RA-1468_9329_CA_MRP_20120723

-·'-
July 23, 2012
Ra-J ~ 1 Mr. Mickey Robcns B-ig~Wnshin-g1-0fl-Regional Office
943 Washington Square Mall
Washington, NC 27889
Re: Ground Water Monitoring Report
Red Apple Market #5
US Highway \58 & Depot Street
Jackson, Nonhampton County, NC
Incident No. 9329
Dear Mr. Roberts,
Please find enclosed the referenced report for the above mentioned site. If you have any questions, please do not
hesitate to contact William Regenthal PG at [phone].
Sincerely,
Geological Rc~ources, Inc.
~i~el~~
Administrative Assistant
Enclosure
cc: Mr. Wood Beasley. Red Apple Markets. Inc.
file ;
! ..: ~ '
. ·~.~-,./ . r:.\
I ' ! 1 ... 1 '--· I! \\ ..... ---,,111
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JUL 2 6 2012 !::J ,._..! I .. I
I" . I 1 \ ': \ -", ' .. '.'·'. '. \--' ' -~~rriCE j
~-=---.--~-·-
2301 Crown Point Executive Drive Suite F Charlotte, NC 2822 7
Phone' (704) 845-40101 [phone] Fax, [phone]
,
MONITORING REPORT OATES
REPORT 1 "l--;. r'l.-
MONITORING EVENT c..-z '1-rz_
RECEIPT ~7wl~7~(lf.L/;!_'I -=~=--­
DATABASE ENTRY -------
REVIEW -.-3-r-r"l.-
REVIEWER _ __:~;!12-:=_ ____ _
MONITORING REPORT INFORMATION
INCIDENTNAME f;G/) AP/'Le
/1H2K GT .#= 5
INCIDENT# . '/} z.Jj
RANK ·:r/'fi!'/C RISK L
COUNTY .-</
MANAGER /( 1'1 fL
'·.
\
.1'
GROUND WATER "-'10NITORING REPORT
RED APPLE MARKET #5
US IIIGIIWAY 158 AND DEPOT STREET
JACKSON, NORTIIAl\IPTON COUNTY
NORTII CAROLINA
INCIDEi\'T NO. 9329
Prepared for:
Red Apple Markets. Inc.
Post Office Box 1386
Ahoskie, North Carolina 27910
Prepared by:
Geological Resources, Inc.
2301-F Crown Point Executive Drive
Charlotte, North Carolina 28227
(704) 845-40 I 0
July 23, 2012
William Regenthal. P.
Project Manager
~ J '-, JUL 2 6 2012 , 2J
'i l -c-c ---;-c.fjf_l"" ,,,,. ' , ·''" ;r 1~U V•-1" ..•• ., .. _ •• '-'' • .
' -----------------------
TABLE OF CONTENTS
1.0 INTRODUCTION .......................................................................................................................... 1
2.0 F . ..\CILI'r\r ll'\FOR~L\'I'ION ........................................................................................................ l
3.0 GROUND WATER QUALITY .................................................................................................... 2
4.0 CO;...'CLUSIOi'\S AND RECOl\DIENDATIONS ....................................................................... 3
5.0 Lii\IITATIO:-.IS .............................................................................................................................. .3
Figure I:
Figure 2:
Figure 3:
Figure 4:
Table 1:
Table 2:
Appendix A:
Appendix B:
Appendix C:
Site Location Map
Site Map
Water Table Surface Map
Ground \:Vater Quality Map
FIGURES
TABLES
Well Construction and Gauging lnfonnation
Summary of Ground Water Sample Analytical Results
APPENDICES
January II, 2007-1\'otice of Residual Petroleum
Summary of Historical Ground Water Quality Data
Laboratof)' Anal)tical Report -Ground Water Samples
1.0 INTRODUCTION
The purpose of this report is to present the results of ground water sampling activities conducted on June
27, 2012, at the Red Apple Market #5 site, located at US Highway 158 and Depot Street in Jackson,
~orthampton County, North Carolina (Figure I). The purpose of the activities was to obtain current
ground water quality data for the site.
According to the available infom1ation, three 4,000-gallon gasoline and one 1 ,000-gallon gasoline
underground storage tanks (USTs) were removed from the site in September 1992 by Coastal
Environmental Services, Inc. (CES). A total of eight monitoring wells (M\V-1 through M\V-8) were
installed at the site during previous ground water assessment and corrective action activities. A Notice of
Residual Petroleum (NRP) was tiled on the deed of the subject property in January 1007. A copy of the
:t\'RP is included as Appendix A. Previous activities \vere conducted by CES. Although Geological
Resources, Inc. (GRI) cannot verify the accuracy of information obtained from preYious reports, for the
purposes of this report, it is assumed to be correct. A Site ;-.1ap showing the locations of the monitoring
wells and the structures on-site has been included as Figure 2. Please refer to previous subminals for
further historical infonnation regarding the site.
2.0 FACILITY IXFOR~IA TION
• Facility ;\'a me:
• Location:
• Ground \\'atcr Incident No.:
• Facility ID No:
• Risk Cla~sification:
• Land Usc Classification:
• Property Owner:
• UST Owner/Oper·ator:
• Consultant:
• Lahoratory:
Red Apple Market #5
US Highv,·ay 158 and Depot Street
Jackson, A1orthampton County (Figure 1)
9329
0-026626
1140R
Commercial
Red Apple Markets. Inc.
Post Office Box 1386
Ahoskie, .North Carolina 27910
Red Apple Markets, lnc.
Post Office Box 1386
Ahoskie, l\'orth Carolina 27910
Geological Resources, Inc.
230 1-F Crown Point Executive D1ive
Charlotte, North Carolina 28227
[phone]
Accutest Laboratories
4405 Vineland Road. Suite C-I 5
Orlando, Florida 3281 I
( 407) 425-6700
State Certification Number: 573
Release Information
• Date Discovered:
• Estimated Quantity of Release:
• Cause of Release:
• Source of Release:
• UST System Size/Contents:
• La t i tu d e/Lo ngitu de:
Certification
September 1 992
Unknown
Leaking UST System
UST System
Three 4,000-ga\lon and one I ,000-gallon gtlsoline USTs
36.389381 o North/77.419475" West
I, John M. Brown, a Licensed Geologist for Geological Resources, Inc., do certify that the information
contained in this report is correct and accurate to the•~'t11i"•u;J).' knowledge. ,. " \1 CAF/o '"•,,, -
, .... <>~ •"""'"fj' L!,f, .,, f ,.,~.,.."\:ENS '•,.,.f \ ..
! ! 1\i h-r tJ .-,__... • ; A ~-.
i • 113 I i ~ .• ::: $ "i'-r;o ...._ • .:~ \ ....-: · ..... {ol oG'~,,,-:-~ ./ ~.,.o,.y ............ \J~ -:-· "• .. 1\1 M a\\ ,,, .. ~ ...... . ..... ,,.
Geological Resources, Inc. is licensed to practic;"g•eoJogy and engineering in Nonh Carolina. The
certification numbers of the company are C-127 and C-2727, respectively.
3,0 GROUl\'D WATER QUALITY
Seven Type II monitoring wells (MW-1 through MW-6 and MW-8) and one Type Ill monitoring well
(MW-7) were gauged, purged, and sampled on June 27, 2012. The depths to ground water in the T)1)C II
monitoring wells during the June 2012 sampling event ranged from 7.60 to 12.41 feet below the top of
well casings. Ground water elevations in the Type II monitoring \vells relative to a temporary benchmark
with an assumed datum of 100.00 feet ranged from 88.91 to 91.62 feet. Based on these data, ground
water flow was generally tO\vard the north. The average horizontal hydraulic gradient across the site was
approximately 0.05 feet per foot. The average vertical hydraulic gradient between paired wells M\V-3
and MW-7 was approximately 0.04 feet per foot downward. A Water Table Surface Map for the June 27,
2012 sampling event has been included as Figure 3. A summary of well construction infonnation
including ground water gauging data is presented in Table 1.
Ground wutcr samples collected from the monitoring wells during the June 2012 sampling event were
submitted for laboratory analyses for volatile organic compounds (VOCs) using EPA Method 6200B and
VPH using the MADEP Method. Concentrations of benzene, MTBE and naphthalene that exceeded the
maximum allowable concentrations (MACs) specified in TISA NCAC 2L.0202 were reported in the
ground water sample collected from MW-3. None of the reported concentrations exceeded the gross
contamination levels (GCLs). A Ground Water Quality Map based on data from the June 27, 2012
2
sampling event has been included as Figure 4. A summary of ground water sample analytical results is
presented in Table 2. A summary of historical ground water quality data is included. as Appendix B. A
complete laboratory report has been included in Appendix C.
4.0 CO:"CLUSIONS AJ>D RECOMMENDATIONS
• The average depth to ground water in the monitoring wells in June 2012 was 9.68 feet. Ground
water nmv during the sampling event was generally toward the north with an average horizontal
hydraulic gradient of approximately 0.05 feet per foot. The average vertical hydraulic gradient
was approximately 0.04 feet per foot downward.
• Concentrations of benzene, MTBE and naphthalene that exceeded the MACs were reported in the
ground water sample collected from ~vf\V-3. N"one of the reponed concentrations exceeded the
GCLs.
• A Notice of Residual Petroleum for ground water was filed on the deed oft he subject property on
January 11, 2007.
• Based on this infonnation, the site risk classification should be lowered to low risk. A 0'o Further
Action (i\rF A) detennination should be issued for the incident. Public notification and monitoring
well abandonment should be completed upon receipt of the NFA letter.
5.0 Lll\IITATIO.l\"S
This report has been prepared for the exclusive use of Red Apple }.farkets, Inc. for specific application to
the referenced site in ?\1orthampton County, ;...,rorth Carolina. The assessment was conducted based on the
scope of work and level of effort desired by the NCDENR and with resources adequate only for that
scope of work .. Our findings ba\·e been developed in accordance with generally accepted standards of
environmental practices in the State of North Carolina, aYailable infom1ation. and our professional
jud&ment. No other warranty is expressed or implied.
The data that are presented m this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would be
interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional infom1ation can logically be inferred from these data. Please note that field data collected prior
to the August 2006 sampling event was not obtained under the supervision of GRL Although the
·accuracy of this information cannot be verified. for the purpose of this report GRI asswnes that it is
correct.
3
MN 9.96" W
Name: JACKSON
Date: 07/19/12
Scale: 1 inch = 2,000 ft.
Figure 1
Red Apple Market #5
Highway 158 East
Jackson, Northhampton Co., NC
Incident #9329
0 1080
SCALE 1 :24000
2000 3000
FEET
Location: 036" 23' 21.77" N 077" 25' 10.11" W
4000 5000
LEGEND I N
MW-5
Q TYPE If MONITORING WELL Q NORTHAMPTON COUNTY
s COURTHOUSE TYPE Ill MONITORING ~tELL
------PROPERTY LIN£
u.s. ROUTE# 158
-----------I I ,'.!W-5 MW-3 ~
Q I
I s MW-7
I Q I r. .... l FORMER MW-4 I I §I I I GAS OliN£ I I I 511 usrs
(\)' I I ~I llil PROPERTY OF I ~I ;:; I L"i.J 1~1 I CAROUNA TELEPHONE &
" r;-----;;::, [;;] m£GRAPH COMPANY
d C!!!O_ ~~_N~ I
ct r;-----;;::, RED APPLE I Crj I ~()_EO_ ~~ex~~ MARKET# 5 "-=-t; I
I Q I !§ MW-2 MW-1 I
Crj Q l ..... I
!? --
I --28 Q ---
MW-8
,----
JACKSON FlRE
DEPARTMENT
LAW ENFORCEMENT BUILDING
AND JAIL
PROPERTY OF TOM-I OF JACKSON
~ SliE MAP 0 10 20 40 R~d Apple Market #5 Highway 158 East
(IN FEET) Jackson, Northampton County. NC lncid~nt # 9329
Geologico/ Resources, Inc. 1 inch = 20 ft Date: 7/19/12 I Drown by A H13 I Figure: 2
LEGEND
TrP£ II MONITORING MZL
TrP£ Ill MONITORING ttFLL
--- ---PROPERTY LIN£
-90 -WATE"R TABLE SURFACE CONiDUR
(91. 62) GROUND WATER ELEVA 710/V (ft)
(NM) NOT M£ASVR£D
LAW ENFORCEMENT BUILDING
AND JAIL
MW-6 (;t
{89.09)
0
MW-5 (;t
(89.06)
I
NORlHAMPTON COUNTY
COUR TJiOUS£
N
u.s. R07 # 758
<'\l' G " "
"" Vj \..:
t &
"' I
!.._
it i:f I
70 20
{IN r7IT)
l inch = 20 ff
I Jl.------7
1 {88.91)~ I~MW-3
I SMW-~
/ I
I
MW-2 (;t (89.25)~
40
FORMER
GASOliNE
VSr's
,./" (;t MW-1
(91.62)
JACKSON FlR£
DEPARTMENT
(4MW-4
{89.05)
/ RED APPLE
~\MARKET# 5
(;t MW-8
(NM)
PROPERTY OF TOI#I OF JACKSON
/
PROPERTY OF
CAROliNA TREPHONE Jt
TElEGRAPH COMPANY
j_
WATER TABLE SURFACE MAP (6/27/12)
Red Apple Market #5
Jackson, Northampton County. NC
Date: 7/19/12 Drawn by.
Highway 758 East
Incident / 9329
AHB Figure: 3
LEGEND
lYP£ II MONITORING ltEIL
lYP£ Iff MONITORING M"LL
--PROPERTY LIN£
2.7 BENZENE
0.20 J TOLUENE
<0.15 ETH"r1..8£NZ£N£
1.B7 J X'tl..ENES
32.4-MTBE
9.4 NAPHTHALENE
CONCENTRA llONS IN pg/L
<0.73 LESS THAN THE METHOD DETECllON liMIT
SPECIFIED IN THE lABORATORY REPORT
"J'' ESllMA T£0 VALUE
-
LAW ENFORCEMENT BUILDING
AND JAIL
MW-6 ~
<0.13
<0.13
<0.15
<0.30
<0.13
<0.10
0
i
<0.13
<0.13
<0.15
"'·"' <0.13
<0.10
MW 5 ~
U.S. ROUTE# 158
I
,.,
0.20 J
<0.15
1.B7 J
32.-4
'·'
<0.13
<0.13 I MW 3(.;t
<0.15
<0.30
<0.13
<0.10
I
I
I
<0.13
<0.15
"'"' <0.13
<0.10
MW 2 ~
SMW 7
r:: .... l
I ><I I ~I
I ~I
I ~I
l ~I L~
-
FORMER
GASOLINE usrs
<0.13
<0.13
<0.15
<0.30
<0.13 .w
~MW-1
JACKSON nRE
DEPARTMt:.'""NT
NORTHAMPTON COUNTY
COURTHOUSE
~MW-4
<0.13
<O.B
0.4-5 J "'·"' <0.13
0.30 J
RED APPLE
MARKET# 5
Q AIW-8
<0.13
<0.13
<().15
<0.30
<0.13
<0.10
PROPERTY OF TOWN OF JACKSON
10 20 40
( IN rt:."ET)
l inch = 20 lt
N
PRCJPERTY OF
CAROliNA m£PHON£ &
TElEGRAPH COMPANY
9329
Hate: 07/11/12
Date Date \Vater·
Well Ill lnstnllcd Lt·wl
(mnr/dd/yy) l\leasur·cd
(mrn/d,Vyy)
M\V-1 0(J/I 0/93 06/27112
~IW-2 06/11/93 06127112
MW-3 0611 1193 06/27/12
t\.1\V-4 08110194 06/27112
M\V-5 08/11/94 06/27/12
MW-6 08/20/94 06/27/12
ivtW-7 08/19/94 06127112
MW-8 05/25106 06/27/12
Notes:
TABLE I
WELL CONSTRUCTION AND GAUGING INFORMATION
RED Al'I'LE l\IAI~KET #5 (INCIDENT NO. 9.329)
Well SlTCened Bottom Top of Depth to
Casing Interval of \Veil Cnsin~ \Vater from
Depth (;s toy n. (ll. IJGS) Elevation* Top of Casing
(I\. BGS) HGS) (li .) ( 1\.)
J 3 - I J 13 100.00 S.33
3 S-IS IS 98.99 9.73
7 7-17 17 98.77 9.86
6 G-16 16 98.41 9.36
6 6-16 16 I 01.4 7 12.41
G 6-16 16 99.53 10.44
30 30-35 35 98.89 10.94
6 6-l (, ](j NM 7.60
• *:Reference point for clcvutionmcasurcrncnts: as~umcd elevation 100.00 Jl.
Facility ID # : 0-026626
Free l'roduct Ground
Thickness** Water Comments
(ll.) I<:Ievation (ft.)
---91.62
---89.26
---88.91
---89.05
---89.06
---89.09
---87.95
---NM
• **:If fi·ee product is pn.;sent in a well, ground water elevation should be calculated by: (Tup of Casing Elevation-Depth to Water)+ (Free Product
Thickness x 0.8581 ).
II. HGS: fcct below ground surl"acc.
• NM: Not mcasurcU.
Page 1 of 1
TABLE 2
SmBIARY OF GROill<D WATER SA,,IPLE ANALYTICAL RESUl~TS
RED APPLE ;\lARKET #5 (IXCIDE;'I;'T ;'1;'0. 9329)
Date: 07/11/P
Analytical ;\[ethod
7
Contaminant of Concern
7
Well ID. Date Collected
(mm/dd/yy)
2L Standard ()..l.g/1)
GCL (~gil)
MW-1 06/27/12
:t\fW-2 06/27/12
M\V-3 06/27/12
MW-4 06/27/12
M\V-5 06127/12
MW-6 06/27112
MW-7 06/27112
MW-S 06/27/12
Notes:
=
I 600
5,000 260,000
<0.13 <0.13
<0.13 <0.13
2.7 0.20 J
<0.13 <0.13
<0.13 <0.13
<0.13 <0.13
<0.13 <0.13
<0.13 <0.13
Results reponed in )lgll (micrograms per liter).
2L Standard: as specified in Tl5A ~CAC 2L0202.
GCL: Gross contamination JeyeJ.
NE: Standard not established.
600 500
84,500 85,500
<0.15 <0.30
<0.15 <0.30
<0.15 1.87 J
0.451 <0.30
<0.15 <0.30
<0.15 <0.30
<0.15 <0.30
<0.15 <0.30
< : Less than the method detection limit specified in the laboratory repon.
Concentrations in bold face type exceeded the 2L standards.
EPA :\lethod 62008
20 6 70
20,000 6,000 70,000
<0.13 <0.10 <0.11
<0.13 <0.10 <0.11
32.4 9.4 0.33 J
<0.13 0.30 J <0.11
<0.13 <0.10 <0.11
<0.13 <0.10 <0.11
<0.13 <0.10 <0.1 1
<0.13 <0.10 <0.11
For other compounds reponed which did not exceed the 2L Standards. refer to the laboratory repons.
Page 1 of 1
-=
70 70
25,000 30,000
<0.10 <0.1 1
<0.10 <0.11
5.5 <0.11
0.66 0.98
<0.10 <0.11
<0.10 <0.11
<0.10 <0.11
0.20 J <0.11
400
25,000
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
, ,
'
~ ~~:;::
N ~. -~-= " = -,...
400
28,500
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
Facility ID #: 0-026626
;\IADEP :\lethod VPH
·--<
" u ' ~ u
400
<35
<35
146
101
<35
<35
<35
<35
·--<
N
u ' ~ u
700
XE
<35
<35
<35
68.4 J
<35
<35
<35
<35
-"
u ' ~ u
200
43.4 J
<35
79.9 J
140
<35
<35
<35
<35
•,
FILED
NORTHAMPTON COUNTY
PAULINE E. DELOATCH
REGISTER OF DEEDS
FILED
AT
BOOK
Jan11,2007
04:12:24 pm
00891
START PAGE
END PAGE
INSTRUMENT#
0775
0777
00113
BK 00891 PG:0775
""R,.e.,d~AJ<PuP;sle'-'M=aruk,;eo_t"'#"-5 _______ ,, _Northampton County, North Carolina
(Slwnamt)
The property that is the subject of this Xoticc (hereinafter referred to as the "Site") contains
residual petroleum and is an Underground Storage Tank (UST) incident under North Carolina's
Statutes and Regulations, which consist of N.C.G.S. 143~2 I 5.94 and regulations adopted thereunder.
This i\otice is part of a remedial action for the Site that has been approved by the Secretary (or
his/her delegate) of the Korth Carolina Department of Euvironment and Natural Resources (or its
successor in function), as authorized by N.C.G.S. Section 143B-279.9 and 143B-279.11. The North
Carolina Department of Environment and ~atural Resources shall hereinafter be referred to as
"DENR".
1\0TICE
Petroleum product was released and/or discharged at the Site. Petroleum constituents remain on
the site, but arc not a danger to public health and the cnvh·onment, provided that the restrictions
described herein, and any other measures required by DEN:R pursuant to N.C.G.S. Sections 143B~
279.9 and 143B~279.11, are strictly complied witb. This "Notice of Residual Petroleum" is composed of
a description of the property, the location of the residual petroleum and the land use restrictions on the
Site. "The Notice has been approved and notarized by DENR pursuant to N.C.G.S. Sections l43B~279.9
r:;:.d 143B~279.11 end hz..s/shz!! be recorded at t..!).e ______ _
(name of c"umy)
Register of Deeds' office Book __ , Page __ .
Source Property
.,;';E~as~t,ern"':'F~u'Cedls~.2ln~c~.----of Ahoskie. North Carolina is the owner in fee
(Owner'.!" name) (ci/)'.!: srare of/,.,me""mer)
simple of all or a portion of'lle Site, which is located in the County of _Nonhampton , State of North
Carolina, and is known a..<d legally described as:
TRACT2:
That lot of land in the Town of Jackson, Jackson Township, Nonhampton County, North Carolina,
described as follows:
Bounded on the Norch Je;Jerson Street, on the South by other lands oftlte said Lucy A. Gay, 011 the East b_v
the Carolina Telephone and Telegraph Company and on rhe West by Depot Stre.zt
'2. I='.~ ).0 'oo '>!. e,ea_-s\"1 t:"'\<.'<pvi\>~S I"c..
1'0 \:>v-o_\1-I~Y i3'blo
F\ hDS\o;e. 1,.\C ~l9jO
Received
wo.ro DWI"il
DEC 1 5 2005
Revised October 19,2006
BK:00891 PG:0776
BEGIJlNING at a stake on the South side of Jefferson Street at the Northwest corner of the Carolina
Telephone and Telegraph Company property; thence running along the South line of Jefferson Street in a
Westerly direction, South 84 degrees 0 mfnutes West 13 7. 7 feet, more or less, to the Southeast corner of
Jefferson Street and Depot Street: thence along the East right of way line of Depot Street, South 0 degrees
42 minutes East 97 feet, more or less, to a point, corner with Jackson Volunteer Fire Department; thence
along the Jackson Volunteer Fire Department, North line, North 85 degrees 18 minutes East 146.70 feet,
more or less, to an iron stake, corner with Carolina Telephone and Telegraph Company,' thence with
Carolina Telephone and Telegraph Company line, North 6 degreeS West 100 feet to the point and place of
beginning. See Deed Book 341, Page 179, and Deed Book 336, Page 236, Office of the Register of Deeds,
Norzhmnpton County, North Carolina. Said description is derived from a sun•ey by J. W Traylor, dated
December 6, 1965, and being the same property as contained in the two deeds recited above.
Exceptt!d fi'on: tile abov(j rrat:r or purcei uf !and i:: the fOllowing de,,cribed lands:
That certain lot or parcel of land in the Town of Jackson, Jackson Township, Northampton County, North
Carolina, containing 283.5 square feel, bounded on the West by Depot Streets and on the South by lands
now belonging to Jackson Vol. Fire Dept. and being shown and designated as Lot No. II Jackson Vol.
Fire Dept. on that map entitled "Survey and Map Showing Property of Jackson Vol. Fire Dept. Located in
Town of Jackson, N. C., Northampton County, North Carolina," dated August 1976, made by Jasper Eley,
R. L. S., recorded in the office of the Register of Deeds of Northampton County, North Carolina, in Map
Book 14, at Page 90, which map is by reference incorporated herein and made a part hereof. and being
particularly described according to said map as follows:
BEGINl\rJNG at an iron stake, No1·theast corner oft he Fire House lot and Northwest corner of the Town
of Jackson Water Tank lot, in the line of Northeastern Oil Co.; thence along a new made line North 86
degrees West 126 feet to Depot Street, at an iron spike and bottle cap; thence along Depot Street South 6
degrees 46 minutes West 4 feet 6.5 inches to the line of Jackson Vol. Fire Dept. Lot No. 1, at an iron spike
and bottle cap; thence along the line of Lor No. 1 South 88 degrees 5 minutes East 126 feet and 7 inches
to the oint o be innin
For protection of public health and the environment, the following land use restrictions required by
N.C.G.S. Section 143B-279.9(b) shall apply to all of the above-described real property. These restrictions
shall continue in effect as long as residual petroleum remains on the site in excess of unrestricted use
standards and ca..'U1ot be amended or cancelled unless and until the Northampton County Register of Deed
receives and records the written concurrence of the Secretary (or his/her delegate) ofDENR (or its
successor in fhnetion).
PERPETUAL LAND USE RESTRICTIONS
Groundwater: Groundwater from the site is prohibitedji-om usc as a water supply. H'ater supply wells
of any kind shall not be installed or operaied on rhe site.
ENFORCEMENT
The above land use restriction(s) shall be enforced by any owner, operator, or other party
responsible for the Site. The above land use restriction(s) may also be enforced by DE:I\"R through any of
the remedies provided by law or by mca..TJ.s of a civil action, and may also be enforced by any unit of local
government having jurisdiction over any part of the Site. Any attempt to cancel this ~otice without the
approval of DENR (or its successor in function) shall be subject to enforcement by DENR to the full extent
of the law. Failure by any party required or authorized to enforce any of the above restriction(s) shall in no
event be deemed a waiver of the right to do so thereafter as to the same violation or as to one occurring
prior or subsequent thereto.
4
Hecefved
\'r':.ro D'r'.'M
DEC j 5 2006 R~viscd October 19,2006
BK: 00891 PG: 0777
IN" WITNESS WHEREOF, C. Wood Beasley, ill has caused this Notice to be executed
pursuant to N.C.G.S. Sections 1438:-279.9 and 1438-279.11: this~ day of De G · ,200~
(no of responsiblt parry if agent is sig in g)
By: .:.:...Ll
toroty or other agent/f!here is one)
(Title of agtntfor rc~ponsible perry lftl1ere U one)
Signatory's name typed or printed: _ _.:C'"--. W!O'iO&O!lld"B"'ea""'s"le!Xv--mill. ____ _
NOF,Tf! CAl~OLIN,.i
-!::h;_ 'f-((J,._,'.._-._Y __ .COUNTY
Approved for the purposes ofN.C.G.S. 1438-279.11
c;u~~cu:v~
(s1gn,~ of Regional S~isor} . o=cc&S'':'b~,':'',I-E:k"::,_JJ,i';':'~:::Cv':'"C!~~--·' Regional Supervisor (printed name of Regional S~pervisor)
:-c"(?_~"'-'( e,.,.4,_-,_£_Regional OWce
UST Secti6n
Division of \V<:ste .Mr;.nageruent
Deparlrnent of Environment and Natural Resources
My commission expires:
''if' I()'/
I certifY that th~ following pers~:n(s) personally ap~eared bB;re p1e this day, each ac!mowledging to me
that he or she s1gne~ the foregomg document:foted: /(. ,~V}t?Sifu/1 prir.ted name of Regional Supen·iw)
5
Received
Waro DWM
DEC 1 5 2006
Revised Qcwbcr 19,2006
TABLE2
ABRIDGED SUMMARY OF LABORATORY ANALYSES'
RED APPLE MARKET #5
TABLE 2 (cont'd.)
ABRIDGED SUMMARY OF LABORATORY ANALYSES
GROUND WATER SAMPLES
RED APPLE MARKET #5
I. Samples collected on May 25, 2004 were analyzed for VOCs u:sing EPA Method 602, SVOCs using EPA Method 625, EDB using Method 504.1 nnd EPHIVPH using the MADEP
Methods; Samples collected on the remaining sample events were analyzed for VOCs using EPA Method 601/602, EDB using Method 504.1, lead using Method 60108 illld EPHNPH
using the MADEP Methods; only the most common hyd=rbon constituents or those present at detectable concentration have been summarized.
2. Approximately 3.30 fed of free product present.
3. Less than the report limit specified in the laboratory report.
4. Analyses not requested.
5. Concentrations in bold face type exceed the MACs.
6. Maximum a11owable concentration specified in TIS A NCAC 2L.0202.
7. Crross contamination level.
8. No standard specified.
Technical Report for
GR! (Geological Resources Inc.)
Ram #5; 101 V>./ Jefferson St (Hwy 158), jackson, NC
Accutest job Number: F94517
Sampling Dale: 06/27/12
Report to:
GRI
2301 F Crown Point EX Dr
Charlotte, NC 28207
e-Hardcopy 2. 0
w!r@ geologicalresourcesinc. com: carriekennedy@ge logicalresourcesinc. com: Iii r@ g eo I o gi calresourcesi nc. corn
jf\TTN: William Regenthall
Total number of pages in report: 44
Test results 'omained within this data package met"t the requirements
of rhe National Environmental Laboratory Accreditation ConfNence
and/or state specific certification programs as applicablr.
~·
Harry Behzadi, Ph.D.
Laboratory Director
Client Service contact: Muna Mohammed 407-425-6700
Certifications: FL (E83510). LA (03051). KS (E-1032n. lA (3G6). IL (200063). NC (5i3). :\J (FLOOl). SC (96038001)
DoD ELAP IL·A·B L2229), CA (0422GCA). TX (TI04704404). AK, AR GA, KY, MA, N\', OK, UT, VA. WA, \.\·1
This repon shall not Ut reproduced. except in itl emirety, ;vltlmut the written appro\'a) of Accutest Laboratories.
Test results relate only to samples analyzed.
Sottthca.,t • 14()5 Vinc!and Road • Suitt· C-15 • Orlando. FL 32811 • tel: 407·425-6700 • fax: [phone] •
Acrutest Labornwrie~ i~ th~ sole authority for authorizing edit> or modifi;:ations to thi~
documem. Lin~uthorized modificati011oftbis repon is strictly prohibited.
111tp:l/w;I'W .accutest. ~om
1111 1 of 44 II ACCUTEST.
F~517
Sections:
Table of Contents
-!-
Section I: Sarnplc Sumrnary ................................................................................................... 3
Section 2: Sumrnary of Hits .................................................................................................... 4
Section 3: Santplc Results ........................................................................................................ 6
3.1: F94517-1: l\1\V-1 .............. ..................................................... .. ............. 7
3.2: F94517-2: M\V-2 ............. .. ............................................................................. ..
3.:1: F94517-3: MW-3 ....................... .. .......................................................................... .
3.4: F94517 -4: l\1\V -4 ........................................................................ .
3.5: F94517-5:
.1.6: F94517-6:
3.7: F94517-7:
3.8: F94517-8:
M\V-5 ....................................................................................................... .
MIV-6 .............. .
MW-7 ...................................................................... .
l\1\V -8 ................................................................................................... .
Section 4: l\1isc. Forms ........................................................................................................... .
4.1: Chain of Custody ......................................................................................................... .
Section 5: GC/:\tS Volatiles-QC Data Summaries ............................................................ ..
5.1: Method Blank Summary ......................................................................................... ..
10
13
16
19
22
25
28
31
32
34
35
5.2: Blank Spike Summary .................................................................................................. 37
5.3: Matrix Spike/Matrix Spike Duplicate Summary.................................................. 39
Section 6: GC Volatiles-QC Data Summaries ...................................................................... n
6.1: Method Blank Summary ................................................................................................ 42
6.2: Blank Spike/Blank Spike Duplicate Summary .............................................................. 43
6.3: Matrix Spike/Matrix Spike Duplicate Summary .......................................................... 44
I
~
IJ[J 2 of 44
llJACCUTEST.
F!l4517
Accutest Laboratories
Sample Summary
GRI (Geological Resources Inc.)
Ram #5; 101 W jefferson St (Hv.y 158), jackson, NC
Sample Collected Matrix
Number Date Time By Received Code Type
F94517c1 Q{i/27/12 14.41 Jl! 06/28/12 AQ Ground Wa1er
F94517-2 06127112 15:20 JH 06128112 AQ Ground Water
F9451(3 OG/27 /12 1 UH Jll 06/28/12 AQ Ground Water
F94517-4 06/27/12 13:24 JH 06/28/12 AQ Ground Water
F!J4517-5 06/27/12 14:15JH 06/28/12 AQ Ground Wa1er
F94517-6 06/27/12 14:26 JH 06/28/12 AQ Ground Wa1er
F94517-7 OG/27/12 13:47 JH 06/28/12 AQ Ground Wa1er
F94517-8 OG/27/12 14:58jH 06/28/12 AQ Ground Wa1cr
Job No:
Client
Sample ID
MW-1
MW-2
M\,\I-3
MW-4
MW-5
MW-6
M\V-7
\1\V-8
F94517
1!10 3 of 44 ID ACCUTEST.
Fi<4517
Summary of Hits
Job Number: F94517
Account: GRI (Geological Resources Inc.)
Project: Ram #5, 101 \V Jefferson St {Jiwy 158), Jm:kson,
Collected: OG/27/12
Lab Sample ID Client Sample ID Result/
Analyte Qual RL
F94517-l MW-1
sec-Butylhemene 0.36 J 0.50
Chloroethane 0.24 J 0.50
C9-CIO Aromatics (Unadj.) 43.4 J 100
F94517-2 MW-2
<no hits reported in this sample>
F94517-3 MW-3
Benzene 2.7 0.50
n-Butylbenzene O.!Jl 0 50
sec-Butylbenzene 1.3. 0.50
teti-Butylbenzene 0.46] 0.50
Di-lsopropyl ether 0.33 J 0.50
IsopropylhenLene 5.5 0.50
Methyl Tert BU!yl Ether 32.4 0.50
Naphthalene 9.4 0.50
Toluene 0 20 J 0.50
m,p-Xylene 0.27 J 1.0
a-Xylene 1.6 0.50
CS-C8 Aliphatir.s (Unadj.) 146 100
C9-C10 Aromatics (Unadj.l 79.9 J 100
F94517-4 MW-4
sec-Butylbenzene 1.3 0.50
tert-Butylllrmzene 0.45) 0.50
Ethylbenzene 0 45 J 0.50
lsopropylbenzene 0.66 0.50
p-l.~opropyltoluene 0.28 J 0.50
:\'aphthalene 0.30 J 0.50
n-Propylbenzene 0.98 0.50
C5-C8 AllphaHcs (Unadj.) 101 100
C9-C12 Aliphatks (Unadj.) 68.4 J 100
C9-C10 Aromatics (Unadj.) 140 100
F94517-5 MW-5
<no hits reported in this .<.ample:>
:\C
MDL Units
0.10 ug/1
0.17 ug/1
35 ug/1
0.13 ug/1
0.10 ugll
0.10 ug/1
0.10 ug/1
0.11 ug/1
0.10 ug/1
0.13 ug/1
0.10 ug/1
0.13 ug/1
0.20 ug/1
0.10 ug/1
35 ugfl
35 ugll
0.10 ug/1
0.10 ug/1
0.15 ug/1
0.10 ug/1
0.10 ug/1
0.10 ug/1
0.11 ug/1
35 ug/1
35 ug/1
35 ugll
Page I of2 I
Method
5~1 62008
SM 62008
l\1ADEP VI'!! REV 1.1
SM 62008
Sl\I 62008
SM 62008
SM 62008
SM 62008
St.·! 62008
SM 62008
SM 02008
SM G200B
SM 62008
St-.-! 62008
:-.1ADEP VPH REV 1.1
MADEP VPH REV 1.1
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
S!'vl 62008
$1\1 62008
J\1/\ DEP VI'll REV 1.1
MADEP VPH REV 1.1
MADEP VPH REV 1.1
l!iiC 4of44 1!1 ACCUTEST.
Fll-4517
Summary of Hits
Job Number: F94517
Account: GRI (Geological Resources Inc.)
Project: Ram #5: 101 \V Jefferson St (Hwy !58), Jackson, :\'C
Collected: 06/27/12
Lab Sample ID Client Sample lD Resu!U
Analyte Qual RL MDL
F94517-6 MW-6
<no hits reported in this sample>
F94517-7 MW-7
<no hits reponed in this sample>
F94517-8 MW-8
~ec-Butylbr.!UC'IlC 0.17 J 0.50 0.10
bopropylbenzene 0.20 J 0.50 0.10
Units Method
ug/1 S~1 fl200B
ug/1 Sl\1 6200B
Page 2 of2 I
liD 5 of 44 Iii ACCUTEST.
F94517
II !d. Ill ACX:::UT~ST.
LA E3 Q,R' .\ T 0 A I E S
Sample Results
Report of Analysis
Section 3
IIC 6 of 44
lJ ACCUTEST.
Accutest Laboratories
Report of Analysis Page I of 2
Client Sample ID:
Lab Sample ID:
Matrix:
Method:
MW·l
F94517-l
AQ -Ground \\1ater
SM 62008
Date Sampled: 06/27 J12
Date Received: 06/28/12
Percent Solids: n/a
Project: Ram #5: 101 \V jefferson St (Hwy 158}, jackson, NC
File ID
E017610.D
DF Analyzed By
Run #I
Run #2
07/06/12 TO
IR"" 'I Run #2
Purge Volume
1 o .n ml
VOA 620GB List
CAS No. Compound
71-43-2 Benzene
108-86-1 Bromo benzene
74-97-5 Bromochloromethane
75-27-4 Bromodichloromethane
75-25-2 Bromofonn
I 04-51-8 n-Butylbenzene
135-98-8 scc-Butylbenzenc
98-06·6 tert-Butylbenzene
108-90-7 Chlorobenzene
75-00-3 Chloroethane
67-66·3 Chlorofonn
95-49-8 o-Chlorotoluene
106-43-4 p-Chlorotoluene
56-23-5 Carbon tetrachloride
75-34-3 1.1-Dichloroethane
75-35-4 1.1-Dichloroethylene
563-58-G 1,1-Dichloropropene
96-12-8 I, 2-Dibromo<!-chloropropane
106-93-4 1,2-0ihromoethane
107-06-2 1,2-Dichloroethane
78-!!7-~ I, Z-Dichloropropane
142-28-D 1,3-0ichlornpropaoe
108-20-:l Di-hopropyl ether
5D4-20-7 2 ,2-Dichloropropane
124-48-1 Dibromochlornmethane
75-71-8 Dichlorodifluoromcthane
ISG-59-2 cis-! ,2-Dichloroethylene
10061-01-5 cis-! , 3-0ichloropropcne
541-73-1 m-Oichlorobenzene
95-50·1 a-Dichlorobenzene
106-46-7 p-Oichlorobenzene
156-60-5 trans-! ,2-Dichlorocthylene
Result
i\'0
:-m
:\'0
:\'0
1\D
:\'0
0.36
1\'0
NO
0.24
l\'0
NO
:'>.'0
:-iD
l\'0
l\'D
NO
NO
l\'D
!\'0
!\'D
ND
ND
ND
ND
ND
ND
ND
l\'D
l\'0
!\'D
ND
!\'D = Not detrcted MDL-Method Detection Limit
RL = Reporting Limit
E = Indicate.~ value exc('eds calibration range
RL
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
Prep Date
nJ,
Prep Batch
n/a
MDL Units Q
0.13 ug/1
0.12 ug/1
0.13 ug/1
0.12 ug/1
0.12 ug/1
0.10 ug/1
0.10 ug/1 J
0.10 ug/1
0.14 ug/1
0.17 ug/1 J
0.16 ug/1
0.11 ug/1
0.10 ug/1
0.18 ug/1
0.12 ug/1
0 18 ug/1
0.14 ug/1
0.14 ug/1
0 10 ug/1
0.1(l ug/1
0.13 ug/1
0.12 ug/1
0.11 ug/1
0.17 ug/1
0.10 ug/1
0 .IS ug/1
0.12 ug/1
0.10 ug/1
0.12 ug/1
0.10 ug/1
0.1 z ug/1
0.18 ug/1
j = Indicates an estimated value
Analytical Batch
VE625
B = Indicates anal)1e found in associated method blank
N = Indicates presumptive evidence of a compound
IIIJ 7 of 44
Bl ACCUTEST.
F!l4517 ...... , ......
Accute.o.t Laboratories
Report of Analysis PageZufZ ~ ~
Client Sample ID: M\\'-1 ~ Lab Sample ID: F94517-l Date Sampled: 06/27/12
Matrix: AQ -Ground Water Date Received: 06/28/12
Method: SJ\1 62008 Percent Solids: "j,
Project: Ham itS: 101 W jefferson St (H\\)' 158), Jackson, \'C
VOA 62008 List
CAS No. Compound Result RL MDL Units Q
10061-02-6 trans-! ,3-Dichloropropcne NO 0.50 O.IO ug/1
I 00-41-4 Ethylbcnzene NO '0.50 0.15 ug/1
87-68-3 Hexachlo robutadiene NO 0.50 O.I3 ug/1
98-82-8 Isopropylbcnzene ND 0.50 0.10 ug/1
99-87-6 p-Isopro pyltoluene ND 0.50 0.10 ug/1
74-83-9 Methyl bromide NO 0.50 0 12 ugll
74-87-:-1 ;>.1cthyl chloride ND 0.50 0.20 ug/1
74-95-3 \1ethylene bromide ND 0.50 0.10 ug/1
75-09-2 \1ethylene chloride ND 2.0 1.0 "gn
1634-04-4 ~-!ethyl Tert Butyl Ether !\0 0.50 0.13 ug/1
91-20-3 ;>.,'aphthalene NO 0.50 0 10 ug/1
103-65-1 n-Propylbenzene ND 0.50 011 ug/1
100-42-5 Styrene ND 0.50 0.10 ug/1
630-20-6 1, I, I ,2-Tetrachloroethane :'\D 0.50 0.12 ug/1
71-55-6 I , 1,1-Trichloroethane ND 0.50 0.19 ug/1
79-34-5 1,1 ,2,2-Tetrachlorm~thane ND 0.50 0.12 ug/1
79-00-5 I , I ,2-Trichloroethane ND . 0.50 0.11 ug/1
87-61-6 1 ,2,3-Trichlorobenzene ND 0.50 0.10 "gn
96-18-4 I. 2.3-Trichloropropane NO 0.50 0.18 ugll
120-82-1 I, 2,4-Trichlorobenzene ~D 0.50 0.1I ug/1
95-63-6 I, 2, 4-Trimcthylbenzenc NO 0.50 0 10 ug/1
108-67-8 I, 3, 5-Trimethylbenzene ND 0.50 0.10 ug/1
127-18-4 Tetrachloroethylene ND 0.50 0.14 ug/1
108-88-3 Toluene t\'0 0.50 0.13 ug/1
79-01-6 Trichloroethylene ND 0.50 0 18 ug/1
75-69-4 TrichloroOuoromethane ND 0.50 0 16 ug/1
75-01-4 Vinyl chloride ND 0.50 0.16 "gn
m,p-Xylene ND 1.0 0.20 ug/1
95-47-6 a-Xylene !\'0 0.50 0.10 ug/1
CAS No. Surrogate Recoveries Run# I Run# 2 Limits
1868-53-7 Dibromonuoromethane 102% 70-130%
17060-07-0 l ,2-Dichlomethane-04 103% 70-130%
2037-26-5 Toluene-DB 94% 70-130%
460-00-4 4-Bromonuorobenzene 109% 70-130%
!\D = Not detected MDL-Method Detection Limit j = Indicates an estimated value
RL = Reporting Limit
E = Indicate~ value exceeds calibration range
B = Indicates analyte found in associated method blank
N = Indicates presumptive evidence of a compound
lllJ a of 44
Ul ACCUTEST.
F94517
Accutest Laboratories
Report of Analysis Page I of I
Client Sample ID:
Lab Sample ID:
Matrix:
Method:
M\V-1
F94517-I
AQ -Ground Water
MADEP VPH REV 1.1
Date Sampled: 06/27/12
Date Received: 06/28/12
Percent Solids: n/a
Project: Ram #5: 101 \V jefferson St (Hwy 158), jackson, NC
J~un #I
Run #2
IR"" #I
Run #2
File ID
UV054283.D
Purge Volume
5.0 ml
DF
MADEP VPH List
CAS No. Compound
C5-C8 Aliphatics (Unadj.)
C9-C12 Aliphatics (Unadj.)
Analyzed By
07110112 i>1M
Result RL
!\'D 100
i\'D 100
CD-CJO Aromatics (Unadj.) 43.4 100
Prep Date
u/e
MDL Units
35 ug/1
35 ug/1
35 ug/!
Prep Batch
n/a
Q
J
Analytical Batch
GUV3011
CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4
460-00-4
BFB
BFB
ND = Not detected
RL = Reporting Limit
83%
RG%
MDL-Method Detection Limit
E = Indicates value exceeds calibration range
70-130%
70-130%
j = Indicates an estimated value
B = Indicates anal)1e found in associated method blank
!\ = Indicates presumptive evidence of a compound
110 9 of 44
I] ACCUTEST.
F94517
Acrutest Laboratories
Report of Analysis Page I of2
Client Sample ID:
Lab Sample ID:
Matrix:
Method:
lvf\V-2
F94517-2
AQ-Ground \".'ater
SM 62008
Date Sampled: 06/27/12
Date Received: 06128112
Percent Solids: n/a
Project: Ram #5: 101 W jefferson St (Hwy 158), jackson, NC
Run #1
Run #2
!Run #I
Run #2
File ID
E017GJJ.D
Purge Volume
10.0 ml
DF
I
VOA 62008 List
CAS No. Compound
71-43-2 Beruene
108-86-1 Bromobenzene
74-97-5 Bromochloromethane
75-27-4 Bromodichloroml.'thane
75-25-2 Bromoform
104-51-8 n-Butylbenzene
135-98-8 scc-Butylbcnzene
98-06-6 tert-Butylbenzene
108-90-7 Chlorobenzene
75-00-3 Chlomethane
G7-66-3 Chloroform
95-49-8 o-Chlorotoluene
IOG-43-4 p-Chlorotoluene
56-23-5 Carbon tetrachloride
75-34-3 1, 1-Dichloroetham)
75-35-4 I , 1-Dichloroethyl(me
563-58-6 I, 1-Dichloropropcne
Analyzed By
07/0fi/12 TO
Result RL
ND
ND
ND
Nil
ND
ND
1\:D
1\:D
1\:D
ND
1\:D
l\D
l\D
ND
ND
1\D
l\'D
96-12-8 I ,2-Dibromo-3-chloropropane i\'D
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0 50
. 0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0 50
0.50
0.50
0.50
0.50
0.50
0.50
106-93-4 I ,2-Dibromocthane ND
107-06-2 1 .2-Dichloroethane !\'])
71::-87-5 1 ,2-Dichloropropane ND
142-28-9 I ,3-Dichloropropane t-iD
108-20-3 Di-lsopropyl ether ND
594-20-7 2, 2-Dichloropropane t-iD
124-48-1 Ditnomochloromcthanc ND
75-71-8 D ichl orodifluorom ethane ND
156-59-2 cis-1. Z-Dichloroethylene 1\:D
10061-01-5 cis-1.3-Dichloropropene 1\:D
541-73-1 m-Dichlorobenzcne 1\:D
95-50-l a-Dichlorobenzene ND
106-46-7 p-Dichlorobenrcne Nil
15G-60-5 trans-1 ,Z-Dirhlorocthylene ND
l\D = Not detected MDL-Method Detection Limit
RL = Reporting Limit
E = Indicates \'alue exceeris calibration range
Prep Date
'"'
MDL Units
0.13 ug/1
0.12 ug/1
0.13 ug/1
0 12 ug/1
0 12 ug/1
0.10 ug/1
0.10 ug/1
0.10 ug/1
0 14 ug/1
0.17 ug/1
0.16 ug/1
0.11 ug/1
0.10 ug/1
0.18 ug/1
0 12 ug/1
0.18 ug/1
0.14 ug/1
0.14 ug/1
0.10 ugll
0.16 ugll
0.13 ug/1
0.12 ug/1
0.11 ugll
0.17 ug/1
0.10 ug/1
0 IS ug/1
0 12 ug/1
0.10 ugll
0.12 ugll
0.10 ug/1
0.12 ug/1
0.18 ug/1
Prep Batch
n/,
Q
j = Indicates an estimated value
Analytical Batch
VEG25
8 = Indicates analyte found in associated method blank
N = Indicates presumptive e\'idcnce of a compound
IIIIJ 1 0 of 44 Ill ACCUTEST.
F94517
Acrutcst Laboratories
Report of Analysis Page 2 of 2 w
"' Client Sample ID: MW-2 ~ Lab Sample ID: F94517-2 Date Sampled: 06/27/12
Matrix: AQ -Ground \\later Date Received: 06128/12
Method: $1\I 62008 Percent Solids: nJ,
Project: Ram #5; 101 W jefferson St (Hwy !58), jackson, NC
VOA 6200B List
CAS No. Compound Result
10061-02-6 trans-! ,3-Dichloropropcne :'\0
100-41-4 Ethylbenzene 1<0
87-68-3 H exachlorobutadiene NO
9R-H2-8 lsopropylhenzene KD
99-87-6 p-lso propy Ito luene 1\'D
74-83·9 Methyl bromide NO
74-87-3 Methyl chloride i\'0
74-95-3 ~·!ethylene bromide NO
75-09-2 ~1ethylene chloride NO
1634-04-4 Methyl Tert Butyl Ether NO
HI-W-3 Naphthalene ND•
103-65-l n-Propylbenzene NO
100-42-5 Styrene NO
630-20-6 1, 1, I, 2-Tetrachloroethane :\'D
71-55-6 1 ,1, 1-Trichloroetha.Jle l'<D
79-34-5 I ,1.2,2-Tetrachloroethane ND
79-00-5 1, 1 . 2· Trichloroethane ND
87-61-G 1, 2.3-Trichlorobenzene ND
96-18-4 I. 2.3-Trichloropropane .\'0
120-82-1 I. 2,4-Trichlorobenzene XD
95-63-G 1, 2,4-Trimethylbenzene NO
108-67-8 I, 3. 5-Trimethylbenzene ND
127-18-4 Tetrachloroethylene NO
Hl8-88-3 Toluene ND
79-01-6 Trichloroethylene NO
75·69-4 Trichlorofluoromethane :\D
75-01-4 Vinyl chloride !\"'0
m.p-Xy!ene I\"0
95-47-G a-Xylene ND
CAS No. Surrogate Recoveries Run# 1
ISGS-53-7 Dihromofluoromethane 99%
17060-07-0 1, 2-Dichloroethane-04 96%
2037-26-5 Toluene-DB 96%
4G0-00-4 4-Bromofluorobenzene 100%
Nn = Not dctPcted MDL -Method Detection Limit
RL = Reporting Limit
E = Indicates value exceeds calibration range
RL MDL Units Q
0.50 0.10 ug/1
0.50 0.15 ug/1
0.50 0.13 ug/1
0.50 0.10 ug/1
0.50 0.10 ug/1
0.50 0.12 . ug/1
0.50 0.20 ugll
0.50 0.10 ug/1
2.0 1 0 ug/1
0.50 0.13 ug/1
0.50 0 10 ug/1
0.50 Oil ug/1
0.50 0.10 ug/1
0.50 0.12 ug/1
0.50 0.19 ug/1
0.50 0.12 ug/1
0.50 0.11 ug/1
0.50 0.10 ug/1
0.50 0.18 ug/1
0.50 0.11 ug/1
0.50 0.10 ug/1
0.50 0.10 ug/1
0.50 () 14 ug/1
0.50 0.13 ug/1
0.50 0.18 ug/1
0.50 0.16 ug/1
0.50 0.16 ug/1
1.0 0.20 ug/1
0.50 0 10 ug/1
Run# 2 Limits
70-130%
70-130%
70-130%
70-130%
] = Indicates an estimated \'alue
B = Indicates anal)1e found in associated method blank
i\' = Indicates presumptive el'idence of a compound
1110 11 of 44
DACCUTEST.
F94517
Accutest Laboratories
Report of Analysis Pagel of]
Client Sample ID:
Lab Sample ID:
Matrix:
Method:
MW-2
F94517-2
AQ -Ground \\'ater
MADEP VPH REV l.l
Date Sampled: 06/27/12
Date Received: 06/28/12
Percent Solids: n/a
Project: Ram itS; 101 W Jefferson St (Hwy 158), jachon, NC
Huu #I
Hun #l
File ID
UV0~4ZH4 D
Purge Volume
5.0 ml
DF
MADEP VPH List
CAS No. Compound
CS-C8 Aliphatics {Unadj.)
C9-CI2 Aliphatics (Unadj.)
Analyzed
07/10/IZ
Result
XD
:\0
C9-CIO Aromatics (Unadj.) XD
CAS No.
4G0-00-4
4(i0-00-4
Surrogate Recoveries
fiFB
BFB
Run# I
94%
96%
By
MM
RL
100
100
100
RU!l.# 2
Prep Date
u/a
MDL Units
35 ugll
35 ug/1
35 "gn
Limits
70-130%
70-130%
Prep Batch
n/a
Q
Analytical Batch
GU\13011
l\'0 = Not detected MDL-Method Detection Limit J = Indicates an estimated \"alue
RL = Reporting Limit
E = Indicates \"alue exceeds calibration range
8 = Indicates ana1)1e found in associated method blank
N = Indicates presumptiYe e\•idence of a compound
•o 12 of 44
• AC:CUTEST.
F94517
Accutest Laboratories
Report of Analysis Page I of 2
Client Sample ID:
Lab Sample ID:
Matrix;
Method:
l"vtW-3
F94517-3
AQ -Ground Water
s:-.t G200B
Date Sampled: OG/27/12
Date Received: 06/28/12
Percent Solids: n/a
Project: Ram 115; 101 W jefferson St (lhvy !58), jackson, NC
File ID DF Analyzed By
Run #I E017612.D 07/06/12 TD
Run #2
IR"" II
Purge Volume
10.0 ml
Run #2
VOA 62008 List
CAS No. Compound Result RL
71-43-2 Benzene 2. 7 0.50
108-86-1 Bromobenzene ~D 0.50
74-97-5 Bromochloromethane NO 0.50
75-27-•l B romod irhlo romethane ND 0.50
75-25-2 Bromofonn NO 0.50
104-51-8 n-Buty1benzene 0.91 0.50
135-98-8 sr.c-lluty1bename 1.3 0.50
98-06-6 tert-Rutylbenzene 0.46 0.50
108-90-7 Ch1orobenzene NO 0.50
75-00-3 Ch1oroethane i\0 0.50
67-66-3 Chlorofonn NO 0.50
95-49-8 o-Ch1oroto1uene ND 0.50
106-43-4 p-Ch1orotoluene NO 0.50
56-23-5 Carbon tetrachloride ND 0 50
75-3-1-3 1, 1-Dichloroethane NO 0.50
75-35-4 I , 1-Dichloroethy1ene NO 0.50
563-58-6 1 .1-Dichloropropene l\0 0.50
96-12-8 1 ,2-Dibromo-3-chloropropane !\'D 0.50
106-93-4 1 ,2-Dibromoethane 1\iD 0.50
107-0G-2 1 ,2-Dichloroethane NO 0.50
78-87-5 1 ,2-Dichloropropane !\'D 0.50
142-28-9 1 ,3-Dichloropropane ;\0 0.50
108-20-3 Oi-hopropy1 ether 0.33 0.50
594-20-7 2, 2-Dich1oropropane NO 0.50
124-48-1 Dibromochloromethane NO 0.50
75-71-8 0 ich!orodifluoromethane l\'D 0.50
156-~9-2 cis-!, 2-0ichloroethylene NO 0.50
10061-01-5 cis-! , 3-Dichloropropene NO 0.50
541-73-1 m-Dichlorobenzene ND 0.50
95-50-1 a-Dichlorobenzene NO 0.50
IOG-46-7 p-Dichlorobenzene IW 0.50
1 5G-G0-5 trans-1 ,2-Dich!oroethy1ene NO 0.50
l\'0 : Not detected MDL-Method Detection Limit
RL = Reporting Limit
E = Indicates value exceed~ calibration range
Prep Date
n/a
Prep Batch
n/a
MDL Units Q
0.13 ug/1
0.12 ug/1
0.13 ug/1
0.12 ug/1
0.12 ug/1
0.10 ug/l
0.10 ug/l
0.10 ug/1 J
0.14 ug/1
0.17 ugl!
0.16 ug/1
0.11 ugll
0.10 ug/1
0.18 ug/1
0.12 ug/1
0.18 ug/1
0.14 ug/1
0.14 ug/1
0.10 ugll
0.16 ug/1
0.13 ug/1
0.12 ugll
0.11 ug/1 .I
0.17 ug/1
0.10 ug/1
0.15 ugll
0.12 ug/1
0.10 ug/1
0.12 ug/1
0.10 ugll
0.12 ug/1
0.18 ug/1
j = Indicates an estimated value
Analytical Batch
VE625
B = Indicates anal)1e found in assuciatcd method blank
N = Indicate~ presumptive evidenct~ of a compoum1
fJIJ 13 of 44
.ACCUTEST.
F\14517 ......... " .. ' ..
Accutest Laboratories
Report of Analysis Page 2 of 2 !"' w
Client Sample ID: MW-3 ~ Lab Sample ID: F!H5J7-:i Date Sampled: OG/27/12 .
Matrix: AQ-Ground Water Date Received: 06/28112
Method: Sl\-1 62008 Percent Solids: n/'
Project: Ram #5: 101 \\'Jefferson St (H\\)' 158), jackson. NC
VOA 6200B List
CAS No. Compound Result
10061-02-6 trans-1 ,3-Dichlnropropene NO
100-41-4 Ethylbenzcne NO
87-68-3 Hexachlorobuta<liene NO
98-82-8 Isopropy1hcm:ene 5.5. :
99-87-6 p-Isopropyltoluene NO
74-83-9 :-.1ethyl bromide NO
74-87-3 :"vlr.thyl chloride NO
74-95-3 \1ethylene bromide ~D.
75-09-2 :-.1ethylene chloride XD
1634-04-4 \lethyl Tert Butyl Ether 32.4
91~20-3 Xaphthalene 9.4
103-65-1 n-Propylbenume ND
100-42-5 Styrene NO
[130-20-6 1,1.1,2-Tt~lrachloroethanc ND
7I-55-6 1, 1 ,1-Trichlomcthane ND
79-34-5 I, I, 2,2-Tetrachloroethane NO
79-00-5 1,1, 2-Trichloroethane NO
87-6I-6 1, 2,3-Trichlorobenzene NO
96-18-4 I. 2,3-Trichloropropane i\'D
120-82-1 1, 2,4-Trichlorobenzene ;\'D
95-63-6 1 , 2.4-Trimethylbenzene i\'D
108-67-8 1,3, 5-Trimethylhenzene !\D
127-18-4 T etrachloroctllylene ND
108-88-3 Toluene 0.20
79-01-6 Trichloroethylene NO
75-69-4 T richloro num omethane ND.
75-01-4 Vinyl chloride NO
m.p-Xylene 0.27
95-47-6 o-Xylene 1.6
CAS No. Surrogate Recoveries Run# l
1868"53-7 Dibromofluoromethane 99%
17060-07-0 1 .2-Dichloroethane-04 95%
2037-26-5 Toluene-DB 101%
4fi0-00-4 4-B rom oflu oro benzene 101%
1\'D = i\ot detected MDL-tvtethod Detection Limit
RL = Reporting Limit
E = Indicates \'alue exceeds calibration range
RL MDL Units Q
0.50 0.10 ug/1
0.50 0.15 ug/1
0.50 0.13 ug/1
0.50 0.10 ug/1
0.50 0.10 ug/1
0.50 0.12 ug/1
0.50 0.20 ug/1
0.50 0.10 ug/1
2.0 1.0 ug/1
0.50 0.13 ug!l
0.50 0.10 ug/1
0.50 0.11 ug/1
0.50 0.10 ug/1
0.50 0.12 ug/1
0.50 0 19 ug/1
0.50 0.12 ug/1
0.50 0.11 ug/1
0.50 0.10 ug/1
0.50 0.18 ug/1
0.50 0.11 ug/1
0.50 0.10 ug/1
0.50 0.10 ug/1
0.50 0.14 ug/1
0.50 0.13 ug/1 J
0.50 0.18 ug/1
(l.~O O.I6 ug/1
0.50 0.16 ug/1
1.0 0.20 ug/1 J
0.50 O.IO ug/1
Run# 2 Limits
70-I30%
70-130%
70-130%
70-130%
J = Indicates an estimated value
B = Indicates analyte found in associated method blank
N = Indicate.<. presumptive e\'idence of a compound
I!IC 14 of 44
li'IACCUTEST.
F94517
Accutest Laboratories
Report of Analysis Page I of 1
Client Sample ID: M\\'-3
Lab Sample ID: F94517-3 Date Sampled: OG/27/12
Matrix: AQ-Ground Water Date Received: OG/28112
Method: 1\IADEP VPH REV 1.1 Percent Solids: n/a
Project: Ram liS; 101 \\1 Jefferson St (Hwy 158). Jackson. NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run Ill U\'054285.0 I 07/10/12 MM '"' n/a GUV3011
Run #2
II'"" #I
Purge Volume
5.0 ml
Run 112
MADEP VPH List
CAS No. Compound Result RL MDL Units Q
C5-CH Aliphatics (Unadj.) 146 !00 35 ug/1
C9-C12 Alipha!ics (Unadj.) ND 100 35 ug/1
C9-CIO Aromatics (Unadj.) 79_.9 !00 35 ug/1 J
CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 97% 70-130%
4G0-00-4 BFB 101% 70-130%
l\'D "' Not detected MDL-Method Detection Limit J = Indicates an estimated \'alue
RL = Reporting Limit
E = lndicales value exceeds calibration range
B = Indicates analyte found in associated me!hod blank
N = Indicate.s presumptive evidence of a compound
liiC 15 of 44
I9ACCUTEBT.
f94517
Accutest Laboratories
Report of Analysis Page 1 of 2
Client Sample ID:
Lab Sample ID:
Matrix:
Method:
1\1\V-4
F94517-4
AQ -Ground Water
Sl\1 6200H
Date Sampled: 06/~7/12
Date Received: OG/2H!12
Percent Solids: n/a
Project: Ram 115: 101 W Jefferson St (Hwy 158), jackson, 1\'C
File ID DF Analyzed By
Run #1 EOI7613.D I 07/06/12 TO
Run #2
IR"" #I
Purge Volume
10.0 ml
Run #2
VOA 62008 List
CAS No. Compound Result RL
71-43-2 Benzene NO 0.50
I 08-86-1 Bromo benzene NO 0.50
74-97-5 Bromochloromethane NO 0.50
75-27-4 Bromodichloromethane NO 0.50
75-25-2 Bromoform i\D 0.50
I 04-51-8 n-Butylbenzene 1\'D 0.50
135-98-8 sec-Butylbenzcne 1.3 0.50
98-06-6 tert-Butylbenlene 0.45 0.50
I 08-90-7 Chlorobenzene ND 0.50
75-00-3 Chloroethane ND 0.50
67-66-3 Chloroform ND 0.50
!!5-49-8 o-Chlorotollll~m.! ND 0.50
106-43-4 p-Chlorotoluene NO 0.50
56-23-5 Carbon tetrachloride ND 0.50
75-34-3 I ,1-Dichloroeth<ine NO 0.50
75-35-4 1,1-Dichloroethylene NO 0.50
563-58-6 1,1-Dichloropropene · ND 0.50
96-12-8 1,2-Dibromo-3-chloropropane !\'0 0.50
106-93-4 1.2-Dibromoethane ND 0.50
107-06-2 1,2-Dichloroethane ND 0.50
78-87-5 1, 2-Dichloropropane !\'D 0.50
142-28-!l I. 3-Dichloropropane NO 0.50
108-20-3 Di-lsopropyl ether NO 0.50
:"i!J-1-20-7 2, 2-Dichloropropanc ND 0.50
124-48-1 Dibromochloromethane ND 0.50
7~-71-8 D ichlorodifluoromet haue NO 0.50
156-59-2 cis-I ,2-Dichloroethylene NO 0.50
10061-01-5 cis-I ,3-Dithloropropene ND 0.50
541-73-1 m-Dichlorobenzene NO 0.50
95-50-1 a-Dichlorobenzene NO 0.50
10G-46-7 p-Dichlorobenzene l\'D 0.50
156-G0-5 trans-1,2-Dichloroethylene KD 0.50
N"D = Not detected MDL-Method Detection Limit
RL = Reporting Limit
E = Indicates value excet·ds calibration range
Prep Date
nh
MDL Units
0.13 ug/1
0.12 ug/1
0.13 ug/1
0.12 ug/1
0.12 ug/1
0.10 ug/1
0.10 ug/1
0 10 ug/1
0.14 ug/1
0.17 ug/1
0.1G ug/1
0.11 ug/1
0.10 ug/1
0.18 ug/1
0.12 ug/1
0.18 ug/1
0.14 ug/1
0.14 ug/1
0.10 ug/1
0.16 ug/1
0.13 ug/1
0.12 ug/1
0.11 ug/1
0.17 ug/1
0.10 ug/1
0.15 ug/1
0.12 ug/1
0.10 ug/1
0.12 ug/1
0.10 ug/1
0.12 ug/1
0.18 ogn
Prep Batch
"''
Q
J
j = Indicates an estimated \·alue
Analytical Batch
\'EG25
B = Indicates analyte found in associated method blank
N = Indicates presumptive evidence of a compound
Ill[] 16 of 44 l!J ACCUTEST.
F94517 ... """ '·-'".
Accutest Laboratories
Report of Analysis Page 2 of 2 w ..
Client Sample ID: M\\I..J ~ Lab Sample ID: F94517-4 Date Sampled: 06/27/12
Matrix: AQ ~Ground Water Date Received: 06/28/12
Method: Sl\1 62008 Percent Solids: nh
Project: Ram #5; 101 W jefferson St (Hwy 158), jackson, NC
VOA 62008 List
CAS No. Compound Result RL MDL Units Q
10061-02-6 trans-! ,3-Dichloropropcne ND 0.50 0.10 ug/1
100-41-4 Ethy!benzene 0.45. . 0.50 0.15 ug/1 J
87-GR-3 I {exachlorobutadiene ND 0.50 0.13 ug/1
98-82-8 l~opropylben7.ene O.G6 0.50 0.10 ug/1
fHl-87-6 p-lsopropyltoluene 0.28 0.50 0.10 . ug/1 J
74-!B-!l ;>.1ethyl bromide No·· 0.50 0.12 ug/1
74-87-:'1 Mdhyl rhlorich~ ~D 0.50 0.20 ug/1
74-95-3 Methylene bromide ND 0.50 0 10 ug/1
75-09·2 ;-..1ethylene chloride ND 2.0 1.0 ug/1
1()34-04-4 ;-..1ethyl Tert Butyl Ether ND 0.50 0 13 ug/1
91-20-3 :-.:aphthalene 0.30 0.50 0.10 ug/1 1
103-65-1 n-Propylbenzene 0.98 0.50 0.11 ug/1
100-42-5 Styrene ND 0.50 0.10 ug/1
630-20-G I ,I .1,2-Tetrachloroethane i\'D 0.50 0.12 ug/1
71-55-G 1.1 .I-Trichloroethane :\0 0.50 0.19 ug/1
79-34-5 I, I ,2,2-Tetrachloroethane i\'D 0.50 0.12 ug/1
79-00-5 1.1.2-Trichloroethane !\D 0.50 0.11 ugll
87-61-6 I, 2 .3-Trichlorobenzene ND 0.50 0.10 ug/1
96-18-4 I. 2 ,3-Trichloropropane ND 0.50 0.18 ug/1
120-82-1 1,2 ,4-T richlorobenzene ND 0.50 0.11 ug/1
95-63-6 I ,2 ,4-Trimethylbenzene :\D 0.50 0.10 ug/1
108-67-8 1,3 ,5-Trimcthylbcnzene ND 0.50 0.10 ug/l
127-18-4 T etrachlowet h ylene ND 0.50 0.14 ug/1
108-88-3 Toluene ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.18 ug/1
75-G9-4 T rich1orofluoromethane ND 0.50 O.IG ug/1
7:).01-'1 Vinyl chloride XD 0.50 0.16 ug/1
m,p-Xylene l\'D 1.0 0.20 ugll
~15-47-G o-Xylene NO 0.50 (l.l 0 ug/1
CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits
18G8-53-7 D i hromofluoromethane 100% 70-130%
17050-07·0 I, Z-Dichloroethane-04 94% 70-130%
2037-ZG-5 Toluene-OS 95% 70-130%
460-00-4 4-Bromofluoro benzene 101% 70-130%
f\D = i\'ot detected !viOL-Method Detection Limit j = Indicates an e.<>timatcd \'alue
RL = Reporting Limit
E = Indicates value exceeds calibration range
B = Indicates anal)1e found in a'>sociated method blank
N = Indicates presumptive evidence of a compound
f!IC 17 of 44 lJ ACCUTEST.
F~517
Accutest Laboratories
Report of Analysis
Client Sample ID:
Lab Sample ID:
Matrix:
Method:
M\\l-4
F94517-4
AQ -Ground \\'ater
MADEP VPH REV 1.1
Date Sampled:
Date Received:
Percent Solids:
OG/27/12
OG/28112
"" Project: Ram IrS: 101 W Jefferson St (Hv·:y 158). jackson, NC
Run #1
Hun #2
File ID
UV054Z!W.D
Purge Volume
5.0 ml
DF
MADEP VPH List
CAS No. Compound
C.'i-C8 Aliphatics (Unadj.)
C9-C12 Aliphatics (Unadj.)
Analyzed
07/10/12
Result
101
Gt\.4
C9-CJO Aromatics (Unadj.) 140
CAS No.
460-00-4
460-00-4
Surrogate Recoveries
BFB
BFB
Run# 1
97%
102%
By
MM
RL
100
100
100
Run# 2
Prep Date
n/a
MDL Units
3.'i ug/1
35 ug/1
35 ug/1
Limits
70-130%
70-130%
Prep Batch
n/e
Q
J
Analytical Batch
CUV3011
i\'0 = i\ot detected MDL-Method Detection Limit j = Indicates an estimated ,-alue
RL = Reporting Limit
E = Indicates value exceeds calibration range
B = Indicates analyte found in associated method blank
N = Indicates presumptive e\'idence of a compound
liD 18 of 44 II ACCUTE"ST.
F94517
Accutest Laboratories
Report of Analysis Page I of 2
Client Sample ID: MW-5
Lab Sample ID: F94517-5 Date Sampled: 06/27/12
Matrix: AQ -Ground Water Date Received: 06/28/12
Method: S\1 G200B Percent Solids: n/a
Project: Ram #5: 101 W jefferson St (Hwy 158}, jackson, NC
Run #I
Run #2
File ID
E017614.D
Purge Volume
10.0 ml
DF Analyzed
1 07/06/12
VOA 6200B List
CAS No. Compound Result
71-43-2 Benzene NO
108-86-1 Bromo benzene NO
74-97-5 Brom ochl oro methane NO
75-27-4 Bromodichloromethane NO
75-25-2 Bromoform NO
104-51-8 n-Butylbrn1.ene NO
135-98-8 sec-Butylbenzcne Nil'.
98-06-6 tert-Butylbem~ene NO
108-90-7 Chlorobenzene I\D
75-00-3 Chloroethane l'\0
67-66-3 Chloroform NO
95-49-8 o-Chloroto1uene NO
106-43-4 p-Ch!orotoluenc NO
56-23-5 Carbon tetrachloride KO
75-34-3 I, I-Oich1oroethane i\'0
75-35-4 I , I-Oich1oror.thy1ene NO
563-58-6 I, 1-0ich1oropropene No·
96-12-8 I. 2-Dibromo-3-chloropropane NO
106-93-4 1.2-0ibromoethane NO
107-06-2 I. 2-0ich!oroetlmne i\'0
78-87-5 I. 2-0ich!oropropanc )\'0
142-28-9 1.3-0ichloropropane NO
108-20-3 Oi-lsopropyl ether NO
594-20-7 2 ,2-0ich1oropropane i\0
124-48-1 Oibromoch1oromethane NO
75-71-8 Oich1orodilluoromethanc !\'D
156-59-2 cis-I. 2-Dichloroethylene :\'D
10061-01-5 cis-1 ,3-Dich\oropropene ~0
541-73-1 m-Dichlorobenzene ND
95-50-1 o-D ichlorob€~nzene NO
I 06-46-7 p-D ichloroh€~nzene NO
156-G0-5 trans-! ,2-Dichloroethy1ene NO
By
TD
RL
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
. 0.50
0.50
0.50
0 50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
1\'D = Not detected MDL -Method Detection Limit
RL = Reporting Limit
E = Indicates value exceed~ cali!Jratiun range
Prep Date Prep Batch Analytical Batch
n/a n/a VEG25
MDL Units Q
0 13 ug/1
0.12 ug/1
0.13 ug/1
0.12 ug/1
0.12 ug/1
0.10 ug/1
0.10 ug/1
0.10 ug/1
0.14 ug/1
0.17 ug/1
0.16 ug/1
0.11 ug/1
0.10 ug/1
0.18 ug/1
0.12 ug/1
0 18 ug/1
0.14 ug/1
0.14 ug/1
0.10 ug/1
0.16 ug/1
0.13 ug/1
0.12 ug/1
0.11 ug/1
0.17 ug/1
0.10 ug/1
0.1 ~ ug/1
0.12 ug/1
0.10 ug/1
0.12 ug/1
0.10 ug/1
0.12 ug/1
0.18 ug/1
j = Indicates an estimated value
B = Indicates analyte found in associated methnd !Jlank
l\' = Indicate.\. presump1ive evidence of a compound
.[] 19 of 44
.ACCUTEST.
F!I45H .............
Accutest Laboratories
Report of Analysis Page 2 of 2 ~ ~
Client Sample ID: M\\1-5 ~ Lab Sample ID: F94517-S Date Sampled: 06/27/12
Matrix: AQ-Ground Water Date Received: OG/28112
Method: SM 62008 Percent Solids: n/•
Project: Ram #5: 101 W jefferson St (H"'Y 158), jackson, 1\'C
VOA 6200B List
CAS No. Compound Result
100GI-02-6 trans-! ,3-Dichloropropcnc ND
100-41-4 Ethylbenzene ND
87-68-3 Hcxachlorobutadiene i\'D
98-82-8 Isopropylbenzenc ND
99-87-6 p-IsopropyHol uene ND
74-83-9 :\-Iethyl bromide ND.
74-87-3 \-!ethyl chloride i\'D
74-95-3 \1cthylene bromide 1\'D
75-09-2 :'\1ethylene chloride ND
1634-04-4 :Vlethyl Tert Butyl Ether ND
91-20-3 \'aphthalene !\D
103-65-1 n-Propylbenzene ND
100-42-5 Styrene ND
630-20-G I , I, I ,2-Tetrachloroethane ND
71-55-6 1 , 1,1-Trichloroethane ND
79-34-5 I. 1 ,2,2-Tetrachloroethane l\'D
79-00-5 I, 1 , 2-Trichloroethane ND
87-61-6 1, 2,3-Trichlorobcnzene ND
96-18--1 I. 2,3-Trichloropropane !\'D
120-82-1 I, 2,4-Trichlorobenzene ND
95-G:'I-fi 1, 2,4-Trimethylhenzene ND
I08-G7-8 1 .3 ,5-Trimethylbenzene 1\'D
127-18-4 T ctrachloroethylene i\'D
108-88-3 Toluene ND
79-01-G T rich!oroethyleJJe NO
75-69-4 T richlorofluoromethane 1\'D
75-01-4 Vinyl chloride KD
m.p-Xylene ND
95-47-G a-Xylene 1\'D
CAS No. Surrogate Recoveries Run# 1
1868-53-7 D i bromofl uoromcthane 98%
170G0·07-0 I. 2-Dichlorocthane-04 94%
2037-26-5 Toluene-DB 100%
460-00-4 4-Bromofluoro benzene 100%
ND = Not detem·d MDL -Method Detection Limit
RL = Reporting Limit
E = Indicates Yaluc exceeds calibration range
RL MDL Units Q
0.50 0.10 ug/1
0.50 0.15 ug/1
0.50 0.13 ug/1
0.50 0 10 ug/1
0.50 () 10 ug/1
0.50 0.12 ug/1
0.50 0:20 ug/1
0.50 0.10 ug/1
2.0 10 ug/1
0.50 0.13 ug/1
0.50 0.10 ug/1
0.50 O.ll ug/1
0.50 0.10 ug/1
0.50 0.12 ug/1
0.50 0.19 ug/1
0.50 0 12 ug/1
0.50 0.11 ug/1
0.50 0.10 ug/1
0.50 0.18 ug/1
0.50 0.11 ug/1
0.50 (l.IO ug/1
0.50 0.10 ug/1
0.50 0.14 ug/1
0.50 0.13 ug/1
0.50 0.18 ug/I
0.50 0.16 ugli
0.50 0.16 ug/1
1.0 0.20 ug/1
0.50 0 10 ug/1
Run# 2 Limits
70-130%
70-130%
70-130%
70-130%
] = Indicates an estimated \'alue
B = Indicates anal)1€ found in associated method blank
:\' = Indicates presumptive evidence of a compound
fi[J · 20 of 44
IJiiiACCUTEST.
F!l-4517
Acrutest Lahora!ories
Report of Analysis Page I of I
Client Sample ID:
Lab Sample ID:
Matrix:
Method:
MW-5
F94517-5
AQ -Ground \Vawr
MADEP VPH REV 1.1
Date Sampled:
Date Received:
Percent Solids:
06/27/12
06/28112
nl•
Project: Ram #5: 101 W jefferson St {Hwy !58), jackson, 0:C
Run #I
Run #2
File ID
UVOS4290.D
Purge Volume
5.0 ml
DF
MADEP VPH List
CAS No. Compoucd
CS-CB Aliphatics {Unadj.)
C9-CI2 Alipha1ics (Uni!dj.)
Analyzed By
07/10/12 ~l:t>.-1
Result RL
KD 100
ND 100
C9-C!O Aromatics {Unadj.) 1'10 100
Prep Date
n/<1
MDL Units
35 ugll
35 ug/1
35 ug/1
Prep Batch
n/a
Q
Analytical Batch
CUV3011
CAS No. Surrogate Recoveries Run# I Rue# 2 Limits
460-00-4
460-00-4
BFB
BFB
8G%
[)0%
1\D "' Not detected r-.mL-Method Detection Limit
RL = Reporting Limit
E = Indicate.~ value exceeds calibration range
70-130%
70-130%
j = Indicates an estimated value
B = Indicates analyte found in associaled method blank
N = Indicates presumptive e\·idence of a compnund
IICI 21 of 44
.ACCUTEST.
f9-4S11
Accutest Laboratories
Report of Analysis Page l of 2
Client Sample ID:
Lab Sample ID:
Matrix:
Method:
MVV-G
F94517-G
AQ -Ground \Vater
SM 62008
Date Sampled: 06127/12
Date Received: OG/28112
Percent Solids: n/a
Project: Ram #5; 101 W Jefferson St (Hwy 158). Jackson. :\'C
File ID
E017615.D
DF Analyzed By
Run #1
Run #2
07/0G/12 TO
Purge Volume
10.0 ml
VOA 6200B List
CAS No. Compound
71-43-2 Be1nene
108-86-1 Bromo benzene
74-97-5 Bro1noch!oromethane
75-27-4 Bromodicl!loromethane
75-25-2 Bromoform
I 04-51-8 n-Butylbenzene
135-98-8 sec-Butylbenzene
98-06-6 tert-ButylhenzP.ne
108-90-7 Chlorobenzene
75-00-3 Chlorocthane
67-GG-3 Chloroform
95-49-8 o-Chlorotoluene
106-43-4 p-Chlorotoluene
56-23-5 Carbon tetrachloride
75-34-3 1,1-Dichloroethane
75-35-4 1.1-Dichloroethylene
563-58-6 1,1-Dkhloropropene
96-12-8 I, 2-Dibromo-3-chloropropanc
106-93-4 1.2-Dibromocthane
107-06-2 I, 2-Dichlorocthane
78-87-5 I, 2-Dichloropropanc
142-28-9 I. 3-Dich1oropropane
108-20-3 Di-lsopropyl ether
594-20-7 2, 2-Dichloropropane
124-48-1 D i bromochl oromethane
75-71-8 Dichlorodinuoromcthane
156-59-2 ds-1 ,2-Dichlorocthylcne
10061-01-5 cis-! ,3-Dichloropropene
541-73-1 m-DichlurolJenzene
95-50-1 a-Dichlorobenzene
106-46-7 p-Dichlorobenzene
156-G0-5 trans-! , 2-Dichloroethylene
Result
ND
ND
!'\D
KO
i\D
:\'D
KD
!'\D
NO
ND
ND
NO
KD
;\j)
:\'D
i\D
ND
ND
ND
ND
NO
ND
1\'D
ND
ND
ND
NO
NO
NO
!'\D.
!\D
NO
:\'D = J\ot detPcted MDL-Method Detection Limit
RL = Reporting Limit
E = Indicates value exceeds calibration range
RL
0.50
0.50
0.50
0.50
0 50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
Prep Date
n/a
MDL Units
0.13 ugll
0.12 ug/1
0.13 ug/1
0.12 ug/1
0.12 ug/1
0.10 ug/1
0.10 ug/1
0.10 ug/1
0.14 ug/1
0.17 ug/1
0.16 ug/1
0.11 ugll
0.10 ug/1
0.18 ug/1
0.12 ug/1
0.18 ug/1
0.14 ug/1
0.14 ug/1
0.10 ug/1
0.16 ugll
0.13 ug/1
0.12 ug/1
0.11 ug/1
0.17 ug/1
0.10 ug/1
0.15 ug/1
0.12 ug/1
0.10 ug/1
0.12 ug/1
0.10 ug/1
0.12 ug/1
0.18 ug/1
Prep Batch
nh
Q
j = Indicates an estimated value
Analytical Batch
VEG25
B = Indicates analyte found in associated method blank
N = Indicates presumptiw eYidenre of a compound
liD 22 of 44
l'!IACCUTEST.
F!/4517 ... """ .......
Arcute~t Laboratories
Report of Analysis Page 2 uf 2 w
"' Client Sample ID: MW-6 ~ Lab Sample ID: F94517-6 Date Sampled: OG/27/12
Matrix: AQ -Ground Water Date Received: 06/28/12
Method: SM 6200B Percent Solids: ole
Project: Ram ~5: 101 W jefferson St (Hwy !58), jackson, NC
VOA 620GB List
CAS No. Compound Result RL MDL Units Q
10061-02-6 tran5-1 ,3-Dichloropropene NO 0.50 0 10 ug/1
100-41-4 Ethylbenzene ND 0.50 0.15 ug/1
87-68-3 H exachlorobutadiene ND 0.50 D.13 ug/1
98-82-8 Isopropylbenzene ND 0 50 0.10 ug/1
99-87-6 p-Isopropylto I uene ND 0.50 0.10 ug/1
74-83-9 Methyl bromide ND . 0.50 u. 12 ug/1
71-87-3 Methyl chloride ND 0.50 0.20 ug/1
74-95-3 Methylene bromide ND 0.50 0.10 ug/1
75-09-2 Methylene chloride ND 2.0 1.0 ug/1
l!i34-04-.:l Methyl Tert Butyl Ether ND 0.50 0.13 ug/1
91-20-3 Naphthalene ND 0.50 0.10 ug/1
103-65-1 n-Propylbeiw~ne ND '; 0.50 0.11 ug/1
100-42-5 Styrene ND 0.50 0.10 ug/1
630-20-6 I, 1,1, 2-Tetrachloroethane ND 0.50 0.12 ug/1
71-55-6 1, 1, 1-Trichloroethane t\'0 . 0.50 0.19 ug/1
79-34-5 1.1 , 2,2-Tetrachloroethane NO 0.50 0.12 ug/1
79-00-5 . 1,1,2-Trichloroethane NO 0.50 0.11 ug/1
87-61-6 1, 2,3-Trichlorobenzene 0.'0 0.50 0.10 ug/1
96-18-4 1 ,2,3-Trichloropropane 1\D 0.50 0.18 ug/1
120-82-1 1, 2, 4-Trichlorohenzene l\'0 0.50 0.11 ug/1
95-63-6 1 ,2 ,4-Trimethylbenzene !\'D 0.50 0.10 ug/1
108-67-8 1 ,3,5-Trimethylbenzene ND 0.50 (l.JO ug/l
127-18-1 Tctrachloroet hylene ND 0.50 0.11 ug/1
108-88-3 Toluene ND 0.50 0.13 ugll
79-01-6 Trichloroethylene NO 0.50 0.18 ug/1
7 5-69-4 T richloroiluo rome! ham~ r\"0 0.50 0.16 ug/1
75-01-4 Vinyl chloride KD 0.50 0.16 ug/1
m,p-Xylene KD 1.0 0.20 ug/1
95-47-6 o-Xylene t<D 0.50 0.10 ug/1
CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 99% 70-130%
17060-07-0 J·, 2-Dichloroethane-04 94% 70-130%
2037-26-5 Toluene-DB 100% 70-130%
460-00-4 4-Bromofluorobenzene 100% 70-130%
NO = Not detected MDL-Method Detection Limit ] = Indicates an estimated \'alue
RL = Reponing Limit
E = Indicate~ value exceeds calibration range
B = Indicates anal}1e found in associated method blank
l\' = Indicates presumptive evidence of a compound
£1[) 23 of 44
Ql ACCUTEST.
F94517
Accutest Laboratories
Report of Analysis Pagelofl
Client Sample ID:
Lab Sample ID:
Matrix:
Method:
MW·6
F94517-G
AQ -Ground Water
1\IADEP VPll REV 1.1
Date Sampled: 06/27/12
Date Receivod: 06/28/12
Percent Solids: n/a
Project: Ram #5: 101 \V Jt:ffer~on St (Hwy 158), jackson, NC
Run #I
Run #2
File ID
UV054291 0
Purge Volume
5.0 ml
DF
I
M.ADEP VPH List
CAS No. Compound
CS-C8 Aliphatics (Umulj.)
C9-C12 Alipha1ic~ (Unadj.)
Analyzed
07/10/12
Result
ND·
ND
C9-ClO Aromatics (Unadj.) ND
CAS No.
460-00-4
4G0-00-4
Surrogate Recoveries
BFB
BFB
Run# 1
91%
97%
By
Ml'v1
RL
100
!00
100
Run#2
Prep Date
n/,
MDL Units
35 ug/1
35 ug/1
35 ug/1
Limits
70-130%
70-130%
Prep Batch
"''
Q
Analytical Batch
GUV3011
1\D = Not detected MDL-Method Detection Limit ] = Indicates an estimated \"alue
RL = Reporting Limit
E = Indicates \'alue exceeds calibration range
B = Indicates anal)1e found in associated method blank
~ = Indicates presumpti\"e e,·idence of a compound
•o 24 of 44 II ACCUTEST.
FMSH
Accutest Laboratories
Report of Analysis Page I of2
Client Sample ID:
Lab Sample ID:
Matrix:
Method:
M\V-7
FD4517-7
AQ-Ground Water
sr-..-1 6wos
Date Sampled:
Date Received:
Percent Solids:
06/27/12
OG/28112
n/a
Project: Ram lfS: 101 W Jefferson St {Hwy ISS), Jackson. NC
File ID DF
Run #I E0176IG.D 1
Rmt #2
IR"" OJ
Purge Volume
10.0 ml
Run #2
VOA 62008 List
CAS No. Compound
71-43-2 Benzene
108-86-1 Bromobenzene
7-l-H7-5 Bromochloromethane
75-27-4 Bromodichlo romethane
75-25-2 Bromoform
104-51-8 n-Butylbenzene
135-98-8 sec-Butylbenzene
98-0G-6 terl-Butylbenzene
108-90-7 Chlorobenzene
75-00-3 Chlorocthane
67-66-3 Chloroform
95-49-8 o-Chloro1oluene
106-43-4 p-Chlorololuene
56-23-5 Carbon tetrachloride
75-34-3 1, 1-Dichloroethane
75·3~-4 1.1-Dichloroe-thylene
5(i3-58-6 1, 1-Olchloropropene
Analyzed By
07/0G/12 TD
Result
:\"D
l\"D
ND
ND
ND
ND
ND
ND
1\'D
ND
ND
ND
ND
1\'D
ND
ND •··
ND
RL
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.~0
0.50
0.50
0.50
0.50
0.50
. 0.50
96-12-8 I, 2-0ibromo-3-chloropropane ND
0.~0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
\06-93-4 1. 2-Oibrornoethane ND
107-06-2 1, 2-0ichloroethane :'\0
78-87-5 1, 2-0ichloropropane !\'0
142-28-9 1 .3-Dich!oropropane ND
108-20-3 Di-lsopropyll!lher ND
591-20-7 2, 2-Dichloropropane ND
124-48-1 Dibromochlor omethane ND
75-71-8 Dichlorodifluorornethane !\'0
156-59-2 cis-1 ,2-Dichloroethylene !\'D
10061-0\-5 cis-1.3-Dichloropropene !\'D
541-73-1 m-Dichlorobenzene ND
95-50-1 o-Dichlorobenzene NO
106-46-7 p-Dichlorobenzene NO
156-G0-5 trans-! .2-Dichloroethylcne N"D
NO = :-\ot detected MDL-!11ethod DeJection Limit
RL = Reponing Limit
E = Indicates value exceeds calibration range
Prep Date
'"'
MDL Units
0.13 ug/1
0.12 ug/1
0.13 ug/1
0.12 ug/1
0.12 ug/1
0.10 ug/1
0.10 ug/1
0.10 ug/1
0.14 ug/1
0.17 ug/1
0.16 ug/1
0.11 ug/1
0.10 ug/1
0.18 ug/1
0.12 ug/1
0.1R ug/1
0.14 ug/1
0.14 ugll
0.10 ug/1
0.16 ug/1
0.13 ug/1
0.12 ug/1
0.11 ug/1
0.17 ug/!
0.10 ug/1
0.15 ug/1
0.12 ug/!
0.10 ug/1
012 ug!l
0.10 ug/1
0.12 ug/1
0.18 ug/1
Prep Batch
n/a
Q
J = lndicales an estimated \"alue
Analytical Batch
VEGZS
B = Indicates anal)1e found in associated method blank
N = Indicates presumptive e\·idcnce of a compound
&10 25 of 44 U!J ACCUTEST.
FS-4517
Accutest Laboratories
Report of Analysis Page 2 of 2 "' "
Client Sample ID: !\1W-7 [§ Lab Sample ID: F94517-7 Date Sampled: OG/27/12
Matrix: AQ -Ground Water Date Received: 06/28/12
Method: SM 620GB Percent Solids: n/a
Project: Ram #5; 101 W jefferson St {lhy !58), jackson, NC
VOA 620GB List
CAS No, Compound Result RL MDL Units Q
10061-02-6 trans-! ,3-Dichloropropene ND 0.50 {) 10 ug/1
100-41-4 Ethylbenzene ND 0.50 0.15 ug/1
87-68-3 H exachlo ro butadiene ND . 0.50 0.13 ug/1
98-82-8 Isopropylbenzene ND 0.50 0.10 ug/1
99-87-6 p-lsopropyltoluene ND 0.50 0.10 ug/1
74-83-9 \lethyl bromide ND 0.50 0.12 ug/1
7<1-87-3 \1ethyl chloride ND 0.50 0.20 ug/1
74-95-3 \-!ethylene bromide NO 0.50 0.10 ug/1
75-09-2 ).-!ethylene ~h.loride :\D 2.0 1.0 ug/1
1634-04-4 \1t>thyl Tert Butyl Ether !\'D 0.50 0.13 ug/1
91-20-3 i\aphthalene !\'D 0.50 0.10 ug/1
103-65-1 n-Propylbenzene ?\'D 0.50 0.11 ug/1
100-42-5 Styren('; i\'D 0.50 0.10 ugll
630-20-6 1 , 1 , I, 2-Tetrachloroethane :-\D. 0.50 0.12 ug/1
71-55-[l 1 , I , 1-Trichloroethane l\'IJ 0.50 0.19 ug/1
7!l·3·1-5 1 , I ,2, 2-TP.trachloroethane l'ID 0.50 0.12 ug/1
79-00-5 1 ,I ,2-Trichloroethane ND 0.50 () .11 ug/1
87-[ll-6 1,2,3-Trichlorobenzene XD 0.50 0.10 ug/1
!JG-18-4 1 , 2,3-Trich1oropropane l'/0 ().~() 0.18 ug/1
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0 II ug/l
95-63-6 I ,2,4-Trimethylbenzene ND 0.50 0 10 ug/1
108-67-8 I .3.5-Trimethylbenzene ND 0.50 0.10 ug/1
127-18-4 T etrach1oroethy lene ND 0.50 0 14 ug/1
108-88-3 Toluene ND 0.50 0.13 ug/1
79-01-6 Trichloroethylene ND 0.50 0.18 ug/1
75-69-4 T richlorofluoromethane I\'D 0.50 0.16 ug/1
75-01-4 Vinyl chloride i\'1). 0.50 0.16 ug/1
m.p-Xylene ND J.O· 0.20 ug/1
95-47-G a-Xylene XD 0.50 0.10 ug/1
CAS No. Surrogate Recoveries Run# I Run# 2 Limits
l8G8-53-7 Dibromofluoromethane 99% 70-130%
170G0-07-0 1, 2-Dichloroethane-04 96% 70-130%
2037·26-5 Toluene-DB 99% 70-130%
4G0-00-4 4 ~ Bromofluorohenzene 101% 70-130%
I\'D = Not detected MDL-lv!ethod Detection Limit J = Indicates an estimated value
RL = Reporting Limit
E = Indicates \'alue exceeds calibration range
B = Indicates analyte found in associated method blank
N = Indicates presumptive P.Yidence of a compound
110 26 of 44
.ACCUTEST.
F9>4517
Accutest Laboratories
Report of Analysis Page 1 of 1
Client Sample ID:
Lab Sample ID:
Matrix:
Method:
MW-7
F94517-7
AQ -Ground \Vater
MADEP VPH REV 1.1
Date Sampled: OG/27/12
Date Received: OG/28/12
Percent Solids: n/a
Project: Ram 115: 101 \".'Jefferson St (Hwy 158), Jackson, NC
Run #1
Run #2
IR"" #1
Run #2
File ID
UVOS4292.D
Purge Volume
5.0 ml
DF
1
MADEP VPH List
CAS No. Compound
CS-C8 A!iphatics (Unadj.)
C9-C12 Aliphatics (Unadj.)
Analyzed By
07/10/12 1\IM
Result RL
!\'0 100
C:D 100
C9-C!O Aromatics (Unadj.) NO !GO
Prep Date
'"'
MDL Units
35 ug/1
35 ug/1
35 ug/1
Prep Batch
""
Q
Analytical Batch
GUV30Il
CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4
4G0-00-4
BFB
BFB
87%
89%
:\0 == Not detected MDL-Method Detection Limit
RL = Reporting Limi1
E == Indicates value exceeds calibration range
70-130%
70-130%
] = Indicates an estimated \'alue
B == indicates analyte found in associated method blank
N = Indicates presumptive evidence of a compound
flO 27 of 44
IIACCUTEST.
F945H
Accmest Laboratories
Report of Analysis P<~ge1of2
Client Sample ID:
Lab Sample ID:
Matrix:
Method:
MW-R
F94517-H
AU -Ground Water
S!\'I 62008
Date Sampled: OG/27/11!
Date Received: OG/28/12
Percent Solids: n/a
Project: Ram #5; 101 \V jefferson St (Hwy 158). jackson. NC
File ID OF Analyzed By
Run #I EOI7617.D 1 07/06/12 TD
Run liZ
IR"" #l
Purge Volume
10.0 ml
Run #2
VOA 6200B List
CAS No. Compound Result RL
71-43-2 Benzene i\'D 0.50
108-86-1 Bromobenzene \'D 0.50
74-97-5 Bromochloromethane i\'D 0.50
75-27-4 Bromodichloromethane i\'D 0.50
75-25-2 Bromofonn NO 0.50
104-51-8 n-Butylbenzenc ND· 0.50
135-98-8 sec-Butylbcnz~nc 0.17 0.50
98-06-6 tert-ButyllH!IIlt!!IC ND 0.50
108-90-7 Chlorobenzene ND. 0.50
75-00-3 Chloroethane ND 0.50
67-66-3 Chloroform ND 0.50
95-49-8 o-Chlorotoluene ND 0.50
106-43-4 p-Chlorotoluene NO 0.50
56-23-5 Carbon tetrachloride 7\D 0.50
75-34-3 1,1-Dichloroethane .\'D 0.50
75-35-4 1 ,I-Dichloroethylene I\D 0.50
563-58-6 1,1-Dichloropropene l\'D 0.50
96-12-8 1, 2-Dibromo-3-chloropropane !\"D 0.50
106-93-4 1. 2-Dibromoethane !\D 0.~0
107-06-2 1. 2-Dichloroethane t\D 0.~0
78-87-5 1. 2-Dichloropropane ND 0.50
142-28-9 1,3-Dichloropropane ND 0.50
108-20-3 Di-lsopropy1 P1hcr ND 0.50
594-20-7 2 ,2-Dichloropropane ND 0.50
124-48-1 Dibromochloromethane I\D 0.50
75-71-8 DichlorodiOuoromethane l\'D 0.50
156-59-2 cis-1,2-Dichloroethylene !\'D 0.50
10061-01-5 cis-1,3-Dichloropropene !\'D 0.50
541-73-1 m-Dichlorobenzene ND 0.50
95-50-1 o-Dichlorobenzene ND 0.50
JOG-46-7 p-Dichlorobcnzenc ND 0.50
156-60-5 trans-!, 2-Dichloroethylcnc ND 0.50
ND "' Not detected M])L -Method Detection Limit
RL == Reporting Limit
E "' Indicates value exceed~ calibration range
Prep Date
n/a
Prep Batch
n/a
MDL Units Q
0.13 ug/1
0.12 ugl!
0.13 ugl!
0.12 ug/1
0.12 ug/1
0.10 ug/1
0.10 ug/1 J
0.10 ug/1
0.14 ug/1
0.17 ug/1
0.16 ug/1
0.11 ug/1
0.10 ug/1
0.18 ugll
0.12 ugll
0.18 ugll
0.14 ug/1
0.14 ug/1
0.10 ug/1
0.16 ug/1
0.13 ug/1
0.12 ug/l
0.11 ug/1
0.17 ug/1
0.10 ug/1
0.15 ug/1
0.12 ug/1
0.10 ug/1
0.12 ug/1
0.10 ug/l
0.12 ug/1
0.18 ug/1
J = Indicates an estimated valt1c
Analytical Batch
\'E625
B = Indicates analyte found in associated method blank
N = Indicates presumptive evidence of a compound
IIC 28 of 44
I£IACCUTEST.
FB4517 •••••••o••••
Accutest L<~horatories
Report of Analysis l'ag(' 2 of 2 "' Q
Client Sample ID: MW-8 [§ Lab Sample ID: F94517-8 Date Sampled: 06/27/12
Matrix: AQ -Ground \\'ater Date Received: 06/28/12
Method: SJ\1 62008 Percent Solids: "'' Project: Ram #5: 101 W jefferson St (Hwy 158}, j~ckson, NC
VOA 6200B List
CAS No. Compound Result
10061-02-6 trans-1,3-Dichloropropene I\'D
100-41-4 Ethylbenzene rm
87-68-3 Hexachlorobutadiene · ND
98-82-8 r~opropylbenzene 0.20
99-R7-G p-lsopropy! to I uene NO
74-83-9 ~1e1hyl bromide ND
74-87-3 !\1ethyl chloride NO
74-95-3 :--.1ethylene bromide ND
75-09-2 :--.1ethylene chloride XD
1634-04-4 \1ethyl Ten Butyl Ether NO
91-20-3 Naphthalene ND
103-65-1 n-Propylbenzene NO
100-42-5 Styrene NO
630-20-6 1.1,1,2-Tetrachloroethane NO
71-55-6 1.1 .1-Trichloroethane KO
79-34-5 1,1 ,2,2-Tetrachloroethane :\D
79-00-5 1.1,2-Trichloroethane I\'D
87-61-6 l , 2.3-Trichlorobenzene 1\D
96-18-4 1 . 2.3-T richloropropane ND
120-82-l 1 . 2,4-Trichlorobenzene NO
95-63-G l , 2. 4-T rimethylbcnzene NO
108-67-8 1 .3 ,5-Trimethylbenzene NO
127-18-4 T etrachlorocth~ ·Jcnc ND
108-88-3 Toluene NO
79-01-6 Trichloroethylene I\D
75-69-4 T rlch1orofluoromethanc I\D
75-01-4 Vinyl chloride NO
m,p·Xylene ND
95-47-6 a-Xylene NO
CAS No. Surrogate Recoveries Run# 1
1868-53-7 Dibromofluoromethane 100%
17060-07-0 1, 2-DicWoroetlmne-04 97%
2037-26-5 Toluene-DB 101%
460-00-4 4-Bromoflu oro benzene 102%
i\0 = Not detected MDL-Method Detection Limit
RL = Reporting Limit
E = Indicates value exceeds calibration range
RL MDL Units Q
0.50 0.10 ug/1
0 50 0.15 ug/1
0.50 0.13 ug/1
0.50 0.10 ug/1 J
0.50 0.10 ug/1
0.50 0.12 ug/1
0.50 0.20 ug/1
0.50 0.10 ug/1
2.0 1.0 ug/1
0.50 0.13 ug/1
0.50 0.10 ug/1
0.50 0.11 ug/1
0.50 0.10 ug/1
0.50 0.12 ug/1
0.50 0.19 ug/1
0.50 0.12 ug/1
0.50 0.11 ug/1
0.50 0.10 ug/1
0.50 0.18 ug/1
0.50 0.11 ug/1
0.50 0.10 ug/1
0.50 0.10 ug/1
0.50 0.14 ug/1
0.50 0.13 ug/1
0.50 0.18 ug/1
0.50 0.16 ug/1
0.50 0.16 ug/1
1.0 0.20 ug/1
0.50 0.10 ug/1
Run# 2 Limits
70-130%
70-130%
70-130%
70-130%
J = Indicates an estimated \'alue
B = Indicates anal)1e found in associated method blank
1\ = Indicates presumptive evidence of a compound
•c 29 of 44
IIACCUTEST.
F~S17
Accutcsl Laboratories
Report of Analysis Page 1 of 1
Client Sample ID:
Lab Sample ID:
Matrix:
Method:
1\.f\V-H
F94517-8
AQ -Ground Water
MADEP VPII REV 1 1
Date Sampled: 06/27/12
Date Received: 06/28/12
Percent Solids: n/a
Project: Ram #5: 101 W jefferson St (Hwy 158), jackson, NC
Run #1
Run #2
I"""" Run #2
File ID
UV05429:l.D
Purge Volume
5.0 ml
DF
MADEP VPH List
CAS No. Compound
C5-C8 Aliphatics (Unadj.)
C9-C12 Aliphatics (Unadj.)
Analyzed By
07/10/12 MM
Result RL
1\"D 100
N"D 100
C9-ClO Aromatics (Unadj.) KD 100
Prep Date
nh.t
MDL Units
35 ug/1
35 ug/1
35 ug/1
Prep Batch
n/a
Q
Analytical Batch
GUV3011
CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4
400-00-4
RFB
BFB
89%
84%
ND = Not dch•cted MDL-Method Detection Limit
RL = Reporting Limit
E = Indicates value exceeds calibration range
70-130%
70-130%
j "' Indicates an cstimat(•d value
B = Indicates analyte found in associated method blank
N "' Indicates presumptive evidence of a compound
liiiJ 30 of 44 ll ACCUTEST.
F9-4517
II[] Sou~heast
• Accl.JT:ES~ ·
l. A !3'0 !~A 1 O·R! . . -
Misc. Forms
Custody Documents and Other Forms
Includes the follovl'ing where applicable:
Certification Exceptions
Ceriiflcation Exceptions {NC)
Chain of Custody
Section 4
110 31 of 44 al ACCUTEST.
F945H
I!JIB Accutest Laboratories Southeast ~~t:a:t 4 5 17Ge_i OF _L_ II ACCUTEST. 4405£,~!~.?w~£~t!~~32SII
••"o"•Tc,.•••
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0 5Da)oRUS>< --D , o., EMERC>!:.CY -0 ~ Oo7 E"'FAGEt.<;V --· 0 1 l>i17 LMEROENCY -----0 omER ~~~ ' l,·.ci..C. '
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F9451 7: Chain of Custody
Page1of2
IIIIJ 32 of 44
8ACCUTEST.
F9<!5H ..............
ACCUTEST LABORATORIES SAMPLE RECEIPT CONFIRMATION
-a * ---ACCl,.lTEST'SJOn NUMBER:_j.-· -/ '-/5! 7 CLIEl-."T: G f4l:: PROJECT: 8 c, ,.._., ...j
DATE/TIME RECEIVED:..Q..&-?y~r L d 100 [MMIDD·'YY 24:00) NIMBER OF COOLERS RECElYED· ..• ""'---
M:ETIIOO OF DELIVERY: ~ UPS ACCL'll!ST COURIER GREniOL'l-ID DELIVERY OrnER
AIRB!LLl>.'UMBERS: ?~lfr1•_jZ."'-7]..,c_ ____________________ _
COOLER IJ\IORMATION ~CUSTODY SEAL NOT PRESE!>."T OR NOT D. 'TACT
CHAlNOt' CUSTODY NOT RECEJ\'ED(COC)
A."lALYSlS REQUESTED IS UNCLEAR OR MISSING
!>AMPLE DATES OR TIMES IJ.o.ICLEAR OR MISSING
TEMPERATURE CR.lTERlA NOT MET
I'IETICEPRESEhT
TRIP BLAI-o'K INFOR.\.fATION
MJSC. JNFORMATION
NUMBER OF ENCOkES 7 l:i.OR.AM __ >-DRAM __
!<."UMBER OF 50H FIELD KITS 1
NUMI!Ell OF LAB Frl.TERED METALS 1
TEMPERATURE INFOB,.\1ATION §IR11iERMID 3 CORR.FACTOR
OBSER\'EDTI..\fl'S: '?__
CORRECTED TEMPS: 7_ ~
SAMPLE INFORMATION
LE LABELS l'RESEhT OS ALL BOTTLES
INCOJUtECT 1-.'t'MBER OF C0,..,7AINERS USED
SAM:PLE RECET\ 'ED IMPROPERLY ?RESERVED
INS!JFFitru.T\'OLL'ME FOR A.'>AL YSIS
DAITS:ITMES OS"COC DO SOT MATCH SAMPLE LABEL
IDS ON COC DO NOT MATCH LABEL
VOC YTALS HA \'E HEADSP ACE (MACRO BUBBLES}
BOTTI.ES RECEIVED BDT A. '\AI. YS!S NOT REQUESTED,
SO BOTil.ES R.ECEIYED FOR ANALYSIS REQUESTED
lJNCLE.AR FU TERING OR COMPOSIT1NG INSTRUCTIONS
SAMPLECO!>.'TAISER(S) RECEIVED BROKEN
SOLIDS IAR NOT RECEIVED
~0.3~ FIELD kiT FROZD/'WlTHIN 41 HOUR'S
RESIDUAL CHLORn.'E PRESE}."T
!AP!'ICAilL£ !0 ErA 600 SERIES OR. NOR.':11 CAllOLIX,o, Oll.GAA'ICS)
NF 12110 r&eeipt conl~rmahon 12291D.x1s
F94517: Chain of Custody
Page 2 of 2
110 33 of 44 II AC:CLJTEST.
F945H ,_ .. ., ... ' ,,. ....
Ill[;] . South~~,st . ,
1111 AcC;bJTES'T,
LA!lOI-11\T.OFI!ES
GC/MS Volatiles
QC Data Summaries
Includes the follO\ving where applicable:
Method Blank Summaries
Blank Spike Summaries
Matrix Spike and Duplicate Summaries
Section 5
liiC 34 of 44
II ACCUTEST.
F94517
Method Blank Summary
Job Number: F9,1517
Account: GRINCC GRI (Geological Resources Inc.)
Project: Ram #5: 101 \'./jefferson S! (I!\\)' !58). jackson, NC
Sample
VE625-MB
File ID DF
E017596.D 1
Analyzed By
07/06/12 TO
The QC reported here applies to the follo"'ing samples:
Prep Date
n/a
Prep Batch
n/a
Page I of 2
Analytical Batch
VE625
Method: S/\1 GZOOB
f-94517-1, F9·1~17-2, F9·1517<l. F94517-4. F94517-S, F94517-6, F945I7-7, F94517-8
CAS No. Compound
71-43-2 Benzene
108-86-1 Bromobcnzene
74-97-5 Bromochloromcl heme
75-27-4 Bromo(Jichloromethane
75-25-2 Bromoform
104-51-8 n-Butylbenzene
135-98-8 sec-Butylbenwne
98-06-6 ten-Buty1benzene
JOH-90-7 Chlorohenzene
75-00-3 Chlorocthane
67-GG-3 Chloroform
95-49-8 o-Ch1orotoluene
106-43-4 p-Chlorotoluenc
56-23-5 Carbon tetrachloride
75-34-3 1,1-Dichloroethane
75-35-4 1.1-0ichloroethylenc
563-58-6 1,1-0ichloropropene
96-12-8 1,2-Dibromo-3-chloropropane
106-93-4 1,2-Dibromoethane
107-06-2 1.2-0ichloroethane
78-87-5 _I. 2-Dich1oropropane
142-28-9 1.3-0ichloropropane
108-20-3 Di-lsopropy1 ether
594-20-7 2 ,2-Dich1oroptopane
124-48-1 Dibromochloromethane
75-71-8 Di ch1orodifluoro methane
156-59-2 cis-! .2-Dich!orocthylcne
10061-01-5 cis-1,3-Dichloropropcne
541-73-1 m-Dichlorobenzenc
95-50-1 a-Dichlorobenzene
106-46-7 p-Dichlorobenzene
156-60-5 trans-I. 2-Dich1oroethy1ene
10061-02-G trans-I, 3-Dich1oropropene
100-41-4 Ethylbenzene
87-68-3 Hexachlorobutadiene
98-82-8 hopropylbenzr.ne
Result RL MDL
NO 0.50 0.13
AD 0.50 0.12
NO 0.50 0.13
1\'D 0.50 0.12
NO 0.50 0.12
:\0 0.50 0.10
ND 0.50 0.10
:\'0 0.50 0.10
NO 0 so 0.14
NO 0.50 0.17
0.26 0.50 O.IG
ND 0.50 0.11
ND 0.50 0.10
ND 0.50 0.18
1\'D 0.50 0 12
:\'0 0.50 0.18
NO 0.50 011
I\'D 0.50 0.14
1\:D 0 so 0 10
!\'D 0.50 0.16
i\'0 0 50 0.13
NO 0.50 0.12
i\'0 0.50 0.11
ND 0.50 0.17
i\0 0.50 0. I 0
ND 0.50 0.15
ND 0.50 0 12
ND 0.50 0.10
?\0 0.50 0 12
NO 0.50 0.10
i\D 0.50 0.12
NO 0.50 0.18
i\0 0.50 0 10
NO 0.50 0.15
1\:D 0.50 0.13
l\'0 0.50 0.10
Units
ug/1
"gn
ug/1
ug/1
ug/1
ug/l
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/l
ug/1
ug/1
ug/1
ug/1
ug/1
ug!l
ug/1
ug/1
ug/1
ug/1
ug/1
ugll
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ugll
ug/1
"gn
ug/1
Q
J
fil[] 35 of 44 IJ ACCUTEST.
FS45H
Method Blank Summary
Job Number: F94517
Account: GRINCC GRI (Geological Rc~ourccs Inc.)
Project: Ram #5: 101 \V Jefferson St (Hwy ISS), jackson, NC
Sample
VE625-MB
File ID OF
E0\7596.0 1
Analyzed By
07/06/12 TO
The QC reported here applies to the follov.ing samples:
Prep Date
"''
Page 2 of 2
Prep Batch Analytical Batch
n/a VEGZS
Method: SM 6200B
F94517-l, EHSI7-2, F94517-3, F94517-4, F94517-5, F94517-6, F94517-7, F94517-8
CAS No. Compound
99-87-6 p-lsopropyltoluene
74-83-9 Methyl bromide
74-87-3 Methyl chloride
74-95-3 :-.!ethylene bromide
75-09-2 Methylene chloride
1634-0·1-4 Methyl Tert Butyl Ether
91-20-3 :\aphthalcne
103-65-1 n-Propylhenzene
100-42-5 Styrene
630-20-6 1.1 , I, 2-Tetrachloroethane
71-55-6 1.1 , 1-Trichloroethane
79-34-5 I, 1 ,2, 2-Tetrachloroethane
79-00-5 1.1 .2-Trichloroethane
87-Gl-6 1.2 ,3-Trichl01 obenzenc
96-18-4 1 ,2, 3-Trichloropropane
120-82-1 I ,2 ,4-Trichlorobenzene
95-63-G I , 2, 4-Trimethylbenzenr.
108-67-8 I ,3,5-Trimetl1ylbenzene
127-18-4 T et rach1oroeth) ·lene
108-88-3 Toluene
79-01-6 Trichloroethylene
75-69-4 T rich1orofluoromethane
75-01-4 Vinyl chloride
m,p-Xylene
95-47·6 a-Xylene
CAS No. Surrogate Recoveries
1868-53-7 Dibromofluoromethane
17060-07-0 I. 2-Dichloroethane-04
2037-26-5 Toluene-OS
460-00-4 4-Bromofluorobenzene
Result RL MDL
XD 0.50 0.10
NO 0.50 0.12
ND 0.50 0.20
\:0 0.50 0.10
NO ' 2.0 1.[)
NO 0.50 0.13
~D 0.50 0.10
NO 0.50 (LJJ
NO 0 50 0.10
:\'0 0.50 0.12
NO 0.50 D.l9
i\'D 0 so 0.12
~0 0.50 0.11
ND 0.50 0.10
ND 0.50 0.18
:\'0 0.50 0.11
NO 0.50 0.10
:\ID 0.50 0.10
!\'D 0.50 0.14
NO 0.50 0.13
:\'D 0.50 0.18
~0 0.50 0.16
i\'D 0.50 0.16
i\'D 1.0 0.20
~0 0 50 0.10
Limits
101% 70-130%
102% 70-130%
102% 70-130%
104% 70-130%
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Q
110 36 of 44
BACCUTEST.
F\14517
Blank Spike Summary
Job Number: F94517
Account: GRINCC GJU (Geological Resources Inc.)
Project: Ram #5: 101 W jefferson St (Jlwy 158), jackson, NC
Sample
VE625-BS
File ID DF
E017594.D 1
Analyzed By
07/06/12 TO
The QC reported here applies to the follov.ing samples:
Prep Date
nl'
Prep Batch
n/'
Page I of2
Analytical Batch
VEGZS
Method: SM GZOOR
F94517-1, F94517-Z, F94517-3, F94S17-4. F94517-5. F94517-6, F94517-7, F9-l517-R
Spike BSP BSP
CAS No. Compound ug/1 ug/1 % Limits
71-43-2 Benzene 10 12.1 121 70-130
108-86-1 Bromohenzene 10 10.8 108 70-130
H-97-5 Bromochloromethane 10 11.8 118 70-J 30
7~-27-4 Bromodkhloromethane 10 10.5 105 70-130
75-25-2 Bromoform 10 9.5 90 70-130
104-51-8 n-Butyl!Jenzene 10 10.2 102 70-130
135-98-8 sec-Butylbenzene 10 10.3 103 70-130
98-06-6 tcr!-Butylhenzenc 10 10.1 101 70·130
108-90-7 ChloroUcm:ene 10 12.0 120 70-130
75-00·3 Chlorocthane 10 12.4 124 60-140
67-66-3 Chloroform 10 1 1.5 115 70-130
95-49·8 o·Chloro!Olttene 10 10.9 109 70·130
106·43-4 p-Chlorotoluene 10 10.7 107 70-130
56·23·5 Carbon tetrachloride 10 11.3 113 70-!30
75·34·3 l,l·Dir.hloroethane 10 12.1 121 70·130
75·35·4 1 .l·Dichloroethylene 10 10.5 105 70·130
563·58·6 1, 1-Dithloropropene 10 10.4 104 70-130
96·12·8 l,2·Dibromo·3·chloropropanc 10 !.L3 93 70·130
1Qfi.93·4 1,2·Dibromoethane 10 10.3 103 70·130
107·06·2 1 ,2·Dichloroethane 10 11.9 ll9 70-130
78·87·5 l,2·Dichloropropane 10 10.7 107 70·130
142·28-!l 1,3·Dichloropropane 10 10.6 100 70·130
108-20·3 Di-Isopropyl ether 10 10.6 106 70·130
594·20·7 2 ,2·Dichloropropane 10 11.9 119 70·130
124·48·1 Dibromochlorom ethane 10 10.1 101 70·130
75·71-8 Dichlorodifluoromethane 10 12.6 126 G0·140
156·59·2 cis· I ,2-Dichloroetbylene 10 10.8 108 70·130
10061·01·5 cis· I ,3·Dichloropropenc 10 10.3 103 70·130
541· 73·1 m-Dichlorobenzene 10 10.7 107 70·130
95·50·1 o·Dichlorohenzene 10 10.5 105 70·130
106·46·7 p·Dichlorobemene 10 10.8 '108 70·130
156·60·5 trans· I, 2·Dichloroethylene 10 10.8 108 70·130
10061·02-6 trans·1,3·Dichloropropene 10 10.5 105 70·130
100·41·4 Ethylbenzene 10 12.1 121 70·130
87-G8-3 llcxachlorobutadienc 10 9.9 99 70·130
98·82·8 lsopropylbenzene 10 10.1 101 70·130
* "' Outside of Control Limits.
110 37 of 44 Ill ACCUTEST.
F94517 .. ··--......
Blank Spike Summary
Job Number: F94517
Ae<:ount: GRINCC GRI (Geological Resources Inc.)
Project: Ram #5; 101 \V Jefferson St (llwy 158). jackson, NC
Sample
VE625-BS
File ID DF
E017594.D 1
Analyzed By
07/06/12 TD
The QC reported here applies to the following samples:
Prep Date
'"'
Page 2 of 2
Prep Batch Anal}tical Batch
n/a VE625
Method: Sl\'1 6200B
F94517-l, F94517-2. F94517-3, F94517-4. F94517-5. F94517-6, F94517-7, F94517-8
CAS No. Compound
~9-87-6 p-lsopropyHoluene
H-83-9 Methyl bromide
74-87-3 Methyl chloride
74-95-3 Methylene bromide
75-09-2 !vi ethylene chloride
1634-04-4 ~1cthyl Tert Butyl Ether
91-20-3 Naphthalene
103-65-1 n-l'ropylbenzene
100-42-5 Styrene
630-20-5 1, J, 1.2-Tetrachloroethane
71-55-6 1, 1 , 1-Trichloroethane
79-34-5 1,1 ,2, 2-Tetrachloroethane
79-00-5 1, I ,2-Trichloroethane
1!7-61-6 1,2,3-Trichlorobenzcne
!HJ-18-4 1 , 2,3-Trichloropropane
120-82-1 1 ,2,4-Trichlorobenzene
!15-63-6 1,2,4-Trimethylbenzene
108-67-8 1,3,5-Trimethylbenzene
127-18-4 Tetrachloroethyhmr.
108-88-3 Toluene
79-01-6 Trichloroethylene
75-69-4 T rich\orofluoromethane
75-01-4 Vinyl chloride
m.p-Xylene
~)5-47-G o-Xylene
CAS No. Surrogate Recoveries
18G8-53-7 Dibromofluoromethane
17060-07-0 1 ,2-Dichlorocthane-D4
2037-26-5 Toluene-DB
460-00-4 4-Bromofluorobenzene
• "" Outside of Control Limits.
Spike BSP BSP
ug/1 ug/1 %
10 10.1 101
10 12.4 1211
I 0 12.5 125
10 10.4 104
10 12.0 120
10 10.4 104
10 9 7 97
10 10.6 JOG
10 10.2 102
10 10.5 105
10 10.5 105
10 11.5 115
10 11.6 JIG
HI 10.3 I {)3
10 11.6 JIG
10 10.0 100
10 10.6 JOG
10 10.4 104
10 II G 11 G
10 11.8 118
10 10.5 105
10 12 .I 121
10 12.2 122
20 21.8 109
10 10.4 104
BSP Limits
101% 70-J:lO%
99% 70-130%
100% 70-130%
101% 70-130%
Limits
70-130
60-140
60-140
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
60-140
60-140
70-130
70-130
JI[J 38 of 44 II ACCUTEST.
F94517
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of2
Job Number: F94517
Account: GRINCC GRI (Geological Resources Inc.)
Project: Ram #5; 101 W jefferson St (llwy 158}, jackson, ;-.;c
Sample File lD DF Analyzed By Prep Date Prep Batch Analytical Batch
F9~516-4MS E017606.D 200 07/06/12 Til n/• n/• VEG25
F945IG-4MSD £017607.0 200 07/06/12 Til n/a n/• VE625 "' w F94516-4 £017603.0 200 07/06/12 TO n/, n/a VE625 ~
The QC reported here applies to the following samples: Method: SM GZOOB I
F94517-l, F945l7-2, F94517-3, F94517-4. F94517-5, F94517-6, F94517-7, F94517-8
F94516-4 Spike MS MS MSD MSD Limits
CAS No. Compound ug/1 Q ug/1 ug/1 % ug/1 % RPD RodRPD
71-43-2 Benzene 4380 2000 6600 Ill 6480 105 2 70-130/20
108-RG-1 Bromobenzene XD 2000 1780 89 1770 89 I 70-130/20
74-97-5 Bromochloromethane XD 2000 1950 98 1940 97 I 70-130/20
75-27-4 Bromodichloromethane :\'0 2000 1700 85 1680 84 I 70-130/20
75-25-2 Bromoform :\'0 2000 1400 70 1360 68. 3 70-130/20
104-51-8 n-Butylbenzene 24.2 J 2000 1880 93 1870 92 I 70-130/20
135-98-8 sec-Butylbenzene ;"\TO 2000 1860 93 1830 92 2 70-130/20
98·06-6 tert-Butylbenzene \TO 2000 1800 90 1780 89 I 70-130/20
108-90-7 Chlorol.wnzene NO 2000 2020 101 1990 100 I 70-130/2.0
75-00·3 Chloroethane ND 2000 2130 107 2030 102 5 G0-140/20
G7-GG·3 Chloroform 63 2 JB 2000 1940 94 1910 92 2 70-130/20
95-48·8 o-Chlorotolueoe ND 2000 1940 97 1900 95 2 70-J:lO/lO
IOH-tl:l-4 p-Chlorotoluene ND 2000 1800 90 1760 88 2 70-!;!0/20
JG-23-5 Carbon tetrachloride ND 2000 1990 100 1940 97 3 70-J:I0/20
75-34-3 1.1-Dichloroethane NO 2000 2030 102· 1990 100 2 70-130/20
75-35-4 1, 1-Dich1oroethy1ene XO 2000 1830 92 1780 89 3 70-130/20
563-58-G I ,1-0ichloropropene XO 2000 1800 90 1770 89 2 70-130/20
96-12-8 1 ,2-Dibromo-3-chloropropane :\'0 2000 1730 87 1690 S5 2 70-130/20
106-93-4 1 ,2-Dibromoethane XO 2000 1710 86 1670 84 2 70-130/20
107-06-2 1,2-Dichloroethane XD 2000 1990 100 1960 98 2 70-130/20
78-87-5 1 ,2-Dichloropropane XO 2000 1780 89 1780 89 0 70-130/20
142-28-9 1,3-Dich!oropropane :\D 2000 1770 89 1750 88 I 70-130/20
108-20-3 Oi-Isopropy1 ether :\'0 :woo 1800 90 1800 90 0 70-130/20
594-20-7 2 ,2-Dichloropropane ?\0 2000 2070 104 1960 98 5 70-130/20
124-48-1 Oibromochloromethalle XO 2000 1550 78 1550 78 0 70-130/20
75-71-8 Oichlorodifluoromethane I\'0 2000 1960 98 1880 94 4 G0-140/20
156-59-2 cis-! , 2-Dichloroethylene i\'D 2000 1760 88 1730 87 2 70-130/20
IOOGl-01-5 cis-! ,3-Dichloropropene l\'0 2000 1700 85 1700 85 0 70-130/20
S41-73-l m-Dichlorobenzene i\'D 2000 1780 89 I 760 88 I 70-130/20
95-50-1 a-Dichlorobenzene \'D 2000 1770 89 17;)0 88 I 70-130120
106-46-7 p-Dichlorobenzene I\'0 2000 1820 91 1790 90 2 70-130/20
15G-G0-5 trans-] ,2-Dich1oroethylene XO 2000 1830 92 1800 90 2 70-130/20
10061-02-6 lrans-1,3-0ichloropropene KD 2000 1750 88 1720 86 2 70-1 :.;o120
100-41-4 Ethylbenzene 2240 2000 4440 110 4340 105 2 70-130/20
87-G8·3 IIcxachlorobutadiene KD 2000 1740 87 1780 89 2 70-13(1/20
!!8-82-8 lsopropylbenzene 89.4 J 2000 1870 89 1850 88 I 70-130/20
* = Outside of Control Limits.
fil[] 39 of 44
.ACCUTEST.
H-4517 ·····-······
Matrix Spike/Matrix Spike Duplicate Summary Pag~2of2
Job Number: F94517
Account: GRII\'CC GRI (Geological Resources Inc.)
Project: Ram #5; 101 \\'jefferson St (llwy 158), jackson, ~C
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
F94516-4~1S E017606.D 200 07/06112 TO nla n/a VE625
F94516-4:-..ISD E017607.D 200 07/06/12 TO nla "'' VE625 "' F9·1516-4 E017603.D 200 07/06/12 TD "'' "'' VE625 "' ~
The QC reported here applies to the follov.ing samples: Method: SM !l200B ~ '
F94517-l, F94517-2, F94517-3, F94517-4. F94517-5, F94517-6, F94517-7, F94517-8
F94516-4 Spike
CAS No. Compound ug/1 Q ug/1
99-87-6 p-lsopropyltoluene l\'D 2000
74-83-!l Methyl bromide ND 2000
74-87-3 Methyl chloride ND 2000
74-95-3 Methylene bromide ND 2000
7:i-09-2 Methylene chloride 271 J 2000
1634-04-·1 Methyl Tcrt Butyl Ether 377 2000
91-20-3 Naphthalene 3I6 2000
103-65-1 n-Propylbenzcne 299 2000
I 00-42-5 Styrene ?\'0 2000
630-20-6 1,1,1 ,2-Tetrachloroethane ::\'0 2000
71-55-6 1.1,1-Trichloroethane l\'0 2000
79-34-5 1.1 ,2, 2-Tetrachloroethane l\'0 2000
79-00-5 1,1,2-Trichloroethane \'0 2000
87-61-6 1.2,3-Trichlorobenzene ND 2000
96-18-4 1,2, 3-Trichloropropane ?\'0 2000
120-82-1 1.2,4-Trichlorobenzene ?\'0 2000
95-63-6 1.2, 4-Trimethylbenzene 2130 2000
108-67-8 1,3,5-Trimrthylbenzenc 517 2000
127-18-4 T ctrachlorol~thylene !\0 2000
108-88-3 Toluene 13200 E 2000
79-01-6 Trichloroethylene ?\"0 2000
75-69-4 Trich1orofluoromethane \"0 2000
75-01-4 Vinyl chloride \"0 2000
m.p-Xylcne 6940 4000
95-47-6 a-Xylene 2820 2000
CAS No. Surrogate Recoveries MS MSD
ISGB-53-7 Dibromofluoromethane 101% 101%
17060-07-0 I ,2-Dichlor~Jethanc-D4 102% 100%
2037-26-5 Toluene-DB 100% 101%
460-00-4 4-Brom on uorobenzene 101% 100%
• = Outside of Control Limits.
MS MS MSD
ug/1 % ug/1
1790 90 1780
2470 121 2340
2030 102 1[)40
1770 89 1720
2170 95 21fl0
2180 90 2150
2ll0 90 2110
2200 95 2170
1690 85 1670
1740 87 1700
1810 91 1760
1990 100 1910
1960 98 1940
1700 85 1790
1940 97 1870
1660 83 1700
-liDO 99 4060
2420 95 2390
2060 103 2000
15200 IOO 14800
1800 90 1760
2110 106 2000
2100 105 1970
10800 97 10600
4810 100 4740
F94516-4 Limits
101% 70-130%
104% 70-130%
103% 70-130%
102% 70-130%
MSD
%
89
117
!17
RG
D5
R~l
90
94
84
85
88
96
97
90
94
85
97
94
100
80
88
100
99
92
96
Limits
RPD RodRPD
" " :;
0
I
II
I
I
2
3
4
I
5
4
2
I
3
3
2
5
6
2
70-130/20
60-110/20
G0-140/20
70-130/20
70-130/20
70-130/20
70-130/20
70-130/20
70-130/20
70-130/20
70-130/20
70-130/20
70-130/20
70-130/20
70-130/20
70-130/20
70-130/20
70-130/20
70-130/20
70-130/20
70-130/20
60-140/20
60-140/20
70-130/20
70-130120
BIJ 40 of 44
UACCUTEST.
F~SH
I!IQ ... Southeast
• ACCUTI'$81':
:L~A!Bo"RATo"Rlt::S
GC Volatiles
QC Data Summaries
Includes the following where applicable:
\'lethod Hlank Summarie~
Blank Spike Summaries
Matrix Spike and Duplicate Summaries
Section 6
liD 41 of 44 Iii ACCUTEST.
F94517
•
Method Blank Summary
Job Number: F94517
Account: GRINCC GH:l (Geological Resouret~~ Inc.)
Project: Ram #5; 101 W jefferson S1 {Hwy 158}, jackson, ?'\C
Sample
GUV3011-MB
File ID DF
UV054286.D 1
Analyzed By
07/10/12 MM
The QC reported here applies to the follo-...ing samples:
Prep Date
n/,
Pagel of!
Prep Batch Analytical Batch
n/a CUV3011
Method: l\1ADEI' VPI-! REV 1.1
F94517-l. F94517-2. F94517-3, F94517-4, F94517-5. F94517-6, F94517-7, F94517-8
CAS No. Compound Result
CS-CS A!iphatics (Unadj.) NO
C9-CIZ Aliphatics {Unarlj.) !\D
C9-C!O Aromatics (Unadj.) :\D
CAS No. Surrogate Recoveries
460-00-4 BFB 100%
460-00-4 HFB 100%
RL MDL
100 35
100 35
100 35
Limits
70-130%
70-130%
Units Q
ug/1
ug/1
ug/1
110 42 of 44 til ACCUTE:ST.
F94517
·•
Blank Spike/Blank Spike Duplicate Summary
Job Number: F94517
Account: GRINCC GRI (Geological Re.~ources Inc.)
Project: Ram #5; 101 W Jefferson St (!Iv.y 158), jackson, :\'C
Sample File ID OF Analyzed By
GUV3011-BS UV054277.Dl 07/10/12 MM
GUV3011-BSD U\'054278.0 I 07/10/12 !\1M
The QC reported here applies to the following samples:
Prep Date
'"' n/a
Pagel of!
Prep Batch Analytical Batch
n/a GUV30Jl
n/~ GUV3011
Method: l'v1ADEP VPJ-l REV 1.1
F9,1517-I, F9•l517-2. F91517-3. F94517-4, F94517-5, F94517-6, F94517-7, F9-1517-8
Spike BSP BSP
CAS No. Compound ug/1 ug/1 %
CS-C8 Aliphatics (Unadj.} 480 480 100
C9-CIZ Aliphatics (Unadj.) 640 651 102
C9-CIO Aromatics (Unadj.) 240 242 101
CAS No. Surrogate Recoveries BSP BSD
460-00-4 BFB 114% Ill%
460-00-4 BFB 110% 101%
• = Outside of Control Limits.
BSD BSD
ug/1 %
493 103
612 96
230 96
Limits
70-130%
70-130%
RPD
. 3
6
5
Limits
Roo/RPD
70-130/25
70-130/25
70-130/25
m:c 43 of 44 II ACCUTEST.
F~517
r ..
Matrix Spike/Matrix Spike Duplicate Summary
JobNumber: F94517
Account: GRINCC GRI (Geological Resources Inc.)
Project: Ram #5: 101 \V jefferson St {Hwy ISS). jackson, i\"C
Sample
FD4540-3lvlS
F94540-31'11SD
F94540-3
File lD OF
U\1054305.0 1
UV054306.D I
U\1054304. D 1
Analyzed By
07/11/12 MM
07/11/12 MM
07/11112 Ml\1
The QC reported here applies to the following samples:
Prep Date
n/e
n/a
n/a
-·
Page I of I
Prep Batch Analytical Batch
n/a GU\'3011
n/a GU\13011
n/a GU\'3011
Method: ldADEP VPH REV 1.1
F94517-l. F94517-2, F94517-3, F94517-4, F94517-5, F94517-6 F94517-7. F94517-8
F94540-3 Spike MS
CAS No. Compound ug/1 Q ug/1 ug/1
CS-C8 Aliphatics {Unadj.) 95.3 J 480 580
C9-CJ2 Aliphatics (Unadj.} KD 640 618
C9-C!O Aromatics (Unadj.) 65.8 J 140 330
CAS No. Surrogate Recoveries MS MSD
4G0-00-4 BFB 109% 109%
4G0-00-4 BFB 105% 102%
* = Outside of Control LimiLS.
MS MSD
% ug/1
101 614
07 644
110 186
F94540-3 Limits
84% 70-130%
85% 70-130%
MSD
%
108
!OJ
02
Limits
RPD Roo/RPD
6
4
14
70-130/50
70-130/50
70-130/50
IIIJ 44 of 44 II ACCUTEST.
· F94517