target Organ Toxicity (Repeat Exposure) - Category 1 (liver, kidneys, bladder, blood, bone marrow, nervous system) Aspiration Hazard - Category 1 Hazardous to the Aquatic Environment – Acute Hazard - Category 3 GHS LABEL ELEMENTS Symbol(s) Signal Word DANGER Hazard Statements Highly flammable liquid and vapour. Causes skin irritation. May cause genetic defects. May cause cancer. May damage fertility or the unborn child. May cause respiratory irritation. May cause drowsiness or dizziness. Causes damage to organs (liver, kidneys, bladder, blood, bone marrow, nervous system) through prolonged or repeated exposure. May be fatal if swallowed and enters airways. Harmful to aquatic life. Safety Data Sheet Material Name: Gasoline All Grades SDS No. 9950 ____________________________________________________________ Page 2 of 16 Revision Date 8/30/12 Precautionary Statements Prevention Keep away from heat/sparks/open flames/hot surfaces. No smoking Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. Wash hands and forearms thoroughly after handling. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe mist/vapours/spray. Use only outdoors or in well-ventilated area. Do not eat, drink or smoke when using this product. Avoid release to the environment. Response In case of fire: Use water spray, fog, dry chemical fire extinguishers or hand held fire extinguisher. IF ON SKIN (or hair): Wash with plenty of soap and water. Remove/Take off immediately all contaminated clothing and wash before reuse. If skin irritation occurs, get medical advice/attention. IF exposed or concerned: Get medical advice/attention. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor/physician if you feel unwell. Get medical advice/attention if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do not induce vomiting. Storage Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. * * * Section 3 - Composition / Information on Ingredients * * * CAS # Component Percent 86290-81-5 Gasoline, motor fuel 100 108-88-3 Toluene 1-25 106-97-8 Butane <10 1330-20-7 Xylenes (o-, m-, p- isomers) 1-15 95-63-6 Benzene, 1,2,4-trimethyl- <6 64-17-5 Ethyl alcohol 0-10 100-41-4 Ethylbenzene <3 71-43-2 Benzene 0.1-4.9 Safety Data Sheet Material Name: Gasoline All Grades SDS No. 9950 ____________________________________________________________ Page 3 of 16 Revision Date 8/30/12 110-54-3 Hexane 0.5-4 A complex blend of petroleum-derived normal and branched-chain alkane, cycloalkane, alkene, and aromatic hydrocarbons. May contain antioxidant and multifunctional additives. Non-oxygenated Conventional Gasoline and RBOB do not have oxygenates (Ethanol). Oxygenated Conventional and Reformulated Gasoline will have oxygenates for octane enhancement or as legally required. * * * Section 4 - First Aid Measures * * * First Aid: Eyes In case of contact with eyes, immediately flush with clean, low-pressure water for at least 15 min. Hold eyelids open to ensure adequate flushing. Seek medical attention. First Aid: Skin Remove contaminated clothing. Wash contaminated areas thoroughly with soap and water or with waterless hand cleanser. Obtain medical attention if irritation or redness develops. First Aid: Ingestion DO NOT INDUCE VOMITING. Do not give liquids. Obtain immediate medical attention. If spontaneous vomiting occurs, lean victim forward to reduce the risk of aspiration. Monitor for breathing difficulties. Small amounts of material which enter the mouth should be rinsed out until the taste is dissipated. First Aid: Inhalation Remove person to fresh air. If person is not breathing, provide artificial respiration. If necessary, provide additional oxygen once breathing is restored if trained to do so. Seek medical attention immediately. * * * Section 5 - Fire Fighting Measures * * * General Fire Hazards See Section 9 for Flammability Properties. Vapors may be ignited rapidly when exposed to heat, spark, open flame or other source of ignition. Flowing product may be ignited by self-generated static electricity. When mixed with air and exposed to an ignition source, flammable vapors can burn in the open or explode in confined spaces. Being heavier than air, vapors may travel long distances to an ignition source and flash back. Runoff to sewer may cause fire or explosion hazard. Hazardous Combustion Products Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke). Contact with nitric and sulfuric acids will form nitrocresols that can decompose violently. Extinguishing Media SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, CO2, water spray, fire fighting foam, or gaseous extinguishing agent. LARGE FIRES: Water spray, fog or fire fighting foam. Water may be ineffective for fighting the fire, but may be used to cool fire-exposed containers. Firefighting foam suitable for polar solvents is recommended for fuel with greater than 10% oxygenate concentration. Unsuitable Extinguishing Media None Safety Data Sheet Material Name: Gasoline All Grades SDS No. 9950 ____________________________________________________________ Page 4 of 16 Revision Date 8/30/12 Fire Fighting Equipment/Instructions Small fires in the incipient (beginning) stage may typically be extinguished using handheld portable fire extinguishers and other fire fighting equipment. Firefighting activities that may result in potential exposure to high heat, smoke or toxic by-products of combustion should require NIOSH/MSHA- approved pressure-demand self- contained breathing apparatus with full facepiece and full protective clothing. Isolate area around container involved in fire. Cool tanks, shells, and containers exposed to fire and excessive heat with water. For massive fires the use of unmanned hose holders or monitor nozzles may be advantageous to further minimize personnel exposure. Major fires may require withdrawal, allowing the tank to burn. Large storage tank fires typically require specially trained personnel and equipment to extinguish the fire, often including the need for properly applied fire fighting foam. * * * Section 6 - Accidental Release Measures * * * Recovery and Neutralization Carefully contain and stop the source of the spill, if safe to do so. Materials and Methods for Clean-Up Take up with sand or other oil absorbing materials. Carefully shovel, scoop or sweep up into a waste container for reclamation or disposal. Caution, flammable vapors may accumulate in closed containers. Emergency Measures Evacuate nonessential personnel and remove or secure all ignition sources. Consider wind direction; stay upwind and uphill, if possible. Evaluate the direction of product travel, diking, sewers, etc. to confirm spill areas. Spills may infiltrate subsurface soil and groundwater; professional assistance may be necessary to determine the extent of subsurface impact. Personal Precautions and Protective Equipment Response and clean-up crews must be properly trained and must utilize proper protective equipment (see Section 8). Environmental Precautions Protect bodies of water by diking, absorbents, or absorbent boom, if possible. Do not flush down sewer or drainage systems, unless system is designed and permitted to handle such material. The use of fire fighting foam may be useful in certain situations to reduce vapors. The proper use of water spray may effectively disperse product vapors or the liquid itself, preventing contact with ignition sources or areas/equipment that require protection. Prevention of Secondary Hazards None * * * Section 7 - Handling and Storage * * * Handling Procedures USE ONLY AS A MOTOR FUEL. DO NOT SIPHON BY MOUTH Handle as a flammable liquid. Keep away from heat, sparks, and open flame! Electrical equipment should be approved for classified area. Bond and ground containers during product transfer to reduce the possibility of static-initiated fire or explosion. Safety Data Sheet Material Name: Gasoline All Grades SDS No. 9950 ____________________________________________________________ Page 5 of 16 Revision Date 8/30/12 Special slow load procedures for "switch loading" must be followed to avoid the static ignition hazard that can exist when higher flash point material (such as fuel oil) is loaded into tanks previously containing low flash point products (such as this product) - see API Publication 2003, "Protection Against Ignitions Arising Out Of Static, Lightning and Stray Currents." Storage Procedures Keep away from flame, sparks, excessive temperatures and open flame. Use approved vented containers. Keep containers closed and clearly labeled. Empty product containers or vessels may contain explosive vapors. Do not pressurize, cut, heat, weld or expose such containers to sources of ignition. Store in a well-ventilated area. This storage area should comply with NFPA 30 "Flammable and Combustible Liquid Code". Avoid storage near incompatible materials. The cleaning of tanks previously containing this product should follow API Recommended Practice (RP) 2013 "Cleaning Mobile Tanks In Flammable and Combustible Liquid Service" and API RP 2015 "Cleaning Petroleum Storage Tanks". Incompatibilities Keep away from strong oxidizers. * * * Section 8 - Exposure Controls / Personal Protection * * * Component Exposure Limits Gasoline, motor fuel (86290-81-5) ACGIH: 300 ppm TWA 500 ppm STEL Toluene (108-88-3) ACGIH: 20 ppm TWA OSHA: 200 ppm TWA; 375 mg/m3 TWA 150 ppm STEL; 560 mg/m3 STEL NIOSH: 100 ppm TWA; 375 mg/m3 TWA 150 ppm STEL; 560 mg/m3 STEL Butane (106-97-8) ACGIH: 1000 ppm TWA (listed under Aliphatic hydrocarbon gases: Alkane C1-4) OSHA: 800 ppm TWA; 1900 mg/m3 TWA NIOSH: 800 ppm TWA; 1900 mg/m3 TWA Xylenes (o-, m-, p- isomers) (1330-20-7) ACGIH: 100 ppm TWA 150 ppm STEL OSHA: 100 ppm TWA; 435 mg/m3 TWA 150 ppm STEL; 655 mg/m3 STEL Benzene, 1,2,4-trimethyl- (95-63-6) NIOSH: 25 ppm TWA; 125 mg/m3 TWA Ethyl alcohol (64-17-5) ACGIH: 1000 ppm STEL OSHA: 1000 ppm TWA; 1900 mg/m3 TWA NIOSH: 1000 ppm TWA; 1900 mg/m3 TWA Safety Data Sheet Material Name: Gasoline All Grades SDS No. 9950 ____________________________________________________________ Page 6 of 16 Revision Date 8/30/12 Ethylbenzene (100-41-4) ACGIH: 20 ppm TWA OSHA: 100 ppm TWA; 435 mg/m3 TWA 125 ppm STEL; 545 mg/m3 STEL NIOSH: 100 ppm TWA; 435 mg/m3 TWA 125 ppm STEL; 545 mg/m3 STEL Benzene (71-43-2) ACGIH: 0.5 ppm TWA 2.5 ppm STEL Skin - potential significant contribution to overall exposure by the cutaneous route OSHA: 5 ppm STEL (Cancer hazard, Flammable, See 29 CFR 1910.1028, 15 min); 0.5 ppm Action Level; 1 ppm TWA NIOSH: 0.1 ppm TWA 1 ppm STEL Hexane (110-54-3) ACGIH: 50 ppm TWA Skin - potential significant contribution to overall exposure by the cutaneous route OSHA: 500 ppm TWA; 1800 mg/m3 TWA NIOSH: 50 ppm TWA; 180 mg/m3 TWA Engineering Measures Use adequate ventilation to keep vapor concentrations of this product below occupational exposure and flammability limits, particularly in confined spaces. Personal Protective Equipment: Respiratory A NIOSH/MSHA-approved air-purifying respirator with organic vapor cartridges or canister may be permissible under certain circumstances where airborne concentrations are or may be expected to exceed exposure limits or for odor or irritation. Protection provided by air-purifying respirators is limited. Use a positive pressure, air-supplied respirator if there is a potential for uncontrolled release, exposure levels are not known, in oxygen-deficient atmospheres, or any other circumstance where an air-purifying respirator may not provide adequate protection. Personal Protective Equipment: Hands Gloves constructed of nitrile, neoprene, or PVC are recommended. PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment: Eyes Safety glasses or goggles are recommended where there is a possibility of splashing or spraying. Personal Protective Equipment: Skin and Body Chemical protective clothing such as of E.I. DuPont TyChem®, Saranex® or equivalent recommended based on degree of exposure. Note: The resistance of specific material may vary from product to product as well as with degree of exposure. Consult manufacturer specifications for further information. Safety Data Sheet Material Name: Gasoline All Grades SDS No. 9950 ____________________________________________________________ Page 7 of 16 Revision Date 8/30/12 * * * Section 9 - Physical & Chemical Properties * * * Appearance: Translucent, straw-colored or light yellow Odor:Strong, characteristic aromatic hydrocarbon odor. Sweet-ether like Physical State: Liquid pH:ND Vapor Pressure: 6.4 - 15 RVP @ 100 °F (38 °C) (275-475 mm Hg @ 68 °F (20 °C) Vapor Density: AP 3-4 Boiling Point: 85-437 °F (39-200 °C) Melting Point: ND Solubility (H2O): Negligible to Slight Specific Gravity: 0.70-0.78 Evaporation Rate: 10-11 VOC:ND Percent Volatile:100% Octanol/H2O Coeff.: ND Flash Point: -45 °F (-43 °C) Flash Point Method: PMCC Upper Flammability Limit (UFL): 7.6% Lower Flammability Limit (LFL): 1.4% Burning Rate: ND Auto Ignition: >530°F (>280°C) * * * Section 10 - Chemical Stability & Reactivity Information * * * Chemical Stability This is a stable material. Hazardous Reaction Potential Will not occur. Conditions to Avoid Avoid high temperatures, open flames, sparks, welding, smoking and other ignition sources. Incompatible Products Keep away from strong oxidizers. Hazardous Decomposition Products Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke). Contact with nitric and sulfuric acids will form nitrocresols that can decompose violently. * * * Section 11 - Toxicological Information * * * Acute Toxicity A: General Product Information Harmful if swallowed. B: Component Analysis - LD50/LC50 Gasoline, motor fuel (86290-81-5) Inhalation LC50 Rat >5.2 mg/L 4 h; Oral LD50 Rat 14000 mg/kg; Dermal LD50 Rabbit >2000 mg/kg Toluene (108-88-3) Inhalation LC50 Rat 12.5 mg/L 4 h; Inhalation LC50 Rat >26700 ppm 1 h; Oral LD50 Rat 636 mg/kg; Dermal LD50 Rabbit 8390 mg/kg; Dermal LD50 Rat 12124 mg/kg Butane (106-97-8) Inhalation LC50 Rat 658 mg/L 4 h Safety Data Sheet Material Name: Gasoline All Grades SDS No. 9950 ____________________________________________________________ Page 8 of 16 Revision Date 8/30/12 Xylenes (o-, m-, p- isomers) (1330-20-7) Inhalation LC50 Rat 5000 ppm 4 h; Inhalation LC50 Rat 47635 mg/L 4 h; Oral LD50 Rat 4300 mg/kg; Dermal LD50 Rabbit >1700 mg/kg Benzene, 1,2,4-trimethyl- (95-63-6) Inhalation LC50 Rat 18 g/m3 4 h; Oral LD50 Rat 3400 mg/kg; Dermal LD50 Rabbit >3160 mg/kg Ethyl alcohol (64-17-5) Oral LD50 Rat 7060 mg/kg; Inhalation LC50 Rat 124.7 mg/L 4 h Ethylbenzene (100-41-4) Inhalation LC50 Rat 17.2 mg/L 4 h; Oral LD50 Rat 3500 mg/kg; Dermal LD50 Rabbit 15354 mg/kg Benzene (71-43-2) Inhalation LC50 Rat 13050-14380 ppm 4 h; Oral LD50 Rat 1800 mg/kg Hexane (110-54-3) Inhalation LC50 Rat 48000 ppm 4 h; Oral LD50 Rat 25 g/kg; Dermal LD50 Rabbit 3000 mg/kg Potential Health Effects: Skin Corrosion Property/Stimulativeness Practically non-toxic if absorbed following acute (single) exposure. May cause skin irritation with prolonged or repeated contact. Liquid may be absorbed through the skin in toxic amounts if large areas of skin are repeatedly exposed. Potential Health Effects: Eye Critical Damage/ Stimulativeness Moderate irritant. Contact with liquid or vapor may cause irritation. Potential Health Effects: Ingestion Ingestion may cause gastrointestinal disturbances, including irritation, nausea, vomiting and diarrhea, and central nervous system (brain) effects similar to alcohol intoxication. In severe cases, tremors, convulsions, loss of consciousness, coma, respiratory arrest, and death may occur. Potential Health Effects: Inhalation Excessive exposure may cause irritations to the nose, throat, lungs and respiratory tract. Central nervous system (brain) effects may include headache, dizziness, loss of balance and coordination, unconsciousness, coma, respiratory failure, and death. WARNING: the burning of any hydrocarbon as a fuel in an area without adequate ventilation may result in hazardous levels of combustion products, including carbon monoxide, and inadequate oxygen levels, which may cause unconsciousness, suffocation, and death. Respiratory Organs Sensitization/Skin Sensitization This product is not reported to have any skin sensitization effects. Generative Cell Mutagenicity This product may cause genetic defects. Carcinogenicity A: General Product Information May cause cancer. Safety Data Sheet Material Name: Gasoline All Grades SDS No. 9950 ____________________________________________________________ Page 9 of 16 Revision Date 8/30/12 IARC has determined that gasoline and gasoline exhaust are possibly carcinogenic in humans. Inhalation exposure to completely vaporized unleaded gasoline caused kidney cancers in male rats and liver tumors in female mice. The U.S. EPA has determined that the male kidney tumors are species-specific and are irrelevant for human health risk assessment. The significance of the tumors seen in female mice is not known. Exposure to light hydrocarbons in the same boiling range as this product has been associated in animal studies with effects to the central and peripheral nervous systems, liver, and kidneys. The significance of these animal models to predict similar human response to gasoline is uncertain. This product contains benzene. Human health studies indicate that prolonged and/or repeated overexposure to benzene may cause damage to the blood-forming system (particularly bone marrow), and serious blood disorders such as aplastic anemia and leukemia. Benzene is listed as a human carcinogen by the NTP, IARC, OSHA and ACGIH. B: Component Carcinogenicity Gasoline, motor fuel (86290-81-5) ACGIH: A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans Toluene (108-88-3) ACGIH: A4 - Not Classifiable as a Human Carcinogen IARC: Monograph 71 [1999]; Monograph 47 [1989] (Group 3 (not classifiable)) Xylenes (o-, m-, p- isomers) (1330-20-7) ACGIH: A4 - Not Classifiable as a Human Carcinogen IARC: Monograph 71 [1999]; Monograph 47 [1989] (Group 3 (not classifiable)) Ethyl alcohol (64-17-5) ACGIH: A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans IARC: Monograph 100E [in preparation] (in alcoholic beverages); Monograph 96 [2010] (in alcoholic beverages) (Group 1 (carcinogenic to humans)) Ethylbenzene (100-41-4) ACGIH: A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans IARC: Monograph 77 [2000] (Group 2B (possibly carcinogenic to humans)) Benzene (71-43-2) ACGIH: A1 - Confirmed Human Carcinogen OSHA: 5 ppm STEL (Cancer hazard, Flammable, See 29 CFR 1910.1028, 15 min); 0.5 ppm Action Level; 1 ppm TWA NIOSH: potential occupational carcinogen NTP: Known Human Carcinogen (Select Carcinogen) IARC: Monograph 100F [in preparation]; Supplement 7 [1987]; Monograph 29 [1982] (Group 1 (carcinogenic to humans)) Reproductive Toxicity This product is suspected of damaging fertility or the unborn child. Specified Target Organ General Toxicity: Single Exposure This product may cause drowsiness or dizziness. Safety Data Sheet Material Name: Gasoline All Grades SDS No. 9950 ____________________________________________________________ Page 10 of 16 Revision Date 8/30/12 Specified Target Organ General Toxicity: Repeated Exposure This product causes damage to organs through prolonged or repeated exposure. Aspiration Respiratory Organs Hazard The major health threat of ingestion occurs from the danger of aspiration (breathing) of liquid drops into the lungs, particularly from vomiting. Aspiration may result in chemical pneumonia (fluid in the lungs), severe lung damage, respiratory failure and even death. * * * Section 12 - Ecological Information * * * Ecotoxicity A: General Product Information Very toxic to aquatic life with long lasting effects. Keep out of sewers, drainage areas and waterways. Report spills and releases, as applicable, under Federal and State regulations. B: Component Analysis - Ecotoxicity - Aquatic Toxicity Gasoline, motor fuel (86290-81-5) Test & Species Conditions 96 Hr LC50 Alburnus alburnus 119 mg/L [static] 96 Hr LC50 Cyprinodon variegatus 82 mg/L [static] 72 Hr EC50 Pseudokirchneriella subcapitata 56 mg/L 24 Hr EC50 Daphnia magna 170 mg/L Toluene (108-88-3) Test & Species Conditions 96 Hr LC50 Pimephales promelas 15.22-19.05 mg/L [flow-through] 1 day old 96 Hr LC50 Pimephales promelas 12.6 mg/L [static] 96 Hr LC50 Oncorhynchus mykiss 5.89-7.81 mg/L [flow-through] 96 Hr LC50 Oncorhynchus mykiss 14.1-17.16 mg/L [static] 96 Hr LC50 Oncorhynchus mykiss 5.8 mg/L [semi- static] 96 Hr LC50 Lepomis macrochirus 11.0-15.0 mg/L [static] 96 Hr LC50 Oryzias latipes 54 mg/L [static] 96 Hr LC50 Poecilia reticulata 28.2 mg/L [semi- static] 96 Hr LC50 Poecilia reticulata 50.87-70.34 mg/L [static] 96 Hr EC50 Pseudokirchneriella subcapitata >433 mg/L 72 Hr EC50 Pseudokirchneriella subcapitata 12.5 mg/L [static] 48 Hr EC50 Daphnia magna 5.46 - 9.83 mg/L [Static] 48 Hr EC50 Daphnia magna 11.5 mg/L Xylenes (o-, m-, p- isomers) (1330-20-7) Test & Species Conditions 96 Hr LC50 Pimephales promelas 13.4 mg/L [flow- through] Safety Data Sheet Material Name: Gasoline All Grades SDS No. 9950 ____________________________________________________________ Page 11 of 16 Revision Date 8/30/12 96 Hr LC50 Oncorhynchus mykiss 2.661-4.093 mg/L [static] 96 Hr LC50 Oncorhynchus mykiss 13.5-17.3 mg/L 96 Hr LC50 Lepomis macrochirus 13.1-16.5 mg/L [flow-through] 96 Hr LC50 Lepomis macrochirus 19 mg/L 96 Hr LC50 Lepomis macrochirus 7.711-9.591 mg/L [static] 96 Hr LC50 Pimephales promelas 23.53-29.97 mg/L [static] 96 Hr LC50 Cyprinus carpio 780 mg/L [semi- static] 96 Hr LC50 Cyprinus carpio >780 mg/L 96 Hr LC50 Poecilia reticulata 30.26-40.75 mg/L [static] 48 Hr EC50 water flea 3.82 mg/L 48 Hr LC50 Gammarus lacustris 0.6 mg/L Benzene, 1,2,4-trimethyl- (95-63-6) Test & Species Conditions 96 Hr LC50 Pimephales promelas 7.19-8.28 mg/L [flow-through] 48 Hr EC50 Daphnia magna 6.14 mg/L Ethyl alcohol (64-17-5) Test & Species Conditions 96 Hr LC50 Oncorhynchus mykiss 12.0 - 16.0 mL/L [static] 96 Hr LC50 Pimephales promelas >100 mg/L [static] 96 Hr LC50 Pimephales promelas 13400 - 15100 mg/L [flow-through] 48 Hr LC50 Daphnia magna 9268 - 14221 mg/L 24 Hr EC50 Daphnia magna 10800 mg/L 48 Hr EC50 Daphnia magna 2 mg/L [Static] Ethylbenzene (100-41-4) Test & Species Conditions 96 Hr LC50 Oncorhynchus mykiss 11.0-18.0 mg/L [static] 96 Hr LC50 Oncorhynchus mykiss 4.2 mg/L [semi- static] 96 Hr LC50 Pimephales promelas 7.55-11 mg/L [flow- through] 96 Hr LC50 Lepomis macrochirus 32 mg/L [static] 96 Hr LC50 Pimephales promelas 9.1-15.6 mg/L [static] 96 Hr LC50 Poecilia reticulata 9.6 mg/L [static] 72 Hr EC50 Pseudokirchneriella subcapitata 4.6 mg/L 96 Hr EC50 Pseudokirchneriella subcapitata >438 mg/L 72 Hr EC50 Pseudokirchneriella subcapitata 2.6 - 11.3 mg/L [static] Safety Data Sheet Material Name: Gasoline All Grades SDS No. 9950 ____________________________________________________________ Page 12 of 16 Revision Date 8/30/12 96 Hr EC50 Pseudokirchneriella subcapitata 1.7 - 7.6 mg/L [static] 48 Hr EC50 Daphnia magna 1.8 - 2.4 mg/L Benzene (71-43-2) Test & Species Conditions 96 Hr LC50 Pimephales promelas 10.7-14.7 mg/L [flow-through] 96 Hr LC50 Oncorhynchus mykiss 5.3 mg/L [flow- through] 96 Hr LC50 Lepomis macrochirus 22.49 mg/L [static] 96 Hr LC50 Poecilia reticulata 28.6 mg/L [static] 96 Hr LC50 Pimephales promelas 22330-41160 µg/L [static] 96 Hr LC50 Lepomis macrochirus 70000-142000 µg/L [static] 72 Hr EC50 Pseudokirchneriella subcapitata 29 mg/L 48 Hr EC50 Daphnia magna 8.76 - 15.6 mg/L [Static] 48 Hr EC50 Daphnia magna 10 mg/L Hexane (110-54-3) Test & Species Conditions 96 Hr LC50 Pimephales promelas 2.1-2.98 mg/L [flow- through] 24 Hr EC50 Daphnia magna >1000 mg/L Persistence/Degradability No information available. Bioaccumulation No information available. Mobility in Soil No information available. * * * Section 13 - Disposal Considerations * * * Waste Disposal Instructions See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations. Disposal of Contaminated Containers or Packaging Dispose of contents/container in accordance with local/regional/national/international regulations. Safety Data Sheet Material Name: Gasoline All Grades SDS No. 9950 ____________________________________________________________ Page 13 of 16 Revision Date 8/30/12 * * * Section 14 - Transportation Information * * * Component Marine Pollutants This material contains one or more of the following chemicals required by US DOT to be identified as marine pollutants. Component CAS # Gasoline, motor fuel 86290-81-5 DOT regulated marine pollutant DOT Information Shipping Name: Gasoline UN #: 1203 Hazard Class: 3 Packing Group: II Placard: * * * Section 15 - Regulatory Information * * * Regulatory Information A: Component Analysis This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4). Toluene (108-88-3) SARA 313: 1.0 % de minimis concentration CERCLA: 1000 lb final RQ; 454 kg final RQ Xylenes (o-, m-, p- isomers) (1330-20-7) SARA 313: 1.0 % de minimis concentration CERCLA: 100 lb final RQ; 45.4 kg final RQ Benzene, 1,2,4-trimethyl- (95-63-6) SARA 313: 1.0 % de minimis concentration Ethylbenzene (100-41-4) SARA 313: 0.1 % de minimis concentration CERCLA: 1000 lb final RQ; 454 kg final RQ Benzene (71-43-2) SARA 313: 0.1 % de minimis concentration CERCLA: 10 lb final RQ (received an adjusted RQ of 10 lbs based on potential carcinogenicity in an August 14, 1989 final rule); 4.54 kg final RQ (received an adjusted RQ of 10 lbs based on potential carcinogenicity in an August 14, 1989 final rule) Safety Data Sheet Material Name: Gasoline All Grades SDS No. 9950 ____________________________________________________________ Page 14 of 16 Revision Date 8/30/12 Hexane (110-54-3) SARA 313: 1.0 % de minimis concentration CERCLA: 5000 lb final RQ; 2270 kg final RQ SARA Section 311/312 – Hazard Classes Acute Health Chronic Health Fire Sudden Release of Pressure Reactive X X X ---- Component Marine Pollutants This material contains one or more of the following chemicals required by US DOT to be identified as marine pollutants. Component CAS # Gasoline, motor fuel 86290-81-5 DOT regulated marine pollutant State Regulations Component Analysis - State The following components appear on one or more of the following state hazardous substances lists: Component CAS CA MA MN NJ PA RI Gasoline, motor fuel 86290-81-5 No No No No Yes No Toluene 108-88-3 Yes Yes Yes Yes Yes No Butane 106-97-8 Yes Yes Yes Yes Yes No Xylenes (o-, m-, p- isomers) 1330-20-7 Yes Yes Yes Yes Yes No Benzene, 1,2,4-trimethyl- 95-63-6 No Yes Yes Yes Yes No Ethyl alcohol 64-17-5 Yes Yes Yes Yes Yes No Ethylbenzene 100-41-4 Yes Yes Yes Yes Yes No Benzene 71-43-2 Yes Yes Yes Yes Yes No Hexane 110-54-3 No Yes Yes Yes Yes No The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): WARNING! This product contains a chemical known to the state of California to cause cancer. WARNING! This product contains a chemical known to the state of California to cause reproductive/developmental effects. Safety Data Sheet Material Name: Gasoline All Grades SDS No. 9950 ____________________________________________________________ Page 15 of 16 Revision Date 8/30/12 Component Analysis - WHMIS IDL The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List: Component CAS #Minimum Concentration Toluene 108-88-3 1 % Butane 106-97-8 1 % Benzene, 1,2,4-trimethyl- 95-63-6 0.1 % Ethyl alcohol 64-17-5 0.1 % Ethylbenzene 100-41-4 0.1 % Benzene 71-43-2 0.1 % Hexane 110-54-3 1 % Additional Regulatory Information Component Analysis - Inventory Component CAS #TSCA CAN EEC Gasoline, motor fuel 86290-81-5 No DSL EINECS Toluene 108-88-3 Yes DSL EINECS Butane 106-97-8 Yes DSL EINECS Xylenes (o-, m-, p- isomers) 1330-20-7 Yes DSL EINECS Benzene, 1,2,4-trimethyl- 95-63-6 Yes DSL EINECS Ethyl alcohol 64-17-5 Yes DSL EINECS Ethylbenzene 100-41-4 Yes DSL EINECS Benzene 71-43-2 Yes DSL EINECS Hexane 110-54-3 Yes DSL EINECS * * * Section 16 - Other Information * * * NFPA® Hazard Rating Health 2 Fire 3 Reactivity 0 HMIS® Hazard Rating Health 2 Moderate Fire 3 Serious Physical 0 Minimal *Chronic 3 02 Key/Legend EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration., NJTSR = New Jersey Trade Secret Registry. Literature References None Safety Data Sheet Material Name: Gasoline All Grades SDS No. 9950 ____________________________________________________________ Page 16 of 16 Revision Date 8/30/12 Other Information Information presented herein has been compiled from sources considered to be dependable, and is accurate and reliable to the best of our knowledge and belief, but is not guaranteed to be so. Since conditions of use are beyond our control, we make no warranties, expressed or implied, except those that may be contained in our written contract of sale or acknowledgment. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material, even if reasonable safety procedures are followed. Furthermore, vendee assumes the risk in their use of the material. End of Sheet