WA-27532_38684_CA_LSA_20180710_Phase I

EXECUTIVE SUMMARY
The Handy Mart #61 site is an active petroleum retail facility, convenience store and Little Caesar’s restaurant
located at 4328 Highway 11 South, Winterville, Pitt County, North Carolina. The site is located within the town
limits of Winterville and zoned as general commercial use. Municipal water is available to the site and all
surrounding properties. One 10,000-gallon diesel, one 12,000-gallon gasoline, one 20,000-gallon gasoline
USTs, associated product piping and dispensers are in use at the site. In February 2018, during annual
compliance testing activities, a non-passing hydrostatic result was reported for the 20,000-gallon gasoline UST
spill bucket. On March 15, 2018, laboratory analysis of soil samples confirmed a release.

On May 21, 2018, a receptor survey was completed for this incident. No potable water supply wells were
identified within 1,000 feet of the site. One water supply well (WSW-1) was identified approximately 1,090
feet from the site. The owner of the WSW-1 advised that the well was inactive and had collapsed. No surface
water bodies are located within 500 feet of the site. The site is not located within a designated wellhead
protection area.

On May 17, 2018, a Type II monitoring well (MW-1) was installed in the vicinity of the 20,000-gallon gasoline
UST. One soil sample (MW-1(2’)) was collected during the installation of MW-1. No concentrations of
requested method constituents that exceed the Maximum Contaminant Concentrations were reported in MW-
1(2’). On May 17, 2018, a ground water sample was collected from MW-1. Concentrations of requested
method constituents that exceeded the applicable water quality standards were reported in the ground water
sample collected in May 2018.

Based on this information, the site risk classification should be ranked as Low Risk. Subsequent to filing a
Notice of Residual Petroleum for ground water on the site deed, no further assessment should be warranted for
the incident.

TABLE OF CONTENTS

A. RISK CHARACTERIZATION .................................................................................................... 1
B. RECEPTOR INFORMATION ..................................................................................................... 4
C. SITE GEOLOGY AND HYDROGEOLOGY .............................................................................. 5
D. SAMPLING RESULTS ................................................................................................................. 5
E. CONCLUSIONS AND RECOMMENDATIONS......................................................................... 6
F. LIMITATIONS ............................................................................................................................. 7

FIGURES
Figure 1: Site Location Map
Figure 2: Site Vicinity Map
Figure 3: Site Map
Figure 4: Soil Quality Map
Figure 5: Ground Water Quality Map

TABLES
Table 1: Water Supply Well Information
Table 2: Adjacent Property Owner Information
Table 3: Well Construction and Gauging Information
Table 4: Summary of Soil Sample Analytical Results
Table 5: Summary of Ground Water Sample Analytical Results

APPENDICIES
Appendix A: Well Construction Record
Appendix B: Laboratory Report - Soil and Ground Water Samples

1

A. RISK CHARACTERIZATION
The Handy Mart #61 site is an active petroleum retail facility, convenience store and Little Caesar’s
restaurant located at 4328 Highway 11 South, Winterville, Pitt County, North Carolina (Figure 1).
Limited Site Assessment Risk Classification and Land Use Form
Part I – Groundwater/Surface Water/Vapor Impacts
High Risk
1. Has the release contaminated any water supply well including any well used for non-drinking
purposes? UNKNOWN
2. Is a water supply well used for drinking water located within 1,000 feet of the source area of the
release? YES/NO
No potable water supply wells were identified within a 1,000-foot radius of the source area.
3. Is a water supply well not used for drinking water (e.g., irrigation, washing cars, industrial
cooling water, filling swimming pools) located within 250 feet of the source area of the release?
YES/NO
No water supply wells were identified within a 250-foot radius of the source area.
4. Does ground water within 500 feet of the source area of the release have the potential for future
use (there is no other source of water supply other than the groundwater)? YES/NO

5. Do vapors from the release pose a threat of explosion because of accumulation of the vapors in a
confined space or pose any other serious threat to public health, public safety or the environment?
YES/NO
6. Are there any other factors that would cause the release to pose an imminent danger to public
health, public safety, or the environment? YES/NO
If YES, explain:
Intermediate Risk
7. Is a surface water body located within 500 feet of the source area of the release? YES/NO

If YES, does the maximum groundwater contaminant concentration exceed the surface water
quality standards and criteria found in 15A NCAC 2B .0200 by a factor of 10? YES/NO

2

8. Is the source area of the release located within an approved or planned wellhead protection area
as defined in 42 USC 300h-7(e)? YES/NO
9. Is the release located in the Coastal Plain physiographic region as designated on a map entitled
“Geology of North Carolina” published by the Department in 1985? YES/NO
If YES, is the source area of the release located in an area in which there is recharge to an
unconfined or semi-confined deeper aquifer that is being used or may be used as a source of
drinking water? YES/NO
If YES, describe.
The source area is located in the surficial aquifer.
10. Do the levels of ground water contamination for any contaminant exceed the Gross
Contamination Levels established by the Department? YES/NO
Part II - Land Use
Property Containing Source Area of Release
The questions below pertain to the property containing the source area of the release.
1. Does the property contain one or more primary or secondary residences (permanent or
temporary)? YES/NO
Explain: The site currently operates as a petroleum retail, convenience store and Little
Caesar’s restaurant.
2. Does the property contain a school, daycare center, hospital, playground, park, recreation area,
church, nursing home, or other place of public assembly? YES/NO
Explain: The site currently operates as a petroleum retail, convenience store and Little
Caesar’s restaurant.
3. Does the property contain a commercial (e.g., retail, warehouse, office/business space, etc.) or
industrial (e.g., manufacturing, utilities, industrial research and development, chemical/petroleum
bulk storage, etc.) enterprise, an inactive commercial or industrial enterprise, or is the land
undeveloped? YES/NO
Explain:
The site currently operates as a petroleum retail, convenience store and Little Caesar’s restaurant.
4. Do children visit the property? YES/NO
Explain:
Children could visit the property as vehicular or pedestrian traffic.
5. Is access to the property reliably restricted consistent with its use (e.g., by fences, security

3

personnel or both)? YES/NO
Explain:
No fences or security personnel were observed during site activities.
6. Do pavement, buildings, or other structures cap the contaminated soil? YES/NO
Explain:
Asphalt covers the parking lot along with concrete surface cover around USTs and dispensers; the
remaining area is capped by the store building.
If yes, what mechanisms are in place or can be put into place to ensure that the contaminated soil
will remain capped in the foreseeable future?
The site is an active convenience store and will remain so in the foreseeable future.
7. What is the zoning status of the property?
According to the available zoning information, the site is zoned general commercial.
8. Is the use of the property likely to change in the next 20 years? YES/NO
Explain: There is no foreseeable change in ownership or use of the property
Property Surrounding Source Area of Release
The questions below pertain to the area within 1,500 feet of the source area of the release (excludes
property containing source area of the release):
9. What is the distance from the source area of the release to the nearest primary or secondary
residence (permanent or temporary)?
The closest primary residence is approximately 600 feet away
10. What is the distance from the source area of the release to the nearest school, daycare center,
hospital, playground, park, recreation area, church, nursing home or other place of public
assembly?
The Winterville Assembly of God church is approximately 1,100 feet north east of the site.
11. What is the zoning status of properties in the surrounding area?
According to the available zoning information, the surrounding areas are commercial and
residential.

4

12. Briefly characterize the use and activities of the land in the surrounding area.
The area surrounding the site is zoned general commercial and residential. They consist of retail
facilities and residential properties.

B. RECEPTOR INFORMATION
1. Water Supply Wells:
One water supply well (WSW-1) was identified during May 2018 receptor survey activities. No
potable water supply wells were identified within 1,000 feet of the site. The owner of WSW-1
confirmed that the well was inactive and had collapsed. Water supply well owner information is
presented in Table 1. The location of WSW-1 is shown on Figure 2.
2. Public Water Supplies:
Are public water supplies available within 1,500 feet of the source area of the release? YES/NO
If yes, where is the location of the nearest public water lines and the source(s) of the public water
supply? Explain:
Public water is available to the site and all of the surrounding properties. Water lines run along
the public streets in the area.
3. Surface Water:
Identify all surface water bodies (e.g., ditch, pond, stream, lake, river) within 1,500 feet of the
source area of the release. This information must be shown on the USGS topographic map.
Several small ponds are located at distances greater than 500 feet from the site.
4. Wellhead Protection Areas:
Identify all planned or approved wellhead protection areas (e.g., ditch, pond, stream, lake, river)
within 1,500 feet of the source area of the release. This information must be shown on the USGS
topographic map. Wellhead protection areas are defined in 42 USC 300h-7(e).
No wellhead protection areas were identified within a 1,500-foot radius of the site.
5. Deep Aquifers in the Coastal Plain Physiographic Region:
The site is located in the Coastal Plain Region of North Carolina. The source area is located in
the surficial aquifer.

5

6. Subsurface Structures:
No structures with basements were observed in the vicinity of the source area.
7. Property Owners and Occupants:
The names and addresses of the owners of properties adjacent to the site are presented in Table 2.
Property boundaries are shown on Figure 2.

C. SITE GEOLOGY AND HYDROGEOLOGY
According to the 1985 Geologic Map of North Carolina, the site is located in the Coastal Plain
Physiographic Province of North Carolina. The Coastal Plain is part of an extensive geologic
province that roughly parallels the Atlantic Ocean and continues northward and southward through
the neighboring states. The site is located within the Quaternary Undivided Surficial Deposits
Formation. The surficial aquifer at the site overlies the Peedee Formation. Soil encountered during
the Limited Site Assessment activities was primarily fine to medium sand.

On May 17, 2018, one Type II monitoring well (MW-1) was installed at the site to a total depth of
twelve feet below ground surface. The well was completed with a ten-foot screened interval set to
bracket the water table at the time of installation. The well was installed adjacent to the failed spill
bucket associated with the 20,000-gallon gasoline UST.

On May 17, 2018, depth to water in MW-1 was 2.81 feet below the top of well casing. A Site Map is
included as Figure 3. A well construction record is included as Appendix A. Well construction and
gauging information is presented in Table 3.

D. SAMPLING RESULTS
1. Soil Sampling:
On May 17, 2018, on soil sample (MW-1(2’)) was collected during the installation of MW-1. The
collected soil sample was submitted for laboratory analysis by EPA Methods 8260 and by MADEP
Method VPH. None of the reported contaminant concentrations exceeded the Maximum
Contaminant Concentrations (MCCs). A summary of soil sample analytical results is presented in
Table 4. A map showing the locations of the soil samples and soil quality information is included as
Figure 4. A complete laboratory report for the soil sample collected in May 2018 is included as

6

Appendix B.

2. Ground Water Sampling:
On May 17, 2018, a ground water sample was collected from MW-1 and submitted for laboratory
analyses of VOCs by EPA Method 6200, lead by SM 610, VPH by MADEP Method, and EDB by
SM 504.1. Concentrations of benzene, naphthalene, n-propylbenzene, 1,2,4-trimethylbenzene, C5-C8
Aliphatics, and C9-C10 Aromatics that exceeded the Maximum Allowable Concentrations (MACs)
specified in T15A NCAC 2L.0202 were reported in the ground water sample collected from MW-1.
None of the reported contaminant concentrations exceeded the Gross Contamination Levels (GCLs).
A summary of ground water sample analytical results is presented in Table 5. A Ground Water
Quality Map is included as Figure 5. A copy of the Laboratory Report for the ground water sample
is included as Appendix B.

3. Quality Control:
The soil and ground water samples were immediately placed in laboratory-supplied containers, which
were then placed in iced coolers. New nitrile gloves were worn when collecting the samples. A new
disposable bailer was used to sample the monitoring well. Samples were logged using proper chain-
of-custody procedures. The samples were transported to a North Carolina Certified laboratory for
analyses.

E. CONCLUSIONS AND RECOMMENDATIONS
 The site is an active convenience store, petroleum retail facility and Little Caesar’s restaurant that
lies within the town limits of Winterville, Pitt County. Land use in the area consists of
commercial and residential properties.
 No potable water supply wells were identified within 1,000 feet of the site. No water supply
wells were identified within a 250-foot radius of the site. No water bodies are within 500 feet of
the site. The site is not located within a designated wellhead protection area.
 No concentrations of requested method constituents exceeding the MCCs were reported in soil
sample MW-1(2’).
 Concentrations of benzene, naphthalene, n-propylbenzene, 1,2,4-trimethylbenzene, C5-C8
Aliphatics, and C9-C10 Aromatics that exceeded the MACs were reported in the ground water
sample collected from MW-1.

7

 Based on this information, the site risk classification should be ranked as Low Risk. Subsequent
to filing a Notice of Residual Petroleum for ground water on the site deed, no further assessment
should be warranted for this incident.

F. LIMITATIONS
This report has been prepared for the exclusive use of E.J. Pope & Son, Inc. for specific application to the
referenced site in Pitt County, North Carolina. The assessment was conducted based on the scope of
work and level of effort specified by NCDEQ and with resources adequate only for that scope of work.
Our findings have been developed in accordance with generally accepted standards of geology and
hydrogeology practices in the State of North Carolina, available information and our professional
judgment. No other warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would be
interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.

FIGURES
Copyright (C) 2009 MyTopo, 2006-2018 TomTom
SCALE 1:24000
0 1000 2000 3000 4000 5000
FEET
Declination
MN 9.90° W
MN
Location: 035.5431340° N 077.4054830° WDate: 03/16/18
Scale: 1 inch = 2,000 ft.
Copyright (C) 2009 MyTopo
Figure 1
Handy Mart 61
4328 Highway 11 South, Winterville, Pitt County, NC
Incident No. N/A
GRI Project No. 4735
"J
SITEWSW-1
4675561524
4675467654
4675450977
4675458800
4675369471
4675455660
4675462313
4675462615
4675361345
FIGURE 2: SITE VICINITY MAPHANDY MART #614328 NC HIGHWAY 11WINTERVILLE, PITT COUNTYNORTH CAROLINAINCIDENT NO. <PENDING>GRI NO. 4735
PREPARED BY:GEOLOGICAL RESOURCES, INC.APRIL 23, 2018
³
0 300150Feet1 inch = 300 feet
1,500-FOOT RADIUS
1,000-FOOT RADIUS 250-FOOT RADIUS
LEGEND
Well Owners
Adjacent Properties
"J Water Supply Well
Ditch
Ponds
Pitt County Parcels

TABLES
Date: 06/07/18
Well # Parcel #Well
Owner Mailing Address Physical Well Address
Well
Use Municipal
Water?
Well
Depth
(ft BGS)
Type
of
Well
(Drilled/
Bored)
Well
Casing
Depth
(ft. BGS)
Well
Screen
Interval
(x to y
ft. BGS)
Approximate
Distance
from
Contaminant
Plume Edge
(ft.)
WSW-1 4675361345 James A. and Deloris V. Little 203 Davenport Farm Road
Winterville, North Carolina 28590
203 Davenport Farm Road
Winterville, North Carolina 28590
Inactive/
Well Collapsed Yes Unkown Unknown Unknown Unknown 1,090' W
Note:
• Water supply wells are keyed to Figure 2.
TABLE 1
WATER SUPPLY WELL INFORMATION
HANDY MART #61 (INCIDENT NO. 38684)
Facility ID # : 0-036234
Date: 06/07/18 Facility ID #: 0-036234
4675462313 (Site)EJP III Real Estate One, LLC Post Office Drawer 649
Mount Olive, North Carolina 28365
4675369471 136 Davenport Farm Road
Winterville, North Carolina 28590
4675462615 5009 Knob View Trail
Winston-Salem, North Carolina 27104
4675467564 Joe P. and Matilda S. Cullipher Post Office Box 66
Winterville, North Carolina 28590
4675561524 Charles V. and Rebecca B. White 139 Vernon White Road
Wintrerville, North Carolina 28590
4675458800 Tripp Farms, LLC 105 Marion Drive
Greenville, North Carolina 27858
4675455660 Trade Land Company, LLC 426 Longmeadow Road
Greenville, North Carolina 27858
4675450977 State Employees Credit Union Winterville Branch Post Office Box 26807
Raleigh, North Carolina 27611-6807
Note:
• Properties are keyed to Figure 2.
Bobo Family, LLC
TABLE 2
ADJACENT PROPERTY OWNER INFORMATION
HANDY MART #61 (INCIDENT NO. 38684)
Parcel Number Property Owner Name Mailing Address
Date: 05/24/18
MW-1 05/17/18 05/17/18 2 2-12 12 NM 2.81 ---NM
Notes:
• ft BGS : feet below ground surface.
• NM: Not Measured.
TABLE 3
WELL CONSTRUCTION AND GAUGING INFORMATION
HANDY MART #61 (INCIDENT NO. 38684)
Facility ID #: 0-036234
Well ID
Date
Installed
(mm/dd/yy)
Date Water
Level
Measured
(mm/dd/yy)
Well
Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation*
(ft.)
Depth to
Water from
Top of
Casing
(ft)
Free Product
Thickness
(ft.)
Ground
Water
Elevation
(ft.)
Comments
Page 1 of 1
Date: 05/18/18
Sample ID Date Collected
(mm/dd/yy)
Sample Depth
(feet)
50 100 NA NA NA NA NA NA NA NA NA
NE NE 0.0056 4.3 4.9 4.6 0.091 0.16 68 540 31
NE NE 18 1,200 1,560 3,129 350 313 939 1,500 469
NE NE 164 32,000 40,000 81,760 3,100 8,176 24,528 40,000 12,264
SB-1 (2')03/02/18 2 191 NR NR NR NR NR NR NR NR NR NR
MW-1 (2')05/17/18 2 NR NR <0.074 0.0687 J <0.060 <0.13 <0.060 <0.12 3.36 J 7.25 8.03
Notes:
• Results reported in mg/kg (milligrams per kilograms)
• MCC: Maximum Contaminant Concentration as specified by T 15A NCAC 2L.0202.
• < : Less than the method detection limit specified in the laboratory report
• Concentrations in bold face type exceeded the soil to ground water MSCCs.
• NR: Not Requested
• NE: Not Established
• J: Estimated value.
TABLE 4
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS
HANDY MART #61 (INCIDENT NO. 38684)
Facility ID No.: 0-036234
C5-C8 AliphaticsC9-C12 AliphaticsC9-C10 AromaticsAnalytical Method EPA Method 8015C EPA Methods 8260B and 8270 MADEP Methods VPH and
EPH
RAL (mg/kg)
Soil to Water MCC (mg/kg)
Residential Soil Cleanup Levels (mg/kg)
Industrial/Commercial Soil Cleanup Levels
(mg/kg)NaphthaleneContaminant of Concern TPH-GROTPH-DROBenzeneTolueneEthylbenzeneXylenesMTBE
Date: 06/07/18
EPA
Method
5040.1
EPA
Method
6010B
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 400 0.02 15 400 700 200
5,000 260,000 84,500 85,500 20,000 6,000 30,000 28,500 50 15,000 NE NE NE
MW-1 05/17/18 446 19.3 443 478 4.9 J 397 83.2 404 <0.0093 12.3 1,560 <700 3,270
Notes:
• Results reported in micrograms per liter (µg/l).
• < : Less than the method detection limit specified in the laboratory report.
• 2L Standard specified in T15A NCAC 2L.0202.
• GCL: Gross contamination level.
• NE: Not Established
• Concentrations in bold face type exceeded the 2L standards.
• Concentrations in italics exceeded the gross contamination levels.
• Refer to laboratory report for detected constituents that did not exceed the MACs, or for which no standard has been established.EDBLeadTABLE 5
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
HANDY MART #61 (INCIDENT NO. 38684)
Analytical Method EPA Method 6200B
GCL (µg/l)
Facility ID No.: 0-036234
C5-C8 AliphaticsC9-C12 AliphaticsC9-C10 AromaticsMADEP Method VPH
MTBENaphthalenen-Propylbenzene2L Standard (µg/l)
Contaminant of Concern
BenzeneTolueneEthylbenzeneXylenes1,2,4-TrimethylbenzenePage 1 of 1

APPENDICES

APPENDIX A
Well Construction Record

APPENDIX B
Laboratory Report – Soil and Ground Water Samples

05/30/18
Technical Report for
GRI (Geological Resources Inc.)
Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
4735
SGS Job Number: FA54306
Sampling Date: 05/17/18
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]; [e-mail]
ATTN: William Regenthall
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AK, AR, IA, KY, MA, MS, ND, NH, NV, OK, OR, UT, WA, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Caitlin Brice, M.S.
General Manager
Orlando, FL 05/30/18
e-Hardcopy 2.0
Automated Report
57
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
1 of 57
FA54306
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................6
3.1: FA54306-1: MW-1 ........................................................................................................7
3.2: FA54306-2: MW-1-2 ....................................................................................................13
Section 4: Misc. Forms ............................................................................................................16
4.1: Chain of Custody ...........................................................................................................17
Section 5: MS Volatiles - QC Data Summaries .....................................................................19
5.1: Method Blank Summary ................................................................................................20
5.2: Blank Spike Summary ...................................................................................................26
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................32
Section 6: GC Volatiles - QC Data Summaries .....................................................................38
6.1: Method Blank Summary ................................................................................................39
6.2: Blank Spike Summary ...................................................................................................42
6.3: Blank Spike/Blank Spike Duplicate Summary ..............................................................44
6.4: Matrix Spike Summary ..................................................................................................46
6.5: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................48
6.6: Duplicate Summary .......................................................................................................49
Section 7: Metals Analysis - QC Data Summaries ................................................................51
7.1: Prep QC MP33772: Pb ..................................................................................................52 12345672 of 57
FA54306
SGS North America Inc.
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA54306
Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Project No: 4735
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
FA54306-1 05/17/18 10:10 WB 05/18/18 AQ Ground Water MW-1
FA54306-2 05/17/18 10:25 WB 05/18/18 SO Soil MW-1-2
Soil samples reported on a dry weight basis unless otherwise indicated on result page.
3 of 57
FA543061
Summary of Hits Page 1 of 2
Job Number:FA54306
Account:GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Collected:05/17/18
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA54306-1 MW-1
Benzene 446 5.0 1.3 ug/l SM 6200B
n-Butylbenzene 32.9 5.0 1.3 ug/l SM 6200B
sec-Butylbenzene 14.5 5.0 1.3 ug/l SM 6200B
Ethylbenzene 443 5.0 1.3 ug/l SM 6200B
Isopropylbenzene 45.4 5.0 1.3 ug/l SM 6200B
p-Isopropyltoluene 3.8 J 5.0 1.3 ug/l SM 6200B
Methyl Tert Butyl Ether 4.9 J 5.0 1.3 ug/l SM 6200B
Naphthalene 397 5.0 1.3 ug/l SM 6200B
n-Propylbenzene 83.2 5.0 1.3 ug/l SM 6200B
Tert-Amyl Alcohol 455 100 20 ug/l SM 6200B
Toluene 19.3 5.0 1.3 ug/l SM 6200B
1,2,4-Trimethylbenzene 404 5.0 1.3 ug/l SM 6200B
1,3,5-Trimethylbenzene 79.6 5.0 1.3 ug/l SM 6200B
m,p-Xylene 475 10 1.3 ug/l SM 6200B
o-Xylene 2.8 J 5.0 1.3 ug/l SM 6200B
Xylene (total)478 15 2.5 ug/l SM 6200B
Benzene 499 5.0 5.0 ug/l MADEP VPH REV 1.1
Ethylbenzene 505 10 5.0 ug/l MADEP VPH REV 1.1
Methyl Tert Butyl Ether 149 10 5.0 ug/l MADEP VPH REV 1.1
Naphthalene 453 25 15 ug/l MADEP VPH REV 1.1
Toluene 25.1 10 5.0 ug/l MADEP VPH REV 1.1
m,p-Xylene 495 20 10 ug/l MADEP VPH REV 1.1
o-Xylene 10 10 5.0 ug/l MADEP VPH REV 1.1
C5- C8 Aliphatics (Unadj.)2230 500 180 ug/l MADEP VPH REV 1.1
C9- C12 Aliphatics (Unadj.)1290 J 2000 700 ug/l MADEP VPH REV 1.1
C9- C10 Aromatics (Unadj.)3270 2000 700 ug/l MADEP VPH REV 1.1
C5- C8 Aliphatics 1560 500 180 ug/l MADEP VPH REV 1.1
C9- C10 Aromatics 3270 2000 700 ug/l MADEP VPH REV 1.1
Lead 12.3 5.0 ug/l SW846 6010D
FA54306-2 MW-1-2
Toluene a 0.0687 J 0.30 0.060 mg/kg SW846 8260B
Ethylbenzene 0.136 0.13 0.064 mg/kg MADEP VPH REV 1.1
Naphthalene 1.09 0.32 0.19 mg/kg MADEP VPH REV 1.1
o-Xylene 0.306 0.13 0.064 mg/kg MADEP VPH REV 1.1
C5- C8 Aliphatics (Unadj.)3.36 J 6.4 2.2 mg/kg MADEP VPH REV 1.1
C9- C12 Aliphatics (Unadj.)7.75 6.4 2.2 mg/kg MADEP VPH REV 1.1
C9- C10 Aromatics (Unadj.)8.03 6.4 2.2 mg/kg MADEP VPH REV 1.1
C5- C8 Aliphatics 3.36 J 6.4 2.2 mg/kg MADEP VPH REV 1.1
C9- C12 Aliphatics 7.25 6.4 2.2 mg/kg MADEP VPH REV 1.1
C9- C10 Aromatics 8.03 6.4 2.2 mg/kg MADEP VPH REV 1.1
4 of 57
FA543062
Summary of Hits Page 2 of 2
Job Number:FA54306
Account:GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Collected:05/17/18
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
(a) Dilution required due to matrix interference (sample foamed). Suspected laboratory contaminant.
5 of 57
FA543062
SGS North America Inc.
Sample Results
Report of Analysis
Orlando, FL
Section 3
6 of 57
FA543063
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:MW-1
Lab Sample ID:FA54306-1 Date Sampled:05/17/18
Matrix:AQ - Ground Water Date Received:05/18/18
Method:SM 6200B Percent Solids:n/a
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0213840.D 10 05/25/18 15:49 TD n/a n/a VA2399
Run #2 E058389.D 10 05/24/18 23:17 TD n/a n/a VE1967
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 446 5.0 1.3 ug/l
108-86-1 Bromobenzene ND 5.0 1.3 ug/l
74-97-5 Bromochloromethane ND 5.0 1.3 ug/l
75-27-4 Bromodichloromethane ND 5.0 1.3 ug/l
75-25-2 Bromoform ND 5.0 1.3 ug/l
104-51-8 n-Butylbenzene 32.9 5.0 1.3 ug/l
135-98-8 sec-Butylbenzene 14.5 5.0 1.3 ug/l
98-06-6 tert-Butylbenzene ND 5.0 1.3 ug/l
56-23-5 Carbon Tetrachloride ND 5.0 1.3 ug/l
108-90-7 Chlorobenzene ND 5.0 1.3 ug/l
75-00-3 Chloroethane ND 5.0 2.0 ug/l
67-66-3 Chloroform ND 5.0 1.3 ug/l
95-49-8 o-Chlorotoluene ND 5.0 1.3 ug/l
106-43-4 p-Chlorotoluene ND 5.0 1.3 ug/l
124-48-1 Dibromochloromethane ND 5.0 1.3 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 5.0 2.5 ug/l
106-93-4 1,2-Dibromoethane ND 5.0 1.3 ug/l
75-71-8 Dichlorodifluoromethane ND 5.0 2.0 ug/l
95-50-1 1,2-Dichlorobenzene ND 5.0 1.3 ug/l
541-73-1 1,3-Dichlorobenzene ND 5.0 1.3 ug/l
106-46-7 1,4-Dichlorobenzene ND 5.0 1.3 ug/l
75-34-3 1,1-Dichloroethane ND 5.0 1.3 ug/l
107-06-2 1,2-Dichloroethane ND 5.0 1.3 ug/l
75-35-4 1,1-Dichloroethylene ND 5.0 1.3 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 5.0 1.3 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 5.0 1.3 ug/l
78-87-5 1,2-Dichloropropane ND 5.0 1.3 ug/l
142-28-9 1,3-Dichloropropane ND 5.0 1.3 ug/l
594-20-7 2,2-Dichloropropane ND 5.0 1.3 ug/l
563-58-6 1,1-Dichloropropene ND 5.0 1.3 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 5.0 1.3 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 5.0 1.3 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
7 of 57
FA5430633.1
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:MW-1
Lab Sample ID:FA54306-1 Date Sampled:05/17/18
Matrix:AQ - Ground Water Date Received:05/18/18
Method:SM 6200B Percent Solids:n/a
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 5.0 1.3 ug/l
100-41-4 Ethylbenzene 443 5.0 1.3 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 5.0 1.3 ug/l
87-68-3 Hexachlorobutadiene ND 5.0 1.3 ug/l
98-82-8 Isopropylbenzene 45.4 5.0 1.3 ug/l
99-87-6 p-Isopropyltoluene 3.8 5.0 1.3 ug/l J
74-83-9 Methyl Bromide ND 5.0 2.0 ug/l
74-87-3 Methyl Chloride ND 5.0 2.0 ug/l
74-95-3 Methylene Bromide ND 5.0 1.3 ug/l
75-09-2 Methylene Chloride ND 20 10 ug/l
1634-04-4 Methyl Tert Butyl Ether 4.9 5.0 1.3 ug/l J
91-20-3 Naphthalene 397 5.0 1.3 ug/l
103-65-1 n-Propylbenzene 83.2 5.0 1.3 ug/l
100-42-5 Styrene ND 5.0 1.3 ug/l
75-85-4 Tert-Amyl Alcohol 455 100 20 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 10 2.0 ug/l
75-65-0 Tert-Butyl Alcohol ND 100 20 ug/l
762-75-4 Tert-Butyl Formate a ND 100 20 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 5.0 1.3 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 5.0 1.3 ug/l
127-18-4 Tetrachloroethylene ND 5.0 1.3 ug/l
108-88-3 Toluene 19.3 5.0 1.3 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 5.0 1.3 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 5.0 1.3 ug/l
71-55-6 1,1,1-Trichloroethane ND 5.0 1.3 ug/l
79-00-5 1,1,2-Trichloroethane ND 5.0 1.3 ug/l
79-01-6 Trichloroethylene ND 5.0 1.3 ug/l
75-69-4 Trichlorofluoromethane ND 5.0 2.0 ug/l
96-18-4 1,2,3-Trichloropropane ND 5.0 1.3 ug/l
95-63-6 1,2,4-Trimethylbenzene 404 5.0 1.3 ug/l
108-67-8 1,3,5-Trimethylbenzene 79.6 5.0 1.3 ug/l
75-01-4 Vinyl Chloride ND 5.0 1.3 ug/l
m,p-Xylene 475 10 1.3 ug/l
95-47-6 o-Xylene 2.8 5.0 1.3 ug/l J
1330-20-7 Xylene (total)478 15 2.5 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 98%98%70-130%
17060-07-0 1,2-Dichloroethane-D4 95%105%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 57
FA5430633.1
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:MW-1
Lab Sample ID:FA54306-1 Date Sampled:05/17/18
Matrix:AQ - Ground Water Date Received:05/18/18
Method:SM 6200B Percent Solids:n/a
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
2037-26-5 Toluene-D8 99%103%70-130%
460-00-4 4-Bromofluorobenzene 98%108%70-130%
(a) Associated BS recovery outside control limits.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
9 of 57
FA5430633.1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:MW-1
Lab Sample ID:FA54306-1 Date Sampled:05/17/18
Matrix:AQ - Ground Water Date Received:05/18/18
Method:EPA 504.1 EPA 504.1 Percent Solids:n/a
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 DD99730.D 1 05/21/18 15:21 NM 05/21/18 09:30 OP70130 GDD2891
Run #2
Initial Volume Final Volume
Run #1 37.8 ml 2.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
106-93-4 1,2-Dibromoethane ND 0.019 0.0093 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 81%63-137%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
10 of 57
FA5430633.1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:MW-1
Lab Sample ID:FA54306-1 Date Sampled:05/17/18
Matrix:AQ - Ground Water Date Received:05/18/18
Method:MADEP VPH REV 1.1 Percent Solids:n/a
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 UU024730.D 5 05/24/18 16:23 SH n/a n/a GUU1276
Run #2 UU024729.D 20 05/24/18 15:51 SH n/a n/a GUU1276
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 499 5.0 5.0 ug/l
100-41-4 Ethylbenzene 505 10 5.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 149 10 5.0 ug/l
91-20-3 Naphthalene 453 25 15 ug/l
108-88-3 Toluene 25.1 10 5.0 ug/l
m,p-Xylene 495 20 10 ug/l
95-47-6 o-Xylene 10 10 5.0 ug/l
C5- C8 Aliphatics (Unadj.)2230 500 180 ug/l
C9- C12 Aliphatics (Unadj.)1290 a 2000 700 ug/l J
C9- C10 Aromatics (Unadj.)3270 a 2000 700 ug/l
C5- C8 Aliphatics 1560 500 180 ug/l
C9- C12 Aliphatics ND a 2000 700 ug/l
C9- C10 Aromatics 3270 a 2000 700 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 117%108%70-130%
460-00-4 BFB 101%97%70-130%
(a) Result is from Run# 2
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
11 of 57
FA5430633.1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:MW-1
Lab Sample ID:FA54306-1 Date Sampled:05/17/18
Matrix:AQ - Ground Water Date Received:05/18/18
Percent Solids:n/a
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Lead 12.3 5.0 ug/l 1 05/22/18 05/22/18 LM SW846 6010D 1 SW846 3010A 2
(1) Instrument QC Batch: MA14915
(2) Prep QC Batch: MP33772
RL = Reporting Limit
12 of 57
FA5430633.1
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-1-2
Lab Sample ID:FA54306-2 Date Sampled:05/17/18
Matrix:SO - Soil Date Received:05/18/18
Method:SW846 8260B Percent Solids:93.6
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 2B8468.D 1 05/21/18 19:11 SP n/a n/a V2B321
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 4.70 g 5.0 ml 100 ul
Run #2
VOA Special List
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 3.0 0.60 mg/kg
71-43-2 Benzene ND 0.30 0.074 mg/kg
75-27-4 Bromodichloromethane ND 0.30 0.060 mg/kg
75-25-2 Bromoform ND 0.30 0.060 mg/kg
78-93-3 2-Butanone (MEK)ND 1.5 0.44 mg/kg
104-51-8 n-Butylbenzene ND 0.30 0.060 mg/kg
75-15-0 Carbon Disulfide ND 0.30 0.060 mg/kg
56-23-5 Carbon Tetrachloride ND 0.30 0.061 mg/kg
108-90-7 Chlorobenzene ND 0.30 0.060 mg/kg
75-00-3 Chloroethane ND 0.30 0.12 mg/kg
67-66-3 Chloroform ND 0.30 0.080 mg/kg
110-82-7 Cyclohexane ND 0.30 0.075 mg/kg
124-48-1 Dibromochloromethane ND 0.30 0.060 mg/kg
96-12-8 1,2-Dibromo-3-chloropropane ND 0.30 0.12 mg/kg
106-93-4 1,2-Dibromoethane ND 0.30 0.060 mg/kg
75-71-8 Dichlorodifluoromethane ND 0.30 0.12 mg/kg
95-50-1 1,2-Dichlorobenzene ND 0.30 0.060 mg/kg
541-73-1 1,3-Dichlorobenzene ND 0.30 0.060 mg/kg
106-46-7 1,4-Dichlorobenzene ND 0.30 0.069 mg/kg
75-34-3 1,1-Dichloroethane ND 0.30 0.11 mg/kg
107-06-2 1,2-Dichloroethane ND 0.30 0.060 mg/kg
75-35-4 1,1-Dichloroethylene ND 0.30 0.060 mg/kg
156-59-2 cis-1,2-Dichloroethylene ND 0.30 0.083 mg/kg
156-60-5 trans-1,2-Dichloroethylene ND 0.30 0.060 mg/kg
78-87-5 1,2-Dichloropropane ND 0.30 0.060 mg/kg
10061-01-5 cis-1,3-Dichloropropene ND 0.30 0.060 mg/kg
10061-02-6 trans-1,3-Dichloropropene ND 0.30 0.060 mg/kg
100-41-4 Ethylbenzene ND 0.30 0.060 mg/kg
591-78-6 2-Hexanone ND 1.5 0.45 mg/kg
98-82-8 Isopropylbenzene ND 0.30 0.060 mg/kg
79-20-9 Methyl Acetate ND 1.5 0.54 mg/kg
74-83-9 Methyl Bromide ND 0.30 0.12 mg/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
13 of 57
FA5430633.2
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-1-2
Lab Sample ID:FA54306-2 Date Sampled:05/17/18
Matrix:SO - Soil Date Received:05/18/18
Method:SW846 8260B Percent Solids:93.6
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
VOA Special List
CAS No.Compound Result RL MDL Units Q
74-87-3 Methyl Chloride ND 0.30 0.12 mg/kg
108-87-2 Methylcyclohexane ND 0.30 0.10 mg/kg
75-09-2 Methylene Chloride ND 0.60 0.24 mg/kg
108-10-1 4-Methyl-2-pentanone (MIBK)ND 1.5 0.45 mg/kg
1634-04-4 Methyl Tert Butyl Ether ND 0.30 0.060 mg/kg
91-20-3 Naphthalene ND 0.30 0.12 mg/kg
103-65-1 n-Propylbenzene ND 0.30 0.060 mg/kg
100-42-5 Styrene ND 0.30 0.060 mg/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 0.30 0.060 mg/kg
127-18-4 Tetrachloroethylene ND 0.30 0.077 mg/kg
108-88-3 Toluene b 0.0687 0.30 0.060 mg/kg J
120-82-1 1,2,4-Trichlorobenzene ND 0.30 0.060 mg/kg
71-55-6 1,1,1-Trichloroethane ND 0.30 0.060 mg/kg
79-00-5 1,1,2-Trichloroethane ND 0.30 0.060 mg/kg
79-01-6 Trichloroethylene ND 0.30 0.060 mg/kg
75-69-4 Trichlorofluoromethane ND 0.30 0.12 mg/kg
95-63-6 1,2,4-Trimethylbenzene ND 0.30 0.060 mg/kg
108-67-8 1,3,5-Trimethylbenzene ND 0.30 0.060 mg/kg
75-01-4 Vinyl Chloride ND 0.30 0.060 mg/kg
1330-20-7 Xylene (total)ND 0.90 0.13 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 98%75-124%
17060-07-0 1,2-Dichloroethane-D4 105%72-135%
2037-26-5 Toluene-D8 101%75-126%
460-00-4 4-Bromofluorobenzene 100%71-133%
(a) Dilution required due to matrix interference (sample foamed).
(b) Suspected laboratory contaminant.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
14 of 57
FA5430633.2
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:MW-1-2
Lab Sample ID:FA54306-2 Date Sampled:05/17/18
Matrix:SO - Soil Date Received:05/18/18
Method:MADEP VPH REV 1.1 Percent Solids:93.6
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 UU024713.D 1 05/23/18 15:57 SH n/a n/a GUU1275
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 4.52 g 5.1 ml 100 ul
Run #2
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.064 0.064 mg/kg
100-41-4 Ethylbenzene 0.136 0.13 0.064 mg/kg
1634-04-4 Methyl Tert Butyl Ether ND 0.13 0.064 mg/kg
91-20-3 Naphthalene 1.09 0.32 0.19 mg/kg
108-88-3 Toluene ND 0.13 0.064 mg/kg
m,p-Xylene ND 0.25 0.13 mg/kg
95-47-6 o-Xylene 0.306 0.13 0.064 mg/kg
C5- C8 Aliphatics (Unadj.)3.36 6.4 2.2 mg/kg J
C9- C12 Aliphatics (Unadj.)7.75 6.4 2.2 mg/kg
C9- C10 Aromatics (Unadj.)8.03 6.4 2.2 mg/kg
C5- C8 Aliphatics 3.36 6.4 2.2 mg/kg J
C9- C12 Aliphatics 7.25 6.4 2.2 mg/kg
C9- C10 Aromatics 8.03 6.4 2.2 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 105%70-130%
460-00-4 BFB 94%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
15 of 57
FA5430633.2
SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Orlando, FL
Section 4
16 of 57
FA543064
FA54306: Chain of Custody
Page 1 of 2
17 of 57
FA5430644.1
Job Number:FA54306 Client:GRI
Date / Time Received:5/18/2018 9:30:00 AM Delivery Method:FX
Project:4735
Airbill #'s:1015906982560003281100812575715363
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
IR Gun
Ice (Bag)
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments
SM001Rev. Date 05/24/17
SGS Sample Receipt Summary
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (3.4);
Cooler 1: (3.8);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:1Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230315 pH 10-12 219813A Other: (Specify)
Y or N N/A
Y or N
Therm ID:IR 1; Therm CF:0.4; # of Coolers:1
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:JORGEC P.H Date:5/18/2018Date:5/18/2018 9:30:00 AM
FA54306: Chain of Custody
Page 2 of 2
18 of 57
FA5430644.1
SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
19 of 57
FA543065
Method Blank Summary Page 1 of 1
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1967-MB E058379.D 1 05/24/18 TD n/a n/a VE1967
The QC reported here applies to the following samples:Method: SM 6200B
FA54306-1
CAS No.Compound Result RL MDL Units Q
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 120%70-130%
2037-26-5 Toluene-D8 105%70-130%
460-00-4 4-Bromofluorobenzene 110%70-130%
20 of 57
FA5430655.1.1
Method Blank Summary Page 1 of 3
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2399-MB A0213834.D 1 05/25/18 TD n/a n/a VA2399
The QC reported here applies to the following samples:Method: SM 6200B
FA54306-1
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
21 of 57
FA5430655.1.2
Method Blank Summary Page 2 of 3
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2399-MB A0213834.D 1 05/25/18 TD n/a n/a VA2399
The QC reported here applies to the following samples:Method: SM 6200B
FA54306-1
CAS No.Compound Result RL MDL Units Q
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 100%70-130%
22 of 57
FA5430655.1.2
Method Blank Summary Page 3 of 3
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2399-MB A0213834.D 1 05/25/18 TD n/a n/a VA2399
The QC reported here applies to the following samples:Method: SM 6200B
FA54306-1
CAS No.Surrogate Recoveries Limits
17060-07-0 1,2-Dichloroethane-D4 97%70-130%
2037-26-5 Toluene-D8 99%70-130%
460-00-4 4-Bromofluorobenzene 97%70-130%
23 of 57
FA5430655.1.2
Method Blank Summary Page 1 of 2
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B321-MB 2B8465.D 1 05/21/18 SP n/a n/a V2B321
The QC reported here applies to the following samples:Method: SW846 8260B
FA54306-2
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 50 10 ug/kg
71-43-2 Benzene ND 5.0 1.2 ug/kg
75-27-4 Bromodichloromethane ND 5.0 1.0 ug/kg
75-25-2 Bromoform ND 5.0 1.0 ug/kg
78-93-3 2-Butanone (MEK)ND 25 7.3 ug/kg
104-51-8 n-Butylbenzene ND 5.0 1.0 ug/kg
75-15-0 Carbon Disulfide ND 5.0 1.0 ug/kg
56-23-5 Carbon Tetrachloride ND 5.0 1.0 ug/kg
108-90-7 Chlorobenzene ND 5.0 1.0 ug/kg
75-00-3 Chloroethane ND 5.0 2.0 ug/kg
67-66-3 Chloroform ND 5.0 1.3 ug/kg
110-82-7 Cyclohexane ND 5.0 1.3 ug/kg
124-48-1 Dibromochloromethane ND 5.0 1.0 ug/kg
96-12-8 1,2-Dibromo-3-chloropropane ND 5.0 1.9 ug/kg
106-93-4 1,2-Dibromoethane ND 5.0 1.0 ug/kg
75-71-8 Dichlorodifluoromethane ND 5.0 2.0 ug/kg
95-50-1 1,2-Dichlorobenzene ND 5.0 1.0 ug/kg
541-73-1 1,3-Dichlorobenzene ND 5.0 1.0 ug/kg
106-46-7 1,4-Dichlorobenzene ND 5.0 1.2 ug/kg
75-34-3 1,1-Dichloroethane ND 5.0 1.8 ug/kg
107-06-2 1,2-Dichloroethane ND 5.0 1.0 ug/kg
75-35-4 1,1-Dichloroethylene ND 5.0 1.0 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 5.0 1.4 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 5.0 1.0 ug/kg
78-87-5 1,2-Dichloropropane ND 5.0 1.0 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 5.0 1.0 ug/kg
10061-02-6 trans-1,3-Dichloropropene ND 5.0 1.0 ug/kg
100-41-4 Ethylbenzene ND 5.0 1.0 ug/kg
591-78-6 2-Hexanone ND 25 7.5 ug/kg
98-82-8 Isopropylbenzene ND 5.0 1.0 ug/kg
79-20-9 Methyl Acetate ND 25 8.9 ug/kg
74-83-9 Methyl Bromide ND 5.0 2.0 ug/kg
74-87-3 Methyl Chloride ND 5.0 2.0 ug/kg
108-87-2 Methylcyclohexane ND 5.0 1.7 ug/kg
75-09-2 Methylene Chloride 4.1 10 4.0 ug/kg J
108-10-1 4-Methyl-2-pentanone (MIBK)ND 25 7.5 ug/kg
24 of 57
FA5430655.1.3
Method Blank Summary Page 2 of 2
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B321-MB 2B8465.D 1 05/21/18 SP n/a n/a V2B321
The QC reported here applies to the following samples:Method: SW846 8260B
FA54306-2
CAS No.Compound Result RL MDL Units Q
1634-04-4 Methyl Tert Butyl Ether ND 5.0 1.0 ug/kg
91-20-3 Naphthalene ND 5.0 2.0 ug/kg
103-65-1 n-Propylbenzene ND 5.0 1.0 ug/kg
100-42-5 Styrene ND 5.0 1.0 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 5.0 1.0 ug/kg
127-18-4 Tetrachloroethylene ND 5.0 1.3 ug/kg
108-88-3 Toluene ND 5.0 1.0 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 5.0 1.0 ug/kg
71-55-6 1,1,1-Trichloroethane ND 5.0 1.0 ug/kg
79-00-5 1,1,2-Trichloroethane ND 5.0 1.0 ug/kg
79-01-6 Trichloroethylene ND 5.0 1.0 ug/kg
75-69-4 Trichlorofluoromethane ND 5.0 2.0 ug/kg
95-63-6 1,2,4-Trimethylbenzene ND 5.0 1.0 ug/kg
108-67-8 1,3,5-Trimethylbenzene ND 5.0 1.0 ug/kg
75-01-4 Vinyl Chloride ND 5.0 1.0 ug/kg
1330-20-7 Xylene (total)ND 15 2.1 ug/kg
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 99%75-124%
17060-07-0 1,2-Dichloroethane-D4 102%72-135%
2037-26-5 Toluene-D8 103%75-126%
460-00-4 4-Bromofluorobenzene 104%71-133%
25 of 57
FA5430655.1.3
Blank Spike Summary Page 1 of 1
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1967-BS E058377.D 1 05/24/18 TD n/a n/a VE1967
The QC reported here applies to the following samples:Method: SM 6200B
FA54306-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 98%70-130%
17060-07-0 1,2-Dichloroethane-D4 103%70-130%
2037-26-5 Toluene-D8 102%70-130%
460-00-4 4-Bromofluorobenzene 105%70-130%
* = Outside of Control Limits.
26 of 57
FA5430655.2.1
Blank Spike Summary Page 1 of 3
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2399-BS A0213832.D 1 05/25/18 TD n/a n/a VA2399
The QC reported here applies to the following samples:Method: SM 6200B
FA54306-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.1 101 70-130
108-86-1 Bromobenzene 10 10.2 102 70-130
74-97-5 Bromochloromethane 10 10 100 70-130
75-27-4 Bromodichloromethane 10 9.7 97 70-130
75-25-2 Bromoform 10 8.8 88 70-130
104-51-8 n-Butylbenzene 10 10.3 103 70-130
135-98-8 sec-Butylbenzene 10 9.7 97 70-130
98-06-6 tert-Butylbenzene 10 9.4 94 70-130
56-23-5 Carbon Tetrachloride 10 9.7 97 70-130
108-90-7 Chlorobenzene 10 10.0 100 70-130
75-00-3 Chloroethane 10 11.5 115 60-140
67-66-3 Chloroform 10 9.4 94 70-130
95-49-8 o-Chlorotoluene 10 10.4 104 70-130
106-43-4 p-Chlorotoluene 10 10.3 103 70-130
124-48-1 Dibromochloromethane 10 9.7 97 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 9.4 94 70-130
106-93-4 1,2-Dibromoethane 10 10.0 100 70-130
75-71-8 Dichlorodifluoromethane 10 9.8 98 60-140
95-50-1 1,2-Dichlorobenzene 10 10.3 103 70-130
541-73-1 1,3-Dichlorobenzene 10 10.2 102 70-130
106-46-7 1,4-Dichlorobenzene 10 9.9 99 70-130
75-34-3 1,1-Dichloroethane 10 9.8 98 70-130
107-06-2 1,2-Dichloroethane 10 9.2 92 70-130
75-35-4 1,1-Dichloroethylene 10 9.4 94 70-130
156-59-2 cis-1,2-Dichloroethylene 10 10.1 101 70-130
156-60-5 trans-1,2-Dichloroethylene 10 9.6 96 70-130
78-87-5 1,2-Dichloropropane 10 10.1 101 70-130
142-28-9 1,3-Dichloropropane 10 10.2 102 70-130
594-20-7 2,2-Dichloropropane 10 10.0 100 70-130
563-58-6 1,1-Dichloropropene 10 9.9 99 70-130
10061-01-5 cis-1,3-Dichloropropene 10 9.3 93 70-130
10061-02-6 trans-1,3-Dichloropropene 10 9.3 93 70-130
108-20-3 Di-Isopropyl Ether 10 9.7 97 70-130
100-41-4 Ethylbenzene 10 10.0 100 70-130
637-92-3 Ethyl Tert Butyl Ether 10 10.0 100 70-130
87-68-3 Hexachlorobutadiene 10 9.9 99 70-130
* = Outside of Control Limits.
27 of 57
FA5430655.2.2
Blank Spike Summary Page 2 of 3
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2399-BS A0213832.D 1 05/25/18 TD n/a n/a VA2399
The QC reported here applies to the following samples:Method: SM 6200B
FA54306-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
98-82-8 Isopropylbenzene 10 10.5 105 70-130
99-87-6 p-Isopropyltoluene 10 9.7 97 70-130
74-83-9 Methyl Bromide 10 11.5 115 60-140
74-87-3 Methyl Chloride 10 9.2 92 60-140
74-95-3 Methylene Bromide 10 9.8 98 70-130
75-09-2 Methylene Chloride 10 9.1 91 70-130
1634-04-4 Methyl Tert Butyl Ether 10 9.8 98 70-130
91-20-3 Naphthalene 10 10.3 103 70-130
103-65-1 n-Propylbenzene 10 10.3 103 70-130
100-42-5 Styrene 10 10 100 70-130
75-85-4 Tert-Amyl Alcohol 100 101 101 70-130
994-05-8 Tert-Amyl Methyl Ether 10 10.2 102 70-130
75-65-0 Tert-Butyl Alcohol 100 70.9 71 70-130
762-75-4 Tert-Butyl Formate 100 ND 0*70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 10 100 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 9.8 98 70-130
127-18-4 Tetrachloroethylene 10 10.1 101 70-130
108-88-3 Toluene 10 10.2 102 70-130
87-61-6 1,2,3-Trichlorobenzene 10 10.1 101 70-130
120-82-1 1,2,4-Trichlorobenzene 10 10.2 102 70-130
71-55-6 1,1,1-Trichloroethane 10 9.8 98 70-130
79-00-5 1,1,2-Trichloroethane 10 10.2 102 70-130
79-01-6 Trichloroethylene 10 9.8 98 70-130
75-69-4 Trichlorofluoromethane 10 10.2 102 60-140
96-18-4 1,2,3-Trichloropropane 10 9.9 99 70-130
95-63-6 1,2,4-Trimethylbenzene 10 10.5 105 70-130
108-67-8 1,3,5-Trimethylbenzene 10 10.6 106 70-130
75-01-4 Vinyl Chloride 10 10.9 109 60-140
m,p-Xylene 20 20.5 103 70-130
95-47-6 o-Xylene 10 10.3 103 70-130
1330-20-7 Xylene (total)30 30.8 103 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 97%70-130%
* = Outside of Control Limits.
28 of 57
FA5430655.2.2
Blank Spike Summary Page 3 of 3
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2399-BS A0213832.D 1 05/25/18 TD n/a n/a VA2399
The QC reported here applies to the following samples:Method: SM 6200B
FA54306-1
CAS No.Surrogate Recoveries BSP Limits
17060-07-0 1,2-Dichloroethane-D4 96%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 99%70-130%
* = Outside of Control Limits.
29 of 57
FA5430655.2.2
Blank Spike Summary Page 1 of 2
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B321-BS 2B8464.D 1 05/21/18 SP n/a n/a V2B321
The QC reported here applies to the following samples:Method: SW846 8260B
FA54306-2
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
67-64-1 Acetone 250 240 96 61-152
71-43-2 Benzene 50 52.1 104 76-126
75-27-4 Bromodichloromethane 50 54.2 108 74-130
75-25-2 Bromoform 50 54.7 109 76-127
78-93-3 2-Butanone (MEK)250 255 102 75-137
104-51-8 n-Butylbenzene 50 56.2 112 71-128
75-15-0 Carbon Disulfide 50 50.7 101 72-122
56-23-5 Carbon Tetrachloride 50 56.6 113 78-133
108-90-7 Chlorobenzene 50 52.7 105 81-129
75-00-3 Chloroethane 50 44.5 89 68-133
67-66-3 Chloroform 50 49.4 99 72-123
110-82-7 Cyclohexane 50 54.4 109 73-126
124-48-1 Dibromochloromethane 50 53.5 107 76-127
96-12-8 1,2-Dibromo-3-chloropropane 50 51.3 103 70-137
106-93-4 1,2-Dibromoethane 50 52.6 105 77-126
75-71-8 Dichlorodifluoromethane 50 47.9 96 68-168
95-50-1 1,2-Dichlorobenzene 50 51.6 103 80-129
541-73-1 1,3-Dichlorobenzene 50 52.6 105 81-129
106-46-7 1,4-Dichlorobenzene 50 52.3 105 76-130
75-34-3 1,1-Dichloroethane 50 56.3 113 73-125
107-06-2 1,2-Dichloroethane 50 52.5 105 74-128
75-35-4 1,1-Dichloroethylene 50 55.0 110 81-136
156-59-2 cis-1,2-Dichloroethylene 50 55.1 110 74-126
156-60-5 trans-1,2-Dichloroethylene 50 56.9 114 70-127
78-87-5 1,2-Dichloropropane 50 53.1 106 74-125
10061-01-5 cis-1,3-Dichloropropene 50 50.7 101 80-123
10061-02-6 trans-1,3-Dichloropropene 50 54.0 108 75-131
100-41-4 Ethylbenzene 50 54.2 108 77-123
591-78-6 2-Hexanone 250 261 104 72-133
98-82-8 Isopropylbenzene 50 54.9 110 80-136
79-20-9 Methyl Acetate 250 228 91 67-137
74-83-9 Methyl Bromide 50 53.5 107 65-139
74-87-3 Methyl Chloride 50 53.1 106 71-144
108-87-2 Methylcyclohexane 50 55.6 111 75-128
75-09-2 Methylene Chloride 50 49.9 100 74-137
108-10-1 4-Methyl-2-pentanone (MIBK)250 250 100 76-132
* = Outside of Control Limits.
30 of 57
FA5430655.2.3
Blank Spike Summary Page 2 of 2
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B321-BS 2B8464.D 1 05/21/18 SP n/a n/a V2B321
The QC reported here applies to the following samples:Method: SW846 8260B
FA54306-2
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
1634-04-4 Methyl Tert Butyl Ether 50 49.6 99 77-120
91-20-3 Naphthalene 50 51.8 104 79-129
103-65-1 n-Propylbenzene 50 52.2 104 80-135
100-42-5 Styrene 50 51.6 103 78-125
79-34-5 1,1,2,2-Tetrachloroethane 50 52.4 105 71-126
127-18-4 Tetrachloroethylene 50 54.8 110 79-130
108-88-3 Toluene 50 50.3 101 76-124
120-82-1 1,2,4-Trichlorobenzene 50 53.7 107 78-130
71-55-6 1,1,1-Trichloroethane 50 52.5 105 70-129
79-00-5 1,1,2-Trichloroethane 50 51.7 103 74-124
79-01-6 Trichloroethylene 50 55.0 110 75-128
75-69-4 Trichlorofluoromethane 50 56.5 113 73-145
95-63-6 1,2,4-Trimethylbenzene 50 50.1 100 74-123
108-67-8 1,3,5-Trimethylbenzene 50 52.5 105 73-122
75-01-4 Vinyl Chloride 50 54.9 110 76-141
1330-20-7 Xylene (total)150 166 111 80-129
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 99%75-124%
17060-07-0 1,2-Dichloroethane-D4 97%72-135%
2037-26-5 Toluene-D8 100%75-126%
460-00-4 4-Bromofluorobenzene 99%71-133%
* = Outside of Control Limits.
31 of 57
FA5430655.2.3
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA54354-2MS E058392.D 500 05/25/18 TD n/a n/a VE1967
FA54354-2MSD E058393.D 500 05/25/18 TD n/a n/a VE1967
FA54354-2 a E058385.D 500 05/24/18 TD n/a n/a VE1967
The QC reported here applies to the following samples:Method: SM 6200B
FA54306-1
FA54354-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
CAS No.Surrogate Recoveries MS MSD FA54354-2 Limits
1868-53-7 Dibromofluoromethane 102%101%96%70-130%
17060-07-0 1,2-Dichloroethane-D4 97%96%96%70-130%
2037-26-5 Toluene-D8 104%103%105%70-130%
460-00-4 4-Bromofluorobenzene 119%117%105%70-130%
(a) Confirmation run.
* = Outside of Control Limits.
32 of 57
FA5430655.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA54310-4MS A0213843.D 100 05/25/18 TD n/a n/a VA2399
FA54310-4MSD A0213844.D 100 05/25/18 TD n/a n/a VA2399
FA54310-4 A0213850.D 10 05/25/18 TD n/a n/a VA2399
FA54310-4 A0213841.D 100 05/25/18 TD n/a n/a VA2399
The QC reported here applies to the following samples:Method: SM 6200B
FA54306-1
FA54310-4 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 28.8 1000 1070 104 1000 1020 99 5 70-130/20
108-86-1 Bromobenzene ND 1000 1040 104 1000 996 100 4 70-130/20
74-97-5 Bromochloromethane ND 1000 906 91 1000 873 87 4 70-130/20
75-27-4 Bromodichloromethane ND 1000 942 94 1000 920 92 2 70-130/20
75-25-2 Bromoform ND 1000 892 89 1000 887 89 1 70-130/20
104-51-8 n-Butylbenzene ND 1000 1110 111 1000 1020 102 8 70-130/20
135-98-8 sec-Butylbenzene ND 1000 1030 103 1000 925 93 11 70-130/20
98-06-6 tert-Butylbenzene ND 1000 937 94 1000 845 85 10 70-130/20
56-23-5 Carbon Tetrachloride ND 1000 936 94 1000 855 86 9 70-130/20
108-90-7 Chlorobenzene ND 1000 1030 103 1000 977 98 5 70-130/20
75-00-3 Chloroethane ND 1000 1030 103 1000 952 95 8 60-140/20
67-66-3 Chloroform 2.9 J 1000 929 93 1000 862 86 7 70-130/20
95-49-8 o-Chlorotoluene ND 1000 1050 105 1000 955 96 9 70-130/20
106-43-4 p-Chlorotoluene ND 1000 1050 105 1000 984 98 6 70-130/20
124-48-1 Dibromochloromethane ND 1000 982 98 1000 925 93 6 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 1000 928 93 1000 895 90 4 70-130/20
106-93-4 1,2-Dibromoethane ND 1000 970 97 1000 991 99 2 70-130/20
75-71-8 Dichlorodifluoromethane ND 1000 772 77 1000 689 69 11 60-140/20
95-50-1 1,2-Dichlorobenzene ND 1000 1050 105 1000 971 97 8 70-130/20
541-73-1 1,3-Dichlorobenzene ND 1000 1050 105 1000 1010 101 4 70-130/20
106-46-7 1,4-Dichlorobenzene ND 1000 1030 103 1000 978 98 5 70-130/20
75-34-3 1,1-Dichloroethane ND 1000 1000 100 1000 923 92 8 70-130/20
107-06-2 1,2-Dichloroethane ND 1000 826 83 1000 798 80 3 70-130/20
75-35-4 1,1-Dichloroethylene ND 1000 955 96 1000 852 85 11 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 1000 1040 104 1000 955 96 9 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 1000 963 96 1000 866 87 11 70-130/20
78-87-5 1,2-Dichloropropane ND 1000 1020 102 1000 980 98 4 70-130/20
142-28-9 1,3-Dichloropropane ND 1000 956 96 1000 954 95 0 70-130/20
594-20-7 2,2-Dichloropropane ND 1000 990 99 1000 913 91 8 70-130/20
563-58-6 1,1-Dichloropropene ND 1000 1020 102 1000 947 95 7 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 1000 896 90 1000 904 90 1 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 1000 922 92 1000 943 94 2 70-130/20
108-20-3 Di-Isopropyl Ether 16.7 1000 846 83 1000 804 79 5 70-130/20
100-41-4 Ethylbenzene 47.8 1000 1080 103 1000 1020 97 6 70-130/20
637-92-3 Ethyl Tert Butyl Ether ND 1000 883 88 1000 836 84 5 70-130/20
87-68-3 Hexachlorobutadiene ND 1000 1090 109 1000 947 95 14 70-130/20
* = Outside of Control Limits.
33 of 57
FA5430655.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA54310-4MS A0213843.D 100 05/25/18 TD n/a n/a VA2399
FA54310-4MSD A0213844.D 100 05/25/18 TD n/a n/a VA2399
FA54310-4 A0213850.D 10 05/25/18 TD n/a n/a VA2399
FA54310-4 A0213841.D 100 05/25/18 TD n/a n/a VA2399
The QC reported here applies to the following samples:Method: SM 6200B
FA54306-1
FA54310-4 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
98-82-8 Isopropylbenzene 2.7 J 1000 1130 113 1000 1040 104 8 70-130/20
99-87-6 p-Isopropyltoluene ND 1000 1020 102 1000 931 93 9 70-130/20
74-83-9 Methyl Bromide ND 1000 995 100 1000 921 92 8 60-140/20
74-87-3 Methyl Chloride ND 1000 978 98 1000 891 89 9 60-140/20
74-95-3 Methylene Bromide ND 1000 953 95 1000 935 94 2 70-130/20
75-09-2 Methylene Chloride ND 1000 851 85 1000 776 78 9 70-130/20
1634-04-4 Methyl Tert Butyl Ether 3170 b 1000 3930 76 1000 3750 58* a 5 70-130/20
91-20-3 Naphthalene ND 1000 1230 123 1000 1080 108 13 70-130/20
103-65-1 n-Propylbenzene 3.1 J 1000 1060 106 1000 970 97 9 70-130/20
100-42-5 Styrene ND 1000 1020 102 1000 991 99 3 70-130/20
75-85-4 Tert-Amyl Alcohol 54.3 J 10000 10100 100 10000 9750 97 4 70-130/20
994-05-8 Tert-Amyl Methyl Ether 66.6 1000 974 91 1000 933 87 4 70-130/20
75-65-0 Tert-Butyl Alcohol ND 10000 10200 102 10000 9890 99 3 70-130/20
762-75-4 Tert-Butyl Formate ND 10000 7910 79 10000 8570 86 8 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 1000 992 99 1000 923 92 7 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 1000 1040 104 1000 1010 101 3 70-130/20
127-18-4 Tetrachloroethylene ND 1000 1080 108 1000 991 99 9 70-130/20
108-88-3 Toluene 403 1000 1480 108 1000 1380 98 7 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 1000 1100 110 1000 950 95 15 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 1000 1070 107 1000 953 95 12 70-130/20
71-55-6 1,1,1-Trichloroethane ND 1000 918 92 1000 840 84 9 70-130/20
79-00-5 1,1,2-Trichloroethane ND 1000 990 99 1000 1000 100 1 70-130/20
79-01-6 Trichloroethylene ND 1000 978 98 1000 931 93 5 70-130/20
75-69-4 Trichlorofluoromethane ND 1000 863 86 1000 778 78 10 60-140/20
96-18-4 1,2,3-Trichloropropane ND 1000 945 95 1000 899 90 5 70-130/20
95-63-6 1,2,4-Trimethylbenzene 17.4 1000 1080 106 1000 981 96 10 70-130/20
108-67-8 1,3,5-Trimethylbenzene 8.8 1000 1100 109 1000 996 99 10 70-130/20
75-01-4 Vinyl Chloride ND 1000 955 96 1000 846 85 12 60-140/20
m,p-Xylene 233 2000 2360 106 2000 2210 99 7 70-130/20
95-47-6 o-Xylene 90.0 1000 1140 105 1000 1060 97 7 70-130/20
1330-20-7 Xylene (total)323 3000 3500 106 3000 3260 98 7 70-130/20
CAS No.Surrogate Recoveries MS MSD FA54310-4 FA54310-4 Limits
1868-53-7 Dibromofluoromethane 94%92%94%95%70-130%
* = Outside of Control Limits.
34 of 57
FA5430655.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA54310-4MS A0213843.D 100 05/25/18 TD n/a n/a VA2399
FA54310-4MSD A0213844.D 100 05/25/18 TD n/a n/a VA2399
FA54310-4 A0213850.D 10 05/25/18 TD n/a n/a VA2399
FA54310-4 A0213841.D 100 05/25/18 TD n/a n/a VA2399
The QC reported here applies to the following samples:Method: SM 6200B
FA54306-1
CAS No.Surrogate Recoveries MS MSD FA54310-4 FA54310-4 Limits
17060-07-0 1,2-Dichloroethane-D4 88%86%87%90%70-130%
2037-26-5 Toluene-D8 101%100%101%97%70-130%
460-00-4 4-Bromofluorobenzene 99%100%97%98%70-130%
(a) Outside control limits due to high level in sample relative to spike amount.
(b) Result is from Run #2.
* = Outside of Control Limits.
35 of 57
FA5430655.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA54291-7MS 2B8482.D 1 05/22/18 SP n/a n/a V2B321
FA54291-7MSD 2B8483.D 1 05/22/18 SP n/a n/a V2B321
FA54291-7 2B8475.D 1 05/21/18 SP n/a n/a V2B321
The QC reported here applies to the following samples:Method: SW846 8260B
FA54306-2
FA54291-7 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/kg Q ug/kg ug/kg %ug/kg ug/kg %RPD Rec/RPD
67-64-1 Acetone 711 I 12900 11600 84 12900 10800 78 7 61-152/27
71-43-2 Benzene 147 I 2580 2770 101 2580 2530 92 9 76-126/26
75-27-4 Bromodichloromethane 260 U 2580 2930 113 2580 2680 104 9 74-130/25
75-25-2 Bromoform 260 U 2580 3040 118 2580 2500 97 19 76-127/26
78-93-3 2-Butanone (MEK)1300 U 12900 12700 98 12900 11700 91 8 75-137/25
104-51-8 n-Butylbenzene 260 U 2580 3180 123 2580 2350 91 30 71-128/35
75-15-0 Carbon Disulfide 260 U 2580 2140 83 2580 1950 75 9 72-122/29
56-23-5 Carbon Tetrachloride 260 U 2580 2330 90 2580 2140 83 9 78-133/29
108-90-7 Chlorobenzene 260 U 2580 3040 118 2580 2420 94 23 81-129/29
75-00-3 Chloroethane 260 U 2580 1710 66*2580 1540 60*10 68-133/29
67-66-3 Chloroform 71.3 I 2580 2580 97 2580 2350 88 9 72-123/26
110-82-7 Cyclohexane 115 I 2580 1890 69*2580 1720 62*9 73-126/32
124-48-1 Dibromochloromethane 260 U 2580 3210 124 2580 2580 100 22 76-127/27
96-12-8 1,2-Dibromo-3-chloropropane 260 U 2580 2990 116 2580 2230 86 29 70-137/29
106-93-4 1,2-Dibromoethane 260 U 2580 3140 121 2580 2510 97 22 77-126/26
75-71-8 Dichlorodifluoromethane 260 U 2580 1320 51*2580 1250 48*5 68-168/29
95-50-1 1,2-Dichlorobenzene 260 U 2580 3370 130*2580 2500 97 30 80-129/32
541-73-1 1,3-Dichlorobenzene 260 U 2580 3310 128 2580 2480 96 29 81-129/33
106-46-7 1,4-Dichlorobenzene 260 U 2580 3350 130 2580 2520 97 28 76-130/32
75-34-3 1,1-Dichloroethane 260 U 2580 2850 110 2580 2600 101 9 73-125/27
107-06-2 1,2-Dichloroethane 260 U 2580 2970 115 2580 2730 106 8 74-128/23
75-35-4 1,1-Dichloroethylene 260 U 2580 2390 92 2580 2170 84 10 81-136/28
156-59-2 cis-1,2-Dichloroethylene 260 U 2580 2830 109 2580 2560 99 10 74-126/26
156-60-5 trans-1,2-Dichloroethylene 260 U 2580 2730 106 2580 2470 96 10 70-127/27
78-87-5 1,2-Dichloropropane 260 U 2580 2870 111 2580 2620 101 9 74-125/25
10061-01-5 cis-1,3-Dichloropropene 260 U 2580 2640 102 2580 2400 93 10 80-123/26
10061-02-6 trans-1,3-Dichloropropene 260 U 2580 3140 121 2580 2510 97 22 75-131/28
100-41-4 Ethylbenzene 132 I 2580 3150 117 2580 2510 92 23 77-123/31
591-78-6 2-Hexanone 1300 U 12900 14200 110 12900 11400 88 22 72-133/26
98-82-8 Isopropylbenzene 260 U 2580 2990 116 2580 2370 92 23 80-136/32
79-20-9 Methyl Acetate 1300 U 12900 13600 105 12900 13200 102 3 67-137/30
74-83-9 Methyl Bromide 260 U 2580 2590 100 2580 2480 96 4 65-139/31
74-87-3 Methyl Chloride 260 U 2580 2440 94 2580 2330 90 5 71-144/27
108-87-2 Methylcyclohexane 121 I 2580 1780 64*2580 1600 57*11 75-128/31
75-09-2 Methylene Chloride 520 U 2580 2730 106 2580 2500 97 9 74-137/28
108-10-1 4-Methyl-2-pentanone (MIBK)1300 U 12900 14600 113 12900 11600 90 23 76-132/26
* = Outside of Control Limits.
36 of 57
FA5430655.3.3
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA54291-7MS 2B8482.D 1 05/22/18 SP n/a n/a V2B321
FA54291-7MSD 2B8483.D 1 05/22/18 SP n/a n/a V2B321
FA54291-7 2B8475.D 1 05/21/18 SP n/a n/a V2B321
The QC reported here applies to the following samples:Method: SW846 8260B
FA54306-2
FA54291-7 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/kg Q ug/kg ug/kg %ug/kg ug/kg %RPD Rec/RPD
1634-04-4 Methyl Tert Butyl Ether 260 U 2580 2820 109 2580 2600 101 8 77-120/24
91-20-3 Naphthalene 260 U 2580 3280 127 2580 2400 93 31 79-129/33
103-65-1 n-Propylbenzene 94.1 I 2580 3130 117 2580 2320 86 30 80-135/33
100-42-5 Styrene 260 U 2580 2920 113 2580 1890 73*43*78-125/30
79-34-5 1,1,2,2-Tetrachloroethane 260 U 2580 3310 128*2580 2490 96 28 71-126/30
127-18-4 Tetrachloroethylene 260 U 2580 2990 116 2580 2310 89 26 79-130/31
108-88-3 Toluene 110 I 2580 2920 109 2580 2300 85 24 76-124/30
120-82-1 1,2,4-Trichlorobenzene 260 U 2580 3570 138*2580 2640 102 30 78-130/34
71-55-6 1,1,1-Trichloroethane 260 U 2580 2380 92 2580 2170 84 9 70-129/27
79-00-5 1,1,2-Trichloroethane 260 U 2580 3270 127*2580 2620 101 22 74-124/28
79-01-6 Trichloroethylene 260 U 2580 2630 102 2580 2370 92 10 75-128/27
75-69-4 Trichlorofluoromethane 260 U 2580 1830 71*2580 1630 63*12 73-145/31
95-63-6 1,2,4-Trimethylbenzene 523 2580 3910 131*2580 2940 94 28 74-123/34
108-67-8 1,3,5-Trimethylbenzene 258 I 2580 3550 127*2580 2660 93 29 73-122/33
75-01-4 Vinyl Chloride 260 U 2580 2100 81 2580 1970 76 6 76-141/27
1330-20-7 Xylene (total)973 7750 10800 127 7750 8580 98 23 80-129/30
CAS No.Surrogate Recoveries MS MSD FA54291-7 Limits
1868-53-7 Dibromofluoromethane 107%100%98%75-124%
17060-07-0 1,2-Dichloroethane-D4 110%102%105%72-135%
2037-26-5 Toluene-D8 101%99%102%75-126%
460-00-4 4-Bromofluorobenzene 99%98%101%71-133%
* = Outside of Control Limits.
37 of 57
FA5430655.3.3
SGS North America Inc.
GC Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 6
38 of 57
FA543066
Method Blank Summary Page 1 of 1
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GUU1275-MB UU024711.D 1 05/23/18 SH n/a n/a GUU1275
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA54306-2
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 51 51 ug/kg
100-41-4 Ethylbenzene ND 100 51 ug/kg
1634-04-4 Methyl Tert Butyl Ether ND 100 51 ug/kg
91-20-3 Naphthalene 236 260 150 ug/kg J
108-88-3 Toluene ND 100 51 ug/kg
m,p-Xylene ND 200 100 ug/kg
95-47-6 o-Xylene ND 100 51 ug/kg
C5- C8 Aliphatics (Unadj.)ND 5100 1800 ug/kg
C9- C12 Aliphatics (Unadj.)ND 5100 1800 ug/kg
C9- C10 Aromatics (Unadj.)ND 5100 1800 ug/kg
C5- C8 Aliphatics ND 5100 1800 ug/kg
C9- C12 Aliphatics ND 5100 1800 ug/kg
C9- C10 Aromatics ND 5100 1800 ug/kg
CAS No.Surrogate Recoveries Limits
460-00-4 BFB 91%70-130%
460-00-4 BFB 89%70-130%
39 of 57
FA5430666.1.1
Method Blank Summary Page 1 of 1
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GUU1276-MB UU024725.D 1 05/24/18 SH n/a n/a GUU1276
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA54306-1
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 1.0 1.0 ug/l
100-41-4 Ethylbenzene ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 2.0 1.0 ug/l
91-20-3 Naphthalene 4.7 5.0 3.0 ug/l J
108-88-3 Toluene ND 2.0 1.0 ug/l
m,p-Xylene ND 4.0 2.0 ug/l
95-47-6 o-Xylene ND 2.0 1.0 ug/l
C5- C8 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C12 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C10 Aromatics (Unadj.)ND 100 35 ug/l
C5- C8 Aliphatics ND 100 35 ug/l
C9- C12 Aliphatics ND 100 35 ug/l
C9- C10 Aromatics ND 100 35 ug/l
CAS No.Surrogate Recoveries Limits
460-00-4 BFB 114%70-130%
460-00-4 BFB 102%70-130%
40 of 57
FA5430666.1.2
Method Blank Summary Page 1 of 1
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP70130-MB DD99726.D 1 05/21/18 NM 05/21/18 OP70130 GDD2891
The QC reported here applies to the following samples:Method: EPA 504.1
FA54306-1
CAS No.Compound Result RL MDL Units Q
106-93-4 1,2-Dibromoethane ND 0.020 0.010 ug/l
CAS No.Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 105%63-137%
41 of 57
FA5430666.1.3
Blank Spike Summary Page 1 of 1
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP70130-BS DD99724.D 1 05/21/18 NM 05/21/18 OP70130 GDD2891
The QC reported here applies to the following samples:Method: EPA 504.1
FA54306-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
106-93-4 1,2-Dibromoethane 0.25 0.25 100 70-130
CAS No.Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 103%63-137%
* = Outside of Control Limits.
42 of 57
FA5430666.2.1
Blank Spike Summary Page 1 of 1
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP70130-BS2 DD99725.D 1 05/21/18 NM 05/21/18 OP70130 GDD2891
The QC reported here applies to the following samples:Method: EPA 504.1
FA54306-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
106-93-4 1,2-Dibromoethane 0.25 0.25 100 70-130
CAS No.Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 104%63-137%
* = Outside of Control Limits.
43 of 57
FA5430666.2.2
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GUU1275-BS UU024709.D 1 05/23/18 SH n/a n/a GUU1275
GUU1275-BSD UU024710.D 1 05/23/18 SH n/a n/a GUU1275
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA54306-2
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/kg ug/kg %ug/kg %RPD Rec/RPD
71-43-2 Benzene 4160 3630 87 3870 93 6 70-130/25
100-41-4 Ethylbenzene 4160 3610 87 3870 93 7 70-130/25
1634-04-4 Methyl Tert Butyl Ether 4160 4070 98 4300 103 5 70-130/25
91-20-3 Naphthalene 4160 4140 99 4210 101 2 70-130/25
108-88-3 Toluene 4160 3660 88 3930 94 7 70-130/25
m,p-Xylene 8320 7190 86 7780 93 8 70-130/25
95-47-6 o-Xylene 4160 3560 86 3860 93 8 70-130/25
C5- C8 Aliphatics (Unadj.)12500 14100 113 15100 121 7 70-130/25
C9- C12 Aliphatics (Unadj.)8320 8110 97 9040 109 11 70-130/25
C9- C10 Aromatics (Unadj.)4160 3230 78 3660 88 12 70-130/25
C9- C10 Aromatics 4160 3230 78 3660 88 12 70-130/25
CAS No.Surrogate Recoveries BSP BSD Limits
460-00-4 BFB 91%98%70-130%
460-00-4 BFB 90%97%70-130%
* = Outside of Control Limits.
44 of 57
FA5430666.3.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GUU1276-BS UU024723.D 1 05/24/18 SH n/a n/a GUU1276
GUU1276-BSD UU024724.D 1 05/24/18 SH n/a n/a GUU1276
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA54306-1
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
71-43-2 Benzene 80 80.9 101 80.4 101 1 70-130/25
100-41-4 Ethylbenzene 80 82.8 104 81.4 102 2 70-130/25
1634-04-4 Methyl Tert Butyl Ether 80 92.4 116 92.0 115 0 70-130/25
91-20-3 Naphthalene 80 76.2 95 77.5 97 2 70-130/25
108-88-3 Toluene 80 82.9 104 81.9 102 1 70-130/25
m,p-Xylene 160 165 103 161 101 2 70-130/25
95-47-6 o-Xylene 80 83.0 104 80.5 101 3 70-130/25
C5- C8 Aliphatics (Unadj.)240 286 119 284 118 1 70-130/25
C9- C12 Aliphatics (Unadj.)160 200 125 197 123 2 70-130/25
C9- C10 Aromatics (Unadj.)80 78.3 98 73.8 92 6 70-130/25
C9- C10 Aromatics 80 78.3 98 73.8 92 6 70-130/25
CAS No.Surrogate Recoveries BSP BSD Limits
460-00-4 BFB 152%* a 146%* a 70-130%
460-00-4 BFB 142%* a 135%* a 70-130%
(a) Outside control limits.
* = Outside of Control Limits.
45 of 57
FA5430666.3.2
Matrix Spike Summary Page 1 of 1
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA54310-3MS UU024718.D 1 05/23/18 SH n/a n/a GUU1275
FA54310-3 UU024716.D 1 05/23/18 SH n/a n/a GUU1275
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA54306-2
FA54310-3 Spike MS MS
CAS No.Compound ug/kg Q ug/kg ug/kg %Limits
71-43-2 Benzene ND 6630 6810 103 70-130
100-41-4 Ethylbenzene ND 6630 6940 105 70-130
1634-04-4 Methyl Tert Butyl Ether ND 6630 7670 116 70-130
91-20-3 Naphthalene ND 6630 4210 64*70-130
108-88-3 Toluene ND 6630 6990 105 70-130
m,p-Xylene ND 13300 14100 106 70-130
95-47-6 o-Xylene ND 6630 7100 107 70-130
C5- C8 Aliphatics (Unadj.)ND 39800 26700 67*70-130
C9- C12 Aliphatics (Unadj.)ND 33100 14300 43*70-130
C9- C10 Aromatics (Unadj.)ND 19900 7270 37*70-130
C9- C10 Aromatics ND 19900 7270 37*70-130
CAS No.Surrogate Recoveries MS FA54310-3 Limits
460-00-4 BFB 147%*157%* a 70-130%
460-00-4 BFB 146%*152%* a 70-130%
(a) Outside control limits; however, sample is ND.
* = Outside of Control Limits.
46 of 57
FA5430666.4.1
Matrix Spike Summary Page 1 of 1
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA54409-4MS UU024739.D 1 05/24/18 SH n/a n/a GUU1276
FA54409-4 UU024737.D 1 05/24/18 SH n/a n/a GUU1276
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA54306-1
FA54409-4 Spike MS MS
CAS No.Compound ug/l Q ug/l ug/l %Limits
71-43-2 Benzene ND 80 78.9 99 70-130
100-41-4 Ethylbenzene ND 80 80.3 100 70-130
1634-04-4 Methyl Tert Butyl Ether 22.6 80 112 112 70-130
91-20-3 Naphthalene ND 80 80.6 101 70-130
108-88-3 Toluene ND 80 80.7 101 70-130
m,p-Xylene ND 160 159 99 70-130
95-47-6 o-Xylene ND 80 80.0 100 70-130
C5- C8 Aliphatics (Unadj.)ND 480 279 58*70-130
C9- C12 Aliphatics (Unadj.)ND 400 191 48*70-130
C9- C10 Aromatics (Unadj.)ND 240 73.1 30*70-130
C9- C10 Aromatics ND 240 73.1 30*70-130
CAS No.Surrogate Recoveries MS FA54409-4 Limits
460-00-4 BFB 144%*110%70-130%
460-00-4 BFB 135%*99%70-130%
* = Outside of Control Limits.
47 of 57
FA5430666.4.2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP70130-MS DD99736.D 1 05/21/18 NM 05/21/18 OP70130 GDD2891
OP70130-MSD DD99737.D 1 05/21/18 NM 05/21/18 OP70130 GDD2891
FA54228-2 DD99735.D 1 05/21/18 NM 05/21/18 OP70130 GDD2891
The QC reported here applies to the following samples:Method: EPA 504.1
FA54306-1
FA54228-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
106-93-4 1,2-Dibromoethane 0.019 U 0.244 0.22 90 0.244 0.27 110 20 70-130/25
CAS No.Surrogate Recoveries MS MSD FA54228-2 Limits
460-00-4 4-Bromofluorobenzene 103%112%99%63-137%
* = Outside of Control Limits.
48 of 57
FA5430666.5.1
Duplicate Summary Page 1 of 1
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA54310-3DUP UU024717.D 1 05/23/18 SH n/a n/a GUU1275
FA54310-3 UU024716.D 1 05/23/18 SH n/a n/a GUU1275
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA54306-2
FA54310-3 DUP
CAS No.Compound ug/kg Q ug/kg Q RPD Limits
71-43-2 Benzene ND ND nc 50
100-41-4 Ethylbenzene ND ND nc 50
1634-04-4 Methyl Tert Butyl Ether ND ND nc 50
91-20-3 Naphthalene ND ND nc 50
108-88-3 Toluene ND ND nc 50
m,p-Xylene ND ND nc 50
95-47-6 o-Xylene ND ND nc 50
C5- C8 Aliphatics (Unadj.)ND ND nc 50
C9- C12 Aliphatics (Unadj.)ND ND nc 50
C9- C10 Aromatics (Unadj.)ND ND nc 50
C5- C8 Aliphatics ND ND nc 50
C9- C12 Aliphatics ND ND nc 50
C9- C10 Aromatics ND ND nc 50
CAS No.Surrogate Recoveries DUP FA54310-3 Limits
460-00-4 BFB 145%* b 157%* a 70-130%
460-00-4 BFB 141%* b 152%* a 70-130%
(a) Outside control limits; however, sample is ND.
(b) Outside control limits.
* = Outside of Control Limits.
49 of 57
FA5430666.6.1
Duplicate Summary Page 1 of 1
Job Number:FA54306
Account:GRINCC GRI (Geological Resources Inc.)
Project:Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA54409-4DUP UU024738.D 1 05/24/18 SH n/a n/a GUU1276
FA54409-4 UU024737.D 1 05/24/18 SH n/a n/a GUU1276
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA54306-1
FA54409-4 DUP
CAS No.Compound ug/l Q ug/l Q RPD Limits
71-43-2 Benzene ND ND nc 50
100-41-4 Ethylbenzene ND ND nc 50
1634-04-4 Methyl Tert Butyl Ether 22.6 22.8 1 50
91-20-3 Naphthalene ND ND nc 50
108-88-3 Toluene ND ND nc 50
m,p-Xylene ND ND nc 50
95-47-6 o-Xylene ND ND nc 50
C5- C8 Aliphatics (Unadj.)ND ND nc 50
C9- C12 Aliphatics (Unadj.)ND ND nc 50
C9- C10 Aromatics (Unadj.)ND ND nc 50
C5- C8 Aliphatics ND ND nc 50
C9- C12 Aliphatics ND ND nc 50
C9- C10 Aromatics ND ND nc 50
CAS No.Surrogate Recoveries DUP FA54409-4 Limits
460-00-4 BFB 107%110%70-130%
460-00-4 BFB 96%99%70-130%
* = Outside of Control Limits.
50 of 57
FA5430666.6.2
SGS North America Inc.
Metals Analysis
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Matrix Spike and Duplicate Summaries
• Blank Spike and Lab Control Sample Summaries
• Serial Dilution Summaries
Orlando, FL
Section 7
51 of 57
FA543067
BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA54306
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
QC Batch ID: MP33772 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/18
MB
Metal RL IDL MDL raw final
Aluminum 200 14 14
Antimony 6.0 1 1
Arsenic 10 1.3 1.3
Barium 200 1 1
Beryllium 4.0 .2 .2
Cadmium 5.0 .2 .2
Calcium 1000 50 50
Chromium 10 1 1
Cobalt 50 .2 .2
Copper 25 1 1
Iron 300 17 17
Lead 5.0 1 1.1 -0.20 <5.0
Magnesium 5000 35 35
Manganese 15 .5 1
Molybdenum 50 .3 .3
Nickel 40 .4 .4
Potassium 10000 200 200
Selenium 10 2.4 2.9
Silver 10 .7 .7
Sodium 10000 500 500
Strontium 10 .5 .5
Thallium 10 1.1 1.4
Tin 50 .9 1
Titanium 10 .5 1
Vanadium 50 .5 .6
Zinc 20 3 4.4
Associated samples MP33772: FA54306-1
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
52 of 57
FA5430677.1.1
MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA54306
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
QC Batch ID: MP33772 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/18 05/22/18
FA54321-3 QC FA54321-3 Spikelot QC
Metal Original DUP RPD Limits Original MS MPFLICP2 % Rec Limits
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium anr
Calcium anr
Chromium anr
Cobalt
Copper
Iron
Lead 0.0 0.0 NC 0-20 0.0 488 500 97.6 80-120
Magnesium anr
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP33772: FA54306-1
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
53 of 57
FA5430677.1.2
MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA54306
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
QC Batch ID: MP33772 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/18
FA54321-3 Spikelot MSD QC
Metal Original MSD MPFLICP2 % Rec RPD Limit
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium anr
Calcium anr
Chromium anr
Cobalt
Copper
Iron
Lead 0.0 478 500 95.6 2.1 20
Magnesium anr
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP33772: FA54306-1
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 2
54 of 57
FA5430677.1.2
SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA54306
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
QC Batch ID: MP33772 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/18
BSP Spikelot QC
Metal Result MPFLICP2 % Rec Limits
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium anr
Calcium anr
Chromium anr
Cobalt
Copper
Iron
Lead 496 500 99.2 80-120
Magnesium anr
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP33772: FA54306-1
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
55 of 57
FA5430677.1.3
SERIAL DILUTION RESULTS SUMMARY
Login Number: FA54306
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
QC Batch ID: MP33772 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/18
FA54321-3 QC
Metal Original SDL 1:5 %DIF Limits
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium anr
Calcium anr
Chromium anr
Cobalt
Copper
Iron
Lead 0.00 0.00 NC 0-10
Magnesium anr
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP33772: FA54306-1
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
56 of 57
FA5430677.1.4
POST DIGESTATE SPIKE SUMMARY
Login Number: FA54306
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Hardy Mart 61; 4328 Hwy 11 S, Winterville, NC
QC Batch ID: MP33772 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/18
Sample Final FA54321-3 PS Spike Spike Spike QC
Metal ml ml Raw Corr.** ug/l ml ug/ml ug/l % Rec Limits
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead 9.8 10 45.4 0.2 2.5 50 90.8 80-120
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP33772: FA54306-1
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(**) Corr. sample result = Raw * (sample volume / final volume)
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
57 of 57
FA5430677.1.5