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HomeMy WebLinkAboutRA-2200_13649_CA_MRP_20230428 ENVIRONMENTAL | CIVIL | GEOTECHNICAL MONITORING REPORT BUD’S SERVICE CENTER 101 SOUTH PARKER STREET ELM CITY, WILSON COUNTY, NC NCDEQ INCIDENT NO. 13649 RISK CLASSIFICATION: H030E APRIL 28, 2023 NCDEQ CONTRACT NO. N122019D TASK AUTHORIZATION NO. 02 CATLIN PROJECT NO. 221048 PREPARED FOR: MS. LINDA BLALOCK NCDEQ, DWM, UST SECTION 1646 MAIL SERVICE CENTER RALEIGH, NC 27699-1646 PREPARED BY: CATLIN ENGINEERS AND SCIENTISTS 220 OLD DAIRY ROAD WILMINGTON, NC 28405 (910) 452-5861 CORPORATE LICENSURE NO. FOR ENGINEERING SERVICES C-0585 CORPORATE LICENSURE NO. FOR GEOLOGY SERVICES C-118 NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 April 2023 TABLE OF CONTENTS PAGE 1.0 SITE INFORMATION 1 2.0 EXECUTIVE SUMMARY 2 3.0 SCOPE OF SERVICES 3 4.0 SITE HISTORY AND CHARACTERIZATION 3 4.1 UST OWNER AND OPERATOR INFORMATION 3 4.2 UST INFORMATION 3 4.3 CONTAMINANT SOURCE INVENTORY 4 4.4 SITE CHARACTERISTICS 4 4.5 OWNERS AND OCCUPANTS OF ADJOINING/NEARBY PROPERTIES AND LAND USE 4 4.6 RECEPTOR INFORMATION 4 4.7 PREVIOUS INVESTIGATIONS AND REMEDIAL ACTIVITIES 4 5.0 REGIONAL AND SITE GEOLOGY AND HYDROGEOLOGY 6 5.1 SOIL AND BEDROCK 6 5.2 HYDROGEOLOGY 6 6.0 SITE ASSESSMENT INFORMATION 6 6.1 AFVR EVENT 7 6.2 GAUGING DATA 7 6.3 SAMPLING DATA 8 6.4 SUMMARY OF GROUNDWATER INFORMATION 9 6.5 EVALUATION OF ASSESSMENT INFORMATION 10 7.0 CONCLUSIONS AND RECOMMENDATIONS 10 8.0 STATEMENTS AND CERTIFICATION 11 9.0 LIMITATIONS 12 10.0 REFERENCES 12 NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 April 2023 TABLES TABLE 1 SITE HISTORY – UST AND OTHER RELEASE INFORMATION TABLE 2 PUBLIC AND PRIVATE WATER SUPPLY WELLS AND OTHER RECEPTOR INFORMATION TABLE 3 WELL CONSTRUCTION AND HISTORICAL WATER LEVEL GAUGING DATA TABLE 4 SUMMARY OF GROUNDWATER LABORATORY RESULTS – STANDARD METHOD 6200B TABLE 5 SUMMARY OF HISTORICAL GROUNDWATER LABORATORY RESULTS – STANDARD METHOD 6200B FIGURES FIGURE 1 SITE VICINITY MAP FIGURE 2 POTENTIAL RECEPTOR MAP FIGURE 3 SITE MAP FIGURE 4 GROUNDWATER ELEVATION – APRIL 3, 2023 FIGURE 5 MONITORING WELL GROUNDWATER SAMPLE ANALYTICAL RESULTS – APRIL 3, 2023 FIGURE 6 ESTIMATED HORIZONTAL EXTENT OF BENZENE – APRIL 3, 2023 APPENDICES APPENDIX A HISTORICAL DATA APPENDIX B SITE PHOTOGRAPHS APPENDIX C JOB HAZARD ANALYSES AND FIELD DATA SHEETS APPENDIX D EMISSIONS CALCULATIONS APPENDIX E DISPOSAL DOCUMENTS APPENDIX F LABORATORY ANALYTICAL REPORT AND CHAIN OF CUSTODY DOCUMENT NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 1 April 2023 1.0 SITE INFORMATION Site Identification Date: 04/28/2023 Site Risk/Priority Rank: H030E UST Number: RA-2200 Incident Number: 13649 Site Name: Bud’s Service Center Facility ID: 0-06477 Site Location: 101 South Parker Street Nearest City/Town: Elm City County: Wilson Description of Geographical Data Point: Former UST basin Location Method: Google Earth Latitude (decimal degrees): 35.806233° Longitude (decimal degrees): -77.863178° Contacts Information UST Owner: Sharpe Oil Company (dissolved) Address: Not Applicable Phone: Not Applicable UST Operator: Sharpe Oil Company (dissolved) Address: Not Applicable Phone: Not Applicable Property Owner: Salim Addi Salif Address: 402 W Wilson St, Elm City, NC 27822-8723 Phone: Unknown Property Occupant: Vacant Address: 101 S Parker St., Elm City, NC 27822 Phone: Unknown Consultant: CATLIN Engineers and Scientists Address: 220 Old Dairy Rd., Wilmington, NC 28405 Phone: (910) 452-5861 Corporate Licensure No. For Engineering Services: C-0585 Corporate Geology License No.: C-118 Analytical Laboratory: Con-Test Analytical Laboratory State Certification: NC 652, NC-DW 25703 Address: 39 Spruce St., E. Longmeadow, MA 01028 Phone: (413) 525-2332 Release Information Date Discovered: 03/17/1994 Estimated Quantity of Release: Unknown Cause of Release: Leak in the UST system Source of Release: UST system or associated fitting(s) Sizes and contents of UST system(s) from which the release occurred: • Three 1,000-gallon gasoline USTs NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 2 April 2023 2.0 EXECUTIVE SUMMARY The Bud’s Service Center site is located at 101 South Parker Street, Elm City, Wilson County, North Carolina. Three underground storage tanks (USTs) were previously operated at the site. The three 1,000-gallon gasoline USTs were removed from the site in 1994. A petroleum release was discovered during tank closure activities. The purpose of this report is to document the latest remediation efforts and groundwater sampling event. On February 22, 2023, CATLIN Engineers and Scientists (CATLIN) personnel coordinated with Eastern Environmental Management (EEM) to conduct an aggressive fluid vapor recovery (AFVR) event. Light non-aqueous phase liquid (LNAPL; aka free product) was measured in both MW-1 (0.36 feet thick) and MW-4 (0.31 feet thick). A total of 2,779 gallons of impacted groundwater and LNAPL were removed along with a calculated 0.860 pounds of petroleum vapors (equivalent to 0.138 gallons of petroleum). CATLIN returned to the site on April 3, 2023 and measured groundwater at approximately three feet deep across the site. LNAPL was not measured in any of the monitoring wells. Groundwater samples from five monitoring wells (MW-1, MW-2, MW-3, MW-4, and MW-5) were collected and were submitted for laboratory analysis of volatile organic compounds (VOCs) per Standard Method (SM) 6200B plus ethylene dibromide (EDB), methyl tert-butyl ether (MTBE), and diisopropyl ether (DIPE). Laboratory results did not indicate any dissolved petroleum constituents above their respective reporting limits in the sample from MW-3. Several VOCs were detected in the MW-1, MW-2, MW-4, and MW-5 samples at concentrations greater than those established in Title 15A of the North Carolina Administrative Code, Subchapter 2L, Section .0202 Groundwater Quality Standards (2L GWQS), but below the Gross Contaminant Levels (GCL). The groundwater samples collected from monitoring wells MW-2 and MW-5 revealed contaminant concentrations lower than those detected during the June 2021 event (CATLIN, 2021). CATLIN recommends to: • Conducting a High Resolution Site Characterization (HRSC) evaluation at the site to determine if LNAPL is present at the site; • Conduct a vapor intrusion screening assessment for the buildings in/near the impacted groundwater plume; and • Conduct a semi-annual sampling event in October 2023. NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 3 April 2023 3.0 SCOPE OF SERVICES The scope of services for this report was performed in general accordance with CATLIN proposal number 221048.2P, dated February 9, 2023. Services were authorized by the North Carolina Department of Environmental Quality’s (NCDEQ’s) Task Authorization (TA) #02, accepted on February 10, 2023, and Contract Number N122019D. The approved scope of services for this Task Authorization included: • Coordinate and oversee an AFVR event; • Approximately two weeks after the AFVR event, collect groundwater samples from five monitoring wells (MW-1 through MW-5); • Analyze seven water samples (five monitoring well samples, one equipment rinsate blank, and one trip blank) according to SM 6200B (including EDB, MTBE, and DIPE); and, • Prepare and submit a monitoring report summarizing the findings. An additional 279 gallons of impacted groundwater (than what was approved in the TA) were collected, with the approval of the NCDEQ Project Manager via phone on February 22, 2023. The remaining scope of services was conducted in general accordance with the approved TA. 4.0 SITE HISTORY AND CHARACTERIZATION The Bud’s Service Center site is located at 101 South Parker Street, Elm City, Wilson County, North Carolina (Figures 1 and 2). Summarized available historical sampling and gauging data from previous consultants are provided in Appendix A. Recent site photographs are presented in Appendix B. 4.1 UST OWNER AND OPERATOR INFORMATION Sharpe Oil Company historically owned and/or operated the former on-site tanks. Sharpe Oil Company is dissolved, and the site is currently in the North Carolina UST Section Trust Fund Branch State Lead Program (S&ME, 2018). Available information regarding UST owners/operators and is presented on Table 1. 4.2 UST INFORMATION Three 1,000-gallon gasoline USTs were previously operated on-site for retail petroleum sales. The tanks were removed in March 1994 (UTTS, 1994). Available UST system information is presented in Table 1 and the approximate former UST system location is illustrated on Figure 3. NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 4 April 2023 4.3 CONTAMINANT SOURCE INVENTORY An on-site release was discovered in 1994 during UST removal activities. Soil sample analytical results revealed total petroleum hydrocarbons (TPH) gasoline range organics (GRO) above the State Action Level (UTTS, 1994). 4.4 SITE CHARACTERISTICS The property is currently owned by Salim Addi Salif. The on-site structure is currently vacant. The parcel is comprised of the store structure, paved parking lot, and grassy area used as storage. 4.5 OWNERS AND OCCUPANTS OF ADJOINING/NEARBY PROPERTIES AND LAND USE Properties in the site vicinity are mostly commercial businesses and residences. Businesses surround the site. South Parker Street and East Main Street border the site to the west and north, respectively. 4.6 RECEPTOR INFORMATION Conducting a receptor survey was outside the scope of this monitoring event. According to previous reports, municipal water is available to the site vicinity. Four non-potable wells and two streams are located within 1,500 feet of the site. No non-potable wells are located within 250 feet of the subject site. The closest non-potable well (WSW-2) is located 912 feet from the site, the other three wells are more than 1,000 feet from the site (S&ME, 2018). Potential receptors are illustrated on Figure 2 and receptor information is shown on Table 2. 4.7 PREVIOUS INVESTIGATIONS AND REMEDIAL ACTIVITIES Historical files available on the NCDEQ Waste Management Online Database (aka Laserfiche) are limited. A summary of previous investigations and remedial activities indicated in available files is provided herein. The release was discovered in 1994 during UST closure activities by UTTS/Environmental (UTTS). Soil samples obtained during the closure reportedly contained TPH GRO concentrations up to 250 parts per million (ppm). A Comprehensive Site Assessment (CSA) was recommended at the time (UTTS, 1994). However, it is unclear that any further investigation and remediation was conducted at the site until a Limited Site Assessment (LSA) was performed in 2009 by Force Environmental Service Company, LLC (Force). During LSA activities, monitoring well MW-1 was installed and sampled. A soil sample was also obtained from the MW-1 boring. Soil sample analytical NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 5 April 2023 results revealed several targeted analytes at concentrations above their Soil-to-Groundwater (STGW) Maximum Soil Contaminant Concentrations (MSCC), but below Residential MSCC. The groundwater sample collected from MW-1 contained multiple targeted analytes above 2L GWQS and benzene above GCL (Force, 2009). Further soil sampling in the vicinity of the former dispenser island was conducted by S&ME, Inc. (S&ME) in June 2012. Soil samples reportedly contained several constituents at concentrations above STGW MSCC (S&ME, 2015). In August 2011, four additional monitoring wells (MW-2 through MW-5) were installed at the site. LNAPL was measured in MW-1 during 2011 field activities and S&ME subsequently performed a free product bail-down test in MW-1 in June 2012. The results of the bail-down test indicated that vacuum extraction events would not be an effective technology for LNAPL recovery at the site (S&ME, 2015). Since 2009, periodic groundwater monitoring events have been conducted at the site. The highest concentrations of benzene, ethylbenzene, toluene, and total xylenes (BTEX) compounds have been reported in samples from MW-1, MW-4, and MW-5. Several petroleum constituents have historically been reported above 2L GWQS in samples from all permanent on-site wells (MW-1 through MW-5). Additionally, benzene has been previously reported at concentrations above GCL in samples from MW-1, MW-4, and MW-5 (S&ME, 2018). In May 2018, temporary monitoring wells MW-6 through MW-8 were installed and sampled; the permanent well network was also sampled. Laboratory analytical results from the 2018 sampling event indicated that BTEX compound concentrations have generally decreased since 2009. However, several VOCs were detected above their 2L GWQS in the samples from MW-1, MW-2, MW-4, MW-5, MW-6, and MW-8. LNAPL was not encountered during the 2018 sampling event (S&ME, 2018). CATLIN conducted a monitoring event in June 2021. The average depth to groundwater was shallow at approximately three feet deep. LNAPL was measured in monitoring wells MW-1 (0.32 feet thick) and MW-4 (0.39 feet thick); this was the first time LNAPL has been recorded at the site since 2012. Groundwater samples from the remaining three monitoring wells (MW-2, MW-3, and MW-5) were analyzed. Laboratory results did not indicate any targeted analytes above their reporting limits in the MW-3 sample. Several VOCs were detected in the MW-2 and MW-5 samples at concentrations above 2L GWQS but below GCL (CATLIN, 2021). Summarized historical data prepared by previous consultants are presented in Appendix A. Site photographs and included in Appendix B. NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 6 April 2023 5.0 REGIONAL AND SITE GEOLOGY AND HYDROGEOLOGY 5.1 SOIL AND BEDROCK As defined in the Geologic Map of North Carolina, published by the North Carolina Department of Natural Resources and Community Development (1985), the site lies within the Coastal Plain physiographic province. The North Carolina Coastal Plain is approximately 90 to 150 miles wide from the Atlantic Ocean westward to its boundary with the Piedmont province. Two natural subdivisions of the Coastal Plain were described by Stuckey (1965): the Tidewater region and the Inner Coastal Plain. The project area is located within the Inner Coastal Plain, which is an area of erosional topography (Horton and Zullo, 1991). The Coastal Plain comprises a wedge-shaped sequence of stratified marine and non-marine sedimentary rocks deposited on crystalline basement. The sedimentary sequences range in age from Recent to lower Cretaceous (Narkunas, 1980). The site is underlain by the Yorktown and Duplin Formations. Fossil-bearing clay with sand, lenses of shell material, shelly sand, and sandy marl crop in the site area (NCDENR, 1985). According to UTTS (1994), the soil in the vicinity of the UST basin was tan silty clay. 5.2 HYDROGEOLOGY Groundwater - The 2020 Visual Hydrogeologic Framework – North Carolina Hydrogeological Database did not identify sufficient boreholes near the site in order to draw a cross-section. Surface Water – Two streams are located within 1,500 feet of the site; one is located 1,220 to the north and the other is 1,344 feet to the south (S&ME, 2018). 6.0 SITE ASSESSMENT INFORMATION CATLIN conducted field activities on February 22 and April 3, 2023 in accordance with the approved TA and pre-prepared Health and Safety Plan (HASP). Upon arrival at the site, potential hazards were evaluated before beginning field work and are documented on electronic Job Hazard Analysis (JHA) forms. The JHA forms are included in Appendix C. Photographs from the site visits are included in Appendix B. CATLIN personnel supervised the performance of the AFVR during the February event and then returned for the April event in which they gauged and collected groundwater samples for laboratory analysis of VOCs per SM 6200B from five monitoring wells (MW-1, MW-2, MW-3, MW-4, and MW-5). Well locations and site NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 7 April 2023 features are shown on Figure 3 and well construction details are presented on Table 3. 6.1 AFVR EVENT CATLIN mobilized to the site on February 22, 2023 to supervise an AFVR event conducted by EEM. The event was conducted for a duration of eight hours utilizing monitoring wells MW-1 and MW-4 as extraction points. Prior to the event, CATLIN personnel gauged the monitoring wells and the depth to water was 3.10 feet below top of casing (BTOC) in MW-1 and 2.60 feet BTOC in MW-4. LNAPL was measured in both MW-1 (0.36 feet thick) and MW-4 (0.31 feet thick). Following the event, there was no measurable LNAPL in MW-1 and 0.01 feet in MW-4. A total of 2,779 gallons of impacted groundwater and LNAPL were removed from the subsurface. The vacuum at the recovery pump maintained and stabilized at approximately 20 inches of mercury. Airflow rates ranged from 13 to 312 feet per minute. The system temperature ranged from 60.4 to 167.6 degrees Fahrenheit and humidity ranged from 75.8 to 100 percent. Field-gauged VOCs ranged from 197 to 2,871 ppm throughout the event. A calculated 0.860 pounds of petroleum vapors were emitted during this event, equivalent to approximately 0.138 gallons of petroleum. The average rate of liquid recovery was 347 gallons per hour. Gauging results are presented on Table 3. Emissions calculations are included in Appendix D. Disposal documents are presented in Appendix E. 6.2 GAUGING DATA Historically, depth to groundwater has ranged from 1.74 feet BTOC (MW-3) to 9.50 feet BTOC (MW-1). Groundwater flow direction has previously been illustrated towards the northeast and southwest, from a local high near the center of the site (S&ME, 2018; CATLIN, 2021). During the April 2023 event, CATLIN personnel measured depth to water using an electronic water interface probe. To prevent cross contamination, the probe and cabling were decontaminated according to the manufacturer’s recommendations between use in each well. Gauging data were recorded on electronic groundwater sampling forms using a tablet device. Gauging procedures were performed in general accordance with North Carolina Department of Environmental and Natural Resources (NCDENR), and NCDEQ Guidelines and Environmental Protection Agency (EPA) Region 4 Operating Procedures. Depth to water ranged from 2.83 feet BTOC (MW-5) to 3.65 feet BTOC (MW-1). Each of the depths to water in the wells were measured above their respective screen intervals. LNAPL was not measured in any of the five monitoring wells during this event, but a heavy sheen was visible on the NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 8 April 2023 purge water from MW-4. Based on groundwater elevations calculated for this monitoring period, groundwater flow direction is towards the northeast. Monitoring well gauging results for events conducted by CATLIN are presented in Table 3. Groundwater elevation is illustrated on Figure 4 and the field data sheets are provided in Appendix C. 6.3 SAMPLING DATA Following gauging, the monitoring wells were sampled in general accordance with NCDENR and NCDEQ Guidelines and EPA Region 4 Operating Procedures. Prior to obtaining representative groundwater samples, each monitoring well was purged by removing a minimum of three well volumes using a new, disposable bailer. Monitoring well groundwater field parameter data were measured at one-minute intervals using an In-Situ Aqua TROLL 600 Multiparameter Sonde (Aqua TROLL). Conductivity, pH, oxidation reduction potential (ORP), dissolved oxygen, and temperature measurements were recorded utilizing the VuSitu mobile application (version 1.17.12). Groundwater parameter data were transferred from the VuSitu mobile application to the electronic field data sheets. Copies of the field data sheets are available in Appendix C. After a minimum of three well volumes were removed, a groundwater sample was collected from the well and poured into appropriate laboratory-provided, pre-preserved glassware, labeled, and placed on ice in an insulated cooler. A laboratory-provided trip blank was maintained in the cooler for the duration of the event. To verify that sampling equipment was decontaminated sufficiently between wells, an equipment rinsate blank (EB) sample was collected from the electronic probe. Clean distilled water was allowed to cascade down the electronic probe and into appropriate laboratory-provided, pre-preserved glassware. The glassware was labeled and placed on ice in an insulated cooler. The groundwater samples, equipment rinsate blank, and laboratory-provided trip blank were submitted to Con-Test Analytical Laboratory (Certification NC 652 and NC-DW 25703) in East Longmeadow, Massachusetts, under proper chain of custody (COC) protocol for analyses described in Section 3.0 Scope of Services. The COC is included with the analytical report provided in Appendix F. NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 9 April 2023 6.4 SUMMARY OF GROUNDWATER INFORMATION Historically, LNAPL has been measured in MW-1 and MW-4, and samples from monitoring wells MW-1, MW-4, and MW-5 have contained the highest BTEX compound concentrations. Prior to the 2021 event, LNAPL had not been measured at the site since 2012. During the May 2018 sampling event conducted by S&ME, samples from MW-1, MW-2, MW-4, MW-5, MW-6, and MW-8 contained multiple VOCs above 2L GWQS, but below GCL (S&ME 2018). Historical information prepared by other consultants is included in Appendix A. The latest groundwater sampling laboratory results for SM 6200B analysis are summarized in Table 4. Historical results for events conducted by CATLIN are in Table 5. Monitoring well sample analytical results are illustrated on Figure 5. A copy of the complete laboratory report and COC documentation are in Appendix F. Monitoring Wells During the April 2023 monitoring event, five monitoring well groundwater samples (MW-1, MW-2, MW-3, MW-4, and MW-5) were collected and submitted for analysis via SM 6200B (including EDB, MTBE, and DIPE). Laboratory analysis did not detect any constituents above their respective reporting limits in the sample from MW-3. No analyte concentrations were detected above GCL in any of the monitoring well samples. Analytical results reported the following constituents at concentrations above their 2L GWQS in samples MW-1, MW-2, MW-4, and MW-5: • MW-1: benzene, DIPE, MTBE, naphthalene, toluene, and total xylenes; • MW-2: benzene and naphthalene; • MW-4: benzene, n-butylbenzene, ethylbenzene, isopropylbenzene, naphthalene, n-propylbenzene, styrene, toluene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, and total xylenes; and • MW-5: benzene, ethylbenzene, isopropylbenzene, naphthalene, n- propylbenzene, toluene, 1,2,4-trimethylbenzene, 1,3,5- trimethylbenzene, and total xylenes. Equipment Rinsate Blank and Trip Blank One laboratory-provided trip blank sample and one equipment rinsate blank were submitted for analysis per SM 6200B (including EDB, MTBE, and DIPE). Estimated concentrations (“J”-values) of acetone (a common laboratory artifact) were reported in both samples. No other targeted analytes were detected. NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 10 April 2023 6.5 EVALUATION OF ASSESSMENT INFORMATION Extent of Contamination Several petroleum constituents were detected above their respective 2L GWQS in samples from MW-1, MW-2, MW-4, and MW-5. No LNAPL was encountered in any of the monitoring wells during the sampling event. A summary of monitoring well groundwater sample analytical results is illustrated on Figure 5. The estimated horizontal extent of benzene is shown on Figure 6. The contaminant plume has not been horizontally or vertically delineated. The highest BTEX concentrations have historically been reported in samples from MW-1, MW-4, and MW-5. Laboratory analytical results from this monitoring period reported BTEX concentrations in samples from MW-2 and MW-5 as generally lower than those reported during the June 2021 sampling event. Cleanup Levels Achieved Soil – To date, approximately 40 cubic yards of impacted soil have been removed from the site. Excavation confirmation soil samples obtained in 1994 at the time of UST removal revealed petroleum constituent concentrations above STGW MSCC. Groundwater – Groundwater contaminant concentrations are above 2L GWQS, but below GCL at the site. LNAPL – LNAPL was not measured in any of the five wells during this monitoring period. 7.0 CONCLUSIONS AND RECOMMENDATIONS Conclusions Groundwater monitoring findings for this monitoring period are summarized below: • An AFVR event was conducted utilizing MW-1 and MW-4 as extraction points. • A total of 2,779 gallons of impacted groundwater and LNAPL were removed. A calculated 0.860 pounds of petroleum vapors were emitted (equivalent to 0.138 gallons of petroleum). • Approximately five weeks after the AFVR event, five monitoring wells (MW-1, MW-2, MW-3, MW-4, and MW-5) were sampled. • Depth to water was measured above the screened interval in all monitoring wells during the sampling event. • LNAPL was not measured in any of the wells during sampling. • No analyzed compound concentrations were detected above the laboratory reporting limit in the sample from MW-3. NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 11 April 2023 • Several petroleum constituents above their 2L GWQS were reported in the samples from MW-1, MW-2, MW-4, and MW-5. • No targeted analytes were reported above GCL. • The BTEX concentrations in the samples from MW-2 and MW-5 have generally decreased since the previous sampling event. Recommendations CATLIN recommends to: • Conducting a HRSC evaluation at the site to determine if LNAPL is present at the site; • Conduct a vapor intrusion screening assessment for the buildings in/near the impacted groundwater plume; and • Conduct a semi-annual sampling event in October 2023. 8.0 STATEMENTS AND CERTIFICATION 1 Enter the date the monitoring report was due. April 28, 2023 Will this report be submitted after the established due date? NO 2 Was any required information from the above template missing from this report? YES No cross sections are provided. Adequate subsurface information is not available. 3 If applicable, will any of the proposed attenuation milestones under the schedule approved in the Corrective Action Plan not be met? NA No CAP has been submitted for this site. 4 Does any known or suspected source zone soil contamination or free product remain outside of the assessed area that could be inhibiting natural attenuation? NO 5 Has there been an unexpected increase in contaminant mass sufficient to suggest a potential new release from a separate onsite or offsite source? NO 6 Certification: I, Sean J. O’Neil, a Licensed Engineer for CATLIN Engineers and Scientists, do certify that the information contained in this report is correct and accurate to the best of my knowledge. CATLIN Engineers and Scientists is licensed to practice engineering in North Carolina. The certification number of the company or corporation is C-0585. NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 12 April 2023 9.0 LIMITATIONS The groundwater samples analyzed as part of this investigation only provide isolated data points and may not represent conditions at every location in the project area. Analyses and conclusions of this report, being based on interpolation between data points at the project area, may not be completely representative of all site conditions. Conclusions and recommendations of this investigation and report are based on the best available data in an effort to comply with current regulatory requirements. 10.0 REFERENCES CATLIN Engineers and Scientists, Monitoring Report, Bud’s Service Center, 101 South Parker Street, Elm City, Wilson County, North Carolina, NCDEQ Incident No. 13649, Risk Classification: H030E, July 23, 2021. Force Environmental Service Company, LLC, Bud’s Service Center; NCDENR Incident #13649; Wilson County, 100 south Parker Street, Elm City, NC, September 22, 2009. Horton, J. Wright, Jr. and Victor A. Zullo, An Introduction to the Geology of the Carolinas: The Geology of the Carolinas, pp 1-11. Narkunas, J., Groundwater Evaluation in the Central Coastal Plain of North Carolina, North Carolina Department of Natural Resources and Community Development, 1980, pp 119. NCDEQ, Division of Water Resources, 2020 Visual Hydrogeologic Framework, North Carolina Hydrogeological Database, ncwater.org/?page=350, accessed July 22, 2021. NCDEQ, UST Section, North Carolina Department of Environmental Quality, Division of Waste Management, Corrective Action Guidelines, January 19, 2021. NCDENR, UST Section, North Carolina Department of Environment and Natural Resources, Division of Waste Management, Guidelines for Sampling, December 1, 2013. NCDEQ, UST Section, North Carolina Department of Environmental Quality, Division of Waste Management, Guidelines for Site Checks, Tank Closure, and Initial Response and Abatement, January 19, 2021. North Carolina Department of Natural Resources and Community Development, Geological Map of North Carolina, 1985. S&ME, Inc., DRAFT Groundwater Monitoring Report, Bud’s Service Center, TF- 13649, 101 South Parker Street, Elm City, Wilson County, NC, S&ME Project No. 4305-17-257, May 24, 2018. S&ME, Inc., Groundwater Monitoring Report, Bud’s Service Center TF-13649, 101 South Parker Street, Elm City, Wilson County, NC, S&ME Project No. 4305-15-137, August 17, 2015. NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 13 April 2023 U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and Ecosystem Support Division, Athens Georgia, Operating Procedure – Field Equipment Cleaning and Decontamination at the FEC, Striggow, B., U.S. EPA Report No. SESDPROC-206-R3, Effective Date December 18, 2015. U.S. EPA, Region 4, U.S. Environmental Protection Agency, Laboratory Services and Applied Science Division, Athens Georgia, Operating Procedure Potable Water Supply Sampling, Chief, Applied Science Branch, U.S. EPA Report No. ASBPROC-305-R4, Effective Date June 11, 2019. U.S. Environmental Protection Agency, Science and Ecosystem Support Division, Athens Georgia, Operating Procedure – Groundwater Level and Well Depth Measurement, Striggow, B., U.S. EPA Report No. SESDPROC-105-R3, Effective Date November 3, 2016. U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and Ecosystem Support Division, Athens Georgia, Operating Procedure – Groundwater Sampling, Striggow, B., U.S. EPA Report No. SESDPROC-301-R4, Effective Date April 26, 2017. U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and Ecosystem Support Division, Athens Georgia, Operating Procedure – In Situ Water Quality Monitoring, Chief, Field Services Branch, U.S. EPA Report No. SESDPROC-111-R4, Effective Date March 14, 2018. UTTS/Environmental, Tank Closure by Removal, Facility: Bud’s Service Center, Parker and Main Streets, Elm City, Wilson County, N.C., April, 1994. Winner, M.D, Jr., and Coble, R.W., Hydrogeologic Framework of the North Carolina Coastal Plain Aquifer System: U.S. Geological Survey Open File Report 87- 690, 1989, pp 155. NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 April 2023 TABLES Page 1 of 1 TABLE 1 SITE HISTORY — UST AND OTHER RELEASE INFORMATION Incident Name and No.: Bud's Service Center - 13649 UST ID Number Name of Owner/ Operator Last Contents Previous Contents Capacity (gal) Construction Details Tank Dimensions (feet) Installation Date (mm/dd/yy) Date Removed (mm/dd/yy) 1 Gasoline Gasoline 1,000 Single Wall Steel 3.8 x 12 05/11/71 03/17/94 2 Gasoline Gasoline 1,000 Single Wall Steel 3.8 x 12 05/09/78 03/17/94 3 Gasoline Gasoline 1,000 Single Wall Steel 3.8 x 12 Unknown 03/17/94 Incident Number Material Released Date Release Discovered (mm/dd/yy) 13649 Gasoline 03/17/94 Information obtained from S&ME (2018), Sharpe (1994), UTTS (1994), and NCDEQ Tanks Database. gal = gallons Dates of Ownership/Operation (mm/dd/yy) Sharpe Oil Company (dissolved) Description of the Release TPH discovered in soils during UST excavation on March 17, 1994 Unknown 05/09/78 - 12/31/93 05/11/71 - 12/31/93 NCDEQ; 13649_Bud's Service Center; T1_Site History CATLIN Project No. 221048 CATLIN Engineers and Scientists April 2023 Page 1 of 1 TABLE 2 Incident Name and No.: Bud's Service Center - 13649 Well ID Property Address Wilson County PIN Number* Owner Name (Last, First MI) Owner Mailing Address Well Use Distance/ Direction from Source Area (ft.) WSW-1 405 W Wilson St., Elm City, NC 27822 3735-50-9285 Pittman, Moses J; Pittman, Susan B 206 S Barnes St, Elm City, NC 27822-9285 Active Non-Potable 1,100 / W WSW-2 308 Dixon St., Elm City, NC 27822 3734-69-2905 Warbritton, Bessie F (HEIRS) c/o Jackie W. Smith 5316 Montclair Dr., Raleigh, NC 27609-4364 Active Non-Potable 912 / WSW WSW-3 406 S Railroad St., Elm City, NC 27822 3734-78-0808 Richardson, Magdalene T (HEIRS) PO Box 275, Elm city, NC 27822-0275 Active Non-Potable 1,440 / S WSW-4 305 N Broad St., Elm City, NC 27822 3735-71-6381 Simpkins, Francena H PO Box 1444, Elm City, NC 27822-1444 Active Non-Potable 1,200 / N Receptor ID Location Contact Distance/ Direction from Source Area (ft.) Stream 1 North of Site —1,220 / N Stream 2 South of Site —1,344 / S Information obtained from Force (2009). * = Obtained from Wilson County GIS, accessed July 2021. ft. = feet PUBLIC AND PRIVATE WATER SUPPLY WELLS AND OTHER RECEPTOR INFORMATION Unnamed stream located south of the site. Unnamed stream located north of the site. Description NCDEQ; 13649_Bud's Service Center; T2_Receptor Info CATLIN Project No. 221048 CATLIN Engineers and Scientists April 2023 Page 1 of 1 TABLE 3 WELL CONSTRUCTION AND HISTORICAL WATER LEVEL GAUGING DATA Incident Name and No.: Bud's Service Center - 13649 Well ID Date Installed (mm/dd/yy)* Date Water Level Measured (mm/dd/yy) Well Diameter (inches) Well Casing Depth (ft. BLS)* Screened Interval (x to y ft. BLS)* Bottom of Well (ft. BLS)* Top of Casing Elevation* (ft.) Free-Phase Product Thickness** (ft.) Depth to Groundwater from Top of Casing (ft.) Groundwater Elevation (ft.)Comments 06/16/21 0.32 2.98 97.29 Ɨ 02/22/23 0.36 3.10 97.21 Pre-AFVR; Ɨ 02/22/23 NMT 4.53 95.47 Post-AFVR; Ɨ 04/03/23 NMT 3.65 96.35 Ɨ 06/16/21 NMT 2.56 97.57 Ɨ 04/03/23 NMT 3.09 97.04 Ɨ 06/16/21 NMT 1.74 98.48 Ɨ 04/03/23 NMT 3.02 97.20 Ɨ 06/16/21 0.39 2.58 98.00 Ɨ 02/22/23 0.31 2.60 97.92 Pre-AFVR; Ɨ 02/22/23 0.01 4.48 95.78 Post-AFVR; Ɨ 04/03/23 NMT 3.20 97.05 Ɨ 06/16/21 NMT 5.18 94.92 04/03/23 NMT 2.83 97.27 Ɨ ft. BLS = feet Below Land Surface NMT = No Measurable Thickness AFVR = Aggressive Fluid Vapor Recovery Ɨ = Water level was measured above the screened interval. * = Data obtained from S&ME (2018). 92.003/17/09MW-1 18 100.13 100.00249-24 2.0 2.0 2.0 5 5-18 5 5-18 18 100.25 100.22185-18 5 5-18 18 100.10 ** = if free-phase product is present in a well, ground water elevation should be calculated by : [top of casing elevation - depth to water]+ [free product thickness x specific gravity of the fuel type] 08/03/11MW-4 MW-5 08/03/11 2.0 5 MW-2 08/03/11 08/03/11MW-3 NCDEQ; 13649_Bud's Service Center; T3_Well Construction & Gauging CATLIN Project No. 221048 CATLIN Engineers and Scientists April 2023 Page 1 of 1 TABLE 4 SUMMARY OF GROUNDWATER LABORATORY RESULTS — STANDARD METHOD 6200B Incident Name and No.: Bud's Service Center - 13649 Date Collected 04/03/23 <80 2,200 <6.0 <5.1 <5.7 160 350 26 <5.1 330 42 L 49 <6.0 1,200 230 61 780 BMDL 04/03/23 <2.0 18 4.3 12 2.6 <0.20 13 17 0.41 J 0.58 R 46 L 23 <0.15 1.4 14 3.7 22.6 BMDL 04/03/23 8.5 J <0.18 <0.15 <0.13 <0.14 <0.20 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.15 <0.22 <0.20 <0.15 <0.73 BMDL 04/03/23 <500 2,100 85 J <32 <35 <50 2,600 140 <32 ƚ <43 ƚ 430 L 300 180 16,000 2,400 610 12,800 BMDL 04/03/23 <500 2,100 <37 <32 <35 <50 3,000 110 J <32 ƚ <43 ƚ 300 L 280 <38 19,000 2,000 420 14,400 BMDL 04/03/23 9.0 J <0.18 <0.15 <0.13 <0.14 <0.20 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.15 <0.22 <0.20 <0.15 <0.73 BMDL 04/03/23 8.8 J <0.18 <0.15 <0.13 <0.14 <0.20 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.15 <0.22 <0.20 <0.15 <0.73 BMDL All results in micrograms per liter (µg/L). BMDL = Below Method Detection Limit (refer to analytical report for a complete list of analytes and detection limits) Bold results indicate concentrations above 2L GWQS. GCL = Gross Contaminant Level 2L GWQS = NCAC T15A:02L Groundwater Quality Standards EB = Equipment Blank TB = Trip Blank < = Less than method detection limit ƚ = The method detection limit is above the 2L GWQS. J = Detected but below the Reporting Limit (lowest calibration standard); result is an estimated concentration (CLP J-Flag). R = Laboratory fortified blank duplicate RPD is outside of control limits. Reduced precision is anticipated for any reported value for this compound (R-05 Flag). L = Laboratory fortified blank/laboratory control sample recovery and duplicate recovery are outside of control limits. Reported value for this compound is likely to be biased on the low side (L-04 Flag). 80,000 600 30,500 70 8,800 70 50,000 500 All Other SM 6200B Analytes1,2,4-Trimethylbenzenen-PropylbenzeneToluene Naphthalene Isopropylbenzene(Cumene)p-Isopropyltoluene(p-Cymene)Ethylbenzene1,3,5-TrimethylbenzeneTotal XylenesDiisopropyl Ether (DIPE)20,000 20 Varies Varies 11,700 25 6,000 6 26,100 70 260,000 600 28,500 400 24,100 400 70,000 70Styrene MW-5 MW-3 MW-1 Well/ Sample ID MW-2 MW-4 Methyl tert-Butyl Ether (MTBE)Contaminant of Concern Benzene n-Butylbenzenesec-Butylbenzene tert-Butylbenzene Acetone 14,750 70 6,000,000 6,000 70,000 70 EB TB GCL (µg/L) 2L GWQS (µg/L) 5,000 1 5,900 70 NCDEQ; 13649_Bud's Service Center; T4_GW Results CATLIN Project No. 221048 CATLIN Engineers and Scientists April 2023 Page 1 of 1 TABLE 5 SUMMARY OF HISTORICAL GROUNDWATER LABORATORY RESULTS — STANDARD METHOD 6200B Incident Name and No.: Bud's Service Center - 13649 Date Collected 04/03/23 <80 2,200 <6.0 <5.1 <5.7 160 350 26 <5.1 330 42 L 49 <6.0 1,200 230 61 780 BMDL 06/16/21 6.2 J 39 6.6 14 2.9 BMDL 69 26 1.8 BMDL 76 40 BMDL 6.9 67 18 92.9 BMDL 04/03/23 <2.0 18 4.3 12 2.6 <0.20 13 17 0.41 J 0.58 R 46 L 23 <0.15 1.4 14 3.7 22.6 BMDL 06/16/21 3.3 J <0.13 <0.14 <0.10 <0.090 BMDL <0.090 <0.10 <0.090 BMDL <0.15 <0.080 BMDL <0.11 <0.10 <0.10 <0.27 BMDL 04/03/23 8.5 J <0.18 <0.15 <0.13 <0.14 <0.20 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.15 <0.22 <0.20 <0.15 <0.73 BMDL 04/03/23 <500 2,100 85 J <32 <35 <50 2,600 140 <32 ƚ <43 ƚ 430 L 300 180 16,000 2,400 610 12,800 BMDL 06/16/21 <940 2,800 <56 <40 <36 BMDL 3,500 130 J <36 ƚ BMDL 890 340 BMDL 22,000 2,300 580 16,200 BMDL 04/03/23 <500 2,100 <37 <32 <35 <50 3,000 110 J <32 ƚ <43 ƚ 300 L 280 <38 19,000 2,000 420 14,400 BMDL All results in micrograms per liter (µg/L). BMDL = Below Method Detection Limit (refer to analytical report for a complete list of analytes and detection limits) Bold results indicate concentrations above 2L GWQS. GCL = Gross Contaminant Level 2L GWQS = NCAC T15A:02L Groundwater Quality Standards < = Less than method detection limit ƚ = The method detection limit is above the 2L GWQS. J = Detected but below the Reporting Limit (lowest calibration standard); result is an estimated concentration (CLP J-Flag). R = Laboratory fortified blank duplicate RPD is outside of control limits. Reduced precision is anticipated for any reported value for this compound (R-05 Flag). L = Laboratory fortified blank/laboratory control sample recovery and duplicate recovery are outside of control limits. Reported value for this compound is likely to be biased on the low side (L-04 Flag).tert-Butylbenzene Well/ Sample ID Diisopropyl Ether (DIPE)EthylbenzeneIsopropylbenzene(Cumene)Contaminant of Concern Acetone Benzene n-Butylbenzenesec-Butylbenzene Toluene 1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneTotal XylenesAll Other SM 6200B Analytes8,800 70 14,750 70 MW-1 MW-4 GCL (µg/L) 2L GWQS (µg/L) 28,500 400 24,100 400 50,000 500 Varies Varies MW-2 MW-3 MW-5 80,000 600 30,500 70 11,700 25 6,000 6 26,100 70 260,000 600 6,000,000 6,000 5,000 1 5,900 70 70,000 70 Methyl tert-Butyl Ether (MTBE)20,000 20 Styrene 70,000 70Naphthalene n-Propylbenzenep-Isopropyltoluene(p-Cymene)NCDEQ; 13649_Bud's Service Center; T5_Historical GW CATLIN Project No. 221048 CATLIN Engineers and Scientists April 2023 NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 April 2023 FIGURES FIGUREPROJECTTITLE 1BUD'S SERVICE CENTER 101 S PARKER STREETELM CITY, NC SITE VICINITY MAP SITE LOCATION US HWY 301PARKER STMAIN ST Copyright:© 2013 National Geographic Society, i-cubed 2,000 0 2,000 4,0001,000 Feet ³ INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY13649221048APR 2023 AS SHOWN KMC/SJO FIGUREPROJECTTITLE 2BUD'S SERVICE CENTER 101 S PARKER STREETELM CITY, NC POTENTIAL RECEPTOR MAP !(W !(W !(W !(W SITE LOCATION PARKER STMAIN ST 1 ,5 0 0 F EET RADIUS 500F E ET RADIUS WSW-4 WSW-1 WSW-2 WSW-3 STREAM 2 STREAM 1 Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community 500 0 500 1,000250 Feet ³ LEGEND !(W Active Non-PotableWater Supply Well INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY13649221048APR 2023 AS SHOWN KMC/SJO FIGUREPROJECTTITLE 3BUD'S SERVICE CENTER 101 S PARKER STREETELM CITY, NC SITE MAP !> !> !> !> !> !( !( !( !(PARKER STMAIN ST MW-1 MW-5 MW-4 MW-3 MW-2FORMER PUMP ISLAND FORMER 1,000-GAL. GASOLINE USTs Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community 20 0 20 4010 Feet ³ INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY13649221048APR 2023 AS SHOWN KMC/SJO NOTE: Well and tank locations were obtained from previous reports prepared by other consultants and are approximate. Monitoring Well (Type II)!> LEGEND Approximate Location of UST System Parcel Boundary FIGUREPROJECTTITLE 4BUD'S SERVICE CENTER101 S PARKER STREETELM CITY, NC GROUNDWATER ELEVATION –APRIL 3, 2023 !> !> !> !> !> !( !( !( !(<<PARKER STMAIN ST MW-1(96.35) MW-5(97.27) MW-4(97.05) MW-3(97.20) MW-2(97.04) 96.50 9 7 .1097.00 96.90 96.80 96.7096.60 97.2096.40 97.10 Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community 20 0 20 4010 Feet ³ INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY13649221048APR 2023 AS SHOWN KMC/SJO NOTES: 1. Well and tank locations were obtained from previous reports prepared by other consultants and are approximate.2. The groundwater elevation contour interval is 0.10 feet. Gauged Monitoring Well (Type II)!> LEGEND Approximate Location of UST System Parcel Boundary Groundwater FlowDirection Groundwater Contour<Groundwater Elevation (Feet)(##) FIGUREPROJECTTITLE 5BUD'S SERVICE CENTER101 S PARKER STREETELM CITY, NC MONITORING WELLGROUNDWATER SAMPLEANALYTICAL RESULTS –APRIL 3, 2023 !> !> !> !> !> !( !( !( !(PARKER STMAIN ST MW-1 MW-5 MW-4 MW-3 MW-2 ??????ESTIMATED HORIZONTAL EXTENT OF 2L GWQS EXCEEDANCES Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community 20 0 20 4010 Feet ³ INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY13649221048APR 2023 AS SHOWN KMC/SJO NOTE: Well and tank locations were obtained from previous reports prepared by other consultants and are approximate. Sampled Monitoring Well (Type II)!> LEGEND Approximate Location of UST System Parcel Boundary Incident Name and No.: Bud's Service Center - 13649 DateCollected 04/03/23 2,200 <6.0 160 350 26 330 42 L 49 <6.0 1,200 230 61 78004/03/23 18 4.3 <0.20 13 17 0.58 R 46 L 23 <0.15 1.4 14 3.7 22.604/03/23 <0.18 <0.15 <0.20 <0.22 <0.15 <0.17 <0.38 <0.12 <0.15 <0.22 <0.20 <0.15 <0.73 04/03/23 2,100 85 J <50 2,600 140 <43 ƚ 430 L 300 180 16,000 2,400 610 12,80004/03/23 2,100 <37 <50 3,000 110 J <43 ƚ 300 L 280 <38 19,000 2,000 420 14,400 All results in micrograms per liter (µg/L).Bold results are above 2L GWQS. Refer to Table 4 for all other results and notes.n-ButylbenzeneDiisopropyl Ether (DIPE)Methyl tert-Butyl Ether (MTBE)Styrene 70,0007070,000705,90070 20,00020 26,10070 SUMMARY OF GROUNDWATER LABORATORY RESULTS - STANDARD METHOD 6200B Naphthalene 80,000600 6,0006EthylbenzeneBenzene 5,0001 Isopropylbenzene(Cumene)30,50070 MW-2 MW-4 n-PropylbenzeneToluene 1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneTotal XylenesContaminant of Concern MW-1 MW-3 MW-5 Well/Sample ID 260,000600 28,500400 24,100400 50,000500GCL (µg/L)2L GWQS (µg/L) FIGUREPROJECTTITLE 6BUD'S SERVICE CENTER101 S PARKER STREETELM CITY, NC ESTIMATED HORIZONTALEXTENT OF BENZENE –APRIL 3, 2023 !> !> !> !> !> !( !( !( !(PARKER STMAIN ST MW-1(2,200) MW-5(2,100) MW-4(2,100) MW-3(<0.18) MW-2(18) ??????(1)(100)(1,000)Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community 20 0 20 4010 Feet ³ INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY13649221048APR 2023 AS SHOWN KMC/SJO NOTES: 1. Well and tank locations were obtained from previous reports prepared by other consultants and are approximate.2. The 2L GWQS for Benzene is 1 µg/L. Sampled Monitoring Well (Type II)!> LEGEND Approximate Location of UST System Parcel Boundary Benzene Concentration (μg/L) Benzene EstimatedIsoconcentration (##) NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 April 2023 APPENDICES NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 April 2023 APPENDIX A HISTORICAL DATA Well ID Date Installed Screened Interval (ft-bgs) Well Diameter (inches) Total Well Depth from Top of Casing (ft.) Top of Casing Elevation (ft-rel) Date of Measurement Depth to Water (ft-BTOC) Depth to Product (ft-BTOC) Free Product Thickness (ft) Groundwater Elevation 3/17/2009 9.50 NM NM 90.50 8/4/2011 NM NM 1.50 NA 6/21/2012 6.51 4.51 2.00 95.21 6/22/2012 5.21 4.99 0.22 94.98 6/24/2015 4.88 NM NM 95.12 5/2/2018 3.55 NM NM 96.45 8/4/2011 8.26 NM NM 91.87 6/22/2012 5.02 NM NM 95.11 6/24/2015 4.74 NM NM 95.39 5/2/2018 3.60 NM NM 96.53 8/4/2011 6.09 NM NM 94.13 6/22/2012 3.82 NM NM 96.40 6/24/2015 2.91 NM NM 97.31 5/2/2018 2.58 NM NM 97.64 8/4/2011 7.41 NM NM 92.84 6/22/2012 4.58 NM NM 95.67 6/24/2015 4.17 NM NM 96.08 5/2/2018 2.93 NM NM 97.32 8/4/2011 5.95 NM NM 94.15 6/22/2012 4.96 NM NM 95.14 6/24/2015 3.10 NM NM 97.00 5/2/2018 2.97 NM NM 97.13 MW-6*5/1/2018 0.0 - 17.0 2 17.00 99.94 5/2/2018 3.27 NM NM 96.67 MW-7*5/1/2018 0.0 - 15.0 2 15.00 99.63 5/2/2018 3.55 NM NM 96.08 MW-8*5/1/2018 0.0 - 15.0 2 15.00 99.61 5/2/2018 3.87 NM NM 95.74 Notes: ft-bgs: feet below ground surface ft-rel: feet relative ft-BTOC: feet below top of casing Monitor well construction data and agroundwater measurements from 3/17/2009 from Force Environmental NM: Not measured S&ME measured relative top of casing elevations for temporary monitor wells MW-6 through MW-8 on May 2, 2018. *Monitor wells MW-6, MW-7, and MW-8 were temporary monitor wells and were abandoned on May 2, 2018. WELL CONSTRUCTION AND LIQUID LEVEL DATA TABLE 3 100.00 MW-2 S&ME Project # 4305-17-257 101 South Parker Street, Elm City, Wilson County, North Carolina Bud's Service Center (Incident No.: 13649, UST No. RA-2200) MW-1 3/17/2009 9.00 - 24.00 2 24.00 18.00 100.13 MW-3 8/3/2011 5.00 - 18.00 2 18.00 100.22 8/3/2011 5.00 - 18.00 2 MW-5 8/3/2011 5.00 - 18.00 2 MW-4 8/3/2011 5.00 - 18.00 18.00 2 18.00 100.25 100.10 Page 1 of 1 APPENDIX A HISTORICAL DATA - S&ME, 2018 NCDEQ; 13649_Bud's Service Center CATLIN Project No. 221048 CATLIN Engineers and Scientists April 2023 TABLE 4 SUMMARY OF GROUNDWATER SAMPLING RESULTS Bud's Service Center (Incident No.: 13649, UST No. RA-2200) 101 South Parker Street, Elm City, Wilson County, North Carolina S&ME Project # 4305-17-257 9/4/2009 10,600 BDL BDL BDL 7.3 95.6 1,040 1,110 BDL BDL 186 290 109 BDL 13,200 792 181 5,540 8/4/2011 6/22/2012 6/24/2015*5,060 BDL BDL BDL BDL BDL 299 957 68.8 BDL 254 379 161 BDL 6,540 913 227 3,890 5/2/2018*4,300 25 J BDL BDL BDL BDL 230 940 57 BDL 290 380 130 BDL 5,000 670 170 3,280 8/4/2011 22.9 BDL 11.9 BDL BDL BDL 0.79 67.4 11.5 BDL 1.5 76.3 23.4 BDL 0.5 73.7 34.5 32.6 6/22/2012 172 BDL 13.8 3.0 BDL BDL 3.80 182 24.7 BDL 15.5 61.7 30.2 BDL 27.9 71.9 5.3 100.2 6/24/2015 214 4.2 14.3 BDL BDL BDL 2.7 264 32.3 BDL 7.1 116 45.4 BDL 121 126 30.6 237.3 5/2/2018*120 5.2 14 3 BDL BDL 1.2 120 24 1.7 2.5 82 36 BDL 21 44 14 106.8 8/4/2011 31 BDL 10.2 BDL BDL BDL BDL 345 23.7 BDL 3.1 151 67.3 BDL 51.3 206.0 79.6 785.3 6/22/2012 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 6/24/2015 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 5/2/2018 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 8/4/2011 6,870 BDL BDL BDL BDL BDL 23.5 1,950 87.2 BDL 16.6 597 229 BDL 22,700 1,290 441 10,910 6/22/2012 6,960 BDL BDL BDL BDL BDL BDL 2,280 BDL BDL BDL 596 220 BDL 22,100 1,720 371 11,910 6/24/2015*3,090 BDL BDL BDL BDL BDL BDL 1,640 BDL BDL BDL 432 196 BDL 12,600 1,340 344 8,000 5/2/2018*1,600 22 17 BDL BDL BDL BDL 840 46 BDL BDL 910 99 25 J 5,500 730 200 3,700 8/4/2011 4,970 BDL BDL BDL BDL BDL 52.1 2,840 106 BDL 4.2 823 290 BDL 24,900 1,970 582 15,700 6/22/2012 4,860 BDL BDL BDL BDL BDL BDL 2,910 112 BDL BDL 715 290 BDL 22,900 2,360 529 15,070 6/24/2015*4,820 BDL BDL BDL BDL BDL BDL 2,810 115 BDL BDL 610 294 BDL 24,800 1,960 485 13,770 5/2/2018*2,800 BDL BDL BDL BDL BDL 52 J 1,900 72 J BDL BDL 990 J 180 40 J 16,000 1,300 320 9,200 MW-6 5/2/2018 48 0.3 J 1 0.32 J BDL 1.8 9.7 17 3.6 0.22 J 23 4.8 J 2.7 BDL 1.1 4.2 0.5 5.06 MW-7 5/2/2018 0.69 1.2 2.3 0.36 J BDL BDL BDL 1.6 3.4 1.2 0.36 J 1.2 J 3.9 BDL BDL 12 5.6 6.4 MW-8 5/2/2018*1,600 9.8 9.8 BDL BDL 36 130 260 25 BDL 130 120 J 48 BDL 370 220 60 600 1 70 70 70 0.02 0.4 70 600 70 25 20 6 70 70 600 400 400 500 5,000 6,900 8,500 15,000 50 400 70,000 84,500 25,000 11,700 20,000 6,000 30,000 70,000 260,000 28,500 25,000 85,500 Notes: Analytes that are not shown for the method were not detected.Concentrations exceeding the laboratory's reporting limits are shown in BOLD fields. Concentrations are reported in micrograms per liter (µg/L).NA: Analysis for sample not requested. * Indicates sample was run at a dilution.GCL - Gross Contaminantion Level 2L Standard: North Carolina Groundwater Quality Standards: 15A NCAC 2L.0202 ND: Not detected in concentrations exceeding laboratory detection limits Concentrations exceeding the 2L Standards are shown in Shaded and BOLD fields.NE: Regulatory standard not established for analyte MW-3 MW-4 MW-5 2L Standards GCLs Total xylenes 2.0 ft. Free Product Measured - Monitor Well Not Sampled 0.22 ft. Free Product Measured - Monitor Well Not Sampled Volatile Organic Compounds (VOCs) by EPA Method 6200B (µg/L) Well ID Date Collected tert-butylbenzeneMW-1 p-isopropyltoluenestyrenen-butylbenzene1,3,5-TrimethylbenzeneToluene1,2,4-TrimethylbenzeneMW-2 1,2-dibromoethanen-PropylbenzeneBenzeneIsoproplybenzeneMethyl tert-butyl etherEthylbenzeneNaphthaleneDi-isopropyl ether1,2-dichloroethanesec-butylbenzenePage 4 of 4 APPENDIX A HISTORICAL DATA - S&ME, 2018 NCDEQ; 13649_Bud's Service Center CATLIN Project No. 221048 CATLIN Engineers and Scientists April 2023 NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 April 2023 APPENDIX B SITE PHOTOGRAPHS APPENDIX B SITE PHOTOGRAPHS – FEBRUARY 22 AND APRIL 3, 2023 NCDEQ; 13649_ Bud’s Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 April 2023 View of site, facing south. View of AFVR setup, facing south. APPENDIX B SITE PHOTOGRAPHS – FEBRUARY 22 AND APRIL 3, 2023 NCDEQ; 13649_ Bud’s Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 April 2023 View of MW-1 setup, facing west. View of MW-4 setup, facing northeast. APPENDIX B SITE PHOTOGRAPHS – FEBRUARY 22 AND APRIL 3, 2023 NCDEQ; 13649_ Bud’s Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 April 2023 View of MW-1. View of MW-1. APPENDIX B SITE PHOTOGRAPHS – FEBRUARY 22 AND APRIL 3, 2023 NCDEQ; 13649_ Bud’s Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 April 2023 View of site, facing northeast. View of site, facing west-southwest. APPENDIX B SITE PHOTOGRAPHS – FEBRUARY 22 AND APRIL 3, 2023 NCDEQ; 13649_ Bud’s Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 April 2023 View of site, facing northeast. View of MW-1, facing south-southwest. APPENDIX B SITE PHOTOGRAPHS – FEBRUARY 22 AND APRIL 3, 2023 NCDEQ; 13649_ Bud’s Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 April 2023 View of MW-2, facing southwest. View of MW-3, facing north. APPENDIX B SITE PHOTOGRAPHS – FEBRUARY 22 AND APRIL 3, 2023 NCDEQ; 13649_ Bud’s Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 April 2023 View of MW-4, facing northeast. View of MW-5, facing east-southeast. NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 April 2023 APPENDIX C JOB HAZARD ANALYSES AND FIELD DATA SHEETS Source Exposure Limit Groundwater and/or soil vapor 0.5 ppm TLV-TWA ACGIH Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH Groundwater and/or soil vapor 20 ppm TLV-TWA ACGIH Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH Groundwater and/or soil vapor 50 ppm TLV-TWA ACGIH Groundwater and/or soil vapor 10 ppm TLV-TWA ACGIH Source Exposure Limit atmosphere N/A atmosphere N/A surroundings N/A AFVR Equipment 85 dBA TWA ACGIH Exposure Potential Unlikely Unlikely Unlikely Start Stop 5:45 7:00 7:00 7:15 7:15 16:00 16:00 15:45 Date and Time: 2/22/23 @ 07:15 Equipment Used:PPE D/Oil-Water Interface Probe/Sampling Supplies/Tablet Van #55 Mileage: Weather: Mob and travel to site On-site health and safety briefing. Watch for cars in driveway and going down the road. Wear safety vest when near road. Watch for ants and spiders when in and around wells. Wear hearing protection and be careful on and around vacuum truck. Open and gauge wells for DTP/DTW. Calibrate PID to 100 ppm isobutylene. Photograph wells and site, conduct AFVR oversight, conversations with BJA on procedures. Gauged wells at completion and closed up. Noise Likely Biological Hazards Name of Biological Hazard Source Insect bites and stings Cold Weather Operations Likely Heat (ambient)Likely Slips/Trips/Falls Likely surroundings Depart site, travel to Raleigh office, demob truck. Start: End: DAILY TASK Snakes surroundings Poison Plants (Ivy, Oak, and/or Sumac)surroundings PERSONNEL ONSITE Name and Company (Print)Signature Sandra Miller / CATLIN Chemical Hazards Sunny, Breezy, High 60s-Low 70s Site-Specific Job Hazard Analysis Location Where Task/Operation Performed Bud's Service Station, Elm City, NC Task/Operation AFVR Event Employee Certifying this JHA Print Name: Benjamin J. Ashba, P.G.Signature: Operational Phase Monitoring Date(s) this JHA Conducted: 02/22/2023 Potential Chemicals Concentration BENZENE ppm ETHYL BENZENE ppm TOLUENE ppm XYLENE, ALL ISOMERS ppm METHYL TERT-BUTYL ETHER ppm NAPHTHALENE ppm Physical Hazards Name of Physical Hazard Exposure Level/ Potential * Gas and/or Diesel Source Exposure Limit Groundwater and/or soil vapor 0.5 ppm TLV-TWA ACGIH Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH Groundwater and/or soil vapor 20 ppm TLV-TWA ACGIH Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH Groundwater and/or soil vapor 50 ppm TLV-TWA ACGIH Groundwater and/or soil vapor 10 ppm TLV-TWA ACGIH Source Exposure Limit atmosphere N/A atmosphere N/A surroundings N/A Exposure Potential Likely Likely Likely Start Stop 8:00 9:45 9:45 10:00 10:00 13:45 13:45 16:00 Date and Time: 04/03/23 @ 10:00 NAPHTHALENE ppm Physical Hazards Name of Physical Hazard Exposure Level/ Potential * Gas and/or Diesel TOLUENE ppm XYLENE, ALL ISOMERS ppm METHYL TERT-BUTYL ETHER ppm Potential Chemicals Concentration BENZENE ppm ETHYL BENZENE ppm Chemical Hazards Sunny, breezy, high 60's Site-Specific Job Hazard Analysis Location Where Task/Operation Performed Bud's Service Center, Elm City, NC Task/Operation Gauge and Sample Wells Employee Certifying this JHA Print Name: Benjamin J. Ashba, P.G.Signature: Operational Phase Monitoring Date(s) this JHA Conducted: 04/03/23 PERSONNEL ONSITE Name and Company (Print)Signature Sandra Miller / CATLIN Likely Slips/Trips/Falls Likely surroundings Cleaned up, departed site, got ice for samples, drove to Pace and delivered sampled samples, proceeded to Raleigh office, and demobed truck. Start: End: DAILY TASK Snakes surroundings Poison Plants (Ivy, Oak, and/or Sumac)surroundings Equipment Used:PPE D/Oil-Water Interface Probe/Sampling Supplies/Aqua Troll 600/Bailers/Tablet Truck #55 Mileage: Weather: Mob and travel to site On site safety briefing; watch for ants and spiders in wells, wear safety vest in parking lot and near roads, be careful to avoid slip, trip, and falls. Located, opened, gauged, photographed, and purged wells. Sampled wells MW-1 through MW-5. Equipment blank (EB) collected at 13:39. Biological Hazards Name of Biological Hazard Source Insect bites and stings Cold Weather Operations Likely Heat (ambient) CATLIN PROJECT:SAMPLED BY: CATLIN PROJECT # :DATE SAMPLED: CLIENT'S NAME: MW-1 20.35 3.65 3.321 NMT 9.963 24 16.606 2 Method:Bailer Purge Start Time:11:05 Required Bails for 3 Well Volumes:42 Purge Stop Time:11:17 Required Bails for 5 Well Volumes:70 Was Well Purged Dry?No Number of Bails Removed:42 Sample Time:11:18 Groundwater Removed (gal):10.1 Equipment Used: Time pH (Standard Units) ORP (mV) Specific Cond. (µS/cm) Dissolved Oxygen (mg/L) Temperature (Co) 11:03 12.60 -62.11 28.98 7.76 27.90 11:04 12.22 -40.65 214.62 3.60 27.23 11:05 12.18 -43.02 220.30 3.71 27.40 11:06 12.11 -51.94 231.67 3.41 27.53 11:07 12.07 -59.81 246.39 3.45 27.83 11:08 12.02 -67.78 257.91 3.79 28.05 11:09 11.99 -74.55 259.09 3.51 28.21 11:10 11.97 -78.65 267.16 3.72 28.38 11:11 11.96 -83.09 268.43 3.71 28.53 11:12 11.94 -85.76 272.61 3.53 28.64 11:13 11.93 -88.93 279.53 3.59 28.72 11:14 11.92 -90.88 277.54 3.61 28.79 11:15 11.91 -92.75 277.65 3.42 28.84 Laboratory:Con-Test Analysis: Well Data Well ID Depth to Product (ft below TOC) Total Well Depth (ft) Purging Information Information Volume of Groundwater in Well Well Diameter (inches) GROUNDWATER SAMPLING FORM Water Column (ft below TOC) One Well Volume (gal) Three Well Volumes (gal) Five Well Volumes (gal) 6200B Laboratory Analysis Information Geochemical Parameters Depth to Water (ft below TOC) Low turbidity; milky gray. Strong HCO. Aqua Troll 600 Turbidity and Additional Sampling Notes NCDEQ-Linda Blalock Monitoring Well Information Sandy Miller 4/3/2023 Bud's Service Center 221048 CATLIN PROJECT:SAMPLED BY: CATLIN PROJECT # :DATE SAMPLED: CLIENT'S NAME: MW-2 14.91 3.09 2.433 NMT 7.300 18 12.167 2 Method:Bailer Purge Start Time:11:32 Required Bails for 3 Well Volumes:31 Purge Stop Time:11:45 Required Bails for 5 Well Volumes:51 Was Well Purged Dry?No Number of Bails Removed:31 Sample Time:11:47 Groundwater Removed (gal):7.4 Equipment Used: Time pH (Standard Units) ORP (mV) Specific Cond. (µS/cm) Dissolved Oxygen (mg/L) Temperature (Co) 11:30 12.56 -48.99 0.19 7.35 27.40 11:31 12.36 -59.75 139.82 3.77 26.08 11:32 12.37 -60.97 149.33 2.99 26.07 11:33 12.33 -62.16 150.31 3.09 26.19 11:34 12.30 -64.52 157.21 3.15 26.28 11:35 12.27 -68.10 165.04 3.11 26.41 11:36 12.25 -70.76 177.70 2.90 26.50 11:37 12.24 -72.03 180.77 2.87 26.60 11:38 12.21 -70.91 180.41 2.85 26.63 11:39 12.20 -76.96 194.09 2.92 26.81 11:40 12.18 -79.25 200.33 3.01 26.92 11:41 12.18 -80.38 202.68 2.90 26.98 11:42 12.17 -81.54 207.08 2.92 27.01 11:43 12.16 -83.85 212.10 2.88 27.09 Laboratory:Con-Test Analysis:6200B Depth to Product (ft below TOC)Three Well Volumes (gal) Total Well Depth (ft)Five Well Volumes (gal) Well Diameter (inches) Purging Information Information Geochemical Parameters Aqua Troll 600 Turbidity and Additional Sampling Notes Moderate turbidity; medium-dark gray. Strong HCO. Laboratory Analysis Information Depth to Water (ft below TOC)One Well Volume (gal) GROUNDWATER SAMPLING FORM Bud's Service Center Sandy Miller 221048 4/3/2023 NCDEQ-Linda Blalock Monitoring Well Information Well Data Volume of Groundwater in Well Well ID Water Column (ft below TOC) CATLIN PROJECT:SAMPLED BY: CATLIN PROJECT # :DATE SAMPLED: CLIENT'S NAME: MW-3 14.98 3.02 2.445 NMT 7.334 18 12.224 2 Method:Bailer Purge Start Time:12:14 Required Bails for 3 Well Volumes:31 Purge Stop Time:12:26 Required Bails for 5 Well Volumes:51 Was Well Purged Dry?No Number of Bails Removed:31 Sample Time:12:27 Groundwater Removed (gal):7.4 Equipment Used: Time pH (Standard Units) ORP (mV) Specific Cond. (µS/cm) Dissolved Oxygen (mg/L) Temperature (Co) 12:11 12.32 -19.34 0.00 7.26 29.99 12:12 12.21 24.61 80.30 4.53 27.55 12:13 12.31 47.88 51.39 3.27 26.99 12:14 12.29 53.03 86.36 3.35 26.58 12:15 12.25 52.38 35.60 3.40 26.70 12:16 12.22 52.86 77.65 3.39 26.57 12:17 12.18 54.88 64.26 3.39 26.65 12:18 12.14 58.36 58.83 3.46 26.72 12:19 12.09 64.11 56.42 3.47 26.84 12:20 12.04 69.72 55.41 3.49 27.00 12:21 12.01 73.65 79.32 3.44 27.14 12:22 11.98 77.34 51.46 3.41 27.38 Laboratory:Con-Test Analysis:6200B Depth to Product (ft below TOC)Three Well Volumes (gal) Total Well Depth (ft)Five Well Volumes (gal) Well Diameter (inches) Purging Information Information Geochemical Parameters Aqua Troll 600 Turbidity and Additional Sampling Notes Mild turbidity; light tan. Laboratory Analysis Information Depth to Water (ft below TOC)One Well Volume (gal) GROUNDWATER SAMPLING FORM Bud's Service Center Sandy Miller 221048 4/3/2023 NCDEQ-Linda Blalock Monitoring Well Information Well Data Volume of Groundwater in Well Well ID Water Column (ft below TOC) CATLIN PROJECT:SAMPLED BY: CATLIN PROJECT # :DATE SAMPLED: CLIENT'S NAME: MW-4 14.80 3.2 2.415 NMT 7.246 18 12.077 2 Method:Bailer Purge Start Time:12:41 Required Bails for 3 Well Volumes:31 Purge Stop Time:12:52 Required Bails for 5 Well Volumes:51 Was Well Purged Dry?No Number of Bails Removed:31 Sample Time:12:54 Groundwater Removed (gal):7.4 Equipment Used: Time pH (Standard Units) ORP (mV) Specific Cond. (µS/cm) Dissolved Oxygen (mg/L) Temperature (Co) 12:39 12.42 -54.52 0.05 7.40 28.97 12:40 12.03 -14.09 153.91 4.69 27.89 12:41 12.00 -15.65 152.88 3.12 27.87 12:42 11.95 -19.12 153.75 3.30 28.08 12:43 11.91 -23.09 155.40 3.34 28.25 12:44 11.88 -27.38 155.00 3.21 28.37 12:45 11.87 -31.19 157.84 3.04 28.44 12:46 11.82 -33.11 156.20 2.81 28.54 12:47 11.81 -37.56 155.32 2.74 28.59 12:48 11.82 -40.66 156.20 2.91 28.65 12:49 11.82 -43.42 156.35 2.90 28.72 Laboratory:Con-Test Analysis:6200B Depth to Product (ft below TOC)Three Well Volumes (gal) Total Well Depth (ft)Five Well Volumes (gal) Well Diameter (inches) Purging Information Information Geochemical Parameters Aqua Troll 600 Turbidity and Additional Sampling Notes Very mild turbidity; slightly milky. VERY strong HCO and sheen on purge water. Laboratory Analysis Information Depth to Water (ft below TOC)One Well Volume (gal) GROUNDWATER SAMPLING FORM Bud's Service Center Sandy Miller 221048 4/3/2023 NCDEQ-Linda Blalock Monitoring Well Information Well Data Volume of Groundwater in Well Well ID Water Column (ft below TOC) CATLIN PROJECT:SAMPLED BY: CATLIN PROJECT # :DATE SAMPLED: CLIENT'S NAME: MW-5 15.17 2.83 2.476 NMT 7.427 18 12.379 2 Method:Bailer Purge Start Time:13:12 Required Bails for 3 Well Volumes:31 Purge Stop Time:13:23 Required Bails for 5 Well Volumes:52 Was Well Purged Dry? No Number of Bails Removed:31 Sample Time:13:25 Groundwater Removed (gal):7.4 Equipment Used: Time pH (Standard Units) ORP (mV) Specific Cond. (µS/cm) Dissolved Oxygen (mg/L) Temperature (Co) 13:10 12.30 -46.30 0.05 7.36 30.50 13:11 11.93 68.46 77.76 5.35 28.15 13:12 11.87 77.97 80.29 4.27 27.58 13:13 11.88 75.96 78.28 4.42 27.53 13:14 11.85 76.60 77.12 4.14 27.60 13:15 11.86 76.93 74.25 3.89 27.60 13:16 11.82 77.94 78.14 3.92 27.51 13:17 11.83 75.58 80.08 3.66 27.55 13:18 11.80 73.96 83.10 4.01 27.59 13:19 11.79 72.19 82.94 3.89 27.63 13:20 11.78 70.72 83.71 3.79 27.68 Laboratory:Con-Test Analysis:6200B Depth to Product (ft below TOC)Three Well Volumes (gal) Total Well Depth (ft)Five Well Volumes (gal) Well Diameter (inches) Purging Information Information Geochemical Parameters Aqua Troll 600 Turbidity and Additional Sampling Notes Mild turbidity: light tan. Strong HCO. Laboratory Analysis Information Depth to Water (ft below TOC)One Well Volume (gal) GROUNDWATER SAMPLING FORM Bud's Service Center Sandy Miller 221048 4/3/2023 NCDEQ-Linda Blalock Monitoring Well Information Well Data Volume of Groundwater in Well Well ID Water Column (ft below TOC) NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 April 2023 APPENDIX D EMISSIONS CALCULATIONS Page 1 of 2 DESCRIBE SOIL IN THE SATURATED ZONE: Unknown IDENTIFY THE WELL AND THE I.D. OF EACH WELL USED FOR AFVR: MW-1 and MW-4PROVIDE BLOWER SPECIFICATIONS OF THE VACUUM TRUCK (cfm @ in Hg): 18-20 " Hg COORDINATES USED FOR HUMIDITY RATIO CALCUALTIONS (Bwsw) (Lat, Long, Elev): 35.806246 Deg. Lat. and -77.863302 Deg. Long. DRY STANDARD CUBIC FEET PER MINUTE (DSCFM) AIR FLOW CALCULATIONS (Qstd) Time Meas. Vacuum AVP Velocity Pipe ID Temp.RH Bwsw Bws Qstd flow (in Hg)(in Hg)(ft/min)(in)(°F)(%)(grainsH2O/lbAir)(% v/v)(DSCFM) 7:30 18 11.92 17 6 60.4 75.8 59.48499618 0.990 0.035 7:45 18 11.92 13 6 70.6 88.8 100.2900549 0.994 0.0168:00 20 9.92 37 6 78.3 92.2 135.8280275 0.995 0.033 8:15 20 9.92 46 6 90.2 98.1 215.5883007 0.997 0.0258:30 20 9.92 46 6 105.4 98.9 355.4810465 0.998 0.015 8:45 20 9.92 35 6 122.6 100 619.3131759 0.999 0.0069:00 20 9.92 49 6 123.3 100 633.0839135 0.999 0.0099:15 20 9.92 190 6 145.1 100 1265.761891 1.000 0.016 9:30 20 9.92 147 6 140.4 100 1087.452531 0.999 0.01510:00 19 10.92 232 6 148.2 100 1400.981695 1.000 0.018 10:30 19 10.92 312 6 149.1 100 1443.227507 1.000 0.02311:00 19 10.92 139 6 147.2 100 1355.6707 1.000 0.011 11:30 19 10.92 305 6 151.8 100 1578.939473 1.000 0.02012:00 19 10.92 104 6 154.6 100 1735.494018 1.000 0.006 12:30 19 10.92 65 6 153.5 100 1671.924484 1.000 0.00413:00 19 10.92 127 6 140.2 100 1080.498295 0.999 0.01313:30 19 10.92 240 6 148.7 100 1424.276042 1.000 0.018 14:00 19 10.92 227 6 149.2 100 1448.009965 1.000 0.01714:30 19 10.92 52 6 145.8 100 1294.970914 1.000 0.004 15:00 20 9.92 62 6 151.6 100 1568.398899 1.000 0.00415:30 20 9.92 61 6 167.6 100 2761.832068 1.000 0.002 NOTESAVP = Absolute Vacuum Pressure Qstd = Flow at DSCFM Measured Vacuum = The level of vacuum being applied (should be recorded from the vacuum truck tank in inches of Hg) Velocity = The rate at which air flow is measured at the blower discharge piping (anemometer or pitot tube) Pipe ID = The inside diameter of the blower discharge piping (from the vacuum truck)Temperature = The temperature of the air stream exiting the blower discharge piping (dry bulb temp., in °F) RH = The % relative humidity of the air stream exiting the blower discharge piping Bwsw = Humidity Ratio (i.e. grains of water per lb of dry air, derived from the Psychrometric chart or calculator (dry bulb temp. vs. RH) Bws = water vapor % by volume EQUATIONS AVP = Standard Pressure (29.92 in Hg) - Measured Vacuum Bws = (Bwsw/18 lb-mole H2O)/[(1/28.84 lb-mole dry air) + (Bwsw/18 lb-mole H2O)] Qstd = (1-Water Vapor) * velocity * [PI * (diameter/24)2] * [528°R/(Temp + 460)] * (AVP/29.92) INDICATE AVERAGE HYDRAULIC CONDUCTIVITY (if known): Unknown AGGRESSIVE FLUID VAPOR RECOVERY (AFVR) EVENT SITE NAME: Bud's Service Center INCIDENT NUMBER: 13649 AVERAGE DEPTH TO GROUNDWATER: 2.85 Feet Below Top of Casing SDC Group, Inc.; 13649_Bud's Service Center_AFVR Calc\Calc AFVR Calculations CATLIN Engineers and Scientists April 2023 Page 2 of 2 EMISSION CALCULATIONS Elapsed Qstd Time Flow PPMmeasured PPMwet PPMdry K PPMconc Cc:m Cc PMRc PMRg PMR (min)(DSCFM)(ppm)(#C - gas)(mg/dsm3)(lb/dscf)(lb/hr)(lb/hr)(lb) 0 0.035 1120 1120 107865 4 431461 215282 0.013 0.028 0.033 0.000 15 0.016 2871 2871 464203 4 1856813 926478 0.058 0.055 0.063 0.016300.033 2675 2675 584826 4 2339306 1167223 0.073 0.143 0.165 0.041 45 0.025 2509 2509 869169 4 3476675 1734726 0.108 0.163 0.188 0.047600.015 2518 2518 1436669 4 5746677 2867370 0.179 0.159 0.184 0.046 75 0.006 2403 2403 2386845 4 9547382 4763775 0.297 0.112 0.129 0.032 90 0.009 2253 2253 2287564 4 9150254 4565623 0.285 0.147 0.170 0.0421050.016 908 908 1842361 4 7369444 3677068 0.230 0.221 0.256 0.128 120 0.015 655 655 1141888 4 4567552 2279032 0.142 0.124 0.144 0.0361500.018 392 392 880308 4 3521233 1756959 0.110 0.116 0.134 0.101 180 0.023 327 327 756472 4 3025890 1509802 0.094 0.130 0.150 0.0752100.011 237 237 515021 4 2060085 1027903 0.064 0.042 0.049 0.024 240 0.020 197 197 498570 4 1994280 995069 0.062 0.076 0.088 0.044 270 0.006 207 207 575801 4 2303204 1149210 0.072 0.027 0.031 0.0163000.004 209 209 560077 4 2240308 1117827 0.070 0.017 0.020 0.020 330 0.013 205 205 355101 4 1420403 708726 0.044 0.034 0.039 0.0193600.018 198 198 452035 4 1808141 902193 0.056 0.061 0.070 0.035 390 0.017 181 181 420107 4 1680428 838469 0.052 0.052 0.060 0.0304200.004 388 388 805422 4 3221690 1607499 0.100 0.026 0.030 0.015 450 0.004 1032 1032 2594369 4 10377476 5177960 0.323 0.081 0.094 0.0474800.002 1046 1046 4629668 4 18518671 9240102 0.577 0.079 0.091 0.046 Total emissions in pounds = 0.860 Total emissions in gallons = 0.138 NOTES PPMmeasured = Actual measurements (ppm) taken with a OVA, PID, or TVA at the blower discharge piping PPMwet = "wet" concentration PPMdry = "dry" concentration K = Number of carbons in calibration gas: (Methane K = 1, or Propane K = 3, or Isobutene K = 4, or Hexane K = 6) PPMc= PPMv, Volumetric concentration of VOC emissions as carbon, dry basis at STP Cc:m = mg/dsm3, mass concentration of VOC emissions as carbon Mc = 12.01 mg/mg-mole, molecular weight of carbon K3 = 24.07 dsm3/106 mg-mole, mass to volume conversion factor at STP Cc = lb/dcsf, mass concentration of VOC emissions as carbon, dry basis at STP PMRc = lb/hr, pollutant mass removal rate of VOCs as carbon PMRg = lb/hr, pollutant mass removal rate of VOCs as gasoline PMR = lb, pollutant mass removal of VOCs as gasoline EQUATIONS PPMwet = PPMmeasured PPMdry = (PPMwet)/(1-Bws) PPMconc = (PPMdry)(K) Cc:m = (PPMconc)(Mc / K3) Cc = (Cc:m)(62.43x10-9 lb-m3/mg-ft3) PMRc = (Cc)(Qstd)(60 min/hr) PMRg = (PMRc)(Mg/Mcg) PMR = (PMRg)(#minutes/60) SDC Group, Inc.; 13649_Bud's Service Center_AFVR Calc\Calc AFVR Calculations CATLIN Engineers and Scientists April 2023 NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 April 2023 APPENDIX E DISPOSAL DOCUMENTS NCDEQ; 13649_Bud's Service Center CATLIN Engineers and Scientists CATLIN Project No. 221048 April 2023 APPENDIX F LABORATORY ANALYTICAL REPORT AND CHAIN OF CUSTODY DOCUMENT 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 April 13, 2023 Sean O’Neil CATLIN Engineers & Scientists 1044 Washington Street Raleigh, NC 27605 Project Location: Elm City, NY Client Job Number: Project Number: 221048.2 Laboratory Work Order Number: 23D0148 Enclosed are results of analyses for samples as received by the laboratory on April 4, 2023. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kaitlyn A. Feliciano Project Manager Table of Contents Sample Summary 3 Hits Only Report 4 Case Narrative 6 Sample Results 8 23D0148-01 8 23D0148-02 10 23D0148-03 12 23D0148-04 14 23D0148-05 16 23D0148-06 18 23D0148-07 20 Sample Preparation Information 22 QC Data 23 Volatile Organic Compounds by GC/MS 23 B336483 23 B336621 27 Flag/Qualifier Summary 31 Certifications 32 Chain of Custody/Sample Receipt 34 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY 4/13/2023 CATLIN Engineers & Scientists 1044 Washington Street Raleigh, NC 27605 ATTN: Sean O’Neil 221048.2 23D0148 The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB Elm City, NY 230403-6 MW-1 23D0148-01 Ground Water SM21-23 6200B MW-2 23D0148-02 Ground Water SM21-23 6200B MW-3 23D0148-03 Ground Water SM21-23 6200B MW-4 23D0148-04 Ground Water SM21-23 6200B MW-5 23D0148-05 Ground Water SM21-23 6200B EB 23D0148-06 Ground Water SM21-23 6200B TB 23D0148-07 Ground Water SM21-23 6200B [TOC_1]Sample Summary[TOC] 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 [TOC_1]Hits Only Report[TOC]EXECUTIVE SUMMARY Client ID:Lab ID: Analyte Results/Qual RL Units Method 23D0148-01MW-1 DL 1,2,4-Trimethylbenzene 230 20 g/L SM21-23 6200B8.0 1,3,5-Trimethylbenzene 61 20 g/L SM21-23 6200B6.0 Benzene 2200 20 g/L SM21-23 6200B7.4 Diisopropyl Ether (DIPE)160 20 g/L SM21-23 6200B8.1 Ethylbenzene 350 20 g/L SM21-23 6200B8.8 Isopropylbenzene (Cumene)26 20 g/L SM21-23 6200B6.0 m+p Xylene 460 40 g/L SM21-23 6200B20 Methyl tert-Butyl Ether (MTBE)330 20 g/L SM21-23 6200B6.8 Naphthalene 42 20 g/L SM21-23 6200BL-04 15 n-Propylbenzene 49 20 g/L SM21-23 6200B5.0 o-Xylene 320 20 g/L SM21-23 6200B9.7 Toluene 1200 20 g/L SM21-23 6200B8.9 Client ID:Lab ID: Analyte Results/Qual RL Units Method 23D0148-02MW-2 DL 1,2,4-Trimethylbenzene 14 0.50 g/L SM21-23 6200B0.20 1,3,5-Trimethylbenzene 3.7 0.50 g/L SM21-23 6200B0.15 Benzene 18 0.50 g/L SM21-23 6200B0.18 Ethylbenzene 13 0.50 g/L SM21-23 6200B0.22 Isopropylbenzene (Cumene)17 0.50 g/L SM21-23 6200B0.15 m+p Xylene 21 1.0 g/L SM21-23 6200B0.49 Methyl tert-Butyl Ether (MTBE)0.58 0.50 g/L SM21-23 6200BR-05 0.17 Naphthalene 46 0.50 g/L SM21-23 6200BL-04 0.38 n-Butylbenzene 4.3 0.50 g/L SM21-23 6200B0.15 n-Propylbenzene 23 0.50 g/L SM21-23 6200B0.12 o-Xylene 1.6 0.50 g/L SM21-23 6200B0.24 p-Isopropyltoluene (p-Cymene)0.41 0.50 g/L SM21-23 6200BJ0.13 sec-Butylbenzene 12 0.50 g/L SM21-23 6200B0.13 tert-Butylbenzene 2.6 0.50 g/L SM21-23 6200B0.14 Toluene 1.4 0.50 g/L SM21-23 6200B0.22 Client ID:Lab ID: Analyte Results/Qual RL Units Method 23D0148-03MW-3 DL Acetone 8.5 50 g/L SM21-23 6200BJ2.0 Client ID:Lab ID: Analyte Results/Qual RL Units Method 23D0148-04MW-4 DL 1,2,4-Trimethylbenzene 2400 120 g/L SM21-23 6200B50 1,3,5-Trimethylbenzene 610 120 g/L SM21-23 6200B37 Benzene 2100 120 g/L SM21-23 6200B46 Ethylbenzene 2600 120 g/L SM21-23 6200B55 Isopropylbenzene (Cumene)140 120 g/L SM21-23 6200B38 m+p Xylene 9000 250 g/L SM21-23 6200B120 Naphthalene 430 120 g/L SM21-23 6200BL-04 95 n-Butylbenzene 85 120 g/L SM21-23 6200BJ37 n-Propylbenzene 300 120 g/L SM21-23 6200B31 o-Xylene 3800 120 g/L SM21-23 6200B61 Styrene 180 120 g/L SM21-23 6200B38 Toluene 16000 120 g/L SM21-23 6200B56 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Client ID:Lab ID: Analyte Results/Qual RL Units Method 23D0148-05MW-5 DL 1,2,4-Trimethylbenzene 2000 120 g/L SM21-23 6200B50 1,3,5-Trimethylbenzene 420 120 g/L SM21-23 6200B37 Benzene 2100 120 g/L SM21-23 6200B46 Ethylbenzene 3000 120 g/L SM21-23 6200B55 Isopropylbenzene (Cumene)110 120 g/L SM21-23 6200BJ38 m+p Xylene 9700 250 g/L SM21-23 6200B120 Naphthalene 300 120 g/L SM21-23 6200BL-04 95 n-Propylbenzene 280 120 g/L SM21-23 6200B31 o-Xylene 4700 120 g/L SM21-23 6200B61 Toluene 19000 120 g/L SM21-23 6200B56 Client ID:Lab ID: Analyte Results/Qual RL Units Method 23D0148-06EB DL Acetone 9.0 50 g/L SM21-23 6200BJ2.0 Client ID:Lab ID: Analyte Results/Qual RL Units Method 23D0148-07TB DL Acetone 8.8 50 g/L SM21-23 6200BJ2.0 Con-Test does not accept liability for the consequences of any actions taken solely on the basis of the information provided in the Executive Summary section of this report. Users must review this report in its entirety to determine data usability and assessment. 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. For method 6200B elevated reporting limits for samples 23D0148-01,04+05 due to high concentrations of target compounds. [TOC_1]Case Narrative[TOC] SM21-23 6200B Qualifications: Laboratory fortified blank/laboratory control sample recovery and duplicate recovery are outside of control limits. Reported value for this compound is likely to be biased on the low side. Analyte & Samples(s) Qualified: L-04 1,2,3-Trichlorobenzene 23D0148-01[MW-1], 23D0148-02[MW-2], 23D0148-03[MW-3], 23D0148-04[MW-4], 23D0148-05[MW-5], 23D0148-06[EB], 23D0148-07[TB], B336483-BLK1, B336483-BS1, B336483-BSD1, B336621-BLK1, B336621-BS1, B336621-BSD1 Naphthalene 23D0148-01[MW-1], 23D0148-02[MW-2], 23D0148-03[MW-3], 23D0148-04[MW-4], 23D0148-05[MW-5], 23D0148-06[EB], 23D0148-07[TB], B336483-BLK1, B336483-BS1, B336483-BSD1, B336621-BLK1, B336621-BS1, B336621-BSD1 Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but the other is within limits. RPD between the two LFB/LCS results is within method specified criteria. Analyte & Samples(s) Qualified: L-07 1,1-Dichloroethylene B336621-BSD1 1,2,4-Trichlorobenzene B336483-BSD1 Acetone B336483-BSD1 Laboratory fortified blank duplicate RPD is outside of control limits. Reduced precision is anticipated for any reported value for this compound. Analyte & Samples(s) Qualified: R-05 1,2,3-Trichloropropane 23D0148-01[MW-1], 23D0148-02[MW-2], 23D0148-03[MW-3], 23D0148-04[MW-4], 23D0148-05[MW-5], 23D0148-06[EB], 23D0148-07[TB], B336483-BLK1, B336483-BS1, B336483-BSD1, B336621-BLK1, B336621-BS1, B336621-BSD1 Methyl tert-Butyl Ether (MTBE) 23D0148-02[MW-2], 23D0148-03[MW-3], 23D0148-04[MW-4], 23D0148-05[MW-5], 23D0148-06[EB], 23D0148-07[TB], B336483-BLK1, B336483-BS1, B336483-BSD1 trans-1,2-Dichloroethylene 23D0148-02[MW-2], 23D0148-03[MW-3], 23D0148-04[MW-4], 23D0148-05[MW-5], 23D0148-06[EB], 23D0148-07[TB], B336483-BLK1, B336483-BS1, B336483-BSD1 Elevated reporting limit due to high concentration of target compounds. Analyte & Samples(s) Qualified: RL-11 23D0148-01[MW-1], 23D0148-04[MW-4], 23D0148-05[MW-5] 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Meghan E. Kelley Reporting Specialist 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 4/4/2023 Work Order: 23D0148Sample Description:Project Location: Elm City, NY Sample ID: 23D0148-01 Field Sample #: MW-1 Sample Matrix: Ground Water Sampled: 4/3/2023 11:18 [TOC_2]23D0148-01[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Sample Flags: RL-11 Volatile Organic Compounds by GC/MS ND 2000 4/11/23 21:31 EEHg/L80 4/7/23SM21-23 6200B40Acetone 2200 20 4/11/23 21:31 EEHg/L7.4 4/7/23SM21-23 6200B40Benzene ND 20 4/11/23 21:31 EEHg/L5.9 4/7/23SM21-23 6200B40Bromobenzene ND 20 4/11/23 21:31 EEHg/L11 4/7/23SM21-23 6200B40Bromochloromethane ND 20 4/11/23 21:31 EEHg/L6.3 4/7/23SM21-23 6200B40Bromodichloromethane ND 20 4/11/23 21:31 EEHg/L16 4/7/23SM21-23 6200B40Bromoform ND 80 4/11/23 21:31 EEHg/L53 4/7/23SM21-23 6200B40Bromomethane ND 200 4/11/23 21:31 EEHg/L67 4/7/23SM21-23 6200B402-Butanone (MEK) ND 20 4/11/23 21:31 EEHg/L6.0 4/7/23SM21-23 6200B40n-Butylbenzene ND 20 4/11/23 21:31 EEHg/L5.1 4/7/23SM21-23 6200B40sec-Butylbenzene ND 20 4/11/23 21:31 EEHg/L5.7 4/7/23SM21-23 6200B40tert-Butylbenzene ND 20 4/11/23 21:31 EEHg/L6.5 4/7/23SM21-23 6200B40Carbon Tetrachloride ND 20 4/11/23 21:31 EEHg/L4.8 4/7/23SM21-23 6200B40Chlorobenzene ND 2000 4/11/23 21:31 EEHg/L810 4/7/23SM21-23 6200B40Ethanol ND 20 4/11/23 21:31 EEHg/L8.0 4/7/23SM21-23 6200B40Chlorodibromomethane ND 20 4/11/23 21:31 EEHg/L14 4/7/23SM21-23 6200B40Chloroethane ND 20 4/11/23 21:31 EEHg/L5.6 4/7/23SM21-23 6200B40Chloroform ND 24 4/11/23 21:31 EEHg/L20 4/7/23SM21-23 6200B40Chloromethane ND 20 4/11/23 21:31 EEHg/L6.2 4/7/23SM21-23 6200B402-Chlorotoluene ND 20 4/11/23 21:31 EEHg/L6.2 4/7/23SM21-23 6200B404-Chlorotoluene ND 20 4/11/23 21:31 EEHg/L6.4 4/7/23SM21-23 6200B401,2-Dibromoethane (EDB) ND 20 4/11/23 21:31 EEHg/L5.2 4/7/23SM21-23 6200B401,2-Dichlorobenzene ND 20 4/11/23 21:31 EEHg/L5.5 4/7/23SM21-23 6200B401,3-Dichlorobenzene ND 20 4/11/23 21:31 EEHg/L5.1 4/7/23SM21-23 6200B401,4-Dichlorobenzene ND 20 4/11/23 21:31 EEHg/L6.4 4/7/23SM21-23 6200B40Dichlorodifluoromethane (Freon 12) ND 20 4/11/23 21:31 EEHg/L5.5 4/7/23SM21-23 6200B401,1-Dichloroethane ND 20 4/11/23 21:31 EEHg/L12 4/7/23SM21-23 6200B401,2-Dichloroethane ND 20 4/11/23 21:31 EEHg/L5.6 4/7/23SM21-23 6200B401,1-Dichloroethylene ND 20 4/11/23 21:31 EEHg/L5.6 4/7/23SM21-23 6200B40cis-1,2-Dichloroethylene ND 20 4/11/23 21:31 EEHg/L6.9 4/7/23SM21-23 6200B40trans-1,2-Dichloroethylene ND 20 4/11/23 21:31 EEHg/L7.7 4/7/23SM21-23 6200B401,2-Dichloropropane ND 20 4/11/23 21:31 EEHg/L4.6 4/7/23SM21-23 6200B401,3-Dichloropropane ND 20 4/11/23 21:31 EEHg/L14 4/7/23SM21-23 6200B402,2-Dichloropropane ND 20 4/11/23 21:31 EEHg/L6.0 4/7/23SM21-23 6200B401,1-Dichloropropene ND 20 4/11/23 21:31 EEHg/L6.5 4/7/23SM21-23 6200B40cis-1,3-Dichloropropene ND 20 4/11/23 21:31 EEHg/L5.7 4/7/23SM21-23 6200B40trans-1,3-Dichloropropene 160 20 4/11/23 21:31 EEHg/L8.1 4/7/23SM21-23 6200B40Diisopropyl Ether (DIPE) 350 20 4/11/23 21:31 EEHg/L8.8 4/7/23SM21-23 6200B40Ethylbenzene ND 200 4/11/23 21:31 EEHg/L48 4/7/23SM21-23 6200B402-Hexanone (MBK) 26 20 4/11/23 21:31 EEHg/L6.0 4/7/23SM21-23 6200B40Isopropylbenzene (Cumene) ND 20 4/11/23 21:31 EEHg/L5.1 4/7/23SM21-23 6200B40p-Isopropyltoluene (p-Cymene) 330 20 4/11/23 21:31 EEHg/L6.8 4/7/23SM21-23 6200B40Methyl tert-Butyl Ether (MTBE) ND 200 4/11/23 21:31 EEHg/L7.1 4/7/23SM21-23 6200B40Methylene Chloride ND 200 4/11/23 21:31 EEHg/L53 4/7/23SM21-23 6200B404-Methyl-2-pentanone (MIBK) [TOC_1]Sample Results[TOC] 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 4/4/2023 Work Order: 23D0148Sample Description:Project Location: Elm City, NY Sample ID: 23D0148-01 Field Sample #: MW-1 Sample Matrix: Ground Water Sampled: 4/3/2023 11:18 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Sample Flags: RL-11 Volatile Organic Compounds by GC/MS 42 20 4/11/23 21:31 EEHg/L15 4/7/23SM21-23 6200B40L-04Naphthalene 49 20 4/11/23 21:31 EEHg/L5.0 4/7/23SM21-23 6200B40n-Propylbenzene ND 20 4/11/23 21:31 EEHg/L6.0 4/7/23SM21-23 6200B40Styrene ND 20 4/11/23 21:31 EEHg/L5.5 4/7/23SM21-23 6200B401,1,2,2-Tetrachloroethane ND 20 4/11/23 21:31 EEHg/L6.7 4/7/23SM21-23 6200B40Tetrachloroethylene 1200 20 4/11/23 21:31 EEHg/L8.9 4/7/23SM21-23 6200B40Toluene ND 40 4/11/23 21:31 EEHg/L14 4/7/23SM21-23 6200B40L-041,2,3-Trichlorobenzene ND 40 4/11/23 21:31 EEHg/L12 4/7/23SM21-23 6200B401,2,4-Trichlorobenzene ND 20 4/11/23 21:31 EEHg/L6.0 4/7/23SM21-23 6200B401,1,1-Trichloroethane ND 20 4/11/23 21:31 EEHg/L7.6 4/7/23SM21-23 6200B401,1,2-Trichloroethane ND 20 4/11/23 21:31 EEHg/L7.0 4/7/23SM21-23 6200B40Trichloroethylene ND 20 4/11/23 21:31 EEHg/L6.2 4/7/23SM21-23 6200B40Trichlorofluoromethane (Freon 11) ND 20 4/11/23 21:31 EEHg/L11 4/7/23SM21-23 6200B40R-051,2,3-Trichloropropane 230 20 4/11/23 21:31 EEHg/L8.0 4/7/23SM21-23 6200B401,2,4-Trimethylbenzene 61 20 4/11/23 21:31 EEHg/L6.0 4/7/23SM21-23 6200B401,3,5-Trimethylbenzene ND 800 4/11/23 21:31 EEHg/L67 4/7/23SM21-23 6200B40Vinyl Acetate ND 20 4/11/23 21:31 EEHg/L9.5 4/7/23SM21-23 6200B40Vinyl Chloride 460 40 4/11/23 21:31 EEHg/L20 4/7/23SM21-23 6200B40m+p Xylene 320 20 4/11/23 21:31 EEHg/L9.7 4/7/23SM21-23 6200B40o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 98.2 4/11/23 21:3170-130 Toluene-d8 98.3 4/11/23 21:3170-130 4-Bromofluorobenzene 97.4 4/11/23 21:3170-130 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 4/4/2023 Work Order: 23D0148Sample Description:Project Location: Elm City, NY Sample ID: 23D0148-02 Field Sample #: MW-2 Sample Matrix: Ground Water Sampled: 4/3/2023 11:47 [TOC_2]23D0148-02[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 50 4/8/23 9:08 MFFg/L2.0 4/7/23SM21-23 6200B1Acetone 18 0.50 4/8/23 9:08 MFFg/L0.18 4/7/23SM21-23 6200B1Benzene ND 0.50 4/8/23 9:08 MFFg/L0.15 4/7/23SM21-23 6200B1Bromobenzene ND 0.50 4/8/23 9:08 MFFg/L0.28 4/7/23SM21-23 6200B1Bromochloromethane ND 0.50 4/8/23 9:08 MFFg/L0.16 4/7/23SM21-23 6200B1Bromodichloromethane ND 0.50 4/8/23 9:08 MFFg/L0.41 4/7/23SM21-23 6200B1Bromoform ND 2.0 4/8/23 9:08 MFFg/L1.3 4/7/23SM21-23 6200B1Bromomethane ND 5.0 4/8/23 9:08 MFFg/L1.7 4/7/23SM21-23 6200B12-Butanone (MEK) 4.3 0.50 4/8/23 9:08 MFFg/L0.15 4/7/23SM21-23 6200B1n-Butylbenzene 12 0.50 4/8/23 9:08 MFFg/L0.13 4/7/23SM21-23 6200B1sec-Butylbenzene 2.6 0.50 4/8/23 9:08 MFFg/L0.14 4/7/23SM21-23 6200B1tert-Butylbenzene ND 0.50 4/8/23 9:08 MFFg/L0.16 4/7/23SM21-23 6200B1Carbon Tetrachloride ND 0.50 4/8/23 9:08 MFFg/L0.12 4/7/23SM21-23 6200B1Chlorobenzene ND 50 4/8/23 9:08 MFFg/L20 4/7/23SM21-23 6200B1Ethanol ND 0.50 4/8/23 9:08 MFFg/L0.20 4/7/23SM21-23 6200B1Chlorodibromomethane ND 0.50 4/8/23 9:08 MFFg/L0.34 4/7/23SM21-23 6200B1Chloroethane ND 0.50 4/8/23 9:08 MFFg/L0.14 4/7/23SM21-23 6200B1Chloroform ND 0.60 4/8/23 9:08 MFFg/L0.50 4/7/23SM21-23 6200B1Chloromethane ND 0.50 4/8/23 9:08 MFFg/L0.15 4/7/23SM21-23 6200B12-Chlorotoluene ND 0.50 4/8/23 9:08 MFFg/L0.15 4/7/23SM21-23 6200B14-Chlorotoluene ND 0.50 4/8/23 9:08 MFFg/L0.16 4/7/23SM21-23 6200B11,2-Dibromoethane (EDB) ND 0.50 4/8/23 9:08 MFFg/L0.13 4/7/23SM21-23 6200B11,2-Dichlorobenzene ND 0.50 4/8/23 9:08 MFFg/L0.14 4/7/23SM21-23 6200B11,3-Dichlorobenzene ND 0.50 4/8/23 9:08 MFFg/L0.13 4/7/23SM21-23 6200B11,4-Dichlorobenzene ND 0.50 4/8/23 9:08 MFFg/L0.16 4/7/23SM21-23 6200B1Dichlorodifluoromethane (Freon 12) ND 0.50 4/8/23 9:08 MFFg/L0.14 4/7/23SM21-23 6200B11,1-Dichloroethane ND 0.50 4/8/23 9:08 MFFg/L0.30 4/7/23SM21-23 6200B11,2-Dichloroethane ND 0.50 4/8/23 9:08 MFFg/L0.14 4/7/23SM21-23 6200B11,1-Dichloroethylene ND 0.50 4/8/23 9:08 MFFg/L0.14 4/7/23SM21-23 6200B1cis-1,2-Dichloroethylene ND 0.50 4/8/23 9:08 MFFg/L0.17 4/7/23SM21-23 6200B1R-05trans-1,2-Dichloroethylene ND 0.50 4/8/23 9:08 MFFg/L0.19 4/7/23SM21-23 6200B11,2-Dichloropropane ND 0.50 4/8/23 9:08 MFFg/L0.12 4/7/23SM21-23 6200B11,3-Dichloropropane ND 0.50 4/8/23 9:08 MFFg/L0.35 4/7/23SM21-23 6200B12,2-Dichloropropane ND 0.50 4/8/23 9:08 MFFg/L0.15 4/7/23SM21-23 6200B11,1-Dichloropropene ND 0.50 4/8/23 9:08 MFFg/L0.16 4/7/23SM21-23 6200B1cis-1,3-Dichloropropene ND 0.50 4/8/23 9:08 MFFg/L0.14 4/7/23SM21-23 6200B1trans-1,3-Dichloropropene ND 0.50 4/8/23 9:08 MFFg/L0.20 4/7/23SM21-23 6200B1Diisopropyl Ether (DIPE) 13 0.50 4/8/23 9:08 MFFg/L0.22 4/7/23SM21-23 6200B1Ethylbenzene ND 5.0 4/8/23 9:08 MFFg/L1.2 4/7/23SM21-23 6200B12-Hexanone (MBK) 17 0.50 4/8/23 9:08 MFFg/L0.15 4/7/23SM21-23 6200B1Isopropylbenzene (Cumene) 0.41 0.50 4/8/23 9:08 MFFg/L0.13 4/7/23SM21-23 6200B1Jp-Isopropyltoluene (p-Cymene) 0.58 0.50 4/8/23 9:08 MFFg/L0.17 4/7/23SM21-23 6200B1R-05Methyl tert-Butyl Ether (MTBE) ND 5.0 4/8/23 9:08 MFFg/L0.18 4/7/23SM21-23 6200B1Methylene Chloride ND 5.0 4/8/23 9:08 MFFg/L1.3 4/7/23SM21-23 6200B14-Methyl-2-pentanone (MIBK) 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 4/4/2023 Work Order: 23D0148Sample Description:Project Location: Elm City, NY Sample ID: 23D0148-02 Field Sample #: MW-2 Sample Matrix: Ground Water Sampled: 4/3/2023 11:47 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS 46 0.50 4/8/23 9:08 MFFg/L0.38 4/7/23SM21-23 6200B1L-04Naphthalene 23 0.50 4/8/23 9:08 MFFg/L0.12 4/7/23SM21-23 6200B1n-Propylbenzene ND 0.50 4/8/23 9:08 MFFg/L0.15 4/7/23SM21-23 6200B1Styrene ND 0.50 4/8/23 9:08 MFFg/L0.14 4/7/23SM21-23 6200B11,1,2,2-Tetrachloroethane ND 0.50 4/8/23 9:08 MFFg/L0.17 4/7/23SM21-23 6200B1Tetrachloroethylene 1.4 0.50 4/8/23 9:08 MFFg/L0.22 4/7/23SM21-23 6200B1Toluene ND 1.0 4/8/23 9:08 MFFg/L0.34 4/7/23SM21-23 6200B1L-041,2,3-Trichlorobenzene ND 1.0 4/8/23 9:08 MFFg/L0.30 4/7/23SM21-23 6200B11,2,4-Trichlorobenzene ND 0.50 4/8/23 9:08 MFFg/L0.15 4/7/23SM21-23 6200B11,1,1-Trichloroethane ND 0.50 4/8/23 9:08 MFFg/L0.19 4/7/23SM21-23 6200B11,1,2-Trichloroethane ND 0.50 4/8/23 9:08 MFFg/L0.17 4/7/23SM21-23 6200B1Trichloroethylene ND 0.50 4/8/23 9:08 MFFg/L0.15 4/7/23SM21-23 6200B1Trichlorofluoromethane (Freon 11) ND 0.50 4/8/23 9:08 MFFg/L0.28 4/7/23SM21-23 6200B1R-051,2,3-Trichloropropane 14 0.50 4/8/23 9:08 MFFg/L0.20 4/7/23SM21-23 6200B11,2,4-Trimethylbenzene 3.7 0.50 4/8/23 9:08 MFFg/L0.15 4/7/23SM21-23 6200B11,3,5-Trimethylbenzene ND 20 4/8/23 9:08 MFFg/L1.7 4/7/23SM21-23 6200B1Vinyl Acetate ND 0.50 4/8/23 9:08 MFFg/L0.24 4/7/23SM21-23 6200B1Vinyl Chloride 21 1.0 4/8/23 9:08 MFFg/L0.49 4/7/23SM21-23 6200B1m+p Xylene 1.6 0.50 4/8/23 9:08 MFFg/L0.24 4/7/23SM21-23 6200B1o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 99.2 4/8/23 9:0870-130 Toluene-d8 99.4 4/8/23 9:0870-130 4-Bromofluorobenzene 96.6 4/8/23 9:0870-130 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 4/4/2023 Work Order: 23D0148Sample Description:Project Location: Elm City, NY Sample ID: 23D0148-03 Field Sample #: MW-3 Sample Matrix: Ground Water Sampled: 4/3/2023 12:27 [TOC_2]23D0148-03[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS 8.5 50 4/8/23 8:40 MFFg/L2.0 4/7/23SM21-23 6200B1JAcetone ND 0.50 4/8/23 8:40 MFFg/L0.18 4/7/23SM21-23 6200B1Benzene ND 0.50 4/8/23 8:40 MFFg/L0.15 4/7/23SM21-23 6200B1Bromobenzene ND 0.50 4/8/23 8:40 MFFg/L0.28 4/7/23SM21-23 6200B1Bromochloromethane ND 0.50 4/8/23 8:40 MFFg/L0.16 4/7/23SM21-23 6200B1Bromodichloromethane ND 0.50 4/8/23 8:40 MFFg/L0.41 4/7/23SM21-23 6200B1Bromoform ND 2.0 4/8/23 8:40 MFFg/L1.3 4/7/23SM21-23 6200B1Bromomethane ND 5.0 4/8/23 8:40 MFFg/L1.7 4/7/23SM21-23 6200B12-Butanone (MEK) ND 0.50 4/8/23 8:40 MFFg/L0.15 4/7/23SM21-23 6200B1n-Butylbenzene ND 0.50 4/8/23 8:40 MFFg/L0.13 4/7/23SM21-23 6200B1sec-Butylbenzene ND 0.50 4/8/23 8:40 MFFg/L0.14 4/7/23SM21-23 6200B1tert-Butylbenzene ND 0.50 4/8/23 8:40 MFFg/L0.16 4/7/23SM21-23 6200B1Carbon Tetrachloride ND 0.50 4/8/23 8:40 MFFg/L0.12 4/7/23SM21-23 6200B1Chlorobenzene ND 50 4/8/23 8:40 MFFg/L20 4/7/23SM21-23 6200B1Ethanol ND 0.50 4/8/23 8:40 MFFg/L0.20 4/7/23SM21-23 6200B1Chlorodibromomethane ND 0.50 4/8/23 8:40 MFFg/L0.34 4/7/23SM21-23 6200B1Chloroethane ND 0.50 4/8/23 8:40 MFFg/L0.14 4/7/23SM21-23 6200B1Chloroform ND 0.60 4/8/23 8:40 MFFg/L0.50 4/7/23SM21-23 6200B1Chloromethane ND 0.50 4/8/23 8:40 MFFg/L0.15 4/7/23SM21-23 6200B12-Chlorotoluene ND 0.50 4/8/23 8:40 MFFg/L0.15 4/7/23SM21-23 6200B14-Chlorotoluene ND 0.50 4/8/23 8:40 MFFg/L0.16 4/7/23SM21-23 6200B11,2-Dibromoethane (EDB) ND 0.50 4/8/23 8:40 MFFg/L0.13 4/7/23SM21-23 6200B11,2-Dichlorobenzene ND 0.50 4/8/23 8:40 MFFg/L0.14 4/7/23SM21-23 6200B11,3-Dichlorobenzene ND 0.50 4/8/23 8:40 MFFg/L0.13 4/7/23SM21-23 6200B11,4-Dichlorobenzene ND 0.50 4/8/23 8:40 MFFg/L0.16 4/7/23SM21-23 6200B1Dichlorodifluoromethane (Freon 12) ND 0.50 4/8/23 8:40 MFFg/L0.14 4/7/23SM21-23 6200B11,1-Dichloroethane ND 0.50 4/8/23 8:40 MFFg/L0.30 4/7/23SM21-23 6200B11,2-Dichloroethane ND 0.50 4/8/23 8:40 MFFg/L0.14 4/7/23SM21-23 6200B11,1-Dichloroethylene ND 0.50 4/8/23 8:40 MFFg/L0.14 4/7/23SM21-23 6200B1cis-1,2-Dichloroethylene ND 0.50 4/8/23 8:40 MFFg/L0.17 4/7/23SM21-23 6200B1R-05trans-1,2-Dichloroethylene ND 0.50 4/8/23 8:40 MFFg/L0.19 4/7/23SM21-23 6200B11,2-Dichloropropane ND 0.50 4/8/23 8:40 MFFg/L0.12 4/7/23SM21-23 6200B11,3-Dichloropropane ND 0.50 4/8/23 8:40 MFFg/L0.35 4/7/23SM21-23 6200B12,2-Dichloropropane ND 0.50 4/8/23 8:40 MFFg/L0.15 4/7/23SM21-23 6200B11,1-Dichloropropene ND 0.50 4/8/23 8:40 MFFg/L0.16 4/7/23SM21-23 6200B1cis-1,3-Dichloropropene ND 0.50 4/8/23 8:40 MFFg/L0.14 4/7/23SM21-23 6200B1trans-1,3-Dichloropropene ND 0.50 4/8/23 8:40 MFFg/L0.20 4/7/23SM21-23 6200B1Diisopropyl Ether (DIPE) ND 0.50 4/8/23 8:40 MFFg/L0.22 4/7/23SM21-23 6200B1Ethylbenzene ND 5.0 4/8/23 8:40 MFFg/L1.2 4/7/23SM21-23 6200B12-Hexanone (MBK) ND 0.50 4/8/23 8:40 MFFg/L0.15 4/7/23SM21-23 6200B1Isopropylbenzene (Cumene) ND 0.50 4/8/23 8:40 MFFg/L0.13 4/7/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene) ND 0.50 4/8/23 8:40 MFFg/L0.17 4/7/23SM21-23 6200B1R-05Methyl tert-Butyl Ether (MTBE) ND 5.0 4/8/23 8:40 MFFg/L0.18 4/7/23SM21-23 6200B1Methylene Chloride ND 5.0 4/8/23 8:40 MFFg/L1.3 4/7/23SM21-23 6200B14-Methyl-2-pentanone (MIBK) 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 4/4/2023 Work Order: 23D0148Sample Description:Project Location: Elm City, NY Sample ID: 23D0148-03 Field Sample #: MW-3 Sample Matrix: Ground Water Sampled: 4/3/2023 12:27 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 0.50 4/8/23 8:40 MFFg/L0.38 4/7/23SM21-23 6200B1L-04Naphthalene ND 0.50 4/8/23 8:40 MFFg/L0.12 4/7/23SM21-23 6200B1n-Propylbenzene ND 0.50 4/8/23 8:40 MFFg/L0.15 4/7/23SM21-23 6200B1Styrene ND 0.50 4/8/23 8:40 MFFg/L0.14 4/7/23SM21-23 6200B11,1,2,2-Tetrachloroethane ND 0.50 4/8/23 8:40 MFFg/L0.17 4/7/23SM21-23 6200B1Tetrachloroethylene ND 0.50 4/8/23 8:40 MFFg/L0.22 4/7/23SM21-23 6200B1Toluene ND 1.0 4/8/23 8:40 MFFg/L0.34 4/7/23SM21-23 6200B1L-041,2,3-Trichlorobenzene ND 1.0 4/8/23 8:40 MFFg/L0.30 4/7/23SM21-23 6200B11,2,4-Trichlorobenzene ND 0.50 4/8/23 8:40 MFFg/L0.15 4/7/23SM21-23 6200B11,1,1-Trichloroethane ND 0.50 4/8/23 8:40 MFFg/L0.19 4/7/23SM21-23 6200B11,1,2-Trichloroethane ND 0.50 4/8/23 8:40 MFFg/L0.17 4/7/23SM21-23 6200B1Trichloroethylene ND 0.50 4/8/23 8:40 MFFg/L0.15 4/7/23SM21-23 6200B1Trichlorofluoromethane (Freon 11) ND 0.50 4/8/23 8:40 MFFg/L0.28 4/7/23SM21-23 6200B1R-051,2,3-Trichloropropane ND 0.50 4/8/23 8:40 MFFg/L0.20 4/7/23SM21-23 6200B11,2,4-Trimethylbenzene ND 0.50 4/8/23 8:40 MFFg/L0.15 4/7/23SM21-23 6200B11,3,5-Trimethylbenzene ND 20 4/8/23 8:40 MFFg/L1.7 4/7/23SM21-23 6200B1Vinyl Acetate ND 0.50 4/8/23 8:40 MFFg/L0.24 4/7/23SM21-23 6200B1Vinyl Chloride ND 1.0 4/8/23 8:40 MFFg/L0.49 4/7/23SM21-23 6200B1m+p Xylene ND 0.50 4/8/23 8:40 MFFg/L0.24 4/7/23SM21-23 6200B1o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 101 4/8/23 8:4070-130 Toluene-d8 99.6 4/8/23 8:4070-130 4-Bromofluorobenzene 96.4 4/8/23 8:4070-130 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 4/4/2023 Work Order: 23D0148Sample Description:Project Location: Elm City, NY Sample ID: 23D0148-04 Field Sample #: MW-4 Sample Matrix: Ground Water Sampled: 4/3/2023 12:54 [TOC_2]23D0148-04[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Sample Flags: RL-11 Volatile Organic Compounds by GC/MS ND 12000 4/8/23 10:29 MFFg/L500 4/7/23SM21-23 6200B250Acetone 2100 120 4/8/23 10:29 MFFg/L46 4/7/23SM21-23 6200B250Benzene ND 120 4/8/23 10:29 MFFg/L37 4/7/23SM21-23 6200B250Bromobenzene ND 120 4/8/23 10:29 MFFg/L71 4/7/23SM21-23 6200B250Bromochloromethane ND 120 4/8/23 10:29 MFFg/L39 4/7/23SM21-23 6200B250Bromodichloromethane ND 120 4/8/23 10:29 MFFg/L100 4/7/23SM21-23 6200B250Bromoform ND 500 4/8/23 10:29 MFFg/L330 4/7/23SM21-23 6200B250Bromomethane ND 1200 4/8/23 10:29 MFFg/L420 4/7/23SM21-23 6200B2502-Butanone (MEK) 85 120 4/8/23 10:29 MFFg/L37 4/7/23SM21-23 6200B250Jn-Butylbenzene ND 120 4/8/23 10:29 MFFg/L32 4/7/23SM21-23 6200B250sec-Butylbenzene ND 120 4/8/23 10:29 MFFg/L35 4/7/23SM21-23 6200B250tert-Butylbenzene ND 120 4/8/23 10:29 MFFg/L41 4/7/23SM21-23 6200B250Carbon Tetrachloride ND 120 4/8/23 10:29 MFFg/L30 4/7/23SM21-23 6200B250Chlorobenzene ND 12000 4/8/23 10:29 MFFg/L5100 4/7/23SM21-23 6200B250Ethanol ND 120 4/8/23 10:29 MFFg/L50 4/7/23SM21-23 6200B250Chlorodibromomethane ND 120 4/8/23 10:29 MFFg/L86 4/7/23SM21-23 6200B250Chloroethane ND 120 4/8/23 10:29 MFFg/L35 4/7/23SM21-23 6200B250Chloroform ND 150 4/8/23 10:29 MFFg/L130 4/7/23SM21-23 6200B250Chloromethane ND 120 4/8/23 10:29 MFFg/L39 4/7/23SM21-23 6200B2502-Chlorotoluene ND 120 4/8/23 10:29 MFFg/L38 4/7/23SM21-23 6200B2504-Chlorotoluene ND 120 4/8/23 10:29 MFFg/L40 4/7/23SM21-23 6200B2501,2-Dibromoethane (EDB) ND 120 4/8/23 10:29 MFFg/L32 4/7/23SM21-23 6200B2501,2-Dichlorobenzene ND 120 4/8/23 10:29 MFFg/L34 4/7/23SM21-23 6200B2501,3-Dichlorobenzene ND 120 4/8/23 10:29 MFFg/L32 4/7/23SM21-23 6200B2501,4-Dichlorobenzene ND 120 4/8/23 10:29 MFFg/L40 4/7/23SM21-23 6200B250Dichlorodifluoromethane (Freon 12) ND 120 4/8/23 10:29 MFFg/L34 4/7/23SM21-23 6200B2501,1-Dichloroethane ND 120 4/8/23 10:29 MFFg/L76 4/7/23SM21-23 6200B2501,2-Dichloroethane ND 120 4/8/23 10:29 MFFg/L35 4/7/23SM21-23 6200B2501,1-Dichloroethylene ND 120 4/8/23 10:29 MFFg/L35 4/7/23SM21-23 6200B250cis-1,2-Dichloroethylene ND 120 4/8/23 10:29 MFFg/L43 4/7/23SM21-23 6200B250R-05trans-1,2-Dichloroethylene ND 120 4/8/23 10:29 MFFg/L48 4/7/23SM21-23 6200B2501,2-Dichloropropane ND 120 4/8/23 10:29 MFFg/L29 4/7/23SM21-23 6200B2501,3-Dichloropropane ND 120 4/8/23 10:29 MFFg/L87 4/7/23SM21-23 6200B2502,2-Dichloropropane ND 120 4/8/23 10:29 MFFg/L37 4/7/23SM21-23 6200B2501,1-Dichloropropene ND 120 4/8/23 10:29 MFFg/L41 4/7/23SM21-23 6200B250cis-1,3-Dichloropropene ND 120 4/8/23 10:29 MFFg/L35 4/7/23SM21-23 6200B250trans-1,3-Dichloropropene ND 120 4/8/23 10:29 MFFg/L50 4/7/23SM21-23 6200B250Diisopropyl Ether (DIPE) 2600 120 4/8/23 10:29 MFFg/L55 4/7/23SM21-23 6200B250Ethylbenzene ND 1200 4/8/23 10:29 MFFg/L300 4/7/23SM21-23 6200B2502-Hexanone (MBK) 140 120 4/8/23 10:29 MFFg/L38 4/7/23SM21-23 6200B250Isopropylbenzene (Cumene) ND 120 4/8/23 10:29 MFFg/L32 4/7/23SM21-23 6200B250p-Isopropyltoluene (p-Cymene) ND 120 4/8/23 10:29 MFFg/L43 4/7/23SM21-23 6200B250R-05Methyl tert-Butyl Ether (MTBE) ND 1200 4/8/23 10:29 MFFg/L44 4/7/23SM21-23 6200B250Methylene Chloride ND 1200 4/8/23 10:29 MFFg/L330 4/7/23SM21-23 6200B2504-Methyl-2-pentanone (MIBK) 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 4/4/2023 Work Order: 23D0148Sample Description:Project Location: Elm City, NY Sample ID: 23D0148-04 Field Sample #: MW-4 Sample Matrix: Ground Water Sampled: 4/3/2023 12:54 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Sample Flags: RL-11 Volatile Organic Compounds by GC/MS 430 120 4/8/23 10:29 MFFg/L95 4/7/23SM21-23 6200B250L-04Naphthalene 300 120 4/8/23 10:29 MFFg/L31 4/7/23SM21-23 6200B250n-Propylbenzene 180 120 4/8/23 10:29 MFFg/L38 4/7/23SM21-23 6200B250Styrene ND 120 4/8/23 10:29 MFFg/L34 4/7/23SM21-23 6200B2501,1,2,2-Tetrachloroethane ND 120 4/8/23 10:29 MFFg/L42 4/7/23SM21-23 6200B250Tetrachloroethylene 16000 120 4/8/23 10:29 MFFg/L56 4/7/23SM21-23 6200B250Toluene ND 250 4/8/23 10:29 MFFg/L86 4/7/23SM21-23 6200B250L-041,2,3-Trichlorobenzene ND 250 4/8/23 10:29 MFFg/L75 4/7/23SM21-23 6200B2501,2,4-Trichlorobenzene ND 120 4/8/23 10:29 MFFg/L37 4/7/23SM21-23 6200B2501,1,1-Trichloroethane ND 120 4/8/23 10:29 MFFg/L48 4/7/23SM21-23 6200B2501,1,2-Trichloroethane ND 120 4/8/23 10:29 MFFg/L44 4/7/23SM21-23 6200B250Trichloroethylene ND 120 4/8/23 10:29 MFFg/L39 4/7/23SM21-23 6200B250Trichlorofluoromethane (Freon 11) ND 120 4/8/23 10:29 MFFg/L69 4/7/23SM21-23 6200B250R-051,2,3-Trichloropropane 2400 120 4/8/23 10:29 MFFg/L50 4/7/23SM21-23 6200B2501,2,4-Trimethylbenzene 610 120 4/8/23 10:29 MFFg/L37 4/7/23SM21-23 6200B2501,3,5-Trimethylbenzene ND 5000 4/8/23 10:29 MFFg/L420 4/7/23SM21-23 6200B250Vinyl Acetate ND 120 4/8/23 10:29 MFFg/L59 4/7/23SM21-23 6200B250Vinyl Chloride 9000 250 4/8/23 10:29 MFFg/L120 4/7/23SM21-23 6200B250m+p Xylene 3800 120 4/8/23 10:29 MFFg/L61 4/7/23SM21-23 6200B250o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 98.9 4/8/23 10:2970-130 Toluene-d8 98.7 4/8/23 10:2970-130 4-Bromofluorobenzene 97.7 4/8/23 10:2970-130 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 4/4/2023 Work Order: 23D0148Sample Description:Project Location: Elm City, NY Sample ID: 23D0148-05 Field Sample #: MW-5 Sample Matrix: Ground Water Sampled: 4/3/2023 13:25 [TOC_2]23D0148-05[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Sample Flags: RL-11 Volatile Organic Compounds by GC/MS ND 12000 4/8/23 10:57 MFFg/L500 4/7/23SM21-23 6200B250Acetone 2100 120 4/8/23 10:57 MFFg/L46 4/7/23SM21-23 6200B250Benzene ND 120 4/8/23 10:57 MFFg/L37 4/7/23SM21-23 6200B250Bromobenzene ND 120 4/8/23 10:57 MFFg/L71 4/7/23SM21-23 6200B250Bromochloromethane ND 120 4/8/23 10:57 MFFg/L39 4/7/23SM21-23 6200B250Bromodichloromethane ND 120 4/8/23 10:57 MFFg/L100 4/7/23SM21-23 6200B250Bromoform ND 500 4/8/23 10:57 MFFg/L330 4/7/23SM21-23 6200B250Bromomethane ND 1200 4/8/23 10:57 MFFg/L420 4/7/23SM21-23 6200B2502-Butanone (MEK) ND 120 4/8/23 10:57 MFFg/L37 4/7/23SM21-23 6200B250n-Butylbenzene ND 120 4/8/23 10:57 MFFg/L32 4/7/23SM21-23 6200B250sec-Butylbenzene ND 120 4/8/23 10:57 MFFg/L35 4/7/23SM21-23 6200B250tert-Butylbenzene ND 120 4/8/23 10:57 MFFg/L41 4/7/23SM21-23 6200B250Carbon Tetrachloride ND 120 4/8/23 10:57 MFFg/L30 4/7/23SM21-23 6200B250Chlorobenzene ND 12000 4/8/23 10:57 MFFg/L5100 4/7/23SM21-23 6200B250Ethanol ND 120 4/8/23 10:57 MFFg/L50 4/7/23SM21-23 6200B250Chlorodibromomethane ND 120 4/8/23 10:57 MFFg/L86 4/7/23SM21-23 6200B250Chloroethane ND 120 4/8/23 10:57 MFFg/L35 4/7/23SM21-23 6200B250Chloroform ND 150 4/8/23 10:57 MFFg/L130 4/7/23SM21-23 6200B250Chloromethane ND 120 4/8/23 10:57 MFFg/L39 4/7/23SM21-23 6200B2502-Chlorotoluene ND 120 4/8/23 10:57 MFFg/L38 4/7/23SM21-23 6200B2504-Chlorotoluene ND 120 4/8/23 10:57 MFFg/L40 4/7/23SM21-23 6200B2501,2-Dibromoethane (EDB) ND 120 4/8/23 10:57 MFFg/L32 4/7/23SM21-23 6200B2501,2-Dichlorobenzene ND 120 4/8/23 10:57 MFFg/L34 4/7/23SM21-23 6200B2501,3-Dichlorobenzene ND 120 4/8/23 10:57 MFFg/L32 4/7/23SM21-23 6200B2501,4-Dichlorobenzene ND 120 4/8/23 10:57 MFFg/L40 4/7/23SM21-23 6200B250Dichlorodifluoromethane (Freon 12) ND 120 4/8/23 10:57 MFFg/L34 4/7/23SM21-23 6200B2501,1-Dichloroethane ND 120 4/8/23 10:57 MFFg/L76 4/7/23SM21-23 6200B2501,2-Dichloroethane ND 120 4/8/23 10:57 MFFg/L35 4/7/23SM21-23 6200B2501,1-Dichloroethylene ND 120 4/8/23 10:57 MFFg/L35 4/7/23SM21-23 6200B250cis-1,2-Dichloroethylene ND 120 4/8/23 10:57 MFFg/L43 4/7/23SM21-23 6200B250R-05trans-1,2-Dichloroethylene ND 120 4/8/23 10:57 MFFg/L48 4/7/23SM21-23 6200B2501,2-Dichloropropane ND 120 4/8/23 10:57 MFFg/L29 4/7/23SM21-23 6200B2501,3-Dichloropropane ND 120 4/8/23 10:57 MFFg/L87 4/7/23SM21-23 6200B2502,2-Dichloropropane ND 120 4/8/23 10:57 MFFg/L37 4/7/23SM21-23 6200B2501,1-Dichloropropene ND 120 4/8/23 10:57 MFFg/L41 4/7/23SM21-23 6200B250cis-1,3-Dichloropropene ND 120 4/8/23 10:57 MFFg/L35 4/7/23SM21-23 6200B250trans-1,3-Dichloropropene ND 120 4/8/23 10:57 MFFg/L50 4/7/23SM21-23 6200B250Diisopropyl Ether (DIPE) 3000 120 4/8/23 10:57 MFFg/L55 4/7/23SM21-23 6200B250Ethylbenzene ND 1200 4/8/23 10:57 MFFg/L300 4/7/23SM21-23 6200B2502-Hexanone (MBK) 110 120 4/8/23 10:57 MFFg/L38 4/7/23SM21-23 6200B250JIsopropylbenzene (Cumene) ND 120 4/8/23 10:57 MFFg/L32 4/7/23SM21-23 6200B250p-Isopropyltoluene (p-Cymene) ND 120 4/8/23 10:57 MFFg/L43 4/7/23SM21-23 6200B250R-05Methyl tert-Butyl Ether (MTBE) ND 1200 4/8/23 10:57 MFFg/L44 4/7/23SM21-23 6200B250Methylene Chloride ND 1200 4/8/23 10:57 MFFg/L330 4/7/23SM21-23 6200B2504-Methyl-2-pentanone (MIBK) 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 4/4/2023 Work Order: 23D0148Sample Description:Project Location: Elm City, NY Sample ID: 23D0148-05 Field Sample #: MW-5 Sample Matrix: Ground Water Sampled: 4/3/2023 13:25 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Sample Flags: RL-11 Volatile Organic Compounds by GC/MS 300 120 4/8/23 10:57 MFFg/L95 4/7/23SM21-23 6200B250L-04Naphthalene 280 120 4/8/23 10:57 MFFg/L31 4/7/23SM21-23 6200B250n-Propylbenzene ND 120 4/8/23 10:57 MFFg/L38 4/7/23SM21-23 6200B250Styrene ND 120 4/8/23 10:57 MFFg/L34 4/7/23SM21-23 6200B2501,1,2,2-Tetrachloroethane ND 120 4/8/23 10:57 MFFg/L42 4/7/23SM21-23 6200B250Tetrachloroethylene 19000 120 4/8/23 10:57 MFFg/L56 4/7/23SM21-23 6200B250Toluene ND 250 4/8/23 10:57 MFFg/L86 4/7/23SM21-23 6200B250L-041,2,3-Trichlorobenzene ND 250 4/8/23 10:57 MFFg/L75 4/7/23SM21-23 6200B2501,2,4-Trichlorobenzene ND 120 4/8/23 10:57 MFFg/L37 4/7/23SM21-23 6200B2501,1,1-Trichloroethane ND 120 4/8/23 10:57 MFFg/L48 4/7/23SM21-23 6200B2501,1,2-Trichloroethane ND 120 4/8/23 10:57 MFFg/L44 4/7/23SM21-23 6200B250Trichloroethylene ND 120 4/8/23 10:57 MFFg/L39 4/7/23SM21-23 6200B250Trichlorofluoromethane (Freon 11) ND 120 4/8/23 10:57 MFFg/L69 4/7/23SM21-23 6200B250R-051,2,3-Trichloropropane 2000 120 4/8/23 10:57 MFFg/L50 4/7/23SM21-23 6200B2501,2,4-Trimethylbenzene 420 120 4/8/23 10:57 MFFg/L37 4/7/23SM21-23 6200B2501,3,5-Trimethylbenzene ND 5000 4/8/23 10:57 MFFg/L420 4/7/23SM21-23 6200B250Vinyl Acetate ND 120 4/8/23 10:57 MFFg/L59 4/7/23SM21-23 6200B250Vinyl Chloride 9700 250 4/8/23 10:57 MFFg/L120 4/7/23SM21-23 6200B250m+p Xylene 4700 120 4/8/23 10:57 MFFg/L61 4/7/23SM21-23 6200B250o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 97.4 4/8/23 10:5770-130 Toluene-d8 98.8 4/8/23 10:5770-130 4-Bromofluorobenzene 94.0 4/8/23 10:5770-130 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 4/4/2023 Work Order: 23D0148Sample Description:Project Location: Elm City, NY Sample ID: 23D0148-06 Field Sample #: EB Sample Matrix: Ground Water Sampled: 4/3/2023 13:39 [TOC_2]23D0148-06[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS 9.0 50 4/8/23 4:34 MFFg/L2.0 4/7/23SM21-23 6200B1JAcetone ND 0.50 4/8/23 4:34 MFFg/L0.18 4/7/23SM21-23 6200B1Benzene ND 0.50 4/8/23 4:34 MFFg/L0.15 4/7/23SM21-23 6200B1Bromobenzene ND 0.50 4/8/23 4:34 MFFg/L0.28 4/7/23SM21-23 6200B1Bromochloromethane ND 0.50 4/8/23 4:34 MFFg/L0.16 4/7/23SM21-23 6200B1Bromodichloromethane ND 0.50 4/8/23 4:34 MFFg/L0.41 4/7/23SM21-23 6200B1Bromoform ND 2.0 4/8/23 4:34 MFFg/L1.3 4/7/23SM21-23 6200B1Bromomethane ND 5.0 4/8/23 4:34 MFFg/L1.7 4/7/23SM21-23 6200B12-Butanone (MEK) ND 0.50 4/8/23 4:34 MFFg/L0.15 4/7/23SM21-23 6200B1n-Butylbenzene ND 0.50 4/8/23 4:34 MFFg/L0.13 4/7/23SM21-23 6200B1sec-Butylbenzene ND 0.50 4/8/23 4:34 MFFg/L0.14 4/7/23SM21-23 6200B1tert-Butylbenzene ND 0.50 4/8/23 4:34 MFFg/L0.16 4/7/23SM21-23 6200B1Carbon Tetrachloride ND 0.50 4/8/23 4:34 MFFg/L0.12 4/7/23SM21-23 6200B1Chlorobenzene ND 50 4/8/23 4:34 MFFg/L20 4/7/23SM21-23 6200B1Ethanol ND 0.50 4/8/23 4:34 MFFg/L0.20 4/7/23SM21-23 6200B1Chlorodibromomethane ND 0.50 4/8/23 4:34 MFFg/L0.34 4/7/23SM21-23 6200B1Chloroethane ND 0.50 4/8/23 4:34 MFFg/L0.14 4/7/23SM21-23 6200B1Chloroform ND 0.60 4/8/23 4:34 MFFg/L0.50 4/7/23SM21-23 6200B1Chloromethane ND 0.50 4/8/23 4:34 MFFg/L0.15 4/7/23SM21-23 6200B12-Chlorotoluene ND 0.50 4/8/23 4:34 MFFg/L0.15 4/7/23SM21-23 6200B14-Chlorotoluene ND 0.50 4/8/23 4:34 MFFg/L0.16 4/7/23SM21-23 6200B11,2-Dibromoethane (EDB) ND 0.50 4/8/23 4:34 MFFg/L0.13 4/7/23SM21-23 6200B11,2-Dichlorobenzene ND 0.50 4/8/23 4:34 MFFg/L0.14 4/7/23SM21-23 6200B11,3-Dichlorobenzene ND 0.50 4/8/23 4:34 MFFg/L0.13 4/7/23SM21-23 6200B11,4-Dichlorobenzene ND 0.50 4/8/23 4:34 MFFg/L0.16 4/7/23SM21-23 6200B1Dichlorodifluoromethane (Freon 12) ND 0.50 4/8/23 4:34 MFFg/L0.14 4/7/23SM21-23 6200B11,1-Dichloroethane ND 0.50 4/8/23 4:34 MFFg/L0.30 4/7/23SM21-23 6200B11,2-Dichloroethane ND 0.50 4/8/23 4:34 MFFg/L0.14 4/7/23SM21-23 6200B11,1-Dichloroethylene ND 0.50 4/8/23 4:34 MFFg/L0.14 4/7/23SM21-23 6200B1cis-1,2-Dichloroethylene ND 0.50 4/8/23 4:34 MFFg/L0.17 4/7/23SM21-23 6200B1R-05trans-1,2-Dichloroethylene ND 0.50 4/8/23 4:34 MFFg/L0.19 4/7/23SM21-23 6200B11,2-Dichloropropane ND 0.50 4/8/23 4:34 MFFg/L0.12 4/7/23SM21-23 6200B11,3-Dichloropropane ND 0.50 4/8/23 4:34 MFFg/L0.35 4/7/23SM21-23 6200B12,2-Dichloropropane ND 0.50 4/8/23 4:34 MFFg/L0.15 4/7/23SM21-23 6200B11,1-Dichloropropene ND 0.50 4/8/23 4:34 MFFg/L0.16 4/7/23SM21-23 6200B1cis-1,3-Dichloropropene ND 0.50 4/8/23 4:34 MFFg/L0.14 4/7/23SM21-23 6200B1trans-1,3-Dichloropropene ND 0.50 4/8/23 4:34 MFFg/L0.20 4/7/23SM21-23 6200B1Diisopropyl Ether (DIPE) ND 0.50 4/8/23 4:34 MFFg/L0.22 4/7/23SM21-23 6200B1Ethylbenzene ND 5.0 4/8/23 4:34 MFFg/L1.2 4/7/23SM21-23 6200B12-Hexanone (MBK) ND 0.50 4/8/23 4:34 MFFg/L0.15 4/7/23SM21-23 6200B1Isopropylbenzene (Cumene) ND 0.50 4/8/23 4:34 MFFg/L0.13 4/7/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene) ND 0.50 4/8/23 4:34 MFFg/L0.17 4/7/23SM21-23 6200B1R-05Methyl tert-Butyl Ether (MTBE) ND 5.0 4/8/23 4:34 MFFg/L0.18 4/7/23SM21-23 6200B1Methylene Chloride ND 5.0 4/8/23 4:34 MFFg/L1.3 4/7/23SM21-23 6200B14-Methyl-2-pentanone (MIBK) 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 4/4/2023 Work Order: 23D0148Sample Description:Project Location: Elm City, NY Sample ID: 23D0148-06 Field Sample #: EB Sample Matrix: Ground Water Sampled: 4/3/2023 13:39 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 0.50 4/8/23 4:34 MFFg/L0.38 4/7/23SM21-23 6200B1L-04Naphthalene ND 0.50 4/8/23 4:34 MFFg/L0.12 4/7/23SM21-23 6200B1n-Propylbenzene ND 0.50 4/8/23 4:34 MFFg/L0.15 4/7/23SM21-23 6200B1Styrene ND 0.50 4/8/23 4:34 MFFg/L0.14 4/7/23SM21-23 6200B11,1,2,2-Tetrachloroethane ND 0.50 4/8/23 4:34 MFFg/L0.17 4/7/23SM21-23 6200B1Tetrachloroethylene ND 0.50 4/8/23 4:34 MFFg/L0.22 4/7/23SM21-23 6200B1Toluene ND 1.0 4/8/23 4:34 MFFg/L0.34 4/7/23SM21-23 6200B1L-041,2,3-Trichlorobenzene ND 1.0 4/8/23 4:34 MFFg/L0.30 4/7/23SM21-23 6200B11,2,4-Trichlorobenzene ND 0.50 4/8/23 4:34 MFFg/L0.15 4/7/23SM21-23 6200B11,1,1-Trichloroethane ND 0.50 4/8/23 4:34 MFFg/L0.19 4/7/23SM21-23 6200B11,1,2-Trichloroethane ND 0.50 4/8/23 4:34 MFFg/L0.17 4/7/23SM21-23 6200B1Trichloroethylene ND 0.50 4/8/23 4:34 MFFg/L0.15 4/7/23SM21-23 6200B1Trichlorofluoromethane (Freon 11) ND 0.50 4/8/23 4:34 MFFg/L0.28 4/7/23SM21-23 6200B1R-051,2,3-Trichloropropane ND 0.50 4/8/23 4:34 MFFg/L0.20 4/7/23SM21-23 6200B11,2,4-Trimethylbenzene ND 0.50 4/8/23 4:34 MFFg/L0.15 4/7/23SM21-23 6200B11,3,5-Trimethylbenzene ND 20 4/8/23 4:34 MFFg/L1.7 4/7/23SM21-23 6200B1Vinyl Acetate ND 0.50 4/8/23 4:34 MFFg/L0.24 4/7/23SM21-23 6200B1Vinyl Chloride ND 1.0 4/8/23 4:34 MFFg/L0.49 4/7/23SM21-23 6200B1m+p Xylene ND 0.50 4/8/23 4:34 MFFg/L0.24 4/7/23SM21-23 6200B1o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 102 4/8/23 4:3470-130 Toluene-d8 98.6 4/8/23 4:3470-130 4-Bromofluorobenzene 96.4 4/8/23 4:3470-130 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 4/4/2023 Work Order: 23D0148Sample Description:Project Location: Elm City, NY Sample ID: 23D0148-07 Field Sample #: TB Sample Matrix: Ground Water Sampled: 4/3/2023 00:00 [TOC_2]23D0148-07[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS 8.8 50 4/8/23 5:02 MFFg/L2.0 4/7/23SM21-23 6200B1JAcetone ND 0.50 4/8/23 5:02 MFFg/L0.18 4/7/23SM21-23 6200B1Benzene ND 0.50 4/8/23 5:02 MFFg/L0.15 4/7/23SM21-23 6200B1Bromobenzene ND 0.50 4/8/23 5:02 MFFg/L0.28 4/7/23SM21-23 6200B1Bromochloromethane ND 0.50 4/8/23 5:02 MFFg/L0.16 4/7/23SM21-23 6200B1Bromodichloromethane ND 0.50 4/8/23 5:02 MFFg/L0.41 4/7/23SM21-23 6200B1Bromoform ND 2.0 4/8/23 5:02 MFFg/L1.3 4/7/23SM21-23 6200B1Bromomethane ND 5.0 4/8/23 5:02 MFFg/L1.7 4/7/23SM21-23 6200B12-Butanone (MEK) ND 0.50 4/8/23 5:02 MFFg/L0.15 4/7/23SM21-23 6200B1n-Butylbenzene ND 0.50 4/8/23 5:02 MFFg/L0.13 4/7/23SM21-23 6200B1sec-Butylbenzene ND 0.50 4/8/23 5:02 MFFg/L0.14 4/7/23SM21-23 6200B1tert-Butylbenzene ND 0.50 4/8/23 5:02 MFFg/L0.16 4/7/23SM21-23 6200B1Carbon Tetrachloride ND 0.50 4/8/23 5:02 MFFg/L0.12 4/7/23SM21-23 6200B1Chlorobenzene ND 50 4/8/23 5:02 MFFg/L20 4/7/23SM21-23 6200B1Ethanol ND 0.50 4/8/23 5:02 MFFg/L0.20 4/7/23SM21-23 6200B1Chlorodibromomethane ND 0.50 4/8/23 5:02 MFFg/L0.34 4/7/23SM21-23 6200B1Chloroethane ND 0.50 4/8/23 5:02 MFFg/L0.14 4/7/23SM21-23 6200B1Chloroform ND 0.60 4/8/23 5:02 MFFg/L0.50 4/7/23SM21-23 6200B1Chloromethane ND 0.50 4/8/23 5:02 MFFg/L0.15 4/7/23SM21-23 6200B12-Chlorotoluene ND 0.50 4/8/23 5:02 MFFg/L0.15 4/7/23SM21-23 6200B14-Chlorotoluene ND 0.50 4/8/23 5:02 MFFg/L0.16 4/7/23SM21-23 6200B11,2-Dibromoethane (EDB) ND 0.50 4/8/23 5:02 MFFg/L0.13 4/7/23SM21-23 6200B11,2-Dichlorobenzene ND 0.50 4/8/23 5:02 MFFg/L0.14 4/7/23SM21-23 6200B11,3-Dichlorobenzene ND 0.50 4/8/23 5:02 MFFg/L0.13 4/7/23SM21-23 6200B11,4-Dichlorobenzene ND 0.50 4/8/23 5:02 MFFg/L0.16 4/7/23SM21-23 6200B1Dichlorodifluoromethane (Freon 12) ND 0.50 4/8/23 5:02 MFFg/L0.14 4/7/23SM21-23 6200B11,1-Dichloroethane ND 0.50 4/8/23 5:02 MFFg/L0.30 4/7/23SM21-23 6200B11,2-Dichloroethane ND 0.50 4/8/23 5:02 MFFg/L0.14 4/7/23SM21-23 6200B11,1-Dichloroethylene ND 0.50 4/8/23 5:02 MFFg/L0.14 4/7/23SM21-23 6200B1cis-1,2-Dichloroethylene ND 0.50 4/8/23 5:02 MFFg/L0.17 4/7/23SM21-23 6200B1R-05trans-1,2-Dichloroethylene ND 0.50 4/8/23 5:02 MFFg/L0.19 4/7/23SM21-23 6200B11,2-Dichloropropane ND 0.50 4/8/23 5:02 MFFg/L0.12 4/7/23SM21-23 6200B11,3-Dichloropropane ND 0.50 4/8/23 5:02 MFFg/L0.35 4/7/23SM21-23 6200B12,2-Dichloropropane ND 0.50 4/8/23 5:02 MFFg/L0.15 4/7/23SM21-23 6200B11,1-Dichloropropene ND 0.50 4/8/23 5:02 MFFg/L0.16 4/7/23SM21-23 6200B1cis-1,3-Dichloropropene ND 0.50 4/8/23 5:02 MFFg/L0.14 4/7/23SM21-23 6200B1trans-1,3-Dichloropropene ND 0.50 4/8/23 5:02 MFFg/L0.20 4/7/23SM21-23 6200B1Diisopropyl Ether (DIPE) ND 0.50 4/8/23 5:02 MFFg/L0.22 4/7/23SM21-23 6200B1Ethylbenzene ND 5.0 4/8/23 5:02 MFFg/L1.2 4/7/23SM21-23 6200B12-Hexanone (MBK) ND 0.50 4/8/23 5:02 MFFg/L0.15 4/7/23SM21-23 6200B1Isopropylbenzene (Cumene) ND 0.50 4/8/23 5:02 MFFg/L0.13 4/7/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene) ND 0.50 4/8/23 5:02 MFFg/L0.17 4/7/23SM21-23 6200B1R-05Methyl tert-Butyl Ether (MTBE) ND 5.0 4/8/23 5:02 MFFg/L0.18 4/7/23SM21-23 6200B1Methylene Chloride ND 5.0 4/8/23 5:02 MFFg/L1.3 4/7/23SM21-23 6200B14-Methyl-2-pentanone (MIBK) 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 4/4/2023 Work Order: 23D0148Sample Description:Project Location: Elm City, NY Sample ID: 23D0148-07 Field Sample #: TB Sample Matrix: Ground Water Sampled: 4/3/2023 00:00 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 0.50 4/8/23 5:02 MFFg/L0.38 4/7/23SM21-23 6200B1L-04Naphthalene ND 0.50 4/8/23 5:02 MFFg/L0.12 4/7/23SM21-23 6200B1n-Propylbenzene ND 0.50 4/8/23 5:02 MFFg/L0.15 4/7/23SM21-23 6200B1Styrene ND 0.50 4/8/23 5:02 MFFg/L0.14 4/7/23SM21-23 6200B11,1,2,2-Tetrachloroethane ND 0.50 4/8/23 5:02 MFFg/L0.17 4/7/23SM21-23 6200B1Tetrachloroethylene ND 0.50 4/8/23 5:02 MFFg/L0.22 4/7/23SM21-23 6200B1Toluene ND 1.0 4/8/23 5:02 MFFg/L0.34 4/7/23SM21-23 6200B1L-041,2,3-Trichlorobenzene ND 1.0 4/8/23 5:02 MFFg/L0.30 4/7/23SM21-23 6200B11,2,4-Trichlorobenzene ND 0.50 4/8/23 5:02 MFFg/L0.15 4/7/23SM21-23 6200B11,1,1-Trichloroethane ND 0.50 4/8/23 5:02 MFFg/L0.19 4/7/23SM21-23 6200B11,1,2-Trichloroethane ND 0.50 4/8/23 5:02 MFFg/L0.17 4/7/23SM21-23 6200B1Trichloroethylene ND 0.50 4/8/23 5:02 MFFg/L0.15 4/7/23SM21-23 6200B1Trichlorofluoromethane (Freon 11) ND 0.50 4/8/23 5:02 MFFg/L0.28 4/7/23SM21-23 6200B1R-051,2,3-Trichloropropane ND 0.50 4/8/23 5:02 MFFg/L0.20 4/7/23SM21-23 6200B11,2,4-Trimethylbenzene ND 0.50 4/8/23 5:02 MFFg/L0.15 4/7/23SM21-23 6200B11,3,5-Trimethylbenzene ND 20 4/8/23 5:02 MFFg/L1.7 4/7/23SM21-23 6200B1Vinyl Acetate ND 0.50 4/8/23 5:02 MFFg/L0.24 4/7/23SM21-23 6200B1Vinyl Chloride ND 1.0 4/8/23 5:02 MFFg/L0.49 4/7/23SM21-23 6200B1m+p Xylene ND 0.50 4/8/23 5:02 MFFg/L0.24 4/7/23SM21-23 6200B1o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 99.9 4/8/23 5:0270-130 Toluene-d8 97.9 4/8/23 5:0270-130 4-Bromofluorobenzene 92.1 4/8/23 5:0270-130 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Sample Extraction Data Prep Method: SW-846 5030B-SM21-23 6200B Lab Number [Field ID]Batch DateInitial [mL]Final [mL] B336483 04/07/235 5.0023D0148-02 [MW-2] B336483 04/07/235 5.0023D0148-03 [MW-3] B336483 04/07/230.02 5.0023D0148-04 [MW-4] B336483 04/07/230.02 5.0023D0148-05 [MW-5] B336483 04/07/235 5.0023D0148-06 [EB] B336483 04/07/235 5.0023D0148-07 [TB] Prep Method: SW-846 5030B-SM21-23 6200B Lab Number [Field ID]Batch DateInitial [mL]Final [mL] B336621 04/07/230.125 5.0023D0148-01 [MW-1] [TOC_1]Sample Preparation Information[TOC] 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL [TOC_2]Volatile Organic Compounds by GC/MS[TOC] Batch B336483 - SW-846 5030B [TOC_3]B336483[TOC] Blank (B336483-BLK1) Prepared: 04/07/23 Analyzed: 04/08/23 Acetone g/L50ND Benzene g/L0.50ND Bromobenzene g/L0.50ND Bromochloromethane g/L0.50ND Bromodichloromethane g/L0.50ND Bromoform g/L0.50ND Bromomethane g/L2.0ND 2-Butanone (MEK)g/L5.0ND n-Butylbenzene g/L0.50ND sec-Butylbenzene g/L0.50ND tert-Butylbenzene g/L0.50ND Carbon Tetrachloride g/L0.50ND Chlorobenzene g/L0.50ND Ethanol g/L50ND Chlorodibromomethane g/L0.50ND Chloroethane g/L0.50ND Chloroform g/L0.50ND Chloromethane g/L0.60ND 2-Chlorotoluene g/L0.50ND 4-Chlorotoluene g/L0.50ND 1,2-Dibromoethane (EDB)g/L0.50ND 1,2-Dichlorobenzene g/L0.50ND 1,3-Dichlorobenzene g/L0.50ND 1,4-Dichlorobenzene g/L0.50ND Dichlorodifluoromethane (Freon 12)g/L0.50ND 1,1-Dichloroethane g/L0.50ND 1,2-Dichloroethane g/L0.50ND 1,1-Dichloroethylene g/L0.50ND cis-1,2-Dichloroethylene g/L0.50ND trans-1,2-Dichloroethylene g/L0.50 R-05ND 1,2-Dichloropropane g/L0.50ND 1,3-Dichloropropane g/L0.50ND 2,2-Dichloropropane g/L0.50ND 1,1-Dichloropropene g/L0.50ND cis-1,3-Dichloropropene g/L0.50ND trans-1,3-Dichloropropene g/L0.50ND Diisopropyl Ether (DIPE)g/L0.50ND Ethylbenzene g/L0.50ND 2-Hexanone (MBK)g/L5.0ND Isopropylbenzene (Cumene)g/L0.50ND p-Isopropyltoluene (p-Cymene)g/L0.50ND Methyl tert-Butyl Ether (MTBE)g/L0.50 R-05ND Methylene Chloride g/L5.0ND 4-Methyl-2-pentanone (MIBK)g/L5.0ND Naphthalene g/L0.50 L-04ND n-Propylbenzene g/L0.50ND Styrene g/L0.50ND 1,1,2,2-Tetrachloroethane g/L0.50ND Tetrachloroethylene g/L0.50ND Toluene g/L0.50ND 1,2,3-Trichlorobenzene g/L1.0 L-04ND 1,2,4-Trichlorobenzene g/L0.50ND [TOC_1]QC Data[TOC] 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL Batch B336483 - SW-846 5030B Blank (B336483-BLK1) Prepared: 04/07/23 Analyzed: 04/08/23 1,1,1-Trichloroethane g/L0.50ND 1,1,2-Trichloroethane g/L0.50ND Trichloroethylene g/L0.50ND Trichlorofluoromethane (Freon 11)g/L0.50ND 1,2,3-Trichloropropane g/L0.50 R-05ND 1,2,4-Trimethylbenzene g/L0.50ND 1,3,5-Trimethylbenzene g/L0.50ND Vinyl Acetate g/L20ND Vinyl Chloride g/L0.50ND m+p Xylene g/L1.0ND o-Xylene g/L0.50ND g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 10325.8 g/L 25.0 70-130Surrogate: Toluene-d8 97.624.4 g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 93.623.4 LCS (B336483-BS1) Prepared: 04/07/23 Analyzed: 04/08/23 Acetone g/L50 100 70-130124124 Benzene g/L0.50 10.0 70-13095.59.55 Bromobenzene g/L0.50 10.0 70-13093.39.33 Bromochloromethane g/L0.50 10.0 70-13010610.6 Bromodichloromethane g/L0.50 10.0 70-13094.69.46 Bromoform g/L0.50 10.0 70-13088.98.89 Bromomethane g/L2.0 10.0 60-14011811.8 2-Butanone (MEK)g/L5.0 100 70-130104104 n-Butylbenzene g/L0.50 10.0 70-13088.28.82 sec-Butylbenzene g/L0.50 10.0 70-13089.78.97 tert-Butylbenzene g/L0.50 10.0 70-13093.39.33 Carbon Tetrachloride g/L0.50 10.0 70-13095.99.59 Chlorobenzene g/L0.50 10.0 70-13098.99.89 Ethanol g/L50 100 70-130112112 Chlorodibromomethane g/L0.50 10.0 70-13091.39.13 Chloroethane g/L0.50 10.0 60-14087.38.73 Chloroform g/L0.50 10.0 70-13092.89.28 Chloromethane g/L0.60 10.0 60-14074.57.45 2-Chlorotoluene g/L0.50 10.0 70-13093.39.33 4-Chlorotoluene g/L0.50 10.0 70-13095.49.54 1,2-Dibromoethane (EDB)g/L0.50 10.0 70-13098.79.87 1,2-Dichlorobenzene g/L0.50 10.0 70-13096.19.61 1,3-Dichlorobenzene g/L0.50 10.0 70-13096.39.63 1,4-Dichlorobenzene g/L0.50 10.0 70-13099.99.99 Dichlorodifluoromethane (Freon 12)g/L0.50 10.0 60-14010510.5 1,1-Dichloroethane g/L0.50 10.0 70-13089.98.99 1,2-Dichloroethane g/L0.50 10.0 70-13010210.2 1,1-Dichloroethylene g/L0.50 10.0 70-13011311.3 cis-1,2-Dichloroethylene g/L0.50 10.0 70-13092.19.21 trans-1,2-Dichloroethylene g/L0.50 10.0 R-0570-13011511.5 1,2-Dichloropropane g/L0.50 10.0 70-13095.69.56 1,3-Dichloropropane g/L0.50 10.0 70-13094.59.45 2,2-Dichloropropane g/L0.50 10.0 70-13076.07.60 1,1-Dichloropropene g/L0.50 10.0 70-13094.49.44 cis-1,3-Dichloropropene g/L0.50 10.0 70-13089.88.98 trans-1,3-Dichloropropene g/L0.50 10.0 70-13090.59.05 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL Batch B336483 - SW-846 5030B LCS (B336483-BS1) Prepared: 04/07/23 Analyzed: 04/08/23 Diisopropyl Ether (DIPE)g/L0.50 10.0 70-13010310.3 Ethylbenzene g/L0.50 10.0 70-13095.39.53 2-Hexanone (MBK)g/L5.0 100 70-13081.281.2 Isopropylbenzene (Cumene)g/L0.50 10.0 70-13092.69.26 p-Isopropyltoluene (p-Cymene)g/L0.50 10.0 70-13089.48.94 Methyl tert-Butyl Ether (MTBE)g/L0.50 10.0 R-0570-13012312.3 Methylene Chloride g/L5.0 10.0 70-13011811.8 4-Methyl-2-pentanone (MIBK)g/L5.0 100 70-13090.090.0 Naphthalene g/L0.50 10.0 L-0470-13051.3 *5.13 n-Propylbenzene g/L0.50 10.0 70-13094.79.47 Styrene g/L0.50 10.0 70-13097.79.77 1,1,2,2-Tetrachloroethane g/L0.50 10.0 70-13094.69.46 Tetrachloroethylene g/L0.50 10.0 70-13095.99.59 Toluene g/L0.50 10.0 70-13092.79.27 1,2,3-Trichlorobenzene g/L1.0 10.0 L-0470-13061.9 *6.19 1,2,4-Trichlorobenzene g/L0.50 10.0 70-13074.07.40 1,1,1-Trichloroethane g/L0.50 10.0 70-13093.79.37 1,1,2-Trichloroethane g/L0.50 10.0 70-13098.39.83 Trichloroethylene g/L0.50 10.0 70-13096.99.69 Trichlorofluoromethane (Freon 11)g/L0.50 10.0 70-13011611.6 1,2,3-Trichloropropane g/L0.50 10.0 R-0570-13085.08.50 1,2,4-Trimethylbenzene g/L0.50 10.0 70-13093.89.38 1,3,5-Trimethylbenzene g/L0.50 10.0 70-13092.59.25 Vinyl Acetate g/L20 100 70-13094.694.6 Vinyl Chloride g/L0.50 10.0 60-14096.39.63 m+p Xylene g/L1.0 20.0 70-13095.519.1 o-Xylene g/L0.50 10.0 70-13094.09.40 g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 10225.5 g/L 25.0 70-130Surrogate: Toluene-d8 10025.0 g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 93.623.4 LCS Dup (B336483-BSD1) Prepared: 04/07/23 Analyzed: 04/08/23 Acetone g/L50 100 25 L-0770-130137 10.1*137 Benzene g/L0.50 10.0 2570-13091.3 4.509.13 Bromobenzene g/L0.50 10.0 2570-13094.0 0.7479.40 Bromochloromethane g/L0.50 10.0 2570-130101 5.2310.1 Bromodichloromethane g/L0.50 10.0 2570-13098.7 4.249.87 Bromoform g/L0.50 10.0 2570-13091.2 2.559.12 Bromomethane g/L2.0 10.0 2560-140127 7.0212.7 2-Butanone (MEK)g/L5.0 100 2570-130103 1.76103 n-Butylbenzene g/L0.50 10.0 2570-13085.3 3.348.53 sec-Butylbenzene g/L0.50 10.0 2570-13089.5 0.2238.95 tert-Butylbenzene g/L0.50 10.0 2570-13091.3 2.179.13 Carbon Tetrachloride g/L0.50 10.0 2570-13094.3 1.689.43 Chlorobenzene g/L0.50 10.0 2570-13095.2 3.819.52 Ethanol g/L50 100 2570-13097.7 13.797.7 Chlorodibromomethane g/L0.50 10.0 2570-13089.2 2.338.92 Chloroethane g/L0.50 10.0 2560-14094.3 7.719.43 Chloroform g/L0.50 10.0 2570-13091.4 1.529.14 Chloromethane g/L0.60 10.0 2560-14072.5 2.727.25 2-Chlorotoluene g/L0.50 10.0 2570-13091.2 2.289.12 4-Chlorotoluene g/L0.50 10.0 2570-13097.2 1.879.72 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL Batch B336483 - SW-846 5030B LCS Dup (B336483-BSD1) Prepared: 04/07/23 Analyzed: 04/08/23 1,2-Dibromoethane (EDB)g/L0.50 10.0 2570-13097.5 1.229.75 1,2-Dichlorobenzene g/L0.50 10.0 2570-13096.2 0.1049.62 1,3-Dichlorobenzene g/L0.50 10.0 2570-13097.1 0.8279.71 1,4-Dichlorobenzene g/L0.50 10.0 2570-13097.1 2.849.71 Dichlorodifluoromethane (Freon 12)g/L0.50 10.0 2560-140100 4.8610.0 1,1-Dichloroethane g/L0.50 10.0 2570-13087.1 3.168.71 1,2-Dichloroethane g/L0.50 10.0 2570-130101 0.29610.1 1,1-Dichloroethylene g/L0.50 10.0 2570-130125 10.312.5 cis-1,2-Dichloroethylene g/L0.50 10.0 2570-13089.9 2.428.99 trans-1,2-Dichloroethylene g/L0.50 10.0 25 R-0570-13089.3 25.2 *8.93 1,2-Dichloropropane g/L0.50 10.0 2570-13093.4 2.339.34 1,3-Dichloropropane g/L0.50 10.0 2570-13097.3 2.929.73 2,2-Dichloropropane g/L0.50 10.0 2570-13075.0 1.327.50 1,1-Dichloropropene g/L0.50 10.0 2570-13090.0 4.779.00 cis-1,3-Dichloropropene g/L0.50 10.0 2570-13089.9 0.1118.99 trans-1,3-Dichloropropene g/L0.50 10.0 2570-13088.9 1.788.89 Diisopropyl Ether (DIPE)g/L0.50 10.0 2570-130100 3.0510.0 Ethylbenzene g/L0.50 10.0 2570-13093.8 1.599.38 2-Hexanone (MBK)g/L5.0 100 2570-13085.5 5.1285.5 Isopropylbenzene (Cumene)g/L0.50 10.0 2570-13094.2 1.719.42 p-Isopropyltoluene (p-Cymene)g/L0.50 10.0 2570-13093.1 4.059.31 Methyl tert-Butyl Ether (MTBE)g/L0.50 10.0 25 R-0570-13093.4 27.1 *9.34 Methylene Chloride g/L5.0 10.0 2570-130119 1.1011.9 4-Methyl-2-pentanone (MIBK)g/L5.0 100 2570-13091.9 2.0991.9 Naphthalene g/L0.50 10.0 25 L-0470-13047.7 7.27*4.77 n-Propylbenzene g/L0.50 10.0 2570-13095.7 1.059.57 Styrene g/L0.50 10.0 2570-13095.2 2.599.52 1,1,2,2-Tetrachloroethane g/L0.50 10.0 2570-13094.7 0.1069.47 Tetrachloroethylene g/L0.50 10.0 2570-13097.7 1.869.77 Toluene g/L0.50 10.0 2570-13093.8 1.189.38 1,2,3-Trichlorobenzene g/L1.0 10.0 25 L-0470-13059.1 4.63*5.91 1,2,4-Trichlorobenzene g/L0.50 10.0 25 L-0770-13069.3 6.56*6.93 1,1,1-Trichloroethane g/L0.50 10.0 2570-13091.0 2.929.10 1,1,2-Trichloroethane g/L0.50 10.0 2570-13097.7 0.6129.77 Trichloroethylene g/L0.50 10.0 2570-13096.8 0.1039.68 Trichlorofluoromethane (Freon 11)g/L0.50 10.0 2570-130121 4.0412.1 1,2,3-Trichloropropane g/L0.50 10.0 25 R-0570-130121 34.8 *12.1 1,2,4-Trimethylbenzene g/L0.50 10.0 2570-13090.7 3.369.07 1,3,5-Trimethylbenzene g/L0.50 10.0 2570-13095.0 2.679.50 Vinyl Acetate g/L20 100 2570-13094.1 0.48894.1 Vinyl Chloride g/L0.50 10.0 2560-14099.4 3.179.94 m+p Xylene g/L1.0 20.0 2570-13095.8 0.36619.2 o-Xylene g/L0.50 10.0 2570-13092.7 1.399.27 g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 10125.2 g/L 25.0 70-130Surrogate: Toluene-d8 99.624.9 g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 95.023.8 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL Batch B336621 - SW-846 5030B [TOC_3]B336621[TOC] Blank (B336621-BLK1) Prepared: 04/10/23 Analyzed: 04/11/23 Acetone g/L50ND Benzene g/L0.50ND Bromobenzene g/L0.50ND Bromochloromethane g/L0.50ND Bromodichloromethane g/L0.50ND Bromoform g/L0.50ND Bromomethane g/L2.0ND 2-Butanone (MEK)g/L5.0ND n-Butylbenzene g/L0.50ND sec-Butylbenzene g/L0.50ND tert-Butylbenzene g/L0.50ND Carbon Tetrachloride g/L0.50ND Chlorobenzene g/L0.50ND Ethanol g/L50ND Chlorodibromomethane g/L0.50ND Chloroethane g/L0.50ND Chloroform g/L0.50ND Chloromethane g/L0.60ND 2-Chlorotoluene g/L0.50ND 4-Chlorotoluene g/L0.50ND 1,2-Dibromoethane (EDB)g/L0.50ND 1,2-Dichlorobenzene g/L0.50ND 1,3-Dichlorobenzene g/L0.50ND 1,4-Dichlorobenzene g/L0.50ND Dichlorodifluoromethane (Freon 12)g/L0.50ND 1,1-Dichloroethane g/L0.50ND 1,2-Dichloroethane g/L0.50ND 1,1-Dichloroethylene g/L0.50ND cis-1,2-Dichloroethylene g/L0.50ND trans-1,2-Dichloroethylene g/L0.50ND 1,2-Dichloropropane g/L0.50ND 1,3-Dichloropropane g/L0.50ND 2,2-Dichloropropane g/L0.50ND 1,1-Dichloropropene g/L0.50ND cis-1,3-Dichloropropene g/L0.50ND trans-1,3-Dichloropropene g/L0.50ND Diisopropyl Ether (DIPE)g/L0.50ND Ethylbenzene g/L0.50ND 2-Hexanone (MBK)g/L5.0ND Isopropylbenzene (Cumene)g/L0.50ND p-Isopropyltoluene (p-Cymene)g/L0.50ND Methyl tert-Butyl Ether (MTBE)g/L0.50ND Methylene Chloride g/L5.0ND 4-Methyl-2-pentanone (MIBK)g/L5.0ND Naphthalene g/L0.50 L-04ND n-Propylbenzene g/L0.50ND Styrene g/L0.50ND 1,1,2,2-Tetrachloroethane g/L0.50ND Tetrachloroethylene g/L0.50ND Toluene g/L0.50ND 1,2,3-Trichlorobenzene g/L1.0 L-04ND 1,2,4-Trichlorobenzene g/L0.50ND 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL Batch B336621 - SW-846 5030B Blank (B336621-BLK1) Prepared: 04/10/23 Analyzed: 04/11/23 1,1,1-Trichloroethane g/L0.50ND 1,1,2-Trichloroethane g/L0.50ND Trichloroethylene g/L0.50ND Trichlorofluoromethane (Freon 11)g/L0.50ND 1,2,3-Trichloropropane g/L0.50 R-05ND 1,2,4-Trimethylbenzene g/L0.50ND 1,3,5-Trimethylbenzene g/L0.50ND Vinyl Acetate g/L20ND Vinyl Chloride g/L0.50ND m+p Xylene g/L1.0ND o-Xylene g/L0.50ND g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 99.624.9 g/L 25.0 70-130Surrogate: Toluene-d8 97.324.3 g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 95.223.8 LCS (B336621-BS1) Prepared: 04/10/23 Analyzed: 04/11/23 Acetone g/L50 200 70-130114227 Benzene g/L0.50 20.0 70-13010320.6 Bromobenzene g/L0.50 20.0 70-13010320.6 Bromochloromethane g/L0.50 20.0 70-13011523.0 Bromodichloromethane g/L0.50 20.0 70-13010320.7 Bromoform g/L0.50 20.0 70-13010020.0 Bromomethane g/L2.0 20.0 60-14071.014.2 2-Butanone (MEK)g/L5.0 200 70-130104208 n-Butylbenzene g/L0.50 20.0 70-13095.619.1 sec-Butylbenzene g/L0.50 20.0 70-13010521.0 tert-Butylbenzene g/L0.50 20.0 70-13010520.9 Carbon Tetrachloride g/L0.50 20.0 70-13010621.2 Chlorobenzene g/L0.50 20.0 70-13010521.0 Ethanol g/L50 200 70-13097.5195 Chlorodibromomethane g/L0.50 20.0 70-13098.019.6 Chloroethane g/L0.50 20.0 60-14086.017.2 Chloroform g/L0.50 20.0 70-13099.019.8 Chloromethane g/L0.60 20.0 60-14062.812.6 2-Chlorotoluene g/L0.50 20.0 70-13010120.1 4-Chlorotoluene g/L0.50 20.0 70-13010420.9 1,2-Dibromoethane (EDB)g/L0.50 20.0 70-13010320.6 1,2-Dichlorobenzene g/L0.50 20.0 70-13010420.7 1,3-Dichlorobenzene g/L0.50 20.0 70-13010721.4 1,4-Dichlorobenzene g/L0.50 20.0 70-13010120.2 Dichlorodifluoromethane (Freon 12)g/L0.50 20.0 60-14010320.7 1,1-Dichloroethane g/L0.50 20.0 70-13010120.2 1,2-Dichloroethane g/L0.50 20.0 70-13010320.5 1,1-Dichloroethylene g/L0.50 20.0 70-13011723.4 cis-1,2-Dichloroethylene g/L0.50 20.0 70-13010320.7 trans-1,2-Dichloroethylene g/L0.50 20.0 70-13011422.8 1,2-Dichloropropane g/L0.50 20.0 70-13010020.1 1,3-Dichloropropane g/L0.50 20.0 70-13096.019.2 2,2-Dichloropropane g/L0.50 20.0 70-13099.219.8 1,1-Dichloropropene g/L0.50 20.0 70-13010120.2 cis-1,3-Dichloropropene g/L0.50 20.0 70-13097.219.4 trans-1,3-Dichloropropene g/L0.50 20.0 70-13010721.5 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL Batch B336621 - SW-846 5030B LCS (B336621-BS1) Prepared: 04/10/23 Analyzed: 04/11/23 Diisopropyl Ether (DIPE)g/L0.50 20.0 70-13010821.7 Ethylbenzene g/L0.50 20.0 70-13010721.5 2-Hexanone (MBK)g/L5.0 200 70-13079.9160 Isopropylbenzene (Cumene)g/L0.50 20.0 70-13010621.1 p-Isopropyltoluene (p-Cymene)g/L0.50 20.0 70-13010521.0 Methyl tert-Butyl Ether (MTBE)g/L0.50 20.0 70-13011122.2 Methylene Chloride g/L5.0 20.0 70-13012024.1 4-Methyl-2-pentanone (MIBK)g/L5.0 200 70-13089.0178 Naphthalene g/L0.50 20.0 L-0470-13050.4 *10.1 n-Propylbenzene g/L0.50 20.0 70-13010721.4 Styrene g/L0.50 20.0 70-13010821.5 1,1,2,2-Tetrachloroethane g/L0.50 20.0 70-13010320.7 Tetrachloroethylene g/L0.50 20.0 70-13010521.0 Toluene g/L0.50 20.0 70-13099.820.0 1,2,3-Trichlorobenzene g/L1.0 20.0 L-0470-13063.2 *12.6 1,2,4-Trichlorobenzene g/L0.50 20.0 70-13076.615.3 1,1,1-Trichloroethane g/L0.50 20.0 70-13010220.4 1,1,2-Trichloroethane g/L0.50 20.0 70-13010621.2 Trichloroethylene g/L0.50 20.0 70-13010420.9 Trichlorofluoromethane (Freon 11)g/L0.50 20.0 70-13011222.5 1,2,3-Trichloropropane g/L0.50 20.0 R-0570-13090.218.0 1,2,4-Trimethylbenzene g/L0.50 20.0 70-13010020.0 1,3,5-Trimethylbenzene g/L0.50 20.0 70-13010621.1 Vinyl Acetate g/L20 200 70-13092.7185 Vinyl Chloride g/L0.50 20.0 60-14096.419.3 m+p Xylene g/L1.0 40.0 70-13010542.1 o-Xylene g/L0.50 20.0 70-13010521.1 g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 10526.4 g/L 25.0 70-130Surrogate: Toluene-d8 96.524.1 g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 98.824.7 LCS Dup (B336621-BSD1) Prepared: 04/10/23 Analyzed: 04/11/23 Acetone g/L50 200 2570-130121 6.31242 Benzene g/L0.50 20.0 2570-130103 0.48620.5 Bromobenzene g/L0.50 20.0 2570-130103 0.048620.6 Bromochloromethane g/L0.50 20.0 2570-130111 3.4922.2 Bromodichloromethane g/L0.50 20.0 2570-130104 1.0620.9 Bromoform g/L0.50 20.0 2570-13099.2 1.1019.8 Bromomethane g/L2.0 20.0 2560-14091.2 25.018.2 2-Butanone (MEK)g/L5.0 200 2570-130100 3.99200 n-Butylbenzene g/L0.50 20.0 2570-13095.6 0.0019.1 sec-Butylbenzene g/L0.50 20.0 2570-130109 3.7821.8 tert-Butylbenzene g/L0.50 20.0 2570-130102 2.4220.4 Carbon Tetrachloride g/L0.50 20.0 2570-130106 0.23621.2 Chlorobenzene g/L0.50 20.0 2570-130105 0.19021.0 Ethanol g/L50 200 2570-130101 3.27202 Chlorodibromomethane g/L0.50 20.0 2570-13098.6 0.61019.7 Chloroethane g/L0.50 20.0 2560-14091.0 5.5418.2 Chloroform g/L0.50 20.0 2570-130101 2.1520.2 Chloromethane g/L0.60 20.0 2560-14067.4 6.9913.5 2-Chlorotoluene g/L0.50 20.0 2570-130105 4.4721.0 4-Chlorotoluene g/L0.50 20.0 2570-130105 0.71621.0 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL Batch B336621 - SW-846 5030B LCS Dup (B336621-BSD1) Prepared: 04/10/23 Analyzed: 04/11/23 1,2-Dibromoethane (EDB)g/L0.50 20.0 2570-130107 4.2421.5 1,2-Dichlorobenzene g/L0.50 20.0 2570-130105 1.4921.0 1,3-Dichlorobenzene g/L0.50 20.0 2570-130109 2.1321.9 1,4-Dichlorobenzene g/L0.50 20.0 2570-130102 0.39520.3 Dichlorodifluoromethane (Freon 12)g/L0.50 20.0 2560-140102 1.0720.5 1,1-Dichloroethane g/L0.50 20.0 2570-130102 0.34520.3 1,2-Dichloroethane g/L0.50 20.0 2570-130102 0.73420.4 1,1-Dichloroethylene g/L0.50 20.0 25 L-0770-130131 11.1*26.1 cis-1,2-Dichloroethylene g/L0.50 20.0 2570-130104 0.38620.8 trans-1,2-Dichloroethylene g/L0.50 20.0 2570-13097.0 15.819.4 1,2-Dichloropropane g/L0.50 20.0 2570-13099.2 1.2019.8 1,3-Dichloropropane g/L0.50 20.0 2570-13099.0 3.0319.8 2,2-Dichloropropane g/L0.50 20.0 2570-130101 1.4520.1 1,1-Dichloropropene g/L0.50 20.0 2570-130100 0.74420.1 cis-1,3-Dichloropropene g/L0.50 20.0 2570-130101 4.0320.2 trans-1,3-Dichloropropene g/L0.50 20.0 2570-130111 3.3922.2 Diisopropyl Ether (DIPE)g/L0.50 20.0 2570-130109 0.13821.7 Ethylbenzene g/L0.50 20.0 2570-130106 0.98221.3 2-Hexanone (MBK)g/L5.0 200 2570-13079.9 0.0563160 Isopropylbenzene (Cumene)g/L0.50 20.0 2570-130107 1.6921.5 p-Isopropyltoluene (p-Cymene)g/L0.50 20.0 2570-130110 4.2921.9 Methyl tert-Butyl Ether (MTBE)g/L0.50 20.0 2570-13093.0 17.518.6 Methylene Chloride g/L5.0 20.0 2570-130115 4.4623.0 4-Methyl-2-pentanone (MIBK)g/L5.0 200 2570-13089.8 0.845180 Naphthalene g/L0.50 20.0 25 L-0470-13050.3 0.0993*10.1 n-Propylbenzene g/L0.50 20.0 2570-130108 0.83621.6 Styrene g/L0.50 20.0 2570-130108 0.88021.7 1,1,2,2-Tetrachloroethane g/L0.50 20.0 2570-130102 1.8520.3 Tetrachloroethylene g/L0.50 20.0 2570-130112 6.2422.3 Toluene g/L0.50 20.0 2570-130103 3.1620.6 1,2,3-Trichlorobenzene g/L1.0 20.0 25 L-0470-13065.2 3.11*13.0 1,2,4-Trichlorobenzene g/L0.50 20.0 2570-13078.0 1.8815.6 1,1,1-Trichloroethane g/L0.50 20.0 2570-130104 2.4720.9 1,1,2-Trichloroethane g/L0.50 20.0 2570-130105 0.70921.1 Trichloroethylene g/L0.50 20.0 2570-130103 1.1620.6 Trichlorofluoromethane (Freon 11)g/L0.50 20.0 2570-130121 7.0324.1 1,2,3-Trichloropropane g/L0.50 20.0 25 R-0570-130121 28.9 *24.1 1,2,4-Trimethylbenzene g/L0.50 20.0 2570-130101 1.0420.3 1,3,5-Trimethylbenzene g/L0.50 20.0 2570-130106 0.70821.3 Vinyl Acetate g/L20 200 2570-13091.5 1.37183 Vinyl Chloride g/L0.50 20.0 2560-14097.0 0.62019.4 m+p Xylene g/L1.0 40.0 2570-130105 0.33342.0 o-Xylene g/L0.50 20.0 2570-130104 1.4820.8 g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 98.724.7 g/L 25.0 70-130Surrogate: Toluene-d8 98.124.5 g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 96.924.2 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 *QC result is outside of established limits. Wide recovery limits established for difficult compound. Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. No results have been blank subtracted unless specified in the case narrative section. FLAG/QUALIFIER SUMMARY Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J Laboratory fortified blank/laboratory control sample recovery and duplicate recovery are outside of control limits. Reported value for this compound is likely to be biased on the low side. L-04 Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but the other is within limits. RPD between the two LFB/LCS results is within method specified criteria. L-07 Laboratory fortified blank duplicate RPD is outside of control limits. Reduced precision is anticipated for any reported value for this compound. R-05 Elevated reporting limit due to high concentration of target compounds.RL-11 [TOC_1]Flag/Qualifier Summary[TOC] 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report SM21-23 6200B in Water NCAcetone NCBenzene NCBromobenzene NCBromochloromethane NCBromodichloromethane NCBromoform NCBromomethane NC2-Butanone (MEK) NCn-Butylbenzene NCsec-Butylbenzene NCtert-Butylbenzene NCCarbon Tetrachloride NCChlorobenzene NCEthanol NCChlorodibromomethane NCChloroethane NCChloroform NCChloromethane NC2-Chlorotoluene NC4-Chlorotoluene NC1,2-Dibromoethane (EDB) NC1,2-Dichlorobenzene NC1,3-Dichlorobenzene NC1,4-Dichlorobenzene NCDichlorodifluoromethane (Freon 12) NC1,1-Dichloroethane NC1,2-Dichloroethane NC1,1-Dichloroethylene NCcis-1,2-Dichloroethylene NCtrans-1,2-Dichloroethylene NC1,2-Dichloropropane NC1,3-Dichloropropane NC2,2-Dichloropropane NC1,1-Dichloropropene NCcis-1,3-Dichloropropene NCtrans-1,3-Dichloropropene NCDiisopropyl Ether (DIPE) NCEthylbenzene NC2-Hexanone (MBK) NCIsopropylbenzene (Cumene) NCp-Isopropyltoluene (p-Cymene) NCMethyl tert-Butyl Ether (MTBE) NCMethylene Chloride NC4-Methyl-2-pentanone (MIBK) NCNaphthalene NCn-Propylbenzene NCStyrene [TOC_1]Certifications[TOC] 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report SM21-23 6200B in Water NC1,1,2,2-Tetrachloroethane NCTetrachloroethylene NCToluene NC1,2,3-Trichlorobenzene NC1,2,4-Trichlorobenzene NC1,1,1-Trichloroethane NC1,1,2-Trichloroethane NCTrichloroethylene NCTrichlorofluoromethane (Freon 11) NC1,2,3-Trichloropropane NC1,2,4-Trimethylbenzene NC1,3,5-Trimethylbenzene NCVinyl Acetate NCVinyl Chloride NCm+p Xylene NCo-Xylene The CON-TEST Environmental Laboratory operates under the following certifications and accreditations: Code Description Number Expires 652North Carolina Div. of Water QualityNC 12/31/2023