RA-2643_16487_CA_SCP_20181008_And CLO

EXECUTIVE SUMMARY

Whitley Texaco is located at 401 East Main Street in Woodland, Northampton County, North Carolina.
According to the available information, a petroleum release occurred from an underground storage tank
(UST) system consisting of five 550-gallon gasoline USTs. The site risk classification is currently Low
risk.

An updated receptor survey was conducted on September 12, 2018, in which one municipal water supply
well was identified within a 1,500-foot radius of the site. Currently, the water supply well is not in use,
however, the Town of Woodland plans to begin using the well in the near future. The well has been
drilled to a total depth of 405 feet and is screened between 275 and 3005 and also 360 to 385 feet. Three
confining units exist between the surficial aquifer and screened interval of the well. The site is not
located in an approved wellhead protection area.

On September 12, 2018, two soil borings were installed at the site. Concentrations of requested method
constituents that exceeded the soil-to-water Maximum Contaminant Concentrations (MACs) were
reported in the soil sample collected from SB-1 4.5-5’. None of the reported contaminant concentrations
exceeded the Residential Soil Cleanup Levels.

On September 12, 2018, four monitoring wells were gauged, purged and sampled. Contaminant
concentrations exceeding the applicable ground water quality standards were reported in the ground water
sample collected from MW-1 and MW-3. None of the reported contaminant concentrations exceeded the
Gross Contamination Levels.

Based on this information, the newly installed municipal well does not appear to be at risk due to the
depth to well screen and the presence of three confining units between the surficial aquifer and well
screen. A Notice of Residual Petroleum for Ground Water should be filed on the deed of the subject
property and the incident should be closed.

TABLE OF CONTENTS
1.0 SITE HISTORY AND CHARACTERIZATION ....................................................................... 1
2.0 CURRENT SITE ASSESSMENT ................................................................................................ 1
3.0 UPDATED RECEPTOR SURVEY .............................................................................................. 1
4.0 SOIL QUALITY ............................................................................................................................ 2
5.0 GROUND WATER QUALITY .................................................................................................... 2
6.0 CONCLUSIONS AND RECOMMENDATIONS ....................................................................... 3
7.0 LIMITATIONS .............................................................................................................................. 3

FIGURES
Figure 1: Site Location Map
Figure 2: Site Vicinity Map
Figure 3: Site Map
Figure 4: Soil Quality Map
Figure 5: Ground Water Flow Map
Figure 6: Ground Water Quality Map

TABLES

Table 1: Adjacent Property Owner Information
Table 2: Water Supply Well Information
Table 3: Summary of Soil Sample Analytical Results
Table 4: Well Construction and Gauging Information
Table 5: Summary of Ground Water Sample Analytical Results

APPENDICES
Appendix A: Soil Boring Logs
Appendix B: Laboratory Report – Soil and Ground Water Samples

1
1.0 SITE HISTORY AND CHARACTERIZATION
The Whitley Texaco site is located at 403 East Main Street in Woodland, Northampton County, North
Carolina (Figure 1). According to the limited available information, a petroleum release occurred from
an underground storage tank (UST) system consisting of five 550-gallon gasoline USTs that were
removed from the site on December 28, 1994.

Please note, information regarding past assessment and/or remediation activities is limited. Past reports
for the incident could not be located during a file review at NCDEQ. Historical information regarding the
incident was obtained by using the NCDEQ Registered Underground Storage Tank (RUST) database,
NCDEQ Registered Tank Report and well tags. Three Type II monitoring wells (MW-1, MW-2 and
MW-3) and one Type III monitoring well (MWD-4) were identified on-site. Please note, only one well
tag identified a well designation (MW-1). The identifications of MW-2, MW-3 and MWD-4 are assumed
based on the well construction dates noted on the well tags. The adjoining properties are commercial and
residential. Municipal water is available to the site and all properties in the surrounding area.

Please note, past assessment activities were conducted by previous consultants. Geological Resources,
Inc. (GRI) cannot verify the accuracy of past reports, but for the purpose of this report, they are assumed
to be correct.

2.0 CURRENT SITE ASSESSMENT
The purpose of this report is to present the results of updated receptor survey and soil & ground water
sampling activities conducted on September 12, 2018, at the Whitley Texaco site. The activities were
conducted in accordance with GRI proposal number 18-472 which was submitted to C. Wood Beasley III
on August 17, 2018, and approved on August 22, 2018. The purpose of the activities was to update
receptor information and to obtain current soil and ground water quality data for the site.

3.0 UPDATED RECEPTOR SURVEY
On September 12, 2018, GRI personnel conducted an updated receptor survey at the site. One municipal
water supply well was identified within a 1,500-foot radius of the site. According to the Town of
Woodland, the well is not currently in use, however, the well is scheduled to go on-line in the near future.
Additionally, the well has been drilled to a total depth of 405 feet below grade surface (bgs) with screened
intervals of 275 to 300 feet and 360 to 385 feet bgs. Three confining units exist between the surficial
aquifer and screened interval of the well. Municipal water is available to the site and surrounding

2
properties. The site does not lie within a designated wellhead protection area. No surface water bodies
were identified within a 500-foot radius of the site. A Site Vicinity Map showing the location of WSW-1
is included as Figure 2. A Site Map showing the locations of structures onsite is included as Figure 3.
Adjacent property owner information is included as Table 1. Water supply well information is included
as Table 2.
4.0 SOIL QUALITY
Two soil borings (SB-1 (4.5-5’) and SB-2 (4.5-5’)) were installed at the site on September 12, 2018. The
soil borings were installed to total depths of 4.5 to 5 feet. The soil samples were collected from the
terminus of each boring and were submitted for laboratory analyses of volatile organic compounds
(VOCs) using EPA Method 8260B and VPH using the MADEP Method. Concentrations of naphthalene,
isopropylbenzene, n-propylbenzene, C5-C8 aliphatics and C9-C10 aromatics that exceeded the soil-to-
water Maximum Contaminant Concentrations (MCCs) were reported in the soil sample collected from
SB-1 (4.5-5’). None of the reported contaminant concentrations exceeded the residential Soil Cleanup
Levels. A Soil Quality Map is included as Figure 4. A summary of soil sample analytical results is
presented in Table 3. Soil boring logs are included as Appendix A. A laboratory report for soil samples
collected in September 2018 is included as Appendix B.
5.0 GROUND WATER QUALITY
Four Type II monitoring wells (MW-1, MW-2, MW-3 and MWD-4) were gauged, purged and sampled on
September 12, 2018. The depths to ground water in the Type II monitoring wells during the September
2018 sampling event ranged from 12.32 to 12.77 feet below the tops of well casings. Top of casing
information was not available, therefore, ground water elevations and ground water flow direction were
not calculated. A summary of well construction information including ground water elevation data is
presented in Table 4.

Laboratory analyses were performed on the ground water samples collected from the monitoring wells
during the September 2018 sampling event for VOCs using EPA Method 6200B.

Concentrations of benzene that exceeded the Maximum Allowable Concentrations (MACs) specified in
T15A NCAC 2L.0202 were reported in the ground water samples collected from MW-1 and MW-3.
None of the reported contaminant concentrations exceeded the Gross Contamination Levels (GCLs). A
Ground Water Quality Map based on data from the September 2018 sampling event has been included as
Figure 4. A summary of ground water sample analytical results is presented in Table 5. A complete
copy of the laboratory report has been included in Appendix B.

3
6.0 CONCLUSIONS AND RECOMMENDATIONS
 The site is located within the Town of Woodland, Northampton County. One potential potable
municipal water supply well was identified within a 1,500-foot radius of the site. The municipal
well is not currently in use, however, the Town of Woodland plans on putting the well on-line in
the near future. Additionally, the well has been drilled to a total depth of 405 feet below grade
surface (bgs) with screened intervals of 275 to 300 feet and 360 to 385 feet bgs. Three confining
units exist between the surficial aquifer and screened interval of the well. Municipal water is
available to the site and surrounding properties. The site is not located within a designated
wellhead protection area. No surface water bodies were identified within a 500-foot radius of the
site.
 The average depth to ground water in the Type II monitoring wells in September 2018 was 12.54
feet. Ground water flow during the September 2018 gauging event was not calculated due to
limited available data.
 Concentrations of naphthalene, isopropylbenzene, n-propylbenzene, C5-C8 aliphatics, and C9-
C10 aromatics that exceeded the soil-to-water MCCs were reported in the soil sample collected
from SB-1 (4.5-5’). None of the reported contaminant concentrations exceeded the residential
Soil Cleanup Levels.
 Concentrations of benzene that exceeded the MACs were reported in the ground water samples
collected from MW-1 and MW-3. None of the reported contaminant concentrations exceeded the
GCLs.
 Based on this information, the newly installed municipal well does not appear to be at risk due to
the depth to well screen and the presence of three confining units between the surficial aquifer
and well screen. A Notice of Residual Petroleum for Ground Water should be filed on the deed
of the subject property and the incident should be closed.

7.0 LIMITATIONS
This report has been prepared for the exclusive use of North East Oil Company, Inc. for specific
application to the referenced site in Northampton County, North Carolina. The assessment was conducted
based on the scope of work and level of effort desired by NCDEQ and with resources adequate only for
that scope of work. Our findings have been developed in accordance with generally accepted standards of
environmental practices in the State of North Carolina, available information, and our professional
judgment. No other warranty is expressed or implied.
The data that are presented in this report are indicative of conditions that existed at the precise locations

4
sampled and at the time the samples were collected. In addition, the data obtained from samples would be
interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data. Please note that field data collected prior
to the September 2018 sampling and updated receptor survey event were not obtained under the
supervision of GRI. Although the accuracy of this information cannot be verified, for the purpose of this
report GRI assumes that it is correct.

FIGURES
Copyright (C) 2009 MyTopo
SCALE 1:24000
0 1000 2000 3000 4000 5000
FEET
Declination
MN 10.18° W

MN
Location: 036.3344100° N 077.2093340° WDate: 10/04/18
Scale: 1 inch = 2,000 ft.
Copyright (C) 2009 MyTopo
Figure 1
Site Location Map
Whitley Texaco
US Highway 258 & Carter Street, Woodland,
Northampton, NC
Incident No. 16487
GRI Project No. 4869
"J
SITE
5924-75-0380
5924-75-6141
5924-65-8478 5924-75-5532
5924-75-33345924-75-44405924-75-4492WSW-1
Sources: Esri, HERE, Garmin, USGS, Intermap, INCREMENT P, NRCan, Esri Japan, METI, Esri China (Hong Kong), Esri Korea, Esri (Thailand), NGCC, ©OpenStreetMap contributors, and the GIS User Community
FIGURE 2: SITE VICINITY MAPWHITLEY TEXACOUS HIGHWAY 258 & CARTER STREETWOODLAND, NORTHAMPTON COUNTYNORTH CAROLINAINCIDENT NO. <PENDING>GRI PROJECT NO. 4869
PREPARED BY:GEOLOGICAL RESOURCES, INC.SEPTEMBER 7, 2018
³
0 300150
Feet
1 inch = 300 feet
LEGEND
Well Ower and Adjacent Properties
"J Water Supply Well (Not In Use)
Northampton County NC Parcels

TABLES
Date: 09/21/18 Facility ID #: 0-034218
5924-75-4440 (Site)Catherine J. Morton Post Office Box 614
Woodland, NC 27897
5924-75-3334 Linwood Joyner, Heirs Post Office Box 36
Woodland, NC 27897
5924-75-5532 Jeffrey M. Manley
Jacqueline E. Mitchell
1108 Ashleys Grove Road
Conway, NC 27820
5924-75-4492 Jeffrey M. Manley 1108 Ashleys Grove Road
Conway, NC 27820
5924-75-6141 James H. and Gloria V. Cloyd Post Office Box 756
Woodland, NC 27897
Note:
• Properties are keyed to Figure 2.
TABLE 1
ADJACENT PROPERTY OWNER INFORMATION
WHITLEY TEXACO (INCIDENT NO. 16487)
Parcel Number Property Owner Name Mailing Address
Date : 10/08/18 Facility ID #: 0-034218
Well ID.Parcel ID No.Well Owner Property
Address
Well Use
(Potable/Agricultural,
etc.)
Well
Depth
(ft. BGS)
Type of Well
(Drilled/
Bored)
Well Casing
Depth
(ft. BGS)
Well Screen
Interval
(x to y ft. BGS)
Distance from
source area of
release
(ft.)
WSW-1 5924-65-8563 Town of Woodland Post Office Box 297
Woodland, North Carolina 27897 Not in Use 405 Drilled 275 275 to 300
360 to 385 ~600' W
• Well construction and screened interval information obtained during telephone conversation with Town of Woodland officials on October 5, 2018.
• ft. BGS: Feet below ground surface.
TABLE 2
WATER SUPPLY WELL INFORMATION
WHITLEY TEXACO (INCIDENT NO. 16487)
Note:
• Water supply wells are keyed to Figure 2.
Page 1 of 1
Date: 09/21/18
0.0056 4.3 4.9 4.6 0.091 0.16 1.7 1.7 68 540 31
18 1,200 1,560 3,129 350 313 1,564 626 939 1,500 469
SB-1 (4.5-5')09/12/18 4.5-5 <0.097 <0.079 2.45 <0.17 <0.079 4.36 2.26 8.30 269 114 140
SB-2 (4.5-5')09/12/18 4.5-5 <0.11 <0.094 <0.094 <0.20 <0.094 <0.19 <0.094 <0.094 6.73 J 2.92 J 6.27 J
Notes:
• Results reported in mg/kg (milligrams per kilogram).
• ft-BGS: feet below ground surface.
• MCC: Maximum Contaminant Concentrations.
• SCLs: Soil clean up levels
• <: Less than the method detection limit specified in the laboratory report.
• NE: Not Established.
• Concentrations in bold face type exceed the soil-to-water MCCs.
TABLE 3
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS
WHITLEY TEXACO (INCIDENT NO. 16487)C5 - C8 AliphaticsC9 - C12 AliphaticsC9 - C10 AromaticsSample IDFacility ID #: 0-034218
Analytical Method →MTBENaphthaleneMADEP Method VPHEPA Method 8260B
Isopropylbenzenen-PropylbenzeneResidential SCLs (mg/kg)
Soil-to-Water MCCs (mg/kg)TolueneEthylbenzeneXylenesDate Collected (mm/dd/yy)Sample Depth (ft-BGS)BenzenePage 1 of 1
Date: 09/21/18
MW-1 09/19/02 09/12/18 5 5 - 20 20 NM 12.54 0.00 NM
MW-2 N/A 09/12/18 NM NM 20 NM 12.77 0.00 NM
MW-3 08/11/04 09/12/18 5 5 - 20 20 NM 12.32 0.00 NM
MWD-4 08/11/04 09/12/18 5 5 - 20 20 NM 12.87 0.00 NM
Notes:
• *Reference point for elevation measurements, elevation relative to a temporary benchmark with an assumed elevation of 100.00 ft.
• **If free product is present in a well, ground water elevation calculated by: [Top of Casing Elevation - Depth to Water] + [free product thickness x 0.8581].
• Well construction information obtained from on-site well tags.
• ft BGS : feet below ground surface.
• N/A: Not available.
• NM: Not measured.
TABLE 4
WELL CONSTRUCTION AND GAUGING INFORMATION
WHITLEY TEXACO (INCIDENT NO. 16487)
Facility ID # : 0-034218
Well ID
Date
Installed
(mm/dd/yy)
Date Water
Level
Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom of
Well
(ft. BGS)
Top of
Casing
Elevation*
(ft.)
Depth to
Water from
Top of
Casing
(ft.)
Free
Product
Thickness**
(ft.)
Groundwater
Elevation (ft.)Comments
Page 1 of 1
Date: 09/21/18
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6
5,000 260,000 84,500 85,500 20,000 6,000
MW-1 09/12/18 85.4 2.6 50.8 24.3 1.3 6.0
MW-2 09/12/18 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13
MW-3 09/12/18 13.7 1.4 0.92 5.6 0.52 4.9
MWD-4 09/12/18 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13
Notes:
• Results reported in micrograms per liter (µg/l).
• < : Less than the method detection limit specified in the laboratory report.
• 2L Standard specified in T15A NCAC 2L.0202.
• GCL: Gross contamination level.
• NR: Not Requested.
• NE: Not Established
• Concentrations in bold face type exceeded the 2L standards.
• Refer to laboratory report for detected constituents that did not exceed the MACs, or for which
no standard has been established.
TABLE 5
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
WHITLEY TEXACO (INCIDENT NO. 16487)
Facility ID: 0-034218
EthylbenzeneXylenesMTBENaphthaleneAnalytical Method EPA Method 6200B
2L Standard (µg/l)
GCL (µg/l)
Contaminant of Concern
BenzeneToluenePage 1 of 1

APPENDICES

APPENDIX A
Soil Boring Logs
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project Whitley Texaco
Address 401 E Main Street, Woodland, Northampton County
Boring Number SB-1 Date Drilled
Sample Method Grab Drilling Method Hand Auger
Completion Details soil boring - abandoned after sample collection
Driller Geological Resources, Inc.Log By William Regenthal
Lab Sample OVA
Depth Sample Interval(ft)ppm LITHOLOGY
0
2
4
X
6 Boring terminated at 6'
8
10

12
14
16

18
20
22

24
26
28

30
32
34

36
9/12/2018
0 - 0.5 Concrete
0.5 - 1 Black sandy silt
1 - 6 Brown to gray silty clay
Sample collected at 4.5-5'
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project Whitley Texaco
Address 401 E Main Street, Woodland, Northampton County
Boring Number SB-2 Date Drilled
Sample Method Grab Drilling Method Hand Auger
Completion Details soil boring - abandoned after sample collection
Driller Geological Resources, Inc.Log By William Regenthal
Lab Sample OVA
Depth Sample Interval(ft)ppm LITHOLOGY
0
2
4
X
6 Boring terminated at 6'
8
10

12
14
16

18
20
22

24
26
28

30
32
34

36
9/12/2018
0 - 3 Gray sandy gravel
3 - 6 Brown to gray silty clay
Sample collected at 4.5-5'

APPENDIX B
Laboratory Report – Soil and Ground Water Samples

09/20/18
Technical Report for
GRI (Geological Resources Inc.)
Whitley Texaco; US 258 & Carter St, Woodland, NC
SGS Job Number: FA57549
Sampling Date: 09/12/18
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]; [e-mail]
ATTN: William Regenthall
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AK, AR, IA, KY, MA, MS, ND, NH, NV, OK, OR, UT, WA, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Caitlin Brice, M.S.
General Manager
Orlando, FL 09/20/18
e-Hardcopy 2.0
Automated Report
41
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
1 of 41
FA57549
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................6
3.1: FA57549-1: SB-1 4.5-5' ...............................................................................................7
3.2: FA57549-2: SB-2 4.5-5' ...............................................................................................10
3.3: FA57549-3: MW-1 ........................................................................................................13
3.4: FA57549-4: MW-2 ........................................................................................................15
3.5: FA57549-5: MW-3 ........................................................................................................17
3.6: FA57549-6: MW-4 ........................................................................................................19
Section 4: Misc. Forms ............................................................................................................21
4.1: Chain of Custody ...........................................................................................................22
Section 5: MS Volatiles - QC Data Summaries .....................................................................24
5.1: Method Blank Summary ................................................................................................25
5.2: Blank Spike Summary ...................................................................................................29
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................33
Section 6: GC Volatiles - QC Data Summaries .....................................................................37
6.1: Method Blank Summary ................................................................................................38
6.2: Blank Spike/Blank Spike Duplicate Summary ..............................................................39
6.3: Matrix Spike Summary ..................................................................................................40
6.4: Duplicate Summary .......................................................................................................41 1234562 of 41
FA57549
SGS North America Inc.
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA57549
Whitley Texaco; US 258 & Carter St, Woodland, NC
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
FA57549-1 09/12/18 11:05 WR 09/13/18 SO Soil SB-1 4.5-5'
FA57549-2 09/12/18 11:55 WR 09/13/18 SO Soil SB-2 4.5-5'
FA57549-3 09/12/18 12:06 WR 09/13/18 AQ Ground Water MW-1
FA57549-4 09/12/18 12:00 WR 09/13/18 AQ Ground Water MW-2
FA57549-5 09/12/18 11:58 WR 09/13/18 AQ Ground Water MW-3
FA57549-6 09/12/18 12:20 WR 09/13/18 AQ Ground Water MW-4
Soil samples reported on a dry weight basis unless otherwise indicated on result page.
3 of 41
FA575491
Summary of Hits Page 1 of 2
Job Number:FA57549
Account:GRI (Geological Resources Inc.)
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
Collected:09/12/18
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA57549-1 SB-1 4.5-5'
n-Butylbenzene 4.03 0.40 0.079 mg/kg SW846 8260B
Cyclohexane 2.21 0.40 0.099 mg/kg SW846 8260B
Ethylbenzene 2.45 0.40 0.079 mg/kg SW846 8260B
Isopropylbenzene 2.26 0.40 0.079 mg/kg SW846 8260B
Methylcyclohexane 7.54 0.40 0.13 mg/kg SW846 8260B
Naphthalene 4.36 0.40 0.16 mg/kg SW846 8260B
n-Propylbenzene 8.30 0.40 0.079 mg/kg SW846 8260B
1,2,4-Trimethylbenzene 1.31 0.40 0.079 mg/kg SW846 8260B
Ethylbenzene 5.08 0.79 0.40 mg/kg MADEP VPH REV 1.1
Methyl Tert Butyl Ether 0.564 J 0.79 0.40 mg/kg MADEP VPH REV 1.1
Naphthalene 6.97 2.0 1.2 mg/kg MADEP VPH REV 1.1
Toluene 2.48 0.79 0.40 mg/kg MADEP VPH REV 1.1
o-Xylene 7.38 0.79 0.40 mg/kg MADEP VPH REV 1.1
C5- C8 Aliphatics (Unadj.) a 272 40 14 mg/kg MADEP VPH REV 1.1
C9- C12 Aliphatics (Unadj.)127 40 14 mg/kg MADEP VPH REV 1.1
C9- C10 Aromatics (Unadj.)140 40 14 mg/kg MADEP VPH REV 1.1
C5- C8 Aliphatics 269 40 14 mg/kg MADEP VPH REV 1.1
C9- C12 Aliphatics 114 40 14 mg/kg MADEP VPH REV 1.1
C9- C10 Aromatics 140 40 14 mg/kg MADEP VPH REV 1.1
FA57549-2 SB-2 4.5-5'
Methylene Chloride 0.407 J 0.94 0.38 mg/kg SW846 8260B
Ethylbenzene 0.175 0.15 0.076 mg/kg MADEP VPH REV 1.1
Naphthalene 0.406 0.38 0.23 mg/kg MADEP VPH REV 1.1
o-Xylene 0.286 0.15 0.076 mg/kg MADEP VPH REV 1.1
C5- C8 Aliphatics (Unadj.) a 6.73 J 7.6 2.7 mg/kg MADEP VPH REV 1.1
C9- C12 Aliphatics (Unadj.)3.39 J 7.6 2.7 mg/kg MADEP VPH REV 1.1
C9- C10 Aromatics (Unadj.)6.27 J 7.6 2.7 mg/kg MADEP VPH REV 1.1
C5- C8 Aliphatics 6.73 J 7.6 2.7 mg/kg MADEP VPH REV 1.1
C9- C12 Aliphatics 2.92 J 7.6 2.7 mg/kg MADEP VPH REV 1.1
C9- C10 Aromatics 6.27 J 7.6 2.7 mg/kg MADEP VPH REV 1.1
FA57549-3 MW-1
Benzene 85.4 1.0 0.25 ug/l SM 6200B
n-Butylbenzene 0.65 J 1.0 0.25 ug/l SM 6200B
sec-Butylbenzene 0.60 J 1.0 0.25 ug/l SM 6200B
Ethylbenzene 50.8 1.0 0.25 ug/l SM 6200B
Isopropylbenzene 5.2 1.0 0.25 ug/l SM 6200B
p-Isopropyltoluene 0.26 J 1.0 0.25 ug/l SM 6200B
Methyl Chloride 0.62 J 1.0 0.40 ug/l SM 6200B
Methylene Chloride 2.1 J 4.0 2.0 ug/l SM 6200B
4 of 41
FA575492
Summary of Hits Page 2 of 2
Job Number:FA57549
Account:GRI (Geological Resources Inc.)
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
Collected:09/12/18
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
Methyl Tert Butyl Ether 1.3 1.0 0.25 ug/l SM 6200B
Naphthalene 6.0 1.0 0.25 ug/l SM 6200B
n-Propylbenzene 12.1 1.0 0.25 ug/l SM 6200B
Toluene 2.6 1.0 0.25 ug/l SM 6200B
1,2,4-Trimethylbenzene 3.7 1.0 0.25 ug/l SM 6200B
m,p-Xylene 14.3 2.0 0.25 ug/l SM 6200B
o-Xylene 10 1.0 0.25 ug/l SM 6200B
Xylene (total)24.3 3.0 0.50 ug/l SM 6200B
FA57549-4 MW-2
No hits reported in this sample.
FA57549-5 MW-3
Benzene 13.7 0.50 0.13 ug/l SM 6200B
n-Butylbenzene 0.72 0.50 0.13 ug/l SM 6200B
sec-Butylbenzene 1.5 0.50 0.13 ug/l SM 6200B
tert-Butylbenzene 0.21 J 0.50 0.13 ug/l SM 6200B
1,2-Dichloroethane 0.15 J 0.50 0.13 ug/l SM 6200B
Ethylbenzene 0.92 0.50 0.13 ug/l SM 6200B
Isopropylbenzene 6.1 0.50 0.13 ug/l SM 6200B
p-Isopropyltoluene 0.21 J 0.50 0.13 ug/l SM 6200B
Methyl Chloride 0.36 J 0.50 0.20 ug/l SM 6200B
Methyl Tert Butyl Ether 0.52 0.50 0.13 ug/l SM 6200B
Naphthalene 4.9 0.50 0.13 ug/l SM 6200B
n-Propylbenzene 10.8 0.50 0.13 ug/l SM 6200B
Toluene 1.4 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 6.1 0.50 0.13 ug/l SM 6200B
1,3,5-Trimethylbenzene 0.21 J 0.50 0.13 ug/l SM 6200B
m,p-Xylene 2.5 1.0 0.13 ug/l SM 6200B
o-Xylene 3.1 0.50 0.13 ug/l SM 6200B
Xylene (total)5.6 1.5 0.25 ug/l SM 6200B
FA57549-6 MW-4
No hits reported in this sample.
(a) Associated BS/BSD recovery outside control limits high.
5 of 41
FA575492
SGS North America Inc.
Sample Results
Report of Analysis
Orlando, FL
Section 3
6 of 41
FA575493
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:SB-1 4.5-5'
Lab Sample ID:FA57549-1 Date Sampled:09/12/18
Matrix:SO - Soil Date Received:09/13/18
Method:SW846 8260B Percent Solids:71.7
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3C1791.D 1 09/14/18 13:48 SP n/a n/a V3C72
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 5.86 g 5.0 ml 100 ul
Run #2
VOA Special List
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 4.0 0.79 mg/kg
71-43-2 Benzene ND 0.40 0.097 mg/kg
75-27-4 Bromodichloromethane ND 0.40 0.079 mg/kg
75-25-2 Bromoform ND 0.40 0.079 mg/kg
78-93-3 2-Butanone (MEK)ND 2.0 0.58 mg/kg
104-51-8 n-Butylbenzene 4.03 0.40 0.079 mg/kg
75-15-0 Carbon Disulfide ND 0.40 0.079 mg/kg
56-23-5 Carbon Tetrachloride ND 0.40 0.081 mg/kg
108-90-7 Chlorobenzene ND 0.40 0.079 mg/kg
75-00-3 Chloroethane ND 0.40 0.16 mg/kg
67-66-3 Chloroform ND 0.40 0.11 mg/kg
110-82-7 Cyclohexane 2.21 0.40 0.099 mg/kg
124-48-1 Dibromochloromethane ND 0.40 0.079 mg/kg
96-12-8 1,2-Dibromo-3-chloropropane ND 0.40 0.15 mg/kg
106-93-4 1,2-Dibromoethane ND 0.40 0.079 mg/kg
75-71-8 Dichlorodifluoromethane ND 0.40 0.16 mg/kg
95-50-1 1,2-Dichlorobenzene ND 0.40 0.079 mg/kg
541-73-1 1,3-Dichlorobenzene ND 0.40 0.079 mg/kg
106-46-7 1,4-Dichlorobenzene ND 0.40 0.091 mg/kg
75-34-3 1,1-Dichloroethane ND 0.40 0.14 mg/kg
107-06-2 1,2-Dichloroethane ND 0.40 0.079 mg/kg
75-35-4 1,1-Dichloroethylene ND 0.40 0.079 mg/kg
156-59-2 cis-1,2-Dichloroethylene ND 0.40 0.11 mg/kg
156-60-5 trans-1,2-Dichloroethylene ND 0.40 0.079 mg/kg
78-87-5 1,2-Dichloropropane ND 0.40 0.079 mg/kg
10061-01-5 cis-1,3-Dichloropropene ND 0.40 0.079 mg/kg
10061-02-6 trans-1,3-Dichloropropene ND 0.40 0.079 mg/kg
100-41-4 Ethylbenzene 2.45 0.40 0.079 mg/kg
591-78-6 2-Hexanone ND 2.0 0.59 mg/kg
98-82-8 Isopropylbenzene 2.26 0.40 0.079 mg/kg
79-20-9 Methyl Acetate ND 2.0 0.71 mg/kg
74-83-9 Methyl Bromide ND 0.40 0.16 mg/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
7 of 41
FA5754933.1
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:SB-1 4.5-5'
Lab Sample ID:FA57549-1 Date Sampled:09/12/18
Matrix:SO - Soil Date Received:09/13/18
Method:SW846 8260B Percent Solids:71.7
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
VOA Special List
CAS No.Compound Result RL MDL Units Q
74-87-3 Methyl Chloride ND 0.40 0.16 mg/kg
108-87-2 Methylcyclohexane 7.54 0.40 0.13 mg/kg
75-09-2 Methylene Chloride ND 0.79 0.32 mg/kg
108-10-1 4-Methyl-2-pentanone (MIBK)ND 2.0 0.59 mg/kg
1634-04-4 Methyl Tert Butyl Ether ND 0.40 0.079 mg/kg
91-20-3 Naphthalene 4.36 0.40 0.16 mg/kg
103-65-1 n-Propylbenzene 8.30 0.40 0.079 mg/kg
100-42-5 Styrene ND 0.40 0.079 mg/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 0.40 0.079 mg/kg
127-18-4 Tetrachloroethylene ND 0.40 0.10 mg/kg
108-88-3 Toluene ND 0.40 0.079 mg/kg
120-82-1 1,2,4-Trichlorobenzene ND 0.40 0.079 mg/kg
71-55-6 1,1,1-Trichloroethane ND 0.40 0.079 mg/kg
79-00-5 1,1,2-Trichloroethane ND 0.40 0.079 mg/kg
79-01-6 Trichloroethylene ND 0.40 0.079 mg/kg
75-69-4 Trichlorofluoromethane ND 0.40 0.16 mg/kg
95-63-6 1,2,4-Trimethylbenzene 1.31 0.40 0.079 mg/kg
108-67-8 1,3,5-Trimethylbenzene ND 0.40 0.079 mg/kg
75-01-4 Vinyl Chloride ND 0.40 0.079 mg/kg
1330-20-7 Xylene (total)ND 1.2 0.17 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 96%75-124%
17060-07-0 1,2-Dichloroethane-D4 99%72-135%
2037-26-5 Toluene-D8 101%75-126%
460-00-4 4-Bromofluorobenzene 96%71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 41
FA5754933.1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-1 4.5-5'
Lab Sample ID:FA57549-1 Date Sampled:09/12/18
Matrix:SO - Soil Date Received:09/13/18
Method:MADEP VPH REV 1.1 Percent Solids:71.7
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 UU025770.D 1 09/17/18 16:58 SH n/a n/a GUU1334
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 5.96 g 5.1 ml 20.0 ul
Run #2
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.40 0.40 mg/kg
100-41-4 Ethylbenzene 5.08 0.79 0.40 mg/kg
1634-04-4 Methyl Tert Butyl Ether 0.564 0.79 0.40 mg/kg J
91-20-3 Naphthalene 6.97 2.0 1.2 mg/kg
108-88-3 Toluene 2.48 0.79 0.40 mg/kg
m,p-Xylene ND 1.6 0.79 mg/kg
95-47-6 o-Xylene 7.38 0.79 0.40 mg/kg
C5- C8 Aliphatics (Unadj.) a 272 40 14 mg/kg
C9- C12 Aliphatics (Unadj.)127 40 14 mg/kg
C9- C10 Aromatics (Unadj.)140 40 14 mg/kg
C5- C8 Aliphatics 269 40 14 mg/kg
C9- C12 Aliphatics 114 40 14 mg/kg
C9- C10 Aromatics 140 40 14 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 211% b 70-130%
460-00-4 BFB 142% b 70-130%
(a) Associated BS/BSD recovery outside control limits high.
(b) Outside control limits due to matrix interference.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
9 of 41
FA5754933.1
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:SB-2 4.5-5'
Lab Sample ID:FA57549-2 Date Sampled:09/12/18
Matrix:SO - Soil Date Received:09/13/18
Method:SW846 8260B Percent Solids:77.2
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3C1792.D 1 09/14/18 14:14 SP n/a n/a V3C72
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 4.08 g 5.0 ml 100 ul
Run #2
VOA Special List
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 4.7 0.94 mg/kg
71-43-2 Benzene ND 0.47 0.11 mg/kg
75-27-4 Bromodichloromethane ND 0.47 0.094 mg/kg
75-25-2 Bromoform ND 0.47 0.094 mg/kg
78-93-3 2-Butanone (MEK)ND 2.4 0.68 mg/kg
104-51-8 n-Butylbenzene ND 0.47 0.094 mg/kg
75-15-0 Carbon Disulfide ND 0.47 0.094 mg/kg
56-23-5 Carbon Tetrachloride ND 0.47 0.096 mg/kg
108-90-7 Chlorobenzene ND 0.47 0.094 mg/kg
75-00-3 Chloroethane ND 0.47 0.19 mg/kg
67-66-3 Chloroform ND 0.47 0.13 mg/kg
110-82-7 Cyclohexane ND 0.47 0.12 mg/kg
124-48-1 Dibromochloromethane ND 0.47 0.094 mg/kg
96-12-8 1,2-Dibromo-3-chloropropane ND 0.47 0.18 mg/kg
106-93-4 1,2-Dibromoethane ND 0.47 0.094 mg/kg
75-71-8 Dichlorodifluoromethane ND 0.47 0.19 mg/kg
95-50-1 1,2-Dichlorobenzene ND 0.47 0.094 mg/kg
541-73-1 1,3-Dichlorobenzene ND 0.47 0.094 mg/kg
106-46-7 1,4-Dichlorobenzene ND 0.47 0.11 mg/kg
75-34-3 1,1-Dichloroethane ND 0.47 0.17 mg/kg
107-06-2 1,2-Dichloroethane ND 0.47 0.094 mg/kg
75-35-4 1,1-Dichloroethylene ND 0.47 0.094 mg/kg
156-59-2 cis-1,2-Dichloroethylene ND 0.47 0.13 mg/kg
156-60-5 trans-1,2-Dichloroethylene ND 0.47 0.094 mg/kg
78-87-5 1,2-Dichloropropane ND 0.47 0.094 mg/kg
10061-01-5 cis-1,3-Dichloropropene ND 0.47 0.094 mg/kg
10061-02-6 trans-1,3-Dichloropropene ND 0.47 0.094 mg/kg
100-41-4 Ethylbenzene ND 0.47 0.094 mg/kg
591-78-6 2-Hexanone ND 2.4 0.71 mg/kg
98-82-8 Isopropylbenzene ND 0.47 0.094 mg/kg
79-20-9 Methyl Acetate ND 2.4 0.84 mg/kg
74-83-9 Methyl Bromide ND 0.47 0.19 mg/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
10 of 41
FA5754933.2
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:SB-2 4.5-5'
Lab Sample ID:FA57549-2 Date Sampled:09/12/18
Matrix:SO - Soil Date Received:09/13/18
Method:SW846 8260B Percent Solids:77.2
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
VOA Special List
CAS No.Compound Result RL MDL Units Q
74-87-3 Methyl Chloride ND 0.47 0.19 mg/kg
108-87-2 Methylcyclohexane ND 0.47 0.16 mg/kg
75-09-2 Methylene Chloride 0.407 0.94 0.38 mg/kg J
108-10-1 4-Methyl-2-pentanone (MIBK)ND 2.4 0.71 mg/kg
1634-04-4 Methyl Tert Butyl Ether ND 0.47 0.094 mg/kg
91-20-3 Naphthalene ND 0.47 0.19 mg/kg
103-65-1 n-Propylbenzene ND 0.47 0.094 mg/kg
100-42-5 Styrene ND 0.47 0.094 mg/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 0.47 0.094 mg/kg
127-18-4 Tetrachloroethylene ND 0.47 0.12 mg/kg
108-88-3 Toluene ND 0.47 0.094 mg/kg
120-82-1 1,2,4-Trichlorobenzene ND 0.47 0.094 mg/kg
71-55-6 1,1,1-Trichloroethane ND 0.47 0.094 mg/kg
79-00-5 1,1,2-Trichloroethane ND 0.47 0.094 mg/kg
79-01-6 Trichloroethylene ND 0.47 0.094 mg/kg
75-69-4 Trichlorofluoromethane ND 0.47 0.19 mg/kg
95-63-6 1,2,4-Trimethylbenzene ND 0.47 0.094 mg/kg
108-67-8 1,3,5-Trimethylbenzene ND 0.47 0.094 mg/kg
75-01-4 Vinyl Chloride ND 0.47 0.094 mg/kg
1330-20-7 Xylene (total)ND 1.4 0.20 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 101%75-124%
17060-07-0 1,2-Dichloroethane-D4 103%72-135%
2037-26-5 Toluene-D8 96%75-126%
460-00-4 4-Bromofluorobenzene 97%71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
11 of 41
FA5754933.2
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-2 4.5-5'
Lab Sample ID:FA57549-2 Date Sampled:09/12/18
Matrix:SO - Soil Date Received:09/13/18
Method:MADEP VPH REV 1.1 Percent Solids:77.2
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 UU025771.D 1 09/17/18 17:29 SH n/a n/a GUU1334
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 5.41 g 5.1 ml 100 ul
Run #2
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.076 0.076 mg/kg
100-41-4 Ethylbenzene 0.175 0.15 0.076 mg/kg
1634-04-4 Methyl Tert Butyl Ether ND 0.15 0.076 mg/kg
91-20-3 Naphthalene 0.406 0.38 0.23 mg/kg
108-88-3 Toluene ND 0.15 0.076 mg/kg
m,p-Xylene ND 0.30 0.15 mg/kg
95-47-6 o-Xylene 0.286 0.15 0.076 mg/kg
C5- C8 Aliphatics (Unadj.) a 6.73 7.6 2.7 mg/kg J
C9- C12 Aliphatics (Unadj.)3.39 7.6 2.7 mg/kg J
C9- C10 Aromatics (Unadj.)6.27 7.6 2.7 mg/kg J
C5- C8 Aliphatics 6.73 7.6 2.7 mg/kg J
C9- C12 Aliphatics 2.92 7.6 2.7 mg/kg J
C9- C10 Aromatics 6.27 7.6 2.7 mg/kg J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 119%70-130%
460-00-4 BFB 114%70-130%
(a) Associated BS/BSD recovery outside control limits high.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
12 of 41
FA5754933.2
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-1
Lab Sample ID:FA57549-3 Date Sampled:09/12/18
Matrix:AQ - Ground Water Date Received:09/13/18
Method:SM 6200B Percent Solids:n/a
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0215293.D 2 09/17/18 16:31 AB n/a n/a VA2455
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 85.4 1.0 0.25 ug/l
108-86-1 Bromobenzene ND 1.0 0.25 ug/l
74-97-5 Bromochloromethane ND 1.0 0.25 ug/l
75-27-4 Bromodichloromethane ND 1.0 0.25 ug/l
75-25-2 Bromoform ND 1.0 0.25 ug/l
104-51-8 n-Butylbenzene 0.65 1.0 0.25 ug/l J
135-98-8 sec-Butylbenzene 0.60 1.0 0.25 ug/l J
98-06-6 tert-Butylbenzene ND 1.0 0.25 ug/l
56-23-5 Carbon Tetrachloride ND 1.0 0.25 ug/l
108-90-7 Chlorobenzene ND 1.0 0.25 ug/l
75-00-3 Chloroethane ND 1.0 0.40 ug/l
67-66-3 Chloroform ND 1.0 0.25 ug/l
95-49-8 o-Chlorotoluene ND 1.0 0.25 ug/l
106-43-4 p-Chlorotoluene ND 1.0 0.25 ug/l
124-48-1 Dibromochloromethane ND 1.0 0.25 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 1.0 0.49 ug/l
106-93-4 1,2-Dibromoethane ND 1.0 0.25 ug/l
75-71-8 Dichlorodifluoromethane a ND 1.0 0.40 ug/l
95-50-1 1,2-Dichlorobenzene ND 1.0 0.25 ug/l
541-73-1 1,3-Dichlorobenzene ND 1.0 0.25 ug/l
106-46-7 1,4-Dichlorobenzene ND 1.0 0.25 ug/l
75-34-3 1,1-Dichloroethane ND 1.0 0.25 ug/l
107-06-2 1,2-Dichloroethane ND 1.0 0.25 ug/l
75-35-4 1,1-Dichloroethylene ND 1.0 0.25 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 1.0 0.25 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 1.0 0.25 ug/l
78-87-5 1,2-Dichloropropane ND 1.0 0.25 ug/l
142-28-9 1,3-Dichloropropane ND 1.0 0.25 ug/l
594-20-7 2,2-Dichloropropane ND 1.0 0.25 ug/l
563-58-6 1,1-Dichloropropene ND 1.0 0.25 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.25 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.25 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
13 of 41
FA5754933.3
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-1
Lab Sample ID:FA57549-3 Date Sampled:09/12/18
Matrix:AQ - Ground Water Date Received:09/13/18
Method:SM 6200B Percent Solids:n/a
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 1.0 0.25 ug/l
100-41-4 Ethylbenzene 50.8 1.0 0.25 ug/l
87-68-3 Hexachlorobutadiene ND 1.0 0.25 ug/l
98-82-8 Isopropylbenzene 5.2 1.0 0.25 ug/l
99-87-6 p-Isopropyltoluene 0.26 1.0 0.25 ug/l J
74-83-9 Methyl Bromide ND 1.0 0.40 ug/l
74-87-3 Methyl Chloride 0.62 1.0 0.40 ug/l J
74-95-3 Methylene Bromide ND 1.0 0.25 ug/l
75-09-2 Methylene Chloride 2.1 4.0 2.0 ug/l J
1634-04-4 Methyl Tert Butyl Ether 1.3 1.0 0.25 ug/l
91-20-3 Naphthalene 6.0 1.0 0.25 ug/l
103-65-1 n-Propylbenzene 12.1 1.0 0.25 ug/l
100-42-5 Styrene ND 1.0 0.25 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 0.25 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.25 ug/l
127-18-4 Tetrachloroethylene ND 1.0 0.25 ug/l
108-88-3 Toluene 2.6 1.0 0.25 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 1.0 0.25 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 1.0 0.25 ug/l
71-55-6 1,1,1-Trichloroethane ND 1.0 0.25 ug/l
79-00-5 1,1,2-Trichloroethane ND 1.0 0.25 ug/l
79-01-6 Trichloroethylene ND 1.0 0.25 ug/l
75-69-4 Trichlorofluoromethane ND 1.0 0.40 ug/l
96-18-4 1,2,3-Trichloropropane ND 1.0 0.25 ug/l
95-63-6 1,2,4-Trimethylbenzene 3.7 1.0 0.25 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 1.0 0.25 ug/l
75-01-4 Vinyl Chloride ND 1.0 0.25 ug/l
m,p-Xylene 14.3 2.0 0.25 ug/l
95-47-6 o-Xylene 10 1.0 0.25 ug/l
1330-20-7 Xylene (total)24.3 3.0 0.50 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 101%70-130%
17060-07-0 1,2-Dichloroethane-D4 103%70-130%
2037-26-5 Toluene-D8 94%70-130%
460-00-4 4-Bromofluorobenzene 99%70-130%
(a) Associated ICV and CCV outside control limits high, however sample ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
14 of 41
FA5754933.3
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-2
Lab Sample ID:FA57549-4 Date Sampled:09/12/18
Matrix:AQ - Ground Water Date Received:09/13/18
Method:SM 6200B Percent Solids:n/a
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0215294.D 1 09/17/18 16:54 AB n/a n/a VA2455
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane a ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
15 of 41
FA5754933.4
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-2
Lab Sample ID:FA57549-4 Date Sampled:09/12/18
Matrix:AQ - Ground Water Date Received:09/13/18
Method:SM 6200B Percent Solids:n/a
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 102%70-130%
17060-07-0 1,2-Dichloroethane-D4 103%70-130%
2037-26-5 Toluene-D8 95%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
(a) Associated ICV and CCV outside control limits high, however sample ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
16 of 41
FA5754933.4
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-3
Lab Sample ID:FA57549-5 Date Sampled:09/12/18
Matrix:AQ - Ground Water Date Received:09/13/18
Method:SM 6200B Percent Solids:n/a
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0215295.D 1 09/17/18 17:17 AB n/a n/a VA2455
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 13.7 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene 0.72 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene 1.5 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene 0.21 0.50 0.13 ug/l J
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane a ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane 0.15 0.50 0.13 ug/l J
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
17 of 41
FA5754933.5
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-3
Lab Sample ID:FA57549-5 Date Sampled:09/12/18
Matrix:AQ - Ground Water Date Received:09/13/18
Method:SM 6200B Percent Solids:n/a
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene 0.92 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 6.1 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene 0.21 0.50 0.13 ug/l J
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride 0.36 0.50 0.20 ug/l J
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 0.52 0.50 0.13 ug/l
91-20-3 Naphthalene 4.9 0.50 0.13 ug/l
103-65-1 n-Propylbenzene 10.8 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 1.4 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene 6.1 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene 0.21 0.50 0.13 ug/l J
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 2.5 1.0 0.13 ug/l
95-47-6 o-Xylene 3.1 0.50 0.13 ug/l
1330-20-7 Xylene (total)5.6 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 101%70-130%
17060-07-0 1,2-Dichloroethane-D4 103%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
(a) Associated ICV and CCV outside control limits high, however sample ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
18 of 41
FA5754933.5
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-4
Lab Sample ID:FA57549-6 Date Sampled:09/12/18
Matrix:AQ - Ground Water Date Received:09/13/18
Method:SM 6200B Percent Solids:n/a
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0215296.D 1 09/17/18 17:40 AB n/a n/a VA2455
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane a ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
19 of 41
FA5754933.6
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-4
Lab Sample ID:FA57549-6 Date Sampled:09/12/18
Matrix:AQ - Ground Water Date Received:09/13/18
Method:SM 6200B Percent Solids:n/a
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 101%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%70-130%
2037-26-5 Toluene-D8 99%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
(a) Associated ICV and CCV outside control limits high, however sample ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
20 of 41
FA5754933.6
SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Orlando, FL
Section 4
21 of 41
FA575494
FA57549: Chain of Custody
Page 1 of 2
22 of 41
FA5754944.1
Job Number:FA57549 Client:GRI
Date / Time Received:9/13/2018 8:45:00 AM Delivery Method:FED EX
Project:WHITLEY TEXACO
Airbill #'s:1015906941810003281100812575717675
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
IR Gun
Ice (Bag)
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments
SM001Rev. Date 05/24/17
SGS Sample Receipt Summary
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (1.0);
Cooler 1: (1.1);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230315 pH 10-12 219813A Other: (Specify)
Y or N N/A
Y or N
Therm ID:IR 1; Therm CF:0.1; # of Coolers:1
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:SHAYLAP BRW Date:9/13/2018Date:9/13/2018 8:45:00 AM
FA57549: Chain of Custody
Page 2 of 2
23 of 41
FA5754944.1
SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
24 of 41
FA575495
Method Blank Summary Page 1 of 2
Job Number:FA57549
Account:GRINCC GRI (Geological Resources Inc.)
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2455-MB A0215278.D 1 09/17/18 AB n/a n/a VA2455
The QC reported here applies to the following samples:Method: SM 6200B
FA57549-3, FA57549-4, FA57549-5, FA57549-6
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
25 of 41
FA5754955.1.1
Method Blank Summary Page 2 of 2
Job Number:FA57549
Account:GRINCC GRI (Geological Resources Inc.)
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2455-MB A0215278.D 1 09/17/18 AB n/a n/a VA2455
The QC reported here applies to the following samples:Method: SM 6200B
FA57549-3, FA57549-4, FA57549-5, FA57549-6
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 100%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 99%70-130%
26 of 41
FA5754955.1.1
Method Blank Summary Page 1 of 2
Job Number:FA57549
Account:GRINCC GRI (Geological Resources Inc.)
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C72-MB 3C1789.D 1 09/14/18 SP n/a n/a V3C72
The QC reported here applies to the following samples:Method: SW846 8260B
FA57549-1, FA57549-2
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone 16.6 50 10 ug/kg J
71-43-2 Benzene ND 5.0 1.2 ug/kg
75-27-4 Bromodichloromethane ND 5.0 1.0 ug/kg
75-25-2 Bromoform ND 5.0 1.0 ug/kg
78-93-3 2-Butanone (MEK)ND 25 7.3 ug/kg
104-51-8 n-Butylbenzene ND 5.0 1.0 ug/kg
75-15-0 Carbon Disulfide ND 5.0 1.0 ug/kg
56-23-5 Carbon Tetrachloride ND 5.0 1.0 ug/kg
108-90-7 Chlorobenzene ND 5.0 1.0 ug/kg
75-00-3 Chloroethane ND 5.0 2.0 ug/kg
67-66-3 Chloroform ND 5.0 1.3 ug/kg
110-82-7 Cyclohexane ND 5.0 1.3 ug/kg
124-48-1 Dibromochloromethane ND 5.0 1.0 ug/kg
96-12-8 1,2-Dibromo-3-chloropropane ND 5.0 1.9 ug/kg
106-93-4 1,2-Dibromoethane ND 5.0 1.0 ug/kg
75-71-8 Dichlorodifluoromethane ND 5.0 2.0 ug/kg
95-50-1 1,2-Dichlorobenzene ND 5.0 1.0 ug/kg
541-73-1 1,3-Dichlorobenzene ND 5.0 1.0 ug/kg
106-46-7 1,4-Dichlorobenzene ND 5.0 1.2 ug/kg
75-34-3 1,1-Dichloroethane ND 5.0 1.8 ug/kg
107-06-2 1,2-Dichloroethane ND 5.0 1.0 ug/kg
75-35-4 1,1-Dichloroethylene ND 5.0 1.0 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 5.0 1.4 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 5.0 1.0 ug/kg
78-87-5 1,2-Dichloropropane ND 5.0 1.0 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 5.0 1.0 ug/kg
10061-02-6 trans-1,3-Dichloropropene ND 5.0 1.0 ug/kg
100-41-4 Ethylbenzene ND 5.0 1.0 ug/kg
591-78-6 2-Hexanone ND 25 7.5 ug/kg
98-82-8 Isopropylbenzene ND 5.0 1.0 ug/kg
79-20-9 Methyl Acetate ND 25 8.9 ug/kg
74-83-9 Methyl Bromide ND 5.0 2.0 ug/kg
74-87-3 Methyl Chloride ND 5.0 2.0 ug/kg
108-87-2 Methylcyclohexane ND 5.0 1.7 ug/kg
75-09-2 Methylene Chloride ND 10 4.0 ug/kg
108-10-1 4-Methyl-2-pentanone (MIBK)ND 25 7.5 ug/kg
27 of 41
FA5754955.1.2
Method Blank Summary Page 2 of 2
Job Number:FA57549
Account:GRINCC GRI (Geological Resources Inc.)
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C72-MB 3C1789.D 1 09/14/18 SP n/a n/a V3C72
The QC reported here applies to the following samples:Method: SW846 8260B
FA57549-1, FA57549-2
CAS No.Compound Result RL MDL Units Q
1634-04-4 Methyl Tert Butyl Ether ND 5.0 1.0 ug/kg
91-20-3 Naphthalene ND 5.0 2.0 ug/kg
103-65-1 n-Propylbenzene ND 5.0 1.0 ug/kg
100-42-5 Styrene ND 5.0 1.0 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 5.0 1.0 ug/kg
127-18-4 Tetrachloroethylene 1.4 5.0 1.3 ug/kg J
108-88-3 Toluene 1.5 5.0 1.0 ug/kg J
120-82-1 1,2,4-Trichlorobenzene ND 5.0 1.0 ug/kg
71-55-6 1,1,1-Trichloroethane ND 5.0 1.0 ug/kg
79-00-5 1,1,2-Trichloroethane ND 5.0 1.0 ug/kg
79-01-6 Trichloroethylene ND 5.0 1.0 ug/kg
75-69-4 Trichlorofluoromethane ND 5.0 2.0 ug/kg
95-63-6 1,2,4-Trimethylbenzene ND 5.0 1.0 ug/kg
108-67-8 1,3,5-Trimethylbenzene ND 5.0 1.0 ug/kg
75-01-4 Vinyl Chloride ND 5.0 1.0 ug/kg
1330-20-7 Xylene (total)ND 15 2.1 ug/kg
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 101%75-124%
17060-07-0 1,2-Dichloroethane-D4 101%72-135%
2037-26-5 Toluene-D8 97%75-126%
460-00-4 4-Bromofluorobenzene 98%71-133%
28 of 41
FA5754955.1.2
Blank Spike Summary Page 1 of 2
Job Number:FA57549
Account:GRINCC GRI (Geological Resources Inc.)
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2455-BS A0215276.D 1 09/17/18 AB n/a n/a VA2455
The QC reported here applies to the following samples:Method: SM 6200B
FA57549-3, FA57549-4, FA57549-5, FA57549-6
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 9.9 99 70-130
108-86-1 Bromobenzene 10 9.1 91 70-130
74-97-5 Bromochloromethane 10 8.3 83 70-130
75-27-4 Bromodichloromethane 10 9.7 97 70-130
75-25-2 Bromoform 10 9.2 92 70-130
104-51-8 n-Butylbenzene 10 9.6 96 70-130
135-98-8 sec-Butylbenzene 10 9.6 96 70-130
98-06-6 tert-Butylbenzene 10 9.4 94 70-130
56-23-5 Carbon Tetrachloride 10 10.7 107 70-130
108-90-7 Chlorobenzene 10 9.4 94 70-130
75-00-3 Chloroethane 10 9.5 95 60-140
67-66-3 Chloroform 10 9.9 99 70-130
95-49-8 o-Chlorotoluene 10 9.2 92 70-130
106-43-4 p-Chlorotoluene 10 9.2 92 70-130
124-48-1 Dibromochloromethane 10 9.3 93 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 8.6 86 70-130
106-93-4 1,2-Dibromoethane 10 9.1 91 70-130
75-71-8 Dichlorodifluoromethane 10 12.8 128 60-140
95-50-1 1,2-Dichlorobenzene 10 9.3 93 70-130
541-73-1 1,3-Dichlorobenzene 10 9.7 97 70-130
106-46-7 1,4-Dichlorobenzene 10 9.3 93 70-130
75-34-3 1,1-Dichloroethane 10 10.2 102 70-130
107-06-2 1,2-Dichloroethane 10 9.4 94 70-130
75-35-4 1,1-Dichloroethylene 10 10.2 102 70-130
156-59-2 cis-1,2-Dichloroethylene 10 10 100 70-130
156-60-5 trans-1,2-Dichloroethylene 10 10.1 101 70-130
78-87-5 1,2-Dichloropropane 10 9.7 97 70-130
142-28-9 1,3-Dichloropropane 10 9.0 90 70-130
594-20-7 2,2-Dichloropropane 10 10 100 70-130
563-58-6 1,1-Dichloropropene 10 10.1 101 70-130
10061-01-5 cis-1,3-Dichloropropene 10 8.9 89 70-130
10061-02-6 trans-1,3-Dichloropropene 10 9.1 91 70-130
108-20-3 Di-Isopropyl Ether 10 8.5 85 70-130
100-41-4 Ethylbenzene 10 9.6 96 70-130
87-68-3 Hexachlorobutadiene 10 9.7 97 70-130
98-82-8 Isopropylbenzene 10 10.3 103 70-130
* = Outside of Control Limits.
29 of 41
FA5754955.2.1
Blank Spike Summary Page 2 of 2
Job Number:FA57549
Account:GRINCC GRI (Geological Resources Inc.)
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2455-BS A0215276.D 1 09/17/18 AB n/a n/a VA2455
The QC reported here applies to the following samples:Method: SM 6200B
FA57549-3, FA57549-4, FA57549-5, FA57549-6
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 9.6 96 70-130
74-83-9 Methyl Bromide 10 9.4 94 60-140
74-87-3 Methyl Chloride 10 12.2 122 60-140
74-95-3 Methylene Bromide 10 9.5 95 70-130
75-09-2 Methylene Chloride 10 10.1 101 70-130
1634-04-4 Methyl Tert Butyl Ether 10 8.0 80 70-130
91-20-3 Naphthalene 10 9.1 91 70-130
103-65-1 n-Propylbenzene 10 9.3 93 70-130
100-42-5 Styrene 10 9.3 93 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 9.7 97 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 9.6 96 70-130
127-18-4 Tetrachloroethylene 10 10.1 101 70-130
108-88-3 Toluene 10 9.8 98 70-130
87-61-6 1,2,3-Trichlorobenzene 10 9.5 95 70-130
120-82-1 1,2,4-Trichlorobenzene 10 9.4 94 70-130
71-55-6 1,1,1-Trichloroethane 10 10 100 70-130
79-00-5 1,1,2-Trichloroethane 10 9.4 94 70-130
79-01-6 Trichloroethylene 10 9.9 99 70-130
75-69-4 Trichlorofluoromethane 10 10.1 101 60-140
96-18-4 1,2,3-Trichloropropane 10 9.0 90 70-130
95-63-6 1,2,4-Trimethylbenzene 10 9.0 90 70-130
108-67-8 1,3,5-Trimethylbenzene 10 9.3 93 70-130
75-01-4 Vinyl Chloride 10 10.6 106 60-140
m,p-Xylene 20 19.1 96 70-130
95-47-6 o-Xylene 10 9.6 96 70-130
1330-20-7 Xylene (total)30 28.7 96 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 102%70-130%
17060-07-0 1,2-Dichloroethane-D4 103%70-130%
2037-26-5 Toluene-D8 99%70-130%
460-00-4 4-Bromofluorobenzene 98%70-130%
* = Outside of Control Limits.
30 of 41
FA5754955.2.1
Blank Spike Summary Page 1 of 2
Job Number:FA57549
Account:GRINCC GRI (Geological Resources Inc.)
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C72-BS 3C1790.D 1 09/14/18 SP n/a n/a V3C72
The QC reported here applies to the following samples:Method: SW846 8260B
FA57549-1, FA57549-2
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
67-64-1 Acetone 250 249 100 61-152
71-43-2 Benzene 50 50.2 100 76-126
75-27-4 Bromodichloromethane 50 53.7 107 74-130
75-25-2 Bromoform 50 54.5 109 76-127
78-93-3 2-Butanone (MEK)250 237 95 75-137
104-51-8 n-Butylbenzene 50 50.1 100 71-128
75-15-0 Carbon Disulfide 50 47.3 95 72-122
56-23-5 Carbon Tetrachloride 50 49.2 98 78-133
108-90-7 Chlorobenzene 50 48.6 97 81-129
75-00-3 Chloroethane 50 47.5 95 68-133
67-66-3 Chloroform 50 50.2 100 72-123
110-82-7 Cyclohexane 50 47.9 96 73-126
124-48-1 Dibromochloromethane 50 53.5 107 76-127
96-12-8 1,2-Dibromo-3-chloropropane 50 44.9 90 70-137
106-93-4 1,2-Dibromoethane 50 50.8 102 77-126
75-71-8 Dichlorodifluoromethane 50 58.3 117 68-168
95-50-1 1,2-Dichlorobenzene 50 48.6 97 80-129
541-73-1 1,3-Dichlorobenzene 50 49.8 100 81-129
106-46-7 1,4-Dichlorobenzene 50 49.0 98 76-130
75-34-3 1,1-Dichloroethane 50 51.0 102 73-125
107-06-2 1,2-Dichloroethane 50 51.5 103 74-128
75-35-4 1,1-Dichloroethylene 50 48.4 97 81-136
156-59-2 cis-1,2-Dichloroethylene 50 49.5 99 74-126
156-60-5 trans-1,2-Dichloroethylene 50 49.0 98 70-127
78-87-5 1,2-Dichloropropane 50 52.8 106 74-125
10061-01-5 cis-1,3-Dichloropropene 50 51.5 103 80-123
10061-02-6 trans-1,3-Dichloropropene 50 53.7 107 75-131
100-41-4 Ethylbenzene 50 48.6 97 77-123
591-78-6 2-Hexanone 250 236 94 72-133
98-82-8 Isopropylbenzene 50 50.4 101 80-136
79-20-9 Methyl Acetate 250 235 94 67-137
74-83-9 Methyl Bromide 50 48.2 96 65-139
74-87-3 Methyl Chloride 50 51.4 103 71-144
108-87-2 Methylcyclohexane 50 50.4 101 75-128
75-09-2 Methylene Chloride 50 53.9 108 74-137
108-10-1 4-Methyl-2-pentanone (MIBK)250 247 99 76-132
* = Outside of Control Limits.
31 of 41
FA5754955.2.2
Blank Spike Summary Page 2 of 2
Job Number:FA57549
Account:GRINCC GRI (Geological Resources Inc.)
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C72-BS 3C1790.D 1 09/14/18 SP n/a n/a V3C72
The QC reported here applies to the following samples:Method: SW846 8260B
FA57549-1, FA57549-2
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
1634-04-4 Methyl Tert Butyl Ether 50 53.0 106 77-120
91-20-3 Naphthalene 50 44.3 89 79-129
103-65-1 n-Propylbenzene 50 48.2 96 80-135
100-42-5 Styrene 50 49.6 99 78-125
79-34-5 1,1,2,2-Tetrachloroethane 50 51.9 104 71-126
127-18-4 Tetrachloroethylene 50 50.4 101 79-130
108-88-3 Toluene 50 47.7 95 76-124
120-82-1 1,2,4-Trichlorobenzene 50 48.0 96 78-130
71-55-6 1,1,1-Trichloroethane 50 47.5 95 70-129
79-00-5 1,1,2-Trichloroethane 50 52.0 104 74-124
79-01-6 Trichloroethylene 50 50.5 101 75-128
75-69-4 Trichlorofluoromethane 50 49.5 99 73-145
95-63-6 1,2,4-Trimethylbenzene 50 47.0 94 74-123
108-67-8 1,3,5-Trimethylbenzene 50 48.7 97 73-122
75-01-4 Vinyl Chloride 50 51.5 103 76-141
1330-20-7 Xylene (total)150 147 98 80-129
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 102%75-124%
17060-07-0 1,2-Dichloroethane-D4 97%72-135%
2037-26-5 Toluene-D8 97%75-126%
460-00-4 4-Bromofluorobenzene 99%71-133%
* = Outside of Control Limits.
32 of 41
FA5754955.2.2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA57549
Account:GRINCC GRI (Geological Resources Inc.)
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA57547-2MS A0215290.D 100 09/17/18 AB n/a n/a VA2455
FA57547-2MSD A0215291.D 100 09/17/18 AB n/a n/a VA2455
FA57547-2 A0215281.D 100 09/17/18 AB n/a n/a VA2455
The QC reported here applies to the following samples:Method: SM 6200B
FA57549-3, FA57549-4, FA57549-5, FA57549-6
FA57547-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 600 1000 1650 105 1000 1660 106 1 70-130/20
108-86-1 Bromobenzene ND 1000 1010 101 1000 1030 103 2 70-130/20
74-97-5 Bromochloromethane ND 1000 864 86 1000 882 88 2 70-130/20
75-27-4 Bromodichloromethane ND 1000 1040 104 1000 1040 104 0 70-130/20
75-25-2 Bromoform ND 1000 949 95 1000 971 97 2 70-130/20
104-51-8 n-Butylbenzene ND 1000 1110 111 1000 1100 110 1 70-130/20
135-98-8 sec-Butylbenzene ND 1000 1060 106 1000 1080 108 2 70-130/20
98-06-6 tert-Butylbenzene ND 1000 1050 105 1000 1060 106 1 70-130/20
56-23-5 Carbon Tetrachloride ND 1000 1120 112 1000 1140 114 2 70-130/20
108-90-7 Chlorobenzene ND 1000 1030 103 1000 1030 103 0 70-130/20
75-00-3 Chloroethane ND 1000 867 87 1000 1050 105 19 60-140/20
67-66-3 Chloroform 20.1 J 1000 1070 105 1000 1080 106 1 70-130/20
95-49-8 o-Chlorotoluene 52.7 1000 1090 104 1000 1090 104 0 70-130/20
106-43-4 p-Chlorotoluene ND 1000 1020 102 1000 1040 104 2 70-130/20
124-48-1 Dibromochloromethane ND 1000 992 99 1000 1020 102 3 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 1000 988 99 1000 983 98 1 70-130/20
106-93-4 1,2-Dibromoethane ND 1000 976 98 1000 986 99 1 70-130/20
75-71-8 Dichlorodifluoromethane ND 1000 1150 115 1000 1490 149*26*60-140/20
95-50-1 1,2-Dichlorobenzene ND 1000 1020 102 1000 1030 103 1 70-130/20
541-73-1 1,3-Dichlorobenzene ND 1000 1060 106 1000 1070 107 1 70-130/20
106-46-7 1,4-Dichlorobenzene ND 1000 1030 103 1000 1030 103 0 70-130/20
75-34-3 1,1-Dichloroethane ND 1000 1070 107 1000 1100 110 3 70-130/20
107-06-2 1,2-Dichloroethane ND 1000 1010 101 1000 1010 101 0 70-130/20
75-35-4 1,1-Dichloroethylene ND 1000 1050 105 1000 1070 107 2 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 1000 1020 102 1000 1050 105 3 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 1000 1050 105 1000 1070 107 2 70-130/20
78-87-5 1,2-Dichloropropane ND 1000 1040 104 1000 1060 106 2 70-130/20
142-28-9 1,3-Dichloropropane ND 1000 959 96 1000 968 97 1 70-130/20
594-20-7 2,2-Dichloropropane ND 1000 1090 109 1000 1040 104 5 70-130/20
563-58-6 1,1-Dichloropropene ND 1000 1080 108 1000 1080 108 0 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 1000 955 96 1000 960 96 1 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 1000 1000 100 1000 994 99 1 70-130/20
108-20-3 Di-Isopropyl Ether 24.0 J 1000 937 91 1000 957 93 2 70-130/20
100-41-4 Ethylbenzene 1890 1000 2920 103 1000 2960 107 1 70-130/20
87-68-3 Hexachlorobutadiene ND 1000 1090 109 1000 1090 109 0 70-130/20
98-82-8 Isopropylbenzene 49.9 J 1000 1150 110 1000 1170 112 2 70-130/20
* = Outside of Control Limits.
33 of 41
FA5754955.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA57549
Account:GRINCC GRI (Geological Resources Inc.)
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA57547-2MS A0215290.D 100 09/17/18 AB n/a n/a VA2455
FA57547-2MSD A0215291.D 100 09/17/18 AB n/a n/a VA2455
FA57547-2 A0215281.D 100 09/17/18 AB n/a n/a VA2455
The QC reported here applies to the following samples:Method: SM 6200B
FA57549-3, FA57549-4, FA57549-5, FA57549-6
FA57547-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene ND 1000 1060 106 1000 1070 107 1 70-130/20
74-83-9 Methyl Bromide ND 1000 844 84 1000 1070 107 24*60-140/20
74-87-3 Methyl Chloride ND 1000 1120 112 1000 1330 133 17 60-140/20
74-95-3 Methylene Bromide ND 1000 1020 102 1000 998 100 2 70-130/20
75-09-2 Methylene Chloride ND 1000 1100 110 1000 1130 113 3 70-130/20
1634-04-4 Methyl Tert Butyl Ether ND 1000 875 88 1000 864 86 1 70-130/20
91-20-3 Naphthalene 793 1000 1840 105 1000 1830 104 1 70-130/20
103-65-1 n-Propylbenzene 149 1000 1200 105 1000 1200 105 0 70-130/20
100-42-5 Styrene 73.0 1000 1120 105 1000 1130 106 1 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 1000 1040 104 1000 1050 105 1 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 1000 1020 102 1000 1030 103 1 70-130/20
127-18-4 Tetrachloroethylene ND 1000 1070 107 1000 1080 108 1 70-130/20
108-88-3 Toluene 2680 1000 3630 95 1000 3660 98 1 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 1000 1030 103 1000 1040 104 1 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 1000 1040 104 1000 1020 102 2 70-130/20
71-55-6 1,1,1-Trichloroethane ND 1000 1040 104 1000 1060 106 2 70-130/20
79-00-5 1,1,2-Trichloroethane ND 1000 1040 104 1000 1040 104 0 70-130/20
79-01-6 Trichloroethylene ND 1000 1060 106 1000 1070 107 1 70-130/20
75-69-4 Trichlorofluoromethane ND 1000 939 94 1000 1150 115 20 60-140/20
96-18-4 1,2,3-Trichloropropane ND 1000 947 95 1000 960 96 1 70-130/20
95-63-6 1,2,4-Trimethylbenzene 1490 1000 2510 102 1000 2510 102 0 70-130/20
108-67-8 1,3,5-Trimethylbenzene 466 1000 1520 105 1000 1520 105 0 70-130/20
75-01-4 Vinyl Chloride ND 1000 936 94 1000 1160 116 21*60-140/20
m,p-Xylene 6410 2000 8310 95 2000 8330 96 0 70-130/20
95-47-6 o-Xylene 3250 1000 4180 93 1000 4180 93 0 70-130/20
1330-20-7 Xylene (total)9660 3000 12500 95 3000 12500 95 0 70-130/20
CAS No.Surrogate Recoveries MS MSD FA57547-2 Limits
1868-53-7 Dibromofluoromethane 100%101%99%70-130%
17060-07-0 1,2-Dichloroethane-D4 102%102%101%70-130%
2037-26-5 Toluene-D8 99%100%101%70-130%
460-00-4 4-Bromofluorobenzene 101%100%99%70-130%
* = Outside of Control Limits.
34 of 41
FA5754955.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA57549
Account:GRINCC GRI (Geological Resources Inc.)
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA57580-2MS 3C1812.D 1 09/14/18 SP n/a n/a V3C72
FA57580-2MSD 3C1813.D 1 09/14/18 SP n/a n/a V3C72
FA57580-2 3C1796.D 1 09/14/18 SP n/a n/a V3C72
The QC reported here applies to the following samples:Method: SW846 8260B
FA57549-1, FA57549-2
FA57580-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/kg Q ug/kg ug/kg %ug/kg ug/kg %RPD Rec/RPD
67-64-1 Acetone 13.0 IV 352 317 86 350 278 76 13 61-152/27
71-43-2 Benzene 4.0 U 70.4 57.9 82 70 54.9 78 5 76-126/26
75-27-4 Bromodichloromethane 4.0 U 70.4 58.4 83 70 54.8 78 6 74-130/25
75-25-2 Bromoform 4.0 U 70.4 53.7 76 70 49.2 70*9 76-127/26
78-93-3 2-Butanone (MEK)20 U 352 296 84 350 269 77 10 75-137/25
104-51-8 n-Butylbenzene 4.0 U 70.4 52.0 74 70 50.2 72 4 71-128/35
75-15-0 Carbon Disulfide 4.0 U 70.4 54.0 77 70 52.1 74 4 72-122/29
56-23-5 Carbon Tetrachloride 4.0 U 70.4 53.5 76*70 51.8 74*3 78-133/29
108-90-7 Chlorobenzene 4.0 U 70.4 53.0 75*70 50.0 71*6 81-129/29
75-00-3 Chloroethane 4.0 U 70.4 54.0 77 70 52.6 75 3 68-133/29
67-66-3 Chloroform 4.0 U 70.4 57.7 82 70 54.5 78 6 72-123/26
110-82-7 Cyclohexane 4.0 U 70.4 43.2 61*70 41.7 60*4 73-126/32
124-48-1 Dibromochloromethane 4.0 U 70.4 54.2 77 70 49.6 71*9 76-127/27
96-12-8 1,2-Dibromo-3-chloropropane 4.0 U 70.4 49.6 70 70 44.5 64*11 70-137/29
106-93-4 1,2-Dibromoethane 4.0 U 70.4 52.8 75*70 48.4 69*9 77-126/26
75-71-8 Dichlorodifluoromethane 4.0 U 70.4 48.5 69 70 45.9 66*6 68-168/29
95-50-1 1,2-Dichlorobenzene 4.0 U 70.4 50.0 71*70 46.5 66*7 80-129/32
541-73-1 1,3-Dichlorobenzene 4.0 U 70.4 51.6 73*70 49.0 70*5 81-129/33
106-46-7 1,4-Dichlorobenzene 4.0 U 70.4 50.4 72*70 47.6 68*6 76-130/32
75-34-3 1,1-Dichloroethane 4.0 U 70.4 59.9 85 70 56.9 81 5 73-125/27
107-06-2 1,2-Dichloroethane 4.0 U 70.4 57.0 81 70 53.0 76 7 74-128/23
75-35-4 1,1-Dichloroethylene 4.0 U 70.4 55.1 78*70 52.8 75*4 81-136/28
156-59-2 cis-1,2-Dichloroethylene 4.0 U 70.4 55.9 79 70 53.5 76 4 74-126/26
156-60-5 trans-1,2-Dichloroethylene 4.0 U 70.4 57.6 82 70 55.2 79 4 70-127/27
78-87-5 1,2-Dichloropropane 4.0 U 70.4 59.4 84 70 55.5 79 7 74-125/25
10061-01-5 cis-1,3-Dichloropropene 4.0 U 70.4 54.0 77*70 50.2 72*7 80-123/26
10061-02-6 trans-1,3-Dichloropropene 4.0 U 70.4 53.5 76 70 49.7 71*7 75-131/28
100-41-4 Ethylbenzene 4.0 U 70.4 55.6 79 70 52.9 76*5 77-123/31
591-78-6 2-Hexanone 20 U 352 278 79 350 252 72 10 72-133/26
98-82-8 Isopropylbenzene 4.0 U 70.4 57.1 81 70 54.6 78*4 80-136/32
79-20-9 Methyl Acetate 20 U 352 425 121 350 386 110 10 67-137/30
74-83-9 Methyl Bromide 4.0 U 70.4 51.6 73 70 50.7 72 2 65-139/31
74-87-3 Methyl Chloride 4.0 U 70.4 68.3 97 70 63.0 90 8 71-144/27
108-87-2 Methylcyclohexane 4.0 U 70.4 41.3 59*70 40.1 57*3 75-128/31
75-09-2 Methylene Chloride 8.0 U 70.4 69.2 98 70 62.3 89 10 74-137/28
108-10-1 4-Methyl-2-pentanone (MIBK)20 U 352 294 84 350 267 76 10 76-132/26
* = Outside of Control Limits.
35 of 41
FA5754955.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA57549
Account:GRINCC GRI (Geological Resources Inc.)
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA57580-2MS 3C1812.D 1 09/14/18 SP n/a n/a V3C72
FA57580-2MSD 3C1813.D 1 09/14/18 SP n/a n/a V3C72
FA57580-2 3C1796.D 1 09/14/18 SP n/a n/a V3C72
The QC reported here applies to the following samples:Method: SW846 8260B
FA57549-1, FA57549-2
FA57580-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/kg Q ug/kg ug/kg %ug/kg ug/kg %RPD Rec/RPD
1634-04-4 Methyl Tert Butyl Ether 4.0 U 70.4 56.6 80 70 52.1 74*8 77-120/24
91-20-3 Naphthalene 4.0 U 70.4 45.4 65*70 41.3 59*9 79-129/33
103-65-1 n-Propylbenzene 4.0 U 70.4 53.1 75*70 51.0 73*4 80-135/33
100-42-5 Styrene 4.0 U 70.4 53.2 76*70 50.0 71*6 78-125/30
79-34-5 1,1,2,2-Tetrachloroethane 4.0 U 70.4 54.7 78 70 49.6 71 10 71-126/30
127-18-4 Tetrachloroethylene 4.0 U 70.4 55.2 78*70 52.9 76*4 79-130/31
108-88-3 Toluene 4.0 U 70.4 53.0 75*70 50.1 72*6 76-124/30
120-82-1 1,2,4-Trichlorobenzene 4.0 U 70.4 47.3 67*70 44.5 64*6 78-130/34
71-55-6 1,1,1-Trichloroethane 4.0 U 70.4 54.9 78 70 52.6 75 4 70-129/27
79-00-5 1,1,2-Trichloroethane 4.0 U 70.4 54.7 78 70 50.5 72*8 74-124/28
79-01-6 Trichloroethylene 4.0 U 70.4 58.5 83 70 56.0 80 4 75-128/27
75-69-4 Trichlorofluoromethane 4.0 U 70.4 46.1 66*70 44.4 63*4 73-145/31
95-63-6 1,2,4-Trimethylbenzene 4.0 U 70.4 50.8 72*70 48.5 69*5 74-123/34
108-67-8 1,3,5-Trimethylbenzene 4.0 U 70.4 53.0 75 70 50.6 72*5 73-122/33
75-01-4 Vinyl Chloride 4.0 U 70.4 59.4 84 70 57.2 82 4 76-141/27
1330-20-7 Xylene (total)12 U 211 167 79*210 159 76*5 80-129/30
CAS No.Surrogate Recoveries MS MSD FA57580-2 Limits
1868-53-7 Dibromofluoromethane 99%100%102%75-124%
17060-07-0 1,2-Dichloroethane-D4 107%106%108%72-135%
2037-26-5 Toluene-D8 96%96%96%75-126%
460-00-4 4-Bromofluorobenzene 96%97%97%71-133%
* = Outside of Control Limits.
36 of 41
FA5754955.3.2
SGS North America Inc.
GC Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 6
37 of 41
FA575496
Method Blank Summary Page 1 of 1
Job Number:FA57549
Account:GRINCC GRI (Geological Resources Inc.)
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GUU1334-MB UU025768.D 1 09/17/18 SH n/a n/a GUU1334
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA57549-1, FA57549-2
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 51 51 ug/kg
100-41-4 Ethylbenzene ND 100 51 ug/kg
1634-04-4 Methyl Tert Butyl Ether ND 100 51 ug/kg
91-20-3 Naphthalene ND 260 150 ug/kg
108-88-3 Toluene ND 100 51 ug/kg
m,p-Xylene ND 200 100 ug/kg
95-47-6 o-Xylene ND 100 51 ug/kg
C5- C8 Aliphatics (Unadj.)ND 5100 1800 ug/kg
C9- C12 Aliphatics (Unadj.)ND 5100 1800 ug/kg
C9- C10 Aromatics (Unadj.)ND 5100 1800 ug/kg
C5- C8 Aliphatics ND 5100 1800 ug/kg
C9- C12 Aliphatics ND 5100 1800 ug/kg
C9- C10 Aromatics ND 5100 1800 ug/kg
CAS No.Surrogate Recoveries Limits
460-00-4 BFB 114%70-130%
460-00-4 BFB 111%70-130%
38 of 41
FA5754966.1.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FA57549
Account:GRINCC GRI (Geological Resources Inc.)
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GUU1334-BS UU025766.D 1 09/17/18 SH n/a n/a GUU1334
GUU1334-BSD UU025767.D 1 09/17/18 SH n/a n/a GUU1334
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA57549-1, FA57549-2
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/kg ug/kg %ug/kg %RPD Rec/RPD
71-43-2 Benzene 4160 4460 107 4420 106 1 70-130/25
100-41-4 Ethylbenzene 4160 4360 105 4310 104 1 70-130/25
1634-04-4 Methyl Tert Butyl Ether 4160 4550 109 4570 110 0 70-130/25
91-20-3 Naphthalene 4160 4300 103 4130 99 4 70-130/25
108-88-3 Toluene 4160 4500 108 4450 107 1 70-130/25
m,p-Xylene 8320 8660 104 8520 102 2 70-130/25
95-47-6 o-Xylene 4160 4340 104 4250 102 2 70-130/25
C5- C8 Aliphatics (Unadj.)12500 16800 135*17000 136*1 70-130/25
C9- C12 Aliphatics (Unadj.)8320 7990 96 7820 94 2 70-130/25
C9- C10 Aromatics (Unadj.)4160 4770 115 4600 111 4 70-130/25
C9- C10 Aromatics 4160 4770 115 4600 111 4 70-130/25
CAS No.Surrogate Recoveries BSP BSD Limits
460-00-4 BFB 113%109%70-130%
460-00-4 BFB 111%107%70-130%
* = Outside of Control Limits.
39 of 41
FA5754966.2.1
Matrix Spike Summary Page 1 of 1
Job Number:FA57549
Account:GRINCC GRI (Geological Resources Inc.)
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA57549-2MS UU025773.D 1 09/17/18 SH n/a n/a GUU1334
FA57549-2 UU025771.D 1 09/17/18 SH n/a n/a GUU1334
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA57549-1, FA57549-2
FA57549-2 Spike MS MS
CAS No.Compound ug/kg Q ug/kg ug/kg %Limits
71-43-2 Benzene ND 6190 6540 106 70-130
100-41-4 Ethylbenzene 175 6190 6780 107 70-130
1634-04-4 Methyl Tert Butyl Ether ND 6190 7220 117 70-130
91-20-3 Naphthalene 406 6190 7180 109 70-130
108-88-3 Toluene ND 6190 6720 109 70-130
m,p-Xylene ND 12400 13000 105 70-130
95-47-6 o-Xylene 286 6190 6810 105 70-130
C5- C8 Aliphatics (Unadj.)6730 J 37100 51000 119 70-130
C9- C12 Aliphatics (Unadj.)3390 J 30900 49900 150*70-130
C9- C10 Aromatics (Unadj.)6270 J 18600 15700 51*70-130
C9- C10 Aromatics 6270 J 18600 15700 51*70-130
CAS No.Surrogate Recoveries MS FA57549-2 Limits
460-00-4 BFB 124%119%70-130%
460-00-4 BFB 116%114%70-130%
* = Outside of Control Limits.
40 of 41
FA5754966.3.1
Duplicate Summary Page 1 of 1
Job Number:FA57549
Account:GRINCC GRI (Geological Resources Inc.)
Project:Whitley Texaco; US 258 & Carter St, Woodland, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA57549-2DUP UU025772.D 1 09/17/18 SH n/a n/a GUU1334
FA57549-2 UU025771.D 1 09/17/18 SH n/a n/a GUU1334
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA57549-1, FA57549-2
FA57549-2 DUP
CAS No.Compound ug/kg Q ug/kg Q RPD Limits
71-43-2 Benzene ND ND nc 50
100-41-4 Ethylbenzene 175 155 12 50
1634-04-4 Methyl Tert Butyl Ether ND ND nc 50
91-20-3 Naphthalene 406 285 J 35 50
108-88-3 Toluene ND ND nc 50
m,p-Xylene ND ND nc 50
95-47-6 o-Xylene 286 241 17 50
C5- C8 Aliphatics (Unadj.)6730 J 7270 J 8 50
C9- C12 Aliphatics (Unadj.)3390 J 3020 J 12 50
C9- C10 Aromatics (Unadj.)6270 J 6220 J 1 50
C5- C8 Aliphatics 6730 J 7270 J 8 50
C9- C12 Aliphatics 2920 J ND 200*50
C9- C10 Aromatics 6270 J 6220 J 1 50
CAS No.Surrogate Recoveries DUP FA57549-2 Limits
460-00-4 BFB 124%119%70-130%
460-00-4 BFB 114%114%70-130%
* = Outside of Control Limits.
41 of 41
FA5754966.4.1