MO-28945_48148_CA_IAR_20211215_Initial Abatement Action Report

INITIAL ABATEMENT ACTION REPORT
December 15, 2021

Site Name: Buttery & Beanery
Site Address: 1653 Mecklenburg Highway
Mooresville, Iredell County, North Carolina 28115

Facility I.D.: 00-0-0000024532 UST Incident Number (if known): NA
Latitude: 35.534601° North Longitude: 80.846361° West
Source: Google Earth

UST Owner: Estate of Linda Holthouser UST Operator: Buttery and Beanery
Address: 1653 Mecklenburg Highway Address 1653 Mecklenburg Highway
Mooresville, North Carolina 28115 Mooresville, North Carolina 28115
Telephone [phone] Telephone [phone]

Property Property
Owner: Estate of Linda Holthouser Occupant: Unoccupied –
Address: 1653 Mecklenburg Highway Address 1653 Mecklenburg Highway
Mooresville, North Carolina 28115 Mooresville, North Carolina
Telephone: Telephone [phone] Telephone: Not Applicable

Consultant: ATC Associates of North Carolina, P.C.
Address: 7606 Whitehall Executive Center Dr, Ste 800, Charlotte, NC 28273
Telephone [phone]

Analytical
Laboratory: Pace Analytical Services, LLC State Certification No. 5342
Address: 9800 Kincey Avenue, Suite 100, Huntersville, NC 28078
Telephone [phone]

Release Information
Date Discovered: 12/3/2021
Estimated Quantity of Release: Unknown
Cause of Release: Unknown
UST Information: Two 6,000-gallon gasoline UST, one 550-gallon Kerosene UST, two 1,000-gallon
orphan gasoline USTs.

I, Michael David Shaw, a Licensed Geologist for
ATC Associates of North Carolina, P.C., do certify
that the information contained in this report is correct
and accurate to the best of my knowledge.

ATC Associates of North Carolina, P.C. is licensed to
practice engineering in North Carolina. The
certification number of the company is C-1598.
TABLE OF CONTENTS

1.0 SITE HISTORY AND CHARACTERIZATION ...................................................................................... 1
1.1 UST OWNER AND OPERATOR INFORMATION ................................................................................ 1
1.2 UST INFORMATION ................................................................................................................................ 1
1.3 AST INFORMATION ................................................................................................................................ 2
1.4 RELEASE INFORMATION ...................................................................................................................... 2
1.5 SITE CHARACTERISTICS ...................................................................................................................... 2
1.5.1 Site Status ........................................................................................................................................... 2
1.5.2 Surrounding Property Use .................................................................................................................. 2
1.5.3 Site Geology/Hydrogeology ............................................................................................................... 2
1.5.4 Receptor Survey ................................................................................................................................. 2
1.6 INITIAL ABATEMENT ACTIONS .......................................................................................................... 2
2.0 SITE CHECK REPORT .............................................................................................................................. 2
2.1 TIGHTNESS TESTING ............................................................................................................................. 2
2.2 SITE CHECK PROCEDURES .................................................................................................................. 2
2.3 INITIAL RESPONSE ACTIONS .............................................................................................................. 2
2.3.1 Notifications ....................................................................................................................................... 3
2.3.2 Residual Material ................................................................................................................................ 3
2.3.3 Source Control Actions ...................................................................................................................... 3
2.3.4 Contaminant Migration Control Measures ......................................................................................... 3
2.3.5 Measures to Identify and Mitigate Hazards ........................................................................................ 3
2.3.6 Contaminated Soil Storage, Treatment, and/or Disposal .................................................................... 3
2.3.7 Groundwater Assessment ................................................................................................................... 3
2.3.8 Free Product Assessment and Removal .............................................................................................. 3
2.4 SOIL EXCAVATION ACTIVITIES ......................................................................................................... 3
2.5 SITE INVESTIGATION ............................................................................................................................ 3
3.0 UST CLOSURE REPORT .......................................................................................................................... 4
3.1 CLOSURE PREPARATION ..................................................................................................................... 4
3.2 CLOSURE PROCEDURES ....................................................................................................................... 4
3.3 CLOSURE SAMPLES ............................................................................................................................... 4
3.4 SOIL EXCAVATION ACTIVITIES ......................................................................................................... 4
3.5 SITE INVESTIGATION ............................................................................................................................ 4
4.0 OVER EXCAVATION ACTIVITIES ........................................................................................................ 4
5.0 GROUNDWATER ASSESSMENT ACTIVITIES ................................................................................... 5
6.0 CONCLUSIONS AND RECOMMENDATIONS ..................................................................................... 5
7.0 LIMITATIONS............................................................................................................................................. 5

TABLES
Table 3 UST Closure Analytical Results – Total Petroleum Hydrocarbons

FIGURES
Figure 1 Topographic Map
Figure 2 Sample Location Map

APPENDICES
Appendix A UST Notification Forms
Appendix B Liquid and UST Disposal Manifests
Appendix C Laboratory Report

1

INITIAL ABATEMENT ACTION REPORT

FOR

Buttery and Beanery
1653 Mecklenburg Highway
Mooresville, Iredell County, North Carolina

ATC Associates of North Carolina, P.C. (ATC) has prepared the following report for the Estate of Linda
Holthouser, detailing underground storage tank (UST) closure and initial abatement activities performed
at the Buttery and Beanery facility located at 1653 Mecklenburg Highway Mooresville, Iredell County,
North Carolina. This report has been prepared pursuant to applicable sections of Title 15A of the North
Carolina Administrative Code (NCAC), Chapter 2, Subchapter 2L and in accordance with the State of
North Carolina Department of Environmental Quality (NCDEQ), Division of Waste Management
(DWM), Underground Storage Tank (UST) Section Guidelines for Site Checks, Tank Closure, and Initial
Response and Abatement, effective January 19, 2021.

1.0 SITE HISTORY AND CHARACTERIZATION

1.1 UST OWNER AND OPERATOR INFORMATION
Two 6,000-gallon gasoline USTs, one 550-gallon kerosene UST, and two orphan 1,000-gallon gasoline
USTs were removed from the referenced facility on November 22 and 23, 2021. The USTs, product
lines/piping, and dispensers were owned by The Estate of Linda Holthouser of Mooresville, North
Carolina. Information regarding each of the tanks is provided below.
1.2 UST INFORMATION
UST
ID PRODUCT CAPACITY
(gals.) MATERIALS INSTALL
DATE
UST
STATUS

RELEASE
ASSOCIATED
(Yes/No)

1 Gasoline
(Premium) 6,000 UST: Steel;
Piping: Steel 2000 Removed Yes
2 Gasoline
(Premium) 6,000 UST: Steel;
Piping: Steel 2000 Removed No
3 Kerosene 550 UST: Steel;
Piping: Steel 2000 Removed No
4 Gasoline 1,000 UST: Steel;
Piping: Steel Unknown Removed No
5 Gasoline 1,000 UST: Steel;
Piping: Steel Unknown Removed No

Figure 1 is a topographical map of the site and surrounding area. Figure 2 depicts the site and pertinent
structures, including approximate locations of the USTs, product lines/piping, and dispensers.
Initial Abatement Action Report ATC Associates of North Carolina, P.C.
Circle K Store #2723470 June 29, 2021

2

1.3 AST INFORMATION
No aboveground storage tanks (ASTs) were identified on the property.
1.4 RELEASE INFORMATION
During closure activities, soil samples were collected from the bottom of the UST basin along the
sidewalls, along the product lines, and at the dispenser islands. Laboratory analytical results did indicated
soil impacted above State Action Levels for Total Petroleum Hydrocarbons (TPH)-Diesel Range Organics
(DRO) and Total Petroleum Hydrocarbons (TPH)-Gasoline Range Organics (GRO). A 24-Hour Release
and UST Leak Reporting Form was submitted to NCDEQ on December 3, 2021.
1.5 SITE CHARACTERISTICS
1.5.1 Site Status
The former Buttery and Beanery facility is vacant. The USTs, product lines/piping, and dispensers have
been removed from the facility. Surface cover at the site consists of asphalt, and gravel.
1.5.2 Surrounding Property Use
Properties surrounding the subject facility are primarily commercial and residential. The zoning status of
the subject facility is commercial. The surrounding area is zoned commercial and residential.
1.5.3 Site Geology/Hydrogeology
Based on observations made during UST closure activities, the soil profile consisted of red-brown silty
clay. Groundwater was not encountered during the excavation activities, which extended to a depth of
approximately 10 feet below ground surface (ft-bgs) in the area of the UST basin.
1.5.4 Receptor Survey
During closure activities, ATC did observed evidence of potential water supply wells within 1,500 feet of
the source area. The site and surrounding properties appear to be connected to the public water system
and private wells.
1.6 INITIAL ABATEMENT ACTIONS
Refer to Section 2.3 in regard to information regarding this site.
2.0 SITE CHECK REPORT

2.1 TIGHTNESS TESTING
Information regarding tightness testing is not currently available.
2.2 SITE CHECK PROCEDURES
Upon closure of the USTs, thirteen soil samples were obtained to document environmental conditions of
soil from the UST basin, along the product lines, and beneath each dispenser. Soil samples were submitted
for analysis by TPH – GRO and/or DRO, depending on sampling location.

Initial Abatement Action Report ATC Associates of North Carolina, P.C.
Circle K Store #2723470 June 29, 2021

3

2.3 INITIAL RESPONSE ACTIONS
2.3.1 Notifications
A UST-3 Notice of Intent: UST Permanent Closure or Change In-Service was submitted to NCDEQ by
ATC personnel on May 24, 2021. A UST-2A Site Investigation Report for Permanent Closure or Change-
in-Service of REGISTERED UST was submitted to NCDEQ by ATC personnel on December 16, 2021. A
UST-61 24-Hour Release and UST Leak Reporting Form was submitted to NCDEQ by ATC personnel
on December 3, 2021. Copies of the referenced correspondence are presented in Appendix A.
2.3.2 Residual Material
Residual product was removed from the USTs when they were taken out of service, prior to these removal
activities. The interior of the USTs were pressure washed to remove product residue remaining in the
tanks. Approximately 390 gallons of rinse water and product residue were generated from pressure
washing the interior of the USTs. The rinse water was removed from the USTs via vacuum truck. Copies
of the liquid manifest is included as Appendix B.
2.3.3 Source Control Actions
Additional source control actions did not appear warranted at the time of site activities.
2.3.4 Contaminant Migration Control Measures
Additional contaminant migration control measures were not utilized.
2.3.5 Measures to Identify and Mitigate Hazards
ATC field personnel did not observe evidence of hazards during UST closure activities.
2.3.6 Contaminated Soil Storage, Treatment, and/or Disposal
During UST removal activities, petroleum-impacted soil was identified in the vicinity of the UST basin.
Only soil required to remove the USTs was removed from the excavation. 39.54-tons of impacted soil
removed during the UST excavation was disposed of off-site by Zebra Environmental. Additional soil
excavation was not completed due to the proximity of the on-site building to the UST bed.
2.3.7 Groundwater Assessment
Groundwater was not encountered during the UST removal activities.
2.3.8 Free Product Assessment and Removal
Evidence of free product was not observed on the soils in the UST basins; thus, free product removal
activities were not warranted.
2.4 SOIL EXCAVATION ACTIVITIES
During UST removal activities, clean overburden was stockpiled on-site. Impacted soil was removed from
the site.
2.5 SITE INVESTIGATION
Refer to Sections 3.0, 4.0, and 5.0 for information on assessment activities.
Initial Abatement Action Report ATC Associates of North Carolina, P.C.
Circle K Store #2723470 June 29, 2021

4

3.0 UST CLOSURE REPORT
3.1 CLOSURE PREPARATION
A UST-3 form was filed with the NCDEQ Mooresville Regional Office by ATC personnel on November
2, 2021. Zebra Environmental personnel were responsible for obtaining any permits for the closure of the
tanks, contacting the local fire department, and having utilities on the area properly located.
3.2 CLOSURE PROCEDURES
Prior to the closure of the USTs, residual fuel had been pumped out of the tanks when they were taken out
of service. Upon removal from the ground, the USTs were noted to be in good condition. The USTs were
transported off-site for disposal. A copy of the tank disposal manifest is included in Appendix B.
3.3 CLOSURE SAMPLES
Thirteen soil samples were collected from the UST excavation, fuel dispensers, along the product line
piping in approximate 10-foot intervals, and at any observed connection points. Soil samples collected
from the UST excavations, product line piping, and fuel dispensers were taken directly from the bucket of
the excavator. All samples were collected utilizing new disposable nitrile gloves during to reduce the
overall risk of cross contamination. Soil samples were placed into sealable Zip-loc® bags with the required
volume for laboratory analysis being placed in laboratory provided bottle-ware. The remaining sample
was allowed time for vapor stabilization at which point the head-space was screened for the presence of
volatile organic vapors (VOCs) using a photoionization detector (PID).

Samples T-1-A through T-3-B were collected from the UST basins, from a depth of approximately 6 to
10 ft-bgs. Soil samples D-1-A through D-2-B, L-1 and L-2 were collected from beneath piping or
dispensers, from a depth of approximately 2-5 ft-bgs. Soil samples were preserved and packed into
approved sample containers, stored in a chilled cooler, and submitted to North Carolina certified Pace
Analytical Laboratories, in Huntersville, North Carolina. Soil samples were submitted for analysis by
TPH – GRO and/or DRO, depending on sampling location. The locations of the UST system soil samples
and select analytical results are provided in Figure 2.

Laboratory analytical results did detected the presence of TPH-DRO or TPH-GRO above the NCDEQ
Action Level of 50 and 100 milligrams per kilogram (mg/kg) in five of the soil samples collected. Table
3 provides a summary of the laboratory results for the TPH analytical results.

A copy of the laboratory report is included in Appendix C.
3.4 SOIL EXCAVATION ACTIVITIES
Potentially impacted soil was not excavated from the site due to the proximity of the building at the site.
3.5 SITE INVESTIGATION
Additional site investigation activities were not conducted as part of the UST closure.
4.0 OVER EXCAVATION ACTIVITIES
Over excavation, activities were not conducted as part of the UST closure.
Initial Abatement Action Report ATC Associates of North Carolina, P.C.
Circle K Store #2723470 June 29, 2021

5

5.0 GROUNDWATER ASSESSMENT ACTIVITIES
Groundwater was not encountered during the UST removal activities.
6.0 CONCLUSIONS AND RECOMMENDATIONS
ATC prepared an Initial Abatement Action Report for a UST closure Based on the information obtained
during UST closure activities at the Buttery and Beanery facility located at 1653 Mecklenburg Highway,
Mooresville in Iredell County, North Carolina. ATC offers the following conclusions:
 Two 6,000-gallon gasoline USTs, one 550-gallon kerosene UST, two 1,000 gallon orphan gasoline
USTs were removed from the referenced facility November 22-23, 2021. ASTs were not identified
on the property.

 The subject property and surrounding properties are primarily commercial and residential. The site
and surrounding properties appear connected to the public water system and also are supplied
water by private wells.

 Approximately 390 gallons of rinse water and product residue were removed from the USTs via
vacuum truck.

 Thirteen soil samples were collected from the bottom of the UST basin, below fuel dispensers, and
along the product line piping. Soil samples were submitted for laboratory analysis by EPA Method
8015C for TPH-GRO and/or TPH-DRO as applicable.

 Groundwater was not encountered during the UST removal activities.

 The concentration of TPH-DRO and TPH GRO were detected in soil samples gathered from the
site.

Based on the information obtained during these activities, additional assessment may be warranted.
7.0 LIMITATIONS
This report has been prepared for the exclusive use of The Estate of Linda Holthouser. The opinions
included herein are based on information obtained during the study, on our experience in accordance with
currently accepted hydrogeological and engineering practices, and relevant regulatory guidelines at this
time and location. Other than this, no warranty is implied or intended.

TABLE
Table 3: Soil Analytical Data
Buttery Beanery
1653 Mecklenburg Highway
Mooresville, North Carolina
Sample ID #Collection
Date
Depth
(ft BGS)
TPH-GRO
(mg/kg)
TPH-DRO
(mg/kg)
PID
Reading
(ppm)
T-1-A 11/23/21 10 48,900 1,000 758
T-1-B 11/23/21 10 2,080 148 364
T-2-A 11/23/21 10 <9.5 NA 0.0
T-2-B 11/23/21 10 <8.5 NA 0.0
T-3-A 11/23/21 6 <10.6 <6.7 0.0
T-3-B 11/23/21 6 <9.4 <6.1 0.0
D-1-A 11/22/21 5 2,870 NA 546
D-1-B 11/22/21 5 2,210 NA 345
D-2-A 11/23/21 5 56.1 NA 15.0
D-2-B 11/23/21 5 <8.7 NA 0.0
D-3-A 11/23/21 2 <9.0 21.3 0.0
L-1 11/23/21 2 <7.9 NA 0.0
L-2 11/23/21 2 <7.4 NA 0.0
50 100 --
NOTES:
BGS - Below Ground Surface
GRO - Gasoline Range Organics
PID - Photoionization Detector
ppm - parts per million
NCDEQ ACTION LEVEL

FIGURES
7606 Whitehall Executive Center Drive, Suite 800
Charlotte, North Carolina 28273
[phone]
FIGURE 1. Site Location
Buttery and Beanery
1653 Mecklenburg Hwy
Mooresville, NCSOURCE: Google Earth
Note: Locations will be adjusted as necessary based on field conditions.
Site
7606 Whitehall Executive Center Drive, Suite 800
Charlotte, North Carolina 28273
[phone]
FIGURE 2. Sample Locations
Buttery and Beanery
1653 Mecklenburg Hwy
Mooresville, NCSOURCE: Google Earth
Note: Locations will be adjusted as necessary based on field conditions.

APPENDIX A

UST NOTIFICATION FORMS
Buttery & Beanery
1653 Mecklenburg Hwy
Mooresville Iredell
NC 28115
704-892-0263
Buttery & Beanery
0-000024532
1653 Mecklenburg Hwy
Mooresville Iredell 28115
704-892-0263
Kathy Holthouser Executor 704-892-0263
Jeremy DeVore Zebra 336-628-8267High Point
Michael D. Shaw, P.G.ATC Associates of NC Charlotte 704-578-5974
X X16,000 96"x15'Gasoline11/22/21 11/22/21
2 6,000 92"x17'Gasoline 11/22/21 11/22/21 X X
3 550 46"x6'Kerosene 11/22/2111/22/21 X X
X
X
X
4 1,000 48:x12'Gasoline Pre-1984 11/22/21 X X X
5 1,000 48"x12'Gasoline Pre-1984 11/22/21 X X X
Michael D. Shaw, P.G. Sr. Program Manager, ATC 11/22/21
UST-3 Notice of Intent: UST Permanent Closure or Change-in-Service
Return completed form to:
The DWM Regional Office located in the area where the facility is located. Also send a copy to the Central Office in Raleigh.
SEE MAP ON THE BACK OF THIS FORM FOR THE CENTRAL AND REGIONAL OFFICE ADDRESSES.
STATE USE ONLY
I.D. #_____________________
Date Received______________
INSTRUCTIONS (READ THIS FIRST)
Complete and return a UST-3 form at least thirty (30) days prior to closure or change-in-service activities. If a Professional Engineer (P.E.) or a Licensed
Geologist (L.G.) provides supervision for closure or change-in-service site assessment activities and signs and seals all closure reports then at least a five
(5) working days’notice is acceptable.
Completed UST closure or change-in-service site assessment reports, along with a copy of the UST-2A and/or 2B forms, should be submitted to the
appropriate Division of Waste Management (DWM) Regional Office within thirty (30) days following closure activities. The UST-2 form should also be
submitted to the Central Office in Raleigh so that the status of the tanks may be changed to permanently closed and your tank fee account can be closed out.
Note: Tank fees may be due for unregistered tanks.
UST closure and change-in-service site assessments must be completed in accordance with the latest version of the Guidelines for Site Checks, Tank Closure
and Initial Response. The guidelines can be obtained at https://deq.nc.gov/about/divisions/waste-management/ust. Note: To close tanks in place you must
obtain prior approval from the DWM Regional office located in the region where the facility is located.
You must make sure that USTs removed from your property are disposed of properly. When choosing a closure contractor, ask where the tank(s) will be
taken for disposal. Usually, USTs are cleaned and cut up for scrap metal. This is dangerous work and must be performed by a qualified company. Tanks
disposed of illegally in fields or other dumpsites can leak petroleum products and sludge into the environment. If your tanks are disposed of improperly, you
could be held responsible for the cleanup of any environmental damage that occurs.
I. OWNERSHIP OF TANKS II. LOCATION
Owner Name (Corporation, Individual, Public Agency, or Other Entity) Facility Name or Company
Street Address Facility ID # (If known)
City County Street Address
State Zip Code City County Zip Code
Phone Number Email Phone Number
III. CONTACT PERSONNEL
Name:Company Name:Job Title: Phone Number:
IV. TANK REMOVAL, CLOSURE IN PLACE, CHANGE-IN SERVICE
1.Contact local fire marshal.
2.Plan entire closure event.
3.Conduct Site Soil Assessment.
4.If removing tanks or closing in place, refer to
API Publication 2015 Cleaning Petroleum
Storage Tanks and 1604 Removal and
Disposal of Used Underground Petroleum
Storage Tanks.
5.Provide a sketch locating piping, tanks and
soil sampling locations.
6.Submit a closure report in the format of UST-
12 (including the form UST-2) within thirty
(30) days following the site investigation.
7.If a release from the tanks has occurred, the
site assessment portion of the tank closure
must be conducted under the supervision of
a P.E. or L.G., with all closure site assessment
reports bearing the signature and seal of the
P.E. or L.G. If a release has not occurred, the
supervision, signature or seal of a P.E. or L.G.
is not required.
8.Keep closure records for three (3) years.
V. WORK TO BE PERFORMED BY
Contractor Name:Contractor Company Name:
Address:State: Zip Code:Phone No:
Primary Consultant Name:Primary Consultant Company Name:Consultant Phone No:
VI. TANKS SCHEDULED FOR CLOSURE OR CHANGE-IN-SERVICE
Tank ID No.Size in Gallons Last Contents
Proposed Activity
Closure Change-In-Service
Removal Abandonment in Place *New Contents Stored
*Prior written approval to abandon a tank in place must be received from a DWM Regional Office.
VII.OWNEROROWNER’SAUTHORIZEDREPRESENTATIVE
Has a release from a UST system occurred at this location? Yes No Unknown
I understand that I can be held responsible for environmental damage resulting from the improper disposal of my USTs.
Print name and official title:
Signature Date Signed SCHEDULED REMOVAL DATE Notify your DWM Regional Office
48 hours before this date if
scheduled removal date changes
UST-3 Rev 3/2020
NC Iredell
NC

APPENDIX B

LIQUID AND UST DISPOSAL MANIFESTS

APPENDIX C

LABORATORY REPORT

#=CL#
December 01, 2021
LIMS USE: FR - MICHAEL SHAW
LIMS OBJECT ID: 92574121
92574121
Project:
Pace Project No.:
RE:
Michael Shaw
ATC Group Services LLC
7606 Whitehall Executive Cente
Suite 800
Charlotte, NC 28273
BUTTERY & BEANERY
Dear Michael Shaw:
Enclosed are the analytical results for sample(s) received by the laboratory on November 23, 2021. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Bonnie Vang
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 30
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 30
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Lab ID Sample ID Matrix Date Collected Date Received
92574121001 T-1 A Solid 11/23/21 09:10 11/23/21 13:30
92574121002 T-1 B Solid 11/23/21 09:15 11/23/21 13:30
92574121003 T-3 A Solid 11/23/21 09:00 11/23/21 13:30
92574121004 T-3 B Solid 11/23/21 09:05 11/23/21 13:30
92574121005 D-3 A Solid 11/23/21 09:40 11/23/21 13:30
92574121006 T-2 A Solid 11/23/21 09:20 11/23/21 13:30
92574121007 T-2 B Solid 11/23/21 09:25 11/23/21 13:30
92574121008 D-1 A Solid 11/22/21 16:00 11/23/21 13:30
92574121009 D-1 B Solid 11/22/21 16:05 11/23/21 13:30
92574121010 D-2 A Solid 11/23/21 09:30 11/23/21 13:30
92574121011 D-2 B Solid 11/23/21 09:35 11/23/21 13:30
92574121012 L-1 Solid 11/23/21 09:45 11/23/21 13:30
92574121013 L-2 Solid 11/23/21 10:50 11/23/21 13:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 30
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92574121001 T-1 A EPA 8015C 2 PASI-CAP2
EPA 8015C 2 PASI-CMAD
SW-846 1 PASI-CKDF
92574121002 T-1 B EPA 8015C 2 PASI-CHH
EPA 8015C 2 PASI-CMAD
SW-846 1 PASI-CKDF
92574121003 T-3 A EPA 8015C 2 PASI-CHH
EPA 8015C 2 PASI-CMAD
SW-846 1 PASI-CKDF
92574121004 T-3 B EPA 8015C 2 PASI-CHH
EPA 8015C 2 PASI-CMAD
SW-846 1 PASI-CKDF
92574121005 D-3 A EPA 8015C 2 PASI-CHH
EPA 8015C 2 PASI-CMAD
SW-846 1 PASI-CKDF
92574121006 T-2 A EPA 8015C 2 PASI-CMAD
SW-846 1 PASI-CKDF
92574121007 T-2 B EPA 8015C 2 PASI-CMAD
SW-846 1 PASI-CKDF
92574121008 D-1 A EPA 8015C 2 PASI-CMAD
SW-846 1 PASI-CKDF
92574121009 D-1 B EPA 8015C 2 PASI-CMAD
SW-846 1 PASI-CKDF
92574121010 D-2 A EPA 8015C 2 PASI-CMAD
SW-846 1 PASI-CKDF
92574121011 D-2 B EPA 8015C 2 PASI-CMAD
SW-846 1 PASI-CKDF
92574121012 L-1 EPA 8015C 2 PASI-CMAD
SW-846 1 PASI-CKDF
92574121013 L-2 EPA 8015C 2 PASI-CMAD
SW-846 1 PASI-CKDF
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Sample:T-1 A Lab ID:92574121001 Collected:11/23/21 09:10 Received:11/23/21 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8015 GCS THC-Diesel
Diesel Range Organics(C10-C28)1000 mg/kg 11/29/21 10:3711/24/21 11:1026.8 4
Surrogates
n-Pentacosane (S)75 %11/29/21 10:37 629-99-211/24/21 11:1032-130 4
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)48900 mg/kg 11/30/21 06:0811/29/21 12:00998100
Surrogates
4-Bromofluorobenzene (S)116 %11/30/21 06:08 460-00-411/29/21 12:0066-131 100
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 24.7 %11/23/21 17:11 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Sample:T-1 B Lab ID:92574121002 Collected:11/23/21 09:15 Received:11/23/21 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8015 GCS THC-Diesel
Diesel Range Organics(C10-C28)148 mg/kg 11/24/21 16:2211/24/21 11:106.9 1
Surrogates
n-Pentacosane (S)73 %11/24/21 16:22 629-99-211/24/21 11:1032-130 1
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)2080 mg/kg 11/30/21 06:3611/29/21 12:0052.7 5
Surrogates
4-Bromofluorobenzene (S)137 %11/30/21 06:36 460-00-4 S211/29/21 12:0066-131 5
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 25.9 %11/23/21 17:11 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Sample:T-3 A Lab ID:92574121003 Collected:11/23/21 09:00 Received:11/23/21 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8015 GCS THC-Diesel
Diesel Range Organics(C10-C28)ND mg/kg 11/24/21 16:3911/24/21 11:106.7 1
Surrogates
n-Pentacosane (S)80 %11/24/21 16:39 629-99-211/24/21 11:1032-130 1
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/29/21 15:0711/29/21 12:0010.6 1
Surrogates
4-Bromofluorobenzene (S)91 %11/29/21 15:07 460-00-411/29/21 12:0066-131 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 24.8 %11/23/21 17:11 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Sample:T-3 B Lab ID:92574121004 Collected:11/23/21 09:05 Received:11/23/21 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8015 GCS THC-Diesel
Diesel Range Organics(C10-C28)ND mg/kg 11/24/21 16:3911/24/21 11:106.1 1
Surrogates
n-Pentacosane (S)85 %11/24/21 16:39 629-99-211/24/21 11:1032-130 1
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/24/21 21:4211/24/21 10:199.4 1
Surrogates
4-Bromofluorobenzene (S)93 %11/24/21 21:42 460-00-411/24/21 10:1966-131 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 18.7 %11/23/21 17:32 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Sample:D-3 A Lab ID:92574121005 Collected:11/23/21 09:40 Received:11/23/21 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8015 GCS THC-Diesel
Diesel Range Organics(C10-C28)21.3 mg/kg 11/24/21 16:5511/24/21 11:106.5 1
Surrogates
n-Pentacosane (S)75 %11/24/21 16:55 629-99-211/24/21 11:1032-130 1
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/24/21 22:1011/24/21 10:199.0 1
Surrogates
4-Bromofluorobenzene (S)87 %11/24/21 22:10 460-00-411/24/21 10:1966-131 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 22.0 %11/23/21 17:32 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Sample:T-2 A Lab ID:92574121006 Collected:11/23/21 09:20 Received:11/23/21 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/24/21 22:3811/24/21 10:199.5 1
Surrogates
4-Bromofluorobenzene (S)90 %11/24/21 22:38 460-00-411/24/21 10:1966-131 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 12.7 %11/23/21 17:32 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Sample:T-2 B Lab ID:92574121007 Collected:11/23/21 09:25 Received:11/23/21 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/24/21 23:0611/24/21 10:198.5 1
Surrogates
4-Bromofluorobenzene (S)93 %11/24/21 23:06 460-00-411/24/21 10:1966-131 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 15.0 %11/23/21 17:33 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Sample:D-1 A Lab ID:92574121008 Collected:11/22/21 16:00 Received:11/23/21 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)2870 mg/kg 11/30/21 07:0411/29/21 12:0049.4 5
Surrogates
4-Bromofluorobenzene (S)187 %11/30/21 07:04 460-00-4 S211/29/21 12:0066-131 5
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 26.2 %11/23/21 17:33 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Sample:D-1 B Lab ID:92574121009 Collected:11/22/21 16:05 Received:11/23/21 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)2210 mg/kg 11/30/21 07:3211/29/21 12:0048.2 5
Surrogates
4-Bromofluorobenzene (S)171 %11/30/21 07:32 460-00-4 S211/29/21 12:0066-131 5
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 24.9 %11/23/21 17:33 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Sample:D-2 A Lab ID:92574121010 Collected:11/23/21 09:30 Received:11/23/21 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)56.1 mg/kg 11/24/21 23:3411/24/21 10:1910.0 1
Surrogates
4-Bromofluorobenzene (S)109 %11/24/21 23:34 460-00-411/24/21 10:1966-131 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 27.1 %11/23/21 17:33 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Sample:D-2 B Lab ID:92574121011 Collected:11/23/21 09:35 Received:11/23/21 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/25/21 00:0211/24/21 10:198.7 1
Surrogates
4-Bromofluorobenzene (S)86 %11/25/21 00:02 460-00-411/24/21 10:1966-131 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 20.7 %11/23/21 17:33 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Sample:L-1 Lab ID:92574121012 Collected:11/23/21 09:45 Received:11/23/21 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/25/21 00:3111/24/21 10:197.9 1
Surrogates
4-Bromofluorobenzene (S)91 %11/25/21 00:31 460-00-411/24/21 10:1966-131 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 18.3 %11/23/21 17:33 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Sample:L-2 Lab ID:92574121013 Collected:11/23/21 10:50 Received:11/23/21 13:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/30/21 00:3011/29/21 12:007.4 1
Surrogates
4-Bromofluorobenzene (S)89 %11/30/21 00:30 460-00-411/29/21 12:0066-131 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 20.6 %11/23/21 17:33 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
662106
EPA 5030B
EPA 8015C
Gasoline Range Organics
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92574121004, 92574121005, 92574121006, 92574121007, 92574121010, 92574121011, 92574121012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3468972
Associated Lab Samples:92574121004, 92574121005, 92574121006, 92574121007, 92574121010, 92574121011, 92574121012
Matrix:Solid
Analyzed
Gas Range Organics (C6-C10)mg/kg ND 5.9 11/24/21 18:25
4-Bromofluorobenzene (S)%87 66-131 11/24/21 18:25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3468973LABORATORY CONTROL SAMPLE:
LCSSpike
Gas Range Organics (C6-C10)mg/kg 48.249.5 97 70-130
4-Bromofluorobenzene (S)%94 66-131
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3468975MATRIX SPIKE SAMPLE:
MSSpike
Result
92573596004
Gas Range Organics (C6-C10)mg/kg 81.662.4 131 70-145ND
4-Bromofluorobenzene (S)%97 66-131
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92573491001
3468974SAMPLE DUPLICATE:
Gas Range Organics (C6-C10)mg/kg ND 30ND
4-Bromofluorobenzene (S)%8991
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
662541
EPA 5030B
EPA 8015C
Gasoline Range Organics
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92574121003, 92574121013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3471082
Associated Lab Samples:92574121003, 92574121013
Matrix:Solid
Analyzed
Gas Range Organics (C6-C10)mg/kg ND 5.9 11/29/21 14:11
4-Bromofluorobenzene (S)%92 66-131 11/29/21 14:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3471083LABORATORY CONTROL SAMPLE:
LCSSpike
Gas Range Organics (C6-C10)mg/kg 54.949.5 111 70-130
4-Bromofluorobenzene (S)%95 66-131
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3471085MATRIX SPIKE SAMPLE:
MSSpike
Result
92574229002
Gas Range Organics (C6-C10)mg/kg 11771.3 139 70-14518.0
4-Bromofluorobenzene (S)%S213766-131
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92574121003
3471084SAMPLE DUPLICATE:
Gas Range Organics (C6-C10)mg/kg ND 30ND
4-Bromofluorobenzene (S)%9091
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
662543
EPA 5030B
EPA 8015C
Gasoline Range Organics
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92574121001, 92574121002, 92574121008, 92574121009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3471088
Associated Lab Samples:92574121001, 92574121002, 92574121008, 92574121009
Matrix:Solid
Analyzed
Gas Range Organics (C6-C10)mg/kg ND 5.9 11/29/21 14:39
4-Bromofluorobenzene (S)%92 66-131 11/29/21 14:39
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3471089LABORATORY CONTROL SAMPLE:
LCSSpike
Gas Range Organics (C6-C10)mg/kg 49.749.5 100 70-130
4-Bromofluorobenzene (S)%97 66-131
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3471091MATRIX SPIKE SAMPLE:
MSSpike
Result
92574238003
Gas Range Organics (C6-C10)mg/kg 83.868.8 122 70-145ND
4-Bromofluorobenzene (S)%95 66-131
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92574238002
3471090SAMPLE DUPLICATE:
Gas Range Organics (C6-C10)mg/kg ND 30ND
4-Bromofluorobenzene (S)%9090
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
662110
EPA 3546
EPA 8015C
8015 Solid GCSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92574121001, 92574121002, 92574121003, 92574121004, 92574121005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3468987
Associated Lab Samples:92574121001, 92574121002, 92574121003, 92574121004, 92574121005
Matrix:Solid
Analyzed
Diesel Range Organics(C10-C28)mg/kg ND 5.0 11/24/21 14:29
n-Pentacosane (S)%86 32-130 11/24/21 14:29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3468988LABORATORY CONTROL SAMPLE:
LCSSpike
Diesel Range Organics(C10-C28)mg/kg 53.266.4 80 47-130
n-Pentacosane (S)%84 32-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3468989MATRIX SPIKE SAMPLE:
MSSpike
Result
92574089001
Diesel Range Organics(C10-C28)mg/kg 66.685 76 10-133ND
n-Pentacosane (S)%73 32-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92574109001
3468990SAMPLE DUPLICATE:
Diesel Range Organics(C10-C28)mg/kg 5500 D6653010800
n-Pentacosane (S)%0 S40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
661928
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92574121001, 92574121002, 92574121003
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92573830003
3468171SAMPLE DUPLICATE:
Percent Moisture %13.1 N292514.3
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92574121003
3468645SAMPLE DUPLICATE:
Percent Moisture %24.8 N202524.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
661998
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92574121004, 92574121005, 92574121006, 92574121007, 92574121008, 92574121009, 92574121010,
92574121011, 92574121012, 92574121013
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92574109001
3468713SAMPLE DUPLICATE:
Percent Moisture %23.2 N212523.4
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92574121013
3468714SAMPLE DUPLICATE:
Percent Moisture %21.1 N232520.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 30
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
Surrogate recovery outside laboratory control limits due to matrix interferences (confirmed by similar results from sample
re-analysis).S2
Surrogate recovery not evaluated against control limits due to sample dilution.S4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 30
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92574121
BUTTERY & BEANERY
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92574121001 662110 662283T-1 A EPA 3546 EPA 8015C
92574121002 662110 662283T-1 B EPA 3546 EPA 8015C
92574121003 662110 662283T-3 A EPA 3546 EPA 8015C
92574121004 662110 662283T-3 B EPA 3546 EPA 8015C
92574121005 662110 662283D-3 A EPA 3546 EPA 8015C
92574121001 662543 662621T-1 A EPA 5030B EPA 8015C
92574121002 662543 662621T-1 B EPA 5030B EPA 8015C
92574121003 662541 662576T-3 A EPA 5030B EPA 8015C
92574121004 662106 662149T-3 B EPA 5030B EPA 8015C
92574121005 662106 662149D-3 A EPA 5030B EPA 8015C
92574121006 662106 662149T-2 A EPA 5030B EPA 8015C
92574121007 662106 662149T-2 B EPA 5030B EPA 8015C
92574121008 662543 662621D-1 A EPA 5030B EPA 8015C
92574121009 662543 662621D-1 B EPA 5030B EPA 8015C
92574121010 662106 662149D-2 A EPA 5030B EPA 8015C
92574121011 662106 662149D-2 B EPA 5030B EPA 8015C
92574121012 662106 662149L-1 EPA 5030B EPA 8015C
92574121013 662541 662576L-2 EPA 5030B EPA 8015C
92574121001 661928T-1 A SW-846
92574121002 661928T-1 B SW-846
92574121003 661928T-3 A SW-846
92574121004 661998T-3 B SW-846
92574121005 661998D-3 A SW-846
92574121006 661998T-2 A SW-846
92574121007 661998T-2 B SW-846
92574121008 661998D-1 A SW-846
92574121009 661998D-1 B SW-846
92574121010 661998D-2 A SW-846
92574121011 661998D-2 B SW-846
92574121012 661998L-1 SW-846
92574121013 661998L-2 SW-846
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/01/2021 05:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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