WS-8027_37355_CA_IAR_20230406

INITIAL ABATEMENT ACTION REPORT
COHEN’S CITGO (POP SHOPPE #233)
1675 US HIGHWAY 601
MOCKSVILLE, DAVIE COUNTY, NORTH CAROLINA
GROUNDWATER INCIDENT: 37355 FACILITY ID: 0-002431 SITE RISK: INTERMEDIATE LATITUDE: N 35° 55’ 28” LONGITUDE: W 80° 35’ 36”
APRIL 6, 2023 UST OWNER: Mid-State Petroleum Leasing, Inc. P.O. Box 1618 Jamestown, NC 27282 Phone Number: [phone] PROPERTY OWNER:
Mid-State Petroleum Realty, LLC
P.O. Box 1618
Jamestown, NC 27282
Phone Number: [phone]

CONSULTANT:
Paragon Environmental Consultants, Inc.
P. O. Box 157
Thomasville, NC 27361-0157
Phone Number: [phone]

RELEASE INFORMATION:
Date Discovered: 11/24/08
Estimated Quantity of Release: Unknown
Cause of Release: UST Failure Source of Release: Middle Gasoline UST
Size and Contents: Three (3) 6,000 Gallon Gasoline USTs

The Initial Abatement Action Report for this site has been prepared by Paragon
Environmental Consultants, Inc. under the direct supervision of a licensed geologist. All
activities performed on this project were conducted under my direct supervision:
Benjamin W. Robinson, L.G.
North Carolina License #2466

April 6, 2023

Tony Perez Mid-State Petroleum Leasing, Inc. P.O. Box 1618 Jamestown, NC 27282

Reference: Initial Abatement Action Report Cohen’s Citgo (Pop Shoppe #233) 1675 US Highway 601 Mocksville, Davie County, North Carolina Groundwater Incident # 37355 Facility ID #00-0-0000002431

Dear Mr. Perez:

Please find contained herein an Initial Abatement Action Report for the release which occurred at the above referenced facility. These activities have been conducted following the discovery of petroleum impacted soil during the UST closure assessment at the subject site. The soil remediation consisted of the excavation and disposal of approximately 426 cubic yards of contaminated soil and confirmatory sampling of in-situ soils. All activities were conducted in accordance with North Carolina Department of Environmental Quality (NC DEQ) guidelines and the requirements of 15A NCAC 2N. Mr. Perez, if you have questions regarding this report, please contact our office.

Sincerely,
Benjamin W. Robinson, L.G.
Paragon Environmental Consultants, Inc.

R23-800
PARAGON
Environmental Consultants, Inc.
P.O. Box 157 • Thomasville, NC 27361-0157
Business Ph: [phone] • Fax: [phone]

TABLE OF CONTENTS

Section Page

B. Site History

1. Introduction .................................................................... 1
2. Scope of Services ........................................................... 1
C. Site Investigation 1. Excavation and Soil Sampling ....................................... 2 2. Soil Disposal .................................................................. 2 3. Conclusions and Recommendations .............................. 3
D. Figures Figure 1: Project Location Figure 2: Remedial Excavation and Soil Sample Locations E. Tables Table 1: Summary of Soil Analytical Results F. Appendices Appendix A: Geologic Log of Excavation Appendix B: Soil Analytical Results Appendix C: Standard Operating Procedures Appendix D: Soil Disposal Manifests
Page - 1
INITIAL ABATEMENT ACTION REPORT
Cohen’s Citgo (Pop Shoppe #233) 1675 US Highway 601 Mocksville, NC

B. Site History

1. Introduction
Mid-State Petroleum Leasing, Inc. owned an UST system at 1675 US Highway 601 in Mocksville, NC, which was referred to as Cohen’s Citgo (Pop Shoppe #233). The subject property was operated as a fueling station by Mid-State Petroleum Leasing, Inc. until 2022. The former tanks were removed from this subject property on January 31, 2023. A release was discovered on November 24, 2008 when the middle gasoline UST failed and has been an open incident (#37355) since that time. Following removal of the tanks, product piping, and dispensers, contaminated soils were detected in the native soils beneath the former UST system. Figure 1 illustrates the location of this facility on the Mocksville Quadrangle U.S.G.S. Topographic Map. Figure 2 illustrates the site layout of this facility and the location of the remedial excavation. After removal of the gasoline USTs, the contaminated soil was accessible for the first time since the release discovery in 2008. Paragon Environmental Consultants, Inc. was contracted by Mid-State Petroleum Leasing, Inc. to perform soil remediation activities and confirmatory soil sampling and laboratory analyses in the impacted areas of the former UST system at this project site. Contained herein is a summary of activities which were completed at the project site.

2. Scope of Services

This Initial Abatement Action Report contains documentation concerning the following activities which have been conducted at this facility:

o Excavation of contaminated soils and backfilling of the excavation performed by
KBS Earthworks, Inc. of Julian, NC

o Transportation of contaminated soil by KBS Earthworks, Inc. and disposal of the
excavated material at AES in Thomasville, NC

o Collection of four soil samples from the vertical limits of the remedial excavation
performed by Paragon Environmental

o Laboratory analyses of soil samples conducted by Waypoint Analytical, LLC of Charlotte, NC

Page - 2
C. Site Investigation

1. Excavation and Soil Sampling

On March 8, March 9, and March 14, 2023, KBS Earthworks, Inc. and Paragon personnel mobilized to the subject site and attempted to remove the petroleum impacted soil which had been confirmed by the UST closure assessment. The impacted soils in the excavation area were excavated to a depth at or beneath the shallow groundwater table. In order to verify site conditions, four soil samples were collected from the bottom of the remedial pit. Appendix A contains a geologic log of excavation for the soil remediation activities at this facility. All of the soil samples collected from the remedial excavation at Cohen’s Citgo (Pop Shoppe #233) were analyzed by EPA Method 8260 and MADEP methods for Volatile Petroleum Hydrocarbons (VPH). The in-situ soil samples from the remedial excavation were collected with the excavator bucket and were immediately placed into laboratory supplied glassware and placed on ice for transportation to the analytical laboratory utilizing EPA approved chain-of-custody procedures. According to the laboratory analytical results for the final in-situ soil samples, sample E, which was located in the eastern corner of the remedial excavation, indicated four Method 8260 compounds and three carbon fraction classes in excess of the Residential Standards. Benzene, Ethylbenzene, Naphthalene, and 1,2,4-Trimethylbenzene were reported by Method 8260 at levels above the Residential Standards in this sample. C5-C8 Aliphatics, C9-C18 Aliphatics, and C9-C22 Aromatics were also shown at concentrations which exceed the Residential Standards in the E soil sample. Soil sample W, obtained from the western corner of the remedial excavation, showed four Method 8260 compounds and two carbon fraction classes in excess of the Residential Standards. Benzene, Ethylbenzene, Naphthalene, and 1,2,4-Trimethylbenzene were reported by Method 8260 at levels above the Residential Standards in this sample. C5-C8 Aliphatics and C9-C22 Aromatics were also shown at concentrations which exceed the Residential Standards in the W soil sample. Sample N, collected from the northern corner of the remedial excavation, indicated Benzene, Ethylbenzene, Naphthalene, and 1,2,4-Trimethylbenzene at levels above the Residential Standards. Sample S, collected from the southern corner of the remedial excavation, indicated Ethylbenzene, Naphthalene, and 1,2,4-Trimethylbenzene at levels above the Residential Standards. Figure 2 illustrates the area of soil remediation and the locations of the in-situ soil samples collected at this facility. The analytical results for the soil analyses are summarized in Table 1, and a copy of the laboratory analytical report and the chain-of-custody record is included in Appendix B. All samples were obtained in accordance with Paragon’s Standard Operating Procedures which are included as Appendix C.

2. Soil Disposal
A total of approximately 426 cubic yards (595.82 tons) of petroleum impacted soils were removed during the site remediation activities on March 8, March 9, and March 14, 2023. This material was transported by KBS Earthworks, Inc. to AES’s facility in Thomasville, NC for treatment and disposal. Copies of the soil disposal manifests for the petroleum impacted material from Cohen’s Citgo (Pop Shoppe #233) are contained as Appendix D.

Page - 3
3. Conclusions and Recommendations
3. A Conclusions and Recommendations

The soil remediation activities at 1675 US Highway 601 have been completed. From a review of all information gathered during this removal project, Paragon Environmental Consultants, Inc. makes the following conclusions:

o Laboratory results for samples from in-situ soils following the excavation activities indicated four Method 8260 compounds and three carbon fraction classes in excess of the Residential Standards.

o A total of 595.82 tons of petroleum contaminated soil were removed from this
facility on March 8, March 9, and March 14, 2023. This material was transported
by KBS Earthworks, Inc. to AES’s facility in Thomasville, NC for disposal.

3. B. Recommendations
Based upon a review of all information gathered during the soil contamination project, Paragon makes the following recommendations:
o Two 4-inch recovery wells should be installed in the remedial excavation to assess current groundwater conditions and conduct further free product recovery / groundwater remediation at this facility.
o A copy of this report should be forwarded to the following address:

Winston-Salem Regional Office - UST Section 450 W. Hanes Mill Road Winston-Salem, NC 27105

3. C. Limitations
This report has been prepared for the exclusive use of Mid-State Petroleum Leasing, Inc. for the specific application to the referenced site located in Davie County, North Carolina. The assessment was conducted based on the scope of work and level of effort desired by the client. Our findings have been developed in accordance with generally accepted standards in the practice of Initial Abatement Reports in the State of North Carolina, available information, and our professional judgment. No other warranty is expressed or implied.
The data presented in this report are indicative of conditions that existed at the precise locations sampled and at the time the samples were collected. Additionally, the data obtained from the samples would be interpreted as meaningful with respect to the parameters indicated in the laboratory reports. No additional information can be logically inferred from this data.

FIGURES

TABLES

TABLE 1
Summary of Soil Analytical Results
Cohen's Citgo (Pop Shoppe #233)
Mocksville, North Carolina
Constituent N E S W Lowest MSCCs Residential Standards Ind./Comm. Standards
Date 3/14/2023 3/14/2023 3/14/2023 3/14/2023
Method 8260 (mg/kg)
Acetone BDL BDL BDL BDL 24 14,000 210,000
Benzene 20.6 110 3.07 41.1 0.0072 12 59.4
n-Butylbenzene 10.4 18.5 11.8 17.7 2.4 782 11,600
sec-Butylbenzene 3.37 6.39 4.21 6.12 2.2 1,560 23,300
Carbon Disulfide BDL BDL BDL BDL 3.7 1,560 23,300
Di-Isopropyl Ether (DIPE)BDL BDL BDL BDL 0.32 NSE 2,330
Ethylbenzene 86.8 231 69.2 205 8 60.3 297
n-Hexane 36.7 126 16.7 132 NSE NSE NSE
Isopropylbenzene 9.3 19.8 9.6 18.4 1.3 1,560 23,300
p-Isopropyltoluene 1.94 3.37 2.09 3.24 0.12 1,560 23,300
Methyl Tert Butyl Ether (MTBE)BDL BDL BDL BDL 0.085 156 1,810
Methylene Chloride 1.27 1.67 1.29 1.74 0.023 93.8 1,400
Naphthalene 26 52.6 33.2 46.8 0.2 5.5 27
n-Propylbenzene 36.2 74.9 37.4 70.1 1.4 1,560 23,300
Styrene 0.748 1.5 0.521 1.84 0.9 3,120 46,700
Toluene 216 795 111 642 5.4 1,250 18,600
1,2,4-Trimethylbenzene 216 502 267 434 6.6 156 2,330
1,3,5-Trimethylbenzene 63 124 70.2 118 6.6 156 2,330
Xylenes (total)448 1,200 377 1,080 6 3,120 46,700
Aliphatic Fraction Classes (mg/kg)
C5-C8 Volatile Aliphatics 439 3,860 267 1,000 68 625 9,340
C9-C12 Volatile Aliphatics 433 4,920 564 972 NSE NSE NSE
C9-C18 Extractable Aliphatics N/A N/A N/A N/A NSE NSE NSE
C9-C18 Aliphatics (total)433 4,920 564 972 540 1,560 23,300
C19-C36 Extractable Aliphatics N/A N/A N/A N/A NSE 31,200 467,000
Aromatic Fraction Classes (mg/kg)
C9-C10 Volatile Aromatics 157 1,670 239 479 NSE NSE NSE
C11-C22 Extractable Aromatics N/A N/A N/A N/A NSE NSE NSE
C9-C22 Aromatics (total)157 1,670 239 479 31 469 7,000
BDL= Below Detection Limits
NSE = No Standard Established X23-800

APPENDIX A

GEOLOGIC LOG OF EXCAVATION

GEOLOGIC LOG OF EXCAVATION
Paragon Environmental Consultants, Inc.
Job Name:Cohen's Citgo (Pop Shoppe #233)
Address:1675 US Highway 601 Mocksville, NC 27028
Job No.:P-800 Excavation Method:Excavator
Start Date:3/8/23 Sample Method:Excavator Bucket
Contractor:KBS Earthworks, Inc.Sampled By:BWR
Sample ID:Initial Abatement Action Samples Logged By:BWR
Comments:

Sample Depth OVA
Number (FT.)Soil Decription (color, soil type, moisture) (ppm)
N 27 Tan/black, SILT with clay, moist N/A
E 27 Tan/black, SILT with clay, moist N/A
S 23 Tan/black, SILT with clay, moist N/A
W 27 Tan/black, SILT with clay, moist N/A
P-800X

APPENDIX B

SOIL ANALYTICAL RESULTS

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

3/24/2023
Paragon Environmental Consultants, Inc. Brandon Moore
PO Box 157 Thomasville, NC, 27361
Ref: Analytical Testing
Lab Report Number: 23-074-0012 Client Project Description: Cohen's Citgo (Pop Shoppe #233)
P-800
Dear Brandon Moore:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/15/2023 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Angela D Overcash Senior Project Manager
Page 1 of 40
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/23-074-0012
Page 2 of 40
Report Number:
Sample Summary Table
Client Project Description:
23-074-0012
Cohen's Citgo (Pop Shoppe #233)
P-800
Lab No Client Sample ID Matrix Date Collected Date Received
03/14/2023 14:00Solids 91221 N 03/15/2023 15:08
03/14/2023 14:20Solids 91222 E 03/15/2023 15:08
03/14/2023 12:00Solids 91223 S 03/15/2023 15:08
03/14/2023 15:00Solids 91224 W 03/15/2023 15:08
Page 3 of 40
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-074-0012
Report Limit
Project:Cohen's Citgo (Pop Shoppe #233)
V 91221N
20.6 03/16/2023 12:418260DBenzenemg/Kg - dry 0.199
10.4 03/16/2023 12:418260Dn-Butylbenzene mg/Kg - dry 0.169
3.37 03/16/2023 12:418260Dsec-Butyl benzene mg/Kg - dry 0.192
86.8 03/16/2023 12:418260DEthylbenzenemg/Kg - dry 0.199
36.7 03/16/2023 12:418260Dn-Hexane mg/Kg - dry 0.226
9.30 03/16/2023 12:418260DIsopropylbenzenemg/Kg - dry 0.158
1.94 03/16/2023 12:418260D4-Isopropyl toluene mg/Kg - dry 0.447
J1.27 03/16/2023 12:418260DMethylene Chloride mg/Kg - dry 0.506
26.0 03/16/2023 12:418260DNaphthalenemg/Kg - dry 0.341
36.2 03/16/2023 12:418260Dn-Propylbenzene mg/Kg - dry 0.185
J0.748 03/16/2023 12:418260DStyrenemg/Kg - dry 0.488
216 03/16/2023 13:098260DToluenemg/Kg - dry 2.27
216 03/16/2023 13:098260D1,2,4-Trimethylbenzene mg/Kg - dry 1.69
63.0 03/16/2023 12:418260D1,3,5-Trimethylbenzene mg/Kg - dry 0.185
136 03/16/2023 12:418260Do-Xylene mg/Kg - dry 0.171
312 03/16/2023 13:098260Dm,p-Xylene mg/Kg - dry 4.33
448 03/16/2023 12:418260DXylene (Total)mg/Kg - dry 0.171
439 03/17/2023 15:43MADEP-VPH Aliphatic C5-C8 mg/Kg - dry 8.36
433 03/17/2023 15:43MADEP-VPH Aliphatic C9-C12 mg/Kg - dry 31.4
157 03/17/2023 15:43MADEP-VPH Aromatic C9-C10 mg/Kg - dry 4.29
27.3 03/21/2023 17:29SW-DRYWT Moisture %
V 91222E
110 03/16/2023 14:038260DBenzenemg/Kg - dry 0.239
18.5 03/16/2023 14:038260Dn-Butylbenzene mg/Kg - dry 0.202
6.39 03/16/2023 14:038260Dsec-Butyl benzene mg/Kg - dry 0.231
231 03/16/2023 14:308260DEthylbenzenemg/Kg - dry 2.39
126 03/16/2023 14:038260Dn-Hexane mg/Kg - dry 0.272
19.8 03/16/2023 14:038260DIsopropylbenzenemg/Kg - dry 0.189
3.37 03/16/2023 14:038260D4-Isopropyl toluene mg/Kg - dry 0.536
J1.67 03/16/2023 14:038260DMethylene Chloride mg/Kg - dry 0.607
52.6 03/16/2023 14:038260DNaphthalenemg/Kg - dry 0.409
74.9 03/16/2023 14:038260Dn-Propylbenzene mg/Kg - dry 0.222
J1.50 03/16/2023 14:038260DStyrenemg/Kg - dry 0.585
795 03/16/2023 14:308260DToluenemg/Kg - dry 2.72
502 03/16/2023 14:308260D1,2,4-Trimethylbenzene mg/Kg - dry 2.03
124 03/16/2023 14:038260D1,3,5-Trimethylbenzene mg/Kg - dry 0.222
Page 4 of 40
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-074-0012
Report Limit
Project:Cohen's Citgo (Pop Shoppe #233)
V 91222E
347 03/16/2023 14:308260Do-Xylene mg/Kg - dry 2.06
850 03/16/2023 14:308260Dm,p-Xylene mg/Kg - dry 5.20
1200 03/16/2023 14:308260DXylene (Total)mg/Kg - dry 2.06
3860 03/17/2023 18:55MADEP-VPH Aliphatic C5-C8 mg/Kg - dry 100
4920 03/17/2023 18:55MADEP-VPH Aliphatic C9-C12 mg/Kg - dry 376
1670 03/17/2023 18:55MADEP-VPH Aromatic C9-C10 mg/Kg - dry 51.5
39.4 03/21/2023 17:29SW-DRYWT Moisture %
V 91223S
3.07 03/16/2023 14:578260DBenzenemg/Kg - dry 0.212
11.8 03/16/2023 14:578260Dn-Butylbenzene mg/Kg - dry 0.180
4.21 03/16/2023 14:578260Dsec-Butyl benzene mg/Kg - dry 0.205
69.2 03/16/2023 14:578260DEthylbenzenemg/Kg - dry 0.212
16.7 03/16/2023 14:578260Dn-Hexane mg/Kg - dry 0.242
9.60 03/16/2023 14:578260DIsopropylbenzenemg/Kg - dry 0.168
2.09 03/16/2023 14:578260D4-Isopropyl toluene mg/Kg - dry 0.477
J1.29 03/16/2023 14:578260DMethylene Chloride mg/Kg - dry 0.540
33.2 03/16/2023 14:578260DNaphthalenemg/Kg - dry 0.364
37.4 03/16/2023 14:578260Dn-Propylbenzene mg/Kg - dry 0.198
J0.521 03/16/2023 14:578260DStyrenemg/Kg - dry 0.521
111 03/16/2023 14:578260DToluenemg/Kg - dry 0.242
267 03/16/2023 15:248260D1,2,4-Trimethylbenzene mg/Kg - dry 1.81
70.2 03/16/2023 14:578260D1,3,5-Trimethylbenzene mg/Kg - dry 0.198
120 03/16/2023 14:578260Do-Xylene mg/Kg - dry 0.183
257 03/16/2023 14:578260Dm,p-Xylene mg/Kg - dry 0.462
377 03/16/2023 14:578260DXylene (Total)mg/Kg - dry 0.183
267 03/17/2023 16:31MADEP-VPH Aliphatic C5-C8 mg/Kg - dry 8.93
564 03/17/2023 16:31MADEP-VPH Aliphatic C9-C12 mg/Kg - dry 33.5
239 03/17/2023 16:31MADEP-VPH Aromatic C9-C10 mg/Kg - dry 4.58
31.9 03/21/2023 17:29SW-DRYWT Moisture %
V 91224W
41.1 03/16/2023 15:528260DBenzenemg/Kg - dry 0.224
17.7 03/16/2023 15:528260Dn-Butylbenzene mg/Kg - dry 0.190
6.12 03/16/2023 15:528260Dsec-Butyl benzene mg/Kg - dry 0.217
205 03/16/2023 16:198260DEthylbenzenemg/Kg - dry 2.25
132 03/16/2023 15:528260Dn-Hexane mg/Kg - dry 0.255
18.4 03/16/2023 15:528260DIsopropylbenzenemg/Kg - dry 0.178
Page 5 of 40
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-074-0012
Report Limit
Project:Cohen's Citgo (Pop Shoppe #233)
V 91224W
3.24 03/16/2023 15:528260D4-Isopropyl toluene mg/Kg - dry 0.503
J1.74 03/16/2023 15:528260DMethylene Chloride mg/Kg - dry 0.570
46.8 03/16/2023 15:528260DNaphthalenemg/Kg - dry 0.384
70.1 03/16/2023 15:528260Dn-Propylbenzene mg/Kg - dry 0.209
J1.84 03/16/2023 15:528260DStyrenemg/Kg - dry 0.550
642 03/16/2023 16:198260DToluenemg/Kg - dry 2.56
434 03/16/2023 16:198260D1,2,4-Trimethylbenzene mg/Kg - dry 1.91
118 03/16/2023 15:528260D1,3,5-Trimethylbenzene mg/Kg - dry 0.209
305 03/16/2023 16:198260Do-Xylene mg/Kg - dry 1.94
729 03/16/2023 16:198260Dm,p-Xylene mg/Kg - dry 4.88
1030 03/16/2023 16:198260DXylene (Total)mg/Kg - dry 1.94
1000 03/17/2023 18:07MADEP-VPH Aliphatic C5-C8 mg/Kg - dry 94.3
972 03/17/2023 17:19MADEP-VPH Aliphatic C9-C12 mg/Kg - dry 35.3
479 03/17/2023 17:19MADEP-VPH Aromatic C9-C10 mg/Kg - dry 4.84
35.5 03/21/2023 17:29SW-DRYWT Moisture %
Page 6 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:N
91221 Matrix:
3/14/2023 14:00
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
27.3 %Moisture 1 03/21/23 17:29 SW-DRYWTAMB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 7 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:N
91221 Matrix:
3/14/2023 14:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30900 03/16/23 08:00
<0.825 mg/Kg - dry 0.825 6.88Acetone 500 03/16/23 12:41 V30901TBL
<0.416 mg/Kg - dry 0.416 6.88Acrolein 500 03/16/23 12:41 V30901TBL
<0.258 mg/Kg - dry 0.258 6.88Acrylonitrile 500 03/16/23 12:41 V30901TBL
20.6 mg/Kg - dry 0.199 1.72Benzene 500 03/16/23 12:41 V30901TBL
<0.171 mg/Kg - dry 0.171 1.72Bromobenzene 500 03/16/23 12:41 V30901TBL
<0.275 mg/Kg - dry 0.275 1.72Bromochloromethane 500 03/16/23 12:41 V30901TBL
<0.409 mg/Kg - dry 0.409 1.72Bromodichloromethane 500 03/16/23 12:41 V30901TBL
<0.348 mg/Kg - dry 0.348 1.72Bromoform 500 03/16/23 12:41 V30901TBL
<0.625 mg/Kg - dry 0.625 3.44
Bromomethane 500 03/16/23 12:41 V30901TBL
10.4 mg/Kg - dry 0.169 1.72n-Butylbenzene 500 03/16/23 12:41 V30901TBL
3.37 mg/Kg - dry 0.192 1.72sec-Butyl benzene 500 03/16/23 12:41 V30901TBL
<0.171 mg/Kg - dry 0.171 1.72tert-Butyl benzene 500 03/16/23 12:41 V30901TBL
<0.220 mg/Kg - dry 0.220 1.72Carbon Disulfide 500 03/16/23 12:41 V30901TBL
<0.543 mg/Kg - dry 0.543 1.72Carbon Tetrachloride 500 03/16/23 12:41 V30901TBL
<0.231 mg/Kg - dry 0.231 1.72Chlorobenzene 500 03/16/23 12:41 V30901TBL
<0.306 mg/Kg - dry 0.306 1.72
Chlorodibromomethane 500 03/16/23 12:41 V30901TBL
<0.306 mg/Kg - dry 0.306 3.44Chloroethane 500 03/16/23 12:41 V30901TBL
<0.361 mg/Kg - dry 0.361 1.72Chloroform 500 03/16/23 12:41 V30901TBL
<0.217 mg/Kg - dry 0.217 3.44Chloromethane 500 03/16/23 12:41 V30901TBL
<0.176 mg/Kg - dry 0.176 1.722-Chlorotoluene 500 03/16/23 12:41 V30901TBL
<0.134 mg/Kg - dry 0.134 1.724-Chlorotoluene 500 03/16/23 12:41 V30901TBL
<0.251 mg/Kg - dry 0.251 1.72Di-Isopropyl Ether (DIPE)500 03/16/23 12:41 V30901TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 8 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:N
91221 Matrix:
3/14/2023 14:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30900 03/16/23 08:00
<0.151 mg/Kg - dry 0.151 3.441,2-Dibromo-3-Chloropropane 500 03/16/23 12:41 V30901TBL
<0.203 mg/Kg - dry 0.203 1.721,2-Dibromoethane 500 03/16/23 12:41 V30901TBL
<0.341 mg/Kg - dry 0.341 1.72Dibromomethane 500 03/16/23 12:41 V30901TBL
<0.106 mg/Kg - dry 0.106 1.721,2-Dichlorobenzene 500 03/16/23 12:41 V30901TBL
<0.130 mg/Kg - dry 0.130 1.721,3-Dichlorobenzene 500 03/16/23 12:41 V30901TBL
<0.206 mg/Kg - dry 0.206 1.721,4-Dichlorobenzene 500 03/16/23 12:41 V30901TBL
<0.453 mg/Kg - dry 0.453 3.44Dichlorodifluoromethane 500 03/16/23 12:41 V30901TBL
<0.281 mg/Kg - dry 0.281 1.721,1-Dichloroethane 500 03/16/23 12:41 V30901TBL
<0.474 mg/Kg - dry 0.474 1.72
1,2-Dichloroethane 500 03/16/23 12:41 V30901TBL
<0.251 mg/Kg - dry 0.251 1.721,1-Dichloroethene 500 03/16/23 12:41 V30901TBL
<0.272 mg/Kg - dry 0.272 1.72cis-1,2-Dichloroethene 500 03/16/23 12:41 V30901TBL
<0.361 mg/Kg - dry 0.361 1.72trans-1,2-Dichloroethene 500 03/16/23 12:41 V30901TBL
<0.151 mg/Kg - dry 0.151 1.721,2-Dichloropropane 500 03/16/23 12:41 V30901TBL
<0.189 mg/Kg - dry 0.189 1.721,3-Dichloropropane 500 03/16/23 12:41 V30901TBL
<0.437 mg/Kg - dry 0.437 1.722,2-Dichloropropane 500 03/16/23 12:41 V30901TBL
<0.261 mg/Kg - dry 0.261 1.72
1,1-Dichloropropene 500 03/16/23 12:41 V30901TBL
<0.185 mg/Kg - dry 0.185 1.72cis-1,3-Dichloropropene 500 03/16/23 12:41 V30901TBL
<0.275 mg/Kg - dry 0.275 1.72trans-1,3-Dichloropropene 500 03/16/23 12:41 V30901TBL
86.8 mg/Kg - dry 0.199 1.72Ethylbenzene 500 03/16/23 12:41 V30901TBL
<0.286 mg/Kg - dry 0.286 34.4Ethyl Tertiary Butyl Ether (ETBE)500 03/16/23 12:41 V30901TBL
<0.272 mg/Kg - dry 0.272 3.44Hexachlorobutadiene 500 03/16/23 12:41 V30901TBL
36.7 mg/Kg - dry 0.226 3.44n-Hexane 500 03/16/23 12:41 V30901TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 9 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:N
91221 Matrix:
3/14/2023 14:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30900 03/16/23 08:00
<0.213 mg/Kg - dry 0.213 6.882-Hexanone 500 03/16/23 12:41 V30901TBL
9.30 mg/Kg - dry 0.158 1.72Isopropylbenzene 500 03/16/23 12:41 V30901TBL
1.94 mg/Kg - dry 0.447 1.724-Isopropyl toluene 500 03/16/23 12:41 V30901TBL
<0.224 mg/Kg - dry 0.224 6.88Methyl Ethyl Ketone (MEK)500 03/16/23 12:41 V30901TBL
<0.213 mg/Kg - dry 0.213 1.72Methyl tert-butyl ether (MTBE)500 03/16/23 12:41 V30901TBL
<5.16 mg/Kg - dry 5.16 6.884-Methyl-2-Pentanone 500 03/16/23 12:41 V30901TBL
1.27 J mg/Kg - dry 0.506 1.72Methylene Chloride 500 03/16/23 12:41 V30901TBL
26.0 mg/Kg - dry 0.341 3.44Naphthalene 500 03/16/23 12:41 V30901TBL
36.2 mg/Kg - dry 0.185 1.72
n-Propylbenzene 500 03/16/23 12:41 V30901TBL
0.748 J mg/Kg - dry 0.488 1.72Styrene 500 03/16/23 12:41 V30901TBL
<0.361 mg/Kg - dry 0.361 1.721,1,1,2-Tetrachloroethane 500 03/16/23 12:41 V30901TBL
<0.110 mg/Kg - dry 0.110 1.721,1,2,2-Tetrachloroethane 500 03/16/23 12:41 V30901TBL
<0.309 mg/Kg - dry 0.309 1.72Tetrachloroethene 500 03/16/23 12:41 V30901TBL
216 mg/Kg - dry 2.27 17.2Toluene 5000 03/16/23 13:09 V30901TBL
<0.185 mg/Kg - dry 0.185 3.441,2,3-Trichlorobenzene 500 03/16/23 12:41 V30901TBL
<0.220 mg/Kg - dry 0.220 3.44
1,2,4-Trichlorobenzene 500 03/16/23 12:41 V30901TBL
<0.495 mg/Kg - dry 0.495 1.721,1,1-Trichloroethane 500 03/16/23 12:41 V30901TBL
<0.162 mg/Kg - dry 0.162 1.721,1,2-Trichloroethane 500 03/16/23 12:41 V30901TBL
<0.316 mg/Kg - dry 0.316 1.72Trichloroethene 500 03/16/23 12:41 V30901TBL
<0.719 mg/Kg - dry 0.719 3.44Trichlorofluoromethane 500 03/16/23 12:41 V30901TBL
<0.247 mg/Kg - dry 0.247 1.721,2,3-Trichloropropane 500 03/16/23 12:41 V30901TBL
216 mg/Kg - dry 1.69 17.21,2,4-Trimethylbenzene 5000 03/16/23 13:09 V30901TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 10 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:N
91221 Matrix:
3/14/2023 14:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30900 03/16/23 08:00
63.0 mg/Kg - dry 0.185 1.721,3,5-Trimethylbenzene 500 03/16/23 12:41 V30901TBL
<0.158 mg/Kg - dry 0.158 3.44Vinyl Acetate 500 03/16/23 12:41 V30901TBL
<0.165 mg/Kg - dry 0.165 3.44Vinyl Chloride 500 03/16/23 12:41 V30901TBL
136 mg/Kg - dry 0.171 1.72o-Xylene 500 03/16/23 12:41 V30901TBL
312 mg/Kg - dry 4.33 34.4m,p-Xylene 5000 03/16/23 13:09 V30901TBL
448 mg/Kg - dry 0.171 1.72Xylene (Total)500 03/16/23 12:41 V30901
Surrogate: 4-Bromofluorobenzene 95.8 Limits: 70-130%03/16/23 12:41500 TBL V30901
Surrogate: Dibromofluoromethane 98.6 Limits: 70-130%03/16/23 12:41500 TBL V30901
Surrogate: Toluene-d8 96.4 Limits: 76-129%03/16/23 12:41500 TBL V30901
Surrogate: 4-Bromofluorobenzene 98.8 Limits: 70-130%03/16/23 13:095000 TBL V30901
Surrogate: Dibromofluoromethane 102 Limits: 70-130%03/16/23 13:095000 TBL V30901
Surrogate: Toluene-d8 92.2 Limits: 76-129%03/16/23 13:095000 TBL V30901
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 11 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:N
91221 Matrix:
3/14/2023 14:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30944 03/17/23 08:00
439 mg/Kg - dry 8.36 55.0Aliphatic C5-C8 500 03/17/23 15:43 V30945TBL
433 mg/Kg - dry 31.4 55.0Aliphatic C9-C12 500 03/17/23 15:43 V30945TBL
157 mg/Kg - dry 4.29 55.0Aromatic C9-C10 500 03/17/23 15:43 V30945TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)91.8 Limits: 70-130%03/17/23 15:43500 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)84.8 Limits: 70-130%03/17/23 15:43500 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 12 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:E
91222 Matrix:
3/14/2023 14:20
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
39.4 %Moisture 1 03/21/23 17:29 SW-DRYWTAMB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 13 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:E
91222 Matrix:
3/14/2023 14:20
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30900 03/16/23 08:00
<0.990 mg/Kg - dry 0.990 8.25Acetone 500 03/16/23 14:03 V30901TBL
<0.500 mg/Kg - dry 0.500 8.25Acrolein 500 03/16/23 14:03 V30901TBL
<0.310 mg/Kg - dry 0.310 8.25Acrylonitrile 500 03/16/23 14:03 V30901TBL
110 mg/Kg - dry 0.239 2.06Benzene 500 03/16/23 14:03 V30901TBL
<0.206 mg/Kg - dry 0.206 2.06Bromobenzene 500 03/16/23 14:03 V30901TBL
<0.330 mg/Kg - dry 0.330 2.06Bromochloromethane 500 03/16/23 14:03 V30901TBL
<0.491 mg/Kg - dry 0.491 2.06Bromodichloromethane 500 03/16/23 14:03 V30901TBL
<0.417 mg/Kg - dry 0.417 2.06Bromoform 500 03/16/23 14:03 V30901TBL
<0.750 mg/Kg - dry 0.750 4.13
Bromomethane 500 03/16/23 14:03 V30901TBL
18.5 mg/Kg - dry 0.202 2.06n-Butylbenzene 500 03/16/23 14:03 V30901TBL
6.39 mg/Kg - dry 0.231 2.06sec-Butyl benzene 500 03/16/23 14:03 V30901TBL
<0.206 mg/Kg - dry 0.206 2.06tert-Butyl benzene 500 03/16/23 14:03 V30901TBL
<0.264 mg/Kg - dry 0.264 2.06Carbon Disulfide 500 03/16/23 14:03 V30901TBL
<0.651 mg/Kg - dry 0.651 2.06Carbon Tetrachloride 500 03/16/23 14:03 V30901TBL
<0.277 mg/Kg - dry 0.277 2.06Chlorobenzene 500 03/16/23 14:03 V30901TBL
<0.367 mg/Kg - dry 0.367 2.06
Chlorodibromomethane 500 03/16/23 14:03 V30901TBL
<0.367 mg/Kg - dry 0.367 4.13Chloroethane 500 03/16/23 14:03 V30901TBL
<0.433 mg/Kg - dry 0.433 2.06Chloroform 500 03/16/23 14:03 V30901TBL
<0.260 mg/Kg - dry 0.260 4.13Chloromethane 500 03/16/23 14:03 V30901TBL
<0.211 mg/Kg - dry 0.211 2.062-Chlorotoluene 500 03/16/23 14:03 V30901TBL
<0.160 mg/Kg - dry 0.160 2.064-Chlorotoluene 500 03/16/23 14:03 V30901TBL
<0.301 mg/Kg - dry 0.301 2.06Di-Isopropyl Ether (DIPE)500 03/16/23 14:03 V30901TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 14 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:E
91222 Matrix:
3/14/2023 14:20
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30900 03/16/23 08:00
<0.181 mg/Kg - dry 0.181 4.131,2-Dibromo-3-Chloropropane 500 03/16/23 14:03 V30901TBL
<0.244 mg/Kg - dry 0.244 2.061,2-Dibromoethane 500 03/16/23 14:03 V30901TBL
<0.409 mg/Kg - dry 0.409 2.06Dibromomethane 500 03/16/23 14:03 V30901TBL
<0.127 mg/Kg - dry 0.127 2.061,2-Dichlorobenzene 500 03/16/23 14:03 V30901TBL
<0.156 mg/Kg - dry 0.156 2.061,3-Dichlorobenzene 500 03/16/23 14:03 V30901TBL
<0.247 mg/Kg - dry 0.247 2.061,4-Dichlorobenzene 500 03/16/23 14:03 V30901TBL
<0.544 mg/Kg - dry 0.544 4.13Dichlorodifluoromethane 500 03/16/23 14:03 V30901TBL
<0.338 mg/Kg - dry 0.338 2.061,1-Dichloroethane 500 03/16/23 14:03 V30901TBL
<0.569 mg/Kg - dry 0.569 2.06
1,2-Dichloroethane 500 03/16/23 14:03 V30901TBL
<0.301 mg/Kg - dry 0.301 2.061,1-Dichloroethene 500 03/16/23 14:03 V30901TBL
<0.326 mg/Kg - dry 0.326 2.06cis-1,2-Dichloroethene 500 03/16/23 14:03 V30901TBL
<0.433 mg/Kg - dry 0.433 2.06trans-1,2-Dichloroethene 500 03/16/23 14:03 V30901TBL
<0.181 mg/Kg - dry 0.181 2.061,2-Dichloropropane 500 03/16/23 14:03 V30901TBL
<0.227 mg/Kg - dry 0.227 2.061,3-Dichloropropane 500 03/16/23 14:03 V30901TBL
<0.524 mg/Kg - dry 0.524 2.062,2-Dichloropropane 500 03/16/23 14:03 V30901TBL
<0.313 mg/Kg - dry 0.313 2.06
1,1-Dichloropropene 500 03/16/23 14:03 V30901TBL
<0.222 mg/Kg - dry 0.222 2.06cis-1,3-Dichloropropene 500 03/16/23 14:03 V30901TBL
<0.330 mg/Kg - dry 0.330 2.06trans-1,3-Dichloropropene 500 03/16/23 14:03 V30901TBL
231 mg/Kg - dry 2.39 20.6Ethylbenzene 5000 03/16/23 14:30 V30901TBL
<0.343 mg/Kg - dry 0.343 41.3Ethyl Tertiary Butyl Ether (ETBE)500 03/16/23 14:03 V30901TBL
<0.326 mg/Kg - dry 0.326 4.13Hexachlorobutadiene 500 03/16/23 14:03 V30901TBL
126 mg/Kg - dry 0.272 4.13n-Hexane 500 03/16/23 14:03 V30901TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 15 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:E
91222 Matrix:
3/14/2023 14:20
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30900 03/16/23 08:00
<0.255 mg/Kg - dry 0.255 8.252-Hexanone 500 03/16/23 14:03 V30901TBL
19.8 mg/Kg - dry 0.189 2.06Isopropylbenzene 500 03/16/23 14:03 V30901TBL
3.37 mg/Kg - dry 0.536 2.064-Isopropyl toluene 500 03/16/23 14:03 V30901TBL
<0.268 mg/Kg - dry 0.268 8.25Methyl Ethyl Ketone (MEK)500 03/16/23 14:03 V30901TBL
<0.255 mg/Kg - dry 0.255 2.06Methyl tert-butyl ether (MTBE)500 03/16/23 14:03 V30901TBL
<6.19 mg/Kg - dry 6.19 8.254-Methyl-2-Pentanone 500 03/16/23 14:03 V30901TBL
1.67 J mg/Kg - dry 0.607 2.06Methylene Chloride 500 03/16/23 14:03 V30901TBL
52.6 mg/Kg - dry 0.409 4.13Naphthalene 500 03/16/23 14:03 V30901TBL
74.9 mg/Kg - dry 0.222 2.06
n-Propylbenzene 500 03/16/23 14:03 V30901TBL
1.50 J mg/Kg - dry 0.585 2.06Styrene 500 03/16/23 14:03 V30901TBL
<0.433 mg/Kg - dry 0.433 2.061,1,1,2-Tetrachloroethane 500 03/16/23 14:03 V30901TBL
<0.132 mg/Kg - dry 0.132 2.061,1,2,2-Tetrachloroethane 500 03/16/23 14:03 V30901TBL
<0.371 mg/Kg - dry 0.371 2.06Tetrachloroethene 500 03/16/23 14:03 V30901TBL
795 mg/Kg - dry 2.72 20.6Toluene 5000 03/16/23 14:30 V30901TBL
<0.222 mg/Kg - dry 0.222 4.131,2,3-Trichlorobenzene 500 03/16/23 14:03 V30901TBL
<0.264 mg/Kg - dry 0.264 4.13
1,2,4-Trichlorobenzene 500 03/16/23 14:03 V30901TBL
<0.594 mg/Kg - dry 0.594 2.061,1,1-Trichloroethane 500 03/16/23 14:03 V30901TBL
<0.194 mg/Kg - dry 0.194 2.061,1,2-Trichloroethane 500 03/16/23 14:03 V30901TBL
<0.379 mg/Kg - dry 0.379 2.06Trichloroethene 500 03/16/23 14:03 V30901TBL
<0.863 mg/Kg - dry 0.863 4.13Trichlorofluoromethane 500 03/16/23 14:03 V30901TBL
<0.297 mg/Kg - dry 0.297 2.061,2,3-Trichloropropane 500 03/16/23 14:03 V30901TBL
502 mg/Kg - dry 2.03 20.61,2,4-Trimethylbenzene 5000 03/16/23 14:30 V30901TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 16 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:E
91222 Matrix:
3/14/2023 14:20
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30900 03/16/23 08:00
124 mg/Kg - dry 0.222 2.061,3,5-Trimethylbenzene 500 03/16/23 14:03 V30901TBL
<0.189 mg/Kg - dry 0.189 4.13Vinyl Acetate 500 03/16/23 14:03 V30901TBL
<0.198 mg/Kg - dry 0.198 4.13Vinyl Chloride 500 03/16/23 14:03 V30901TBL
347 mg/Kg - dry 2.06 20.6o-Xylene 5000 03/16/23 14:30 V30901TBL
850 mg/Kg - dry 5.20 41.3m,p-Xylene 5000 03/16/23 14:30 V30901TBL
1200 mg/Kg - dry 2.06 20.6Xylene (Total)5000 03/16/23 14:30 V30901
Surrogate: 4-Bromofluorobenzene 97.4 Limits: 70-130%03/16/23 14:03500 TBL V30901
Surrogate: Dibromofluoromethane 99.0 Limits: 70-130%03/16/23 14:03500 TBL V30901
Surrogate: Toluene-d8 95.2 Limits: 76-129%03/16/23 14:03500 TBL V30901
Surrogate: 4-Bromofluorobenzene 99.4 Limits: 70-130%03/16/23 14:305000 TBL V30901
Surrogate: Dibromofluoromethane 100 Limits: 70-130%03/16/23 14:305000 TBL V30901
Surrogate: Toluene-d8 96.6 Limits: 76-129%03/16/23 14:305000 TBL V30901
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 17 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:E
91222 Matrix:
3/14/2023 14:20
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30944 03/17/23 08:00
3860 mg/Kg - dry 100 660Aliphatic C5-C8 5000 03/17/23 18:55 V30945TBL
4920 mg/Kg - dry 376 660Aliphatic C9-C12 5000 03/17/23 18:55 V30945TBL
1670 mg/Kg - dry 51.5 660Aromatic C9-C10 5000 03/17/23 18:55 V30945TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)104 Limits: 70-130%03/17/23 18:555000 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)90.7 Limits: 70-130%03/17/23 18:555000 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 18 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:S
91223 Matrix:
3/14/2023 12:00
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
31.9 %Moisture 1 03/21/23 17:29 SW-DRYWTAMB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 19 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:S
91223 Matrix:
3/14/2023 12:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30900 03/16/23 08:00
<0.881 mg/Kg - dry 0.881 7.34Acetone 500 03/16/23 14:57 V30901TBL
<0.444 mg/Kg - dry 0.444 7.34Acrolein 500 03/16/23 14:57 V30901TBL
<0.276 mg/Kg - dry 0.276 7.34Acrylonitrile 500 03/16/23 14:57 V30901TBL
3.07 mg/Kg - dry 0.212 1.84Benzene 500 03/16/23 14:57 V30901TBL
<0.183 mg/Kg - dry 0.183 1.84Bromobenzene 500 03/16/23 14:57 V30901TBL
<0.293 mg/Kg - dry 0.293 1.84Bromochloromethane 500 03/16/23 14:57 V30901TBL
<0.437 mg/Kg - dry 0.437 1.84Bromodichloromethane 500 03/16/23 14:57 V30901TBL
<0.371 mg/Kg - dry 0.371 1.84Bromoform 500 03/16/23 14:57 V30901TBL
<0.668 mg/Kg - dry 0.668 3.67
Bromomethane 500 03/16/23 14:57 V30901TBL
11.8 mg/Kg - dry 0.180 1.84n-Butylbenzene 500 03/16/23 14:57 V30901TBL
4.21 mg/Kg - dry 0.205 1.84sec-Butyl benzene 500 03/16/23 14:57 V30901TBL
<0.183 mg/Kg - dry 0.183 1.84tert-Butyl benzene 500 03/16/23 14:57 V30901TBL
<0.234 mg/Kg - dry 0.234 1.84Carbon Disulfide 500 03/16/23 14:57 V30901TBL
<0.580 mg/Kg - dry 0.580 1.84Carbon Tetrachloride 500 03/16/23 14:57 V30901TBL
<0.246 mg/Kg - dry 0.246 1.84Chlorobenzene 500 03/16/23 14:57 V30901TBL
<0.327 mg/Kg - dry 0.327 1.84
Chlorodibromomethane 500 03/16/23 14:57 V30901TBL
<0.327 mg/Kg - dry 0.327 3.67Chloroethane 500 03/16/23 14:57 V30901TBL
<0.386 mg/Kg - dry 0.386 1.84Chloroform 500 03/16/23 14:57 V30901TBL
<0.232 mg/Kg - dry 0.232 3.67Chloromethane 500 03/16/23 14:57 V30901TBL
<0.187 mg/Kg - dry 0.187 1.842-Chlorotoluene 500 03/16/23 14:57 V30901TBL
<0.143 mg/Kg - dry 0.143 1.844-Chlorotoluene 500 03/16/23 14:57 V30901TBL
<0.268 mg/Kg - dry 0.268 1.84Di-Isopropyl Ether (DIPE)500 03/16/23 14:57 V30901TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 20 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:S
91223 Matrix:
3/14/2023 12:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30900 03/16/23 08:00
<0.161 mg/Kg - dry 0.161 3.671,2-Dibromo-3-Chloropropane 500 03/16/23 14:57 V30901TBL
<0.217 mg/Kg - dry 0.217 1.841,2-Dibromoethane 500 03/16/23 14:57 V30901TBL
<0.364 mg/Kg - dry 0.364 1.84Dibromomethane 500 03/16/23 14:57 V30901TBL
<0.113 mg/Kg - dry 0.113 1.841,2-Dichlorobenzene 500 03/16/23 14:57 V30901TBL
<0.139 mg/Kg - dry 0.139 1.841,3-Dichlorobenzene 500 03/16/23 14:57 V30901TBL
<0.220 mg/Kg - dry 0.220 1.841,4-Dichlorobenzene 500 03/16/23 14:57 V30901TBL
<0.484 mg/Kg - dry 0.484 3.67Dichlorodifluoromethane 500 03/16/23 14:57 V30901TBL
<0.301 mg/Kg - dry 0.301 1.841,1-Dichloroethane 500 03/16/23 14:57 V30901TBL
<0.506 mg/Kg - dry 0.506 1.84
1,2-Dichloroethane 500 03/16/23 14:57 V30901TBL
<0.268 mg/Kg - dry 0.268 1.841,1-Dichloroethene 500 03/16/23 14:57 V30901TBL
<0.290 mg/Kg - dry 0.290 1.84cis-1,2-Dichloroethene 500 03/16/23 14:57 V30901TBL
<0.386 mg/Kg - dry 0.386 1.84trans-1,2-Dichloroethene 500 03/16/23 14:57 V30901TBL
<0.161 mg/Kg - dry 0.161 1.841,2-Dichloropropane 500 03/16/23 14:57 V30901TBL
<0.202 mg/Kg - dry 0.202 1.841,3-Dichloropropane 500 03/16/23 14:57 V30901TBL
<0.466 mg/Kg - dry 0.466 1.842,2-Dichloropropane 500 03/16/23 14:57 V30901TBL
<0.279 mg/Kg - dry 0.279 1.84
1,1-Dichloropropene 500 03/16/23 14:57 V30901TBL
<0.198 mg/Kg - dry 0.198 1.84cis-1,3-Dichloropropene 500 03/16/23 14:57 V30901TBL
<0.293 mg/Kg - dry 0.293 1.84trans-1,3-Dichloropropene 500 03/16/23 14:57 V30901TBL
69.2 mg/Kg - dry 0.212 1.84Ethylbenzene 500 03/16/23 14:57 V30901TBL
<0.305 mg/Kg - dry 0.305 36.7Ethyl Tertiary Butyl Ether (ETBE)500 03/16/23 14:57 V30901TBL
<0.290 mg/Kg - dry 0.290 3.67Hexachlorobutadiene 500 03/16/23 14:57 V30901TBL
16.7 mg/Kg - dry 0.242 3.67n-Hexane 500 03/16/23 14:57 V30901TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 21 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:S
91223 Matrix:
3/14/2023 12:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30900 03/16/23 08:00
<0.227 mg/Kg - dry 0.227 7.342-Hexanone 500 03/16/23 14:57 V30901TBL
9.60 mg/Kg - dry 0.168 1.84Isopropylbenzene 500 03/16/23 14:57 V30901TBL
2.09 mg/Kg - dry 0.477 1.844-Isopropyl toluene 500 03/16/23 14:57 V30901TBL
<0.239 mg/Kg - dry 0.239 7.34Methyl Ethyl Ketone (MEK)500 03/16/23 14:57 V30901TBL
<0.227 mg/Kg - dry 0.227 1.84Methyl tert-butyl ether (MTBE)500 03/16/23 14:57 V30901TBL
<5.51 mg/Kg - dry 5.51 7.344-Methyl-2-Pentanone 500 03/16/23 14:57 V30901TBL
1.29 J mg/Kg - dry 0.540 1.84Methylene Chloride 500 03/16/23 14:57 V30901TBL
33.2 mg/Kg - dry 0.364 3.67Naphthalene 500 03/16/23 14:57 V30901TBL
37.4 mg/Kg - dry 0.198 1.84
n-Propylbenzene 500 03/16/23 14:57 V30901TBL
0.521 J mg/Kg - dry 0.521 1.84Styrene 500 03/16/23 14:57 V30901TBL
<0.386 mg/Kg - dry 0.386 1.841,1,1,2-Tetrachloroethane 500 03/16/23 14:57 V30901TBL
<0.117 mg/Kg - dry 0.117 1.841,1,2,2-Tetrachloroethane 500 03/16/23 14:57 V30901TBL
<0.330 mg/Kg - dry 0.330 1.84Tetrachloroethene 500 03/16/23 14:57 V30901TBL
111 mg/Kg - dry 0.242 1.84Toluene 500 03/16/23 14:57 V30901TBL
<0.198 mg/Kg - dry 0.198 3.671,2,3-Trichlorobenzene 500 03/16/23 14:57 V30901TBL
<0.234 mg/Kg - dry 0.234 3.67
1,2,4-Trichlorobenzene 500 03/16/23 14:57 V30901TBL
<0.528 mg/Kg - dry 0.528 1.841,1,1-Trichloroethane 500 03/16/23 14:57 V30901TBL
<0.173 mg/Kg - dry 0.173 1.841,1,2-Trichloroethane 500 03/16/23 14:57 V30901TBL
<0.337 mg/Kg - dry 0.337 1.84Trichloroethene 500 03/16/23 14:57 V30901TBL
<0.767 mg/Kg - dry 0.767 3.67Trichlorofluoromethane 500 03/16/23 14:57 V30901TBL
<0.264 mg/Kg - dry 0.264 1.841,2,3-Trichloropropane 500 03/16/23 14:57 V30901TBL
267 mg/Kg - dry 1.81 18.41,2,4-Trimethylbenzene 5000 03/16/23 15:24 V30901TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 22 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:S
91223 Matrix:
3/14/2023 12:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30900 03/16/23 08:00
70.2 mg/Kg - dry 0.198 1.841,3,5-Trimethylbenzene 500 03/16/23 14:57 V30901TBL
<0.168 mg/Kg - dry 0.168 3.67Vinyl Acetate 500 03/16/23 14:57 V30901TBL
<0.176 mg/Kg - dry 0.176 3.67Vinyl Chloride 500 03/16/23 14:57 V30901TBL
120 mg/Kg - dry 0.183 1.84o-Xylene 500 03/16/23 14:57 V30901TBL
257 mg/Kg - dry 0.462 3.67m,p-Xylene 500 03/16/23 14:57 V30901TBL
377 mg/Kg - dry 0.183 1.84Xylene (Total)500 03/16/23 14:57 V30901
Surrogate: 4-Bromofluorobenzene 96.6 Limits: 70-130%03/16/23 14:57500 TBL V30901
Surrogate: Dibromofluoromethane 99.0 Limits: 70-130%03/16/23 14:57500 TBL V30901
Surrogate: Toluene-d8 95.6 Limits: 76-129%03/16/23 14:57500 TBL V30901
Surrogate: 4-Bromofluorobenzene 99.4 Limits: 70-130%03/16/23 15:245000 TBL V30901
Surrogate: Dibromofluoromethane 96.0 Limits: 70-130%03/16/23 15:245000 TBL V30901
Surrogate: Toluene-d8 95.4 Limits: 76-129%03/16/23 15:245000 TBL V30901
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 23 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:S
91223 Matrix:
3/14/2023 12:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30944 03/17/23 08:00
267 mg/Kg - dry 8.93 58.7Aliphatic C5-C8 500 03/17/23 16:31 V30945TBL
564 mg/Kg - dry 33.5 58.7Aliphatic C9-C12 500 03/17/23 16:31 V30945TBL
239 mg/Kg - dry 4.58 58.7Aromatic C9-C10 500 03/17/23 16:31 V30945TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)114 Limits: 70-130%03/17/23 16:31500 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)94.4 Limits: 70-130%03/17/23 16:31500 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 24 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:W
91224 Matrix:
3/14/2023 15:00
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
35.5 %Moisture 1 03/21/23 17:29 SW-DRYWTAMB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 25 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:W
91224 Matrix:
3/14/2023 15:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30900 03/16/23 08:00
<0.930 mg/Kg - dry 0.930 7.75Acetone 500 03/16/23 15:52 V30901TBL
<0.469 mg/Kg - dry 0.469 7.75Acrolein 500 03/16/23 15:52 V30901TBL
<0.291 mg/Kg - dry 0.291 7.75Acrylonitrile 500 03/16/23 15:52 V30901TBL
41.1 mg/Kg - dry 0.224 1.94Benzene 500 03/16/23 15:52 V30901TBL
<0.193 mg/Kg - dry 0.193 1.94Bromobenzene 500 03/16/23 15:52 V30901TBL
<0.310 mg/Kg - dry 0.310 1.94Bromochloromethane 500 03/16/23 15:52 V30901TBL
<0.462 mg/Kg - dry 0.462 1.94Bromodichloromethane 500 03/16/23 15:52 V30901TBL
<0.392 mg/Kg - dry 0.392 1.94Bromoform 500 03/16/23 15:52 V30901TBL
<0.705 mg/Kg - dry 0.705 3.88
Bromomethane 500 03/16/23 15:52 V30901TBL
17.7 mg/Kg - dry 0.190 1.94n-Butylbenzene 500 03/16/23 15:52 V30901TBL
6.12 mg/Kg - dry 0.217 1.94sec-Butyl benzene 500 03/16/23 15:52 V30901TBL
<0.193 mg/Kg - dry 0.193 1.94tert-Butyl benzene 500 03/16/23 15:52 V30901TBL
<0.248 mg/Kg - dry 0.248 1.94Carbon Disulfide 500 03/16/23 15:52 V30901TBL
<0.612 mg/Kg - dry 0.612 1.94Carbon Tetrachloride 500 03/16/23 15:52 V30901TBL
<0.260 mg/Kg - dry 0.260 1.94Chlorobenzene 500 03/16/23 15:52 V30901TBL
<0.345 mg/Kg - dry 0.345 1.94
Chlorodibromomethane 500 03/16/23 15:52 V30901TBL
<0.345 mg/Kg - dry 0.345 3.88Chloroethane 500 03/16/23 15:52 V30901TBL
<0.407 mg/Kg - dry 0.407 1.94Chloroform 500 03/16/23 15:52 V30901TBL
<0.244 mg/Kg - dry 0.244 3.88Chloromethane 500 03/16/23 15:52 V30901TBL
<0.198 mg/Kg - dry 0.198 1.942-Chlorotoluene 500 03/16/23 15:52 V30901TBL
<0.151 mg/Kg - dry 0.151 1.944-Chlorotoluene 500 03/16/23 15:52 V30901TBL
<0.283 mg/Kg - dry 0.283 1.94Di-Isopropyl Ether (DIPE)500 03/16/23 15:52 V30901TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 26 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:W
91224 Matrix:
3/14/2023 15:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30900 03/16/23 08:00
<0.170 mg/Kg - dry 0.170 3.881,2-Dibromo-3-Chloropropane 500 03/16/23 15:52 V30901TBL
<0.229 mg/Kg - dry 0.229 1.941,2-Dibromoethane 500 03/16/23 15:52 V30901TBL
<0.384 mg/Kg - dry 0.384 1.94Dibromomethane 500 03/16/23 15:52 V30901TBL
<0.120 mg/Kg - dry 0.120 1.941,2-Dichlorobenzene 500 03/16/23 15:52 V30901TBL
<0.147 mg/Kg - dry 0.147 1.941,3-Dichlorobenzene 500 03/16/23 15:52 V30901TBL
<0.232 mg/Kg - dry 0.232 1.941,4-Dichlorobenzene 500 03/16/23 15:52 V30901TBL
<0.511 mg/Kg - dry 0.511 3.88Dichlorodifluoromethane 500 03/16/23 15:52 V30901TBL
<0.317 mg/Kg - dry 0.317 1.941,1-Dichloroethane 500 03/16/23 15:52 V30901TBL
<0.534 mg/Kg - dry 0.534 1.94
1,2-Dichloroethane 500 03/16/23 15:52 V30901TBL
<0.283 mg/Kg - dry 0.283 1.941,1-Dichloroethene 500 03/16/23 15:52 V30901TBL
<0.306 mg/Kg - dry 0.306 1.94cis-1,2-Dichloroethene 500 03/16/23 15:52 V30901TBL
<0.407 mg/Kg - dry 0.407 1.94trans-1,2-Dichloroethene 500 03/16/23 15:52 V30901TBL
<0.170 mg/Kg - dry 0.170 1.941,2-Dichloropropane 500 03/16/23 15:52 V30901TBL
<0.213 mg/Kg - dry 0.213 1.941,3-Dichloropropane 500 03/16/23 15:52 V30901TBL
<0.493 mg/Kg - dry 0.493 1.942,2-Dichloropropane 500 03/16/23 15:52 V30901TBL
<0.294 mg/Kg - dry 0.294 1.94
1,1-Dichloropropene 500 03/16/23 15:52 V30901TBL
<0.209 mg/Kg - dry 0.209 1.94cis-1,3-Dichloropropene 500 03/16/23 15:52 V30901TBL
<0.310 mg/Kg - dry 0.310 1.94trans-1,3-Dichloropropene 500 03/16/23 15:52 V30901TBL
205 mg/Kg - dry 2.25 19.4Ethylbenzene 5000 03/16/23 16:19 V30901TBL
<0.322 mg/Kg - dry 0.322 38.8Ethyl Tertiary Butyl Ether (ETBE)500 03/16/23 15:52 V30901TBL
<0.306 mg/Kg - dry 0.306 3.88Hexachlorobutadiene 500 03/16/23 15:52 V30901TBL
132 mg/Kg - dry 0.255 3.88n-Hexane 500 03/16/23 15:52 V30901TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 27 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:W
91224 Matrix:
3/14/2023 15:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30900 03/16/23 08:00
<0.240 mg/Kg - dry 0.240 7.752-Hexanone 500 03/16/23 15:52 V30901TBL
18.4 mg/Kg - dry 0.178 1.94Isopropylbenzene 500 03/16/23 15:52 V30901TBL
3.24 mg/Kg - dry 0.503 1.944-Isopropyl toluene 500 03/16/23 15:52 V30901TBL
<0.252 mg/Kg - dry 0.252 7.75Methyl Ethyl Ketone (MEK)500 03/16/23 15:52 V30901TBL
<0.240 mg/Kg - dry 0.240 1.94Methyl tert-butyl ether (MTBE)500 03/16/23 15:52 V30901TBL
<5.81 mg/Kg - dry 5.81 7.754-Methyl-2-Pentanone 500 03/16/23 15:52 V30901TBL
1.74 J mg/Kg - dry 0.570 1.94Methylene Chloride 500 03/16/23 15:52 V30901TBL
46.8 mg/Kg - dry 0.384 3.88Naphthalene 500 03/16/23 15:52 V30901TBL
70.1 mg/Kg - dry 0.209 1.94
n-Propylbenzene 500 03/16/23 15:52 V30901TBL
1.84 J mg/Kg - dry 0.550 1.94Styrene 500 03/16/23 15:52 V30901TBL
<0.407 mg/Kg - dry 0.407 1.941,1,1,2-Tetrachloroethane 500 03/16/23 15:52 V30901TBL
<0.124 mg/Kg - dry 0.124 1.941,1,2,2-Tetrachloroethane 500 03/16/23 15:52 V30901TBL
<0.348 mg/Kg - dry 0.348 1.94Tetrachloroethene 500 03/16/23 15:52 V30901TBL
642 mg/Kg - dry 2.56 19.4Toluene 5000 03/16/23 16:19 V30901TBL
<0.209 mg/Kg - dry 0.209 3.881,2,3-Trichlorobenzene 500 03/16/23 15:52 V30901TBL
<0.248 mg/Kg - dry 0.248 3.88
1,2,4-Trichlorobenzene 500 03/16/23 15:52 V30901TBL
<0.558 mg/Kg - dry 0.558 1.941,1,1-Trichloroethane 500 03/16/23 15:52 V30901TBL
<0.182 mg/Kg - dry 0.182 1.941,1,2-Trichloroethane 500 03/16/23 15:52 V30901TBL
<0.356 mg/Kg - dry 0.356 1.94Trichloroethene 500 03/16/23 15:52 V30901TBL
<0.810 mg/Kg - dry 0.810 3.88Trichlorofluoromethane 500 03/16/23 15:52 V30901TBL
<0.279 mg/Kg - dry 0.279 1.941,2,3-Trichloropropane 500 03/16/23 15:52 V30901TBL
434 mg/Kg - dry 1.91 19.41,2,4-Trimethylbenzene 5000 03/16/23 16:19 V30901TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 28 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:W
91224 Matrix:
3/14/2023 15:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30900 03/16/23 08:00
118 mg/Kg - dry 0.209 1.941,3,5-Trimethylbenzene 500 03/16/23 15:52 V30901TBL
<0.178 mg/Kg - dry 0.178 3.88Vinyl Acetate 500 03/16/23 15:52 V30901TBL
<0.186 mg/Kg - dry 0.186 3.88Vinyl Chloride 500 03/16/23 15:52 V30901TBL
305 mg/Kg - dry 1.94 19.4o-Xylene 5000 03/16/23 16:19 V30901TBL
729 mg/Kg - dry 4.88 38.8m,p-Xylene 5000 03/16/23 16:19 V30901TBL
1030 mg/Kg - dry 1.94 19.4Xylene (Total)5000 03/16/23 16:19 V30901
Surrogate: 4-Bromofluorobenzene 97.2 Limits: 70-130%03/16/23 15:52500 TBL V30901
Surrogate: Dibromofluoromethane 96.8 Limits: 70-130%03/16/23 15:52500 TBL V30901
Surrogate: Toluene-d8 97.0 Limits: 76-129%03/16/23 15:52500 TBL V30901
Surrogate: 4-Bromofluorobenzene 98.8 Limits: 70-130%03/16/23 16:195000 TBL V30901
Surrogate: Dibromofluoromethane 98.2 Limits: 70-130%03/16/23 16:195000 TBL V30901
Surrogate: Toluene-d8 96.2 Limits: 76-129%03/16/23 16:195000 TBL V30901
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 29 of 40
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27361
23-074-0012
01156
Paragon Environmental Consultants, Inc.
PO Box 157
Brandon Moore
Thomasville
P-800 Received : 03/15/2023
Cohen's Citgo (Pop Shoppe #233)
Report Date : 03/24/2023
Sample ID :
Lab No :
Sampled:W
91224 Matrix:
3/14/2023 15:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30944 03/17/23 08:00
1000 mg/Kg - dry 94.3 620Aliphatic C5-C8 5000 03/17/23 18:07 V30945TBL
972 mg/Kg - dry 35.3 62.0Aliphatic C9-C12 500 03/17/23 17:19 V30945TBL
479 mg/Kg - dry 4.84 62.0Aromatic C9-C10 500 03/17/23 17:19 V30945TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)89.8 Limits: 70-130%03/17/23 17:19500 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)89.0 Limits: 70-130%03/17/23 17:19500 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)118 Limits: 70-130%03/17/23 18:075000 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)119 Limits: 70-130%03/17/23 18:075000 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 30 of 40
Quality Control Data
23-074-0012Report No:
Project Description:
Client ID:Paragon Environmental Consultants, Inc.
Cohen's Citgo (Pop Shoppe #233)
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V30901QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V30900
Associated Lab Samples: 91221, 91222, 91223, 91224
LRB-V30900 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/16/23 11:200.0200.002<0.002mg/KgAcetone
03/16/23 11:200.0200.001<0.001mg/KgAcrolein
03/16/23 11:200.0200.0008<0.0008mg/KgAcrylonitrile
03/16/23 11:200.0050.0006<0.0006mg/KgBenzene
03/16/23 11:200.0050.0005<0.0005mg/KgBromobenzene
03/16/23 11:200.0050.0008<0.0008mg/KgBromochloromethane
03/16/23 11:200.0050.001<0.001mg/KgBromodichloromethane
03/16/23 11:200.0050.001<0.001mg/KgBromoform
03/16/23 11:200.0100.001<0.001mg/KgBromomethane
03/16/23 11:200.0050.0005<0.0005mg/Kgn-Butylbenzene
03/16/23 11:200.0050.0006<0.0006mg/Kgsec-Butyl benzene
03/16/23 11:200.0050.0005<0.0005mg/Kgtert-Butyl benzene
03/16/23 11:200.0050.0006<0.0006mg/KgCarbon Disulfide
03/16/23 11:200.0050.001<0.001mg/KgCarbon Tetrachloride
03/16/23 11:200.0050.0007<0.0007mg/KgChlorobenzene
03/16/23 11:200.0050.0009<0.0009mg/KgChlorodibromomethane
03/16/23 11:200.0100.0009<0.0009mg/KgChloroethane
03/16/23 11:200.0050.001<0.001mg/KgChloroform
03/16/23 11:200.0100.0006<0.0006mg/KgChloromethane
03/16/23 11:200.0050.0005<0.0005mg/Kg2-Chlorotoluene
03/16/23 11:200.0050.0004<0.0004mg/Kg4-Chlorotoluene
03/16/23 11:200.0050.0007<0.0007mg/KgDi-Isopropyl Ether (DIPE)
03/16/23 11:200.0100.0004<0.0004mg/Kg1,2-Dibromo-3-Chloropropane
03/16/23 11:200.0050.0006<0.0006mg/Kg1,2-Dibromoethane
03/16/23 11:200.0050.0010<0.0010mg/KgDibromomethane
03/16/23 11:200.0050.0003<0.0003mg/Kg1,2-Dichlorobenzene
03/16/23 11:200.0050.0004<0.0004mg/Kg1,3-Dichlorobenzene
Page 1 of 8Date:03/24/2023 12:08 PM
Page 31 of 40
Quality Control Data
23-074-0012Report No:
Project Description:
Client ID:Paragon Environmental Consultants, Inc.
Cohen's Citgo (Pop Shoppe #233)
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V30901QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V30900
Associated Lab Samples: 91221, 91222, 91223, 91224
LRB-V30900 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/16/23 11:200.0050.0006<0.0006mg/Kg1,4-Dichlorobenzene
03/16/23 11:200.0100.001<0.001mg/KgDichlorodifluoromethane
03/16/23 11:200.0050.0008<0.0008mg/Kg1,1-Dichloroethane
03/16/23 11:200.0050.001<0.001mg/Kg1,2-Dichloroethane
03/16/23 11:200.0050.0007<0.0007mg/Kg1,1-Dichloroethene
03/16/23 11:200.0050.0008<0.0008mg/Kgcis-1,2-Dichloroethene
03/16/23 11:200.0050.001<0.001mg/Kgtrans-1,2-Dichloroethene
03/16/23 11:200.0050.0004<0.0004mg/Kg1,2-Dichloropropane
03/16/23 11:200.0050.0006<0.0006mg/Kg1,3-Dichloropropane
03/16/23 11:200.0050.001<0.001mg/Kg2,2-Dichloropropane
03/16/23 11:200.0050.0008<0.0008mg/Kg1,1-Dichloropropene
03/16/23 11:200.0050.0005<0.0005mg/Kgcis-1,3-Dichloropropene
03/16/23 11:200.0050.0008<0.0008mg/Kgtrans-1,3-Dichloropropene
03/16/23 11:200.0050.0006<0.0006mg/KgEthylbenzene
03/16/23 11:200.1000.0008<0.0008mg/KgEthyl Tertiary Butyl Ether (ETBE)
03/16/23 11:200.0100.0008<0.0008mg/KgHexachlorobutadiene
03/16/23 11:200.0100.0007<0.0007mg/Kgn-Hexane
03/16/23 11:200.0200.0006<0.0006mg/Kg2-Hexanone
03/16/23 11:200.0050.0005<0.0005mg/KgIsopropylbenzene
03/16/23 11:200.0050.001<0.001mg/Kg4-Isopropyl toluene
03/16/23 11:200.0200.0007<0.0007mg/KgMethyl Ethyl Ketone (MEK)
03/16/23 11:200.0050.0006<0.0006mg/KgMethyl tert-butyl ether (MTBE)
03/16/23 11:200.0050.0010.002mg/KgMethylene Chloride
03/16/23 11:200.0100.0010<0.0010mg/KgNaphthalene
03/16/23 11:200.0050.0005<0.0005mg/Kgn-Propylbenzene
03/16/23 11:200.0050.001<0.001mg/KgStyrene
03/16/23 11:200.0050.001<0.001mg/Kg1,1,1,2-Tetrachloroethane
Page 2 of 8Date:03/24/2023 12:08 PM
Page 32 of 40
Quality Control Data
23-074-0012Report No:
Project Description:
Client ID:Paragon Environmental Consultants, Inc.
Cohen's Citgo (Pop Shoppe #233)
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V30901QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V30900
Associated Lab Samples: 91221, 91222, 91223, 91224
LRB-V30900 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/16/23 11:200.0050.0003<0.0003mg/Kg1,1,2,2-Tetrachloroethane
03/16/23 11:200.0050.0009<0.0009mg/KgTetrachloroethene
03/16/23 11:200.0050.0007<0.0007mg/KgToluene
03/16/23 11:200.0100.0005<0.0005mg/Kg1,2,3-Trichlorobenzene
03/16/23 11:200.0100.0006<0.0006mg/Kg1,2,4-Trichlorobenzene
03/16/23 11:200.0050.001<0.001mg/Kg1,1,1-Trichloroethane
03/16/23 11:200.0050.0005<0.0005mg/Kg1,1,2-Trichloroethane
03/16/23 11:200.0050.0009<0.0009mg/KgTrichloroethene
03/16/23 11:200.0100.002<0.002mg/KgTrichlorofluoromethane
03/16/23 11:200.0050.0007<0.0007mg/Kg1,2,3-Trichloropropane
03/16/23 11:200.0050.0005<0.0005mg/Kg1,2,4-Trimethylbenzene
03/16/23 11:200.0050.0005<0.0005mg/Kg1,3,5-Trimethylbenzene
03/16/23 11:200.0100.0005<0.0005mg/KgVinyl Acetate
03/16/23 11:200.0100.0005<0.0005mg/KgVinyl Chloride
03/16/23 11:200.0050.0005<0.0005mg/Kgo-Xylene
03/16/23 11:200.0100.001<0.001mg/Kgm,p-Xylene
03/16/23 11:204-Bromofluorobenzene (S)100 70-130
03/16/23 11:20Dibromofluoromethane (S)104 70-130
03/16/23 11:20Toluene-d8 (S)95.2 76-129
LCS-V30900 LCSD-V30900Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.128 1281330.1330.100mg/KgAcetone 29-198 3.8 20
0.098 98.698.90.0980.100mg/KgAcrolein 70-130 0.3 20
0.117 1171120.1120.100mg/KgAcrylonitrile 65-134 4.3 20
Page 3 of 8Date:03/24/2023 12:08 PM
Page 33 of 40
Quality Control Data
23-074-0012Report No:
Project Description:
Client ID:Paragon Environmental Consultants, Inc.
Cohen's Citgo (Pop Shoppe #233)
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V30901QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V30900
LCS-V30900 LCSD-V30900Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.048 96.496.40.0480.050mg/KgBenzene 74-127 0.0 20
0.044 89.084.80.0420.050mg/KgBromobenzene 73-125 4.8 20
0.052 1041060.0520.050mg/KgBromochloromethane 72-134 1.7 20
0.049 99.297.00.0480.050mg/KgBromodichloromethane 75-122 2.2 20
0.051 10297.00.0480.050mg/KgBromoform 66-135 5.0 20
0.046 92.290.20.0450.050mg/KgBromomethane 20-180 2.1 20
0.044 88.888.80.0440.050mg/Kgn-Butylbenzene 65-135 0.0 20
0.042 85.485.00.0420.050mg/Kgsec-Butyl benzene 66-131 0.4 20
0.043 87.486.60.0430.050mg/Kgtert-Butyl benzene 67-132 0.9 20
0.046 92.496.40.0480.050mg/KgCarbon Disulfide 61-129 4.2 20
0.046 93.698.00.0490.050mg/KgCarbon Tetrachloride 64-143 4.5 20
0.047 95.093.40.0460.050mg/KgChlorobenzene 74-118 1.6 20
0.048 96.094.80.0470.050mg/KgChlorodibromomethane 73-122 1.2 20
0.046 93.894.20.0470.050mg/KgChloroethane 33-149 0.4 20
0.047 95.897.00.0480.050mg/KgChloroform 73-127 1.2 20
0.047 94.492.80.0460.050mg/KgChloromethane 45-143 1.7 20
0.043 87.485.40.0420.050mg/Kg2-Chlorotoluene 67-124 2.3 20
0.043 87.285.20.0420.050mg/Kg4-Chlorotoluene 71-126 2.3 20
0.049 98.297.20.0480.050mg/KgDi-Isopropyl Ether (DIPE)59-159 1.0 20
0.047 94.690.20.0450.050mg/Kg1,2-Dibromo-3-Chloropropane 55-157 4.7 20
0.048 97.297.40.0480.050mg/Kg1,2-Dibromoethane 70-132 0.2 20
0.050 1011030.0510.050mg/KgDibromomethane 74-133 1.3 20
0.046 92.490.60.0450.050mg/Kg1,2-Dichlorobenzene 72-123 1.9 20
0.046 92.490.80.0450.050mg/Kg1,3-Dichlorobenzene 71-120 1.7 20
0.045 91.287.00.0430.050mg/Kg1,4-Dichlorobenzene 71-123 4.7 20
0.044 88.693.40.0460.050mg/KgDichlorodifluoromethane 26-146 5.2 20
Page 4 of 8Date:03/24/2023 12:08 PM
Page 34 of 40
Quality Control Data
23-074-0012Report No:
Project Description:
Client ID:Paragon Environmental Consultants, Inc.
Cohen's Citgo (Pop Shoppe #233)
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V30901QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V30900
LCS-V30900 LCSD-V30900Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.048 97.096.40.0480.050mg/Kg1,1-Dichloroethane 74-127 0.6 20
0.050 10197.20.0480.050mg/Kg1,2-Dichloroethane 68-128 3.4 20
0.047 94.096.20.0480.050mg/Kg1,1-Dichloroethene 67-149 2.3 20
0.049 99.897.80.0480.050mg/Kgcis-1,2-Dichloroethene 76-134 2.0 20
0.047 94.896.80.0480.050mg/Kgtrans-1,2-Dichloroethene 73-132 2.0 20
0.049 98.699.60.0490.050mg/Kg1,2-Dichloropropane 73-130 1.0 20
0.049 98.296.80.0480.050mg/Kg1,3-Dichloropropane 75-124 1.4 20
0.047 94.299.00.0490.050mg/Kg2,2-Dichloropropane 50-142 4.9 20
0.047 95.695.60.0470.050mg/Kg1,1-Dichloropropene 71-130 0.0 20
0.050 1011050.0520.050mg/Kgcis-1,3-Dichloropropene 71-125 3.3 20
0.053 1081060.0520.050mg/Kgtrans-1,3-Dichloropropene 68-123 1.6 20
0.044 88.289.20.0440.050mg/KgEthylbenzene 74-128 1.1 20
0.100 10097.90.0970.100mg/KgEthyl Tertiary Butyl Ether (ETBE)70-130 2.1 20
0.045 91.291.20.0450.050mg/KgHexachlorobutadiene 64-125 0.0 20
0.046 93.495.40.0470.050mg/Kgn-Hexane 70-130 2.1 20
0.055 1121120.0560.050mg/Kg2-Hexanone 61-157 0.7 20
0.043 86.884.60.0420.050mg/KgIsopropylbenzene 68-126 2.5 20
0.043 87.287.80.0430.050mg/Kg4-Isopropyl toluene 68-129 0.6 20
0.052 1051080.0540.050mg/KgMethyl Ethyl Ketone (MEK)63-149 2.4 20
0.050 1011000.0500.050mg/KgMethyl tert-butyl ether (MTBE)70-130 0.7 20
0.045 91.090.40.0450.050mg/KgMethylene Chloride 74-129 0.6 20
0.050 10196.00.0480.050mg/KgNaphthalene 57-157 4.6 20
0.042 84.885.60.0420.050mg/Kgn-Propylbenzene 67-130 0.9 20
0.047 95.495.40.0470.050mg/KgStyrene 77-121 0.0 20
0.047 94.694.60.0470.050mg/Kg1,1,1,2-Tetrachloroethane 72-115 0.0 20
0.044 89.287.40.0430.050mg/Kg1,1,2,2-Tetrachloroethane 56-126 2.0 20
Page 5 of 8Date:03/24/2023 12:08 PM
Page 35 of 40
Quality Control Data
23-074-0012Report No:
Project Description:
Client ID:Paragon Environmental Consultants, Inc.
Cohen's Citgo (Pop Shoppe #233)
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V30901QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V30900
LCS-V30900 LCSD-V30900Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.050 1001030.0510.050mg/KgTetrachloroethene 68-130 3.3 20
0.047 94.296.40.0480.050mg/KgToluene 71-129 2.3 20
0.048 97.693.80.0460.050mg/Kg1,2,3-Trichlorobenzene 68-130 3.9 20
0.048 97.01010.0500.050mg/Kg1,2,4-Trichlorobenzene 66-125 3.6 20
0.046 93.897.00.0480.050mg/Kg1,1,1-Trichloroethane 67-131 3.3 20
0.046 92.693.60.0460.050mg/Kg1,1,2-Trichloroethane 70-133 1.0 20
0.050 10097.80.0480.050mg/KgTrichloroethene 75-133 2.2 20
0.044 89.893.80.0460.050mg/KgTrichlorofluoromethane 44-146 4.3 20
0.045 90.692.80.0460.050mg/Kg1,2,3-Trichloropropane 60-137 2.3 20
0.044 88.687.40.0430.050mg/Kg1,2,4-Trimethylbenzene 69-129 1.3 20
0.043 86.085.40.0420.050mg/Kg1,3,5-Trimethylbenzene 69-128 0.7 20
0.058 1181140.0560.050mg/KgVinyl Acetate 60-140 3.2 20
0.044 89.692.20.0460.050mg/KgVinyl Chloride 48-147 2.8 20
0.046 93.491.40.0450.050mg/Kgo-Xylene 74-126 2.1 20
0.090 90.892.10.0920.100mg/Kgm,p-Xylene 75-124 1.4 20
10197.24-Bromofluorobenzene (S)70-130
99.8100Dibromofluoromethane (S)70-130
95.695.2Toluene-d8 (S)76-129
Page 6 of 8Date:03/24/2023 12:08 PM
Page 36 of 40
Quality Control Data
23-074-0012Report No:
Project Description:
Client ID:Paragon Environmental Consultants, Inc.
Cohen's Citgo (Pop Shoppe #233)
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V30945QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V30944
Associated Lab Samples: 91221, 91222, 91223, 91224
LRB-V30944 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/17/23 13:198.001.22<1.22mg/KgAliphatic C5-C8
03/17/23 13:198.004.56<4.56mg/KgAliphatic C9-C12
03/17/23 13:198.000.624<0.624mg/KgAromatic C9-C10
03/17/23 13:192,5-Dibromotoluene (FID) (S)97.1 70-130
03/17/23 13:192,5-Dibromotoluene (PID) (S)92.2 70-130
LCS-V30944 LCSD-V30944Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
31.5 98.494.030.132.0mg/KgAliphatic C5-C8 70-130 4.5 50
37.9 11812238.932.0mg/KgAliphatic C9-C12 70-130 2.6 50
12.0 11210911.710.7mg/KgAromatic C9-C10 70-130 2.5 50
87.589.72,5-Dibromotoluene (FID) (S)70-130
80.977.72,5-Dibromotoluene (PID) (S)70-130
Page 7 of 8Date:03/24/2023 12:08 PM
Page 37 of 40
Quality Control Data
23-074-0012Report No:
Project Description:
Client ID:Paragon Environmental Consultants, Inc.
Cohen's Citgo (Pop Shoppe #233)
Dry Weight Determination
SW-DRYWT
V31042QC Analytical Batch:
Analysis Method:
Analysis Description:
V 91381-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 03/21/23 17:294.017.117.8%Moisture
V 91385-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 03/21/23 17:292.225.926.5%Moisture
Page 8 of 8Date:03/24/2023 12:08 PM
Page 38 of 40
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-074-0012
Paragon Environmental Consultants, Inc.
01156
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 3.5C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:03/15/2023 16:27:59
Special precautions or instructions included?
Comments:
Page 39 of 40
Page 40 of 40

APPENDIX C

STANDARD OPERATING PROCEDURES

STANDARD OPERATING PROCEDURES
PARAGON ENVIRONMENTAL CONSULTANTS, INC.

I. SOIL SAMPLE PROCEDURES
1. Collect all samples using disposable Latex gloves. Gloves are not to be re- used. 2. Place samples into laboratory supplied glassware following requirements for specific analysis. 3. Label samples with sample ID, date, time, and job number. Immediately place samples on ice or in refrigerator to be cooled to approximately 4 degrees Celsius. 4. Store all samples on ice or refrigerate until samples are delivered to the laboratory. 5. Complete a chain of custody record for samples to be submitted to laboratory. Sign and date the chain of custody when samples are relinquished in accordance with EPA chain of custody protocol. II. GROUNDWATER SAMPLING 1. Use new disposable bailer and new nylon string to develop well and collect sample. Handle bailer and string with Latex gloves. 2. Develop well by removing 3 well volumes of water. Dispose of water in accordance with NCDEQ guidelines. 3. Following well development obtain samples in laboratory supplied glassware following requirements for specific analysis. 4. Handle, store, and transport samples in same manner as for soil samples. See items I.3, I.4, and I.5 above. III. EQUIPMENT CONTAMINATION 1. Decontaminate augers, split spoons, and other sampling equipment by the following procedure: A. Soap and tap water wash B. Tap water rinse C. Distilled deionized water rinse D. Isopropyl alcohol rinse E. Distilled water rinse 2. Use new disposable sampling equipment whenever practical.
SOP

APPENDIX D

SOIL DISPOSAL MANIFESTS