WA-27076_38241_CA_RPTS_20170530_MRP

MONITORING REPORT
for
Gasoline Dispenser Line Release at
NCDOT Martin County Maintenance Facility
1740 Prison Camp Road
Williamston, Martin County, NC

WBS Element: 30173.156

FACILITY ID: 0-024673
SITE RISK: H 165 D
NCDEQ INCIDENT NUMBER: 38241
LAND USE CLASSIFICATION: RESIDENTIAL

MAY 30, 2017

PREPARED FOR:
NORTH CAROLINA DEPARTMENT OF TRANSPORTATION

ATTN: MR. JEFFREY WALSTON, PE, CPESC, CPSWQ
ROADSIDE ENVIRONMENTAL UNIT
1557 MAIL SERVICE CENTER
RALEIGH, NORTH CAROLINA 27699-1557

CATLIN PROJECT NO. 211010

PREPARED BY:

CATLIN ENGINEERS AND SCIENTISTS
P. O. BOX 10279
WILMINGTON, NORTH CAROLINA 28404-0279
[phone]

CORPORATE GEOLOGY LICENSE NO. C-118
CORPORATE LICENSURE NO. FOR ENGINEERING SERVICES C-0585
Post Office Box 10279
Wilmington, North Carolina 28404-0279

Telephone: [phone]
Fax: [phone]

www.catlinusa.com

May 30, 2017

North Carolina Department of Environmental Quality
Washington Regional Office
Division of waste Management
Underground Storage Tank Section
Attn: Ms. Sylvia Newsome-Hunneke
943 Washington Square Mall
Washington, North Carolina 27889

Re: Monitoring Report
NCDOT Martin County Maintenance Facility
Gasoline Dispenser Line Release
1740 Prison Camp Road
Williamston, North Carolina 27892
WBS Element: 30173.156
NCDEQ Incident No. 38241
CATLIN Project No. 211010

Dear Ms. Newsome-Hunneke:

On behalf of the North Carolina Department of Transportation (NCDOT), CATLIN Engineers and
Scientists (CATLIN) is pleased to submit the latest Monitoring Report for the above referenced
site in Williamston, North Carolina.

If you should have any questions, concerns or require further actions, please contact Mr. Jeffrey
Walston at [phone] or CATLIN at [phone] at your convenience.

Sincerely,

Sean O’Neil, P.E. G. Richard Garrett, P.G.
Project Engineer Project Manager

Enclosures

cc: Mr. Jeffrey Walston, NCDOT (Enclosure w/CD)

DOT_MartinCntyGAS_Mtr_Ltr_2017

NCDOT; 211010_2017_MR CATLIN Engineers and Scientists
CATLIN Project No. 211010 May 2017
TABLE OF CONTENTS
PAGE
A. SITE INFORMATION 1
B. SITE HISTORY AND SOURCE CHARACTERIZATION 2
C. RECEPTOR INFORMATION 3
D. CURRENT SITE ASSESSMENT INFORMATION AND COMPARISION TO
HISTORICAL INFORMATION 4
E. CONCLUSIONS AND RECOMMENDATIONS 6
F. LIMITATIONS 6

TABLES

TABLE 1 SITE HISTORY – UST OWNER/OPERATOR INFORMATION
TABLE 2 SITE HISTORY – UST SYSTEM INFORMATION
TABLE 3 MONITORING WELL CONSTRUCTION AND GROUNDWATER ELEVATION
INFORMATION
TABLE 4 SUMMARY OF MONITORING WELL GROUNDWATER LABORATORY
RESULTS – STANDARD METHOD 6200B
TABLE 5 SUMMARY OF HISTORICAL MONITORING WELL GROUNDWATER
LABORATORY RESULTS – STANDARD METHOD 6200B

FIGURES

FIGURE 1A SITE VICINITY MAP
FIGURE 1B AERIAL PHOTOGRAPH WITH WATER SUPPLY WELLS
FIGURE 2 SITE MAP
FIGURE 3A GROUNDWATER CONTOURS AS OF SEPTEMBER 17, 2015
FIGURE 3B GROUNDWATER CONTOURS AS OF FEBRUARY 9, 2017
FIGURE 4 GROUNDWATER SAMPLE LOCATIONS AND SUMMARIZED RESULTS AS
OF FEBRUARY 2017

APPENDICES

APPENDIX A LABORATORY REPORT AND CHAIN-OF-CUSTODY
DOCUMENTATION
MONITORING REPORT
A. SITE INFORMATION
SITE IDENTIFICATION: Date of Report: May 30, 2017
Facility ID: 0-024673 UST Incident Number {if known}: _3::...:8=2:....:.4....:...1 __ _
Site Risk: H 165 D Site Rank: High Land Use Classification: Residential
Site Name: NCDOT Martin County Maintenance Facility (Gasoline Dispenser Line Release)
Site Location: 1740 Prison Camp Road (see Figures 1A and 1B)
Nearest City/Town: Williamston County: .....:M:..:..:..=a:....:rt.::.:..;m:.__ _______ _
CONTACTS: (see Table 1)
North Carolina Department of Transportation (NCDOT) Fleet & Material
UST Owner: Management Unit
Address: 4809 Beryl Road Raleigh, NC 27606 Phone: [phone]
UST Operator: NCDOT Fleet & Material Management Unit
Address: 4809 Beryl Road Raleigh, NC 27606 Phone: [phone]
Property Owner: NCDOT Martin County (Division 1)
Address: 1740 Prison Camp Road Williamston, NC 27892 Phone: [phone]
Property Occupant: NCDOT Martin County (Division 1)
Address: 1740 Prison Camp Road Williamston, NC 27892 Phone: [phone]
Consultant/Contractor: CATLIN Engineers and Scientists (CATLIN)
Address: 220 Old Dairy Road, Wilmington, NC 28405 Phone: [phone]
Analytical Laboratory: Pace Analytical Services, Inc. (Pace) State Cert. No. 12
9800 Kincey Ave. Suite 100
Address: Huntersville, NC 28078 Phone: [phone] --------------------
RELEASE INFORMATION:
Date Discovered: _S.:::.e.=.Jpc..:t:.=.e:.:..m:.:::b-=.e.:_r 2='!....:2::..::0:...:1:-=0 ________ _
Longitude: W -77.095822822° Latitude: .....:Nc..:......=3-=.5.:...:.8:-=3....:...16-=-1.:....:5:...:9:.....:4....:...7_0 __________________ _
Estimated Quantity of Release: _U.=..:....:.nk:...:.:n..:..:o:....:.w.:...:.n.:..__-::------,----------------
Cause of Release: Unknown, possibly resulting from utility work in the area.
Source of Release {e.g. Piping/UST}: Gasoline piping (supply line)
Sizes and contents of UST system{s} from
which the release occurred: (see Table 2) 15,000 gallon gasoline UST
Criteria Used to No contaminant concentrations above the established Gross Contaminant
Classify Risk: Levels (GCLs), potable well(s) within 1,000 feet
I, Sean O'Neil
CATLIN Engineers and Scientists, o c a e information contained in this report is
correct and accurate to the best of my knowledge.
(Please Affix Seal and Signature)
NCDOT; 211010_2017_MR
CATLIN Project No. 211010
CATLIN Engineers and Scientists
May 2017

NCDOT; 211010_2017_MR CATLIN Engineers and Scientists
CATLIN Project No. 211010 2 May 2017
B. SITE HISTORY AND SOURCE CHARACTERIZATION

1. Site Operations and History

Table 1 includes a summary of the underground storage tank (UST)
owner/operator information and Table 2 includes site UST system information.
The UST dispenser canopy, line layout and approximate area of excavation
are indicated on Figure 2.
2. Contaminant Source Inventory

According to NCDOT, a gasoline line leak was discovered in 2010 during a
UST system pressure test. Soils around the identified leak were excavated
and the line leak was repaired.

3. Previous Investigations and Initial Abatement

A “24-Hour Release and UST Leak Reporting Form (UST 61 Form)” was
submitted to the North Carolina Department of Environmental Quality
(NCDEQ) by NCDOT on September 2, 2010. A Limited Site Assessment
(LSA) investigation was conducted by CATLIN and a LSA report dated
August 19, 2011 was submitted to NCDEQ. Since the submittal of the LSA,
several groundwater sampling events have been conducted at this site.
Results from these sampling events were submitted to NCDEQ in
subsequently prepared reports.

4. Site Characteristics

Currently, potable water is available to the subject site and surrounding
properties (within a 1,000 foot radius) from a public municipal water system.
There are no water supply wells within 250 feet of the source area. Initially,
during the LSA investigation, sixteen water wells were identified as shown on
Figure 1B. Interviews with occupants and subsequent follow-up with the Town
of Williamston indicate there are currently three (3) potable wells within the
1,000 foot radius. Water supply well information is summarized in Section C of
this report. Potable wells are identified on the table in Section C of this report
and their locations are illustrated on Figure 1B.

5. Surface Water

The nearest natural surface water body is an intermittent, unnamed stream
approximately 1,200 feet northeast of the site (refer to Figure 1A).

6. Wellhead Protection Areas

According to the NCDEQ webpage, updated October 27, 2016, the subject site
is not located within an approved wellhead protection plan area. The closest
public water supply well is located approximately two (2) miles north-northeast
of the subject site.

NCDOT; 211010_2017_MR CATLIN Engineers and Scientists
CATLIN Project No. 211010 3 May 2017
7. Deep Aquifers in the Coastal Plain Physiographic Region

According to the NCDEQ Division of Water Resources online Framework
Query cross-section results, the surficial aquifer is underlain by the Yorktown
confining unit and Yorktown aquifer, the Peedee confining unit and aquifer,
and the Upper and Lower Cape Fear confining units and aquifers.

8. Subsurface Structures

Site surveys conducted during the LSA revealed no evidence or reports of
subsurface structures accessible for humans (basements, vaults, etc.)
adjacent to the source area. Figure 2 illustrates the subsurface utility lines at
the subject site that were identified during LSA activities.

C. RECEPTOR INFORMATION

Currently there are three (3) potable water supply wells within 1,000 feet of the
source area. These wells (numbers 5, 10 and 16) are identified on Figure 1B and
indicated in bold on the following table.

Owner /
Occupant Address Phone # Well
Use
Well
Depth
Type of
Well
Well
Screen
Interval
Distance
from
Source
Figure 1B
Location
Key
Barbara
Rogers
1788 Prison
Camp Rd. Unknown Not in
Use Unknown Unknown Unknown 400 feet
Southwest 1
NC Forest
Service
1169
Kekukee
Rd.
252-331-
4781
Not in
Use Unknown 4-inch
galvanized Unknown 850 feet
West 2
Garland
Craft
1731 Prison
Camp Rd
252-792-
5393
Not in
Use Unknown Unknown Unknown
263 feet
South-
Southeast
3
Cecil Bonds
/ Rebecca
Thomas
1685 Prison
Camp Rd.
252-792-
2306
Not In
Use Unknown Unknown Unknown
259 feet
East-
Southeast
4
Jorge
Villigas /
David
Williams
1671
Prison
Camp Rd.
252-217-
7880 Potable Un-
known Unknown Un-
known
350 feet
East-
Southeast
5
Jeffrey
Whitley
1651 Prison
Camp Rd. Unknown Not in
Use Unknown Unknown Unknown 400 feet
East 6
Nathan
Mizelle
1797 Prison
Camp Rd.
252-792-
2861
Not in
Use Unknown Unknown Unknown 600 feet
South 7
Nathan
Mizelle
1829 Prison
Camp Rd. Unknown Not in
Use Unknown Unknown Unknown
650 feet
South-
Southwest
8
Gregory Kay
1710
Kekukee
Rd.
Unknown Not in
Use Unknown Unknown Unknown
1,000 feet
South-
Southwest
9
John
Dunlow
1690
Kekukee
Rd.
252-802-
0499 Potable Un-
known Unknown Un-
known
1,000 feet
West 10

NCDOT; 211010_2017_MR CATLIN Engineers and Scientists
CATLIN Project No. 211010 4 May 2017
Owner /
Occupant Address Phone # Well
Use
Well
Depth
Type of
Well
Well
Screen
Interval
Distance
from
Source
Sheet 1B
Location
Key
Gordon
Knox
Knox
Mobile
Home Park
– Prison
Camp Rd.
252-217-
5484
Not in
Use Unknown Unknown Unknown 800 feet
South 11
Martin
County
Community
College /
Equine
Barns
1161
Kekukee
Park Rd.
252-792-
1521
Not in
Use Unknown Unknown Unknown 800 feet
Northwest 12
Robert
Warren
1605 Prison
Camp Rd. Unknown Not in
Use Unknown Unknown Unknown 900 feet
East 13
Donnie
Whitley
1210
Pineview
Road
Unknown Irrigation Unknown Unknown Unknown 950 feet
East 14
Daniel
Casey
1250
Pineview
Road
Unknown Not in
Use Unknown Unknown Unknown 850 feet
Southeast 15
William
Roberson
1211
Pineview
Road
252-792-
8409 Potable Un-
known Unknown Un-
known
750 feet
East-
Southeast
16

There are additional supply wells located within 1,000 feet of the site that are either
not in service or utilized for irrigation. Public water is available for surrounding
properties; however, utilization of the water supply system is voluntary at this time.

Due to the location of well 16 and based on the current municipal water supply line
locations, it would be difficult and expensive to hook the property to municipal water.
CATLIN had discussions with NCDEQ and based on the distance of well 16 from
the project site and the orientation of the well (in a side gradient groundwater flow
direction), it was determined in an email correspondence dated December 31, 2015,
that potable well 16 could be left in place and only wells 5 and 10 needed to be
disconnected in order to request the site be re-ranked to a Low Risk Site.

D. CURRENT SITE ASSESSMENT INFORMATION AND COMPARISON TO
HISTORICAL INFORMATION

The field activities associated with this monitoring report were completed on
February 9, 2017. All site monitoring wells were gauged to determine water table
elevations and groundwater samples were collected for laboratory analysis per
Standard Method (SM) 6200B. No free-phase product was detected during the
February 2017 sampling event or any prior sampling events. The site layout and
monitoring well network is illustrated on Figure 2.

NCDOT; 211010_2017_MR CATLIN Engineers and Scientists
CATLIN Project No. 211010 5 May 2017
Groundwater Gauging

Groundwater gauging data from the February 2017 gauging event, along with
historical gauging data, are summarized in Table 3. Groundwater contours were
computer generated by entering groundwater elevation data into a contouring
software program (AutoCAD Land Development).

During the February 2017 gauging event, the depths to groundwater in the shallow
aquifer monitoring wells across the project site ranged from 2.10 feet to 4.98 feet
below top of casing. Shallow groundwater contours for the previous sampling event
(September 2015) and current sampling event (February 2017) are illustrated on
Figures 3A and 3B, respectively. The February 2017 surficial groundwater
migration trend is primarily towards the west, which is generally consistent with
previous gauging events.

Groundwater Sampling

CATLIN personnel collected groundwater samples from all site monitoring wells on
February 9, 2017. New, disposable nitrile gloves were worn during sampling
activities. The depth to groundwater was measured with an electronic water level
indicator and the volume of water in each well was calculated. Water was then
purged from each well utilizing new, disposable plastic bailers and twine. After
purging a minimum of three volumes of well water, a groundwater sample was
poured directly from the bailer into the appropriate, laboratory provided glassware.

After collection, groundwater samples were placed on ice for transport, under proper
Chain-of-Custody protocols, to Pace Analytical Services, Inc. in Huntersville, NC.
Groundwater samples were analyzed for diesel and gasoline constituents per SM
6200B.

Results for the most recent sampling activities (February 9, 2017) are summarized
in Table 4, and illustrated on Figure 4. No compound concentrations were revealed
above the Gross Contaminant Levels (GCLs). Groundwater laboratory results
revealed dissolved Benzene concentrations in monitoring wells MW01 (520 ug/L)
and MW02 (2.8 ug/L) above the established North Carolina Administrative Code
(NCAC) T15A:02L Groundwater Quality Standards (2L GWQS) of 1 ug/L. A
dissolved Naphthalene concentration above the 2L GWQS of 6 ug/L was detected
in the groundwater sample collected from MW01 (38.6 ug/L). Several other SM
6200B parameters were detected in the groundwater samples collected from MW01
and MW02; however, these concentrations were all below their respective 2L
GWQS. A dissolved Methyl-tert-butyl ether (MTBE) concentration of 0.66 ug/L was
detected in the sample collected from monitoring well MW03, which is below the 2L
GWQS of 20 ug/L. No contaminant concentrations were detected above the
laboratory reporting limits in the groundwater sample collected from MW04.

Table 5 summarizes historical SM 6200B analytical results for site monitoring wells
MW01 through MW04. Contaminant concentrations that have been detected above

NCDOT; 211010_2017_MR CATLIN Engineers and Scientists
CATLIN Project No. 211010 6 May 2017
2L GWQS have generally decreased since the initial sampling event. The complete
laboratory analytical report is provided in Appendix A.

E. CONCLUSIONS AND RECOMMENDATIONS

1. Conclusions

Based on the findings of this monitoring report, the following conclusions are
made:
 Historically, no free-phase product has ever been detected when gauging
or sampling the site.
 Groundwater volatile contaminant concentrations were detected above
corresponding 2L GWQS in the groundwater samples collected from
MW01 (Benzene and Naphthalene) and MW02 (Benzene).
 It is likely that elevated groundwater concentrations in MW02 are the
result of contaminant migration along a preferential pathway created by
the utility line and backfill.
 Laboratory analytical results did not reveal any groundwater contaminant
concentrations above the GCLs. Historically, no GCL exceedances have
been reported at this site.
 Groundwater volatile compound concentrations have clearly decreased
over time.
2. Recommendations

Due to the low levels of groundwater contamination (below GCLs), CATLIN
recommends disconnecting/abandoning the potable water supply wells 5 and
10, if possible, and connecting the properties to municipal water. If wells 5
and 10 are disconnected/abandoned, CATLIN will request the site be re-
ranked to a Low Risk Site. As previously mentioned, based on discussions
with NCDEQ, well 16 does not need to be disconnected at this time. In the
meantime, CATLIN recommends continuing with annual groundwater
sampling.

F. LIMITATIONS

The field and groundwater data evaluated as part of this investigation only provides
isolated data points and may not represent conditions at every location in the project
area. Analyses and conclusions of this report, being based on interpolation
between data points at the project area, may not be completely representative of all
site conditions. Conclusions and recommendations of this investigation and report
are based on the best available data in an effort to comply with current regulatory
requirements.

NCDOT; 211010_2017_MR CATLIN Engineers and Scientists
CATLIN Project No. 211010 May 2017

TABLES

Page 1 of 1
NCDOT; TABLE1OwnerOperator CATLIN Engineers and Scientists
CATLIN Project No.: 211010 May 2017
TABLE 1

SITE HISTORY
UST OWNER/OPERATOR INFORMATION

Incident Number and Name: Facility ID#:
38241 - NCDOT Martin County Maintenance Facility
(Gasoline Dispenser Line Release) 0-024673

UST ID Numbers:
160-101
160-102
160-103
Facility ID Number: 0-024673
Name of Owner Dates of Operation
NCDOT Fleet & Material Management Unit 4/30/1990 to Present
Street Address
4809 Beryl Road
City State Zip Telephone Number
Raleigh NC 27606 [phone]
Name of Operator Dates of Operation
NCDOT Martin County Maintenance 4/30/1990 to Present
Street Address
1740 Prison Camp Road
City State Zip Telephone Number
Williamston NC 27892 (252)-792-2503
Incident Number: 38241
Name of Other Responsible Party Dates of Release(s)
None Unknown – Discovered September 2, 2010
Street Address
Not Applicable
City State Zip Telephone Number
Not Applicable Not
Applicable
Not
Applicable
Not Applicable

Page 1 of 1
SITE HISTORY - UST SYSTEM INFORMATION*
UST ID
Number
Last
Contents
Previous
Contents
Capacity
(gallons)
Construction
Details
Tank
Dimensions
Description
of Associated
Piping
Date
Installed Status of UST
Was Release
Associated With
UST System?
1 Gasoline Unknown 6,300 Unknown Unknown Unknown 8/29/1973 Removed
4/30/1990 No
2 Kerosene Unknown 1,000 Unknown Unknown Unknown 8/29/1974 Removed
4/30/1990 No
3 Waste Oil Unknown 3,000 Unknown Unknown Unknown 8/29/1972 Removed
4/30/1990 No
4 Gasoline Unknown 10,000 Unknown Unknown Unknown 8/29/1974 Removed
4/30/1990 No
5 Diesel Unknown 10,000 Unknown Unknown Unknown 8/29/1975 Removed
4/30/1990 No
6 Waste OIl Unknown 3,500 Unknown Unknown Unknown 1/1/1964 Removed
10/31/1994 No
160-101 Gasoline None 15,000 Unknown Unknown Unknown 4/30/1990 Active Yes - Piping Only
160-102 Diesel None 15,000 Unknown Unknown Unknown 4/30/1990 Active No
160-103 Waste Oil Unknown 2,000 Unknown Unknown Unknown 4/30/1990 Active No
* = UST System information reported by MACTEC as obtained from NCDEQ online UST registry
TABLE 2
Incident Number and Name: 38241 - NCDOT Martin County Maintenance Facility (Gasoline Dispenser Line Release)
Facility ID#:
0-024673
NCDOT; TABLE2SystemInfo
CATLIN Project No. 211010
CATLIN Engineers and Scientists
May 2017
Page 1 of 1
MONITORING WELL CONSTRUCTION AND GROUNDWATER ELEVATION INFORMATION
Facility ID#:
0-024673
Well ID Date
Installed
Date Water
Level
Measured
Well Casing
Depth
(ft. BLS)
Screened
Interval
(x to y ft.
BLS)
Bottom of
Well
(ft. BLS)
Top of
Casing
Elevation*
(ft.)
Depth to
Ground-
water
(ft.)
Groundwater
Elevation
(ft.)
5/13/11 4.43 70.66
12/8/11 4.92 70.17
6/17/13 5.04 70.05
12/5/13 7.67 67.42
8/28/14 4.92 70.17
9/17/15 5.63 69.46
2/9/17 4.98 70.11
5/13/11 3.43 70.97
12/8/11 2.47 71.93
6/17/13 3.01 71.39
12/5/13 2.51 71.89
8/28/14 2.38 72.02
9/17/15 3.49 70.91
2/9/17 2.10 72.30
5/13/11 4.05 70.87
12/8/11 3.55 71.37
6/17/13 4.07 70.85
12/5/13 3.83 71.09
8/28/14 3.39 71.53
9/17/15 4.85 70.07
2/9/17 3.65 71.27
5/13/11 2.90 72.22
12/8/11 3.15 71.97
6/17/13 3.35 71.77
12/5/13 3.00 72.12
8/28/14 3.20 71.92
9/17/15 4.72 70.40
2/9/17 2.79 72.33
No free-phase product has been measured at the site.
ft. BLS = Feet Below Land Surface
TABLE 3
Incident Number and Name:
38241 - NCDOT Martin County Maintenance Facility (Gasoline Dispenser Line
Release)
MW01 5/12/11 2 2 - 12 12 75.09
74.40
MW03 5/12/11 2 2 - 12 12 74.92
MW02 5/12/11 2 2 - 12 12
75.12MW045/12/11 2 2 - 12 12
NCDOT; TABLE3Wellcon-Grndwtr
CATLIN Project No. 211010
CATLIN Engineers and Scientists
May 2017
Page 1 of 1
TABLE 4
SUMMARY OF MONITORING WELL GROUNDWATER LABORATORY RESULTS - STANDARD METHOD 6200B
Incident Number and Name: 38241 - NCDOT Martin County Maintenance Facility (Gasoline Dispenser Line Release) Facility ID: 0-024673
Sample
ID
Date
Collected
MW01 MW-01 2/9/2017 111 40.9 520 146 20.2 38.6 283 25.7 375 4.2 <1.0 1.6 J
MW02 MW-02 2/9/2017 6.3 2.4 2.8 3.5 0.45 J 1.7 J 1.3 1.3 8.6 <0.25 <0.25 ND
MW03 MW-03 2/9/2017 <0.25 <0.25 <0.25 <0.25 <0.25 <1.0 <0.25 <0.25 <0.75 0.66 <0.25 ND
MW04 MW-04 2/9/2017 <0.25 <0.25 <0.25 <0.25 <0.25 <1.0 <0.25 <0.25 <0.75 <0.25 <0.25 ND
All results in micrograms per liter (mg/L).
< = Less than Method Detection Limit
ND= Not detected at or above the adjusted reporting limit
GCL = Gross Contaminant Level
2L GWQS = North Carolina Adminstrative Code Title 15A 2L Groundwater Quality Standards
Bold results indicate concentrations above 2L GWQS.
J = Estimated concentration abovethe adjusted Method Detection Limit and below the adjusted Report Limit
20,000
20
Varies
Varies
30,000
70
85,500
500
6,900
70
6,000
6
260,000
600
84,500
600
25,000
70
5,000
1
25,000
400
28,500
400
GCL (mg/L)
2L GWQS (mg/L)Methyl-tert-butyl ether (MTBE)All Other 6200B Parametersn-PropylbenzeneTotal Xylenesn-ButylbenzeneIsopropylbenzene (Cumene)NaphthaleneTolueneEthylbenzeneBenzene1,3,5-Trimethylbenzene1,2,4-TrimethylbenzeneWell ID
Contaminant
of Concern
NCDOT;TABLE4WELLS6200B
CATLIN Project No. 211010
CATLIN Engineers and Scientists
May 2017
Page 1 of 2
TABLE 5
SUMMARY OF HISTORICAL MONITORING WELL GROUNDWATER LABORATORY RESULTS - STANDARD METHOD 6200B
Incident Number and Name: 38241 - NCDOT Martin County Maintenance Facility (Gasoline Dispenser Line Release) Facility ID: 0-024673
Sample
ID
Date
Collected
MW01 5/13/2011 518 138 3,030 <0.620 540 33.3 162 3,690 76.6 2,744 <0.576 BMDL
MW-01 12/8/2011 58.8 16.8 650 <0.155 20.2 7.22 11.9 76 6.82 163.5 <0.144 10.28
MW-01 6/17/2013 163 26.9 900 <0.25 96.2 18.7 34.2 166 20.4 383.2 1.6 BMDL
MW-01 12/5/2013 165 23.6 902 <0.50 81.5 25.9 32.7 80.0 21.0 257.3 <0.50 ND
MW-01 8/28/2014 187 34.5 785 <0.50 129 29.7 45.1 203 28.1 386 1.7 ND
MW-01 9/17/2015 79.5 23.4 665 <2.5 81.2 16.4 27.3 141 15.9 187.1 <2.5 2.6
MW-01 2/9/2017 111 40.9 520 <1.0 146 20.2 38.6 283 25.7 375 4.2 1.6 J
MW02 5/13/2011 202 45.9 1,320 2.34 188 7.78 62.0 1,620 21.4 990 3.32 BMDL
MW-02 7/27/2011 76.0 20.8 740 <20.0 74.4 <20.0 <20.0 54.6 <20.0 249 <20.0 BMDL
MW-02 12/8/2011 28.6 6.14 259 <0.155 17.9 3.05 12.5 2.75 5.00 73.3 <0.144 5.77
MW-02 6/17/2013 2.4 0.74 247 1.1 1.7 0.45 J 2.5 0.25 J 0.49 J 2.6 1.1 BMDL
MW-02 12/5/2013 2.1 <0.50 182 0.77 0.60 0.75 2.6 <0.50 <0.50 2.9 0.84 ND
MW-02 8/28/2014 0.58 0.57 59.8 <0.50 0.82 <0.50 <2.0 <0.50 <0.50 <1.50 <0.50 ND
MW-02 9/17/2015 <0.50 <0.50 4.2 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <1.50 <0.50 ND
MW-02 2/9/2017 6.30 2.4 2.8 <0.25 3.50 0.45 J 1.7 J 1.3 1.3 8.6 <0.25 ND
MW03 5/13/2011 <0.0961 <0.113 <0.113 <0.155 <0.0877 <0.0869 <0.0855 0.140 J <0.113 <0.2694 0.760 BMDL
MW-03 12/8/2011 <0.0961 <0.113 <0.113 <0.155 <0.0877 <0.0869 <0.0855 <0.133 <0.113 <0.2694 <0.144 BMDL
MW-03 6/17/2013 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <1.0 <0.25 <0.25 <0.75 1.2 BMDL
MW-03 12/5/2013 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <1.50 1.5 ND
MW-03 8/28/2014 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <1.50 <0.50 ND
MW-03 9/17/2015 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <1.50 2.7 ND
MW-03 2/9/2017 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <1.0 <0.25 <0.25 <0.75 0.66 ND
MW03
GCL (mg/L)
2L GWQS (mg/L)
Contaminant
of Concern
Well ID
MW01
MW02 1,2,4-Trimethylbenzene28,500
400 1,3,5-Trimethylbenzene25,000
400 Benzene5,000
1 NaphthaleneEthylbenzeneDiisopropyl EtherIsopropylbenzene (Cumene)70,000
70
84,500
600
25,000
70
6,000
6 Toluene30,000
70
85,500
500
20,000
20
Varies
VariesAll Other SM 6200B Parametersn-PropylbenzeneMethyl-tert-butyl ether (MTBE)Total Xylenes260,000
600
NCDOT; TABLE5Historical
CATLIN Project No. 211010
CATLIN Engineers and Scientists
May 2017
Page 2 of 2
TABLE 5
SUMMARY OF HISTORICAL MONITORING WELL GROUNDWATER LABORATORY RESULTS - STANDARD METHOD 6200B
Incident Number and Name: 38241 - NCDOT Martin County Maintenance Facility (Gasoline Dispenser Line Release) Facility ID: 0-024673
Sample
ID
Date
Collected
GCL (mg/L)
2L GWQS (mg/L)
Contaminant
of Concern
Well ID
1,2,4-Trimethylbenzene28,500
400 1,3,5-Trimethylbenzene25,000
400 Benzene5,000
1 NaphthaleneEthylbenzeneDiisopropyl EtherIsopropylbenzene (Cumene)70,000
70
84,500
600
25,000
70
6,000
6 Toluene30,000
70
85,500
500
20,000
20
Varies
VariesAll Other SM 6200B Parametersn-PropylbenzeneMethyl-tert-butyl ether (MTBE)Total Xylenes260,000
600
MW04 5/13/2011 <0.0961 <0.113 1.16 <0.155 <0.0877 <0.0869 <0.0855 0.640 <0.113 <0.352 J <0.144 BMDL
MW-04 12/8/2011 <0.0961 <0.113 <0.113 <0.155 <0.0877 <0.0869 <0.0855 <0.133 <0.113 <0.2694 <0.144 BMDL
MW-04 6/17/2013 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <1.0 <0.25 <0.25 <0.75 <0.25 BMDL
MW-04 12/5/2013 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <1.50 <0.50 ND
MW-04 8/28/2014 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <1.50 1.0 ND
MW-04 9/17/2015 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <1.50 <0.50 ND
MW-04 2/9/2017 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <1.0 <0.25 <0.25 <0.75 <0.25 ND
All results in micrograms per liter (mg/L).
< = Less than method detection limit or reporting limit
BMDL = Below Method Detection Limit
GCL = Gross Contaminant Level
2L GWQS = North Carolina Administrative Code Title 15A 2L Groundwater Quality Standards
J = Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
Bold results indicate concentrations above 2L GWQS.
ND= Not detected at or above the adjusted reporting limit.
MW04
NCDOT; TABLE5Historical
CATLIN Project No. 211010
CATLIN Engineers and Scientists
May 2017

NCDOT; 211010_2017_MR CATLIN Engineers and Scientists
CATLIN Project No. 211010 May 2017

FIGURES

2,000 0 2,000 4,0001,000 Feet
SOIL STOCKPILEAREA(NCDOT YARD)PRISON CAMP ROADT
Y
N
E
R

R
O
A
DKEKUKEE PARK ROADUS HWY 64
SCALE
Source: Terrain Navigator Pro Quadrangle, (Williamston, NC 1982)/
SITE LOCATION
DESCRIPTION:
PREPARED BY:SCALE:TITLE:COUNTY:
FA No:
ST PROJ:WBS ELEM:FIGURE No:NCDOT MARTIN COUNTYMAINTENANCE FACILITYGASOLINE RELEASE SITE
SITE VICINITYMAPAS SHOWN
MARTINN/AN/A30173.156 1A
211010
ENGLISH
400 0 400 800200Feet1000FOOTRADIUS
SITE LOCATION
PRISON CAMP ROADT
Y
N
E
R

R
O
A
DKEKUKEE PARK ROAD2
9
1
4 5
6
13
1178
1431215 1610
SCALE
Source: Terrain Navigator Pro Orthophotos, (Williamston, NC 2009) Parcels provided by Martin County GIS, 2011./
DESCRIPTION:
PREPARED BY:SCALE:TITLE:COUNTY:FA No:
ST PROJ:WBS ELEM:FIGURE No:
NCDOT MARTIN COUNTYMAINTENANCE FACILITYGASOLINE RELASE SITE
AERIAL PHOTOGRAPH WITH WATER SUPPLY WELLSAS SHOWN
MARTINN/AN/A30173.156 1B
211010
ENGLISH
LEGEND
WATER SUPPLY WELL LOCATION!(W
NOTE: Water Supply Well numbers correspond to LSA Report Section D.1 (Water Supply Well Table)
LEGEND
EXISTING OESCRIPTlON
-$-SOIL BORING/SAMPLE
S MONITORING WELL (TYPE II)
X::X FIRE HYDRANT
NOTES:
1. MAP ADAPTED FROM GPS DATA COLLECTED
BYCAn.IN.
GRASS
GRASS
CESCRIP'TlON:
NCOOT MARTIN COUNTY
MAIN'Tl!NANCE FACILITY
GASOLINE RB..EASE SITE
~CATLIN
Engineers and Scientists
220 Old O..lry Road WiiMingtotl, NC 28"05
Corpouit•lkt!fl!MI,. ti~lor &lgi~S.,..ku~~
PROJECT NO.: 211010
20
FIGURENO. Z
L"'WBS:~· =---....oi!301~7S.~158!!-I 'f.I.P. NO.: NfA f::-OO~U~NTY:~.;;....._ ___ MIIRT......:..::IN"-1
TITlE:
SITE MAP
DISPENSER
ISLAND
CANOPY
10 0
SCALE IN FEET
N
20
S:\CAO\DWG\2011\211010\FEBRUARY 2017\FIGURE2.DWG
NOTES:
LEGEND
EXISTING DESCRIPTION
S MONITORING WELL (TYPE II)
t:):. FIRE HYDRANT
I GROUNDWATER FLOW DIRECTION
( )
GROUNDWATER CONTOUR (0.1 FT. INTERVAL)
GROUNDWATER ELEVATION (FEET)
1. MAP ADAPTED FROM GPS DATA COLLECTED BY CATLIN.
2. ELEVATION BASED ON MEAN SEA LEVEL.
3. "-MW01 GROUNDWATER ELEVATION CONSIDERED ANOMALOUS, LIKELY
EFFECTED BY ADJACENT UTILITIES AND WAS NOT USED FOR CONTOURING.
I
MW03 I
(70.07) s
GRASS
CESCRIP'TlON:
NCOOT MARTIN COUNTY
MAIN'T1!'NANCE FACILITY
GASOLINE RB..EASE SITE
~CATLIN
Engineers and Scientists
220 Old ~lry Roild WiJmlngtotl, NC 28"05
Cotpor•t.lk.•M41"' Ho, 104' &l{jl~kvk~ C-oM•
PROJECTNO.: 211010
APPROXIMATE AREA OF PREVIOUS
.~-=-----EXCAVATION AROUND FUEL LINE RELEASE
GRASS
20
..-~-----= 1-'-'FIG:=.=U=RE=N0.=-----=~'---1 ~ NGIJa~::~;:;;.P_''=::NO:-.: -----'301~7S.~:H ~·COUNTY: MMTIN
TITlE:
GROUNDWATER CONTOURS
AS OF SEPTEMBER 17, 2015
DISPENSER
ISLAND
CANOPY
10 0
SCALE IN FEET
N
20
S:\CAD\DWG'\2011'\211010\FEBRUARY 2017\FIGURE3A.DWG
LEGEND
EXISTING
( )
NOTES:
DESCRIPTION
MONITORING WELL (TYPE II)
FIRE HYDRANT
GROUNDWATER FLOW DIRECTION
GROUNDWATER CONTOUR (0.1 FT. INTERVAL)
GROUNDWATER ELEVATION (FEET)
1. MAP ADAPTED FROM GPS DATA COLLECTED BY CATLIN.
2. ELEVATION BASED ON MEAN SEA LEVEL.
3. "-MW01 GROUNDWATER ELEVATION CONSIDERED ANOMALOUS, LIKELY
EFFECTED BY ADJACENT UTILITIES AND WAS NOT USED FOR CONTOURING.
' \
' ' ' \ '
MW04 s (72.33)
' ' \ ' ' ' ' \
CESCRIP'TlON:
GRASS
APPROXIMATE AREA OF PREVIOUS
NCOOT MARTIN COUNTY
MAIN'T1!'NANCE FACILITY
GASOLINE RB..EASE SITE
~CATLIN
Engineers and Scientists
220 Old ~lry Roild WiJmlngtotl, NC 28"05
Cotpor•t.lk.•M41"' Ho, 104' &l{jl~kvk~ C-oM•
PROJECTNO.: 211010
. .-1-~--EXCAVATION AROUND FUEL LINE RELEASE
GRASS
20
FIGURE NO. 3B ~ NGLiaF-~;:;:,,P~ .. N0=.:---'301~7S.~:!j!-l ~·COUNTY: MMTIN
TITlE:
GROUNDWATER CONTOURS
AS OF FEBRUARY 9, 2017
DISPENSER
ISLAND
CANOPY
10 0
SCALE IN FEET
N
20
S:\CAD\DWG'\2011\211010\FEBRUARY 2017\FIGURE3B.DWG
Olnlarrinart
c:l O:lnoem -
'N!IIID
$anpe Cite
10 O:llleded
M/\01 MN01 2/9'a:rl7
1\N\.02 MN{]2 2/9'a:rl7
M/\03 MN03 2/9'a:rl7
Ml\04 I\NIJ04 2/9'a:rl7
a_~~
,oa rest.lts in rricrc::gcms perli1er ~·
<=Less tha1 M3lhcx:l Deledi01 Urrit
I I l' l' ~ ~ ~ ~
N (1) .,.: .,.:
111 40.9
6.3 2 4
<025 <025
<0.25 <0.25
28,00:> ~(XX)
<IX) <IX)
I'D= 1\t:X detected et or c:tx:r-e 1t'eac!usted rep:;ytirg lirrit
ro.. = Qoss CortaTinart l.el.el
~ I ~! ~ j IV ~
~ ~
SD 143 Zl2 38.6
2 8 3.5 Q45J 1.7J
<025 <025 <025 <1.0
<025 <0.25 <0.25 <1.0
S,CXX> ~00) ~(XX) 6,CXX>
1 600 70 6
2L G/ICS= N:rth Ca'dina Jlchins1rai-.e O:x:le li~e 156.21.. ~ Q.aity9a"dcros
B:*l resl.Ats incicate 001 1001 CJ atic:rs c:tx:r-e 2L G/ICS.
I ~ i j2
283 25.7
1.3 1.3
<0.25 <025
<025 <025
:B), (XX) ~(XX)
600 70
J =Estimated 001 1001 lbaicn ab:::>.elhe acjusted M3lhcx:l Deledicn Urrit a1d belONthe acjusted Report Urrit
LEGEND
EXISTING DESCRIPTION
S MONITORING WELl. (TYPE II)
;(): FIRE HYDRANT
NOTES:
1. MAP ADAPTED FROM GPS DATA COLLECTED
BY CATLIN.
E 'ttl ~
~ f I ~ J ~ II ~ ~ ~ ~
375 4.2 <1.0 1.6J
86 <025 <0.25 1\0
<075 0.65 <0.25 1\0
<0.75 <025 <0.25 1\0
85,00:> a>,CXX> 6,9)) Varies
~ a> 70 Varies
MW-01
s
MW-04
CESCRIP'TlON:
NCOOT MARTIN COUNTY
MAIN'T1!'NANCE FACILITY
GASOLINE RB..EASE SITE
~CATLIN Engineers and Scientists
2200kS Dairy Ro;tt~ \Wtnangton, NC 28405
~-._•Ute!!•~o~111NO.I9fl,.g~gS.f'IIC; .. c.ou.l
PROJECT NO.: 211010
ESTIMATED EXTENT OF
IMPACTED GROUNDWATER
ABOVE 2L GWQS
GRASS
20
FIGURENO. 4
~~;I.P:;.'N0~.:: ::::~30!~73.~~:~
COUNTY: MMTIN
TITlE: GROUNDWATER SAMPLE
LOCATIONS AND
SUMMARIZED RESULTS
AS OF FEBRUARY 2017
DISPENSER
ISLAND
CANOPY
10 0
SCALE IN FEET
N
20
S:\CAO\DWG\2011\211010\FEBRUARY 2017\FIGURE4.DWG

NCDOT; 211010_2017_MR CATLIN Engineers and Scientists
CATLIN Project No. 211010 May 2017

APPENDICES

NCDOT; 211010_2017_MR CATLIN Engineers and Scientists
CATLIN Project No. 211010 May 2017

APPENDIX A

LABORATORY REPORT AND CHAIN-OF-CUSTODY DOCUMENTATION

#=CL#
February 17, 2017
LIMS USE: FR - CHEMICAL
LIMS OBJECT ID: 92329657
92329657
Project:
Pace Project No.:
RE:
Chemical Testing Engineer
NCDOT
Materials & Tests Unit
1801 Blue Ridge Road
Raleigh, NC 27607
GASOLINE WBS:30173.156 210027
Dear Chemical Engineer:
Enclosed are the analytical results for sample(s) received by the laboratory on February 11, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor Ezell
[e-mail]
Project Manager
Enclosures
cc:Ben Ashba, CATLIN Engineers & Scientists, Inc.
Sean O'Neil, CATLIN Engineers and Scientists
Theodore Triantafillopoulos, Catlin Engineers and Scientst
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 20
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92329657
GASOLINE WBS:30173.156 210027
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 20
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92329657
GASOLINE WBS:30173.156 210027
Lab ID Sample ID Matrix Date Collected Date Received
92329657001 MW-01 Water 02/09/17 14:45 02/11/17 09:30
92329657002 MW-02 Water 02/09/17 14:10 02/11/17 09:30
92329657003 MW-03 Water 02/09/17 14:15 02/11/17 09:30
92329657004 MW-04 Water 02/09/17 14:55 02/11/17 09:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 20
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92329657
GASOLINE WBS:30173.156 210027
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92329657001 MW-01 SM 6200B 63 PASI-CCAH
92329657002 MW-02 SM 6200B 63 PASI-CCAH
92329657003 MW-03 SM 6200B 63 PASI-CCAH
92329657004 MW-04 SM 6200B 63 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329657
GASOLINE WBS:30173.156 210027
Sample:MW-01 Lab ID:92329657001 Collected:02/09/17 14:45 Received:02/11/17 09:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Benzene 520 ug/L 02/15/17 19:48 71-43-22.0 1.0 4
Bromobenzene ND ug/L 02/15/17 19:48 108-86-12.0 1.0 4
Bromochloromethane ND ug/L 02/15/17 19:48 74-97-52.0 1.0 4
Bromodichloromethane ND ug/L 02/15/17 19:48 75-27-42.0 1.0 4
Bromoform ND ug/L 02/15/17 19:48 75-25-22.0 1.0 4
Bromomethane ND ug/L 02/15/17 19:48 74-83-920.0 2.0 4
n-Butylbenzene ND ug/L 02/15/17 19:48 104-51-82.0 1.0 4
sec-Butylbenzene 1.6J ug/L 02/15/17 19:48 135-98-82.0 1.0 4
tert-Butylbenzene ND ug/L 02/15/17 19:48 98-06-62.0 1.0 4
Carbon tetrachloride ND ug/L 02/15/17 19:48 56-23-52.0 1.0 4
Chlorobenzene ND ug/L 02/15/17 19:48 108-90-72.0 1.0 4
Chloroethane ND ug/L 02/15/17 19:48 75-00-34.0 2.0 4
Chloroform ND ug/L 02/15/17 19:48 67-66-32.0 1.0 4
Chloromethane ND ug/L 02/15/17 19:48 74-87-34.0 2.0 4
2-Chlorotoluene ND ug/L 02/15/17 19:48 95-49-82.0 1.0 4
4-Chlorotoluene ND ug/L 02/15/17 19:48 106-43-42.0 1.0 4
1,2-Dibromo-3-chloropropane ND ug/L 02/15/17 19:48 96-12-84.0 2.0 4
Dibromochloromethane ND ug/L 02/15/17 19:48 124-48-12.0 1.0 4
1,2-Dibromoethane (EDB)ND ug/L 02/15/17 19:48 106-93-42.0 1.0 4
Dibromomethane ND ug/L 02/15/17 19:48 74-95-32.0 1.0 4
1,2-Dichlorobenzene ND ug/L 02/15/17 19:48 95-50-12.0 1.0 4
1,3-Dichlorobenzene ND ug/L 02/15/17 19:48 541-73-12.0 1.0 4
1,4-Dichlorobenzene ND ug/L 02/15/17 19:48 106-46-72.0 1.0 4
Dichlorodifluoromethane ND ug/L 02/15/17 19:48 75-71-82.0 1.0 4
1,1-Dichloroethane ND ug/L 02/15/17 19:48 75-34-32.0 1.0 4
1,2-Dichloroethane ND ug/L 02/15/17 19:48 107-06-22.0 1.0 4
1,1-Dichloroethene ND ug/L 02/15/17 19:48 75-35-42.0 1.0 4
cis-1,2-Dichloroethene ND ug/L 02/15/17 19:48 156-59-22.0 1.0 4
trans-1,2-Dichloroethene ND ug/L 02/15/17 19:48 156-60-52.0 1.0 4
1,2-Dichloropropane ND ug/L 02/15/17 19:48 78-87-52.0 1.0 4
1,3-Dichloropropane ND ug/L 02/15/17 19:48 142-28-92.0 1.0 4
2,2-Dichloropropane ND ug/L 02/15/17 19:48 594-20-72.0 1.0 4
1,1-Dichloropropene ND ug/L 02/15/17 19:48 563-58-62.0 1.0 4
cis-1,3-Dichloropropene ND ug/L 02/15/17 19:48 10061-01-52.0 1.0 4
trans-1,3-Dichloropropene ND ug/L 02/15/17 19:48 10061-02-62.0 1.0 4
Diisopropyl ether ND ug/L 02/15/17 19:48 108-20-32.0 1.0 4
Ethylbenzene 146 ug/L 02/15/17 19:48 100-41-42.0 1.0 4
Hexachloro-1,3-butadiene ND ug/L 02/15/17 19:48 87-68-38.0 4.0 4
Isopropylbenzene (Cumene)20.2 ug/L 02/15/17 19:48 98-82-82.0 1.0 4
Methylene Chloride ND ug/L 02/15/17 19:48 75-09-28.0 4.0 4
Methyl-tert-butyl ether 4.2 ug/L 02/15/17 19:48 1634-04-42.0 1.0 4
Naphthalene 38.6 ug/L 02/15/17 19:48 91-20-38.0 4.0 4
n-Propylbenzene 25.7 ug/L 02/15/17 19:48 103-65-12.0 1.0 4
Styrene ND ug/L 02/15/17 19:48 100-42-52.0 1.0 4
1,1,1,2-Tetrachloroethane ND ug/L 02/15/17 19:48 630-20-62.0 1.0 4
1,1,2,2-Tetrachloroethane ND ug/L 02/15/17 19:48 79-34-52.0 1.0 4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/17/2017 04:38 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329657
GASOLINE WBS:30173.156 210027
Sample:MW-01 Lab ID:92329657001 Collected:02/09/17 14:45 Received:02/11/17 09:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Tetrachloroethene ND ug/L 02/15/17 19:48 127-18-42.0 1.0 4
Toluene 283 ug/L 02/15/17 19:48 108-88-32.0 1.0 4
1,2,3-Trichlorobenzene ND ug/L 02/15/17 19:48 87-61-68.0 4.0 4
1,2,4-Trichlorobenzene ND ug/L 02/15/17 19:48 120-82-18.0 4.0 4
1,1,1-Trichloroethane ND ug/L 02/15/17 19:48 71-55-62.0 1.0 4
1,1,2-Trichloroethane ND ug/L 02/15/17 19:48 79-00-52.0 1.0 4
Trichloroethene ND ug/L 02/15/17 19:48 79-01-62.0 1.0 4
Trichlorofluoromethane ND ug/L 02/15/17 19:48 75-69-44.0 2.0 4
1,2,3-Trichloropropane ND ug/L 02/15/17 19:48 96-18-42.0 1.0 4
1,2,4-Trimethylbenzene 111 ug/L 02/15/17 19:48 95-63-62.0 1.0 4
1,3,5-Trimethylbenzene 40.9 ug/L 02/15/17 19:48 108-67-82.0 1.0 4
Vinyl chloride ND ug/L 02/15/17 19:48 75-01-44.0 1.0 4
m&p-Xylene 247 ug/L 02/15/17 19:48 179601-23-14.0 2.0 4
o-Xylene 128 ug/L 02/15/17 19:48 95-47-62.0 1.0 4
Surrogates
1,2-Dichloroethane-d4 (S)110 %02/15/17 19:48 17060-07-070-130 4
4-Bromofluorobenzene (S)94 %02/15/17 19:48 460-00-470-130 4
Toluene-d8 (S)99 %02/15/17 19:48 2037-26-570-130 4
Sample:MW-02 Lab ID:92329657002 Collected:02/09/17 14:10 Received:02/11/17 09:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Benzene 2.8 ug/L 02/15/17 18:23 71-43-20.50 0.25 1
Bromobenzene ND ug/L 02/15/17 18:23 108-86-10.50 0.25 1
Bromochloromethane ND ug/L 02/15/17 18:23 74-97-50.50 0.25 1
Bromodichloromethane ND ug/L 02/15/17 18:23 75-27-40.50 0.25 1
Bromoform ND ug/L 02/15/17 18:23 75-25-20.50 0.25 1
Bromomethane ND ug/L 02/15/17 18:23 74-83-95.0 0.50 1
n-Butylbenzene ND ug/L 02/15/17 18:23 104-51-80.50 0.25 1
sec-Butylbenzene ND ug/L 02/15/17 18:23 135-98-80.50 0.25 1
tert-Butylbenzene ND ug/L 02/15/17 18:23 98-06-60.50 0.25 1
Carbon tetrachloride ND ug/L 02/15/17 18:23 56-23-50.50 0.25 1
Chlorobenzene ND ug/L 02/15/17 18:23 108-90-70.50 0.25 1
Chloroethane ND ug/L 02/15/17 18:23 75-00-31.0 0.50 1
Chloroform ND ug/L 02/15/17 18:23 67-66-30.50 0.25 1
Chloromethane ND ug/L 02/15/17 18:23 74-87-31.0 0.50 1
2-Chlorotoluene ND ug/L 02/15/17 18:23 95-49-80.50 0.25 1
4-Chlorotoluene ND ug/L 02/15/17 18:23 106-43-40.50 0.25 1
1,2-Dibromo-3-chloropropane ND ug/L 02/15/17 18:23 96-12-81.0 0.50 1
Dibromochloromethane ND ug/L 02/15/17 18:23 124-48-10.50 0.25 1
1,2-Dibromoethane (EDB)ND ug/L 02/15/17 18:23 106-93-40.50 0.25 1
Dibromomethane ND ug/L 02/15/17 18:23 74-95-30.50 0.25 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/17/2017 04:38 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 6 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329657
GASOLINE WBS:30173.156 210027
Sample:MW-02 Lab ID:92329657002 Collected:02/09/17 14:10 Received:02/11/17 09:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
1,2-Dichlorobenzene ND ug/L 02/15/17 18:23 95-50-10.50 0.25 1
1,3-Dichlorobenzene ND ug/L 02/15/17 18:23 541-73-10.50 0.25 1
1,4-Dichlorobenzene ND ug/L 02/15/17 18:23 106-46-70.50 0.25 1
Dichlorodifluoromethane ND ug/L 02/15/17 18:23 75-71-80.50 0.25 1
1,1-Dichloroethane ND ug/L 02/15/17 18:23 75-34-30.50 0.25 1
1,2-Dichloroethane ND ug/L 02/15/17 18:23 107-06-20.50 0.25 1
1,1-Dichloroethene ND ug/L 02/15/17 18:23 75-35-40.50 0.25 1
cis-1,2-Dichloroethene ND ug/L 02/15/17 18:23 156-59-20.50 0.25 1
trans-1,2-Dichloroethene ND ug/L 02/15/17 18:23 156-60-50.50 0.25 1
1,2-Dichloropropane ND ug/L 02/15/17 18:23 78-87-50.50 0.25 1
1,3-Dichloropropane ND ug/L 02/15/17 18:23 142-28-90.50 0.25 1
2,2-Dichloropropane ND ug/L 02/15/17 18:23 594-20-70.50 0.25 1
1,1-Dichloropropene ND ug/L 02/15/17 18:23 563-58-60.50 0.25 1
cis-1,3-Dichloropropene ND ug/L 02/15/17 18:23 10061-01-50.50 0.25 1
trans-1,3-Dichloropropene ND ug/L 02/15/17 18:23 10061-02-60.50 0.25 1
Diisopropyl ether ND ug/L 02/15/17 18:23 108-20-30.50 0.25 1
Ethylbenzene 3.5 ug/L 02/15/17 18:23 100-41-40.50 0.25 1
Hexachloro-1,3-butadiene ND ug/L 02/15/17 18:23 87-68-32.0 1.0 1
Isopropylbenzene (Cumene)0.45J ug/L 02/15/17 18:23 98-82-80.50 0.25 1
Methylene Chloride ND ug/L 02/15/17 18:23 75-09-22.0 1.0 1
Methyl-tert-butyl ether ND ug/L 02/15/17 18:23 1634-04-40.50 0.25 1
Naphthalene 1.7J ug/L 02/15/17 18:23 91-20-32.0 1.0 1
n-Propylbenzene 1.3 ug/L 02/15/17 18:23 103-65-10.50 0.25 1
Styrene ND ug/L 02/15/17 18:23 100-42-50.50 0.25 1
1,1,1,2-Tetrachloroethane ND ug/L 02/15/17 18:23 630-20-60.50 0.25 1
1,1,2,2-Tetrachloroethane ND ug/L 02/15/17 18:23 79-34-50.50 0.25 1
Tetrachloroethene ND ug/L 02/15/17 18:23 127-18-40.50 0.25 1
Toluene 1.3 ug/L 02/15/17 18:23 108-88-30.50 0.25 1
1,2,3-Trichlorobenzene ND ug/L 02/15/17 18:23 87-61-62.0 1.0 1
1,2,4-Trichlorobenzene ND ug/L 02/15/17 18:23 120-82-12.0 1.0 1
1,1,1-Trichloroethane ND ug/L 02/15/17 18:23 71-55-60.50 0.25 1
1,1,2-Trichloroethane ND ug/L 02/15/17 18:23 79-00-50.50 0.25 1
Trichloroethene ND ug/L 02/15/17 18:23 79-01-60.50 0.25 1
Trichlorofluoromethane ND ug/L 02/15/17 18:23 75-69-41.0 0.50 1
1,2,3-Trichloropropane ND ug/L 02/15/17 18:23 96-18-40.50 0.25 1
1,2,4-Trimethylbenzene 6.3 ug/L 02/15/17 18:23 95-63-60.50 0.25 1
1,3,5-Trimethylbenzene 2.4 ug/L 02/15/17 18:23 108-67-80.50 0.25 1
Vinyl chloride ND ug/L 02/15/17 18:23 75-01-41.0 0.25 1
m&p-Xylene 4.5 ug/L 02/15/17 18:23 179601-23-11.0 0.50 1
o-Xylene 4.1 ug/L 02/15/17 18:23 95-47-60.50 0.25 1
Surrogates
1,2-Dichloroethane-d4 (S)111 %02/15/17 18:23 17060-07-070-130 1
4-Bromofluorobenzene (S)94 %02/15/17 18:23 460-00-470-130 1
Toluene-d8 (S)101 %02/15/17 18:23 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/17/2017 04:38 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329657
GASOLINE WBS:30173.156 210027
Sample:MW-03 Lab ID:92329657003 Collected:02/09/17 14:15 Received:02/11/17 09:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 02/15/17 18:40 71-43-20.50 0.25 1
Bromobenzene ND ug/L 02/15/17 18:40 108-86-10.50 0.25 1
Bromochloromethane ND ug/L 02/15/17 18:40 74-97-50.50 0.25 1
Bromodichloromethane ND ug/L 02/15/17 18:40 75-27-40.50 0.25 1
Bromoform ND ug/L 02/15/17 18:40 75-25-20.50 0.25 1
Bromomethane ND ug/L 02/15/17 18:40 74-83-95.0 0.50 1
n-Butylbenzene ND ug/L 02/15/17 18:40 104-51-80.50 0.25 1
sec-Butylbenzene ND ug/L 02/15/17 18:40 135-98-80.50 0.25 1
tert-Butylbenzene ND ug/L 02/15/17 18:40 98-06-60.50 0.25 1
Carbon tetrachloride ND ug/L 02/15/17 18:40 56-23-50.50 0.25 1
Chlorobenzene ND ug/L 02/15/17 18:40 108-90-70.50 0.25 1
Chloroethane ND ug/L 02/15/17 18:40 75-00-31.0 0.50 1
Chloroform ND ug/L 02/15/17 18:40 67-66-30.50 0.25 1
Chloromethane ND ug/L 02/15/17 18:40 74-87-31.0 0.50 1
2-Chlorotoluene ND ug/L 02/15/17 18:40 95-49-80.50 0.25 1
4-Chlorotoluene ND ug/L 02/15/17 18:40 106-43-40.50 0.25 1
1,2-Dibromo-3-chloropropane ND ug/L 02/15/17 18:40 96-12-81.0 0.50 1
Dibromochloromethane ND ug/L 02/15/17 18:40 124-48-10.50 0.25 1
1,2-Dibromoethane (EDB)ND ug/L 02/15/17 18:40 106-93-40.50 0.25 1
Dibromomethane ND ug/L 02/15/17 18:40 74-95-30.50 0.25 1
1,2-Dichlorobenzene ND ug/L 02/15/17 18:40 95-50-10.50 0.25 1
1,3-Dichlorobenzene ND ug/L 02/15/17 18:40 541-73-10.50 0.25 1
1,4-Dichlorobenzene ND ug/L 02/15/17 18:40 106-46-70.50 0.25 1
Dichlorodifluoromethane ND ug/L 02/15/17 18:40 75-71-80.50 0.25 1
1,1-Dichloroethane ND ug/L 02/15/17 18:40 75-34-30.50 0.25 1
1,2-Dichloroethane ND ug/L 02/15/17 18:40 107-06-20.50 0.25 1
1,1-Dichloroethene ND ug/L 02/15/17 18:40 75-35-40.50 0.25 1
cis-1,2-Dichloroethene ND ug/L 02/15/17 18:40 156-59-20.50 0.25 1
trans-1,2-Dichloroethene ND ug/L 02/15/17 18:40 156-60-50.50 0.25 1
1,2-Dichloropropane ND ug/L 02/15/17 18:40 78-87-50.50 0.25 1
1,3-Dichloropropane ND ug/L 02/15/17 18:40 142-28-90.50 0.25 1
2,2-Dichloropropane ND ug/L 02/15/17 18:40 594-20-70.50 0.25 1
1,1-Dichloropropene ND ug/L 02/15/17 18:40 563-58-60.50 0.25 1
cis-1,3-Dichloropropene ND ug/L 02/15/17 18:40 10061-01-50.50 0.25 1
trans-1,3-Dichloropropene ND ug/L 02/15/17 18:40 10061-02-60.50 0.25 1
Diisopropyl ether ND ug/L 02/15/17 18:40 108-20-30.50 0.25 1
Ethylbenzene ND ug/L 02/15/17 18:40 100-41-40.50 0.25 1
Hexachloro-1,3-butadiene ND ug/L 02/15/17 18:40 87-68-32.0 1.0 1
Isopropylbenzene (Cumene)ND ug/L 02/15/17 18:40 98-82-80.50 0.25 1
Methylene Chloride ND ug/L 02/15/17 18:40 75-09-22.0 1.0 1
Methyl-tert-butyl ether 0.66 ug/L 02/15/17 18:40 1634-04-40.50 0.25 1
Naphthalene ND ug/L 02/15/17 18:40 91-20-32.0 1.0 1
n-Propylbenzene ND ug/L 02/15/17 18:40 103-65-10.50 0.25 1
Styrene ND ug/L 02/15/17 18:40 100-42-50.50 0.25 1
1,1,1,2-Tetrachloroethane ND ug/L 02/15/17 18:40 630-20-60.50 0.25 1
1,1,2,2-Tetrachloroethane ND ug/L 02/15/17 18:40 79-34-50.50 0.25 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/17/2017 04:38 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329657
GASOLINE WBS:30173.156 210027
Sample:MW-03 Lab ID:92329657003 Collected:02/09/17 14:15 Received:02/11/17 09:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Tetrachloroethene ND ug/L 02/15/17 18:40 127-18-40.50 0.25 1
Toluene ND ug/L 02/15/17 18:40 108-88-30.50 0.25 1
1,2,3-Trichlorobenzene ND ug/L 02/15/17 18:40 87-61-62.0 1.0 1
1,2,4-Trichlorobenzene ND ug/L 02/15/17 18:40 120-82-12.0 1.0 1
1,1,1-Trichloroethane ND ug/L 02/15/17 18:40 71-55-60.50 0.25 1
1,1,2-Trichloroethane ND ug/L 02/15/17 18:40 79-00-50.50 0.25 1
Trichloroethene ND ug/L 02/15/17 18:40 79-01-60.50 0.25 1
Trichlorofluoromethane ND ug/L 02/15/17 18:40 75-69-41.0 0.50 1
1,2,3-Trichloropropane ND ug/L 02/15/17 18:40 96-18-40.50 0.25 1
1,2,4-Trimethylbenzene ND ug/L 02/15/17 18:40 95-63-60.50 0.25 1
1,3,5-Trimethylbenzene ND ug/L 02/15/17 18:40 108-67-80.50 0.25 1
Vinyl chloride ND ug/L 02/15/17 18:40 75-01-41.0 0.25 1
m&p-Xylene ND ug/L 02/15/17 18:40 179601-23-11.0 0.50 1
o-Xylene ND ug/L 02/15/17 18:40 95-47-60.50 0.25 1
Surrogates
1,2-Dichloroethane-d4 (S)109 %02/15/17 18:40 17060-07-070-130 1
4-Bromofluorobenzene (S)93 %02/15/17 18:40 460-00-470-130 1
Toluene-d8 (S)101 %02/15/17 18:40 2037-26-570-130 1
Sample:MW-04 Lab ID:92329657004 Collected:02/09/17 14:55 Received:02/11/17 09:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 02/15/17 18:57 71-43-20.50 0.25 1
Bromobenzene ND ug/L 02/15/17 18:57 108-86-10.50 0.25 1
Bromochloromethane ND ug/L 02/15/17 18:57 74-97-50.50 0.25 1
Bromodichloromethane ND ug/L 02/15/17 18:57 75-27-40.50 0.25 1
Bromoform ND ug/L 02/15/17 18:57 75-25-20.50 0.25 1
Bromomethane ND ug/L 02/15/17 18:57 74-83-95.0 0.50 1
n-Butylbenzene ND ug/L 02/15/17 18:57 104-51-80.50 0.25 1
sec-Butylbenzene ND ug/L 02/15/17 18:57 135-98-80.50 0.25 1
tert-Butylbenzene ND ug/L 02/15/17 18:57 98-06-60.50 0.25 1
Carbon tetrachloride ND ug/L 02/15/17 18:57 56-23-50.50 0.25 1
Chlorobenzene ND ug/L 02/15/17 18:57 108-90-70.50 0.25 1
Chloroethane ND ug/L 02/15/17 18:57 75-00-31.0 0.50 1
Chloroform ND ug/L 02/15/17 18:57 67-66-30.50 0.25 1
Chloromethane ND ug/L 02/15/17 18:57 74-87-31.0 0.50 1
2-Chlorotoluene ND ug/L 02/15/17 18:57 95-49-80.50 0.25 1
4-Chlorotoluene ND ug/L 02/15/17 18:57 106-43-40.50 0.25 1
1,2-Dibromo-3-chloropropane ND ug/L 02/15/17 18:57 96-12-81.0 0.50 1
Dibromochloromethane ND ug/L 02/15/17 18:57 124-48-10.50 0.25 1
1,2-Dibromoethane (EDB)ND ug/L 02/15/17 18:57 106-93-40.50 0.25 1
Dibromomethane ND ug/L 02/15/17 18:57 74-95-30.50 0.25 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/17/2017 04:38 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329657
GASOLINE WBS:30173.156 210027
Sample:MW-04 Lab ID:92329657004 Collected:02/09/17 14:55 Received:02/11/17 09:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
1,2-Dichlorobenzene ND ug/L 02/15/17 18:57 95-50-10.50 0.25 1
1,3-Dichlorobenzene ND ug/L 02/15/17 18:57 541-73-10.50 0.25 1
1,4-Dichlorobenzene ND ug/L 02/15/17 18:57 106-46-70.50 0.25 1
Dichlorodifluoromethane ND ug/L 02/15/17 18:57 75-71-80.50 0.25 1
1,1-Dichloroethane ND ug/L 02/15/17 18:57 75-34-30.50 0.25 1
1,2-Dichloroethane ND ug/L 02/15/17 18:57 107-06-20.50 0.25 1
1,1-Dichloroethene ND ug/L 02/15/17 18:57 75-35-40.50 0.25 1
cis-1,2-Dichloroethene ND ug/L 02/15/17 18:57 156-59-20.50 0.25 1
trans-1,2-Dichloroethene ND ug/L 02/15/17 18:57 156-60-50.50 0.25 1
1,2-Dichloropropane ND ug/L 02/15/17 18:57 78-87-50.50 0.25 1
1,3-Dichloropropane ND ug/L 02/15/17 18:57 142-28-90.50 0.25 1
2,2-Dichloropropane ND ug/L 02/15/17 18:57 594-20-70.50 0.25 1
1,1-Dichloropropene ND ug/L 02/15/17 18:57 563-58-60.50 0.25 1
cis-1,3-Dichloropropene ND ug/L 02/15/17 18:57 10061-01-50.50 0.25 1
trans-1,3-Dichloropropene ND ug/L 02/15/17 18:57 10061-02-60.50 0.25 1
Diisopropyl ether ND ug/L 02/15/17 18:57 108-20-30.50 0.25 1
Ethylbenzene ND ug/L 02/15/17 18:57 100-41-40.50 0.25 1
Hexachloro-1,3-butadiene ND ug/L 02/15/17 18:57 87-68-32.0 1.0 1
Isopropylbenzene (Cumene)ND ug/L 02/15/17 18:57 98-82-80.50 0.25 1
Methylene Chloride ND ug/L 02/15/17 18:57 75-09-22.0 1.0 1
Methyl-tert-butyl ether ND ug/L 02/15/17 18:57 1634-04-40.50 0.25 1
Naphthalene ND ug/L 02/15/17 18:57 91-20-32.0 1.0 1
n-Propylbenzene ND ug/L 02/15/17 18:57 103-65-10.50 0.25 1
Styrene ND ug/L 02/15/17 18:57 100-42-50.50 0.25 1
1,1,1,2-Tetrachloroethane ND ug/L 02/15/17 18:57 630-20-60.50 0.25 1
1,1,2,2-Tetrachloroethane ND ug/L 02/15/17 18:57 79-34-50.50 0.25 1
Tetrachloroethene ND ug/L 02/15/17 18:57 127-18-40.50 0.25 1
Toluene ND ug/L 02/15/17 18:57 108-88-30.50 0.25 1
1,2,3-Trichlorobenzene ND ug/L 02/15/17 18:57 87-61-62.0 1.0 1
1,2,4-Trichlorobenzene ND ug/L 02/15/17 18:57 120-82-12.0 1.0 1
1,1,1-Trichloroethane ND ug/L 02/15/17 18:57 71-55-60.50 0.25 1
1,1,2-Trichloroethane ND ug/L 02/15/17 18:57 79-00-50.50 0.25 1
Trichloroethene ND ug/L 02/15/17 18:57 79-01-60.50 0.25 1
Trichlorofluoromethane ND ug/L 02/15/17 18:57 75-69-41.0 0.50 1
1,2,3-Trichloropropane ND ug/L 02/15/17 18:57 96-18-40.50 0.25 1
1,2,4-Trimethylbenzene ND ug/L 02/15/17 18:57 95-63-60.50 0.25 1
1,3,5-Trimethylbenzene ND ug/L 02/15/17 18:57 108-67-80.50 0.25 1
Vinyl chloride ND ug/L 02/15/17 18:57 75-01-41.0 0.25 1
m&p-Xylene ND ug/L 02/15/17 18:57 179601-23-11.0 0.50 1
o-Xylene ND ug/L 02/15/17 18:57 95-47-60.50 0.25 1
Surrogates
1,2-Dichloroethane-d4 (S)111 %02/15/17 18:57 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %02/15/17 18:57 460-00-470-130 1
Toluene-d8 (S)100 %02/15/17 18:57 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/17/2017 04:38 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329657
GASOLINE WBS:30173.156 210027
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348422
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92329657001, 92329657002, 92329657003, 92329657004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1933134
Associated Lab Samples:92329657001, 92329657002, 92329657003, 92329657004
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 02/15/17 17:320.25
1,1,1-Trichloroethane ug/L ND 0.50 02/15/17 17:320.25
1,1,2,2-Tetrachloroethane ug/L ND 0.50 02/15/17 17:320.25
1,1,2-Trichloroethane ug/L ND 0.50 02/15/17 17:320.25
1,1-Dichloroethane ug/L ND 0.50 02/15/17 17:320.25
1,1-Dichloroethene ug/L ND 0.50 02/15/17 17:320.25
1,1-Dichloropropene ug/L ND 0.50 02/15/17 17:320.25
1,2,3-Trichlorobenzene ug/L ND 2.0 02/15/17 17:321.0
1,2,3-Trichloropropane ug/L ND 0.50 02/15/17 17:320.25
1,2,4-Trichlorobenzene ug/L ND 2.0 02/15/17 17:321.0
1,2,4-Trimethylbenzene ug/L ND 0.50 02/15/17 17:320.25
1,2-Dibromo-3-chloropropane ug/L ND 1.0 02/15/17 17:320.50
1,2-Dibromoethane (EDB)ug/L ND 0.50 02/15/17 17:320.25
1,2-Dichlorobenzene ug/L ND 0.50 02/15/17 17:320.25
1,2-Dichloroethane ug/L ND 0.50 02/15/17 17:320.25
1,2-Dichloropropane ug/L ND 0.50 02/15/17 17:320.25
1,3,5-Trimethylbenzene ug/L ND 0.50 02/15/17 17:320.25
1,3-Dichlorobenzene ug/L ND 0.50 02/15/17 17:320.25
1,3-Dichloropropane ug/L ND 0.50 02/15/17 17:320.25
1,4-Dichlorobenzene ug/L ND 0.50 02/15/17 17:320.25
2,2-Dichloropropane ug/L ND 0.50 02/15/17 17:320.25
2-Chlorotoluene ug/L ND 0.50 02/15/17 17:320.25
4-Chlorotoluene ug/L ND 0.50 02/15/17 17:320.25
Benzene ug/L ND 0.50 02/15/17 17:320.25
Bromobenzene ug/L ND 0.50 02/15/17 17:320.25
Bromochloromethane ug/L ND 0.50 02/15/17 17:320.25
Bromodichloromethane ug/L ND 0.50 02/15/17 17:320.25
Bromoform ug/L ND 0.50 02/15/17 17:320.25
Bromomethane ug/L ND 5.0 02/15/17 17:320.50
Carbon tetrachloride ug/L ND 0.50 02/15/17 17:320.25
Chlorobenzene ug/L ND 0.50 02/15/17 17:320.25
Chloroethane ug/L ND 1.0 02/15/17 17:320.50
Chloroform ug/L ND 0.50 02/15/17 17:320.25
Chloromethane ug/L ND 1.0 02/15/17 17:320.50
cis-1,2-Dichloroethene ug/L ND 0.50 02/15/17 17:320.25
cis-1,3-Dichloropropene ug/L ND 0.50 02/15/17 17:320.25
Dibromochloromethane ug/L ND 0.50 02/15/17 17:320.25
Dibromomethane ug/L ND 0.50 02/15/17 17:320.25
Dichlorodifluoromethane ug/L ND 0.50 02/15/17 17:320.25
Diisopropyl ether ug/L ND 0.50 02/15/17 17:320.25
Ethylbenzene ug/L ND 0.50 02/15/17 17:320.25
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/17/2017 04:38 PM
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Page 11 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329657
GASOLINE WBS:30173.156 210027
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1933134
Associated Lab Samples:92329657001, 92329657002, 92329657003, 92329657004
Matrix:Water
AnalyzedMDL
Hexachloro-1,3-butadiene ug/L ND 2.0 02/15/17 17:321.0
Isopropylbenzene (Cumene)ug/L ND 0.50 02/15/17 17:320.25
m&p-Xylene ug/L ND 1.0 02/15/17 17:320.50
Methyl-tert-butyl ether ug/L ND 0.50 02/15/17 17:320.25
Methylene Chloride ug/L ND 2.0 02/15/17 17:321.0
n-Butylbenzene ug/L ND 0.50 02/15/17 17:320.25
n-Propylbenzene ug/L ND 0.50 02/15/17 17:320.25
Naphthalene ug/L ND 2.0 02/15/17 17:321.0
o-Xylene ug/L ND 0.50 02/15/17 17:320.25
sec-Butylbenzene ug/L ND 0.50 02/15/17 17:320.25
Styrene ug/L ND 0.50 02/15/17 17:320.25
tert-Butylbenzene ug/L ND 0.50 02/15/17 17:320.25
Tetrachloroethene ug/L ND 0.50 02/15/17 17:320.25
Toluene ug/L ND 0.50 02/15/17 17:320.25
trans-1,2-Dichloroethene ug/L ND 0.50 02/15/17 17:320.25
trans-1,3-Dichloropropene ug/L ND 0.50 02/15/17 17:320.25
Trichloroethene ug/L ND 0.50 02/15/17 17:320.25
Trichlorofluoromethane ug/L ND 1.0 02/15/17 17:320.50
Vinyl chloride ug/L ND 1.0 02/15/17 17:320.25
1,2-Dichloroethane-d4 (S)%107 70-130 02/15/17 17:32
4-Bromofluorobenzene (S)%96 70-130 02/15/17 17:32
Toluene-d8 (S)%99 70-130 02/15/17 17:32
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1933135LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 45.450 91 60-140
1,1,1-Trichloroethane ug/L 48.550 97 60-140
1,1,2,2-Tetrachloroethane ug/L 47.050 94 60-140
1,1,2-Trichloroethane ug/L 48.650 97 60-140
1,1-Dichloroethane ug/L 47.650 95 60-140
1,1-Dichloroethene ug/L 49.150 98 60-140
1,1-Dichloropropene ug/L 47.950 96 60-140
1,2,3-Trichlorobenzene ug/L 48.150 96 60-140
1,2,3-Trichloropropane ug/L 49.050 98 60-140
1,2,4-Trichlorobenzene ug/L 45.850 92 60-140
1,2,4-Trimethylbenzene ug/L 47.750 95 60-140
1,2-Dibromo-3-chloropropane ug/L 47.150 94 60-140
1,2-Dibromoethane (EDB)ug/L 47.950 96 60-140
1,2-Dichlorobenzene ug/L 47.350 95 60-140
1,2-Dichloroethane ug/L 47.650 95 60-140
1,2-Dichloropropane ug/L 45.650 91 60-140
1,3,5-Trimethylbenzene ug/L 46.450 93 60-140
1,3-Dichlorobenzene ug/L 45.350 91 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/17/2017 04:38 PM
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Page 12 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329657
GASOLINE WBS:30173.156 210027
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1933135LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 47.150 94 60-140
1,4-Dichlorobenzene ug/L 45.150 90 60-140
2,2-Dichloropropane ug/L 46.750 93 60-140
2-Chlorotoluene ug/L 47.250 94 60-140
4-Chlorotoluene ug/L 46.350 93 60-140
Benzene ug/L 47.050 94 60-140
Bromobenzene ug/L 47.950 96 60-140
Bromochloromethane ug/L 49.550 99 60-140
Bromodichloromethane ug/L 48.750 97 60-140
Bromoform ug/L 43.650 87 60-140
Bromomethane ug/L 41.650 83 60-140
Carbon tetrachloride ug/L 43.550 87 60-140
Chlorobenzene ug/L 46.750 93 60-140
Chloroethane ug/L 47.650 95 60-140
Chloroform ug/L 49.550 99 60-140
Chloromethane ug/L 47.050 94 60-140
cis-1,2-Dichloroethene ug/L 48.950 98 60-140
cis-1,3-Dichloropropene ug/L 49.050 98 60-140
Dibromochloromethane ug/L 48.150 96 60-140
Dibromomethane ug/L 47.450 95 60-140
Dichlorodifluoromethane ug/L 33.450 67 60-140
Diisopropyl ether ug/L 54.050 108 60-140
Ethylbenzene ug/L 45.750 91 60-140
Hexachloro-1,3-butadiene ug/L 45.150 90 60-140
Isopropylbenzene (Cumene)ug/L 45.950 92 60-140
m&p-Xylene ug/L 91.0100 91 60-140
Methyl-tert-butyl ether ug/L 52.350 105 60-140
Methylene Chloride ug/L 52.150 104 60-140
n-Butylbenzene ug/L 47.450 95 60-140
n-Propylbenzene ug/L 46.550 93 60-140
Naphthalene ug/L 48.850 98 60-140
o-Xylene ug/L 46.650 93 60-140
sec-Butylbenzene ug/L 47.150 94 60-140
Styrene ug/L 46.550 93 60-140
tert-Butylbenzene ug/L 39.150 78 60-140
Tetrachloroethene ug/L 42.450 85 60-140
Toluene ug/L 46.350 93 60-140
trans-1,2-Dichloroethene ug/L 48.050 96 60-140
trans-1,3-Dichloropropene ug/L 47.150 94 60-140
Trichloroethene ug/L 45.350 91 60-140
Trichlorofluoromethane ug/L 50.850 102 60-140
Vinyl chloride ug/L 39.050 78 60-140
1,2-Dichloroethane-d4 (S)%110 70-130
4-Bromofluorobenzene (S)%96 70-130
Toluene-d8 (S)%101 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/17/2017 04:38 PM
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Huntersville, NC 28078
[phone]
Page 13 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329657
GASOLINE WBS:30173.156 210027
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1933136MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329565002
1933137
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 98 60-14088 10 3020ND19.6 17.7
1,1,1-Trichloroethane ug/L 20 112 60-140105 6 3020ND22.4 21.1
1,1,2,2-Tetrachloroethane ug/L 20 106 60-140101 5 3020ND21.2 20.2
1,1,2-Trichloroethane ug/L 20 106 60-14098 8 3020ND21.1 19.6
1,1-Dichloroethane ug/L 20 109 60-140103 5 3020ND21.8 20.7
1,1-Dichloroethene ug/L 20 116 60-140109 7 3020ND23.2 21.8
1,1-Dichloropropene ug/L 20 110 60-140106 4 3020ND22.0 21.1
1,2,3-Trichlorobenzene ug/L 20 101 60-14096 5 3020ND20.3 19.2
1,2,3-Trichloropropane ug/L 20 108 60-140101 7 3020ND21.6 20.2
1,2,4-Trichlorobenzene ug/L 20 98 60-14095 3 3020ND19.6 19.0
1,2,4-Trimethylbenzene ug/L 20 105 60-14098 7 3020ND21.0 19.7
1,2-Dibromo-3-
chloropropane ug/L 20 99 60-14098 1 3020ND19.8 19.6
1,2-Dibromoethane (EDB)ug/L 20 104 60-14099 5 3020ND20.7 19.8
1,2-Dichlorobenzene ug/L 20 104 60-14098 6 3020ND20.9 19.6
1,2-Dichloroethane ug/L 20 105 60-14099 6 3020ND21.2 20.0
1,2-Dichloropropane ug/L 20 102 60-14095 7 3020ND20.4 19.0
1,3,5-Trimethylbenzene ug/L 20 103 60-14096 6 3020ND20.5 19.3
1,3-Dichlorobenzene ug/L 20 100 60-14094 6 3020ND20.0 18.8
1,3-Dichloropropane ug/L 20 105 60-14097 8 3020ND21.1 19.4
1,4-Dichlorobenzene ug/L 20 100 60-14094 6 3020ND20.0 18.8
2,2-Dichloropropane ug/L 20 96 60-14091 6 3020ND19.2 18.2
2-Chlorotoluene ug/L 20 105 60-140100 5 3020ND21.0 19.9
4-Chlorotoluene ug/L 20 102 60-14096 6 3020ND20.5 19.3
Benzene ug/L 20 107 60-140101 6 3020ND21.5 20.2
Bromobenzene ug/L 20 103 60-14094 9 3020ND20.6 18.9
Bromochloromethane ug/L 20 110 60-140102 8 3020ND22.1 20.5
Bromodichloromethane ug/L 20 103 60-14097 6 3020ND20.7 19.5
Bromoform ug/L 20 87 60-14082 5 3020ND17.3 16.5
Bromomethane ug/L 20 75 60-14073 2 3020ND15.0 14.6
Carbon tetrachloride ug/L 20 96 60-14094 2 3020ND19.2 18.8
Chlorobenzene ug/L 20 107 60-14099 8 3020ND21.4 19.8
Chloroethane ug/L 20 118 60-140105 12 3020ND23.5 21.0
Chloroform ug/L 20 111 60-140105 6 3020ND22.2 20.9
Chloromethane ug/L 20 106 60-140100 5 3020ND21.1 20.1
cis-1,2-Dichloroethene ug/L 20 110 60-140105 5 3020ND22.0 21.0
cis-1,3-Dichloropropene ug/L 20 100 60-14094 7 3020ND20.0 18.7
Dibromochloromethane ug/L 20 102 60-14095 8 3020ND20.4 18.9
Dibromomethane ug/L 20 110 60-140100 10 3020ND22.0 19.9
Dichlorodifluoromethane ug/L 20 81 60-14078 4 3020ND16.2 15.6
Diisopropyl ether ug/L 20 120 60-140111 8 3020ND24.1 22.2
Ethylbenzene ug/L 20 106 60-14097 9 3020ND21.2 19.4
Hexachloro-1,3-butadiene ug/L 20 95 60-14095 0 3020ND19.0 19.1
Isopropylbenzene (Cumene)ug/L 20 104 60-14098 6 3020ND20.8 19.5
m&p-Xylene ug/L 40 105 60-14097 8 3040ND42.1 39.0
Methyl-tert-butyl ether ug/L 20 114 60-140109 4 30200.61 23.5 22.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/17/2017 04:38 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329657
GASOLINE WBS:30173.156 210027
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1933136MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329565002
1933137
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methylene Chloride ug/L 20 113 60-140104 8 3020ND22.5 20.9
n-Butylbenzene ug/L 20 100 60-14096 4 3020ND20.1 19.3
n-Propylbenzene ug/L 20 104 60-14097 7 3020ND20.7 19.4
Naphthalene ug/L 20 105 60-140100 4 3020ND20.9 20.1
o-Xylene ug/L 20 105 60-14099 6 3020ND21.1 19.8
sec-Butylbenzene ug/L 20 105 60-140100 4 3020ND20.9 20.0
Styrene ug/L 20 105 60-14097 8 3020ND20.9 19.4
tert-Butylbenzene ug/L 20 87 60-14082 6 3020ND17.4 16.3
Tetrachloroethene ug/L 20 98 60-14091 7 3020ND19.5 18.3
Toluene ug/L 20 103 60-14097 6 3020ND20.6 19.5
trans-1,2-Dichloroethene ug/L 20 112 60-140106 6 3020ND22.5 21.2
trans-1,3-Dichloropropene ug/L 20 99 60-14091 8 3020ND19.7 18.3
Trichloroethene ug/L 20 105 60-14098 7 3020ND21.0 19.5
Trichlorofluoromethane ug/L 20 125 60-140116 8 3020ND24.9 23.1
Vinyl chloride ug/L 20 91 60-14086 6 3020ND18.1 17.1
1,2-Dichloroethane-d4 (S)%111 70-130110
4-Bromofluorobenzene (S)%99 70-13095
Toluene-d8 (S)%100 70-13099
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/17/2017 04:38 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 20
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92329657
GASOLINE WBS:30173.156 210027
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/17/2017 04:38 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 20
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92329657
GASOLINE WBS:30173.156 210027
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92329657001 348422MW-01 SM 6200B
92329657002 348422MW-02 SM 6200B
92329657003 348422MW-03 SM 6200B
92329657004 348422MW-04 SM 6200B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/17/2017 04:38 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 20
Page 18 of 20
peAnalyticat"
Laboratory receiving samples:
Asheville D EdenD
Courier:
0 Commercial
Custody Seal Present? D Yes
Packing Material: O subble Wrap
Thermometer: OJh Gun 10: "T \ l Q(j 2;)
uul:urnent 1\lame:
Sample Condition Upon Receipt(SCUR)
Document No.:
Document Revised: Sept. 21, 2016
Pag_e 1 of 2
Issuing Authority:
F-CAR-CS-033-Rev.01 Pace Quality Office
Greenwood D
Seals Intact? D Yes
~ubble Bags O N one
cn'l.Let
Type of Ice: ~·
Huntersvillt!QJ Raleigh0 MechanicsvilleO
Project#: lJ0#"92329657
Client ~2~U~IIIIII 1111 111
Q~o Date/Initials Person Examining C~ (l?,-/Bll-:7
O o t her: __
0 Biue 0None ~mples on ice, cooling process has begun
Correction Factor: Cooler Temp Corrected ('C): 1l Q Biological Tissue Fro zen? DYes ~o O N/A
Temp should be abo'!e ~ezing to 6"C
USDA Regulated Soil'l{d)N/A, water sample)
k Did sam~~1riginate in a quarantine zone within the United States: CA, NY, or SC (chec
O ves o
Chain of Cu~tody Present?
Samples Arrive.~ within Hold Time?
Short Hold Time Analysis (<72 hr.)?
Rush Turn _Aro~nd Time Requested?
Sufficient Volume?
Correct Contail:~rs Used?
-Pace Containers Used?
Containers Intact?
Samples Field Filtered?
Sample Labels Match COC?
-Includes DatefTime/ID/Analysis Matrix: Vv--r
Headspace in VOA Vials (>S-6mm)?
Trip Blank Present?
Trip Blank Custody Seals Present?
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comment s/Sample
Discrepancy:
Project Manager SCURF Review:
Project Manager SRF Review:
<u:lYes 0 No O N/A
d'"'lves 0 No O N/A
O ves ·g;}o O N/A
O ves ~0 O N/A
t I?Jves 0 No O N/A
~es 0 No ON/A
~es 0No ON/A
~es 0No ON/A
Oves 0No \ON/A
~5 0No ON/A
O ves ~ ON/A
O ves ~ ON/A I Oves 0No ~/A
)? (" t f II maps Did samples origmate rom a ore gn source '"~ 1ona y,
including Hawaii and Puerto Rico)? D Yes o
Comments/Discrepancy:
1. ·. --
2.
3. -·
4.
5. -
6.
7. ~
8. Note if sediment is visible in the dissolved container
9. ...
10.
11.
Field Data Required? DYes 0No
Date/Time:
Date: ----------------
Note: Whenever there Is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers)
Page 19 of 20VI .... .... .... <0 00 " "' "' ~ ...... "' .... "' .... 0 ... 3 "'C ;o v v v / !/ v v 1/ 1/ 1/ / / 0 --i < "'C ID s. .., iil "' ID < / / / 1/ 1/ / / 1/ / l( / 1/ ~ ;;:· ID / / / 1/ 1/ / / 1/ / / L 1/ "'C :I: c "'C 0 "' / / / 1/ 1/ / / 1/ 1/ / v 1/ / / / 1/ 1/ / / / / / ~ 1/ ;;; "lj n ID :X: ~ l> .9: 0 c ... 1/) ... .... II> 3 ~ tD :J: ::I ID .... < ~ r-0 c;· OQ "' ... -Q. 0 c:· ... ~ "'C II> Q. ... tD 1/) tD --i ... < 3" tD / / v v v / / / / / v v / / 1/ 1/ / / 1/ / / / / / / / / 1/ / !/ 1/ / :/ 1/ / / / / 1/ v / 1/ 1/ / / 1/ / / ' £::.. +-··~ ..... ' II> a. ., "'C ~ib (I) ~ ; Q) "' ~ 3 Q. < ~ "lj 0 tD "' 1/) )> 3 0 r::: "' ... ., s. Q. Q. "0 II> ~ Q. II> < ~ 1/ 1/ 1/ / v / / / / v / / ;;:· "' l( 1/ / / 1/ / / / / !/ / / ,.... ~ ~ Item# BP4U-125 ml Plastic Unpreserved (N/A) (CI-) BP3U-250 ml Plastic Unpreserved (N/A) BP2U-500 ml Plastic Unpreserved (N/A) BP1U-11iter Plastic Unpreserved (N/A) BP3S-250 ml Plastic H2S04 (pH< 2) (CI-) BP3N-250 ml plastic HN03 (pH< 2) BP3Z-250 ml Plastic ZN Acetate & NaOH (>9) BP3C-250 ml Plastic NaOH (pH > 12) (CI-) WGFU-Wide-mouthed Glass jar Unpreserved AG1U-11iter Amber Unpreserved (N/A) (CI-) AG1H-11iter Amber HCI (pH< 2) AG3U-250 mLAmber Unpreserved (N/A) (CI-) AG1S-11iter Amber H2S04 (pH< 2) AG3S-250 ml Amber H2S04 (p:; < 2) AG3A(DG3A)-250 ml Amber NH4CI (N/A)(CI-) DG9H-40 ml VOA HCI (N/A) VG9T-40 ml VOA Na2S203 (N/A) VG9U-40 ml VOA Unp (N/A) DG9P-40 ml VOA H3P04 (N/A) VOAK (6 vials per kit)-5035 kit (N/A) V/GK (3 vials per kit)-vPH/Gas kit (N/A) SPST-125 mLSterile Plastic (N/A-Iab) SP2T-250 mLSterile Plastic (N/A -lab) BP3A-250 ml Plastic (NH2)2S04 (9.3-9.7) Cubitainer VSGU-20 ml Scintillation vials (N/ A) GN *"'0 Ul * * ... n CD tD < =r 0 Ul tD tD .... tD ... n .... ... ~ "' 0 < ;· 3 ~. Q. 3 Ill =r 0 Ill ... Ill ::I ::I "' ::;; VI Q. .... 0 Ill :E 0 -3 ;:::;: "'0 c-"'0 =r =r 0 ~ 5' Ill X !" ::;; iii' ... 0 =r -... tD 0 c-Ill 0 iii' n X n .... tD ~ ::I "'0 "'0 1: ... Ill :I: 3 ::I Ill CT n ::I tD tD ... ... Q. -0 Ill 0 -::I ... CT OQ Q. tD 0 -tD .... n ... 0 CD" ... =r "' 0 ::! • ::I Ill ... o· ::I "'C ... 0 ~n· .... 0 -o a~ r 3 ...... "' z -o # -t -t .. "" . . U) U) N I z N 0 0 w 0 0 -t N z c rn II 0 .. ~ .. .. 0 N ....... N 0 ....... .... ..,J I I 0 0 n c 3 It) ;;;;) .... N 0 ~I
Page 20 of 20
Section A /"' ~ Pti· • A';.,/~"IC..1' Required Chcnt lnformatton: Company CA TUN Enq.neers and Sctenttsls Address 120 Old Daory Road Wolmonqton. NC 28405 Ematl moke <l mason@catllnusa com Phone 919-952·5861 !Fax Requested Due Dote 2 3 4 5 6 7 8 9 10 11 12 I SAMPLE 10 One Character per box. (A·Z,0·91, -) Sample Ids must be unique .MW-D I ADDITIONAL COMMENTS CHAIN-OF-CUSTODY I Analytical Request Document The Chatr. of-Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately I Paqe · Section 8 Required Project Information· Section C Invoice Information· Of Report To Mochael Mason -? 5,pa-, 0 "/1).;>,· I Allentoon e· II Nc...DV'/ Copy To Company Name: Addross Purchase Order #. Pace Quote· w<_S".-!. :J;f-:SO i73 !Sf;;, ProJect Name. Gasoline Release WBS 30173 156 Pace Pro,ect Manager taylor ezell@pacelabs com. Pro1ec1 # ::Z I Do 2 7 Pace Proftle # 5838-1 Requested Analysis Filtered (YIN) MA1RIX 011nkmg W..tl~t w.,, •. , W,t:.teWatct Puw:luc:1 SooiiSoloo Ool W•po ... O!"e' T..-.sue ~ ;;: 0 :: 0 COOE ~ ~ ow ~ " u W1 8 "' ww " <( p ~ "' " COLLECTED SL G Q. Ol G START END WP w w AR 0 a. 01 0 ~ u TS >( ~ ;:;; a. .... ::; ~ <( U) DATE TIME DATE TIME u "" t7 i~{O ') REUNQUISHEO BY I AFFtUATION DATE U) 0:: w z ~ z 0 u u. 0 .. '0 " c: :;: !!! Q. c: ::> TIME z Preservatives >= -Ul ., 1-Ul ., g Ul N "' 0 ]!> ID ... 2 c: "' >-0 "' I "' "' a; c: D 0 .c: <( (.) "' u 0 N iii .c: N z "' "' 6 0 I I I z z ::; > '( X i y f X X X A~CEPTED BY I AJ'liATION I I '-"1( ( II SAMPLER NAME AND SIGNATURE 1.._1 PRINT Name of SAMPLER: /" i _ J. f) /U L _ 1...-0 J '5. 7\ c.,., 15 . ~-~c::J/i?...r SIGNATURE of SAMPLER:~ 8. 9~ DATE Signed: DATE TIME -I r --v 2/ot /; 7 Regulatory Agency State I Location NC CD\ SAMPLE CONDITIONS {lj u (.) c. ::,; w ,... "' .. ~uz ~~~