WS-29296_48461_CA_RPTS_20220623_LetRpt-WSW-6100 NC 704

S&ME, Inc. | 8646 W Market St, Ste 105 | Greensboro, NC 27409 | p 336.288.7180 | f 336.288.8980 | www.smeinc.com

June 23, 2022
Mr. Melvin Dodson
6100 NC Highway 704 East
Sandy Ridge, North Carolina 27046
Reference: Water Well Analyses
6100 NC Highway 704 East
Sandy Ridge, North Carolina
S&ME Project No. 22580285

Dear Mr. Dodson:

S&ME, Inc. collected a water sample from your water supply well at 6100 NC Highway 704 East on June 8,
2022. The sample was collected from an outside spigot on the back of the house. S&ME also collected a
water sample from the men’s restroom at the D&M Grocery property on June 8, 2022. The water supply
well that provides water to the D&M Grocery store is located on the property that adjoins the D&M
Grocery property to the west, which you also own. Prior to sample collection at each location, water was
allowed to run for approximately 15 minutes. The water samples were placed into laboratory provided
containers, placed into a cooler with ice and shipped to Analytical Services for analysis.
The two samples were analyzed for volatile organic compounds by EPA Method 6200B. Methyl tert-butyl
ether (MTBE) was reported in the water sample collected at 6100 NC Highway 704 East at a low
concentration, estimated to be 0.45 micrograms per liter (ug/l, parts per billion). The North Carolina
groundwater quality standard for MTBE is 20 ug/l. S&ME provided a copy of the laboratory report to the
North Carolina Department of Environmental Quality (NCDEQ) for review. Based on the reported results,
water from the well located at 6100 NC Highway 704 East is safe to use. The laboratory analysis did not
detect targeted compounds in the sample collected from the men’s restroom at the D&M Grocery. A
copy of the laboratory report is attached.
If you have any questions regarding the laboratory analysis, please call Wayne Watterson at (336) 908-
7653.
Sincerely,
S&ME, Inc.

Lyndal Butler Wayne H. Watterson, P.E.
Project Professional Senior Engineer
Attachment: Laboratory Report
cc: Mr. James Barnwell, III - Huffman Oil Company
Ms. Linda Estkowski, UST Section-NCDEQ Winston-Salem Regional Office

Attachment
#=CL#
June 13, 2022
LIMS USE: FR - WAYNE WATTERSON
LIMS OBJECT ID: 92608565
92608565
Project:
Pace Project No.:
RE:
Mr. Wayne Watterson
S&ME, Inc.
8646 West Market Street
Greensboro, NC 27409
22580285 Ph A
Dear Mr. Watterson:
Enclosed are the analytical results for sample(s) received by the laboratory on June 08, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
[phone]
Enclosures
cc:Mr. Lyndal Butler, S&ME, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 21
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92608565
22580285 Ph A
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 21
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92608565
22580285 Ph A
Lab ID Sample ID Matrix Date Collected Date Received
92608565001 6100 Well Water 06/08/22 10:00 06/08/22 12:45
92608565002 6066 Well Water 06/08/22 10:30 06/08/22 12:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 21
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92608565
22580285 Ph A
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92608565001 6100 Well SM 6200B 69 PASI-CSAS
92608565002 6066 Well SM 6200B 69 PASI-CSAS
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 21
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92608565
22580285 Ph A
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92608565001 6100 Well
Methyl-tert-butyl ether 0.45J ug/L 06/13/22 14:120.50SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 21
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92608565
22580285 Ph A
Method:
Client:S&ME - Greensboro
SM 6200B
Date:June 13, 2022
Description:6200B MSV
General Information:
2 samples were analyzed for SM 6200B by Pace Analytical Services Charlotte. All samples were received in acceptable condition with
any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end ofthis report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 703719
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92607183003
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 3674043)
• Benzene
• MSD (Lab ID: 3674044)
• Benzene
• Toluene
P5: The EPA or method required sample preservation degrades this compound, therefore acceptable recoveries may not be
achieved in sample matrix spikes.
• MS (Lab ID: 3674043)
• tert-Butyl Formate
• MSD (Lab ID: 3674044)
• tert-Butyl Formate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 21
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92608565
22580285 Ph A
Method:
Client:S&ME - Greensboro
SM 6200B
Date:June 13, 2022
Description:6200B MSV
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92608565
22580285 Ph A
Sample:6100 Well Lab ID:92608565001 Collected:06/08/22 10:00 Received:06/08/22 12:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol ND ug/L 06/13/22 14:12 75-85-410036.4 1
tert-Amylmethyl ether ND ug/L 06/13/22 14:12 994-05-810.0 9.2 1
Benzene ND ug/L 06/13/22 14:12 71-43-20.50 0.34 1
Bromobenzene ND ug/L 06/13/22 14:12 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 06/13/22 14:12 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 06/13/22 14:12 75-27-40.50 0.31 1
Bromoform ND ug/L 06/13/22 14:12 75-25-20.50 0.34 1
Bromomethane ND ug/L 06/13/22 14:12 74-83-95.0 1.7 1
tert-Butyl Alcohol ND ug/L 06/13/22 14:12 75-65-050.0 26.8 1
n-Butylbenzene ND ug/L 06/13/22 14:12 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 06/13/22 14:12 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 06/13/22 14:12 98-06-60.50 0.32 1
tert-Butyl Formate ND ug/L 06/13/22 14:12 762-75-450.0 29.4 1
Carbon tetrachloride ND ug/L 06/13/22 14:12 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 06/13/22 14:12 108-90-70.50 0.28 1
Chloroethane ND ug/L 06/13/22 14:12 75-00-31.0 0.65 1
Chloroform ND ug/L 06/13/22 14:12 67-66-30.50 0.43 1
Chloromethane ND ug/L 06/13/22 14:12 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 06/13/22 14:12 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 06/13/22 14:12 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 06/13/22 14:12 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 06/13/22 14:12 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 06/13/22 14:12 106-93-40.50 0.27 1
Dibromomethane ND ug/L 06/13/22 14:12 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 06/13/22 14:12 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 06/13/22 14:12 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 06/13/22 14:12 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 06/13/22 14:12 75-71-80.50 0.35 1
1,1-Dichloroethane ND ug/L 06/13/22 14:12 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 06/13/22 14:12 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 06/13/22 14:12 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 06/13/22 14:12 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 06/13/22 14:12 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 06/13/22 14:12 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 06/13/22 14:12 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 06/13/22 14:12 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 06/13/22 14:12 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 06/13/22 14:12 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 06/13/22 14:12 10061-02-60.50 0.36 1
Diisopropyl ether ND ug/L 06/13/22 14:12 108-20-30.50 0.31 1
Ethanol ND ug/L 06/13/22 14:12 64-17-520072.2 1
Ethylbenzene ND ug/L 06/13/22 14:12 100-41-40.50 0.30 1
Ethyl-tert-butyl ether ND ug/L 06/13/22 14:12 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene ND ug/L 06/13/22 14:12 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)ND ug/L 06/13/22 14:12 98-82-80.50 0.33 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/13/2022 03:47 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92608565
22580285 Ph A
Sample:6100 Well Lab ID:92608565001 Collected:06/08/22 10:00 Received:06/08/22 12:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride ND ug/L 06/13/22 14:12 75-09-22.0 2.0 1
Methyl-tert-butyl ether 0.45J ug/L 06/13/22 14:12 1634-04-40.50 0.42 1
Naphthalene ND ug/L 06/13/22 14:12 91-20-32.0 0.64 1
n-Propylbenzene ND ug/L 06/13/22 14:12 103-65-10.50 0.34 1
Styrene ND ug/L 06/13/22 14:12 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 06/13/22 14:12 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 06/13/22 14:12 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 06/13/22 14:12 127-18-40.50 0.29 1
Toluene ND ug/L 06/13/22 14:12 108-88-30.50 0.48 1
1,2,3-Trichlorobenzene ND ug/L 06/13/22 14:12 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 06/13/22 14:12 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 06/13/22 14:12 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 06/13/22 14:12 79-00-50.50 0.32 1
Trichloroethene ND ug/L 06/13/22 14:12 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 06/13/22 14:12 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 06/13/22 14:12 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene ND ug/L 06/13/22 14:12 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene ND ug/L 06/13/22 14:12 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 06/13/22 14:12 75-01-41.0 0.39 1
m&p-Xylene ND ug/L 06/13/22 14:12 179601-23-11.0 0.71 1
o-Xylene ND ug/L 06/13/22 14:12 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)98 %06/13/22 14:12 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %06/13/22 14:12 460-00-470-130 1
Toluene-d8 (S)102 %06/13/22 14:12 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/13/2022 03:47 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92608565
22580285 Ph A
Sample:6066 Well Lab ID:92608565002 Collected:06/08/22 10:30 Received:06/08/22 12:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol ND ug/L 06/13/22 13:54 75-85-410036.4 1
tert-Amylmethyl ether ND ug/L 06/13/22 13:54 994-05-810.0 9.2 1
Benzene ND ug/L 06/13/22 13:54 71-43-20.50 0.34 1
Bromobenzene ND ug/L 06/13/22 13:54 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 06/13/22 13:54 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 06/13/22 13:54 75-27-40.50 0.31 1
Bromoform ND ug/L 06/13/22 13:54 75-25-20.50 0.34 1
Bromomethane ND ug/L 06/13/22 13:54 74-83-95.0 1.7 1
tert-Butyl Alcohol ND ug/L 06/13/22 13:54 75-65-050.0 26.8 1
n-Butylbenzene ND ug/L 06/13/22 13:54 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 06/13/22 13:54 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 06/13/22 13:54 98-06-60.50 0.32 1
tert-Butyl Formate ND ug/L 06/13/22 13:54 762-75-450.0 29.4 1
Carbon tetrachloride ND ug/L 06/13/22 13:54 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 06/13/22 13:54 108-90-70.50 0.28 1
Chloroethane ND ug/L 06/13/22 13:54 75-00-31.0 0.65 1
Chloroform ND ug/L 06/13/22 13:54 67-66-30.50 0.43 1
Chloromethane ND ug/L 06/13/22 13:54 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 06/13/22 13:54 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 06/13/22 13:54 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 06/13/22 13:54 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 06/13/22 13:54 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 06/13/22 13:54 106-93-40.50 0.27 1
Dibromomethane ND ug/L 06/13/22 13:54 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 06/13/22 13:54 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 06/13/22 13:54 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 06/13/22 13:54 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 06/13/22 13:54 75-71-80.50 0.35 1
1,1-Dichloroethane ND ug/L 06/13/22 13:54 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 06/13/22 13:54 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 06/13/22 13:54 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 06/13/22 13:54 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 06/13/22 13:54 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 06/13/22 13:54 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 06/13/22 13:54 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 06/13/22 13:54 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 06/13/22 13:54 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 06/13/22 13:54 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 06/13/22 13:54 10061-02-60.50 0.36 1
Diisopropyl ether ND ug/L 06/13/22 13:54 108-20-30.50 0.31 1
Ethanol ND ug/L 06/13/22 13:54 64-17-520072.2 1
Ethylbenzene ND ug/L 06/13/22 13:54 100-41-40.50 0.30 1
Ethyl-tert-butyl ether ND ug/L 06/13/22 13:54 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene ND ug/L 06/13/22 13:54 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)ND ug/L 06/13/22 13:54 98-82-80.50 0.33 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/13/2022 03:47 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92608565
22580285 Ph A
Sample:6066 Well Lab ID:92608565002 Collected:06/08/22 10:30 Received:06/08/22 12:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride ND ug/L 06/13/22 13:54 75-09-22.0 2.0 1
Methyl-tert-butyl ether ND ug/L 06/13/22 13:54 1634-04-40.50 0.42 1
Naphthalene ND ug/L 06/13/22 13:54 91-20-32.0 0.64 1
n-Propylbenzene ND ug/L 06/13/22 13:54 103-65-10.50 0.34 1
Styrene ND ug/L 06/13/22 13:54 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 06/13/22 13:54 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 06/13/22 13:54 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 06/13/22 13:54 127-18-40.50 0.29 1
Toluene ND ug/L 06/13/22 13:54 108-88-30.50 0.48 1
1,2,3-Trichlorobenzene ND ug/L 06/13/22 13:54 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 06/13/22 13:54 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 06/13/22 13:54 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 06/13/22 13:54 79-00-50.50 0.32 1
Trichloroethene ND ug/L 06/13/22 13:54 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 06/13/22 13:54 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 06/13/22 13:54 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene ND ug/L 06/13/22 13:54 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene ND ug/L 06/13/22 13:54 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 06/13/22 13:54 75-01-41.0 0.39 1
m&p-Xylene ND ug/L 06/13/22 13:54 179601-23-11.0 0.71 1
o-Xylene ND ug/L 06/13/22 13:54 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)99 %06/13/22 13:54 17060-07-070-130 1
4-Bromofluorobenzene (S)99 %06/13/22 13:54 460-00-470-130 1
Toluene-d8 (S)100 %06/13/22 13:54 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 06/13/2022 03:47 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92608565
22580285 Ph A
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
703719
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92608565001, 92608565002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3672284
Associated Lab Samples:92608565001, 92608565002
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 06/13/22 13:360.31
1,1,1-Trichloroethane ug/L ND 0.50 06/13/22 13:360.33
1,1,2,2-Tetrachloroethane ug/L ND 0.50 06/13/22 13:360.22
1,1,2-Trichloroethane ug/L ND 0.50 06/13/22 13:360.32
1,1-Dichloroethane ug/L ND 0.50 06/13/22 13:360.37
1,1-Dichloroethene ug/L ND 0.50 06/13/22 13:360.35
1,1-Dichloropropene ug/L ND 0.50 06/13/22 13:360.43
1,2,3-Trichlorobenzene ug/L ND 2.0 06/13/22 13:360.81
1,2,3-Trichloropropane ug/L ND 0.50 06/13/22 13:360.26
1,2,4-Trichlorobenzene ug/L ND 2.0 06/13/22 13:360.64
1,2,4-Trimethylbenzene ug/L ND 0.50 06/13/22 13:360.50
1,2-Dibromo-3-chloropropane ug/L ND 1.0 06/13/22 13:360.34
1,2-Dibromoethane (EDB)ug/L ND 0.50 06/13/22 13:360.27
1,2-Dichlorobenzene ug/L ND 0.50 06/13/22 13:360.34
1,2-Dichloroethane ug/L ND 0.50 06/13/22 13:360.32
1,2-Dichloropropane ug/L ND 0.50 06/13/22 13:360.36
1,3,5-Trimethylbenzene ug/L ND 0.50 06/13/22 13:360.33
1,3-Dichlorobenzene ug/L ND 0.50 06/13/22 13:360.34
1,3-Dichloropropane ug/L ND 0.50 06/13/22 13:360.28
1,4-Dichlorobenzene ug/L ND 0.50 06/13/22 13:360.33
2,2-Dichloropropane ug/L ND 0.50 06/13/22 13:360.39
2-Chlorotoluene ug/L ND 0.50 06/13/22 13:360.32
4-Chlorotoluene ug/L ND 0.50 06/13/22 13:360.32
Benzene ug/L ND 0.50 06/13/22 13:360.34
Bromobenzene ug/L ND 0.50 06/13/22 13:360.29
Bromochloromethane ug/L ND 0.50 06/13/22 13:360.47
Bromodichloromethane ug/L ND 0.50 06/13/22 13:360.31
Bromoform ug/L ND 0.50 06/13/22 13:360.34
Bromomethane ug/L ND 5.0 06/13/22 13:361.7
Carbon tetrachloride ug/L ND 0.50 06/13/22 13:360.33
Chlorobenzene ug/L ND 0.50 06/13/22 13:360.28
Chloroethane ug/L ND 1.0 06/13/22 13:360.65
Chloroform ug/L ND 0.50 06/13/22 13:360.43
Chloromethane ug/L ND 1.0 06/13/22 13:360.54
cis-1,2-Dichloroethene ug/L ND 0.50 06/13/22 13:360.38
cis-1,3-Dichloropropene ug/L ND 0.50 06/13/22 13:360.36
Dibromochloromethane ug/L ND 0.50 06/13/22 13:360.36
Dibromomethane ug/L ND 0.50 06/13/22 13:360.39
Dichlorodifluoromethane ug/L ND 0.50 06/13/22 13:360.35
Diisopropyl ether ug/L ND 0.50 06/13/22 13:360.31
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 06/13/2022 03:47 PM
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Page 12 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92608565
22580285 Ph A
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3672284
Associated Lab Samples:92608565001, 92608565002
Matrix:Water
AnalyzedMDL
Ethanol ug/L ND 200 06/13/22 13:3672.2
Ethyl-tert-butyl ether ug/L ND 10.0 06/13/22 13:363.2
Ethylbenzene ug/L ND 0.50 06/13/22 13:360.30
Hexachloro-1,3-butadiene ug/L ND 2.0 06/13/22 13:361.5
Isopropylbenzene (Cumene)ug/L ND 0.50 06/13/22 13:360.33
m&p-Xylene ug/L ND 1.0 06/13/22 13:360.71
Methyl-tert-butyl ether ug/L ND 0.50 06/13/22 13:360.42
Methylene Chloride ug/L ND 2.0 06/13/22 13:362.0
n-Butylbenzene ug/L ND 0.50 06/13/22 13:360.49
n-Propylbenzene ug/L ND 0.50 06/13/22 13:360.34
Naphthalene ug/L ND 2.0 06/13/22 13:360.64
o-Xylene ug/L ND 0.50 06/13/22 13:360.34
sec-Butylbenzene ug/L ND 0.50 06/13/22 13:360.40
Styrene ug/L ND 0.50 06/13/22 13:360.29
tert-Amyl Alcohol ug/L ND 100 06/13/22 13:3636.4
tert-Amylmethyl ether ug/L ND 10.0 06/13/22 13:369.2
tert-Butyl Alcohol ug/L ND 50.0 06/13/22 13:3626.8
tert-Butyl Formate ug/L ND 50.0 06/13/22 13:3629.4
tert-Butylbenzene ug/L ND 0.50 06/13/22 13:360.32
Tetrachloroethene ug/L ND 0.50 06/13/22 13:360.29
Toluene ug/L ND 0.50 06/13/22 13:360.48
trans-1,2-Dichloroethene ug/L ND 0.50 06/13/22 13:360.40
trans-1,3-Dichloropropene ug/L ND 0.50 06/13/22 13:360.36
Trichloroethene ug/L ND 0.50 06/13/22 13:360.38
Trichlorofluoromethane ug/L ND 1.0 06/13/22 13:360.30
Vinyl chloride ug/L ND 1.0 06/13/22 13:360.39
1,2-Dichloroethane-d4 (S)%96 70-130 06/13/22 13:36
4-Bromofluorobenzene (S)%99 70-130 06/13/22 13:36
Toluene-d8 (S)%88 70-130 06/13/22 13:36
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3672285LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.150 100 60-140
1,1,1-Trichloroethane ug/L 46.150 92 60-140
1,1,2,2-Tetrachloroethane ug/L 44.250 88 60-140
1,1,2-Trichloroethane ug/L 45.550 91 60-140
1,1-Dichloroethane ug/L 41.750 83 60-140
1,1-Dichloroethene ug/L 47.850 96 60-140
1,1-Dichloropropene ug/L 42.650 85 60-140
1,2,3-Trichlorobenzene ug/L 57.550 115 60-140
1,2,3-Trichloropropane ug/L 45.250 90 60-140
1,2,4-Trichlorobenzene ug/L 59.050 118 60-140
1,2,4-Trimethylbenzene ug/L 48.450 97 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 06/13/2022 03:47 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92608565
22580285 Ph A
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3672285LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dibromo-3-chloropropane ug/L 49.350 99 60-140
1,2-Dibromoethane (EDB)ug/L 49.050 98 60-140
1,2-Dichlorobenzene ug/L 54.550 109 60-140
1,2-Dichloroethane ug/L 45.650 91 60-140
1,2-Dichloropropane ug/L 49.850 100 60-140
1,3,5-Trimethylbenzene ug/L 49.950 100 60-140
1,3-Dichlorobenzene ug/L 48.450 97 60-140
1,3-Dichloropropane ug/L 47.450 95 60-140
1,4-Dichlorobenzene ug/L 47.250 94 60-140
2,2-Dichloropropane ug/L 44.650 89 60-140
2-Chlorotoluene ug/L 46.450 93 60-140
4-Chlorotoluene ug/L 46.750 93 60-140
Benzene ug/L 44.050 88 60-140
Bromobenzene ug/L 46.450 93 60-140
Bromochloromethane ug/L 39.650 79 60-140
Bromodichloromethane ug/L 43.250 86 60-140
Bromoform ug/L 47.350 95 60-140
Bromomethane ug/L 46.350 93 60-140
Carbon tetrachloride ug/L 52.650 105 60-140
Chlorobenzene ug/L 47.550 95 60-140
Chloroethane ug/L 60.450 121 60-140
Chloroform ug/L 38.850 78 60-140
Chloromethane ug/L 49.050 98 60-140
cis-1,2-Dichloroethene ug/L 44.450 89 60-140
cis-1,3-Dichloropropene ug/L 47.450 95 60-140
Dibromochloromethane ug/L 48.150 96 60-140
Dibromomethane ug/L 45.150 90 60-140
Dichlorodifluoromethane ug/L 57.050 114 60-140
Diisopropyl ether ug/L 49.650 99 60-140
Ethanol ug/L 19302000 97 60-140
Ethyl-tert-butyl ether ug/L 86.6100 87 60-140
Ethylbenzene ug/L 46.950 94 60-140
Hexachloro-1,3-butadiene ug/L 67.450 135 60-140
Isopropylbenzene (Cumene)ug/L 48.850 98 60-140
m&p-Xylene ug/L 95.8100 96 60-140
Methyl-tert-butyl ether ug/L 41.850 84 60-140
Methylene Chloride ug/L 42.250 84 60-140
n-Butylbenzene ug/L 57.550 115 60-140
n-Propylbenzene ug/L 47.350 95 60-140
Naphthalene ug/L 55.850 112 60-140
o-Xylene ug/L 47.350 95 60-140
sec-Butylbenzene ug/L 50.550 101 60-140
Styrene ug/L 47.650 95 60-140
tert-Amyl Alcohol ug/L 10501000 105 60-140
tert-Amylmethyl ether ug/L 92.5100 93 60-140
tert-Butyl Alcohol ug/L 415500 83 60-140
tert-Butyl Formate ug/L 365400 91 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 06/13/2022 03:47 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92608565
22580285 Ph A
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3672285LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butylbenzene ug/L 41.350 83 60-140
Tetrachloroethene ug/L 51.450 103 60-140
Toluene ug/L 42.550 85 60-140
trans-1,2-Dichloroethene ug/L 47.050 94 60-140
trans-1,3-Dichloropropene ug/L 46.450 93 60-140
Trichloroethene ug/L 53.450 107 60-140
Trichlorofluoromethane ug/L 53.750 107 60-140
Vinyl chloride ug/L 53.350 107 60-140
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%94 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3674043MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92607183003
3674044
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 101 60-140102 0 3020ND20.3 20.3
1,1,1-Trichloroethane ug/L 20 89 60-140103 15 3020ND17.8 20.6
1,1,2,2-Tetrachloroethane ug/L 20 93 60-14095 3 3020ND18.5 19.1
1,1,2-Trichloroethane ug/L 20 94 60-14085 9 3020ND18.7 17.0
1,1-Dichloroethane ug/L 20 81 60-14082 1 3020ND16.2 16.4
1,1-Dichloroethene ug/L 20 95 60-14096 1 3020ND19.0 19.3
1,1-Dichloropropene ug/L 20 86 60-14098 13 3020ND17.1 19.6
1,2,3-Trichlorobenzene ug/L 20 102 60-140114 11 3020ND20.4 22.9
1,2,3-Trichloropropane ug/L 20 93 60-14095 2 3020ND18.7 19.0
1,2,4-Trichlorobenzene ug/L 20 98 60-140108 9 3020ND19.6 21.6
1,2,4-Trimethylbenzene ug/L 20 105 60-140109 3 30205.1 26.0 26.9
1,2-Dibromo-3-
chloropropane ug/L 20 86 60-14091 6 3020ND17.2 18.2
1,2-Dibromoethane (EDB)ug/L 20 99 60-140100 1 3020ND19.8 20.0
1,2-Dichlorobenzene ug/L 20 100 60-140102 2 3020ND20.0 20.5
1,2-Dichloroethane ug/L 20 98 60-140100 2 3020ND19.6 20.0
1,2-Dichloropropane ug/L 20 109 60-140109 0 3020ND21.8 21.8
1,3,5-Trimethylbenzene ug/L 20 105 60-140111 4 30201.3 22.3 23.4
1,3-Dichlorobenzene ug/L 20 102 60-140105 3 3020ND20.3 21.0
1,3-Dichloropropane ug/L 20 111 60-140102 9 3020ND22.2 20.3
1,4-Dichlorobenzene ug/L 20 100 60-140104 3 3020ND20.1 20.7
2,2-Dichloropropane ug/L 20 83 60-14086 4 3020ND16.7 17.3
2-Chlorotoluene ug/L 20 99 60-140102 3 3020ND19.8 20.4
4-Chlorotoluene ug/L 20 100 60-140103 4 3020ND20.0 20.7
Benzene ug/L M12014960-140147 1 302056.9 86.8 86.2
Bromobenzene ug/L 20 101 60-140103 2 3020ND20.2 20.6
Bromochloromethane ug/L 20 76 60-14087 14 3020ND15.1 17.4
Bromodichloromethane ug/L 20 86 60-14087 2 3020ND17.1 17.4
Bromoform ug/L 20 84 60-14087 3 3020ND16.9 17.5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 06/13/2022 03:47 PM
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Huntersville, NC 28078
[phone]
Page 15 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92608565
22580285 Ph A
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3674043MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92607183003
3674044
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromomethane ug/L 20 101 60-140102 1 3020ND20.2 20.3
Carbon tetrachloride ug/L 20 95 60-140109 14 3020ND19.0 21.9
Chlorobenzene ug/L 20 103 60-140103 0 3020ND20.6 20.6
Chloroethane ug/L 20 124 60-140119 4 3020ND24.9 23.8
Chloroform ug/L 20 66 60-14077 15 3020ND13.2 15.3
Chloromethane ug/L 20 99 60-14099 0 3020ND19.7 19.8
cis-1,2-Dichloroethene ug/L 20 86 60-14087 1 3020ND17.2 17.4
cis-1,3-Dichloropropene ug/L 20 100 60-14095 6 3020ND20.1 18.9
Dibromochloromethane ug/L 20 102 60-14095 7 3020ND20.4 19.0
Dibromomethane ug/L 20 97 60-140101 4 3020ND19.4 20.1
Dichlorodifluoromethane ug/L 20 111 60-140112 1 3020ND22.1 22.4
Diisopropyl ether ug/L 20 91 60-14092 0 30209.7 27.9 28.0
Ethanol ug/L 800 90 60-14098 9 30800ND720785
Ethyl-tert-butyl ether ug/L 40 78 60-14080 2 3040ND31.4 31.9
Ethylbenzene ug/L 20 105 60-140107 1 30209.1 30.1 30.4
Hexachloro-1,3-butadiene ug/L 20 118 60-140124 5 3020ND23.6 24.7
Isopropylbenzene
(Cumene)ug/L 20 106 60-140110 3 3020ND21.2 21.9
m&p-Xylene ug/L 40 119 60-140121 1 304033.2 81.0 81.8
Methyl-tert-butyl ether ug/L 20 78 60-14077 1 30202.1 17.6 17.4
Methylene Chloride ug/L 20 67 60-14068 1 3020ND13.5 13.6
n-Butylbenzene ug/L 20 110 60-140116 6 3020ND22.0 23.2
n-Propylbenzene ug/L 20 103 60-140105 2 30200.43J 21.1 21.5
Naphthalene ug/L 20 97 60-140107 9 30201.1J 20.5 22.4
o-Xylene ug/L 20 111 60-140114 2 302015.1 37.3 37.9
sec-Butylbenzene ug/L 20 109 60-140113 4 3020ND21.8 22.6
Styrene ug/L 20 100 60-140104 4 3020ND20.0 20.8
tert-Amyl Alcohol ug/L 400 111 60-140117 5 30400ND444466
tert-Amylmethyl ether ug/L 40 98 60-14099 1 3040ND39.1 39.5
tert-Butyl Alcohol ug/L 200 97 60-140108 12 30200ND193217
tert-Butyl Formate ug/L P51604060-14037 9 30160ND64.7 58.9
tert-Butylbenzene ug/L 20 89 60-14094 6 3020ND17.8 18.8
Tetrachloroethene ug/L 20 128 60-140117 9 3020ND25.7 23.4
Toluene ug/L M12010260-14056 19 302032.1 52.6 43.2
trans-1,2-Dichloroethene ug/L 20 91 60-14092 2 3020ND18.1 18.4
trans-1,3-Dichloropropene ug/L 20 92 60-14082 11 3020ND18.3 16.4
Trichloroethene ug/L 20 115 60-140117 2 3020ND22.9 23.4
Trichlorofluoromethane ug/L 20 108 60-140110 2 3020ND21.6 22.0
Vinyl chloride ug/L 20 104 60-140105 1 3020ND20.8 21.1
1,2-Dichloroethane-d4 (S)%96 70-130101
4-Bromofluorobenzene (S)%97 70-13098
Toluene-d8 (S)%103 70-13083
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 06/13/2022 03:47 PM
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Huntersville, NC 28078
[phone]
Page 16 of 21
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92608565
22580285 Ph A
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The EPA or method required sample preservation degrades this compound, therefore acceptable recoveries may not be
achieved in sample matrix spikes.P5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 06/13/2022 03:47 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 21
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92608565
22580285 Ph A
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92608565001 7037196100 Well SM 6200B
92608565002 7037196066 Well SM 6200B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 06/13/2022 03:47 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 21
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