RA-8491_46552_CA_RPTS_20220930

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]

September 30, 2022

Ms. Allison Ward
North Carolina Department of
Environmental Quality
Washington Regional Office
943 Washington Square Mall
Washington, North Carolina 27889

Re: Comprehensive Site Assessment Report
March 2021 – August 2022
P&K Food Mart
1510 Goldsboro Street South
Wilson, Wilson County
North Carolina
Facility ID Numbers: 0-00-0000031246
Incident Numbers: 19233/46552
GRI Project Number: 5079

Dear Ms. Ward,

Please find enclosed the referenced report for the above mentioned site.
If you have any questions, please contact Rae Brown at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Mr. Johnny Nasser; P&K Mart. LLC, file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
Comprehensive Site Assessment Report
March 2021 – August 2022
P&K Food Mart
1510 Goldsboro Street South
Wilson, Wilson County
North Carolina
Facility ID Number: 0-00-0000031246
Incident Number: 19233/46552
GRI Project Number: 5079

Prepared for:

Johnny Nasser
P&K Mart, LLC
1510 Goldsboro Street
Wilson, North Carolina, 27893

September 30, 2022

Rae Troiano Brown, P.G.
Project Manager
AJ Discepolo
Report Writer

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 30, 2022 P&K Food Mart
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5079
i
EXECUTIVE SUMMARY
The P&K Food Mart site is an active convenience store and petroleum retail facility located at 1510
Goldsboro Street South in Wilson, Wilson County, North Carolina. The site is covered by concrete and
asphalt. One 12,000-gallon diesel and two 12,000-gallon gasoline USTs with five associated dispensers
are in use at the site. One 12, 000-gallon gasoline, one 12,000-gallon diesel UST, and one 12,000-gallon
kerosene UST are in temporary closure. The surrounding properties are commercial, residential, office,
and public/institutional.

On November 13, 2019, an updated receptor survey was conducted. No water supply wells were
observed in 1,500-foot radius of the site. Public water is available to the subject site and to all surrounding
properties. No surface water bodies were identified within a 500-foot radius of the site. The site is not
located in a wellhead protection area.

Between November and December 2019, one monitoring well was installed and sampled as part of the
LSA activities. Based on the results of the LSA activities, additional assessment was required.

On August 25, 2021, three shallow Type II monitoring wells and one deep Type II monitoring well were
installed as part of additional assessment activities. Based on the results of the additional assessment, a
CSA was required.

Between March 7, 2022 and August 8, 2022, five Type II monitoring wells were installed as part of the CSA
activities. Contaminant concentrations of benzene, toluene, ethylbenzene, xylenes, MTBE, naphthalene,
TAA, TBA, methyl chloride, 1,2-dichloroethane, isopropylbenzene, n-propylbenzene, 1,2,4-
triethylbenzene, 1,3,5-trimethylbenzene, bis 2-ethylhexyl)phthalate (DEHP), 1-methylnaphthalene, 2-
methylnaphthalene, C5-C8 aliphatics, C9-C10 aromatics and/or C11-C22 aromatics reported in the ground
water samples collected from GMW-1 through GMW-8, SW-1 and DW-1 exceeded the MACs. The
benzene concentration reported in the ground water samples collected from GMW-1, GMW-4, and SW-1
exceeded the GCL. No free product was found on the site.

Soil encountered during the monitoring well installation activities was primarily fine sand and clay silt.
Rising head slug tests were conducted on GMW-2, GMW-4, and DW-1 in September 2021. The average
hydraulic conductivity and seepage velocity for the shallow Type II monitoring wells 8.848 x 10-5 feet per
minute (1.274 x 10-1 feet per day) and 9.56 x 10-2 feet per day (34.9 feet per year), respectively. The
hydraulic conductivity and seepage velocity in the deep Type II monitoring well were 4.105 x 10-5 feet per
minute (5.911 x 10-2 feet per day) and 4.43 x 10-2 feet per day (16.2 feet per year), respectively.

The risk classification for the site should remain intermediate risk based on the presence of GCL
exceedances. Therefore, ground water contamination must be remediated to below the GCLs. Please
note that the contaminant plume is not adequately defined to the west; however, access was denied by
the property owner. Therefore, no well was installed on the property to the west of the site.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 30, 2022 P&K Food Mart
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5079
ii

A comprehensive ground water sampling event should be conducted in February 2023 to establish
contaminant trends. Once plume stability has been established, a remedial strategy can be proposed.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 30, 2022 P&K Food Mart
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5079
iii
SITE INFORMATION
1. Site Identification
 P&K Food Mart (Facility ID 0-00-0000031246)
 Incident Number 19233/46552 – Intermediate Risk (I115D)
 Location of Source Area: 1510 Goldsboro Street South
Wilson, NC 28677
Wilson County
35.7106380°N, 77.9257070°W (Topographical Map)

2. Information about Contacts Associated with the Leaking UST System

UST/AST Owner
P&K Food Mart
1510 Goldsboro St. S
Wilson, NC 27893
[e-mail]
901-318-1538

UST/AST Operator
P&K Food Mart
1510 Goldsboro St. S
Wilson, NC 27893
[e-mail]
901-318-1538

Property Owner
Lions House, LLC
5014 Country Club Dr. NW
Wilson, NC 27896
Email Unknown
252-206-6667

Property Occupant
P&K Mart
1510 Goldsboro Street
Wilson, NC 27893
[e-mail]
901-318-1538

Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-845-4010

Analytical Laboratory
Waypoint Analytical, LLC
449 Springbrook Road
Charlotte, NC 28217
State Certification No. 402
704-529-6364
3. Information about Release
 In 1993, a release was reported at the site which was closed when an NRP for ground water was filed in
2014.
 A release was discovered on April 3, 2019.
 An unknown amount of product was released to the subsurface from the non-passing diesel dispenser
and associated product piping.
 One 12,000-gallon diesel and two 12,000-gallon gasoline USTs are in use at the site. Please note
that on 12,000-gallon gasoline UST, one 12,000-gallon diesel UST and one 12,000-gallon kerosene
UST are in temporary closure.

Certification:

I, Rae Troiano Brown, a Professional Geologist for Geological Resources, Inc., do certify that the
information contained in this report is correct and accurate to the best of my knowledge.

Geological Resources, Inc. is licensed to practice geology and engineering in North Carolina. The
certification numbers of the company are C-127 and C-2727, respectively.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 30, 2022 P&K Food Mart
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5079
iv
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality

NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWAP: Source Water Assessment and
Protection
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 30, 2022 P&K Food Mart
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5079
TABLE OF CONTENTS
EXECUTIVE SUMMARY ....................................................................................................................... i
SITE INFORMATION ........................................................................................................................... iii
ACRONYMS ....................................................................................................................................... iv
1.0 SITE HISTORY AND CHARACTERIZATION ...................................................................................1
RECEPTOR INFORMATION ..................................................................................................................3
2.0 LAND USE ................................................................................................................................3
3.0 SOIL ASSESSMENT ...................................................................................................................3
4.0 GROUND WATER ASSESSMENT ................................................................................................4
5.0 FREE PRODUCT INVESTIGATION AND RECOVERY ......................................................................7
6.0 HYDROGEOLOGIC INVESTIGATION ...........................................................................................7
7.0 REGIONAL GEOLOGY AND HYDROGEOLOGY .............................................................................8
8.0 SITE GEOLOGY AND HYDROGEOLOGY ......................................................................................8
9.0 DISCUSSION ............................................................................................................................8
10.0 CONCLUSIONS AND RECOMMENDATIONS ...............................................................................9
11.0 PUBLIC NOTICE ........................................................................................................................9
12.0 LIMITATIONS ...........................................................................................................................9
13.0 REFERENCES ............................................................................................................................9

FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3: Site Vicinity Map
Figure 4: Soil Quality Map
Figure 5: Cross-Section A-A’
Figure 6: Cross-Section B-B’
Figure 7: Ground Water Quality Map
Figure 8: Benzene Isoconcentration Map
Figure 9: Water Table Surface Map
TABLES
Table 1: UST Owner and Operator Information
Table 2: UST System Information
Table 3: Adjacent Property Owner Information
Table 4: Land Use Information
Table 5: Summary of Soil Sample Analytical Results
Table 6: Summary of Ground Water Sample Analytical Results
Table 7: Well Construction and Gauging Information
Table 8: Summary of Slug Test Analyses

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 30, 2022 P&K Food Mart
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5079
APPENDICES
Appendix A: State Correspondence
Appendix B: Well Construction Records
Appendix C: Laboratory Analytical Report
Appendix D: Slug Test Data
Appendix E: Public Notification

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 30, 2022 P&K Food Mart
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5079
1
1.0 SITE HISTORY AND CHARACTERIZATION
GRI presents the results of the August 2021 through August 2022 CSA activities at the P&K Food Mart site;
located at 1510 Goldsboro Street South in Wilson, Wilson County, North Carolina (Figure 1). These
activities were conducted in accordance with GRI Proposal Nos. 22-115 and 22-350, which were submitted
to the NCDEQ on February 9, 2022 and May 12, 2022, and were approved as Task Authorization Nos.
19233/46552-4 and 19233/46552-5 on February 16, 2022 and May 13, 2022, respectively. State
correspondence has been included as Appendix A.

The site is currently owned and operated by P&K Mart LLC. as a convenience store and petroleum retail
facility. Two 12,000-gallon gasoline and one 12,000-gallon diesel USTs are currently in use at the site with
four associated gasoline and one diesel dispenser islands. Also, there are one 12,000-gallon gasolines,
one 12,000-gallon diesel, and one 12,000-gallon kerosene USTs on the site that are currently in temporary
closure. UST owner/operator information and UST system information are included as Tables 1 and 2,
respectively. The Registered Tank Report is shown below:

In 1993, the site was occupied by Winoco #6-Wilson which reported a release (Incident 19233). An LSA
was conducted at the site in 2004 and the site was classified as low risk. In 2014, the incident was closed
after an NRP was filed for ground water. A copy of the NCDEQ Incident Report is included in Appendix A.

On October 29, 2018, during annual compliance testing activities, a non-passing line tightness test was
reported for the diesel dispenser and its associated product line. A Site Check was conducted in March
2019. The RALs, soil-to-water MCCs, and/or residential SCLs were below the concentrations of GRO,

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 30, 2022 P&K Food Mart
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5079
2
benzene, toluene, ethylbenzene, xylenes and/or MTBE reported in soil samples SB-1-3’ and SB-2-3’. Based
on these results, a release was confirmed at the site and an LSA was required.

On November 14, 2019, one Type II monitoring well (GMW-1) was installed in the location of SB-1-3’. On
December 2, 2019, GMW-1 was gauged, purged, and sampled during LSA activities. The collected ground
water sample was submitted for analysis of VOCs and oxygenates by EPA Method 6200 and semi-VOCs by
EPA Method 625. The MACs were below the reported concentrations of individual BTEX constituents,
MTBE, naphthalene, isopropybenzene, n-propybenzene, 1,2,4-trimethylbnzene, TAA, TBA, 2,4-
dimethylphenol, 1-methylnaphthalene, 2-methylnaphthalene, and phenol in GMW-1. The benzene
concentration ecxeeded the GCL. No free product was observed at the site. Based on the results of the
LSA, additional assessment was required.

On August 25, 2021, four Type II monitoring wells (GMW-2, GMW-3, GMW-4, and DW-1) were installed
during additional assessment activities. DW-1 was intended to be installed as a Type III telescoping well,
but the fuel canopy was too low to allow this. Therefore, DW-1 was installed as a deep Type II monitoring
well instead. Soil samples were collected from three monitoring well boreholes, and ground water
samples were collected from five monitoring wells. No free product was observed. The RAL of TPH-GRO
was below the contaminant concentrations reported in soil samples GMW-2-5’, GMW-4-5’, DW-1-15’, and
DW-1-5’. On August 26, 2021, ground water samples collected from the monitoring wells (GMW-1 through
GMW-4 and DW-1 for laboratory analysis of VOCs and oxygenates by EPA Method 6200B and SVOCs by
EPA Method 625. The MACs were below the concentrations of individual BTEX constituents, MTBE,
naphthalene, TAA, TBA, ethanol, isopropylbenzene, n-propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-
trimethylbenzene, 1-methylnaphthalene, and/or 2-methylnaphthalene reported in the ground water
samples collected from each well. The GCL was below the reported concentrations of benzene in the
samples collected from GMW-1 and GMW-4. Based on the results of the assessment activities, a CSA was
required.

On March 7, 2022, three Type II monitoring wells (GMW-5 through GMW-7) were installed, and on March
8, 2022, all of the onsite monitoring wells were gauged, purged and sampled. Contaminant
concentrations of individual BTEX constituents, MTBE, naphthalene, TAA, TBA, methyl chloride, 1,2-
dichloroethane, isopropylbenzene, n-propylbenzene, 1,2,4-triethylbenzene, 1,3,5-trimethylbenzene,
bis(2-ethylhexyl)phthalate (DEHP), 1-methylnaphthalene, 2-methylnaphthalene, C5-C8 aliphatics, C9-C10
aromatics, and/or C11-C22 aromatics reported in the ground water samples collected from GMW-1
through GMW-7, SW-1, and DW-1 exceeded the MACs. The benzene concentration reported in the
ground water samples collected from GMW-1, GMW-4, and SW-1 exceeded the GCL. No free product was
found in any of the ground water samples. The contaminant plume remained undefined; therefore,
additional CSA activities were required.

August 8, 2022, two additional Type II monitoring wells (GMW-8 and GMW-9) were installed, gauged, and
sampled. The concentration of benzene reported in the ground water sample collected from GMW-8

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 30, 2022 P&K Food Mart
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5079
3
exceeded the MAC. None of the reported concentration exceeded the GCLs. A Site Map showing the
locations of the monitoring wells and the structures on-site has been included as Figure 2.

RECEPTOR INFORMATION
Water Supply Wells:
On November 14, 2019, GRI personnel conducted a receptor survey at the site. No water supply wells
were identified within a 1,500-foot radius of the site.

Public Water Supplies:
Public water is available to the site and all of the surrounding properties. Water lines run along the public
streets in the area. Public water is supplied by the Wilson County Water Department.

Surface Water:
No surface water bodies were identified within a 500-foot radius of the site during the November 2019
receptor survey.

Wellhead Protection Areas:
On August 19, 2022, GRI personnel accessed the NCDEQ SWAP Program’s website to identify wellhead
protection areas in the vicinity of the subject site. The site is not located within a wellhead protection
area.

Deep Aquifers in the Coastal Plain Physiographic Region:
The site is located within the Coastal Plain Physiographic Province of North Carolina. The site is underlain
by the Yorktown aquifer. The Yorktown confining unit is present in the vicinity of the site.

Subsurface Structures:
No structures with basements were observed in the vicinity of the source area. Utilities in the source area
are located along Goldsboro Street and Barron Street and do not appear to intersect the seasonal high
water table.

2.0 LAND USE
The site is currently occupied by a petroleum retail facility and convenience store. The closest primary
residence is located on an adjacent property approximately 60 feet west of the source area. The adjoining
properties are commercial and residential. According to the City of Wilson Official Zoning Map, the
surrounding areas are zoned Residential and Commercial. Adjacent property owner information and land
use information have been summarized in Tables 3 and 4, respectively. A Vicinity Map and a Zoning Map
have been included as Figures 3A and 3B, respectively.

3.0 SOIL ASSESSMENT
On March 21, 2019, during Site Check activities, soil samples SB-1-3’ and SB-2-3’ were collected and
submitted for laboratory analyses. The applicable RAL and/or soil-to-water MCCs were below the

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 30, 2022 P&K Food Mart
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5079
4
concentrations of GRO, benzene, toluene, ethylbenzene xylenes and/or MTBE were reported in the soil
samples collected from SB-1-3’ and SB-2-3’. The residential SCLs were below the concentrations of
benzene for SB-1-3’.

On November 14, 2019, a soil sample (GMW-1-5’) was collected at 5-feet during the installation of
monitoring well GMW-1. The soil-to-water MCCs were below the concentrations of individual BTEX
constituents, MTBE, C5-C8 aliphatics, and C9-C10 aromatics reported in soil sample GMW-1-5’. The
residential SCL was below the concentration of C5-C8 aliphatics in soil sample GMW-1-5’.

On August 25, 2021, during the installation of the monitoring wells, soil samples were collected at depths
ranging from 5 to 15 feet. The RALs were below the concentrations of TPH GRO reported in samples GMW-
2-5’, GMW-4-5’, DW-1-5’, and DW-1-15’. A summary of the analytical results for soil samples is presented
in Table 5. A Soil Quality Map based on the August 2021 data is included as Figure 4

Clean, disposable nitrile gloves were used for the collection of the soil samples. The samples were
collected in laboratory supplied containers and shipped to the laboratory in a cooler following proper
chain-of-custody procedures.

4.0 GROUND WATER ASSESSMENT
One Type II monitoring well (GMW-1) was installed during LSA activities at the site. The concentrations
of individual BTEX constituents, MTBE, naphthalene, isopropybenzene, n-propybenzene, 1,2,4-
trimethylbnzene, TAA, TBA, 2,4-dimethylphenol, 1-methylnaphthalene, 2-methylnaphthalene, and
phenol in the ground water sample collected from GMW-1 exceeded the MACs. The benzene
concentration exceeded the GCL. No free product was observed at the site.

On August 25, 2021, four Type II monitoring wells (GMW-2, GMW-3, GMW-4, and DW-1) were installed
to provide additional risk assessment. On August 26, 2021, GMW-1 through GMW-4 and DW-1 were
gauged, purged, and sampled. The MACs were below the concentrations of individual BTEX constituents,
MTBE, naphthalene, TAA, TBA, ethanol, isopropylbenzene, n-propylbenzene, 1,2,4-trimethylbenzene,
1,3,5-trimethylbenzene, 1-methylnaphthalene, and/or 2-methylnaphthalene reported in the ground
water samples collected from Each well. The GCL was below the reported concentrations of benzene in
the samples collected from GMW-1 and GMW-4.

On March 7, 2022, three Type II monitoring wells (GMW-5, GMW-6 and GMW-7) were installed to a total
depth of 15 feet each with a 10-foot screened interval. Well photos are shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 30, 2022 P&K Food Mart
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5079
5

On March 8, 2022, monitoring wells GMW-1 through GMW-7, SW-1, and DW-1 were gauged, purged, and
sampled. Concentrations of individual BTEX constituents, MTBE, naphthalene, TAA, TBA, methyl chloride,
1,2-dichloroethane, isopropylbenzene, n-propylbenzene, 1,2,4-triethylbenzene, 1,3,5-trimethylbenzene,
bis(2-ethylhexyl)phthalate (DEHP), 1-methylnaphthalene, 2-methylnaphthalene, C5-C8 aliphatics, C9-C10
aromatics and/or C11-C22 aromatics reported in the ground water samples collected from GMW-1
through GMW-7, SW-1, and DW-1 exceeded the MACs. The benzene concentration reported in the
ground water samples collected from GMW-1, GMW-4, and SW-1 exceeded the GCL.

On August 10, 2022. Two additional Type II monitoring wells (MW-8 and MW-9) were installed adjacent
to the site in the DOT right-of-way to a total depth of 15 feet each with a 10-foot screened interval. The

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 30, 2022 P&K Food Mart
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5079
6
owner of the adjacent property to the west declined to allow access for well installation. Copies of the
well permits and the denied access agreement are included in Appendix B. Well photos are shown below:

On August 15, 2022, monitoring wells GMW-8 and GMW-9 were gauged, purged and sampled. The
concentration of benzene reported in the ground water sample collected from GMW-8 exceeded the
MAC. None of the reported concentration exceeded the GCLs. A summary of the March 8, 2022 and
August 15, 2022 ground water analytical data is shown below:

Contaminant of
Concern Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Well ID
MACs (µg/l) 1 600 600 500 20 6
GCL (µg/l) 5,000 260,000 80,000 50,000 20,000 6,000
GMW-1 8,100 1,940 1,190 2,890 85.0 J 121
GMW-2 3,480 E 66.5 253 131.9 12.8 J 91.7
GMW-3 1,440 11.2 92.8 62.7 33.4 21.1
GMW-4 9,780 158 J 849 654 J <63 378
GMW-5 43.5 J <13 56.4 74.2 J <13 <13
GMW-6 2,260 451 447 1,280 50.3 J 115
GMW-7 1,000 143 116 269.8 <6.3 67.8
GMW-8 1.12 <0.220 0.528 0.670 J <0.140 <0.470
GMW-9 0.385 J <0.220 0.209 J <0.210 <0.140 <0.470
SW-1 9,650 <63 1,450 888 <63 138 J
DW-1 16.9 1.5 14.5 5.5 11.4 7.6

All samples were collected in accordance with the NCDEQ guidelines. Clean, disposable bailers and nitrile
gloves were used for the collection of the ground water samples. The samples were collected in

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 30, 2022 P&K Food Mart
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5079
7
laboratory supplied containers and shipped to the laboratory in a cooler following proper chain-of-custody
procedures. A laboratory supplied trip blank was included in the sample cooler. No detectable
concentrations of requested method constituents were reported in the trip blank.

The locations of the monitoring wells are shown on Figure 2. Well construction records for the monitoring
wells installed during CSA activities have been included as Appendix B.

Cross sections A-A’ and B-B’ are included as Figures 5 and 6; the lines of cross section are included on
Figure 2. A Ground Water Quality Map for the March 2022 and August 2022 ground water sampling
events has been included as Figure 7. A benzene isoconcentration map for is included as Figure 8. A
summary of laboratory analyses for the ground water samples collected during CSA activities has been
included as Table 6. Complete copies of the laboratory reports for the ground water samples have been
included as Appendix C.

5.0 FREE PRODUCT INVESTIGATION AND RECOVERY
Free product has historically not been present in site monitoring wells.

6.0 HYDROGEOLOGIC INVESTIGATION
The depths to ground water in the Type II monitoring wells (GMW-1 through GMW-9, SW-1 through SW-
4) measured on August 15, 2022, ranged from 2.55 to 13.78 feet below the tops of well casings. Ground
water elevations at the site, based on an assumed datum of 100 feet, ranged from 85.65 to 97.45 feet
relative to a temporary benchmark. Based on this information, the ground water flow direction was
generally toward the east. The horizontal hydraulic gradient between SW-1 and GMW-9 was
approximately 0.06 feet per foot. The vertical hydraulic gradient could not be calculated for paired wells
GMW-1/DW-1 because DW-1 was not measured during the August 15 gauging event. A summary of
ground water elevation data obtained during assessment activities to date is presented in Table 7. A
Water Table Surface Map based on the August 15, 2022 gauging data is included as Figure 9.

Rising head slug tests were conducted in GMW-2, GMW-4, and DW-1 on September 27, 2021. Hydraulic
conductivities in the shallow Type II monitoring wells (GMW-2 and GMW-4), calculated using the Bouwer
and Rice method, ranged from 3.686 x 10-5 feet per minute (5.308 x 10-2 feet per day) to 1.401 x 10-4 feet
per minute (2.017 x 10-1 feet per day). The average hydraulic conductivity was 8.848 x 10-5 feet per minute
(1.274 x 10-1 feet per day). Seepage velocities, calculated using the equation V = k(dh/dl)/ne, ranged from
3.98 x 10-2 to 1.51 x 10-1 feet per day (14.5 to 55.2 feet per year) in the shallow monitoring wells. The
average seepage velocity was 9.56 x 10-2 feet per day (34.9 feet per year). The hydraulic conductivity in
the deep Type II monitoring well (DW-1), calculated using the Bouwer and Rice method, was 4.105 x 10-5
feet per minute (5.911 x 10-2 feet per day). The seepage velocity calculated for the deep Type II monitoring
well was 4.43 x 10-2 feet per day (16.2 feet per year). A summary of the results of slug test analyses is
presented in Table 8. Calculations and raw data from the slug tests are included in Appendix D.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 30, 2022 P&K Food Mart
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5079
8
7.0 REGIONAL GEOLOGY AND HYDROGEOLOGY
According to the 1985 Geologic Map of North Carolina, the site is located in the Coastal Plain
Physiographic Province of North Carolina. The Coastal Plain is part of an extensive geologic province that
roughly parallels the Atlantic Ocean and continues northward and southward through the neighboring
states. The site is located within the Yorktown Formation which consists of fossiliferous clay with varying
amounts of fine-grained sand, blush gray, shell material commonly concentrated in lenses; mainly in area
north of Neuse River. The surficial aquifer at the site is the Yorktown aquifer. Soil encountered during
the monitoring well installation activities was primarily fine sand and clay silt.
8.0 SITE GEOLOGY AND HYDROGEOLOGY
Based on observations made during assessment activities, surficial soils observed at the site consist of
primarily silts and clays. A summary of the current ground water gauging data is shown below:

Well ID
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(ft.)
Free
Product
Thickness
(ft.)
Ground
Water
Elevation
(ft.)
GMW-1 4-14 14 100.00 2.55 - 97.45
GMW-2 2-15 15 99.83 3.12 - 96.71
GMW-3 2-15 15 99.60 2.75 - 96.85
GWM-4 2-15 15 99.73 2.72 - 97.01
GMW-5 5 - 15 15 100.06 4.48 - 95.58
GMW-6 5 - 15 15 99.79 4.05 - 95.74
GMW-7 5 - 15 15 100.23 4.16 - 96.07
GMW-8 5 - 15 15 99.35 9.33 - 90.02
GMW-9 5 - 15 15 99.43 13.78 - 85.65
SW-1 2 - 8 8 99.62 3.32 - 96.30
SW-2 2 - 8 8 100.07 3.91 - 96.16
SW-3 2 - 8 8 99.86 3.71 - 96.15
SW-4 2 - 8 8 99.42 2.81 - 96.61
DW-1 25-30 30 100.03 NM NM NM

On August 15, 2022, monitoring wells GMW-1 through GMW-9 and SW-1 through SW-4 were gauged,
purged and/or sampled. Depths to ground water in the Type II monitoring wells ranged from 2.55 to 13.78
feet below the tops of well casings. Ground water elevations at the site, based on an assumed datum of
100.00 feet, ranged from 85.65 to 97.45 feet. Ground water flow was generally toward the east.
9.0 DISCUSSION
On October 29, 2018, a non-passing line tightness test was reported for the diesel dispenser and
associated product line. On March 21, 2018, GRI conducted a site check at the subject site. Site Check
results identified an unknown amount of diesel has been released from the UST system.

To date, thirteen Type II monitoring wells and one deep Type II monitoring well have been installed to
determine the horizontal and vertical extent of the release. Free product has historically not been present
in site monitoring wells. The GCL plume remains undefined to the west; however, attempts to gain access
to the property to the west of the site were denied. Therefore, no additional assessment was conducted
to the west of the site.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 30, 2022 P&K Food Mart
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5079
9

10.0 CONCLUSIONS AND RECOMMENDATIONS
 No water supply wells were identified within a 1,500-foot radius of the site. Public water is
available to the subject site and to all surrounding properties.
 No surface water bodies were identified within a 500-foot radius of the site.
 Ground water flow direction is to the east.
 The risk classification for the site should remain intermediate risk based on the presence of GCL
exceedances. Therefore, ground water contamination must be remediated to below the GCLs.
 Based on the contaminant concentrations in ground water samples collected during the March
and August 2022 sampling events, the plume is not delineated to less than the MACs horizontally
or vertically; however, due to the access issues to the west and the site cleanup goals, the site
should be considered sufficiently delineated.
 GRI recommends comprehensive ground water sampling should be conducted at the site in
February 2023 to establish contaminant trends. Once plume stability has been established, a
remedial strategy can be proposed.
11.0 PUBLIC NOTICE
Copies of the applicable portions of this CSA report have been forwarded to the appropriate local officials
by certified mail. Copies of the cover letters have been included in Appendix E.
12.0 LIMITATIONS
This report has been prepared for the exclusive use of P&K Mart, LLC for specific application to the
referenced site in Wilson County, North Carolina. The assessment was conducted based on the scope of
work and level of effort desired by the NCDEQ and with resources adequate only for that scope of work.
Our findings have been developed in accordance with generally accepted standards of environmental
practices in the State of North Carolina, available information, and our professional judgment. No other
warranty is expressed or implied.

The data that is presented in this report is indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from this data.
13.0 REFERENCES
Bouwer, H., 1989, The Bouwer and Rice slug test - an update, Ground Water, vol.27, no. 3, pp.304-309
Bouwer, H. and R.C. Rice, 1976, A slug test method for determining hydraulic conductivity of unconfined
aquifers with completely or partially penetrating wells, Water Resources Research, vol. 12, no.3,
pp. 423-428
Department of Natural Resources and Community Development, 1985, Geologic Map of North Carolina,
1 sheet
Fetter, C. W., 1988, Applied Hydrogeology, Second Edition, Macmillan Publishing Company, 592 p.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 30, 2022 P&K Food Mart
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5079
10
North Carolina Department of Environment and Natural Resources, 2000, Ground Water Section
Guidelines for the Investigation and Remediation of Soil and Ground Water, 79 p.
North Carolina Department of Environmental Quality, Division of Waste Management – UST Section
Guidelines for Assessment and Corrective Action for UST Releases, July 15, 2008 Version, Change
3, December 1, 2013
Limited Site Assessment Report, P&K Food Mart, Geological Resources, Inc., January 30, 2020
Site Check Report, P&K Food Mart, Geological Resources, Inc., April 24, 2019
Additional Risk Assessment Report, P&K Food Mart, Geological Resources, Inc., December 21, 2021

FIGURES
SITE LOCATIONFigure 1 Site LocationP & K Mart1510 Goldsboro Street SouthWilson, North CarolinaWilson CountyIncident No. 46552GRI Project No. 5079500 M2000 FTDate: 12/18/2021Location: 35.7106380° N -77.9257070° W Dad
SITE3711-85-8393.000
3711-95-0167.000
3711-85-7376.000
3711-95-0391.000
3711-95-0267.000
3711-95-1305.000
3711-85-9425.0003711-85-8408.000
3711-85-8271.000
3711-85-7258.000
3711-85-7243.000
WARD BLVD
AYCOCK ST
BRIGGS ST
JORDAN STMEADOW STGOLDSBORO STGRANGER ST
D O W N IN G S T
WOODROW STRANDOLPH ST
FIFTH STCRAWFORD STPHILLIP STBARNHILL STBELMONT AVEHOOD ST
MACON ST NORRI
S BLVDPI
CKETT
STDENBY STMALPASS DRDEWEY ST
EDGEWOOD STMOSBY STRUANN D R
KILLETTE STWINOCA RDBARNHILL STPHILLIP ST
MACON ST
H
O
MI
N
Y

S
WA
M
P
C
A
N
A
L
FIGURE 3A: SITE VICINITY MAPP & K MART1510 GOLDSBORO STREET SOUTHWILSON, WILSON COUNTYNORTH CAROLINAINCIDENT NOS. 46552GRI NO. 5079
PREPARED BY:GEOLOGICAL RESOURCES, INC.DECEMBER 17, 20211,500-FOOT RADIUS
1,000-FOOT RADIUS
250-FOOT RADIUS
500-FOOT RADIUS
³
0 300150Feet
1 inch = 300 feet
LEGEND
centerlines
ncrivers
Adjacent Properties
nc_wilson_parcels_poly_2018_03_26
1
1 Land Use Code
SITE
WARD BLVD
AYCOCK ST
BRIGGS ST
JORDAN STMEADOW STGOLDSBORO STGRANGER ST
D O W N IN G S T
WOODROW STRANDOLPH ST
FIFTH STCRAWFORD STPHILLIP STBARNHILL STBELMONT AVEHOOD ST
MACON ST NORRI
S BLVDPI
CKETT
STDENBY STMALPASS DRDEWEY ST
EDGEWOOD STMOSBY STRUANN D R
BARRON ST
KILLETTE STWINOCA RDBARNHILL STPHILLIP ST
MACON ST
H
O
MI
N
Y

S
WA
M
P
C
A
N
A
L
FIGURE 3B: ZONING MAPP & K MART1510 GOLDSBORO STREET SOUTHWILSON, WILSON COUNTYNORTH CAROLINAINCIDENT NOS. 46552GRI NO. 5079
PREPARED BY:GEOLOGICAL RESOURCES, INC.DECEMBER 17, 20211,500-FOOT RADIUS
1,000-FOOT RADIUS
250-FOOT RADIUS
500-FOOT RADIUS
³
0 300150Feet
1 inch = 300 feet
LEGEND
centerlines
ncrivers
ZONING - NC
ZONING - LI
ZONING - RMX
ZONING - GR6
ZONING - GC
ZONING - NMX
nc_wilson_parcels_poly_2018_03_26

TABLES
UST ID Number 6A - 6F Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 6A - 6F Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 6A - 6F Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 6A - 6F Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 6A - 6F Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 6C - 6F Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 6E & 6F Facility ID Number
Owner or Operator?
00-0-0000031246
TABLE 1
UST OWNER/OPERATOR INFORMATION
P&K MART (INICDENT NO. 19233/46552)
1510 Goldsboro Street, Wilson NC 27893 252-206-6667
Name of Owner or Operator Dates of Ownership / Operation
PK Food Mart 05/02/2003 - Current
Address Telephone Number
00-0-0000031246
Name of Owner or Operator Dates of Ownership / Operation
Trade Oil Company 03/28/2002 - 05/02/2003
Address Telephone Number
3602 Highway 264 East, Greenville, NC 27834 Unknwon
00-0-0000031246
00-0-0000031246
Name of Owner or Operator Dates of Ownership / Operation
Unknown 09/24/1978 - 09/23/1983
Address Telephone Number
Unknown Unknown
00-0-0000031246
Name of Owner or Operator
Name of Owner or Operator Dates of Ownership / Operation
Dates of Ownership / Operation
Convenience USA, LLC 09/01/1989 - 03/28/2002
Address Telephone Number
2200 West Main Street, Suite 800, Durham, NC 27705 Unknown
00-0-0000031246
Name of Owner or Operator Dates of Ownership / Operation
00-0-0000031246
Name of Owner or Operator Dates of Ownership / Operation
Rawl & Winstead, Inc. 09/01/1989 - 09/01/1989
Address Telephone Number
3801 Sunset Avenue, Rocky Mount, NC 27804 252-937-4118
Unknown 09/23/1983 - 09/01/1989
Address Telephone Number
Unknown Unknown
Page 1 of 2
TABLE 1
UST OWNER/OPERATOR INFORMATION
P&K MART (INICDENT NO. 19233/46552)
Owner/Operator
Unknown Unknown
Unknown 09/24/1976 - 09/24/1978
Address Telephone Number
Page 2 of 2
Date: 09/27/22
Was Release
Associated
with UST
System?
(Yes / No)
6A Gasoline 12,000 9/23/1983 Single Wall Steel 10' 6" x 19' Other
In Temp.
Closure No
6B Gasoline 12,000 9/23/1983 Single Wall Steel 10' 6" x 19' Other Current No
6C Gasoline 12,000 9/24/1978 Single Wall Steel 10' 6" x 19' Other Current No
6D Diesel 12,000 9/24/1978 Single Wall Steel 10' 6" x 19' Other Current Yes
6E Diesel 12,000 9/24/1976 Single Wall Steel 10' 6" x 19' Other
In Temp.
Closure No
6F Kerosene 12,000 9/24/1976 Single Wall Steel 10' 6" x 19' Other
In Temp.
Closure No
TABLE 2
UST SYSTEM INFORMATION
P&K MART (INICDENT NO. 19233/46552)
UST
ID
No.
Current
or Most
Recent
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
Facility ID #: 00-0-0000031246
Page 1 of 1
Date: 08/24/22 Facility ID #: 00-0-0000031246
PIN Number Property Owner Name Property Owner Address
3711858393.000 (site) Lions House, LLC
5014 Country Club Dr NW
Wilson, NC 27896
3711858271.000 Samuel Victoriano Ascencion
974 Savannah Hill Rd
Dunn, NC 28334
3711857243.000 Andrews Properties
2500 Nash Street N Suite A
Wilson, NC 27896
3711857258.000 Dean Properties, LLC
2303 Sulgrave Drive NW
Wilson, NC 27896
3711857376.000 Mildred Bass Barnes
1111 W Florida Street
Greensboro, NC 27043
3711858408.000 Patrick & Keisha McNeil
3212 Harmony Ct
Raleigh, NC 27610
3711859425.000 BRH1, LLC
PO Box 1254
Wilson, NC 27894
3711951305.000 Carl & Evelyn Barnes
1507 Goldsboro St.
Wilson, NC 27893
3711950391.000 Jorge Luis Torres Romero
1509 Goldsboro St.
Wilson, NC 27893
3711950267.000 Johnnie Lee Johnson
409 Denby St SW
Wilson, NC 27893
3711950167.000 Willliam T. Goff
1601 Goldsboro Street S
Wilson, NC 27893
Note:
• Properties are keyed to Figure 3.
TABLE 3
ADJACENT PROPERTY OWNER INFORMATION
P&K MART (INICDENT NO. 19233/46552)
Page 1 of 1
Date: 12/17/21 Facility ID #: 00-0-0000031246
Map ID No. Land Use Feature Zoning Description Address
Distance from
Source Area
(feet)
1 Bread of Life Family Worship
Church GR6 Church
910 Granger St. S.
Wilson, NC 27893 700 SE
n/a GC General Commercial n/a n/a
n/a GR6 General Residential
Medium Density n/a n/a
n/a LI Light Industrial n/a n/a
n/a NC Neighborhood
Commercial n/a n/a
n/a NMX Neighborhood Mixed
Use n/a n/a
n/a RMX Residential Mixed Use n/a n/a
TABLE 4
LAND USE INFORMATION
P&K MART (INICDENT NO. 19233/46552)
Page 1 of 1
Date: 08/25/21
SW846
8270E
Sample ID Date Collected
(mm/dd/yy)
Sample
Depth
(feet)
50 100 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
NE NE 0.0072 5.4 8 6 0.085 0.2 2.4 1.3 1.4 6.6 6.6 0.054 68 540 31 540 NE 31
NE NE 12 1,250 60.3 3,120 156 5.5 782 1,560 1,560 156 156 22.8 625 1,500 469 1,560 31,200 469
NE NE 59.4 18,600 297 46,700 1,810 27 11,600 23,300 23,300 2,330 2,330 112 9,340 40,000 12,264 23,300 467,000 12,264
SB-1-3' 03/21/2019 3 6,600 NR 23.1 131 45.9 225 <0.77 NR NR NR NR NR NR NR NR NR NR NR NR NR
SB-2-3' 03/21/2019 3 97.7 NR 6.17 17.2 4.06 18.5 <0.50 NR NR NR NR NR NR NR NR NR NR NR NR NR
GMW-1-5' 11/14/2019 5 NR NR 15.7 89.9 31.7 156 <0.63 8.62 3.56 3.81 12.4 66.7 19.4 0.438 1,100 <110 395 34.2 J <13 29.0 J
GMW-2-15' 08/25/2021 15 <4.7 <3.8 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR
GMW-2-5' 08/25/2021 5 247 33.6 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR
GMW-4-10' 08/25/2021 10 37.3 <3.7 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR
GMW-4-5' 08/25/2021 5 229 17.3 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR
DW-1-15' 08/25/2021 15 439 5.88 J NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR
DW-1-5' 08/25/2021 5 201 9.80 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR
Notes:
• Results reported in mg/kg (milligrams per kilograms)
• MSCC: Maximum Soil Contaminant Concentration level as specified by T 15A NCAC 2L.0202.
• < : Less than the method detection limit specified in the laboratory report
• Concentrations in bold face type exceeded the soil to ground water MSCCs.
• Concentrations in italix exceeded the residential clean up levels.
• NE: Not Established
• J: Estimated value.
• NR: Not Requested C11-C22 Aromatics1,2,4-TrimethylbenzeneC5-C8 AliphaticsRAL (mg/kg)
Industrial/Commercial Soil Cleanup Levels (mg/kg)C19-C36 AliphaticsSoil to Water MSCC (mg/kg)
Residential Soil Cleanup Levels (mg/kg)C9-C18 AliphaticsC9-C12 AliphaticsC9-C10 Aromatics1,3,5-Trimethylbenzenen-PropylbenzeneIsopropylbenzenen-Butylbenzene1-MethylnaphthaleneNaphthaleneMADEP VPH
Contaminant of Concern TPH-GROTPH-DROBenzeneTolueneEthylbenzeneTotal XylenesMTBETABLE 5
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS
P&K MART (INICDENT NO. 19233/46552)
Facility ID No. 00-0-0000031246
Analytical Method SW846 8015C SW846 8260D MADEP EPH
Date: 08/25/22
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 40 10 3 0.4 4,000 70 70 400 400 3 100 1 30 30 400 700 200 700 10,000 200
5,000 260,000 80,000 50,000 20,000 6,000 40,000 10,000 3,000 400 4,000,000 30,500 26,100 28,500 24,100 135 100,000 1,000 12,000 30,000 NE NE NE NE NE NE
12/02/19 7,180 6,320 1,490 4,250 86.7 J 463 978 J 1,140 J <40 <25 <13,000 95.5 J 205 1,390 363 <5.1 102 44.6 78.8 42.9 NR NR NR NR NR NR
08/26/21 7,440 2,130 1,570 3,510 82.2 J 418 1,170 J 1,510 J <40 <25 <13,000 98.1 J 221 1,330 365 <0.96 41.4 46.5 72.6 2.1 J NR NR NR NR NR NR
03/08/22 8,100 1,940 1,190 2,890 85.0 J 121 1,540 J 1,140 J <0.20 9.1 <65 57.2 J 102 930 306 <5.0 89.1 10.3 J 5.1 J 7.1 J <700 <700 2,070 <49 <49 445
08/26/21 1,200 19.8 18.7 36.2 20.5 194 213 797 <4.0 <2.5 <1,300 19.8 24.6 13 4.5 J <0.97 <0.72 30.3 34.6 1.7 J NR NR NR NR NR NR
03/08/22 3,480 E 66.5 253 131.9 12.8 J 91.7 599 526 17.6 J <6.3 <3,300 23.6 J 49 38.9 23.1 J <0.96 2.6 J 37.8 49.0 <0.48 1,320 E <35 365 J <48 <48 338
08/26/21 1,730 17.6 38 78.4 49.7 8.3 J 351 1,190 <4.0 <2.5 <1,300 43.4 96.7 18 4.6 J <0.95 2.5 J 53.3 56.2 9.1 NR NR NR NR NR NR
03/08/22 1,440 11.2 92.8 62.7 33.4 21.1 283 262 9.3 <0.13 <65 58.7 128 47.2 1.7 <4.9 <3.6 71.1 57.7 3.3 J <180 <180 536 <48 <48 413
08/26/21 12,200 166 1,230 1,690 49.6 412 853 <100 <10 <6.3 <3,300 210 271 642 159 <0.96 88.4 45.1 69.4 21.0 NR NR NR NR NR NR
03/08/22 9,780 158 J 849 654 J <63 378 1,130 J <1,000 <100 <63 <33,000 170 J 301 450 135 J <1.1 44.7 41.8 64.8 13.4 1,200 E <180 1,740 52.4 J <51 564
GMW-5 03/08/22 43.5 J <13 56.4 74.2 J <13 <13 <200 <200 <20 <13 <6,500 <13 <13 37.9 J 18.9 J <1.0 1.3 J 1.4 J 2.6 J <0.52 321 <35 206 <51 <51 145 J
GMW-6 03/08/22 2,260 451 447 1,280 50.3 J 115 530 J <400 <40 <25 <13,000 54.7 J 90.3 J 298 106 <1.1 17.7 13.2 18.3 4.3 J 495 E <35 970 J <48 <48 257
GMW-7 03/08/22 1,000 143 116 269.8 <6.3 67.8 1,110 165 J <10 <6.3 <3,300 9.9 J 27.0 47.1 16.9 J <0.94 1.7 J 15.3 15.6 1.4 J 413 E <35 353 J <52 62.3 J 335
GMW-8 08/15/22 1.12 <0.220 0.528 0.670 J <0.140 <0.470 <1.90 <1.60 <0.220 <0.150 <42.0 <0.180 <0.190 0.281 J <0.180 <9.59 NR <1.20 <7.54 NR <11.5 <25.8 <4.02 <28.2 <124 <61.2
GMW-9 08/15/22 0.385 J <0.220 0.209 J <0.210 <0.140 <0.470 <1.90 <1.60 <0.220 <0.150 <42.0 <0.180 <0.190 <0.190 <0.180 NR NR NR NR NR <11.5 <25.8 <4.02 NR NR NR
SW-1 03/08/22 9,650 <63 1,450 888 <63 138 J <1,000 <1,000 <100 <63 <33,000 77.1 J 226 J 138 J 65.1 J <0.97 22.2 49.0 81.8 14.4 2,370 E <35 1,260 397 203 671
08/26/21 4,510 5,290 2,120 6,390 <63 518 <1000 <1000 <100 <63 42,200 J 161 J 369 2,320 635 <1.2 50.1 89.4 172 14.5 NR NR NR NR NR NR
03/08/22 16.9 1.5 14.5 5.5 11.4 7.6 <500 <500 0.24 J <0.13 <16,000 3.4 6.8 8.1 9.6 28.7 J <7.4 15.9 J 32.9 J <5.0 257 <35 103 90.2 J <71 167 J
Trip Blank 08/15/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 NR
NR <0.220 <0.150 <42.0 <0.180 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR NR NR NR
Notes:
• Results reported in micrograms per liter (µg/l).
• < : Less than the method detection limit specified in the laboratory report.
• 2L Standard specified in T15A NCAC 2L.0202.
• GCL: Gross contamination level.
• NE: Not Established
• Concentrations in bold face type exceeded the 2L standards.
• Concentrations in italics exceeded the gross contamination levels.
• Refer to laboratory report for detected constituents that did not exceed the MACs, or for which no standard has been established.Bis(2-ethylhexyl)phthalate (DEHP)TABLE 6
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
P&K MART (INICDENT NO. 19233/46552)
Facility ID No. 00-0-0000031246
1,3,5-TrimethylbenzeneMADEP EPH
Contaminant of Concern BenzeneTolueneEthylbenzeneTotal XylenesMethyl-tert-butyl ether(MTBE)NaphthaleneAnalytical Method EPA Method 625 MADEP VPH
Phenol1-Methylnaphthalene2-Methylnaphthalene2,4-DimethylphenolC9-C18 AliphaticsC19-C36 AliphaticsC11-C22 AromaticsC5-C8 AliphaticsC9-C12 AliphaticsC9-C10 AromaticsEPA Method 6200B or EPA Method 602
MAC (µg/l)
GCL (µg/l)
DW-1
GMW-2
GMW-3
GMW-1
GMW-4 1,2,4-Trimethylbenzenen-PropylbenzeneIsopropylbenzeneEthanol1,2-DichloroethaneMethyl chloride(Chloromethane)tert-Butyl alcohol(TBA)tert-Amyl alcohol(TAA)Page 1 of 1
Facility ID#: 00-0-0000031246
ft/min ft/day ft/day ft/year
GMW-2 3.686E-05 5.308E-02 3.98E-02 1.45E+01
GMW-4 1.401E-04 2.017E-01 1.51E-01 5.52E+01
Averages 8.848E-05 1.274E-01 9.56E-02 3.49E+01
DW-1 4.105E-05 5.911E-02 4.43E-02 1.62E+01
Note:
Seepage velocities calculated using the equation v = k(dh/dl)/ne , where:
k = hydraulic conductivity
ne = effective porosity = 0.20
dh/dl = hydraulic gradient = 0.15 ft/ft
TABLE 8
SUMMARY OF SLUG TEST ANALYSES
P&K MART (INICDENT NO. 19233/46552)
Date : 12/16/21
Well Hydraulic Conductivity (k) Seepage Velocity (v)
Page 1 of 1
Date: 08/18/22 Facility ID #: 00-0-0000031246
Well ID Date Installed
(mm/dd/yy)
Date Water
Level
Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to Water
from Top of
Casing
(ft.)
Free Product
Thickness
(ft.)
Ground Water
Elevation
(ft.)
Comments
12/02/19 9.98 - 90.02
08/26/21 2.69 - 97.31
03/08/22 3.87 - 96.13
08/15/22 2.55 -97.45
08/26/21 9.20 - 90.63
03/08/22 3.32 - 96.51
08/15/22 3.12 -96.71
08/26/21 3.59 - 96.01
03/08/22 2.91 - 96.69
08/15/22 2.75 -96.85
08/26/21 2.97 - 96.76
03/08/22 3.41 - 96.32
08/15/22 2.72 - 97.01
03/08/22 4.60 - 95.46
08/15/22 4.48 - 95.58
03/08/22 11.97 - 87.82
08/15/22 4.05 - 95.74
03/08/22 3.98 - 96.25
08/15/22 4.16 - 96.07
GMW-8 08/10/22 08/15/22 5 5 - 15 15 99.35 9.33 - 90.02
GMW-9 08/10/22 08/15/22 5 5 - 15 15 99.43 13.78 - 85.65
03/08/22 3.36 - 96.26
08/15/22 3.32 - 96.30
03/08/22 NM NM NM
08/15/22 3.91 - 96.16
100.00144-14411/14/19
TABLE 7
WELL CONSTRUCTION AND GAUGING INFORMATION
P&K MART (INICDENT NO. 19233/46552)
99.60152-15208/25/21GMW-3
GMW-2
GMW-1
99.83152-15208/25/21
SW-2 06/07/93
06/07/93SW-1
GMW-7 03/07/22
03/07/22GMW-6
GMW-5 03/07/22
GWM-4 08/25/21 2 2-15 15 99.73
5
5
15
15
5 5 - 15
5 - 15
5 - 15
2 - 82
2 2 - 8 100.07
15
100.06
99.79
100.23
99.628
8
Page 1 of 2
Date: 08/18/22 Facility ID #: 00-0-0000031246
Well ID Date Installed
(mm/dd/yy)
Date Water
Level
Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to Water
from Top of
Casing
(ft.)
Free Product
Thickness
(ft.)
Ground Water
Elevation
(ft.)
Comments
TABLE 7
WELL CONSTRUCTION AND GAUGING INFORMATION
P&K MART (INICDENT NO. 19233/46552)
03/08/22 NM NM NM
08/15/22 3.71 - 96.15
03/08/22 NM NM NM
08/15/22 2.81 - 96.61
08/26/21 7.36 - 92.67
03/08/22 8.20 - 91.83
08/15/22 NM NM NM
Notes:
• ft BGS: feet below ground surface.
• NM: Not measured.
DW-1 100.033025-302508/25/21
SW-4 06/07/93
06/07/93SW-3 2
2 2 - 8
2 - 8 99.86
99.42
8
8
Page 2 of 2

APPENDICES

APPENDIX A
State Correspondence
NCDEQ Incident Report
RP/Company RAWLS & WINSTEAD, INC.
RPAddress P.O.BOX 7009
RPCity ROCY MOUNT
Contact BEN WINSTEAD III
RPState NC
TELEPHONE [phone]
IncidentNumber 19233 USTNum RA-2902
IncidentName WINOCO #6-WILSON
FacilID 00-0-0000031246
Address 1510 GOLDSBORO STREET
CityTown WILSON State NC
ZipCode 27893-5860
DateOccurred 4 /1 /1993
DateReported 6 /11/1993
ConfRisk L
CloseOut 10/1/2014
COMMENT
LSA rec'd 6/15/04
RptType Rcvd Rvwd Appvd
Incident Mgr HMMLongitude-77.925800 Latitude 35.710600
County WILSO
LSA 3/17/1998 6/20/2014
LSA rec'd 6/15/04, RKD. 5 MWs, values above 2L but not above GCLs. Soil
values above S-GW, but not above Residential. NRP on GW sent 6/23/2014.
SCH 7/6/2009 8/12/2009 8/12/2009
DR 8/28/2014 8/28/2014 8/29/2014
GW-only NRP. -MRP// Recorded in Book 2590, Page 698-700, Wilson
county on 10/07/2014. BRH
Wednesday, September 28, 2022 Page 1 of 1

North Carolina Department of Environmental Quality | Division of Waste Management
Washington Regional Office | 943 Washington Square Mall | Washington, NC 27889 |
[phone]

February 3, 2022

PK Mart, LLC
Mr. Johnny Nasser
1510 Goldsboro Street
Wilson, North Carolina 27893

Re: Notice of Regulatory Requirements
15A NCAC 2L .0407(d) [Intermediate Risk]
Risk-based Assessment and Corrective Action
For Petroleum Underground Storage Tanks

P& K Food Mart
1510 Goldsboro Street, Wilson
Wilson County
Incident Number: 46552
Risk Classification: Intermediate
Ranking: I 115 D

Dear Mr. Nasser:

The Additional Risk Assessment Report dated December 21, 2021 has been reviewed by the UST
Section, Division of Waste Management, Washington Regional Office. The risk posed by the discharge or
release at the subject site is classified by the Department of Environmental Quality as intermediate, as
stipulated under Title 15A NCAC 2L .0406. The land use at the site is classified as industrial/commercial.
Title 15A NCAC 2L .0407(a) requires you to notify the Department of any changes that might affect the
risk or land use classifications that have been assigned.
Title 15A NCAC 2L .0407(d) [Intermediate Risk] requires you to comply with the assessment and
cleanup requirements of Title 15A NCAC 2N .0706 and Title15A NCAC 2L .0106(c) and 2L .0106(g). A
Comprehensive Site Assessment (CSA) Report prepared in accordance with these requirements and the
most recent version of the UST Section Assessment Guidelines must be received by this office within 90
days of the date of this notice. In addition, you must submit a summary of the CSA Report to the local
Health Director and the local Chief Administrative Officer in accordance with 15A NCAC 2L .0114. The
summary should be submitted to these persons no later than five working days after submittal of the CSA
Report to this office.

North Carolina Department of Environmental Quality | Division of Waste Management
Washington Regional Office | 943 Washington Square Mall | Washington, NC 27889 |
[phone]

Failure to comply in the manner and time specified may result in the assessment of civil
penalties and/or the use of other enforcement mechanisms.
An extension to this deadline may be obtained through the completion and submittal of an
Accelerated Site Characterization (ASC) Report prior to the completion of the CSA. The scope of work
defined by the ASC Report consists of generating an updated conceptual site model based upon real-time
field screening using high-resolution site characterization practices. In this process the vertical and
horizontal extent of soil and ground water contamination onsite may be quickly evaluated to reduce the
number of iterative steps necessary to complete plume delineation and allow for the creation of a more
accurate comprehensive soil and ground water assessment and monitoring network plan to improve the
quality and reduce the costs of the subsequent CSA Report.
Effective October 1, 2004, the Department of Environmental Quality requires that all work not
determined to be an emergency response or associated with risk assessment (i.e., the Limited Site
Assessment Report, per Title 15A NCAC 2L .0405) must be preapproved if State Trust Fund reimbursement
is anticipated. To comply with this requirement, a completed Preapproval/Claim Authorization Form,
encompassing the required remedial activities, must be received in this office within 14 days of the date of
this letter. Upon completion of the preapproved activities, you should submit your claim promptly.
Reimbursement funds are budgeted based on completed preapprovals, but delays in reimbursement or even
denial due to exceeding the statute of limitations on claiming eligible costs can result where claims are not
submitted immediately following work completion.
Because a release or discharge has been confirmed, a Licensed Geologist or a Professional
Engineer, certified by the State of North Carolina, is required to prepare and certify all reports submitted to
the Department in accordance with 15A NCAC 2L .0103(e) and 2L .0111(b).
If you have any questions regarding trust fund eligibility or reimbursement from the Commercial
Leaking Petroleum Underground Storage Tank Cleanup Fund, please contact the UST Section Trust Fund
Branch at [phone]. If you have any questions regarding the actions that must be taken or the rules
mentioned in this letter, please contact me at the address or telephone number listed below.
Sincerely,

Allison Ward
Hydrogeologist
Washington Regional Office
UST Section, Division of Waste Management, NCDEQ

cc: Wilson County Health Department
GRI, Inc., Rae Brown, P.G., via email

Washington Regional Office | 943 Washington Square Mall | Washington, NC 27889 | [phone]

CSA_ACS request NOR 0317.dotx

Site Name City / County /wilson Incident #19233 46552
Resp Pty Name / Contact Incident Mgr Region WAS
RP Type (Owner/Operator / Landowner / Attny-in-fact)Change Order?Prev. TA #3
Consultant / Project Mgr /Rae Brown
Telephone / Fax Number /Task Authorization Number:4 ChangeOrd:
Project Mgr Email Site Risk / Rank / Abatement:I 115 D RRA Date:2/5/2020
Proposal# / Scope Dates /% Commercial (C=100%, NC=0%, Both=1%-99%)
Has STF Eligibility Been Determined? (Y/N)Site Status (Active or NFA Date)
With Claim: [ ] All Main Consultant/Contractor invoices attached?[ ] Proof of payment attached directly to the front of each invoice?
w Important: The date of reimbursement is dependent on the Trust Fund balance. There may be a delay in the reimbursement of claims for work under this ePATA.3rd Pty Ded?Task #Lab /
SubCode
RO IM AuthProposed
Rate/Price
(Consultant)RO Supv. AuthProposed Task
Subtotal
(Consultant)
Preapproved
Subtotal
(UST Section)
Claimed
Amount3
(Consultant)
3.101 60 /feet Y $12.50 Y $750.00 $750.00 /
3.113 60 /feet Y $50.00 Y $3,000.00 $3,000.00 /
3.351 4 /wells Y $80.00 Y $320.00 $320.00 /
3.398 1 /event Y $350.00 Y $350.00 $350.00 /
4.031 9 /wells Y $110.00 Y $990.00 $990.00 /
4.090 #240 9 /samples Y $88.00 Y $792.00 $792.00 /
4.090 #310 9 /samples Y $139.00 Y $1,251.00 $1,251.00 /
4.090 #341 9 /samples Y $52.00 Y $468.00 $468.00 /
4.090 #342 9 /samples Y $94.00 Y $846.00 $846.00 /
6.050 1 /report Y $4,400.00 Y $4,400.00 $4,400.00 /
6.082 1 /site Y $500.00 Y $500.00 $500.00 /
12.050 2 /trips Y $250.00 Y $500.00 $500.00 /
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
Requested Preapproved Claimed 3
TOTAL:$14,167.00 $14,167.00 TOTAL:
Total Standard Costs (Not Third Party)$14,167.00 $14,167.00 Total Standard Costs
Total applied as Third Party Deductible/Damage Costs $0.00 $0.00 Total Third Pty Costs
Process Tracking (Date)
TA Submittal:2/9/22 by:(PM)(Reserved for RO)
RO Review:2/10/22 by:(IM)Joint UST Preapproval Confirmed By:Date1 2/16/2022
RO Supv. Review:2/15/22 by:(STF)RP or Designee Receipt Confirmation By:Date 4
1 - This ePATA expires one year from the Joint UST Preapproval date. This does not extend, alter, or supersede any regulatory deadlines (e.g., NORR's, NOV's, Enforcements, etc.)
2 - THE ONE YEAR STATUTE OF LIMITATIONS APPLIES TO EACH INDIVIDUAL TASK. Costs must be claimed within one year of completion of that task to be reimbursable.
3 - Only Tasks included on this ePATA may be claimed. Do not include other Tasks or claimed costs (i.e., Claim preparation) that were not preapproved or the claim will be returned.
4 - Preapproval is not valid (i.e., claimable) until receipt is signed as 'Confirmed' by the RP or their designee within a week of approval. The signed pre-approval must be submitted
in the submitted claim. Signature indicates acknowledgement of the tasks and amounts approved. Any objections/appeals must be submitted via Change Order prior to work
proceeding. Scope/cost negotiations do not supersede other regulatory deadlines as described in #1 above. Also, any ePATA that has been signed as 'Confirmed' by both the
UST Section and RP is not to be modified without written consent by all signatories.
5 - Tasks approved on Directed - CAB Only ePATAs must be performed in accordance with all applicable rules, statutes, and RRD Task Scopes of Work to be reimbursed in full.
DWM/UST ePATA 8/1/2020
RB
Proposed
Units / Type
(Consultant)
Allison Ward
ACTIVETRUE
22-115 Febuary 9-28, 2022
704-845-4012
Dates of Work
(Consultant)
Started1 / Completed2
FINAL REIMBURSEMENT
100.00%
No
[e-mail]
Johnny Nasser 252-206-6667
Geological Resources, Inc.
DIRECTED - CAB ONLY
Wilson
(Must Complete with Claim Submittal)(See Instructions / RRD for Tasks requiring Preapproval / Task Authorization)
Owner/Operator
704-845-4010
(Reserved for Incident Manager)
PREAPPROVAL / TASK AUTHORIZATION
P and K Mart
Note:This Electronic Preapproval Task Authorization (ePATA)shall be used to receive preapproval from the UST Section.A proposal,including maps and figures,must be attached to
elaborate on the costs for the tasks listed below that describes the scope of work and the rationale for the proposed activities.If,following completion of this ePATA,you discover that
unexpected tasks must be performed,incurring costs for tasks not originally included with this form,you must complete and submit a separate ePATA request designated as a "Change
Order"in the provided space above prior to conducting those tasks.Include a copy of the prior ePATA form for confirmation.Please attach this form to the cover of the corresponding
claim when requesting reimbursement.IMPORTANT:Only one claim may be submitted per ePATA and all work on the ePATA must have been completed within 12 months of the
completion date of the FIRST completed task to remain within the Statute of Limitations.All ePATAs submitted within a claim are closed with that claim,and may not be re-used in a
separate submittal,even for costs or tasks that were not originally claimed.Final reimbursement of costs associated with the Total Claimed amount below may be affected by the
eligibility status of the site (i.e.,deductibles,apportionment,etc.),and the documentary validation of incurred costs as reasonable and necessary expenses per 15A NCAC 2P .0402 and
.0404.
ALW
SNH
(Initials)
ALW
ELECTRONIC PREAPPROVAL TASK AUTHORIZATION FORM
Dept of Environmental Quality -Division of Waste Management
Site Name City / County /Wilson Incident #19233 46552
Resp Pty Name / Contact Incident Mgr Region WAS
RP Type (Owner/Operator / Landowner / Attny-in-fact)Change Order?Prev. TA #4
Consultant / Project Mgr /Rae Troiano Brown
Telephone / Fax Number /Task Authorization Number:5 ChangeOrd:
Project Mgr Email Site Risk / Rank / Abatement:I 115 D RRA Date:2/5/2020
Proposal# / Scope Dates /% Commercial (C=100%, NC=0%, Both=1%-99%)
Has STF Eligibility Been Determined? (Y/N)Site Status (Active or NFA Date)
With Claim: [ ] All Main Consultant/Contractor invoices attached?[ ] Proof of payment attached directly to the front of each invoice?
Important: The date of reimbursement is dependent on the Trust Fund balance. There may be a delay in the reimbursement of claims for work under this ePATA.3rd Pty Ded?Task #Lab /
SubCode
RO IM AuthProposed
Rate/Price
(Consultant)RO Supv. AuthProposed Task
Subtotal
(Consultant)
Final
Preapproved
Subtotal
(UST Section)
Claimed
Amount3
(Consultant)
1.050 1 /agreement y $300.00 Y $300.00 $300.00 /
3.080 1 /permit y $250.00 Y $250.00 $250.00 /
3.101 45 /feet y $12.50 Y $562.50 $562.50 /
3.113 45 /feet y $50.00 Y $2,250.00 $2,250.00 /
3.118 45 /feet y $5.00 Y $225.00 $225.00 /
3.310 1 /agreement y $625.00 Y $625.00 $625.00 /
3.351 3 /wells y $80.00 Y $240.00 $240.00 /
3.397 1 /Mobe y $100.00 Y $100.00 $100.00 /
3.398 1 /Mobe y $350.00 Y $350.00 $350.00 /
4.031 3 /wells y $110.00 Y $330.00 $330.00 /
4.090 #240 3 /samples y $94.00 Y $282.00 $282.00 /
4.090 #310 3 /samples y $148.00 Y $444.00 $444.00 /
4.090 #341 3 /samples y $56.00 Y $168.00 $168.00 /
4.090 #342 3 /samples y $100.00 Y $300.00 $300.00 /
4.090 #810 11 /samples y $11.00 Y $121.00 $121.00 /
4.091 1 /shipment y $60.00 Y $60.00 $60.00 /
6.050 1 /report y $4,400.00 Y $4,400.00 $4,400.00 /
6.082 1 /site y $500.00 Y $500.00 $500.00 /
12.050 2 /trips y $250.00 Y $500.00 $500.00 /
12.055 2 /trips y $50.00 Y $100.00 $100.00 /
//
//
//
//
//
//
//
Requested Preapproved Claimed3
TOTAL:$12,107.50 $12,107.50 TOTAL:
Total Standard Costs (Not Third Party)$12,107.50 $12,107.50 Total Standard Costs
Total applied as Third Party Deductible/Damage Costs $0.00 $0.00 Total Third Pty CostsProcess Tracking (Date)
TA Submittal:5/12/22 by:(PM)(Reserved for RO)
RO Review:5/12/22 by:(IM)Joint UST Preapproval Confirmed By:Date1 5/13/2022
RO Supv. Review:5/12/22 by:(STF)RP or Designee Receipt Confirmation By:Date 4
1 - This ePATA expires one year from the Joint UST Preapproval date. This does not extend, alter, or supersede any regulatory deadlines (e.g., NORR's, NOV's, Enforcements, etc.)
2 - THE ONE YEAR STATUTE OF LIMITATIONS APPLIES TO EACH INDIVIDUAL TASK. Costs must be claimed within one year of completion of that task to be reimbursable.
3 - Only Tasks included on this ePATA may be claimed. Do not include other Tasks or claimed costs (i.e., Claim preparation) that were not preapproved or the claim will be returned.
4 - Preapproval is not valid (i.e., claimable) until receipt is signed as 'Confirmed' by the RP or their designee within a week of approval. The signed pre-approval must be submitted
in the submitted claim. Signature indicates acknowledgement of the tasks and amounts approved. Any objections/appeals must be submitted via Change Order prior to work
proceeding. Scope/cost negotiations do not supersede other regulatory deadlines as described in #1 above. Also, any ePATA that has been signed as 'Confirmed' by both the
UST Section and RP is not to be modified without written consent by all signatories.
5 - Tasks approved on Directed - CAB Only ePATAs must be performed in accordance with all applicable rules, statutes, and RRD Task Scopes of Work to be reimbursed in full.
DWM/UST ePATA 4/1/2022
RTB
Proposed
Units / Type
(Consultant)
Allison Ward
activeYES
22-350 May 2022
704-845-4012
Dates of Work
(Consultant)
Started1 / Completed2
FINAL REIMBURSEMENT
100.00%
[e-mail]
Johnny Nasser 252-206-6667
Geological Resources, Inc.
DIRECTED - CAB ONLY
Wilson
(Must Complete with Claim Submittal)(See Instructions / RRD for Tasks requiring Preapproval / Task Authorization)
Owner/Operator
704-845-4010
(Reserved for Incident Manager)
PREAPPROVAL / TASK AUTHORIZATION
P and K Mart
Note:This Electronic Preapproval Task Authorization (ePATA)shall be used to receive preapproval from the UST Section.A proposal,including maps and figures,must be attachedto
elaborate on the costs for the tasks listed below that describes thescope of work and the rationale for the proposed activities.If,following completion of this ePATA,you discover that
unexpected tasks must be performed,incurring costs for tasks not originally included withthis form,youmust complete andsubmit a separate ePATArequest designated as a"Change
Order"in the provided space above prior to conducting those tasks.Include a copy of the prior ePATA form for confirmation.Pleaseattach this form to thecover of the corresponding
claim when requesting reimbursement.IMPORTANT:Only one claim may be submitted per ePATA and all work on the ePATA must have been completed within 12 months of the
completion date of the FIRST completed task to remain within the Statute of Limitations.All ePATAs submitted within a claim are closed with that claim,and may not be re-used in a
separate submittal,even for costs or tasks that were not originally claimed.Final reimbursement of costs associated with the Total Claimed amount below may be affected by the
eligibility status of the site (i.e.,deductibles,apportionment,etc.),and the documentary validation of incurred costs as reasonable and necessary expenses per 15A NCAC 2P .0402 and
.0404.
ALW
SNH
(Initials)
ELECTRONIC PREAPPROVAL TASK AUTHORIZATION FORMDept of Environmental Quality -Division of Waste Management
5/16/22
5079 Received MAY 16 2022

Appendix B
Well Construction Records and Subsurface Logs

WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
SUBJECT:
Respectfully yours,
For K Bowen
Bobby Liverman, PE
District Engineer
cc:
Mr. B. L. Liverman, PE- District Engineer
STATE OF NORTH CAROLINA
DEPARTMENT OF TRANSPORTATION
Governor Secretary
Geological Resources
Geological Resources, Inc.
Roy Cooper J. Eric Boyette
3502 Hayes Rd
Monroe,NC 28110
May 18, 2022
Wilson County
Encroachment Number: E042-098-22-00108
Route(s): SR 1168 ( Goldsboro St )
Encroachment Contract - Geological Resources, Inc.
KGB/BLL/rim
Installation of Two Type II monitoring wells to determine extent of ground water contamination
associated with P&K Mart.
This encroachment is approved subject to the standard and special provisions that are attached to
and made part of the encroachment contract.
Attached for your files is a copy of right-of-way encroachment agreement R/W 16.2 that has been
properly executed. This contract covers the following:
Dear Sir:
Wilson County Maintenance Engineer
Attachments
The Encroacher shall notify the District Engineer's Office (252)-462-2550 prior to beginning work.
The Encroacher shall provide 24 hours notification for inspections.
Wilson County Encroachment Letter
PO Box 3165 - Wilson, NC 27895-3165
PH: [phone] FAX: [phone]
Standard Provisions
1.Approval may be rescinded upon failure to follow any of the provisions in this permit and may be
considered a violation of the encroachment agreement.
2.The Encroaching party or their contractor shall provide the following notices prior to
construction activity within the NCDOT Right of Way:
a. Three (3) business days advance phone call at telephone [phone] or email to
[e-mail] to the District Engineer’s office
b. If the construction falls within the limits of an NCDOT managed construction project,
five (5) business days advance phone call to the Resident Engineer, Ms. Kim Moore at
[phone] or email to [e-mail].
Failure to provide these notifications prior to beginning construction is subject to the
Division Engineer’s discretion to cease construction activity for this encroachment.
NCDOT reserves the right to cease any construction or maintenance work associated with
this installation by the encroaching party until the construction or maintenance meets the
satisfaction of the Division Engineer or their representative.
3.Prior to beginning work, it is the requirement of the Encroaching Party to contact the
appropriate Utility Companies involved and make arrangements to adjust or relocate any
utilities that conflict with the proposed work.
4.It shall be the responsibility of the encroaching party to determine the location of utilities
within the encroachment area. NCGS § 87-115 through § 87-130 of the Underground
Utility Safety and Damage Prevention Act requires underground utilities to be located by
calling 811 prior to construction. The encroaching party shall be responsible for notifying
other utility owners and providing protection and safeguards to prevent damage or
interruption to existing facilities and maintain access to them.
5.The encroaching party shall notify the appropriate municipal office prior to beginning any
work within the municipality’s limits of jurisdiction.
6.This approval and associated plans and supporting documents shall not be interpreted to
allow any design change or change in the intent of the design by the Owner, Design
Engineer, or any of their representatives. Any revisions or changes to these approved
plans or intent for construction must be obtained in writing from the Division Engineer’s
office or their representative prior to construction or during construction, if an issue arises
during construction to warrant changes.
7.NCDOT does not guarantee the right of way on this road, nor will it be responsible for any
claim for damages brought about by any property owner by reason of this installation. It is
the responsibility of the encroaching party to verify the right of way.
8.Encroaching party shall be responsible for obtaining all necessary permanent and/or
temporary construction, drainage, utility and/or sight distance easements.
Wilson County Encroachment Letter
9.WORK ZONE TRAFFIC CONTROL QUALIFICATIONS AND TRAINING
PROGRAM
All personnel performing any activity inside the highway right of way are required to be
familiar with the NCDOT Maintenance / Utility Traffic Control Guidelines (MUTCG).
No specific training course or test is required for qualification in the Maintenance /Utility
Traffic Control Guidelines (MUTCG).
All flagging, spotting, or operating Automated Flagger Assist Devices (AFAD) inside the
highway right of way requires qualified and trained Work Zone Flaggers. Training for this
certification is provided by NCDOT approved training resources and by private entities
that have been pre-approved to train themselves.
All personnel involved with the installation of Work Zone Traffic Control devices inside
the highway right of way are required to be qualified and trained Work Zone Installers.
Training for this certification is provided by NCDOT approved training resources and by
private entities that have been pre-approved to train themselves.
10.The party of the second part shall employ traffic control measures that are in accordance
with the prevailing federal, state, local, and NCDOT policies, standards, and procedures.
These policies, standards, and procedures include, but are not limited to the following:
a. Manual on Uniform Traffic Control Devices (MUTCD) – North Carolina has adopted
the MUTCD to provide basic principles and guidelines for traffic control device design,
application, installation, and maintenance. North Carolina uses the MUTCD as a
minimum requirement where higher supplemental standards specific to North Carolina are
not established. Use fundamental principles and best practices of MUTCD (Part 6,
Temporary Traffic Control).
b. NCDOT Maintenance / Utility Traffic Control Guidelines – This document enhances the
fundamental principles and best practices established in MUTCD Part 6, Temporary
Traffic Control, incorporating NCDOT-specific standards and details. It also covers
important safety knowledge for a wide range of work zone job responsibilities.
11.Nighttime and weekend operations will NOT be allowed unless written approval is
received from the District Engineer. If nighttime or weekend work is allowed or required,
all signs must be retro-reflective, and a work zone lighting plan must be submitted for
approval prior to construction.
12.Two-way traffic shall be maintained at all times unless designated by the District
Engineer. Traffic shall not be rerouted or detoured without the prior written approval from
the District Engineer. No utility work will be allowed on state holidays from 7:00 PM the
night before through 9:00 AM the day prior to, following or during local events without
prior approval from the District Engineer. If the construction is within 1000 feet of a
school location or on a designated bus route, the construction shall be coordinated with the
school start and end times to avoid traffic delays.
13.Work requiring lane or shoulder closures shall not be performed on both sides of the road
simultaneously within the same area.
Wilson County Encroachment Letter
14.Any work requiring equipment or personnel within 5 feet of the edge of any travel lane of
an undivided facility and within 10 feet of the edge of any travel lane of a divided facility
shall require a lane closure with appropriate tapers per current NCDOT Roadway Standard
Drawings or MANUAL ON UNIFORM TRAFFIC CONTROL DEVICES.
15.Any pavement markings that are damaged or obliterated shall be restored by the
encroaching party at no expense to NCDOT.
16.The encroaching party shall comply with all applicable Federal, State and local
environmental regulations and shall obtain all necessary Federal, State and local
environmental permits, including but not limited to, those related to sediment control,
stormwater, wetland, streams, endangered species and historical sites. Additional
information can be obtained by contacting the NCDOT Roadside Environmental Engineer
regarding the North Carolina Natural Heritage Program or the United States Fish and
Wildlife Services. Contact the Division Roadside Environmental Engineer’s Office at 252-
640-6427.
17.When surface area in excess of one acre will be disturbed, the Encroacher shall submit a
Sediment and Erosion Control Plan which has been approved by the appropriate regulatory
agency or authority prior to beginning any work on the Right of Way. Failure to provide
this information shall be grounds for suspension of operations. Proper temporary and
permanent measures shall be used to control erosion and sedimentation in accordance with
the approved sediment and erosion control plan.
18.The Verification of Compliance with Environmental Regulations (VCER-1) form is
required for all non-utility encroachment agreements or any utility encroachments when
land disturbance within NCDOT right of way exceeds 1 acre. The VCER-1 form must be
PE sealed by a NC registered professional engineer who has verified that all appropriate
environmental permits (if applicable) have been obtained and all applicable environmental
regulations have been followed.
19.All erosion control devices and measures shall be constructed, installed, maintained, and
removed by the Encroacher in accordance with all applicable Federal, State, and Local
laws, regulations, ordinances, and policies. Permanent vegetation shall be established on
all disturbed areas in accordance with the recommendations of the Division Roadside
Environmental Engineer. All areas disturbed (shoulders, ditches, removed accesses, etc.)
shall be graded and seeded in accordance with the latest NCDOT Standards Specifications
for Roads and Structures and within 15 calendar days with an approved NCDOT seed
mixture (all lawn type areas shall be maintained and reseeded as such). Seeding rates per
acre shall be applied according to the Division Roadside Environmental Engineer. Any
plant or vegetation in the NCDOT planted sites that is destroyed or damaged as a result of
this encroachment shall be replaced with plants of like kind or similar shape.
20.The contractor shall not begin the construction until after the traffic control and erosion
control devices have been installed to the satisfaction of the Division Engineer or their
agent.
Wilson County Encroachment Letter
21.An executed copy of the encroachment agreement, provisions and approved plans shall be
present at the construction site at all times. If safety or traffic conditions warrant such an
action, NCDOT reserves the right to further limit, restrict or suspend operations within the
right of way.
22.The Encroaching Party and/or their Contractor shall comply with all OSHA requirements.
If OSHA visits the work area associated with this encroachment, the District Office shall
be notified by the encroaching party immediately if any violations are cited.
23.All disturbed areas are to be fully restored to current NCDOT minimum roadway
standards or as directed by the Division Engineer or their representative. Disturbed areas
within NCDOT Right-of-Way include, but not limited to, any excavation areas, pavement
removal, drainage or other features.
24.The encroaching party shall notify the Division Engineer or their representative
immediately in the event any drainage structure is blocked, disturbed or damaged. All
drainage structures disturbed, damaged or blocked shall be restored to its original
condition as directed by the Division Engineer or their representative.
25.Unless specified otherwise, during non-working hours, equipment shall be located away
from the job site or parked as close to the right of way line as possible and be properly
barricaded in order not to have any equipment obstruction within the Clear Recovery Area.
Also, during non-working hours, no parking or material storage shall be allowed along the
shoulders of any state-maintained roadway.
26.Right of Way monuments disturbed during construction shall be referenced by a registered
Land Surveyor and reset after construction.
27.If the approved method of construction is unsuccessful and other means are required, prior
approval must be obtained through the District Engineer before construction may continue.
28.All traffic control, asphalt mixes, structures, construction, workmanship and construction
methods, and materials shall be in compliance with the most-recent versions of the
following resources: ASTM Standards, Manual on Uniform Traffic Control Devices,
NCDOT Utilities Accommodations Manual, NCDOT Standard Specifications for Roads
and Structures, NCDOT Roadway Standard Drawings, NCDOT Asphalt Quality
Management System manual, and the approved plans.
29.It is the responsibility of the encroaching party or their contractor to prevent any mud/dirt
from tracking onto the roadway. Any dirt which may collect on the roadway pavement
from equipment and/or truck traffic on site shall be immediately removed to avoid any
unsafe traffic conditions.
30.The Encroaching party shall notify the District Engineer’s office within 2 business days
after construction is complete. The District Engineer may perform a construction
inspection. Any deficiencies may be noted and reported to the encroaching party to make
immediate repairs or resolve any issues to restore the right-of-way to a similar condition
prior to construction, including pavement, signage, traffic signals, pavement markings,
drainage, structures/pipes, or other highway design features.
Wilson County Encroachment Letter
Special Provisions
1.Excavation within 1000 feet of a signalized intersection will require notification by the
encroaching party to the Division Traffic Engineer at telephone number [phone] no
less than one week prior to beginning work. All traffic signal or detection cables must be
located prior to excavation. Cost to replace or repair NCDOT signs, signals, pavement
markings or associated equipment and facilities shall be the responsibility of the
encroaching party.
2.Ingress and egress shall be maintained to all businesses and dwellings affected by the
project. Special attention shall be paid to police, EMS and fire stations, fire hydrants,
secondary schools, and hospitals.
3.Traffic shall be maintained at all times. All lanes of traffic are to be open during the hours
of 7:00 A.M. to 9:00 A.M. and from 4:00 P.M. to 6:00 P.M. Monday through Friday,
during any time of inclement weather, or as directed by the District Engineer. Any
violation of these hours will result in ceasing any further construction by the Encroaching
Party or their contractor.
4.No trees within NCDOT ROW shall be cut without authorization from the Division
Roadside Environmental Engineer. An inventory of trees measuring greater than 4 caliper
inches (measured 6” above the ground) is required when trees within C/A right of way will
be impacted by the encroachment installation. Mitigation is required and will be
determined by the Division Roadside Environmental Engineer’s Office.
5.The contractor shall perform all monitoring and record keeping and any required
maintenance of erosion and sediment control measures to maintain compliance with
stormwater regulations.
6.Any REVISIONS marked in RED on the attached non-PE sealed plans shall be
incorporated into and made part of the approved encroachment agreement.
Wilson County Encroachment Letter
FORM R/W 16.1A (Revised February 2021)
STATE OF NORTH CAROLINA
ROUTE PROJECT COUNTY OF

DEPARTMENT OF TRANSPORTATION

-AND-
RIGHT OF WAY ENCROACHMENT AGREEMENT
FOR NON-UTILITY ENCROACHMENTS ON
PRIMARY AND SECONDARY HIGHWAYS

THIS AGREEMENT, made and entered into this the day of , 20 , by and between the Department
of Transportation, party of the first part; and
party of the second part,
W I T N E S S E T H
THAT WHEREAS, the party of the second part desires to encroach on the right of way of the public road designated as
Route(s) , located

with the construction and/or erection of:

WHEREAS, it is to the material advantage of the party of the second part to effect this encroachment, and the
party of the first part in the exercise of authority conferred upon it by statute, is willing to permit the encroachment
within the limits of the right of way as indicated, subject to the conditions of this agreement;
NOW, THEREFORE, IT IS AGREED that the party of the first part hereby grants to the party of the second
part the right and privilege to make this encroachment as shown on attached plan sheet(s), specifications and
special provisions which are made a part hereof upon the following conditions, to wit:
That the said party of the second part binds and obligates himself to install and maintain the encroaching facility in such safe
and proper condition that it will not interfere with or endanger travel upon said highway, nor obstruct nor interfere with the proper
maintenance thereof, to reimburse the party of the first part for the cost incurred for any repairs or maintenance to its roadways
and structures necessary due to the installation and existence of the facilities of the party of the second part, and if at any time the
party of the first part shall require the removal of or changes in the location of the said facilities, that the said party of the second
part binds himself, his successors and assigns, to promptly remove or alter the said facilities, in order to conform to the said
requirement, without any cost to the party of the first part.

That the party of the second part agrees to provide during construction and any subsequent maintenance proper signs, signal
lights, flagmen and other warning devices for the protection of traffic in conformance with the latest Manual on Uniform Traffic
Control Devices for Streets and Highways and Amendments or Supplements thereto. Information as to the above rules and
regulations may be obtained from the Division Engineer of the party of the first part.

That the party of the second part hereby agrees to indemnify and save harmless the party of the first part from all damages
and claims for damage that may arise by reason of the installation and maintenance of this encroachment.

It is clearly understood by the party of the second part that the party of the first part will assume no responsibility for any
damage that may be caused to such facilities, within the highway rights of way limits, in carrying out its construction and
maintenance operations.

That the party of the second part agrees to restore all areas disturbed during installation and maintenance to the satisfaction of
the Division Engineer of the party of the first part. The party of the second part agrees to exercise every reasonable precaution
during construction and maintenance to prevent eroding of soil; silting or pollution of rivers, streams, lakes, reservoirs, other water
impoundments, ground surfaces or other property; or pollution of the air. There shall be compliance with applicable rules and
regulations of the North Carolina Division of Environmental Management, North Carolina Sedimentation Control Commission, and
with ordinances and regulations of various counties, municipalities and other official agencies relating to pollution prevention and
control. When any installation or maintenance operation disturbs the ground surface and existing ground cover, the party of the
second part agrees to remove and replace the sod or otherwise reestablish the grass cover to meet the satisfaction of the Division
Engineer of the party of the first part.

That the party of the second part agrees to assume the actual cost of any inspection of the work considered to be necessary
by the Division Engineer of the party of the first part.

That the party of the second part agrees to have available at the encroaching site, at all times during construction, a copy of
this agreement showing evidence of approval by the party of the first part. The party of the first part reserves the right to stop all
work unless evidence of approval can be shown.

Provided the work contained in this agreement is being performed on a completed highway open to traffic; the party of the
second part agrees to give written notice to the Division Engineer of the party of the first part when all work contained herein has
been completed. Unless specifically requested by the party of the first part, written notice of completion of work on highway
projects under construction will not be required.

That in the case of noncompliance with the terms of this agreement by the party of the second part, the party of the first part
reserves the right to stop all work until the facility has been brought into compliance or removed from the right of way at no cost to
the party of the first part.

That it is agreed by both parties that this agreement shall become void if actual construction of the work contemplated herein
is not begun within one (1) year from the date of authorization by the party of the first part unless written waiver is secured by the
party of the second part from the party of the first part.
contamination associated with P&K Mart.
Tow Type II monitoring wells. Wells are being installed to determine extent of ground water
Wilson, Wilson County SR 1168 / Goldsboro Street SW
Geological Resources, Inc.
Monroe, NC 28110
3502 Hayes Road
Geological Resources, Inc.
WilsonP&K MartGoldsboro St SW/SR 1168
18 May 22
For K. Bowen
Map Scale: 1 inch = 50 feet
Long:77 923 Lat:35 711
+
−
Wi ls on Cou nty , North Caro lin a
GIS Mapping
County Home Page (https://www.wilson-co.com/) | GIS Home (https://wilsoncounty.maps.arcgis.com/hom
proposed well
proposed well
P&K Mart
SR 1168 / Goldsboro St. SW
Wilson, Wilson County
GRI 5079
15'
3'
2'
Traffic bearing; flush mounted; domestic steel

Appendix C
Laboratory Analytical Report

03/29/22
Technical Report for
GRI (Geological Resources Inc.)
P&K Food Mart; 1510 Goldsboro St, Wilson, NC
5079
SGS Job Number: FA93743
Sampling Date: 03/08/22
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]; [e-mail]
ATTN: Rae Brown
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AL, AK, AR, CT, IA, KY, MA, MI. MS, ND, NH, NV, OK, OR, IL, UT, VT, WA, WI, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Norm Farmer
Technical Director
Orlando, FL 03/29/22
e-Hardcopy 2.0
Automated Report
129
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
1 of 129
FA93743
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................12
3.1: FA93743-1: DW-1 ........................................................................................................13
3.2: FA93743-2: GMW-1 .....................................................................................................21
3.3: FA93743-3: GMW-6 .....................................................................................................29
3.4: FA93743-4: GMW-2 .....................................................................................................37
3.5: FA93743-5: GMW-5 .....................................................................................................45
3.6: FA93743-6: GMW-3 .....................................................................................................53
3.7: FA93743-7: GMW-4 .....................................................................................................62
3.8: FA93743-8: SW-1 .........................................................................................................71
3.9: FA93743-9: GMW-7 .....................................................................................................79
Section 4: Misc. Forms ............................................................................................................87
4.1: Chain of Custody ...........................................................................................................88
Section 5: MS Volatiles - QC Data Summaries .....................................................................90
5.1: Method Blank Summary ................................................................................................91
5.2: Blank Spike Summary ...................................................................................................97
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................103
Section 6: MS Semi-volatiles - QC Data Summaries ............................................................109
6.1: Method Blank Summary ................................................................................................110
6.2: Blank Spike Summary ...................................................................................................112
6.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................114
Section 7: GC Volatiles - QC Data Summaries .....................................................................116
7.1: Method Blank Summary ................................................................................................117
7.2: Blank Spike/Blank Spike Duplicate Summary ..............................................................120
7.3: Duplicate Summary .......................................................................................................123
Section 8: GC/LC Semi-volatiles - QC Data Summaries .....................................................126
8.1: Method Blank Summary ................................................................................................127
8.2: Blank Spike/Blank Spike Duplicate Summary ..............................................................128 123456782 of 129
FA93743
SGS North America Inc.
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA93743
P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Project No: 5079
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the MDL
FA93743-1 03/08/22 09:41 JB 03/09/22 AQ Ground Water DW-1
FA93743-2 03/08/22 10:02 JB 03/09/22 AQ Ground Water GMW-1
FA93743-3 03/08/22 10:05 JB 03/09/22 AQ Ground Water GMW-6
FA93743-4 03/08/22 10:17 JB 03/09/22 AQ Ground Water GMW-2
FA93743-5 03/08/22 10:23 JB 03/09/22 AQ Ground Water GMW-5
FA93743-6 03/08/22 10:42 JB 03/09/22 AQ Ground Water GMW-3
FA93743-7 03/08/22 10:51 JB 03/09/22 AQ Ground Water GMW-4
FA93743-8 03/08/22 11:03 JB 03/09/22 AQ Ground Water SW-1
FA93743-9 03/08/22 11:15 JB 03/09/22 AQ Ground Water GMW-7
3 of 129
FA937431
Summary of Hits Page 1 of 8
Job Number:FA93743
Account:GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Collected:03/08/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA93743-1 DW-1
Benzene 16.9 0.50 0.13 ug/l SM 6200B
n-Butylbenzene 3.7 0.50 0.13 ug/l SM 6200B
sec-Butylbenzene 1.8 0.50 0.13 ug/l SM 6200B
Di-Isopropyl Ether 1.5 0.50 0.13 ug/l SM 6200B
Ethylbenzene 14.5 0.50 0.13 ug/l SM 6200B
Isopropylbenzene 3.4 0.50 0.13 ug/l SM 6200B
p-Isopropyltoluene 1.1 0.50 0.13 ug/l SM 6200B
Methyl Chloride 0.24 J 0.50 0.20 ug/l SM 6200B
Methyl Tert Butyl Ether 11.4 0.50 0.13 ug/l SM 6200B
Naphthalene 7.6 0.50 0.13 ug/l SM 6200B
n-Propylbenzene 6.8 0.50 0.13 ug/l SM 6200B
Toluene 1.5 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 8.1 0.50 0.13 ug/l SM 6200B
1,3,5-Trimethylbenzene 9.6 0.50 0.13 ug/l SM 6200B
m,p-Xylene 4.3 1.0 0.13 ug/l SM 6200B
o-Xylene 1.2 0.50 0.13 ug/l SM 6200B
Xylene (total)5.5 1.5 0.25 ug/l SM 6200B
bis(2-Ethylhexyl)phthalate 28.7 J 50 10 ug/l EPA 625.1
1-Methylnaphthalene 15.9 J 50 5.3 ug/l EPA 625.1
2-Methylnaphthalene 32.9 J 50 6.0 ug/l EPA 625.1
Naphthalene 17.4 J 50 5.0 ug/l EPA 625.1
Total TIC, Semi-Volatile 1651 J ug/l
Benzene 14.3 1.0 1.0 ug/l MADEP VPH REV 2.1
Ethylbenzene 12.6 2.0 1.0 ug/l MADEP VPH REV 2.1
Methyl Tert Butyl Ether 11.4 2.0 1.0 ug/l MADEP VPH REV 2.1
Naphthalene 6.9 5.0 3.0 ug/l MADEP VPH REV 2.1
Toluene 1.5 J 2.0 1.0 ug/l MADEP VPH REV 2.1
m,p-Xylene 4.6 4.0 2.0 ug/l MADEP VPH REV 2.1
o-Xylene 1.5 J 2.0 1.0 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics (Unadj.)284 100 35 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics (Unadj.)103 100 35 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics 257 100 35 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics 103 100 35 ug/l MADEP VPH REV 2.1
2-Methylnaphthalene 12.9 5.7 2.9 ug/l MADEP EPH REV 2.1
Naphthalene 26.4 5.7 2.9 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics (Unadj.)206 J 290 110 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics 167 J 290 110 ug/l MADEP EPH REV 2.1
C9-C18 Aliphatics 90.2 J 290 71 ug/l MADEP EPH REV 2.1
FA93743-2 GMW-1
Benzene a 8100 100 25 ug/l SM 6200B
n-Butylbenzene b 8.3 0.50 0.13 ug/l SM 6200B
4 of 129
FA937432
Summary of Hits Page 2 of 8
Job Number:FA93743
Account:GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Collected:03/08/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
sec-Butylbenzene b 8.8 0.50 0.13 ug/l SM 6200B
tert-Butylbenzene b 0.54 0.50 0.13 ug/l SM 6200B
1,2-Dichloroethane b 9.1 0.50 0.13 ug/l SM 6200B
Di-Isopropyl Ether b 31.5 0.50 0.13 ug/l SM 6200B
Ethylbenzene a 1190 100 25 ug/l SM 6200B
Ethyl Tert Butyl Ether b 0.93 0.50 0.13 ug/l SM 6200B
Isopropylbenzene a 57.2 J 100 25 ug/l SM 6200B
p-Isopropyltoluene b 6.1 0.50 0.13 ug/l SM 6200B
Methyl Tert Butyl Ether a 85.0 J 100 25 ug/l SM 6200B
Naphthalene a 121 100 25 ug/l SM 6200B
n-Propylbenzene a 102 100 25 ug/l SM 6200B
Styrene b 7.0 0.50 0.13 ug/l SM 6200B
Tert-Amyl Alcohol c 1540 J 2000 400 ug/l SM 6200B
Tert-Butyl Alcohol c 1140 J 2000 400 ug/l SM 6200B
Toluene a 1940 100 25 ug/l SM 6200B
1,2,4-Trimethylbenzene a 930 100 25 ug/l SM 6200B
1,3,5-Trimethylbenzene a 306 100 25 ug/l SM 6200B
m,p-Xylene a 2320 200 25 ug/l SM 6200B
o-Xylene a 567 100 25 ug/l SM 6200B
Xylene (total) a 2890 300 50 ug/l SM 6200B
2,4-Dimethylphenol d 89.1 25 3.7 ug/l EPA 625.1
2-Methylphenol d 42.7 25 2.8 ug/l EPA 625.1
3&4-Methylphenol d 20.8 J 25 4.9 ug/l EPA 625.1
Phenol d 7.1 J 25 2.5 ug/l EPA 625.1
1-Methylnaphthalene d 10.3 J 25 2.6 ug/l EPA 625.1
2-Methylnaphthalene d 5.1 J 25 3.0 ug/l EPA 625.1
Naphthalene d 48.2 25 2.5 ug/l EPA 625.1
Total TIC, Semi-Volatile 6537 J ug/l
Benzene 6930 20 20 ug/l MADEP VPH REV 2.1
Ethylbenzene 1080 40 20 ug/l MADEP VPH REV 2.1
Methyl Tert Butyl Ether 56.4 40 20 ug/l MADEP VPH REV 2.1
Naphthalene 140 100 60 ug/l MADEP VPH REV 2.1
Toluene 1720 40 20 ug/l MADEP VPH REV 2.1
m,p-Xylene 2130 80 40 ug/l MADEP VPH REV 2.1
o-Xylene 545 40 20 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics (Unadj.)8180 2000 700 ug/l MADEP VPH REV 2.1
C9- C12 Aliphatics (Unadj.)1180 J 2000 700 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics (Unadj.)2070 2000 700 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics 2070 2000 700 ug/l MADEP VPH REV 2.1
2-Methylnaphthalene 18.3 3.9 2.0 ug/l MADEP EPH REV 2.1
Naphthalene 75.3 3.9 2.0 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics (Unadj.)538 200 78 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics 445 200 78 ug/l MADEP EPH REV 2.1
5 of 129
FA937432
Summary of Hits Page 3 of 8
Job Number:FA93743
Account:GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Collected:03/08/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA93743-3 GMW-6
Benzene 2260 100 25 ug/l SM 6200B
Ethylbenzene 447 100 25 ug/l SM 6200B
Isopropylbenzene 54.7 J 100 25 ug/l SM 6200B
Methyl Tert Butyl Ether 50.3 J 100 25 ug/l SM 6200B
Naphthalene 115 100 25 ug/l SM 6200B
n-Propylbenzene 90.3 J 100 25 ug/l SM 6200B
Tert-Amyl Alcohol 530 J 2000 400 ug/l SM 6200B
Toluene 451 100 25 ug/l SM 6200B
1,2,4-Trimethylbenzene 298 100 25 ug/l SM 6200B
1,3,5-Trimethylbenzene 106 100 25 ug/l SM 6200B
m,p-Xylene 1090 200 25 ug/l SM 6200B
o-Xylene 186 100 25 ug/l SM 6200B
Xylene (total)1280 300 50 ug/l SM 6200B
2,4-Dimethylphenol 17.7 5.3 0.79 ug/l EPA 625.1
3&4-Methylphenol 2.2 J 5.3 1.0 ug/l EPA 625.1
Phenol 4.3 J 5.3 0.53 ug/l EPA 625.1
1-Methylnaphthalene 13.2 5.3 0.56 ug/l EPA 625.1
2-Methylnaphthalene 18.3 5.3 0.64 ug/l EPA 625.1
Naphthalene 119 27 2.7 ug/l EPA 625.1
Total TIC, Semi-Volatile 2979 J ug/l
Benzene 2230 20 20 ug/l MADEP VPH REV 2.1
Ethylbenzene 474 40 20 ug/l MADEP VPH REV 2.1
Methyl Tert Butyl Ether 48.6 2.0 1.0 ug/l MADEP VPH REV 2.1
Naphthalene 191 5.0 3.0 ug/l MADEP VPH REV 2.1
Toluene 364 2.0 1.0 ug/l MADEP VPH REV 2.1
m,p-Xylene 1120 80 40 ug/l MADEP VPH REV 2.1
o-Xylene 184 2.0 1.0 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics (Unadj.)2470 2000 700 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics (Unadj.)970 J 2000 700 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics e 495 E 100 35 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics 970 J 2000 700 ug/l MADEP VPH REV 2.1
2-Methylnaphthalene 13.2 3.8 1.9 ug/l MADEP EPH REV 2.1
Naphthalene 97.2 3.8 1.9 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics (Unadj.)368 190 77 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics 257 190 77 ug/l MADEP EPH REV 2.1
FA93743-4 GMW-2
Benzene f 3480 E 25 6.3 ug/l SM 6200B
Di-Isopropyl Ether 11.7 J 25 6.3 ug/l SM 6200B
Ethylbenzene 253 25 6.3 ug/l SM 6200B
Isopropylbenzene 23.6 J 25 6.3 ug/l SM 6200B
Methyl Chloride 17.6 J 25 10 ug/l SM 6200B
6 of 129
FA937432
Summary of Hits Page 4 of 8
Job Number:FA93743
Account:GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Collected:03/08/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
Methyl Tert Butyl Ether 12.8 J 25 6.3 ug/l SM 6200B
Naphthalene 91.7 25 6.3 ug/l SM 6200B
n-Propylbenzene 49.0 25 6.3 ug/l SM 6200B
Tert-Amyl Alcohol 599 500 100 ug/l SM 6200B
Tert-Butyl Alcohol 526 500 100 ug/l SM 6200B
Toluene 66.5 25 6.3 ug/l SM 6200B
1,2,4-Trimethylbenzene 38.9 25 6.3 ug/l SM 6200B
1,3,5-Trimethylbenzene 23.1 J 25 6.3 ug/l SM 6200B
m,p-Xylene 113 50 6.3 ug/l SM 6200B
o-Xylene 18.9 J 25 6.3 ug/l SM 6200B
2,4-Dimethylphenol 2.6 J 4.8 0.71 ug/l EPA 625.1
Acenaphthene 1.0 J 4.8 0.60 ug/l EPA 625.1
Dibenzofuran 0.69 J 4.8 0.58 ug/l EPA 625.1
Fluorene 1.4 J 4.8 0.67 ug/l EPA 625.1
1-Methylnaphthalene 37.8 4.8 0.50 ug/l EPA 625.1
2-Methylnaphthalene 49.0 4.8 0.58 ug/l EPA 625.1
Naphthalene 78.0 4.8 0.48 ug/l EPA 625.1
Total TIC, Semi-Volatile 782 J ug/l
Benzene 3080 10 10 ug/l MADEP VPH REV 2.1
Ethylbenzene 251 2.0 1.0 ug/l MADEP VPH REV 2.1
Naphthalene 120 5.0 3.0 ug/l MADEP VPH REV 2.1
Toluene 58.1 2.0 1.0 ug/l MADEP VPH REV 2.1
m,p-Xylene 118 4.0 2.0 ug/l MADEP VPH REV 2.1
o-Xylene 23.5 2.0 1.0 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics (Unadj.)3120 1000 350 ug/l MADEP VPH REV 2.1
C9- C12 Aliphatics (Unadj.) e 37.7 EJ 100 35 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics (Unadj.)365 J 1000 350 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics e 1320 E 100 35 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics 365 J 1000 350 ug/l MADEP VPH REV 2.1
2-Methylnaphthalene 40.4 3.8 1.9 ug/l MADEP EPH REV 2.1
Naphthalene 76.6 3.8 1.9 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics (Unadj.)455 190 76 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics 338 190 76 ug/l MADEP EPH REV 2.1
FA93743-5 GMW-5
Benzene 43.5 J 50 13 ug/l SM 6200B
Ethylbenzene 56.4 50 13 ug/l SM 6200B
1,2,4-Trimethylbenzene 37.9 J 50 13 ug/l SM 6200B
1,3,5-Trimethylbenzene 18.9 J 50 13 ug/l SM 6200B
m,p-Xylene 74.2 J 100 13 ug/l SM 6200B
Xylene (total)74.2 J 150 25 ug/l SM 6200B
2,4-Dimethylphenol 1.3 J 5.2 0.77 ug/l EPA 625.1
Fluorene 1.9 J 5.2 0.73 ug/l EPA 625.1
1-Methylnaphthalene 1.4 J 5.2 0.55 ug/l EPA 625.1
7 of 129
FA937432
Summary of Hits Page 5 of 8
Job Number:FA93743
Account:GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Collected:03/08/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
2-Methylnaphthalene 2.6 J 5.2 0.63 ug/l EPA 625.1
Naphthalene 5.8 5.2 0.52 ug/l EPA 625.1
Total TIC, Semi-Volatile 524.8 J ug/l
Benzene 39.3 1.0 1.0 ug/l MADEP VPH REV 2.1
Ethylbenzene 60.1 2.0 1.0 ug/l MADEP VPH REV 2.1
Naphthalene 10.5 5.0 3.0 ug/l MADEP VPH REV 2.1
Toluene 11.0 2.0 1.0 ug/l MADEP VPH REV 2.1
m,p-Xylene 86.6 4.0 2.0 ug/l MADEP VPH REV 2.1
o-Xylene 10.0 2.0 1.0 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics (Unadj.)371 100 35 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics (Unadj.)206 100 35 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics 321 100 35 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics 206 100 35 ug/l MADEP VPH REV 2.1
Naphthalene 6.0 4.1 2.0 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics (Unadj.)151 J 200 82 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics 145 J 200 82 ug/l MADEP EPH REV 2.1
FA93743-6 GMW-3
Benzene a 1440 25 6.3 ug/l SM 6200B
n-Butylbenzene 6.6 0.50 0.13 ug/l SM 6200B
sec-Butylbenzene 14.4 0.50 0.13 ug/l SM 6200B
tert-Butylbenzene 1.7 0.50 0.13 ug/l SM 6200B
o-Chlorotoluene 0.31 J 0.50 0.13 ug/l SM 6200B
cis-1,2-Dichloroethylene 0.71 0.50 0.13 ug/l SM 6200B
Di-Isopropyl Ether 8.3 0.50 0.13 ug/l SM 6200B
Ethylbenzene a 92.8 25 6.3 ug/l SM 6200B
Isopropylbenzene a 58.7 25 6.3 ug/l SM 6200B
p-Isopropyltoluene 0.38 J 0.50 0.13 ug/l SM 6200B
Methyl Chloride 9.3 0.50 0.20 ug/l SM 6200B
Methyl Tert Butyl Ether 33.4 0.50 0.13 ug/l SM 6200B
Naphthalene 21.1 0.50 0.13 ug/l SM 6200B
n-Propylbenzene a 128 25 6.3 ug/l SM 6200B
Tert-Amyl Alcohol 283 10 2.0 ug/l SM 6200B
Tert-Butyl Alcohol 262 10 2.0 ug/l SM 6200B
Toluene 11.2 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene a 47.2 25 6.3 ug/l SM 6200B
1,3,5-Trimethylbenzene 1.7 0.50 0.13 ug/l SM 6200B
m,p-Xylene 59.4 1.0 0.13 ug/l SM 6200B
o-Xylene 3.3 0.50 0.13 ug/l SM 6200B
Xylene (total)62.7 1.5 0.25 ug/l SM 6200B
Phenol d 3.3 J 25 2.5 ug/l EPA 625.1
Fluorene d 3.5 J 25 3.4 ug/l EPA 625.1
1-Methylnaphthalene d 71.1 25 2.6 ug/l EPA 625.1
2-Methylnaphthalene d 57.7 25 2.9 ug/l EPA 625.1
8 of 129
FA937432
Summary of Hits Page 6 of 8
Job Number:FA93743
Account:GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Collected:03/08/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
Naphthalene d 20.3 J 25 2.5 ug/l EPA 625.1
Total TIC, Semi-Volatile 1020 J ug/l
Benzene 1200 5.0 5.0 ug/l MADEP VPH REV 2.1
Ethylbenzene 81.8 10 5.0 ug/l MADEP VPH REV 2.1
Methyl Tert Butyl Ether 31.8 10 5.0 ug/l MADEP VPH REV 2.1
Naphthalene 28.9 25 15 ug/l MADEP VPH REV 2.1
Toluene 11.7 10 5.0 ug/l MADEP VPH REV 2.1
m,p-Xylene 62.9 20 10 ug/l MADEP VPH REV 2.1
o-Xylene 7.8 J 10 5.0 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics (Unadj.)1410 500 180 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics (Unadj.)536 500 180 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics 536 500 180 ug/l MADEP VPH REV 2.1
2-Methylnaphthalene g 24.8 3.8 1.9 ug/l MADEP EPH REV 2.1
Naphthalene g 30.6 3.8 1.9 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics (Unadj.) g 468 190 76 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics g 413 190 76 ug/l MADEP EPH REV 2.1
FA93743-7 GMW-4
Benzene 9780 250 63 ug/l SM 6200B
Ethylbenzene 849 250 63 ug/l SM 6200B
Isopropylbenzene 170 J 250 63 ug/l SM 6200B
Naphthalene 378 250 63 ug/l SM 6200B
n-Propylbenzene 301 250 63 ug/l SM 6200B
Tert-Amyl Alcohol 1130 J 5000 1000 ug/l SM 6200B
Toluene 158 J 250 63 ug/l SM 6200B
1,2,4-Trimethylbenzene 450 250 63 ug/l SM 6200B
1,3,5-Trimethylbenzene 135 J 250 63 ug/l SM 6200B
m,p-Xylene 654 500 63 ug/l SM 6200B
Xylene (total)654 J 750 130 ug/l SM 6200B
2,4-Dimethylphenol 44.7 5.4 0.80 ug/l EPA 625.1
Phenol 13.4 5.4 0.54 ug/l EPA 625.1
1-Methylnaphthalene 41.8 5.4 0.57 ug/l EPA 625.1
2-Methylnaphthalene 64.8 5.4 0.65 ug/l EPA 625.1
Naphthalene 169 27 2.7 ug/l EPA 625.1
Total TIC, Semi-Volatile 1857 J ug/l
Benzene 9080 50 50 ug/l MADEP VPH REV 2.1
Ethylbenzene 808 10 5.0 ug/l MADEP VPH REV 2.1
Methyl Tert Butyl Ether 41.4 10 5.0 ug/l MADEP VPH REV 2.1
Naphthalene 324 25 15 ug/l MADEP VPH REV 2.1
Toluene 116 10 5.0 ug/l MADEP VPH REV 2.1
m,p-Xylene 639 20 10 ug/l MADEP VPH REV 2.1
o-Xylene 39.0 10 5.0 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics (Unadj.)8250 1000 350 ug/l MADEP VPH REV 2.1
C9- C12 Aliphatics (Unadj.)194 J 500 180 ug/l MADEP VPH REV 2.1
9 of 129
FA937432
Summary of Hits Page 7 of 8
Job Number:FA93743
Account:GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Collected:03/08/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
C9- C10 Aromatics (Unadj.)1740 500 180 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics e 1200 E 500 180 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics 1740 500 180 ug/l MADEP VPH REV 2.1
2-Methylnaphthalene g 47.7 4.1 2.0 ug/l MADEP EPH REV 2.1
Naphthalene g 146 4.1 2.0 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics (Unadj.) g 758 200 82 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics g 564 200 82 ug/l MADEP EPH REV 2.1
C9-C18 Aliphatics g 52.4 J 200 51 ug/l MADEP EPH REV 2.1
FA93743-8 SW-1
Benzene 9650 250 63 ug/l SM 6200B
Ethylbenzene 1450 250 63 ug/l SM 6200B
Isopropylbenzene 77.1 J 250 63 ug/l SM 6200B
Naphthalene 138 J 250 63 ug/l SM 6200B
n-Propylbenzene 226 J 250 63 ug/l SM 6200B
1,2,4-Trimethylbenzene 138 J 250 63 ug/l SM 6200B
1,3,5-Trimethylbenzene 65.1 J 250 63 ug/l SM 6200B
m,p-Xylene 888 500 63 ug/l SM 6200B
Xylene (total)888 750 130 ug/l SM 6200B
2,4-Dimethylphenol 22.2 4.9 0.72 ug/l EPA 625.1
Phenol 14.4 4.9 0.49 ug/l EPA 625.1
1-Methylnaphthalene 49.0 4.9 0.51 ug/l EPA 625.1
2-Methylnaphthalene 81.8 4.9 0.58 ug/l EPA 625.1
Naphthalene 125 24 2.4 ug/l EPA 625.1
Total TIC, Semi-Volatile 3517 J ug/l
Benzene 8940 50 50 ug/l MADEP VPH REV 2.1
Ethylbenzene 1480 20 10 ug/l MADEP VPH REV 2.1
Naphthalene 183 5.0 3.0 ug/l MADEP VPH REV 2.1
Toluene 102 2.0 1.0 ug/l MADEP VPH REV 2.1
m,p-Xylene 709 4.0 2.0 ug/l MADEP VPH REV 2.1
o-Xylene 26.2 2.0 1.0 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics (Unadj.)10500 1000 350 ug/l MADEP VPH REV 2.1
C9- C12 Aliphatics (Unadj.)798 J 1000 350 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics (Unadj.)1260 1000 350 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics e 2370 E 1000 350 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics 1260 1000 350 ug/l MADEP VPH REV 2.1
2-Methylnaphthalene 61.2 3.8 1.9 ug/l MADEP EPH REV 2.1
Naphthalene 117 3.8 1.9 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics (Unadj.)849 190 76 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics 671 190 76 ug/l MADEP EPH REV 2.1
C9-C18 Aliphatics 397 190 48 ug/l MADEP EPH REV 2.1
C19-C36 Aliphatics 203 190 48 ug/l MADEP EPH REV 2.1
10 of 129
FA937432
Summary of Hits Page 8 of 8
Job Number:FA93743
Account:GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Collected:03/08/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA93743-9 GMW-7
Benzene 1000 25 6.3 ug/l SM 6200B
Ethylbenzene 116 25 6.3 ug/l SM 6200B
Isopropylbenzene 9.9 J 25 6.3 ug/l SM 6200B
Naphthalene 67.8 25 6.3 ug/l SM 6200B
n-Propylbenzene 27.0 25 6.3 ug/l SM 6200B
Tert-Amyl Alcohol 1110 500 100 ug/l SM 6200B
Tert-Butyl Alcohol 165 J 500 100 ug/l SM 6200B
Toluene 143 25 6.3 ug/l SM 6200B
1,2,4-Trimethylbenzene 47.1 25 6.3 ug/l SM 6200B
1,3,5-Trimethylbenzene 16.9 J 25 6.3 ug/l SM 6200B
m,p-Xylene 241 50 6.3 ug/l SM 6200B
o-Xylene 28.8 25 6.3 ug/l SM 6200B
2,4-Dimethylphenol 1.7 J 4.7 0.70 ug/l EPA 625.1
Phenol 1.4 J 4.7 0.47 ug/l EPA 625.1
Dibenzofuran 0.79 J 4.7 0.57 ug/l EPA 625.1
1-Methylnaphthalene 15.3 4.7 0.50 ug/l EPA 625.1
2-Methylnaphthalene 15.6 4.7 0.57 ug/l EPA 625.1
Naphthalene 43.6 4.7 0.47 ug/l EPA 625.1
Total TIC, Semi-Volatile 965 J ug/l
Benzene 892 10 10 ug/l MADEP VPH REV 2.1
Ethylbenzene 109 2.0 1.0 ug/l MADEP VPH REV 2.1
Naphthalene 79.9 5.0 3.0 ug/l MADEP VPH REV 2.1
Toluene 114 2.0 1.0 ug/l MADEP VPH REV 2.1
m,p-Xylene 218 4.0 2.0 ug/l MADEP VPH REV 2.1
o-Xylene 35.0 2.0 1.0 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics (Unadj.)1310 1000 350 ug/l MADEP VPH REV 2.1
C9- C12 Aliphatics (Unadj.) e 59.5 EJ 100 35 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics (Unadj.)353 J 1000 350 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics e 413 E 100 35 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics 353 J 1000 350 ug/l MADEP VPH REV 2.1
2-Methylnaphthalene 18.3 4.2 2.1 ug/l MADEP EPH REV 2.1
Naphthalene 51.2 4.2 2.1 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics (Unadj.)405 210 83 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics 335 210 83 ug/l MADEP EPH REV 2.1
C19-C36 Aliphatics 62.3 J 210 52 ug/l MADEP EPH REV 2.1
(a) Internal standard areas outside method criteria.
(b) Results from different vials are not consistent; higher results were reported.
(c) Internal standard areas outside method criteria. Associated ECC outside control limits low.
(d) Dilution required due to matrix interference.
(e) Compound below calibration range in higher dilution.
(f) Insufficient sample available for reanalysis.
(g) Confirmed by refractionation and reanalysis. Insufficient sample for re-extraction.
11 of 129
FA937432
SGS North America Inc.
Sample Results
Report of Analysis
Orlando, FL
Section 3
12 of 129
FA937433
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:DW-1
Lab Sample ID:FA93743-1 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 N0124881.D 1 03/22/22 19:37 LR n/a n/a VN6437
Run #2 A0231120.D 250 03/21/22 15:30 SS n/a n/a VA3092
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 16.9 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene 3.7 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene 1.8 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND a 130 50 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
13 of 129
FA9374333.1
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:DW-1
Lab Sample ID:FA93743-1 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 1.5 0.50 0.13 ug/l
64-17-5 Ethyl Alcohol ND a 25000 16000 ug/l
100-41-4 Ethylbenzene 14.5 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 3.4 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene 1.1 0.50 0.13 ug/l
74-83-9 Methyl Bromide b ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride 0.24 0.50 0.20 ug/l J
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride b ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 11.4 0.50 0.13 ug/l
91-20-3 Naphthalene 7.6 0.50 0.13 ug/l
103-65-1 n-Propylbenzene 6.8 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND a 2500 500 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND a 2500 500 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 1.5 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene 8.1 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene 9.6 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 4.3 1.0 0.13 ug/l
95-47-6 o-Xylene 1.2 0.50 0.13 ug/l
1330-20-7 Xylene (total)5.5 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 101%98%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
14 of 129
FA9374333.1
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:DW-1
Lab Sample ID:FA93743-1 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 105%102%70-130%
2037-26-5 Toluene-D8 94%100%70-130%
460-00-4 4-Bromofluorobenzene 97%103%70-130%
(a) Result is from Run# 2
(b) Associated ECC outside of control limits high, sample was ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
15 of 129
FA9374333.1
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:DW-1
Lab Sample ID:FA93743-1 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 6F13676.D 1 03/16/22 12:34 WH 03/10/22 10:10 OP90179 S6F510
Run #2 a 6F13652.D 1 03/10/22 21:19 WH 03/10/22 10:10 OP90179 S6F508
Initial Volume Final Volume
Run #1 100 ml 1.0 ml
Run #2 100 ml 1.0 ml
ABN Special List
CAS No.Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 500 100 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 50 5.9 ug/l
95-57-8 2-Chlorophenol ND 50 6.3 ug/l
120-83-2 2,4-Dichlorophenol ND 50 8.4 ug/l
105-67-9 2,4-Dimethylphenol ND 50 7.4 ug/l
51-28-5 2,4-Dinitrophenol ND 250 50 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 100 20 ug/l
95-48-7 2-Methylphenol ND 50 5.6 ug/l
3&4-Methylphenol ND 50 9.8 ug/l
88-75-5 2-Nitrophenol ND 50 8.5 ug/l
100-02-7 4-Nitrophenol b ND 250 50 ug/l
87-86-5 Pentachlorophenol ND 250 50 ug/l
108-95-2 Phenol ND 50 5.0 ug/l
88-06-2 2,4,6-Trichlorophenol ND 50 7.5 ug/l
83-32-9 Acenaphthene ND 50 6.3 ug/l
208-96-8 Acenaphthylene ND 50 6.4 ug/l
120-12-7 Anthracene ND 50 8.0 ug/l
56-55-3 Benzo(a)anthracene ND 50 7.6 ug/l
50-32-8 Benzo(a)pyrene ND 50 7.8 ug/l
205-99-2 Benzo(b)fluoranthene ND 50 7.8 ug/l
191-24-2 Benzo(g,h,i)perylene ND 50 8.2 ug/l
207-08-9 Benzo(k)fluoranthene ND 50 8.6 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 50 8.5 ug/l
85-68-7 Butyl Benzyl Phthalate ND 50 10 ug/l
106-47-8 4-Chloroaniline ND 50 6.3 ug/l
111-91-1 bis(2-Chloroethoxy)methane ND 50 8.1 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 50 7.3 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane)ND 50 7.6 ug/l
91-58-7 2-Chloronaphthalene ND 50 5.0 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether ND 50 5.4 ug/l
218-01-9 Chrysene ND 50 8.5 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 50 8.0 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
16 of 129
FA9374333.1
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:DW-1
Lab Sample ID:FA93743-1 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
ABN Special List
CAS No.Compound Result RL MDL Units Q
132-64-9 Dibenzofuran ND 50 6.0 ug/l
91-94-1 3,3'-Dichlorobenzidine ND 50 6.4 ug/l
84-66-2 Diethyl Phthalate ND 50 10 ug/l
131-11-3 Dimethyl Phthalate ND 50 10 ug/l
84-74-2 Di-n-butyl Phthalate ND 50 10 ug/l
117-84-0 Di-n-octyl Phthalate b ND 50 10 ug/l
121-14-2 2,4-Dinitrotoluene ND 50 8.1 ug/l
606-20-2 2,6-Dinitrotoluene ND 50 7.1 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate 28.7 50 10 ug/l J
206-44-0 Fluoranthene ND 50 5.5 ug/l
86-73-7 Fluorene ND 50 7.0 ug/l
118-74-1 Hexachlorobenzene ND 50 6.9 ug/l
87-68-3 Hexachlorobutadiene ND 50 5.0 ug/l
77-47-4 Hexachlorocyclopentadiene ND 50 18 ug/l
67-72-1 Hexachloroethane ND 50 16 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 50 7.1 ug/l
78-59-1 Isophorone c ND 50 7.8 ug/l
90-12-0 1-Methylnaphthalene 15.9 50 5.3 ug/l J
91-57-6 2-Methylnaphthalene 32.9 50 6.0 ug/l J
91-20-3 Naphthalene 17.4 50 5.0 ug/l J
98-95-3 Nitrobenzene ND 50 9.3 ug/l
621-64-7 N-Nitrosodi-n-propylamine ND 50 6.7 ug/l
86-30-6 N-Nitrosodiphenylamine ND 50 8.1 ug/l
85-01-8 Phenanthrene ND 50 8.6 ug/l
129-00-0 Pyrene ND 50 6.8 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
367-12-4 2-Fluorophenol 14%14%14-67%
4165-62-2 Phenol-d5 21%20%10-50%
118-79-6 2,4,6-Tribromophenol 26% d 26%33-118%
4165-60-0 Nitrobenzene-d5 55%52%42-108%
321-60-8 2-Fluorobiphenyl 35% d 36%40-106%
1718-51-0 Terphenyl-d14 25% d 26%39-121%
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
3522-94-9 Hexane, 2,2,5-trimethyl-2.79 60 ug/l JN
111-65-9 Octane 3.01 68 ug/l JN
2216-34-4 Octane, 4-methyl-3.72 58 ug/l JN
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
17 of 129
FA9374333.1
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:DW-1
Lab Sample ID:FA93743-1 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
ABN Special List
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
2216-33-3 Octane, 3-methyl-3.81 94 ug/l JN
111-84-2 Nonane 4.11 84 ug/l JN
103-65-1 Benzene, propyl-4.66 73 ug/l JN
620-14-4 Benzene, 1-ethyl-3-methyl-4.74 120 ug/l JN
611-14-3 Benzene, 1-ethyl-2-methyl-4.77 81 ug/l JN
526-73-8 Benzene, 1,2,3-trimethyl-4.82 120 ug/l JN
108-67-8 Benzene, 1,3,5-trimethyl-5.05 210 ug/l JN
124-18-5 Decane 5.08 60 ug/l JN
135-01-3 Benzene, 1,2-diethyl-5.52 56 ug/l JN
1074-43-7 Benzene, 1-methyl-3-propyl-5.55 89 ug/l JN
934-80-5 Benzene, 4-ethyl-1,2-dimethyl-5.60 180 ug/l JN
1758-88-9 Benzene, 2-ethyl-1,4-dimethyl-5.76 68 ug/l JN
527-84-4 Benzene, 1-methyl-2-(1-methylethyl 5.79 51 ug/l JN
933-98-2 Benzene, 1-ethyl-2,3-dimethyl-6.10 52 ug/l JN
95-93-2 Benzene, 1,2,4,5-tetramethyl-6.13 59 ug/l JN
767-58-8 Indan, 1-methyl-6.37 68 ug/l JN
Total TIC, Semi-Volatile 1651 ug/l J
(a) Confirmation run for surrogate recoveries.
(b) Associated CCV outside of control limits high, sample was ND.
(c) Associated BS outside control limits high, sample was ND.
(d) Confirmed by reanalysis. Insufficient sample for re-extraction.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
18 of 129
FA9374333.1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:DW-1
Lab Sample ID:FA93743-1 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP VPH REV 2.1 Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U9069.D 1 03/18/22 10:46 JR n/a n/a G1U400
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 14.3 1.0 1.0 ug/l
100-41-4 Ethylbenzene 12.6 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 11.4 2.0 1.0 ug/l
91-20-3 Naphthalene 6.9 5.0 3.0 ug/l
108-88-3 Toluene 1.5 2.0 1.0 ug/l J
m,p-Xylene 4.6 4.0 2.0 ug/l
95-47-6 o-Xylene 1.5 2.0 1.0 ug/l J
C5- C8 Aliphatics (Unadj.)284 100 35 ug/l
C9- C12 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C10 Aromatics (Unadj.)103 100 35 ug/l
C5- C8 Aliphatics 257 100 35 ug/l
C9- C12 Aliphatics ND 100 35 ug/l
C9- C10 Aromatics 103 100 35 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 76%70-130%
460-00-4 BFB 70%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
19 of 129
FA9374333.1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:DW-1
Lab Sample ID:FA93743-1 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP EPH REV 2.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 NN037779.D 1 03/11/22 17:55 AF 03/10/22 12:05 OP90180 GNN1768
Run #2
Initial Volume Final Volume
Run #1 700 ml 2.0 ml
Run #2
MAEPH List
CAS No.Compound Result RL MDL Units Q
83-32-9 Acenaphthene ND 5.7 2.9 ug/l
208-96-8 Acenaphthylene ND 5.7 2.9 ug/l
120-12-7 Anthracene ND 5.7 2.9 ug/l
56-55-3 Benzo(a)anthracene ND 5.7 2.9 ug/l
50-32-8 Benzo(a)pyrene ND 5.7 2.9 ug/l
205-99-2 Benzo(b)fluoranthene ND 5.7 2.9 ug/l
191-24-2 Benzo(g,h,i)perylene ND 5.7 2.9 ug/l
207-08-9 Benzo(k)fluoranthene ND 5.7 2.9 ug/l
218-01-9 Chrysene ND 5.7 2.9 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 5.7 2.9 ug/l
206-44-0 Fluoranthene ND 5.7 2.9 ug/l
86-73-7 Fluorene ND 5.7 2.9 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 5.7 2.9 ug/l
91-57-6 2-Methylnaphthalene 12.9 5.7 2.9 ug/l
91-20-3 Naphthalene 26.4 5.7 2.9 ug/l
85-01-8 Phenanthrene ND 5.7 2.9 ug/l
129-00-0 Pyrene ND 5.7 2.9 ug/l
C11-C22 Aromatics (Unadj.)206 290 110 ug/l J
C11-C22 Aromatics 167 290 110 ug/l J
C9-C18 Aliphatics 90.2 290 71 ug/l J
C19-C36 Aliphatics ND 290 71 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
3386-33-2 1-Chlorooctadecane 58% a 40-140%
580-13-2 2-Bromonaphthalene 77%40-140%
84-15-1 o-Terphenyl 67% a 40-140%
321-60-8 2-Fluorobiphenyl 75%40-140%
(a) Surrogate recoveries corrected for double spike.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
20 of 129
FA9374333.1
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:GMW-1
Lab Sample ID:FA93743-2 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a A0231114.D 1 03/21/22 13:12 SS n/a n/a VA3092
Run #2 b N0124877.D 200 03/22/22 18:04 LR n/a n/a VN6437
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 8100 c 100 25 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene 8.3 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene 8.8 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene 0.54 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane d ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane 9.1 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene e ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
21 of 129
FA9374333.2
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:GMW-1
Lab Sample ID:FA93743-2 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 31.5 0.50 0.13 ug/l
64-17-5 Ethyl Alcohol ND 100 65 ug/l
100-41-4 Ethylbenzene 1190 c 100 25 ug/l
637-92-3 Ethyl Tert Butyl Ether 0.93 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 57.2 c 100 25 ug/l J
99-87-6 p-Isopropyltoluene 6.1 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 85.0 c 100 25 ug/l J
91-20-3 Naphthalene 121 c 100 25 ug/l
103-65-1 n-Propylbenzene 102 c 100 25 ug/l
100-42-5 Styrene 7.0 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol e 1540 c 2000 400 ug/l J
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol e 1140 c 2000 400 ug/l J
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 1940 c 100 25 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane d ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene 930 c 100 25 ug/l
108-67-8 1,3,5-Trimethylbenzene 306 c 100 25 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 2320 c 200 25 ug/l
95-47-6 o-Xylene 567 c 100 25 ug/l
1330-20-7 Xylene (total)2890 c 300 50 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 96%102%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
22 of 129
FA9374333.2
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:GMW-1
Lab Sample ID:FA93743-2 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 99%104%70-130%
2037-26-5 Toluene-D8 103%100%70-130%
460-00-4 4-Bromofluorobenzene 116%95%70-130%
(a) Results from different vials are not consistent; higher results were reported.
(b) Internal standard areas outside method criteria.
(c) Result is from Run# 2
(d) Associated ECC outside of control limits high, sample was ND.
(e) Associated ECC outside control limits low.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
23 of 129
FA9374333.2
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:GMW-1
Lab Sample ID:FA93743-2 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 6F13653.D 5 03/10/22 21:44 WH 03/10/22 10:10 OP90179 S6F508
Run #2
Initial Volume Final Volume
Run #1 1000 ml 1.0 ml
Run #2
ABN Special List
CAS No.Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 250 50 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 25 3.0 ug/l
95-57-8 2-Chlorophenol ND 25 3.2 ug/l
120-83-2 2,4-Dichlorophenol ND 25 4.2 ug/l
105-67-9 2,4-Dimethylphenol 89.1 25 3.7 ug/l
51-28-5 2,4-Dinitrophenol ND 130 25 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 50 10 ug/l
95-48-7 2-Methylphenol 42.7 25 2.8 ug/l
3&4-Methylphenol 20.8 25 4.9 ug/l J
88-75-5 2-Nitrophenol ND 25 4.3 ug/l
100-02-7 4-Nitrophenol ND 130 25 ug/l
87-86-5 Pentachlorophenol ND 130 25 ug/l
108-95-2 Phenol 7.1 25 2.5 ug/l J
88-06-2 2,4,6-Trichlorophenol ND 25 3.8 ug/l
83-32-9 Acenaphthene ND 25 3.1 ug/l
208-96-8 Acenaphthylene ND 25 3.2 ug/l
120-12-7 Anthracene ND 25 4.0 ug/l
56-55-3 Benzo(a)anthracene ND 25 3.8 ug/l
50-32-8 Benzo(a)pyrene ND 25 3.9 ug/l
205-99-2 Benzo(b)fluoranthene ND 25 3.9 ug/l
191-24-2 Benzo(g,h,i)perylene ND 25 4.1 ug/l
207-08-9 Benzo(k)fluoranthene ND 25 4.3 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 25 4.2 ug/l
85-68-7 Butyl Benzyl Phthalate ND 25 5.0 ug/l
106-47-8 4-Chloroaniline ND 25 3.2 ug/l
111-91-1 bis(2-Chloroethoxy)methane ND 25 4.0 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 25 3.7 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane)ND 25 3.8 ug/l
91-58-7 2-Chloronaphthalene ND 25 2.5 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether ND 25 2.7 ug/l
218-01-9 Chrysene ND 25 4.3 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 25 4.0 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
24 of 129
FA9374333.2
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:GMW-1
Lab Sample ID:FA93743-2 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
ABN Special List
CAS No.Compound Result RL MDL Units Q
132-64-9 Dibenzofuran ND 25 3.0 ug/l
91-94-1 3,3'-Dichlorobenzidine ND 25 3.2 ug/l
84-66-2 Diethyl Phthalate ND 25 5.0 ug/l
131-11-3 Dimethyl Phthalate ND 25 5.0 ug/l
84-74-2 Di-n-butyl Phthalate ND 25 5.0 ug/l
117-84-0 Di-n-octyl Phthalate b ND 25 5.0 ug/l
121-14-2 2,4-Dinitrotoluene ND 25 4.1 ug/l
606-20-2 2,6-Dinitrotoluene ND 25 3.6 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate b ND 25 5.0 ug/l
206-44-0 Fluoranthene ND 25 2.8 ug/l
86-73-7 Fluorene ND 25 3.5 ug/l
118-74-1 Hexachlorobenzene ND 25 3.5 ug/l
87-68-3 Hexachlorobutadiene ND 25 2.5 ug/l
77-47-4 Hexachlorocyclopentadiene ND 25 9.1 ug/l
67-72-1 Hexachloroethane ND 25 8.2 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 25 3.6 ug/l
78-59-1 Isophorone c ND 25 3.9 ug/l
90-12-0 1-Methylnaphthalene 10.3 25 2.6 ug/l J
91-57-6 2-Methylnaphthalene 5.1 25 3.0 ug/l J
91-20-3 Naphthalene 48.2 25 2.5 ug/l
98-95-3 Nitrobenzene ND 25 4.7 ug/l
621-64-7 N-Nitrosodi-n-propylamine ND 25 3.3 ug/l
86-30-6 N-Nitrosodiphenylamine b ND 25 4.0 ug/l
85-01-8 Phenanthrene ND 25 4.3 ug/l
129-00-0 Pyrene ND 25 3.4 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
367-12-4 2-Fluorophenol 24%14-67%
4165-62-2 Phenol-d5 18%10-50%
118-79-6 2,4,6-Tribromophenol 81%33-118%
4165-60-0 Nitrobenzene-d5 80%42-108%
321-60-8 2-Fluorobiphenyl 77%40-106%
1718-51-0 Terphenyl-d14 73%39-121%
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
590-36-3 2-Pentanol, 2-methyl-2.42 110 ug/l JN
108-88-3 Toluene 2.77 950 ug/l JN
1462-03-9 Cyclopentanol, 1-methyl-3.08 72 ug/l JN
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
25 of 129
FA9374333.2
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:GMW-1
Lab Sample ID:FA93743-2 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
ABN Special List
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
597-96-6 3-Hexanol, 3-methyl-3.64 100 ug/l JN
100-41-4 Ethylbenzene 3.82 830 ug/l JN
106-42-3 p-Xylene 3.92 1500 ug/l JN
108-38-3 Benzene, 1,3-dimethyl-4.15 400 ug/l JN
103-65-1 Benzene, propyl-4.77 70 ug/l JN
620-14-4 Benzene, 1-ethyl-3-methyl-4.84 260 ug/l JN
611-14-3 Benzene, 1-ethyl-2-methyl-4.87 190 ug/l JN
526-73-8 Benzene, 1,2,3-trimethyl-4.92 250 ug/l JN
611-14-3 Benzene, 1-ethyl-2-methyl-5.00 180 ug/l JN
108-67-8 Benzene, 1,3,5-trimethyl-5.16 750 ug/l JN
108-67-8 Benzene, 1,3,5-trimethyl-5.40 260 ug/l JN
496-11-7 Indane 5.53 310 ug/l JN
135-01-3 Benzene, 1,2-diethyl-5.62 50 ug/l JN
83-33-0 1H-Inden-1-one, 2,3-dihydro-7.47 50 ug/l JN
610-72-0 Benzoic acid, 2,5-dimethyl-7.91 75 ug/l JN
87-41-2 1(3H)-Isobenzofuranone 7.94 130 ug/l JN
Total TIC, Semi-Volatile 6537 ug/l J
(a) Dilution required due to matrix interference.
(b) Associated CCV outside of control limits high, sample was ND.
(c) Associated BS outside control limits high, sample was ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
26 of 129
FA9374333.2
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-1
Lab Sample ID:FA93743-2 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP VPH REV 2.1 Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U8983.D 20 03/16/22 14:59 JR n/a n/a G1U398
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 6930 20 20 ug/l
100-41-4 Ethylbenzene 1080 40 20 ug/l
1634-04-4 Methyl Tert Butyl Ether 56.4 40 20 ug/l
91-20-3 Naphthalene 140 100 60 ug/l
108-88-3 Toluene 1720 40 20 ug/l
m,p-Xylene 2130 80 40 ug/l
95-47-6 o-Xylene 545 40 20 ug/l
C5- C8 Aliphatics (Unadj.)8180 2000 700 ug/l
C9- C12 Aliphatics (Unadj.)1180 2000 700 ug/l J
C9- C10 Aromatics (Unadj.)2070 2000 700 ug/l
C5- C8 Aliphatics ND 2000 700 ug/l
C9- C12 Aliphatics ND 2000 700 ug/l
C9- C10 Aromatics 2070 2000 700 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 103%70-130%
460-00-4 BFB 89%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
27 of 129
FA9374333.2
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-1
Lab Sample ID:FA93743-2 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP EPH REV 2.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 NN037780.D 1 03/11/22 18:24 AF 03/10/22 12:05 OP90180 GNN1768
Run #2
Initial Volume Final Volume
Run #1 1020 ml 2.0 ml
Run #2
MAEPH List
CAS No.Compound Result RL MDL Units Q
83-32-9 Acenaphthene ND 3.9 2.0 ug/l
208-96-8 Acenaphthylene ND 3.9 2.0 ug/l
120-12-7 Anthracene ND 3.9 2.0 ug/l
56-55-3 Benzo(a)anthracene ND 3.9 2.0 ug/l
50-32-8 Benzo(a)pyrene ND 3.9 2.0 ug/l
205-99-2 Benzo(b)fluoranthene ND 3.9 2.0 ug/l
191-24-2 Benzo(g,h,i)perylene ND 3.9 2.0 ug/l
207-08-9 Benzo(k)fluoranthene ND 3.9 2.0 ug/l
218-01-9 Chrysene ND 3.9 2.0 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 3.9 2.0 ug/l
206-44-0 Fluoranthene ND 3.9 2.0 ug/l
86-73-7 Fluorene ND 3.9 2.0 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 3.9 2.0 ug/l
91-57-6 2-Methylnaphthalene 18.3 3.9 2.0 ug/l
91-20-3 Naphthalene 75.3 3.9 2.0 ug/l
85-01-8 Phenanthrene ND 3.9 2.0 ug/l
129-00-0 Pyrene ND 3.9 2.0 ug/l
C11-C22 Aromatics (Unadj.)538 200 78 ug/l
C11-C22 Aromatics 445 200 78 ug/l
C9-C18 Aliphatics ND 200 49 ug/l
C19-C36 Aliphatics ND 200 49 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
3386-33-2 1-Chlorooctadecane 54% a 40-140%
580-13-2 2-Bromonaphthalene 96%40-140%
84-15-1 o-Terphenyl 65% a 40-140%
321-60-8 2-Fluorobiphenyl 78%40-140%
(a) Surrogate recoveries corrected for double spike.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
28 of 129
FA9374333.2
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:GMW-6
Lab Sample ID:FA93743-3 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0231121.D 200 03/21/22 15:53 SS n/a n/a VA3092
Run #2 a N0124878.D 50 03/22/22 18:27 LR n/a n/a VN6437
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 2260 100 25 ug/l
108-86-1 Bromobenzene ND 100 25 ug/l
74-97-5 Bromochloromethane ND 100 25 ug/l
75-27-4 Bromodichloromethane ND 100 25 ug/l
75-25-2 Bromoform ND 100 25 ug/l
104-51-8 n-Butylbenzene ND 100 25 ug/l
135-98-8 sec-Butylbenzene ND 100 25 ug/l
98-06-6 tert-Butylbenzene ND 100 25 ug/l
56-23-5 Carbon Tetrachloride ND 100 25 ug/l
108-90-7 Chlorobenzene ND 100 25 ug/l
75-00-3 Chloroethane ND 100 40 ug/l
67-66-3 Chloroform ND 100 25 ug/l
95-49-8 o-Chlorotoluene ND 100 25 ug/l
106-43-4 p-Chlorotoluene ND 100 25 ug/l
124-48-1 Dibromochloromethane ND 100 25 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 100 49 ug/l
106-93-4 1,2-Dibromoethane ND 100 25 ug/l
75-71-8 Dichlorodifluoromethane b ND 100 40 ug/l
95-50-1 1,2-Dichlorobenzene ND 100 25 ug/l
541-73-1 1,3-Dichlorobenzene ND 100 25 ug/l
106-46-7 1,4-Dichlorobenzene ND 100 25 ug/l
75-34-3 1,1-Dichloroethane ND 100 25 ug/l
107-06-2 1,2-Dichloroethane ND 100 25 ug/l
75-35-4 1,1-Dichloroethylene c ND 100 25 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 100 25 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 100 25 ug/l
78-87-5 1,2-Dichloropropane ND 100 25 ug/l
142-28-9 1,3-Dichloropropane ND 100 25 ug/l
594-20-7 2,2-Dichloropropane ND 100 25 ug/l
563-58-6 1,1-Dichloropropene ND 100 25 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 100 25 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 100 25 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
29 of 129
FA9374333.3
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:GMW-6
Lab Sample ID:FA93743-3 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 100 25 ug/l
64-17-5 Ethyl Alcohol ND 20000 13000 ug/l
100-41-4 Ethylbenzene 447 100 25 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 100 25 ug/l
87-68-3 Hexachlorobutadiene ND 100 25 ug/l
98-82-8 Isopropylbenzene 54.7 100 25 ug/l J
99-87-6 p-Isopropyltoluene ND 100 25 ug/l
74-83-9 Methyl Bromide ND 100 40 ug/l
74-87-3 Methyl Chloride ND 100 40 ug/l
74-95-3 Methylene Bromide ND 100 25 ug/l
75-09-2 Methylene Chloride ND 400 200 ug/l
1634-04-4 Methyl Tert Butyl Ether 50.3 100 25 ug/l J
91-20-3 Naphthalene 115 100 25 ug/l
103-65-1 n-Propylbenzene 90.3 100 25 ug/l J
100-42-5 Styrene ND 100 25 ug/l
75-85-4 Tert-Amyl Alcohol 530 2000 400 ug/l J
994-05-8 Tert-Amyl Methyl Ether ND 200 40 ug/l
75-65-0 Tert-Butyl Alcohol ND 2000 400 ug/l
762-75-4 Tert-Butyl Formate ND 2000 400 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 100 25 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 100 25 ug/l
127-18-4 Tetrachloroethylene ND 100 25 ug/l
108-88-3 Toluene 451 100 25 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 100 25 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 100 25 ug/l
71-55-6 1,1,1-Trichloroethane ND 100 25 ug/l
79-00-5 1,1,2-Trichloroethane ND 100 25 ug/l
79-01-6 Trichloroethylene ND 100 25 ug/l
75-69-4 Trichlorofluoromethane b ND 100 40 ug/l
96-18-4 1,2,3-Trichloropropane ND 100 25 ug/l
95-63-6 1,2,4-Trimethylbenzene 298 100 25 ug/l
108-67-8 1,3,5-Trimethylbenzene 106 100 25 ug/l
75-01-4 Vinyl Chloride ND 100 25 ug/l
m,p-Xylene 1090 200 25 ug/l
95-47-6 o-Xylene 186 100 25 ug/l
1330-20-7 Xylene (total)1280 300 50 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 97%101%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
30 of 129
FA9374333.3
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:GMW-6
Lab Sample ID:FA93743-3 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 102%104%70-130%
2037-26-5 Toluene-D8 100%100%70-130%
460-00-4 4-Bromofluorobenzene 102%94%70-130%
(a) Internal standard areas outside method criteria. Confirmation run.
(b) Associated ECC outside of control limits high, sample was ND.
(c) Associated ECC outside control limits low.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
31 of 129
FA9374333.3
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:GMW-6
Lab Sample ID:FA93743-3 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 6F13654.D 1 03/10/22 22:09 WH 03/10/22 10:10 OP90179 S6F508
Run #2 6F13677.D 5 03/16/22 12:59 WH 03/10/22 10:10 OP90179 S6F510
Initial Volume Final Volume
Run #1 940 ml 1.0 ml
Run #2 940 ml 1.0 ml
ABN Special List
CAS No.Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 53 11 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 5.3 0.63 ug/l
95-57-8 2-Chlorophenol ND 5.3 0.67 ug/l
120-83-2 2,4-Dichlorophenol ND 5.3 0.89 ug/l
105-67-9 2,4-Dimethylphenol 17.7 5.3 0.79 ug/l
51-28-5 2,4-Dinitrophenol ND 27 5.3 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 11 2.1 ug/l
95-48-7 2-Methylphenol ND 5.3 0.59 ug/l
3&4-Methylphenol 2.2 5.3 1.0 ug/l J
88-75-5 2-Nitrophenol ND 5.3 0.91 ug/l
100-02-7 4-Nitrophenol ND 27 5.3 ug/l
87-86-5 Pentachlorophenol ND 27 5.3 ug/l
108-95-2 Phenol 4.3 5.3 0.53 ug/l J
88-06-2 2,4,6-Trichlorophenol ND 5.3 0.80 ug/l
83-32-9 Acenaphthene ND 5.3 0.67 ug/l
208-96-8 Acenaphthylene ND 5.3 0.68 ug/l
120-12-7 Anthracene ND 5.3 0.85 ug/l
56-55-3 Benzo(a)anthracene ND 5.3 0.81 ug/l
50-32-8 Benzo(a)pyrene ND 5.3 0.83 ug/l
205-99-2 Benzo(b)fluoranthene ND 5.3 0.83 ug/l
191-24-2 Benzo(g,h,i)perylene ND 5.3 0.87 ug/l
207-08-9 Benzo(k)fluoranthene ND 5.3 0.91 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 5.3 0.90 ug/l
85-68-7 Butyl Benzyl Phthalate ND 5.3 1.1 ug/l
106-47-8 4-Chloroaniline ND 5.3 0.67 ug/l
111-91-1 bis(2-Chloroethoxy)methane ND 5.3 0.86 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 5.3 0.78 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane)ND 5.3 0.81 ug/l
91-58-7 2-Chloronaphthalene ND 5.3 0.54 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether ND 5.3 0.57 ug/l
218-01-9 Chrysene ND 5.3 0.90 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 5.3 0.86 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
32 of 129
FA9374333.3
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:GMW-6
Lab Sample ID:FA93743-3 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
ABN Special List
CAS No.Compound Result RL MDL Units Q
132-64-9 Dibenzofuran ND 5.3 0.64 ug/l
91-94-1 3,3'-Dichlorobenzidine ND 5.3 0.68 ug/l
84-66-2 Diethyl Phthalate ND 5.3 1.1 ug/l
131-11-3 Dimethyl Phthalate ND 5.3 1.1 ug/l
84-74-2 Di-n-butyl Phthalate ND 5.3 1.1 ug/l
117-84-0 Di-n-octyl Phthalate a ND 5.3 1.1 ug/l
121-14-2 2,4-Dinitrotoluene ND 5.3 0.86 ug/l
606-20-2 2,6-Dinitrotoluene ND 5.3 0.76 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate a ND 5.3 1.1 ug/l
206-44-0 Fluoranthene ND 5.3 0.59 ug/l
86-73-7 Fluorene ND 5.3 0.75 ug/l
118-74-1 Hexachlorobenzene ND 5.3 0.74 ug/l
87-68-3 Hexachlorobutadiene ND 5.3 0.53 ug/l
77-47-4 Hexachlorocyclopentadiene ND 5.3 1.9 ug/l
67-72-1 Hexachloroethane ND 5.3 1.7 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 5.3 0.76 ug/l
78-59-1 Isophorone b ND 5.3 0.82 ug/l
90-12-0 1-Methylnaphthalene 13.2 5.3 0.56 ug/l
91-57-6 2-Methylnaphthalene 18.3 5.3 0.64 ug/l
91-20-3 Naphthalene 119 c 27 2.7 ug/l
98-95-3 Nitrobenzene ND 5.3 0.99 ug/l
621-64-7 N-Nitrosodi-n-propylamine ND 5.3 0.71 ug/l
86-30-6 N-Nitrosodiphenylamine a ND 5.3 0.86 ug/l
85-01-8 Phenanthrene ND 5.3 0.92 ug/l
129-00-0 Pyrene ND 5.3 0.73 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
367-12-4 2-Fluorophenol 28%26%14-67%
4165-62-2 Phenol-d5 19%18%10-50%
118-79-6 2,4,6-Tribromophenol 85%80%33-118%
4165-60-0 Nitrobenzene-d5 78%81%42-108%
321-60-8 2-Fluorobiphenyl 77%75%40-106%
1718-51-0 Terphenyl-d14 87%83%39-121%
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
590-36-3 2-Pentanol, 2-methyl-2.42 50 ug/l JN
77-74-7 3-Pentanol, 3-methyl-2.65 35 ug/l JN
108-88-3 Toluene 2.77 210 ug/l JN
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
33 of 129
FA9374333.3
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:GMW-6
Lab Sample ID:FA93743-3 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
ABN Special List
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
1462-03-9 Cyclopentanol, 1-methyl-3.08 44 ug/l JN
100-41-4 Ethylbenzene 3.82 340 ug/l JN
106-42-3 p-Xylene 3.93 820 ug/l JN
108-38-3 Benzene, 1,3-dimethyl-4.16 160 ug/l JN
98-82-8 Benzene, (1-methylethyl)-4.47 54 ug/l JN
103-65-1 Benzene, propyl-4.77 94 ug/l JN
611-14-3 Benzene, 1-ethyl-2-methyl-4.85 180 ug/l JN
611-14-3 Benzene, 1-ethyl-2-methyl- $$ Tolu 4.87 94 ug/l JN
526-73-8 Benzene, 1,2,3-trimethyl-4.93 93 ug/l JN
611-14-3 Benzene, 1-ethyl-2-methyl-5.01 73 ug/l JN
108-67-8 Benzene, 1,3,5-trimethyl-5.16 370 ug/l JN
620-14-4 Benzene, 1-ethyl-3-methyl-5.40 88 ug/l JN
496-11-7 Indane 5.53 140 ug/l JN
135-01-3 Benzene, 1,2-diethyl-5.62 26 ug/l JN
1074-43-7 Benzene, 1-methyl-3-propyl-5.65 26 ug/l JN
105-05-5 Benzene, 1,4-diethyl-5.70 82 ug/l JN
Total TIC, Semi-Volatile 2979 ug/l J
(a) Associated CCV outside of control limits high, sample was ND.
(b) Associated BS outside control limits high, sample was ND.
(c) Result is from Run# 2
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
34 of 129
FA9374333.3
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-6
Lab Sample ID:FA93743-3 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP VPH REV 2.1 Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U8982.D 1 03/16/22 14:29 JR n/a n/a G1U398
Run #2 1U8981.D 20 03/16/22 13:59 JR n/a n/a G1U398
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 2230 a 20 20 ug/l
100-41-4 Ethylbenzene 474 a 40 20 ug/l
1634-04-4 Methyl Tert Butyl Ether 48.6 2.0 1.0 ug/l
91-20-3 Naphthalene 191 5.0 3.0 ug/l
108-88-3 Toluene 364 2.0 1.0 ug/l
m,p-Xylene 1120 a 80 40 ug/l
95-47-6 o-Xylene 184 2.0 1.0 ug/l
C5- C8 Aliphatics (Unadj.)2470 a 2000 700 ug/l
C9- C12 Aliphatics (Unadj.)ND a 2000 700 ug/l
C9- C10 Aromatics (Unadj.)970 a 2000 700 ug/l J
C5- C8 Aliphatics b 495 100 35 ug/l E
C5- C8 Aliphatics ND a 2000 700 ug/l
C9- C12 Aliphatics ND 100 35 ug/l
C9- C10 Aromatics 970 a 2000 700 ug/l J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 112%96%70-130%
460-00-4 BFB 89%82%70-130%
(a) Result is from Run# 2
(b) Compound below calibration range in higher dilution.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
35 of 129
FA9374333.3
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-6
Lab Sample ID:FA93743-3 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP EPH REV 2.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 NN037781.D 1 03/11/22 18:54 AF 03/10/22 12:05 OP90180 GNN1768
Run #2
Initial Volume Final Volume
Run #1 1040 ml 2.0 ml
Run #2
MAEPH List
CAS No.Compound Result RL MDL Units Q
83-32-9 Acenaphthene ND 3.8 1.9 ug/l
208-96-8 Acenaphthylene ND 3.8 1.9 ug/l
120-12-7 Anthracene ND 3.8 1.9 ug/l
56-55-3 Benzo(a)anthracene ND 3.8 1.9 ug/l
50-32-8 Benzo(a)pyrene ND 3.8 1.9 ug/l
205-99-2 Benzo(b)fluoranthene ND 3.8 1.9 ug/l
191-24-2 Benzo(g,h,i)perylene ND 3.8 1.9 ug/l
207-08-9 Benzo(k)fluoranthene ND 3.8 1.9 ug/l
218-01-9 Chrysene ND 3.8 1.9 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 3.8 1.9 ug/l
206-44-0 Fluoranthene ND 3.8 1.9 ug/l
86-73-7 Fluorene ND 3.8 1.9 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 3.8 1.9 ug/l
91-57-6 2-Methylnaphthalene 13.2 3.8 1.9 ug/l
91-20-3 Naphthalene 97.2 3.8 1.9 ug/l
85-01-8 Phenanthrene ND 3.8 1.9 ug/l
129-00-0 Pyrene ND 3.8 1.9 ug/l
C11-C22 Aromatics (Unadj.)368 190 77 ug/l
C11-C22 Aromatics 257 190 77 ug/l
C9-C18 Aliphatics ND 190 48 ug/l
C19-C36 Aliphatics ND 190 48 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
3386-33-2 1-Chlorooctadecane 60% a 40-140%
580-13-2 2-Bromonaphthalene 108%40-140%
84-15-1 o-Terphenyl 85% a 40-140%
321-60-8 2-Fluorobiphenyl 92%40-140%
(a) Surrogate recoveries corrected for double spike.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
36 of 129
FA9374333.3
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:GMW-2
Lab Sample ID:FA93743-4 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0231122.D 50 03/21/22 16:16 SS n/a n/a VA3092
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene a 3480 25 6.3 ug/l E
108-86-1 Bromobenzene ND 25 6.3 ug/l
74-97-5 Bromochloromethane ND 25 6.3 ug/l
75-27-4 Bromodichloromethane ND 25 6.3 ug/l
75-25-2 Bromoform ND 25 6.3 ug/l
104-51-8 n-Butylbenzene ND 25 6.3 ug/l
135-98-8 sec-Butylbenzene ND 25 6.3 ug/l
98-06-6 tert-Butylbenzene ND 25 6.3 ug/l
56-23-5 Carbon Tetrachloride ND 25 6.3 ug/l
108-90-7 Chlorobenzene ND 25 6.3 ug/l
75-00-3 Chloroethane ND 25 10 ug/l
67-66-3 Chloroform ND 25 6.3 ug/l
95-49-8 o-Chlorotoluene ND 25 6.3 ug/l
106-43-4 p-Chlorotoluene ND 25 6.3 ug/l
124-48-1 Dibromochloromethane ND 25 6.3 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 25 12 ug/l
106-93-4 1,2-Dibromoethane ND 25 6.3 ug/l
75-71-8 Dichlorodifluoromethane b ND 25 10 ug/l
95-50-1 1,2-Dichlorobenzene ND 25 6.3 ug/l
541-73-1 1,3-Dichlorobenzene ND 25 6.3 ug/l
106-46-7 1,4-Dichlorobenzene ND 25 6.3 ug/l
75-34-3 1,1-Dichloroethane ND 25 6.3 ug/l
107-06-2 1,2-Dichloroethane ND 25 6.3 ug/l
75-35-4 1,1-Dichloroethylene c ND 25 6.3 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 25 6.3 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 25 6.3 ug/l
78-87-5 1,2-Dichloropropane ND 25 6.3 ug/l
142-28-9 1,3-Dichloropropane ND 25 6.3 ug/l
594-20-7 2,2-Dichloropropane ND 25 6.3 ug/l
563-58-6 1,1-Dichloropropene ND 25 6.3 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 25 6.3 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 25 6.3 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
37 of 129
FA9374333.4
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:GMW-2
Lab Sample ID:FA93743-4 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 11.7 25 6.3 ug/l J
64-17-5 Ethyl Alcohol ND 5000 3300 ug/l
100-41-4 Ethylbenzene 253 25 6.3 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 25 6.3 ug/l
87-68-3 Hexachlorobutadiene ND 25 6.3 ug/l
98-82-8 Isopropylbenzene 23.6 25 6.3 ug/l J
99-87-6 p-Isopropyltoluene ND 25 6.3 ug/l
74-83-9 Methyl Bromide ND 25 10 ug/l
74-87-3 Methyl Chloride 17.6 25 10 ug/l J
74-95-3 Methylene Bromide ND 25 6.3 ug/l
75-09-2 Methylene Chloride ND 100 50 ug/l
1634-04-4 Methyl Tert Butyl Ether 12.8 25 6.3 ug/l J
91-20-3 Naphthalene 91.7 25 6.3 ug/l
103-65-1 n-Propylbenzene 49.0 25 6.3 ug/l
100-42-5 Styrene ND 25 6.3 ug/l
75-85-4 Tert-Amyl Alcohol 599 500 100 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 50 10 ug/l
75-65-0 Tert-Butyl Alcohol 526 500 100 ug/l
762-75-4 Tert-Butyl Formate ND 500 100 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 25 6.3 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 25 6.3 ug/l
127-18-4 Tetrachloroethylene ND 25 6.3 ug/l
108-88-3 Toluene 66.5 25 6.3 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 25 6.3 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 25 6.3 ug/l
71-55-6 1,1,1-Trichloroethane ND 25 6.3 ug/l
79-00-5 1,1,2-Trichloroethane ND 25 6.3 ug/l
79-01-6 Trichloroethylene ND 25 6.3 ug/l
75-69-4 Trichlorofluoromethane b ND 25 10 ug/l
96-18-4 1,2,3-Trichloropropane ND 25 6.3 ug/l
95-63-6 1,2,4-Trimethylbenzene 38.9 25 6.3 ug/l
108-67-8 1,3,5-Trimethylbenzene 23.1 25 6.3 ug/l J
75-01-4 Vinyl Chloride ND 25 6.3 ug/l
m,p-Xylene 113 50 6.3 ug/l
95-47-6 o-Xylene 18.9 25 6.3 ug/l J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 95%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
38 of 129
FA9374333.4
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:GMW-2
Lab Sample ID:FA93743-4 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 103%70-130%
(a) Insufficient sample available for reanalysis.
(b) Associated ECC outside of control limits high, sample was ND.
(c) Associated ECC outside control limits low.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
39 of 129
FA9374333.4
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:GMW-2
Lab Sample ID:FA93743-4 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 6F13655.D 1 03/10/22 22:34 WH 03/10/22 10:10 OP90179 S6F508
Run #2
Initial Volume Final Volume
Run #1 1040 ml 1.0 ml
Run #2
ABN Special List
CAS No.Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 48 9.6 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 4.8 0.57 ug/l
95-57-8 2-Chlorophenol ND 4.8 0.61 ug/l
120-83-2 2,4-Dichlorophenol ND 4.8 0.80 ug/l
105-67-9 2,4-Dimethylphenol 2.6 4.8 0.71 ug/l J
51-28-5 2,4-Dinitrophenol ND 24 4.8 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 9.6 1.9 ug/l
95-48-7 2-Methylphenol ND 4.8 0.54 ug/l
3&4-Methylphenol ND 4.8 0.94 ug/l
88-75-5 2-Nitrophenol ND 4.8 0.82 ug/l
100-02-7 4-Nitrophenol ND 24 4.8 ug/l
87-86-5 Pentachlorophenol ND 24 4.8 ug/l
108-95-2 Phenol ND 4.8 0.48 ug/l
88-06-2 2,4,6-Trichlorophenol ND 4.8 0.72 ug/l
83-32-9 Acenaphthene 1.0 4.8 0.60 ug/l J
208-96-8 Acenaphthylene ND 4.8 0.61 ug/l
120-12-7 Anthracene ND 4.8 0.77 ug/l
56-55-3 Benzo(a)anthracene ND 4.8 0.73 ug/l
50-32-8 Benzo(a)pyrene ND 4.8 0.75 ug/l
205-99-2 Benzo(b)fluoranthene ND 4.8 0.75 ug/l
191-24-2 Benzo(g,h,i)perylene ND 4.8 0.79 ug/l
207-08-9 Benzo(k)fluoranthene ND 4.8 0.82 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 4.8 0.81 ug/l
85-68-7 Butyl Benzyl Phthalate ND 4.8 0.96 ug/l
106-47-8 4-Chloroaniline ND 4.8 0.61 ug/l
111-91-1 bis(2-Chloroethoxy)methane ND 4.8 0.78 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 4.8 0.70 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane)ND 4.8 0.73 ug/l
91-58-7 2-Chloronaphthalene ND 4.8 0.48 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether ND 4.8 0.52 ug/l
218-01-9 Chrysene ND 4.8 0.82 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 4.8 0.77 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
40 of 129
FA9374333.4
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:GMW-2
Lab Sample ID:FA93743-4 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
ABN Special List
CAS No.Compound Result RL MDL Units Q
132-64-9 Dibenzofuran 0.69 4.8 0.58 ug/l J
91-94-1 3,3'-Dichlorobenzidine ND 4.8 0.62 ug/l
84-66-2 Diethyl Phthalate ND 4.8 0.96 ug/l
131-11-3 Dimethyl Phthalate ND 4.8 0.96 ug/l
84-74-2 Di-n-butyl Phthalate ND 4.8 0.96 ug/l
117-84-0 Di-n-octyl Phthalate a ND 4.8 0.96 ug/l
121-14-2 2,4-Dinitrotoluene ND 4.8 0.78 ug/l
606-20-2 2,6-Dinitrotoluene ND 4.8 0.69 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate a ND 4.8 0.96 ug/l
206-44-0 Fluoranthene ND 4.8 0.53 ug/l
86-73-7 Fluorene 1.4 4.8 0.67 ug/l J
118-74-1 Hexachlorobenzene ND 4.8 0.67 ug/l
87-68-3 Hexachlorobutadiene ND 4.8 0.48 ug/l
77-47-4 Hexachlorocyclopentadiene ND 4.8 1.7 ug/l
67-72-1 Hexachloroethane ND 4.8 1.6 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 4.8 0.69 ug/l
78-59-1 Isophorone b ND 4.8 0.75 ug/l
90-12-0 1-Methylnaphthalene 37.8 4.8 0.50 ug/l
91-57-6 2-Methylnaphthalene 49.0 4.8 0.58 ug/l
91-20-3 Naphthalene 78.0 4.8 0.48 ug/l
98-95-3 Nitrobenzene ND 4.8 0.90 ug/l
621-64-7 N-Nitrosodi-n-propylamine ND 4.8 0.64 ug/l
86-30-6 N-Nitrosodiphenylamine a ND 4.8 0.78 ug/l
85-01-8 Phenanthrene ND 4.8 0.83 ug/l
129-00-0 Pyrene ND 4.8 0.66 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
367-12-4 2-Fluorophenol 24%14-67%
4165-62-2 Phenol-d5 18%10-50%
118-79-6 2,4,6-Tribromophenol 81%33-118%
4165-60-0 Nitrobenzene-d5 76%42-108%
321-60-8 2-Fluorobiphenyl 74%40-106%
1718-51-0 Terphenyl-d14 62%39-121%
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
590-36-3 2-Pentanol, 2-methyl-2.42 34 ug/l JN
77-74-7 3-Pentanol, 3-methyl-2.65 26 ug/l JN
108-88-3 Toluene 2.76 27 ug/l JN
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
41 of 129
FA9374333.4
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:GMW-2
Lab Sample ID:FA93743-4 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
ABN Special List
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
1462-03-9 Cyclopentanol, 1-methyl-3.08 30 ug/l JN
100-41-4 Ethylbenzene 3.82 170 ug/l JN
106-42-3 p-Xylene 3.93 66 ug/l JN
108-38-3 Benzene, 1,3-dimethyl-4.15 13 ug/l JN
98-82-8 Benzene, (1-methylethyl)-4.47 24 ug/l JN
103-65-1 Benzene, propyl-4.77 44 ug/l JN
108-67-8 Benzene, 1,3,5-trimethyl-4.92 19 ug/l JN
611-14-3 Benzene, 1-ethyl-2-methyl-5.00 15 ug/l JN
526-73-8 Benzene, 1,2,3-trimethyl-5.15 40 ug/l JN
496-11-7 Indane 5.53 150 ug/l JN
135-01-3 Benzene, 1,2-diethyl-5.62 24 ug/l JN
535-77-3 Benzene, 1-methyl-3-(1-methylethyl)-5.70 34 ug/l JN
95-93-2 Benzene, 1,2,4,5-tetramethyl-6.21 16 ug/l JN
768-49-0 Benzene, (2-methyl-1-propenyl)-6.40 21 ug/l JN
632-46-2 Benzoic acid, 2,6-dimethyl-7.93 13 ug/l JN
581-40-8 Naphthalene, 2,3-dimethyl-8.42 16 ug/l JN
Total TIC, Semi-Volatile 782 ug/l J
(a) Associated CCV outside of control limits high, sample was ND.
(b) Associated BS outside control limits high, sample was ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
42 of 129
FA9374333.4
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-2
Lab Sample ID:FA93743-4 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP VPH REV 2.1 Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U9070.D 1 03/18/22 11:16 JR n/a n/a G1U400
Run #2 1U9081.D 10 03/18/22 17:05 JR n/a n/a G1U401
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 3080 a 10 10 ug/l
100-41-4 Ethylbenzene 251 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 2.0 1.0 ug/l
91-20-3 Naphthalene 120 5.0 3.0 ug/l
108-88-3 Toluene 58.1 2.0 1.0 ug/l
m,p-Xylene 118 4.0 2.0 ug/l
95-47-6 o-Xylene 23.5 2.0 1.0 ug/l
C5- C8 Aliphatics (Unadj.)3120 a 1000 350 ug/l
C9- C12 Aliphatics (Unadj.) b 37.7 100 35 ug/l EJ
C9- C10 Aromatics (Unadj.)365 a 1000 350 ug/l J
C5- C8 Aliphatics b 1320 100 35 ug/l E
C9- C12 Aliphatics ND 100 35 ug/l
C9- C10 Aromatics 365 a 1000 350 ug/l J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 116%92%70-130%
460-00-4 BFB 98%81%70-130%
(a) Result is from Run# 2
(b) Compound below calibration range in higher dilution.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
43 of 129
FA9374333.4
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-2
Lab Sample ID:FA93743-4 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP EPH REV 2.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 NN037782.D 1 03/11/22 19:23 AF 03/10/22 12:05 OP90180 GNN1768
Run #2
Initial Volume Final Volume
Run #1 1050 ml 2.0 ml
Run #2
MAEPH List
CAS No.Compound Result RL MDL Units Q
83-32-9 Acenaphthene ND 3.8 1.9 ug/l
208-96-8 Acenaphthylene ND 3.8 1.9 ug/l
120-12-7 Anthracene ND 3.8 1.9 ug/l
56-55-3 Benzo(a)anthracene ND 3.8 1.9 ug/l
50-32-8 Benzo(a)pyrene ND 3.8 1.9 ug/l
205-99-2 Benzo(b)fluoranthene ND 3.8 1.9 ug/l
191-24-2 Benzo(g,h,i)perylene ND 3.8 1.9 ug/l
207-08-9 Benzo(k)fluoranthene ND 3.8 1.9 ug/l
218-01-9 Chrysene ND 3.8 1.9 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 3.8 1.9 ug/l
206-44-0 Fluoranthene ND 3.8 1.9 ug/l
86-73-7 Fluorene ND 3.8 1.9 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 3.8 1.9 ug/l
91-57-6 2-Methylnaphthalene 40.4 3.8 1.9 ug/l
91-20-3 Naphthalene 76.6 3.8 1.9 ug/l
85-01-8 Phenanthrene ND 3.8 1.9 ug/l
129-00-0 Pyrene ND 3.8 1.9 ug/l
C11-C22 Aromatics (Unadj.)455 190 76 ug/l
C11-C22 Aromatics 338 190 76 ug/l
C9-C18 Aliphatics ND 190 48 ug/l
C19-C36 Aliphatics ND 190 48 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
3386-33-2 1-Chlorooctadecane 56% a 40-140%
580-13-2 2-Bromonaphthalene 107%40-140%
84-15-1 o-Terphenyl 90% a 40-140%
321-60-8 2-Fluorobiphenyl 102%40-140%
(a) Surrogate recoveries corrected for double spike.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
44 of 129
FA9374333.4
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:GMW-5
Lab Sample ID:FA93743-5 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0231123.D 100 03/21/22 16:39 SS n/a n/a VA3092
Run #2 a N0124880.D 2 03/22/22 19:14 LR n/a n/a VN6437
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 43.5 50 13 ug/l J
108-86-1 Bromobenzene ND 50 13 ug/l
74-97-5 Bromochloromethane ND 50 13 ug/l
75-27-4 Bromodichloromethane ND 50 13 ug/l
75-25-2 Bromoform ND 50 13 ug/l
104-51-8 n-Butylbenzene ND 50 13 ug/l
135-98-8 sec-Butylbenzene ND 50 13 ug/l
98-06-6 tert-Butylbenzene ND 50 13 ug/l
56-23-5 Carbon Tetrachloride ND 50 13 ug/l
108-90-7 Chlorobenzene ND 50 13 ug/l
75-00-3 Chloroethane ND 50 20 ug/l
67-66-3 Chloroform ND 50 13 ug/l
95-49-8 o-Chlorotoluene ND 50 13 ug/l
106-43-4 p-Chlorotoluene ND 50 13 ug/l
124-48-1 Dibromochloromethane ND 50 13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 50 25 ug/l
106-93-4 1,2-Dibromoethane ND 50 13 ug/l
75-71-8 Dichlorodifluoromethane b ND 50 20 ug/l
95-50-1 1,2-Dichlorobenzene ND 50 13 ug/l
541-73-1 1,3-Dichlorobenzene ND 50 13 ug/l
106-46-7 1,4-Dichlorobenzene ND 50 13 ug/l
75-34-3 1,1-Dichloroethane ND 50 13 ug/l
107-06-2 1,2-Dichloroethane ND 50 13 ug/l
75-35-4 1,1-Dichloroethylene c ND 50 13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 50 13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 50 13 ug/l
78-87-5 1,2-Dichloropropane ND 50 13 ug/l
142-28-9 1,3-Dichloropropane ND 50 13 ug/l
594-20-7 2,2-Dichloropropane ND 50 13 ug/l
563-58-6 1,1-Dichloropropene ND 50 13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 50 13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 50 13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
45 of 129
FA9374333.5
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:GMW-5
Lab Sample ID:FA93743-5 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 50 13 ug/l
64-17-5 Ethyl Alcohol ND 10000 6500 ug/l
100-41-4 Ethylbenzene 56.4 50 13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 50 13 ug/l
87-68-3 Hexachlorobutadiene ND 50 13 ug/l
98-82-8 Isopropylbenzene ND 50 13 ug/l
99-87-6 p-Isopropyltoluene ND 50 13 ug/l
74-83-9 Methyl Bromide ND 50 20 ug/l
74-87-3 Methyl Chloride ND 50 20 ug/l
74-95-3 Methylene Bromide ND 50 13 ug/l
75-09-2 Methylene Chloride ND 200 100 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 50 13 ug/l
91-20-3 Naphthalene ND 50 13 ug/l
103-65-1 n-Propylbenzene ND 50 13 ug/l
100-42-5 Styrene ND 50 13 ug/l
75-85-4 Tert-Amyl Alcohol ND 1000 200 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 100 20 ug/l
75-65-0 Tert-Butyl Alcohol ND 1000 200 ug/l
762-75-4 Tert-Butyl Formate ND 1000 200 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 50 13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 50 13 ug/l
127-18-4 Tetrachloroethylene ND 50 13 ug/l
108-88-3 Toluene ND 50 13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 50 13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 50 13 ug/l
71-55-6 1,1,1-Trichloroethane ND 50 13 ug/l
79-00-5 1,1,2-Trichloroethane ND 50 13 ug/l
79-01-6 Trichloroethylene ND 50 13 ug/l
75-69-4 Trichlorofluoromethane b ND 50 20 ug/l
96-18-4 1,2,3-Trichloropropane ND 50 13 ug/l
95-63-6 1,2,4-Trimethylbenzene 37.9 50 13 ug/l J
108-67-8 1,3,5-Trimethylbenzene 18.9 50 13 ug/l J
75-01-4 Vinyl Chloride ND 50 13 ug/l
m,p-Xylene 74.2 100 13 ug/l J
95-47-6 o-Xylene ND 50 13 ug/l
1330-20-7 Xylene (total)74.2 150 25 ug/l J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 98%104%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
46 of 129
FA9374333.5
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:GMW-5
Lab Sample ID:FA93743-5 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 103%106%70-130%
2037-26-5 Toluene-D8 101%100%70-130%
460-00-4 4-Bromofluorobenzene 102%95%70-130%
(a) Internal standard areas outside method criteria. Confirmation run.
(b) Associated ECC outside of control limits high, sample was ND.
(c) Associated ECC outside control limits low.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
47 of 129
FA9374333.5
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:GMW-5
Lab Sample ID:FA93743-5 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 6F13656.D 1 03/10/22 22:59 WH 03/10/22 10:10 OP90179 S6F508
Run #2
Initial Volume Final Volume
Run #1 960 ml 1.0 ml
Run #2
ABN Special List
CAS No.Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 52 10 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 5.2 0.62 ug/l
95-57-8 2-Chlorophenol ND 5.2 0.66 ug/l
120-83-2 2,4-Dichlorophenol ND 5.2 0.87 ug/l
105-67-9 2,4-Dimethylphenol 1.3 5.2 0.77 ug/l J
51-28-5 2,4-Dinitrophenol ND 26 5.2 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 10 2.1 ug/l
95-48-7 2-Methylphenol ND 5.2 0.58 ug/l
3&4-Methylphenol ND 5.2 1.0 ug/l
88-75-5 2-Nitrophenol ND 5.2 0.89 ug/l
100-02-7 4-Nitrophenol ND 26 5.2 ug/l
87-86-5 Pentachlorophenol ND 26 5.2 ug/l
108-95-2 Phenol ND 5.2 0.52 ug/l
88-06-2 2,4,6-Trichlorophenol ND 5.2 0.78 ug/l
83-32-9 Acenaphthene ND 5.2 0.65 ug/l
208-96-8 Acenaphthylene ND 5.2 0.66 ug/l
120-12-7 Anthracene ND 5.2 0.83 ug/l
56-55-3 Benzo(a)anthracene ND 5.2 0.79 ug/l
50-32-8 Benzo(a)pyrene ND 5.2 0.82 ug/l
205-99-2 Benzo(b)fluoranthene ND 5.2 0.81 ug/l
191-24-2 Benzo(g,h,i)perylene ND 5.2 0.86 ug/l
207-08-9 Benzo(k)fluoranthene ND 5.2 0.89 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 5.2 0.88 ug/l
85-68-7 Butyl Benzyl Phthalate ND 5.2 1.0 ug/l
106-47-8 4-Chloroaniline ND 5.2 0.66 ug/l
111-91-1 bis(2-Chloroethoxy)methane ND 5.2 0.84 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 5.2 0.76 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane)ND 5.2 0.79 ug/l
91-58-7 2-Chloronaphthalene ND 5.2 0.53 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether ND 5.2 0.56 ug/l
218-01-9 Chrysene ND 5.2 0.89 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 5.2 0.84 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
48 of 129
FA9374333.5
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:GMW-5
Lab Sample ID:FA93743-5 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
ABN Special List
CAS No.Compound Result RL MDL Units Q
132-64-9 Dibenzofuran ND 5.2 0.63 ug/l
91-94-1 3,3'-Dichlorobenzidine ND 5.2 0.67 ug/l
84-66-2 Diethyl Phthalate ND 5.2 1.0 ug/l
131-11-3 Dimethyl Phthalate ND 5.2 1.0 ug/l
84-74-2 Di-n-butyl Phthalate ND 5.2 1.0 ug/l
117-84-0 Di-n-octyl Phthalate a ND 5.2 1.0 ug/l
121-14-2 2,4-Dinitrotoluene ND 5.2 0.85 ug/l
606-20-2 2,6-Dinitrotoluene ND 5.2 0.74 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate a ND 5.2 1.0 ug/l
206-44-0 Fluoranthene ND 5.2 0.58 ug/l
86-73-7 Fluorene 1.9 5.2 0.73 ug/l J
118-74-1 Hexachlorobenzene ND 5.2 0.72 ug/l
87-68-3 Hexachlorobutadiene ND 5.2 0.52 ug/l
77-47-4 Hexachlorocyclopentadiene ND 5.2 1.9 ug/l
67-72-1 Hexachloroethane ND 5.2 1.7 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 5.2 0.74 ug/l
78-59-1 Isophorone b ND 5.2 0.81 ug/l
90-12-0 1-Methylnaphthalene 1.4 5.2 0.55 ug/l J
91-57-6 2-Methylnaphthalene 2.6 5.2 0.63 ug/l J
91-20-3 Naphthalene 5.8 5.2 0.52 ug/l
98-95-3 Nitrobenzene ND 5.2 0.97 ug/l
621-64-7 N-Nitrosodi-n-propylamine ND 5.2 0.70 ug/l
86-30-6 N-Nitrosodiphenylamine a ND 5.2 0.84 ug/l
85-01-8 Phenanthrene ND 5.2 0.90 ug/l
129-00-0 Pyrene ND 5.2 0.71 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
367-12-4 2-Fluorophenol 33%14-67%
4165-62-2 Phenol-d5 32%10-50%
118-79-6 2,4,6-Tribromophenol 87%33-118%
4165-60-0 Nitrobenzene-d5 83%42-108%
321-60-8 2-Fluorobiphenyl 81%40-106%
1718-51-0 Terphenyl-d14 85%39-121%
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
594-60-5 2-Butanol, 2,3-dimethyl-2.40 13 ug/l JN
1462-03-9 Cyclopentanol, 1-methyl-3.08 17 ug/l JN
19550-46-0 1,3-Dimethyl cyclopentanol 3.65 11 ug/l JN
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
49 of 129
FA9374333.5
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:GMW-5
Lab Sample ID:FA93743-5 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
ABN Special List
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
100-41-4 Ethylbenzene 3.82 58 ug/l JN
108-38-3 Benzene, 1,3-dimethyl-3.93 79 ug/l JN
98-82-8 Benzene, (1-methylethyl)-4.47 12 ug/l JN
103-65-1 Benzene, propyl-4.77 26 ug/l JN
620-14-4 Benzene, 1-ethyl-3-methyl-4.84 34 ug/l JN
611-14-3 Benzene, 1-ethyl-2-methyl-4.87 26 ug/l JN
526-73-8 Benzene, 1,2,3-trimethyl-4.92 27 ug/l JN
611-14-3 Benzene, 1-ethyl-2-methyl-5.00 20 ug/l JN
108-67-8 Benzene, 1,3,5-trimethyl-5.16 82 ug/l JN
620-14-4 Benzene, 1-ethyl-3-methyl-5.40 21 ug/l JN
496-11-7 Indane 5.53 16 ug/l JN
135-01-3 Benzene, 1,2-diethyl-5.62 21 ug/l JN
1074-17-5 Benzene, 1-methyl-2-propyl-5.65 13 ug/l JN
135-01-3 Benzene, 1,2-diethyl-5.70 40 ug/l JN
768-49-0 Benzene, (2-methyl-1-propenyl)-6.40 8.8 ug/l JN
Total TIC, Semi-Volatile 524.8 ug/l J
(a) Associated CCV outside of control limits high, sample was ND.
(b) Associated BS outside control limits high, sample was ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
50 of 129
FA9374333.5
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-5
Lab Sample ID:FA93743-5 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP VPH REV 2.1 Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U8985.D 1 03/16/22 16:00 JR n/a n/a G1U398
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 39.3 1.0 1.0 ug/l
100-41-4 Ethylbenzene 60.1 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 2.0 1.0 ug/l
91-20-3 Naphthalene 10.5 5.0 3.0 ug/l
108-88-3 Toluene 11.0 2.0 1.0 ug/l
m,p-Xylene 86.6 4.0 2.0 ug/l
95-47-6 o-Xylene 10.0 2.0 1.0 ug/l
C5- C8 Aliphatics (Unadj.)371 100 35 ug/l
C9- C12 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C10 Aromatics (Unadj.)206 100 35 ug/l
C5- C8 Aliphatics 321 100 35 ug/l
C9- C12 Aliphatics ND 100 35 ug/l
C9- C10 Aromatics 206 100 35 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 103%70-130%
460-00-4 BFB 98%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
51 of 129
FA9374333.5
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-5
Lab Sample ID:FA93743-5 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP EPH REV 2.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 NN037783.D 1 03/11/22 19:53 AF 03/10/22 12:05 OP90180 GNN1768
Run #2
Initial Volume Final Volume
Run #1 980 ml 2.0 ml
Run #2
MAEPH List
CAS No.Compound Result RL MDL Units Q
83-32-9 Acenaphthene ND 4.1 2.0 ug/l
208-96-8 Acenaphthylene ND 4.1 2.0 ug/l
120-12-7 Anthracene ND 4.1 2.0 ug/l
56-55-3 Benzo(a)anthracene ND 4.1 2.0 ug/l
50-32-8 Benzo(a)pyrene ND 4.1 2.0 ug/l
205-99-2 Benzo(b)fluoranthene ND 4.1 2.0 ug/l
191-24-2 Benzo(g,h,i)perylene ND 4.1 2.0 ug/l
207-08-9 Benzo(k)fluoranthene ND 4.1 2.0 ug/l
218-01-9 Chrysene ND 4.1 2.0 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 4.1 2.0 ug/l
206-44-0 Fluoranthene ND 4.1 2.0 ug/l
86-73-7 Fluorene ND 4.1 2.0 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 4.1 2.0 ug/l
91-57-6 2-Methylnaphthalene ND 4.1 2.0 ug/l
91-20-3 Naphthalene 6.0 4.1 2.0 ug/l
85-01-8 Phenanthrene ND 4.1 2.0 ug/l
129-00-0 Pyrene ND 4.1 2.0 ug/l
C11-C22 Aromatics (Unadj.)151 200 82 ug/l J
C11-C22 Aromatics 145 200 82 ug/l J
C9-C18 Aliphatics ND 200 51 ug/l
C19-C36 Aliphatics ND 200 51 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
3386-33-2 1-Chlorooctadecane 56% a 40-140%
580-13-2 2-Bromonaphthalene 80%40-140%
84-15-1 o-Terphenyl 69% a 40-140%
321-60-8 2-Fluorobiphenyl 76%40-140%
(a) Surrogate recoveries corrected for double spike.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
52 of 129
FA9374333.5
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:GMW-3
Lab Sample ID:FA93743-6 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0231128.D 1 03/21/22 18:34 SS n/a n/a VA3092
Run #2 a N0124879.D 50 03/22/22 18:51 LR n/a n/a VN6437
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 1440 b 25 6.3 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene 6.6 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene 14.4 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene 1.7 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene 0.31 0.50 0.13 ug/l J
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane c ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene d ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene 0.71 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
53 of 129
FA9374333.6
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:GMW-3
Lab Sample ID:FA93743-6 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 8.3 0.50 0.13 ug/l
64-17-5 Ethyl Alcohol ND 100 65 ug/l
100-41-4 Ethylbenzene 92.8 b 25 6.3 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 58.7 b 25 6.3 ug/l
99-87-6 p-Isopropyltoluene 0.38 0.50 0.13 ug/l J
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride 9.3 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 33.4 0.50 0.13 ug/l
91-20-3 Naphthalene 21.1 0.50 0.13 ug/l
103-65-1 n-Propylbenzene 128 b 25 6.3 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol 283 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol 262 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 11.2 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane c ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene 47.2 b 25 6.3 ug/l
108-67-8 1,3,5-Trimethylbenzene 1.7 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 59.4 1.0 0.13 ug/l
95-47-6 o-Xylene 3.3 0.50 0.13 ug/l
1330-20-7 Xylene (total)62.7 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 97%102%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
54 of 129
FA9374333.6
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:GMW-3
Lab Sample ID:FA93743-6 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 99%105%70-130%
2037-26-5 Toluene-D8 95%100%70-130%
460-00-4 4-Bromofluorobenzene 107%94%70-130%
(a) Internal standard areas outside method criteria.
(b) Result is from Run# 2
(c) Associated ECC outside of control limits high, sample was ND.
(d) Associated ECC outside control limits low.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
55 of 129
FA9374333.6
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:GMW-3
Lab Sample ID:FA93743-6 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 6F13657.D 5 03/10/22 23:24 WH 03/10/22 10:10 OP90179 S6F508
Run #2
Initial Volume Final Volume
Run #1 1020 ml 1.0 ml
Run #2
ABN Special List
CAS No.Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 250 49 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 25 2.9 ug/l
95-57-8 2-Chlorophenol ND 25 3.1 ug/l
120-83-2 2,4-Dichlorophenol ND 25 4.1 ug/l
105-67-9 2,4-Dimethylphenol ND 25 3.6 ug/l
51-28-5 2,4-Dinitrophenol ND 120 25 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 49 9.8 ug/l
95-48-7 2-Methylphenol ND 25 2.7 ug/l
3&4-Methylphenol ND 25 4.8 ug/l
88-75-5 2-Nitrophenol ND 25 4.2 ug/l
100-02-7 4-Nitrophenol ND 120 25 ug/l
87-86-5 Pentachlorophenol ND 120 25 ug/l
108-95-2 Phenol 3.3 25 2.5 ug/l J
88-06-2 2,4,6-Trichlorophenol ND 25 3.7 ug/l
83-32-9 Acenaphthene ND 25 3.1 ug/l
208-96-8 Acenaphthylene ND 25 3.1 ug/l
120-12-7 Anthracene ND 25 3.9 ug/l
56-55-3 Benzo(a)anthracene ND 25 3.7 ug/l
50-32-8 Benzo(a)pyrene ND 25 3.8 ug/l
205-99-2 Benzo(b)fluoranthene ND 25 3.8 ug/l
191-24-2 Benzo(g,h,i)perylene ND 25 4.0 ug/l
207-08-9 Benzo(k)fluoranthene ND 25 4.2 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 25 4.2 ug/l
85-68-7 Butyl Benzyl Phthalate ND 25 4.9 ug/l
106-47-8 4-Chloroaniline ND 25 3.1 ug/l
111-91-1 bis(2-Chloroethoxy)methane ND 25 4.0 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 25 3.6 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane)ND 25 3.7 ug/l
91-58-7 2-Chloronaphthalene ND 25 2.5 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether ND 25 2.6 ug/l
218-01-9 Chrysene ND 25 4.2 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 25 3.9 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
56 of 129
FA9374333.6
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:GMW-3
Lab Sample ID:FA93743-6 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
ABN Special List
CAS No.Compound Result RL MDL Units Q
132-64-9 Dibenzofuran ND 25 2.9 ug/l
91-94-1 3,3'-Dichlorobenzidine ND 25 3.2 ug/l
84-66-2 Diethyl Phthalate ND 25 4.9 ug/l
131-11-3 Dimethyl Phthalate ND 25 4.9 ug/l
84-74-2 Di-n-butyl Phthalate ND 25 4.9 ug/l
117-84-0 Di-n-octyl Phthalate b ND 25 4.9 ug/l
121-14-2 2,4-Dinitrotoluene ND 25 4.0 ug/l
606-20-2 2,6-Dinitrotoluene ND 25 3.5 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate b ND 25 4.9 ug/l
206-44-0 Fluoranthene ND 25 2.7 ug/l
86-73-7 Fluorene 3.5 25 3.4 ug/l J
118-74-1 Hexachlorobenzene ND 25 3.4 ug/l
87-68-3 Hexachlorobutadiene ND 25 2.5 ug/l
77-47-4 Hexachlorocyclopentadiene ND 25 8.9 ug/l
67-72-1 Hexachloroethane ND 25 8.0 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 25 3.5 ug/l
78-59-1 Isophorone c ND 25 3.8 ug/l
90-12-0 1-Methylnaphthalene 71.1 25 2.6 ug/l
91-57-6 2-Methylnaphthalene 57.7 25 2.9 ug/l
91-20-3 Naphthalene 20.3 25 2.5 ug/l J
98-95-3 Nitrobenzene ND 25 4.6 ug/l
621-64-7 N-Nitrosodi-n-propylamine ND 25 3.3 ug/l
86-30-6 N-Nitrosodiphenylamine b ND 25 4.0 ug/l
85-01-8 Phenanthrene ND 25 4.2 ug/l
129-00-0 Pyrene ND 25 3.4 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
367-12-4 2-Fluorophenol 25%14-67%
4165-62-2 Phenol-d5 17%10-50%
118-79-6 2,4,6-Tribromophenol 86%33-118%
4165-60-0 Nitrobenzene-d5 80%42-108%
321-60-8 2-Fluorobiphenyl 80%40-106%
1718-51-0 Terphenyl-d14 83%39-121%
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
100-41-4 Ethylbenzene 3.81 110 ug/l JN
108-38-3 Benzene, 1,3-dimethyl-3.93 110 ug/l JN
98-82-8 Benzene, (1-methylethyl)-4.47 71 ug/l JN
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
57 of 129
FA9374333.6
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:GMW-3
Lab Sample ID:FA93743-6 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
ABN Special List
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
103-65-1 Benzene, propyl-4.77 150 ug/l JN
526-73-8 Benzene, 1,2,3-trimethyl-5.15 45 ug/l JN
496-11-7 Indane 5.53 300 ug/l JN
135-01-3 Benzene, 1,2-diethyl-5.62 41 ug/l JN
527-53-7 Benzene, 1,2,3,5-tetramethyl- $$ I 6.20 35 ug/l JN
768-49-0 Benzene, (2-methyl-1-propenyl)-6.40 48 ug/l JN
767-58-8 Indan, 1-methyl-6.47 110 ug/l JN
Total TIC, Semi-Volatile 1020 ug/l J
(a) Dilution required due to matrix interference.
(b) Associated CCV outside of control limits high, sample was ND.
(c) Associated BS outside control limits high, sample was ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
58 of 129
FA9374333.6
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-3
Lab Sample ID:FA93743-6 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP VPH REV 2.1 Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U8997.D 5 03/16/22 22:02 JR n/a n/a G1U398
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 1200 5.0 5.0 ug/l
100-41-4 Ethylbenzene 81.8 10 5.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 31.8 10 5.0 ug/l
91-20-3 Naphthalene 28.9 25 15 ug/l
108-88-3 Toluene 11.7 10 5.0 ug/l
m,p-Xylene 62.9 20 10 ug/l
95-47-6 o-Xylene 7.8 10 5.0 ug/l J
C5- C8 Aliphatics (Unadj.)1410 500 180 ug/l
C9- C12 Aliphatics (Unadj.)ND 500 180 ug/l
C9- C10 Aromatics (Unadj.)536 500 180 ug/l
C5- C8 Aliphatics ND 500 180 ug/l
C9- C12 Aliphatics ND 500 180 ug/l
C9- C10 Aromatics 536 500 180 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 106%70-130%
460-00-4 BFB 92%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
59 of 129
FA9374333.6
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:GMW-3
Lab Sample ID:FA93743-6 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP EPH REV 2.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a NN037784.D 1 03/11/22 20:22 AF 03/10/22 12:05 OP90180 GNN1768
Run #2 b NN037857.D 1 03/17/22 22:51 AF 03/10/22 12:05 OP90180 GNN1770
Initial Volume Final Volume
Run #1 1050 ml 2.0 ml
Run #2 1050 ml 2.0 ml
MAEPH List
CAS No.Compound Result RL MDL Units Q
83-32-9 Acenaphthene ND 3.8 1.9 ug/l
208-96-8 Acenaphthylene ND 3.8 1.9 ug/l
120-12-7 Anthracene ND 3.8 1.9 ug/l
56-55-3 Benzo(a)anthracene ND 3.8 1.9 ug/l
50-32-8 Benzo(a)pyrene ND 3.8 1.9 ug/l
205-99-2 Benzo(b)fluoranthene ND 3.8 1.9 ug/l
191-24-2 Benzo(g,h,i)perylene ND 3.8 1.9 ug/l
207-08-9 Benzo(k)fluoranthene ND 3.8 1.9 ug/l
218-01-9 Chrysene ND 3.8 1.9 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 3.8 1.9 ug/l
206-44-0 Fluoranthene ND 3.8 1.9 ug/l
86-73-7 Fluorene ND 3.8 1.9 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 3.8 1.9 ug/l
91-57-6 2-Methylnaphthalene 24.8 3.8 1.9 ug/l
91-20-3 Naphthalene 30.6 3.8 1.9 ug/l
85-01-8 Phenanthrene ND 3.8 1.9 ug/l
129-00-0 Pyrene ND 3.8 1.9 ug/l
C11-C22 Aromatics (Unadj.)468 190 76 ug/l
C11-C22 Aromatics 413 190 76 ug/l
C9-C18 Aliphatics ND 190 48 ug/l
C19-C36 Aliphatics ND 190 48 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
3386-33-2 1-Chlorooctadecane 11% c 14% c 40-140%
580-13-2 2-Bromonaphthalene 81%96%40-140%
84-15-1 o-Terphenyl 66% d 76% d 40-140%
321-60-8 2-Fluorobiphenyl 75%89%40-140%
(a) Confirmed by refractionation and reanalysis. Insufficient sample for re-extraction.
(b) Confirmation run.
(c) Surrogate recoveries corrected for double spike. Outside control limits due to breakthrough during
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
60 of 129
FA9374333.6
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:GMW-3
Lab Sample ID:FA93743-6 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP EPH REV 2.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
MAEPH List
CAS No.Compound Result RL MDL Units Q
fractionation.
(d) Surrogate recoveries corrected for double spike.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
61 of 129
FA9374333.6
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:GMW-4
Lab Sample ID:FA93743-7 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0231129.D 500 03/21/22 18:56 SS n/a n/a VA3092
Run #2 a N0124890.D 250 03/22/22 23:03 LR n/a n/a VN6437
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 9780 250 63 ug/l
108-86-1 Bromobenzene ND 250 63 ug/l
74-97-5 Bromochloromethane ND 250 63 ug/l
75-27-4 Bromodichloromethane ND 250 63 ug/l
75-25-2 Bromoform ND 250 63 ug/l
104-51-8 n-Butylbenzene ND 250 63 ug/l
135-98-8 sec-Butylbenzene ND 250 63 ug/l
98-06-6 tert-Butylbenzene ND 250 63 ug/l
56-23-5 Carbon Tetrachloride ND 250 63 ug/l
108-90-7 Chlorobenzene ND 250 63 ug/l
75-00-3 Chloroethane ND 250 100 ug/l
67-66-3 Chloroform ND 250 63 ug/l
95-49-8 o-Chlorotoluene ND 250 63 ug/l
106-43-4 p-Chlorotoluene ND 250 63 ug/l
124-48-1 Dibromochloromethane ND 250 63 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 250 120 ug/l
106-93-4 1,2-Dibromoethane ND 250 63 ug/l
75-71-8 Dichlorodifluoromethane b ND 250 100 ug/l
95-50-1 1,2-Dichlorobenzene ND 250 63 ug/l
541-73-1 1,3-Dichlorobenzene ND 250 63 ug/l
106-46-7 1,4-Dichlorobenzene ND 250 63 ug/l
75-34-3 1,1-Dichloroethane ND 250 63 ug/l
107-06-2 1,2-Dichloroethane ND 250 63 ug/l
75-35-4 1,1-Dichloroethylene c ND 250 63 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 250 63 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 250 63 ug/l
78-87-5 1,2-Dichloropropane ND 250 63 ug/l
142-28-9 1,3-Dichloropropane ND 250 63 ug/l
594-20-7 2,2-Dichloropropane ND 250 63 ug/l
563-58-6 1,1-Dichloropropene ND 250 63 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 250 63 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 250 63 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
62 of 129
FA9374333.7
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:GMW-4
Lab Sample ID:FA93743-7 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 250 63 ug/l
64-17-5 Ethyl Alcohol ND 50000 33000 ug/l
100-41-4 Ethylbenzene 849 250 63 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 250 63 ug/l
87-68-3 Hexachlorobutadiene ND 250 63 ug/l
98-82-8 Isopropylbenzene 170 250 63 ug/l J
99-87-6 p-Isopropyltoluene ND 250 63 ug/l
74-83-9 Methyl Bromide ND 250 100 ug/l
74-87-3 Methyl Chloride ND 250 100 ug/l
74-95-3 Methylene Bromide ND 250 63 ug/l
75-09-2 Methylene Chloride ND 1000 500 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 250 63 ug/l
91-20-3 Naphthalene 378 250 63 ug/l
103-65-1 n-Propylbenzene 301 250 63 ug/l
100-42-5 Styrene ND 250 63 ug/l
75-85-4 Tert-Amyl Alcohol 1130 5000 1000 ug/l J
994-05-8 Tert-Amyl Methyl Ether ND 500 100 ug/l
75-65-0 Tert-Butyl Alcohol ND 5000 1000 ug/l
762-75-4 Tert-Butyl Formate ND 5000 1000 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 250 63 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 250 63 ug/l
127-18-4 Tetrachloroethylene ND 250 63 ug/l
108-88-3 Toluene 158 250 63 ug/l J
87-61-6 1,2,3-Trichlorobenzene ND 250 63 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 250 63 ug/l
71-55-6 1,1,1-Trichloroethane ND 250 63 ug/l
79-00-5 1,1,2-Trichloroethane ND 250 63 ug/l
79-01-6 Trichloroethylene ND 250 63 ug/l
75-69-4 Trichlorofluoromethane b ND 250 100 ug/l
96-18-4 1,2,3-Trichloropropane ND 250 63 ug/l
95-63-6 1,2,4-Trimethylbenzene 450 250 63 ug/l
108-67-8 1,3,5-Trimethylbenzene 135 250 63 ug/l J
75-01-4 Vinyl Chloride ND 250 63 ug/l
m,p-Xylene 654 500 63 ug/l
95-47-6 o-Xylene ND 250 63 ug/l
1330-20-7 Xylene (total)654 750 130 ug/l J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 94%102%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
63 of 129
FA9374333.7
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:GMW-4
Lab Sample ID:FA93743-7 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 100%106%70-130%
2037-26-5 Toluene-D8 100%100%70-130%
460-00-4 4-Bromofluorobenzene 104%95%70-130%
(a) Sample vial(s) contained significant headspace; reported results are considered minimum values. Internal
standard areas outside method criteria. Confirmation run.
(b) Associated ECC outside of control limits high, sample was ND.
(c) Associated ECC outside control limits low.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
64 of 129
FA9374333.7
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:GMW-4
Lab Sample ID:FA93743-7 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 6F13658.D 1 03/10/22 23:50 WH 03/10/22 10:10 OP90179 S6F508
Run #2 6F13678.D 5 03/16/22 13:25 WH 03/10/22 10:10 OP90179 S6F510
Initial Volume Final Volume
Run #1 920 ml 1.0 ml
Run #2 920 ml 1.0 ml
ABN Special List
CAS No.Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 54 11 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 5.4 0.64 ug/l
95-57-8 2-Chlorophenol ND 5.4 0.69 ug/l
120-83-2 2,4-Dichlorophenol ND 5.4 0.91 ug/l
105-67-9 2,4-Dimethylphenol 44.7 5.4 0.80 ug/l
51-28-5 2,4-Dinitrophenol ND 27 5.4 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 11 2.2 ug/l
95-48-7 2-Methylphenol ND 5.4 0.61 ug/l
3&4-Methylphenol ND 5.4 1.1 ug/l
88-75-5 2-Nitrophenol ND 5.4 0.93 ug/l
100-02-7 4-Nitrophenol ND 27 5.4 ug/l
87-86-5 Pentachlorophenol ND 27 5.4 ug/l
108-95-2 Phenol 13.4 5.4 0.54 ug/l
88-06-2 2,4,6-Trichlorophenol ND 5.4 0.82 ug/l
83-32-9 Acenaphthene ND 5.4 0.68 ug/l
208-96-8 Acenaphthylene ND 5.4 0.69 ug/l
120-12-7 Anthracene ND 5.4 0.87 ug/l
56-55-3 Benzo(a)anthracene ND 5.4 0.83 ug/l
50-32-8 Benzo(a)pyrene ND 5.4 0.85 ug/l
205-99-2 Benzo(b)fluoranthene ND 5.4 0.84 ug/l
191-24-2 Benzo(g,h,i)perylene ND 5.4 0.89 ug/l
207-08-9 Benzo(k)fluoranthene ND 5.4 0.93 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 5.4 0.92 ug/l
85-68-7 Butyl Benzyl Phthalate ND 5.4 1.1 ug/l
106-47-8 4-Chloroaniline ND 5.4 0.68 ug/l
111-91-1 bis(2-Chloroethoxy)methane ND 5.4 0.88 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 5.4 0.79 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane)ND 5.4 0.82 ug/l
91-58-7 2-Chloronaphthalene ND 5.4 0.55 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether ND 5.4 0.58 ug/l
218-01-9 Chrysene ND 5.4 0.92 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 5.4 0.87 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
65 of 129
FA9374333.7
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:GMW-4
Lab Sample ID:FA93743-7 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
ABN Special List
CAS No.Compound Result RL MDL Units Q
132-64-9 Dibenzofuran ND 5.4 0.65 ug/l
91-94-1 3,3'-Dichlorobenzidine ND 5.4 0.70 ug/l
84-66-2 Diethyl Phthalate ND 5.4 1.1 ug/l
131-11-3 Dimethyl Phthalate ND 5.4 1.1 ug/l
84-74-2 Di-n-butyl Phthalate ND 5.4 1.1 ug/l
117-84-0 Di-n-octyl Phthalate a ND 5.4 1.1 ug/l
121-14-2 2,4-Dinitrotoluene ND 5.4 0.88 ug/l
606-20-2 2,6-Dinitrotoluene ND 5.4 0.78 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate a ND 5.4 1.1 ug/l
206-44-0 Fluoranthene ND 5.4 0.60 ug/l
86-73-7 Fluorene ND 5.4 0.76 ug/l
118-74-1 Hexachlorobenzene ND 5.4 0.75 ug/l
87-68-3 Hexachlorobutadiene ND 5.4 0.54 ug/l
77-47-4 Hexachlorocyclopentadiene ND 5.4 2.0 ug/l
67-72-1 Hexachloroethane ND 5.4 1.8 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 5.4 0.78 ug/l
78-59-1 Isophorone b ND 5.4 0.84 ug/l
90-12-0 1-Methylnaphthalene 41.8 5.4 0.57 ug/l
91-57-6 2-Methylnaphthalene 64.8 5.4 0.65 ug/l
91-20-3 Naphthalene 169 c 27 2.7 ug/l
98-95-3 Nitrobenzene ND 5.4 1.0 ug/l
621-64-7 N-Nitrosodi-n-propylamine ND 5.4 0.73 ug/l
86-30-6 N-Nitrosodiphenylamine a ND 5.4 0.88 ug/l
85-01-8 Phenanthrene ND 5.4 0.94 ug/l
129-00-0 Pyrene ND 5.4 0.74 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
367-12-4 2-Fluorophenol 44%41%14-67%
4165-62-2 Phenol-d5 33%33%10-50%
118-79-6 2,4,6-Tribromophenol 89%86%33-118%
4165-60-0 Nitrobenzene-d5 79%80%42-108%
321-60-8 2-Fluorobiphenyl 51%74%40-106%
1718-51-0 Terphenyl-d14 81%78%39-121%
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
590-36-3 2-Pentanol, 2-methyl-2.42 60 ug/l JN
108-88-3 Toluene 2.76 36 ug/l JN
1462-03-9 Cyclopentanol, 1-methyl-3.08 46 ug/l JN
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
66 of 129
FA9374333.7
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:GMW-4
Lab Sample ID:FA93743-7 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
ABN Special List
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
100-41-4 Ethylbenzene 3.83 320 ug/l JN
108-38-3 Benzene, 1,3-dimethyl-3.93 140 ug/l JN
98-82-8 Benzene, (1-methylethyl)-4.47 85 ug/l JN
103-65-1 Benzene, propyl-4.77 120 ug/l JN
611-14-3 Benzene, 1-ethyl-2-methyl-4.87 41 ug/l JN
108-67-8 Benzene, 1,3,5-trimethyl-4.92 58 ug/l JN
526-73-8 Benzene, 1,2,3-trimethyl-5.16 210 ug/l JN
496-11-7 Indane 5.54 290 ug/l JN
135-01-3 Benzene, 1,2-diethyl-5.63 53 ug/l JN
135-01-3 Benzene, 1,2-diethyl-5.71 130 ug/l JN
1758-88-9 Benzene, 2-ethyl-1,4-dimethyl- $$5.87 70 ug/l JN
99-87-6 Benzene, 1-methyl-4-(1-methylethyl)-5.90 38 ug/l JN
95-93-2 Benzene, 1,2,4,5-tetramethyl-6.21 36 ug/l JN
95-93-2 Benzene, 1,2,4,5-tetramethyl-6.24 50 ug/l JN
767-58-8 Indan, 1-methyl-6.41 34 ug/l JN
87-41-2 1(3H)-Isobenzofuranone 7.95 40 ug/l JN
Total TIC, Semi-Volatile 1857 ug/l J
(a) Associated CCV outside of control limits high, sample was ND.
(b) Associated BS outside control limits high, sample was ND.
(c) Result is from Run# 2
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
67 of 129
FA9374333.7
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-4
Lab Sample ID:FA93743-7 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP VPH REV 2.1 Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U9003.D 5 03/17/22 01:02 JR n/a n/a G1U398
Run #2 1U9082.D 10 03/18/22 17:36 JR n/a n/a G1U401
Run #3 1U9060.D 50 03/18/22 06:17 JR n/a n/a G1U400
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
Run #3 5.0 ml
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 9080 a 50 50 ug/l
100-41-4 Ethylbenzene 808 10 5.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 41.4 10 5.0 ug/l
91-20-3 Naphthalene 324 25 15 ug/l
108-88-3 Toluene 116 10 5.0 ug/l
m,p-Xylene 639 20 10 ug/l
95-47-6 o-Xylene 39.0 10 5.0 ug/l
C5- C8 Aliphatics (Unadj.)8250 b 1000 350 ug/l
C9- C12 Aliphatics (Unadj.)194 500 180 ug/l J
C9- C10 Aromatics (Unadj.)1740 500 180 ug/l
C5- C8 Aliphatics c 1200 500 180 ug/l E
C9- C12 Aliphatics ND 500 180 ug/l
C9- C10 Aromatics 1740 500 180 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Run# 3 Limits
460-00-4 BFB 104%112%84%70-130%
460-00-4 BFB 99%95%78%70-130%
(a) Result is from Run# 3
(b) Result is from Run# 2
(c) Compound below calibration range in higher dilution.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
68 of 129
FA9374333.7
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:GMW-4
Lab Sample ID:FA93743-7 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP EPH REV 2.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a NN037785.D 1 03/11/22 20:52 AF 03/10/22 12:05 OP90180 GNN1768
Run #2 b NN037858.D 1 03/17/22 23:21 AF 03/10/22 12:05 OP90180 GNN1770
Initial Volume Final Volume
Run #1 980 ml 2.0 ml
Run #2 980 ml 2.0 ml
MAEPH List
CAS No.Compound Result RL MDL Units Q
83-32-9 Acenaphthene ND 4.1 2.0 ug/l
208-96-8 Acenaphthylene ND 4.1 2.0 ug/l
120-12-7 Anthracene ND 4.1 2.0 ug/l
56-55-3 Benzo(a)anthracene ND 4.1 2.0 ug/l
50-32-8 Benzo(a)pyrene ND 4.1 2.0 ug/l
205-99-2 Benzo(b)fluoranthene ND 4.1 2.0 ug/l
191-24-2 Benzo(g,h,i)perylene ND 4.1 2.0 ug/l
207-08-9 Benzo(k)fluoranthene ND 4.1 2.0 ug/l
218-01-9 Chrysene ND 4.1 2.0 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 4.1 2.0 ug/l
206-44-0 Fluoranthene ND 4.1 2.0 ug/l
86-73-7 Fluorene ND 4.1 2.0 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 4.1 2.0 ug/l
91-57-6 2-Methylnaphthalene 47.7 4.1 2.0 ug/l
91-20-3 Naphthalene 146 4.1 2.0 ug/l
85-01-8 Phenanthrene ND 4.1 2.0 ug/l
129-00-0 Pyrene ND 4.1 2.0 ug/l
C11-C22 Aromatics (Unadj.)758 200 82 ug/l
C11-C22 Aromatics 564 200 82 ug/l
C9-C18 Aliphatics 52.4 200 51 ug/l J
C19-C36 Aliphatics ND 200 51 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
3386-33-2 1-Chlorooctadecane 26% c 35% c 40-140%
580-13-2 2-Bromonaphthalene 93%112%40-140%
84-15-1 o-Terphenyl 66% d 80% d 40-140%
321-60-8 2-Fluorobiphenyl 75%88%40-140%
(a) Confirmed by refractionation and reanalysis. Insufficient sample for re-extraction.
(b) Confirmation run for surrogate recoveries.
(c) Surrogate recoveries corrected for double spike. Outside control limits due to breakthrough during
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
69 of 129
FA9374333.7
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:GMW-4
Lab Sample ID:FA93743-7 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP EPH REV 2.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
MAEPH List
CAS No.Compound Result RL MDL Units Q
fractionation.
(d) Surrogate recoveries corrected for double spike.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
70 of 129
FA9374333.7
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:SW-1
Lab Sample ID:FA93743-8 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0231130.D 500 03/21/22 19:20 SS n/a n/a VA3092
Run #2 a N0124891.D 250 03/22/22 23:26 LR n/a n/a VN6437
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 9650 250 63 ug/l
108-86-1 Bromobenzene ND 250 63 ug/l
74-97-5 Bromochloromethane ND 250 63 ug/l
75-27-4 Bromodichloromethane ND 250 63 ug/l
75-25-2 Bromoform ND 250 63 ug/l
104-51-8 n-Butylbenzene ND 250 63 ug/l
135-98-8 sec-Butylbenzene ND 250 63 ug/l
98-06-6 tert-Butylbenzene ND 250 63 ug/l
56-23-5 Carbon Tetrachloride ND 250 63 ug/l
108-90-7 Chlorobenzene ND 250 63 ug/l
75-00-3 Chloroethane ND 250 100 ug/l
67-66-3 Chloroform ND 250 63 ug/l
95-49-8 o-Chlorotoluene ND 250 63 ug/l
106-43-4 p-Chlorotoluene ND 250 63 ug/l
124-48-1 Dibromochloromethane ND 250 63 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 250 120 ug/l
106-93-4 1,2-Dibromoethane ND 250 63 ug/l
75-71-8 Dichlorodifluoromethane b ND 250 100 ug/l
95-50-1 1,2-Dichlorobenzene ND 250 63 ug/l
541-73-1 1,3-Dichlorobenzene ND 250 63 ug/l
106-46-7 1,4-Dichlorobenzene ND 250 63 ug/l
75-34-3 1,1-Dichloroethane ND 250 63 ug/l
107-06-2 1,2-Dichloroethane ND 250 63 ug/l
75-35-4 1,1-Dichloroethylene c ND 250 63 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 250 63 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 250 63 ug/l
78-87-5 1,2-Dichloropropane ND 250 63 ug/l
142-28-9 1,3-Dichloropropane ND 250 63 ug/l
594-20-7 2,2-Dichloropropane ND 250 63 ug/l
563-58-6 1,1-Dichloropropene ND 250 63 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 250 63 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 250 63 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
71 of 129
FA9374333.8
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:SW-1
Lab Sample ID:FA93743-8 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 250 63 ug/l
64-17-5 Ethyl Alcohol ND 50000 33000 ug/l
100-41-4 Ethylbenzene 1450 250 63 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 250 63 ug/l
87-68-3 Hexachlorobutadiene ND 250 63 ug/l
98-82-8 Isopropylbenzene 77.1 250 63 ug/l J
99-87-6 p-Isopropyltoluene ND 250 63 ug/l
74-83-9 Methyl Bromide ND 250 100 ug/l
74-87-3 Methyl Chloride ND 250 100 ug/l
74-95-3 Methylene Bromide ND 250 63 ug/l
75-09-2 Methylene Chloride ND 1000 500 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 250 63 ug/l
91-20-3 Naphthalene 138 250 63 ug/l J
103-65-1 n-Propylbenzene 226 250 63 ug/l J
100-42-5 Styrene ND 250 63 ug/l
75-85-4 Tert-Amyl Alcohol ND 5000 1000 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 500 100 ug/l
75-65-0 Tert-Butyl Alcohol ND 5000 1000 ug/l
762-75-4 Tert-Butyl Formate ND 5000 1000 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 250 63 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 250 63 ug/l
127-18-4 Tetrachloroethylene ND 250 63 ug/l
108-88-3 Toluene ND 250 63 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 250 63 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 250 63 ug/l
71-55-6 1,1,1-Trichloroethane ND 250 63 ug/l
79-00-5 1,1,2-Trichloroethane ND 250 63 ug/l
79-01-6 Trichloroethylene ND 250 63 ug/l
75-69-4 Trichlorofluoromethane b ND 250 100 ug/l
96-18-4 1,2,3-Trichloropropane ND 250 63 ug/l
95-63-6 1,2,4-Trimethylbenzene 138 250 63 ug/l J
108-67-8 1,3,5-Trimethylbenzene 65.1 250 63 ug/l J
75-01-4 Vinyl Chloride ND 250 63 ug/l
m,p-Xylene 888 500 63 ug/l
95-47-6 o-Xylene ND 250 63 ug/l
1330-20-7 Xylene (total)888 750 130 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 97%103%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
72 of 129
FA9374333.8
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:SW-1
Lab Sample ID:FA93743-8 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 101%106%70-130%
2037-26-5 Toluene-D8 100%100%70-130%
460-00-4 4-Bromofluorobenzene 104%93%70-130%
(a) Sample vial(s) contained significant headspace; reported results are considered minimum values. Internal
standard areas outside method criteria. Confirmation run.
(b) Associated ECC outside of control limits high, sample was ND.
(c) Associated ECC outside control limits low.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
73 of 129
FA9374333.8
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:SW-1
Lab Sample ID:FA93743-8 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 6F13659.D 1 03/11/22 00:15 WH 03/10/22 10:10 OP90179 S6F508
Run #2 6F13679.D 5 03/16/22 13:50 WH 03/10/22 10:10 OP90179 S6F510
Initial Volume Final Volume
Run #1 1030 ml 1.0 ml
Run #2 1030 ml 1.0 ml
ABN Special List
CAS No.Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 49 9.7 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 4.9 0.58 ug/l
95-57-8 2-Chlorophenol ND 4.9 0.61 ug/l
120-83-2 2,4-Dichlorophenol ND 4.9 0.81 ug/l
105-67-9 2,4-Dimethylphenol 22.2 4.9 0.72 ug/l
51-28-5 2,4-Dinitrophenol ND 24 4.9 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 9.7 1.9 ug/l
95-48-7 2-Methylphenol ND 4.9 0.54 ug/l
3&4-Methylphenol ND 4.9 0.95 ug/l
88-75-5 2-Nitrophenol ND 4.9 0.83 ug/l
100-02-7 4-Nitrophenol ND 24 4.9 ug/l
87-86-5 Pentachlorophenol ND 24 4.9 ug/l
108-95-2 Phenol 14.4 4.9 0.49 ug/l
88-06-2 2,4,6-Trichlorophenol ND 4.9 0.73 ug/l
83-32-9 Acenaphthene ND 4.9 0.61 ug/l
208-96-8 Acenaphthylene ND 4.9 0.62 ug/l
120-12-7 Anthracene ND 4.9 0.77 ug/l
56-55-3 Benzo(a)anthracene ND 4.9 0.74 ug/l
50-32-8 Benzo(a)pyrene ND 4.9 0.76 ug/l
205-99-2 Benzo(b)fluoranthene ND 4.9 0.75 ug/l
191-24-2 Benzo(g,h,i)perylene ND 4.9 0.80 ug/l
207-08-9 Benzo(k)fluoranthene ND 4.9 0.83 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 4.9 0.82 ug/l
85-68-7 Butyl Benzyl Phthalate ND 4.9 0.97 ug/l
106-47-8 4-Chloroaniline ND 4.9 0.61 ug/l
111-91-1 bis(2-Chloroethoxy)methane ND 4.9 0.79 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 4.9 0.71 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane)ND 4.9 0.73 ug/l
91-58-7 2-Chloronaphthalene ND 4.9 0.49 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether ND 4.9 0.52 ug/l
218-01-9 Chrysene ND 4.9 0.83 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 4.9 0.78 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
74 of 129
FA9374333.8
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:SW-1
Lab Sample ID:FA93743-8 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
ABN Special List
CAS No.Compound Result RL MDL Units Q
132-64-9 Dibenzofuran ND 4.9 0.58 ug/l
91-94-1 3,3'-Dichlorobenzidine ND 4.9 0.62 ug/l
84-66-2 Diethyl Phthalate ND 4.9 0.97 ug/l
131-11-3 Dimethyl Phthalate ND 4.9 0.97 ug/l
84-74-2 Di-n-butyl Phthalate ND 4.9 0.97 ug/l
117-84-0 Di-n-octyl Phthalate a ND 4.9 0.97 ug/l
121-14-2 2,4-Dinitrotoluene ND 4.9 0.79 ug/l
606-20-2 2,6-Dinitrotoluene ND 4.9 0.69 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate a ND 4.9 0.97 ug/l
206-44-0 Fluoranthene ND 4.9 0.54 ug/l
86-73-7 Fluorene ND 4.9 0.68 ug/l
118-74-1 Hexachlorobenzene ND 4.9 0.67 ug/l
87-68-3 Hexachlorobutadiene ND 4.9 0.49 ug/l
77-47-4 Hexachlorocyclopentadiene ND 4.9 1.8 ug/l
67-72-1 Hexachloroethane ND 4.9 1.6 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 4.9 0.69 ug/l
78-59-1 Isophorone b ND 4.9 0.75 ug/l
90-12-0 1-Methylnaphthalene 49.0 4.9 0.51 ug/l
91-57-6 2-Methylnaphthalene 81.8 4.9 0.58 ug/l
91-20-3 Naphthalene 125 c 24 2.4 ug/l
98-95-3 Nitrobenzene ND 4.9 0.91 ug/l
621-64-7 N-Nitrosodi-n-propylamine ND 4.9 0.65 ug/l
86-30-6 N-Nitrosodiphenylamine a ND 4.9 0.78 ug/l
85-01-8 Phenanthrene ND 4.9 0.84 ug/l
129-00-0 Pyrene ND 4.9 0.66 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
367-12-4 2-Fluorophenol 25%24%14-67%
4165-62-2 Phenol-d5 17%17%10-50%
118-79-6 2,4,6-Tribromophenol 82%76%33-118%
4165-60-0 Nitrobenzene-d5 79%82%42-108%
321-60-8 2-Fluorobiphenyl 76%74%40-106%
1718-51-0 Terphenyl-d14 58%53%39-121%
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
590-36-3 2-Pentanol, 2-methyl-2.42 37 ug/l JN
1528-22-9 Cyclobutane, (1-methylethylidene)-2.58 28 ug/l JN
108-88-3 Toluene 2.76 69 ug/l JN
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
75 of 129
FA9374333.8
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:SW-1
Lab Sample ID:FA93743-8 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
ABN Special List
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
19550-46-0 1,3-Dimethyl cyclopentanol 3.66 36 ug/l JN
100-41-4 Ethylbenzene 3.84 1000 ug/l JN
108-38-3 Benzene, 1,3-dimethyl-3.94 680 ug/l JN
98-82-8 Benzene, (1-methylethyl)-4.47 75 ug/l JN
103-65-1 Benzene, propyl-4.77 160 ug/l JN
611-14-3 Benzene, 1-ethyl-2-methyl-4.84 24 ug/l JN
611-14-3 Benzene, 1-ethyl-2-methyl-4.87 80 ug/l JN
108-67-8 Benzene, 1,3,5-trimethyl-4.92 66 ug/l JN
611-14-3 Benzene, 1-ethyl-2-methyl-5.01 91 ug/l JN
526-73-8 Benzene, 1,2,3-trimethyl-5.16 200 ug/l JN
620-14-4 Benzene, 1-ethyl-3-methyl-5.41 190 ug/l JN
496-11-7 Indane 5.54 490 ug/l JN
135-01-3 Benzene, 1,2-diethyl-5.63 52 ug/l JN
141-93-5 Benzene, 1,3-diethyl-5.70 84 ug/l JN
527-53-7 Benzene, 1,2,3,5-tetramethyl- $$ I 6.21 41 ug/l JN
3290-53-7 Benzene, (2-methyl-2-propenyl)-6.40 29 ug/l JN
767-58-8 Indan, 1-methyl-6.48 85 ug/l JN
Total TIC, Semi-Volatile 3517 ug/l J
(a) Associated CCV outside of control limits high, sample was ND.
(b) Associated BS outside control limits high, sample was ND.
(c) Result is from Run# 2
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
76 of 129
FA9374333.8
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SW-1
Lab Sample ID:FA93743-8 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP VPH REV 2.1 Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U8989.D 1 03/16/22 18:00 JR n/a n/a G1U398
Run #2 1U9083.D 10 03/18/22 18:06 JR n/a n/a G1U401
Run #3 1U8990.D 20 03/16/22 18:30 JR n/a n/a G1U398
Run #4 1U9061.D 50 03/18/22 06:47 JR n/a n/a G1U400
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
Run #3 5.0 ml
Run #4 5.0 ml
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 8940 a 50 50 ug/l
100-41-4 Ethylbenzene 1480 b 20 10 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 2.0 1.0 ug/l
91-20-3 Naphthalene 183 5.0 3.0 ug/l
108-88-3 Toluene 102 2.0 1.0 ug/l
m,p-Xylene 709 4.0 2.0 ug/l
95-47-6 o-Xylene 26.2 2.0 1.0 ug/l
C5- C8 Aliphatics (Unadj.)10500 b 1000 350 ug/l
C9- C12 Aliphatics (Unadj.)798 b 1000 350 ug/l J
C9- C10 Aromatics (Unadj.)1260 b 1000 350 ug/l
C5- C8 Aliphatics c 2370 b 1000 350 ug/l E
C9- C12 Aliphatics ND 100 35 ug/l
C9- C10 Aromatics 1260 b 1000 350 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Run# 3 Limits
460-00-4 BFB 95%108%106%70-130%
460-00-4 BFB 88%94%93%70-130%
(a) Result is from Run# 4
(b) Result is from Run# 2
(c) Compound below calibration range in higher dilution.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
77 of 129
FA9374333.8
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SW-1
Lab Sample ID:FA93743-8 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP EPH REV 2.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 NN037859.D 1 03/17/22 23:50 AF 03/10/22 12:05 OP90180 GNN1770
Run #2
Initial Volume Final Volume
Run #1 1050 ml 2.0 ml
Run #2
MAEPH List
CAS No.Compound Result RL MDL Units Q
83-32-9 Acenaphthene ND 3.8 1.9 ug/l
208-96-8 Acenaphthylene ND 3.8 1.9 ug/l
120-12-7 Anthracene ND 3.8 1.9 ug/l
56-55-3 Benzo(a)anthracene ND 3.8 1.9 ug/l
50-32-8 Benzo(a)pyrene ND 3.8 1.9 ug/l
205-99-2 Benzo(b)fluoranthene ND 3.8 1.9 ug/l
191-24-2 Benzo(g,h,i)perylene ND 3.8 1.9 ug/l
207-08-9 Benzo(k)fluoranthene ND 3.8 1.9 ug/l
218-01-9 Chrysene ND 3.8 1.9 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 3.8 1.9 ug/l
206-44-0 Fluoranthene ND 3.8 1.9 ug/l
86-73-7 Fluorene ND 3.8 1.9 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 3.8 1.9 ug/l
91-57-6 2-Methylnaphthalene 61.2 3.8 1.9 ug/l
91-20-3 Naphthalene 117 3.8 1.9 ug/l
85-01-8 Phenanthrene ND 3.8 1.9 ug/l
129-00-0 Pyrene ND 3.8 1.9 ug/l
C11-C22 Aromatics (Unadj.)849 190 76 ug/l
C11-C22 Aromatics 671 190 76 ug/l
C9-C18 Aliphatics 397 190 48 ug/l
C19-C36 Aliphatics 203 190 48 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
3386-33-2 1-Chlorooctadecane 43% a 40-140%
580-13-2 2-Bromonaphthalene 105%40-140%
84-15-1 o-Terphenyl 65% a 40-140%
321-60-8 2-Fluorobiphenyl 97%40-140%
(a) Surrogate recoveries corrected for double spike.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
78 of 129
FA9374333.8
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:GMW-7
Lab Sample ID:FA93743-9 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0231131.D 50 03/21/22 19:43 SS n/a n/a VA3092
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 1000 25 6.3 ug/l
108-86-1 Bromobenzene ND 25 6.3 ug/l
74-97-5 Bromochloromethane ND 25 6.3 ug/l
75-27-4 Bromodichloromethane ND 25 6.3 ug/l
75-25-2 Bromoform ND 25 6.3 ug/l
104-51-8 n-Butylbenzene ND 25 6.3 ug/l
135-98-8 sec-Butylbenzene ND 25 6.3 ug/l
98-06-6 tert-Butylbenzene ND 25 6.3 ug/l
56-23-5 Carbon Tetrachloride ND 25 6.3 ug/l
108-90-7 Chlorobenzene ND 25 6.3 ug/l
75-00-3 Chloroethane ND 25 10 ug/l
67-66-3 Chloroform ND 25 6.3 ug/l
95-49-8 o-Chlorotoluene ND 25 6.3 ug/l
106-43-4 p-Chlorotoluene ND 25 6.3 ug/l
124-48-1 Dibromochloromethane ND 25 6.3 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 25 12 ug/l
106-93-4 1,2-Dibromoethane ND 25 6.3 ug/l
75-71-8 Dichlorodifluoromethane a ND 25 10 ug/l
95-50-1 1,2-Dichlorobenzene ND 25 6.3 ug/l
541-73-1 1,3-Dichlorobenzene ND 25 6.3 ug/l
106-46-7 1,4-Dichlorobenzene ND 25 6.3 ug/l
75-34-3 1,1-Dichloroethane ND 25 6.3 ug/l
107-06-2 1,2-Dichloroethane ND 25 6.3 ug/l
75-35-4 1,1-Dichloroethylene b ND 25 6.3 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 25 6.3 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 25 6.3 ug/l
78-87-5 1,2-Dichloropropane ND 25 6.3 ug/l
142-28-9 1,3-Dichloropropane ND 25 6.3 ug/l
594-20-7 2,2-Dichloropropane ND 25 6.3 ug/l
563-58-6 1,1-Dichloropropene ND 25 6.3 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 25 6.3 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 25 6.3 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
79 of 129
FA9374333.9
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:GMW-7
Lab Sample ID:FA93743-9 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 25 6.3 ug/l
64-17-5 Ethyl Alcohol ND 5000 3300 ug/l
100-41-4 Ethylbenzene 116 25 6.3 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 25 6.3 ug/l
87-68-3 Hexachlorobutadiene ND 25 6.3 ug/l
98-82-8 Isopropylbenzene 9.9 25 6.3 ug/l J
99-87-6 p-Isopropyltoluene ND 25 6.3 ug/l
74-83-9 Methyl Bromide ND 25 10 ug/l
74-87-3 Methyl Chloride ND 25 10 ug/l
74-95-3 Methylene Bromide ND 25 6.3 ug/l
75-09-2 Methylene Chloride ND 100 50 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 25 6.3 ug/l
91-20-3 Naphthalene 67.8 25 6.3 ug/l
103-65-1 n-Propylbenzene 27.0 25 6.3 ug/l
100-42-5 Styrene ND 25 6.3 ug/l
75-85-4 Tert-Amyl Alcohol 1110 500 100 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 50 10 ug/l
75-65-0 Tert-Butyl Alcohol 165 500 100 ug/l J
762-75-4 Tert-Butyl Formate ND 500 100 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 25 6.3 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 25 6.3 ug/l
127-18-4 Tetrachloroethylene ND 25 6.3 ug/l
108-88-3 Toluene 143 25 6.3 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 25 6.3 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 25 6.3 ug/l
71-55-6 1,1,1-Trichloroethane ND 25 6.3 ug/l
79-00-5 1,1,2-Trichloroethane ND 25 6.3 ug/l
79-01-6 Trichloroethylene ND 25 6.3 ug/l
75-69-4 Trichlorofluoromethane a ND 25 10 ug/l
96-18-4 1,2,3-Trichloropropane ND 25 6.3 ug/l
95-63-6 1,2,4-Trimethylbenzene 47.1 25 6.3 ug/l
108-67-8 1,3,5-Trimethylbenzene 16.9 25 6.3 ug/l J
75-01-4 Vinyl Chloride ND 25 6.3 ug/l
m,p-Xylene 241 50 6.3 ug/l
95-47-6 o-Xylene 28.8 25 6.3 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 94%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
80 of 129
FA9374333.9
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:GMW-7
Lab Sample ID:FA93743-9 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:SM 6200B Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
2037-26-5 Toluene-D8 102%70-130%
460-00-4 4-Bromofluorobenzene 103%70-130%
(a) Associated ECC outside of control limits high, sample was ND.
(b) Associated ECC outside control limits low.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
81 of 129
FA9374333.9
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:GMW-7
Lab Sample ID:FA93743-9 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 6F13660.D 1 03/11/22 00:40 WH 03/10/22 10:10 OP90179 S6F508
Run #2
Initial Volume Final Volume
Run #1 1060 ml 1.0 ml
Run #2
ABN Special List
CAS No.Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 47 9.4 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 4.7 0.56 ug/l
95-57-8 2-Chlorophenol ND 4.7 0.60 ug/l
120-83-2 2,4-Dichlorophenol ND 4.7 0.79 ug/l
105-67-9 2,4-Dimethylphenol 1.7 4.7 0.70 ug/l J
51-28-5 2,4-Dinitrophenol ND 24 4.7 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 9.4 1.9 ug/l
95-48-7 2-Methylphenol ND 4.7 0.53 ug/l
3&4-Methylphenol ND 4.7 0.92 ug/l
88-75-5 2-Nitrophenol ND 4.7 0.80 ug/l
100-02-7 4-Nitrophenol ND 24 4.7 ug/l
87-86-5 Pentachlorophenol ND 24 4.7 ug/l
108-95-2 Phenol 1.4 4.7 0.47 ug/l J
88-06-2 2,4,6-Trichlorophenol ND 4.7 0.71 ug/l
83-32-9 Acenaphthene ND 4.7 0.59 ug/l
208-96-8 Acenaphthylene ND 4.7 0.60 ug/l
120-12-7 Anthracene ND 4.7 0.75 ug/l
56-55-3 Benzo(a)anthracene ND 4.7 0.72 ug/l
50-32-8 Benzo(a)pyrene ND 4.7 0.74 ug/l
205-99-2 Benzo(b)fluoranthene ND 4.7 0.73 ug/l
191-24-2 Benzo(g,h,i)perylene ND 4.7 0.78 ug/l
207-08-9 Benzo(k)fluoranthene ND 4.7 0.81 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 4.7 0.80 ug/l
85-68-7 Butyl Benzyl Phthalate ND 4.7 0.94 ug/l
106-47-8 4-Chloroaniline ND 4.7 0.59 ug/l
111-91-1 bis(2-Chloroethoxy)methane ND 4.7 0.76 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 4.7 0.69 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane)ND 4.7 0.71 ug/l
91-58-7 2-Chloronaphthalene ND 4.7 0.48 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether ND 4.7 0.51 ug/l
218-01-9 Chrysene ND 4.7 0.80 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 4.7 0.76 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
82 of 129
FA9374333.9
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:GMW-7
Lab Sample ID:FA93743-9 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
ABN Special List
CAS No.Compound Result RL MDL Units Q
132-64-9 Dibenzofuran 0.79 4.7 0.57 ug/l J
91-94-1 3,3'-Dichlorobenzidine ND 4.7 0.61 ug/l
84-66-2 Diethyl Phthalate ND 4.7 0.94 ug/l
131-11-3 Dimethyl Phthalate ND 4.7 0.94 ug/l
84-74-2 Di-n-butyl Phthalate ND 4.7 0.94 ug/l
117-84-0 Di-n-octyl Phthalate a ND 4.7 0.94 ug/l
121-14-2 2,4-Dinitrotoluene ND 4.7 0.77 ug/l
606-20-2 2,6-Dinitrotoluene ND 4.7 0.67 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate a ND 4.7 0.94 ug/l
206-44-0 Fluoranthene ND 4.7 0.52 ug/l
86-73-7 Fluorene ND 4.7 0.66 ug/l
118-74-1 Hexachlorobenzene ND 4.7 0.65 ug/l
87-68-3 Hexachlorobutadiene ND 4.7 0.47 ug/l
77-47-4 Hexachlorocyclopentadiene ND 4.7 1.7 ug/l
67-72-1 Hexachloroethane ND 4.7 1.5 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 4.7 0.67 ug/l
78-59-1 Isophorone b ND 4.7 0.73 ug/l
90-12-0 1-Methylnaphthalene 15.3 4.7 0.50 ug/l
91-57-6 2-Methylnaphthalene 15.6 4.7 0.57 ug/l
91-20-3 Naphthalene 43.6 4.7 0.47 ug/l
98-95-3 Nitrobenzene ND 4.7 0.88 ug/l
621-64-7 N-Nitrosodi-n-propylamine ND 4.7 0.63 ug/l
86-30-6 N-Nitrosodiphenylamine a ND 4.7 0.76 ug/l
85-01-8 Phenanthrene ND 4.7 0.82 ug/l
129-00-0 Pyrene ND 4.7 0.65 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
367-12-4 2-Fluorophenol 27%14-67%
4165-62-2 Phenol-d5 19%10-50%
118-79-6 2,4,6-Tribromophenol 84%33-118%
4165-60-0 Nitrobenzene-d5 78%42-108%
321-60-8 2-Fluorobiphenyl 77%40-106%
1718-51-0 Terphenyl-d14 77%39-121%
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
590-36-3 2-Pentanol, 2-methyl-2.42 73 ug/l JN
108-88-3 Toluene 2.76 68 ug/l JN
1462-03-9 Cyclopentanol, 1-methyl-3.08 66 ug/l JN
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
83 of 129
FA9374333.9
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:GMW-7
Lab Sample ID:FA93743-9 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
ABN Special List
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
625-23-0 2-Hexanol, 2-methyl-3.52 19 ug/l JN
19550-46-0 1,3-Dimethyl cyclopentanol 3.66 62 ug/l JN
100-41-4 Ethylbenzene 3.81 91 ug/l JN
108-38-3 Benzene, 1,3-dimethyl-3.92 180 ug/l JN
106-42-3 p-Xylene 4.15 25 ug/l JN
103-65-1 Benzene, propyl-4.77 31 ug/l JN
620-14-4 Benzene, 1-ethyl-3-methyl-4.84 28 ug/l JN
611-14-3 Benzene, 1-ethyl-2-methyl-4.87 14 ug/l JN
108-67-8 Benzene, 1,3,5-trimethyl-4.92 15 ug/l JN
611-14-3 Benzene, 1-ethyl-2-methyl-5.00 14 ug/l JN
95-63-6 Benzene, 1,2,4-trimethyl-5.15 56 ug/l JN
526-73-8 Benzene, 1,2,3-trimethyl-5.40 16 ug/l JN
496-11-7 Indane 5.53 140 ug/l JN
135-01-3 Benzene, 1,2-diethyl-5.62 23 ug/l JN
141-93-5 Benzene, 1,3-diethyl-5.70 30 ug/l JN
768-49-0 Benzene, (2-methyl-1-propenyl)-6.40 14 ug/l JN
Total TIC, Semi-Volatile 965 ug/l J
(a) Associated CCV outside of control limits high, sample was ND.
(b) Associated BS outside control limits high, sample was ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
84 of 129
FA9374333.9
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-7
Lab Sample ID:FA93743-9 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP VPH REV 2.1 Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U8991.D 1 03/16/22 19:01 JR n/a n/a G1U398
Run #2 1U9080.D 10 03/18/22 16:35 JR n/a n/a G1U401
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 892 a 10 10 ug/l
100-41-4 Ethylbenzene 109 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 2.0 1.0 ug/l
91-20-3 Naphthalene 79.9 5.0 3.0 ug/l
108-88-3 Toluene 114 2.0 1.0 ug/l
m,p-Xylene 218 4.0 2.0 ug/l
95-47-6 o-Xylene 35.0 2.0 1.0 ug/l
C5- C8 Aliphatics (Unadj.)1310 a 1000 350 ug/l
C9- C12 Aliphatics (Unadj.) b 59.5 100 35 ug/l EJ
C9- C10 Aromatics (Unadj.)353 a 1000 350 ug/l J
C5- C8 Aliphatics b 413 100 35 ug/l E
C9- C12 Aliphatics ND 100 35 ug/l
C9- C10 Aromatics 353 a 1000 350 ug/l J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 108%105%70-130%
460-00-4 BFB 93%92%70-130%
(a) Result is from Run# 2
(b) Compound below calibration range in higher dilution.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
85 of 129
FA9374333.9
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-7
Lab Sample ID:FA93743-9 Date Sampled:03/08/22
Matrix:AQ - Ground Water Date Received:03/09/22
Method:MADEP EPH REV 2.1 SW846 3510C Percent Solids:n/a
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 NN037789.D 1 03/11/22 22:49 AF 03/10/22 12:05 OP90180 GNN1768
Run #2
Initial Volume Final Volume
Run #1 960 ml 2.0 ml
Run #2
MAEPH List
CAS No.Compound Result RL MDL Units Q
83-32-9 Acenaphthene ND 4.2 2.1 ug/l
208-96-8 Acenaphthylene ND 4.2 2.1 ug/l
120-12-7 Anthracene ND 4.2 2.1 ug/l
56-55-3 Benzo(a)anthracene ND 4.2 2.1 ug/l
50-32-8 Benzo(a)pyrene ND 4.2 2.1 ug/l
205-99-2 Benzo(b)fluoranthene ND 4.2 2.1 ug/l
191-24-2 Benzo(g,h,i)perylene ND 4.2 2.1 ug/l
207-08-9 Benzo(k)fluoranthene ND 4.2 2.1 ug/l
218-01-9 Chrysene ND 4.2 2.1 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 4.2 2.1 ug/l
206-44-0 Fluoranthene ND 4.2 2.1 ug/l
86-73-7 Fluorene ND 4.2 2.1 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 4.2 2.1 ug/l
91-57-6 2-Methylnaphthalene 18.3 4.2 2.1 ug/l
91-20-3 Naphthalene 51.2 4.2 2.1 ug/l
85-01-8 Phenanthrene ND 4.2 2.1 ug/l
129-00-0 Pyrene ND 4.2 2.1 ug/l
C11-C22 Aromatics (Unadj.)405 210 83 ug/l
C11-C22 Aromatics 335 210 83 ug/l
C9-C18 Aliphatics ND 210 52 ug/l
C19-C36 Aliphatics 62.3 210 52 ug/l J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
3386-33-2 1-Chlorooctadecane 56% a 40-140%
580-13-2 2-Bromonaphthalene 97%40-140%
84-15-1 o-Terphenyl 82% a 40-140%
321-60-8 2-Fluorobiphenyl 92%40-140%
(a) Surrogate recoveries corrected for double spike.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
86 of 129
FA9374333.9
SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Orlando, FL
Section 4
87 of 129
FA937434
FA93743: Chain of Custody
Page 1 of 2
88 of 129
FA9374344.1
Job Number:FA93743 Client:GRI
Date / Time Received:3/9/2022 9:30:00 AM Delivery Method:FX
Project:P&K FOOD MART
Airbill #'s:1009634794093
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
IR Gun
Ice (Bag)
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments
SM001Rev. Date 05/24/17
SGS Sample Receipt Summary
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (2.8); Cooler 2: (3.4);
Cooler 1: (3.2); Cooler 2: (3.8);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230315 pH 10-12 219813A Other: (Specify)
Y or N N/A
Y or N
Therm ID:IR 1; Therm CF:0.4; # of Coolers:2
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:NATHANS Date:Date:3/9/2022 9:30:00 AM
FA93743: Chain of Custody
Page 2 of 2
89 of 129
FA9374344.1
SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
90 of 129
FA937435
Method Blank Summary Page 1 of 3
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3092-MB A0231113.D 1 03/21/22 SS n/a n/a VA3092
The QC reported here applies to the following samples:Method: SM 6200B
FA93743-1, FA93743-2, FA93743-3, FA93743-4, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
64-17-5 Ethyl Alcohol ND 100 65 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
91 of 129
FA9374355.1.1
Method Blank Summary Page 2 of 3
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3092-MB A0231113.D 1 03/21/22 SS n/a n/a VA3092
The QC reported here applies to the following samples:Method: SM 6200B
FA93743-1, FA93743-2, FA93743-3, FA93743-4, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
CAS No.Compound Result RL MDL Units Q
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride 1.0 2.0 1.0 ug/l J
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
92 of 129
FA9374355.1.1
Method Blank Summary Page 3 of 3
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3092-MB A0231113.D 1 03/21/22 SS n/a n/a VA3092
The QC reported here applies to the following samples:Method: SM 6200B
FA93743-1, FA93743-2, FA93743-3, FA93743-4, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 98%70-130%
17060-07-0 1,2-Dichloroethane-D4 104%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
93 of 129
FA9374355.1.1
Method Blank Summary Page 1 of 3
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VN6437-MB N0124869.D 1 03/22/22 LR n/a n/a VN6437
The QC reported here applies to the following samples:Method: SM 6200B
FA93743-1, FA93743-2, FA93743-6
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
94 of 129
FA9374355.1.2
Method Blank Summary Page 2 of 3
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VN6437-MB N0124869.D 1 03/22/22 LR n/a n/a VN6437
The QC reported here applies to the following samples:Method: SM 6200B
FA93743-1, FA93743-2, FA93743-6
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 104%70-130%
17060-07-0 1,2-Dichloroethane-D4 106%70-130%
95 of 129
FA9374355.1.2
Method Blank Summary Page 3 of 3
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VN6437-MB N0124869.D 1 03/22/22 LR n/a n/a VN6437
The QC reported here applies to the following samples:Method: SM 6200B
FA93743-1, FA93743-2, FA93743-6
CAS No.Surrogate Recoveries Limits
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 96%70-130%
96 of 129
FA9374355.1.2
Blank Spike Summary Page 1 of 3
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3092-BS A0231111.D 1 03/21/22 SS n/a n/a VA3092
The QC reported here applies to the following samples:Method: SM 6200B
FA93743-1, FA93743-2, FA93743-3, FA93743-4, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 9.2 92 70-130
108-86-1 Bromobenzene 10 9.0 90 70-130
74-97-5 Bromochloromethane 10 7.5 75 70-130
75-27-4 Bromodichloromethane 10 9.0 90 70-130
75-25-2 Bromoform 10 8.5 85 70-130
104-51-8 n-Butylbenzene 10 8.9 89 70-130
135-98-8 sec-Butylbenzene 10 10.3 103 70-130
98-06-6 tert-Butylbenzene 10 9.8 98 70-130
56-23-5 Carbon Tetrachloride 10 9.4 94 70-130
108-90-7 Chlorobenzene 10 8.8 88 70-130
75-00-3 Chloroethane 10 9.7 97 60-140
67-66-3 Chloroform 10 8.5 85 70-130
95-49-8 o-Chlorotoluene 10 9.3 93 70-130
106-43-4 p-Chlorotoluene 10 9.2 92 70-130
124-48-1 Dibromochloromethane 10 8.6 86 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 8.5 85 70-130
106-93-4 1,2-Dibromoethane 10 8.7 87 70-130
75-71-8 Dichlorodifluoromethane 10 10.5 105 60-140
95-50-1 1,2-Dichlorobenzene 10 8.9 89 70-130
541-73-1 1,3-Dichlorobenzene 10 9.1 91 70-130
106-46-7 1,4-Dichlorobenzene 10 8.7 87 70-130
75-34-3 1,1-Dichloroethane 10 9.0 90 70-130
107-06-2 1,2-Dichloroethane 10 8.6 86 70-130
75-35-4 1,1-Dichloroethylene 10 9.4 94 70-130
156-59-2 cis-1,2-Dichloroethylene 10 8.8 88 70-130
156-60-5 trans-1,2-Dichloroethylene 10 9.1 91 70-130
78-87-5 1,2-Dichloropropane 10 9.2 92 70-130
142-28-9 1,3-Dichloropropane 10 8.7 87 70-130
594-20-7 2,2-Dichloropropane 10 8.6 86 70-130
563-58-6 1,1-Dichloropropene 10 9.6 96 70-130
10061-01-5 cis-1,3-Dichloropropene 10 9.4 94 70-130
10061-02-6 trans-1,3-Dichloropropene 10 9.4 94 70-130
108-20-3 Di-Isopropyl Ether 10 8.3 83 70-130
64-17-5 Ethyl Alcohol 500 623 125 70-130
100-41-4 Ethylbenzene 10 9.2 92 70-130
637-92-3 Ethyl Tert Butyl Ether 10 7.3 73 70-130
* = Outside of Control Limits.
97 of 129
FA9374355.2.1
Blank Spike Summary Page 2 of 3
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3092-BS A0231111.D 1 03/21/22 SS n/a n/a VA3092
The QC reported here applies to the following samples:Method: SM 6200B
FA93743-1, FA93743-2, FA93743-3, FA93743-4, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
87-68-3 Hexachlorobutadiene 10 9.9 99 70-130
98-82-8 Isopropylbenzene 10 9.7 97 70-130
99-87-6 p-Isopropyltoluene 10 9.4 94 70-130
74-83-9 Methyl Bromide 10 9.0 90 60-140
74-87-3 Methyl Chloride 10 9.3 93 60-140
74-95-3 Methylene Bromide 10 8.2 82 70-130
75-09-2 Methylene Chloride 10 9.2 92 70-130
1634-04-4 Methyl Tert Butyl Ether 10 8.0 80 70-130
91-20-3 Naphthalene 10 8.4 84 70-130
103-65-1 n-Propylbenzene 10 9.6 96 70-130
100-42-5 Styrene 10 8.8 88 70-130
75-85-4 Tert-Amyl Alcohol 100 81.9 82 70-130
994-05-8 Tert-Amyl Methyl Ether 10 7.5 75 70-130
75-65-0 Tert-Butyl Alcohol 100 94.3 94 70-130
762-75-4 Tert-Butyl Formate 100 102 102 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 9.1 91 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 8.7 87 70-130
127-18-4 Tetrachloroethylene 10 9.1 91 70-130
108-88-3 Toluene 10 9.1 91 70-130
87-61-6 1,2,3-Trichlorobenzene 10 9.0 90 70-130
120-82-1 1,2,4-Trichlorobenzene 10 9.2 92 70-130
71-55-6 1,1,1-Trichloroethane 10 9.0 90 70-130
79-00-5 1,1,2-Trichloroethane 10 8.7 87 70-130
79-01-6 Trichloroethylene 10 9.3 93 70-130
75-69-4 Trichlorofluoromethane 10 11.9 119 60-140
96-18-4 1,2,3-Trichloropropane 10 8.6 86 70-130
95-63-6 1,2,4-Trimethylbenzene 10 8.7 87 70-130
108-67-8 1,3,5-Trimethylbenzene 10 9.7 97 70-130
75-01-4 Vinyl Chloride 10 9.7 97 60-140
m,p-Xylene 20 18.8 94 70-130
95-47-6 o-Xylene 10 9.2 92 70-130
1330-20-7 Xylene (total)30 28.0 93 70-130
* = Outside of Control Limits.
98 of 129
FA9374355.2.1
Blank Spike Summary Page 3 of 3
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3092-BS A0231111.D 1 03/21/22 SS n/a n/a VA3092
The QC reported here applies to the following samples:Method: SM 6200B
FA93743-1, FA93743-2, FA93743-3, FA93743-4, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 99%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
* = Outside of Control Limits.
99 of 129
FA9374355.2.1
Blank Spike Summary Page 1 of 3
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VN6437-BS N0124867.D 1 03/22/22 LR n/a n/a VN6437
The QC reported here applies to the following samples:Method: SM 6200B
FA93743-1, FA93743-2, FA93743-6
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.1 101 70-130
108-86-1 Bromobenzene 10 9.4 94 70-130
74-97-5 Bromochloromethane 10 8.6 86 70-130
75-27-4 Bromodichloromethane 10 9.7 97 70-130
75-25-2 Bromoform 10 8.9 89 70-130
104-51-8 n-Butylbenzene 10 10.7 107 70-130
135-98-8 sec-Butylbenzene 10 11.3 113 70-130
98-06-6 tert-Butylbenzene 10 10.9 109 70-130
56-23-5 Carbon Tetrachloride 10 10.8 108 70-130
108-90-7 Chlorobenzene 10 9.6 96 70-130
67-66-3 Chloroform 10 9.7 97 70-130
95-49-8 o-Chlorotoluene 10 9.9 99 70-130
106-43-4 p-Chlorotoluene 10 9.6 96 70-130
124-48-1 Dibromochloromethane 10 9.0 90 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 9.2 92 70-130
106-93-4 1,2-Dibromoethane 10 9.1 91 70-130
75-71-8 Dichlorodifluoromethane 10 7.3 73 60-140
95-50-1 1,2-Dichlorobenzene 10 9.7 97 70-130
541-73-1 1,3-Dichlorobenzene 10 9.9 99 70-130
106-46-7 1,4-Dichlorobenzene 10 9.4 94 70-130
75-34-3 1,1-Dichloroethane 10 10.1 101 70-130
107-06-2 1,2-Dichloroethane 10 9.7 97 70-130
75-35-4 1,1-Dichloroethylene 10 11.0 110 70-130
156-59-2 cis-1,2-Dichloroethylene 10 9.9 99 70-130
156-60-5 trans-1,2-Dichloroethylene 10 10.3 103 70-130
78-87-5 1,2-Dichloropropane 10 9.6 96 70-130
142-28-9 1,3-Dichloropropane 10 9.0 90 70-130
594-20-7 2,2-Dichloropropane 10 10.9 109 70-130
563-58-6 1,1-Dichloropropene 10 10.5 105 70-130
10061-01-5 cis-1,3-Dichloropropene 10 9.6 96 70-130
10061-02-6 trans-1,3-Dichloropropene 10 9.6 96 70-130
108-20-3 Di-Isopropyl Ether 10 9.4 94 70-130
100-41-4 Ethylbenzene 10 10.3 103 70-130
637-92-3 Ethyl Tert Butyl Ether 10 8.4 84 70-130
87-68-3 Hexachlorobutadiene 10 12.1 121 70-130
98-82-8 Isopropylbenzene 10 10.7 107 70-130
* = Outside of Control Limits.
100 of 129
FA9374355.2.2
Blank Spike Summary Page 2 of 3
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VN6437-BS N0124867.D 1 03/22/22 LR n/a n/a VN6437
The QC reported here applies to the following samples:Method: SM 6200B
FA93743-1, FA93743-2, FA93743-6
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 10.9 109 70-130
74-83-9 Methyl Bromide 10 8.5 85 60-140
74-87-3 Methyl Chloride 10 8.4 84 60-140
74-95-3 Methylene Bromide 10 8.8 88 70-130
75-09-2 Methylene Chloride 10 11.3 113 70-130
1634-04-4 Methyl Tert Butyl Ether 10 9.1 91 70-130
91-20-3 Naphthalene 10 10.3 103 70-130
103-65-1 n-Propylbenzene 10 10.4 104 70-130
100-42-5 Styrene 10 9.9 99 70-130
75-85-4 Tert-Amyl Alcohol 100 91.8 92 70-130
994-05-8 Tert-Amyl Methyl Ether 10 8.3 83 70-130
75-65-0 Tert-Butyl Alcohol 100 103 103 70-130
762-75-4 Tert-Butyl Formate 100 91.7 92 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 10.2 102 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 10.1 101 70-130
127-18-4 Tetrachloroethylene 10 10.2 102 70-130
108-88-3 Toluene 10 9.9 99 70-130
87-61-6 1,2,3-Trichlorobenzene 10 10.3 103 70-130
120-82-1 1,2,4-Trichlorobenzene 10 10.1 101 70-130
71-55-6 1,1,1-Trichloroethane 10 10.2 102 70-130
79-00-5 1,1,2-Trichloroethane 10 9.4 94 70-130
79-01-6 Trichloroethylene 10 9.9 99 70-130
75-69-4 Trichlorofluoromethane 10 9.9 99 60-140
96-18-4 1,2,3-Trichloropropane 10 9.0 90 70-130
95-63-6 1,2,4-Trimethylbenzene 10 9.9 99 70-130
108-67-8 1,3,5-Trimethylbenzene 10 10.5 105 70-130
75-01-4 Vinyl Chloride 10 8.6 86 60-140
m,p-Xylene 20 20.5 103 70-130
95-47-6 o-Xylene 10 10.1 101 70-130
1330-20-7 Xylene (total)30 30.5 102 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 103%70-130%
17060-07-0 1,2-Dichloroethane-D4 102%70-130%
* = Outside of Control Limits.
101 of 129
FA9374355.2.2
Blank Spike Summary Page 3 of 3
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VN6437-BS N0124867.D 1 03/22/22 LR n/a n/a VN6437
The QC reported here applies to the following samples:Method: SM 6200B
FA93743-1, FA93743-2, FA93743-6
CAS No.Surrogate Recoveries BSP Limits
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 97%70-130%
* = Outside of Control Limits.
102 of 129
FA9374355.2.2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA93854-4MS A0231155.D 5 03/22/22 SS n/a n/a VA3092
FA93854-4MSD A0231156.D 5 03/22/22 SS n/a n/a VA3092
FA93854-4 A0231116.D 1 03/21/22 SS n/a n/a VA3092
The QC reported here applies to the following samples:Method: SM 6200B
FA93743-1, FA93743-2, FA93743-3, FA93743-4, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
FA93854-4 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 0.94 50 55.6 109 50 53.4 105 4 70-130/20
108-86-1 Bromobenzene ND 50 51.5 103 50 51.5 103 0 70-130/20
74-97-5 Bromochloromethane ND 50 44.5 89 50 42.9 86 4 70-130/20
75-27-4 Bromodichloromethane ND 50 50.2 100 50 48.2 96 4 70-130/20
75-25-2 Bromoform ND 50 39.5 79 50 38.4 77 3 70-130/20
104-51-8 n-Butylbenzene 0.22 J 50 51.6 103 50 52.5 105 2 70-130/20
135-98-8 sec-Butylbenzene 0.56 50 61.9 123 50 61.7 122 0 70-130/20
98-06-6 tert-Butylbenzene 0.31 J 50 58.6 117 50 58.6 117 0 70-130/20
56-23-5 Carbon Tetrachloride ND 50 55.6 111 50 54.5 109 2 70-130/20
108-90-7 Chlorobenzene ND 50 52.2 104 50 51.1 102 2 70-130/20
75-00-3 Chloroethane 0.24 J 50 50.6 101 50 52.8 105 4 60-140/20
67-66-3 Chloroform ND 50 50.3 101 50 48.6 97 3 70-130/20
95-49-8 o-Chlorotoluene 0.31 J 50 55.8 111 50 55.6 111 0 70-130/20
106-43-4 p-Chlorotoluene ND 50 53.5 107 50 53.6 107 0 70-130/20
124-48-1 Dibromochloromethane ND 50 44.7 89 50 43.7 87 2 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 50 49.4 99 50 49.3 99 0 70-130/20
106-93-4 1,2-Dibromoethane ND 50 51.0 102 50 50.2 100 2 70-130/20
75-71-8 Dichlorodifluoromethane ND 50 57.2 114 50 59.0 118 3 60-140/20
95-50-1 1,2-Dichlorobenzene ND 50 53.0 106 50 52.4 105 1 70-130/20
541-73-1 1,3-Dichlorobenzene ND 50 53.2 106 50 53.1 106 0 70-130/20
106-46-7 1,4-Dichlorobenzene ND 50 50.2 100 50 50.2 100 0 70-130/20
75-34-3 1,1-Dichloroethane ND 50 53.5 107 50 51.7 103 3 70-130/20
107-06-2 1,2-Dichloroethane ND 50 51.4 103 50 49.3 99 4 70-130/20
75-35-4 1,1-Dichloroethylene ND 50 56.3 113 50 54.0 108 4 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 50 52.8 106 50 51.2 102 3 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 50 54.5 109 50 52.0 104 5 70-130/20
78-87-5 1,2-Dichloropropane ND 50 53.6 107 50 51.8 104 3 70-130/20
142-28-9 1,3-Dichloropropane ND 50 50.9 102 50 49.4 99 3 70-130/20
594-20-7 2,2-Dichloropropane ND 50 53.0 106 50 51.0 102 4 70-130/20
563-58-6 1,1-Dichloropropene ND 50 57.2 114 50 55.6 111 3 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 50 50.6 101 50 49.5 99 2 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 50 53.1 106 50 52.1 104 2 70-130/20
108-20-3 Di-Isopropyl Ether 0.13 J 50 50.3 100 50 49.0 98 3 70-130/20
64-17-5 Ethyl Alcohol ND 2500 3480 139*2500 3380 135*3 70-130/20
100-41-4 Ethylbenzene 0.50 50 55.2 109 50 54.4 108 1 70-130/20
637-92-3 Ethyl Tert Butyl Ether ND 50 43.8 88 50 42.4 85 3 70-130/20
* = Outside of Control Limits.
103 of 129
FA9374355.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA93854-4MS A0231155.D 5 03/22/22 SS n/a n/a VA3092
FA93854-4MSD A0231156.D 5 03/22/22 SS n/a n/a VA3092
FA93854-4 A0231116.D 1 03/21/22 SS n/a n/a VA3092
The QC reported here applies to the following samples:Method: SM 6200B
FA93743-1, FA93743-2, FA93743-3, FA93743-4, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
FA93854-4 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
87-68-3 Hexachlorobutadiene ND 50 56.6 113 50 55.9 112 1 70-130/20
98-82-8 Isopropylbenzene 1.1 50 59.6 117 50 59.0 116 1 70-130/20
99-87-6 p-Isopropyltoluene ND 50 55.2 110 50 55.2 110 0 70-130/20
74-83-9 Methyl Bromide ND 50 52.5 105 50 53.4 107 2 60-140/20
74-87-3 Methyl Chloride ND 50 50.9 102 50 52.9 106 4 60-140/20
74-95-3 Methylene Bromide ND 50 48.1 96 50 46.2 92 4 70-130/20
75-09-2 Methylene Chloride ND 50 52.3 105 50 50.2 100 4 70-130/20
1634-04-4 Methyl Tert Butyl Ether ND 50 47.6 95 50 45.9 92 4 70-130/20
91-20-3 Naphthalene 1.1 50 50.6 99 50 51.5 101 2 70-130/20
103-65-1 n-Propylbenzene 1.1 50 57.3 112 50 57.7 113 1 70-130/20
100-42-5 Styrene ND 50 50.4 101 50 49.4 99 2 70-130/20
75-85-4 Tert-Amyl Alcohol ND 500 479 96 500 473 95 1 70-130/20
994-05-8 Tert-Amyl Methyl Ether ND 50 45.0 90 50 43.8 88 3 70-130/20
75-65-0 Tert-Butyl Alcohol ND 500 569 114 500 571 114 0 70-130/20
762-75-4 Tert-Butyl Formate ND 500 451 90 500 451 90 0 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 50 54.1 108 50 52.9 106 2 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 50 53.2 106 50 52.1 104 2 70-130/20
127-18-4 Tetrachloroethylene ND 50 53.8 108 50 52.4 105 3 70-130/20
108-88-3 Toluene ND 50 54.6 109 50 53.0 106 3 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 50 52.4 105 50 53.0 106 1 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 50 53.7 107 50 54.6 109 2 70-130/20
71-55-6 1,1,1-Trichloroethane ND 50 53.5 107 50 52.0 104 3 70-130/20
79-00-5 1,1,2-Trichloroethane ND 50 52.3 105 50 51.5 103 2 70-130/20
79-01-6 Trichloroethylene ND 50 52.1 104 50 50.1 100 4 70-130/20
75-69-4 Trichlorofluoromethane ND 50 65.3 131 50 68.7 137 5 60-140/20
96-18-4 1,2,3-Trichloropropane ND 50 50.5 101 50 49.8 100 1 70-130/20
95-63-6 1,2,4-Trimethylbenzene 6.1 50 62.2 112 50 61.6 111 1 70-130/20
108-67-8 1,3,5-Trimethylbenzene 2.7 50 62.3 119 50 62.3 119 0 70-130/20
75-01-4 Vinyl Chloride ND 50 53.3 107 50 55.4 111 4 60-140/20
m,p-Xylene 0.89 J 100 114 113 100 111 110 3 70-130/20
95-47-6 o-Xylene 0.47 J 50 56.8 113 50 55.8 111 2 70-130/20
1330-20-7 Xylene (total)1.4 J 150 170 112 150 167 110 2 70-130/20
* = Outside of Control Limits.
104 of 129
FA9374355.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA93854-4MS A0231155.D 5 03/22/22 SS n/a n/a VA3092
FA93854-4MSD A0231156.D 5 03/22/22 SS n/a n/a VA3092
FA93854-4 A0231116.D 1 03/21/22 SS n/a n/a VA3092
The QC reported here applies to the following samples:Method: SM 6200B
FA93743-1, FA93743-2, FA93743-3, FA93743-4, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
CAS No.Surrogate Recoveries MS MSD FA93854-4 Limits
1868-53-7 Dibromofluoromethane 98%99%96%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%99%99%70-130%
2037-26-5 Toluene-D8 100%100%95%70-130%
460-00-4 4-Bromofluorobenzene 102%103%102%70-130%
* = Outside of Control Limits.
105 of 129
FA9374355.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA93741-16MS N0124882.D 200 03/22/22 LR n/a n/a VN6437
FA93741-16MSD N0124883.D 200 03/22/22 LR n/a n/a VN6437
FA93741-16 a N0124874.D 200 03/22/22 LR n/a n/a VN6437
The QC reported here applies to the following samples:Method: SM 6200B
FA93743-1, FA93743-2, FA93743-6
FA93741-16 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 6550 2000 8290 87 2000 8240 85 1 70-130/20
108-86-1 Bromobenzene <100 2000 1950 98 2000 2110 106 8 70-130/20
74-97-5 Bromochloromethane <100 2000 1670 84 2000 1880 94 12 70-130/20
75-27-4 Bromodichloromethane <100 2000 1980 99 2000 2160 108 9 70-130/20
75-25-2 Bromoform <100 2000 1820 91 2000 1970 99 8 70-130/20
104-51-8 n-Butylbenzene <100 2000 2110 106 2000 2210 111 5 70-130/20
135-98-8 sec-Butylbenzene <100 2000 2300 115 2000 2400 120 4 70-130/20
98-06-6 tert-Butylbenzene <100 2000 2230 112 2000 2310 116 4 70-130/20
56-23-5 Carbon Tetrachloride <100 2000 2200 110 2000 2400 120 9 70-130/20
108-90-7 Chlorobenzene <100 2000 2020 101 2000 2110 106 4 70-130/20
67-66-3 Chloroform <100 2000 1970 99 2000 2150 108 9 70-130/20
95-49-8 o-Chlorotoluene <100 2000 2080 104 2000 2170 109 4 70-130/20
106-43-4 p-Chlorotoluene <100 2000 1970 99 2000 2100 105 6 70-130/20
124-48-1 Dibromochloromethane <100 2000 1880 94 2000 1980 99 5 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane <100 2000 1830 92 2000 1990 100 8 70-130/20
106-93-4 1,2-Dibromoethane <100 2000 1920 96 2000 2010 101 5 70-130/20
75-71-8 Dichlorodifluoromethane <100 2000 1550 78 2000 1760 88 13 60-140/20
95-50-1 1,2-Dichlorobenzene <100 2000 2020 101 2000 2120 106 5 70-130/20
541-73-1 1,3-Dichlorobenzene <100 2000 2050 103 2000 2180 109 6 70-130/20
106-46-7 1,4-Dichlorobenzene <100 2000 1960 98 2000 2080 104 6 70-130/20
75-34-3 1,1-Dichloroethane <100 2000 2070 104 2000 2220 111 7 70-130/20
107-06-2 1,2-Dichloroethane 43.6 2000 1990 97 2000 2180 107 9 70-130/20
75-35-4 1,1-Dichloroethylene <100 2000 2300 115 2000 2460 123 7 70-130/20
156-59-2 cis-1,2-Dichloroethylene <100 2000 1990 100 2000 2190 110 10 70-130/20
156-60-5 trans-1,2-Dichloroethylene <100 2000 2150 108 2000 2260 113 5 70-130/20
78-87-5 1,2-Dichloropropane <100 2000 1920 96 2000 2120 106 10 70-130/20
142-28-9 1,3-Dichloropropane <100 2000 1880 94 2000 1990 100 6 70-130/20
594-20-7 2,2-Dichloropropane <100 2000 2110 106 2000 2160 108 2 70-130/20
563-58-6 1,1-Dichloropropene <100 2000 2200 110 2000 2290 115 4 70-130/20
10061-01-5 cis-1,3-Dichloropropene <100 2000 1940 97 2000 2100 105 8 70-130/20
10061-02-6 trans-1,3-Dichloropropene <100 2000 2000 100 2000 2080 104 4 70-130/20
108-20-3 Di-Isopropyl Ether <100 2000 1940 97 2000 2090 105 7 70-130/20
100-41-4 Ethylbenzene 690 2000 2840 108 2000 2890 110 2 70-130/20
637-92-3 Ethyl Tert Butyl Ether <100 2000 1620 81 2000 1810 91 11 70-130/20
87-68-3 Hexachlorobutadiene <100 2000 2500 125 2000 2610 131*4 70-130/20
98-82-8 Isopropylbenzene 79.3 2000 2360 114 2000 2430 118 3 70-130/20
* = Outside of Control Limits.
106 of 129
FA9374355.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA93741-16MS N0124882.D 200 03/22/22 LR n/a n/a VN6437
FA93741-16MSD N0124883.D 200 03/22/22 LR n/a n/a VN6437
FA93741-16 a N0124874.D 200 03/22/22 LR n/a n/a VN6437
The QC reported here applies to the following samples:Method: SM 6200B
FA93743-1, FA93743-2, FA93743-6
FA93741-16 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene <100 2000 2240 112 2000 2350 118 5 70-130/20
74-83-9 Methyl Bromide <100 2000 2350 118 2000 2330 117 1 60-140/20
74-87-3 Methyl Chloride <100 2000 1800 90 2000 2030 102 12 60-140/20
74-95-3 Methylene Bromide <100 2000 1730 87 2000 1930 97 11 70-130/20
75-09-2 Methylene Chloride <400 2000 2370 119 2000 2660 133*12 70-130/20
1634-04-4 Methyl Tert Butyl Ether 985 2000 2630 82 2000 2920 97 10 70-130/20
91-20-3 Naphthalene 218 2000 2360 107 2000 2450 112 4 70-130/20
103-65-1 n-Propylbenzene 100 2000 2220 106 2000 2340 112 5 70-130/20
100-42-5 Styrene <100 2000 2040 102 2000 2190 110 7 70-130/20
75-85-4 Tert-Amyl Alcohol 2450 20000 13700 56*20000 21500 95 44*70-130/20
994-05-8 Tert-Amyl Methyl Ether <200 2000 1640 82 2000 1810 91 10 70-130/20
75-65-0 Tert-Butyl Alcohol 575 20000 14500 70 20000 19700 96 30*70-130/20
762-75-4 Tert-Butyl Formate <2000 20000 16200 81 20000 17500 88 8 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane <100 2000 2140 107 2000 2250 113 5 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane <100 2000 2050 103 2000 2170 109 6 70-130/20
127-18-4 Tetrachloroethylene <100 2000 2160 108 2000 2250 113 4 70-130/20
108-88-3 Toluene 8860 2000 10600 87 2000 10300 72 3 70-130/20
87-61-6 1,2,3-Trichlorobenzene <100 2000 2110 106 2000 2200 110 4 70-130/20
120-82-1 1,2,4-Trichlorobenzene <100 2000 2120 106 2000 2220 111 5 70-130/20
71-55-6 1,1,1-Trichloroethane <100 2000 2070 104 2000 2250 113 8 70-130/20
79-00-5 1,1,2-Trichloroethane <100 2000 1960 98 2000 2050 103 4 70-130/20
79-01-6 Trichloroethylene <100 2000 2060 103 2000 2190 110 6 70-130/20
75-69-4 Trichlorofluoromethane <100 2000 2110 106 2000 2290 115 8 60-140/20
96-18-4 1,2,3-Trichloropropane <100 2000 1860 93 2000 1990 100 7 70-130/20
95-63-6 1,2,4-Trimethylbenzene 71.3 2000 2150 104 2000 2250 109 5 70-130/20
108-67-8 1,3,5-Trimethylbenzene 87.0 2000 2250 108 2000 2330 112 3 70-130/20
75-01-4 Vinyl Chloride <100 2000 1750 88 2000 2000 100 13 60-140/20
m,p-Xylene 573 4000 4920 109 4000 5050 112 3 70-130/20
95-47-6 o-Xylene 835 2000 3000 108 2000 3070 112 2 70-130/20
1330-20-7 Xylene (total)1410 6000 7920 109 6000 8120 112 2 70-130/20
CAS No.Surrogate Recoveries MS MSD FA93741-16 Limits
1868-53-7 Dibromofluoromethane 102%104%100%70-130%
17060-07-0 1,2-Dichloroethane-D4 102%101%104%70-130%
* = Outside of Control Limits.
107 of 129
FA9374355.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA93741-16MS N0124882.D 200 03/22/22 LR n/a n/a VN6437
FA93741-16MSD N0124883.D 200 03/22/22 LR n/a n/a VN6437
FA93741-16 a N0124874.D 200 03/22/22 LR n/a n/a VN6437
The QC reported here applies to the following samples:Method: SM 6200B
FA93743-1, FA93743-2, FA93743-6
CAS No.Surrogate Recoveries MS MSD FA93741-16 Limits
2037-26-5 Toluene-D8 103%102%100%70-130%
460-00-4 4-Bromofluorobenzene 98%97%96%70-130%
(a) Internal standard areas outside method criteria. Confirmation run.
* = Outside of Control Limits.
108 of 129
FA9374355.3.2
SGS North America Inc.
MS Semi-volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 6
109 of 129
FA937436
Method Blank Summary Page 1 of 2
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP90179-MB 6F13648.D 1 03/10/22 WH 03/10/22 OP90179 S6F508
The QC reported here applies to the following samples:Method: EPA 625.1
FA93743-1, FA93743-2, FA93743-3, FA93743-4, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
CAS No.Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 50 10 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 5.0 0.59 ug/l
95-57-8 2-Chlorophenol ND 5.0 0.63 ug/l
120-83-2 2,4-Dichlorophenol ND 5.0 0.84 ug/l
105-67-9 2,4-Dimethylphenol ND 5.0 0.74 ug/l
51-28-5 2,4-Dinitrophenol ND 25 5.0 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 10 2.0 ug/l
95-48-7 2-Methylphenol ND 5.0 0.56 ug/l
3&4-Methylphenol ND 5.0 0.98 ug/l
88-75-5 2-Nitrophenol ND 5.0 0.85 ug/l
100-02-7 4-Nitrophenol ND 25 5.0 ug/l
87-86-5 Pentachlorophenol ND 25 5.0 ug/l
108-95-2 Phenol ND 5.0 0.50 ug/l
88-06-2 2,4,6-Trichlorophenol ND 5.0 0.75 ug/l
83-32-9 Acenaphthene ND 5.0 0.63 ug/l
208-96-8 Acenaphthylene ND 5.0 0.64 ug/l
120-12-7 Anthracene ND 5.0 0.80 ug/l
56-55-3 Benzo(a)anthracene ND 5.0 0.76 ug/l
50-32-8 Benzo(a)pyrene ND 5.0 0.78 ug/l
205-99-2 Benzo(b)fluoranthene ND 5.0 0.78 ug/l
191-24-2 Benzo(g,h,i)perylene ND 5.0 0.82 ug/l
207-08-9 Benzo(k)fluoranthene ND 5.0 0.86 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 5.0 0.85 ug/l
85-68-7 Butyl Benzyl Phthalate ND 5.0 1.0 ug/l
106-47-8 4-Chloroaniline ND 5.0 0.63 ug/l
111-91-1 bis(2-Chloroethoxy)methane ND 5.0 0.81 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 5.0 0.73 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane)ND 5.0 0.76 ug/l
91-58-7 2-Chloronaphthalene ND 5.0 0.50 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether ND 5.0 0.54 ug/l
218-01-9 Chrysene ND 5.0 0.85 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 5.0 0.80 ug/l
132-64-9 Dibenzofuran ND 5.0 0.60 ug/l
91-94-1 3,3'-Dichlorobenzidine ND 5.0 0.64 ug/l
84-66-2 Diethyl Phthalate ND 5.0 1.0 ug/l
131-11-3 Dimethyl Phthalate ND 5.0 1.0 ug/l
110 of 129
FA9374366.1.1
Method Blank Summary Page 2 of 2
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP90179-MB 6F13648.D 1 03/10/22 WH 03/10/22 OP90179 S6F508
The QC reported here applies to the following samples:Method: EPA 625.1
FA93743-1, FA93743-2, FA93743-3, FA93743-4, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
CAS No.Compound Result RL MDL Units Q
84-74-2 Di-n-butyl Phthalate ND 5.0 1.0 ug/l
117-84-0 Di-n-octyl Phthalate ND 5.0 1.0 ug/l
121-14-2 2,4-Dinitrotoluene ND 5.0 0.81 ug/l
606-20-2 2,6-Dinitrotoluene ND 5.0 0.71 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate ND 5.0 1.0 ug/l
206-44-0 Fluoranthene ND 5.0 0.55 ug/l
86-73-7 Fluorene ND 5.0 0.70 ug/l
118-74-1 Hexachlorobenzene ND 5.0 0.69 ug/l
87-68-3 Hexachlorobutadiene ND 5.0 0.50 ug/l
77-47-4 Hexachlorocyclopentadiene ND 5.0 1.8 ug/l
67-72-1 Hexachloroethane ND 5.0 1.6 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 5.0 0.71 ug/l
78-59-1 Isophorone ND 5.0 0.78 ug/l
90-12-0 1-Methylnaphthalene ND 5.0 0.53 ug/l
91-57-6 2-Methylnaphthalene ND 5.0 0.60 ug/l
91-20-3 Naphthalene ND 5.0 0.50 ug/l
98-95-3 Nitrobenzene ND 5.0 0.93 ug/l
621-64-7 N-Nitrosodi-n-propylamine ND 5.0 0.67 ug/l
86-30-6 N-Nitrosodiphenylamine ND 5.0 0.81 ug/l
85-01-8 Phenanthrene ND 5.0 0.86 ug/l
129-00-0 Pyrene ND 5.0 0.68 ug/l
CAS No.Surrogate Recoveries Limits
367-12-4 2-Fluorophenol 40%14-67%
4165-62-2 Phenol-d5 29%10-50%
118-79-6 2,4,6-Tribromophenol 87%33-118%
4165-60-0 Nitrobenzene-d5 84%42-108%
321-60-8 2-Fluorobiphenyl 80%40-106%
1718-51-0 Terphenyl-d14 95%39-121%
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
Total TIC, Semi-Volatile 0 ug/l
111 of 129
FA9374366.1.1
Blank Spike Summary Page 1 of 2
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP90179-BS 6F13647.D 1 03/10/22 WH 03/10/22 OP90179 S6F508
The QC reported here applies to the following samples:Method: EPA 625.1
FA93743-1, FA93743-2, FA93743-3, FA93743-4, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
65-85-0 Benzoic Acid 100 28.5 29 10-69
59-50-7 4-Chloro-3-methyl Phenol 50 45.3 91 54-103
95-57-8 2-Chlorophenol 50 37.5 75 52-98
120-83-2 2,4-Dichlorophenol 50 45.1 90 53-103
105-67-9 2,4-Dimethylphenol 50 43.2 86 43-90
51-28-5 2,4-Dinitrophenol 100 68.4 68 44-112
534-52-1 4,6-Dinitro-o-cresol 100 90.8 91 66-121
95-48-7 2-Methylphenol 50 32.9 66 43-90
3&4-Methylphenol 100 63.2 63 36-88
88-75-5 2-Nitrophenol 50 43.5 87 53-102
100-02-7 4-Nitrophenol 100 54.7 55 18-62
87-86-5 Pentachlorophenol 100 93.1 93 61-115
108-95-2 Phenol 50 18.8 38 19-56
88-06-2 2,4,6-Trichlorophenol 50 47.3 95 59-107
83-32-9 Acenaphthene 50 42.5 85 61-107
208-96-8 Acenaphthylene 50 42.8 86 60-104
120-12-7 Anthracene 50 43.6 87 65-108
56-55-3 Benzo(a)anthracene 50 44.9 90 66-111
50-32-8 Benzo(a)pyrene 50 43.2 86 62-107
205-99-2 Benzo(b)fluoranthene 50 48.3 97 65-114
191-24-2 Benzo(g,h,i)perylene 50 46.0 92 66-116
207-08-9 Benzo(k)fluoranthene 50 45.8 92 65-114
101-55-3 4-Bromophenyl Phenyl Ether 50 41.7 83 65-109
85-68-7 Butyl Benzyl Phthalate 50 52.2 104 65-112
106-47-8 4-Chloroaniline 50 37.9 76 49-105
111-91-1 bis(2-Chloroethoxy)methane 50 41.8 84 51-102
111-44-4 bis(2-Chloroethyl)ether 50 39.4 79 53-100
108-60-1 2,2'-Oxybis(1-chloropropane)50 42.8 86 45-106
91-58-7 2-Chloronaphthalene 50 42.5 85 57-103
7005-72-3 4-Chlorophenyl Phenyl Ether 50 42.2 84 62-105
218-01-9 Chrysene 50 45.5 91 66-111
53-70-3 Dibenzo(a,h)anthracene 50 47.2 94 66-119
132-64-9 Dibenzofuran 50 42.6 85 61-106
91-94-1 3,3'-Dichlorobenzidine 50 45.7 91 46-117
84-66-2 Diethyl Phthalate 50 46.5 93 64-108
131-11-3 Dimethyl Phthalate 50 44.2 88 63-106
* = Outside of Control Limits.
112 of 129
FA9374366.2.1
Blank Spike Summary Page 2 of 2
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP90179-BS 6F13647.D 1 03/10/22 WH 03/10/22 OP90179 S6F508
The QC reported here applies to the following samples:Method: EPA 625.1
FA93743-1, FA93743-2, FA93743-3, FA93743-4, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
84-74-2 Di-n-butyl Phthalate 50 47.8 96 65-107
117-84-0 Di-n-octyl Phthalate 50 57.3 115 62-118
121-14-2 2,4-Dinitrotoluene 50 49.8 100 61-110
606-20-2 2,6-Dinitrotoluene 50 45.5 91 63-108
117-81-7 bis(2-Ethylhexyl)phthalate 50 52.7 105 61-117
206-44-0 Fluoranthene 50 44.0 88 63-106
86-73-7 Fluorene 50 45.3 91 62-108
118-74-1 Hexachlorobenzene 50 40.3 81 63-108
87-68-3 Hexachlorobutadiene 50 40.9 82 42-102
77-47-4 Hexachlorocyclopentadiene 50 32.8 66 39-102
67-72-1 Hexachloroethane 50 40.5 81 42-100
193-39-5 Indeno(1,2,3-cd)pyrene 50 51.1 102 64-119
78-59-1 Isophorone 50 45.4 91*43-87
90-12-0 1-Methylnaphthalene 50 40.9 82 53-102
91-57-6 2-Methylnaphthalene 50 42.6 85 51-102
91-20-3 Naphthalene 50 40.5 81 47-100
98-95-3 Nitrobenzene 50 44.3 89 50-104
621-64-7 N-Nitrosodi-n-propylamine 50 43.3 87 52-104
86-30-6 N-Nitrosodiphenylamine 50 41.7 83 64-108
85-01-8 Phenanthrene 50 44.4 89 66-110
129-00-0 Pyrene 50 48.6 97 64-113
CAS No.Surrogate Recoveries BSP Limits
367-12-4 2-Fluorophenol 45%14-67%
4165-62-2 Phenol-d5 32%10-50%
118-79-6 2,4,6-Tribromophenol 87%33-118%
4165-60-0 Nitrobenzene-d5 84%42-108%
321-60-8 2-Fluorobiphenyl 81%40-106%
1718-51-0 Terphenyl-d14 87%39-121%
* = Outside of Control Limits.
113 of 129
FA9374366.2.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP90179-MS 6F13650.D 1 03/10/22 WH 03/10/22 OP90179 S6F508
OP90179-MSD 6F13651.D 1 03/10/22 WH 03/10/22 OP90179 S6F508
FA93727-1 a 6F13675.D 5 03/16/22 WH 03/10/22 OP90179 S6F510
The QC reported here applies to the following samples:Method: EPA 625.1
FA93743-1, FA93743-2, FA93743-3, FA93743-4, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
FA93727-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
65-85-0 Benzoic Acid ND 192 131 68 192 112 58 16 10-69/39
59-50-7 4-Chloro-3-methyl Phenol ND 96.2 109 113*96.2 111 115*2 54-103/23
95-57-8 2-Chlorophenol ND 96.2 78.4 82 96.2 79.7 83 2 52-98/25
120-83-2 2,4-Dichlorophenol ND 96.2 88.1 92 96.2 90.6 94 3 53-103/26
105-67-9 2,4-Dimethylphenol 151 96.2 218 70 96.2 252 105*14 43-90/27
51-28-5 2,4-Dinitrophenol ND 192 169 88 192 170 88 1 44-112/25
534-52-1 4,6-Dinitro-o-cresol ND 192 197 102 192 203 106 3 66-121/23
95-48-7 2-Methylphenol 63.1 96.2 153 93*96.2 172 113*12 43-90/28
3&4-Methylphenol 49.6 192 210 83 192 226 92*7 36-88/28
88-75-5 2-Nitrophenol ND 96.2 84.1 87 96.2 85.5 89 2 53-102/29
100-02-7 4-Nitrophenol ND 192 162 84*192 154 80*5 18-62/33
87-86-5 Pentachlorophenol ND 192 195 101 192 198 103 2 61-115/26
108-95-2 Phenol 32.9 96.2 129 100*96.2 128 99*1 19-56/35
88-06-2 2,4,6-Trichlorophenol ND 96.2 88.2 92 96.2 88.8 92 1 59-107/23
83-32-9 Acenaphthene ND 96.2 80.8 84 96.2 85.5 89 6 61-107/22
208-96-8 Acenaphthylene ND 96.2 80.2 83 96.2 85.1 89 6 60-104/22
120-12-7 Anthracene ND 96.2 82.0 85 96.2 87.1 91 6 65-108/20
56-55-3 Benzo(a)anthracene ND 96.2 86.3 90 96.2 91.7 95 6 66-111/22
50-32-8 Benzo(a)pyrene ND 96.2 81.6 85 96.2 85.4 89 5 62-107/23
205-99-2 Benzo(b)fluoranthene ND 96.2 90.4 94 96.2 96.0 100 6 65-114/23
191-24-2 Benzo(g,h,i)perylene ND 96.2 87.7 91 96.2 91.0 95 4 66-116/23
207-08-9 Benzo(k)fluoranthene ND 96.2 87.0 90 96.2 89.7 93 3 65-114/24
101-55-3 4-Bromophenyl Phenyl Ether ND 96.2 78.8 82 96.2 85.5 89 8 65-109/23
85-68-7 Butyl Benzyl Phthalate ND 96.2 101 105 96.2 106 110 5 65-112/24
106-47-8 4-Chloroaniline ND 96.2 51.3 53 96.2 52.5 55 2 49-105/27
111-91-1 bis(2-Chloroethoxy)methane ND 96.2 78.6 82 96.2 84.3 88 7 51-102/28
111-44-4 bis(2-Chloroethyl)ether 4.5 J 96.2 80.6 79 96.2 81.9 80 2 53-100/27
108-60-1 2,2'-Oxybis(1-chloropropane)ND 96.2 79.5 83 96.2 83.9 87 5 45-106/26
91-58-7 2-Chloronaphthalene ND 96.2 80.5 84 96.2 85.5 89 6 57-103/23
7005-72-3 4-Chlorophenyl Phenyl Ether ND 96.2 77.1 80 96.2 81.4 85 5 62-105/20
218-01-9 Chrysene ND 96.2 87.2 91 96.2 93.4 97 7 66-111/22
53-70-3 Dibenzo(a,h)anthracene ND 96.2 90.2 94 96.2 93.9 98 4 66-119/24
132-64-9 Dibenzofuran ND 96.2 79.1 82 96.2 84.5 88 7 61-106/21
84-66-2 Diethyl Phthalate ND 96.2 87.5 91 96.2 90.5 94 3 64-108/21
131-11-3 Dimethyl Phthalate ND 96.2 81.8 85 96.2 85.0 88 4 63-106/22
84-74-2 Di-n-butyl Phthalate ND 96.2 90.8 94 96.2 95.9 100 5 65-107/21
* = Outside of Control Limits.
114 of 129
FA9374366.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP90179-MS 6F13650.D 1 03/10/22 WH 03/10/22 OP90179 S6F508
OP90179-MSD 6F13651.D 1 03/10/22 WH 03/10/22 OP90179 S6F508
FA93727-1 a 6F13675.D 5 03/16/22 WH 03/10/22 OP90179 S6F510
The QC reported here applies to the following samples:Method: EPA 625.1
FA93743-1, FA93743-2, FA93743-3, FA93743-4, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
FA93727-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
117-84-0 Di-n-octyl Phthalate ND 96.2 107 111 96.2 114 119*6 62-118/24
121-14-2 2,4-Dinitrotoluene ND 96.2 92.1 96 96.2 97.1 101 5 61-110/21
606-20-2 2,6-Dinitrotoluene ND 96.2 86.0 89 96.2 92.2 96 7 63-108/21
117-81-7 bis(2-Ethylhexyl)phthalate ND 96.2 103 107 96.2 109 113 6 61-117/23
206-44-0 Fluoranthene ND 96.2 83.5 87 96.2 87.5 91 5 63-106/21
86-73-7 Fluorene ND 96.2 86.3 90 96.2 90.2 94 4 62-108/20
118-74-1 Hexachlorobenzene ND 96.2 75.8 79 96.2 81.4 85 7 63-108/22
87-68-3 Hexachlorobutadiene ND 96.2 77.4 80 96.2 81.6 85 5 42-102/28
77-47-4 Hexachlorocyclopentadiene ND 96.2 59.5 62 96.2 65.7 68 10 39-102/29
67-72-1 Hexachloroethane ND 96.2 75.3 78 96.2 80.2 83 6 42-100/29
193-39-5 Indeno(1,2,3-cd)pyrene ND 96.2 96.1 100 96.2 102 106 6 64-119/24
78-59-1 Isophorone ND 96.2 91.1 95*96.2 97.8 102*7 43-87/25
90-12-0 1-Methylnaphthalene ND 96.2 78.2 81 96.2 84.3 88 8 53-102/27
91-57-6 2-Methylnaphthalene ND 96.2 81.2 84 96.2 88.0 92 8 51-102/26
91-20-3 Naphthalene 4.1 J 96.2 80.0 79 96.2 85.6 85 7 47-100/29
98-95-3 Nitrobenzene ND 96.2 121 126*96.2 138 144*13 50-104/28
621-64-7 N-Nitrosodi-n-propylamine ND 96.2 81.3 85 96.2 89.0 93 9 52-104/25
86-30-6 N-Nitrosodiphenylamine ND 96.2 81.3 85 96.2 84.8 88 4 64-108/23
85-01-8 Phenanthrene ND 96.2 84.4 88 96.2 89.4 93 6 66-110/21
129-00-0 Pyrene ND 96.2 94.4 98 96.2 98.9 103 5 64-113/23
CAS No.Surrogate Recoveries MS MSD FA93727-1 Limits
367-12-4 2-Fluorophenol 60%51%27%14-67%
4165-62-2 Phenol-d5 56%* b 55%* b 33%10-50%
118-79-6 2,4,6-Tribromophenol 86%87%58%33-118%
4165-60-0 Nitrobenzene-d5 87%94%90%42-108%
321-60-8 2-Fluorobiphenyl 78%84%76%40-106%
1718-51-0 Terphenyl-d14 87%92%74%39-121%
(a) Dilution required due to matrix interference.
(b) Outside control limits.
* = Outside of Control Limits.
115 of 129
FA9374366.3.1
SGS North America Inc.
GC Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 7
116 of 129
FA937437
Method Blank Summary Page 1 of 1
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1U398-MB 1U8979.D 1 03/16/22 JR n/a n/a G1U398
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA93743-2, FA93743-3, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 1.0 1.0 ug/l
100-41-4 Ethylbenzene ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 2.0 1.0 ug/l
91-20-3 Naphthalene ND 5.0 3.0 ug/l
108-88-3 Toluene ND 2.0 1.0 ug/l
m,p-Xylene ND 4.0 2.0 ug/l
95-47-6 o-Xylene ND 2.0 1.0 ug/l
C5- C8 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C12 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C10 Aromatics (Unadj.)ND 100 35 ug/l
C5- C8 Aliphatics ND 100 35 ug/l
C9- C12 Aliphatics ND 100 35 ug/l
C9- C10 Aromatics ND 100 35 ug/l
CAS No.Surrogate Recoveries Limits
460-00-4 BFB 90%70-130%
460-00-4 BFB 76%70-130%
117 of 129
FA9374377.1.1
Method Blank Summary Page 1 of 1
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1U400-MB 1U9037.D 1 03/17/22 JR n/a n/a G1U400
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA93743-1, FA93743-4, FA93743-7, FA93743-8
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 1.0 1.0 ug/l
100-41-4 Ethylbenzene ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 2.0 1.0 ug/l
91-20-3 Naphthalene ND 5.0 3.0 ug/l
108-88-3 Toluene ND 2.0 1.0 ug/l
m,p-Xylene ND 4.0 2.0 ug/l
95-47-6 o-Xylene ND 2.0 1.0 ug/l
C5- C8 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C12 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C10 Aromatics (Unadj.)ND 100 35 ug/l
C5- C8 Aliphatics ND 100 35 ug/l
C9- C12 Aliphatics ND 100 35 ug/l
C9- C10 Aromatics ND 100 35 ug/l
CAS No.Surrogate Recoveries Limits
460-00-4 BFB 89%70-130%
460-00-4 BFB 75%70-130%
118 of 129
FA9374377.1.2
Method Blank Summary Page 1 of 1
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1U401-MB 1U9078.D 1 03/18/22 JR n/a n/a G1U401
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA93743-4, FA93743-7, FA93743-8, FA93743-9
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 1.0 1.0 ug/l
100-41-4 Ethylbenzene ND 2.0 1.0 ug/l
C5- C8 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C12 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C10 Aromatics (Unadj.)ND 100 35 ug/l
C5- C8 Aliphatics ND 100 35 ug/l
C9- C10 Aromatics ND 100 35 ug/l
CAS No.Surrogate Recoveries Limits
460-00-4 BFB 88%70-130%
460-00-4 BFB 75%70-130%
119 of 129
FA9374377.1.3
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1U398-BS 1U8977.D 1 03/16/22 JR n/a n/a G1U398
G1U398-BSD 1U8978.D 1 03/16/22 JR n/a n/a G1U398
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA93743-2, FA93743-3, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
71-43-2 Benzene 80 74.7 93 78.4 98 5 70-130/25
100-41-4 Ethylbenzene 80 73.9 92 77.7 97 5 70-130/25
1634-04-4 Methyl Tert Butyl Ether 80 66.7 83 72.2 90 8 70-130/25
91-20-3 Naphthalene 80 67.2 84 75.5 94 12 70-130/25
108-88-3 Toluene 80 72.0 90 75.8 95 5 70-130/25
m,p-Xylene 160 149 93 157 98 5 70-130/25
95-47-6 o-Xylene 80 74.6 93 78.6 98 5 70-130/25
C5- C8 Aliphatics (Unadj.)240 265 110 278 116 5 70-130/25
C9- C12 Aliphatics (Unadj.)160 191 119 201 126 5 70-130/25
C9- C10 Aromatics (Unadj.)80 67.6 85 71.5 89 6 70-130/25
C9- C10 Aromatics 80 67.6 85 71.5 89 6 70-130/25
CAS No.Surrogate Recoveries BSP BSD Limits
460-00-4 BFB 109%110%70-130%
460-00-4 BFB 95%95%70-130%
* = Outside of Control Limits.
120 of 129
FA9374377.2.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1U400-BS 1U9035.D 1 03/17/22 JR n/a n/a G1U400
G1U400-BSD 1U9036.D 1 03/17/22 JR n/a n/a G1U400
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA93743-1, FA93743-4, FA93743-7, FA93743-8
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
71-43-2 Benzene 80 71.1 89 77.0 96 8 70-130/25
100-41-4 Ethylbenzene 80 70.6 88 76.7 96 8 70-130/25
1634-04-4 Methyl Tert Butyl Ether 80 64.8 81 71.3 89 10 70-130/25
91-20-3 Naphthalene 80 71.2 89 80.2 100 12 70-130/25
108-88-3 Toluene 80 69.2 87 74.9 94 8 70-130/25
m,p-Xylene 160 143 89 155 97 8 70-130/25
95-47-6 o-Xylene 80 71.5 89 77.5 97 8 70-130/25
C5- C8 Aliphatics (Unadj.)240 245 102 269 112 9 70-130/25
C9- C12 Aliphatics (Unadj.)160 176 110 195 122 10 70-130/25
C9- C10 Aromatics (Unadj.)80 64.8 81 70.5 88 8 70-130/25
C9- C10 Aromatics 80 64.8 81 70.5 88 8 70-130/25
CAS No.Surrogate Recoveries BSP BSD Limits
460-00-4 BFB 102%107%70-130%
460-00-4 BFB 90%94%70-130%
* = Outside of Control Limits.
121 of 129
FA9374377.2.2
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1U401-BS 1U9076.D 1 03/18/22 JR n/a n/a G1U401
G1U401-BSD 1U9077.D 1 03/18/22 JR n/a n/a G1U401
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA93743-4, FA93743-7, FA93743-8, FA93743-9
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
71-43-2 Benzene 80 71.2 89 78.1 98 9 70-130/25
100-41-4 Ethylbenzene 80 71.0 89 77.9 97 9 70-130/25
C5- C8 Aliphatics (Unadj.)240 239 100 265 110 10 70-130/25
C9- C12 Aliphatics (Unadj.)160 172 108 191 119 10 70-130/25
C9- C10 Aromatics (Unadj.)80 65.3 82 72.5 91 10 70-130/25
C9- C10 Aromatics 80 65.3 82 72.5 91 10 70-130/25
CAS No.Surrogate Recoveries BSP BSD Limits
460-00-4 BFB 105%111%70-130%
460-00-4 BFB 95%99%70-130%
* = Outside of Control Limits.
122 of 129
FA9374377.2.3
Duplicate Summary Page 1 of 1
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA93272-3DUP 1U9006.D 2 03/17/22 JR n/a n/a G1U398
FA93272-3 a 1U9005.D 2 03/17/22 JR n/a n/a G1U398
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA93743-2, FA93743-3, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
FA93272-3 DUP
CAS No.Compound ug/l Q ug/l Q RPD Limits
71-43-2 Benzene 5.0 4.5 11 50
100-41-4 Ethylbenzene 19.2 19.2 0 50
1634-04-4 Methyl Tert Butyl Ether ND ND nc 50
91-20-3 Naphthalene ND ND nc 50
108-88-3 Toluene 48.9 50.7 4 50
m,p-Xylene 77.1 77.8 1 50
95-47-6 o-Xylene 34.1 34.9 2 50
C5- C8 Aliphatics (Unadj.)913 927 2 50
C9- C12 Aliphatics (Unadj.)ND ND nc 50
C9- C10 Aromatics (Unadj.)96.4 J 94.4 J 2 50
C5- C8 Aliphatics 859 872 2 50
C9- C12 Aliphatics ND ND nc 50
C9- C10 Aromatics 96.4 J 94.4 J 2 50
CAS No.Surrogate Recoveries DUP FA93272-3 Limits
460-00-4 BFB 104%105%70-130%
460-00-4 BFB 91%91%70-130%
(a) Sample re-analyzed beyond hold time; reported results are considered minimum values.
* = Outside of Control Limits.
123 of 129
FA9374377.3.1
Duplicate Summary Page 1 of 1
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA93561-5DUP 1U9044.D 1 03/17/22 JR n/a n/a G1U400
FA93561-5 a 1U9043.D 1 03/17/22 JR n/a n/a G1U400
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA93743-1, FA93743-4, FA93743-7, FA93743-8
FA93561-5 DUP
CAS No.Compound ug/l Q ug/l Q RPD Limits
71-43-2 Benzene ND ND nc 50
100-41-4 Ethylbenzene ND ND nc 50
1634-04-4 Methyl Tert Butyl Ether ND ND nc 50
91-20-3 Naphthalene ND ND nc 50
108-88-3 Toluene ND ND nc 50
m,p-Xylene ND ND nc 50
95-47-6 o-Xylene ND ND nc 50
C5- C8 Aliphatics (Unadj.)ND ND nc 50
C9- C12 Aliphatics (Unadj.)ND ND nc 50
C9- C10 Aromatics (Unadj.)ND ND nc 50
C5- C8 Aliphatics ND ND nc 50
C9- C12 Aliphatics ND ND nc 50
C9- C10 Aromatics ND ND nc 50
CAS No.Surrogate Recoveries DUP FA93561-5 Limits
460-00-4 BFB 97%102%70-130%
460-00-4 BFB 87%90%70-130%
(a) Confirmation run beyond holdtime.
* = Outside of Control Limits.
124 of 129
FA9374377.3.2
Duplicate Summary Page 1 of 1
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA93854-3DUP 1U9087.D 50 03/18/22 JR n/a n/a G1U401
FA93854-3 1U9079.D 10 03/18/22 JR n/a n/a G1U401
FA93854-3 1U9086.D 50 03/18/22 JR n/a n/a G1U401
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA93743-4, FA93743-7, FA93743-8, FA93743-9
FA93854-3 DUP
CAS No.Compound ug/l Q ug/l Q RPD Limits
71-43-2 Benzene 7930 E 8560 8 50
100-41-4 Ethylbenzene 1770 1710 3 50
C5- C8 Aliphatics (Unadj.)26500 E 24500 8 50
C9- C12 Aliphatics (Unadj.)4620 4570 J 1 50
C9- C10 Aromatics (Unadj.)2950 2550 J 15 50
C5- C8 Aliphatics 5440 E ND 200*50
C9- C10 Aromatics 2950 2550 J 15 50
CAS No.Surrogate Recoveries DUP FA93854-3 FA93854-3 Limits
460-00-4 BFB 103%96%99%70-130%
460-00-4 BFB 92%79%89%70-130%
* = Outside of Control Limits.
125 of 129
FA9374377.3.3
SGS North America Inc.
GC/LC Semi-volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 8
126 of 129
FA937438
Method Blank Summary Page 1 of 1
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP90180-MB NN037776.D 1 03/11/22 AF 03/10/22 OP90180 GNN1768
The QC reported here applies to the following samples:Method: MADEP EPH REV 2.1
FA93743-1, FA93743-2, FA93743-3, FA93743-4, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
CAS No.Compound Result RL MDL Units Q
83-32-9 Acenaphthene ND 4.0 2.0 ug/l
208-96-8 Acenaphthylene ND 4.0 2.0 ug/l
120-12-7 Anthracene ND 4.0 2.0 ug/l
56-55-3 Benzo(a)anthracene ND 4.0 2.0 ug/l
50-32-8 Benzo(a)pyrene ND 4.0 2.0 ug/l
205-99-2 Benzo(b)fluoranthene ND 4.0 2.0 ug/l
191-24-2 Benzo(g,h,i)perylene ND 4.0 2.0 ug/l
207-08-9 Benzo(k)fluoranthene ND 4.0 2.0 ug/l
218-01-9 Chrysene ND 4.0 2.0 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 4.0 2.0 ug/l
206-44-0 Fluoranthene ND 4.0 2.0 ug/l
86-73-7 Fluorene ND 4.0 2.0 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 4.0 2.0 ug/l
91-57-6 2-Methylnaphthalene ND 4.0 2.0 ug/l
91-20-3 Naphthalene ND 4.0 2.0 ug/l
85-01-8 Phenanthrene ND 4.0 2.0 ug/l
129-00-0 Pyrene ND 4.0 2.0 ug/l
C11-C22 Aromatics (Unadj.)ND 200 80 ug/l
C11-C22 Aromatics ND 200 80 ug/l
C9-C18 Aliphatics ND 200 50 ug/l
C19-C36 Aliphatics ND 200 50 ug/l
CAS No.Surrogate Recoveries Limits
3386-33-2 1-Chlorooctadecane 59% a 40-140%
580-13-2 2-Bromonaphthalene 120%40-140%
84-15-1 o-Terphenyl 92% a 40-140%
321-60-8 2-Fluorobiphenyl 115%40-140%
(a) Surrogate recoveries corrected for double spike.
127 of 129
FA9374388.1.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 2
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP90180-BS NN037777.D 1 03/11/22 AF 03/10/22 OP90180 GNN1768
OP90180-BSD NN037778.D 1 03/11/22 AF 03/10/22 OP90180 GNN1768
The QC reported here applies to the following samples:Method: MADEP EPH REV 2.1
FA93743-1, FA93743-2, FA93743-3, FA93743-4, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
83-32-9 Acenaphthene 100 87.1 87 84.5 85 3 40-140/30
208-96-8 Acenaphthylene 100 88.7 89 85.9 86 3 40-140/30
120-12-7 Anthracene 100 92.5 93 90.0 90 3 40-140/30
56-55-3 Benzo(a)anthracene 100 101 101 98.3 98 3 40-140/30
50-32-8 Benzo(a)pyrene 100 97.0 97 94.8 95 2 40-140/30
205-99-2 Benzo(b)fluoranthene 100 114 114 112 112 2 40-140/30
191-24-2 Benzo(g,h,i)perylene 100 95.1 95 92.7 93 3 40-140/30
207-08-9 Benzo(k)fluoranthene 100 84.1 84 81.9 82 3 40-140/30
218-01-9 Chrysene 100 101 101 97.9 98 3 40-140/30
53-70-3 Dibenzo(a,h)anthracene 100 99.8 100 97.3 97 3 40-140/30
206-44-0 Fluoranthene 100 96.7 97 94.3 94 3 40-140/30
86-73-7 Fluorene 100 90.0 90 87.3 87 3 40-140/30
193-39-5 Indeno(1,2,3-cd)pyrene 100 96.4 96 94.3 94 2 40-140/30
91-57-6 2-Methylnaphthalene 100 77.5 78 74.0 74 5 40-140/30
91-20-3 Naphthalene 100 72.1 72 67.7 68 6 40-140/30
85-01-8 Phenanthrene 100 93.6 94 91.2 91 3 40-140/30
129-00-0 Pyrene 100 100 100 97.7 98 2 40-140/30
C11-C22 Aromatics (Unadj.)1700 1620 95 1590 94 2 40-140/30
C9-C18 Aliphatics 600 358 60 362 60 1 40-140/30
C19-C36 Aliphatics 800 683 85 690 86 1 40-140/30
CAS No.Surrogate Recoveries BSP BSD Limits
3386-33-2 1-Chlorooctadecane 64% a 67% a 40-140%
580-13-2 2-Bromonaphthalene 99%94%40-140%
84-15-1 o-Terphenyl 93% a 91% a 40-140%
321-60-8 2-Fluorobiphenyl 95%89%40-140%
Sample Compound Col #1 Col #2 Breakthrough Limit
OP90180-BS 2-Methylnaphthalene 77.5 ND 0.0%5.0
OP90180-BS Naphthalene 72.1 ND 0.0%5.0
OP90180-BSD 2-Methylnaphthalene 74.0 ND 0.0%5.0
OP90180-BSD Naphthalene 67.7 ND 0.0%5.0
* = Outside of Control Limits.
128 of 129
FA9374388.2.1
Blank Spike/Blank Spike Duplicate Summary Page 2 of 2
Job Number:FA93743
Account:GRINCC GRI (Geological Resources Inc.)
Project:P&K Food Mart; 1510 Goldsboro St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP90180-BS NN037777.D 1 03/11/22 AF 03/10/22 OP90180 GNN1768
OP90180-BSD NN037778.D 1 03/11/22 AF 03/10/22 OP90180 GNN1768
The QC reported here applies to the following samples:Method: MADEP EPH REV 2.1
FA93743-1, FA93743-2, FA93743-3, FA93743-4, FA93743-5, FA93743-6, FA93743-7, FA93743-8, FA93743-9
(a) Surrogate recoveries corrected for double spike.
* = Outside of Control Limits.
129 of 129
FA9374388.2.1

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

8/24/2022
Geological Resources, Inc. Rae Brown
113 West Firetower Road, Suite G Winterville, NC, 28590
Ref: Analytical Testing
Lab Report Number: 22-228-0001 Client Project Description: P&K Food Mart
GRI #5079
Dear Rae Brown:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 8/16/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 38
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2022402State ProgramNorth Carolina
07/31/202299012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/22-228-0001
Page 2 of 38
Report Number:
Sample Summary Table
Client Project Description:
22-228-0001
P&K Food Mart
GRI #5079
Lab No Client Sample ID Matrix Date Collected Date Received
08/15/2022 08:02Aqueous 97108 TRIP BLANKS 08/16/2022 10:42
08/15/2022 09:11Aqueous 97109 GMW-8 08/16/2022 10:42
08/15/2022 09:33Aqueous 97110 GMW-9 08/16/2022 10:42
Page 3 of 38
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-228-0001
Report Limit
Project:P&K Food Mart
V 97109GMW-8
26.5 08/23/2022 01:546200BAcetoneµg/L 1.80
1.12 08/23/2022 01:546200BBenzeneµg/L 0.180
0.528 08/23/2022 01:546200BEthylbenzeneµg/L 0.170
1.24 08/23/2022 01:546200B4-Methyl-2-Pentanone µg/L 0.078
J0.281 08/23/2022 01:546200B1,2,4-Trimethylbenzene µg/L 0.190
J0.670 08/23/2022 01:546200Bm,p-Xylene µg/L 0.420
J0.670 08/23/2022 01:546200BXylene (Total)µg/L 0.210
V 97110GMW-9
J5.51 08/23/2022 02:226200BAcetoneµg/L 1.80
J0.385 08/23/2022 02:226200BBenzeneµg/L 0.180
J0.209 08/23/2022 02:226200BEthylbenzeneµg/L 0.170
Page 4 of 38

Client: Geological Resources, Inc. CASE NARRATIVE
Project: P&K Food Mart Lab Report Number: 22-228-0001
Date: 8/24/2022
625.1 - Base/Neutrals and Acids by GC/MS Method 625.1 Sample 97109 (GMW-8) QC Batch No: V22965/V22850
Surrogate(s) were flagged for recoveries in the associated project sample. During the extraction step, the extraction technician noted that a significant emulsion formed. Batch QC samples (Method Blank and Laboratory
Control Samples) all showed surrogate recoveries within QC limits, indicating that the biased recoveries were due to the sample matrix.
Analyte: 2-Chloronaphthalene
QC Batch No: V22965/V22850 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this
analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for a low bias.
Massachusetts EPH Method MADEP-EPH Analyte: Aliphatic C9-C18 QC Batch No: V22991/V22779
Breakthrough is 6.2% for LCSD C9-C18 Aliphatic range. LCS is within range. No further action taken. Volatile Organic Compounds - GC/MS Method 6200B Analyte: Ethanol QC Batch No: V23021/V23020 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.

Page 5 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:TRIP BLANKS
97108 Matrix:
8/15/2022 8:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23020 08/22/22 14:00
<1.80 µg/L 1.80 10.0Acetone 1 08/23/22 00:03 V23021JLB
<0.180 µg/L 0.180 0.500Benzene 1 08/23/22 00:03 V23021JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/23/22 00:03 V23021JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/23/22 00:03 V23021JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/23/22 00:03 V23021JLB
<1.50 µg/L 1.50 5.00Bromoform 1 08/23/22 00:03 V23021JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 08/23/22 00:03 V23021JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/23/22 00:03 V23021JLB
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 08/23/22 00:03 V23021JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/23/22 00:03 V23021JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/23/22 00:03 V23021JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/23/22 00:03 V23021JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/23/22 00:03 V23021JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 08/23/22 00:03 V23021JLB
<0.220 µg/L 0.220 0.500Chloroform 1 08/23/22 00:03 V23021JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 08/23/22 00:03 V23021JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/23/22 00:03 V23021JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/23/22 00:03 V23021JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/23/22 00:03 V23021JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/23/22 00:03 V23021JLB
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/23/22 00:03 V23021JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/23/22 00:03 V23021JLB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 6 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:TRIP BLANKS
97108 Matrix:
8/15/2022 8:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23020 08/22/22 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/23/22 00:03 V23021JLB
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/23/22 00:03 V23021JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/23/22 00:03 V23021JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/23/22 00:03 V23021JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/23/22 00:03 V23021JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/23/22 00:03 V23021JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/23/22 00:03 V23021JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/23/22 00:03 V23021JLB
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 08/23/22 00:03 V23021JLB
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/23/22 00:03 V23021JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/23/22 00:03 V23021JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/23/22 00:03 V23021JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/23/22 00:03 V23021JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/23/22 00:03 V23021JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/23/22 00:03 V23021JLB
<42.0 µg/L 42.0 200
Ethanol 1 08/23/22 00:03 V23021JLB
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/23/22 00:03 V23021JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/23/22 00:03 V23021JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 08/23/22 00:03 V23021JLB
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/23/22 00:03 V23021JLB
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/23/22 00:03 V23021JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/23/22 00:03 V23021JLB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 7 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:TRIP BLANKS
97108 Matrix:
8/15/2022 8:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23020 08/22/22 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/23/22 00:03 V23021JLB
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/23/22 00:03 V23021JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/23/22 00:03 V23021JLB
<0.470 µg/L 0.470 1.00Naphthalene 1 08/23/22 00:03 V23021JLB
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/23/22 00:03 V23021JLB
<0.220 µg/L 0.220 0.500Styrene 1 08/23/22 00:03 V23021JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/23/22 00:03 V23021JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/23/22 00:03 V23021JLB
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 08/23/22 00:03 V23021JLB
<0.220 µg/L 0.220 0.500Toluene 1 08/23/22 00:03 V23021JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/23/22 00:03 V23021JLB
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/23/22 00:03 V23021JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/23/22 00:03 V23021JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/23/22 00:03 V23021JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/23/22 00:03 V23021JLB
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 08/23/22 00:03 V23021JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/23/22 00:03 V23021JLB
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/23/22 00:03 V23021JLB
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/23/22 00:03 V23021JLB
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/23/22 00:03 V23021JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/23/22 00:03 V23021JLB
<0.210 µg/L 0.210 0.500o-Xylene 1 08/23/22 00:03 V23021JLB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 8 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:TRIP BLANKS
97108 Matrix:
8/15/2022 8:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23020 08/22/22 14:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/23/22 00:03 V23021JLB
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/23/22 00:03 V23021
Surrogate: 4-Bromofluorobenzene 98.0 Limits: 70-130%08/23/22 00:031 JLB V23021
Surrogate: Dibromofluoromethane 104 Limits: 70-130%08/23/22 00:031 JLB V23021
Surrogate: 1,2-Dichloroethane - d4 92.6 Limits: 70-130%08/23/22 00:031 JLB V23021
Surrogate: Toluene-d8 97.4 Limits: 70-130%08/23/22 00:031 JLB V23021
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 9 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:GMW-8
97109 Matrix:
8/15/2022 9:11
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 08/23/22 01:54 6200BJLB
Surrogate: 4-Bromofluorobenzene 96.8 Limits: 70-130%08/23/22 01:541 JLB V23021
Surrogate: Dibromofluoromethane 105 Limits: 70-130%08/23/22 01:541 JLB V23021
Surrogate: 1,2-Dichloroethane - d4 92.4 Limits: 70-130%08/23/22 01:541 JLB V23021
Surrogate: Toluene-d8 97.6 Limits: 70-130%08/23/22 01:541 JLB V23021
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 10 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:GMW-8
97109 Matrix:
8/15/2022 9:11
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23020 08/22/22 14:00
26.5 µg/L 1.80 10.0Acetone 1 08/23/22 01:54 V23021JLB
1.12 µg/L 0.180 0.500Benzene 1 08/23/22 01:54 V23021JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/23/22 01:54 V23021JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/23/22 01:54 V23021JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/23/22 01:54 V23021JLB
<1.50 µg/L 1.50 5.00Bromoform 1 08/23/22 01:54 V23021JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 08/23/22 01:54 V23021JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/23/22 01:54 V23021JLB
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 08/23/22 01:54 V23021JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/23/22 01:54 V23021JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/23/22 01:54 V23021JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/23/22 01:54 V23021JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/23/22 01:54 V23021JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 08/23/22 01:54 V23021JLB
<0.220 µg/L 0.220 0.500Chloroform 1 08/23/22 01:54 V23021JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 08/23/22 01:54 V23021JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/23/22 01:54 V23021JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/23/22 01:54 V23021JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/23/22 01:54 V23021JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/23/22 01:54 V23021JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/23/22 01:54 V23021JLB
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/23/22 01:54 V23021JLB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 11 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:GMW-8
97109 Matrix:
8/15/2022 9:11
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23020 08/22/22 14:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/23/22 01:54 V23021JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/23/22 01:54 V23021JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/23/22 01:54 V23021JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/23/22 01:54 V23021JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/23/22 01:54 V23021JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/23/22 01:54 V23021JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/23/22 01:54 V23021JLB
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/23/22 01:54 V23021JLB
<0.190 µg/L 0.190 0.500
1,2-Dichloropropane 1 08/23/22 01:54 V23021JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/23/22 01:54 V23021JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/23/22 01:54 V23021JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/23/22 01:54 V23021JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/23/22 01:54 V23021JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/23/22 01:54 V23021JLB
<42.0 µg/L 42.0 200Ethanol 1 08/23/22 01:54 V23021JLB
0.528 µg/L 0.170 0.500
Ethylbenzene 1 08/23/22 01:54 V23021JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/23/22 01:54 V23021JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 08/23/22 01:54 V23021JLB
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/23/22 01:54 V23021JLB
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/23/22 01:54 V23021JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/23/22 01:54 V23021JLB
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/23/22 01:54 V23021JLB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 12 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:GMW-8
97109 Matrix:
8/15/2022 9:11
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23020 08/22/22 14:00
1.24 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/23/22 01:54 V23021JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/23/22 01:54 V23021JLB
<0.470 µg/L 0.470 1.00Naphthalene 1 08/23/22 01:54 V23021JLB
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/23/22 01:54 V23021JLB
<0.220 µg/L 0.220 0.500Styrene 1 08/23/22 01:54 V23021JLB
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 08/23/22 01:54 V23021JLB
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 08/23/22 01:54 V23021JLB
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 08/23/22 01:54 V23021JLB
<0.280 µg/L 0.280 10.0
tert-Amyl Methyl Ether (TAME)1 08/23/22 01:54 V23021JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/23/22 01:54 V23021JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/23/22 01:54 V23021JLB
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/23/22 01:54 V23021JLB
<0.220 µg/L 0.220 0.500Toluene 1 08/23/22 01:54 V23021JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/23/22 01:54 V23021JLB
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/23/22 01:54 V23021JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/23/22 01:54 V23021JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/23/22 01:54 V23021JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/23/22 01:54 V23021JLB
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/23/22 01:54 V23021JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/23/22 01:54 V23021JLB
0.281 J µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/23/22 01:54 V23021JLB
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/23/22 01:54 V23021JLB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 13 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:GMW-8
97109 Matrix:
8/15/2022 9:11
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23020 08/22/22 14:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/23/22 01:54 V23021JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/23/22 01:54 V23021JLB
<0.210 µg/L 0.210 0.500o-Xylene 1 08/23/22 01:54 V23021JLB
0.670 J µg/L 0.420 1.00m,p-Xylene 1 08/23/22 01:54 V23021JLB
0.670 J µg/L 0.210 0.500Xylene (Total)1 08/23/22 01:54 V23021KCC
Surrogate: 4-Bromofluorobenzene 96.8 Limits: 70-130%08/23/22 01:541 JLB V23021
Surrogate: Dibromofluoromethane 105 Limits: 70-130%08/23/22 01:541 JLB V23021
Surrogate: 1,2-Dichloroethane - d4 92.4 Limits: 70-130%08/23/22 01:541 JLB V23021
Surrogate: Toluene-d8 97.6 Limits: 70-130%08/23/22 01:541 JLB V23021
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V22850 08/18/22 09:37
<7.76 µg/L 7.76 10.9
Acenaphthene 1 08/18/22 22:34 V22965JMV
<7.53 µg/L 7.53 21.7Acenaphthylene 1 08/18/22 22:34 V22965JMV
<7.16 µg/L 7.16 10.9Anthracene 1 08/18/22 22:34 V22965JMV
<5.54 µg/L 5.54 10.9Benzidine 1 08/18/22 22:34 V22965JMV
<7.25 µg/L 7.25 10.9Benzo(a)anthracene 1 08/18/22 22:34 V22965JMV
<5.09 µg/L 5.09 10.9Benzo(a)pyrene 1 08/18/22 22:34 V22965JMV
<4.93 µg/L 4.93 10.9Benzo(b)fluoranthene 1 08/18/22 22:34 V22965JMV
<4.62 µg/L 4.62 10.9
Benzo(g,h,i)perylene 1 08/18/22 22:34 V22965JMV
<5.30 µg/L 5.30 10.9Benzo(k)fluoranthene 1 08/18/22 22:34 V22965JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 14 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:GMW-8
97109 Matrix:
8/15/2022 9:11
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V22850 08/18/22 09:37
<6.18 µg/L 6.18 10.9Bis(2-Chloroethoxy)methane 1 08/18/22 22:34 V22965JMV
<7.96 µg/L 7.96 10.9Bis(2-Chloroethyl)ether 1 08/18/22 22:34 V22965JMV
<7.18 µg/L 7.18 10.9Bis(2-Chloroisopropyl)ether 1 08/18/22 22:34 V22965JMV
<9.59 µg/L 9.59 10.9Bis(2-ethylhexyl)phthalate 1 08/18/22 22:34 V22965JMV
<6.79 µg/L 6.79 21.74-Bromophenyl phenyl ether 1 08/18/22 22:34 V22965JMV
<4.94 µg/L 4.94 10.9Butyl benzyl phthalate 1 08/18/22 22:34 V22965JMV
<8.01 µg/L 8.01 21.72-Chloronaphthalene 1 08/18/22 22:34 V22965JMV
<7.58 µg/L 7.58 21.74-Chlorophenyl phenyl ether 1 08/18/22 22:34 V22965JMV
<5.86 µg/L 5.86 10.9
Chrysene 1 08/18/22 22:34 V22965JMV
<6.52 µg/L 6.52 21.7Dibenz(a,h)anthracene 1 08/18/22 22:34 V22965JMV
<5.51 µg/L 5.51 21.7Dibenzofuran 1 08/18/22 22:34 V22965JMV
<6.44 µg/L 6.44 10.91,2-Dichlorobenzene 1 08/18/22 22:34 V22965JMV
<6.35 µg/L 6.35 10.91,3-Dichlorobenzene 1 08/18/22 22:34 V22965JMV
<6.44 µg/L 6.44 10.91,4-Dichlorobenzene 1 08/18/22 22:34 V22965JMV
<7.19 µg/L 7.19 10.93,3'-Dichlorobenzidine 1 08/18/22 22:34 V22965JMV
<5.67 µg/L 5.67 10.9
2,4-Dinitrotoluene 1 08/18/22 22:34 V22965JMV
<6.40 µg/L 6.40 21.72,6-Dinitrotoluene 1 08/18/22 22:34 V22965JMV
<6.57 µg/L 6.57 10.9Fluoranthene 1 08/18/22 22:34 V22965JMV
<7.92 µg/L 7.92 10.9Fluorene 1 08/18/22 22:34 V22965JMV
<6.24 µg/L 6.24 21.7Hexachlorobenzene 1 08/18/22 22:34 V22965JMV
<6.38 µg/L 6.38 21.7Hexachlorobutadiene 1 08/18/22 22:34 V22965JMV
<6.40 µg/L 6.40 21.7Hexachlorocyclopentadiene 1 08/18/22 22:34 V22965JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 15 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:GMW-8
97109 Matrix:
8/15/2022 9:11
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V22850 08/18/22 09:37
<5.69 µg/L 5.69 10.9Hexachloroethane 1 08/18/22 22:34 V22965JMV
<6.76 µg/L 6.76 10.9Indeno(1,2,3-cd)pyrene 1 08/18/22 22:34 V22965JMV
<7.31 µg/L 7.31 10.9Isophorone 1 08/18/22 22:34 V22965JMV
<1.20 µg/L 1.20 10.91-Methylnaphthalene 1 08/18/22 22:34 V22965JMV
<7.54 µg/L 7.54 10.92-Methylnaphthalene 1 08/18/22 22:34 V22965JMV
<8.59 µg/L 8.59 10.9Naphthalene 1 08/18/22 22:34 V22965JMV
<8.59 µg/L 8.59 10.9Nitrobenzene 1 08/18/22 22:34 V22965JMV
<11.9 µg/L 11.9 21.7N-Nitrosodiphenylamine 1 08/18/22 22:34 V22965JMV
<8.79 µg/L 8.79 21.7
N-Nitroso-di-n-propylamine 1 08/18/22 22:34 V22965JMV
<6.91 µg/L 6.91 10.9Phenanthrene 1 08/18/22 22:34 V22965JMV
<5.91 µg/L 5.91 10.9Pyrene 1 08/18/22 22:34 V22965JMV
<6.81 µg/L 6.81 10.91,2,4-Trichlorobenzene 1 08/18/22 22:34 V22965JMV
Surrogate: 2-Fluorobiphenyl 42.9 *Limits: 49-118%08/18/22 22:341 JMV V22965
Surrogate: Nitrobenzene-d5 36.8 *Limits: 43-123%08/18/22 22:341 JMV V22965
Surrogate: 4-Terphenyl-d14 63.7 Limits: 49-151%08/18/22 22:341 JMV V22965
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 16 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:GMW-8
97109 Matrix:
8/15/2022 9:11
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 50.0Aliphatic C5-C8 (Adjusted)1 08/16/22 13:12
<25.8 µg/L 50.0Aliphatics C9-C12 (Adjusted)1 08/16/22 13:12
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 08/16/22 13:12
<61.2 µg/L 61.2 250Aromatic C11-C22 (Adjusted)1 08/18/22 22:34
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V22779 08/17/22 09:10
<28.2 µg/L 28.2 350Aliphatic C9-C18 1 08/19/22 01:46 V22991JLK
<124 µg/L 124 500Aliphatic C19-C36 1 08/19/22 01:46 V22991JLK
<61.2 µg/L 61.2 250Aromatic C11-C22 1 08/19/22 01:46 V22991JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 95.0 Limits: 40-140%08/19/22 01:461 JLK
MADEP-EPHSurrogate: Chlorooctadecane 53.0 Limits: 40-140%08/19/22 01:461 JLK
MADEP-EPHSurrogate: OTP Surrogate 74.5 Limits: 40-140%08/19/22 01:461 JLK
Surrogate: 2-Fluorobiphenyl 99.5 Limits: 40-140%08/19/22 01:461 JLK V22991
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V22772 08/16/22 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 08/16/22 13:12 V22773TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 08/16/22 13:12 V22773TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 17 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:GMW-8
97109 Matrix:
8/15/2022 9:11
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V22772 08/16/22 08:00
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 08/16/22 13:12 V22773TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)108 Limits: 70-130%08/16/22 13:121 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)104 Limits: 70-130%08/16/22 13:121 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 18 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:GMW-9
97110 Matrix:
8/15/2022 9:33
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 08/23/22 02:22 6200BJLB
Surrogate: 4-Bromofluorobenzene 97.0 Limits: 70-130%08/23/22 02:221 JLB V23021
Surrogate: Dibromofluoromethane 102 Limits: 70-130%08/23/22 02:221 JLB V23021
Surrogate: 1,2-Dichloroethane - d4 91.0 Limits: 70-130%08/23/22 02:221 JLB V23021
Surrogate: Toluene-d8 97.2 Limits: 70-130%08/23/22 02:221 JLB V23021
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 19 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:GMW-9
97110 Matrix:
8/15/2022 9:33
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23020 08/22/22 14:00
5.51 J µg/L 1.80 10.0Acetone 1 08/23/22 02:22 V23021JLB
0.385 J µg/L 0.180 0.500Benzene 1 08/23/22 02:22 V23021JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/23/22 02:22 V23021JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/23/22 02:22 V23021JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/23/22 02:22 V23021JLB
<1.50 µg/L 1.50 5.00Bromoform 1 08/23/22 02:22 V23021JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 08/23/22 02:22 V23021JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/23/22 02:22 V23021JLB
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 08/23/22 02:22 V23021JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/23/22 02:22 V23021JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/23/22 02:22 V23021JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/23/22 02:22 V23021JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/23/22 02:22 V23021JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 08/23/22 02:22 V23021JLB
<0.220 µg/L 0.220 0.500Chloroform 1 08/23/22 02:22 V23021JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 08/23/22 02:22 V23021JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/23/22 02:22 V23021JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/23/22 02:22 V23021JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/23/22 02:22 V23021JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/23/22 02:22 V23021JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/23/22 02:22 V23021JLB
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/23/22 02:22 V23021JLB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 20 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:GMW-9
97110 Matrix:
8/15/2022 9:33
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23020 08/22/22 14:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/23/22 02:22 V23021JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/23/22 02:22 V23021JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/23/22 02:22 V23021JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/23/22 02:22 V23021JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/23/22 02:22 V23021JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/23/22 02:22 V23021JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/23/22 02:22 V23021JLB
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/23/22 02:22 V23021JLB
<0.190 µg/L 0.190 0.500
1,2-Dichloropropane 1 08/23/22 02:22 V23021JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/23/22 02:22 V23021JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/23/22 02:22 V23021JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/23/22 02:22 V23021JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/23/22 02:22 V23021JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/23/22 02:22 V23021JLB
<42.0 µg/L 42.0 200Ethanol 1 08/23/22 02:22 V23021JLB
0.209 J
µg/L 0.170 0.500
Ethylbenzene 1 08/23/22 02:22 V23021JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/23/22 02:22 V23021JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 08/23/22 02:22 V23021JLB
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/23/22 02:22 V23021JLB
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/23/22 02:22 V23021JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/23/22 02:22 V23021JLB
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/23/22 02:22 V23021JLB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 21 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:GMW-9
97110 Matrix:
8/15/2022 9:33
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23020 08/22/22 14:00
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/23/22 02:22 V23021JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/23/22 02:22 V23021JLB
<0.470 µg/L 0.470 1.00Naphthalene 1 08/23/22 02:22 V23021JLB
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/23/22 02:22 V23021JLB
<0.220 µg/L 0.220 0.500Styrene 1 08/23/22 02:22 V23021JLB
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 08/23/22 02:22 V23021JLB
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 08/23/22 02:22 V23021JLB
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 08/23/22 02:22 V23021JLB
<0.280 µg/L 0.280 10.0
tert-Amyl Methyl Ether (TAME)1 08/23/22 02:22 V23021JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/23/22 02:22 V23021JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/23/22 02:22 V23021JLB
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/23/22 02:22 V23021JLB
<0.220 µg/L 0.220 0.500Toluene 1 08/23/22 02:22 V23021JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/23/22 02:22 V23021JLB
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/23/22 02:22 V23021JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/23/22 02:22 V23021JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/23/22 02:22 V23021JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/23/22 02:22 V23021JLB
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/23/22 02:22 V23021JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/23/22 02:22 V23021JLB
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/23/22 02:22 V23021JLB
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/23/22 02:22 V23021JLB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 22 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:GMW-9
97110 Matrix:
8/15/2022 9:33
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23020 08/22/22 14:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/23/22 02:22 V23021JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/23/22 02:22 V23021JLB
<0.210 µg/L 0.210 0.500o-Xylene 1 08/23/22 02:22 V23021JLB
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/23/22 02:22 V23021JLB
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/23/22 02:22 V23021KCC
Surrogate: 4-Bromofluorobenzene 97.0 Limits: 70-130%08/23/22 02:221 JLB V23021
Surrogate: Dibromofluoromethane 102 Limits: 70-130%08/23/22 02:221 JLB V23021
Surrogate: 1,2-Dichloroethane - d4 91.0 Limits: 70-130%08/23/22 02:221 JLB V23021
Surrogate: Toluene-d8 97.2 Limits: 70-130%08/23/22 02:221 JLB V23021
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 23 of 38
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-228-0001
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5079 Received : 08/16/2022
P&K Food Mart
Report Date : 08/24/2022
Sample ID :
Lab No :
Sampled:GMW-9
97110 Matrix:
8/15/2022 9:33
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 50.0Aliphatic C5-C8 (Adjusted)1 08/16/22 13:36
<25.8 µg/L 50.0Aliphatics C9-C12 (Adjusted)1 08/16/22 13:36
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 08/16/22 13:36
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V22772 08/16/22 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 08/16/22 13:36 V22773TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 08/16/22 13:36 V22773TBL
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 08/16/22 13:36 V22773TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)127 Limits: 70-130%08/16/22 13:361 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)128 Limits: 70-130%08/16/22 13:361 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Page 24 of 38
Quality Control Data
22-228-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
P&K Food Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23021QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23020
Associated Lab Samples: 97108, 97109, 97110
LRB-V23020 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/22/22 23:3510.01.80<1.80µg/LAcetone
08/22/22 23:350.5000.180<0.180µg/LBenzene
08/22/22 23:350.5000.210<0.210µg/LBromobenzene
08/22/22 23:351.000.420<0.420µg/LBromochloromethane
08/22/22 23:350.5000.160<0.160µg/LBromodichloromethane
08/22/22 23:355.001.50<1.50µg/LBromoform
08/22/22 23:351.000.280<0.280µg/LBromomethane
08/22/22 23:350.5000.180<0.180µg/Ln-Butylbenzene
08/22/22 23:350.5000.200<0.200µg/Lsec-Butyl benzene
08/22/22 23:352.000.920<0.920µg/Ltert-Butyl benzene
08/22/22 23:350.5000.180<0.180µg/LCarbon Tetrachloride
08/22/22 23:350.5000.190<0.190µg/LChlorobenzene
08/22/22 23:350.5000.190<0.190µg/LChlorodibromomethane
08/22/22 23:351.000.430<0.430µg/LChloroethane
08/22/22 23:350.5000.220<0.220µg/LChloroform
08/22/22 23:350.5000.220<0.220µg/LChloromethane
08/22/22 23:350.5000.200<0.200µg/L2-Chlorotoluene
08/22/22 23:350.5000.200<0.200µg/L4-Chlorotoluene
08/22/22 23:350.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
08/22/22 23:352.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
08/22/22 23:350.5000.200<0.200µg/L1,2-Dibromoethane
08/22/22 23:350.5000.230<0.230µg/LDibromomethane
08/22/22 23:350.5000.220<0.220µg/L1,2-Dichlorobenzene
08/22/22 23:350.5000.190<0.190µg/L1,3-Dichlorobenzene
08/22/22 23:350.5000.210<0.210µg/L1,4-Dichlorobenzene
08/22/22 23:355.001.20<1.20µg/LDichlorodifluoromethane
08/22/22 23:350.5000.240<0.240µg/L1,1-Dichloroethane
Page 1 of 12Date:08/24/2022 02:00 PM
Page 25 of 38
Quality Control Data
22-228-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
P&K Food Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23021QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23020
Associated Lab Samples: 97108, 97109, 97110
LRB-V23020 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/22/22 23:350.5000.150<0.150µg/L1,2-Dichloroethane
08/22/22 23:350.5000.150<0.150µg/L1,1-Dichloroethene
08/22/22 23:350.5000.200<0.200µg/Lcis-1,2-Dichloroethene
08/22/22 23:350.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
08/22/22 23:350.5000.190<0.190µg/L1,2-Dichloropropane
08/22/22 23:350.5000.130<0.130µg/L1,3-Dichloropropane
08/22/22 23:352.000.210<0.210µg/L2,2-Dichloropropane
08/22/22 23:350.5000.200<0.200µg/L1,1-Dichloropropene
08/22/22 23:350.5000.210<0.210µg/Lcis-1,3-Dichloropropene
08/22/22 23:350.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
08/22/22 23:3520042.0<42.0µg/LEthanol
08/22/22 23:350.5000.170<0.170µg/LEthylbenzene
08/22/22 23:353.000.350<0.350µg/LHexachlorobutadiene
08/22/22 23:351.000.380<0.380µg/L2-Hexanone
08/22/22 23:350.5000.180<0.180µg/LIsopropylbenzene
08/22/22 23:350.5000.089<0.089µg/L4-Isopropyl toluene
08/22/22 23:355.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
08/22/22 23:351.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
08/22/22 23:351.000.078<0.078µg/L4-Methyl-2-Pentanone
08/22/22 23:352.000.330<0.330µg/LMethylene Chloride
08/22/22 23:351.000.470<0.470µg/LNaphthalene
08/22/22 23:350.5000.190<0.190µg/Ln-Propylbenzene
08/22/22 23:350.5000.220<0.220µg/LStyrene
08/22/22 23:3510.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
08/22/22 23:3510.00.350<0.350µg/Ltert-Butyl formate (TBF)
08/22/22 23:3510.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
08/22/22 23:3510.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 2 of 12Date:08/24/2022 02:00 PM
Page 26 of 38
Quality Control Data
22-228-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
P&K Food Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23021QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23020
Associated Lab Samples: 97108, 97109, 97110
LRB-V23020 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/22/22 23:350.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
08/22/22 23:350.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
08/22/22 23:350.5000.220<0.220µg/LTetrachloroethene
08/22/22 23:350.5000.220<0.220µg/LToluene
08/22/22 23:350.5000.380<0.380µg/L1,2,3-Trichlorobenzene
08/22/22 23:350.5000.310<0.310µg/L1,2,4-Trichlorobenzene
08/22/22 23:350.5000.160<0.160µg/L1,1,1-Trichloroethane
08/22/22 23:350.5000.096<0.096µg/L1,1,2-Trichloroethane
08/22/22 23:350.5000.180<0.180µg/LTrichloroethene
08/22/22 23:350.5000.180<0.180µg/LTrichlorofluoromethane
08/22/22 23:350.5000.270<0.270µg/L1,2,3-Trichloropropane
08/22/22 23:350.5000.190<0.190µg/L1,2,4-Trimethylbenzene
08/22/22 23:350.5000.180<0.180µg/L1,3,5-Trimethylbenzene
08/22/22 23:355.001.00<1.00µg/LVinyl Acetate
08/22/22 23:350.5000.170<0.170µg/LVinyl Chloride
08/22/22 23:350.5000.210<0.210µg/Lo-Xylene
08/22/22 23:351.000.420<0.420µg/Lm,p-Xylene
08/22/22 23:3510.01.00<1.00µg/L3,3-Dimethyl-1-butanol
08/22/22 23:354-Bromofluorobenzene (S)96.0 70-130
08/22/22 23:35Dibromofluoromethane (S)102 70-130
08/22/22 23:351,2-Dichloroethane - d4 (S)92.6 70-130
08/22/22 23:35Toluene-d8 (S)98.0 70-130
Page 3 of 12Date:08/24/2022 02:00 PM
Page 27 of 38
Quality Control Data
22-228-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
P&K Food Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23021QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23020
LCS-V23020 LCSD-V23020Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
27.1 67.775.730.340.0µg/LAcetone 40-160 11.1 20.0
20.2 10111021.920.0µg/LBenzene 70-130 8.0 20.0
21.0 10510621.120.0µg/LBromobenzene 70-130 0.4 20.0
20.6 10311222.420.0µg/LBromochloromethane 70-130 8.3 20.0
21.0 10511122.220.0µg/LBromodichloromethane 70-130 5.5 20.0
19.0 95.093.018.620.0µg/LBromoform 70-130 2.1 20.0
21.0 10511322.620.0µg/LBromomethane 60-140 7.3 20.0
23.0 11511623.120.0µg/Ln-Butylbenzene 70-130 0.4 20.0
23.8 11912024.020.0µg/Lsec-Butyl benzene 70-130 0.8 20.0
24.2 12112124.120.0µg/Ltert-Butyl benzene 70-130 0.4 20.0
20.6 10311222.420.0µg/LCarbon Tetrachloride 70-130 8.3 20.0
20.6 10310721.420.0µg/LChlorobenzene 70-130 3.8 20.0
20.2 10110320.620.0µg/LChlorodibromomethane 70-130 1.9 20.0
19.6 98.010821.520.0µg/LChloroethane 60-140 9.2 20.0
21.7 10911823.520.0µg/LChloroform 70-130 7.9 20.0
18.4 92.097.519.520.0µg/LChloromethane 60-140 5.8 20.0
22.3 11211322.620.0µg/L2-Chlorotoluene 70-130 1.3 20.0
23.0 11511422.720.0µg/L4-Chlorotoluene 70-130 1.3 20.0
20.5 10310921.820.0µg/LDi-Isopropyl Ether (DIPE)70-130 6.1 20.0
16.3 81.586.017.220.0µg/L1,2-Dibromo-3-Chloropropane 70-130 5.3 20.0
19.6 98.097.019.420.0µg/L1,2-Dibromoethane 70-130 1.0 20.0
18.6 93.099.019.820.0µg/LDibromomethane 70-130 6.2 20.0
24.4 12212324.620.0µg/L1,2-Dichlorobenzene 70-130 0.8 20.0
24.6 12312224.420.0µg/L1,3-Dichlorobenzene 70-130 0.8 20.0
23.6 11811422.720.0µg/L1,4-Dichlorobenzene 70-130 3.8 20.0
20.8 10411222.320.0µg/LDichlorodifluoromethane 60-140 6.9 20.0
Page 4 of 12Date:08/24/2022 02:00 PM
Page 28 of 38
Quality Control Data
22-228-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
P&K Food Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23021QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23020
LCS-V23020 LCSD-V23020Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.6 10310921.820.0µg/L1,1-Dichloroethane 70-130 5.6 20.0
17.9 89.595.519.120.0µg/L1,2-Dichloroethane 70-130 6.4 20.0
21.7 10912024.020.0µg/L1,1-Dichloroethene 70-130 10.0 20.0
20.7 10411222.320.0µg/Lcis-1,2-Dichloroethene 70-130 7.4 20.0
21.6 10811222.420.0µg/Ltrans-1,2-Dichloroethene 70-130 3.6 20.0
22.2 11111823.520.0µg/L1,2-Dichloropropane 70-130 5.6 20.0
20.0 10010020.020.0µg/L1,3-Dichloropropane 70-130 0.0 20.0
19.9 99.511021.920.0µg/L2,2-Dichloropropane 70-130 9.5 20.0
21.5 10811623.120.0µg/L1,1-Dichloropropene 70-130 7.1 20.0
22.1 11112124.120.0µg/Lcis-1,3-Dichloropropene 70-130 8.6 20.0
22.1 11112124.120.0µg/Ltrans-1,3-Dichloropropene 70-130 8.6 20.0
380 76.097.4487500µg/LEthanol 60-140 24.6*20.0
19.6 98.010320.520.0µg/LEthylbenzene 70-130 4.4 20.0
25.6 12812525.020.0µg/LHexachlorobutadiene 70-130 2.3 20.0
14.2 71.070.514.120.0µg/L2-Hexanone 60-140 0.7 20.0
23.6 11811723.320.0µg/LIsopropylbenzene 70-130 1.2 20.0
24.3 12212524.920.0µg/L4-Isopropyl toluene 70-130 2.4 20.0
15.7 78.590.518.120.0µg/LMethyl Ethyl Ketone (MEK)60-140 14.2 20.0
19.5 97.510721.420.0µg/LMethyl tert-butyl ether (MTBE)70-130 9.2 20.0
14.1 70.575.515.120.0µg/L4-Methyl-2-Pentanone 60-140 6.8 20.0
20.0 10010621.120.0µg/LMethylene Chloride 70-130 5.3 20.0
14.1 70.570.514.120.0µg/LNaphthalene 70-130 0.0 20.0
23.5 11811623.220.0µg/Ln-Propylbenzene 70-130 1.2 20.0
21.3 10710520.920.0µg/LStyrene 70-130 1.8 20.0
38.3 95.780.232.140.0µg/Ltert-Butyl Alcohol (TBA)40-140 17.6 20.0
40.7 10210943.740.0µg/Ltert-Butyl formate (TBF)40-140 7.1 20.0
Page 5 of 12* QC Fail Date:08/24/2022 02:00 PM
Page 29 of 38
Quality Control Data
22-228-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
P&K Food Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23021QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23020
LCS-V23020 LCSD-V23020Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
17.1 85.572.014.420.0µg/Ltert-Amyl Alcohol (TAA)40-140 17.1 20.0
41.2 10310943.540.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 5.4 20.0
20.0 10010821.620.0µg/L1,1,1,2-Tetrachloroethane 70-130 7.6 20.0
19.6 98.095.019.020.0µg/L1,1,2,2-Tetrachloroethane 70-130 3.1 20.0
22.1 11111422.720.0µg/LTetrachloroethene 70-130 2.6 20.0
19.8 99.010721.320.0µg/LToluene 70-130 7.2 20.0
15.8 79.079.015.820.0µg/L1,2,3-Trichlorobenzene 70-130 0.0 20.0
19.2 96.095.519.120.0µg/L1,2,4-Trichlorobenzene 70-130 0.5 20.0
21.7 10911623.220.0µg/L1,1,1-Trichloroethane 70-130 6.6 20.0
19.6 98.010521.020.0µg/L1,1,2-Trichloroethane 70-130 6.8 20.0
21.6 10811823.520.0µg/LTrichloroethene 70-130 8.4 20.0
21.4 10711222.320.0µg/LTrichlorofluoromethane 60-140 4.1 20.0
20.5 10395.519.120.0µg/L1,2,3-Trichloropropane 70-130 7.0 20.0
23.6 11811723.420.0µg/L1,2,4-Trimethylbenzene 70-130 0.8 20.0
23.3 11711823.520.0µg/L1,3,5-Trimethylbenzene 70-130 0.8 20.0
19.1 95.510320.520.0µg/LVinyl Acetate 60-140 7.0 20.0
20.9 10511522.920.0µg/LVinyl Chloride 60-140 9.1 20.0
20.5 10310320.520.0µg/Lo-Xylene 70-130 0.0 20.0
41.9 10510843.040.0µg/Lm,p-Xylene 70-130 2.5 20.0
18.9 94.598.519.720.0µg/L3,3-Dimethyl-1-butanol 70-130 4.1 20.0
1141094-Bromofluorobenzene (S)70-130
104108Dibromofluoromethane (S)70-130
92.296.21,2-Dichloroethane - d4 (S)70-130
99.099.2Toluene-d8 (S)70-130
Page 6 of 12Date:08/24/2022 02:00 PM
Page 30 of 38
Quality Control Data
22-228-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
P&K Food Mart
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V22965QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V22850
Associated Lab Samples: 97109
LRB-V22850 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/18/22 18:0710.07.12<7.12µg/LAcenaphthene
08/18/22 18:0720.06.94<6.94µg/LAcenaphthylene
08/18/22 18:0710.06.57<6.57µg/LAnthracene
08/18/22 18:0710.05.08<5.08µg/LBenzidine
08/18/22 18:0710.06.65<6.65µg/LBenzo(a)anthracene
08/18/22 18:0710.04.67<4.67µg/LBenzo(a)pyrene
08/18/22 18:0710.04.52<4.52µg/LBenzo(b)fluoranthene
08/18/22 18:0710.04.24<4.24µg/LBenzo(g,h,i)perylene
08/18/22 18:0710.04.86<4.86µg/LBenzo(k)fluoranthene
08/18/22 18:0710.05.67<5.67µg/LBis(2-Chloroethoxy)methane
08/18/22 18:0710.07.30<7.30µg/LBis(2-Chloroethyl)ether
08/18/22 18:0710.06.59<6.59µg/LBis(2-Chloroisopropyl)ether
08/18/22 18:0710.08.80<8.80µg/LBis(2-ethylhexyl)phthalate
08/18/22 18:0720.06.26<6.26µg/L4-Bromophenyl phenyl ether
08/18/22 18:0710.04.53<4.53µg/LButyl benzyl phthalate
08/18/22 18:0720.07.38<7.38µg/L2-Chloronaphthalene
08/18/22 18:0720.06.99<6.99µg/L4-Chlorophenyl phenyl ether
08/18/22 18:0710.05.38<5.38µg/LChrysene
08/18/22 18:0720.06.01<6.01µg/LDibenz(a,h)anthracene
08/18/22 18:0720.05.08<5.08µg/LDibenzofuran
08/18/22 18:0710.05.91<5.91µg/L1,2-Dichlorobenzene
08/18/22 18:0710.05.83<5.83µg/L1,3-Dichlorobenzene
08/18/22 18:0710.05.91<5.91µg/L1,4-Dichlorobenzene
08/18/22 18:0710.06.60<6.60µg/L3,3'-Dichlorobenzidine
08/18/22 18:0710.05.20<5.20µg/L2,4-Dinitrotoluene
08/18/22 18:0720.05.90<5.90µg/L2,6-Dinitrotoluene
08/18/22 18:0710.06.03<6.03µg/LFluoranthene
Page 7 of 12Date:08/24/2022 02:00 PM
Page 31 of 38
Quality Control Data
22-228-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
P&K Food Mart
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V22965QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V22850
Associated Lab Samples: 97109
LRB-V22850 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/18/22 18:0710.07.27<7.27µg/LFluorene
08/18/22 18:0720.05.75<5.75µg/LHexachlorobenzene
08/18/22 18:0720.05.88<5.88µg/LHexachlorobutadiene
08/18/22 18:0720.05.90<5.90µg/LHexachlorocyclopentadiene
08/18/22 18:0710.05.22<5.22µg/LHexachloroethane
08/18/22 18:0710.06.20<6.20µg/LIndeno(1,2,3-cd)pyrene
08/18/22 18:0710.06.71<6.71µg/LIsophorone
08/18/22 18:0710.01.10<1.10µg/L1-Methylnaphthalene
08/18/22 18:0710.06.92<6.92µg/L2-Methylnaphthalene
08/18/22 18:0710.07.88<7.88µg/LNaphthalene
08/18/22 18:0710.07.88<7.88µg/LNitrobenzene
08/18/22 18:0720.010.9<10.9µg/LN-Nitrosodiphenylamine
08/18/22 18:0720.08.10<8.10µg/LN-Nitroso-di-n-propylamine
08/18/22 18:0710.06.34<6.34µg/LPhenanthrene
08/18/22 18:0710.05.42<5.42µg/LPyrene
08/18/22 18:0710.06.25<6.25µg/L1,2,4-Trichlorobenzene
08/18/22 18:072-Fluorobiphenyl (S)60.6 49-118
08/18/22 18:072-Fluorophenol (S)36.4 22-84
08/18/22 18:07Nitrobenzene-d5 (S)53.4 43-123
08/18/22 18:074-Terphenyl-d14 (S)73.0 49-151
08/18/22 18:072,4,6-Tribromophenol (S)86.6 31-144
08/18/22 18:07Phenol-d5 (S)23.2 10-63
Page 8 of 12Date:08/24/2022 02:00 PM
Page 32 of 38
Quality Control Data
22-228-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
P&K Food Mart
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V22965QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V22850
LCS-V22850 LCSD-V22850Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
29.2 58.457.428.750.0µg/LAcenaphthene 47-145 1.7 20.0
28.5 57.061.230.650.0µg/LAcenaphthylene 33-145 7.1 20.0
30.7 61.463.631.850.0µg/LAnthracene 27-133 3.5 20.0
25.9 51.846.623.350.0µg/LBenzidine 15-150 10.5 20.0
30.7 61.463.031.550.0µg/LBenzo(a)anthracene 33-143 2.5 20.0
37.2 74.475.637.850.0µg/LBenzo(a)pyrene 17-163 1.6 20.0
33.8 67.668.634.350.0µg/LBenzo(b)fluoranthene 24-159 1.4 20.0
32.1 64.265.632.850.0µg/LBenzo(g,h,i)perylene 10-219 2.1 20.0
32.1 64.265.232.650.0µg/LBenzo(k)fluoranthene 11-162 1.5 20.0
24.5 49.051.025.550.0µg/LBis(2-Chloroethoxy)methane 33-184 4.0 20.0
35.5 71.075.237.650.0µg/LBis(2-Chloroethyl)ether 12-158 5.7 20.0
19.9 39.845.622.850.0µg/LBis(2-Chloroisopropyl)ether 36-166 13.5 20.0
30.5 61.062.031.050.0µg/LBis(2-ethylhexyl)phthalate 10-158 1.6 20.0
31.4 62.866.233.150.0µg/L4-Bromophenyl phenyl ether 53-127 5.2 20.0
27.8 55.655.627.850.0µg/LButyl benzyl phthalate 10-152 0.0 20.0
27.4 54.8*59.2*29.650.0µg/L2-Chloronaphthalene 60-118 7.7 20.0
32.5 65.070.435.250.0µg/L4-Chlorophenyl phenyl ether 25-158 7.9 20.0
32.6 65.265.832.950.0µg/LChrysene 17-168 0.9 20.0
34.9 69.871.235.650.0µg/LDibenz(a,h)anthracene 10-227 1.9 20.0
29.4 58.862.231.150.0µg/LDibenzofuran 39-114 5.6 20.0
23.4 46.851.225.650.0µg/L1,2-Dichlorobenzene 32-129 8.9 20.0
22.3 44.650.225.150.0µg/L1,3-Dichlorobenzene 20-124 11.8 20.0
22.8 45.648.624.350.0µg/L1,4-Dichlorobenzene 20-124 6.3 20.0
26.6 53.254.227.150.0µg/L3,3'-Dichlorobenzidine 10-262 1.8 20.0
33.7 67.466.633.350.0µg/L2,4-Dinitrotoluene 39-139 1.1 20.0
33.1 66.267.633.850.0µg/L2,6-Dinitrotoluene 50-158 2.0 20.0
Page 9 of 12* QC Fail Date:08/24/2022 02:00 PM
Page 33 of 38
Quality Control Data
22-228-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
P&K Food Mart
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V22965QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V22850
LCS-V22850 LCSD-V22850Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
31.9 63.865.832.950.0µg/LFluoranthene 26-137 3.0 20.0
30.8 61.668.234.150.0µg/LFluorene 59-121 10.1 20.0
31.2 62.467.633.850.0µg/LHexachlorobenzene 10-152 8.0 20.0
25.4 50.853.426.750.0µg/LHexachlorobutadiene 24-116 4.9 20.0
23.9 47.848.024.050.0µg/LHexachlorocyclopentadiene 32-117 0.4 20.0
20.3 40.643.821.950.0µg/LHexachloroethane 40-113 7.5 20.0
32.3 64.665.432.750.0µg/LIndeno(1,2,3-cd)pyrene 10-171 1.2 20.0
19.7 39.444.022.050.0µg/LIsophorone 21-196 11.0 20.0
25.4 50.850.025.050.0µg/L1-Methylnaphthalene 40-135 1.5 20.0
24.1 48.250.425.250.0µg/L2-Methylnaphthalene 18-121 4.4 20.0
23.1 46.248.624.350.0µg/LNaphthalene 21-133 5.0 20.0
23.2 46.443.821.950.0µg/LNitrobenzene 35-180 5.7 20.0
35.5 71.074.637.350.0µg/LN-Nitrosodiphenylamine 69-152 4.9 20.0
23.4 46.850.425.250.0µg/LN-Nitroso-di-n-propylamine 10-230 7.4 20.0
30.8 61.664.032.050.0µg/LPhenanthrene 54-120 3.8 20.0
31.4 62.864.632.350.0µg/LPyrene 52-115 2.8 20.0
24.1 48.249.624.850.0µg/L1,2,4-Trichlorobenzene 44-142 2.8 20.0
53.058.42-Fluorobiphenyl (S)49-118
33.335.62-Fluorophenol (S)22-84
43.443.2Nitrobenzene-d5 (S)43-123
65.667.04-Terphenyl-d14 (S)49-151
73.975.22,4,6-Tribromophenol (S)31-144
21.422.1Phenol-d5 (S)10-63
Page 10 of 12Date:08/24/2022 02:00 PM
Page 34 of 38
Quality Control Data
22-228-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
P&K Food Mart
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V22991QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V22779
Associated Lab Samples: 97109
LRB-V22779 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/18/22 17:5235028.2<28.2µg/LAliphatic C9-C18
08/18/22 17:52500124<124µg/LAliphatic C19-C36
08/18/22 17:5225061.2<61.2µg/LAromatic C11-C22
08/18/22 17:522-Fluorobiphenyl (S)83.7 40-140
08/18/22 17:522-Bromonaphthalene (S)89.0 40-140
08/18/22 17:52Chlorooctadecane (S)48.9 40-140
08/18/22 17:52OTP Surrogate (S)61.5 40-140
LCS-V22779 LCSD-V22779Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
270 45.047.3284600µg/LAliphatic C9-C18 40-140 5.0 50.0
481 60.159.5476800µg/LAliphatic C19-C36 40-140 1.0 50.0
1200 70.573.512501700µg/LAromatic C11-C22 40-140 4.0 50.0
91.099.72-Fluorobiphenyl (S)40-140
73.01082-Bromonaphthalene (S)40-140
51.553.0Chlorooctadecane (S)40-140
60.067.5OTP Surrogate (S)40-140
Page 11 of 12Date:08/24/2022 02:00 PM
Page 35 of 38
Quality Control Data
22-228-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
P&K Food Mart
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V22773QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V22772
Associated Lab Samples: 97109, 97110
LRB-V22772 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/16/22 12:2550.011.5<11.5µg/LAliphatic C5-C8
08/16/22 12:2550.025.8<25.8µg/LAliphatic C9-C12
08/16/22 12:2550.04.02<4.02µg/LAromatic C9-C10
08/16/22 12:252,5-Dibromotoluene (FID) (S)114 70-130
08/16/22 12:252,5-Dibromotoluene (PID) (S)104 70-130
LCS-V22772 LCSD-V22772Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
338 113113339300µg/LAliphatic C5-C8 70-130 0.2 50.0
315 105103309300µg/LAliphatic C9-C12 70-130 1.9 50.0
120 120106106100µg/LAromatic C9-C10 70-130 12.3 50.0
1121162,5-Dibromotoluene (FID) (S)70-130
1111212,5-Dibromotoluene (PID) (S)70-130
Page 12 of 12Date:08/24/2022 02:00 PM
Page 36 of 38
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:22-228-0001
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT-15 0.1C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Adam Crouch Date & Time:08/16/2022 10:45:33
Special precautions or instructions included?
Comments:
Page 37 of 38
Page 38 of 38

Appendix D
Slug Test Data

0. 0.8 1.6 2.4 3.2 4.
0.1
1.
10.
Time (min)Displacement (ft)WELL TEST ANALYSIS
Data Set: F:\...\GMW-2.aqt
Date: 12/16/21 Time: 15:50:24
PROJECT INFORMATION
Company: Geological Resources, Inc.
Client: P&K Food Mart
Project: 5079
Location: Wilson, NC
Test Well: GMW-2
Test Date: 9/27/21
AQUIFER DATA
Saturated Thickness: 27.28 ft Anisotropy Ratio (Kz/Kr): 0.1
WELL DATA (GMW-2)
Initial Displacement: 1.75 ft Static Water Column Height: 11.4 ft
Total Well Penetration Depth: 11.4 ft Screen Length: 11.4 ft
Casing Radius: 0.085 ft Well Radius: 0.25 ft
Gravel Pack Porosity: 0.
SOLUTION
Aquifer Model: Unconfined Solution Method: Bouwer-Rice
K = 3.686E-5 ft/min y0 = 0.6651 ft
Page Item Value Remarks
NA Static depth to water (SDTW) from TOC SDTW 3.60 Test well
Initial DTW (IDTW) - after remove/introduce slug from TOC IDTW 5.35 Test well
Total well depth (TWD)TWD 15.00 Test well
Top of Casing Elevation (TOC)TOC 99.83 Test well
Highest historical ground water elevation at site (HGWE)HGWE 97.31 All site wells
Deepest well depth elevation (DWDE)DWDE 70.03 Deepest well
5 Project Name
Project location (city, state)
Test Well #
Date slug test conducted
6 H(o): Initial displacement (IDTW minus SDTW)H(o)1.75 1.75' = For a 3' , 1-1/2 " bailer in a 2" dia. Well
H: Static water column height H 11.40 TWD minus SDTW
Well #GMW-2 Test well ID
7 b: Saturated thickness of aquifer b 27.28
HGWE - DWDE
* If no telescoping well, use H
KV/KH: Vertical/Horizontal KV/KH 0.1 Use 0.1
8 D: Casing length 0 Use 0.0 If water table intersects screen
L: Well screen length 11.40 Use H If H is less than L
9 R(c ): Inside radius of well casing R(c)0.085 Use 0.085 for 2" wells; use 0.167 for 4" wells
R(w): Well radius R(w)0.2500 1/2 auger outside diameter in feet
R(sk): Well skin radius R(sk)0.2500 1/2 auger outside diameter in feet
10 N(e): N(e): 0.3 Use 0.3
H(o): H(o)1.75 Use H(o)
P&K Mart
Wilson, NC
GMW-2
9/27/2021
AQTESOLV DATA ENTRY FORM
(For wells screened ACROSS water table)
File: AQTESOLV Data Entry Form GMW-2
P&K Mart
Well GMW-2
Test Date 09/27/21
Initial DTW (ft) 3.60

Time Displacement
(min) (ft)
0.000 0.0000
0.017 2.0858
0.033 1.2308
0.050 1.3390
0.067 1.1849
0.083 1.1806
0.100 1.0910
0.117 1.0684
0.133 0.9989
0.150 0.9746
0.167 0.9222
0.183 0.8978
0.200 0.8605
0.217 0.8390
0.233 0.8159
0.250 0.8000
0.267 0.7846
0.283 0.7731
0.300 0.7631
0.317 0.7540
0.333 0.7452
0.350 0.7387
0.367 0.7331
0.383 0.7279
0.400 0.7222
0.417 0.7182
0.433 0.7118
0.450 0.7084
0.467 0.7034
0.483 0.7005
0.500 0.6968
0.517 0.6933
0.533 0.6897
0.550 0.6869
0.567 0.6858
Time Displacement
(min) (ft)
0.583 0.6825
0.600 0.6821
0.617 0.6777
0.633 0.6745
0.650 0.6731
0.667 0.6715
0.683 0.6714
0.700 0.6675
0.717 0.6611
0.733 0.6626
0.750 0.6627
0.767 0.6579
0.783 0.6591
0.800 0.6580
0.817 0.6585
0.833 0.6575
0.850 0.6560
0.867 0.6547
0.883 0.6534
0.900 0.6511
0.917 0.6515
0.933 0.6486
0.950 0.6504
0.967 0.6480
0.983 0.6474
1.000 0.6463
1.017 0.6455
1.033 0.6446
1.050 0.6429
1.067 0.6428
1.083 0.6411
1.100 0.6413
1.117 0.6403
1.133 0.6404
1.150 0.6406
1.167 0.6378
1.183 0.6383
1.200 0.6369
1.217 0.6358
1.233 0.6346
1.250 0.6353
Time Displacement
(min) (ft)
1.267 0.6348
1.283 0.6336
1.300 0.6325
1.317 0.6316
1.333 0.6316
1.350 0.6310
1.367 0.6320
1.383 0.6294
1.400 0.6305
1.417 0.6302
1.433 0.6278
1.450 0.6287
1.467 0.6291
1.483 0.6274
1.500 0.6266
1.517 0.6271
1.533 0.6257
1.550 0.6245
1.567 0.6260
1.583 0.6252
1.600 0.6249
1.617 0.6240
1.633 0.6236
1.650 0.6234
1.667 0.6214
1.683 0.6225
1.700 0.6218
1.717 0.6214
1.733 0.6216
1.750 0.6216
1.767 0.6201
1.783 0.6212
1.800 0.6197
1.817 0.6194
1.833 0.6191
1.850 0.6193
1.867 0.6188
1.883 0.6183
1.900 0.6189
1.917 0.6197
1.933 0.6180
Time Displacement
(min) (ft)
1.950 0.6190
1.967 0.6179
1.983 0.6168
2.000 0.6155
2.017 0.6163
2.033 0.6163
2.050 0.6156
2.067 0.6161
2.083 0.6157
2.100 0.6154
2.117 0.6144
2.133 0.6143
2.150 0.6151
2.167 0.6143
2.183 0.6150
2.200 0.6148
2.217 0.6133
2.233 0.6129
2.250 0.6134
2.267 0.6125
2.283 0.6125
2.300 0.6115
2.317 0.6130
2.333 0.6117
2.350 0.6120
2.367 0.6094
2.383 0.6108
2.400 0.6089
2.417 0.6108
2.433 0.6088
2.450 0.6100
2.467 0.6104
2.483 0.6084
2.500 0.6089
2.517 0.6078
2.533 0.6080
2.550 0.6086
2.567 0.6077
2.583 0.6089
2.600 0.6096
2.617 0.6065
Time Displacement
(min) (ft)
2.633 0.6066
2.650 0.6059
2.667 0.6065
2.683 0.6078
2.700 0.6063
2.717 0.6062
2.733 0.6062
2.750 0.6068
2.767 0.6063
2.783 0.6055
2.800 0.6068
2.817 0.6034
2.833 0.6053
2.850 0.6054
2.867 0.6059
2.883 0.6042
2.900 0.6034
2.917 0.6033
2.933 0.6034
2.950 0.6052
2.967 0.6030
2.983 0.6042
3.000 0.6031
3.017 0.6055
3.033 0.6034
3.050 0.6026
3.067 0.6037
3.083 0.6023
3.100 0.6030
3.117 0.6021
3.133 0.6011
3.150 0.6012
3.167 0.6011
3.183 0.6029
3.200 0.6017
3.217 0.6024
3.233 0.6015
3.250 0.6012
3.267 0.6009
3.283 0.6011
3.300 0.6012
Time Displacement
(min) (ft)
3.317 0.5994
3.333 0.6006
3.350 0.5996
3.367 0.5998
3.383 0.6015
3.400 0.5995
3.417 0.5997
3.433 0.5995
3.450 0.5990
3.467 0.5991
3.483 0.5992
3.500 0.6002
3.517 0.5991
3.533 0.5984
3.550 0.5995
3.567 0.5984
3.583 0.5990
3.600 0.5978
3.617 0.5977
3.633 0.5983
3.650 0.5982
3.667 0.5977
3.683 0.5981
3.700 0.5985
3.717 0.5979
3.733 0.5968
3.750 0.5965
3.767 0.5970
3.783 0.5961
3.800 0.5966
3.817 0.5975
3.833 0.5972
3.850 0.5952
3.867 0.5968
3.883 0.5971
3.900 0.5971
3.917 0.5961
3.933 0.5967
3.950 0.5957
3.967 0.5963
3.983 0.5954
Time Displacement
(min) (ft)
4.000 0.5962

0. 1.2 2.4 3.6 4.8 6.
0.1
1.
10.
Time (min)Displacement (ft)WELL TEST ANALYSIS
Data Set: F:\...\GMW-4.aqt
Date: 12/16/21 Time: 15:51:02
PROJECT INFORMATION
Company: Geological Resources, Inc.
Client: P&K Food Mart
Project: 5079
Location: Wilson, NC
Test Well: GMW-4
Test Date: 9/27/21
AQUIFER DATA
Saturated Thickness: 27.28 ft Anisotropy Ratio (Kz/Kr): 0.1
WELL DATA (New Well)
Initial Displacement: 1.75 ft Static Water Column Height: 11.77 ft
Total Well Penetration Depth: 10. ft Screen Length: 10. ft
Casing Radius: 0.085 ft Well Radius: 0.25 ft
SOLUTION
Aquifer Model: Unconfined Solution Method: Bouwer-Rice
K = 0.0001401 ft/min y0 = 0.6241 ft
Page Item Value Remarks
NA Static depth to water (SDTW) from TOC SDTW 3.23 Test well (ft)
Initial DTW (IDTW) - after remove/introduce slug from TOC IDTW 4.98 Test well (ft)
Total well depth (TWD)TWD 15.00 Test well (ft)
Top of Casing Elevation (TOC)TOC 99.73 Test well (ft)
Highest ground water elevation at site (HGWE)HGWE 97.31 All site wells (ft)
Deepest well depth elevation (DWDE)DWDE 70.03 Deepest well (ft)
5 Project Name
Project location (city, state)
Test Well #
Date slug test conducted
6 H(o): Initial displacement (IDTW minus SDTW (ft))H(o)1.75 Use 1.75
H: Static water column height H 11.77 TWD minus SDTW (ft)
Well #GMW-4 Test well ID
7 b: Saturated thickness of aquifer b 27.28
HGWE - DWDE
* If no telescoping well, use H
KV/KH: Vertical/Horizontal KV/KH 0.10 Use 0.1
8 D: Casing length D 1.77 TWD minus SDTW minus screen length (ft)
L: Well screen length L 10.00 Screen length (ft)
9 R(c ): Inside radius of well casing R(c)0.085 Use 0.085 for 2" wells; use 0.167 for 4" wells(ft)
R(w): Well radius R(w)0.2500 1/2 auger outside diameter (ft)
R(sk): Well skin radius R(sk)0.2500 1/2 auger outside diameter (ft)
9/27/2021
AQTESOLV DATA ENTRY FORM
(For wells screened BELOW water table)
P&K Mart
Wilson, NC
GMW-4
File: AQTESOLV Data Entry Form GMW-2
P&K Mart
Well GMW-4
Test Date 09/27/21
Initial DTW (ft) 3.23

Time Displacement
(min) (ft)
0.000 0.000
0.017 1.966
0.033 1.715
0.050 1.431
0.067 1.367
0.083 1.304
0.100 1.242
0.117 1.181
0.133 1.128
0.150 1.074
0.167 1.025
0.183 0.979
0.200 0.940
0.217 0.908
0.233 0.876
0.250 0.848
0.267 0.823
0.283 0.800
0.300 0.781
0.317 0.766
0.333 0.752
0.350 0.740
0.367 0.728
0.383 0.720
0.400 0.710
0.417 0.702
0.433 0.695
0.450 0.688
0.467 0.682
0.483 0.676
0.500 0.672
0.517 0.664
0.533 0.649
0.550 0.657
0.567 0.651
Time Displacement
(min) (ft)
0.583 0.647
0.600 0.642
0.617 0.637
0.633 0.634
0.650 0.626
0.667 0.624
0.683 0.621
0.700 0.618
0.717 0.618
0.733 0.614
0.750 0.610
0.767 0.607
0.783 0.604
0.800 0.602
0.817 0.600
0.833 0.597
0.850 0.595
0.867 0.591
0.883 0.589
0.900 0.588
0.917 0.585
0.933 0.582
0.950 0.581
0.967 0.577
0.983 0.577
1.000 0.576
1.017 0.572
1.033 0.569
1.050 0.569
1.067 0.565
1.083 0.564
1.100 0.562
1.117 0.561
1.133 0.561
1.150 0.557
1.167 0.556
1.183 0.554
1.200 0.552
1.217 0.549
1.233 0.549
1.250 0.547
Time Displacement
(min) (ft)
1.267 0.545
1.283 0.543
1.300 0.543
1.317 0.540
1.333 0.539
1.350 0.538
1.367 0.535
1.383 0.534
1.400 0.532
1.417 0.530
1.433 0.529
1.450 0.524
1.467 0.525
1.483 0.523
1.500 0.522
1.517 0.522
1.533 0.519
1.550 0.518
1.567 0.517
1.583 0.516
1.600 0.514
1.617 0.513
1.633 0.513
1.650 0.511
1.667 0.509
1.683 0.508
1.700 0.507
1.717 0.504
1.733 0.503
1.750 0.503
1.767 0.502
1.783 0.500
1.800 0.501
1.817 0.497
1.833 0.496
1.850 0.495
1.867 0.493
1.883 0.494
1.900 0.492
1.917 0.491
1.933 0.491
Time Displacement
(min) (ft)
1.950 0.488
1.967 0.488
1.983 0.487
2.000 0.485
2.017 0.483
2.033 0.483
2.050 0.482
2.067 0.480
2.083 0.480
2.100 0.477
2.117 0.478
2.133 0.478
2.150 0.476
2.167 0.477
2.183 0.474
2.200 0.472
2.217 0.472
2.233 0.471
2.250 0.469
2.267 0.469
2.283 0.468
2.300 0.466
2.317 0.466
2.333 0.466
2.350 0.464
2.367 0.464
2.383 0.462
2.400 0.461
2.417 0.461
2.433 0.460
2.450 0.457
2.467 0.458
2.483 0.455
2.500 0.456
2.517 0.455
2.533 0.454
2.550 0.452
2.567 0.452
2.583 0.451
2.600 0.451
2.617 0.448
Time Displacement
(min) (ft)
2.633 0.448
2.650 0.447
2.667 0.446
2.683 0.445
2.700 0.445
2.717 0.443
2.733 0.444
2.750 0.442
2.767 0.441
2.783 0.441
2.800 0.440
2.817 0.440
2.833 0.438
2.850 0.437
2.867 0.437
2.883 0.436
2.900 0.437
2.917 0.435
2.933 0.434
2.950 0.434
2.967 0.433
2.983 0.432
3.000 0.432
3.017 0.429
3.033 0.429
3.050 0.429
3.067 0.428
3.083 0.426
3.100 0.426
3.117 0.425
3.133 0.421
3.150 0.424
3.167 0.424
3.183 0.423
3.200 0.422
3.217 0.420
3.233 0.420
3.250 0.419
3.267 0.420
3.283 0.418
3.300 0.419
Time Displacement
(min) (ft)
3.317 0.416
3.333 0.418
3.350 0.416
3.367 0.414
3.383 0.415
3.400 0.415
3.417 0.414
3.433 0.413
3.450 0.413
3.467 0.411
3.483 0.410
3.500 0.410
3.517 0.409
3.533 0.409
3.550 0.408
3.567 0.406
3.583 0.407
3.600 0.405
3.617 0.404
3.633 0.404
3.650 0.403
3.667 0.402
3.683 0.402
3.700 0.403
3.717 0.401
3.733 0.400
3.750 0.400
3.767 0.399
3.783 0.398
3.800 0.396
3.817 0.397
3.833 0.396
3.850 0.395
3.867 0.395
3.883 0.395
3.900 0.393
3.917 0.393
3.933 0.393
3.950 0.393
3.967 0.391
3.983 0.391
Time Displacement
(min) (ft)
4.000 0.390
4.017 0.389
4.033 0.387
4.050 0.388
4.067 0.386
4.083 0.388
4.100 0.386
4.117 0.386
4.133 0.385
4.150 0.386
4.167 0.382
4.183 0.383
4.200 0.384
4.217 0.382
4.233 0.380
4.250 0.380
4.267 0.380
4.283 0.379
4.300 0.378
4.317 0.378
4.333 0.380
4.350 0.378
4.367 0.374
4.383 0.375
4.400 0.375
4.417 0.375
4.433 0.373
4.450 0.372
4.467 0.372
4.483 0.373
4.500 0.369
4.517 0.371
4.533 0.370
4.550 0.369
4.567 0.370
4.583 0.368
4.600 0.368
4.617 0.366
4.633 0.367
4.650 0.366
4.667 0.364
Time Displacement
(min) (ft)
4.683 0.365
4.700 0.366
4.717 0.364
4.733 0.363
4.750 0.363
4.767 0.363
4.783 0.363
4.800 0.362
4.817 0.362
4.833 0.362
4.850 0.361
4.867 0.360
4.883 0.359
4.900 0.358
4.917 0.356
4.933 0.358
4.950 0.357
4.967 0.356
4.983 0.356
5.000 0.356
5.017 0.355
5.033 0.354
5.050 0.354
5.067 0.354
5.083 0.351
5.100 0.353
5.117 0.352
5.133 0.352
5.150 0.351
5.167 0.351
5.183 0.351
5.200 0.349
5.217 0.349
5.233 0.348
5.250 0.348
5.267 0.347
5.283 0.345
5.300 0.346
5.317 0.346
5.333 0.344
5.350 0.345
Time Displacement
(min) (ft)
5.367 0.343
5.383 0.343
5.400 0.343
5.417 0.342
5.433 0.342
5.450 0.342
5.467 0.343
5.483 0.341
5.500 0.341
5.517 0.340
5.533 0.340
5.550 0.339
5.567 0.339
5.583 0.338
5.600 0.338
5.617 0.338
5.633 0.337
5.650 0.336
5.667 0.336
5.683 0.335
5.700 0.335
5.717 0.335
5.733 0.334
5.750 0.332
5.767 0.333
5.783 0.333
5.800 0.331
5.817 0.330
5.833 0.331
5.850 0.330
5.867 0.331
5.883 0.330
5.900 0.328
5.917 0.328
5.933 0.328
5.950 0.328
5.967 0.327
5.983 0.328
6.000 0.327

0. 0.8 1.6 2.4 3.2 4.
1.
10.
Time (min)Displacement (ft)WELL TEST ANALYSIS
Data Set: F:\...\DW-1.aqt
Date: 12/16/21 Time: 15:46:56
PROJECT INFORMATION
Company: Geological Resources, Inc.
Client: P&K Food Mart
Project: 5079
Location: Wilson, NC
Test Well: DW-1
Test Date: 9/27/21
AQUIFER DATA
Saturated Thickness: 27.28 ft Anisotropy Ratio (Kz/Kr): 0.1
WELL DATA (New Well)
Initial Displacement: 1.75 ft Static Water Column Height: 22.23 ft
Total Well Penetration Depth: 22.23 ft Screen Length: 5. ft
Casing Radius: 0.085 ft Well Radius: 0.25 ft
SOLUTION
Aquifer Model: Unconfined Solution Method: Bouwer-Rice
K = 4.105E-5 ft/min y0 = 1.73 ft
Page Item Value Remarks
NA Static depth to water (SDTW) from TOC SDTW 7.77 Test well (ft)
Initial DTW (IDTW) - after remove/introduce slug from TOC IDTW 9.52 Test well (ft)
Total well depth (TWD)TWD 30.00 Test well (ft)
Top of Casing Elevation (TOC)TOC 100.03 Test well (ft)
Highest ground water elevation at site (HGWE)HGWE 97.31 All site wells (ft)
Deepest well depth elevation (DWDE)DWDE 70.03 Deepest well (ft)
5 Project Name
Project location (city, state)
Test Well #
Date slug test conducted
6 H(o): Initial displacement (IDTW minus SDTW (ft))H(o)1.75 Use 1.75
H: Static water column height H 22.23 TWD minus SDTW (ft)
Well #DW-1 Test well ID
7 b: Saturated thickness of aquifer b 27.28
HGWE - DWDE
* If no telescoping well, use H
KV/KH: Vertical/Horizontal KV/KH 0.10 Use 0.1
8 D: Casing length D 17.23 TWD minus SDTW minus screen length (ft)
L: Well screen length L 5.00 Screen length (ft)
9 R(c ): Inside radius of well casing R(c)0.085 Use 0.085 for 2" wells; use 0.167 for 4" wells(ft)
R(w): Well radius R(w)0.2500 1/2 auger outside diameter (ft)
R(sk): Well skin radius R(sk)0.2500 1/2 auger outside diameter (ft)
9/27/2021
AQTESOLV DATA ENTRY FORM
(For wells screened BELOW water table)
P&K Mart
Wilson, NC
DW-1
File: AQTESOLV Data Entry Form GMW-2
P&K Mart
Well DW-1
Test Date 09/27/21
Initial DTW (ft) 7.77

Time Displacement
(min) (ft)
0 0
0.017 1.781
0.033 1.743
0.050 1.761
0.067 1.752
0.083 1.742
0.100 1.742
0.117 1.733
0.133 1.733
0.150 1.732
0.167 1.733
0.183 1.733
0.200 1.733
0.217 1.722
0.233 1.723
0.250 1.723
0.267 1.723
0.283 1.723
0.300 1.722
0.317 1.723
0.333 1.723
0.350 1.723
0.367 1.713
0.383 1.713
0.400 1.712
0.417 1.712
0.433 1.712
0.450 1.713
0.467 1.712
0.483 1.712
0.500 1.712
0.517 1.713
0.533 1.711
0.550 1.713
0.567 1.713
Time Displacement
(min) (ft)
0.583 1.712
0.600 1.713
0.617 1.713
0.633 1.713
0.650 1.712
0.667 1.702
0.683 1.703
0.700 1.702
0.717 1.703
0.733 1.702
0.750 1.702
0.767 1.702
0.783 1.702
0.800 1.703
0.817 1.703
0.833 1.703
0.850 1.702
0.867 1.702
0.883 1.703
0.900 1.702
0.917 1.702
0.933 1.701
0.950 1.702
0.967 1.693
0.983 1.692
1.000 1.693
1.017 1.692
1.033 1.692
1.050 1.692
1.067 1.692
1.083 1.692
1.100 1.692
1.117 1.692
1.133 1.693
1.150 1.692
1.167 1.692
1.183 1.692
1.200 1.692
1.217 1.692
1.233 1.692
1.250 1.692
Time Displacement
(min) (ft)
1.267 1.692
1.283 1.692
1.300 1.693
1.317 1.692
1.333 1.692
1.350 1.692
1.367 1.684
1.383 1.684
1.400 1.683
1.417 1.683
1.433 1.683
1.450 1.683
1.467 1.684
1.483 1.683
1.500 1.683
1.517 1.683
1.533 1.683
1.550 1.682
1.567 1.683
1.583 1.683
1.600 1.684
1.617 1.683
1.633 1.683
1.650 1.684
1.667 1.683
1.683 1.683
1.700 1.683
1.717 1.683
1.733 1.673
1.750 1.674
1.767 1.673
1.783 1.673
1.800 1.673
1.817 1.673
1.833 1.674
1.850 1.673
1.867 1.672
1.883 1.674
1.900 1.673
1.917 1.673
1.933 1.673
Time Displacement
(min) (ft)
1.950 1.674
1.967 1.673
1.983 1.673
2.000 1.674
2.017 1.673
2.033 1.672
2.050 1.673
2.067 1.672
2.083 1.673
2.100 1.673
2.117 1.673
2.133 1.673
2.150 1.673
2.167 1.673
2.183 1.674
2.200 1.663
2.217 1.663
2.233 1.663
2.250 1.663
2.267 1.663
2.283 1.663
2.300 1.663
2.317 1.663
2.333 1.663
2.350 1.663
2.367 1.664
2.383 1.663
2.400 1.662
2.417 1.663
2.433 1.663
2.450 1.662
2.467 1.662
2.483 1.663
2.500 1.663
2.517 1.663
2.533 1.662
2.550 1.663
2.567 1.663
2.583 1.662
2.600 1.662
2.617 1.662
Time Displacement
(min) (ft)
2.633 1.663
2.650 1.653
2.667 1.653
2.683 1.653
2.700 1.652
2.717 1.652
2.733 1.653
2.750 1.653
2.767 1.653
2.783 1.652
2.800 1.653
2.817 1.652
2.833 1.653
2.850 1.651
2.867 1.651
2.883 1.652
2.900 1.653
2.917 1.652
2.933 1.653
2.950 1.652
2.967 1.652
2.983 1.653
3.000 1.651
3.017 1.652
3.033 1.652
3.050 1.652
3.067 1.651
3.083 1.651
3.100 1.651
3.117 1.653
3.133 1.652
3.150 1.642
3.167 1.642
3.183 1.642
3.200 1.643
3.217 1.641
3.233 1.642
3.250 1.642
3.267 1.642
3.283 1.642
3.300 1.642
Time Displacement
(min) (ft)
3.317 1.642
3.333 1.642
3.350 1.642
3.367 1.642
3.383 1.642
3.400 1.642
3.417 1.642
3.433 1.642
3.450 1.642
3.467 1.641
3.483 1.642
3.500 1.642
3.517 1.641
3.533 1.642
3.550 1.642
3.567 1.642
3.583 1.641
3.600 1.641
3.617 1.642
3.633 1.641
3.650 1.641
3.667 1.631
3.683 1.632
3.700 1.632
3.717 1.631
3.733 1.632
3.750 1.631
3.767 1.631
3.783 1.631
3.800 1.631
3.817 1.631
3.833 1.631
3.850 1.63
3.867 1.631
3.883 1.631
3.900 1.63
3.917 1.631
3.933 1.631
3.950 1.631
3.967 1.631
3.983 1.632
Time Displacement
(min) (ft)
4.000 1.631

Appendix E
Notification of Local Official

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
September 30, 2022

Ms. Denise Stinagle
County Manager – Wilson County
2201 Miller Rd. South
Wilson, NC 27893

Re: Comprehensive Site Assessment – Public Notice
P&K Mart
1510 Goldsboro Street South
Wilson, Wilson County, North Carolina
Incident No. 19233/46552
GRI Project No. 5079

Dear Ms. Stinagle,

A petroleum release was reported at the above referenced property. In conjunction with North Carolina
Department of Environmental Quality (NCDEQ) requirements, soil and ground water assessment activities,
including those Site Check, Phase I Limited Site Assessment and Comprehensive Site Assessment (CSA),
were conducted at the site.

Please find enclosed a copy of the executive summary and pertinent figures and tables associated with the
CSA Report for the above referenced site in accordance with the public notice requirements listed 15A
NCAC 2L .0114 of the Guidelines for Assessment and Corrective Action published by the UST Section of
NCDEQ.

Please do not hesitate to contact the undersigned at [phone], if you have any questions or comments.

Sincerely
Geological Resources, Inc.

Rae Troiano Brown
Project Manager

enclosure

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
September 30, 2022

The Honorable Carlton Stevens
Mayor, City of Wilson
P.O. Box 10
Wilson, NC 27894-0010

Re: Comprehensive Site Assessment – Public Notice
P&K Mart
1510 Goldsboro Street South
Wilson, Wilson County, North Carolina
Incident No. 19233/46552
GRI Project No. 5079

Dear Mayor Baldwin,

A petroleum release was reported at the above referenced property. In conjunction with North Carolina
Department of Environmental Quality (NCDEQ) requirements, soil and ground water assessment activities,
including those for Site Check, Phase I Limited Site Assessment, and Comprehensive Site Assessment
(CSA), were conducted at the site.

Please find enclosed a copy of the executive summary and pertinent figures and tables associated with the
CSA Report for the above referenced site in accordance with the public notice requirements listed 15A
NCAC 2L .0114 of the Guidelines for Assessment and Corrective Action published by the UST Section of
NCDEQ.

Please do not hesitate to contact the undersigned at [phone], if you have any questions or comments.

Sincerely
Geological Resources, Inc.

Rae Troiano Brown
Project Manager

enclosure

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
September 30, 2022

Mr. DeEtt Taylor
Environmental Health Director
1801 Glendale Drive SW
Wilson, NC 27893

Re: Comprehensive Site Assessment – Public Notice
P&K Mart
1510 Goldsboro Street South
Wilson, Wilson County, North Carolina
Incident No. 19233/46552
GRI Project No. 5079

Dear Mr. Taylor,

A petroleum release was reported at the above referenced property. In conjunction with North Carolina
Department of Environmental Quality (NCDEQ) requirements, soil and ground water assessment activities,
including those for Site Check, Phase I Limited Site Assessment and Comprehensive Site Assessment
(CSA), were conducted at the site.

Please find enclosed a copy of the executive summary and pertinent figures and tables associated with the
CSA Report for the above referenced site in accordance with the public notice requirements listed 15A
NCAC 2L .0114 of the Guidelines for Assessment and Corrective Action published by the UST Section of
NCDEQ.

Please do not hesitate to contact the undersigned at [phone], if you have any questions or comments.

Sincerely
Geological Resources, Inc.

Rae Troiano Brown
Project Manager

enclosure