WA-364_7173_CA_MPR_20180405

3502 Hayes Road • Monroe, North Carolina 28110
Phone [phone] • [phone] • Fax [phone]
April 5, 2018

Ms. Carrie Stone
North Carolina Department of
Environmental Quality
Washington Regional Office
943 Washington Square Mall
Washington, North Carolina 27889

Re: April 2018 Ground Water Assessment
Elizabeth City Garage
410 Pritchard Street
Elizabeth City, Pasquotank County
Risk Classification L140D
Incident No. 7173
GRI Project No. 4650

Dear Ms. Stone,

Geological Resources, Inc. (GRI) presents the results of the April 2018 sampling event at the above
referenced site. The activities were conducted in accordance with Geological Resources, Inc. (GRI)
proposal number 18-189 which was submitted to NCDEQ on March 16, 2018 and approved as Task
Authorization No. 7173-15 on March 23, 2018.

One monitoring well (GMW-1) was installed at the site. GMW-1 was drilled to a depth of 12 feet below
grade and was completed with a 10-foot screened interval set to bracket the water table at the time of
installation. GMW-1 was gauged, purged and sampled on March 29, 2018. The ground water sample
was submitted for laboratory analyses of VOCs + 5 oxygenates using EPA Method 6200B, EDB using
EPA Method 504.1 and lead using EPA Method 6010B. Please see the attached laboratory report.

Please do not hesitate to contact the undersigned at [phone] if you have any questions or require
additional information.

Sincerely,

Geological Resources, Inc.

William Regenthal, P. G.
Project Manager

Enclosures: Well Construction Record, Laboratory Report, Site Map, Site Location Map
cc: City of Elizabeth City, P.O. Box 404, Elizabeth City, NC 27909
file
Copyright (C) 2009 MyTopo, 2006-2017 TomTom
SCALE 1:24000
0 1000 2000 3000 4000 5000
FEET
Declination
MN 10.75° W

MN
Location: 036.2968940° N 076.2369090° WDate: 11/30/17
Scale: 1 inch = 2,000 ft.
Copyright (C) 2009 MyTopo
Figure 1
Elizabeth City Garage
410 Pritchard Street, Elizabeth City, Pasquotank County,
NC
Incident No. N/A
GRI Project No. 4650
04/04/18
Technical Report for
GRI (Geological Resources Inc.)
Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
4650
SGS Job Number: FA52959
Sampling Date: 03/29/18
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]; [e-mail]
ATTN: William Regenthall
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AK, AR, IA, KY, MA, MS, ND, NH, NV, OK, OR, UT, WA, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Caitlin Brice, M.S.
General Manager
Orlando, FL 04/04/18
e-Hardcopy 2.0
Automated Report
34
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
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FA52959
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................5
3.1: FA52959-1: GMW-1 .....................................................................................................6
Section 4: Misc. Forms ............................................................................................................11
4.1: Chain of Custody ...........................................................................................................12
Section 5: MS Volatiles - QC Data Summaries .....................................................................14
5.1: Method Blank Summary ................................................................................................15
5.2: Blank Spike Summary ...................................................................................................18
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................21
Section 6: GC Volatiles - QC Data Summaries .....................................................................24
6.1: Method Blank Summary ................................................................................................25
6.2: Blank Spike Summary ...................................................................................................26
6.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................27
Section 7: Metals Analysis - QC Data Summaries ................................................................28
7.1: Prep QC MP33545: Pb ..................................................................................................29 12345672 of 34
FA52959
SGS North America Inc.
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA52959
Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
Project No: 4650
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
FA52959-1 03/29/18 14:30 WR 03/30/18 AQ Ground Water GMW-1
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FA529591
Summary of Hits Page 1 of 1
Job Number:FA52959
Account:GRI (Geological Resources Inc.)
Project:Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
Collected:03/29/18
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA52959-1 GMW-1
Benzene 1660 25 6.3 ug/l SM 6200B
n-Butylbenzene 55.9 25 6.3 ug/l SM 6200B
sec-Butylbenzene 28.6 25 6.3 ug/l SM 6200B
Di-Isopropyl Ether 53.7 25 6.3 ug/l SM 6200B
Ethylbenzene 1010 25 6.3 ug/l SM 6200B
Isopropylbenzene 172 25 6.3 ug/l SM 6200B
Methyl Tert Butyl Ether 43.0 25 6.3 ug/l SM 6200B
Naphthalene 133 25 6.3 ug/l SM 6200B
n-Propylbenzene 465 25 6.3 ug/l SM 6200B
Tert-Amyl Alcohol 612 500 100 ug/l SM 6200B
Toluene 22.0 J 25 6.3 ug/l SM 6200B
1,2,4-Trimethylbenzene 7.6 J 25 6.3 ug/l SM 6200B
m,p-Xylene 23.9 J 50 6.3 ug/l SM 6200B
Xylene (total)23.9 J 75 13 ug/l SM 6200B
Lead 698 5.0 ug/l SW846 6010D
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FA529592
SGS North America Inc.
Sample Results
Report of Analysis
Orlando, FL
Section 3
5 of 34
FA529593
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:GMW-1
Lab Sample ID:FA52959-1 Date Sampled:03/29/18
Matrix:AQ - Ground Water Date Received:03/30/18
Method:SM 6200B Percent Solids:n/a
Project:Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0212632.D 50 04/04/18 05:13 TD n/a n/a VA2354
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 1660 25 6.3 ug/l
108-86-1 Bromobenzene ND 25 6.3 ug/l
74-97-5 Bromochloromethane ND 25 6.3 ug/l
75-27-4 Bromodichloromethane ND 25 6.3 ug/l
75-25-2 Bromoform ND 25 6.3 ug/l
104-51-8 n-Butylbenzene 55.9 25 6.3 ug/l
135-98-8 sec-Butylbenzene 28.6 25 6.3 ug/l
98-06-6 tert-Butylbenzene ND 25 6.3 ug/l
56-23-5 Carbon Tetrachloride ND 25 6.3 ug/l
108-90-7 Chlorobenzene ND 25 6.3 ug/l
75-00-3 Chloroethane ND 25 10 ug/l
67-66-3 Chloroform ND 25 6.3 ug/l
95-49-8 o-Chlorotoluene ND 25 6.3 ug/l
106-43-4 p-Chlorotoluene ND 25 6.3 ug/l
124-48-1 Dibromochloromethane ND 25 6.3 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 25 12 ug/l
106-93-4 1,2-Dibromoethane ND 25 6.3 ug/l
75-71-8 Dichlorodifluoromethane ND 25 10 ug/l
95-50-1 1,2-Dichlorobenzene ND 25 6.3 ug/l
541-73-1 1,3-Dichlorobenzene ND 25 6.3 ug/l
106-46-7 1,4-Dichlorobenzene ND 25 6.3 ug/l
75-34-3 1,1-Dichloroethane ND 25 6.3 ug/l
107-06-2 1,2-Dichloroethane ND 25 6.3 ug/l
75-35-4 1,1-Dichloroethylene ND 25 6.3 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 25 6.3 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 25 6.3 ug/l
78-87-5 1,2-Dichloropropane ND 25 6.3 ug/l
142-28-9 1,3-Dichloropropane ND 25 6.3 ug/l
594-20-7 2,2-Dichloropropane ND 25 6.3 ug/l
563-58-6 1,1-Dichloropropene ND 25 6.3 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 25 6.3 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 25 6.3 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA5295933.1
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Report of Analysis Page 2 of 3
Client Sample ID:GMW-1
Lab Sample ID:FA52959-1 Date Sampled:03/29/18
Matrix:AQ - Ground Water Date Received:03/30/18
Method:SM 6200B Percent Solids:n/a
Project:Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 53.7 25 6.3 ug/l
100-41-4 Ethylbenzene 1010 25 6.3 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 25 6.3 ug/l
87-68-3 Hexachlorobutadiene ND 25 6.3 ug/l
98-82-8 Isopropylbenzene 172 25 6.3 ug/l
99-87-6 p-Isopropyltoluene ND 25 6.3 ug/l
74-83-9 Methyl Bromide ND 25 10 ug/l
74-87-3 Methyl Chloride ND 25 10 ug/l
74-95-3 Methylene Bromide ND 25 6.3 ug/l
75-09-2 Methylene Chloride ND 100 50 ug/l
1634-04-4 Methyl Tert Butyl Ether 43.0 25 6.3 ug/l
91-20-3 Naphthalene 133 25 6.3 ug/l
103-65-1 n-Propylbenzene 465 25 6.3 ug/l
100-42-5 Styrene ND 25 6.3 ug/l
75-85-4 Tert-Amyl Alcohol 612 500 100 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 50 10 ug/l
75-65-0 Tert-Butyl Alcohol ND 500 100 ug/l
762-75-4 Tert-Butyl Formate ND 500 100 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 25 6.3 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 25 6.3 ug/l
127-18-4 Tetrachloroethylene ND 25 6.3 ug/l
108-88-3 Toluene 22.0 25 6.3 ug/l J
87-61-6 1,2,3-Trichlorobenzene ND 25 6.3 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 25 6.3 ug/l
71-55-6 1,1,1-Trichloroethane ND 25 6.3 ug/l
79-00-5 1,1,2-Trichloroethane ND 25 6.3 ug/l
79-01-6 Trichloroethylene ND 25 6.3 ug/l
75-69-4 Trichlorofluoromethane ND 25 10 ug/l
96-18-4 1,2,3-Trichloropropane ND 25 6.3 ug/l
95-63-6 1,2,4-Trimethylbenzene 7.6 25 6.3 ug/l J
108-67-8 1,3,5-Trimethylbenzene ND 25 6.3 ug/l
75-01-4 Vinyl Chloride ND 25 6.3 ug/l
m,p-Xylene 23.9 50 6.3 ug/l J
95-47-6 o-Xylene ND 25 6.3 ug/l
1330-20-7 Xylene (total)23.9 75 13 ug/l J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 94%70-130%
17060-07-0 1,2-Dichloroethane-D4 88%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
7 of 34
FA5295933.1
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:GMW-1
Lab Sample ID:FA52959-1 Date Sampled:03/29/18
Matrix:AQ - Ground Water Date Received:03/30/18
Method:SM 6200B Percent Solids:n/a
Project:Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
2037-26-5 Toluene-D8 102%70-130%
460-00-4 4-Bromofluorobenzene 100%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 34
FA5295933.1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-1
Lab Sample ID:FA52959-1 Date Sampled:03/29/18
Matrix:AQ - Ground Water Date Received:03/30/18
Method:EPA 504.1 EPA 504.1 Percent Solids:n/a
Project:Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 DD98595.D 1 04/03/18 17:35 NM 04/03/18 11:10 OP69450 GDD2868
Run #2
Initial Volume Final Volume
Run #1 36.9 ml 2.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
106-93-4 1,2-Dibromoethane ND 0.019 0.0095 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 133%63-137%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
9 of 34
FA5295933.1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-1
Lab Sample ID:FA52959-1 Date Sampled:03/29/18
Matrix:AQ - Ground Water Date Received:03/30/18
Percent Solids:n/a
Project:Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Lead 698 5.0 ug/l 1 04/03/18 04/04/18 LM SW846 6010D 1 SW846 3010A 2
(1) Instrument QC Batch: MA14797
(2) Prep QC Batch: MP33545
RL = Reporting Limit
10 of 34
FA5295933.1
SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Orlando, FL
Section 4
11 of 34
FA529594
FA52959: Chain of Custody
Page 1 of 2
12 of 34
FA5295944.1
Job Number:FA52959 Client:GRI
Date / Time Received:3/30/2018 9:00:00 AM Delivery Method:FX
Project:ELIZABETH CITY
Airbill #'s:1015906964360003281100808776153974
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
IR Gun
Ice (Bag)
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments 2 VOA vials received instead of 3for EDB
SM001Rev. Date 05/24/17
SGS Sample Receipt Summary
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (3.0);
Cooler 1: (3.4);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230315 pH 10-12 219813A Other: (Specify)
Y or N N/A
Y or N
Therm ID:IR 1; Therm CF:0.4; # of Coolers:1
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:JORGEC AG Date:3/30/2018Date:3/30/2018 9:00:00 AM
FA52959: Chain of Custody
Page 2 of 2
13 of 34
FA5295944.1
SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
14 of 34
FA529595
Method Blank Summary Page 1 of 3
Job Number:FA52959
Account:GRINCC GRI (Geological Resources Inc.)
Project:Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2354-MB A0212618.D 1 04/03/18 TD n/a n/a VA2354
The QC reported here applies to the following samples:Method: SM 6200B
FA52959-1
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
15 of 34
FA5295955.1.1
Method Blank Summary Page 2 of 3
Job Number:FA52959
Account:GRINCC GRI (Geological Resources Inc.)
Project:Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2354-MB A0212618.D 1 04/03/18 TD n/a n/a VA2354
The QC reported here applies to the following samples:Method: SM 6200B
FA52959-1
CAS No.Compound Result RL MDL Units Q
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 96%70-130%
16 of 34
FA5295955.1.1
Method Blank Summary Page 3 of 3
Job Number:FA52959
Account:GRINCC GRI (Geological Resources Inc.)
Project:Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2354-MB A0212618.D 1 04/03/18 TD n/a n/a VA2354
The QC reported here applies to the following samples:Method: SM 6200B
FA52959-1
CAS No.Surrogate Recoveries Limits
17060-07-0 1,2-Dichloroethane-D4 87%70-130%
2037-26-5 Toluene-D8 99%70-130%
460-00-4 4-Bromofluorobenzene 104%70-130%
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FA5295955.1.1
Blank Spike Summary Page 1 of 3
Job Number:FA52959
Account:GRINCC GRI (Geological Resources Inc.)
Project:Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2354-BS A0212616.D 1 04/03/18 TD n/a n/a VA2354
The QC reported here applies to the following samples:Method: SM 6200B
FA52959-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 9.8 98 70-130
108-86-1 Bromobenzene 10 10.1 101 70-130
74-97-5 Bromochloromethane 10 9.6 96 70-130
75-27-4 Bromodichloromethane 10 8.9 89 70-130
75-25-2 Bromoform 10 9.7 97 70-130
104-51-8 n-Butylbenzene 10 10.3 103 70-130
135-98-8 sec-Butylbenzene 10 10.3 103 70-130
98-06-6 tert-Butylbenzene 10 9.6 96 70-130
56-23-5 Carbon Tetrachloride 10 8.3 83 70-130
108-90-7 Chlorobenzene 10 9.4 94 70-130
75-00-3 Chloroethane 10 9.6 96 60-140
67-66-3 Chloroform 10 8.9 89 70-130
95-49-8 o-Chlorotoluene 10 9.7 97 70-130
106-43-4 p-Chlorotoluene 10 10 100 70-130
124-48-1 Dibromochloromethane 10 9.8 98 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 8.8 88 70-130
106-93-4 1,2-Dibromoethane 10 10 100 70-130
75-71-8 Dichlorodifluoromethane 10 7.0 70 60-140
95-50-1 1,2-Dichlorobenzene 10 9.9 99 70-130
541-73-1 1,3-Dichlorobenzene 10 9.9 99 70-130
106-46-7 1,4-Dichlorobenzene 10 9.5 95 70-130
75-34-3 1,1-Dichloroethane 10 9.4 94 70-130
107-06-2 1,2-Dichloroethane 10 8.0 80 70-130
75-35-4 1,1-Dichloroethylene 10 8.8 88 70-130
156-59-2 cis-1,2-Dichloroethylene 10 9.9 99 70-130
156-60-5 trans-1,2-Dichloroethylene 10 8.9 89 70-130
78-87-5 1,2-Dichloropropane 10 9.9 99 70-130
142-28-9 1,3-Dichloropropane 10 9.6 96 70-130
594-20-7 2,2-Dichloropropane 10 8.3 83 70-130
563-58-6 1,1-Dichloropropene 10 9.4 94 70-130
10061-01-5 cis-1,3-Dichloropropene 10 9.6 96 70-130
10061-02-6 trans-1,3-Dichloropropene 10 9.3 93 70-130
108-20-3 Di-Isopropyl Ether 10 8.9 89 70-130
100-41-4 Ethylbenzene 10 9.3 93 70-130
637-92-3 Ethyl Tert Butyl Ether 10 9.7 97 70-130
87-68-3 Hexachlorobutadiene 10 9.5 95 70-130
* = Outside of Control Limits.
18 of 34
FA5295955.2.1
Blank Spike Summary Page 2 of 3
Job Number:FA52959
Account:GRINCC GRI (Geological Resources Inc.)
Project:Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2354-BS A0212616.D 1 04/03/18 TD n/a n/a VA2354
The QC reported here applies to the following samples:Method: SM 6200B
FA52959-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
98-82-8 Isopropylbenzene 10 10.3 103 70-130
99-87-6 p-Isopropyltoluene 10 10.5 105 70-130
74-83-9 Methyl Bromide 10 9.5 95 60-140
74-87-3 Methyl Chloride 10 10.3 103 60-140
74-95-3 Methylene Bromide 10 9.2 92 70-130
75-09-2 Methylene Chloride 10 8.2 82 70-130
1634-04-4 Methyl Tert Butyl Ether 10 9.3 93 70-130
91-20-3 Naphthalene 10 10.7 107 70-130
103-65-1 n-Propylbenzene 10 10 100 70-130
100-42-5 Styrene 10 10.0 100 70-130
75-85-4 Tert-Amyl Alcohol 100 116 116 70-130
994-05-8 Tert-Amyl Methyl Ether 10 9.2 92 70-130
75-65-0 Tert-Butyl Alcohol 100 120 120 70-130
762-75-4 Tert-Butyl Formate 100 73.2 73 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 9.2 92 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 10.2 102 70-130
127-18-4 Tetrachloroethylene 10 9.5 95 70-130
108-88-3 Toluene 10 9.9 99 70-130
87-61-6 1,2,3-Trichlorobenzene 10 9.9 99 70-130
120-82-1 1,2,4-Trichlorobenzene 10 10 100 70-130
71-55-6 1,1,1-Trichloroethane 10 8.3 83 70-130
79-00-5 1,1,2-Trichloroethane 10 10.1 101 70-130
79-01-6 Trichloroethylene 10 9.2 92 70-130
75-69-4 Trichlorofluoromethane 10 8.8 88 60-140
96-18-4 1,2,3-Trichloropropane 10 9.6 96 70-130
95-63-6 1,2,4-Trimethylbenzene 10 9.8 98 70-130
108-67-8 1,3,5-Trimethylbenzene 10 10.3 103 70-130
75-01-4 Vinyl Chloride 10 10.9 109 60-140
m,p-Xylene 20 19.2 96 70-130
95-47-6 o-Xylene 10 9.8 98 70-130
1330-20-7 Xylene (total)30 29.0 97 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 92%70-130%
* = Outside of Control Limits.
19 of 34
FA5295955.2.1
Blank Spike Summary Page 3 of 3
Job Number:FA52959
Account:GRINCC GRI (Geological Resources Inc.)
Project:Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2354-BS A0212616.D 1 04/03/18 TD n/a n/a VA2354
The QC reported here applies to the following samples:Method: SM 6200B
FA52959-1
CAS No.Surrogate Recoveries BSP Limits
17060-07-0 1,2-Dichloroethane-D4 82%70-130%
2037-26-5 Toluene-D8 103%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
* = Outside of Control Limits.
20 of 34
FA5295955.2.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:FA52959
Account:GRINCC GRI (Geological Resources Inc.)
Project:Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA52959-1MS A0212636.D 50 04/04/18 TD n/a n/a VA2354
FA52959-1MSD A0212637.D 50 04/04/18 TD n/a n/a VA2354
FA52959-1 A0212632.D 50 04/04/18 TD n/a n/a VA2354
The QC reported here applies to the following samples:Method: SM 6200B
FA52959-1
FA52959-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 1660 500 2170 102 500 2150 98 1 70-130/20
108-86-1 Bromobenzene ND 500 500 100 500 505 101 1 70-130/20
74-97-5 Bromochloromethane ND 500 461 92 500 468 94 2 70-130/20
75-27-4 Bromodichloromethane ND 500 402 80 500 400 80 0 70-130/20
75-25-2 Bromoform ND 500 330 66*500 371 74 12 70-130/20
104-51-8 n-Butylbenzene 55.9 500 586 106 500 591 107 1 70-130/20
135-98-8 sec-Butylbenzene 28.6 500 561 106 500 572 109 2 70-130/20
98-06-6 tert-Butylbenzene ND 500 493 99 500 493 99 0 70-130/20
56-23-5 Carbon Tetrachloride ND 500 407 81 500 385 77 6 70-130/20
108-90-7 Chlorobenzene ND 500 475 95 500 471 94 1 70-130/20
75-00-3 Chloroethane ND 500 481 96 500 469 94 3 60-140/20
67-66-3 Chloroform ND 500 438 88 500 432 86 1 70-130/20
95-49-8 o-Chlorotoluene ND 500 494 99 500 491 98 1 70-130/20
106-43-4 p-Chlorotoluene ND 500 497 99 500 495 99 0 70-130/20
124-48-1 Dibromochloromethane ND 500 386 77 500 400 80 4 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 500 504 101 500 505 101 0 70-130/20
106-93-4 1,2-Dibromoethane ND 500 489 98 500 498 100 2 70-130/20
75-71-8 Dichlorodifluoromethane ND 500 365 73 500 346 69 5 60-140/20
95-50-1 1,2-Dichlorobenzene ND 500 498 100 500 499 100 0 70-130/20
541-73-1 1,3-Dichlorobenzene ND 500 510 102 500 506 101 1 70-130/20
106-46-7 1,4-Dichlorobenzene ND 500 476 95 500 476 95 0 70-130/20
75-34-3 1,1-Dichloroethane ND 500 457 91 500 454 91 1 70-130/20
107-06-2 1,2-Dichloroethane ND 500 378 76 500 371 74 2 70-130/20
75-35-4 1,1-Dichloroethylene ND 500 439 88 500 434 87 1 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 500 497 99 500 488 98 2 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 500 442 88 500 424 85 4 70-130/20
78-87-5 1,2-Dichloropropane ND 500 495 99 500 495 99 0 70-130/20
142-28-9 1,3-Dichloropropane ND 500 479 96 500 488 98 2 70-130/20
594-20-7 2,2-Dichloropropane ND 500 326 65*500 315 63*3 70-130/20
563-58-6 1,1-Dichloropropene ND 500 474 95 500 466 93 2 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 500 449 90 500 428 86 5 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 500 432 86 500 418 84 3 70-130/20
108-20-3 Di-Isopropyl Ether 53.7 500 482 86 500 484 86 0 70-130/20
100-41-4 Ethylbenzene 1010 500 1480 94 500 1470 92 1 70-130/20
637-92-3 Ethyl Tert Butyl Ether ND 500 467 93 500 472 94 1 70-130/20
87-68-3 Hexachlorobutadiene ND 500 482 96 500 478 96 1 70-130/20
* = Outside of Control Limits.
21 of 34
FA5295955.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:FA52959
Account:GRINCC GRI (Geological Resources Inc.)
Project:Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA52959-1MS A0212636.D 50 04/04/18 TD n/a n/a VA2354
FA52959-1MSD A0212637.D 50 04/04/18 TD n/a n/a VA2354
FA52959-1 A0212632.D 50 04/04/18 TD n/a n/a VA2354
The QC reported here applies to the following samples:Method: SM 6200B
FA52959-1
FA52959-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
98-82-8 Isopropylbenzene 172 500 718 109 500 718 109 0 70-130/20
99-87-6 p-Isopropyltoluene ND 500 540 108 500 541 108 0 70-130/20
74-83-9 Methyl Bromide ND 500 464 93 500 448 90 4 60-140/20
74-87-3 Methyl Chloride ND 500 468 94 500 509 102 8 60-140/20
74-95-3 Methylene Bromide ND 500 470 94 500 448 90 5 70-130/20
75-09-2 Methylene Chloride ND 500 393 79 500 390 78 1 70-130/20
1634-04-4 Methyl Tert Butyl Ether 43.0 500 495 90 500 503 92 2 70-130/20
91-20-3 Naphthalene 133 500 669 107 500 703 114 5 70-130/20
103-65-1 n-Propylbenzene 465 500 995 106 500 987 104 1 70-130/20
100-42-5 Styrene ND 500 498 100 500 509 102 2 70-130/20
75-85-4 Tert-Amyl Alcohol 612 5000 6150 111 5000 6520 118 6 70-130/20
994-05-8 Tert-Amyl Methyl Ether ND 500 451 90 500 463 93 3 70-130/20
75-65-0 Tert-Butyl Alcohol ND 5000 6980 140*5000 7060 141*1 70-130/20
762-75-4 Tert-Butyl Formate ND 5000 3750 75 5000 4050 81 8 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 500 454 91 500 442 88 3 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 500 528 106 500 539 108 2 70-130/20
127-18-4 Tetrachloroethylene ND 500 486 97 500 483 97 1 70-130/20
108-88-3 Toluene 22.0 J 500 527 101 500 531 102 1 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 500 500 100 500 515 103 3 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 500 520 104 500 523 105 1 70-130/20
71-55-6 1,1,1-Trichloroethane ND 500 403 81 500 393 79 3 70-130/20
79-00-5 1,1,2-Trichloroethane ND 500 548 110 500 565 113 3 70-130/20
79-01-6 Trichloroethylene ND 500 459 92 500 444 89 3 70-130/20
75-69-4 Trichlorofluoromethane ND 500 424 85 500 417 83 2 60-140/20
96-18-4 1,2,3-Trichloropropane ND 500 457 91 500 485 97 6 70-130/20
95-63-6 1,2,4-Trimethylbenzene 7.6 J 500 506 100 500 507 100 0 70-130/20
108-67-8 1,3,5-Trimethylbenzene ND 500 519 104 500 522 104 1 70-130/20
75-01-4 Vinyl Chloride ND 500 543 109 500 547 109 1 60-140/20
m,p-Xylene 23.9 J 1000 995 97 1000 995 97 0 70-130/20
95-47-6 o-Xylene ND 500 510 102 500 518 104 2 70-130/20
1330-20-7 Xylene (total)23.9 J 1500 1510 99 1500 1510 99 0 70-130/20
CAS No.Surrogate Recoveries MS MSD FA52959-1 Limits
1868-53-7 Dibromofluoromethane 89%89%94%70-130%
* = Outside of Control Limits.
22 of 34
FA5295955.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:FA52959
Account:GRINCC GRI (Geological Resources Inc.)
Project:Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA52959-1MS A0212636.D 50 04/04/18 TD n/a n/a VA2354
FA52959-1MSD A0212637.D 50 04/04/18 TD n/a n/a VA2354
FA52959-1 A0212632.D 50 04/04/18 TD n/a n/a VA2354
The QC reported here applies to the following samples:Method: SM 6200B
FA52959-1
CAS No.Surrogate Recoveries MS MSD FA52959-1 Limits
17060-07-0 1,2-Dichloroethane-D4 78%78%88%70-130%
2037-26-5 Toluene-D8 103%104%102%70-130%
460-00-4 4-Bromofluorobenzene 101%101%100%70-130%
* = Outside of Control Limits.
23 of 34
FA5295955.3.1
SGS North America Inc.
GC Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 6
24 of 34
FA529596
Method Blank Summary Page 1 of 1
Job Number:FA52959
Account:GRINCC GRI (Geological Resources Inc.)
Project:Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP69450-MB DD98587.D 1 04/03/18 NM 04/03/18 OP69450 GDD2868
The QC reported here applies to the following samples:Method: EPA 504.1
FA52959-1
CAS No.Compound Result RL MDL Units Q
106-93-4 1,2-Dibromoethane ND 0.020 0.010 ug/l
CAS No.Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 92%63-137%
25 of 34
FA5295966.1.1
Blank Spike Summary Page 1 of 1
Job Number:FA52959
Account:GRINCC GRI (Geological Resources Inc.)
Project:Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP69450-BS DD98586.D 1 04/03/18 NM 04/03/18 OP69450 GDD2868
The QC reported here applies to the following samples:Method: EPA 504.1
FA52959-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
106-93-4 1,2-Dibromoethane 0.25 0.26 104 70-130
CAS No.Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 95%63-137%
* = Outside of Control Limits.
26 of 34
FA5295966.2.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FA52959
Account:GRINCC GRI (Geological Resources Inc.)
Project:Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP69450-MS DD98590.D 1 04/03/18 NM 04/03/18 OP69450 GDD2868
OP69450-MSD DD98591.D 1 04/03/18 NM 04/03/18 OP69450 GDD2868
FA52839-2 DD98589.D 1 04/03/18 NM 04/03/18 OP69450 GDD2868
The QC reported here applies to the following samples:Method: EPA 504.1
FA52959-1
FA52839-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
106-93-4 1,2-Dibromoethane 0.019 U 0.242 0.21 87 0.249 0.22 89 5 70-130/25
CAS No.Surrogate Recoveries MS MSD FA52839-2 Limits
460-00-4 4-Bromofluorobenzene 78%83%84%63-137%
* = Outside of Control Limits.
27 of 34
FA5295966.3.1
SGS North America Inc.
Metals Analysis
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Matrix Spike and Duplicate Summaries
• Blank Spike and Lab Control Sample Summaries
• Serial Dilution Summaries
Orlando, FL
Section 7
28 of 34
FA529597
BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA52959
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
QC Batch ID: MP33545 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 04/03/18
MB
Metal RL IDL MDL raw final
Aluminum 200 14 14
Antimony 6.0 1 1
Arsenic 10 1.3 1.3
Barium 200 1 1
Beryllium 4.0 .2 .2
Cadmium 5.0 .2 .2
Calcium 1000 50 50
Chromium 10 1 1
Cobalt 50 .2 .2
Copper 25 1 1
Iron 300 17 17
Lead 5.0 1 1.1 0.90 <5.0
Magnesium 5000 35 35
Manganese 15 .5 1
Molybdenum 50 .3 .3
Nickel 40 .4 .4
Potassium 10000 200 200
Selenium 10 2.4 2.9
Silver 10 .7 .7
Sodium 10000 500 500
Strontium 10 .5 .5
Thallium 10 1.1 1.4
Tin 50 .9 1
Titanium 10 .5 1
Vanadium 50 .5 .6
Zinc 20 3 4.4
Associated samples MP33545: FA52959-1
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
29 of 34
FA5295977.1.1
MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA52959
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
QC Batch ID: MP33545 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 04/03/18 04/03/18
FA52895-4 QC FA52895-4 Spikelot QC
Metal Original DUP RPD Limits Original MS MPFLICP2 % Rec Limits
Aluminum
Antimony
Arsenic anr
Barium
Beryllium
Cadmium anr
Calcium
Chromium anr
Cobalt anr
Copper anr
Iron
Lead 0.0 0.0 NC 0-20 0.0 483 500 96.6 80-120
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium anr
Silver anr
Sodium
Strontium
Thallium
Tin anr
Titanium
Vanadium
Zinc anr
Associated samples MP33545: FA52959-1
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
30 of 34
FA5295977.1.2
MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA52959
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
QC Batch ID: MP33545 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 04/03/18
FA52895-4 Spikelot MSD QC
Metal Original MSD MPFLICP2 % Rec RPD Limit
Aluminum
Antimony
Arsenic anr
Barium
Beryllium
Cadmium anr
Calcium
Chromium anr
Cobalt anr
Copper anr
Iron
Lead 0.0 471 500 94.2 2.5 20
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium anr
Silver anr
Sodium
Strontium
Thallium
Tin anr
Titanium
Vanadium
Zinc anr
Associated samples MP33545: FA52959-1
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 2
31 of 34
FA5295977.1.2
SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA52959
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
QC Batch ID: MP33545 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 04/03/18
BSP Spikelot QC
Metal Result MPFLICP2 % Rec Limits
Aluminum
Antimony
Arsenic anr
Barium
Beryllium
Cadmium anr
Calcium
Chromium anr
Cobalt anr
Copper anr
Iron
Lead 483 500 96.6 80-120
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium anr
Silver anr
Sodium
Strontium
Thallium
Tin anr
Titanium
Vanadium
Zinc anr
Associated samples MP33545: FA52959-1
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
32 of 34
FA5295977.1.3
SERIAL DILUTION RESULTS SUMMARY
Login Number: FA52959
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
QC Batch ID: MP33545 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 04/03/18
FA52895-4 QC
Metal Original SDL 1:5 %DIF Limits
Aluminum
Antimony
Arsenic anr
Barium
Beryllium
Cadmium anr
Calcium
Chromium anr
Cobalt anr
Copper anr
Iron
Lead 0.00 0.00 NC 0-10
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium anr
Silver anr
Sodium
Strontium
Thallium
Tin anr
Titanium
Vanadium
Zinc anr
Associated samples MP33545: FA52959-1
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
33 of 34
FA5295977.1.4
POST DIGESTATE SPIKE SUMMARY
Login Number: FA52959
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Elizabeth City Garage; 410 Pritchard St, Elizabeth City, NC
QC Batch ID: MP33545 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 04/03/18
Sample Final FA52895-4 PS Spike Spike Spike QC
Metal ml ml Raw Corr.** ug/l ml ug/ml ug/l % Rec Limits
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead 9.8 10 44.1 0.2 2.5 50 88.2 80-120
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP33545: FA52959-1
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(**) Corr. sample result = Raw * (sample volume / final volume)
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
34 of 34
FA5295977.1.5