WS-6277_44319_CA_MRP_20230427

Monitoring Report

Former Bob May’s Automotive Service Center
727 West Northwest Boulevard
Winston-Salem, Forsyth County, North Carolina
NCDEQ Incident #44319
ATC Project No. SLC4446302

Submittal Date:

April 27, 2023

Prepared for:

North Carolina Department of Environmental Quality
Division of Waste Management – Underground Storage Tank Section
1646 Mail Service Center
Raleigh, North Carolina 27699-1646

Prepared By:
ATC Associates of North Carolina, P.C.
7606 Whitehall Executive Center Drive, Suite 800
Charlotte, North Carolina 28273
p: [phone] / f: [phone]

7606 Whitehall Executive Center Drive
Suite 800
Charlotte, NC 28273
Tel: [phone]
Fax: [phone]
www.oneatlas.com
N.C. Engineering License No. C-1598

April 27, 2023

Mr. Scott Ryals, P.E.
North Carolina Department of Environmental Quality
Division of Waste Management - Underground Storage Tank Section
1646 Mail Service Center
Raleigh, North Carolina 27699-1646

Re: Monitoring Report
Former Bob May’s Automotive Service Center
727 West Northwest Boulevard
Winston-Salem, Forsyth County, North Carolina
NCDEQ Incident #44319
ATC Project #SLC4446302
Task Authorization: TA-02

Dear Mr. Ryals:

ATC Associates of North Carolina, P.C., under contract to the North Carolina Department of
Environmental Quality, submits this Monitoring Report for the former Bob May’s Automotive Service
Center site. The report presents the results for the monitoring well installation and groundwater
assessment activities conducted during January and February of 2023. If you have any questions
or require additional information, please contact our office at [phone].

Sincerely,

ATC Associates of North Carolina, P.C.

Ashleigh Thrash Al Quarles, P.G.
Project Manager Senior Project Manager

Monitoring Report April 27, 2023
Former Bob Mays Automotive Service ATC Project #SLC4431902

TABLE OF CONTENTS
1.0 SITE IDENTIFICATION ............................................................................... 1
2.0 EXECUTIVE SUMMARY ............................................................................. 1
3.0 SITE DESCRIPTION ................................................................................... 2
3.1 Site Characterization .................................................................... 2
3.2 Site Background ........................................................................... 2
3.3 Site and Regional Geology .......................................................... 3
3.4 Site and Regional Hydrogeology .................................................. 3
4.0 POTENTIAL RECEPTORS ......................................................................... 4
5.0 GROUNDWATER ASSESSMENT ACTIVITIES ......................................... 4
5.1 Monitoring Well Installation .......................................................... 4
5.2 Groundwater Levels ..................................................................... 5
5.3 Groundwater Quality .................................................................... 5
6.0 WASTE MANAGEMENT ........................................................................ 6
7.0 CONCLUSIONS AND RECOMMENDATIONS ........................................... 7

TABLES
Table 1 Monitoring Well and Groundwater Level Data
Table 2 Field Parameters
Table 3 Summary of Groundwater Analytical Results
Table 4 Summary of Soil Analytical Results

FIGURES
Figure 1 Site Location Map
Figure 2 Site Map
Figure 3 Groundwater Elevation Contour Map
Figure 4 Contaminants of Concern Map

APPENDICES
Appendix A Field Notes and Photographs
Appendix B Well Logs and Well Construction Records
Appendix C Laboratory Analytical Reports
Appendix D Bill of Lading / Material Manifest

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1.0 SITE IDENTIFICATION
1. Site Identification
Date of Report: April 27, 2023
Facility I.D.:___N/A UST Incident Number (if known): 44319
Site Risk: Not Established Site Rank: Not Established Land Use Category: Commercial
Site Name: Former Bob May’s Automotive Service Center
Site Street Address:_ 727 West Northwest Boulevard
City/Town: Winston-Salem Zip Code: 27101 County: Forsyth
Description of Geographical Data Point: __Former UST Basin______________
Location Method: __Google Earth______________________________
Latitude (decimal degrees): 36.106036 Longitude (decimal degrees):-80.254038°

2. Information about Contacts Associated with the Leaking UST System
UST Owner/Operator: Unknown
Address: Unknown Tel.: N/A
Property Owner: Mr. Bob May
Address: 2615 Union Grove Road, Lexington, NC 27295 Tel.: (336) 722 - 5657
Property Occupant: No current occupant
Address: N/A Tel.: N/A
Consultant/Contractor: ATC Associates of North Carolina, P.C.
Address: 7606 Whitehall Executive Center Dr., Charlotte, NC 28273 Tel.: [phone]
Analytical Laboratory: Pace Analytical Services, LLC __State Certification No._ 12
Address: _9800 Kincey Avenue, Ste 100, Huntersville, NC 28078_Tel: [phone]

3. Information about Release
Date Discovered: April 20, 2014
Estimated Quantity of Release: Unknown
Cause of Release: Unknown
Source of Release (Dispenser/Piping/UST): Leaking UST System
Sizes and contents of UST system(s) from which the release occurred: One 2,000-gallon
waste oil UST
Criteria Used to Classify Risk: Risk Not Classified

4. Information about the Monitoring Report
Date(s) of Monitoring Well Installation Activities: January 3-10, 2023
Date(s) of Groundwater Monitoring/Soil Sampling Event(s): January 11 &12, 2023

5. Certification
I, Al Quarles, a Licensed Geologist for ATC Associates of North
Carolina, P.C., do certify that the information contained in this
report is correct and accurate to the best of my knowledge.

ATC Associates of North Carolina, P.C. is licensed to practice
engineering and geology in North Carolina. The certification
number of the company or corporation for engineering is C-1598.
The certification number of the company or corporation for geology
is C-294.
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2.0 EXECUTIVE SUMMARY
ATC Associates of North Carolina, P.C. (ATC) submits this Monitoring Report documenting soil
and groundwater assessment activities conducted during January and February 2023 associated
with the former Bob May’s Automotive Service Center site, located at 727 West Northwest
Boulevard, in Winston-Salem, North Carolina. The approved activities included the installation of
four new Type II monitoring wells, two new Type III monitoring wells, surface waer sampling, and
a comprehensive groundwater monitoring event. The report has been completed based on a
December 6, 2022, Task Authorization (TA-2) approved by the Trust Fund Branch of the
Underground Storage Tank (UST) Section, Division of Waste Management, North Carolina
Department of Environmental Quality (NCDEQ). Two Change Orders (#1 and #2) were approved
on January 10, 2023 for additional services associated with the discovery of a landfill on the
property and included the analysis of soil and groundwater for waste management and the off-
site disposal of investigative derived waste (IDW). The work was performed as part of the State
Lead Contract # N122019A between the NCDEQ and ATC.

A former waste oil UST was removed on April 20, 2014, and during the removal the tank sparked
and caught on fire. The NCDEQ was informed of the incident and based on reported staining on
the tank, a release of was suspected. Monitoring well MW-1 was installed on November 17, 2015
at the location of a fomer waste oil UST. Tetrachloroethane [PCE, a chlorinated volatile organic
compound (VOC)] were detected in the MW-1 sample at concentrations exceeding the 15A NCAC
02L groundwater quality standard (2L Standard) and the 15A NCAC 02B surface water quality
standard (2B Standard). Other chlorinated VOCs were reported at concentrations less than the
2L Standards and 2B Standards. Petroleum volatile organic compounds (VOCs) were not
detected in the MW-1 sample at concentrations exceeding the 2L Standards or the 15A NCAC
02B surface water quality standards (2B Standards). This assessment was conducted to evaluate
the extent of the chlorinated VOCs for possible closure of the incident. Based on field activities
conducted by ATC in January and February 2023 and previous assessment activities, the site
conditions are summarized below:

 No water supply wells are located within 1,000 feet of the source area;
 One surface water body (Peters Creek, a Class C stream) is located within 500 feet north-
northeast of the source area;
 New monitoring wells MW-2, MW-2D, MW-3, MW-3D, MW-4, and MW-5 were installed on the site
property in January 2023;
 Groundwater samples were collected from monitoring wells MW-1, MW-2, MW-2D, MW-3,
MW-3, MW-3D, MW-4, and MW-5 on January 11 and 12, 2023;
 Light Non-Aqueous Phase Liquid (LNAPL) was not detected in the monitoring wells during
the groundwater monitoring event;
 No volatile organic compounds (VOCs) were reported in the monitoring well samples at
concentrations exceeding the Gross Contamination Levels (GCLs);
 PCE was detected above the 2L Standard and the 2B Standard in monitoring well MW-1
(115 microgram per liter or µg/L);
 Trihalomethanes bromodichloromethane (3.0 µg/L) and dibromochloromethane (0.80 µg/L)
were reported in MW-3D at concentrations above their respective 2L Standards. Chloroform
was also reported in MW-3D at a concentration less than the 2L Standard. These three VOCs
may be associated with city water used for the drilling activities;
 Excluding the trihalomethanes in MW-3D, VOCs were not detected above the 2L Standards
or 2B Standards in wells MW-2, MW-2R, MW-3, MW-3D, MW-4, or MW-5;
 Groundwater flow is estimated to be to the northwest towards Peter’s Creek.
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 The depth to groundwater in the shallow monitoring wells ranged from 14.28 feet below top
of casing (ft-toc) in MW-1 to 16.52 ft-toc in MW-2.
 Bedrock was not encountered to a depth of approximately 50 feet below ground surface (ft-
bgs).
 Surface water samples were not collected due to the inability to access the stream from
the south side due to slopes, vegetation and debris, or from the north side due to the
inability to obtain access agreements with the property owners adjoining the site property;
 Buried debris was identified during drilling activites for wells MW-2, MW-2D, MW-3, MW-
3D, and MW-4. The area of these wells was determined to be a former landfill. Debris
(e.g., concrete) was observed along the bank of Peters Creek. Analysis of soil and
groundwater samples for waste characterization indicated the waste to be non-hazardous.
No VOCs, semi-volatile organic compounds (SVOCs), Appendix IX metal, dioxins, or
furans were reported above the NCDEQ, Division of Waste Management, Inactive
Hazardous Site Branch’s (IHSB) Preliminary Soil Remediation Goals (PSRGs), except for
methylene chloride and cobalt exceeding the Protection of Groundwater PRSGs and
arsenic exceeding the Residential PSRG.

The PCE detected in monitoring well MW-1 does not appear to have migrated to the property
boundaries or to Peters Creek. Based on the site conditions decribed above, ATC presents the
following recommendations:

 Close the UST incident 44319 and abandon the monitoring wells.
 Report the results to the IHSB for further evaluation of subsequent actions that may be
required relating to the discovered landfill.

3.0 SITE DESCRIPTION
3.1 Site Characterization
ATC, under contract to the NCDEQ, provided environmental consulting services at the former
Bob May’s Automotive Service Center site, located at 727 West Northwest Boulevard, in Winston-
Salem, North Carolina. Figure 1 depicts the site loctaion on a topographic map. The site formerly
operated as a auto repair facility, but is currently vacant. Based on information obtained during a
receptor survey conducted in 2016, there are no water supply wells located within 1,000 feet of
the site and one surface water body (Peters Creek, a Class C stream) is located within 500 feet
north-northeast of the source area.

3.2 Site Background
The former Bob May’s Automotive Service Center facility (the Site) is located at 727 West
Northwest Boulevard, in Winston-Salem, North Carolina. A February 2, 2016 Phase I Limited Site
Assessment Report, prepared by S&ME, Inc. for the NCDEQ included the results of soil and
groundwater sampling (from one location, boring and monitoring well MW-1) and a receptor
survey. The assessment was performed due to a former 2,000-gallon waste oil UST. The site
conditions are presented below:

 No water supply wells are located within 1,000 feet of the source area.
 One surface water body (Peters Creek) is located within 500 feet north-northeast of the
source area.
 The depth to groundwater was approximately 14 feet below ground surface, and based
on topography, groundwater flow is expected to flow to the north-northeast.
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 No exceedances of the Maximum Soil Contaminant Concentrations (MSCCs) were
identified in the soil.
 No exceedances of the GCLs were identified in the groundwater.
 PCE was detected in the groundwater at a concentration of 75 micrograms per liter (µg/L),
that exceeded the 2L Standard of 0.7 µg/L. No other contaminants were reported at
concentrations exceeding the 2L Standards.

On October 25, 2021, Withers & Ravenel sampled monitoring well MW-1, and the results
confirmed the presence and concentration of PCE at 74.3 µg/L.

On July 5 and 6, 2022, ATC conducted passive soil gas (PSG) sampling at the site for the
purposes of evaluating the potential source of the tetrachloroethene reported in the groundwater.
ATC installed twenty-three Beacon Samplers (PSG-1 through PSG-23). After installation, the
PSG Beacon Samplers remained in-place for at least 14 days prior to retrieval. On July 19-20,
2022, ATC returned to retrieve the PSG samplers. Multiple VOCs were reported in the PSG
samples. None of the VOC concentrations exceeded the established Non-Residential VISLs,
except for the Total Petroleum Hydrocarbons (TPH) C4-C9 and C10-C15.

Of note, the highest concentrations of PCE, trichloroethylene (TCE), and 1,1,1-trichloroethane
(1,1,1-TCA) were reported in the two samples nearest the former waste oil UST (samples PSG-
8 and PSG-11). VOC concentrations reported in the remaining PSG samples were much lower
than those detected in PSG-8 and PSG-11, including results reported as non-detects.

The location of the site and surrounding topography is depicted on Figure 1. The layout of the
site, the approximate location of existing monitoring well MW-1, and the approximate location of
the former waste oil UST is presented on Figure 2.

3.3 Site and Regional Geology

According to the Geologic Map of North Carolina (1985), According to the 1985 USGS Geologic
Map of North Carolina, and the 2016 LSA submitted by S&ME, the site is underlain by the Milton
Belt of the Piedmont Physiographic Province. Bedrock in this area is biotite gneiss and schist.
These are rocks that are inequigranular and megacrystic, with abundant potassic feldspar and
garnet. They are interlayered and gradational with calcsilicate rock, sillimanite-mica schist, mica
schist, and amphibolite. It also contains small masses of granitic rock.

Boring logs from recent shallow monitoring well installation activities conducted at the site indicate
that the site subsurface generally consists of light red to red-brown and tan to brown interbedded
layers of clay, silt, and silty clay to a depth of approximately 15 ft-bgs, and tan to brown clay to
clayey-silt 15 to 25 ft-bgs. Soils observed during the installation of the deep wells indicated soils
at depth consisted primarily of tan silt from approximately 35 to 50 ft-bgs. Bedrock was not
encountered to a depth of 50 ft-bgs.

3.4 Site and Regional Hydrogeology

The shallow aquifer occurrence varies in depth from ground surface at springs, creeks, and rivers
to as deep as 50 feet or more beneath upland surfaces in some parts of the Piedmont. Water in
the alluvium or unconsolidated residual material, including saprolite and PWR, usually behaves
as an unconfined aquifer, or water table, and will yield water with head elevation equivalent to the
first elevation where water was encountered. Permeability varies with lithology and is typically
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relatively low in residual soils, with higher permeability in saprolite or PWR due to relict rock
texture and variable susceptibility to weathering exhibited by different minerals in the rock.
Groundwater flow in residual soils or alluvium is usually in rough concurrence with local
topographic conditions and is toward local drainage features.

The bedrock fractures or other planar features of the Piedmont generally constitute the bedrock
aquifer, with the surrounding rock material being effectively impermeable. Along with fractures,
contacts between rock bodies probably constitute zones of significant groundwater occurrence in
the bedrock. The surrounding material and overlying residuum tend to make the bedrock aquifer
a semi-confined aquifer. That is, the overlying water and soil weight normally results in pressure
that causes water in a borehole, which intersects a fracture or other feature, to rise above the
elevation of the fracture or feature. Modern water supply wells in the Piedmont are typically
installed with a surface casing through the unconsolidated material, and an open borehole into
the bedrock where water-bearing fractures are encountered.

The January 11, 2023 depths to groundwater in the shallow wells ranged from 14.28 ft-toc in well
MW-1 to 16.52 ft-toc in well MW-2. Based on calculated groundwater elevations, the shallow
horizontal gradient was approximately 0.022 feet per foot to the northwest towards Peters Creek.
Groundwater elevations in the pair shallow and deep and MW-3/MW-3d, indicated an upward
vertical gradient for monitoring wells MW-2/MW-2D and a slight downward gradient for monitoring
wells MW-3/MW-3D.

4.0 POTENTIAL RECEPTORS
A February 2, 2016 Phase I Limited Site Assessment Report, prepared by S&ME, Inc. for the
NCDEQ included the results of soil and groundwater sampling (from one location, boring and
monitoring well MW-1) and a receptor survey. The assessment was performed due to a former
2,000-gallon waste oil UST. The site conditions are presented below:

 No water supply wells are located within 1,000 feet of the source area.
 One surface water body (Peters Creek) is located within 500 feet north-northeast of the
source area.

No other potential receptors were identified within 500 feet of the Site.

5.0 GROUNDWATER ASSESSMENT ACTIVITIES
5.1 Monitoring Well Installation
Between January 3 and 10, 2023, ATC supervised the installation of monitoring wells MW-2, MW-
2D, MW-3, MW-3D, MW-4, and MW-5. The locations of the wells are indicated on Figure 2. ATC
contracted with SAEDACCO, a North Carolina certified well contractor, to drill the borings and
install the monitoring wells.

The borings for the shallow monitoring wells were extended to depths of approximately 25 ft-bgs
using 4.25-inch inner diameter (ID) hollow stem augers (HSAs), with screened intervals of 10 to
25 ft-bgs. The borings for the deep wells MW-2D and MW-3D were drilled using 10-inch inner
diameter HSAs with 6-inch diameter schedule 40 PVC casing set to depths of approximately 35
and 38 ft-bgs, respectively. The deep well borings for wells MW-2D and MW-3D were extended
to depths of approximately 50 and 47 ft-bgs using a 6-inch nominal mud-rotary bit, with screen
intervals of 47 to 50 ft-bgs for well MW-2D and 42 to 47 ft-bgs for well MW-3D.
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The monitoring wells were were constructed of 2-inch diameter, Schedule 40 PVC screen (0.010-
inch slots) and Schedule 40 PVC riser to near land surface. Filtered sand was installed within the
annulus to approximately 2-feet above the top of the screens, with approximately 2-feet of
bentonite above the sand pack, and grout to near land surface. Each well was completed with a
2-foot-by-2-foot concrete pad, 8-inch diameter well vault, and capped with a lockable water-tight
cap.

The Type II monitoring wells were developed by SAEDACCO, utilizing a submersible Monsoon
pump and new tubing, by purging groundwater until turbidity was visibly reduced.

All IDW (soil cuttings, well development water, well purge water, and plastic used for the
decontamination of drilling equipment) was contained in 55-gallon drums. Samples of the
contained soil and water were collected and analyzed for waste characterization, as further
discusses in Section 6.0, Waste Management.

On February 1, 2023 (during the removal of the drummed IDW), ATC measured the top of casing
elevations of the new wells relative to monitoring well MW-1. Field notes of the field activities are
presented in Appendix A. Well construction records and wells logs with soil descriptions are
included in Appendix B.

5.2 Groundwater Levels
On January 11, 2023, ATC measured the depth to groundwater in monitoring wells MW-1, MW-
2, MW-3, MW-4, MW-5, MW-2D, and MW-3D. LNAPL was not identified in the monitoring wells.
The depths to groundwater in the shallow wells ranged from 14.28 ft-toc in well MW-1 to 16.52 ft-
toc in well MW-2. Groundwater elevations ranged from 86.26 feet in MW-5 to 82.79 feet in MW-2
(3.47 feet elevation difference). Based on these measurements, the shallow horizontal gradient
is calculated to be approximately 0.022 feet per foot to the northwest towards Peters Creek. The
groundwater elevations of MW-2 (82.79) and MW-2D (83.24) indicate an upward vertical gradient.
The groundwater elevations of MW-3 (83.38) and MW-3D (83.35) indicate a slight downward
vertical gradient. A summary of monitoring well construction and water level elevation data is
provided in Table 1. A map depicting groundwater elevations and estimated flow is provided as
Figure 3.

Field notes of the January 11, 2023, groundwater monitoring event are presented in Appendix
A.

5.3 Groundwater Quality
On January 11, 2023 and January 12, 2023, groundwater samples were collected from monitoring
wells MW-1, MW-2, MW-2D, MW-3, MW-3, MW-3D, MW-4, and MW-5. At least three standing
well volumes were purged from the monitoring wells, or purged until dry and allowed to recharge,
prior to groundwater sample collection to ensure a representative sample was collected. After
purging and prior to collecting groundwater samples, water quality parameters were measured.
Water quality parameters recorded prior to sample collection are included in Table 2.

The water samples were collected in laboratory-supplied, preserved containers; entered into
chain-of-custody control; placed on ice; and delivered to North Carolina-accredited Pace
Analytical (Pace) in Huntersville, North Carolina. A field blank was also collected and submitted
for laboratory analysis. The groundwater samples and field blank were analyzed for VOCs by
Standard Method 6200B. Groundwater samples from the shallow monitoring wells within the
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landfill area (MW-2, MW-3, and MW-4) were also analyzed for TCLP RCRA Metals for disposal
purposes as discussed in Section 6.0, Waste Management. The analytical report is included as
Appendix C.

The January 2023 groundwater analytical results are summarized in Table 3. This includes the
SM 6200B VOCs and the TCLP RCRA Metals. Six chlorinated VOCs were detected in monitoring
well MW-1, and the concentrations of those VOCs for each well are presented on Figure 4. The
groundwater analytical results were compared to 2L Standards, 2B Standards, and GCLs.
Groundwater analytical results from the January 2023 sampling event indicated the following:

 VOC concentrations did not exceed the GCLs;
 Three VOCs were reported in the sample from MW-3D: trihalomethanes chloroform (less
than the 2L Standard) and bromodichloromethane and dibromochloromethane (above the
2L Standards). These VOCs may be the mud-rotary drilling activities that utilized municipal
water;
 PCE (115 µg/L) was reported in MW-1 at a concentration that exceeds the 2L Standard and
the 2B Standard (0.7 µg/L for both). The PCE concentration increased by approximately
55% from the October 25, 2021 sample results; and
 VOCs were not reported in wells MW-2, MW-2D, MW-3, MW-3, MW-3D, MW-4, and MW-
5 above the 2L Standards (excluding the trihalomethanes in MW-3D) or 2B Standards.

As part of ATC’s quality assurance and quality control (QA and QC) measures, a data review of
the laboratory report was conducted. During the review, it was found that the samples were
received from the laboratory in acceptable condition and properly preserved. The chain-of-
custody was properly completed by all parties. The samples were analyzed within correct holding
times and reported within the lab report.

The laboratory QC reports show that internal blanks were analyzed for the requested analytical
methods for the groundwater samples submitted. The laboratory fortified blank (LFB) and
laboratory control sample (LCS) data results were also provided for the requested analytical
methods. A field blank (FB) was also collected during the groundwater monitoring event and
analyzed for VOCs by EPA Method 6200B. Laboratory analysis of the field blank did not indicate
VOCs above laboratory method detection limits. Refer to the laboratory report in Appendix C for
details regarding QA results for the laboratory samples and any noted exceptions. Overall, ATC
concludes that the laboratory results are usable and any exceptions do not significantly impact
the conclusions presented in this report.

6.0 WASTE MANAGEMENT
Due to the drilling through landfill debris that was unknown and uncharacterized, ATC collected
composite soil samples of the soil cuttings from the depths of 0 to 10 ft-bgs and greater than 10
ft-bgs. The analyses included VOCs by EPA Method 8260 for both samples. The >10-foot sample
was also analyzed for pesticides by EPA Method 8081, Appendix iX herbicides by Method
SW8151, polychlorinated biphenyls (PCBs by EPA Method 8082, Appendix IX Metals by EPA
Mehods 6010/7471, SVOCs by EPA Method 8270, sulfides by SM 4500S2D, cyanide by SM
4500CNE, and for dioxins and furans [polychlorodibenzo-p-dioxins (PCDDs) and
polychlorodibenzofurans (PCDFs)] for the >10-ft sample by EPA Method 8290. The results are
summarized below, and presented in Table 4.

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 0-10-ft-bgs sample: VOCs (naphthalene, toluene, p-isopropyltoluene, and PCE) were
reported at concentrations less than the lowest PSRG.
 1>10-ft-bgs sample:
o Pesticides, herbicides, PCBs, SVOCs, sulfide, cyanide, and furans were not
detected.
o One VOC (methylene chloride) was reported at an estimated concentration of
0.026 milligrams per kilogram (mg/kg) that exceeding the Protection of
Groundwater PSRG of 0.025 mg/kg.
o Two metals were reported at concentrations exceeding the Residential PSRG
(arsenic at 1.1 mg/kg) and the Protection of Groundwater PSRG (cobalt at 4.4
mg/kg).
o Dioxin (total HxCDD) was reported at a concentration of 2.9x10-6 mg/kg, less than
the lowest PSRG of 1.0x10-4 mg/kg.

Based on the soil samples results, water samples from wells MW-2, MW-3, and MW-4 were also
analyzed for RCRA Metals following the TCLP method for waste characterization. Barium was
reported in all three samples and cadmium was reported in the MW-4 sample (Table 3). The
concentrations were less than the hazardous waste limits.

Copies of the laboratory reports are included in Appendix C. Copies of the waste profiles for the
IDW (solids, water, and plastic) are included in Appendix D.

On February 1, 2023, A&D Environmental removed the drummed IDW: nine drums of liquid, 25
drums of solid/drilling mud, and one drum of plastic waste. A&D Environmental transported the
waste to their Archdale, North Carolina facility. A copy of the “Bill of Lading / Material Manifest” is
also included in Appendix D.

7.0 CONCLUSIONS AND RECOMMENDATIONS
ATC Associates of North Carolina, P.C. (ATC) submits this Monitoring Report documenting soil
and groundwater assessment activities conducted during January and February 2023 associated
with the former Bob May’s Automotive Service Center site, located at 727 West Northwest
Boulevard, in Winston-Salem, North Carolina.

 No water supply wells are located within 1,000 feet of the source area;
 One surface water body (Peters Creek, a Class C stream) is located within 500 feet north-
northeast of the source area;
 New monitoring wells MW-2, MW-2D, MW-3, MW-3D, MW-4, and MW-5 were installed on the site
property in January 2023;
 Groundwater samples were collected from monitoring wells MW-1, MW-2, MW-2D, MW-3,
MW-3, MW-3D, MW-4, and MW-5 on January 11 and 12, 2023;
 LNAPL was not detected in the monitoring wells during the groundwater monitoring event;
 No VOCs were reported in the monitoring well samples at concentrations exceeding the
GCLs;
 PCE was detected above the 2L Standard and the 2B Standard in monitoring well MW-1
(115 µg/L);
 Trihalomethanes bromodichloromethane (3.0 µg/L) and dibromochloromethane (0.80 µg/L)
were reported in MW-3D at concentrations above their respective 2L Standards. Chloroform
was also reported in MW-3D at a concentration less than the 2L Standard. These three VOCs
may be associated with city water used for the drilling activities;
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 Excluding the trihalomethanes in MW-3D, VOCs were not detected above the 2L Standards
or 2B Standards in wells MW-2, MW-2R, MW-3, MW-3D, MW-4, or MW-5;
 Groundwater flow is estimated to be to the northwest towards Peter’s Creek.
 The depth to groundwater in the shallow monitoring wells ranged from 14.28 ft-toc in MW-1
to 16.52 ft-toc in MW-2.
 Bedrock was not encountered to a depth of approximately 50 ft-bgs.
 Surface water samples were not collected due to the inability to access the stream from
the south side due to slopes, vegetation and debris, or from the north side due to the
inability to obtain access agreements with the property owners adjoining the site property;
 Buried debris was identified during drilling activites for wells MW-2, MW-2D, MW-3, MW-
3D, and MW-4. The area of these wells was determined to be a former landfill. Debris
(e.g., concrete) was observed along the bank of Peters Creek. Analysis of soil and
groundwater samples for waste characterization indicated the waste to be non-hazardous.
No VOCs, SVOCs, Appendix IX metal, dioxins, or furans were reported above the
NCDEQ, Division of Waste Management, Inactive Hazardous Site Branch’s Preliminary
Soil Remediation Goals (PSRGs), except for methylene chloride and cobalt exceeding the
Protection of Groundwater PRSGs and arsenic exceeding the Residential PSRG.

The PCE detected in monitoring well MW-1 does not appear to have migrated to the property
boundaries or to Peters Creek. Based on the site conditions decribed above, ATC presents the
following recommendations:

 Close the UST incident 44319 and abandon the monitoring wells.
 Report the results to the IHSB for further evaluation of subsequent actions that may be
required relating to the discovered landfill.

TABLES
Table 1
Well Construction and Groundwater Level Data
Former Bob May's Automotive Service Center (Incident # 44319)
727 West Northwest Boulevard
Winston-Salem, Forsyth County, North Carolina 27101
Well ID Date
Installed
Well Casing
Diameter
(in)
Screen
Interval
(ft-bgs)
Depth of Well
(ft-bgs)
Ground
Elevation
(ft)
Top of
Casing
Elevation
(ft)
Date Water
Level
Measured
Depth to
Water
(ft-toc)
Ground
water
Elevation
(ft)
MW-1 11/17/15 2 8 - 18 18 100.55 100.00 1/11/23 14.28 85.72
MW-2 01/05/23 2 10 - 25 25 99.68 99.31 1/11/23 16.52 82.79
MW-2D 01/10/23 2 47 - 50 50 99.65 99.39 1/11/23 16.15 83.24
MW-3 01/05/23 2 10 - 25 25 99.10 98.88 1/11/23 15.50 83.38
MW-3D 01/10/23 2 42 - 47 47 99.41 99.19 1/11/23 15.84 83.35
MW-4 01/03/23 2 10 - 25 25 99.85 99.56 1/11/23 14.42 85.14
MW-5 01/03/23 2 10 - 25 25 101.27 100.76 1/11/23 14.50 86.26
Notes:
ft-bgs: feet below ground surface
ft: feet
in: inches
TOC: top of casing
Table 2
Field Parameters
Former Bob May's Automotive Service Center (Incident # 44319)
727 West Northwest Boulevard
Winston-Salem, Forsyth County, North Carolina 27101
Well ID Sample Date Temperature
(°C)
pH
(su)
ORP
(mV)
Conductivity
(mS/cm)
Dissolved
Oxygen
(mg/L)
MW-1 01/12/23 18.58 4.8 306 0.50 7.4
MW-2 01/11/23 14.18 6.5 264 0.42 0.9
MW-2D 01/12/23 17.61 7.3 210 0.52 3.0
MW-3 01/11/23 16.63 5.2 43 0.23 1.4
MW-3D 01/11/23 20.60 9.1 109 0.74 5.8
MW-4 01/11/23 18.04 5.0 302 0.40 2.8
MW-5 01/12/23 17.64 5.5 288 0.33 4.7
Notes:
°C = degrees Celsius
su = standard units
ORP = oxidation-reduction potential
mV = millivolts
mS/cm = milliSiemens per centimeter
mg/L = milligrams per liter
Table 3
Summary of Groundwater Analytical Results
Former Bob May's Automotive Service Center (Incident # 44319)
727 West Northwest Boulevard
Winston-Salem, Forsyth County, North Carolina 27101
Analytical Method SM 6200B EPA 6010D *
Constituent of
Concern
BromodichloromethaneChloroformDibromochloromethane1,1-Dichloroethane1,2-Dichloroethane1,1-Dichloroethenecis-1,2-DichloroetheneDi-isopropyl etherMethyl-tert-butyl etherTetrachloroetheneTrichloroethene1,1,1-TrichloroethaneBariumCadmiumDate
Collected
(mm/dd/yy)
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/L mg/L
12/4/2015 <0.5 <0.5 <0.5 3.2 0.29J 2.7 3.4 0.31J 0.46J 75 1.3 120 N/A N/A
10/25/2021 <0.5 <0.5 <0.5 3.92 <0.5 1.77 1.37 <0.5 <0.5 74.3 0.966 41.6 N/A N/A
01/12/2023 <0.5 <0.5 <0.5 4.2 <0.5 2.7 1.0 <0.5 <0.5 115 0.98 39.8 N/A N/A
MW-2 01/11/2023 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0.044J <0.00014
MW-2D 01/12/2023 <0.5 1.9 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 N/A N/A
MW-3 01/11/2023 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0.050J <0.00014
MW-3D 01/11/2023 3.0 17.0 0.80 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 N/A N/A
MW-4 01/11/2023 <0.5 0.52 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0.87 0.00030J
MW-5 01/12/2023 <0.5 0.56 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 N/A N/A
0.6 70 0.4 6 0.4 350 70 70 20 0.7 3 200 NA NA
NE 2000 21 100 650 20000 720 20000 1500 0.7 2.5 2500 NA NA
NE 70,000 400 6,000 400 350,000 70,000 70,000 20,000 700 3,000 600 NA NA
Notes:
µg/L: Micrograms per liter
mg/L: Milligrams per liter
<#: Less than Laboratory Reporting Limit
2L Standard: 15A NCAC 02L .0202 groundwater quality standard
2B Standard: 15A NCAC 02B surface water quality standard (lower of the freshwater Class C or Aquatic Life & Secondary Recreation values)
GCL: Gross Contamination Level
*: EPA 6010D analyses following TCLP extraction, for disposal purposes. Regulatory levels not applicable for this analytical method.
N/A: Not Analyzed
NE: Not Established
Sample ID
2L Standard
GCL
MW-1
2B Standard
Table 4
Summary of Soil Analytical Results
Former Bob May's Automotive Service Center (Incident # 44319)
727 West Northwest Boulevard
Winston-Salem, Forsyth County, North Carolina 27101
Analytical Method EPA 8260D EPA 6010 EPA 7471 EPA 8290
Constituent of
Concern
Methylene ChlorideNaphthaleneTetrachloroetheneToluenep-IsopropyltolueneArsenicBariumBerylliumCadmiumChromiumCobaltCopperLeadNickelTinVanadiumZincMercuryTotal HxCDDDate
Collected
(mm/dd/yy)
mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg
0-10 01/05/2023 <0.018 0.021 0.0043J 0.0063J 0.0043J N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
>10 01/05/2023 0.026J 0.036 <0.0022 <0.0020 <0.0034 1.1 64 0.89 0.56 18.9 4.4 13.5 36.6 7.5 7.5 24.1 404 0.078 2.9E-06
0.023 0.2 0.005 5.4 0.12 N/A 620 N/A N/A 360,000 N/A N/A 270 N/A N/A N/A N/A N/A N/A
93.8 5.5 93.8 1,250 1,560 N/A 3,100 N/A N/A 23,400 N/A N/A 400 N/A N/A N/A N/A N/A N/A
1,400 27 1,400 18,600 23,300 N/A 46,000 N/A N/A 350,000 N/A N/A 400 N/A N/A N/A N/A N/A N/A
Residential PSRG 58 2.1 17 990 N/A 0.68 3,100 31 1.4 23,000 4.7 630 N/A 310 9,400 78 4,700 2.3 1.0E-04
Industrial/Commercial PSRG 650 8.8 82 9,700 N/A 3 47,000 470 20 350,000 70 9,300 N/A 4,700 140,000 1,200 70,000 9.7 4.7E-04
Protection of Groundwater PSRG 0.025 0.39 0.0063 8.3 N/A 5.8 580 63 3 360,000 0.9 700 270 130 10,000 140 1,200 1 1.6E-04
Notes:
Soil samples collected for waste characterization, composite of soil cuttings during well installation activities
mg/kg: Milligrams per kilogram
MSCC: UST Section Maximum Soil Contaminant Concentration
PSRG: Inactive Hazardous Sites Branch Preliminary Soil Remediation Goals
Values for chromium assumed to be for triavalent chromium
HxCDD: Hexachlorodibenzo-p-dioxin, Mixture
N/A: Not Analyzed
NE: Not Established
Sample ID
Soil to Groundwater MSCC
Residential MSCC
Industrial/Commercial MSCC

FIGURES
SITE LOCATION MAP
1"= 2,000'
1
Project Number:
Date:Scale:
Drawing File:
Figure:
App'd By:
Drn. By:
Ckd. By:
N
H:\2023\1 OTHER OFFICES\NORTH CAROLINA\NCDEQ-STATE LEAD\FORMER BOB MAY'S\SLC4431902-VIC.DWG, FIG102/02/2023
SEE LOWER LEFT
FORMER BOB MAY'S AUTOMOTIVE SERVICE CENTER
727 WEST NORTHWEST BOULEVARD
WINSTON-SALEM, NORTH CAROLINA
SLC4431902 BM
AQ
AQ
SITE
NORTHW
E
S
T
BOU
L
EVAR
D
10SCALE: 1" = 30'02030NAPPROXIMATE LOCATION OFFORMER 1,000 GAL. WASTE OIL USTMW-1MW-2MW-2DMW-3MW-3DMW-4MW-5LEGEND:SITE PROPERTY LINENOTE: ALL LOCATIONS ARE APPROXIMATEPARCEL LINEMW-2SHALLOW MONITORING WELLWell IdentificationMW-2DDEEP MONITORING WELLWell IdentificationSTREAMFigure:Drawing File:
Project Number:
Ckd. By:
Drn. By:
App'd By:
Ckd. Date:Scale:Date:H:\2023\1 OTHER OFFICES\NORTH CAROLINA\NCDEQ-STATE LEAD\FORMER BOB MAY'S\SLC4431902-SITE.DWG, FIG2
SITE MAP02/27/2023SEE LOWER LEFTFORMER BOB MAY'S AUTOMOTIVE SERVICE CENTER
727 WEST NORTHWEST BOULEVARD
WINSTON-SALEM, NORTH CAROLINA
SLC4431902AS SHOWNBM
AQ2NOTES:
1.Features shown are not an authoritative location, nor are they presented
to a stated accuracy.
COORDINATE SYSTEM:
NAD 1983 NORTH CAROLINA STATE PLANE FIPS 3200, US SURVEY FEET
SITE
NORTHW
E
S
T
BOU
L
EVAR
D
10SCALE: 1" = 30'02030NLEGEND:SITE PROPERTY LINENOTE: ALL LOCATIONS ARE APPROXIMATEPARCEL LINEAPPROXIMATE LOCATION OFFORMER 1,000 GAL. WASTE OIL USTMW-1MW-2MW-2DMW-3MW-3DMW-5MW-2DDEEP MONITORING WELLWell IdentificationSTREAM83.388383.584
84
.
5
8
5
8
5
.
5
86 82.7985.1485.7286.2683GROUNDWATER ELEVATION CONTOUR(DASHED WHERE INFERRED) (ft)GROUNDWATER FLOW DIRECTIONMW-282.79SHALLOW MONITORING WELLWell IdentificationRelative Groundwater Elevation (ft)MW-4Figure:Drawing File:
Project Number:
Ckd. By:
Drn. By:
App'd By:
Ckd. Date:Scale:Date:H:\2023\1 OTHER OFFICES\NORTH CAROLINA\NCDEQ-STATE LEAD\FORMER BOB MAY'S\SLC4431902-POT.DWG, FIG3
GROUNDWATER ELEVATION
CONTOUR MAP02/27/2023SEE LOWER LEFTFORMER BOB MAY'S AUTOMOTIVE SERVICE CENTER
727 WEST NORTHWEST BOULEVARD
WINSTON-SALEM, NORTH CAROLINA
SLC4431902AS SHOWNBM
AQ3NOTES:
1.Features shown are not an authoritative location, nor are they presented
to a stated accuracy.
COORDINATE SYSTEM:
NAD 1983 NORTH CAROLINA STATE PLANE FIPS 3200, US SURVEY FEET
SITE
NORTHW
E
S
T
BOU
L
EVAR
D
10SCALE: 1" = 30'02030NLEGEND:SITE PROPERTY LINENOTE: ALL LOCATIONS ARE APPROXIMATEPARCEL LINEAPPROXIMATE LOCATION OFFORMER 1,000 GAL. WASTE OIL USTMW-2SHALLOW MONITORING WELLWell IdentificationMW-2DMW-3DMW-2DDEEP MONITORING WELLWell IdentificationSTREAMMW-1MW-2MW-3MW-5MW-4Figure:Drawing File:
Project Number:
Ckd. By:
Drn. By:
App'd By:
Ckd. Date:Scale:Date:H:\2023\1 OTHER OFFICES\NORTH CAROLINA\NCDEQ-STATE LEAD\FORMER BOB MAY'S\SLC4431902-GW.DWG, FIG4
CONTAMINANTS OF CONCERN MAP02/27/2023SEE LOWER LEFTFORMER BOB MAY'S AUTOMOTIVE SERVICE CENTER
727 WEST NORTHWEST BOULEVARD
WINSTON-SALEM, NORTH CAROLINA
SLC4431902AS SHOWNBM
AQ4NOTES:
1.Features shown are not an authoritative location, nor are they presented
to a stated accuracy.
COORDINATE SYSTEM:
NAD 1983 NORTH CAROLINA STATE PLANE FIPS 3200, US SURVEY FEET

APPENDIX A
FIELD NOTES AND PHOTOGRAPHS
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLC4431902
REVIEWED BY: AQ SCALE: NTS DATE: 2/2023
Former Bob May’s Auto Service
727 West Northwest Boulevard
Winston Salem, Forsyth County, NC 27101
NCDEQ UST Incident #44319
Photo #2: View of utility work facing West Northwest Boulevard
from MW-4 location (1/3/2023)
Photo #1: View from back of Former Bob May’s Auto Service (site)
over-looking Peters Creek (facing northwest) (1/3/2023)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLC4431902
REVIEWED BY: AQ SCALE: NTS DATE: 2/2023
Former Bob May’s Auto Service
727 West Northwest Boulevard
Winston Salem, Forsyth County, NC 27101
NCDEQ UST Incident #44319
Photo #4: View from drum staging area behind site facing northwest towards Peters
Creek (1/3/2023)
Photo #3: Side and back of site facing towards the northwest (1/3/2023)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLC4431902
REVIEWED BY: AQ SCALE: NTS DATE: 2/2023
Former Bob May’s Auto Service
727 West Northwest Boulevard
Winston Salem, Forsyth County, NC 27101
NCDEQ UST Incident #44319
Photo #6: MW-3 and MW-3D area prior to installation (1/13/2023)
Photo #5: MW-4 during construction facing northeast
towards adjacent property (1/3/2023)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLC4431902
REVIEWED BY: AQ SCALE: NTS DATE: 2/2023
Moody’s Grocery
912 Old Highway 21
State Road, Wilkes County, NC 28676
NCDEQ UST Incident # 22446
Photo #8: Northeast side of Former Bob May’s Auto Building (1/6/2023)
Photo #7: MW-4 during construction facing West Northwest Boulevard
to the southeast (1/3/2023)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLC4431902
REVIEWED BY: AQ SCALE: NTS DATE: 2/2023
Former Bob May’s Auto Service
727 West Northwest Boulevard
Winston Salem, Forsyth County, NC 27101
NCDEQ UST Incident #44319
Photo #10: MW-3 drilling activities (1/5/2023)
Photo #9: MW-3 drilling activities (1/5/2023)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLC4431902
REVIEWED BY: AQ SCALE: NTS DATE: 2/2023
Former Bob May’s Auto Service
727 West Northwest Boulevard
Winston Salem, Forsyth County, NC 27101
NCDEQ UST Incident #44319
Photo #12: MW-3 drilling activities (1/5/2023)
Photo #11: MW-2 drilling activities (1/5/2023)
)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLC4431902
REVIEWED BY: AQ SCALE: NTS DATE: 2/2023
Former Bob May’s Auto Service
727 West Northwest Boulevard
Winston Salem, Forsyth County, NC 27101
NCDEQ UST Incident #44319
Photo #14: Closeup of MW-2 (1/12/2023)
Photo #13: MW-1 facing toward the West towards the Former Bob May’s Auto Service Building (1/12/2023)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLC4431902
REVIEWED BY: AQ SCALE: NTS DATE: 2/2023
Former Bob May’s Auto Service
727 West Northwest Boulevard
Winston Salem, Forsyth County, NC 27101
NCDEQ UST Incident #44319
Photo #16: MW-3D facing towards the northeast (1/13/2023)
Photo #15: MW-3 facing towards the north (1/12/2023)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLC4431902
REVIEWED BY: AQ SCALE: NTS DATE: 2/2023
Former Bob May’s Auto Service
727 West Northwest Boulevard
Winston Salem, Forsyth County, NC 27101
NCDEQ UST Incident #44319
Photo #18: MW-5 facing toward the Southeast (1/13/2023)
Photo #17: MW-4 facing toward the Northeast (1/12/2023)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLC2244602
REVIEWED BY: AQ SCALE: NTS DATE: 2/2023
Former Bob May’s Auto Service
727 West Northwest Boulevard
Winston Salem, Forsyth County, NC 27101
NCDEQ UST Incident #44319
Photo #20: Closeup of bank to Peters Creek, note debris (1/3/2023)
Photo #19: View from Peters Creek (1/3/2023)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLC4431902
REVIEWED BY: AQ SCALE: NTS DATE: 2/2023
Former Bob May’s Auto Service
727 West Northwest Boulevard
Winston Salem, Forsyth County, NC 27101
NCDEQ UST Incident #44319
Photo #22: Strips of rubber found in MW-4 boring (1/13/2023)
Photo #21: View from landfill debris (concrete, tile, brick) in auger boring (1/3/2023)

APPENDIX B
WELL LOGS AND WELL CONSTRUCTION RECORDS

02-28-2023 S:\NCDENR State Lead Contract\PM - Scott\Bob Mays Auto Service 44319\WellConstructionRecords\MW-2.borClient: NCDEQ State Lead Program
ATC Project No. SLC4431902
Winston-Salem, NC 27101
727 West Northwest Boulevard
Former Bob May's Automotive Service Center
ft bgs = ft below ground surface
PID = Photoionization Detector
ppm = parts per million
MONITORING WELL: MW-2
(Page 1 of 1)
Date(s) Drilled : 1/5/23
Drilling Conractor : SAEDACCO
Drilling Method : Hand Auger (HA)
: Hollow-Stem Auger (HSA)
Boring Diameter : HA = 3.25"
: HSA = 8.25"
Logged By : J. A. Cooper
Depth in Feet0
2
4
6
8
10
12
14
16
18
20
22
24
26 USCSCL
CL
ML GRAPHICDESCRIPTION
Red, moist, CLAY
Tan, wet, CLAY
Tan, wet, SILT
End of Boring PID(ppm)1
2
2
1
Elev.: 99.31
Well: MW-2
Grout
Bentonite
Sand
Cover
2" Diameter Casing
Screen
Zach Thompson
4478A
SAEDACCO Inc
X
1/5/2023 MW-2
Former Bob May's Automotive
727 W. Northwest Blvd., Winston-Salem, NC, 27101
Forsyth
36.106159 -80.254428
X
X
1
25
8.25"
HSA
0 10 2"SCH-40 PVC
10 25 2".010 SCH-40 PVC
0 6 Portland CementInjection
8 25 Filtered Sand #2
0 25 Tan/brown silty sand
Bentonite seal from 6-8'
1/7/2023
02-28-2023 S:\NCDENR State Lead Contract\PM - Scott\Bob Mays Auto Service 44319\WellConstructionRecords\MW-2D.borClient: NCDEQ State Lead Program
ATC Project No. SLC4431902
Winston-Salem, NC 27101
727 West Northwest Boulevard
Former Bob May's Automotive Service Center
PID = Photoionization Detector
ft-bgs = Feet Below Ground Surface
ppm = parts per million
MONITORING WELL: MW-2D
(Page 1 of 1)
Date(s) Drilled : 1/4/23 - 1/10/23
Drilling Contractor : SAEDACCO
Drilling Method : Hollow Stem Auger/ Mud Rotary
Boring Diameter : Inner Diameter = 6.0"
: Outer Diameter = 11"
Logged By : J.A. Cooper
Depth (ft-bgs)0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
34
36
38
40
42
44
46
48
50
52 USCSCL
CL
ML GRAPHICDESCRIPTION
Red, moist, CLAY
Tan, wet, CLAY
Tan, wet, SILT
End of Boring
PID
(ppm)
1
2
2
1
1
1
1
1
Elev.: 99.39
Well: MW-2D
Grout
Bentonite
Filter Sand
OuterCasing
Cover
Inner Casing
Well Screen
Stefan Smith
3576A
SAEDACCO Inc
X
1/10/2023 MW-2D
Former Bob May's Automotive
727 W. Northwest Blvd., Winston-Salem, NC, 27101
Forsyth
36.106183 80254378
X
X
1
50
6"
Mud
0 35 6"SCH-40 PVC
0 47 2"SCH-40 PVC
47 50 2"010 SCH-40 PVC
0 35 Portland CementTremie
0 43 Portland CementTremie
45 50 Sand 2
mud rotary drill out; bentonite seal from
43-45'
1/16/2023
02-28-2023 S:\NCDENR State Lead Contract\PM - Scott\Bob Mays Auto Service 44319\WellConstructionRecords\MW-3.borClient: NCDEQ State Lead Program
ATC Project No. SLC4431902
Winston-Salem, NC 27101
727 West Northwest Boulevard
Former Bob May's Automotive Service Center
ft bgs = ft below ground surface
PID = Photoionization Detector (See MW-3D)
ppm = parts per million
MONITORING WELL: MW-3
(Page 1 of 1)
Date(s) Drilled : 1/5/23
Drilling Conractor : SAEDACCO
Drilling Method : Hand Auger (HA)
: Hollow-Stem Auger (HSA)
Boring Diameter : HA = 3.25"
: HSA = 8.25"
Logged By : J. A. Cooper
Depth in Feet0
2
4
6
8
10
12
14
16
18
20
22
24
26 USCSML GRAPHICDESCRIPTION
Light-Brown, dry, SILT
No Recovery
End of Boring PID(ppm)1
2
2
1
Elev.: 98.88
Well: MW-3
Grout
Bentonite
Sand
Cover
2" Diameter Casing
Screen
Zach Thompson
4478A
SAEDACCO Inc
X
1/5/2023 MW-3
Former Bob May's Automotive
727 W. Northwest Blvd., Winston-Salem, NC, 27101
Forsyth
36.106271 -80.254272
X
X
1
25
8.25"
HSA
0 10 2"SCH-40 PVC
10 25 2".010 SCH-40 PVC
0 6 Portland CementInjection
8 25 Filtered Sand #2
0 25 Tan/brown silty sand
Bentonite seal from 6-8'
1/7/2023
02-28-2023 S:\NCDENR State Lead Contract\PM - Scott\Bob Mays Auto Service 44319\WellConstructionRecords\MW-3D.borClient: NCDEQ State Lead Program
ATC Project No. SLC4431902
Winston-Salem, NC 27101
727 West Northwest Boulevard
Former Bob May's Automotive Service Center
PID = Photoionization Detector
ft-bgs = Feet Below Ground Surface
ppm = parts per million
MONITORING WELL: MW-3D
(Page 1 of 1)
Date(s) Drilled : 1/2/23 - 1/10/23
Drilling Contractor : SAEDACCO
Drilling Method : Hollow Stem Auger/ Mud Rotary
Boring Diameter : Inner Diameter = 6.0"
: Outer Diameter = 11"
Logged By : J.A. Cooper
Depth (ft-bgs)0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
34
36
38
40
42
44
46
48
50 USCSML
CL
CL
SP GRAPHICDESCRIPTION
Brown, dry, SANDY SILT
Red-Brown, moist, SILTY CLAY
Light-Red, moist, CLAY
Light Brown, wet, SAND
Not recorded, mud rotary
End of Boring
PID
(ppm)
1
1
1
2
1
0.2
0.3
Elev.: 99.19
Well: MW-3D
Grout
Bentonite
Filter Sand
OuterCasing
Cover
Inner Casing
Well Screen
Stefan Smith
3576A
SAEDACCO Inc
X

1/10/2023 MW-3D
Former Bob May's Automotive
727 W. Northwest Blvd., Winston-Salem, NC, 27101
Forsyth
36.106183 80254378
X
X
1
47
6"
Mud
0 38 6"SCH-40 PVC
0 42 2"SCH-40 PVC
42 47 2".010 SCH-40 PVC
0 38 Portland CementTremie
0 38 Portland CementTremie
40 47 Sand 2
mud rotary drill out; bentonite seal from
38-40'
1/16/2023
02-28-2023 S:\NCDENR State Lead Contract\PM - Scott\Bob Mays Auto Service 44319\WellConstructionRecords\MW-4.borClient: NCDEQ State Lead Program
ATC Project No. SLC4431902
Winston-Salem, NC 27101
727 West Northwest Boulevard
Former Bob May's Automotive Service Center
ft bgs = ft below ground surface
PID = Photoionization Detector
ppm = parts per million
MONITORING WELL: MW-4
(Page 1 of 1)
Date(s) Drilled : 1/3/23
Drilling Conractor : SAEDACCO
Drilling Method : Hand Auger (HA)
: Hollow-Stem Auger (HSA)
Boring Diameter : HA = 3.25"
: HSA = 8.25"
Logged By : J. A. Cooper
Depth in Feet0
2
4
6
8
10
12
14
16
18
20
22
24
26 USCSCL
CL
CL
CL
CL GRAPHICDESCRIPTION
Red, moist, SILTY CLAY
Brown, dry, SILTY CLAY, with layers of rubber membrane
Brown, dry, SILTY CLAY
Tan-Brown, moist, CLAY
Tan, wet, CLAY
End of Boring PID(ppm)15
8
NM
10
Elev.: 99.56
Well: MW-4
Grout
Bentonite
Sand
Cover
2" Diameter Casing
Screen
Zach Thompson
4478A
SAEDACCO Inc
X
1/3/2023 MW-4
Former Bob May's Automotive
727 W. Northwest Blvd., Winston-Salem, NC, 27101
Forsyth
36.106196 -80.253932
X
X
1
25
8.25"
HSA
0 10 2"SCH-40 PVC
10 25 2".010 SCH-40 PVC
0 6 Portland CementInjection
8 25 Filtered Sand #2
0 25 Tan/brown silty sand
Bentonite seal from 6-8'
1/7/2023
02-28-2023 S:\NCDENR State Lead Contract\PM - Scott\Bob Mays Auto Service 44319\WellConstructionRecords\MW-5.borClient: NCDEQ State Lead Program
ATC Project No. SLC4431902
Winston-Salem, NC 27101
727 West Northwest Boulevard
Former Bob May's Automotive Service Center
ft bgs = ft below ground surface
PID = Photoionization Detector
ppm = parts per million
MONITORING WELL: MW-5
(Page 1 of 1)
Date(s) Drilled : 1/3/23
Drilling Conractor : SAEDACCO
Drilling Method : Hand Auger (HA)
: Hollow-Stem Auger (HSA)
Boring Diameter : HA = 3.25"
: HSA = 8.25"
Logged By : J. A. Cooper
Depth in Feet0
2
4
6
8
10
12
14
16
18
20
22
24
26
28 USCSCL
CL
CL
CL
ML GRAPHICDESCRIPTION
Red, moist, SILTY CLAY
Brown, dry, SILTY CLAY
Light-brown, dry, SILTY CLAY
Light-brown, wet, CLAY
Light-brown to tan, moist, CLAYEY SILT
End of Boring PID(ppm)8
5
8
6
Elev.: 100.76
Well: MW-5
Grout
Bentonite
Sand
Cover
2" Diameter Casing
Screen
Zach Thompson
4478A
SAEDACCO Inc
X
1/3/2023 MW-5
Former Bob May's Automotive
727 W. Northwest Blvd., Winston-Salem, NC, 27101
Forsyth
36.106014 -80.253932
X
X
1
25
8.25"
HSA
0 10 2"SCH-40 PVC
10 25 2".010 SCH-40 PVC
0 6 Portland CementInjection
8 25 Filtered Sand #2
0 25 Tan/brown silty sand
Bentonite seal from 6-8'
1/7/2023

APPENDIX C
LABORATORY ANALYTICAL REPORTS

#=CL#
January 27, 2023
LIMS USE: FR - AL QUARLES
LIMS OBJECT ID: 92646727
92646727
Project:
Pace Project No.:
RE:
Al Quarles
ATC Group Services LLC
7606 Whitehall Executive Cente
Suite 800
Charlotte, NC 28273
BOB MAY'S SLC4431902 APP IX
Dear Al Quarles:
Enclosed are the analytical results for sample(s) received by the laboratory on January 12, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
Some analyses were subcontracted outside of the Pace Network. The test report from the external subcontractor is
attached to this report in its entirety.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor M Cannon
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 32
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 32
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Lab ID Sample ID Matrix Date Collected Date Received
92646727001 MW1 Water 01/12/23 11:00 01/12/23 15:49
92646727002 MW2 Water 01/11/23 14:15 01/12/23 15:49
92646727003 MW3 Water 01/11/23 14:45 01/12/23 15:49
92646727004 MW4 Water 01/11/23 16:35 01/12/23 15:49
92646727005 MW5 Water 01/12/23 09:35 01/12/23 15:49
92646727006 MW2D Water 01/12/23 12:40 01/12/23 15:49
92646727007 MW3D Water 01/11/23 17:30 01/12/23 15:49
92646727008 FB Water 01/12/23 13:00 01/12/23 15:49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 32
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92646727001 MW1 SM 6200B 63 PASI-CCL
92646727002 MW2 EPA 6010D 7 PASI-ADEC
EPA 7470A 1 PASI-ANMP
SM 6200B 63 PASI-CCL
92646727003 MW3 EPA 6010D 7 PASI-ADEC
EPA 7470A 1 PASI-ANMP
SM 6200B 63 PASI-CCL
92646727004 MW4 EPA 6010D 7 PASI-ADEC
EPA 7470A 1 PASI-ANMP
SM 6200B 63 PASI-CCL
92646727005 MW5 SM 6200B 63 PASI-CCL
92646727006 MW2D SM 6200B 63 PASI-CCL
92646727007 MW3D SM 6200B 63 PASI-CCL
92646727008 FB SM 6200B 63 PASI-CCL
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Sample:MW1 Lab ID:92646727001 Collected:01/12/23 11:00 Received:01/12/23 15:49 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene <0.34 ug/L 01/16/23 20:33 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 01/16/23 20:33 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 01/16/23 20:33 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 01/16/23 20:33 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 01/16/23 20:33 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 01/16/23 20:33 74-83-95.0 1.7 1
n-Butylbenzene <0.49 ug/L 01/16/23 20:33 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 01/16/23 20:33 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 01/16/23 20:33 98-06-60.50 0.32 1
Carbon tetrachloride <0.33 ug/L 01/16/23 20:33 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 01/16/23 20:33 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 01/16/23 20:33 75-00-31.0 0.65 1
Chloroform <0.43 ug/L 01/16/23 20:33 67-66-30.50 0.43 1
Chloromethane <0.54 ug/L 01/16/23 20:33 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 01/16/23 20:33 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 01/16/23 20:33 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 01/16/23 20:33 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 01/16/23 20:33 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 01/16/23 20:33 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 01/16/23 20:33 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 01/16/23 20:33 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 01/16/23 20:33 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 01/16/23 20:33 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 01/16/23 20:33 75-71-80.50 0.35 1
1,1-Dichloroethane 4.2 ug/L 01/16/23 20:33 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 01/16/23 20:33 107-06-20.50 0.32 1
1,1-Dichloroethene 2.7 ug/L 01/16/23 20:33 75-35-40.50 0.35 1
cis-1,2-Dichloroethene 1.0 ug/L 01/16/23 20:33 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 01/16/23 20:33 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 01/16/23 20:33 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 01/16/23 20:33 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 01/16/23 20:33 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 01/16/23 20:33 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 01/16/23 20:33 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 01/16/23 20:33 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 01/16/23 20:33 108-20-30.50 0.31 1
Ethylbenzene <0.30 ug/L 01/16/23 20:33 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene <1.5 ug/L 01/16/23 20:33 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 01/16/23 20:33 98-82-80.50 0.33 1
Methylene Chloride <2.0 ug/L 01/16/23 20:33 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 01/16/23 20:33 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 01/16/23 20:33 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 01/16/23 20:33 103-65-10.50 0.34 1
Styrene <0.29 ug/L 01/16/23 20:33 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 01/16/23 20:33 630-20-60.50 0.31 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Sample:MW1 Lab ID:92646727001 Collected:01/12/23 11:00 Received:01/12/23 15:49 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane <0.22 ug/L 01/16/23 20:33 79-34-50.50 0.22 1
Tetrachloroethene 115 ug/L 01/16/23 20:33 127-18-40.50 0.29 1
Toluene <0.24 ug/L 01/16/23 20:33 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 01/16/23 20:33 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 01/16/23 20:33 120-82-12.0 0.64 1
1,1,1-Trichloroethane 39.8 ug/L 01/16/23 20:33 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 01/16/23 20:33 79-00-50.50 0.32 1
Trichloroethene 0.98 ug/L 01/16/23 20:33 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 01/16/23 20:33 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 01/16/23 20:33 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 01/16/23 20:33 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 01/16/23 20:33 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 01/16/23 20:33 75-01-41.0 0.39 1
m&p-Xylene <0.71 ug/L 01/16/23 20:33 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 01/16/23 20:33 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)100 %01/16/23 20:33 17060-07-070-130 1
4-Bromofluorobenzene (S)91 %01/16/23 20:33 460-00-470-130 1
Toluene-d8 (S)107 %01/16/23 20:33 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Sample:MW2 Lab ID:92646727002 Collected:01/11/23 14:15 Received:01/12/23 15:49 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Leachate Method/Date: EPA 1311; 01/20/23 13:10 Initial pH: ; Final pH: 2
Pace Analytical Services - Asheville
6010 MET ICP, TCLP
Arsenic <0.0018 mg/L 01/26/23 15:47 7440-38-201/24/23 01:560.050 0.0018 1
Barium 0.044J mg/L 01/26/23 15:47 7440-39-301/24/23 01:560.25 0.00039 1
Cadmium <0.00014 mg/L 01/26/23 15:47 7440-43-901/24/23 01:560.0050 0.00014 1
Chromium <0.0023 mg/L 01/26/23 15:47 7440-47-301/24/23 01:560.050 0.0023 1
Lead <0.0013 mg/L 01/26/23 15:47 7439-92-101/24/23 01:560.025 0.0013 1
Selenium <0.0046 mg/L 01/26/23 15:47 7782-49-201/24/23 01:560.10 0.0046 1
Silver <0.00064 mg/L 01/26/23 15:47 7440-22-401/24/23 01:560.025 0.00064 1
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Leachate Method/Date: EPA 1311; 01/20/23 13:10 Initial pH: ; Final pH: 2
Pace Analytical Services - Asheville
7470 Mercury, TCLP
Mercury <0.00012 mg/L 01/25/23 11:54 7439-97-601/24/23 16:190.00020 0.00012 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene <0.34 ug/L 01/16/23 19:02 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 01/16/23 19:02 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 01/16/23 19:02 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 01/16/23 19:02 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 01/16/23 19:02 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 01/16/23 19:02 74-83-95.0 1.7 1
n-Butylbenzene <0.49 ug/L 01/16/23 19:02 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 01/16/23 19:02 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 01/16/23 19:02 98-06-60.50 0.32 1
Carbon tetrachloride <0.33 ug/L 01/16/23 19:02 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 01/16/23 19:02 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 01/16/23 19:02 75-00-31.0 0.65 1
Chloroform <0.43 ug/L 01/16/23 19:02 67-66-30.50 0.43 1
Chloromethane <0.54 ug/L 01/16/23 19:02 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 01/16/23 19:02 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 01/16/23 19:02 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 01/16/23 19:02 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 01/16/23 19:02 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 01/16/23 19:02 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 01/16/23 19:02 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 01/16/23 19:02 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 01/16/23 19:02 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 01/16/23 19:02 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 01/16/23 19:02 75-71-80.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 01/16/23 19:02 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 01/16/23 19:02 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 01/16/23 19:02 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 01/16/23 19:02 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 01/16/23 19:02 156-60-50.50 0.40 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Sample:MW2 Lab ID:92646727002 Collected:01/11/23 14:15 Received:01/12/23 15:49 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,2-Dichloropropane <0.36 ug/L 01/16/23 19:02 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 01/16/23 19:02 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 01/16/23 19:02 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 01/16/23 19:02 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 01/16/23 19:02 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 01/16/23 19:02 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 01/16/23 19:02 108-20-30.50 0.31 1
Ethylbenzene <0.30 ug/L 01/16/23 19:02 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene <1.5 ug/L 01/16/23 19:02 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 01/16/23 19:02 98-82-80.50 0.33 1
Methylene Chloride <2.0 ug/L 01/16/23 19:02 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 01/16/23 19:02 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 01/16/23 19:02 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 01/16/23 19:02 103-65-10.50 0.34 1
Styrene <0.29 ug/L 01/16/23 19:02 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 01/16/23 19:02 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 01/16/23 19:02 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 01/16/23 19:02 127-18-40.50 0.29 1
Toluene <0.24 ug/L 01/16/23 19:02 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 01/16/23 19:02 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 01/16/23 19:02 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 01/16/23 19:02 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 01/16/23 19:02 79-00-5 M10.50 0.32 1
Trichloroethene <0.38 ug/L 01/16/23 19:02 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 01/16/23 19:02 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 01/16/23 19:02 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 01/16/23 19:02 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 01/16/23 19:02 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 01/16/23 19:02 75-01-41.0 0.39 1
m&p-Xylene <0.71 ug/L 01/16/23 19:02 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 01/16/23 19:02 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)101 %01/16/23 19:02 17060-07-070-130 1
4-Bromofluorobenzene (S)90 %01/16/23 19:02 460-00-470-130 1
Toluene-d8 (S)109 %01/16/23 19:02 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Sample:MW3 Lab ID:92646727003 Collected:01/11/23 14:45 Received:01/12/23 15:49 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Leachate Method/Date: EPA 1311; 01/20/23 13:10 Initial pH: ; Final pH: 2
Pace Analytical Services - Asheville
6010 MET ICP, TCLP
Arsenic <0.0018 mg/L 01/26/23 15:59 7440-38-201/24/23 01:560.050 0.0018 1
Barium 0.050J mg/L 01/26/23 15:59 7440-39-301/24/23 01:560.25 0.00039 1
Cadmium <0.00014 mg/L 01/26/23 15:59 7440-43-901/24/23 01:560.0050 0.00014 1
Chromium <0.0023 mg/L 01/26/23 15:59 7440-47-301/24/23 01:560.050 0.0023 1
Lead <0.0013 mg/L 01/26/23 15:59 7439-92-101/24/23 01:560.025 0.0013 1
Selenium <0.0046 mg/L 01/26/23 15:59 7782-49-201/24/23 01:560.10 0.0046 1
Silver <0.00064 mg/L 01/26/23 15:59 7440-22-401/24/23 01:560.025 0.00064 1
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Leachate Method/Date: EPA 1311; 01/20/23 13:10 Initial pH: ; Final pH: 2
Pace Analytical Services - Asheville
7470 Mercury, TCLP
Mercury <0.00012 mg/L 01/25/23 12:05 7439-97-601/24/23 16:190.00020 0.00012 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene <0.34 ug/L 01/16/23 19:20 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 01/16/23 19:20 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 01/16/23 19:20 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 01/16/23 19:20 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 01/16/23 19:20 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 01/16/23 19:20 74-83-95.0 1.7 1
n-Butylbenzene <0.49 ug/L 01/16/23 19:20 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 01/16/23 19:20 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 01/16/23 19:20 98-06-60.50 0.32 1
Carbon tetrachloride <0.33 ug/L 01/16/23 19:20 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 01/16/23 19:20 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 01/16/23 19:20 75-00-31.0 0.65 1
Chloroform <0.43 ug/L 01/16/23 19:20 67-66-30.50 0.43 1
Chloromethane <0.54 ug/L 01/16/23 19:20 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 01/16/23 19:20 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 01/16/23 19:20 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 01/16/23 19:20 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 01/16/23 19:20 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 01/16/23 19:20 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 01/16/23 19:20 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 01/16/23 19:20 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 01/16/23 19:20 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 01/16/23 19:20 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 01/16/23 19:20 75-71-80.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 01/16/23 19:20 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 01/16/23 19:20 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 01/16/23 19:20 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 01/16/23 19:20 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 01/16/23 19:20 156-60-50.50 0.40 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Sample:MW3 Lab ID:92646727003 Collected:01/11/23 14:45 Received:01/12/23 15:49 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,2-Dichloropropane <0.36 ug/L 01/16/23 19:20 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 01/16/23 19:20 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 01/16/23 19:20 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 01/16/23 19:20 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 01/16/23 19:20 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 01/16/23 19:20 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 01/16/23 19:20 108-20-30.50 0.31 1
Ethylbenzene <0.30 ug/L 01/16/23 19:20 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene <1.5 ug/L 01/16/23 19:20 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 01/16/23 19:20 98-82-80.50 0.33 1
Methylene Chloride <2.0 ug/L 01/16/23 19:20 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 01/16/23 19:20 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 01/16/23 19:20 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 01/16/23 19:20 103-65-10.50 0.34 1
Styrene <0.29 ug/L 01/16/23 19:20 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 01/16/23 19:20 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 01/16/23 19:20 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 01/16/23 19:20 127-18-40.50 0.29 1
Toluene <0.24 ug/L 01/16/23 19:20 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 01/16/23 19:20 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 01/16/23 19:20 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 01/16/23 19:20 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 01/16/23 19:20 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 01/16/23 19:20 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 01/16/23 19:20 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 01/16/23 19:20 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 01/16/23 19:20 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 01/16/23 19:20 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 01/16/23 19:20 75-01-41.0 0.39 1
m&p-Xylene <0.71 ug/L 01/16/23 19:20 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 01/16/23 19:20 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)102 %01/16/23 19:20 17060-07-070-130 1
4-Bromofluorobenzene (S)89 %01/16/23 19:20 460-00-470-130 1
Toluene-d8 (S)102 %01/16/23 19:20 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Sample:MW4 Lab ID:92646727004 Collected:01/11/23 16:35 Received:01/12/23 15:49 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Leachate Method/Date: EPA 1311; 01/20/23 13:10 Initial pH: ; Final pH: 2
Pace Analytical Services - Asheville
6010 MET ICP, TCLP
Arsenic <0.0018 mg/L 01/26/23 16:02 7440-38-201/24/23 01:560.050 0.0018 1
Barium 0.87 mg/L 01/26/23 16:02 7440-39-301/24/23 01:560.25 0.00039 1
Cadmium 0.00030J mg/L 01/26/23 16:02 7440-43-901/24/23 01:560.0050 0.00014 1
Chromium <0.0023 mg/L 01/26/23 16:02 7440-47-301/24/23 01:560.050 0.0023 1
Lead <0.0013 mg/L 01/26/23 16:02 7439-92-101/24/23 01:560.025 0.0013 1
Selenium <0.0046 mg/L 01/26/23 16:02 7782-49-201/24/23 01:560.10 0.0046 1
Silver <0.00064 mg/L 01/26/23 16:02 7440-22-401/24/23 01:560.025 0.00064 1
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Leachate Method/Date: EPA 1311; 01/20/23 13:10 Initial pH: ; Final pH: 2
Pace Analytical Services - Asheville
7470 Mercury, TCLP
Mercury <0.00012 mg/L 01/25/23 12:08 7439-97-601/24/23 16:190.00020 0.00012 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene <0.34 ug/L 01/16/23 19:38 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 01/16/23 19:38 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 01/16/23 19:38 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 01/16/23 19:38 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 01/16/23 19:38 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 01/16/23 19:38 74-83-95.0 1.7 1
n-Butylbenzene <0.49 ug/L 01/16/23 19:38 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 01/16/23 19:38 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 01/16/23 19:38 98-06-60.50 0.32 1
Carbon tetrachloride <0.33 ug/L 01/16/23 19:38 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 01/16/23 19:38 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 01/16/23 19:38 75-00-31.0 0.65 1
Chloroform 0.52 ug/L 01/16/23 19:38 67-66-3 C70.50 0.43 1
Chloromethane <0.54 ug/L 01/16/23 19:38 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 01/16/23 19:38 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 01/16/23 19:38 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 01/16/23 19:38 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 01/16/23 19:38 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 01/16/23 19:38 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 01/16/23 19:38 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 01/16/23 19:38 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 01/16/23 19:38 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 01/16/23 19:38 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 01/16/23 19:38 75-71-80.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 01/16/23 19:38 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 01/16/23 19:38 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 01/16/23 19:38 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 01/16/23 19:38 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 01/16/23 19:38 156-60-50.50 0.40 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Sample:MW4 Lab ID:92646727004 Collected:01/11/23 16:35 Received:01/12/23 15:49 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,2-Dichloropropane <0.36 ug/L 01/16/23 19:38 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 01/16/23 19:38 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 01/16/23 19:38 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 01/16/23 19:38 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 01/16/23 19:38 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 01/16/23 19:38 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 01/16/23 19:38 108-20-30.50 0.31 1
Ethylbenzene <0.30 ug/L 01/16/23 19:38 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene <1.5 ug/L 01/16/23 19:38 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 01/16/23 19:38 98-82-80.50 0.33 1
Methylene Chloride <2.0 ug/L 01/16/23 19:38 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 01/16/23 19:38 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 01/16/23 19:38 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 01/16/23 19:38 103-65-10.50 0.34 1
Styrene <0.29 ug/L 01/16/23 19:38 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 01/16/23 19:38 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 01/16/23 19:38 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 01/16/23 19:38 127-18-40.50 0.29 1
Toluene <0.24 ug/L 01/16/23 19:38 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 01/16/23 19:38 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 01/16/23 19:38 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 01/16/23 19:38 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 01/16/23 19:38 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 01/16/23 19:38 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 01/16/23 19:38 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 01/16/23 19:38 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 01/16/23 19:38 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 01/16/23 19:38 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 01/16/23 19:38 75-01-41.0 0.39 1
m&p-Xylene <0.71 ug/L 01/16/23 19:38 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 01/16/23 19:38 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)101 %01/16/23 19:38 17060-07-070-130 1
4-Bromofluorobenzene (S)93 %01/16/23 19:38 460-00-470-130 1
Toluene-d8 (S)100 %01/16/23 19:38 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Sample:MW5 Lab ID:92646727005 Collected:01/12/23 09:35 Received:01/12/23 15:49 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene <0.34 ug/L 01/16/23 19:56 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 01/16/23 19:56 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 01/16/23 19:56 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 01/16/23 19:56 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 01/16/23 19:56 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 01/16/23 19:56 74-83-95.0 1.7 1
n-Butylbenzene <0.49 ug/L 01/16/23 19:56 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 01/16/23 19:56 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 01/16/23 19:56 98-06-60.50 0.32 1
Carbon tetrachloride <0.33 ug/L 01/16/23 19:56 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 01/16/23 19:56 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 01/16/23 19:56 75-00-31.0 0.65 1
Chloroform 0.56 ug/L 01/16/23 19:56 67-66-3 C70.50 0.43 1
Chloromethane <0.54 ug/L 01/16/23 19:56 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 01/16/23 19:56 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 01/16/23 19:56 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 01/16/23 19:56 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 01/16/23 19:56 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 01/16/23 19:56 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 01/16/23 19:56 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 01/16/23 19:56 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 01/16/23 19:56 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 01/16/23 19:56 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 01/16/23 19:56 75-71-80.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 01/16/23 19:56 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 01/16/23 19:56 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 01/16/23 19:56 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 01/16/23 19:56 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 01/16/23 19:56 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 01/16/23 19:56 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 01/16/23 19:56 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 01/16/23 19:56 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 01/16/23 19:56 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 01/16/23 19:56 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 01/16/23 19:56 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 01/16/23 19:56 108-20-30.50 0.31 1
Ethylbenzene <0.30 ug/L 01/16/23 19:56 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene <1.5 ug/L 01/16/23 19:56 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 01/16/23 19:56 98-82-80.50 0.33 1
Methylene Chloride <2.0 ug/L 01/16/23 19:56 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 01/16/23 19:56 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 01/16/23 19:56 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 01/16/23 19:56 103-65-10.50 0.34 1
Styrene <0.29 ug/L 01/16/23 19:56 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 01/16/23 19:56 630-20-60.50 0.31 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Sample:MW5 Lab ID:92646727005 Collected:01/12/23 09:35 Received:01/12/23 15:49 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane <0.22 ug/L 01/16/23 19:56 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 01/16/23 19:56 127-18-40.50 0.29 1
Toluene <0.24 ug/L 01/16/23 19:56 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 01/16/23 19:56 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 01/16/23 19:56 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 01/16/23 19:56 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 01/16/23 19:56 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 01/16/23 19:56 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 01/16/23 19:56 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 01/16/23 19:56 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 01/16/23 19:56 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 01/16/23 19:56 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 01/16/23 19:56 75-01-41.0 0.39 1
m&p-Xylene <0.71 ug/L 01/16/23 19:56 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 01/16/23 19:56 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)102 %01/16/23 19:56 17060-07-070-130 1
4-Bromofluorobenzene (S)88 %01/16/23 19:56 460-00-470-130 1
Toluene-d8 (S)99 %01/16/23 19:56 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Sample:MW2D Lab ID:92646727006 Collected:01/12/23 12:40 Received:01/12/23 15:49 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene <0.34 ug/L 01/16/23 20:15 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 01/16/23 20:15 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 01/16/23 20:15 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 01/16/23 20:15 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 01/16/23 20:15 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 01/16/23 20:15 74-83-95.0 1.7 1
n-Butylbenzene <0.49 ug/L 01/16/23 20:15 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 01/16/23 20:15 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 01/16/23 20:15 98-06-60.50 0.32 1
Carbon tetrachloride <0.33 ug/L 01/16/23 20:15 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 01/16/23 20:15 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 01/16/23 20:15 75-00-31.0 0.65 1
Chloroform 1.9 ug/L 01/16/23 20:15 67-66-30.50 0.43 1
Chloromethane <0.54 ug/L 01/16/23 20:15 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 01/16/23 20:15 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 01/16/23 20:15 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 01/16/23 20:15 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 01/16/23 20:15 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 01/16/23 20:15 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 01/16/23 20:15 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 01/16/23 20:15 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 01/16/23 20:15 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 01/16/23 20:15 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 01/16/23 20:15 75-71-80.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 01/16/23 20:15 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 01/16/23 20:15 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 01/16/23 20:15 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 01/16/23 20:15 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 01/16/23 20:15 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 01/16/23 20:15 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 01/16/23 20:15 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 01/16/23 20:15 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 01/16/23 20:15 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 01/16/23 20:15 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 01/16/23 20:15 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 01/16/23 20:15 108-20-30.50 0.31 1
Ethylbenzene <0.30 ug/L 01/16/23 20:15 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene <1.5 ug/L 01/16/23 20:15 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 01/16/23 20:15 98-82-80.50 0.33 1
Methylene Chloride <2.0 ug/L 01/16/23 20:15 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 01/16/23 20:15 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 01/16/23 20:15 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 01/16/23 20:15 103-65-10.50 0.34 1
Styrene <0.29 ug/L 01/16/23 20:15 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 01/16/23 20:15 630-20-60.50 0.31 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Sample:MW2D Lab ID:92646727006 Collected:01/12/23 12:40 Received:01/12/23 15:49 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane <0.22 ug/L 01/16/23 20:15 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 01/16/23 20:15 127-18-40.50 0.29 1
Toluene <0.24 ug/L 01/16/23 20:15 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 01/16/23 20:15 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 01/16/23 20:15 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 01/16/23 20:15 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 01/16/23 20:15 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 01/16/23 20:15 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 01/16/23 20:15 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 01/16/23 20:15 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 01/16/23 20:15 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 01/16/23 20:15 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 01/16/23 20:15 75-01-41.0 0.39 1
m&p-Xylene <0.71 ug/L 01/16/23 20:15 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 01/16/23 20:15 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)99 %01/16/23 20:15 17060-07-070-130 1
4-Bromofluorobenzene (S)101 %01/16/23 20:15 460-00-470-130 1
Toluene-d8 (S)104 %01/16/23 20:15 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Sample:MW3D Lab ID:92646727007 Collected:01/11/23 17:30 Received:01/12/23 15:49 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene <0.34 ug/L 01/16/23 20:51 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 01/16/23 20:51 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 01/16/23 20:51 74-97-50.50 0.47 1
Bromodichloromethane 3.0 ug/L 01/16/23 20:51 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 01/16/23 20:51 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 01/16/23 20:51 74-83-95.0 1.7 1
n-Butylbenzene <0.49 ug/L 01/16/23 20:51 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 01/16/23 20:51 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 01/16/23 20:51 98-06-60.50 0.32 1
Carbon tetrachloride <0.33 ug/L 01/16/23 20:51 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 01/16/23 20:51 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 01/16/23 20:51 75-00-31.0 0.65 1
Chloroform 17.0 ug/L 01/16/23 20:51 67-66-30.50 0.43 1
Chloromethane <0.54 ug/L 01/16/23 20:51 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 01/16/23 20:51 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 01/16/23 20:51 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 01/16/23 20:51 96-12-81.0 0.34 1
Dibromochloromethane 0.80 ug/L 01/16/23 20:51 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 01/16/23 20:51 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 01/16/23 20:51 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 01/16/23 20:51 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 01/16/23 20:51 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 01/16/23 20:51 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 01/16/23 20:51 75-71-80.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 01/16/23 20:51 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 01/16/23 20:51 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 01/16/23 20:51 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 01/16/23 20:51 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 01/16/23 20:51 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 01/16/23 20:51 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 01/16/23 20:51 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 01/16/23 20:51 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 01/16/23 20:51 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 01/16/23 20:51 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 01/16/23 20:51 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 01/16/23 20:51 108-20-30.50 0.31 1
Ethylbenzene <0.30 ug/L 01/16/23 20:51 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene <1.5 ug/L 01/16/23 20:51 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 01/16/23 20:51 98-82-80.50 0.33 1
Methylene Chloride <2.0 ug/L 01/16/23 20:51 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 01/16/23 20:51 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 01/16/23 20:51 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 01/16/23 20:51 103-65-10.50 0.34 1
Styrene <0.29 ug/L 01/16/23 20:51 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 01/16/23 20:51 630-20-60.50 0.31 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Sample:MW3D Lab ID:92646727007 Collected:01/11/23 17:30 Received:01/12/23 15:49 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane <0.22 ug/L 01/16/23 20:51 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 01/16/23 20:51 127-18-40.50 0.29 1
Toluene <0.24 ug/L 01/16/23 20:51 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 01/16/23 20:51 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 01/16/23 20:51 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 01/16/23 20:51 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 01/16/23 20:51 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 01/16/23 20:51 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 01/16/23 20:51 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 01/16/23 20:51 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 01/16/23 20:51 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 01/16/23 20:51 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 01/16/23 20:51 75-01-41.0 0.39 1
m&p-Xylene <0.71 ug/L 01/16/23 20:51 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 01/16/23 20:51 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)95 %01/16/23 20:51 17060-07-070-130 1
4-Bromofluorobenzene (S)91 %01/16/23 20:51 460-00-470-130 1
Toluene-d8 (S)98 %01/16/23 20:51 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Sample:FB Lab ID:92646727008 Collected:01/12/23 13:00 Received:01/12/23 15:49 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene <0.34 ug/L 01/16/23 18:07 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 01/16/23 18:07 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 01/16/23 18:07 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 01/16/23 18:07 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 01/16/23 18:07 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 01/16/23 18:07 74-83-95.0 1.7 1
n-Butylbenzene <0.49 ug/L 01/16/23 18:07 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 01/16/23 18:07 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 01/16/23 18:07 98-06-60.50 0.32 1
Carbon tetrachloride <0.33 ug/L 01/16/23 18:07 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 01/16/23 18:07 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 01/16/23 18:07 75-00-31.0 0.65 1
Chloroform <0.43 ug/L 01/16/23 18:07 67-66-30.50 0.43 1
Chloromethane <0.54 ug/L 01/16/23 18:07 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 01/16/23 18:07 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 01/16/23 18:07 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 01/16/23 18:07 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 01/16/23 18:07 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 01/16/23 18:07 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 01/16/23 18:07 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 01/16/23 18:07 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 01/16/23 18:07 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 01/16/23 18:07 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 01/16/23 18:07 75-71-80.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 01/16/23 18:07 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 01/16/23 18:07 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 01/16/23 18:07 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 01/16/23 18:07 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 01/16/23 18:07 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 01/16/23 18:07 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 01/16/23 18:07 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 01/16/23 18:07 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 01/16/23 18:07 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 01/16/23 18:07 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 01/16/23 18:07 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 01/16/23 18:07 108-20-30.50 0.31 1
Ethylbenzene <0.30 ug/L 01/16/23 18:07 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene <1.5 ug/L 01/16/23 18:07 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 01/16/23 18:07 98-82-80.50 0.33 1
Methylene Chloride <2.0 ug/L 01/16/23 18:07 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 01/16/23 18:07 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 01/16/23 18:07 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 01/16/23 18:07 103-65-10.50 0.34 1
Styrene <0.29 ug/L 01/16/23 18:07 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 01/16/23 18:07 630-20-60.50 0.31 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Sample:FB Lab ID:92646727008 Collected:01/12/23 13:00 Received:01/12/23 15:49 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane <0.22 ug/L 01/16/23 18:07 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 01/16/23 18:07 127-18-40.50 0.29 1
Toluene <0.24 ug/L 01/16/23 18:07 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 01/16/23 18:07 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 01/16/23 18:07 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 01/16/23 18:07 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 01/16/23 18:07 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 01/16/23 18:07 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 01/16/23 18:07 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 01/16/23 18:07 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 01/16/23 18:07 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 01/16/23 18:07 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 01/16/23 18:07 75-01-41.0 0.39 1
m&p-Xylene <0.71 ug/L 01/16/23 18:07 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 01/16/23 18:07 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)101 %01/16/23 18:07 17060-07-070-130 1
4-Bromofluorobenzene (S)94 %01/16/23 18:07 460-00-470-130 1
Toluene-d8 (S)105 %01/16/23 18:07 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
751230
EPA 7470A
EPA 7470A
7470 Mercury TCLP
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92646727002, 92646727003, 92646727004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3901658
Associated Lab Samples:92646727002, 92646727003, 92646727004
Matrix:Water
AnalyzedMDL
Mercury mg/L <0.00012 0.00020 01/25/23 12:150.00012
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3904030LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/L 0.00270.0025 107 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3904031MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92646727002
3904032
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury mg/L 0.0025 104 75-125103 1 200.0025<0.00012 0.0027 0.0027
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
751225
EPA 3010A
EPA 6010D
6010 MET TCLP
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92646727002, 92646727003, 92646727004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3901658
Associated Lab Samples:92646727002, 92646727003, 92646727004
Matrix:Water
AnalyzedMDL
Arsenic mg/L <0.0018 0.050 01/26/23 15:420.0018
Barium mg/L 0.028J 0.25 01/26/23 15:420.00039
Cadmium mg/L <0.00014 0.0050 01/26/23 15:420.00014
Chromium mg/L <0.0023 0.050 01/26/23 15:420.0023
Lead mg/L <0.0013 0.025 01/26/23 15:420.0013
Selenium mg/L 0.026J 0.10 01/26/23 15:420.0046
Silver mg/L <0.00064 0.025 01/26/23 15:420.00064
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3904016LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic mg/L 2.52.5 101 80-120
Barium mg/L 2.52.5 102 80-120
Cadmium mg/L 2.52.5 100 80-120
Chromium mg/L 2.52.5 99 80-120
Lead mg/L 2.52.5 100 80-120
Selenium mg/L 2.72.5 107 80-120
Silver mg/L 1.31.2 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3904017MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92646727002
3904018
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic mg/L 2.5 96 75-12598 2 202.5<0.0018 2.4 2.4
Barium mg/L 2.5 96 75-12598 2 202.50.044J 2.4 2.5
Cadmium mg/L 2.5 96 75-12597 2 202.5<0.00014 2.4 2.4
Chromium mg/L 2.5 95 75-12597 2 202.5<0.0023 2.4 2.4
Lead mg/L 2.5 96 75-12597 2 202.5<0.0013 2.4 2.4
Selenium mg/L 2.5 98 75-125100 2 202.5<0.0046 2.5 2.5
Silver mg/L 1.2 93 75-12595 2 201.2<0.00064 1.2 1.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
749593
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92646727001, 92646727002, 92646727003, 92646727004, 92646727005, 92646727006, 92646727007,
92646727008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3896754
Associated Lab Samples:92646727001, 92646727002, 92646727003, 92646727004, 92646727005, 92646727006, 92646727007,
92646727008
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.31 0.50 01/16/23 13:160.31
1,1,1-Trichloroethane ug/L <0.33 0.50 01/16/23 13:160.33
1,1,2,2-Tetrachloroethane ug/L <0.22 0.50 01/16/23 13:160.22
1,1,2-Trichloroethane ug/L <0.32 0.50 01/16/23 13:160.32
1,1-Dichloroethane ug/L <0.37 0.50 01/16/23 13:160.37
1,1-Dichloroethene ug/L <0.35 0.50 01/16/23 13:160.35
1,1-Dichloropropene ug/L <0.43 0.50 01/16/23 13:160.43
1,2,3-Trichlorobenzene ug/L <0.81 2.0 01/16/23 13:160.81
1,2,3-Trichloropropane ug/L <0.26 0.50 01/16/23 13:160.26
1,2,4-Trichlorobenzene ug/L <0.64 2.0 01/16/23 13:160.64
1,2,4-Trimethylbenzene ug/L <0.50 0.50 01/16/23 13:160.50
1,2-Dibromo-3-chloropropane ug/L <0.34 1.0 01/16/23 13:160.34
1,2-Dibromoethane (EDB)ug/L <0.27 0.50 01/16/23 13:160.27
1,2-Dichlorobenzene ug/L <0.34 0.50 01/16/23 13:160.34
1,2-Dichloroethane ug/L <0.32 0.50 01/16/23 13:160.32
1,2-Dichloropropane ug/L <0.36 0.50 01/16/23 13:160.36
1,3,5-Trimethylbenzene ug/L <0.33 0.50 01/16/23 13:160.33
1,3-Dichlorobenzene ug/L <0.34 0.50 01/16/23 13:160.34
1,3-Dichloropropane ug/L <0.28 0.50 01/16/23 13:160.28
1,4-Dichlorobenzene ug/L <0.33 0.50 01/16/23 13:160.33
2,2-Dichloropropane ug/L <0.39 0.50 01/16/23 13:160.39
2-Chlorotoluene ug/L <0.32 0.50 01/16/23 13:160.32
4-Chlorotoluene ug/L <0.32 0.50 01/16/23 13:160.32
Benzene ug/L <0.34 0.50 01/16/23 13:160.34
Bromobenzene ug/L <0.29 0.50 01/16/23 13:160.29
Bromochloromethane ug/L <0.47 0.50 01/16/23 13:160.47
Bromodichloromethane ug/L <0.31 0.50 01/16/23 13:160.31
Bromoform ug/L <0.34 0.50 01/16/23 13:160.34
Bromomethane ug/L <1.7 5.0 01/16/23 13:161.7
Carbon tetrachloride ug/L <0.33 0.50 01/16/23 13:160.33
Chlorobenzene ug/L <0.28 0.50 01/16/23 13:160.28
Chloroethane ug/L <0.65 1.0 01/16/23 13:160.65
Chloroform ug/L <0.43 0.50 01/16/23 13:160.43
Chloromethane ug/L <0.54 1.0 01/16/23 13:160.54
cis-1,2-Dichloroethene ug/L <0.38 0.50 01/16/23 13:160.38
cis-1,3-Dichloropropene ug/L <0.36 0.50 01/16/23 13:160.36
Dibromochloromethane ug/L <0.36 0.50 01/16/23 13:160.36
Dibromomethane ug/L <0.39 0.50 01/16/23 13:160.39
Dichlorodifluoromethane ug/L <0.35 0.50 01/16/23 13:160.35
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3896754
Associated Lab Samples:92646727001, 92646727002, 92646727003, 92646727004, 92646727005, 92646727006, 92646727007,
92646727008
Matrix:Water
AnalyzedMDL
Diisopropyl ether ug/L <0.31 0.50 01/16/23 13:160.31
Ethylbenzene ug/L <0.30 0.50 01/16/23 13:160.30
Hexachloro-1,3-butadiene ug/L <1.5 2.0 01/16/23 13:161.5
Isopropylbenzene (Cumene)ug/L <0.33 0.50 01/16/23 13:160.33
m&p-Xylene ug/L <0.71 1.0 01/16/23 13:160.71
Methyl-tert-butyl ether ug/L <0.42 0.50 01/16/23 13:160.42
Methylene Chloride ug/L <2.0 2.0 01/16/23 13:162.0
n-Butylbenzene ug/L <0.49 0.50 01/16/23 13:160.49
n-Propylbenzene ug/L <0.34 0.50 01/16/23 13:160.34
Naphthalene ug/L <0.64 2.0 01/16/23 13:160.64
o-Xylene ug/L <0.34 0.50 01/16/23 13:160.34
sec-Butylbenzene ug/L <0.40 0.50 01/16/23 13:160.40
Styrene ug/L <0.29 0.50 01/16/23 13:160.29
tert-Butylbenzene ug/L <0.32 0.50 01/16/23 13:160.32
Tetrachloroethene ug/L <0.29 0.50 01/16/23 13:160.29
Toluene ug/L <0.24 0.50 01/16/23 13:160.24
trans-1,2-Dichloroethene ug/L <0.40 0.50 01/16/23 13:160.40
trans-1,3-Dichloropropene ug/L <0.36 0.50 01/16/23 13:160.36
Trichloroethene ug/L <0.38 0.50 01/16/23 13:160.38
Trichlorofluoromethane ug/L <0.30 1.0 01/16/23 13:160.30
Vinyl chloride ug/L <0.39 1.0 01/16/23 13:160.39
1,2-Dichloroethane-d4 (S)%106 70-130 01/16/23 13:16
4-Bromofluorobenzene (S)%90 70-130 01/16/23 13:16
Toluene-d8 (S)%114 70-130 01/16/23 13:16
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3896755LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 21.520 108 60-140
1,1,1-Trichloroethane ug/L 20.220 101 60-140
1,1,2,2-Tetrachloroethane ug/L 21.420 107 60-140
1,1,2-Trichloroethane ug/L 19.020 95 60-140
1,1-Dichloroethane ug/L 16.620 83 60-140
1,1-Dichloroethene ug/L 19.720 98 60-140
1,1-Dichloropropene ug/L 21.920 109 60-140
1,2,3-Trichlorobenzene ug/L 23.920 119 60-140
1,2,3-Trichloropropane ug/L 20.620 103 60-140
1,2,4-Trichlorobenzene ug/L 21.220 106 60-140
1,2,4-Trimethylbenzene ug/L 19.420 97 60-140
1,2-Dibromo-3-chloropropane ug/L 20.920 104 60-140
1,2-Dibromoethane (EDB)ug/L 22.020 110 60-140
1,2-Dichlorobenzene ug/L 20.620 103 60-140
1,2-Dichloroethane ug/L 20.020 100 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3896755LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloropropane ug/L 19.520 97 60-140
1,3,5-Trimethylbenzene ug/L 19.620 98 60-140
1,3-Dichlorobenzene ug/L 20.820 104 60-140
1,3-Dichloropropane ug/L 20.620 103 60-140
1,4-Dichlorobenzene ug/L 20.220 101 60-140
2,2-Dichloropropane ug/L 20.020 100 60-140
2-Chlorotoluene ug/L 18.720 93 60-140
4-Chlorotoluene ug/L 19.520 97 60-140
Benzene ug/L 19.420 97 60-140
Bromobenzene ug/L 19.320 97 60-140
Bromochloromethane ug/L 21.220 106 60-140
Bromodichloromethane ug/L 18.720 93 60-140
Bromoform ug/L 18.620 93 60-140
Bromomethane ug/L 20.620 103 60-140
Carbon tetrachloride ug/L 20.020 100 60-140
Chlorobenzene ug/L 20.320 101 60-140
Chloroethane ug/L 20.620 103 60-140
Chloroform ug/L 18.920 95 60-140
Chloromethane ug/L 17.420 87 60-140
cis-1,2-Dichloroethene ug/L 17.220 86 60-140
cis-1,3-Dichloropropene ug/L 17.920 89 60-140
Dibromochloromethane ug/L 18.320 91 60-140
Dibromomethane ug/L 20.320 101 60-140
Dichlorodifluoromethane ug/L 17.020 85 60-140
Diisopropyl ether ug/L 15.520 77 60-140
Ethylbenzene ug/L 19.520 98 60-140
Hexachloro-1,3-butadiene ug/L 21.320 107 60-140
Isopropylbenzene (Cumene)ug/L 19.020 95 60-140
m&p-Xylene ug/L 39.340 98 60-140
Methyl-tert-butyl ether ug/L 16.820 84 60-140
Methylene Chloride ug/L 16.720 84 60-140
n-Butylbenzene ug/L 20.420 102 60-140
n-Propylbenzene ug/L 18.920 95 60-140
Naphthalene ug/L 23.720 119 60-140
o-Xylene ug/L 20.020 100 60-140
sec-Butylbenzene ug/L 19.520 98 60-140
Styrene ug/L 20.520 103 60-140
tert-Butylbenzene ug/L 16.520 82 60-140
Tetrachloroethene ug/L 19.620 98 60-140
Toluene ug/L 16.820 84 60-140
trans-1,2-Dichloroethene ug/L 17.720 88 60-140
trans-1,3-Dichloropropene ug/L 18.820 94 60-140
Trichloroethene ug/L 21.220 106 60-140
Trichlorofluoromethane ug/L 17.420 87 60-140
Vinyl chloride ug/L 17.620 88 60-140
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%96 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3896755LABORATORY CONTROL SAMPLE:
LCSSpike
Toluene-d8 (S)%85 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3896756MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92646727002
3896757
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 127 60-140131 3 3020<0.31 25.5 26.2
1,1,1-Trichloroethane ug/L 20 122 60-140127 4 3020<0.33 24.5 25.5
1,1,2,2-Tetrachloroethane ug/L 20 117 60-140124 6 3020<0.22 23.5 24.9
1,1,2-Trichloroethane ug/L M12014560-140115 23 3020<0.32 29.0 23.0
1,1-Dichloroethane ug/L 20 112 60-140122 8 3020<0.37 22.5 24.4
1,1-Dichloroethene ug/L 20 123 60-140118 4 3020<0.35 24.7 23.7
1,1-Dichloropropene ug/L 20 131 60-140135 3 3020<0.43 26.2 27.0
1,2,3-Trichlorobenzene ug/L 20 112 60-140118 5 3020<0.81 22.4 23.5
1,2,3-Trichloropropane ug/L 20 110 60-140118 7 3020<0.26 21.9 23.5
1,2,4-Trichlorobenzene ug/L 20 106 60-140117 10 3020<0.64 21.2 23.3
1,2,4-Trimethylbenzene ug/L 20 119 60-140117 1 3020<0.50 23.7 23.4
1,2-Dibromo-3-
chloropropane ug/L 20 116 60-140120 4 3020<0.34 23.1 24.0
1,2-Dibromoethane (EDB)ug/L 20 126 60-140131 3 3020<0.27 25.2 26.1
1,2-Dichlorobenzene ug/L 20 114 60-140119 4 3020<0.34 22.9 23.8
1,2-Dichloroethane ug/L 20 113 60-140121 7 3020<0.32 22.7 24.2
1,2-Dichloropropane ug/L 20 122 60-140114 7 3020<0.36 24.4 22.8
1,3,5-Trimethylbenzene ug/L 20 113 60-140117 3 3020<0.33 22.7 23.3
1,3-Dichlorobenzene ug/L 20 115 60-140120 4 3020<0.34 23.0 24.0
1,3-Dichloropropane ug/L 20 120 60-140121 1 3020<0.28 24.1 24.2
1,4-Dichlorobenzene ug/L 20 112 60-140117 4 3020<0.33 22.4 23.4
2,2-Dichloropropane ug/L 20 108 60-140116 7 3020<0.39 21.6 23.2
2-Chlorotoluene ug/L 20 110 60-140113 3 3020<0.32 21.9 22.6
4-Chlorotoluene ug/L 20 110 60-140114 3 3020<0.32 22.0 22.7
Benzene ug/L 20 117 60-140119 2 3020<0.34 23.3 23.8
Bromobenzene ug/L 20 113 60-140117 3 3020<0.29 22.6 23.3
Bromochloromethane ug/L 20 123 60-140130 6 3020<0.47 24.5 25.9
Bromodichloromethane ug/L 20 117 60-140109 7 3020<0.31 23.4 21.8
Bromoform ug/L 20 102 60-140108 6 3020<0.34 20.5 21.6
Bromomethane ug/L 20 113 60-140125 11 3020<1.7 22.5 25.1
Carbon tetrachloride ug/L 20 125 60-140131 5 3020<0.33 25.0 26.2
Chlorobenzene ug/L 20 117 60-140124 5 3020<0.28 23.5 24.8
Chloroethane ug/L 20 139 60-140130 7 3020<0.65 27.8 26.0
Chloroform ug/L 20 113 60-140119 5 3020<0.43 22.8 24.1
Chloromethane ug/L 20 106 60-140104 2 3020<0.54 21.2 20.8
cis-1,2-Dichloroethene ug/L 20 116 60-140123 6 3020<0.38 23.2 24.6
cis-1,3-Dichloropropene ug/L 20 116 60-140104 10 3020<0.36 23.1 20.9
Dibromochloromethane ug/L 20 113 60-140111 2 3020<0.36 22.6 22.2
Dibromomethane ug/L 20 121 60-140117 3 3020<0.39 24.1 23.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Page 26 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3896756MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92646727002
3896757
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Dichlorodifluoromethane ug/L 20 114 60-140106 7 3020<0.35 22.7 21.2
Diisopropyl ether ug/L 20 101 60-14099 2 3020<0.31 20.3 19.8
Ethylbenzene ug/L 20 116 60-140119 3 3020<0.30 23.2 23.9
Hexachloro-1,3-butadiene ug/L 20 103 60-140111 8 3020<1.5 20.6 22.2
Isopropylbenzene(Cumene)ug/L 20 107 60-140116 8 3020<0.33 21.4 23.1
m&p-Xylene ug/L 40 117 60-140121 4 3040<0.71 46.8 48.6
Methyl-tert-butyl ether ug/L 20 104 60-140100 4 3020<0.42 20.9 20.1
Methylene Chloride ug/L 20 105 60-140109 4 3020<2.0 21.0 21.9
n-Butylbenzene ug/L 20 107 60-140113 6 3020<0.49 21.4 22.7
n-Propylbenzene ug/L 20 108 60-140113 4 3020<0.34 21.7 22.5
Naphthalene ug/L 20 122 60-140127 4 3020<0.64 24.4 25.4
o-Xylene ug/L 20 114 60-140120 5 3020<0.34 22.9 24.1
sec-Butylbenzene ug/L 20 111 60-140116 5 3020<0.40 22.2 23.3
Styrene ug/L 20 116 60-140123 6 3020<0.29 23.1 24.7
tert-Butylbenzene ug/L 20 95 60-14099 4 3020<0.32 19.1 19.8
Tetrachloroethene ug/L 20 114 60-140119 5 3020<0.29 22.8 23.8
Toluene ug/L 20 122 60-140106 14 3020<0.24 24.4 21.1
trans-1,2-Dichloroethene ug/L 20 114 60-140112 2 3020<0.40 22.8 22.3
trans-1,3-Dichloropropene ug/L 20 126 60-140108 15 3020<0.36 25.2 21.7
Trichloroethene ug/L 20 127 60-140132 4 3020<0.38 25.4 26.3
Trichlorofluoromethane ug/L 20 122 60-140114 6 3020<0.30 24.3 22.8
Vinyl chloride ug/L 20 120 60-140112 7 3020<0.39 24.0 22.4
1,2-Dichloroethane-d4 (S)%99 70-13099
4-Bromofluorobenzene (S)%93 70-13096
Toluene-d8 (S)%109 70-13087
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Page 27 of 32
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Analyte is a possible laboratory contaminant (not present in method blank).C7
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Page 28 of 32
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92646727
BOB MAY'S SLC4431902 APP IX
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92646727002 751225 751238MW2EPA 3010A EPA 6010D
92646727003 751225 751238MW3EPA 3010A EPA 6010D
92646727004 751225 751238MW4EPA 3010A EPA 6010D
92646727002 751230 751485MW2EPA 7470A EPA 7470A
92646727003 751230 751485MW3EPA 7470A EPA 7470A
92646727004 751230 751485MW4EPA 7470A EPA 7470A
92646727001 749593MW1SM 6200B
92646727002 749593MW2SM 6200B
92646727003 749593MW3SM 6200B
92646727004 749593MW4SM 6200B
92646727005 749593MW5SM 6200B
92646727006 749593MW2DSM 6200B
92646727007 749593MW3DSM 6200B
92646727008 749593FBSM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/27/2023 04:32 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Page 29 of 32
Page 30 of 32
Page 31 of 32
Page 32 of 32
Thisreportshouldnotbereproduced,exceptinfull,
withoutthewrittenconsentofPaceAnalyticalServices,Inc.
Theresultsrelateonlytothesamplesincludedinthisreport.
Report of Laboratory Analysis
www.pacelabs.com
Pace Analytical Services,LLC.
1700 Elm Street
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
Taylor Cannon
PACE Charlotte
9800 Kincey Ave.
Huntersville NC 28078
REPORT OF
LABORATORY
ANALYSIS FOR
PCDD/PCDF
This report has been reviewed by:
Invoicing & Reporting Options:
Report Information:
Report Prepared Date:
January 17, 2023
Pace Project #: 10639360
Sample Receipt Date: 01/11/2023
Client Project #: 92645777
Client Sub PO #: N/A
The report provided has been invoiced as a Level 2
PCDD/PCDF Report. If an upgrade of this report
package is requested,an additional charge may be
applied.
Please review the attached invoice for accuracy and
forward any questions to Matt Ray,your Pace Project
Manager.
State Cert #: N/A
Suite 100
Report Prepared for:
Page 1 of 11Report No.....10639360_SW8290FC_L2_dfr
January 17, 2023
Matt Ray,
(fax)
Pace Analytical Services,LLC.
1700 Elm Street
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
REPORTOF LABORATORY ANALYSIS
This report shall notbe reproduced,except in full,
withoutthewrittenconsentofPaceAnalyticalServices,Inc.
This report presents the results from the analysis performed on one sample submitted by a representative
of Pace Analytical Services, LLC. The sample was analyzed for the presence or absence of
polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) using a modified version of
USEPA Method 8290. The estimated detection limits (EDLs) were based on signal-to-noise
measurements. Estimated maximum possible concentration (EMPC) values were treated as positives in
the toxic equivalence calculations.
The isotopically-labeled PCDD/PCDF internal standards in the sample extract were recovered at
50-103%. All of the labeled internal standard recoveries obtained for this project were within the 40-135%
target range specified in Method 8290. Since the quantification of the native 2,3,7,8-substituted congeners
was based on isotope dilution, the data were automatically corrected for recovery and accurate values
were obtained.
Values were flagged "I" where incorrect isotope ratios were obtained or "P" where polychlorinated diphenyl
ethers were present. Concentrations below the calibration range were flagged "J" and should be regarded
as estimates.
A laboratory method blank was prepared and analyzed with the sample batch as part of our routine quality
control procedures. The results show that PCDDs and PCDFs were not detected.
A laboratory spike sample was also prepared with the sample batch using clean reference matrix that had
been fortified with native standard materials. The results show that the spiked native compounds were
recovered at 95-121%. These results were within the target range for the method. Matrix spikes were
prepared with the sample batch using sample material from a separate project; results from these
analyses will be provided upon request.
The response obtained for the labeled OCDD in calibration standard analysis U230116A_20 was outside
the target range. As specified in our procedures for this method, the average of the daily response factors
for this compound was used in the calculations for the samples from this runshift. The affected values
were flagged "Y" on the results tables.
DISCUSSION
Page 2 of 11Report No.....10639360_SW8290FC_L2_dfr
REPORT OFLABORATORY ANALYSIS
This report shallnot bereproduced,exceptin full,
withoutthe written consentofPaceAnalyticalServices,Inc.
Pace Analytical Services,LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel:[phone]
Fax:[phone]
Report No.....10639360
Minnesota Laboratory Certifications
Authority Certificate #Authority Certificate #
Missouri 10100
A2LA 2926.01 Montana CERT0092
Alabama 40770 Nebraska NE-OS-18-06
Alaska-DW MN00064 Nevada MN00064
Alaska-UST 17-009 New Hampshire 2081
Arizona AZ0014 New Jersey MN002
Arkansas - WW 88-0680 New York 11647
Arkansas-DW MN00064 North Carolina-27700
California 2929 North Carolina-530
Colorado MN00064 North Dakota R-036
Connecticut PH-0256 Ohio-DW 41244
Florida E87605 Ohio-VAP (170 CL101
Georgia 959 Ohio-VAP (180 CL110
Hawaii MN00064 Oklahoma 9507
Idaho MN00064 Oregon-Primary MN300001
Illinois 200011 Oregon-Second MN200001
Indiana C-MN-01 Pennsylvania 68-00563
Iowa 368 Puerto Rico MN00064
Kansas E-10167 South Carolina 74003
Kentucky-DW 90062 Tennessee TN02818
Kentucky-WW 90062 Texas T104704192
Louisiana-DEQ AI-84596 Utah MN00064
Louisiana-DW MN00064 Vermont VT-027053137
Maine MN00064 Virginia 460163
Maryland 322 Washington C486
Michigan 9909 West Virginia-D 382
Minnesota 027-053-137 West Virginia-D 9952C
Minnesota-Ag via MN 027-053 Wisconsin 999407970
Minnesota-Petr 1240 Wyoming-UST via A2LA 2926.
Mississippi MN00064
Page 3 of 11Report No.....10639360_SW8290FC_L2_dfr
Pace Analytical Services, LLC
1700 Elm Street, Suite 200
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
www.pacelabs.com
Appendix A
Sample Management
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 11Report No.....10639360_SW8290FC_L2_dfr
Page 5 of 11Report No.....10639360_SW8290FC_L2_dfr
1/11/23
Page 6 of 11Report No.....10639360_SW8290FC_L2_dfr
Pace Analytical Services, LLC
1700 Elm Street, Suite 200
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
www.pacelabs.com
A =

B =

C =

D =

E =

H2 =

I =

J =

L =

Nn =

P =

R =

S =

U =

V =

X =

Y =

* =
Reporting Limit based on signal to noise (EDL)

Less than 10x higher than method blank level

Result obtained from confirmation analysis

Result obtained from analysis of diluted sample

Exceeds calibration range

Extracted outside of holding time

Isotope ratio out of specification

Estimated value

Suppressive interference, analyte may be biased low

Value obtained from additional analysis

PCDE Interference

Recovery outside target range

Peak saturated

Analyte not detected

Result verified by confirmation analysis

%D Exceeds limits

Calculated using average of daily RFs

See Discussion
Reporting Flags
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 11Report No.....10639360_SW8290FC_L2_dfr
Pace Analytical Services, LLC
1700 Elm Street, Suite 200
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
www.pacelabs.com
Appendix B
Sample Analysis Summary
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 11Report No.....10639360_SW8290FC_L2_dfr
REPORTOF LABORATORY ANALYSIS
This report shall notbe reproduced,except in full,
withoutthewrittenconsentofPaceAnalyticalServices,Inc.
Pace Analytical Services,LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel:[phone]
Fax:[phone]
Lab Sample ID
Injected By
Filename
Total Amount Extracted% MoistureDry Weight Extracted
ICAL ID
CCal Filename(s)
Method Blank ID
Client's Sample ID >1092645777001
U230116A_14
SMT
20.415.4 g
12.3 g
U221005
U230116A_03 & U230116A_20
BLANK-103481
MatrixDilutionCollected
Received
Extracted
Analyzed
SolidNA01/05/2023 13:45
01/11/2023 08:50
01/12/2023 11:35
01/16/2023 20:15
Client - PACE Charlotte
Method 8290 Sample Analysis Results
NativeIsomers Concng/Kg ng/Kg InternalStandards Addedng's PercentRecoveryEMPCng/Kg EDL
2,3,7,8-TCDF 0.63 0.26 2,3,7,8-TCDF-13C 2.00 91J-----Total TCDF 19 0.26 2,3,7,8-TCDD-13C 2.00 80-----1,2,3,7,8-PeCDF-13C 2.00 932,3,7,8-TCDD ND 0.17 2,3,4,7,8-PeCDF-13C 2.00 90-----Total TCDD 1.2 0.17 1,2,3,7,8-PeCDD-13C 2.00 93-----1,2,3,4,7,8-HxCDF-13C 2.00 1031,2,3,7,8-PeCDF -----0.25 1,2,3,6,7,8-HxCDF-13C 2.00 96P132,3,4,7,8-PeCDF 2.5 0.19 2,3,4,6,7,8-HxCDF-13C 2.00 89J-----Total PeCDF 50 0.19 1,2,3,7,8,9-HxCDF-13C 2.00 84-----1,2,3,4,7,8-HxCDD-13C 2.00 911,2,3,7,8-PeCDD 0.31 0.086 1,2,3,6,7,8-HxCDD-13C 2.00 93J-----Total PeCDD 1.4 0.086 1,2,3,4,6,7,8-HpCDF-13C 2.00 65J-----1,2,3,4,7,8,9-HpCDF-13C 2.00 55
1,2,3,4,7,8-HxCDF -----0.17 1,2,3,4,6,7,8-HpCDD-13C 2.00 63PJ1.51,2,3,6,7,8-HxCDF 1.3 0.15 OCDD-13C 4.00 50J-----Y2,3,4,6,7,8-HxCDF 1.3 0.16 J-----1,2,3,7,8,9-HxCDF -----0.26 1,2,3,4-TCDD-13C 2.00 NAIJ0.54Total HxCDF 30 0.15 1,2,3,7,8,9-HxCDD-13C 2.00 NA-----
1,2,3,4,7,8-HxCDD 0.43 0.19 2,3,7,8-TCDD-37Cl4 0.20 81J-----1,2,3,6,7,8-HxCDD -----0.15 IJ0.541,2,3,7,8,9-HxCDD 0.34 0.16 J-----Total HxCDD 2.9 0.15 J-----
1,2,3,4,6,7,8-HpCDF 6.0 0.17 Total 2,3,7,8-TCDD-----1,2,3,4,7,8,9-HpCDF 0.34 0.13 Equivalence: 2.5 ng/KgJ-----Total HpCDF 13 0.13 (Lower-bound - Using 2005 WHO Factors)-----
1,2,3,4,6,7,8-HpCDD 9.1 0.12-----Total HpCDD 19 0.12-----
OCDF 7.1 0.38 J-----OCDD 700 0.43-----
Conc =Concentration (Totalsinclude 2,3,7,8-substituted isomers).
EMPC = Estimated Maximum Possible Concentration
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
Resultsreported on a dry weightbasis and are valid to nomore than 2 significant figures.
J = Estimated value
P = PCDE Interference
I=Isotope ratio out of specification
Y =Calculated using average of daily RFs
EDL = Estimated Detection Limit
Page 9 of 11Report No.....10639360_SW8290FC_L2_dfr
REPORTOF LABORATORY ANALYSIS
This report shall notbe reproduced,except in full,
withoutthewrittenconsentofPaceAnalyticalServices,Inc.
Pace Analytical Services,LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel:[phone]
Fax:[phone]
Lab Sample ID
Injected By
Filename
Total Amount Extracted
ICAL IDCCal Filename(s)
BLANK-103481
U230116A_13
SMT
10.6 g
U221005U230116A_03 & U230116A_20
Matrix
Dilution
Extracted
Analyzed
Solid
01/12/2023 11:35
01/16/2023 19:29
NA
Method 8290 Blank Analysis Results
Lab Sample Name DFBLKKK
Native
Isomers ng/Kg
Conc EMPC
ng/Kg ng/Kg
Internal
Standards Added
ng's Percent
Recovery
EDL
2,3,7,8-TCDF ND -----0.11 2,3,7,8-TCDF-13C 2.00 82Total TCDF ND -----0.11 2,3,7,8-TCDD-13C 2.00 671,2,3,7,8-PeCDF-13C 2.00 822,3,7,8-TCDD ND -----0.14 2,3,4,7,8-PeCDF-13C 2.00 83Total TCDD ND -----0.14 1,2,3,7,8-PeCDD-13C 2.00 821,2,3,4,7,8-HxCDF-13C 2.00 1031,2,3,7,8-PeCDF ND -----0.16 1,2,3,6,7,8-HxCDF-13C 2.00 1042,3,4,7,8-PeCDF ND -----0.092 2,3,4,6,7,8-HxCDF-13C 2.00 97Total PeCDF ND -----0.092 1,2,3,7,8,9-HxCDF-13C 2.00 761,2,3,4,7,8-HxCDD-13C 2.00 881,2,3,7,8-PeCDD ND -----0.099 1,2,3,6,7,8-HxCDD-13C 2.00 103Total PeCDD ND -----0.099 1,2,3,4,6,7,8-HpCDF-13C 2.00 691,2,3,4,7,8,9-HpCDF-13C 2.00 511,2,3,4,7,8-HxCDF ND -----0.097 1,2,3,4,6,7,8-HpCDD-13C 2.00 641,2,3,6,7,8-HxCDF ND -----0.099 OCDD-13C 4.00 45 Y2,3,4,6,7,8-HxCDF ND -----0.0971,2,3,7,8,9-HxCDF ND -----0.16 1,2,3,4-TCDD-13C 2.00 NATotal HxCDF ND -----0.097 1,2,3,7,8,9-HxCDD-13C 2.00 NA
1,2,3,4,7,8-HxCDD ND -----0.20 2,3,7,8-TCDD-37Cl4 0.20 691,2,3,6,7,8-HxCDD ND -----0.191,2,3,7,8,9-HxCDD ND -----0.17Total HxCDD ND -----0.17
1,2,3,4,6,7,8-HpCDF ND -----0.27 Total 2,3,7,8-TCDD1,2,3,4,7,8,9-HpCDF ND -----0.52 Equivalence: 0.00 ng/KgTotal HpCDF ND -----0.27 (Lower-bound - Using 2005 WHO Factors)
1,2,3,4,6,7,8-HpCDD ND -----0.20Total HpCDD ND -----0.20
OCDF ND -----0.63OCDDND-----0.75
Conc=Concentration(Totalsinclude2,3,7,8-substitutedisomers).
EMPC=EstimatedMaximumPossibleConcentration
Results reported ona total weight basisandare valid tono morethan 2 significant figures.
Y=Calculatedusing average of daily RFs
EDL=EstimatedDetectionLimit
Page 10 of 11Report No.....10639360_SW8290FC_L2_dfr
REPORTOF LABORATORY ANALYSIS
This report shall notbe reproduced,except in full,
withoutthewrittenconsentofPaceAnalyticalServices,Inc.
Pace Analytical Services,LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel:[phone]
Fax:[phone]
Lab Sample ID
Injected By
Filename
Total Amount Extracted
ICAL IDCCal Filename(s)
LCS-103482
U230116A_07
SMT
10.8 g
U221005U230116A_03 & U230116A_20
Matrix
Dilution
ExtractedAnalyzed
Solid
01/12/2023 11:3501/16/2023 14:53
NA
Method Blank ID BLANK-103481
Method 8290 Laboratory Control Spike Results
Native Qs Qm Internal ng's Percent
RecoveryIsomersStandardsAdded
%
Rec.(ng)(ng)
2,3,7,8-TCDF 0.20 0.22 2,3,7,8-TCDF-13C 2.0 110108Total TCDF 2,3,7,8-TCDD-13C 2.0 951,2,3,7,8-PeCDF-13C 2.0 1172,3,7,8-TCDD 0.20 0.24 2,3,4,7,8-PeCDF-13C 2.0 122121Total TCDD 1,2,3,7,8-PeCDD-13C 2.0 1221,2,3,4,7,8-HxCDF-13C 2.0 1331,2,3,7,8-PeCDF 1.0 1.0 1,2,3,6,7,8-HxCDF-13C 2.0 1331042,3,4,7,8-PeCDF 1.0 1.0 2,3,4,6,7,8-HxCDF-13C 2.0 130103Total PeCDF 1,2,3,7,8,9-HxCDF-13C 2.0 1121,2,3,4,7,8-HxCDD-13C 2.0 1161,2,3,7,8-PeCDD 1.0 1.00 1,2,3,6,7,8-HxCDD-13C 2.0 132100Total PeCDD 1,2,3,4,6,7,8-HpCDF-13C 2.0 921,2,3,4,7,8,9-HpCDF-13C 2.0 771,2,3,4,7,8-HxCDF 1.0 1.1 1,2,3,4,6,7,8-HpCDD-13C 2.0 941051,2,3,6,7,8-HxCDF 1.0 1.1 OCDD-13C 4.0 83111 Y2,3,4,6,7,8-HxCDF 1.0 1.1 1091,2,3,7,8,9-HxCDF 1.0 1.1 1,2,3,4-TCDD-13C 2.0 NA108Total HxCDF 1,2,3,7,8,9-HxCDD-13C 2.0 NA
1,2,3,4,7,8-HxCDD 1.0 1.1 2,3,7,8-TCDD-37Cl4 0.20 961141,2,3,6,7,8-HxCDD 1.0 1.0 1051,2,3,7,8,9-HxCDD 1.0 1.0 104Total HxCDD
1,2,3,4,6,7,8-HpCDF 1.0 1.1 1111,2,3,4,7,8,9-HpCDF 1.0 1.1 107Total HpCDF
1,2,3,4,6,7,8-HpCDD 1.0 0.95 95Total HpCDD
OCDF 2.0 2.4 119OCDD2.0 2.3 117
Qs = Quantity Spiked
Qm = Quantity Measured
Rec.=Recovery(ExpressedasPercent)
R=Recoveryoutsideoftarget range
Y =RF averaging usedin calculations
Nn =Value obtained from additional analysis
NA = Not Applicable
*=See Discussion
Page 11 of 11Report No.....10639360_SW8290FC_L2_dfr
#=CL#
January 10, 2023
LIMS USE: FR - AL QUARLES
LIMS OBJECT ID: 92645404
92645404
Project:
Pace Project No.:
RE:
Al Quarles
ATC Group Services LLC
7606 Whitehall Executive Cente
Suite 800
Charlotte, NC 28273
SLC4431902 FORMER BOB MAYS AUT
Dear Al Quarles:
Enclosed are the analytical results for sample(s) received by the laboratory on January 06, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor M Cannon
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 21
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92645404
SLC4431902 FORMER BOB MAYS AUT
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 21
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92645404
SLC4431902 FORMER BOB MAYS AUT
Lab ID Sample ID Matrix Date Collected Date Received
92645404001 0-10 Solid 01/05/23 13:45 01/06/23 09:20
92645404002 >10 Solid 01/05/23 13:45 01/06/23 09:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 21
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92645404
SLC4431902 FORMER BOB MAYS AUT
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92645404001 0-10 EPA 8260D 70 PASI-CSAS
SW-846 1 PASI-CKDF
92645404002 >10 EPA 8260D 70 PASI-CSAS
SW-846 1 PASI-CKDF
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92645404
SLC4431902 FORMER BOB MAYS AUT
Sample:0-10 Lab ID:92645404001 Collected:01/05/23 13:45 Received:01/06/23 09:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone <0.042 mg/kg 01/06/23 17:42 67-64-101/06/23 16:300.13 0.042 1
Benzene <0.0026 mg/kg 01/06/23 17:42 71-43-201/06/23 16:300.0065 0.0026 1
Bromobenzene <0.0021 mg/kg 01/06/23 17:42 108-86-101/06/23 16:300.0065 0.0021 1
Bromochloromethane <0.0019 mg/kg 01/06/23 17:42 74-97-501/06/23 16:300.0065 0.0019 1
Bromodichloromethane <0.0025 mg/kg 01/06/23 17:42 75-27-401/06/23 16:300.0065 0.0025 1
Bromoform <0.0023 mg/kg 01/06/23 17:42 75-25-201/06/23 16:300.0065 0.0023 1
Bromomethane <0.010 mg/kg 01/06/23 17:42 74-83-901/06/23 16:300.013 0.010 1
2-Butanone (MEK)<0.031 mg/kg 01/06/23 17:42 78-93-301/06/23 16:300.13 0.031 1
n-Butylbenzene <0.0031 mg/kg 01/06/23 17:42 104-51-801/06/23 16:300.0065 0.0031 1
sec-Butylbenzene <0.0029 mg/kg 01/06/23 17:42 135-98-801/06/23 16:300.0065 0.0029 1
tert-Butylbenzene <0.0023 mg/kg 01/06/23 17:42 98-06-601/06/23 16:300.0065 0.0023 1
Carbon tetrachloride <0.0024 mg/kg 01/06/23 17:42 56-23-501/06/23 16:300.0065 0.0024 1
Chlorobenzene <0.0013 mg/kg 01/06/23 17:42 108-90-701/06/23 16:300.0065 0.0013 1
Chloroethane <0.0050 mg/kg 01/06/23 17:42 75-00-301/06/23 16:300.013 0.0050 1
Chloroform <0.0040 mg/kg 01/06/23 17:42 67-66-301/06/23 16:300.0065 0.0040 1
Chloromethane <0.0055 mg/kg 01/06/23 17:42 74-87-3 v201/06/23 16:300.013 0.0055 1
2-Chlorotoluene <0.0023 mg/kg 01/06/23 17:42 95-49-801/06/23 16:300.0065 0.0023 1
4-Chlorotoluene <0.0012 mg/kg 01/06/23 17:42 106-43-401/06/23 16:300.0065 0.0012 1
1,2-Dibromo-3-chloropropane <0.0025 mg/kg 01/06/23 17:42 96-12-8 IK01/06/23 16:300.0065 0.0025 1
Dibromochloromethane <0.0037 mg/kg 01/06/23 17:42 124-48-101/06/23 16:300.0065 0.0037 1
1,2-Dibromoethane (EDB)<0.0029 mg/kg 01/06/23 17:42 106-93-401/06/23 16:300.0065 0.0029 1
Dibromomethane <0.0014 mg/kg 01/06/23 17:42 74-95-301/06/23 16:300.0065 0.0014 1
1,2-Dichlorobenzene <0.0023 mg/kg 01/06/23 17:42 95-50-101/06/23 16:300.0065 0.0023 1
1,3-Dichlorobenzene <0.0020 mg/kg 01/06/23 17:42 541-73-101/06/23 16:300.0065 0.0020 1
1,4-Dichlorobenzene <0.0017 mg/kg 01/06/23 17:42 106-46-701/06/23 16:300.0065 0.0017 1
Dichlorodifluoromethane <0.0028 mg/kg 01/06/23 17:42 75-71-8 IH,v201/06/23 16:300.013 0.0028 1
1,1-Dichloroethane <0.0027 mg/kg 01/06/23 17:42 75-34-301/06/23 16:300.0065 0.0027 1
1,2-Dichloroethane <0.0043 mg/kg 01/06/23 17:42 107-06-201/06/23 16:300.0065 0.0043 1
1,1-Dichloroethene <0.0027 mg/kg 01/06/23 17:42 75-35-401/06/23 16:300.0065 0.0027 1
cis-1,2-Dichloroethene <0.0022 mg/kg 01/06/23 17:42 156-59-201/06/23 16:300.0065 0.0022 1
trans-1,2-Dichloroethene <0.0023 mg/kg 01/06/23 17:42 156-60-501/06/23 16:300.0065 0.0023 1
1,2-Dichloropropane <0.0020 mg/kg 01/06/23 17:42 78-87-501/06/23 16:300.0065 0.0020 1
1,3-Dichloropropane <0.0020 mg/kg 01/06/23 17:42 142-28-901/06/23 16:300.0065 0.0020 1
2,2-Dichloropropane <0.0021 mg/kg 01/06/23 17:42 594-20-701/06/23 16:300.0065 0.0021 1
1,1-Dichloropropene <0.0031 mg/kg 01/06/23 17:42 563-58-601/06/23 16:300.0065 0.0031 1
cis-1,3-Dichloropropene <0.0018 mg/kg 01/06/23 17:42 10061-01-501/06/23 16:300.0065 0.0018 1
trans-1,3-Dichloropropene <0.0022 mg/kg 01/06/23 17:42 10061-02-601/06/23 16:300.0065 0.0022 1
Diisopropyl ether <0.0018 mg/kg 01/06/23 17:42 108-20-301/06/23 16:300.0065 0.0018 1
Ethylbenzene <0.0030 mg/kg 01/06/23 17:42 100-41-401/06/23 16:300.0065 0.0030 1
Hexachloro-1,3-butadiene <0.011 mg/kg 01/06/23 17:42 87-68-301/06/23 16:300.013 0.011 1
2-Hexanone <0.0063 mg/kg 01/06/23 17:42 591-78-6 IK01/06/23 16:300.065 0.0063 1
Isopropylbenzene (Cumene)<0.0022 mg/kg 01/06/23 17:42 98-82-801/06/23 16:300.0065 0.0022 1
p-Isopropyltoluene 0.0043J mg/kg 01/06/23 17:42 99-87-601/06/23 16:300.0065 0.0032 1
Methylene Chloride <0.018 mg/kg 01/06/23 17:42 75-09-201/06/23 16:300.026 0.018 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2023 09:18 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92645404
SLC4431902 FORMER BOB MAYS AUT
Sample:0-10 Lab ID:92645404001 Collected:01/05/23 13:45 Received:01/06/23 09:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
4-Methyl-2-pentanone (MIBK)<0.0063 mg/kg 01/06/23 17:42 108-10-101/06/23 16:300.065 0.0063 1
Methyl-tert-butyl ether <0.0024 mg/kg 01/06/23 17:42 1634-04-401/06/23 16:300.0065 0.0024 1
Naphthalene 0.021 mg/kg 01/06/23 17:42 91-20-301/06/23 16:300.0065 0.0034 1
n-Propylbenzene <0.0023 mg/kg 01/06/23 17:42 103-65-101/06/23 16:300.0065 0.0023 1
Styrene <0.0017 mg/kg 01/06/23 17:42 100-42-501/06/23 16:300.0065 0.0017 1
1,1,1,2-Tetrachloroethane <0.0025 mg/kg 01/06/23 17:42 630-20-601/06/23 16:300.0065 0.0025 1
1,1,2,2-Tetrachloroethane <0.0017 mg/kg 01/06/23 17:42 79-34-501/06/23 16:300.0065 0.0017 1
Tetrachloroethene 0.0043J mg/kg 01/06/23 17:42 127-18-401/06/23 16:300.0065 0.0021 1
Toluene 0.0063J mg/kg 01/06/23 17:42 108-88-301/06/23 16:300.0065 0.0019 1
1,2,3-Trichlorobenzene <0.0053 mg/kg 01/06/23 17:42 87-61-601/06/23 16:300.0065 0.0053 1
1,2,4-Trichlorobenzene <0.0055 mg/kg 01/06/23 17:42 120-82-101/06/23 16:300.0065 0.0055 1
1,1,1-Trichloroethane <0.0034 mg/kg 01/06/23 17:42 71-55-601/06/23 16:300.0065 0.0034 1
1,1,2-Trichloroethane <0.0022 mg/kg 01/06/23 17:42 79-00-501/06/23 16:300.0065 0.0022 1
Trichloroethene <0.0017 mg/kg 01/06/23 17:42 79-01-601/06/23 16:300.0065 0.0017 1
Trichlorofluoromethane <0.0036 mg/kg 01/06/23 17:42 75-69-401/06/23 16:300.0065 0.0036 1
1,2,3-Trichloropropane <0.0033 mg/kg 01/06/23 17:42 96-18-401/06/23 16:300.0065 0.0033 1
1,2,4-Trimethylbenzene <0.0018 mg/kg 01/06/23 17:42 95-63-601/06/23 16:300.0065 0.0018 1
1,3,5-Trimethylbenzene <0.0022 mg/kg 01/06/23 17:42 108-67-801/06/23 16:300.0065 0.0022 1
Vinyl acetate <0.0047 mg/kg 01/06/23 17:42 108-05-401/06/23 16:300.065 0.0047 1
Vinyl chloride <0.0033 mg/kg 01/06/23 17:42 75-01-4 v201/06/23 16:300.013 0.0033 1
Xylene (Total)<0.0037 mg/kg 01/06/23 17:42 1330-20-701/06/23 16:300.013 0.0037 1
m&p-Xylene <0.0045 mg/kg 01/06/23 17:42 179601-23-101/06/23 16:300.013 0.0045 1
o-Xylene <0.0029 mg/kg 01/06/23 17:42 95-47-601/06/23 16:300.0065 0.0029 1
Surrogates
Toluene-d8 (S)101 %01/06/23 17:42 2037-26-501/06/23 16:3070-130 1
4-Bromofluorobenzene (S)102 %01/06/23 17:42 460-00-401/06/23 16:3070-130 1
1,2-Dichloroethane-d4 (S)102 %01/06/23 17:42 17060-07-001/06/23 16:3070-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 20.5 %01/06/23 13:30 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2023 09:18 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92645404
SLC4431902 FORMER BOB MAYS AUT
Sample:>10 Lab ID:92645404002 Collected:01/05/23 13:45 Received:01/06/23 09:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone <0.045 mg/kg 01/06/23 17:59 67-64-101/06/23 16:300.14 0.045 1
Benzene <0.0028 mg/kg 01/06/23 17:59 71-43-201/06/23 16:300.0069 0.0028 1
Bromobenzene <0.0023 mg/kg 01/06/23 17:59 108-86-101/06/23 16:300.0069 0.0023 1
Bromochloromethane <0.0021 mg/kg 01/06/23 17:59 74-97-501/06/23 16:300.0069 0.0021 1
Bromodichloromethane <0.0027 mg/kg 01/06/23 17:59 75-27-401/06/23 16:300.0069 0.0027 1
Bromoform <0.0024 mg/kg 01/06/23 17:59 75-25-201/06/23 16:300.0069 0.0024 1
Bromomethane <0.011 mg/kg 01/06/23 17:59 74-83-901/06/23 16:300.014 0.011 1
2-Butanone (MEK)<0.033 mg/kg 01/06/23 17:59 78-93-301/06/23 16:300.14 0.033 1
n-Butylbenzene <0.0033 mg/kg 01/06/23 17:59 104-51-801/06/23 16:300.0069 0.0033 1
sec-Butylbenzene <0.0031 mg/kg 01/06/23 17:59 135-98-801/06/23 16:300.0069 0.0031 1
tert-Butylbenzene <0.0025 mg/kg 01/06/23 17:59 98-06-601/06/23 16:300.0069 0.0025 1
Carbon tetrachloride <0.0026 mg/kg 01/06/23 17:59 56-23-501/06/23 16:300.0069 0.0026 1
Chlorobenzene <0.0013 mg/kg 01/06/23 17:59 108-90-701/06/23 16:300.0069 0.0013 1
Chloroethane <0.0054 mg/kg 01/06/23 17:59 75-00-301/06/23 16:300.014 0.0054 1
Chloroform <0.0042 mg/kg 01/06/23 17:59 67-66-301/06/23 16:300.0069 0.0042 1
Chloromethane <0.0058 mg/kg 01/06/23 17:59 74-87-3 v201/06/23 16:300.014 0.0058 1
2-Chlorotoluene <0.0025 mg/kg 01/06/23 17:59 95-49-801/06/23 16:300.0069 0.0025 1
4-Chlorotoluene <0.0012 mg/kg 01/06/23 17:59 106-43-401/06/23 16:300.0069 0.0012 1
1,2-Dibromo-3-chloropropane <0.0027 mg/kg 01/06/23 17:59 96-12-8 IK01/06/23 16:300.0069 0.0027 1
Dibromochloromethane <0.0039 mg/kg 01/06/23 17:59 124-48-101/06/23 16:300.0069 0.0039 1
1,2-Dibromoethane (EDB)<0.0031 mg/kg 01/06/23 17:59 106-93-401/06/23 16:300.0069 0.0031 1
Dibromomethane <0.0015 mg/kg 01/06/23 17:59 74-95-301/06/23 16:300.0069 0.0015 1
1,2-Dichlorobenzene <0.0025 mg/kg 01/06/23 17:59 95-50-101/06/23 16:300.0069 0.0025 1
1,3-Dichlorobenzene <0.0021 mg/kg 01/06/23 17:59 541-73-101/06/23 16:300.0069 0.0021 1
1,4-Dichlorobenzene <0.0018 mg/kg 01/06/23 17:59 106-46-701/06/23 16:300.0069 0.0018 1
Dichlorodifluoromethane <0.0030 mg/kg 01/06/23 17:59 75-71-8 IH,v201/06/23 16:300.014 0.0030 1
1,1-Dichloroethane <0.0029 mg/kg 01/06/23 17:59 75-34-301/06/23 16:300.0069 0.0029 1
1,2-Dichloroethane <0.0046 mg/kg 01/06/23 17:59 107-06-201/06/23 16:300.0069 0.0046 1
1,1-Dichloroethene <0.0029 mg/kg 01/06/23 17:59 75-35-401/06/23 16:300.0069 0.0029 1
cis-1,2-Dichloroethene <0.0024 mg/kg 01/06/23 17:59 156-59-201/06/23 16:300.0069 0.0024 1
trans-1,2-Dichloroethene <0.0024 mg/kg 01/06/23 17:59 156-60-501/06/23 16:300.0069 0.0024 1
1,2-Dichloropropane <0.0021 mg/kg 01/06/23 17:59 78-87-501/06/23 16:300.0069 0.0021 1
1,3-Dichloropropane <0.0022 mg/kg 01/06/23 17:59 142-28-901/06/23 16:300.0069 0.0022 1
2,2-Dichloropropane <0.0023 mg/kg 01/06/23 17:59 594-20-701/06/23 16:300.0069 0.0023 1
1,1-Dichloropropene <0.0033 mg/kg 01/06/23 17:59 563-58-601/06/23 16:300.0069 0.0033 1
cis-1,3-Dichloropropene <0.0019 mg/kg 01/06/23 17:59 10061-01-501/06/23 16:300.0069 0.0019 1
trans-1,3-Dichloropropene <0.0024 mg/kg 01/06/23 17:59 10061-02-601/06/23 16:300.0069 0.0024 1
Diisopropyl ether <0.0019 mg/kg 01/06/23 17:59 108-20-301/06/23 16:300.0069 0.0019 1
Ethylbenzene <0.0032 mg/kg 01/06/23 17:59 100-41-401/06/23 16:300.0069 0.0032 1
Hexachloro-1,3-butadiene <0.011 mg/kg 01/06/23 17:59 87-68-301/06/23 16:300.014 0.011 1
2-Hexanone <0.0067 mg/kg 01/06/23 17:59 591-78-6 IK01/06/23 16:300.069 0.0067 1
Isopropylbenzene (Cumene)<0.0024 mg/kg 01/06/23 17:59 98-82-801/06/23 16:300.0069 0.0024 1
p-Isopropyltoluene <0.0034 mg/kg 01/06/23 17:59 99-87-601/06/23 16:300.0069 0.0034 1
Methylene Chloride 0.026J mg/kg 01/06/23 17:59 75-09-2 C901/06/23 16:300.028 0.019 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2023 09:18 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92645404
SLC4431902 FORMER BOB MAYS AUT
Sample:>10 Lab ID:92645404002 Collected:01/05/23 13:45 Received:01/06/23 09:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
4-Methyl-2-pentanone (MIBK)<0.0067 mg/kg 01/06/23 17:59 108-10-101/06/23 16:300.069 0.0067 1
Methyl-tert-butyl ether <0.0026 mg/kg 01/06/23 17:59 1634-04-401/06/23 16:300.0069 0.0026 1
Naphthalene 0.036 mg/kg 01/06/23 17:59 91-20-301/06/23 16:300.0069 0.0036 1
n-Propylbenzene <0.0025 mg/kg 01/06/23 17:59 103-65-101/06/23 16:300.0069 0.0025 1
Styrene <0.0018 mg/kg 01/06/23 17:59 100-42-501/06/23 16:300.0069 0.0018 1
1,1,1,2-Tetrachloroethane <0.0027 mg/kg 01/06/23 17:59 630-20-601/06/23 16:300.0069 0.0027 1
1,1,2,2-Tetrachloroethane <0.0018 mg/kg 01/06/23 17:59 79-34-501/06/23 16:300.0069 0.0018 1
Tetrachloroethene <0.0022 mg/kg 01/06/23 17:59 127-18-401/06/23 16:300.0069 0.0022 1
Toluene <0.0020 mg/kg 01/06/23 17:59 108-88-301/06/23 16:300.0069 0.0020 1
1,2,3-Trichlorobenzene <0.0056 mg/kg 01/06/23 17:59 87-61-601/06/23 16:300.0069 0.0056 1
1,2,4-Trichlorobenzene <0.0058 mg/kg 01/06/23 17:59 120-82-101/06/23 16:300.0069 0.0058 1
1,1,1-Trichloroethane <0.0036 mg/kg 01/06/23 17:59 71-55-601/06/23 16:300.0069 0.0036 1
1,1,2-Trichloroethane <0.0023 mg/kg 01/06/23 17:59 79-00-501/06/23 16:300.0069 0.0023 1
Trichloroethene <0.0018 mg/kg 01/06/23 17:59 79-01-601/06/23 16:300.0069 0.0018 1
Trichlorofluoromethane <0.0038 mg/kg 01/06/23 17:59 75-69-401/06/23 16:300.0069 0.0038 1
1,2,3-Trichloropropane <0.0035 mg/kg 01/06/23 17:59 96-18-401/06/23 16:300.0069 0.0035 1
1,2,4-Trimethylbenzene <0.0019 mg/kg 01/06/23 17:59 95-63-601/06/23 16:300.0069 0.0019 1
1,3,5-Trimethylbenzene <0.0023 mg/kg 01/06/23 17:59 108-67-801/06/23 16:300.0069 0.0023 1
Vinyl acetate <0.0050 mg/kg 01/06/23 17:59 108-05-401/06/23 16:300.069 0.0050 1
Vinyl chloride <0.0035 mg/kg 01/06/23 17:59 75-01-4 v201/06/23 16:300.014 0.0035 1
Xylene (Total)<0.0040 mg/kg 01/06/23 17:59 1330-20-701/06/23 16:300.014 0.0040 1
m&p-Xylene <0.0047 mg/kg 01/06/23 17:59 179601-23-101/06/23 16:300.014 0.0047 1
o-Xylene <0.0031 mg/kg 01/06/23 17:59 95-47-601/06/23 16:300.0069 0.0031 1
Surrogates
Toluene-d8 (S)102 %01/06/23 17:59 2037-26-501/06/23 16:3070-130 1
4-Bromofluorobenzene (S)101 %01/06/23 17:59 460-00-401/06/23 16:3070-130 1
1,2-Dichloroethane-d4 (S)102 %01/06/23 17:59 17060-07-001/06/23 16:3070-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 22.0 %01/06/23 13:30 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2023 09:18 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645404
SLC4431902 FORMER BOB MAYS AUT
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
747944
EPA 5035A/5030B
EPA 8260D
8260D 5035A 5030B
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92645404001, 92645404002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3888507
Associated Lab Samples:92645404001, 92645404002
Matrix:Solid
AnalyzedMDL
1,1,1,2-Tetrachloroethane mg/kg <0.0019 0.0050 01/06/23 15:390.0019
1,1,1-Trichloroethane mg/kg <0.0026 0.0050 01/06/23 15:390.0026
1,1,2,2-Tetrachloroethane mg/kg <0.0013 0.0050 01/06/23 15:390.0013
1,1,2-Trichloroethane mg/kg <0.0017 0.0050 01/06/23 15:390.0017
1,1-Dichloroethane mg/kg <0.0021 0.0050 01/06/23 15:390.0021
1,1-Dichloroethene mg/kg <0.0021 0.0050 01/06/23 15:390.0021
1,1-Dichloropropene mg/kg <0.0024 0.0050 01/06/23 15:390.0024
1,2,3-Trichlorobenzene mg/kg <0.0040 0.0050 01/06/23 15:390.0040
1,2,3-Trichloropropane mg/kg <0.0025 0.0050 01/06/23 15:390.0025
1,2,4-Trichlorobenzene mg/kg <0.0042 0.0050 01/06/23 15:390.0042
1,2,4-Trimethylbenzene mg/kg <0.0014 0.0050 01/06/23 15:390.0014
1,2-Dibromo-3-chloropropane mg/kg <0.0019 0.0050 IK01/06/23 15:390.0019
1,2-Dibromoethane (EDB)mg/kg <0.0022 0.0050 01/06/23 15:390.0022
1,2-Dichlorobenzene mg/kg <0.0018 0.0050 01/06/23 15:390.0018
1,2-Dichloroethane mg/kg <0.0033 0.0050 01/06/23 15:390.0033
1,2-Dichloropropane mg/kg <0.0015 0.0050 01/06/23 15:390.0015
1,3,5-Trimethylbenzene mg/kg <0.0017 0.0050 01/06/23 15:390.0017
1,3-Dichlorobenzene mg/kg <0.0016 0.0050 01/06/23 15:390.0016
1,3-Dichloropropane mg/kg <0.0016 0.0050 01/06/23 15:390.0016
1,4-Dichlorobenzene mg/kg <0.0013 0.0050 01/06/23 15:390.0013
2,2-Dichloropropane mg/kg <0.0016 0.0050 01/06/23 15:390.0016
2-Butanone (MEK)mg/kg <0.024 0.10 01/06/23 15:390.024
2-Chlorotoluene mg/kg <0.0018 0.0050 01/06/23 15:390.0018
2-Hexanone mg/kg <0.0048 0.050 IK01/06/23 15:390.0048
4-Chlorotoluene mg/kg <0.00088 0.0050 01/06/23 15:390.00088
4-Methyl-2-pentanone (MIBK)mg/kg <0.0048 0.050 01/06/23 15:390.0048
Acetone mg/kg <0.032 0.10 01/06/23 15:390.032
Benzene mg/kg <0.0020 0.0050 01/06/23 15:390.0020
Bromobenzene mg/kg <0.0016 0.0050 01/06/23 15:390.0016
Bromochloromethane mg/kg <0.0015 0.0050 01/06/23 15:390.0015
Bromodichloromethane mg/kg <0.0019 0.0050 01/06/23 15:390.0019
Bromoform mg/kg <0.0018 0.0050 01/06/23 15:390.0018
Bromomethane mg/kg <0.0079 0.010 01/06/23 15:390.0079
Carbon tetrachloride mg/kg <0.0019 0.0050 01/06/23 15:390.0019
Chlorobenzene mg/kg <0.00096 0.0050 01/06/23 15:390.00096
Chloroethane mg/kg <0.0039 0.010 01/06/23 15:390.0039
Chloroform mg/kg 0.0044J 0.0050 01/06/23 15:390.0030
Chloromethane mg/kg <0.0042 0.010 v201/06/23 15:390.0042
cis-1,2-Dichloroethene mg/kg <0.0017 0.0050 01/06/23 15:390.0017
cis-1,3-Dichloropropene mg/kg <0.0014 0.0050 01/06/23 15:390.0014
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2023 09:18 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645404
SLC4431902 FORMER BOB MAYS AUT
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3888507
Associated Lab Samples:92645404001, 92645404002
Matrix:Solid
AnalyzedMDL
Dibromochloromethane mg/kg <0.0028 0.0050 01/06/23 15:390.0028
Dibromomethane mg/kg <0.0011 0.0050 01/06/23 15:390.0011
Dichlorodifluoromethane mg/kg <0.0022 0.010 IH,v201/06/23 15:390.0022
Diisopropyl ether mg/kg <0.0014 0.0050 01/06/23 15:390.0014
Ethylbenzene mg/kg <0.0023 0.0050 01/06/23 15:390.0023
Hexachloro-1,3-butadiene mg/kg <0.0082 0.010 01/06/23 15:390.0082
Isopropylbenzene (Cumene)mg/kg <0.0017 0.0050 01/06/23 15:390.0017
m&p-Xylene mg/kg <0.0034 0.010 01/06/23 15:390.0034
Methyl-tert-butyl ether mg/kg <0.0019 0.0050 01/06/23 15:390.0019
Methylene Chloride mg/kg <0.014 0.020 01/06/23 15:390.014
n-Butylbenzene mg/kg <0.0024 0.0050 01/06/23 15:390.0024
n-Propylbenzene mg/kg <0.0018 0.0050 01/06/23 15:390.0018
Naphthalene mg/kg <0.0026 0.0050 01/06/23 15:390.0026
o-Xylene mg/kg <0.0022 0.0050 01/06/23 15:390.0022
p-Isopropyltoluene mg/kg <0.0025 0.0050 01/06/23 15:390.0025
sec-Butylbenzene mg/kg <0.0022 0.0050 01/06/23 15:390.0022
Styrene mg/kg <0.0013 0.0050 01/06/23 15:390.0013
tert-Butylbenzene mg/kg <0.0018 0.0050 01/06/23 15:390.0018
Tetrachloroethene mg/kg <0.0016 0.0050 01/06/23 15:390.0016
Toluene mg/kg <0.0014 0.0050 01/06/23 15:390.0014
trans-1,2-Dichloroethene mg/kg <0.0018 0.0050 01/06/23 15:390.0018
trans-1,3-Dichloropropene mg/kg <0.0017 0.0050 01/06/23 15:390.0017
Trichloroethene mg/kg <0.0013 0.0050 01/06/23 15:390.0013
Trichlorofluoromethane mg/kg <0.0028 0.0050 01/06/23 15:390.0028
Vinyl acetate mg/kg <0.0036 0.050 01/06/23 15:390.0036
Vinyl chloride mg/kg <0.0025 0.010 v201/06/23 15:390.0025
Xylene (Total)mg/kg <0.0028 0.010 01/06/23 15:390.0028
1,2-Dichloroethane-d4 (S)%103 70-130 01/06/23 15:39
4-Bromofluorobenzene (S)%97 70-130 01/06/23 15:39
Toluene-d8 (S)%101 70-130 01/06/23 15:39
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3888508LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane mg/kg 1.41.2 111 70-130
1,1,1-Trichloroethane mg/kg 1.31.2 103 70-130
1,1,2,2-Tetrachloroethane mg/kg 1.21.2 99 70-130
1,1,2-Trichloroethane mg/kg 1.21.2 100 70-130
1,1-Dichloroethane mg/kg 1.21.2 98 70-130
1,1-Dichloroethene mg/kg 1.31.2 101 70-130
1,1-Dichloropropene mg/kg 1.31.2 105 70-130
1,2,3-Trichlorobenzene mg/kg 1.21.2 98 70-130
1,2,3-Trichloropropane mg/kg 1.31.2 101 70-130
1,2,4-Trichlorobenzene mg/kg 1.31.2 104 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2023 09:18 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645404
SLC4431902 FORMER BOB MAYS AUT
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3888508LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene mg/kg 1.21.2 98 70-130
1,2-Dibromo-3-chloropropane mg/kg 1.4 IK1.2 111 67-130
1,2-Dibromoethane (EDB)mg/kg 1.31.2 106 70-130
1,2-Dichlorobenzene mg/kg 1.21.2 97 70-130
1,2-Dichloroethane mg/kg 1.21.2 97 70-130
1,2-Dichloropropane mg/kg 1.31.2 105 70-130
1,3,5-Trimethylbenzene mg/kg 1.31.2 105 70-130
1,3-Dichlorobenzene mg/kg 1.21.2 97 70-130
1,3-Dichloropropane mg/kg 1.21.2 99 70-130
1,4-Dichlorobenzene mg/kg 1.31.2 100 70-130
2,2-Dichloropropane mg/kg 1.31.2 102 67-130
2-Butanone (MEK)mg/kg 2.52.5 99 66-130
2-Chlorotoluene mg/kg 1.31.2 103 70-130
2-Hexanone mg/kg 2.7 IK2.5 108 70-130
4-Chlorotoluene mg/kg 1.31.2 104 70-130
4-Methyl-2-pentanone (MIBK)mg/kg 2.52.5 102 70-130
Acetone mg/kg 2.12.5 85 67-130
Benzene mg/kg 1.21.2 96 70-130
Bromobenzene mg/kg 1.21.2 99 70-130
Bromochloromethane mg/kg 1.21.2 94 70-130
Bromodichloromethane mg/kg 1.41.2 108 70-130
Bromoform mg/kg 1.41.2 113 70-130
Bromomethane mg/kg 1.51.2 118 53-175
Carbon tetrachloride mg/kg 1.41.2 114 70-130
Chlorobenzene mg/kg 1.31.2 102 70-130
Chloroethane mg/kg 1.41.2 110 70-135
Chloroform mg/kg 1.21.2 96 70-130
Chloromethane mg/kg 1.4 v31.2 114 64-130
cis-1,2-Dichloroethene mg/kg 1.31.2 103 70-130
cis-1,3-Dichloropropene mg/kg 1.31.2 105 70-130
Dibromochloromethane mg/kg 1.41.2 113 70-130
Dibromomethane mg/kg 1.31.2 105 70-130
Dichlorodifluoromethane mg/kg 1.7 IH,v31.2 133 63-145
Diisopropyl ether mg/kg 1.21.2 98 68-130
Ethylbenzene mg/kg 1.21.2 99 70-130
Hexachloro-1,3-butadiene mg/kg 1.31.2 104 70-130
Isopropylbenzene (Cumene)mg/kg 1.41.2 108 70-130
m&p-Xylene mg/kg 2.72.5 107 70-130
Methyl-tert-butyl ether mg/kg 1.21.2 95 70-130
Methylene Chloride mg/kg 1.21.2 96 67-130
n-Butylbenzene mg/kg 1.31.2 104 70-130
n-Propylbenzene mg/kg 1.31.2 101 70-130
Naphthalene mg/kg 1.21.2 99 70-130
o-Xylene mg/kg 1.31.2 104 70-130
p-Isopropyltoluene mg/kg 1.31.2 106 70-130
sec-Butylbenzene mg/kg 1.31.2 102 70-130
Styrene mg/kg 1.41.2 111 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2023 09:18 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645404
SLC4431902 FORMER BOB MAYS AUT
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3888508LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butylbenzene mg/kg 1.21.2 94 64-130
Tetrachloroethene mg/kg 1.31.2 105 70-130
Toluene mg/kg 1.31.2 100 70-130
trans-1,2-Dichloroethene mg/kg 1.31.2 102 70-130
trans-1,3-Dichloropropene mg/kg 1.31.2 108 70-130
Trichloroethene mg/kg 1.41.2 110 70-130
Trichlorofluoromethane mg/kg 1.21.2 99 70-130
Vinyl acetate mg/kg 2.72.5 109 70-134
Vinyl chloride mg/kg 1.4 v31.2 113 68-130
Xylene (Total)mg/kg 4.03.8 106 70-130
1,2-Dichloroethane-d4 (S)%85 70-130
4-Bromofluorobenzene (S)%104 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3888509MATRIX SPIKE SAMPLE:
MSSpike
Result
92645404001
1,1,1,2-Tetrachloroethane mg/kg 0.600.65 91 58-140<0.0025
1,1,1-Trichloroethane mg/kg 0.640.65 99 58-144<0.0034
1,1,2,2-Tetrachloroethane mg/kg 0.560.65 86 52-139<0.0017
1,1,2-Trichloroethane mg/kg 0.600.65 92 56-140<0.0022
1,1-Dichloroethane mg/kg 0.640.65 98 58-145<0.0027
1,1-Dichloroethene mg/kg 0.680.65 104 57-158<0.0027
1,1-Dichloropropene mg/kg 0.660.65 102 58-151<0.0031
1,2,3-Trichlorobenzene mg/kg 0.450.65 70 48-149<0.0053
1,2,3-Trichloropropane mg/kg 0.560.65 86 54-132<0.0033
1,2,4-Trichlorobenzene mg/kg 0.550.65 85 51-151<0.0055
1,2,4-Trimethylbenzene mg/kg 0.590.65 91 38-170<0.0018
1,2-Dibromo-3-chloropropane mg/kg 0.52 IK0.65 80 44-134<0.0025
1,2-Dibromoethane (EDB)mg/kg 0.600.65 92 60-138<0.0029
1,2-Dichlorobenzene mg/kg 0.580.65 88 59-147<0.0023
1,2-Dichloroethane mg/kg 0.620.65 94 57-139<0.0043
1,2-Dichloropropane mg/kg 0.650.65 100 62-145<0.0020
1,3,5-Trimethylbenzene mg/kg 0.630.65 96 47-159<0.0022
1,3-Dichlorobenzene mg/kg 0.570.65 88 58-144<0.0020
1,3-Dichloropropane mg/kg 0.570.65 88 60-142<0.0020
1,4-Dichlorobenzene mg/kg 0.590.65 90 57-143<0.0017
2,2-Dichloropropane mg/kg 0.620.65 95 37-144<0.0021
2-Butanone (MEK)mg/kg 1.21.3 93 28-146<0.031
2-Chlorotoluene mg/kg 0.610.65 93 55-158<0.0023
2-Hexanone mg/kg 1.1 IK1.3 83 44-141<0.0063
4-Chlorotoluene mg/kg 0.620.65 95 55-146<0.0012
4-Methyl-2-pentanone (MIBK)mg/kg 1.21.3 92 50-138<0.0063
Acetone mg/kg 0.961.3 74 20-136<0.042
Benzene mg/kg 0.600.65 92 60-145<0.0026
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2023 09:18 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645404
SLC4431902 FORMER BOB MAYS AUT
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3888509MATRIX SPIKE SAMPLE:
MSSpike
Result
92645404001
Bromobenzene mg/kg 0.580.65 89 59-145<0.0021
Bromochloromethane mg/kg 0.600.65 92 57-143<0.0019
Bromodichloromethane mg/kg 0.610.65 94 53-133<0.0025
Bromoform mg/kg 0.550.65 85 48-133<0.0023
Bromomethane mg/kg 0.530.65 81 10-167<0.010
Carbon tetrachloride mg/kg 0.500.65 76 57-147<0.0024
Chlorobenzene mg/kg 0.590.65 91 61-144<0.0013
Chloroethane mg/kg 0.360.65 55 10-153<0.0050
Chloroform mg/kg 0.620.65 95 58-141<0.0040
Chloromethane mg/kg 0.76 v30.65 116 54-165<0.0055
cis-1,2-Dichloroethene mg/kg 0.660.65 101 59-144<0.0022
cis-1,3-Dichloropropene mg/kg 0.620.65 95 56-137<0.0018
Dibromochloromethane mg/kg 0.580.65 89 53-139<0.0037
Dibromomethane mg/kg 0.620.65 95 60-136<0.0014
Dichlorodifluoromethane mg/kg 0.87 IH,v30.65 133 49-177<0.0028
Diisopropyl ether mg/kg 0.600.65 92 53-136<0.0018
Ethylbenzene mg/kg 0.560.65 87 53-150<0.0030
Hexachloro-1,3-butadiene mg/kg 0.650.65 100 42-186<0.011
Isopropylbenzene (Cumene)mg/kg 0.630.65 97 62-154<0.0022
m&p-Xylene mg/kg 1.21.3 93 49-156<0.0045
Methyl-tert-butyl ether mg/kg 0.590.65 91 54-133<0.0024
Methylene Chloride mg/kg 0.640.65 98 50-153<0.018
n-Butylbenzene mg/kg 0.620.65 94 44-174<0.0031
n-Propylbenzene mg/kg 0.620.65 95 52-157<0.0023
Naphthalene mg/kg 0.450.65 66 37-1500.021
o-Xylene mg/kg 0.600.65 92 54-150<0.0029
p-Isopropyltoluene mg/kg 0.640.65 97 50-1640.0043J
sec-Butylbenzene mg/kg 0.650.65 99 58-161<0.0029
Styrene mg/kg 0.610.65 94 60-148<0.0017
tert-Butylbenzene mg/kg 0.590.65 90 44-151<0.0023
Tetrachloroethene mg/kg 0.580.65 88 53-1510.0043J
Toluene mg/kg 0.620.65 95 52-1480.0063J
trans-1,2-Dichloroethene mg/kg 0.670.65 103 60-148<0.0023
trans-1,3-Dichloropropene mg/kg 0.630.65 96 55-133<0.0022
Trichloroethene mg/kg 0.680.65 104 60-148<0.0017
Trichlorofluoromethane mg/kg 0.460.65 70 10-154<0.0036
Vinyl acetate mg/kg 1.21.3 95 50-149<0.0047
Vinyl chloride mg/kg 0.72 v30.65 110 57-157<0.0033
Xylene (Total)mg/kg 1.82 93 52-153<0.0037
1,2-Dichloroethane-d4 (S)%112 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%102 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2023 09:18 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645404
SLC4431902 FORMER BOB MAYS AUT
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92645404002
3888510SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane mg/kg <0.0027 30<0.0027
1,1,1-Trichloroethane mg/kg <0.0036 30<0.0036
1,1,2,2-Tetrachloroethane mg/kg <0.0018 30<0.0018
1,1,2-Trichloroethane mg/kg <0.0023 30<0.0023
1,1-Dichloroethane mg/kg <0.0029 30<0.0029
1,1-Dichloroethene mg/kg <0.0029 30<0.0029
1,1-Dichloropropene mg/kg <0.0033 30<0.0033
1,2,3-Trichlorobenzene mg/kg <0.0056 30<0.0056
1,2,3-Trichloropropane mg/kg <0.0035 30<0.0035
1,2,4-Trichlorobenzene mg/kg <0.0058 30<0.0058
1,2,4-Trimethylbenzene mg/kg <0.0019 30<0.0019
1,2-Dibromo-3-chloropropane mg/kg <0.0027 IK30<0.0027
1,2-Dibromoethane (EDB)mg/kg <0.0031 30<0.0031
1,2-Dichlorobenzene mg/kg <0.0025 30<0.0025
1,2-Dichloroethane mg/kg <0.0046 30<0.0046
1,2-Dichloropropane mg/kg <0.0021 30<0.0021
1,3,5-Trimethylbenzene mg/kg <0.0023 30<0.0023
1,3-Dichlorobenzene mg/kg <0.0021 30<0.0021
1,3-Dichloropropane mg/kg <0.0022 30<0.0022
1,4-Dichlorobenzene mg/kg <0.0018 30<0.0018
2,2-Dichloropropane mg/kg <0.0023 30<0.0023
2-Butanone (MEK)mg/kg <0.033 30<0.033
2-Chlorotoluene mg/kg <0.0025 30<0.0025
2-Hexanone mg/kg <0.0067 IK30<0.0067
4-Chlorotoluene mg/kg <0.0012 30<0.0012
4-Methyl-2-pentanone (MIBK)mg/kg <0.0067 30<0.0067
Acetone mg/kg <0.045 30<0.045
Benzene mg/kg <0.0028 30<0.0028
Bromobenzene mg/kg <0.0023 30<0.0023
Bromochloromethane mg/kg <0.0021 30<0.0021
Bromodichloromethane mg/kg <0.0027 30<0.0027
Bromoform mg/kg <0.0024 30<0.0024
Bromomethane mg/kg <0.011 30<0.011
Carbon tetrachloride mg/kg <0.0026 30<0.0026
Chlorobenzene mg/kg <0.0013 30<0.0013
Chloroethane mg/kg <0.0054 30<0.0054
Chloroform mg/kg <0.0042 30<0.0042
Chloromethane mg/kg <0.0058 v230<0.0058
cis-1,2-Dichloroethene mg/kg <0.0024 30<0.0024
cis-1,3-Dichloropropene mg/kg <0.0019 30<0.0019
Dibromochloromethane mg/kg <0.0039 30<0.0039
Dibromomethane mg/kg <0.0015 30<0.0015
Dichlorodifluoromethane mg/kg <0.0030 IH,v230<0.0030
Diisopropyl ether mg/kg <0.0019 30<0.0019
Ethylbenzene mg/kg <0.0032 30<0.0032
Hexachloro-1,3-butadiene mg/kg <0.011 30<0.011
Isopropylbenzene (Cumene)mg/kg <0.0024 30<0.0024
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/10/2023 09:18 AM
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Page 14 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645404
SLC4431902 FORMER BOB MAYS AUT
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92645404002
3888510SAMPLE DUPLICATE:
m&p-Xylene mg/kg <0.0047 30<0.0047
Methyl-tert-butyl ether mg/kg <0.0026 30<0.0026
Methylene Chloride mg/kg 0.023J 300.026J
n-Butylbenzene mg/kg <0.0033 30<0.0033
n-Propylbenzene mg/kg <0.0025 30<0.0025
Naphthalene mg/kg 0.037 3 300.036
o-Xylene mg/kg <0.0031 30<0.0031
p-Isopropyltoluene mg/kg <0.0034 30<0.0034
sec-Butylbenzene mg/kg <0.0031 30<0.0031
Styrene mg/kg <0.0018 30<0.0018
tert-Butylbenzene mg/kg <0.0025 30<0.0025
Tetrachloroethene mg/kg <0.0022 30<0.0022
Toluene mg/kg <0.0020 30<0.0020
trans-1,2-Dichloroethene mg/kg <0.0024 30<0.0024
trans-1,3-Dichloropropene mg/kg <0.0024 30<0.0024
Trichloroethene mg/kg <0.0018 30<0.0018
Trichlorofluoromethane mg/kg <0.0038 30<0.0038
Vinyl acetate mg/kg <0.0050 30<0.0050
Vinyl chloride mg/kg <0.0035 v230<0.0035
Xylene (Total)mg/kg <0.0040 30<0.0040
1,2-Dichloroethane-d4 (S)%99102
4-Bromofluorobenzene (S)%100101
Toluene-d8 (S)%101102
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/10/2023 09:18 AM
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Page 15 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645404
SLC4431902 FORMER BOB MAYS AUT
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
747866
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92645404001, 92645404002
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92644911002
3888197SAMPLE DUPLICATE:
Percent Moisture %88.5 N202588.5
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92645503005
3888207SAMPLE DUPLICATE:
Percent Moisture %32.6 N242533.9
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/10/2023 09:18 AM
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Page 16 of 21
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92645404
SLC4431902 FORMER BOB MAYS AUT
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Common Laboratory Contaminant.C9
This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.IH
The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.IK
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.v2
The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.v3
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/10/2023 09:18 AM
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Page 17 of 21
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92645404
SLC4431902 FORMER BOB MAYS AUT
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92645404001 747944 7481010-10 EPA 5035A/5030B EPA 8260D
92645404002 747944 748101>10 EPA 5035A/5030B EPA 8260D
92645404001 7478660-10 SW-846
92645404002 747866>10 SW-846
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/10/2023 09:18 AM
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[phone]
Page 18 of 21
Page 19 of 21
Page 20 of 21
Page 21 of 21
#=CL#
January 18, 2023
LIMS USE: FR - AL QUARLES
LIMS OBJECT ID: 92645777
92645777
Project:
Pace Project No.:
RE:
Al Quarles
ATC Group Services LLC
7606 Whitehall Executive Cente
Suite 800
Charlotte, NC 28273
BOB MAY'S SLC4431902
Dear Al Quarles:
Enclosed are the analytical results for sample(s) received by the laboratory on January 09, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
Some analyses were subcontracted outside of the Pace Network. The test report from the external subcontractor is
attached to this report in its entirety.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Ormond Beach
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni for
[e-mail]
Project Manager
Taylor M Cannon
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 41
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CS/UST/LUST
Alabama Certification #: 41320
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maine Certification #: FL01264
Maryland Certification: #346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
New Hampshire Certification #: 2958
New Jersey Certification #: FL022
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Ohio DEP 87780
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 2 of 41
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Lab ID Sample ID Matrix Date Collected Date Received
92645777001 >10 Solid 01/05/23 13:45 01/09/23 12:41
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 3 of 41
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92645777001 >10 EPA 8081B 24 PASI-CBAJ
EPA 8082A 8 PASI-CBAJ
EPA 6010 16 PASI-OKC2, TMA
EPA 7471 1 PASI-OJNK
EPA 8270E 122 PASI-CBPJ
SW-846 1 PASI-CKDF
SM 4500-S2D-2011 Modified 1 PASI-AJP1
SM 4500-CN-E-2011 1 PASI-AANM
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Huntersville, NC 28078
[phone]
Page 4 of 41
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Sample:>10 Lab ID:92645777001 Collected:01/05/23 13:45 Received:01/09/23 12:41 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 8081B Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8081 GCS Pesticides
alpha-BHC <1.1 ug/kg 01/12/23 11:07 319-84-601/10/23 16:222.5 1.1 1
gamma-BHC (Lindane)<1.0 ug/kg 01/12/23 11:07 58-89-901/10/23 16:222.5 1.0 1
beta-BHC <1.2 ug/kg 01/12/23 11:07 319-85-701/10/23 16:222.5 1.2 1
Heptachlor <1.2 ug/kg 01/12/23 11:07 76-44-801/10/23 16:222.5 1.2 1
delta-BHC <1.2 ug/kg 01/12/23 11:07 319-86-801/10/23 16:222.5 1.2 1
Aldrin <1.0 ug/kg 01/12/23 11:07 309-00-201/10/23 16:222.5 1.0 1
Heptachlor epoxide <0.99 ug/kg 01/12/23 11:07 1024-57-301/10/23 16:222.5 0.99 1
Endosulfan I <1.1 ug/kg 01/12/23 11:07 959-98-801/10/23 16:222.5 1.1 1
4,4'-DDE <1.2 ug/kg 01/12/23 11:07 72-55-901/10/23 16:222.5 1.2 1
Dieldrin <1.1 ug/kg 01/12/23 11:07 60-57-101/10/23 16:222.5 1.1 1
Endrin <1.2 ug/kg 01/12/23 11:07 72-20-801/10/23 16:222.5 1.2 1
4,4'-DDD <1.1 ug/kg 01/12/23 11:07 72-54-801/10/23 16:222.5 1.1 1
Endosulfan II <1.1 ug/kg 01/12/23 11:07 33213-65-901/10/23 16:222.5 1.1 1
4,4'-DDT <1.1 ug/kg 01/12/23 11:07 50-29-301/10/23 16:222.5 1.1 1
Endrin aldehyde <1.7 ug/kg 01/12/23 11:07 7421-93-401/10/23 16:222.5 1.7 1
Endosulfan sulfate <1.4 ug/kg 01/12/23 11:07 1031-07-801/10/23 16:222.5 1.4 1
Methoxychlor <3.1 ug/kg 01/12/23 11:07 72-43-501/10/23 16:226.3 3.1 1
Endrin ketone <1.4 ug/kg 01/12/23 11:07 53494-70-501/10/23 16:222.5 1.4 1
Chlordane (Technical)<10.9 ug/kg 01/12/23 11:07 57-74-901/10/23 16:2212.5 10.9 1
Toxaphene <6.7 ug/kg 01/12/23 11:07 8001-35-201/10/23 16:228.8 6.7 1
Mirex <2.8 ug/kg 01/12/23 11:07 2385-85-501/10/23 16:226.3 2.8 1
Hexachlorobenzene <1.0 ug/kg 01/12/23 11:07 118-74-101/10/23 16:222.5 1.0 1
Surrogates
Tetrachloro-m-xylene (S)66 %01/12/23 11:07 877-09-801/10/23 16:2210-133 1
Decachlorobiphenyl (S)91 %01/12/23 11:07 2051-24-301/10/23 16:2210-146 1
Analytical Method: EPA 8082A Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8082 GCS PCB
PCB-1016 (Aroclor 1016)<16.3 ug/kg 01/18/23 10:33 12674-11-201/17/23 14:4841.1 16.3 1
PCB-1221 (Aroclor 1221)<27.6 ug/kg 01/18/23 10:33 11104-28-201/17/23 14:4841.1 27.6 1
PCB-1232 (Aroclor 1232)<18.3 ug/kg 01/18/23 10:33 11141-16-501/17/23 14:4841.1 18.3 1
PCB-1242 (Aroclor 1242)<10 ug/kg 01/18/23 10:33 53469-21-901/17/23 14:4841.1 10 1
PCB-1248 (Aroclor 1248)<11.1 ug/kg 01/18/23 10:33 12672-29-601/17/23 14:4841.1 11.1 1
PCB-1254 (Aroclor 1254)<18.0 ug/kg 01/18/23 10:33 11097-69-101/17/23 14:4841.1 18.0 1
PCB-1260 (Aroclor 1260)<18.2 ug/kg 01/18/23 10:33 11096-82-501/17/23 14:4841.1 18.2 1
Surrogates
Decachlorobiphenyl (S)65 %01/18/23 10:33 2051-24-301/17/23 14:4810-160 1
Analytical Method: EPA 6010 Preparation Method: EPA 3050
Pace Analytical Services - Ormond Beach
6010 MET ICP
Antimony <0.43 mg/kg 01/13/23 09:03 7440-36-001/12/23 16:030.87 0.43 1
Arsenic 1.1 mg/kg 01/13/23 09:03 7440-38-201/12/23 16:030.58 0.29 1
Barium 64.0 mg/kg 01/13/23 09:03 7440-39-301/12/23 16:030.58 0.097 1
Beryllium 0.89 mg/kg 01/13/23 09:03 7440-41-701/12/23 16:030.058 0.010 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
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Page 5 of 41
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Sample:>10 Lab ID:92645777001 Collected:01/05/23 13:45 Received:01/09/23 12:41 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 6010 Preparation Method: EPA 3050
Pace Analytical Services - Ormond Beach
6010 MET ICP
Cadmium 0.56 mg/kg 01/13/23 09:03 7440-43-901/12/23 16:030.058 0.029 1
Chromium 18.9 mg/kg 01/13/23 09:03 7440-47-301/12/23 16:030.29 0.14 1
Cobalt 4.4 mg/kg 01/13/23 09:03 7440-48-401/12/23 16:030.58 0.065 1
Copper 13.5 mg/kg 01/13/23 09:03 7440-50-801/12/23 16:030.29 0.14 1
Lead 36.6 mg/kg 01/13/23 09:03 7439-92-101/12/23 16:030.58 0.29 1
Nickel 7.5 mg/kg 01/13/23 09:03 7440-02-001/12/23 16:030.29 0.14 1
Selenium <0.43 mg/kg 01/13/23 09:03 7782-49-201/12/23 16:030.87 0.43 1
Silver <0.064 mg/kg 01/13/23 09:03 7440-22-401/12/23 16:030.29 0.064 1
Thallium <0.38 mg/kg 01/13/23 09:03 7440-28-001/12/23 16:030.87 0.38 1
Tin 7.5 mg/kg 01/13/23 09:03 7440-31-501/12/23 16:032.9 1.4 1
Vanadium 24.1 mg/kg 01/13/23 09:03 7440-62-201/12/23 16:030.58 0.061 1
Zinc 404 mg/kg 01/17/23 11:03 7440-66-601/12/23 16:0328.9 10.4 5
Analytical Method: EPA 7471 Preparation Method: EPA 7471
Pace Analytical Services - Ormond Beach
7471 Mercury
Mercury 0.078 mg/kg 01/16/23 14:46 7439-97-601/12/23 14:550.011 0.0055 1
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Acenaphthene <148 ug/kg 01/18/23 10:44 83-32-901/17/23 14:424221481
Acenaphthylene <148 ug/kg 01/18/23 10:44 208-96-801/17/23 14:424221481
Acetophenone <109 ug/kg 01/18/23 10:44 98-86-201/17/23 14:424221091
2-Acetylaminofluorene <120 ug/kg 01/18/23 10:44 53-96-3 v101/17/23 14:428441201
4-Aminobiphenyl <96.3 ug/kg 01/18/23 10:44 92-67-1 M101/17/23 14:4242296.3 1
Aniline <165 ug/kg 01/18/23 10:44 62-53-301/17/23 14:424221651
Anthracene <138 ug/kg 01/18/23 10:44 120-12-701/17/23 14:424221381
Aramite <98.2 ug/kg 01/18/23 10:44 140-57-8 M101/17/23 14:42211098.2 1
Benzo(a)anthracene <141 ug/kg 01/18/23 10:44 56-55-301/17/23 14:424221411
Benzo(a)pyrene <146 ug/kg 01/18/23 10:44 50-32-801/17/23 14:424221461
Benzo(b)fluoranthene <141 ug/kg 01/18/23 10:44 205-99-201/17/23 14:424221411
Benzo(g,h,i)perylene <164 ug/kg 01/18/23 10:44 191-24-201/17/23 14:424221641
Benzo(k)fluoranthene <148 ug/kg 01/18/23 10:44 207-08-901/17/23 14:424221481
Benzyl alcohol <320 ug/kg 01/18/23 10:44 100-51-601/17/23 14:428443201
4-Bromophenylphenyl ether <162 ug/kg 01/18/23 10:44 101-55-301/17/23 14:424221621
Butylbenzylphthalate <178 ug/kg 01/18/23 10:44 85-68-701/17/23 14:424221781
4-Chloro-3-methylphenol <297 ug/kg 01/18/23 10:44 59-50-701/17/23 14:428442971
4-Chloroaniline <331 ug/kg 01/18/23 10:44 106-47-801/17/23 14:428443311
Chlorobenzilate <83.3 ug/kg 01/18/23 10:44 510-15-6 M101/17/23 14:4242283.3 1
bis(2-Chloroethoxy)methane <175 ug/kg 01/18/23 10:44 111-91-101/17/23 14:424221751
bis(2-Chloroethyl) ether <159 ug/kg 01/18/23 10:44 111-44-401/17/23 14:424221591
2-Chloronaphthalene <167 ug/kg 01/18/23 10:44 91-58-701/17/23 14:424221671
2-Chlorophenol <159 ug/kg 01/18/23 10:44 95-57-801/17/23 14:424221591
4-Chlorophenylphenyl ether <157 ug/kg 01/18/23 10:44 7005-72-301/17/23 14:424221571
Chrysene <153 ug/kg 01/18/23 10:44 218-01-901/17/23 14:424221531
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 41
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Sample:>10 Lab ID:92645777001 Collected:01/05/23 13:45 Received:01/09/23 12:41 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Diallate <141 ug/kg 01/18/23 10:44 2303-16-401/17/23 14:424221411
Dibenz(a,h)anthracene <162 ug/kg 01/18/23 10:44 53-70-301/17/23 14:424221621
Dibenzofuran <152 ug/kg 01/18/23 10:44 132-64-901/17/23 14:424221521
3,3'-Dichlorobenzidine <285 ug/kg 01/18/23 10:44 91-94-101/17/23 14:428442851
2,4-Dichlorophenol <165 ug/kg 01/18/23 10:44 120-83-201/17/23 14:424221651
2,6-Dichlorophenol <108 ug/kg 01/18/23 10:44 87-65-001/17/23 14:424221081
Diethylphthalate <155 ug/kg 01/18/23 10:44 84-66-201/17/23 14:424221551
Dimethoate <225 ug/kg 01/18/23 10:44 60-51-5 v101/17/23 14:428442251
P-Dimethylaminoazobenzene <40.3 ug/kg 01/18/23 10:44 60-11-7 IL,M101/17/23 14:4242240.3 1
7,12-Dimethylbenz(a)anthracene <174 ug/kg 01/18/23 10:44 57-97-6 M101/17/23 14:424221741
3,3'-Dimethylbenzidine <376 ug/kg 01/18/23 10:44 119-93-7 IH01/17/23 14:428443761
2,4-Dimethylphenol <175 ug/kg 01/18/23 10:44 105-67-901/17/23 14:424221751
a,a-Dimethylphenylethylamine <330 ug/kg 01/18/23 10:44 122-09-8 M1,v101/17/23 14:4221103301
Dimethylphthalate <153 ug/kg 01/18/23 10:44 131-11-301/17/23 14:424221531
Di-n-butylphthalate <142 ug/kg 01/18/23 10:44 84-74-201/17/23 14:424221421
4,6-Dinitro-2-methylphenol <394 ug/kg 01/18/23 10:44 534-52-101/17/23 14:428443941
1,3-Dinitrobenzene <94.7 ug/kg 01/18/23 10:44 99-65-001/17/23 14:4242294.7 1
2,4-Dinitrophenol <1300 ug/kg 01/18/23 10:44 51-28-501/17/23 14:42211013001
2,4-Dinitrotoluene <162 ug/kg 01/18/23 10:44 121-14-201/17/23 14:424221621
2,6-Dinitrotoluene <155 ug/kg 01/18/23 10:44 606-20-201/17/23 14:424221551
Di-n-octylphthalate <166 ug/kg 01/18/23 10:44 117-84-001/17/23 14:424221661
Dinoseb <225 ug/kg 01/18/23 10:44 88-85-7 v101/17/23 14:428442251
Diphenylamine <166 ug/kg 01/18/23 10:44 122-39-401/17/23 14:424221661
Disulfoton <122 ug/kg 01/18/23 10:44 298-04-401/17/23 14:424221221
bis(2-Ethylhexyl)phthalate <164 ug/kg 01/18/23 10:44 117-81-701/17/23 14:424221641
Ethyl methanesulfonate <225 ug/kg 01/18/23 10:44 62-50-001/17/23 14:428442251
Famphur <213 ug/kg 01/18/23 10:44 52-85-7 IH01/17/23 14:428442131
Fluoranthene <144 ug/kg 01/18/23 10:44 206-44-001/17/23 14:424221441
Fluorene <148 ug/kg 01/18/23 10:44 86-73-701/17/23 14:424221481
Hexachlorobenzene <165 ug/kg 01/18/23 10:44 118-74-101/17/23 14:424221651
Hexachlorocyclopentadiene <242 ug/kg 01/18/23 10:44 77-47-401/17/23 14:424222421
Hexachloroethane <161 ug/kg 01/18/23 10:44 67-72-101/17/23 14:424221611
Hexachlorophene <2450 ug/kg 01/18/23 10:44 70-30-4 IL,M1,
v201/17/23 14:42422024501
Hexachloropropene <115 ug/kg 01/18/23 10:44 1888-71-701/17/23 14:424221151
Indeno(1,2,3-cd)pyrene <166 ug/kg 01/18/23 10:44 193-39-501/17/23 14:424221661
Isodrin <100 ug/kg 01/18/23 10:44 465-73-601/17/23 14:424221001
Isophorone <188 ug/kg 01/18/23 10:44 78-59-101/17/23 14:424221881
Isosafrole <320 ug/kg 01/18/23 10:44 120-58-101/17/23 14:424223201
Kepone <465 ug/kg 01/18/23 10:44 143-50-0 M101/17/23 14:428444651
Methapyrilene <325 ug/kg 01/18/23 10:44 91-80-5 v101/17/23 14:4221103251
3-Methylcholanthrene <160 ug/kg 01/18/23 10:44 56-49-501/17/23 14:424221601
Methyl methanesulfonate <182 ug/kg 01/18/23 10:44 66-27-3 v101/17/23 14:428441821
2-Methylnaphthalene <169 ug/kg 01/18/23 10:44 91-57-601/17/23 14:424221691
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 41
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Sample:>10 Lab ID:92645777001 Collected:01/05/23 13:45 Received:01/09/23 12:41 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Methyl parathion <211 ug/kg 01/18/23 10:44 298-00-0 v101/17/23 14:424222111
2-Methylphenol(o-Cresol)<173 ug/kg 01/18/23 10:44 95-48-701/17/23 14:424221731
3&4-Methylphenol(m&p Cresol)<170 ug/kg 01/18/23 10:44 15831-10-401/17/23 14:424221701
1-Naphthalenamine <142 ug/kg 01/18/23 10:44 134-32-7 M101/17/23 14:428441421
2-Naphthalenamine <162 ug/kg 01/18/23 10:44 91-59-8 M101/17/23 14:428441621
1,4-Naphthoquinone <110 ug/kg 01/18/23 10:44 130-15-4 M101/17/23 14:4221101101
2-Nitroaniline <345 ug/kg 01/18/23 10:44 88-74-401/17/23 14:4221103451
3-Nitroaniline <331 ug/kg 01/18/23 10:44 99-09-201/17/23 14:4221103311
4-Nitroaniline <321 ug/kg 01/18/23 10:44 100-01-601/17/23 14:428443211
Nitrobenzene <196 ug/kg 01/18/23 10:44 98-95-301/17/23 14:424221961
2-Nitrophenol <183 ug/kg 01/18/23 10:44 88-75-501/17/23 14:424221831
4-Nitrophenol <816 ug/kg 01/18/23 10:44 100-02-701/17/23 14:4221108161
4-Nitroquinoline-n-oxide <312 ug/kg 01/18/23 10:44 56-57-501/17/23 14:4221103121
5-Nitro-o-toluidine <127 ug/kg 01/18/23 10:44 99-55-801/17/23 14:424221271
N-Nitrosodiethylamine <88.0 ug/kg 01/18/23 10:44 55-18-501/17/23 14:4242288.0 1
N-Nitrosodimethylamine <142 ug/kg 01/18/23 10:44 62-75-901/17/23 14:424221421
N-Nitroso-di-n-butylamine <146 ug/kg 01/18/23 10:44 924-16-301/17/23 14:424221461
N-Nitroso-di-n-propylamine <159 ug/kg 01/18/23 10:44 621-64-701/17/23 14:424221591
N-Nitrosodiphenylamine <150 ug/kg 01/18/23 10:44 86-30-601/17/23 14:424221501
N-Nitrosomethylethylamine <90.1 ug/kg 01/18/23 10:44 10595-95-601/17/23 14:4242290.1 1
N-Nitrosomorpholine <122 ug/kg 01/18/23 10:44 59-89-201/17/23 14:424221221
N-Nitrosopiperidine <85.0 ug/kg 01/18/23 10:44 100-75-401/17/23 14:4284485.0 1
N-Nitrosopyrrolidine <97.7 ug/kg 01/18/23 10:44 930-55-201/17/23 14:4284497.7 1
O,O,O-Triethylphosphorothioate <84.9 ug/kg 01/18/23 10:44 126-68-1 M101/17/23 14:4242284.9 1
2,2'-Oxybis(1-chloropropane)<201 ug/kg 01/18/23 10:44 108-60-101/17/23 14:424222011
Parathion (Ethyl parathion)<141 ug/kg 01/18/23 10:44 56-38-2 v101/17/23 14:424221411
Pentachlorobenzene <106 ug/kg 01/18/23 10:44 608-93-501/17/23 14:424221061
Pentachloroethane <76.6 ug/kg 01/18/23 10:44 76-01-7 M101/17/23 14:4242276.6 1
Pentachloronitrobenzene <136 ug/kg 01/18/23 10:44 82-68-801/17/23 14:424221361
Pentachlorophenol <413 ug/kg 01/18/23 10:44 87-86-501/17/23 14:428444131
Phenacetin <137 ug/kg 01/18/23 10:44 62-44-201/17/23 14:428441371
Phenanthrene <138 ug/kg 01/18/23 10:44 85-01-801/17/23 14:424221381
Phenol <188 ug/kg 01/18/23 10:44 108-95-201/17/23 14:424221881
p-Phenylenediamine <844 ug/kg 01/18/23 10:44 106-50-3 IL01/17/23 14:428448441
Phorate <155 ug/kg 01/18/23 10:44 298-02-2 v101/17/23 14:424221551
2-Picoline <84.8 ug/kg 01/18/23 10:44 109-06-8 M101/17/23 14:4242284.8 1
Pronamide <113 ug/kg 01/18/23 10:44 23950-58-501/17/23 14:428441131
Pyrene <171 ug/kg 01/18/23 10:44 129-00-001/17/23 14:424221711
Pyridine <133 ug/kg 01/18/23 10:44 110-86-101/17/23 14:424221331
Safrole <75.6 ug/kg 01/18/23 10:44 94-59-701/17/23 14:4284475.6 1
Sulfotepp (Thiodiphosphoric Ac <105 ug/kg 01/18/23 10:44 3689-24-501/17/23 14:424221051
1,2,4,5-Tetrachlorobenzene <103 ug/kg 01/18/23 10:44 95-94-301/17/23 14:424221031
2,3,4,6-Tetrachlorophenol <106 ug/kg 01/18/23 10:44 58-90-201/17/23 14:424221061
Thionazin <104 ug/kg 01/18/23 10:44 297-97-201/17/23 14:424221041
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 41
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Sample:>10 Lab ID:92645777001 Collected:01/05/23 13:45 Received:01/09/23 12:41 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
O-Toluidine <86.5 ug/kg 01/18/23 10:44 95-53-4 M101/17/23 14:4242286.5 1
2,4,5-Trichlorophenol <193 ug/kg 01/18/23 10:44 95-95-401/17/23 14:424221931
2,4,6-Trichlorophenol <174 ug/kg 01/18/23 10:44 88-06-201/17/23 14:424221741
1,3,5-Trinitrobenzene <196 ug/kg 01/18/23 10:44 99-35-4 v101/17/23 14:424221961
Surrogates
2-Fluorobiphenyl (S)40 %01/18/23 10:44 321-60-801/17/23 14:4210-130 1
Terphenyl-d14 (S)37 %01/18/23 10:44 1718-51-001/17/23 14:4210-130 1
Phenol-d6 (S)54 %01/18/23 10:44 13127-88-301/17/23 14:4210-130 1
2-Fluorophenol (S)54 %01/18/23 10:44 367-12-401/17/23 14:4210-130 1
2,4,6-Tribromophenol (S)53 %01/18/23 10:44 118-79-601/17/23 14:4210-131 1
Nitrobenzene-d5 (S)57 %01/18/23 10:44 4165-60-001/17/23 14:4210-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 20.4 %01/10/23 11:48 N20.10 0.10 1
Analytical Method: SM 4500-S2D-2011 Modified Preparation Method: SM 4500-S2D-2011 Modified
Pace Analytical Services - Asheville
4500S2D Sulfide Soil
Sulfide <6.0 mg/kg 01/12/23 03:32 18496-25-801/12/23 02:176.0 6.0 1
Analytical Method: SM 4500-CN-E-2011 Preparation Method: SM 4500-CN-E-2011
Pace Analytical Services - Asheville
4500CNE Cyanide, Total
Cyanide <0.19 mg/kg 01/13/23 19:35 57-12-501/13/23 17:040.38 0.19 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
885659
EPA 7471
EPA 7471
7471 Mercury
Laboratory:Pace Analytical Services - Ormond Beach
Associated Lab Samples:92645777001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4872037
Associated Lab Samples:92645777001
Matrix:Solid
AnalyzedMDL
Mercury mg/kg <0.0046 0.0093 01/16/23 13:510.0046
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4872038LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/kg 0.0960.097 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4872039MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35769980001
4872040
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury mg/kg M10.452 116 80-120126 4 200.4470.30 0.83 0.87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
885880
EPA 3050
EPA 6010
6010 MET Solid
Laboratory:Pace Analytical Services - Ormond Beach
Associated Lab Samples:92645777001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4873101
Associated Lab Samples:92645777001
Matrix:Solid
AnalyzedMDL
Antimony mg/kg <0.44 0.88 01/13/23 08:320.44
Arsenic mg/kg <0.29 0.59 01/13/23 08:320.29
Barium mg/kg <0.099 0.59 01/13/23 08:320.099
Beryllium mg/kg <0.010 0.059 01/13/23 08:320.010
Cadmium mg/kg <0.029 0.059 01/13/23 08:320.029
Chromium mg/kg 0.41 0.29 01/13/23 08:320.15
Cobalt mg/kg <0.066 0.59 01/13/23 08:320.066
Copper mg/kg <0.15 0.29 01/13/23 08:320.15
Lead mg/kg <0.29 0.59 01/13/23 08:320.29
Nickel mg/kg 0.17J 0.29 01/13/23 08:320.15
Selenium mg/kg <0.44 0.88 01/13/23 08:320.44
Silver mg/kg <0.065 0.29 01/13/23 08:320.065
Thallium mg/kg <0.39 0.88 01/13/23 08:320.39
Tin mg/kg <1.5 2.9 01/13/23 08:321.5
Vanadium mg/kg <0.062 0.59 01/13/23 08:320.062
Zinc mg/kg <2.1 5.9 01/13/23 08:322.1
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4873102LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony mg/kg 12.413.4 92 80-120
Arsenic mg/kg 12.213.4 91 80-120
Barium mg/kg 13.813.4 103 80-120
Beryllium mg/kg 1.21.3 92 80-120
Cadmium mg/kg 1.31.3 96 80-120
Chromium mg/kg 13.413.4 100 80-120
Cobalt mg/kg 13.113.4 98 80-120
Copper mg/kg 13.213.4 98 80-120
Lead mg/kg 13.113.4 98 80-120
Nickel mg/kg 13.113.4 98 80-120
Selenium mg/kg 12.213.4 91 80-120
Silver mg/kg 1.31.3 94 80-120
Thallium mg/kg 12.813.4 96 80-120
Tin mg/kg 64.567.1 96 80-120
Vanadium mg/kg 13.213.4 98 80-120
Zinc mg/kg 64.067.1 95 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4873103MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35770560001
4873104
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony mg/kg 14.3 84 75-12582 1 2014.81.4 13.4 13.5
Arsenic mg/kg 14.3 90 75-12588 1 2014.80.98 13.8 14.0
Barium mg/kg M114.3 88 75-12572 2 2014.887.4 100 98.1
Beryllium mg/kg 1.43 92 75-12591 1 201.430.054J 1.4 1.4
Cadmium mg/kg 1.43 88 75-12586 0 201.430.71 2.0 2.0
Chromium mg/kg 14.3 102 75-12595 3 2014.88.8 23.5 22.9
Cobalt mg/kg 14.3 92 75-12591 1 2014.81.1 14.3 14.4
Copper mg/kg E14.3 152 75-125137 1 2014.8156 177 176
Lead mg/kg 14.3 87 75-12586 1 2014.810.1 22.6 22.8
Nickel mg/kg 14.3 94 75-12589 1 2014.89.5 22.9 22.7
Selenium mg/kg 14.3 97 75-12594 0 2014.85.2 19.0 19.0
Silver mg/kg 1.43 90 75-12586 0 201.432.3 3.6 3.6
Thallium mg/kg 14.3 78 75-12576 1 2014.80.41U 11.1 11.3
Tin mg/kg M171.6 75 75-12574 1 2073.931.7 85.4 86.2
Vanadium mg/kg 14.3 96 75-12593 0 2014.86.0 19.8 19.8
Zinc mg/kg E71.6 -115 75-125-132 2 2073.9832 750 735
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
748442
EPA 3546
EPA 8081B
8081 GCS Pesticides
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92645777001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3890798
Associated Lab Samples:92645777001
Matrix:Solid
AnalyzedMDL
4,4'-DDD ug/kg <0.92 2.0 01/11/23 12:220.92
4,4'-DDE ug/kg <0.96 2.0 01/11/23 12:220.96
4,4'-DDT ug/kg <0.90 2.0 01/11/23 12:220.90
Aldrin ug/kg <0.82 2.0 01/11/23 12:220.82
alpha-BHC ug/kg <0.88 2.0 01/11/23 12:220.88
beta-BHC ug/kg <0.98 2.0 01/11/23 12:220.98
Chlordane (Technical)ug/kg <8.8 10.1 01/11/23 12:228.8
delta-BHC ug/kg <1.0 2.0 01/11/23 12:221.0
Dieldrin ug/kg <0.88 2.0 01/11/23 12:220.88
Endosulfan I ug/kg <0.87 2.0 01/11/23 12:220.87
Endosulfan II ug/kg <0.92 2.0 01/11/23 12:220.92
Endosulfan sulfate ug/kg <1.1 2.0 01/11/23 12:221.1
Endrin ug/kg <0.94 2.0 01/11/23 12:220.94
Endrin aldehyde ug/kg <1.4 2.0 01/11/23 12:221.4
Endrin ketone ug/kg <1.1 2.0 01/11/23 12:221.1
gamma-BHC (Lindane)ug/kg <0.81 2.0 01/11/23 12:220.81
Heptachlor ug/kg <0.94 2.0 01/11/23 12:220.94
Heptachlor epoxide ug/kg <0.80 2.0 01/11/23 12:220.80
Hexachlorobenzene ug/kg <0.84 2.0 01/11/23 12:220.84
Methoxychlor ug/kg <2.5 5.1 01/11/23 12:222.5
Mirex ug/kg <2.2 5.1 01/11/23 12:222.2
Toxaphene ug/kg <5.4 7.1 01/11/23 12:225.4
Decachlorobiphenyl (S)%87 10-146 01/11/23 12:22
Tetrachloro-m-xylene (S)%80 10-133 01/11/23 12:22
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3890799LABORATORY CONTROL SAMPLE:
LCSSpike
4,4'-DDD ug/kg 8.98.2 108 40-160
4,4'-DDE ug/kg 8.98.2 109 41-154
4,4'-DDT ug/kg 9.38.2 113 34-163
Aldrin ug/kg 6.98.2 84 39-144
alpha-BHC ug/kg 7.08.2 86 36-145
beta-BHC ug/kg 6.88.2 83 39-152
delta-BHC ug/kg 7.28.2 87 41-147
Dieldrin ug/kg 8.88.2 107 42-153
Endosulfan I ug/kg 7.38.2 88 39-148
Endosulfan II ug/kg 7.08.2 86 40-147
Endosulfan sulfate ug/kg 7.08.2 86 40-148
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3890799LABORATORY CONTROL SAMPLE:
LCSSpike
Endrin ug/kg 8.98.2 108 42-158
Endrin aldehyde ug/kg 6.08.2 73 39-130
Endrin ketone ug/kg 6.68.2 80 39-159
gamma-BHC (Lindane)ug/kg 7.18.2 87 38-146
Heptachlor ug/kg 7.38.2 88 39-144
Heptachlor epoxide ug/kg 7.08.2 85 40-143
Hexachlorobenzene ug/kg 6.78.2 81 33-139
Methoxychlor ug/kg 21.224.7 86 32-146
Mirex ug/kg 21.524.7 87 39-141
Decachlorobiphenyl (S)%91 10-146
Tetrachloro-m-xylene (S)%81 10-133
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3890800MATRIX SPIKE SAMPLE:
MSSpike
Result
92645777001
4,4'-DDD ug/kg 9.610.7 91 10-160<1.1
4,4'-DDE ug/kg 9.910.7 93 10-170<1.2
4,4'-DDT ug/kg 9.910.7 93 10-194<1.1
Aldrin ug/kg 7.910.7 74 10-143<1.0
alpha-BHC ug/kg 8.010.7 75 10-144<1.1
beta-BHC ug/kg 8.510.7 80 10-152<1.2
delta-BHC ug/kg 8.210.7 77 10-147<1.2
Dieldrin ug/kg 10.210.7 95 10-181<1.1
Endosulfan I ug/kg 8.010.7 75 10-147<1.1
Endosulfan II ug/kg 7.910.7 75 11-149<1.1
Endosulfan sulfate ug/kg 8.010.7 75 10-153<1.4
Endrin ug/kg 9.710.7 91 10-160<1.2
Endrin aldehyde ug/kg 6.710.7 63 10-134<1.7
Endrin ketone ug/kg 7.710.7 72 11-155<1.4
gamma-BHC (Lindane)ug/kg 9.310.7 88 10-152<1.0
Heptachlor ug/kg 8.210.7 77 10-149<1.2
Heptachlor epoxide ug/kg 8.010.7 75 10-142<0.99
Hexachlorobenzene ug/kg 7.410.7 69 10-140<1.0
Methoxychlor ug/kg 25.431.9 79 10-147<3.1
Mirex ug/kg 23.231.9 73 11-139<2.8
Decachlorobiphenyl (S)%61 10-146
Tetrachloro-m-xylene (S)%49 10-133
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92645833001
3890801SAMPLE DUPLICATE:
4,4'-DDD ug/kg <22.7 30ND
4,4'-DDE ug/kg <23.6 30ND
4,4'-DDT ug/kg <22.2 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92645833001
3890801SAMPLE DUPLICATE:
Aldrin ug/kg <20.2 30ND
alpha-BHC ug/kg <21.7 30ND
beta-BHC ug/kg <24.1 30ND
Chlordane (Technical)ug/kg 811 D673301740
delta-BHC ug/kg <24.9 30ND
Dieldrin ug/kg <21.7 30ND
Endosulfan I ug/kg <21.4 30ND
Endosulfan II ug/kg <22.6 30ND
Endosulfan sulfate ug/kg <27.7 30ND
Endrin ug/kg <23.3 30ND
Endrin aldehyde ug/kg <33.5 30ND
Endrin ketone ug/kg <27.5 30ND
gamma-BHC (Lindane)ug/kg <20.0 30ND
Heptachlor ug/kg <23.1 30ND
Heptachlor epoxide ug/kg <19.8 30ND
Hexachlorobenzene ug/kg <20.7 30ND
Methoxychlor ug/kg <61.2 30ND
Mirex ug/kg <55.2 30ND
Toxaphene ug/kg <133 30ND
Decachlorobiphenyl (S)%0 S40
Tetrachloro-m-xylene (S)%0 S40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
749785
EPA 3546
EPA 8082A
8082 GCS PCB
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92645777001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3897436
Associated Lab Samples:92645777001
Matrix:Solid
AnalyzedMDL
PCB-1016 (Aroclor 1016)ug/kg <12.9 32.6 01/18/23 10:0412.9
PCB-1221 (Aroclor 1221)ug/kg <21.9 32.6 01/18/23 10:0421.9
PCB-1232 (Aroclor 1232)ug/kg <14.5 32.6 01/18/23 10:0414.5
PCB-1242 (Aroclor 1242)ug/kg <7.9 32.6 01/18/23 10:047.9
PCB-1248 (Aroclor 1248)ug/kg <8.8 32.6 01/18/23 10:048.8
PCB-1254 (Aroclor 1254)ug/kg <14.3 32.6 01/18/23 10:0414.3
PCB-1260 (Aroclor 1260)ug/kg <14.4 32.6 01/18/23 10:0414.4
Decachlorobiphenyl (S)%83 10-160 01/18/23 10:04
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3897437LABORATORY CONTROL SAMPLE:
LCSSpike
PCB-1016 (Aroclor 1016)ug/kg 121168 72 34-143
PCB-1260 (Aroclor 1260)ug/kg 116168 69 31-146
Decachlorobiphenyl (S)%71 10-160
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3897438MATRIX SPIKE SAMPLE:
MSSpike
Result
92645777001
PCB-1016 (Aroclor 1016)ug/kg 140209 67 10-184<16.3
PCB-1260 (Aroclor 1260)ug/kg 150209 72 10-151<18.2
Decachlorobiphenyl (S)%76 10-160
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92646676001
3897439SAMPLE DUPLICATE:
PCB-1016 (Aroclor 1016)ug/kg <133 30ND
PCB-1221 (Aroclor 1221)ug/kg <226 30ND
PCB-1232 (Aroclor 1232)ug/kg <149 30ND
PCB-1242 (Aroclor 1242)ug/kg <81.5 30ND
PCB-1248 (Aroclor 1248)ug/kg <90.6 30ND
PCB-1254 (Aroclor 1254)ug/kg <147 30ND
PCB-1260 (Aroclor 1260)ug/kg <148 30ND
Decachlorobiphenyl (S)%0 D3,S40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
749782
EPA 3546
EPA 8270E
8270E Solid MSSV Microwave
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92645777001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3897426
Associated Lab Samples:92645777001
Matrix:Solid
AnalyzedMDL
1,2,4,5-Tetrachlorobenzene ug/kg <81.2 333 01/18/23 09:1481.2
1,3,5-Trinitrobenzene ug/kg <155 333 v101/18/23 09:14155
1,3-Dinitrobenzene ug/kg <74.8 333 01/18/23 09:1474.8
1,4-Naphthoquinone ug/kg <86.8 1670 01/18/23 09:1486.8
1-Naphthalenamine ug/kg <112 667 01/18/23 09:14112
2,2'-Oxybis(1-chloropropane)ug/kg <159 333 01/18/23 09:14159
2,3,4,6-Tetrachlorophenol ug/kg <83.5 333 01/18/23 09:1483.5
2,4,5-Trichlorophenol ug/kg <153 333 01/18/23 09:14153
2,4,6-Trichlorophenol ug/kg <137 333 01/18/23 09:14137
2,4-Dichlorophenol ug/kg <130 333 01/18/23 09:14130
2,4-Dimethylphenol ug/kg <138 333 01/18/23 09:14138
2,4-Dinitrophenol ug/kg <1030 1670 01/18/23 09:141030
2,4-Dinitrotoluene ug/kg <128 333 01/18/23 09:14128
2,6-Dichlorophenol ug/kg <85.4 333 01/18/23 09:1485.4
2,6-Dinitrotoluene ug/kg <122 333 01/18/23 09:14122
2-Acetylaminofluorene ug/kg <95.2 667 v101/18/23 09:1495.2
2-Chloronaphthalene ug/kg <132 333 01/18/23 09:14132
2-Chlorophenol ug/kg <125 333 01/18/23 09:14125
2-Methylnaphthalene ug/kg <133 333 01/18/23 09:14133
2-Methylphenol(o-Cresol)ug/kg <136 333 01/18/23 09:14136
2-Naphthalenamine ug/kg <128 667 01/18/23 09:14128
2-Nitroaniline ug/kg <273 1670 01/18/23 09:14273
2-Nitrophenol ug/kg <144 333 01/18/23 09:14144
2-Picoline ug/kg <67.0 333 01/18/23 09:1467.0
3&4-Methylphenol(m&p Cresol)ug/kg <134 333 01/18/23 09:14134
3,3'-Dichlorobenzidine ug/kg <225 667 01/18/23 09:14225
3,3'-Dimethylbenzidine ug/kg <297 667 IH01/18/23 09:14297
3-Methylcholanthrene ug/kg <126 333 01/18/23 09:14126
3-Nitroaniline ug/kg <262 1670 01/18/23 09:14262
4,6-Dinitro-2-methylphenol ug/kg <311 667 01/18/23 09:14311
4-Aminobiphenyl ug/kg <76.1 333 01/18/23 09:1476.1
4-Bromophenylphenyl ether ug/kg <128 333 01/18/23 09:14128
4-Chloro-3-methylphenol ug/kg <234 667 01/18/23 09:14234
4-Chloroaniline ug/kg <262 667 01/18/23 09:14262
4-Chlorophenylphenyl ether ug/kg <124 333 01/18/23 09:14124
4-Nitroaniline ug/kg <254 667 01/18/23 09:14254
4-Nitrophenol ug/kg <644 1670 01/18/23 09:14644
4-Nitroquinoline-n-oxide ug/kg <246 1670 01/18/23 09:14246
5-Nitro-o-toluidine ug/kg <100 333 01/18/23 09:14100
7,12-Dimethylbenz(a)anthracene ug/kg <137 333 01/18/23 09:14137
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3897426
Associated Lab Samples:92645777001
Matrix:Solid
AnalyzedMDL
a,a-Dimethylphenylethylamine ug/kg <261 1670 v101/18/23 09:14261
Acenaphthene ug/kg <117 333 01/18/23 09:14117
Acenaphthylene ug/kg <117 333 01/18/23 09:14117
Acetophenone ug/kg <85.9 333 01/18/23 09:1485.9
Aniline ug/kg <130 333 01/18/23 09:14130
Anthracene ug/kg <109 333 01/18/23 09:14109
Aramite ug/kg <77.6 1670 01/18/23 09:1477.6
Benzo(a)anthracene ug/kg <111 333 01/18/23 09:14111
Benzo(a)pyrene ug/kg <115 333 01/18/23 09:14115
Benzo(b)fluoranthene ug/kg <111 333 01/18/23 09:14111
Benzo(g,h,i)perylene ug/kg <129 333 01/18/23 09:14129
Benzo(k)fluoranthene ug/kg <117 333 01/18/23 09:14117
Benzyl alcohol ug/kg <253 667 01/18/23 09:14253
bis(2-Chloroethoxy)methane ug/kg <138 333 01/18/23 09:14138
bis(2-Chloroethyl) ether ug/kg <125 333 01/18/23 09:14125
bis(2-Ethylhexyl)phthalate ug/kg <129 333 01/18/23 09:14129
Butylbenzylphthalate ug/kg <140 333 01/18/23 09:14140
Chlorobenzilate ug/kg <65.9 333 01/18/23 09:1465.9
Chrysene ug/kg <121 333 01/18/23 09:14121
Di-n-butylphthalate ug/kg <112 333 01/18/23 09:14112
Di-n-octylphthalate ug/kg <131 333 01/18/23 09:14131
Diallate ug/kg <111 333 01/18/23 09:14111
Dibenz(a,h)anthracene ug/kg <128 333 01/18/23 09:14128
Dibenzofuran ug/kg <120 333 01/18/23 09:14120
Diethylphthalate ug/kg <122 333 01/18/23 09:14122
Dimethoate ug/kg <178 667 v101/18/23 09:14178
Dimethylphthalate ug/kg <121 333 01/18/23 09:14121
Dinoseb ug/kg <178 667 v101/18/23 09:14178
Diphenylamine ug/kg <131 333 01/18/23 09:14131
Disulfoton ug/kg <96.5 333 01/18/23 09:1496.5
Ethyl methanesulfonate ug/kg <178 667 01/18/23 09:14178
Famphur ug/kg <169 667 IH01/18/23 09:14169
Fluoranthene ug/kg <114 333 01/18/23 09:14114
Fluorene ug/kg <117 333 01/18/23 09:14117
Hexachlorobenzene ug/kg <130 333 01/18/23 09:14130
Hexachlorocyclopentadiene ug/kg <191 333 01/18/23 09:14191
Hexachloroethane ug/kg <127 333 01/18/23 09:14127
Hexachlorophene ug/kg <1940 3330 IL,v201/18/23 09:141940
Hexachloropropene ug/kg <91.2 333 01/18/23 09:1491.2
Indeno(1,2,3-cd)pyrene ug/kg <131 333 01/18/23 09:14131
Isodrin ug/kg <79.3 333 01/18/23 09:1479.3
Isophorone ug/kg <148 333 01/18/23 09:14148
Isosafrole ug/kg <253 333 01/18/23 09:14253
Kepone ug/kg <368 667 01/18/23 09:14368
Methapyrilene ug/kg <257 1670 v101/18/23 09:14257
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3897426
Associated Lab Samples:92645777001
Matrix:Solid
AnalyzedMDL
Methyl methanesulfonate ug/kg <143 667 v101/18/23 09:14143
Methyl parathion ug/kg <167 333 v101/18/23 09:14167
N-Nitroso-di-n-butylamine ug/kg <115 333 01/18/23 09:14115
N-Nitroso-di-n-propylamine ug/kg <125 333 01/18/23 09:14125
N-Nitrosodiethylamine ug/kg <69.5 333 01/18/23 09:1469.5
N-Nitrosodimethylamine ug/kg <112 333 01/18/23 09:14112
N-Nitrosodiphenylamine ug/kg <118 333 01/18/23 09:14118
N-Nitrosomethylethylamine ug/kg <71.2 333 01/18/23 09:1471.2
N-Nitrosomorpholine ug/kg <96.3 333 01/18/23 09:1496.3
N-Nitrosopiperidine ug/kg <67.2 667 01/18/23 09:1467.2
N-Nitrosopyrrolidine ug/kg <77.2 667 01/18/23 09:1477.2
Nitrobenzene ug/kg <155 333 01/18/23 09:14155
O,O,O-Triethylphosphorothioate ug/kg <67.1 333 01/18/23 09:1467.1
O-Toluidine ug/kg <68.4 333 01/18/23 09:1468.4
P-Dimethylaminoazobenzene ug/kg <31.8 333 IL01/18/23 09:1431.8
p-Phenylenediamine ug/kg <667 667 IL01/18/23 09:14667
Parathion (Ethyl parathion)ug/kg <111 333 v101/18/23 09:14111
Pentachlorobenzene ug/kg <84.0 333 01/18/23 09:1484.0
Pentachloroethane ug/kg <60.5 333 01/18/23 09:1460.5
Pentachloronitrobenzene ug/kg <107 333 01/18/23 09:14107
Pentachlorophenol ug/kg <326 667 01/18/23 09:14326
Phenacetin ug/kg <108 667 01/18/23 09:14108
Phenanthrene ug/kg <109 333 01/18/23 09:14109
Phenol ug/kg <148 333 01/18/23 09:14148
Phorate ug/kg <122 333 v101/18/23 09:14122
Pronamide ug/kg <89.2 667 01/18/23 09:1489.2
Pyrene ug/kg <135 333 01/18/23 09:14135
Pyridine ug/kg <105 333 01/18/23 09:14105
Safrole ug/kg <59.7 667 01/18/23 09:1459.7
Sulfotepp (Thiodiphosphoric Ac ug/kg <82.8 333 01/18/23 09:1482.8
Thionazin ug/kg <82.5 333 01/18/23 09:1482.5
2,4,6-Tribromophenol (S)%70 10-131 01/18/23 09:14
2-Fluorobiphenyl (S)%63 10-130 01/18/23 09:14
2-Fluorophenol (S)%65 10-130 01/18/23 09:14
Nitrobenzene-d5 (S)%67 10-130 01/18/23 09:14
Phenol-d6 (S)%66 10-130 01/18/23 09:14
Terphenyl-d14 (S)%79 10-130 01/18/23 09:14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3897427LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4,5-Tetrachlorobenzene ug/kg 11401670 68 44-130
1,3,5-Trinitrobenzene ug/kg 2220 v1167013346-143
1,3-Dinitrobenzene ug/kg 14201670 85 66-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3897427LABORATORY CONTROL SAMPLE:
LCSSpike
1,4-Naphthoquinone ug/kg 1020J1670 61 10-137
1-Naphthalenamine ug/kg 10901670 65 45-130
2,2'-Oxybis(1-chloropropane)ug/kg 11001670 66 29-130
2,3,4,6-Tetrachlorophenol ug/kg 12701670 76 51-130
2,4,5-Trichlorophenol ug/kg 12801670 77 47-130
2,4,6-Trichlorophenol ug/kg 12401670 74 47-130
2,4-Dichlorophenol ug/kg 11701670 70 45-130
2,4-Dimethylphenol ug/kg 14901670 89 45-130
2,4-Dinitrophenol ug/kg 67508360 81 27-140
2,4-Dinitrotoluene ug/kg 14201670 85 46-130
2,6-Dichlorophenol ug/kg 12801670 77 36-131
2,6-Dinitrotoluene ug/kg 14401670 86 48-130
2-Acetylaminofluorene ug/kg 1720 v1167010323-136
2-Chloronaphthalene ug/kg 12801670 77 46-130
2-Chlorophenol ug/kg 11201670 67 43-130
2-Methylnaphthalene ug/kg 11501670 69 47-130
2-Methylphenol(o-Cresol)ug/kg 11701670 70 42-130
2-Naphthalenamine ug/kg 11001670 66 25-130
2-Nitroaniline ug/kg 25303340 76 41-130
2-Nitrophenol ug/kg 11801670 71 48-130
2-Picoline ug/kg 10601670 63 10-130
3&4-Methylphenol(m&p Cresol)ug/kg 12501670 75 39-130
3,3'-Dichlorobenzidine ug/kg 26003340 78 41-130
3,3'-Dimethylbenzidine ug/kg 3890 IL334011610-130
3-Methylcholanthrene ug/kg 12101670 73 27-130
3-Nitroaniline ug/kg 27603340 82 37-130
4,6-Dinitro-2-methylphenol ug/kg 28003340 84 38-141
4-Aminobiphenyl ug/kg 8101670 48 10-130
4-Bromophenylphenyl ether ug/kg 12501670 75 47-130
4-Chloro-3-methylphenol ug/kg 25103340 75 44-130
4-Chloroaniline ug/kg 22903340 69 41-130
4-Chlorophenylphenyl ether ug/kg 11801670 71 45-130
4-Nitroaniline ug/kg 26803340 80 42-130
4-Nitrophenol ug/kg 68408360 82 39-131
4-Nitroquinoline-n-oxide ug/kg 29503340 88 30-130
5-Nitro-o-toluidine ug/kg 13601670 81 35-132
7,12-Dimethylbenz(a)anthracene ug/kg 11201670 67 62-130
a,a-Dimethylphenylethylamine ug/kg 384J v116702310-160
Acenaphthene ug/kg 12701670 76 49-130
Acenaphthylene ug/kg 12701670 76 50-130
Acetophenone ug/kg 10801670 65 36-130
Aniline ug/kg 9671670 58 38-130
Anthracene ug/kg 12001670 72 49-130
Aramite ug/kg 1630J3340 49 34-130
Benzo(a)anthracene ug/kg 13801670 82 51-130
Benzo(a)pyrene ug/kg 15301670 91 51-130
Benzo(b)fluoranthene ug/kg 16401670 98 49-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3897427LABORATORY CONTROL SAMPLE:
LCSSpike
Benzo(g,h,i)perylene ug/kg 14601670 87 48-140
Benzo(k)fluoranthene ug/kg 16001670 96 51-130
Benzyl alcohol ug/kg 23303340 70 43-130
bis(2-Chloroethoxy)methane ug/kg 12001670 72 43-130
bis(2-Chloroethyl) ether ug/kg 11301670 67 42-130
bis(2-Ethylhexyl)phthalate ug/kg 14201670 85 43-130
Butylbenzylphthalate ug/kg 15901670 95 44-131
Chlorobenzilate ug/kg 13001670 78 55-130
Chrysene ug/kg 13401670 80 51-130
Di-n-butylphthalate ug/kg 13101670 78 46-130
Di-n-octylphthalate ug/kg 15301670 91 45-130
Diallate ug/kg 15201670 91 48-130
Dibenz(a,h)anthracene ug/kg 15301670 92 48-130
Dibenzofuran ug/kg 13101670 78 10-130
Diethylphthalate ug/kg 13501670 81 48-130
Dimethoate ug/kg 1900 v1167011467-133
Dimethylphthalate ug/kg 13201670 79 48-130
Dinoseb ug/kg 1830 v1167010935-130
Diphenylamine ug/kg 12601670 76 58-130
Disulfoton ug/kg 13201670 79 55-139
Ethyl methanesulfonate ug/kg 12601670 76 39-144
Famphur ug/kg 510J IH33401510-130
Fluoranthene ug/kg 12701670 76 48-130
Fluorene ug/kg 12501670 75 48-130
Hexachlorobenzene ug/kg 12301670 73 47-130
Hexachlorocyclopentadiene ug/kg 10201670 61 17-130
Hexachloroethane ug/kg 10901670 65 40-130
Hexachlorophene ug/kg 8220 IL,v3167004910-131
Hexachloropropene ug/kg 11701670 70 34-130
Indeno(1,2,3-cd)pyrene ug/kg 14701670 88 50-130
Isodrin ug/kg 14301670 86 66-130
Isophorone ug/kg 12201670 73 41-130
Isosafrole ug/kg 10901670 65 32-130
Kepone ug/kg 6903340 21 10-147
Methapyrilene ug/kg 1020J v116706110-130
Methyl methanesulfonate ug/kg 1610 v116709623-138
Methyl parathion ug/kg 1930 v1167011557-130
N-Nitroso-di-n-butylamine ug/kg 13801670 82 26-130
N-Nitroso-di-n-propylamine ug/kg 11901670 71 36-130
N-Nitrosodiethylamine ug/kg 11701670 70 34-130
N-Nitrosodimethylamine ug/kg 10501670 63 34-130
N-Nitrosodiphenylamine ug/kg 12601670 76 48-130
N-Nitrosomethylethylamine ug/kg 11401670 68 31-130
N-Nitrosomorpholine ug/kg 15201670 91 22-139
N-Nitrosopiperidine ug/kg 12601670 75 31-130
N-Nitrosopyrrolidine ug/kg 13001670 78 28-130
Nitrobenzene ug/kg 11901670 71 39-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3897427LABORATORY CONTROL SAMPLE:
LCSSpike
O,O,O-Triethylphosphorothioate ug/kg 11101670 66 29-175
O-Toluidine ug/kg 11401670 68 24-130
P-Dimethylaminoazobenzene ug/kg 633 IL16703814-130
p-Phenylenediamine ug/kg <662 IL
Parathion (Ethyl parathion)ug/kg 1670 v1167010061-130
Pentachlorobenzene ug/kg 12101670 73 36-130
Pentachloroethane ug/kg 10801670 65 35-141
Pentachloronitrobenzene ug/kg 16601670 99 37-154
Pentachlorophenol ug/kg 25103340 75 42-130
Phenacetin ug/kg 15701670 94 28-130
Phenanthrene ug/kg 13001670 77 50-130
Phenol ug/kg 12401670 74 42-130
Phorate ug/kg 2070 v1167012459-130
Pronamide ug/kg 15201670 91 30-133
Pyrene ug/kg 14101670 84 50-130
Pyridine ug/kg 9151670 55 26-130
Safrole ug/kg 11401670 68 33-130
Sulfotepp (Thiodiphosphoric Ac ug/kg 12901670 77 10-160
Thionazin ug/kg 13301670 80 43-146
2,4,6-Tribromophenol (S)%75 10-131
2-Fluorobiphenyl (S)%67 10-130
2-Fluorophenol (S)%63 10-130
Nitrobenzene-d5 (S)%65 10-130
Phenol-d6 (S)%67 10-130
Terphenyl-d14 (S)%74 10-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3897428MATRIX SPIKE SAMPLE:
MSSpike
Result
92645777001
1,2,4,5-Tetrachlorobenzene ug/kg 12702060 61 10-130<103
1,3,5-Trinitrobenzene ug/kg 2690 v1206013070-130<196
1,3-Dinitrobenzene ug/kg 17002060 82 70-130<94.7
1,4-Naphthoquinone ug/kg 1230J M120605970-130<110
1-Naphthalenamine ug/kg 1300 M120606370-130<142
2,2'-Oxybis(1-chloropropane)ug/kg 13202060 64 10-130<201
2,3,4,6-Tetrachlorophenol ug/kg 13902060 67 10-136<106
2,4,5-Trichlorophenol ug/kg 14002060 68 19-130<193
2,4,6-Trichlorophenol ug/kg 13802060 67 18-130<174
2,4-Dichlorophenol ug/kg 13902060 67 16-130<165
2,4-Dimethylphenol ug/kg 18202060 88 10-130<175
2,4-Dinitrophenol ug/kg 369010300 36 10-143<1300
2,4-Dinitrotoluene ug/kg 16202060 78 19-130<162
2,6-Dichlorophenol ug/kg 15902060 77 10-150<108
2,6-Dinitrotoluene ug/kg 16502060 80 22-130<155
2-Acetylaminofluorene ug/kg 1990 v120609610-130<120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3897428MATRIX SPIKE SAMPLE:
MSSpike
Result
92645777001
2-Chloronaphthalene ug/kg 13902060 67 18-130<167
2-Chlorophenol ug/kg 13902060 67 20-130<159
2-Methylnaphthalene ug/kg 13402060 65 18-130<169
2-Methylphenol(o-Cresol)ug/kg 14402060 70 13-130<173
2-Naphthalenamine ug/kg 1270 M120606170-130<162
2-Nitroaniline ug/kg 29204140 71 18-130<345
2-Nitrophenol ug/kg 15102060 73 19-130<183
2-Picoline ug/kg 1370 M120606670-130<84.8
3&4-Methylphenol(m&p Cresol)ug/kg 15702060 76 13-130<170
3,3'-Dichlorobenzidine ug/kg 27904140 68 10-130<285
3,3'-Dimethylbenzidine ug/kg 4660 IH414011370-130<376
3-Methylcholanthrene ug/kg 13702060 66 10-183<160
3-Nitroaniline ug/kg 32304140 78 22-130<331
4,6-Dinitro-2-methylphenol ug/kg 30204140 73 10-144<394
4-Aminobiphenyl ug/kg 885 M120604370-130<96.3
4-Bromophenylphenyl ether ug/kg 13802060 67 18-130<162
4-Chloro-3-methylphenol ug/kg 30804140 74 16-130<297
4-Chloroaniline ug/kg 28104140 68 17-130<331
4-Chlorophenylphenyl ether ug/kg 13202060 64 17-130<157
4-Nitroaniline ug/kg 31604140 76 21-130<321
4-Nitrophenol ug/kg 772010300 75 13-131<816
4-Nitroquinoline-n-oxide ug/kg 36404140 88 70-130<312
5-Nitro-o-toluidine ug/kg 16002060 77 10-130<127
7,12-Dimethylbenz(a)anthracene ug/kg 1230 M120605970-130<174
a,a-Dimethylphenylethylamine ug/kg <320 M1,v120601470-130<330
Acenaphthene ug/kg 13902060 67 20-130<148
Acenaphthylene ug/kg 13702060 66 21-130<148
Acetophenone ug/kg 13402060 65 10-130<109
Aniline ug/kg 11802060 57 10-130<165
Anthracene ug/kg 13202060 64 19-130<138
Aramite ug/kg 1850J M141404570-130<98.2
Benzo(a)anthracene ug/kg 15402060 75 17-130<141
Benzo(a)pyrene ug/kg 15802060 77 14-130<146
Benzo(b)fluoranthene ug/kg 17702060 86 11-134<141
Benzo(g,h,i)perylene ug/kg 15802060 76 12-130<164
Benzo(k)fluoranthene ug/kg 16802060 81 15-130<148
Benzyl alcohol ug/kg 28404140 69 20-130<320
bis(2-Chloroethoxy)methane ug/kg 14502060 70 16-130<175
bis(2-Chloroethyl) ether ug/kg 13802060 67 18-130<159
bis(2-Ethylhexyl)phthalate ug/kg 15602060 75 11-130<164
Butylbenzylphthalate ug/kg 17702060 85 10-130<178
Chlorobenzilate ug/kg 1440 M120606970-130<83.3
Chrysene ug/kg 14902060 72 17-130<153
Di-n-butylphthalate ug/kg 14602060 71 16-130<142
Di-n-octylphthalate ug/kg 16802060 81 16-130<166
Diallate ug/kg 17902060 86 70-130<141
Dibenz(a,h)anthracene ug/kg 15802060 76 13-130<162
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3897428MATRIX SPIKE SAMPLE:
MSSpike
Result
92645777001
Dibenzofuran ug/kg 14202060 68 19-130<152
Diethylphthalate ug/kg 15202060 74 22-130<155
Dimethoate ug/kg 2330 v1206011370-130<225
Dimethylphthalate ug/kg 14902060 72 23-130<153
Dinoseb ug/kg 2100 v1206010110-146<225
Diphenylamine ug/kg 14302060 69 16-130<166
Disulfoton ug/kg 15302060 74 70-130<122
Ethyl methanesulfonate ug/kg 16002060 77 70-130<225
Famphur ug/kg 508J IH41401210-200<213
Fluoranthene ug/kg 14202060 69 14-130<144
Fluorene ug/kg 13602060 66 19-130<148
Hexachlorobenzene ug/kg 13602060 66 17-130<165
Hexachlorocyclopentadiene ug/kg 11102060 54 10-130<242
Hexachloroethane ug/kg 12602060 61 14-130<161
Hexachlorophene ug/kg 9460 IL,M1,v3206004670-130<2450
Hexachloropropene ug/kg 14402060 69 10-145<115
Indeno(1,2,3-cd)pyrene ug/kg 15702060 76 13-130<166
Isodrin ug/kg 16602060 80 70-130<100
Isophorone ug/kg 14802060 72 17-130<188
Isosafrole ug/kg 12402060 60 24-130<320
Kepone ug/kg 675J M141401670-130<465
Methapyrilene ug/kg 2400 v1206011610-199<325
Methyl methanesulfonate ug/kg 2000 v120609770-130<182
Methyl parathion ug/kg 2280 v1206011070-130<211
N-Nitroso-di-n-butylamine ug/kg 17102060 83 10-130<146
N-Nitroso-di-n-propylamine ug/kg 14902060 72 10-130<159
N-Nitrosodiethylamine ug/kg 14502060 70 10-130<88.0
N-Nitrosodimethylamine ug/kg 12602060 61 16-130<142
N-Nitrosodiphenylamine ug/kg 14302060 69 19-130<150
N-Nitrosomethylethylamine ug/kg 14302060 69 10-130<90.1
N-Nitrosomorpholine ug/kg 19302060 93 10-130<122
N-Nitrosopiperidine ug/kg 16502060 80 10-130<85.0
N-Nitrosopyrrolidine ug/kg 16702060 81 10-130<97.7
Nitrobenzene ug/kg 14202060 69 15-130<196
O,O,O-Triethylphosphorothioate ug/kg 1400 M120606870-130<84.9
O-Toluidine ug/kg 1430 M120606970-130<86.5
P-Dimethylaminoazobenzene ug/kg 732 IL,M120603570-130<40.3
p-Phenylenediamine ug/kg <819 IL<844
Parathion (Ethyl parathion)ug/kg 1990 v120609670-130<141
Pentachlorobenzene ug/kg 13702060 66 10-130<106
Pentachloroethane ug/kg 1320 M120606470-130<76.6
Pentachloronitrobenzene ug/kg 18702060 90 24-130<136
Pentachlorophenol ug/kg 27204140 66 10-130<413
Phenacetin ug/kg 18902060 91 10-137<137
Phenanthrene ug/kg 14702060 71 17-130<138
Phenol ug/kg 15402060 75 15-130<188
Phorate ug/kg 2460 v1206011970-130<155
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3897428MATRIX SPIKE SAMPLE:
MSSpike
Result
92645777001
Pronamide ug/kg 17802060 86 10-156<113
Pyrene ug/kg 15602060 75 31-130<171
Pyridine ug/kg 11402060 55 10-130<133
Safrole ug/kg 14002060 68 10-132<75.6
Sulfotepp (Thiodiphosphoric Ac ug/kg 15402060 74 70-130<105
Thionazin ug/kg 15602060 76 70-130<104
2,4,6-Tribromophenol (S)%64 10-131
2-Fluorobiphenyl (S)%55 10-130
2-Fluorophenol (S)%60 10-130
Nitrobenzene-d5 (S)%63 10-130
Phenol-d6 (S)%66 10-130
Terphenyl-d14 (S)%61 10-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92646848001
3897429SAMPLE DUPLICATE:
1,2,4,5-Tetrachlorobenzene ug/kg <1090 30ND
1,3,5-Trinitrobenzene ug/kg <2070 v130ND
1,3-Dinitrobenzene ug/kg <1000 30ND
1,4-Naphthoquinone ug/kg <1160 30ND
1-Naphthalenamine ug/kg <1500 30ND
2,2'-Oxybis(1-chloropropane)ug/kg <2120 30ND
2,3,4,6-Tetrachlorophenol ug/kg <1120 30ND
2,4,5-Trichlorophenol ug/kg <2040 30ND
2,4,6-Trichlorophenol ug/kg <1840 30ND
2,4-Dichlorophenol ug/kg <1740 30ND
2,4-Dimethylphenol ug/kg <1850 30ND
2,4-Dinitrophenol ug/kg <13800 30ND
2,4-Dinitrotoluene ug/kg <1710 30ND
2,6-Dichlorophenol ug/kg <1140 30ND
2,6-Dinitrotoluene ug/kg <1630 30ND
2-Acetylaminofluorene ug/kg <1270 v130ND
2-Chloronaphthalene ug/kg <1770 30ND
2-Chlorophenol ug/kg <1670 30ND
2-Methylnaphthalene ug/kg <1780 30ND
2-Methylphenol(o-Cresol)ug/kg <1820 30ND
2-Naphthalenamine ug/kg <1710 30ND
2-Nitroaniline ug/kg <3650 30ND
2-Nitrophenol ug/kg <1930 30ND
2-Picoline ug/kg <895 30ND
3&4-Methylphenol(m&p Cresol)ug/kg <1800 30ND
3,3'-Dichlorobenzidine ug/kg <3010 30ND
3,3'-Dimethylbenzidine ug/kg <3970 IH30ND
3-Methylcholanthrene ug/kg <1690 30ND
3-Nitroaniline ug/kg <3500 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92646848001
3897429SAMPLE DUPLICATE:
4,6-Dinitro-2-methylphenol ug/kg <4160 30ND
4-Aminobiphenyl ug/kg <1020 30ND
4-Bromophenylphenyl ether ug/kg <1710 30ND
4-Chloro-3-methylphenol ug/kg <3130 30ND
4-Chloroaniline ug/kg <3500 30ND
4-Chlorophenylphenyl ether ug/kg <1660 30ND
4-Nitroaniline ug/kg <3390 30ND
4-Nitrophenol ug/kg <8610 30ND
4-Nitroquinoline-n-oxide ug/kg <3290 30ND
5-Nitro-o-toluidine ug/kg <1340 30ND
7,12-Dimethylbenz(a)anthracene ug/kg <1840 30ND
a,a-Dimethylphenylethylamine ug/kg <3480 v130ND
Acenaphthene ug/kg <1570 30ND
Acenaphthylene ug/kg <1570 30ND
Acetophenone ug/kg <1150 30ND
Aniline ug/kg <1740 30ND
Anthracene ug/kg <1460 30ND
Aramite ug/kg <1040 30ND
Benzo(a)anthracene ug/kg <1490 30ND
Benzo(a)pyrene ug/kg <1540 30ND
Benzo(b)fluoranthene ug/kg <1490 30ND
Benzo(g,h,i)perylene ug/kg <1730 30ND
Benzo(k)fluoranthene ug/kg <1570 30ND
Benzyl alcohol ug/kg <3380 30ND
bis(2-Chloroethoxy)methane ug/kg <1850 30ND
bis(2-Chloroethyl) ether ug/kg <1670 30ND
bis(2-Ethylhexyl)phthalate ug/kg <1730 30ND
Butylbenzylphthalate ug/kg <1880 30ND
Chlorobenzilate ug/kg <880 30ND
Chrysene ug/kg <1620 30ND
Di-n-butylphthalate ug/kg <1500 30ND
Di-n-octylphthalate ug/kg <1760 30ND
Diallate ug/kg <1490 30ND
Dibenz(a,h)anthracene ug/kg <1710 30ND
Dibenzofuran ug/kg <1610 30ND
Diethylphthalate ug/kg <1630 30ND
Dimethoate ug/kg <2380 v130ND
Dimethylphthalate ug/kg <1620 30ND
Dinoseb ug/kg <2380 v130ND
Diphenylamine ug/kg <1760 30ND
Disulfoton ug/kg <1290 30ND
Ethyl methanesulfonate ug/kg <2380 30ND
Famphur ug/kg <2250 IH30ND
Fluoranthene ug/kg <1530 30ND
Fluorene ug/kg <1570 30ND
Hexachlorobenzene ug/kg <1740 30ND
Hexachlorocyclopentadiene ug/kg <2550 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92646848001
3897429SAMPLE DUPLICATE:
Hexachloroethane ug/kg <1700 30ND
Hexachlorophene ug/kg <25900 IL,v230ND
Hexachloropropene ug/kg <1220 30ND
Indeno(1,2,3-cd)pyrene ug/kg <1760 30ND
Isodrin ug/kg <1060 30ND
Isophorone ug/kg <1980 30ND
Isosafrole ug/kg <3380 30ND
Kepone ug/kg <4910 30ND
Methapyrilene ug/kg <3430 v130ND
Methyl methanesulfonate ug/kg <1920 v130ND
Methyl parathion ug/kg <2230 v130ND
N-Nitroso-di-n-butylamine ug/kg <1540 30ND
N-Nitroso-di-n-propylamine ug/kg <1670 30ND
N-Nitrosodiethylamine ug/kg <929 30ND
N-Nitrosodimethylamine ug/kg <1500 30ND
N-Nitrosodiphenylamine ug/kg <1580 30ND
N-Nitrosomethylethylamine ug/kg <952 30ND
N-Nitrosomorpholine ug/kg <1290 30ND
N-Nitrosopiperidine ug/kg <898 30ND
N-Nitrosopyrrolidine ug/kg <1030 30ND
Nitrobenzene ug/kg <2070 30ND
O,O,O-Triethylphosphorothioate ug/kg <896 30ND
O-Toluidine ug/kg <914 30ND
P-Dimethylaminoazobenzene ug/kg <425 IL30ND
p-Phenylenediamine ug/kg <8910 IL30ND
Parathion (Ethyl parathion)ug/kg <1490 v130ND
Pentachlorobenzene ug/kg <1120 30ND
Pentachloroethane ug/kg <809 30ND
Pentachloronitrobenzene ug/kg <1430 30ND
Pentachlorophenol ug/kg <4360 30ND
Phenacetin ug/kg <1440 30ND
Phenanthrene ug/kg <1460 30ND
Phenol ug/kg <1980 30ND
Phorate ug/kg <1630 v130ND
Pronamide ug/kg <1190 30ND
Pyrene ug/kg <1810 30ND
Pyridine ug/kg <1400 30ND
Safrole ug/kg <798 30ND
Sulfotepp (Thiodiphosphoric Ac ug/kg <1110 30ND
Thionazin ug/kg <1100 30ND
2,4,6-Tribromophenol (S)%0 S40
2-Fluorobiphenyl (S)%0 D3,S40
2-Fluorophenol (S)%0 S40
Nitrobenzene-d5 (S)%0 S40
Phenol-d6 (S)%0 S40
Terphenyl-d14 (S)%0 S40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
748393
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92645777001
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92645593010
3890503SAMPLE DUPLICATE:
Percent Moisture %18.2 N212518.3
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92645777001
3890504SAMPLE DUPLICATE:
Percent Moisture %20.1 N222520.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
748866
SM 4500-S2D-2011 Modified
SM 4500-S2D-2011 Modified
4500S2D Sulfide Soil
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92645777001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3893158
Associated Lab Samples:92645777001
Matrix:Solid
AnalyzedMDL
Sulfide mg/kg <5.0 5.0 01/12/23 03:305.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3893159LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
3893160
Sulfide mg/kg 26.825 107 80-1209824.4 9 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 41
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
749348
SM 4500-CN-E-2011
SM 4500-CN-E-2011
4500CNE Cyanide, Total
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92645777001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3895487
Associated Lab Samples:92645777001
Matrix:Solid
AnalyzedMDL
Cyanide mg/kg <0.14 0.29 01/13/23 19:330.14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3895488LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide mg/kg 2.42.7 88 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3895489MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92645777001
3895490
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide mg/kg 3.4 90 80-12090 4 103.3<0.19 3.2 3.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 41
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
Analyte concentration exceeded the calibration range. The reported result is estimated.E
This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.IH
This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be
considered an estimated value.IL
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
Surrogate recovery not evaluated against control limits due to sample dilution.S4
The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.v1
The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.v2
The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.v3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 41
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92645777
BOB MAY'S SLC4431902
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92645777001 748442 748636>10 EPA 3546 EPA 8081B
92645777001 749785 750069>10 EPA 3546 EPA 8082A
92645777001 885880 885942>10 EPA 3050 EPA 6010
92645777001 885659 885885>10 EPA 7471 EPA 7471
92645777001 749782 749985>10 EPA 3546 EPA 8270E
92645777001 748393>10 SW-846
92645777001 748866 748871>10 SM 4500-S2D-2011
Modified
SM 4500-S2D-2011
Modified
92645777001 749348 749420>10 SM 4500-CN-E-2011 SM 4500-CN-E-2011
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/18/2023 03:57 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 41
Page 33 of 41
Page 34 of 41
January 18, 2023
Dear Order No:
RE:
Analytical Environmental Services, Inc. received samples on
for the analyses presented in following report.
1
“No problems were encountered during the analyses except as noted in the Case Narrative or by qualifiers in
the report or QC Summary. Additionally, all results for the associated Quality Control samples were within
EPA and/or AES established limits.
AES’ certifications are as follows:
-NELAP/Florida State Laboratory ID E87582 for analysis of Non-Potable Water, Solid & Chemical Materials,
Air & Emissions for Organics, and Drinking Water Microbiology & Metals, effective 07/01/22-06/30/23.
-North Carolina Certification number 562 for analysis of Surface Water, Groundwater, Effluent, effective until
12/31/22.
-South Carolina Environmental Laboratory Certification number 98016003 effective until 6/30/23.
These results relate only to the items tested as received. This report may only be reproduced in full and with
written permission from the laboratory.
If you have any questions regarding these test results, please feel free to call.
Sincerely,
Project Manager
2301B58
Taylor Cannon
Pace Analytical Services, Inc.
9800 Kincey Ave Suite 100
Huntersville NC 28078-8400
92645777
Haris Bejdic
January 11, 2023 7:46 am
Taylor Cannon:
Page 1 of 7Page 35 of 41
Page 2 of 7Page 36 of 41
2301B58-001
18-Jan-23Date:Analytical Environmental Services, Inc
Analyses Date AnalyzedDilution
FactorBatchIDUnitsQualReporting
LimitResult
Client:
Solid
1/5/2023 1:45:00 PM
>10
Matrix:
Collection Date:
Client Sample ID:
92645777
Pace Analytical Services, Inc.
Lab ID:
Project Name:
Analyst
(SW3550C)CHLORINATED HERBICIDES, APPENDIX IX LIST SW8151A
2,4,5-T BRL 42 ug/Kg-dry 349535 1 01/17/2023 15:13 TB
2,4,5-TP (Silvex)BRL 42 ug/Kg-dry 349535 1 01/17/2023 15:13 TB
2,4-D BRL 42 ug/Kg-dry 349535 1 01/17/2023 15:13 TB
Dinoseb BRL 110 ug/Kg-dry 349535 1 01/17/2023 15:13 TB
Surr: DCAA 88.9 42-120 %REC 349535 1 01/17/2023 15:13 TB
PERCENT MOISTURE D2216
Percent Moisture 21.9 0 wt%R505847 1 01/11/2023 00:00 JW
Qualifiers: * Value exceeds maximum contaminant level
BRL Below reporting limit
H Holding times for preparation or analysis exceeded
N Analyte not NELAC certified
B Analyte detected in the associated method blank
E Estimated (value above quantitation range)
S Spike Recovery outside limits due to matrix
Narr See case narrative
F Analyzed in the lab which is a deviation from the method
< Less than Result value
> Greater than Result value J Estimated value detected below Reporting Limit Page 3 of 7Page 37 of 41
SAMPLE/COOLERRECEIPTCHECKLIST1. ClientName:AESWorkOrderNumber:2.Carrier:FedExUPSUSPSClientCourierOtherYes No N/ADetailsComments3.Shippingcontainer/coolerreceivedingoodcondition?damagedleakingother4.Custodysealspresentonshippingcontainer?5.Custodysealsintactonshippingcontainer?6.Temperatureblankspresent?7.Coolertemperature(s)withinlimitsof0Ͳ6϶C?[Seeitem13 and 14fortemperature recordings.]Coolinginitiatedforrecentlycollectedsamples/icepresent8.ChainofCustody(COC)present?9.ChainofCustodysigned,dated,andtimedwhenrelinquishedandreceived?10.Samplernameand/orsignatureonCOC?11.Wereallsamplesreceivedwithinholdingtime?12.TATmarkedontheCOC?IfnoTATindicated,proceededwithstandardTATperTerms&Conditions.13.Cooler1Temperature϶CCooler2Temperature϶CCooler3Temperature϶CCooler4Temperature϶C Cooler5Temperature϶CCooler6Temperature϶CCooler7Temperature϶CCooler8Temperature϶C15.Comments:IcertifythatIhavecompletedsections1Ͳ1ϱ(datedinitials).Yes No N/ADetailsComments16.Weresamplecontainersintactuponreceipt?17.Custodysealspresentonsamplecontainers?18.Custodysealsintactonsamplecontainers?19.DosamplecontainerlabelsmatchtheCOC?incompleteinfoillegiblenolabelother20.AreanalysesrequestedindicatedontheCOC?21. WereallofthesampleslistedontheCOCreceived?samplesreceivedbutnotlistedonCOCsampleslistedonCOCnotreceived22.Wasthesamplecollectiondate/timenoted?23.Didwereceivesufficientsamplevolumeforindicatedanalyses?24.Weresamplesreceivedinappropriatecontainers?25.WereVOAsamplesreceivedwithoutheadspace(<1/4"bubble)?26.Weretripblankssubmitted?listedonCOCnotlistedonCOC27.Comments:IcertifythatIhavecompletedsections1ϲͲ27(datedinitials).YesNo N/ADetailsComments28.Havecontainersneedingchemicalpreservationbeenchecked? *29.Containersmeetpreservationguidelines?30.WaspHadjusted at Sample Receipt?IcertifythatIhavecompletedsections28Ͳ30(datedinitials).ClearSave asPace Analytical Services, Inc.2301B580.614.CW 1/11/23This section only applies to samples where pH can be checked at Sample Receipt.CW 1/11/23* Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & Grease/TPH.This also excludes metals by EPA 200.7, 200.8 and 245.1 which will be verified between 16 and 24 hours after preservation.CW 1/11/23LockedChecklist 7.9.20 Rev 3Page 4 of 7Page 38 of 41
18-Jan-23Date:Analytical Environmental Services, Inc
Client:
BatchID:Workorder:
Project Name:ANALYTICAL QC SUMMARY REPORT92645777
2301B58
Pace Analytical Services, Inc.
349535
RPT Limit QualAnalyteResultSPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit
SampleType:BatchID:Analysis Date:Seq No:TestCode:349535MBLK 01/17/2023CHLORINATED HERBICIDES, APPENDIX IX LIST SW8151A
Units:Prep Date:Sample ID:Client ID:Run No:ug/Kg 01/17/2023 506422MB-349535
11887455
2,4,5-T 33BRL
2,4,5-TP (Silvex)33BRL
2,4-D 33BRL
Dinoseb 85BRL
Surr: DCAA 0133.2 166.7 79.9 42 120
RPT Limit QualAnalyteResultSPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit
SampleType:BatchID:Analysis Date:Seq No:TestCode:349535LCS 01/17/2023CHLORINATED HERBICIDES, APPENDIX IX LIST SW8151A
Units:Prep Date:Sample ID:Client ID:Run No:ug/Kg 01/17/2023 506422LCS-349535
11887456
2,4,5-T 33140.8 166.7 84.5 50.5 120
2,4,5-TP (Silvex)33145.3 166.7 87.2 52.8 120
2,4-D 33142.9 166.7 85.7 50.6 120
Surr: DCAA 0150.9 166.7 90.5 42 120
RPT Limit QualAnalyteResultSPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit
SampleType:BatchID:Analysis Date:Seq No:TestCode:349535MS 01/17/2023CHLORINATED HERBICIDES, APPENDIX IX LIST SW8151A
Units:Prep Date:Sample ID:Client ID:Run No:ug/Kg-dry 01/17/2023 5064222301G31-003BMS
11887460
2,4,5-T 42160.5 210.6 76.2 40.6 120
2,4,5-TP (Silvex)42161.9 210.6 76.9 42 120
2,4-D 42160.0 210.6 76.0 40.3 118
Surr: DCAA 0158.4 210.6 75.2 42 120
RPT Limit QualAnalyteResultSPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit
SampleType:BatchID:Analysis Date:Seq No:TestCode:349535MSD 01/17/2023CHLORINATED HERBICIDES, APPENDIX IX LIST SW8151A
Units:Prep Date:Sample ID:Client ID:Run No:ug/Kg-dry 01/17/2023 5064222301G31-003BMSD
11887464
Qualifiers:
J Estimated value detected below Reporting Limit
BRL Below reporting limit H Holding times for preparation or analysis exceeded
N Analyte not NELAC certified
B Analyte detected in the associated method blank
E Estimated (value above quantitation range)
S Spike Recovery outside limits due to matrix
< Less than Result value> Greater than Result value
R RPD outside limits due to matrix
Rpt Lim Reporting Limit Page 5 of 7Page 39 of 41
18-Jan-23Date:Analytical Environmental Services, Inc
Client:
BatchID:Workorder:
Project Name:ANALYTICAL QC SUMMARY REPORT92645777
2301B58
Pace Analytical Services, Inc.
349535
RPT Limit QualAnalyteResultSPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit
SampleType:BatchID:Analysis Date:Seq No:TestCode:349535MSD 01/17/2023CHLORINATED HERBICIDES, APPENDIX IX LIST SW8151A
Units:Prep Date:Sample ID:Client ID:Run No:ug/Kg-dry 01/17/2023 5064222301G31-003BMSD
11887464
2,4,5-T 42168.9 23.8210.6 80.2 40.6 120 160.5 5.10
2,4,5-TP (Silvex)42169.4 23.1210.6 80.4 42 120 161.9 4.51
2,4-D 42163.4 24.9210.6 77.6 40.3 118 160.0 2.12
Surr: DCAA 0165.4 0210.6 78.5 42 120 158.4 0
Qualifiers:
J Estimated value detected below Reporting Limit
BRL Below reporting limit H Holding times for preparation or analysis exceeded
N Analyte not NELAC certified
B Analyte detected in the associated method blank
E Estimated (value above quantitation range)
S Spike Recovery outside limits due to matrix
< Less than Result value> Greater than Result value
R RPD outside limits due to matrix
Rpt Lim Reporting Limit Page 6 of 7Page 40 of 41

End of Report
Page 7 of 7Page 41 of 41

APPENDIX D
BILL OF LADING / MATERIAL MANIFEST

2/4/2023S. Kaiser2/3/2024xNC20230026
2/4/2023S. Kaiser2/3/2024xNC20230027
2/4/2023S. Kaiser2/3/2024xNC20230025